WorldWideScience

Sample records for laser ionization gas

  1. Two-step laser ionization schemes for in-gas laser ionization and spectroscopy of radioactive isotopes

    Energy Technology Data Exchange (ETDEWEB)

    Kudryavtsev, Yu., E-mail: yuri.kudryavtsev@fys.kuleuven.be; Ferrer, R.; Huyse, M.; Van den Bergh, P.; Van Duppen, P. [Instituut voor Kern- en Stralingsfysica, KU Leuven, 3001 Leuven (Belgium); Vermeeren, L. [SCK-CEN, Nuclear Research Centre, Boeretang 200, B-2400 Mol (Belgium)

    2014-02-15

    The in-gas laser ionization and spectroscopy technique has been developed at the Leuven isotope separator on-line facility for the production and in-source laser spectroscopy studies of short-lived radioactive isotopes. In this article, results from a study to identify efficient optical schemes for the two-step resonance laser ionization of 18 elements are presented.

  2. Modulation of ionization on laser frequency in ultra-short pulse intense laser-gas-target

    Institute of Scientific and Technical Information of China (English)

    Hu Qiang-Lin; Liu Shi-Bing

    2006-01-01

    Based on the dispersion relation of intense laser pulse propagating in gradually ionized plasma, this paper discusses the frequency modulation induced by ionization of an ultra-short intense laser pulse interacting with a gas target.The relationship between the frequency modulation and the ionization rate, the plasmas frequency variation, and the polarization of atoms (ions) is analysed. The numerical results indicate that, at high frequency, the polarization of atoms (ions) plays a more important role than plasma frequency variation in modulating the laser frequency, and the laser frequency variation is different at different positions of the laser pulse.

  3. Ionization processes in combined high-voltage nanosecond - laser discharges in inert gas

    Science.gov (United States)

    Starikovskiy, Andrey; Shneider, Mikhail; PU Team

    2016-09-01

    Remote control of plasmas induced by laser radiation in the atmosphere is one of the challenging issues of free space communication, long-distance energy transmission, remote sensing of the atmosphere, and standoff detection of trace gases and bio-threat species. Sequences of laser pulses, as demonstrated by an extensive earlier work, offer an advantageous tool providing access to the control of air-plasma dynamics and optical interactions. The avalanche ionization induced in a pre-ionized region by infrared laser pulses where investigated. Pre-ionization was created by an ionization wave, initiated by high-voltage nanosecond pulse. Then, behind the front of ionization wave extra avalanche ionization was initiated by the focused infrared laser pulse. The experiment was carried out in argon. It is shown that the gas pre-ionization inhibits the laser spark generation under low pressure conditions.

  4. Double ionization effect in electron accelerations by high-intensity laser pulse interaction with a neutral gas

    Science.gov (United States)

    Nandan Gupta, Devki

    2013-11-01

    We study the effect of laser-induced double-ionization of a helium gas (with inhomogeneous density profile) on vacuum electron acceleration. For enough laser intensity, helium gas can be found doubly ionized and it strengthens the divergence of the pulse. The double ionization of helium gas can defocus the laser pulse significantly, and electrons are accelerated by the front of the laser pulse in vacuum and then decelerated by the defocused trail part of the laser pulse. It is observed that the electrons experience a very low laser-intensity at the trailing part of the laser pulse. Hence, there is not much electron deceleration at the trailing part of the pulse. We found that the inhomogeneity of the neutral gas reduced the rate of tunnel ionization causing less defocusing of the laser pulse and thus the electron energy gain is reduced.

  5. Double ionization effect in electron accelerations by high-intensity laser pulse interaction with a neutral gas

    Directory of Open Access Journals (Sweden)

    Gupta Devki Nandan

    2013-11-01

    Full Text Available We study the effect of laser-induced double-ionization of a helium gas (with inhomogeneous density profile on vacuum electron acceleration. For enough laser intensity, helium gas can be found doubly ionized and it strengthens the divergence of the pulse. The double ionization of helium gas can defocus the laser pulse significantly, and electrons are accelerated by the front of the laser pulse in vacuum and then decelerated by the defocused trail part of the laser pulse. It is observed that the electrons experience a very low laser-intensity at the trailing part of the laser pulse. Hence, there is not much electron deceleration at the trailing part of the pulse. We found that the inhomogeneity of the neutral gas reduced the rate of tunnel ionization causing less defocusing of the laser pulse and thus the electron energy gain is reduced.

  6. In-gas-cell laser ionization studies of plutonium isotopes at IGISOL

    Science.gov (United States)

    Pohjalainen, I.; Moore, I. D.; Kron, T.; Raeder, S.; Sonnenschein, V.; Tomita, H.; Trautmann, N.; Voss, A.; Wendt, K.

    2016-06-01

    In-gas-cell resonance laser ionization has been performed on long-lived isotopes of Pu at the IGISOL facility, Jyväskylä. This initiates a new programme of research towards high-resolution optical spectroscopy of heavy actinide elements which can be produced in sufficient quantities at research reactors and transported to facilities elsewhere. In this work a new gas cell has been constructed for fast extraction of laser-ionized elements. Samples of 238-240,242Pu and 244Pu have been evaporated from Ta filaments, laser ionized, mass separated and delivered to the collinear laser spectroscopy station. Here we report on the performance of the gas cell through studies of the mass spectra obtained in helium and argon, before and after the radiofrequency quadrupole cooler-buncher. This provides valuable insight into the gas phase chemistry exhibited by Pu, which has been additionally supported by measurements of ion time profiles. The resulting monoatomic yields are sufficient for collinear laser spectroscopy. A gamma-ray spectroscopic analysis of the Pu samples shows a good agreement with the assay provided by the Mainz Nuclear Chemistry department.

  7. Determination of Hexachlorocyclohexane by Gas Chromatography Combined with Femtosecond Laser Ionization Mass Spectrometry

    Science.gov (United States)

    Yang, Xixiang; Imasaka, Tomoko; Li, Adan; Imasaka, Totaro

    2016-09-01

    Structural isomers and enantiomers of hexachlorocyclohexane (HCH) were separated using a chiral column by gas chromatography and quantitatively determined by multiphoton ionization mass spectrometry using an ultraviolet femtosecond laser (200 and 267 nm) as the ionization source. The order of elution of the enantiomers (i.e., (+)-α-HCH and (-)-α-HCH) was predicted from stabilization energies calculated for the complexes using permethylated γ-cyclodextrin as the stationary phase of the column, and the results were compared with the experimental data. The molecular ions observed for HCH were weak, even though they can be ionized through a process of resonance enhanced two-photon ionization at 200 nm. This unfavorable result can be attributed to the dissociation of the molecular ion, as predicted from quantum chemical calculations.

  8. Towards high-resolution laser ionization spectroscopy of the heaviest elements in supersonic gas jet expansion

    Science.gov (United States)

    Ferrer, R.; Barzakh, A.; Bastin, B.; Beerwerth, R.; Block, M.; Creemers, P.; Grawe, H.; de Groote, R.; Delahaye, P.; Fléchard, X.; Franchoo, S.; Fritzsche, S.; Gaffney, L. P.; Ghys, L.; Gins, W.; Granados, C.; Heinke, R.; Hijazi, L.; Huyse, M.; Kron, T.; Kudryavtsev, Yu.; Laatiaoui, M.; Lecesne, N.; Loiselet, M.; Lutton, F.; Moore, I. D.; Martínez, Y.; Mogilevskiy, E.; Naubereit, P.; Piot, J.; Raeder, S.; Rothe, S.; Savajols, H.; Sels, S.; Sonnenschein, V.; Thomas, J-C; Traykov, E.; Van Beveren, C.; Van den Bergh, P.; Van Duppen, P.; Wendt, K.; Zadvornaya, A.

    2017-01-01

    Resonant laser ionization and spectroscopy are widely used techniques at radioactive ion beam facilities to produce pure beams of exotic nuclei and measure the shape, size, spin and electromagnetic multipole moments of these nuclei. However, in such measurements it is difficult to combine a high efficiency with a high spectral resolution. Here we demonstrate the on-line application of atomic laser ionization spectroscopy in a supersonic gas jet, a technique suited for high-precision studies of the ground- and isomeric-state properties of nuclei located at the extremes of stability. The technique is characterized in a measurement on actinium isotopes around the N=126 neutron shell closure. A significant improvement in the spectral resolution by more than one order of magnitude is achieved in these experiments without loss in efficiency. PMID:28224987

  9. Ionization effects in the generation of wake-fields by ultra-high contrast femtosecond laser pulses in argon gas

    Energy Technology Data Exchange (ETDEWEB)

    Makito, K.; Shin, J.-H. [Graduate School of Engineering, Osaka University, 2-1, Yamadaoka, Suita, Osaka (Japan); Zhidkov, A.; Hosokai, T.; Masuda, S. [Photon Pioneers Center, Osaka University, 2-8, Yamadaoka, Suita, Osaka (Japan); Japan Science and Technology Agency (JST), CREST, 2-8 Yamadaoka, Suita, Osaka (Japan); Kodama, R. [Graduate School of Engineering, Osaka University, 2-1, Yamadaoka, Suita, Osaka (Japan); Photon Pioneers Center, Osaka University, 2-8, Yamadaoka, Suita, Osaka (Japan); Japan Science and Technology Agency (JST), CREST, 2-8 Yamadaoka, Suita, Osaka (Japan)

    2012-10-15

    Difference in mechanisms of wake-field generation and electron self-injection by high contrast femtosecond laser pulses in an initially neutral Argon gas and in pre-ionized plasma without ionization is studied via 2D particle-in-cell simulations including optical ionization of the media. For shorter laser pulses, 40 fs, ionization results only in an increase of the charge of accelerated electrons by factor of {approx}3 with qualitatively the same energy distribution. For longer pulses, 80 fs, a more stable wake field structure is observed in the neutral gas with the maximal energy of the accelerated electrons exceeding that in the fixed density plasma. In higher density Argon, an ionizing laser pulse converts itself to a complex system of solitons at a self-induced, critical density ramp.

  10. Ionization effects in the generation of wake-fields by ultra-high contrast femtosecond laser pulses in argon gas

    Science.gov (United States)

    Makito, K.; Zhidkov, A.; Hosokai, T.; Shin, J.-H.; Masuda, S.; Kodama, R.

    2012-10-01

    Difference in mechanisms of wake-field generation and electron self-injection by high contrast femtosecond laser pulses in an initially neutral Argon gas and in pre-ionized plasma without ionization is studied via 2D particle-in-cell simulations including optical ionization of the media. For shorter laser pulses, 40 fs, ionization results only in an increase of the charge of accelerated electrons by factor of ˜3 with qualitatively the same energy distribution. For longer pulses, 80 fs, a more stable wake field structure is observed in the neutral gas with the maximal energy of the accelerated electrons exceeding that in the fixed density plasma. In higher density Argon, an ionizing laser pulse converts itself to a complex system of solitons at a self-induced, critical density ramp.

  11. Development of a resonant laser ionization gas cell for high-energy, short-lived nuclei

    CERN Document Server

    Sonoda, T; Tomita, H; Sakamoto, C; Takatsuka, T; Furukawa, T; Iimura, H; Ito, Y; Kubo, T; Matsuo, Y; Mita, H; Naimi, S; Nakamura, S; Noto, T; Schury, P; Shinozuka, T; Wakui, T; Miyatake, H; Jeong, S; Ishiyama, H; Watanabe, Y X; Hirayama, Y; Okada, K; Takamine, A

    2012-01-01

    A new laser ion source configuration based on resonant photoionization in a gas cell has been developed at RIBF RIKEN. This system is intended for the future PArasitic RI-beam production by Laser Ion-Source (PALIS) project which will be installed at RIKEN's fragment separator, BigRIPS. A novel implementation of differential pumping, in combination with a sextupole ion beam guide (SPIG), has been developed. A few small scroll pumps create a pressure difference from 1000 hPa - 10^-3 Pa within a geometry drastically miniaturized compared to conventional systems. This system can utilize a large exit hole for fast evacuation times, minimizing the decay loss for short-lived nuclei during extraction from a buffer gas cell, while sufficient gas cell pressure is maintained for stopping high energy RI-beams. In spite of the motion in a dense pressure gradient, the photo-ionized ions inside the gas cell are ejected with an assisting force gas jet and successfully transported to a high-vacuum region via SPIG followed by ...

  12. Spectrum Blueshifting of Ultrashort UV Laser Pulse Induced by Ionization of Supersonic He and Ar Gas Jets

    Institute of Scientific and Technical Information of China (English)

    YAN Lixin; ZHANG Yongsheng; LIU Jingru; HUANG Wenhui; TANG Chuanxiang; CHENG Jianping

    2008-01-01

    The predominant spectral blueshifting of a sub-picosecond UV laser pulse induced by ultrafast ionization of noble gases was investigated. Spectral measurements were made at various gas densities. Typical quasi-periodic structures in the blueshifted spectrum were obtained. The observations were in connection with the so-called self-phase modulation of laser pulses in the ultrafast ionization process which was simply simulated with an ADK (Ammosov-Delone-Krainov) ionization model. Some quantitative information can be deduced from the measurements and calculations.

  13. Pulse Operation of Chemical Oxygen-Iodine Laser by Pulsed Gas Discharge with the Assistance of Spark Pre-ionization

    Institute of Scientific and Technical Information of China (English)

    LI Guo-Fu; YU Hai-Jun; DUO Li-Ping; JIN Yu-Qi; WANG Jian; SANG Feng-Ting; FANG Ben-Jie; WANG De-Zhen

    2009-01-01

    The continuous wavelength chemical oxygen-iodine laser can be turned into pulse operation mode in order to obtain high energy and high pulse power. We propose an approach to produce iodine atoms instantaneously by pulsed gas discharge with the assistance of spark pre-ionization to achieve the pulsed goal. The influence of spark pre-ionization on discharge homogeneity is discussed. Voltage-current characteristics are shown and discussed in existence of the pre-ionization capacitor and peaking capacitor. The spark pre-ionization and peaking capacitor are very helpful in obtaining a stable and homogeneous discharge. The lasing is achieved at the total pressure of 2.2-2.9 kPa and single pulse energy is up to 180m J, the corresponding specific output energy is 1.0 J/L.

  14. Resonance Ionization Laser Ion Sources

    CERN Document Server

    Marsh, B

    2013-01-01

    The application of the technique of laser resonance ionization to the production of singly charged ions at radioactive ion beam facilities is discussed. The ability to combine high efficiency and element selectivity makes a resonance ionization laser ion source (RILIS) an important component of many radioactive ion beam facilities. At CERN, for example, the RILIS is the most commonly used ion source of the ISOLDE facility, with a yearly operating time of up to 3000 hours. For some isotopes the RILIS can also be used as a fast and sensitive laser spectroscopy tool, provided that the spectral resolution is sufficiently high to reveal the influence of nuclear structure on the atomic spectra. This enables the study of nuclear properties of isotopes with production rates even lower than one ion per second and, in some cases, enables isomer selective ionization. The solutions available for the implementation of resonance laser ionization at radioactive ion beam facilities are summarized. Aspects such as the laser r...

  15. Effect of gas pressure on ionization of ambient gas

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    An Nd: YAG pulsed laser (145 mJ) was used to ablate aluminum target and Ar was used as protecting gas. Time-and space-resolved spectra of the plasmas under pressure 100 Pa, 1 kPa, 10 kPa and 100 kPa were acquired with time- and space-resolved technique. The characteristics of the plasma radiating under each pressure were briefly described, and the laws of Ar characteristical radiaton were analyzed in detail. Based on the profile of Ar characteristical radiation under these pressure, the relation between protecting gas pressure and its ionization was briefly discussed, and explained with quantum theory. Farther more, the mechanism of ambient gas ionization was investigated. As the result, it was suggested that the main mechanism inducing protecting gas to ionize should be the absorption of the plasma continuum radiation by the gas.

  16. Radiative feedback from ionized gas

    CERN Document Server

    Glover, S C O

    2007-01-01

    H2 formation in metal-free gas occurs via the intermediate H- or H2+ ions. Destruction of these ions by photodissociation therefore serves to suppress H2 formation. In this paper, I highlight the fact that several processes that occur in ionized primordial gas produce photons energetic enough to photodissociate H- or H2+ and outline how to compute the photodissociation rates produced by a particular distribution of ionized gas. I also show that there are circumstances of interest, such as during the growth of HII regions around the first stars, in which this previously overlooked form of radiative feedback is of considerable importance.

  17. Search for Efficient Laser Resonance Ionization Schemes of Refractory Elements for KISS

    Science.gov (United States)

    Mukai, M.; Hirayama, Y.; Imai, N.; Ishiyama, H.; Jeong, S. C.; Miyatake, H.; Oyaizu, M.; Watanabe, Y. X.; Kim, Y. H.; Kimura, S.

    Laser resonance ionization is employed for the element-selective ionization of multi-nucleon transfer reaction products which are stopped and neutralized in the gas cell filled with argon gas of 50 kPa. We searched for laser resonance ionization schemes of tantalum (Z = 73), tungsten (Z = 74), rhenium (Z = 75) and iridium (Z = 77) elements. We deduced the photon absorption cross section for each transition and the laser ionization efficiency in the gas cell.

  18. to fully ionized gas

    Directory of Open Access Journals (Sweden)

    Ma. T. García Díaz

    2008-01-01

    Full Text Available Presentamos un atlas4 de espectros tridimensionales (posición-posición-velocidad de la Nebulosa de Orión en líneas de emisión ópticas de una variedad de diferentes etapas de ionización: [O I] 6300 ˚A, [S II] 6716,6731˚A, [N II] 6584˚A, [S III] 6312˚A, Hα 6563˚A, y [O III] 5007˚A. Estas transiciones nos dan información punto a punto sobre la estructura física y cinemática de la nebulosa a una resolución efectiva de 3´´ × 2´´ × 10 km s−1, mostrando claramente el comportamiento a gran escala del gas ionizado y la presencia de fenómenos localizados tales como flujos colimados relacionados a objetos Herbig-Haro. Como un ejemplo de la aplicación del atlas presentamos un análisis estadístico de los anchos de las líneas de Hα, [OIII] y [N II], que permiten una determinación de la temperatura electrónica media en la nebulosa de (9200±400 K. También, en contraste con trabajos anteriores, encontramos que no hay diferencia entre el ensanchamiento no térmico de las líneas de recombinación y el de las líneas colisionales.

  19. Efficiency of Gas-Phase Ion Formation in Matrix-Assisted Laser Desorption Ionization with 2,5-Dihydroxybenzoic Acid as Matrix

    Energy Technology Data Exchange (ETDEWEB)

    Park, Kyung Man; Ahn, Sung Hee; Bae, Yong Jin; Kim, Myung Soo [Seoul National Univ., Seoul (Korea, Republic of)

    2013-03-15

    Numbers of matrix- and analyte-derived ions and their sum in matrix-assisted laser desorption ionization (MALDI) of a peptide were measured using 2,5-dihydroxybenzoic acid (DHB) as matrix. As for MALDI with α-cyano-4-hydroxy cinnamic acid as matrix, the sum was independent of the peptide concentration in the solid sample, or was the same as that of pure DHB. This suggested that the matrix ion was the primary ion and that the peptide ion was generated by matrix-to-peptide proton transfer. Experimental ionization efficiencies of 10{sup -5}-10{sup -4} for peptides and 10{sup -8}-10{sup -7} for matrices are far smaller than 10.3-10.1 for peptides and 10{sup -5}-10{sup -3} for matrices speculated by Hillenkamp and Karas. Number of gas-phase ions generated by MALDI was unaffected by laser wavelength or pulse energy. This suggests that the main role of photo-absorption in MALDI is not in generating ions via a multi-photon process but in ablating materials in a solid sample to the gas phase.

  20. Introduction to gas lasers with emphasis on selective excitation processes

    CERN Document Server

    Willett, Colin S

    1974-01-01

    Introduction to Gas Lasers: Population Inversion Mechanisms focuses on important processes in gas discharge lasers and basic atomic collision processes that operate in a gas laser. Organized into six chapters, this book first discusses the historical development and basic principles of gas lasers. Subsequent chapters describe the selective excitation processes in gas discharges and the specific neutral, ionized and molecular laser systems. This book will be a valuable reference on the behavior of gas-discharge lasers to anyone already in the field.

  1. Mapping the Ionization State of Laser-Irradiated Ar Gas Jets With Multi-Wavelength Monochromatic X-Ray Imaging

    Energy Technology Data Exchange (ETDEWEB)

    Kugland, N L; Doppner, T; Kemp, A; Schaeffer, D; Glenzer, S H; Niemann, C

    2010-04-08

    Two-dimensional monochromatic images of fast-electron stimulated Ar K{alpha} and He-{alpha} x-ray self-emission have recorded a time-integrated map of the extent of Ar{sup {approx}6+} and Ar{sup 16+} ions, respectively, within a high density (10{sup 20} cm{sup -3} atomic density) Ar plasma. This plasma was produced by irradiating a 2 mm wide clustering Ar gas jet with an ultra-high intensity (10{sup 19} W/cm{sup 2}, 200 fs) Ti:Sapphire laser operating at 800 nm. Spherically bent quartz crystals in the 200 (for K{alpha}) and 201 (for He-{alpha}) planes were used as near-normal incidence reflective x-ray optics. We see that a large (830 {micro}m long) region of plasma emits K{alpha} primarily along the laser axis, while the He-{alpha} emission is confined to smaller hot spot (230 {micro}m long) region that likely corresponds to the focal volume of the f/8 laser beam. X-ray spectra from a Bragg spectrometer operating in the von Hamos geometry, which images in one dimension, indicate that the centroids of the K{alpha} and He-{alpha} emission regions are separated by approximately 330 {micro}m along the laser axis.

  2. Turbulence and the ionization of interstellar gas

    Science.gov (United States)

    Hill, Alex S.

    2015-08-01

    Turbulence is widely observed in the ionized gas in the interstellar media of star-forming galaxies. Observations in the Milky Way indicate emission from that the warm ionized medium -- ionized gas far from massive stars, the most likely source of the ionization -- has a lognormal intensity distribution. This and other measurements indicate that the gas is well-described as a transonic turbulent fluid. Such a fluid can be produced by feedback from supernovae in the Galaxy. Understanding of this turbulence has also led to a natural explanation for a long-standing puzzle: how do ionizing photons travel through the largely-neutral interstellar medium and produce the ionization? In the turbulent gas, low-density pathways allow ionizing photons to propagate for kiloparsecs, with implications for radiative energy transport in star-forming galaxies.

  3. Comparative study of matrix-assisted laser desorption/ionization and gas chromatography for quantitative determination of cocoa butter and cocoa butter equivalent triacylglycerol composition.

    Science.gov (United States)

    Guyon, F; Absalon, Ch; Eloy, A; Salagoity, M H; Esclapez, M; Medina, B

    2003-01-01

    The triacylglycerol (TAG) composition study of cocoa butter (CB) and cocoa butter equivalents (CBEs) has been performed by gas chromatography (GC) and matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI-TOFMS). These two techniques provided comparable results. The advantage of the MALDI technique was the detection of each compound comprising the triacylglycerol classes (Cn). Moreover, comparison of the data obtained by these two techniques indicated that TAG relative percentages could be obtained quantitatively with the MALDI technique. These techniques have been applied for the composition determination of CB + CBE mixtures. Encouraging results showed that it is possible to quantify an admixture containing as little as 4% of CBE.

  4. A gas laser design

    Energy Technology Data Exchange (ETDEWEB)

    Syudzo, Y.; Nooya, Kh.

