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Sample records for liquor recovery boilers

  1. Black liquor combustion validated recovery boiler modeling, five-year report

    Energy Technology Data Exchange (ETDEWEB)

    Grace, T.M.; Frederick, W.J.; Salcudean, M.; Wessel, R.A.

    1996-08-01

    The objective of this project was to develop a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. The project originated in October 1990 and was scheduled to run for four years. At that time, there was considerable emphasis on developing accurate predictions of the physical carryover of macroscopic particles of partially burnt black liquor and smelt droplets out of the furnace, since this was seen as the main cause of boiler plugging. This placed a major emphasis on gas flow patterns within the furnace and on the mass loss rates and swelling and shrinking rates of burning black liquor drops. As work proceeded on developing the recovery boiler furnace model, it became apparent that some recovery boilers encounter serious plugging problems even when physical carryover was minimal. After the original four-year period was completed, the project was extended to address this issue. The objective of the extended project was to improve the utility of the models by including the black liquor chemistry relevant to air emissions predictions and aerosol formation, and by developing the knowledge base and computational tools to relate furnace model outputs to fouling and plugging of the convective sections of the boilers. The work done to date includes CFD model development and validation, acquisition of information on black liquor combustion fundamentals and development of improved burning models, char bed model development, and model application and simplification.

  2. Improved Materials for Use as Components in Kraft Black Liquor Recovery Boilers; TOPICAL

    International Nuclear Information System (INIS)

    Keiser, J.R.

    2001-01-01

    This Cooperative Research and Development Agreement (CRADA) was undertaken to evaluate current and improved materials and materials processing conditions for use as components in kraft black liquor recovery boilers and other unit processes. The main areas addressed were: (1) Improved Black Liquor Nozzles, (2) Weld Overlay of Composite Floor Tubes, and (3) Materials for Lime Kilns. Iron aluminide was evaluated as an alternate material for the nozzles used to inject an aqueous solution known as black liquor into recovery boilers as well for the uncooled lining in the ports used for the nozzles. Although iron aluminide is known to have much better sulfidation resistance in gases than low alloy and stainless steels, it did not perform adequately in the environment where it came into contact with molten carbonate, sulfide and sulfate salts. Weld overlaying carbon steel tubes with a layer of stainless weld metal was a proposed method of extending the life of recovery boiler floor tubes that have experienced considerable fireside corrosion. After exposure under service conditions, sections of weld overlaid floor tubes were removed from a boiler floor and examined metallographically. Examination results indicated satisfactory performance of the tubes. Refractory-lined lime kilns are a critical component of the recovery process in kraft pulp mills, and the integrity of the lining is essential to the successful operation of the kiln. A modeling study was performed to determine the cause of, and possible solutions for, the repeated loss of the refractory lining from the cooled end of a particular kiln. The evaluation showed that the temperature, the brick shape and the coefficient of friction between the bricks were the most important parameters influencing the behavior of the refractory lining

  3. Cracking and Corrosion of Composite Tubes in Black Liquor Recovery Boiler Primary Air Ports

    Energy Technology Data Exchange (ETDEWEB)

    Keiser, James R.; Singbeil, Douglas L.; Sarma, Gorti B.; Kish, Joseph R.; Yuan, Jerry; Frederick, Laurie A.; Choudhury, Kimberly A.; Gorog, J. Peter; Jetté, Francois R.; Hubbard, Camden R.; Swindeman, Robert W.; Singh, Prett M.; Maziasz, Phillip J.

    2006-10-01

    Black liquor recovery boilers are an essential part of kraft mills. Their design and operating procedures have changed over time with the goal of providing improved boiler performance. These performance improvements are frequently associated with an increase in heat flux and/or operating temperature with a subsequent increase in the demand on structural materials associated with operation at higher temperatures and/or in more corrosive environments. Improvements in structural materials have therefore been required. In most cases the alternate materials have provided acceptable solutions. However, in some cases the alternate materials have solved the original problem but introduced new issues. This report addresses the performance of materials in the tubes forming primary air port openings and, particularly, the problems associated with use of stainless steel clad carbon steel tubes and the solutions that have been identified.

  4. Materials for the pulp and paper industry. Section 1: Development of materials for black liquor recovery boilers

    Energy Technology Data Exchange (ETDEWEB)

    Keiser, J.R.; Hubbard, C.R.; Payzant, E.A. [Oak Ridge National Lab., TN (United States)] [and others

    1997-04-01

    Black liquor recovery boilers are essential components of kraft pulp and paper mills because they are a critical element of the system used to recover the pulping chemicals required in the kraft pulping process. In addition, the steam produced in these boilers is used to generate a significant portion of the electrical power used in the mill. Recovery boilers require the largest capital investment of any individual component of a paper mill, and these boilers are a major source of material problems in a mill. The walls and floors of these boilers are constructed of tube panels that circulate high pressure water. Molten salts (smelt) accumulate on the floor of recovery boilers, and leakage of water into the boiler can result in a violent explosion when the leaked water instantly vaporizes upon contacting the molten smelt. Because corrosion of the conventionally-used carbon steel tubing was found to be excessive in the lower section of recovery boilers, use of stainless steel/carbon steel co-extruded tubing was adopted for boiler walls to lessen corrosion and reduce the likelihood of smelt/water explosions. Eventually, this co-extruded or composite (as it is known in the industry) tubing was selected for use as a portion or all of the floor of recovery boilers, particularly those operating at pressures > 6.2 MPa (900 psi), because of the corrosion problems encountered in carbon steel floor tubes. Since neither the cause of the cracking nor an effective solution has been identified, this program was established to develop a thorough understanding of the degradation that occurs in the composite tubing used for walls and floors. This is being accomplished through a program that includes collection and review of technical reports, examination of unexposed and cracked tubes from boiler floors, computer modeling to predict residual stresses under operating conditions, and operation of laboratory tests to study corrosion, stress corrosion cracking, and thermal fatigue.

  5. Feasibility of recovery boiler in paper and pulp industry

    International Nuclear Information System (INIS)

    Rashid, H.

    2010-01-01

    in this paper feasibility of recovery boiler in terms of economics and environmental impacts in studied. Recovery boilers are employed in the pulp and paper industry where the cooking agent is recovered by burning black liquor. Cooking agent is exhausted due to the absorption of lignin (a burnable component) in cooking agent in the process of straw cooking. The process of recovery boiler is to remove lignin by combustion from black liquor, and heat is produced during the combustion of lignin which is used to produce steam. Recovery boiler is economical as it is recovering valuable chemicals and steam is produced as a byproduct. Steam from recovery boiler is also used for concentrating weak black liquor to concentrated black liquor recovering 50% of the utility water being used at the plant. The regenerated water in the form of foul condensate is reused in the process. The recovery of hazardous chemicals also reduces load of environmental pollution. Which otherwise can pollute the water reservoirs, and regeneration of water makes it environmentally friendly plant. Construction and challenges in operation of recovery boiler such as smelt-water explosion are also discussed in this paper. (author)

  6. Recovery boiler model; Soodakattilan kehitystyoe III

    Energy Technology Data Exchange (ETDEWEB)

    Janka, K.; Ylitalo, M.; Sundstroem, K.; Helke, R.; Heinola, M. [Kvaerner Pulping Oy, Tampere (Finland)

    1997-10-01

    The recovery boiler model was further tested and developed. At this moment the model includes submodels for: droplet drying, pyrolysis, char burning, gas burning and for droplet trajectory. During 1996 the formation of CH{sub 4} during pyrolysis and release of sulfur was included to the model. Further the formation of NO from fuel nitrogen and formation of thermal- NO were included to the model using Arrhenius type reaction rate equations. The calculated results are realistic and the model is used as a tool to find out methods to increase the efficiency and availability and decrease the emissions. Analysing the results of the earlier field study of 8 boilers showed that the furnace heat load, fuming rate, find the black liquor composition have influence on the enrichment of the potassium to the fly ash. (orig.)

  7. Cracking and corrosion recovery boiler

    Energy Technology Data Exchange (ETDEWEB)

    Suik, H. [Tallinn Technical University, Horizon Pulp and Paper, Tallinn (Estonia)

    1998-12-31

    The corrosion of heat surfaces and the cracking the drums are the main problems of the recovery boiler. These phenomena have been appeared during long-term operation of boiler `Mitsubishi - 315` erected at 1964. Depth of the crack is depending on the number of shutdowns and on operation time. Corrosion intensity of different heat surfaces is varying depend on the metal temperature and the conditions at place of positioning of tube. The lowest intensity of corrosion is on the bank tubes and the greatest is on the tubes of the second stage superheater and on the tubes at the openings of air ports. (orig.) 5 refs.

  8. Cracking and corrosion recovery boiler

    Energy Technology Data Exchange (ETDEWEB)

    Suik, H [Tallinn Technical University, Horizon Pulp and Paper, Tallinn (Estonia)

    1999-12-31

    The corrosion of heat surfaces and the cracking the drums are the main problems of the recovery boiler. These phenomena have been appeared during long-term operation of boiler `Mitsubishi - 315` erected at 1964. Depth of the crack is depending on the number of shutdowns and on operation time. Corrosion intensity of different heat surfaces is varying depend on the metal temperature and the conditions at place of positioning of tube. The lowest intensity of corrosion is on the bank tubes and the greatest is on the tubes of the second stage superheater and on the tubes at the openings of air ports. (orig.) 5 refs.

  9. CCD camera eases the control of a soda recovery boiler; CCD-kamera helpottaa soodakattilan valvontaa

    Energy Technology Data Exchange (ETDEWEB)

    Kinnunen, L.

    2001-07-01

    Fortum Technology has developed a CCD firebox camera, based on semiconductor technology, enduring hard conditions of soda recovery boiler longer than traditional cameras. The firebox camera air- cooled and the same air is pressed over the main lens so it remains clean despite of the alkaline liquor splashing around in the boiler. The image of the boiler is transferred through the main lens, image transfer lens and a special filter, mounted inside the camera tube, into the CCD camera. The first CCD camera system has been in use since 1999 in Sunila pulp mill in Kotka, owned by Myllykoski Oy and Enso Oyj. The mill has two medium-sized soda recovery boilers. The amount of black liquor, formed daily, is about 2000 tons DS, which is more than enough for the heat generation. Even electric power generation exceeds sometimes the demand, so the surplus power can be sold out. Black liquor is sprayed inside the soda recovery boiler with high pressure. The liquor form droplets in the boiler, the temperature of which is over 1000 deg C. A full-hot pile is formed at the bottom of the boiler after burning. The size and shape of the pile effect on the efficiency and the emissions of the boiler. The camera has operated well.

  10. Further development of recovery boiler; Soodakattilan kehitystyoe

    Energy Technology Data Exchange (ETDEWEB)

    Janka, K.; Siiskonen, P.; Sundstroem, K. [Tampella Power Oy, Tampere (Finland)] [and others

    1996-12-01

    The global model of a recovery boiler was further developed. The aim is to be able to model the velocity, temperature and concentration fields in a boiler. At this moment the model includes submodels for: droplet drying, pyrolysis, char burning, gas burning and for droplet trajectory. The preliminary study of NO{sub x} and fly ash behaviour in a boiler was carried out. The study concerning flow field in the superheater area was carried out a 2-dimensional case in which the inflow parameters were taken from global model of a recovery boiler. Further the prediction methods of fouling in a recovery boiler were developed based on theoretical calculations of smelting behaviour of multicomponent mixtures and measurements at operating recovery boilers. (author)

  11. Factors controlling alkalisalt deposition in recovery boiler- release mechanisms

    Energy Technology Data Exchange (ETDEWEB)

    McKeough, P.; Kylloenen, H.; Kurkela, M. [VTT Energy, Espoo (Finland). Process Technology Group

    1996-12-01

    As part of a cooperative effort to develop a model to describe the behaviour of inorganic compounds in kraft recovery boilers, an experimental investigation of the release of sulphur during black liquor pyrolysis has been undertaken. Previous to these studies, the mechanisms of sulphur release and the reasons for the observed effects of process conditions on sulphur release were very poorly understood. On the basis of the experimental results, the main reactions leading to sulphur release have been elucidated with a fair degree of certainty. Logical explanations for the variations of sulphur release with temperature and with liquor solids content have been proposed. The influence of pressure has been investigated in order to gain insights into the effects of mass transfer on the sulphur-release rate. In the near future, the research will be aimed at generating the kinetic data necessary for modelling the release of sulphur in the recovery furnace. (author)

  12. Reduction efficiency prediction of CENIBRA's recovery boiler by direct minimization of gibbs free energy

    Directory of Open Access Journals (Sweden)

    W. L. Silva

    2008-09-01

    Full Text Available The reduction efficiency is an important variable during the black liquor burning process in the Kraft recovery boiler. This variable value is obtained by slow experimental routines and the delay of this measure disturbs the pulp and paper industry customary control. This paper describes an optimization approach for the reduction efficiency determination in the furnace bottom of the recovery boiler based on the minimization of the Gibbs free energy. The industrial data used in this study were directly obtained from CENIBRA's data acquisition system. The resulting approach is able to predict the steady state behavior of the chemical composition of the furnace recovery boiler, - especially the reduction efficiency when different operational conditions are used. This result confirms the potential of this approach in the analysis of the daily operation of the recovery boiler.

  13. The recovery boiler advisor. Combination of practical experience and advanced thermodynamic modelling

    Energy Technology Data Exchange (ETDEWEB)

    Backman, R. [Aabo Akademi, Turku (Finland); Eriksson, G. [LTH/RWTH (Germany); Sundstroem, K. [Tampella Power Oy, Tampere (Finland)

    1996-12-31

    The Aabo Advisor is a computer based program intended to provide information about the high temperature ash and fluegas chemistry in pulping spent black liquor recovery boilers of kraft pulp mills. The program can be used for predictions of a variety of furnace and flue gas phenomena, such as fireside fouling of the heat exchanger surfaces caused by the flue gas particulate matter, emissions of SO{sub 2}(g), HCl(g) and NO{sub x}(g) with the flue gas etc. The program determines the composition of the fluegas as well as the amount and composition of the two typical fly ash fractions found in recovery boiler fluegases, the condensed fly ash particles and the carry over particles. These data are used for calculating the melting behavior of the fly ash present at different locations in the boiler and this characteristic behavior is used for the fireside fouling predictions. The program may also be used for studying how different mill processes affecting the black liquor composition affects on the fireside chemistry of the recovery boiler. As input data for the calculations only a few boiler operation parameters and the composition of the black liquor is required. The calculations are based on a one-dimensional, multi-stage chemistry model where both thermodynamic equilibrium calculations and stoichiometric material balances are used. The model calculates at first the chemistry in the lower furnace and smelt after which it moves to the upper furnace and the radiative parts of the fluegas channel. As the last block the program calculates the chemistry in the convective part, the electrostatic precipitator cath and stack. The results from each block are presented in tables, key numbers and melt curves representing the fluegas or fly ash fraction present at each location

  14. The recovery boiler advisor. Combination of practical experience and advanced thermodynamic modelling

    Energy Technology Data Exchange (ETDEWEB)

    Backman, R [Aabo Akademi, Turku (Finland); Eriksson, G [LTH/RWTH (Germany); Sundstroem, K [Tampella Power Oy, Tampere (Finland)

    1997-12-31

    The Aabo Advisor is a computer based program intended to provide information about the high temperature ash and fluegas chemistry in pulping spent black liquor recovery boilers of kraft pulp mills. The program can be used for predictions of a variety of furnace and flue gas phenomena, such as fireside fouling of the heat exchanger surfaces caused by the flue gas particulate matter, emissions of SO{sub 2}(g), HCl(g) and NO{sub x}(g) with the flue gas etc. The program determines the composition of the fluegas as well as the amount and composition of the two typical fly ash fractions found in recovery boiler fluegases, the condensed fly ash particles and the carry over particles. These data are used for calculating the melting behavior of the fly ash present at different locations in the boiler and this characteristic behavior is used for the fireside fouling predictions. The program may also be used for studying how different mill processes affecting the black liquor composition affects on the fireside chemistry of the recovery boiler. As input data for the calculations only a few boiler operation parameters and the composition of the black liquor is required. The calculations are based on a one-dimensional, multi-stage chemistry model where both thermodynamic equilibrium calculations and stoichiometric material balances are used. The model calculates at first the chemistry in the lower furnace and smelt after which it moves to the upper furnace and the radiative parts of the fluegas channel. As the last block the program calculates the chemistry in the convective part, the electrostatic precipitator cath and stack. The results from each block are presented in tables, key numbers and melt curves representing the fluegas or fly ash fraction present at each location

  15. Uranium recovery from acid leach liquors: Ix or Sx?

    International Nuclear Information System (INIS)

    Van Tonder, D.; Kotze, M.

    2007-01-01

    Various technologies for uranium recovery from sulphuric acid leach solutions were compared. Although the main consideration was the economics (Capex, recovery and Opex) of the various technologies and associated unit operations, other factors, such as flexibility, reliability, ease of operation, fire risk, stability with regards to feed flow variations, and feed solids content, would also need to be considered in the overall analysis. The design basis used for the comparison was a production rate or 200 kg/h U 3 O8 over a solution concentration range of 40 to 1500 mg/L U 3 O8. The technologies to be compared included Resin-in-pulp (RIP), Fixed-bed Ion Exchange (FBIX), Continuous Countercurrent Ion Exchange (CCIX, e.g. NIMCIX), and Solvent Extraction (Sx) using Bateman Pulsed Columns (BPC) and Bateman Settlers. Countercurrent Decantation (CCD) and clarification would be required for the Sx and FBIX technologies. The preliminary economic evaluation indicated that a flowsheet, comprising RIP for bulk uranium extraction and upgrade, followed by Sx, employing the BPC for purification of the RIP eluate stream, was the most economic option at leach liquor concentrations below 900 mg/L. Above 900 mg/L the economic evaluation suggested that CCDs followed by Sx in the BPC was the most economical processing option. For applications where the ore is abrasive and not amenable to RIP, due to the rate of resin consumption, Paste Thickeners to remove the bulk of the solids, followed by RIP, was found to be the most economic processing option at leach liquor concentrations below 200 mg/L. However, for leach liquor concentrations above 200 mg/L, a CCD-circuit followed by Sx using BPC was again the most economic favourable route

  16. The structure and behavior of salts in kraft recovery boilers

    Energy Technology Data Exchange (ETDEWEB)

    Backman, R.; Badoi, R.D.; Enestam, S. [Aabo Akademi Univ., Turku (Finland). Combustion Chemistry Research Group

    1997-10-01

    The melting behavior in the salt system (Na,K)(CO{sub 3},SO{sub 4},S,Cl,OH) is investigated by laboratory methods to enhance and further develop a chemical model for salt mixtures with compositions relevant for recovery boilers. The model, based on both literature data and experimental work can be used as (a) submodel in models for the over-all chemistry in recovery boilers and to estimate (b) deposit formation on heat transfer surfaces (fouling), (c) the melting properties of the fly ash, and (d) the smelt bed in recovery boilers. Experimental techniques used are thermal analysis, high temperature microscopy` and scanning electron microscopy. The model is implemented in a global calculation model which can handle both gas phases and condensed phases in the recovery boiler. The model gives a detailed description of the chemical reactions involved in the fume and dust formation in different locations of the flue gas channel in the boiler. (orig.)

  17. Final Report, Materials for Industrial Heat Recovery Systems, Tasks 3 and 4 Materials for Heat Recovery in Recovery Boilers

    Energy Technology Data Exchange (ETDEWEB)

    Keiser, James R.; Kish, Joseph R.; Singh, Preet M.; Sarma, Gorti B.; Yuan, Jerry; Gorog, J. Peter; Frederick, Laurie A.; Jette, Francois R.; Meisner, Roberta A.; Singbeil, Douglas L.

    2007-12-31

    The DOE-funded project on materials for industrial heat recovery systems included four research tasks: materials for aluminum melting furnace recuperator tubes, materials and operational changes to prevent cracking and corrosion of the co-extruded tubes that form primary air ports in black liquor recovery boilers, the cause of and means to prevent corrosion of carbon steel tubes in the mid-furnace area of recovery boilers, and materials and operational changes to prevent corrosion and cracking of recovery boiler superheater tubes. Results from studies on the latter two topics are given in this report while separate reports on results for the first two tasks have already been published. Accelerated, localized corrosion has been observed in the mid-furnace area of kraft recovery boilers. This corrosion of the carbon steel waterwall tubes is typically observed in the vicinity of the upper level of air ports where the stainless clad co-extruded wall tubes used in the lower portion of the boiler are welded to the carbon steel tubes that extend from this transition point or “cut line” to the top of the boiler. Corrosion patterns generally vary from one boiler to another depending on boiler design and operating parameters, but the corrosion is almost always found within a few meters of the cut line and often much closer than that. This localized corrosion results in tube wall thinning that can reach the level where the integrity of the tube is at risk. Collection and analysis of gas samples from various areas near the waterwall surface showed reducing and sulfidizing gases were present in the areas where corrosion was accelerated. However, collection of samples from the same areas at intervals over a two year period showed the gaseous environment in the mid-furnace section can cycle between oxidizing and reducing conditions. These fluctuations are thought to be due to gas flow instabilities and they result in an unstable or a less protective scale on the carbon steel

  18. Energy Balance and Performance Indices for Kraft Recovery Boilers; Standardmetod foer beraekning av energibalans oever sodapanna

    Energy Technology Data Exchange (ETDEWEB)

    Kjoerk, Anders

    2007-09-15

    It has been recognized that different rules exist in calculating energy flows to and from a Recovery boiler. In this report definitions are given with the intention that the branch should adopt a common position in reporting power production for the Swedish system with charge on emission of nitrogen oxides, for the EU Emissions Trading Scheme and for the electricity certificate system. Legislation and guidelines are described as also different standards for determination of boiler efficiency. The definition of the liquor heating value is discussed as also the different ways in which an energy balance could be set up. For the Emissions Trading Scheme a literature survey of interpretations made in other countries has been made. The recommendation is to define the heat input as the product of the virgin liquor flow and the net calorific value of virgin liquor. A net calorific value as defined in SS-ISO 1928 is determined in an environment with excess of oxygen and is consequently named net calorific value in oxidizing condition. In a Recovery boiler part of that heat is required for reduction of sulfur and a net calorific value in reducing condition are therefore defined in a branch specific way. The flow of liquor could be calculated using a heat balance based on steam generation. The envelope for that heat balance could be selected as to fit each individual installation; however some general recommendations are given. In reporting energy flow for the EU Emissions Trading Scheme and to EPA it is recommended to use the net calorific value in oxidizing condition. This definition should also be good for reporting to Statistics Sweden, Swedish Forest Industries Federation and for internal use. For reporting to the electricity certificate system the part of the total power production with origin from biofuel should be stated. The heat of reduction is not available for power production and consequently the recommendation is to use the net calorific value in reducing

  19. Atmospheric emission of nitrogen oxide from kraft recovery boilers in Sweden

    International Nuclear Information System (INIS)

    Kjoerk, Anders; Herstad Swaerd, Solvie

    2000-05-01

    Recovery boiler NO x emissions are low compared with those from power boilers. However tighter environmental requirements to decrease the acidic emissions implies that all sources have to be addressed. There are an ongoing evaluation and development of NO x control technologies in the pulp industry. Basically air staging, selective catalytic reduction, SCR, and selective noncatalytic reduction, SNCR, have been discussed. Other NO x control options may be available as a result of ongoing research and development. As a background in the work to reduce the acid rain it has been considered necessary to have a good picture of the NO x emission from recovery boilers, and the Thermal Engineering Research Institute in Sweden have therefore sponsored this study. The intention is to give a good general view and try to explain the reasons for the large differences between boilers. Data from the 30 kraft recovery boilers which were in operation in Sweden during 1999 have been collected. Both NO x levels and specific conditions which could have an influence on the level have been included. The evaluation show a clear correlation between the nitrogen content in the liquor and the NO x level. It seams also that a long retention time in the furnace give an opportunity to reduce the amount of nitrogen oxide. For most boilers in Sweden the NO x levels are reported in mg/MJ and comparison could be done between different types of boilers. However for recovery boilers there could be a large uncertainty in the calculation which gives the amount (mg) of NO x , the definition of the heat input to be used (MJ) is either not clear. As a base for the study the measured concentration in ppm is used instead. The reported values are in the range of 30 - 100 ppm, however the majority of the boilers operate in a more narrow range 60-80 ppm. Air staging and other combustion methods could not reasonably reduce the NO x emission with more than 20% in the next decade. If the goal is higher other

  20. Improved Recovery Boiler Performance Through Control of Combustion, Sulfur, and Alkali Chemistry

    Energy Technology Data Exchange (ETDEWEB)

    Baxter, Larry L.

    2008-06-09

    This project involved the following objectives: 1. Determine black liquor drying and devolatilization elemental and total mass release rates and yields. 2. Develop a public domain physical/chemical kinetic model of black liquor drop combustion, including new information on drying and devolatilization. 3. Determine mechanisms and rates of sulfur scavenging in recover boilers. 4. Develop non-ideal, public-domain thermochemistry models for alkali salts appropriate for recovery boilers 5. Develop data and a one-dimensional model of a char bed in a recovery boiler. 6. Implement all of the above in comprehensive combustion code and validate effects on boiler performance. 7. Perform gasification modeling in support of INEL and commercial customers. The major accomplishments of this project corresponding to these objectives are as follows: 1. Original data for black liquor and biomass data demonstrate dependencies of particle reactions on particle size, liquor type, gas temperature, and gas composition. A comprehensive particle submodel and corresponding data developed during this project predicts particle drying (including both free and chemisorbed moisture), devolatilization, heterogeneous char oxidation, char-smelt reactions, and smelt oxidation. Data and model predictions agree, without adjustment of parameters, within their respective errors. The work performed under these tasks substantially exceeded the original objectives. 2. A separate model for sulfur scavenging and fume formation in a recovery boiler demonstrated strong dependence on both in-boiler mixing and chemistry. In particular, accurate fume particle size predictions, as determined from both laboratory and field measurements, depend on gas mixing effects in the boilers that lead to substantial particle agglomeration. Sulfur scavenging was quantitatively predicted while particle size required one empirical mixing factor to match data. 3. Condensed-phase thermochemistry algorithms were developed for salt

  1. Studies Concerning Water-Surface Deposits in Recovery Boilers

    Energy Technology Data Exchange (ETDEWEB)

    Strandberg, O; Arvesen, J; Dahl, L

    1971-11-15

    The Feed-water Committee of the Stiftelsen Svensk Cellulosaforskning (Foundation for Swedish Cellulose Research) has initiated research and investigations which aim to increase knowledge about water-surface deposits in boiler tubes, and the resulting risks of gas-surface corrosion in chemical recovery boilers (sulphate pulp industry). The Committee has arranged with AB Atomenergi, Studsvik, for investigations into the water-surface deposits on tubes from six Scandinavian boilers. These investigations have included direct measurements of the thermal conductivity of the deposits, and determinations of their quantity, thickness and structure have been carried out. Previous investigations have shown that gas-surface corrosion can occur at tube temperatures above 330 deg C. The measured values for the thermal conductivity of the deposits indicate that even with small quantities of deposit (c. 1 g/dm2 ) and a moderate boiler pressure (40 atm), certain types of deposit can give rise to the above-mentioned surface temperature, at which the risk of gas-surface corrosion becomes appreciable. For higher boiler pressures the risk is great even with a minimal layer of deposit. The critical deposit thickness can be as low as 0.1 mm

  2. Research on combustion of black-liquor drops

    International Nuclear Information System (INIS)

    Macek, A.

    1999-01-01

    Black liquor, the major by-product of the kraft process for production of pulp, is one of the most important industrial fuels. It is burned in recovery boilers in the form of large spray drops (mm), with the objective of simultaneous recovery of heat and chemicals (sodium and sulfur). Even though black-liquor combustion in boilers has been practised for over half a century, research efforts toward improvement of combustion efficiency and abatement of environmental emissions are much more recent. The present paper addresses a specific aspect of that research, namely, elucidation of processes which occur during combustion of black-liquor drops in boiler-gas streams. The paper (a) gives a brief description of the kraft process, (b) reviews the experimental and theoretical (modeling) research advances on combustion of kraft-liquor drops during the 1980s and 1990s, (c) re-examines the results of an earlier combustion study in which black-liquor drops were observed in free flight at temperatures near those in recovery boilers, and (d) recommends input for the modeling of in-flight combustion of kraft-liquor drops in recovery boilers. (author)

  3. Recovery of Flavonoids from Orange Press Liquor by an Integrated Membrane Process

    Directory of Open Access Journals (Sweden)

    Alfredo Cassano

    2014-08-01

    Full Text Available Orange press liquor is a by-product generated by the citrus processing industry containing huge amounts of natural phenolic compounds with recognized antioxidant activity. In this work, an integrated membrane process for the recovery of flavonoids from orange press liquors was investigated on a laboratory scale. The liquor was previously clarified by ultrafiltration (UF in selected operating conditions by using hollow fiber polysulfone membranes. Then, the clarified liquor with a total soluble solids (TSS content of 10 g·100 g−1 was pre-concentrated by nanofiltration (NF up to 32 g TSS 100 g−1 by using a polyethersulfone spiral-wound membrane. A final concentration step, up to 47 g TSS 100 g−1, was performed by using an osmotic distillation (OD apparatus equipped with polypropylene hollow fiber membranes. Suspended solids were completely removed in the UF step producing a clarified liquor containing most part of the flavonoids of the original press liquor due to the low rejection of the UF membrane towards these compounds. Flavanones and anthocyanins were highly rejected by the NF membrane, producing a permeate stream with a TSS content of 4.5 g·100 g−1. An increasing of both the flavanones and anthocyanins concentration was observed in the NF retentate by increasing the volume reduction factor (VRF. The final concentration of flavonoids by OD produced a concentrated solution of interest for nutraceutical and pharmaceutical applications.

  4. Recovery of flavonoids from orange press liquor by an integrated membrane process.

    Science.gov (United States)

    Cassano, Alfredo; Conidi, Carmela; Ruby-Figueroa, René

    2014-08-11

    Orange press liquor is a by-product generated by the citrus processing industry containing huge amounts of natural phenolic compounds with recognized antioxidant activity. In this work, an integrated membrane process for the recovery of flavonoids from orange press liquors was investigated on a laboratory scale. The liquor was previously clarified by ultrafiltration (UF) in selected operating conditions by using hollow fiber polysulfone membranes. Then, the clarified liquor with a total soluble solids (TSS) content of 10 g·100 g-1 was pre-concentrated by nanofiltration (NF) up to 32 g TSS 100 g-1 by using a polyethersulfone spiral-wound membrane. A final concentration step, up to 47 g TSS 100 g-1, was performed by using an osmotic distillation (OD) apparatus equipped with polypropylene hollow fiber membranes. Suspended solids were completely removed in the UF step producing a clarified liquor containing most part of the flavonoids of the original press liquor due to the low rejection of the UF membrane towards these compounds. Flavanones and anthocyanins were highly rejected by the NF membrane, producing a permeate stream with a TSS content of 4.5 g·100 g-1. An increasing of both the flavanones and anthocyanins concentration was observed in the NF retentate by increasing the volume reduction factor (VRF). The final concentration of flavonoids by OD produced a concentrated solution of interest for nutraceutical and pharmaceutical applications.

  5. Centrifugal washing and recovery as an improved method for obtaining lignin precipitated from South African kraft mill black liquor

    CSIR Research Space (South Africa)

    Namane, M

    2015-10-01

    Full Text Available This study describes centrifugal recovery as an improved method for collection of lignin isolated from black liquor obtained from a South African kraft mill. Precipitation of lignin was achieved by utilising 6 M sulphuric acid. Recovery...

  6. Mill Integration-Pulping, Stream Reforming and Direct Causticization for Black Liquor Recovery

    Energy Technology Data Exchange (ETDEWEB)

    Adriaan van Heiningen

    2007-06-30

    MTCI/StoneChem developed a steam reforming, fluidized bed gasification technology for biomass. DOE supported the demonstration of this technology for gasification of spent wood pulping liquor (or 'black liquor') at Georgia-Pacific's Big Island, Virginia mill. The present pre-commercial R&D project addressed the opportunities as well as identified negative aspects when the MTCI/StoneChem gasification technology is integrated in a pulp mill production facility. The opportunities arise because black liquor gasification produces sulfur (as H{sub 2}S) and sodium (as Na{sub 2}CO{sub 3}) in separate streams which may be used beneficially for improved pulp yield and properties. The negative aspect of kraft black liquor gasification is that the amount of Na{sub 2}CO{sub 3} which must be converted to NaOH (the so called causticizing requirement) is increased. This arises because sulfur is released as Na{sub 2}S during conventional kraft black liquor recovery, while during gasification the sodium associated Na{sub 2}S is partly or fully converted to Na{sub 2}CO{sub 3}. The causticizing requirement can be eliminated by including a TiO{sub 2} based cyclic process called direct causticization. In this process black liquor is gasified in the presence of (low sodium content) titanates which convert Na{sub 2}CO{sub 3} to (high sodium content) titanates. NaOH is formed when contacting the latter titanates with water, thereby eliminating the causticizing requirement entirely. The leached and low sodium titanates are returned to the gasification process. The project team comprised the University of Maine (UM), North Carolina State University (NCSU) and MTCI/ThermoChem. NCSU and MTCI are subcontractors to UM. The principal organization for the contract is UM. NCSU investigated the techno-economics of using advanced pulping techniques which fully utilize the unique cooking liquors produced by steam reforming of black liquor (Task 1). UM studied the kinetics and

  7. Life cycle greenhouse gases and non-renewable energy benefits of kraft black liquor recovery

    International Nuclear Information System (INIS)

    Gaudreault, Caroline; Malmberg, Barry; Upton, Brad; Miner, Reid

    2012-01-01

    The life cycle greenhouse gas (GHG) and fossil fuel benefits of black liquor recovery are analyzed. These benefits are due to the production of energy that can be used in the pulping process or sold, and the recovery of the pulping chemicals that would otherwise need to be produced from other resources. The fossil GHG emissions and non-renewable energy consumption of using black liquor in the kraft recovery system are approximately 90% lower than those for a comparable fossil fuel-based system. Across all scenarios, the systems relying on black liquor solids achieve a median reduction of approximately 140 kg CO 2 eq./GJ of energy produced, compared to the systems relying on fossil fuels to provide the same energy and pulping chemical production functions. The benefits attributable to the recovery of pulping chemicals vary from 44% to 75% of the total benefit. Applied to the total production of kraft pulp in the U.S., the avoided emissions are equivalent to the total Scopes 1 and 2 emissions from the entire U.S. forest products industry. These results do not depend on the accounting method for biogenic carbon (because biogenic CO 2 emissions are the same for the systems compared) and the results are valid across a range of assumptions about the displaced fossil fuel, the GHG-intensity of the electricity grid, the fossil fuels used in the lime kiln, and the level of cogeneration at pulp and paper mills. The benefits occur without affecting the amount of wood harvested or the amount of chemical pulp produced. -- Highlights: ► Black liquor, a by-product of kraft pulping, represents about half of the energy used in the paper industry. ► The greenhouse gases (GHG) benefits of black liquor recovery compared to an equivalent fossil fuel system were analyzed. ► The GHG emissions of the black liquor system are approximately 90% lower than those for the fossil fuel system. ► The benefits from the recovery of the chemicals vary from 44% to 75% of the total benefit.

  8. Recovery of Chromium from Waste Taning Liquors by Magnesium Oxide

    Directory of Open Access Journals (Sweden)

    Mahmood M. Barbooti

    2010-10-01

    Full Text Available This is a case study of AL-Za’afaraniya tanning factory, 15 km to the south of Baghdad, to spot light on simple chemical treatment of the discharged water to solve the environmental problems associated with its chromium content management. The treatment was extended to the recovery and reuse of chromium. Chromium was precipitated by the addition of magnesium oxide which also aid as a neutralizer for the acidic effluent. The laboratory treatment was carried out to find the optimum conditions. The wastewater samples were taken from the outline area of the tannery. Box-Wilson method was adopted to find useful relationships between the operating variables (temperature, mixing period and magnesium oxide dose and the pH and chromium content of effluent. The experimental data were successfully fitted to second order polynomial mathematical models for the treatment. The most favorable operating conditions for the treatment were: temperature, 30 ºC; mixing period, 50 min and magnesium oxide concentration, 3000 mg/L. On using the optimum conditions a mathematical model simulating the operation for the treatment was obtained as follows:Cr = 6.0848 – 0.001839 X11 – 0.105334 X12 – 0.041038 X13pH = 10.29086 – 0.001223 X11 – 0.140043 X12 – 0.00953 X13Experimentally Cr concentration was decreased to about (0.5 mg/L in wastewater after raising the pH value to (7.35 by adding magnesium oxide.

  9. MSWI boiler fly ashes: magnetic separation for material recovery.

    Science.gov (United States)

    De Boom, Aurore; Degrez, Marc; Hubaux, Paul; Lucion, Christian

    2011-07-01

    Nowadays, ferrous materials are usually recovered from Municipal Solid Waste Incineration (MSWI) bottom ash by magnetic separation. To our knowledge, such a physical technique has not been applied so far to other MSWI residues. This study focuses thus on the applicability of magnetic separation on boiler fly ashes (BFA). Different types of magnet are used to extract the magnetic particles. We investigate the magnetic particle composition, as well as their leaching behaviour (EN 12457-1 leaching test). The magnetic particles present higher Cr, Fe, Mn and Ni concentration than the non-magnetic (NM) fraction. Magnetic separation does not improve the leachability of the NM fraction. To approximate industrial conditions, magnetic separation is also applied to BFA mixed with water by using a pilot. BFA magnetic separation is economically evaluated. This study globally shows that it is possible to extract some magnetic particles from MSWI boiler fly ashes. However, the magnetic particles only represent from 23 to 120 g/kg of the BFA and, though they are enriched in Fe, are composed of similar elements to the raw ashes. The industrial application of magnetic separation would only be profitable if large amounts of ashes were treated (more than 15 kt/y), and the process should be ideally completed by other recovery methods or advanced treatments. Copyright © 2011 Elsevier Ltd. All rights reserved.

  10. Electrostatic precipitator performance and trace element emissions from two Kraft recovery boilers.

    Science.gov (United States)

    Lind, Terttaliisa; Hokkinen, Jouni; Jokiniemi, Jorma K; Hillamo, Risto; Makkonen, Ulla; Raukola, Antti; Rintanen, Jaakko; Saviharju, Kari

    2006-01-15

    Fine particle emissions from combustion sources have gained attention recently due to their adverse effects on human health. The emission depends on the combustion process, fuel, and particulate removal technology. Particle concentrations at Kraft recovery boiler exits are very high, and the boilers are typically equipped with electrostatic precipitators (ESP). However, little data are available on the ESP performance in recovery boilers. Particle concentrations and size distributions were determined at two modern, operating recovery boilers. In addition, we determined the fractional collection efficiency of the ESPs by simultaneous measurements at the ESP inlet and outlet and the particulate emissions of trace metals. The particle mass concentration atthe ESP inlet was 11-24 g/Nm3 at the two boilers. Particle emissions were 30-40 mg/ Nm3 at boiler A and 12-15 mg/Nm3 at boiler B. The particle size distributions had a major particle mode at around 1 microm. These fume particles contained most of the particle mass. The main components in the particles were sodium and sulfate with minor amounts of chloride, potassium, and presumably some carbonate. The ESP collection efficiency was 99.6-99.8% at boiler A and 99.9% at boiler B. The particle penetration through the ESP was below 0.6% in the entire fume particle size range of 0.3-3 microm. Trace element emissions from both boilers were well below the limit values set by EU directive for waste incineration.

  11. The use of BMED for glyphosate recovery from glyphosate neutralization liquor in view of zero discharge.

    Science.gov (United States)

    Shen, Jiangnan; Huang, Jie; Liu, Lifen; Ye, Wenyuan; Lin, Jiuyang; Van der Bruggen, Bart

    2013-09-15

    Alkaline glyphosate neutralization liquors containing a high salinity pose a severe environmental pollution problem by the pesticide industry. However, there is a high potential for glyphosate recovery due to the high concentration of glyphosate in the neutralization liquors. In the study, a three-compartment bipolar membrane electrodialysis (BMED) process was applied on pilot scale for the recovery of glyphosate and the production of base/acid with high concentration in view of zero discharge of wastewater. The experimental results demonstrate that BMED can remove 99.0% of NaCl from the feed solution and transform this fraction into HCl and NaOH with high concentration and purity. This is recycled for the hydrolysis reaction of the intermediate product generated by the means of the Mannich reaction of paraformaldehyde, glycine and dimethylphosphite catalyzed by triethylamine in the presence of HCl and reclamation of the triethylamine catalyst during the production process of glyphosate. The recovery of glyphosate in the feed solution was over 96%, which is acceptable for industrial production. The current efficiency for producing NaOH with a concentration of 2.0 mol L(-1) is above 67% and the corresponding energy consumption is 2.97 kWh kg(-1) at a current density of 60 mA cm(-2). The current efficiency increases and energy consumption decreases as the current density decreases, to 87.13% and 2.37 kWh kg(-1), respectively, at a current density of 30 mA cm(-2). Thus, BMED has a high potential for desalination of glyphosate neutralization liquor and glyphosate recovery, aiming at zero discharge and resource recycling in industrial application. Copyright © 2013 Elsevier B.V. All rights reserved.

  12. Hydrometallurgical recovery of metal values from sulfuric acid leaching liquor of spent lithium-ion batteries.

    Science.gov (United States)

    Chen, Xiangping; Chen, Yongbin; Zhou, Tao; Liu, Depei; Hu, Hang; Fan, Shaoyun

    2015-04-01

    Environmentally hazardous substances contained in spent Li-ion batteries, such as heavy metals and nocuous organics, will pose a threat to the environment and human health. On the other hand, the sustainable recycling of spent lithium-ion batteries may bring about environmental and economic benefits. In this study, a hydrometallurgical process was adopted for the comprehensive recovery of nickel, manganese, cobalt and lithium from sulfuric acid leaching liquor from waste cathode materials of spent lithium-ion batteries. First, nickel ions were selectively precipitated and recovered using dimethylglyoxime reagent. Recycled dimethylglyoxime could be re-used as precipitant for nickel and revealed similar precipitation performance compared with fresh dimethylglyoxime. Then the separation of manganese and cobalt was conducted by solvent extraction method using cobalt loaded D2EHPA. And McCabe-Thiele isotherm was employed for the prediction of the degree of separation and the number of extraction stages needed at specific experimental conditions. Finally, cobalt and lithium were sequentially precipitated and recovered as CoC2O4 ⋅ 2H2O and Li2CO3 using ammonium oxalate solution and saturated sodium carbonate solution, respectively. Recovery efficiencies could be attained as follows: 98.7% for Ni; 97.1% for Mn, 98.2% for Co and 81.0% for Li under optimized experimental conditions. This hydrometallurgical process may promise a candidate for the effective separation and recovery of metal values from the sulfuric acid leaching liquor. Copyright © 2015 Elsevier Ltd. All rights reserved.

  13. Direct recovery of boiler residue by combustion synthesis.

    Science.gov (United States)

    Nourbaghaee, Homan; Ghaderi Hamidi, Ahmad; Pourabdoli, Mahdi

    2018-04-01

    Boiler residue (BR) of thermal power plants is one of the important secondary sources for vanadium production. In this research, the aluminothermic self-propagating high-temperature synthesis (SHS) was used for recovering the transition metals of BR for the first time. The effects of extra aluminum as reducing agent and flux to aluminum ratio (CaO/Al) were studied and the efficiency of recovery and presence of impurities were measured. Aluminothermic reduction of vanadium and other metals was carried out successfully by SHS without any foreign heat source. Vanadium, iron, and nickel principally were reduced and gone into metallic master alloy as SHS product. High levels of efficiency (>80%) were achieved and the results showed that SHS has a great potential to be an industrial process for BR recovery. SHS produced two useful products. Metallic master alloy and fused glass slag that is applicable for ceramic industries. SHS can also neutralize the environmental threats of BR by a one step process. Copyright © 2018 Elsevier Ltd. All rights reserved.

  14. Factors controlling alkali salt deposition in recovery boilers. Release mechanisms

    Energy Technology Data Exchange (ETDEWEB)

    McKeough, P; Kurkela, M; Kylloenen, H; Tapola, E [VTT Energy, Espoo (Finland). Process Technology Group

    1997-10-01

    The research was part of an ongoing cooperative research effort aimed at developing a model to describe the behaviour of inorganic compounds in kraft recovery boilers. During 1996 experimental investigations of sulphur release were continued. Experiments at elevated pressures and employing larger particle sizes were performed in order to gain information about mass transfer effects. The first experiments yielding data on the rates of the sulphur-release reactions were performed. This data will be used as the basis of a drop model for sulphur release being developed in cooperation with another research group. The other part of the work during 1996 explored the possibility of using chemical equilibrium calculations to predict the release of sodium, potassium and chlorine in the recovery furnace. The approach is essentially different from that employed in earlier studies in that the effects of fume formation are taken into account. So far, the predictions of the chemical equilibrium release model have, in no way, conflicted with field measurements. (orig.)

  15. Factors controlling alkali salt deposition in recovery boilers - particle formation and deposition; Soodakattilan likaantuminen ja siihen vaikuttavien tekijoeiden hallinta - hiukkasten muodostuminen ja depositio

    Energy Technology Data Exchange (ETDEWEB)

    Kauppinen, E.I.; Mikkanen, P.; Ylaetalo, S. [VTT Chemistry, Espoo (Finland); Jokiniemi, J.K.; Lyyraenen, J.; Pyykoenen, J.; Saastamoinen, J. [VTT Energy, Espoo (Finland)

    1996-12-01

    In this project, the aim was to find out those critical factors that control the deposit formation in the recovery boilers. We focus on the particle formation, growth and deposition as well as the single black liquor particle combustion behaviour. The final goal is the development of the predictive model to be used to describe deposit growth and subsequent behaviour as well as the dependence of deposition on black liquor characteristics and boiler operation conditions. During year 1995 an experimental study on the aerosol particle formation within the recovery boiler furnace and a sensitivity study with the Aerosol Behaviour in Combustion (ABC) code were carried out. The experimental study confirmed the fact that the particles are already formed in the recovery boiler furnace. The particle formation is initiated in the boundary layer of the burning droplet or smelt bed, where metals are vaporised and oxidised to form tiny seed particles. Trace amounts of metals were measured in all particle sizes and the sensitivity study with the ABC model gave further evidence of the seed formation was necessary primary step in the particle formation. At the furnace outlet the sintration ratio and the sulfation ratio of the particles were dependent on the furnace temperature and the residence time in the furnace. At ESP inlet three types of particles were observed (1) fine particles with the major mass mode at about 1-2 {mu}m, (2) large agglomerates in sizes larger than 8 {mu}m, and (3) spherical particles about 2-4 {mu}m in size. The fine particles were formed from vapours and the large agglomerates were formed from fine particles agglomerated on heat exchanger surfaces and re-entrained back to flue gas flow. The large agglomerates also contain vapours that have directly condensed to surfaces. The large spherical particles contain silicon and pass the process almost unchanged. (Abstract Truncated)

  16. New configurations of a heat recovery absorption heat pump integrated with a natural gas boiler for boiler efficiency improvement

    International Nuclear Information System (INIS)

    Qu, Ming; Abdelaziz, Omar; Yin, Hongxi

    2014-01-01

    Highlights: • Thermal and heat transfer models of absorption heat pumps driven by exhaust gas, hot water, or natural gas. • Natural gas boiler combustion model. • Heat exchanger for condensing. • Experimental data of a hot water absorption heat pump. • Economic assessment of heat recovery absorption heat pump for improving natural gas boilers. - Abstract: Conventional natural gas-fired boilers exhaust flue gas direct to the atmosphere at 150–200 °C, which, at such temperatures, contains large amount of energy and results in relatively low thermal efficiency ranging from 70% to 80%. Although condensing boilers for recovering the heat in the flue gas have been developed over the past 40 years, their present market share is still less than 25%. The major reason for this relatively slow acceptance is the limited improvement in the thermal efficiency of condensing boilers. In the condensing boiler, the temperature of the hot water return at the range of 50–60 °C, which is used to cool the flue gas, is very close to the dew point of the water vapor in the flue gas. Therefore, the latent heat, the majority of the waste heat in the flue gas, which is contained in the water vapor, cannot be recovered. This paper presents a new approach to improve boiler thermal efficiency by integrating absorption heat pumps with natural gas boilers for waste heat recovery (HRAHP). Three configurations of HRAHPs are introduced and discussed. The three configurations are modeled in detail to illustrate the significant thermal efficiency improvement they attain. Further, for conceptual proof and validation, an existing hot water-driven absorption chiller is operated as a heat pump at operating conditions similar to one of the devised configurations. An overall system performance and economic analysis are provided for decision-making and as evidence of the potential benefits. These three configurations of HRAHP provide a pathway to achieving realistic high-efficiency natural

  17. Drop formation of black liquor spraying; Mustalipeaen pisaroituminen

    Energy Technology Data Exchange (ETDEWEB)

    Fogelholm, C J; Kankkunen, A; Nieminen, K; Laine, J; Miikkulainen, P [Helsinki Univ. of Technology, Otaniemi (Finland): Lab. of Energy Technology and Environmental Protection

    1997-10-01

    Black liquor is a spent liquor of the pulp and paper industry. It is burned in kraft recovery boilers for chemical and energy recovery. The high dry solids content and viscosity of black liquor require a high spraying temperature. This affects the performance of the boiler. Kraft recovery boiler deposit formation, emissions and chemical recovery are strongly affected by the drop size and the velocity of the black liquor spray formed by a splashplate nozzle. The sheet breakup mechanism is studied with a system based on a video and image-analysis. The drop size of mill-scale nozzles was measured also with an image-analysis-system. Measurements were carried out in a spray test chamber. The sheet breakup mechanism and drop size tests were carried out both below and over the boiling point of black liquor. Special attention was paid to the effect of flashing on drop formation. Temperature increase normally decreases drop size. In the temperature where the wavy-sheet disintegration changes to perforated-sheet disintegration the drop size increases. Spray velocity rises when the temperature is increased above the boiling point. (orig.)

  18. Composite tube cracking in kraft recovery boilers: A state-of-the-art review

    Energy Technology Data Exchange (ETDEWEB)

    Singbeil, D.L.; Prescott, R. [Pulp and Paper Research Inst. of Canada, Vancouver, British Columbia (Canada); Keiser, J.R.; Swindeman, R.W. [Oak Ridge National Lab., TN (United States)

    1997-07-01

    Beginning in the mid-1960s, increasing energy costs in Finland and Sweden made energy recovery more critical to the cost-effective operation of a kraft pulp mill. Boiler designers responded to this need by raising the steam operating pressure, but almost immediately the wall tubes in these new boilers began to corrode rapidly. Test panels installed in the walls of the most severely corroding boiler identified austenitic stainless steel as sufficiently resistant to the new corrosive conditions, and discussions with Sandvik AB, a Swedish tube manufacturer, led to the suggestion that coextruded tubes be used for water wall service in kraft recovery boilers. Replacement of carbon steel by coextruded tubes has solved most of the corrosion problems experienced by carbon steel wall tubes, however, these tubes have not been problem-free. Beginning in early 1995, a multidisciplinary research program funded by the US Department of Energy was established to investigate the cause of cracking in coextruded tubes and to develop improved materials for use in water walls and floors of kraft recovery boilers. One portion of that program, a state-of-the-art review of public- and private-domain documents related to coextruded tube cracking in kraft recovery boilers is reported here. Sources of information that were consulted for this review include the following: tube manufacturers, boiler manufacturers, public-domain literature, companies operating kraft recovery boilers, consultants and failure analysis laboratories, and failure analyses conducted specifically for this project. Much of the information contained in this report involves cracking problems experienced in recovery boiler floors and those aspects of spout and air-port-opening cracking not readily attributable to thermal fatigue. 61 refs.

  19. Hydrometallurgical recovery of metal values from sulfuric acid leaching liquor of spent lithium-ion batteries

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Xiangping; Chen, Yongbin; Zhou, Tao, E-mail: zhoutao@csu.edu.cn; Liu, Depei; Hu, Hang; Fan, Shaoyun

    2015-04-15

    Highlights: • Selective precipitation and solvent extraction were adopted. • Nickel, cobalt and lithium were selectively precipitated. • Co-D2EHPA was employed as high-efficiency extraction reagent for manganese. • High recovery percentages could be achieved for all metal values. - Abstract: Environmentally hazardous substances contained in spent Li-ion batteries, such as heavy metals and nocuous organics, will pose a threat to the environment and human health. On the other hand, the sustainable recycling of spent lithium-ion batteries may bring about environmental and economic benefits. In this study, a hydrometallurgical process was adopted for the comprehensive recovery of nickel, manganese, cobalt and lithium from sulfuric acid leaching liquor from waste cathode materials of spent lithium-ion batteries. First, nickel ions were selectively precipitated and recovered using dimethylglyoxime reagent. Recycled dimethylglyoxime could be re-used as precipitant for nickel and revealed similar precipitation performance compared with fresh dimethylglyoxime. Then the separation of manganese and cobalt was conducted by solvent extraction method using cobalt loaded D2EHPA. And McCabe–Thiele isotherm was employed for the prediction of the degree of separation and the number of extraction stages needed at specific experimental conditions. Finally, cobalt and lithium were sequentially precipitated and recovered as CoC{sub 2}O{sub 4}⋅2H{sub 2}O and Li{sub 2}CO{sub 3} using ammonium oxalate solution and saturated sodium carbonate solution, respectively. Recovery efficiencies could be attained as follows: 98.7% for Ni; 97.1% for Mn, 98.2% for Co and 81.0% for Li under optimized experimental conditions. This hydrometallurgical process may promise a candidate for the effective separation and recovery of metal values from the sulfuric acid leaching liquor.

  20. Hydrometallurgical recovery of metal values from sulfuric acid leaching liquor of spent lithium-ion batteries

    International Nuclear Information System (INIS)

    Chen, Xiangping; Chen, Yongbin; Zhou, Tao; Liu, Depei; Hu, Hang; Fan, Shaoyun

    2015-01-01

    Highlights: • Selective precipitation and solvent extraction were adopted. • Nickel, cobalt and lithium were selectively precipitated. • Co-D2EHPA was employed as high-efficiency extraction reagent for manganese. • High recovery percentages could be achieved for all metal values. - Abstract: Environmentally hazardous substances contained in spent Li-ion batteries, such as heavy metals and nocuous organics, will pose a threat to the environment and human health. On the other hand, the sustainable recycling of spent lithium-ion batteries may bring about environmental and economic benefits. In this study, a hydrometallurgical process was adopted for the comprehensive recovery of nickel, manganese, cobalt and lithium from sulfuric acid leaching liquor from waste cathode materials of spent lithium-ion batteries. First, nickel ions were selectively precipitated and recovered using dimethylglyoxime reagent. Recycled dimethylglyoxime could be re-used as precipitant for nickel and revealed similar precipitation performance compared with fresh dimethylglyoxime. Then the separation of manganese and cobalt was conducted by solvent extraction method using cobalt loaded D2EHPA. And McCabe–Thiele isotherm was employed for the prediction of the degree of separation and the number of extraction stages needed at specific experimental conditions. Finally, cobalt and lithium were sequentially precipitated and recovered as CoC 2 O 4 ⋅2H 2 O and Li 2 CO 3 using ammonium oxalate solution and saturated sodium carbonate solution, respectively. Recovery efficiencies could be attained as follows: 98.7% for Ni; 97.1% for Mn, 98.2% for Co and 81.0% for Li under optimized experimental conditions. This hydrometallurgical process may promise a candidate for the effective separation and recovery of metal values from the sulfuric acid leaching liquor

  1. Questions about the reliability of recovery boilers of steel smelting units

    Energy Technology Data Exchange (ETDEWEB)

    Sazykin, Yu K; Mukhametzyanov, N K

    1979-01-01

    Because the main reason for failure of recovery boilers is contamination of the heating surfaces, the operational conditions of individual elements of boiler units, equipped with vibrational and pulsed cleaning are analyzed and the reliability of the cleaning systems in use today is evaluated. The recovery boilers from open hearth furnaces and two bath steel smelting units from the Magnitogorsk Metallurgic Combine were selected as the subjects of the study. It is established that the boiler heating surface cleaning system has a quite large number of failures. The vibrational cleaning readiness factor is rated at 0.9323 and that of the pulsed cleaning system, 0.9698. For the KU-100 recovery boilers with a mean productivity of 18-20 t/h, the losses caused by failures during operation with vibration and pulsed cleaning were 3,200 and 1,700 rubles per year, respectively. With reconstruction of the boilers, which is associated with an increase in their reliability, the vibration cleaning of the heating surface was replaced by pulsed cleaning.

  2. Exergy analysis and evolutionary optimization of boiler blowdown heat recovery in steam power plants

    International Nuclear Information System (INIS)

    Vandani, Amin Mohammadi Khoshkar; Bidi, Mokhtar; Ahmadi, Fatemeh

    2015-01-01

    Highlights: • Heat recovery of boiler blow downed water using a flash tank is modeled. • Exergy destruction of each component is calculated. • Exergy efficiency of the whole system is optimized using GA and PSO algorithms. • Utilizing the flash tank increases the net power and efficiency of the system. - Abstract: In this study, energy and exergy analyses of boiler blowdown heat recovery are performed. To evaluate the effect of heat recovery on the system performance, a steam power plant in Iran is selected and the results of implementation of heat recovery system on the power plant are investigated. Also two different optimization algorithms including GA and PSO are established to increase the plant efficiency. The decision variables are extraction pressure from steam turbine and temperature and pressure of boiler outlet stream. The results indicate that using blowdown recovery technique, the net generated power increases 0.72%. Also energy and exergy efficiency of the system increase by 0.23 and 0.22, respectively. The optimization results show that temperature and pressure of boiler outlet stream have a higher effect on the exergy efficiency of the system in respect to the other decision variables. Using optimization methods, exergy efficiency of the system reaches to 30.66% which shows a 1.86% augmentation with regard to the situation when a flash tank is implemented.

  3. Sensing system for detection and control of deposition on pendant tubes in recovery and power boilers

    Science.gov (United States)

    Kychakoff, George [Maple Valley, WA; Afromowitz, Martin A [Mercer Island, WA; Hogle, Richard E [Olympia, WA

    2008-10-14

    A system for detection and control of deposition on pendant tubes in recovery and power boilers includes one or more deposit monitoring sensors operating in infrared regions of about 4 or 8.7 microns and directly producing images of the interior of the boiler, or producing feeding signals to a data processing system for information to enable a distributed control system by which the boilers are operated to operate said boilers more efficiently. The data processing system includes an image pre-processing circuit in which a 2-D image formed by the video data input is captured, and includes a low pass filter for performing noise filtering of said video input. It also includes an image compensation system for array compensation to correct for pixel variation and dead cells, etc., and for correcting geometric distortion. An image segmentation module receives a cleaned image from the image pre-processing circuit for separating the image of the recovery boiler interior into background, pendant tubes, and deposition. It also accomplishes thresholding/clustering on gray scale/texture and makes morphological transforms to smooth regions, and identifies regions by connected components. An image-understanding unit receives a segmented image sent from the image segmentation module and matches derived regions to a 3-D model of said boiler. It derives a 3-D structure the deposition on pendant tubes in the boiler and provides the information about deposits to the plant distributed control system for more efficient operation of the plant pendant tube cleaning and operating systems.

