Lipid-based liquid biofuels from autotrophic microalgae: energetic and environmental performance

NARCIS (Netherlands)

Reijnders, L.

2013-01-01

Commercial cultivation of autotrophic microalgae for food production dates back to the 1950s. Autotrophic microalgae have also been proposed as a source for lipid-based liquid biofuels. As yet, there is no commercial production of such biofuels and estimated near-term prices are far in excess of

Stagnating liquid biofuel developments in Russia: Present status andfuture perspectives

International Nuclear Information System (INIS)

Pristupa, Alexey O.; Mol, Arthur P.J.; Oosterveer, Peter

2010-01-01

It is widely acknowledged that Russia possesses enormous biomass resources (). Its vast areas devoted to agricultural production and plentiful timber resources suggest good prospects for the development of liquid biofuel production. However, no significant advances in this direction have been reported till now. None of the numerous investment projects announced at the heydays of biofuel excitement in Russia (2006-2008) are at the moment commercially operating. There are no specialised plants for the production of bioethanol and biodiesel in Russia. Little is known of the reasons for this discrepancy between biofuel potential and actual development. In investigating this discrepancy, this article analyses national developments and investigates local dynamics through a case-study in the Omsk region. It is found that the reasons for this discrepancy are not related to technological incapabilities, but are to be found in the low policy and institutional priority given to non-fossil fuel exploitation and lack of market opportunities. Sprouts of second generation liquid biofuel technologies can be identified within the state system, but it remains to be seen how strong and how long these will be supported by the Russian state.

The potential of liquid biofuels in France

International Nuclear Information System (INIS)

Poitrat, Etienne

1999-01-01

The objective fixed by the European Commission in 1995 was that 5% of the fuel used for transport in Fance should be produced from renewable energy by 2005. As opposed to some other European countries, there is no environmental tax on fossil fuels in France, but the Government has agreed to a tax incentive system on biofuels. Experimental work on liquid biofuels as a transport fuel started in France in the early 80's, but the use of biofuels on a commercial basis really started to develop when the setaside rules and tax incentives came into force in 1991. Out of the two routes originally considered for development; bioethanol and its ETBE derivative, and vegetable oils and their methyl ester derivatives, priority has now been given to: ETBE produced from sugar beet and wheat and now from sub-products of starch industry, which are widely grown in France; ETBE is blended with gasoline for use in spark ignition engines. Production of wheat and beet for energy purposes is very similar to food production. In France, ethanol produce from sugar beet is a traditional industry; this was the first route to be developed. The results of a life cycle analysis made for ETBE produce from sugar beet will be given, showing advantages and limitations. Alcohol produced from wheat is a more recent activity; two industrial plants have been built since beginning of the 90's and other projects are planned like for example a production from starch industry. RME (rapeseed methyl ester) for use in diesel engines at various blend rates. Vegetable oils or their derivatives such as esters can be used directly in diesel engines. Pure, filtered and degummed oils can be used in pre-chamber engines. Relatively advanced knowledge has now been gained about esters; because their characteristics are very similar to those of conventional diesel fuel, they are considered suitable for use in direct injection diesel engines without engine modification. In France, methyl ester is at present produced mainly

Biofuels securing the planet's future energy needs

Energy Technology Data Exchange (ETDEWEB)

Demirbas, Ayhan [Sila Science, Univ. Mah, Mekan Sok No: 24, Trabzon (Turkey)

2009-09-15

The biofuels include bioethanol, biobutanol, biodiesel, vegetable oils, biomethanol, pyrolysis oils, biogas, and biohydrogen. There are two global biomass based liquid transportation fuels that might replace gasoline and diesel fuel. These are bioethanol and biodiesel. World production of biofuel was about 68 billion L in 2007. The primary feedstocks of bioethanol are sugarcane and corn. Bioethanol is a gasoline additive/substitute. Bioethanol is by far the most widely used biofuel for transportation worldwide. About 60% of global bioethanol production comes from sugarcane and 40% from other crops. Biodiesel refers to a diesel-equivalent mono alkyl ester based oxygenated fuel. Biodiesel production using inedible vegetable oil, waste oil and grease has become more attractive recently. The economic performance of a biodiesel plant can be determined once certain factors are identified, such as plant capacity, process technology, raw material cost and chemical costs. The central policy of biofuel concerns job creation, greater efficiency in the general business environment, and protection of the environment. (author)

Microwave-assisted pyrolysis of biomass for liquid biofuels production

DEFF Research Database (Denmark)

Yin, Chungen

2012-01-01

Production of 2nd-generation biofuels from biomass residues and waste feedstock is gaining great concerns worldwide. Pyrolysis, a thermochemical conversion process involving rapid heating of feedstock under oxygen-absent condition to moderate temperature and rapid quenching of intermediate products......, is an attractive way for bio-oil production. Various efforts have been made to improve pyrolysis process towards higher yield and quality of liquid biofuels and better energy efficiency. Microwave-assisted pyrolysis is one of the promising attempts, mainly due to efficient heating of feedstock by ‘‘microwave...

Enzymatic biofuel cell based on electrodes modified with lipid liquid-crystalline cubic phases

Science.gov (United States)

Nazaruk, Ewa; Smoliński, Sławomir; Swatko-Ossor, Marta; Ginalska, Grażyna; Fiedurek, Jan; Rogalski, Jerzy; Bilewicz, Renata

Two glassy carbon electrodes modified with enzymes embedded in lyotropic liquid-crystalline cubic phase were used for the biofuel cell construction. The monoolein liquid-crystalline film allowed to avoid separators in the biofuel cell. Glucose and oxygen as fuels, and glucose oxidase and laccase as anode and cathode biocatalysts, respectively were used. The biofuel cell parameters were examined in McIlvaine buffer, pH 7 solution containing 15 mM of glucose and saturated with dioxygen. A series of mediators were tested taking into account their formal potentials, stability in the cubic phase and efficiency of mediation. Most stable was the biofuel cell based on tetrathiafulvalene (TTF) and 2,2‧-azino-bis(3-ethylbenzothiazoline-6-sulfonate) (ABTS) as anode and cathode mediators, respectively. The open-circuit voltage was equal to 450 ± 40 mV. The power densities and current densities were measured for all the systems studied.

Liquid biofuels - can they meet our expectations?

Science.gov (United States)

Glatzel, G.

2012-04-01

Liquid biofuels are one of the options for reducing the emission of greenhouse gases and the dependence on fossil fuels. This is reflected in the DIRECTIVE 2003/30/EC OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL on the promotion of the use of biofuels or other renewable fuels for transport. The promotion of E10, an automotive fuel containing 10 percent bioethanol, is based on this directive. At present almost all bioethanol is produced from agricultural crops such as maize, corn or sugar beet and sugar cane in suitable climates. In view of shortages and rising prices of food, in particular in developing countries, the use of food and feed crops for biofuel production is increasingly criticized. Alternative sources of biomass are perennial grasses and wood, whose cellulose fraction can be converted to alcohol by the so called "second generation" processes, which seem to be close to commercial deployment. The use of the total plant biomass increases the biofuel yield per hectare as compared to conventional crops. Of special interest for biofuel production is woody biomass from forests as this avoids competition with food production on arable land. Historically woody biomass was for millennia the predominant source of thermal energy. Before fossil fuels came into use, up to 80 percent of a forest was used for fuel wood, charcoal and raw materials such as potash for trade and industry. Now forests are managed to yield up to 80 percent of high grade timber for the wood industry. Replacing sophisticatedly managed forests by fast growing biofuel plantations could make economic sense for land owners when a protected market is guaranteed by politics, because biofuel plantations would be highly mechanized and cheap to operate, even if costs for certified planting material and fertilizer are added. For forest owners the decision to clear existing long rotation forests for biofuel plantations would still be weighty because of the extended time of decades required to rebuild a

The macro-environment for liquid biofuels in the German science, mass, media and government

OpenAIRE

Talamini, E.; Wubben, E.F.M.; Dewes, H.

2010-01-01

The purpose of this study is to investigate under which dimensions the macro-environment for liquid biofuels has been structured during time, respectively by science, mass media, and government in Germany, and how these three social expressions related to each other. Research was carried out on German official government documents, mass media news, and scientific papers on the topic 'liquid biofuels'. Text Mining was used to extract knowledge from their content. The results indicate that in c...

Economics of small-scale on-farm use of canola and soybean for biodiesel and straight vegetable oil biofuels

International Nuclear Information System (INIS)

Fore, Seth R.; Porter, Paul; Jordan, Nicholas; Lazarus, William

2011-01-01

While the cost competitiveness of vegetable oil-based biofuels (VOBB) has impeded extensive commercialization on a large-scale, the economic viability of small-scale on-farm production of VOBB is unclear. This study assessed the cost competitiveness of small-scale on-farm production of canola- [Brassica napus (L.)] and soybean-based [Glycine max (L.)] biodiesel and straight vegetable oil (SVO) biofuels in the upper Midwest at 2007 price levels. The effects of feedstock type, feedstock valuation (cost of production or market price), biofuel type, and capitalization level on the cost L -1 of biofuel were examined. Valuing feedstock at the cost of production, the cost of canola-based biodiesel ranged from 0.94 to 1.13 L -1 and SVO from 0.64 to 0.83 L -1 depending on capitalization level. Comparatively, the cost of soybean-based biodiesel and SVO ranged from 0.40 to 0.60 L -1 and from 0.14 to 0.33 L -1 , respectively, depending on capitalization level. Valuing feedstock at the cost of production, soybean biofuels were cost competitive whereas canola biofuels were not. Valuing feedstock at its market price, canola biofuels were more cost competitive than soybean-based biofuels, though neither were cost competitive with petroleum diesel. Feedstock type proved important in terms of the meal co-product credit, which decreased the cost of biodiesel by 1.39 L -1 for soybean and 0.44 L -1 for canola. SVO was less costly to produce than biodiesel due to reduced input costs. At a small scale, capital expenditures have a substantial impact on the cost of biofuel, ranging from 0.03 to 0.25 L -1 . (author)

Practical implementation of liquid biofuels: The transferability of the Brazilian experiences

International Nuclear Information System (INIS)

Alonso-Pippo, Walfrido; Luengo, Carlos A.; Alonsoamador Morales Alberteris, Lidice; García del Pino, Gilberto; Duvoisin, Sergio

2013-01-01

The main purpose of this paper was to carry out a systematic analysis of the particularities and trends pertaining to the development of biofuels in Brazil—a country which has demonstrated its leadership in this field during the last 40 years. The Brazilian experiences with biofuels are often used as references for decision making by other developed and developing countries. The transferability of Brazil's biofuels practices would be appreciated by many researchers and energy policy markers across the world. This work uses an adapted 5W2H (what, when, where, why, who, how, and how much) analysis technique to answer a variety of questions about the subject. The data, facts, and figures herein are offered as resources for other researchers and policy makers seeking benchmarking. Also, this work discusses the main certainties and uncertainties of the sugarcane agro-industry, and also goes into detail about the ethanol supply chain structure, its management, and particularities. Finally, this research analyzes the central aspects of biofuels implementation in Brazil, lists the most important aspects to consider during a selection of possible standard biofuels, and presents the main aspects of the National Program of Biodiesel Production and its sustainability. - Highlights: • A systemic cause–effect analysis was carried out on biofuel program success. • Main questions concerning implementation of liquid biofuels in Brazil were studied. • Main weakness aspects of biofuel logistic were treated. • During selection of benchmarking strategy. What needs to take into account?

Economics of small-scale on-farm use of canola and soybean for biodiesel and straight vegetable oil biofuels

Energy Technology Data Exchange (ETDEWEB)

Fore, Seth R.; Porter, Paul; Jordan, Nicholas [Department of Agronomy and Plant Genetics, 1991 Upper Buford Circle, Borlaug 411, The University of Minnesota, Saint Paul, Minnesota 55108 (United States); Lazarus, William [Department of Applied Economics, 231 Classroom Office Building, 1994 Buford Avenue, The University of Minnesota, Saint Paul, Minnesota 55108 (United States)

2011-01-15

While the cost competitiveness of vegetable oil-based biofuels (VOBB) has impeded extensive commercialization on a large-scale, the economic viability of small-scale on-farm production of VOBB is unclear. This study assessed the cost competitiveness of small-scale on-farm production of canola- [Brassica napus (L.)] and soybean-based [Glycine max (L.)] biodiesel and straight vegetable oil (SVO) biofuels in the upper Midwest at 2007 price levels. The effects of feedstock type, feedstock valuation (cost of production or market price), biofuel type, and capitalization level on the cost L{sup -1} of biofuel were examined. Valuing feedstock at the cost of production, the cost of canola-based biodiesel ranged from 0.94 to 1.13 L{sup -1} and SVO from 0.64 to 0.83 L{sup -1} depending on capitalization level. Comparatively, the cost of soybean-based biodiesel and SVO ranged from 0.40 to 0.60 L{sup -1} and from 0.14 to 0.33 L{sup -1}, respectively, depending on capitalization level. Valuing feedstock at the cost of production, soybean biofuels were cost competitive whereas canola biofuels were not. Valuing feedstock at its market price, canola biofuels were more cost competitive than soybean-based biofuels, though neither were cost competitive with petroleum diesel. Feedstock type proved important in terms of the meal co-product credit, which decreased the cost of biodiesel by 1.39 L{sup -1} for soybean and 0.44 L{sup -1} for canola. SVO was less costly to produce than biodiesel due to reduced input costs. At a small scale, capital expenditures have a substantial impact on the cost of biofuel, ranging from 0.03 to 0.25 L{sup -1}. (author)

Examining the potential for liquid biofuels production and usage in Ghana

International Nuclear Information System (INIS)

Afrane, George

2012-01-01

The perennial political and social upheavals in major oil-producing regions, the increasing energy demand from emerging economies, the global economic crisis and even environmental disasters, like the recent major oil spill in the Gulf of Mexico, all contribute to price fluctuations and escalations. Usually price instability affects the least-developed countries with the most fragile economies, like Ghana, the most. This paper gives a brief overview of the Ghanaian energy situation, describes the liquid biofuel production processes and examines the possibility of replacing some of the fossil fuels consumed annually, with locally produced renewable biofuels. Various scenarios for substituting different portions of petrol and diesel with biofuels derived from cassava and palm oil are examined. Based on 2009 crop production and fuel consumption data, replacement of 5% of both petrol and diesel with biofuels would require 1.96% and 17.3% of the cassava and palm oil produced in that year, respectively; while replacement of 10% of both fossil fuels would need 3.91% and 34.6% of the corresponding biofuels. Thus while petrol replacement could be initiated with little difficulty, regarding raw material availability, biodiesel would require enhanced palm oil production and/or oil supplement from other sources, including, potentially, jatropha. An implementation strategy is proposed.

Synthesis of three advanced biofuels from ionic liquid-pretreated switchgrass using engineered Escherichia coli

Science.gov (United States)

Bokinsky, Gregory; Peralta-Yahya, Pamela P.; George, Anthe; Holmes, Bradley M.; Steen, Eric J.; Dietrich, Jeffrey; Soon Lee, Taek; Tullman-Ercek, Danielle; Voigt, Christopher A.; Simmons, Blake A.; Keasling, Jay D.

2011-01-01

One approach to reducing the costs of advanced biofuel production from cellulosic biomass is to engineer a single microorganism to both digest plant biomass and produce hydrocarbons that have the properties of petrochemical fuels. Such an organism would require pathways for hydrocarbon production and the capacity to secrete sufficient enzymes to efficiently hydrolyze cellulose and hemicellulose. To demonstrate how one might engineer and coordinate all of the necessary components for a biomass-degrading, hydrocarbon-producing microorganism, we engineered a microorganism naïve to both processes, Escherichia coli, to grow using both the cellulose and hemicellulose fractions of several types of plant biomass pretreated with ionic liquids. Our engineered strains express cellulase, xylanase, beta-glucosidase, and xylobiosidase enzymes under control of native E. coli promoters selected to optimize growth on model cellulosic and hemicellulosic substrates. Furthermore, our strains grow using either the cellulose or hemicellulose components of ionic liquid-pretreated biomass or on both components when combined as a coculture. Both cellulolytic and hemicellulolytic strains were further engineered with three biofuel synthesis pathways to demonstrate the production of fuel substitutes or precursors suitable for gasoline, diesel, and jet engines directly from ionic liquid-treated switchgrass without externally supplied hydrolase enzymes. This demonstration represents a major advance toward realizing a consolidated bioprocess. With improvements in both biofuel synthesis pathways and biomass digestion capabilities, our approach could provide an economical route to production of advanced biofuels. PMID:22123987

Guidance to the regulations on sustainability criteria for biofuels and liquid biofuels. Version 2.0; Vaegledning till regelverket om haallbarhetskriterier foer biodrivmedel och flytande biobraenslen. Version 2.0

Energy Technology Data Exchange (ETDEWEB)

Engstroem, Lina; Jozsa, Emmi; Hagberg, Linus; Wollin, Per; Petren Axner, Margareta

2012-11-01

For biofuels and liquid biofuels: Swedish Energy Agency's guidance on the regulatory framework on sustainability criteria have been updated and expanded with new sections on control systems, independent auditing, sustainability statements and verification of land criteria in Sweden.

Land availability for biofuel production.

Science.gov (United States)

Cai, Ximing; Zhang, Xiao; Wang, Dingbao

2011-01-01

Marginal agricultural land is estimated for biofuel production in Africa, China, Europe, India, South America, and the continental United States, which have major agricultural production capacities. These countries/regions can have 320-702 million hectares of land available if only abandoned and degraded cropland and mixed crop and vegetation land, which are usually of low quality, are accounted. If grassland, savanna, and shrubland with marginal productivity are considered for planting low-input high-diversity (LIHD) mixtures of native perennials as energy crops, the total land availability can increase from 1107-1411 million hectares, depending on if the pasture land is discounted. Planting the second generation of biofuel feedstocks on abandoned and degraded cropland and LIHD perennials on grassland with marginal productivity may fulfill 26-55% of the current world liquid fuel consumption, without affecting the use of land with regular productivity for conventional crops and without affecting the current pasture land. Under the various land use scenarios, Africa may have more than one-third, and Africa and Brazil, together, may have more than half of the total land available for biofuel production. These estimations are based on physical conditions such as soil productivity, land slope, and climate.

A thermophilic ionic liquid-tolerant cellulase cocktail for the production of cellulosic biofuels.

Directory of Open Access Journals (Sweden)

Joshua I Park

Full Text Available Generation of biofuels from sugars in lignocellulosic biomass is a promising alternative to liquid fossil fuels, but efficient and inexpensive bioprocessing configurations must be developed to make this technology commercially viable. One of the major barriers to commercialization is the recalcitrance of plant cell wall polysaccharides to enzymatic hydrolysis. Biomass pretreatment with ionic liquids (ILs enables efficient saccharification of biomass, but residual ILs inhibit both saccharification and microbial fuel production, requiring extensive washing after IL pretreatment. Pretreatment itself can also produce biomass-derived inhibitory compounds that reduce microbial fuel production. Therefore, there are multiple points in the process from biomass to biofuel production that must be interrogated and optimized to maximize fuel production. Here, we report the development of an IL-tolerant cellulase cocktail by combining thermophilic bacterial glycoside hydrolases produced by a mixed consortia with recombinant glycoside hydrolases. This enzymatic cocktail saccharifies IL-pretreated biomass at higher temperatures and in the presence of much higher IL concentrations than commercial fungal cocktails. Sugars obtained from saccharification of IL-pretreated switchgrass using this cocktail can be converted into biodiesel (fatty acid ethyl-esters or FAEEs by a metabolically engineered strain of E. coli. During these studies, we found that this biodiesel-producing E. coli strain was sensitive to ILs and inhibitors released by saccharification. This cocktail will enable the development of novel biomass to biofuel bioprocessing configurations that may overcome some of the barriers to production of inexpensive cellulosic biofuels.

A Thermophilic Ionic Liquid-Tolerant Cellulase Cocktail for the Production of Cellulosic Biofuels

Science.gov (United States)

Park, Joshua I.; Steen, Eric J.; Burd, Helcio; Evans, Sophia S.; Redding-Johnson, Alyssa M.; Batth, Tanveer; Benke, Peter I.; D'haeseleer, Patrik; Sun, Ning; Sale, Kenneth L.; Keasling, Jay D.; Lee, Taek Soon; Petzold, Christopher J.; Mukhopadhyay, Aindrila; Singer, Steven W.; Simmons, Blake A.; Gladden, John M.

2012-01-01

Generation of biofuels from sugars in lignocellulosic biomass is a promising alternative to liquid fossil fuels, but efficient and inexpensive bioprocessing configurations must be developed to make this technology commercially viable. One of the major barriers to commercialization is the recalcitrance of plant cell wall polysaccharides to enzymatic hydrolysis. Biomass pretreatment with ionic liquids (ILs) enables efficient saccharification of biomass, but residual ILs inhibit both saccharification and microbial fuel production, requiring extensive washing after IL pretreatment. Pretreatment itself can also produce biomass-derived inhibitory compounds that reduce microbial fuel production. Therefore, there are multiple points in the process from biomass to biofuel production that must be interrogated and optimized to maximize fuel production. Here, we report the development of an IL-tolerant cellulase cocktail by combining thermophilic bacterial glycoside hydrolases produced by a mixed consortia with recombinant glycoside hydrolases. This enzymatic cocktail saccharifies IL-pretreated biomass at higher temperatures and in the presence of much higher IL concentrations than commercial fungal cocktails. Sugars obtained from saccharification of IL-pretreated switchgrass using this cocktail can be converted into biodiesel (fatty acid ethyl-esters or FAEEs) by a metabolically engineered strain of E. coli. During these studies, we found that this biodiesel-producing E. coli strain was sensitive to ILs and inhibitors released by saccharification. This cocktail will enable the development of novel biomass to biofuel bioprocessing configurations that may overcome some of the barriers to production of inexpensive cellulosic biofuels. PMID:22649505

Viewls - WP2. Environmental and economic performance of biofuels. Vol. 2 - Appendices

Energy Technology Data Exchange (ETDEWEB)

NONE

2005-04-15

According to the European Directive 2003/30 'Promotion of the use of biofuels or other renewable fuels for transport' the use of biofuels in the transportation sector should be strongly increased in the next decades in Europe. The purpose of this study was to obtain and present clear data and information to outline environmental and economic performance of different biofuels. Based on a standardised review of the most relevant international studies on transportation systems using biomass, the study presented estimation of ranges for the environmental and economic performance of different biofuels given by the two 'threshold values' and the 'reference value' between these threshold values. These results might be used by different stakeholders as an information source for future activities regarding the use of biofuels in the transportation sector in Europe. This report presents data about the following biofuels: bioethanol, bio-ETBE, biomethanol, bio-MTBE, pure vegetable oil, biodiesel, Fischer-Tropsch diesel, bio-DME, biogas, gaseous biohydrogen, liquid biohydrogen and bio-SNG. (BA)

The Macro-Environment for Liquid Biofuels in German Science, Mass Media and Government

NARCIS (Netherlands)

Talamini, E.; Wubben, E.F.M.; Dewes, H.

2013-01-01

This paper aims to investigate the dimensions under which the macro-environment for liquid biofuels has been structured during the time, respectively by German scientists, journalists, and policy-makers, and how these three stakeholders related to each other. Research was carried out on German

Bio-fuels

International Nuclear Information System (INIS)

2008-01-01

This report presents an overview of the technologies which are currently used or presently developed for the production of bio-fuels in Europe and more particularly in France. After a brief history of this production since the beginning of the 20. century, the authors describe the support to agriculture and the influence of the Common Agricultural Policy, outline the influence of the present context of struggle against the greenhouse effect, and present the European legislative context. Data on the bio-fuels consumption in the European Union in 2006 are discussed. An overview of the evolution of the activity related to bio-fuels in France, indicating the locations of ethanol and bio-diesel production facilities, and the evolution of bio-fuel consumption, is given. The German situation is briefly presented. Production of ethanol by fermentation, the manufacturing of ETBE, the bio-diesel production from vegetable oils are discussed. Second generation bio-fuels are then presented (cellulose enzymatic processing), together with studies on thermochemical processes and available biomass resources

Combustion of animal or vegetable based liquid waste products

International Nuclear Information System (INIS)

Wikman, Karin; Berg, Magnus

2002-04-01

In this project experiences from combustion of animal and vegetable based liquid waste products have been compiled. Legal aspects have also been taken into consideration and the potential for this type of fuel on the Swedish energy market has been evaluated. Today the supply of animal and vegetable based liquid waste products for energy production in Sweden is limited. The total production of animal based liquid fat is about 10,000 tonnes annually. The animal based liquid waste products origin mainly from the manufacturing of meat and bone meal. Since meat and bone meal has been banned from use in animal feeds it is possible that the amount of animal based liquid fat will decrease. The vegetable based liquid waste products that are produced in the processing of vegetable fats are today used mainly for internal energy production. This result in limited availability on the commercial market. The potential for import of animal and vegetable based liquid waste products is estimated to be relatively large since the production of this type of waste products is larger in many other countries compared to Sweden. Vegetable oils that are used as food or raw material in industries could also be imported for combustion, but this is not reasonable today since the energy prices are relatively low. Restrictions allow import of SRM exclusively from Denmark. This is today the only limit for increased imports of animal based liquid fat. The restrictions for handle and combustion of animal and vegetable based liquid waste products are partly unclear since this is covered in several regulations that are not easy to interpret. The new directive for combustion of waste (2000/76/EG) is valid for animal based waste products but not for cadaver or vegetable based waste products from provisions industries. This study has shown that more than 27,400 tonnes of animal based liquid waste products and about 6,000 tonnes of vegetable based liquid waste products were used for combustion in Sweden

On the atomization and combustion of liquid biofuels in gas turbines: towards the application of biomass-derived pyrolysis oil

NARCIS (Netherlands)

Sallevelt, J.L.H.P.

2015-01-01

The combustion of liquid biofuels in gas turbines is an efficient way of generating heat and power from biomass. Gas turbines play a major role in the global energy supply and are suitable for a wide range of applications. However, biofuels generally have different properties compared to

The Renewable Energy Directive: biofuels, biomass and sustainable development criteria. How to check in France the compliance of marketed biofuels with sustainability criteria defined by the Directive on renewable energies? (Phase 1: biofuels and bio-liquids)

International Nuclear Information System (INIS)

2009-06-01

After having recalled and commented the main principles of the European directive which sets objectives in terms of renewable energy promotion and consumption, this report analyses the quantitative and qualitative sustainability criteria which must be applied particularly to biofuels and bio-liquids produced from agricultural activities, and their application perspectives. It gives recommendations to assess these criteria. It also comments the modalities used to control the compliance of biofuels with these criteria

Next generation of liquid biofuel production

NARCIS (Netherlands)

Batidzirai, B.

2012-01-01

More than 99% of all currently produced biofuels are classified as “first generation” (i.e. fuels produced primarily from cereals, grains, sugar crops and oil seeds) (IEA, 2008b). “Second generation” or “next generation” biofuels, on the other hand, are produced from lignocellulosic feedstocks such

Layered double hydroxide catalyst for the conversion of crude vegetable oils to a sustainable biofuel

Science.gov (United States)

Mollaeian, Keyvan

Over the last two decades, the U.S. has developed the production of biodiesel, a mixture of fatty acid methyl esters, using chiefly vegetable oils as feedstocks. However, there is much concern about the availability of high-quality vegetable oils for longterm biodiesel production. Problems have also risen due to the production of glycerol, an unwanted byproduct, as well as the need for process wash water. Therefore, this study was initiated to produce not only fatty acid methyl esters (FAMEs) but also fatty acid glycerol carbonates (FAGCs) by replacing methanol with dimethyl carbonate (DMC). The process would have no unnecessary byproducts and would be a simplified process compared to traditional biodiesel. In addition, this altering of the methylating agent could convert triglycerides, free fatty acids, and phospholipids to a sustainable biofuel. In this project, Mg-Al Layered Double Hydroxide (LDH) was optimized by calcination in different temperature varied from 250°C to 450°C. The gallery between layers was increased by intercalating sodium dodecylsulfate (SDS). During catalyst preparation, the pH was controlled ~10. In our experiment, triazabicyclodecene (TBD) was attached with trimethoxysilane (3GPS) as a coupling agent, and N-cetyl-N,N,N-trimethylammonium bromide (CTAB) was added to remove SDS from the catalyst. The catalyst was characterized by XRD, FTIR, and Raman spectroscopy. The effect of the heterogeneous catalyst on the conversion of canola oil, corn oil, and free fatty acids was investigated. To analyze the conversion of lipid oils to biofuel an in situ Raman spectroscopic method was developed. Catalyst synthesis methods and a proposed mechanism for converting triglycerides and free fatty acids to biofuel will be presented.

Solid and liquid biofuels markets in Finland. A study on international biofuels trade. IEA bioenergy task 40 and EUROBIONET II. Country report of Finland

International Nuclear Information System (INIS)

Heinimoe, J.; Alakangas, E.

2006-01-01

This study considered the current situation of solid and liquid biofuels markets and international biofuels trade in Finland and identified the challenges of the emerging international biofuels markets for Finland. The fact that industry consumes more than half of the total primary energy, widely applied combined heat and power production (CHP) and a high share of biofuels in the total energy consumption are specific to the Finnish energy system. One third of the electricity is generated in CHP plants. As much as 27% of the total energy consumption is met by using wood and peat, which makes Finland the leading country in the use of biofuels. Finland has made a commitment to maintain greenhouse gas emissions at the 1990 level at the highest during the period 2008-2012. The Finnish energy policy aims to achieve the target, and a variety of measures are taken to promote the use of renewable energy sources and especially wood fuels. In this study, the wooden raw material streams of the forest industry were included the international biofuels trade in addition to biomass streams that are traded for energy production. In 2004, as much as 45% of the raw wood imported into Finland ended up in energy production. The total international trading of biofuels was evaluated at 72 PJ, of which the majority, 58 PJ, was raw wood. About 22% of wood based energy in Finland originated from imported raw wood. Tall oil and wood pellets composed the largest export streams of biofuels. The annual turnover of international biofuels trade was estimated at about euro 90 million for direct trade and at about euro 190 million for indirect trade. The forest industry as the biggest user of wood, and the producer and user of wood fuels has a central position in biomass and biofuels markets in Finland. Lately, the international aspects of Finnish biofuels markets have been emphasised as the import of raw wood and the export of wood pellets have increased. Expanding the use of biofuels in the road

Is it environmentally advantageous to use vegetable oil directly as biofuel instead of converting it to biodiesel?

International Nuclear Information System (INIS)

Esteban, Bernat; Baquero, Grau; Puig, Rita; Riba, Jordi-Roger; Rius, Antoni

2011-01-01

The oil price instability and the measures taken to reduce the increase in greenhouse gas emissions are the main factors promoting the development and use of environmentally friendly energies. From an energy efficiency point of view, biofuels constitute a renewable energy source and its use helps to reduce energy dependency on fossil fuels. The most used biofuels for transport worldwide are biodiesel (BD) and bioethanol. However, there are other options such as straight vegetable oil (SVO). SVO can be small-scale produced in local cooperatives through pressing, filtering and conditioning processes which are much simpler than the ones required for BD production. In this study a comparative life cycle assessment (LCA) of two biofuels obtained from Spanish rapeseed, namely small-scale SVO and large-scale BD, is performed. The LCA methodology allows the two biofuels' production and their rate of consumption in a vehicle (a truck) to be compared. In this manner, it is possible to assess which is environmentally advantageous: to use SVO directly as biofuel or to convert it to BD. Moreover, LCA is used in the study to calculate the energy return on investment index (EROI) and an energy conversion ratio to evaluate which biofuel is more energy efficient. The obtained results show the environmental benefits of using SVO instead of BD by analyzing representative impact categories defined by the CML and EDIP methods. A sensitivity analysis has also been conducted. EROI indexes for SVO and BD production show a clear preference for SVO as compared to BD.

The macro-environment for liquid biofuels in the German science, mass, media and government

NARCIS (Netherlands)

Talamini, E.; Wubben, E.F.M.; Dewes, H.

2010-01-01

The purpose of this study is to investigate under which dimensions the macro-environment for liquid biofuels has been structured during time, respectively by science, mass media, and government in Germany, and how these three social expressions related to each other. Research was carried out on

The macro-environment for liquid biofuels in the US mass media, science and government

NARCIS (Netherlands)

Wubben, E.F.M.; Talamini, E.; Dewes, H.

2010-01-01

The purpose of this study is to investigate under which dimensions the macro-environment for liquid biofuels has been structured during time, respectively by science, mass media, and government in Germany, and how these three social expressions related to each other. Research was carried out on

Environmental and energy aspects of liquid biofuels

International Nuclear Information System (INIS)

De Boo, W.

1993-02-01

When spending public money to reduce CO 2 emissions, it is necessary to establish which alternative energy source results in the largest reduction of CO 2 emission per unit cost. Comparison of different biofuels with other energy resources is therefore important. Bioethanol is compared with leadfree gasoline, and rapeseed oil methylester (RME) is compared with diesel. Subsequently, biofuel production as a method to reduce CO 2 emission will be compared with other sustainable energy resources. This comparison is based on the energy balance in chapter two and the final costs of biofuels in chapter six. The comparison of biofuels and current fossil fuels is based on emissions to the atmosphere of greenhouse gases and acidifying pollutants in chapter three. Pollution to soil and water by arable cropping is a specific characteristic of biofuel production and is difficult to compare with fossil fuels. On this subject biofuels are compared with other land uses in chapter four. This also applies to other adverse environmental aspects of agricultural production such as competition for land use with natural areas and recreation purposes. To explore future technological developments, a comparison is made in energy balances with estimated results after the year 2000. The overall conclusion is that there are far better options to achieve CO 2 reduction. 2 figs., 9 tabs., 14 appendices, 28 refs

Production of liquid biofuels in the world after 2000. Its level and dynamics

Directory of Open Access Journals (Sweden)

Michał Borychowski

2014-08-01

Full Text Available As crude oil resources decrease, the demand for this raw material is growing and its extraction is becoming less certain. In this situation the world turns to renewable energy sources, which include inter alia liquid biocomponents I generation (conventional biocomponents, which are produced from agricultural raw materials. The global biofuels has been sector is for several years developing fast. The main indications of this is the increasing production and consumption of liquid biocomponents in an increasing number of countries on all continents – both in developed countries, as well as developing countries. The main basis for the development of this industry tends to be the economic benefits, but we must not ignore the risks that arise in relation to this segment of the economy. The significance of this subject is fact that today the importance of liquid biocomponents (and other renewable energy sources is increasing. In addition, the production of biofuels from edible agricultural raw materials is controversial, and hence we need a world wide discourse to look at the sector from the perspective of both the benefits and risks (economic, social, environmental. The purpose of this article is to present the production and consumption of liquid biocomponents worldwide and in selected countries the release dynamics in recent years. In addition, this article is an attempt to identify the factors determining the development of the industry on a global scale.

The macro-environment for liquid biofuels in the US mass media, science and government

OpenAIRE

Wubben, E.F.M.; Talamini, E.; Dewes, H.

2010-01-01

The purpose of this study is to investigate under which dimensions the macro-environment for liquid biofuels has been structured during time, respectively by science, mass media, and government in Germany, and how these three social expressions related to each other. Research was carried out on German official government documents, mass media news, and scientific papers on the topic ‘liquid biofuels’. Text Mining was used to extract knowledge from their content. The results indicate that in c...

Biofuels. An overview. Final Report

International Nuclear Information System (INIS)

De Castro, J.F.M.

2007-05-01

The overall objective of this desk study is to get an overview of the most relevant liquid biofuels especially in the African context, and more specifically in the Netherlands' relevant partner countries. The study will focus on biofuels for transport, but will also consider biofuels for cooking and power generation. Biogas as the result of anaerobic fermentation which can be used for cooking, lighting and electricity generation will not be considered in this study. Liquid biofuels are usually divided into alcohols that are used to substitute for gasoline and oils that are used to substitute for diesel and are often called Biodiesel, and this division will be followed in this study. In chapter 2 we will analyse several aspects of the use of alcohols particularly ethanol, in chapter 3 the same analysis will be done for oils, using as example the very promising Jatropha oil. In chapter we will analyse socio-economic issues of the use of these biofuels

Sustainable Liquid Biofuels from Biomass Biorefining (SUNLIBB). Policy Brief No. 1

Energy Technology Data Exchange (ETDEWEB)

NONE

2012-03-01

The SUNLIBB project is funded under the European Seventh Framework Programme (FP7) within the Energy theme: Second Generation Biofuels -- EU Brazil Coordinated Call. SUNLIBB started on 1 October 2010 for 4 years and collaborates with a parallel project in Brazil, CeProBIO. First generation biofuels -- which are mainly produced from food crops such as grains, sugarcane and vegetable oils -- have triggered one of the most highly contentious debates on the current international sustainability agenda, given their links to energy security, transport, trade, food security, land-use impacts and climate change concerns. Developing second generation biofuels has emerged as a more attractive option, as these are manufactured from inedible sources, such as woody crops, energy grasses, or even agricultural and forestry residues. Residues from sugarcane and biomass from maize, as well as 'whole-crop' miscanthus are all potential raw material (called 'feedstock') for second generation bioethanol production. Because these three plants are all closely related, processing the biomass from these crops raises common technical challenges, which offers the opportunity for breakthroughs in one species to be rapidly exploited in the others. Despite the potential sustainability benefits of second generation bioethanol, the current inefficiency of production makes it economically uncompetitive. Taking up this challenge, the SUNLIBB consortium's multidisciplinary team of scientists -- in cooperation with CeProBIO, the sister project in Brazil -- combines European and Brazilian research strengths so as to open the way for environmentally, socially and economically sustainable second generation bioethanol production.

Biofuels barometer

International Nuclear Information System (INIS)

Anon.

2012-01-01

The European Union governments no longer view the rapid increase in biofuel consumption as a priority. Between 2010 and 2011 biofuel consumption increased by only 3%, which translates into 13.6 million tonnes of oil equivalent (toe) used in 2011 compared to 13.2 million toe in 2010. In 2011 6 European countries had a biofuel consumption in transport that went further 1 million toe: Germany (2,956,746 toe), France (2,050,873 toe), Spain (1,672,710 toe), Italy (1,432,455 toe), United Kingdom (1,056,105 toe) and Poland (1,017,793 toe). The breakdown of the biofuel consumption for transport in the European Union in 2011 into types of biofuels is: bio-diesel (78%), bio-ethanol (21%), biogas (0.5%) and vegetable oil (0.5%). In 2011, 4 bio-diesel producers had a production capacity in Europe that passed beyond 900,000 tonnes: Diester Industrie International (France) with 3,000,000 tonnes, Neste Oil (Finland) with 1,180,000 tonnes, ADM bio-diesel (Germany) with 975,000 tonnes, and Infinita (Spain) with 900,000 tonnes. It seems that the European Union's attention has shifted to setting up sustainability systems to verify that the biofuel used in the various countries complies with the Renewable Energy Directive's sustainability criteria

The development of the biofuels in the german farms

International Nuclear Information System (INIS)

Palz, W.

2005-03-01

Germany is today at the first place of the world for the production and the utilization of vegetable oils and by products, the Diester. The main reasons of this enjoyment is the two european directives on biofuels and the tax exemption at 100% decided by the government in 2004. All the biofuels available in Germany, as the ethanol, the vegetable oils and the bio-alcohol, are presented in this paper. The research axis and the government policy in favor of the biofuels are also discussed. (A.L.B.)

Pretreatment techniques for biofuels and biorefineries

Energy Technology Data Exchange (ETDEWEB)

Fang, Zhen (ed.) [Chinese Academy of Sciences, Kunming, YN (China). Xishuangbanna Tropical Botonical Garden

2013-02-01

The first book focused on pretreatment techniques for biofuels contributed by the world's leading experts. Extensively covers the different types of biomass, various pretreatment approaches and methods that show the subsequent production of biofuels and chemicals. In addition to traditional pretreatment methods, novel techniques are also introduced and discussed. An accessible reference work for students, researchers, academicians and industrialists in biorefineries. This book includes 19 chapters contributed by the world's leading experts on pretreatment methods for biomass. It extensively covers the different types of biomass (e.g. molasses, sugar beet pulp, cheese whey, sugarcane residues, palm waste, vegetable oil, straws, stalks and wood), various pretreatment approaches (e.g. physical, thermal, chemical, physicochemical and biological) and methods that show the subsequent production of biofuels and chemicals such as sugars, ethanol, extracellular polysaccharides, biodiesel, gas and oil. In addition to traditional methods such as steam, hot-water, hydrothermal, diluted-acid, organosolv, ozonolysis, sulfite, milling, fungal and bacterial, microwave, ultrasonic, plasma, torrefaction, pelletization, gasification (including biogas) and liquefaction pretreatments, it also introduces and discusses novel techniques such as nano and solid catalysts, organic electrolyte solutions and ionic liquids. This book offers a review of state-of-the-art research and provides guidance for the future paths of developing pretreatment techniques of biomass for biofuels, especially in the fields of biotechnology, microbiology, chemistry, materials science and engineering. It intends to provide a systematic introduction of pretreatment techniques. It is an accessible reference work for students, researchers, academicians and industrialists in biorefineries.

Methodological aspects on international biofuels trade: International streams and trade of solid and liquid biofuels in Finland

International Nuclear Information System (INIS)

Heinimoe, J.

2008-01-01

The use of biomass for fuel is increasing in industrialised countries. Rapidly developing biomass markets for energy purposes along with weak information on biofuels trade that statistics offer have been incentives for several recently published studies investigating the status of biofuels trade. The comparison of the studies is often challenging due particularly to the various approaches to the indirect trade of biofuels and the diverse data sources utilised. The purpose of this study was to provide an overview of the Finnish situation with respect to the status of the streams of international biofuels trade. Parallel to this, the study aimed to identify methodological and statistical challenges in observing international biofuels trade. The study analysed available statistical information and introduced a procedure to obtain a clear overview on import and export streams of biofuels. In Finland, the total direct import and export of biofuels, being mainly composed of wood pellets and tall oil, is tiny in comparison with the total consumption of biofuels. Instead, the indirect trade has remarkable importance. Large import volumes of industrial raw wood make Finland a net importer of biofuels. In 2004, approximately 22% (64 PJ) of wood-based energy in Finland originated from imported wood. The study showed that the indirect trade of biofuels may be a significant sector of global biofuels trade. In the case of Finland, a comprehensive compilation of statistics on energy and forestry enabled the determination of the trade status satisfactory. However, national and international statistics should be further developed to take better into consideration international trade and to support continuously developing biofuels markets. (author)

Transport biofuels - a life-cycle assessment approach

NARCIS (Netherlands)

Reijnders, L.

2008-01-01

Life-cycle studies of the currently dominant transport biofuels (bioethanol made from starch or sugar and biodiesel made from vegetable oil) show that solar energy conversion efficiency is relatively poor if compared with solar cells and that such biofuels tend to do worse than conventional fossil

Review and experimental study on pyrolysis and hydrothermal liquefaction of microalgae for biofuel production

International Nuclear Information System (INIS)

Chiaramonti, David; Prussi, Matteo; Buffi, Marco; Rizzo, Andrea Maria; Pari, Luigi

2017-01-01

Highlights: • A review of microalgae thermochemical conversion to bioliquids was carried out. • We focused on pyrolysis and hydrothermal liquefaction for biocrude/biofuels. • Original experimental research on microalgae pyrolysis was also carried out. • Starvation does not impact significant on the energy content of the biocrude. • This result is relevant for designing full scale microalgae production plants. - Abstract: Advanced Biofuels steadily developed during recent year, with several highly innovative processes and technologies explored at various scales: among these, lignocellulosic ethanol and CTO (Crude Tall Oil)-biofuel technologies already achieved early-commercial status, while hydrotreating of vegetable oils is today fully commercial, with almost 3.5 Mt/y installed capacity worldwide. In this context, microalgae grown in salt-water and arid areas represent a promising sustainable chain for advanced biofuel production but, at the same time, they also represent a considerable challenge. Processing microalgae in an economic way into a viable and sustainable liquid biofuel (a low-cost mass-product) is not trivial. So far, the most studied microalgae-based biofuel chain is composed by microorganism cultivation, lipid accumulation, oil extraction, co-product valorization, and algae oil conversion through conventional esterification into Fatty Acids Methyl Esters (FAME), i.e. Biodiesel, or Hydrotreated Esters and Fatty Acids (HEFA), the latter representing a very high quality drop-in biofuel (suitable either for road transport or for aviation). However, extracting the algae oil at low cost and industrial scale is not yet a mature process, and there is not yet industrial production of algae-biofuel from these two lipid-based chains. Another option can however be considered: processing the algae through dedicated thermochemical reactors into advanced biofuels, thus approaching the downstream processing of algae in a completely different way than

The hard choice for alternative biofuels to diesel in Brazil.

Science.gov (United States)

Carioca, J O B; Hiluy Filho, J J; Leal, M R L V; Macambira, F S

2009-01-01

This paper selects biofuel scenarios to substitute diesel in Brazil based on oil reserves increase, diesel imports, CO(2) emissions, crops agronomic yields, byproducts marketing and social impacts. This hard task still considers that agricultural practices in developing countries have large social impacts. Brazil presents high consumption of diesel oil in transport; low agronomic yield of traditional vegetable oil crops, which demand large cultivation areas contrasting with microalgae and palm oils which present high productivity. Concerning technologies, thermal cracking and transesterification of vegetable oils present a difficult economic situation related to vegetable oils price, food competition and glycerin market; BTL technology, meaning thermal gasification of biomass to liquids, faces problems related to low density of biomaterials and low viscosity of synthetic biodiesel produced. Biorefinery algal integrated systems and co-solvent technology to introduce up to 8% of ethanol into diesel seem to be feasible routes to reduce diesel consumption.

One-pot integrated biofuel production using low-cost biocompatible protic ionic liquids

Energy Technology Data Exchange (ETDEWEB)

Sun, Jian; Konda, Murthy; Parthasarathi, Ramakrishnan; Dutta, Tanmoy; Valiev, Marat; Xu, Feng; Simmons, Blake A.; Singh, Seema

2017-01-01

The transformation of biomass into liquid fuels is of great importance. Previous work has demonstrated the capability of specific ionic liquids (ILs), such as 1-ethyl-3-methylimidazolium acetate ([C(2)C(1)Im][OAc]) and cholinium lysinate ([Ch][Lys]), to be effective biomass pretreatment solvents. Using these ILs for an integrated biomass-to-biofuel configuration is still challenging due to a significant water-wash related to the high toxicity of [C(2)C(1)Im][OAc] and pH adjustment prior to saccharification for the highly basic [Ch][Lys]. In this work, we demonstrate, for the first time, that a one-pot integrated biofuel production is enabled by a low cost (similar to$1 per kg) and biocompatible protic IL (PIL), ethanolamine acetate, without pH adjustments, water-wash and solid-liquid separations. After pretreatment, the whole slurry is directly used for simultaneous saccharification and fermentation (SSF) with commercial enzyme cocktails and wild type yeast strains, generating 70% of the theoretical ethanol yield (based on switchgrass). The structure-performance relationships of PILs in terms of lignin removal, net basicity, and pH value are systematically studied. A technoeconomic analysis (TEA) revealed that an integrated biorefinery concept based on this PIL process could potentially reduce the minimum ethanol selling price by more than 40% compared to scenarios that require pH adjustment prior to SSF. Improvement of the economic performance will be made by reducing the dilution and enzyme loading during SSF as identified by TEA. This study demonstrates the impact of a biocompatible IL in terms of process optimization and conversion efficiency, and opens up avenues for realizing an IL based efficiently integrated biomass conversion technology.

Algae as a Biofuel: Renewable Source for Liquid Fuel

Directory of Open Access Journals (Sweden)

Vijay Kant Pandey

2016-09-01

Full Text Available Biofuels produced by algae may provide a feasible alternative to fossil fuels like petroleum sourced fuels. However, looking to limited fossil fuel associated with problems, intensive efforts have been given to search for alternative biofuels like biodiesel. Algae are ubiquitous on earth, have potential to produce biofuel. However, technology of biofuel from algae facing a number of hurdles before it can compete in the fuel market and be broadly organized. Different challenges include strain identification and improvement of algal biomass, both in terms of biofuel productivity and the production of other products to improve the economics of the entire system. Algal biofuels could be made more cost effective by extracting other valuable products from algae and algal strains. Algal oil can be prepared by culture of algae on municipal and industrial wastewaters. Photobioreactors methods provide a controlled environment that can be tailored to the specific demands of high production of algae to attain a consistently good yield of biofuel. The algal biomass has been reported to yield high oil contents and have good amount of the biodiesel production capacity. In this article, it has been attempted to review to elucidate the approaches for making algal biodiesel economically competitive with respect to petrodiesel. Consequently, R & D work has been carried out for the growth, harvesting, oil extraction and conversion to biodiesel from algal sources.

Thermochemical conversion of microalgal biomass into biofuels: a review.

Science.gov (United States)

Chen, Wei-Hsin; Lin, Bo-Jhih; Huang, Ming-Yueh; Chang, Jo-Shu

2015-05-01

Following first-generation and second-generation biofuels produced from food and non-food crops, respectively, algal biomass has become an important feedstock for the production of third-generation biofuels. Microalgal biomass is characterized by rapid growth and high carbon fixing efficiency when they grow. On account of potential of mass production and greenhouse gas uptake, microalgae are promising feedstocks for biofuels development. Thermochemical conversion is an effective process for biofuel production from biomass. The technology mainly includes torrefaction, liquefaction, pyrolysis, and gasification. Through these conversion technologies, solid, liquid, and gaseous biofuels are produced from microalgae for heat and power generation. The liquid bio-oils can further be upgraded for chemicals, while the synthesis gas can be synthesized into liquid fuels. This paper aims to provide a state-of-the-art review of the thermochemical conversion technologies of microalgal biomass into fuels. Detailed conversion processes and their outcome are also addressed. Copyright © 2014 Elsevier Ltd. All rights reserved.

Production of liquid biofuels (biodiesel and bioethanol) from brown marine macroalgae Padina tetrastromatica

International Nuclear Information System (INIS)

Ashokkumar, Veeramuthu; Salim, Mohd Razman; Salam, Zainal; Sivakumar, Pandian; Chong, Cheng Tung; Elumalai, Sanniyasi; Suresh, Veeraperumal; Ani, Farid Nasir

2017-01-01

Highlights: • Integrated concept of biofuels production from brown macroalgae P. tetrastromatica. • The activation energy was determined as Ea = 34.314 kJ mol"−"1. • Brown marine alga produced 7.8% of biodiesel by acid and alkali transesterification. • The fuel properties of Padina biodiesel meet the ASTM specifications. • Spent biomass of Padina yields 16.1% of bioethanol after fermentation process. - Abstract: In this study, an integrated biomass conversion concept of producing liquid biofuels from brown marine macroalga Padina tetrastromatica was investigated. The algal biomass was collected from the Mandapam coastal region and processed under laboratory. Various parameters were studied to extract crude lipids from the biomass. A kinetic study was conducted for extracting the lipids from the biomass, which follows the first order kinetics and the lipid yield was 8.15 wt.%. The activation energy; Ea = 34.314 kJ mol"−"1 and their thermodynamic parameters were determined. Since the crude algal lipids contain high amount of free fatty acids, a sequential transesterification technique was examined and 7.8% of biodiesel (78 mg/g algal biomass) yield was obtained. The biodiesel was analyzed by "1H and "1"3C–NMR spectroscopy and the conversion yield was estimated. Further, the biodiesel fuel properties were investigated and found that all the features fit the required ASTM D6751 specification limits. The residual biomass after lipid extraction was further explored for bioethanol production through the anaerobic fermentation process. The ethanol yield obtained after saccharification and fermentation were estimated and 161 mg/g residue biomass was reported. The theoretical yield of conversion of hydrolysate to bioethanol was estimated and found to be 83.4%. Therefore, this study demonstrates that macroalga P. tetrastromatica biomass has great potential to produce liquid biofuels such as biodiesel and bioethanol.

Triacylglycerol profiling of microalgae strains for biofuel feedstock by liquid chromatography-high-resolution mass spectrometry

Energy Technology Data Exchange (ETDEWEB)

MacDougall, Karen M.; McNichol, Jesse; McGinn, Patrick J.; O' Leary, Stephen J.B.; Melanson, Jeremy E. [Institute for Marine Biosciences, National Research Council of Canada, Halifax, NS (Canada)

2011-11-15

Biofuels from photosynthetic microalgae are quickly gaining interest as a viable carbon-neutral energy source. Typically, characterization of algal feedstock involves breaking down triacylglycerols (TAG) and other intact lipids, followed by derivatization of the fatty acids to fatty acid methyl esters prior to analysis by gas chromatography (GC). However, knowledge of the intact lipid profile could offer significant advantages for discovery stage biofuel research such as the selection of an algal strain or the optimization of growth and extraction conditions. Herein, lipid extracts from microalgae were directly analyzed by ultra-high pressure liquid chromatography-mass spectrometry (UHPLC-MS) using a benchtop Orbitrap mass spectrometer. Phospholipids, glycolipids, and TAGs were analyzed in the same chromatographic run, using a combination of accurate mass and diagnostic fragment ions for identification. Using this approach, greater than 100 unique TAGs were identified over the six algal strains studied and TAG profiles were obtained to assess their potential for biofuel applications. Under the growth conditions employed, Botryococcus braunii and Scenedesmus obliquus yielded the most comprehensive TAG profile with a high abundance of TAGs containing oleic acid. (orig.)

Biofuels for transportation. From R and D to market

Energy Technology Data Exchange (ETDEWEB)

Pilo, C [comp.

1996-11-01

The aim of the Workshop was to bring together stakeholders in industry, government and science to identify technical, economic and institutional opportunities and/or barriers to the market penetration of biofuels and to tackle these issues jointly in an international environment. The Workshop was to cover the role of biofuels in replacing fossil fuels and achieving sustainable transportation. It was to be more oriented towards policy issues than towards analyses of scientific and technical details. The Workshop was focused on the conditions in Northern Europe and North America. Three main themes were chosen: THEME 1. Biomass Feedstocks. How do we produce them cost-effectively and for what purpose? THEME 2. Biofuels for Transportation. What will make them technically and economically competitive? THEME 3. Market Penetration of Biofuels. How do we remove barriers? The following biofuels were considered during the Workshop: Alcohols, such as ethanol and methanol. Ethers, such as MTBE (methyl-tertio-butyl-ether) and ETBE (ethyl-tertio-butyl-ether). Vegetable oils and esters, such as VME (vegetable-oil-methylester), RME (rape-oil-methyl-ester) and REE (rape-oil-ethyl-ester)

Biofuels for transport

International Nuclear Information System (INIS)

2004-01-01

In the absence of strong government policies, the IEA projects that the worldwide use of oil in transport will nearly double between 2000 and 2030, leading to a similar increase in greenhouse gas emissions. Biofuels, such as ethanol, bio-diesel, and other liquid and gaseous fuels, could offer an important alternative to petroleum over this time frame and help reduce atmospheric pollution. This book looks at recent trends in biofuel production and considers what the future might hold if such alternatives were to displace petroleum in transport. The report takes a global perspective on the nascent biofuels industry, assessing regional similarities and differences as well as the cost and benefits of the various initiatives being undertaken around the world. In the short term, conventional biofuel production processes in IEA countries could help reduce oil use and thence greenhouse gas emissions, although the costs may be high. In the longer term, possibly within the next decade, advances in biofuel production and the use of new feedstocks could lead to greater, more cost-effective reductions. Countries such as Brazil are already producing relatively low-cost biofuels with substantial reductions in fossil energy use and greenhouse gas emissions. This book explores the range of options on offer and asks whether a global trade in biofuels should be more rigorously pursued

National Algal Biofuels Technology Roadmap

Energy Technology Data Exchange (ETDEWEB)

Ferrell, John [Dept. of Energy (DOE), Washington DC (United States); Sarisky-Reed, Valerie [Dept. of Energy (DOE), Washington DC (United States)

2010-05-01

The framework for National Algal Biofuels Technology Roadmap was constructed at the Algal Biofuels Technology Roadmap Workshop, held December 9-10, 2008, at the University of Maryland-College Park. The Workshop was organized by the Biomass Program to discuss and identify the critical challenges currently hindering the development of a domestic, commercial-scale algal biofuels industry. This Roadmap presents information from a scientific, economic, and policy perspectives that can support and guide RD&D investment in algal biofuels. While addressing the potential economic and environmental benefits of using algal biomass for the production of liquid transportation fuels, the Roadmap describes the current status of algae RD&D. In doing so, it lays the groundwork for identifying challenges that likely need to be overcome for algal biomass to be used in the production of economically viable biofuels.

Towards Sustainable Production of Biofuels from Microalgae

Directory of Open Access Journals (Sweden)

Hans Ragnar Giselrød

2008-07-01

Full Text Available Renewable and carbon neutral biofuels are necessary for environmental and economic sustainability. The viability of the first generation biofuels production is however questionable because of the conflict with food supply. Microalgal biofuels are a viable alternative. The oil productivity of many microalgae exceeds the best producing oil crops. This paper aims to analyze and promote integration approaches for sustainable microalgal biofuel production to meet the energy and environmental needs of the society. The emphasis is on hydrothermal liquefaction technology for direct conversion of algal biomass to liquid fuel.

Potentials of biofuels

Energy Technology Data Exchange (ETDEWEB)

Munack, A.; Schroder, O. [Johann Heinrich von Thunen Inst., Braunschweig (Germany); Krahl, J. [Coburg Univ. of Applied Sciences, Coburg (Germany); Bunger, J. [Inst. for Prevention and Occupational Medicine of the German Social Accident Insurance, Ruhr-Univ. Inst., Bochum (Germany)

2010-07-01

This paper discussed the potential of biofuels with particular reference to the situation in Germany and Europe. Emphasis was on technical potential, such as biofuel production, utilization and environmental aspects. The Institute of Agricultural Technology and Biosystems Engineering ran vTI emission tests on diesel engines to evaluate the environmental impacts of biofuels. This testing facility is able to drive heavy-duty diesel engines in both stationary and dynamic test cycles, such as the European ESC and ETC. Additional analyses were conducted to determine the fine and ultra-fine particles, polycyclic aromatic hydrocarbons (PAH), aldehydes, ketones, and the usual regulated exhaust gas compounds. Ames tests were conducted to assess the mutagenic potential of tailpipe emissions. Previous study results showed that neat vegetable oils can render the exhaust high in mutagenic potency. Some of the non-regulated exhaust gas compounds were found to vary nonlinearly with the blend composition. B20 was found to have high mutagenic potential and was subject to sedimentation.