    1984-05-28

    A gas laser design that excludes direct contact between the gas medium and the atmosphere is proposed. The laser operates at a reduced gas pressure. After shutdown, a special system is used to increase the gas pressure inside the discharge chamber, which approaches atmospheric pressure. The laser employs an internal optical resonator. The electrical discharge which excites the gas medium originates from three electrodes located within the gas discharge tube.

  5. Ionization in nearby interstellar gas

    Science.gov (United States)

    Frisch, P. C.; Welty, D. E.; York, D. G.; Fowler, J. R.

    1990-01-01

    Due to dielectric recombination, neutral magnesium represents an important tracer for the warm low-density gas around the solar system. New Mg I 2852 absorption-line data from IUE are presented, including detections in a few stars within 40 pc of the sun. The absence of detectable Mg I in Alpha CMa and other stars sets limits on the combined size and electron density of the interstellar cloud which gives rise to the local interstellar wind. For a cloud radius greater than 1 pc and density of 0.1/cu cm, the local cloud has a low fractional ionization, n(e)/n(tot) less than 0.05, if magnesium is undepleted, equilibrium conditions prevail, the cloud temperature is 11,750 K, and 80 percent of the magnesium in the sightline is Mg II.

  6. Ionization in nearby interstellar gas

    Energy Technology Data Exchange (ETDEWEB)

    Frisch, P.C.; Welty, D.E.; York, D.G.; Fowler, J.R. (Chicago Univ., IL (USA) New Mexico State Univ., Las Cruces (USA))

    1990-07-01

    Due to dielectric recombination, neutral magnesium represents an important tracer for the warm low-density gas around the solar system. New Mg I 2852 absorption-line data from IUE are presented, including detections in a few stars within 40 pc of the sun. The absence of detectable Mg I in Alpha CMa and other stars sets limits on the combined size and electron density of the interstellar cloud which gives rise to the local interstellar wind. For a cloud radius greater than 1 pc and density of 0.1/cu cm, the local cloud has a low fractional ionization, n(e)/n(tot) less than 0.05, if magnesium is undepleted, equilibrium conditions prevail, the cloud temperature is 11,750 K, and 80 percent of the magnesium in the sightline is Mg II. 85 refs.

  7. Infrared laser desorption/ionization on silicon.

    Science.gov (United States)

    Bhattacharya, Sucharita H; Raiford, Timothy J; Murray, Kermit K

    2002-05-01

    Laser desorption/ionization from a single-crystal silicon surface was performed using a laser operating in the 3-microm region of the mid-infrared. Analyte molecules up to 6 kDa were ionized with no added matrix. As with ultraviolet desorption/ionization from porous silicon (DIOS), IR laser desorption from silicon does not produce matrix ions that can interfere with analysis of low-mass analytes. However, in contrast to UV DIOS, silicon porosity or roughness is not required for ionization using an IR laser. Mass spectra were obtained in the wavelength range between 2.8 and 3.5 microm, which is consistent with energy absorption by a hydrogen-bonded OH group. A mechanism based on desorption of adsorbed solvent molecules is postulated.

  8. A gas laser system

    Energy Technology Data Exchange (ETDEWEB)

    Sydzo, Y.; Norio, T.

    1984-04-02

    It is reported that an improved gas laser system with active medium circulation has been developed. The design of the gas laser is given in block diagram form, and its principle of operation is described in detail. The gaseous active medium flows through the inlet hole to the laser system, and is uniformly dispersed as it flows through the cylindrical diffuser. Thus, a near uniform distribution in the flow velocity of the gas flow in the laser discharge tube is achieved. The gas flow velocity along the edges of the discharge tube exceeds somewhat the flow velocity in the central section, which aids in generating and maintaining a stable and uniform pumping discharge. It is established experimentally that when using the proposed design, the parameters of the output emission from the gas laser are improved significantly. A relationship is given which demonstrates the near linear relationship between the pumping voltage and the output emission power from a gas laser.

  9. Ionizing laser propagation and spectral phase determination

    Science.gov (United States)

    Mittelberger, D. E.; Nakamura, K.; Lehe, R.; Gonsalves, A. J.; Benedetti, C.; Mao, H.-S.; Daniels, J.; Dale, N.; Swanson, K. K.; Esarey, E.; Leemans, W. P.

    2017-03-01

    Ionization-induced blueshifting is investigated through INF&RNO simulations and experimental studies at the Berkeley Laboratory Laser Accelerator (BELLA) Center. The effects of spectral phase and optical compression are explored. An in-situ method for verifying the spectral phase of an intense laser pulse at focus is presented, based on the effects of optical compression on the morphology of the blueshifted laser spectra.

  10. Spectral splitting of high order harmonics of ionizing gases irradiated with ultrashort intense laser pulses

    Institute of Scientific and Technical Information of China (English)

    钟方川; 胡雪原; 黎忠; 张正泉; 李儒新; 徐至展

    2002-01-01

    The spectrum of harmonics generated and propagated in ionized noble gas has been analyzed using one-dimensional wave propagation equation.The result shows that the spectral lines of harmonic become broadened and then split into two peaks when the laser intensity is strong enough to ionize the noble gas.The influnence of laser parameters and gas pressure on the splitting has been made clear.

  11. A gas laser

    Energy Technology Data Exchange (ETDEWEB)

    Sydzo, Y.

    1984-03-27

    It is reported that an improved design of a discharge tube for a gas laser is developed. A schematic of the discharge tube is given and its principle of operation is described in detail. In order to improve the flow of the gaseous active substance, it is proposed that tow additional incoming channels be used which are located between the primary incoming channels and the gas laser mirrors. The use of the additional incoming channels provides better circulation of the active medium in the regions near the laser mirrors. Thus, a more uniform heating of the region near the discharge tube is achieved due to the heat liberated from pumping discharge. It is noted that the proposed design serves to reduce the thermal deformation to the mirrors in the gas laser, and improves the laser efficiency.

  12. Laboratory simulation of cometary neutral gas ionization

    Science.gov (United States)

    Chang, Tsuey-Fen; Rahman, H. U.; White, R. S.

    1989-01-01

    The laboratory simulation of the interaction of the solar wind with a comet is used to study the cometary neural gas ionization. The experiment is carried out in the UCR T-1 facility with an ice ball as the comet model. Photographs and data are taken with a variety of values of the solar wind velocity, interplanetary magnetic field (IMF), and comet configurations. The results show that the cometary neutral gas ionization depends on both the velocity of the solar wind and the interplanetary magnetic field. The plasma cloud surrounding the comet is visible only when the solar wind velocity and IMF are both above certain minimum values. This velocity dependent phenomena is explained by Alfven's critical ionization velocity effect. The critical magnetic field may be explained by assuming two stream lower hybrid instability as a triggering mechanism for the ionization of the neutral gas by plasma flow. Critical upper and lower limits for the magnetic field, required by anomalous ionization, are also derived that satisfy the experimental observations.

  13. Improvement of a New Gas Ionization Chamber

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    In order to identify heavier elements, we have developed a new longitudinal field gas ionization chamber (IC)with an angle of 30° of plate (as shown in Fig.1). The IC is operated in flowing iso-butane gas at a pressure of 10kPa. After testing by using a 3- component α particle source and comparing with the old longitudinal field

  14. Ionization of Atoms by Intense Laser Pulses

    CERN Document Server

    Froehlich, Juerg; Schlein, Benjamin

    2010-01-01

    The process of ionization of a hydrogen atom by a short infrared laser pulse is studied in the regime of very large pulse intensity, in the dipole approximation. Let $A$ denote the integral of the electric field of the pulse over time at the location of the atomic nucleus. It is shown that, in the limit where $|A| \\to \\infty$, the ionization probability approaches unity and the electron is ejected into a cone opening in the direction of $-A$ and of arbitrarily small opening angle. Asymptotics of various physical quantities in $|A|^{-1}$ is studied carefully. Our results are in qualitative agreement with experimental data reported in \\cite{1,2}.

  15. A gas laser tube

    Energy Technology Data Exchange (ETDEWEB)

    Tetsuo, F.; Tokhikhide, N.

    1984-04-19

    A gas laser tube is described in which contamination of the laser gas mixture by the coolant is avoided, resulting in a longer service life of the mirrors. The holder contains two tubes, one inside the other. The laser gas mixture flows through the internal tube. An electrode is fastened to the holder. The coolant is pumped through the slot between the two tubes, for which a hole is cut into the holder. The external tube has a ring which serves to seal the cavity containing the coolant from the atmosphere. The internal tube has two rings, one to seal the laser gas mixture and the other to seal the coolant. A slot is located between these two rings, which leads to the atmosphere (the atmosphere layer). With this configuration, the degradation of the sealing properties of the internal ring caused by interaction with the atmospheric layer is not reflected in the purity of the laser gas mixture. Moreover, pollution of the mirrors caused by the penetration of the coolant into the cavity is eliminated.

  16. Analysis of persistent organic pollutants at sub-femtogram levels using a high-power picosecond laser for multiphoton ionization in conjunction with gas chromatography/time-of-flight mass spectrometry.

    Science.gov (United States)

    Matsui, Taiki; Fukazawa, Kodai; Fujimoto, Masatoshi; Imasaka, Totaro

    2012-01-01

    A low-energy, high-repetition-rate picosecond laser (40 µJ, 20 kHz, 258 nm) was used for multiphoton ionization (MPI) in gas chromatography/time-of-flight mass spectrometry to quantitatively determine dioxins (DXNs) and polycyclic aromatic hydrocarbons (PAHs). The sensitivity of the technique was compared with that obtained using a high-energy, low-repetition-rate femtosecond laser (86 µJ, 1 kHz, 261 nm). The limits of detection (LODs) for the picosecond laser were several femtograms for chlorinated DXNs with low numbers of chloro substituents, and were several times lower than values obtained using a femtosecond laser, although the LODs were increased, reaching values that were nearly identical to those for the femtosecond laser for octachlorodibenzo-p-dioxin (octaCDD) and octachlorodibenzofuran (octaCDF). The LODs were also measured for 16 PAHs specified by the United States Environmental Protection Agency; the values for half of these compounds were at sub-femtogram levels. The procedure was used to analyze a surface-water sample collected from a river.

  17. The ionization mechanisms in direct and dopant-assisted atmospheric pressure photoionization and atmospheric pressure laser ionization.

    Science.gov (United States)

    Kauppila, Tiina J; Kersten, Hendrik; Benter, Thorsten

    2014-11-01

    A novel, gas-tight API interface for gas chromatography-mass spectrometry was used to study the ionization mechanism in direct and dopant-assisted atmospheric pressure photoionization (APPI) and atmospheric pressure laser ionization (APLI). Eight analytes (ethylbenzene, bromobenzene, naphthalene, anthracene, benzaldehyde, pyridine, quinolone, and acridine) with varying ionization energies (IEs) and proton affinities (PAs), and four common APPI dopants (toluene, acetone, anisole, and chlorobenzene) were chosen. All the studied compounds were ionized by direct APPI, forming mainly molecular ions. Addition of dopants suppressed the signal of the analytes with IEs above the IE of the dopant. For compounds with suitable IEs or Pas, the dopants increased the ionization efficiency as the analytes could be ionized through dopant-mediated gas-phase reactions, such as charge exchange, proton transfer, and other rather unexpected reactions, such as formation of [M + 77](+) in the presence of chlorobenzene. Experiments with deuterated toluene as the dopant verified that in case of proton transfer, the proton originated from the dopant instead of proton-bound solvent clusters, as in conventional open or non-tight APPI sources. In direct APLI using a 266 nm laser, a narrower range of compounds was ionized than in direct APPI, because of exceedingly high IEs or unfavorable two-photon absorption cross-sections. Introduction of dopants in the APLI system changed the ionization mechanism to similar dopant-mediated gas-phase reactions with the dopant as in APPI, which produced mainly ions of the same form as in APPI, and ionized a wider range of analytes than direct APLI.

  18. Spontaneous avalanche ionization of a strongly blockaded Rydberg gas

    CERN Document Server

    Robert-de-Saint-Vincent, M; Schempp, H; Günter, G; Whitlock, S; Weidemüller, M

    2012-01-01

    We report the sudden and spontaneous evolution of an initially correlated gas of repulsively interacting Rydberg atoms to an ultracold plasma. Under continuous laser coupling we create a Rydberg ensemble in the strong blockade regime, which at longer times undergoes an ionization avalanche. By combining optical imaging and ion detection, we access the full information on the dynamical evolution of the system, including the rapid increase in the number of ions and a sudden depletion of the Rydberg and ground state densities. Rydberg-Rydberg interactions are observed to strongly affect the dynamics of plasma formation. Using a coupled rate-equation model to describe our data, we extract the average energy of electrons trapped in the plasma, and an effective cross-section for ionizing collisions between Rydberg atoms and atoms in low-lying states. Our results suggest that the initial correlations of the Rydberg ensemble should persist through the avalanche. This would provide the means to overcome disorder-induc...

  19. Theory of recombination x-ray lasers based on optical-field ionization

    Energy Technology Data Exchange (ETDEWEB)

    Eder, D.C.; Amendt, P.; DaSilva, L.B.; London, R.A.; Rosen, M.D.; Wilks, S.C. [Lawrence Livermore National Lab., CA (United States); Donnelly, T.D.; Falcone, R.W. [Univ. of California at Berkeley, Berkeley, CA (United States)

    1994-12-01

    Ultrashort-pulse, high-intensity laser drivers have the potential for creating tabletop-size x-ray lasers by ionizing the target gas via the electric field of the laser pulse. For appropriate plasma conditions following ionization, lasing can occur during the subsequent rapid recombination. A review of the theory and modeling for these optical-field-ionized x-ray lasers is presented. Particular attention is given to the issues of electron beating and ionization-induced refraction. We summarize modeling in support of experiments where evidence of lasing in H-like Li at 135 {Angstrom} was obtained. In addition, we present modeling results for lasing in Li-like N at 247 {Angstrom}. We briefly discuss new applications appropriate for tabletop-size high-repetition-rate x-ray lasers.

  20. Application of laser induced electron impact ionization to the deposition chemistry in the hot-wire chemical vapor deposition process with SiH4-NH3 gas mixtures.

    Science.gov (United States)

    Eustergerling, Brett; Hèden, Martin; Shi, Yujun

    2007-11-01

    The application of a laser-induced electron impact (LIEI) ionization source in studying the gas-phase chemistry of the SiH(4)/NH(3) hot-wire chemical vapor deposition (HWCVD) system has been investigated. The LIEI source is achieved by directing an unfocused laser beam containing both 118 nm (10.5 eV) vacuum ultraviolet (VUV) and 355 nm UV radiations to the repeller plate in a time-of-flight mass spectrometer. Comparison of the LIEI source with the conventional 118 nm VUV single-photon ionization (SPI) method has demonstrated that the intensities of the chemical species with ionization potentials (IP) above 10.5 eV, e.g., H(2), N(2) and He, have been significantly enhanced with the incorporation of the LIEI source. It is found that the SPI source due to the 118 nm VUV light coexists in the LIEI source. This allows simultaneous observations of parent ions with enhanced intensity from VUV SPI and their "fingerprint" fragmentation ions from LIEI. It is, therefore, an effective tool to diagnose the gas-phase chemical species involved with both NH(3) and SiH(4) in the HWCVD reactor. In using the LIEI source to SiH(4), NH(3) and their mixtures, it has been shown that the NH(3) decomposition is suppressed with the addition of SiH(4) molecules. Examination of the NH(3) decomposition percentage and the time to reach the N(2) and H(2) steady-state intensities for various NH(3)/SiH(4) mixtures suggests that the extent of the suppression is enhanced with more SiH(4) content in the mixture. With increasing filament temperatures, the negative effect of SiH(4) becomes less important.

  1. Analysis of chirality by femtosecond laser ionization mass spectrometry.

    Science.gov (United States)

    Horsch, Philipp; Urbasch, Gunter; Weitzel, Karl-Michael

    2012-09-01

    Recent progress in the field of chirality analysis employing laser ionization mass spectrometry is reviewed. Emphasis is given to femtosecond (fs) laser ionization work from the author's group. We begin by reviewing fundamental aspects of determining circular dichroism (CD) in fs-laser ionization mass spectrometry (fs-LIMS) discussing an example from the literature (resonant fs-LIMS of 3-methylcyclopentanone). Second, we present new data indicating CD in non-resonant fs-LIMS of propylene oxide.

  2. Substrate-Enhanced Micro Laser Desorption Ionization Mass Spectrometry Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Aerodyne Research, Inc. and the University of Massachusetts at Amherst will collaborate to develop laser desorption ionization (LDI) mass spectrometric analysis of...

  3. The Ionization of Nearby Interstellar Gas

    CERN Document Server

    Slavin, J D; Slavin, Jonathan D.; Frisch, Priscilla C.

    2002-01-01

    We present new calculations of the photoionization of interstellar matter within ~5 pc of the Sun (which we refer to as the Local Cloud Complex or LCC) by directly observed radiation sources including nearby hot stars and the diffuse emission of the Soft X-ray Background (SXRB). In addition, we model the important, unobserved EUV emission both from the hot gas responsible for the SXRB and from a possible evaporative boundary between the LCC and the hot gas. We carry out radiative transfer calculations and show that these radiation sources can provide the ionization and heating of the cloud required to match a variety of observations. The ionization predicted in our models shows good agreement with pickup ion results, interstellar absorption line data towards epsilon CMa, and EUV opacity measurements of nearby white dwarf stars. Including the radiation from the conductive boundary improves agreement with data on the temperature and electron density in the cloud. The presence of dust in the cloud, or at least d...

  4. Microwave Triggered Laser Ionization of Air

    Science.gov (United States)

    Vadiee, Ehsan; Prasad, Sarita; Jerald Buchenauer, C.; Schamiloglu, Edl

    2012-10-01

    The goal of this work is to study the evolution and dynamics of plasma expansion when a high power microwave (HPM) pulse is overlapped in time and space on a very small, localized region of plasma formed by a high energy laser pulse. The pulsed Nd:YAG laser (8 ns, 600mJ, repetition rate 10 Hz) is focused to generate plasma filaments in air with electron density of 10^17/cm^3. When irradiated with a high power microwave pulse these electrons would gain enough kinetic energy and further escalate avalanche ionization of air due to elastic electron-neutral collisions thereby causing an increased volumetric discharge region. An X-band relativistic backward wave oscillator(RBWO) at the Pulsed Power,Beams and Microwaves laboratory at UNM is constructed as the microwave source. The RBWO produces a microwave pulse of maximum power 400 MW, frequency of 10.1 GHz, and energy of 6.8 Joules. Special care is being given to synchronize the RBWO and the pulsed laser system in order to achieve a high degree of spatial and temporal overlap. A photodiode and a microwave waveguide detector will be used to ensure the overlap. Also, a new shadowgraph technique with a nanosecond time resolution will be used to detect changes in the shock wave fronts when the HPM signal overlaps the laser pulse in time and space.

  5. Ionization of EPA contaminants in direct and dopant-assisted atmospheric pressure photoionization and atmospheric pressure laser ionization.

    Science.gov (United States)

    Kauppila, Tiina J; Kersten, Hendrik; Benter, Thorsten

    2015-06-01

    Seventy-seven EPA priority environmental pollutants were analyzed using gas chromatography-mass spectrometry (GC-MS) equipped with an optimized atmospheric pressure photoionization (APPI) and an atmospheric pressure laser ionization (APLI) interface with and without dopants. The analyzed compounds included e.g., polycyclic aromatic hydrocarbons (PAHs), nitro compounds, halogenated compounds, aromatic compounds with phenolic, acidic, alcohol, and amino groups, phthalate and adipatic esters, and aliphatic ethers. Toluene, anisole, chlorobenzene, and acetone were tested as dopants. The widest range of analytes was ionized using direct APPI (66/77 compounds). The introduction of dopants decreased the amount of compounds ionized in APPI (e.g., 54/77 with toluene), but in many cases the ionization efficiency increased. While in direct APPI the formation of molecular ions via photoionization was the main ionization reaction, dopant-assisted (DA) APPI promoted ionization reactions, such as charge exchange and proton transfer. Direct APLI ionized a much smaller amount of compounds than APPI (41/77 compounds), showing selectivity towards compounds with low ionization energies (IEs) and long-lived resonantly excited intermediate states. DA-APLI, however, was able to ionize a higher amount of compounds (e.g. 51/77 with toluene), as the ionization took place entirely through dopant-assisted ion/molecule reactions similar to those in DA-APPI. Best ionization efficiency in APPI and APLI (both direct and DA) was obtained for PAHs and aromatics with O- and N-functionalities, whereas nitro compounds and aliphatic ethers were the most difficult to ionize. Halogenated aromatics and esters were (mainly) ionized in APPI, but not in APLI.

  6. High quality electron beam acceleration by ionization injection in laser wakefields with mid-infrared dual-color lasers

    CERN Document Server

    Zeng, Ming; Chen, Min; Mori, Warren B; Sheng, Zheng-Ming; Hidding, Bernhard

    2016-01-01

    For the laser wakefield acceleration, suppression of beam energy spread while keeping sufficient charge is one of the key challenges. In order to achieve this, we propose bichromatic laser ionization injection with combined laser wavelengths of $2.4\\rm \\mu m$ and $0.8\\rm \\mu m$ for wakefield excitation and for triggering electron injection via field ionization, respectively. A laser pulse at $2.4\\rm \\mu m$ wavelength enables one to drive an intense acceleration structure with relatively low laser power. To further reduce the requirement of laser power, we also propose to use carbon dioxide as the working gas medium, where carbon acts as the injection element. Our full three dimensional particle-in-cell simulations show that electron beams at the GeV energy level with both low energy spreads (around one percent) and high charges (several tens of picocoulomb) can be obtained by this scheme with laser parameters achievable in the near future.

  7. Mass spectrometry of solid samples in open air using combined laser ionization and ambient metastable ionization

    Science.gov (United States)

    He, X. N.; Xie, Z. Q.; Gao, Y.; Hu, W.; Guo, L. B.; Jiang, L.; Lu, Y. F.

    2012-01-01

    Mass spectrometry of solid samples in open air was carried out using combined laser ionization and metastable ionization time-of-flight mass spectrometry (LI-MI-TOFMS) in ambient environment for qualitative and semiquantitative (relative analyte information, not absolute information) analysis. Ambient metastable ionization using a direct analysis in realtime (DART) ion source was combined with laser ionization time-of-flight mass spectrometry (LI-TOFMS) to study the effects of combining metastable and laser ionization. A series of metallic samples from the National Institute of Standards and Technology (NIST 494, 495, 498, 499, and 500) and a pure carbon target were characterized using LI-TOFMS in open air. LI-MI-TOFMS was found to be superior to laser-induced breakdown spectroscopy (LIBS). Laser pulse energies between 10 and 200 mJ at the second harmonic (532 nm) of an Nd:YAG laser were applied in the experiment to obtain a high degree of ionization in plasmas. Higher laser pulse energy improves signal intensities of trace elements (such as Fe, Cr, Mn, Ni, Ca, Al, and Ag). Data were analyzed by numerically calculating relative sensitivity coefficients (RSCs) and limit of detections (LODs) from mass spectrometry (MS) and LIBS spectra. Different parameters, such as boiling point, ionization potential, RSC, LOD, and atomic weight, were shown to analyze the ionization and MS detection processes in open air.

  8. LONGITUDINAL DISCH. CO2 LASER WITH PULSED PRE-IONIZATION

    Institute of Scientific and Technical Information of China (English)

    Yu Yanning; Wan Chongyi

    2002-01-01

    A novel pre-ionization scheme of helical transverse-pulsed pre-ionization in a longitudinal discharge CO2 laser is presented. The laser tube is made of glass with inner diameter of 7.5mm and discharge length of 50cm. The laser performance characteristics as functions of parameters, such as pressure, charging capacitance and applied voltage, are investigated. Compared with the same laser structure without pre-ionization, the maximum pulse energy improves by 23%, the optimum electro-optical efficiency increases by 31%, and the specific output energy reaches 26 J/(L·atm).