  4. Evaluation of trigeneration system using microturbine, ammonia-water absorption chiller, and a heat recovery boiler

    Energy Technology Data Exchange (ETDEWEB)

    Preter, Felipe C.; Rocha, Marcelo S.; Simoes-Moreira, Jose Roberto [SISEA - Alternative Energy Systems Lab. Dept. of Mechanical Engineering. University of Sao Paulo (EP/USP), SP (Brazil)], e-mails: felipe.preter@poli.usp.br, msrocha@poli.usp.br, jrsimoes@usp.br; Andreos, Ronaldo [COMGAS - Companhia de Gas de Sao Paulo, SP (Brazil)], e-mail: randreos@comgas.com.br

    2010-07-01

    In this work, a CCHP or tri generation system has been projected, mounted, and tested in laboratory, combining a microturbine for power generation, a heat recovery boiler for hot water production, and an ammonia water absorption chiller for chilled water production. The project was motivated by the large practical applications of this kind of energy recovery system in commerce, and industry, and, in general, more than 85% of the energy source is used as power, hot water, and cold water. In the first part, the trigeneration system theoretical model is detailed, and in the second part, experimental results are presented for different operation conditions. (author)

  5. Soot blowing methods and soot steam consumption in Swedish recovery boilers; Sotningsmetoder och sotaangfoerbrukning i svenska sodapannor

    Energy Technology Data Exchange (ETDEWEB)

    Svedin, Kristoffer; Wallin, Erik; Ahlroth, Mikael

    2008-09-15

    The aim with the report was to put together a description of the current state of the sootblowing systems at Swedish recovery boilers, and to explain differences in cleanability and sootblowing efficiency. In chapter 4 a summary of new techniques and alternative soot blowing methods is found. The report is intended for persons working in the pulp industry. To facilitate the benchmarking the recovery boilers have been divided into two groups. Group A comprises recovery boilers which only have one stop per year and the remaining recovery boilers with more than one stop are classified into group B. The following conclusions, based on the recovery boiler design specifications, are of importance to achieve high boiler availability: Low furnace load; High recovery boiler, wide furnace bottom area; Modern air ports; Small or no correlation between cross pitch division in heat surfaces and cleanability could be seen. The expectation was to identify such a relation. However there are doubts on the correctness in reported data. The amount of chlorine and potassium is assumed to affect the cleanability for a few recovery boilers, but for the majority the amounts are low and most likely do not impact the operation. Because of the large impact of the recovery boilers design data (furnace area, load etc.) on the sootblowing, it has been hard to identify the relation cleanability contra sootblowing system. The relations that could be seen are: No distinction between normally designed nozzles and 'high efficiency' nozzles could be identified. The operational conditions for the different models differ a lot and the effect of nozzle type could not be distinguished. Only a minority of the soot blowing sequences are known from the study. In the recovery boilers with problematic areas improvements can be made in the soot blowing sequence. Four recovery boilers are using intelligent soot blowing of some kind. Two of these boilers have low availability and the other two have

  6. Thermal performance analysis of Brayton cycle with waste heat recovery boiler for diesel engines of offshore oil production facilities

    International Nuclear Information System (INIS)

    Liu, Xianglong; Gong, Guangcai; Wu, Yi; Li, Hangxin

    2016-01-01

    Highlights: • Comparison of Brayton cycle with WHRB adopted in diesel engines with and without fans by thermal performance. • Waste heat recovery technology for FPSO. • The thermoeconomic analysis for the heat recovery for FPSO. - Abstract: This paper presents the theoretical analysis and on-site testing on the thermal performance of the waste heat recovery system for offshore oil production facilities, including the components of diesel engines, thermal boilers and waste heat boilers. We use the ideal air standard Brayton cycle to analyse the thermal performance. In comparison with the traditional design, the fans at the engine outlet of the waste heat recovery boiler is removed due to the limited space of the offshore platform. The cases with fan and without fan are compared in terms of thermal dynamics performance, energy efficiency and thermo-economic index of the system. The results show that the application of the WHRB increases the energy efficiency of the whole system, but increases the flow resistance in the duct. It is proved that as the waste heat recovery boiler takes the place of the thermal boiler, the energy efficiency of whole system without fan is slightly reduced but heat recovery efficiency is improved. This research provides an important guidance to improve the waste heat recovery for offshore oil production facilities.

  7. Evaluation of a flue gas driven open absorption system for heat and water recovery from fossil fuel boilers

    International Nuclear Information System (INIS)

    Wang, Zhenying; Zhang, Xiaoyue; Li, Zhen

    2016-01-01

    Highlights: • Flue gas driven open absorption system that efficiently recovers total heat. • Efficient heat and water recovery for various kinds of fossil fuel boilers. • Heat and water recovery efficiencies increase with moisture content of flue gas. • Temperature requirements for district heat supply and domestic hot water were met. • Experimental system surpasses conventional condensing system in total heat recovery. - Abstract: This paper presents an open absorption system for total heat recovery from fossil fuel boilers using the high temperature flue gas as the regeneration heat source. In this system, liquid desiccant serves as the recycling medium, which absorbs waste heat and moisture contained in the low temperature flue gas in the packed tower and then regenerates in the regenerator by the high temperature flue gas. Water vapor generated in the regenerator gets condensed after releasing heat to the heating water system and the condensing water also gets recycled. The return water collects heat from the solution water heat exchanger, the flue gas water heat exchanger and the condenser respectively and is then used for district heating. Driven by the vapor pressure difference between high humidity flue gas and the liquid desiccant, the heat recovery efficiency of the system is not limited by the dew point of the flue gas, enabling a warmer water to be heated up than the conventional condensing boiler. The performance of this system was analyzed theoretically and experimentally and the results showed that the system operated well for both district heat supply and domestic hot water supply. The system efficiency increased with the moisture content of flue gas and the total heat recovery was about 8.5%, 17.2%, 21.2%, and 9.2% higher than the conventional condensing system in the case of coal fired boiler, fuel oil boiler, natural gas boiler, and coke oven gas boiler, respectively.

  8. Recovery of thorium and uranium from monazite processing Liquor produced by INB/Caldas, M G, by solvent extraction

    International Nuclear Information System (INIS)

    Amaral, Janubia Cristina Braganca da Silva

    2006-01-01

    This work describes the study of thorium and uranium recovery from sulfuric liquor generated in chemical monazite treatment by solvent extraction technique. The sulfuric liquor was produced by Industries Nuclear of Brazil - INB, Caldas - Minas Gerais State. The study was carried out in two steps: in the first the process variable were investigated through discontinuous experiments; in the second, the parameters were optimized by continuous solvent extraction experiments. The influence of the following process variables was investigated: type and concentration of extracting agents, contact time between phases and aqueous/organic volumetric ratio. Extractants used in this study included: Primene J M-T, Primene 81-R, Alamine 336 and Aliquat 336. Thorium and uranium were simultaneously extracted by a mixture of Primene J M-T and Alamine 336, into Exxsol D-100. The stripping was carried out by hydrochloric acid (HCl) 2.0 mol/L. The study was carried out at room temperature. After selected the best process conditions, two continuous experiments of extraction and stripping were carried out. In the first experiment a mixture of 0.15 mol/L Primene J M-T and 0.05 mol/L Alamine 336 were used. The second experiment was carried out using 0.15 mol/L Primene J M-T and 0.15 mol/L Alamine 336. Four extraction stages and five stripping stages were used in both experiments. The first experiment showed a ThU 2 and U 3 O 8 content in loaded strip solution of 34.3 g/L and 1.49 g/L respectively and 0.10 g/L Th) 2 and 0.05 g/L U 3 O 8 in the raffinate. In the second experiment a loaded strip solution with 29.3 g/L ThO 2 and 0.94 g/L U 3 O 8 was obtained. In this experiment, the metals content in raffinate was less than 0.001 g/L, indicating a thorium recovery over 99.9% and uranium recovery of 99.4%. (author)

  9. New black liquor combustion characteristics III; Mustalipeaen uudet poltto-ominaisuudet III

    Energy Technology Data Exchange (ETDEWEB)

    Hupa, M.; Forssen, M.; Backman, R.; Enestam, S.; Lauren, T.; Skrifvars, B.J. [Aabo Akademi, Turku (Finland). Combustion Chemistry Research Group

    1997-10-01

    The main purposes in this work is to: 1. Compare black liquor combustion characterization results to recovery boiler experiences. 2. Study the mechanisms of sodium release in black liquor combustion In the first part results from black liquor combustion characterization tests developed by Aabo Akademi University will be compared to experiences at four Finnish kraft recovery boilers. When comparing the laboratory data to the compiled field data emphasis will be put on the behavior of the black liquor during burning, the release of sodium and potassium, the melting behavior of the deposits and the NO and SO{sub 2} emissions. The main purpose in the second part of the work is to study the release mechanisms of sodium from black liquor char during combustion. Sodium is mainly released from the char by the mechanism where the molten sodiumcarbonate reacts with the char carbon. The study is divided into four subtasks and is performed mainly by conducting experiments in laboratory scale devices: (1) Sodium release during char reactions is studied for different liquors by analyzing the amount of sodium remaining in char after different holding times in a hot inert atmosphere. (2) A DTA/TGA apparatus is used to study in isothermal conditions the char reactions on prepyrolyzed char. (3) The effect of the form of sodium on the sodium release during char reactions. Black liquors added with different sodium salts (Na{sub 2}CO{sub 3}, Na{sub 2}SO{sub 4}, Na{sub 2}S{sub 2}O{sub 2}, Na{sub 2}S sekae NaCl) are used in experiments as in subtask 1. (4) Sodium release during combustion (2-5 % O{sub 2}) of single black liquor particles

  10. Techno-economic analysis and optimization of the heat recovery of utility boiler flue gas

    International Nuclear Information System (INIS)

    Xu, Gang; Huang, Shengwei; Yang, Yongping; Wu, Ying; Zhang, Kai; Xu, Cheng

    2013-01-01

    Highlights: • Four typical flue gas heat recovery schemes are quantitatively analyzed. • The analysis considers thermodynamic, heat transfer and hydrodynamics factors. • Techno-economic analysis and optimization design are carried out. • High-stage steam substitute scheme obtains better energy-saving effect. • Large heat transfer area and high flue gas resistances weaken overall performance. - Abstract: Coal-fired power plants in China consume nearly half of available coals, and the resulting CO 2 emissions cover over 40% of total national emissions. Therefore, reducing the energy expenditure of coal-fired power plants is of great significance to China’s energy security and greenhouse gas reduction programs. For coal-fired power plants, the temperature of a boiler’s exhaust gas reaches 120–150 °C or even higher. The thermal energy of boiler’s exhaust accounts for approximately 3–8% of the total energy of fuel input. Given these factors, we conducted a techno-economic analysis and optimization design of the heat recovery system using boiler exhaust gas. This research is conformed to the principles of thermodynamic, heat transfer, and hydrodynamics. Based on the data from an existing 1000 MW typical power generation unit in China, four typical flue gas heat recovery schemes are quantitatively analyzed from the thermodynamics perspective. The impacts of flue gas heat recovery on net work output and standard coal consumption rate of various schemes are performed. Furthermore, the transfer area of heat recovery exchanger and the draft fan work increment due to the flue gas pressure drop are analyzed. Finally, a techno-economic analysis of the heat recovery schemes is conducted, and some recommendations on optimization design parameters are proposed, with full consideration of various factors such as the decrease on fuel cost due to energy conservation as well as the investment cost of heat recovery retrofitting. The results revealed that, high

  11. Effective removal of hazardous trace metals from recovery boiler fly ashes.

    Science.gov (United States)

    Kinnarinen, Teemu; Golmaei, Mohammad; Jernström, Eeva; Häkkinen, Antti

    2018-02-15

    The objective of this study is to introduce a treatment sequence enabling straightforward and effective recovery of hazardous trace elements from recovery boiler fly ash (RBFA) by a novel method, and to demonstrate the subsequent removal of Cl and K with the existing crystallization technology. The treatment sequence comprises two stages: dissolution of most other RBFA components than the hazardous trace elements in water in Step 1 of the treatment, and crystallization of the process chemicals in Step 2. Solid-liquid separation has an important role in the treatment, due to the need to separate first the small solid residue containing the trace elements, and to separate the valuable crystals, containing Na and S, from the liquid rich in Cl and K. According to the results, nearly complete recovery of cadmium, lead and zinc can be reached even without pH adjustment. Some other metals, such as Mg and Mn, are removed together with the hazardous metals. Regarding the removal of Cl and K from the process, in this non-optimized case the removal efficiency was satisfactory: 60-70% for K when 80% of sodium was recovered, and close to 70% for Cl when 80% of sulfate was recovered. Copyright © 2017 Elsevier B.V. All rights reserved.

  12. A new conceptual cold-end design of boilers for coal-fired power plants with waste heat recovery

    International Nuclear Information System (INIS)

    Yang, Yongping; Xu, Cheng; Xu, Gang; Han, Yu; Fang, Yaxiong; Zhang, Dongke

    2015-01-01

    Highlights: • A new cold-end design of boilers for CFPPs with waste heat recovery is proposed. • Thermodynamic and economic analyses are quantitatively conducted. • Higher energy efficiency improvement and greater economic benefits are achieved. • Lower exergy destruction and better matched energy level are obtained. - Abstract: After conducting an in-depth analysis of the conventional boiler cold-end design for waste heat recovery, this work proposed a new conceptual boiler cold-end design integrated with the steam cycle in a 1000 MW CFPP, in which the preheating of air was divided into high-temperature air preheater (HTAP), main air preheater (MAP) and low-temperature air preheater (LTAP). The HTAP and an economizer were installed in separate flue ducts, and the low temperature economizer (LTE) was situated between the MAP and the LTAP in the main flue duct to heat the condensed water. In the proposed boiler cold-end design, the flue gas waste heat was not only used to heat condensed water, but also to further preheat the combustion air. The air temperature at the air-preheater outlet increases and part of the steam bleeds with high exergy can be saved, resulting in greater energy-savings and better economics. Results showed that, for a typical 1000 MW CFPP in China, using the proposed boiler cold-end design for waste heat recovery could produce 13.3 MW e additional net power output with a heat rate reduction of approximately 112.0 kJ/kW h and could yield a net benefit of up to $85.8 M per year, which is much greater than those of the conventional cases. Exergy destruction is also reduced from 49.9 MW th in the conventional boiler cold-end design to 39.6 MW th in the proposed design

  13. A review on methods of recovery of acid(s) from spent pickle liquor of steel industry.

    Science.gov (United States)

    Ghare, N Y; Wani, K S; Patil, V S

    2013-04-01

    Pickling is the process of removal of oxide layer and rust formed on metal surface. It also removes sand and corrosion products from the surface of metal. Acids such as sulfuric acid, hydrochloric acid are used for pickling. Hydrofluoric acid-Nitric acid mixture is used for stainless steel pickling. Pickling solutions are spent when acid concentration in pickling solutions decreases by 75-85%, which also has metal content up to 150-250 g/ dm3. Spent pickling liquor (SPL) should be dumped because the efficiency of pickling decreases with increasing content of dissolved metal in the bath. The SPL content depends on the plant of origin and the pickling method applied there. SPL from steel pickling in hot-dip galvanizing plants contains zinc(II), iron, traces of lead, chromium. and other heavy metals (max. 500 mg/dm3) and hydrochloric acid. Zinc(II) passes tothe spent solution after dissolution of this metal from zinc(II)-covered racks, chains and baskets used for transportation of galvanized elements. Unevenly covered zinc layers are usually removed in another pickling bath. Due to this, zinc(II) concentration increases even up to 110 g/dm3, while iron content may reach or exceed even 80 g/dm3 in the same solution. This review presents an overview on different aspects of generation and treatment of SPL with recourse to recovery of acid for recycling. Different processes are described in this review and higher weightage is given to membrane processes.

  14. REFRACTORY FOR BLACK LIQUOR GASIFIERS

    Energy Technology Data Exchange (ETDEWEB)

    William L. Headrick Jr; Musa Karakus; Jun Wei

    2005-03-01

    The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective

  15. Recovery Act: Oxy-Combustion Technology Development for Industrial-Scale Boiler Applications

    Energy Technology Data Exchange (ETDEWEB)

    Levasseur, Armand

    2014-01-01

    This Topical Report outlines guidelines and key considerations for design and operation of pulverized coal-fired boilers for oxy-combustion. The scope addressed includes only the boiler island, not the entire oxy-fired CO{sub 2} capture plant. These guidelines are primarily developed for tangential-fired boilers and focus on designs capable of dual air and oxy-fired operation. The guidelines and considerations discussed are applicable to both new units and existing boiler retrofits. These guidelines are largely based on the findings from the extensive 15 MW{sub th} pilot testing and design efforts conducted under this project. A summary level description is provided for each major aspect of boiler design impacted by oxy-combustion, and key considerations are discussed for broader application to different utility and industrial designs. Guidelines address the boiler system arrangement, firing system, boiler thermal design, ducting, materials, control system, and other key systems.

  16. Fate of recovery boiler smelt nitrogen in the recovery cycle; Soodakattilan sulan typpiyhdisteitten kaeyttaeytyminen talteenottoprosessissa

    Energy Technology Data Exchange (ETDEWEB)

    Hupa, M.; Forssen, M.; Backman, R.; Ek, P.; Hulden, S.G.; Kilpinen, P.; Kymaelaeinen, M.; Malm, H. [Aabo Akademi, Turku (Finland). Combustion Chemistry Research Group

    1997-10-01

    The purpose of this project is to study the fate of the nitrogen bound in the inorganic smelt after it enters the dissolving tank. Of special interest is to find in what form this nitrogen can be found further down in the recovery process and especially in what form it can be removed from the process. The aim is to clarify if the nitrogen can be a potential problem in the process or if it can become a potential emission. The work is divided into choosing methods for the analysis of different nitrogen species, collection and analysis of mill samples, laboratory studies and theoretical studies on nitrogen chemistry in alkaline solutions and reporting

  17. Uranium extraction from ores with lemon juice I,b-uranium recovery from pregnant lemon juice liquors obtained by attacking phosphate ores and suggested flowsheet

    International Nuclear Information System (INIS)

    EL-Sayed, M.H.

    1992-01-01

    In order to recover uranium from the pregnant liquors obtained by attacking safaga phosphate and qatrani phosphatic sandstone ore materials with lemon juice, methylation for acidic fraction-salt separation has been carried out. Afterwards, separation of uranium from the associated calcium (mainly present in lemon juice liquors as citrate) has been performed by making-use of the wide difference in their water solubility. The solutions containing the separated uranium were then subjected to evaporation till dryness whereby the precipitated uranyl citrate was calcined at 500 degree C to obtain the yellow orange oxide powder (U o 3 ). On the basis of one ton ore treatment, a flowsheet for uranium recovery from the two ore materials has been suggested

  18. Uranium extraction from ores with lemon juice; II,b. uranium recovery from pregnant lemon juice liquors obtained by attacking phosphate ore and suggested flowsheet

    International Nuclear Information System (INIS)

    Hussein, E.M.

    1997-01-01

    In order to recover uranium from the pregnant liquors obtained by attacking Safaga phosphate and Qatrani phosphatic sandstone ore materials with lemon juice, methylation for acidic fraction-salt separation has been carried out. Afterwards, separation of uranium from the associated calcium (mainly present in lemon juice liquors as citrate) has been performed by making-use of the wide difference in their water solubility. The solutions containing the separated uranium were then subjected to evaporation till dryness whereby the precipitated uranyl citrate was calcined at 500 degree C to obtain the yellow orange oxide powder (UO 3 ). On the basis of one ton ore treatment, a flowsheet for uranium recovery from the two ore materials has been suggested

  19. Refractory for Black Liquor Gasifiers

    Energy Technology Data Exchange (ETDEWEB)

    William L. Headrick Jr; Musa Karakus; Xiaoting Laing

    2005-10-01

    The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective

  20. Process for the separation and recovery of palladium and platinum from spent automobile catalyst leach liquor using LIX 84I and Alamine 336.

    Science.gov (United States)

    Reddy, B Ramachandra; Raju, B; Lee, Jin Young; Park, Hyung Kyu

    2010-08-15

    Spent catalysts from automobile industry contain environmentally critical and economically valuable metals such as Pt, Pd, Fe, Ni, Mn, and Cr. In this paper, we present a process for the selective separation and complete recovery of palladium (Pd) and platinum (Pt) from hydrochloric acid leach liquors of spent automobile catalyst employing solvent extraction method. Typical composition of leach liquor used for the present study contains (mg/L): Pd-150, Pt-550, Mn-500, Ni-1000, Fe-1500, Cr-100 and 3 M HCl. Selective separation of Pd from the leach liquor is achieved with 0.5 vol.% LIX 84I (2-hydroxy-5-nonylacetophenone oxime in a mixture with a high flash point hydrocarbon diluent) in kerosene at an aqueous to organic (A/O) ratio of 3 in 2 stages, with an enrichment factor of three. Quantitative stripping of Pd from loaded organic is achieved with 0.5 M thiourea and 1 M HCl. Co-extraction of Fe and Pt with 5 vol.% Alamine 336 (tertiary amine of mixed tri-octyl/decyl amine) in kerosene followed by selective scrubbing of Fe with dilute HCl and complete stripping of Pt from loaded organic was proposed with 0.5 M thiourea and 0.1 M HCl. Purity of Pd and Pt strip solutions are 99.7%. Finally, the present process can solve environmental related issues and at the same time recover valuable metals in pure form. Copyright 2010 Elsevier B.V. All rights reserved.

  1. An analysis of the thermodynamic efficiency for exhaust gas recirculation-condensed water recirculation-waste heat recovery condensing boilers (EGR-CWR-WHR CB)

    International Nuclear Information System (INIS)

    Lee, Chang-Eon; Yu, Byeonghun; Lee, Seungro

    2015-01-01

    This study presents fundamental research on the development of a new boiler that is expected to have a higher efficiency and lower emissions than existing boilers. The thermodynamic efficiency of exhaust gas recirculation-condensed water recirculation-waste heat recovery condensing boilers (EGR-CWR-WHR CB) was calculated using thermodynamic analysis and was compared with other boilers. The results show the possibility of obtaining a high efficiency when the temperature of the exhaust gas is controlled within 50–60 °C because water in the exhaust gas is condensed within this temperature range. In addition, the enthalpy emitted by the exhaust gas for the new boiler is smaller because the amount of condensed water is increased by the high dew-point temperature and the low exhaust gas temperature. Thus, the new boiler can obtain a higher efficiency than can older boilers. The efficiency of the EGR-CWR-WHR CB proposed in this study is 93.91%, which is 7.04% higher than that of existing CB that is currently used frequently. - Highlights: • The study presents the development of a new boiler expected to have a high efficiency. • Thermodynamic efficiency of EGR-CWR-WHR condensing boiler was calculated. • Efficiency of EGR-CWR-WHR CB is 93.91%, which is 7.04% higher than existing CB

  2. Recovery Act: Oxy-Combustion Techology Development for Industrial-Scale Boiler Applications

    Energy Technology Data Exchange (ETDEWEB)

    Levasseur, Armand

    2014-04-30

    Alstom Power Inc. (Alstom), under U.S. DOE/NETL Cooperative Agreement No. DE-NT0005290, is conducting a development program to generate detailed technical information needed for application of oxy-combustion technology. The program is designed to provide the necessary information and understanding for the next step of large-scale commercial demonstration of oxy combustion in tangentially fired boilers and to accelerate the commercialization of this technology. The main project objectives include: • Design and develop an innovative oxyfuel system for existing tangentially-fired boiler units that minimizes overall capital investment and operating costs. • Evaluate performance of oxyfuel tangentially fired boiler systems in pilot scale tests at Alstom’s 15 MWth tangentially fired Boiler Simulation Facility (BSF). • Address technical gaps for the design of oxyfuel commercial utility boilers by focused testing and improvement of engineering and simulation tools. • Develop the design, performance and costs for a demonstration scale oxyfuel boiler and auxiliary systems. • Develop the design and costs for both industrial and utility commercial scale reference oxyfuel boilers and auxiliary systems that are optimized for overall plant performance and cost. • Define key design considerations and develop general guidelines for application of results to utility and different industrial applications. The project was initiated in October 2008 and the scope extended in 2010 under an ARRA award. The project completion date was April 30, 2014. Central to the project is 15 MWth testing in the BSF, which provided in-depth understanding of oxy-combustion under boiler conditions, detailed data for improvement of design tools, and key information for application to commercial scale oxy-fired boiler design. Eight comprehensive 15 MWth oxy-fired test campaigns were performed with different coals, providing detailed data on combustion, emissions, and thermal behavior over a

  3. Recovery of Water from Boiler Flue Gas Using Condensing Heat Exchangers

    Energy Technology Data Exchange (ETDEWEB)

    Edward Levy; Harun Bilirgen; John DuPoint

    2011-03-31

    Most of the water used in a thermoelectric power plant is used for cooling, and DOE has been focusing on possible techniques to reduce the amount of fresh water needed for cooling. DOE has also been placing emphasis on recovery of usable water from sources not generally considered, such as mine water, water produced from oil and gas extraction, and water contained in boiler flue gas. This report deals with development of condensing heat exchanger technology for recovering moisture from flue gas from coal-fired power plants. The report describes: (1) An expanded data base on water and acid condensation characteristics of condensing heat exchangers in coal-fired units. This data base was generated by performing slip stream tests at a power plant with high sulfur bituminous coal and a wet FGD scrubber and at a power plant firing high-moisture, low rank coals. (2) Data on typical concentrations of HCl, HNO{sub 3} and H{sub 2}SO{sub 4} in low temperature condensed flue gas moisture, and mercury capture efficiencies as functions of process conditions in power plant field tests. (3) Theoretical predictions for sulfuric acid concentrations on tube surfaces at temperatures above the water vapor dewpoint temperature and below the sulfuric acid dew point temperature. (4) Data on corrosion rates of candidate heat exchanger tube materials for the different regions of the heat exchanger system as functions of acid concentration and temperature. (5) Data on effectiveness of acid traps in reducing sulfuric acid concentrations in a heat exchanger tube bundle. (6) Condensed flue gas water treatment needs and costs. (7) Condensing heat exchanger designs and installed capital costs for full-scale applications, both for installation immediately downstream of an ESP or baghouse and for installation downstream of a wet SO{sub 2} scrubber. (8) Results of cost-benefit studies of condensing heat exchangers.

  4. Recovery of Water from Boiler Flue Gas Using Condensing Heat Exchangers

    Energy Technology Data Exchange (ETDEWEB)

    Levy, Edward; Bilirgen, Harun; DuPont, John

    2011-03-31

    Most of the water used in a thermoelectric power plant is used for cooling, and DOE has been focusing on possible techniques to reduce the amount of fresh water needed for cooling. DOE has also been placing emphasis on recovery of usable water from sources not generally considered, such as mine water, water produced from oil and gas extraction, and water contained in boiler flue gas. This report deals with development of condensing heat exchanger technology for recovering moisture from flue gas from coal-fired power plants. The report describes: • An expanded data base on water and acid condensation characteristics of condensing heat exchangers in coal-fired units. This data base was generated by performing slip stream tests at a power plant with high sulfur bituminous coal and a wet FGD scrubber and at a power plant firing highmoisture, low rank coals. • Data on typical concentrations of HCl, HNO{sub 3} and H{sub 2}SO{sub 4} in low temperature condensed flue gas moisture, and mercury capture efficiencies as functions of process conditions in power plant field tests. • Theoretical predictions for sulfuric acid concentrations on tube surfaces at temperatures above the water vapor dewpoint temperature and below the sulfuric acid dew point temperature. • Data on corrosion rates of candidate heat exchanger tube materials for the different regions of the heat exchanger system as functions of acid concentration and temperature. • Data on effectiveness of acid traps in reducing sulfuric acid concentrations in a heat exchanger tube bundle. • Condensed flue gas water treatment needs and costs. • Condensing heat exchanger designs and installed capital costs for full-scale applications, both for installation immediately downstream of an ESP or baghouse and for installation downstream of a wet SO{sub 2} scrubber. • Results of cost-benefit studies of condensing heat exchangers.

  5. REFRACTORY FOR BLACK LIQUOR GASIFIERS

    Energy Technology Data Exchange (ETDEWEB)

    William L. Headrick Jr.; Alireza Rezaie

    2003-12-01

    The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the materials problems encountered during the operation of low-pressure high-temperature (LFHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective

  6. Refractory for Black Liquor Gasifiers

    Energy Technology Data Exchange (ETDEWEB)

    William L. Headrick Jr; Alireza Rezaie

    2003-12-01

    The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the materials problems encountered during the operation of low-pressure high-temperature (LFHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective

  7. Refractory for Black Liquor Gasifiers

    Energy Technology Data Exchange (ETDEWEB)

    William L. Headrick Jr; Alireza Rezaie; Xiaoting Liang; Musa Karakus; Jun Wei

    2005-12-01

    The University of Missouri-Rolla identified materials that permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project was to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study attempted to define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials were selected or developed that reacted with the gasifier environment to form protective surfaces in

  8. Refractory for Black Liquor Gasifiers

    Energy Technology Data Exchange (ETDEWEB)

    William L. Headrick Jr; Musa Karakus; Xiaoting Liang

    2005-10-01

    The University of Missouri-Rolla identified materials that permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project was to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study attempted to define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials were selected/developed that either react with the gasifier environment to form protective surfaces in

  9. Refractory for Black Liquor Gasifiers

    Energy Technology Data Exchange (ETDEWEB)

    William L. Headrick; Musa Karakus; Alireza Rezaie

    2004-03-30

    The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective

  10. REFRACTORY FOR BLACK LIQUOR GASIFIERS

    Energy Technology Data Exchange (ETDEWEB)

    William L. Headrick Jr; Musa Karakus; Xiaoting Liang; Alireza Rezaie

    2004-07-01

    The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective

  11. REFRACTORY FOR BLACK LIQUOR GASIFIERS

    Energy Technology Data Exchange (ETDEWEB)

    William L. Headrick Jr; Musa Karakus; Xiaoting Liang; Alireza Rezaie

    2004-10-01

    The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective

  12. REFRACTORY FOR BLACK LIQUOR GASIFIERS

    Energy Technology Data Exchange (ETDEWEB)

    William L. Headrick Jr; Musa Karakus; Xiaoting Liang; Jun Wei

    2005-01-01

    The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective

  13. REFRACTORY FOR BLACK LIQUOR GASIFIERS

    Energy Technology Data Exchange (ETDEWEB)

    William L. Headrick Jr; Musa Karakus; Xiaoting Liang; Jun Wei

    2005-04-01

    The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective

  14. REFRACTORY FOR BLACK LIQUOR GASIFIERS

    Energy Technology Data Exchange (ETDEWEB)

    William L. Headrick Jr; Musa Karakus; Xiaoting Liang

    2005-07-01

    The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective

  15. REFRACTORY FOR BLACK LIQUOR GASIFIERS

    Energy Technology Data Exchange (ETDEWEB)

    William L. Headrick Jr.; Alireza Rezaie

    2004-04-01

    The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the materials problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective

  16. Technical Report Cellulosic Based Black Liquor Gasification and Fuels Plant Final Technical Report

    Energy Technology Data Exchange (ETDEWEB)

    Fornetti, Micheal [Escanaba Paper Company, MI (United States); Freeman, Douglas [Escanaba Paper Company, MI (United States)

    2012-10-31

    produce transportation fuels and produce pulp at the same time. This has the added advantage of reducing or eliminating the need for a recovery boiler. The recovery boiler is an extremely expensive unit operation in the Kraft process and is key to the chemical recovery system that makes the Kraft process successful. Going to a gasification process with potentially higher energy efficiency, improve the pulping process and be more efficient with the use of wood. At the same time a renewable fuel product can be made. Cellulosic Based Black Liquor Gasification and Fuels Plant progressed with the design of the mill as Chemrec continued to work on their pilot plant data gathering. The design information helped to guide the pilot plant and vice versa. In the end, the design details showed that the process was technically feasible. However, at the relatively small size of this plant the specific capital cost was very high and could only be considered if the pulp operation needed to replace the recovery boiler. Some of the reasons for the costs being high are attributed to the many constraints that needed to be addressed in the pulping process. Additionally, the Methanol product did not have a vehicle fuel supply chain to enter into. A different product selection could have eliminated this issue. However, with the selected design, the installation at Escanaba Paper Mill was not economically feasible and the project was not pursued further.

  17. Recycling of Dilute Deacetylation Black Liquor to Enable Efficient Recovery and Reuse of Spent Chemicals and Biomass Pretreatment Waste

    Directory of Open Access Journals (Sweden)

    Xiaowen Chen

    2018-06-01

    Full Text Available Deacetylation/dilute alkaline pretreatment followed by mechanical refining (DMR has been proven as an effective process for biomass sugar liberation without severe chemical modification to lignin. Previous research has been focused on optimizing deacetylation conditions, reducing energy consumptions in mechanical refining, and improving sugar yields and titers in enzymatic hydrolysis. To successfully commercialize this process, another critical challenge is to develop a robust process to balance water usage, recover spent chemicals, and utilize waste carbons from the dilute deacetylation waste liquor. In this work, a new process modification and strategy is pioneered to recycle and reuse the weak black liquor (WBL in order to reduce water, chemical, and energy usage while increasing both inorganic and organic contents in the WBLto facilitate downstream processing. Results suggest that the accumulation did not lower acetyl and lignin removal in alkaline pretreatment, resulting in comparable sugar yields in enzymatic hydrolysis. Sodium and potassium were found to be the two most important inorganic compounds in the recycled WBL. Moreover, the accumulated sodium and phenolic compounds did not inhibit the downstream ethanol fermentation processes. Finally, techno-economic analysis (TEA showed a decrease in the minimum ethanol selling price (MESP by ~5 to 15 cents per gallon of ethanol resulting from the inclusion of the recycling of weak black liquor when compared to a conventional non-recycling process.

  18. Synthetic gas production from dry black liquor gasification process using direct causticization with CO2 capture

    International Nuclear Information System (INIS)

    Naqvi, Muhammad; Yan, Jinyue; Dahlquist, Erik

    2012-01-01

    Highlights: ► We study synthetic gas production from dry black liquor gasification system. ► Direct causticization eliminates energy intensive lime kiln reducing biomass use. ► Results show large SNG production potential at significant energy efficiency (58%). ► Substantial CO 2 capture potential plus CO 2 reductions from natural gas replacement. ► Significant transport fuel replacement especially in Sweden and Europe. -- Abstract: Synthetic natural gas (SNG) production from dry black liquor gasification (DBLG) system is an attractive option to reduce CO 2 emissions replacing natural gas. This article evaluates the energy conversion performance of SNG production from oxygen blown circulating fluidized bed (CFB) black liquor gasification process with direct causticization by investigating system integration with a reference pulp mill producing 1000 air dried tonnes (ADt) of pulp per day. The direct causticization process eliminates use of energy intensive lime kiln that is a main component required in the conventional black liquor recovery cycle with the recovery boiler. The paper has estimated SNG production potential, the process energy ratio of black liquor (BL) conversion to SNG, and quantified the potential CO 2 abatement. Based on reference pulp mill capacity, the results indicate a large potential of SNG production (about 162 MW) from black liquor but at a cost of additional biomass import (36.7 MW) to compensate the total energy deficit. The process shows cold gas energy efficiency of about 58% considering black liquor and biomass import as major energy inputs. About 700 ktonnes per year of CO 2 abatement i.e. both possible CO 2 capture and CO 2 offset from bio-fuel use replacing natural gas, is estimated. Moreover, the SNG production offers a significant fuel replacement in transport sector especially in countries with large pulp and paper industry e.g. in Sweden, about 72% of motor gasoline and 40% of total motor fuel could be replaced.

  19. Factors controlling deposits in recovery boilers -particle formation and deposition; Soodakattilan likaantuminen ja siihen vaikuttavien tekijoeiden hallinta. Hiukkasten muodostuminen ja depositio

    Energy Technology Data Exchange (ETDEWEB)

    Kauppinen, E I; Mikkanen, P; Tapper, U; Ylaetalo, S; Jaervinen, R [VTT Chemical Technology, Espoo (Finland); Jokiniemi, J K; Pyykoenen, J; Eskola, A [VTT Energy, Espoo (Finland)

    1997-10-01

    In this project the aim is to find critical factors controlling the deposit formation in the recovery boilers. Focus is on particle formation, growth and deposition. During year 1995 the aerosol particle formation was studied by an experimental study within the recovery boiler furnace and by a sensitivity study with the ABC (Aerosol Behaviour in Combustion) computer code. During year 1996 the experimental studies on the aerosol particle formation continued within the furnace and the deposition mechanisms for carry over particles were included in the ABC code and sensitivity studies of the deposition were carried out. The experimental study confirmed the fact that the particles are already formed in the recovery boiler furnace. The particle formation is initiated in the boundary layer of the burning droplet or char bed, where metals are vaporised and oxidised to form tiny seed particles

  20. Two-step process of regeneration of acid(s) from ZrF{sub 4} containing spent pickle liquor and recovery of zirconium metal

    Energy Technology Data Exchange (ETDEWEB)

    Nersisyan, Hayk [Graduate School of Department of Materials Science & Engineering, Chungnam National University, 99 Daehakro, Yuseong-gu, Daejeon (Korea, Republic of); RASOM, Chungnam National University, 99 Daehak-ro, Yuseong-gu, Daejeon (Korea, Republic of); Han, Seul Ki; Choi, Jeong Hun [Graduate School of Department of Materials Science & Engineering, Chungnam National University, 99 Daehakro, Yuseong-gu, Daejeon (Korea, Republic of); Graduate School of Energy Science & Technology, Chungnam National University, 99 Daehak-ro, Yuseong-gu, Daejeon (Korea, Republic of); Lee, Young-Jun; Yoo, Bung Uk [Graduate School of Energy Science & Technology, Chungnam National University, 99 Daehak-ro, Yuseong-gu, Daejeon (Korea, Republic of); Ri, Vladislav E. [Graduate School of Department of Materials Science & Engineering, Chungnam National University, 99 Daehakro, Yuseong-gu, Daejeon (Korea, Republic of); Lee, Jong Hyeon, E-mail: jonglee@cnu.ac.kr [Graduate School of Department of Materials Science & Engineering, Chungnam National University, 99 Daehakro, Yuseong-gu, Daejeon (Korea, Republic of); Graduate School of Energy Science & Technology, Chungnam National University, 99 Daehak-ro, Yuseong-gu, Daejeon (Korea, Republic of); RASOM, Chungnam National University, 99 Daehak-ro, Yuseong-gu, Daejeon (Korea, Republic of)

    2017-04-01

    In this paper we describe a progressive two-step process that allows zirconium fluoride (ZrF{sub 4}) contained in spent baths for etched zirconium alloys to be effectively recycled on a pilot scale and produce a high purity regenerated pickling acid. In the first step, a spent pickling liquor is treated by a BaF{sub 2} suspension to produce water insoluble Ba{sub 2}ZrF{sub 8}. After filtration of Ba{sub 2}ZrF{sub 8} more than 99.9 wt % purity pickling acid is regenerated. The precipitation mechanism of Ba{sub 2}ZrF{sub 8} is discussed and the role of BaF{sub 2} particles size on the precipitation process is demonstrated. In the second step the as-precipitated Ba{sub 2}ZrF{sub 8} is mixed with Mg and Cu metal powders and heat-treated at 1200 °C (or above) to produce CuZr alloy ingot. The characteristics of the ingot are discussed in regard to Cu concentration and the heating temperature. - Highlights: •Two-step process for recycling ZrF{sub 4} containing pickling acid on a pilot scale is developed. •Water insoluble Ba{sub 2}ZrF{sub 8} is precipitated by mixing spent pickling liquor with BaF{sub 2}. •The recycled pickling acid demonstrates more than 99.9 wt % purity. •The processing of Ba{sub 2}ZrF{sub 8} with Cu and Mg metals at 1200 °C yielded CuZr alloy. •The recovery depth of Zr was more than 95 wt%.

  1. Study of immersed heat exchange surface for high efficiency heat recovery from wire rim tires in a fluidized bed boiler; Hai tire nado kara no kokoritsu netsukaishuyo ryudosho boiler no sonai dennetsukan no kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Oshita, T; Nagato, S; Miyoshi, N; Hosoda, S [Ebara Corp., Tokyo (Japan)

    1996-07-10

    In an ICFB boiler, the fluidized bed is separated by a partition into the main combustion and the heat recovery chambers. The flows in these chambers are generated by using silica sand as the fluidizing medium. To determine the overall heat transfer coefficient (HTC) of the boiler`s panel type immersed heat transfer tulles, combustion tests were performed with wire rim tires. The overall HTC of a panel tube array was lower than that of a zigzag tube arrangement. In practice, the heat absorbed by the fins makes the coefficients of either type of tube array almost identical. The air flow rate in the circulating bed at the loot Tom of the heat recovery chamber can be changed to control the overall HTC to a value virtually identical with that of a zigzag tube array. The combustion of wire rim tires leads to a buildup of wires in the zigzag array hampering the transfer of heat. Yet, the panel type array showed no buildup so that it was possible to maintain steady operation with this type of tube arrangement. 8 refs., 10 figs., 2 tabs.

  2. Development and optimisation of process parameters for recovery of uranium from calcia slag and lining material (SLM) by leaching process and subsequent recovery of uranium from the leach liquor generated

    International Nuclear Information System (INIS)

    Verma, Dinesh Kumar; Srivastava, Praveen Kumar; Das, Santanu; Kumar, Raj; Roy, S.B.

    2014-01-01

    Presently uranium value is recovered by nitric acid dissolution of the SLM, to get uranyl nitrate solution (UNS) and subsequent solvent extraction process. UNS generated After SLM dissolution is very lean in uranium content and create difficulty in solvent extraction. Moreover, NO X is also generated during SLM dissolution in nitric acid. An alternate process was developed where nitric acid is not being used and uranium is being recovered by leaching out the SLM using acetic acid. The process was also optimised for recovery and overall economics of the process by using process effluent AALL (Acetic Acid Leach Liquor) as a leaching agent. The uranium value in the leach liquor was precipitated by using sodium hydroxide. The precipitate was dissolved in nitric acid and the Uranyl Nitrate Solution generated was having Uranium concentration of 15-30 g/l. The alternate process developed will have less effluent generation, less NO X generation and will produce more concentrated UNS in comparison to the nitric acid dissolution process

  3. Trace recovery of uranium and rare earth contained in phosphates by liquid-liquid extraction in sulfuric attack liquor

    International Nuclear Information System (INIS)

    Bousquet, F.; Foraison, D.; Leveque, A.; Sabot, J.L.

    1980-06-01

    Uranium and rare earths can be recovered in sedimentary phosphates during the wet processing of the ore by sulfuric acid giving raw phosphoric acid at 30 per cent of P 2 O 5 . Practically all the uranium contained and only part of rare earths are put into solution in this treatment. Separation of these elements in the phosphoric solution is obtained by liquid-liquid extraction with alkylphosphoric acids and especially with their mono and di esters. Partition isotherms are determined and counter-current tests are effected. Uranium and rare earths reextraction from these solvents can be simultaneous or separate with aqueous solutions alkaline or containing HF or by antisynergism. Pros and cons of each reextraction process are discussed. In conclusion HDEHP or OPPA are recommended because of availability, stability and hydrodynamic, OPPA less selective with rare earths allows the recovery with uranium of ceric earths, yttrium and yttric earths [fr

  4. Furnace and Heat Recovery Area Design and Analysis for Conceptual Design of Supercritical O2-Based PC Boiler

    International Nuclear Information System (INIS)

    Andrew Seltzer

    2006-01-01

    The objective of the furnace and heat recovery area design and analysis task of the Conceptual Design of Supercritical Oxygen-Based PC Boiler study is to optimize the location and design of the furnace, burners, over-fire gas ports, and internal radiant surfaces. The furnace and heat recovery area were designed and analyzed using the FW-FIRE, Siemens, and HEATEX computer programs. The furnace is designed with opposed wall-firing burners and over-fire air ports. Water is circulated in the furnace by forced circulation to the waterwalls at the periphery and divisional wall panels within the furnace. Compared to the air-fired furnace, the oxygen-fired furnace requires only 65% of the surface area and 45% of the volume. Two oxygen-fired designs were simulated: (1) with cryogenic air separation unit (ASU) and (2) with oxygen ion transport membrane (OITM). The maximum wall heat flux in the oxygen-fired furnace is more than double that of the air-fired furnace due to the higher flame temperature and higher H 2 O and CO 2 concentrations. The coal burnout for the oxygen-fired case is 100% due to a 500 F higher furnace temperature and higher concentration of O 2 . Because of the higher furnace wall temperature of the oxygen-fired case compared to the air-fired case, furnace water wall material was upgraded from T2 to T92. Compared to the air-fired heat recovery area (HRA), the oxygen-fired HRA total heat transfer surface is 35% less for the cryogenic design and 13% less for the OITM design due to more heat being absorbed in the oxygen-fired furnace and the greater molecular weight of the oxygen-fired flue gas. The HRA tube materials and wall thickness are nearly the same for the air-fired and oxygen-fired design since the flue gas and water/steam temperature profiles encountered by the heat transfer banks are similar

  5. System analysis of dry black liquor gasification based synthetic gas production comparing oxygen and air blown gasification systems

    International Nuclear Information System (INIS)

    Naqvi, Muhammad; Yan, Jinyue; Dahlquist, Erik

    2013-01-01

    Highlights: ► Circulating fluidized bed system for black liquor gasification with direct causticization. ► Effects of gasifying medium i.e. oxygen or air, on gasification are studied. ► Direct causticization eliminates energy intensive limekiln reducing biomass use. ► Results show 10% higher SNG production from O 2 blown system than air blown system. ► SNG production is higher in O 2 blown system than air blown system. - Abstract: The black liquor gasification based bio-fuel production at chemical pulp mill is an attractive option to replace conventional recovery boilers increasing system energy efficiency. The present paper studies circulating fluidized bed system with direct causticization using TiO 2 for the gasification of the black liquor to the synthesis gas. The advantage of using direct causticization is the elimination of energy-intensive lime kiln which is an integral part of the conventional black liquor recovery system. The study evaluates the effects of gasifying medium i.e. oxygen or air, on the fluidized bed gasification system, the synthesis gas composition, and the downstream processes for the synthesis gas conversion to the synthetic natural gas (SNG). The results showed higher synthetic natural gas production potential with about 10% higher energy efficiency using oxygen blown gasification system than the air blown system. From the pulp mill integration perspective, the material and energy balance results in better integration of air blown system than the oxygen blown system, e.g. less steam required to be generated in the power boiler, less electricity import, and less additional biomass requirement. However, the air blown system still requires a significant amount of energy in terms of the synthesis gas handling and gas upgrading using the nitrogen rejection system

  6. Toxic waste liquor disposal

    International Nuclear Information System (INIS)

    Burton, W.R.

    1985-01-01

    Toxic waste liquors, especially radio active liquors, are disposed in a sub-zone by feeding down a bore hole a first liquid, then a buffer liquid (e.g. water), then the toxic liquors. Pressure variations are applied to the sub-zone to mix the first liquid and liquors to form gels or solids which inhibit further mixing and form a barrier between the sub-zone and the natural waters in the environment of the sub-zone. In another example the location of the sub-zone is selected so that the environement reacts with the liquors to produce a barrier around the zone. Blind bore holes are used to monitor the sub-zone profile. Materials may be added to the liquor to enhance barrier formation. (author)

  7. Sulphate removal from uraniferous liquors

    International Nuclear Information System (INIS)

    Berger, B.

    1983-01-01

    A process for the recovery of uranium from liquor resulting from the attack of sulphur containing uraniferous ores by an alkaline solution of sodium carbonate and/or sodium bicarbonate is claimed. An ion exchange resin is used to separate the uranium from the solution of sodium carbonate and/or bicarbonate and sodium sulphate. The ion exchange resin is then eluted with a solution of ammonium carbonate and/or bicarbonate to provide an eluate containing ammonium uranyl tricarbonate, ammonium carbonate and/or bicarbonate and ammonium sulphate. The eluate is heated to boiling to convert the ammonium uranyl tricarbonate to ammonium uranate and/or diuranate. Ammonia, carbon dioxide and water vapor are released. The precipitated ammonium uranate and/or diuranate is separated from the remaining liquor and calcined to give uranium trioxide

  8. Refractive Index of Black and Green Liquors

    Directory of Open Access Journals (Sweden)

    E. A. Avramenko

    2015-01-01

    Full Text Available Lack of reliable data on the optical properties of black and green liquors complicates control of their composition in technological process of sulphate cellulose production. In this regard the paper presents measurement results of refraction index of black liquors n (k,t at concentration in solutions of bone-dry solids up to k = 70% and at temperatures t = 10-90 °C, as well as in green liquors n(C,t at the total alkalinity of C = 0-250 g/l and in the same temperature range. All samples of solutions of black and green liquors were provided by Segezha Pulp and Paper Mill and certified in factory laboratory. Measurements were taken by means of the laboratory Abbe refractometer (URL-1, digital refractometer "Expert pro", goniometer spectrometer GS-5, and ultra-violet spectrophotometer as well. The work also presents optical D density spectra in the ultra-violet region of the wavelengths for the samples of a green liquor and main mineral component to form it, i.e. Na2S (sodium sulphide. To calculate dispersion of n (λ in the visible spectral range, here a Lorentz single-oscillator model was used. The paper discusses study results of dispersive dependence of refraction index in green liquors with various concentration and chemical components of n (λ, C forming them at t = 20°C. Computing and experimental dependences of n (λ had not only good qualitative, but also quite satisfactory quantitative compliance. The work also describes main mineral components defining optical properties in these liquors. Given here data on concentration and temperature dependences of a refraction index in black n(k,t and green n(C,t liquors have been never published before. These data are of essential interest to control soda recovery technologies in manufacturing sulphate cellulose. The received results can be also used to tune and calibrate modern domestic and foreign industrial refractometers.

  9. Causticizing for Black Liquor Gasifiers

    Energy Technology Data Exchange (ETDEWEB)

    Scott Sinquefeld; James Cantrell; Xiaoyan Zeng; Alan Ball; Jeff Empie

    2009-01-07

    The cost-benefit outlook of black liquor gasification (BLG) could be greatly improved if the smelt causticization step could be achieved in situ during the gasification step. Or, at a minimum, the increase in causticizing load associated with BLG could be mitigated. A number of chemistries have been proven successful during black liquor combustion. In this project, three in situ causticizing processes (titanate, manganate, and borate) were evaluated under conditions suitable for high temperature entrained flow BLG, and low temperature steam reforming of black liquor. The evaluation included both thermodynamic modeling and lab experimentation. Titanate and manganate were tested for complete direct causticizing (to thus eliminate the lime cycle), and borates were evaluated for partial causticizing (to mitigate the load increase associated with BLG). Criteria included high carbonate conversion, corresponding hydroxide recovery upon hydrolysis, non process element (NPE) removal, and economics. Of the six cases (three chemistries at two BLG conditions), only two were found to be industrially viable: titanates for complete causticizing during high temperature BLG, and borates for partial causticizing during high temperature BLG. These two cases were evaluated for integration into a gasification-based recovery island. The Larsen [28] BLG cost-benefit study was used as a reference case for economic forecasting (i.e. a 1500 tpd pulp mill using BLG and upgrading the lime cycle). By comparison, using the titanate direct causticizing process yielded a net present value (NPV) of $25M over the NPV of BLG with conventional lime cycle. Using the existing lime cycle plus borate autocausticizing for extra capacity yielded a NPV of $16M.

  10. Spent sulfite liquor developments

    Energy Technology Data Exchange (ETDEWEB)

    Black, H H

    1958-01-01

    A review of methods of utilizing spent sulfite liquor, including evaporation and burning, fermentation to produce yeast or alcohol, production of vanillin and lignosulfonates, and use as a roadbinder.

  11. Transport of Zn (II by TDDA-Polypropylene Supported Liquid Membranes and Recovery from Waste Discharge Liquor of Galvanizing Plant of Zn (II

    Directory of Open Access Journals (Sweden)

    Hanif Ur Rehman

    2017-01-01

    Full Text Available The facilitated passage of Zn (II across flat sheet supported liquid membrane saturated with TDDA (tri-n-dodecylamine in xylene membrane phase has been investigated. The effect of acid and metal ion concentration in the feed solution, the carrier concentration in membrane phase, stripping agent concentration in stripping phase, and coions on the extraction of Zn (II was investigated. The stoichiometry of the extracted species, that is, complex, was investigated on slope analysis method and it was found that the complex (LH2·Zn(Cl2 is responsible for transport of Zn (II. A mathematical model was developed for transport of Zn (II, and the predicted results strongly agree with experimental ones. The mechanism of transport was determined by coupled coion transport mechanism with H+ and Cl− coupled ions. The optimized SLM was effectively used for elimination of Zn (II from waste discharge liquor of galvanizing plant of Zn (II.

  12. Removal of sulfite liquor from digesters with partially diluted liquor

    Energy Technology Data Exchange (ETDEWEB)

    Leshchenko, I G; Sykol, V P

    1957-01-01

    The yield of reducing sugars was raised from 189 to 224 kg/ton of pulp by displacing the cooking liquor with diluted liquor. As the pressure during blow-off dropped to 3.5-3.0 atmosphere, weak sulfite liquor was added at the rate 120 cu m/hr. After 5-10 minutes the liquor was pumped from the digester to the ethanol plant.

  13. HR boiler

    Energy Technology Data Exchange (ETDEWEB)

    1982-08-01

    A number of manufacturers of central heating boilers in the Netherlands have produced high-efficiency boilers, all carrying the GIVEG-HR seal of approval (GIVEG is the manufacturers' association in the Netherlands, and HR stands for 'hoog rendement': high efficiency). Efficiences were considerably improved by reducing flue, idling and radiation losses. Control and safety, discharges of flue gases and condensate need special attention. Whether installation of a GIVEG-HR boiler is profitable in view of the cost/profit ratio, will have to be determined from case to case. N.V. Nederlandse Gasunie felt it was time to present the facts so far in a way specially aimed at the construction industry. This special edition of 'Gas and Architecture' answers a number of questions which the architect or consultant engineer might have in particular before advising on the installation of the new boiler in houses and other buildings in the interests of energy saving. A technical description of the HR boiler covers the backgrounds of its development and considers the role of the Netherlands government as regards to the introduction of the boiler.

  14. Recovery Act: Oxy-Combustion Technology Development for Industrial-Scale Boiler Applications. Task 4 - Testing in Alstom's 15 MWth Boiler Simulation Facility

    Energy Technology Data Exchange (ETDEWEB)

    Levasseur, Armand

    2014-04-30

    Alstom Power Inc. (Alstom), under U.S. DOE/NETL Cooperative Agreement No. DE-NT0005290, is conducting a development program to generate detailed technical information needed for application of oxy-combustion technology. The program is designed to provide the necessary information and understanding for the next step of large-scale commercial demonstration of oxy combustion in tangentially fired boilers and to accelerate the commercialization of this technology. The main project objectives include: Design and develop an innovative oxyfuel system for existing tangentially-fired boiler units that minimizes overall capital investment and operating costs; Evaluate performance of oxyfuel tangentially fired boiler systems in pilot scale tests at Alstom’s 15 MWth tangentially fired Boiler Simulation Facility (BSF); Address technical gaps for the design of oxyfuel commercial utility boilers by focused testing and improvement of engineering and simulation tools; Develop the design, performance and costs for a demonstration scale oxyfuel boiler and auxiliary systems; Develop the design and costs for both industrial and utility commercial scale reference oxyfuel boilers and auxiliary systems that are optimized for overall plant performance and cost; and, Define key design considerations and develop general guidelines for application of results to utility and different industrial applications. The project was initiated in October 2008 and the scope extended in 2010 under an ARRA award. The project is scheduled for completion by April 30, 2014. Central to the project is 15 MWth testing in the BSF, which provided in-depth understanding of oxy-combustion under boiler conditions, detailed data for improvement of design tools, and key information for application to commercial scale oxy-fired boiler design. Eight comprehensive 15 MWth oxy-fired test campaigns were performed with different coals, providing detailed data on combustion, emissions, and thermal behavior over a matrix of

  15. Chemical by-products from spent sulfite liquors

    Energy Technology Data Exchange (ETDEWEB)

    Whitmore, Jr, L M; Wiley, A J

    1958-01-01

    Current practices for recovering sugars, lignosulfonates, ethanol and feed yeast and product uses are reviewed. A process for separating sugars is described in which the sulfite liquor is spray dried and refluxed with acetone containing a concentrated H/sub 2/SO/sub 4/ catalyst, and the di-acetone sugar derivatives are filtered or centrifuged from the acetone insolubles. Recovery of guaiacyl and syringyl derivatives from the lignosulfonate portion of the liquor is discussed.

  16. System aspects of black liquor gasification - Consequences for both industry and society

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2002-02-01

    The pulp and paper industry consumes large quantities of biofuels (mainly bark and black liquor) to satisfy process requirements. Biomass is however a limited resource, and biofuel usage should therefore be as effective as possible. Modern pulp mills and integrated pulp and paper mills have excess fuel compared to the amounts needed to satisfy the process steam demand. The excess fuel is often used for cogeneration of electric power in CHP units. For integrated pulp and paper mills, this usually requires import of supplementary fuel to the plant. For market pulp mills, the excess internal biofuel quantities are sufficient to also allow electric power generation in condensing power plant units. If biofuel availability at a reasonable price is limited, import/export to, from a mill changes the amount of such biofuel available to alternative users. The goal of this thesis is to compare different mill powerhouse technologies and CHP plant configurations (including conventional recovery boiler technology and black liquor gasification technology) in order to identify the technology and CHP plant configuration that can produce the most electric power output from a given fuel resource for a given process steam demand. Different process steam demand levels for different representative mill types are considered. The comparison accounts for increased/decreased electricity production in an alternative energy system when biofuel is imported/exported to/from from the mill. The alternative energy system considered includes a district heating system with CHP capacity and natural gas fired combined cycle power plant capacity. The results show that black liquor gasification is in all cases considered an attractive powerhouse recovery cycle technology compared to conventional recovery boiler technology. If the marginal electric power generation efficiency for biofuel exported to the reference alternative energy system is 49%, excess mill internal biofuel should be used on mill

  17. Efficient boiler operations sourcebook

    Energy Technology Data Exchange (ETDEWEB)

    Payne, F.W. (comp.)

    1985-01-01

    This book emphasizes the practical aspects of industrial and commercial boiler operations. It starts with a comprehensive review of general combustion and boiler fundamentals and then deals with specific efficiency improvement methods, and the cost savings which result. The book has the following chapter headings: boiler combustion fundamentals; boiler efficiency goals; major factors controlling boiler efficiency; boiler efficiency calculations; heat loss; graphical solutions; preparation for boiler testing; boiler test procedures; efficiency-related boiler maintenance procedures; boiler tune-up; boiler operational modifications; effect of water side and gas side scale deposits; load management; auxillary equipment to increase boiler efficiency; air preheaters and economizers; other types of auxillary equipment; combustion control systems and instrumentation; boiler O/sub 2/ trim controls; should you purchase a new boiler.; financial evaluation procedures; case studies. The last chapter includes a case study of a boiler burning pulverized coal and a case study of stoker-fired coal.