Biofuels and sustainability.

Science.gov (United States)

Solomon, Barry D

2010-01-01

Interest in liquid biofuels production and use has increased worldwide as part of government policies to address the growing scarcity and riskiness of petroleum use, and, at least in theory, to help mitigate adverse global climate change. The existing biofuels markets are dominated by U.S. ethanol production based on cornstarch, Brazilian ethanol production based on sugarcane, and European biodiesel production based on rapeseed oil. Other promising efforts have included programs to shift toward the production and use of biofuels based on residues and waste materials from the agricultural and forestry sectors, and perennial grasses, such as switchgrass and miscanthus--so-called cellulosic ethanol. This article reviews these efforts and the recent literature in the context of ecological economics and sustainability science. Several common dimensions for sustainable biofuels are discussed: scale (resource assessment, land availability, and land use practices); efficiency (economic and energy); equity (geographic distribution of resources and the "food versus fuel" debate); socio-economic issues; and environmental effects and emissions. Recent proposals have been made for the development of sustainable biofuels criteria, culminating in standards released in Sweden in 2008 and a draft report from the international Roundtable on Sustainable Biofuels. These criteria hold promise for accelerating a shift away from unsustainable biofuels based on grain, such as corn, and toward possible sustainable feedstock and production practices that may be able to meet a variety of social, economic, and environmental sustainability criteria.

Biofuels: stakes, perspectives and researches; Biocarburants: enjeux, perspectives et recherches

Energy Technology Data Exchange (ETDEWEB)

Appert, O.; Ballerin, D.; Montagne, X.

2004-07-01

The French institute of petroleum (IFP) is a major intervener of the biofuels sector, from the production to the end-use in engines. In this press conference, the IFP takes stock of the technological, environmental and economical stakes of today and future biofuel production processes and of their impact on transports. This document gathers 2 presentations dealing with: IFP's research strategy on biofuels (transparencies: context; today's processes: ethanol, ETBE, bio-diesel; tomorrows processes: biomass to liquid; perspectives), bio-diesel fuel: the Axens process selected by Diester Industrie company for its Sete site project of bio-diesel production unit. The researches carried out at the IFP on biofuels and biomass are summarized in an appendix: advantage and drawbacks of biofuels, the ethanol fuel industry, the bio-diesel industry, biomass to liquid fuels, French coordinated research program, statistical data of biofuel consumption in France, Spain and Germany. (J.S.)

Biofuels. Environment, technology and food security

International Nuclear Information System (INIS)

Escobar, Jose C.; Lora, Electo S.; Venturini, Osvaldo J.; Yanez, Edgar E.; Castillo, Edgar F.; Almazan, Oscar

2009-01-01

The imminent decline of the world's oil production, its high market prices and environmental impacts have made the production of biofuels to reach unprecedent volumes over the last 10 years. This is why there have been intense debates among international organizations and political leaders in order to discuss the impacts of the biofuel use intensification. Besides assessing the causes of the rise in the demand and production of biofuels, this paper also shows the state of the art of their world's current production. It is also discussed different vegetable raw materials sources and technological paths to produce biofuels, as well as issues regarding production cost and the relation of their economic feasibility with oil international prices. The environmental impacts of programs that encourage biofuel production, farmland land requirements and the impacts on food production are also discussed, considering the life cycle analysis (LCA) as a tool. It is concluded that the rise in the use of biofuels is inevitable and that international cooperation, regulations and certification mechanisms must be established regarding the use of land, the mitigation of environmental and social impacts caused by biofuel production. It is also mandatory to establish appropriate working conditions and decent remuneration for workers of the biofuels production chain. (author)

BIOFUEL PRODUCTION FROM PALM OLEIN BY CATALYTIC CRACKING PROCESS USING ZSM-5 CATALYST

Directory of Open Access Journals (Sweden)

Rondang Tambun

2017-06-01

Full Text Available The depletion of fossil energy reserves raises the potential in the development of renewable fuels from vegetable oils. Indonesia is the largest palm oil producer in the world, where palm oil can be converted into biofuels such as biogasoline, kerosene and biodiesel. These biofuels are environmentally friendly and free of the content of nitrogen and sulfur through catalytic cracking process. In this research, palm olein is used as feedstock using catalytic cracking process. ZSM-5 is used as a catalyst, which has a surface area of 425 m2/g and Si/Al ratio of 50. Variables varied are the operating temperature of 375 oC - 450 °C and reaction time of 60 minutes - 150 minutes. The result shows that the highest yield of liquid product is 84.82%. This yield is obtained at a temperature of 400 °C and reaction time of 120 minutes. The yield of the liquid product in the operating conditions consisting of C6-C12 amounted to 19.47 %, C14-C16 amounted to 16.56 % and the C18-C28 amounted to 48.80 %.

Microwave-assisted ionic liquid-mediated rapid catalytic conversion of non-edible lignocellulosic Sunn hemp fibres to biofuels.

Science.gov (United States)

Paul, Souvik Kumar; Chakraborty, Saikat

2018-04-01

Sunn hemp fibre - a cellulose-rich crystalline non-food energy crop, containing 75.6% cellulose, 10.05% hemicellulose, 10.32% lignin, with high crystallinity (80.17%) and degree of polymerization (650) - is identified as a new non-food substrate for lignocellulosic biofuel production. Microwave irradiation is employed to rapidly rupture the cellulose's glycosidic bonds and enhance glucose yield to 78.7% at 160 °C in only 46 min. The reactants - long-chain cellulose, ionic liquid, transition metal catalyst, and water - form a polar supramolecular complex that rotates under the microwave's alternating polarity and rapidly dissipates the electromagnetic energy through molecular collisions, thus accelerating glycosidic bond breakage. In 46 min, 1 kg of Sunn hemp fibres containing 756 g of cellulose produces 595 g of glucose at 160 °C, and 203 g of hydroxymethyl furfural (furanic biofuel precursor) at 180 °C. Yeast mediated glucose fermentation produces 75.6% bioethanol yield at 30 °C, and the ionic liquid is recycled for cost-effectiveness. Copyright © 2018 Elsevier Ltd. All rights reserved.

Recommendations for a sustainable development of biofuels in France

International Nuclear Information System (INIS)

Douaud, A.; Gruson, J.F.

2006-01-01

The biofuels are presented as a solution to the greenhouse gases and the petroleum consumption decrease. The development of the biofuels needs an active research of the production, transformation and use costs improvement. It will be necessary to prepare the market of the biofuels to the globalization. Some recommendations are also provided in the domains of the vegetal oil ester, the ethanol for the diesel and for the development of simulation tools to evaluate the costs. (A.L.B.)

Highly effective ionic liquids for biodiesel production from waste vegetable oils

Directory of Open Access Journals (Sweden)

Fathy A. Yassin

2015-03-01

Full Text Available As conventional energy sources deplete, the need for developing alternative energy resources which are environment friendly becomes more imperative. Vegetable oils are attracting increased interest in this purpose. The methanolysis of vegetable oil to produce a fatty acid methyl ester (FAME, i.e., biodiesel fuel was catalyzed by commercial ionic liquid and its chloride modification. The imidazolium chloride ionic liquid was frequently chosen for the synthesis of biodiesel. The dual-functionalized’ ionic liquid is prepared by a direct combination reaction between imidazolium cation and various metal chlorides such as CoCl2, CuCl2, NiCl2, FeCl3 and AlCl3. Imidazolium tetrachloroferrate was proved to be a selective catalyst for the methanolysis reaction at a yield of 97% when used at 1:10, catalyst: oil ratio for 8 h at 55 °C. Operational simplicity, reusability of the used catalyst for 8 times at least, high yields and no saponification are the key features of this methodology. The dynamic viscosity and density of the upgraded vegetable oil decreased from 32.1 cP and 0.9227 g/cm3 to 10.2 cP and 0.9044 g/cm3 respectively, compared to those of the base vegetable oil. The objective of this study was the synthesis and characterization of biodiesel using commercial ionic liquid and its chloride modification. The ionic liquid catalysts were characterized using FTIR, Raman spectroscopy, DSC, TG and UV.

State-of-art in liquid biofuels

Energy Technology Data Exchange (ETDEWEB)

Poitrat, E. [Agency for Environment and Energy Management, Dept. of Agriculture and Bioenergies, Paris (France)

2001-09-01

European production of fuel alcohol/ETBE and VOME has now become significant and the research work undertaken i) to reduce the energy requirements and financial costs and ii) to improve environmental benefits, are of major importance. While optimisation still seems necessary, the gain to be achieved should come from the valorisation of co-products and increasing the size of production plants. Larger production plants will make it possible to implement techniques with higher investment costs but having greater energy efficiency. For VOME, the importance of the cost of producing the agricultural feedstock remains very critical, more so than the size of the industrial plant where the size of new plants (100 000 tons up to 250 000 tons) seems a good compromise. Wider use of biofuels will also depend on agricultural policy (setaside status), tax system and harmonisation of the European legislation on oxyfuels. It will improve the greenhouse effect in harmony with the KYOTO agreement. Environmental impacts, and more particularly their quantification in terms of externalities, remain a very crucial topic. In this situation, the quantity of produced biofuels is or will be more 2 millions tons now, including forecasted quantities, which represent 11% of the objective by 2010. Otherwise, the repartition of this current production is very unequal between the different countries of EC. The first production is planned by Germany with 1 millions tons, the second by France with 570 000 tons and the third by Spain with 306 000 tons. Smaller quantities are linked at Italy, Austria, Sweden and Belgium. Other countries have not biofuels production currently. (au)

Life cycle analyses applied to first generation bio-fuels consumed in France

International Nuclear Information System (INIS)

2010-01-01

This rather voluminous publication reports detailed life cycle analyses for the different present bio-fuels channels also named first-generation bio-fuels: bio-ethanol, bio-diesel, pure vegetal oils, and oil. After a recall of the general principles adopted for this life-cycle analysis, it reports the modelling of the different channels (agricultural steps, bio-fuel production steps, Ethyl tert-butyl ether or ETBE steps, vehicles, animal fats and used vegetal oils, soil assignment change). It gives synthetic descriptions of the different production ways (methyl ester from different plants, ethanol from different plants). It reports and compares the results obtained in terms of performance

Round table on bio-fuels

International Nuclear Information System (INIS)

2005-11-01

The French ministers of agriculture and of industry have organized a meeting with the main French actors of agriculture, petroleum industry, car making and accessories industry and with professionals of agriculture machines to encourage the development of bio-fuels in France. This meeting took place in Paris in November 21, 2005. Its aim was to favor the partnerships between the different actors and the public authorities in order to reach the ambitious goals of the government of 5.75% of bio-fuels in fossil fuels by 2008, 7% by 2010 and 10% by 2015. The main points discussed by the participants were: the compatibility of automotive fuel standards with the objectives of bio-fuel incorporation, the development of direct incorporation of methanol in gasoline, the ethanol-ETBE partnership, the question of the lower calorific value of ETBE (ethyl tertio butyl ether), the development of new bio-fuels, the development of bio-diesel and the specific case of pure vegetal oils, and the fiscal framework of bio-fuels. This meeting has permitted to reach important improvements with 15 concrete agreements undertaken by the participants. (J.S.)

[Biofuels, food security and transgenic crops].

Science.gov (United States)

Acosta, Orlando; Chaparro-Giraldo, Alejandro

2009-01-01

Soaring global food prices are threatening to push more poor people back below the poverty line; this will probably become aggravated by the serious challenge that increasing population and climate changes are posing for food security. There is growing evidence that human activities involving fossil fuel consumption and land use are contributing to greenhouse gas emissions and consequently changing the climate worldwide. The finite nature of fossil fuel reserves is causing concern about energy security and there is a growing interest in the use of renewable energy sources such as biofuels. There is growing concern regarding the fact that biofuels are currently produced from food crops, thereby leading to an undesirable competition for their use as food and feed. Nevertheless, biofuels can be produced from other feedstocks such as lingo-cellulose from perennial grasses, forestry and vegetable waste. Biofuel energy content should not be exceeded by that of the fossil fuel invested in its production to ensure that it is energetically sustainable; however, biofuels must also be economically competitive and environmentally acceptable. Climate change and biofuels are challenging FAO efforts aimed at eradicating hunger worldwide by the next decade. Given that current crops used in biofuel production have not been domesticated for this purpose, transgenic technology can offer an enormous contribution towards improving biofuel crops' environmental and economic performance. The present paper critically presents some relevant relationships between biofuels, food security and transgenic plant technology.

Scope of algae as third generation biofuels

Directory of Open Access Journals (Sweden)

Shuvashish eBehera

2015-02-01

Full Text Available An initiative has been taken to develop different solid, liquid and gaseous biofuels as the alternative energy resources. The current research and technology based on the third generation biofuels derived from algal biomass have been considered as the best alternative bioresource that avoids the disadvantages of first and second generation biofuels. Algal biomass have been investigated for the implementation of economic conversion processes producing different biofuels such as biodiesel, bioethanol, biogas, biohydrogen and other valuable co-products. In the present review, the recent findings and advance developments in algal biomass for improved biofuel production. This review discusses about the importance of the algal cell contents, various strategies for product formation through various conversion technologies, and its future scope as an energy security.

Land use competition for production of food and liquid biofuels. An analysis of the arguments in the current debate

Energy Technology Data Exchange (ETDEWEB)

Rathmann, Regis; Szklo, Alexandre; Schaeffer, Roberto [Energy Planning Program, Graduate School of Engineering, Federal University of Rio de Janeiro, Centro de Tecnologia, Bloco C, Sala 211, Cidade Universitaria, Ilha do Fundao, Rio de Janeiro, RJ 21941-972 (Brazil)

2010-01-15

This article analyses the current state of the debate over competition for land use, by means of an index of the main arguments in favor and against the production of liquid biofuels and the impacts on food production. Based on this index, an analytic framework is constructed to establish the causal relations indicated by the existing studies on this competition. We find that the emergence of agro-energy has altered the land use dynamic, albeit not yet significantly, with a shift of areas traditionally used to grow foods over to crops to produce biofuels. This has been contributing to raise food prices in the short run. However, it is probable that this is not the only factor determining this trend, nor will it last over the long run. The challenge is to conciliate the production of biofuels with the production of foods in sustainable form. (author)

Current Challenges in Commercially Producing Biofuels from Lignocellulosic Biomass

Science.gov (United States)

Balan, Venkatesh

2014-01-01

Biofuels that are produced from biobased materials are a good alternative to petroleum based fuels. They offer several benefits to society and the environment. Producing second generation biofuels is even more challenging than producing first generation biofuels due the complexity of the biomass and issues related to producing, harvesting, and transporting less dense biomass to centralized biorefineries. In addition to this logistic challenge, other challenges with respect to processing steps in converting biomass to liquid transportation fuel like pretreatment, hydrolysis, microbial fermentation, and fuel separation still exist and are discussed in this review. The possible coproducts that could be produced in the biorefinery and their importance to reduce the processing cost of biofuel are discussed. About $1 billion was spent in the year 2012 by the government agencies in US to meet the mandate to replace 30% existing liquid transportation fuels by 2022 which is 36 billion gallons/year. Other countries in the world have set their own targets to replace petroleum fuel by biofuels. Because of the challenges listed in this review and lack of government policies to create the demand for biofuels, it may take more time for the lignocellulosic biofuels to hit the market place than previously projected. PMID:25937989

The second generation of biofuels aims at 2015; La seconde generation de biocarburants vise 2015

Energy Technology Data Exchange (ETDEWEB)

Orliac, A

2008-12-15

Research work is intensifying on the second generation of biofuels in order to optimize the processes and to reduce the production costs. Poorly valorized vegetable resources are targeted in order to avoid conflicts with other agricultural processes. Two ways are explored since several years: the biological way (bio-ethanol) and the thermochemical way (bio-diesel). So far, no method allows to recover oils with a satisfactory energy efficiency but several pilot-plants are under study or already in operation (Futurol, BTL (biomass-to-liquid)..). Short paper. (J.S.)

Scanning the macro-environment for liquid biofuels: A comparative analysis from public pocies in Brazil, United States and Germany

NARCIS (Netherlands)

Talamini, E.; Wubben, E.F.M.; Padula, A.D.; Dewes, H.

2013-01-01

Purpose – Macro-environmental scanning is a first step in strategic planning, which is essential in an emerging industry such as liquid biofuels. The purpose of this paper is to identify the dimensions within which the governments of Brazil, the USA and Germany have constructed the macro-environment

Allies in Biofuels. Opportunities in the Dutch - Argentinean biofuels trade relation

International Nuclear Information System (INIS)

Verhagen, M.

2007-01-01

First generation biofuels as an environmental solution are showing their own negative environmental, social and economic side effects. These need to be dealt with, because it is apparent that those same biofuels can be produced in a sustainable manner, thereby contributing to a healthier planet. Since both Argentina and the Netherlands would benefit from sustainable biofuels trade, policy measures need to be taken to guide the proper way. In what manner could bilateral cooperation concerning biofuels, optimize trade and policy output in both countries? By answering this question, one can hand solutions to upcoming problems - barriers to a sustainable energy structure - while at the same time facilitating trade between Argentina and the Netherlands. Besides providing information about the European, Dutch and Argentine market, this report presents an overview of biofuel policies. Special attention is given to the issue of sustainable biofuel production, in order to spread the necessary awareness, create wide support for corresponding politics, and offer opportunities for cooperation to prevent future entrapment. An entrapment, which could easily occur when actors in politics and business ignore international requirements for sustainable biofuel production. The research aims to produce the following output: Policy recommendations regarding the promotion of environmentally sound biofuels in both countries; A set arena to support a policy dialogue between both countries; An overview of current Dutch and Argentinean biofuel policies; Up to date information on current volumes of production, consumption and trade; Data with contact information of partners in both countries. Argentina shows an extremely professional agricultural sector, producing large quantities of vegetable oils, specifically of soybean. This sector has started to turn its attention towards biofuels - particularly to biodiesel. Projected production (for 2007-2008) is astonishingly high. The sector mainly

Competitive liquid biofuels from biomass

International Nuclear Information System (INIS)

Demirbas, Ayhan

2011-01-01

The cost of biodiesels varies depending on the feedstock, geographic area, methanol prices, and seasonal variability in crop production. Most of the biodiesel is currently made from soybean, rapeseed, and palm oils. However, there are large amounts of low-cost oils and fats (e.g., restaurant waste, beef tallow, pork lard, and yellow grease) that could be converted to biodiesel. The crop types, agricultural practices, land and labor costs, plant sizes, processing technologies and government policies in different regions considerably vary ethanol production costs and prices by region. The cost of producing bioethanol in a dry mill plant currently totals US$1.65/galon. The largest ethanol cost component is the plant feedstock. It has been showed that plant size has a major effect on cost. The plant size can reduce operating costs by 15-20%, saving another $0.02-$0.03 per liter. Thus, a large plant with production costs of $0.29 per liter may be saving $0.05-$0.06 per liter over a smaller plant. Viscosity of biofuel and biocrude varies greatly with the liquefaction conditions. The high and increasing viscosity indicates a poor flow characteristic and stability. The increase in the viscosity can be attributed to the continuing polymerization and oxidative coupling reactions in the biocrude upon storage. Although stability of biocrude is typically better than that of bio-oil, the viscosity of biocrude is much higher. The bio-oil produced by flash pyrolysis is a highly oxygenated mixture of carbonyls, carboxyls, phenolics and water. It is acidic and potentially corrosive. Bio-oil can also be potentially upgraded by hydrodeoxygenation. The liquid, termed biocrude, contains 60% carbon, 10-20 wt.% oxygen and 30-36 MJ/kg heating value as opposed to <1 wt.% and 42-46 MJ/kg for petroleum. (author)

Competitive liquid biofuels from biomass

Energy Technology Data Exchange (ETDEWEB)

Demirbas, Ayhan [Sirnak University, Dean of Engineering Faculty, Department of Mechanical Engineering, Sirnak (Turkey)

2011-01-15

The cost of biodiesels varies depending on the feedstock, geographic area, methanol prices, and seasonal variability in crop production. Most of the biodiesel is currently made from soybean, rapeseed, and palm oils. However, there are large amounts of low-cost oils and fats (e.g., restaurant waste, beef tallow, pork lard, and yellow grease) that could be converted to biodiesel. The crop types, agricultural practices, land and labor costs, plant sizes, processing technologies and government policies in different regions considerably vary ethanol production costs and prices by region. The cost of producing bioethanol in a dry mill plant currently totals US$1.65/galon. The largest ethanol cost component is the plant feedstock. It has been showed that plant size has a major effect on cost. The plant size can reduce operating costs by 15-20%, saving another $0.02-$0.03 per liter. Thus, a large plant with production costs of $0.29 per liter may be saving $0.05-$0.06 per liter over a smaller plant. Viscosity of biofuel and biocrude varies greatly with the liquefaction conditions. The high and increasing viscosity indicates a poor flow characteristic and stability. The increase in the viscosity can be attributed to the continuing polymerization and oxidative coupling reactions in the biocrude upon storage. Although stability of biocrude is typically better than that of bio-oil, the viscosity of biocrude is much higher. The bio-oil produced by flash pyrolysis is a highly oxygenated mixture of carbonyls, carboxyls, phenolics and water. It is acidic and potentially corrosive. Bio-oil can also be potentially upgraded by hydrodeoxygenation. The liquid, termed biocrude, contains 60% carbon, 10-20 wt.% oxygen and 30-36 MJ/kg heating value as opposed to <1 wt.% and 42-46 MJ/kg for petroleum. (author)

Biofuels: What potential for development?

International Nuclear Information System (INIS)

Alazard-Toux, Nathalie

2010-01-01

The current production chain of the first generation of biofuels has quite real limits. To overcome them, efforts are being made to develop processes for converting vegetable resources of little worth into fuel. This research focuses both on these resources and on the technology and processes for turning them into fuel

Biofuel characteristics of beniseed (Sesanum indicum) oil

African Journals Online (AJOL)

SERVER

2007-11-05

Nov 5, 2007 ... Local method was used to extract oil from beniseed (Sesanum indicum). ... fuel properties similar to common biofuels, hence beniseed could be utilized as an .... industries for the manufacture of soap and vegetable oil –.

Vegetable oil based liquid nanocomposite dielectric

Directory of Open Access Journals (Sweden)

Leon Chetty

2013-01-01

Full Text Available Physically smaller dielectric materials would improve the optimisation of space for power systems. Development of nanotechnology provides an effective way to improve the performances of insulating oils used in power system applications. In this research study, we focused on the development of nanomodified vegetable oils to be used in power transformers. Higher conduction currents were observed in virgin linseed oil than in virgin castor oil. However, for both virgin linseed and virgin castor oil, the DC conduction current increased approximately linearly with the applied DC voltage. In nanomodified linseed oil, the characteristic curve showed two distinct regions: a linear region (at lower applied voltage and a saturation region (at slightly higher voltage. Conversely, in nanomodified castor oil, the characteristic curve showed three distinct regions: a linear region (at lower applied voltage, a saturation region (at intermediate applied voltage and an exponential growth region (at higher applied voltage. The nanomodified linseed oil exhibited a better dielectric performance than the nanomodified castor oil. Overall, the addition of nanodielectrics to vegetable oils decreased the dielectric performance of the vegetable oils. The results of this study contribute to the understanding of the pre-breakdown phenomenon in liquid nanocomposite dielectrics.

Assay in engine of agricultural tractor with biofuel

Energy Technology Data Exchange (ETDEWEB)

Lopes, Reny Adilmar Prestes; Meyer, Wagner [Universidade Estadual de Maringa (DEA/CCA/UEM), Cidade Gaucha, PR (Brazil). Centro de Ciencias Agrarias. Dept. de Engenharia Agricola], E-mail: raplopes@uem.br; Pinheiro Neto, Raimundo; Pinheiro, Andreia Cristina [Universidade Estadual de Maringa (DAG/CCA/UEM), PR (Brazil). Centro de Ciencias Agrarias. Dept. de Agronomia; Laurindo, Jose Carlos [Instituto de Tecnologia do Parana (CERBIO/TECPAR), Curitiba, PR (Brazil). Centro Brasileiro de Referencia em Biocombustiveis; Biazzono, Sergio Luis [Instituto de Tecnologia do Parana (TECPAR), Maringa, PR (Brazil). Inspecao Veicular

2008-07-01

The use of biofuel in tractors of diesel engines and agricultural harvester, in the operations of soil preparation and harvest, is a good option of fuel economy for the agriculturist. For a good performance of the machine a good regulation is necessary. The experiment was carried through in the Experimental Farm Iguatemi of the State University of Maringa, Maringa - PR. A tractor Massey Ferguson MF275 was used for the assay connected to be even grating. It carried through if the assays of consumption of diesel (100%) and biofuel (diesel 80% + vegetable oil 20%). To carry through the assay tractor + grating with three openings and without load was used to be even set. The rotation without load and of work was of 1900 rpm and mean speed of 6 km h{sup -1}. The hourly consumption was verified by a test tube and a fluxgate OVAL Flow mate M III - LSF 45L0-M2 connected to data logger CR23X. The hourly consumption was express in L h{sup -1}. The engine of the tractor presented similar behavior of fuel consumption for diesel and biofuel. The mean values of consumption had been inside of the specified one for the manufacturer. Mixture 80% diesel + 20% vegetable oil can be used as biofuel in the engine in study. (author)

Biofuels - the UFIP position

International Nuclear Information System (INIS)

2004-01-01

Since 2003 a directive promote the biofuels use. The industry is then using them in ETBE (Ethyl Tertio Butyl Ether) fuels and in diesel oil of vegetal oils esters EMHV. Meanwhile some of them present technical difficulties and must free themselves from fiscal incentives which make them competitive. For these reasons, the UFIP (french union of petroleum industries) do not agree their obligatory incorporation. (A.L.B.)

Engineering ionic liquid-tolerant cellulases for biofuels production.

Science.gov (United States)

Wolski, Paul W; Dana, Craig M; Clark, Douglas S; Blanch, Harvey W

2016-04-01

Dissolution of lignocellulosic biomass in certain ionic liquids (ILs) can provide an effective pretreatment prior to enzymatic saccharification of cellulose for biofuels production. Toward the goal of combining pretreatment and enzymatic hydrolysis, we evolved enzyme variants of Talaromyces emersonii Cel7A to be more active and stable than wild-type T. emersonii Cel7A or Trichoderma reesei Cel7A in aqueous-IL solutions (up to 43% (w/w) 1,3-dimethylimdazolium dimethylphosphate and 20% (w/w) 1-ethyl-3-methylimidazolium acetate). In general, greater enzyme stability in buffer at elevated temperature corresponded to greater stability in aqueous-ILs. Post-translational modification of the N-terminal glutamine residue to pyroglutamate via glutaminyl cyclase enhanced the stability of T. emersonii Cel7A and variants. Differential scanning calorimetry revealed an increase in melting temperature of 1.9-3.9°C for the variant 1M10 over the wild-type T. emersonii Cel7A in aqueous buffer and in an IL-aqueous mixture. We observed this increase both with and without glutaminyl cyclase treatment of the enzymes. © The Author 2016. Published by Oxford University Press. All rights reserved. For Permissions, please e-mail: journals.permissions@oup.com.

Biofuels and Biotechnology

Energy Technology Data Exchange (ETDEWEB)

Mielenz, Jonathan R [ORNL

2009-01-01

The world obtains 86% of its energy from fossil fuels, 40% from petroleum, a majority of which goes to the transportation sector (www.IEA.gov). Well-recognized alternatives are fuels derived from renewable sources known as biofuels. There are a number of biofuels useful for transportation fuels, which include ethanol, biobutanol, mixed alcohols, biodiesel, and hydrogen. These biofuels are produced from biologically derived feedstock, almost exclusively being plant materials, either food or feed sources or inedible plant material called biomass. This chapter will discuss technologies for production of liquid transportation biofuels from renewable feedstocks, but hydrogen will not be included, as the production technology and infrastructure are not near term. In addition, a specific emphasis will be placed upon the research opportunities and potential for application of system biology tools to dissect and understand the biological processes central to production of these biofuels from biomass and biological materials. There are a number of technologies for production of each of these biofuels that range from fully mature processes such as grain-derived ethanol, emerging technology of ethanol form cellulose derived ethanol and immature processes such thermochemical conversion technologies and production of hydrogen all produced from renewable biological feedstocks. Conversion of biomass by various thermochemical and combustion technologies to produce thermochemical biodiesel or steam and electricity provide growing sources of bioenergy. However, these technologies are outside of the scope of this chapter, as is the use of biological processing for upgrading and conversion of fossil fuels. Therefore, this chapter will focus on the current status of production of biofuels produced from biological-derived feedstocks using biological processes. Regardless of the status of development of the biological process for production of the biofuels, each process can benefit from

Bio-fuels for the gas turbine: A review

International Nuclear Information System (INIS)

Gupta, K.K.; Rehman, A.; Sarviya, R.M.

2010-01-01

Due to depletion of fossil fuel, bio-fuels have generated a significant interest as an alternative fuel for the future. The use of bio-fuels to fuel gas turbine seems a viable solution for the problems of decreasing fossil-fuel reserves and environmental concerns. Bio-fuels are alternative fuels, made from renewable sources and having environmental benefit. In recent years, the desire for energy independence, foreseen depletion of nonrenewable fuel resources, fluctuating petroleum fuel costs, the necessity of stimulating agriculture based economy, and the reality of climate change have created an interest in the development of bio-fuels. The application of bio-fuels in automobiles and heating applications is increasing day by day. Therefore the use of these fuels in gas turbines would extend this application to aviation field. The impact of costly petroleum-based aviation fuel on the environment is harmful. So the development of alternative fuels in aviation is important and useful. The use of liquid and gaseous fuels from biomass will help to fulfill the Kyoto targets concerning global warming emissions. In addition, to reduce exhaust emission waste gases and syngas, etc., could be used as a potential gas turbine fuel. The term bio-fuel is referred to alternative fuel which is produced from biomass. Such fuels include bio-diesel, bio-ethanol, bio-methanol, pyrolysis oil, biogas, synthetic gas (dimethyl ether), hydrogen, etc. The bio-ethanol and bio-methanol are petrol additive/substitute. Bio-diesel is an environment friendly alternative liquid fuel for the diesel/aviation fuel. The gas turbine develops steady flame during its combustion; this feature gives a flexibility to use alternative fuels. Therefore so the use of different bio-fuels in gas turbine has been investigated by a good number of researchers. The suitability and modifications in the existing systems are also recommended. (author)

Biofuels and biodiversity in South Africa

Directory of Open Access Journals (Sweden)

Patrick J. O’Farrell

2011-05-01

Full Text Available The South African government, as part of its efforts to mitigate the effects of the ongoing energy crisis, has proposed that biofuels should form an important part of the country’s energy supply. The contribution of liquid biofuels to the national fuel supply is expected to be at least 2% by 2013. The Biofuels Industrial Strategy of the Republic of South Africa of 2007 outlines key incentives for reaching this target and promoting the development of a sustainable biofuels industry. This paper discusses issues relating to this strategy as well as key drivers in biofuel processing with reference to potential impacts on South Africa’s rich biological heritage.

Our understanding of many of the broader aspects of biofuels needs to be enhanced. We identify key areas where challenges exist, such as the link between technology, conversion processes and feedstock selection. The available and proposed processing technologies have important implications for land use and the use of different non-native plant species as desired feedstocks. South Africa has a long history of planting non-native plant species for commercial purposes, notably for commercial forestry. Valuable lessons can be drawn from this experience on mitigation against potential impacts by considering plausible scenarios and the appropriate management framework and policies. We conceptualise key issues embodied in the biofuels strategy, adapting a framework developed for assessing and quantifying impacts of invasive alien species. In so doing, we provide guidelines for minimising the potential impacts of biofuel projects on biodiversity.

Bio-fuels: European Communities fiscal initiatives

International Nuclear Information System (INIS)

Autrand, A.

1992-01-01

This paper first reviews the influence that European Communities fiscal policies have had in the past on the development of more environmentally compatible fuels such as unleaded gasoline. It then discusses which directions fiscal policy makers should take in order to create appropriate financial incentives encouraging the production and use of biomass derived fuels - methanol, ethanol and pure and transesterified vegetable oils. An assessment is made of the efficacy of a recent European Communities proposal which calls for the application of excise tax reductions on bio-fuels. Attention is given to the net effects due to reduced sulfur and carbon dioxide emissions characterizing bio-fuels and the increased use of fertilizers necessary to produce biomass fuels

The blue water footprint and land use of biofuels from algae

NARCIS (Netherlands)

Gerbens-Leenes, Winnie; Xu, L.; de Vries, G.J.; Hoekstra, Arjen Ysbert

2014-01-01

Biofuels from microalgae are potentially important sources of liquid renewable energy. Algae are not yet produced on a large scale, but research shows promising results. This study assesses the blue water footprint (WF) and land use of algae-based biofuels. It combines the WF concept with an energy

Biofuels made easy

International Nuclear Information System (INIS)

Hamilton, C.

2004-01-01

Much has been said and written in Australia since the Federal Government introduced its Clean Fuels Policy in September 2001. Various biofuel projects are now being considered in different states of Australia for the manufacture of bioethanol and biodiesel from renewable resources. However, the economic viability required to establish an Australian liquid biofuels industry is predicated on supportive government legislation and an encouraging fuel excise regime. On the other hand, the benefits of such an industry are also in debate. In an attempt to clarify some of the concerns being raised, this paper endeavours to provide an overview of the current use of bioethanol and biodiesel around the world, to summarise the process technologies involved, to review the benefits and non-benefits of renewable fuels to the transport industry and to address the issues for such an industry here in Australia

An economic analysis of a major bio-fuel program undertaken by OECD countries

International Nuclear Information System (INIS)

2002-01-01

Biofuels such as ethanol and bio-diesel are creating a new demand for agricultural output and for agriculture land in Canada. However, the participation of other large countries with a large demand potential is necessary for bio-fuels to have a significant impact on the price of grains and oilseeds. This paper quantified the potential impact that a major bio-fuel program initiated by OECD countries has on grain and oilseed prices. The program was initiated for the period 1999 to 2006. There is considerable interest by Canadian producers to stimulate grain and oilseed prices by increasing demand of biofuels. This renewable energy source produces fewer greenhouse gas emissions than petroleum products. The analysis presented in this paper only considered ethanol from corn or wheat and bio-diesel from vegetable oils. It also focused only on the use of bio-fuels in the OECD transportation sector. The analysis was undertaken with AGLINK, a multi-commodity multi-country policy-specific dynamic model of the international agricultural markets built by the OECD with member countries. It was shown that the increase in world and domestic prices for grains and vegetable oils will remain strong, particularly toward 2006. It was also shown that a major bio-fuel program for all OECD countries would be beneficial to Canadian agriculture. It was concluded that ultimately, an increase in OECD bio-fuels usage has a direct impact on the demand for grains and oilseeds which are important feed-stocks in biofuel production. The analysis presumes an increase in renewable fuel use, but does not consider factors such as financial incentives and regulatory requirements that could bring about this increase. 7 refs., 6 tabs., 4 figs

Transport biofuel yields from food and lignocellulosic C{sub 4} crops

Energy Technology Data Exchange (ETDEWEB)

Reijnders, L. [IBED University of Amsterdam, Nieuwe Achtergracht 166, 1018 WV Amsterdam (Netherlands)

2010-01-15

In the near future, the lignocellulosic C{sub 4} crops Miscanthus and switchgrass (Panicum virgatum) are unlikely to outcompete sugarcane (Saccharum officinarum) in net energetic yearly yield of transport biofuel ha{sup -1}. This holds both for the thermochemical conversion into liquid hydrocarbons and the enzymatic conversion into ethanol. Currently, Miscanthus and switchgrass would also not seem able to outcompete corn (Zea mays) in net energetic yearly yield of liquid transport biofuel ha{sup -1}, but further development of these lignocellulosic crops may gradually lead to a different outcome. (author)

Utilization of Variable Consumption Biofuel in Diesel Engine

Science.gov (United States)

Markov, V. A.; Kamaltdinov, V. G.; Savastenko, A. A.

2018-01-01

The depletion of oil fields and the deteriorating environmental situation leads to the need for the search of new alternative sources of energy. Actuality of the article due to the need for greater use of the alternative fuels in internal combustion engines is necessary. The advantages of vegetables origin fuels using as engine fuels are shown. Diesel engine operation on mixtures of petroleum diesel and rapeseed oil is researched. A fuel delivery system of mixture biofuel with a control system of the fuel compound is considered. The results of the system experimental researches of fuel delivery of mixture biofuel are led.

Harnessing biofuels. A global Renaissance in energy production?

Energy Technology Data Exchange (ETDEWEB)

Jegannathan, Kenthorai Raman; Chan, Eng-Seng; Ravindra, Pogaku [Centre of Materials and Minerals, School of Engineering and Information Technology, Universiti Malaysia Sabah, 88999 Kota Kinabalu, Sabah (Malaysia)

2009-10-15

Biofuel, peoples' long awaiting alternative fuel, is yet to struggle a long way to reach in retail outlet all over the world as an economical and environmental friendly fuel. Biofuels include bioethanol, biodiesel, biogas, bio-synthetic gas (bio-syngas), bio-oil, bio-char, Fischer-Tropsch liquids, and biohydrogen. Among these bioethanol, biodiesel, biogas are predominant which can be produced either using chemical catalyst or biocatalyst from biomass. At present, the conventional process involves the chemical catalyst while a rigorous research is focused on using a biocatalyst. This review brings out the advantages and disadvantages of using different type of catalyst in biofuel production and emphasis on new technologies as an alternative to conventional technologies. (author)

Stimulating learning-by-doing in advanced biofuels: effectiveness of alternative policies

International Nuclear Information System (INIS)

Chen Xiaoguang; Khanna, Madhu; Yeh, Sonia

2012-01-01

This letter examines the effectiveness of various biofuel and climate policies in reducing future processing costs of cellulosic biofuels due to learning-by-doing. These policies include a biofuel production mandate alone and supplementing the biofuel mandate with other policies, namely a national low carbon fuel standard, a cellulosic biofuel production tax credit or a carbon price policy. We find that the binding biofuel targets considered here can reduce the unit processing cost of cellulosic ethanol by about 30% to 70% between 2015 and 2035 depending on the assumptions about learning rates and initial costs of biofuel production. The cost in 2035 is more sensitive to the speed with which learning occurs and less sensitive to uncertainty in the initial production cost. With learning rates of 5–10%, cellulosic biofuels will still be at least 40% more expensive than liquid fossil fuels in 2035. The addition of supplementary low carbon/tax credit policies to the mandate that enhance incentives for cellulosic biofuels can achieve similar reductions in these costs several years earlier than the mandate alone; the extent of these incentives differs across policies and different kinds of cellulosic biofuels. (letter)

Biofuels derived from corn; Biocombustibles derivados del maiz

Energy Technology Data Exchange (ETDEWEB)

Arvizu Fernandez, Jose Luis [Instituto de Investigaciones Electricas, Cuernavaca, Morelos (Mexico)

2012-06-22

The biofuels can be obtained from the biomass, are liquid, solid or gaseous from matter of vegetal or animal origin, by biological, chemical or physical processes and combinations of them. The biofuels appear as an alternating fuels in the transport sector, mainly due to the positive impact of greenhouse gases effect (GHG) and to the increase of oil prices. In theory the use of bioethanol and the biofuels, they not have CO{sub 2} emissions since this it is absorbed in the same amount by the cultures that generate them, as the corn or sugar cane. Our country has a deficit in the food production, mainly in corn, grain that can offer the opportunity not only to continue being the base of the national feeding, but also the raw material to produce bioethanol. The national yields are so diverse that they resemble to those of EUA or Africa, without a doubt this is indicative that is due to devise the way of increase the yields of this appraised culture, reach in average the six tons by hectare, improving the culture practice and access to fertilizers, water, transport, transparent markets and right prices. [Spanish] Los biocombustibles pueden ser obtenidos de la biomasa, son liquidos, solidos o gaseosos provenientes de material vegetal u origen animal, pueden obtenerse mediante procesos biologicos, quimicos o fisicos, y combinaciones de ellos. Se presentan como combustibles alternos en el sector transporte, debido principalmente al impacto positivo de la reduccion de gases de efecto invernadero (GEI) y al aumento de los precios del petroleo. En teoria el uso del bioetanol y los biocombustibles no produce emisiones de CO{sub 2} porque este se absorbe en la misma cantidad a traves de los cultivos que los generan, como el maiz y la cana de azucar. Mexico tiene deficit en la produccion de alimentos, principalmente maiz, grano que puede ofrecer la oportunidad no solo de continuar siendo la base de la alimentacion nacional, sino tambien la materia prima para producir bioetanol

High liquid fuel yielding biofuel processes and a roadmap for the future transportation

Science.gov (United States)

Singh, Navneet R.

In a fossil-fuel deprived world when crude oil will be scarce and transportation need cannot be met with electricity and transportation liquid fuel must be produced, biomass derived liquid fuels can be a natural replacement. However, the carbon efficiency of the currently known biomass to liquid fuel conversion processes ranges from 35-40%, yielding 90 ethanol gallon equivalents (ege) per ton of biomass. This coupled with the fact that the efficiency at which solar energy is captured by biomass (hydrodeoxygenation is proposed which can achieve liquid fuel yield of 215 ege/ton consuming 0.11 kg hydrogen per liter of oil. Due to the lower hydrogen consumption of the H2Bioil process, synergistically integrated transition pathways are feasible where hot syngas derived from coal gasification (H2Bioil-C) or a natural gas reformer (H 2Bioil-NG) is used to supply the hydrogen and process heat for the biomass fast-hydropyrolysis/hydrodeoxygenation. Another off-shoot of the H2Bioil process is the H2Bioil-B process, where hydrogen required for the hydropyrolysis is obtained from gasification of a fraction of the biomass. H2Bioil-B achieves the highest liquid fuel yield (126-146 ege/ton of biomass) reported in the literature for any self-contained conversion of biomass to biofuel. Finally, an integration of the H2Bioil process with the H2CAR process is suggested which can achieve 100% carbon efficiency (330 ege/ton of biomass) at the expense of 0.24 kg hydrogen/liter of oil. A sun-to-fuel efficiency analysis shows that extracting CO2 from air and converting it to liquid fuel is at least two times more efficient than growing dedicated fuel crops and converting them to liquid fuel even for the highest biomass growth rates feasible by algae. This implies that liquid fuel should preferably be produced from sustainably available waste (SAW) biomass first and if the SAW biomass is unable to meet the demand for liquid fuel, then, CO2 should be extracted from air and converted to

Panorama 2007: Biofuels and their Environmental Performance

International Nuclear Information System (INIS)

Prieur-Vernat, A.; His, St.; Bouvart, F.

2007-01-01

Today, the development of bio-fuel pathways is closely associated with targets for the reduction of greenhouse gas (GHG) emissions in the transport sector. Well-to-wheel assessments indicate that the use of these automotive fuels of vegetable origin yield definite benefits in terms of GHG emissions and fossil energy consumption compared to petroleum-based automotive fuels. (author)

Byproducts for biofuels

International Nuclear Information System (INIS)

Bondt, N.; Meeusen, M.J.G.

2008-02-01

This report examines the market for residues from the Dutch food and beverage industry, and the appeal of these residues for the production of bio-ethanol and biodiesel. The firstgeneration technology is readily suited to the conversion of no more than 29% of the 7.5 million tonnes of residues into biofuels. Moreover, when non-technological criteria are also taken into account virtually none of the residues are of interest for conversion into bioethanol, although vegetable and animal fats can be used to produce biodiesel. The economic consequences for sectors such as the animal-feed sector are limited [nl

Primary productivity and the prospects for biofuels in the United Kingdom

Science.gov (United States)

Lawson, G. J.; Callaghan, T. V.

1983-09-01

Estimates of land use and plant productivity are combined to predict total annual primary production in the UK as 252 million tonnes dry matter (10.5 t ha-1yr-1). Annual above ground production is predicted to be 165 Mt (6.9 t ha-1yr-1). Within these totals, intensive agriculture contributes 60%, productive woodland 8%, natural vegetation 26% and urban vegetation 5%. However, only 25% of total plant production is cropped by man and animals, and most of this is subsequently discarded as wastes and residues. 2112 PJ of organic material is available for fuel without reducing food or fibre production, but since much of this could not be economically collected, 859 PJ is calculated as a more realistic biofuel contribution by the year 2000. After deducting 50% conversion losses, this could save P1 billion (1979 prices) in oil imports. Short rotation energy plantations, forest residues, coppice woodlands, animal and crop wastes, industrial and domestic wastes, catch crops, natural vegetation and urban vegetation all have immediate or short term potential as biofuel sources. Sensitive planning is required to reduce environmental impact, but in some cases more diverse wildlife habitats may be created.

Liquid Bio fuels: Vegetable Oils and Bi oethanol

International Nuclear Information System (INIS)

Ballesteros, M.; Ballesteros, I.; Oliva, J. M.; Navarro, A. A.

1998-01-01

The European energy policy has defined clear objectives to reduce the high dependency on fossil petroleum imports, and to increase the security of sustainable energy supply for the transport sector. Moreover, the European environmental policy is requesting clean fuels that reduce environmental risks. Liquid Bio fuels (vegetable oils and bio ethanol) appear to be in a good position to contribute to achieve these goals expressed by the established objective of European Union to reach for bio fuels a market share of 5% of motor vehicle consumption. This work presents the current state and perspectives of the production and utilisation of liquid fuels from agricultural sources by reviewing agricultural feedstocks for energy sector, conversion technologies and different ways to use bio fuels. Environmental and economical aspects are also briefly analysed. (Author) 10 refs

The Third Pacific Basin Biofuels Workshop: Proceedings

Science.gov (United States)

Among the many compelling reasons for the development of biofuels on remote Pacific islands, several of the most important include: (1) a lack of indigenous fossil fuels necessitates their import at great economic loss to local island economics, (2) ideal conditions for plant growth exist on many Pacific islands to produce yields of biomass feedstocks, (3) gaseous and liquid fuels such as methane, methanol and ethanol manufactured locally from biomass feedstocks are the most viable alternatives to gasoline and diesel fuels for transportation, and (4) the combustion of biofuels is cleaner than burning petroleum products and contributes no net atmospheric CO2 to aggravate the greenhouse effect and the subsequent threat of sea level rise to low islands. Dr. Vic Phillips, HNEI Program Manager of the Hawaii Integrated Biofuels Research Program welcomed 60 participants to the Third Pacific Basin Biofuels Workshop at the Sheraton Makaha Hotel, Waianae, Oahu, on March 27 and 28, 1989. The objectives of the workshop were to update progress since the Second Pacific Basin Biofuels Workshop in April 1987 and to develop a plan for action for biofuels R and D, technology transfer, and commercialization now (immediate attention), in the near-term (less than two years), in the mid-term (three to five years), and in the long-term (more than six years). An emerging theme of the workshop was how the production, conversion, and utilization of biofuels can help increase environmental and economic security locally and globally. Individual papers are processed separately for the data base.

Relative Greenhouse Gas Abatement Cost Competitiveness of Biofuels in Germany

Directory of Open Access Journals (Sweden)

Markus Millinger

2018-03-01

Full Text Available Transport biofuels derived from biogenic material are used for substituting fossil fuels, thereby abating greenhouse gas (GHG emissions. Numerous competing conversion options exist to produce biofuels, with differing GHG emissions and costs. In this paper, the analysis and modeling of the long-term development of GHG abatement and relative GHG abatement cost competitiveness between crop-based biofuels in Germany are carried out. Presently dominant conventional biofuels and advanced liquid biofuels were found not to be competitive compared to the substantially higher yielding options available: sugar beet-based ethanol for the short- to medium-term least-cost option and substitute natural gas (SNG for the medium to long term. The competitiveness of SNG was found to depend highly on the emissions development of the power mix. Silage maize-based biomethane was found competitive on a land area basis, but not on an energetic basis. Due to land limitations, as well as cost and GHG uncertainty, a stronger focus on the land use of crop-based biofuels should be laid out in policy.

Microbial consortium role in processing liquid waste of vegetables in Keputran Market Surabaya as organic liquid fertilizer ferti-plus

Science.gov (United States)

Rizqi, Fauziah; Supriyanto, Agus; Lestari, Intan; Lita Indri D., L.; Elmi Irmayanti, A.; Rahmaniyah, Fadilatur

2016-03-01

Many activities in this market is directly proportional to increase production of vegetables waste, especially surabaya. Therefore, in this study aims to utilize liquid waste of vegetables into liquid organic fertilizer by mixing microbial consorsium. The microbial consorsium consist of Azotobacter chrococcum, Azospirillum brasilense, Rhizobium leguminosarum, Bacillus subtilis, Bacillus megaterium, Pseudomonas putida, and Pseudomonas fluorescens. Ttreatment of microbial concentrations (5%, 10%, 15%) and the length of the incubation period (7 days, 14 days, 21 days) used in this research. The parameters used are: C/N ratio, levels of CNP, and BOD value. This study uses a standard organic fertilizer value according SNI19-7030-2004, The results show the value of C/N ratio comply with the ISO standards. C levels showed an increase during the incubation period but not compare with standards. N levels that compare with standards are microbial treatment in all group concentration except control group with an incubation period of 21 days is > 7. P levels compare with the existing standards in the group of microbe concentration of 10% and 15% during the incubation period. The value of the initial BOD liquid waste of vegetable is 790.25 mg / L, this value indicates that the waste should not go into the water body. Accordingly, the results of this study can not be used as a liquid organic fertilizer, but potentially if it is used as a natural career or build natural soil. The Building natural soil is defined as the natural ingredients that can be used to improve soil properties.

Biofuels from pyrolysis in perspective: trade-offs between energy yields and soil-carbon additions.

Science.gov (United States)

Woolf, Dominic; Lehmann, Johannes; Fisher, Elizabeth M; Angenent, Largus T

2014-06-03

Coproduction of biofuels with biochar (the carbon-rich solid formed during biomass pyrolysis) can provide carbon-negative bioenergy if the biochar is sequestered in soil, where it can improve fertility and thus simultaneously address issues of food security, soil degradation, energy production, and climate change. However, increasing biochar production entails a reduction in bioenergy obtainable per unit biomass feedstock. Quantification of this trade-off for specific biochar-biofuel pathways has been hampered by lack of an accurate-yet-simple model for predicting yields, product compositions, and energy balances from biomass slow pyrolysis. An empirical model of biomass slow pyrolysis was developed and applied to several pathways for biochar coproduction with gaseous and liquid biofuels. Here, we show that biochar production reduces liquid biofuel yield by at least 21 GJ Mg(-1) C (biofuel energy sacrificed per unit mass of biochar C), with methanol synthesis giving this lowest energy penalty. For gaseous-biofuel production, the minimum energy penalty for biochar production is 33 GJ Mg(-1) C. These substitution rates correspond to a wide range of Pareto-optimal system configurations, implying considerable latitude to choose pyrolysis conditions to optimize for desired biochar properties or to modulate energy versus biochar yields in response to fluctuating price differentials for the two commodities.

Synthetic Biology Guides Biofuel Production

Directory of Open Access Journals (Sweden)

Michael R. Connor

2010-01-01

Full Text Available The advancement of microbial processes for the production of renewable liquid fuels has increased with concerns about the current fuel economy. The development of advanced biofuels in particular has risen to address some of the shortcomings of ethanol. These advanced fuels have chemical properties similar to petroleum-based liquid fuels, thus removing the need for engine modification or infrastructure redesign. While the productivity and titers of each of these processes remains to be improved, progress in synthetic biology has provided tools to guide the engineering of these processes through present and future challenges.

Round table on bio-fuels; Table ronde sur les biocarburants

Energy Technology Data Exchange (ETDEWEB)

NONE

2005-11-15

The French ministers of agriculture and of industry have organized a meeting with the main French actors of agriculture, petroleum industry, car making and accessories industry and with professionals of agriculture machines to encourage the development of bio-fuels in France. This meeting took place in Paris in November 21, 2005. Its aim was to favor the partnerships between the different actors and the public authorities in order to reach the ambitious goals of the government of 5.75% of bio-fuels in fossil fuels by 2008, 7% by 2010 and 10% by 2015. The main points discussed by the participants were: the compatibility of automotive fuel standards with the objectives of bio-fuel incorporation, the development of direct incorporation of methanol in gasoline, the ethanol-ETBE partnership, the question of the lower calorific value of ETBE (ethyl tertio butyl ether), the development of new bio-fuels, the development of bio-diesel and the specific case of pure vegetal oils, and the fiscal framework of bio-fuels. This meeting has permitted to reach important improvements with 15 concrete agreements undertaken by the participants. (J.S.)

Biofuels: What Are They and How Can They Improve Practical Work and Discussions?

Science.gov (United States)

MacLean, Tristan

2014-01-01

This article looks at the potential of bioenergy as a replacement for fossil fuels, the cutting-edge research being undertaken by scientists, and classroom resources available for teaching this topic. There is currently a large programme of scientific research aiming to develop advanced biofuels (replenishable liquid biofuels from non-food plants,…

Production of biofuels via hydrothermal conversion

DEFF Research Database (Denmark)

Biller, Patrick; Ross, Andrew

2016-01-01

as the quality of targeted biofuel is a function of feedstock and operating conditions. The quality of hydrochar influences its uses as a solid fuel while biocrude quality affects its use as a liquid fuel and feedstock for upgrading to drop-in replacement fuels, while HTG produces a syngas rich in either H2...

Determination of spirocyclic tetronic/tetramic acid derivatives and neonicotinoid insecticides in fruits and vegetables by liquid chromatography and mass spectrometry after dispersive liquid-liquid microextraction.

Science.gov (United States)

Pastor-Belda, Marta; Garrido, Isabel; Campillo, Natalia; Viñas, Pilar; Hellín, Pilar; Flores, Pilar; Fenoll, José

2016-07-01

Dispersive liquid-liquid microextraction was used to preconcentrate three spirocyclic tetronic/tetramic acid derivatives (spirotetramat, spiromesifen and spirodiclofen) and five neonicotinoid (thiamethoxam, chlotianidin, imidacloprid, acetamiprid and thiacloprid) insecticides previously extracted from fruit and vegetable matrices with acetonitrile. The organic enriched phase was evaporated, reconstituted in 25μL acetonitrile and analyzed by reversed-phase liquid chromatography with tandem mass spectrometry using a triple quadrupole in selected reaction monitoring mode. Enrichment factors in the 15-100 range were obtained. A matrix effect was observed, the detection limits varying between 0.025 and 0.5ngg(-1), depending on the compound and the sample matrix. The developed method was applied to the analysis of 25 samples corresponding to five different fruit and vegetable matrices. Only thiamethoxam was detected in a lemon sample at a concentration close to the quantification limit, and spiromesifen and spirotetramat at concentrations between 11.6 and 54.5ngg(-1). Copyright © 2016 Elsevier Ltd. All rights reserved.

Determination of Fusarium toxins in functional vegetable milks applying salting-out-assisted liquid-liquid extraction combined with ultra-high-performance liquid chromatography tandem mass spectrometry.

Science.gov (United States)

Hamed, Ahmed M; Arroyo-Manzanares, Natalia; García-Campaña, Ana M; Gámiz-Gracia, Laura

2017-11-01

Vegetable milks are considered as functional foods due to their physiological benefits. Although the consumption of these products has significantly increased, they have received little attention in legislation with regard to contaminants. However, they may contain mycotoxins resulting from the use of contaminated raw materials. In this work, ultra-high-performance liquid chromatography tandem mass spectrometry has been proposed for the determination of the most relevant Fusarium toxins (fumonisin B 1 and B 2 , HT-2 and T-2 toxins, zearalenone, deoxynivalenol and fusarenon-X) in different functional beverages based on cereals, legumes and seeds. Sample treatment consisted of a simple salting-out-assisted liquid-liquid extraction with no further clean-up. The method provided limits of quantification between 3.2 and 57.7 µg L -1 , recoveries above 80% and precision with RSD lower than 12%. The method was also applied for studying the occurrence of these mycotoxins in market samples of vegetable functional beverages and deoxynivalenol was found in three oat-based commercial drinks.

Biofuels combustion.

Science.gov (United States)

Westbrook, Charles K

2013-01-01

This review describes major features of current research in renewable fuels derived from plants and from fatty acids. Recent and ongoing fundamental studies of biofuel molecular structure, oxidation reactions, and biofuel chemical properties are reviewed, in addition to combustion applications of biofuels in the major types of engines in which biofuels are used. Biofuels and their combustion are compared with combustion features of conventional petroleum-based fuels. Two main classes of biofuels are described, those consisting of small, primarily alcohol, fuels (particularly ethanol, n-butanol, and iso-pentanol) that are used primarily to replace or supplement gasoline and those derived from fatty acids and used primarily to replace or supplement conventional diesel fuels. Research efforts on so-called second- and third-generation biofuels are discussed briefly.

Global Biofuels at the Crossroads: An Overview of Technical, Policy, and Investment Complexities in the Sustainability of Biofuel Development

Directory of Open Access Journals (Sweden)

Kathleen Araújo

2017-03-01

Full Text Available Biofuels have the potential to alter the transport and agricultural sectors of decarbonizing societies. Yet, the sustainability of these fuels has been questioned in recent years in connection with food versus fuel trade-offs, carbon accounting, and land use. Recognizing the complicated playing field for current decision-makers, we examine the technical attributes, policy, and global investment activity for biofuels (primarily liquids. Differences in feedstock and fuel types are considered, in addition to policy approaches of major producer countries. Issues with recent, policy-driven trade developments are highlighted to emphasize how systemic complexities associated with sustainability must also be managed. We conclude with near-term areas to watch.