  9. Resonance ionization laser ion sources for on-line isotope separators (invited).

    Science.gov (United States)

    Marsh, B A

    2014-02-01

    A Resonance Ionization Laser Ion Source (RILIS) is today considered an essential component of the majority of Isotope Separator On Line (ISOL) facilities; there are seven laser ion sources currently operational at ISOL facilities worldwide and several more are under development. The ionization mechanism is a highly element selective multi-step resonance photo-absorption process that requires a specifically tailored laser configuration for each chemical element. For some isotopes, isomer selective ionization may even be achieved by exploiting the differences in hyperfine structures of an atomic transition for different nuclear spin states. For many radioactive ion beam experiments, laser resonance ionization is the only means of achieving an acceptable level of beam purity without compromising isotope yield. Furthermore, by performing element selection at the location of the ion source, the propagation of unwanted radioactivity downstream of the target assembly is reduced. Whilst advances in laser technology have improved the performance and reliability of laser ion sources and broadened the range of suitable commercially available laser systems, many recent developments have focused rather on the laser/atom interaction region in the quest for increased selectivity and/or improved spectral resolution. Much of the progress in this area has been achieved by decoupling the laser ionization from competing ionization processes through the use of a laser/atom interaction region that is physically separated from the target chamber. A new application of gas catcher laser ion source technology promises to expand the capabilities of projectile fragmentation facilities through the conversion of otherwise discarded reaction fragments into high-purity low-energy ion beams. A summary of recent RILIS developments and the current status of laser ion sources worldwide is presented.

  10. Ambient Femtosecond Laser Vaporization and Nanosecond Laser Desorption Electrospray Ionization Mass Spectrometry

    Science.gov (United States)

    Flanigan, Paul; Levis, Robert

    2014-06-01

    Recent investigations of ambient laser-based transfer of molecules into the gas phase for subsequent mass spectral analysis have undergone a renaissance resulting from the separation of vaporization and ionization events. Here, we seek to provide a snapshot of recent femtosecond (fs) duration laser vaporization and nanosecond (ns) duration laser desorption electrospray ionization mass spectrometry experiments. The former employs pulse durations of proteins, and even preserve the condensed phase of folded or unfolded protein structures according to the mass spectral charge state distribution, as demonstrated for cytochrome c and lysozyme. Because of the ability to vaporize and ionize multiple components from complex mixtures for subsequent analysis, near perfect classification of explosive formulations, plant tissue phenotypes, and even the identity of the manufacturer of smokeless powders can be determined by multivariate statistics. We also review the more mature field of nanosecond laser desorption for ambient mass spectrometry, covering the wide range of systems analyzed, the need for resonant absorption, and the spatial imaging of complex systems like tissue samples.

  11. Electrospray ionization and matrix assisted laser desorption/ionization mass spectrometry: powerful analytical tools in recombinant protein chemistry

    DEFF Research Database (Denmark)

    Andersen, Jens S.; Svensson, B; Roepstorff, P

    1996-01-01

    Electrospray ionization and matrix assisted laser desorption/ionization are effective ionization methods for mass spectrometry of biomolecules. Here we describe the capabilities of these methods for peptide and protein characterization in biotechnology. An integrated analytical strategy is presen......Electrospray ionization and matrix assisted laser desorption/ionization are effective ionization methods for mass spectrometry of biomolecules. Here we describe the capabilities of these methods for peptide and protein characterization in biotechnology. An integrated analytical strategy...

  12. Resonant- and avalanche-ionization amplification of laser-induced plasma in air

    Energy Technology Data Exchange (ETDEWEB)

    Wu, Yue; Zhang, Zhili, E-mail: zzhang24@utk.edu [Department of Mechanical, Aerospace and Biomedical Engineering, University of Tennessee, Knoxville, Tennessee 37996 (United States); Jiang, Naibo; Roy, Sukesh [Spectral Energies, LLC, 5100 Springfield St., Suite 301, Dayton, Ohio 45431 (United States); Gord, James R. [Air Force Research Laboratory, Aerospace Systems Directorate, Wright-Patterson Air Force Base, Ohio 45433 (United States)

    2014-10-14

    Amplification of laser-induced plasma in air is demonstrated utilizing resonant laser ionization and avalanche ionization. Molecular oxygen in air is ionized by a low-energy laser pulse employing (2 + 1) resonance-enhanced multi-photon ionization (REMPI) to generate seed electrons. Subsequent avalanche ionization of molecular oxygen and nitrogen significantly amplifies the laser-induced plasma. In this plasma-amplification effect, three-body attachments to molecular oxygen dominate the electron-generation and -loss processes, while either nitrogen or argon acts as the third body with low electron affinity. Contour maps of the electron density within the plasma obtained in O₂/N₂ and O₂/Ar gas mixtures are provided to show relative degrees of plasma amplification with respect to gas pressure and to verify that the seed electrons generated by O₂ 2 + 1 REMPI are selectively amplified by avalanche ionization of molecular nitrogen in a relatively low-pressure condition (≤100 Torr). Such plasma amplification occurring in air could be useful in aerospace applications at high altitude.

  13. Multivariate correction in laser-enhanced ionization with laser sampling

    Science.gov (United States)

    Popov, A. M.; Labutin, T. A.; Sychev, D. N.; Gorbatenko, A. A.; Zorov, N. B.

    2007-03-01

    The opportunity of normalizing laser-enhanced ionization (LEI) signals by several reference signals (RS) measured simultaneously has been examined in view of correcting variations of laser parameters and matrix interferences. Opto-acoustic, atomic emission and non-selective ionization signals and their paired combination were used as RS for Li determination in aluminum alloys (0-6% Mg, 0-5% Cu, 0-1% Sc, 0-1% Ag). The specific normalization procedure in case of RS essential multicollinearity has been proposed. LEI and RS for each definite ablation pulse energy were plotted in Cartesian co-ordinates ( x and y axes — the RS values, z axis — LEI signal). It was found that in the three-dimensional space the slope of the correlation line to the plane of RS depends on the analyte content in the solid sample. The use of this slope has therefore been proposed as a multivariate corrected analytical signal. Multivariate correlative normalization provides analytical signal free of matrix interferences for Al-Mg-Cu-Li alloys. The application of this novel approach to the determination of Li allows plotting unified calibration curves for Al-alloys of different matrix composition.

  14. Multivariate correction in laser-enhanced ionization with laser sampling

    Energy Technology Data Exchange (ETDEWEB)

    Popov, A.M. [Department of Chemistry, M. V. Lomonosov Moscow State University, 119992 Russia Moscow GSP-2, Leninskie Gory 1 build.3 (Russian Federation); Labutin, T.A. [Department of Chemistry, M. V. Lomonosov Moscow State University, 119992 Russia Moscow GSP-2, Leninskie Gory 1 build.3 (Russian Federation)], E-mail: timurla@laser.chem.msu.ru; Sychev, D.N.; Gorbatenko, A.A.; Zorov, N.B. [Department of Chemistry, M. V. Lomonosov Moscow State University, 119992 Russia Moscow GSP-2, Leninskie Gory 1 build.3 (Russian Federation)

    2007-03-15

    The opportunity of normalizing laser-enhanced ionization (LEI) signals by several reference signals (RS) measured simultaneously has been examined in view of correcting variations of laser parameters and matrix interferences. Opto-acoustic, atomic emission and non-selective ionization signals and their paired combination were used as RS for Li determination in aluminum alloys (0-6% Mg, 0-5% Cu, 0-1% Sc, 0-1% Ag). The specific normalization procedure in case of RS essential multicollinearity has been proposed. LEI and RS for each definite ablation pulse energy were plotted in Cartesian co-ordinates (x and y axes - the RS values, z axis - LEI signal). It was found that in the three-dimensional space the slope of the correlation line to the plane of RS depends on the analyte content in the solid sample. The use of this slope has therefore been proposed as a multivariate corrected analytical signal. Multivariate correlative normalization provides analytical signal free of matrix interferences for Al-Mg-Cu-Li alloys. The application of this novel approach to the determination of Li allows plotting unified calibration curves for Al-alloys of different matrix composition.

  15. Current developments with TRIUMF’s titanium-sapphire laser based resonance ionization laser ion source

    Energy Technology Data Exchange (ETDEWEB)

    Lassen, J., E-mail: LASSEN@triumf.ca; Li, R. [TRIUMF (Canada); Raeder, S. [GSI Helmholtzzentrum für Schwerionenforschung GmbH (Germany); Zhao, X.; Dekker, T. [TRIUMF (Canada); Heggen, H. [GSI Helmholtzzentrum für Schwerionenforschung GmbH (Germany); Kunz, P.; Levy, C. D. P.; Mostanmand, M.; Teigelhöfer, A.; Ames, F. [TRIUMF (Canada)

    2017-11-15

    Developments at TRIUMF’s isotope separator and accelerator (ISAC) resonance ionization laser ion source (RILIS) in the past years have concentrated on increased reliability for on-line beam delivery of radioactive isotopes to experiments, as well as increasing the number of elements available through resonance ionization and searching for ionization schemes with improved efficiency. The current status of these developments is given with a list of two step laser ionization schemes implemented recently.

  16. Modeling the early ionization of dielectrics by ultrashort laser pulses

    OpenAIRE

    Bourgeade, Antoine; Mézel, Candice; Saut, Olivier

    2010-01-01

    International audience; In this paper, we present a model for propagation of intense and ultrashort laser pulses ionizing dielectrics. We consider early ion- ization so that this process is sufficiently weak to avoid requiring a complete description of the ionization process (e.g. the use of ki- netic equations which are very expensive from a computational point of view). As the intensity of the field is small, one photon ioniza- tion is neglected. Ionization may only occur through multi-phot...

  17. Selective enhancement of resonant multiphoton ionization with strong laser fields

    CERN Document Server

    Li, Min; Luo, Siqiang; Zhou, Yueming; Zhang, Qingbin; Lan, Pengfei; Lu, Peixiang

    2015-01-01

    High-resolution photoelectron momentum distributions of Xe atom ionized by 800-nm linearly polarized laser fields have been traced at intensities from 1.1*1013 W/cm2 to 3.5*1013 W/cm2 using velocity-map imaging techniques. At certain laser intensities, the momentum spectrum exhibits a distinct double-ring structure for low-order above-threshold ionization, which appears to be absent at lower or higher laser intensities. By investigating intensity-resolved photoelectron energy spectrum, we find that this double-ring structure originates from resonant multiphoton ionization involving multiple Rydberg states of atoms. Varying the laser intensity, we can selectively enhance multiphoton excitation of atomic Rydberg populations. The photoelectron angular distributions of multiphoton resonance are also investigated for the low-order above threshold ionization.

  18. The first experience with LHC beam gas ionization monitor

    CERN Document Server

    Sapinski, M; Dehning, B; Guerrero, A; Patecki, M; Versteegen, R

    2012-01-01

    The Beam Gas Ionization Monitors (BGI) are used to measure beam emittance on LHC. This paper describes the detectors and their operation and discusses the issues met during the commissioning. It also discusses the various calibration procedures used to correct for non-uniformity of Multi-Channel plates and to correct the beam size for effects affecting the electron trajectory after ionization.

  19. Interpreting tunneling time in circularly polarized strong-laser ionization

    CERN Document Server

    Yuan, MingHu; Chu, TianShu; Liu, HongPing

    2016-01-01

    We propose a method to study the tunneling process by analyzing the time-dependent ionization yield in circularly polarized laser. A numerical calculation shows that for an atom exposed to a long laser pulse, if its initial electronic state wave function is non-spherical symmetric, the delayed phase shift of the ionization rate vs. the laser cycle period in real time in the region close to the peak intensity of the laser pulse can be used to probe the tunneling time. In this region, an obvious delay phase shift is observed, showing the tunneling time is in order of tens of attoseconds. Further study shows the atom has a longer tunneling time in the ionization under a shorter wavelength laser pulse. In our method, a Wigner rotation technique is employed to numerically solve the time-dependent Schr\\"odinger equation of a single-active-electron in a three dimensional spherical coordinate system.

  20. Ionization-injected electron acceleration with sub-terawatt laser pulses

    Science.gov (United States)

    Feder, Linus; Goers, Andy; Hine, George; Miao, Bo; Salehi, Fatholah; Woodbury, Daniel; Milchberg, Howard

    2016-10-01

    The vast majority of laser wakefield acceleration (LWFA) experiments use drive lasers with peak powers >10 TW and repetition rates from 10 Hz to less than once an hour. However, it was recently demonstrated that by using a thin, high density gas target, LWFA can be driven by laser pulses well below a TW and with high repetition rates. We present experiments and particle-in-cell (PIC) simulations of the effect of doping the high density gas jet with higher Z molecules (here nitrogen). Our earlier experiments with low-Z gas relied on self-injection of electrons into the accelerating wake through wave-breaking. In ionization injection, the relativistically self-focused laser pulse ionizes the inner shell of the dopant inside the plasma wake. High energy electrons are then trapped by the wakefield in the earliest potential buckets, which overlap with the laser pulse. PIC simulations show acceleration of these electrons by LWFA and directly by the laser pulse, with the direct contribution significantly increasing the electron energy beyond the LWFA contribution alone. Additionally, ionization injection can be controlled to prevent dephasing of the electron beam, resulting in a narrower energy spectrum and lower spatial divergence. This research is supported by the Department of Energy and the National Science Foundation.

  1. Discharge processes of UV pre-ionized electric-discharge pulsed DF laser

    Science.gov (United States)

    Pan, Qikun; Xie, Jijiang; Shao, Chunlei; Wang, Chunrui; Shao, Mingzhen; Guo, Jin

    2016-03-01

    The discharge processes of ultraviolet (UV) pre-ionized electric-discharge pulsed DF laser operating with a SF6-D2 gas mixture are studied. A mathematical model based on continuity equation of electrons and Kirchhoff equations for discharge circuit is established to describe the discharge processes. Voltage and current waveforms of main discharge and voltage waveforms of pre-ionization are solved numerically utilizing the model. The calculations correctly display some physical processes, such as the delay time between pre-ionization and main discharge, breakdown of the main electrode and self-sustained volume discharge (SSVD). The results of theory are consistent with the experiments, which are performed in our non-chain pulsed DF laser. Then the delay inductance and peak capacitance are researched to analyze their influences on discharge processes, and the circuit parameters of DF laser are given which is useful to improve the discharge stability.

  2. Multiphoton Ionization Detection in Collinear Laser Spectroscopy of Isolde Beams

    CERN Multimedia

    2002-01-01

    The experiments using the multiphoton ionization technique have been continued in the beginning of 1990 with stable beam tests on the modified apparatus and with another radioactive beam time on Yb. Higher laser power and an increased vacuum in the ionization region (see figure) yielded a further gain in sensitivity, mainly due to the better suppression of the background ions produced in rest gas collisions. For even Yb isotopes we have now reached a detection efficiency of $\\epsilon$~=~1~x~10$^{-5}$ ions per incoming atom at a background count rate of 30~ions from a beam of 5~x~10$^9$. This sensitivity was high enough for spectroscopy on $^{157}$Yb, where the typical ISOLDE yield of 5~x~10$^7$Yb ions is covered by an isobaric contamination of more than 10$^{10}$ ions. Measurements have also been performed on $^{175}$Yb. These give the first precise value for the magnetic moment of this isotope, $\\mu$~=~0.766(8)$ mu _{N} $, which agrees rather well with the magnetic moment of the isotone $^{177}$Hf. The isoto...

  3. Search for efficient laser resonance ionization schemes of tantalum using a newly developed time-of-flight mass-spectrometer in KISS

    Science.gov (United States)

    Mukai, M.; Hirayama, Y.; Ishiyama, H.; Jung, H. S.; Miyatake, H.; Oyaizu, M.; Watanabe, Y. X.; Kimura, S.; Ozawa, A.; Jeong, S. C.; Sonoda, T.

    2016-06-01

    The technique of laser resonance ionization is employed for an element-selective ionization of multi-nucleon transfer reaction products which are stopped and neutralized in a gas cell filled with argon gas at 50 kPa. We have been searching for efficient laser ionization schemes for refractory elements of Z = 73-78 using a time-of-flight mass-spectrometer (TOF-MS) chamber. To evaluate the isotope shift and ionization efficiency for each candidate of the ionization scheme, isotope separation using the TOF-MS was devised. The TOF-MS was designed to separate the isotopes using two-stage linear acceleration with a mass resolving power M / ΔM of >350. A mass resolving power of 250 was experimentally confirmed by measuring the TOF of laser-ionized tantalum (Z = 73) ions with mass number 181. We searched for a laser resonance ionization scheme of tantalum using the TOF-MS.

  4. Resonance ionization spectroscopy using ultraviolet laser

    CERN Document Server

    Han, J M; Ko, D K; Park, H M; Rhee, Y J

    2002-01-01

    In this study, Ti:sapphire laser which is pumped by the enhanced Nd:YAG laser using laser diode, was designed and manufactured. The AO Q-switched CW Nd:YAG laser was converted into a high repetition plus-type laser using the AO Q-switch, and two heads were installed inside the cavity in order to improve the laser beam quality. The Nd:YAG laser enhancement was completed by optimization using a simulation for the cavity length, structure and thermal lens effect that greatly effected the laser beam output and quality. As the result of the enhancement, a 30W laser at 532nm and at 5k-Hz was successfully made. Also, the Ti:sapphire laser that will be used for atomic spectroscopy which is pumped by the Nd:YAG laser, was completely designed. As a basic experiment for laser oscillation. We measured the tunability of the laser, and it turned out that the wave tunability range was 730 850 nm. A self-seeding type tunable laser using grating for narrow line width, is planned to be designed due to the fact that the Ti:sapp...

  5. In-Source Laser Resonance Ionization at ISOL Facilities

    CERN Document Server

    Marsh, Bruce; Feddosseev, Valentin

    Resonance ionization laser ion source development has been carried out at two radioactive ion beam facilities: ISOLDE (CERN, Switzerland) and the IGISOL facility (Jyvaskyla, Finland). The scope of the Resonance Ionization Laser Ion Source has been extended to 27 elements with the development of new three-step ionization schemes for Sb, Sc, Dy, Y and Au. The efficiencies were determined to be in the range of 2 - 20 %. Additionally, a new two-step ionization scheme has been developed for bismuth in an off-line atomic beam unit. The scheme relies on ionization via a strong and broad auto-ionizing resonance at an energy of 63196.79 cm$^{−1}$. This scheme may offer an improvement over the existing RILIS efficiency and will be more convenient for use during resonance ionization spectroscopy of Bi isotopes. The RILIS can be used as a spectroscopic tool to probe features such as the hyperfine structures and the isotope-shifts of radioisotopes with low production rates. By coupling a laser scanning process that dire...

  6. Helium Ionization in the Diffuse Ionized Gas Surrounding UCH ii Regions

    Science.gov (United States)

    Anish Roshi, D.; Churchwell, E.; Anderson, L. D.

    2017-04-01

    We present measurements of the singly ionized helium-to-hydrogen ratio ({n}{{He}+}/{n}{{{H}}+}) toward diffuse gas surrounding three ultracompact H ii (UCH ii) regions: G10.15-0.34, G23.46-0.20, and G29.96-0.02. We observe radio recombination lines of hydrogen and helium near 5 GHz using the GBT to measure the {n}{{He}+}/{n}{{{H}}+} ratio. The measurements are motivated by the low helium ionization observed in the warm ionized medium and in the inner Galaxy diffuse ionized regions. Our data indicate that the helium is not uniformly ionized in the three observed sources. Helium lines are not detected toward a few observed positions in sources G10.15-0.34 and G23.46-0.20, and the upper limits of the {n}{{He}+}/{n}{{{H}}+} ratio obtained are 0.03 and 0.05, respectively. The selected sources harbor stars of type O6 or hotter as indicated by helium line detection toward the bright radio continuum emission from the sources with mean {n}{{He}+}/{n}{{{H}}+} value 0.06 ± 0.02. Our data thus show that helium in diffuse gas located a few parsecs away from the young massive stars embedded in the observed regions is not fully ionized. We investigate the origin of the nonuniform helium ionization and rule out the possibilities (a) that the helium is doubly ionized in the observed regions and (b) that the low {n}{{He}+}/{n}{{{H}}+} values are due to additional hydrogen ionizing radiation produced by accreting low-mass stars. We find that selective absorption of ionizing photons by dust can result in low helium ionization but needs further investigation to develop a self-consistent model for dust in H ii regions.

  7. The Application of Resonance-Enhanced Multiphoton Ionization Technique in Gas Chromatography Mass Spectrometry

    Directory of Open Access Journals (Sweden)

    Adan Li

    2014-01-01

    Full Text Available Gas chromatography resonance-enhanced multiphoton ionization time-of-flight mass spectrometry (GC/REMPI-TOFMS using a nanosecond laser has been applied to analyze the 16 polycyclic aromatic hydrocarbons (PAHs. The excited-state lifetime, absorption characters, and energy of electronic states of the 16 PAHs were investigated to optimize the ionization yield. A river water sample pretreated by means of solid phase extraction was analyzed to evaluate the performance of the analytical instrument. The results suggested that REMPI is superior to electron impact ionization method for soft ionization and suppresses the background signal due to aliphatic hydrocarbons. Thus, GC/REMPI-TOFMS is a more reliable method for the determination of PAHs present in the environment.

  8. Laser desorption lamp ionization source for ion trap mass spectrometry.

    Science.gov (United States)

    Wu, Qinghao; Zare, Richard N

    2015-01-01

    A two-step laser desorption lamp ionization source coupled to an ion trap mass spectrometer (LDLI-ITMS) has been constructed and characterized. The pulsed infrared (IR) output of an Nd:YAG laser (1064 nm) is directed to a target inside a chamber evacuated to ~15 Pa causing desorption of molecules from the target's surface. The desorbed molecules are ionized by a vacuum ultraviolet (VUV) lamp (filled with xenon, major wavelength at 148 nm). The resulting ions are stored and detected in a three-dimensional quadrupole ion trap modified from a Finnigan Mat LCQ mass spectrometer operated at a pressure of ≥ 0.004 Pa. The limit of detection for desorbed coronene molecules is 1.5 pmol, which is about two orders of magnitude more sensitive than laser desorption laser ionization mass spectrometry using a fluorine excimer laser (157 nm) as the ionization source. The mass spectrum of four standard aromatic compounds (pyrene, coronene, rubrene and 1,4,8,11,15,18,22,25-octabutoxy-29H,31H-phthalocyanine (OPC)) shows that parent ions dominate. By increasing the infrared laser power, this instrument is capable of detecting inorganic compounds.

  9. The distribution of ionized gas in early-type galaxies

    Science.gov (United States)

    Buson, L. M.; Sadler, E. M.; Zeilinger, W. W.; Bertin, G.; Bertola, F.; Danzinger, J.; Dejonghe, H.; Saglia, R. P.; de Zeeuw, P. T.

    1993-12-01

    We present and discuss H-alpha+(N II) imaging observations of fifteen nearby elliptical and SO galaxies with extended optical emission lines. The morphology of the emitting regions suggests that the ionized gas usually lies in a disk which is often geometrically decoupled from the stellar body, as expected in a triaxial galaxy. The presence of a gaseous disk makes these galaxies suitable for testing their gravitational field in a straightforward way. The presence of dust in many of the disks, together with the observed morphological properties, suggests that the ionized gas in most of these galaxies is more closely associated with the cold Interstellar Medium (ISM) than with the hot X-ray component. The mass of ionized gas in the galaxies studied here is typically 10-100 times that in a 'normal' early-type galaxy of similar optical luminosity. These appear to be galaxies where an unusually high fraction of the cold gas has been ionized, rather than unusually gas-rich systems in an overall sense. The extra ionizing source may be related to an active nucleus, since the continuum radio emission from these galaxies is typically 10-15 times more powerful than in 'normal' ellipticals of the smae optical luminosity.