  18. Clear Liquor Scrubbing with Anhydrite Production

    International Nuclear Information System (INIS)

    Hargrove, O. W.; Carey, T. R.; Lowell, P. S.; Meserole, F. B.; Rhudy, R. G.; Feeley, Thomas J.

    1997-01-01

    The objective of this project to develop an advanced flue gas desulfurization (FGD) process that has decreased capital and operating costs, higher SO 2 removal efficiency, and better by-product solids quality than existing, commercially available technology. A clear liquor process (which uses a scrubbing liquid with no solids) will be used to accomplish this objective rather than a slurry liquor process (which contains solids). This clear liquor scrubbing (CLS) project is focused on three research areas: (1) Development of a clear liquor scrubbing process that uses a clear solution to remove SO 2 from flue gas and can be operated under inhibited-oxidation conditions; (2) Development of an anhydrite process that converts precipitated calcium sulfite to anhydrous calcium sulfate (anhydrite); and (3) Development of an alkali/humidification process to remove HCl from flue gas upstream of the FGD system. The anhydrite process also can be retrofit into existing FGD systems to produce a valuable by-product as an alternative to gypsum. This fits well into another of FETC's PRDA objectives of developing an advanced byproduct recovery subsystem capable of transforming SO 2 into a useable byproduct or high-volume valuable commodities of interest. This paper describes the proposed processes, outlines the test approach, and preliminary Phase I test results

  19. Recovery of uranium from liquors from shale attack by ion exchange; Recuperation de l'uranium des liqueurs d'attaque des schistes par echange d'ions

    Energy Technology Data Exchange (ETDEWEB)

    Parly, B; Pottier, P

    1959-04-01

    This report deals with the recovery of the uranium from a lot of shale mined at Schaentzel with an U content of 285 ppm. Recovery is realized by alkaline attack with a solution of 25 g/l Na{sub 2}CO{sub 3} at 75 C followed by absorption of the dissolved uranium by an anionic Amberlite resin, IRA 410. Final recovery is done by elution with a solution of M NaNO{sub 3}. These treatment tests determine the capacity of the resin in the case of the above solutions, verify the effects of recycling on this capacity, and finally, provide figures on the consumption of reactive and efficiency of attack and uranium recovery. (author) [French] Il s'agit de la recuperation, de l'uranium d'un lot de schiste- de Schaentzel (puits AO) dont la teneur en U est de 285 ppm. Cette recuperation consiste en une attaque alcaline par une solution de CO{sub 3}Na{sub 2} a 25 g/l et a 75 deg C. L'attaque est suivie de l'adsorption de l'uranium solubilise, sur resine anionique Amberlite IRA 410. On recupere finalement l'uranium par elution a l'aide d'une solution de NO{sub 3}Na M. Cet essai de traitement permit de determiner la capacite de la resine dans le cas de ces solutions, de verifier l'effet du recyclage sur la capacite et enfin de chiffrer la consommation en reactifs ainsi que les rendements d'attaque et de recuperation de l'uranium. (auteur)

  20. Stress-Assisted Corrosion in Boiler Tubes

    Energy Technology Data Exchange (ETDEWEB)

    Preet M Singh; Steven J Pawel

    2006-05-27

    A number of industrial boilers, including in the pulp and paper industry, needed to replace their lower furnace tubes or decommission many recovery boilers due to stress-assisted corrosion (SAC) on the waterside of boiler tubes. More than half of the power and recovery boilers that have been inspected reveal SAC damage, which portends significant energy and economic impacts. The goal of this project was to clarify the mechanism of stress-assisted corrosion (SAC) of boiler tubes for the purpose of determining key parameters in its mitigation and control. To accomplish this in-situ strain measurements on boiler tubes were made. Boiler water environment was simulated in the laboratory and effects of water chemistry on SAC initiation and growth were evaluated in terms of industrial operations. Results from this project have shown that the dissolved oxygen is single most important factor in SAC initiation on carbon steel samples. Control of dissolved oxygen can be used to mitigate SAC in industrial boilers. Results have also shown that sharp corrosion fatigue and bulbous SAC cracks have similar mechanism but the morphology is different due to availability of oxygen during boiler shutdown conditions. Results are described in the final technical report.

  1. CFD Simulation On CFBC Boiler

    Directory of Open Access Journals (Sweden)

    Amol S. Kinkar

    2015-02-01

    Full Text Available Abstract Heavy industrialization amp modernization of society demands in increasing of power cause to research amp develop new technology amp efficient utilization of existing power units. Variety of sources are available for power generation such as conventional sources like thermal hydro nuclear and renewable sources like wind tidal biomass geothermal amp solar. Out of these most common amp economical way for producing the power is by thermal power stations. Various industrial boilers plays an important role to complete the power generation cycle such as CFBC Circulating Fluidized Bed Combustion FBC Fluidized Bed Combustion AFBC Atmospheric Fluidized Bed Combustion Boiler CO Boiler RG amp WHR Boiler Waster heat recovery Boiler. This paper is intended to comprehensively give an account of knowledge related to refractory amp its failure in CFBC boiler with due effect of flue gas flow during operation on refractory by using latest technology of CAD Computer aided Design amp CAE Computer aided Engineering. By conceptual application of these technology the full scale model is able to analyze in regards the flow of flue gas amp bed material flow inside the CFBC loop via CFD Computational Fluid Dynamics software. The results obtained are helpful to understand the impact of gas amp particles on refractory in different areas amp also helped to choose suitable refractory material in different regions.

  2. Study of cupuassu liquor

    OpenAIRE

    Cohen, Kelly de Oliveira; Jackix, Marisa de Nazaré Hoelz

    2005-01-01

    O cupuaçu (Theobroma grandiflorum Schum), que é um fruto amazônico, vem conquistando a cada ano mais espaço no mercado nacional e internacional com a comercialização de sua polpa. Suas sementes, consideradas como subproduto, vem despertando interesse não só no mundo científico como pelas indústrias. Sabe-se que, a partir das sementes, pode-se obter produtos análogos aos oriundos das sementes de cacau, seguindo as mesmas etapas de processamento. Dentre esses produtos tem-se o liquor de cupuaçu...

  3. Formation of fuel NOx during black-liquor combustion

    International Nuclear Information System (INIS)

    Nichols, K.M.; Lien, S.J.

    1993-01-01

    Fuel NOx and thermal NOx were measured in combustion gases from black liquors in two laboratory furnaces. Combustion at 950 C in air (8% O 2 ) produced NOx concentrations of 40-80ppm. Combustion at 950 C in synthetic air containing no nitrogen (21% 0 2 in Ar) produced the same result, demonstrating that all of the NOx produced during combustion at 950 C was fuel NOx. Formation of fuel NOx increased moderately with increasing temperature in the range of 800-1,000 C, but temperature sensitivity of fuel NOx was much less than that of thermal NOx. The results imply that the major source of NOx in recovery furnace emissions is the fuel NOx in recovery furnace formed by conversion of liquor-bound nitrogen during combustion. This is consistent with thermal NOx theory, which postulates that black-liquor combustion temperatures are too low to generate significant amounts of thermal NOx

  4. Proceedings of the black liquor research program review fifth meeting

    Energy Technology Data Exchange (ETDEWEB)

    1988-09-01

    On June 14--17, 1988 the participants and invited guests of the Cooperative Program in Kraft Recovery gathered in Charleston, South Carolina, to review progress on four major black liquor research programs being executed at the Institute of Paper Chemistry, the University of Maine, the National Bureau of Standards, and the University of Florida. These programs include: (1) Black Liquor Properties; (2) Black Liquor Droplet Formation; (3) Black Liquor Nozzle Evaluation; and (4) Black Liquor Combustion. In addition to the objectives of previous meetings, this meeting made a direct attempt to gather ideas on how to improve our ability to move from new technology concepts to commercial implementation. Also attached is the agenda for the Charleston meeting. The first two days were involved with updates and reviews of the four major black liquor programs. A half day was spent discussing pathways to implementation and developing thoughts on what industry, DOE and academia could do to facilitate commercial implementation of the research results. This publication is a summary of the presentations made in Charleston and the industry responses to the research work. Readers are cautioned that the contents are in-progress updates on the status of the research and do not represent referred technical papers. Any questions regarding the content should be referred to the principal investigators of the project.

  5. Size effects on acid bisulfite pretreatment efficiency: multiple product yields in spent liquor and enzymatic digestibility of pretreated solids

    Science.gov (United States)

    Yalan Liu; Jinwu Wang; Michael P. Wolcott

    2017-01-01

    Currently, feedstock size effects on chemical pretreatment performance were not clear due to the complexity of the pretreatment process and multiple evaluation standards such as the sugar recovery in spent liquor or enzymatic digestibility. In this study, we evaluated the size effects by various ways: the sugar recovery and coproduct yields in spent liquor, the...

  6. Utilisation aspects of ashes and green liquor dregs from an integrated semichemical pulp and board mill

    Energy Technology Data Exchange (ETDEWEB)

    Manskinen, K.

    2013-09-01

    This thesis investigated the properties of bottom and fly ashes originating from a bubbling fluidised bed boiler (120 MW) using two different fuel mixtures (i.e. Fuel mixture A: coal, wood and peat; and B: wood and peat) and of the green liquor dregs originating from the associated semichemical pulp and board mill in relation to the potential utilisation of these residues from various aspects. The total concentrations of As, Cd, Cr, Cu, Ni, Pb, Zn and Hg in the bottom ashes were lower than the maximum allowable concentrations for these elements in forest fertilisers. The total Ca concentrations in bottom ashes A (2.4%; d.w.) and B (3.4%; d.w.) were lower than the legal requirement of 6.0% (d.w.) for ash used as a forest fertiliser. The total Ca concentrations in fly ashes A (6.4%; d.w.) and B (11.0%; d.w.) were higher than the minimum limit value of 6.0% (d.w.), but the concentration of As in fly ashes A (46.9 mg/kg d.w.) and B (41.3 mg/kg; d.w.) exceeded the maximum limit value of 40 mg/kg (d.w.). Only bottom ash B could be used as a forest fertiliser, provided some additional Ca is used. The bottom ashes both fulfilled the Finnish regulations on waste recovery in earth construction. Due to the elevated total concentration of PAH (23 mg/kg; d.w.) and extractable concentrations of Mo (3.9 mg/kg; d.w.) and Se (0.2 mg/kg; d.w.) in fly ash A, this residue cannot be used in covered structures. Due to the elevated concentration of PAH (90 mg/kg; d.w.) in fly ash B, this residue cannot be used in covered and paved structures. However, the utilisation of these residues as an earth construction agent is still possible, but an environmental permit would be required. According to the sequential extraction studies, extractable concentrations of most of the elements in the fly ash A were higher than those in the bottom ash A. The extractability of various elements, both in the bottom and fly ashes A, varied widely. Most of the elements did not occur as readily soluble and

  7. Potentialities of spinal liquor scanography

    International Nuclear Information System (INIS)

    Vlakhov, N.; Vylkanov, P.

    1986-01-01

    It is shown that spinal liquor scanography is a harmless and informative method for the examination of patients, permitting to detect injury foci for spinal cord tumours in 90% cases, for acute injuries of the vertebral column and spinal cord in 89.5% cases, for herniation of nucleus pulposus in 81% cases. The method of spinal liquor scanography can be used in neurology and neurosurgery to select the method of treatment and to evaluate its efficiency

  8. Mystery behind Chinese liquor fermentation

    OpenAIRE

    Jin, Guangyuan; Zhu, Yang; Xu, Yan

    2017-01-01

    Background Chinese liquor, a very popular fermented alcoholic beverage with thousands of years’ history in China, though its flavour formation and microbial process have only been partly explored, is facing the industrial challenge of modernisation and standardisation for food quality and safety as well as sustainability. Meanwhile, the hidden knowledge behind the complicated and somehow empirical solid-state fermentation process of Chinese liquor can enrich the food sector to improve our qua...

  9. A comprehensive program to develop correlations for physical properties of kraft black liquor. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Fricke, A.L.; Zaman, A.A.; Stoy, M.O.; Schmidl, G.W.; Dong, D.J.; Speck, B.

    1998-04-01

    A wide variety of experimental techniques have been used in this work, and many of these have been developed completely or improved significantly in the course of the research done during this program. Therefore, it is appropriate to describe these techniques in detail as a reference for future workers so that the techniques can be used in future work with little additional effort or so that the results reported from this program can be compared better with future results from other work. In many cases, the techniques described are for specific analytical instruments. It is recognized that these may be superseded by future developments and improvements in instrumentation if a complete description of techniques used successfully in the past on other instrumentation is available. The total pulping and liquor preparation research work performed included chip and white liquor preparation, digestion, pulp washing, liquor and wash recovery, liquor sampling, weak liquor concentration in two steps to about 45--50% solids with an intermediate soap skimming at about 140F and 27--30% solids, determination of pulp yield and Kappa number, determination of total liquor solids, and a check on the total material balance for pulping. All other research was performed either on a sample of the weak black liquor (the combined black liquor and washes from the digester) or on the skimmed liquor that had been concentrated.

  10. The effect of alkali on the product distribution from black liquor conversion under supercritical water.

    Science.gov (United States)

    Hawangchu, Y; Atong, D; Sricharoenchaikul, V

    2017-07-01

    Lignin in chemical pulping waste, or black liquor (BL), can be converted into various products via supercritical water gasification (SCWG). However, the inherited alkaline contents from the pulping chemicals may affect the product yields and properties. In this research, the influence of the residual alkali on the product distribution via SCWG of soda BL and kraft BL was evaluated. The SCWG was performed in a batch quartz reactor for 10 min at various temperatures (673, 773 and 873 K) and pressures (250, 300 and 400 bar). The highest hydrogen (H 2 ) production occurred at 873 K for the soda BL. The water-gas shift reaction with sodium ions played an important part in the H 2 production, while only small amounts of methane and carbon monoxide were detected. Hydrocarbons, carboxylic acids and esters were the dominant substrates in the liquid products, which denoted the potential of this method for bond cleaving of the lignin macromolecule. As a result, BL, which typically contains alkali salt, was an appropriate feedstock for the SCWG reaction to produce renewable fuel. This method not only has a positive influence on the generation of value added products from highly corrosive waste but also helps avoid some technical problems commonly encountered with direct firing in a recovery boiler.

  11. Chemical cleaning of UK AGR boilers

    International Nuclear Information System (INIS)

    Rudge, A.; Turner, P.; Ghosh, A.; Clary, W.; Tice, D.

    2002-01-01

    For the first time in their operational lives, UK advanced gas-cooled reactor once-through boilers have been chemically cleaned. Chemical cleaning was necessary to avoid lost output resulting from boiler pressure drops, which had been increasing for a number of years. Chemical cleaning of these boilers presents a number of unique difficulties. These include lack of access to the boilers, highly sensitised 316H superheater sections that cannot be excluded from the cleaning flow path, relatively thin boiler tube walls and an intolerance to boiler tube failure because of the role of the boilers in nuclear decay heat removal. The difficulties were overcome by implementing the clean in a staged manner, starting with an extensive materials testwork programme to select and then to substantiate the cleaning process. The selected process was based on ammoniated citric acid plus formic acid for the principal acid cleaning stage. Materials testwork was followed by an in-plant trial clean of six boiler tubes, further materials testwork and the clean of a boiler tube in a full-scale test rig. An overview is presented of the work that was carried out to demonstrate that the clean could be carried out safely, effectively and without leading to unacceptable corrosion losses. Full-scale chemical cleaning was implemented by using as much of the existing plant as possible. Careful control and monitoring was employed to ensure that the cleaning was implemented according to the specified design, thus ensuring that a safe and effective clean was carried out. Full-scale cleaning has resulted in significant boiler pressure drop recovery, even though the iron burden was relatively low and cleaning was completed in a short time. (orig.)

  12. Boilers, evaporators, and condensers

    International Nuclear Information System (INIS)

    Kakac, S.

    1991-01-01

    This book reports on the boilers, evaporators and condensers that are used in power plants including nuclear power plants. Topics included are forced convection for single-phase side heat exchangers, heat exchanger fouling, industrial heat exchanger design, fossil-fuel-fired boilers, once through boilers, thermodynamic designs of fossil fuel-first boilers, evaporators and condensers in refrigeration and air conditioning systems (with respect to reducing CFC's) and nuclear steam generators

  13. The use of biomass energy in the pulp and paper industry and the prospects for black liquor gasification combined cycle generation

    Energy Technology Data Exchange (ETDEWEB)

    Nilsson, L J [Department of Environmental and Energy Systems Studies, Lund University, Lund (Sweden)

    1995-12-01

    The world production of paper and paperboard products, which increased 3.3% per year since 1980, reached 243 million tonnes in 1991 and is expected to continue to grow by about 2.5% per year over the next decade. Consumption levels in 1990 ranged from 2.8 kg per capita in India to 313 kg per capita in the United States. The biggest producers of pulp are the United States, Canada and the Scandinavian countries, but much of the expansion of pulp production capacity is taking place in countries such as Brazil, Chile and Indonesia. The pulp and paper industry has always relied on biomass as a fuel source to meet process energy demands. Kraft pulping is the most common process accounting for about two thirds of world wood pulp production. Energy recovered from burning black liquor, a lignin-rich by-product, in a chemicals recovery boiler typically provides most of the on-site demand for heat and electricity in a modem kraft pulp mill. Another important fuel source is bark and wood waste generated at the mill. Aging recovery boilers in industrialized countries and increasing electricity/heat demand ratios are stimulating interest in alternative co-generation technologies. Most of the interest in new biomass and black liquor co-generation technologies focuses on those that would utilize gas turbines rather than steam turbines. Gas turbines are generally characterized by higher electricity/heat ratios than steam turbines, as well as lower unit capital costs. With the black liquor and biomass gasification technologies that are now being developed and demonstrated, the energy needs of an energy-efficient kraft pulp mill could be met and 40-50 MW of baseload power would be available for export. Using, in addition, currently unused logging residues for fuel would increase that potential. The pulp and paper industry is likely to be an important early market for advanced biomass-based cogeneration technology owing to its access to biomass fuels and the potential for co

  14. The use of biomass energy in the pulp and paper industry and the prospects for black liquor gasification combined cycle generation

    International Nuclear Information System (INIS)

    Nilsson, L.J.

    1995-01-01

    The world production of paper and paperboard products, which increased 3.3% per year since 1980, reached 243 million tonnes in 1991 and is expected to continue to grow by about 2.5% per year over the next decade. Consumption levels in 1990 ranged from 2.8 kg per capita in India to 313 kg per capita in the United States. The biggest producers of pulp are the United States, Canada and the Scandinavian countries, but much of the expansion of pulp production capacity is taking place in countries such as Brazil, Chile and Indonesia. The pulp and paper industry has always relied on biomass as a fuel source to meet process energy demands. Kraft pulping is the most common process accounting for about two thirds of world wood pulp production. Energy recovered from burning black liquor, a lignin-rich by-product, in a chemicals recovery boiler typically provides most of the on-site demand for heat and electricity in a modem kraft pulp mill. Another important fuel source is bark and wood waste generated at the mill. Aging recovery boilers in industrialized countries and increasing electricity/heat demand ratios are stimulating interest in alternative co-generation technologies. Most of the interest in new biomass and black liquor co-generation technologies focuses on those that would utilize gas turbines rather than steam turbines. Gas turbines are generally characterized by higher electricity/heat ratios than steam turbines, as well as lower unit capital costs. With the black liquor and biomass gasification technologies that are now being developed and demonstrated, the energy needs of an energy-efficient kraft pulp mill could be met and 40-50 MW of baseload power would be available for export. Using, in addition, currently unused logging residues for fuel would increase that potential. The pulp and paper industry is likely to be an important early market for advanced biomass-based cogeneration technology owing to its access to biomass fuels and the potential for co

  15. Mystery behind Chinese liquor fermentation

    NARCIS (Netherlands)

    Jin, Guangyuan; Zhu, Yang; Xu, Yan

    2017-01-01

    Background Chinese liquor, a very popular fermented alcoholic beverage with thousands of years’ history in China, though its flavour formation and microbial process have only been partly explored, is facing the industrial challenge of modernisation and standardisation for food quality and safety as

  16. Indication of the incineration situation using image analysis of the grate boilers fireplace; Indikation av foerbraenningssituationen genom bildanalys av rostens eldstad

    Energy Technology Data Exchange (ETDEWEB)

    Persson, Anna; Helgesson, Johan [Vattenfall Utveckling AB, Aelvkarleby (Sweden)

    2004-12-01

    Vattenfall Utveckling AB has earlier performed tests where the incineration situation in a black liquor recovery boiler (BLRB) has been investigated using a simple water-cooled camera. It was also shown possible to repress emission lines for e.g., sodium. These results led to wishes of performing the same tests in a grate boiler. Initially in the project, an investigation about what effect optical filters has on the image from a camera that captures the incineration situation in a grate boiler. The goal was to improve the conditions for flame front detection using image analysis, i.e., to increase the contrast between flames (the flame front) and no flames (bed, ashes, walls etc.). The result was that the image improvement optical filters were predicted to give, did not happen. The conclusion of the investigation is therefore that the best result is achieved when no information-reducing filters are used in front of the camera. However, for cameras using automatic shutter, intensity-reducing filters are recommended. After that, an image analysis algorithm to automatically detect the location of the flame front on the bed was implemented. The evaluation of the algorithm was successfully performed on movies from three grate boilers. This method should be possible to implement for all types of grate boilers, regardless of size and fuel type. However, the material (e.g., wide angle objective) and the placement of the camera have to be individually adjusted. In a future project, the goal is to be able to reconnect this information about the instant incineration situation to the control system to control e.g., the air supply or the fuel feed. This could lead to lower emissions, higher efficiency and an operation less sensitive against changes in fuel quality.

  17. Performance Analysis of a Reciprocating Piston Expander and a Plate Type Exhaust Gas Recirculation Boiler in a Water-Based Rankine Cycle for Heat Recovery from a Heavy Duty Diesel Engine

    Directory of Open Access Journals (Sweden)

    Gunnar Latz

    2016-06-01

    Full Text Available The exhaust gas in an internal combustion engine provides favorable conditions for a waste-heat recovery (WHR system. The highest potential is achieved by the Rankine cycle as a heat recovery technology. There are only few experimental studies that investigate full-scale systems using water-based working fluids and their effects on the performance and operation of a Rankine cycle heat recovery system. This paper discusses experimental results and practical challenges with a WHR system when utilizing heat from the exhaust gas recirculation system of a truck engine. The results showed that the boiler’s pinch point necessitated trade-offs between maintaining adequate boiling pressure while achieving acceptable cooling of the EGR and superheating of the water. The expander used in the system had a geometric compression ratio of 21 together with a steam outlet timing that caused high re-compression. Inlet pressures of up to 30 bar were therefore required for a stable expander power output. Such high pressures increased the pump power, and reduced the EGR cooling in the boiler because of pinch-point effects. Simulations indicated that reducing the expander’s compression ratio from 21 to 13 would allow 30% lower steam supply pressures without adversely affecting the expander’s power output.

  18. Life extension of boilers using weld overlay protection

    Energy Technology Data Exchange (ETDEWEB)

    Lai, G.; Hulsizer, P. [Welding Services Inc., Norcross, GA (United States); Brooks, R. [Welding Services Inc., Welding Services Europe, Spijkenisse (Netherlands)

    1998-12-31

    The presentation describes the status of modern weld overlay technology for refurbishment, upgrading and life extension of boilers. The approaches to life extension of boilers include field overlay application, shop-fabricated panels for replacement of the worn, corroded waterwall and shop-fabricated overlay tubing for replacement of individual tubes in superheaters, generating banks and other areas. The characteristics of weld overlay products are briefly described. Also discussed are successful applications of various corrosion-resistant overlays for life extension of boiler tubes in waste-to-energy boilers, coal-fired boilers and chemical recovery boilers. Types of corrosion and selection of weld overlay alloys in these systems are also discussed. (orig.) 14 refs.

  19. Life extension of boilers using weld overlay protection

    Energy Technology Data Exchange (ETDEWEB)

    Lai, G; Hulsizer, P [Welding Services Inc., Norcross, GA (United States); Brooks, R [Welding Services Inc., Welding Services Europe, Spijkenisse (Netherlands)

    1999-12-31

    The presentation describes the status of modern weld overlay technology for refurbishment, upgrading and life extension of boilers. The approaches to life extension of boilers include field overlay application, shop-fabricated panels for replacement of the worn, corroded waterwall and shop-fabricated overlay tubing for replacement of individual tubes in superheaters, generating banks and other areas. The characteristics of weld overlay products are briefly described. Also discussed are successful applications of various corrosion-resistant overlays for life extension of boiler tubes in waste-to-energy boilers, coal-fired boilers and chemical recovery boilers. Types of corrosion and selection of weld overlay alloys in these systems are also discussed. (orig.) 14 refs.

  20. Generation of Hydrogen, Lignin and Sodium Hydroxide from Pulping Black Liquor by Electrolysis

    Directory of Open Access Journals (Sweden)

    Guangzai Nong

    2015-12-01

    Full Text Available Black liquor is generated in Kraft pulping of wood or non-wood raw material in pulp mills, and regarded as a renewable resource. The objective of this paper was to develop an effective means to remove the water pollutants by recovery of both lignin and sodium hydroxide from black liquor, based on electrolysis. The treatment of a 1000 mL of black liquor (122 g/L solid contents consumed 345.6 kJ of electric energy, and led to the generation of 30.7 g of sodium hydroxide, 0.82 g of hydrogen gas and 52.1 g of biomass solids. Therefore, the recovery ratios of elemental sodium and biomass solids are 80.4% and 76%, respectively. Treating black liquor by electrolysis is an environmentally friendly technology that can, in particular, be an alternative process in addressing the environmental issues of pulping waste liquor to the small-scale mills without black liquor recovery.

  1. Boiler water regime

    Science.gov (United States)

    Khavanov, Pavel; Chulenyov, Anatoly

    2017-10-01

    Active development of autonomous heating the past 25 years has led to the widespread use of hot-water boilers of small capacity up to 2.5 MW. Rational use of the design of autonomous sources of heating boilers design features significantly improve their technical, economic and operational performance. This publication reviewed and analyzed a number of features of the design, operation and exploitation of boilers of small capacity, significantly affecting the efficiency and reliability of their application.

  2. Boiler conversions for biomass

    Energy Technology Data Exchange (ETDEWEB)

    Kinni, J [Tampella Power Inc., Tampere (Finland)

    1997-12-31

    Boiler conversions from grate- and oil-fired boilers to bubbling fluidized bed combustion have been most common in pulp and paper industry. Water treatment sludge combustion, need for additional capacity and tightened emission limits have been the driving forces for the conversion. To accomplish a boiler conversion for biofuel, the lower part of the boiler is replaced with a fluidized bed bottom and new fuel, ash and air systems are added. The Imatran Voima Rauhalahti pulverized-peat-fired boiler was converted to bubbling fluidized bed firing in 1993. In the conversion the boiler capacity was increased by 10 % to 295 MWth and NO{sub x} emissions dropped. In the Kymmene Kuusankoski boiler, the reason for conversion was the combustion of high chlorine content biosludge. The emissions have been under general European limits. During the next years, the emission limits will tighten and the boilers will be designed for most complete combustion and compounds, which can be removed from flue gases, will be taken care of after the boiler. (orig.) 3 refs.

  3. Boiler conversions for biomass

    Energy Technology Data Exchange (ETDEWEB)

    Kinni, J. [Tampella Power Inc., Tampere (Finland)

    1996-12-31

    Boiler conversions from grate- and oil-fired boilers to bubbling fluidized bed combustion have been most common in pulp and paper industry. Water treatment sludge combustion, need for additional capacity and tightened emission limits have been the driving forces for the conversion. To accomplish a boiler conversion for biofuel, the lower part of the boiler is replaced with a fluidized bed bottom and new fuel, ash and air systems are added. The Imatran Voima Rauhalahti pulverized-peat-fired boiler was converted to bubbling fluidized bed firing in 1993. In the conversion the boiler capacity was increased by 10 % to 295 MWth and NO{sub x} emissions dropped. In the Kymmene Kuusankoski boiler, the reason for conversion was the combustion of high chlorine content biosludge. The emissions have been under general European limits. During the next years, the emission limits will tighten and the boilers will be designed for most complete combustion and compounds, which can be removed from flue gases, will be taken care of after the boiler. (orig.) 3 refs.

  4. Combustion properties of kraft black liquors; Ligniinifraktion vaikutus mustalipeaen poltto-ominaisuuksiin

    Energy Technology Data Exchange (ETDEWEB)

    Alen, R.; Rantanen, K.; Ekman, J.; Malkavaara, P. [Jyvaeskylae Univ. (Finland)

    1996-12-01

    The aim of this investigation was to find relationships between the structure of the dissolved lignin and the combustion properties (pyrolysis time, char burning time, and swelling) of softwood and hardwood kraft black liquors. In this conjunction, pine and birch chips, as well as their two mixtures (the mass ratios of pine chips to birch chips were 80:20 and 60:40), were delignified by conventional kraft pulping. In each cook series, a liquor sample was withdrawn at certain time intervals to obtain liquor samples with different chemical composition. The black liquors obtained were analyzed with respect to the content of lignin and `lignin monomers`, but also the molecular-mass distribution and the mass average molecular mass of lignin were made. In addition, the dissolved lignin was characterized by NMR spectroscopy and elemental analysis. Further data on the chemical structures of lignin in black liquors were obtained by identifying various degradation products formed from this material during oxidative (CuO oxidation) and pyrolytic treatments. Several correlations between the `structural parameters` of the dissolved lignin and the combustion properties of black liquor were found. These correlations were significant especially in the case of pine cook. The results revealed many findings which are, together with the earlier data, useful for a better understanding of the thermochemical behavior of different kraft black liquors during combustion in a recovery furnace. (author)

  5. Energy recovery and emissions of PBDD/Fs and PBDEs from cocombustion of woodchip and wastewater sludge in an industrial boiler.

    Science.gov (United States)

    Chang, Shun-Shiang Chang; Lee, Wen-Jhy Lee; Wang, Lin-Chi Wang; Chang-Chien, Guo-Ping Chang-Chien; Wu, Chang-Yu

    2013-01-01

    The emissions of polybrominated dibenzo-pdioxins,dibenzofurans (PBDD/Fs), and polybrominated diphenyl ethers (PBDEs) from trial combustion of 10 wt % dried industrial wastewater-treatment sludge (IWTS) and 90 wt % woodchip in an industrial boiler were investigated and compared to that from woodchip combustion. The PBDD/F toxic equivalent (TEQ) andPBDE emissions increased from 0.121 pg TEQ Nm−3 and 2260 pgNm−3, respectively, of the woodchip combustion to 0.211 pg TEQNm−3 and 4200 pg Nm−3, respectively, of the trial combustion.PBDD/F and PBDE congener profiles of inputs and outputs of the same type of combustion were similar; they also show similarity between woodchip and trial combustions, revealing that the destruction pathway was little affected by the introduction of the IWTS. The fates of PBDD/Fs and PBDEs show that the indigenous pollutants in the feed were effectively depleted (>93.5%). The dominant releasing route of PBDD/F and PBDE shifted from the stack flue gas of woodchip combustion to the ashes of trial combustion. This study demonstrates that co-combustion not only handles the fast growing sludge stream but also yields a saving of 26.3% in the fuel cost and treatment fees of sludge and ashes.

  6. Electric utility CFB boilers

    International Nuclear Information System (INIS)

    Fairbanks, D.A.

    1991-01-01

    This paper reports on Circulating Fluidized Bed (CFB) boiler technology which caught the attention of boiler users: first for its technical advantages of reduced air emissions and low grade fuel tolerance, then later for its problems in becoming a reliable process. Refractory longevity and fuel feed reliability plagued a number of new installations. The efficacy of CFB technology is now more assured with the recent success of Texas-New Mexico Power Company's 160 MWe CFB based units, the world's largest operating CFB boilers. Most of the more notable CFB development problems have been successfully addressed by these units. The TNP units have demonstrated that CFB's can reliable produce high capacity factors at low emission rates using a fuel that has traditionally hampered the operation of pulverized coal (PC) boilers and without the attendant problems associated with sulfur scrubbers required by PC boilers

  7. CECIL lances Bruce's boilers

    International Nuclear Information System (INIS)

    Malaugh, J.; Monaghan, D.

    1994-01-01

    Over the past few years Ontario Hydro has become increasingly concerned about accumulations of sludge in its nuclear plant boilers, so a comprehensive sludge management programme has been instituted to combat build-up. This included developing the tele-operated robot CECIL (Consolidated Edison Combined Inspection and Lancing) equipment, originally designed for work in PWRs, for CANDU boilers. This required a significantly reconfigured robotic system as well as modifications to the boilers themselves. Work on the Bruce A reactor is described. (4 figures). (author)

  8. Design of special facility for liquor irradiation

    International Nuclear Information System (INIS)

    Yao Shibin; Chen Zigen

    1989-01-01

    The design principle, physical scheme, technological process, construction and safety features of a special facility used for irradiating liquors is briefly described. 0.925 x 10 15 Bq cobalt source is used and the irradiation capacity for liquors approaches 10 t per day. The facility bears advantages of simple in construction, easy to operate, safe, reliable and efficient in source utilization

  9. Liquor circulation disturbance after subarachnoid haemorrhages - comparative pneumoencephalography and liquor scintigraphic investigations

    International Nuclear Information System (INIS)

    Menzel, J.; Georgi, P.; Krastel, A.; Deutsches Krebsforschungszentrum, Heidelberg

    1976-01-01

    Haemorrhages into the subarachnoid space often lead to instant blocking of the liquor circulation pathways with an acute increase of the intracranial pressure and acute venticular enlargement. These liquor circulation disturbances may be diagnosed by liquor scintiscanning as well as by pneumoencephalography. 165 patients were examined by both methods. The following results were obtained: liquor circulation disturbances after subarachnoid bleeding are frequent, they should be expected in 33% of all cases after spontaneous subarachnoid haemorrhages and in 68% of the cases after traumatic subarachnoid haemorrhages. The most severe form of liquor circulation distrubance may also be diagnosed by liquor scintiscanning as well as by pneumoencephalography. Liquor scintiscanning is the more exact method in cases with transitory ventricular reflux, while lumbar pneumoencephalography, in this series, is the method of choice when it comes to documenting the extent of the hydrocephalus. (GSE) [de

  10. ENERGY STAR Certified Boilers

    Data.gov (United States)

    U.S. Environmental Protection Agency — Certified models meet all ENERGY STAR requirements as listed in the Version 3.0 ENERGY STAR Program Requirements for Boilers that are effective as of October 1,...

  11. Charting the boiler market

    International Nuclear Information System (INIS)

    2003-01-01

    The ''boiler market'' of electricity, sometimes called unsecured transmission, is electric power consumption that in public statistics is restricted by the obligation of the customers to cut their consumption at short notice and therefore are granted some discount on the network lease. The present document is part of a project that aims to provide a better understanding of the flexibility in the Norwegian power market, limited by the power-intensive industry and the boiler market. It discusses the boiler market. It begins with a discusses of the available statistics, where different sources show very dissimilar consumption figures. Then it examines how the consumption in the boiler market developed during the winter 2002/2003. Finally, there is a description of the regulations of unsecured transmission and how the various network owners adapt to the regulations.

  12. Dynamic Boiler Performance

    DEFF Research Database (Denmark)

    Sørensen, Kim

    Traditionally, boilers have been designed mainly focussing on the static operation of the plant. The dynamic capability has been given lower priority and the analysis has typically been limited to assuring that the plant was not over-stressed due to large temperature gradients. New possibilities...... developed. Analyzing boilers for dynamic operation gives rise to a number of opposing aims: shrinking and swelling, steam quality, stress levels, control system/philosophy, pressurization etc. Common for these opposing aims is that an optimum can be found for selected operation conditions. The framework has...... for buying and selling energy has increased the focus on the dynamic operation capability, efciency, emissions etc. For optimizing the design of boilers for dynamic operation a quantication of the dynamic capability is needed. A framework for optimizing design of boilers for dynamic operation has been...

  13. Integration of the Mini-Sulfide Sulfite Anthraquinone (MSS-AQ) Pulping Process and Black Liquor Gasification in a Pulp Mill

    Energy Technology Data Exchange (ETDEWEB)

    Hasan Jameel, North Carolina State University; Adrianna Kirkman, North Carolina State University; Ravi Chandran,Thermochem Recovery International Brian Turk Research Triangle Institute; Brian Green, Research Triangle Institute

    2010-01-27

    As many of the recovery boilers and other pieces of large capital equipment of U.S. pulp mills are nearing the end of their useful life, the pulp and paper industry will soon need to make long-term investments in new technologies. The ability to install integrated, complete systems that are highly efficient will impact the industry’s energy use for decades to come. Developing a process for these new systems is key to the adoption of state-of-the-art technologies in the Forest Products industry. This project defined an integrated process model that combines mini-sulfide sulfite anthraquinone (MSS-AQ) pulping and black liquor gasification with a proprietary desulfurization process developed by the Research Triangle Institute. Black liquor gasification is an emerging technology that enables the use of MSS-AQ pulping, which results in higher yield, lower bleaching cost, lower sulfur emissions, and the elimination of causticization requirements. The recently developed gas cleanup/absorber technology can clean the product gas to a state suitable for use in a gas turbine and also regenerate the pulping chemicals needed to for the MSS-AQ pulping process. The combination of three advanced technologies into an integrated design will enable the pulping industry to achieve a new level of efficiency, environmental performance, and cost savings. Because the three technologies are complimentary, their adoption as a streamlined package will ensure their ability to deliver maximum energy and cost savings benefits. The process models developed by this project will enable the successful integration of new technologies into the next generation of chemical pulping mills. When compared to the Kraft reference pulp, the MSS-AQ procedures produced pulps with a 10-15 % yield benefit and the ISO brightness was 1.5-2 times greater. The pulp refined little easier and had a slightly lower apparent sheet density (In both the cases). At similar levels of tear index the MSS-AQ pulps also

  14. MODELLING, SIMULATING AND OPTIMIZING BOILERS

    DEFF Research Database (Denmark)

    Sørensen, Kim; Condra, Thomas Joseph; Houbak, Niels

    2004-01-01

    In the present work a framework for optimizing the design of boilers for dynamic operation has been developed. A cost function to be minimized during the optimization has been formulated and for the present design variables related to the Boiler Volume and the Boiler load Gradient (i.e. ring rate...... on the boiler) have been dened. Furthermore a number of constraints related to: minimum and maximum boiler load gradient, minimum boiler size, Shrinking and Swelling and Steam Space Load have been dened. For dening the constraints related to the required boiler volume a dynamic model for simulating the boiler...... performance has been developed. Outputs from the simulations are shrinking and swelling of water level in the drum during for example a start-up of the boiler, these gures combined with the requirements with respect to allowable water level uctuations in the drum denes the requirements with respect to drum...

  15. Uranium adsorption from the sulphuric acid leach liquor containing more chlorides with cation-exchange resin SL-406

    International Nuclear Information System (INIS)

    Hu Jun; Wang Zhaoguo; Chi Renqing; Niu Xuejun

    1994-01-01

    The feasibility of uranium adsorption was studied from the sulphuric acid leach liquor of a uranium ore containing more chlorides with cation-exchange resin SL-406. The influence of some factors on uranium adsorption was investigated. It was shown that the resin possesses better selectivity, stability and higher capacity. It can be effectively used to recovery uranium from leach liquors of uranium ores containing more chlorides

  16. Pressurized pyrolysis and gasification behaviour of black liquor and biofuels

    Energy Technology Data Exchange (ETDEWEB)

    Whitty, K.; Backman, R.; Hupa, M. [Aabo Akademi, Turku (Finland)

    1996-12-01

    The objective of this project is to obtain basic experimental data on pyrolysis and gasification of various black liquors and biofuels at elevated pressures, and to model these processes. Liquor-to-liquor differences in conversion behavior of single liquor droplets during gasification at atmospheric pressure were investigated. The applicability of a rate equation developed for catalyzed gasification of carbon was investigated with regard to pressurized black liquor gasification. A neural network was developed to simulate the progression of char conversion during pressurized black liquor gasification. Pyrolysis of black liquor in a pressurized drop-tube furnace was investigated in collaboration with KTH in Stockholm. (author)

  17. Super Boiler: First Generation, Ultra-High Efficiency Firetube Boiler

    Energy Technology Data Exchange (ETDEWEB)

    None

    2006-06-01

    This factsheet describes a research project whose goal is to develop and demonstrate a first-generation ultra-high-efficiency, ultra-low emissions, compact gas-fired package boiler (Super Boiler), and formulate a long-range RD&D plan for advanced boiler technology out to the year 2020.

  18. Utilization of spent sulfite liquor carbohydrates

    Energy Technology Data Exchange (ETDEWEB)

    Wiley, A J; Whitmore, L M; Boggs, Jr, L A

    1959-01-01

    Possible utilization of the sugars in spent sulfite liquor in the manufacture of ethanol, torula food yeast, and other fermentation products, and in the production of sugar derivatives, such as the diacetone derivatives, is discussed.

  19. Condensing boiler applications in the process industry

    International Nuclear Information System (INIS)

    Chen, Qun; Finney, Karen; Li, Hanning; Zhang, Xiaohui; Zhou, Jue; Sharifi, Vida; Swithenbank, Jim

    2012-01-01

    Major challenging issues such as climate change, energy prices and fuel security have focussed the attention of process industries on their energy efficiency and opportunities for improvement. The main objective of this research study was to investigate technologies needed to exploit the large amount of low grade heat available from a flue gas condensing system through industrial condensing boilers. The technology and application of industrial condensing boilers in various heating systems were extensively reviewed. As the condensers require site-specific engineering design, a case study was carried out to investigate the feasibility (technically and economically) of applying condensing boilers in a large scale district heating system (40 MW). The study showed that by recovering the latent heat of water vapour in the flue gas through condensing boilers, the whole heating system could achieve significantly higher efficiency levels than conventional boilers. In addition to waste heat recovery, condensing boilers can also be optimised for emission abatement, especially for particle removal. Two technical barriers for the condensing boiler application are corrosion and return water temperatures. Highly corrosion-resistant material is required for condensing boiler manufacture. The thermal design of a 'case study' single pass shell-and-tube condensing heat exchanger/condenser showed that a considerable amount of thermal resistance was on the shell-side. Based on the case study calculations, approximately 4900 m 2 of total heat transfer area was required, if stainless steel was used as a construction material. If the heat transfer area was made of carbon steel, then polypropylene could be used as the corrosion-resistant coating material outside the tubes. The addition of polypropylene coating increased the tube wall thermal resistance, hence the required heat transfer area was approximately 5800 m 2 . Net Present Value (NPV) calculations showed that the choice of a carbon

  20. Optimising boiler performance.

    Science.gov (United States)

    Mayoh, Paul

    2009-01-01

    Soaring fuel costs continue to put the squeeze on already tight health service budgets. Yet it is estimated that combining established good practice with improved technologies could save between 10% and 30% of fuel costs for boilers. Paul Mayoh, UK technical manager at Spirax Sarco, examines some of the practical measures that healthcare organisations can take to gain their share of these potential savings.

  1. Millwright Apprenticeship. Related Training Modules. 7.1-7.9 Boilers.

    Science.gov (United States)

    Lane Community Coll., Eugene, OR.

    This packet, part of the instructional materials for the Oregon apprenticeship program for millwright training, contains nine modules covering boilers. The modules provide information on the following topics: fire and water tube types of boilers, construction, fittings, operation, cleaning, heat recovery systems, instruments and controls, and…

  2. Bio-refinery system of DME or CH4 production from black liquor gasification in pulp mills.

    Science.gov (United States)

    Naqvi, M; Yan, J; Fröling, M

    2010-02-01

    There is great interest in developing black liquor gasification technology over recent years for efficient recovery of bio-based residues in chemical pulp mills. Two potential technologies of producing dimethyl ether (DME) and methane (CH(4)) as alternative fuels from black liquor gasification integrated with the pulp mill have been studied and compared in this paper. System performance is evaluated based on: (i) comparison with the reference pulp mill, (ii) fuel to product efficiency (FTPE) and (iii) biofuel production potential (BPP). The comparison with the reference mill shows that black liquor to biofuel route will add a highly significant new revenue stream to the pulp industry. The results indicate a large potential of DME and CH(4) production globally in terms of black liquor availability. BPP and FTPE of CH(4) production is higher than DME due to more optimized integration with the pulping process and elimination of evaporation unit in the pulp mill.

  3. Clarification of Orange Press Liquors by PVDF Hollow Fiber Membranes

    Directory of Open Access Journals (Sweden)

    Silvia Simone

    2016-01-01

    Full Text Available Press liquors are typical by-products of the citrus juice processing characterized by a high content of organic compounds and associated problems of environmental impact, which imply high treatment costs. However, these wastes contain a great number of health promoting substances, including fibers, carotenoids and phenolic compounds (mainly flavonoids, whose recovery against waste-destruction technologies is very attractive for new business opportunities. In this work, the clarification of orange press liquor by using microfiltration (MF membranes is studied as a preliminary step to obtain a permeate stream enriched in antioxidant compounds which can be further processed to produce extracts of nutraceutical and/or pharmaceutical interest. MF poly(vinylidene fluoride (PVDF hollow fibers were prepared by the dry/wet spinning technique. A series of fibers was produced from the same polymeric dope, in order to investigate the effect of selected spinning parameters, i.e., bore fluid composition and flowrate, on their properties. The morphology of the produced fibers was analyzed by Scanning Electron Microscopy (SEM. Fibers were further characterized for their mechanical properties, porosity, bubble point, pore size distribution and pure water permeability (PWP. Some of the produced fibers exhibited high permeability (pure water permeability ~530 L/m2·h·bar, coupled to good mechanical resistance and pore size in the range of MF membranes. These fibers were selected and used for the clarification of press liquor from orange peel processing. In optimized operating conditions, the selected fibers produced steady-state fluxes of about 41 L/m2·h with rejections towards polyphenols and total antioxidant activity of 4.1% and 1.4%, respectively.

  4. Fouling control in biomass boilers

    Energy Technology Data Exchange (ETDEWEB)

    Romeo, Luis M.; Gareta, Raquel [Centro de Investigacion de Recursos y Consumos Energeticos (CIRCE), Universidad de Zaragoza, Centro Politecnico Superior, Maria de Luna, 3, 50018 Zaragoza (Spain)

    2009-05-15

    One of the important challenges for biomass combustion in industrial applications is the fouling tendency and how it affects to the boiler performance. The classical approach for this question is to activate sootblowing cycles with different strategies to clean the boiler (one per shift, one each six hours..). Nevertheless, it has been often reported no effect on boiler fouling or an excessive steam consumption for sootblowing. This paper illustrates the methodology and the application to select the adequate time for activating sootblowing in an industrial biomass boiler. The outcome is a control strategy developed with artificial intelligence (Neural Network and Fuzzy Logic Expert System) for optimizing the biomass boiler cleaning and maximizing heat transfer along the time. Results from an optimize sootblowing schedule show savings up to 12 GWh/year in the case-study biomass boiler. Extra steam generation produces an average increase of turbine power output of 3.5%. (author)

  5. Mod increases AGR boiler output

    International Nuclear Information System (INIS)

    Jones, W.K.C.; Rider, G.; Taylor, D.E.

    1986-01-01

    During the commissioning runs of the first reactor units at Heysham I and Hartlepool Advanced Gas-cooled Reactors (AGRs), non-uniform temperature distributions were observed across individual boiler units which were more severe than those predicted from the design analysis. This article describes the re-orificing (referruling) of the boilers to overcome this problem. The referruling has reduced boiler sensitivity and resulted in an increase of load of 7 or 8%. (U.K.)

  6. Single particle studies of black liquor gasification under pressurized conditions

    Energy Technology Data Exchange (ETDEWEB)

    Whitty, K; Backman, R; Hupa, M; Backman, P; Ek, P; Hulden, S T; Kullberg, M; Sorvari, V

    1997-10-01

    The purpose of this project is to provide experimental data relevant to pressurized black liquor gasification concepts. Specifically, the following two goals will be achieved: Data on swelling, char yields and component release during pressurized pyrolysis of small samples of black liquor will be obtained. The reactivity and physical behavior of single black liquor droplets during simultaneous pyrolysis and gasification will be investigated. The structure and composition of black liquor char during formation and conversion will be studied. (orig.)

  7. Liquor licences issued to Australian schools.

    Science.gov (United States)

    Ward, Bernadette M; Kippen, Rebecca; Munro, Geoffrey; Buykx, Penny; McBride, Nyanda; Wiggers, John; Clark, Madeline

    2017-08-01

    Children's positive socialisation to alcohol is associated with early initiation of drinking and alcohol-related harm in adult life. Internationally, there have been reports of adults' alcohol consumption at school events in the presence of children. The aim of this research was to identify the conditions under which Australian schools are required to apply for a liquor licence and the associated prevalence of liquor licences for these events where children were likely to be present. A document review was conducted to examine temporary liquor licensing legislation. Quantitative analysis was used to examine relevant licensing data. Coding criteria was developed to determine school type, student year levels and the likely presence of children. Four jurisdictions provided data on 1817 relevant licences. The average annual licences/100 schools was highest amongst Independent schools followed by Catholic and public (government) schools. The rates were highest in Queensland and Victoria where children were present at 61% and 32% of events respectively. While there are legislative differences across jurisdictions, the prevalence of adults' alcohol use at school events in the presence of children may reflect the various education department policies and principals' and school communities' beliefs and attitudes. Licences are not required for all events where liquor is consumed so the prevalence of adults' use of alcohol at school events is likely to be higher than our analyses imply. Such practices may undermine teaching about alcohol use in the school curriculum and health promotion efforts to develop alcohol-free events when children are present.

  8. 21 CFR 163.111 - Chocolate liquor.

    Science.gov (United States)

    2010-04-01

    ... CONSUMPTION CACAO PRODUCTS Requirements for Specific Standardized Cacao Products § 163.111 Chocolate liquor... ingredients. The following safe and suitable ingredients may be used: (1) Cacao fat and cocoas (breakfast cocoa, cocoa, or lowfat cocoa); (2) Alkali ingredients. Ammonium, potassium, or sodium bicarbonate...

  9. Daqu - a traditional Chinese liquor fermentation starter

    NARCIS (Netherlands)

    Zheng, X.; Rezaei Tabrizi, M.; Nout, M.J.R.; Han, B.

    2011-01-01

    Chinese liquor is one of the world's oldest distilled alcoholic beverages, and it is typically obtained with the use of Daqufermentation starters. Daqu is a saccharifying and fermenting agent, having a significant impact on the flavour of the product. Daqucan be categorized according to maximum

  10. Boiler tube failure prevention in fossil fired boilers

    International Nuclear Information System (INIS)

    Townsend, R.D.

    1993-01-01

    It is the common experience of power generating companies worldwide that the main causes of forced outages on power plant are those due to boiler tube failures on fossil units. The main reason for the large number of failures are the severe environmental conditions in fossil boilers as the effects of stress, temperature, temperature gradients, corrosion, erosion and vibration combine to produce degradation of the tube steel. Corrosion by oxidation, by combustion products and by impure boiler water can significantly reduce the tube wall thickness and result in failure of a tube many years before its designed service life. Errors can also occur in the design manufacturer, storage, operation, and maintenance of boiler tubing and the wrong material installed in a critical location can lead to premature failure. Altogether, experts in the US and UK, from many different disciplines, have identified seven broad categories of boiler tube failure mechanisms. 1 tab., 2 figs

  11. Improved nuclear boiler

    International Nuclear Information System (INIS)

    Pierart, Robert.

    1980-01-01

    The improved nuclear boiler concerned in this invention is of the kind comprising, inter alia, a nuclear reactor supported by a metallic structure and of which the vessel is at least enclosed in part by a casing acting as a protective containment integrated in this structure. It is essentially characterized in that this casing is fitted into and maintained in position in the metallic structure by removable locking devices which enable the casing to be withdrawn from the remainder of the structure. Hence, after the casing has been withdrawn or removed from the metallic structure, access to the reactor vessel is readily obtained for inspection and/or testing from without [fr

  12. Factors affecting stress assisted corrosion cracking of carbon steel under industrial boiler conditions

    Science.gov (United States)

    Yang, Dong

    Failure of carbon steel boiler tubes from waterside has been reported in the utility boilers and industrial boilers for a long time. In industrial boilers, most waterside tube cracks are found near heavy attachment welds on the outer surface and are typically blunt, with multiple bulbous features indicating a discontinuous growth. These types of tube failures are typically referred to as stress assisted corrosion (SAC). For recovery boilers in the pulp and paper industry, these failures are particularly important as any water leak inside the furnace can potentially lead to smelt-water explosion. Metal properties, environmental variables, and stress conditions are the major factors influencing SAC crack initation and propagation in carbon steel boiler tubes. Slow strain rate tests (SSRT) were conducted under boiler water conditions to study the effect of temperature, oxygen level, and stress conditions on crack initation and propagation on SA-210 carbon steel samples machined out of boiler tubes. Heat treatments were also performed to develop various grain size and carbon content on carbon steel samples, and SSRTs were conducted on these samples to examine the effect of microstructure features on SAC cracking. Mechanisms of SAC crack initation and propagation were proposed and validated based on interrupted slow strain tests (ISSRT). Water chemistry guidelines are provided to prevent SAC and fracture mechanics model is developed to predict SAC failure on industrial boiler tubes.

  13. Application of a mechanism-based rate equation to black liquor gasification rate data

    Energy Technology Data Exchange (ETDEWEB)

    Overacker, N.L.; Waag, K.J.; Frederick, W.J. [Oregon State University, OR (United States). Dept. of Chemical Engineering; Whitty, K.J.

    1995-09-01

    There is growing interest worldwide to develop alternate chemical recovery processes for paper mills which are cheaper, safer, more efficient and more environmentally sound than traditional technology. Pressurized gasification of black liquor is the basis for many proposed schemes and offers the possibility to double the amount of electricity generated per unit of dry black liquor solids. Such technology also has capital, safety and environmental advantages. One of the most important considerations regarding this emerging technology is the kinetics of the gasification reaction. This has been studied empirically at Aabo Akademi University for the pressurized gasification with carbon dioxide and steam. For the purposes of reactor modeling and scale-up, however, a thorough understanding of the mechanism behind the reaction is desirable. This report discusses the applicability of a mechanism-based rate equation to gasification of black liquor. The mechanism considered was developed for alkali-catalyzed gasification of carbon and is tested using black liquor gasification data obtained during simultaneous reaction with H{sub 2}O and CO. Equilibrium considerations and the influence of the water-gas shift reaction are also discussed. The work presented here is a cooperative effort between Aabo Akademi University and Oregon State University. The experimental work and some of the data analysis was performed at Aabo Akademi University. Development of the models and consideration of their applicability was performed primarily at Oregon State University

  14. Stabilization of ash from combustion of MSW in a fluidised bed boiler

    Energy Technology Data Exchange (ETDEWEB)

    Steenari, Britt-Marie; Wilewska, Magda [Chalmers Univ. of Technology, Goeteborg (Sweden). Dept. of Environmental Inorganic Chemistry

    2004-06-01

    Due to restrictions against the land filling of combustible waste and directives from authorities that favour energy recovery from the waste, combustion of household waste is becoming more common. Even though combustion of MSW reduces the volume of waste to be handled by approximately 90%, it produces ash residues containing most of the metals present in the original fuel and a number of other species carried through the boiler or formed during combustion. The residues can be divided into three categories: 1. Stable, inert ash that can be utilised in, for example, construction applications 2. Ash that is stable enough to be land filled as nonhazardous waste 3. Ash that contains large amounts of soluble components and potentially toxic metal species. The regulations considering leaching of ash components set limits for the release of soluble salts and toxic metals. Some fly ashes show low leachability for metals but gives a salt release that is too close to the limit for total dissolved solids. Since fly ash from FBC boilers represent the largest volume of ash from these boilers there is a need for a simple and cheap treatment method that reduces the amount of soluble salts, i.e. NaCl, KCl etc, in the ash. After stabilisation, the ash is supposed to go into a more stable category. The aim of this project has been to investigate the applicability of a method to wash such an ash with water. The work included laboratory studies of the ash properties, the water washing process, filtration properties of the ash slurry and also tests of the method in pilot scale at a full scale boiler. This work has been concentrated towards the investigation of cyclone ash from a bubbling fluidised bed boiler in Lidkoeping fired with 100% household waste. Elemental composition of ash samples before and after washing/filtration was determined by AAS or ICP after a suitable dissolution of the sample. The mineralogy of ash samples was analysed using X-ray powder diffractometry. This method

  15. A survey of present levels of radiocesium in Swedish pulp mill liquors and the implications for wood radiocesium transfer factors. Using Kraft mill liquors as an indicator of wood radiocesium contamination

    International Nuclear Information System (INIS)

    Ravila, A.; Holm, E.

    2000-01-01

    A survey was initiated to depict and compare the present activity levels in pulp mill liquors from various mill locations. The 137 Cs levels in pulp mill liquors were compared with the mill location and the deposition pattern of the Chernobyl fallout and nuclear weapons fallout. The large input of wood (about 2500 m 3 per day) to an average Nordic Kraft mill and the relatively long-term retention time for radiocesium in the Kraft mill recovery cycle enables representative sampling of substances directly related to the activity concentration in wood. (author)

  16. Eyelid liquoric fistula secondary to orbital meningocele

    Directory of Open Access Journals (Sweden)

    Renato Antunes Schiave Germano

    2015-02-01

    Full Text Available Liquoric fistula (LF is defined as the communication of the subarachnoid space with the external environment, which main complication is the development of infection in the central nervous system. We reported the case of a patient with non-traumatic eyelid liquoric fistula secondary to orbital meningocele (congenital lesion, which main clinical manifestation was unilateral eyelid edema. Her symptoms and clinical signs appeared in adulthood, which is uncommon. The patient received surgical treatment, with complete resolution of the eyelid swelling. In conclusion, eyelid cerebrospinal fluid (CSF fistula is a rare condition but with great potential deleterious to the patient. It should be considered in the differential diagnosis of unilateral eyelid edema, and surgical treatment is almost always mandatory.

  17. Market review. Pellet wood gasification boiler / combination boiler. 8. ed.; Marktuebersicht. Scheitholzvergaser-/Kombikessel

    Energy Technology Data Exchange (ETDEWEB)

    Uth, Joern

    2012-01-15

    In the market review under consideration on pellet wood gasification boilers and combination boilers, the Federal Ministry of Food, Agriculture and Consumer Protection (Bonn, Federal Republic of Germany) reports on planning and installation of wood-fired heating systems, recommendations regarding to the technical assessment of boiler systems, buffers/combination boilers, prices of pellet wood gasification boilers, data sheets of the compared pellet wood gasification boilers, pellet wood combination boilers, prices of pellet wood combination boilers, data sheets of the compared pellet wood gasification boilers, list of providers.