Recommendations for a sustainable development of biofuels in France; Recommandations pour un developpement durable des biocarburants en France

Energy Technology Data Exchange (ETDEWEB)

Douaud, A.; Gruson, J.F

2006-01-15

The biofuels are presented as a solution to the greenhouse gases and the petroleum consumption decrease. The development of the biofuels needs an active research of the production, transformation and use costs improvement. It will be necessary to prepare the market of the biofuels to the globalization. Some recommendations are also provided in the domains of the vegetal oil ester, the ethanol for the diesel and for the development of simulation tools to evaluate the costs. (A.L.B.)

Consortium for Algal Biofuel Commercialization (CAB-COMM) Final Report

Energy Technology Data Exchange (ETDEWEB)

Mayfield, Stephen P. [Univ. of California, San Diego, CA (United States)

2015-12-04

The Consortium for Algal Biofuel Commercialization (CAB-Comm) was established in 2010 to conduct research to enable commercial viability of alternative liquid fuels produced from algal biomass. The main objective of CAB-Comm was to dramatically improve the viability of algae as a source of liquid fuels to meet US energy needs, by addressing several significant barriers to economic viability. To achieve this goal, CAB-Comm took a diverse set of approaches on three key aspects of the algal biofuels value chain: crop protection; nutrient utilization and recycling; and the development of genetic tools. These projects have been undertaken as collaboration between six academic institutions and two industrial partners: University of California, San Diego; Scripps Institution of Oceanography; University of Nebraska, Lincoln; Rutgers University; University of California, Davis; Johns Hopkins University; Sapphire Energy; and Life Technologies.

Toward nitrogen neutral biofuel production.

Science.gov (United States)

Huo, Yi-Xin; Wernick, David G; Liao, James C

2012-06-01

Environmental concerns and an increasing global energy demand have spurred scientific research and political action to deliver large-scale production of liquid biofuels. Current biofuel processes and developing approaches have focused on closing the carbon cycle by biological fixation of atmospheric carbon dioxide and conversion of biomass to fuels. To date, these processes have relied on fertilizer produced by the energy-intensive Haber-Bosch process, and have not addressed the global nitrogen cycle and its environmental implications. Recent developments to convert protein to fuel and ammonia may begin to address these problems. In this scheme, recycling ammonia to either plant or algal feedstocks reduces the demand for synthetic fertilizer supplementation. Further development of this technology will realize its advantages of high carbon fixation rates, inexpensive and simple feedstock processing, in addition to reduced fertilizer requirements. Copyright © 2011 Elsevier Ltd. All rights reserved.

Microalgae for Biofuels and Animal Feeds

Directory of Open Access Journals (Sweden)

John Benemann

2013-11-01

Full Text Available The potential of microalgae biomass production for low-cost commodities—biofuels and animal feeds—using sunlight and CO2 is reviewed. Microalgae are currently cultivated in relatively small-scale systems, mainly for high value human nutritional products. For commodities, production costs must be decreased by an order of magnitude, and high productivity algal strains must be developed that can be stably cultivated in large open ponds and harvested by low-cost processes. For animal feeds, the algal biomass must be high in digestible protein and long-chain omega-3 fatty acids that can substitute for fish meal and fish oils. Biofuels will require a high content of vegetable oils (preferably triglycerides, hydrocarbons or fermentable carbohydrates. Many different cultivation systems, algal species, harvesting methods, and biomass processing technologies are being developed worldwide. However, only raceway-type open pond systems are suitable for the production of low-cost commodities.

The Renewable Energy Directive: biofuels, biomass and sustainable development criteria. How to check in France the compliance of marketed biofuels with sustainability criteria defined by the Directive on renewable energies? (Phase 1: biofuels and bio-liquids); Directive Energies Renouvelables: Biocarburants, biomasse et criteres de developpement durable. Comment verifier, en France, la conformite des biocarburants mis sur le marche aux criteres de durabilite prevus par la Directive sur les energies renouvelables? (Phase 1: biocarburants et bioliquides)

Energy Technology Data Exchange (ETDEWEB)

NONE

2009-06-15

After having recalled and commented the main principles of the European directive which sets objectives in terms of renewable energy promotion and consumption, this report analyses the quantitative and qualitative sustainability criteria which must be applied particularly to biofuels and bio-liquids produced from agricultural activities, and their application perspectives. It gives recommendations to assess these criteria. It also comments the modalities used to control the compliance of biofuels with these criteria

The net cost of biofuels in Thailand. An economic analysis

International Nuclear Information System (INIS)

Bell, David R.; Kamens, Richard; Silalertruksa, Thapat; Gheewala, Shabbir H.

2011-01-01

Biofuels are expected to represent a growing portion of liquid fuel consumption in Thailand due to environmental and social considerations in conjunction with policy goals supporting their domestic production and consumption. This paper reviews the economic costs associated with biofuel policy implementation in Thailand in the short term target year of 2011. Internal (production) and external (environmental, social, etc.) costs and benefits are evaluated, and, where possible, monetized. Domestic production of biofuel is calculated to be 9.5 billion THB (317 million USD) more expensive than importing the equivalent amount of petroleum. The environmental benefits from GHG savings as well as losses due to increased ground level ozone formation and government expenditure to support the biofuel industry yield a total 'net cost' of 8.6 billion THB or 121 THB (4.04 USD) per capita for the year 2011. This result is contextualized with the (non-monetized) consideration that although biofuels are somewhat more expensive in the short term, their domestic production allows virtually all of the money to stay within the Thai economy as opposed to being sent abroad. This fact, coupled with significant uncertainty in future petroleum prices, could strongly influence the direction of Thai policy with respect to biofuels. (author)

Thermodynamic characterization of bio-fuels: Excess functions for binary mixtures containing ETBE and hydrocarbons

International Nuclear Information System (INIS)

Segovia, Jose J.; Villamanan, Rosa M.; Martin, M. Carmen; Chamorro, Cesar R.; Villamanan, Miguel A.

2010-01-01

European energy policy is promoting the use of bio-fuels for transportation. Bioethers and bioalcohols are used as blending agents for enhancing the octane number. They make gasoline work harder, help the engine last longer and reduce air pollution. They also cause changes in the fuel properties. Development of renewable fuels needs both knowledge of new thermodynamic data and improvement of clean energy technologies. In this context, the use of ethanol of vegetable origin in its manufacture process, increases the interest of ETBE or bio-ETBE as an oxygenated additive. A complete study of the behaviour of ETBE + hydrocarbons mixtures is presented. Some experimental data concerning vapor-liquid equilibria and heats of mixing were determined in our laboratory. All the techniques have a high accuracy. The data were reduced by well-known models, such as NRTL and used to model the thermodynamic properties.

Biofuel market and carbon modeling to evaluate French biofuel policy

International Nuclear Information System (INIS)

Bernard, F.; Prieur, A.

2006-10-01

In order to comply with European objectives, France has set up an ambitious biofuel plan. This plan is evaluated considering two criteria: tax exemption need and GHG emission savings. An economic marginal analysis and a life cycle assessment (LCA) are provided using a coupling procedure between a partial agro-industrial equilibrium model and a refining optimization model. Thus, we are able to determine the minimum tax exemption needed to place on the market a targeted quantity of biofuel by deducing the agro-industrial marginal cost of biofuel production to the biofuel refining long-run marginal revenue. In parallel, a biofuels LCA is carried out using model outputs. Such a method avoid common allocation problems between joint products. The French biofuel plan is evaluated for 2008, 2010 and 2012 using prospective scenarios. Results suggest that biofuel competitiveness depends on crude oil prices and petroleum products demands. Consequently, biofuel tax exemption does not always appear to be necessary. LCA results show that biofuels production and use, from 'seed to wheel', would facilitate the French Government's to compliance with its 'Plan Climat' objectives by reducing up to 5% GHG emissions in the French road transport sector by 2010. (authors)

Biofuels in Spain: Market penetration analysis and competitiveness in the automotive fuel market

International Nuclear Information System (INIS)

Sobrino, Fernando Hernandez; Monroy, Carlos Rodriguez; Perez, Jose Luis Hernandez

2010-01-01

For several years the European Union (E.U.) has been promoting the use of biofuels due to their potential benefits such as the reduction of dependence on foreign energy imports (the raw materials can be produced within the E.U.), the more stable fossil fuel prices (they can replace fossil fuels on the market), the greenhouse gas (GHG) reduction (biofuels' raw materials fix CO 2 from the atmosphere) and the fact that they can represent an additional source of income for the primary sector (biofuels' raw materials are vegetables that can be grown and harvested). Despite the public aids (direct and indirect), biofuels are not competitive with fossil fuels at present, but it is possible that in the future the environment conditions change and biofuels might become competitive. It is difficult to assess whether this will happen or not, but it is possible to make an assessment of a future situation. This article presents two analyses with one objective: to determine if biofuels might become competitive in the future. The first analysis examines the dependencies of two quotations which have a strong relationship with fuels: the crude oil quotation and the CO 2 bond quotation. The analysis of these relationships may help to forecast the future competitiveness of biofuels. For instance, biofuels' future competitiveness will be higher if their raw material costs are not related to crude oil quotations or if they are related in a negative way (the higher the crude oil quotations the lower the raw material biofuels' cost). The second analysis focuses on the market penetration of biofuels in the Spanish market. There are data related to biofuels monthly consumption in Spain since 2007 and it is possible to know if biofuels are gaining market quota since then. (author)

Biofuels in Spain: Market penetration analysis and competitiveness in the automotive fuel market

Energy Technology Data Exchange (ETDEWEB)

Sobrino, Fernando Hernandez; Monroy, Carlos Rodriguez [Department of Business Administration, School of Industrial Engineering, Universidad Politecnica de Madrid, Jose Gutierrez Abascal 2, 28006 Madrid (Spain); Perez, Jose Luis Hernandez [High School Chemistry Teacher, Madrid (Spain)

2010-12-15

For several years the European Union (E.U.) has been promoting the use of biofuels due to their potential benefits such as the reduction of dependence on foreign energy imports (the raw materials can be produced within the E.U.), the more stable fossil fuel prices (they can replace fossil fuels on the market), the greenhouse gas (GHG) reduction (biofuels' raw materials fix CO{sub 2} from the atmosphere) and the fact that they can represent an additional source of income for the primary sector (biofuels' raw materials are vegetables that can be grown and harvested). Despite the public aids (direct and indirect), biofuels are not competitive with fossil fuels at present, but it is possible that in the future the environment conditions change and biofuels might become competitive. It is difficult to assess whether this will happen or not, but it is possible to make an assessment of a future situation. This article presents two analyses with one objective: to determine if biofuels might become competitive in the future. The first analysis examines the dependencies of two quotations which have a strong relationship with fuels: the crude oil quotation and the CO{sub 2} bond quotation. The analysis of these relationships may help to forecast the future competitiveness of biofuels. For instance, biofuels' future competitiveness will be higher if their raw material costs are not related to crude oil quotations or if they are related in a negative way (the higher the crude oil quotations the lower the raw material biofuels' cost). The second analysis focuses on the market penetration of biofuels in the Spanish market. There are data related to biofuels monthly consumption in Spain since 2007 and it is possible to know if biofuels are gaining market quota since then. (author)

Developing symbiotic consortia for lignocellulosic biofuel production

Energy Technology Data Exchange (ETDEWEB)

Zuroff, Trevor R.; Curtis, Wayne R. [Pennsylvania State Univ., University Park, PA (United States). Dept. of Chemical Engineering

2012-02-15

The search for petroleum alternatives has motivated intense research into biological breakdown of lignocellulose to produce liquid fuels such as ethanol. Degradation of lignocellulose for biofuel production is a difficult process which is limited by, among other factors, the recalcitrance of lignocellulose and biological toxicity of the products. Consolidated bioprocessing has been suggested as an efficient and economical method of producing low value products from lignocellulose; however, it is not clear whether this would be accomplished more efficiently with a single organism or community of organisms. This review highlights examples of mixtures of microbes in the context of conceptual models for developing symbiotic consortia for biofuel production from lignocellulose. Engineering a symbiosis within consortia is a putative means of improving both process efficiency and stability relative to monoculture. Because microbes often interact and exist attached to surfaces, quorum sensing and biofilm formation are also discussed in terms of consortia development and stability. An engineered, symbiotic culture of multiple organisms may be a means of assembling a novel combination of metabolic capabilities that can efficiently produce biofuel from lignocellulose. (orig.)

Sustainability of algal biofuel production using integrated renewable energy park (IREP) and algal biorefinery approach

International Nuclear Information System (INIS)

Subhadra, Bobban G.

2010-01-01

Algal biomass can provide viable third generation feedstock for liquid transportation fuel. However, for a mature commercial industry to develop, sustainability as well as technological and economic issues pertinent to algal biofuel sector must be addressed first. This viewpoint focuses on three integrated approaches laid out to meet these challenges. Firstly, an integrated algal biorefinery for sequential biomass processing for multiple high-value products is delineated to bring in the financial sustainability to the algal biofuel production units. Secondly, an integrated renewable energy park (IREP) approach is proposed for amalgamating various renewable energy industries established in different locations. This would aid in synergistic and efficient electricity and liquid biofuel production with zero net carbon emissions while obviating numerous sustainability issues such as productive usage of agricultural land, water, and fossil fuel usage. A 'renewable energy corridor' rich in multiple energy sources needed for algal biofuel production for deploying IREPs in the United States is also illustrated. Finally, the integration of various industries with algal biofuel sector can bring a multitude of sustainable deliverables to society, such as renewable supply of cheap protein supplements, health products and aquafeed ingredients. The benefits, challenges, and policy needs of the IREP approach are also discussed.

Biofuel market and carbon modeling to analyse French biofuel policy

International Nuclear Information System (INIS)

Bernard, F.; Prieur, A.

2007-01-01

In order to comply with European Union objectives, France has set up an ambitious biofuel plan. This plan is evaluated on the basis of two criteria: tax exemption on fossil fuels and greenhouse gases (GHG) emission savings. An economic marginal analysis and a life cycle assessment (LCA) are provided using a coupling procedure between a partial agro-industrial equilibrium model and an oil refining optimization model. Thus, we determine the minimum tax exemption needed to place on the market a targeted quantity of biofuel by deducting the biofuel long-run marginal revenue of refiners from the agro-industrial marginal cost of biofuel production. With a clear view of the refiner's economic choices, total pollutant emissions along the biofuel production chains are quantified and used to feed an LCA. The French biofuel plan is evaluated for 2008, 2010 and 2012 using prospective scenarios. Results suggest that biofuel competitiveness depends on crude oil prices and demand for petroleum products and consequently these parameters should be taken into account by authorities to modulate biofuel tax exemption. LCA results show that biofuel production and use, from 'seed to wheel', would facilitate the French Government's compliance with its 'Plan Climat' objectives by reducing up to 5% GHG emissions in the French road transport sector by 2010

Meeting the global demand for biofuels in 2021 through sustainable land use change policy

International Nuclear Information System (INIS)

Goldemberg, José; Mello, Francisco F.C.; Cerri, Carlos E.P.; Davies, Christian A.; Cerri, Carlos C.

2014-01-01

The 2013 renewable energy policy mandates adopted in twenty-seven countries will increase the need for liquid biofuels. To achieve this, ethanol produced from corn and sugarcane will need to increase from 80 to approximately 200 billion l in 2021. This could be achieved by increasing the productivity of raw material per hectare, expansion of land into dedicated biofuels, or a combination of both. We show here that appropriate land expansion policies focused on conservationist programs and a scientific basis, are important for sustainable biofuel expansion whilst meeting the increasing demand for food and fiber. The Brazilian approach to biofuel and food security could be followed by other nations to provide a sustainable pathway to renewable energy and food production globally. One sentence summary: Conservationist policy programs with scientific basis are key to drive the expansion of biofuel production and use towards sustainability

Models for the prediction of the cetane index of biofuels obtained from different vegetable oils using their fatty acid composition

International Nuclear Information System (INIS)

Sanchez Borroto, Yisel; Piloto Rodriguez, Ramon; Goyos Perez, Leonardo

2011-01-01

The objective of the present work is to obtain a physical-mathematical model that establishes a relationship between the cetane index of biofuels obtained from different vegetable oils and its composition of essential fatty acid. This model is based on experimental data obtained by the authors of the present work and an experimental data reported by different extracted authors of indexed databases. The adjustment of the coefficients of the model is based on the obtaining of residual minima in the capacity of prediction of the model. Starting from these results it is established a very useful tool for the determination of such an important parameter for the fuel diesel as it is the cetane index obtained from an analysis of chemical composition and not obtained from tests in engines banks, to save time and economic resources. (author)

Biological research survey for the efficient conversion of biomass to biofuels.

Energy Technology Data Exchange (ETDEWEB)

Kent, Michael Stuart; Andrews, Katherine M. (Computational Biosciences)

2007-01-01

The purpose of this four-week late start LDRD was to assess the current status of science and technology with regard to the production of biofuels. The main focus was on production of biodiesel from nonpetroleum sources, mainly vegetable oils and algae, and production of bioethanol from lignocellulosic biomass. One goal was to assess the major technological hurdles for economic production of biofuels for these two approaches. Another goal was to compare the challenges and potential benefits of the two approaches. A third goal was to determine areas of research where Sandia's unique technical capabilities can have a particularly strong impact in these technologies.

Tailoring next-generation biofuels and their combustion in next-generation engines

Energy Technology Data Exchange (ETDEWEB)

Gladden, John Michael [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Wu, Weihua [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Taatjes, Craig A. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Scheer, Adam Michael [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Turner, Kevin M. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Yu, Eizadora T. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); O' Bryan, Greg [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Powell, Amy Jo [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Gao, Connie W. [Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)

2013-11-01

Increasing energy costs, the dependence on foreign oil supplies, and environmental concerns have emphasized the need to produce sustainable renewable fuels and chemicals. The strategy for producing next-generation biofuels must include efficient processes for biomass conversion to liquid fuels and the fuels must be compatible with current and future engines. Unfortunately, biofuel development generally takes place without any consideration of combustion characteristics, and combustion scientists typically measure biofuels properties without any feedback to the production design. We seek to optimize the fuel/engine system by bringing combustion performance, specifically for advanced next-generation engines, into the development of novel biosynthetic fuel pathways. Here we report an innovative coupling of combustion chemistry, from fundamentals to engine measurements, to the optimization of fuel production using metabolic engineering. We have established the necessary connections among the fundamental chemistry, engine science, and synthetic biology for fuel production, building a powerful framework for co-development of engines and biofuels.

Biofuels Baseline 2008

Energy Technology Data Exchange (ETDEWEB)

Hamelinck, C.; Koper, M.; Berndes, G.; Englund, O.; Diaz-Chavez, R.; Kunen, E.; Walden, D.

2011-10-15

The European Union is promoting the use of biofuels and other renewable energy in transport. In April 2009, the Renewable Energy Directive (2009/28/EC) was adopted that set a 10% target for renewable energy in transport in 2020. The directive sets several requirements to the sustainability of biofuels marketed in the frame of the Directive. The Commission is required to report to the European Parliament on a regular basis on a range of sustainability impacts resulting from the use of biofuels in the EU. This report serves as a baseline of information for regular monitoring on the impacts of the Directive. Chapter 2 discusses the EU biofuels market, the production and consumption of biofuels and international trade. It is derived where the feedstock for EU consumed biofuels originally come from. Chapter 3 discusses the biofuel policy framework in the EU and major third countries of supply. It looks at various policy aspects that are relevant to comply with the EU sustainability requirements. Chapter 4 discusses the environmental and social sustainability aspects associated with EU biofuels and their feedstock. Chapter 5 discusses the macro-economic effects that indirectly result from increased EU biofuels consumption, on commodity prices and land use. Chapter 6 presents country factsheets for main third countries that supplied biofuels to the EU market in 2008.

Limits to biofuels

Directory of Open Access Journals (Sweden)

Johansson S.

2013-06-01

Full Text Available Biofuel production is dependent upon agriculture and forestry systems, and the expectations of future biofuel potential are high. A study of the global food production and biofuel production from edible crops implies that biofuel produced from edible parts of crops lead to a global deficit of food. This is rather well known, which is why there is a strong urge to develop biofuel systems that make use of residues or products from forest to eliminate competition with food production. However, biofuel from agro-residues still depend upon the crop production system, and there are many parameters to deal with in order to investigate the sustainability of biofuel production. There is a theoretical limit to how much biofuel can be achieved globally from agro-residues and this amounts to approximately one third of todays’ use of fossil fuels in the transport sector. In reality this theoretical potential may be eliminated by the energy use in the biomass-conversion technologies and production systems, depending on what type of assessment method is used. By surveying existing studies on biofuel conversion the theoretical limit of biofuels from 2010 years’ agricultural production was found to be either non-existent due to energy consumption in the conversion process, or up to 2–6000TWh (biogas from residues and waste and ethanol from woody biomass in the more optimistic cases.

Limits to biofuels

Science.gov (United States)

Johansson, S.

2013-06-01

Biofuel production is dependent upon agriculture and forestry systems, and the expectations of future biofuel potential are high. A study of the global food production and biofuel production from edible crops implies that biofuel produced from edible parts of crops lead to a global deficit of food. This is rather well known, which is why there is a strong urge to develop biofuel systems that make use of residues or products from forest to eliminate competition with food production. However, biofuel from agro-residues still depend upon the crop production system, and there are many parameters to deal with in order to investigate the sustainability of biofuel production. There is a theoretical limit to how much biofuel can be achieved globally from agro-residues and this amounts to approximately one third of todays' use of fossil fuels in the transport sector. In reality this theoretical potential may be eliminated by the energy use in the biomass-conversion technologies and production systems, depending on what type of assessment method is used. By surveying existing studies on biofuel conversion the theoretical limit of biofuels from 2010 years' agricultural production was found to be either non-existent due to energy consumption in the conversion process, or up to 2-6000TWh (biogas from residues and waste and ethanol from woody biomass) in the more optimistic cases.

Sustainable Liquid Biofuels from Biomass Biorefining (SUNLIBB). Policy Brief No. 2

Energy Technology Data Exchange (ETDEWEB)

NONE

2013-09-15

The SUNLIBB project is funded under the European Seventh Framework Programme (FP7) within the Energy theme: Second Generation Biofuels -- EU Brazil Coordinated Call. SUNLIBB started on 1 October 2010 for 4 years and collaborates with a parallel project in Brazil, CeProBIO. This is the second in a series of policy briefs providing an update on the project. The first brief was issued in March 2012. The project focus is on looking at developing second generation biofuels that hope to improve on issues seen with the first generation options. Second generation biofuels are manufactured from inedible sources, such as woody crops, energy grasses, or even agricultural and forestry residues. Residues from sugarcane and biomass from maize, as well as 'whole-crop' miscanthus are all potential raw material (called 'feedstock') for second generation bioethanol production. Because these three plants are all closely related, processing the biomass from these crops raises common technical challenges, which offers the opportunity for breakthroughs in one species to be rapidly exploited in the others. Despite the potential sustainability benefits of second generation bioethanol, the current inefficiency of production makes it economically uncompetitive. Taking up this challenge, the SUNLIBB consortium's multidisciplinary team of scientists -- in cooperation with CeProBIO, the sister project in Brazil -- combines European and Brazilian research strengths so as to open the way for environmentally, socially and economically sustainable second generation bioethanol production.

Evaluation of biofuels sustainability: can we keep biofuel appropriate and green?

CSIR Research Space (South Africa)

Amigun, B

2009-11-01

Full Text Available and Industrial Research (CSIR) Pretoria, South Africa bamigun@csir.co.za Outlines • State of biofuels in Africa - Biofuels initiatives in Africa • Barriers to biofuels market penetration and policy incentives to stimulate the market. • Sustainability... are then motivated to put these ideas into practice. The end of Phase I is the political decision to invest money and other resources into biofuel research. Biofuels developmental stages in Africa…explanation © CSIR 2009 www...

Ghana's biofuels policy: challenges and the way forward

Energy Technology Data Exchange (ETDEWEB)

Antwi, Edward [Kumasi Polytechnic, Mechanical Engineering Department, Box 854, Kumasi (Ghana); Bensah, Edem Cudjoe; Ahiekpor, Julius [Kumasi Polytechnic, Chemical Engineering Department, Box 854, Kumasi (Ghana); Quansah, David Ato [The Energy Centre, Kwame Nkrumah University of Science and Technology, Kumasi (Ghana); Arthur, Richard [Koforidua Polytechnic, PMB, Koforidua (Ghana)

2010-07-01

Liquid biofuels have come up strongly as possible substitute to conventional fossils fuels and woodfuels apparently because of its perceived environmental benefit, sustainability and recent hikes in petroleum fuel prices. These have led most countries to include biofuels in their energy mix to mitigate climate change effect caused by petroleum fuels and also to ensure energy security. Ghana as a developing country has also identified the potential of biofuels in her energy mix by setting some targets in its Strategic National Energy Policy (SNEP). This paper analyses the implications of the policy as presented in SNEP. It also looks at programmes put in place to achieve the set objectives and the possible challenges that are likely to be faced in their implementation. The paper concludes by calling for strong governmental involvement in achieving the set objectives.

A Review of Environmental Life Cycle Assessments of Liquid Transportation Biofuels in the Pan American Region.

Science.gov (United States)

Shonnard, David R; Klemetsrud, Bethany; Sacramento-Rivero, Julio; Navarro-Pineda, Freddy; Hilbert, Jorge; Handler, Robert; Suppen, Nydia; Donovan, Richard P

2015-12-01

Life-cycle assessment (LCA) has been applied to many biofuel and bioenergy systems to determine potential environmental impacts, but the conclusions have varied. Different methodologies and processes for conducting LCA of biofuels make the results difficult to compare, in-turn making it difficult to make the best possible and informed decision. Of particular importance are the wide variability in country-specific conditions, modeling assumptions, data quality, chosen impact categories and indicators, scale of production, system boundaries, and co-product allocation. This study has a double purpose: conducting a critical evaluation comparing environmental LCA of biofuels from several conversion pathways and in several countries in the Pan American region using both qualitative and quantitative analyses, and making recommendations for harmonization with respect to biofuel LCA study features, such as study assumptions, inventory data, impact indicators, and reporting practices. The environmental management implications are discussed within the context of different national and international regulatory environments using a case study. The results from this study highlight LCA methodology choices that cause high variability in results and limit comparability among different studies, even among the same biofuel pathway, and recommendations are provided for improvement.

A Review of Environmental Life Cycle Assessments of Liquid Transportation Biofuels in the Pan American Region

Science.gov (United States)

Shonnard, David R.; Klemetsrud, Bethany; Sacramento-Rivero, Julio; Navarro-Pineda, Freddy; Hilbert, Jorge; Handler, Robert; Suppen, Nydia; Donovan, Richard P.

2015-12-01

Life-cycle assessment (LCA) has been applied to many biofuel and bioenergy systems to determine potential environmental impacts, but the conclusions have varied. Different methodologies and processes for conducting LCA of biofuels make the results difficult to compare, in-turn making it difficult to make the best possible and informed decision. Of particular importance are the wide variability in country-specific conditions, modeling assumptions, data quality, chosen impact categories and indicators, scale of production, system boundaries, and co-product allocation. This study has a double purpose: conducting a critical evaluation comparing environmental LCA of biofuels from several conversion pathways and in several countries in the Pan American region using both qualitative and quantitative analyses, and making recommendations for harmonization with respect to biofuel LCA study features, such as study assumptions, inventory data, impact indicators, and reporting practices. The environmental management implications are discussed within the context of different national and international regulatory environments using a case study. The results from this study highlight LCA methodology choices that cause high variability in results and limit comparability among different studies, even among the same biofuel pathway, and recommendations are provided for improvement.

Effect of the use of waste vegetable oil based biodiesel on the landscape in diesel engines

Directory of Open Access Journals (Sweden)

Bereczky Akos

2017-01-01

Full Text Available Petroleum-based fuels are now widely known as environmentally unfriendly because of non-renewable supplies and its contribution to environmental pollution. The challenge, therefore is to ensure appropriate energy supplies at minimum cost. There is an increasing energy demand in the world and nowadays it can be fulfilled only on the basis of fossil fuels. Therefore, it is necessary to evolve a renewable energy source with lower environmental impact. One alternative solution can be oils of plant origin, like vegetable oils and non-edible oils. With waste vegetable oil methyl ester, biofuel dependency can be decreased. Therefore, the aim of this research paper is to analyze the economic and environmental effect of waste vegetable oil methyl ester compared to fossil fuels. In some cases only the age of vehicles could raise burdens to biofuel utilization in road vehicles. Transport and energy policy – on a large scale – can play an important role in fuel consumption. Author is aware that waste vegetable oil methyl ester can play only a limited role in biofuel substitution.

Can biofuels be a solution to climate change? The implications of land use change-related emissions for policy

Science.gov (United States)

Khanna, Madhu; Crago, Christine L.; Black, Mairi

2011-01-01

Biofuels have gained increasing attention as an alternative to fossil fuels for several reasons, one of which is their potential to reduce the greenhouse gas (GHG) emissions from the transportation sector. Recent studies have questioned the validity of claims about the potential of biofuels to reduce GHG emissions relative to the liquid fossil fuels they are replacing when emissions owing to direct (DLUC) and indirect land use changes (ILUC) that accompany biofuels are included in the life cycle GHG intensity of biofuels. Studies estimate that the GHG emissions released from ILUC could more than offset the direct GHG savings by producing biofuels and replacing liquid fossil fuels and create a ‘carbon debt’ with a long payback period. The estimates of this payback period, however, vary widely across biofuels from different feedstocks and even for a single biofuel across different modelling assumptions. In the case of corn ethanol, this payback period is found to range from 15 to 200 years. We discuss the challenges in estimating the ILUC effect of a biofuel and differences across biofuels, and its sensitivity to the assumptions and policy scenarios considered by different economic models. We also discuss the implications of ILUC for designing policies that promote biofuels and seek to reduce GHG emissions. In a first-best setting, a global carbon tax is needed to set both DLUC and ILUC emissions to their optimal levels. However, it is unclear whether unilateral GHG mitigation policies, even if they penalize the ILUC-related emissions, would increase social welfare and lead to optimal emission levels. In the absence of a global carbon tax, incentivizing sustainable land use practices through certification standards, government regulations and market-based pressures may be a viable option for reducing ILUC. PMID:22482030

Chapter 11: New Conversion Technologies for Liquid Biofuels Production in Africa

NARCIS (Netherlands)

Batidzirai, B.; Smeets, E.M.W.; Faaij, A.P.C.

2012-01-01

On the longer term, the production of second generation biofuels from lignocellulosic biomass is expected to become economically competitive with gasoline and diesel. A pre-requisite is that several technological hurdles will be overcome and that a large, stable supply of lignocellulosic biomass

Biofuels versus food production: Does biofuels production increase food prices?

International Nuclear Information System (INIS)

Ajanovic, Amela

2011-01-01

Rapidly growing fossil energy consumption in the transport sector in the last two centuries caused problems such as increasing greenhouse gas emissions, growing energy dependency and supply insecurity. One approach to solve these problems could be to increase the use of biofuels. Preferred feedstocks for current 1st generation biofuels production are corn, wheat, sugarcane, soybean, rapeseed and sunflowers. The major problem is that these feedstocks are also used for food and feed production. The core objective of this paper is to investigate whether the recent increase of biofuels production had a significant impact on the development of agricultural commodity (feedstock) prices. The most important impact factors like biofuels production, land use, yields, feedstock and crude oil prices are analysed. The major conclusions of this analysis are: In recent years the share of bioenergy-based fuels has increased moderately, but continuously, and so did feedstock production, as well as yields. So far, no significant impact of biofuels production on feedstock prices can be observed. Hence, a co-existence of biofuel and food production seems possible especially for 2nd generation biofuels. However, sustainability criteria should be seriously considered. But even if all crops, forests and grasslands currently not used were used for biofuels production it would be impossible to substitute all fossil fuels used today in transport.

Biofuels barometer

International Nuclear Information System (INIS)

Anon.

2008-01-01

Biofuels represent 2,6% of the energy content of all the fuels used in road transport in Europe today. Nearly half of the target of 5,75% for 2010 set by the directive on biofuels has thus been reached in four years time. To achieve 5,75%, the european union is going to have to increase its production and doubtless call even more on imports, at a moment when biofuels are found at the core of complex ecological and economic issues. This analysis provided data and reflexions on the biofuels situation in the european union: consumption, bio-diesel, bio-ethanol, producers, environmental problems, directives. (A.L.B.)

A geographical assessment of vegetation carbon stocks and greenhouse gas emissions on potential microalgae-based biofuel facilities in the United States.

Science.gov (United States)

Quiroz Arita, Carlos; Yilmaz, Özge; Barlak, Semin; Catton, Kimberly B; Quinn, Jason C; Bradley, Thomas H

2016-12-01

The microalgae biofuels life cycle assessments (LCA) present in the literature have excluded the effects of direct land use change (DLUC) from facility construction under the assumption that DLUC effects are negligible. This study seeks to model the greenhouse gas (GHG) emissions of microalgae biofuels including DLUC by quantifying the CO 2 equivalence of carbon released to the atmosphere through the construction of microalgae facilities. The locations and types of biomass and Soil Organic Carbon that are disturbed through microalgae cultivation facility construction are quantified using geographical models of microalgae productivity potential including consideration of land availability. The results of this study demonstrate that previous LCA of microalgae to biofuel processes have overestimated GHG benefits of microalgae-based biofuels production by failing to include the effect of DLUC. Previous estimations of microalgae biofuel production potential have correspondingly overestimated the volume of biofuels that can be produced in compliance with U.S. environmental goals. Copyright © 2016 Elsevier Ltd. All rights reserved.

Systems analysis and futuristic designs of advanced biofuel factory concepts.

Energy Technology Data Exchange (ETDEWEB)

Chianelli, Russ; Leathers, James; Thoma, Steven George; Celina, Mathias C.; Gupta, Vipin P.

2007-10-01

The U.S. is addicted to petroleum--a dependency that periodically shocks the economy, compromises national security, and adversely affects the environment. If liquid fuels remain the main energy source for U.S. transportation for the foreseeable future, the system solution is the production of new liquid fuels that can directly displace diesel and gasoline. This study focuses on advanced concepts for biofuel factory production, describing three design concepts: biopetroleum, biodiesel, and higher alcohols. A general schematic is illustrated for each concept with technical description and analysis for each factory design. Looking beyond current biofuel pursuits by industry, this study explores unconventional feedstocks (e.g., extremophiles), out-of-favor reaction processes (e.g., radiation-induced catalytic cracking), and production of new fuel sources traditionally deemed undesirable (e.g., fusel oils). These concepts lay the foundation and path for future basic science and applied engineering to displace petroleum as a transportation energy source for good.

Recent patents on genetic modification of plants and microbes for biomass conversion to biofuels.

Science.gov (United States)

Lubieniechi, Simona; Peranantham, Thinesh; Levin, David B

2013-04-01

Development of sustainable energy systems based on renewable biomass feedstocks is now a global effort. Lignocellulosic biomass contains polymers of cellulose, hemicellulose, and lignin, bound together in a complex structure. Liquid biofuels, such as ethanol, can be made from biomass via fermentation of sugars derived from the cellulose and hemicellulose within lignocellulosic materials, but pre-treatment of the biomass to release sugars for microbial conversion is a significant barrier to commercial success of lignocellulosic biofuel production. Strategies to reduce the energy and cost inputs required for biomass pre-treatment include genetic modification of plant materials to reduce lignin content. Significant efforts are also underway to create recombinant microorganisms capable of converting sugars derived from lignocellulosic biomass to a variety of biofuels. An alternative strategy to reduce the costs of cellulosic biofuel production is the use of cellulolytic microorganisms capable of direct microbial conversion of ligno-cellulosic biomass to fuels. This paper reviews recent patents on genetic modification of plants and microbes for biomass conversion to biofuels.

High-performance liquid chromatography for determination of α-tocopherol in vegetables

Directory of Open Access Journals (Sweden)

Marcin Horbowicz

2013-12-01

Full Text Available A simple method for the determination of α-tocopherol in vegetables is described. The procedure consists of the following steps: saponification, extraction, silica-column clean-up, and high-performance liquid chromatography. Elution time for D, L-α-tocopherol was 9.0 min using a Zorbax Sil (250 x 4.6 mm column and an isocratic mobile phase of hexane-methanol (99.3 + 0.7, with a flow rate of 1 ml/min, and detection at 292 nm using a variable UV detector. The average recovery of α-tocopherol was 91.2%, and the minimum detectable amount was 0.1 mg/100 g of fresh vegetable tissue. This method is comparable to gas-chromatographic determination of α-tocopherol, but has fewer analytical steps and gives more reproducible results.

Extraction and preconcentration of trace Al and Cr from vegetable samples by vortex-assisted ionic liquid-based dispersive liquid-liquid microextraction prior to atomic absorption spectrometric determination.

Science.gov (United States)

Altunay, Nail; Yıldırım, Emre; Gürkan, Ramazan

2018-04-15

In the study, a simple, and efficient microextraction approach, which is termed as vortex-assisted ionic liquid-based dispersive liquid-liquid microextraction (VA-IL-DLLME), was developed for flame atomic absorption spectrometric analysis of aluminum (Al) and chromium (Cr) in vegetables. The method is based on the formation of anionic chelate complexes of Al(III) and Cr(VI) with o-hydroxy azo dye, at pH 6.5, and then extraction of the hydrophobic ternary complexes formed in presence of cetyltrimethylammonium bromide (CTAB) into a 125 μL volume of 1-butyl-3-methylimidazolium bis(trifluorosulfonyl)imide [C 4 mim][Tf 2 N]) as extraction solvent. Under optimum conditions, the detection limits were 0.02 µg L -1 in linear working range of 0.07-100 µg L -1 for Al(III), and 0.05 µg L -1 in linear working range of 0.2-80 µg L -1 for Cr(VI). After the validation by analysis of a certified reference material (CRM), the method was successfully applied to the determination of Al and Cr in vegetables using standard addition method. Copyright © 2017 Elsevier Ltd. All rights reserved.

Microalgae as a raw material for biofuels production.

Science.gov (United States)

Gouveia, Luisa; Oliveira, Ana Cristina

2009-02-01

Biofuels demand is unquestionable in order to reduce gaseous emissions (fossil CO(2), nitrogen and sulfur oxides) and their purported greenhouse, climatic changes and global warming effects, to face the frequent oil supply crises, as a way to help non-fossil fuel producer countries to reduce energy dependence, contributing to security of supply, promoting environmental sustainability and meeting the EU target of at least of 10% biofuels in the transport sector by 2020. Biodiesel is usually produced from oleaginous crops, such as rapeseed, soybean, sunflower and palm. However, the use of microalgae can be a suitable alternative feedstock for next generation biofuels because certain species contain high amounts of oil, which could be extracted, processed and refined into transportation fuels, using currently available technology; they have fast growth rate, permit the use of non-arable land and non-potable water, use far less water and do not displace food crops cultures; their production is not seasonal and they can be harvested daily. The screening of microalgae (Chlorella vulgaris, Spirulina maxima, Nannochloropsis sp., Neochloris oleabundans, Scenedesmus obliquus and Dunaliella tertiolecta) was done in order to choose the best one(s), in terms of quantity and quality as oil source for biofuel production. Neochloris oleabundans (fresh water microalga) and Nannochloropsis sp. (marine microalga) proved to be suitable as raw materials for biofuel production, due to their high oil content (29.0 and 28.7%, respectively). Both microalgae, when grown under nitrogen shortage, show a great increase (approximately 50%) in oil quantity. If the purpose is to produce biodiesel only from one species, Scenedesmus obliquus presents the most adequate fatty acid profile, namely in terms of linolenic and other polyunsaturated fatty acids. However, the microalgae Neochloris oleabundans, Nannochloropsis sp. and Dunaliella tertiolecta can also be used if associated with other

Biofuel technologies. Recent developments

Energy Technology Data Exchange (ETDEWEB)

Gupta, Vijai Kumar [National Univ. of Ireland Galway (Ireland). Dept. of Biochemistry; MITS Univ., Rajasthan (India). Dept. of Science; Tuohy, Maria G. (eds.) [National Univ. of Ireland Galway (Ireland). Dept. of Biochemistry

2013-02-01

Written by experts. Richly illustrated. Of interest to both experienced researchers and beginners in the field. Biofuels are considered to be the main potential replacement for fossil fuels in the near future. In this book international experts present recent advances in biofuel research and related technologies. Topics include biomethane and biobutanol production, microbial fuel cells, feedstock production, biomass pre-treatment, enzyme hydrolysis, genetic manipulation of microbial cells and their application in the biofuels industry, bioreactor systems, and economical processing technologies for biofuel residues. The chapters provide concise information to help understand the technology-related implications of biofuels development. Moreover, recent updates on biofuel feedstocks, biofuel types, associated co- and byproducts and their applications are highlighted. The book addresses the needs of postgraduate researchers and scientists across diverse disciplines and industrial sectors in which biofuel technologies and related research and experimentation are pursued.

Driving to destruction. The impacts of Europe's biofuel plans on carbon emissions and land

International Nuclear Information System (INIS)

Novis, J.

2010-11-01

A new study analyses the likely impacts on land use and greenhouse gas (GHG) emissions of biofuel use by 2020, as projected in recently published National Renewable Energy Action Plans (NREAPs) in 23 EU member states. The analysis includes evidence on size and impacts of 'indirect land use change' (ILUC) resulting from biofuel use. It is the most comprehensive study to date to quantify these effects. Previous attempts were not based on projections from NREAPs and in most cases excluded the effects of indirect land use change. The assessment comes at a key time for EU biofuel policy, with the European Commission due to report on how to address and minimise these emissions by the end of this year. The study reveals that the EU's plans for biofuels will result in the conversion of up to 69,000 square kilometres of land to agricultural use due to ILUC. This will potentially put forests, other natural ecosystems, and poor communities at risk. Land conversion on such a scale will lead to the release of carbon emissions from vegetation and soil, making biofuels more damaging to the climate than the fossil fuels they are designed to replace.

A simple and selective method for determination of phthalate biomarkers in vegetable samples by high pressure liquid chromatography-electrospray ionization-tandem mass spectrometry.

Science.gov (United States)

Zhou, Xi; Cui, Kunyan; Zeng, Feng; Li, Shoucong; Zeng, Zunxiang

2016-06-01

In the present study, solid-phase extraction cartridges including silica reversed-phase Isolute C18, polymeric reversed-phase Oasis HLB and mixed-mode anion-exchange Oasis MAX, and liquid-liquid extractions with ethyl acetate, n-hexane, dichloromethane and its mixtures were compared for clean-up of phthalate monoesters from vegetable samples. Best recoveries and minimised matrix effects were achieved using ethyl acetate/n-hexane liquid-liquid extraction for these target compounds. A simple and selective method, based on sample preparation by ultrasonic extraction and liquid-liquid extraction clean-up, for the determination of phthalate monoesters in vegetable samples by liquid chromatography/electrospray ionisation-tandem mass spectrometry was developed. The method detection limits for phthalate monoesters ranged from 0.013 to 0.120 ng g(-1). Good linearity (r(2)>0.991) between MQLs and 1000× MQLs was achieved. The intra- and inter-day relative standard deviation values were less than 11.8%. The method was successfully used to determine phthalate monoester metabolites in the vegetable samples. Copyright © 2016 Elsevier Ltd. All rights reserved.

Biofuels barometer

International Nuclear Information System (INIS)

Anon.

2011-01-01

In 2010 bio-fuel continued to gnaw away at petrol and diesel consumption in the European Union (EU). However its pace backs the assertion that bio-fuel consumption growth in EU slackened off in 2010. In the transport sector, it increased by only 1.7 Mtoe compared to 2.7 Mtoe in 2009. The final total bio-fuel consumption figure for 2010 should hover at around 13.9 Mtoe that can be broken down into 10.7 Mtoe for bio-diesel, 2.9 Mtoe for bio-ethanol and 0.3 Mtoe for others. Germany leads the pack for the consumption of bio-fuels and for the production of bio-diesel followed by France and Spain

Automobile industry and new bio-fuel oils: International panorama

International Nuclear Information System (INIS)

Hampel, G.

1992-01-01

In assessing the technical/economic feasibility of the direct combustion of vegetable oils in diesel type engines, this paper first points out the good results obtained in performance tests on these fuels in Elsberg engines, and their low sulfur and nitrogen oxides and carbon dioxide emission characteristics. It then assesses the improvements that are necessary in the development of marketable bio-fuel oils that conform to European Communities air pollution standards for automobiles. Further efforts must be made to reduce bio-fuel oil smoke emission levels, to compensate for their lower calorific value as compared with conventional diesel fuels, and to make them compatible with automobile finishing materials - paints and plastics. The paper suggests a set of suitable fiscal policies designed to favour the marketing of bio-diesel fuels based on their favourable pollution abating qualities - low greenhouse gas emissions and biodegradability

Lignocellulosic biomass-Thermal pretreatment with steam: Pretreatment techniques for biofuels and biorefineries

DEFF Research Database (Denmark)

Toor, Saqib; Rosendahl, Lasse; Hoffmann, Jessica

2013-01-01

With the ever rising demand for more energy and the limited availability of depleted world resources, many are beginning to look for alternatives to fossil fuels. Liquid biofuel, in particular, is of key interest to decrease our dependency on fuels produced from imported petroleum. Biomass pre......-treatment remains one of the most pressing challenges in terms of cost-effective production of biofuels. The digestibility of lingo-cellulosic biomass is limited by different factors such as the lignin content, the crystallinity of cellulose, and the available cellulose accessibility to hydrolytic enzymes. A number...

Micro-economic modelling of biofuel system in France to determine tax exemption policy under uncertainty

International Nuclear Information System (INIS)

Rozakis, S.; Sourie, J.-C.

2005-01-01

Liquid biofuel support program launched in 1993 in France is implemented through tax exemptions to biofuels produced by agro-industrial chains. Activity levels are fixed by decree and allocated by the government to the different chains. Based on earmarked budget increase voted in parliament, total quantity of biofuels will be increased by 50% in the horizon 2002-2003. A micro-economic biofuel activity model containing a detailed agricultural sector component, that is represented by 700 farms, is used to estimate costs and surpluses generated by the activity at the national level as well as tax exemption levels. Furthermore, Monte Carlo simulation has been used to search for efficient tax exemptions policies in an uncertain environment, where biofuel profitability is significantly affected by petroleum price and soja cake prices. Results suggest that, for the most efficient units both at the industry level (large size biomass conversion units) and at the agricultural sector level (most productive farms), unitary tax exemptions could be decreased by 10-20% for both biofuels, ethyl ether and methyl ester, with no risk for the viability of any existing chain. (author)

Micro-economic modelling of biofuel system in France to determine tax exemption policy under uncertainty

International Nuclear Information System (INIS)

Rozakis, S.; Sourie, J.-C.

2005-01-01

Liquid biofuel support program launched in 1993 in France is implemented through tax exemptions to biofuels produced by agro-industrial chains. Activity levels are fixed by decree and allocated by the government to the different chains. Based on earmarked budget increase voted in the parliament, total quantity of biofuels will be increased by 50% in the horizon 2002-2003. A micro-economic biofuel activity model containing a detailed agricultural sector component, that is represented by 700 farms, is used to estimate costs and surpluses generated by the activity at the national level as well as tax exemption levels. Furthermore, Monte Carlo simulation has been used to search for efficient tax exemptions policies in an uncertain environment, where biofuel profitability is significantly affected by petroleum price and soja cake prices. Results suggest that, for the most efficient units both at the industry level (large size biomass conversion units) and at the agricultural sector level (most productive farms), unitary tax exemptions could be decreased by 10-20% for both biofuels, ethyl ether and methyl ester, with no risk for the viability of any existing chain

Production of gaseous and liquid bio-fuels from the upgrading of lignocellulosic bio-oil in sub- and supercritical water: Effect of operating conditions on the process

International Nuclear Information System (INIS)

Remón, J.; Arcelus-Arrillaga, P.; García, L.; Arauzo, J.

2016-01-01

Highlights: • Bio-oil valorisation in sub-/supercritical water: a promising route for bio-fuels. • Effect of P, T, t, catalyst and water regime on bio-oil upgrading studied in depth. • Tailor-made route for H_2, CH_4 and liquid bio-fuel production in a single process. • Upgraded liquid with high proportions of C and H, higher HHV and less O content. - Abstract: This work analyses the influence of the temperature (310–450 °C), pressure (200–260 bar), catalyst/bio-oil mass ratio (0–0.25 g catalyst/g bio-oil), and reaction time (0–60 min) on the reforming in sub- and supercritical water of bio-oil obtained from the fast pyrolysis of pinewood. The upgrading experiments were carried out in a batch micro-bomb reactor employing a co-precipitated Ni–Co/Al–Mg catalyst. This reforming process turned out to be highly customisable for the valorisation of bio-oil for the production of either gaseous or liquid bio-fuels. Depending on the operating conditions and water regime (sub/supercritical), the yields to upgraded bio-oil (liquid), gas and solid varied as follows: 5–90%, 7–91% and 3–31%, respectively. The gas phase, having a LHV ranging from 2 to 17 MJ/m"3 STP, was made up of a mixture of H_2 (9–31 vol.%), CO_2 (41–84 vol.%), CO (1–22 vol.%) and CH_4 (1–45 vol.%). The greatest H_2 production from bio-oil (76% gas yield with a relative amount of H_2 of 30 vol.%) was achieved under supercritical conditions at a temperature of 339 °C, 200 bar of pressure and using a catalyst/bio-oil ratio of 0.2 g/g for 60 min. The amount of C, H and O (wt.%) in the upgraded bio-oil varied from 48 to 74, 4 to 9 and 13 to 48, respectively. This represents an increase of up to 37% and 171% in the proportions of C and H, respectively, as well as a decrease of up to 69% in the proportion of O. The HHV of the treated bio-oil shifted from 20 to 35 MJ/kg, which corresponds to an increase of up to 89% with respect to the HHV of the original bio-oil. With a

Market analysis biofuels. Implications for the armed forces in the Netherlands

International Nuclear Information System (INIS)

De Wilde, H.P.J.; Londo, H.M.

2009-11-01

Commercial road fuels are increasingly blended with biofuels. These biofuel blends impose risks for the specific application in the military environment. Therefore the Ministry of Defence has commissioned ECN to provide a market analysis of biofuel (blends) projected to become available up till 2030, with a focus on diesel fuels for ground use. We conclude that the percentage of conventional biodiesel (FAME) in the EU is likely to increase up to around 7% until 2020. It is unlikely that the share of FAME in commercially available diesel blends will increase above 10%. Hydrogenated vegetable oil (HVO) is expected to gain an increasing market share, especially in the time window 2015-2020. After 2020, the fraction of biogenic diesel in blends may further increase. However, this additional demand will most likely be met by the production of advanced high quality 2nd generation BTL diesel, thereby not reducing the fuel quality, also not for military applications. From a global perspective, it is most likely that up to 2030 biodiesel blends will only contain a minor average fraction of diesel from biological origin (below 3%). The main reason is that biofuel substitutes for petrol are expected to maintain their market share of about 80% of the total biofuel production. However, in addition to the EU, biodiesel blends up to 10% may also be introduced in regions with a large biodiesel feedstock supply potential, such as South East Asia, Latin America or Sub-Sahara Africa.

The influence of biofuels, economic and financial factors on daily returns of commodity futures prices

International Nuclear Information System (INIS)

Algieri, Bernardina

2014-01-01

Biofuels production has experienced rapid growth worldwide as one of the several strategies to promote green energy economies. Indeed, climate change mitigation and energy security have been frequent rationales behind biofuel policies, but biofuels production could generate negative impacts, such as additional demand for feedstocks, and therefore for land on which to grow them, with a consequent increase in food commodity prices. In this context, this paper examines the effect of biofuels and other economic and financial factors on daily returns of a group of commodity futures prices using Generalized Autoregressive Conditional Heteroskedasticity (GARCH) family models in univariate and multivariate settings. The results show that a complex of drivers are relevant in explaining commodity futures returns; more precisely, the Standard and Poor's (S and P) 500 positively affects commodity markets, while the US/Euro exchange rate brings about a decline in commodity returns. It turns out, in addition, that energy market returns are significant in explaining commodity returns on a daily basis, while monetary liquidity is not. This would imply that biofuel policy should be carefully monitored in order to avoid excessive first-generation subsidization, which would trigger a fuel vs. food conflict. - Highlights: • The effects of biofuels and other economic and financial factors on daily returns of commodity futures prices are examined. • A GARCH methodology in univariate and multivariate settings is adopted. • The results show that a complex of drivers is relevant in explaining commodity futures returns. • Energy market returns play a significant role in pushing commodity returns. • The increase in monetary liquidity does not contribute to changes in futures returns on a daily basis

Algal biofuels.

Science.gov (United States)

Razeghifard, Reza

2013-11-01

The world is facing energy crisis and environmental issues due to the depletion of fossil fuels and increasing CO2 concentration in the atmosphere. Growing microalgae can contribute to practical solutions for these global problems because they can harvest solar energy and capture CO2 by converting it into biofuel using photosynthesis. Microalgae are robust organisms capable of rapid growth under a variety of conditions including in open ponds or closed photobioreactors. Their reduced biomass compounds can be used as the feedstock for mass production of a variety of biofuels. As another advantage, their ability to accumulate or secrete biofuels can be controlled by changing their growth conditions or metabolic engineering. This review is aimed to highlight different forms of biofuels produced by microalgae and the approaches taken to improve their biofuel productivity. The costs for industrial-scale production of algal biofuels in open ponds or closed photobioreactors are analyzed. Different strategies for photoproduction of hydrogen by the hydrogenase enzyme of green algae are discussed. Algae are also good sources of biodiesel since some species can make large quantities of lipids as their biomass. The lipid contents for some of the best oil-producing strains of algae in optimized growth conditions are reviewed. The potential of microalgae for producing petroleum related chemicals or ready-make fuels such as bioethanol, triterpenic hydrocarbons, isobutyraldehyde, isobutanol, and isoprene from their biomass are also presented.

Environmental Impacts and Costs of Hydrotreated Vegetable Oils, Transesterified Lipids and Woody BTL—A Review

Directory of Open Access Journals (Sweden)

Andreas Brekke

2011-05-01

Full Text Available This article reviews and compares assessments of three biodiesel fuels: (1 transesterified lipids, (2 hydrotreated vegetable oils (HVO, and (3 woody biomass-to-liquid (BTL Fischer-Tropsch diesel and selected feedstock options. The article attempts to rank the environmental performance and costs of fuel and feedstock combinations. Due to inter-study differences in goal and study assumptions, the ranking was mostly qualitative and intra-study results are emphasized. Results indicate that HVO made from wastes or by-products such as tall oil, tallow or used cooking oil outperform transesterified lipids and BTL from woody material, both with respect to environmental life cycle impacts and costs. These feedstock options are, however, of limited availability, and to produce larger volumes of biofuels other raw materials must also be used. BTL from woody biomass seems promising with good environmental performance and the ability not to compete with food production. Production of biofuels from agricultural feedstock sources requires much energy and leads to considerable emissions due to agrochemical inputs. Thus, such biodiesel fuels are ranked lowest in this comparison. Production of feedstock is the most important life cycle stage. Avoiding detrimental land use changes and maintaining good agricultural or forestry management practices are the main challenges to ensure that biofuels can be a sustainable option for the future transport sector.

Second generation biofuels, an accelerator of the transition toward an economy driven by energy drawn from hydrogen

International Nuclear Information System (INIS)

Delabroy, O.

2013-01-01

The growth of the bio economy, especially in transportation, involves developing a bio-fuel industry. First generation bio-fuels were produced from plant sugars like starch or from plant oils. Second generation bio fuels use as raw materials the whole plant and especially agricultural and forestry wastes which extend the resource considerably and limit the competition between food use and fuel use. Second generation bio-fuels can be made with not only biological methods but also biomass-to-liquid processes borrowed from thermochemistry. Players in this field, including 'Air Liquide' company, are drawing up a technical and economic road-map for competitiveness in this emerging branch of industry. Since the thermochemical approach for gasifying a biomass also yields large quantities of hydrogen, the industrialization of this branch and concomitant production of bio-hydrogen at competitive prices provide leverage for accelerating the transition toward using H 2 for transportation

Biofuels worldwide

International Nuclear Information System (INIS)

His, St.

2004-01-01

After over 20 years of industrial development, the outlook for biofuels now looks bright. Recent developments indicate that the use of biofuels, previously confined to a handful of countries including Brazil and the United States, is 'going global' and a world market may emerge. However, these prospects could eventually be limited by constraints relative to resources and costs. The future of biofuels probably depends on the development of new technologies to valorize lignocellulosic substances such as wood and straw. (author)

Review of the direct thermochemical conversion of lignocellulosic biomass for liquid fuels

Directory of Open Access Journals (Sweden)

Jianchun JIANG,Junming XU,Zhanqian SONG

2015-03-01

Full Text Available Increased demand for liquid transportation fuels, environmental concerns and depletion of petroleum resources requires the development of efficient conversion technologies for production of second-generation biofuels from non-food resources. Thermochemical approaches hold great potential for conversion of lignocellulosic biomass into liquid fuels. Direct thermochemical processes convert biomass into liquid fuels in one step using heat and catalysts and have many advantages over indirect and biological processes, such as greater feedstock flexibility, integrated conversion of whole biomass, and lower operation costs. Several direct thermochemical processes are employed in the production of liquid biofuels depending on the nature of the feedstock properties: such as fast pyrolysis/liquefaction of lignocellulosic biomass for bio-oil, including upgrading methods, such as catalytic cracking and hydrogenation. Owing to the substantial amount of liquid fuels consumed by vehicular transport, converting biomass into drop-in liquid fuels may reduce the dependence of the fuel market on petroleum-based fuel products. In this review, we also summarize recent progress in technologies for large-scale equipment for direct thermochemical conversion. We focus on the technical aspects critical to commercialization of the technologies for production of liquid fuels from biomass, including feedstock type, cracking catalysts, catalytic cracking mechanisms, catalytic reactors, and biofuel properties. We also discuss future prospects for direct thermochemical conversion in biorefineries for the production of high grade biofuels.

