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Sample records for lender pays sba

  1. 13 CFR 120.1600 - General procedures for enforcement actions against SBA Lenders, SBA Supervised Lenders, Other...

    Science.gov (United States)

    2010-01-01

    ... BUSINESS ADMINISTRATION BUSINESS LOANS Risk-Based Lender Oversight Enforcement Actions § 120.1600 General procedures for enforcement actions against SBA Lenders, SBA Supervised Lenders, Other Regulated SBLCs... actions against SBA Lenders, SBA Supervised Lenders, Other Regulated SBLCs, Management Officials, Other...

  2. 13 CFR 120.1010 - SBA access to SBA Lender, Intermediary, and NTAP files.

    Science.gov (United States)

    2010-01-01

    ... ADMINISTRATION BUSINESS LOANS Risk-Based Lender Oversight Supervision § 120.1010 SBA access to SBA Lender, Intermediary, and NTAP files. An SBA Lender, Intermediary, and NTAP must allow SBA's authorized representatives... 13 Business Credit and Assistance 1 2010-01-01 2010-01-01 false SBA access to SBA Lender...

  3. 75 FR 9257 - SBA Lender Risk Rating System

    Science.gov (United States)

    2010-03-01

    ... identifying those SBA Lenders whose portfolio performance, or other Lender-specific risk-related factors, may... to enhance the predictive value of the model over the earlier model factors. II. The Redeveloped Risk... values of the risk rating model for 7(a) Lenders and was therefore included as a new 7(a) rating...

  4. 75 FR 13145 - SBA Lender Risk Rating System

    Science.gov (United States)

    2010-03-18

    ... of Credit Risk Management, U.S. Small Business Administration, 409 Third Street, SW., 8th Floor...)(7) and 15 U.S.C. 687(f). Dated: March 12, 2010. Bryan Hooper, Director, Office of Credit Risk... SMALL BUSINESS ADMINISTRATION [Docket No. SBA-2010-0004] SBA Lender Risk Rating System AGENCY...

  5. 13 CFR 120.1500 - Types of enforcement actions-SBA Lenders.

    Science.gov (United States)

    2010-01-01

    ... Lenders. 120.1500 Section 120.1500 Business Credit and Assistance SMALL BUSINESS ADMINISTRATION BUSINESS LOANS Risk-Based Lender Oversight Enforcement Actions § 120.1500 Types of enforcement actions—SBA Lenders. Upon a determination that the grounds set forth in § 120.1400 exist, SBA may undertake, in SBA's...

  6. 13 CFR 120.462 - What are SBA's additional requirements on capital maintenance for SBA Supervised Lenders?

    Science.gov (United States)

    2010-01-01

    ... capital that each SBA Supervised Lender must maintain to protect against the credit risk and other general... 13 Business Credit and Assistance 1 2010-01-01 2010-01-01 false What are SBA's additional requirements on capital maintenance for SBA Supervised Lenders? 120.462 Section 120.462 Business Credit and...

  7. 13 CFR 120.1400 - Grounds for enforcement actions-SBA Lenders.

    Science.gov (United States)

    2010-01-01

    ...-SBA Lenders. 120.1400 Section 120.1400 Business Credit and Assistance SMALL BUSINESS ADMINISTRATION BUSINESS LOANS Risk-Based Lender Oversight Enforcement Actions § 120.1400 Grounds for enforcement actions... Lender (regardless of its Risk Rating) include: (1) Failure to maintain eligibility requirements for...

  8. 13 CFR 120.463 - Regulatory accounting-What are SBA's regulatory accounting requirements for SBA Supervised Lenders?

    Science.gov (United States)

    2010-01-01

    ... experienced in auditing financial institutions. The audit must be performed in accordance with generally accepted auditing standards as adopted by the Auditing Standards Board of the American Institute of... Lender discharges or changes its auditor, it must notify SBA in writing within ten days of the occurrence...

  9. 13 CFR 120.1070 - Lender oversight fees.

    Science.gov (United States)

    2010-01-01

    ... 13 Business Credit and Assistance 1 2010-01-01 2010-01-01 false Lender oversight fees. 120.1070 Section 120.1070 Business Credit and Assistance SMALL BUSINESS ADMINISTRATION BUSINESS LOANS Risk-Based Lender Oversight Supervision § 120.1070 Lender oversight fees. Lenders are required to pay to SBA fees to...

  10. Small Businesses Save Big: A Guide to Help SBA Lenders Understand and Communicate the Value of Energy Efficiency Investments (Fact Sheet)

    Energy Technology Data Exchange (ETDEWEB)

    2015-01-01

    Dollars saved through energy efficiency can directly impact your bottom line. Whether you are planning for a major renovation or upgrading individual pieces of building equipment, these improvements can help reduce operating costs, save on utility bills, and boost profits. This fact sheet provides guidelines for SBA lenders to understand the value of financing energy efficiency investments.

  11. 13 CFR 120.433 - What are SBA's other requirements for sales and sales of participating interests?

    Science.gov (United States)

    2010-01-01

    ... Lender has satisfactory SBA performance, as determined by SBA in its discretion. The Lender's Risk Rating... SMALL BUSINESS ADMINISTRATION BUSINESS LOANS Lenders Other Conveyances § 120.433 What are SBA's other requirements for sales and sales of participating interests? SBA requires the following: (a) The Lender must be...

  12. 13 CFR 120.410 - Requirements for all participating Lenders.

    Science.gov (United States)

    2010-01-01

    ... performance, as determined by SBA in its discretion. The 7(a) Lender's Risk Rating, among other factors, will... Lenders. 120.410 Section 120.410 Business Credit and Assistance SMALL BUSINESS ADMINISTRATION BUSINESS LOANS Lenders Participation Criteria § 120.410 Requirements for all participating Lenders. A Lender must...

  13. 13 CFR 120.434 - What are SBA's requirements for loan pledges?

    Science.gov (United States)

    2010-01-01

    ... satisfactory SBA performance, as determined by SBA in its discretion. The Lender's Risk Rating, among other... BUSINESS LOANS Lenders Other Conveyances § 120.434 What are SBA's requirements for loan pledges? (a) Except... 7(a) loan, which consent SBA may withhold in its sole discretion; (b) The Lender must be in good...

  14. 13 CFR 120.470 - What are SBA's additional requirements for SBLCs?

    Science.gov (United States)

    2010-01-01

    ... 13 Business Credit and Assistance 1 2010-01-01 2010-01-01 false What are SBA's additional... BUSINESS LOANS Lenders Small Business Lending Companies (sblc) § 120.470 What are SBA's additional requirements for SBLCs? In addition to complying with SBA's requirements for SBA Lenders and SBA Supervised...

  15. 13 CFR 120.451 - How does a Lender become a PLP Lender?

    Science.gov (United States)

    2010-01-01

    .... The Lender's Risk Rating, among other factors, will be considered in determining satisfactory SBA... 13 Business Credit and Assistance 1 2010-01-01 2010-01-01 false How does a Lender become a PLP Lender? 120.451 Section 120.451 Business Credit and Assistance SMALL BUSINESS ADMINISTRATION BUSINESS...

  16. 13 CFR 120.413 - Advertisement of relationship with SBA.

    Science.gov (United States)

    2010-01-01

    ... refer in its advertising to its participation with SBA. The advertising may not: (a) State or imply that... or misleading; or (c) Make use of SBA's seal. Participating Lender Financings Source: Sections 120...

  17. 13 CFR 120.424 - What are the basic conditions a Lender must meet to securitize?

    Science.gov (United States)

    2010-01-01

    ... performance, as determined by SBA in its discretion. The Lender's Risk Rating, among other factors, will be... Lender must meet to securitize? 120.424 Section 120.424 Business Credit and Assistance SMALL BUSINESS ADMINISTRATION BUSINESS LOANS Lenders Participating Lender Financings § 120.424 What are the basic conditions a...

  18. 13 CFR 120.441 - How does a Lender become a CLP Lender?

    Science.gov (United States)

    2010-01-01

    ... 13 Business Credit and Assistance 1 2010-01-01 2010-01-01 false How does a Lender become a CLP Lender? 120.441 Section 120.441 Business Credit and Assistance SMALL BUSINESS ADMINISTRATION BUSINESS... satisfactory performance history with SBA, including the submission of complete and accurate loan guarantee...

  19. 13 CFR 120.524 - When is SBA released from liability on its guarantee?

    Science.gov (United States)

    2010-01-01

    ... any of the events below occur: (1) The Lender has failed to comply materially with any Loan Program Requirement for 7(a) loans. (2) The Lender has failed to make, close, service, or liquidate a loan in a prudent manner; (3) The Lender's improper action or inaction has placed SBA at risk; (4) The Lender has...

  20. 13 CFR 120.464 - Reports to SBA.

    Science.gov (United States)

    2010-01-01

    .... The SBA Supervised Lender must include such information in any reporting required under other... of personal history on the form approved by SBA); (iii) Any change in capitalization, including such... basis, in accordance with GAAP principles and such other accounting requirements, standards, and...

  1. 13 CFR 120.213 - What fixed interest rates may a Lender charge?

    Science.gov (United States)

    2010-01-01

    ... Lender charge? 120.213 Section 120.213 Business Credit and Assistance SMALL BUSINESS ADMINISTRATION... have a reasonable fixed interest rate. SBA periodically publishes the maximum allowable rate in the... government determines the interest rate on direct loans. SBA publishes the rate periodically in the Federal...

  2. Mortgage lenders and loans

    NARCIS (Netherlands)

    Aalbers, M.B.; Smith, S.J.

    2012-01-01

    This article presents a short historical overview of the different types of lenders that are active in the origination of residential mortgage loans. First, a distinction is made between depository and nondepository lenders. Second, there are two major types of depository lenders: commercial banks,

  3. 75 FR 13329 - Implications of Financial Accounting System (FAS) 166 on SBA Guaranteed Loan Programs

    Science.gov (United States)

    2010-03-19

    ... from the public on: (1) The effect that the accounting changes mandated by the Financial Accounting Standards Board (FASB) in Financial Accounting Standard (FAS) 166 have on SBA Lender and investor... SMALL BUSINESS ADMINISTRATION [Docket No. SBA-2010-0005] Implications of Financial Accounting...

  4. 13 CFR 114.110 - What is SBA's policy with respect to indemnifying and providing legal representation to SBA...

    Science.gov (United States)

    2010-01-01

    ... federal court or any arbitration proceeding; (2) Settle or compromise the claim; and/or (3) Pay for, or... Credit and Assistance SMALL BUSINESS ADMINISTRATION ADMINISTRATIVE CLAIMS UNDER THE FEDERAL TORT CLAIMS ACT AND REPRESENTATION AND INDEMNIFICATION OF SBA EMPLOYEES Representation and Indemnification of SBA...

  5. 13 CFR 120.460 - What are SBA's additional requirements for SBA Supervised Lenders?

    Science.gov (United States)

    2010-01-01

    ...) Standards for training to implement the asset review program. [73 FR 75512, Dec. 11, 2008] ... company and does not have its own board of directors) must adopt an internal control policy which provides... operations, programs, and resources. The internal control policy must, at a minimum: (1) Direct management to...

  6. 13 CFR 120.440 - The Certified Lenders Program.

    Science.gov (United States)

    2010-01-01

    ... Lenders Certified Lenders Program (clp) § 120.440 The Certified Lenders Program. Under the Certified Lenders Program (CLP), designated Lenders process and close 7(a) loans and service and liquidate such.... All other rules in this part 120 relating to the operations of Lenders apply to CLP Lenders. ...

  7. SBA Innovation Clusters

    Science.gov (United States)

    2012-03-02

    Programs and services to help you start, grow and succeed www.sba.gov U.S. Small Business Administration Your Small Business Resource 1Approved for...UNIT NUMBER 7. PERFORMING ORGANIZATION NAME(S) AND ADDRESS(ES) U.S. Small Business Administration ,Advanced Defense Technology Cluster,409 3rd St, SW...Z39-18 Programs and services to help you start, grow and succeed www.sba.gov U.S. Small Business Administration Your Small Business Resource

  8. HUD Subprime and Manufactured Home Lender List

    Data.gov (United States)

    Department of Housing and Urban Development — The U.S. Department of Housing and Urban Development (HUD) periodically produce its HUD Subprime and Manufactured home Lender List for the lenders who specialize in...

  9. 7 CFR 1779.27 - Lenders.

    Science.gov (United States)

    2010-01-01

    ... 7 Agriculture 12 2010-01-01 2010-01-01 false Lenders. 1779.27 Section 1779.27 Agriculture Regulations of the Department of Agriculture (Continued) RURAL UTILITIES SERVICE, DEPARTMENT OF AGRICULTURE (CONTINUED) WATER AND WASTE DISPOSAL PROGRAMS GUARANTEED LOANS § 1779.27 Lenders. (a) Eligible lenders...

  10. How SEA can inform lenders

    DEFF Research Database (Denmark)

    Banhalmi-Zakar, Zsuzsa; Larsen, Sanne Vammen

    SEA can be a powerful tool to improve decision-making for plans, policies and programmes, but it can also be a useful for banks. SEA can help lenders address the reputational risks they are exposed to through financing projects that may have a negative impact on the environment and it can also help......, such as in the credit policies. It was also found that in some cases lenders become involved in project planning at a very early stage, when projects are conceptualized, and certainly before formal approval is sought from relevant authorities and an EIA is conducted. This suggests that SEA can be a useful tool...

  11. Do Lower Lender Subsidies Reduce Guaranteed Student Loan Supply?

    Science.gov (United States)

    Austin, D. Andrew

    2010-01-01

    The article analyzes effects of borrower interest rates and student lender subsidies on federally guaranteed student loan volumes from 1988 to 1994 and from 1996 to 2006. Some have argued that lender subsidy cuts would reduce loan supply or cause lenders to exit the student loan market. If lenders get economic rents due to overly generous…

  12. 24 CFR 202.9 - Investing lenders and mortgagees.

    Science.gov (United States)

    2010-04-01

    ... 24 Housing and Urban Development 2 2010-04-01 2010-04-01 false Investing lenders and mortgagees... Investing lenders and mortgagees. (a) Definition. An investing lender or mortgagee is an organization that is not approved under any other section of this part. An investing lender or mortgagee may purchase...

  13. 13 CFR 120.1000 - Risk-Based Lender Oversight.

    Science.gov (United States)

    2010-01-01

    ... 13 Business Credit and Assistance 1 2010-01-01 2010-01-01 false Risk-Based Lender Oversight. 120.1000 Section 120.1000 Business Credit and Assistance SMALL BUSINESS ADMINISTRATION BUSINESS LOANS Risk-Based Lender Oversight Supervision § 120.1000 Risk-Based Lender Oversight. (a) Risk-Based Lender...

  14. 13 CFR 107.1520 - How a Licensee computes and allocates Prioritized Payments to SBA.

    Science.gov (United States)

    2010-01-01

    ... BUSINESS ADMINISTRATION SMALL BUSINESS INVESTMENT COMPANIES SBA Financial Assistance for Licensees... your Participating Security was sold to a short-term investor in accordance with § 107.1240, the... Charges. You are obligated to pay Prioritized Payments, Adjustments and Charges only if you have profit as...

  15. 24 CFR 232.865 - Election by lender.

    Science.gov (United States)

    2010-04-01

    ... FACILITIES Contract Rights and Obligations Rights and Duties of Lender Under the Contract of Insurance § 232.865 Election by lender. Where a real estate mortgage, or other security instrument has been used to...

  16. 24 CFR 241.865 - Election by the lender.

    Science.gov (United States)

    2010-04-01

    ... Without a HUD-Insured or HUD-Held Mortgage Rights and Duties of Lender Under the Contract of Insurance § 241.865 Election by the lender. Where a real estate mortgage, or other security instrument has been...

  17. Do Lower Lender Subsidies Reduce Guaranteed Student Loan Supply?

    OpenAIRE

    D. Andrew Austin

    2010-01-01

    The article analyzes effects of borrower interest rates and student lender subsidies on federally guaranteed student loan volumes from 1988 to 1994 and from 1996 to 2006. Some have argued that lender subsidy cuts would reduce loan supply or cause lenders to exit the student loan market. If lenders get economic rents due to overly generous subsidies, a simple model of the student loan market suggests that small changes in subsidy levels should not affect loan supply. Empirical results based on...

  18. The Lender’s Mercy

    Science.gov (United States)

    2012-04-01

    expires. Like a consumer getting a second credit card to pay the first, or more accurately a Ponzi scheme , the government can even sell new bonds to...AIR COMMAND AND STAFF COLLEGE AIR UNIVERSITY The Lender’s Mercy by Jeffrey E. Shuck, Major, Air Force A Research Report Submitted to the ...Faculty In Partial Fulfillment of the Graduation Requirements Advisor: Dr. Sebastian H. Lukasik Maxwell Air Force Base, Alabama April 2012

  19. 7 CFR 762.105 - Eligibility and substitution of lenders.

    Science.gov (United States)

    2010-01-01

    ... from participation in Government contracts or programs or be delinquent on a Government debt. (c... writing by executing a modification of the guarantee to identify the new lender, the amount of debt at the... the loan. (d) Lender name or ownership changes. (1) When a lender begins doing business under a new...

  20. 75 FR 28814 - FHA Lender Approval, Annual Renewal, Periodic Updates and Required Reports From FHA Approved Lenders

    Science.gov (United States)

    2010-05-24

    ... proposal. This information is required for: (1) FHA lender approval, (2) Annual renewal of each FHA lender... following information: Title of Proposal: FHA Lender Approval, Annual Renewal, Periodic Updates and Required... and HUD-92001-C. Description of the Need for the Information and Its Proposed Use: This information is...

  1. 40 CFR 281.39 - Lender liability.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 26 2010-07-01 2010-07-01 false Lender liability. 281.39 Section 281.39 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED... petroleum production, refining, and marketing as defined under § 280.200(b) of this chapter is not: (A) An...

  2. 7 CFR 4279.29 - Eligible lenders.

    Science.gov (United States)

    2010-01-01

    ... Regulations of the Department of Agriculture (Continued) RURAL BUSINESS-COOPERATIVE SERVICE AND RURAL... have the legal authority to operate a lending program and sufficient lending expertise and financial... consideration to become a guaranteed lender must submit a request in writing to the State Office for the State...

  3. 13 CFR 106.500 - What is SBA's Gift authority?

    Science.gov (United States)

    2010-01-01

    ... 13 Business Credit and Assistance 1 2010-01-01 2010-01-01 false What is SBA's Gift authority? 106... AND NON-FEE BASED SBA-SPONSORED ACTIVITIES AND GIFTS Gifts § 106.500 What is SBA's Gift authority? This section covers SBA's Gift acceptance authority under sections 4(g), 8(b)(1)(G), 5(b)(9) and 7(k)(2...

  4. Discharge of residual debt: Do private and institutional lenders differ?

    OpenAIRE

    Kirchkamp, Oliver; Prömpers, Henning

    2013-01-01

    With the help of lab experiments we study the impact of discharging insolvent debtors of their residual debt. We investigate the impact of different participation rules and the impact of different types of lenders. We find that higher participation rates encourage risk taking behaviour of borrowers. Higher participation rates also reduce the amount of moonlighting. Most importantly, institutional lenders can suffer more from moonlighting than private lenders.

  5. Vapour Phase Hydrogenation of Phenol over Rhodium on SBA-15 and SBA-16

    Directory of Open Access Journals (Sweden)

    Liliana Giraldo

    2014-12-01

    Full Text Available In the present work, mesoporous SBA-15 and SBA-16 were synthesised using classical methods, and their physicochemical properties were investigated by X-ray diffraction (XRD, FTIR, TEM and N2 adsorption–desorption. Rhodium (Rh, 1 wt % was loaded on the mesoporous SBA-15 and SBA-16 by an impregnation method. The Rh surface coverage, dispersion and crystallite size were determined by room temperature H2 chemisorption on reduced samples. The catalytic activity of Rh supported on mesoporous SBA-15 and SBA-16 was evaluated for the first time in the hydrogenation of phenol in vapour phase in a temperature range between 130 and 270 °C at atmospheric pressure. The reaction over Rh/SBA-15 at 180 °C produced cyclohexanone as the major product (about 60% along with lower amounts of cyclohexanol (about 35% and cyclohexane (about 15%. The influences of temperature, H2/phenol ratio, contact time and the nature of the solvent on the catalytic performance were systematically investigated. The Rh/SBA-16 system offered lower phenol conversion compared to Rh/SBA-15, but both have a very high selectivity for cyclohexanone (above 60%.

  6. SBA Disaster Loan Data FY2008

    Data.gov (United States)

    Small Business Administration — SBA Disaster Loan Data for FY 2008 provides verified loss and approved loan amount totals for both home and business disaster loans, segmented by city, county, zip...

  7. SBA Disaster Loan Data FY2011

    Data.gov (United States)

    Small Business Administration — SBA Disaster Loan Data for FY 2011 provides verified loss and approved loan amount totals for both home and business disaster loans, segmented by city, county, zip...

  8. SBA Disaster Loan Data FY2004

    Data.gov (United States)

    Small Business Administration — SBA Disaster Loan Data for FY 2004 provides verified loss and approved loan amount totals for both home and business disaster loans, segmented by city, county, zip...

  9. SBA Disaster Loan Data FY2007

    Data.gov (United States)

    Small Business Administration — SBA Disaster Loan Data for FY 2007 provides verified loss and approved loan amount totals for both home and business disaster loans, segmented by city, county, zip...

  10. SBA Disaster Loan Data FY2006

    Data.gov (United States)

    Small Business Administration — SBA Disaster Loan Data for FY 2006 provides verified loss and approved loan amount totals for both home and business disaster loans, segmented by city, county, zip...

  11. SBA Disaster Loan Data FY2012

    Data.gov (United States)

    Small Business Administration — SBA Disaster Loan Data for FY 2012 provides verified loss and approved loan amount totals for both home and business disaster loans, segmented by city, county, zip...

  12. SBA Disaster Loan Data FY2005

    Data.gov (United States)

    Small Business Administration — SBA Disaster Loan Data for FY 2005 provides verified loss and approved loan amount totals for both home and business disaster loans, segmented by city, county, zip...

  13. 12 CFR 560.110 - Most favored lender usury preemption.

    Science.gov (United States)

    2010-01-01

    ... 12 Banks and Banking 5 2010-01-01 2010-01-01 false Most favored lender usury preemption. 560.110... INVESTMENT Lending and Investment Provisions Applicable to all Savings Associations § 560.110 Most favored... permits its most favored lender to charge late fees, then a savings association located in that state may...

  14. 24 CFR 202.8 - Loan correspondent lenders and mortgagees.

    Science.gov (United States)

    2010-04-01

    ... terminated. (3) Audit report. A loan correspondent lender or mortgagee must comply with the financial... definition of a supervised lender or mortgagee in § 202.6(a) need not file annual audit reports. Audit... Secretary and an analysis of escrow funds; and (ii) Such other financial information as the Secretary may...

  15. 7 CFR 1779.8 - Access to lender's records.

    Science.gov (United States)

    2010-01-01

    ... 7 Agriculture 12 2010-01-01 2010-01-01 false Access to lender's records. 1779.8 Section 1779.8 Agriculture Regulations of the Department of Agriculture (Continued) RURAL UTILITIES SERVICE, DEPARTMENT OF AGRICULTURE (CONTINUED) WATER AND WASTE DISPOSAL PROGRAMS GUARANTEED LOANS § 1779.8 Access to lender's records...

  16. 75 FR 80561 - Community Express Pilot Program

    Science.gov (United States)

    2010-12-22

    ... Community Express Lenders have increased program risk. Based on the issues identified above, the central... Express Pilot Program was established in 1999 and was based on the Agency's SBA Express Program. Lenders..., participating lenders must arrange and, when necessary, pay for appropriate management and technical assistance...

  17. 13 CFR 107.1230 - Draw-downs by Licensee under SBA's Leverage commitment.

    Science.gov (United States)

    2010-01-01

    ... 13 Business Credit and Assistance 1 2010-01-01 2010-01-01 false Draw-downs by Licensee under SBA's... Commitments by Sba to Reserve Leverage for A Licensee § 107.1230 Draw-downs by Licensee under SBA's Leverage... for a draw against SBA's Leverage commitment, you authorize SBA, or any agent or trustee SBA...

  18. 77 FR 3598 - Federal Housing Administration (FHA) Single Family Lender Insurance Process: Eligibility...

    Science.gov (United States)

    2012-01-25

    ... close loans or to endorse loans through the Lender Insurance process. Regardless of the risk assessment... a more lenient standard for retaining Lender Insurance authority is not acceptable from a risk... will be marginal change for those lenders with ineffective risk management practices and those lenders...

  19. 75 FR 62335 - Federal Housing Administration (FHA) Single Family Lender Insurance Process: Eligibility...

    Science.gov (United States)

    2010-10-08

    ... those lenders with ineffective risk management practices and/or those lenders who have refused to... a marginal impact on those lenders with ineffective risk management practices and who have refused... has any impact, it will be as a consequence of the lender's inability to maintain acceptable risk...

  20. 48 CFR 619.804-3 - SBA acceptance.

    Science.gov (United States)

    2010-10-01

    ... 48 Federal Acquisition Regulations System 4 2010-10-01 2010-10-01 false SBA acceptance. 619.804-3... BUSINESS PROGRAMS Contracting with the Small Business Administration (The 8(a) Program) 619.804-3 SBA acceptance. ...

  1. 13 CFR 107.1720 - Characteristics of SBA's guarantee.

    Science.gov (United States)

    2010-01-01

    ... 13 Business Credit and Assistance 1 2010-01-01 2010-01-01 false Characteristics of SBA's guarantee. 107.1720 Section 107.1720 Business Credit and Assistance SMALL BUSINESS ADMINISTRATION SMALL BUSINESS... Characteristics of SBA's guarantee. If SBA agrees to guarantee a Licensee's Debentures or Participating Securities...

  2. 13 CFR 120.601 - SBA Secondary Market.

    Science.gov (United States)

    2010-01-01

    ... 13 Business Credit and Assistance 1 2010-01-01 2010-01-01 false SBA Secondary Market. 120.601... Market Fiscal and Transfer Agent (fta) § 120.601 SBA Secondary Market. The SBA secondary market (“Secondary Market”) consists of the sale of Certificates, representing either the entire guaranteed portion...

  3. 13 CFR 120.395 - What is SBA's collateral position?

    Science.gov (United States)

    2010-01-01

    ... 13 Business Credit and Assistance 1 2010-01-01 2010-01-01 false What is SBA's collateral position? 120.395 Section 120.395 Business Credit and Assistance SMALL BUSINESS ADMINISTRATION BUSINESS LOANS Special Purpose Loans Builders Loan Program § 120.395 What is SBA's collateral position? SBA will require...

  4. SBA-15-Supported Nickel Phosphide Hydrotreating Catalysts.

    Czech Academy of Sciences Publication Activity Database

    Korányi, T.I.; Vít, Zdeněk; Poduval, D.G.; Ryoo, R.; Kim, H.S.; Hensen, E.J. M.

    2008-01-01

    Roč. 253, 1 (2008) , s. 119-131 ISSN 0021-9517 R&D Projects: GA ČR(CZ) GA104/06/0870 Institutional research plan: CEZ:AV0Z40720504 Keywords : nickel phosphide * sba-15 * hydrodesulfurization Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 5.167, year: 2008

  5. 13 CFR 120.630 - Qualifications to be a Pool Assembler.

    Science.gov (United States)

    2010-01-01

    ... assembler that is an SBA Lender, that the SBA Lender has satisfactory SBA performance, as determined by SBA in its discretion. The Lender's Risk Rating, among other factors, will be considered in determining...

  6. 42 CFR 60.43 - Limitation, suspension, or termination of the eligibility of a HEAL lender or holder.

    Science.gov (United States)

    2010-10-01

    ... notice, sent by certified mail, specifying his or her intention to terminate the lender or holder's... that a HEAL lender fails to meet the statutory definition of an “eligible lender.” (d) This section...

  7. 13 CFR 120.423 - Which 7(a) loans may a Lender securitize?

    Science.gov (United States)

    2010-01-01

    ... Lender may only securitize 7(a) loans that will be fully disbursed within 90 days of the securitization's closing date. If the amount of a fully disbursed loan increases after a securitization settles, the Lender...

  8. 24 CFR 1000.404 - What lenders are eligible for participation?

    Science.gov (United States)

    2010-04-01

    ... Activities § 1000.404 What lenders are eligible for participation? Eligible lenders are those approved under... 24 Housing and Urban Development 4 2010-04-01 2010-04-01 false What lenders are eligible for participation? 1000.404 Section 1000.404 Housing and Urban Development Regulations Relating to Housing and Urban...

  9. 75 FR 12251 - Notice of Proposed Information Collection for Public Comment; FHA Lender Approval, Annual Renewal...

    Science.gov (United States)

    2010-03-15

    ... Lenders. OMB Control Number, if applicable: 2502-0005. Description of the need for the information and proposed use: The information is used by FHA to verify that lenders meet all approval, renewal, update and... Information Collection for Public Comment; FHA Lender Approval, Annual Renewal, Periodic Updates and...

  10. 78 FR 17937 - Notice of Proposed Information Collection for Public Comment; FHA Lender Approval, Annual Renewal...

    Science.gov (United States)

    2013-03-25

    ... Lenders. OMB Control Number, if applicable: 2502-0005. Description of the need for the information and proposed use: The information is used by FHA to verify that lenders meet all approval, renewal, update and... Information Collection for Public Comment; FHA Lender Approval, Annual Renewal, Periodic Updates and...

  11. 78 FR 36560 - 30-Day Notice of Proposed Information Collection: FHA Lender Approval, Annual Renewal, Periodic...

    Science.gov (United States)

    2013-06-18

    ... 92001-C Non-compliances on Title I Lenders Description of the need for the information and proposed use... Information Collection: FHA Lender Approval, Annual Renewal, Periodic Updates and Noncompliance Reporting by FHA Approved Lenders AGENCY: Office of the Chief Information Officer, HUD. ACTION: Notice. SUMMARY...

  12. 77 FR 63323 - Notice of Proposed Information Collection for Public Comment; FHA Lender Approval, Annual Renewal...

    Science.gov (United States)

    2012-10-16

    ... Lenders OMB Control Number, if applicable: 2502-0005. Description of the need for the information and proposed use: The information is used by FHA to verify that lenders meet all approval, renewal, update and... Information Collection for Public Comment; FHA Lender Approval, Annual Renewal, Periodic Updates and...

  13. 76 FR 8847 - Proposed Information Collection (Lenders Staff Appraisal Reviewer (SAR) Application) Activity...

    Science.gov (United States)

    2011-02-15

    ... AFFAIRS Proposed Information Collection (Lenders Staff Appraisal Reviewer (SAR) Application) Activity... solicits comments information needed to certify a lender's nominee as a VA Staff Appraisal Reviewer. DATES...: Lenders Staff Appraisal Reviewer (SAR) Application, VA Form 26-0785. OMB Control Number: 2900-0658. Type...

  14. 77 FR 21991 - Federal Housing Administration (FHA): Multifamily Accelerated Processing (MAP)-Lender and...

    Science.gov (United States)

    2012-04-12

    .... This practice would mitigate risk, since MAP lenders and underwriters will now be approved at a tier... Administration (FHA): Multifamily Accelerated Processing (MAP)--Lender and Underwriter Eligibility Criteria and Credit Watch for MAP Lenders AGENCY: Office of the Assistant Secretary for Housing--Federal Housing...

  15. 76 FR 34091 - Notice of Proposed Information Collection for Public Comment; FHA Lender Approval, Annual Renewal...

    Science.gov (United States)

    2011-06-10

    ... managing its financial risks and protect consumers from lender noncompliance with FHA rules and regulations... Information Collection for Public Comment; FHA Lender Approval, Annual Renewal, Periodic Updates and Noncompliance Reporting by FHA Approved Lenders AGENCY: Office of the Assistant Secretary for Housing, HUD...

  16. 12 CFR 617.7130 - What initial disclosures must a qualified lender make to a borrower?

    Science.gov (United States)

    2010-01-01

    ... lender make to a borrower? 617.7130 Section 617.7130 Banks and Banking FARM CREDIT ADMINISTRATION FARM... must a qualified lender make to a borrower? (a) Required disclosures—in general. A qualified lender... certificates that borrowers are required to purchase are at risk and may only be retired at the discretion of...

  17. 7 CFR 3565.304 - Lender loan processing responsibilities.

    Science.gov (United States)

    2010-01-01

    ... application at the feasibility stage or when they request a conditional commitment. (b) Project servicing, management and disposition. Unless otherwise permitted by the Agency, the originating lender must perform all loan functions during the period of the guarantee. These functions include servicing, asset management...

  18. 7 CFR 1779.29 - Fees and charges by lender.

    Science.gov (United States)

    2010-01-01

    ... 7 Agriculture 12 2010-01-01 2010-01-01 false Fees and charges by lender. 1779.29 Section 1779.29 Agriculture Regulations of the Department of Agriculture (Continued) RURAL UTILITIES SERVICE, DEPARTMENT OF AGRICULTURE (CONTINUED) WATER AND WASTE DISPOSAL PROGRAMS GUARANTEED LOANS § 1779.29 Fees and charges by...

  19. 13 CFR 121.103 - How does SBA determine affiliation?

    Science.gov (United States)

    2010-01-01

    ... 13 Business Credit and Assistance 1 2010-01-01 2010-01-01 false How does SBA determine affiliation? 121.103 Section 121.103 Business Credit and Assistance SMALL BUSINESS ADMINISTRATION SMALL BUSINESS....103 How does SBA determine affiliation? (a) General Principles of Affiliation. (1) Concerns and...

  20. 13 CFR 120.1721 - SBA's right to investigate.

    Science.gov (United States)

    2010-01-01

    ... 13 Business Credit and Assistance 1 2010-01-01 2010-01-01 false SBA's right to investigate. 120.1721 Section 120.1721 Business Credit and Assistance SMALL BUSINESS ADMINISTRATION BUSINESS LOANS... right to investigate. SBA may undertake such investigation as it deems necessary to determine whether it...

  1. Propene epoxidation over Au/Ti-SBA-15 catalysts

    NARCIS (Netherlands)

    Sacaliuc, E.; Beale, A.M.; Weckhuysen, B.M.; Nijhuis, T.A.

    2007-01-01

    Highly dispersed gold nanoparticles were synthesized within the channels of a mesoporous Ti-SBA-15 support, followed by thorough catalyst characterization and testing in the selective epoxidation of propene to propene oxide. For this purpose, two series of Ti-SBA-15 materials differing in their Ti

  2. 13 CFR 117.8 - Responsibilities of SBA recipients.

    Science.gov (United States)

    2010-01-01

    ... 13 Business Credit and Assistance 1 2010-01-01 2010-01-01 false Responsibilities of SBA recipients. 117.8 Section 117.8 Business Credit and Assistance SMALL BUSINESS ADMINISTRATION NONDISCRIMINATION IN FEDERALLY ASSISTED PROGRAMS OR ACTIVITIES OF SBA-EFFECTUATION OF THE AGE DISCRIMINATION ACT OF 1975, AS...

  3. Significant improvement in the pore properties of SBA-15 brought ...

    Indian Academy of Sciences (India)

    WINTEC

    Presence of carboxylic acids as well as hydrothermal treatment improves the pore properties of SBA-15. Keywords. SBA-15; mesoporous; carboxylic acids; adsorption; hydrothermal treatment; morphology. 1. Introduction. Molecular sieves with large pores have been of great use in carrying out reactions and separation proc-.

  4. Carbon material formation on SBA-15 and Ni-SBA-15 and residue constituents during acetylene decomposition

    International Nuclear Information System (INIS)

    Chiang, Hung-Lung; Wu, Trong-Neng; Ho, Yung-Shou; Zeng, Li-Xuan

    2014-01-01

    Highlights: • Acetylene was decomposed on SBA-15 and Ni-SBA-15 at 650–850 °C. • Carbon spheres and filaments were formed after acetylene decomposition. • PAHs were determined in tar and residues. • Exhaust constituents include CO 2 , H 2 , NO x and hydrocarbon species. - Abstract: Carbon materials including carbon spheres and nanotubes were formed from acetylene decomposition on hydrogen-reduced SBA-15 and Ni-SBA-15 at 650–850 °C. The physicochemical characteristics of SBA-15, Ni-SBA-15 and carbon materials were analyzed by field emission scanning electronic microscopy (FE-SEM), Raman spectrometry, and energy dispersive spectrometry (EDS). In addition, the contents of polyaromatic hydrocarbons (PAHs) in the tar and residue and volatile organic compounds (VOCs) in the exhaust were determined during acetylene decomposition on SBA-15 and Ni-SBA-15. Spherical carbon materials were observed on SBA-15 during acetylene decomposition at 750 and 850 °C. Carbon filaments and ball spheres were formed on Ni-SBA-15 at 650–850 °C. Raman spectroscopy revealed peaks at 1290 (D-band, disorder mode, amorphous carbon) and 1590 (G-band, graphite sp 2 structure) cm −1 . Naphthalene (2 rings), pyrene (4 rings), phenanthrene (3 rings), and fluoranthene (4 rings) were major PAHs in tar and residues. Exhaust constituents of hydrocarbon (as propane), H 2 , and C 2 H 2 were 3.9–2.6/2.7–1.5, 1.4–2.8/2.6–4.3, 4.2–2.4/3.2–1.7% when acetylene was decomposed on SBA-15/Ni-SBA-15, respectively, corresponding to temperatures ranging from 650 to 850 °C. The concentrations of 52 VOCs ranged from 9359 to 5658 and 2488 to 1104 ppm for SBA-15 and Ni-SBA-15 respectively, at acetylene decomposition temperatures from 650 to 850 °C, and the aromatics contributed more than 87% fraction of VOC concentrations

  5. Behind the Pay Gap

    Science.gov (United States)

    Dey, Judy Goldberg; Hill, Catherine

    2007-01-01

    Women have made remarkable gains in education during the past three decades, yet these achievements have resulted in only modest improvements in pay equity. The gender pay gap has become a fixture of the U.S. workplace and is so ubiquitous that many simply view it as normal. "Behind the Pay Gap" examines the gender pay gap for college graduates.…

  6. 13 CFR 120.1025 - Off-site reviews and monitoring.

    Science.gov (United States)

    2010-01-01

    ... Risk-Based Lender Oversight Supervision § 120.1025 Off-site reviews and monitoring. SBA may conduct off-site reviews and monitoring of SBA Lenders, Intermediaries, and NTAPs, including SBA Lenders...

  7. Preparation and characterization of catalyst 20% Co/SBA-15

    International Nuclear Information System (INIS)

    Lima, L.A.; Nogueira, A.C.; Rodrigues, J.J.; Rodrigues, M.G.F.

    2012-01-01

    The utilization of molecular sieves as supports for cobalt catalysts are promising. SBA-15 is a class of mesoporous silicate with a high thermal stability and high degree of structural order, which confers an important feature for the catalytic process. It was prepared SBA-15 molecular sieve with molar composition: 1.0 TEOS: 0017P123: 5.7 HCl: 193 H2O. The deposition of cobalt on the substrate SBA-15 was performed by wet impregnation, using a solution of 0.1M cobalt nitrate. The materials were characterized by the techniques of X-Ray Diffraction (XRD), chemical analysis by X-Ray Spectrometry by Energy Dispersive (EDX), and nitrogen adsorption (BET). By XRD and BET verified the formation of SBA-15, and after the impregnation there was no change in the structure, with EDX showed that the impregnation method is efficient, the sample showed cobalt content close to the nominal value. (author)

  8. 13 CFR 120.545 - What are SBA's policies concerning the liquidation of collateral and the sale of business loans...

    Science.gov (United States)

    2010-01-01

    ... security instrument (see § 120.550 for Homestead Protection for Farmers). (1) Competitive bids or... financial assistance have no rights of contribution against SBA on an SBA guaranteed or direct loan. SBA is...

  9. 12 CFR 617.7125 - How should a qualified lender determine the effective interest rate?

    Science.gov (United States)

    2010-01-01

    ... effective interest rate? 617.7125 Section 617.7125 Banks and Banking FARM CREDIT ADMINISTRATION FARM CREDIT SYSTEM BORROWER RIGHTS Disclosure of Effective Interest Rates § 617.7125 How should a qualified lender determine the effective interest rate? (a) A qualified lender must calculate the effective interest rate on...

  10. 24 CFR 1005.104 - What lenders are eligible for participation?

    Science.gov (United States)

    2010-04-01

    ... 24 Housing and Urban Development 4 2010-04-01 2010-04-01 false What lenders are eligible for participation? 1005.104 Section 1005.104 Housing and Urban Development Regulations Relating to Housing and Urban... URBAN DEVELOPMENT LOAN GUARANTEES FOR INDIAN HOUSING § 1005.104 What lenders are eligible for...

  11. 75 FR 80066 - Quality Control Requirements for Direct Endorsement Lenders; Notice of Proposed Information...

    Science.gov (United States)

    2010-12-21

    ... for Direct Endorsement Lenders; Notice of Proposed Information Collection: Comment Request AGENCY... information: Title of Proposal: Quality Control Requirements for Direct Endorsement Lenders. OMB Control Number, if applicable: 2502--NEW. Description of the need for the information and proposed use: As of...

  12. 7 CFR 1980.309 - Lender participation in guaranteed RH loans.

    Science.gov (United States)

    2010-01-01

    ... Housing Mortgage Insurance or as an issuer of Ginnie Mae mortgage backed securities; (3) Any Lender... one to four family mortgage loans; (6) An FCS institution with direct lending authority; and (7) Any... Lender's internal loan criteria for issues of credit history and repayment ability and a copy of the...

  13. 76 FR 71329 - Request for Information Regarding Private Education Loans and Private Educational Lenders

    Science.gov (United States)

    2011-11-17

    ... Regarding Private Education Loans and Private Educational Lenders AGENCY: Bureau of Consumer Financial... Justice and the Federal Trade Commission, to prepare a Report on Private Education Loans and Private Education Lenders. The Bureau seeks information on private education loans and related consumer financial...

  14. 34 CFR 601.40 - Disclosure and reporting requirements for lenders.

    Science.gov (United States)

    2010-07-01

    ... disclosures required in § 682.205(a) and (b). (2) A lender must, for each of its private education loans... 34 Education 3 2010-07-01 2010-07-01 false Disclosure and reporting requirements for lenders. 601.40 Section 601.40 Education Regulations of the Offices of the Department of Education (Continued...

  15. How do mortgage lenders influence neighbourhood dynamics? Redlining and predatory lending

    NARCIS (Netherlands)

    Aalbers, M.B.; van Ham, M.; Manley, D.; Bailey, N.; Simpson, L.; Maclennan, D.

    2013-01-01

    Manuel Aalbers argues that the actions of mortgage lenders can play an important role in understanding the trajectories of some of the most deprived neighbourhoods in Western cities. Mortgage lenders use the notion of the neighbourhood as a means to reduce their risk or to extract profit, and as

  16. Guaranteed Student Loans: Profits of Secondary Market Lenders Vary Widely. United States General Accounting Office Briefing Report to Congressional Requesters.

    Science.gov (United States)

    General Accounting Office, Washington, DC. Div. of Human Resources.

    This report was prepared to determine lenders' rates of return or profitability on Stafford loans in their portfolios, reasons for varying levels of profitability among institutions that hold such loans, and the effect of 1986 subsidy reductions on these lenders' profitability. The study focused on the activities of lenders that purchase Stafford…

  17. 78 FR 40312 - 30-Day Notice of Proposed Information Collection: FHA TOTAL (Technology Open to Approved Lenders...

    Science.gov (United States)

    2013-07-03

    ... lender and used for scoring, loan underwriting and additional risk & fraud evaluation. [ssquf] Risk... Information Collection: FHA TOTAL (Technology Open to Approved Lenders) Mortgage Scorecard AGENCY: Office of... (Technology Open to Approved Lenders) Mortgage Scorecard. OMB Approval Number: 2502-0556. Type of Request...

  18. 13 CFR 123.203 - What interest rate will my business pay on a physical disaster business loan and what are the...

    Science.gov (United States)

    2010-01-01

    ... 13 Business Credit and Assistance 1 2010-01-01 2010-01-01 false What interest rate will my... Business Loans § 123.203 What interest rate will my business pay on a physical disaster business loan and what are the repayment terms? (a) SBA will announce interest rates with each disaster declaration. If...

  19. 13 CFR 101.401 - What programs and activities of SBA are subject to this subpart?

    Science.gov (United States)

    2010-01-01

    ... ADMINISTRATION ADMINISTRATION Intergovernmental Partnership § 101.401 What programs and activities of SBA are subject to this subpart? SBA publishes in the Federal Register a list of programs and activities subject...

  20. Lender of last resort in a monetary union

    Directory of Open Access Journals (Sweden)

    Gylfi Magnússon

    2014-12-01

    Full Text Available The theory of optimal currency areas was developed during the 1960’s and 1970’s. At that time the international financial system was very different from the current system, banking systems were smaller and the flow of funds across borders limited. Developments in the Eurozone in recent years have shown that when the theory was developed and the decision made to adopt the euro some of the drawbacks of a common currency were not foreseen and important issues were not addressed. This includes the role of a common central bank as a lender of last resort to national governments. In addition, few foresaw how many closely linked financial systems could create problems that are unsolvable without the cooperation of several governments. An adequate framework for dealing with such problems was thus not put in place. The possibility that macro-economic shocks could originate in the financial system was mainly ignored. During the current crisis it has been necessary to address all these issues. It took four years to find a politically viable solution. This involves the redefinition of the role of the European Central Bank, making it a lender of last resort to national governments. This policy change buys time to deal with many fundamental imbalances within the Eurozone but does not in and of itself solve the underlying problems. The delay in implementing this policy was however very costly.

  1. 13 CFR 120.521 - What interest rate applies after SBA purchases its guaranteed portion?

    Science.gov (United States)

    2010-01-01

    ... 13 Business Credit and Assistance 1 2010-01-01 2010-01-01 false What interest rate applies after... 504 Loans Sba's Purchase of A Guaranteed Portion § 120.521 What interest rate applies after SBA purchases its guaranteed portion? When SBA purchases the guaranteed portion of a fixed interest rate loan...

  2. 13 CFR 127.403 - What happens if SBA verifies the concern's eligibility?

    Science.gov (United States)

    2010-01-01

    ....403 What happens if SBA verifies the concern's eligibility? If SBA verifies that the concern satisfies... 13 Business Credit and Assistance 1 2010-01-01 2010-01-01 false What happens if SBA verifies the concern's eligibility? 127.403 Section 127.403 Business Credit and Assistance SMALL BUSINESS...

  3. 13 CFR 108.1230 - Draw-downs by NMVC Company under SBA's Leverage commitment.

    Science.gov (United States)

    2010-01-01

    ... 13 Business Credit and Assistance 1 2010-01-01 2010-01-01 false Draw-downs by NMVC Company under...) Conditional Commitments by Sba to Reserve Leverage for A Nmvc Company § 108.1230 Draw-downs by NMVC Company... submitting a request for a draw against SBA's Leverage commitment, you authorize SBA, or any agent or trustee...

  4. 13 CFR 101.100 - What is the purpose of SBA?