  18. Pellet wood gasification boiler / Combination boiler. Market review. 7. ed.; Scheitholzvergaser-/Kombikessel. Marktuebersicht

    Energy Technology Data Exchange (ETDEWEB)

    Uth, Joern

    2010-08-15

    In the market review under consideration on pellet wood gasification boilers and combination boilers, the Federal Ministry of Food, Agriculture and Consumer Protection (Bonn, Federal Republic of Germany) report on planning and installation of wood-fired heating systems, recommendations regarding to the technical assessment of boiler systems, buffers/combination boilers, prices of pellet wood gasification boilers, data sheets of the compared pellet wood gasification boilers, pellet wood combination boilers, prices of pellet wood combination boilers, data sheets of the compared pellet wood gasification boilers, list of providers.

  19. A study on the boiler efficiency influenced by the boiler operation parameter in fossil power plant

    International Nuclear Information System (INIS)

    Kwon, Y. S.; Suh, J. S.

    2002-01-01

    The main reason to analyze the boiler operation parameter in fossil power plant is to increase boiler high efficiency and energy saving movement in the government. This study intends to have trend and analyze the boiler efficiency influenced by the boiler parameter in sub-critical and super-critical type boiler

  20. 49 CFR 230.47 - Boiler number.

    Science.gov (United States)

    2010-10-01

    ... 49 Transportation 4 2010-10-01 2010-10-01 false Boiler number. 230.47 Section 230.47..., DEPARTMENT OF TRANSPORTATION STEAM LOCOMOTIVE INSPECTION AND MAINTENANCE STANDARDS Boilers and Appurtenances Steam Gauges § 230.47 Boiler number. (a) Generally. The builder's number of the boiler, if known, shall...

  1. 30 CFR 77.413 - Boilers.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Boilers. 77.413 Section 77.413 Mineral... Mechanical Equipment § 77.413 Boilers. (a) Boilers shall be equipped with guarded, well-maintained water... the gages shall be kept clean and free of scale and rust. (b) Boilers shall be equipped with automatic...

  2. 30 CFR 56.13030 - Boilers.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Boilers. 56.13030 Section 56.13030 Mineral... HEALTH SAFETY AND HEALTH STANDARDS-SURFACE METAL AND NONMETAL MINES Compressed Air and Boilers § 56.13030 Boilers. (a) Fired pressure vessels (boilers) shall be equipped with water level gauges, pressure gauges...

  3. 30 CFR 57.13030 - Boilers.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Boilers. 57.13030 Section 57.13030 Mineral... HEALTH SAFETY AND HEALTH STANDARDS-UNDERGROUND METAL AND NONMETAL MINES Compressed Air and Boilers § 57.13030 Boilers. (a) Fired pressure vessels (boilers) shall be equipped with water level gauges, pressure...

  4. CFB boilers in multifuel application

    International Nuclear Information System (INIS)

    Goral, D.; Krzton, B.

    2007-01-01

    Fuel flexibility characteristic for CFB boilers plays an important rule in industrial and utility size applications. Possibility to use wider range of fuels that has been long time considered as by-products or wastes and possibility to design boilers able to operate with alternative fuels is an important factor that improves fuel delivery security and plant economy. Presented article is based on similar publications that present Foster Wheeler's experience in design and delivery of the CFB boilers for wide range of coals and cofiring by- products of crude oil refining and coal processing. Aspects of biomass cofiring will be also presented. (author)

  5. National Emission Standards for Hazardous Air Pollutants for Major Sources: Industrial, Commercial, and Institutional Boilers; Guidance for Calculating Efficiency Credits Resulting from Implementation of Energy Conservation Measures

    Energy Technology Data Exchange (ETDEWEB)

    Cox, Daryl [ORNL; Papar, Riyaz [Hudson Technologies; Wright, Dr. Anthony [ALW Consulting

    2013-02-01

    The purpose of this document is to provide guidance for developing a consistent approach to documenting efficiency credits generated from energy conservation measures in the Implementation Plan for boilers covered by the Boiler MACT rule (i.e., subpart DDDDD of CFR part 63). This document divides Boiler System conservation opportunities into four functional areas: 1) the boiler itself, 2) the condensate recovery system, 3) the distribution system, and 4) the end uses of the steam. This document provides technical information for documenting emissions credits proposed in the Implementation Plan for functional areas 2) though 4). This document does not include efficiency improvements related to the Boiler tune-ups.

  6. Significance of the combined tests application in serum and liquor of patients with suspected neurosyphilis

    Directory of Open Access Journals (Sweden)

    Mirković Mihailo

    2007-01-01

    Full Text Available Background. Tertiary syphilis develops in 8-40% of untreated patients. It is most commonly manifested in the form of neurosyphilis, which can be asymptomatic taking the form of tabes dorsalis or progressive paralyze. Nowadays, in the developed countries, progressive paralyze is a rather rare disease, although the incidence of this disease has been rising within the last decades. Case report. We reported a 74-year-old male with the clinical image of dementia showing psychotic symptoms. On cytobiochemical examination of cerebrospinal liquor, hyperproteinorhacmia of 0.70 g/l with the normal number of cells was revealed. Computed tomography of the brain showed the marked cortical cerebral and cerebellar reduction changes with multiple ischemic lesions. Within a routine examination of patients with demention, we performed serologic reactions to syphilis out of which the Veneral Disease Researc Laboratory (VDRL test in serum and liquor was unreactive, while the Treponema pallidum hemagglutination (TPNA test in serum and liquor was positive. Positivity in serum and liquor was additionally confirmed by the Western blot method and fluoroscent treponema antibody (FTA test. The treatment with benzathine fenylpenicilline 2.4 g once weekly resulted in significant improving the psychotic symptoms of the disease even after two weeks. Conclusion. This case report showed that within the differential diagnostics in patients with demention or psychotic disorder it is obligatory to consider syphilis of the nervous system, as well as to apply a combination of various tests which, besides the typical liquor findings, significantly improve the accuracy of diagnosis. Such approach is especially important regarding the fact that neurosyphilis can remain clinically quite asymptomatic for a long period, which could lead to late therapy, while, on the contrary, an adequate and timely treatment can contribute to a significant recovery of any patients.

  7. 46 CFR 61.05-10 - Boilers in service.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 2 2010-10-01 2010-10-01 false Boilers in service. 61.05-10 Section 61.05-10 Shipping... INSPECTIONS Tests and Inspections of Boilers § 61.05-10 Boilers in service. (a) Each boiler, including superheater, reheater, economizer, auxiliary boiler, low-pressure heating boiler, and unfired steam boiler...

  8. ENERGY STAR Certified Commercial Boilers

    Data.gov (United States)

    U.S. Environmental Protection Agency — Certified models meet all ENERGY STAR requirements as listed in the Version 1.0 ENERGY STAR Program Requirements for Commercial Boilers that are effective as of...

  9. Hybrid model of steam boiler

    International Nuclear Information System (INIS)

    Rusinowski, Henryk; Stanek, Wojciech

    2010-01-01

    In the case of big energy boilers energy efficiency is usually determined with the application of the indirect method. Flue gas losses and unburnt combustible losses have a significant influence on the boiler's efficiency. To estimate these losses the knowledge of the operating parameters influence on the flue gases temperature and the content of combustible particles in the solid combustion products is necessary. A hybrid model of a boiler developed with the application of both analytical modelling and artificial intelligence is described. The analytical part of the model includes the balance equations. The empirical models express the dependence of the flue gas temperature and the mass fraction of the unburnt combustibles in solid combustion products on the operating parameters of a boiler. The empirical models have been worked out by means of neural and regression modelling.

  10. Perspectives for the electricity surplus generation at the paper and cellulose segment through the gasification of black liquor; Perspectivas para a geracao de excedentes de eletricidade no segmento de papel e celulose atraves da gaseificacao de lixivia

    Energy Technology Data Exchange (ETDEWEB)

    Velazquez, Silvia Maria Stortini Gonzalez [Universidade Presbiteriana Mackenzie, Sao Paulo, SP (Brazil). Escola de Engenharia]. E-mail: velazquez@mackenzie.com.br; Coelho, Suani Teixeira [CENBIO - Centro Nacional de Referencia em Biomassa, Sao Paulo, Sp (Brazil)]. E-mail: suani@iee.usp.br

    2006-07-01

    industries, that currently, already demonstrate little interest in generating and/or to commercialize excesses, the problem is more complex. Beyond the technological impediment, therefore the Tomlinson recovery boilers limit the scale of the process (besides being in the end of its useful life in many units) and of the development training period of the black liquor gasification (still not available commercially), it has the raised cost of this technology (new one). (author)'.

  11. Boiler-turbine life extension

    Energy Technology Data Exchange (ETDEWEB)

    Natzkov, S. [TOTEMA, Ltd., Sofia (Bulgaria); Nikolov, M. [CERB, Sofia (Bulgaria)

    1995-12-01

    The design life of the main power equipment-boilers and turbines is about 105 working hours. The possibilities for life extension are after normatively regulated control tests. The diagnostics and methodology for Boilers and Turbines Elements Remaining Life Assessment using up to date computer programs, destructive and nondestructive control of metal of key elements of units equipment, metal creep and low cycle fatigue calculations. As well as data for most common damages and some technical decisions for elements life extension are presented.

  12. Combustion properties of kraft black liquors; Mustalipeaen koostumuksen vaikutus lipeaen poltto-ominaisuuksiin

    Energy Technology Data Exchange (ETDEWEB)

    Alen, R.; Siistonen, H.; Heikkinen, T.; Malkavaara, P. [Jyvaeskylae Univ. (Finland)

    1996-12-01

    The aim of this work is to study the combustion properties of kraft black liquors from modified cooking. Both the industrial and laboratory-made black liquors are included. In addition, changes in the combustion properties of the spent liquors obtained by mixing prior to combustion different chlorine-free bleach liquors with black liquor are studied. (author)

  13. Estudo do liquor de cupuaçu Study of cupuassu liquor

    Directory of Open Access Journals (Sweden)

    Kelly de Oliveira Cohen

    2005-03-01

    Full Text Available O cupuaçu (Theobroma grandiflorum Schum, que é um fruto amazônico, vem conquistando a cada ano mais espaço no mercado nacional e internacional com a comercialização de sua polpa. Suas sementes, consideradas como subproduto, vem despertando interesse não só no mundo científico como pelas indústrias. Sabe-se que, a partir das sementes, pode-se obter produtos análogos aos oriundos das sementes de cacau, seguindo as mesmas etapas de processamento. Dentre esses produtos tem-se o liquor de cupuaçu, semelhante ao liquor de cacau que é um dos ingredientes da formulação do chocolate. Este trabalho teve como objetivo o estudo da obtenção e caracterização física, química e físico-química do liquor de cupuaçu. Obteve-se três amostras de liquor de cupuaçu, cada qual partindo de lotes diferentes de fermentação. Foram avaliados a composição centesimal e o comportamento reológico. O liquor de cupuaçu apresentou alto teor de lipídios (63,93 a 66,51% e alto valor calórico (677,35 a 691,17kcal/100g. O teor de proteínas variou de 8,95 a 10,31%. A viscosidade plástica de Casson diminuiu com o aumento de temperatura. A distribuição do tamanho das partículas influenciou nas diferenças de viscosidades entre as amostras, havendo maior redução de viscosidade plástica com o aumento da temperatura nas amostras que apresentaram maior diâmetro de partículas. A gordura de cupuaçu apresentou comportamento newtoniano à 40ºC.Cupuassu (Theobroma grandiflorum Schum is an amazon fruit, that each year is conquering more space in national and international market with the commercialization of its pulp. Its seeds, considered as subproducts, are arousing interest not only in the scientific world but also in the industry. It's known that from those seeds, it can be obtained analogous products as those cocoa seeds, following the same stages of processing. Among those products there is the cupuassu liquor, similar to cocoa liquor that is one

  14. Boiler using combustible fluid

    Science.gov (United States)

    Baumgartner, H.; Meier, J.G.

    1974-07-03

    A fluid fuel boiler is described comprising a combustion chamber, a cover on the combustion chamber having an opening for introducing a combustion-supporting gaseous fluid through said openings, means to impart rotation to the gaseous fluid about an axis of the combustion chamber, a burner for introducing a fluid fuel into the chamber mixed with the gaseous fluid for combustion thereof, the cover having a generally frustro-conical configuration diverging from the opening toward the interior of the chamber at an angle of between 15/sup 0/ and 55/sup 0/; means defining said combustion chamber having means defining a plurality of axial hot gas flow paths from a downstream portion of the combustion chamber to flow hot gases into an upstream portion of the combustion chamber, and means for diverting some of the hot gas flow along paths in a direction circumferentially of the combustion chamber, with the latter paths being immersed in the water flow path thereby to improve heat transfer and terminating in a gas outlet, the combustion chamber comprising at least one modular element, joined axially to the frustro-conical cover and coaxial therewith. The modular element comprises an inner ring and means of defining the circumferential, radial, and spiral flow paths of the hot gases.

  15. Effects of Non Process Elements in the chemical recovery system of paper mills; Effekter av PFG foer integrerade pappersbruk vid indunstning och foerbraenning av bioslam i sodapannan

    Energy Technology Data Exchange (ETDEWEB)

    Dahlbom, Johan [AaF Process AB, Stockholm (Sweden); Wadsborn, Rickard [STFI-Packforsk AB, Stockholm (Sweden)

    2005-09-01

    Effluent treatment of pulp and paper mills generates a biological sludge that according to Swedish implementation of EU-directives from 2005 has to be taken care of by incineration or by production of soil for agriculture or ground cover. An alternative way to take care of the sludge is incineration in the recovery boiler. This method is used in two Finish and two Swedish pulp mills with good results. The purpose of this project is to investigate the consequences for integrated pulp and paper mills when the biological sludge is incinerated in the recovery boiler. The biological sludge contents Non Process Elements, NPE, which increase the risks of incrustations in the system and increase the need of make up lime. This study comprises the following NPE: aluminum, silicon, phosphorus, chloride, potassium, manganese, magnesium, iron, copper, barium and calcium. The simulation program WinGEMS 5.0 (Pacific Simulation) was used in the study to predict the levels of NPE in the recovery system of the Kraft mills. Three different pulp and paper mills were selected for the study, Billerud Skaerblacka, ASSI Domaen Froevi and SCA Obbola. The mills are different concerning raw materials, process, degree of own produced pulp and paper products. All three the mills have effluent treatment and use the method of activated sludge that generates a surplus of biological sludge. The results of the study proved that for Skaerblacka mill the method is applicable. For Obbola the prerequisites are somewhat more complicated, the effluent treatment generates considerably higher amount of sludge per ton pulp produced due to the treatment technique and use of waste paper (40 %) for the paper machine. The high input of aluminum with the sludge will give troublesome incrustations of sodium-aluminum-silicate on the heat surfaces in the evaporation plant. To eliminate the aluminum from the system magnesium can be added to the black liquor which will precipitate as the double salt hydrotalcite in

  16. 27 CFR 31.42 - Restaurants serving liquors with meals.

    Science.gov (United States)

    2010-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2010-04-01 2010-04-01 false Restaurants serving... Part Certain Organizations, Agencies, and Persons § 31.42 Restaurants serving liquors with meals. Proprietors of restaurants and other persons who serve liquors with meals to paying customers, even if no...

  17. Influence of probiotics on rumen liquor characteristics and ...

    African Journals Online (AJOL)

    Probiotics has been noted to work synergistically with rumen microbes and improved rumen liquor characteristics. In this study, we investigated the effect of probiotics inclusion on rumen liquor characteristics (physical, chemical and fermentative qualities) and microbiology in WAD goats. In a completely randomised design, ...

  18. New controls spark boiler efficiency

    Energy Technology Data Exchange (ETDEWEB)

    Engels, T. (Monsanto, University Park, IL (United States))

    1993-09-01

    Monsanto's NutraSweet plant in University Park, IL, produces aspartame, the patented NutraSweet artificial sweetener product. Until recently, boiler control was managed by a '60s-era Fireye jackshaft system in which air and natural gas were mechanically linked with an offset to compensate for oxygen trim. The interlocking devices on the Fireye system were becoming obsolete, and the boiler needed a new front end retrofitted for low emissions. In order to improve boiler control efficiency, we decided to modernize and automate the entire boiler control system. We replaced the original jackshaft system, and installed a Gordon-Piet burner system, including gas valves, air dampers, blowers, and burner. The upgrade challenges included developing a control strategy and selecting and implementing a process control system. Since our plant has standardized on the PROVOX process management information system from Fisher Controls (now Fisher-Rosemount Systems) to support most of our process, it was a natural and logical choice for boiler controls as well. 2 figs.

  19. Failure analysis of boiler tube

    International Nuclear Information System (INIS)

    Mehmood, K.; Siddiqui, A.R.

    2007-01-01

    Boiler tubes are energy conversion components where heat energy is used to convert water into high pressure superheated steam, which is then delivered to a turbine for electric power generation in thermal power plants or to run plant and machineries in a process or manufacturing industry. It was reported that one of the tubes of a fire-tube boiler used in a local industry had leakage after the formation of pits at the external surface of the tube. The inner side of the fire tube was working with hot flue gasses with a pressure of 10 Kg/cm/sup 2/ and temperature 225 degree C. The outside of the tube was surrounded by feed water. The purpose of this study was to determine the cause of pits developed at the external surface of the failed boiler tube sample. In the present work boiler tube samples of steel grade ASTM AI61/ASTM A192 were analyzed using metallographic analysis, chemical analysis, and mechanical testing. It was concluded that the appearance of defects on the boiler tube sample indicates cavitation type corrosion failure. Cavitation damage superficially resembled pitting, but surface appeared considerably rougher and had many closely spaced pits. (author)

  20. Uranium complex recycling method of purifying uranium liquors

    International Nuclear Information System (INIS)

    Elikan, L.; Lyon, W.L.; Sundar, P.S.

    1976-01-01

    Uranium is separated from contaminating cations in an aqueous liquor containing uranyl ions. The liquor is mixed with sufficient recycled uranium complex to raise the weight ratio of uranium to said cations preferably to at least about three. The liquor is then extracted with at least enough non-interfering, water-immiscible, organic solvent to theoretically extract about all of the uranium in the liquor. The organic solvent contains a reagent which reacts with the uranyl ions to form a complex soluble in the solvent. If the aqueous liquor is acidic, the organic solvent is then scrubbed with water. The organic solvent is stripped with a solution containing at least enough ammonium carbonate to precipitate the uranium complex. A portion of the uranium complex is recycled and the remainder can be collected and calcined to produce U 3 O 8 or UO 2

  1. Structured Mathematical Modeling of Industrial Boiler

    Directory of Open Access Journals (Sweden)

    Abdullah Nur Aziz

    2014-04-01

    Full Text Available As a major utility system in industry, boilers consume a large portion of the total energy and costs. Significant reduction of boiler cost operation can be gained through improvements in efficiency. In accomplishing such a goal, an adequate dynamic model that comprehensively reflects boiler characteristics is required. This paper outlines the idea of developing a mathematical model of a water-tube industrial boiler based on first principles guided by the bond graph method in its derivation. The model describes the temperature dynamics of the boiler subsystems such as economizer, steam drum, desuperheater, and superheater. The mathematical model was examined using industrial boiler performance test data.It can be used to build a boiler simulator or help operators run a boiler effectively.

  2. Concept of Heat Recovery from Exhaust Gases

    Science.gov (United States)

    Bukowska, Maria; Nowak, Krzysztof; Proszak-Miąsik, Danuta; Rabczak, Sławomir

    2017-10-01

    The theme of the article is to determine the possibility of waste heat recovery and use it to prepare hot water. The scope includes a description of the existing sample of coal-fired boiler plant, the analysis of working condition and heat recovery proposals. For this purpose, a series of calculations necessary to identify the energy effect of exhaust temperature decreasing and transferring recovery heat to hot water processing. Heat recover solutions from the exhaust gases channel between boiler and chimney section were proposed. Estimation for the cost-effectiveness of such a solution was made. All calculations and analysis were performed for typical Polish conditions, for coal-fired boiler plant. Typicality of this solution is manifested by the volatility of the load during the year, due to distribution of heat for heating and hot water, determining the load variation during the day. Analysed system of three boilers in case of load variation allows to operational flexibility and adaptation of the boilers load to the current heat demand. This adaptation requires changes in the operating conditions of boilers and in particular assurance of properly conditions for the combustion of fuel. These conditions have an impact on the existing thermal loss and the overall efficiency of the boiler plant. On the boiler plant efficiency affects particularly exhaust gas temperature and the excess air factor. Increasing the efficiency of boilers plant is possible to reach by following actions: limiting the excess air factor in coal combustion process in boilers and using an additional heat exchanger in the exhaust gas channel outside of boilers (economizer) intended to preheat the hot water.

  3. Uranium and thorium determination in Santa Quiteria liquor by ICP-OES analysis

    International Nuclear Information System (INIS)

    Pedro Junior, A.; Rezende, Paulo R.; Carvalho, Leonel M.; Ferreira, Elizabeth de Massena

    2009-01-01

    The mineral source of Itataia located in Santa Quiteria (Ceara/Brazil) is a phosphorus uraniferous one, where uranium occurs in collophanite (fluoroapatite) form. Phosphate minerals of the apatite family make possible the uses of uranium as a byproduct. The sulfuric leaching of the phosphate rock in order to obtain phosphoric acid also permits uranium recovery. Thus, the liquor coming from the leaching contains high levels of phosphoric acid as well as elements like Mg, Fe, U, Zr, Th and some rare earths in significant concentrations. The direct determination of U and Th content of this liquor is essential to a rapid response in the uranium separation and purification together process by solvent extraction, aiming its use for commercial purposes, as nuclear industry fuel. In this study U and Th were determined by Inductively Coupled Plasma Spectrometry (ICP-OES) in several samples of liquor, in high concentrations of H 3 PO 4 in environment. Several ratios of U/Th and H 3 PO 4 concentrations were studied, in order to find the optimal conditions for the direct determination of U and Th, without need to prior separation. (author)

  4. Structured Mathematical Modeling of Industrial Boiler

    OpenAIRE

    Aziz, Abdullah Nur; Nazaruddin, Yul Yunazwin; Siregar, Parsaulian; Bindar, Yazid

    2014-01-01

    As a major utility system in industry, boilers consume a large portion of the total energy and costs. Significant reduction of boiler cost operation can be gained through improvements in efficiency. In accomplishing such a goal, an adequate dynamic model that comprehensively reflects boiler characteristics is required. This paper outlines the idea of developing a mathematical model of a water-tube industrial boiler based on first principles guided by the bond graph method in its derivation. T...

  5. Sootblowing optimization for improved boiler performance

    Science.gov (United States)

    James, John Robert; McDermott, John; Piche, Stephen; Pickard, Fred; Parikh, Neel J.

    2012-12-25

    A sootblowing control system that uses predictive models to bridge the gap between sootblower operation and boiler performance goals. The system uses predictive modeling and heuristics (rules) associated with different zones in a boiler to determine an optimal sequence of sootblower operations and achieve boiler performance targets. The system performs the sootblower optimization while observing any operational constraints placed on the sootblowers.

  6. Optimizing the Integrated Design of Boilers - Simulation

    DEFF Research Database (Denmark)

    Sørensen, K.; Karstensen, C.; Condra, T.

    2004-01-01

    Boilers can be considered as consisting of three main components: (i) the pressure part, (ii) the burner and (iii) the control system. To be able to develop the boilers of the future (i.e. the boilers with the lowest emissions, the highest efciency, the best dynamic performance etc.) it is import...

  7. Methylated liquor treatment process in caffeine production

    Science.gov (United States)

    Zhou, Junbo; Yang, Mingyang; Huang, Wenjia; Cui, Shenglu; Gao, Liping

    2018-02-01

    The caffeine production process produces a large amount of sodium methyl sulphate in the methylated mother liquor. In order to recycle this part of ingredient, we use the mother liquid of Shijiazhuang Xin Nuowei Pharmaceutical Co., Ltd. as the object of study, the use of “nanofiltration (NF) - Dish Type Reverse Osmosis (DTRO) “combination of membrane technology for desalination and concentration. The experimental results show that the concentration of sodium sulfate in the nanofiltration solution is 0.37 g • L -1, the rejection rate is 98%, and the concentration of sodium methyl sulfate in DTRO concentrated solution is 453.80 g • L -1, which meets the requirements of the enterprise.

  8. MULTIPLE LINEAR REGRESSION ANALYSIS FOR PREDICTION OF BOILER LOSSES AND BOILER EFFICIENCY

    OpenAIRE

    Chayalakshmi C.L

    2018-01-01

    MULTIPLE LINEAR REGRESSION ANALYSIS FOR PREDICTION OF BOILER LOSSES AND BOILER EFFICIENCY ABSTRACT Calculation of boiler efficiency is essential if its parameters need to be controlled for either maintaining or enhancing its efficiency. But determination of boiler efficiency using conventional method is time consuming and very expensive. Hence, it is not recommended to find boiler efficiency frequently. The work presented in this paper deals with establishing the statistical mo...

  9. Catalytic mechanism of sodium compounds in black liquor during gasification of coal black liquor slurry

    International Nuclear Information System (INIS)

    Kuang Jianping; Zhou Junhu; Zhou Zhijun; Liu Jianzhong; Cen Kefa

    2008-01-01

    The coal black liquor slurry (CBLS) was composed of coal and black pulping liquor, which has plenty of sodium compounds, lignin and cellulose. The sodium compounds have a catalytic effect on the gasification process of coal black liquor slurry, while lignin and cellulose enhance the heat value. Alkali-catalyzed gasification experiments of CBLS and CWS (coal water slurry) are investigated on the thermobalance and fixed bed reactor. The residues of the gasification of CBLS and CWS are analyzed by XRD, SEM and FT-IR. It is found that many micro- and mesopores and zigzag faces exist in the surface of the CBLS coke, which play a key role in the catalytic gasification. Sodium can enhance the reaction potential, weaken the bond of C-O and improve the gasification reaction rate. XRD results show that sodium aluminum silicate and nepheline are the main crystal components of the CBLS and CWS. The C-O stretching vibration peak in the 1060 cm -1 band in the CBLS shifts to 995.65 cm -1 in the CBLS coke after partial gasification. This means that the energy of the C-O stretching vibration in the CBLS carbon matrix decreases, so the structure of the carbon matrix is more liable to react with an oxygen ion or hydroxide ion. The amplitude of the C-O stretching vibration peak is augmented step by step due to the ground-excited level jump of the C-O band

  10. Failure Analysis of 600 MW Supercritical Boiler Water Wall

    OpenAIRE

    Fu Huilin; Cai Zhengchun; Yan Xiaozhong; He Jinqiao; Zhou Yucai

    2013-01-01

    Boiler tube often causes abnormal boiler outage, bringing greater economic losses. This thesis mainly comes from the dynamics of boiler water, boiler furnace accident location of wall temperature distribution to explore the cause of the accident boiler. Calculation results show that the deformation will seriously reduce the boiler allowable maximum temperature difference between the screens. And the boiler is not over-temperature, low temperature difference between the screens, which have bur...

  11. Biomass boiler still best choice

    International Nuclear Information System (INIS)

    Wallace, Paula

    2014-01-01

    Full text: The City of Mount Gambier upgraded its boiler in September after analysis showed that biomass was still the optimal energy option. The Mount Gambier Aquatic Centre was built by the local city council in the 1980s as an outdoor pool facility for the public. The complex has three pools — an Olympic-sized, toddler and a learner pool — for a total volume of 1.38ML (including balance tanks). The large pool is heated to 27-28°C, the smaller one 30-32°C. From the very beginning, the pool water was heated by a biomass boiler, and via two heat exchangers whose combined capacity is 520 kW. The original biomass boiler ran on fresh sawdust from a local timber mill. After thirty years of dedicated service the original boiler had become unreliable and difficult to operate. Replacement options were investigated and included a straight gas boiler, a combined solar hot water and gas option, and biomass boilers. The boiler only produces heat, not electricity. All options were subjected to a triple bottom line assessment, which included potential capital costs, operating costs, community and environmental benefits and costs. The project was also assessed using a tool developed by Mount Gambier City Council that considers the holistic benefits — the CHAT Tool, which stands for Comprehensive Holistic Assessment Tool. “Basically it is a survey that covers environmental, social, economic and governance factors,” the council's environmental sustainability officer, Aaron Izzard told WME. In relation to environmental considerations, the kinds of questions explored by the CHAT Tool included: Sustainable use of resources — objective is to reduce council's dependence on non-renewable resources; Greenhouse emissions — objective is to reduce council's contribution of GHG into the atmosphere; Air quality — objective is to improve local air quality. The conclusion of these analyses was that while a biomass boiler would have a higher capital cost than a straight gas

  12. Lignin derivatives from desilicated rice straw soda black liquor

    Energy Technology Data Exchange (ETDEWEB)

    El-Taraboulsi, M A; Nasser, M M

    1979-01-01

    Carboxymethyl lignin, cyanoethyl lignin, carboxyethyl lignin, and aminopropyl lignin were prepared from alkali lignin of rice straw black liquor (after disilication by storage for 1 wk to 1 yr) and used as sizes for paper, drilling fluid additives and flocculants.

  13. 27 CFR 5.46 - Standard liquor bottles.

    Science.gov (United States)

    2010-04-01

    ..., DEPARTMENT OF THE TREASURY LIQUORS LABELING AND ADVERTISING OF DISTILLED SPIRITS Standards of Fill for... appeal procedures, see part 13 of this chapter. (Sec. 5, 49 Stat. 981, as amended (27 U.S.C. 205); 26 U.S...

  14. Pyrolysis and gasification behavior of black liquor under pressurized conditions

    Energy Technology Data Exchange (ETDEWEB)

    Whitty, K

    1997-11-01

    The purpose of this study has been to enhance the understanding of the processes involved in pressurized black liquor gasification. Gasification is known to occur in three stages: drying, pyrolysis and char gasification. The work presented here focuses on the pyrolysis and gasification stages. Experiments were carried out primarily in two laboratory-scale reactors. A pressurized grid heater was used to study black liquor pyrolysis under pressurized conditions. Char yields and the fate of elements in the liquor, as well as the degree of liquor swelling, were measured in this device. A pressurized thermogravimetric reactor was used to measure the rate of the char gasification process under different temperatures and pressures and in various gas atmospheres. Pyrolysis experiments were also carried out in this device, and data on swelling behavior, char yields and component release were obtained 317 refs.

  15. Study on uranium loss during 'Iron-Gypsum Cake' precipitation from acid leach liquor of Jaduguda ore using factorially designed experiments

    International Nuclear Information System (INIS)

    Das, Amrita; Yadav, Manoj; Chatterjee, Ankur; Singh, A.K.; Hubli, R.C.

    2012-01-01

    Acid leaching process for uranium recovery from ore often generates considerable amounts of impurities into the solution. It is a challenge to separate the non-valuable impurities as manageable and stable waste products for final disposal, without losing the valuable constituents. The main impurities that come with the leach liquor are iron and sulfate. Their removal is essential for meeting the iron requirement in leaching circuit and also for making the effluent suitable for recycle. Factorial design analysis was applied to study of process variables for precipitation of iron and sulphate from leach liquor with composition using CaO as precipitation reagent

  16. Vanillin: Synthetic Flavoring from Spent Sulfite Liquor

    Science.gov (United States)

    Hocking, Martin B.

    1997-09-01

    Separation of the lignin component of wood from the cellulose presents an opportunity to access various interesting products from the lignin fragments. The lignin represents availability of a sizable renewable resource. Vanillin, or 3-methoxy-4-hydroxybenzaldehyde, is one of a series of related substituted aromatic flavor constituents, and represents one of the potentially profitable possibilities. Vanillin production from the lignin-containing waste liquor obtained from acid sulfite pulping of wood began in North America in the mid 1930's. By 1981 one plant at Thorold, Ontario produced 60% of the contemporary world supply of vanillin. The process also simultaneously decreased the organic loading of the aqueous waste streams of the pulping process. Today, however, whilst vanillin production from lignin is still practiced in Norway and a few other areas, all North American facilities using this process have closed, primarily for environmental reasons. New North American vanillin plants use petrochemical raw materials. An innovation is needed to help overcome the environmental problems of this process before vanillin production from lignin is likely to resume here. Current interest in the promotion of chemicals production from renewable raw materials reinforces the incentive to do this.

  17. Quality and generation rate of solid residues in the boiler of a waste-to-energy plant

    International Nuclear Information System (INIS)

    Allegrini, E.; Boldrin, A.; Jansson, S.; Lundtorp, K.; Fruergaard Astrup, T.

    2014-01-01

    Highlights: • Ash was sampled at 10 different points of the boiler of a waste-to-energy plant. • Samples were analysed for the chemical composition, PCDD/F and leaching behaviour. • Enrichment trends of elements were investigated in relation to boiler conditions. • No significant differences were found between boiler ash samples. - Abstract: The Danish waste management system relies significantly on waste-to-energy (WtE) plants. The ash produced at the energy recovery section (boiler ash) is classified as hazardous waste, and is commonly mixed with fly ash and air pollution control residues before disposal. In this study, a detailed characterization of boiler ash from a Danish grate-based mass burn type WtE was performed, to evaluate the potential for improving ash management. Samples were collected at 10 different points along the boiler's convective part, and analysed for grain size distribution, content of inorganic elements, polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD and PCDF), and leaching of metals. For all samples, PCDD and PCDF levels were below regulatory limits, while high pH values and leaching of e.g. Cl were critical. No significant differences were found between boiler ash from individual sections of the boiler, in terms of total content and leaching, indicating that separate management of individual ash fractions may not provide significant benefits

  18. Quality and generation rate of solid residues in the boiler of a waste-to-energy plant

    Energy Technology Data Exchange (ETDEWEB)

    Allegrini, E., E-mail: elia@env.dtu.dk [Technical University of Denmark, Department of Environmental Engineering, Building 115, Lyngby 2800 (Denmark); Boldrin, A. [Technical University of Denmark, Department of Environmental Engineering, Building 115, Lyngby 2800 (Denmark); Jansson, S. [Umeå University, Department of Chemistry, Umeå SE-901 87 (Sweden); Lundtorp, K. [Babcock and Wilcox Vølund A/S, Göteborg (Sweden); Fruergaard Astrup, T. [Technical University of Denmark, Department of Environmental Engineering, Building 115, Lyngby 2800 (Denmark)

    2014-04-01

    Highlights: • Ash was sampled at 10 different points of the boiler of a waste-to-energy plant. • Samples were analysed for the chemical composition, PCDD/F and leaching behaviour. • Enrichment trends of elements were investigated in relation to boiler conditions. • No significant differences were found between boiler ash samples. - Abstract: The Danish waste management system relies significantly on waste-to-energy (WtE) plants. The ash produced at the energy recovery section (boiler ash) is classified as hazardous waste, and is commonly mixed with fly ash and air pollution control residues before disposal. In this study, a detailed characterization of boiler ash from a Danish grate-based mass burn type WtE was performed, to evaluate the potential for improving ash management. Samples were collected at 10 different points along the boiler's convective part, and analysed for grain size distribution, content of inorganic elements, polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD and PCDF), and leaching of metals. For all samples, PCDD and PCDF levels were below regulatory limits, while high pH values and leaching of e.g. Cl were critical. No significant differences were found between boiler ash from individual sections of the boiler, in terms of total content and leaching, indicating that separate management of individual ash fractions may not provide significant benefits.

  19. Comparative study of operation of condensing and traditional boilers equipped with the ORC module for electricity generation

    Directory of Open Access Journals (Sweden)

    Mikielewicz Dariusz

    2017-01-01

    Full Text Available Condensing technology applied to boilers is to make full use of thermal energy contained in the fuel. That means that additionaly the heat from condensation of exhaust gases can be used for the purposes of heating the domestic hot water and to cover the demand for central heating. The study analyzed the operation of the “traditional” boiler equipped with the ORC module as the similar arrangement but with the condensing boiler. In the case of a conventional boiler there is noted a greater fuel consumption and the greater power generated than in the case of the unit with the condensing boiler. Postulated is the indicator in the form of a ratio of turbine power to the mass flow rate of fuel, which in turn gives a higher value for the condensing boiler, thus demonstrating that the operation of condensing boiler ORC module will be more economical. Perspective domestic micro CHP with ORC should be installed in boilers with recovery of heat from condensation from the exhaust gases.

  20. Studies on inhibition characteristics of corn steep liquor and black sulphite liquor on corrosion of mild steel in acid media

    Energy Technology Data Exchange (ETDEWEB)

    Deb, P C; Mukherjea, R N

    1968-06-01

    The purpose of this study was to economically reduce the attack by acid on the parent metal, during the process of removing mill scale by acid pickling. Two inhibitors, by-products of the starch industry and pulp industry, were studied due to their cheapness and availability in India. The inhibition efficiency of the corn steep liquor and black sulfite liquor was found to be below that of thiourea. For example, in 6.2% (w/w) H/sub 2/SO/sub 4/ (at 50/sup 0/C), an inhibition efficiency of 90.5% and 84.5% is reached for inhibitor concentrations of 10 g per liter in the case of corn steep liquor and black sulfite liquor, respectively, while a concentration of 0.25 g per liter of thiourea was required to reach an inhibition efficiency of 98.6%.

  1. 46 CFR 52.25-20 - Exhaust gas boilers.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 2 2010-10-01 2010-10-01 false Exhaust gas boilers. 52.25-20 Section 52.25-20 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) MARINE ENGINEERING POWER BOILERS Other Boiler Types § 52.25-20 Exhaust gas boilers. Exhaust gas boilers with a maximum allowable working pressure...

  2. 46 CFR 63.25-1 - Small automatic auxiliary boilers.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 2 2010-10-01 2010-10-01 false Small automatic auxiliary boilers. 63.25-1 Section 63.25... AUXILIARY BOILERS Requirements for Specific Types of Automatic Auxiliary Boilers § 63.25-1 Small automatic auxiliary boilers. Small automatic auxiliary boilers defined as having heat-input ratings of 400,000 Btu/hr...

  3. Fluidized bed boiler feed system

    Science.gov (United States)

    Jones, Brian C.

    1981-01-01

    A fluidized bed boiler feed system for the combustion of pulverized coal. Coal is first screened to separate large from small particles. Large particles of coal are fed directly to the top of the fluidized bed while fine particles are first mixed with recycled char, preheated, and then fed into the interior of the fluidized bed to promote char burnout and to avoid elutriation and carryover.

  4. Inception report and gap analysis. Boiler inspection

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2004-06-01

    This inception and gap analysis report on boilers in Latvia, has been prepared in the framework of the 'Implementation of the EU directive on energy performance of buildings: development of the Latvian Scheme for energy auditing of building and inspection of boilers'. The report is the basis for the establishment of training of boiler inspectors; it develops a gap analysis for better understanding and estimating the number of installations in Latvia and develops suggestions for the institutional set up. In particular includes information on existing standard and regulation on boiler, suggestion for the content of the training material of experts for boiler inspections and a syllabus of the training course. A specific section is dedicated to the suggestion for certification system of trained boiler inspectors. (au)

  5. Inception report and gap analysis. Boiler inspection

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2004-06-01

    This inception and gap analysis report on boilers in Latvia, has been prepared in the framework of the 'Implementation of the EU directive on energy performance of buildings: development of the Latvian Scheme for energy auditing of building and inspection of boilers'. The report is the basis for the establishment of training of boiler inspectors; it develops a gap analysis for better understanding and estimating the number of installations in Latvia and develops suggestions for the institutional set up. In particular includes information on existing standard and regulation on boiler, suggestion for the content of the training material of experts for boiler inspections and a syllabus of the training course. A specific section is dedicated to the suggestion for certification system of trained boiler inspectors. (au)

  6. CHP Integrated with Burners for Packaged Boilers

    Energy Technology Data Exchange (ETDEWEB)

    Castaldini, Carlo; Darby, Eric

    2013-09-30

    division of Sempra Energy. These match funds were provided via concurrent contracts and investments available via CMCE, Altex, and Leva Energy The project attained all its objectives and is considered a success. CMCE secured the support of GI&E from Italy to supply 100 kW Turbec T-100 microturbines for the project. One was purchased by the project’s subcontractor, Altex, and a second spare was purchased by CMCE under this project. The microturbines were then modified to convert from their original recuperated design to a simple cycle configuration. Replacement low-NOx silo combustors were designed and bench tested in order to achieve compliance with the California Air Resources Board (CARB) 2007 emission limits for NOx and CO when in CHP operation. The converted microturbine was then mated with a low NOx burner provided by Altex via an integration section that allowed flow control and heat recovery to minimize combustion blower requirements; manage burner turndown; and recover waste heat. A new fully integrated control system was designed and developed that allowed one-touch system operation in all three available modes of operation: (1) CHP with both microturbine and burner firing for boiler heat input greater than 2 MMBtu/hr; (2) burner head only (BHO) when the microturbine is under service; and (3) microturbine only when boiler heat input requirements fall below 2 MMBtu/hr. This capability resulted in a burner turndown performance of nearly 10/1, a key advantage for this technology over conventional low NOx burners. Key components were then assembled into a cabinet with additional support systems for generator cooling and fuel supply. System checkout and performance tests were performed in the laboratory. The assembled system and its support equipment were then shipped and installed at a host facility where final performance tests were conducted following efforts to secure fabrication, air, and operating permits. The installed power burner is now in commercial

  7. Boiler plants completed in record time

    International Nuclear Information System (INIS)

    Anon.

    2001-01-01

    Bubbling fluidised bed (BFB) combustion has steadily increased its share of the boiler market in recent years, particularly in the Nordic region, where it is particularly well-suited to handling the high moisture content biofuels produced and used by the forest products industry. Foster Wheeler is the world's leading supplier of fluidised bed combustion technology. Over 200 of the more than 300 fluidised bed boilers supplied by the company are circulating fluidised bed (CFB) designs, a market in which Foster Wheeler has more than a 40% share. Foster Wheeler Energia Oy supplied the Myllykoski project at Anjalankoski with a fluidised bed boiler, auxiliary steam boilers, and flue gas scrubber systems

  8. The Technology Introduction of Chain Boiler Energy Conservation Transformation

    Science.gov (United States)

    Li, Henan; Liu, Xiwen; Yuan, Hong; Lin, Jiadai; Zhang, Yu

    2017-12-01

    Introduced the present status of chain boiler efficiency is low, the system analysis of the chain boiler optimization and upgrading of technology, for the whole progress of chain boiler to provide some ideas and reference.

  9. Elevated temperature failures in boiler tubes - case studies

    International Nuclear Information System (INIS)

    Gowrisankar, I.; Bandyopadhyay, G.

    1989-01-01

    Metallurgical investigation of boiler tube failures enables identification of failure mechanisms and the underlying cause related to boiler conditions. Some case studies in short term overheating, prolonged overheating and low cycle fatigue failures in boiler tubes are discussed. (author)

  10. Influence of the chemical composition on the combustion properties of kraft black liquor; Mustalipeaen koostumuksen vaikutus lipeaen poltto-ominaisuuksiin

    Energy Technology Data Exchange (ETDEWEB)

    Alen, R; Siistonen, H; Malkavaara, P [Jyvaeskylae Univ. (Finland). Inst. of Chemistry

    1997-10-01

    The aim of this work is to study the combustion properties of kraft black liquors from modified cooking. Both the industrial and laboratory-made black liquors are included. In addition, changes in the combustion properties of the spent liquors obtained by mixing prior to combustion different chlorine-free bleach liquors with black liquor are studied. (orig.)

  11. EFFICIENCY IMPROVEMENT IN INDUSTRIAL BOILER BY FLUE GAS DUCT INSULATION

    OpenAIRE

    Sanjay H. Zala

    2017-01-01

    Now a days in industry major losses are find out so here we calculate these losses and find out efficiency of boiler. Boiler efficiency and energy losses from boiler are important parameter for any industry using boiler. In this work a detailed analysis was carried out for boiler at Anish Chemicals Bhavnagar. It is a combined water and fire tube boiler using biomass coal as fuel. Boiler efficiency calculated by direct method is in range of (78.5% to 81.6%). Major losses from boiler are heat ...

  12. MODELLING, SIMULATING AND OPTIMIZING BOILERS

    DEFF Research Database (Denmark)

    Sørensen, K.; Condra, T.; Houbak, Niels

    2003-01-01

    , and the total stress level (i.e. stresses introduced due to internal pressure plus stresses introduced due to temperature gradients) must always be kept below the allowable stress level. In this way, the increased water-/steam space that should allow for better dynamic performance, in the end causes limited...... freedom with respect to dynamic operation of the plant. By means of an objective function including as well the price of the plant as a quantification of the value of dynamic operation of the plant an optimization is carried out. The dynamic model of the boiler plant is applied to define parts...

  13. Wood fuelled boiler operating costs

    International Nuclear Information System (INIS)

    Sandars, D.L.

    1995-01-01

    This report is a management study into the operating costs of wood-fired boilers. Data obtained from existing wood-fired plant has been analysed and interpreted using the principles of machinery management and the science that underlies the key differences between this fuel and any other. A set of budgeting principles has been developed for the key areas of labour requirement, insurance, maintenance and repair and electricity consumption. Other lesser cost centres such as the provision of shelter and the effects of neglect and accidents have also been considered, and a model constructed. (author)

  14. Economic evaluation of a coal fired boiler

    International Nuclear Information System (INIS)

    Briem, J.J.

    1983-01-01

    This paper provides basic information on boiler economics which will assist steam users in analyzing the feasibility of using coal to generate steam - in either new or existing facilities. The information presented covers boilers ranging in size from 10,000 to 100,000 pounds per hour steaming capacity

  15. 46 CFR 109.555 - Propulsion boilers.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 4 2010-10-01 2010-10-01 false Propulsion boilers. 109.555 Section 109.555 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) A-MOBILE OFFSHORE DRILLING UNITS OPERATIONS Miscellaneous § 109.555 Propulsion boilers. The master or person in charge and the engineer in charge shall...

  16. 29 CFR 1915.162 - Ship's boilers.

    Science.gov (United States)

    2010-07-01

    ... 29 Labor 7 2010-07-01 2010-07-01 false Ship's boilers. 1915.162 Section 1915.162 Labor Regulations Relating to Labor (Continued) OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR (CONTINUED) OCCUPATIONAL SAFETY AND HEALTH STANDARDS FOR SHIPYARD EMPLOYMENT Ship's Machinery and Piping Systems § 1915.162 Ship's boilers. (a) Before...

  17. Sulfate reduction in an entrained-flow black liquor gasifier

    Energy Technology Data Exchange (ETDEWEB)

    Kymaelaeinen, M.; Janka, K. [Tampella Power, Tampere (Finland); Frederick, W.J.; Littau, M.; Sricharoenchaikul, V.; Jivakanun, N.; Waag, K. [Oregon State Univ., Corvallis, OR (United States). Dept. of Chemical Engineering

    1995-12-31

    Sulfate reduction and carbon conversion during pyrolysis and gasification of black liquor particles were experimentally studied in a laminar entrained-flow reactor. A model was also developed to simulate an entrained-flow black liquor gasifier. Experimental results were then compared to model calculations. Results indicated that carbon must be present to get a high degree of sulfate reduction during gasification. It is therefore important to balance the rates of carbon conversion and sulfate reduction. High local temperatures in the reactor should be avoided so that carbon does not convert too rapidly, but temperatures of nearly 1000 degrees C are required to achieve good sulfate reduction. It was suggested that a new equation was needed to adequately predict sulfate reduction in an entrained-flow black liquor gasifier. 12 refs., 8 figs., 5 tabs.

  18. Influence of pressure on pyrolysis of black liquor: 1. Swelling.

    Science.gov (United States)

    Whitty, Kevin; Backman, Rainer; Hupa, Mikko

    2008-02-01

    This is the first of two papers concerning the behavior of black liquor during pyrolysis under pressurized conditions. Two industrial kraft liquors were pyrolyzed in a laboratory-scale pressurized single particle reactor and a pressurized grid heater at temperatures ranging from 650 to 1100 degrees C and at pressures between 1 and 20 bar. The dimensions of the chars produced were measured and the specific swollen volume was calculated. Swelling decreased roughly logarithmically over the pressure range 1-20 r. An expression is developed to predict the specific swollen volume at elevated pressure when the volume at 1 bar is known. The bulk density of the char increased with pressure, indicating that liquors will be entrained less easily at higher pressures.

  19. Engineering study: disposition of terminal liquors for interim storage

    International Nuclear Information System (INIS)

    Metz, W.P.; Ogren, W.E.

    1975-02-01

    Eight alternative processes were chosen as being technologically feasible within the time frame dictated by budgeting procedures and terminal liquor availability. Solidified waste products acceptable for single-shell tank storage were assumed to be placed in available single-shell tanks. Double-shell tanks were used only for the more mobile terminal liquors or semi-solid mush products. The mush, chemical neutralization, and clay in-tank processes offer potential savings of tens of millions of dollars over double-shell tank storage of terminal liquors. In order to achieve this cost savings, the process development and demonstration must be completed prior to the beginning of double-shell tank construction (Dec. 1976) expected to be funded from a fiscal year 1977 line item. Budgeting for these additional double-shell tanks must proceed since the processing options discussed here are not yet available and may not prove to be available at the required time. This study indicates the following topics for additional study: Process technology development to achieve interim storage of terminal liquor products receives the greatest emphasis as a means of reducing capital expenditures. Interim storage product criteria, waste inventory, and conversion to final form require definition to allow comparison of the alternatives for disposition of terminal liquors. The pseudotechnical nature of product acceptability criteria is important to the evaluation of the partial neutralization and aluminum removal alternatives. More accurate estimates of terminal liquor quantity and composition are required to give a sound technical basis for choosing the appropriate processing alternative. Retrieval and reprocessing operations may affect the comparisons presented by this study

  20. Developing Boiler Concepts as Integrated Units

    DEFF Research Database (Denmark)

    Sørensen, Kim; Condra, Thomas Joseph; Houbak, Niels

    2004-01-01

    - consisting of pressure part, burner and control system. The Technical University of Denmark, MEK - Energy Engineering Section [12] has participated in the modelling process. The project has included static and dynamic modelling of the boiler concept. For optimization of operation, verication of performance......With the objective to be able to optimize the design and operation of steam boiler concepts Aalborg Industries A/S [1] has together with Aalborg University, Institute of Energy Technology [9] carried out a development project paying special attention to the boiler concept as an integrated unit......, emissions and to obtain long time operation experiences with the boiler concept, a full scale prototype has been built and these tests have been accomplished on the prototype. By applying this integrated unit approach to the boiler concept development it has been possible to optimize the different building...

  1. Release model for black liquor droplet; Mustalipeaepisaran vapautumismalli

    Energy Technology Data Exchange (ETDEWEB)

    Saastamoinen, J. [VTT Energy, Espoo (Finland)

    1997-10-01

    The release of sodium, potassium, chlorine and sulphur from black liquor droplets during pyrolysis, combustion and gasification is studied by modelling work. A model for drying, pyrolysis and swelling of black liquor has been developed earlier. A submodel for the release of sulphur, which takes place at temperatures below 500 deg C has been incorporated to this model. A previous model for the combustion and gasification of char particles has been further developed to account for the effect of sodium, potassium and chlorine. A model for the release of these components as function of time has been developed. (orig.)

  2. Electrocoagulation treatment of black liquor from paper industry.

    Science.gov (United States)

    Zaied, M; Bellakhal, N

    2009-04-30

    The procedure of electrocoagulation is an effective, fast and economic technique for treatment of black liquor resulting from paper industry. The effect of electrolysis time, current density, type of electrode material and initial pH were studied in an attempt to achieve a higher removal capacity. Under the optimal experimental conditions (initial pH 7, t=50 min and J=14 mA cm(-2)), the treatment of black liquor by electrocoagulation has led to a removal capacity of 98% of COD, 92% of polyphenols and 99% of color intensity with a good repeatability (R.S.D.industrial interest of this electrochemical process.

  3. Plastic Optical Fiber Sensing of Alcohol Concentration in Liquors

    Directory of Open Access Journals (Sweden)

    Masayuki Morisawa

    2012-01-01

    Full Text Available A simple optical fiber sensing system of alcohol concentration in liquors has been studied. In this sensor head, a mixture polymer of novolac resin and polyvinylidenefluoride (PVDF with a ratio of 9 : 1 was coated as a sensitive cladding layer on the plastic fiber core made of polystyrene-(PS-coated polycarbonate (PC. Using this sensor head and a green LED light source, it was confirmed that alcohol concentration in several kinds of liquors from beer to whisky can easily be measured with a fast response time less than 1 minute.

  4. Plastic Optical Fiber Sensing of Alcohol Concentration in Liquors

    OpenAIRE

    Masayuki Morisawa; Shinzo Muto

    2012-01-01

    A simple optical fiber sensing system of alcohol concentration in liquors has been studied. In this sensor head, a mixture polymer of novolac resin and polyvinylidenefluoride (PVDF) with a ratio of 9 : 1 was coated as a sensitive cladding layer on the plastic fiber core made of polystyrene-(PS-)coated polycarbonate (PC). Using this sensor head and a green LED light source, it was confirmed that alcohol concentration in several kinds of liquors from beer to whisky can easily be measured with a...

  5. Chemical cleaning of AGR boilers

    International Nuclear Information System (INIS)

    Moore, S.V.; Moore, W.; Rantell, A.

    1978-01-01

    AGR boilers are likely to require post service chemical cleaning to remove accumulated oxides at intervals of 15 - 35 kh. The need to clean will be based on an assessment of such factors as the development of flow imbalances through parallel tubes induced by the formation of rough oxide surfaces, an increasing risk of localised corrosion as the growth of porous oxides proceeds and the risk of tube blockage caused by the exfoliation of steam-grown oxides. The study has shown what heterogeneous multilayer oxides possessing a range of physical and chemical properties form on the alloy steels. They include porous and compact magnetites, chromium spinels and sesquioxide. Ammoniated citric acid has been shown to remove deposited and water-grown magnetites from the carbon and alloy steels but will not necessarily remove the substituted spinels grown on the alloy steels or the potentially spalling steam-grown magnetite on the A1SI 316 superheater. Citric acid supplemented with the reducing agent glyoxal completely removes all oxides from the boiler except the protective inner spinel formed on the 316. Removal of the spinels and compact magnetites occurs more by undercutting and physical detachment than by the dissolution. (author)

  6. Integrating black liquor gasification with pulping - Process simulation, economics and potential benefits

    Science.gov (United States)

    Lindstrom, Erik Vilhelm Mathias

    Gasification of black liquor could drastically increase the flexibility and improve the profit potential of a mature industry. The completed work was focused on research around the economics and benefits of its implementation, utilizing laboratory pulping experiments and process simulation. The separation of sodium and sulfur achieved through gasification of recovered black liquor, can be utilized in processes like modified continuous cooking, split sulfidity and green liquor pretreatment pulping, and polysulfide-anthraquinone pulping, to improve pulp yield and properties. Laboratory pulping protocols have been developed for these modified pulping technologies and different process options evaluated. The process simulation work around BLG has led to the development of a WinGEMS module for the low temperature MTCI steam reforming process, and case studies comparing a simulated conventional kraft process to different process options built around the implementation of a BLG unit operation into the kraft recovery cycle. Pulp yield increases of 1-3% points with improved product quality, and the potential for capital and operating cost savings relative to the conventional kraft process have been demonstrated. Process simulation work has shown that the net variable operating cost for a pulping process using BLGCC is highly dependent on the cost of lime kiln fuel and the selling price of green power to the grid. Under the assumptions taken in the performed case study, the BLGCC process combined with split sulfidity or PSAQ pulping operations had net variable operating cost 2-4% greater than the kraft reference. The influence of the sales price of power to the grid is the most significant cost factor. If a sales price increase to 6 ¢/KWh for green power could be achieved, cost savings of about $40/ODtP could be realized in all investigated BLG processes. Other alternatives to improve the process economics around BLG would be to modify or eliminate the lime kiln unit

  7. Modelling, simulation, and optimisation of a downflow entrained flow reactor for black liquor gasification

    Energy Technology Data Exchange (ETDEWEB)

    Marklund, Magnus [ETC Energitekniskt Centrum, Piteaa (Sweden)

    2003-12-01

    Black liquor, a by-product of the chemical pulping process, is an important liquid fuel in the pulp and paper industry. A potential technology for improving the recovery cycle of energy and chemicals contained in the liquid fuel is pressurised gasification of black liquor (PGLG). However, uncertainties about the reliability and robustness of the technology are preventing a large-scale market introduction. One important step towards a greater trust in the process reliability is the development of simulation tools that can provide a better understanding of the process and improve performance through optimisation. In the beginning of 2001 a project was initiated in order to develop a simulation tool for an entrained-flow gasifier in PBLG based on CFD (Computational Fluid Dynamics). The aim has been to provide an advanced tool for a better understanding of process performance, to help with trouble shooting in the development plant, and for use in optimisation of a full-scale commercial gasifier. Furthermore, the project will also provide quantitative information on burner functionality through advanced laser-optical measurements by use of a Phase Doppler Anemometer (PDA). To this point in current project, three different concept models have been developed. The work has been comprised in a thesis 'Modelling and Simulation of Pressurised Black Liquor Gasification at High Temperature' and presented at Luleaa Univ. of Technology in Oct 2003. The construction of an atmospheric burner test rig has also been initiated. The main objective with the rig will be to quantify the atomisation performance of suitable burner nozzles for a PBLG gasifier that can be used as input for the CFD model. The main conclusions from the modelling work done this far can be condensed to the following points: From the first modelling results it was concluded that a wide spray pattern is preferable with respect to demand for long residence times for black liquor droplets and a low amount

  8. Advancement of High Temperature Black Liquor Gasification Technology

    Energy Technology Data Exchange (ETDEWEB)

    Craig Brown; Ingvar Landalv; Ragnar Stare; Jerry Yuan; Nikolai DeMartini; Nasser Ashgriz

    2008-03-31

    Weyerhaeuser operates the world's only commercial high-temperature black liquor gasifier at its pulp mill in New Bern, NC. The unit was started-up in December 1996 and currently processes about 15% of the mill's black liquor. Weyerhaeuser, Chemrec AB (the gasifier technology developer), and the U.S. Department of Energy recognized that the long-term, continuous operation of the New Bern gasifier offered a unique opportunity to advance the state of high temperature black liquor gasification toward the commercial-scale pressurized O2-blown gasification technology needed as a foundation for the Forest Products Bio-Refinery of the future. Weyerhaeuser along with its subcontracting partners submitted a proposal in response to the 2004 joint USDOE and USDA solicitation - 'Biomass Research and Development Initiative'. The Weyerhaeuser project 'Advancement of High Temperature Black Liquor Gasification' was awarded USDOE Cooperative Agreement DE-FC26-04NT42259 in November 2004. The overall goal of the DOE sponsored project was to utilize the Chemrec{trademark} black liquor gasification facility at New Bern as a test bed for advancing the development status of molten phase black liquor gasification. In particular, project tasks were directed at improvements to process performance and reliability. The effort featured the development and validation of advanced CFD modeling tools and the application of these tools to direct burner technology modifications. The project also focused on gaining a fundamental understanding and developing practical solutions to address condensate and green liquor scaling issues, and process integration issues related to gasifier dregs and product gas scrubbing. The Project was conducted in two phases with a review point between the phases. Weyerhaeuser pulled together a team of collaborators to undertake these tasks. Chemrec AB, the technology supplier, was intimately involved in most tasks, and focused primarily on the

  9. Quality and generation rate of solid residues in the boiler of a waste-to-energy plant

    DEFF Research Database (Denmark)

    Allegrini, Elisa; Boldrin, Alessio; Jansson, S.