Life Cycle Assessment for Biofuels

Science.gov (United States)

A presentation based on life cycle assessment (LCA) for biofuels is given. The presentation focuses on energy and biofuels, interesting environmental aspects of biofuels, and how to do a life cycle assessment with some examples related to biofuel systems. The stages of a (biofuel...

Biofuel Database

Science.gov (United States)

Biofuel Database (Web, free access)   This database brings together structural, biological, and thermodynamic data for enzymes that are either in current use or are being considered for use in the production of biofuels.

Transporter-mediated biofuel secretion.

Science.gov (United States)

Doshi, Rupak; Nguyen, Tuan; Chang, Geoffrey

2013-05-07

Engineering microorganisms to produce biofuels is currently among the most promising strategies in renewable energy. However, harvesting these organisms for extracting biofuels is energy- and cost-intensive, limiting the commercial feasibility of large-scale production. Here, we demonstrate the use of a class of transport proteins of pharmacological interest to circumvent the need to harvest biomass during biofuel production. We show that membrane-embedded transporters, better known to efflux lipids and drugs, can be used to mediate the secretion of intracellularly synthesized model isoprenoid biofuel compounds to the extracellular milieu. Transporter-mediated biofuel secretion sustainably maintained an approximate three- to fivefold boost in biofuel production in our Escherichia coli test system. Because the transporters used in this study belong to the ubiquitous ATP-binding cassette protein family, we propose their use as "plug-and-play" biofuel-secreting systems in a variety of bacteria, cyanobacteria, diatoms, yeast, and algae used for biofuel production. This investigation showcases the potential of expressing desired membrane transport proteins in cell factories to achieve the export or import of substances of economic, environmental, or therapeutic importance.

Biofuels Fuels Technology Pathway Options for Advanced Drop-in Biofuels Production

Energy Technology Data Exchange (ETDEWEB)

Kevin L Kenney

2011-09-01

Advanced drop-in hydrocarbon biofuels require biofuel alternatives for refinery products other than gasoline. Candidate biofuels must have performance characteristics equivalent to conventional petroleum-based fuels. The technology pathways for biofuel alternatives also must be plausible, sustainable (e.g., positive energy balance, environmentally benign, etc.), and demonstrate a reasonable pathway to economic viability and end-user affordability. Viable biofuels technology pathways must address feedstock production and environmental issues through to the fuel or chemical end products. Potential end products include compatible replacement fuel products (e.g., gasoline, diesel, and JP8 and JP5 jet fuel) and other petroleum products or chemicals typically produced from a barrel of crude. Considering the complexity and technology diversity of a complete biofuels supply chain, no single entity or technology provider is capable of addressing in depth all aspects of any given pathway; however, all the necessary expert entities exist. As such, we propose the assembly of a team capable of conducting an in-depth technology pathway options analysis (including sustainability indicators and complete LCA) to identify and define the domestic biofuel pathways for a Green Fleet. This team is not only capable of conducting in-depth analyses on technology pathways, but collectively they are able to trouble shoot and/or engineer solutions that would give industrial technology providers the highest potential for success. Such a team would provide the greatest possible down-side protection for high-risk advanced drop-in biofuels procurement(s).

Biofuels - the UFIP position; Biocarburants - la position de l'UFIP

Energy Technology Data Exchange (ETDEWEB)

NONE

2004-07-01

Since 2003 a directive promote the biofuels use. The industry is then using them in ETBE (Ethyl Tertio Butyl Ether) fuels and in diesel oil of vegetal oils esters EMHV. Meanwhile some of them present technical difficulties and must free themselves from fiscal incentives which make them competitive. For these reasons, the UFIP (french union of petroleum industries) do not agree their obligatory incorporation. (A.L.B.)

Bio-fuel barometer

International Nuclear Information System (INIS)

2015-01-01

After a year of doubt and decline the consumption of bio-fuel resumed a growth in 2014 in Europe: +6.1% compared to 2013, to reach 14 millions tep (Mtep) that is just below the 2012 peak. This increase was mainly due to bio-diesel. By taking into account the energy content and not the volume, the consumption of bio-diesel represented 79.7% of bio-fuel consumption in 2014, that of bio-ethanol only 19.1% and that of biogas 1%. The incorporating rate of bio-fuels in fuels used for transport were 4.6% in 2013 and 4.9% in 2014. The trend is good and the future of bio-fuel seems clearer as the European Union has set a not-so-bad limit of 7% for first generation bio-fuels in order to take into account the CASI effect. The CASI effect shows that an increase of the consumption of first generation bio-fuels (it means bio-fuels produced from food crops like rape, soy, cereals, sugar beet,...) implies in fact a global increase in greenhouse gas release that is due to a compensation phenomenon. More uncultivated lands (like forests, grasslands, bogs are turned into cultivated lands in order to compensate lands used for bio-fuel production. In most European countries the consumption of bio-diesel increased in 2014 while it was a bad year for the European industry of ethanol because ethanol prices dropped by 16 %. Oil companies are now among the most important producers of bio-diesel in Europe.

World Biofuels Study

Energy Technology Data Exchange (ETDEWEB)

Alfstad,T.

2008-10-01

This report forms part of a project entitled 'World Biofuels Study'. The objective is to study world biofuel markets and to examine the possible contribution that biofuel imports could make to help meet the Renewable Fuel Standard (RFS) of the Energy Independence and Security Act of 2007 (EISA). The study was sponsored by the Biomass Program of the Assistant Secretary for Energy Efficiency and Renewable Energy (EERE), U.S. Department of Energy. It is a collaborative effort among the Office of Policy and International Affairs (PI), Department of Energy and Oak Ridge National Laboratory (ORNL), National Renewable Energy Laboratory (NREL) and Brookhaven National Laboratory (BNL). The project consisted of three main components: (1) Assessment of the resource potential for biofuel feedstocks such as sugarcane, grains, soybean, palm oil and lignocellulosic crops and development of supply curves (ORNL). (2) Assessment of the cost and performance of biofuel production technologies (NREL). (3) Scenario-based analysis of world biofuel markets using the ETP global energy model with data developed in the first parts of the study (BNL). This report covers the modeling and analysis part of the project conducted by BNL in cooperation with PI. The Energy Technology Perspectives (ETP) energy system model was used as the analytical tool for this study. ETP is a 15 region global model designed using the MARKAL framework. MARKAL-based models are partial equilibrium models that incorporate a description of the physical energy system and provide a bottom-up approach to study the entire energy system. ETP was updated for this study with biomass resource data and biofuel production technology cost and performance data developed by ORNL and NREL under Tasks 1 and 2 of this project. Many countries around the world are embarking on ambitious biofuel policies through renewable fuel standards and economic incentives. As a result, the global biofuel demand is expected to grow very

Biofuel: an alternative to fossil fuel for alleviating world energy and economic crises.

Science.gov (United States)

Bhattarai, Keshav; Stalick, Wayne M; McKay, Scott; Geme, Gija; Bhattarai, Nimisha

2011-01-01

The time has come when it is desirable to look for alternative energy resources to confront the global energy crisis. Consideration of the increasing environmental problems and the possible crisis of fossil fuel availability at record high prices dictate that some changes will need to occur sooner rather than later. The recent oil spill in the Gulf of Mexico is just another example of the environmental threats that fossil fuels pose. This paper is an attempt to explore various bio-resources such as corn, barley, oat, rice, wheat, sorghum, sugar, safflower, and coniferous and non-coniferous species for the production of biofuels (ethanol and biodiesel). In order to assess the potential production of biofuel, in this paper, countries are organized into three groups based on: (a) geographic areas; (b) economic development; and(c) lending types, as classified by the World Bank. First, the total fossil fuel energy consumption and supply and possible carbon emission from burning fossil fuel is projected for these three groups of countries. Second, the possibility of production of biofuel from grains and vegetative product is projected. Third, a comparison of fossil fuel and biofuel is done to examine energy sustainability issues.

78 FR 34975 - Notice of Contract Proposals (NOCP) for the Advanced Biofuels Payment Program

Science.gov (United States)

2013-06-11

... Dun and Bradstreet Data Universal Numbering System (DUNS) number, which can be obtained at no cost via... liquid advanced biofuel per year or exceeding 15,900,000 million British Thermal Units of biogas and...

Can the Nigerian biofuel policy and incentives (2007) transform Nigeria into a biofuel economy?

International Nuclear Information System (INIS)

Ohimain, Elijah I.

2013-01-01

Nigeria's economy is largely dependent on petroleum, yet the country is suffering from fuel supply shortages. In response to the transportation fuel supply difficulties in Nigeria, the country released the Nigerian Biofuel Policy and Incentives in 2007 to create favorable investment climate for the entrance of Nigeria into the biofuel sector. The paper assessed the progress made thus far by Nigeria, 4 years after the Nigerian biofuel was released in an attempt to answer the question whether the policy is adequate to transform Nigeria into a biofuel economy. The study found that little progress has been made, which includes commencement of the construction of 20 bioethanol factories, installation of biofuel handling facilities at two depots (Mosimi and Atlas Cove), and selection of retail outlets for biofuel/conventional fuel mix. The site construction of the announced biofuel projects is now slow and other progress is marginal. We therefore conclude that the Nigerian biofuel policy is unlikely to transform Nigeria into a biofuel economy unless the Government revert and refocus on biofuel and include additional financial incentives such as grants and subsidy to complement the tax waivers (income, import duty, VAT), loans, and insurance cover contained in the policy. - Highlights: ► Nigeria's economy is dependent on petroleum, yet the country is suffering from fuel shortages. ► The Nigerian Biofuel Policy and Incentives was released in 2007. ► Little progress has been made since the policy was released 4 years ago. ► Hence, the policy is unlikely to transform Nigeria into a biofuel economy

Economical analysis of biofuel products and nuclear plant hydrogen

International Nuclear Information System (INIS)

Edwaren Liun

2011-01-01

The increasing in oil prices over the last six years is unprecedented that should be seen as a spur to increased efficiency. The surge in oil prices on the world market today is driven by strong demand factors in the depletion of world oil reserves. To replace the fuel oil from the bowels of the earth the various alternatives should be considered, including other crops or vegetable oil production of bio-fuels and hydrogen are produced by high temperature nuclear reactors. Biofuels in the form of ethanol made from corn or sugar cane and biodiesel made from palm oil or jatropha. With the latest world oil prices, future fuel vegetable oil and nuclear hydrogen-based energy technologies become popular in various parts of the world. Economics of biodiesel will be changed in accordance with world oil prices and subsidy regulations which apply to fuel products. On the other hand the role of nuclear energy in hydrogen production with the most potential in the techno-economics is a form of high temperature steam electrolysis, using heat and electricity from nuclear reactors. The production cost of biodiesel fuel on the basis of ADO type subsidy is 10.49 US$/MMBTU, while the production cost of hydrogen as an energy carrier of high temperature reactor is 15.30 US$/MMBTU. Thus, both types seem to have strong competitiveness. (author)

Long-term developments in the transport sector -- comparing biofuel and hydrogen roadmaps

Energy Technology Data Exchange (ETDEWEB)

Uyterlinde, M.A.; Londo, M.; Godfroij, P.; Jeeninga, H.

2007-07-01

In view of climate change and declining oil reserves, alternative fuels for transport receive increasing attention. Two promising options are biofuels, of which the market penetration has already started, and hydrogen, which, when used in fuel cell cars, could lead to zero-emission vehicles. This paper draws on the results of two ongoing EU projects in which roadmaps are being developed for respectively biofuels and hydrogen . The most important potential conflict lies in competition for biomass as a feedstock. In this context, the hydrogen-fuel cell route has the advantage of a higher efficiency (in terms of km driven per ha or tonne biomass) than biofuels. Furthermore, hydrogen is more flexible in feedstock, since it can also be produced in a climate-friendly way from fossil resources such as coal. Synergy between biofuels and hydrogen is in gasification technology. This technology is required both for biomass-to-liquids, one of the more promising biofuels, and for hydrogen production from biomass and/or coal. Our analysis indicates that the transportation sector will need both options in the long term: while hydrogen may become dominant for passenger cars, greening of long-distance heavy duty transport will become dependent on a bio-based diesel substitute. (auth)

Carbon and energy balances for a range of biofuels options

Energy Technology Data Exchange (ETDEWEB)

Elsayed, M.A.; Matthews, R.; Mortimer, N.D.

2003-03-01

This is the final report of a project to produce a set of baseline energy and carbon balances for a range of electricity, heat and transport fuel production systems based on biomass feedstocks. A list of 18 important biofuel technologies in the UK was selected for study of their energy and carbon balances in a consistent approach. Existing studies on these biofuel options were reviewed and their main features identified in terms of energy input, greenhouse gas emissions (carbon dioxide, methane, nitrous oxide and total), transparency and relevance. Flow charts were produced to represent the key stages of the production of biomass and its conversion to biofuels. Outputs from the study included primary energy input per delivered energy output, carbon dioxide outputs per delivered energy output, methane output per delivered energy output, nitrous oxide output per delivered energy output and total greenhouse gas requirements. The net calorific value of the biofuel is given where relevant. Biofuels studied included: biodiesel from oilseed rape and recycled vegetable oil; combined heat and power (CHP) by combustion of wood chip from forestry residues; CHP by gasification of wood chip from short rotation coppice; electricity from the combustion of miscanthus, straw, wood chip from forestry residues and wood chip from short rotation coppice; electricity from gasification of wood chip from forestry residues and wood chip from short rotation coppice; electricity by pyrolysis of wood chip from forestry residues and wood chip from short rotation coppice; ethanol from lignocellulosics, sugar beet and wheat; heat (small scale) from combustion of wood chip from forestry residues and wood chip from short rotation coppice; and rapeseed oil from oilseed rape.

Strategic niche management for biofuels: Analysing past experiments for developing new biofuel policies

International Nuclear Information System (INIS)

Laak, W.W.M. van der; Raven, R.P.J.M.; Verbong, G.P.J.

2007-01-01

Biofuels have gained a lot of attention since the implementation of the 2003 European Directive on biofuels. In the Netherlands the contribution of biofuels is still very limited despite several experiments in the past. This article aims to contribute to the development of successful policies for stimulating biofuels by analysing three experiments in depth. The approach of strategic niche management (SNM) is used to explain success and failure of these projects. Based on the analysis as well as recent innovation literature we develop a list of guidelines that is important to consider when developing biofuel policies

Biofuels: which interest, which perspectives?

International Nuclear Information System (INIS)

2006-01-01

This paper is a synthesis of several studies concerning the production and utilization of bio-fuels: energy balance and greenhouse effect of the various bio-fuel systems; economical analysis and profitability of bio-fuel production; is the valorization of bio-fuel residues and by-products in animal feeding a realistic hypothesis?; assessment of the cost for the community due to tax exemption for bio-fuels

Biofuel from "humified" biomass

Science.gov (United States)

Kpogbemabou, D.; Lemée, L.; Amblès, A.

2009-04-01

In France, 26% of the emissions of greenhouse effect gas originate from transportation which depends for 87% on fossil fuels. Nevertheless biofuels can contribute to the fight against climate change while reducing energetic dependence. Indeed biomass potentially represents in France 30 Mtoe a year that is to say 15% national consumption. But 80% of these resources are made of lignocellulosic materials which are hardly exploitable. First-generation biofuels are made from sugar, starch, vegetable oil, or animal fats. Due to their competition with human food chain, first-generation biofuels could lead to food shortages and price rises. At the contrary second-generation biofuel production can use a variety of non food crops while using the lignocellulosic part of biomass [1]. Gasification, fermentation and direct pyrolysis are the most used processes. However weak yields and high hydrogen need are limiting factors. In France, the National Program for Research on Biofuels (PNRB) aims to increase mobilizable biomass resource and to develop lignocellulosic biomass conversion. In this context, the LIGNOCARB project studies the liquefaction of biodegraded biomass in order to lower hydrogen consumption. Our aim was to develop and optimize the biodegradation of the biomass. Once the reactor was achieved, the influence of different parameters (starting material, aeration, moisture content) on the biotransformation process was studied. The monitored parameters were temperature, pH and carbon /nitrogen ratio. Chemical (IHSS protocol) and biochemical (van Soest) fractionations were used to follow the maturity ("humic acid"/"fulvic acid" ratio) and the biological stability (soluble, hemicelluloses, celluloses, lignin) of the organic matter (OM). In example, the increase in lignin can be related to the stabilization since the OM becomes refractory to biodegradation whereas the increase in the AH/AF ratio traduces "humification". However, contrarily to the composting process, we do

In-vial liquid-liquid microextraction-capillary electrophoresis method for the determination of phenolic acids in vegetable oils.

Science.gov (United States)

Abu Bakar, Nur Bahiyah; Makahleh, Ahmad; Saad, Bahruddin

2012-09-12

An in-vial liquid-liquid microextraction method was developed for the selective extraction of the phenolic acids (caffeic, gallic, cinnamic, ferulic, chlorogenic, syringic, vanillic, benzoic, p-hydroxybenzoic, 2,4-dihydroxybenzoic, o-coumaric, m-coumaric and p-coumaric) in vegetable oil samples. The optimised extraction conditions for 20 g sample were: volume of diluent (n-hexane), 2 mL; extractant, methanol: 5 mM sodium hydroxide (60:40; v/v); volume of extractant, 300 μL (twice); vortex, 1 min; centrifugation, 5 min. Recoveries for the studied phenolic acids were 80.1-119.5%. The simultaneous determination of the phenolic acid extracts was investigated by capillary electrophoresis (CE). Separations were carried out on a bare fused-silica capillary (50 μm i.d.× 40 cm length) involving 25 mM sodium tetraborate (pH 9.15) and 5% methanol as CE background electrolyte in the normal polarity mode, voltage of 30 kV, temperature of 25°C, injection time of 4s (50 mbar) and electropherograms were recorded at 200 nm. The phenolic acids were successfully separated in less than 10 min. The validated in-vial LLME-CE method was applied to the determination of phenolic acids in vegetable oil samples (extra virgin olive oil, virgin olive oil, pure olive oil, walnut oil and grapeseed oil). The developed method shows significant advantages over the current methods as lengthy evaporation step is not required. Copyright © 2012 Elsevier B.V. All rights reserved.

Modified Dispersive Liquid-Liquid Micro Extraction Using Green Solvent for Determination of Polycyclic Aromatic Hydrocarbons (PAHs) in Vegetable Samples

International Nuclear Information System (INIS)

Kin, C.M.; Shing, W.L.

2016-01-01

According to International Agency for Research on Cancer (IARC), most of Polycyclic Aromatic Hydrocarbons (PAHs) known as genotoxic human carcinogen and mutagenic. PAHs represent as poorly degradable pollutants that exist in soils, sediments, surface water and atmosphere. A simple, rapid and sensitive extraction method termed modified Dispersive Liquid-Liquid Micro extraction (DLLME) using green solvent was developed to determine PAHs in vegetable samples namely radish, cabbage and cucumber prior to Gas Chromatography Flame Ionization Detection (GC-FID). The extraction method is based on replacing chlorinated organic extraction solvent in the conventional DLLME with low toxic solvent, 1-bromo-3-methylbutane without using dispersive solvent. Several experimental factors such as type and volume of extraction solvents, extraction time, confirmation of 12 PAHs by GC-MS, recovery percentages on vegetable samples and the comparative analysis with conventional DLLME were carried out. Both DLLME were successfully extracted 12 types of PAHs. In modified DLLME, the recoveries of the analytes obtained were in a range of 72.72 - 88.07 % with RSD value below 7.5 % which is comparable to the conventional DLLME. The use of microliter of low toxic extraction solvent without addition of dispersive solvent caused the method is economic and environmental friendly which is fulfill the current requirement, green chemistry based analytical method. (author)

The atomization and burning of biofuels in the combustion chambers of gas turbine engines

Science.gov (United States)

Maiorova, A. I.; Vasil'ev, A. Yu; Sviridenkov, A. A.; Chelebyan, O. G.

2017-11-01

The present work analyzes the effect of physical properties of liquid fuels with high viscosity (including biofuels) on the spray and burning characteristics. The study showed that the spray characteristics behind devices well atomized fuel oil, may significantly deteriorate when using biofuels, until the collapse of the fuel bubble. To avoid this phenomenon it is necessary to carry out the calculation of the fuel film form when designing the nozzles. As a result of this calculation boundary curves in the coordinates of the Reynolds number on fuel - the Laplace number are built, characterizing the transition from sheet breakup to spraying. It is shown that these curves are described by a power function with the same exponent for nozzles of various designs. The swirl of air surrounding the nozzle in the same direction, as the swirl of fuel film, can significantly improve the performance of atomization of highly viscous fuel. Moreover the value of the tangential air velocity has the determining influence on the film shape. For carrying out of hot tests in aviation combustor some embodiments of liquid fuels were proved and the most preferred one was chosen. Fire tests of combustion chamber compartment at conventional fuel has shown comprehensible characteristics, in particular wide side-altars of the stable combustion. The blended biofuel application makes worse combustion stability in comparison with kerosene. A number of measures was recommended to modernize the conventional combustors when using biofuels in gas turbine engines.

Economic evaluation of technology for a new generation biofuel production using wastes.

Science.gov (United States)

Koutinas, Athanasios; Kanellaki, Maria; Bekatorou, Argyro; Kandylis, Panagiotis; Pissaridi, Katerina; Dima, Agapi; Boura, Konstantina; Lappa, Katerina; Tsafrakidou, Panagiota; Stergiou, Panagiota-Yiolanda; Foukis, Athanasios; Gkini, Olga A; Papamichael, Emmanuel M

2016-01-01

An economic evaluation of an integrated technology for industrial scale new generation biofuel production using whey, vinasse, and lignocellulosic biomass as raw materials is reported. Anaerobic packed-bed bioreactors were used for organic acids production using initially synthetic media and then wastes. Butyric, lactic and acetic acid were predominately produced from vinasse, whey, and cellulose, respectively. Mass balance was calculated for a 16,000L daily production capacity. Liquid-liquid extraction was applied for recovery of the organic acids using butanol-1 as an effective extraction solvent which serves also as the alcohol for the subsequent enzyme-catalyzed esterification. The investment needed for the installation of the factory was estimated to about 1.7million€ with depreciation excepted at about 3months. For cellulosics, the installation investment was estimated to be about 7-fold higher with depreciation at about 1.5years. The proposed technology is an alternative trend in biofuel production. Copyright © 2015. Published by Elsevier Ltd.

Biofuels in China.

Science.gov (United States)

Tan, Tianwei; Yu, Jianliang; Lu, Jike; Zhang, Tao

2010-01-01

The Chinese government is stimulating the biofuels development to replace partially fossil fuels in the transport sector, which can enhance energy security, reduce greenhouse gas emissions, and stimulate rural development. Bioethanol, biodiesel, biobutanol, biogas, and biohydrogen are the main biofuels developed in China. In this chapter, we mainly present the current status of biofuel development in China, and illustrate the issues of feedstocks, food security and conversion processes.

An economic evaluation of alternative biofuel deployment scenarios in the USA

Directory of Open Access Journals (Sweden)

Gbadebo Oladosu

2017-05-01

Full Text Available Energy market conditions have shifted dramatically since the USA renewable fuel standards (RFS1 in 2005; RFS2 in 2007 were enacted. The USA has transitioned from an increasing dependence on oil imports to abundant domestic oil production. In addition, increases in the use of ethanol, the main biofuel currently produced in the USA, is now limited by the blend wall constraint. Given this, the current study evaluates alternative biofuel deployment scenarios in the USA, accounting for changes in market conditions. The analysis is performed with a general equilibrium model that reflects the structure of the USA biofuel market as the transition to advanced biofuels begins. Results suggest that ethanol consumption would increase, albeit slowly, if current biofuel deployment rates of about 10% are maintained as persistently lower oil prices lead to a gradual increase in the consumption of liquid transportation fuels. Without the blend wall constraint, this study finds that the overall economic impact of a full implementation of the USA RFS2 policy is largely neutral before 2022. However, the economic impacts become slightly negative under the blend wall constraint since more expensive bio-hydrocarbons are needed to meet the RFS2 mandates. Results for a scenario with reduced advanced biofuel deployment based on current policy plans show near neutral economic impacts up to 2027. This scenario is also consistent with another scenario where the volume of bio-hydrocarbons deployed is reduced to adjust for its higher cost and energy content relative to deploying the mandated RFS2 advanced biofuel volumes as ethanol. The important role of technological change is demonstrated under pioneer and accelerated technology scenarios, with the latter leading to neutral or positive economic effects up to 2023 under most blend wall scenarios. All scenarios evaluated in this study are found to have positive long-term benefits for the USA economy.

Four myths surrounding U.S. biofuels

International Nuclear Information System (INIS)

Wetzstein, M.; Wetzstein, H.

2011-01-01

The rapid growth of biofuels has elicited claims and predictions concerning the current and future role of these fuels in the U.S. vehicle-fuel portfolio. These assertions are at times based on a false set of assumptions concerning the biofuel's market related to the petroleum and agricultural commodities markets, and the nonmarket consequences of our automobile driving. As an aid in clarifying these market relations, the following four biofuel myths are presented: (1) biofuels will be adopted because we will soon run out of oil, (2) biofuels will solve the major external costs associated with our automobile driving, (3) biofuels cause food price inflation (the food before fuel issue), and (4) biofuels will become a major vehicle fuel. - Highlights: → Biofuels will be adopted because we will soon run out of oil. → Biofuels will solve the major external costs associated with our automobile driving. → Biofuels cause food price inflation (the food before fuel issue). → Biofuels will become a major vehicle fuel.

Panorama 2007: Biofuels Worldwide

International Nuclear Information System (INIS)

Prieur-Vernat, A.; His, St.

2007-01-01

The biofuels market is booming: after more than 20 years of industrial development, global bio-fuel production is growing fast. Willingness to reduce their oil dependence and necessity to promote low-carbon energies are the two main drivers for states to support biofuels development. (author)

Response of Sesamum radiatum Schum vegetable and seed yield ...

African Journals Online (AJOL)

Response of Sesamum radiatum Schum vegetable and seed yield to phosphorus ... Western region of Nigeria and Research Farm of the Bio-fuel and Alternate ... that 90 kg P2O5 ha-1 was appropriate with basal application of 80 kg N ha-1.

An overview of biofuels

International Nuclear Information System (INIS)

Qureshi, I.H.; Ahmad, S.

2007-01-01

Biofuels for transport have received considerable attention due to rising oil prices and growing concern about greenhouse gas emissions. Biofuels namely ethanol and esters of fatty acids have the potential to displace a substantial amount of petroleum fuel in the next few decades which will help to conserve fossil fuel resources. Life cycle analyses show that biofuels release lesser amount of greenhouse gases and other air pollutants. Thus biofuels are seen as a pragmatic step towards reducing carbon dioxide emission from transport sector. Biofuels are compatible with petroleum and combustion engines can easily operate with 10% ethanol and 20% biodiesel blended fuel with no modification. However higher concentrations require 'flex-fuel' engines which automatically adjust fuel injection depending upon fuel mix. Biofuels are derived from renewable biomass and can be produced from a variety of feedstocks. The only limiting factors are the availability of cropland, growth of plants and the climate. Countries with warmer climate can get about five times more biofuel crops from each acre of land than cold climate countries. Genetically modified crops and fast growing trees are being developed increase the production of energy crops. (author)

Macroalgae-Derived Biofuel: A Review of Methods of Energy Extraction from Seaweed Biomass

Directory of Open Access Journals (Sweden)

John J. Milledge

2014-11-01

Full Text Available The potential of algal biomass as a source of liquid and gaseous biofuels is a highly topical theme, but as yet there is no successful economically viable commercial system producing biofuel. However, the majority of the research has focused on producing fuels from microalgae rather than from macroalgae. This article briefly reviews the methods by which useful energy may be extracted from macroalgae biomass including: direct combustion, pyrolysis, gasification, trans-esterification to biodiesel, hydrothermal liquefaction, fermentation to bioethanol, fermentation to biobutanol and anaerobic digestion, and explores technical and engineering difficulties that remain to be resolved.

Biomass, biogas and biofuels

International Nuclear Information System (INIS)

Colonna, P.

2011-01-01

This article reviews the different ways to produce biofuels. It appears that there are 3 generations of biofuels. The first generation was based on the use of the energetic reserves of the plants for instance sugar from beetroot or starch from cereals or oil from oleaginous plants. The second generation is based on a more complete use of the plant, the main constituents of the plant: cellulose and lignin are turned into energy. The third generation of biofuels relies on the use of energy plants and algae. The second generation of biofuels reduces drastically the competition between an alimentary use and a non-alimentary use of plants. In 2008 the production of biofuels reached 43 Mtep which represents only 2% of all the energy used in the transport sector. The international agency for energy expects that the production of biofuels would be multiplied by a factor 6 (even 10 if inciting measures are taken) by 2030. (A.C.)

NREL biofuels program overview

Energy Technology Data Exchange (ETDEWEB)

Mielenz, J.R. [National Renewable Energy Laboratory, Golden, CO (United States)

1996-09-01

The NREL Biofuels Program has been developing technology for conversion of biomass to transportation fuels with support from DOE Office of Transportation Technologies Biofuels System Program. This support has gone to both the National Renewable Energy Laboratory, and over 100 subcontractors in universities and industry. This overview will outline the value of the Biofuels development program to the Nation, the current status of the technology development, and what research areas still need further support and progress for the development of a biofuels industry in the US.

Making biofuels sustainable

International Nuclear Information System (INIS)

Gallagher, Ed

2008-01-01

Full text: As the twentieth century drew to a close, there was considerable support for the use of biofuels as a source of renewable energy. To many people, they offered significant savings in greenhouse gas emissions compared to fossil fuels, an opportunity for reduced dependency on oil for transport, and potential as a counter weight to increasing oil prices. They also promised an opportunity for rural economies to benefit from a new market for their products and a chance of narrowing the gap between rich and poor nations. Biofuel development was encouraged by government subsidies, and rapid growth occurred in many parts of the world. Forty per cent of Brazilian sugar cane is used for biofuel production, for example, as is almost a quarter of maize grown in the United States. Although only around 1 per cent of arable land is cultivated to grow feedstock for biofuels, there has been increasing concern over the way a largely unchecked market has developed, and about its social and environmental consequences. Recent research has confirmed that food prices have been driven significantly higher by competition for prime agricultural land and that savings in greenhouse gas emissions are much smaller - and in some cases entirely eliminated - when environmentally important land, such as rainforest, is destroyed to grow biofuels. As a result, many now believe that the economic benefits of biofuels have been obtained at too high a social and environmental price, and they question whether they can be a truly sustainable source of energy. The United Kingdom has always had sustainability at the heart of its biofuel policies and set up the Renewable Fuels Agency to ensure that this goal was met. The direct effects of biofuel production are already being assessed through five measures of environmental performance and two measures of social performance, as well as measures of the energy efficiency of the production processes used and of the greenhouse gas savings achieved

Basic data biogas Germany. Solid fuels, biofuels, biogas; Basisdaten Bioenergie Deutschland. Festbrennstoffe, Biokraftstoffe, Biogas

Energy Technology Data Exchange (ETDEWEB)

NONE

2011-09-15

The brochure ''Basic data biogas Germany'' gives statistical information about (a) renewable energies: primary energy consumption, power generation, energy supply, avoidance of greenhouse gases; (b) Solid fuels: energetic utilization, wood pellets, energy consumption, comparison to heating oil; (c) Biofuels: consumption, bioethanol, biodiesel, vegetable oils; (d) Biogas: biogas power plants, energy content, production, legal aspects.

Basic data biogas Germany. Solid fuels, biofuels, biogas; Basisdaten Bioenergie Deutschland. Festbrennstoffe - Biokraftstoffe - Biogas

Energy Technology Data Exchange (ETDEWEB)

NONE

2012-08-15

The brochure ''Basic data biogas Germany'' gives statistical information about (a) renewable energies: primary energy consumption, power generation, energy supply, avoidance of greenhouse gases; (b) Solid fuels: energetic utilization, wood pellets, energy consumption, comparison to heating oil; (c) Biofuels: consumption, bioethanol, biodiesel, vegetable oils; (d) Biogas: biogas power plants, energy content, production, legal aspects.

Strategic niche management for biofuels : analysing past experiments for developing new biofuels policy

NARCIS (Netherlands)

Laak, W.W.M.; Raven, R.P.J.M.; Verbong, G.P.J.

2007-01-01

Biofuels have gained a lot of attention since the implementation of the 2003 European Directive on biofuels. In the Netherlands the contribution of biofuels is still very limited despite several experiments in the past. This article aims to contribute to the development of successful policies for

Biofuel technology handbook. 2. ed.

Energy Technology Data Exchange (ETDEWEB)

Rutz, Dominik; Janssen, Rainer

2008-01-15

This comprehensive handbook was created in order to promote the production and use of biofuels and to inform politicians, decision makers, biofuel traders and all other relevant stakeholders about the state-of-the-art of biofuels and relevant technologies. The large variety of feedstock types and different conversion technologies are described. Explanations about the most promising bio fuels provide a basis to discuss about the manifold issues of biofuels. The impartial information in this handbook further contributes to diminish existing barriers for the broad use of biofuels. Emphasis of this handbook is on first generation biofuels: bio ethanol, Biodiesel, pure plant oil, and bio methane. It also includes second generation biofuels such as BTL-fuels and bio ethanol from lingo-cellulose as well as bio hydrogen. The whole life cycle of bio fuels is assessed under technical, economical, ecological, and social aspect. Characteristics and applications of bio fuels for transport purposes are demonstrated and evaluated. This is completed by an assessment about the most recent studies on biofuel energy balances. This handbook describes the current discussion about green house gas (GHG) balances and sustainability aspects. GHG calculation methods are presented and potential impacts of biofuel production characterized: deforestation of rainforests and wetlands, loss of biodiversity, water pollution, human health, child labour, and labour conditions.

Hydrodeoxygenation of aliphatic and aromatic oxygenates on sulphided catalysts for production of second generation biofuels

Energy Technology Data Exchange (ETDEWEB)

Senol, O.I.

2007-07-01

Environmental concerns and diminishing petroleum reserves have increased the importance of biofuels for traffic fuel applications. Second generation biofuels produced from wood, vegetable oils and animal fats have been considered promising for delivering biofuels in large amount with low production cost. The abundance of oxygen in the form of various aliphatic and aromatic oxygenates decreases the quality of biofuels, however, and therefore the oxygen content of biofuels must be reduced. Upgrading of biofuels can be achieved by hydrodeoxygenation (HDO), which is similar to hydrodesulphurisation in oil refining. In HDO, oxygen-containing compounds are converted to hydrocarbons by eliminating oxygen in the form of water in the presence of hydrogen and a sulphided catalyst. Due to the low sulphur content of biofuels, a sulphiding agent is typically added to the HDO feed to maintain activity and stability of the catalyst. The aim of this work was to investigate HDO using aliphatic and aromatic oxygenates as model compounds on sulphided NiMo/gamma-Al{sub 2}O3 and CoMo/gamma-Al{sub 2}O3 catalysts. The effects of side product, water, and of sulphiding agents, H{sub 2}S and CS{sub 2}, on HDO were determined. The primary focus was on the HDO of aliphatic oxygenates, because a reasonable amount of data regarding the HDO of aromatic oxygenates already exists. The HDO of aliphatic esters produced hydrocarbons from intermediate alcohol, carboxylic acid, aldehyde and ether compounds. A few sulphur-containing compounds were also detected in trace amounts, and their formation caused desulphurisation of the catalysts. Hydrogenation reactions and acid-catalysed reactions (dehydration, hydrolysis, esterification, E{sub 2} elimination and SN{sub 2} nucleophilic substitution) played a major role in the HDO of aliphatic oxygenates. The NiMo catalyst showed a higher activity for HDO and hydrogenation reactions than the CoMo catalyst, but both catalysts became deactivated because of

Biofuels: 1995 project summaries

Energy Technology Data Exchange (ETDEWEB)

NONE

1996-01-01

Domestic transportation fuels are derived primarily from petroleum and account for about two-thirds of the petroleum consumption in the United States. In 1994, more than 40% of our petroleum was imported. That percentage is likely to increase, as the Middle East has about 75% of the world`s oil reserves, but the United States has only about 5%. Because we rely so heavily on oil (and because we currently have no suitable substitutes for petroleum-based transportation fuels), we are strategically and economically vulnerable to disruptions in the fuel supply. Additionally, we must consider the effects of petroleum use on the environment. The Biofuels Systems Division (BSD) is part of the U.S. Department of Energy (DOE) Office of Energy Efficiency and Renewable Energy (EE). The day-to-day research activities, which address these issues, are managed by the National Renewable Energy Laboratory in Golden, Colorado, and Oak Ridge National Laboratory in Oak Ridge, Tennessee. BSD focuses its research on biofuels-liquid and gaseous fuels made from renewable domestic crops-and aggressively pursues new methods for domestically producing, recovering, and converting the feedstocks to produce the fuels economically. The biomass resources include forage grasses, oil seeds, short-rotation woody crops, agricultural and forestry residues, algae, and certain industrial and municipal waste streams. The resulting fuels include ethanol, methanol, biodiesel, and ethers.

The price for biofuels sustainability

International Nuclear Information System (INIS)

Pacini, Henrique; Assunção, Lucas; Dam, Jinke van; Toneto, Rudinei

2013-01-01

The production and usage of biofuels has increased worldwide, seeking goals of energy security, low-carbon energy and rural development. As biofuels trade increased, the European Union introduced sustainability regulations in an attempt to reduce the risks associated with biofuels. Producers were then confronted with costs of sustainability certification, in order to access the EU market. Hopes were that sustainably-produced biofuels would be rewarded with higher prices in the EU. Based on a review of recent literature, interviews with traders and price data from Platts, this paper explores whether sustainability premiums emerged and if so, did they represent an attracting feature in the market for sustainable biofuels. This article finds that premiums for ethanol and biodiesel evolved differently between 2011 and 2012, but have been in general very small or inexistent, with certified fuels becoming the new norm in the market. For different reasons, there has been an apparent convergence between biofuel policies in the EU and the US. As market operators perceive a long-term trend for full certification in the biofuels market, producers in developing countries are likely to face additional challenges in terms of finance and capacity to cope with the sustainability requirements. - Highlights: • EU biofuel sustainability rules were once thought to reward compliant producers with price-premiums. • Premiums for certified biofuels, however, have been small for biodiesel and almost non-existent for ethanol. • As sustainable biofuels became the new norm, premiums disappeared almost completely in 2012. • Early stages of supply chains concentrate the highest compliance costs, affecting specially developing country producers. • Producers are now in a market where sustainable biofuels have become the new norm

Natural Gas and Cellulosic Biomass: A Clean Fuel Combination? Determining the Natural Gas Blending Wall in Biofuel Production.

Science.gov (United States)

M Wright, Mark; Seifkar, Navid; Green, William H; Román-Leshkov, Yuriy

2015-07-07

Natural gas has the potential to increase the biofuel production output by combining gas- and biomass-to-liquids (GBTL) processes followed by naphtha and diesel fuel synthesis via Fischer-Tropsch (FT). This study reflects on the use of commercial-ready configurations of GBTL technologies and the environmental impact of enhancing biofuels with natural gas. The autothermal and steam-methane reforming processes for natural gas conversion and the gasification of biomass for FT fuel synthesis are modeled to estimate system well-to-wheel emissions and compare them to limits established by U.S. renewable fuel mandates. We show that natural gas can enhance FT biofuel production by reducing the need for water-gas shift (WGS) of biomass-derived syngas to achieve appropriate H2/CO ratios. Specifically, fuel yields are increased from less than 60 gallons per ton to over 100 gallons per ton with increasing natural gas input. However, GBTL facilities would need to limit natural gas use to less than 19.1% on a LHV energy basis (7.83 wt %) to avoid exceeding the emissions limits established by the Renewable Fuels Standard (RFS2) for clean, advanced biofuels. This effectively constitutes a blending limit that constrains the use of natural gas for enhancing the biomass-to-liquids (BTL) process.

International bioenergy trade - a review of past developments in the liquid biofuels market

NARCIS (Netherlands)

Lamers, P.; Hamelinck, C.N.; Junginger, H.M.|info:eu-repo/dai/nl/202130703; Faaij, A.P.C.|info:eu-repo/dai/nl/10685903X

2011-01-01

Policies aimed to promote biofuels locally had tremendous effects on global market developments across the past decade. This article develops insights into the interaction of these policies and market forces via a comprehensive collection and analysis of international production and trade data. It

Optimal production scheduling for energy efficiency improvement in biofuel feedstock preprocessing considering work-in-process particle separation

International Nuclear Information System (INIS)

Li, Lin; Sun, Zeyi; Yao, Xufeng; Wang, Donghai

2016-01-01

Biofuel is considered a promising alternative to traditional liquid transportation fuels. The large-scale substitution of biofuel can greatly enhance global energy security and mitigate greenhouse gas emissions. One major concern of the broad adoption of biofuel is the intensive energy consumption in biofuel manufacturing. This paper focuses on the energy efficiency improvement of biofuel feedstock preprocessing, a major process of cellulosic biofuel manufacturing. An improved scheme of the feedstock preprocessing considering work-in-process particle separation is introduced to reduce energy waste and improve energy efficiency. A scheduling model based on the improved scheme is also developed to identify an optimal production schedule that can minimize the energy consumption of the feedstock preprocessing under production target constraint. A numerical case study is used to illustrate the effectiveness of the proposed method. The research outcome is expected to improve the energy efficiency and enhance the environmental sustainability of biomass feedstock preprocessing. - Highlights: • A novel method to schedule production in biofuel feedstock preprocessing process. • Systems modeling approach is used. • Capable of optimize preprocessing to reduce energy waste and improve energy efficiency. • A numerical case is used to illustrate the effectiveness of the method. • Energy consumption per unit production can be significantly reduced.

Global biofuel use, 1850-2000

Science.gov (United States)

Fernandes, Suneeta D.; Trautmann, Nina M.; Streets, David G.; Roden, Christoph A.; Bond, Tami C.

2007-06-01

This paper presents annual, country-level estimates of biofuel use for the period 1850-2000. We estimate that global biofuel consumption rose from about 1000 Tg in 1850 to 2460 Tg in 2000, an increase of 140%. In the late 19th century, biofuel consumption in North America was very high, ˜220-250 Tg/yr, because widespread land clearing supplied plentiful fuelwood. At that time biofuel use in Western Europe was lower, ˜180-200 Tg/yr. As fossil fuels became available, biofuel use in the developed world fell. Compensating changes in other parts of the world, however, caused global consumption to remain remarkably stable between 1850 and 1950 at ˜1200 ± 200 Tg/yr. It was only after World War II that biofuel use began to increase more rapidly in response to population growth in the developing world. Between 1950 and 2000, biofuel use in Africa, South Asia, and Southeast Asia grew by 170%, 160%, and 130%, respectively.

Glucose-based Biofuel Cells: Nanotechnology as a Vital Science in Biofuel Cells Performance

Directory of Open Access Journals (Sweden)

Hamideh Aghahosseini

2016-07-01

Full Text Available Nanotechnology has opened up new opportunities for the design of nanoscale electronic devices suitable for developing high-performance biofuel cells. Glucose-based biofuel cells as green energy sources can be a powerful tool in the service of small-scale power source technology as it provides a latent potential to supply power for various implantable medical electronic devices. By using physiologically produced glucose as a fuel, the living battery can recharge for continuous production of electricity. This review article presents how nanoscience, engineering and medicine are combined to assist in the development of renewable glucose-based biofuel cell systems. Here, we review recent advances and applications in both abiotic and enzymatic glucose biofuel cells with emphasis on their “implantable” and “implanted” types. Also the challenges facing the design and application of glucose-based biofuel cells to convert them to promising replacement candidates for non-rechargeable lithium-ion batteries are discussed. Nanotechnology could make glucose-based biofuel cells cheaper, lighter and more efficient and hence it can be a part of the solutions to these challenges.

Technology Roadmaps: Biofuels for Transport

Energy Technology Data Exchange (ETDEWEB)

NONE

2011-07-01

Biofuels could provide up to 27% of total transport fuel worldwide by 2050. The use of transport fuels from biomass, when produced sustainably, can help cut petroleum use and reduce CO2 emissions in the transport sector, especially in heavy transport. Sustainable biofuel technologies, in particular advanced biofuels, will play an important role in achieving this roadmap vision. The roadmap describes the steps necessary to realise this ambitious biofuels target; identifies key actions by different stakeholders, and the role for government policy to adopt measures needed to ensure the sustainable expansion of both conventional and advanced biofuel production.

Microbial advanced biofuels production: overcoming emulsification challenges for large-scale operation.

Science.gov (United States)

Heeres, Arjan S; Picone, Carolina S F; van der Wielen, Luuk A M; Cunha, Rosiane L; Cuellar, Maria C

2014-04-01

Isoprenoids and alkanes produced and secreted by microorganisms are emerging as an alternative biofuel for diesel and jet fuel replacements. In a similar way as for other bioprocesses comprising an organic liquid phase, the presence of microorganisms, medium composition, and process conditions may result in emulsion formation during fermentation, hindering product recovery. At the same time, a low-cost production process overcoming this challenge is required to make these advanced biofuels a feasible alternative. We review the main mechanisms and causes of emulsion formation during fermentation, because a better understanding on the microscale can give insights into how to improve large-scale processes and the process technology options that can address these challenges. Copyright © 2014 Elsevier Ltd. All rights reserved.

Tracking U.S. biofuel innovation through patents

International Nuclear Information System (INIS)

Kessler, Jeff; Sperling, Daniel

2016-01-01

We use biofuel patents as a proxy for biofuel innovation. Through use of natural language processing and machine-learning algorithms, we expand patent classification capabilities to better explain the history of biofuels innovation. Results indicate that after the initial establishment of the U.S. biofuel industry, there were two surges in biofuel innovation: 1995–2000, characterized by heavy patenting by 1st generation (food-based) biofuel firms; and 2005–2010, characterized by a second surge of innovation by those same large firms, complemented by a large number of biotechnology firms producing a relatively small number of 2nd generation biofuel patents. Our analysis corroborates the widespread understanding that the first surge in biofuel innovation was linked to innovations in agriculture, and that the second surge of biofuel innovation was driven by demand-pull policies mandating and incentivizing biofuels. But the slow emergence of a 2nd generation cellulose-based biofuels industry, far slower than called for by policy, suggests that technology-push policies more focused on R&D and investment may be needed to accelerate the commercialization of 2nd generation biofuels. - Highlights: • Patenting activity closely corresponds to sociotechnical shifts in biofuel innovation. • The Renewable Fuel Standard likely contributed to the rise in biofuel patenting activity after 2005. • 2nd generation biofuel technology innovation appears lacking compared to 1st generation technologies.

An Investigation of Viscosities, Calorific Values and Densities of Binary Biofuel Blends

Directory of Open Access Journals (Sweden)

Che Mat Sharzali

2017-01-01

Full Text Available Straight vegetable oil (SVO biofuel is a promising alternative to petroleum diesel fuel primarily due to its comparable physical properties to that of petroleum diesel fuel. However, the relatively higher viscosity of SVO limits its direct application in diesel engine. To resolve this issue, binary biofuel blends was introduced in this study to reduce the viscosity of SVO. In this work, a novel biofuel namely Melaleuca Cajuputi oil (MCO was used and blended with refined palm oil (RPO. A total of four blends with the mixing ratios of 20%, 40%, 50% and 60% of MCO were prepared. Various key properties of dynamic viscosity, calorific value and density of the blends were measured and benchmarked against the biodiesel standards based on ASTM D6751. It was found that viscosity and density of the blends decreased with the increase of MCO fraction. Meanwhile, the calorific value of the blends increased linearly as the MCO fraction increased. The blend of 40RPO60MCO was found to have comparable key properties of viscosity, calorific value and density to those of petroleum diesel fuel and ASTM D6751 standard.

Determination of the physical characteristics of vegetable oils

Energy Technology Data Exchange (ETDEWEB)

Andrade, Danielle Oliveira de; Andrade, Ednilton Tavares de; Pereira, Roberto Guimaraes [Universidade Federal Fluminense (TER/UFF), Niteroi, RJ (Brazil). Dept. de Engenharia Agricola e do Meio Ambiente; Tulcan, Oscar Edwin Piamba [Universidade Nacional da Colombia (UNAL), Bogota (Colombia). Fac de Ingenieria

2008-07-01

The objective of this work was the characterization of vegetable oils of canola, sunflower, corn and soybean through corrosion, kinematic viscosity, density, cloud point and flow point tests. Vegetable oils are used as raw material for preparation of biofuels or as fuel diesel additive or substitute. The vegetable oils tested showed a low level of corrosion, kinematic viscosities are measured in the range of 31 to 36 mm{sup 2}.s{sup -1}, density was tested at 15 and 20 deg C and showed results varying in the third decimal order. For the oils tested, the cloud point is around 0 deg C and the flow point around -17 deg C. (author)

Investigating biofuels through network analysis

International Nuclear Information System (INIS)

Curci, Ylenia; Mongeau Ospina, Christian A.

2016-01-01

Biofuel policies are motivated by a plethora of political concerns related to energy security, environmental damages, and support of the agricultural sector. In response to this, much scientific work has chiefly focussed on analysing the biofuel domain and on giving policy advice and recommendations. Although innovation has been acknowledged as one of the key factors in sustainable and cost-effective biofuel development, there is an urgent need to investigate technological trajectories in the biofuel sector by starting from consistent data and appropriate methodological tools. To do so, this work proposes a procedure to select patent data unequivocally related to the investigated sector, it uses co-occurrence of technological terms to compute patent similarity and highlights content and interdependencies of biofuels technological trajectories by revealing hidden topics from unstructured patent text fields. The analysis suggests that there is a breaking trend towards modern generation biofuels and that innovators seem to focus increasingly on the ability of alternative energy sources to adapt to the transport/industrial sector. - Highlights: • Innovative effort is devoted to biofuels additives and modern biofuels technologies. • A breaking trend can be observed from the second half of the last decade. • A patent network is identified via text mining techniques that extract latent topics.

Chlamydomonas as a model for biofuels and bio-products production.

Science.gov (United States)

Scranton, Melissa A; Ostrand, Joseph T; Fields, Francis J; Mayfield, Stephen P

2015-05-01

Developing renewable energy sources is critical to maintaining the economic growth of the planet while protecting the environment. First generation biofuels focused on food crops like corn and sugarcane for ethanol production, and soybean and palm for biodiesel production. Second generation biofuels based on cellulosic ethanol produced from terrestrial plants, has received extensive funding and recently pilot facilities have been commissioned, but to date output of fuels from these sources has fallen well short of what is needed. Recent research and pilot demonstrations have highlighted the potential of algae as one of the most promising sources of sustainable liquid transportation fuels. Algae have also been established as unique biofactories for industrial, therapeutic, and nutraceutical co-products. Chlamydomonas reinhardtii's long established role in the field of basic research in green algae has paved the way for understanding algal metabolism and developing genetic engineering protocols. These tools are now being utilized in C. reinhardtii and in other algal species for the development of strains to maximize biofuels and bio-products yields from the lab to the field. © 2015 The Authors The Plant Journal © 2015 John Wiley & Sons Ltd.

European biofuel policies in retrospect

International Nuclear Information System (INIS)

Van Thuijl, E.; Deurwaarder, E.P.

2006-05-01

Despite the benefits of the production and use of biofuels in the fields of agriculture, security of energy supply and the environment, in India and surrounding countries, the barriers to the use of biofuels are still substantial. The project ProBios (Promotion of Biofuels for Sustainable Development in South and South East Asia) aims at promoting biofuels in the view of sustainable development in the Southern and South eastern Asian countries. The first stage of this project concerns a study, which will provide a thorough review of the complicated and sector-overarching issue of biofuels in India and surrounding countries. This report describes past experiences with the policy context for a selection of EU countries, with the purpose of identifying conclusions from the European experience that may be valuable for Indian and South East Asian policy makers and other biofuels stakeholders

Land Use Change under Biofuel Policies and a Tax on Meat and Dairy Products: Considering Complexity in Agricultural Production Chains Matters

Directory of Open Access Journals (Sweden)

Ruth Delzeit

2018-02-01

Full Text Available Growing demand for meat and dairy products (MDP, biofuels, and scarcity of agricultural land are drivers of global land use competition. Impacts of policies targeting demand for MDP or biofuels have only been analysed separately. We use the computable general equilibrium model DART-BIO to investigate combined effects, since MDP and biofuel production are closely related via feestock use and co-production of animal feed. We implement four scenarios: (a a baseline scenario; (b halving MDP consumption in industrialised countries by a tax; (c abolishing current biofuel policies; and (d no exogenous land use change. We find that a MDP tax and exogenous land use change have larger effects on land use and food markets than biofuel policies. International trade is affected in all scenarios. With respect to combined effects of a MDP tax and biofuel policies, we find decreasing biodiesel but increasing bioethanol production. In addition, the MDP tax decreases the impact of biofuel policies on agricultural markets and land use. Our results highlight the importance of a detailed representation of different vegetable oils used in biodiesel production and related by-products. Finally, since the MDP tax increases the use of fossil fuels, the net climate mitigation potentials of such a tax should be investigated further.

An integrated renewable energy park approach for algal biofuel production in United States

International Nuclear Information System (INIS)

Subhadra, Bobban; Edwards, Mark

2010-01-01

Algal biomass provides viable third generation feedstock for liquid transportation fuel that does not compete with food crops for cropland. However, fossil energy inputs and intensive water usage diminishes the positive aspects of algal energy production. An integrated renewable energy park (IREP) approach is proposed for aligning renewable energy industries in resource-specific regions in United States for synergistic electricity and liquid biofuel production from algal biomass with net zero carbon emissions. The benefits, challenges and policy needs of this approach are discussed.

A modelling approach to estimate the European biofuel production: from crops to biofuels

Energy Technology Data Exchange (ETDEWEB)

Clodic, Melissa [Institute National de la Recherche Agronomique (IFP/INRA), Paris (France). Instituto Frances do Petroleo

2008-07-01

Today, in the context of energy competition and climate change, biofuels are promoted as a renewable resource to diversify the energy supply. However, biofuel development remains controversial. Here, we will present a way to make an environmental and economic cost and benefit analysis of European biofuels, from the crops until the marketed products, by using a linear programming optimization modelling approach. To make this European biofuel production model, named AGRAF, possible, we decided to use different independent linear programming optimization models which represent the separate parts of the process: European agricultural production, production of transforming industries and refinery production. To model the agricultural and the refining sections, we have chosen to improve existing and experimented models by adding a biofuel production part. For the transforming industry, we will create a new partial equilibrium model which will represent stake holders such as Sofiproteol, Stereos, etc. Data will then be exchanged between the models to coordinate all the biofuel production steps. Here, we will also focus on spatialization in order to meet certain of our requirements, such as the exchange flux analysis or the determination of transport costs, usually important in an industrial optimization model. (author)

Oil price, biofuels and food supply

International Nuclear Information System (INIS)

Timilsina, Govinda R.; Mevel, Simon; Shrestha, Ashish

2011-01-01

The price of oil could play a significant role in influencing the expansion of biofuels, but this issue has yet to be fully investigated in the literature. Using a global computable general equilibrium (CGE) model, this study analyzes the impact of oil price on biofuel expansion, and subsequently, on food supply. The study shows that a 65% increase in oil price in 2020 from the 2009 level would increase the global biofuel penetration to 5.4% in 2020 from 2.4% in 2009. If oil prices rise 150% from their 2009 levels by 2020, the resulting penetration of biofuels would be 9%, which is higher than that would be caused by current mandates and targets introduced in more than forty countries around the world. The study also shows that aggregate agricultural output drops due to an oil price increase, but the drop is small in major biofuel producing countries as the expansion of biofuels would partially offset the negative impacts of the oil price increase on agricultural outputs. An increase in oil price would reduce global food supply through direct impacts as well as through the diversion of food commodities and cropland towards the production of biofuels. - Highlights: ► A global CGE model to analyze impacts of oil price on biofuels and food supply. ► Global biofuel penetration increases from 2.4% (2009) to 5.4% (2020) in baseline. ► A 150% rise of oil price boosts biofuels more than current mandates and targets do. ► Biofuels partially offset drops in agricultural outputs caused by oil price rise. ► Biofuels as well as oil price rise negatively affect global food supply.

Finding the food-fuel balance. Supply and demand dynamics in global vegetable oil markets

Energy Technology Data Exchange (ETDEWEB)

Savanti, P.

2012-10-15

Demand for vegetable oils for food and biofuel use is expected to increase by an additional 23 million tonnes by 2016; however supply is expected to struggle to keep up with this demand, according to this Rabobank report. Vegetable oil stocks have reached a 38 year low this year due in large part to constraints such as land availability and adverse weather.

Liquid biofuel production from volatile fatty acids

Energy Technology Data Exchange (ETDEWEB)

Steinbusch, K.J.J.