    Science.gov (United States)

    2010-01-01

    ... 13 Business Credit and Assistance 1 2010-01-01 2010-01-01 false What is the purpose of SBA? 101.100 Section 101.100 Business Credit and Assistance SMALL BUSINESS ADMINISTRATION ADMINISTRATION Overview § 101.100 What is the purpose of SBA? The U.S. Small Business Administration (SBA) aids, counsels, assists, and protects the interests of small...

  5. 13 CFR 108.1140 - NMVC Company's acceptance of SBA remedies under § 108.1810.

    Science.gov (United States)

    2010-01-01

    ... ADMINISTRATION NEW MARKETS VENTURE CAPITAL (âNMVCâ) PROGRAM SBA Financial Assistance for NMVC Companies (Leverage) General Information About Obtaining Leverage § 108.1140 NMVC Company's acceptance of SBA remedies under... 13 Business Credit and Assistance 1 2010-01-01 2010-01-01 false NMVC Company's acceptance of SBA...

  6. Financial Advice: Who Pays

    Science.gov (United States)

    Finke, Michael S.; Huston, Sandra J.; Winchester, Danielle D.

    2011-01-01

    Using a cost-benefit framework for financial planning services and proprietary data collected in the summer of 2008, the client characteristics that are associated with the likelihood of paying for professional financial advice, as well as the type of financial services purchased, are identified. Results indicate that respondents who pay for…

  7. Paying for Hitler's War

    DEFF Research Database (Denmark)

    Lund, Joachim

    2017-01-01

    Book review of: Jonas Scherner & Eugene N. White (eds.), Paying for Hitler's War: The Consequenses of Nazi Hegemony for Europe (NY: Cambridge University Press, 2016)......Book review of: Jonas Scherner & Eugene N. White (eds.), Paying for Hitler's War: The Consequenses of Nazi Hegemony for Europe (NY: Cambridge University Press, 2016)...

  8. 13 CFR 123.412 - What happens if SBA declines your business' pre-disaster mitigation loan request?

    Science.gov (United States)

    2010-01-01

    ... business disagrees with SBA's decision, it may respond in accordance with § 123.13. If SBA reverses its decision, SBA will use the date it received your business' last request for reconsideration or appeal as... 13 Business Credit and Assistance 1 2010-01-01 2010-01-01 false What happens if SBA declines your...

  9. Organically functionalized mesoporous SBA-15 as sorbents for removal of selected pharmaceuticals from water

    Energy Technology Data Exchange (ETDEWEB)

    Bui, Tung Xuan [School of Environmental Science and Engineering, Gwangju Institute of Science and Technology (GIST), 261 Cheomdan-gwagiro, Buk-gu, Gwangju 500-712 (Korea, Republic of); Kang, Seo-Young [International Environmental Research Center (IERC), Gwangju Institute of Science and Technology (GIST), 261 Cheomdan-gwagiro, Buk-gu, Gwangju 500-712 (Korea, Republic of); Lee, Sang-Hyup [Water Environment Center, Korea Institute of Science and Technology, Cheongryang, Seoul 130-650 (Korea, Republic of); Choi, Heechul, E-mail: hcchoi@gist.ac.kr [School of Environmental Science and Engineering, Gwangju Institute of Science and Technology (GIST), 261 Cheomdan-gwagiro, Buk-gu, Gwangju 500-712 (Korea, Republic of)

    2011-10-15

    Highlights: {yields} SBA-15 grafted with aminopropyl, hydroxymethyl, and trimethylsilyl groups as sorbents. {yields} Sorbents for removal of a mixture of 12 pharmaceuticals from water. {yields} Hydroxymethyl-SBA-15 shows similar adsorption efficiency like SBA-15. {yields} Aminopropyl-SBA-15 makes increase for clofibric acid, diclofenac, decrease for atenolol, estrone, trimethoprim. {yields} Trimethylsilyl-SBA-15 makes increase for 9 compounds; 7 compounds from 70.6% to 98.9%. - Abstract: Mesoporous silica SBA-15 and its postfunctionalized counterparts with hydroxymethyl (HM-SBA-15), aminopropyl (AP-SBA-15), and trimethylsilyl (TMS-SBA-15) were prepared and characterized by powder X-ray diffraction, N{sub 2} adsorption-desorption measurement, Fourier-transform infrared spectroscopy, and elemental analysis. The removal of a mixture of 12 selected pharmaceuticals was investigated by batch adsorption experiments onto SBA-15 and the grafted materials. SBA-15 showed to have moderate adsorption affinity with amino-containing (atenolol, trimethoprim) and hydrophobic pharmaceuticals, but it displayed minimal adsorption affinity toward hydrophilic compounds. HM-SBA-15 was analogous with SBA-15 in terms of the adsorption efficiency toward all pharmaceuticals. AP-SBA-15 exhibited an increase in the adsorption of two acidic compounds (clofibric acid, diclofenac) but a decrease in the adsorption of estrone and the two amino-containing compounds. Among the grafted materials, TMS-SBA-15 had the highest adsorption affinity toward most pharmaceuticals. Moreover, the adsorption of nine pharmaceuticals to TMS-SBA-15 was significantly higher than that to SBA-15; seven of which showed the removal percentages from 70.6% to 98.9% onto TMS-SBA-15. The number of pharmaceuticals showing high adsorption efficiency onto TMS-SBA-15 did not alter significantly as the pH changed in the range of 5.5-7.6. The results suggest that TMS-SBA-15 is a promising material for the removal of pharmaceuticals

  10. Desidratação de etanol sobre material nanoestruturado do tipo LaSBA-15 Ethanol dehydration over LaSBA-15 nanostrutured material

    Directory of Open Access Journals (Sweden)

    Geraldo E. Luz Jr

    2010-01-01

    Full Text Available La-incorporated SBA-15 mesopourous molecular sieves (LaSBA-15 were directly synthesized with aim to convert ethanol to ethylene. The samples were characterized by XRD, XRF, nitrogen sorption and acidity, by thermodesorption of n-buthylamine. The results have indicated that all the samples have showed high ordered mesostructure with a large average pore size, and that the lanthanum incorporation has caused an increase in the acidity of the SBA-15. The LaSBA-15 samples have improved, with low deactivation rate, the conversion of the ethanol to water, ether, acetaldehyde and ethylene. In addition, they have increased the ethylene selectivity.

  11. Grafting of alumina on SBA-15: Effect of surface roughness

    Czech Academy of Sciences Publication Activity Database

    Zukal, Arnošt; Šiklová, Helena; Čejka, Jiří

    2008-01-01

    Roč. 24, č. 17 (2008), s. 9837-9842 ISSN 0743-7463 R&D Projects: GA AV ČR KAN100400701 Institutional research plan: CEZ:AV0Z40400503 Keywords : alumina-grafted materials * SBA-15 * Nitrogen adsorption Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 4.097, year: 2008

  12. Textural and morphological studies of transition metal doped SBA ...

    Indian Academy of Sciences (India)

    remarkable progress in diverse applications such as organic transformation,1 enzyme immobilization,2 drug .... tion of final morphology of SBA-15 mesostructure. It is interesting to note the promoting role of two inor- ... the MClx performs self-generated acid role whilst the. F− dramatically enlarges the pore sizes respectively.

  13. 13 CFR 107.509 - Employment of SBA officials.

    Science.gov (United States)

    2010-01-01

    ... 13 Business Credit and Assistance 1 2010-01-01 2010-01-01 false Employment of SBA officials. 107.509 Section 107.509 Business Credit and Assistance SMALL BUSINESS ADMINISTRATION SMALL BUSINESS..., involved discretion with respect to the granting of Assistance under the Act. Management and Compensation ...

  14. 78 FR 19263 - Lender Placed Insurance, Terms and Conditions

    Science.gov (United States)

    2013-03-29

    ... by such costs where a servicer pays the higher premiums and is unable to recoup the cost from the... also invites input on enhancing the transparency and consumer and investor protections related to...

  15. 76 FR 8846 - Proposed Information Collection (VBA Loan Guaranty Service Lender Satisfaction Survey) Activity...

    Science.gov (United States)

    2011-02-15

    ... AFFAIRS Proposed Information Collection (VBA Loan Guaranty Service Lender Satisfaction Survey) Activity.... SUMMARY: The Veterans Benefits Administration (VBA), Department of Veterans Affairs (VA), is announcing an... the following collection of information, VBA invites comments on: (1) Whether the proposed collection...

  16. 13 CFR 123.411 - What if SBA determines that your business loan request meets the selection criteria of § 123.409...

    Science.gov (United States)

    2010-01-01

    ... 13 Business Credit and Assistance 1 2010-01-01 2010-01-01 false What if SBA determines that your business loan request meets the selection criteria of § 123.409 but SBA is unable to fund it because SBA... fund it because SBA has already allocated all program funds? If SBA determines that your business' loan...

  17. Characterization and comprehension of zeolite NaY/mesoporous SBA-15 composite as adsorbent for paraquat

    Energy Technology Data Exchange (ETDEWEB)

    Osakoo, Nattawut, E-mail: natawut.work@gmail.com [School of Chemistry, Institute of Science, Suranaree University of Technology, Nakhon Ratchasima, 30000 (Thailand); Pansakdanon, Chaianun [School of Chemistry, Institute of Science, Suranaree University of Technology, Nakhon Ratchasima, 30000 (Thailand); Department of Chemistry, Faculty of Science, Ubon Ratchathani University, Ubon Ratchathani, 34190 (Thailand); Sosa, Narongrit; Deekamwong, Krittanun; Keawkumay, Chalermpan; Rongchapo, Wina [School of Chemistry, Institute of Science, Suranaree University of Technology, Nakhon Ratchasima, 30000 (Thailand); Chanlek, Narong [Synchrotron Light Research Institute, Nakhon Ratchasima, 30000 (Thailand); Jitcharoen, Juthamas [Department of Chemistry, Faculty of Science, Ubon Ratchathani University, Ubon Ratchathani, 34190 (Thailand); Prayoonpokarach, Sanchai [School of Chemistry, Institute of Science, Suranaree University of Technology, Nakhon Ratchasima, 30000 (Thailand); Wittayakun, Jatuporn, E-mail: jatuporn@g.sut.ac.th [School of Chemistry, Institute of Science, Suranaree University of Technology, Nakhon Ratchasima, 30000 (Thailand)

    2017-06-01

    NaY was synthesized from fumed silica and further modified to form a composite with SBA-15. Textural properties and basicity of the composite NaY-SBA-15 were between those of the parent materials. Paraquat adsorption on NaY was 204.1 mg/g, higher than that on NaY synthesized with rice husk silica from the previous work. SBA-15 was a poor adsorbent for paraquat. Based on the weight of NaY, the adsorption capacity of analytical-grade paraquat on the NaY-SBA-15 composite was 241.5 mg/g-NaY. Moreover, the composite adsorbed blue dye from a commercial grade paraquat. Interaction between the NaY-SBA-15 and paraquat could be from C and N atoms in paraquat with oxygen atom on NaY-SBA-15. - Highlights: • Zeolite NaY/mesoporous SBA-15 composite was synthesized with a simple method. • NaY and SBA-15 coexisted in the composite confirmed by FTIR, CO{sub 2}-TPD and XPS. • Adsorption capacity of paraquat (mg/g-NaY) was improved by NaY and SBA-15 composite. • C and N atoms in paraquat could interact with oxygen atom on NaY-SBA-15 composite.

  18. Characterization and comprehension of zeolite NaY/mesoporous SBA-15 composite as adsorbent for paraquat

    International Nuclear Information System (INIS)

    Osakoo, Nattawut; Pansakdanon, Chaianun; Sosa, Narongrit; Deekamwong, Krittanun; Keawkumay, Chalermpan; Rongchapo, Wina; Chanlek, Narong; Jitcharoen, Juthamas; Prayoonpokarach, Sanchai; Wittayakun, Jatuporn

    2017-01-01

    NaY was synthesized from fumed silica and further modified to form a composite with SBA-15. Textural properties and basicity of the composite NaY-SBA-15 were between those of the parent materials. Paraquat adsorption on NaY was 204.1 mg/g, higher than that on NaY synthesized with rice husk silica from the previous work. SBA-15 was a poor adsorbent for paraquat. Based on the weight of NaY, the adsorption capacity of analytical-grade paraquat on the NaY-SBA-15 composite was 241.5 mg/g-NaY. Moreover, the composite adsorbed blue dye from a commercial grade paraquat. Interaction between the NaY-SBA-15 and paraquat could be from C and N atoms in paraquat with oxygen atom on NaY-SBA-15. - Highlights: • Zeolite NaY/mesoporous SBA-15 composite was synthesized with a simple method. • NaY and SBA-15 coexisted in the composite confirmed by FTIR, CO 2 -TPD and XPS. • Adsorption capacity of paraquat (mg/g-NaY) was improved by NaY and SBA-15 composite. • C and N atoms in paraquat could interact with oxygen atom on NaY-SBA-15 composite.

  19. Preparation of Pd-Diimine@SBA-15 and Its Catalytic Performance for the Suzuki Coupling Reaction

    Directory of Open Access Journals (Sweden)

    Jiahuan Yu

    2016-11-01

    Full Text Available A highly efficient and stable Pd-diimine@SBA-15 catalyst was successfully prepared by immobilizing Pd onto diimine-functionalized mesoporous silica SBA-15. With the help of diimine functional groups grafted onto the SBA-15, Pd could be anchored on a support with high dispersion. Pd-diimine@SBA-15 catalyst exhibited excellent catalytic performance for the Suzuki coupling reaction of electronically diverse aryl halides and phenylboronic acid under mild conditions with an ultralow amount of Pd (0.05 mol % Pd. When the catalyst amount was increased, it could catalyze the coupling reaction of chlorinated aromatics with phenylboronic acid. Compared with the catalytic performances of Pd/SBA-15 and Pd-diimine@SiO2 catalysts, the Pd-diimine@SBA-15 catalyst exhibited higher hydrothermal stability and could be repeatedly used four times without a significant decrease of its catalytic activity.

  20. Adsorptive removal of selected pharmaceuticals by mesoporous silica SBA-15

    International Nuclear Information System (INIS)

    Bui, Tung Xuan; Choi, Heechul

    2009-01-01

    The removal of five selected pharmaceuticals, viz., carbamazepine, clofibric acid, diclofenac, ibuprofen, and ketoprofen was examined by batch sorption experiments onto a synthesized mesoporous silica SBA-15. SBA-15 was synthesized and characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), N 2 adsorption-desorption measurement, and point of zero charge (PZC) measurement. Pharmaceutical adsorption kinetics was rapid and occurred on a scale of minutes, following a pseudo-second-order rate expression. Adsorption isotherms were best fitted by the Freundlich isotherm model. High removal rates of individual pharmaceuticals were achieved in acidic media (pH 3-5) and reached 85.2% for carbamazepine, 88.3% for diclofenac, 93.0% for ibuprofen, 94.3% for ketoprofen, and 49.0% for clofibric acid at pH 3 but decreased with increase in pH. SBA-15 also showed high efficiency for removal of a mixture of 5 pharmaceuticals. Except for clofibric acid (35.6%), the removal of pharmaceuticals in the mixture ranged from 75.2 to 89.3%. Based on adsorption and desorption results, the mechanism of the selected pharmaceuticals was found to be a hydrophilic interaction, providing valuable information for further studies to design materials for the purpose. The results of this study suggest that mesoporous-silica-based materials are promising adsorbents for removing pharmaceuticals from not only surface water but also wastewater of pharmaceutical industrial manufactures.

  1. Adsorptive removal of selected pharmaceuticals by mesoporous silica SBA-15

    Energy Technology Data Exchange (ETDEWEB)

    Bui, Tung Xuan, E-mail: bxtung@gist.ac.kr [Department of Environmental Science and Engineering, Gwangju Institute of Science and Technology (GIST), 261 Cheomdan-gwagiro, Buk-gu, Gwangju 500-712 (Korea, Republic of); Choi, Heechul, E-mail: hcchoi@gist.ac.kr [Department of Environmental Science and Engineering, Gwangju Institute of Science and Technology (GIST), 261 Cheomdan-gwagiro, Buk-gu, Gwangju 500-712 (Korea, Republic of)

    2009-09-15

    The removal of five selected pharmaceuticals, viz., carbamazepine, clofibric acid, diclofenac, ibuprofen, and ketoprofen was examined by batch sorption experiments onto a synthesized mesoporous silica SBA-15. SBA-15 was synthesized and characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), N{sub 2} adsorption-desorption measurement, and point of zero charge (PZC) measurement. Pharmaceutical adsorption kinetics was rapid and occurred on a scale of minutes, following a pseudo-second-order rate expression. Adsorption isotherms were best fitted by the Freundlich isotherm model. High removal rates of individual pharmaceuticals were achieved in acidic media (pH 3-5) and reached 85.2% for carbamazepine, 88.3% for diclofenac, 93.0% for ibuprofen, 94.3% for ketoprofen, and 49.0% for clofibric acid at pH 3 but decreased with increase in pH. SBA-15 also showed high efficiency for removal of a mixture of 5 pharmaceuticals. Except for clofibric acid (35.6%), the removal of pharmaceuticals in the mixture ranged from 75.2 to 89.3%. Based on adsorption and desorption results, the mechanism of the selected pharmaceuticals was found to be a hydrophilic interaction, providing valuable information for further studies to design materials for the purpose. The results of this study suggest that mesoporous-silica-based materials are promising adsorbents for removing pharmaceuticals from not only surface water but also wastewater of pharmaceutical industrial manufactures.

  2. Encapsulation of mangiferin in ordered mesoporous silica type SBA-15: synthesis and characterization

    Science.gov (United States)

    Pontes Silva, Cássia Roberta; da Rocha Ferreira, Fabricia; Dresch Webler, Geovana; Osimar Sousa da Silva, Antônio; Caxico de Abreu, Fabiane; Fonseca, Eduardo J. S.

    2017-06-01

    SBA-15 ordered mesoporous silica were synthesized using the method reported by Zhao et al (1998 J. Am. Chem. Soc. 120 6024-36). The goal of this work is to study the encapsulation of mangiferin (MGN) into porous SBA-15. SBA-MGN composites were obtained from a mixture of SBA-15 and MGN. The structures of these materials were analyzed using different characterization techniques: differential scanning calorimetry (DSC), Fourier transform infrared spectroscopy (FTIR), N2 adsorption-desorption measurement, transmission electron microscopy (TEM), absorbance spectra and electrochemical assay. The isotherms of the adsorption/desorption for SBA-15 and SBA-MGN are type IV, showing that the ordered mesoporous structure of SBA-15 was maintained even after the incorporation of MGN. The decrease in the value of the specific surface area and the reduction in pore volume confirmed the incorporation of MGN at the surface and in the pores of SBA-15. The incorporation of MGN in SBA-15 aims to increase the solubility of mangiferin.

  3. LES PAYS EN TRANSITION

    International Development Research Centre (IDRC) Digital Library (Canada)

    Cathy Egan

    capacité du pays d'exécuter des recherches pouvant avoir une incidence sur les poli- tiques et d'élaborer des politiques fondées sur les constatations de la recherche. Ce processus exigeait un calendrier à long terme et des engagements solides; il suppo- sait également de l'expérimentation au cours des premières étapes ...

  4. LES PAYS EN TRANSITION

    International Development Research Centre (IDRC) Digital Library (Canada)

    Cathy Egan

    observations. Premièrement, il vaut mieux savoir précisément ce qu'on entend par. « transition » dans le cas d'un pays en développement. Il ne s'agit presque jamais d'un ... La deuxième observation tirée des données probantes présentées est que, dans un contexte de ... des perturbations propres aux transitions. Pourtant ...

  5. Photocatalytic activity of Ce-modified SBA-15 for the degradation of ...

    Indian Academy of Sciences (India)

    als. Photocatalytic activity evaluation studies are made on all the samples for the degradation of isoproturon. Among them, 0.3 (wt%) Ce-modified Al-SBA-15 catalyst has shown a maximum activity in comparison with Ce-modified. SBA-15. The better activity is attributed to the synergistic effect of mesoporosity and the ...

  6. 13 CFR 121.408 - What are the size procedures for SBA's Certificate of Competency Program?

    Science.gov (United States)

    2010-01-01

    ..., including its affiliates, is small for purposes of the COC program, SBA will process the application for COC... SBA's Certificate of Competency Program? 121.408 Section 121.408 Business Credit and Assistance SMALL... Certificate of Competency Program? (a) A firm which applies for a COC must file an “Application for Small...

  7. 13 CFR 123.513 - Does SBA require collateral on its Military Reservist EIDL?

    Science.gov (United States)

    2010-01-01

    ... provide available collateral such as a lien on business property, a security interest in personal property... 13 Business Credit and Assistance 1 2010-01-01 2010-01-01 false Does SBA require collateral on its... collateral on its Military Reservist EIDL? SBA will not generally require you to pledge collateral to secure...

  8. Metal-loaded SBA-16-like silica – Correlation between basicity and affinity towards hydrogen

    Energy Technology Data Exchange (ETDEWEB)

    Ouargli-Saker, R. [Department of Materials Engineering, University of Science and Technology, El M’naouer, BP 1505, Oran (Algeria); Nanoqam, Department of Chemistry, University of Quebec at Montreal, H3C3P8 (Canada); Bouazizi, N. [Nanoqam, Department of Chemistry, University of Quebec at Montreal, H3C3P8 (Canada); Unité de recherche, Electrochimie, Matériaux et Environnement, Faculté des Sciences de Gabès, Université de Gabès, Cité Erriadh, 6072 Gabès (Tunisia); Boukoussa, B. [Department of Materials Engineering, University of Science and Technology, El M’naouer, BP 1505, Oran (Algeria); Lqamb, Laboratório de Química Analítica Ambiental, Faculdade de Química, Pontifícia Universidade Católica do Rio Grande do Sul (Brazil); Barrimo, Diana [Nanoqam, Department of Chemistry, University of Quebec at Montreal, H3C3P8 (Canada); Paola-Nunes-Beltrao, Ana [Nanoqam, Department of Chemistry, University of Quebec at Montreal, H3C3P8 (Canada); Laboratory of Materials Chemistry L.C.M, University of Oran1 Ahmed Ben Bella, BP 1524, El-Mnaouer, 31000 Oran (Algeria); Azzouz, A., E-mail: azzouz.a@uqam.ca [Nanoqam, Department of Chemistry, University of Quebec at Montreal, H3C3P8 (Canada)

    2017-07-31

    Highlights: • Metal dispersion in longitudinal channels confers adsorption properties to SBA-16. • Both Fe{sup 0}-NPs and Cu{sup 0}-NPs seem to be responsible of this effect. • Effect of the repetitive adsorption-desorption cycles on CO{sub 2} and water sorption. • Hydrogen storage on the functionalized materials. - Abstract: Nanoparticles of Cu{sup o} (CuNPs) and Fe{sup o} (FeNPs) were dispersed in SBA-16-like silica, resulting metal-loaded materials (Cu-SBA-16 and Fe-SBA-16) with improved affinity towards hydrogen. Electron microscopy and X-ray diffraction showed that MNP dispersion occurs mainly inside SBA-16 channels. MNP incorporation was found to confer affinity to the silica surface, since higher CO{sub 2} retention capacity (CRC) was registered Cu/SBA-16 and Fe/SBA-16. This was accompanied by a significant improvement of the affinity towards hydrogen, as supported by hydrogen adsorption tests. This was explained in terms of strong hydrogen interaction with MNP and lattice oxygen atoms. The results reported herein open new prospects for SBA-16 as potential adsorbents for hydrogen storage.

  9. 13 CFR 107.1570 - Distributions by Licensee-optional Distribution to private investors and SBA.

    Science.gov (United States)

    2010-01-01

    ... private investors and SBA. If you have outstanding Participating Securities or Earmarked Assets, you may... Capital Impairment. (v) The Distribution does not reduce your Regulatory Capital (excluding commitments... contrary to section 303 of the Act. (2) SBA's share of Distribution. (i) If your Capital Impairment...

  10. 13 CFR 121.107 - How does SBA determine a concern's “primary industry”?

    Science.gov (United States)

    2010-01-01

    ... Applicability § 121.107 How does SBA determine a concern's “primary industry”? In determining the primary industry in which a concern or a concern combined with its affiliates is engaged, SBA considers the distribution of receipts, employees and costs of doing business among the different industries in which...

  11. 13 CFR 101.104 - What are the functions of SBA's field offices?

    Science.gov (United States)

    2010-01-01

    ... 13 Business Credit and Assistance 1 2010-01-01 2010-01-01 false What are the functions of SBA's field offices? 101.104 Section 101.104 Business Credit and Assistance SMALL BUSINESS ADMINISTRATION ADMINISTRATION Overview § 101.104 What are the functions of SBA's field offices? (a) Regional offices. Regional...

  12. Silylated Co/SBA-15 catalysts for Fischer-Tropsch synthesis

    International Nuclear Information System (INIS)

    Jia Lihong; Jia Litao; Li Debao; Hou Bo; Wang Jungang; Sun Yuhan

    2011-01-01

    A series of silylated Co/SBA-15 catalysts were prepared via the reaction of surface Si-OH of SBA-15 with hexamethyldisilazane (HMDS) under anhydrous, vapor-phase conditions, and then characterized by FT-IR, N 2 physisorption, TG, XRD, and TPR-MS. The results showed that organic modification led to a silylated SBA-15 surface composed of stable hydrophobic Si-(CH 3 ) 3 species even after calcinations and H 2 reduction at 673 K. Furthermore, the hydrophobic surface strongly influenced both metal dispersion and reducibility. Compared with non-silylated Co/SBA, Co/S-SBA (impregnation after silylation) showed a high activity, due to the better cobalt reducibility on the hydrophobic support. However, S-Co/SBA (silylation after impregnation) had the lowest FT activity among all the catalysts, due to the lower cobalt reducibility along with the steric hindrance of grafted -Si(CH 3 ) 3 for the re-adsorption of α-olefins. -- Graphical abstract: The silylation of an SBA-15 before cobalt impregnation enhanced the reducibility of cobalt oxides on an SBA-15-supported cobalt catalyst and consequently increased the catalytic activity for Fischer-Tropsch synthesis. Display Omitted

  13. 13 CFR 121.102 - How does SBA establish size standards?

    Science.gov (United States)

    2010-01-01

    ... from other industries, growth trends, historical activity within an industry, unique factors occurring... standards, SBA's Office of Size Standards will examine the impact of inflation on monetary-based size... Administrator or designee. If SBA finds that inflation has significantly eroded the value of the monetary-based...

  14. 13 CFR 126.201 - Who does SBA consider to own a HUBZone SBC?

    Science.gov (United States)

    2010-01-01

    ... persons who are U.S. citizens. (b) Partnerships. SBA considers all partners, whether general or limited, to be owners in a partnership. (c) Sole proprietorships. The proprietor is the owner. (d) Limited liability companies. SBA considers each member to be an owner of a limited liability company. [69 FR 29422...

  15. 13 CFR 120.427 - Will SBA approve a securitization application from a capital impaired Securitizer?

    Science.gov (United States)

    2010-01-01

    ... 13 Business Credit and Assistance 1 2010-01-01 2010-01-01 false Will SBA approve a securitization... securitization application from a capital impaired Securitizer? If a securitizer does not maintain the level of capital required by this subpart, SBA will not approve a securitization application from that securitizer. ...

  16. 13 CFR 108.140 - SBA approval of initial Management Expenses.

    Science.gov (United States)

    2010-01-01

    ... 13 Business Credit and Assistance 1 2010-01-01 2010-01-01 false SBA approval of initial Management Expenses. 108.140 Section 108.140 Business Credit and Assistance SMALL BUSINESS ADMINISTRATION NEW MARKETS... SBA approval of initial Management Expenses. A NMVC Company must have its Management Expenses approved...

  17. 13 CFR 127.402 - How will SBA conduct an examination?

    Science.gov (United States)

    2010-01-01

    ... 13 Business Credit and Assistance 1 2010-01-01 2010-01-01 false How will SBA conduct an examination? 127.402 Section 127.402 Business Credit and Assistance SMALL BUSINESS ADMINISTRATION WOMEN-OWNED SMALL BUSINESS FEDERAL CONTRACT ASSISTANCE PROCEDURES Eligibility Examinations § 127.402 How will SBA...

  18. 13 CFR 127.604 - How will SBA process an EDWOSB or WOSB status protest?

    Science.gov (United States)

    2010-01-01

    ... 13 Business Credit and Assistance 1 2010-01-01 2010-01-01 false How will SBA process an EDWOSB or WOSB status protest? 127.604 Section 127.604 Business Credit and Assistance SMALL BUSINESS ADMINISTRATION WOMEN-OWNED SMALL BUSINESS FEDERAL CONTRACT ASSISTANCE PROCEDURES Protests § 127.604 How will SBA...

  19. 13 CFR 107.140 - SBA approval of initial Management Expenses.

    Science.gov (United States)

    2010-01-01

    ... 13 Business Credit and Assistance 1 2010-01-01 2010-01-01 false SBA approval of initial Management Expenses. 107.140 Section 107.140 Business Credit and Assistance SMALL BUSINESS ADMINISTRATION SMALL BUSINESS INVESTMENT COMPANIES Qualifying for an SBIC License Organizing An Sbic § 107.140 SBA approval of...

  20. 13 CFR 120.197 - Notifying SBA's Office of Inspector General of suspected fraud.

    Science.gov (United States)

    2010-01-01

    ... 13 Business Credit and Assistance 1 2010-01-01 2010-01-01 false Notifying SBA's Office of Inspector General of suspected fraud. 120.197 Section 120.197 Business Credit and Assistance SMALL BUSINESS ADMINISTRATION BUSINESS LOANS Policies Applying to All Business Loans Reporting § 120.197 Notifying SBA's Office...

  1. 78 FR 71704 - Request for Comments on Draft SBA Strategic Plan for FY 2014-2018

    Science.gov (United States)

    2013-11-29

    ...; (2) Serve as the voice for small business; and, (3) Build an Agency that meets the needs of today's... SMALL BUSINESS ADMINISTRATION Request for Comments on Draft SBA Strategic Plan for FY 2014-2018... Business Administration. ACTION: Request for Comments on Draft SBA Strategic Plan for FY2014- 2018. SUMMARY...

  2. Value-Added Merit Pay.

    Science.gov (United States)

    Twomey, Daniel F.

    The purpose of merit pay is to reward employees for their accomplishments and motivate them to continue improving. Critics of merit pay say the increased extrinsic motivation that it prompts is more than offset by the decrease in intrinsic motivation. Supporters of performance-based pay claim several benefits of the practice. This study addressed…

  3. Different CO2 absorbents-modified SBA-15 sorbent for highly selective CO2 capture

    Science.gov (United States)

    Liu, Xiuwu; Zhai, Xinru; Liu, Dongyang; Sun, Yan

    2017-05-01

    Different CO2 absorbents-modified SBA-15 materials are used as CO2 sorbent to improve the selectivity of CH4/CO2 separation. The SBA-15 sorbents modified by physical CO2 absorbents are very limited to increasing CO2 adsorption and present poor selectivity. However, the SBA-15 sorbents modified by chemical CO2 absorbents increase CO2 adsorption capacity obviously. The separation coefficients of CO2/CH4 increase in this case. The adsorption and regeneration properties of the SBA-15 sorbents modified by TEA, MDEA and DIPA have been compared. The SBA-15 modified by triethanolamine (TEA) presents better CO2/CH4 separation performance than the materials modified by other CO2 absorbents.

  4. Dehydrogenation of Isobutane with Carbon Dioxide over SBA-15-Supported Vanadium Oxide Catalysts

    Directory of Open Access Journals (Sweden)

    Chunling Wei

    2016-10-01

    Full Text Available A series of vanadia catalysts supported on SBA-15 (V/SBA with a vanadia (V content ranging from 1% to 11% were prepared by an incipient wetness method. Their catalytic behavior in the dehydrogenation of isobutane to isobutene with CO2 was examined. The catalysts were characterized by N2 adsorption, X-ray diffraction (XRD, scanning electron microscopy (SEM, Raman spectroscopy, and temperature-programmed reduction (TPR. It was found that these catalysts were effective for the dehydrogenation reaction, and the catalytic activity is correlated with the amount of dispersed vanadium species on the SBA-15 support. The 7% V/SBA catalyst shows the highest activity, which gives 40.8% isobutane conversion and 84.8% isobutene selectivity. The SBA-15-supported vanadia exhibits higher isobutane conversion and isobutene selectivity than the MCM-41-supported one.

  5. Solvent optimization for niacinamide adsorption on organo-functionalized SBA-15 mesoporous silica

    Science.gov (United States)

    Moritz, Michał

    2013-10-01

    This work describes the application of organo-modified SBA-15 siliceous materials as the carrier for niacinamide. The surface functionalization of SBA-15 by a grafting strategy with triethoxyphenylsilane, triethoxy(4-methoxyphenyl)silane, triethoxymethylsilane and (3-mercaptopropyl)trimethoxysilane as modifying agents has been successfully achieved. The adsorption process was performed in acetonitrile, methanol, 2-propanol, 1-pentanol and ethyl acetate. The obtained results indicated a promote niacinamide adsorption on sulfopropyl-modified (119 mg/g) and non-modified (78 mg/g) SBA-15 from ethyl acetate. The pure and derivatized SBA-15 products have been characterized by elemental analysis, thermogravimetry, nitrogen adsorption and diffuse reflectance UV spectroscopy. After niacinamide adsorption the textural parameters of mesoporous carriers such as BET surface area, pore volume and microporosity were reduced. The mesoporous matrices loaded with niacinamide exhibited prolonged-release kinetics of this vitamin, especially from sulfopropyl-modified SBA-15 carrier.

  6. Selective Preparation of Furfural from Xylose over Sulfonic Acid Functionalized Mesoporous Sba-15 Materials

    Directory of Open Access Journals (Sweden)

    Panpan Li

    2011-04-01

    Full Text Available Sulfonic acid functionalized mesoporous SBA-15 materials were prepared using the co-condensation and grafting methods, respectively, and their catalytic performance in the dehydration of xylose to furfural was examined. SBA-15-SO3H(C prepared by the co-condensation method showed 92–95% xylose conversion and 74% furfural selectivity, and 68–70% furfural yield under the given reaction conditions. The deactivation and regeneration of the SBA-15-SO3H(C catalyst for the dehydration of xylose was also investigated. The results indicate that the used and regeneration catalysts retained the SBA-15 mesoporous structure, and the S content of SBA-15-SO3H(C almost did not change. The deactivation of the catalysts is proposed to be associated with the accumulation of byproducts, which is caused by the loss reaction of furfural. After regeneration by H2O2, the catalytic activity of the catalyst almost recovered.

  7. When Punishment Pays

    Science.gov (United States)

    Roberts, Gilbert

    2013-01-01

    Explaining cooperation in groups remains a key problem because reciprocity breaks down between more than two. Punishing individuals who contribute little provides a potential answer but changes the dilemma to why pay the costs of punishing which, like cooperation itself, provides a public good. Nevertheless, people are observed to punish others in behavioural economic games, posing a problem for existing theory which highlights the difficulty in explaining the spread and persistence of punishment. Here, I consider the apparent mismatch between theory and evidence and show by means of instructive analysis and simulation how much of the experimental evidence for punishment comes from scenarios in which punishers may expect to obtain a net benefit from punishing free-riders. In repeated games within groups, punishment works by imposing costs on defectors so that it pays them to switch to cooperating. Both punishers and non-punishers then benefit from the resulting increase in cooperation, hence investing in punishment can constitute a social dilemma. However, I show the conditions in which the benefits of increased cooperation are so great that they more than offset the costs of punishing, thereby removing the temptation to free-ride on others' investments and making punishment explicable in terms of direct self-interest. Crucially, this is because of the leveraging effect imposed in typical studies whereby people can pay a small cost to inflict a heavy loss on a punished individual. In contrast to previous models suggesting punishment is disadvantaged when rare, I show it can invade until it comes into a producer-scrounger equilibrium with non-punishers. I conclude that adding punishment to an iterated public goods game can solve the problem of achieving cooperation by removing the social dilemma. PMID:23483907

  8. 24 CFR 1007.70 - Disqualification of lenders and civil money penalties.

    Science.gov (United States)

    2010-04-01

    ... civil money penalties. 1007.70 Section 1007.70 Housing and Urban Development Regulations Relating to....70 Disqualification of lenders and civil money penalties. (a) In general—(1) Grounds for action. HUD... or holder that are guaranteed under this part. (b) Civil money penalties for intentional violations...

  9. 76 FR 27382 - Agency Information Collection Activity (VBA Loan Guaranty Service Lender Satisfaction Survey...

    Science.gov (United States)

    2011-05-11

    ... AFFAIRS Agency Information Collection Activity (VBA Loan Guaranty Service Lender Satisfaction Survey... notice announces that the Veterans Benefits Administration (VBA), Department of Veterans Affairs, will... information, VBA invites comments on: (1) Whether the proposed collection of information is necessary for the...

  10. 25 CFR 103.17 - Must the lender follow any special procedures to close the loan?

    Science.gov (United States)

    2010-04-01

    ... searches for each asset to be used as loan collateral. (c) At or prior to closing, the lender must obtain recent appraisals for all real property and improvements to be used as collateral for the loan, to the... of a leasehold interest in tribal trust property); (4) Guarantees (other than from BIA); (5...

  11. 24 CFR 203.492 - Assignments, pledges and transfers by approved lender.

    Science.gov (United States)

    2010-04-01

    ... 24 Housing and Urban Development 2 2010-04-01 2010-04-01 false Assignments, pledges and transfers... HOUSING ACT AND OTHER AUTHORITIES SINGLE FAMILY MORTGAGE INSURANCE Contract Rights and Obligations Rehabilitation Loans § 203.492 Assignments, pledges and transfers by approved lender. (a) An assignment, pledge...

  12. 76 FR 52271 - Institutions and Lender Requirements Relating to Education Loans, Student Assistance General...

    Science.gov (United States)

    2011-08-22

    ... DEPARTMENT OF EDUCATION 34 CFR Part 668 [Docket ID ED-2009-OPE-0003] RIN 1840-AC95 Institutions and Lender Requirements Relating to Education Loans, Student Assistance General Provisions, Federal Perkins Loan Program, Federal Family Education Loan Program, and William D. Ford Federal Direct Loan...

  13. 75 FR 80516 - Notice of Submission of Proposed Information Collection to OMB; Lender Qualifications for...

    Science.gov (United States)

    2010-12-22

    ... Proposed Information Collection to OMB; Lender Qualifications for Multifamily Accelerated Processing (MAP) AGENCY: Office of the Chief Information Officer, HUD. ACTION: Notice. SUMMARY: The proposed information... Number: 2502-0541. Form Numbers: None. Description of the Need for the Information and Its Proposed Use...

  14. 42 CFR 60.53 - Notification to lender or holder of change in enrollment status.

    Science.gov (United States)

    2010-10-01

    ... SERVICES GRANTS HEALTH EDUCATION ASSISTANCE LOAN PROGRAM The School § 60.53 Notification to lender or holder of change in enrollment status. Each school must notify the holder of a HEAL loan of any change in... failure to enroll as scheduled for any academic period as a full-time student, the student's latest known...

  15. 7 CFR 1779.65 - Lender's sale or assignment of the guaranteed portion of loan.

    Science.gov (United States)

    2010-01-01

    ... 7 Agriculture 12 2010-01-01 2010-01-01 false Lender's sale or assignment of the guaranteed portion of loan. 1779.65 Section 1779.65 Agriculture Regulations of the Department of Agriculture (Continued) RURAL UTILITIES SERVICE, DEPARTMENT OF AGRICULTURE (CONTINUED) WATER AND WASTE DISPOSAL PROGRAMS...

  16. 7 CFR 1779.64 - Issuance of Lender's Agreement, Loan Note Guarantee, and Assignment Guarantee Agreement.

    Science.gov (United States)

    2010-01-01

    ... 7 Agriculture 12 2010-01-01 2010-01-01 false Issuance of Lender's Agreement, Loan Note Guarantee, and Assignment Guarantee Agreement. 1779.64 Section 1779.64 Agriculture Regulations of the Department of Agriculture (Continued) RURAL UTILITIES SERVICE, DEPARTMENT OF AGRICULTURE (CONTINUED) WATER AND...

  17. Crisis management and lender of last resort in the European banking market

    NARCIS (Netherlands)

    Boot, A.W.A.; Marinč, M.

    2008-01-01

    We discuss some key issues related to supervisory arrangements in the Euro-system countries. In particular, we address the lender of last resort (LOLR) structure and the related crisis management framework. We focus on the responsibilities and powers of individual countries (and national central

  18. Crisis management and lender of last resort in the European banking market

    NARCIS (Netherlands)

    Boot, A.W.A.; Marinč, M.; Alessandrini, P.; Fratianni, M.; Zazzaro, A.

    2009-01-01

    We discuss some key issues related to supervisory arrangements in the Euro-system countries. In particular, we address the lender of last resort (LOLR) structure and the related crisis management framework. We focus on the responsibilities and powers of individual countries (and national central

  19. 77 FR 77050 - Agency Information Collection Activities; Part 601 Preferred Lender Arrangements

    Science.gov (United States)

    2012-12-31

    ... regulations governing private education loans offered at covered institutions by lenders also participating in... obtaining a private education loan. These regulations require covered institutions to provide a variety of... submitting the Private Education Loan Applicant Self-Certification form for OMB's approval. While information...

  20. 25 CFR 103.30 - What standard of care must a lender meet?

    Science.gov (United States)

    2010-04-01

    ... in which the borrower's business is located, and in accordance with this part. If the lender fails to... insurance approval, or if not so specified, then in descending order of importance: (1) BIA's written loan... other security interests in accordance with State and local law, including the laws of any tribe that...

  1. Lending policies of informal, formal and semiformal lenders - Evidence from Vietnam

    NARCIS (Netherlands)

    Pham, Thi Thu Tra; Lensink, Robert

    2007-01-01

    This paper compares lending policies of formal, informal and semiformal lenders with respect to household lending in Vietnam. The analysis suggests that the probability of using formal or semiformal credit increases if borrowers provide collateral, a guarantor and/or borrow for business-related

  2. Lending Policies of Informal, Formal, and Semi-formal Lenders: Evidence from Vietnam

    NARCIS (Netherlands)

    Lensink, B.W.; Pham, T.T.T.

    2007-01-01

    This paper compares lending policies of formal, informal and semiformal lenders with respect to household lending in Vietnam. The analysis suggests that the probability of using formal or semiformal credit increases if borrowers provide collateral, a guarantor and/or borrow for business-related

  3. Paying for Payments

    DEFF Research Database (Denmark)

    Korsgaard, Søren

    Do consumers and merchants use the most efficient payment instruments? I examine how interchange fees, which are fees paid from merchants' banks to consumers' banks when card transactions take place, influence the choice between cash and payment cards. I show that when consumers do not pay...... transaction fees to banks - a common feature in bank contracts - card use is declining in interchange fees, and surcharging does not neutralize interchange fees. According to my model, banks set interchange fees at too high a level, resulting in too few card payments. I derive an optimal interchange fee which...

  4. Dynamical properties of nimodipine molecules confined in SBA-15 matrix

    International Nuclear Information System (INIS)

    Kiwilsza, A.; Pajzderska, A.; Mielcarek, J.; Jenczyk, J.; Wąsicki, J.

    2016-01-01

    Highlights: • Dynamics of confined nimodipine (drug) in SBA-15 studied by ssNMR. • Higher mobility of confined molecules in comparison with bulk drug. • Decreasing of the energy barrier for reorientation of methyl groups in confined drug. - Abstract: The paper reports results of 13 C and 1 H ssNMR for nimodipine confined in mesopores of SBA-15 for the samples (i) containing nimodipine molecules inside and on the external surface of silica, (ii) containing nimodipine only inside pores forming an incomplete monolayer on the surface (iii) for bulk nimodipine. The measurements permitted comparison of the dynamics of nimodipine bulk and confined in pores. The confined nimodipine is in an amorphous state and has additional degrees of rotational freedom with respect to the bulk one. The height of the energy barrier related to the rotation of methyl groups in confined nimodipine is lower than in bulk nimodipine. The higher mobility of nimodipine molecules confined in silica pores can explain the higher release rate of nimodipine from silica matrix than dissolution rate of bulk drug.

  5. Dynamical properties of nimodipine molecules confined in SBA-15 matrix

    Energy Technology Data Exchange (ETDEWEB)

    Kiwilsza, A. [Faculty of Physics, Adam Mickiewicz University, Umultowska 85, 61-614 Poznan (Poland); NanoBioMedical Center, Adam Mickiewicz University, Umultowska 85, 61-614 Poznan (Poland); Pajzderska, A. [Faculty of Physics, Adam Mickiewicz University, Umultowska 85, 61-614 Poznan (Poland); Mielcarek, J. [Department of Inorganic and Analytical Chemistry, Poznan University of Medical Sciences, Grunwaldzka 6, 60-780 Poznan (Poland); Jenczyk, J. [NanoBioMedical Center, Adam Mickiewicz University, Umultowska 85, 61-614 Poznan (Poland); Wąsicki, J., E-mail: jwasicki@amu.edu.pl [Faculty of Physics, Adam Mickiewicz University, Umultowska 85, 61-614 Poznan (Poland); NanoBioMedical Center, Adam Mickiewicz University, Umultowska 85, 61-614 Poznan (Poland)

    2016-08-22

    Highlights: • Dynamics of confined nimodipine (drug) in SBA-15 studied by ssNMR. • Higher mobility of confined molecules in comparison with bulk drug. • Decreasing of the energy barrier for reorientation of methyl groups in confined drug. - Abstract: The paper reports results of {sup 13}C and {sup 1}H ssNMR for nimodipine confined in mesopores of SBA-15 for the samples (i) containing nimodipine molecules inside and on the external surface of silica, (ii) containing nimodipine only inside pores forming an incomplete monolayer on the surface (iii) for bulk nimodipine. The measurements permitted comparison of the dynamics of nimodipine bulk and confined in pores. The confined nimodipine is in an amorphous state and has additional degrees of rotational freedom with respect to the bulk one. The height of the energy barrier related to the rotation of methyl groups in confined nimodipine is lower than in bulk nimodipine. The higher mobility of nimodipine molecules confined in silica pores can explain the higher release rate of nimodipine from silica matrix than dissolution rate of bulk drug.

  6. Carboxylic acid-functionalized SBA-15 nanorods for gemcitabine delivery

    International Nuclear Information System (INIS)

    Bahrami, Zohreh; Badiei, Alireza; Ziarani, Ghodsi Mohammadi

    2015-01-01

    The present study deals with the functionalization of mesoporous silica nanoparticles as drug delivery systems. Mono, di, and tri amino-functionalized SBA-15 nanorods were synthesized by post-grafting method using (3-aminopropyl) triethoxysilane, N-(2-aminoethyl-)3- aminopropyltrimethoxysilane, and 3-[2-(2-aminoethylamino) ethylamino] propyl trimethoxysilane, respectively. The carboxylic acid derivatives of the amino-functionalized samples were obtained using succinic anhydride. Tminopropyltrimethoxysilanehe obtained modified materials were investigated as matrixes for the anticancer drug (gemcitabine) delivery. The prepared samples were characterized by SAXS, N 2 adsorption/desorption, SEM, transmission electron microscopy, thermogravimetric analysis, and FTIR and UV spectroscopies. The adsorption and release properties of all samples were studied. It was revealed that the adsorption capacity and release behavior of gemcitabine were highly dependent on the type of the introduced functional groups. The carboxylic acid-modified samples have higher loading content, due to the strong interaction with gemcitabine. The maximum content of deposited drug in the modified SBA-15 nanorods is close to 40 wt%. It was found that the surface functionalization leads toward significant decrease of the drug release rate. The carboxylic acid-functionalized samples have slower release rate in contrast with the amino-functionalized samples

  7. 28 CFR 345.52 - Premium pay.