    2014-01-01

    The Danish waste management system relies significantly on waste-to-energy (WtE) plants. The ash produced at the energy recovery section (boiler ash) is classified as hazardous waste, and is commonly mixed with fly ash and air pollution control residues before disposal. In this study, a detailed...... characterization of boiler ash from a Danish grate-based mass burn type WtE was performed, to evaluate the potential for improving ash management. Samples were collected at 10 different points along the boiler's convective part, and analysed for grain size distribution, content of inorganic elements......, polychlorinated dibenzo-. p-dioxins and dibenzofurans (PCDD and PCDF), and leaching of metals. For all samples, PCDD and PCDF levels were below regulatory limits, while high pH values and leaching of e.g. Cl were critical. No significant differences were found between boiler ash from individual sections...

  10. Characterization of Chinese liquor aroma components during aging process and liquor age discrimination using gas chromatography combined with multivariable statistics

    Science.gov (United States)

    Xu, M. L.; Yu, Y.; Ramaswamy, H. S.; Zhu, S. M.

    2017-01-01

    Chinese liquor aroma components were characterized during the aging process using gas chromatography (GC). Principal component and cluster analysis (PCA, CA) were used to discriminate the Chinese liquor age which has a great economic value. Of a total of 21 major aroma components identified and quantified, 13 components which included several acids, alcohols, esters, aldehydes and furans decreased significantly in the first year of aging, maintained the same levels (p > 0.05) for next three years and decreased again (p counterfeit and defective products.

  11. Utilization of black liquor as concrete admixture and set retarder aid

    OpenAIRE

    El-Mekkawi, Samar A.; Ismail, Ibrahim M.; El-Attar, Mohammed M.; Fahmy, Alaa A.; Mohammed, Samia S.

    2011-01-01

    The utilization of black liquor, produced by the pulp and paper industry in Egypt, as a workability aid and set retarder admixture has been investigated. This approach may help eliminate the environmentally polluting black liquor waste. It also provides a low cost by-product, which can be widely used in the construction industry. The properties of black liquor and its performance on concrete at two different ratios of water to cement have been studied. The results revealed that black liquor f...

  12. 19 CFR 122.135 - When airline has in-bond liquor storeroom.

    Science.gov (United States)

    2010-04-01

    ... 19 Customs Duties 1 2010-04-01 2010-04-01 false When airline has in-bond liquor storeroom. 122.135 Section 122.135 Customs Duties U.S. CUSTOMS AND BORDER PROTECTION, DEPARTMENT OF HOMELAND SECURITY; DEPARTMENT OF THE TREASURY AIR COMMERCE REGULATIONS Aircraft Liquor Kits § 122.135 When airline has in-bond liquor storeroom. (a) Restocking. Liquor...

  13. Numerical modelling of the CHEMREC black liquor gasification process. Conceptual design study of the burner in a pilot gasification reactor

    Energy Technology Data Exchange (ETDEWEB)

    Marklund, Magnus

    2001-02-01

    The work presented in this report is done in order to develop a simplified CFD model for Chemrec's pressurised black liquor gasification process. This process is presently under development and will have a number of advantages compared to conventional processes for black liquor recovery. The main goal with this work has been to get qualitative information on influence of burner design for the gas flow in the gasification reactor. Gasification of black liquor is a very complex process. The liquor is composed of a number of different substances and the composition may vary considerably between liquors originating from different mills and even for black liquor from a single process. When a black liquor droplet is gasified it loses its organic material to produce combustible gases by three stages of conversion: Drying, pyrolysis and char gasification. In the end of the conversion only an inorganic smelt remains (ideally). The aim is to get this smelt to form a protective layer, against corrosion and heat, on the reactor walls. Due to the complexity of gasification of black liquor some simplifications had to be made in order to develop a CFD model for the preliminary design of the gasification reactor. Instead of modelling droplets in detail, generating gas by gasification, sources were placed in a prescribed volume where gasification (mainly drying and pyrolysis) of the black liquor droplets was assumed to occur. Source terms for the energy and momentum equations, consistent with the mass source distribution, were derived from the corresponding control volume equations by assuming a symmetric outflow of gas from the droplets and a uniform degree of conversion of reactive components in the droplets. A particle transport model was also used in order to study trajectories from droplets entering the reactor. The resulting model has been implemented in a commercial finite volume code (AEA-CFX) through customised Fortran subroutines. The advantages with this simple

  14. A survey of present levels of radiocesium in Swedish pulp mill liquors and the implications for wood radiocesium transfer factors

    International Nuclear Information System (INIS)

    Ravila, A.; Holm, E.

    1998-01-01

    Assessments of the impact from radioactive fallout on the pulp industry and the accumulation processes for radionuclides in such industries, using wood and water as primary raw materials, have been conducted in previous studies. Hitherto, there is a general lack of data on present levels of radioactivity in pulp mill liquors apart from the few mills studied by [NILSSON (1992)] [RAVILA AND HOLM (1992)] [MANJON ET AL. (1996) and [KROSSHAVN ET AL. (1997)]. A survey was therefore initiated to describe and compare the present activity levels in pulp mill liquors from various mill locations in Sweden. The 137 Cs activity in pulp mill liquors were compared with the mill location and the deposition pattern of the Chernobyl fallout and nuclear weapons fallout. The large input of wood (approx. 2500 m 3 day -1 ) to an average Nordic Kraft mill and the relatively long-term retention time for radiocesium in the Kraft mill recovery cycle enables representative sampling of substances directly related to the activity concentration in wood

  15. 77 FR 10547 - Kickapoo Traditional Tribe of Texas-First Amended Beer and Liquor Tax Ordinance

    Science.gov (United States)

    2012-02-22

    ... Amended Beer and Liquor Tax Ordinance AGENCY: Bureau of Indian Affairs, Interior. ACTION: Notice. SUMMARY: This notice publishes the amendment to the Kickapoo Traditional Tribe of Texas' Beer and Liquor Tax... adopted this amendment to the Kickapoo Traditional Tribe of Texas' Beer and Liquor Tax Ordinance by...

  16. 46 CFR 61.05-15 - Boiler mountings and attachments.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 2 2010-10-01 2010-10-01 false Boiler mountings and attachments. 61.05-15 Section 61.05... TESTS AND INSPECTIONS Tests and Inspections of Boilers § 61.05-15 Boiler mountings and attachments. (a....05-10. (b) Each stud or bolt for each boiler mounting that paragraph (c) of this section requires to...

  17. 46 CFR 63.25-7 - Exhaust gas boilers.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 2 2010-10-01 2010-10-01 false Exhaust gas boilers. 63.25-7 Section 63.25-7 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) MARINE ENGINEERING AUTOMATIC AUXILIARY BOILERS Requirements for Specific Types of Automatic Auxiliary Boilers § 63.25-7 Exhaust gas boilers. (a) Construction...

  18. 49 CFR 230.30 - Lap-joint seam boilers.

    Science.gov (United States)

    2010-10-01

    ... 49 Transportation 4 2010-10-01 2010-10-01 false Lap-joint seam boilers. 230.30 Section 230.30..., DEPARTMENT OF TRANSPORTATION STEAM LOCOMOTIVE INSPECTION AND MAINTENANCE STANDARDS Boilers and Appurtenances Inspection and Repair § 230.30 Lap-joint seam boilers. Every boiler having lap-joint longitudinal seams...

  19. Utilization of Brewery Spent Grain Liquor by Aspergillus niger1

    Science.gov (United States)

    Hang, Y. D.; Splittstoesser, D. F.; Woodams, E. E.

    1975-01-01

    Aspergillus niger was found capable of rapidly converting about 97% of the sugar from brewery spent grain liquor to fungal mass. The yield of dry mycelium, based on the sugar consumed, was approximately 57%. This fungus produced 1.10% titratable acid calculated as citric acid and reduced the biochemical oxygen demand by 96%. PMID:1200633

  20. Context and consequences of liquor sachets use among young ...

    African Journals Online (AJOL)

    This article presents a relatively new phenomenon regarding alcohol related problems in Malawi; the context and consequences of the consumption of liquor sachets among young people. The results presented are part of a larger study looking at the prevalence and social norms related to alcohol use, as well as people's ...

  1. Chemical composition and utilization of Hungarian spent sulfite liquor

    Energy Technology Data Exchange (ETDEWEB)

    Toth, B

    1968-01-01

    A review on the composition of Hungarian spent sulfite liquor and on its possible utilization, e.g., for the manufacturing of vanillin, yeast protein, or ethanol, as well as its direct utilization as a plasticizer for cement, additive for insecticides, or in adhesives.

  2. Selective removal of chromium from sulphuric acid leach liquor of ...

    African Journals Online (AJOL)

    ... removed in multiple batch extractions from the leach liquor and titanium losses were minimal (< 1%). The chromium content of extracted solutions was reduced to less than 1 ppm and thermal hydrolysis of these solutions yielded white titanium(IV) oxide pigments that are suitable for use in the coatings pigment industry.

  3. Feasibility of wood pulping black liquor for treatment of soybean ...

    African Journals Online (AJOL)

    use

    2011-11-23

    Nov 23, 2011 ... This study was carried out to determine the effects of neutral black liquor and moisture heating treatments ... The most commonly used methods of protecting protein include ..... Induced non-enzymatic browning of soybean meal for enhancing efficiency of ... ammonia relase of soluble soybean meal proterin.

  4. Evaluation of ogi liquor from different grains for antibacterial ...

    African Journals Online (AJOL)

    Administrator

    2007-05-02

    May 2, 2007 ... Antibiotic sensitivity pattern of the test organisms. This was done as above except that instead of making wells on the already seeded plates and pouring in the prepared liquors, standard commercial antibiotics disc was placed on the seeded agar plates before the plates were incubated at 37○C for 24 h.

  5. Lauryl Amine as heavy metal collector of boiler ash from pulp and paper mill waste

    Science.gov (United States)

    Sembiring, M. P.; Kaban, J.; Bangun, N.; Saputra, E.

    2018-04-01

    Theincreasing of demand of pulp and paper products, will following with the growing the pulp and paper industryand generate significant mill waste. The total waste reached 1/3 of the amount raw materials used and ash boiler is the waste with the largest percentage of 52%. For that it takes effort to manage the existing waste. The boiler ash contained the chemical elements, it can be utilized such as fertilizer, because it also contains transition metals in form of heavy metal such as Cadmium (Cd), Cobalt (Co), Chrome (Cr), Cupprum (Cu), Ferrum (Fe), Nickel (Ni), and Zinc (Zn), the use of boiler ash must follow the threshold specified by the Government. Several studies have been undertaken to reduce and extract heavy metals from ash and sand of the boiler by using carbon dioxide as its ligand. Eelectrochemical method was used to remove and recovery of heavy metals from the incenerator. This study focused on removal of heavy metals using Lauryl Amine as collector and three solvents namely Dichloromethane, Ethanol and n-Hexane. The treatmentswas able to extract the heavy metal and generally reduce the heavy metal content of ash boiler pulp and paper mill waste. The combination treatment used toreduce the heavy metal content of 5 gram Lauryl Amine collector in Dichloromethane solvent for 4 hours process time.

  6. Electrical design requirements for electrode boilers for nuclear plants

    International Nuclear Information System (INIS)

    Kempker, M.J.

    1979-01-01

    Medium-voltage steam electrode boilers, in the 20- to 50-MW range, have become an attractive alternative to comparable fossil-fueled boilers as a source of auxiliary steam during the startup and normal shutdown of nuclear power plants. The electrode boiler represents a favorable option because of environmental, fire protection, and licensing considerations. However, this electrical option brings some difficult design problems for which solutions are required in order to integrate the electrode boiler into the plant low resistance grounded power system. These considerations include the effects of an unbalanced electrode boiler on the performance of polyphase induction motors, boiler grounding for personnel safety, boiler neutral grounding, and ground relaying

  7. Environmental performance assessment of utility boiler energy conversion systems

    International Nuclear Information System (INIS)

    Li, Changchun; Gillum, Craig; Toupin, Kevin; Park, Young Ho; Donaldson, Burl

    2016-01-01

    Highlights: • Sustainability analyses of utility boilers are performed. • Natural gas fired boilers have the least CO_2 emissions in fossil fueled boilers. • Solar boilers rank last with an emergy yield ratio of 1.2. • Biomass boilers have the best emergy sustainability index. - Abstract: A significant amount of global electric power generation is produced from the combustion of fossil fuels. Steam boilers are one of the most important components for steam and electricity production. The objective of this paper is to establish a theoretical framework for the sustainability analysis of a utility boiler. These analyses can be used by decision-makers to diagnose and optimize the sustainability of a utility boiler. Seven utility boiler systems are analyzed using energy and embodied solar energy (emergy) principles in order to evaluate their environmental efficiencies. They include a subcritical coal fired boiler, a supercritical coal fired boiler, an oil fired boiler, a natural gas fired boiler, a concentrating solar power boiler utilizing a tower configuration, a biomass boiler, and a refuse derived fuel boiler. Their relative environmental impacts were compared. The results show that the natural gas boiler has significantly lower CO_2 emission than an equivalent coal or oil fired boiler. The refuse derived fuel boiler has about the same CO_2 emissions as the natural gas boiler. The emergy sustainability index of a utility boiler system is determined as the measure of its sustainability from an environmental perspective. Our analyses results indicate that the natural gas boiler has a relatively high emergy sustainability index compared to other fossil fuel boilers. Converting existing coal boilers to natural gas boilers is a feasible option to achieve better sustainability. The results also show that the biomass boiler has the best emergy sustainability index and it will remain a means to utilize the renewable energy within the Rankine steam cycle. Before

  8. Chemical cleaning of UK AGR boilers

    International Nuclear Information System (INIS)

    Rudge, A.; Turner, P.; Ghosh, S.; Clary, W.; Tice, D.R.

    2002-01-01

    For a number of years, the waterside pressure drops across the advanced gas-cooled reactor (AGR) pod boilers have been increasing. The pressure drop increases have accelerated with time, which is the converse behaviour to that expected for rippled magnetite formation (rapid initial increase slowing down with time). Nonetheless, magnetite deposition remains the most likely cause for the increasing boiler resistances. A number of potential countermeasures have been considered in response to the boiler pressure drop increases. However, there was no detectable reduction in the rate of pressure drop increase. Chemical cleaning was therefore considered and a project to substantiate and then implement chemical cleaning was initiated. (authors)

  9. Recovery of thebaine and cryptopine from Indian opium.

    Science.gov (United States)

    Ramanathan, V S; Chandra, P

    1980-01-01

    The thebaine content of the opium collected in the Madhya Pradesh region of India has been estimated and reported to range from 1.5 to 2.0 per cent. A technological process for the recovery of thebaine from the mother liquor remaining after the separation of natural codeine in the Government Opium and Alkaloid Works, Neemuch, has been developed in the laboratory and stepped up to an industrial scale. A method for the recovery to thebaine from the waste slaked-lime residues obtained from crude alkaloid cake mother liquor in the Government Opium and Alkaloid Works at Ghazipur has been worked out and the technical details of the process described. The recovery of thebaine would help to increase the production of codeine, and thebaine can also be used as a raw material for the manufacture of other drugs. Cryptopine has also been recovered from the mother liquor after the separation of thebaine.

  10. Treatment of Berkeley boilers in Studsvik. Project description and experiences - Berkeley Boilers Project

    International Nuclear Information System (INIS)

    Saul, Dave; Davidson, Gavin; Wirendal, Bo

    2014-01-01

    In November 2011 Studsvik was awarded a contract to transport five decommissioned boilers from the Berkeley Nuclear Licensed Site in the UK to the Studsvik Nuclear Site in Sweden for metal treatment and recycling. A key objective of the project was to remove the boilers from the site by 31 March 2012 and this was successfully achieved with all boilers off site by 22 March and delivered to Studsvik on 6 April. In November 2012 Studsvik was awarded a further contract for the remaining ten Berkeley Boilers with the requirement to remove all boilers from the Berkeley site by 31 March 2013. Again this was successfully achieved ahead of programme with all boilers in Sweden by 1 April 2013. A total of nine boilers have now been processed and all remaining boilers will be completed by end of September 2014. The projects have had many challenges including a very tight timescale and both have been successfully delivered to cost and ahead of the baseline programme. This paper describes the project and the experience gained from treatment of the boilers to date. (authors)

  11. A comprehensive program to develop correlations for physical properties of kraft black liquor. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Fricke, A.L.; Zaman, A.A.

    1998-05-01

    The overall objective of the program was to develop correlations to predict physical properties within requirements of engineering precision from a knowledge of pulping conditions and of kraft black liquor composition, if possible. These correlations were to include those relating thermodynamic properties to pulping conditions and liquor composition. The basic premise upon which the research was based is the premise that black liquor behaves as a polymer solution. This premise has proven to be true, and has been used successfully in developing data reduction methods and in interpreting results. A three phase effort involving pulping, analysis of liquor composition, and measurement of liquor properties was conducted.

  12. Multi-pressure boiler thermodynamics analysis code

    International Nuclear Information System (INIS)

    Lorenzoni, G.

    1992-01-01

    A new method and the relative FORTRAN program for the thermodynamics design analysis of a multipressure boiler are reported. This method permits the thermodynamics design optimization with regard to total exergy production and a preliminary costs

  13. New thinking for the boiler room.

    Science.gov (United States)

    Rose, Wayne

    2008-09-01

    Wayne Rose, marketing manager at integrated plant room manufacturer Armstrong Integrated Systems, explains how increasing use of off-site manufacture, the latest 3D modelling technology, and advances in control technology, are revolutionising boiler room design and construction.

  14. Modelling and simulating fire tube boiler performance

    DEFF Research Database (Denmark)

    Sørensen, K.; Condra, T.; Houbak, Niels

    2003-01-01

    A model for a flue gas boiler covering the flue gas and the water-/steam side has been formulated. The model has been formulated as a number of sub models that are merged into an overall model for the complete boiler. Sub models have been defined for the furnace, the convection zone (split in 2......: a zone submerged in water and a zone covered by steam), a model for the material in the boiler (the steel) and 2 models for resp. the water/steam zone (the boiling) and the steam. The dynamic model has been developed as a number of Differential-Algebraic-Equation system (DAE). Subsequently Mat......Lab/Simulink has been applied for carrying out the simulations. To be able to verify the simulated results experiments has been carried out on a full scale boiler plant....

  15. Pirotubular boilers design. Diseno de calderas pirotubulares

    Energy Technology Data Exchange (ETDEWEB)

    Latre Durso, F. (Geval S.A. (Spain))

    1994-01-01

    This article describes the conceptual design of Pirotubular boilers from the valuable thermal point of view, to the dimensional. This topic is a very tool valuable for professionals of design and for maintenance and operation equipment.

  16. Water side corrosion prevention in boilers

    International Nuclear Information System (INIS)

    Zeid, A.

    1993-01-01

    Corrosion may be defined as a naturally occurring physical and chemical deterioration of a material due to reaction with the environment or surrounding atmosphere. In boilers the material is subjected on both sides to two different media which may cause severe corrosion. At the water side the content of O 2 considered one of the principal factors which determine the extent of corrosion in the boiler tubes. This paper deals with certain conditions that result in the increase of O 2 in the boiler water and hence increase the corrosion rate, to minimize the effect of these conditions a chemical treatment was carried out the results obtained indicated the success of the treatment procedure in corrosion prevention and boiler material protection. The treatment is traditional. But the study indicates how a simple mean could be applied to solve a serious problem. 4 tab

  17. Catalytic burners in larger boiler appliances

    Energy Technology Data Exchange (ETDEWEB)

    Silversand, Fredrik; Persson, Mikael (Catator AB, Lund (Sweden))

    2009-02-15

    This project focuses on the scale up of a Catator's catalytic burner technology to enable retrofit installation in existing boilers and the design of new innovative combinations of catalytic burners and boilers. Different design approaches are discussed and evaluated in the report and suggestions are made concerning scale-up. Preliminary test data, extracted from a large boiler installation are discussed together with an accurate analysis of technical possibilities following an optimization of the boiler design to benefit from the advantages of catalytic combustion. The experimental work was conducted in close collaboration with ICI Caldaie (ICI), located in Verona, Italy. ICI is a leading European boiler manufacturer in the effect segment ranging from about 20 kWt to several MWt. The study shows that it is possibly to scale up the burner technology and to maintain low emissions. The boilers used in the study were designed around conventional combustion and were consequently not optimized for implementation of catalytic burners. From previous experiences it stands clear that the furnace volume can be dramatically decreased when applying catalytic combustion. In flame combustion, this volume is normally dimensioned to avoid flame impingement on cold surfaces and to facilitate completion of the gas-phase reactions. The emissions of nitrogen oxides can be reduced by decreasing the residence time in the furnace. Even with the over-dimensioned furnace used in this study, we easily reached emission values close to 35 mg/kWh. The emissions of carbon monoxide and unburned hydrocarbons were negligible (less than 5 ppmv). It is possible to decrease the emissions of nitrogen oxides further by designing the furnace/boiler around the catalytic burner, as suggested in the report. Simultaneously, the size of the boiler installation can be reduced greatly, which also will result in material savings, i.e. the production cost can be reduced. It is suggested to optimize the

  18. Authentication of Chinese vintage liquors using bomb-pulse 14C

    Science.gov (United States)

    Cheng, Peng; Zhou, Weijian; Burr, G. S.; Fu, Yunchong; Fan, Yukun; Wu, Shugang

    2016-12-01

    The older a bottle of Chinese vintage liquor is, the higher the price it commands. Driven by the potential for higher profits, some newly-founded distilleries openly sell liquor whose storage ages are exaggerated. In China, the market for vintage liquor has become fraught with uncertainty and a pressing need has arisen to establish an effective method to authenticate the age of vintage liquors. A radiocarbon (14C) dating method is described here that can verify cellar-stored years of Chinese liquors distilled within the last fifty years. Two different flavored Chinese liquors produced in “the golden triangular region” in the Upper Yangtze River region in southwest China, with known cellar-stored years, were analyzed to benchmark the technique. Strong flavored liquors are found to be consistent with local atmospheric Δ14C values. A small offset of 2-3 years between predicted vintage years of soy-sauce flavored liquors and strong flavored liquors is found to be associated with the fermentation cycle of certain varieties. The technique can measure cellar-stored years of a wide range of liquors including those with fundamentally different aromas. This demonstrates the strength of our method in identifying suspect Chinese vintage liquors.

  19. Boiler burden reduced at Bedford site.

    Science.gov (United States)

    Horsley, Chris

    2011-10-01

    With the NHS aiming to reduce its 2007 carbon footprint by 10% by 2015, Chris Horsley, managing director of Babcock Wanson UK, a provider of industrial boilers and burners, thermal oxidisers, air treatment, water treatment, and associated services, looks at how one NHS Trust has approached the challenge, and considerably reduced its carbon emissions, by refurbishing its boiler house and moving from oil to gas-fired steam generation.

  20. Ecological boiler modernization, feasible energy solutions

    International Nuclear Information System (INIS)

    Krcek, F.; Matev, M.; Sykora, J.; Chladek, J.

    2005-01-01

    Alstom Power, s.r.o., ALSTOM GROUP in Brno, Czech Republic is a successor of PBS (First Brno Machine Works). PBS was a well-known company in Bulgaria - mainly as Heating Power Plant (HPP) and Industrial Plant supplier of boilers, industrial steam turbines, milling systems, heat exchangers Btc. PBS has been privatised in two stages starting at1993 year. Alstom recently deals with boiler and heat exchanger products. Industrial turbine but has been sold to Siemens in 2004

  1. Gas fired boilers and atmospheric pollution

    International Nuclear Information System (INIS)

    Chiaranello, J.M.

    1991-01-01

    A general analysis concerning atmospheric pollution is presented: chemical composition and vertical distribution of atmosphere and pollutants, chemical reactions, ozone destruction and production cycles, COx, NOx and SOx pollutions. The gas fired boiler number and repartition in France are presented and the associated pollution is analyzed (CO2, CO, NOx) and quantified. Various pollution control technics concerning gas fired boiler pollutants are described and a pollution criterion for clean gas fired generators is proposed

  2. Purification of Polymer-Grade Fumaric Acid from Fermented Spent Sulfite Liquor

    Directory of Open Access Journals (Sweden)

    Diogo Figueira

    2017-04-01

    Full Text Available Fumaric acid is a chemical building block with many applications, namely in the polymer industry. The fermentative production of fumaric acid from renewable feedstock is a promising and sustainable alternative to petroleum-based chemical synthesis. The use of existing industrial side-streams as raw-materials within biorefineries potentially enables production costs competitive against current chemical processes, while preventing the use of refined sugars competing with food and feed uses and avoiding purposely grown crops requiring large areas of arable land. However, most industrial side streams contain a diversity of molecules that will add complexity to the purification of fumaric acid from the fermentation broth. A process for the recovery and purification of fumaric acid from a complex fermentation medium containing spent sulfite liquor (SSL as a carbon source was developed and is herein described. A simple two-stage precipitation procedure, involving separation unit operations, pH and temperature manipulation and polishing through the removal of contaminants with activated carbon, allowed for the recovery of fumaric acid with 68.3% recovery yield with specifications meeting the requirements of the polymer industry. Further, process integration opportunities were implemented that allowed minimizing the generation of waste streams containing fumaric acid, which enabled increasing the yield to 81.4% while keeping the product specifications.

  3. Assessment of physical workload in boiler operations.

    Science.gov (United States)

    Rodrigues, Valéria Antônia Justino; Braga, Camila Soares; Campos, Julio César Costa; Souza, Amaury Paulo de; Minette, Luciano José; Sensato, Guilherme Luciano; Moraes, Angelo Casali de; Silva, Emília Pio da

    2012-01-01

    The use of boiler wood-fired is fairly common equipment utilized in steam generation for energy production in small industries. The boiler activities are considered dangerous and heavy, mainly due to risks of explosions and the lack of mechanization of the process. This study assessed the burden of physical labor that operators of boilers are subjected during the workday. Assessment of these conditions was carried out through quantitative and qualitative measurements. A heart rate monitor, a wet-bulb globe thermometer (WBGT), a tape-measure and a digital infrared camera were the instruments used to collect the quantitative data. The Nordic Questionnaire and the Painful Areas Diagram were used to relate the health problems of the boiler operator with activity. With study, was concluded that the boiler activity may cause pains in the body of intensity different, muscle fatigue and diseases due to excessive weight and the exposure to heat. The research contributed to improve the boiler operator's workplace and working conditions.

  4. Increasing the thermal efficiency of boiler plant

    Directory of Open Access Journals (Sweden)

    Uyanchinov Evgeniy

    2017-01-01

    Full Text Available The thermal efficiency increase of boiler plant is actual task of scientific and technical researches. The optimization of boiler operating conditions is task complex, which determine by most probable average load of boiler, operating time and characteristics of the auxiliary equipment. The work purpose – the determination of thermodynamic efficiency increase ways for boiler plant with a gas-tube boiler. The tasks, solved at the research are the calculation of heat and fuel demand, the exergetic analysis of boilerhouse and heat network equipment, the determination of hydraulic losses and exergy losses due to restriction. The calculation was shown that the exergy destruction can be reduced by 2.39% due to excess air reducing to 10%; in addition the oxygen enrichment of air can be used that leads to reducing of the exergy destruction rate. The processes of carbon deposition from the side of flame and processes of scale formation on the water side leads to about 4.58% losses of fuel energy at gas-tube boiler. It was shown that the exergy losses may be reduced by 2.31% due to stack gases temperature reducing to 148 °C.

  5. Physical properties of kraft black liquor. Final report. Phase I

    Energy Technology Data Exchange (ETDEWEB)

    Fricke, A.L.

    1983-12-01

    Methods were selected, equipment installed, and procedures developed for determining rheological properties; for determining thermal properties (stability, density, thermal expansion, and heat capacity); for purification and characterization of lignin (glass transition, stability, weight average molecular weight, and number average molecular weight); and for performing chemical analyses (negative inorganic ions, positive inorganic ions, acid organic salts, lignin, and total solids). A strategy for pulping to supply test liquors was developed, and a statistically designed pulping experiment was specified for a Southern softwood species. Arrangements were made for performing initial pulping work in an industrial pilot plant, and a preliminary set of pulping experiments were conducted. Liquors from the preliminary pulping experiments were used to test procedures and to determine reproducibility of the experiment. Literature was also surveyed and preliminary selection of designs for a pilot digester, and for equipment to determine surface tension were made.

  6. Pelly Crossing wood chip boiler

    Energy Technology Data Exchange (ETDEWEB)

    1985-03-11

    The Pelly wood chip project has demonstrated that wood chips are a successful fuel for space and domestic water heating in a northern climate. Pelly Crossing was chosen as a demonstration site for the following reasons: its extreme temperatures, an abundant local supply of resource material, the high cost of fuel oil heating and a lack of local employment. The major obstacle to the smooth operation of the boiler system was the poor quality of the chip supply. The production of poor quality chips has been caused by inadequate operation and maintenance of the chipper. Dull knives and faulty anvil adjustments produced chips and splinters far in excess of the one centimetre size specified for the system's design. Unanticipated complications have caused costs of the system to be higher than expected by approximately $15,000. The actual cost of the project was approximately $165,000. The first year of the system's operation was expected to accrue $11,600 in heating cost savings. This estimate was impossible to confirm given the system's irregular operation and incremental costs. Consistent operation of the system for a period of at least one year plus the installation of monitoring devices will allow the cost effectiveness to be calculated. The wood chip system's impact on the environment was estimated to be minimal. Wood chip burning was considered cleaner and safer than cordwood burning. 9 refs., 6 figs., 6 tabs.

  7. Boiler and HRSG tube failures. Lesson 4: Hydrogen damage

    Energy Technology Data Exchange (ETDEWEB)

    Dooley, R. Barry; Bursik, Albert

    2010-02-15

    University 101 courses are typically designed to help incoming first-year undergraduate students to adjust to the university, develop a better understanding of the college environment, and acquire essential academic success skills. Why are we offering a special Boiler and HRSG Tube Failures PPChem 101? The answer is simple, yet very conclusive: There is a lack of knowledge on the identification of tube failure mechanisms and for the implementation of adequate counteractions in many power plants, particularly at industrial power and steam generators. There is a lack of knowledge to prevent repeat tube failures. The vast majority of BTF/HTF have been, and continue to be, repeat failures. It is hoped that the information about the failure mechanisms of BTF supplied in this course will help to put plant engineers and chemists on the right track. The major goal of this course is the avoidance of repeat BTF. This fourth lesson is focused on hydrogen damage of water-touched tubes in conventional boilers and in the high-pressure evaporators of heat recovery steam generators. (orig.)

  8. Boiler and HRSG tube failures. Lesson 5. Caustic gouging

    Energy Technology Data Exchange (ETDEWEB)

    Dooley, Barry R.; Bursik, Albert

    2010-03-15

    University 101 courses are typically designed to help incoming first-year undergraduate students to adjust to the university, develop a better understanding of the college environment, and acquire essential academic success skills. Why are we offering a special Boiler and HRSG Tube Failures PPChem 101? The answer is simple, yet very conclusive: - There is a lack of knowledge on the identification of tube failure mechanisms and for the implementation of adequate counteractions in many power plants, particularly at industrial power and steam generators. - There is a lack of knowledge to prevent repeat tube failures. The vast majority of BTF/HTF have been, and continue to be, repeat failures. It is hoped that the information about the failure mechanisms of BTF supplied in this course will help to put plant engineers and chemists on the right track. The major goal of this course is the avoidance of repeat BTF. This fifth lesson is focused on caustic gouging of water-touched tubes in conventional boilers and in the high-pressure evaporators of heat recovery steam generators. (orig.)

  9. Hydrogen production by supercritical water gasification of alkaline black liquor

    Energy Technology Data Exchange (ETDEWEB)

    Cao, Changqing; Guo, Liejin; Chen, Yunan; Lu, Youjun [Xi' an Jiatong Univ. (China)

    2010-07-01

    Black liquor was gasified continuously in supercritical water successfully and the main gaseous products were H{sub 2}, CO{sub 2} and CH{sub 4} with little amount of CO, C{sub 2}H{sub 4} and C{sub 2}H{sub 6}. The increase of the temperature and the decrease of the flow rate and black liquor concentration enhanced SCWG of black liquor. The change of the system pressure had limited influence on the gasification effect. The maximal COD removal efficiency of 88.69 % was obtained at the temperature of 600 C. The pH values of the aqueous residue were all decreased to the range of 6.4{proportional_to}8 while the pH value of cooling effluence below 360 C increased to about 11 and the sodium content was much higher than that in the aqueous residue. The reaction rate for COD degradation in supercritical water was obtained by assuming pseudo first order reaction. And the activation energy and pre-exponential for COD removal in SCWG were 74.38kJ/mol and 1.11 x 10{sup 4} s{sup -1} respectively. (orig.)

  10. Application of Evaporative Cooling for the Condensation of Water Vapors from a Flue Gas Waste Heat Boilers CCP

    Directory of Open Access Journals (Sweden)

    Galashov Nikolay

    2016-01-01

    Full Text Available The object of the study are boilers that burn organic fuel and the recovery boilers (RB of the combined cycle plant (CCP, which are al-so working on the products of the combustion of hydrocarbon fuels. The purpose of research is to find technologies that increase efficiency of the thermal power plant (TPP and technologies that reduce the environmental impact on the environment by burning fossil fuels. The paper deals with the technology of the boilers burning hydrocarbon fuel with condensation of water vapor from the exhaust flue gases. Considered the problems caused by using of this technology. Research shows that the main problem of this technology in the boilers is the lack of reliable methods of calculation of heat exchangers, condensers. Particular attention is paid to the application of this technology in the recovery boilers combined-cycle plants, which are currently gaining increasing use in the generation of electricity from the combustion of gas in power plants. It is shown that the application of technology of condensation of water vapor in RB CCP, the temperature decreases of exhaust gases from 100 to 40 °С, allows increasing the effi-ciency of the RB with 86.2 % to 99.5 %, i.e. at 12.3 %, and increase the ef-ficiency of the CCP at 2.8 %.

  11. Fenton process combined with coagulation for the treatment of black liquor from bioethanol wastewater

    Science.gov (United States)

    Muryanto, Muryanto; Hanifah, Ummu; Amriani, Feni; Ibadurrahman, Ahmad Faiz; Sari, Ajeng Arum

    2017-11-01

    High amounts of black liquor are generated from bioethanol production by using oil palm empty fruit bunches. The black liquor is waste from alkaline pretreatment, it contains high amount of an alkaline solution (NaOH). The black liquor wastewater was highly contaminated with organic materials, and quite toxic for aquatic ecosystems if discharged directly into waters. This study aimed to determine ability of Fenton process combined with coagulation to treat black liquor. The addition 5% of polyaluminium chloride (PAC) could decolorized black liquor, degraded lignin, and produced sludge 70.64%, 68.28%, and 2.76 gram, respectively. Decolorization of black liquor was in line with degradation of black liquor because lignin is the main compound in black liquor. SEM images after addition of PAC of 5% indicated fragmentation of structure. Fenton reagent consist of 0.7 M FeSO4+ 3M H2O2 has able to decolorize black liquor, degrade lignin, and produce sludge 51.67% and 25.44%, and 0.44 gram, respectively. It was concluded that black liquor wastewater from bioethanol can be treated by using Fenton process combined with coagulation. However, these methods still need improvement to obtain the higher degradation rate, and coagulation sludge needs further consideration.

  12. Project recovers free wasted energy from an OSB dryer while eliminating a hog boiler

    Energy Technology Data Exchange (ETDEWEB)

    Normandin, A.; Levesque, S.; Laflamme, Y.; Charron, R. [Mesar-Environair Inc., Quebec, PQ (Canada)

    2008-09-15

    This article described how a mill producing oriented strand board (OSB) in Quebec optimized its energy balance with the installation of a flue gas heat recovery (FGHR) system developed by Mesar-Environair Inc. Many OSB mills produce enough wood waste heat to supply their hog boilers with valuable, yet inexpensive, fuel. The objective of this project was to recover waste heat and to find an application in the milling process to re-valorize it. The plant was using 3 hog boilers to heat thermal oil for their process, but only the newest hog boiler was in compliance for particulate emissions levels. The solution involved the use of a direct contact heat exchanger to meet the mill's requirements. The process consisted of pumping the log pond water in a counter-current direction to the humid OSB dryer flue gas. The energy was transferred from the gas to the water via vapor condensation. The customized equipment recovered most of the wasted heat and transferred it to the plant's log ponds. Cool process water from the log ponds was then recirculated through the condenser to trap the wasted energy. The efficiency of the main hog boiler and the chip dry was about 80 per cent. The FGHR process was designed to recover 85 per cent of the wasted energy that was directed to the atmosphere. The heat recovery unit can typically generate temperatures of 70 to 80 degrees C. In addition to fewer emissions of carbon dioxide and nitrogen oxides going out the stack, the FGHR system offers the advantages of heating the process water without additional fuel, and shutting down an old hog boiler. 1 tabs., 3 figs.

  13. Disturbances of the liquor circulation: differential diagnosis of the hydrocephalus by radionuclide scintigraphy, pneumoencephalography and determination of the liquor pressure

    International Nuclear Information System (INIS)

    Fuhrmeister, U.; Boerner, W.; Wuerzburg Univ.

    1976-01-01

    Normal-pressure hydrocephalus (NPH) is a special case of communicating hydrocephalus with disturbed resorption of cerebrospinal fluid. Because of the therapeutic consequences, NPH must be clearly differentiated from cerebral atrophy with compensatory increase of the liquor and from hydrocephalus with well-balanced cerebrospinal fluid. NPH is indicated by: excessive pressure rise after artificial volume load on the liquor space in spinal infusion tests; in the X-ray picture, an internal hydrocephalus; an acute-angled corpus callosum, and a progressive ventricular enlargement following in the pneumoencephalography; ventricular reflux with stasis in radionuclide cisternography. In some limiting cases, the diagnosis can be facilitated by a quantitative functional study of the dynamics of the cerebrospinal fluid with the aid of radionuclides. The biological half-life of 131 I albumin is doubled when the resorption of the cerebrospinal fluid is disturbed. (orig.) [de

  14. Disturbances of the liquor circulation: differential diagnosis of the hydrocephalus by radionuclide scintigraphy, pneumoencephalography and determination of the liquor pressure

    Energy Technology Data Exchange (ETDEWEB)

    Fuhrmeister, U; Boerner, W [Wuerzburg Univ. (F.R. Germany). Neurologische Klinik; Wuerzburg Univ. (F.R. Germany). Nuklearmedizinische Abt.)

    1976-06-01

    Normal-pressure hydrocephalus (NPH) is a special case of communicating hydrocephalus with disturbed resorption of cerebrospinal fluid. Because of the therapeutic consequences, NPH must be clearly differentiated from cerebral atrophy with compensatory increase of the liquor and from hydrocephalus with well-balanced cerebrospinal fluid. NPH is indicated by: excessive pressure rise after artificial volume load on the liquor space in spinal infusion tests; in the x-ray picture, an internal hydrocephalus; an acute-angled corpus callosum, and a progressive ventricular enlargement following in the pneumoencephalography; ventricular reflux with stasis in radionuclide cisternography. In some limiting cases, the diagnosis can be facilitated by a quantitative functional study of the dynamics of the cerebrospinal fluid with the aid of radionuclides. The biological half-life of /sup 131/I albumin is doubled when the resorption of the cerebrospinal fluid is disturbed.

  15. HIGHLY ENERGY EFFICIENT D-GLU (DIRECTED-GREEN LIQ-UOR UTILIZATION) PULPING

    Energy Technology Data Exchange (ETDEWEB)

    Lucia, Lucian A

    2013-04-19

    Purpose: The purpose of the project was to retrofit the front end (pulp house) of a commercial kraft pulping mill to accommodate a mill green liquor (GL) impregna-tion/soak/exposure and accrue downstream physical and chemical benefits while prin-cipally reducing the energy footprint of the mill. A major player in the mill contrib-uting to excessive energy costs is the lime kiln. The project was intended to offload the energy (oil or natural gas) demands of the kiln by by-passing the causticization/slaking site in the recovery area and directly using green liquor as a pulping medium for wood. Scope: The project was run in two distinct, yet mutually compatible, phases: Phase 1 was the pre-commercial or laboratory phase in which NC State University and the Insti-tute of Paper Science and Technology (at the Georgia Institute of Technology) ran the pulping and associated experiments, while Phase 2 was the mill scale trial. The first tri-al was run at the now defunct Evergreen Pulp Mill in Samoa, CA and lead to a partial retrofit of the mill that was not completed because it went bankrupt and the work was no longer the low-hanging fruit on the tree for the new management. The second trial was run at the MeadWestvaco Pulp Mill in Evedale, TX which for all intents and pur-poses was a success. They were able to fully retrofit the mill, ran the trial, studied the pulp properties, and gave us conclusions.

  16. Boiler house modernization through shared savings program

    Energy Technology Data Exchange (ETDEWEB)

    Breault, R.W. [Tecogen, Waltham, MA (United States)

    1995-12-31

    Throughout Poland as well as the rest of Eastern Europe, communities and industries rely on small heat only boilers to provide district and process heat. Together these two sectors produce about 85,000 MW from boilers in the 2 to 35 MW size range. The bulk of these units were installed prior to 1992 and must be completely overhauled to meet the emission regulations which will be coming into effect on January 1, 1998. Since the only practical fuel is coal in most cases, these boilers must be either retrofit with emission control technology or be replaced entirely. The question that arises is how to accomplish this given the current tight control of capital in Poland and other East European countries. A solution that we have for this problem is shared savings. These boilers are typically operating with a quiet low efficiency as compared to western standards and with excessive manual labor. Installing modernization equipment to improve the efficiency and to automate the process provides savings. ECOGY provides the funds for the modernization to improve the efficiency, add automation and install emission control equipment. The savings that are generated during the operation of the modernized boiler system are split between the client company and ECOGY for a number of years and then the system is turned over in entirety to the client. Depending on the operating capacity, the shared savings agreement will usually span 6 to 10 years.

  17. The load structure of electro boilers

    International Nuclear Information System (INIS)

    Feilberg, N.; Livik, K.

    1995-01-01

    Load measurements have been performed on 24 electro boilers with a time resolution of one hour throughout a period of one year. The boilers are used for space heating and heating of tap water in office buildings, shopping centres and apartment buildings. All boilers have tariffs with disconnection agreements. This report presents load analyses of the measurements from each boiler, and typical load profiles are calculated and presented. It also analyses how boilers are used in relation to the outdoor temperature and the power price on the spot market. All the measurements are performed in Bergen, Norway, in the period August 1993 - August 1994. Typical load profiles are shown, both annual and daily, as well as specific load parameters in addition to key figures used in calculating the total power load on the distribution network. The climate impact on energy and power load is evaluated. The report also shows examples of how the results may be applied in various special fields. 8 figs., 9 tabs

  18. Increasing the efficiency of the condensing boiler

    Science.gov (United States)

    Zaytsev, ON; Lapina, EA

    2017-11-01

    Analysis of existing designs of boilers with low power consumption showed that the low efficiency of the latter is due to the fact that they work in most cases when the heating period in the power range is significantly less than the nominal power. At the same time, condensing boilers do not work in the most optimal mode (in condensing mode) in the central part of Russia, a significant part of their total operating time during the heating season. This is due to existing methods of equipment selection and joint operation with heating systems with quantitative control of the coolant. It was also revealed that for the efficient operation of the heating system, it is necessary to reduce the inertia of the heat generating equipment. Theoretical patterns of thermal processes in the furnace during combustion gas at different radiating surfaces location schemes considering the influence of the very furnace configuration, characterized in that to reduce the work condensing boiler in conventional gas boiler operation is necessary to maintain a higher temperature in the furnace (in the part where spiral heat exchangers are disposed), which is possible when redistributing heat flow - increase the proportion of radiant heat from the secondary burner emitter allow Perey For the operation of the condensing boiler in the design (condensation) mode practically the entire heating period.

  19. Ultrasonic boiler inspection and economic analysis guidelines

    International Nuclear Information System (INIS)

    Anon.

    1987-01-01

    Boiler tube failures cause approximately 6% availability loss of large fossil-fired power generating plants. This loss can be reduced by systematic approaches using ultrasonic examination and root cause failure analysis methods. Two projects sponsored by EPRI have provided utility engineers with guidelines for performing ultrasonic examinations and with details on 22 types of tube failure mechanisms. A manual has been published that provides descriptions of typical locations, superficial appearances, damage mechanisms, metallurgy, microstructural changes, likely root causes, and potential corrective actions. Application of the principles in the manual is being demonstrated in an EPRI-funded project at 10 electric utilities over the next two years. Guidelines have been published that prescribe the activities necessary for ultrasonic examinations of boiler tubes. Eight essential elements of a boiler examination should be performed to assure that possible economic benefits are obtained. Work was supported by EPRI under RP 1890 and RP 1865. A software package has been developed for effectively planning inspections for wall thinning in fossil-fired boiler tubing. The software assists in minimizing costs associated with maintenance, such as inspection and repair, while the life of the boiler is maximized

  20. Reuse of Anode Slime Generated by the Zinc Industry to Obtain a Liquor for Manufacturing Electrolytic Manganese

    Science.gov (United States)

    Ayala, J.; Fernández, B.

    2013-08-01

    A hydrometallurgical process is proposed in this article to recover manganese from a zinc electrowinning residue. The article describes the digestion-leaching experiments, precipitation, and electrowinning assays to recover Mn from this residue. Anode slime is treated with sulfuric acidic in a furnace within a temperature range of 400-450°C, leached with water, and then filtered. The results show that the dissolution of manganese increases with increasing temperature in the digestion step. The recovery yield of manganese was higher than 90%. As manganese electrolysis requires an electrolyte free of Zn, Ni, Co, and Cu pollutants, the sulfuric acid liquor needs a purification step. Na2S is used to remove pollutants. The results obtained in this study have shown that the proposed process for the recovery of manganese from this type of residue is technically viable.

  1. 46 CFR 52.25-5 - Miniature boilers (modifies PMB-1 through PMB-21).

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 2 2010-10-01 2010-10-01 false Miniature boilers (modifies PMB-1 through PMB-21). 52.25... ENGINEERING POWER BOILERS Other Boiler Types § 52.25-5 Miniature boilers (modifies PMB-1 through PMB-21). Miniature boilers must meet the applicable provisions in this part for the boiler type involved and the...

  2. Evaluation of thermal overload in boiler operators.

    Science.gov (United States)

    Braga, Camila Soares; Rodrigues, Valéria Antônia Justino; Campos, Julio César Costa; de Souza, Amaury Paulo; Minette, Luciano José; de Moraes, Angêlo Casali; Sensato, Guilherme Luciano

    2012-01-01

    The Brazilians educational institutions need a large energy demand for the operation of laundries, restaurants and accommodation of students. Much of that energy comes from steam generated in boilers with wood fuel. The laboral activity in boiler may present problems for the operator's health due to exposure to excessive heat, and its operation has a high degree of risk. This paper describes an analysis made the conditions of thermal environment in the operation of a B category boiler, located at a Higher Education Institution, located in the Zona da Mata Mineira The equipments used to collect data were Meter WBGT of the Heat Index; Meter of Wet Bulb Index and Globe Thermometer (WBGT); Politeste Instruments, an anemometer and an Infrared Thermometer. By the application of questionnaires, the second phase consisted of collecting data on environmental factors (temperature natural environment, globe temperature, relative humidity and air velocity). The study concluded that during the period evaluated, the activity had thermal overload.

  3. Performance of Ceriporiopsis sp. in the Treatment of Black Liquor Wastewater

    OpenAIRE

    Sari, Ajeng Arum

    2016-01-01

    High amounts of black liquor wastewater are generated from bioethanol production by using oil palm empty fruit bunches. It contains an alkaline solution (NaOH), so it is quite toxic for aquatic ecosystems if discharged directly into waters. Black liquor has been treated by coagulation method, and it still needs additional treatment. This study aimed to determine degradation of black liquor wastewater by selected white-rot fungi (WRF). Five different strains of WRF have been tested for their a...

  4. 19 CFR 122.134 - When airline does not have in-bond liquor storeroom.

    Science.gov (United States)

    2010-04-01

    ... 19 Customs Duties 1 2010-04-01 2010-04-01 false When airline does not have in-bond liquor storeroom. 122.134 Section 122.134 Customs Duties U.S. CUSTOMS AND BORDER PROTECTION, DEPARTMENT OF HOMELAND SECURITY; DEPARTMENT OF THE TREASURY AIR COMMERCE REGULATIONS Aircraft Liquor Kits § 122.134 When airline does not have in-bond liquor storeroom. (a...

  5. 46 CFR 61.05-20 - Boiler safety valves.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 2 2010-10-01 2010-10-01 false Boiler safety valves. 61.05-20 Section 61.05-20 Shipping... INSPECTIONS Tests and Inspections of Boilers § 61.05-20 Boiler safety valves. Each safety valve for a drum, superheater, or reheater of a boiler shall be tested at the interval specified by table 61.05-10. [CGD 95-028...

  6. Computer simulation of the fire-tube boiler hydrodynamics

    Directory of Open Access Journals (Sweden)

    Khaustov Sergei A.

    2015-01-01

    Full Text Available Finite element method was used for simulating the hydrodynamics of fire-tube boiler with the ANSYS Fluent 12.1.4 engineering simulation software. Hydrodynamic structure and volumetric temperature distribution were calculated. The results are presented in graphical form. Complete geometric model of the fire-tube boiler based on boiler drawings was considered. Obtained results are suitable for qualitative analysis of hydrodynamics and singularities identification in fire-tube boiler water shell.

  7. Application of GPRS and GIS in Boiler Remote Monitoring System

    OpenAIRE

    Hongchao Wang; Yifeng Wu

    2012-01-01

    Application of GPRS and GIS in boiler remote monitoring system was designed in this paper by combining the advantage of GPRS and GIS in remote data transmission with configuration monitoring technology. The detail information of the operating conditions of the industrial boiler can be viewed by marking the location of boiler on the electronic map dynamically which can realize the unified management for industrial boiler of a region or city conveniently. Experimental application show that the ...

  8. Control Properties of Bottom Fired Marine Boilers

    DEFF Research Database (Denmark)

    Solberg, Brian; Andersen, Palle; Karstensen, Claus M. S.

    2005-01-01

    This paper focuses on model analysis of a dynamic model of a bottom fired one-pass smoke tube boiler. Linearised versions of the model are analysed to determine how gain, time constants and right half plane zeros (caused by the shrink-and-swell phenomenon) depend on the steam flow load. Furthermore...... the interactions in the system are inspected to analyse potential benefit from using a multivariable control strategy in favour of the current strategy based on single loop theory. An analysis of the nonlinear model is carried out to further determine the nonlinear characteristics of the boiler system...

  9. Developing trends with boiler operation and management

    Energy Technology Data Exchange (ETDEWEB)

    Stark, J.M. [Occupational Safety and Health Service, Wellington (New Zealand). Dept. of Labour, Engineering Safety Branch

    1993-12-31

    Over recent years there have been many improvements in boiler control and safety management systems. Technology has made major advances and is now regarded as being well proven in Australia, Europe and the United Kingdom and these changes have been examined by a project committee, convened for the purpose, to establish whether they are equally applicable in New Zealand. The result of the committee`s findings and experience is contained in the `Draft Code of Practice`. This paper explains the development of the `Code of Practice`, the reasoning behind some of the decisions taken and the implications of these changes to boiler owners.

  10. Optimal load allocation of multiple fuel boilers.

    Science.gov (United States)

    Dunn, Alex C; Du, Yan Yi

    2009-04-01

    This paper presents a new methodology for optimally allocating a set of multiple industrial boilers that each simultaneously consumes multiple fuel types. Unlike recent similar approaches in the utility industry that use soft computing techniques, this approach is based on a second-order gradient search method that is easy to implement without any specialized optimization software. The algorithm converges rapidly and the application yields significant savings benefits, up to 3% of the overall operating cost of industrial boiler systems in the examples given and potentially higher in other cases, depending on the plant circumstances. Given today's energy prices, this can yield significant savings benefits to manufacturers that raise steam for plant operations.

  11. Firewood boiler operators and heat exposure

    Directory of Open Access Journals (Sweden)

    Vilson Bernardo Stollmeier

    2017-12-01

    Full Text Available This article presents an analysis of heat exposure work in boiler industry wood from a company in the industrial sector, focusing on the analysis of the environmental burden of the activity. Therefore, the methodological procedures consisted of document analysis, interviews, filming, evaluation problems of the effects of the hot environment and its prevention. The results show that the fuel to the boiler operators are exposed to heat and need guidance on their daily activities with prevention of diseases affected by excessive heat. Are also suggested training in technical and health to improve working conditions and the operator's health.

  12. Boiler inspection manipulator for Torness Power Station

    International Nuclear Information System (INIS)

    Carrey, R.T.A.; Yule, I.Y.; Sibson, S.; Playle, M.J.

    1996-01-01

    The Advanced Gas-cooled Reactors at Torness and Heysham 2 are provided with dedicated access for remote inspection equipment. These in-service inspection (ISI) accesses comprise 12 penetrations above the core for inspection of the above core area and boilers, 12 below core penetrations for inspection of the lower boiler area and access through any of the 8 gas circulator penetrations for inspection of the sub-diagrid area. This paper describes a manipulator which will access the reactor from above the core via any of the 8 peripheral penetrations. (UK)

  13. TA-2 Water Boiler Reactor Decommissioning Project

    International Nuclear Information System (INIS)

    Durbin, M.E.; Montoya, G.M.

    1991-06-01

    This final report addresses the Phase 2 decommissioning of the Water Boiler Reactor, biological shield, other components within the biological shield, and piping pits in the floor of the reactor building. External structures and underground piping associated with the gaseous effluent (stack) line from Technical Area 2 (TA-2) Water Boiler Reactor were removed in 1985--1986 as Phase 1 of reactor decommissioning. The cost of Phase 2 was approximately $623K. The decommissioning operation produced 173 m 3 of low-level solid radioactive waste and 35 m 3 of mixed waste. 15 refs., 25 figs., 3 tabs

  14. Yeast community associated with the solid state fermentation of traditional Chinese Maotai-flavor liquor.

    Science.gov (United States)

    Wu, Qun; Chen, Liangqiang; Xu, Yan

    2013-09-02

    Yeasts are the most important group of microorganisms contributing to liquor quality in the solid-state fermentation process of Chinese Maotai-flavor liquor. There occurred a complex yeast community structure during this process, including stages of Daqu (the starter) making, stacking fermentation on the ground and liquor fermentation in the pits. In the Daqu making stage, few yeast strains accumulated. However, the stacking fermentation stage accumulated nine yeast species with different physio-biochemical characteristics. But only four species kept dominant until liquor fermentation, which were Zygosaccharomyces bailii, Saccharomyces cerevisiae, Pichia membranifaciens, and Schizosaccharomyces pombe, implying their important functions in liquor making. The four species tended to inhabit in different locations of the stack and pits during stacking and liquor fermentation, due to the condition heterogeneity of the solid-state fermentation, including the different fermentation temperature profiles and oxygen density in different locations. Moreover, yeast population was much larger in the upper layer than that in the middle and bottom layers in liquor fermentation, which was in accordance with the profile of reducing sugar consumption and ethanol production. This was a systematical investigation of yeast community structure dynamics in the Maotai-flavor liquor fermentation process. It would be of help to understand the fermentative mechanism in solid-state fermentation for Maotai-flavor liquor. © 2013.

  15. Treatment of black liquor from the papermaking industry by acidification and reuse.

    Science.gov (United States)

    Yang, Wen-Bo; Mu, Huan-Zhen; Huang, Yan-Chu

    2003-09-01

    Two different kinds of black liquor from the papermaking industry were treated by acidification and reuse. The experimental parameters and conditions were discussed in detail. The experimental results indicated that the treatment process mentioned in this article is an effective process for the treatment of black liquor from the papermaking industry. By the treatment, the solid materials in black liquor are transferred into two by-products and the other components are reused or evaporated. Thus, no wastewater except some condensation water would be discharged in pulping process and the problem of pollution of black liquor would be effectively solved.

  16. Antioxidant capacity of Kraft black liquor from the pulp and paper industry.

    Science.gov (United States)

    Perez-Perez, Elizabeth; Rodríguez-Malaver, Antonio J

    2005-07-01

    The effect of Kraft black liquor on the lipid peroxidation of rat homogenates was examined. The lipid peroxidation of homogenates from different organs (kidney, brain, lung, and liver) was induced by Fenton's reagent. The products of lipid peroxidation, lipid hydroperoxides and TBARS were measured by FOX method and TBA assay, respectively. It was found that black liquor significantly reduced the concentration of TBARS, but not the concentration of lipid hydroperoxides. This inhibition was directly proportional to the concentration of Kraft black liquor and the incubation temperature. Conclusively, the black liquor from pulp and paper industry exhibited an antioxidant activity.

  17. 46 CFR 56.50-30 - Boiler feed piping.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 2 2010-10-01 2010-10-01 false Boiler feed piping. 56.50-30 Section 56.50-30 Shipping... APPURTENANCES Design Requirements Pertaining to Specific Systems § 56.50-30 Boiler feed piping. (a) General... least two separate means of supplying feed water for the boilers. All feed pumps shall be fitted with...

  18. Biomass boiler conversion potential in the eastern United States

    Science.gov (United States)

    Charles D. Ray; Li Ma; Thomas Wilson; Daniel Wilson; Lew McCreery; Janice K. Wiedenbeck

    2013-01-01

    The U.S. is the world's leading consumer of primary energy. A large fraction of this energy is used in boiler installations to generate steam and hot water for heating applications. It is estimated there are total 163,000 industrial and commercial boilers in use in the United States of all sizes. This paper characterizes the commercial and industrial boilers in...

  19. New materials for boilers in USC power plants

    International Nuclear Information System (INIS)

    Hong, Sung Ho; Hong, Seok Joo

    2003-01-01

    The efficiency of boiler in fossil power plants is a strong function of steam temperature and pressure. Thus, the main technology of increasing boiler efficiency is the development of stronger high temperature materials, capable of operating under high stresses at ever increasing temperature. This paper will presents the new material relating to boiler of USC power plant

  20. 46 CFR 176.812 - Pressure vessels and boilers.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 7 2010-10-01 2010-10-01 false Pressure vessels and boilers. 176.812 Section 176.812... TONS) INSPECTION AND CERTIFICATION Material Inspections § 176.812 Pressure vessels and boilers. (a.... (b) Periodic inspection and testing requirements for boilers are contained in § 61.05 in subchapter F...

  1. 46 CFR 115.812 - Pressure vessels and boilers.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 4 2010-10-01 2010-10-01 false Pressure vessels and boilers. 115.812 Section 115.812... CERTIFICATION Material Inspections § 115.812 Pressure vessels and boilers. (a) Pressure vessels must be tested... testing requirements for boilers are contained in § 61.05 in subchapter F of this chapter. [CGD 85-080, 61...

  2. 46 CFR 109.205 - Inspection of boilers and machinery.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 4 2010-10-01 2010-10-01 false Inspection of boilers and machinery. 109.205 Section 109... OPERATIONS Tests, Drills, and Inspections § 109.205 Inspection of boilers and machinery. The chief engineer or engineer in charge, before he assumes charge of the boilers and machinery of a unit shall inspect...