  10. Minimizing matrix effect by femtosecond laser ablation and ionization in elemental determination.

    Science.gov (United States)

    Zhang, Bochao; He, Miaohong; Hang, Wei; Huang, Benli

    2013-05-07

    Matrix effect is unavoidable in direct solid analysis, which usually is a leading cause of the nonstoichiometric effect in quantitative analysis. In this research, experiments were carried out to study the overall characteristics of atomization and ionization in laser-solid interaction. Both nanosecond (ns) and femtosecond (fs) lasers were applied in a buffer-gas-assisted ionization source coupled with an orthogonal time-of-flight mass spectrometer. Twenty-nine solid standards of ten different matrices, including six metals and four dielectrics, were analyzed. The results indicate that the fs-laser mode offers more stable relative sensitivity coefficients (RSCs) with irradiance higher than 7 × 10(13) W·cm(-2), which could be more reliable in the determination of element composition of solids. The matrix effect is reduced by half when the fs-laser is employed, owing to the fact that the fs-laser ablation and ionization (fs-LAI) incurs an almost heat-free ablation process and creates a dense plasma for the stable ionization.

  11. Laser-Induced Ionization Efficiency Enhancement On A Filament For Thermal Ionization Mass Spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Siegfried, M. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

    2015-10-14

    The evaluation of trace Uranium and Plutonium isotope ratios for nanogram to femtogram material quantities is a vital tool for nuclear counter-proliferation and safeguard activities. Thermal Ionization Mass Spectrometry (TIMS) is generally accepted as the state of the art technology for highly accurate and ultra-trace measurements of these actinide ratios. However, the very low TIMS ionization yield (typically less than 1%) leaves much room for improvement. Enhanced ionization of Nd and Sm from a TIMS filament was demonstrated using wavelength resonance with a nanosecond (pulse width) laser operating at 10 Hz when light was directed toward the filament.1 For this study, femtosecond and picosecond laser capabilities were to be employed to study the dissociation and ionization mechanisms of actinides/lanthanides and measure the enhanced ionization of the metal of interest. Since the underlying chemistry of the actinide/lanthanide carbides produced and dissociated on a TIMS filament is not well understood, the experimental parameters affecting the photodissociation and photoionization with one and two laser beams were to be investigated.

  12. Subcellular analysis by laser ablation electrospray ionization mass spectrometry

    Science.gov (United States)

    Vertes, Akos; Stolee, Jessica A; Shrestha, Bindesh

    2014-12-02

    In various embodiments, a method of laser ablation electrospray ionization mass spectrometry (LAESI-MS) may generally comprise micro-dissecting a cell comprising at least one of a cell wall and a cell membrane to expose at least one subcellular component therein, ablating the at least one subcellular component by an infrared laser pulse to form an ablation plume, intercepting the ablation plume by an electrospray plume to form ions, and detecting the ions by mass spectrometry.

  13. Laser fields in dynamically ionized plasma structures for coherent acceleration

    CERN Document Server

    Luu-Thanh, Ph.; Pukhov, A.; Kostyukov, I.

    2015-01-01

    With the emergence of the CAN (Coherent Amplification Network) laser technology, a new scheme for direct particle acceleration in periodic plasma structures has been proposed. By using our full electromagnetic relativistic particle-in-cell (PIC) simulation code equipped with ionisation module, we simulate the laser fields dynamics in the periodic structures of different materials. We study how the dynamic ionization influences the field structure.

  14. Measurement of the first ionization potential of astatine by laser ionization spectroscopy

    CERN Document Server

    Rothe, S; Antalic, S; Borschevsky, A; Capponi, L; Cocolios, T E; De Witte, H; Eliav, E; Fedorov, D V; Fedosseev, V N; Fink, D A; Fritzsche, S; Ghys, L; Huyse, M; Imai, N; Kaldor, U; Kudryavtsev, Yu; Köster, U; Lane, J; Lassen, J; Liberati, V; Lynch, K M; Marsh, B A; Nishio, K; Pauwels, D; Pershina, V; Popescu, L; Procter, T J; Radulov, D; Raeder, S; Rajabali, M M; Rapisarda, E; Rossel, R E; Sandhu, K; Seliverstov, M D; Sjödin, A M; Van den Bergh, P; Van Duppen, P; Venhart, M; Wakabayashi, Y; Wendt K D A

    2013-01-01

    The radioactive element astatine exists only in trace amounts in nature. Its properties can therefore only be explored by study of smallest quantities of artificially produced isotopes or by performing theoretical calculations. One of the most important properties influencing the chemical behaviour is the energy required to remove one electron from the valence shell, referred to as the ionization potential. Here we use laser spectroscopy to probe the optical spectrum of astatine near the ionization threshold. The observed series of Rydberg states enabled the first determination of the ionization potential of the astatine atom, 9.317510(8) eV. New ab initio calculations were performed to support the experimental result. The measured value serves as a benchmark for quantum chemistry calculations of the properties of astatine as well as for the theoretical prediction of the ionization potential of super-heavy element 117, the heaviest homologue of astatine.

  15. Intracellular protein mass spectroscopy using mid-infrared laser ionization

    Science.gov (United States)

    Awazu, K.; Suzuki, S.

    2007-07-01

    Large-scale analysis of proteins, which can be regarded as functional biomolecule, assumes an important role in the life science. A MALDI using an ultraviolet laser (UV-MALDI) is one of ionization methods without fragmentation and has achieved conformation analysis of proteins. Recently, protein analysis has shifted from conformation analysis to functional and direct one that reserves posttranslational modifications such as the sugar chain addition and phosphorylation. We have proposed a MALDI using a mid-infrared tunable laser (IR-MALDI) as a new ionization method. IR-MALDI is promising because most biomolecules have a specific absorption in mid-infrared range, and IR-MALDI is expected to offer; (1) use of various matrices, (2) use of biomolecules such as water and lipid as the matrix, and (3) super-soft ionization. First, we evaluated the wavelength dependence of ionization of different matrices using a difference frequency generation (DFG) laser, which can tune the wavelength within a range from 5.5 to 10.0 μm. As results, ionization was specifically occurred at 5.8 μm which the C=O vibration stretching bond in matrix material and mass spectrum was observed. Next, protein mass spectrum was observed in the culture cells, MIN6, which secrete insulin, without the conventional cell-preparation processes. We demonstrate that the IR-MALDI has an advantage over the conventional method (UV-MALDI) in direct analysis of intracellular proteins.

  16. A comparison of nano-electrospray gas-phase electrophoretic mobility macromolecular analysis and matrix-assisted laser desorption/ionization linear time-of-flight mass spectrometry for the characterization of the recombinant coagulation glycoprotein von Willebrand factor.

    Science.gov (United States)

    Kemptner, Jasmin; Marchetti-Deschmann, Martina; Müller, Roland; Ivens, Andreas; Turecek, Peter; Schwarz, Hans Peter; Allmaier, Günter

    2010-03-01

    Von Willebrand factor (VWF), an adhesive glycoprotein with an approximate molecular weight (MW) of the monomer of 260 kDa, circulates in human blood plasma as a series of multimers ranging in size up to 20.000 kDa; thus the determination of the accurate MW of the monomer is of great importance and due to its high MW quite challenging. In this study accurate MW determination of intact recombinant VWF monomer (rVWF) was performed with GEMMA (gas-phase electrophoretic mobility macromolecular analysis) and MALDI TOF MS (matrix-assisted laser desorption/ionization linear time-of-flight mass spectrometry). Three rVWF preparations with differing buffer systems and glycoprotein concentrations were analyzed. First investigations directed towards heterogeneity determination by means of capillary gel electrophoresis (CGE)-on-the-chip with a laser-induced fluorescence detector revealed two compounds (MW of 277 kDa (migration time 44.3 s) and 341 kDa (migration time 49.5 s)) present in each sample to varying extents, namely mature and pro-rVWF. MALDI MS analysis in the linear positive ion mode allowed the detection of mature rVWF with an exact MW of 256.1 kDa (+/-0.8%) and pro-rVWF with a MW of 349.8 kDa (+/-0.8%). Two samples containing pro-rVWF in very minor concentration resulted in GEMMA detection of the mature rVWF with a MW of 227.4 kDa (+/-2.5%), derived from the measured globular size of 10.9 nm. For one sample containing both rVWF species in almost equal concentrations no differentiation of the two species was possible with GEMMA. Due to its lower resolution only a peak representing a mixture of both species at 11.8 nm could be observed, yielding a MW of 298.8 kDa (+/-1.6%).

  17. Nonsequential double ionization with mid-infrared laser fields

    Science.gov (United States)

    Li, Ying-Bin; Wang, Xu; Yu, Ben-Hai; Tang, Qing-Bin; Wang, Guang-Hou; Wan, Jian-Guo

    2016-11-01

    Using a full-dimensional Monte Carlo classical ensemble method, we present a theoretical study of atomic nonsequential double ionization (NSDI) with mid-infrared laser fields, and compare with results from near-infrared laser fields. Unlike single-electron strong-field processes, double ionization shows complex and unexpected interplays between the returning electron and its parent ion core. As a result of these interplays, NSDI for mid-IR fields is dominated by second-returning electron trajectories, instead of first-returning trajectories for near-IR fields. Some complex NSDI channels commonly happen with near-IR fields, such as the recollision-excitation-with-subsequent-ionization (RESI) channel, are virtually shut down by mid-IR fields. Besides, the final energies of the two electrons can be extremely unequal, leading to novel e-e momentum correlation spectra that can be measured experimentally.

  18. Monitoring UF/sub 6/ photodissociation via laser multiphoton ionization

    Energy Technology Data Exchange (ETDEWEB)

    Stuke, M.; Reisler, H.; Wittig, C.

    1981-08-01

    Laser multiphoton ionization (MPI) is used to detect nascent photoproducts following the UV photodissociation of UF/sub 6/. Sensitivity is high, and there is no measurable background due to the MPI of parent UF/sub 6/. The technique is very well suited for monitoring isotopically selective photodissociation on a ''single shot'' basis.

  19. Ionization of molecular hydrogen in ultrashort intense laser pulses

    Energy Technology Data Exchange (ETDEWEB)

    Vanne, Yulian V.

    2010-03-18

    A novel ab initio numerical approach is developed and applied that solves the time-dependent Schroedinger equation describing two-electron diatomic molecules (e.g. molecular hydrogen) exposed to an intense ultrashort laser pulse. The method is based on the fixed-nuclei and the non-relativistic dipole approximations and aims to accurately describe both correlated electrons in full dimensionality. The method is applicable for a wide range of the laser pulse parameters and is able to describe both few-photon and many-photon single ionization processes, also in a non-perturbative regime. A key advantage of the method is its ability to treat the strong-field response of the molecules with arbitrary orientation of the molecular axis with respect to the linear-polarized laser field. Thus, this work reports on the first successful orientation-dependent analysis of the multiphoton ionization of H{sub 2} performed by means of a full-dimensional numerical treatment. Besides the investigation of few-photon regime, an extensive numerical study of the ionization by ultrashort frequency-doubled Ti:sapphire laser pulses (400 nm) is presented. Performing a series of calculations for different internuclear separations, the total ionization yields of H{sub 2} and D{sub 2} in their ground vibrational states are obtained for both parallel and perpendicular orientations. A series of calculations for 800 nm laser pulses are used to test a popular simple interference model. Besides the discussion of the ab initio numerical method, this work considers different aspects related to the application of the strong-field approximation (SFA) for investigation of a strong-field response of an atomic and molecular system. Thus, a deep analysis of the gauge problem of SFA is performed and the quasistatic limit of the velocity-gauge SFA ionization rates is derived. The applications of the length-gauge SFA are examined and a recently proposed generalized Keldysh theory is criticized. (orig.)

  20. Localization of ionization-induced trapping in a laser wakefield accelerator using a density down-ramp

    CERN Document Server

    Hansson, M.; Ekerfelt, H.; Aurand, B.; Gallardo Ganzalez, I.; Desforges, F. G.; Davoine, X.; Maitrallain, A.; Reymond, S.; Monot, P.; Persson, A.; Dobosz Dufrénoy S.; Wahlström C-G.; Cros, B.; Lundh, O.

    2016-01-01

    We report on a study on controlled trapping of electrons, by field ionization of nitrogen ions, in laser wakefield accelerators in variable length gas cells. In addition to ionization-induced trapping in the density plateau inside the cells, which results in wide, but stable, electron energy spectra, a regime of ionization-induced trapping localized in the density down-ramp at the exit of the gas cells, is found. The resulting electron energy spectra are peaked, with 10% shot-to-shot fluctuations in peak energy. Ionization-induced trapping of electrons in the density down-ramp is a way to trap and accelerate a large number of electrons, thus improving the efficiency of the laser-driven wakefield acceleration.

  1. Signature of superradiance from a nitrogen gas plasma channel produced by strong field ionization

    CERN Document Server

    Li, Guihua; Zeng, Bin; Xie, Hongqiang; Yao, Jinping; Chu, Wei; Ni, Jielei; Zhang, Haisu; Xu, Huailiang; Cheng, Ya; Xu, Zhizhan

    2013-01-01

    Recently, Yao et al. demonstrated the creation of coherent emissions in nitrogen gas with two-color (800 nm + 400 nm) ultrafast laser pulses [New J. Phys. 15, 023046 (2013)]. Based on this two-color scheme, here we report on systematic investigation of temporal characteristics of the coherent emission at 391 nm by experimentally examining its evolution with the increase of the plasma channel induced by the intense 800 nm femtosecond laser pulses at a nitrogen gas pressure of ~25 mbar. We reveal unexpected temporal profiles of the coherent emissions, which show significant superradiance signatures owing to the quantum coherence via cooperation of an ensemble of excited N2+ molecules. Our findings shed more light on the mechanisms behind the laser-like emissions induced by strong-field ionization of molecules.

  2. Similarity of ionized gas nebulae around unobscured and obscured quasars

    CERN Document Server

    Liu, Guilin; Greene, Jenny E

    2014-01-01

    Quasar feedback is suspected to play a key role in the evolution of massive galaxies, by removing or reheating gas in quasar host galaxies and thus limiting the amount of star formation. In this paper we continue our investigation of quasar-driven winds on galaxy-wide scales. We conduct Gemini Integral Field Unit spectroscopy of a sample of luminous unobscured (type 1) quasars, to determine the morphology and kinematics of ionized gas around these objects, predominantly via observations of the [O III]5007 emission line. We find that ionized gas nebulae extend out to ~13 kpc from the quasar, that they are smooth and round, and that their kinematics are inconsistent with gas in dynamical equilibrium with the host galaxy. The observed morphological and kinematic properties are strikingly similar to those of ionized gas around obscured (type 2) quasars with matched [O III] luminosity, with marginal evidence that nebulae around unobscured quasars are slightly more compact. Therefore in samples of obscured and unob...

  3. Viscosity Coefficient Curve Fits for Ionized Gas Species Grant Palmer

    Science.gov (United States)

    Palmer, Grant; Arnold, James O. (Technical Monitor)

    2001-01-01

    Viscosity coefficient curve fits for neutral gas species are available from many sources. Many do a good job of reproducing experimental and computational chemistry data. The curve fits are usually expressed as a function of temperature only. This is consistent with the governing equations used to derive an expression for the neutral species viscosity coefficient. Ionized species pose a more complicated problem. They are subject to electrostatic as well as intermolecular forces. The electrostatic forces are affected by a shielding phenomenon where electrons shield the electrostatic forces of positively charged ions beyond a certain distance. The viscosity coefficient for an ionized gas species is a function of both temperature and local electron number density. Currently available curve fits for ionized gas species, such as those presented by Gupta/Yos, are a function of temperature only. What they did was to assume an electron number density. The problem is that the electron number density they assumed was unrealistically high. The purpose of this paper is two-fold. First, the proper expression for determining the viscosity coefficient of an ionized species as a function of both temperature and electron number density will be presented. Then curve fit coefficients will be developed using the more realistic assumption of an equilibrium electron number density. The results will be compared against previous curve fits and against highly accurate computational chemistry data.

  4. Strong-Field Ionization of Laser Cooled Li Atoms

    Science.gov (United States)

    Sharma, Sachin; Romans, Kevin; Fischer, Daniel

    2016-05-01

    Recently, our understanding of few-body effects has been substantially boosted by the development of intense femto- and attosecond laser sources. Observing the momenta of the fragments of atoms and molecules ionized in these strong fields provided new and before inconceivable insights in molecular and electronic dynamics. Here, we report on a new experiment, where the target atoms (6 Li) are laser cooled and trapped using a magneto optical trap (MOT). Momentum vectors of the target fragments will be measured using a reaction microscope (ReMi). The exclusivity of this setup is a combination of MOT and ReMi, thus dubbed as MOTReMi. Here, the advantages over standard COLTRIMS systems are multifold: Firstly, an unprecedented recoil ion momentum resolution can be achieved, as the target can be prepared at significantly lower temperatures. Second, the atoms can be optically prepared in the ground or in polarized excited states. In a first experimental campaign, studies on single ionization of laser excited and polarized Lithium atoms will be performed with circularly polarized light. This experiment can provide insight into the helicity-dependence of the ionization dynamics as the differences among co- and counter rotating electron and laser field, if any, can be investigated.

  5. Laser interferometry of radiation driven gas jets

    Science.gov (United States)

    Swanson, Kyle James; Ivanov, Vladimir; Mancini, Roberto; Mayes, Daniel C.

    2017-06-01

    In a series of experiments performed at the 1MA Zebra pulsed power accelerator of the Nevada Terawatt Facility nitrogen gas jets were driven with the broadband x-ray flux produced during the collapse of a wire-array z-pinch implosion. The wire arrays were comprised of 4 and 8, 10μm-thick gold wires and 17μm-thick nickel wires, 2cm and 3cm tall, and 0.3cm in diameter. They radiated 12kJ to 16kJ of x-ray energy, most of it in soft x-ray photons of less than 1keV of energy, in a time interval of 30ns. This x-ray flux was used to drive a nitrogen gas jet located at 0.8cm from the axis of the z-pinch radiation source and produced with a supersonic nozzle. The x-ray flux ionizes the nitrogen gas thus turning it into a photoionized plasma. We used laser interferometry to probe the ionization of the plasma. To this end, a Mach-Zehnder interferometer at the wavelength of 266 nm was set up to extract the atom number density profile of the gas jet just before the Zebra shot, and air-wedge interferometers at 266 and 532 nm were used to determine the electron number density of the plasma right during the Zebra shot. The ratio of electron to atom number densities gives the distribution of average ionization state of the plasma. A python code was developed to perform the image data processing, extract phase shift spatial maps, and obtain the atom and electron number densities via Abel inversion. Preliminary results from the experiment are promising and do show that a plasma has been created in the gas jet driven by the x-ray flux, thus demonstrating the feasibility of a new experimental platform to study photoionized plasmas in the laboratory. These plasmas are found in astrophysical scenarios including x-ray binaries, active galactic nuclei, and the accretion disks surrounding black holes1. This work was sponsored in part by DOE Office of Science Grant DE-SC0014451.1R. C. Mancini et al, Phys. Plasmas 16, 041001 (2009)

  6. Photo-triggering and secondary electron produced ionization in electric discharge ArF* excimer lasers

    Science.gov (United States)

    Xiong, Zhongmin; Kushner, Mark J.

    2011-10-01

    Electric discharge excimer lasers are sustained in multi-atmosphere attaching gas mixtures that are typically preionized to enable a reproducible, uniform glow, which maximizes optical quality and gain. This preionization is often accomplished using UV light produced by a corona discharge within the plasma cavity. To quantify the relationship between corona discharge properties and those of the laser discharge, the triggering of electron avalanche by preionizing UV light in an electric discharge-pumped ArF* excimer laser was numerically investigated using a two-dimensional model. The preionizing UV fluxes were generated by a corona-bar discharge driven by the same voltage pulse as the main discharge sustained in a multi-atmospheric Ne/Ar/Xe/F2 gas mixture. The resulting peak photo-electron density in the inter-electrode spacing is around 108 cm-3, and its distribution is biased toward the UV source. The preionization density increases with increasing dielectric constant and capacitance of the corona bar. The symmetry and uniformity of the discharge are, however, improved significantly once the main avalanche develops. In addition to bulk electron impact ionization, the ionization generated by sheath accelerated secondary electrons was found to be important in sustaining the discharge current at experimentally observed values. At peak current, the magnitude of the ionization by sheath accelerated electrons is comparable to that from bulk electron impact in the vicinity of the cathode.

  7. The formation and physical origin of highly ionized cooling gas

    CERN Document Server

    Bordoloi, Rongmon; Norman, Colin A

    2016-01-01

    We present a physically clear cooling flow theory that explains the origin of warm diffuse gas seen primarily as highly ionized absorption line systems in the spectra of background sources. We predict the observed column densities of several highly ionized transitions such as O VI, O VII, Ne VIII, N V, and Mg X; and present a unified comparison of the model predictions with absorption lines seen in the Milky Way disk, Milky Way halo, starburst galaxies, the circumgalactic medium and the intergalactic medium at low and high redshifts. We show that diffuse gas seen in such diverse environments can be simultaneously explained by a simple model of radiatively cooling gas. We show that most of such absorption line systems are consistent with being collisionally ionized, and estimate the maximum likelihood temperature of the gas in each observation. This model satisfactorily explains why O VI is regularly observed around star-forming low-z L* galaxies, and why N V is rarely seen around the same galaxies. We predict...

  8. Off-line studies of the laser ionization of yttrium at the IGISOL facility

    CERN Document Server

    Kessler, T; Kudryavtsev, Y; Peräjärvi, K; Popov, A; Ronkanen, P; Sonoda, T; Tordoff, B; Wendt, K D A; Äystö, J

    2007-01-01

    A laser ion source is under development at the IGISOL facility, Jyvaskyla, in order to address deficiencies in the ion guide technique. The key elements of interest are those of a refractory nature, whose isotopes and isomers are widely studied using both laser spectroscopic and high precision mass measurement techniques. Yttrium has been the first element of choice for the new laser ion source. In this work we present a new coupled dye-Ti:Sapphire laser scheme and give a detailed discussion of the results obtained from laser ionization of yttrium atoms produced in an ion guide via joule heating of a filament. The importance of not only gas purity, but indeed the baseline vacuum pressure in the environment outside the ion guide is discussed in light of the fast gas phase chemistry seen in the yttrium system. A single laser shot model is introduced and is compared to the experimental data in order to extract the level of impurities within the gas cell.

  9. Subcycle engineering of laser filamentation in gas by harmonic seeding

    CERN Document Server

    Béjot, P; Billard, F; Doussot, J; Hertz, E; Lavorel, B; Faucher, O

    2014-01-01

    Manipulating at will the propagation dynamics of high power laser pulses is a long-standing dream whose accomplishment would lead to the control of a plethora of fascinating physical phenomena emerging from laser-matter interaction. The present work represents a significant step towards such an ideal control by manipulating the nonlinear optical properties of the gas medium at the quantum level. This is accomplished by engineering the intense laser pulse experiencing filamentation at the subcycle level with a relatively weak (about 1%) third-harmonic radiation. The control results from quantum interferences between a single and a two-color (mixing the fundamental frequency with its 3rd harmonic) ionization channel. This mechanism, which depends on the relative phase between the two electric fields, is responsible for wide refractive index modifications in relation with significant enhancement or suppression of the ionization rate. As a first application, we demonstrate the production and control of an axially...