2010-03-19

The production of renewable fuels and chemicals reduces the dependency on fossil fuels and limits the increase of CO2 concentration in the atmosphere only if a sustainable feedstock and an energy efficient process are used. The thesis assesses the possibility to use municipal and industrial waste as biomass feedstock to have little of no competition with food production, and to save greenhouse gasses emissions. Waste is a complex substrate with a diverse composition and high water content. It can be homogenized without losing its initial energy value by anaerobic conversion to volatile fatty acids (VFA). Using VFA gives the opportunity to process cheap and abundantly present biomass residues to a fuel and chemical instead of sugar containing crops or vegetable oil. This thesis describes the feasibility to convert VFA to compounds with a higher energy content using mixed culture fermentations by eliminating of oxygen and/or increasing the carbon and hydrogen content. At high hydrogen pressure, protons and electrons release via the reduction of organic products such as VFA becomes thermodynamically more attractive. Three VFA reduction reactions were studied: hydrogenation to an alcohol with (1) hydrogen and (2) an electrode as electron donor, and (3) by chain elongation with hydrogen and ethanol. Based on concentration, production rate and efficiency, elongation of acetate with hydrogen and/or ethanol was the best technique to convert VFA into a fuel. In a CSTR (Continuous-flow stirred-tank reactor), 10.5 g L{sup -1} caproic acid and 0.48 g L{sup -1} caprylic acid were produced with ethanol and/or hydrogen at a specific MCFA (medium-chain fatty acids) production activity of 2.9 g caproate and 0.09 g caprylate per gram VSS d{sup -1} (volatile suspended solids). The products were selectively removed by calcium precipitation and solvent extraction with ethyl hexanoate and petroleum ether. Microbial characterization revealed that the microbial populations were stable and

Recent advances on the production and utilization trends of bio-fuels: A global perspective

International Nuclear Information System (INIS)

Demirbas, M.F.; Balat, Mustafa

2006-01-01

Bio-fuels are important because they replace petroleum fuels. There are many benefits for the environment, economy and consumers in using bio-fuels. Bio-oil can be used as a substitute for fossil fuels to generate heat, power and/or chemicals. Upgrading of bio-oil to a transportation fuel is technically feasible, but needs further development. Bio-fuels are made from biomass through thermochemical processes such as pyrolysis, gasification, liquefaction and supercritical fluid extraction or biochemical. Biochemical conversion of biomass is completed through alcoholic fermentation to produce liquid fuels and anaerobic digestion or fermentation, resulting in biogas. In wood derived pyrolysis oil, specific oxygenated compounds are present in relatively large amounts. Basically, the recovery of pure compounds from the complex bio-oil is technically feasible but probably economically unattractive because of the high costs for recovery of the chemical and its low concentration in the oil

Genetic Resources for Advanced Biofuel Production Described with the Gene Ontology

Directory of Open Access Journals (Sweden)

Trudy eTorto-Alalibo

2014-10-01

Full Text Available Dramatic increases in research in the area of microbial biofuel production coupled with high-throughput data generation on bioenergy-related microbes has led to a deluge of information in the scientific literature and in databases. Consolidating this information and making it easily accessible requires a unified vocabulary. The Gene Ontology (GO fulfills that requirement, as it is a well-developed structured vocabulary that describes the activities and locations of gene products in a consistent manner across all kingdoms of life. The Microbial Energy Gene Ontology (MENGO: http://www.mengo.biochem.vt.edu project is extending the GO to include new terms to describe microbial processes of interest to bioenergy production. Our effort has added over 600 bioenergy related terms to the Gene Ontology. These terms will aid in the comprehensive annotation of gene products from diverse energy-related microbial genomes. An area of microbial energy research that has received a lot of attention is microbial production of advanced biofuels. These include alcohols such as butanol, isopropanol, isobutanol, and fuels derived from fatty acids, isoprenoids, and polyhydroxyalkanoates. These fuels are superior to first generation biofuels (ethanol and biodiesel esterified from vegetable oil or animal fat, can be generated from non-food feedstock sources, can be used as supplements or substitutes for gasoline, diesel and jet fuels, and can be stored and distributed using existing infrastructure. Here we review the roles of genes associated with synthesis of advanced biofuels, and at the same time introduce the use of the GO to describe the functions of these genes in a standardized way.

From first generation biofuels to advanced solar biofuels.

Science.gov (United States)

Aro, Eva-Mari

2016-01-01

Roadmaps towards sustainable bioeconomy, including the production of biofuels, in many EU countries mostly rely on biomass use. However, although biomass is renewable, the efficiency of biomass production is too low to be able to fully replace the fossil fuels. The use of land for fuel production also introduces ethical problems in increasing the food price. Harvesting solar energy by the photosynthetic machinery of plants and autotrophic microorganisms is the basis for all biomass production. This paper describes current challenges and possibilities to sustainably increase the biomass production and highlights future technologies to further enhance biofuel production directly from sunlight. The biggest scientific breakthroughs are expected to rely on a new technology called "synthetic biology", which makes engineering of biological systems possible. It will enable direct conversion of solar energy to a fuel from inexhaustible raw materials: sun light, water and CO2. In the future, such solar biofuels are expected to be produced in engineered photosynthetic microorganisms or in completely synthetic living factories.

Near-zero emissions combustor system for syngas and biofuels

International Nuclear Information System (INIS)

Yongho, Kim; Rosocha, Louis

2010-01-01

research necessary to develop a novel, high-efficiency, low-emissions (near-zero, or as low as reasonably achievable), advanced combustion technology for electricity and heat production from biofuels and fuels derived from MSW. For any type of combustion technology, including the advanced technology of this project, two problems of special interest must be addressed: developing and optimizing the combustion chambers and the systems for igniting and sustaining the fuel-burning process. For MSW in particular, there are new challenges over gaseous or liquid fuels because solid fuels must be ground into fine particulates (∼ 10 (micro)m diameter), fed into the advanced combustor, and combusted under plasma-assisted conditions that are quite different than gaseous or liquid fuels. The principal idea of the combustion chamber design is to use so-called reverse vortex gas flow, which allows efficient cooling of the chamber wall and flame stabilization in the central area of the combustor (Tornado chamber). Considerable progress has been made in design ing an advanced, reverse vortex flow combustion chamber for biofuels, although it was not tested on biofuels and a system that could be fully commercialized has never been completed.

Flambeau River Biofuels Demonstration Plant

Energy Technology Data Exchange (ETDEWEB)

Byrne, Robert J. [Flambeau River Biofuels, Inc., Park Falls, WI (United States)

2012-07-30

Flambeau River BioFuels, Inc. (FRB) proposed to construct a demonstration biomass-to-liquids (BTL) biorefinery in Park Falls, Wisconsin. The biorefinery was to be co-located at the existing pulp and paper mill, Flambeau River Papers, and when in full operation would both generate renewable energy – making Flambeau River Papers the first pulp and paper mill in North America to be nearly fossil fuel free – and produce liquid fuels from abundant and renewable lignocellulosic biomass. The biorefinery would serve to validate the thermochemical pathway and economic models for BTL production using forest residuals and wood waste, providing a basis for proliferating BTL conversion technologies throughout the United States. It was a project goal to create a compelling new business model for the pulp and paper industry, and support the nation’s goal for increasing renewable fuels production and reducing its dependence on foreign oil. FRB planned to replicate this facility at other paper mills after this first demonstration scale plant was operational and had proven technical and economic feasibility.

An integrated renewable energy park approach for algal biofuel production in United States

Energy Technology Data Exchange (ETDEWEB)

Subhadra, Bobban [Department of Internal Medicine, School of Medicine, University of New Mexico, Albuquerque, NM 87131 (United States); Edwards, Mark [Marketing and Sustainability, W.P. Carey School of Business, Arizona State University, Tempe, AZ 85282 (United States)

2010-09-15

Algal biomass provides viable third generation feedstock for liquid transportation fuel that does not compete with food crops for cropland. However, fossil energy inputs and intensive water usage diminishes the positive aspects of algal energy production. An integrated renewable energy park (IREP) approach is proposed for aligning renewable energy industries in resource-specific regions in United States for synergistic electricity and liquid biofuel production from algal biomass with net zero carbon emissions. The benefits, challenges and policy needs of this approach are discussed. (author)

Estimates of US biofuels consumption, 1990

International Nuclear Information System (INIS)

1991-10-01

This report is the sixth in the series of publications developed by the Energy Information Administration to quantify the amount of biofuel-derived primary energy used by the US economy. It provides preliminary estimates of 1990 US biofuels energy consumption by sector and by biofuels energy resource type. The objective of this report is to provide updated annual estimates of biofuels energy consumption for use by congress, federal and state agencies, and other groups involved in activities related to the use of biofuels. 5 figs., 10 tabs

Estimates of US biofuels consumption, 1990

Energy Technology Data Exchange (ETDEWEB)

1991-10-01

This report is the sixth in the series of publications developed by the Energy Information Administration to quantify the amount of biofuel-derived primary energy used by the US economy. It provides preliminary estimates of 1990 US biofuels energy consumption by sector and by biofuels energy resource type. The objective of this report is to provide updated annual estimates of biofuels energy consumption for use by congress, federal and state agencies, and other groups involved in activities related to the use of biofuels. 5 figs., 10 tabs.

[Determination of gossypol in edible vegetable oil with high performance liquid chromatography-tandem mass spectrometry].

Science.gov (United States)

Zhang, Wenhua; Huang, Chaoqun; Xie, Wen; Shen, Li

2014-06-01

A liquid chromatography-tandem mass spectrometry (LC-MS/MS) method was developed for the determination of gossypol in edible vegetable oil. The sample was extracted with ethyl alcohol by vortex-excited oscillation. The extract was cleaned up by 0.22 microm filter membrane and centrifuged for 5 min at 4 000 r/min after standing in a fridge at 4 degrees C for 30 min. The compound was separated on a C18 column (100 mm x 2.1 mm, 3.5 microm) with acetonitrile and 1% (v/v) formic acid aqueous solution as mobile phase. The detection of gossypol was carried out by LC-MS/MS with positive electrospray ionization under multiple reaction monitoring (MRM) mode using external standard method. The limits of quantification (S/N > 10) of gossypol in edible vegetable oil was 1 mg/kg. The recoveries were from 87.4% to 100% at the spiked levels of 1, 2, 200 mg/kg of gossypol in edible vegetable oil with the relative standard deviations (RSDs) between 3.9% and 12.2%. The method, with high sensitivity, good precision and high recovery, was suitable for the confirmation and quantification of gossypol residue in edible vegetable oil.

Study of by-products of agro-food industries which could be used for bio-fuel production (animal fat, used food oils, and wine production by-products). Synthesis of the final report

International Nuclear Information System (INIS)

Gomy, Catherine; Thonier, Gregoire; Gagnepain, Bruno; Mhiri, Tarek

2015-04-01

As the Renewable Energy directive proposes the implementation of incentive arrangements for the production of bio-fuels from biomass, this report proposes a synthesis of a study which addressed three by-products of agro-food industry and of catering (collective, traditional, fast) which can help to reach objectives of energy production from biomass: used food oils, rendered animal fat of category 1 and 2, and vinification by-products (grape marc, lees, sludge). The objectives were to quantify, at the French national and regional levels, present resources and uses for these three by-products, non-valorised volumes and thus potentially available volumes for the production of liquid bio-fuels, to identify present actors and their interactions, and to study the potential of local production of liquid bio-fuels. The study comprised a comprehensive analysis of production and valorisation sectors for the three addressed types of by-products, and an identification of recent experiments implemented for the production of liquid bio-fuels. This synthesis states the lessons learned from the study of these three different sectors, and proposes recommendations for further developments

The Danish Biofuel Debate

DEFF Research Database (Denmark)

Hansen, Janus

2014-01-01

of biofuels enrol scientific authority to support their positions? The sociological theory of functional differentiation combined with the concept of advocacy coalition can help in exploring this relationship between scientific claims-making and the policy stance of different actors in public debates about...... biofuels. In Denmark two distinct scientific perspectives about biofuels map onto the policy debates through articulation by two competing advocacy coalitions. One is a reductionist biorefinery perspective originating in biochemistry and neighbouring disciplines. This perspective works upwards from...

Outlook for advanced biofuels

International Nuclear Information System (INIS)

Hamelinck, Carlo N; Faaij, Andre P.C.

2006-01-01

To assess which biofuels have the better potential for the short-term or the longer term (2030), and what developments are necessary to improve the performance of biofuels, the production of four promising biofuels-methanol, ethanol, hydrogen, and synthetic diesel-is systematically analysed. This present paper summarises, normalises and compares earlier reported work. First, the key technologies for the production of these fuels, such as gasification, gas processing, synthesis, hydrolysis, and fermentation, and their improvement options are studied and modelled. Then, the production facility's technological and economic performance is analysed, applying variations in technology and scale. Finally, likely biofuels chains (including distribution to cars, and end-use) are compared on an equal economic basis, such as costs per kilometre driven. Production costs of these fuels range 16-22 Euro /GJ HHV now, down to 9-13 Euro /GJ HHV in future (2030). This performance assumes both certain technological developments as well as the availability of biomass at 3 Euro /GJ HHV . The feedstock costs strongly influence the resulting biofuel costs by 2-3 Euro /GJ fuel for each Euro /GJ HHV feedstock difference. In biomass producing regions such as Latin America or the former USSR, the four fuels could be produced at 7-11 Euro /GJ HHV compared to diesel and gasoline costs of 7 and 8 Euro /GJ (excluding distribution, excise and VAT; at crude oil prices of ∼35 Euro /bbl or 5.7 Euro /GJ). The uncertainties in the biofuels production costs of the four selected biofuels are 15-30%. When applied in cars, biofuels have driving costs in ICEVs of about 0.18-0.24 Euro /km now (fuel excise duty and VAT excluded) and may be about 0.18 in future. The cars' contribution to these costs is much larger than the fuels' contribution. Large-scale gasification, thorough gas cleaning, and micro-biological processes for hydrolysis and fermentation are key major fields for RD and D efforts, next to

Biofuel supply chain, market, and policy analysis

Science.gov (United States)

Zhang, Leilei

Renewable fuel is receiving an increasing attention as a substitute for fossil based energy. The US Department of Energy (DOE) has employed increasing effort on promoting the advanced biofuel productions. Although the advanced biofuel remains at its early stage, it is expected to play an important role in climate policy in the future in the transportation sector. This dissertation studies the emerging biofuel supply chain and markets by analyzing the production cost, and the outcomes of the biofuel market, including blended fuel market price and quantity, biofuel contract price and quantity, profitability of each stakeholder (farmers, biofuel producers, biofuel blenders) in the market. I also address government policy impacts on the emerging biofuel market. The dissertation is composed with three parts, each in a paper format. The first part studies the supply chain of emerging biofuel industry. Two optimization-based models are built to determine the number of facilities to deploy, facility locations, facility capacities, and operational planning within facilities. Cost analyses have been conducted under a variety of biofuel demand scenarios. It is my intention that this model will shed light on biofuel supply chain design considering operational planning under uncertain demand situations. The second part of the dissertation work focuses on analyzing the interaction between the key stakeholders along the supply chain. A bottom-up equilibrium model is built for the emerging biofuel market to study the competition in the advanced biofuel market, explicitly formulating the interactions between farmers, biofuel producers, blenders, and consumers. The model simulates the profit maximization of multiple market entities by incorporating their competitive decisions in farmers' land allocation, biomass transportation, biofuel production, and biofuel blending. As such, the equilibrium model is capable of and appropriate for policy analysis, especially for those policies

Biofuels - 5 disturbing questions

International Nuclear Information System (INIS)

Legalland, J.P.; Lemarchand, J.L.

2008-01-01

Initially considered as the supreme weapon against greenhouse gas emissions, biofuels are today hold responsible to all harms of the Earth: leap of agriculture products price, deforestation, food crisis. Considered some time ago as the perfect clean substitute to petroleum, biofuels are now suspected to have harmful effects on the environment. Should it be just an enormous technical, environmental and human swindle? Should we abandon immediately biofuels to protect the earth and fight the threatening again starvation? Should we wait for the second generation of efficient biofuels, made from non food-derived products and cultivation wastes? This book analyses this delicate debate through 5 main questions: do they starve the world? Are they a clean energy source? Do they contribute to deforestation? Are they economically practicable? Is the second generation ready? (J.S.)

Market possibilities for biofuels

International Nuclear Information System (INIS)

Hektor, B.

1992-01-01

The market for biofuels in Sweden after introduction of a proposed CO 2 -tax on fossil fuels is forecast. The competition between biofuels, fossil fuels and electricity is described for important market segments such as: Paper industry, Sawmills, Other energy-intensive industry, Power and heat producers, small Heat producers, and for Space heating of one-family houses. A market increase of the use of biofuels is probable for the segment small (district) heating centrals, 10 TWh in the next ten year period and even more during a longer period. Other market segments will not be much affected. An increased use of biofuels in paper and pulp industry will not influence the fuel market, since the increase will happen in the industry's normal lumber purchase. (2 figs., 18 tabs.)

Biofuels: Project summaries. Research summaries, Fiscal year 1992

Energy Technology Data Exchange (ETDEWEB)

1993-05-01

Domestic transportation fuels are almost exclusively derived from petroleum and account for about two-thirds of total US petroleum consumption. In 1990, more than 40% of the petroleum used domestically was imported. Because the United States has only 5% of the world`s petroleum reserves, and the countries of the Middle East have about 75%, US imports are likely to continue to increase. With our heavy reliance on oil and without suitable substitutes for petroleum-based transportation fuels, the United States is extremely vulnerable, both strategically and economically, to fuel supply disruptions. In addition to strategic and economic affairs, the envirorunental impacts of our use of petroleum are becoming increasingly evident and must be addressed. The US Department of Energy`s (DOE`s) Office of Energy Efficiency and Renewable Energy (EE), through its Biofuels Systems Division (BSD), is addressing these issues. The BSD is aggressively pursuing research on biofuels-liquid and gaseous fuels produced from renewable domestic feedstocks such as forage grasses, oil seeds, short-rotation tree crops, agricultural and forestry residues, algae, and certain industrial and municipal waste streams.

Initial development of a blurry injector for biofuels

Energy Technology Data Exchange (ETDEWEB)

Azevedo, Claudia Goncalves de; Costa, Fernando de Souza [National Institute for Space Research (INPE) Cachoeira Paulista, SP (Brazil). Associated Lab. of Combustion and Propulsion], Emails: claudia@lcp.inpe.br, fernando@lcp.inpe.br; Couto, Heraldo da Silva [Vale Energy Solution, Sao Jose dos Campos, SP (Brazil)], E-mail: heraldo.couto@vsesa.com.br

2010-07-01

The increasing costs of fossil fuels, environmental concerns and stringent regulations on fuel emissions have caused a significant interest on biofuels, especially ethanol and biodiesel. The combustion of liquid fuels in diesel engines, turbines, rocket engines and industrial furnaces depends on the effective atomization to increase the surface area of the fuel and thus to achieve high rates of mixing and evaporation. In order to promote combustion with maximum efficiency and minimum emissions, an injector must create a fuel spray that evaporates and disperses quickly to produce a homogeneous mixture of vaporized fuel and air. Blurry injectors can produce a spray of small droplets of similar sizes, provide excellent vaporization and mixing of fuel with air, low emissions of NO{sub x} and CO, and high efficiency. This work describes the initial development of a blurry injector for biofuels. Theoretical droplet sizes are calculated in terms of feed pressures and mass flow rates of fuel and air. Droplet size distribution and average diameters are measured by a laser system using a diffraction technique. (author)

L-ascorbic acid losses in Kenyan vegetables during cooking as determined by high performance liquid chromatography

Directory of Open Access Journals (Sweden)

N.M.N. Wekesa

2001-06-01

Full Text Available The loss of L-ascorbic acid (L-AA in 14 different cooked local vegetables found in Nairobi markets was determined by high performance liquid chromatography. The effect of quantity of water on the loss of L-AA during cooking was studied with cowpea leaves. It was found that more L-AA was lost when larger amount of water was used than when smaller amount was used. The effect of the sharpness of the knife on the loss of L-AA was studied with spinach. It was found that more loss of L-AA occurred when a blunt (edge thickness 0.08 cm knife was used for cutting the vegetables than when a sharp knife (edge thickness 0.04 cm was used during cooking. L-AA was also determined when vegetables were cooked in different size pieces (surface are >1 cm2

Washington State Biofuels Industry Development

Energy Technology Data Exchange (ETDEWEB)

Gustafson, Richard [Univ. of Washington, Seattle, WA (United States)

2017-04-09

The funding from this research grant enabled us to design, renovate, and equip laboratories to support University of Washington biofuels research program. The research that is being done with the equipment from this grant will facilitate the establishment of a biofuels industry in the Pacific Northwest and enable the University of Washington to launch a substantial biofuels and bio-based product research program.

Biofuel from jute stick by pyrolysis technology

Science.gov (United States)

Ferdous, J.; Parveen, M.; Islam, M. R.; Haniu, H.; Takai, K.

2017-06-01

In this study the conversion of jute stick into biofuels and chemicals by externally heated fixed-bed pyrolysis reactor have been taken into consideration. The solid jute stick was characterized through proximate and ultimate analysis, gross calorific values and thermo-gravimetric analysis to investigate their suitability as feedstock for this consideration. The solid biomass particles were fed into the reactor by gravity feed type reactor feeder. The products were oil, char and gases. The liquid and char products were collected separately while the gas was flared into the atmosphere. The process conditions were varied by fixed-bed temperature; feed stock particle size, N2 gas flow rate and running time. All parameters were found to influence the product yields significantly. The maximum liquid yields were 50 wt% of solid jute stick at reactor temperature 425°C for N2 gas flow rate 6 l/min, feed particle size 1180-1700 µm and running time 30 min. Liquid products obtained at these conditions were characterized by physical properties, chemical analysis and GC-MS techniques. The results show that it is possible to obtained liquid products that are comparable to petroleum fuels and valuable chemical feedstock from the selected biomass if the pyrolysis conditions are chosen accordingly.

Promoting biofuels: Implications for developing countries

International Nuclear Information System (INIS)

Peters, Joerg; Thielmann, Sascha

2008-01-01

Interest in biofuels is growing worldwide as concerns about the security of energy supply and climate change are moving into the focus of policy makers. With the exception of bioethanol from Brazil, however, production costs of biofuels are typically much higher than those of fossil fuels. As a result, promotion measures such as tax exemptions or blending quotas are indispensable for ascertaining substantial biofuel demand. With particular focus on developing countries, this paper discusses the economic justification of biofuel promotion instruments and investigates their implications. Based on data from India and Tanzania, we find that substantial biofuel usage induces significant financial costs. Furthermore, acreage availability is a binding natural limitation that could also lead to conflicts with food production. Yet, if carefully implemented under the appropriate conditions, biofuel programs might present opportunities for certain developing countries

Associative properties of 137Cs in biofuel ashes

International Nuclear Information System (INIS)

Ravila, A.; Holm, E.

1999-01-01

The present study aims to reveal how radiocesium is associated to the ash particles derived from biofuel combustion. A sequential extraction procedure was carried out for the characterisation of radiocesium speciation in ash generated by different fuels and burner types. The ash types considered were fly ash and bottom ash collected from Swedish district heating plants using bark wood or peat as fuel. A fraction of the radiocesium in biofuel ash can easily become solubilised and mobilised by water and also, a significant fraction of the radionuclides can be bound to the ash particles in cation-exchangeable forms. Therefore, at using the ash derived from biofuels to recycle mineral nutrients for forestry or short rotation coppicing, radiocesium solubilised and leached from the ash by rains has a potential to rather quickly enter the rooting zone of forest vegetation or energy crops. On the other hand, radiocesium strongly bound to the ash will migrate slowly into the soil column with the successive accumulation of litter and in the process act to maintain the external dose rate at an elevated level for a long time. The results of the sequential extraction procedure and activity determination of the different extracted fractions implies that the bioavailable fraction of radiocesium in ash from bark, wood or peat is in the range between 20-85% of the total ash contents. Peat ash collected from a powder burner strongly retained a large fraction (70-90%) of its radiocesium content while the peat ash from a continuos fluidized bed type burner retained nearly 100% of the radiocesium in the bottom ash and only about 15% in the fly ash

Biofuels Refining Engineering

Energy Technology Data Exchange (ETDEWEB)

Lobban, Lance [Univ. of Oklahoma, Norman, OK (United States)

2017-03-28

The goal of this project is the development of novel catalysts and knowledge of reaction pathways and mechanisms for conversion of biomass-based compounds to fuels that are compatible with oil-based fuels and with acceptable or superior fuel properties. The research scope included both catalysts to convert lignocellulosic biomass-based molecules (from pyrolysis) and vegetable oil-based molecules (i.e., triglycerides and fatty acid methyl esters). This project comprised five technical tasks. Each task is briefly introduced below, and major technical accomplishments summarized. Technical accomplishments were described in greater detail in the quarterly progress reports, and in even more detail in the >50 publications acknowledging this DoE project funding (list of publications and presentations included at the end of this report). The results of this research added greatly to the knowledge base necessary for upgrading of pyrolysis oil to hydrocarbon fuels and chemicals, and for conversion of vegetable oils to fungible diesel fuel. Numerous new catalysts and catalytic reaction systems were developed for upgrading particular compounds or compound families found in the biomass-based pyrolysis oils and vegetable oils. Methods to mitigate catalyst deactivation were investigated, including novel reaction/separation systems. Performance and emission characteristics of biofuels in flames and engines were measured. Importantly, the knowledge developed from this project became the basis for a subsequent collaborative proposal led by our research group, involving researchers from the University of Wisconsin, the University of Pittsburg, and the Idaho National Lab, for the DoE Carbon, Hydrogen and Separations Efficiency (CHASE) program, which was subsequently funded (one of only four projects awarded in the CHASE program). The CHASE project examined novel catalytic processes for lignocellulosic biomass conversion as well as technoeconomic analyses for process options for maximum

Evaluation of the agricultural tractor using biofuel and diesel oil; Avaliacao de um trator agricola utilizando biocombustivel e oleo diesel

Energy Technology Data Exchange (ETDEWEB)

Lopes, Reny Adilmar Prestes; Pinheiro Neto, Raimundo; Meyer, Wagner; Mendonca, Elton Costa de; Roberti, Marcelo [Universidade Estadual de Maringa (UEM), PR (Brazil)], Emails: raplopes@uem.br, rpneto@uem.br

2009-07-01

Test with alternative fuels is essential to evaluate the performance of machines and engines. In this paper, the performance of a tractor in chiseling operation was evaluated using oil diesel and biofuel (oil diesel + soybean vegetable oil mixture). Speed of displacement, slip wheels, force traction bar and fuel consumption was evaluated in areas under tillage and no-tillage. The speed of displacement of the set presented similar behavior in tillage and no-tillage. Bigger values mean force in the bar of traction, slip and fuel consumptions had been observed for no-tillage with the tractor operating with diesel. Bigger values mean consumption the biofuel had been observed in areas under tillage. The coverings of the soil had influenced in the values of force bar traction, slip wheels, speed of displacement and fuel consumption. In the studied conditions, the tests demonstrate that the mixture oil diesel + soybean vegetable oil had not influenced in the performance of the tractor. (author)

A multi-actor multi-criteria framework to assess the stakeholder support for different biofuel options: The case of Belgium

International Nuclear Information System (INIS)

Turcksin, Laurence; Macharis, Cathy; Lebeau, Kenneth; Boureima, Faycal; Van Mierlo, Joeri; Bram, Svend; De Ruyck, Jacques; Mertens, Lara; Jossart, Jean-Marc; Gorissen, Leen; Pelkmans, Luc

2011-01-01

The multi-actor multi-criteria analysis (MAMCA) is a methodology to evaluate different policy measures, whereby different stakeholders' opinions are explicitly taken into account. In this paper, the framework is used to assess several biofuel options for Belgium that can contribute to the binding target of 10% renewable fuels in transport by 2020, issued by the Renewable Energy Directive (RED). Four biofuel options (biodiesel, ethanol, biogas and synthetic biodiesel (also referred to as 'biomass-to-liquid' or BTL)) together with a reference fossil fuel option, are evaluated on the aims and objectives of the different stakeholders involved in the biofuel supply chain (feedstock producers, biofuel producers, fuel distributors, end users, vehicle manufacturers, government, NGOs and North-South organizations). Overall, the MAMCA provided insights in the stakeholder's position and possible implementation problems for every biofuel option. As such, it helps decision makers in establishing a supportive policy framework to facilitate implementation and to ensure market success, once they have decided on which biofuel option (or combination of options) to implement. - Research Highlights: → Stakeholder support is an indispensable factor for market success of biofuels. → A MAMCA explicitly includes stakeholder visions in the decision-making process. → The MAMCA shows strengths and weaknesses of alternatives for different stakeholders. →Information on stakeholder's position helps to establish implementation pathways. → Policy makers should focus on combination of biofuel options to reach EU 2020 target.

Organisms for biofuel production: natural bioresources and methodologies for improving their biosynthetic potentials.

Science.gov (United States)

Hu, Guangrong; Ji, Shiqi; Yu, Yanchong; Wang, Shi'an; Zhou, Gongke; Li, Fuli

2015-01-01

In order to relieve the pressure of energy supply and environment contamination that humans are facing, there are now intensive worldwide efforts to explore natural bioresources for production of energy storage compounds, such as lipids, alcohols, hydrocarbons, and polysaccharides. Around the world, many plants have been evaluated and developed as feedstock for bioenergy production, among which several crops have successfully achieved industrialization. Microalgae are another group of photosynthetic autotroph of interest due to their superior growth rates, relatively high photosynthetic conversion efficiencies, and vast metabolic capabilities. Heterotrophic microorganisms, such as yeast and bacteria, can utilize carbohydrates from lignocellulosic biomass directly or after pretreatment and enzymatic hydrolysis to produce liquid biofuels such as ethanol and butanol. Although finding a suitable organism for biofuel production is not easy, many naturally occurring organisms with good traits have recently been obtained. This review mainly focuses on the new organism resources discovered in the last 5 years for production of transport fuels (biodiesel, gasoline, jet fuel, and alkanes) and hydrogen, and available methods to improve natural organisms as platforms for the production of biofuels.

[Model-based biofuels system analysis: a review].

Science.gov (United States)

Chang, Shiyan; Zhang, Xiliang; Zhao, Lili; Ou, Xunmin

2011-03-01

Model-based system analysis is an important tool for evaluating the potential and impacts of biofuels, and for drafting biofuels technology roadmaps and targets. The broad reach of the biofuels supply chain requires that biofuels system analyses span a range of disciplines, including agriculture/forestry, energy, economics, and the environment. Here we reviewed various models developed for or applied to modeling biofuels, and presented a critical analysis of Agriculture/Forestry System Models, Energy System Models, Integrated Assessment Models, Micro-level Cost, Energy and Emission Calculation Models, and Specific Macro-level Biofuel Models. We focused on the models' strengths, weaknesses, and applicability, facilitating the selection of a suitable type of model for specific issues. Such an analysis was a prerequisite for future biofuels system modeling, and represented a valuable resource for researchers and policy makers.

Second generation biofuels: Economics and policies

International Nuclear Information System (INIS)

Carriquiry, Miguel A.; Du Xiaodong; Timilsina, Govinda R.

2011-01-01

This study reviews economics of production of second generation biofuels from various feedstocks, including crop and wood/forestry residues, lignocellulosic energy crops, jatropha, and algae. The study indicates that while second generation biofuels could significantly contribute to the future energy supply mix, cost is a major barrier to its commercial production in the near to medium term. Depending upon type of biofuels, feedstock prices and conversion costs, the cost of cellulosic ethanol is found to be two to three times higher than the current price of gasoline on an energy equivalent basis. The median cost (across the studies reviewed) of biodiesel produced from microalgae, a prospective feedstock, is seven times higher than the current price of diesel, although much higher cost estimates have been reported. As compared with the case of first generation biofuels, in which feedstock can account for over two-thirds of the total costs, the share of feedstock in the total costs is relatively lower (30-50%) in the case of second generation biofuels. While significant cost reductions are needed for both types of second generation biofuels, the critical barriers are at different steps of the production process. For cellulosic ethanol, the biomass conversion costs needs to be reduced. On the other hand, feedstock cost is the main issue for biodiesel. At present, policy instruments, such as fiscal incentives and consumption mandates have in general not differentiated between the first and second generation biofuels except in the cases of the US and EU. The policy regime should be revised to account for the relative merits of different types of biofuels. - Highlights: → Second generation biofuels could significantly contribute to the future energy supply mix. → Cost is a major barrier to its the commercial production in the near to medium term. → The policy regime should be revised to account for the relative merits of different biofuels.

Second generation biofuels: Economics and policies

Energy Technology Data Exchange (ETDEWEB)

Carriquiry, Miguel A., E-mail: miguelc@iastate.edu [Center for Agricultural and Rural Development, Iowa State University (United States); Du Xiaodong, E-mail: xdu23@wisc.edu [Department of Agricultural and Applied Economics, University of Wisconsin-Madison (United States); Timilsina, Govinda R., E-mail: gtimilsina@worldbank.org [Development Research Group, The World Bank (United States)

2011-07-15

This study reviews economics of production of second generation biofuels from various feedstocks, including crop and wood/forestry residues, lignocellulosic energy crops, jatropha, and algae. The study indicates that while second generation biofuels could significantly contribute to the future energy supply mix, cost is a major barrier to its commercial production in the near to medium term. Depending upon type of biofuels, feedstock prices and conversion costs, the cost of cellulosic ethanol is found to be two to three times higher than the current price of gasoline on an energy equivalent basis. The median cost (across the studies reviewed) of biodiesel produced from microalgae, a prospective feedstock, is seven times higher than the current price of diesel, although much higher cost estimates have been reported. As compared with the case of first generation biofuels, in which feedstock can account for over two-thirds of the total costs, the share of feedstock in the total costs is relatively lower (30-50%) in the case of second generation biofuels. While significant cost reductions are needed for both types of second generation biofuels, the critical barriers are at different steps of the production process. For cellulosic ethanol, the biomass conversion costs needs to be reduced. On the other hand, feedstock cost is the main issue for biodiesel. At present, policy instruments, such as fiscal incentives and consumption mandates have in general not differentiated between the first and second generation biofuels except in the cases of the US and EU. The policy regime should be revised to account for the relative merits of different types of biofuels. - Highlights: > Second generation biofuels could significantly contribute to the future energy supply mix. > Cost is a major barrier to its the commercial production in the near to medium term. > The policy regime should be revised to account for the relative merits of different biofuels.

Review on biofuel oil and gas production processes from microalgae

International Nuclear Information System (INIS)

Amin, Sarmidi

2009-01-01

Microalgae, as biomass, are a potential source of renewable energy, and they can be converted into energy such as biofuel oil and gas. This paper presents a brief review on the main conversion processes of microalgae becoming energy. Since microalgae have high water content, not all biomass energy conversion processes can be applied. By using thermochemical processes, oil and gas can be produced, and by using biochemical processes, ethanol and biodiesel can be produced. The properties of the microalgae product are almost similar to those of offish and vegetable oils, and therefore, it can be considered as a substitute of fossil oil.

Renewable liquid transport fuels from microbes and waste resources

OpenAIRE

Jenkins, Rhodri

2014-01-01

In order to satisfy the global requirement for transport fuel sustainably, renewable liquid biofuels must be developed. Currently, two biofuels dominate the market; bioethanol for spark ignition and biodiesel for compression ignition engines. However, both fuels exhibit technical issues such as low energy density, poor low temperature performance and poor stability. In addition, bioethanol and biodiesel sourced from first generation feedstocks use arable land in competition with food producti...

Biofuels, a bad thing?; Boeser Biokraftstoff?

Energy Technology Data Exchange (ETDEWEB)

Jensen, D.; Bensmann, M.

2008-05-15

The discussions over biofuels are still going on. Critics claim that biofuels ruin engine components, destroy rainforests and cause high food prices and global hunger. According to this contribution, the Federal government's biofuels policy was wrong and was doomed to fail. (orig.)

Climate regulation enhances the value of second generation biofuel technology

Science.gov (United States)

Hertel, T. W.; Steinbuks, J.; Tyner, W.

2014-12-01

Commercial scale implementation of second generation (2G) biofuels has long been 'just over the horizon - perhaps a decade away'. However, with recent innovations, and higher oil prices, we appear to be on the verge of finally seeing commercial scale implementations of cellulosic to liquid fuel conversion technologies. Interest in this technology derives from many quarters. Environmentalists see this as a way of reducing our carbon footprint, however, absent a global market for carbon emissions, private firms will not factor this into their investment decisions. Those interested in poverty and nutrition see this as a channel for lessening the biofuels' impact on food prices. But what is 2G technology worth to society? How valuable are prospective improvements in this technology? And how are these valuations affected by future uncertainties, including climate regulation, climate change impacts, and energy prices? This paper addresses all of these questions. We employ FABLE, a dynamic optimization model for the world's land resources which characterizes the optimal long run path for protected natural lands, managed forests, crop and livestock land use, energy extraction and biofuels over the period 2005-2105. By running this model twice for each future state of the world - once with 2G biofuels technology available and once without - we measure the contribution of the technology to global welfare. Given the uncertainty in how these technologies are likely to evolve, we consider a range cost estimates - from optimistic to pessimistic. In addition to technological uncertainty, there is great uncertainty in the conditions characterizing our baseline for the 21st century. For each of the 2G technology scenarios, we therefore also consider a range of outcomes for key drivers of global land use, including: population, income, oil prices, climate change impacts and climate regulation. We find that the social valuation of 2G technologies depends critically on climate change

Experimental investigation concerning the influence of fuel type and properties on the injection and atomization of liquid biofuels in an optical combustion chamber

International Nuclear Information System (INIS)

Galle, J.; Defruyt, S.; Van de Maele, C.; Rodriguez, R. Piloto; Denon, Q.; Verliefde, A.; Verhelst, S.

2013-01-01

Due to the scarcity of fossil fuels and the future stringent emission limits, there is an increasing interest for the use of renewable biofuels in compression ignition engines. However, these fuels have different physical, chemical and thermodynamic properties affecting atomization, spray development and combustion processes. The results reported in this paper have been obtained by experimentation with a constant volume combustion chamber. The influences of physical fuel properties on injections under non-evaporating conditions are studied, using a pump-line-nozzle system from a medium speed diesel engine with injection pressures up to 1200 bar, by changing the fuel type and temperature. Experiments were conducted for diesel, biodiesel, straight vegetable oils and animal fats. Injection pressure and needle lift measurements were analyzed. A high speed camera was used to visualize the spray, which enabled us to study the spray penetration and spray angle. Our results show that the fuel temperature is an important parameter to control because it significantly affects the fuel properties. Both the injection timing and injection duration are affected by the fuel properties. The influences of these properties on the spray development were less pronounced. At low temperatures, a strongly deteriorated atomization of oils and fats was observed. -- Highlights: • Spray measurements in an optical combustion chamber. • Influence on the injections system is compared for different bio-fuels. •Temperature effects the fuel properties, with strong influence on the injection system. • Viscosity has significant influence on atomization, especially for viscous fuels. • No difference for spray penetration and angle unlike the mass distribution

Alternative Crops and Biofuel Production

Energy Technology Data Exchange (ETDEWEB)

Kenkel, Philip [Oklahoma State Univ., Stillwater, OK (United States); Holcomb, Rodney B. [Oklahoma State Univ., Stillwater, OK (United States)

2013-03-01

In order for the biofuel industry to meet the RFS benchmarks for biofuels, new feedstock sources and production systems will have to be identified and evaluated. The Southern Plains has the potential to produce over a billion gallons of biofuels from regionally produced alternative crops, agricultural residues, and animal fats. While information on biofuel conversion processes is available, it is difficult for entrepreneurs, community planners and other interested individuals to determine the feasibility of biofuel processes or to match production alternatives with feed stock availability and community infrastructure. This project facilitates the development of biofuel production from these regionally available feed stocks. Project activities are concentrated in five major areas. The first component focused on demonstrating the supply of biofuel feedstocks. This involves modeling the yield and cost of production of dedicated energy crops at the county level. In 1991 the DOE selected switchgrass as a renewable source to produce transportation fuel after extensive evaluations of many plant species in multiple location (Caddel et al,. 2010). However, data on the yield and cost of production of switchgrass are limited. This deficiency in demonstrating the supply of biofuel feedstocks was addressed by modeling the potential supply and geographic variability of switchgrass yields based on relationship of available switchgrass yields to the yields of other forage crops. This model made it possible to create a database of projected switchgrass yields for five different soil types at the county level. A major advantage of this methodology is that the supply projections can be easily updated as improved varieties of switchgrass are developed and additional yield data becomes available. The modeling techniques are illustrated using the geographic area of Oklahoma. A summary of the regional supply is then provided.

Retro-analysis of liquid bio-ethanol and bio-diesel in New Zealand

International Nuclear Information System (INIS)

Krumdieck, S.; Page, S.

2013-01-01

This paper uses a new approach of retro-analysis. Typically policy is informed by forward-looking analysis of potential for alternative energy technologies. But historical knowledge of energy and processing requirements and greenhouse effects is more reliable for engineering evaluation of biofuel production systems. This study calculates energy inputs and greenhouse gas emissions for the most efficient biomass feedstocks in New Zealand if the policy had been implemented to maximize liquid biofuel production in the year 2004/2005. The study uses existing processing technologies and agricultural statistics. Bioethanol production is calculated from putrescible wastes and starch crops, and biodiesel production from rapeseed, tallow, wood and waste paper. Each production system is further evaluated using measures of land use, energy input, crop production related to the energy product, plus relative measures of efficiency and renewability. The research findings are that maximum biofuel production in 2004/2005 would have provided only a few per cent of demand, and would not have reduced dependence on foreign imported oil or exposure to fuel price rise. Finally, we conclude that demand management and efficiency are more effective means of meeting policy objectives. -- Graphical abstract: Input-output energy flows for liquid biofuels with retro-analysis reference to 2004. Display Omitted -- Highlights: •We conducted a Retro-analysis of biofuel production for New Zealand in 2004. •EROI analysis shows biodiesel from oil crops is the only viable biofuel. •Renewability analysis shows biofuels do not reduce exposure to peak oil issues. •GHG analysis shows 89% CO 2 emission reductions for the best biodiesel. •Total biofuel from food crops and wastes could provide less than 10% of demand

Algal Biofuels | Bioenergy | NREL

Science.gov (United States)

biofuels and bioproducts, Algal Research (2016) Process Design and Economics for the Production of Algal cyanobacteria, Nature Plants (2015) Acid-catalyzed algal biomass pretreatment for integrated lipid and nitrogen, we can indefinitely maintain the genetic state of the sample for future research in biofuels

An assessment of Thailand's biofuel development

DEFF Research Database (Denmark)

Kumar, S.; Salam, P. Abdul; Shrestha, Pujan

2013-01-01

The paper provides an assessment of first generation biofuel (ethanol and biodiesel) development in Thailand in terms of feedstock used, production trends, planned targets and policies and discusses the biofuel sustainability issues-environmental, socio-economic and food security aspects. The pol......The paper provides an assessment of first generation biofuel (ethanol and biodiesel) development in Thailand in terms of feedstock used, production trends, planned targets and policies and discusses the biofuel sustainability issues-environmental, socio-economic and food security aspects...... to land and water use and food security are important considerations to be addressed for its large scale application. Second generation biofuels derived from agricultural residues perform favorably on environmental and social sustainability issues in comparison to first generation biofuel sources...... as transportation fuel. Alternatively, the same amount of residue could provide 0.8-2.1 billion liters per year of diesel (biomass to Fischer-Tropsch diesel) to potentially offset 6%-15% of national diesel consumption in the transportation sector....

Ultrasonic waste activated sludge disintegration for recovering multiple nutrients for biofuel production.

Science.gov (United States)

Xie, Guo-Jun; Liu, Bing-Feng; Wang, Qilin; Ding, Jie; Ren, Nan-Qi

2016-04-15

Waste activated sludge is a valuable resource containing multiple nutrients, but is currently treated and disposed of as an important source of pollution. In this work, waste activated sludge after ultrasound pretreatment was reused as multiple nutrients for biofuel production. The nutrients trapped in sludge floc were transferred into liquid medium by ultrasonic disintegration during first 30 min, while further increase of pretreatment time only resulted in slight increase of nutrients release. Hydrogen production by Ethanoligenens harbinense B49 from glucose significantly increased with the concentration of ultrasonic sludge, and reached maximum yield of 1.97 mol H2/mol glucose at sludge concentration of 7.75 g volatile suspended solids/l. Without addition of any other chemicals, waste molasses rich in carbohydrate was efficiently turned into hydrogen with yield of 189.34 ml H2/g total sugar by E. harbinense B49 using ultrasonic sludge as nutrients. The results also showed that hydrogen production using pretreated sludge as multiple nutrients was higher than those using standard nutrients. Acetic acid produced by E. harbinense B49 together with the residual nutrients in the liquid medium were further converted into hydrogen (271.36 ml H2/g total sugar) by Rhodopseudomonas faecalis RLD-53 through photo fermentation, while ethanol was the sole end product with yield of 220.26 mg/g total sugar. Thus, pretreated sludge was an efficient nutrients source for biofuel production, which could replace the standard nutrients. This research provided a novel strategy to achieve environmental friendly sludge disposal and simultaneous efficient biofuel recovery from organic waste. Copyright © 2016 Elsevier Ltd. All rights reserved.

World Biofuels Production Potential Understanding the Challenges to Meeting the U.S. Renewable Fuel Standard

Energy Technology Data Exchange (ETDEWEB)

Sastri, B.; Lee, A.

2008-09-15

. Within the mandate, amounts of advanced biofuels, including biomass-based diesel and cellulosic biofuels, are required beginning in 2009. Imported renewable fuels are also eligible for the RFS. Another key U.S. policy is the $1.01 per gal tax credit for producers of cellulosic biofuels enacted as part of the 2008 Farm Bill. This credit, along with the DOE's research, development and demonstration (RD&D) programs, are assumed to enable the rapid expansion of U.S. and global cellulosic biofuels production needed for the U.S. to approach the 2022 RFS goal. While the Environmental Protection Agency (EPA) has yet to issue RFS rules to determine which fuels would meet the greenhouse gas (GHG) reduction and land use restrictions specified in EISA, we assume that cellulosic ethanol, biomass-to-liquid fuels (BTL), sugar-derived ethanol, and fatty acid methyl ester biodiesel would all meet the EISA advanced biofuel requirements. We also assume that enough U.S. corn ethanol would meet EISA's biofuel requirements or otherwise be grandfathered under EISA to reach 15 B gal per year.

A roadmap for biofuels...

NARCIS (Netherlands)

Faaij, A.P.C.; Londo, H.M.

2009-01-01

Biofuels have been in the eye of the storm, in particular since 2008, when the food crisis was considered by many to be caused by the increased production of biofuels. Heavy criticism in public media made various governments, including the European Commission, reconsider their targets and ambitions

The rationality of biofuels

International Nuclear Information System (INIS)

Horta Nogueira, Luiz Augusto; Moreira, Jose Roberto; Schuchardt, Ulf; Goldemberg, Jose

2013-01-01

In an editorial of a recent issue of a known academic journal, Prof. Hartmut Michel affirmed that “…the production of biofuels constitutes an extremely inefficient land use… We should not grow plants for biofuel production.”, after comparing the area occupied with plants for bioenergy production with the one required for photovoltaic cells to supply the same amount of energy for transportation. This assertion is not correct for all situations and this comparison deserves a more careful analysis, evaluating the actual and prospective technological scenarios and other relevant aspects, such as capacity requirements, energy consumed during the life cycle of energy systems and the associated impacts. In this communication this comparison is revaluated, presenting a different perspective, more favorable for the bioenergy routes. - Highlights: • Energy systems and life cycle impacts are compared under equal conditions. • The comparison is done between biofuels and photovoltaic/battery in mobility uses. • Biofuels are a valuable option when produced sustainably by efficient routes

Sustainability development: Biofuels in agriculture

OpenAIRE

Cheteni, Priviledge

2017-01-01

Biofuels are socially and politically accepted as a form of sustainable energy in numerous countries. However, cases of environmental degradation and land grabs have highlighted the negative effects to their adoption. Smallholder farmers are vital in the development of a biofuel industry. The study sort to assess the implications in the adoption of biofuel crops by smallholder farmers. A semi-structured questionnaire was administered to 129 smallholder farmers who were sampled from the Easter...

Sustainable production of a new generation biofuel by lipase-catalyzed esterification of fatty acids from liquid industrial waste biomass.

Science.gov (United States)

Foukis, Athanasios; Gkini, Olga A; Stergiou, Panagiota-Yiolanda; Sakkas, Vasilios A; Dima, Agapi; Boura, Konstantina; Koutinas, Athanasios; Papamichael, Emmanuel M

2017-08-01

In this work we suggest a methodology comprising the design and use of cost-effective, sustainable, and environmentally friendly process for biofuel production compatible with the market demands. A new generation biofuel is produced using fatty acids, which were generated from acidogenesis of industrial wastes of bioethanol distilleries, and esterified with selected alcohols by immobilized Candida antarctica Lipase-B. Suitable reactors with significant parameters and conditions were studied through experimental design, and novel esterification processes were suggested; among others, the continuous removal of the produced water was provided. Finally, economically sustainable biofuel production was achieved providing high ester yield (<97%) along with augmented concentration (3.35M) in the reaction mixtures at relatively short esterification times, whereas the immobilized lipase maintained over 90% of its initial esterifying ability after reused for ten cycles. Copyright © 2017 Elsevier Ltd. All rights reserved.

Enzymatic electrodes nanostructured with functionalized carbon nanotubes for biofuel cell applications

Energy Technology Data Exchange (ETDEWEB)

Nazaruk, E.; Bilewicz, R. [University of Warsaw, Faculty of Chemistry, Warsaw (Poland); Sadowska, K.; Biernat, J.F. [Gdansk University of Technology, Chemical Faculty, Gdansk (Poland); Rogalski, J. [Maria Curie Sklodowska University, Department of Biochemistry, Lublin (Poland); Ginalska, G. [Medical University of Lublin, Department of Biochemistry, Lublin (Poland)

2010-10-15

Nanostructured bioelectrodes were designed and assembled into a biofuel cell with no separating membrane. The glassy carbon electrodes were modified with mediator-functionalized carbon nanotubes. Ferrocene (Fc) and 2,2{sup '}-azino-bis (3-ethylbenzothiazoline-6-sulfonate) diammonium salt (ABTS) bound chemically to the carbon nanotubes were found useful as mediators of the enzyme catalyzed electrode processes. Glucose oxidase from Aspergillus niger AM-11 and laccase from Cerrena unicolor C-139 were incorporated in a liquid-crystalline matrix-monoolein cubic phase. The carbon nanotubes-nanostructured electrode surface was covered with the cubic phase film containing the enzyme and acted as the catalytic surface for the oxidation of glucose and reduction of oxygen. Thanks to the mediating role of derivatized nanotubes the catalysis was almost ten times more efficient than on the GCE electrodes: catalytic current of glucose oxidation was 1 mA cm{sup -2} and oxygen reduction current exceeded 0.6 mA cm{sup -2}. The open circuit voltage of the biofuel cell was 0.43 V. Application of carbon nanotubes increased the maximum power output of the constructed biofuel cell to 100 {mu}W cm{sup -2} without stirring of the solution which was ca. 100 times more efficient than using the same bioelectrodes without nanotubes on the electrode surface. (orig.)

Biofuels in Central America, a real potential for commercial production

Energy Technology Data Exchange (ETDEWEB)

Garcia, O.L. (Regional Coordinator Energy and Environmental Partnership with Central America EEP (El Salvador))

2007-07-01

The purpose of this paper is to show the current capabilities of the Central American countries regarding the production of biofuels, and the real potential in increasing the volumes produced and the impacts that can be generated if a non sustainable policy is followed for achieving the targets of biofuel production. Due to the world oil price crisis, and the fact that Central American counties are fully dependant on oil imports (just Guatemala and Belize produce little amounts of oil), just to mention, in some countries the imports of oil is equivalent to the 40% of the total exports, the region started to look for massive production of biofuels, something that it is not new for us. The countries have started with programs for producing ethanol from sugar cane, because it is one of the most strongest industries in Central America and they have all the infrastructure and financial sources to develop this project. The ethanol is a biofuel that can be mixed with gasoline or a complete substitute. Another biofuel that is currently under develop, is the production of biodiesel, and the main source for it nowadays is the Palm oil, where Costa Rica, Honduras and Guatemala have already commercial productions of crude palm oil, but the principal use of it is for the food industry, but now it is under assessment for using part of it for biodiesel. EEP is now developing pilot programs for production of biodiesel from a native plant named Jatropha curcas, and up to now we have a commercial plantation in Guatemala, and we started as well in Honduras for start spreading this plantations. In El Salvador we installed a pilot processing plant for biodiesel that can be operated with multiple feed stock, such as Jatropha, palm oil, castor oil, vegetable used oil and others. Currently we have interesting and good results regarding the production of Jatropha, we have developed a methodology for its cropping, harvesting and processing. All the vehicles and equipment involved in the

Privileged Biofuels, Marginalized Indigenous Peoples: The Coevolution of Biofuels Development in the Tropics

Science.gov (United States)

Montefrio, Marvin Joseph F.

2012-01-01

Biofuels development has assumed an important role in integrating Indigenous peoples and other marginalized populations in the production of biofuels for global consumption. By combining the theories of commoditization and the environmental sociology of networks and flows, the author analyzed emerging trends and possible changes in institutions…

Energy intensity, life-cycle greenhouse gas emissions, and economic assessment of liquid biofuel pipelines.

Science.gov (United States)

Strogen, Bret; Horvath, Arpad; Zilberman, David

2013-12-01

Petroleum fuels are predominantly transported domestically by pipelines, whereas biofuels are almost exclusively transported by rail, barge, and truck. As biofuel production increases, new pipelines may become economically attractive. Location-specific variables impacting pipeline viability include construction costs, availability and costs of alternative transportation modes, electricity prices and emissions (if priced), throughput, and subsurface temperature. When transporting alcohol or diesel-like fuels, pipelines have a lower direct energy intensity than rail, barge, and trucks if fluid velocity is under 1 m/s for 4-inch diameter pipelines and 2 m/s for 8-inch or larger pipelines. Across multiple hypothetical state-specific scenarios, profit-maximizing design velocities range from 1.2 to 1.9 m/s. In costs and GHG emissions, optimized pipelines outperform trucks in each state and rail and barge in most states, if projected throughput exceeds four billion liters/year. If emissions are priced, optimum design diameters typically increase to reduce pumping energy demands, increasing the cost-effectiveness of pipeline projects. Copyright © 2013 Elsevier Ltd. All rights reserved.

Bio-fuels barometer

International Nuclear Information System (INIS)

Anon.

2010-01-01

European Union bio-fuel use for transport reached 12 million tonnes of oil equivalent (mtoe) threshold during 2009. The slowdown in the growth of European consumption deepened again. Bio-fuel used in transport only grew by 18.7% between 2008 and 2009, as against 30.3% between 2007 and 2008 and 41.8% between 2006 and 2007. The bio-fuel incorporation rate in all fuels used by transport in the E.U. is unlikely to pass 4% in 2009. We can note that: -) the proportion of bio-fuel in the German fuels market has plummeted since 2007: from 7.3% in 2007 to 5.5% in 2009; -) France stays on course with an incorporation rate of 6.25% in 2009; -) In Spain the incorporation rate reached 3.4% in 2009 while it was 1.9% in 2008. The European bio-diesel industry has had another tough year. European production only rose by 16.6% in 2009 or by about 9 million tonnes which is well below the previous year-on-year growth rate recorded (35.7%). France is leading the production of bio-ethanol fuels in Europe with an output of 1250 million liters in 2009 while the total European production reached 3700 million litters and the world production 74000 million liters. (A.C.)

Sustainability aspects of biofuel production

Science.gov (United States)

Pawłowski, L.; Cel, W.; Wójcik Oliveira, K.

2018-05-01

Nowadays, world development depends on the energy supply. The use of fossil fuels leads to two threats: depletion of resources within a single century and climate changes caused by the emission of CO2 from fossil fuels combustion. Widespread application of renewable energy sources, in which biofuels play a major role, is proposed as a counter-measure. The paper made an attempt to evaluate to what extent biofuels meet the criteria of sustainable development. It was shown that excessive development of biofuels may threaten the sustainable development paradigms both in the aspect of: intergenerational equity, leading to an increase of food prices, as well as intergenerational equity, resulting in degradation of the environment. The paper presents the possibility of sustainable biofuels production increase.

Biofuels: policies, standards and technologies

Energy Technology Data Exchange (ETDEWEB)

NONE

2010-09-15

Skyrocketing prices of crude oil in the middle of the first decade of the 21st century accompanied by rising prices for food focused political and public attention on the role of biofuels. On the one hand, biofuels were considered as a potential automotive fuel with a bright future, on the other hand, biofuels were accused of competing with food production for land. The truth must lie somewhere in-between and is strongly dependent on the individual circumstance in different countries and regions. As food and energy are closely interconnected and often compete with each other for other resources, such as water, the World Energy Council - following numerous requests of its Member Committees - decided to undertake an independent assessment of biofuels policies, technologies and standards.

Two-step microextraction combined with high performance liquid chromatographic analysis of pyrethroids in water and vegetable samples.

Science.gov (United States)

Mukdasai, Siriboon; Thomas, Chunpen; Srijaranai, Supalax

2014-03-01

Dispersive liquid microextraction (DLME) combined with dispersive µ-solid phase extraction (D-µ-SPE) has been developed as a new approach for the extraction of four pyrethroids (tetramethrin, fenpropathrin, deltamethrin and permethrin) prior to the analysis by high performance liquid chromatography (HPLC) with UV detection. 1-Octanol was used as the extraction solvent in DLME. Magnetic nanoparticles (Fe3O4) functionalized with 3-aminopropyl triethoxysilane (APTS) were used as the dispersive in DLME and as the adsorbent in D-µ-SPE. The extracted pyrethroids were separated within 30 min using isocratic elution with acetonitrile:water (72:28). The factors affecting the extraction efficiency were investigated. Under the optimum conditions, the enrichment factors were in the range of 51-108. Linearity was obtained in the range 0.5-400 ng mL(-1) (tetramethrin) and 5-400 ng mL(-1) (fenpropathrin, deltamethrin and permethrin) with the correlation coefficients (R(2)) greater than 0.995. Detection limits were 0.05-2 ng mL(-1) (water samples) and 0.02-2.0 ng g(-1) (vegetable samples). The relative standard deviations of peak area varied from 1.8 to 2.5% (n=10). The extraction recoveries of the four pyrethroids in field water and vegetable samples were 91.7-104.5%. The proposed method has high potential for use as a sensitive method for determination of pyrethroid residues in water and vegetable samples. Copyright © 2013 Elsevier B.V. All rights reserved.