  3. 40 CFR 63.988 - Incinerators, boilers, and process heaters.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 10 2010-07-01 2010-07-01 false Incinerators, boilers, and process... Routing to a Fuel Gas System or a Process § 63.988 Incinerators, boilers, and process heaters. (a) Equipment and operating requirements. (1) Owners or operators using incinerators, boilers, or process...

  4. Aspects of new material application for boilers construction

    International Nuclear Information System (INIS)

    Czerniawski, R.

    1996-01-01

    Review of steel types commonly used for energetic boilers construction has been done. The worldwide trends in new materials application for improvement of boilers quality have been discussed. The mechanical properties of boiler construction steels have been shown and compared. 3 refs, 5 figs, 1 tab

  5. Lower price for solar boilers must improve market penetration

    International Nuclear Information System (INIS)

    Koevoet, J.B.J.

    1999-01-01

    The Dutch government aims at 1.7 PJ thermal energy for the year 2007 to be supplied by solar water heaters. For that target the number of installed solar boilers must increase seven times the number of installed solar boilers in 1998. This can be stimulated by a considerable reduction of the market price for such boilers

  6. 10 CFR 431.82 - Definitions concerning commercial packaged boilers.

    Science.gov (United States)

    2010-01-01

    ... gases. Manufacturer of a commercial packaged boiler means any person who manufactures, produces... 10 Energy 3 2010-01-01 2010-01-01 false Definitions concerning commercial packaged boilers. 431.82... COMMERCIAL AND INDUSTRIAL EQUIPMENT Commercial Packaged Boilers § 431.82 Definitions concerning commercial...

  7. 40 CFR 761.71 - High efficiency boilers.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 30 2010-07-01 2010-07-01 false High efficiency boilers. 761.71... PROHIBITIONS Storage and Disposal § 761.71 High efficiency boilers. (a) To burn mineral oil dielectric fluid containing a PCB concentration of ≥50 ppm, but boiler shall comply with the following...

  8. 49 CFR 230.36 - Hydrostatic testing of boilers.

    Science.gov (United States)

    2010-10-01

    ... 49 Transportation 4 2010-10-01 2010-10-01 false Hydrostatic testing of boilers. 230.36 Section 230... Appurtenances Pressure Testing of Boilers § 230.36 Hydrostatic testing of boilers. (a) Time of test. The... to any hydrostatic pressure. Hydrostatic testing required by these rules shall be conducted at 25...

  9. Efficient exfoliation of layered materials by waste liquor

    Science.gov (United States)

    Ding, Jiheng; Zhao, Hongran; Zheng, Yan; Wang, Qiaolei; Chen, Hao; Dou, Huimin; Yu, Haibin

    2018-03-01

    Based on their unique material properties, two-dimensional (2D) nanomaterials such as graphene, molybdenum disulfide (MoS2), and boron nitride (BN) have been attracting increased research interest. The potential of 2D materials, in the form of nanoplatelets that are used as new materials, will be important to both nanomaterials and advanced materials. Water is usually considered to be the ideal dispersed medium, and the essential hydrophobicity and limitations to mass production of 2D nanoplatelets have become quite serious obstacles to their usage in various fields. In this paper, pulping black liquor was used as dispersant, with high concentration of lignin to get single- and few-layered nanoplatelets. The whole process required only the high-shear mixing of 2D layered materials and pulping waste liquor. This method was not only simple and efficient but also environmentally friendly and resource-recycling. Moreover, the fabricated single- or few-layered nanoplatelets possessed good solubility in aqueous solution due to their edge functionalization, and could be well dispersed in water at concentrations (10 mg ml-1 for graphene, 6.3 mg ml-1 for MoS2, and 6.0 mg ml-1 for BN) which were much higher than that of other methods. The dispersions of graphene, MoS2, and BN nanosheets were highly stable over several months, which allowed us to easily prepare graphene, MoS2, and BN films through simple vacuum filtration or spraying. These results indicated that pulping black liquor can be used as a material or reagent, and the mass production of 2D material is possible in a simple and fast method.

  10. Generation of PHB from Spent Sulfite Liquor Using Halophilic Microorganisms.

    Science.gov (United States)

    Weissgram, Michaela; Gstöttner, Janina; Lorantfy, Bettina; Tenhaken, Raimund; Herwig, Christoph; Weber, Hedda K

    2015-06-08

    Halophilic microorganisms thrive at elevated concentrations of sodium chloride up to saturation and are capable of growing on a wide variety of carbon sources like various organic acids, hexose and also pentose sugars. Hence, the biotechnological application of these microorganisms can cover many aspects, such as the treatment of hypersaline waste streams of different origin. Due to the fact that the high osmotic pressure of hypersaline environments reduces the risk of contamination, the capacity for cost-effective non-sterile cultivation can make extreme halophilic microorganisms potentially valuable organisms for biotechnological applications. In this contribution, the stepwise use of screening approaches, employing design of experiment (DoE) on model media and subsequently using industrial waste as substrate have been implemented to investigate the applicability of halophiles to generate PHB from the industrial waste stream spent sulfite liquor (SSL). The production of PHB on model media as well as dilutions of industrial substrate in a complex medium has been screened for by fluorescence microscopy using Nile Blue staining. Screening was used to investigate the ability of halophilic microorganisms to withstand the inhibiting substances of the waste stream without negatively affecting PHB production. It could be shown that neither single inhibiting substances nor a mixture thereof inhibited growth in the investigated range, hence, leaving the question on the inhibiting mechanisms open. However, it could be demonstrated that some haloarchaea and halophilic bacteria are able to produce PHB when cultivated on 3.3% w/w dry matter spent sulfite liquor, whereas H. halophila was even able to thrive on 6.6% w/w dry matter spent sulfite liquor and still produce PHB.

  11. A novel method to prepare L-Arabinose from xylose mother liquor by yeast-mediated biopurification

    Directory of Open Access Journals (Sweden)

    Lin Shuangjun

    2011-06-01

    Full Text Available Abstract Background L-arabinose is an important intermediate for anti-virus drug synthesis and has also been used in food additives for diets-controlling in recent years. Commercial production of L-arabinose is a complex progress consisting of acid hydrolysis of gum arabic, followed by multiple procedures of purification, thus making high production cost. Therefore, there is a biotechnological and commercial interest in the development of new cost-effective and high-performance methods for obtaining high purity grade L-arabinose. Results An alternative, economical method for purifying L-arabinose from xylose mother liquor was developed in this study. After screening 306 yeast strains, a strain of Pichia anomala Y161 was selected as it could effectively metabolize other sugars but not L-arabinose. Fermentation in a medium containing xylose mother liquor permitted enrichment of L-arabinose by a significant depletion of other sugars. Biochemical analysis of this yeast strain confirmed that its poor capacity for utilizing L-arabinose was due to low activities of the enzymes required for the metabolism of this sugar. Response surface methodology was employed for optimization the fermentation conditions in shake flask cultures. The optimum conditions were: 75 h fermentation time, at 32.5°C, in a medium containing 21% (v/v xylose mother liquor. Under these conditions, the highest purity of L-arabinose reached was 86.1% of total sugar, facilitating recovery of white crystalline L-arabinose from the fermentation medium by simple methods. Conclusion Yeast-mediated biopurification provides a dynamic method to prepare high purity of L-arabinose from the feedstock solution xylose mother liqour, with cost-effective and high-performance properties.

  12. The denitration of simulated fast reactor highly active liquor waste

    International Nuclear Information System (INIS)

    Saum, C.J.; Ford, L.H.; Blatts, N.

    1981-01-01

    A short series of tests have been made with simulated HAL containing representative concentrations of palladium and phosphate ion. The information obtained has been confirmed in a small scale continuous denitration plant. These cases of four stirred pot reactors arranged in cascade. One possible advantage of this plant would be the low mean acidity in the first stage compared to the feed material which would limit to some extent the violence of the reaction. This would lead to a lower rate of gas evolution and may permit operation even with liquors where foaming is a problem. (DG)

  13. Oxidizing attack process of uranium ore by a carbonated liquor

    International Nuclear Information System (INIS)

    Maurel, Pierre; Nicolas, Francois.

    1981-01-01

    A continuous process for digesting a uraniferous ore by oxidation with a recycling aqueous liquor containing alkaline carbonates and bicarbonates in solution as well as uranium in a concentration close to its solubility limit at digestion temperature, and of recuperation of the precipitated uranium within the solid phase remaining after digestion. The digestion is carried out by spraying oxygen into the hot reactional medium in order not only to permit oxidation of the uranium and its solubilization but also to ensure that the sulphides of impurities and organic substances present in the ore are oxidized [fr

  14. Effects of Quebracho Tannin on Recovery of Colloidal Gold from ...

    African Journals Online (AJOL)

    This paper considered effects of Quebracho Tannin (QT) on recovery of gold from the oxidized flotation concentrate wash liquor. The effect of Quebracho Tannin on Total Suspended Solids (TSS) was also established. This research established that the gold lost to tailings was not soluble in the effluent but was mainly in the ...

  15. Optimization of Boiler Heat Load in Water-Heating Boiler-House

    Directory of Open Access Journals (Sweden)

    B. A. Bayrashevsky

    2009-01-01

    Full Text Available An analytical method for optimization of water-heating boiler loads has been developed on the basis of approximated semi-empirical dependences pertaining to changes of boiler gross efficiency due to its load. A complex (∂tух/∂ξΔξ is determined on the basis of a systematic analysis (monitoring of experimental data and the Y. P. Pecker’s formula for calculation of balance losses q2. This complex makes it possible to set a corresponding correction to a standard value of the boiler gross efficiency due to contamination of heating surfaces.Software means for optimization of water-heating boilers has been developed and it is recommended to be applied under operational conditions.

  16. Modelling and verification of once-through subcritical heat recovery steam generator

    International Nuclear Information System (INIS)

    Lee, Chae Soo; Choi, Young Jun; Kim, Hyun Gee; Yang, Ok Chul; Chong Chae Hon

    2004-01-01

    The once-through heat recovery steam generator is ideally matched to very high temperature and pressure, well into the supercritical range. Moreover this type of boiler is structurally simpler than drum type boiler. In drum type boiler, each tube play a well-defined role: water preheating, vaporization, superheating. Empirical equations are available to predict the average heat transfer coefficient for each regime. For once-through heat recovery steam generator, this is no more the case and mathematical models have to be adapted to account for the disappearance of drum type economizer, boiler, superheater. General equations have to be used for each tube of boiler, and actual heat transfer condition in each tube has to be identified

  17. ENVIRONMENTAL ASPECTS OF MODERNIZATION OF HIGH POWER WATER-HEATING BOILERS

    Directory of Open Access Journals (Sweden)

    P. M. Glamazdin

    2016-01-01

    Full Text Available Boilers of KVGM and PTVM series are characterized by high values of NOx and CO content in the combustion products. Reduction of NOx and CO content can be achieved by two ways: by installing the condensing heat recovery unit at the boiler outlet and by improving the heat and mass transfer processes in boiler furnaces. Application of the condensing heat recovery units causes pollution of resulting condensate by low-concentration acids. The authors conducted a study in order to determine the effectiveness of the previously applied methods of suppressing the emission of nitrogen oxides in the boilers of these types. Equalization of the temperature field and, consequently, enhancement of heat transfer in the furnace by substitution the used burners by the more advanced ones, the design of which facilitates reduction the emission of nitrogen oxides, were applied to all the upgraded facilities. The studies fulfilled demonstrate that a reduction of NOx emissions in water-heating high power boilers is fairly possible by means of modernization of the latter. The authors have developed the project of the PTVM-30 boiler modernization, which was implemented at a large boiler plant in the city of Vinnitsa (Ukraine. The project included a number of technical solutions. Six burners were replaced by the two ones that were located in the hearth; also the hearth screen was dismantled. At the same time, reducing the total surface area of the heating caused by the exclusion of hearth screen was compensated by filling the locations of the six embrasures of staff burners on the side screens with straightened furnace tubes. Installing the burners separate from the screen made it possible to eliminate the transfer of vibration to the furnace tubes, and – via them – to the boilers setting. Automation provided “associated regulations”. Draught machines were equipped with frequency regulators. During commissioning of the boiler the studies were carried out that

  18. Control Properties of Bottom Fired Marine Boilers

    DEFF Research Database (Denmark)

    Solberg, Brian; Andersen, Palle; Karstensen, Claus M. S.

    2007-01-01

    This paper focuses on model analysis of a dynamic model of a bottom fired one-pass smoke tube boiler. Linearized versions of the model are analyzed and show large variations in system gains at steady state as function of load whereas gain variations near the desired bandwidth are small. An analys...

  19. Selecting Actuator Configuration for a Benson Boiler

    DEFF Research Database (Denmark)

    Kragelund, Martin Nygaard; Leth, John-Josef; Wisniewski, Rafal

    2009-01-01

    with particular focus on a boiler in a power plant operated by DONG Energy - a Danish energy supplier. The problem has been reformulated using mathematic notions from economics. The selection of actuator configuration has been limited to the fuel system which in the considered plant consists of three different...

  20. Model boiler studies on deposition and corrosion

    International Nuclear Information System (INIS)

    Balakrishnan, P.V.; McVey, E.G.

    1977-09-01

    Deposit formation was studied in a model boiler, with sea-water injections to simulate the in-leakage which could occur from sea-water cooled condensers. When All Volatile Treatment (AVT) was used for chemistry control the deposits consisted of the sea-water salts and corrosion products. With sodium phosphate added to the boiler water, the deposits also contained the phosphates derived from the sea-water salts. The deposits were formed in layers of differing compositions. There was no significant corrosion of the Fe-Ni-Cr alloy boiler tube under deposits, either on the open area of the tube or in crevices. However, carbon steel that formed a crevice around the tube was corroded severely when the boiler water did not contain phosphate. The observed corrosion of carbon steel was caused by the presence of acidic, highly concentrated chloride solution produced from the sea-water within the crevice. Results of theoretical calculations of the composition of the concentrated solution are presented. (author)

  1. Environmental control during steam boiler washing

    Energy Technology Data Exchange (ETDEWEB)

    Guimaraes, Marcio A.B.; Abreu Pereira, Vera L. de [Companhia Petroquimica do Nordeste (COPENE), Camacari, BA (Brazil). Div. de Engenharia Ambiental; Ringler, Ulrich E.S. [PROMON Engenharia Ltda., Salvador, BA (Brazil)

    1993-12-31

    The washing and chemical cleaning of boilers, activities of a high polluting potential, are responsible for the generation of wastewater of high contents of heavy metals, suspended solids and chemical oxygen demand (COD). This paper describes the actions carried out by COPENE - Petroquimica do Nordeste S/A - in order to reduce this problem. (author). 10 refs., 3 figs., 2 tabs.

  2. The investigation of the locomotive boiler material

    International Nuclear Information System (INIS)

    Tucholski, Z.; Wasiak, J.; Bilous, W.; Hajewska, E.

    2006-01-01

    In the paper, the history of narrow-gauge railway system is described. The other information about the steam locomotive construction, as well as the technical regulations of its construction and exploitation are also done. The results of the studies of the locomotive boiler material are presented. (authors)

  3. Coal reburning technology for cyclone boilers

    International Nuclear Information System (INIS)

    Yagiela, A.S.; Maringo, G.J.; Newell, R.J.; Farzan, H.

    1990-01-01

    Babcock and Wilcox has obtained encouraging results from engineering feasibility and pilot-scale proof-of-concept studies of coal reburning for cyclone boiler NO x control. Accordingly, B and W completed negotiations for a clean coal cooperative agreement with the Department of Energy to demonstrate coal reburning technology for cyclone boilers. The host site for the demonstration is the Wisconsin Power and Light (WP and L) Company's 100MWe Nelson Dewey Station. Reburning involves the injection of a supplemental fuel (natural gas, oil, or coal) into the main furnace to produce locally reducing stoichiometric conditions which convert the NO x produced therein to molecular nitrogen, thereby reducing overall NO x emissions. There are currently no commercially-demonstrated combustion modification techniques for cyclone boilers which reduce NO x emissions. The emerging reburning technology offers cyclone boiler operators a promising alternative to expensive flue gas cleanup techniques for NO x emission reduction. This paper reviews baseline testing results at the Nelson Dewey Station and pilot-scale results simulating Nelson Dewey operation using pulverized coal (PC) as the reburning fuel. Outcomes of the model studies as well as the full-scale demonstration preliminary design are discussed

  4. Environmental control during steam boiler washing

    Energy Technology Data Exchange (ETDEWEB)

    Guimaraes, Marcio A.B.; Abreu Pereira, Vera L. de [Companhia Petroquimica do Nordeste (COPENE), Camacari, BA (Brazil). Div. de Engenharia Ambiental; Ringler, Ulrich E.S. [PROMON Engenharia Ltda., Salvador, BA (Brazil)

    1994-12-31

    The washing and chemical cleaning of boilers, activities of a high polluting potential, are responsible for the generation of wastewater of high contents of heavy metals, suspended solids and chemical oxygen demand (COD). This paper describes the actions carried out by COPENE - Petroquimica do Nordeste S/A - in order to reduce this problem. (author). 10 refs., 3 figs., 2 tabs.

  5. Recovery of naphthalene, anthracene, etc. , from tar

    Energy Technology Data Exchange (ETDEWEB)

    1920-12-25

    A process is described for the recovery of naphthalene, anthracene, and the like from tar oils and similar liquors, characterized in that the oil is treated in a rapidly rotating hammer mill, such as a colloid mill, with water sufficient, in the presence or absence of suitable solvents, for the only portion preferably in the presence of emulsifiers; and is filtered through a filter with fine pores.

  6. Mixture of working fluids in ORC plants with pool boiler evaporator

    International Nuclear Information System (INIS)

    Rajabloo, Talieh; Iora, Paolo; Invernizzi, Costante

    2016-01-01

    Highlights: • We assess the feasibility of pool boiler in ORCs operating with mixture working fluids. • We consider hydrocarbon and siloxane mixtures for low and high temperature ORCs. • Plants with pool boiler show comparable performances to once through evaporator. - Abstract: Power generation using Organic Rankine Cycle was studied in this paper in case of both low and high temperature cycles, exploiting respectively a geothermal heat source available at 167 °C, and heat available at 300 °C from the combustion of biomass. In particular we assess the feasibility of employing mixture of working fluids, in the case of replacing the typical once-through (OT) evaporator with the pool boiler (PB) technology, typically adopted for pure fluids. The analysis evidenced that in general the OT evaporator shows a slightly improved cycle performance in comparison to the PB and it results in some cases advantageous with respect to the pure working fluid. For instance in case of low temperature cycle, the best thermodynamic performances are obtained with mixture of i-C_5 and 75% n-C_4 in case of OT evaporator, yielding a recovery efficiency higher than the case with pure i-C_5 (7.7 vs. 7.4%) given the relatively higher values of both the recovery factor and cycle efficiency. Implementation of PB did not affect the plant performance significantly which shows the feasibility of having PB with potentially easier control.

  7. Quality and generation rate of solid residues in the boiler of a waste-to-energy plant.

    Science.gov (United States)

    Allegrini, E; Boldrin, A; Jansson, S; Lundtorp, K; Fruergaard Astrup, T

    2014-04-15

    The Danish waste management system relies significantly on waste-to-energy (WtE) plants. The ash produced at the energy recovery section (boiler ash) is classified as hazardous waste, and is commonly mixed with fly ash and air pollution control residues before disposal. In this study, a detailed characterization of boiler ash from a Danish grate-based mass burn type WtE was performed, to evaluate the potential for improving ash management. Samples were collected at 10 different points along the boiler's convective part, and analysed for grain size distribution, content of inorganic elements, polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD and PCDF), and leaching of metals. For all samples, PCDD and PCDF levels were below regulatory limits, while high pH values and leaching of e.g. Cl were critical. No significant differences were found between boiler ash from individual sections of the boiler, in terms of total content and leaching, indicating that separate management of individual ash fractions may not provide significant benefits. Copyright © 2014 Elsevier B.V. All rights reserved.

  8. Physical properties of highly active liquor containing molybdate solids

    International Nuclear Information System (INIS)

    Dunnett, B.; Ward, T.; Roberts, R.; Cheeseright, J.

    2016-01-01

    The reprocessing of irradiated nuclear fuel at Sellafield produces a nitric acid based Highly Active Liquor (HAL) waste. The liquor, containing fission products and process additives, is concentrated in an evaporator in order to reduce the volume and is then stored in Highly Active Storage Tanks (HASTs) prior to vitrification. Caesium phosphomolybdate (CPM) is precipitated during the evaporation process and can convert to zirconium molybdate (ZM) during storage. During Post Operational Clean Out (POCO) of the HASTs, it is expected that their highly active content will be reduced by repeated cycles of washing using nitric acid and other reagents. Initial washings are likely to have a chemical composition comparable to concentrated HAL, becoming more dilute during the wash-out process. It is expected that the wash-out process will also recover significant quantities of molybdate solids (ZM, CPM or a mixture) from the HASTs. In order to determine the processing challenges from such washings during POCO, the physical properties of varying concentrations of non-active HAL simulants containing molybdate solids have recently been measured by the UK's National Nuclear Laboratory. The following measurements are presented and discussed: Particle size distribution; Density; Settling behaviour of solids; Voidage of settled sediment beds; Viscosity; Yield stress; And influence of ZM morphology on physical properties. (authors)

  9. D-Xylose from waste liquors of a viscose process

    Energy Technology Data Exchange (ETDEWEB)

    Hashimoto, T; Mimura, M

    1977-12-14

    D-Xylose was prepared in good yields by neutralizing alkali waste liquors containing hemicellulose (I) with inorganic acids, dialyzing to remove salts hydrolyzing with acids, fermenting to decompose hexose, decolorizing, concentrating to < 15% sugars, treating with alcohols to precipitate oligosugars, removing the precipitate, and crystalizing. Thus, 1 kg waste liquor containing 27 g I was neutralized with 5% HCl, dialyzed at 15/sup 0/ for 48 h with parchment paper, concentrated at 40/sup 0/ to give a 500 g solution containing 7% H/sub 2/SO/sub 4/, boiled for 3 h, neutralized with BaCO/sub 3/, mixed with 10 g yeast at pH 5.4 to 5.8 (filtrate) fermented at 35/sup 0/ for 12 h, filtered, decolorized, concentrated at 40/sup 0/ to > 80 g mixed with EtOH to give a precipitate, filtered, concentrated to 17 g syrup, and mixed with AcOH to obtain 7.2 g D-Xylose.

  10. Physical properties of highly active liquor containing molybdate solids

    Energy Technology Data Exchange (ETDEWEB)

    Dunnett, B.; Ward, T.; Roberts, R. [National Nuclear Laboratory, Sellafield, Seascale, Cumbria, CA20 1PG (United Kingdom); Cheeseright, J. [Sellafield Ltd, Sellafield, Seascale, Cumbria, CA20 1PG (United Kingdom)

    2016-07-01

    The reprocessing of irradiated nuclear fuel at Sellafield produces a nitric acid based Highly Active Liquor (HAL) waste. The liquor, containing fission products and process additives, is concentrated in an evaporator in order to reduce the volume and is then stored in Highly Active Storage Tanks (HASTs) prior to vitrification. Caesium phosphomolybdate (CPM) is precipitated during the evaporation process and can convert to zirconium molybdate (ZM) during storage. During Post Operational Clean Out (POCO) of the HASTs, it is expected that their highly active content will be reduced by repeated cycles of washing using nitric acid and other reagents. Initial washings are likely to have a chemical composition comparable to concentrated HAL, becoming more dilute during the wash-out process. It is expected that the wash-out process will also recover significant quantities of molybdate solids (ZM, CPM or a mixture) from the HASTs. In order to determine the processing challenges from such washings during POCO, the physical properties of varying concentrations of non-active HAL simulants containing molybdate solids have recently been measured by the UK's National Nuclear Laboratory. The following measurements are presented and discussed: Particle size distribution; Density; Settling behaviour of solids; Voidage of settled sediment beds; Viscosity; Yield stress; And influence of ZM morphology on physical properties. (authors)

  11. On-line monitoring system for utility boiler diagnostics

    International Nuclear Information System (INIS)

    Radovanovic, P.M.; Afgan, N.H.; Caralho, M.G.

    1997-01-01

    The paper deals with the new developed modular type Monitoring System for Utility Boiler Diagnostics. Each module is intended to assess the specific process and can be used as a stand alone application. Four modules are developed, namely: LTC - module for the on-line monitoring of parameters related to the life-time consumption of selected boiler components; TRD - module for the tube rupture detection by the position and working fluid Ieakage quantity; FAM - module for the boiler surfaces fouling (slagging) assessment and FLAP - module for visualization of the boiler furnace flame position. All four modules are tested on respective pilot plants built oil the 200 and 300 MWe utility boilers. Monitoring System is commercially available and can be realized in any combination of its modules depending on demands induced by the operational problems of specific boiler. Further development of Monitoring System is performed in accordance with the respective EU project on development of Boiler Expert System. (Author)

  12. The behavior of ash species in suspension fired biomass boilers

    DEFF Research Database (Denmark)

    Jensen, Peter Arendt

    While fluid bed and grate fired boilers initially was the choice of boilers used for power production from both wood and herbaceous biomass, in recent years suspension fired boilers have been increasingly used for biomass based power production. In Denmark several large pulverized fuel boilers have...... been converted from coal to biomass combustion in the last 15 years. This have included co-firing of coal and straw, up to 100% firing of wood or straw andthe use of coal ash as an additive to remedy problems with wood firing. In parallel to the commercialization of the pulverized biomass firing...... technology a long range of research studies have been conducted, to improve our understanding of the influence and behavior of biomass ash species in suspension fired boilers. The fuel ash plays a key role with respect tooptimal boiler operation and influences phenomena’s as boiler chamber deposit formation...

  13. Evaluation of anaerobic digestion processes for short sludge-age waste activated sludge combined with anammox treatment of digestate liquor.

    Science.gov (United States)

    Ge, Huoqing; Batstone, Damien; Keller, Jurg

    2016-01-01

    The need to reduce energy input and enhance energy recovery from wastewater is driving renewed interest in high-rate activated sludge treatment (i.e. short hydraulic and solids retention times (HRT and SRT, respectively)). This process generates short SRT activated sludge stream, which should be highly degradable. However, the evaluation of anaerobic digestion of short SRT sludge has been limited. This paper assesses anaerobic digestion of short SRT sludge digestion derived from meat processing wastewater under thermophilic and mesophilic conditions. The thermophilic digestion system (55°C) achieved 60 and 68% volatile solids destruction at 8 day and 10 day HRT, respectively, compared with 50% in the mesophilic digestion system (35°C, 10 day HRT). The digestion effluents from the thermophilic (8-10 day HRT) and mesophilic systems were stable, as assessed by residual methane potentials. The ammonia rich sludge dewatering liquor was effectively treated by a batch anammox process, which exhibited comparable nitrogen removal rate as the tests using a control synthetic ammonia solution, indicating that the dewatering liquor did not have inhibiting/toxic effects on the anammox activity.

  14. Analysis of potassium nitrate purification with recovery of solvent through single effect mechanical vapor compression

    Directory of Open Access Journals (Sweden)

    Kiprotich E. Kosgey

    2017-12-01

    Full Text Available Analysis of purification of potassium nitrate with incorporation of single effect mechanical vapor compressor for solvent recovery was done. Analysis focused on the effect of concentration and temperature of mother liquor on the energy efficiency of the process and the amount of recovered solvent. Performance coefficient of mechanical vapor compressor ranged between 1.5 and 7.5 depending primarily on the temperature of mother liquor. It was found that with increase in temperature of mother liquor through pre-heating, the power of the compressor, compression ratio and amount of heat supplied to the evaporator decrease. For a 40% concentrated feed solution and mother liquor temperature above 80 °C, performance coefficient is higher than 4. It is therefore concluded that preheating mother liquor and reduction of the effect of concentration of both mother liquor and concentrated waste stream through other methods reduces the power consumption of purification process. Keywords: Performance coefficient, Mother liquor, Concentrated solution, Recovered solvent, Boiling point elevation, Mechanical vapor compressor

  15. De kristallisatie-methode bij het onderzoek van de liquor cerebro-spinalis

    NARCIS (Netherlands)

    Wittermans, Aafko Willinge

    1941-01-01

    Ongeveer twaalfhonderd liquores zijn volgens een in de kliniek nog weinig bekende zeer eenvoudige methode van onderzoek van den Roemeenschen Hoogleraar TOMESCO onderzocht. Deze methode berust op het beoordeelen van het kristalbeeld dat ontstaat bij het indampen van druppels sterk verdunde liquor

  16. Rapid identification of Chinese Sauce liquor from different fermentation positions with FT-IR spectroscopy

    Science.gov (United States)

    Li, Changwen; Wei, Jiping; Zhou, Qun; Sun, Suqin

    2008-07-01

    FT-IR and two-dimensional correlation spectroscopy (2D-IR) technology were applied to discriminate Chinese Sauce liquor from different fermentation positions (top, middle and bottom of fermentation cellar) for the first time. The liquors at top, middle and bottom of fermentation cellar, possessed the characteristic peaks at 1731 cm -1, 1733 cm -1 and 1602 cm -1, respectively. In the 2D correlation infrared spectra, the differences were amplified. A strong auto-peak at 1725 cm -1 showed in the 2D spectra of the Top Liquor, which indicated that the liquor might contain some ester compounds. Different from Top Liquor, three auto-peaks at 1695, 1590 and 1480 cm -1 were identified in 2D spectra of Middle Liquor, which were the characteristic absorption of acid, lactate. In 2D spectra of Bottom Liquor, two auto-peaks at 1570 and 1485 cm -1 indicated that lactate was the major component. As a result, FT-IR and 2D-IR correlation spectra technology provided a rapid and effective method for the quality analysis of the Sauce liquor.

  17. Discrimination between authentic and adulterated liquors by near-infrared spectroscopy and ensemble classification

    Science.gov (United States)

    Chen, Hui; Tan, Chao; Wu, Tong; Wang, Li; Zhu, Wanping

    2014-09-01

    Chinese liquor is one of the famous distilled spirits and counterfeit liquor is becoming a serious problem in the market. Especially, age liquor is facing the crisis of confidence because it is difficult for consumer to identify the marked age, which prompts unscrupulous traders to pose off low-grade liquors as high-grade liquors. An ideal method for authenticity confirmation of liquors should be non-invasive, non-destructive and timely. The combination of near-infrared spectroscopy with chemometrics proves to be a good way to reach these premises. A new strategy is proposed for classification and verification of the adulteration of liquors by using NIR spectroscopy and chemometric classification, i.e., ensemble support vector machines (SVM). Three measures, i.e., accuracy, sensitivity and specificity were used for performance evaluation. The results confirmed that the strategy can serve as a screening tool applied to verify adulteration of the liquor, that is, a prior step used to condition the sample to a deeper analysis only when a positive result for adulteration is obtained by the proposed methodology.

  18. Feasibility of disposing waste glyphosate neutralization liquor with cement rotary kiln

    Energy Technology Data Exchange (ETDEWEB)

    Bai, Y.; Bao, Y.B.; Cai, X.L.; Chen, C.H. [College of Materials Science and Engineering, Nanjing Tech University, Nanjing 210009 (China); State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University, Nanjing 210009 (China); Ye, X.C., E-mail: yexuchu@njtech.edu.cn [College of Materials Science and Engineering, Nanjing Tech University, Nanjing 210009 (China); State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University, Nanjing 210009 (China)

    2014-08-15

    Highlights: • The waste neutralization liquor was injected directly into the kiln system. • No obvious effect on the quality of cement clinker. • The disposing method was a zero-discharge process. • The waste liquor can be used as an alternative fuel to reduce the coal consumption. - Abstract: The waste neutralization liquor generated during the glyphosate production using glycine-dimethylphosphit process is a severe pollution problem due to its high salinity and organic components. The cement rotary kiln was proposed as a zero discharge strategy of disposal. In this work, the waste liquor was calcinated and the mineralogical phases of residue were characterized by scanning electron microscope (SEM) and X-ray diffraction (XRD). The mineralogical phases and the strength of cement clinker were characterized to evaluate the influence to the products. The burnability of cement raw meal added with waste liquor and the calorific value of waste liquor were tested to evaluate the influence to the thermal state of the kiln system. The results showed that after the addition of this liquor, the differences of the main phases and the strength of cement clinker were negligible, the burnability of raw meal was improved; and the calorific value of this liquor was 6140 J/g, which made it could be considered as an alternative fuel during the actual production.

  19. Feasibility of disposing waste glyphosate neutralization liquor with cement rotary kiln

    International Nuclear Information System (INIS)

    Bai, Y.; Bao, Y.B.; Cai, X.L.; Chen, C.H.; Ye, X.C.

    2014-01-01

    Highlights: • The waste neutralization liquor was injected directly into the kiln system. • No obvious effect on the quality of cement clinker. • The disposing method was a zero-discharge process. • The waste liquor can be used as an alternative fuel to reduce the coal consumption. - Abstract: The waste neutralization liquor generated during the glyphosate production using glycine-dimethylphosphit process is a severe pollution problem due to its high salinity and organic components. The cement rotary kiln was proposed as a zero discharge strategy of disposal. In this work, the waste liquor was calcinated and the mineralogical phases of residue were characterized by scanning electron microscope (SEM) and X-ray diffraction (XRD). The mineralogical phases and the strength of cement clinker were characterized to evaluate the influence to the products. The burnability of cement raw meal added with waste liquor and the calorific value of waste liquor were tested to evaluate the influence to the thermal state of the kiln system. The results showed that after the addition of this liquor, the differences of the main phases and the strength of cement clinker were negligible, the burnability of raw meal was improved; and the calorific value of this liquor was 6140 J/g, which made it could be considered as an alternative fuel during the actual production

  20. 19 CFR 11.6 - Distilled spirits, wines, and malt liquors in bulk.

    Science.gov (United States)

    2010-04-01

    ... 19 Customs Duties 1 2010-04-01 2010-04-01 false Distilled spirits, wines, and malt liquors in bulk...; DEPARTMENT OF THE TREASURY PACKING AND STAMPING; MARKING Packing and Stamping § 11.6 Distilled spirits, wines... conveying imported distilled spirits, wines, and malt liquors, in accordance with 19 U.S.C. 467. (b) Marks...

  1. 77 FR 74025 - Federated Indians of Graton Rancheria-Liquor Control Statute

    Science.gov (United States)

    2012-12-12

    ... Statute reads as follows: Chapter One--Introduction Section: 1.1 Authority. This Statute is enacted... viability of tribal enterprises. 1.3 Short Title. This Statute shall be known and cited as the ``Liquor..., currently prohibits the introduction of liquor into Indian country, except in accordance with State law and...

  2. 76 FR 77549 - Colorado River Indian Tribes-Amendment to Health & Safety Code, Article 2. Liquor

    Science.gov (United States)

    2011-12-13

    ... Health & Safety Code, Article 2. Liquor AGENCY: Bureau of Indian Affairs, Interior. ACTION: Notice. SUMMARY: This notice publishes the amendment to the Colorado River Tribal Health and Safety Code, Article... Code, Article 2, Liquor by Ordinance No. 10-03 on December 13, 2010. This notice is published in...

  3. Discrimination of Chinese Sauce liquor using FT-IR and two-dimensional correlation IR spectroscopy

    Science.gov (United States)

    Sun, Su-Qin; Li, Chang-Wen; Wei, Ji-Ping; Zhou, Qun; Noda, Isao

    2006-11-01

    We applied the three-step IR macro-fingerprint identification method to obtain the IR characteristic fingerprints of so-called Chinese Sauce liquor (Moutai liquor and Kinsly liquor) and a counterfeit Moutai. These fingerprints can be used for the identification and discrimination of similar liquor products. The comparison of their conventional IR spectra, as the first step of identification, shows that the primary difference in Sauce liquor is the intensity of characteristic peaks at 1592 and 1225 cm -1. The comparison of the second derivative IR spectra, as the second step of identification, shows that the characteristic absorption in 1400-1800 cm -1 is substantially different. The comparison of 2D-IR correlation spectra, as the third and final step of identification, can discriminate the liquors from another direction. Furthermore, the method was successfully applied to the discrimination of a counterfeit Moutai from the genuine Sauce liquor. The success of the three-step IR macro-fingerprint identification to provide a rapid and effective method for the identification of Chinese liquor suggests the potential extension of this technique to the identification and discrimination of other wine and spirits, as well.

  4. A process for producing lignin and volatile compounds from hydrolysis liquor.

    Science.gov (United States)

    Khazraie, Tooran; Zhang, Yiqian; Tarasov, Dmitry; Gao, Weijue; Price, Jacquelyn; DeMartini, Nikolai; Hupa, Leena; Fatehi, Pedram

    2017-01-01

    Hot water hydrolysis process is commercially applied for treating wood chips prior to pulping or wood pellet production, while it produces hydrolysis liquor as a by-product. Since the hydrolysis liquor is dilute, the production of value-added materials from it would be challenging. In this study, acidification was proposed as a viable method to extract (1) furfural and acetic acid from hot water hydrolysis liquor and (2) lignin compounds from the liquor. The thermal properties of the precipitates made from the acidification of hydrolysis liquor confirmed the volatile characteristics of precipitates. Membrane dialysis was effective in removing inorganic salts associated with lignin compounds. The purified lignin compounds had a glass transition temperature (Tg) of 180-190 °C, and were thermally stable. The results confirmed that lignin compounds present in hot water hydrolysis liquor had different characteristics. The acidification of hydrolysis liquor primarily removed the volatile compounds from hydrolysis liquor. Based on these results, a process for producing purified lignin and precipitates of volatile compounds was proposed.

  5. Studies on the antimicrobial effect of corn steep liquor on some ...

    African Journals Online (AJOL)

    ROFIAT

    2014-01-08

    Jan 8, 2014 ... The antimicrobial effect of Corn Steep Liquor (CSL) was investigated over a five day period. The pH and titrable acidity of the liquor were determined, while the antimicrobial effect on some diarrhoea causing organisms such as Escherichia coli, Salmonella enteriditis, Staphylococcus aureus and Vibrio.

  6. Study on the changes of physical and chemical properties for the black liquor of straw plug induced by radiation

    International Nuclear Information System (INIS)

    Zhu Guanghua; Lan Liqiao

    1994-12-01

    The black liquor of straw plug was treated by electron beam or γ-ray radiation. The relationship between the viscosity of the black liquor of straw plug and the radiation beam type, the irradiated dose, the temperature of the black liquor at irradiation time and the concentration of the solid state matter in the black liquor was investigated. The result shows that the radiation treatment makes the organic big molecular of the black liquor decomposed, the environmental loading factor of the black liquor reduced; after an irradiation of 20 kGy, the viscosity of the black liquor of straw plug with 30% solid state matter is reduced by 50%, the property of vaporization is obviously improved, but the calorific value of the black liquor has almost no change

  7. Kinetics and compensation effects during steam gasification of Fujian anthracite using viscose liquor as catalyst

    Energy Technology Data Exchange (ETDEWEB)

    Lin Ju; Zhang Ji-yu; Zhong Xue-qing [Fuzhou University, Fuzhou (China). Institute of Chemical Engineering and Technology

    2009-08-15

    Catalytic steam gasification kinetics of Fujian Youxi anthracite using viscose liquor as catalyst was investigated in an isothermal thermo-gravimetric analyzer under ambient pressure. Coal conversions versus reaction time with different viscose liquor concentrations (0-12% NaOH) were measured at the temperature range from 850 to 950{sup o}C. The research shows that the viscose liquor can greatly improve the gasification rate and carbon conversion. The Loading Saturation Level (LSL) of the viscose liquor within the experimental conditions was also determined. The catalytic steam gasification reaction can be well fitted by a shrinking-core model (SCM) and the reaction rate constants are obtained. The kinetic analysis indicates that the catalytic gasification exhibits a prominent compensation effect between the activation energy and the pre-exponential factor. The kinetic equation including the compensation effects for the catalytic steam gasification of Fujian Youxi anthracite using viscose liquor as catalyst is presented. 23 refs., 7 figs., 3 tabs.

  8. Effects of ancestral populations on entrepreneurial founding and failure: private liquor stores in Alberta, 1994--2003

    OpenAIRE

    Glen Dowell; Robert J. David

    2011-01-01

    Until 1993, all liquor stores in the Canadian province of Alberta were government owned and run. In the fall of 1993, the provincial government exited liquor retailing, all government stores were shut down, and entrepreneurs were allowed to open private liquor stores. In this article, we take advantage of this abrupt regulatory change in the Alberta liquor-retailing industry to address two related issues that have received little empirical attention. First, we investigate how an ancestral pop...

  9. Oxy-Combustion Boiler Material Development

    Energy Technology Data Exchange (ETDEWEB)

    Gagliano, Michael; Seltzer, Andrew; Agarwal, Hans; Robertson, Archie; Wang, Lun

    2012-01-31

    Under U.S. Department of Energy Cooperative Agreement No. DE-NT0005262 Foster Wheeler North America Corp conducted a laboratory test program to determine the effect of oxy-combustion on boiler tube corrosion. In this program, CFD modeling was used to predict the gas compositions that will exist throughout and along the walls of air-fired and oxy-fired boilers operating with low to high sulfur coals. Test coupons of boiler tube materials were coated with deposits representative of those coals and exposed to the CFD predicted flue gases for up to 1000 hours. The tests were conducted in electric tube furnaces using oxy-combustion and air-fired flue gases synthesized from pressurized cylinders. Following exposure, the test coupons were evaluated to determine the total metal wastage experienced under air and oxy-combustions conditions and materials recommendations were made. Similar to air-fired operation, oxy-combustion corrosion rates were found to vary with the boiler material, test temperature, deposit composition, and gas composition. Despite this, comparison of air-fired and oxy-fired corrosion rates showed that oxy-firing rates were, for the most part, similar to, if not lower than those of air-firing; this finding applied to the seven furnace waterwall materials (wrought and weld overlay) and the ten superheater/reheater materials (wrought and weld overlay) that were tested. The results of the laboratory oxy-combustion tests, which are based on a maximum bulk flue gas SO2 level of 3200 ppmv (wet) / 4050 ppmv (dry), suggest that, from a corrosion standpoint, the materials used in conventional subcritical and supercritical, air-fired boilers should also be suitable for oxy-combustion retrofits. Although the laboratory test results are encouraging, they are only the first step of a material evaluation process and it is recommended that follow-on corrosion tests be conducted in coal-fired boilers operating under oxy-combustion to provide longer term (one to two year

  10. Oxy-Combustion Boiler Material Development

    Energy Technology Data Exchange (ETDEWEB)

    Michael Gagliano; Andrew Seltzer; Hans Agarwal; Archie Robertson; Lun Wang

    2012-01-31

    Under U.S. Department of Energy Cooperative Agreement No. DE-NT0005262 Foster Wheeler North America Corp conducted a laboratory test program to determine the effect of oxy-combustion on boiler tube corrosion. In this program, CFD modeling was used to predict the gas compositions that will exist throughout and along the walls of air-fired and oxy-fired boilers operating with low to high sulfur coals. Test coupons of boiler tube materials were coated with deposits representative of those coals and exposed to the CFD predicted flue gases for up to 1000 hours. The tests were conducted in electric tube furnaces using oxy-combustion and air-fired flue gases synthesized from pressurized cylinders. Following exposure, the test coupons were evaluated to determine the total metal wastage experienced under air and oxy-combustions conditions and materials recommendations were made. Similar to air-fired operation, oxy-combustion corrosion rates were found to vary with the boiler material, test temperature, deposit composition, and gas composition. Despite this, comparison of air-fired and oxy-fired corrosion rates showed that oxy-firing rates were, for the most part, similar to, if not lower than those of air-firing; this finding applied to the seven furnace waterwall materials (wrought and weld overlay) and the ten superheater/reheater materials (wrought and weld overlay) that were tested. The results of the laboratory oxy-combustion tests, which are based on a maximum bulk flue gas SO{sub 2} level of 3200 ppmv (wet) / 4050 ppmv (dry), suggest that, from a corrosion standpoint, the materials used in conventional subcritical and supercritical, air-fired boilers should also be suitable for oxy-combustion retrofits. Although the laboratory test results are encouraging, they are only the first step of a material evaluation process and it is recommended that follow-on corrosion tests be conducted in coal-fired boilers operating under oxy-combustion to provide longer term (one to

  11. Fractionation and characterization of saccharides and lignin components in wood prehydrolysis liquor from dissolving pulp production.

    Science.gov (United States)

    Wang, Zhaojiang; Wang, Xiaojun; Jiang, Jungang; Fu, Yingjuan; Qin, Menghua

    2015-08-01

    Saccharides and lignin components in prehydrolysis liquor (PHL) from kraft-based dissolving pulp production was characterized after being fractionated using membrane filtration. The results showed that the membrane filtration provided a method for organics fractionation with considerable recovery rate, but exhibited some disadvantages. Besides the limited ability in purifying oligosaccharides (OS) due to the overlaps of molecular weight distribution with lignin components, the membrane filtration could not improve the homogeneity of OS as indicated by the analysis of chemical compositions and the degree of polymerization (DP), which may be ascribed to the linear conformation of OS. The characterization of lignin components indicated a great potential for polymer industry because of the remarkable content of phenolic hydroxyl groups (PhOH), especially for low molecular weight (LMW) fraction. It was concluded the organics in PHL provided streams of value-added chemicals. However, the practical significance thereof can be realized and maximized only when they are successfully and completely fractionated. Copyright © 2015 Elsevier Ltd. All rights reserved.

  12. 27 CFR 31.52 - Wholesale dealers in liquors consummating sales of wines or beer at premises of other dealers.

    Science.gov (United States)

    2010-04-01

    ... liquors consummating sales of wines or beer at premises of other dealers. 31.52 Section 31.52 Alcohol... § 31.52 Wholesale dealers in liquors consummating sales of wines or beer at premises of other dealers... wholesale dealer on account of those sales. (b) Sales of beer. Any wholesale dealer in liquors who has...

  13. Maximising safety in the boiler house.

    Science.gov (United States)

    Derry, Carr

    2013-03-01

    Last month's HEJ featured an article, the second in our new series of guidance pieces aimed principally at Technician-level engineers, highlighting some of the key steps that boiler operators can take to maximise system performance and efficiency, and thus reduce running both costs and carbon footprint. In the third such article, Derry Carr, C.Env, I.Eng, BSc (Hons), M.I.Plant.E., M.S.O.E., technical manager & group gas manager at Dalkia, who is vice-chairman of the Combustion Engineering Association, examines the key regulatory and safety obligations for hospital energy managers and boiler technicians, a number of which have seen changes in recent years with revision to guidance and other documentation.

  14. Control Properties of Bottom Fired Marine Boilers

    DEFF Research Database (Denmark)

    Solberg, Brian; Andersen, Palle; Karstensen, Claus M. S.

    2005-01-01

    This paper focuses on model analysis of a dynamic model of a bottom fired one-pass smoke tube boiler. Linearised versions of the model are analysed to determine how gain, time constants and right half plane zeros (caused by the shrink-and-swell phenomenon) depend on the steam flow load. Furthermore...... the interactions in the system are inspected to analyse potential benefit from using a multivariable control strategy in favour of the current strategy based on single loop theory. An analysis of the nonlinear model is carried out to further determine the nonlinear characteristics of the boiler system...... and to verify whether nonlinear control is needed. Finally a controller based on single loop theory is used to analyse if input constraints become active when rejecting transient behaviour from the disturbance steam flow. The model analysis shows large variations in system gains at steady state as function...

  15. Biomass Cofiring in Coal-Fired Boilers

    Energy Technology Data Exchange (ETDEWEB)

    2004-06-01

    Cofiring biomass-for example, forestry residues such as wood chips-with coal in existing boilers is one of the easiest biomass technologies to implement in a federal facility. The current practice is to substitute biomass for up to 20% of the coal in the boiler. Cofiring has many benefits: it helps to reduce fuel costs as well as the use of landfills, and it curbs emissions of sulfur oxide, nitrogen oxide, and the greenhouse gases associated with burning fossil fuels. This Federal Technology Alert was prepared by the Department of Energy's Federal Energy Management Program to give federal facility managers the information they need to decide whether they should pursue biomass cofiring at their facilities.

  16. Fermentation assisted byproduct recovery in the palm oil industry

    Energy Technology Data Exchange (ETDEWEB)

    Stanton, W.R.

    1983-05-01

    The production of palm oil from Elaeis guineensis is a leading natural product industry in Malaysia, giving rise to a number of residues, including a rich, fruity liquor from the pulp. The liquor, of which 7-10 million tonnes a year are currently produced, has some 6% organic solids, including 0.7-1.0% or more of oil which physical processing has failed to extract. Present anaerobic digestion processes exploit only the energy and fertiliser value. Methods are described in this paper for thermophilic, microbially assisted digestion for component separation and recovery, exploiting the widely used techniques for fruit juice extraction involving enzymic breakdown of starch, pectin and other cell components. Anaerobiosis and acidogenesis help protect and release residual oil, concomitantly preserving the solids against rancidity and spoilage by ensilage. The separated wet solids are nutritive (17% protein on dry matter), biologically safe and attractive to livestock. Downstream use of the liquor is aided by the thermophilic digestion. (Refs. 33).

  17. The kinetics of the gasification of black liquor. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Richards, Tobias; Theliander, Hans; Wintoko, Joko [Chalmers Univ. of Technology, Goeteborg (Sweden). Forest Products and Chemical Engineering

    2004-05-01

    Within the project, a special equipment has been manufactured in order to perform gasification experiments on single black liquor droplets. There are possibilities with the equipment to dynamically measure the weight of the droplet as well as its center temperature. Furthermore, some key gases (CO{sub 2}, CO, H{sub 2}S, CH{sub 4} and SO{sub 2}) are continuously measured. It is also possible to follow the gasification stages visually through a glass window. Parallel with this, a mathematical model has been developed to describe the gasification. It consists of both reaction kinetics and transport phenomenon. As a first step, the temperature profile was modeled and after that the model has been expanded to describe the swelling.

  18. Fixation Of Mo In Uranium Leach Liquor By Activated Carbon

    International Nuclear Information System (INIS)

    Mainar, S.; Guswita, A.; Erni, R.A.; Susilaningtyas

    1996-01-01

    The use of activated carbon for Mo fixation by bulk system is reported. Several factors influencing the fixation process were examined, including contact time, carbon particle size, carbon porosity and the effect of other elements present in Mo containing solutions. Experimental data showed that an adsorption equilibrium of Mo on of activated carbon and 0,85 to 1,18 mm of carbon particle size under forced-convection mass transfer in 100 ml solution that contains + 0,56 m mol of Mo and +. 0,25 m mol Of U was reached after 6 hours period. Under those conditions, about 0,50 m mol of Mo and 0,026 m mol of U were adsorbed into carbon. High concentration of rare earth elements decreased Mo adsorption, hence, the use of activated carbon was not effective to separate Mo from the digestion liquor of Rirang are where Mo was adsorbed, into the carbon + 34,5 %

  19. Electrowinning of lead powder from chloride leach liquor

    Energy Technology Data Exchange (ETDEWEB)

    Owais, Ashour [Suez Canal Univ., Suez (Egypt). Metallurgical and Materials Engineering Dept.

    2012-11-15

    Electrowinning of lead powder from chloride leach liquor obtained from secondary lead slag leached in hydrochloric acid is the main aim of this work. The resulted lead chloride solution (leachate) containing 2.2 wt.-% Pb and 1.24 wt.-% HCl was electrowon in an electrolytic cell containing one graphite plate as inert anode and two lead sheets as starting permanent cathodes. Different electrolysis parameters such as current density, electrolyte temperature and electrolyte stirring rate were studied. As indicated by SEM, EDX and XRD analyses, fine and pure (100 % Pb) powders with a dispersed and needle-like shape were formed with cathodic current efficiency up to 67.9 % and electrical energy demand ranges from 0.809 to 4.998 kWh/kg Pb with productivity up to 2.63 g/Ah. (orig.)

  20. Anaerobic biodegradation of spent sulphite liquor in a UASB reactor

    DEFF Research Database (Denmark)

    Jantsch, T.G.; Angelidaki, Irini; Schmidt, Jens Ejbye

    2002-01-01

    Anaerobic biodegradation of fermented spent sulphite liquor, SSL, which is produced during the manufacture of sulphite pulp, was investigated. SSL contains a high concentration of lignin products in addition to hemicellulose and has a very high COD load (173 g COD l1). Batch experiments...... ðl dÞ1 and hydraulic retention time from 3.7 to 1.5 days. The biogas productivity was 3 l ðlreactor dÞ1, with a yield of 0.05 l gas ðg VSÞ1. These results suggest that anaerobic digestion in UASB reactors may provide a new alternative for the treatment of SSL to other treatment strategies...... such as incineration. Although the total COD reduction achieved is limited, bioenergy is produced and readily biodegradable matter is removed causing less load on post-treatment installations. 2002 Elsevier Science Ltd. All rights reserved....

  1. Stationary Engineers Apprenticeship. Related Training Modules. 12.1-12.9. Boilers.

    Science.gov (United States)

    Lane Community Coll., Eugene, OR.

    This learning module, one in a series of 20 related training modules for apprentice stationary engineers, deals with boilers. Addressed in the individual instructional packages included in the module are the following topics: firetube and watertube boilers; boiler construction; procedures for operating and cleaning boilers; and boiler fittings,…

  2. 46 CFR 52.25-7 - Electric boilers (modifies PEB-1 through PEB-19).

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 2 2010-10-01 2010-10-01 false Electric boilers (modifies PEB-1 through PEB-19). 52.25... ENGINEERING POWER BOILERS Other Boiler Types § 52.25-7 Electric boilers (modifies PEB-1 through PEB-19). Electric boilers required to comply with this part must meet the applicable provisions in this part and the...

  3. Novel precipitation technique for uranium recovery from carbonate leach solutions

    International Nuclear Information System (INIS)

    Sujoy Biswas; Rupawate, V.H.; Hareendran, K.N.; Roy, S.B.; Chakravartty, J.K.

    2015-01-01

    The recovery of uranium from carbonate ore leach solution was studied using novel precipitation method. The uranium from leach liquor was recovered as magnesium diuranate with NaOH in presence of trace amount of Mg 2+ . Effects of various parameters such as addition of H 2 SO 4 , MgO, MgSO 4 as well as NaOH were investigated for maximum uranium recovery. Overall uranium recovery of the process was 97 % with improved particle size (∼57 µm). Based on the experimental findings, a process flow-sheet was developed for uranium recovery from carbonate ore leach solution with a uranium concentration of <1 g/L. (author)

  4. Circulating fluidized bed boilers design and operations

    CERN Document Server

    Basu, Prabir

    1991-01-01

    This book provides practicing engineers and students with insight into the design and operation of circulating fluidized bed (CFB) boilers. Through a combination of theoretical concepts and practical experience, this book gives the reader a basic understanding of the many aspects of this subject.Important environmental considerations, including solid waste disposal and predicted emissions, are addressed individually in separate chapters. This book places an emphasis on combustion, hydrodynamics, heat transfer, and material issues, and illustrates these concepts with numerous examples of pres

  5. Chromate dermatitis from a boiler lining.

    Science.gov (United States)

    Rycroft, R J; Calnan, C D

    1977-08-01

    Chromate dermatitis is described in a mechanical fitter working inside boiler combustion chambers. A source of hexavalent chromate is traced to the action of the heat and alkaline fuel ash on trivalent chrome ore in parts of the refractory lining. Removal of the patient from this contact has resulted in almost complete clearing of his dermatitis, without any relapse, during a 9-month follow-up period.

  6. Husk energy for boilers and furnaces

    Energy Technology Data Exchange (ETDEWEB)

    Deven, M.

    1985-10-01

    In view of the technical feasibility and economic viability, industries located in rice, coconut, and cotton growing areas, can easily switch over from oil/coal fired furnace/boilers to husk fired ones and thereby effect fuel economy. The banks and financial institutions will readily agree to provide finance as per directions of the governments and in some cases they also offer subsidy for development and utilization of energy saving devices.

  7. Particulate emission abatement for Krakow boiler houses

    Energy Technology Data Exchange (ETDEWEB)

    Wysk, R.

    1995-12-31

    Among the many strategies for improving air quality in Krakow, one possible method is to adapt new and improved emission control technology. This project focuses on such a strategy. In order to reduce dust emissions from coal-fueled boilers, a new device called a Core Separator has been introduced in several boiler house applications. This advanced technology has been successfully demonstrated in Poland and several commercial units are now in operation. Particulate emissions from the Core Separator are typically 3 to 5 times lower than those from the best cyclone collectors. It can easily meet the new standard for dust emissions which will be in effect in Poland after 1997. The Core Separator is a completely inertial collector and is based on a unique recirculation method. It can effectively remove dust particles below 10 microns in diameter, the so-called PM-10 emissions. Its performance approaches that of fabric filters, but without the attendant cost and maintenance. It is well-suited to the industrial size boilers located in Krakow. Core Separators are now being marketed and sold by EcoInstal, one of the leading environmental firms in Poland, through a cooperative agreement with LSR Technologies.

  8. Boiler systems for nuclear powered reactors

    International Nuclear Information System (INIS)

    Cook, R.K.; George, B.V.

    1979-01-01

    A power generating plant which comprises a heat source, at least one main steam turbine and at least one main boiler heated by heat from the heat source and providing the steam to drive the turbine, comprises additionally at least one further steam turbine, smaller than the main turbine, and at least one further boiler, of lower capacity than the main boiler, and heated from the same heat source and providing steam for the further turbine. Particularly advantageous in nuclear power stations, where the heat source is a nuclear reactor, the invention enables peak loads, above the normal continuous rating of the main generators driven by the main turbines, to be met by the further turbine(s) and one or more further generators driven thereby. This enables the main turbines to be freed from the thermal stresses of rapid load changes, which stresses are more easily accommodated by the smaller and thus more tolerant further turbine(s). Thus auxiliary diesel-driven or other independent power plant may be made partly or wholly unnecessary. Further, low-load running which would be inefficient if achieved by means of the main turbine(s), can be more efficiently effected by shutting them down and using the smaller further turbine(s) instead. These latter may also be used to provide independent power for servicing the generating plant during normal operation or during emergency or other shutdown, and in this latter case may also serve as a heat sink for the shutdown reactor

  9. BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS

    Energy Technology Data Exchange (ETDEWEB)

    R. Viswanathan; K. Coleman; R.W. Swindeman; J. Sarver; J. Blough; W. Mohn; M. Borden; S. Goodstine; I. Perrin

    2003-10-20

    The principal objective of this project is to develop materials technology for use in ultrasupercritical (USC) plant boilers capable of operating with 760 C (1400 F), 35 MPa (5000 psi) steam. This project has established a government/industry consortium to undertake a five-year effort to evaluate and develop of advanced materials that allow the use of advanced steam cycles in coal-based power plants. These advanced cycles, with steam temperatures up to 760 C, will increase the efficiency of coal-fired boilers from an average of 35% efficiency (current domestic fleet) to 47% (HHV). This efficiency increase will enable coal-fired power plants to generate electricity at competitive rates (irrespective of fuel costs) while reducing CO{sub 2} and other fuel-related emissions by as much as 29%. Success in achieving these objectives will support a number of broader goals. First, from a national prospective, the program will identify advanced materials that will make it possible to maintain a cost-competitive, environmentally acceptable coal-based electric generation option. High sulfur coals will specifically benefit in this respect by having these advanced materials evaluated in high-sulfur coal firing conditions and from the significant reductions in waste generation inherent in the increased operational efficiency. Second, from a national prospective, the results of this program will enable domestic boiler manufacturers to successfully compete in world markets for building high-efficiency coal-fired power plants.