  10. FIELD IONIZATION OF MOLECULES IN AN INTENSE LASER FIELD

    Institute of Scientific and Technical Information of China (English)

    吴成印; 龚旗煌

    2001-01-01

    In order to predict the field ionization probabilities, the accurate ab initio electrostatic potential of molecules has to be calculated. However, the calculation of the full ab initio electrostatic potential of molecules is complicated,even impossible for some larger molecules with low symmetry. Here, we present a semi-empirical model to treat the field ionization of molecules in an intense laser field. In this model, a modified Coulomb potential is used to take the place of the complicated ab initio electrostatic potential of molecules. The analytic equations of the Keldysh adiabatic parameter using the Coulomb potential and the modified Coulomb potential have first been given. Using our semiempirical model, we have calculated the field ionization probabilities and the Keldysh adiabatic parameters of O2,N2, SO2, C2H4, CH3CN and C6H6 in an intense laser field. The results agree excellently with the calculations using the ab initio electrostatic potential of molecules. As the modified parameter for the Coulomb potential can be found from experimental measurements, the field ionization mechanism of molecules can be immediately predicted with our semi-empirical model.

  11. ISO observations of the Galactic center Interstellar Medium: ionized gas

    CERN Document Server

    Rodríguez-Fernández, N J

    2004-01-01

    (Abridged) We present fine structure and recombination lines observations of the ionized gas toward a sample of 18 sources located within 300 pc of the center of the Galaxy (GC). The fine structure lines from [NII] and [SIII] have been detected in 16 sources. In 10 sources we have even detected the [OIII] 88 $\\mu$m line. The measured N, S and Ne abundances are similar to those measured in the HII regions in the 5-kpc ring and in the nuclei of starburst galaxies. The fine structure lines ratios measured for all the sources can be explained by photo-ionization with an effective temperature of 32000-37000 K and an ionization parameter, $U$, of $-1>\\log U > -3$. The highest excitation is found in the Radio Arc region but there must be more ionizing sources distributed over the Galactic center than the known clusters of massive stars. Most of the clouds are located far from the prominent continuum complexes (Sgr C, B ...). However, it is possible that the clouds are ionized by escaped photons from those complexes....

  12. Collisional line broadening using laser excitation and ionization

    Energy Technology Data Exchange (ETDEWEB)

    Nayfeh, M.H.; Hurst, G.S.; Payne, M.G.; Young, J.P.

    1977-09-05

    A laser excitation and ionization process is used to measure Cs-Ar interaction forces at long range. With energy densities of 1 J/cm/sup 2/, nonlinear excitation persists as far out as 70 A at one atmosphere of Ar. This method provides extreme sensitivity (even single absorption events can be measured) which allows absolute measurements on the very far wing where absorption or fluorescence becomes vanishingly small.

  13. Ionized gas at the edge of the central molecular zone

    Science.gov (United States)

    Langer, W. D.; Goldsmith, P. F.; Pineda, J. L.; Velusamy, T.; Requena-Torres, M. A.; Wiesemeyer, H.

    2015-04-01

    Context. The edge of the central molecular zone (CMZ) is the location where massive dense molecular clouds with large internal velocity dispersions transition to the surrounding more quiescent and lower CO emissivity region of the Galaxy. Little is known about the ionized gas surrounding the molecular clouds and in the transition region. Aims: We determine the properties of the ionized gas at the edge of the CMZ near Sgr E using observations of N+ and C+. Methods: We observed a small portion of the edge of the CMZ near Sgr E with spectrally resolved [C ii] 158 μm and [N ii] 205 μm fine structure lines at six positions with the GREAT instrument on SOFIA and in [C ii] using Herschel HIFI on-the-fly strip maps. We use the [N ii] spectra along with a radiative transfer model to calculate the electron density of the gas and the [C ii] maps to illuminate the morphology of the ionized gas and model the column density of CO-dark H2. Results: We detect two [C ii] and [N ii] velocity components, one along the line of sight to a CO molecular cloud at - 207 km s-1 associated with Sgr E and the other at -174 km s-1 outside the edge of another CO cloud. From the [N ii] emission we find that the average electron density is in the range of ~5 to 21 cm-3 for these features. This electron density is much higher than that of the disk's warm ionized medium, but is consistent with densities determined for bright diffuse H ii nebula. The column density of the CO-dark H2 layer in the -207 km s-1 cloud is ~1-2 × 1021 cm-2 in agreement with theoretical models. The CMZ extends further out in Galactic radius by ~7 to 14 pc in ionized gas than it does in molecular gas traced by CO. Conclusions: The edge of the CMZ likely contains dense hot ionized gas surrounding the neutral molecular material. The high fractional abundance of N+ and high electron density require an intense EUV field with a photon flux of order 106 to 107 photons cm-2 s-1, and/or efficient proton charge exchange with

  14. Developments towards in-gas-jet laser spectroscopy studies of actinium isotopes at LISOL

    Energy Technology Data Exchange (ETDEWEB)

    Raeder, S., E-mail: s.raeder@gsi.de [KU Leuven, Instituut voor Kern- en Stralingsfysica, Celestijnenlaan 200D, B-3001 Leuven (Belgium); Helmholtz-Institut Mainz, 55128 Mainz (Germany); GSI Helmholtzzentrum für Schwerionenforschung GmbH, Planckstraße 1, 64291 Darmstadt (Germany); Bastin, B. [GANIL, CEA/DSM-CNRS/IN2P3, B.P. 55027, 14076 Caen (France); Block, M. [Helmholtz-Institut Mainz, 55128 Mainz (Germany); GSI Helmholtzzentrum für Schwerionenforschung GmbH, Planckstraße 1, 64291 Darmstadt (Germany); Institut für Kernchemie, Johannes Gutenberg Universität, 55128 Mainz (Germany); Creemers, P. [KU Leuven, Instituut voor Kern- en Stralingsfysica, Celestijnenlaan 200D, B-3001 Leuven (Belgium); Delahaye, P. [GANIL, CEA/DSM-CNRS/IN2P3, B.P. 55027, 14076 Caen (France); Ferrer, R. [KU Leuven, Instituut voor Kern- en Stralingsfysica, Celestijnenlaan 200D, B-3001 Leuven (Belgium); Fléchard, X. [LPC Caen, ENSICAEN, Université de Caen, CNRS/IN2P3, Caen (France); Franchoo, S. [Institute de Physique Nucléaire (IPN) d’Orsay, 91406 Orsay, Cedex (France); Ghys, L. [KU Leuven, Instituut voor Kern- en Stralingsfysica, Celestijnenlaan 200D, B-3001 Leuven (Belgium); SCK-CEN, Belgian Nuclear Research Center, Boeretang 200, 2400 Mol (Belgium); Gaffney, L.P.; Granados, C. [KU Leuven, Instituut voor Kern- en Stralingsfysica, Celestijnenlaan 200D, B-3001 Leuven (Belgium); Heinke, R. [Institut für Physik, Johannes Gutenberg Universität, 55128 Mainz (Germany); Hijazi, L. [GANIL, CEA/DSM-CNRS/IN2P3, B.P. 55027, 14076 Caen (France); and others

    2016-06-01

    To study exotic nuclides at the borders of stability with laser ionization and spectroscopy techniques, highest efficiencies in combination with a high spectral resolution are required. These usually opposing requirements are reconciled by applying the in-gas-laser ionization and spectroscopy (IGLIS) technique in the supersonic gas jet produced by a de Laval nozzle installed at the exit of the stopping gas cell. Carrying out laser ionization in the low-temperature and low density supersonic gas jet eliminates pressure broadening, which will significantly improve the spectral resolution. This article presents the required modifications at the Leuven Isotope Separator On-Line (LISOL) facility that are needed for the first on-line studies of in-gas-jet laser spectroscopy. Different geometries for the gas outlet and extraction ion guides have been tested for their performance regarding the acceptance of laser ionized species as well as for their differential pumping capacities. The specifications and performance of the temporarily installed high repetition rate laser system, including a narrow bandwidth injection-locked Ti:sapphire laser, are discussed and first preliminary results on neutron-deficient actinium isotopes are presented indicating the high capability of this novel technique.

  15. Ionizing gas breakdown waves in strong electric fields.

    Science.gov (United States)

    Klingbeil, R.; Tidman, D. A.; Fernsler, R. F.

    1972-01-01

    A previous analysis by Albright and Tidman (1972) of the structure of an ionizing potential wave driven through a dense gas by a strong electric field is extended to include atomic structure details of the background atoms and radiative effects, especially, photoionization. It is found that photoionization plays an important role in avalanche propagation. Velocities, electron densities, and temperatures are presented as a function of electric field for both negative and positive breakdown waves in nitrogen.

  16. Ionized gas at the edge of the Central Molecular Zone

    CERN Document Server

    Langer, W D; Pineda, J L; Velusamy, T; Requena-Torres, M A; Wiesemeyer, H

    2015-01-01

    To determine the properties of the ionized gas at the edge of the CMZ near Sgr E we observed a small portion of the edge of the CMZ near Sgr E with spectrally resolved [C II] 158 micron and [N II] 205 micron fine structure lines at six positions with the GREAT instrument on SOFIA and in [C II] using Herschel HIFI on-the-fly strip maps. We use the [N II] spectra along with a radiative transfer model to calculate the electron density of the gas and the [C II] maps to illuminate the morphology of the ionized gas and model the column density of CO-dark H2. We detect two [C II] and [N II] velocity components, one along the line of sight to a CO molecular cloud at -207 km/s associated with Sgr E and the other at -174 km/s outside the edge of another CO cloud. From the [N II] emission we find that the average electron density is in the range of about 5 to 25 cm{-3} for these features. This electron density is much higher than that of the warm ionized medium in the disk. The column density of the CO-dark H$_2$ layer ...

  17. Outflows of neutral (and ionized) gas in radio galaxies

    OpenAIRE

    Morganti, R.; Oosterloo, T.; Tadhunter, C.

    2004-01-01

    Outflows up to 1500 km/s of atomic neutral hydrogen are detected in a growing number of radio galaxies. Outflows with similar velocities are also detected in ionized gas, suggesting a common origin for the extreme kinematics of these two phases of the gas. The high detection rate ofsuch outflows in young (or restarted) radio sources appears to be related to the existence of a dense ISM around these objects. Such a dense ISM can have important consequences for the evolution of the radio source...

  18. Influence of laser intensity on the double-resonance multiphoton ionization process of NO molecule

    Institute of Scientific and Technical Information of China (English)

    Guiyin Zhang; Yidong Jin

    2008-01-01

    The analytic forrnula of the ionization efficiency in the process of double resonance enhanced multi-photon ionization (DREMPI) is derived from the dynamic rate equation about the interaction of photon and material. Based on rids formula, the ionization efficiency arid the laser power index versus laser intensity in the DREMPI process of NO molecule, via A2∑ and S2∑ intermediate resonant states, is numerically sinnllated. It is shown that the ionization efficiency of NO molecule increases with the laser intensity until getting saturation, while the laser power index decreases with the enhancement of the laser intensity arid changes to zero at last. The variation of the laser power index with the laser intensity indicates that the ionization efficiency reaches saturation in the one, two, and three excitation steps respectively. It is also found that the narrower the laser pulse duration is, the higher becomes the laser intensity for saturation.

  19. Turbulence in the ionized gas of the Orion nebula

    Science.gov (United States)

    Arthur, S. J.; Medina, S.-N. X.; Henney, W. J.

    2016-12-01

    In order to study the nature, origin, and impact of turbulent velocity fluctuations in the ionized gas of the Orion nebula, we apply a variety of statistical techniques to observed velocity cubes. The cubes are derived from high resolving power (R ≈ 40 000) longslit spectroscopy of optical emission lines that span a range of ionizations. From velocity channel analysis (VCA), we find that the slope of the velocity power spectrum is consistent with predictions of Kolmogorov theory between scales of 8 and 22 arcsec (0.02 to 0.05 pc). The outer scale, which is the dominant scale of density fluctuations in the nebula, approximately coincides with the autocorrelation length of the velocity fluctuations that we determine from the second-order velocity structure function. We propose that this is the principal driving scale of the turbulence, which originates in the autocorrelation length of dense cores in the Orion molecular filament. By combining analysis of the non-thermal linewidths with the systematic trends of velocity centroid versus ionization, we find that the global champagne flow and smaller scale turbulence each contribute in equal measure to the total velocity dispersion, with respective root-mean-square widths of 4-5 km s-1. The turbulence is subsonic and can account for only one half of the derived variance in ionized density, with the remaining variance provided by density gradients in photoevaporation flows from globules and filaments. Intercomparison with results from simulations implies that the ionized gas is confined to a thick shell and does not fill the interior of the nebula.

  20. Study of ionization process of matrix molecules in matrix-assisted laser desorption ionization

    Energy Technology Data Exchange (ETDEWEB)

    Murakami, Kazumasa; Sato, Asami; Hashimoto, Kenro; Fujino, Tatsuya, E-mail: fujino@tmu.ac.jp

    2013-06-20

    Highlights: ► Proton transfer and adduction reaction of matrix in MALDI were studied. ► Hydroxyl group forming intramolecular hydrogen bond was related to the ionization. ► Intramolecular proton transfer in the electronic excited state was the initial step. ► Non-volatile analytes stabilized protonated matrix in the ground state. ► A possible mechanism, “analyte support mechanism”, has been proposed. - Abstract: Proton transfer and adduction reaction of matrix molecules in matrix-assisted laser desorption ionization were studied. By using 2,4,6-trihydroxyacetophenone (THAP), 2,5-dihydroxybenzoic acid (DHBA), and their related compounds in which the position of a hydroxyl group is different, it was clarified that a hydroxyl group forming an intramolecular hydrogen bond is related to the ionization of matrix molecules. Intramolecular proton transfer in the electronic excited state of the matrix and subsequent proton adduction from a surrounding solvent to the charge-separated matrix are the initial steps for the ionization of matrix molecules. Nanosecond pump–probe NIR–UV mass spectrometry confirmed that the existence of analyte molecules having large dipole moment in their structures is necessary for the stabilization of [matrix + H]{sup +} in the electronic ground state.

  1. Turbulent dynamo in a conducting fluid and partially ionized gas

    CERN Document Server

    Xu, Siyao

    2016-01-01

    By following the Kazantsev theory and taking into account both microscopic and turbulent diffusion of magnetic fields, we develop a unified treatment of the kinematic and nonlinear stages of turbulent dynamo, and study the dynamo process for a full range of magnetic Prandtl number Pm and ionization fractions. We find a striking similarity between the dependence of dynamo behavior on Pm in a conducting fluid and R (a function of ionization fraction) in partially ionized gas. In a weakly ionized medium, the kinematic stage is largely extended, including not only exponential growth but a new regime of dynamo characterized by linear-in-time growth of magnetic field strength, and the resulting magnetic energy is much higher than the kinetic energy carried by viscous-scale eddies. Unlike the kinematic stage, the subsequent nonlinear stage is unaffected by microscopic diffusion processes and has a universal linear-in-time growth of magnetic energy with the growth rate as a constant fraction $3/38$ of the turbulent e...

  2. Laser resonance ionization spectroscopy on lutetium for the MEDICIS project

    Energy Technology Data Exchange (ETDEWEB)

    Gadelshin, V., E-mail: gadelshin@uni-mainz.de [University of Mainz, Institute of Physics (Germany); Cocolios, T. [KU Leuven, Institute for Nuclear and Radiation Physics (Belgium); Fedoseev, V. [CERN, EN Department (Switzerland); Heinke, R.; Kieck, T. [University of Mainz, Institute of Physics (Germany); Marsh, B. [CERN, EN Department (Switzerland); Naubereit, P. [University of Mainz, Institute of Physics (Germany); Rothe, S.; Stora, T. [CERN, EN Department (Switzerland); Studer, D. [University of Mainz, Institute of Physics (Germany); Duppen, P. Van [KU Leuven, Institute for Nuclear and Radiation Physics (Belgium); Wendt, K. [University of Mainz, Institute of Physics (Germany)

    2017-11-15

    The MEDICIS-PROMED Innovative Training Network under the Horizon 2020 EU program aims to establish a network of early stage researchers, involving scientific exchange and active cooperation between leading European research institutions, universities, hospitals, and industry. Primary scientific goal is the purpose of providing and testing novel radioisotopes for nuclear medical imaging and radionuclide therapy. Within a closely linked project at CERN, a dedicated electromagnetic mass separator system is presently under installation for production of innovative radiopharmaceutical isotopes at the new CERN-MEDICIS laboratory, directly adjacent to the existing CERN-ISOLDE radioactive ion beam facility. It is planned to implement a resonance ionization laser ion source (RILIS) to ensure high efficiency and unrivaled purity in the production of radioactive ions. To provide a highly efficient ionization process, identification and characterization of a specific multi-step laser ionization scheme for each individual element with isotopes of interest is required. The element lutetium is of primary relevance, and therefore was considered as first candidate. Three two-step excitation schemes for lutetium atoms are presented in this work, and spectroscopic results are compared with data of other authors.

  3. Physics of a partially ionized gas relevant to galaxy formation simulations -- the ionization potential energy reservoir

    CERN Document Server

    Vandenbroucke, Bert; Schroyen, Joeri; Jachowicz, Natalie

    2013-01-01

    Simulation codes for galaxy formation and evolution take on board as many physical processes as possible beyond the standard gravitational and hydrodynamical physics. Most of this extra physics takes place below the resolution level of the simulations and is added in a sub-grid fashion. However, these sub-grid processes affect the macroscopic hydrodynamical properties of the gas and thus couple to the on-grid physics that is explicitly integrated during the simulation. In this paper, we focus on the link between partial ionization and the hydrodynamical equations. We show that the energy stored in ions and free electrons constitutes a potential energy term which breaks the linear dependence of the internal energy on temperature. Correctly taking into account ionization hence requires modifying both the equation of state and the energy-temperature relation. We implemented these changes in the cosmological simulation code Gadget2. As an example of the effects of these changes, we study the propagation of Sedov-...

  4. Characterization of a Continuous Wave Laser for Resonance Ionization Mass Spectroscopy Analysis in Nuclear Forensics

    Science.gov (United States)

    2015-06-01

    OF A CONTINUOUS WAVE LASER FOR RESONANCE IONIZATION MASS SPECTROSCOPY ANALYSIS IN NUCLEAR FORENSICS by Sunny G. Lau June 2015 Thesis...IONIZATION MASS SPECTROSCOPY ANALYSIS IN NUCLEAR FORENSICS 5. FUNDING NUMBERS 6. AUTHOR(S) Sunny G. Lau 7. PERFORMING ORGANIZATION NAME(S) AND...200 words) The application of resonance ionization mass spectroscopy (RIMS) to nuclear forensics involves the use of lasers to selectively ionize

  5. Triggered star formation in giant HI supershells: ionized gas

    CERN Document Server

    Egorov, O V; Moiseev, A V

    2015-01-01

    We considered the regions of triggered star formation inside kpc-sized HI supershells in three dwarf galaxies: IC 1613, IC 2574 and Holmberg II. The ionized and neutral gas morphology and kinematics were studied based on our observations with scanning Fabry-Perot interferometer at the SAO RAS 6-m telescope and 21 cm archival data of THINGS and LITTLE THINGS surveys. The qualitative analysis of the observational data performed in order to highlight the two questions: why the star formation occurred very locally in the supershells, and how the ongoing star formation in HI supershells rims influence its evolution? During the investigation we discovered the phenomenon never observed before in galaxies IC 2574 and Holmberg II: we found faint giant (kpc-sized) ionized shells in H-alpha and [SII]6717,6731 lines inside the supergiant HI shells.

  6. RESIDUAL-GAS-IONIZATION BEAM PROFILE MONITORS IN RHIC.

    Energy Technology Data Exchange (ETDEWEB)

    CONNOLLY, R.; MICHNOFF, R.; TEPIKIAN, S.

    2005-05-16

    Four ionization profile monitors (IPMs) in RHIC measure vertical and horizontal beam profiles in the two rings by measuring the distribution of electrons produced by beam ionization of residual gas. During the last three years both the collection accuracy and signal/noise ratio have been improved. An electron source is mounted across the beam pipe from the collector to monitor microchannel plate (MCP) aging and the signal electrons are gated to reduce MCP aging and to allow charge replenishment between single-turn measurements. Software changes permit simultaneous measurements of any number of individual bunches in the ring. This has been used to measure emittance growth rates on six bunches of varying intensities in a single store. Also the software supports FFT analysis of turn-by-turn profiles of a single bunch at injection to detect dipole and quadrupole oscillations.

  7. Knee structure in double ionization of noble atoms in circularly polarized laser fields

    Science.gov (United States)

    Chen, Xiang; Wu, Yan; Zhang, Jingtao

    2017-01-01

    Nonsequential double ionization is characterized by a knee structure in the plot of double-ionization probability versus laser intensity. In circularly polarized (CP) laser fields, this structure has only been observed for Mg atoms. By choosing laser fields according to a scaling law, we exhibit the knee structure in CP laser fields for Ar and He atoms. The collision of the ionized electron with the core enhances the ionization of the second electron and forms the knee structure. The electron recollision is universal in CP laser fields, but the ionization probability in the knee region decreases as the wavelength of the driven field increases. For experimental observations, it is beneficial to use target atoms with small ionization potentials and laser fields with short wavelengths.

  8. Laser desorption ionization and peptide sequencing on laser induced silicon microcolumn arrays

    Science.gov (United States)

    Vertes, Akos [Reston, VA; Chen, Yong [San Diego, CA

    2011-12-27

    The present invention provides a method of producing a laser-patterned silicon surface, especially silicon wafers for use in laser desorption ionization (LDI-MS) (including MALDI-MS and SELDI-MS), devices containing the same, and methods of testing samples employing the same. The surface is prepared by subjecting a silicon substrate to multiple laser shots from a high-power picosecond or femtosecond laser while in a processing environment, e.g., underwater, and generates a remarkable homogenous microcolumn array capable of providing an improved substrate for LDI-MS.

  9. The laser desorption/laser ionization mass spectra of some methylated xanthines and the laser desorption of caffeine and theophylline from thin layer chromatography plates

    Science.gov (United States)

    Rogers, Kevin; Milnes, John; Gormally, John

    1993-02-01

    Laser desorption/laser ionization time-of-flight mass spectra of caffeine, theophylline, theobromine and xanthine are reported. These mass spectra are compared with published spectra obtained using electron impact ionization. Mass spectra of caffeine and theophylline obtained by IR laser desorption from thin layer chromatography plates are also described. The laser desorption of materials from thin layer chromatography plates is discussed.

  10. Detection of Extraplanar Diffuse Ionized Gas in M83

    Science.gov (United States)

    Boettcher, Erin; Gallagher, J. S., III; Zweibel, Ellen G.

    2017-08-01

    We present the first kinematic study of extraplanar diffuse ionized gas (eDIG) in the nearby, face-on disk galaxy M83 using optical emission-line spectroscopy from the Robert Stobie Spectrograph on the Southern African Large Telescope. We use a Markov Chain Monte Carlo method to decompose the [N ii]λ λ 6548, 6583, Hα, and [S ii]λ λ 6717, 6731 emission lines into H ii region and diffuse ionized gas emission. Extraplanar, diffuse gas is distinguished by its emission-line ratios ([N ii]λ6583/Hα ≳ 1.0) and its rotational velocity lag with respect to the disk ({{Δ }}v=-24 km s-1 in projection). With interesting implications for isotropy, the velocity dispersion of the diffuse gas, σ =96 km s-1, is a factor of a few higher in M83 than in the Milky Way and nearby, edge-on disk galaxies. The turbulent pressure gradient is sufficient to support the eDIG layer in dynamical equilibrium at an electron scale height of {h}z=1 kpc. However, this dynamical equilibrium model must be finely tuned to reproduce the rotational velocity lag. There is evidence of local bulk flows near star-forming regions in the disk, suggesting that the dynamical state of the gas may be intermediate between a dynamical equilibrium and a galactic fountain flow. As one of the first efforts to study eDIG kinematics in a face-on galaxy, this study demonstrates the feasibility of characterizing the radial distribution, bulk velocities, and vertical velocity dispersions in low-inclination systems. Based on observations made with the Southern African Large Telescope (SALT) under program 2015-2-SCI-004 (PI: E. Boettcher).