    Science.gov (United States)

    2010-07-01

    ... (FPI) INMATE WORK PROGRAMS Inmate Pay and Benefits § 345.52 Premium pay. Payment of premium pay to... premium pay inmate may refuse the appointment without prejudice. (c) [Reserved] (d) Pay rate. Premium pay...-related. (2) Inmates absent from work for more than 30 consecutive calendar days may be removed from...

  8. Removal of uranium (VI) ion from aqueous solution by SBA-15

    International Nuclear Information System (INIS)

    Wang, Xinghui; Zhu, Guiru; Guo, Feng

    2013-01-01

    Highlights: ► SBA-15 was utilized as an adsorbent for removal of uranium from aqueous solutions. ► The maximum adsorption capacity is 203 mg/g for fresh SBA-15. ► The outer surface of SBA-15 is the main adsorption site. ► Demonstrating an excellent reusability with adsorption capacity of 170 mg/g. - Abstract: SBA-15, a type of mesoporous material, was employed to remove uranium (VI) from aqueous solution. Variables of the batch experiments were investigated including initial concentration, pH of initial solution, contact time, weight of adsorbent, ionic strength and desorption. The results indicate that the adsorption equilibrium can be reached within 30 min with a saturated adsorption capacity of 203 mg/g at optimum pH of 6 for the fresh calcined SBA-15. According to the coefficients, the isothermal data correlates with the Langmuir model better than the Freundlich model, and the adsorption process follows a pseudo-second order rate equation. Five repeated adsorption–desorption cycles were carried out. The maximum adsorption capacity of SBA-15 in the last four cycles is almost kept at 170 mg/g and achieves equilibrium within 10 min. Therefore, SBA-15 could be as a promising adsorbent to remove uranium ion from aqueous solution with large adsorption capacity, fast adsorption rate and reusability

  9. 13 CFR 120.1055 - Review and examination results.

    Science.gov (United States)

    2010-01-01

    ... Risk-Based Lender Oversight Supervision § 120.1055 Review and examination results. (a) Written Reports. SBA will provide an SBA Lender, Intermediary, and NTAP a copy of SBA's written report prepared as a result of the SBA Lender review or examination (“Report”). The Report may contain findings, conclusions...

  10. Paying for Market Quality

    DEFF Research Database (Denmark)

    Anand, Amber; Tanggaard, Carsten; G. Weaver, Daniel

    One way to improve the liquidity of small stocks is to subsidize the providers of liquidity. These subsidies take many forms such as informational advantages, priority in trading with incoming order flow, and fee rebates for limit order traders. In this study, we examine another type of subsidy...... - directly paying liquidity providers to provide contractual improvement in liquidity. Our specific focus here is the 2002 decision by the Stockholm Stock Exchange to allow listed firms to negotiate with liquidity providers to set maximum spread widths and minimum depths. We find, for a sample of stocks...... that entered into such an arrangement, a significant improvement in market quality with a decline in quoted spreads and an increase in quoted depth throughout the limit order book. We also find evidence that suggests that there are improvements beyond those contracted for. In addition, both inter and intraday...

  11. Green buildings pay

    DEFF Research Database (Denmark)

    Naboni, Emanuele; Edwards, Brian

    The new edition of ‘Green Buildings Pay’ authored by Brian Edwards and Emanuele Naboni explores the business and professional benefits which derive from architectural design driven by sustainability. With a new sub-title ‘Green Buildings Pay: design, productivity and ecology’ the book argues...... or environmental thinking and this finds expression in new approaches to the design of building facades, roofs, atria. Another is that new software simulation tools have changed energy assumptions and hence building forms. In a fast evolving arena, the book shows how architects are reshaping their practices....... Branding via LEED and BREEAM has taken green ideas to China and other emerging economies. The globalization of sustainability and of architectural practice is an important strand of the new edition....

  12. Green buildings pay

    DEFF Research Database (Denmark)

    Naboni, Emanuele; Edwards, Brian

    The new edition of ‘Green Buildings Pay’ authored by Brian Edwards and Emanuele Naboni explores the business and professional benefits which derive from architectural design driven by sustainability. With a new sub-title ‘Green Buildings Pay: design, productivity and ecology’ the book argues...... that environmental design has altered how we design, construct and manage buildings. The book has relevance to those who not only design and engineer buildings but to those who commission architecture and those who occupy the products of this process. Hence, the user is a key consideration. The book examines via....... Branding via LEED and BREEAM has taken green ideas to China and other emerging economies. The globalization of sustainability and of architectural practice is an important strand of the new edition....

  13. Pay as you throw

    International Nuclear Information System (INIS)

    Dahlen, Lisa; Lagerkvist, Anders

    2010-01-01

    Householders' response to weight-based billing for the collection of household waste was investigated with the aim of providing decision support for waste management policies. Three questions were addressed: How much and what kind of information on weight-based billing is discernible in generic Swedish waste collection statistics? Why do local authorities implement weight-based billing, and how do they perceive the results? and, Which strengths and weaknesses of weight-based billing have been observed on the local level? The study showed that municipalities with pay-by-weight schemes collected 20% less household waste per capita than other municipalities. Surprisingly, no part of this difference could be explained by higher recycling rates. Nevertheless, the majority of waste management professionals were convinced that recycling had increased as a result of the billing system. A number of contradicting strengths and weaknesses of weight-based billing were revealed.

  14. Paying the price

    International Nuclear Information System (INIS)

    1993-01-01

    In spring 1993 MORI was commissioned to find out whether people think the prices they pay for water, gas, electricity and telephones are reasonable or not. The findings were compared with similar surveys in 1987 and 1990. Overall, more consumers now think prices for these household services are unreasonable compared to three years ago. The biggest shift in opinion is about water bills. One in four customers now feel that water charges are very unreasonable - a rise of nearly nine per cent since 1990. A similar proportion are unhappy with telephone charges, a negative view that has been fairly consistent over six years. There has been little change in people's views about gas and electricity prices since 1990 although satisfaction since 1987 has dropped slightly. (author)

  15. Hybrid All-Pay and Winner-Pay Contests

    DEFF Research Database (Denmark)

    Lagerlöf, Johan

    2017-01-01

    In many contests in economic and political life, both all-pay and winner-pay expenditures matter for winning. This paper studies such hybrid contests under symmetry and asymmetry. The symmetric model is very general but still yields a simple closed-form solution. More contestants tend to lead to ...

  16. Preparation of mesoporous silica films SBA-15 over different substrates

    International Nuclear Information System (INIS)

    Campos, V.O.; Sousa, E.M.B. de; Macedo, W.A.A.

    2010-01-01

    Mesoporous materials have been target of frequent interest due to its wide application possibilities, for example development of gas sensors, catalysis, molecules transportation, pharmaceuticals release, synthesis of auto-organized nanostructures, among others. The possibilities of application are enhanced when such materials are disposed in the form of thin and ultrathin films. In this work the preparation of mesoporous SBA-15 silica films is explored by means of the dipcoating technique of a sol-gel on different substrates (glass slides, stainless steel, copper), using the surfactant poly(ethylene glycol)-block-poly(propylene glycol)- block-poly(ethylene glycol), known as P123, a block copolymer. Synthesis parameters surfactant concentration, aging time and temperature were investigated. In this work we present the morphological and structural characterization of the prepared films, which were obtained using atomic force microscopy and x-ray fluorescence and diffraction. (author)

  17. The impact of the European insolvency regulation on lenders, lending decisions, the structuring of transactions and enforcement of security

    OpenAIRE

    Sharma, R

    2011-01-01

    This Thesis seeks to shed light on the issue of how far secured creditor rights are protected in EU cross-border insolvencies by focusing on the perspective and position of English lenders. The main thread throughout is the legal concerns faced by lenders when lending to a company incorporated in England and Wales which operates across the European Union and has assets and creditors spread across various Member States. The initial stages of the structuring of a cross-border security arrangeme...

  18. Teacher Pay and Teacher Aptitude

    Science.gov (United States)

    Leigh, Andrew

    2012-01-01

    Can changes in teacher pay encourage more able individuals to enter the teaching profession? So far, studies of the impact of pay on the aptitude distribution of teachers have provided mixed evidence on the extent to which altering teacher salaries represents a feasible solution to the teacher quality problem. One possible reason is that these…

  19. Equal Pay for Comparable Work.

    Science.gov (United States)

    Von Frank, Jane

    1980-01-01

    Argues that sex discrimination has depressed salaries for jobs filled primarily by women. Shows that under the Equal Pay Act and Title VII, workers in traditionally female occupations can establish equal pay claims. Suggests approaches for developing legal and enforcement standards to deal with discriminatory compensation in traditionally female…

  20. 13 CFR 108.470 - SBA approval of merger, consolidation, or reorganization of NMVC Company.

    Science.gov (United States)

    2010-01-01

    ... BUSINESS ADMINISTRATION NEW MARKETS VENTURE CAPITAL (âNMVCâ) PROGRAM Changes in Ownership, Structure, or... partnership) or reorganize without SBA's prior written approval. Any such merger or consolidation will be...

  1. Calorimetric Study of Mesoporous SBA-15 Modified for Controlled Valproic Acid Delivery

    Directory of Open Access Journals (Sweden)

    Liliana Giraldo

    2013-01-01

    Full Text Available SBA-15 ordered mesoporous silica functionalized with (3-aminopropyltriethoxysilane (APTES was used as the carrier for anticonvulsant drug 2-propylpentanoic acid (valproic acid. The surface of SBA-15 containing free silanol groups was modified with 3-aminopropyltriethoxysilane via postsynthetic reaction. Functionalization of the carrier with basic aminopropyl groups resulted in an ionic interaction with acidic valproic acid. The samples of carriers and carrier-drug complexes were characterized by elemental analysis, N2 adsorption, FTIR, and UV spectroscopy. The adsorption of valproic acid on modified mesoporous matrix was proportional to the amount of introduced aminopropyl groups. A thermodynamic study with isothermal titration calorimetry (ITC was made to characterize the modification and encapsulation of SBA-15 with APTES and valproic acid, respectively. The maximum content of deposited drug in modified SBA-15 was close to 30 wt.%. Tests performed in acidic solution (pH 2.0 showed the best pharmaceutical availability.

  2. The Analysis of Simulation Based Acquisition (SBA) Economic Breakpoints in the Life Cycle of Major Programs

    National Research Council Canada - National Science Library

    Hunt, George

    2002-01-01

    ...). Application of SBA initiatives relies upon the use of modeling and simulation, among other methods, to effectively use scarce resources funds, manpower, equipment in the life cycle of major programs...

  3. Dehydrogenation of Isobutane with Carbon Dioxide over SBA-15-Supported Vanadium Oxide Catalysts

    OpenAIRE

    Chunling Wei; Fangqi Xue; Changxi Miao; Yinghong Yue; Weimin Yang; Weiming Hua; Zi Gao

    2016-01-01

    A series of vanadia catalysts supported on SBA-15 (V/SBA) with a vanadia (V) content ranging from 1% to 11% were prepared by an incipient wetness method. Their catalytic behavior in the dehydrogenation of isobutane to isobutene with CO2 was examined. The catalysts were characterized by N2 adsorption, X-ray diffraction (XRD), scanning electron microscopy (SEM), Raman spectroscopy, and temperature-programmed reduction (TPR). It was found that these catalysts were effective for the dehydrogenati...

  4. The European central bank and the us federal reserve as lender of last resort

    Directory of Open Access Journals (Sweden)

    Herr Hansjörg

    2014-01-01

    Full Text Available Without a lender of last resort financial stability is not possible and systemic financial crises get out of control. During and after the Great Recession the US Federal Reserve System (Fed and the European Central Bank (ECB took on the role of lender of last resort in a comprehensive way. The Fed stabilised the financial system, including the shadow banking system. However, the chance to fundamentally restructure the financial system was not used. The ECB was confronted with sovereign debt crises and an incomplete integration of the European Monetary Union (EMU. It followed a kind of “muddling through” to keep the Euro area together. In the EMU not only a fundamental restructuring of the financial system is needed but also a deeper economic and political integration. The Fed and the ECB both were the most important institutions to avoid repetition of the 1930s.

  5. Paying for family planning.

    Science.gov (United States)

    1998-09-12

    Both houses of the US Congress have passed bills to require that all health plans for federal employees which pay for prescription medications also cover prescription contraceptives approved by the US Food and Drug Administration (USFDA). Of these, the five most commonly prescribed are contraceptive pills, implantable levonorgestrel (Norplant), long-acting injectable medroxyprogesterone acetate (Depo-provera), IUDs, and the diaphragm. Differences between the two bills are now being worked out by a joint House-Senate committee and passage seems almost certain. If a compromise joint bill is passed by both houses, it would cover plans which insure more than 1 million reproductive age women. However, the Equity in Prescription and Contraceptive Coverage (EPICC) Act requiring all US private health plans to cover contraceptive prescriptions is less certain to eventually become legislation. Currently, only 49% of traditional indemnity plans and 39% of health maintenance organizations cover the five most commonly prescribed reversible methods of contraception, while many health plans cover no form of contraception, other than sterilization. The passage of EPICC would expand contraceptive choice for another 45 million US women of childbearing age. Opposition to both bills has come mainly from health insurance and business groups, as well as conservative groups which oppose funding for family planning. Supporters of legislation to expand contraceptive choice for US women should understand that the right to reproductive health and contraceptive services extends beyond US borders, and pressure Congress to bolster US financial support for international population control programs.

  6. 4 CFR 5.1 - Pay.

    Science.gov (United States)

    2010-01-01

    ... fixed by the Comptroller General consistent with the principles that— (1) There be equal pay for work of substantially equal value. (2) Pay distinctions be maintained in keeping with work and performance distinctions. (3) Pay rates be comparable with private enterprise pay rates for the same levels of work. (4) Pay...

  7. Fischer-Tropsch synthesis in slurry-phase reactors using Co/SBA-15 catalysts

    Energy Technology Data Exchange (ETDEWEB)

    Rodrigues, J.J.; Lima, L.A.; Lima, W.S.; Rodrigues, M.G.F. [Universidade Federal de Campina Grande (UFCG), PB (Brazil). Unidade Academica de Engenharia Quimica], e-mail: meiry@deq.ufcg.edu.br; Fernandes, F.A.N. [Universidade Federal do Ceara (UFCE), CE (Brazil). Dept. de Engenharia Quimica

    2011-07-15

    The objective of this work is to describe the production of bifunctional catalysts using the incipient humidity method, producing catalysts with 15 wt.% cobalt supported in SBA-15 molecular sieve, to be applied in the Fischer-Tropsch (FT) reaction. The originality of this work is its focus on the use of a 15 wt.% Co/SBA-15 catalyst in FT synthesis in slurry reactors. The deposition of cobalt over SBA-15 support was accomplished by impregnation with a 0.1-M aqueous solution of cobalt nitrate. The Fischer-Tropsch synthesis was carried out with the catalyst at 240 deg C and 20 atm, under a COH{sub 2} atmosphere (molar ratio= 1), in a slurry reactor for 8 hours. X-ray diffraction measurements showed that the calcined cobalt catalyst did not modify the structure of SBA-15, proving that Co was present under the form of Co{sub 3}O{sub 4} in the catalyst. The addition of cobalt in the SBA-15 decreased the specific superficial area of the molecular sieve. The 15 wt.% Co/SBA-15 catalyst had a 40% CO conversion rate and a high selectivity towards the production of C{sub 5}{sup +} (53.9% after 8 hours). (author)

  8. Evidence for metalsupport interactions in Au modified TiO_{x}/SBA-15 materials prepared by photodeposition

    OpenAIRE

    Mei, Bastian; Wiktor, Christian; Turner, Stuart; Pougin, Anna; Tendeloo, Van, Gustaaf; Fischer, Roland A.; Muhler, Martin; Strunk, Jennifer

    2013-01-01

    Abstract: Gold nanoparticles have been efficiently photodeposited onto titanate-loaded SBA-15 (Ti(x)/SBA-15) with different titania coordination. Transmission electron microscopy shows that relatively large Au nanoparticles are photodeposited on the outer surface of the Ti(x)/SBA-15 materials and that TiOx tends to form agglomerates in close proximity to the Au nanoparticles, often forming coreshell Au/TiOx structures. This behavior resembles typical processes observed due to strong-metal sup...

  9. 13 CFR 107.1630 - SBA regulation of Brokers and Dealers and disclosure to purchasers of Leverage or Trust...

    Science.gov (United States)

    2010-01-01

    ... Credit and Assistance SMALL BUSINESS ADMINISTRATION SMALL BUSINESS INVESTMENT COMPANIES SBA Financial... standing in respect to compliance with the financial, ethical, and reporting requirements of such body...

  10. Fine CuO anisotropic nanoparticles supported on mesoporous SBA-15 for selective hydrogenation of nitroaromatics.

    Science.gov (United States)

    Sareen, Shweta; Mutreja, Vishal; Singh, Satnam; Pal, Bonamali

    2016-01-01

    SBA-15 modified with APTMS (3-aminopropyl trimethoxysilane) having pore diameter (∼8 nm) has been synthesized and impregnated with 1-10 wt.% Cu using Cu(NO3)2 as a metal source followed by calcination at 350 °C. As-prepared CuO/ap-SBA-15 powder showed changes in the color from white for bare SBA-15 to light green due to formation of anisotropic CuO nanoparticles that exhibited a characteristic plasmon absorption band at 359 and 747 nm. TEM studies showed a change in the morphology of CuO NPs as a function of increased Cu loading. Moreover, well dispersed CuO nanospheres (∼5-6 nm) and nanorods (aspect ratio ∼11-20 nm) having monoclinic crystal phase were observed within the mesoporous channels of SBA-15. Elemental mapping studies confirmed uniform distribution of CuO nanoparticles on the surface of SBA-15. An increase in surface area was also observed from 694 m(2) g(-1) for SBA-15 to 762 m(2) g(-1) for 10 wt.% Cu loading probably due to the deposition of excess of CuO nanoparticles on the outer siliceous surface. The catalytic activity also increased with Cu loading and 10 wt.% CuO/ap-SBA-15 catalyst displayed the highest catalytic activity for the reduction of m-chloronitrobenzene and m-nitrotoluene with 83% and 100% selectivity for m-chloroaniline and m-aminotoluene respectively. Copyright © 2015 Elsevier Inc. All rights reserved.

  11. VOx species supported on Al2O3-SBA-15 prepared by the grafting of alumina onto SBA-15: structure and activity in the oxidative dehydrogenation of ethane

    Czech Academy of Sciences Publication Activity Database

    Botková, Š.; Čapek, L.; Setnička, M.; Bulánek, R.; Čičmanec, P.; Kalužová, A.; Pastva, Jakub; Zukal, Arnošt

    2016-01-01

    Roč. 119, č. 1 (2016), s. 319-333 ISSN 1878-5190 R&D Projects: GA ČR GAP106/10/0196 Institutional support: RVO:61388955 Keywords : Ethane * UV-Vis * VOx species * Al2O3-SBA-15 Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 1.264, year: 2016

  12. Inclusion of cefalexin in SBA-15 mesoporus material and release property

    Energy Technology Data Exchange (ETDEWEB)

    Zhai, Qing-Zhou, E-mail: zhaiqingzhou@163.com

    2012-12-01

    SBA-15 (Santa Barbara Amorphous-15) is a high ordered mesoporous material. It has the advantages of a non-toxic property, good hydrothermal stability and thermal stability, etc. Inside inner surface a lot of silanols exist. Pore diameter size is uniform and pore size distribution is narrow. This structural feature makes SBA-15 have a higher loading drug amount and be able to effectively extend the drug release cycle. In this paper, polyethylene glycol-block-polypropylene glycol-block-polyethylene glycol was used as template and tetraethyl orthosilicate was used as silica source to prepare SBA-15 by hydrothermal synthesis method. Cefalexin was included in SBA-15 and the included cefalexin drug content was 158.72 mg/g. The composite materials were characterized by using chemical analysis, powder X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), infrared (IR) spectroscopy, and low temperature nitrogen adsorption-desorption. The results showed that cefalexin had been successfully included in host SBA-15 pore channels. Rational analyses of the release processes of cefalexin drug from the pores of SBA-15 to the simulated body fluid, simulated gastric juice and simulated intestinal fluid were made and sustained-release effects of the drug in complex system were studied. The results showed that in simulated body fluid within 1-5 h cefalexin was fast released and the cumulative release reached 50.00% at 5 h. In 15-20 h, the sustained release speed of cefalexin drug in the composite material decreased and the sustained-release cumulative amount reached 99.87% at 20 h. The release of cefalexin was basically complete. In simulated gastric fluid, composite material sustained-release ended at 4 h, the cumulative sustained release ratio reaching 26.10%. In simulated gastric fluid, the sustained-release was complete at 7 h, the cumulative sustained release ratio reaching 32.46%. The composite material of SBA-15 and cefalexin could

  13. Inclusion of cefalexin in SBA-15 mesoporus material and release property

    International Nuclear Information System (INIS)

    Zhai, Qing-Zhou

    2012-01-01

    SBA-15 (Santa Barbara Amorphous-15) is a high ordered mesoporous material. It has the advantages of a non-toxic property, good hydrothermal stability and thermal stability, etc. Inside inner surface a lot of silanols exist. Pore diameter size is uniform and pore size distribution is narrow. This structural feature makes SBA-15 have a higher loading drug amount and be able to effectively extend the drug release cycle. In this paper, polyethylene glycol-block-polypropylene glycol-block-polyethylene glycol was used as template and tetraethyl orthosilicate was used as silica source to prepare SBA-15 by hydrothermal synthesis method. Cefalexin was included in SBA-15 and the included cefalexin drug content was 158.72 mg/g. The composite materials were characterized by using chemical analysis, powder X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), infrared (IR) spectroscopy, and low temperature nitrogen adsorption–desorption. The results showed that cefalexin had been successfully included in host SBA-15 pore channels. Rational analyses of the release processes of cefalexin drug from the pores of SBA-15 to the simulated body fluid, simulated gastric juice and simulated intestinal fluid were made and sustained-release effects of the drug in complex system were studied. The results showed that in simulated body fluid within 1–5 h cefalexin was fast released and the cumulative release reached 50.00% at 5 h. In 15–20 h, the sustained release speed of cefalexin drug in the composite material decreased and the sustained-release cumulative amount reached 99.87% at 20 h. The release of cefalexin was basically complete. In simulated gastric fluid, composite material sustained-release ended at 4 h, the cumulative sustained release ratio reaching 26.10%. In simulated gastric fluid, the sustained-release was complete at 7 h, the cumulative sustained release ratio reaching 32.46%. The composite material of SBA-15 and cefalexin

  14. The synthesis of novel hybrid thiol-functionalized nano-structured SBA-15

    International Nuclear Information System (INIS)

    Hoang, Van Duc; Dang, Tuyet Phuong; Dinh, Quang Khieu; Vu, Anh Tuan; Nguyen, Huu Phu

    2010-01-01

    Mesoporous thiol-functionalized SBA-15 has been directly synthesized by co-condensation of tetraethyl orthosilicate (TEOS) and 3-mercaptopropyltrimethoxysilane (MPTMS) with triblock copolymer P123 as-structure-directing agent under hydrothermal conditions. Surfactant removal was performed by Soxhlet ethanol extraction. These materials have been characterized by powder x-ray diffraction (XRD), nitrogen adsorption/desorption (BET model), transmission electron microscopy (TEM), thermal analysis, infrared spectroscopy (IR) and energy-dispersive x-ray spectroscopy (EDX). The main parameters, such as the initial molar ratio of MPTMS to TEOS, the time of adding MPTMS to synthesized gel and the Soxhlet ethanol extraction on the thiol functionalized SBA-15 with high thiol content and highly ordered hexagonal mesostructure, were investigated and evaluated. The adsorption capacity of the thiol-functionalized and non-functionalized SBA-15 materials for Pb 2+ ion from aqueous solution was tested. It was found that the Pb 2+ adsorption capacity of the thiol functionalized SBA-15 is three times higher than that of non-functionalized SBA-15

  15. Immobilization of lipase and keratinase on functionalized SBA-15 nanostructured materials

    Science.gov (United States)

    Le, Hy G.; Vu, Tuan A.; Tran, Hoa T. K.; Dang, Phuong T.

    2013-12-01

    SBA-15 nanostructured materials were synthesized via hydrothermal treatment and were functionalized with 3- aminopropyltriethoxysilane (APTES). The obtained samples were characterized by different techniques such as XRD, BET, TEM, IR and DTA. After functionalization, it showed that these nanostrucrured materials still maintained the hexagonal pore structure of the parent SBA-15. The model enzyms chosen in this study were lipase and keratinase. Lipase was a biocatalyst for hydrolyzation of long chain triglycerides or methyl esters of long chain alcohols and fatty acids; keratinase is a proteolytic enzyme that catalyzes the cleavage of keratin. The functionalized SBA-15 materials were used to immobilize lipase and keratinase, exhibiting higher activity than that of the unfunctionalized pure silica SBA-15 ones. This might be due to the enhancing of surface hydrophobicity upon functionalization. The surface functionalization of the nanostructured silicas with organic groups can favor the interaction between enzyme and the supports and consequently increasing the operational stability of the immobilized enzymes. The loading of lipase on functionalized SBA-15 materials was higher than that of keratinase. This might be rationalized by the difference in size of enzyms.

  16. 5 CFR 9701.356 - Pay retention.

    Science.gov (United States)

    2010-01-01

    ... Administrative Personnel DEPARTMENT OF HOMELAND SECURITY HUMAN RESOURCES MANAGEMENT SYSTEM (DEPARTMENT OF HOMELAND SECURITY-OFFICE OF PERSONNEL MANAGEMENT) DEPARTMENT OF HOMELAND SECURITY HUMAN RESOURCES MANAGEMENT SYSTEM Pay and Pay Administration Pay Administration § 9701.356 Pay retention. (a) Subject to the...

  17. Silver Nanoparticles Confined in SBA-15 Mesoporous Silica and the Application as a Sensor for Detecting Hydrogen Peroxide

    Directory of Open Access Journals (Sweden)

    Dong-Hai Lin

    2008-01-01

    Full Text Available Silver nanoparticles within the pore channels of selectively grafted mesoporous silica SBA-15 were synthesized. Silanols on the external surface of as-SBA-15 were first capped by –Si(CH33 groups. After removal of the template of capped SBA-15 by calcination, silanols on the internal surface of SBA-15 were modified by 3-aminopropyltrimethoxysilane (APTMS, and then formaldehyde was grafted by amino groups of APTMS, and further Ag(NH32NO3SBA-15. High-resolution transmission electron microscopy (HRTEM, X-ray diffraction (XRD, Fourier transformation infrared spectroscopy (FTIR, nitrogen adsorption/desorption isotherms, and UV-vis spectra confirm that the silver nanoparticles have been confined inside the channels of SBA-15. In addition, the Ag-mSBA-15 modified electrode (Ag-mSBA-15/GC exhibited an excellent electrocatalytic activity toward the reduction of hydrogen peroxide (H2O2. The proposed H2O2 sensor exhibits a linear range of 48.5 μM–0.97 M with a detection limit of 12 μM (S/N=3 and analytical time of 10 seconds per sample.

  18. 48 CFR 619.804-3-70 - SBA acceptance under MOUs for acquisitions exceeding $100,000.

    Science.gov (United States)

    2010-10-01

    ... the contracting agency may grant, an extension beyond the five-day limit. (c) SBA's acceptance letter... 48 Federal Acquisition Regulations System 4 2010-10-01 2010-10-01 false SBA acceptance under MOUs... System DEPARTMENT OF STATE SOCIOECONOMIC PROGRAMS SMALL BUSINESS PROGRAMS Contracting with the Small...

  19. 13 CFR 120.425 - What are the minimum elements that SBA will require before consenting to a securitization?

    Science.gov (United States)

    2010-01-01

    ... SBA will require before consenting to a securitization? 120.425 Section 120.425 Business Credit and... What are the minimum elements that SBA will require before consenting to a securitization? A... any securitization pools. Each nondepository institution must submit annual audited financial...

  20. 7 CFR Exhibit B to Subpart F of... - Suggested Outline for Seeking Information From Lenders on Credit Criteria for Graduation of...

    Science.gov (United States)

    2010-01-01

    ... 7 Agriculture 14 2010-01-01 2009-01-01 true Suggested Outline for Seeking Information From Lenders... Seeking Information From Lenders on Credit Criteria for Graduation of Single Family Housing Loans Date... (CONTINUED) PROGRAM REGULATIONS (CONTINUED) SERVICING AND COLLECTIONS Analyzing Credit Needs and Graduation...

  1. A Pd/SBA-15 composite: synthesis, characterization and protein biosensing

    Energy Technology Data Exchange (ETDEWEB)

    Liu Yuge; Zhang Jingjing; Hou Wenhua; Zhu Junjie [Key Laboratory of Mesoscopic Chemistry and Key Laboratory of Analytical Chemistry for Life Science, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093 (China)], E-mail: whou@nju.edu.cn, E-mail: jjzhu@nju.edu.cn

    2008-04-02

    In this paper, palladium (Pd) nanoparticles have been successfully encapsulated into the channels of modified SBA-15 in situ via a facile, ethylene glycol (EG)-assisted sonochemical method. The products were confirmed by x-ray diffraction, transmission electron microscopy (TEM) and nitrogen adsorption analysis. The Pd/SBA-15 composite was used for the realization of direct electron transfer of hemoglobin (Hb). Electrochemical results showed that the Pd nanoparticles in the channels of SBA-15 could enhance the direct electron transfer between Hb and the electrode surface. The composite modified electrode displayed excellent electrochemical behavior. The sensor fabricated by the composite showed an excellent response to the reduction of hydrogen peroxide (H{sub 2}O{sub 2}), and the linear range for the determination of H{sub 2}O{sub 2} was from 1.8 to 119.3 {mu}M with a detection limit of 0.8 {mu}M.

  2. Hydrothermal Synthesis of SBA-15 Using Sodium Silicate Derived from Coal Gangue

    Directory of Open Access Journals (Sweden)

    Jing Wang

    2013-01-01

    Full Text Available Well-ordered SBA-15 was prepared with a hydrothermal route by sodium silicate derived from coal gangue. The as-prepared sample was analyzed by SAXRD, BET, TEM, and SEM, respectively. The results indicate that at a low hydrothermal temperature of 100∘C the well-ordered mesoporous SBA-15 could be synthesized. The surface area, pore volume, and pore size of the sample are 552 m2/g, 0.54 cm3/g, and 7.0 nm, respectively. It is suggested that coal gangue could be used in obtaining an Si source to prepare mesoporous materials, such as SBA-15.

  3. Study on catalytic properties and carbon deposition of Ni-Cu/SBA-15 for cyclohexane dehydrogenation

    Science.gov (United States)

    Xia, Zhijun; Liu, Huayan; Lu, Hanfeng; Zhang, Zekai; Chen, Yinfei

    2017-11-01

    A series of Ni-Cu supported on SBA-15 were prepared by impregnation, and used as catalysts in cyclohexane dehydrogenation for hydrogen production. The results indicated that the addition of Cu into Ni changes the crystal structure of metal Ni, and forms Ni-Cu alloy. Thus, Cu improves the reduction properties of Ni. Conversely, Ni stables and disperses metal Cu. With the space limitation of the ordered channels and high surface area of SBA-15, the bimetallic Ni-Cu/SBA-15 catalysts expose large amounts of selective active sites composed uniformly with Ni and Cu. Therefore, they present not only excellent catalytic performance for cyclohexane dehydrogenation, but also low coke formation. The in-situ DRIFT studies have shown the vinyl species, indicating the existence of alkenes in the reactive intermediates. Additionally, the strong absorption of benzene on the metal could induce benzene was dehydrogenated further to carbon.

  4. Ni-exchanged AlSBA-15 mesoporous materials as outstanding catalysts for ethylene oligomerization

    Science.gov (United States)

    Andrei, R. D.; Mureseanu, M.; Popa, M. I.; Cammarano, C.; Fajula, F.; Hulea, V.

    2015-07-01

    Ni-exchanged mesoporous materials with SBA-15 topology were prepared by post-synthesis alumination of SBA-15 silica with sodium aluminate at room temperature, followed by ion exchange with nickel. Exploration of various parameters resulted in a simple preparation method for catalysts with perfect pore system and aluminium tetrahedrally coordinated in the silica framework for Si/Al > 6. These properties were proved by using appropriate characterisation techniques, including powder X-ray diffraction, N2 sorption, TEM, and 27Al MAS NMR. Ni-AlSBA-15 exhibited outstanding catalytic properties in the oligomerization reaction of ethylene performed at 150 ∘C and 3.5 MPa. Activity up to 175 g of oligomers per gram of catalyst per hour was the highest reported to date with Ni-based solid catalysts.

  5. Removal of patulin from aqueous solutions by propylthiol functionalized SBA-15.

    Science.gov (United States)

    Appell, Michael; Jackson, Michael A; Dombrink-Kurtzman, Mary Ann

    2011-03-15

    Propylthiol functionalized SBA-15 silica was investigated to detoxify aqueous solutions contaminated with the regulated mycotoxin patulin. Micelle templated silicas with a specific pore size were synthetically modified to possess propylthiol groups, a functional group known to form Michael reaction products with the conjugated double bond system of patulin. BET surface area analysis indicated the propylthiol functionalized SBA-15 possesses channels with the pore size of 5.4 nm and a surface area of 345 m(2)g(-1). Elemental analysis indicates the silicon/sulfur ratio to be 10:1, inferring one propylthiol substituent for every ten silica residues. The propylthiol modified SBA-15 was effective at significantly reducing high levels of patulin from aqueous solutions (pH 7.0) in batch sorption assays at room temperature. The material was less effective at lower pH; however heating low pH solutions and apple juice to 60 °C in the presence of propylthiol functionalized SBA-15 significantly reduced the levels of patulin in contaminated samples. Composite molecular models developed by semi-empirical PM3 and empirical force field methods support patulin permeation through the mesoporous channels of propylthiol functionalized SBA-15. Density functional study at the B3LYP/6-31G(d,p) level predicts the proposed patulin adducts formed by reaction with the thiol residues exhibit less electrophilic properties than patulin. It is demonstrated the use of propylthiol functionalized SBA-15 is a viable approach to reduce patulin levels in aqueous solutions, including contaminated apple juice. Published by Elsevier B.V.

  6. Removal of patulin from aqueous solutions by propylthiol functionalized SBA-15

    Energy Technology Data Exchange (ETDEWEB)

    Appell, Michael, E-mail: michael.appell@ars.usda.gov [Bacterial Foodborne Pathogens and Mycology Research Unit, United States Department of Agriculture, Agricultural Research Service, National Center for Agricultural Utilization Research, 1815 N. University St., Peoria, IL 61604 (United States); Jackson, Michael A.; Dombrink-Kurtzman, Mary Ann [Renewable Product Technology Research Unit, United States Department of Agriculture, Agricultural Research Service, National Center for Agricultural Utilization Research, 1815 N. University St., Peoria, IL 61604 (United States)

    2011-03-15

    Propylthiol functionalized SBA-15 silica was investigated to detoxify aqueous solutions contaminated with the regulated mycotoxin patulin. Micelle templated silicas with a specific pore size were synthetically modified to possess propylthiol groups, a functional group known to form Michael reaction products with the conjugated double bond system of patulin. BET surface area analysis indicated the propylthiol functionalized SBA-15 possesses channels with the pore size of 5.4 nm and a surface area of 345 m{sup 2} g{sup -1}. Elemental analysis indicates the silicon/sulfur ratio to be 10:1, inferring one propylthiol substituent for every ten silica residues. The propylthiol modified SBA-15 was effective at significantly reducing high levels of patulin from aqueous solutions (pH 7.0) in batch sorption assays at room temperature. The material was less effective at lower pH; however heating low pH solutions and apple juice to 60 deg, C in the presence of propylthiol functionalized SBA-15 significantly reduced the levels of patulin in contaminated samples. Composite molecular models developed by semi-empirical PM3 and empirical force field methods support patulin permeation through the mesoporous channels of propylthiol functionalized SBA-15. Density functional study at the B3LYP/6-31G(d,p) level predicts the proposed patulin adducts formed by reaction with the thiol residues exhibit less electrophilic properties than patulin. It is demonstrated the use of propylthiol functionalized SBA-15 is a viable approach to reduce patulin levels in aqueous solutions, including contaminated apple juice.

  7. Removal of patulin from aqueous solutions by propylthiol functionalized SBA-15

    International Nuclear Information System (INIS)

    Appell, Michael; Jackson, Michael A.; Dombrink-Kurtzman, Mary Ann

    2011-01-01

    Propylthiol functionalized SBA-15 silica was investigated to detoxify aqueous solutions contaminated with the regulated mycotoxin patulin. Micelle templated silicas with a specific pore size were synthetically modified to possess propylthiol groups, a functional group known to form Michael reaction products with the conjugated double bond system of patulin. BET surface area analysis indicated the propylthiol functionalized SBA-15 possesses channels with the pore size of 5.4 nm and a surface area of 345 m 2 g -1 . Elemental analysis indicates the silicon/sulfur ratio to be 10:1, inferring one propylthiol substituent for every ten silica residues. The propylthiol modified SBA-15 was effective at significantly reducing high levels of patulin from aqueous solutions (pH 7.0) in batch sorption assays at room temperature. The material was less effective at lower pH; however heating low pH solutions and apple juice to 60 deg, C in the presence of propylthiol functionalized SBA-15 significantly reduced the levels of patulin in contaminated samples. Composite molecular models developed by semi-empirical PM3 and empirical force field methods support patulin permeation through the mesoporous channels of propylthiol functionalized SBA-15. Density functional study at the B3LYP/6-31G(d,p) level predicts the proposed patulin adducts formed by reaction with the thiol residues exhibit less electrophilic properties than patulin. It is demonstrated the use of propylthiol functionalized SBA-15 is a viable approach to reduce patulin levels in aqueous solutions, including contaminated apple juice.

  8. Single-site SBA-15 supported zirconium catalysts. Synthesis, characterization and toward cyanosilylation reaction

    International Nuclear Information System (INIS)

    Xu, Wei; Yu, Bo; Zhang, Ying; Chen, Xi; Zhang, Guofang; Gao, Ziwei

    2015-01-01

    Graphical abstract: Ligand-modified signal-site SBA-15 supported zirconium catalysts were synthesized by SOMC method and characterized by a variety of techniques. The zirconium surface complexes show high catalytic efficiency for cyanosilylation of benzaldehyde. - Highlights: • Some Zr active species have been anchored on the surface of SBA-15 by SOMC technique. • The structures of the Zr species have been characterized by a variety of techniques. • The anchored Zr species are single-sited surface complexes. • The Zr surface complexes are catalytic active for cyanosilylation of benzaldehyde. - Abstract: A successive anchoring of Zr(NMe 2 ) 4 , cyclopentadiene and a O-donor ligand, 1-hydroxyethylbenzene (PEA), 1,1′-bi-2-naphthol (Binol) or 2,3-dihydroxybutanedioic acid diethyl ester (Tartrate), on dehydroxylated SBA-15 pretreated at 500 °C for 16 h (SBA-15 -500 ) was conducted by SOMC strategy in moderate conditions. The dehydoxylation of SBA-15 was monitored by in situ Fourier transform infrared spectroscopy (in situ FT-IR). The ligand-modified SBA-15 -500 supported zirconium complexes were characterized by in situ FT-IR, 13 C CP MAS-NMR, X-ray photoelectron spectroscopy (XPS), inductively coupled plasma mass spectrometry (ICP-MAS) and elemental analysis in detail, verifying that the surface zirconium species are single-sited. The catalytic activity of these complexes was evaluated by cyanosilylation of benzaldehyde. The results showed that the catalytic activity is dependent strongly on the structure of surface species and the configuration of the ligands

  9. Single-site SBA-15 supported zirconium catalysts. Synthesis, characterization and toward cyanosilylation reaction

    Energy Technology Data Exchange (ETDEWEB)

    Xu, Wei; Yu, Bo; Zhang, Ying; Chen, Xi; Zhang, Guofang, E-mail: gfzhang@snnu.edu.cn; Gao, Ziwei, E-mail: zwgao@snnu.edu.cn

    2015-01-15

    Graphical abstract: Ligand-modified signal-site SBA-15 supported zirconium catalysts were synthesized by SOMC method and characterized by a variety of techniques. The zirconium surface complexes show high catalytic efficiency for cyanosilylation of benzaldehyde. - Highlights: • Some Zr active species have been anchored on the surface of SBA-15 by SOMC technique. • The structures of the Zr species have been characterized by a variety of techniques. • The anchored Zr species are single-sited surface complexes. • The Zr surface complexes are catalytic active for cyanosilylation of benzaldehyde. - Abstract: A successive anchoring of Zr(NMe{sub 2}){sub 4}, cyclopentadiene and a O-donor ligand, 1-hydroxyethylbenzene (PEA), 1,1′-bi-2-naphthol (Binol) or 2,3-dihydroxybutanedioic acid diethyl ester (Tartrate), on dehydroxylated SBA-15 pretreated at 500 °C for 16 h (SBA-15{sub -500}) was conducted by SOMC strategy in moderate conditions. The dehydoxylation of SBA-15 was monitored by in situ Fourier transform infrared spectroscopy (in situ FT-IR). The ligand-modified SBA-15{sub -500} supported zirconium complexes were characterized by in situ FT-IR, {sup 13}C CP MAS-NMR, X-ray photoelectron spectroscopy (XPS), inductively coupled plasma mass spectrometry (ICP-MAS) and elemental analysis in detail, verifying that the surface zirconium species are single-sited. The catalytic activity of these complexes was evaluated by cyanosilylation of benzaldehyde. The results showed that the catalytic activity is dependent strongly on the structure of surface species and the configuration of the ligands.

  10. Magnetic properties of nanocomposite Fe-doped SBA-15 magnetic materials

    International Nuclear Information System (INIS)

    Jin, H.X.; Li, L.; Chu, N.J.; Liu, Y.P.; Wang, L.Y.; Lu, Q.; Qian, J.; Sun, L.N.; Tang, Q.; Ge, H.L.; Wang, X.Q.

    2008-01-01

    Fe-doped SBA-15 magnetic materials was synthesized by pH-adjusting method, and then characterized by X-ray diffraction (XRD) and vibrating sample magnetometer (VSM). All results showed that the samples presented ferromagnetism and the magnetism improved with the Fe content. Saturation magnetization and coercivity of the as-prepared Fe-doped SBA-15 samples increased with the calcined temperature up to 850 deg. C, followed by decreasing. Furthermore, the magnetic properties at lower temperature (measured at 100 K) of the Fe-doped samples was presented. Finally, the type of the intergranular exchange interaction was conformed by plotting Henkel (δM) formulation

  11. Surface functionalization of SBA-15 by the solvent-free method

    International Nuclear Information System (INIS)

    Wang Yimeng; Zheng Yingwu; Zhu Jianhua

    2004-01-01

    A solvent-free technique was employed for fast modification of mesoporous materials. Copper, chromium and iron oxide species could be highly dispersed in SBA-15 by manually grinding the corresponding precursor salts and the host, followed by calcinations for the first time. This method is more effective to spontaneously disperse oxide species onto SBA-15 than impregnation, probably forming monolayer or submonolayer dispersion of salts or oxides. Besides, Cr(VI) species dominate in the mixing sample while Cr(III) species dominate in the impregnation one. In the temperature programmed surface reaction of nitrosamines, the sample prepared by solvent-free method showed a higher catalytic activity than the impregnation one

  12. SBA-15 Mesoporous Silica as Catalytic Support for Hydrodesulfurization Catalysts—Review

    Science.gov (United States)

    Huirache-Acuña, Rafael; Nava, Rufino; Peza-Ledesma, Carmen L.; Lara-Romero, Javier; Alonso-Núñez, Gabriel; Pawelec, Barbara; Rivera-Muñoz, Eric M.

    2013-01-01

    SBA-15 is an interesting mesoporous silica material having highly ordered nanopores and a large surface area, which is widely employed as catalyst supports, absorbents, drug delivery materials, etc. Since it has a lack of functionality, heteroatoms and organic functional groups have been incorporated by direct or post-synthesis methods in order to modify their functionality. The aim of this article is to review the state-of-the-art related to the use of SBA-15-based mesoporous systems as supports for hydrodesulfurization (HDS) catalysts. PMID:28788323

  13. Oil price risk management in the 1990s - issues for producers and lenders

    International Nuclear Information System (INIS)

    Lambert, S.

    1994-01-01

    Oil prices have exhibited considerable volatility over the past five or ten years and the management of oil price risk has become an important factor in underpinning the viability of many oil producing operations from both a lender's and investor's perspective. Various oil based hedging products are now available to protect against such volatility, ranging from products which fix forward prices to option based arrangements which set a floor price but retain some (or all) of the potential upside. These products have particular relevance for petroleum companies with limited financial resources or who are looking to limit recourse to particular assets/cash flows. There are a number of techniques which can be successfully combined to mitigate oil price volatility and the most relevant of these to a producer are discussed. The recent development of the Tapis swap and option markets, which have provided flexibility to Australasian producers, is also discussed. Oil based financial products can also be used as a method of funding (e.g. for a development or acquisition) as an alternative to traditional cash based borrowing structures, thus creating a natural hedge against oil price movements. It is estimated that the use of such structures, coupled with a well structured revenue hedging program, can enhance a project's attractiveness from a lender's perspective (particularly with respect to protection against down side movements in oil price) and/or provide greater certainty of returns to producers. A case study of a recent commodity risk management based financing is presented. 1 fig., 6 tabs

  14. TAP: More than Performance Pay

    Science.gov (United States)

    Sawchuk, Stephen

    2009-01-01

    Since its inception, the program has tackled the most challenging issue facing the teaching profession: how to align systems for managing schools' human capital with goals for improving student achievement. In addition to pay, the Teacher Advancement Program (TAP) shapes new approaches to on-the-job training, career advancement, and evaluation in…

  15. 13 CFR 120.1051 - Frequency of on-site reviews and examinations.

    Science.gov (United States)

    2010-01-01

    ... LOANS Risk-Based Lender Oversight Supervision § 120.1051 Frequency of on-site reviews and examinations. SBA may conduct on-site reviews and examinations of SBA Lenders, Intermediaries, and NTAPs on a...) Off-site review/monitoring results, including an SBA Lender's, Intermediary's or NTAP's Risk Rating...