  10. Engineering Study for a Full Scale Demonstration of Steam Reforming Black Liquor Gasification at Georgia-Pacific's Mill in Big Island, Virginia; FINAL

    International Nuclear Information System (INIS)

    Robert De Carrera; Mike Ohl

    2002-01-01

    Georgia-Pacific Corporation performed an engineering study to determine the feasibility of installing a full-scale demonstration project of steam reforming black liquor chemical recovery at Georgia-Pacific's mill in Big Island, Virginia. The technology considered was the Pulse Enhanced Steam Reforming technology that was developed and patented by Manufacturing and Technology Conversion, International (MTCI) and is currently licensed to StoneChem, Inc., for use in North America. Pilot studies of steam reforming have been carried out on a 25-ton per day reformer at Inland Container's Ontario, California mill and on a 50-ton per day unit at Weyerhaeuser's New Bern, North Carolina mill

  11. Field Test of Boiler Primary Loop Temperature Controller

    Energy Technology Data Exchange (ETDEWEB)

    Glanville, P. [Partnership for Advanced Residential Retrofit, Des Plaines, IL (United States); Rowley, P. [Partnership for Advanced Residential Retrofit, Des Plaines, IL (United States); Schroeder, D. [Partnership for Advanced Residential Retrofit, Des Plaines, IL (United States); Brand, L. [Partnership for Advanced Residential Retrofit, Des Plaines, IL (United States)

    2014-09-01

    Beyond these initial system efficiency upgrades are an emerging class of Advanced Load Monitoring (ALM) aftermarket controllers that dynamically respond to the boiler load, with claims of 10% to 30% of fuel savings over a heating season. For hydronic boilers specifically, these devices perform load monitoring, with continuous measurement of supply and, in some cases, return water temperatures. Energy savings from these ALM controllers are derived from dynamic management of the boiler differential, where a microprocessor with memory of past boiler cycles prevents the boiler from firing for a period of time, to limit cycling losses and inefficient operation during perceived low load conditions. These differ from OTR controllers, which vary boiler setpoint temperatures with ambient conditions while maintaining a fixed differential.

  12. Modelling, simulating and optimizing boiler heating surfaces and evaporator circuits

    DEFF Research Database (Denmark)

    Sørensen, K.; Condra, T.; Houbak, Niels

    2003-01-01

    A model for optimizing the dynamic performance of boiler have been developed. Design variables related to the size of the boiler and its dynamic performance have been defined. The object function to be optimized takes the weight of the boiler and its dynamic capability into account. As constraints...... for the optimization a dynamic model for the boiler is applied. Furthermore a function for the value of the dynamic performance is included in the model. The dynamic models for simulating boiler performance consists of a model for the flue gas side, a model for the evaporator circuit and a model for the drum....... The dynamic model has been developed for the purpose of determining boiler material temperatures and heat transfer from the flue gas side to the water-/steam side in order to simulate the circulation in the evaporator circuit and hereby the water level fluctuations in the drum. The dynamic model has been...

  13. Behavioral study solar boilers 1994. Summary. Part 2 (households)

    International Nuclear Information System (INIS)

    Visser, J.M.

    1995-04-01

    The aim of the Dutch national solar boiler campaign of NOVEM and Holland Solar is to realize the installation of 300,000 solar boilers in the Netherlands in the year 2010. In 1995 10,000 boilers were installed. More knowledge of the decision making process and the backgrounds and motives of (potential) buyers is required. From September 1994 to March 1995 a survey has been carried out of the decision making processes in households and housing corporations. The most important results, conclusions and recommendations of the survey are summarized in this report. The parameters that can influence the decision whether to purchase a solar boiler or not are knowledge about the solar boiler, the attitude towards the solar boiler and towards the use of energy and the environment, risk perception, social aspects, information retrieval behavior, constraints, and socio-economic aspects. 44 tabs

  14. NOx PREDICTION FOR FBC BOILERS USING EMPIRICAL MODELS

    Directory of Open Access Journals (Sweden)

    Jiří Štefanica

    2014-02-01

    Full Text Available Reliable prediction of NOx emissions can provide useful information for boiler design and fuel selection. Recently used kinetic prediction models for FBC boilers are overly complex and require large computing capacity. Even so, there are many uncertainties in the case of FBC boilers. An empirical modeling approach for NOx prediction has been used exclusively for PCC boilers. No reference is available for modifying this method for FBC conditions. This paper presents possible advantages of empirical modeling based prediction of NOx emissions for FBC boilers, together with a discussion of its limitations. Empirical models are reviewed, and are applied to operation data from FBC boilers used for combusting Czech lignite coal or coal-biomass mixtures. Modifications to the model are proposed in accordance with theoretical knowledge and prediction accuracy.

  15. New microbial resource: microbial diversity, function and dynamics in Chinese liquor starter.

    Science.gov (United States)

    Huang, Yuhong; Yi, Zhuolin; Jin, Yanling; Zhao, Yonggui; He, Kaize; Liu, Dayu; Zhao, Dong; He, Hui; Luo, Huibo; Zhang, Wenxue; Fang, Yang; Zhao, Hai

    2017-11-06

    Traditional Chinese liquor (Baijiu) solid state fermentation technology has lasted for several thousand years. The microbial communities that enrich in liquor starter are important for fermentation. However, the microbial communities are still under-characterized. In this study, 454 pyrosequencing technology was applied to comprehensively analyze the microbial diversity, function and dynamics of two most-consumed liquor starters (Jiang- and Nong-flavor) during production. In total, 315 and 83 bacterial genera and 72 and 47 fungal genera were identified in Jiang- and Nong-flavor liquor starter, respectively. The relatively high diversity was observed when the temperature increased to 70 and 62 °C for Jiang- and Nong-flavor liquor starter, respectively. Some thermophilic fungi have already been isolated. Microbial communities that might contribute to ethanol fermentation, saccharification and flavor development were identified and shown to be core communities in correlation-based network analysis. The predictively functional profile of bacterial communities showed significant difference in energy, carbohydrate and amino acid metabolism and the degradation of aromatic compounds between the two kinds of liquor starters. Here we report these liquor starters as a new functionally microbial resource, which can be used for discovering thermophilic and aerobic enzymes and for food and feed preservation.

  16. Aroma characteristics of Moutai-flavour liquor produced with Bacillus licheniformis by solid-state fermentation.

    Science.gov (United States)

    Zhang, R; Wu, Q; Xu, Y

    2013-07-01

    The potential of Bacillus licheniformis as a starter culture for aroma concentration improvement in the fermentation of Chinese Moutai-flavour liquor was elucidated. The volatile compounds produced by B. licheniformis were identified by GC-MS, in which C4 compounds, pyrazines, volatile acids, aromatic and phenolic compounds were the main ingredients. The strains B. licheniformis (MT-6 and MT-15) produced more volatile compound concentrations, mainly C4 compounds, than the type strain of B. licheniformis (ATCC 14580) at the fermentation temperature of 55°C. Meanwhile, more volatile compound concentrations were produced by B. licheniformis in solid-state fermentation than in submerged state fermentation. Thus, the strains MT-6 and MT-15 were used as the Bacillus starter culture for investigating Moutai-flavour liquor production. The distilled liquor inoculated with Bacillus starter culture was significantly different from the liquor without inoculum. This was particularly evident in the fore-run part of the distilled sample which was inoculated with Bacillus starter culture, where volatile compounds greatly increased compared to the control. Furthermore, the distilled liquor with Bacillus starter culture showed improved results in sensory appraisals. These results indicated that B. licheniformis was one of the main species influencing the aroma characteristics of Moutai-flavour liquor. This is the first report of an investigation into the effect of Bacillus starter cultures on the flavour features of Moutai-flavour liquor, which verified that Bacillus licheniformis can enhance aroma concentration in Moutai-flavour liquor. Bacillus starter culture brought C4 compounds, pyrazines, volatile acids, aromatic and phenolic compounds to the liquor, which gave a better result in sensory appraisals. © 2013 The Society for Applied Microbiology.

  17. Separation and Recovery of Precious Metals from Leach Liquors of Spent Electronic Wastes by Solvent Extraction

    Energy Technology Data Exchange (ETDEWEB)

    Nguyen, Thi Hong; Wang, Lingyun; Lee, Man Seung [Mokpo National University, Mokpo (Korea, Republic of)

    2017-04-15

    Solvent extraction was employed to recover precious metals (Au (III), Pd (II) and Pt (IV)) from the leach solution of spent electronic wastes containing Cu (II), Cr (III) and Fe (III). First, pure Fe (III) and Au (III) were recovered by simultaneous extraction with Cyanex 923 followed by selective stripping with HCl and Na{sub 2}S{sub 2}O{sub 3}. Second, Pt (IV), Pd (II) and Cu (II) were extracted by Alamine 336 from the raffinate. After the removal of Cu (II) by stripping with weak HCl, Pd (II) and Pt (IV) were separately stripped by controlling the concentration of thiourea in the mixture with HCl. A process flow sheet for the separation of precious metals was proposed.

  18. Field Test of Boiler Primary Loop Temperature Controller

    Energy Technology Data Exchange (ETDEWEB)

    Glanville, P.; Rowley, P.; Schroeder, D.; Brand, L.

    2014-09-01

    Beyond these initial system efficiency upgrades are an emerging class of Advanced Load Monitoring (ALM) aftermarket controllers that dynamically respond to the boiler load, with claims of 10% to 30% of fuel savings over a heating season. For hydronic boilers specifically, these devices perform load monitoring, with continuous measurement of supply and in some cases return water temperatures. Energy savings from these ALM controllers are derived from dynamic management of the boiler differential, where a microprocessor with memory of past boiler cycles prevents the boiler from firing for a period of time, to limit cycling losses and inefficient operation during perceived low load conditions. These differ from OTR controllers, which vary boiler setpoint temperatures with ambient conditions while maintaining a fixed differential. PARR installed and monitored the performance of one type of ALM controller, the M2G from Greffen Systems, at multifamily sites in the city of Chicago and its suburb Cary, IL, both with existing OTR control. Results show that energy savings depend on the degree to which boilers are over-sized for their load, represented by cycling rates. Also savings vary over the heating season with cycling rates, with greater savings observed in shoulder months. Over the monitoring period, over-sized boilers at one site showed reductions in cycling and energy consumption in line with prior laboratory studies, while less over-sized boilers at another site showed muted savings.

  19. Between the boiler and buffer tank; Zwischen Kessel und Speicher

    Energy Technology Data Exchange (ETDEWEB)

    Ertmer, Katharina

    2013-08-06

    Some manufacturers offer new heating pump groups for return temperature raising for solid-fuel boilers. [German] Einige Hersteller bieten neue Heizungspumpengruppen zur Ruecklauftemperaturanhebung bei Festbrennstoffkesseln an.

  20. Simulation and testing of a new condensing boiler

    International Nuclear Information System (INIS)

    Rosa, L.; Tosato, R.

    1987-01-01

    The paper describes a new condensing boiler, characterized by the evacuation of flue-gases by natural draft. The best result is the consequent simplification of manufacturing, hook-up and operation of the boiler. Seasonal efficiency of the boiler, which operates with flue-gases conditioning to assure natural draft, rests about at same levels as for conventional condensing boilers. The authors emphasize the difficulty of simulate natural draft mechanism by mathematics because, in this case, flow of flue-gases and air at the draft diverter is strongly three-dimensional

  1. Use of sulfide-containing liquors for removing mercury from flue gases

    Science.gov (United States)

    Nolan, Paul S.; Downs, William; Bailey, Ralph T.; Vecci, Stanley J.

    2006-05-02

    A method and apparatus for reducing and removing mercury in industrial gases, such as a flue gas, produced by the combustion of fossil fuels, such as coal, adds sulfide ions to the flue gas as it passes through a scrubber. Ideally, the source of these sulfide ions may include at least one of: sulfidic waste water, kraft caustic liquor, kraft carbonate liquor, potassium sulfide, sodium sulfide, and thioacetamide. The sulfide ion source is introduced into the scrubbing liquor as an aqueous sulfide species. The scrubber may be either a wet or dry scrubber for flue gas desulfurization systems.

  2. Method for improving separation of carbohydrates from wood pulping and wood or biomass hydrolysis liquors

    Science.gov (United States)

    Griffith, William Louis; Compere, Alicia Lucille; Leitten, Jr., Carl Frederick

    2010-04-20

    A method for separating carbohydrates from pulping liquors includes the steps of providing a wood pulping or wood or biomass hydrolysis pulping liquor having lignin therein, and mixing the liquor with an acid or a gas which forms an acid upon contact with water to initiate precipitation of carbohydrate to begin formation of a precipitate. During precipitation, at least one long chain carboxylated carbohydrate and at least one cationic polymer, such as a polyamine or polyimine are added, wherein the precipitate aggregates into larger precipitate structures. Carbohydrate gel precipitates are then selectively removed from the larger precipitate structures. The method process yields both a carbohydrate precipitate and a high purity lignin.

  3. Investigation of Fuel Chemistry and Bed Performance in a Fluidized Bed Black Liquor Steam Reformer

    Energy Technology Data Exchange (ETDEWEB)

    Kevin Whitty

    2007-06-30

    University of Utah's project entitled 'Investigation of Fuel Chemistry and Bed Performance in a Fluidized Bed Black Liquor Steam Reformer' (DOE Cooperative Agreement DE-FC26-02NT41490) was developed in response to a solicitation released by the U.S. Department of Energy in December 2001, requesting proposals for projects targeted towards black liquor/biomass gasification technology support research and development. Specifically, the solicitation was seeking projects that would provide technical support for Department of Energy supported black liquor and biomass gasification demonstration projects under development at the time.

  4. Rapid determination of methanol in black liquors by full evaporation headspace gas chromatography.

    Science.gov (United States)

    Li, Hailong; Zhan, Huaiyu; Fu, Shiyu; Liu, Mengru; Chai, Xin-Sheng

    2007-12-14

    This paper reported a full evaporation headspace gas chromatographic (GC) technique for determination of methanol content in black liquors (pulping spent liquor). In this method, a very small volume (10-20 microL) of liquor sample is introduced into a headspace sample vial (20 mL) and heated up to a temperature of 105 degrees C. A near-complete mass transfer of methanol from the liquid phase to vapor phase (headspace), i.e., a full evaporation, can be achieved within 3 min. The methanol in the headspace of the vial is then measured by GC. The present method is simple, rapid and accurate.

  5. Uranium recovery from mine water

    International Nuclear Information System (INIS)

    Sarkar, K.M.

    1984-01-01

    In many plant trials it has been proven that very small amounts (10 to 20 ppm) of uranium dissolved in mine water can be effectively recovered by the use of ion exchange resins and this uranium recovery has many advantages. In this paper an economic analysis at different levels of uranium contamination and at different market prices of uranium are described. For this study an operating mine-mill complex with a sulphuric acid leach circuit, followed by solvent extraction (SX) process, is considered, where contaminated mine water is available in excess of process requirements. It is further assumed that the sulphuric acid eluant containing uranium would be mixed with the mill pregnant liquor stream that proceeds to the SX plant for final uranium recovery

  6. Increase of energy efficiency in proportional adjusting of flow rate in the boiler circuit

    OpenAIRE

    Artamonov Pavel A.; Kurilenko Nikolai I.; Mamontov Gennady Ya.

    2017-01-01

    The article presents the results of theoretical studies in the field of the boiler circuit operating modes for the boiler rooms operating by the independent heat supply scheme. The 3D model of a boiler circuit for a boiler room with 3 MW rated output was developed, based on which there was made an estimation of the boiler pump performance indicators. There is proposed a method for reducing energy costs for the operation of the pumping equipment of the boiler circuit.

  7. WITHDRAWN: Amnioinfusion for meconium-stained liquor in labour.

    Science.gov (United States)

    Hofmeyr, G Justus

    2009-01-21

    Amnioinfusion aims to prevent or relieve umbilical cord compression during labour by infusing a solution into the uterine cavity. It is also thought to dilute meconium when present in the amniotic fluid and so reduce the risk of meconium aspiration. However, it may be that the mechanism of effect is that it corrects oligohydramnios (reduced amniotic fluid), for which thick meconium staining is a marker. The objective of this review was to assess the effects of amnioinfusion for meconium-stained liquor on perinatal outcome. The Cochrane Pregnancy and Childbirth Group trials register (October 2001) and the Cochrane Controlled Trials Register (Issue 3, 2001) were searched. Randomised trials comparing amnioinfusion with no amnioinfusion for women in labour with moderate or thick meconium-staining of the amniotic fluid. Eligibility and trial quality were assessed by one reviewer. Twelve studies, most involving small numbers of participants, were included. Under standard perinatal surveillance, amnioinfusion was associated with a reduction in the following: heavy meconium staining of the liquor (relative risk 0.03, 95% confidence interval 0.01 to 0.15); variable fetal heart rate deceleration (relative risk 0.65, 95% confidence interval 0.49 to 0.88); and reduced caesarean section overall (relative risk 0.82, 95% confidence interval 0.69 to 1.97). No perinatal deaths were reported. Under limited perinatal surveillance, amnioinfusion was associated with a reduction in the following: meconium aspiration syndrome (relative risk 0.24, 95% confidence interval 0.12 to 0.48); neonatal hypoxic ischaemic encephalopathy (relative risk 0.07, 95% confidence interval 0.01 to 0.56) and neonatal ventilation or intensive care unit admission (relative risk 0.56, 95% confidence interval 0.39 to 0.79); there was a trend towards reduced perinatal mortality (relative risk 0.34, 95% confidence interval 0.11 to 1.06). Amnioinfusion is associated with improvements in perinatal outcome

  8. Application of 1-hydroxyethylidene-1, 1-diphosphonic acid in boiler water for industrial boilers.

    Science.gov (United States)

    Zeng, Bin; Li, Mao-Dong; Zhu, Zhi-Ping; Zhao, Jun-Ming; Zhang, Hui

    2013-01-01

    The primary method used for boiler water treatment is the addition of chemicals to industrial boilers to prevent corrosion and scaling. The static scale inhibition method was used to evaluate the scale inhibition performance of 1-hydroxyethylidene-1, 1-diphosphonic acid (HEDP). Autoclave static experiments were used to study the corrosion inhibition properties of the main material for industrial boilers (20# carbon steel) with an HEDP additive in the industrial boiler water medium. The electrochemical behavior of HEDP on carbon steel corrosion control was investigated using electrochemical impedance spectroscopy and Tafel polarization techniques. Experimental results indicate that HEDP can have a good scale inhibition effect when added at a quantity of 5 to 7 mg/L at a test temperature of not more than 100 °C. To achieve a high scale inhibition rate, the HEDP dosage must be increased when the test temperature exceeds 100 °C. Electrochemical and autoclave static experimental results suggest that HEDP has a good corrosion inhibition effect on 20# carbon steel at a concentration of 25 mg/L. HEDP is an excellent water treatment agent.

  9. Deposit Probe Measurements in Large Biomass-Fired Grate Boilers and Pulverized-Fuel Boilers

    DEFF Research Database (Denmark)

    Hansen, Stine Broholm; Jensen, Peter Arendt; Jappe Frandsen, Flemming

    2014-01-01

    A number of full-scale deposit probe measuring campaigns conducted in grate-fired and suspension-fired boilers, fired with biomass, have been reviewed and compared. The influence of operational parameters on the chemistry of ash and deposits, on deposit build-up rates, and on shedding behavior has...... of the deposits formed is determined by the fly ash composition and the flue gas temperature; increases in the local flue gas temperature lead to higher contents of Si and Ca and lower contents of Cl in the deposits. The net deposit build-up rates in grate-fired and suspension-fired boilers are at similar levels....../wood-firing in suspension-fired boilers, shedding occurred by debonding with incomplete removal at flue gas temperatures of 600–1000 °C and by debonding with complete removal during wood-firing in suspension-fired boilers at high flue gas temperatures (1300 °C). Shedding events were not observed during wood suspension...

  10. Efficiency of 72h- fermented corn waste liquor as a potential source for

    African Journals Online (AJOL)

    okafor

    tests. Equal concentrations of the LAB isolates at their determined peak ... Key Words: Probiotics, Lactic acid bacteria, Fermentation, Corn waste-liquor. ... diary products, decaying plants, intestinal tract and mucous membranes of animals and ...

  11. Evaluating the Intoxicating Degree of Liquor Products with Combinations of Fusel Alcohols, Acids, and Esters

    Directory of Open Access Journals (Sweden)

    Jia Xie

    2018-05-01

    Full Text Available To investigate the effects of fusel alcohols on the intoxicating degree of liquor products, formulated liquors (FLs were prepared by blending 1-propanol, isobutanol, and isoamyl alcohol with ethanol, organic acids, and corresponding ethyl esters to simulate the formula of traditional Chinese liquors. The prepared FLs were submitted for evaluation of their intoxicating degree (ID. The results showed that the fusel alcohols had a biphasic effect on the IDs of the FLs, depending on the comprehensive coordination of the characteristic minor components. The importance of the suitable ratio of alcohols/acids/esters (RAAE on the IDs was also revealed. Under an optimal ratio level, the fusel alcohols exhibited negligible effects on the IDs of the FLs. Moreover, the ratio of isoamyl alcohol to isobutanol (IA/IB showed a strong positive correlation to the IDs of the FLs. This study lays a foundation for the potential application in producing low-ID liquor.

  12. Evaluating the Intoxicating Degree of Liquor Products with Combinations of Fusel Alcohols, Acids, and Esters.

    Science.gov (United States)

    Xie, Jia; Tian, Xiao-Fei; He, Song-Gui; Wei, Yun-Lu; Peng, Bin; Wu, Zhen-Qiang

    2018-05-23

    To investigate the effects of fusel alcohols on the intoxicating degree of liquor products, formulated liquors (FLs) were prepared by blending 1-propanol, isobutanol, and isoamyl alcohol with ethanol, organic acids, and corresponding ethyl esters to simulate the formula of traditional Chinese liquors. The prepared FLs were submitted for evaluation of their intoxicating degree (ID). The results showed that the fusel alcohols had a biphasic effect on the IDs of the FLs, depending on the comprehensive coordination of the characteristic minor components. The importance of the suitable ratio of alcohols/acids/esters (RAAE) on the IDs was also revealed. Under an optimal ratio level, the fusel alcohols exhibited negligible effects on the IDs of the FLs. Moreover, the ratio of isoamyl alcohol to isobutanol (IA/IB) showed a strong positive correlation to the IDs of the FLs. This study lays a foundation for the potential application in producing low-ID liquor.

  13. A review of liquor transfer systems for use in nuclear reprocessing plants

    International Nuclear Information System (INIS)

    Singh, J.

    1982-01-01

    Liquor pumping systems for use in nuclear fuel reprocessing plants are described. Comparison of the operating characteristics and system constants are made between the air lift/Vacuum Operated Slug Lift, power fluidics and ejector pump systems. (author)

  14. Utilization of black liquor as concrete admixture and set retarder aid

    Directory of Open Access Journals (Sweden)

    Samar A. El-Mekkawi

    2011-04-01

    Full Text Available The utilization of black liquor, produced by the pulp and paper industry in Egypt, as a workability aid and set retarder admixture has been investigated. This approach may help eliminate the environmentally polluting black liquor waste. It also provides a low cost by-product, which can be widely used in the construction industry. The properties of black liquor and its performance on concrete at two different ratios of water to cement have been studied. The results revealed that black liquor from rice straw pulp increases concrete workability, improves compaction, and reduces honeycombing. Moreover, it retards the initial and final set time and enhances uniform compaction. The effect of incorporating small portions of silica fume has been investigated. The ageing effect of this material over a period of one year, to determine its safe storage period, has been studied. Finally, this admixture was found to comply with the relevant Egyptian standards.

  15. Treatment of soak liquor and bioelectricity generation in dual chamber microbial fuel cell.

    Science.gov (United States)

    Sathishkumar, Kuppusamy; Narenkumar, Jayaraman; Selvi, Adikesavan; Murugan, Kadarkarai; Babujanarthanam, Ranganathan; Rajasekar, Aruliah

    2018-02-08

    The discharge of untreated soak liquor from tannery industry causes severe environmental pollution. This study is characterizing the soak liquor as a substrate in the microbial fuel cell (MFC) for remediation along with electricity generation. The dual chamber MFC was constructed and operated. Potassium permanganate was used as cathode solution and carbon felt electrode as anodic and cathodic material, respectively. The soak liquor was characterized by electrochemical studies viz., cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), and polarization studies, respectively. The removal percentage of protein, lipid, and chemical oxygen demand (COD) were measured before and after treatment with MFC. The results of MFC showed a highest current density of 300 mA/cm 2 and a power density of 92 mW/m 2 . The removal of COD, protein, and lipid were noted as 96, 81, and 97% respectively during MFC process. This MFC can be used in tannery industries for treating soak liquor and simultaneous electricity generation.

  16. Simultaneous and rapid determination of multiple component concentrations in a Kraft liquor process stream

    Science.gov (United States)

    Li, Jian [Marietta, GA; Chai, Xin Sheng [Atlanta, GA; Zhu, Junyoung [Marietta, GA

    2008-06-24

    The present invention is a rapid method of determining the concentration of the major components in a chemical stream. The present invention is also a simple, low cost, device of determining the in-situ concentration of the major components in a chemical stream. In particular, the present invention provides a useful method for simultaneously determining the concentrations of sodium hydroxide, sodium sulfide and sodium carbonate in aqueous kraft pulping liquors through use of an attenuated total reflectance (ATR) tunnel flow cell or optical probe capable of producing a ultraviolet absorbency spectrum over a wavelength of 190 to 300 nm. In addition, the present invention eliminates the need for manual sampling and dilution previously required to generate analyzable samples. The inventive method can be used in Kraft pulping operations to control white liquor causticizing efficiency, sulfate reduction efficiency in green liquor, oxidation efficiency for oxidized white liquor and the active and effective alkali charge to kraft pulping operations.

  17. 77 FR 34981 - Stillaguamish Tribe of Indians-Liquor Control Ordinance

    Science.gov (United States)

    2012-06-12

    ... person who resides, conducts business, engages in a business transaction, receives benefits from the... liquor, wine, and beer, at a rate determined to be fair and equitable by the Board through independent...

  18. Stirred cell ultrafiltration of lignin from black liquor generated from South African kraft mills

    CSIR Research Space (South Africa)

    Kekana, Paul

    2016-12-01

    Full Text Available Ultrafiltration of lignin from black liquor was carried out in a stirred batch cell using polyethersulfone membranes. Parameters such as operating pressure, feed concentration, stirring rate and membrane cut-off size were varied and their effects...

  19. Materials and boiler rig testing to support chemical cleaning of once-through AGR boilers

    International Nuclear Information System (INIS)

    Tice, D.R.; Platts, N.; Raffel, A.S.; Rudge, A.

    2002-01-01

    An extensive programme of work has been carried out to evaluate two candidate inhibited cleaning solutions for possible implementation on plant, which would be the first chemical clean of an AGR boiler. The two candidate cleaning solutions considered were a Stannine-inhibited citric acid/formic acid mixture (GOM106) and inhibited hydrofluoric acid. Citric acid-based cleaning processes are widely used within the UK Power Industry. The GOM106 solution, comprising a mixture of 3% citric acid, 0.5% formic acid and 0.05% Stannine LTP inhibitor, buffered with ammonia to pH 3.5, was developed specifically for the AGR boilers during the 1970's. Although a considerable amount of materials testing work was carried out by British Energy's predecessor companies to produce a recommended cleaning procedure there were some remaining concerns with the use of GOM106, from these earlier studies, for example, an increased risk of pitting attack associated with the removal of thick 9Cr oxide deposits and a risk of unacceptable damage in critical locations such as the upper transition joints and other weld locations. Hence, additional testing was still required to validate the solution for use on plant. Inhibited hydrofluoric acid (HFA) was also evaluated as an alternative reagent to GOM106. HFA has been used extensively for cleaning mild and low'alloy steel boiler tubes in fossil-fired plant in the UK and elsewhere in Europe and is known to remove oxide quickly. Waste treatment is also easier than for the GOM106 process and some protection against damage to the boiler tube materials is provided by complexing of fluoride with ferric ion. Validation of the potential reagents and inhibitors was achieved by assessing the rate and effectiveness of oxide removal from specimens of helical boiler tubing and welds, together with establishing the extent of any metal loss or localised damage. The initial materials testing resulted in the inhibited ammoniated citric / formic acid reagent being

  20. CFD modeling of a boiler's tubes rupture

    International Nuclear Information System (INIS)

    Rahimi, Masoud; Khoshhal, Abbas; Shariati, Seyed Mehdi

    2006-01-01

    This paper reports the results of a study on the reason for tubes damage in the superheater Platen section of the 320 MW Bisotoun power plant, Iran. The boiler has three types of superheater tubes and the damage occurs in a series of elbows belongs to the long tubes. A three-dimensional modeling was performed using an in-house computational fluid dynamics (CFD) code in order to explore the reason. The code has ability of simultaneous solving of the continuity, the Reynolds-Averaged Navier-Stokes (RANS) equations and employing the turbulence, combustion and radiation models. The whole boiler including; walls, burners, air channels, three types of tubes, etc., was modeled in the real scale. The boiler was meshed into almost 2,000,000 tetrahedral control volumes and the standard k-ε turbulence model and the Rosseland radiation model were used in the model. The theoretical results showed that the inlet 18.9 MPa saturated steam becomes superheated inside the tubes and exit at a pressure of 17.8 MPa. The predicted results showed that the temperature of the steam and tube's wall in the long tubes is higher than the short and medium size tubes. In addition, the predicted steam mass flow rate in the long tube was lower than other ones. Therefore, it was concluded that the main reason for the rupture in the long tubes elbow is changing of the tube's metal microstructure due to working in a temperature higher than the design temperature. In addition, the structural fatigue tension makes the last elbow of the long tube more ready for rupture in comparison with the other places. The concluded result was validated by observations from the photomicrograph of the tube's metal samples taken from the damaged and undamaged sections

  1. Waste heat recovery system

    Energy Technology Data Exchange (ETDEWEB)

    Ernst, Timothy C.; Zigan, James A.

    2017-12-19

    A waste heat recovery system includes a Rankine cycle (RC) circuit having a pump, a boiler, an energy converter, and a condenser fluidly coupled via conduits in that order, to provide additional work. The additional work is fed to an input of a gearbox assembly including a capacity for oil by mechanically coupling to the energy converter to a gear assembly. An interface is positioned between the RC circuit and the gearbox assembly to partially restrict movement of oil present in the gear assembly into the RC circuit and partially restrict movement of working fluid present in the RC circuit into the gear assembly. An oil return line is fluidly connected to at least one of the conduits fluidly coupling the RC components to one another and is operable to return to the gear assembly oil that has moved across the interface from the gear assembly to the RC circuit.

  2. Boiler inspection manipulator for Torness Power Station

    International Nuclear Information System (INIS)

    Carrey, R.T.A.; Playle, M.J.

    1996-01-01

    In-service inspection at Torness Advanced Gas-cooled Reactor is achieved, via penetrations above and below the core area and boilers and through eight circulator penetrations for inspection of the sub-diagrid area. A manipulator is described which can access the area above the reactor core via any of these eight peripheral penetrations. The design and fabrication of the manipulator has led to innovation with a number of possible solutions being tendered. In reactor deployment of the successful design is expected in early 1997. (UK)

  3. Multiloop control of a drum boiler

    Directory of Open Access Journals (Sweden)

    Alena Kozáková

    2014-05-01

    Full Text Available The Equivalent Subsystems Method (ESM (Kozáková et al., 2011 is methodology of decentralized controller design in the frequency domain which allows designing local controllers using any SISO frequency domain method. The paper deals with the digital ESM version where digital local PID controllers guaranteeing required performance for the full system are designed for individual equivalent subsystems using the practice-oriented Sine-wave method (Bucz et al., 2012. The proposed decentralized controller design procedure was verified on the nonlinear benchmark drum boiler simulation model (Morilla, 2012.

  4. Nuclear reactors with auxiliary boiler circuit

    International Nuclear Information System (INIS)

    George, B.V.; Cook, R.K.

    1976-01-01

    A gas-cooled nuclear reactor has a main circulatory system for the gaseous coolant incorporating one or more main energy converting units, such as gas turbines, and an auxiliary circulatory system for the gaseous coolant incorporating at least one steam generating boiler arranged to be heated by the coolant after its passage through the reactor core to provide steam for driving an auxiliary steam turbine, such an arrangement providing a simplified start-up procedure also providing emergency duties associated with long term heat removal on reactor shut down

  5. Elimination of Phenol and Color from Pulping Black Liquor Using Electrocoagulation Process

    OpenAIRE

    Nahid Rastegarfar; Rabi Behrouz; Nader Bahramifar

    2013-01-01

    There are many non-wood lignocelluloses resources such as wheat, rice straw and other agriculture by- products with appropriate feature for pulp production in Iran. The most major deterrent to their use is presence of pulping black liquor that due to lignin of lignocelluloses solution contains significant amounts of color and phenol compounds. The aim of this paper was investigation of the ability to remove phenol and color as the most important organic pollutants from back liquor of agri-bas...

  6. Pubs in Public Life: A Place for Liquor Spaces in the City of Vancouver

    OpenAIRE

    Forbes, Heather

    2010-01-01

    Vancouver liquor licensing bylaws has been described by members of the media, industry, government and general public as overly restrictive, especially in the areas of hours ofservice, geographical distribution and the cultural diversity ofpublic liquor spaces. According to the City of Vancouver, the objective of city stewardship is to provide for the social, economic and physical well-being of citizens. A consultation of both academic research and the Vancouver community suggests that public...

  7. Maleic acid treatment of biologically detoxified corn stover liquor.

    Science.gov (United States)

    Kim, Daehwan; Ximenes, Eduardo A; Nichols, Nancy N; Cao, Guangli; Frazer, Sarah E; Ladisch, Michael R

    2016-09-01

    Elimination of microbial and enzyme inhibitors from pretreated lignocellulose is critical for effective cellulose conversion and yeast fermentation of liquid hot water (LHW) pretreated corn stover. In this study, xylan oligomers were hydrolyzed using either maleic acid or hemicellulases, and other soluble inhibitors were eliminated by biological detoxification. Corn stover at 20% (w/v) solids was LHW pretreated LHW (severity factor: 4.3). The 20% solids (w/v) pretreated corn stover derived liquor was recovered and biologically detoxified using the fungus Coniochaeta ligniaria NRRL30616. After maleic acid treatment, and using 5 filter paper units of cellulase/g glucan (8.3mg protein/g glucan), 73% higher cellulose conversion from corn stover was obtained for biodetoxified samples compared to undetoxified samples. This corresponded to 87% cellulose to glucose conversion. Ethanol production by yeast of pretreated corn stover solids hydrolysate was 1.4 times higher than undetoxified samples, with a reduction of 3h in the fermentation lag phase. Copyright © 2016 Elsevier Ltd. All rights reserved.

  8. The evaporation of viscose process liquors: Final report

    Energy Technology Data Exchange (ETDEWEB)

    Thornton, R

    1984-01-01

    A program of work aimed at producing designs for an energy efficient process for the evaporation of water from viscose process liquors has been completed. The process uses mechanical vapor recompression in conjunction with a thin plastic heat transfer surface. A bench laboratory evaporation rig was built to prove the technical viability of the process. This was followed by the construction of a research plant at a viscose production site. The capacity of this plant was 100 to 150 kg/h of water evaporated. The construction and operation of a plastic heat exchanger with thin walled plastic tubes was achieved with considerable success. The lining of the concrete containment vessel proved more difficult, and the technique employed may not be the best for commercial units. Heat transfer coefficients of up to 550 Wm/sup -2/ K/sup -1/ were measured on the research plant. These agreed well with results obtained from a mathematical model developed for the process. An optimum design for a commercial unit has been costed and the financial parameters determined. Courtaulds considers that the construction of a demonstration plant is justified. 3 refs., 8 figs.

  9. The transport of plutonium nitrate liquor in the UK

    International Nuclear Information System (INIS)

    Barrett, T.R.; Wilson, D.; Bancroft, M.; Higson, J.

    1994-01-01

    The PFR fuel cycle reasons for plutonium nitrate liquor transport are discussed, identifying the pre 1980 'one litre' bottle associated with nuclear R and D activities and then the 250 litre PUNIT transport container to support the PFR fuel cycle. The PUNIT vessel design is discussed, addressing, in particular, the need for clean filling and criticality design features together with the identification of the IAEA transport regulations criteria and the late 1970s testing programme -the full scale drop tests and the model fire tests. Radiolysis is discussed together with the need for inert gas padding. The filling facility and operation are then outlined together with the fissile material accountancy requirements. The shipments and emergency arrangements are then described drawing attention to time and weather constraints. The risk assessment is discussed, together with reference to the Competent Authority (DoT) 'authorisation' and any constraints. A history of the amount of material transferred is then given - relating that to the reprocessing plant operations since 1980. The most satisfactory performance over 12 years is noted. (author)

  10. Test of a small domestic boiler using different pellets

    International Nuclear Information System (INIS)

    Dias, J.; Costa, M.; Azevedo, J.L.T.

    2004-01-01

    This paper presents results from an experimental study performed on a 13 kW th commercial domestic boiler using pellets as fuel. Four different types of pellets were used and, for each one, the boiler was tested as a function of its capacity and the fan regulation affecting excess air. Measurements were performed for boiler heat load, pellet consumption rate, flue-gas temperature and composition. Mass balances allowed the calculation of the flue-gas flow rate and associated heat losses. Losses from incomplete combustion have also been quantified. Under boiler steady-state conditions the flue-gas O 2 concentration changes with boiler load and ventilation due to the regulation scheme of the boiler. Flue-gas CO shows a minimum for values of O 2 in the flue-gases of about 13%. NO x emissions are independent of excess air for low values of nitrogen in the fuel whereas, for larger values, NO x emissions increase with the O 2 present in the combustion products. The fractional conversion of the pellet nitrogen into NO x is in line with literature data. The boiler start-up was characterised by the temperature evolution inside and above the bed showing the propagation of combustion in the bed during about 10 min. During boiler start-up, a maximum in CO emissions was observed which is associated with the maximum combustion intensity, as typified by the flue-gas O 2 concentration and temperature, regardless the pellet type. (Author)

  11. A rule-based industrial boiler selection system

    NARCIS (Netherlands)

    Tan, C.F.; Khalil, S.N.; Karjanto, J.; Tee, B.T.; Wahidin, L.S.; Chen, W.; Rauterberg, G.W.M.; Sivarao, S.; Lim, T.L.

    2015-01-01

    Boiler is a device used for generating the steam for power generation, process use or heating, and hot water for heating purposes. Steam boiler consists of the containing vessel and convection heating surfaces only, whereas a steam generator covers the whole unit, encompassing water wall tubes,

  12. CFD investigation of flow through internally riffled boiler tubes

    DEFF Research Database (Denmark)

    Rasmussen, Christian; Houbak, Niels; Sørensen, Jens Nørkær

    1997-01-01

    In this paper we show how to model the swirling flow in an internally riffled boiler tube. The flow field is visualized and the results are compared with measurements.......In this paper we show how to model the swirling flow in an internally riffled boiler tube. The flow field is visualized and the results are compared with measurements....

  13. 30 CFR 77.411 - Compressed air and boilers; general.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Compressed air and boilers; general. 77.411 Section 77.411 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE... COAL MINES Safeguards for Mechanical Equipment § 77.411 Compressed air and boilers; general. All...

  14. Exergetic Modelling of Oil-Fired Steam Boilers | Ohijeagbon ...

    African Journals Online (AJOL)

    The performance variables and potential for energy savings in oil-fired industrial steam boilers were studied. Operational parameters of steam boilers using low pour fuel oil (LPFO) and diesel were used to determine thermodynamic properties of material streams and exergetic parameters. Analysis of thermodynamic ...

  15. Assessment of Some Performance Characteristics of Refuse Boiler ...

    African Journals Online (AJOL)

    A pioneer palm oil boiler unit, in an immense power self-contained oil mill, impaired by many years of accumulated depreciation, was rebuilt in the pattern of a design-out scheme aimed primarily at rehabilitating the entire boiler system to a state of functionality. The research work studied the pre-maintenance and post ...

  16. DESIGN REPORT: LOW-NOX BURNERS FOR PACKAGE BOILERS

    Science.gov (United States)

    The report describes a low-NOx burner design, presented for residual-oil-fired industrial boilers and boilers cofiring conventional fuels and nitrated hazardous wastes. The burner offers lower NOx emission levels for these applications than conventional commercial burners. The bu...

  17. Solved and unsolved problems in boiler systems. Learning from accidents

    International Nuclear Information System (INIS)

    Ozawa, Mamoru

    2000-01-01

    This paper begins with a brief review on the similarity law of conventional fossil-fuel-fired boilers. The concept is based on the fact that the heat release due to combustion in the furnace is restricted by the furnace volume but the heat absorption is restricted by the heat transfer surface area. This means that a small-capacity boiler has relatively high specific furnace heat release rate, about 10 MW/m 3 , and on the contrary a large-capacity boiler has lower value. The surface-heat-flux limit is mainly dominated by the CHF inside the water-wall tubes of the boiler furnace, about 350 kW/m 2 . This heat-flux limit is almost the same order independently on the capacity of boilers. For the safety of water-walls, it is essential to retain suitable water circulation, i.e. circulation ratio and velocity of water. This principle is a common knowledge of boiler designer, but actual situation is not the case. Newly designed boilers often suffer from similar accidents, especially burnout due to circulation problems. This paper demonstrates recent accidents encountered in practical boilers, and raises problems of rather classical but important two-phase flow and heat transfer. (author)

  18. Thermomechanical finite element analysis of hot water boiler structure

    Directory of Open Access Journals (Sweden)

    Živković Dragoljub S.

    2012-01-01

    Full Text Available The paper presents an application of the Finite Elements Method for stress and strain analysis of the hot water boiler structure. The aim of the research was to investigate the influence of the boiler scale on the thermal stresses and strains of the structure of hot water boilers. Results show that maximum thermal stresses appear in the zone of the pipe carrying wall of the first reversing chamber. This indicates that the most critical part of the boiler are weld spots of the smoke pipes and pipe carrying plate, which in the case of significant scale deposits can lead to cracks in the welds and water leakage from the boiler. The nonlinear effects were taken into account by defining the bilinear isotropic hardening model for all boiler elements. Temperature dependency was defined for all relevant material properties, i. e. isotropic coefficient of thermal expansion, Young’s modulus, and isotropic thermal conductivity. The verification of the FEA model was performed by comparing the measured deformations of the hot water boiler with the simulation results. As a reference object, a Viessmann - Vitomax 200 HW boiler was used, with the installed power of 18.2 MW. CAD modeling was done within the Autodesk Inventor, and stress and strain analysis was performed in the ANSYS Software.

  19. Water Boiler Change-Over in Mini-TPP Mode

    Directory of Open Access Journals (Sweden)

    B. A. Bayrashevsky

    2011-01-01

    Full Text Available The paper considers water boiler modernization by its change-over in mini-TPP mode with an expansion tank and a heating turbine of small capacity.  A software complex permitting to evaluate competitive ability of such water boiler modernization in comparison with a cogeneration plant.

  20. Hybrid system for fouling control in biomass boilers

    Energy Technology Data Exchange (ETDEWEB)

    Romeo, Luis M.; Gareta, Raquel [Centro de Investigacin de Recursos y Consumos Energeticos (CIRCE), Universidad de Zaragoza, Centro Politecnico Superior, Mareda de Luna, 3, Zaragoza 50018, (Spain)

    2006-12-15

    Renewable energy sources are essential paths towards sustainable development and CO{sub 2} emission reduction. For example, the European Union has set the target of achieving 22% of electricity generation from renewable sources by 2010. However, the extensive use of this energy source is being avoided by some technical problems as fouling and slagging in the surfaces of boiler heat exchangers. Although these phenomena were extensively studied in the last decades in order to optimize the behaviour of large coal power boilers, a simple, general and effective method for fouling control has not been developed. For biomass boilers, the feedstock variability and the presence of new components in ash chemistry increase the fouling influence in boiler performance. In particular, heat transfer is widely affected and the boiler capacity becomes dramatically reduced. Unfortunately, the classical approach of regular sootblowing cycles becomes clearly insufficient for them. Artificial Intelligence (AI) provides new means to undertake this problem. This paper illustrates a methodology based on Neural Networks (NNs) and Fuzzy-Logic Expert Systems to select the moment for activating sootblowing in an industrial biomass boiler. The main aim is to minimize the boiler energy and efficiency losses with a proper sootblowing activation. Although the NN type used in this work is well-known and the Hybrid Systems had been extensively used in the last decade, the excellent results obtained in the use of AI in industrial biomass boilers control with regard to previous approaches makes this work a novelty. (Author)

  1. Optimization of feed water control for auxiliary boiler

    International Nuclear Information System (INIS)

    Li Lingmao

    2004-01-01

    This paper described the feed water control system of the auxiliary boiler steam drum in Qinshan Phase III Nuclear Power Plant, analyzed the deficiency of the original configuration, and proposed the optimized configuration. The optimized feed water control system can ensure the stable and safe operation of the auxiliary boiler, and the normal operation of the users. (author)

  2. Assessment of the candidate markets for liquid boiler fuels

    Energy Technology Data Exchange (ETDEWEB)

    None

    1979-12-01

    Liquid fuels can be produced from coal in a number of indirect and direct liquefaction processes. While indirect coal liquefaction has been proved commercially outside the United States, most attention in this country has focused on the direct liquefaction processes, which include the processes under examination in this report; namely, the Exxon Donor Solvent (EDS), the H-Coal, and the Solvent Refined Coal (SRC) II processes. The objectives of the study were to: compare the boiler fuels of direct coal liquefaction with residual fuel oil (No. 6 fuel oil) including physical characteristics and environmental hazards, such as carcinogenic characteristics and toxic hazard characteristics; determine whether a boiler fuel market would exist for the coal liquefaction products given their physical characteristics and potential environmental hazards; determine the advantages of utilizing methanol as a boiler fuel on a continuous basis in commercial boilers utilizing existing technology; identify the potential regional candidate markets for direct coal liquefaction products as liquid boiler fuels; determine the distributing and handling costs associated with marketing coal liquefaction products as liquid boiler fuels; determine the current regulatory issues associated with the marketing of coal liquefaction products as boiler fuels; and determine and evaluate other institutional issues associated with the marketing of direct coal liquefaction products as boiler fuels.

  3. Computed tomographic volumetry of cerebral liquor by semiautomatic contour recognition and gray value histogram analysis

    International Nuclear Information System (INIS)

    Tschammler, A.; Middendorf, C.; Luedinghausen, M. v.; Wittenberg, G.; Krahe, T.

    1996-01-01

    A program (VAC, Siemens) using selfmade, anthropomorphous phantomas to measure semiautomatically the volume of the cerebral liquor in CT scans of the whole skull was tested. Cerebral tissue was simulated by ellipsoid bodies made from Agar and Nal which were placed in a human skull. Volumes of the ventricular and subarachnoidal liquor could be defined arbitrarily. A correlation coefficient of r>=0.9 using a slice thickness of 1-5 mm was found (thickness 8 mm: r=0.75). The volume of the cerebral liquor was underestimated by 25-68%. Separate measurements of the ventricular and subarachnoidal liquor spaces showed a high accuracy of the measurements done in the ventricles (r=0.997, y=0.996x-1). The volume of the subarachnoidal liquor was not detected completely due to partial volume effects which were seen especially in the basal and apical scans. The program VAC is useful for the semiautomatic measurement of the volume of the ventricles. The assessment of the subarachnoidal liquor is limited to semiquantitative results. (orig./MG) [de

  4. Sacrificial adsorbate for surfactants utilized in chemical floods of enhanced oil recovery operations

    Science.gov (United States)

    Johnson, Jr., James S.; Westmoreland, Clyde G.

    1982-01-01

    The present invention is directed to a sacrificial or competitive adsorbate for surfactants contained in chemical flooding emulsions for enhanced oil recovery operations. The adsorbate to be utilized in the method of the present invention is a caustic effluent from the bleach stage or the weak black liquor from the digesters and pulp washers of the kraft pulping process. This effluent or weak black liquor is injected into an oil-bearing subterranean earth formation prior to or concurrent with the chemical flood emulsion and is adsorbed on the active mineral surfaces of the formation matrix so as to effectively reduce adsorption of surfactant in the chemical flood. Alternatively, the effluent or liquor can be injected into the subterranean earth formation subsequent to a chemical flood to displace the surfactant from the mineral surfaces for the recovery thereof.

  5. Recover of some rare earth elements from leach liquor of the Saghand uranium ore using combined precipitation and cation exchange methods

    International Nuclear Information System (INIS)

    Khanchi, A. R.; Rafati, H.; Rezvaniyanzadeh, M. R.

    2008-01-01

    In this research work, the recovery and separation of La(III), Ce(III), Sm(III), Dy(III) and Nd(III) from Saghand uranium ore have been studied by precipitation and ion-exchange chromatography methods using Dowex 50 W-X 8 cation exchanger. At first, some preliminary and preconcentration experiments such as comminution, sieve analysis, gravity table and electrostatic in preconcentration of lanthanides were performed. Then, acidic digesting and leaching procedure were used. The results of experiments showed that rare earth elements, along with interfering ions such as Al(III), Fe(III), Mg(II) and Mn(II) present in the leach liquor solution. The investigation of separation process by precipitation method revealed that precipitation and then fast separation using centrifugal technique had the best results in the elimination of interference elements. In order to separate the lanthanides and to obtain their elution curves, the chromatographic column containing Dowex 50 W-X 8 resin was employed. For efficient separation of lanthanides from interference elements the hydrochloric acid with concentration of two and six molar was used respectively. Recovery of lanthanides from the leach liquor solution was achieved more than 85%

  6. A theoretical approach for energy saving in industrial steam boilers

    International Nuclear Information System (INIS)

    Sabry, T.I.; Mohamed, N.H.; Elghonimy, A.M.

    1993-01-01

    Optimization of the performance characteristics of such a steam boiler has been analyzed theoretically. Suitable thermodynamic relations have been utilized here to construct a computer model that would carry out the boiler performance characteristics at different operating parameters (e.g.; amount of excess air, fuel type, rate of blowdown preheating of combustion air and flow gases temperature). The results demonstrate that this computer model is to be used successfully in selecting the different operating parameters of the steam boiler at variant loads considering the best economical operation. Besides, this model can be used to investigate the sensitivity of the performance characteristics to the deviation of the boiler operating parameters from their optimum values. It was found also that changing the operating parameters beside the type of fuel in a boiler affects its performance characteristics. 3 figs

  7. Optimisation of Marine Boilers using Model-based Multivariable Control

    DEFF Research Database (Denmark)

    Solberg, Brian

    Traditionally, marine boilers have been controlled using classical single loop controllers. To optimise marine boiler performance, reduce new installation time and minimise the physical dimensions of these large steel constructions, a more comprehensive and coherent control strategy is needed....... This research deals with the application of advanced control to a specific class of marine boilers combining well-known design methods for multivariable systems. This thesis presents contributions for modelling and control of the one-pass smoke tube marine boilers as well as for hybrid systems control. Much...... of the focus has been directed towards water level control which is complicated by the nature of the disturbances acting on the system as well as by low frequency sensor noise. This focus was motivated by an estimated large potential to minimise the boiler geometry by reducing water level fluctuations...

  8. Boiling process modelling peculiarities analysis of the vacuum boiler

    Science.gov (United States)

    Slobodina, E. N.; Mikhailov, A. G.

    2017-06-01

    The analysis of the low and medium powered boiler equipment development was carried out, boiler units possible development directions with the purpose of energy efficiency improvement were identified. Engineering studies for the vacuum boilers applying are represented. Vacuum boiler heat-exchange processes where boiling water is the working body are considered. Heat-exchange intensification method under boiling at the maximum heat- transfer coefficient is examined. As a result of the conducted calculation studies, heat-transfer coefficients variation curves depending on the pressure, calculated through the analytical and numerical methodologies were obtained. The conclusion about the possibility of numerical computing method application through RPI ANSYS CFX for the boiling process description in boiler vacuum volume was given.

  9. Biomass boilers: towards a higher efficiency

    International Nuclear Information System (INIS)

    Petitot, Pauline; Signoret, Stephane; Mary, Olivier; Dejeu, Mathieu; Tachet, Jean-Pierre

    2014-01-01

    A set of articles proposes an overview of the situation and perspectives of biomass fuelled boilers in France. As outlined in an interview, professionals are supported by ADEME and the Heat Fund (Fonds Chaleur) for a continuous development of wood-energy in order to reach national objectives for renewable energies by 2020. The next article discusses issues related to wood supply, with some concerns regarding forest exploitation, and needs to find new management ways and to use other sources than forests. The technical status and perspectives of smoke condensation in wood-fuelled boilers are discussed. The example of a malt-house near Issoudun fuelled by biomass since 2013 is presented. Other examples concern a small town of Burgundy which developed and is still improving a heat network, a wood-fuelled heat network in Saint-Denis, and a biomass wood-fuelled heat production plant for the Toulouse University hospital. Graphs indicate evolutions of prices for different wood-based fuel products. The last article outlines the role of forests and the importance of their protection in the struggle against climate change, and discusses problems faced to support this preservation and its financing

  10. Mercury emissions from polish pulverized coalfired boiler

    Directory of Open Access Journals (Sweden)

    Wichliński Michał

    2017-01-01

    Full Text Available The current paper presents the research results carried out at one of Polish power plants at a pulverized hard coal-fired 225 MW unit. The research was carried out at full load of the boiler (100% MCR and focused on analysis of mercury content in the input fuel and limestone sorbent for wet flue gas desulfurization (FGD system, as well as investigation of mercury content in the combustion products, i.e. fly ash, slag, FGD product (gypsum and FGD effluents (waste. Within the framework of the present study the concentration of mercury vapor in the exhaust gas was also investigated. The analysis was performed using Lumex RA-915+ spectrometer with an attachment (RP-91C. The measurements were carried out at three locations, i.e. before the electrostatic precipitator (ESP, downstream the ESP, and downstream the wet FGD plant. Design of the measurement system allowed to determine both forms of mercury in the flue gas (Hg0 and Hg2+ at all measurement locations.Based on the measurement results the balance of mercury for a pulverized coal (PC boiler was calculated and the amount of mercury was assessed both in the input solids (fuel and sorbent, as well as the gaseous and solids products (flue gas, slag, ash, gypsum and FGD waste.

  11. Code boiler and pressure vessel life assessment

    International Nuclear Information System (INIS)

    Farr, J.R.

    1992-01-01

    In the United States of America and in Canada, laws and controls for determining life assessment for continued operation of equipment exist only for those pressure vessels built to Section III and evaluated according to Section XI. In this presentation, some of those considerations which are made in the USA and Canada for deciding on life or condition assessment of boilers and pressure vessels designed and constructed to other sections of the ASME Boiler and Pressure Vessel Code are reviewed. Life assessment or condition assesssment is essential in determining what is necessary for continued operation. With no ASME rules being adopted by laws or regulations, other than OSHA in the USA and similar environmental controls in Canada, to control life assessment for continued operation, the equipment owner must decide if assessment is to be done and how much to do. Some of those considerations are reviewed along with methods and procedures to make an assessment along with a discussion of where the ASME B and PV Code currently stands regarding continued operation. (orig.)

  12. Establishing an energy efficiency recommendation for commercial boilers

    International Nuclear Information System (INIS)

    Ware, Michelle J.

    2000-01-01

    To assist the federal government in meeting its energy reduction goals, President Clinton's Executive Order 12902 established the Procurement Challenge, which directed all federal agencies to purchase equipment within the top 25th percentile of efficiency. Under the direction of DOE's Federal Energy Management Program (FEMP), the Procurement Challenge's goal is to create efficiency recommendations for all energy-using products that could substantially impact the government's energy reduction goals, like commercial boilers. A typical 5,000,000 Btuh boiler, with a thermal efficiency of 83.2%, can have lifetime energy cost savings of$40,000 when compared to a boiler with a thermal efficiency of 78%. For the federal market, which makes up 2% of the boiler market, this means lifetime energy cost savings of over$25,600,000. To establish efficiency recommendations, FEMP uses standardized performance ratings for products sold in the marketplace. Currently, the boiler industry uses combustion efficiency and, sometimes, thermal efficiency performance measures when specifying a commercial boiler. For many years, the industry has used these efficiency measures interchangeably, causing confusion about boiler performance measurements, and making it difficult for FEMP to establish the top 25th percentile of efficiency. This paper will illustrate the method used to establish FEMP's recommendation for boilers. The method involved defining a correlation between thermal and combustion efficiency among boiler classifications; using the correlation to model a data set of all the boiler types available in the market; and identifying how the correlation affected the top 25th percentile analysis. The paper also will discuss the applicability of this method for evaluating other equipment for which there are limited data on performance ratings

  13. Kajian penerapan recycle, reuse dan recovery untuk proses produksi kulit web blue pada industri penyamakan kulit

    Directory of Open Access Journals (Sweden)

    Prayitno Prayitno

    2009-06-01

    Full Text Available Leather tanning industries are industries that process skin to produce finish leather product by using many stages of process in which for every stage of process will generate a huge amount either liquid or solid waste. If waste are not to be treated properly, it will cause environmental pollution. Implementation of 3R programs i.e. recycle, reuse and recovery will give impact on minimizing of waste problem. In leather tanning industries for producing wet blue leather however, 3R programs have to be implemented in processes of desalting, washing liquor, flesh and fat, chrome liquor and chrome-tanned waste. In implementing 3 R the waste generated can be either reused, recycled or recoveried as follow salt as swelling agent preventing in pickling process; washing liquor waste as washing liquor for dirt washing; flesh and fat as raw material for producing tallow, soap, fertilizer and livestock fodder; chrome liquor waste as chrome agent for chrome tanning and chrome-tanned waste as filler for producing material building or livestock fodder as protein sources.