Potential of biofuels for shipping. Final Report

Energy Technology Data Exchange (ETDEWEB)

Florentinus, A.; Hamelinck, C.; Van den Bos, A.; Winkel, R.; Cuijpers, M. [Ecofys Netherlands, Utrecht (Netherlands)

2012-01-15

Biofuels could be one of the options to realize a lower carbon intensity in the propulsion of ships and also possibly reduce the effect of ship emissions on local air quality. Therefore, EMSA, the European Maritime Safety Agency, is evaluating if and how biofuels could be used in the shipping sector as an alternative fuel. To determine the potential of biofuels for ships, a clearer picture is needed on technical and organizational limitations of biofuels in ships, both on board of the ship as in the fuel supply chain to the ship. Economic and sustainability analysis of biofuels should be included in this picture, as well as an overview on current and potential policy measures to stimulate the use of biofuels in shipping. Ecofys has determined the potential of biofuels, based on analysis of collected data through literature review, own expertise and experiences, direct communication with EMSA, research publications, market developments based on press and other media, and consultations with relevant stakeholders in the shipping market.

Biofuels and certification. A workshop at the Harvard Kennedy School of Government. Summary report

Energy Technology Data Exchange (ETDEWEB)

Devereaux, Charan; Lee, Henry

2009-06-01

Liquid biofuels can provide a substitute for fossil fuels in the transportation sector. Many countries have mandated the use of biofuels, by creating targets for their use. If not implemented with care, however, actions that increase biofuel production can put upward pressure on food prices, increase greenhouse gas (GHG) emissions, and exacerbate degradation of land, forest, and water sources. A strong global biofuels industry will not emerge unless these environmental and social concerns are addressed. Interested parties around the world are actively debating the design and implementation of policies to meet the biofuel goals, particularly those established in the United States and Europe. In general, policy options for managing the potential risks and benefits of biofuel development should specify not only clear standards governing biofuel content and production processes, but also certification processes for verifying whether particular biofuels meet those standards, and specific metrics or indicators on which to base the certification. Historically, many standards in the energy and environment fields have ultimately been set or supported by governments. Many of the certification processes have been voluntary, carried out by independent third parties. The biofuels case is a young one, however, with questions of goals, standards, certification, and metrics still in interdependent flux. The workshop focused its discussions on certification issues, but found the discussions naturally reaching into ongoing debates regarding possible goals, standards, and metrics. Many countries are proposing that for a biofuel to qualify as contributing to government-mandated targets or goals, it must be certified to meet certain standards. These standards could be limited to the amount of GHG emitted in the production process or could include a number of other environmental sustainability concerns ranging from deforestation and biodiversity to water resources. While the threat to

Biofuels: making tough choices

Energy Technology Data Exchange (ETDEWEB)

Vermeulen, Sonja; Dufey, Annie; Vorley, Bill

2008-02-15

The jury is still out on biofuels. But one thing at least is certain: serious trade-offs are involved in the production and use of these biomass-derived alternatives to fossil fuels. This has not been lost on the European Union. The year kicked off with an announcement from the EU environment commissioner that it may be better for the EU to miss its target of reaching 10 per cent biofuel content in road fuels by 2020 than to compromise the environment and human wellbeing. The 'decision tree' outlined here can guide the interdependent processes of deliberation and analysis needed for making tough choices in national biofuels development.

Biofuels for sustainable transportation

Energy Technology Data Exchange (ETDEWEB)

Neufeld, S.

2000-05-23

Biomass is an attractive energy source, and transportation fuels made from biomass offer a number of benefits. Developing the technology to produce and use biofuels will create transportation fuel options that can positively impact the national energy security, the economy, and the environment. Biofuels include ethanol, methanol, biodiesel, biocrude, and methane.

Panorama 2018 - 2017 biofuels scoreboard

International Nuclear Information System (INIS)

Boute, Anne; Lorne, Daphne

2018-01-01

This note presents some 2017 statistical data about biofuels: consumption, fuel substitution rate, world ethanol and bio-diesel markets, diesel substitutes, French market, R and D investments, political measures for biofuels development

Effect of biofuel on environment

International Nuclear Information System (INIS)

Kalam, M.A; Masjuki, H.H.; Maleque, M.A.

2001-01-01

Biofuels are alcohols, esters, and other chemical made from cellulosic biomass such as herbaceous and woody plants, agricultural and forestry residues, and a large portion of municipal solid and industrial waste. Biofuels are renewable and mostly suitable for diesel engines due to their similar physiochemical properties as traditional diesel oil. Demand of biofuel is increasing and some European countries have started using biofuel in diesel engine. This interest has been grown in many countries mainly due to fluctuating oil prices because of diminishing availability of conventional sources and polluted environment. However, the use of biofuel for diesel engine would be more beneficial to oil importing countries by saving foreign exchange, because biofuel is domestic renewable fuels. This paper presents the evaluation results of a multi-cylinder diesel engine operated on blends of ten, twenty, thirty, forty and fifty percent of ordinary coconut oil (COCO) with ordinary diesel (OD). The test results from all the COCO blends were compared with OD. The fuels were compared based on the emissions results including, exhaust temperature, NO x , smoke, CO, HC, benzene and polycyclic aromatic hydrocarbon (PAH). Carbon deposit on injector nozzles was also monitored. Exhaust emissions results showed that increasing coconut oil in blend decreases all the exhaust emissions. Carbon deposited on injector nozzles was observed where no hard carbon was found on injector tip when the engine was running on COCO blends. (Author)

Land Clearing and the Biofuel Carbon Debt

Science.gov (United States)

Fargione, Joseph; Hill, Jason; Tilman, David; Polasky, Stephen; Hawthorne, Peter

2008-02-01

Increasing energy use, climate change, and carbon dioxide (CO2) emissions from fossil fuels make switching to low-carbon fuels a high priority. Biofuels are a potential low-carbon energy source, but whether biofuels offer carbon savings depends on how they are produced. Converting rainforests, peatlands, savannas, or grasslands to produce food crop based biofuels in Brazil, Southeast Asia, and the United States creates a “biofuel carbon debt” by releasing 17 to 420 times more CO2 than the annual greenhouse gas (GHG) reductions that these biofuels would provide by displacing fossil fuels. In contrast, biofuels made from waste biomass or from biomass grown on degraded and abandoned agricultural lands planted with perennials incur little or no carbon debt and can offer immediate and sustained GHG advantages.

Protecting innovation: genomics-based intellectual property for the development of feedstock for second-generation biofuels.

Science.gov (United States)

Harfouche, Antoine; Grant, Kannan; Selig, Marcus; Tsai, Daniel; Meilan, Richard

2010-06-01

One of the many controversies surrounding large-scale biofuel production is the diversion of land and other resources that might otherwise be used for food crops. Recent innovations will lead to a second generation of biofuel crops that can co-exist with food crops with little or no competition. Feedstocks from these bio-energy crops will be used to produce liquid fuel from cellulose, the most abundant polymer on the planet. Cell walls of higher plants are mainly composed of cellulose, hemicellulose, and lignin polymers. Cellulose and hemicellulose are polysaccharides with obvious value for biofuel production. However, lignin, while vital for plant growth and development, is widely known to negatively impact conversion efficiencies. Biomass pre-treatment, which is aimed at lignin removal, is not straightforward, and presents one of the major scientific and technical challenges and expenses associated with secondgeneration biofuel production. Scientific breakthroughs associated with altering the expression of key genes in the lignin biosynthetic pathway of biomass crops is a promising path toward solving this problem, and will likely impact the feedstock patent landscape in the near future. This review summarizes some of the recent and most important issued patents and patent applications associated with lignin-modification genes and methods of developing transgenic plants with altered lignin content and composition.

Biofuels and their global influence on land availability for agriculture and nature. A first evaluation and a proposal for further fact finding

Energy Technology Data Exchange (ETDEWEB)

Bergsma, G.; Kampman, B.; Croezen, H.; Sevenster, M.

2007-02-15

Unilever asked CE to make a script for a strategic study to provide insight in the effects of the various competing sectors, and in the limitations of land availability with respect to the production of biomass for biofuels. Furthermore, this strategic study should provide recommendations on how to proceed on these issues, aimed at governments and other stakeholders in the EU and the USA. This report is the result of this preliminary study, and provides the necessary background information and the script for further work. This report is build up along the following lines: Chapter 2: An overview of the main biofuel market developments, including biofuel policies and drivers, with a focus on the EU and the USA. Chapter 3: A discussion of the main issues and developments regarding the competition between biofuels, the food industry and biodiversity. Chapter 4: Overview of the relevant literature regarding the potential availability of biomass, the competition with the food sector and potential effects of increased use of biofuels on biodiversity. Chapter 5: Conclusions and recommendations for further studies, the script for further work. Chapter 6: Draft policy suggestions. A more extensive literature overview can be found in Annex A, the main actors in the biofuels land availability discussions are listed in Annex B. Annex C provides an overview of the global vegetable oil and oilseed markets.

Biofuel investment in Tanzania: Omissions in implementation

International Nuclear Information System (INIS)

Habib-Mintz, Nazia

2010-01-01

Increasing demand for biofuels as a component of climate change mitigation, energy security, and a fossil fuel alternative attracts investors to developing countries like Tanzania. Ample unused land is critical for first generation biofuels production and an important feature to attract foreign direct investments that can contribute towards agricultural modernization and poverty reduction initiatives. Despite the economic justifications, the existing institutional and infrastructural capacities dictate the impacts of biofuels market penetrations. Furthermore, exogenous factors like global recessionary pressure depressed oil prices below the level at which biofuel production were profitable in 2007, making Tanzania's competitiveness and potential benefits questionable. This paper investigates the extent that first generation, jatropha-based biofuels industry development in Tanzania observed during fieldwork in Kisarawe and Bahi may fulfill policy objectives. This paper argues that without strong regulatory frameworks for land, investment management, and rural development, biofuel industrialization could further exacerbate poverty and food insecurity in Tanzania. The paper concludes with policy recommendations for first generation biofuel development while keeping in mind implications of second generation production. Since the topic is broad and multifaceted, a multidisciplinary approach is used that includes political, institutional, and agricultural economics to analyze and conceptualize biofuel industry development and food security.

Vegetable oils as fuels and lubrificants: Commercialization problematics

International Nuclear Information System (INIS)

Bartolelli, V.

1992-01-01

The aim of this paper is to assess the commercialization feasibility of vegetable oils as industrial fuels and lubricants. The paper also discusses what should be the suitable mix of Italian Government agricultural, environmental and fiscal strategies to support and encourage the production and use of industrial vegetable fuel oils and lubricants. It points out the main advantages of bio-fuel oils - they are much less polluting than conventional fossil fuel oils and can be produced domestically, thus reducing national dependency on foreign energy imports and increasing employment opportunities. The major obstacle to their development is identified as being the creation of suitable pricing and fiscal policies in harmony with traditional energy markets

Preparation of Biofuel Using Acetylatation of Jojoba Fatty Alcohols and Assessment as a Blend Component in Ultra Low Sulfur Diesel Fuel

Science.gov (United States)

The majority of biodiesel fuels are produced from vegetable oils or animal fats by transesterification of oil with alcohol in the presence of a catalyst. In this study, a new class of biofuel is explored by acetylation of fatty alcohols from Jojoba oil. Recently, we reported Jojoba oil methyl este...

Assessing the environmental sustainability of biofuels.

Science.gov (United States)

Kazamia, Elena; Smith, Alison G

2014-10-01

Biofuels vary in their potential to reduce greenhouse gas emissions when displacing fossil fuels. Savings depend primarily on the crop used for biofuel production, and on the effect that expanding its cultivation has on land use. Evidence-based policies should be used to ensure that maximal sustainability benefits result from the development of biofuels. Copyright © 2014 Elsevier Ltd. All rights reserved.

Green Biorefinery of Giant Miscanthus for Growing Microalgae and Biofuel Production

Directory of Open Access Journals (Sweden)

Shuangning Xiu

2017-12-01

Full Text Available In this study, an innovative green biorefinery system was successfully developed to process the green biomass into multiple biofuels and bioproducts. In particular, fresh giant miscanthus was separated into a solid stream (press cake and a liquid stream (press juice using a screw press. The juice was used to cultivate microalga Chlorella vulgaris, which was further thermochemically converted via thermogravimetry analysis (TGA and pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS analysis, resulting in an approximately 80% conversion. In addition, the solid cake of miscanthus was pretreated with dilute sulfuric acid and used as the feedstock for bioethanol production. The results showed that the miscanthus juice could be a highly nutritious source for microalgae that are a promising feedstock for biofuels. The highest cell density was observed in the 15% juice medium. Sugars released from the miscanthus cake were efficiently fermented to ethanol using Saccharomyces cerevisiae through a simultaneous saccharification and fermentation (SSF process, with 88.4% of the theoretical yield.

POTENTIAL FOR LIQUID BIOFUEL PRODUCTION IN THE ...

African Journals Online (AJOL)

user

2013-02-27

Feb 27, 2013 ... production from agro-industrial waste in South Africa. Gikuru Mwithiga ... are produced in. South Africa, as well as the immediately economic effect is also discussed. ... Also, the average cost ... production industry that produces some if not all liquid ... capable of producing alcohol in the fermentation process.

Biofuels and sustainability in Africa

Energy Technology Data Exchange (ETDEWEB)

Amigun, Bamikole; Stafford, William [Sustainable Energy Futures, Natural Resources and the Environment, Council for Scientific and Industrial Research (CSIR), 7599 Stellenbosch (South Africa); Musango, Josephine Kaviti [Resource Based Sustainable Development, Natural Resources and the Environment, Council for Scientific and Industrial Research (CSIR), 7599 Stellenbosch (South Africa)

2011-02-15

The combined effects of climate change, the continued volatility of fuel prices, the recent food crisis and global economic turbulence have triggered a sense of urgency among policymakers, industries and development practitioners to find sustainable and viable solutions in the area of biofuels. This sense of urgency is reflected in the rapid expansion of global biofuels production and markets over the past few years. Biofuels development offers developing countries some prospect of self-reliant energy supplies at national and local levels, with potential economic, ecological, social, and security benefits. Forty-two African countries are net oil importers. This makes them particularly vulnerable to volatility in global fuel prices and dependent on foreign exchange to cover their domestic energy needs. The goal therefore is to reduce the high dependence on imported petroleum by developing domestic, renewable energy. But can this objective be achieved while leaving a minimal social and environmental footprint? A fundamental question is if biofuels can be produced with consideration of social, economic and environmental factors without setting unrealistic expectation for an evolving renewable energy industry that holds such great promise. The overall performance of different biofuels in reducing non-renewable energy use and greenhouse gas emissions varies when considering the entire lifecycle from production through to use. The net performance depends on the type of feedstock, the production process and the amount of non-renewable energy needed. This paper presents an overview of the development of biofuels in Africa, and highlights country-specific economic, environmental and social issues. It proposes a combination framework of policy incentives as a function of technology maturity, discusses practices, processes and technologies that can improve efficiency, lower energy and water demand, and further reduce the social and environmental footprint of biofuels

Biofuels and sustainability in Africa

International Nuclear Information System (INIS)

Amigun, Bamikole; Stafford, William; Musango, Josephine Kaviti

2011-01-01

The combined effects of climate change, the continued volatility of fuel prices, the recent food crisis and global economic turbulence have triggered a sense of urgency among policymakers, industries and development practitioners to find sustainable and viable solutions in the area of biofuels. This sense of urgency is reflected in the rapid expansion of global biofuels production and markets over the past few years. Biofuels development offers developing countries some prospect of self-reliant energy supplies at national and local levels, with potential economic, ecological, social, and security benefits. Forty-two African countries are net oil importers. This makes them particularly vulnerable to volatility in global fuel prices and dependent on foreign exchange to cover their domestic energy needs. The goal therefore is to reduce the high dependence on imported petroleum by developing domestic, renewable energy. But can this objective be achieved while leaving a minimal social and environmental footprint? A fundamental question is if biofuels can be produced with consideration of social, economic and environmental factors without setting unrealistic expectation for an evolving renewable energy industry that holds such great promise. The overall performance of different biofuels in reducing non-renewable energy use and greenhouse gas emissions varies when considering the entire lifecycle from production through to use. The net performance depends on the type of feedstock, the production process and the amount of non-renewable energy needed. This paper presents an overview of the development of biofuels in Africa, and highlights country-specific economic, environmental and social issues. It proposes a combination framework of policy incentives as a function of technology maturity, discusses practices, processes and technologies that can improve efficiency, lower energy and water demand, and further reduce the social and environmental footprint of biofuels

International Trade of Biofuels (Brochure)

Energy Technology Data Exchange (ETDEWEB)

2013-05-01

In recent years, the production and trade of biofuels has increased to meet global demand for renewable fuels. Ethanol and biodiesel contribute much of this trade because they are the most established biofuels. Their growth has been aided through a variety of policies, especially in the European Union, Brazil, and the United States, but ethanol trade and production have faced more targeted policies and tariffs than biodiesel. This fact sheet contains a summary of the trade of biofuels among nations, including historical data on production, consumption, and trade.

Sustainability of biofuels in Latin America: Risks and opportunities

Energy Technology Data Exchange (ETDEWEB)

Janssen, Rainer, E-mail: rainer.janssen@wip-munich.de [WIP Renewable Energies, Sylvensteinstrasse 2, 81369 Munich (Germany); Rutz, Dominik Damian [WIP Renewable Energies, Sylvensteinstrasse 2, 81369 Munich (Germany)

2011-10-15

Several Latin American countries are setting up biofuel programmes to establish alternative markets for agricultural commodities. This is mainly triggered by the current success of Brazilian bioethanol production for the domestic market and for export. Furthermore, the global biofuel market is expected to increase due to ambitious biofuel programmes in the EU and in the USA. Colombia, Venezuela, Costa Rica and Guatemala are focusing on bioethanol production from sugarcane whereas biofuel production in Argentina is based on soy biodiesel. Recent developments of the biofuel sector take place extremely rapid especially in Argentina, which became one of the five largest biodiesel producers in the world in 2008. Till date no specific biofuel sustainability certification systems have been implemented in Latin American, as well as on global level. This fact and the predominant use of food crops for biofuel production raise concerns about the sustainability of biofuel production related to environmental and social aspects. This paper provides an overview of the hotspots of conflicts in biofuel production in Latin America. It investigates presently available sustainability tools and initiatives to ensure sustainable biofuel production in Latin America. Finally, it provides an outlook on how to integrate sustainability in the Latin American biofuel sector. - Research Highlights: > This study investigates risks and opportunities of biofuels in Latin America. > Latin American countries are setting up programmes to promote biofuel development. > Strong biofuel sectors provide opportunities for economic development. > Potential negative impact includes deforestation and effects on food security. > Sustainability initiatives exist to minimise negative impact.

Sustainability of biofuels in Latin America: Risks and opportunities

International Nuclear Information System (INIS)

Janssen, Rainer; Rutz, Dominik Damian

2011-01-01

Several Latin American countries are setting up biofuel programmes to establish alternative markets for agricultural commodities. This is mainly triggered by the current success of Brazilian bioethanol production for the domestic market and for export. Furthermore, the global biofuel market is expected to increase due to ambitious biofuel programmes in the EU and in the USA. Colombia, Venezuela, Costa Rica and Guatemala are focusing on bioethanol production from sugarcane whereas biofuel production in Argentina is based on soy biodiesel. Recent developments of the biofuel sector take place extremely rapid especially in Argentina, which became one of the five largest biodiesel producers in the world in 2008. Till date no specific biofuel sustainability certification systems have been implemented in Latin American, as well as on global level. This fact and the predominant use of food crops for biofuel production raise concerns about the sustainability of biofuel production related to environmental and social aspects. This paper provides an overview of the hotspots of conflicts in biofuel production in Latin America. It investigates presently available sustainability tools and initiatives to ensure sustainable biofuel production in Latin America. Finally, it provides an outlook on how to integrate sustainability in the Latin American biofuel sector. - Research Highlights: → This study investigates risks and opportunities of biofuels in Latin America. → Latin American countries are setting up programmes to promote biofuel development. → Strong biofuel sectors provide opportunities for economic development. → Potential negative impact includes deforestation and effects on food security. → Sustainability initiatives exist to minimise negative impact.

Upgrading pyrolysis bio-oil to biofuel over bifunctional Co-Zn/HZSM-5 catalyst in supercritical methanol

International Nuclear Information System (INIS)

Cheng, Shouyun; Wei, Lin; Julson, James; Muthukumarappan, Kasiviswanathan; Kharel, Parashu Ram

2017-01-01

Highlights: • Integration of Co-Zn/HZSM-5 and supercritical methanol was used for bio-oil hydrodeoxygenation. • Co-Zn/HZSM-5 exhibited higher effectiveness than Co/HZSM-5 or Zn/HZSM-5. • 15%Co5%Zn/HZSM-5 produced biofuel with the highest hydrocarbons content at 35.33%. • Loading of Co and/or Zn did not change crystalline structure of HZSM-5. • Hydrogenation and esterification are main reactions in bio-oil hydrodeoxygenation. - Abstract: The role of catalyst is essential in processes of upgrading biomass pyrolysis bio-oil into hydrocarbon biofuel. While the majority of heterogeneous catalytic processes are conducted in the presence of gas (nearly ideal) or liquid phase, a growing number of processes are utilizing supercritical fluids (SCFs) as reaction media. Although hydrodeoxygenation (HDO) is proven a promising process for pyrolysis bio-oil upgrading to hydrocarbon biofuel, catalyst efficiency remains a challenge. Integrating heterogeneous catalysts with SCFs in a bio-oil HDO process was investigated in this study. Bifunctional Co-Zn/HZSM-5 catalysts were firstly used to upgrade bio-oil to biofuel in supercritical methanol. The loading of Co and Zn did not change HZSM-5 crystalline structure. Physicochemical properties of biofuel produced by Co and/or Zn loaded HZSM-5 catalysts such as water content, total acid number, viscosity and higher heating value improved. Bimetallic Co-Zn/HZSM-5 catalysts showed enhanced reactions of decarboxylation and decarbonylation that resulted in higher yields of CO and CO 2 . Bimetallic Co-Zn/HZSM-5 catalysts were more effective for bio-oil HDO than monometallic Co/HZSM-5 or Zn/HZSM-5 catalyst , which was attributed to the synergistic effect of Co and Zn on HZSM-5 support. Bimetallic Co-Zn/HZSM-5 catalysts increased biofuel yields and hydrocarbons contents in biofuels in comparison with monometallic Co/HZSM-5 and Zn/HZSM-5 catalysts. 5%Co15%Zn/HZSM-5 catalyst generated the highest biofuel yield at 22.13 wt.%, and 15%Co5

Modifying plants for biofuel and biomaterial production.

Science.gov (United States)

Furtado, Agnelo; Lupoi, Jason S; Hoang, Nam V; Healey, Adam; Singh, Seema; Simmons, Blake A; Henry, Robert J

2014-12-01

The productivity of plants as biofuel or biomaterial crops is established by both the yield of plant biomass per unit area of land and the efficiency of conversion of the biomass to biofuel. Higher yielding biofuel crops with increased conversion efficiencies allow production on a smaller land footprint minimizing competition with agriculture for food production and biodiversity conservation. Plants have traditionally been domesticated for food, fibre and feed applications. However, utilization for biofuels may require the breeding of novel phenotypes, or new species entirely. Genomics approaches support genetic selection strategies to deliver significant genetic improvement of plants as sources of biomass for biofuel manufacture. Genetic modification of plants provides a further range of options for improving the composition of biomass and for plant modifications to assist the fabrication of biofuels. The relative carbohydrate and lignin content influences the deconstruction of plant cell walls to biofuels. Key options for facilitating the deconstruction leading to higher monomeric sugar release from plants include increasing cellulose content, reducing cellulose crystallinity, and/or altering the amount or composition of noncellulosic polysaccharides or lignin. Modification of chemical linkages within and between these biomass components may improve the ease of deconstruction. Expression of enzymes in the plant may provide a cost-effective option for biochemical conversion to biofuel. © 2014 Society for Experimental Biology, Association of Applied Biologists and John Wiley & Sons Ltd.

Innovative technological paradigm-based approach towards biofuel feedstock

International Nuclear Information System (INIS)

Xu, Jiuping; Li, Meihui

2017-01-01

Highlights: • DAS was developed through an innovative approach towards literature mining and technological paradigm theory. • A novel concept of biofuel feedstock development paradigm (BFDP) is proposed. • The biofuel production diffusion velocity model gives predictions for the future. • Soft path appears to be the driving force for the new paradigm shift. • An integrated biofuel production feedstock system is expected to play a significant role in a low-carbon sustainable future. - Abstract: Biofuels produced from renewable energy biomass are playing a more significant role because of the environmental problems resulting from the use of fossil fuels. However, a major problem with biofuel production is that despite the range of feedstock that can be used, raw material availability varies considerably. By combining a series of theories and methods, the research objective of this study is to determine the current developments and the future trends in biofuel feedstock. By combining technological paradigm theory with literature mining, it was found that biofuel feedstock production development followed a three-stage trajectory, which was in accordance with the traditional technological paradigm – the S-curve. This new curve can be divided into BFDP (biofuel feedstock development paradigm) competition, BFDP diffusion, and BFDP shift. The biofuel production diffusion velocity model showed that there has been constant growth from 2000, with the growth rate reaching a peak in 2008, after which time it began to drop. Biofuel production worldwide is expected to remain unchanged until 2030 when a paradigm shift is expected. This study also illustrates the results of our innovative procedure – a combination of the data analysis system and the technological paradigm theory – for the present biofuel feedstock soft path that will lead to this paradigm shift, with integrated biofuel production feedstock systems expected to be a significant new trend.

Socio-economic aspects of different biofuel development pathways

International Nuclear Information System (INIS)

Duer, Henrik; Christensen, Pernille Ovre

2010-01-01

There are several policy drivers for biofuels on a larger scale in the EU transport sector, including increased security of energy supply, reduced emission of greenhouse gases (GHG), and new markets for the agricultural sector. The purpose of this socio-economic cost analysis is to provide an overview of the costs of meeting EU biofuels targets, taking into account several external costs and benefits. Biofuels are generally more expensive than traditional fossil fuels, but the expected increasing value of GHG emission reductions will over time reduce the cost gap. High crude oil prices significantly improve the economic benefit of biofuels, but increased demand for biomass for energy purposes is likely to increase the price of biofuels feedstock and biofuels costs. The key question is to what extent increasing oil prices will be passed on to biofuels costs. Socio-economic least costs for biofuels production require a market with a clear pricing of GHG emissions to ensure that this factor is included in the decision-making of actors in all links of the fuel chain.

Biofuels - Illusion or Reality? - The european experience

International Nuclear Information System (INIS)

Furfari, A.

2008-01-01

Environmental issues, rising prices and security of supply are putting energy at the centre of all attentions. Policy-makers pushed by various stakeholders are struggling to find more sustainable solutions to the world legitimate demand for energy. The transport sector is especially under pressure as it relies for 98% on oil. Despite vast research and development investments, no short-term solutions appeared to be reliable. Thanks to lawmakers support to biofuels, these substitutes for oil are now seen as the potential solution for a sustainable transport. This book analyses the real possibility of biofuels. Does Europe has enough land to produce the needed feedstock? What are the real gains in terms of greenhouse gases emissions and energy efficiency? Are biofuels really a sustainable solution? Will this policy succeed? Are the targets reachable? The reader will find some indications in this book to make up his mind on this complex, multifaceted and highly political subject. Contents: Summary. Introduction. Biofuels in the U.S.A. and Brazil. Do we have enough land in Europe? Biofuels life cycle analysis. Greenhouse gases reduction and efficiency. Case of the glycerin price. Variables affecting biofuels sustainability. Standard for Biofuels. Conclusion. General Bibliography. Annexes. References

Biofuels – On the way to sustainability?: Opinion

Directory of Open Access Journals (Sweden)

Martin Kaltschmitt

2016-12-01

Full Text Available Biofuels contribute to cover the strongly increasing energy demand within our global transportation system. The current status of biofuel production can be summarized on a world wide scale as follows [1, 2]: Biofuels contribute to cover the strongly increasing energy demand within our global transportation system. The current status of biofuel production can be summarized on a world wide scale as follows [1, 2]:Bioethanol. About 97 Billion l of ethanol (2,218 PJ were produced in 2015. Roughly 57 % were provided in the US (56.1 Billion l; 1,282 PJ; primarily from corn and 28 % in Brazil (26.8 Billion l; 614 PJ; mainly from sugar cane. The remaining 15 % were produced in Europe and Asia.Biodiesel / HVO. In 2015, ca. 32 Billion l (1,050 PJ Biodiesel were sold. Brazil provided ca. 3.5 Billion l (116 PJ and Germany roughly 3.2 Billion l (105 PJ. The market in North America is dominated by the US with 16 % of the global production (168 PJ. The remaining rest is widely distributed throughout the world and comes from smaller markets like Argentine, Germany, Indonesia and other countries.Other biofuels. To a very minor extend, also bio-methane as well as pure vegetable oil are used. But on a global scale the contribution of these options is negligible.Related to the overall energy demand for transportation purposes this biofuel use of roughly 3.3 EJ (2015 represents a share of less than 3 % [3]. This small share could only be realized over time due to administrative measures implemented by various governments already years ago. There have been manifold communicated reasons to justify these legal measures as well as the resulting financial support from the public purse [4]:Contribution to the reduction of greenhouse gas (GHG emissions;Protection of scarce and finite fossil fuel resources;Domestic energy provision and thus an increased security of fuel supply;Use of agricultural surplus production and thus avoidance of set aside land;Creation of employment

Which future for aviation bio-fuels?

International Nuclear Information System (INIS)

Botti, Jean; Combarnous, Michel; Jarry, Bruno; Monsan, Pierre; Burzynski, Jean-Pierre; Jeuland, Nicolas; Porot, Pierre; Demoment, Pascale; Gillmann, Marc; Marchand, Philippe; Kuentzmann, Paul; Kurtsoglou, Nicolas; Lombaert-Valot, Isabelle; Pelegrin, Marc; Renvier, Jacques; Rousseau, Julien; Stadler, Thierry; Tremeau, Benoit

2014-01-01

This collective report proposes a detailed overview of the evolution of aviation fuels and bio-fuels from technological, regulatory and economic points of view. It also proposes a road-map for possible future evolutions, and outlines the different assessments between American and European countries regarding the predictions for the beginning of industrial production and use of bio-jet-fuel. After having recalled international objectives, an overview of European and French commitments for technological and operational advances, and a discussion of the role of bio-fuels in the carbon cycle, the report presents various technical constraints met in aircraft industry and describes the role bio-fuels may have. The next part proposes an overview of bio-fuels which are industrially produced in the world in 2013. The authors then focus on aviation bio-fuels (main production processes, thermo-chemical processes), discuss the political context, and examine obstacles, partnerships and the role of public authorities

How policies affect international biofuel price linkages

International Nuclear Information System (INIS)

Rajcaniova, Miroslava; Drabik, Dusan; Ciaian, Pavel

2013-01-01

We estimate the role of biofuel policies in determining which country is the price leader in world biofuel markets using a cointegration analysis and a Vector Error Correction (VEC) model. Weekly prices are analyzed for the EU, US, and Brazilian ethanol and biodiesel markets in the 2002–2010 and 2005–2010 time periods, respectively. The US blender's tax credit and Brazil's consumer tax exemption are found to play a role in determining the ethanol prices in other countries. For biodiesel, our results demonstrate that EU policies – the consumer tax exemption and blending target – tend to determine the world biodiesel price. - Highlights: • We estimate the role of biofuel policies in determining biofuel prices. • We use a cointegration analysis and the Vector Error Correction (VEC) model. • The biofuel policies in US and Brazil determine the world ethanol prices. • EU biofuel policies tend to form the world biodiesel price

Frames in the Ethiopian Debate on Biofuels

Directory of Open Access Journals (Sweden)

Brigitte Portner

2013-01-01

Full Text Available Biofuel production, while highly contested, is supported by a number of policies worldwide. Ethiopia was among the first sub-Saharan countries to devise a biofuel policy strategy to guide the associated demand toward sustainable development. In this paper, I discuss Ethiopia’s biofuel policy from an interpretative research position using a frames approach and argue that useful insights can be obtained by paying more attention to national contexts and values represented in the debates on whether biofuel production can or will contribute to sustainable development. To this end, I was able to distinguish three major frames used in the Ethiopian debate on biofuels: an environmental rehabilitation frame, a green revolution frame and a legitimacy frame. The article concludes that actors advocating for frames related to social and human issues have difficulties entering the debate and forming alliances, and that those voices need to be included in order for Ethiopia to develop a sustainable biofuel sector.

Recent Inventions and Trends in Algal Biofuels Research.

Science.gov (United States)

Karemore, Ankush; Nayak, Manoranjan; Sen, Ramkrishna

2016-01-01

In recent times, when energy crisis compounded by global warming and climate change is receiving worldwide attention, the emergence of algae, as a better feedstock for third-generation biofuels than energy crops or plants, holds great promise. As compared to conventional biofuels feedstocks, algae offer several advantages and can alone produce a significant amount of biofuels sustainably in a shorter period to fulfill the rising demand for energy. Towards commercialisation, there have been numerous efforts put for- ward for the development of algae-derived biofuel. This article reviews and summarizes the recent inventions and the current trends that are reported and captured in relevant patents pertaining to the novel methods of algae biomass cultivation and processing for biofuels and value-added products. In addition, the recent advancement in techniques and technologies for microalgal biofuel production has been highlighted. Various steps involved in the production of algal biofuels have been considered in this article. Moreover, the work that advances to improve the efficiency and cost-effectiveness of the processes for the manufacture of biofuels has been presented. Our survey was conducted in the patent databases: WIPO, Spacenet and USPTO. There are still some technological bottlenecks that could be overcome by designing advanced photobioreactor and raceway ponds, developing new and low cost technologies for biomass cultivation, harvesting, drying and extraction. Recent advancement in algae biofuels methods is directed toward developing efficient and integrated systems to produce biofuels by overcoming the current challenges. However, further research effort is required to scale-up and improve the efficiency of these methods in the upstream and downstream technologies to make the cost of biofuels competitive with petroleum fuels.

Coupling of Algal Biofuel Production with Wastewater

Directory of Open Access Journals (Sweden)

Neha Chamoli Bhatt

2014-01-01

Full Text Available Microalgae have gained enormous consideration from scientific community worldwide emerging as a viable feedstock for a renewable energy source virtually being carbon neutral, high lipid content, and comparatively more advantageous to other sources of biofuels. Although microalgae are seen as a valuable source in majority part of the world for production of biofuels and bioproducts, still they are unable to accomplish sustainable large-scale algal biofuel production. Wastewater has organic and inorganic supplements required for algal growth. The coupling of microalgae with wastewater is an effective way of waste remediation and a cost-effective microalgal biofuel production. In this review article, we will primarily discuss the possibilities and current scenario regarding coupling of microalgal cultivation with biofuel production emphasizing recent progress in this area.

Renewable energy from vegetation; Les energies renouvelables d'origine vegetale

Energy Technology Data Exchange (ETDEWEB)

Sales, C. [Centre francais de cooperation international en recherche agronomique pour le developpement (France)

2009-07-15

Currently, vegetation accounts for 3 major types of energy sources, notably woody biomass, starches and vegetable oils. Bio-ethanol and biodiesel is produced from the fermentation of starches, such as sugar cane, beet sugar, sorghum, corn and potatoes. Biofuels can be produced from palm tree oil, coconut oil , soya oil, sunflower oil or any type of vegetable based oil. This article discussed energy efficiency issues and the environmental impact of developing these energies. In general, the lower energy efficiency of the starches can be attributed to the enzymes responsible for the catalysis. The article also reviewed the thermochemistry and energy efficiency regarding second generation fuels. It also discussed the burning of biomass, including woody biomass, forest waste and agricultural waste. 1 ref., 2 figs.

The biofuels, situation, perspectives

International Nuclear Information System (INIS)

Acket, C.

2007-03-01

The climatic change with the fight against the greenhouse effect gases, sees the development of ''clean'' energy sources. Meanwhile the biofuels remain penalized by their high production cost, the interest is increasing. Facing their development ecologists highlight the environmental and social negative impacts of the development of the biofuels. The author aims to take stock on the techniques and the utilizations. (A.L.B.)

The effect of native and introduced biofuel crops on the composition of soil biota communities

Science.gov (United States)

Frouz, Jan; Hedenec, Petr

2016-04-01

Biofuel crops are an accepted alternative to fossil fuels, but little is known about the ecological impact of their production. The aim of this contribution is to study the effect of native (Salix viminalis and Phalaris arundinacea) and introduced (Helianthus tuberosus, Reynoutria sachalinensis and Silphium perfoliatum) biofuel crop plantations on the soil biota in comparison with cultural meadow vegetation used as control. The study was performed as part of a split plot field experiment of the Crop Research Institute in the city of Chomutov (Czech Republic). The composition of the soil meso- and macrofauna community, composition of the cultivable fraction of the soil fungal community, cellulose decomposition (using litter bags), microbial biomass, basal soil respiration and PLFA composition (incl. F/B ratio) were studied in each site. The C:N ratio and content of polyphenols differed among plant species, but these results could not be considered significant between introduced and native plant species. Abundance of the soil meso- and macrofauna was higher in field sites planted with S. viminalis and P. arundinacea than those planted with S. perfoliatum, H. tuberosus and R. sachalinensis. RDA and Monte Carlo Permutation Test showed that the composition of the faunal community differed significantly between various native and introduced plants. Significantly different basal soil respiration was found in sites planted with various energy crops; however, this difference was not significant between native and introduced species. Microbial biomass carbon and cellulose decomposition did not exhibit any statistical differences among the biofuel crops. The largest statistically significant difference we found was in the content of actinobacterial and bacterial (bacteria, G+ bacteria and G- bacteria) PLFA in sites overgrown by P. arundinacea compared to introduced as well as native biofuel crops. In conclusion, certain parameters significantly differ between various native

DLA Energy Biofuel Feedstock Metrics Study

Science.gov (United States)

2012-12-11

moderately/highly in- vasive  Metric 2: Genetically modified organism ( GMO ) hazard, Yes/No and Hazard Category  Metric 3: Species hybridization...4– biofuel distribution Stage # 5– biofuel use Metric 1: State inva- siveness ranking Yes Minimal Minimal No No Metric 2: GMO hazard Yes...may utilize GMO microbial or microalgae species across the applicable biofuel life cycles (stages 1–3). The following consequence Metrics 4–6 then

Biofuels Program Plan, FY 1992--FY 1996. Executive summary

Energy Technology Data Exchange (ETDEWEB)

1993-01-01

This five-year program plan describes the goals and philosophy of the US Department of Energy`s (DOE) Biofuels Systems Division (BSD) program and the BSD`s major research and development (R&D) activities for fiscal years (FY) 1992 through 1996. The plan represents a consensus among government and university researchers, fuel and automotive manufacturers, and current and potential users of alternative fuels and fuel additives produced from biomass. It defines the activities that are necessary to produce versatile, domestic, economical, renewable liquid fuels from biomass feedstocks. The BSD program focuses on the production of alternative liquid fuels for transportation-fuels such as ethanol, methanol, biodiesel, and fuel additives for reformulated gasoline. These fuels can be produced from many plant materials and from a significant portion of the wastes generated by municipalities and industry. Together these raw materials and wastes, or feedstocks, are called biomass.

Lessons from first generation biofuels and implications for the sustainability appraisal of second generation biofuels

International Nuclear Information System (INIS)

Mohr, Alison; Raman, Sujatha

2013-01-01

Aims: The emergence of second generation (2G) biofuels is widely seen as a sustainable response to the increasing controversy surrounding the first generation (1G). Yet, sustainability credentials of 2G biofuels are also being questioned. Drawing on work in Science and Technology Studies, we argue that controversies help focus attention on key, often value-related questions that need to be posed to address broader societal concerns. This paper examines lessons drawn from the 1G controversy to assess implications for the sustainability appraisal of 2G biofuels. Scope: We present an overview of key 1G sustainability challenges, assess their relevance for 2G, and highlight the challenges for policy in managing the transition. We address limitations of existing sustainability assessments by exploring where challenges might emerge across the whole system of bioenergy and the wider context of the social system in which bioenergy research and policy are done. Conclusions: Key lessons arising from 1G are potentially relevant to the sustainability appraisal of 2G biofuels depending on the particular circumstances or conditions under which 2G is introduced. We conclude that sustainability challenges commonly categorised as either economic, environmental or social are, in reality, more complexly interconnected (so that an artificial separation of these categories is problematic). - Highlights: • Controversy surrounding 1G biofuels is relevant to sustainability appraisal of 2G. • Challenges for policy in managing the transition to 2G biofuels are highlighted. • A key lesson is that sustainability challenges are complexly interconnected

Integrated biofuels process synthesis

DEFF Research Database (Denmark)

Torres-Ortega, Carlo Edgar; Rong, Ben-Guang

2017-01-01

Second and third generation bioethanol and biodiesel are more environmentally friendly fuels than gasoline and petrodiesel, andmore sustainable than first generation biofuels. However, their production processes are more complex and more expensive. In this chapter, we describe a two-stage synthesis......% used for bioethanol process), and steam and electricity from combustion (54%used as electricity) in the bioethanol and biodiesel processes. In the second stage, we saved about 5% in equipment costs and 12% in utility costs for bioethanol separation. This dual synthesis methodology, consisting of a top......-level screening task followed by a down-level intensification task, proved to be an efficient methodology for integrated biofuel process synthesis. The case study illustrates and provides important insights into the optimal synthesis and intensification of biofuel production processes with the proposed synthesis...

From biomass to sustainable biofuels in southern Africa

Energy Technology Data Exchange (ETDEWEB)

Van Zyl, W.H.; Den Haan, R.; Rose, S.H.; La Grange, D.C.; Bloom, M. [Stellenbosch Univ., Matieland (South Africa). Dept. of Microbiology; Gorgens, J.F.; Knoetze, J.H. [Stellenbosch Univ., Matieland (South Africa). Dept. of Process Engineering; Von Blottnitz, H. [Cape Town Univ., Rondebosch (South Africa). Dept. of Chemical Engineering

2009-07-01

This presentation reported on a global sustainable bioenergy project with particular reference to South Africa's strategy to develop biofuels. The current biofuel production in South Africa was presented along with the potential for biofuels production and other clean alternative fuels. The South African industrial biofuel strategy (IBS) was developed in 2007 with a mandate to create jobs in the energy-crop and biofuels value chain; attract investment into rural areas; promote agricultural development; and reduce the import of foreign oil. The proposed crops for bioethanol include sugar cane and sugar beet, while the proposed crops for biodiesel include sunflower, canola and soya beans. The exclusion of maize was based on food security concerns. Jatropha curcas was also excluded because it is considered to be an invasive species. In addition to environmental benefits, the production of biofuels from biomass in Africa offers improved energy security, economic development and social upliftment. All biofuel projects are evaluated to ensure that these benefits are realized. Although first generation technologies do not score well due to marginal energy balance, negative life cycle impacts or detriment to biodiversity, the conversion of lignocellulosic biomass scores well in terms of enabling the commercialization of second generation biofuels. This paper discussed both the biochemical and thermochemical technological interventions needed to develop commercially-viable second generation lignocellulose conversion technologies to biofuels. tabs., figs.

Indirect land use change and biofuel policy

International Nuclear Information System (INIS)

Kocoloski, Matthew; Griffin, W Michael; Matthews, H Scott

2009-01-01

Biofuel debates often focus heavily on carbon emissions, with parties arguing for (or against) biofuels solely on the basis of whether the greenhouse gas emissions of biofuels are less than (or greater than) those of gasoline. Recent studies argue that land use change leads to significant greenhouse gas emissions, making some biofuels more carbon intensive than gasoline. We argue that evaluating the suitability and utility of biofuels or any alternative energy source within the limited framework of plus and minus carbon emissions is too narrow an approach. Biofuels have numerous impacts, and policy makers should seek compromises rather than relying solely on carbon emissions to determine policy. Here, we estimate that cellulosic ethanol, despite having potentially higher life cycle CO 2 emissions (including from land use) than gasoline, would still be cost-effective at a CO 2 price of $80 per ton or less, well above estimated CO 2 mitigation costs for many alternatives. As an example of the broader approach to biofuel policy, we suggest the possibility of using the potential cost reductions of cellulosic ethanol relative to gasoline to balance out additional carbon emissions resulting from indirect land use change as an example of ways in which policies could be used to arrive at workable solutions.

Indirect land use change and biofuel policy

Science.gov (United States)

Kocoloski, Matthew; Griffin, W. Michael; Matthews, H. Scott

2009-09-01

Biofuel debates often focus heavily on carbon emissions, with parties arguing for (or against) biofuels solely on the basis of whether the greenhouse gas emissions of biofuels are less than (or greater than) those of gasoline. Recent studies argue that land use change leads to significant greenhouse gas emissions, making some biofuels more carbon intensive than gasoline. We argue that evaluating the suitability and utility of biofuels or any alternative energy source within the limited framework of plus and minus carbon emissions is too narrow an approach. Biofuels have numerous impacts, and policy makers should seek compromises rather than relying solely on carbon emissions to determine policy. Here, we estimate that cellulosic ethanol, despite having potentially higher life cycle CO2 emissions (including from land use) than gasoline, would still be cost-effective at a CO2 price of 80 per ton or less, well above estimated CO2 mitigation costs for many alternatives. As an example of the broader approach to biofuel policy, we suggest the possibility of using the potential cost reductions of cellulosic ethanol relative to gasoline to balance out additional carbon emissions resulting from indirect land use change as an example of ways in which policies could be used to arrive at workable solutions.

Opportunity for profitable investments in cellulosic biofuels

International Nuclear Information System (INIS)

Babcock, Bruce A.; Marette, Stephan; Treguer, David

2011-01-01

Research efforts to allow large-scale conversion of cellulose into biofuels are being undertaken in the US and EU. These efforts are designed to increase logistic and conversion efficiencies, enhancing the economic competitiveness of cellulosic biofuels. However, not enough attention has been paid to the future market conditions for cellulosic biofuels, which will determine whether the necessary private investment will be available to allow a cellulosic biofuels industry to emerge. We examine the future market for cellulosic biofuels, differentiating between cellulosic ethanol and 'drop-in' cellulosic biofuels that can be transported with petroleum fuels and have equivalent energy values. We show that emergence of a cellulosic ethanol industry is unlikely without costly government subsidies, in part because of strong competition from conventional ethanol and limits on ethanol blending. If production costs of drop-in cellulosic biofuels fall enough to become competitive, then their expansion will not necessarily cause feedstock prices to rise. As long as local supplies of feedstocks that have no or low-valued alternative uses exist, then expansion will not cause prices to rise significantly. If cellulosic feedstocks come from dedicated biomass crops, then the supply curves will have a steeper slope because of competition for land. (author)

Controllable production of liquid and solid biofuels by doping-free, microwave-assisted, pressurised pyrolysis of hemicellulose

International Nuclear Information System (INIS)

Li, T.; Remón, J.; Shuttleworth, P.S.; Jiang, Z.; Fan, J.; Clark, J.H.; Budarin, V.L.

2017-01-01

Highlights: • Microwave pyrolysis of xylan in the absence of any external microwave absorber. • High energy-efficient and controllable production of biochar and bio-oil from xylan. • Water in liquid phase is needed for fast microwave pyrolysis. • Production of bio-oil and bio-char with HHVs 52% and 19% greater than that of xylan. - Abstract: Batch, pressurised microwave-assisted pyrolysis of hemicellulose in the absence of any external microwave absorber was found to be a promising route for the production of bio-based chemicals and biofuels. The experiments were conducted in a 10 mL batch reactor using a fixed power of 200 W employing different initial masses of xylan (0.1–0.7 g) for a maximum time, temperature and pressure of 10 min, 250 °C and 200 psi, respectively. The gas, bio-oil and solid (char) yields varied by 16–40%, 2–21% and 40–82%, respectively. Char production is preferential using a low amount of xylan (<0.25 g), while bio-oil production is favoured using a high amount of xylan (0.25–0.7 g). The effect of the sample mass is accounted for by the different physical state of the volatiles released during pyrolysis depending on the pressure attained during the experiment. This permits the process to be easily customised for the selective production of liquid (bio-oil) or solid (bio-char). Regarding the bio-oil, it is composed of a mixture of platform chemicals such as aldehydes, alkenes, phenols, polyaromatic hydrocarbons (PAHC), cyclic ketones and furans, with the composition varying depending on the initial mass of xylan. The char had a higher proportion of C together with a lower proportion of O than the original feedstock. Energy efficiencies of 100 and 26% were achieved for char and bio-oil production, respectively; thus leading to an increase in the HHV of the products (with respect to the original feedstock) of 52% for char and 19% for bio-oil.

Contrasts and synergies in different biofuel reports.

Science.gov (United States)

Michalopoulos, A; Landeweerd, L; Van der Werf-Kulichova, Z; Puylaert, P G B; Osseweijer, P

2011-04-06

The societal debate on biofuels is characterised by increased complexity. This can hinder the effective governance of the field. This paper attempts a quantitative bird's eye meta-analysis of this complexity by mapping different stakeholder perspectives and expected outcomes as seen in the secondary literature on biofuels, along the lines of the People-Planet-Profit framework. Our analysis illustrates the tension between stated and actual drivers of large scale biofuel development, especially for first generation biofuels. Although environmental (Planet) aspects have dominated the biofuel debate, their overall assessment is mostly negative with regard to first generation biofuels. By contrast, economic (Profit) aspects are the only ones that are assessed positively with regard to first generation biofuels. Furthermore, positive and negative assessments of biofuel development are strongly influenced by the differences in focus between different stakeholder clusters. Stakeholders who appear generally supportive to biofuel development (industry) focus relatively more on aspects that are generally assessed as positive (Profit). By contrast, non-supportive stakeholders (NGO's) tend to focus mainly on aspects that are generally assessed as negative (Planet). Moreover, our analysis of reference lists revealed few citations of primary scientific data, and also that intergovernmental organizations produce the most influential publications in the debate. The surprising lack of listed references to scientific (primary) data reveals a need to assess in which arena the transition of scientific data towards secondary publications takes place, and how one can measure its quality. This work should be understood as a first effort to take some control over a complex and contradictory number of publications, and to allow the effective governance of the field through the identification of areas of overlapping consensus and persisting controversy, without reverting to claims on

Overview on Biofuels from a European Perspective

Science.gov (United States)

Ponti, Luigi; Gutierrez, Andrew Paul

2009-01-01

In light of the recently developed European Union (EU) Biofuels Strategy, the literature is reviewed to examine (a) the coherency of biofuel production with the EU nonindustrial vision of agriculture, and (b) given its insufficient land base, the implications of a proposed bioenergy pact to grow biofuel crops in the developing world to meet EU…

Hybrid-renewable processes for biofuels production: concentrated solar pyrolysis of biomass residues

Energy Technology Data Exchange (ETDEWEB)

George, Anthe [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Geier, Manfred [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Dedrick, Daniel E. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

2014-10-01

The viability of thermochemically-derived biofuels can be greatly enhanced by reducing the process parasitic energy loads. Integrating renewable power into biofuels production is one method by which these efficiency drains can be eliminated. There are a variety of such potentially viable "hybrid-renewable" approaches; one is to integrate concentrated solar power (CSP) to power biomass-to-liquid fuels (BTL) processes. Barriers to CSP integration into BTL processes are predominantly the lack of fundamental kinetic and mass transport data to enable appropriate systems analysis and reactor design. A novel design for the reactor has been created that can allow biomass particles to be suspended in a flow gas, and be irradiated with a simulated solar flux. Pyrolysis conditions were investigated and a comparison between solar and non-solar biomass pyrolysis was conducted in terms of product distributions and pyrolysis oil quality. A novel method was developed to analyse pyrolysis products, and investigate their stability.

Economy-wide impacts of biofuels in Argentina

International Nuclear Information System (INIS)

Timilsina, Govinda R.; Chisari, Omar O.; Romero, Carlos A.

2013-01-01

Argentina is one of the world's largest biodiesel producers and the largest exporter, using soybeans as feedstock. Using a computable general equilibrium model that explicitly represents the biofuel industry, this study carries out several simulations on two sets of issues: (i) international markets for biofuel and feedstock, such as an increase in prices of soybean, soybean oil, and biodiesel, and (ii) domestic policies related to biofuels, such as an introduction of biofuel mandates. Both sets of issues can have important consequences to the Argentinean economy. The simulations indicate that increases in international prices of biofuels and feedstocks would increase Argentina's gross domestic product and social welfare. Increases in international prices of ethanol and corn also can benefit Argentina, but to a lesser extent. The domestic mandates for biofuels, however, would cause small losses in economic output and social welfare because they divert part of biodiesel and feedstock from exports to lower-return domestic consumption. An increase in the export tax on either feedstock or biodiesel also would lead to a reduction in gross domestic product and social welfare, although government revenue would rise. - Highlights: ► Argentina is one of the largest biodiesel producer and exporter using soybeans. ► Economy-wide impacts are assessed using a CGE model for Argentina. ► Policies simulated are feedstock and biodiesel price change, and domestic mandates. ► Increases in international prices of biofuels and feedstock benefit the country. ► Domestic mandates for biofuels cause small losses in economic output

Status of advanced biofuels demonstration facilities in 2012. A report to IEA Bioenergy task 39

Energy Technology Data Exchange (ETDEWEB)

Bacovsky, Dina; Ludwiczek, Nikolaus; Ognissanto, Monica; Woergetter, Manfred

2013-03-18

A number of companies around the world pursue projects to develop and deploy advanced technologies for the production of biofuels. Plenty of options are available, e.g. on which feedstock to use, how to pretreat it and how to convert it, up to which fuel to produce. This report monitors the multi-facetted development, adds transparency to the sector and thus supports the development and deployment of advanced biofuels production technologies. Main pathways under development can be classified into biochemical technologies, thermochemical technologies and chemical technologies. Biochemical technologies are usually based on lignocellulosic feedstock which is pretreated, hydrolysed into sugars and then fermented to ethanol. Alternative biochemical pathways process sugars or gaseous components into methanol, butanol, mixed alcohols, acetic acids, or other chemical building blocks. Most thermochemical technologies use gasification to convert lignocellulosic feedstock into synthesis gas, which can be converted into BtL-Diesel, SNG, DME or mixed alcohols. Alternative thermochemical pathways include pyrolysis of biomass and upgrading of the resulting pyrolysis oil. The most successful chemical pathway is the hydrotreatment of vegetable oil or fats to produce diesel-type hydrocarbons. Other pathways include catalytic decarboxylation, and methanol production from glycerin. This report is based on a database on advanced biofuels projects. The database feeds into an interactive map which is available at http://demoplants.bioenergy2020.eu, and it is updated continuously. The report includes general descriptions of the main advanced biofuels technologies under development, a list of 102 projects that are being pursued worldwide, and detailed descriptions of these projects. All data displayed has been made available by the companies that pursue these projects. For this reason, the list of projects may not be complete, as some companies may still be reluctant to share data. Since

Biofuel impacts on water.

Energy Technology Data Exchange (ETDEWEB)

Tidwell, Vincent Carroll; Malczynski, Leonard A.; Sun, Amy Cha-Tien

2011-01-01

Sandia National Laboratories and General Motors Global Energy Systems team conducted a joint biofuels systems analysis project from March to November 2008. The purpose of this study was to assess the feasibility, implications, limitations, and enablers of large-scale production of biofuels. 90 billion gallons of ethanol (the energy equivalent of approximately 60 billion gallons of gasoline) per year by 2030 was chosen as the book-end target to understand an aggressive deployment. Since previous studies have addressed the potential of biomass but not the supply chain rollout needed to achieve large production targets, the focus of this study was on a comprehensive systems understanding the evolution of the full supply chain and key interdependencies over time. The supply chain components examined in this study included agricultural land use changes, production of biomass feedstocks, storage and transportation of these feedstocks, construction of conversion plants, conversion of feedstocks to ethanol at these plants, transportation of ethanol and blending with gasoline, and distribution to retail outlets. To support this analysis, we developed a 'Seed to Station' system dynamics model (Biofuels Deployment Model - BDM) to explore the feasibility of meeting specified ethanol production targets. The focus of this report is water and its linkage to broad scale biofuel deployment.

Development of a biorefinery optimized biofuel supply curve for the Western United States

International Nuclear Information System (INIS)

Parker, Nathan; Tittmann, Peter; Hart, Quinn; Nelson, Richard; Skog, Ken; Schmidt, Anneliese; Gray, Edward; Jenkins, Bryan

2010-01-01

A resource assessment and biorefinery siting optimization model was developed and implemented to assess potential biofuel supply across the Western United States from agricultural, forest, urban, and energy crop biomass. Spatial information including feedstock resources, existing and potential refinery locations and a transportation network model is provided to a mixed integer-linear optimization model that determines the optimal locations, technology types and sizes of biorefineries to satisfy a maximum profit objective function applied across the biofuel supply and demand chain from site of feedstock production to the product fuel terminal. The resource basis includes preliminary considerations of crop and residue sustainability. Sensitivity analyses explore possible effects of policy and technology changes. At a target market price of 19.6 $ GJ -1 , the model predicts a feasible production level of 610-1098 PJ, enough to supply up to 15% of current regional liquid transportation fuel demand. (author)

Bio-fuels - biohazard

International Nuclear Information System (INIS)

Slovak, K.

2008-01-01

Politicians have a clear explanation for growing commodity prices. It is all the fault of speculators. It is easy to point the finger at an imaginary enemy. It is more difficult and from the point of view of a political career suicidal to admit one's mistakes. And there are reasons for remorse. According to studies prepared by the OECD and the World Bank bio-fuels are to be blame for high food prices. The bio-fuel boom that increases the demand for agro-commodities has been created by politicians offering generous subsidies. And so farming products do not end up on the table, but in the fuel tanks of cars in the form of additives. And their only efficiency is that they make food more expensive. The first relevant indication that environmentalist tendencies in global politics have resulted in shortages and food price increases can be found in a confidential report prepared by the World Bank. Parts of the report were leaked to the media last month. According to this information growing bio-fuel production has resulted in a food price increase by 75%. The theory that this development was caused by speculators and Chinese and Indian demand received a serious blow. And the OECD report definitely contradicted the excuse used by the politicians. According to the report one of the main reasons for growing food prices are generously subsidized bio-fuels. Their share of the increase of demand for agro-commodities in 2005 -2007 was 60% according to the study. (author)

Biofuels development and the policy regime.