  11. Boosting terahertz generation in laser-field ionized gases using a sawtooth wave shape

    CERN Document Server

    Martínez, P González de Alaiza; Bergé, L; Skupin, S; Cabrera-Granado, E; Köhler, C; Morgner, U; Husakou, A; Herrmann, J

    2014-01-01

    Broadband ultrashort terahertz (THz) pulses can be produced using plasma generation in a noble gas ionized by femtosecond two-color pulses. Here we demonstrate that, by using multiple-frequency laser pulses, one can obtain a waveform which optimizes the free electron trajectories in such a way that they reach the highest velocity at the electric field extrema. This allows to increase the THz conversion efficiency to the percent level, an unprecedented performance for THz generation in gases. Besides the analytical study of THz generation using a local current model, we perform comprehensive 3D simulations accounting for propagation effects which confirm this prediction. Our results show that THz conversion via tunnel ionization can be greatly improved with well-designed multicolor pulses.

  12. Detection of polychlorinated biphenyls in transformer oils in Vietnam by multiphoton ionization mass spectrometry using a far-ultraviolet femtosecond laser as an ionization source.

    Science.gov (United States)

    Vu, Thi Thuy Duong; Vu, Duong; Nghiem, Thi Ha Lien; Imasaka, Tomoko; Tang, Yuanyuan; Shibuta, Shinpei; Hamachi, Akifumi; Do, Quang Hoa; Imasaka, Totaro

    2016-03-01

    Polychlorinated biphenyls (PCBs) in transformer and food oils were measured using gas chromatography combined with multiphoton ionization mass spectroscopy. An ultrashort laser pulse emitting in the far-ultraviolet region was utilized for efficient ionization of the analytes. Numerous signal peaks were clearly observed for a standard sample mixture of PCBs when the third and fourth harmonic emissions (267 and 200nm) of a femtosecond Ti:sapphire laser (800nm) were employed. The signal intensities were found to be greater when measured at 200nm compared with those measured at 267nm, providing lower detection limits especially for highly chlorinated PCBs at shorter wavelengths. After simple pretreatment using disposable columns, PCB congeners were measured and found to be present in the transformer oils used in Vietnam.

  13. Outflows of neutral (and ionized) gas in radio galaxies

    CERN Document Server

    Morganti, R; Tadhunter, C

    2004-01-01

    Outflows up to 1500 km/s of atomic neutral hydrogen are detected in a growing number of radio galaxies. Outflows with similar velocities are also detected in ionized gas, suggesting a common origin for the extreme kinematics of these two phases of the gas. The high detection rate ofsuch outflows in young (or restarted) radio sources appears to be related to the existence of a dense ISM around these objects. Such a dense ISM can have important consequences for the evolution of the radio source and the galaxy as a whole. Here we summarize the recent results obtained and the characteristics derived so far for these outflows. We also discuss possible mechanisms (e.g. interaction between the radio plasma and the ISM and adiabatically expanding broad emission lines clouds) that can be at the origin of these phenomena.

  14. Role of Direct Laser Acceleration of Electrons in a Laser Wakefield Accelerator with Ionization Injection

    Science.gov (United States)

    Shaw, J. L.; Lemos, N.; Amorim, L. D.; Vafaei-Najafabadi, N.; Marsh, K. A.; Tsung, F. S.; Mori, W. B.; Joshi, C.

    2017-02-01

    We show the first experimental demonstration that electrons being accelerated in a laser wakefield accelerator operating in the forced or blowout regimes gain significant energy from both the direct laser acceleration (DLA) and the laser wakefield acceleration mechanisms. Supporting full-scale 3D particle-in-cell simulations elucidate the role of the DLA of electrons in a laser wakefield accelerator when ionization injection of electrons is employed. An explanation is given for how electrons can maintain the DLA resonance condition in a laser wakefield accelerator despite the evolving properties of both the drive laser and the electrons. The produced electron beams exhibit characteristic features that are indicative of DLA as an additional acceleration mechanism.

  15. Non-dissociative and dissociative ionization of a CO+ beam in intense ultrashort laser pulses

    Science.gov (United States)

    Gaire, B.; Ablikim, U.; Zohrabi, M.; Roland, S.; Carnes, K. D.; Ben-Itzhak, I.

    2011-05-01

    We have investigated the ionization of CO+ beams in intense ultrashort laser pulses. With the recent upgrades to our coincidence three-dimensional momentum imaging method we are able to measure both non-dissociative and dissociative ionization of the molecular-ion beam targets. Using CO+ as an example, we have found that non-dissociative ionization (leading to the metastable dication CO2+) involves a direct transition, i.e. the molecule is ionized with little or no internuclear distance stretch. Dissociative ionization (C+ + O+) occurs both directly and indirectly, stretching first and then ionizing. Our results show that the yield of dissociative ionization is higher than that of non-dissociative ionization and can be manipulated with the laser pulse duration by suppressing the indirect ionization path using ultrashort pulses (Office of Basic Energy Sciences, Office of Science, U.S. Department of Energy.

  16. Large-scale shock-ionized and photo-ionized gas in M83: the impact of star formation

    OpenAIRE

    Hong, Sungryong; Calzetti, Daniela; Dopita, Michael A.; Blair, William P.; Whitmore, Bradley C.; Balick, Bruce; Bond, Howard E.; Carollo, Marcella; Disney, Michael J.; Frogel, Jay A.; Hall, Donald; Holtzman, Jon A.; Kimble, Randy A.; McCarthy, Patrick J.; O'Connell, Robert W.

    2011-01-01

    We investigate the ionization structure of the nebular gas in M83 using the line diagnostic diagram, [O III](5007 \\degA)/H{\\beta} vs. [S II](6716 \\deg A+6731 \\deg A)/H{\\alpha} with the newly available narrowband images from the Wide Field Camera 3 (WFC3) of the Hubble Space Telescope (HST). We produce the diagnostic diagram on a pixel-by-pixel (0.2" x 0.2") basis and compare it with several photo- and shock-ionization models. For the photo-ionized gas, we observe a gradual increase of the log...

  17. Coherent combs in ionization by intense and short laser pulses

    Energy Technology Data Exchange (ETDEWEB)

    Krajewska, K., E-mail: Katarzyna.Krajewska@fuw.edu.pl [Institute of Theoretical Physics, Faculty of Physics, University of Warsaw, Pasteura 5, 02-093 Warszawa (Poland); Department of Physics and Astronomy, University of Nebraska, Lincoln, NE 68588-0299 (United States); Kamiński, J.Z., E-mail: Jerzy.Kaminski@fuw.edu.pl [Institute of Theoretical Physics, Faculty of Physics, University of Warsaw, Pasteura 5, 02-093 Warszawa (Poland)

    2016-03-22

    Photoionization of positive ions by a train of intense, short laser pulses is investigated within the relativistic strong field approximation, using the velocity gauge. The formation of broad peak structures in the high-energy domain of photoelectrons is observed and interpreted. The emergence of coherent photoelectron energy combs within these structures is demonstrated, and it is interpreted as the consequence of the Fraunhofer-type interference/diffraction of probability amplitudes of ionization from individual pulses comprising the train. Extensions to the coherent angular combs are also studied, and effects related to the radiation pressure are presented. - Highlights: • We develop relativistic Strong-Field Approximation for ionization by intense and short laser pulses of arbitrary spectral compositions. • We show that the consistent interpretation of results is provided by the Keldysh-type saddle point analysis of probability amplitudes. • We derive a general Fraunhofer-type interference/diffraction formula for finite train of pulses. • We study the coherent combs in photoelectron probability distributions.

  18. Intermediate- and High-Velocity Ionized Gas toward zeta Orionis

    CERN Document Server

    Welty, D E; Raymond, J C; Mallouris, C; York, D G

    2002-01-01

    We combine UV spectra obtained with the HST/GHRS echelle, IMAPS, and Copernicus to study the abundances and physical conditions in the predominantly ionized gas seen at high (-105 to -65 km/s) and intermediate velocities (-60 to -10 km/s) toward zeta Ori. We have high resolution (FWHM ~ 3.3-4.5 km/s) and/or high S/N spectra for at least two significant ions of C, N, Al, Si, S, and Fe -- enabling accurate estimates for both the total N(H II) and the elemental depletions. C, N, and S have essentially solar relative abundances; Al, Si, and Fe appear to be depleted by about 0.8, 0.3-0.4, and 0.95 dex, respectively. While various ion ratios would be consistent with collisional ionization equilibrium (CIE) for T ~ 25,000-80,000 K, the widths of individual high-velocity absorption components indicate that T ~ 9000 K -- so the gas is not in CIE. Analysis of the C II fine-structure excitation equilibrium yields estimated densities (n_e ~ n_H ~ 0.1-0.2 cm^{-3}), thermal pressures (2 n_H T ~ 2000-4000 cm^{-3}K), and thi...

  19. Optimal laser pulse energy partitioning for air ionization

    CERN Document Server

    Schubert, Elise; Matthews, Mary; Courjaud, Antoine; Kasparian, Jérôme; Wolf, Jean-Pierre

    2016-01-01

    We investigate the pulse partitioning of a 6.3 mJ, 450 fs pulse at 1030 nm to produce plasma channels. At such moderate energies, splitting the energy into several sub-pulses reduces the ionization efficiency and thus does not extend the plasma lifetime. We numerically show that when sufficient energy to produce multifilamentation is available, splitting the pulse temporally in a pulse train increases the gas temperature compared to a filament bundle of the same energy. This could improve the mean free path of the free electrons, therefore enhancing the efficiency of discharge triggering.

  20. Origin and Dynamical Support of Ionized Gas in Galaxy Bulges

    CERN Document Server

    Ho, Luis C

    2009-01-01

    We combine ionized gas ([N II] 6583) and stellar central velocity dispersions for a sample of 345 galaxies, with and without active galactic nuclei (AGNs), to study the dynamical state of the nuclear gas and its physical origin. The gas dispersions strongly correlate with the stellar dispersions over the velocity range of 30-350 km/s such that sigma_g/sigma_* ~ 0.6-1.4, with an average value of 0.80. These results are independent of Hubble type (for galaxies from E to Sbc), presence or absence of a bar, or local galaxy environment. For galaxies of type Sc and later and that have sigma_* < 40 km/s, the gas seems to have a minimum threshold of sigma_g ~ 30 km/s, such that sigma_g/sigma_* always exceeds 1. Within the sample of AGNs, sigma_g/sigma_* increases with nuclear luminosity or Eddington ratio, a possible manifestation of AGN feedback associated with accretion disk winds or outflows. This extra source of nongravitational line broadening should be removed when trying to use sigma_g to estimate sigma_*. ...

  1. Two-colour multiphoton ionization of hydrogen by an intense laser field and its third harmonic

    Energy Technology Data Exchange (ETDEWEB)

    Potvliege, R.M.; Smith, P.H.G. (Durham Univ. (United Kingdom). Dept. of Physics)

    1991-12-28

    We present results of ab initio non-perturbative Floquet calculations of rates for multiphoton ionization of atomic hydrogen by an intense laser field and its third harmonic, discussing in particular resonant ionization and the dependence of the ionization rate on the relative phase of the two fields. (author).

  2. Quantifying Uranium Isotope Ratios Using Resonance Ionization Mass Spectrometry: The Influence of Laser Parameters on Relative Ionization Probability

    Energy Technology Data Exchange (ETDEWEB)

    Isselhardt, Brett H. [Univ. of California, Berkeley, CA (United States)

    2011-09-01

    Resonance Ionization Mass Spectrometry (RIMS) has been developed as a method to measure relative uranium isotope abundances. In this approach, RIMS is used as an element-selective ionization process to provide a distinction between uranium atoms and potential isobars without the aid of chemical purification and separation. We explore the laser parameters critical to the ionization process and their effects on the measured isotope ratio. Specifically, the use of broad bandwidth lasers with automated feedback control of wavelength was applied to the measurement of 235U/238U ratios to decrease laser-induced isotopic fractionation. By broadening the bandwidth of the first laser in a 3-color, 3-photon ionization process from a bandwidth of 1.8 GHz to about 10 GHz, the variation in sequential relative isotope abundance measurements decreased from >10% to less than 0.5%. This procedure was demonstrated for the direct interrogation of uranium oxide targets with essentially no sample preparation. A rate equation model for predicting the relative ionization probability has been developed to study the effect of variation in laser parameters on the measured isotope ratio. This work demonstrates that RIMS can be used for the robust measurement of uranium isotope ratios.

  3. Ultra-low emittance beam generation using two-color ionization injection in a CO2 laser-driven plasma accelerator

    Energy Technology Data Exchange (ETDEWEB)

    Schroeder, Carl [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Benedetti, Carlo [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Bulanov, Stepan [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Chen, Min [Shanghai Jiao Tong Univ. (China); Esarey, Eric [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Geddes, Cameron [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Vay, J. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Yu, Lule [Shanghai Jiao Tong Univ. (China); Leemans, Wim [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

    2015-05-21

    Ultra-low emittance (tens of nm) beams can be generated in a plasma accelerator using ionization injection of electrons into a wakefield. An all-optical method of beam generation uses two laser pulses of different colors. A long-wavelength drive laser pulse (with a large ponderomotive force and small peak electric field) is used to excite a large wakefield without fully ionizing a gas, and a short-wavelength injection laser pulse (with a small ponderomotive force and large peak electric field), co-propagating and delayed with respect to the pump laser, to ionize a fraction of the remaining bound electrons at a trapped wake phase, generating an electron beam that is accelerated in the wake. The trapping condition, the ionized electron distribution, and the trapped bunch dynamics are discussed. Expressions for the beam transverse emittance, parallel and orthogonal to the ionization laser polarization, are presented. An example is shown using a 10-micron CO2 laser to drive the wake and a frequency-doubled Ti:Al2O3 laser for ionization injection.

  4. Dense Ionized and Neutral Gas Surrounding Sgr A*

    CERN Document Server

    Shukla, Hemant; Scoville, N Z

    2004-01-01

    We present high resolution H41a hydrogen recombination line observations of the 1.2' (3 pc) region surrounding Sgr A* at 92 GHz using the OVRO Millimeter Array with an angular resolution of 7" x 3" and velocity resolution of 13 km/s. New observations of H31a, H35a, H41a, and H44a lines were obtained using the NRAO 12-m telescope, and their relative line strengths are interpreted in terms of various emission mechanisms. These are the most extensive and most sensitive observations of recombination line to date. Observations of HCO+ (1 - 0) transition at 89 GHz are also obtained simultaneously with a 40% improved angular resolution and 4-15 times improved sensitivity over previous observations, and the distribution and kinematics of the dense molecular gas in the circumnuclear disk (CND) are mapped and compared with those of the ionized gas. The line brightness ratios of the hydrogen recombination lines are consistent with purely spontaneous emission from 7000 K gas with n_e = 20,000 cm$^{-3}$ near LTE condition...

  5. Turbulence in the Ionized Gas of the Orion Nebula

    CERN Document Server

    Arthur, S J; Henney, W J

    2016-01-01

    In order to study the nature, origin, and impact of turbulent velocity fluctuations in the ionized gas of the Orion Nebula, we apply a variety of statistical techniques to observed velocity cubes. The cubes are derived from high resolving power ($R \\approx 40,000$) longslit spectroscopy of optical emission lines that span a range of ionizations. From Velocity Channel Analysis (VCA), we find that the slope of the velocity power spectrum is consistent with predictions of Kolmogorov theory between scales of 8 and 22 arcsec (0.02 to 0.05 pc). The outer scale, which is the dominant scale of density fluctuations in the nebula, approximately coincides with the autocorrelation length of the velocity fluctuations that we determine from the second order velocity structure function. We propose that this is the principal driving scale of the turbulence, which originates in the autocorrelation length of dense cores in the Orion molecular filament. By combining analysis of the non-thermal line widths with the systematic tr...

  6. Performance of the ETH gas ionization chamber at low energy

    Energy Technology Data Exchange (ETDEWEB)

    Mueller, A.M., E-mail: arnold.mueller@phys.ethz.ch [Laboratory of Ion Beam Physics, ETH-Zurich, Schafmattstrasse 20, CH-8093 Zurich (Switzerland); Doebeli, M.; Suter, M.; Synal, H.-A. [Laboratory of Ion Beam Physics, ETH-Zurich, Schafmattstrasse 20, CH-8093 Zurich (Switzerland)

    2012-09-15

    The performance of gas ionization chambers (GIC) for the detection of low energy ions has been considerably improved in the past years by the use of silicon nitride entrance windows and low noise preamplifiers. This has led to an increased use of high resolution GICs in the fields of accelerator mass spectrometry and ion beam analysis. This development and the underlying physical principles are reviewed and the latest technical status of such devices is summarized. A detailed study on energy resolution and pulse height defect is presented with projectiles covering a wide particle mass range (H, {sup 9}Be, {sup 13}C, {sup 27}Al, {sup 35}Cl, {sup 127}I, {sup 232}Th) with energies between 0.1 and 2.2 MeV. The dependence of energy resolution and charge output per unit particle energy on the nuclear charge of the projectile is investigated and parametrized. SRIM calculations of ionizing energy loss considerably differ from these experimental findings. For 1 MeV particles discrepancies up to 50% are observed. The performance of GICs and their practical use is compared to that of solid state detectors. The potential for further improvement of the technology and its fields of application are assessed.

  7. Development of a portable gas-filled ionization chamber

    Energy Technology Data Exchange (ETDEWEB)

    Chae, K. Y.; Cha, S. M.; Gwak, M. S. [Sungkyunkwan University, Suwon (Korea, Republic of)

    2014-02-15

    A new portable gas-filled ionization chamber has been designed and constructed at the Physics Department of Sung Kyun Kwan University. To overcome the maximum count rate of ∼ 10{sup 5} particles per second of a conventional ionization chamber, which utilizes a Frisch grid, and to enhance the portability of a detector, we adopted the design of multiple electrodes and modified it from the original designs by Kimura et al. and Chae et al. The new design utilizes a stack of multiple electrodes installed perpendicular to the optical beam axis. This configuration provides a fast response time for the detector, which is essential for high-rate counting. The device has been tested with a {sup 241}Am (t{sub 1/2} = 432.2 years) radioactive α source, which mainly emits 5.486-MeV (branching ratio of 85%) and 5.443-MeV (branching ratio of 13%) α particles. An energy resolution of 6.3% was achieved.

  8. Multiphoton resonant ionization of hydrogen atom exposed to two-colour laser pulses

    Institute of Scientific and Technical Information of China (English)

    Wang Pei-Jie; Fang Yan

    2008-01-01

    This paper studies the multiphoton resonant ionization by two-colour laser pulses in the hydrogen atom by solving the time-dependent Schr(o)dinger equation.By fixing the parameters of fundamental laser field and scanning the frequency of second laser field,it finds that the ionization probability shows several resonance peaks and is also much larger than the linear superposition of probabilities by applying two lasers separately.The enhancement of the ionization happens when the system is resonantly pumped to the excited states by absorbing two or more colour photons non-sequentially.

  9. Beam Impedance Studies of the PS Beam Gas Ionization Monitor

    CERN Document Server

    Avgidis, Fotios

    2016-01-01

    The Beam Gas Ionization monitor (BGI) is a device for continuous beam size monitoring that is intended to be installed in the CERN Proton Synchrotron (PS) during the extended year-end technical stop from December 2016 to April 2017. With the objective of determining the impedance contribution of the BGI vacuum chamber to the overall beam impedance, we report on RF measurements on the device in a laboratory frame, measurement data analysis, and RF simulations of the structure under investigation. For the impedance contribution characterization of the BGI, the following approach has been followed: First, the EM fields inside a simplified BGI model that doesn’t include any of the internal components of the vacuum chamber have been simulated. RF measurements have been performed on the same empty structure showing great agreement between measurement and simulation and thus verifying the validity of the model. Second, simulations have been executed on a fully assembled BGI model that includes all the internal ele...

  10. Nuclear pumped gas laser research

    Science.gov (United States)

    Thom, K.

    1976-01-01

    Nuclear pumping of lasers by fission-fragments from nuclear chain reactions is discussed. Application of the newly developed lasers to spacecraft propulsion or onboard power, to lunar bases for industrial processing, and to earth for utilization of power without pollution and hazards is envisioned. Emphasis is placed on the process by which the fission-fragement kinetic energy is converted into laser light.

  11. Large-scale shock-ionized and photo-ionized gas in M83: the impact of star formation

    CERN Document Server

    Hong, Sungryong; Dopita, Michael A; Blair, William P; Whitmore, Bradley C; Balick, Bruce; Bond, Howard E; Carollo, Marcella; Disney, Michael J; Frogel, Jay A; Hall, Donald; Holtzman, Jon A; Kimble, Randy A; McCarthy, Patrick J; O'Connell, Robert W; Paresce, Francesco; Saha, Abhijit; Silk, Joseph I; Trauger, John T; Walker, Alistair R; Windhorst, Rogier A; Young, Erick T; Mutchler, Max

    2011-01-01

    We investigate the ionization structure of the nebular gas in M83 using the line diagnostic diagram, [O III](5007 \\degA)/H{\\beta} vs. [S II](6716 \\deg A+6731 \\deg A)/H{\\alpha} with the newly available narrowband images from the Wide Field Camera 3 (WFC3) of the Hubble Space Telescope (HST). We produce the diagnostic diagram on a pixel-by-pixel (0.2" x 0.2") basis and compare it with several photo- and shock-ionization models. For the photo-ionized gas, we observe a gradual increase of the log([O III]/H{\\beta}) ratios from the center to the spiral arm, consistent with the metallicity gradient, as the H II regions go from super solar abundance to roughly solar abundance from the center out. Using the diagnostic diagram, we separate the photo-ionized from the shock-ionized component of the gas. We find that the shock-ionized H{\\alpha} emission ranges from ~2% to about 15-33% of the total, depending on the separation criteria used. An interesting feature in the diagnostic diagram is an horizontal distribution aro...

  12. Gas-phase recombination, grain neutralization and cosmic-ray ionization in diffuse gas

    CERN Document Server

    Liszt, H S

    2003-01-01

    Atomic ions are mostly neutralized by small grains (or PAH molecules) in current theories of heating and cooling in cool diffuse clouds; in the main they do not recombine with free electrons. This alters the ionization balance by depressing n(H+) and n(He+) while carbon generally remains nearly fully once-ionized: charge exchange with atomic oxygen and formation of H2 and OH also depress n(H+) in partly molecular gas. Seemingly restrictive empirical limits on the cosmic ray ionization rate of hydrogen ($\\zeta_H$) are relaxed and faster rates are favored in a wide range of circumstances, when grain neutralization is recognized. Maintenance of the proton density at levels needed to reproduce observations of HD requires $\\zeta_H$ at least 2x10^{-16} s^{-1}, but such models naturally explain the presence of both HD and H3^+ in relatively tenuous H I clouds. In dense gas, a higher ionization rate can account for high observed fractions of atomic hydrogen, and recognition of the effects of grain neutralization can ...