  14. MHD (Magnetohydrodynamics) recovery and regeneration

    Energy Technology Data Exchange (ETDEWEB)

    McIlroy, R. A. [Babcock and Wilcox Co., Alliance, OH (United States). Research Center; Probert, P. B. [Babcock and Wilcox Co., Alliance, OH (United States). Research Center; Lahoda, E. J. [Westinghouse Electric Corp., Pittsburgh, PA (United States); Swift, W. M. [Argonne National Lab. (ANL), Argonne, IL (United States); Jackson, D. M. [Univ. of Tennessee Space Inst. (UTSI), Tullahoma, TN (United States); Prasad, J. [Univ. of Tennessee Space Inst. (UTSI), Tullahoma, TN (United States); Martin, J. [Hudson Engineering (United States); Rogers, C. [Hudson Engineering (United States); Ho, K. K. [Babcock and Wilcox Co., Alliance, OH (United States). Research Center; Senary, M. K. [Babcock and Wilcox Co., Alliance, OH (United States). Research Center; Lee, S. [Univ. of Akron, OH (United States)

    1988-10-01

    A two-phase program investigating MHD seed regeneration is described. In Phase I, bench scale experiments were carried out to demonstrate the technical feasibility of a proposed Seed Regeneration Process. The Phase I data has been used for the preliminary design of a Proof-of-Concept (POC) plant which will be built and tested in Phase II. The Phase I data will also be used to estimate the costs of a 300 Mw(t) demonstration plant for comparison with other processes. The Seed Regeneration Process consists of two major subprocesses; a Westinghouse Dry Reduction process and a modified Tampella (sulfur) Recovery process. The Westinghouse process reduces the recovered spent seed (i.e., potassium sulfate) to potassium polysulfide in a rotary kiln. The reduction product is dissolved in water to form green liquor, clarified to remove residual coal ash, and sent to the Tampella sulfur release system. The sulfur is released using carbon dioxide from flue gas in a two stage reaction. The sulfur is converted to elemental sulfur as a marketable by product. The potassium is crystallized from the green liquor and dried to the anhydrous form for return to the MHD unit.

  15. Impact of chocolate liquor on vascular lesions in apoE-knockout mice.

    Science.gov (United States)

    Yazdekhasti, Narges; Brandsch, Corinna; Hirche, Frank; Kühn, Julia; Schloesser, Anke; Esatbeyoglu, Tuba; Huebbe, Patricia; Wolffram, Siegfried; Rimbach, Gerald; Stangl, Gabriele I

    2017-10-15

    Cocoa polyphenols are thought to reduce the risk of cardiovascular diseases. Thus, cocoa-containing foods may have significant health benefits. Here, we studied the impact of chocolate liquor on vascular lesion development and plaque composition in a mouse model of atherosclerosis. Apolipoprotein E (apoE)-knockout mice were assigned to two groups and fed a Western diet that contained 250 g/kg of either chocolate liquor or a polyphenol-free isoenergetic control paste for 16 weeks. In addition to fat, protein, and fibers, the chocolate liquor contained 2 g/kg of polyphenols. Compared with the control group, mice fed the chocolate liquor had larger plaque areas in the descending aorta and aortic root, which were attributed to a higher mass of vascular smooth muscle cells (VSMCs) and collagen. Vascular lipid deposits and calcification areas did not differ between the two groups. The aortic tissue level of interleukin-6 (IL-6) mRNA was 5-fold higher in the mice fed chocolate liquor than in the control mice. Chocolate-fed mice exhibited an increased hepatic saturated to polyunsaturated fatty acid ratio than the controls. Although the chocolate liquor contained 14 µg/kg of vitamin D 2 , the chocolate liquor-fed mice did not have measurable 25-hydroxyvitamin D 2 in the serum. These mice even showed a 25% reduction in the level of 25-hydroxyvitamin D 3 compared with the control mice. Overall, present data may contribute to our understanding how chocolate constituents can impact vascular lesion development. © 2017 The Author(s). Published by Portland Press Limited on behalf of the Biochemical Society.

  16. Degradation of black liquor from bioethanol process using coagulation and Fenton-like methods

    Science.gov (United States)

    Muryanto, Muryanto; Sari, Ajeng Arum; Abimanyu, Haznan

    2017-01-01

    Black liquor is one of the main by-products of the pretreatment process in bioethanol production from oil palm empty fruit bunches. Black liquor wastewater releases black coloured effluent with high chemical oxygen demand (COD) and low dissolved oxygen (DO). It had a distinctive dark coloration, high alkalinity (pH=13), high organic content (COD > 50,000 ppm) and a high solid content (TSS > 5,000 ppm). Lignin destruction can be done by using high oxidation from OH radical system such as advanced oxidation processes (AOPs). Thereafter, the high concentration of COD, color, and TSS can be removed. The general aim of the present investigation was to determine degradation of black liquor wastewater by using a combined coagulation and Fenton-like methods. In this research, we use Poly Aluminum Chloride (PAC) as a coagulant and FeCl3.6H2O and H2O2 for Fenton-like's reagent. The process was conducted in jar test at 200 rpm for 30 minutes and after that slowly mixed for 2 hours and left for sedimentation 24 hours. 50 ml black liquor was added with variation dose of 1-5% PAC, and 10 % Fenton-like reagent. Hydroxyl radical was generated by the Fenton-like's reagent (ratio FeCl3.6H2O : H2O2 was varied). The highest decolorization of black liquor 70 % was obtained under 5% PAC coagulant. The pH of the wastewater was reduced from 13.00 to 8.07 after the addition of the coagulant. The decolorization of original black liquor was approximately 58% through the Fenton-like process. The combination of PAC and Fenton-like reagent has able to enhance the decolorization of black liquor up to 97%.

  17. Social capital, the miniaturisation of community and consumption of homemade liquor and smuggled liquor during the past year. A population-based study.

    Science.gov (United States)

    Lindström, Martin

    2005-12-01

    To study the impact of social participation, trust and the miniaturisation of community, i.e. high social participation/low trust, on consumption of homemade liquor and smuggled liquor during the past year. The Scania 2000 public health survey is a cross-sectional, postal questionnaire study. A total of 13,604 persons aged 18-80 years were included. A logistic regression model was used to investigate the association between the social capital variables and illegal alcohol consumption. The multivariate analyses analysed the importance of confounders (age, country of origin, education and economic stress) on the differences in consumption of homemade and smuggled liquor according to the social capital variables. A 28.2% proportion of all men and 14.9% of all women had consumed homemade liquor during the past year. The proportions who had consumed smuggled liquor during the past year were even higher, 40.1% among men and 21.4% among women. Both forms of illegal alcohol consumption were significantly positively associated with social participation and negatively associated with trust. The miniaturisation of community category, i.e. high social participation/low trust, had significantly higher risks of consumption during the past year of the consumption of both forms of illegally provided alcohol compared to the high social capital (high social participation/high trust) category, while the low social participation/high trust category had significantly lower risks. High social participation combined with low trust is positively associated with consumption of illegally provided alcohol. The results have implications for alcohol prevention programs, because structural/social factors that may hinder information and norms concerning illegal alcohol have been identified in this study.

  18. BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS

    Energy Technology Data Exchange (ETDEWEB)

    R. Viswanathan; K. Coleman

    2003-01-20

    The principal objective of this project is to develop materials technology for use in ultrasupercritical (USC) plant boilers capable of operating with 760 C (1400 F), 35 MPa (5000 psi) steam. In the 21st century, the world faces the critical challenge of providing abundant, cheap electricity to meet the needs of a growing global population while at the same time preserving environmental values. Most studies of this issue conclude that a robust portfolio of generation technologies and fuels should be developed to assure that the United States will have adequate electricity supplies in a variety of possible future scenarios. The use of coal for electricity generation poses a unique set of challenges. On the one hand, coal is plentiful and available at low cost in much of the world, notably in the U.S., China, and India. Countries with large coal reserves will want to develop them to foster economic growth and energy security. On the other hand, traditional methods of coal combustion emit pollutants and CO{sub 2} at high levels relative to other generation options. Maintaining coal as a generation option in the 21st century will require methods for addressing these environmental issues. This project has established a government/industry consortium to undertake a five-year effort to evaluate and develop of advanced materials that allow the use of advanced steam cycles in coal-based power plants. These advanced cycles, with steam temperatures up to 760 C, will increase the efficiency of coal-fired boilers from an average of 35% efficiency (current domestic fleet) to 47% (HHV). This efficiency increase will enable coal-fired power plants to generate electricity at competitive rates (irrespective of fuel costs) while reducing CO{sub 2} and other fuel-related emissions by as much as 29%. Success in achieving these objectives will support a number of broader goals. First, from a national prospective, the program will identify advanced materials that will make it possible to

  19. A novel direct-fired porous-medium boiler

    Science.gov (United States)

    Prasartkaew, Boonrit

    2018-01-01

    Nowadays, power and heat generation systems pay an important role in all economic sectors. These systems are mainly based on combustion reaction and operated under the second law of thermodynamics. A conventional boilers, a main component of heat and power generators, have thermal efficiency in the range of 70 to 85%, mainly owing to they have flue gas heat loss. This paper proposes a novel type of boiler, called a Direct-fired Porous-medium Boiler (DPB). Due to being operated without flue gas heat loss, its thermal efficiency cloud be approximately close to 100%. The steam produced from the proposed boiler; however, is not pure water steam. It is the composite gases of steam and combustion-product-gases. This paper aims at presenting the working concept and reporting the experimental results on the performance of the proposed boiler. The experiments of various operating parameters were performed and collected data were used for the performance analysis. The experimental results demonstrated that the proposed boiler can be operated as well as the conceptual design and then it is promising. It can be possibly further developed to be a high efficiency boiler by means of reducing or suppressing the surface heat loss with better insulator and/or refractory lined.

  20. Cross connecting absorber module inlets of multiple boiler units

    International Nuclear Information System (INIS)

    Cirillo, A.J.; Sperber, P.K.; Belavadi, V.N.; Mukherji, A.

    1991-01-01

    The retrofitting of scrubbers downstream of existing balanced draft boilers is often accomplished by the addition of induced draft (ID) booster fans. By creating a common plenum between the ID fans and the ID booster fans of two or more boiler-absorber trains, absorber module capacity may be shared among multiple boiler units. At Harrison Power Station, three (3) 4,900,000 lb/hour boilers (640 MWe Gross) will be linked through a common plenum. This sharing capability precludes the need to add standby module capacity, thereby saving capital dollars and keeping project critical path schedules, which typically run through absorber procurement and construction, to a minimum. Through damper placement in the ductwork cross connections, unitized boiler-absorber module operation or common plenum operation may be obtained, thus providing both operational flexibility and reliability. Additionally, open plenum operation allows the removal of an absorber unit from service, while keeping its associated boiler on line, thereby precluding 'cold starts' and maintaining overall unit availabilities. As either unitized or common plenum operation is possible with the cross connection, the furnace draft control systems of each boiler must be examined for varying load operation and trip conditions. This paper addresses the means by which to analyze such cross connection operational scenarios while maintaining compliance with furnace flame out safety guidelines, and will discuss the physical design considerations, ramifications and benefits of same, with select emphasis on what is being implemented at the Harrison Power Station

  1. Supercritical boiler material selection using fuzzy analytic network process

    Directory of Open Access Journals (Sweden)

    Saikat Ranjan Maity

    2012-08-01

    Full Text Available The recent development of world is being adversely affected by the scarcity of power and energy. To survive in the next generation, it is thus necessary to explore the non-conventional energy sources and efficiently consume the available sources. For efficient exploitation of the existing energy sources, a great scope lies in the use of Rankin cycle-based thermal power plants. Today, the gross efficiency of Rankin cycle-based thermal power plants is less than 28% which has been increased up to 40% with reheating and regenerative cycles. But, it can be further improved up to 47% by using supercritical power plant technology. Supercritical power plants use supercritical boilers which are able to withstand a very high temperature (650-720˚C and pressure (22.1 MPa while producing superheated steam. The thermal efficiency of a supercritical boiler greatly depends on the material of its different components. The supercritical boiler material should possess high creep rupture strength, high thermal conductivity, low thermal expansion, high specific heat and very high temperature withstandability. This paper considers a list of seven supercritical boiler materials whose performance is evaluated based on seven pivotal criteria. Given the intricacy and difficulty of this supercritical boiler material selection problem having interactions and interdependencies between different criteria, this paper applies fuzzy analytic network process to select the most appropriate material for a supercritical boiler. Rene 41 is the best supercritical boiler material, whereas, Haynes 230 is the worst preferred choice.

  2. Up-date on cyclone combustion and cyclone boilers

    Energy Technology Data Exchange (ETDEWEB)

    Carmo, Felipe Alfaia do; Nogueira, Manoel Fernandes Martins; Rocha, Rodrigo Carnera Castro da; Gazel, Hussein Felix; Martins, Diego Henrique dos Reis [Universidade Federal do Para (UFPA), Belem, PA (Brazil). Campus Universitario Jose da Silveira Netto], E-mails: mfmn@ufpa.br, mfmn@ufpa.br

    2010-07-01

    The boiler concept has been around for more than 70 years, and there are many types available. Boilers provide steam or hot water for industrial and commercial use. The Federal University of Para (UFPA) through the research group EBMA (Energy,Biomass and Environment) has been developing cyclonic furnace with a water wall, a boiler, aiming to use regional timbers (sawdust) and agro-industries residues as fuel to produce steam to be used in industrial processes as well as in power generation,. The use of cyclonic combustion for burning waste instead of burning in a fixed bed is mainly due to two factors efficiency improvement causing a more compact boiler and less risk of explosion, since their process does not generate an accumulation of volatile. Present state-of-art for commercial cyclone boilers has as set up a cyclone combustor with two combustion chambers, in fluid communication, where there ducts for supplying air and fuel directly into the first chamber and for forming a cyclonic flow pattern and a heat exchanger surrounding the second chamber for keeping low combustion temperature in both chambers. This paper shows the results of a literature review about design, construction and operation of cyclonic boilers using solid, liquid or gaseous fuel. This information has been used for the design of a cyclone boiler to be constructed at UFPA for research purposes and its basic concept is presented at the end of this article. (author)

  3. Evaluation of conditions of SNCR in small boilers

    International Nuclear Information System (INIS)

    Kullendorff, A.; Lorentzon, K.

    1996-04-01

    The report describes the first part of a project 'SNCR for small boilers', supported by Vaermeforsk (Thermal Engineering Research Institute), with the purpose of assessing the potential for SNCR in small boilers. Given favourable conditions, the project was to be continued in a second part with the demonstration of a SNCR system in a small boiler (or several boilers). During the base establishment, the temperatures in four locations per boiler, in a couple of horizontal or vertical levels and at 2-3 thermal outputs, were measured. Out of the four locations two showed temperatures mainly within the theoretical temperature window for SNCR. These locations were used during the try-out tests to inject urea and ammonia. The locations and the equipment used during the try-out tests together with existing operation strategies seem to limit the reduction levels to approximately 10-20% at acceptable levels of ammonia slip. The measurements and try-out tests carried out does not provide enough basis for forming any general conclusions concerning SNCR in small boilers. Neither the base establishment nor the try-out tests included any optimisation of the boilers regarding the operation strategy or, for the try-out tests, locations and equipment (drop size, flow shape and direction). Therefore, it is likely to believe that better results can be obtained, given other conditions of operation and using well established SNCR technology, adapted to the circumstances. 2 refs, 27 figs, 5 tabs

  4. 46 CFR 52.20-17 - Opening between boiler and safety valve (modifies PFT-44).

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 2 2010-10-01 2010-10-01 false Opening between boiler and safety valve (modifies PFT-44). 52.20-17 Section 52.20-17 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) MARINE ENGINEERING POWER BOILERS Requirements for Firetube Boilers § 52.20-17 Opening between boiler and safety valve...

  5. 40 CFR 266.110 - Waiver of DRE trial burn for boilers.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 26 2010-07-01 2010-07-01 false Waiver of DRE trial burn for boilers... HAZARDOUS WASTE MANAGEMENT FACILITIES Hazardous Waste Burned in Boilers and Industrial Furnaces § 266.110 Waiver of DRE trial burn for boilers. Boilers that operate under the special requirements of this section...

  6. 9 CFR 91.22 - Protection from heat of boilers and engines.

    Science.gov (United States)

    2010-01-01

    ... 9 Animals and Animal Products 1 2010-01-01 2010-01-01 false Protection from heat of boilers and... Protection from heat of boilers and engines. No animals shall be stowed along the alleyways leading to the engine or boiler rooms unless the sides of said engine or boiler rooms are covered by a tongue and groove...

  7. 46 CFR 91.15-1 - Standards in inspection of hulls, boilers, and machinery.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 4 2010-10-01 2010-10-01 false Standards in inspection of hulls, boilers, and machinery... hulls, boilers, and machinery. In the inspection of hulls, boilers, and machinery of vessels, the..., respecting material and inspection of hulls, boilers, and machinery, and the certificate of classification...

  8. 30 CFR 57.13001 - General requirements for boilers and pressure vessels.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false General requirements for boilers and pressure... NONMETAL MINES Compressed Air and Boilers § 57.13001 General requirements for boilers and pressure vessels. All boilers and pressure vessels shall be constructed, installed, and maintained in accordance with...

  9. 40 CFR 63.7506 - Do any boilers or process heaters have limited requirements?

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 13 2010-07-01 2010-07-01 false Do any boilers or process heaters have..., and Institutional Boilers and Process Heaters General Compliance Requirements § 63.7506 Do any boilers or process heaters have limited requirements? (a) New or reconstructed boilers and process heaters in...

  10. 46 CFR 189.15-1 - Standards in inspection of hulls, boilers, and machinery.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 7 2010-10-01 2010-10-01 false Standards in inspection of hulls, boilers, and machinery... inspection of hulls, boilers, and machinery. In the inspection of hulls, boilers, and machinery of vessels... chapter, respecting material and construction of hulls, boilers, and machinery, and certificate of...

  11. 49 CFR 230.20 - Alteration and repair report for steam locomotive boilers.

    Science.gov (United States)

    2010-10-01

    ... boilers. 230.20 Section 230.20 Transportation Other Regulations Relating to Transportation (Continued... boilers. (a) Alterations. When an alteration is made to a steam locomotive boiler, the steam locomotive... maintained for the life of the boiler. (See appendix B of this part.) (b) Welded and riveted repairs to...

  12. 46 CFR 61.05-5 - Preparation of boilers for inspection and test.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 2 2010-10-01 2010-10-01 false Preparation of boilers for inspection and test. 61.05-5... PERIODIC TESTS AND INSPECTIONS Tests and Inspections of Boilers § 61.05-5 Preparation of boilers for... preparing the boilers for the hydrostatic test, they shall be filled with water at not less than 70 °F. and...

  13. 40 CFR 63.7491 - Are any boilers or process heaters not subject to this subpart?

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 13 2010-07-01 2010-07-01 false Are any boilers or process heaters not..., and Institutional Boilers and Process Heaters What This Subpart Covers § 63.7491 Are any boilers or process heaters not subject to this subpart? The types of boilers and process heaters listed in paragraphs...

  14. 40 CFR 63.7499 - What are the subcategories of boilers and process heaters?

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 13 2010-07-01 2010-07-01 false What are the subcategories of boilers..., and Institutional Boilers and Process Heaters Emission Limits and Work Practice Standards § 63.7499 What are the subcategories of boilers and process heaters? The subcategories of boilers and process...

  15. 46 CFR 71.15-1 - Standards in inspection of hulls, boilers, and machinery.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 3 2010-10-01 2010-10-01 false Standards in inspection of hulls, boilers, and machinery..., boilers, and machinery. In the inspection of hulls, boilers, and machinery of vessels, the standards... and inspection of hulls, boilers, and machinery, and the certificate of classification referring...

  16. 30 CFR 56.13001 - General requirements for boilers and pressure vessels.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false General requirements for boilers and pressure... MINES Compressed Air and Boilers § 56.13001 General requirements for boilers and pressure vessels. All boilers and pressure vessels shall be constructed, installed, and maintained in accordance with the...

  17. Apparatus and method of controlling the thermal performance of an oxygen-fired boiler

    Science.gov (United States)

    Levasseur, Armand A.; Kang, Shin G.; Kenney, James R.; Edberg, Carl D.

    2017-09-05

    Disclosed herein is a method of controlling the operation of an oxy-fired boiler; the method comprising combusting a fuel in a boiler; producing a heat absorption pattern in the boiler; discharging flue gases from the boiler; recycling a portion of the flue gases to the boiler; combining a first oxidant stream with the recycled flue gases to form a combined stream; splitting the combined stream into several fractions; and introducing each fraction of the combined stream to the boiler at different points of entry to the boiler.

  18. Failure Analysis Of Industrial Boiler Pipe

    International Nuclear Information System (INIS)

    Natsir, Muhammad; Soedardjo, B.; Arhatari, Dewi; Andryansyah; Haryanto, Mudi; Triyadi, Ari

    2000-01-01

    Failure analysis of industrial boiler pipe has been done. The tested pipe material is carbon steel SA 178 Grade A refer to specification data which taken from Fertilizer Company. Steps in analysis were ; collection of background operation and material specification, visual inspection, dye penetrant test, radiography test, chemical composition test, hardness test, metallography test. From the test and analysis result, it is shown that the pipe failure caused by erosion and welding was shown porosity and incomplete penetration. The main cause of failure pipe is erosion due to cavitation, which decreases the pipe thickness. Break in pipe thickness can be done due to decreasing in pipe thickness. To anticipate this problem, the ppe will be replaced with new pipe

  19. Model technique for aerodynamic study of boiler furnace

    Energy Technology Data Exchange (ETDEWEB)

    1966-02-01

    The help of the Division was recently sought to improve the heat transfer and reduce the exit gas temperature in a pulverized-fuel-fired boiler at an Australian power station. One approach adopted was to construct from Perspex a 1:20 scale cold-air model of the boiler furnace and to use a flow-visualization technique to study the aerodynamic patterns established when air was introduced through the p.f. burners of the model. The work established good correlations between the behaviour of the model and of the boiler furnace.

  20. Model-based Control of a Bottom Fired Marine Boiler

    DEFF Research Database (Denmark)

    Solberg, Brian; Karstensen, Claus M. S.; Andersen, Palle

    2005-01-01

    This paper focuses on applying model based MIMO control to minimize variations in water level for a specific boiler type. A first principles model is put up. The model is linearized and an LQG controller is designed. Furthermore the benefit of using a steam °ow measurement is compared to a strategy...... relying on estimates of the disturbance. Preliminary tests at the boiler system show that the designed controller is able to control the boiler process. Furthermore it can be concluded that relying on estimates of the steam flow in the control strategy does not decrease the controller performance...

  1. Numerical modelling of a straw-fired grate boiler

    DEFF Research Database (Denmark)

    Kær, Søren Knudsen

    2004-01-01

    The paper presents a computational fluid dynamics (CFD) analysis of a 33 MW straw-fired grate boiler. Combustion on the grate plays akey-role in the analysis of these boilers and in this work a stand-alone code was used to provide inlet conditions for the CFD analysis. Modelpredictions were...... compared with available gas temperature and species concentration measurements showing good agreement. Combustionof biomass in grate-based boilers is often associated with high emission levels and relatively high amounts of unburnt carbon in the fly ash.Based on the CFD analysis, it is suggested that poor...

  2. Vacuum boilers developed heating surfaces technic and economic efficiency evaluation

    Science.gov (United States)

    Slobodina, E. N.; Mikhailov, A. G.; Semenov, B. A.

    2018-01-01

    The vacuum boilers as manufacturing proto types application analysis was carried out, the possible directions for the heating surfaces development are identified with a view to improving the energy efficiency. Economic characteristics to evaluate the vacuum boilers application efficiency (Net Discounted Income (NDI), Internal Rate of Return (IRR), Profitability Index (PI) and Payback Period) are represented. The given type boilers application technic and economic efficiency criteria were established. NDI changing curves depending on the finning coefficient and operating pressure were obtained as a result of the conducted calculation studies.

  3. An optimising controller for Hinkley Point B AGR boilers

    International Nuclear Information System (INIS)

    Wells, C.

    1986-01-01

    The improvements to the control system at Hinkley Point 'B' Power Station has as one of its objectives the provision of a half unit valve controller. This will enable the asymmetry between the boiler half units, which is a feature of current operation, to be reduced. The use of an on-line boiler model in conjunction with this facility will allow the risk to the boilers from corrosion, creep, and vibration to be assessed and held at the minimum attainable value, thereby prolonging plant life whilst maximising output and efficiency. (author)

  4. Model-based Control of a Bottom Fired Marine Boiler

    DEFF Research Database (Denmark)

    Solberg, Brian; Karstensen, Claus M. S.; Andersen, Palle

    This paper focuses on applying model based MIMO control to minimize variations in water level for a specific boiler type. A first principles model is put up. The model is linearized and an LQG controller is designed. Furthermore the benefit of using a steam °ow measurement is compared to a strategy...... relying on estimates of the disturbance. Preliminary tests at the boiler system show that the designed controller is able to control the boiler process. Furthermore it can be concluded that relying on estimates of the steam flow in the control strategy does not decrease the controller performance...

  5. Modelling transition states of a small once-through boiler

    Energy Technology Data Exchange (ETDEWEB)

    Talonpoika, T [Lappeenranta Univ. of Technology (Finland). Dept. of Energy Technology

    1998-12-31

    This article presents a model for the unsteady dynamic behaviour of a once-through counter flow boiler that uses an organic working fluid. The boiler is a compact waste-heat boiler without a furnace and it has a preheater, a vaporiser and a superheater. The relative lengths of the boiler parts vary with the operating conditions since they are all parts of a single tube. The boiler model is presented using a selected example case that uses toluene as the process fluid and flue gas from natural gas combustion as the heat source. The dynamic behaviour of the boiler means transition from the steady initial state towards another steady state that corresponds to the changed process conditions. The solution method chosen is to find such a pressure of the process fluid that the mass of the process fluid in the boiler equals the mass calculated using the mass flows into and out of the boiler during a time step, using the finite difference method. A special method of fast calculation of the thermal properties is used, because most of the calculation time is spent in calculating the fluid properties. The boiler is divided into elements. The values of the thermodynamic properties and mass flows are calculated in the nodes that connect the elements. Dynamic behaviour is limited to the process fluid and tube wall, and the heat source is regarded as to be steady. The elements that connect the preheater to the vaporiser and the vaporiser to the superheater are treated in a special way that takes into account a flexible change from one part to the other. The initial state of the boiler is received from a steady process model that is not a part of the boiler model. The known boundary values that may vary during the dynamic calculation were the inlet temperature and mass flow rates of both the heat source fluid and the process fluid. The dynamic boiler model is analysed for linear and step charges of the entering fluid temperatures and flow rates. The heat source side tests show that

  6. Economical analyses of construction of a biomass boiler house

    International Nuclear Information System (INIS)

    Normak, A.

    2002-01-01

    To reduce the energy costs we can use cheaper fuel to fire our boiler. One of the cheapest fuels is wood biomass. It is very actual issue how to use cheaper wood biomass in heat generation to decrease energy costs and to increase biomass share in our energy balance. Before we decide to build biomass boiler house it is recommendable to analyse the economical situation and work out most profitable, efficient, reliable and ecological boiler plant design on particular conditions. The best way to perform the analyses is to use the economical model presented. It saves our time and gives objective evaluation to the project. (author)

  7. Modelling transition states of a small once-through boiler

    Energy Technology Data Exchange (ETDEWEB)

    Talonpoika, T. [Lappeenranta Univ. of Technology (Finland). Dept. of Energy Technology

    1997-12-31

    This article presents a model for the unsteady dynamic behaviour of a once-through counter flow boiler that uses an organic working fluid. The boiler is a compact waste-heat boiler without a furnace and it has a preheater, a vaporiser and a superheater. The relative lengths of the boiler parts vary with the operating conditions since they are all parts of a single tube. The boiler model is presented using a selected example case that uses toluene as the process fluid and flue gas from natural gas combustion as the heat source. The dynamic behaviour of the boiler means transition from the steady initial state towards another steady state that corresponds to the changed process conditions. The solution method chosen is to find such a pressure of the process fluid that the mass of the process fluid in the boiler equals the mass calculated using the mass flows into and out of the boiler during a time step, using the finite difference method. A special method of fast calculation of the thermal properties is used, because most of the calculation time is spent in calculating the fluid properties. The boiler is divided into elements. The values of the thermodynamic properties and mass flows are calculated in the nodes that connect the elements. Dynamic behaviour is limited to the process fluid and tube wall, and the heat source is regarded as to be steady. The elements that connect the preheater to the vaporiser and the vaporiser to the superheater are treated in a special way that takes into account a flexible change from one part to the other. The initial state of the boiler is received from a steady process model that is not a part of the boiler model. The known boundary values that may vary during the dynamic calculation were the inlet temperature and mass flow rates of both the heat source fluid and the process fluid. The dynamic boiler model is analysed for linear and step charges of the entering fluid temperatures and flow rates. The heat source side tests show that

  8. Maintenance of immersion ultrasonic testing on the water tube boiler

    International Nuclear Information System (INIS)

    Ishiyama, Toru; Kawasaki, Ichio; Miura, Hirohito

    2014-01-01

    There are 4-boiler in nuclear fuel cycle engineering laboratories (NCL). These boilers have been operated in the long term over 20 years. One of them, the leakage of boiler water was found at one of the generating tubes, and 2 adjoining generating tubes were corroded in Dec, 2011. These generating tubes were investigated by immersion ultrasonic testing (UT) for measure thickness of the tube. As a result, thinner tube was found in a part of a bend and near the water drum. These parts are covered with sulfide deposit, it seems that the generating tubes were corroded by sulfide. (author)

  9. Orion Ammonia Boiler System Preflight Test Preparations

    Science.gov (United States)

    Levitt, Julia L.

    2017-01-01

    The Environmental Controls and Life Support Systems (ECLSS) branch at Kennedy Space Center (KSC) is currently undergoing preparations for ground testing of the Orion Multi-Purpose Crew Vehicle (MPCV) to prepare its subsystems for EM-1 (Exploration Mission-1). EM-1, Orions second unmanned flight, is a three-week long lunar mission during which the vehicle will complete a 6-day retrograde lunar orbit before returning to Earth. This paper focuses on the work done during the authors 16-week internship with the Mechanical Engineering Branch of KSCs Engineering Directorate. The authors project involved assisting with the preparations for testing the Orion MPCVs ammonia boiler system. The purpose of the ammonia boiler system is to keep the spacecraft sufficiently cool during the reentry portion of its mission, from service module (SM) separation to post-landing. This system is critical for keeping both the spacecraft (avionics and electronics) and crew alive during reentry, thus a successful test of the system is essential to the success of EM-1. XXXX The author was able to draft a detailed outline of the procedure for the ammonia system functional test. More work will need to be done on the vehicle power-up and power-down portions of the procedure, but the ammonia system testing portion of the procedure is thorough and includes vehicle test configurations, vehicle commands, and GSE. The author was able to compile a substantial list of questions regarding the ammonia system functional test with the help of her mentors. A significant number of these questions were answered in the teleconferences with Lockheed Martin.

  10. New black liquor combustion characteristics II; Mustalipeaen uudet poltto-ominaisuudet II

    Energy Technology Data Exchange (ETDEWEB)

    Hupa, M.; Backman, R.; Bostroem, S.; Forssen, M.; Uusikartano, T. [Aabo Akademi, Turku (Finland)

    1996-12-01

    In an earlier study (LIEKKI 2, Y 17), the combustion characteristics of 17 liquors of different origin were studied by four laboratory tests. These tests were (1) single droplet burning, (2) single droplet pyrolysis, (3) pressurized gasification, and (4) calculation of melting properties of inorganic carryover particles. The study showed that there are big differences between liquors of different origin. These differences strongly affect the combustion properties, i.e. pyrolysis and burning times, swelling, and fouling tendency of heat transfer surfaces. The objective for the present research project was to investigate the reasons why some properties affect the combustion behavior more than others. The project is partly complementary to the previous study, partly a more detailed study of some of the phenomena observed earlier. The work constitutes of the following studies: (1) further study of several more liquors by the same methods, (2) pyrolysis swelling in inert gas (N{sub 2}) at two temperatures, 700 deg C and 900 deg C, (3) effect of heat treatment black liquors, (4) effect of addition of sodium compounds to a virgin black liquor, (5) data treatment and correlations, (6) nitrogen oxide formation tendency. (author)

  11. Development of blueberry liquor: influence of distillate, sweetener and fruit quantity.

    Science.gov (United States)

    Caldeira, Ilda; Lopes, Daniel; Delgado, Teresa; Canas, Sara; Anjos, Ofélia

    2018-02-01

    In this work different formulations of blueberry liquor were tested and characterised based on their physico-chemical and sensory characteristics. Three factors were evaluated: the distillate used to produce the liquor (wine spirit or grape marc spirit); the sweetener (white sugar or honey) and the fruit quantity (two doses). For each liquor, pH, total acidity, dry soluble solids content, dry extract, alcoholic strength, reducing sugars, colour intensity, methanol content, acetaldehyde and fusel alcohols were determined. Sensory tests were carried out with a trained panel. The three factors studied significantly influenced the physico-chemical features of the liquors, being the quantity of fruit the most discriminating factor, except for the volatile compounds which were mainly influenced by the distillate. As regards the sensory analysis, it was found that the most appreciated liquor was that prepared with wine spirit, sugar and a lower dose of blueberry, and the less appreciated formulation was the one made with grape marc spirit, honey and a lower quantity of blueberry. © 2017 Society of Chemical Industry. © 2017 Society of Chemical Industry.

  12. Bio-refinery system in a pulp mill for methanol production with comparison of pressurized black liquor gasification and dry gasification using direct causticization

    International Nuclear Information System (INIS)

    Naqvi, Muhammad; Yan, Jinyue; Dahlquist, Erik

    2012-01-01

    Black liquor gasification (BLG) for bio-fuel or electricity production at the modern pulp mills is a field in continuous evolution and the efforts are considerably driven by the climate change, fuel security, and renewable energy. This paper evaluates and compares two BLG systems for methanol production: (i) oxygen blown pressurized thermal BLG; and (ii) dry BLG with direct causticization, which have been regarded as the most potential technology candidates for the future deployment. A key objective is to assess integration possibilities of BLG technologies with the reference Kraft pulp mill producing 1000 air dried tonnes (ADt) pulp/day replacing conventional recovery cycle. The study was performed to compare the systems’ performance in terms of potential methanol production, energy efficiency, and potential CO 2 reductions. The results indicate larger potential of black liquor conversion to methanol from the pressurized BLG system (about 77 million tonnes/year of methanol) than the dry BLG system (about 30 million tonnes/year of methanol) utilizing identical amount of black liquor available worldwide (220 million tDS/year). The potential CO 2 emissions reduction from the transport sector is substantially higher in pressurized BLG system (117 million tonnes/year CO 2 reductions) as compared to dry BLG system (45 million tonnes/year CO 2 reductions). However, the dry BLG system with direct causticization shows better results when considering consequences of additional biomass import. In addition, comparison of methanol production via BLG with other bio-refinery products, e.g. hydrogen, dimethyl ether (DME) and bio-methane, has also been discussed.

  13. Smooth Surfaces: A review of current and planned smooth surface technologies for fouling resistance in boiler

    Energy Technology Data Exchange (ETDEWEB)

    Corkery, Robert; Baefver, Linda; Davidsson, Kent; Feiler, Adam

    2012-02-15

    Here we have described the basics of boilers, fuels, combustion, flue gas composition and mechanisms of deposition. We have reviewed coating technologies for boiler tubes, including their materials compositions, nano structures and performances. The surface forces in boilers, in particular those relevant to formation of unwanted deposits in boilers have also been reviewed, and some comparative calculations have been included to indicate the procedures needed for further study. Finally practical recommendations on the important considerations in minimizing deposition on boiler surfaces are made

  14. Amnioinfusion for meconium-stained liquor in labour.

    Science.gov (United States)

    Hofmeyr, G Justus; Xu, Hairong; Eke, Ahizechukwu C

    2014-01-23

    Amnioinfusion is thought to dilute meconium present in the amniotic fluid and so reduce the risk of meconium aspiration. To assess the effects of amnioinfusion for meconium-stained liquor on perinatal outcome. We searched the Cochrane Pregnancy and Childbirth Group's Trials Register (1 December 2013). Randomised trials comparing amnioinfusion with no amnioinfusion for women in labour with moderate or thick meconium staining of the amniotic fluid. Three review authors independently assessed eligibility and trial quality, and extracted data. Fourteen studies of variable quality (4435 women) are included.Subgroup analysis was performed for studies from settings with limited facilities to monitor the baby's condition during labour and intervene effectively, and settings with standard peripartum surveillance.Settings with standard peripartum surveillance: there was considerable heterogeneity for several outcomes. There was no significant reduction in the primary outcomes meconium aspiration syndrome, perinatal death or severe morbidity, and maternal death or severe morbidity. There was a reduction in caesarean sections (CSs) for fetal distress but not overall. Meconium below the vocal cords diagnosed by laryngoscopy was reduced, as was neonatal ventilation or neonatal intensive care unit admission, but there was no significant reduction in perinatal deaths or other morbidity. Planned sensitivity analysis excluding trials with greater risk of bias resulted in an absence of benefits for any of the outcomes studied.Settings with limited peripartum surveillance: three studies were included. In the amnioinfusion group there was a reduction in CS for fetal distress and overall; meconium aspiration syndrome (three studies, 1144 women; risk ratio (RR) 0.17, 95% confidence interval (CI) 0.05 to 0.52); perinatal mortality (three studies, 1151 women; RR 0.24, 95% CI 0.11 to 0.53) and neonatal ventilation or neonatal intensive care unit admission. In one of the studies, meconium

  15. GREENHOUSE GAS EMISSIONS CONTROL BY OXYGEN FIRING IN CIRCULATING FLUIDIZED BED BOILERS

    Energy Technology Data Exchange (ETDEWEB)

    Nsakala ya Nsakala; Gregory N. Liljedahl

    2003-05-15

    Given that fossil fuel fired power plants are among the largest and most concentrated producers of CO{sub 2} emissions, recovery and sequestration of CO{sub 2} from the flue gas of such plants has been identified as one of the primary means for reducing anthropogenic CO{sub 2} emissions. In this study, ALSTOM Power Inc. (ALSTOM) has investigated several coal fired power plant configurations designed to capture CO{sub 2} from effluent gas streams for use or sequestration. Burning fossil fuels in mixtures of oxygen and recirculated flue gas (made principally of CO{sub 2}) essentially eliminates the presence of atmospheric nitrogen in the flue gas. The resulting flue gas is comprised primarily of CO{sub 2}. Oxygen firing in utility scale Pulverized Coal (PC) fired boilers has been shown to be a more economical method for CO{sub 2} capture than amine scrubbing (Bozzuto, et al., 2001). Additionally, oxygen firing in Circulating Fluid Bed Boilers (CFB's) can be more economical than in PC or Stoker firing, because recirculated gas flow can be reduced significantly. Oxygen-fired PC and Stoker units require large quantities of recirculated flue gas to maintain acceptable furnace temperatures. Oxygen-fired CFB units, on the other hand, can accomplish this by additional cooling of recirculated solids. The reduced recirculated gas flow with CFB units results in significant Boiler Island cost savings. Additionally, ALSTOM has identified several advanced/novel plant configurations, which improve the efficiency and cost of the CO{sub 2} product cleanup and compression process. These advanced/novel concepts require long development efforts. An economic analysis indicates that the proposed oxygen-firing technology in circulating fluidized boilers could be developed and deployed economically in the near future in enhanced oil recovery (EOR) applications or enhanced gas recovery (EGR), such as coal bed methane recovery. ALSTOM received a Cooperative Agreement from the US

  16. Numerical simulation of a biomass fired grate boiler

    DEFF Research Database (Denmark)

    Yin, Chungen; Rosendahl, Lasse; Kær, Søren Knudsen

    2006-01-01

    Computational fluid dynamic (CFD) analysis of the thermal flow in the combustion furnace of a biomass-fired grate boiler provides crucial insight into the boiler's performance. Quite a few factors play important roles in a general CFD analysis, such as grid, models, discretization scheme and so on....... For a grate boiler, the modeling the interaction of the fuel bed and the gas phase above the bed is also essential. Much effort can be found in literature on developing bed models whose results are introduced into CFD simulations of freeboard as inlet conditions. This paper presents a CFD analysis...... of the largest biomass-fired grate boiler in Denmark. The focus of this paper is to study how significantly an accurate bed model can affect overall CFD results, i.e., how necessarily it is to develop an accurate bed model in terms of the reliability of CFD results. The ultimate purpose of the study is to obtain...

  17. Criteria of choosing building structures for rooftop boiler rooms

    Directory of Open Access Journals (Sweden)

    Plotnikov Artyom

    2018-01-01

    Full Text Available The paper investigates parameters of noise and vibration distribution in the territory of residential area depending on the structural materials and power of independent heat supply systems. Rooftop boiler rooms are decentralized heat supply systems in buildings. Today, residential areas are strongly affected by noise and vibrations. Adverse effects are isolated by buildings materials, protective shields and floating floors. Rooftop boiler rooms located in Tyumen city were investigated within this research. Structures of rooftop boiler rooms were analyzed. Acoustic analysis results and the parameters of equivalent continuous sound level are presented. An option for improvement of rooftop boiler rooms structures is suggested. Comparison of capital investments in construction and installation activities is carried out. Conclusion on capital investments required for noise protection is made.

  18. Emissions from Power Plant and Industrial Boiler Sector

    Data.gov (United States)

    U.S. Environmental Protection Agency — This asset provides hourly data on SO2, NOx, and CO2 emissions; gross load, steam load, and heat input; from electricity generation units and industrial boilers from...

  19. Knowledge based system for fouling assessment of power plant boiler

    International Nuclear Information System (INIS)

    Afgan, N.H.; He, X.; Carvalho, M.G.; Azevedo, J.L.T.

    1999-01-01

    The paper presents the design of an expert system for fouling assessment in power plant boilers. It is an on-line expert system based on selected criteria for the fouling assessment. Using criteria for fouling assessment based on 'clean' and 'not-clean' radiation heat flux measurements, the diagnostic variable are defined for the boiler heat transfer surface. The development of the prototype knowledge-based system for fouling assessment in power plants boiler comprise the integrations of the elements including knowledge base, inference procedure and prototype configuration. Demonstration of the prototype knowledge-based system for fouling assessment was performed on the Sines power plant. It is a 300 MW coal fired power plant. 12 fields are used with 3 on each side of boiler

  20. Numerical investigation of ash deposition in straw-fired boilers

    DEFF Research Database (Denmark)

    Kær, Søren Knudsen

    in the design phase of straw-fired boilers. Some of the primary model outputs include improved heat transfer rate predictions and detailed information about local deposit formation rates. This information is essential when boiler availability and efficiency is to be estimated. A stand-alone program has been...... accumulation rates encountered during straw combustion in grate-fired boilers. The sub-models have been based on information about the combustion and deposition properties of straw gathered from the literature and combined into a single Computational Fluid Dynamics (CFD) based analysis tool which can aid...... transfer mechanisms have a pronounced influence on the combustion pattern. The combined set of sub-models has been evaluated using the straw-fired boiler at Masnedø CHP plant as a test case. The predicted grate combustion and KCl release patterns are in qualitative agreement with experimental findings...

  1. Boiler for combustion fuel in a fluidized bed

    Directory of Open Access Journals (Sweden)

    Laković Mirjana S.

    2015-01-01

    Full Text Available Fuel combustion in fluidized bed combustion is a process that is current and which every day gives more attention and there are many studies that have been closely associated with this technology. This combustion technology is widespread and constantly improving the range of benefits it provides primarily due to reduced emissions. This paper presents the boilers for combustion in a fluidized bed, whit characteristics and advantages. Also is shown the development of this type of boilers in Republic of Serbia. In this paper is explained the concept of fluidized bed combustion. Boilers for this type of combustion can be improved and thereby increase their efficiency level. More detailed characteristics are given for boilers with bubbling and circulating fluidized bed as well as their mutual comparison.

  2. Energy efficiency in boilers; Eficiencia energetica em caldeiras

    Energy Technology Data Exchange (ETDEWEB)

    Ponte, Ricardo Silva The [Universidade Federal do Ceara (UFCE), Fortaleza, CE (Brazil). Dept. de Engenharia Eletrica], email: ricthe@dee.ufc.br; Barbosa, Marcos Antonio Pinheiro; Rufino, Maria da Gracas [Universidade de Fortaleza (UNIFOR), CE (Brazil). Dept. de Engenharia Eletrica], emails: marcos_apb@unifor.br, gsrufino@unifor.br

    2010-07-01

    The boiler is vapor generator equipment that has been widely used in industrial milieu as in electric energy generation in thermoelectric plants. Since their first conception, the boilers have been changed in order to provide security and energetic efficiency. They can present high losses of energy if they don't be operated according to some criteria. A considerable part of boilers operation cost include fuel expenses. So, the adoption of effective steps in order to reduce fuel consumption is important to industry economy, besides it brings environmental benefits through the reduction of pollution liberation. The present article has the objective of emphasizing the effective steps for the economy of energy in boilers, such as, the regulation of combustion; the control of soot and incrustations; the installation of economizers, air heaters and super heaters; the reduction in purges and reintroduction of condensed steam. (author)

  3. Wood-Fired Boiler System Evaluation at Fort Stewart, GA

    National Research Council Canada - National Science Library

    Potts, Noel

    2002-01-01

    Part of the plan to modernize the central energy plant (CEP) at Fort Stewart, GA is focused on the installations wood-fired boiler, which provides steam for heating, cooling, and domestic hot water. The U.S...

  4. Seismic model of the nuclear boiler SPX2

    International Nuclear Information System (INIS)

    Christodoulou, K.

    1982-01-01

    A model of the nuclear boiler SPX2 is proposed in this paper enabling to carry out comparative calculations on the response to seismic effects. The calculations are made in CISE and SEPTEN departments of Electricite de France [fr

  5. High gradient magnetic filters for boiler water treatment

    International Nuclear Information System (INIS)

    Harland, J.R.; Nichols, R.M.

    1977-01-01

    Heavy metal oxide suspended solids in those steam condensates recycled to the boilers produce buildup within the boiler tubes which can lead to unequal and reduced heat transfer efficiency, and indirectly, to boiler tube failures. Recommended reductions in such suspended solids in feedwater to the economizers of modern high pressure boilers to levels of under 10 ppb have been published. The industrially-available SALA-HGMF magnetic filter has achieved these desired suspended solids levels in treating steam condensates. The high gradient magnetic filter has been shown in pilot tests to achieve and even exceed the recommended low level suspended solids in a practical and efficient industrial system. Such electromagnetic filters, when combined with good system chemistry, have achieved low single number parts per billion levels of several heavy metals with very high single-pass efficiencies

  6. An acoustic technique for the determination of liquor level in tanks

    International Nuclear Information System (INIS)

    Watson, J.; Jones, T.L.

    1980-02-01

    The design, development and application of a prototype suitable for the measurement of liquor levels in tanks is described. The technique involves directing an acoustic pulse down a constraining tube to the liquor surface and measuring the time of return of the reflected pulse. Using the equipment it is possible to determine the position of a solid surface with a total error of less than 1 mm. The prototype instrument was used to measure the volume of liquors contained in rectangular slab tanks used for accountancy purposes at Dounreay Nuclear Power Development Establishment. The total error obtained in an individual measurement of volume was less than 0.2 litres (95% confidence limits). The instrument may be used as a replacement for a Pneumercator system in existing installations. (author)

  7. Exploration on trickle leaching of uranium ore by refreshed liquor of bacterial oxidation

    International Nuclear Information System (INIS)

    Chen Shian; Huang Xiangfu; Fan Baotuan

    1995-01-01

    The paper describes the adaptation of the domesticated thiobacillus ferroxidans to the trickle leaching conditions of uranium ore. When the bacterial leaching liquor through multiple cycles of oxidation and regeneration was used to return to the trickle leaching, the following results were obtained: the extraction rate was more than 95%, the acid consumption was saved by 30%, and the consumed 2.0% pyrolusite (MnO 2 40%) was eliminated. The following problems are discussed: the basic principle, process and some factors influencing the process of the trickle leaching of uranium ore using regenerated liquor of bacterial oxidation, counter-current trickle leaching mode, oxidation and regeneration techniques of bacterial leaching liquor and other technological problems on the process of uranium extraction by thiobacillus ferroxidans

  8. Recovery of uranium from wet process by the chloridic leaching of phosphate rocks

    International Nuclear Information System (INIS)

    Santana, A.O.; Paula, H.C.B.; Dantas, C.C.

    1984-01-01

    Uranium was recovered from chloridic leach liquor of phosphate rocks by solvent extraction on a laboratory scale. The extractor system is a mixture of di-(2-ethylhexyl) phosphoric acid (D 2 EHPA) and tributyl-phosphate (TBP) in a varsol diluent. The uranium concentration is 150 ppm in the rocks and 12 ppm in the leach liquor. The phosphate rocks are leached on a semi-industrial scale for dicalcium phosphate production. The recovery process comprises the following steps: extraction, reextraction, iron removal and uranium precipitation. (orig./EF)

  9. Recovery of uranium from wet process by the chloridic leaching of phosphate rocks

    Energy Technology Data Exchange (ETDEWEB)

    Santana, A O; Paula, H C.B.; Dantas, C C

    1984-03-01

    Uranium was recovered from chloridic leach liquor of phosphate rocks by solvent extraction on a laboratory scale. The extractor system is a mixture of di-(2-ethylhexyl) phosphoric acid (D/sub 2/EHPA) and tributyl-phosphate (TBP) in a varsol diluent. The uranium concentration is 150 ppm in the rocks and 12 ppm in the leach liquor. The phosphate rocks are leached on a semi-industrial scale for dicalcium phosphate production. The recovery process comprises the following steps: extraction, reextraction, iron removal and uranium precipitation.

  10. Installations of SNCR on bark-fired boilers

    International Nuclear Information System (INIS)

    Hjalmarsson, A.K.; Hedin, K.; Andersson, Lars

    1997-01-01

    Experience has been collected from the twelve bark-fired boilers in Sweden with selective non catalytic reduction (SNCR) installations to reduce emissions of nitrogen oxides. Most of the boilers have slope grates, but there are also two boilers with cyclone ovens and two fluidized bed boilers. In addition to oil there are also possibilities to burn other fuel types in most boilers, such as sludge from different parts of the pulp and paper mills, saw dust and wood chips. The SNCR installations seems in general to be of simple design. In most installations the injection nozzles are located in existing holes in the boiler walls. The availability is reported to be good from several of the SNCR installations. There has been tube leakage in several boilers. The urea system has resulted in corrosion and in clogging of one oil burner. This incident has resulted in a decision not to use SNCR system with the present design of the system. The fuel has also caused operational problems with the SNCR system in several of the installations due to variations in the moisture content and often high moisture content in bark and sludge, causing temperature variations. The availability is presented to be high for the SNCR system at several of the plants, in two of them about 90 %. The results in NO x reduction vary between the installations depending on boiler, fuel and operation. The emissions are between 45 and 100 mg NO 2 /MJ fuel input and the NO x reduction rates are in most installations between 30 and 40 %, the lowest 20 and the highest 70 %. 13 figs, 3 tabs

  11. [Emission characteristics of fine particles from grate firing boilers].

    Science.gov (United States)

    Wang, Shu-Xiao; Zhao, Xiu-Juan; Li, Xing-Hua; Wei, Wei; Hao, Ji-Ming

    2009-04-15

    Grate firing boilers are the main type of Chinese industrial boilers, which accounts for 85% of the industrial boilers and is one of the most important emission sources of primary air pollutants in China. In this study, five boilers in three cities were selected and tested to measure the emission characteristics of PM2.5, and gaseous pollutants were applied by a compact dilution sampling system, which was developed for this field study. Results showed that particles mass size distributions for the five industrial boilers presented single peak or double peak, former peaks near 0.14 microm and the later peaks after 1.0 microm; the cyclone dust remover and wet scrubber dust remover had effective removal efficiencies not only to PM2.5, but also to PM1.0; and under the condition of same control techniques, grate firing boiler with high capacity has less PM2.5 emission than the boiler with low capacity. In the PM2.5 collected from flue gases, SO4(2-) was the most abundant ion, accounted for 20%-40% of the PM2.5; and C was the most abundant element (7.5%-31.8%), followed by S (8.4%-18.7%). Carbon balance method was applied to calculate the emission factors of these pollutants. The emission factors of PM2.5, NO, and SO2 were in the range of 0.046-0.486 g x kg(-1), 1.63-2.47 g x kg(-1), 1.35-9.95 g x kg(-1) respectively. The results are useful for the emission inventory development of industrial boilers and the source analysis of PM2.5 in atmospheric environment.

  12. AUTOMATIC CONTROL SYSTEM OF THE DRUM BOILER SUPERHEATED STEAM TEMPERATURE.

    Directory of Open Access Journals (Sweden)

    Juravliov A.A.

    2006-04-01

    Full Text Available The control system of the temperature of the superheated steam of the drum boiler is examined. Main features of the system are the PI-controller in the external control loop and introduction of the functional component of the error signal of the external control loop with the negative feedback of the error signal between the prescribed value of steam flowrate and the signal of the steam flowrate in the exit of the boiler in the internal control loop.

  13. Brief introduction of GEF efficient industrial boiler project in China

    Energy Technology Data Exchange (ETDEWEB)

    Meijian, T.

    1996-12-31

    The present situation of installed industrial boilers, their efficiency and environmental impact are assessed. And the factors contribute to the low efficiency and serious pollution are summarized. Based on WB-assisted GEF project, {open_quotes}Efficient Industrial Boiler Project{close_quotes} aimed at CO{sub 2} mitigation in China, a series of effective measures to bring the GHG emission under control are addressed, in technology, system performance, and operation management aspects.

  14. The ASME Boiler and Pressure Vessel Code: overview

    International Nuclear Information System (INIS)

    Farr, J.R.

    1987-01-01

    To become familiar with the Boiler and Pressure Vessel Code of the American Society of Mechanical Engineers, it is necessary to understand the history, organization, and operation of the Boiler Code Committee as well as to become familiar with the important aspects of each Section of the Code. This chapter will review the background and contents of the Code as well as give a review of the salient contents of most sections. (author)

  15. Electric boilers for nuclear power plant in Liebstadt

    International Nuclear Information System (INIS)

    Anon.

    1977-01-01

    A type of electric boiler, two of which are to be supplied to the Liebstadt nuclear power plant by Sulzer, is described. They are to be used for start-up and as reserve for the normal steam supply. The mode of operation is that feed water is sprayed into a high tension electrode such that the falling water conducts the current to the earthed electrode. This type of boiler presents advantages in space requrements and enviromental factors. (JIW)

  16. Electric boilers for nuclear power plant in Liebstadt

    Energy Technology Data Exchange (ETDEWEB)

    1977-11-29

    A type of electric boiler, two of which are to be supplied to the Liebstadt nuclear power plant by Sulzer, is described. They are to be used for start-up and as reserve for the normal steam supply. The mode of operation is that feedwater is sprayed into a high tension electrode such that the falling water conducts the current to the earthed electrode. This type of boiler presents advantages in space requrements and enviromental factors.

  17. Numerical modelling of a straw-fired grate boiler

    DEFF Research Database (Denmark)

    Kær, Søren Knudsen

    2004-01-01

    The paper presents a computational fluid dynamics (CFD) analysis of a 33 MW straw-fired grate boiler. Combustion on the grate plays akey-role in the analysis of these boilers and in this work a stand-alone code was used to provide inlet conditions for the CFD analysis. Modelpredictions were compa...... mixing in the furnace is a key issue leading to these problems. q 2003 Elsevier Ltd. All rights reserved....

  18. Fracture analysis of tube boiler for physical explosion accident.

    Science.gov (United States)

    Kim, Eui Soo

    2017-09-01

    Material and failure analysis techniques are key tools for determining causation in case of explosive and bursting accident result from material and process defect of product in the field of forensic science. The boiler rupture generated by defect of the welding division, corrosion, overheating and degradation of the material have devastating power. If weak division of boiler burner is fractured by internal pressure, saturated vapor and water is vaporized suddenly. At that time, volume of the saturated vapor and water increases up to thousands of volume. This failure of boiler burner can lead to a fatal disaster. In order to prevent an explosion and of the boiler, it is critical to introduce a systematic investigation and prevention measures in advance. In this research, the cause of boiler failure is investigated through forensic engineering method. Specifically, the failure mechanism will be identified by fractography using scanning electron microscopes (SEM) and Optical Microscopes (OM) and mechanical characterizations. This paper presents a failure analysis of household welding joints for the water tank of a household boiler burner. Visual inspection was performed to find out the characteristics of the fracture of the as-received material. Also, the micro-structural changes such as grain growth and carbide coarsening were examined by optical microscope. Detailed studies of fracture surfaces were made to find out the crack propagation on the weld joint of a boiler burner. It was concluded that the rupture may be caused by overheating induced by insufficient water on the boiler, and it could be accelerated by the metal temperature increase. Copyright © 2017 Elsevier B.V. All rights reserved.

  19. Precipitation of uranium peroxide from the leach liquor of uranium ores

    International Nuclear Information System (INIS)

    Gao Xizhen; Lin Sirong; Guo Erhua; Lu Shijie

    1995-06-01

    A chemical precipitation process of recovering uranium from the leach liquor of uranium ores was investigated. The process primarily includes the precipitation of iron with lime, the preprocessing of the slurry of iron hydroxides and the precipitation of uranium with H 2 O 2 . The leach liquor is neutralized by lime milk to pH 3.7 to precipitate the iron hydroxides which after flocculation and settle is separated out and preprocessed at 170 degree C in an autoclave. H 2 O 2 is then used to precipitate uranium in the leach liquor free of iron, and the pH of process for uranium precipitation adjusted by adding MgO slurry to 3.5. The barren solution can be used to wash the filter cakes of leach tailing. The precipitated slurry of iron hydroxides after being preprocessed is recycled to leaching processes for recovering uranium in it. This treatment can not only avoid the filtering of the slurry of iron hydroxides, but also prevent the iron precipitate from redissolving and consequently the increase of iron concentration in the leach liquor. The results of the investigation indicate that lime, H 2 O 2 and MgO are the main chemical reagents used to obtain the uranium peroxide product containing over 65% uranium from the leach liquor, and they also do not cause environmental pollution. In accordance with the uranium content in the liquor, the consumption of chemical reagent for H 2 O 2 (30%) and MgO are 0.95 kg/kgU and 0.169 kg/kgU, respectively. (1 fig., 8 tabs., 7 refs.)

  20. Engineering study: disposition of terminal liquors for interim storage. [Eight alternative processes

    Energy Technology Data Exchange (ETDEWEB)

    Metz, W.P.; Ogren, W.E.

    1975-02-01

    Eight alternative processes were chosen as being technologically feasible within the time frame dictated by budgeting procedures and terminal liquor availability. Solidified waste products acceptable for single-shell tank storage were assumed to be placed in available single-shell tanks. Double-shell tanks were used only for the more mobile terminal liquors or semi-solid mush products. The mush, chemical neutralization, and clay in-tank processes offer potential savings of tens of millions of dollars over double-shell tank storage of terminal liquors. In order to achieve this cost savings, the process development and demonstration must be completed prior to the beginning of double-shell tank construction (Dec. 1976) expected to be funded from a fiscal year 1977 line item. Budgeting for these additional double-shell tanks must proceed since the processing options discussed here are not yet available and may not prove to be available at the required time. This study indicates the following topics for additional study: Process technology development to achieve interim storage of terminal liquor products receives the greatest emphasis as a means of reducing capital expenditures. Interim storage product criteria, waste inventory, and conversion to final form require definition to allow comparison of the alternatives for disposition of terminal liquors. The pseudotechnical nature of product acceptability criteria is important to the evaluation of the partial neutralization and aluminum removal alternatives. More accurate estimates of terminal liquor quantity and composition are required to give a sound technical basis for choosing the appropriate processing alternative. Retrieval and reprocessing operations may affect the comparisons presented by this study. (DLC)