  16. Microstructure and Magnetic Properties of Highly Ordered SBA-15 Nanocomposites Modified with Fe2O3 and Co3O4 Nanoparticles

    Directory of Open Access Journals (Sweden)

    P. F. Wang

    2012-01-01

    Full Text Available Owing to the unique order mesopores, mesoporous SBA-15 could be used as the carrier of the magnetic nanoparticles. The magnetic nanoparticles in the frame and the mesopores lead to the exchange-coupling interaction or other interactions, which could improve the magnetic properties of SBA-15 nanocomposites. Mesoporous Fe/SBA-15 had been prepared via in situ anchoring Fe2O3 into the frame and the micropores of SBA-15 using the sol-gel and hydrothermal processes. Co3O4 nanoparticles had been impregnated into the mesopores of Fe/SBA-15 to form mesoporous Fe/SBA-15-Co3O4 nanocomposites. XRD, HRTEM, VSM, and N2 physisorption isotherms were used to characterize the mesostructure and magnetic properties of the SBA-15 nanocomposites, and all results indicated that the Fe2O3 nanoparticles presented into the frame and micropores, while the Co3O4 nanoparticles existed inside the mesopores of Fe/SBA-15. Furthermore, the magnetic properties of SBA-15 could be conveniently adjusted by the Fe2O3 and Co3O4 magnetic nanoparticles. Fe/SBA-15 exhibited ferromagnetic properties, while the impregnation of Co3O4 nanoparticles greatly improved the coercivity with a value of 1424.6 Oe, which was much higher than that of Fe/SBA-15.

  17. 7 CFR Appendix H to Subpart E of... - Suggested Format for the Opinion of the Lender's Legal Counsel

    Science.gov (United States)

    2010-01-01

    ... 7 Agriculture 14 2010-01-01 2009-01-01 true Suggested Format for the Opinion of the Lender's Legal Counsel H Appendix H to Subpart E of Part 1980 Agriculture Regulations of the Department of Agriculture... Industrial Loan Program Pt. 1980, Subpt. E, App. H Appendix H to Subpart E of Part 1980—Suggested Format for...

  18. 12 CFR 221.119 - Applicability of plan-lender provisions to financing of stock options and stock purchase rights...

    Science.gov (United States)

    2010-01-01

    ... this area. (c) Section 221.4(a) provides that a plan-lender may include a wholly-owned subsidiary of the issuer of the collateral (taking as a whole, corporate groups including subsidiaries and... reasons, permitted the employing corporation to act through a subsidiary or other entity should not be...

  19. 7 CFR 1779.28 - Transfer of lenders or borrowers (prior to issuance of Loan Note Guarantee).

    Science.gov (United States)

    2010-01-01

    ... 7 Agriculture 12 2010-01-01 2010-01-01 false Transfer of lenders or borrowers (prior to issuance of Loan Note Guarantee). 1779.28 Section 1779.28 Agriculture Regulations of the Department of Agriculture (Continued) RURAL UTILITIES SERVICE, DEPARTMENT OF AGRICULTURE (CONTINUED) WATER AND WASTE...

  20. 12 CFR 617.7105 - When must a qualified lender disclose the effective interest rate to a borrower?

    Science.gov (United States)

    2010-01-01

    ... 12 Banks and Banking 6 2010-01-01 2010-01-01 false When must a qualified lender disclose the effective interest rate to a borrower? 617.7105 Section 617.7105 Banks and Banking FARM CREDIT... contract that specifically provides for future advances. ...

  1. Mesostructured SBA-15-Pr-SO3H: An efficient solid acid catalyst for ...

    Indian Academy of Sciences (India)

    of biological importance,20–23 we decided to utilize this catalyst in the .... effect of solvent on this four-component reaction, the .... Ultrasound. 12. 85. 201130. 4. SBA-Pr-SO3H. -. Heating (140. ◦. C). 40. 90. This study pyridone derivatives though the four-component reac- tion and in other reported methods, microwave irradi-.

  2. 13 CFR 101.200 - When does SBA hire private counsel?

    Science.gov (United States)

    2010-01-01

    ... private counsel to represent it in regard to business loans when the volume of activity in an area is not... 13 Business Credit and Assistance 1 2010-01-01 2010-01-01 false When does SBA hire private counsel? 101.200 Section 101.200 Business Credit and Assistance SMALL BUSINESS ADMINISTRATION ADMINISTRATION...

  3. 13 CFR 108.1710 - SBA authority to collect or compromise its claims.

    Science.gov (United States)

    2010-01-01

    ... 13 Business Credit and Assistance 1 2010-01-01 2010-01-01 false SBA authority to collect or compromise its claims. 108.1710 Section 108.1710 Business Credit and Assistance SMALL BUSINESS ADMINISTRATION... for such consideration as it deems reasonable, collect or compromise all claims relating to...

  4. 13 CFR 120.210 - What percentage of a loan may SBA guarantee?

    Science.gov (United States)

    2010-01-01

    ... 13 Business Credit and Assistance 1 2010-01-01 2010-01-01 false What percentage of a loan may SBA guarantee? 120.210 Section 120.210 Business Credit and Assistance SMALL BUSINESS ADMINISTRATION BUSINESS... percent, except as otherwise authorized by law. [61 FR 3235, Jan. 31, 1996, as amended at 68 FR 51680, Aug...

  5. Thermodynamics of CO2 adsorption on functionalized SBA-15 silica. NLDFT analysis of surface energetic heterogeneity

    Czech Academy of Sciences Publication Activity Database

    Zukal, Arnošt; Jagiello, J.; Mayerová, Jana; Čejka, Jiří

    2011-01-01

    Roč. 13, č. 34 (2011), s. 15468-15475 ISSN 1463-9076 R&D Projects: GA ČR GA203/08/0604 Institutional research plan: CEZ:AV0Z40400503 Keywords : thermodynamics * CO2 adsorption * SBA-15 silica Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 3.573, year: 2011

  6. Mesostructured SBA-15-Pr-SO 3 H: An efficient solid acid catalyst for ...

    Indian Academy of Sciences (India)

    ... a one-pot four-component reaction of benzaldehyde derivatives, Meldrum's acid, methyl acetoacetate and ammonium acetate in the presence of sulphonic acid-functionalized ordered nanoporous SBA-15 as a nano heterogeneous catalyst under solvent-free conditions. This process is a simple, environmentally friendly, ...

  7. SBA-15-Pr–SO3H: An efficient, environment friendly and recyclable ...

    Indian Academy of Sciences (India)

    s12039-014-0762-1. SBA-15-Pr–SO3H: An efficient, environment friendly and recyclable heterogeneous nanoreactor catalyst for the one-pot multicomponent synthesis of β-acetamido ketones. KIUMARS BAHRAMIa,b,∗, MOHAMMAD M KHODAEIa ...

  8. 13 CFR 106.300 - Fee Based SBA-Sponsored Activity.

    Science.gov (United States)

    2010-01-01

    ...-Sponsored Activities pursuant to section 4(h) of the Small Business Act. ... 13 Business Credit and Assistance 1 2010-01-01 2010-01-01 false Fee Based SBA-Sponsored Activity. 106.300 Section 106.300 Business Credit and Assistance SMALL BUSINESS ADMINISTRATION COSPONSORSHIPS...

  9. 13 CFR 108.510 - SBA approval of NMVC Company's Investment Adviser/Manager.

    Science.gov (United States)

    2010-01-01

    ... ADMINISTRATION NEW MARKETS VENTURE CAPITAL (âNMVCâ) PROGRAM Managing the Operations of a NMVC Company Management..., managing members, or general partner. If you have Leverage or plan to seek Leverage, you must obtain SBA's... Expenses. (b) Material change to approved management contract. If there is a material change, both you and...

  10. Thermogravimetric Analysis (TGA) Profile of Modified Sba-15 at Different Amount of Alkoxy silane Group

    International Nuclear Information System (INIS)

    Norhasyimi Rahmat; Nur Fathilah Mohd Yusof; Ezani Hafiza

    2014-01-01

    This study focused on meso porous silica SBA-15 modified with alkoxy silane functional group; phenyltriethoxysilane (PTES) and vinyltriethoxysilane (VTES) using direct synthesis and post-grafting methods. By direct synthesis method, SBA-15 template by triblock copolymer (P123) and functionalized with alkoxy silane groups at different amount of loadings were co-condensed with tetraethyl orthosilicate (TEOS) under acidic conditions. As for post-grafting method, different loadings of alkoxy silane groups were added after co-condensation of TEOS with P123 template. Both synthesis methods used calcination process to remove surfactant template at 550 degree Celsius for 5 hours. The derivatized SBA-15 was characterized by thermogravimetric analysis to evaluate the profile at different loadings of alkoxy silane groups with different synthesis method. At temperature range of 300-800 degree Celsius, post-grafting method displayed the highest weight loss of phenyl and vinyl groups. However, there was no significant difference of weight loss for different amount of organo silane groups. In this study, TGA has shown to be significant characterization means to determine the effects of different method used in synthesizing modified SBA-15. It was shown that different loading of phenyl and vinyl groups did not affect the efficiency of surfactant removal. (author)

  11. Thermal detemplation of SBA-15 mesophases. Effect of the activation protocol on the framework contraction

    NARCIS (Netherlands)

    Zhang, Zheng; Yin, Jie; Heeres, Hero Jan; Melian-Cabrera, Ignacio

    The potential use of the solvothermal extraction (SE) as a preliminary step to calcination for detemplating SBA-15 mesophases is investigated; aiming to reduce the amount of organics to be burnt and thereby the corresponding structural shrinkage. A systematic study was carried out by soxhlet

  12. Single-site SBA-15 supported zirconium catalysts. Synthesis, characterization and toward cyanosilylation reaction

    Science.gov (United States)

    Xu, Wei; Yu, Bo; Zhang, Ying; Chen, Xi; Zhang, Guofang; Gao, Ziwei

    2015-01-01

    A successive anchoring of Zr(NMe2)4, cyclopentadiene and a O-donor ligand, 1-hydroxyethylbenzene (PEA), 1,1‧-bi-2-naphthol (Binol) or 2,3-dihydroxybutanedioic acid diethyl ester (Tartrate), on dehydroxylated SBA-15 pretreated at 500 °C for 16 h (SBA-15-500) was conducted by SOMC strategy in moderate conditions. The dehydoxylation of SBA-15 was monitored by in situ Fourier transform infrared spectroscopy (in situ FT-IR). The ligand-modified SBA-15-500 supported zirconium complexes were characterized by in situ FT-IR, 13C CP MAS-NMR, X-ray photoelectron spectroscopy (XPS), inductively coupled plasma mass spectrometry (ICP-MAS) and elemental analysis in detail, verifying that the surface zirconium species are single-sited. The catalytic activity of these complexes was evaluated by cyanosilylation of benzaldehyde. The results showed that the catalytic activity is dependent strongly on the structure of surface species and the configuration of the ligands.

  13. 13 CFR 107.510 - SBA approval of Licensee's Investment Adviser/Manager.

    Science.gov (United States)

    2010-01-01

    ... 13 Business Credit and Assistance 1 2010-01-01 2010-01-01 false SBA approval of Licensee's Investment Adviser/Manager. 107.510 Section 107.510 Business Credit and Assistance SMALL BUSINESS ADMINISTRATION SMALL BUSINESS INVESTMENT COMPANIES Managing the Operations of a Licensee Management and...

  14. New method for quantification of dye sorption using SBA mesoporous silica as a target sorbent.

    Science.gov (United States)

    Nesic, Aleksandra R; Kokunesoski, Maja J; Volkov-Husovic, Tatjana D; Velickovic, Sava J

    2016-03-01

    In this work, a new method for the quantification of methyl violet cationic dye sorption onto SBA-15 mesoporous silica was developed. This method related the intensity of coloration of SBA-15 samples (after reached equilibrium sorption) within dye concentration in aqueous solution using Image-Pro Plus software. The sorption process of methyl violet dye onto SBA-15 was analyzed varying different initial parameters (dye concentration, mass of sorbent, pH of dye solution, and contact sorption time). SBA-15 proved as efficient sorbent for removal of methyl violet dye in contact time of 5 min, with maximum percentage of dye removal 99% at pH 8. The results obtained from Image-Pro Plus showed to be in good agreement with the sorption parameters obtained by UV/Vis spectroscopy, which has been the most commonly used instrument for quantification of dye sorption. The image analysis method proved well prediction of dye concentrations with maximum relative error of 1.83%. The advantages of this method are low cost and reliable quantitative evaluation with minimum of time.

  15. 13 CFR 107.630 - Requirement for Licensees to file financial statements with SBA (Form 468).

    Science.gov (United States)

    2010-01-01

    ... Accounting Standards and Financial Reporting Requirements for Small Business Investment Companies. (d) Where... financial statements with SBA (Form 468). 107.630 Section 107.630 Business Credit and Assistance SMALL BUSINESS ADMINISTRATION SMALL BUSINESS INVESTMENT COMPANIES Recordkeeping, Reporting, and Examination...

  16. 32 CFR 644.508 - Agreement with Small Business Administration (SBA) on sale of timber.

    Science.gov (United States)

    2010-07-01

    ... 32 National Defense 4 2010-07-01 2010-07-01 true Agreement with Small Business Administration (SBA) on sale of timber. 644.508 Section 644.508 National Defense Department of Defense (Continued) DEPARTMENT OF THE ARMY (CONTINUED) REAL PROPERTY REAL ESTATE HANDBOOK Disposal Disposal of Standing Timber, Crops, and Embedded Gravel, Sand and Stone §...

  17. 13 CFR 107.470 - SBA approval of merger, consolidation, or reorganization of Licensee.

    Science.gov (United States)

    2010-01-01

    ... 13 Business Credit and Assistance 1 2010-01-01 2010-01-01 false SBA approval of merger, consolidation, or reorganization of Licensee. 107.470 Section 107.470 Business Credit and Assistance SMALL..., consolidation, or reorganization of Licensee. (a) Prior approval requirements. You may not merge, consolidate...

  18. The Promotion of Critical Thinking Skills in School-Based Assessment (SBA)

    Science.gov (United States)

    Kamarulzaman, Wirawani; Kamarulzaman, Wirawahida

    2016-01-01

    The new curriculum introduced in the Malaysian primary students; the Primary School Standard Curriculum (Kurikulum Standard Sekolah Rendah-KSSR) together with the school-based assessment (SBA) is a step taken by the Malaysian government to encourage thinking skills to students, specifically critical thinking skills. The study explores teachers'…

  19. Effect of amine functionalization of spherical MCM-41 and SBA-15 on controlled drug release

    International Nuclear Information System (INIS)

    Szegedi, A.; Popova, M.; Goshev, I.; Mihaly, J.

    2011-01-01

    MCM-41 and SBA-15 silica materials with spherical morphology and different particle sizes were synthesized and modified by post-synthesis method with 3-aminopropyltriethoxysilane (APTES). A comparative study of the adsorption and release of a model drug, ibuprofen, were carried out. The modified and drug loaded mesoporous materials were characterized by XRD, TEM, N 2 physisorption, thermal analysis, elemental analysis and FT-IR spectroscopy. Surface modification with amino groups resulted in high degree of ibuprofen loading and slow rate of release for MCM-41, whereas it was the opposite for SBA-15. The adsorbed drug content and the delivery rate can be predetermined by the choice of mesoporous material with the appropriate structural characteristics and surface functionality. -- Graphical Abstract: Ibuprofen delivery from the parent and amino-modified spherical MCM-41 materials with 100 nm (small) and 500 nm (large) particle sizes. Display Omitted Highlights: → Spherical type MCM-41 and SBA-15 with different particle sizes were modified by APTES. → Adsorption and release rate of ibuprofen were compared. → High degree of ibuprofen loading, slow release rate for MCM-41, the opposite for SBA-15. → MCM-41 with 100 nm particles was more stable and showed slower release rate

  20. Performance pay, sorting and social motivation

    OpenAIRE

    Eriksson, Tor; Villeval, Marie Claire

    2008-01-01

    International audience; Variable pay links pay and performance but may also help firms in attracting more productive employees. Our experiment investigates the impact of performance pay on both incentives and sorting and analyzes the influence of repeated interactions between firms and employees on these effects. We show that (i) the opportunity to switch from a fixed wage to variable pay scheme increases the average effort level and its variance; (ii) high skill employees concentrate under t...

  1. The International Instruments on Gender Pay Equity

    OpenAIRE

    Chen, Cher Weixia

    2008-01-01

    Today in the world women are earning around 78% of what men are earning. Gender pay gap ironically is still one major feature of the modern labor market, despite the fact that the right to equal pay is one of the founding principles recognized by the 1945 ILO constitution amendment. Since 1919 the right to equal pay was discussed during the preparation for the ILO constitution, scholars have been constantly making efforts to explore the potential solutions to gender pay differentials...

  2. Anchoring Tri(8-QuinolinolatoIron Onto Sba-15 for Partial Oxidation of Benzyl Alcohol Using Water as the Solvent

    Directory of Open Access Journals (Sweden)

    Yang Xiaoyuan

    2014-09-01

    Full Text Available Tri(8-quinolinolatoiron complex immobilized onto SBA-15 catalyst has been synthesized through a stepwise procedure. The characterization results indicated that the BET surface area, total pore volume and average pore width decrease after stepwise modification of SBA-15, while the structure keeps intact. Catalytic tests showed that FeQ3-SBA-15 catalyzes the oxidation reaction well with 34.8% conversion of benzyl alcohol and 74.7% selectivity to benzaldehyde when water is used as the solvent after 1 h reaction. In addition, homogeneous catalyst tri(8-quinolinolatoiron exhibits very bad catalytic behavior using water as the solvent.

  3. 28 CFR 551.108 - Performance pay.

    Science.gov (United States)

    2010-07-01

    ... 28 Judicial Administration 2 2010-07-01 2010-07-01 false Performance pay. 551.108 Section 551.108 Judicial Administration BUREAU OF PRISONS, DEPARTMENT OF JUSTICE INSTITUTIONAL MANAGEMENT MISCELLANEOUS Pretrial Inmates § 551.108 Performance pay. The Warden may approve a pretrial inmate for performance pay...

  4. 75 FR 18133 - Pay for Sunday Work

    Science.gov (United States)

    2010-04-09

    ... rate equal to 25 percent of his or her rate of basic pay for each hour of Sunday work (as defined in...-AM08 Pay for Sunday Work AGENCY: Office of Personnel Management. ACTION: Proposed rule. SUMMARY: The U... provisions of 5 U.S.C. 5546(a), the statute governing the payment of Sunday premium pay for work performed on...

  5. Equal Pay for Work of Comparable Value.

    Science.gov (United States)

    Mutari, Ellen; And Others

    1982-01-01

    Discusses occupational segregation and other barriers to equal job opportunities for women and examines two approaches toward correcting pay inequities: equal pay for equal work and equal pay for work of comparable value. Legal cases, job evaluation studies, and other steps toward comparable worth are described. A 64-item reference list is…

  6. Social Comparison of Pay and Inequity Theory.

    Science.gov (United States)

    Judd, Ben

    Inequity theory differs from social exchange theory in its analysis of a worker's reaction to pay by asserting that effects on work performance caused by high or low pay are due to social comparison of fairness rather than principles of direct exchange, such as reciprocity and power. The present experiment held piece-rate pay constant at two…

  7. TARGET2 Imbalances and the ECB as Lender of Last Resort

    Directory of Open Access Journals (Sweden)

    Francesco Purificato

    2015-10-01

    Full Text Available This paper analyses the issue of the dynamics of the TARGET2 system balances during the sovereign debt crisis, when some countries registered a decisive inflow of the central bank liquidity and others showed an outflow. The dynamics in the TARGET2 are here explained as being due to a fall in the level of confidence in the capacity of the Economic and Monetary Union to survive, rather than to disparities in the level of competitiveness among countries of the Eurozone. This crisis of confidence has to be considered as the consequence of the implicit refusal of the European institutions to create a mechanism working as lender of last resort for the euro area member States; indeed, only when the ECB took this responsibility by launching the Outright Monetary Transactions clear signs of improvement were observed in the sovereign debt crisis.

  8. 13 CFR 108.1630 - SBA regulation of Brokers and Dealers and disclosure to purchasers of Leverage or Trust...

    Science.gov (United States)

    2010-01-01

    ... Financial Assistance for NMVC Companies (Leverage) Funding Leverage by Use of Sba Guaranteed Trust... standing in respect to compliance with the financial, ethical, and reporting requirements of such body...

  9. Anatase TiO{sub 2} nanocrystals anchored at inside of SBA-15 mesopores and their optical behavior

    Energy Technology Data Exchange (ETDEWEB)

    Araújo, M.M. [PPGQ-GERATEC-CCN-DQ, Universidade Estadual do Piauí, João Cabral, N. 2231, P.O. Box 381, 64002-150 Teresina, PI (Brazil); Departamento de Química (DQ), Universidade Federal do Piauí-UFPI, 64049-550 Teresina, PI (Brazil); Silva, L.K.R. [PPGQ-GERATEC-CCN-DQ, Universidade Estadual do Piauí, João Cabral, N. 2231, P.O. Box 381, 64002-150 Teresina, PI (Brazil); Sczancoski, J.C.; Orlandi, M.O.; Longo, E. [CDMF-Universidade Estadual Paulista, P.O. Box 355, 14801-907, Araraquara, SP (Brazil); Santos, A.G.D. [Departamento de Ciências Naturais, Universidade Estadual do Rio Grande do Norte, Mossoró, RN (Brazil); Sá, J.L.S.; Santos, R.S.; Luz, G.E. [PPGQ-GERATEC-CCN-DQ, Universidade Estadual do Piauí, João Cabral, N. 2231, P.O. Box 381, 64002-150 Teresina, PI (Brazil); Cavalcante, L.S., E-mail: laeciosc@gmail.com [PPGQ-GERATEC-CCN-DQ, Universidade Estadual do Piauí, João Cabral, N. 2231, P.O. Box 381, 64002-150 Teresina, PI (Brazil)

    2016-12-15

    Highlights: • New synthesis method to obtention of TiO{sub 2}/SBA-15 mesoporous. • Textural properties of TiO{sub 2}/SBA-15 mesoporous. • Optical band gap model to TiO{sub 2}/SBA-15 mesoporous. - Abstract: In this paper, a new synthesis method was proposed to obtain anatase titanium oxide (TiO{sub 2}) nanocrystals anchored into SBA-15 molecular sieve, as a matrix assigned by the in-situ anchoring (ISA) method. Pure SBA-15 and modified with TiO{sub 2} nanocrystals at different Si/Ti molar ratios (R = 75, 50, and 25) were structurally characterized by X-ray diffraction (XRD), Micro-Raman and Fourier Transform infrared (FTIR) spectroscopies. Specific surface area, pore volume and average pore diameter were estimated using both Brunauer-Emmett-Teller (BET) and Barrett-Joyner-Halenda (BJH) methods, respectively. Morphological aspects of these samples were observed by means of field emission scanning electron microscopy (FE-SEM) and transmission electron microscopy (TEM). Optical properties were investigated by ultraviolet-visible (UV-vis) diffuse reflectance spectroscopy. XRD patterns, Micro-Raman and FT-IR spectra indicate the TiO{sub 2} nanocrystals crystallized in a tetragonal structure anchored into the SBA-15 mesopores. BET and BJH methods prove a large amount of TiO{sub 2} nanocrystals were anchored inside of SBA-15 mesopores due to increase in surface area and average pore size of SBA-15 matrix. FE-SEM and TEM images showed the pure SBA-15 has an elongated hexagon-shaped microstructure, and an average size of 7.34 nm for 2D hexagonal mesopores. Moreover, ISA method was able to avoid blocking of mesopores, in addition promotes a significant increasing the impregnation rate of anatase TiO{sub 2} nanocrystals in SBA-15 matrix. A growth mechanism was proposed in order to explain the stages involved in the formation of TiO{sub 2}-SBA mesoporous. UV–vis spectra revealed a dependence of the optical band gap energy (E{sub gap}) with the decreasing of Si/Ti molar

  10. Fraud prevention in paying portal

    Science.gov (United States)

    Sandhu, P. S.; Senthilkumar, N. C.

    2017-11-01

    The purpose of presenting this paper is to give the idea to prevent the fraud in finance paying portals as fraud is increasing on daily basis and mostly in financial sector. So through this paper we are trying to prevent the fraud. This paper will give you the working algorithm through which you can able to prevent the fraud. Algorithm will work according to the spending amount of the user, which means that use will get categories into one of the low, medium, high or very high category.

  11. Paying your marketers--properly.

    Science.gov (United States)

    Pearson, Elizabeth Zink

    2003-09-01

    Home health agencies have more freedom to market their services since the implementation of the prospective payment system. In order to do that, a number of agencies have turned to marketing professionals for help. A common method of compensating marketers in the business world, however, is through payment for referrals--something expressly forbidden by federal statute. Home health agencies need to know what they can and can't do to pay marketers and must train their marketers on the federal anti-kickback regulations to assure their compliance.

  12. Dimerization of Ethylene to Butenes Over Ordered Mesoporous Silica SBA-15 Supported Ni-Al Catalysts with Different Morphologies.

    Science.gov (United States)

    Kim, Tae-Wan; Jun, Jong Won; Hong, Seok Il; Kim, Chul-Ung

    2018-03-01

    A series of ordered mesoporous silica (OMS) SBA-15 supports with different morphologies were prepared by different synthetic methods to investigate the effect of the characteristics of the morphology of OMS on the ethylene dimerization outcomes. After additions of Ni and Al species into the SBA-15 support, a dimerization reaction of ethylene was performed using a fixed-bed reactor. Rod-type Ni-Al-SBA-15 with a small micron size showed better catalytic performance compared to those of the other catalysts. From these catalytic results, the particle size and morphology of a SBA-15 support critically influenced the catalytic activities and lifetimes of the dimerization catalysts. The optimum reaction pathway in the Ni-Al-SBA-15 catalyst enhanced the overall catalytic performance due to the suppression of the further oligomerization of ethylene and butenes. Moreover, ethylene dimerization was investigated over the rod-type Ni-Al-SBA-15 catalyst to discover an optimum reaction condition. The maximum yield of butenes was 24.7% at 300 °C at 11.5 bar with a WHSV of 1.5 h-1.

  13. Nickel Particles Selectively Confined in the Mesoporous Channels of SBA-15 Yielding a Very Stable Catalyst for DRM Reaction.

    Science.gov (United States)

    Rodriguez-Gomez, Alberto; Pereñiguez, Rosa; Caballero, Alfonso

    2018-01-18

    A series of four Ni catalysts supported on SBA-15 and on a high SiO 2 surface area have been prepared by modified impregnation (ImU) and deposition-precipitation (DP) methods. The catalysts have been extensively characterized, including in situ XAS (bulk sensitive) and XPS (surface sensitive) techniques, and their catalytic activities evaluated in the dry reforming reaction of methane (DRM). The combined use of XPS and XAS has allowed us to determine the location of nickel particles on each catalyst after reduction at high temperature (750 °C). Both Ni/SiO 2 -DP and Ni/SBA-15-DP catalysts yield well-dispersed and homogeneous metallic phases mainly located in the mesoporosity of both supports. On the contrary, the Ni/SiO 2 -ImU and Ni/SBA-15-ImU catalysts present a bimodal distribution of the reduced nickel phase, with nickel metallic particles located out and into the mesoporous structure of SiO 2 or the SBA-15 channels. The Ni/SBA-15-DP catalyst was found the most stable and performing system, with a very low level of carbon deposition, about an order of magnitude lower than the equivalent ImU catalyst. This outstanding performance comes from the confinement of small and homogeneous nickel particles in the mesoporous channels of SBA-15, which, in strong interaction with the support, are resistant to sintering and coke deposition during the demanding reaction conditions of DRM.

  14. Functionalized SBA-15 supported nickel (II)–oxime–imine catalysts for liquid phase oxidation of olefins under solvent-free conditions

    International Nuclear Information System (INIS)

    Paul, Luna; Banerjee, Biplab; Bhaumik, Asim; Ali, Mahammad

    2016-01-01

    A new oxime–imine functionalized highly ordered mesoporous SBA-15 (SBA-15-NH 2 -DAMO) has been synthesized via post-synthesis functionalization of SBA-15 with 3-aminopropyl-triethoxysilane followed by the Schiff base condensation with diacetylmonooxime, which was further reacted with Ni(ClO 4 ) 2 to yield the functionalized nickel catalyst SBA-15-NH 2 -DAMO-Ni. All the synthesized materials were thoroughly characterized using different characterization techniques. It was found that SBA-15-NH 2 -DAMO-Ni catalyzes the one-pot oxidation of olefins like styrene, cyclohexene, cyclooctene, 1-hexene and 1-octene to the corresponding benzaldehyde, cyclohexene-1-ol and cyclooctene-oxide, respectively under solvent-free conditions by using tert-butylhydroperoxide as oxidant. - Graphical abstract: A new well characterized oxime–imine functionalized highly ordered mesoporous SBA-15-NH 2 -DAMO-Ni complex catalyzes the one-pot oxidation of olefins under solvent free mild conditions.

  15. Encapsulation of Coumarin 151 into the mesopores of modified rodlike SBA-15

    International Nuclear Information System (INIS)

    Guli, Mina; Li, Xiaotian; Chen, Yue; Ding, Hong; Li, Jixue; Qiu, Shilun

    2010-01-01

    Dye Coumarin 151 was postgrafted into the rodlike SBA-15 mesoporous materials, which were synthesized by a direct hydrothermal synthesis method and further modified by an organic silane with a terminal amino group. Characterization by powder X-ray diffraction, N 2 adsorption-desorption, transmission electron microscopy, photoluminescence and scanning electron microscopy were carried out. Small-angle X-ray diffraction and N 2 adsorption-desorption characterizations showed that these dye containing materials remained as ordered mesostructures and the pore size was from 6 nm for blank sample to 3.6 nm for postgrafting sample. PL characterization of composite samples exhibited optical properties with different dye concentrations. The characterization showed the existence of Coumarin 151 in the channels of SBA-15 and the composite materials with novel optical properties enabled possible applications in optical sensing and electron acceptors.

  16. Selective Preparation of trans-Carveol over Ceria Supported Mesoporous Materials MCM-41 and SBA-15

    Directory of Open Access Journals (Sweden)

    Nariman F. Salakhutdinov

    2013-05-01

    Full Text Available Ce-modified mesoporous silica materials MCM-41 and SBA-15, namely 32 wt % Ce–Si–MCM-41, 16 wt % Ce–H–MCM-41 and 20 wt % Ce–Si–SBA-15, were prepared, characterized and studied in the selective preparation of trans-carveol by α-pinene oxide isomerization. The characterizations of these catalysts were performed using scanning electron microscopy, X-ray photoelectron spectroscopy, nitrogen adsorption and FTIR pyridine adsorption. Selective preparation of trans-carveol was carried out in the liquid phase in a batch reactor. The activity and the selectivity of catalyst were observed to be influenced by their acidity, basicity and morphology of the mesoporous materials. The formation of trans-carveol is moreover strongly influenced by the basicity of the used solvent and in order to achieve high yields of this desired alcohol it is necessary to use polar basic solvent.

  17. or Ni-promoted MoS2/SBA-15 catalysts

    Indian Academy of Sciences (India)

    onboard fuel cells requires sulphur levels to be brought down to 0.1 ppm. Hydrotreating is a well-known unit operation in a petroleum refinery to reduce sulphur le- ... review.7 Klimova et al.8 and their group reported the highly active SBA-15 supported NiMo and CoMo cata- lysts and the role of citric acid.9,10 Various ...

  18. STATISTICAL ANALYSIS OF PUBLIC ADMINISTRATION PAY

    Directory of Open Access Journals (Sweden)

    Elena I. Dobrolyubova

    2014-01-01

    Full Text Available This article reviews the progress achieved inimproving the pay system in public administration and outlines the key issues to be resolved.The cross-country comparisons presented inthe article suggest high differentiation in pay levels depending on position held. In fact,this differentiation in Russia exceeds one in OECD almost twofold The analysis of theinternal pay structure demonstrates that thelow share of the base pay leads to perversenature of ‘stimulation elements’ of the paysystem which in fact appear to be used mostlyfor compensation purposes. The analysis of regional statistical data demonstrates thatdespite high differentiation among regionsin terms of their revenue potential, averagepublic official pay is strongly correlated withthe average regional pay.

  19. 25 CFR 103.38 - Is there anything else for BIA or the lender to do after BIA makes payment?

    Science.gov (United States)

    2010-04-01

    ... 25 Indians 1 2010-04-01 2010-04-01 false Is there anything else for BIA or the lender to do after BIA makes payment? 103.38 Section 103.38 Indians BUREAU OF INDIAN AFFAIRS, DEPARTMENT OF THE INTERIOR FINANCIAL ACTIVITIES LOAN GUARANTY, INSURANCE, AND INTEREST SUBSIDY Default and Payment by BIA § 103.38 Is there anything else for BIA or the lende...

  20. Efficient low-temperature soot combustion by bimetallic Ag-Cu/SBA-15 catalysts.

    Science.gov (United States)

    Wen, Zhaojun; Duan, Xinping; Hu, Menglin; Cao, Yanning; Ye, Linmin; Jiang, Lilong; Yuan, Youzhu

    2018-02-01

    In this study, the effects of copper (Cu) additive on the catalytic performance of Ag/SBA-15 in complete soot combustion were investigated. The soot combustion performance of bimetallic Ag-Cu/SBA-15 catalysts was higher than that of monometallic Ag and Cu catalysts. The optimum catalytic performance was acquired with the 5Ag 1 -Cu 0.1 /SBA-15 catalyst, on which the soot combustion starts at T ig =225°C with a T 50 =285°C. The temperature for 50% of soot combustion was lower than that of conventional Ag-based catalysts to more than 50°C (Aneggi et al., 2009). Physicochemical characterizations of the catalysts indicated that addition of Cu into Ag could form smaller bimetallic Ag-Cu nanolloy particles, downsizing the mean particle size from 3.7nm in monometallic catalyst to 2.6nm in bimetallic Ag-Cu catalyst. Further experiments revealed that Ag and Cu species elicited synergistic effects, subsequently increasing the content of surface active oxygen species. As a result, the structure modifications of Ag by the addition of Cu strongly intensified the catalytic performance. Copyright © 2017. Published by Elsevier B.V.

  1. Synthesis of Pt-Sn core-shell nanoparticles deposited on SBA-15 modified

    Energy Technology Data Exchange (ETDEWEB)

    Alvarez-Contreras, L.; Alonso-Lemus, I. [Centro de Investigacion en Materiales Avanzados S.C., Laboratorio Nacional de Nanotecnologia (Mexico); Botte, G. G. [Ohio University, Center for Electrochemical Engineering Research, Department of Chemical and Biomolecular Engineering (United States); Verde-Gomez, Y., E-mail: ysmaelverde@yahoo.com [Instituto Tecnologico de Cancun (Mexico)

    2013-07-15

    A novel one-step synthesis method to prepare Pt-Sn bimetallic nanoparticles supported on mesoporous silica with high surface area (SBA-15, 700 m{sup 2}/g) and narrow pore size distribution (around 9.5 nm) was developed. Tin incorporation plays an important dual role, to create active sites into the silica walls that serve as particles anchors center, and to grow Pt-Sn core-shell nanoparticles. High-resolution transmission and scanning electron microscopy, and X-ray diffraction pattern confirm the formation of the Pt-Sn core-shell type nanoparticles ( Almost-Equal-To 1-10 nm). The metal loading was 2.2 and 2.3 wt% for Pt and Sn, respectively. Electron microscopy results show that the metal nanoparticles were deposited not only on the matrix, but also inside of it. Structural, textural, and morphological features of the SBA-15 were slightly affected after the nanoparticles deposition, maintaining its high surface area. The results obtained suggest that Pt-Sn on SBA-15 could be attractive material for several catalytic applications, due to the narrow particle size distribution achieved (from 1 to 10 nm) the high dispersion on the support, as well as the Pt-Sn alloy developed.Graphical Abstract.

  2. Thermoresponsive copolymer-grafted SBA-15 porous silica particles for temperature-triggered topical delivery systems

    Directory of Open Access Journals (Sweden)

    S. A. Jadhav

    2017-02-01

    Full Text Available A series of poly(N-isopropylacrylamide-co-acrylamide thermoresponsive random copolymers with different molecular weights and composition were synthesized and characterized by attenuated total reflectance Fourier-transform infrared (ATR-FTIR, differential scanning calorimetry (DSC, size exclusion chromatography (SEC and proton nuclear magnetic resonance (NMR spectroscopy. The lower critical solution temperatures (LCST of the copolymers were tuned by changing the mole ratios of monomers. Copolymer with highest molecular weight and LCST (41.2 °C was grafted on SBA-15 type mesoporous silica particles by a two-step polymer grafting procedure. Bare SBA-15 and the thermoresponsive copolymergrafted (hybrid SBA-15 particles were fully characterized by scanning electron microscope (SEM, ATR-FTIR, thermogravimetric analysis (TGA and Brunauer-Emmett-Teller (BET analyses. The hybrid particles were tested for their efficiency as temperature-sensitive systems for dermal delivery of the antioxidant rutin (quercetin-3-O-rutinoside. Improved control over rutin release by hybrid particles was obtained which makes them attractive hybrid materials for drug delivery.

  3. Enhanced nitrogen removal from pharmaceutical wastewater using SBA-ANAMMOX process.

    Science.gov (United States)

    Tang, Chong-Jian; Zheng, Ping; Chen, Ting-Ting; Zhang, Ji-Qiang; Mahmood, Qaisar; Ding, Shuang; Chen, Xiao-Guang; Chen, Jian-Wei; Wu, Da-Tian

    2011-01-01

    Efficient biological nitrogen removal from pharmaceutical wastewater has been focused recently. The present study dealt with the treatment of colistin sulfate and kitasamycin manufacturing wastewater through anaerobic ammonium oxidation (ANAMMOX). The biotoxicity assay on luminescent bacterium Photobacterium phosphoreum (T3 mutation) showed that the pharmaceutical wastewater imparted severe toxicity with a relative luminosity of 3.46% ± 0.45%. During long-term operation, the cumulative toxicity from toxic pollutants in wastewater resulted in the performance collapse of conventional ANAMMOX process. A novel ANAMMOX process with sequential biocatalyst (ANAMMOX granules) addition (SBA-ANAMMOX process) was developed by combining high-rate ANAMMOX reactor with sequential biocatalyst addition (SBA). At biocatalyst addition rate of 0.025 g VSS (L wastewater)(-1) day(-1), the nitrogen removal rate of the process reached up to 9.4 kg N m(-3) day(-1) in pharmaceutical wastewater treatment. The effluent ammonium concentration was lower than 50 mg N L(-1), which met the Discharge Standard of Water Pollutants for Pharmaceutical Industry in China (GB 21903-2008). The application of SBA-ANAMMOX process in refractory ammonium-rich wastewater is promising. Copyright © 2010 Elsevier Ltd. All rights reserved.

  4. Effects of surface residual species in SBA-16 on encapsulated chiral (1S,2S)-DPEN-RuCl2(TPP)2 in asymmetric hydrogenation of acetophenone

    Science.gov (United States)

    Shi, Xiufeng; Xing, Bin; Fan, Binbin; Xue, Zhaoteng; Li, Ruifeng

    2016-03-01

    The SBA-16 obtained by different routes of elimination of organic templates were used as the hosts for encapsulation of chiral Ru complex (1S,2S)-DPEN-RuCl2(TPP)2 ( 1) (DPEN = 1,2-diphenylethylene-diamine, TPP = triphenyl phosphine). The methods for removing templates had distinct effects on the amount of residual template in SBA-16, which made the SBA-16 with different surface and structure properties. 1 encapsulated in SBA-16 extracted with the mixture of pyridine and ethanol showed higher activity and enantioselectivity for acetophenone asymmetric hydrogenation.

  5. Post-crisis Belarus: Marxism and the lender of last resort

    Directory of Open Access Journals (Sweden)

    Heather Bell

    2015-07-01

    Full Text Available Existing literature has examined the predictions and proscriptions of Karl Marx in response to the 2008 global financial crisis. However, the suggestions put forth by the Marxist-leaning literature never took hold and state-level banking and finance policies have remained largely unchanged. While many criticisms of Marxism exist, this paper examines Belarus, a ‘neo-communist’ or ‘market-socialist’ state, to provide a new perspective on the continuation of capitalism in the United States and Europe. In the case of Belarus, the International Monetary Fund and the Eurasian Economic Community's Anti-Crisis Fund provided both the critical liquidity needed to temporarily quell the effects of the financial crisis. Their demands meant that Belarus agreed to speed its move away from the Soviet-era finance and banking policies and more towards its western capitalist neighbors. Its failure to implement these policies further hurt its recovery. Examining Belarus' path to and out of its financial crisis makes apparent that the role of the international lender of last resort (LOLR. The LOLR acts as a key element in protecting states embroiled in the financial crisis from facing the possibility of making the difficult policy changes put forth by the Marxist literature. By ignoring its promises under the loan conditions from its LOLRs, Belarus moved further from the recovery promised by the Marxist suggestions.

  6. Explaining the Gender Wage Gap: Pay Expectations for Self, Others, and Perceptions of "Fair Pay."

    Science.gov (United States)

    Gardner, Philip D.; Jackson, Linda A.

    This study was conducted to investigate the pay expectations of graduating seniors, and specifically, the relationship between gender and pay expectations for one's self and others. The main purpose of the study was to determine if women and men differed in their initial pay expectations. Surveys were received from 447 college seniors, including…

  7. Large-scale energy consumers pay less

    International Nuclear Information System (INIS)

    Denneman, A.

    2012-01-01

    The price of electricity in the Netherlands rose with 6 percent in the first quarter of 2012, whereas large business consumers are paying less. The natural gas price has risen with about 10 percent in the last year, both for households and for large business consumers. Meanwhile, households are paying twice as much for electricity and gas as large business consumers. [nl

  8. Public Perceptions of the Pay Gap

    Science.gov (United States)

    Hill, Catherine; Silva, Elena

    2005-01-01

    Women have made gains toward closing the gender pay gap during the past two decades. Much of the progress occurred during the 1980s, with smaller gains in the 1990s (Institute for Women's Policy Research 2004). Women's achievements in higher education are partly responsible for narrowing the pay gap in the 1980s and 1990s. As more women earned…

  9. 20 CFR 218.28 - Sick pay.

    Science.gov (United States)

    2010-04-01

    ...' Benefits RAILROAD RETIREMENT BOARD REGULATIONS UNDER THE RAILROAD RETIREMENT ACT ANNUITY BEGINNING AND... Beginning Date § 218.28 Sick pay. (a) From railroad employer. If the employee is carried on the payroll while sick, the annuity can begin no earlier than the day after the last day of sick pay. However, sick...

  10. 76 FR 52537 - Pay for Sunday Work

    Science.gov (United States)

    2011-08-23

    ... OFFICE OF PERSONNEL MANAGEMENT 5 CFR Parts 532 and 550 RIN 3206-AM08 Pay for Sunday Work AGENCY: Office of Personnel Management. ACTION: Final rule. SUMMARY: The U.S. Office of Personnel Management is... earning Sunday premium pay because of the nature of their appointment. DATES: This rule is effective...

  11. Pay Dispersion and Performance in Teams

    DEFF Research Database (Denmark)

    Bucciol, Alessandro; Foss, Nicolai J; Piovesan, Marco

    2014-01-01

    contribute to the outcome, high pay dispersion has a detrimental impact on team performance. Enlarging the definition of the team causes this effect to disappear or even change direction. Finally, we find that the detrimental effect of pay dispersion is due to worse individual performance, rather than...

  12. Sex, Money and the Equal Pay Act

    Science.gov (United States)

    Feldman, Edwin B.

    1973-01-01

    Institutions who justify a wage differential between male and female custodians on the basis that women typically do the lighter work, and men the heavier, can find themselves in trouble. The Equal Pay Act of 1963 requires that men and women get the same pay for equal work -- and all custodial work is substantially equal to the Labor Department.…

  13. Willingness to Pay for Insurance in Denmark

    DEFF Research Database (Denmark)

    Hansen, Jan V.; Højbjerg Jacobsen, Rasmus; Lau, Morten I.

    . The results show that the willingness to pay is marginally higher than the actuarial fair value under Expected Utility Theory. However, the estimated willingness to pay is significantly higher under Rank-Dependent Utility Theory, and for some households it may be up to 600% higher than the actuarial value...

  14. Pay Dispersion and Performance in Teams

    Science.gov (United States)

    Bucciol, Alessandro; Foss, Nicolai J.; Piovesan, Marco

    2014-01-01

    Extant research offers conflicting predictions about the effect of pay dispersion on team performance. We collected a unique dataset from the Italian soccer league to study the effect of intra-firm pay dispersion on team performance, under different definitions of what constitutes a “team”. This peculiarity of our dataset can explain the conflicting evidence. Indeed, we also find positive, null, and negative effects of pay dispersion on team performance, using the same data but different definitions of team. Our results show that when the team is considered to consist of only the members who directly contribute to the outcome, high pay dispersion has a detrimental impact on team performance. Enlarging the definition of the team causes this effect to disappear or even change direction. Finally, we find that the detrimental effect of pay dispersion is due to worse individual performance, rather than a reduction of team cooperation. PMID:25397615

  15. Pay for performance: is it ethical?

    Science.gov (United States)

    Taub, Susan J

    2007-01-01

    Since the advent of pay for performance in medicine, there has been an intense debate about its efficacy and enforceability. This article examines some philosophical and psychological aspects of pay for performance. The very concept of pay for performance is inimical to the Hippocratic oath; it operates in direct conflict with powerful ideals such as altruism and concern for community. These ideals traditionally serve as powerful motivators for physicians. Physicians have just begun to incorporate and enhance the autonomy model. This is designed to help patients and physicians make decisions leading to positive outcomes. Pay for performance threatens to reintroduce an incurable power imbalance between patients and clinicians. Research from the corporate world suggests that hardwiring the thought processes of pay for performance into health-care delivery may lead to a culture of hyper-productivity. This can lead to addictive behavior and ethical abuse.

  16. Effect of Different Calcination Temperatures on the Structural and Photocatalytic Performance of Bi-TiO2/SBA-15

    Directory of Open Access Journals (Sweden)

    Jing Ma

    2013-01-01

    Full Text Available The new novel material Bi-TiO2/SBA-15 was synthesized by an easy wet impregnation method. A combination of XRD, XPS, Raman, N2 adsorption-desorption isotherm measurement, TEM, and solid state UV-Vis spectroscopy has been used to characterize the Bi-TiO2/SBA-15 material. It was found that SBA-15 retained the ordered hexagonal mesostructure after incorporation of TiO2 and Bi. The photodecomposition of rhodamine B (RhB in aqueous medium was selected to evaluate the photocatalytic performance of Bi-TiO2/SBA-15 under visible light irradiation (λ≥420 nm. The experiment results indicated that Bi-TiO2/SBA-15 exhibited higher photocatalytic activities than pure TiO2 and Bi2O3. The influences of calcination temperature were studied. It strongly influenced the activity of the samples. The sample calcined at 550°C shows the highest photocatalytic activity in the decomposition of RhB under visible light. The catalyst preserved almost its initial photocatalytic activity after six reuses.