Science.gov (United States)

Philp, Jim C; Guy, Ken; Ritchie, Rachael J

2013-01-01

Any major change to the energy order is certain to provoke both positive and negative societal responses. The current wave of biofuels development ignited controversies that have re-shaped the thinking about their future development. Mistakes were made in the early support for road transport biofuels in Organisation for Economic Co-operation and Development (OECD) countries. This article examines some of the policies that shaped the early development of biofuels and looks to the future. Copyright © 2012 Elsevier Ltd. All rights reserved.

Stabilizing the agricultural frontier: Leveraging REDD with biofuels for sustainable development

International Nuclear Information System (INIS)

Killeen, Timothy J.; Schroth, Goetz; Turner, Will; Harvey, Celia A.; Steininger, Marc K.; Dragisic, Christine; Mittermeier, Russell A.

2011-01-01

We evaluate the potential of a proposed policy model that would explicitly link the cultivation of biofuels with forest conservation (Biofuel + FC) as part of the United Nations Framework Convention on Climate Change. The model postulates that a ratio of 4:1 forest conservation to biofuel cultivation be linked to proposals for reducing emissions from deforestation and forest degradation (REDD + Biofuel), while a ratio of 9:1 biofuel cultivation to reforestation on degraded landscape (RDL + Biofuel) be linked to the afforestation/reforestation component of the Clean Development Mechanism. Both biofuel production options would be limited to the cultivation of woody perennial biofuel species on low biomass landscapes in order to maximize the carbon benefits of the proposed policy model. The potential to conserve forest, avoid GHG emissions, improve carbon sequestration, and produce renewable energy are evaluated by an illustrative model for five case studies (Pará – Brazil, East Kalimantan – Indonesia, Madagascar, Colombia and Liberia). The Biofuel + FC policy model is then compared with three counterfactual scenarios: REDD Alone with no biofuel cultivation; Biofuel Alone with expanded biofuel cultivation in the absence of REDD and a Most Likely scenario where REDD and biofuel cultivation are implemented without explicit regulatory linkages. The proposed policy model would leverage forest carbon with biofuel markets, which would reduce greenhouse gas emissions and conserve biodiversity, as well as improve human welfare in developing countries, a win–win–win strategy for sustainable development. -- Highlights: ► We propose to link biofuel cultivation with forest conservation (REDD + Biofuels). ► A similar proposal to support reforestation on degraded landscapes (RDL + Biofuels). ► Woody perennial biofuel species on low biomass landscapes maximize carbon benefits. ► REDD+ revenues can subsidize and foster sustainable biofuels. ► Production of

An Assessment of Thailand’s Biofuel Development

Directory of Open Access Journals (Sweden)

Pujan Shrestha

2013-04-01

Full Text Available The paper provides an assessment of first generation biofuel (ethanol and biodiesel development in Thailand in terms of feedstock used, production trends, planned targets and policies and discusses the biofuel sustainability issues—environmental, socio-economic and food security aspects. The policies, measures and incentives for the development of biofuel include targets, blending mandates and favorable tax schemes to encourage production and consumption of biofuels. Biofuel development improves energy security, rural income and reduces greenhouse gas (GHG emissions, but issues related to land and water use and food security are important considerations to be addressed for its large scale application. Second generation biofuels derived from agricultural residues perform favorably on environmental and social sustainability issues in comparison to first generation biofuel sources. The authors estimate that sustainably-derived agricultural crop residues alone could amount to 10.4 × 106 bone dry tonnes per year. This has the technical potential of producing 1.14–3.12 billion liters per year of ethanol to possibly displace between 25%–69% of Thailand’s 2011 gasoline consumption as transportation fuel. Alternatively, the same amount of residue could provide 0.8–2.1 billion liters per year of diesel (biomass to Fischer-Tropsch diesel to potentially offset 6%–15% of national diesel consumption in the transportation sector.

Biofuels barometer - EurObserv'ER - July 2011

International Nuclear Information System (INIS)

2011-07-01

13,6 % the increase in EU biofuel consumption in 2010. In 2010 biofuel continued to gnaw away at petrol and diesel consumption in the European Union. However its pace backs the assertion that EU biofuel consumption growth slackened off. In the transport sector, it increased by only 1.7 Mtoe compared to 2.7 Mtoe in 2009. The final total biofuel consumption figure for 2010 should hover at around 13,9 Mtoe

Institutional analysis of biofuel production in Northern Ghana

OpenAIRE

Kwoyiga, Lydia

2013-01-01

The thesis studied the nature of institutional arrangement around biofuel production and how this arrangement has shaped the production outcome of biofuel companies and community development. The study was conducted in two communities of the Yendi Municipal Assembly of the Northern Region of Ghana. In this area, a biofuel company called Biofuel Africa Limited has acquired areas of land and cultivated Jatropha plantations. A total of 32 informants were interviewed to arrive at information ne...

Assessment of biofuels supporting policies using the BioTrans model

International Nuclear Information System (INIS)

Lensink, Sander; Londo, Marc

2010-01-01

The introduction of advanced, 2nd generation biofuels is a difficult to forecast process. Policies may impact the timing of their introduction and the future biofuels mix. The least-cost optimization model BioTrans supports policy analyses on these issues. It includes costs for all parts of the supply chain, and endogenous learning for all biofuels technologies, including cost reductions through scale. BioTrans shows that there are significant lock-in effects favouring traditional biofuels, and that the optimal biofuels mix by 2030 is path dependent. The model captures important barriers for the introduction of emerging technologies, thereby providing valuable quantitative information that can be used in analyses of biofuels supporting policies. It is shown that biodiesel from oil crops will remain a cost effective way of producing biofuels in the medium term at moderate target levels. Aiming solely at least-cost biofuel production is in conflict with a longer term portfolio approach on biofuels, and the desire to come to biofuels with the lowest greenhouse gas emissions. Lowering the targets because of environmental constraints delays the development of 2nd generation biofuels, unless additional policy measures (such as specific sub targets for these fuels) are implemented.

Impact of Technology and Feedstock Choice on the Environmental Footprint of Biofuels

Science.gov (United States)

Schultz, P. B.; Dodder, R. S.

2012-12-01

The implementation of the U.S. Renewable Fuel Standard program (RFS2) has led to a dramatic shift in the use of biofuel in the U.S. transportation system over the last decade. To satisfy this demand, the production of U.S. corn-based ethanol has grown rapidly, with an average increase of over 25% annually from 2002 to 2010. RFS2 requires a similarly steep increase in the production of advanced biofuels, such as cellulosic ethanol. Unlike corn-based ethanol, which is derived from the biochemical fermentation of sugars in wet and dry mills, it is likely that a more diverse suite of technologies will need to be developed to be able to meet the advanced biofuel RFS2 targets, including biochemical as well as thermochemical (e.g., gasification and pyrolysis) approaches. Rather than relying on energy crops, a potential advantage of thermochemical approaches is the ability to use a wider variety of feedstocks, including municipal solid waste and wood waste. In this work, we conduct a system-level analysis to understand how technology and feedstock choice can impact the environmental footprint of biofuels in the U.S. We use a least-cost optimization model of the U.S. energy system to account for interactions between various components of the energy system: industrial, transportation, electric, and residential/commercial sectors. The model was used to understand the scale of feedstock demand required from dedicated energy crops, as well as other biomass feedstocks, in order to meet the RFS2 mandate. On a regional basis, we compare the overall water-consumption and land requirements for biofuels production given a suite of liquid-fuel production technologies. By considering a range of scenarios, we examine how the use of various feedstocks (e.g., agricultural residues, wood wastes, mill residues and municipal wastes) can be used to off-set environmental impacts as compared to relying solely on energy crops.

Small-size biofuel cell on paper.

Science.gov (United States)

Zhang, Lingling; Zhou, Ming; Wen, Dan; Bai, Lu; Lou, Baohua; Dong, Shaojun

2012-05-15

In this work, we demonstrated a novel paper-based mediator-less and compartment-less biofuel cell (BFC) with small size (1.5 cm × 1.5 cm). Ionic liquid functionalized carbon nanotubes (CNTs-IL) nanocomposite was used as support for both stably confining the anodic biocatalyst (i.e., NAD(+)-dependent glucose dehydrogenase, GDH) for glucose electrooxidation and for facilitating direct electrochemistry of the cathodic biocatalyst (i.e., bilirubin oxidase, BOD) for O(2) electroreduction. Such BFC provided a simple approach to fabricate low-cost and portable power devices on small-size paper, which can harvest energy from a wide range of commercial beverages containing glucose (e.g., Nescafe instant coffee, Maidong vitamin water, Watermelon fresh juice, and Minute Maid grape juice). These made the low-cost paper-based biodevice potential for broad energy applications. Copyright © 2012 Elsevier B.V. All rights reserved.

Controversies, development and trends of biofuel industry in the world

Directory of Open Access Journals (Sweden)

WenJun Zhang

2012-09-01

Full Text Available Controversies, development and trends of biofuel industry in the world were discussed in present article. First-generation biofuels, i.e., grain and land based biofuels, occupied large areas of arable lands and severely constrained food supplies, are widely disputed. They have been replaced by second-generation biofuels. The raw materials of the second-generation biofuels include plants, straw, grass and other crops and forest residues. However, the cost for production of the second-generation biofuels is higher. Therefore the development of the third-generation biofuels is undergoing. The third-generation technologies use, mainly algae, as raw material to produce bioethanol, biobutanol, biodiesel and hydrogen, and use discarded fruits to produce dimethylfuran, etc. Different countries and regions are experiencing different stages of biofuel industry. In the future the raw materials for biofuel production will be focused on various by-products, wastes, and organisms that have not direct economic benefit for human. Production technologies should be improved or invented to reduce carbon emission and environmental pollution during biofuel production and to reduce production cost.

Fuel taxes and biofuel promotion: a complementary approach

International Nuclear Information System (INIS)

Santamaría, Marta; Azqueta, Diego

2015-01-01

Public support for renewable energy technologies is usually justified in terms of its contribution to reducing energy dependency; an improvement in environmental quality and a stimulation of economic activity and employment. In the case of biofuels, greenhouse gas emissions reduction has received significant attention. Nevertheless, nowadays there is a lively debate surrounding the convenience of biofuels. This is a consequence of the potentially negative impacts revealed from their production on a large scale. The aim of the present work is to analyses the potential contribution of biofuels to the main impact categories identified above. This paper tries to analyze the role of biofuel promotion in the context of fuel taxes. Based on the assessment of biofuels in Spain related to environmental damage and economic impacts, it shows that fuel taxes and biofuel promotion should be considered as complementary tools and treated accordingly. (full text)

Glucose-based Biofuel Cells: Nanotechnology as a Vital Science in Biofuel Cells Performance

OpenAIRE

Hamideh Aghahosseini; Ali Ramazani; Pegah Azimzadeh Asiabi; Farideh Gouranlou; Fahimeh Hosseini; Aram Rezaei; Bong-Ki Min; Sang Woo Joo

2016-01-01

Nanotechnology has opened up new opportunities for the design of nanoscale electronic devices suitable for developing high-performance biofuel cells. Glucose-based biofuel cells as green energy sources can be a powerful tool in the service of small-scale power source technology as it provides a latent potential to supply power for various implantable medical electronic devices. By using physiologically produced glucose as a fuel, the living battery can recharge for continuous production of el...

Transitioning to sustainable use of biofuel in Australia★

Directory of Open Access Journals (Sweden)

Sasongko Nugroho Adi

2017-01-01

Full Text Available Biofuel is identified as one of the key renewable energy sources for sustainable development, and can potentially replace fossil-based fuels. Anticipating the competition between food and energy security, the Australian Government is intensively exploring other biofuel resources. There have been numerous research projects in Australia using the second and third generation model based on different feedstocks including lignocellulosic and microalgae. Such projects have been successfully demonstrated but are yet to be commercially viable. Moreover, transition pathways to realize the potential benefits of these value chains are not well understood. This preliminary study tried to provide an alternative framework and proposes future long-term transport biofuel pathways in Australia which can be seen as a solution for a post-carbon society. The study is targeted to outline the milestone of the Australian biofuel industry and its roadmap into the future. An investigation has been carried out on biofuel status and barrier, technology development, market and the chronology of biofuel related policies in Australia to understand the current situation and possibilities to develop further strategies, while also providing an insight into the consequences of producing biofuel for transportation. Several methods have been proposed to introduce the transition into a post-carbon society. Seven scenarios were divided, covering the roadmap of first, second and third generation of biofuel, alternative transportation modes such as electric vehicles (EVs and fuel cell vehicles (FCVs and the elimination of the fossil fuel running vehicles within a time frame of 20 years. The utilization of biofuel can be seen as a short to medium mode for transition into a green transportation society. Our investigation also showed that microalgae gave a better ecological footprint which offers the strongest potential for future Australian biofuel industry and aviation. Meanwhile, EVs

Biofuels barometer - EurObserv'ER - July 2010

International Nuclear Information System (INIS)

2010-07-01

12.1 Mtoe of biofuels consumed in the transport sector in the EU in 2009. European Union biofuel use for transport reached the 12 million tons of oil equivalent (mtoe) threshold during 2009, heralding a further drop in the pace of the sector's growth, which rose by only 18.7% between 2008 and 2009 - just 1.9 mtoe of consumption over the previous year. The biofuel incorporation rate in all fuels used by transport in the EU is unlikely to pass 4% in 2009, which is a very long way short of the 5.75% goal for 2010 set in the 2003 European biofuel directive, which would require around 18 mtoe of biofuel use

A viable technology to generate third-generation biofuel

DEFF Research Database (Denmark)

Singh, Anoop; Olsen, Stig Irving; Nigam, Poonam Singh

2011-01-01

First generation biofuels are commercialized at large as the production technologies are well developed. However, to grow the raw materials, there is a great need to compromise with food security, which made first generation biofuels not so much promising. The second generation of biofuels does...

75 FR 11836 - Bioenergy Program for Advanced Biofuels

Science.gov (United States)

2010-03-12

... Biofuels AGENCY: Rural Business-Cooperative Service (RBS), USDA. ACTION: Notice of Contract for Proposal... Year 2009 for the Bioenergy Program for Advanced Biofuels under criteria established in the prior NOCP... Bioenergy Program for Advanced Biofuels. In response to the previously published NOCP, approximately $14.5...

Catalytic pyrolysis of microalgae to high-quality liquid bio-fuels

NARCIS (Netherlands)

Babych, Igor V.; van der Hulst, M.; Lefferts, Leonardus; Moulijn, J.A.; Seshan, Kulathuiyer; O'Connor, P.

2011-01-01

The pyrolytic conversion of chlorella algae to liquid fuel precursor in presence of a catalyst (Na2CO3) has been studied. Thermal decomposition studies of the algae samples were performed using TGA coupled with MS. Liquid oil samples were collected from pyrolysis experiments in a fixed-bed reactor

Assessment of Peruvian biofuel resources and alternatives

Energy Technology Data Exchange (ETDEWEB)

Harper, J.P.; Smith, W.; Mariani, E.

1979-08-01

Comprehensive assessment of the biofuel potential of Peru is based on: determination of current biofuel utilization practices, evauation of Peruvian biomass productivity, identification of Peruvian agricultural and forestry resources, assessment of resource development and management concerns, identification of market considerations, description of biofuel technological options, and identification of regional biofuel technology applications. Discussion of current biofuel utilization centers on a qualitative description of the main conversion approaches currently being practiced in Peru. Biomass productivity evaluations consider the terrain and soil, and climatic conditions found in Peru. The potential energy from Peruvian agricultural and forestry resources is described quantitatively. Potental regional production of agricultural residues and forest resources that could supply energy are identified. Assessment of resource development and management concerns focuses on harvesting, reforestation, training, and environmental consequences of utilization of forest resources. Market factors assessed include: importation, internal market development, external market development, energy policy and pricing, and transportation. Nine biofuel technology options for Peru are identified: (1) small-to-medium-scale gasification, (2) a wood waste inventory, (3) stationary and mobile charcoal production systems, (4) wood distillation, (5) forest resource development and management, (6) electrical cogeneration, (7) anaerobic digestion technology, (8) development of ethanol production capabilities, and (9) agricultural strategies for fuel production. Applications of these biofuel options are identified for each of the three major regions - nine applications for the Costa Region, eight for the Sierra Region, and ten for the Selva Region.

Engineering microbes for tolerance to next-generation biofuels

Directory of Open Access Journals (Sweden)

Dunlop Mary J

2011-09-01

Full Text Available Abstract A major challenge when using microorganisms to produce bulk chemicals such as biofuels is that the production targets are often toxic to cells. Many biofuels are known to reduce cell viability through damage to the cell membrane and interference with essential physiological processes. Therefore, cells must trade off biofuel production and survival, reducing potential yields. Recently, there have been several efforts towards engineering strains for biofuel tolerance. Promising methods include engineering biofuel export systems, heat shock proteins, membrane modifications, more general stress responses, and approaches that integrate multiple tolerance strategies. In addition, in situ recovery methods and media supplements can help to ease the burden of end-product toxicity and may be used in combination with genetic approaches. Recent advances in systems and synthetic biology provide a framework for tolerance engineering. This review highlights recent targeted approaches towards improving microbial tolerance to next-generation biofuels with a particular emphasis on strategies that will improve production.

Montana Advanced Biofuels Great Falls Approval

Science.gov (United States)

This November 20, 2015 letter from EPA approves the petition from Montana Advanced Biofuels, LLC, Great Falls facility, regarding ethanol produced through a dry mill process, qualifying under the Clean Air Act for advanced biofuel (D-code 5) and renewable

Climate design of vegetable oil fuels for agricultural equipment; Klimadesign von Pflanzenoelkraftstoffen fuer landwirtschaftliche Maschinen

Energy Technology Data Exchange (ETDEWEB)

Stoehr, Michael [B.A.U.M. Consult GmbH, Muenchen (Germany). International and Energy Projects; Pickel, Peter [John Deere European Technology Innovation Center, Kaiserslautern (Germany)

2012-07-01

The use of biofuels in agricultural machinery is an option for complying with climate protection requirements that are presently discussed to be placed on manufacturers of mobile off-road machinery by the European Commission. A mathematical model has been developed that allows calculating greenhouse gas emissions (GHGE) of biofuels for complex production paths in a straightforward, transparent manner and in pattern with the EU's Fuel Quality Directive (FQD). Therewith it has been shown that both rape seed and camelina sativa oil fuels can save more than 60 % GHGE. Key parameters have been identified and rules for a climate design of vegetable oil fuels have been formulated. (orig.)

Water use implications of biofuel scenarios

Science.gov (United States)

Teter, J.; Mishra, G. S.; Yeh, S.

2012-12-01

Existing studies rely upon attributional lifecycle analysis (LCA) approaches to estimate water intensity of biofuels in liters of irrigated/evapotranspiration water consumed for biofuel production. Such approaches can be misleading. From a policy perspective, a better approach is to compare differential water impacts among scenarios on a landscape scale. We address the shortcomings of existing studies by using consequential LCA, and incorporate direct and indirect land use (changes) of biofuel scenarios, marginal vs. average biofuel water use estimates, future climate, and geographic heterogeneity. We use the outputs of a partial equilibrium economic model, climate and soil data, and a process-based crop-soil-climate-water model to estimate differences in green water (GW - directly from precipitation to soil) and blue water (BW - supplied by irrigation) use among three scenarios: (1) business-as-usual (BAU), (2) Renewable Fuels Standard (RFS) mandates, and (3) a national Low Carbon Fuel Standard (LCFS) plus the RFS scenario. We use spatial statistical methods to interpolate key climatic variables using daily climate observations for the contiguous USA. Finally, we use FAO's crop model AquaCrop to estimate the domestic GW and BW impacts of biofuel policies from 2007-2035. We assess the differences among scenarios along the following metrics: (1) crop area expansion at the county level, including prime and marginal lands, (2) crop-specific and overall annual/seasonal water balances including (a) water inflows (irrigation & precipitation), (b) crop-atmosphere interactions: (evaporation & transpiration) and (d) soil-water flows (runoff & soil infiltration), in mm 3 /acre over the relevant time period. The functional unit of analysis is the BW and GW requirements of biofuels (mm3 per Btu biofuel) at the county level. Differential water use impacts among scenarios are a primarily a function of (1) land use conversion, in particular that of formerly uncropped land classes

Anaerobic Biodegradation of Biofuels (Ethanol and Biodiesel) and Proposed Biofuels (n-Propanol, iso-Propanol, n-Butanol)

Science.gov (United States)

Biofuels, such as ethanol and biodiesel, are a growing component of the nation’s fuel supply. Ethanol is the primary biofuel in the US market, distributed as a blend with petroleum gasoline, in concentrations ranging from 10% ethanol (E10) to 85% ethanol (E85). Biodiesel, made fr...

Third Generation Biofuels via Direct Cellulose Fermentation

Directory of Open Access Journals (Sweden)

David B. Levin

2008-07-01

Full Text Available Consolidated bioprocessing (CBP is a system in which cellulase production, substrate hydrolysis, and fermentation are accomplished in a single process step by cellulolytic microorganisms. CBP offers the potential for lower biofuel production costs due to simpler feedstock processing, lower energy inputs, and higher conversion efficiencies than separate hydrolysis and fermentation processes, and is an economically attractive near-term goal for “third generation” biofuel production. In this review article, production of third generation biofuels from cellulosic feedstocks will be addressed in respect to the metabolism of cellulolytic bacteria and the development of strategies to increase biofuel yields through metabolic engineering.

NREL Algal Biofuels Projects and Partnerships

Energy Technology Data Exchange (ETDEWEB)

2016-10-01

This fact sheet highlights several algal biofuels research and development projects focused on improving the economics of the algal biofuels production process. These projects should serve as a foundation for the research efforts toward algae as a source of fuels and other chemicals.

potential for liquid biofuel production in the southern african region

African Journals Online (AJOL)

user

2013-02-27

Feb 27, 2013 ... There has been a sustained and growing interest in the production of liquid fuel from biomass in recent years. ... This work looks at the energy situation in South Africa and especially the liquid fuel sector and explores the ...... alcohol production.http://www.lowcvp.org.uk/assets/reports/HGCA%20RR61.

Straight vegetable oil use in Micro-Gas Turbines: System adaptation and testing

International Nuclear Information System (INIS)

Prussi, M.; Chiaramonti, D.; Riccio, G.; Martelli, F.; Pari, L.

2012-01-01

Highlights: → The possibility to feed a Micro Gas Turbine with Straight Vegetable Oil (SVO) has been investigated. → Correlative analysis and CFD were used to model the effect of SVO characteristics on atomization and evaporation. → Minor modifications to a the commercial MGT were adopted. → Measured power output and specific fuel consumption were close to standard fuel, taking into account the LHV of SVO. → Emissions were higher than for standard fossil fuel but strongly affected by SVO temperature. -- Abstract: The aim of this research work is to investigate the use of straight vegetable sunflower oil (SFO), a liquid biofuel, in a Micro-Gas Turbine (MGT). Compared to conventional diesel engines, micro-gas turbines represent a very reliable, clean and performing small scale cogeneration technology. Commercial gas turbines have already been tested with unconventional fuels, such as biomass derived fuels; however, research work on using Straight Vegetable Oil (SVO) as fuel in MGTs are really scarce. The chemical and physical characteristics of SVO are different from fossil diesel oil and rather far from the common technical specifications for gas turbine liquid fuels, not only in terms of kinematic viscosity and Lower Heating Value, but also as regards other issues as contaminant levels and composition, fuel cold properties, ignition properties, etc. Therefore, particular attention has to be given to the atomization and evaporation phases, as these are the most critical steps to achieve stable and efficient long term operation. An analysis based on numerical correlations available from literature was initially adopted for the analysis of the atomization process, supported by CFD modeling to qualitatively investigate the flow pattern. Control parameters were revised and set so to produce a sunflower oil spray having evaporation time comparable to diesel, and minor adaptations to the fuel line were designed and installed on the MGT. Tests with blends and

Biofuels from food processing wastes.

Science.gov (United States)

Zhang, Zhanying; O'Hara, Ian M; Mundree, Sagadevan; Gao, Baoyu; Ball, Andrew S; Zhu, Nanwen; Bai, Zhihui; Jin, Bo

2016-04-01

Food processing industry generates substantial high organic wastes along with high energy uses. The recovery of food processing wastes as renewable energy sources represents a sustainable option for the substitution of fossil energy, contributing to the transition of food sector towards a low-carbon economy. This article reviews the latest research progress on biofuel production using food processing wastes. While extensive work on laboratory and pilot-scale biosystems for energy production has been reported, this work presents a review of advances in metabolic pathways, key technical issues and bioengineering outcomes in biofuel production from food processing wastes. Research challenges and further prospects associated with the knowledge advances and technology development of biofuel production are discussed. Copyright © 2016. Published by Elsevier Ltd.

Microalgae biofuel potentials (review).

Science.gov (United States)

Ghasemi, Y; Rasoul-Amini, S; Naseri, A T; Montazeri-Najafabady, N; Mobasher, M A; Dabbagh, F

2012-01-01

With the decrease of fossil based fuels and the environmental impact of them over the planet, it seems necessary to seek the sustainable sources of clean energy. Biofuels, is becoming a worldwide leader in the development of renewable energy resources. It is worthwhile to say that algal biofuel production is thought to help stabilize the concentration of carbon dioxide in the atmosphere and decrease global warming impacts. Also, among algal fuels' attractive characteristics, algal biodiesel is non toxic, with no sulfur, highly biodegradable and relatively harmless to the environment if spilled. Algae are capable of producing in excess of 30 times more oil per acre than corn and soybean crops. Currently, algal biofuel production has not been commercialized due to high costs associated with production, harvesting and oil extraction but the technology is progressing. Extensive research was conducted to determine the utilization of microalgae as an energy source and make algae oil production commercially viable.

L-ascorbic acid losses in Kenyan vegetables during cooking as determined by high performance liquid chromatography

OpenAIRE

N.M.N. Wekesa; S.C. Chhabra; H.M. Thairu

2001-01-01

The loss of L-ascorbic acid (L-AA) in 14 different cooked local vegetables found in Nairobi markets was determined by high performance liquid chromatography. The effect of quantity of water on the loss of L-AA during cooking was studied with cowpea leaves. It was found that more L-AA was lost when larger amount of water was used than when smaller amount was used. The effect of the sharpness of the knife on the loss of L-AA was studied with spinach. It was found that more loss of L-AA occurred...

REFUEL. Potential and realizable cost reduction of 2nd generation biofuels

International Nuclear Information System (INIS)

Londo, H.M.; Deurwaarder, E.P.; Lensink, S.M.; Junginer, H.M.; De Wit, M.

2007-05-01

In the REFUEL project steering possibilities for and impacts of a greater market penetration of biofuels are assessed. Several benefits are attributed to second generation biofuels, fuels made from lignocellulosic feedstock, such as higher productivity, less impacts on land use and food markets and improved greenhouse gas emission reductions. The chances of second generation biofuels entering the market autonomously are assessed and several policy measures enhancing those changes are evaluated. It shows that most second generation biofuels might become competitive in the biofuel market, if the production of biodiesel from oil crops becomes limited by land availability. Setting high biofuel targets, setting greenhouse gas emissions caps on biofuel and setting subtargets for second generation biofuels, all have a similar impact of stimulating second generation's entrance into the biofuel market. Contrary, low biofuel targets and high imports can have a discouraging impact on second generation biofuel development, and thereby on overall greenhouse gas performance. Since this paper shows preliminary results from the REFUEL study, one is advised to contact the authors before quantitatively referring to this paper

Biofuels barometer - EurObserv'ER - July 2015

International Nuclear Information System (INIS)

2015-07-01

+6.1% The increase of biofuel consumption in European Union transport between 2013 and 2014 (in energy content). Biofuel consumption for transport picked up in Europe after a year of uncertainty and decline, increasing by 6.1% over 2013, to 14 million toe (Mtoe) according to EurObserv'ER's first estimates. However it is still below its 2012 level when 14.5 Mtoe of biofuel was incorporated. Consumption of biofuel that meets the European Renewable Energy directive's sustainability criteria rose to 12.5 Mtoe, its highest level so far

Vermont Biofuels Initiative: Local Production for Local Use to Supply a Portion of Vermont's Energy Needs

Energy Technology Data Exchange (ETDEWEB)

Sawyer, Scott; Kahler, Ellen

2009-05-31

The Vermont Biofuels initiative (VBI) is the Vermont Sustainable Jobs Fund's (VSJF) biomass-to-biofuels market development program. Vermont is a small state with a large petroleum dependency for transportation (18th in per capita petroleum consumption) and home heating (55% of all households use petroleum for heating). The VBI marks the first strategic effort to reduce Vermont's dependency on petroleum through the development of homegrown alternatives. As such, it supports the four key priorities of the U.S. Department of Energy's Multi-year Biomass Plan: 1.) Dramatically reduce dependence on foreign oil; 2.) Promote the use of diverse, domestic and sustainable energy resources; 3.) Reduce carbon emissions from energy production and consumption; 4.) Establish a domestic bioindustry. In 2005 VSJF was awarded with a $496,000 Congressionally directed award from U.S. Senator Patrick Leahy. This award was administered through the U.S. Department of Energy (DE-FG36- 05GO85017, hereafter referred to as DOE FY05) with $396,000 to be used by VSJF for biodiesel development and $100,000 to be used by the Vermont Department of Public Service for methane biodigester projects. The intent and strategic focus of the VBI is similar to another DOE funded organization-the Biofuels Center of North Carolina-in that it is a nonprofit driven, statewide biofuels market development effort. DOE FY05 funds were expensed from 2006 through 2008 for seven projects: 1) a feedstock production, logistics, and biomass conversion research project conducted by the University of Vermont Extension; 2) technical assistance in the form of a safety review and engineering study of State Line Biofuels existing biodiesel production facility; 3) technical assistance in the form of a safety review and engineering study of Borderview Farm's proposed biodiesel production facility; 4) technology and infrastructure purchases for capacity expansion at Green Technologies, LLC, a waste vegetable

Biofuels in Italy: obstacles and development opportunities

International Nuclear Information System (INIS)

Pignatelli, Vito; Clementi, Chiara

2006-01-01

Today biofuels are the sole realistically practical way to reduce CO 2 emissions in the transportation sector. In many countries, including Italy, biofuel production and use are already a reality corresponding to a large agro-industrial production system that uses essentially mature technologies. To significantly lower production costs and optimise land use, Italy needs to develop new, second-generation biofuel production operations that can offer significant opportunities to the nation's agro-industrial sector [it

Alternative spatial allocation of suitable land for biofuel production in China

DEFF Research Database (Denmark)

Zhang, Jianjun; Chen, Yang; Rao, Yongheng

2017-01-01

How to select locations for biofuel production is still a critical consideration for balance of crop and biofuel productions as well as of energy consumption and environmental conservation. Biofuels are widely produced all over the world, but this practice in China is still at the initial stage....... Based on China's current stage on food security and changing biofuel demands, this paper selected agro-environmental and socio-economic factors of biofuel production, and simulated and spatially allocated areas suited for biofuel production under the two scenarios of planning-oriented scenario (Po......S) and biofuel-oriented scenario (BoS) by the target year 2020. It also estimated biofuel production potentials and zones across China's provinces. The results show that land suited for biofuel production is primarily located in Northwestern, Northern, Northeastern, Central and Southwestern China...

The changing dynamics between biofuels and commodity markets

International Nuclear Information System (INIS)

Bole, T.; Londo, H.M.

2008-06-01

The recent development of the biofuel industries coincides with significant increases in prices of basic commodities such as food and feed. Against popular perception, it appears that there is not a straightforward causal relationship between the two; there are a number of factors that determine the level and strength of the impact of the biofuels sector on other commodities. For the case of markets of agricultural raw material these factors include the amount of feedstock claimed by the biofuels industry, its relative purchasing power, the responsiveness of the agricultural sector to price incentives and availability of substitutes. For consumer food markets we must additionally consider the relative share of agricultural input costs in the retail food price and the demand elasticity. Based on the analysis of these factors and estimates of other studies that attempted to quantify the price impacts of biofuels on crop prices, we conclude that the impact of biofuels is relatively small, especially when compared with other causes that triggered the recent price increases. We end the paper with a recommendation for future efforts in curbing food price inflations while keeping ambitious biofuel targets and suggest a shift in focus of the debate around the social costs of biofuels

Biofuel Cells – Alternative Power Sources

International Nuclear Information System (INIS)

Babanova, Sofia; Yolina Hubenova; Mario Mitov

2009-01-01

Energy generation from renewable sources and effective waste treatment are two key challenges for the sustainable development. Microbiological (or Bio-) Fuel Cells provide an elegant solution by linking both tasks. Biofuel cells, which can directly generate electricity from biodegradable substances, have rapidly gained increasing research attention. Widely available fuel sources and moderate operational conditions make them promising in renewable energy generation, wastewater treatment, power sources for remote devices, etc. This paper reviews the use of microorganisms as biocatalysts in microbiological fuel cells. The principle of biofuel cells and their construction elements are discussed. Keywords: alternative power sources, biofuel cells, biocatalysts

Bio-fuel production potential in Romania

International Nuclear Information System (INIS)

Laurentiu, F.; Silvian, F.; Dumitru, F.

2006-01-01

The paper is based on the ESTO Study: Techno- Economic Feasibility of Large-Scale Production of Bio-Fuels in EU-Candidate Countries. Bio-fuel production has not been taken into account significantly until now in Romania, being limited to small- scale productions of ethanol, used mostly for various industrial purposes. However the climatic conditions and the quality of the soil are very suitable in the country for development of the main crops (wheat, sugar-beet, sunflower and rape-seed) used in bio-ethanol and bio-diesel production. The paper intended to consider a pertinent discussion of the present situation in Romania's agriculture stressing on the following essential items in the estimation of bio-fuels production potential: availability of feed-stock for bio-fuel production; actual productions of bio-fuels; fuel consumption; cost assessment; SWOT approach; expected trends. Our analysis was based on specific agricultural data for the period 1996-2000. An important ethanol potential (due to wheat, sugar-beet and maize cultures), as well as bio-diesel one (due to sun-flower and rape-seed) were predicted for the period 2005-2010 which could be exploited with the support of an important financial and technological effort, mainly from EU countries

Biofuel consumption, biodiversity, and the environmental Kuznets curve: trivariate analysis in a panel of biofuel consuming countries.

Science.gov (United States)

Zaman, Khalid

2017-11-01

This study examined the relationship between biofuel consumption, forest biodiversity, and a set of national scale indicators of per capita income, foreign direct investment (FDI) inflows, trade openness, and population density with a panel data of 12 biofuels consuming countries for a period of 2000 to 2013. The study used Global Environmental Facility (GEF) biodiversity benefits index and forest biodiversity index in an environmental Kuznets curve (EKC) framework. The results confirmed an inverted U-shaped relationship between GEF biodiversity index and per capita income, while there is flat/no relationship between carbon emissions and economic growth, and between forest biodiversity and economic growth models. FDI inflows and trade openness both reduce carbon emissions while population density and biofuel consumption increase carbon emissions and decrease GEF biodiversity index. Trade openness supports to increases GEF biodiversity index while it decreases forest biodiversity index and biofuel consumption in a region.

Process modeling and supply chain design for advanced biofuel production based on bio-oil gasification

Science.gov (United States)

Li, Qi

As a potential substitute for petroleum-based fuel, second generation biofuels are playing an increasingly important role due to their economic, environmental, and social benefits. With the rapid development of biofuel industry, there has been an increasing literature on the techno-economic analysis and supply chain design for biofuel production based on a variety of production pathways. A recently proposed production pathway of advanced biofuel is to convert biomass to bio-oil at widely distributed small-scale fast pyrolysis plants, then gasify the bio-oil to syngas and upgrade the syngas to transportation fuels in centralized biorefinery. This thesis aims to investigate two types of assessments on this bio-oil gasification pathway: techno-economic analysis based on process modeling and literature data; supply chain design with a focus on optimal decisions for number of facilities to build, facility capacities and logistic decisions considering uncertainties. A detailed process modeling with corn stover as feedstock and liquid fuels as the final products is presented. Techno-economic analysis of the bio-oil gasification pathway is also discussed to assess the economic feasibility. Some preliminary results show a capital investment of 438 million dollar and minimum fuel selling price (MSP) of $5.6 per gallon of gasoline equivalent. The sensitivity analysis finds that MSP is most sensitive to internal rate of return (IRR), biomass feedstock cost, and fixed capital cost. A two-stage stochastic programming is formulated to solve the supply chain design problem considering uncertainties in biomass availability, technology advancement, and biofuel price. The first-stage makes the capital investment decisions including the locations and capacities of the decentralized fast pyrolysis plants and the centralized biorefinery while the second-stage determines the biomass and biofuel flows. The numerical results and case study illustrate that considering uncertainties can be

Land substitution effects of biofuel side products and implications on the land area requirement for EU 2020 biofuel targets

International Nuclear Information System (INIS)

Ozdemir, Enver Doruk; Haerdtlein, Marlies; Eltrop, Ludger

2009-01-01

The provision of biofuels today is based on energy crops rather than residual biomass, which results in the requirement of agricultural land area. The side products may serve as animal feed and thus prevent cultivation of other feedstock and the use of corresponding land area. These effects of biofuel provision have to be taken into account for a comprising assessment of land area requirement for biofuel provision. Between 18.5 and 21.1 Mio. hectares (ha) of land area is needed to meet the EU 2020 biofuel target depending on the biofuel portfolio when substitution effects are neglected. The utilization of the bioethanol side products distiller's dried grain and solubles (DDGS) and pressed beet slices may save up to 0.7 Mio. ha of maize cultivation area in the EU. The substitution effect due to the utilization of biodiesel side products (oil cakes of rape, palm and soy) as animal feed may account for up to 7.1 Mio. ha of soy cultivation area in Brazil. The results show that the substitution of land area due to use of side products might ease the pressures on land area requirement considerably and should therefore not be neglected in assessing the impacts of biofuel provision worldwide.

Center for Advanced Biofuel Systems (CABS) Final Report

Energy Technology Data Exchange (ETDEWEB)

Kutchan, Toni M. [Donald Danforth Plant Science Center, St. Louis, MO (United States)

2015-12-02

One of the great challenges facing current and future generations is how to meet growing energy demands in an environmentally sustainable manner. Renewable energy sources, including wind, geothermal, solar, hydroelectric, and biofuel energy systems, are rapidly being developed as sustainable alternatives to fossil fuels. Biofuels are particularly attractive to the U.S., given its vast agricultural resources. The first generation of biofuel systems was based on fermentation of sugars to produce ethanol, typically from food crops. Subsequent generations of biofuel systems, including those included in the CABS project, will build upon the experiences learned from those early research results and will have improved production efficiencies, reduced environmental impacts and decreased reliance on food crops. Thermodynamic models predict that the next generations of biofuel systems will yield three- to five-fold more recoverable energy products. To address the technological challenges necessary to develop enhanced biofuel systems, greater understanding of the non-equilibrium processes involved in solar energy conversion and the channeling of reduced carbon into biofuel products must be developed. The objective of the proposed Center for Advanced Biofuel Systems (CABS) was to increase the thermodynamic and kinetic efficiency of select plant- and algal-based fuel production systems using rational metabolic engineering approaches grounded in modern systems biology. The overall strategy was to increase the efficiency of solar energy conversion into oils and other specialty biofuel components by channeling metabolic flux toward products using advanced catalysts and sensible design:1) employing novel protein catalysts that increase the thermodynamic and kinetic efficiencies of photosynthesis and oil biosynthesis; 2) engineering metabolic networks to enhance acetyl-CoA production and its channeling towards lipid synthesis; and 3) engineering new metabolic networks for the

The Roundtable on Sustainable Biofuels: plant scientist input needed.

Science.gov (United States)

Haye, Sébastien; Hardtke, Christian S

2009-08-01

The Energy Center at the Ecole Polytechnique Fédérale de Lausanne (Swiss federal institute of technology) is coordinating a multi-stakeholder effort, the Roundtable on Sustainable Biofuels (http://energycenter.epfl.ch/biofuels), to develop global standards for sustainable biofuels production and processing. Given that many of the aspects related to biofuel production request a high scientific level of understanding, it is crucial that scientists take part in the discussion.

Perspectives of microalgal biofuels as a renewable source of energy

International Nuclear Information System (INIS)

Kiran, Bala; Kumar, Ritunesh; Deshmukh, Devendra

2014-01-01

Highlights: • Microalgae offer solution of wastewater treatment, CO 2 sequestration, and energy crises. • Microalgal biofuel is renewable, nontoxic and environmentally friendly option. • Integration of wastewater treatment with biofuels production has made them more cost effective. • This article details out the potential production process and benefits of microalgal biofuels. - Abstract: Excessive use of fossil fuels to satisfy our rapidly increasing energy demand has created severe environmental problems, such as air pollution, acid rain and global warming. Biofuels are a potential alternative to fossil fuels. First- and second-generation biofuels face criticism due to food security and biodiversity issues. Third-generation biofuels, based on microalgae, seem to be a plausible solution to the current energy crisis, as their oil-producing capability is many times higher than that of various oil crops. Microalgae are the fastest-growing plants and can serve as a sustainable energy source for the production of biodiesel and several other biofuels by conversion of sunlight into chemical energy. Biofuels produced from microalgae are renewable, non-toxic, biodegradable and environment friendly. Microalgae can be grown in open pond systems or closed photobioreactors. Microalgal biofuels are a potential means to keep the development of human activities in synchronization with the environment. The integration of wastewater treatment with biofuel production using microalgae has made microalgal biofuels more attractive and cost effective. A biorefinery approach can also be used to improve the economics of biofuel production, in which all components of microalgal biomass (i.e., proteins, lipids and carbohydrates) are used to produce useful products. The integration of various processes for maximum economic and environmental benefits minimizes the amount of waste produced and the pollution level. This paper presents an overview of various aspects associated with

Reconciling biofuels, sustainability and commodities demand. Pitfalls and policy options

International Nuclear Information System (INIS)

Uslu, A.; Bole, T.; Londo, M.; Pelkmans, L.; Berndes, G.; Prieler, S.; Fischer, G.; Cueste Cabal, H.

2010-06-01

Increasing fossil fuel prices, energy security considerations and environmental concerns, particularly concerning climate change, have motivated countries to explore alternative energy sources including biofuels. Global demand for biofuels has been rising rapidly due to biofuel support policies established in many countries. However, proposed strong links between biofuels demand and recent years' high food commodity prices, and notions that increasing biofuels production might bring about serious negative environmental impacts, in particularly associated with the land use change to biofuel crops, have shifted public enthusiasm about biofuels. In this context, the ELOBIO project aims at shedding further light to these aspects of biofuel expansion by collecting and reviewing the available data, and also developing strategies to decrease negative effects of biofuels while enabling their positive contribution to climate change, security of supply and rural development. ELOBIO considers aspects associated with both 1st and 2nd generation biofuels, hence analyses effects on both agricultural commodity markets and lignocellulosic markets. This project, funded by the Intelligent Energy Europe programme, consists of a review of current experiences with biofuels and other renewable energy policies and their impacts on other markets, iterative stakeholder-supported development of low-disturbing biofuels policies, model supported assessment of these policies' impacts on food, feed and lignocellulosic markets, and finally an assessment of the effects of selected optimal policies on biofuels costs and potentials. Results of the ELOBIO study show that rapid biofuel deployment without careful monitoring of consequences and implementation of mitigating measures risks leading to negative consequences. Implementing ambitious global biofuel targets for 2020, based on current 1st generation technologies, can push international agricultural commodity prices upwards and increase crop

Total employment effect of biofuels

International Nuclear Information System (INIS)

Stridsberg, S.

1998-08-01

The study examined the total employment effect of both direct production of biofuel and energy conversion to heat and electricity, as well as the indirect employment effect arising from investments and other activities in conjunction with the production organization. A secondary effect depending on the increased capital flow is also included in the final result. The scenarios are based on two periods, 1993-2005 and 2005-2020. In the present study, the different fuels and the different applications have been analyzed individually with regard to direct and indirect employment within each separate sector. The greatest employment effect in the production chain is shown for logging residues with 290 full-time jobs/TWh, whereas other biofuels range between 80 and 280 full-time jobs/TWh. In the processing chain, the corresponding range is 200-300 full-time jobs per each additional TWh. Additionally and finally, there are secondary effects that give a total of 650 full-time jobs/TWh. Together with the predicted increase, this suggests that unprocessed fuel will provide an additional 16 000 annual full-time jobs, and that fuel processing will contribute with a further 5 000 full-time jobs. The energy production from the fuels will provide an additional 13 000 full-time jobs. The total figure of 34 000 annual full-time jobs must then be reduced by about 4000 on account of lost jobs, mainly in the oil sector and to some extent in imports of biofuel. In addition, the anticipated increase in capital turnover that occurs within the biofuel sector, will increase full-time jobs up to year 2020. Finally, a discussion is given of the accomplishment of the programmes anticipated by the scenario, where it is noted that processing of biofuel to wafers, pellets or powder places major demands on access to raw material of good quality and that agrarian fuels must be given priority if they are to enter the system sufficiently fast. Straw is already a resource but is still not accepted by

Novel biofuel formulations for enhanced vehicle performance

Energy Technology Data Exchange (ETDEWEB)

Miller, Dennis [Michigan State Univ., East Lansing, MI (United States); Narayan, Ramani [Michigan State Univ., East Lansing, MI (United States); Berglund, Kris [Michigan State Univ., East Lansing, MI (United States); Lira, Carl [Michigan State Univ., East Lansing, MI (United States); Schock, Harold [Michigan State Univ., East Lansing, MI (United States); Jaberi, Farhad [Michigan State Univ., East Lansing, MI (United States); Lee, Tonghun [Michigan State Univ., East Lansing, MI (United States); Anderson, James [Michigan State Univ., East Lansing, MI (United States); Wallington, Timothy [Michigan State Univ., East Lansing, MI (United States); Kurtz, Eric [Michigan State Univ., East Lansing, MI (United States); Ruona, Will; Hass, Heinz

2013-08-30

This interdisciplinary research program at Michigan State University, in collaboration with Ford Motor Company, has explored the application of tailored or designed biofuels for enhanced vehicle performance and reduced emissions. The project has included a broad range of experimental research, from chemical and biological formation of advanced biofuel components to multicylinder engine testing of blended biofuels to determine engine performance parameters. In addition, the project included computation modeling of biofuel physical and combustion properties, and simulation of advanced combustion modes in model engines and in single cylinder engines. Formation of advanced biofuel components included the fermentation of five-carbon and six-carbon sugars to n-butanol and to butyric acid, two four-carbon building blocks. Chemical transformations include the esterification of the butyric acid produced to make butyrate esters, and the esterification of succinic acid with n-butanol to make dibutyl succinate (DBS) as attractive biofuel components. The conversion of standard biodiesel, made from canola or soy oil, from the methyl ester to the butyl ester (which has better fuel properties), and the ozonolysis of biodiesel and the raw oil to produce nonanoate fuel components were also examined in detail. Physical and combustion properties of these advanced biofuel components were determined during the project. Physical properties such as vapor pressure, heat of evaporation, density, and surface tension, and low temperature properties of cloud point and cold filter plugging point were examined for pure components and for blends of components with biodiesel and standard petroleum diesel. Combustion properties, particularly emission delay that is the key parameter in compression ignition engines, was measured in the MSU Rapid Compression Machine (RCM), an apparatus that was designed and constructed during the project simulating the compression stroke of an internal combustion

Biofuel, land and water: maize, switchgrass or Miscanthus?

International Nuclear Information System (INIS)

Zhuang Qianlai; Qin Zhangcai; Chen Min

2013-01-01

The productive cellulosic crops switchgrass and Miscanthus are considered as viable biofuel sources. To meet the 2022 national biofuel target mandate, actions must be taken, e.g., maize cultivation must be intensified and expanded, and other biofuel crops (switchgrass and Miscanthus) must be cultivated. This raises questions on the use efficiencies of land and water; to date, the demand on these resources to meet the national biofuel target has rarely been analyzed. Here, we present a data-model assimilation analysis, assuming that maize, switchgrass and Miscanthus will be grown on currently available croplands in the US. Model simulations suggest that maize can produce 3.0–5.4 kiloliters (kl) of ethanol for every hectare of land, depending on the feedstock to ethanol conversion efficiency; Miscanthus has more than twice the biofuel production capacity relative to maize, and switchgrass is the least productive of the three potential sources of ethanol. To meet the biofuel target, about 26.5 million hectares of land and over 90 km 3 of water (of evapotranspiration) are needed if maize grain alone is used. If Miscanthus was substituted for maize, the process would save half of the land and one third of the water. With more advanced biofuel conversion technology for Miscanthus, only nine million hectares of land and 45 km 3 of water would probably meet the national target. Miscanthus could be a good alternative biofuel crop to maize due to its significantly lower demand for land and water on a per unit of ethanol basis. (letter)

Improving the environmental performance of biofuels with industrial symbiosis

International Nuclear Information System (INIS)

Martin, Michael; Eklund, Mats

2011-01-01

In the production of biofuels for transport many critics have argued about the poor energy efficiency and environmental performance of the production industries. Optimism is thus set on the production of second generation biofuels, while first generation biofuels continue to dominate worldwide. Therefore it is interesting to consider how the environmental performance of first generation biofuel industries can be improved. The field of industrial symbiosis offers many possibilities for potential improvements in the biofuel industry and theories from this research field are used in this paper to highlight how environmental performance improvements can be accomplished. This comes in the form of by-product synergies and utility synergies which can improve material and energy handling. Furthermore, the processes and products can gain increased environmental performance improvements by the adaption of a renewable energy system which will act as a utility provider for many industries in a symbiotic network. By-products may thereafter be upcycled through biogas production processes to generate both energy and a bio-fertilizer. A case study of an actual biofuel industrial symbiosis is also reviewed to provide support for these theories. -- Highlights: → By-product and utility synergies may improve the production processes of biofuel industries for reduced energy consumption and improved environmental performance. → Upcycling tenants can make use of wastes to upgrade waste to a valuable product and/or energy source. → Energy systems for biofuel production have a large influence on the performance of biofuel industries.

Biofuels development in Sub-Saharan Africa: Are the policies conducive?

International Nuclear Information System (INIS)

Jumbe, Charles B.L.; Msiska, Frederick B.M.; Madjera, Michael

2009-01-01

This paper analyses national, regional and international biofuels policies and strategies to assess whether these policies promote or undermine the development of biofuels sector in Africa. Despite having a huge comparative advantage in land, labour and good climatic conditions favourable for the growing of energy crops, few countries in Sub-Saharan Africa have included biofuels strategies in their energy or national development policies. Further results show that while developed countries commit huge financial resources for research, technology development and the provision of tax-incentives to both producers and consumers, there is little government support for promoting biofuels in Africa. Although the consequences of biofuels on food supply remain uncertain, the mandatory blending of biofuels with fossil fuels by industrialized countries will create demand for land in Africa for the growing of energy crops for biofuels. This paper urgently calls upon national governments in Sub-Saharan Africa to develop appropriate strategies and regulatory frameworks to harness the potential economic opportunities from biofuels sector development, while protecting the environment and rural communities from the adverse effects of land alienation from the mainstream agriculture towards the growing of energy crops for biofuels at the expense of traditional food crops.

Biofuels development in Sub-Saharan Africa: Are the policies conducive?

Energy Technology Data Exchange (ETDEWEB)

Jumbe, Charles B.L., E-mail: charlesjumbe@bunda.unima.m [University of Malawi, Centre for Agricultural Research and Development, Bunda College, P.O. Box 219, Lilongwe (Malawi); Msiska, Frederick B.M., E-mail: frederickmsiska@yahoo.co [Ministry of Agriculture and Food Security, P.O. Box 30134, Lilongwe 3 (Malawi); Madjera, Michael, E-mail: michael.madjera@onlinehome.d [Evangelical Church in Middle Germany, P.O. Box 1424, 39004 Magdeburg (Germany)

2009-11-15

This paper analyses national, regional and international biofuels policies and strategies to assess whether these policies promote or undermine the development of biofuels sector in Africa. Despite having a huge comparative advantage in land, labour and good climatic conditions favourable for the growing of energy crops, few countries in Sub-Saharan Africa have included biofuels strategies in their energy or national development policies. Further results show that while developed countries commit huge financial resources for research, technology development and the provision of tax-incentives to both producers and consumers, there is little government support for promoting biofuels in Africa. Although the consequences of biofuels on food supply remain uncertain, the mandatory blending of biofuels with fossil fuels by industrialized countries will create demand for land in Africa for the growing of energy crops for biofuels. This paper urgently calls upon national governments in Sub-Saharan Africa to develop appropriate strategies and regulatory frameworks to harness the potential economic opportunities from biofuels sector development, while protecting the environment and rural communities from the adverse effects of land alienation from the mainstream agriculture towards the growing of energy crops for biofuels at the expense of traditional food crops.

Biofuels development in Sub-Saharan Africa. Are the policies conducive?

Energy Technology Data Exchange (ETDEWEB)

Jumbe, Charles B.L. [University of Malawi, Centre for Agricultural Research and Development, Bunda College, P.O. Box 219, Lilongwe (Malawi); Msiska, Frederick B.M. [Ministry of Agriculture and Food Security, P.O. Box 30134, Lilongwe 3 (Malawi); Madjera, Michael [Evangelical Church in Middle Germany, P.O. Box 1424, 39004 Magdeburg (Germany)

2009-11-15

This paper analyses national, regional and international biofuels policies and strategies to assess whether these policies promote or undermine the development of biofuels sector in Africa. Despite having a huge comparative advantage in land, labour and good climatic conditions favourable for the growing of energy crops, few countries in Sub-Saharan Africa have included biofuels strategies in their energy or national development policies. Further results show that while developed countries commit huge financial resources for research, technology development and the provision of tax-incentives to both producers and consumers, there is little government support for promoting biofuels in Africa. Although the consequences of biofuels on food supply remain uncertain, the mandatory blending of biofuels with fossil fuels by industrialized countries will create demand for land in Africa for the growing of energy crops for biofuels. This paper urgently calls upon national governments in Sub-Saharan Africa to develop appropriate strategies and regulatory frameworks to harness the potential economic opportunities from biofuels sector development, while protecting the environment and rural communities from the adverse effects of land alienation from the mainstream agriculture towards the growing of energy crops for biofuels at the expense of traditional food crops. (author)

The Brazilian biofuels industry

Directory of Open Access Journals (Sweden)

Goldemberg José

2008-05-01

Full Text Available Abstract Ethanol is a biofuel that is used as a replacement for approximately 3% of the fossil-based gasoline consumed in the world today. Most of this biofuel is produced from sugarcane in Brazil and corn in the United States. We present here the rationale for the ethanol program in Brazil, its present 'status' and its perspectives. The environmental benefits of the program, particularly the contribution of ethanol to reducing the emission of greenhouse gases, are discussed, as well as the limitations to its expansion.

Biological potential of microalgae in China for biorefinery-based production of biofuels and high value compounds.

Science.gov (United States)

Li, Jingjing; Liu, Ying; Cheng, Jay J; Mos, Michal; Daroch, Maurycy

2015-12-25

Microalgae abundance and diversity in China shows promise for identifying suitable strains for developing algal biorefinery. Numerous strains of microalgae have already been assessed as feedstocks for bioethanol and biodiesel production, but commercial scale algal biofuel production is yet to be demonstrated, most likely due to huge energy costs associated with algae cultivation, harvesting and processing. Biorefining, integrated processes for the conversion of biomass into a variety of products, can improve the prospects of microalgal biofuels by combining them with the production of high value co-products. Numerous microalgal strains in China have been identified as producers of various high value by-products with wide application in the medicine, food, and cosmetics industries. This paper reviews microalgae resources in China and their potential in producing liquid biofuels (bioethanol and biodiesel) and high value products in an integrated biorefinery approach. Implementation of a 'high value product first' principle should make the integrated process of fuels and chemicals production economically feasible and will ensure that public and private interest in the development of microalgal biotechnology is maintained. Copyright © 2015 Elsevier B.V. All rights reserved.

Biofuels from microbes

Energy Technology Data Exchange (ETDEWEB)

Antoni, D. [Technische Univ. Muenchen, Freising-Weihenstephan (Germany). Inst. of Resource and Energy Technology; Zverlov, V.V.; Schwarz, W.H. [Technische Univ. Muenchen, Freising-Weihenstephan (Germany). Dept. of Microbiology

2007-11-15

Today, biomass covers about 10% of the world's primary energy demand. Against a backdrop of rising crude oil prices, depletion of resources, political instability in producing countries and environmental challenges, besides efficiency and intelligent use, only biomass has the potential to replace the supply of an energy hungry civilisation. Plant biomass is an abundant and renewable source of energy-rich carbohydrates which can be efficiently converted by microbes into biofuels, of which, only bioethanol is produced on an industrial scale today. Biomethane is produced on a large scale, but is not yet utilised for transportation. Biobutanol is on the agenda of several companies and may be used in the near future as a supplement for gasoline, diesel and kerosene, as well as contributing to the partially biological production of butyl-t-butylether, BTBE as does bioethanol today with ETBE. Biohydrogen, biomethanol and microbially made biodiesel still require further development. This paper reviews microbially made biofuels which have potential to replace our present day fuels, either alone, by blending, or by chemical conversion. It also summarises the history of biofuels and provides insight into the actual production in various countries, reviewing their policies and adaptivity to the energy challenges of foreseeable future. (orig.)

The second generation biofuels from the biomass

International Nuclear Information System (INIS)

2007-01-01

The author takes stock on the second generation biofuels in the world, the recent technologies, their advantages, the research programs and the economical and environmental impacts of the biofuels development. (A.L.B.)