  13. Fast outflow of neutral and ionized gas from the radio galaxy 3C 293

    NARCIS (Netherlands)

    Emonts, B.H.C.; Morganti, R.; Oosterloo, T.A.; Tadhunter, C.N.; Hulst, J.M. van der

    2005-01-01

    Abstract: We detect a fast outflow of neutral and ionized gas with velocities up to about 1000 km/s from the central region of radio galaxy 3C 293. With optical spectroscopy we locate the bulk of the ionized gas outflow at the position of a bright radio hot-spot in the inner radio jet, about 1 kpc e

  14. Fast outflow of neutral and ionized gas from the radio galaxy 3C 293

    NARCIS (Netherlands)

    Emonts, BHC; Morganti, R; Osterloo, TA; Tadhunter, CN; van der Hulst, JM; Braun, R

    2005-01-01

    We detect a fast outflow of neutral and ionized gas with velocities up to similar to 1000 km/s from the central region of radio galaxy 3C 293. With optical spectroscopy we locate the bulk of the ionized gas outflow at the position of a bright radio hot-spot in the inner radio jet, about I kpc east o

  15. A measure method of the time respond function for gas ionization chamber

    CERN Document Server

    Wang Li; Qing Shang Yu

    2002-01-01

    In quick scanning radiography system, the time respond speed of array gas ionization chamber effects the image clarity directly. The author presents a measure method of the time respond function for gas ionization chamber. The image clarity will be improved by inverse convoluting the image data

  16. Electron ionization and spin polarization control of Fe atom adsorbed graphene irradiated by a femtosecond laser

    Energy Technology Data Exchange (ETDEWEB)

    Yu, Dong [Laser Micro/Nano Fabrication Laboratory, School of Mechanical Engineering, Beijing Institute of Technology, Beijing 100081 (China); Jiang, Lan, E-mail: jianglan@bit.edu.cn [Laser Micro/Nano Fabrication Laboratory, School of Mechanical Engineering, Beijing Institute of Technology, Beijing 100081 (China); Wang, Feng; Li, Xin [Laser Micro/Nano Fabrication Laboratory, School of Mechanical Engineering, Beijing Institute of Technology, Beijing 100081 (China); Qu, Liangti [Key Laboratory of Cluster Science, Ministry of Education, School of Chemistry, Beijing Institute of Technology, Beijing 100081 (China); Lu, Yongfeng [Department of Electrical Engineering, University of Nebraska-Lincoln, Lincoln, NE 68588-0511 (United States)

    2015-10-23

    We investigate the structural properties and ionized spin electrons of an Fe–graphene system, in which the time-dependent density functional theory (TDDFT) within the generalized gradient approximation is used. The electron dynamics, including electron ionization and ionized electron spin polarization, is described for Fe atom adsorbed graphene under femtosecond laser irradiation. The theoretical results show that the electron ionization and ionized electron spin polarization are sensitive to the laser parameters, such as the incident angle and the peak intensity. The spin polarization presents the maximum value under certain laser parameters, which may be used as a source of spin-polarized electrons. - Highlights: • The structural properties of Fe–graphene system are investigated. • The electron dynamics of Fe–graphene system under laser irradiation are described. • The Fe–graphene system may be used as a source of spin-polarized electrons.

  17. Star Formation in HII Galaxies. Properties of the ionized gas

    CERN Document Server

    Hägele, G F; Terlevich, E; Pérez-Montero, E; Terlevich, R; Cardaci, M V

    2009-01-01

    We propose a methodology to perform a self-consistent analysis of the physical properties of the emitting gas of HII galaxies adequate to the data that can be obtained with the XXI century technology. This methodology requires the production and calibration of empirical relations between the different line temperatures that should superseed currently used ones based on very simple, and poorly tested, photo-ionization model sequences. Then, these observations are analysed applying a methodology designed to obtain accurate elemental abundances of oxygen, sulphur, nitrogen, neon, argon and iron in the ionsied gas. Four electron temperatures and one electron density are derived from the observed forbidden line ratios using the five-level atom approximation. For our best objects errors of 1% in T([OIII]), 3% in T([OII]) and 5% in T([SIII]) are achieved with a resulting accuracy between 5 and 9% in total oxygen abundances, O/H. These accuracies are expected to improve as better calibrations based on more precise me...

  18. The Impact of Diffuse Ionized Gas on Emission-line Ratios and Gas Metallicity Measurements

    Science.gov (United States)

    Zhang, Kai; Yan, Renbin; MaNGA Team

    2016-01-01

    Diffuse Ionized Gas (DIG) is prevalent in star-forming galaxies. Using a sample of galaxies observed by MaNGA, we demonstrate how DIG in star-forming galaxies impact the measurements of emission line ratios, hence the gas-phase metallicity measurements and the interpretation of diagnostic diagrams. We demonstrate that emission line surface brightness (SB) is a reasonably good proxy to separate HII regions from regions dominated by diffuse ionized gas. For spatially-adjacent regions or regions at the same radius, many line ratios change systematically with emission line surface brightness, reflecting a gradual increase of dominance by DIG towards low SB. DIG could significantly bias the measurement of gas metallicity and metallicity gradient. Because DIG tend to have a higher temperature than HII regions, at fixed metallicity DIG displays lower [NII]/[OII] ratios. DIG also show lower [OIII]/[OII] ratios than HII regions, due to extended partially-ionized regions that enhance all low-ionization lines ([NII], [SII], [OII], [OI]). The contamination by DIG is responsible for a substantial portion of the scatter in metallicity measurements. At different surface brightness, line ratios and line ratio gradients can differ systematically. As DIG fraction could change with radius, it can affect the metallicity gradient measurements in systematic ways. The three commonly used strong-line metallicity indicators, R23, [NII]/[OII], O3N2, are all affected in different ways. To make robust metallicity gradient measurements, one has to properly isolate HII regions and correct for DIG contamination. In line ratio diagnostic diagrams, contamination by DIG moves HII regions towards composite or LINER-like regions.

  19. Role of ambient gas in heating of metal samples by femtosecond pulses of laser radiation

    Science.gov (United States)

    Zhukov, V. P.; Bulgakova, N. M.

    2009-06-01

    In this work we consider an experimentally observed effect of significant increasing of the residual heat in metal targets at their irradiation with femtosecond laser pulses in an ambient gas in respect to the vacuum conditions. Numerical modelling of heating of a platinum target by femtosecond laser pulses in argon under normal conditions has been performed taking into account gas breakdown in the focussing region of the laser beam in front of the target. The applied model is based on a combination of a thermal model describing heating and phase transitions in irradiated samples and a hydrodynamic model to describe motion of the ambient gas perturbed by laser irradiation as a result of multiphoton ionization. The hot ambient gas is shown to heat efficiently the irradiated sample. The hydrodynamic processes in the ambient gas play an important role in heating.

  20. A simple resonance enhanced laser ionization scheme for CO via the A1Π state

    Science.gov (United States)

    Sun, Z. F.; von Zastrow, A. D.; Parker, D. H.

    2017-07-01

    We investigate the laser ionization process taking place when the CO molecule is exposed to vacuum ultraviolet (VUV) radiation resonant with the CO A1Π (v = 0) ← X1Σ+ (v = 0) transition around 154 nm, along with the ultraviolet (UV) and visible (Red) radiation used to generate VUV by four-wave difference-frequency mixing. By measuring the CO+ ion recoil and a room temperature gas spectrum, it is possible to assign the ionization process as 1 + 1' + 1'' REMPI where the one-photon steps refer to the VUV, UV, and Red radiation, respectively. Resonance enhanced ionization of rotational states around J = 12 arise due to the overlap of the fixed wavelength UV (˜250 nm) with the R band-head of a transition assigned to CO E1Π (v = 6) ← A1Π (v = 0) with a term value of 104 787.5 cm-1. The REMPI process is efficient and polarization sensitive and should be useful in a wide range of studies involving nascent CO.

  1. Controlling Nonsequential Double Ionization in Two-Color Circularly Polarized Femtosecond Laser Fields

    Science.gov (United States)

    Mancuso, Christopher A.; Dorney, Kevin M.; Hickstein, Daniel D.; Chaloupka, Jan L.; Ellis, Jennifer L.; Dollar, Franklin J.; Knut, Ronny; Grychtol, Patrik; Zusin, Dmitriy; Gentry, Christian; Gopalakrishnan, Maithreyi; Kapteyn, Henry C.; Murnane, Margaret M.

    2016-09-01

    Atoms undergoing strong-field ionization in two-color circularly polarized femtosecond laser fields exhibit unique two-dimensional photoelectron trajectories and can emit bright circularly polarized extreme ultraviolet and soft-x-ray beams. In this Letter, we present the first experimental observation of nonsequential double ionization in these tailored laser fields. Moreover, we can enhance or suppress nonsequential double ionization by changing the intensity ratio and helicity of the two driving laser fields to maximize or minimize high-energy electron-ion rescattering. Our experimental results are explained through classical simulations, which also provide insight into how to optimize the generation of circularly polarized high harmonic beams.

  2. Multiphoton processes in KrF-laser induced gas breakdown

    Energy Technology Data Exchange (ETDEWEB)

    Poprawe, R.; Herziger, G.

    1986-05-01

    Ionization by multiphoton processes is the dominant generation mechanism of first electrons in the UV-laser-induced gas breakdown. A strongly simplified analytical model for the ion generation rate is used to give an estimate of the threshold intensity I/sub TH/. The result is compared to descriptions by Keldish and Bebb to check its limits of applicability. Solving the kinetic conservation equations for the focus volume gives an estimation of the breakdown intensity where the Debye criterion has been used in the sense of a plasma definition. As an example, breakdown experiments with a KrF-escimer laser have been carried out at different pressures in an argon atmosphere. The pressure dependency of the breakdown threshold intensity and its order of magnitude are predicted by the model.

  3. Solar-pumped gas laser development

    Science.gov (United States)

    Wilson, J. W.

    1980-01-01

    A survey of gas properties through detailed kinetic models led to the identification of critical gas parameters for use in choosing appropriate gas combinations for solar pumped lasers. Broadband photoabsorption in the visible or near UV range is required to excite large volumes of gas and to insure good solar absorption efficiency. The photoexcitation density is independent of the absorption bandwidth. The state excited must be a metastable state which is not quenched by the parent gas. The emission bandwidth must be less than 10 A to insure lasing threshold over reasonable gain lengths. The system should show a high degree of chemical reversibility and an insensitivity to increasing temperature. Other properties such as good quantum efficiency and kinetic efficiency are also implied. Although photoexcitation of electronic vibrational transitions is considered as a possible system if the emission bands sufficiently narrow, it appears that photodissociation into atomic metastables is more likely to result in a successful solar pumped laser system.

  4. Third Harmonic Generation of a Short Pulse Laser in a Tunnel Ionizing Plasma: Effect of Self-Defocusing

    OpenAIRE

    Niti Kant

    2013-01-01

    Third harmonic generation of a Gaussian short pulse laser in a tunnel ionizing plasma is investigated. A Gaussian short pulse laser propagating through a tunnel ionizing plasma generates third harmonic wave. Inhomogeneity of the electric field along the wavefront of the fundamental laser pulse causes more ionization along the axis of propagation while less ionization off axis, leading to strong density gradient with its maximum on the axis of propagation. The medium acts like a diverging lens...

  5. Simulations of laser propagation and ionization in l'OASIS experiments

    Energy Technology Data Exchange (ETDEWEB)

    Dimitrov, D.A.; Bruhwiler, D.L.; Leemans, W.; Esarey, E.; Catravas, P.; Toth, C.; Shadwick, B.; Cary, J.R.; Giacone, R.

    2002-06-30

    We have conducted particle-in-cell simulations of laser pulse propagation through neutral He, including the effects of tunneling ionization, within the parameter regime of the l'OASIS experiments [1,2] at the Lawrence Berkeley National Laboratory (LBNL). The simulations show the theoretically predicted [3] blue shifting of the laser frequency at the leading edge of the pulse. The observed blue shifting is in good agreement with the experimental data. These results indicate that such computations can be used to accurately simulate a number of important effects related to tunneling ionization for laser-plasma accelerator concepts, such as steepening due to ionization-induced pump depletion, which can seed and enhance instabilities. Our simulations show self-modulation occurring earlier when tunneling ionization is included then for a pre-ionized plasma.

  6. A new mini gas ionization chamber for IBA applications

    Energy Technology Data Exchange (ETDEWEB)

    Mueller, A.M., E-mail: arnold.mueller@phys.ethz.ch [Laboratory of Ion Beam Physics, ETH Zurich, 8093 Zurich (Switzerland); Cassimi, A., E-mail: cassimi@ganil.fr [CIMAP/CIRIL, CEA/CNRS/ENSICAEN, BP5133, F-14070 Caen cedex 5 (France); Doebeli, M., E-mail: doebeli@phys.ethz.ch [Laboratory of Ion Beam Physics, ETH Zurich, 8093 Zurich (Switzerland); Mallepell, M., E-mail: mallepell@phys.ethz.ch [Laboratory of Ion Beam Physics, ETH Zurich, 8093 Zurich (Switzerland); Monnet, I., E-mail: monnet@ganil.fr [CIMAP/CIRIL, CEA/CNRS/ENSICAEN, BP5133, F-14070 Caen cedex 5 (France); Simon, M.J. [Laboratory of Ion Beam Physics, ETH Zurich, 8093 Zurich (Switzerland); Suter, M., E-mail: martin.suter@phys.ethz.ch [Laboratory of Ion Beam Physics, ETH Zurich, 8093 Zurich (Switzerland); Synal, H.-A., E-mail: synal@phys.ethz.ch [Laboratory of Ion Beam Physics, ETH Zurich, 8093 Zurich (Switzerland)

    2011-12-15

    Novel prototypes of high resolution gas ionization chambers (GIC) were designed with increased compactness and simplicity of the setup. They have no Frisch-grid and a simple anode wire. Under certain operating conditions these mini detectors have an energy resolution comparable with that of state-of-the-art GICs of much higher complexity. They can be operated both under vacuum and atmospheric pressure. First measurements were made with protons in the energy range of 0.3-1.0 MeV. For protons at 0.3 MeV an energy resolution of about 12 keV was achieved. With a 72 MeV {sup 129}Xe beam a relative resolution of 1.4% was obtained. Due to their versatility and reduced size the detectors can easily be applied in the field of ion beam analysis (IBA) and accelerator mass spectrometry (AMS). Since they are almost completely insensitive to radiation damage they are especially suited for use in high fluence applications such as scanning transmission ion microscopy (STIM). A comparison of the radiation hardness of the mini GIC with a Si PIN diode was therefore performed. The GIC showed no peak shift or change in energy resolution at all after collecting 10{sup 15} protons per cm{sup 2} while the performance of the Si detector clearly started to degrade at 10{sup 12} particles per cm{sup 2}.

  7. Classical trajectory perspective of atomic ionization in strong laser fields semiclassical modeling

    CERN Document Server

    Liu, Jie

    2014-01-01

    The ionization of atoms and molecules in strong laser fields is an active field in modern physics and has versatile applications in such as attosecond physics, X-ray generation, inertial confined fusion (ICF), medical science and so on. Classical Trajectory Perspective of Atomic Ionization in Strong Laser Fields covers the basic concepts in this field and discusses many interesting topics using the semiclassical model of classical trajectory ensemble simulation, which is one of the most successful ionization models and has the advantages of a clear picture, feasible computing and accounting for many exquisite experiments quantitatively. The book also presents many applications of the model in such topics as the single ionization, double ionization, neutral atom acceleration and other timely issues in strong field physics, and delivers useful messages to readers with presenting the classical trajectory perspective on the strong field atomic ionization. The book is intended for graduate students and researchers...

  8. DYNAMICS OF IONIZATION-ENHANCED SPECTRAL EXPANSION IN WATER INDUCED BY AN INTENSE FEMTOSECOND LASER BEAM

    Institute of Scientific and Technical Information of China (English)

    WANG SHU-FENG; QIN YUAN-DONG; YANG HONG; WANG DAN-LING; ZHU CHANG-JUN; GONG QI-HUANG

    2001-01-01

    The dynamic process of white-continuum generation in water was investigated by the pump-probe technique with a femtosecond intense laser at 805nm. The spectrum width of the probe beam was broadened at the blue side and varied with different delay times. This blueshift was attributed to the ionization-enhanced optical nonlinearity, in which both the multi-photon ionization and avalanche ionization had an effect.

  9. Relative Phase Dependence of Double Ionization in a Synthesized Laser Pulse

    Institute of Scientific and Technical Information of China (English)

    WANG Yuan-Sheng; XIA Chang-Long; GUO Jing; LIU Xue-Shen

    2011-01-01

    @@ We investigate the double ionization process of a three-dimensional model atom interacting with a synthesized laser pulse and explore the mechanism of non-sequential double ionization varying with the value of relative phase.The result shows that the recollision probability decreases when the value of the relative phase increases.The momentum spectra of electrons in the sequential ionization region are also illustrated.

  10. Ultra-low emittance beam generation using two-color ionization injection in a CO2 laser-driven plasma accelerator

    CERN Document Server

    Schroeder, C B; Bulanov, S S; Chen, M; Esarey, E; Geddes, C G R; Vay, J -L; Yu, L -L; Leemans, W P

    2015-01-01

    Ultra-low emittance (tens of nm) beams can be generated in a plasma accelerator using ionization injection of electrons into a wakefield. An all-optical method of beam generation uses two laser pulses of different colors. A long-wavelength drive laser pulse (with a large ponderomotive force and small peak electric field) is used to excite a large wakefield without fully ionizing a gas, and a short-wavelength injection laser pulse (with a small ponderomotive force and large peak electric field), co-propagating and delayed with respect to the pump laser, to ionize a fraction of the remaining bound electrons at a trapped wake phase, generating an electron beam that is accelerated in the wake. The trapping condition, the ionized electron distribution, and the trapped bunch dynamics are discussed. Expressions for the beam transverse emittance, parallel and orthogonal to the ionization laser polarization, are presented. An example is shown using a 10-micron CO2 laser to drive the wake and a frequency-doubled Ti:Al2...

  11. Determination of equilibrium composition of thermally ionized monoatomic gas under different physical conditions

    Science.gov (United States)

    Romanova, M. S.; Rydalevskaya, M. A.

    2017-05-01

    Perfect gas mixtures that result from thermal ionization of spatially and chemically homogeneous monoatomic gases are considered. Equilibrium concentrations of the components of such mixtures are determined using integration over the momentum space and summation with respect to energy levels of the distribution functions that maximize the entropy of system under condition for constancy of the total number of nuclei and electrons. It is demonstrated that such a method allows significant simplification of the calculation of the equilibrium composition for ionized mixtures at different temperatures and makes it possible to study the degree of ionization of gas versus gas density and number in the periodic table of elements.

  12. Laser vaporization/ionization interface for coupling microscale separation techniques with mass spectrometry

    Science.gov (United States)

    Yeung, E.S.; Chang, Y.C.

    1999-06-29

    The present invention provides a laser-induced vaporization and ionization interface for directly coupling microscale separation processes to a mass spectrometer. Vaporization and ionization of the separated analytes are facilitated by the addition of a light-absorbing component to the separation buffer or solvent. 8 figs.

  13. Resonant three-photon ionization of hydrogenic atoms by a non-monochromatic laser field

    NARCIS (Netherlands)

    Yakhontov, V.; Santra, R.; Jungmann, K.

    1999-01-01

    We present ionization probability and lineshape calculations for the two-step three- photon ionization process, 1S (2(h)over-bar-omega)under-right-arrow, 2S ((h)over-bar-omega)under-right-arrow epsilon P, of the ground state of hydrogenic atoms in a non-monochromatic laser field with a time-dependen

  14. Resonant three-photon ionization of hydrogenic atoms by a non-monochromatic laser field

    NARCIS (Netherlands)

    Yakhontov, V.; Santra, R.; Jungmann, K.

    1999-01-01

    We present ionization probability and lineshape calculations for a specifed two-step three-photon ionization process of the ground state of hydrogenic atoms in a non-monochromatic laser field with a time-dependent amplitude. Within the framework of a three-level model, the AC Stark shifts and non-ze

  15. LONGITUDINAL DISCH.CO2 LASER WITH PULSED PRE—IONIZATION

    Institute of Scientific and Technical Information of China (English)

    YuYanning; WanChongyi

    2002-01-01

    A novel pre-iolization scheme of helical transverse-prlsed pre-ionization in a lon-gitudinal discharge CO2 laser is presented.The laser tube is made of glass with inner diameter of 7.5mm and discharge length of 50cm .The laser performance characteristics as functions of parameters,such as pressure,charging capacitance and applied voltage,are investigated.Com-pared with the same laser structure without pre-ionization ,the maximum pulse energy improves by 23%,the optimum electro-optical efficiency increases by 30%,and the specific output energy reaches 26 J/(L-atm).

  16. Electron impact ionization of the gas-phase sorbitol

    Science.gov (United States)

    Chernyshova, Irina; Markush, Pavlo; Zavilopulo, Anatoly; Shpenik, Otto

    2015-03-01

    Ionization and dissociative ionization of the sorbitol molecule by electron impact have been studied using two different experimental methods. In the mass range of m/ z = 10-190, the mass spectra of sorbitol were recorded at the ionizing electron energies of 70 and 30 eV. The ion yield curves for the fragment ions have been analyzed and the appearance energies of these ions have been determined. The relative total ionization cross section of the sorbitol molecule was measured using monoenergetic electron beam. Possible fragmentation pathways for the sorbitol molecule were proposed.

  17. Experiments of discharge guiding using strongly and weakly ionized plasma channels for laser-triggered lightning

    Science.gov (United States)

    Shimada, Yoshinori; Uchida, Shigeaki; Yamanaka, Chiyoe; Ogata, Akihisa; Yamanaka, Tatsuhiko; Kawasaki, Zen-ichiro; Fujiwara, Etsuo; Ishikubo, Yuji; Kawabata, Kinya

    2000-01-01

    Generation of a long laser-plasma channel capable of triggering and guiding an electrical discharge is a crucial issue for laser-triggering protection system. We make a long plasma channel to increase the probability of triggered lightning by laser. To produce a long laser plasma channel, we propose da new technique called hybrid plasma channel method which combines weakly and strongly ionized plasma channels to maximize laser-energy efficiency of discharge guiding. We investigate the characteristics of the hybrid plasma channels to maximize laser-energy efficiency of discharge guiding. We investigate the characteristics of the hybrid plasma channel method through several laboratory experiments. The weakly ionized channel was generated by UV laser pulses in air. As the number density of electrons in weakly ionized channel is proportional to 1.1 power of laser intensity, nitrogen and oxygen molecules can not attributed to the source of ionized plasma. It is suggested that dissociation process of impurities in air whose density is 1011 - 1012 cm-3 plays an important role in plasma formation and leader triggering effect. The 50 percent flashover voltage using the hybrid plasma channel method is lower than that without the weakly ionized plasma channel. It was also found that higher repetition rate of the plasma generation on lowers the V50 furthermore.

  18. Alfvén ionization in an MHD-gas interactions code

    Science.gov (United States)

    Wilson, A. D.; Diver, D. A.

    2016-07-01

    A numerical model of partially ionized plasmas is developed in order to capture their evolving ionization fractions as a result of Alfvén ionization (AI). The mechanism of, and the parameter regime necessary for, AI is discussed and an expression for the AI rate based on fluid parameters, from a gas-MHD model, is derived. This AI term is added to an existing MHD-gas interactions' code, and the result is a linear, 2D, two-fluid model that includes momentum transfer between charged and neutral species as well as an ionization rate that depends on the velocity fields of both fluids. The dynamics of waves propagating through such a partially ionized plasma are investigated, and it is found that AI has a significant influence on the fluid dynamics as well as both the local and global ionization fraction.