  17. Microwave radiation hydrothermal synthesis and characterization of micro- and mesoporous composite molecular sieve Y/SBA-15

    Directory of Open Access Journals (Sweden)

    Wenyuan Wu

    2017-05-01

    Full Text Available A microwave radiation hydrothermal method to control synthesis of micro- and mesoporous Y/SBA-15 composite molecular sieves was reported. The synthesized SBA-15 and Y/SBA-15 were characterized by scanning electron microscopy (SEM and N2 adsorption–desorption. The three kinds of different concentrations of hydrochloric acid (0.75 M, 2 M and 3.25 M were used to investigate the effect on Y/SBA-15. The analysis results of the composite products indicated that the optimization synthesis condition employed zeolite type Y and TEOS as silicon sources under 0.75 M hydrochloric acid by the microwave radiation hydrothermal synthesis method. The N2 adsorption–desorption test results of micro–mesoporous composite molecular sieve type Y/SBA-15 in mesoporous extent indicated that SBET is 355.529 m2/g, D‾BET is 4.050 nm, and mesoporous aperture focuses on the distribution region of 5.3 nm. It was found that the received composite product has an appropriate proportion of smaller size, larger size pore structure and the thicker pore wall. In addition, its internal channels have a high degree of order and smooth flow in long-range channels.

  18. 5 CFR 9901.354 - Setting pay upon promotion.

    Science.gov (United States)

    2010-01-01

    ... 5 Administrative Personnel 3 2010-01-01 2010-01-01 false Setting pay upon promotion. 9901.354 Section 9901.354 Administrative Personnel DEPARTMENT OF DEFENSE HUMAN RESOURCES MANAGEMENT AND LABOR... SECURITY PERSONNEL SYSTEM (NSPS) Pay and Pay Administration Pay Administration § 9901.354 Setting pay upon...

  19. 5 CFR 9901.353 - Setting pay upon reassignment.

    Science.gov (United States)

    2010-01-01

    ... 5 Administrative Personnel 3 2010-01-01 2010-01-01 false Setting pay upon reassignment. 9901.353 Section 9901.353 Administrative Personnel DEPARTMENT OF DEFENSE HUMAN RESOURCES MANAGEMENT AND LABOR... SECURITY PERSONNEL SYSTEM (NSPS) Pay and Pay Administration Pay Administration § 9901.353 Setting pay upon...

  20. 5 CFR 9701.346 - Pay progression for new supervisors.

    Science.gov (United States)

    2010-01-01

    ... SECURITY HUMAN RESOURCES MANAGEMENT SYSTEM Pay and Pay Administration Performance-Based Pay § 9701.346 Pay....346 Section 9701.346 Administrative Personnel DEPARTMENT OF HOMELAND SECURITY HUMAN RESOURCES.../developmental program, as well as his or her performance. Pay Administration ...

  1. 5 CFR 9701.353 - Setting pay upon promotion.

    Science.gov (United States)

    2010-01-01

    ... HUMAN RESOURCES MANAGEMENT SYSTEM Pay and Pay Administration Pay Administration § 9701.353 Setting pay... 5 Administrative Personnel 3 2010-01-01 2010-01-01 false Setting pay upon promotion. 9701.353 Section 9701.353 Administrative Personnel DEPARTMENT OF HOMELAND SECURITY HUMAN RESOURCES MANAGEMENT...

  2. 5 CFR 9701.354 - Setting pay upon demotion.

    Science.gov (United States)

    2010-01-01

    ... HUMAN RESOURCES MANAGEMENT SYSTEM Pay and Pay Administration Pay Administration § 9701.354 Setting pay... 5 Administrative Personnel 3 2010-01-01 2010-01-01 false Setting pay upon demotion. 9701.354 Section 9701.354 Administrative Personnel DEPARTMENT OF HOMELAND SECURITY HUMAN RESOURCES MANAGEMENT...

  3. Preparation of mesoporous silica films SBA-15 over different substrates; Preparacao de filmes de silica mesoporosa SBA-15 sobre diferentes substratos

    Energy Technology Data Exchange (ETDEWEB)

    Campos, V.O.; Sousa, E.M.B. de; Macedo, W.A.A., E-mail: vitorcampos@ufmg.b [Centro de Desenvolvimento da Tecnologia Nuclear (CDTN/CNEN-MG), Belo Horizonte, MG (Brazil). Servico de Nanotecnologia

    2010-07-01

    Mesoporous materials have been target of frequent interest due to its wide application possibilities, for example development of gas sensors, catalysis, molecules transportation, pharmaceuticals release, synthesis of auto-organized nanostructures, among others. The possibilities of application are enhanced when such materials are disposed in the form of thin and ultrathin films. In this work the preparation of mesoporous SBA-15 silica films is explored by means of the dipcoating technique of a sol-gel on different substrates (glass slides, stainless steel, copper), using the surfactant poly(ethylene glycol)-block-poly(propylene glycol)- block-poly(ethylene glycol), known as P123, a block copolymer. Synthesis parameters surfactant concentration, aging time and temperature were investigated. In this work we present the morphological and structural characterization of the prepared films, which were obtained using atomic force microscopy and x-ray fluorescence and diffraction. (author)

  4. Physicochemical properties of poly(ethylene oxide)-based composite polymer electrolytes with a silane-modified mesoporous silica SBA-15

    Energy Technology Data Exchange (ETDEWEB)

    Shen Chen [Department of Chemistry, Zhejiang University, Hangzhou 310027 (China); Wang, Jianming [Department of Chemistry, Zhejiang University, Hangzhou 310027 (China)], E-mail: wjm@zju.edu.cn; Tang Zheng; Wang Huijuan; Lian Huiqin [Department of Chemistry, Zhejiang University, Hangzhou 310027 (China); Zhang Jianqing; Cao Chunan [Department of Chemistry, Zhejiang University, Hangzhou 310027 (China); State Key Laboratory for Corrosion and Protection of Metal, Institute of Metal Research, Chinese Academy of Sciences, 62 Wencui Road, Shenyang 110016 (China)

    2009-04-30

    Mesoporous silica SBA-15 was surface-modified by {gamma}-glycidoxypropyltrimethoxy silane (GPTMS), and novel poly(ethylene oxide) (PEO)-based composite polymer electrolytes (CPE) using the silane-modified SBA-15 (SBA-15-GPTMS) as filler were prepared and characterized. The results of the low-angle X-ray diffraction (XRD) patterns and Fourier-transform infrared (FT-IR) spectroscopy indicated that GPTMS has been successfully attached to the surface of SBA-15 with a high degree of mesoscopic hexagonal pore structure. The incorporation of SBA-15-GPTMS in the PEO-LiClO{sub 4} matrix effectively reduced the PEO crystallinity and obviously improved the conductivity and electrochemical stability of the CPEs. The CPE with 10 wt.% SBA-15-GPTMS provided the highest conductivity among all the tested CPEs, about 2-3 orders of magnitude higher than that of the PEO-LiClO{sub 4} matrix below the melting temperature of PEO. The reasons that the CPEs using SBA-15-GPTMS as filler showed higher conductivity than that with SBA-15 were discussed.

  5. HCI as a key parameter in size-tunable synthesis of SBA-15 silica with rodlike morphology.

    Science.gov (United States)

    Kang, Segoo; Chae, Young Bae; Yu, Jong-Sung

    2009-01-01

    Highly ordered mesoporous SBA-15 silica particles with rodlike morphologies were synthetically controlled for the first time by adjusting hydrochloric acid concentration in the range of 0.1-5.0 M in the presence of block copolymer template under static condition but with no addition of inorganic salts. This work illustrates that it is possible to achieve a facile, convenient, reproducible high yield synthesis of SBA-15 silica particles with rodlike morphology in a wide range of length scale (0.4-4.5 microm in length), and it is HCl that plays a key role in regulating the morphological architecture of the mesoporous particles. The acid revealed strong effects not only on mesostuctural properties, but also on macrostructural morphologies of the resulting SBA-15 particles in a wide range of acid concentration (1.0-3.0 M).

  6. Visible Light-Induced Metal Free Surface Initiated Atom Transfer Radical Polymerization of Methyl Methacrylate on SBA-15

    Directory of Open Access Journals (Sweden)

    Liang Ma

    2017-02-01

    Full Text Available Surface-initiated atom transfer radical polymerization (SI-ATRP is one of the most versatile techniques to modify the surface properties of materials. Recent developed metal-free SI-ATRP makes such techniques more widely applicable. Herein photo-induced metal-free SI-ATRP of methacrylates, such as methyl methacrylate, N-isopropanyl acrylamide, and N,N-dimethylaminoethyl methacrylate, on the surface of SBA-15 was reported to fabricate organic-inorganic hybrid materials. A SBA-15-based polymeric composite with an adjustable graft ratio was obtained. The structure evolution during the SI-ATRP modification of SBA-15 was monitored and verified by FT-IR, XPS, TGA, BET, and TEM. The obtained polymeric composite showed enhanced adsorption ability for the model compound toluene in aqueous conditions. This procedure provides a low-cost, readily available, and easy modification method to synthesize polymeric composites without the contamination of metal.

  7. Selective debenzylation of 1-benzyloxy-4-methoxy benzene over 5-sulfosalicylic acid-functionalized ordered mesoporous silica (SBA-15/SFSA) catalyst

    Science.gov (United States)

    Verma, Savita; Dubey, Amit

    2017-12-01

    5-Sulfosalicylic acid (SFSA) functionalized mesoporous silica nanocomposites (SBA/APTS/SFSA) were synthesized by post grafting technique for selective debenzylation of 1-benzyloxy-4-methoxy benzene. The uniform incorporation of SFSA inside the mesoporous SBA-15 framework was confirmed by standard characterization techniques (PXRD, adsorption studies, FT-IR, etc.). Total surface area, pore size and pore volume of the SBA/APTS/SFSA catalysts decreased with increase in the concentration of SFSA confirming the uniform insertion of SFSA into mesoporous SBA-15 matrix. Catalytic activity studies showed highest conversion and selectivity of the desired product on SBA/APTS/SFSA catalyst compared to homogeneous SFSA and other solid support (Al2O3 and SiO2). All the reaction parameters such as reaction time, reaction temperature and catalyst weight were optimized under environmental friendly conditions. Finally, the possible mechanism of the reaction was explained.

  8. Highly active and durable Ca-doped Ce-SBA-15 catalyst for biodiesel production

    International Nuclear Information System (INIS)

    Thitsartarn, Warintorn; Maneerung, Thawatchai; Kawi, Sibudjing

    2015-01-01

    In this work, Ca-doped Ce-incorporated SBA-15 (Ca/CeS) catalyst was successfully synthesized by using direct synthesis of Ce-incorporated SBA-15 followed by impregnation of CaO (calcium oxide). The maximum Si/Ce molar ratio that Ce atoms can be incorporated successfully into the mesoporous framework was found to be 5 (CeS-5). After the impregnation of 30 wt. % Ca, the obtained 30Ca/CeS-5 catalysts showed the superior catalytic performance for transesterification reaction of palm oil with methanol and also the higher catalytic activity as compared to other supported catalysts, i.e. CaO/CeO 2 and CaO–CeO 2 /SBA-15. This can be attributed to the well-dispersion of CaO on the CeS-5 support surface. Furthermore, it was found that the leaching of Si, Ce and Ca from the catalyst into biodiesel produced was negligible (i.e. <1 ppm after 7 cycles), indicating the strong interaction between CaO and CeS-5 support. As a result, the 30Ca/CeS-5 catalyst can be reused at least 15 cycles with insignificant decrease in catalytic activity, offering the efficient CaO-based catalyst for biodiesel production. - Highlights: • Mesoporous Ca-based catalyst was successfully developed for biodiesel production. • Catalyst exhibited high activity towards transesterification (FAME yield > 98%). • Catalyst can be effectively re-used at least 15 cycles. • Extremely low catalyst contaminant (<1 ppm) was presented

  9. Troubled by unequal pay rather than low pay: The incentive effects of a top management team pay gap

    Directory of Open Access Journals (Sweden)

    Yue Xu

    2016-06-01

    Full Text Available We examine the relationships with firm performance of the internal pay gap among individual members of the top management team (TMT and the compensation level of TMT members relative to their industry peers. We find that pay gap is positively related to firm performance and that this positive relation is stronger when the TMT pay level is higher than the industry median. However, we do not observe such effects in Chinese state-owned enterprises (SOEs, in which both the executive managerial market and compensation are government-regulated. We also document that cutting central SOE managers’ pay level can increase firm value, whereas doing so for local SOE managers has the opposite effect. Our findings have important implications for research on TMT compensation as well as for policy makers considering SOE compensation reform.

  10. Synthesis and characterization of nano structures of Silica SBA-16 containing Gadolinium-159 as potential nanoparticulated system for cancer therapy

    International Nuclear Information System (INIS)

    Oliveira, Andre Felipe de

    2013-01-01

    Cancer is a leading cause of death worldwide, and malignant neoplasms of the lung, stomach, liver, colon and breast in greater numbers. And recently observed in the literature a large number of reviews where new materials, especially nanoparticle, has been studied as drug carriers and radioisotopes applied to cancer treatment. How mesoporous materials based on silica, thanks to its huge surface area and biocompatibility, have been studied intensively providing broad applications in various areas, the use of nanostructured silica SBA-16 might be a carrier specific radioisotope accumulate in the cells malignant. Thus the aim of this study is to develop in vitro studies using SBA-16 can selectively concentrate in malignant cells therapeutic amounts of the radioisotope Gadolinium-159 escorting them to death. This work was performed orderly synthesis of mesoporous silica, SBA-16 and incorporating the complex Gd-DTPA-BMA, as well as chemical and structural characterization. The techniques used to analyze the occurrence of the incorporation of the gadolinium complex in the silica matrix were elemental analysis (CHN), atomic emission spectroscopy (ICP-AES), infrared spectroscopy (FTIR), nitrogen adsorption (BET), small-angle X-ray scattering (SAXS) and thermogravimetric analysis (TG). To analyze the morphology of pure silica used the scanning electron microscopy (SEM) and transmission electron microscopy (TEM). By photon correlation spectroscopy (PCS) it was possible to obtain a measure of mean particle size, the polydispersity index (PDI) of the silica SBA-16, and the zeta potential by laser Doppler anemometry (LDA). The results of incorporation analyzed by ICP-AES indicated that the material SBA-16 had a higher rate of incorporation of gadolinium (93%). The release kinetics in simulated body fluid, showed considerable stability and low release (1%). The mesoporous silica SBA-16 showed cell viability in direct contact with cell culture. Samples with gadolinium

  11. Preparation of Mesoporous SBA-16 Silica-Supported Biscinchona Alkaloid Ligand for the Asymmetric Dihydroxylation of Olefins

    Directory of Open Access Journals (Sweden)

    Shaheen M. Sarkar

    2014-01-01

    Full Text Available Optically active cinchona alkaloid was anchored onto mesoporous SBA-16 silica and the as-prepared complex was used as a heterogeneous chiral ligand of osmium tetraoxide for the asymmetric dihydroxylation of olefins. The prepared catalytic system provided 90–93% yield of vicinal diol with 92–99% enantioselectivity. The ordered mesoporous SBA-16 silica was found to be a valuable support for the cinchona alkaloid liganded osmium catalyst system which is frequently used in chemical industries and research laboratories for olefin functionalization.

  12. On the Effectiveness of Incentive Pay

    DEFF Research Database (Denmark)

    Friis, Ivar; Hansen, Allan; Vámosi, Tamás S.

    2015-01-01

    Extant research already emphasises that complementarities and substitution involving incentive pay and other elements of an organisation's management control system play an important role in terms of explaining the effectiveness of incentive systems. Despite this awareness calls continue for more...

  13. Farmers' willingness to pay for groundwater protection

    Science.gov (United States)

    Lichtenberg, Erik; Zimmerman, Rae

    1999-03-01

    The effectiveness of current groundwater protection policies depends largely on farmers' voluntary compliance with leaching reduction measures, an important component of which is their willingness to adopt costlier production practices in order to prevent leaching of chemicals. Data from an original survey of 1611 corn and soybean growers in the mid-Atlantic region were used to estimate farmers' willingness to pay to prevent leaching of pesticides into groundwater. The results indicate that farmers are willing to pay more for leaching prevention than nonfarm groundwater consumers, both absolutely and relative to total income. The primary motivation appears to be concern for overall environmental quality rather than protection of drinking water or the health and safety of themselves and their families. Hobby farmers are willing to pay more than farmers with commercial activity. Certified pesticide applicators are willing to pay less than farmers without certification.

  14. Clinical research: Should patients pay to play?

    Science.gov (United States)

    Emanuel, Ezekiel J; Joffe, Steven; Grady, Christine; Wendler, David; Persad, Govind

    2015-07-29

    Permitting patients to pay for participation in clinical research threatens the principles of social value and fair subject selection as well as robust clinical trial design. Copyright © 2015, American Association for the Advancement of Science.

  15. Income taxes and the composition of pay

    OpenAIRE

    Brunello, Giorgio; Comi, Simona; Sonedda, Daniela

    2006-01-01

    According to the standard principal-agent model, the optimal composition of pay should balance the provision of incentives with the individual demand for insurance. Do income taxes alter this balance? We show that the relative share of PRP on total pay is reduced by higher average taxes, and is affected in a complex way by higher marginal tax rates. Empirical evidence based on the British Household Panel Survey, which exploits the UK 1999 Tax Reform, supports the theoretical predictions of th...

  16. 75 FR 60588 - Immediate Disaster Assistance Program

    Science.gov (United States)

    2010-10-01

    ... provisions detail SBA's risk-based lender oversight program, including off-site reviews and monitoring, on... program. SBA will provide an 85 percent guarantee on IDAP loans made by participating lenders for up to... percent guarantee on loans made by participating lenders for up to $25,000. The intent of the IDAP loan...

  17. The role of lenders' trust in determining borrowing conditions for sovereign debt: An analysis of one-period government bonds with default risk

    OpenAIRE

    Guo, Yanling

    2015-01-01

    In this paper, the author considers the sovereign debt in the form of one-period government bonds with default risk, which can be purchased by and traded among domestic and foreign investors. She shows that the weight assigned to the lenders' interest by the borrowing government at the time of debt repayment, which captures the lenders' trust in the government's propensity to repay the debt and is denoted as », also determines the default risk: a higher » means a lower default risk ceteris pa...

  18. Motivational effects of pay dispersion in pay for performance programs implemented in Romanian companies

    OpenAIRE

    Urieşi Sebastian

    2016-01-01

    The present study investigates the motivational effects in a sample of Romanian employees in private companies that implement pay for performance programs of one of the characteristics of these programs, namely pay dispersion, and on the potential mediating role of organizational justice in these effects. To this aim, we examined the relationships between the amounts of pay dispersion introduced by the respective financial incentive system, employee perceptions of distributive and procedural ...

  19. Board Independence, Executive Pay Structures, and Pay Disclosure: Evidence from Europe

    OpenAIRE

    Muslu, Volkan

    2004-01-01

    Using a broad sample of the largest European companies, I examine whether the two governance mechanisms, namely (i) independent monitoring by a board of directors and (ii) grants and disclosures of incentive-based executive pay, are substitutes for one another. I find that companies with proportionately more executives on their boards of directors grant greater incentive-based pay to their executives, and improve the transparency of their pay disclosure. The findings are consistent with the e...

  20. Isocyanate-mediated covalent immobilization of Mucor miehei lipase onto SBA-15 for transesterification reaction.

    Science.gov (United States)

    Canilho, N; Jacoby, J; Pasc, A; Carteret, C; Dupire, F; Stébé, M J; Blin, J L

    2013-12-01

    Mucor miehei lipase (Mm-L) covalently bind on a hexagonally ordered silica SBA-15 (Santa Barbara Amorphous), previously functionalized with isocyanate moieties, was examined as biocatalyst for transesterification of colza oil with methanol. The isocyanate-mesoporous silica (NCO-SBA-15) was obtained by condensation of silanol with triethoxysilane propyl isocyanate (TPI). The efficiency of the functionalization has been evidenced by infrared, (29)Si and (13)C NMR spectroscopies. The substrate provided a moderate hydrophobic microenvironment together with reactive sites for chemical immobilization of the enzyme. The biocatalyst containing 0.28 g of Mm-L per gram of support afforded a high level of transesterification activity (yield up to 80%) while using 1:1 molar ratio of methanol/colza oil and small amount of water. The biocatalyst showed higher operational stability than the corresponding physisorbed enzyme since it can be reused 6 times against 2 consecutive runs for the physisorbed enzyme. © 2013 Elsevier B.V. All rights reserved.

  1. Synthesis and characterization of zero-valent iron nanoparticles supported on SBA-15

    Directory of Open Access Journals (Sweden)

    Felipe Sombra dos Santos

    2017-04-01

    Full Text Available This paper aims to synthesize zero-valent iron nanoparticles (nZVI supported on SBA-15 nanosilica. The nanosilica generate in the system by polymer reaction with hydrochloric acid under controlled temperature. After, the iron nanomaterial was obtained by sodium borohydride reduction as described in this work. Afterward the synthesis of the nanoparticles contained iron supported on silica SBA-15, the material was characterized by X-ray diffraction, transmission electron microscopy, scanning electron microscopy, zeta potential and X-ray fluorescence spectroscopy. The results indicated that nanomaterial obtained was in nanometric scale, by TEM results, and showing characteristic peaks at EDS results, with 11.9% iron and 14.0% silicon content, respectively, and containing 73.0% and 27.0% of their respective oxides through X-ray fluorescence spectroscopy. The isoelectric potential of the sample was around 2.0, close to the value reported for silica, due to the higher percentage of silica in the sample when compared to iron. The obtained material can be used, for some cases, as an possible alternative, to the Fenton reaction for the degradation of xenobiotic compounds or other applications in the groundwater and wastewater treatments.

  2. Template occluded SBA-15: An effective dissolution enhancer for poorly water-soluble drug

    International Nuclear Information System (INIS)

    Fu Tingming; Guo Liwei; Le Kang; Wang Tianyao; Lu Jin

    2010-01-01

    The aim of the present work was to improve the dissolution rate of piroxicam by inclusion into template occluded SBA-15. Our strategy involves directly introducing piroxicam into as-prepared SBA-15 occluded with P123 (EO 20 PO 70 EO 20 ) by self assembling method in acetonitrile/methylene chloride mixture solution. Ultraviolet spectrometry experiment and thermogravimetric analysis-differential scanning calorimetry (TG-DSC) profiles show that the piroxicam and P123 contents in the inclusion compound are 12 wt% and 28 wt%, respectively. X-ray powder diffraction and DSC analysis reveal that the included piroxicam is arranged in amorphous form. N 2 adsorption-desorption experiment indicates that the piroxicam has been introduced to the mesopores instead of precipitating at the outside of the silica material. The inclusion compound was submitted to in vitro dissolution tests, the results show that the piroxicam dissolve from template occluded inclusion compound more rapidly, than these from the piroxicam crystalline and template removed samples in all tested conditions. Thus a facile method to improve the dissolution rate of poorly water-soluble drug was established, and this discovery opens a new avenue for the utilization of templates used for the synthesis of mesoporous materials.

  3. Template occluded SBA-15: An effective dissolution enhancer for poorly water-soluble drug

    Energy Technology Data Exchange (ETDEWEB)

    Fu Tingming, E-mail: futingming@gmail.com [College of Pharmacy, Nanjing University of Chinese Medicine, Nanjing 210029 (China); Guo Liwei; Le Kang; Wang Tianyao; Lu Jin [College of Pharmacy, Nanjing University of Chinese Medicine, Nanjing 210029 (China)

    2010-09-15

    The aim of the present work was to improve the dissolution rate of piroxicam by inclusion into template occluded SBA-15. Our strategy involves directly introducing piroxicam into as-prepared SBA-15 occluded with P123 (EO{sub 20}PO{sub 70}EO{sub 20}) by self assembling method in acetonitrile/methylene chloride mixture solution. Ultraviolet spectrometry experiment and thermogravimetric analysis-differential scanning calorimetry (TG-DSC) profiles show that the piroxicam and P123 contents in the inclusion compound are 12 wt% and 28 wt%, respectively. X-ray powder diffraction and DSC analysis reveal that the included piroxicam is arranged in amorphous form. N{sub 2} adsorption-desorption experiment indicates that the piroxicam has been introduced to the mesopores instead of precipitating at the outside of the silica material. The inclusion compound was submitted to in vitro dissolution tests, the results show that the piroxicam dissolve from template occluded inclusion compound more rapidly, than these from the piroxicam crystalline and template removed samples in all tested conditions. Thus a facile method to improve the dissolution rate of poorly water-soluble drug was established, and this discovery opens a new avenue for the utilization of templates used for the synthesis of mesoporous materials.

  4. Iron Doped SBA-15 Mesoporous Silica Studied by Mössbauer Spectroscopy

    Directory of Open Access Journals (Sweden)

    Łukasz Laskowski

    2016-01-01

    Full Text Available Mesoporous silica SBA-15 containing propyl-iron-phosphonate groups were considered to confirm their molecular structure. To detect the iron-containing group configuration the Mössbauer spectroscopy was used. Both mesoporous silica SBA-15 containing propyl-iron-phosphonate groups and pure doping agent (iron acetylacetate were investigated using Mössbauer spectroscopy. The parameters such as isomer shift, quadrupole splitting, and asymmetry in 57Fe Mössbauer spectra were analyzed. The differences in Mössbauer spectra were explained assuming different local surroundings of Fe nuclei. On this base we were able to conclude about activation of phosphonate units by iron ions and determinate the oxidation state of the metal ion. To examine bonding between iron atoms and phosphonic units the resonance Raman spectroscopy was applied. The density functional theory (DFT approach was used to make adequate calculations. The distribution of active units inside silica matrix was estimated by comparison of calculated vibrational spectra with the experimental ones. Analysis of both Mössbauer and resonance Raman spectra seems to confirm the correctness of the synthesis procedure. Also EDX elemental analysis confirms our conclusions.

  5. Zr-SBA-15 Lewis Acid Catalyst: Activity in Meerwein Ponndorf Verley Reduction

    Directory of Open Access Journals (Sweden)

    Jose Iglesias

    2015-11-01

    Full Text Available Zr-SBA-15 Lewis acid catalyst has demonstrated an outstanding catalytic activity in the reduction of several carbonyl compounds by means of Meerwein Ponndorf Verley (MPV reaction, using several secondary alcohols, and showing a very high selectivity towards the desired products. Special focus was addressed in the catalytic activity of Zr-SBA-15 material in the production of furfuryl alcohol from furfural, which is an important reaction for the lignocellulosic biomass valorization. In this transformation, both the reaction temperature and the i-PrOH:Furfural molar ratio exert a positive influence on the rate of the MPV transformation, with the influence of the former being much higher. i-propyl-furfuryl ether, a by-product resulting from the etherification of the target product with the sacrificing alcohol, is also found together with the main product. The production of this side-product is highly influenced by the reaction temperature, so that low temperatures and high sacrificing alcohol to substrate molar ratios have to be applied to keep its production at low levels.

  6. 13 CFR 120.960 - Responsibility for closing.

    Science.gov (United States)

    2010-01-01

    ... places SBA at risk; (4) The CDC has failed to use required SBA forms or electronic versions of those forms; (5) The CDC, Third Party Lender or Borrower has failed to timely disclose to SBA a material fact regarding the Project or 504 loan; (6) The CDC, Third Party Lender or Borrower has misrepresented a material...

  7. 13 CFR 107.1810 - Events of default and SBA's remedies for Licensee's noncompliance with terms of Debentures.

    Science.gov (United States)

    2010-01-01

    ... avail itself of one or more of the remedies in paragraph (e) of this section. (1) Fraud. You commit a... the end of each fiscal year. In determining whether you have maintained the ratio, SBA will disregard... Capital, and any receipt of additional Leverage, within 120 days prior to the end of your fiscal year. (10...

  8. 75 FR 47859 - Availability of SBA Draft Strategic Plan for Fiscal Years 2011-2016 and Request for Public Comment

    Science.gov (United States)

    2010-08-09

    ... ADMINISTRATION Availability of SBA Draft Strategic Plan for Fiscal Years 2011- 2016 and Request for Public.... SUMMARY: This notice announces the availability of the Small Business Administration's draft Strategic.... Small Business Administration, Strategic Plan-Office of Performance Management, Office of the Chief...

  9. Catalytic Synthesis of n-Butyl Oleate by Cerium Complex Doped Y/SBA-15 Composite Molecular Sieve

    Science.gov (United States)

    Shi, Chunwei; Bian, Xue; Wu, Yongfu; Cong, Yufeng; Pei, Mingyuan

    2018-01-01

    Cerium ion was successfully incorporated into Y/SBA-15 micro-mesoporous molecular sieves via the hydrothermal synthesis method to give a series of composite materials. The prepared materials were thoroughly characterized using Fourier transform infrared spectroscopy (FT-IR), X-ray fluorescence spectroscopy (XRF), scanning electron microscopy-energy dispersive spectroscopy (SEM-EDS) and differential thermo gravimetric analysis (TG-DTG). The results showed that the prepared composite materials retained the highly ordered mesoporous two-dimensional hexagonal structure of SBA-15 and the octagonal structure of Y. The catalyst Ce-Y/SBA-15 was prepared and characterized, then the esterification of n-butanol and oleic acid was studied with bismuth phosphotungstate as a catalyst. Using this model reaction, the effects of Ce-HY/SBA-15, molar ratio of alcohol to oleic acid, amount of catalysts, reaction time and reaction temperature were investigated. The experimental results show that the optimal reaction conditions were: 1.8:1 molar ratio of alcohol to acid, 5 % catalyst amount (based on weight of oleic acid), 4 h reaction time and reflux conditions. Under these conditions, the yield of esterification was 90.6 %. The results suggest that the addition of Ce can effectively improve the catalytic properties of composite molecular sieves.

  10. Dissolution and physicochemical stability enhancement of artemisinin and mefloquine co-formulation via nano-confinement with mesoporous SBA-15.

    Science.gov (United States)

    Letchmanan, Kumaran; Shen, Shou-Cang; Ng, Wai Kiong; Tan, Reginald B H

    2017-07-01

    The objective of this study is to enhance the dissolution rate, supersaturation and physicochemical stability of combination of two poorly water-soluble anti-malarial drugs, artemisinin (ART) and mefloquine (MFQ), by encapsulating them inside mesoporous silica (SBA-15) via co-spray drying. Characteristic studies such as powder X-ray diffraction (PXRD), transmission electron microscopy (TEM) and scanning electron microscope (SEM) clearly indicate the amorphization of the crystalline drugs. ART/MQF/SBA-15 formulations show a superior dissolution enhancement with a burst release of more than 95% of drugs within 30min. In addition, the combination formulation exhibits a stable supersaturation enhancement by 2-fold higher than that of the untreated crystalline counterparts. ART/MQF/SBA-15 samples possess excellent physicochemical stability under 2 different moderate storage conditions for 6 months. The amorphization of ART and MFQ via nano-confinement using mesoporous SBA-15 is a potentially promising approach to enhance the solubility of poorly water-soluble anti-malarial drugs that co-formulated into a single dosage form. Copyright © 2017 Elsevier B.V. All rights reserved.

  11. 2 CFR 2700.930 - Debarring official (SBA supplement to government-wide definition at 2 CFR 180.930).

    Science.gov (United States)

    2010-01-01

    ... government-wide definition at 2 CFR 180.930). 2700.930 Section 2700.930 Grants and Agreements Federal Agency... Definitions § 2700.930 Debarring official (SBA supplement to government-wide definition at 2 CFR 180.930). For... Risk Management; for all other programs, the debarring official is the Associate General Counsel for...

  12. 2 CFR 2700.1010 - Suspending official (SBA supplement to government-wide definition at 2 CFR 180.1010).

    Science.gov (United States)

    2010-01-01

    ... government-wide definition at 2 CFR 180.1010). 2700.1010 Section 2700.1010 Grants and Agreements Federal... SUSPENSION Definitions § 2700.1010 Suspending official (SBA supplement to government-wide definition at 2 CFR... Office of Credit Risk Management; for all other programs, the suspending official is the Associate...

  13. Metathesis of 2-pentene over Mo and W supported mesoporous molecular sieves MCM-41 and SBA-15

    Czech Academy of Sciences Publication Activity Database

    Ibrahim, M. A.; Akhtar, M. N.; Čejka, Jiří; Montanari, E.; Balcar, Hynek; Kubů, Martin; Al-Khattaf, S. S.

    2017-01-01

    Roč. 53, SEP 2017 (2017), s. 119-126 ISSN 1226-086X R&D Projects: GA ČR(CZ) GAP106/12/0189 Institutional support: RVO:61388955 Keywords : metathesis * MCM-41 * SBA-15 Subject RIV: CF - Physical ; Theoretical Chemistry OBOR OECD: Physical chemistry Impact factor: 4.421, year: 2016

  14. Evaluation of AgClNPs@SBA-15/IL nanoparticle-induced oxidative stress and DNA mutation in Escherichia coli.

    Science.gov (United States)

    Karimi, Farrokh; Dabbagh, Somayyeh; Alizadeh, Sina; Rostamnia, Sadegh

    2016-08-01

    The bactericidal effects of silver nanoparticles have been demonstrated in the past years. Recently, the new antimicrobial compounds of silver nanoparticles with different formulations have been developed. In this work, AgClNPs@SBA-15/IL as a new compound of Ag nanoparticles, was synthesized and characterized by XRD, TEM, SEM, FTIR, and EDX. The antibacterial activity and the molecular mechanism effects of AgClNPs@SBA-15/IL nanoparticles (SNPs) on Escherichia coli DH5α cells were investigated by analyzing the growth inhibitory, H2O2 level, catalase activity, DNA mutation, and plasmid copy number following treatment with AgClNPs@SBA-15/IL nanoparticles. In experimental results, the minimum inhibitory concentration (MIC) was observed in 75 μg/ml and the antibacterial efficacy (ABE) in CFU analysis was estimated 95.3 %. In bacterial cells treated with 75 and 100 μg/ml, H2O2 level significantly increased and catalase activity decreased compared with control. The random amplified polymorphic DNA (RAPD) was used to evaluate the effect of AgClNPs@SBA-15/IL nanoparticles in DNA damages and mutation in E. coli genome. RADP-PCR results indicated different banding patterns including appearance or disappearance of bands and differences in their intensity. Cluster analysis of the RAPD-PCR results based on genetic similarity showed genetic difference between E. coli cells treated with AgClNPs@SBA-15/IL nanoparticles, and control and phylogenetic tree were divided to two clusters. Plasmid copy number analysis indicated that after 8 h incubation of E. coli cells with 50, 75, and 100 μg/ml AgClNPs@SBA-15/IL nanoparticles, copy number of pET21a (+) significantly decreased compared with control which indicating DNA replication inhibition by Ag nanoparticles. In conclusion, the results of this study indicated that AgClNPs@SBA-15/IL nanoparticles can be used as an effective bactericidal agent against bacterial cells.

  15. 5 CFR 9901.352 - Setting an employee's starting pay.

    Science.gov (United States)

    2010-01-01

    ... 5 Administrative Personnel 3 2010-01-01 2010-01-01 false Setting an employee's starting pay. 9901.352 Section 9901.352 Administrative Personnel DEPARTMENT OF DEFENSE HUMAN RESOURCES MANAGEMENT AND... NATIONAL SECURITY PERSONNEL SYSTEM (NSPS) Pay and Pay Administration Pay Administration § 9901.352 Setting...

  16. 5 CFR 9701.345 - Developmental pay adjustments.

    Science.gov (United States)

    2010-01-01

    ... HUMAN RESOURCES MANAGEMENT SYSTEM Pay and Pay Administration Performance-Based Pay § 9701.345... 5 Administrative Personnel 3 2010-01-01 2010-01-01 false Developmental pay adjustments. 9701.345 Section 9701.345 Administrative Personnel DEPARTMENT OF HOMELAND SECURITY HUMAN RESOURCES MANAGEMENT...

  17. 5 CFR 9901.305 - Rate of pay.

    Science.gov (United States)

    2010-01-01

    ... 5 Administrative Personnel 3 2010-01-01 2010-01-01 false Rate of pay. 9901.305 Section 9901.305 Administrative Personnel DEPARTMENT OF DEFENSE HUMAN RESOURCES MANAGEMENT AND LABOR RELATIONS SYSTEMS (DEPARTMENT... (NSPS) Pay and Pay Administration General § 9901.305 Rate of pay. (a) The term “rate of pay” in 5 U.S.C...

  18. 76 FR 32859 - General Schedule Locality Pay Areas

    Science.gov (United States)

    2011-06-07

    ... make General Schedule rates of pay ``substantially equal (when considered in the aggregate) to the... is nothing in the pay statute that requires the Government to pay more than warranted by the local.... 5304 and 5 U.S.C. 5941. Congress chose to phase out COLA and replace it with locality pay. Public Law...

  19. 5 CFR 9701.351 - Setting an employee's starting pay.

    Science.gov (United States)

    2010-01-01

    ... SECURITY HUMAN RESOURCES MANAGEMENT SYSTEM Pay and Pay Administration Pay Administration § 9701.351 Setting... 5 Administrative Personnel 3 2010-01-01 2010-01-01 false Setting an employee's starting pay. 9701.351 Section 9701.351 Administrative Personnel DEPARTMENT OF HOMELAND SECURITY HUMAN RESOURCES...

  20. Paying Teachers to Perform: The Impact of Bonus Pay in Pernambuco, Brazil

    Science.gov (United States)

    Ferraz, Claudio; Bruns, Barbara

    2012-01-01

    This study evaluates the impact of a group (school-based) teacher bonus program introduced in the Brazilian state of Pernambuco in 2008. Research questions are: i) Does setting school level targets and awarding bonus pay produce improvements in student learning? ii) Does setting school level targets and awarding bonus pay stimulate visible…

  1. Motivational effects of pay dispersion in pay for performance programs implemented in Romanian companies

    Directory of Open Access Journals (Sweden)

    Urieşi Sebastian

    2016-07-01

    Full Text Available The present study investigates the motivational effects in a sample of Romanian employees in private companies that implement pay for performance programs of one of the characteristics of these programs, namely pay dispersion, and on the potential mediating role of organizational justice in these effects. To this aim, we examined the relationships between the amounts of pay dispersion introduced by the respective financial incentive system, employee perceptions of distributive and procedural justice, work motivation, and base salary, respectively. The results of the data analysis, performed through structural equation modeling, support our hypotheses concerning the positive effect of performance – related pay dispersion on motivation and the mediating role of the two dimensions of organizational justice in this effect. Larger financial rewards allocated by the financial incentive system for high performers increase employee perceptions of distributive and procedural justice, which, in turn, foster work motivation. Base salary was also found to influence pay dispersion, as well as perceived distributive justice.

  2. 7 CFR Exhibit B-4 to Subpart B of... - Letter for Notifying Applicants, Lenders and Holders and Borrowers of Unfavorable Decision...

    Science.gov (United States)

    2010-01-01

    ... Used in Cases Involving Farmer Program Primary Loan Servicing Actions) B Exhibit B-4 to Subpart B of... AGRICULTURE PROGRAM REGULATIONS GENERAL Adverse Decisions and Administrative Appeals Pt. 1900, Subpt. B, Exh. B-4 Exhibit B-4 to Subpart B of Part 1900—Letter for Notifying Applicants, Lenders and Holders and...

  3. 7 CFR Exhibit B-2 to Subpart B of... - Letter for Notifying Applicants, Lenders and Holders and Borrowers of Unfavorable Decision...

    Science.gov (United States)

    2010-01-01

    ... and Borrowers of Unfavorable Decision Reached at the Meeting B Exhibit B-2 to Subpart B of Part 1900... REGULATIONS GENERAL Adverse Decisions and Administrative Appeals Pt. 1900, Subpt. B, Exh. B-2 Exhibit B-2 to Subpart B of Part 1900—Letter for Notifying Applicants, Lenders and Holders and Borrowers of Unfavorable...

  4. 5 CFR 550.131 - Authorization of pay for holiday work.

    Science.gov (United States)

    2010-01-01

    ... 5 Administrative Personnel 1 2010-01-01 2010-01-01 false Authorization of pay for holiday work... REGULATIONS PAY ADMINISTRATION (GENERAL) Premium Pay Pay for Holiday Work § 550.131 Authorization of pay for... entitled to pay at his or her rate of basic pay plus premium pay at a rate equal to his or her rate of...

  5. Laos. Un pays en mutation, Vatthana Pholsena

    Directory of Open Access Journals (Sweden)

    Vanina Bouté

    2012-09-01

    Full Text Available C’est avec un regard neuf et une approche originale que Vatthana Pholsena a relevé le défi d’écrire l’ouvrage Laos. Un pays en mutation, le dernier-né de la collection « Asie Plurielle » (Belin qui a déjà proposé une longue série d’ouvrages de présentation générale des pays d’Asie. Cet ouvrage vient combler un grand manque dans la littérature sur le Laos. Aucun ouvrage généraliste en langue française n’existant jusque-là sur ce petit pays d’Asie du Sud-Est, le lecteur curieux devait se référ...

  6. Java Card for PayTv Application

    OpenAIRE

    Dutta, Pallab

    2013-01-01

    Smart cards are widely used along with PayTV receivers to store secret user keys and to perform security functions to prevent any unauthorized viewing of PayTV channels. Java Card technology enables programs written in the Java programming language to run on smart cards. Smart cards represent one of the smallest computing platforms in use today. The memory configuration of a smart card are of the order of 4K of RAM, 72K of EEPROM, and 24K of ROM. Using Java card provides advantages to the ind...

  7. 34 CFR Appendix D to Part 682 - Policy for Waiving the Secretary's Right To Recover or Refuse To Pay Interest Benefits, Special...

    Science.gov (United States)

    2010-07-01

    ... end of the filing period. However, the lender may, but need not, file a claim on that loan before the... lender may, but need not, file a default claim on the loan at that time. If, however, the loan again... this information as the first day of delinquency. In the course of discussion with lenders, the...

  8. Determination of Thallium(I by Hybrid Mesoporous Silica (SBA-15 Modified Electrode

    Directory of Open Access Journals (Sweden)

    Geeta Rani

    2016-01-01

    Full Text Available Chemically modified mesoporous silica material (SBA-15 was used for the construction of Tl(I selective carbon paste electrode. The best response was found with the electrode containing 10% modifier as electrode material. The electrode has a lower detection limit of 6.0 × 10−9 M in a working concentration range of 1.0 × 10−8–1.0 × 10−1 M. The selectivity coefficient calculated by match potential method (MPM shows the high selectivity of electrode towards Tl(I over other tested ions. The electrode was successfully applied as an indicator electrode for the titration of 0.01 M TlNO3 solution with standards EDTA solution and for sequential titration of mixture of different anions.

  9. Mesoporous carbon synthesized from different pore sizes of SBA-15 for high density electrode supercapacitor application

    Science.gov (United States)

    Jamil, Farinaa Md; Sulaiman, Mohd Ali; Ibrahim, Suhaina Mohd; Masrom, Abdul Kadir; Yahya, Muhd Zu Azhan

    2017-12-01

    A series of mesoporous carbon sample was synthesized using silica template, SBA-15 with two different pore sizes. Impregnation method was applied using glucose as a precursor for converting it into carbon. An appropriate carbonization and silica removal process were carried out to produce a series of mesoporous carbon with different pore sizes and surface areas. Mesoporous carbon sample was then assembled as electrode and its performance was tested using cyclic voltammetry and impedance spectroscopy to study the effect of ion transportation into several pore sizes on electric double layer capacitor (EDLC) system. 6M KOH was used as electrolyte at various scan rates of 10, 20, 30 and 50 mVs-1. The results showed that the pore size of carbon increased as the pore size of template increased and the specific capacitance improved as the increasing of the pore size of carbon.

  10. Temperature dependence of positron lifetime in ordered porous silica (SBA-3)

    International Nuclear Information System (INIS)

    Kunishige, S.; Koshimizu, M.; Asai, K.

    2009-01-01

    The temperature dependence of positron lifetime in uniform mesopores was analyzed. We used SBA-3 as the sample material, which possesses an ordered porous structure with uniform cylindrical mesopores. The positron lifetime corresponding to the annihilation in the mesopores increased gradually with a decrease in temperature down to 100 K, and its relative intensity also increased concomitantly. This result was attributed to the lower probability of the escape of the ortho-positronium (o-Ps) from the mesopores into the intergrain space at lower temperatures. An anomalous and sudden increase in the lifetime was observed at around 100 K; this result was in agreement with an increase in the positron lifetime reported in a previous study. It was revealed that the increase in the lifetime is very steep in cases of uniform mesopores, suggesting that the temperature dependence is influenced by the pore size.

  11. Insights into the Hydrothermal Stability of Triamine-Functionalized SBA-15 Silica for CO2 Adsorption.

    Science.gov (United States)

    Jahandar Lashaki, Masoud; Ziaei-Azad, Hessam; Sayari, Abdelhamid

    2017-10-23

    The hydrothermal stability of triamine-grafted, large-pore SBA-15 CO 2 adsorbents was studied by using steam stripping. Following two 3 h cycles of steam regeneration, lower CO 2 uptakes, lower CO 2 /N ratios, and slower adsorption kinetics were observed relative to fresh samples, particularly at the lowest adsorption temperature (25 °C). CO 2 adsorption measurements for a selected sample exposed to 48 h of steam stripping depicted that after the initial loss during the first exposure to steam (3-6 h), the adsorptive properties stabilized. For higher adsorption temperatures (i.e., 50 and 75 °C), however, all adsorptive properties remained almost unchanged after steaming, indicating the significance of diffusional limitations. Thermogravimetric analysis and FTIR spectroscopy on grafted samples before and after steam stripping showed no amine leaching and no change in the chemical nature of the amine groups, respectively. Also, a six-cycle CO 2 adsorption/desorption experiment under dry conditions showed no thermal degradation. However, N 2 adsorption measurement at 77 K showed significant reductions in the BET surface area of the grafted samples following steaming. Based on the pore size distribution of calcined, grafted samples before and after steaming, it is proposed that exposure to steam restructured the grafted materials, causing mass transfer resistance. It is inferred that triamine-grafted, large-pore SBA-15 adsorbents are potential candidates for CO 2 capture at relatively high temperatures (50-75 °C; for example, flue gas) combined with steam regeneration. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  12. ARE SMES MORE CONFORTABLE WITH SMALL DOMESTIC LENDERS? (II –EVIDENCE FOR ROMANIAN SMES

    Directory of Open Access Journals (Sweden)

    Badulescu Daniel

    2012-12-01

    Full Text Available Based on a consistent literature presented in the previous part of our paper, and analysing our research results, carried out on a significant number of SMEs from Romania in 2011, the purpose of this paper is to examine how SMEs are affected and how they perceive the bank involvement in financing SMEs needs, in terms of the nature and characteristics of organizational structure of these lenders. We have found that, despite of the recent development of the crisis and the decision of the most of important European banks to reduce theirs involvement in Central and Eastern Europe, the mostly of the Romanian SMEs considered they are not ignored or under-privileged by large, international banks operating in Romania.

  13. 76 FR 68631 - Pay in Nonforeign Areas

    Science.gov (United States)

    2011-11-07

    ... of Congress does not have the effect of law, OPM has recognized that it is an expression of the... practice and procedure, Freedom of information, Government employees, Law enforcement officers, Reporting....405 also issued under 5 U.S.C. 552, Freedom of Information Act, Public Law 92-502. Subpart C--Pay...