Thermodynamic evaluation of biomass-to-biofuels production systems

International Nuclear Information System (INIS)

Piekarczyk, Wodzisław; Czarnowska, Lucyna; Ptasiński, Krzysztof; Stanek, Wojciech

2013-01-01

Biomass is a renewable feedstock for producing modern energy carriers. However, the usage of biomass is accompanied by possible drawbacks, mainly due to limitation of land and water, and competition with food production. In this paper, the analysis concerns so-called second generation biofuels, like Fischer–Tropsch fuels or Substitute Natural Gas which are produced either from wood or from waste biomass. For these biofuels the most promising conversion case is the one which involves production of syngas from biomass gasification, followed by synthesis of biofuels. The thermodynamic efficiency of biofuels production is analyzed and compared using both the direct exergy analysis and the thermo-ecological cost. This analysis leads to the detection of exergy losses in various elements which forms the starting point to the improvement of conversion efficiency. The efficiency of biomass conversion to biofuels is also evaluated for the whole production chain, including biomass cultivation, transportation and conversion. The global effects of natural resources management are investigated using the thermo-ecological cost. The energy carriers' utilities such as electricity and heat are externally generated either from fossil fuels or from renewable biomass. In the former case the production of biofuels not always can be considered as a renewable energy source whereas in the latter case the production of biofuels leads always to the reduction of depletion of non-renewable resources

Low pressure catalytic co-conversion of biogenic waste (rapeseed cake) and vegetable oil.

Science.gov (United States)

Giannakopoulou, Kanellina; Lukas, Michael; Vasiliev, Aleksey; Brunner, Christoph; Schnitzer, Hans

2010-05-01

Zeolite catalysts of three types (H-ZSM-5, Fe-ZSM-5 and H-Beta) were tested in the catalytic co-conversion of rapeseed cake and safflower oil into bio-fuel. This low pressure process was carried out at the temperatures of 350 and 400 degrees Celsius. The yields and compositions of the product mixtures depended on the catalyst nature and the process temperatures. The produced organic phases consisted mainly of hydrocarbons, fatty acids and nitriles. This mixture possessed improved characteristics (e.g. heating value, water content, density, viscosity, pH) compared with the bio-oils, making possible its application as a bio-fuel. The most effective catalyst, providing the highest yield of organic liquid phase, was the highly acidic/wide-pore H-Beta zeolite. The products obtained on this catalyst demonstrated the highest degree of deoxygenation and the higher HHV (Higher Heating Value). The aqueous liquid phase contained water-soluble carboxylic acids, phenols and heterocyclic compounds. Copyright 2009 Elsevier Ltd. All rights reserved.

Detection of argan oil adulteration with vegetable oils by high-performance liquid chromatography-evaporative light scattering detection.

Science.gov (United States)

Salghi, Rachid; Armbruster, Wolfgang; Schwack, Wolfgang

2014-06-15

Triacylglycerol profiles were selected as indicator of adulteration of argan oils to carry out a rapid screening of samples for the evaluation of authenticity. Triacylglycerols were separated by high-performance liquid chromatography-evaporative light scattering detection. Different peak area ratios were defined to sensitively detect adulteration of argan oil with vegetable oils such as sunflower, soy bean, and olive oil up to the level of 5%. Based on four reference argan oils, mean limits of detection and quantitation were calculated to approximately 0.4% and 1.3%, respectively. Additionally, 19 more argan oil reference samples were analysed by high-performance liquid chromatography-refractive index detection, resulting in highly comparative results. The overall strategy demonstrated a good applicability in practise, and hence a high potential to be transferred to routine laboratories. Copyright © 2013 Elsevier Ltd. All rights reserved.

Bio-fuels barometer - EurObserv'ER - July 2016

International Nuclear Information System (INIS)

2016-07-01

The European bio-fuel market is now regulated by the directive, known as ILUC, whose wording focuses on the environmental impact of first generation bio-fuel development. This long-awaited clarification has arrived against the backdrop of falling oil prices and shrinking European Union bio-fuel consumption, which should drop by 1.7% between 2014 and 2015, according to EurObserv'ER

Biofuels barometer - EurObserv'ER - July 2016

International Nuclear Information System (INIS)

2016-07-01

The European biofuel market is now regulated by the directive, known as ILUC, whose wording focuses on the environmental impact of first generation biofuel development. This long-awaited clarification has arrived against the backdrop of falling oil prices and shrinking European Union biofuel consumption, which should drop by 1.7% between 2014 and 2015, according to EurObserv'ER

Integrated microbial processes for biofuels and high value-added products: the way to improve the cost effectiveness of biofuel production.

Science.gov (United States)

da Silva, Teresa Lopes; Gouveia, Luísa; Reis, Alberto

2014-02-01

The production of microbial biofuels is currently under investigation, as they are alternative sources to fossil fuels, which are diminishing and their use has a negative impact on the environment. However, so far, biofuels derived from microbes are not economically competitive. One way to overcome this bottleneck is the use of microorganisms to transform substrates into biofuels and high value-added products, and simultaneously taking advantage of the various microbial biomass components to produce other products of interest, as an integrated process. In this way, it is possible to maximize the economic value of the whole process, with the desired reduction of the waste streams produced. It is expected that this integrated system makes the biofuel production economically sustainable and competitive in the near future. This review describes the investigation on integrated microbial processes (based on bacteria, yeast, and microalgal cultivations) that have been experimentally developed, highlighting the importance of this approach as a way to optimize microbial biofuel production process.

Putting a green toe on the biofuels foot : determining and reducing the ecological footprint anticipated from accelerated biofuel development in Canada

International Nuclear Information System (INIS)

McIntyre, T.

2007-01-01

Results from recent Environment Canada (EC) research on punctuated life cycle analysis of biofuels and completed ongoing global benchmarking were presented. The purpose of the presentation was to demonstrate how the research community was responding to and organizing themselves for the biofuels opportunity/challenge agenda. The presentation provided a list of some of the environmental benefits of biofuels claimed in the public domain and identified potential environmental impact areas of concern. The author indicated that environmental data was not very robust and that this complex issue lends itself to a weak understanding of theoretical versus likely/achievable benefits. Other topics that were presented included biomass conversion technologies; the petrochemical distribution infrastructure in Canada; the biofuels distribution infrastructure; biofuel spill fate and behaviour; and the focus of EC's BEST research and development program. 2 tabs., 1 fig

Improving Biofuels Recovery Processes for Energy Efficiency and Sustainability

Science.gov (United States)

Biofuels are made from living or recently living organisms. For example, ethanol can be made from fermented plant materials. Biofuels have a number of important benefits when compared to fossil fuels. Biofuels are produced from renewable energy sources such as agricultural resou...

Policies for second generation biofuels: current status and future challenges

Energy Technology Data Exchange (ETDEWEB)

Egger, Haakan; Greaker, Mads; Potter, Emily

2011-07-01

Current state-of-the-art knowledge concludes that green house gas (GHG) emissions must be controlled and reduced within the next 30-40 years. The transport sector contributes almost a fifth of the current global emissions, and its share is likely to increase in the future. The US and a number of European countries have therefore introduced various support schemes for research and development (RandD) of low emission fuels that can potentially replace the current fossil fuels. One such alternative is biofuels. The advantage of biofuels are that it is easy to introduce into the transport sector. On the other hand, recent research papers question whether the supply of feedstock is sufficient, and to what extent biofuels lead to GHG emission reductions. This report reviews the current status of second generation biofuels. Second generation biofuels are made from cellulose, which according to our survey of the literature, is in more abundant supply than the first generation biofuels feedstocks. Furthermore, it seems to have the potential to reduce GHG emissions from the transport sector without leading to devastating land use changes, which recent critique has held against first generation biofuels. Given that governments have decided to support RandD of low emission fuels, we ask the following questions: Should second generation biofuels receive RandD support to the same extent as other low emission fuels like hydrogen? How should support schemes for second generation biofuels be designed? Second generation biofuels can be divided according to the production process into thermo-chemical and bio-chemical. With respect to the thermo-chemical process the potential for cost reductions seems to be low. On the other hand, ethanol made from cellulose using the biochemical conversion process is far from a ripe technology. Expert reports point to several potential technological breakthroughs which may reduce costs substantially. Hence, cellulosic ethanol, should receive direct

Biofuels for automobiles - an overview

Energy Technology Data Exchange (ETDEWEB)

Schaub, G. [Universitaet Karlsruhe, Engler-Bunte-Institut, Karlsruhe (Germany); Vetter, A. [Thueringer Landesanstalt fuer Landwirtschaft, Dornburg (Germany)

2008-05-15

Due to increasing oil prices and climate change concerns, biofuels have become more important as potential alternative energy sources. It is an open question as to which types of biofuels have the best yield potentials, characteristic properties and environmental consequences for providing the largest contribution to future energy requirements. Apart from the quality aspects, the question of quantity is very important, i.e., yields of biomass raw materials from agriculture and forestry as well as the conversion efficiencies/yields of the conversion process to automotive fuels. The most widely used biofuel forms today are fatty acid methyl esters and ethanol. However, in the future it is possible that synthetic hydrocarbons and hydrogen, produced via biotechnological or chemical processes may become feasible as fuel sources. Limitations in quantity are caused by net productivities of photosynthesis, which are limited by several factors, e.g., by the supply of water, limited availability of land, and conversion losses. As a consequence, biofuels as they exist can only contribute to a limited extent to securing raw material supplies for energy requirements in the future. Efficiency improvements in processing technologies and changes in consumer behavior and attitude will also be required. (Abstract Copyright [2008], Wiley Periodicals, Inc.)

Cadmium in the biofuel system

International Nuclear Information System (INIS)

Aabyhammar, T.; Fahlin, M.; Holmroos, S.

1993-12-01

Removal of biofuel depletes the soil of important nutrients. Investigations are being made of possibilities to return most of these nutrients by spreading the ashes remaining after combustion in the forest or on field. Return of ashes implies that both beneficial and harmful substances are returned. This study has been conducted to illustrate that the return of cadmium implies the greatest risk for negative influences. The occurrence, utilization, emissions and effects of cadmium are discussed. The behaviour of cadmium in soil is discussed in detail. Flows and quantities of cadmium in Swedish society are reviewed. Flows and quantities of both total and plant available cadmium in the entire forest and arable areas of Sweden are given. A scenario for a bioenergy system of max 100 TWh is discussed. The cadmium flow in different biofuels and forest raw products, and anticipated amounts of ashes and cadmium concentrations, are calculated. Power production from biofuels is surveyed. Possibilities to clean ashes have been examined in laboratory experiments. Ashes and trace elements occurring as a result of the gasification of biofuels are reviewed. Strategies for handling ashes are discussed. Proposals on continued inputs in both the biological and technical sciences are made. 146 refs, 23 figs, 38 tabs

Towards a sustainably certifiable futures contract for biofuels

International Nuclear Information System (INIS)

Mathews, John A.

2008-01-01

How are biofuels to be certified as produced in a sustainable and responsible fashion? In the global debate over this issue, one party to the proceedings seems rarely to be mentioned-namely the commodities exchanges through which a global biofuels market is being created. In this contribution, I propose a solution to the problem of sustainability certification through a biofuels futures contract equipped with 'proof of origin' documentation. The proposal does not call for any radical break with current practice, extending existing certification procedures with a requirement for the vendor to provide documentation, probably in barcoded form, of the history of the biofuel offered for sale, including plantation and biorefinery where the biofuel was produced and subsequent blendings it may have undergone. The proposal is thus compatible with the blending practices of large global traders, whose activities are the source of the difficulties of other approaches to certification. It is argued that if such a sustainable futures contract for bioethanol (in the first instance) were to be introduced, then it would likely trade at a premium and become the primary vehicle for North-South trade in biofuels

Biofuel and Food-Commodity Prices

Directory of Open Access Journals (Sweden)

David Zilberman

2012-09-01

Full Text Available The paper summarizes key findings of alternative lines of research on the relationship between food and fuel markets, and identifies gaps between two bodies of literature: one that investigates the relationship between food and fuel prices, and another that investigates the impact of the introduction of biofuels on commodity-food prices. The former body of literature suggests that biofuel prices do not affect food-commodity prices, but the latter suggests it does. We try to explain this gap, and then show that although biofuel was an important contributor to the recent food-price inflation of 2001–2008, its effect on food-commodity prices declined after the recession of 2008/09. We also show that the introduction of cross-price elasticity is important when explaining soybean price, but less so when explaining corn prices.

Biofuel initiatives in Japan: Strategies, policies, and future potential

International Nuclear Information System (INIS)

Matsumoto, Naoko; Sano, Daisuke; Elder, Mark

2009-01-01

Japan has developed a variety of national strategies and plans related to biofuels which address four main policy objectives, including reduction of greenhouse gas (GHG) emissions, energy security, rural development, and realisation of a recycle-based society. This paper reviews these national strategies and plans as well as associated implementing policies, and discusses the extent to which these objectives may be achieved. This paper found that the long-term potential of biofuels to contribute to GHG reduction goals will depend not only on the rates of technological development of the second generation biofuels but also on the development of other advanced vehicles. In the medium term, the potential contribution of biofuels to rural development and realising a recycle-based society could become significant depending on the progress of technology for both second generation biofuel production and the collection and transportation of their feedstocks. The potential contribution of biofuels to Japan's energy security is constrained by the availability of imports and the potential of domestic production. (author)

The water-land-food nexus of first-generation biofuels

Science.gov (United States)

Rulli, Maria Cristina; Bellomi, Davide; Cazzoli, Andrea; de Carolis, Giulia; D'Odorico, Paolo

2016-03-01

Recent energy security strategies, investment opportunities and energy policies have led to an escalation in biofuel consumption at the expenses of food crops and pastureland. To evaluate the important impacts of biofuels on food security, the food-energy nexus needs to be investigated in the context of its linkages with the overall human appropriation of land and water resources. Here we provide a global assessment of biofuel crop production, reconstruct global patterns of biofuel crop/oil trade and determine the associated displacement of water and land use. We find that bioethanol is mostly produced with domestic crops while 36% of biodiesel consumption relies on international trade, mainly from Southeast Asia. Altogether, biofuels rely on about 2-3% of the global water and land used for agriculture, which could feed about 30% of the malnourished population. We evaluate the food-energy tradeoff and the impact an increased reliance on biofuel would have on the number of people the planet can feed.

Vegetable oil and fat viscosity forecast models based on iodine number and saponification number

International Nuclear Information System (INIS)

Toscano, G.; Riva, G.; Foppa Pedretti, E.; Duca, D.

2012-01-01

Vegetable oil and fats can be considered as an important renewable source for the energy production. There are many applications where these biofuels are used directly in engines. However, the use of pure vegetable oils causes some problems as consequence of its chemical and physical characteristic. Viscosity is one of the most important parameters affecting several physical and mechanical processes of the operation of the engine. The determination of this parameter at different tis important to determine the behavior of the vegetable oil and fats. In this work we investigated the effects of two analytical chemical parameters (iodine number and saponification number) and forecasting models have been proposed. -- Highlights: ► Vegetable oil and fat viscosity is predicted by mathematical model based on saponification number and iodine number. ► Unsaturated vegetable oils with small size molecules of fatty acids have a lower viscosity values. ► The models proposed show an average error lower than 12%

Biomass upgrading by torrefaction for the production of biofuels: A review

International Nuclear Information System (INIS)

Stelt, M.J.C. van der; Gerhauser, H.; Kiel, J.H.A.; Ptasinski, K.J.

2011-01-01

An overview of the research on biomass upgrading by torrefaction for the production of biofuels is presented. Torrefaction is a thermal conversion method of biomass in the low temperature range of 200-300 o C. Biomass is pre-treated to produce a high quality solid biofuel that can be used for combustion and gasification. In this review the characteristics of torrefaction are described and a short history of torrefaction is given. Torrefaction is based on the removal of oxygen from biomass which aims to produce a fuel with increased energy density by decomposing the reactive hemicellulose fraction. Different reaction conditions (temperature, inert gas, reaction time) and biomass resources lead to various solid, liquid and gaseous products. A short overview of the different mass and energy balances is presented. Finally, the technology options and the most promising torrefaction applications and their economic potential are described. -- Highlights: → We reviewed recent developments in biomass upgrading by torrefaction. → Torrefaction improves biomass to a high quality solid fuel. → Main advantages of torrefaction are improvement of energy density and grindability. → Further research on kinetics is recommended for design of torrefaction reactor.

Synthetic biology and the technicity of biofuels.

Science.gov (United States)

Mackenzie, Adrian

2013-06-01

The principal existing real-world application of synthetic biology is biofuels. Several 'next generation biofuel' companies-Synthetic Genomics, Amyris and Joule Unlimited Technologies-claim to be using synthetic biology to make biofuels. The irony of this is that highly advanced science and engineering serves the very mundane and familiar realm of transport. Despite their rather prosaic nature, biofuels could offer an interesting way to highlight the novelty of synthetic biology from several angles at once. Drawing on the French philosopher of technology and biology Gilbert Simondon, we can understand biofuels as technical objects whose genesis involves processes of concretisation that negotiate between heterogeneous geographical, biological, technical, scientific and commercial realities. Simondon's notion of technicity, the degree of concretisation of a technical object, usefully conceptualises this relationality. Viewed in terms of technicity, we might understand better how technical entities, elements, and ensembles are coming into being in the name of synthetic biology. The broader argument here is that when we seek to identify the newness of disciplines, their newness might be less epistemic and more logistic. Crown Copyright © 2013. Published by Elsevier Ltd. All rights reserved.

High Relative Abundance of Biofuel Sourced Ethanol in Precipitation in the US and Brazil Determined Using Compound Specific Stable Carbon Isotopes

Science.gov (United States)

Shimizu, M. S.; Felix, J. D. D.; Casas, M.; Avery, G. B., Jr.; Kieber, R. J.; Mead, R. N.; Willey, J. D.; Lane, C.

2017-12-01

Ethanol biofuel production and consumption have increased exponentially over the last two decades to help reduce greenhouse gas emissions. Currently, 85% of global ethanol production and consumption occurs in the US and Brazil. Increasing biofuel ethanol usage in these two countries enhances emissions of uncombusted ethanol to the atmosphere contributing to poor air quality. Although measurements of ethanol in the air and the precipitation reveal elevated ethanol concentrations in densely populated cities, other sources such as natural vegetation can contribute to emission to the atmosphere. Previous modeling studies indicated up to 12% of atmospheric ethanol is from anthropogenic emissions. Only one gas phase study in southern Florida attempted to constrain the two sources through direct isotopic measurements. The current study used a stable carbon isotope method to constrain sources of ethanol in rainwater from the US and Brazil. A method was developed using solid phase microextraction (SPME) with subsequent analysis by gas chromatography-combustion-isotope ratio mass spectrometry (GC-C-IRMS). Stable carbon isotope signatures (δ13C) of vehicle ethanol emission sources for both the US (-9.8‰) and Brazil (-12.7‰) represented C4 plants as feedstock (corn and sugarcane) for biofuel production. An isotope mixing model using biofuel from vehicles (C4 plants) and biogenic (C3 plants) end-members was implemented to estimate ethanol source apportionment in the rain. We found that stable carbon isotope ratio of ethanol in the rain ranged between -22.6‰ and -12.7‰. Our results suggest that the contribution of biofuel to atmospheric ethanol can be higher than previously estimated. As biofuel usage increasing globally, it is essential to determine the relative abundance of anthropogenic ethanol in other areas of the world.

Lipid extraction from microalgae using a single ionic liquid

Science.gov (United States)

Salvo, Roberto Di; Reich, Alton; Dykes, Jr., H. Waite H.; Teixeira, Rodrigo

2013-05-28

A one-step process for the lysis of microalgae cell walls and separation of the cellular lipids for use in biofuel production by utilizing a hydrophilic ionic liquid, 1-butyl-3-methylimidazolium. The hydrophilic ionic liquid both lyses the microalgae cell walls and forms two immiscible layers, one of which consists of the lipid contents of the lysed cells. After mixture of the hydrophilic ionic liquid with a suspension of microalgae cells, gravity causes a hydrophobic lipid phase to move to a top phase where it is removed from the mixture and purified. The hydrophilic ionic liquid is recycled to lyse new microalgae suspensions.

Fuel production from biomass: generation of liquid biofuels

Directory of Open Access Journals (Sweden)

Carmen Ghergheleş

2008-05-01

Full Text Available Anaerobic fermentation processes mayalso be used to produce liquid fuels frombiological raw materials. An example is theethanol production from glucose, known asstandard yeast fermentation in the beer, wine andliquor industries. It has to take place in steps, suchthat the ethanol is removed (by distillation ordehydrator application whenever itsconcentration approaches a value (around 12%which would impede reproduction of the yeastculture.

Session 8: biofuels; Session 8: Les biocarburants

Energy Technology Data Exchange (ETDEWEB)

Botte, J.M.

2006-01-15

Here are given the summaries of the speeches of Mr Daniel Le Breton (Total): the transports of the future: the role of biofuels; of Mr Pierre Rouveirolles (Renault): the future expectations and needs; of Mr Frederic Monot (IFP): the developments of new generations of biofuels from biomass; of Mr Willem Jan Laan (Unilever): the use of bio resources for food and fuel: a fair competition? All these speeches have been presented at the AFTP yearly days (12-13 october 2005) on the session 8 concerning the biofuels. (O.M.)

Improving EU biofuels policy?

DEFF Research Database (Denmark)

Swinbank, Alan; Daugbjerg, Carsten

2013-01-01

to be 'like' a compliant biofuel. A more economically rational way to reduce GHG emissions, and one that might attract greater public support, would be for the RED to reward emission reductions along the lines of the FQD. Moreover, this modification would probably make the provisions more acceptable...... in the WTO, as there would be a clearer link between policy measures and the objective of reductions in GHG emissions; and the combination of the revised RED and the FQD would lessen the commercial incentive to import biofuels with modest GHG emission savings, and thus reduce the risk of trade tension....

Biofuels, poverty, and growth

DEFF Research Database (Denmark)

Arndt, Channing; Benfica, Rui; Tarp, Finn

2010-01-01

and accrual of land rents to smallholders, compared with the more capital-intensive plantation approach. Moreover, the benefits of outgrower schemes are enhanced if they result in technology spillovers to other crops. These results should not be taken as a green light for unrestrained biofuels development...... Mozambique's annual economic growth by 0.6 percentage points and reduces the incidence of poverty by about 6 percentage points over a 12-year phase-in period. Benefits depend on production technology. An outgrower approach to producing biofuels is more pro-poor, due to the greater use of unskilled labor...

Renewable Energy Laboratory Development for Biofuels Advanced Combustion Studies

Energy Technology Data Exchange (ETDEWEB)

Soloiu, Valentin A. [Georgia Southern Univ., Statesboro, GA (United States)

2012-03-31

The research advanced fundamental science and applied engineering for increasing the efficiency of internal combustion engines and meeting emissions regulations with biofuels. The project developed a laboratory with new experiments and allowed investigation of new fuels and their combustion and emissions. This project supports a sustainable domestic biofuels and automotive industry creating economic opportunities across the nation, reducing the dependence on foreign oil, and enhancing U.S. energy security. The one year period of research developed fundamental knowledge and applied technology in advanced combustion, emissions and biofuels formulation to increase vehicle's efficiency. Biofuels combustion was investigated in a Compression Ignition Direct Injection (DI) to develop idling strategies with biofuels and an Indirect Diesel Injection (IDI) intended for auxiliary power unit.

Catalytic pyrolysis of microalgae to high-quality liquid bio-fuels

International Nuclear Information System (INIS)

Babich, I.V.; Hulst, M. van der; Lefferts, L.; Moulijn, J.A.; O'Connor, P.; Seshan, K.

2011-01-01

The pyrolytic conversion of chlorella algae to liquid fuel precursor in presence of a catalyst (Na 2 CO 3 ) has been studied. Thermal decomposition studies of the algae samples were performed using TGA coupled with MS. Liquid oil samples were collected from pyrolysis experiments in a fixed-bed reactor and characterized for water content and heating value. The oil composition was analyzed by GC-MS. Pretreatment of chlorella with Na 2 CO 3 influences the primary conversion of chlorella by shifting the decomposition temperature to a lower value. In the presence of Na 2 CO 3 , gas yield increased and liquid yield decreased when compared with non-catalytic pyrolysis at the same temperatures. However, pyrolysis oil from catalytic runs carries higher heating value and lower acidity. Lower content of acids in the bio-oil, higher aromatics, combined with higher heating value show promise for production of high-quality bio-oil from algae via catalytic pyrolysis, resulting in energy recovery in bio-oil of 40%. -- Highlights: → The pyrolytic catalytic conversion of chlorella algae to liquid fuel precursor. → Na 2 CO 3 as a catalyst for the primary conversion of chlorella. → Pyrolysis oil from catalytic runs carries higher heating value and lower acidity. → High-quality bio-oil from algae via catalytic pyrolysis with energy recovery in bio-oil of 40%.

Biofuels. Is the curse worse than the disease?

International Nuclear Information System (INIS)

Doornbosch, R.; Steenblik, R.

2007-09-01

Biofuels have been championed as an energy source that can increase security of supply, reduce vehicle emissions and provide a new income stream for farmers. These claims are contested, however. Critics assert that biofuels will increase energy-price volatility, food prices and even life-cycle emissions of greenhouse gases. This paper presents salient facts and figures to shed light on these controversial issues and asks whether biofuels offer a cure that is worse than the disease they seek to heal. The information gathered in this paper gives rise to two fundamental questions: (1) Do the technical means exist to produce biofuels in ways that enable the world to meet demand for transportation energy in more secure and less harmful ways, on a meaningful scale and without compromising the ability to feed a growing population?; and (2) Do current national and international policies that promote the production of biofuels represent the most cost-effective means of using biomass and the best way forward for the transport sector?

Supply Chain Sustainability Analysis of Three Biofuel Pathways

Energy Technology Data Exchange (ETDEWEB)

Jacob J. Jacobson; Erin Searcy; Kara Cafferty; Jennifer B. Dunn; Michael Johnson; Zhichao Wang; Michael Wang; Mary Biddy; Abhijit Dutta; Daniel Inman; Eric Tan; Sue Jones; Lesley Snowden-Swan

2013-11-01

The Department of Energy’s (DOE) Bioenergy Technologies Office (BETO) collaborates with industrial, agricultural, and non-profit partners to develop and deploy biofuels and other biologically-derived products. As part of this effort, BETO and its national laboratory teams conduct in-depth techno-economic assessments (TEA) of technologies to produce biofuels as part state of technology (SOT) analyses. An SOT assesses progress within and across relevant technology areas based on actual experimental results relative to technical targets and cost goals from design cases and includes technical, economic, and environmental criteria as available. Overall assessments of biofuel pathways begin with feedstock production and the logistics of transporting the feedstock from the farm or plantation to the conversion facility or biorefinery. The conversion process itself is modeled in detail as part of the SOT analysis. The teams then develop an estimate of the biofuel minimum selling price (MSP) and assess the cost competitiveness of the biofuel with conventional fuels such as gasoline.

Will EU Biofuel Policies affect Global Agricultural Markets?

International Nuclear Information System (INIS)

Banse, M.; Vvan Meijl, H.; Tabeau, A.; Woltjer, G.

2008-04-01

This paper assesses the global and sectoral implications of the European Union Biofuels Directive (BFD) in a multi-region computable general equilibrium framework with endogenous determination of land supply. The results show that, without mandatory blending policies or subsidies to stimulate the use of biofuel crops in the petroleum sector, the targets of the BFD will not be met in 2010 and 2020. With a mandatory blending policy, the enhanced demand for biofuel crops has a strong impact on agriculture at the global and European levels. The additional demand from the energy sector leads to an increase in global land use and, ultimately, a decrease in biodiversity. The development, on the other hand, might slow or reverse the long-term process of declining real agricultural prices. Moreover, assuming a further liberalization of the European agricultural market imports of biofuels are expected to increase to more than 50% of the total biofuel demand in Europe

Assessment of environmental stresses for enhanced microalgal biofuel production-an overview

Directory of Open Access Journals (Sweden)

Dan eCheng

2014-07-01

Full Text Available Microalgal biofuels are currently considered to be the most promising alternative to future renewable energy source. Microalgae have great potential to produce various biofuels, including biodiesel, bioethanol, biomethane, and biohydrogen. Cultivation of biofuel-producing microalgae demands favorable environmental conditions, such as suitable light, temperature, nutrients, salinity, and pH. However, these conditions are not always compatible with the conditions beneficial to biofuel production, because biofuel-related compounds (such as lipids and carbohydrates tend to accumulate under environmental-stress conditions of light, temperature, nutrient, and salt. This paper presents a brief overview of the effects of environmental conditions on production of microalgal biomass and biofuel, with specific emphasis on how to utilize environmental stresses to improve biofuel productivity. The potential avenues of reaping the benefits of enhanced biofuel production by environmental stresses while maintaining high yields of biomass production have been discussed.

Current status: biomass valorisation and biofuels in Singapore

International Nuclear Information System (INIS)

Guermont, C.; Barbi, A.P.

2010-05-01

After having briefly presented the main types of biofuels (bio-ethanol, bio-diesel) and their first, second and third generation technologies to produce them (from food crops, from non food crops, and from algae), this report presents Singapore public R and D centres working in the field of biofuels development, and their activities. It also presents actors belonging to the private sector, and various realized and announced projects on biofuels

Carbon and environmental footprinting of global biofuel production

OpenAIRE

Hammond, Geoff P.; Seth, S.M.

2013-01-01

The carbon and environmental footprints associated with the global production of biofuels have been computed from a baseline of 2007-2009 out until 2019. Estimates of future global biofuel production were adopted from OECD-FAO and related projections. In order to determine the footprints associated with these (essentially 'first generation') biofuel resources, the overall environmental footprint was disaggregated into bioproductive land, built land, carbon, embodied energy, materials and wast...

Streamflow impacts of biofuel policy-driven landscape change.

Directory of Open Access Journals (Sweden)

Sami Khanal

Full Text Available Likely changes in precipitation (P and potential evapotranspiration (PET resulting from policy-driven expansion of bioenergy crops in the United States are shown to create significant changes in streamflow volumes and increase water stress in the High Plains. Regional climate simulations for current and biofuel cropping system scenarios are evaluated using the same atmospheric forcing data over the period 1979-2004 using the Weather Research Forecast (WRF model coupled to the NOAH land surface model. PET is projected to increase under the biofuel crop production scenario. The magnitude of the mean annual increase in PET is larger than the inter-annual variability of change in PET, indicating that PET increase is a forced response to the biofuel cropping system land use. Across the conterminous U.S., the change in mean streamflow volume under the biofuel scenario is estimated to range from negative 56% to positive 20% relative to a business-as-usual baseline scenario. In Kansas and Oklahoma, annual streamflow volume is reduced by an average of 20%, and this reduction in streamflow volume is due primarily to increased PET. Predicted increase in mean annual P under the biofuel crop production scenario is lower than its inter-annual variability, indicating that additional simulations would be necessary to determine conclusively whether predicted change in P is a response to biofuel crop production. Although estimated changes in streamflow volume include the influence of P change, sensitivity results show that PET change is the significantly dominant factor causing streamflow change. Higher PET and lower streamflow due to biofuel feedstock production are likely to increase water stress in the High Plains. When pursuing sustainable biofuels policy, decision-makers should consider the impacts of feedstock production on water scarcity.

Biofuels for transport in Europe: lessons from Germany and the UK

International Nuclear Information System (INIS)

Bomb, C.; McCormick, K.; Kaaberger, T.; Lund University, Lund

2007-01-01

The utilisation of biofuels is attracting growing support from the European Union and member states as a strategy to tackle climate change, enhance energy security, and contribute to regional development. This paper describes, compares, and analyses the markets for biofuels in Germany and the UK. The introduction of biofuels for transport in these member states provides contrasting pictures, and the success or failure of biofuels here is pertinent to the development and diffusion of biofuels across Europe. This paper concentrates on the socio-political context for the biofuels industry in Germany and the UK, discusses the lessons learned from the German and British experiences, and presents general conclusions for policy-makers that are predominantly relevant for the early stages of a biofuels industry. (author)

The Biofuels Revolution: Understanding the Social, Cultural and Economic Impacts of Biofuels Development on Rural Communities

Energy Technology Data Exchange (ETDEWEB)

Selfa, Theresa L; Goe, Richard; Kulcsar, Laszlo; Middendorf, Gerad; Bain, Carmen

2013-02-11

The aim of this research was an in-depth analysis of the impacts of biofuels industry and ethanol plants on six rural communities in the Midwestern states of Kansas and Iowa. The goal was to provide a better understanding of the social, cultural, and economic implications of biofuels development, and to contribute to more informed policy development regarding bioenergy.Specific project objectives were: 1. To understand how the growth of biofuel production has affected and will affect Midwestern farmers and rural communities in terms of economic, demographic, and socio-cultural impacts; 2. To determine how state agencies, groundwater management districts, local governments and policy makers evaluate or manage bioenergy development in relation to competing demands for economic growth, diminishing water resources, and social considerations; 3. To determine the factors that influence the water management practices of agricultural producers in Kansas and Iowa (e.g. geographic setting, water management institutions, competing water-use demands as well as producers attitudes, beliefs, and values) and how these influences relate to bioenergy feedstock production and biofuel processing; 4. To determine the relative importance of social-cultural, environmental and/or economic factors in the promotion of biofuels development and expansion in rural communities; The research objectives were met through the completion of six detailed case studies of rural communities that are current or planned locations for ethanol biorefineries. Of the six case studies, two will be conducted on rural communities in Iowa and four will be conducted on rural communities in Kansas. A multi-method or mixed method research methodology was employed for each case study.

Algae biofuels: versatility for the future of bioenergy.

Science.gov (United States)

Jones, Carla S; Mayfield, Stephen P

2012-06-01

The world continues to increase its energy use, brought about by an expanding population and a desire for a greater standard of living. This energy use coupled with the realization of the impact of carbon dioxide on the climate, has led us to reanalyze the potential of plant-based biofuels. Of the potential sources of biofuels the most efficient producers of biomass are the photosynthetic microalgae and cyanobacteria. These versatile organisms can be used for the production of bioethanol, biodiesel, biohydrogen, and biogas. In fact, one of the most economic methods for algal biofuels production may be the combined biorefinery approach where multiple biofuels are produced from one biomass source. Copyright © 2011 Elsevier Ltd. All rights reserved.

Forecast for biofuel trade in Europe

International Nuclear Information System (INIS)

Hektor, B.; Vinterbaeck, J.; Toro, A.de; Nilsson, Daniel

1993-01-01

One principal general conclusion is that the European biofuel market for the period up to the year 2000 will be competitive, dynamic and affected by technical development and innovations. That leads to the conclusion that prices will go down, which will increase the ability of biofuels to compete in the market. Still, biofuels will generally not be able to compete at the price level of fossil fuels in the world market, but will need support or protection to reach a competitive position. There are several reasons for support, e.g. offsetting the green-house effect and acid rain, conservation of the limited fossil fuel deposits, utilisation of local and domestic energy resources, etc. As energy crops in Europe are at an introductory stage, no large international trade can be expected within the next ten years. In this study it is assumed that some limited protective measures are imposed, which is a possible result of the energy and environmental policy currently discussed for the European Community, EC. The study implies that in the year 2000 it is possible to transport large quantities of biofuels to large energy consumers if taxes and other incentives now under discussion in the EC and national governments are introduced. The study also implies that in the year 2000 it is possible to utilise biofuels primarily in local and national markets. In the latter case, international trade will be reduced to minor spot quantities

[Progress in synthesis technologies and application of aviation biofuels].

Science.gov (United States)

Sun, Xiaoying; Liu, Xiang; Zhao, Xuebing; Yang, Ming; Liu, Dehua

2013-03-01

Development of aviation biofuels has attracted great attention worldwide because that the shortage of fossil resources has become more and more serious. In the present paper, the development background, synthesis technologies, current application status and existing problems of aviation biofuels were reviewed. Several preparation routes of aviation biofuels were described, including Fischer-Tropsch process, catalytic hydrogenation and catalytic cracking of bio-oil. The status of flight tests and commercial operation were also introduced. Finally the problems for development and application of aviation biofuels were stated, and some accommodation were proposed.

Livelihood implications of biofuel crop production: Implications for governance

DEFF Research Database (Denmark)

Hunsberger, Carol; Bolwig, Simon; Corbera, Esteve

2014-01-01

While much attention has focused on the climate change mitigation potential of biofuels, research from the social sciences increasingly highlights the social and livelihood impacts of their expanded production. Policy and governance measures aimed at improving the social effects of biofuels have...... by their cultivation in the global South – income, food security, access to land-based resources, and social assets – revealing that distributional effects are crucial to evaluating the outcomes of biofuel production across these dimensions. Second, we ask how well selected biofuel governance mechanisms address...

Biofuel Sustainability and the Formation of Transnational Hybrid Governance

DEFF Research Database (Denmark)

Ponte, Stefano; Daugbjerg, Carsten

2015-01-01

We examine the transnational governance of biofuel sustainability and its coexistence with the WTO trade regime. The way in which the EU Renewable Energy Directive (RED) is shaping transnational biofuel governance shows deep and mutual dependence between public and private. The EU relies on a pri......We examine the transnational governance of biofuel sustainability and its coexistence with the WTO trade regime. The way in which the EU Renewable Energy Directive (RED) is shaping transnational biofuel governance shows deep and mutual dependence between public and private. The EU relies...

The development of the biofuels in the french farms

International Nuclear Information System (INIS)

Treguer, D.; Sourie, J.C.

2005-03-01

At first, developed to compensate the farmers incomes after 1993, the biofuels are going today on a second development phase, in the framework of the Kyoto protocol. The aim of this paper is to define the particularities of the biofuels production agricultural phase. The most important aspects of the common agricultural policy (PAC) for the biofuels are underlined. The costs of the raw material and the tool developed by the INRA to estimate the biofuels costs are also presented. In conclusion the authors propose some reference results. (A.L.B.)

Direct observation of the release of alkali vapor species in biofuel combustion and gasification

Energy Technology Data Exchange (ETDEWEB)

French, R.J.; Milne, T.A. [National Renewable Energy Lab., Golden, CO (United States)

1993-12-31

The largest present use of biomass for energy is in combustion for steam and electrical power. Biofuels have an acknowledged advantage over coal as a solid fuel because of their low sulfur and ash content. However, some forms of biomass have substantial quantities of alkali metals and chlorine. In addition, evidence indicates that the alkali in biomass is largely atomically dispersed, resulting in its facile mobilization into the gas-phase. Gaseous alkali compounds aggravate problems of slagging, fouling, and corrosion on heat transfer surfaces in present-day boilers. These problems can be particularly severe when mixed and variable agricultural residues are burned. Furthermore, the next generation of biomass-to-power systems will likely involve combined cycle gas turbines, where alkali tolerances are especially restrictive. In this paper, we report on laboratory studies in which biofuels are combusted under simulated turbine or boiler-firing conditions. Gaseous alkali, sulfur, nitrogen, and halogen-containing species are measured by direct extraction from the hot gases through molecular-beam mass spectrometry (MBMS). The experimental apparatus will be described and its capability illustrated with results of time-resolved evolution of species like K, KCl, KOH, SO{sub 2} and NO{sub x} from small samples of biomass in combustion environments. The nature and release of such species will be explicated by referring to thermodynamic equilibrium predictions and the form of alkali in solid, gaseous, and liquid biofuels.

Glucose oxidase/cellulose-carbon nanotube composite paper as a biocompatible bioelectrode for biofuel cells.

Science.gov (United States)

Won, Keehoon; Kim, Young-Hoo; An, Seulji; Lee, Hye Jung; Park, Saerom; Choi, Yong-Keun; Kim, Ji Hyeon; Hwang, Hak-In; Kim, Hyung Joo; Kim, Hyungsup; Lee, Sang Hyun

2013-11-01

Biofuel cells are devices for generating electrical energy directly from chemical energy of renewable biomass using biocatalysts such as enzymes. Efficient electrical communication between redox enzymes and electrodes is essential for enzymatic biofuel cells. Carbon nanotubes (CNTs) have been recognized as ideal electrode materials because of their high electrical conductivity, large surface area, and inertness. Electrodes consisting entirely of CNTs, which are known as CNT paper, have high surface areas but are typically weak in mechanical strength. In this study, cellulose (CL)-CNT composite paper was fabricated as electrodes for enzymatic biofuel cells. This composite electrode was prepared by vacuum filtration of CNTs followed by reconstitution of cellulose dissolved in ionic liquid, 1-ethyl-3-methylimidazolium acetate. Glucose oxidase (GOx), which is a redox enzyme capable of oxidizing glucose as a renewable fuel using oxygen, was immobilized on the CL-CNT composite paper. Cyclic voltammograms revealed that the GOx/CL-CNT paper electrode showed a pair of well-defined peaks, which agreed well with that of FAD/FADH2, the redox center of GOx. This result clearly shows that the direct electron transfer (DET) between the GOx and the composite electrode was achieved. However, this DET was dependent on the type of CNTs. It was also found that the GOx immobilized on the composite electrode retained catalytic activity for the oxidation of glucose.

Environmental effect of constructed wetland as biofuel production system

Science.gov (United States)

Liu, Dong

2017-04-01

Being as a renewable energy, biofuel has attracted worldwide attention. Clean biofuel production is an effective way to mitigate global climate change and energy crisis. Biofuel may offer a promising alternative to fossil fuels, but serious concerns arise about the adverse greenhouse gas consequences from using nitrogen fertilizers. Waste-nitrogen recycling is an attractive idea. Here we advocate a win-win approach to biofuel production which takes advantage of excessive nitrogen in domestic wastewater treated via constructed wetland (CW) in China. This study will carry on environmental effect analysis of CW as a biomass generation system through field surveys and controllable simulated experiments. This study intends to evaluate net energy balance, net greenhouse effect potential and ecosystem service of CW as biomass generation system, and make comparation with traditional wastewater treatment plant and other biofuel production systems. This study can provide a innovation mode in order to solve the dilemma between energy crops competed crops on production land and excessive nitrogen fertilizer of our traditional energy plant production. Data both from our experimental CWs in China and other researches on comparable CWs worldwide showed that the biomass energy yield of CWs can reach 182.3 GJ ha-1 yr-1, which was two to eight times higher than current biofuel-production systems. Energy output from CW was ˜137% greater than energy input for biofuel production. If CWs are designed with specific goal of biofuel production, biofuel production can be greatly enhanced through the optimization of N supply, hydraulic structures, and species selection in CWs. Assuming that 2.0 Tg (1 Tg = 1012 g) waste nitrogen contained in domestic wastewater is treated by CWs, biofuel production can account for 1.2% of national gasoline consumption in China. The proportion would increase to 6.7% if extra nitrogen (9.5 Tg) from industrial wastewater and agricultural runoff was included

Heterologous Synthesis and Recovery of Advanced Biofuels from Bacterial Cell Factories.

Science.gov (United States)

Malik, Sana; Afzal, Ifrah; Mehmood, Muhammad Aamer; Al Doghaither, Huda; Rahimuddin, Sawsan Abdulaziz; Gull, Munazza; Nahid, Nazia

2018-01-01

Microbial engineering to produce advanced biofuels is currently the most encouraging approach in renewable energy. Heterologous synthesis of biofuels and other useful industrial chemicals using bacterial cell factories has radically diverted the attentions from the native synthesis of these compounds. However, recovery of biofuels from the media and cellular toxicity are the main hindrances to successful commercialization of advanced biofuels. Therefore, membrane transporter engineering is gaining increasing attentions from all over the world. The main objective of this review is to explore the ways to increase the microbial production of biofuels by counteracting the cellular toxicity and facilitating their easier recovery from media. Microbial synthesis of industrially viable compounds such as biofuels has been increased due to genomic revolution. Moreover, advancements in protein engineering, gene regulation, pathway portability, metabolic engineering and synthetic biology led the focus towards the development of robust and cost-effective systems for biofuel production. The most convenient way to combat cellular toxicity and to secrete biofuels is the use of membrane transport system. The use of membrane transporters is currently a serious oversight as do not involve chemical changes and contribute greatly to efflux biofuels in extracellular milieu. However, overexpression of transport systems can also be detrimental to cell, so, in future, structure-based engineering of transporters can be employed to evaluate optimum expression range, to increase biofuel specificity and transport rate through structural studies of biofuel molecules. Copyright© Bentham Science Publishers; For any queries, please email at epub@benthamscience.org.

Determination of calorific values of some renewable biofuels

Energy Technology Data Exchange (ETDEWEB)

Kumar, Jothi V.; Pratt, Benjamin C. [Department of Chemistry, North Carolina A and T State University, Greensboro, North Carolina (United States)

1996-06-01

Thermal methods such as differential scanning calorimetry (DSC), and elemental analysis (EA) were employed to determine the calorific values of some renewable biofuels either directly or indirectly. The biofuels tested were the common milkweed, dogbane, kudzu, and eucalyptus tree. The purpose of this work was to optimize the experimental conditions for DSC analysis of biofuels, improve the calorific values by adding metal oxides as catalysts, and compare the heat values between DSC and EA analyses

Wind versus Biofuels for Addressing Climate, Health, and Energy

International Nuclear Information System (INIS)

Jacobson, Mark Z.

2007-01-01

The favored approach today for addressing global warming is to promote a variety of options: biofuels, wind, solar thermal, solar photovoltaic, geothermal, hydroelectric, and nuclear energy and to improve efficiency. However, by far, most emphasis has been on biofuels. It is shown here, though, that current-technology biofuels cannot address global warming and may slightly increase death and illness due to ozone-related air pollution. Future biofuels may theoretically slow global warming, but only temporarily and with the cost of increased air pollution mortality. In both cases, the land required renders biofuels an impractical solution. Recent measurements and statistical analyses of U.S. and world wind power carried out at Stanford University suggest that wind combined with other options can substantially address global warming, air pollution mortality, and energy needs simultaneously.

O governo e a mídia na configuração do macroambiente para os biocombustíveis líquidos no Brasil Government and media in the configuration of the macroenvironment for liquid biofuels in Brazil

Directory of Open Access Journals (Sweden)

Edson Talamini

2009-04-01

Full Text Available Este artigo identifica as dimensões nas quais o governo e a mídia do Brasil têm configurado o macroambiente para os biocombustíveis líquidos ao longo do tempo e testam a existência de similaridade entre esses meios de expressão da sociedade na configuração do macroambiente. Para atingir o objetivo, foi realizada uma pesquisa documental a partir das notícias sobre o tema "biocombustíveis líquidos" veiculadas pela mídia escrita e de documentos oficiais do governo brasileiro tratando do mesmo tema. Foram coletados documentos textuais em formato eletrônico para um período de 10 anos (1997 a 2006. A extração do conhecimento dos textos em formato eletrônico foi realizada por meio de mineração em textos, aplicando-se uma estrutura de análise específica contendo as dimensões macroambientais e suas respectivas "palavras-d", que foram definidas a partir das palavras mais frequentes nas áreas do conhecimento relacionadas a cada dimensão. Os resultados indicam que a configuração do macroambiente para os biocombustíveis líquidos pela mídia e pelo governo difere quanto ao uso das dimensões macroambientais. A configuração do macroambiente também apresentou variações ao longo do período analisado, tanto na mídia quanto no governo. Testes de similaridade, aderência e homogeneidade confirmam a existência de diferenças entre a mídia e o governo. As implicações dos resultados encontrados para a atividade de escaneamento macroambiental destinado ao planejamento estratégico das organizações em geral e dos biocombustíveis líquidos em particular são discutidas.This article identifies the dimensions in which the Brazilian government and the media have shaped the macroenvironment for liquid biofuels through time, and tests the similarities among these means of expression of the society in the macroenvironmental setting. It conducts a documental research of the news on liquid biofuels published by the press and of official

Microalgae: biofuel production

Directory of Open Access Journals (Sweden)

Babita Kumari

2013-04-01

Full Text Available In the present day, microalgae feedstocks are gaining interest in energy scenario due to their fast growth potential coupled with relatively high lipid, carbohydrate and nutrients contents. All of these properties render them an excellent source for biofuels such as biodiesel, bioethanol and biomethane; as well as a number of other valuable pharmaceutical and nutraceutical products. The present review is a critical appraisal of the commercialization potential of microalgae biofuels. The available literature on various aspects of microalgae for e.g. its cultivation, life cycle assessment, and conceptualization of an algal biorefinery, has been done. The evaluation of available information suggests the operational and maintenance cost along with maximization of oil-rich microalgae production is the key factor for successful commercialization of microalgae-based fuels.

Bio-fuels of the first generation

International Nuclear Information System (INIS)

2012-04-01

After having briefly recalled the objective of use of renewable energies and the role bio-fuels may play, this publication briefly presents various bio-fuels: bio-diesel (from colza, soybean or sunflower oil), and ethanol (from beet, sugar cane, wheat or corn). Some key data regarding bio-fuel production and use in France are briefly commented. The publication outlines strengths (a positive energy assessment, a decreased dependency on imported fossil fuels and a higher supply safety, a diversification of agriculture revenues and prospects, a reduction of greenhouse gas emissions) and weaknesses (uncertainty regarding the evolution of soil use, an environmental impact related to farming methods) of this sector. Actions undertaken by the ADEME in collaboration with other agencies and institutions are briefly overviewed

Global nitrogen requirement for increased biofuel production

NARCIS (Netherlands)

Flapper, Joris

2008-01-01

Biofuels are thought to be one of the options to substitute fossil fuels and prevent global warming by the greenhouse gas (GHG) effect as they are seen as a renewable form of energy. However, biofuels are almost solely subjected to criticism from an energ

A model for improving microbial biofuel production using a synthetic feedback loop

Energy Technology Data Exchange (ETDEWEB)

Dunlop, Mary; Keasling, Jay; Mukhopadhyay, Aindrila

2011-07-14

Cells use feedback to implement a diverse range of regulatory functions. Building synthetic feedback control systems may yield insight into the roles that feedback can play in regulation since it can be introduced independently of native regulation, and alternative control architectures can be compared. We propose a model for microbial biofuel production where a synthetic control system is used to increase cell viability and biofuel yields. Although microbes can be engineered to produce biofuels, the fuels are often toxic to cell growth, creating a negative feedback loop that limits biofuel production. These toxic effects may be mitigated by expressing efflux pumps that export biofuel from the cell. We developed a model for cell growth and biofuel production and used it to compare several genetic control strategies for their ability to improve biofuel yields. We show that controlling efflux pump expression directly with a biofuel-responsive promoter is a straight forward way of improving biofuel production. In addition, a feed forward loop controller is shown to be versatile at dealing with uncertainty in biofuel production rates.

Biofuel implementation in East Europe: Current status and future prospects

International Nuclear Information System (INIS)

Kondili, E.M.; Kaldellis, J.K.

2007-01-01

There is a continuously increasing interest concerning the biofuel implementation in Europe, mainly because of environmental protection and energy supply security reasons. In this context, the European Union (EU) strongly encourages the use of biofuels through a number of Directives. To that effect, EU members follow the Directives implementing various political, fiscal and technical measures and incentives. In the light of the potential created by the recently joined Eastern European countries, an increasing interest is shown in the whole biofuel supply chain within the EU. In parallel, the status of the Eastern European countries domestic market, as far as biofuels are concerned, is an interesting issue, since most of these countries present a significant potential, however still lagging in biofuel implementation. In the above context, the objective of the present work is to give a concise and up-to-date picture of the present status of biofuel implementation in East Europe. The work also aims at identifying the prospects of these countries as far as biofuels are concerned and their role in the EU framework as potential suppliers of a wider market. (author)

Perspectives for Sustainable Aviation Biofuels in Brazil

Directory of Open Access Journals (Sweden)

Luís A. B. Cortez

2015-01-01

Full Text Available The aviation industry has set ambitious goals to reduce carbon emissions in coming decades. The strategy involves the use of sustainable biofuels, aiming to achieve benefits from environmental, social, and economic perspectives. In this context, Brazilian conditions are favorable, with a mature agroindustry that regularly produces automotive biofuel largely adopted by Brazilian road vehicles, while air transportation has been growing at an accelerating pace and a modern aircraft industry is in place. This paper presents the main conclusions and recommendations from a broad assessment of the technological, economic, and sustainability challenges and opportunities associated with the development of drop-in aviation biofuels in Brazil. It was written by a research team that prepared the initial reports and conducted eight workshops with the active participation of more than 30 stakeholders encompassing the private sector, government institutions, NGOs, and academia. The main outcome was a set of guidelines for establishing a new biofuels industry, including recommendations for (a filling the identified research and development knowledge gaps in the production of sustainable feedstock; (b overcoming the barriers in conversion technology, including scaling-up issues; (c promoting greater involvement and interaction between private and government stakeholders; and (d creating a national strategy to promote the development of aviation biofuels.

Public opinion about biofuels: The interplay between party identification and risk/benefit perception

International Nuclear Information System (INIS)

Fung, Timothy K.F.; Choi, Doo Hun; Scheufele, Dietram A.; Shaw, Bret R.

2014-01-01

Using an experiment embedded within a representative survey, this study examined the interactive effect of party identification and risk/benefit perception on public opinion about biofuels. Democrats tended to be more supportive of biofuels than Republicans. However, the effect of party identification on opinion about biofuels varied when individuals considered the risk/benefit of biofuels in different domains. Individuals who reported greater affiliation with the Democratic Party were likely to support funding biofuels research when primed with the economic risks or the social/ethical benefits of biofuels. For those who considered the social/ethical benefits of biofuels, more self-identified Democrats were likely to support biofuels production and use. However, more self-identified Democrats were less supportive of biofuels production and use when they considered the political risks of biofuels. Implications are discussed. - Highlights: • We examined public opinion about biofuels policies. • Effect of risk/benefit perception varied across respondents' party identification. • Democrats favored more research when considering economic risks or social benefits. • Democrats favored biofuels more when considering social benefits. • Democrats favored biofuels less when considering political risks

Rapid and accurate biofuel moisture content gauging using magnetic resonance measurement technology

Energy Technology Data Exchange (ETDEWEB)

Jaervinen, T.

2013-04-15

Biomass is extensively utilised in energy production and as a raw material, such as for the production of liquid biofuels. All those processes will benefit if the moisture content of bio material is known in advance as accurately as possible under transient circumstances. Biofuel trade is increasingly based on the calorific value of fuels. In the first step, this also increases the need for rapid and accurate moisture content determination. During the last few years, large biofuel standardisation has been implemented, emphasising biofuel quality control at all stages of the utilisation chain. In principle, the moisture instrumental measurement can be utilised by many technologies and procedures. Typical techniques are infrared, radiofrequency, microwave, radiometric, electrical conductivity, capacitance, and impedance. Nuclear magnetic resonance (MR) and thermal neutron absorption are also applied. The MR measurement principle has been known and utilised already since the early 1950s. It has become the basic instrumental analysis tool in chemistry. It is also well-known as a very accurate method for analysing most compounds, especially substances containing hydrogen. The utilisation of MR metering is expanded extensively to medical diagnostics as a form of magnetic resonance imaging (MRI). Because of the precision of the MR principle, there have for a long time been efforts to apply it in new and different areas, and to make more user-friendly, smaller, and even portable devices. Such a device was designed by Vaisala a few years ago. VTT has utilised Vaisala's MR prototype for approximately one year for moisture content measurement of different biofuels. The first step in the use of an MR device for moisture determination was the definition of its measurement accuracy compared to the standard method (EN 14774). Those tests proved that the absolute precision seems to be comparable to the standard moisture content measurement method. It was also found out that

Source profiles and contributions of biofuel combustion for PM2.5, PM10 and their compositions, in a city influenced by biofuel stoves.

Science.gov (United States)

Tian, Ying-Ze; Chen, Jia-Bao; Zhang, Lin-Lin; Du, Xin; Wei, Jin-Jin; Fan, Hui; Xu, Jiao; Wang, Hai-Ting; Guan, Liao; Shi, Guo-Liang; Feng, Yin-Chang

2017-12-01

Source and ambient samples were collected in a city in China that uses considerable biofuel, to assess influence of biofuel combustion and other sources on particulate matter (PM). Profiles and size distribution of biofuel combustion were investigated. Higher levels in source profiles, a significant increase in heavy-biomass ambient and stronger correlations of K + , Cl - , OC and EC suggest that they can be tracers of biofuel combustion. And char-EC/soot-EC (8.5 for PM 2.5 and 15.8 for PM 10 of source samples) can also be used to distinguish it. In source samples, water-soluble organic carbon (WSOC) were approximately 28.0%-68.8% (PM 2.5 ) and 27.2%-43.8% (PM 10 ) of OC. For size distribution, biofuel combustion mainly produces smaller particles. OC1, OC2, EC1 and EC2 abundances showed two peaks with one below 1 μm and one above 2 μm. An advanced three-way factory analysis model was applied to quantify source contributions to ambient PM 2.5 and PM 10 . Higher contributions of coal combustion, vehicular emission, nitrate and biofuel combustion occurred during the heavy-biomass period, and higher contributions of sulfate and crustal dust were observed during the light-biomass period. Mass and percentage contributions of biofuel combustion were significantly higher in heavy-biomass period. The biofuel combustion attributed above 45% of K + and Cl - , above 30% of EC and about 20% of OC. In addition, through analysis of source profiles and contributions, they were consistently evident that biofuel combustion and crustal dust contributed more to cation than to anion, while sulfate & SOC and nitrate showed stronger influence on anion than on cation. Copyright © 2017 Elsevier Ltd. All rights reserved.

De novo assembly, functional annotation, and analysis of the giant reed (Arundo donax L.) leaf transcriptome provide tools for the development of a biofuel feedstock

NARCIS (Netherlands)

Evangelistella, Chiara; Valentini, Alessio; Ludovisi, Riccardo; Firrincieli, Andrea; Fabbrini, Francesco; Scalabrin, Simone; Cattonaro, Federica; Morgante, Michele; Mugnozza, Giuseppe Scarascia; Keurentjes, Joost J.B.; Harfouche, Antoine