  14. Women of Color and Pay Equity.

    Science.gov (United States)

    Gee, Marguerite; Mitchell, Denise

    Pay equity is the most important issue affecting all women (but especially women of color) seeking economic equity in the workplace. Over the last two decades, the earnings of White women as a percentage of the earnings of White men have remained constant at about 60%. The wages of women of color, on the other hand, increased dramatically (as a…

  15. 76 FR 45710 - Pay in Nonforeign Areas

    Science.gov (United States)

    2011-08-01

    ... cost-of-living allowances (COLAs) in evaluating the need for special rates, special rate supplements to... in the nonforeign areas while phasing out nonforeign area cost-of-living allowances (COLAs...) Locality pay authorized under 5 U.S.C. 5304 for the area involved; (5) A nonforeign area cost-of-living...

  16. Job Evaluation: Pay Equity Problem or Solution?

    Science.gov (United States)

    Mecham, Robert C.

    It has been hypothesized that current methods of determining pay rates value the characteristics of jobs held primarily by men differently than the characteristics of jobs held primarily by women, resulting in lower earnings for women. A policy capturing approach using numerically rated job characteristics (PAQ data) was applied separately to the…

  17. 78 FR 37246 - January 2013 Pay Schedules

    Science.gov (United States)

    2013-06-20

    ... incorporated as part of this notice. U.S. Office of Personnel Management. Elaine Kaplan, Acting Director... MANAGEMENT January 2013 Pay Schedules AGENCY: U.S. Office of Personnel Management. ACTION: Notice. SUMMARY... levels. This notice serves as documentation for the public record. FOR FURTHER INFORMATION CONTACT...

  18. An Accounting Program Merit Pay Survey

    Science.gov (United States)

    Lindsay, David H.; Campbell, Annhenrie; Tan, Kim B.; Wagner, Andrew

    2010-01-01

    Basing the compensation of accounting professors on merit pay in order to encourage better teaching, research and service is controversial. Before the effectiveness of merit-based salary plans can be examined empirically, it must be determined which accounting programs use such a system. In this study, the 852 accounting programs in the United…

  19. Getting Paid, but Paying the Price.

    Science.gov (United States)

    Greenlee, Craig T.

    2001-01-01

    Explores why Black colleges continue to play guarantee games (in which prominent Division I men's basketball teams pay smaller teams a fee to play them) given the reality of losses by huge margins, and how they reconcile the need to earn money with the need for athletes to have a chance to be truly competitive. (EV)

  20. Why it pays to 'grill' your supplier.

    Science.gov (United States)

    Fudge, Joe

    2010-03-01

    When it comes to ensuring that your cold storage operation and maintenance meets MHRA requirements, it pays to ensure that your service supplier knows what it is doing. So says Joe Fudge, instrumentation service manager for ABB's instrumentation business in the U.K., who outlines some of the key factors to consider when selecting a supplier of cold chain mapping services.

  1. How to pay in LicenseScript

    NARCIS (Netherlands)

    Corin, R.J.; Chong, C.N.; Etalle, Sandro; Hartel, Pieter H.

    Current DRM systems do not provide flexible payment methods, requiring the user to handle the payment by hand. For instance, when the user needs to pay for watching a movie, she needs to decide which available payment method is the most optimal and suitable. This is a rather cumbersome process for

  2. Willingness to Pay for Insurance in Denmark

    DEFF Research Database (Denmark)

    Hansen, Jan V.; Højbjerg Jacobsen, Rasmus; Lau, Morten

    2016-01-01

    Danish population, and information on household income and wealth from registers at Statistics Denmark. The results show that the willingness to pay is marginally higher than the actuarially fair value under expected utility theory, but significantly higher under rank-dependent utility theory, and up...... to 600 percent higher than the actuarially fair value....

  3. The Pays de Gex on the Menu

    CERN Document Server

    2001-01-01

    Did you know that you can swing from tree to tree like Tarzan (or Jane!) in the brand new forest adventure centre at the Col de la Faucille? And that, in addition to Crozet-Lélex, Mijoux-La Faucille and La Vattay, the Pays de Gex boasts a fourth ski resort at Menthières above Bellegarde-sur-Valserine? All these attractions, and hundreds of others that the Pays de Gex has to offer, were presented at a special exhibition stand in CERN's Restaurant No. 1 last week. For the tenth year running, the Pays de Gex-La Faucille Tourist Office and Geneva's fourteen Coop restaurants had organised a special week devoted to promoting the Pays de Gex-Monts Jura region. Thousands of information leaflets were handed out and visitors had the opportunity to take part in a big raffle with no fewer than 145 prizes to be won: ski passes, Juraventure entrance tickets, meal vouchers courtesy of local hotels and restaurants, and subscriptions to the Val Vital fitness centre in Divonne-les-Bains. The Coop restaur...

  4. Teacher-Pay Experiments Mounting Amid Debate

    Science.gov (United States)

    Olson, Lynn

    2007-01-01

    The debate over linking teacher pay to student test scores that ignited on Capitol Hill recently underscores the growing momentum--and continued controversy--behind tying what teachers earn to what students learn. Both the National Education Association and the American Federation of Teachers came out swinging against language in a draft bill for…

  5. Application of sulfonic acid functionalized nanoporous silica (SBA-Pr-SO3H in the green one-pot synthesis of triazoloquinazolinones and benzimidazoquinazolinones

    Directory of Open Access Journals (Sweden)

    Ghodsi Mohammadi Ziarani

    2015-01-01

    Full Text Available Sulfonic acid functionalized SBA-15 (SBA-Pr-SO3H with a pore size of 6 nm was proven to be an efficient heterogeneous nanoporous solid acid catalyst in the green one-pot synthesis of triazoloquinazolinones and benzimidazoquinazolinones from the reaction of aromatic aldehydes with 3-amino-1,2,4-triazole (or 2-aminobenzimidazole and dimedone under solvent free conditions.

  6. 77 FR 6619 - Community Advantage Pilot Program

    Science.gov (United States)

    2012-02-08

    ...-Site Examinations. SBA's Office of Credit Risk Management (OCRM) will evaluate the CA Lender's level of... Community Advantage Pilot Program loan applications (or requests for loan numbers submitted under a lender's... Advantage Lenders (``CA Lenders'') to pledge loans made under the CA Pilot Program (``CA loans'') as...

  7. Pay for performance: will dentistry follow?

    Directory of Open Access Journals (Sweden)

    Gilbert Gregg H

    2010-04-01

    Full Text Available Abstract Background "Pay for performance" is an incentive system that has been gaining acceptance in medicine and is currently being considered for implementation in dentistry. However, it remains unclear whether pay for performance can effect significant and lasting changes in provider behavior and quality of care. Provider acceptance will likely increase if pay for performance programs reward true quality. Therefore, we adopted a quality-oriented approach in reviewing those factors which could influence whether it will be embraced by the dental profession. Discussion The factors contributing to the adoption of value-based purchasing were categorized according to the Donabedian quality of care framework. We identified the dental insurance market, the dental profession position, the organization of dental practice, and the dental patient involvement as structural factors influencing the way dental care is practiced and paid for. After considering variations in dental care and the early stage of development for evidence-based dentistry, the scarcity of outcome indicators, lack of clinical markers, inconsistent use of diagnostic codes and scarcity of electronic dental records, we concluded that, for pay for performance programs to be successfully implemented in dentistry, the dental profession and health services researchers should: 1 expand the knowledge base; 2 increase considerably evidence-based clinical guidelines; and 3 create evidence-based performance measures tied to existing clinical practice guidelines. Summary In this paper, we explored factors that would influence the adoption of value-based purchasing programs in dentistry. Although none of these factors were essential deterrents for the implementation of pay for performance programs in medicine, the aggregate seems to indicate that significant changes are needed before this type of program could be considered a realistic option in dentistry.

  8. Functionalized SBA-15 supported nickel (II)–oxime–imine catalysts for liquid phase oxidation of olefins under solvent-free conditions

    Energy Technology Data Exchange (ETDEWEB)

    Paul, Luna [Department of Chemistry, Jadavpur University, Kolkata 700 032 (India); Banerjee, Biplab [Department of Materials Science, Indian Association for the Cultivation of Science, Jadavpur, Kolkata 700 032 (India); Bhaumik, Asim, E-mail: msab@iacs.res.in [Department of Materials Science, Indian Association for the Cultivation of Science, Jadavpur, Kolkata 700 032 (India); Ali, Mahammad, E-mail: m_ali2062@yahoo.com [Department of Chemistry, Jadavpur University, Kolkata 700 032 (India)

    2016-05-15

    A new oxime–imine functionalized highly ordered mesoporous SBA-15 (SBA-15-NH{sub 2}-DAMO) has been synthesized via post-synthesis functionalization of SBA-15 with 3-aminopropyl-triethoxysilane followed by the Schiff base condensation with diacetylmonooxime, which was further reacted with Ni(ClO{sub 4}){sub 2} to yield the functionalized nickel catalyst SBA-15-NH{sub 2}-DAMO-Ni. All the synthesized materials were thoroughly characterized using different characterization techniques. It was found that SBA-15-NH{sub 2}-DAMO-Ni catalyzes the one-pot oxidation of olefins like styrene, cyclohexene, cyclooctene, 1-hexene and 1-octene to the corresponding benzaldehyde, cyclohexene-1-ol and cyclooctene-oxide, respectively under solvent-free conditions by using tert-butylhydroperoxide as oxidant. - Graphical abstract: A new well characterized oxime–imine functionalized highly ordered mesoporous SBA-15-NH{sub 2}-DAMO-Ni complex catalyzes the one-pot oxidation of olefins under solvent free mild conditions.

  9. Production of Ethylene through Ethanol Dehydration on SBA-15 Catalysts Synthesized by Sol-gel and One-step Hydrothermal Methods.

    Science.gov (United States)

    Autthanit, Chaowat; Jongsomjit, Bunjerd

    2018-02-01

    The present work deals with the catalytic performance of SBA-15 supported catalysts in the gas phase catalytic dehydration of ethanol in the temperature range of 200 to 400°C. The SBA-15 support was incorporated on a zirconium (Zr) and bimetal of zirconium and lanthanum (Zr-La) prepared by sol-gel (SG) and hydrothermal (HT) methods. The catalysts were characterized by means of N 2 physisorption, SEM/EDX, and NH 3 -TPD. The experimental results demonstrated that the Zr-La/SBA-15-HT exhibited the highest catalytic activity. Ethanol conversion and ethylene selectivity were found to increase with increased reaction temperature. The best catalytic results were achieved for Zr-La/SBA-15-HT indicating values of ethanol conversion and ethylene yield of ca. 84% and 80%, respectively at 400°C. The most important parameter influencing their catalytic properties appears to be the interaction between metal and support depending on different methods. The metal dispersion inside the siliceous matrix of SBA-15 has a direct influence on their surface acidity. Meanwhile, the performance of these SBA-15 supported catalysts in ethanol dehydration is also related with the alteration of surface acidity caused by the introduction of Zr and Zr-La.

  10. Heterogeneous advanced photo-fenton oxidation of phenolic aqueous solutions over iron-containing SBA-15 catalyst

    Directory of Open Access Journals (Sweden)

    Bailiche Z.

    2013-09-01

    Full Text Available Iron-containing SBA15 catalysts have been prepared following different synthesisroutes, direct synthesis by adjusting pH at 3 and 6 and with post synthesis procedure. Activity and stability of these materials were assessed on the photo-Fenton degradation of phenolic aqueous solutions by H2O2 using near UV irradiation (254 nm at room temperature and initial neutral pH. Their catalytic performance was mentioned in terms of phenol and total organic carbon (TOC conversions. Several complementary techniques, including XRD, Nitrogen sorption isotherms, UV visible, were used to evaluate the final structural and textural properties of calcined Fe-SBA15 materials. These materials show a high activity and stability of iron species.

  11. Cyclic ligand functionalized mesoporous silica (SBA-15) for selective adsorption of Co2+ ion from artificial seawater.

    Science.gov (United States)

    Moorthy, Madhappan Santha; Park, Sung Soo; Selvaraj, M; Ha, Chang-Sik

    2014-11-01

    Hard donor atoms (N and O) containing macrocyclic ligand was synthesized and further functionalized with mesoporous SBA-15 materials by chemical modification method. The modification was achieved by the immobilization of 3-chloropropyltriethoxysilane (CIPTES) onto mesoporous silica surface followed by post grafting route. The resulting material (Py-Cy-SBA-15) has been characterized by low angle X-ray diffraction (XRD), nitrogen adsorption-desorption isotherm, Fourier-transform infrared (FT-IR) spectroscopy, 29Si and 13C CP MAS NMR spectroscopic analyses, Thermogravimetric analysis (TGA) and elemental analysis. The long range orders of the materials were identified by transmission electron microscopy (TEM). The functionalized material was employed to the heavy metal ions adsorption from aqueous solution containing Cu2+, Co2+, Zn2+, Cd2+ and Cr2+. The prepared hybrid material showed high selectivity and adsorption capacity for Co2+ ion at pH 8.0.

  12. Power and pay: The union and equal pay at B.C. Electric/Hydro

    International Nuclear Information System (INIS)

    Creese, G.

    1993-01-01

    The struggle for equal pay for women in one large office union, the Office and Technical Employees' Union (OTEU), at British Columbia Electric/Hydro is analyzed. The analysis concentrates on the second phase of the equal pay movement that preoccupied the union for over 30 years starting in 1949. Equal pay for equal job-evaluation was finally achieved in 1981, yet this struggle did not produce a subsequent questioning of gender bias within the job evaluation process or the structure of the existing hierarchy of jobs. The study illustrates some of the ways that gender hierarchies and inequities are defined and reinforced by employers seeking to maintain profits by keeping labor costs down, as BC Electric/Hydro resisted eliminating the differential in male and female pay, systematically restructured unequal pay, and continually resorted to lower community standards even when the company's own job evaluation system suggested equal comparators with male jobs. Gendered jobs are also shaped by union practices, as evidenced by the OTEU's role in restructuring the postwar gender division of labor in the late 1940s, as well as their early and persistent challenges to the female differential but, at the same time, the continued marginalization of equal pay as a women's issue rather than a general union issue. 66 refs

  13. Toward a typology of health-related informal credit: an exploration of borrowing practices for paying for health care by the poor in Cambodia

    Directory of Open Access Journals (Sweden)

    Ir Por

    2012-11-01

    Full Text Available Abstract Background Borrowing money is a common strategy to cope with health care costs. The impact of borrowing on households can be severe, leading to indebtedness and further impoverishment. However, the available literature on borrowing practices for health is limited. We explore borrowing practices for paying for health care by the poor in Cambodia and provide a typology, associated conditions, and the extent of the phenomenon. Methods In addition to a semi-structured literature review, in-depth interviews were conducted with representatives of 47 households with health-related debt and 19 managers of formal or informal credit schemes. Results A large proportion of Cambodians, especially the poor, resort to borrowing to meet the cost of health care. Because of limited cash flow and access to formal creditors, the majority take out loans with high interest rates from informal money lenders. The most common type of informal credit is locally known as Changkar and consists of five kinds of loans: short-term loans, medium-term loans, seasonal loans, loans for an unspecified period, and loans with repayment in labour, each with different lending and repayment conditions and interest rates. Conclusion This study suggests the importance of informal credit for coping with the cost of treatment and its potentially negative impact on the livelihood of Cambodian people. We provide directions for further studies on financial protection interventions to mitigate harmful borrowing practices to pay for health care in Cambodia.

  14. A well-defined mesoporous amine silica surface via a selective treatment of SBA-15 with ammonia

    KAUST Repository

    Bendjeriou-Sedjerari, Anissa

    2012-01-01

    2D double-quantum 1H- 1H NMR unambiguously shows that the "isolated" Si-OH surface silanols of dehydroxylated SBA-15 are converted upon treatment with ammonia into single silylamine surface site Si-NH 2. The "gem" di-silanols (Si(OH) 2) remain intact. Treatment using HMDS produces (Si(OSiMe 3) 2) but leaves Si-NH 2 untouched. The resulting surface is hydrophobic and stable. © The Royal Society of Chemistry 2012.

  15. Support and Pretreatment Effects on the Hydrotreating Activity of SBA-15 and CMK-5 Supported Nickel Phosphide Catalysts.

    Czech Academy of Sciences Publication Activity Database

    Korányi, T.I.; Vít, Zdeněk; Nagy, J.B.

    2007-01-01

    Roč. 130, 1 (2007) , s. 80-85 ISSN 0920-5861. [International Symposium Molecular Aspects of Catalysis by Sulfides MACS-IV /4./. Doorn, 13.05.2007-17.05.2007] R&D Projects: GA ČR(CZ) GA104/06/0870 Institutional research plan: CEZ:AV0Z40720504 Keywords : nickel phosphide * sba-15 * cmk-5 Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 2.764, year: 2007

  16. 13 CFR 120.10 - Definitions.

    Science.gov (United States)

    2010-01-01

    ... Provider is an entity that contracts with a Lender or CDC to perform management, marketing, legal or other... to time. SOPs are publicly available on SBA's Web site at http://www.sba.gov in the online library...

  17. Discrete complexes immobilized onto click-SBA-15 silica: controllable loadings and the impact of surface coverage on catalysis.

    Science.gov (United States)

    Nakazawa, Jun; Smith, Brian J; Stack, T Daniel P

    2012-02-08

    Azidopropyl functionalized mesoporous silica SBA-15 were prepared with variable azide loadings of 0.03-0.7 mmol g(-1) (~2-50% of maximal surface coverage) through a direct synthesis, co-condensation approach. These materials are functionalized selectively with ethynylated organic moieties through a copper-catalyzed azide alkyne cycloaddition (CuAAC) or "click" reaction. Specific loading within a material can be regulated by either the azide loading or limiting the alkyne reagent relative to the azide loading. The immobilization of ferrocene, pyrene, tris(pyridylmethyl)amine (TPA), and iron porphyrin (FeTPP) demonstrates the robust nature and reproducibility of this two-step synthetic attachment strategy. Loading-sensitive pyrene fluorescence correlates with a theoretically random surface distribution, rather than a uniform one; site-isolation of tethered moieties ~15 Å in length occurs at loadings less than 0.02 mmol g(-1). The effect of surface loading on reactivity is observed in the oxygenation of SBA-15-[Cu(I)(TPA)]. SBA-15-[Mn(II)(TPA)]-catalyzed epoxidation exhibits a systematic dependence on surface loading. A comparison of homogeneous, site-isolated and site-dense complexes provides insight into catalyst speciation and ligand activity.

  18. Biodegradation of polycyclic aromatic hydrocarbons (PAHs) by laccase from Trametes versicolor covalently immobilized on amino-functionalized SBA-15.

    Science.gov (United States)

    Bautista, Luis Fernando; Morales, Gabriel; Sanz, Raquel

    2015-10-01

    A covalent immobilization method based on glutaraldehyde and amino-functionalized SBA-15 supports has been successfully applied to covalently and stably immobilize laccase from Trametes versicolor. The resultant biocatalysts displayed high incorporation yields of enzyme and led to excellent biodegradation rates of selected HPAs models, i.e. naphthalene, phenanthrene and anthracene, in water. The nature of the hydrocarbon chain accompanying the amino group has been shown as determinant for the immobilization as well as for the activity and reusability of the materials. Thus, alkyl moieties displayed higher enzyme loadings than phenyl moieties, being more adequate the larger n-butyl tethering residue likely due to its higher mobility. Using the aminobutyl-based laccase-SBA-15, 82%, 73%, and 55% conversion of naphthalene, phenanthrene and anthracene, respectively, were achieved after 48 h, very close to the values obtained with free laccase under the same reaction conditions. On the other hand, aminopropyl-based laccase-SBA-15 biocatalysts displayed the best reusability properties, retaining higher activity after four repeated uses than the corresponding aminobutyl-based materials. Copyright © 2015 Elsevier Ltd. All rights reserved.

  19. Dengue vaccine acceptance and willingness to pay.

    Science.gov (United States)

    Harapan, Harapan; Fajar, Jonny K; Sasmono, R Tedjo; Kuch, Ulrich

    2017-04-03

    The introduction of new vaccines is accompanied by a variety of challenges. Among these, very important ones concern the questions whether the public is willing to accept and willing to purchase the vaccine. Here we discuss factors associated with these questions in the context of vaccines that are becoming available against dengue virus infection. We reviewed published studies available from PubMed and Embase, conducting a meta-analysis when possible and narrative review when the data did not qualify for meta-analysis. We found that attitude toward vaccination and socioeconomic level had significant associations with dengue vaccine acceptance. In addition, socioeconomic level, knowledge, attitude and practice regarding dengue fever, having personally experienced dengue fever and vaccine price were associated with willingness to pay for dengue vaccine. To improve acceptance and willingness to pay for dengue vaccine, well-designed introduction programs that address the associated factors in a context-specific manner are essential.

  20. 27 CFR 70.103 - Failure to pay tax.

    Science.gov (United States)

    2010-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 2 2010-04-01 2010-04-01 false Failure to pay tax. 70.103... § 70.103 Failure to pay tax. Whoever fails to pay any tax imposed by Part I of Subchapter A of Chapter... penalty of 5 percent of the tax due but unpaid. For additional penalties for failure to pay tax, see 27...

  1. Employee perspectives on individualized pay : Attitudes and fairness perceptions

    OpenAIRE

    Stråberg, Teresia

    2010-01-01

    The use of various types of individualized pay setting has increased dramatically in Sweden. In order for individualized pay to work as an incentive, the pay system has to be perceived as fair. This thesis focuses on the various subjective perceptions that arise in relation to individualized pay setting, since such perceptions may have consequences for employee attitudes and behavior. Using survey data from Swedish human service workers (Study I and II) as well as other public employees (Stud...

  2. Understanding the "Family Gap" in Pay for Women with Children

    OpenAIRE

    Jane Waldfogel

    1998-01-01

    As the gender gap in pay between women and men has been narrowing, the 'family gap' in pay between mothers and nonmothers has been widening. One reason may be the institutional structure in the United States, which has emphasized equal pay and opportunity policies but not family policies, in contrast to other countries that have implemented both. The authors now have evidence on the links between one such family policy and women's pay. Recent research suggests that maternity leave coverage, b...

  3. Incentive pay and gender gaps in the Nordic countries

    OpenAIRE

    Westling, Tatu

    2011-01-01

    This paper explores the effect of incentive pay on gender pay gaps in Finland, Norway and Sweden among professionals and managers within MNCs. Mercer 2009 Total Remuneration Survey data is utilised. Uniform job ladder, occupation, industry and wage definitions enable consistent cross-country comparisons. In addition to the between-country variation, the within-country variation of gender gap with respect to incentive pay is analysed. The results indicate that gender pay gaps differ among the ...

  4. Low Pay, Poverty and Social Security

    OpenAIRE

    Tim Callan; Brian Nolan

    1992-01-01

    Directing support towards those in employment but on low incomes is one of the most serious challenges facing social security policy, whether based on Beveridge or other models. Beveridge saw family allowances - universal cash transfers for children- as the mechanism for eliminating want for those at work. Means-tested transfers to those in work, tax allowances or exemptions, and minimum wages are other widely-used policy options. Here the links between low pay and poverty and the effectivene...

  5. Pay schemes, bargaining, and competition for talent

    OpenAIRE

    Lindbeck, Assar; Weibull, Jörgen W.

    2015-01-01

    The paper provides a framework for analysis of remuneration to agents whose task is to make well-informed decisions on behalf of a principal, with managers in large corporations as the most prominent example. The principal and agent initially bargain over the pay scheme to the latter. The bargaining outcome depends both on competition for agents and on the relative bargaining power of the two parties, given their outside options, thus allowing for the possibility that the agent may be the cur...

  6. Corruption: Who pays for the bill?

    OpenAIRE

    Figueiredo, Dalila Adriana Bernardino

    2014-01-01

    This paper intends to study who pays for corruption in Brazil from 2005 to 2011. Politicians may decide to charge the spillovers of corruption at a municipal level through taxes or to charge it to the entire country through voluntary transfers. The used measure of corruption is based on audit reports conducted on randomly selected municipalities from 2005 to 2011.In order to address this question an IV strategy was computed using as instrument for the number of observed cases of corruption th...

  7. 27 CFR 70.97 - Failure to pay tax.

    Science.gov (United States)

    2010-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 2 2010-04-01 2010-04-01 false Failure to pay tax. 70.97... § 70.97 Failure to pay tax. (a) Negligence—(1) General. If any part of any underpayment (as defined in... section 6651 of the Internal Revenue Code (relating to failure to file such return or pay tax) shall be...

  8. 5 CFR 9701.372 - Creating initial pay ranges.

    Science.gov (United States)

    2010-01-01

    ... HUMAN RESOURCES MANAGEMENT SYSTEM Pay and Pay Administration Transitional Provisions § 9701.372 Creating... 5 Administrative Personnel 3 2010-01-01 2010-01-01 false Creating initial pay ranges. 9701.372 Section 9701.372 Administrative Personnel DEPARTMENT OF HOMELAND SECURITY HUMAN RESOURCES MANAGEMENT...

  9. 5 CFR 9901.364 - Foreign language proficiency pay.

    Science.gov (United States)

    2010-01-01

    ....364 Section 9901.364 Administrative Personnel DEPARTMENT OF DEFENSE HUMAN RESOURCES MANAGEMENT AND... NATIONAL SECURITY PERSONNEL SYSTEM (NSPS) Pay and Pay Administration Premium Pay § 9901.364 Foreign... policy for administration of the Defense Language Program. (3) Employees may be certified as proficient...

  10. 5 CFR 9901.371 - Conversion into NSPS pay system.

    Science.gov (United States)

    2010-01-01

    ... 5 Administrative Personnel 3 2010-01-01 2010-01-01 false Conversion into NSPS pay system. 9901.371 Section 9901.371 Administrative Personnel DEPARTMENT OF DEFENSE HUMAN RESOURCES MANAGEMENT AND LABOR... SECURITY PERSONNEL SYSTEM (NSPS) Pay and Pay Administration Conversion Provisions § 9901.371 Conversion...

  11. 5 CFR 531.214 - Setting pay upon promotion.

    Science.gov (United States)

    2010-01-01

    ... 5 Administrative Personnel 1 2010-01-01 2010-01-01 false Setting pay upon promotion. 531.214 Section 531.214 Administrative Personnel OFFICE OF PERSONNEL MANAGEMENT CIVIL SERVICE REGULATIONS PAY... Changes § 531.214 Setting pay upon promotion. (a) General. An agency must set an employee's payable rate...

  12. Equal pay legislation and the gender wage gap

    OpenAIRE

    Polachek, Solomon W.

    2014-01-01

    Despite equal pay legislation dating back 50 years, American women still earn 22% less than their male counterparts. In the UK, with its Equal Pay Act of 1970, and France, which legislated in 1972, the gap is 21% and 17% respectively, and in Australia it remains around 17%. Thus, the gender pay gap continues to be an important policy issue.

  13. Reviving Pay Equity: New Strategies for Attacking the Wage Gap.

    Science.gov (United States)

    Kahn, Peggy; Figart, Deborah M.

    1998-01-01

    Pay equity remains a problem linked to the problem of low pay. Pay equity must be understood as one solution to the problem of securing a living wage for women and men in the restructuring economy as well as a means for challenging gender equity. (JOW)

  14. 5 CFR 9701.342 - Performance pay increases.

    Science.gov (United States)

    2010-01-01

    ... increases, the Secretary or designee must take into account the average value of within-grade and quality... pay pool controls to allocate pay increases based on performance points that are directly linked to... function of the amount of money in the performance pay pool, the relative point value placed on ratings...

  15. Colloidally Synthesized Monodisperse Rh Nanoparticles Supported on SBA-15 for Size- and Pretreatment-Dependent Studies of CO Oxidation

    Energy Technology Data Exchange (ETDEWEB)

    Grass, Michael E.; Joo, Sang Hoon; Somorjai, Gabor A.

    2009-02-12

    A particle size dependence for CO oxidation over rhodium nanoparticles of 1.9-11.3 nm has been investigated and determined to be modified by the existence of the capping agent poly(vinylpyrrolidone) (PVP). The particles were prepared using a polyol reduction procedure with PVP as the capping agent. The Rh nanoparticles were subsequently supported on SBA-15 during hydrothermal synthesis to produce Rh/SBA-15 supported catalysts for size-dependent catalytic studies. CO oxidation by O{sub 2} at 40 Torr CO and 100 Torr O{sub 2} was investigated over two series of Rh/SBA-15 catalysts: as-synthesized Rh/SBA-15 covering the full range of Rh sizes and the same set of catalysts after high temperature calcination and reduction. The turnover frequency at 443 K increases from 0.4 to 1.7 s{sup -1} as the particle size decreases from 11.3 to 1.9 nm for the as-synthesized catalysts. After calcination and reduction, the turnover frequency is between 0.1 and 0.4 s{sup -1} with no particle size dependence. The apparent activation energy for all catalysts is {approx}30 kcal mol{sup -1} and is independent of particle size and thermal treatment. Infrared spectroscopy of CO on the Rh nanoparticles indicates that the heat treatments used influence the mode of CO adsorption. As a result, the particle size dependence for CO oxidation is altered after calcination and reduction of the catalysts. CO adsorbs at two distinct bridge sites on as-synthesized Rh/SBA-15, attributable to metallic Rh(0) and oxidized Rh(I) bridge sites. After calcination and reduction, however, CO adsorbs only at Rh(0) atop sites. The change in adsorption geometry and oxidation activity may be attributable to the interaction between PVP and the Rh surface. This capping agent affect may open new possibilities for the tailoring of metal catalysts using solution nanoparticle synthesis methods.

  16. Transition Metal Phosphide Nanoparticles Supported on SBA-15 as Highly Selective Hydrodeoxygenation Catalysts for the Production of Advanced Biofuels.

    Science.gov (United States)

    Yang, Yongxing; Ochoa-Hernández, Cristina; de la Peña O'Shea, Víctor A; Pizarro, Patricia; Coronado, Juan M; Serrano, David P

    2015-09-01

    A series of catalysts constituted by nanoparticles of transition metal (M = Fe, Co, Ni and Mo) phosphides (TMP) dispersed on SBA-15 were synthesized by reduction of the corresponding metal phosphate precursors previously impregnated on the mesostructured support. All the samples contained a metal-loading of 20 wt% and with an initial M/P mole ratio of 1, and they were characterized by X-ray diffraction (XRD), N2 sorption, H2-TPR and transmission electron microscopy (TEM). Metal phosphide nanocatalysts were tested in a high pressure continuous flow reactor for the hydrodeoxygenation (HDO) of a methyl ester blend containing methyl oleate (C17H33-COO-CH3) as main component (70%). This mixture constitutes a convenient surrogate of triglycerides present in vegetable oils, and following catalytic hydrotreating yields mainly n-alkanes. The results of the catalytic assays indicate that Ni2P/SBA-15 catalyst presents the highest ester conversion, whereas the transformation rate is about 20% lower for MoP/SBA-15. In contrast, catalysts based on Fe and Co phosphides show a rather limited activity. Hydrocarbon distribution in the liquid product suggests that both hydrodeoxygenation and decarboxylation/decarbonylation reactions occur simultaneously over the different catalysts, although MoP/SBA-15 possess a selectivity towards hydrodeoxygenation exceeding 90%. Accordingly, the catalyst based on MoP affords the highest yield of n-octadecane, which is the preferred product in terms of carbon atom economy. Subsequently, in order to conjugate the advantages of both Ni and Mo phosphides, a series of catalysts containing variable proportions of both metals were prepared. The obtained results reveal that the mixed phosphides catalysts present a catalytic behavior intermediate between those of the monometallic phosphides. Accordingly, only marginal enhancement of the yield of n-octadecane is obtained for the catalysts with a Mo/Ni ratio of 3. Nevertheless, owing to this high selectivity

  17. Production of Renewable Hydrogen from Glycerol Steam Reforming over Bimetallic Ni-(Cu,Co,Cr Catalysts Supported on SBA-15 Silica

    Directory of Open Access Journals (Sweden)

    Alicia Carrero

    2017-02-01

    Full Text Available Glycerol steam reforming (GSR is a promising alternative to obtain renewable hydrogen and help the economics of the biodiesel industry. Nickel-based catalysts are typically used in reforming reactions. However, the choice of the catalyst greatly influences the process, so the development of bimetallic catalysts is a research topic of relevant interest. In this work, the effect of adding Cu, Co, and Cr to the formulation of Ni/SBA-15 catalysts for hydrogen production by GSR has been studied, looking for an enhancement of its catalytic performance. Bimetallic Ni-M/SBA-15 (M: Co, Cu, Cr samples were prepared by incipient wetness co-impregnation to reach 15 wt % of Ni and 4 wt % of the second metal. Catalysts were characterized by inductively coupled plasma atomic emission spectroscopy (ICP-AES, N2-physisorption, X-ray powder diffraction (XRD, hydrogen temperature programmed reduction (H2-TPR, transmission electron microscopy (TEM, scanning electron microscopy (SEM, and thermogravimetric analyses (TGA, and tested in GSR at 600 °C and atmospheric pressure. The addition of Cu, Co, and Cr to the Ni/SBA-15 catalyst helped to form smaller crystallites of the Ni phase, this effect being more pronounced in the case of the Ni-Cr/SBA-15 sample. This catalyst also showed a reduction profile shifted towards higher temperatures, indicating stronger metal-support interaction. As a consequence, the Ni-Cr/SBA-15 catalyst exhibited the best performance in GSR in terms of glycerol conversion and hydrogen production. Additionally, Ni-Cr/SBA-15 achieved a drastic reduction in coke formation compared to the Ni/SBA-15 material.

  18. The Effects of Introducing Advertising in Pay TV: A Model of Asymmetric Competition between Pay TV and Free TV

    OpenAIRE

    Helmut Dietl; Markus Lang; Panlang Lin

    2012-01-01

    This paper develops a theoretical model of asymmetric competition between a pay TV and a free TV broadcaster. Our model shows that the pay TV broadcaster has incentives to place advertising on its channel if the marginal return on advertising exceeds the viewers' disutility from advertising. In this case, however, the pay TV advertising level is always below the corresponding level on free TV. The pay TV advertising level can increase with a higher viewer disutility from advertising but the p...

  19. Does obfuscating excessive CEO pay work? The influence of remuneration report readability on say-on-pay votes

    NARCIS (Netherlands)

    Hooghiemstra, Reggy; Kuang, Yu Flora; Qin, Bo

    2017-01-01

    This paper assesses whether reducing ‘readability’ is an effective obfuscation strategy for influencing the level of shareholder say-on-pay voting dissent in firms with excessive CEO pay. Based on a sample of UK-listed firms, our results indicate that in cases of excessive CEO pay, a less readable

  20. Summary different routes for procurement of molecular sieves type AL-SBA-15

    International Nuclear Information System (INIS)

    Figueiroa, D.S.; Santos, J.O.P.N.; Medeiros, C.D.; Sousa, B.V.

    2012-01-01

    The search for new materials to assist industrial development, especially in the chemical industry has been growing more and more. Molecular sieves are great examples of these materials that aim the improvement of various chemical processes. The present work aimed to synthesize the molecular sieve Al-SBA-15 by two different synthesis procedures. In procedure A was used a temperature of 40°C for 24 hours during stirring process. For B process the stirring procedure was done at room temperature. The molar composition of reactants was: 1.0 SiO 2 : 0.04 Al 2 O 3 :0.0168 EO 20 PO 70 EO 20 : 5.85 HCl: 160 H 2 O. The pH of the reaction gel was adjusted to 7 and after the gel was putted under 100 deg C for 48 hours for the heat treatment. Then the sample was calcined under flowing air at 500° C for 6 hours. By techniques such as XRD and SEM, it was confirmed the formation of the hexagonal mesoporous structure, with an orderly distribution of its pores, also indicating the successful incorporation of aluminum into the hexagonal structure of the catalyst support. (author)

  1. The Epoxidation of Limonene over the TS-1 and Ti-SBA-15 Catalysts

    Directory of Open Access Journals (Sweden)

    Agnieszka Wróblewska

    2014-11-01

    Full Text Available Limonene belongs to a group of very important intermediates used in the production of fine chemicals. This monoterpene compound can be obtained from peels of oranges or lemon which are a (biomass waste from the orange juice industry. Thus, limonene is a renewable, easy available and a relatively cheap compound. This work presents preliminary studies on the process of limonene epoxidation over zeolite type catalysts such as: TS-1 and Ti-SBA-15. In these studies methanol was used as a solvent and as an oxidizing agent a 60 wt % hydrogen peroxide solution was applied. The activity of each catalyst was investigated for four chosen temperatures (0 °C, 40 °C, 80 °C and 120 °C. The reaction time was changed from 0.5 to 24 h. For each catalyst the most beneficial conditions (the appropriate temperature and the reaction time have been established. The obtained results were compared and the most active catalyst was chosen. These studies have also shown different possible ways of limonene transformation, not only in the direction of 1,2-epoxylimonene and its corresponding diol, but also in direction of carveol, carvone and perillyl alcohol—compounds with a lot of applications. The possible mechanisms of formation of the allylic oxidation products were proposed.

  2. Covalent Anchoring of Chloroperoxidase and Glucose Oxidase on the Mesoporous Molecular Sieve SBA-15

    Directory of Open Access Journals (Sweden)

    Martin Hartmann

    2010-02-01

    Full Text Available Functionalization of porous solids plays an important role in many areas, including heterogeneous catalysis and enzyme immobilization. In this study, large-pore ordered mesoporous SBA-15 molecular sieves were synthesized with tetraethyl orthosilicate (TEOS in the presence of the non-ionic triblock co-polymer Pluronic P123 under acidic conditions. These materials were grafted with 3 aminopropyltrimethoxysilane (ATS, 3-glycidoxypropyltrimethoxysilane (GTS and with 3 aminopropyltrimethoxysilane and glutaraldehyde (GA-ATS in order to provide covalent anchoring points for enzymes. The samples were characterized by nitrogen adsorption, powder X-ray diffraction, solid-state NMR spectroscopy, elemental analysis, diffuse reflectance fourier transform infrared spectroscopy and diffuse reflectance UV/Vis spectroscopy. The obtained grafted materials were then used for the immobilization of chloroperoxidase (CPO and glucose oxidase (GOx and the resulting biocatalysts were tested in the oxidation of indole. It is found that enzymes anchored to the mesoporous host by the organic moieties can be stored for weeks without losing their activity. Furthermore, the covalently linked enzymes are shown to be less prone to leaching than the physically adsorbed enzymes, as tested in a fixed-bed reactor under continuous operation conditions.

  3. QCM study of superfluid transition in 4He films adsorbed in SBA-15

    International Nuclear Information System (INIS)

    Matsuda, K; Hieda, M; Matsushita, T; Wada, N; Suzuki, T; Kuroda, K

    2009-01-01

    A quartz crystal microbalance (QCM) is a useful tool to study the superfluidity of 4 He films at very high frequencies. Our recent efforts to fabricate mesoporous silica films onto QCM have enabled us to study the noble superfluidity adsorbed in nanopores. In this paper we report results of QCM measurements for the superfluid 4 He films in SBA-15 with one-dimensional nanopores 4.1 nm in diameter and ∼ 1 μM in length. From the 4 He pressure isotherm at 4.2 K, a uniform layer is formed in the nanopores up to the coverage of 48 μmol/m 2 , corresponding to ∼ 2.5 layers. The superfluid response is measured at 12 MHz for various coverages in the temperature range of 0.1 - 1.5 K. Above the onset coverage of ∼ 23 μmol/m 2 , we observed a frequency shift accompanied by a dissipation peak due to the superfluid Kosterlitz-Thouless (KT) transition.

  4. A novel visible light-driven Ag3PO4/SBA-15 nanocomposite: Preparation and application in the photo-degradation of pollutants

    International Nuclear Information System (INIS)

    Chai, Yuanyuan; Wang, Li; Ren, Jia; Dai, Wei-Lin

    2015-01-01

    Graphical abstract: - Highlights: • Highly efficient visible-light-driven Ag 3 PO 4 /SBA-15 nanocomposite. • Application in the photo-degradation of RhB. • Synthesis from a facile and simple colloidal method. • 20%-Ag 3 PO 4 /SBA-15 shows 8 times faster degradation rate than Ag 3 PO 4 . • Super stability and recycling ability. - Abstract: A novel visible light-driven environmental-benign Ag 3 PO 4 /SBA-15 nanocomposite photo-catalyst was synthesized for the photo-degradation of pollutants. The exploration on adsorption and photo-catalysis of dye or organic pollution for the nanocomposite was carried out. The adsorption capability for Ag 3 PO 4 /SBA-15 nanocomposite increases by 3 times compared with that of the Ag 3 PO 4 particles. The photo-catalytic activity of nanocomposite is higher than pristine Ag 3 PO 4 nanoparticle for the degradation of RhB or MO under visible light irradiation (λ > 420 nm). The effect of Ag 3 PO 4 loading on the catalytic performance was also studied. The results show that the optimum degradation is achieved over 20% Ag 3 PO 4 /SBA-15. Compared to pure Ag 3 PO 4 nanoparticle, the most efficient catalyst showed 8 times higher photo-catalytic activity for the degradation of RhB. The Ag 3 PO 4 /SBA-15 catalysts were systematically characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), UV–Vis diffuse reflectance spectroscopy (DRS), and N 2 -adsorption–desorption isotherms (BET). A possible mechanism scheme regarding photo-degradation enhancement induced by dye enrichments has been proposed on the Ag 3 PO 4 /SBA-15 nanocomposite. Additionally, the SBA-15 support can enhance the efficiency of separation of catalyst from the reaction mixture, implying that the Ag 3 PO 4 loading on the SBA-15 catalyst will not result in the extra environment and health problems and reduce the cost of wastewater treatment

  5. Controlled synthesis, characterization, and catalytic properties of Mn(2)O(3) and Mn(3)O(4) nanoparticles supported on mesoporous silica SBA-15.

    Science.gov (United States)

    Han, Yi-Fan; Chen, Fengxi; Zhong, Ziyi; Ramesh, Kanaparthi; Chen, Luwei; Widjaja, Effendi

    2006-12-07

    A method established in the present study has proven to be effective in the synthesis of Mn(2)O(3) nanocrystals by the thermolysis of manganese(III) acetyl acetonate ([CH(3)COCH=C(O)CH(3)](3)-Mn) and Mn(3)O(4) nanocrystals by the thermolysis of manganese(II) acetyl acetonate ([CH(3)COCH=C(O)-CH(3)](2)Mn) on a mesoporous silica, SBA-15. In particular, Mn(2)O(3) nanocrystals are the first to be reported to be synthesized on SBA-15. The structure, texture, and electronic properties of nanocomposites were studied using various characterization techniques such as N2 physisorption, X-ray diffraction (XRD), laser Raman spectroscopy (LRS), temperature-programmed reduction (TPR), transmission electron microscopy (TEM), and X-ray photoelectron spectroscopy (XPS). The results of powder XRD at low angles show that the framework of SBA-15 remains unaffected after generation of the manganese oxide (MnO(x)) nanoparticles, whereas the pore volume and the surface area of SBA-15 dramatically decreased as indicated by N2 adsorption-desorption. TEM images reveal that the pores of SBA-15 are progressively blocked with MnO(x) nanoparticles. The formation of the hausmannite Mn(3)O(4) and bixbyite Mn(2)O(3) structures was clearly confirmed by XRD. The surface structures of MnO(x) were also determined by LRS, XPS, and TPR. The crystalline phases of MnO(x) were identified by LRS with corresponding out-of-plane bending and symmetric stretching vibrations of bridging oxygen species (M-O-M) of both MnO(x) nanoparticles and bulk MnO(x). We also observed the terminal Mn=O bonds corresponding to vibrations at 940 and 974 cm-1 for Mn(3)O(4)/SBA-15 and Mn(2)O(3)/SBA-15, respectively. These results show that the MnO(x) species to be highly dispersed inside the channels of SBA-15. The nanostructure of the particles was further identified by the TPR profiles. Furthermore, the chemical states of the surface manganese (Mn) determined by XPS agreed well with the findings of LRS and XRD. These results

  6. Preparation of SBA-15-PAMAM as a Nano Adsorbent for Removal of Acid Red 266 from Aqueous Media: Batch Adsorption and Equilibrium Studies

    Directory of Open Access Journals (Sweden)

    Maryam Mirzaie

    2017-12-01

    Full Text Available The purpose of the present study was to increase the adsorption capacity of SBA-15 for acidic dyes. Ordered mesoporous silica SBA-15 was successfully synthesized and functionalized by polyamidoamine (PAMAM dendrimer to develop an efficient anionic dye adsorbent. The prepared materials were characterized by field emission scanning electron microscope (FE-SEM, Fourier transforms infrared spectroscope (FT-IR and N2 adsorption–desorption analysis. The study was concocted in the Science and Research Branch of Islamic Azad University of Tehran, Iran in 2016. The produced adsorbent (SBA-15-Den was applied for the removal of Acid Red 266 (AR266 from aqueous media. The effects of various operational parameters including solution pH, adsorbent dosage, contact time, and temperature on removal of AR266 using SBA-15-Den were investigated in batch adsorption mode. Within the optimum conditions, SBA-15-Den exhibited an excellent adsorptive capability of 1111.11 mg/g. Equilibrium data were best described by Langmuir model (R2 > 0.98 completely.

  7. Catalytic Steam Reforming of Toluene as a Model Compound of Biomass Gasification Tar Using Ni-CeO2/SBA-15 Catalysts

    Directory of Open Access Journals (Sweden)

    Erik Dahlquist

    2013-07-01

    Full Text Available Nickel supported on SBA-15 doped with CeO2 catalysts (Ni-CeO2/SBA-15 was prepared, and used for steam reforming of toluene which was selected as a model compound of biomass gasification tar. A fixed-bed lab-scale set was designed and employed to evaluate the catalytic performances of the Ni-CeO2/SBA-15 catalysts. Experiments were performed to reveal the effects of several factors on the toluene conversion and product gas composition, including the reaction temperature, steam/carbon (S/C ratio, and CeO2 loading content. Moreover, the catalysts were subjected to analysis of their carbon contents after the steam reforming experiments, as well as to test the catalytic stability over a long experimental period. The results indicated that the Ni-CeO2/SBA-15 catalysts exhibited promising capabilities on the toluene conversion, anti-coke deposition and catalytic stability. The toluene conversion reached as high as 98.9% at steam reforming temperature of 850 °C and S/C ratio of 3 using the Ni-CeO2(3wt%/SBA-15 catalyst. Negligible coke formation was detected on the used catalyst. The gaseous products mainly consisted of H2 and CO, together with a little CO2 and CH4.

  8. EMBL pay settlement will cost millions

    CERN Multimedia

    Abott, A

    1999-01-01

    A labour dispute at EMBL, Heidelberg, was settled last week at a cost of at least DM4 million for the organisation's 16 member states. The lab has asked for clarification on whether the ruling from the IL0 refers simply to a salary adjustment from 1995 or also to a backdated implementation of higher salary scales. This second option would cost considerably more - 8 percent of the budget in back pay and DM3.5 million per annum (1/2 page).

  9. Pay Policy Reform : Building a Foundation for Public Sector Performance Through Improved Public Sector Pay Policy by Using a "Single Pay Spine"

    OpenAIRE

    Malcolm Green

    2009-01-01

    Appropriate public sector remuneration policies are key for performance. They can motivate staff to a limited extent by rewarding performance but more generally by eliminating inequities and avoiding frequent and sudden changes in pay. They can also assist in retaining competent staff one of the most critical drivers of public sector performance. Developing pay policy in the public sector is ...

  10. 5 CFR 550.171 - Authorization of pay for Sunday work.

    Science.gov (United States)

    2010-01-01

    ... rate equal to 25 percent of his or her rate of basic pay for each hour of Sunday work (as defined in... 5 Administrative Personnel 1 2010-01-01 2010-01-01 false Authorization of pay for Sunday work. 550... PAY ADMINISTRATION (GENERAL) Premium Pay Pay for Sunday Work § 550.171 Authorization of pay for Sunday...

  11. 41 CFR 302-3.417 - Will I have to pay any income tax if my agency pays for extended storage of my household goods?

    Science.gov (United States)

    2010-07-01

    ... income tax if my agency pays for extended storage of my household goods? 302-3.417 Section 302-3.417... Paid During Assignment § 302-3.417 Will I have to pay any income tax if my agency pays for extended... expenses your agency pays. However, your agency will pay you a relocation income tax allowance under part...

  12. Frontal Brain Asymmetry and Willingness to Pay

    Directory of Open Access Journals (Sweden)

    Thomas Z. Ramsøy

    2018-03-01

    Full Text Available Consumers frequently make decisions about how much they are willing to pay (WTP for specific products and services, but little is known about the neural mechanisms underlying such calculations. In this study, we were interested in testing whether specific brain activation—the asymmetry in engagement of the prefrontal cortex—would be related to consumer choice. Subjects saw products and subsequently decided how much they were willing to pay for each product, while undergoing neuroimaging using electroencephalography. Our results demonstrate that prefrontal asymmetry in the gamma frequency band, and a trend in the beta frequency band that was recorded during product viewing was significantly related to subsequent WTP responses. Frontal asymmetry in the alpha band was not related to WTP decisions. Besides suggesting separate neuropsychological mechanisms of consumer choice, we find that one specific measure—the prefrontal gamma asymmetry—was most strongly related to WTP responses, and was most coupled to the actual decision phase. These findings are discussed in light of the psychology of WTP calculations, and in relation to the recent emergence of consumer neuroscience and neuromarketing.

  13. Frontal Brain Asymmetry and Willingness to Pay.

    Science.gov (United States)

    Ramsøy, Thomas Z; Skov, Martin; Christensen, Maiken K; Stahlhut, Carsten

    2018-01-01

    Consumers frequently make decisions about how much they are willing to pay (WTP) for specific products and services, but little is known about the neural mechanisms underlying such calculations. In this study, we were interested in testing whether specific brain activation-the asymmetry in engagement of the prefrontal cortex-would be related to consumer choice. Subjects saw products and subsequently decided how much they were willing to pay for each product, while undergoing neuroimaging using electroencephalography. Our results demonstrate that prefrontal asymmetry in the gamma frequency band, and a trend in the beta frequency band that was recorded during product viewing was significantly related to subsequent WTP responses. Frontal asymmetry in the alpha band was not related to WTP decisions. Besides suggesting separate neuropsychological mechanisms of consumer choice, we find that one specific measure-the prefrontal gamma asymmetry-was most strongly related to WTP responses, and was most coupled to the actual decision phase. These findings are discussed in light of the psychology of WTP calculations, and in relation to the recent emergence of consumer neuroscience and neuromarketing.

  14. Refusal to pay electricity bill is illegal

    International Nuclear Information System (INIS)

    Hermann, H.P.

    1979-01-01

    Pursuant to a judgement passed by the Lower Court of Hamburg, the author discusses probable legal arguments justifying the refusal to pay one's electricity bill, the so-called electricity bill boycott. Following an analysis of the power supply contract and of the content and the limits of the fundamental right of freedom of conscience, as well as of the concept of free enterprise and of the legal effect of licenses under the nuclear law, his point of view stated in the article is to agree with the decision of the court saying that the operation of a nuclear power plant licensed under the nuclear law does not mean an infringement of the right of freedom of conscience. It can further not be accepted to let people refuse to pay their electricity bill by referring to the right of freedom of speech, by alleging conduct against public policy on the part of the public utilities, or by referring to the right of opposition. (HSCH) [de

  15. Gender Differences in Pay Histories and Views on Pay Entitlement among University Students.

    Science.gov (United States)

    Desmarais, Serge; Curtis, James

    1997-01-01

    Examines whether gender differences in recent pay experience influence entitlement views by providing different standards for female and male students' judgments of their entitlements. Responses from 309 undergraduate students reveal that income gaps in the full-time working world extended to their own recent work experiences and that these past…

  16. Ultrasound-assisted polyol method for the preparation of SBA-15-supported ruthenium nanoparticles and the study of their catalytic activity on the partial oxidation of methane.

    Science.gov (United States)

    Li, Hongliang; Wang, Renzhang; Hong, Qi; Chen, Luwei; Zhong, Ziyi; Koltypin, Yuri; Calderon-Moreno, J; Gedanken, Aharon

    2004-09-14

    Metallic Ru nanoparticles have been successfully produced and incorporated into the pores of SBA-15 in situ employing a simple ultrasound-assisted polyol method. The product has been confirmed by X-ray diffraction, transmission electron microscopy, and X-ray photoelectron spectroscopy, where ultrasound provides both the energy for the reduction of the Ru(III) ion and the driving force for the loading of the Ru(0) nanoparticles into the SBA-15 pores. An ultrasound-assisted insertion mechanism has been proposed based on the microjets and shake-wave effect of the collapsed bubbles. The catalytic properties of the SBA-15-supported Ru nanoparticles have been tested by the partial oxidization of methane and show very high activity and high CO selectivity.

  17. Space-confined preparation of high surface area tungsten oxide and tungsten nitride inside the pores of mesoporous silica SBA-15

    DEFF Research Database (Denmark)

    Meyer, Simon; Beyer, Hans; Köhler, Klaus

    2015-01-01

    For the direct preparation of high surface area nitride materials, a lack of suitable precursors exists. Indirect preparation by gas phase nitridation (e.g. by ammonia) requires high temperatures and often results in sintering. The present work demonstrates that the space-confined preparation of W2......N inside the pores of ordered mesoporous silica SBA-15 offers a possibility to reduce sintering phenomena and thus to obtain smaller particles, porous structures and a higher surface area material. The preparation was pursued in a two-step approach. First, WO3 was introduced into the channels of SBA......-15 and second, ammonolysis was conducted for its conversion to W2N. When performed in the presence of the exo-template, SBA-15 acts as a stabilizer and small W2N particles (6-7 nm) with a high specific surface area (40 m(2) g(-1)) are obtained after template removal. When the template is, however...

  18. Pyrolysis and co-pyrolysis of Laminaria japonica and polypropylene over mesoporous Al-SBA-15 catalyst

    Science.gov (United States)

    Lee, Hyung Won; Choi, Suek Joo; Park, Sung Hoon; Jeon, Jong-Ki; Jung, Sang-Chul; Kim, Sang Chai; Park, Young-Kwon

    2014-08-01

    The catalytic co-pyrolysis of a seaweed biomass, Laminaria japonica, and a typical polymer material, polypropylene, was studied for the first time. A mesoporous material Al-SBA-15 was used as a catalyst. Pyrolysis experiments were conducted using a fixed-bed reactor and pyrolysis gas chromatography/mass spectrometry (Py-GC/MS). BET surface area, N2 adsorption-desorption isotherms, and NH3 temperature programmed desorption were measured to examine the catalyst characteristics. When only L. japonica was pyrolyzed, catalytic reforming slightly increased the gas yield and decreased the oil yield. The H2O content in bio-oil was increased by catalytic reforming from 42.03 to 50.32 wt% due to the dehydration reaction occurring on the acid sites inside the large pores of Al-SBA-15. Acids, oxygenates, mono-aromatics, poly aromatic hydrocarbons, and phenolics were the main components of the bio-oil obtained from the pyrolysis of L. japonica. Upon catalytic reforming over Al-SBA-15, the main oxygenate species 1,4-anhydro- d-galactitol and 1,5-anhydro- d-manitol were completely removed. When L. japonica was co-pyrolyzed with polypropylene, the H2O content in bio-oil was decreased dramatically (8.93 wt% in the case of catalytic co-pyrolysis), contributing to the improvement of the oil quality. A huge increase in the content of gasoline-range and diesel-range hydrocarbons in bio-oil was the most remarkable change that resulted from the co-pyrolysis with polypropylene, suggesting its potential as a transport fuel. The content of mono-aromatics with high economic value was also increased significantly by catalytic co-pyrolysis.

  19. Syngas Production from CO2 Reforming and CO2-steam Reforming of Methane over Ni/Ce-SBA-15 Catalyst

    Science.gov (United States)

    Tan, J. S.; Danh, H. T.; Singh, S.; Truong, Q. D.; Setiabudi, H. D.; Vo, D.-V. N.

    2017-06-01

    This study compares the catalytic performance of mesoporous 10 Ni/Ce-SBA-15 catalyst for CO2 reforming and CO2-steam reforming of methane reactions in syngas production. The catalytic performance of 10 Ni/Ce-SBA-15 catalyst for CO2 reforming and CO2-steam reforming of methane was evaluated in a temperature-controlled tubular fixed-bed reactor at stoichiometric feed composition, 1023 K and atmospheric pressure for 12 h on-stream with gas hourly space velocity (GHSV) of 36 L gcat -1 h-1. The 10 Ni/Ce-SBA-15 catalyst possessed a high specific BET surface area and average pore volume of 595.04 m2 g-1. The XRD measurement revealed the presence of NiO phase with crystallite dimension of about 13.60 nm whilst H2-TPR result indicates that NiO phase was completely reduced to metallic Ni0 phase at temperature beyond 800 K and the reduction temperature relied on different degrees of metal-support interaction associated with the location and size of NiO particles. The catalytic reactivity was significantly enhanced with increasing H2O/CO2 feed ratio. Interestingly, the H2/CO ratio for CO2-steam reforming of methane varied between 1 and 3 indicated the occurrence of parallel reactions, i.e., CH4 steam reforming giving a H2/CO of 3 whilst reverse water-gas shift (RWGS) reaction consuming H2 to produce CO gaseous product.

  20. Pyrolysis and co-pyrolysis of Laminaria japonica and polypropylene over mesoporous Al-SBA-15 catalyst

    Science.gov (United States)

    2014-01-01

    The catalytic co-pyrolysis of a seaweed biomass, Laminaria japonica, and a typical polymer material, polypropylene, was studied for the first time. A mesoporous material Al-SBA-15 was used as a catalyst. Pyrolysis experiments were conducted using a fixed-bed reactor and pyrolysis gas chromatography/mass spectrometry (Py-GC/MS). BET surface area, N2 adsorption-desorption isotherms, and NH3 temperature programmed desorption were measured to examine the catalyst characteristics. When only L. japonica was pyrolyzed, catalytic reforming slightly increased the gas yield and decreased the oil yield. The H2O content in bio-oil was increased by catalytic reforming from 42.03 to 50.32 wt% due to the dehydration reaction occurring on the acid sites inside the large pores of Al-SBA-15. Acids, oxygenates, mono-aromatics, poly aromatic hydrocarbons, and phenolics were the main components of the bio-oil obtained from the pyrolysis of L. japonica. Upon catalytic reforming over Al-SBA-15, the main oxygenate species 1,4-anhydro-d-galactitol and 1,5-anhydro-d-manitol were completely removed. When L. japonica was co-pyrolyzed with polypropylene, the H2O content in bio-oil was decreased dramatically (8.93 wt% in the case of catalytic co-pyrolysis), contributing to the improvement of the oil quality. A huge increase in the content of gasoline-range and diesel-range hydrocarbons in bio-oil was the most remarkable change that resulted from the co-pyrolysis with polypropylene, suggesting its potential as a transport fuel. The content of mono-aromatics with high economic value was also increased significantly by catalytic co-pyrolysis. PMID:25136282

  1. Synthesis of lithium superionic conductor by growth of a nanoglass within mesoporous silica SBA-15 template

    Science.gov (United States)

    Chatterjee, Soumi; Miah, Milon; Saha, Shyamal Kumar; Chakravorty, Dipankar

    2018-04-01

    Nanodimensional silica based glasses containing alkali ions have recently been grown using suitable templates. These have shown electrical properties drastically different from those of their bulk counterpart. We have synthesized silicophosphate glasses having lithium ions with concentrations of 15-35 mole% Li2O within mesoporous silica SBA-15 (Santa Barbara amorphous-15) comprising of pores of diameter ~5 nm. The nanoglasses are characterized by electrical conductivities 5-6 orders of magnitude higher than those of the corresponding bulk glasses. These properties are attributed to the presence of a larger free volume in the nanoglasses as compared to their bulk states. The nanocomposites with 35 mole% Li2O exhibit an electrical conductivity of ~3 × 10-4 S · cm-1 at around room temperature. The activation energy for Li+ ion migration has been estimated from the conductivity-temperature variation to be 0.078 eV. These nanocomposites are believed to be ideally suited for the fabrication of solid state lithium ion batteries. We have also explored the efficiency of silicophosphate glass powders as possible electrode materials. Glass of composition 70SiO2/30P2O5 was prepared by using Pluronic P-123 tri-block copolymer along with suitable precursor sols. Cyclic voltammetric and galvanostatic charge/discharge measurements were carried out on the samples prepared in combination with suitable conductive fillers using a two-electrode system. These exhibited a high specific capacitance of 356 F g-1 making them ideally suitable as electrode materials for making a lithium ion solid state battery system.

  2. CO2 activation through silylimido and silylamido zirconium hydrides supported on N-donor chelating SBA15 surface ligand

    KAUST Repository

    Pasha, Fahran Ahmad

    2016-01-04

    Density functional theory calculations and 2D 1H-13C HETCOR solid state NMR spectroscopy prove that CO2 can probe, by its own reactivity, different types of N-donor surface ligands on SBA15-supported ZrIV hydrides: [(≡Si-O-)(≡Si-N=)[Zr]H] and [(≡Si-NH-)(≡Si-X-)[Zr]H2] (X = O or NH). Moreover, [(≡Si-O-)(≡Si-N=)[Zr]H] activates CO2 more efficiently than the other complexes and leads to a carbimato Zr formate.

  3. Heat storage properties of organic phase-change materials confined in the nanospace of mesoporous SBA-15 and CMK-3.

    Science.gov (United States)

    Kadoono, Tomosuke; Ogura, Masaru

    2014-03-28

    A novel type of material encapsulating phase-change materials (PCMs) is reported concerning their implication for use as thermal energy storage devices. The composites of siliceous SBA-15 or carbonaceous CMK-3 mesoporous assemblies and organic PCMs could be used to make leak-free devices that retain their capabilities over many thermal cycles for heat storage/release. A confinement effect was observed that alters the thermal properties of the encapsulated PCM, especially in CMK-3 without any similar effects in other carbon materials.

  4. 26 CFR 301.6653-1 - Failure to pay tax.

    Science.gov (United States)

    2010-04-01

    ... 26 Internal Revenue 18 2010-04-01 2010-04-01 false Failure to pay tax. 301.6653-1 Section 301.6653... Additions to the Tax and Additional Amounts § 301.6653-1 Failure to pay tax. (a) Negligence or intentional... paragraph (b)(2) of this section. (e) Failure to pay stamp tax. Any person (as defined in section 6671(b...

  5. CULTURAL INFLUENCES ON PRE-PAY MOBILE TELECOMMUNICATIONS SERVICES USERS

    Directory of Open Access Journals (Sweden)

    Georgeta-Madalina MEGHISAN

    2015-06-01

    Full Text Available Purpose: The purpose of this research paper is to identify the preferences of the pre-pay mobile telecommunications services young users from Romania. Approach/ methodology: The analysis of the pre-pay mobile telecommunications services was made using statistical functions: descriptive statistics, t test, correlation and factor analysis. Results: According to the analysis made, we could underline the habits of usage from the part of pre-pay mobile telecommunications services consumers. Originality: The paper drew an objective analysis on the pre-pay mobile telecommunications services from the perspective of young consumers.

  6. The Pays de Gex celebrates science

    CERN Document Server

    CERN Bulletin

    2010-01-01

    From 18 to 23 October, the Fête de la Science will be celebrated at various venues in the Pays de Gex and at CERN.   Physiscope will perform awe-inspiring demonstrations in the Globe. The Physiscope team will give demonstrations for schools and the general public in the Globe, performing awe-inspiring experiments to answer questions like "Can you drive a nail in with a banana?" or "Is it possible to survive a 100,000 volt shock?" The Esplanade du Lac in Divonne-les-Bains will host a Café des Sciences and performances by the children of the Lycée International in Ferney-Voltaire. The Physiscope is an educational venture of the Physics section of the University of Geneva and the research programme MaNEP. The programme of the Fête de la Science can be consulted here.      

  7. Who will pay the ecological debts

    International Nuclear Information System (INIS)

    Marcan, P.; Benka, M.

    2006-01-01

    The ecological ignorance of the past has to be addressed. The question is who will pay the ecological debts. State officials know exactly who should pay. According to them the main part of the burden should be carried by companies - the successors of the former socialist factories and companies that inherited the ecological debts. The companies object to this idea. And their reason is obvious - the estimated cost of the disposal of all high risk tips, old chemical stores and contaminated soil amounts to a prohibitive 100 billions Slovak crowns (2.63 billion EUR). The Ministry of Environment of the Slovak Republic has been working on legislation that would address the ecological debt in a comprehensive way for two years. But the final effect is minimal. The draft legislation presented in 2004 did not pass the commenting process and after pressure from the commercial sector the Ministry finally withdrew its draft. The Ministry then formed a working group with representatives of industries that was supposed to find a solution acceptable for both environmentalists and industries. But no progress has been made so far. 'The original bill was superficial and not supported by expert studies. And was presented too early,' explained Jozef Mikulec, a representative of the Industry Association of Slovakia, and argued that not even the European Union has yet issued a dedicated directive addressing the environmental burden. In his opinion the existing legislation - the Act on Water - is sufficient: and the closed and liquidated petrol stations provide a good enough example. At some old petrol stations the distribution pipes were leaking. The Ministry of Environment wants a new act. In its opinion the Act on Water only addresses the ecological debts on an ad hoc basis but does not offer a comprehensive solution. Enforceability measures are missing. 'We cannot even investigate the locations of ecological burdens as without new legislation we do not have access to production plants

  8. Pay, working conditions, and teacher quality.

    Science.gov (United States)

    Hanushek, Eric A; Rivkin, Steven G

    2007-01-01

    Eric Hanushek and Steven Rivkin examine how salary and working conditions affect the quality of instruction in the classroom. The wages of teachers relative to those of other college graduates have fallen steadily since 1940. Today, average wages differ little, however, between urban and suburban districts. In some metropolitan areas urban districts pay more, while in others, suburban districts pay more. But working conditions in urban and suburban districts differ substantially, with urban teachers reporting far less administrator and parental support, worse materials, and greater student problems. Difficult working conditions may drive much of the difference in turnover of teachers and the transfer of teachers across schools. Using rich data from Texas public schools, the authors describe in detail what happens when teachers move from school to school. They examine how salaries and student characteristics change when teachers move and also whether turnover affects teacher quality and student achievement. They note that both wages and student characteristics affect teachers' choices and result in a sorting of teachers across schools, but they find little evidence that teacher transitions are detrimental to student learning. The extent to which variations in salaries and working conditions translate into differences in the quality of instruction depends importantly on the effectiveness of school personnel policies in hiring and retaining the most effective teachers and on constraints on both entry into the profession and the firing of low performers. The authors conclude that overall salary increases for teachers would be both expensive and ineffective. The best way to improve the quality of instruction would be to lower barriers to becoming a teacher, such as certification, and to link compensation and career advancement more closely with teachers' ability to raise student performance.

  9. Equal Pay as a Moving Target: International perspectives on forty-years of addressing the gender pay gap

    OpenAIRE

    Jacqueline O’Reilly; Mark Smith; Simon Deakin; Brendan Burchell

    2015-01-01

    This paper provides an overview of the key factors impacting upon the gender pay gap in the UK, Europe and Australia. Forty years after the implementation of the first equal pay legislation, the pay gap remains a key aspect of the inequalities women face in the labour market. While the overall pay gap has tended to fall in many countries over the past forty years, it has not closed; in some countries it has been stubbornly resistant, or has even widened. In reviewing the collection of papers ...

  10. Hydrogen Production from Cyclic Chemical Looping Steam Methane Reforming over Yttrium Promoted Ni/SBA-16 Oxygen Carrier

    Directory of Open Access Journals (Sweden)

    Sanaz Daneshmand-Jahromi

    2017-09-01

    Full Text Available In this work, the modification of Ni/SBA-16 oxygen carrier (OC with yttrium promoter is investigated. The yttrium promoted Ni-based oxygen carrier was synthesized via co-impregnation method and applied in chemical looping steam methane reforming (CL-SMR process, which is used for the production of clean energy carrier. The reaction temperature (500–750 °C, Y loading (2.5–7.4 wt. %, steam/carbon molar ratio (1–5, Ni loading (10–30 wt. % and life time of OCs over 16 cycles at 650 °C were studied to investigate and optimize the structure of OC and process temperature with maximizing average methane conversion and hydrogen production yield. The synthesized OCs were characterized by multiples techniques. The results of X-ray powder diffraction (XRD and energy dispersive X-ray spectroscopy (EDX of reacted OCs showed that the presence of Y particles on the surface of OCs reduces the coke formation. The smaller NiO species were found for the yttrium promoted OC and therefore the distribution of Ni particles was improved. The reduction-oxidation (redox results revealed that 25Ni-2.5Y/SBA-16 OC has the highest catalytic activity of about 99.83% average CH4 conversion and 85.34% H2 production yield at reduction temperature of 650 °C with the steam to carbon molar ratio of 2.

  11. Jet-Fuel Range Hydrocarbons from Biomass-Derived Sorbitol over Ni-HZSM-5/SBA-15 Catalyst

    Directory of Open Access Journals (Sweden)

    Yujing Weng

    2015-12-01

    Full Text Available Aromatics and cyclic-hydrocarbons are the significant components of jet fuel with high energy-density. However, conventional technologies for bio-fuel production cannot produce these products without further aromatization and isomerization. In this work, renewable liquid fuel with high content of aromatics and cyclic-hydrocarbons was obtained through aqueous catalytic conversion of biomass sorbitol over Ni-HZSM-5/SBA-15 catalyst. Texture characteristics of the catalyst were determined by physisorption of N2, which indicated its bimodal pore structures were microporous (HZSM-5, pore width: 0.56 nm and mesoporous (SBA-15, pore width: 8 nm. The surface acidity included weak and strong acid sites, predominantly Lewis type, and was further confirmed by the NH3-TPD and Py-IR analysis. The catalytic performances were tested in a fixed-bed reactor under the conditions of 593 K, WHSV of 0.75 h−1, GHSV of 2500 h−1 and 4.0 MPa of hydrogen pressure, whereby oil yield of 40.4 wt. % with aromatics and cyclic-hydrocarbons content of 80.0% was obtained.

  12. Structural characterization of vanadium oxide catalysts supported on nanostructured silica SBA-15 using X-ray absorption spectroscopy

    Directory of Open Access Journals (Sweden)

    Walter Anke

    2010-02-01

    Full Text Available Abstract The local structure of vanadium oxide supported on nanostructured SiO2 (VxOy/SBA-15 was investigated by in situ X-ray absorption spectroscopy (XAS. Because the number of potential parameters in XAS data analysis often exceeds the number of "independent" parameters, evaluating the reliability and significance of a particular fitting procedure is mandatory. The number of independent parameters (Nyquist may not be sufficient. Hence, in addition to the number of independent parameters, a novel approach to evaluate the significance of structural fitting parameters in XAS data analysis is introduced. Three samples with different V loadings (i.e. 2.7 wt %, 5.4 wt %, and 10.8 wt % were employed. Thermal treatment in air at 623 K resulted in characteristic structural changes of the V oxide species. Independent of the V loading, the local structure around V centers in dehydrated VxOy/SBA-15 corresponded to an ordered arrangement of adjacent V2O7 units. Moreover, the V2O7 units were found to persist under selective oxidation reaction conditions.

  13. Gender inequality, gender pay gap, and pay inequity: Perceptions and reactions in Finnish society and workplaces

    OpenAIRE

    Khoreva, Violetta

    2012-01-01

    A growing awareness of gender inequality as well as a conviction that it should be eliminated has produced a number of studies aiming at uncovering its reasons. Much less attention has been given to the subjective dimension of how individuals perceive gender inequality. One of the main elements of gender inequality, the gender pay gap, has also received considerable attention by scholars all around the world. However, several researchers documented that their respondents did not perceive the...

  14. 75 FR 36451 - Data Collection Available for Public Comments and Recommendations

    Science.gov (United States)

    2010-06-25

    ... focused on the needs of small businesses and lenders. The SBA would like the new site to incorporate... business owners, and lenders to save time and money by providing them with tools to find information they... and specific to their needs. Without regular program information collections, SBA would be unable to...

  15. 76 FR 55720 - Data Collection Available for Public Comments and Recommendations

    Science.gov (United States)

    2011-09-08

    ... collection, to Felicia Smith, Supervisory Financial Analyst, Office of Credit Risk Management, Small Business... authorized under the Small Business Act to conduct off-site review and monitoring of SBA Lenders... performance of its oversight and monitoring functions. These plans will inform SBA how the lender intends to...

  16. 13 CFR 120.1015 - Risk Rating System.

    Science.gov (United States)

    2010-01-01

    ... Lender Oversight Supervision § 120.1015 Risk Rating System. (a) Risk Rating. SBA may assign a Risk Rating to all SBA Lenders, Intermediaries, and NTAPs on a periodic basis. Risk Ratings are based on certain... 13 Business Credit and Assistance 1 2010-01-01 2010-01-01 false Risk Rating System. 120.1015...

  17. 76 FR 13697 - Data Collection Available for Public Comments and Recommendations

    Science.gov (United States)

    2011-03-14

    ... used by the reporting participants and the SBA to assist with portfolio management, risk management...: Microloan Program Intermediary Lenders. Form Number: N/A. Annual Responses: 2,500. Annual Burden: 625... selected to partner with the SBA as Microloan Program Intermediary Lenders for the purpose of providing...

  18. Young tourists visiting strip clubs and paying for sex

    DEFF Research Database (Denmark)

    Hesse, Morten; Tutenges, Sébastien

    2011-01-01

    it for the first time. Among the men who attended strip clubs, 32% reported having done it for the first time. Stripclub patronage and paying for sex were both associated with higher levels of drinking, use of Viagra, and with having done the same thing before the holiday. Paying for sex was uniquely associated...

  19. Do Consumers Pay More Using Debit Cards than Cash

    DEFF Research Database (Denmark)

    Runnemark, Emma; Hedman, Jonas; Xiao, Xiao

    2015-01-01

    We conduct an incentivized experiment to study the effect of the payment method on spending. We find that the willingness to pay is higher when subjects pay with debit cards compared to cash. The result is robust to controlling for cash-on-hand constraints, spending type, price familiarity and co...

  20. Will Volunteers in a Youth Sports Event Become Paying Visitors?

    DEFF Research Database (Denmark)

    Mahadevan, Renuka; Ren, Carina Bregnholm

    2017-01-01

    This article explores possible factors that influence the willingness of volunteers to reattend as paying visitors. Using the 2016 Arctic Winter Games in Greenland as a case study, it was found that 47% of the volunteers were willing to reattend as paying visitors; some self-related benefits and ...

  1. Measurement Invariance of the Pay Satisfaction Questionnaire across Three Countries

    Science.gov (United States)

    Lievens, Filip; Anseel, Frederik; Harris, Michael M.; Eisenberg, Jacob

    2007-01-01

    In recent years, pay satisfaction has been increasingly studied in an international context, prompting the importance of examining whether the Pay Satisfaction Questionnaire (PSQ) is invariant across countries other than the United States. This study investigated the measurement invariance across three countries, namely, the United States (N =…

  2. Be vigilant, this government is coming after your pay.

    Science.gov (United States)

    Travis, Mike

    2016-02-10

    When chancellor George Osborne accepted what might have been a couple of luncheon vouchers from Google in payment of ten years' unpaid UK tax, the Department of Health submitted its evidence to the Pay Review Body in favour of extending 'plain time working' and introducing performance-related incremental pay progression.

  3. 5 CFR 531.215 - Setting pay upon demotion.

    Science.gov (United States)

    2010-01-01

    ... 5 Administrative Personnel 1 2010-01-01 2010-01-01 false Setting pay upon demotion. 531.215 Section 531.215 Administrative Personnel OFFICE OF PERSONNEL MANAGEMENT CIVIL SERVICE REGULATIONS PAY... termination of a temporary promotion. (1) When an employee is returned to the lower grade from which promoted...

  4. 31 CFR 321.10 - Responsibilities of paying agents.

    Science.gov (United States)

    2010-07-01

    ...) FISCAL SERVICE, DEPARTMENT OF THE TREASURY BUREAU OF THE PUBLIC DEBT PAYMENTS BY BANKS AND OTHER... of Authority § 321.10 Responsibilities of paying agents. (a) Payment of securities. A paying agent is... a customer, who can establish his or her identity as the owner or co-owner named on the securities...

  5. 76 FR 21221 - National Equal Pay Day, 2011

    Science.gov (United States)

    2011-04-15

    ... average than working men. Each year, National Equal Pay Day reflects how far into the current year women must work to match what men earned in the previous year. On National Equal Pay Day, we rededicate..., education, industry, and hours, this wage gap persists. Over the course of her lifetime, this gap will cost...

  6. Households willingness to pay for improved water quality and ...

    African Journals Online (AJOL)

    This survey investigated the willingness to pay for an improved water quality and reliability in Chobe ward in Maun. On average, 54% of the households are willing to pay for improved water quality. It is therefore apparent that Chobe Ward, Maun residents in general regard water as an economic good as they are willing to ...

  7. Cross-Country Evidence on Teacher Performance Pay

    Science.gov (United States)

    Woessmann, Ludger

    2011-01-01

    The general-equilibrium effects of performance-related teacher pay include long-term incentive and teacher-sorting mechanisms that usually elude experimental studies but are captured in cross-country comparisons. Combining country-level performance-pay measures with rich PISA-2003 international achievement micro data, this paper estimates…

  8. Shortchanged: The Hidden Costs of Lockstep Teacher Pay

    Science.gov (United States)

    TNTP, 2014

    2014-01-01

    Nobody goes into teaching to get rich, but that's no excuse not to pay teachers as professionals. Compensation is one of the most important factors in determining who enters the teaching profession and how long they stay--yet 90 percent of all U.S. school districts pay teachers without any regard for their actual performance with students,…

  9. Equal Pay for Equal Work; Women in Special Libraries.

    Science.gov (United States)

    Special Libraries Association, New York, NY.

    The Special Libraries Association (SLA) provides information on achieving equal pay for equal work for women librarians in special libraries. A 1973 SLA study is cited to show pay differences between men and women. Then relevant legislation and executive orders are listed for the United States, along with similar legislation for Canada. Attention…

  10. 77 FR 23595 - National Equal Pay Day, 2012

    Science.gov (United States)

    2012-04-20

    ... President, empowers women to recover wages lost to discrimination by extending the time period in which an...--regardless of the innovator's gender. On National Equal Pay Day, let us resolve to become a Nation that... injustice of wage discrimination, and join efforts to achieve equal pay. [[Page 23596

  11. Willingness to pay for fresh milk and associated marketing services ...

    African Journals Online (AJOL)

    ... in the willingness to pay for milk delivered to the doorstep. Consumers in the more endowed income group have a 32 per cent more willingness to pay for fresh milk brought to the local market or delivered at the doorstep. The results provide empirical basis for market strategy formation in the peri-urban milk marketing.

  12. Survey of pay satisfaction, job satisfaction and employee turnover in ...

    African Journals Online (AJOL)

    Survey of pay satisfaction, job satisfaction and employee turnover in selected business organisations in Lagos, Nigeria. ... Global Journal of Social Sciences ... The study was an attempt at investigating the relatedness of pay satisfaction, job satisfaction and employee turnover in business organizations in Lagos Nigeria.

  13. households' willingness to pay for restoring environmental resource

    African Journals Online (AJOL)

    Eyerusalem

    deforestation and over-exploitation of forest resource leads to low economic benefits, unsustainable .... Malaysia's canopy walkway are willing to pay about MYR7.61 for the entrance permit. The study concluded that .... Moreover, education, age, sex and family size turned out to be factors affecting the willingness to pay in ...

  14. Private Schools and the Willingness to Pay for Public Schooling

    Science.gov (United States)

    Brasington, David M.

    2007-01-01

    Households pay a premium to live in houses assigned to high quality public schools, and the housing market yields information about the demand for public school quality. The current study estimates a two-stage house price hedonic emphasizing the role that private schools play in the willingness to pay for public school quality. The elasticity of…

  15. 48 CFR 222.302 - Liquidated damages and overtime pay.

    Science.gov (United States)

    2010-10-01

    ... ACQUISITIONS Contract Work Hours and Safety Standards Act 222.302 Liquidated damages and overtime pay. Upon receipt of notification of Contract Work Hours and Safety Standards Act violations, the contracting... overtime pay. 222.302 Section 222.302 Federal Acquisition Regulations System DEFENSE ACQUISITION...

  16. Who pays for health care in Ghana?

    Directory of Open Access Journals (Sweden)

    McIntyre Diane

    2011-06-01

    Full Text Available Abstract Background Financial protection against the cost of unforeseen ill health has become a global concern as expressed in the 2005 World Health Assembly resolution (WHA58.33, which urges its member states to "plan the transition to universal coverage of their citizens". An important element of financial risk protection is to distribute health care financing fairly in relation to ability to pay. The distribution of health care financing burden across socio-economic groups has been estimated for European countries, the USA and Asia. Until recently there was no such analysis in Africa and this paper seeks to contribute to filling this gap. It presents the first comprehensive analysis of the distribution of health care financing in relation to ability to pay in Ghana. Methods Secondary data from the Ghana Living Standard Survey (GLSS 2005/2006 were used. This was triangulated with data from the Ministry of Finance and other relevant sources, and further complemented with primary household data collected in six districts. We implored standard methodologies (including Kakwani index and test for dominance for assessing progressivity in health care financing in this paper. Results Ghana's health care financing system is generally progressive. The progressivity of health financing is driven largely by the overall progressivity of taxes, which account for close to 50% of health care funding. The national health insurance (NHI levy (part of VAT is mildly progressive and formal sector NHI payroll deductions are also progressive. However, informal sector NHI contributions were found to be regressive. Out-of-pocket payments, which account for 45% of funding, are regressive form of health payment to households. Conclusion For Ghana to attain adequate financial risk protection and ultimately achieve universal coverage, it needs to extend pre-payment cover to all in the informal sector, possibly through funding their contributions entirely from tax, and

  17. Who pays for health care in Ghana?

    Science.gov (United States)

    2011-01-01

    Background Financial protection against the cost of unforeseen ill health has become a global concern as expressed in the 2005 World Health Assembly resolution (WHA58.33), which urges its member states to "plan the transition to universal coverage of their citizens". An important element of financial risk protection is to distribute health care financing fairly in relation to ability to pay. The distribution of health care financing burden across socio-economic groups has been estimated for European countries, the USA and Asia. Until recently there was no such analysis in Africa and this paper seeks to contribute to filling this gap. It presents the first comprehensive analysis of the distribution of health care financing in relation to ability to pay in Ghana. Methods Secondary data from the Ghana Living Standard Survey (GLSS) 2005/2006 were used. This was triangulated with data from the Ministry of Finance and other relevant sources, and further complemented with primary household data collected in six districts. We implored standard methodologies (including Kakwani index and test for dominance) for assessing progressivity in health care financing in this paper. Results Ghana's health care financing system is generally progressive. The progressivity of health financing is driven largely by the overall progressivity of taxes, which account for close to 50% of health care funding. The national health insurance (NHI) levy (part of VAT) is mildly progressive and formal sector NHI payroll deductions are also progressive. However, informal sector NHI contributions were found to be regressive. Out-of-pocket payments, which account for 45% of funding, are regressive form of health payment to households. Conclusion For Ghana to attain adequate financial risk protection and ultimately achieve universal coverage, it needs to extend pre-payment cover to all in the informal sector, possibly through funding their contributions entirely from tax, and address other issues

  18. Fluorescence properties of riboflavin-functionalized mesoporous silica SBA-15 and riboflavin solutions in presence of different metal and organic cations

    Science.gov (United States)

    Lewandowski, Dawid; Schroeder, Grzegorz; Sawczak, Mirosław; Ossowski, Tadeusz

    2015-10-01

    Riboflavin was covalently linked to mesoporous SBA-15 silica surface via grafting technique. Then fluorescence properties of the system obtained were analyzed in the presence of several metal and organic cations. Both quenching and strengthening of fluorescence as well as significant changes in the maximum fluorescence wavelength were observed. The results were compared with absorption and fluorescence data obtained for riboflavin water solutions.

  19. NiMo Catalysts Supported on the Nb Modified Mesoporous SBA-15 and HMS: Effect of Thioglycolic Acid Addition on HDS.

    Czech Academy of Sciences Publication Activity Database

    Palcheva, R.; Kaluža, Luděk; Dimitrov, L.; Tyuliev, G.; Avdeev, G.; Jirátová, Květa; Spojakina, A.

    2016-01-01

    Roč. 50, JUN 25 (2016), s. 24-34 ISSN 0926-860X R&D Projects: GA ČR GAP106/11/0902 Institutional support: RVO:67985858 Keywords : HDS * mesoporous SBA-15 and HMS * thioglycolic acid Subject RIV: CI - Industrial Chemistry, Chemical Engineering Impact factor: 4.339, year: 2016

  20. Direct synthesis of mesoporous molecular sieves of Ni-SBA-16 by internal pH adjustment method and its performance for adsorption of toxic Brilliant Green dye

    Directory of Open Access Journals (Sweden)

    Asma Tufail Shah

    2015-07-01

    Full Text Available An ordered mesoporous novel material Ni-SBA-16 has been synthesized by internal pH-adjustment method. The synthesized material has been characterized by small angle XRD (SXRD, wide angle XRD (WXRD, Scanning Electron Microscope (SEM, High-Resolution Transmission Electron Microscope (HRTEM, Fourier-transform Infra-red (FTIR spectroscope and Nitrogen Adsorption desorption techniques. The characterization results have shown that material possesses highly ordered mesostructure with high surface area (736 m2/g and large pore diameter (3.8 nm. FTIR and WXRD spectra revealed that nickel was uniformly dispersed on SBA-16 surface. The synthesized material has been used as adsorbent for removal of toxic Brilliant Green dye due to its large surface area and pore size. At optimized conditions, almost 100% of Brilliant Green dye was removed from aqueous solution by Ni-SBA-16. The isotherms analysis indicates that the Langmuir and Hill models provide the best correlation of the experimental data. The maximum adsorption capacity (qmax of Ni-SBA-16 for Brilliant Green dye was 322.58 mg/g.

  1. Encapsulated heterogeneous base catalysts onto SBA-15 nanoporous material as highly active catalysts in the transesterification of sunflower oil to biodiesel

    Energy Technology Data Exchange (ETDEWEB)

    Albayati, Talib M., E-mail: talib-albyati@yahoo.com [University of Technology, Department of Chemical Engineering (Iraq); Doyle, Aidan M., E-mail: a.m.doyle@mmu.ac.uk [Manchester Metropolitan University, Division of Chemistry and Environmental Science (United Kingdom)

    2015-02-15

    Alkali metals and their hydroxides, Na, NaOH, Li, and LiOH, were encapsulated onto SBA-15 nanoporous material as highly active catalysts for the production of biodiesel fuel from sunflower oil. The incipient wetness impregnation method was adopted for the prepared catalysts. The characterization properties of the catalysts and unmodified SBA-15 were determined using X-ray diffraction, scanning electron microscopy, EDAX, nitrogen adsorption–desorption porosimetry (Brunauer–Emmett–Teller), Fourier-transform infrared spectroscopy, and transmission electron microscopy. Transesterification was conducted in a batch reactor at atmospheric pressure and 65 °C. The catalysts were highly active with yields of fatty acid methyl ester (FAME) in the range 96–99 %. Na/SBA-15 catalyst was reused for seven consecutive cycles under the same reaction conditions; the yield to FAME on the final cycle was 96 %. This study shows that the alkali metals and their hydroxides supported on SBA-15-based catalyst are excellent catalysts for the biodiesel reaction.

  2. Controlled and localized delivery of c-myc AS-ODN to cells by 3-aminopropyl-trimethoxylsilane modified SBA-15 mesoporous silica

    Science.gov (United States)

    Zhang, Juan; Chen, Minmin; Zhao, Xiqiu; Zhang, Min; Mao, Jinxiang; Cao, Xichuan; Zhang, Zhuoqi

    2018-01-01

    SBA-15 mesoporous silicate was synthesized and functionalized with 3-aminopropyl organic groups through a post-synthesis method. The materials were characterized consecutively by powder X-ray diffraction (XRD), N2 adsorption/desorption analysis and solid-state magic-angle spinning 29Si nuclear magnetic resonance (MAS NMR). Human c-myc anti-sense oligodeoxyneucleotide (AS-ODN) was selected as a model molecule to be loaded onto the surface of bare and functionalized SBA-15 via different loading conditions. It has been found that the amount of AS-ODN incorporated into the porous matrix is strongly dependent on the surface properties, pH of the loading solvent and AS-ODN concentration. The release behaviour of AS-ODN from modified SBA-15 materials was also investigated and depended on conditions chosen. Cellular uptake of the eluted AS-ODN into Hela cells was observed by fluorescent microscopy. The materials showed excellent cytocompatibility. The AS-ODN keeps full transfection and expression activities indicating its structural integrity. The functionalized SBA-15 is an excellent prospect as a biomedical material candidate for the future.

  3. Encapsulated heterogeneous base catalysts onto SBA-15 nanoporous material as highly active catalysts in the transesterification of sunflower oil to biodiesel

    International Nuclear Information System (INIS)

    Albayati, Talib M.; Doyle, Aidan M.

    2015-01-01

    Alkali metals and their hydroxides, Na, NaOH, Li, and LiOH, were encapsulated onto SBA-15 nanoporous material as highly active catalysts for the production of biodiesel fuel from sunflower oil. The incipient wetness impregnation method was adopted for the prepared catalysts. The characterization properties of the catalysts and unmodified SBA-15 were determined using X-ray diffraction, scanning electron microscopy, EDAX, nitrogen adsorption–desorption porosimetry (Brunauer–Emmett–Teller), Fourier-transform infrared spectroscopy, and transmission electron microscopy. Transesterification was conducted in a batch reactor at atmospheric pressure and 65 °C. The catalysts were highly active with yields of fatty acid methyl ester (FAME) in the range 96–99 %. Na/SBA-15 catalyst was reused for seven consecutive cycles under the same reaction conditions; the yield to FAME on the final cycle was 96 %. This study shows that the alkali metals and their hydroxides supported on SBA-15-based catalyst are excellent catalysts for the biodiesel reaction

  4. LHCb: full-steam strategy pays off

    CERN Multimedia

    CERN Bulletin

    2011-01-01

    LHCb looks at LHC proton collisions from a special angle. The experiment studies rare decays of the B particle to look into the physical processes that might hide new physics. Designed to operate at moderate luminosity, LHCb has been more daring for the last year and is running at conditions tougher than the nominal. The new strategy is paying off, as important physics results have just started to emerge…   Event display presented at the EPS-HEP 2011 conference showing a B0s meson decaying into a μ+ and μ- pair.  The LHCb detector was originally designed to run at moderate luminosity and low interaction pile-up. In other words, unlike the CMS and ATLAS experiments, the whole LHCb experimental set-up and data-taking infrastructure was designed to process just one proton interaction for each bunch crossing. For the last year, however, this has all been old news. A change in LHCb strategy was made possible when it became clear that the LHC was going to first i...

  5. INDUSTRIAL BRANDING – DOES IT PAY OFF?

    Directory of Open Access Journals (Sweden)

    Anca BUTNARIU

    2017-12-01

    Full Text Available In a world characterized by the growth of global competition, a key question raised by business-to-business marketers is if brands in industrial markets really pay off, that is in which contexts and for what type of customers branding efforts are important and can bring competitive advantages for the companies owning those brands. The particularities and importance of branding in business has become a major field of scientific debate in the last years, but there are still questions unanswered and aspects unclear and under researched. Traditionally, B2B managers have been more skeptical about the benefits of branding, arguing that the organizational buying process is rational and focused on functional characteristics of the products and not based on the emotional values used in the B2C context. In this paper, we review the literature on brand equity in industrial markets and propose a synthetic conceptual model, with the purpose to shed more light on the issue of industrial branding.

  6. The New Urban Success: How Culture Pays

    Directory of Open Access Journals (Sweden)

    Desislava Hristova

    2018-04-01

    Full Text Available Urban economists have put forward the idea that cities that are culturally interesting tend to attract “the creative class” and, as a result, end up being economically successful. Yet it is still unclear how economic and cultural dynamics mutually influence each other. By contrast, that has been extensively studied in the case of individuals. Over decades, the French sociologist Pierre Bourdieu showed that people's success and their positions in society mainly depend on how much they can spend (their economic capital and what their interests are (their cultural capital. For the first time, we adapt Bourdieu's framework to the city context. We operationalize a neighborhood's cultural capital in terms of the cultural interests that pictures geo-referenced in the neighborhood tend to express. This is made possible by the mining of what users of the photo-sharing site of Flickr have posted in the cities of London and New York over 5 years. In so doing, we are able to show that economic capital alone does not explain urban development. The combination of cultural capital and economic capital, instead, is more indicative of neighborhood growth in terms of house prices and improvements of socio-economic conditions. Culture pays, but only up to a point as it comes with one of the most vexing urban challenges: that of gentrification.

  7. 5 CFR 9901.363 - Premium pay for health care personnel.

    Science.gov (United States)

    2010-01-01

    ... 5 Administrative Personnel 3 2010-01-01 2010-01-01 false Premium pay for health care personnel. 9901.363 Section 9901.363 Administrative Personnel DEPARTMENT OF DEFENSE HUMAN RESOURCES MANAGEMENT AND... NATIONAL SECURITY PERSONNEL SYSTEM (NSPS) Pay and Pay Administration Premium Pay § 9901.363 Premium pay for...

  8. Synthesis and Application of Cerium-Incorporated SBA-16 Supported Ni-Based Oxygen Carrier in Cyclic Chemical Looping Steam Methane Reforming

    Directory of Open Access Journals (Sweden)

    Maryam Meshksar

    2018-01-01

    Full Text Available Hydrogen, as a clean energy carrier, could be produced aided by cyclic oxidation-reduction of oxygen carriers (OCs in contact with carbonaceous fuel in chemical looping steam methane reforming (CL-SMR process. In this study, the cerium was incorporated into the SBA-16 support structure to synthesize the Ni/Ce-SBA-16 OC. The supports were synthesized using hydrothermal method followed by impregnation of Ni and characterized via low and wide angle X-ray diffraction (XRD, Brunauer-Emmett-Teller (BET, scanning electron microscopy (SEM, coupled with energy dispersive X-ray (EDX spectroscopy, and transmission electron micrograph (TEM techniques. In addition, the effect of various Si/Ce molar ratios (20–60 in the support structure, Ni loading (10–30 wt %, reaction temperature (500–750 °C, and life time of optimal oxygen carrier over 16 cycles were investigated. The results of wide angle XRD and SEM revealed that the incorporation of CeO2 in the channels of SBA-16 caused the formation of nickel metallic particles with smaller size and prevents the coke formation. The results showed that OC with 15 wt % Ni and Si/Ce molar ratio of 40 (15Ni/Ce-SBA-16(40 has the best performance when compared with other OCs in terms of catalytic activity and structural properties. The methane conversion of about 99.7% was achieved at 700 °C using 15Ni/Ce-SBA-16(40 OC. We anticipate that the strategy can be extended to investigate a variety of novel modified mesoporous silica as the supporting material for the Ni based OCs.

  9. The Multi-Template Molecularly Imprinted Polymer Based on SBA-15 for Selective Separation and Determination of Panax notoginseng Saponins Simultaneously in Biological Samples

    Directory of Open Access Journals (Sweden)

    Chenghong Sun

    2017-11-01

    Full Text Available The feasible, reliable and selective multi-template molecularly imprinted polymers (MT-MIPs based on SBA-15 (SBA-15@MT-MIPs for the selective separation and determination of the trace level of ginsenoside Rb1 (Rb1, ginsenoside Rg1 (Rg1 and notoginsenoside R1 (R1 simultaneously from biological samples were developed. The polymers were constructed by SBA-15 as support, Rb1, Rg1, R1 as multi-template, acrylamide (AM as functional monomer and ethylene glycol dimethacrylate (EGDMA as cross-linker. The new synthetic SBA-15@MT-MIPs were satisfactorily applied to solid-phase extraction (SPE coupled with high performance liquid chromatography (HPLC for the separation and determination of trace Rb1, Rg1 and R1 in plasma samples. Under the optimized conditions, the limits of detection (LODs and quantitation (LOQs of the proposed method for Rb1, Rg1 and R1 were in the range of 0.63–0.75 ng·mL−1 and 2.1–2.5 ng·mL−1, respectively. The recoveries of R1, Rb1 and Rg1 were obtained between 93.4% and 104.3% with relative standard deviations (RSDs in the range of 3.3–4.2%. All results show that the obtained SBA-15@MT-MIPs could be a promising prospect for the practical application in the selective separation and enrichment of trace Panax notoginseng saponins (PNS in the biological samples.

  10. Synthesis and characterization of nano structures of Silica SBA-16 containing Gadolinium-159 as potential nanoparticulated system for cancer therapy; Sintese e caracterizacao de nanoestruturas de Silica SBA-16 contendo Gadolinio-159 como potencial sistema nanoparticulado para o tratamento do cancer

    Energy Technology Data Exchange (ETDEWEB)

    Oliveira, Andre Felipe de

    2013-07-01

    Cancer is a leading cause of death worldwide, and malignant neoplasms of the lung, stomach, liver, colon and breast in greater numbers. And recently observed in the literature a large number of reviews where new materials, especially nanoparticle, has been studied as drug carriers and radioisotopes applied to cancer treatment. How mesoporous materials based on silica, thanks to its huge surface area and biocompatibility, have been studied intensively providing broad applications in various areas, the use of nanostructured silica SBA-16 might be a carrier specific radioisotope accumulate in the cells malignant. Thus the aim of this study is to develop in vitro studies using SBA-16 can selectively concentrate in malignant cells therapeutic amounts of the radioisotope Gadolinium-159 escorting them to death. This work was performed orderly synthesis of mesoporous silica, SBA-16 and incorporating the complex Gd-DTPA-BMA, as well as chemical and structural characterization. The techniques used to analyze the occurrence of the incorporation of the gadolinium complex in the silica matrix were elemental analysis (CHN), atomic emission spectroscopy (ICP-AES), infrared spectroscopy (FTIR), nitrogen adsorption (BET), small-angle X-ray scattering (SAXS) and thermogravimetric analysis (TG). To analyze the morphology of pure silica used the scanning electron microscopy (SEM) and transmission electron microscopy (TEM). By photon correlation spectroscopy (PCS) it was possible to obtain a measure of mean particle size, the polydispersity index (PDI) of the silica SBA-16, and the zeta potential by laser Doppler anemometry (LDA). The results of incorporation analyzed by ICP-AES indicated that the material SBA-16 had a higher rate of incorporation of gadolinium (93%). The release kinetics in simulated body fluid, showed considerable stability and low release (1%). The mesoporous silica SBA-16 showed cell viability in direct contact with cell culture. Samples with gadolinium

  11. Who Pays for Dates? Following Versus Challenging Gender Norms

    Directory of Open Access Journals (Sweden)

    Janet Lever

    2015-10-01

    Full Text Available Chivalry dictates that on a “date,” the man pays, whereas egalitarian ideals suggest that gender should not determine who pays. We examined the extent to which people embrace or reject these competing notions. Unmarried heterosexual participants (N = 17,607 reported their behaviors and attitudes regarding who does and who should pay for dates on a survey posted on NBCNews.com. Although most men (74% and women (83% report that both members of the couple contribute to dating expenses after dating for 6 months, most men (84% and women (58% reported that men still pay more expenses. Many women (39% wished men would reject their offers to pay and 44% of women were bothered when men expected women to help pay. Many women, however, were bothered when men won’t accept their money (40%. Nearly two thirds of men (64% believed that women should contribute and nearly half of men (44% said they would stop dating a woman who never pays. Nevertheless, the majority of men said they feel guilty when accepting women’s money (76%. These data illustrate how many people are resisting or conforming to traditional gender norms in one telling aspect of dating that historically was related to the male’s displaying benevolent sexism, dominance, and ability to fulfill breadwinner role during courtship.

  12. Take-or-Pay under Japanese energy policy

    International Nuclear Information System (INIS)

    Namikawa, Ryoichi

    2003-01-01

    Japan has tried to increase the import of liquefied natural gas (LNG) because of the nation's fragile energy supply structure. In Japan, almost all LNG is imported under long-term contracts with a Take-or-Pay clause, although buyers assume considerable risk under such a clause. This paper tries to determine why the Take-or-Pay clause has been retained in LNG import contracts in Japan, focusing on the relation between Take-or-Pay and energy security policy. It is found that the government has not pursued a consistent, consecutive policy on Take-or-Pay under the changing energy situation after oil crises. On the one hand, the government has accepted Take-or-Pay because it secures a stable supply of LNG, but on the other hand, it has tried to scrap Take-or-Pay in order to reduce buyers' risk. Furthermore, it was not until the middle/late 1990s that the government implemented deregulation. It is concluded that the government's energy security policy has played an important role in keeping Take-or-Pay in Japan

  13. Does it work? evaluating a new pay system

    OpenAIRE

    Corby, Susan; White, Geoff; Dennison, Paul; Douglas, Fiona

    2002-01-01

    This report focuses on the evaluation of the impact of new pay systems in large, unionised multi-site organisations by the organisations themselves. Evaluation of the effectiveness of a pay system, however, does not take place in a vacuum and relates to the aims and objectives of the pay system concerned. Moreover, evaluation is not an end in itself. It is, therefore, relevant to consider if any further steps were taken as a result of evaluation. Accordingly our research questions were:\\ud • ...

  14. Are Consumers Willing to Pay for Irradiated Foods

    International Nuclear Information System (INIS)

    Nayga, Rodolfo M. Jr.; Woodward, Richard; Aiew, Wipon

    2005-09-01

    This paper focuses on estimating willingness to pay for irradiated food using a non-hypothetical experiment utilizing real food products (i.e., ground beef), real cash, and actual exchange in a market setting. Single-bounded and one and one-half bounded models are developed using dichotomous choice experiments. Our results indicate that individuals are willing to pay for a reduction in the risk of food-borne illness once informed about the nature of food irradiation. Our respondents are willing to pay a premium of about $0.77 for a pound of irradiated ground beef, which is higher than the cost to irradiate the product

  15. Kinetics of Enantiomerically Enriched Synthesis of Solketal Esters Using Native and SBA-15 supported P. Fluorescens Lipase

    Directory of Open Access Journals (Sweden)

    Zniszczoł Aurelia

    2017-06-01

    Full Text Available The studies showed that alkaline lipase from Pseudomonas fluorescens enables an irreversible transesterification of vinyl esters to give enantiomeric excess (eeR of about 80% using vinyl butyrate as acyl donor and diisopropyl ether as a solvent, at partially optimized conditions. For the native lipase the process was adequately described by a five-parameter Ping-Pong Bi Bi model for both enantiomers plus expression accounting for the formation of enzyme-acyl donor complex, but for the same lipase supported on mesoporous materials of SBA-15-Oc type, R-product inhibition also had to be taken into account. The use of hydrophobic support increased by more than two-fold the rate of the S-solketal conversion but even more that of R-solketal. Thus the immobilization of lipase had very positive effect on the process kinetics but decreased its enantioselectivity.

  16. Iron oxide inside SBA-15 modified with amino groups as reusable adsorbent for highly efficient removal of glyphosate from water

    Science.gov (United States)

    Fiorilli, Sonia; Rivoira, Luca; Calì, Giada; Appendini, Marta; Bruzzoniti, Maria Concetta; Coïsson, Marco; Onida, Barbara

    2017-07-01

    Iron oxide clusters were incorporated into amino-functionalized SBA-15 in order to obtain a magnetically recoverable adsorbent. The physical-chemical properties of the material were characterized by FE-SEM, STEM, XRD, TGA, XPS, FT-IR and acid-base titration analysis. Iron oxide nanoparticles were uniformly dispersed into the pore of mesoporous silica and that the adsorbent is characterized high specific surface area (177 m2/g) and accessible porosity. The sorbent was successfully tested for the removal of glyphosate in real water matrices. Despite the significant content of inorganic ions, a quantitative removal of the contaminant was found. The complete regeneration of the sorbent after the adsorption process through diluted NaOH solution was also proved.

  17. Silicon oxynitrides of KCC-1, SBA-15 and MCM-41 for CO 2 capture with excellent stability and regenerability

    KAUST Repository

    Patil, Umesh

    2012-01-01

    We report the use of silicon oxynitrides as novel adsorbents for CO 2 capture. Three series of functionalized materials based on KCC-1, SBA-15 and MCM-41 with Si-NH 2 groups were prepared using a simple one-step process via thermal ammonolysis using ammonia gas, and they demonstrated excellent CO 2 capture capabilities. These materials overcome several limitations of conventional amine-grafted mesoporous silica. They offer good CO 2 capture capacity, faster adsorption-desorption kinetics, efficient regeneration and reuse, more crucially excellent thermal and mechanical stability even in oxidative environments, and a clean and green synthesis route, which allows the overall CO 2 capture process to be practical and sustainable. This journal is © The Royal Society of Chemistry 2012.

  18. 76 FR 9626 - Community Advantage Pilot Program

    Science.gov (United States)

    2011-02-18

    ...-based, mission lenders, will mitigate the risks associated with lending in these markets, reduce losses... LLRA based on the risk characteristics and performance of the CA Lender. SBA microloan intermediaries.../sops/index.html .) CA Lenders will be monitored both for performance and other risk characteristics as...

  19. 75 FR 20870 - Data Collection Available for Public Comments and Recommendations

    Science.gov (United States)

    2010-04-21

    ... forms from lenders and borrowers to carry out its loan monitoring portfolio risk management, and lender... reporting participants and the SBA to assist with portfolio management, risk management, loan servicing and... Program Intermediary Lenders. Form Number: N/A, Annual Responses: 2,500, Annual Burden: 625 Addresses...

  20. 13 CFR 120.1060 - Confidentiality of Reports, Risk Ratings and related Confidential Information.

    Science.gov (United States)

    2010-01-01

    ... SMALL BUSINESS ADMINISTRATION BUSINESS LOANS Risk-Based Lender Oversight Supervision § 120.1060... Lender, Intermediary, or NTAP for its confidential use only. The Reports, Risk Ratings, and related... written permission. An SBA Lender, Intermediary, and NTAP may use the Report, Risk Rating, and...

  1. 77 FR 67433 - Community Advantage Pilot Program

    Science.gov (United States)

    2012-11-09

    ... market loan sales create a direct risk to SBA. The total cash reserve required for CA Lenders needs to be... projected purchase rates, and risk rating for each lender. OCRM will also review compliance with the cash..., Office of Credit Risk Management, discretion to suspend secondary market authority for any CA Lender...

  2. Hydrothermal and postsynthesis surface modification of cubic, MCM-48, and ultralarge pore SBA-15 mesoporous silica with titanium

    Energy Technology Data Exchange (ETDEWEB)

    Morey, M.S.; O' Brien, S.; Schwarz, S.; Stucky, G.D.

    2000-04-01

    The authors describe the introduction of titanium centers to cubic MCM-48 was hydrothermally prepared with a gemini surfactant that favors the cubic phase and leads to a high degree of long-range pore ordering. This phase was chosen due to its high surface area (1100--1300 m{sup 2}/g) and its three-dimensional, bicontinuous pore array. SBA-15, synthesized with a block copolymer template under acidic conditions, has a surface area from 600 to 900 m{sup 2}/g and an average pore diameter of 69 {angstrom}, compared to 24--27 {angstrom} for MCM-48. Alkoxide precursors of titanium were used to prepare samples of Ti-MCM-48 and Ti-SBA-15. The authors have detailed the bulk and molecular structure of both the silica framework and the local bonding environment of the titanium ions within each matrix. X-ray powder diffraction and nitrogen adsorption shows the pore structure is maintained despite some shrinkage of the pore diameter at high Ti loadings by grafting methods. UV-visible and Raman spectroscopy indicate that grafting produces the least amount of Ti-O-Ti bonds and instead favors isolated tetrahedral and octahedral titanium centers. High-resolution photoacoustic FTIR spectra demonstrated the presence of intermediate range order within the silicate walls of MCM-48, established the consumption of surface silanols to form Si-O-Ti bonds by grafting, and resolved the characteristic IR absorbance at 960 cm{sup {minus}1}, occurring in titanium silicates, into two components. All three spectroscopic techniques, including in situ Raman, reveal the reactive intermediates formed when the materials are contacted with hydrogen peroxide.

  3. Structural aspects of graphitic carbon modified SBA-15 mesoporous silica and biological interactions with red blood cells and plasma proteins.

    Science.gov (United States)

    Martinez, Diego S T; Damasceno, João Paulo V; Franqui, Lidiane S; Bettini, Jefferson; Mazali, Italo O; Strauss, Mathias

    2017-09-01

    Functional mesoporous materials have been worldwide studied for different applications. Mesoporous silicas are highlighted due to the synthetic possibilities for the preparation of such materials with different particle sizes and morphologies, and controlled pores sizes and structures. Moreover, the silica superficial silanol groups are explored in several chemical modifications, leading to functional materials with tuned functionalities and properties. In this work, an organo-functionalization and pyrolysis synthetic procedure is used to obtain graphitic carbon modified mesoporous SBA-15 silica. The carbon content was tuned during the functionalization step, and the graphitic nanodomains were formed in the pores surface and particles outer surface. Textural and small angle X-ray diffraction analysis accessed the presence of the carbon nanostructures inside the SBA-15 mesopores. Advanced microanalysis using electron energy loss spectroscopy coupled to a transmission electron microscope had confirmed the carbon distribution along the silica pores, which gives higher hydrophobicity and changed the interaction of the mesoporous material with biological systems. Finally, the influence of the surface modification with graphitic carbon species over the interaction with human red blood cells (hemolysis) and human blood plasma (protein corona formation) was elucidated for the very first time for this kind of functional materials. It was observed that the graphitic carbon species considerably reduced the hemolytic effect of the silica particles, and was responsible for modulating the loading and composition of the hard corona plasma proteins. This work deepness the fundamental knowledge on the interaction between such nanomaterials and biological systems, one step further the use of these modified silicas in biomedical applications. Copyright © 2017 Elsevier B.V. All rights reserved.

  4. 5 CFR 9701.335 - Eligibility for pay increase associated with a supplement adjustment.

    Science.gov (United States)

    2010-01-01

    ... SECURITY HUMAN RESOURCES MANAGEMENT SYSTEM (DEPARTMENT OF HOMELAND SECURITY-OFFICE OF PERSONNEL MANAGEMENT) DEPARTMENT OF HOMELAND SECURITY HUMAN RESOURCES MANAGEMENT SYSTEM Pay and Pay Administration Locality and...

  5. 5 CFR 9701.323 - Eligibility for pay increase associated with a rate range adjustment.

    Science.gov (United States)

    2010-01-01

    ... SECURITY HUMAN RESOURCES MANAGEMENT SYSTEM (DEPARTMENT OF HOMELAND SECURITY-OFFICE OF PERSONNEL MANAGEMENT) DEPARTMENT OF HOMELAND SECURITY HUMAN RESOURCES MANAGEMENT SYSTEM Pay and Pay Administration Setting and...

  6. 5 CFR 9901.334 - Eligibility for pay increase associated with a supplement adjustment.

    Science.gov (United States)

    2010-01-01

    ... HUMAN RESOURCES MANAGEMENT AND LABOR RELATIONS SYSTEMS (DEPARTMENT OF DEFENSE-OFFICE OF PERSONNEL MANAGEMENT) DEPARTMENT OF DEFENSE NATIONAL SECURITY PERSONNEL SYSTEM (NSPS) Pay and Pay Administration Local...

  7. Helping patients struggling to pay their prescription charges.

    Science.gov (United States)

    Clark, Christine

    2015-01-27

    In his latest column on Medicines Management (Reflections January 7), Matt Griffiths responds to the question: 'I have patients who are struggling to pay their prescription charges. Is there anything I can do to help?'

  8. 75 FR 21155 - National Equal Pay Day, 2010

    Science.gov (United States)

    2010-04-23

    ... Americans are women, yet they earn only about 80 cents for every dollar men earn. This gap increases among..., helps women achieve wage fairness. This law brings us closer to ending pay disparities based on gender...

  9. Pay as You Speed, ISA with incentive for not speeding

    DEFF Research Database (Denmark)

    Lahrmann, Harry Spaabæk; Agerholm, Niels; Tradisauskas, Nerius

    2012-01-01

    To simulate a market introduction of Intelligent Speed Adaptation (ISA) and to study the effect of a Pay as You Speed (PAYS) concept, a field trial with 153 drivers was conducted during 2007–2009. The participants drove under PAYS conditions for a shorter or a longer period. The PAYS concept...... consisted of informative ISA linked with economic incentive for not speeding, measured through automatic count of penalty points whenever the speed limit was exceeded. The full incentive was set to 30% of a participant's insurance premium. The participants were exposed to different treatments......, with and without incentive crossed with informative ISA present or absent. The results showed that ISA is an efficient tool for reducing speeding particularly on rural roads. The analysis of speed data demonstrated that the proportion of distance driven above the speed where the ISA equipment responded (PDA...

  10. Willingness to pay for rural telephone services: Implications for rural ...

    African Journals Online (AJOL)

    WTP) for rural telephone services and the implications on poverty reduction in Southeast Nigeria. The key research problem was the inability of the telephone providers or regulatory agencies to estimate the amount the people were willing to pay ...

  11. Gender, Pay and Job Satisfaction of Faculty in Journalism.

    Science.gov (United States)

    Kelly, James D.

    1989-01-01

    Examines gender-based differences in job satisfaction among faculty in journalism and mass communication. Finds that women faculty members receive less pay but have the same degree of job satisfaction as men. (RS)

  12. Drivers willingness to pay progressive rate for street parking.

    Science.gov (United States)

    2015-01-01

    This study finds willingness to pay and price elasticity for on-street parking demand using stated : preference data obtained from 238 respondents. Descriptive, statistical and economic analyses including : regression, generalized linear model, and f...

  13. The Effect of Nitrogen Surface Ligands on Propane Metathesis: Design and Characterizations of N-modified SBA15-Supported Schrock-type Tungsten Alkylidyne

    KAUST Repository

    Eid, Ahmed A.

    2014-04-01

    Catalysis, which is primarily a molecular phenomenon, is an important field of chemistry because it requires the chemical conversion of molecules into other molecules. It also has an effect on many fields, including, but not limited to, industry, environment and life Science[1]. Surface Organometallic Chemistry is an effective methodology for Catalysis as it imports the concept and mechanism of organometallic chemistry, to surface science and heterogeneous catalysis. So, it bridges the gap between homogenous and heterogeneous catalysis[1]. The aim of the present research work is to study the effect of Nitrogen surface ligands on the activity of Alkane, Propane in particular, metathesis. Our approach is based on the preparation of selectively well-defined group (VI) transition metal complexes supported onto mesoporous materials, SBA15 and bearing amido and/or imido ligands. We choose nitrogen ligands because, according to the literature, they showed in some cases better catalytic properties in homogenous catalysis in comparison with their oxygen counterparts[2]. The first section covers the modification of a highly dehydroxylated SBA15 surface using a controlled ammonia treatment. These will result in the preparation of two kind of Nitrogen surface ligands: -\\tOne with vicinal silylamine/silanol, (≡SiNH2)(≡SiOH), noted [N,O]SBA15 and, -\\tAnother\\tone\\twith\\tvicinal\\tbis-silylamine moieties (≡SiNH2)2, noted [N,N]SBA15[3]. The second section covers the reaction of Schrock type Tungsten Carbyne [W(≡C- tBu)(CH2-tBu)3] with those N-surface ligands and their characterizations by FT-IR, multiple quantum solid state NMR (1H, 13C), elemental analysis and gas phase analysis. The third section covers the generation of the active site, tungsten hydride species. Their performance toward propane metathesis reaction using the dynamic reactor technique PID compared toward previous well-known catalysts supported on silica oxide or mesoporous materials[4]. A fairly good

  14. An Analysis of Merit Pay Reforms in Educational Institutions

    Directory of Open Access Journals (Sweden)

    Andrew Brulle

    2006-05-01

    Full Text Available With roots in behaviorist philosophy, performance pay for teachers is often linked to accountability regimes in school reform. The theory girding such programs suggests that pay as an economic incentive can help cause teachers to increase student outcomes as measured by standardized test scores. What is little noticed by many educationists, but particularly by policy makers, is how programmatic effects affect the ontology of educational environment. There are several ways to approach the viability of such programs. In this study of three pay-for-performance programs, two in the U.S. and one in the UK, we provide theoretic insights in light of three variables: (i their psychological framework, (ii teacher efficacy and the teacher-student relationship, and (iii how the psychological impact of such programs coincides with larger institutional forces. Using theory to examine pay-for-performance is necessary in order to get beneath mere data and secure more thorough understandings of the phenomenological impacts of performance pay. And better understanding of these foundational features is necessary, even critical, in order to fully appreciate the economic and informational trade-offs in implementation. Our study suggests that as a small-scale reform measure and when it specifically accounts for complexities of educational production, performance pay may be a viable reform option.

  15. Searching for Determinants of Pay or Not to Pay Cash Dividend in Indonesia

    Directory of Open Access Journals (Sweden)

    Triasesiarta Nur

    2014-01-01

    Full Text Available Normal 0 false false false EN-US X-NONE X-NONE /* Style Definitions */ table.MsoNormalTable {mso-style-name:"Table Normal"; mso-tstyle-rowband-size:0; mso-tstyle-colband-size:0; mso-style-noshow:yes; mso-style-priority:99; mso-style-qformat:yes; mso-style-parent:""; mso-padding-alt:0in 5.4pt 0in 5.4pt; mso-para-margin-top:0in; mso-para-margin-right:0in; mso-para-margin-bottom:10.0pt; mso-para-margin-left:0in; line-height:115%; mso-pagination:widow-orphan; font-size:11.0pt; font-family:"Calibri","sans-serif"; mso-ascii-font-family:Calibri; mso-ascii-theme-font:minor-latin; mso-fareast-font-family:"Times New Roman"; mso-fareast-theme-font:minor-fareast; mso-hansi-font-family:Calibri; mso-hansi-theme-font:minor-latin;} A dividend decision of a firm is an outcome of various considerations. These considerations differ across time and industry. Based on asymetric information – agency theory thougtht, this study re-examined various variables that have a bearing on the dividend decision of a firm. In addition to examining the impact of corporate fundamentals on  dividend policy, the study also analyzed the effect of expropriation trigger variables (family ownership, cash funds, the level of diversification and Related Party Transaction/RPT on a dividend policy. The results of panel logistic regression indicated that Cash Funds, RPT, Profitability, Size, Growth, Debt and Macroecomics variables are the determinants of the dividend policy for Indonesian listed public companies, observed during 2002 to 2010.   Keywords: dividend policy-pay and not pay cash dividend, expropriation, asymmetry information, agency theory,  family ownership, cash funds, level of diversification, related party transaction, panel data analysis.

  16. High surface area Au-SBA-15 and Au-MCM-41 materials synthesis: tryptophan amino acid mediated confinement of gold nanostructures within the mesoporous silica pore walls.

    Science.gov (United States)

    Selvakannan, Pr; Mantri, Kshudiram; Tardio, James; Bhargava, Suresh K

    2013-03-15

    Advantages of confining the gold nanostructures formation within the mesoporous silica pore walls during its silica condensation and consequent improvement in the textural properties such as specific surface area, pore volume, pore diameter have been demonstrated, while retaining gold nanostructures within the silica walls. This has been achieved by tryptophan mediated confinement of gold nanoparticles formation within the condensing silica framework, to obtain Au-SBA-15 (SSA 1247 m(2)/g, V(t)~1.37 cm(3)/g) and Au-MCM-41 (SSA 1287 m(2)/g, V(t)~1.1 cm(3)/g), mesoporous silica materials having the combination of very high surface area from the porous support as well as gold nanoparticles infiltrated silica walls. Choice of tryptophan for this purpose is that it has an indole group, which was known to reduce gold ions to form gold nanoparticles and its amine and carboxylic acid groups, catalyze the hydrolysis of silica precursors in a wide range of pH. These properties have been utilized in restricting the gold nanostructures formation inside the condensing silica phase without affecting the self assembly between the silica precursors and the triblock copolymer (for SBA-15) or cetyltrimethylammonium bromide template (for MCM-41). The polytryptophan and the gold nanostructures, which were encapsulated within the silica framework and upon removal of the template by calcination resulting in the formation mesoporous materials wherein the silica walls become microporous due to the removal of occluded polytryptophan and the resulting microchannels contain very small gold nanostructures. Hence, the resulting materials have very high surface area, high pore volume and narrow pore size distribution as compared to their parent SBA-15, MCM-41 and SBA-15, MCM-41 post functionalized with gold nanoparticles inside the pores. Copyright © 2012 Elsevier Inc. All rights reserved.

  17. Preparation of Al-SBA-15 Pellets with Low Amount of Additives: Effect of Binder Content on Texture and Mechanical Properties. Application to Friedel-Crafts Alkylation

    Czech Academy of Sciences Publication Activity Database

    Topka, Pavel; Karban, Jindřich; Soukup, Karel; Jirátová, Květa; Šolcová, Olga

    2011-01-01

    Roč. 168, č. 1 (2011), s. 433-440 ISSN 1385-8947 R&D Projects: GA ČR GA104/09/0694; GA AV ČR KAN400720701 Institutional research plan: CEZ:AV0Z40720504 Keywords : mesoporous aluminosilicates * pellets * Al-SBA-15 Subject RIV: CI - Industrial Chemistry, Chemical Engineering Impact factor: 3.461, year: 2011

  18. Amine-modified SBA-15 and MCF mesoporous molecular sieves as promising sorbents for natural antioxidant. Modeling of caffeic acid adsorption.

    Science.gov (United States)

    Moritz, Michał; Geszke-Moritz, Małgorzata

    2016-04-01

    This work presents a detailed study of caffeic acid adsorption on mesoporous SBA-15 and MCF silicas functionalized with (3-aminopropyl)triethoxysilane (APTES) and 3-[2-(aminoethylamino)propyl]trimethoxysilane (AEAPTMS). Synthesized mesoporous adsorbents were characterized using different analytical techniques such as N2 sorption, XRD, TEM, SEM and FT-IR. The adsorption studies of caffeic acid were conducted in various organic solvents. Moreover, the effect of water content in 2-propanol-water mixture on adsorption efficiency was investigated. The experimental data were best fitted to the Langmuir equation, followed by the Temkin, Dubinin-Radushkevich and Freundlich models. The maximum adsorption capacity values calculated from the Langmuir model demonstrated that SBA-15 and MCF silicas modified with AEAPTMS revealed better adsorption properties toward caffeic acid (192.3 and 161.3mg/g, respectively) as compared to the materials modified with APTES (125.0 and 113.6 mg/g, respectively). The obtained results indicate that both SBA-15 and MCF silicas functionalized with AEAPTMS and APTES are promising materials for the entrapment of caffeic acid. Copyright © 2015 Elsevier B.V. All rights reserved.

  19. Atomic-Level Organization of Vicinal Acid-Base Pairs through the Chemisorption of Aniline and Derivatives onto Mesoporous SBA15

    KAUST Repository

    Basset, Jean-Marie

    2016-06-09

    The design of novel heterogeneous catalysts with multiple adjacent functionalities is of high interest for heterogeneous catalysis. Herein, we report a method to obtain a majority bifunctional acid-base pairs on SBA15. Aniline reacts with SBA15 by opening siloxane bridges leading to N-phenylsilanamine-silanol pairs. In contrast with ammonia treated surfaces, the material is stable under air/moisture. Advanced solid state MAS NMR: 2D ¹H-¹H double-quantum, ¹H-¹³C HETCOR experiments and dynamic nuclear polarization enhanced ²⁹Si and ¹⁵N spectra demonstrate both the close proximity between the two moieties and the formation of a covalent Si-N surface bond and confirm the design of vicinal acid-base pairs. This approach was successfully applied to the design of a series of aniline derivatives bifunctional SBA15. A correlation of the substituents effects on the aromatic ring (Hammet parameters) on the kinetics of the model reaction of Knoevenagel is observed.

  20. Incorporation of nanoscale zero-valent iron particles inside the channels of SBA-15 silica rods by a “two solvents” reduction technique

    Energy Technology Data Exchange (ETDEWEB)

    Sun, Xia [School of Environmental and Biological Engineering, Nanjing University of Science and Technology, Nanjing 210094 (China); School of Chemistry and Chemical Engineering, Huaihai Institute of Technology, Lian yungang 222005 (China); Yu, Hongxia; Zheng, Da [School of Environmental and Biological Engineering, Nanjing University of Science and Technology, Nanjing 210094 (China); Wang, Xuesong [School of Chemistry and Chemical Engineering, Huaihai Institute of Technology, Lian yungang 222005 (China); Li, Jiansheng, E-mail: lijsh@mail.njust.edu.cn [School of Environmental and Biological Engineering, Nanjing University of Science and Technology, Nanjing 210094 (China); Wang, Lianjun, E-mail: wanglj@mail.njust.edu.cn [School of Environmental and Biological Engineering, Nanjing University of Science and Technology, Nanjing 210094 (China)

    2013-08-15

    A new reduction method named a “two solvents” reduction technique was developed for incorporation of nanoscale zero-valent iron particles (NZVIs) inside the channels of SBA-15 silica rods under mild conditions. The resulting NZVIs/SBA-15 composites were compared with the ones prepared by the conventional liquid phase reduction method in structure, morphology and reactivity. All the samples were characterized by X-ray diffraction (XRD), N{sub 2} adsorption–desorption isotherms, transmission electron microscopy (TEM) and all-direct-reading plasma atomic emission spectrometry (ICP-AES). Results showed that abundant ultrasmall zero-valent iron particles were synthesized and well dispersed in the mesopores of SBA-15 silica rods by the new reduction technique, whereas larger iron particles were supported and aggregated on the surface of the silica rods by conventional reduction method. Batch experiment demonstrated that NZVIs incorporated inside the silica channels had higher reactivity for the removal of Cr(VI) in aqueous solution than those supported on the surface.

  1. 27 CFR 70.96 - Failure to file tax return or to pay tax.

    Science.gov (United States)

    2010-04-01

    ... or to pay tax. 70.96 Section 70.96 Alcohol, Tobacco Products and Firearms ALCOHOL AND TOBACCO TAX AND... Assessable Penalties § 70.96 Failure to file tax return or to pay tax. (a) Addition to the tax—(1) Failure to...) of this section. (2) Failure to pay tax shown on return. In case of failure to pay the amount shown...

  2. 27 CFR 24.274 - Failure to timely pay tax or file a return.

    Science.gov (United States)

    2010-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2010-04-01 2010-04-01 false Failure to timely pay tax... Taxpaid Removals § 24.274 Failure to timely pay tax or file a return. Penalties for failure to pay tax at the time required, for willful refusal to pay the tax and for fraudulent nonpayment of tax are...

  3. 29 CFR 4.181 - Overtime pay provisions of other Acts.

    Science.gov (United States)

    2010-07-01

    ... overtime pay standards of the Fair Labor Standards Act. This is true with respect to employees engaged in... 29 Labor 1 2010-07-01 2010-07-01 true Overtime pay provisions of other Acts. 4.181 Section 4.181... Standards Overtime Pay of Covered Employees § 4.181 Overtime pay provisions of other Acts. (a) Fair Labor...

  4. 5 CFR 9901.355 - Setting pay upon reduction in band.

    Science.gov (United States)

    2010-01-01

    ... 5 Administrative Personnel 3 2010-01-01 2010-01-01 false Setting pay upon reduction in band. 9901.355 Section 9901.355 Administrative Personnel DEPARTMENT OF DEFENSE HUMAN RESOURCES MANAGEMENT AND... NATIONAL SECURITY PERSONNEL SYSTEM (NSPS) Pay and Pay Administration Pay Administration § 9901.355 Setting...

  5. 5 CFR 9901.372 - Conversion or movement out of NSPS pay system.

    Science.gov (United States)

    2010-01-01

    ... system. 9901.372 Section 9901.372 Administrative Personnel DEPARTMENT OF DEFENSE HUMAN RESOURCES... DEFENSE NATIONAL SECURITY PERSONNEL SYSTEM (NSPS) Pay and Pay Administration Conversion Provisions § 9901... established under this paragraph (d) will be used in applying GS pay administration rules in setting pay in...

  6. 78 FR 28717 - Advancing Pay Equality in the Federal Government and Learning From Successful Practices

    Science.gov (United States)

    2013-05-15

    ... address any gender pay gap in the Federal workforce. This strategy shall include: (a) analysis of whether changes to the General Schedule classification system would assist in addressing any gender pay gap; (b... narrow any gender pay gap. Sec. 2. Agency Review of Pay and Promotion Policies and Practices. To...

  7. 29 CFR 1620.20 - Pay differentials claimed to be based on extra duties.

    Science.gov (United States)

    2010-07-01

    ... COMMISSION THE EQUAL PAY ACT § 1620.20 Pay differentials claimed to be based on extra duties. Additional... of the higher paid sex receive the higher pay without doing the extra work; (b) Members of the lower... 29 Labor 4 2010-07-01 2010-07-01 false Pay differentials claimed to be based on extra duties. 1620...

  8. 5 CFR 610.407 - Premium pay for holiday work for employees on compressed work schedules.

    Science.gov (United States)

    2010-01-01

    ... pay for holiday work for employees on compressed work schedules. (a) An employee on a compressed schedule who performs work on a holiday is entitled to basic pay, plus premium pay at a rate equal to basic... 5 Administrative Personnel 1 2010-01-01 2010-01-01 false Premium pay for holiday work for...

  9. 5 CFR 534.404 - Setting and adjusting pay for senior executives.

    Science.gov (United States)

    2010-01-01

    ... transparency in the processes for making pay decisions, while assuring confidentiality. In developing its plan... 5 Administrative Personnel 1 2010-01-01 2010-01-01 false Setting and adjusting pay for senior... REGULATIONS PAY UNDER OTHER SYSTEMS Pay and Performance Awards Under the Senior Executive Service § 534.404...

  10. 5 CFR 536.307 - Treatment of a retained rate as basic pay for other purposes.

    Science.gov (United States)

    2010-01-01

    ... 5 Administrative Personnel 1 2010-01-01 2010-01-01 false Treatment of a retained rate as basic pay... CIVIL SERVICE REGULATIONS GRADE AND PAY RETENTION Pay Retention § 536.307 Treatment of a retained rate... for accumulated and annual leave under 5 CFR part 550, subpart L; (8) General Schedule pay...

  11. Nursing Gender Pay Differentials in the New Millennium.

    Science.gov (United States)

    Wilson, Barbara L; Butler, Matthew J; Butler, Richard J; Johnson, William G

    2018-01-01

    The gender pay gap in the United States is an ongoing issue, affecting women in nearly all occupations. Jobs traditionally associated with men tend to pay better than traditionally female-dominated jobs, and there is evidence to suggest within-occupation gender pay differences as well. We compared and contrasted gender wage disparities for registered nurses (RNs), relative to gender wage disparities for another female-dominated occupation, teachers, while controlling for sociodemographic factors. Using data in the American Community Survey, we analyzed the largest U.S. random representative sample of self-identified RNs and primary or secondary school teachers from 2000 to 2013 using fixed-effects regression analysis. There is greater disparity between nurse pay by gender than in teacher pay by gender. In addition, the net return in wages for additional education is higher for school teachers (21.7%) than for RNs (4.7%). Findings support preferential wages for men in nursing, more so than for men in teaching. The substantial gender disparities are an indirect measure of the misallocation of resources in effective patient care. © 2017 Sigma Theta Tau International.

  12. Are Tourists Really Willing to Pay More for Sustainable Destinations?

    Directory of Open Access Journals (Sweden)

    Juan Ignacio Pulido-Fernández

    2016-11-01

    Full Text Available The understanding of pro-sustainable behavior and its true economic implications is an important subject for tourism destination marketers and policymakers, especially given that limited research has focused on the economic implications of tourist preferences for more sustainable destinations. Following the identification of three different demand segments using the concept of “sustainable intelligence” (level of commitment, attitude, knowledge and/or behavior with regard to sustainability, this study hypothesizes that the tourist segment with high level of “sustainable intelligence” (called “pro-sustainable tourist” is willing to pay more to visit a more sustainable destination. The main aim of this paper is to use the logistic regression model to estimate the premium price that each segment is willing to pay to visit a sustainable destination. This paper reports the result of a willingness to pay study using data from 1118 respondents visiting the Western Costa del Sol (Andalusia, Spain, a mature sun-and-sand destination that is currently facing several developmental challenges supposedly associated with sustainability. The results obtained from this research study indicate that the tourist segment with high levels of “sustainable intelligence” is willing to pay more to visit a more sustainable tourism destination. However, there is little willingness to pay if the destination’s commitment to sustainability increases the price of the tourism product (26.6% of respondents.

  13. Reactions to merit pay increases: a longitudinal test of a signal sensitivity perspective.

    Science.gov (United States)

    Shaw, Jason D; Duffy, Michelle K; Mitra, Atul; Lockhart, Daniel E; Bowler, Matthew

    2003-06-01

    The relationships among merit pay raises, trait positive affectivity (PA), and reactions to merit pay increases (pay attitudes and behavioral intentions) were explored in a longitudinal study of hospital employees. Drawing on signal sensitivity theory, the authors expected that PA would moderate the relationship between merit pay raise size and reactions to the increase such that pay raise size would be more strongly related to pay attitudes and behavioral intentions among those low in PA. Results strongly supported the predictions in the case of reactions to the raise amount (happiness and effort intentions) but not for pay level satisfaction. Implications of the results and directions for future research are identified.

  14. Consumers’Willingness to Pay for Safety Attributes of Bread in Lagos Metropolis, Nigeria

    OpenAIRE

    Anyam, Osemeke E.; Fashogbon, Ayodele E.; Oni, Omobowale A.

    2013-01-01

    This study examined consumer’s willingness to pay for food safety attributes in bread in Lagos metropolis. It empirically analyzed the factors driving willingness to pay for improved bread and the effect of attributes on willingness to pay and mean willingness to pay for improved bread. The data for the study using a well-structured questionnaire containing Choice Experiment (CE) questions for eliciting willingness to pay was collected from 150 respondents using a two-stage random sampling te...

  15. Consumers' willingness to pay for irradiated prepared ground beef

    International Nuclear Information System (INIS)

    Nayga, R.M. Jr.; Woodward, R.; Aiew, W.

    2009-01-01

    This paper focuses on estimating willingness to pay for reducing the risk of contracting foodborne illness using a non-hypothetical experiment utilizing real food products (i.e. prepared ground beef), real cash and actual exchange in a market setting. Respondents were given positive information about the nature of food irradiation. Single bounded and one and one-half bounded models are developed using dichotomous choice experiments. The results indicate that individuals are willing to pay for a reduction in the risk of foodborne illness once informed about the nature of food irradiation. Respondents are willing to pay a premium of about US $0.77 for 450 g (1 pound) of irradiated ground beef, which is higher than the cost of irradiating the product. (author)

  16. Synthesis and characterization of functionalized mesoprous SBA-15 decorated with Fe(3)O(4) nanoparticles for removal of Ce(III) ions from aqueous solution: ICP-OES detection and central composite design optimization.

    Science.gov (United States)

    Dashtian, Kheibar; Zare-Dorabei, Rouholah

    2017-05-15

    A selective adsorbent based on the modification of mesoprous SBA-15 with N,N'-bis(salicylidene)-1,3-ethylenediamine Schiff base and decorated with Fe 3 O 4 nanoparticles (SBA-15-BSEA-Fe 3 O 4 -NPs) for Ce(III) ions removal was reported. The SBA-15-BSEA-Fe 3 O 4 -NPs was identified by XRD, FE-SEM, TEM, SEM, FT-IR, VSM, BET and BJH analysis. Central composite design (CCD) was applied to evaluate the main and interactive effects of adsorption variables and optimize the operational parameters. The important variable such as initial pH solution, SBA-15-BSEA-Fe 3 O 4 -NPs mass, shaking time and initial concentration of Ce 3+ ions were studied under batch mode. In desirability concession of 1.0 as optimum value for R% Ce(III) , the level of factors was as follows: shaking time 80min, SBA-15-BSEA-Fe 3 O 4 -NPs mass 0.05g, pH 5 and initial concentration of Ce(III) ions 40mgL -1 . The SBA-15-BSEA-Fe 3 O 4 -NPs exhibited high adsorption efficiency and very good selectivity through cerium removal even in the presence of other ions (La 3+ , Nb 3+ , Er 3+ , Cu 2+ , Cd 2+ , Cr 3+ , and Fe 2+ ions). The SBA-15-BSEA-Fe 3 O 4 -NPs was successfully regenerated and the response was reversible. The R.S.D. of the adsorption process was less than 1.02%. Copyright © 2017 Elsevier Inc. All rights reserved.

  17. Pay as You Speed, ISA with incentives for not speeding

    DEFF Research Database (Denmark)

    Lahrmann, Harry Spaabæk; Agerholm, Niels; Tradisauskas, Nerius

    2012-01-01

    The Intelligent Speed Adaptation (ISA) project we describe in this article is based on Pay as You Drive principles. These principles assume that the ISA equipment informs a driver of the speed limit, warns the driver when speeding and calculates penalty points. Each penalty point entails...... the reduction of a 30% discount on the driver's car insurance premium, which therefore produced the name, Pay as You Speed. The ISA equipment consists of a GPS-based On Board Unit with a mobile phone connection to a web server. The project was planned for a three-year test period with 300 young car drivers...

  18. Mesostructured Au/C materials obtained by replication of functionalized SBA-15 silica containing highly dispersed gold nanoparticles

    KAUST Repository

    Kerdi, Fatmé

    2011-04-01

    The preparation and characterization of highly dispersed gold nanoparticles in ordered mesoporous carbons CMK-3 are reported. These carbons were obtained using gold-containing functionalized SBA-15 silicas as hard templates. Two series of Au/SiO2 templates were prepared, depending on the nature of the functionalization molecule. While ammonium-functionalized silicas gave gold particles with a size determined by the pores of the silica support, the use of mercaptopropyltrimethoxysilane as grafting molecule afforded the possibility to control the particle size inside the mesopores. Both series gave highly ordered mesoporous carbons with gold particles incorporated in the carbon nanorods. However, the gold particle size in mesoporous carbons was the same for both series and apparently did not depend on the nature of the silica template. Both Au/SiO2 templates and their corresponding Au/CMK-3 materials have been characterized by X-ray diffraction, nitrogen adsorption/desorption, chemical analysis, solid-state nuclear magnetic resonance and transmission electron microscopy. They were also used as catalysts in the aerobic oxidation of cyclohexene and trans-stilbene in the liquid phase. © 2010 Elsevier Inc. All rights reserved.

  19. Catalytic Cracking of Triglyceride-Rich Biomass toward Lower Olefins over a Nano-ZSM-5/SBA-15 Analog Composite

    Directory of Open Access Journals (Sweden)

    Xuan Hoan Vu

    2015-10-01

    Full Text Available The catalytic cracking of triglyceride-rich biomass toward C2–C4 olefins was evaluated over a hierarchically textured nano-ZSM-5/SBA-15 analog composite (ZSC-24 under fluid catalytic cracking (FCC conditions. The experiments were performed on a fully automated Single-Receiver Short-Contact-Time Microactivity Test unit (SR-SCT-MAT, Grace Davison at 550 °C and different catalyst-to-oil mass ratios (0–1.2 g∙g−1. The ZSC-24 catalyst is very effective for transformation of triglycerides to valuable hydrocarbons, particularly lower olefins. The selectivity to C2–C4 olefins is remarkably high (>90% throughout the investigated catalyst-to-oil ratio range. The superior catalytic performance of the ZSC-24 catalyst can be attributed to the combination of its medium acid site amount and improved molecular transport provided by the bimodal pore system, which effectively suppresses the secondary reactions of primarily formed lower olefins.

  20. Selective Hydrogenation of Furfural to Furfuryl Alcohol in the Presence of a Recyclable Cobalt/SBA-15 Catalyst.

    Science.gov (United States)

    Audemar, Maïté; Ciotonea, Carmen; De Oliveira Vigier, Karine; Royer, Sébastien; Ungureanu, Adrian; Dragoi, Brindusa; Dumitriu, Emil; Jérôme, François

    2015-06-08

    The hydrogenation of furfural to furfuryl alcohol was performed in the presence of a Co/SBA-15 catalyst. High selectivity (96 %) at a conversion higher than 95 % is reported over this catalytic system. As the conversion of furfural to furfuryl alcohol occurs over metallic Co sites, the effect of reduction temperature, H2 pressure, and reaction temperature were studied. Optimum reaction conditions were: 150 °C, 1.5 h, 2.0 MPa of H2 . The catalyst was recyclable, and furfuryl alcohol was recovered with a purity higher than 90 %. The effect of the solvent concentration was also studied. With a minimum of 50 wt % of solvent, the selectivity to furfuryl alcohol and the conversion of furfural remained high (both over 80 %). Likewise, the activity of the catalyst is maintained even in pure furfural, which confirms the real potential of the proposed catalytic system. This catalyst was also used in the hydrogenation of levulinic acid to produce γ-valerolactone selectively. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.