  19. Laser resonance ionization scheme development for tellurium and germanium at the dual Ti:Sa–Dye ISOLDE RILIS

    Energy Technology Data Exchange (ETDEWEB)

    Day Goodacre, T., E-mail: thomas.day.goodacre@cern.ch [CERN, CH-1211 Geneva 23 (Switzerland); School of Physics and Astronomy, The University of Manchester, Manchester M13 9PL (United Kingdom); Fedorov, D. [Petersburg Nuclear Physics Institute, 188350 Gatchina (Russian Federation); Fedosseev, V.N.; Forster, L.; Marsh, B.A. [CERN, CH-1211 Geneva 23 (Switzerland); Rossel, R.E. [CERN, CH-1211 Geneva 23 (Switzerland); Institut für Physik, Johannes Gutenberg Universität, D-55099 Mainz (Germany); Faculty of Design, Computer Science and Media, Hochschule RheinMain, Wiesbaden (Germany); Rothe, S.; Veinhard, M. [CERN, CH-1211 Geneva 23 (Switzerland)

    2016-09-11

    The resonance ionization laser ion source (RILIS) is the principal ion source of the ISOLDE radioactive beam facility based at CERN. Using the method of in-source laser resonance ionization spectroscopy, a transition to a new autoionizing state of tellurium was discovered and applied as part of a three-step, three-resonance, photo-ionization scheme. In a second study, a three-step, two-resonance, photo-ionization scheme for germanium was developed and the ionization efficiency was measured at ISOLDE. This work increases the range of ISOLDE RILIS ionized beams to 31 elements. Details of the spectroscopy studies are described and the new ionization schemes are summarized.

  20. Laser resonance ionization scheme development for tellurium and germanium at the dual Ti:Sa–Dye ISOLDE RILIS

    CERN Document Server

    Day Goodacre, T.; Fedosseev, V.N.; Forster, L.; Marsh, B.A.; Rossel, R.E.; Rothe, S.; Veinhard, M.

    2016-01-01

    The resonance ionization laser ion source (RILIS) is the principal ion source of the ISOLDE radioactive beam facility based at CERN. Using the method of in-source laser resonance ionization spectroscopy, a transition to a new autoionizing state of tellurium was discovered and applied as part of a three-step, three-resonance, photo-ionization scheme. In a second study, a three-step, two-resonance, photo-ionization scheme for germanium was developed and the ionization efficiency was measured at ISOLDE. This work increases the range of ISOLDE RILIS ionized beams to 31 elements. Details of the spectroscopy studies are described and the new ionization schemes are summarized.

  1. Laser resonance ionization scheme development for tellurium and germanium at the dual Ti:Sa-Dye ISOLDE RILIS

    Science.gov (United States)

    Day Goodacre, T.; Fedorov, D.; Fedosseev, V. N.; Forster, L.; Marsh, B. A.; Rossel, R. E.; Rothe, S.; Veinhard, M.

    2016-09-01

    The resonance ionization laser ion source (RILIS) is the principal ion source of the ISOLDE radioactive beam facility based at CERN. Using the method of in-source laser resonance ionization spectroscopy, a transition to a new autoionizing state of tellurium was discovered and applied as part of a three-step, three-resonance, photo-ionization scheme. In a second study, a three-step, two-resonance, photo-ionization scheme for germanium was developed and the ionization efficiency was measured at ISOLDE. This work increases the range of ISOLDE RILIS ionized beams to 31 elements. Details of the spectroscopy studies are described and the new ionization schemes are summarized.

  2. Ionization cross sections for electron scattering from metastable rare-gas atoms (Ne* and Ar*)

    Institute of Scientific and Technical Information of China (English)

    Zhang Yong-Zhi; Zhou Ya-Jun

    2013-01-01

    The optical-model approach has been used to investigate the electron-impact ionization of metastable rare-gas atoms.A complex equivalent-local polarization potential is obtained to describe the ionization continuum channels.We have calculated the cross sections for collisional ionization of the metastable atoms Ne* and Ar* by electrons in the energy range from threshold to 200 eV.The present results are in agreement with the available experimental measurements and other theoretical calculations.

  3. A BEAM PROFILE MONITOR USING THE IONIZATION OF RESIDUAL-GAS IN THE BEAM PIPE

    NARCIS (Netherlands)

    SCHIPPERS, JM; KIEWIET, HH; ZIJLSTA, J

    1991-01-01

    A beam profile monitor for high energy beams, which has no intercepting parts in the beam pipe, is described. It makes use of the ionization of the residual gas, which is still present in the vacuum chamber of the beam guiding system. The detection of the ionization products is performed with microc

  4. Simulation of various ionization effects in overdense plasmas irradiated by a subpicosecond pulse laser

    Energy Technology Data Exchange (ETDEWEB)

    Zhidkov, A.; Sasaki, Akira; Tajima, Toshiki [Advanced Photon Research Center, Japan Atomic Energy Research Institute, Neyagawa, Osaka (Japan)

    2000-07-01

    The effects of the elastic collisions and ionization under non-LET on the absorption efficiency, heat transfer, and particle acceleration in short pulse laser irradiated overdense plasmas are studied. We present a newly developed hybrid electromagnetic particle-in-cell method (in 1D) employing the nonlinear Langevin equation to account for Coulomb collisions and the average ion model to calculate the plasma transient ionization. The collisional and field ionization are included. Interaction between solid targets and thin foils with an arbitrary polarized, intense (I=10{sup 16}-10{sup 20} W/cm{sup 2}) laser pulse are investigated. (author)

  5. Gas lasers applied atomic collision physics, v.3

    CERN Document Server

    McDaniel, E W

    1982-01-01

    Applied Atomic Collision Physics, Volume 3: Gas Lasers describes the applications of atomic collision physics in the development of many types of gas lasers. Topics covered range from negative ion formation in gas lasers to high-pressure ion kinetics and relaxation of molecules exchanging vibrational energy. Ion-ion recombination in high-pressure plasmas is also discussed, along with electron-ion recombination in gas lasers and collision processes in chemical lasers.Comprised of 14 chapters, this volume begins with a historical summary of gas laser developments and an overview of the basic ope

  6. Laser-Ionization TOF Mass Spectrometer Characterization of Benzene Destruction in Atmospheric Pressure Pulsed Discharge

    Institute of Scientific and Technical Information of China (English)

    LIU Jiahong; XIAO Qingmei; WANG Liping; YAO Zhi; DING Hongbin

    2009-01-01

    Benzene is.a major industrial air pollutant and can cause serious human health disorders. In this paper an investigation on benzene destruction, in an atmospheric-pressure fast-flow pulsed DC-discharge by means of laser ionization combined with time-of-flight (TOF) mass spectrometry, is reported. Most by-products including transient reactive species from the benzene discharge were characterized by molecular beam sampling combined with TOF mass spectrometry.It is showed that, with a gas mixture of 0.5% C6H6 in Ar, benzene can be effectively destroyed by discharge plasma. The intermediate species consisted of small fragments of CNHm (n=3~5,m =1~11), cycle-chain species of CNHm (n=6~9, m = 7~10) and polycyclic species CNHm (n ≥9,m = 8~12). The alternation of mass peaks (intensity) with even/odd electrons was observed in the measured mass spectra. The results indicated that the alternation is mainly due to the different ionization potentials of the open shell and close shell species. Based on the examination of the features of the species' composition, the primary reaction pathways are proposed and discussed.

  7. Multiphoton and tunneling ionization of atoms in an intense laser field

    Institute of Scientific and Technical Information of China (English)

    Fu Yan-Zhuo; Zhao Song-Feng; Zhou Xiao-Xin

    2012-01-01

    We study the ionization probabilities of atoms by a short laser pulse with three different theoretical methods,i.e.,the numerical solution of the time-dependent Schr(o)dinger equation (TDSE),the Perelomov Popov-Terent'ev (PPT)theory,and the Ammosov-Delone-Krainov (ADK) theory.Our results show that laser intensity dependent ionization probabilities of several atoms (i.e.,H,He,and Ne) obtained from the PPT theory accord quite well with the TDSE results both in the multiphoton and tunneling ionization regimes,while the ADK results fit well to the TDSE data only in the tunneling ionization regime.Our calculations also show that laser intensity dependent ionization probabilities of a H atom at three different laser wavelengths of 600 nm,800 nm,and 1200 nm obtained from the PPT theory are also in good agreement with those from the TDSE,while the ADK theory fails to give the wavelength dependence of ionization probability.Only when the laser wavelength is long enough,will the results of ADK be close to those of TDSE.

  8. Influence of ionization on ultrafast gas-based nonlinear fiber optics.

    Science.gov (United States)

    Chang, W; Nazarkin, A; Travers, J C; Nold, J; Hölzer, P; Joly, N Y; Russell, P St J

    2011-10-10

    We numerically investigate the effect of ionization on ultrashort high-energy pulses propagating in gas-filled kagomé-lattice hollow-core photonic crystal fibers by solving an established uni-directional field equation. We consider the dynamics of two distinct regimes: ionization induced blue-shift and resonant dispersive wave emission in the deep-UV. We illustrate how the system evolves between these regimes and the changing influence of ionization. Finally, we consider the effect of higher ionization stages.

  9. Gas lasers with wave-chaotic resonators

    CERN Document Server

    Zaitsev, Oleg

    2010-01-01

    Semiclassical multimode laser theory is extended to gas lasers with open two-dimensional resonators of arbitrary shape. The Doppler frequency shift of the linear-gain coefficient leads to an additional linear coupling between the modes, which, however, is shown to be negligible. The nonlinear laser equations simplify in the special case of wave-chaotic resonators. In the single-mode regime, the intensity of a chaotic laser, as a function of the mode frequency, displays a local minimum at the frequency of the atomic transition. The width of the minimum scales with the inhomogeneous linewidth, in contrast to the Lamb dip in uniaxial resonators whose width is given by the homogeneous linewidth.

  10. The ionization state in a gas with a non-Maxwellian electron distribution

    Science.gov (United States)

    Owocki, S. P.; Scudder, J. D.

    1981-01-01

    The inferred degree of ionization of a gas is often used in astrophysics as a diagnostic of the gas temperature. In the solar transition region and corona, in the outer atmospheres of cool stars, and in some portions of the interstellar medium), photoionization can be neglected, and the ionization state is fixed by the balance between ion-electron collisional ionization and dielectronic and/or radiative recombination. Under these conditions, higher degrees of ionization result from higher energy ion-electron collisions which are common in a high temperature gas. Actually, ionization occurs through collisions with electrons that have kinetic energies greater than the ionization potential of the given ion, and so the ionization rate depends on to the number of such high-energy electrons in the tail of the electron velocity distribution. High-velocity electrons move across large distances between effective coulomb collisions, and, in a strong temperature or density gradient, the tail can be overpopulated relative to Maxwell-Boltzmann distribution of equivalent energy density. Thus, the ionization rate can also be greatly increased. These effects for a parameterized form of the electron distribution function with an enhanced high-velocity tail, namely the kappa distribution are illustrated.

  11. Intensity-Resolved Above Threshold Ionization of Xenon with Short Laser Pulses

    CERN Document Server

    Hart, Nathan A; Kaya, Gamze; Kaya, Necati; Kolomenskii, Alexandre A; Schuessler, Hans A

    2014-01-01

    We present intensity-resolved above threshold ionization (ATI) spectra of xenon using an intensity scanning and deconvolution technique. Experimental data were obtained with laser pulses of 58 fs and central wavelength of 800 nm from a chirped-pulse amplifier. Applying a deconvolution algorithm, we obtained spectra that have higher contrast and are in excellent agreement with characteristic 2 $U_p$ and 10 $U_p$ cutoff energies contrary to that found for raw data. The retrieved electron ionization probability is consistent with the presence of a second electron from double ionization. This recovered ionization probability is confirmed with a calculation based on the PPT tunneling ionization model [Perelomov, Popov, and Terent'ev, Sov. Phys. JETP 23, 924 (1966)]. Thus, the measurements of photoelectron yields and the proposed deconvolution technique allowed retrieval of more accurate spectroscopic information from the ATI spectra and ionization probability features that are usually concealed by volume averaging...

  12. Nonadiabatic dynamics and multiphoton resonances in strong field molecular ionization with few cycle laser pulses

    CERN Document Server

    Tagliamonti, Vincent; Zhao, Arthur; Rozgonyi, Tamás; Marquetand, Philipp; Weinacht, Thomas

    2016-01-01

    We study strong field molecular ionization using few- (four to ten) cycle laser pulses. Employing a supercontinuum light source, we are able to tune the optical laser wavelength (photon energy) over a range of about $\\sim$200 nm (500 meV). We measure the photoelectron spectrum for a series of different molecules as a function of laser intensity, frequency, and bandwidth and illustrate how the ionization dynamics vary with these parameters. We find that multiphoton resonances and nonadiabatic dynamics (internal conversion) play an important role and result in ionization to different ionic continua. Interestingly, while nuclear dynamics can be "frozen" for sufficiently short laser pulses, we find that resonances strongly influence the photoelectron spectrum and final cationic state of the molecule regardless of pulse duration -- even for pulses that are less than four cycles in duration.

  13. Optimization of a hot-cavity type resonant ionization laser ion source

    Energy Technology Data Exchange (ETDEWEB)

    Henares, J. L., E-mail: henares@ganil.fr; Lecesne, N.; Hijazi, L.; Bastin, B.; Leroy, R.; Osmond, B.; Vignet, J. L. [GANIL, BP 55027, 14076 Caen Cedex 5 (France); Kron, T.; Naubereit, P.; Wendt, K. [Johannes Gutenberg-Universität Mainz, Staudinger Weg 7, 55099 Mainz (Germany); Lassen, J. [TRIUMF, 4004 Wesbrook Mall, Vancouver, British Columbia V6T 2A3 (Canada); Le Blanc, F. [IPN Orsay, BP 1-91406 Orsay (France)

    2016-02-15

    Resonant Ionization Laser Ion Source (RILIS) is nowadays an important technique in many Radioactive Ion Beam (RIB) facilities for its reliability and ability to ionize efficiently and element selectively. Grand Accélérateur National d’Ions Lourds (GANIL) Ion Source using Electron Laser Excitation (GISELE) is an off-line test bench for RILIS developed to study a fully operational resonant laser ion source at GANIL facility. The ion source body has been designed as a modular system to investigate different experimental approaches by varying the design parameters, to develop the future on-line laser ion source. The aim of this project is to determine the best technical solution which combines high selectivity and ionization efficiency with small ion beam emittance and stable long term operation. Latest results concerning emittance and time profile development as a function of the temperature for different ion source versions will be presented.

  14. Spectroscopic analysis of high electric field enhanced ionization in laser filaments in air for corona guiding

    Institute of Scientific and Technical Information of China (English)

    Yingxia Wei; Yaoxiang Liu; Tie-Jun Wang; Na Chen; Jingjing Ju; Yonghong Liu; Haiyi Sun; Cheng Wang; Jiansheng Liu; Haihe Lu; See Leang Chin; Ruxin Li

    2016-01-01

    We report on a systematic experimental study on the fluorescence spectra produced from a femtosecond laser filament in air under a high electric field. The electric field alone was strong enough to create corona discharge(CD). Fluorescence spectra from neutral and ionic air molecules were measured and compared with pure high-voltage CD and pure laser filamentation(FIL). Among them, high electric field assisted laser FIL produced nitrogen fluorescence more efficiently than either pure CD or pure FIL processes. The nonlinear enhancement of fluorescence from the interaction of the laser filament and corona discharging electric field resulted in a more efficient ionization along the laser filament zone, which was confirmed by the spectroscopic measurement of both ionization-induced fluorescence and plasma-scattered 800 nm laser pulses. This is believed to be the key precursor process for filament-guided discharge.

  15. Mass spectrometry analysis of polychlorinated biphenyls: chemical ionization and selected ion chemical ionization using methane as a reagent gas

    Directory of Open Access Journals (Sweden)

    RAYMOND E. MARCH

    2000-06-01

    Full Text Available In the present paper a quadrupole ion trap mass spectrometer, coupled with a gas chromatograph, was used to compare the electron impact ionization (EI and chemical ionization (Cl technique, in terms of their selectivity in polychlorinated biphenyls (PCBs quantitative analysis. The experiments were carried out with a modified Varian SATURN III quadrupole ion-storage mass spectrometer equipped with Varian waveform generator, coupled with a gas chromatograph with DB-5 capillary column. The disadvantage of using EI in the analysis of PCBs congeners is the extensive fragmentation of the molecular ion. The main fragmentation pattern recorded in the EI mass spectra of PCBs was the loss of a chlorine atom from the molecular ion. Therefore the fragment-ion signal overlapped with the molecular-ion cluster of lower mass congener. The fragmentation reactions of PCBs are suppressed if methane is used as a reagent gas for chemical ionization, but fragment ions are also present in the spectrum as an obstruction for quantitative analysis. The most selective method for PCBs quantitative analysis appears to be Cl with mass-selected C2H5+ ions from methane, which results in a mass spectrum with a negligible amount of fragment ions.

  16. Characterization of nonpolar lipids and steroids by using laser-induced acoustic desorption/chemical ionization, atmospheric pressure chemical ionization, and electrospray ionization mass spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Jin, Z; Daiya, S; Kenttämaa, Hilkka I

    Laser-induced acoustic desorption (LIAD) combined with ClMn(H{sub 2}O){sup +} chemical ionization (CI) was tested for the analysis of nonpolar lipids and selected steroids in a Fourier-transform ion cyclotron resonance mass spectrometer (FT-ICR). The nonpolar lipids studied, cholesterol, 5α-cholestane, cholesta-3,5-diene, squalene, and β-carotene, were found to solely form the desired water replacement product (adduct-H{sub 2}O) upon reaction with the ClMn(H{sub 2}O){sup +} ions. The steroids, androsterone, dehydroepiandrosterone (DHEA), estrone, estradiol, and estriol, also form abundant adduct-H{sub 2}O ions, but less abundant adduct-2H{sub 2}O ions were also observed. Neither (+)APCI nor (+)ESI can ionize the saturated hydrocarbon lipid, cholestane. APCI successfully ionizes the unsaturated hydrocarbon lipids to form exclusively the intact protonated analytes. However, it causes extensive fragmentation for cholesterol and the steroids. The worst case is cholesterol that does not produce any stable protonated molecules. On the other hand, ESI cannot ionize any of the hydrocarbon analytes, saturated or unsaturated. However, ESI can be used to protonate the oxygen-containing analytes with substantially less fragmentation than for APCI in all cases except for cholesterol and estrone. In conclusion, LIAD/ClMn(H{sub 2}O){sup +} chemical ionization is superior over APCI and ESI for the mass spectrometric characterization of underivatized nonpolar lipids and steroids.

  17. Ionization Induced Scattering of Femtosecond Intense Laser Pulses in Cluster Plasmas

    Institute of Scientific and Technical Information of China (English)

    Wang Xiangxin; Wang Cheng; Liu Jiansheng; Li Shaohui; Ni Guoquan

    2005-01-01

    The 45° scattering of a femtosecond (60 fs) intense laser pulse with a 20 nm FWHM (the full width at half maximum) spectrum centered at 790 nm has been studied experimentally while focused in argon clusters at intensity ~ 1016 W/cra2. Scattering spectra under different backing pressures and laser-plasma interaction lengths were obtained, which showed spectral blueshifting, beam refraction and complex modulation. These ionization-induced effects reveal the modulation of laser pulses propagating in plasmas and the existing obstacle in laser cluster interaction at high laser intensity and high electron density.

  18. Chemical characterization of latent fingerprints by matrix-assisted laser desorption ionization, time-of-flight secondary ion mass spectrometry, mega electron volt secondary mass spectrometry, gas chromatography/mass spectrometry, X-ray photoelectron spectroscopy, and attenuated total reflection Fourier transform infrared spectroscopic imaging: an intercomparison.

    Science.gov (United States)

    Bailey, Melanie J; Bright, Nicholas J; Croxton, Ruth S; Francese, Simona; Ferguson, Leesa S; Hinder, Stephen; Jickells, Sue; Jones, Benjamin J; Jones, Brian N; Kazarian, Sergei G; Ojeda, Jesus J; Webb, Roger P; Wolstenholme, Rosalind; Bleay, Stephen

    2012-10-16

    The first analytical intercomparison of fingerprint residue using equivalent samples of latent fingerprint residue and characterized by a suite of relevant techniques is presented. This work has never been undertaken, presumably due to the perishable nature of fingerprint residue, the lack of fingerprint standards, and the intradonor variability, which impacts sample reproducibility. For the first time, time-of-flight secondary ion mass spectrometry, high-energy secondary ion mass spectrometry, and X-ray photoelectron spectroscopy are used to target endogenous compounds in fingerprints and a method is presented for establishing their relative abundance in fingerprint residue. Comparison of the newer techniques with the more established gas chromatography/mass spectrometry and attenuated total reflection Fourier transform infrared spectroscopic imaging shows good agreement between the methods, with each method detecting repeatable differences between the donors, with the exception of matrix-assisted laser desorption ionization, for which quantitative analysis has not yet been established. We further comment on the sensitivity, selectivity, and practicability of each of the methods for use in future police casework or academic research.

  19. Ghost peaks observed after atmospheric pressure matrix-assisted laser desorption/ionization experiments may disclose new ionization mechanism of matrix-assisted hypersonic velocity impact ionization.

    Science.gov (United States)

    Moskovets, Eugene

    2015-08-30

    Understanding the mechanisms of matrix-assisted laser desorption/ionization (MALDI) promises improvements in the sensitivity and specificity of many established applications in the field of mass spectrometry. This paper reports a serendipitous observation of a significant ion yield in a post-ionization experiment conducted after the sample had been removed from a standard atmospheric pressure (AP)-MALDI source. This post-ionization is interpreted in terms of collisions of microparticles moving with a hypersonic velocity into a solid surface. Calculations show that the thermal energy released during such collisions is close to that absorbed by the top matrix layer in traditional MALDI. The microparticles, containing both the matrix and analytes, could be detached from a film produced inside the inlet capillary during the sample ablation and accelerated by the flow rushing through the capillary. These observations contribute some new perspective to ion formation in both laser and laser-less matrix-assisted ionization. An AP-MALDI ion source hyphenated with a three-stage high-pressure ion funnel system was utilized for peptide mass analysis. After the laser had been turned off and the MALDI sample removed, ions were detected during a gradual reduction of the background pressure in the first funnel. The constant-rate pressure reduction led to the reproducible appearance of different singly and doubly charged peptide peaks in mass spectra taken a few seconds after the end of the MALDI analysis of a dried-droplet spot. The ion yield as well as the mass range of ions observed with a significant delay after a completion of the primary MALDI analysis depended primarily on the background pressure inside the first funnel. The production of ions in this post-ionization step was exclusively observed during the pressure drop. A lower matrix background and significant increase in relative yield of double-protonated ions are reported. The observations were partially consistent

  20. Enhanced performance of a repetitively pulsed 130 mJ KrF laser with improved pre-ionization parameters

    Indian Academy of Sciences (India)

    N S Benerji; A Singh; N Varshnay; Bijendra Singh

    2014-01-01

    Studies related to the effect of pre-ionizer on laser output energy of a repetitively pulsed KrF laser are presented. The dependence of laser output energy, spectral width and beam spot homogeneity on pre-ionization parameters, namely its current and voltage rise time are reported here. Here, effectiveness of pre-ionization is optimized by improving pre-ionization current and rise time of the pump pulse of the automatic UV pre-ionizer KrF laser. It is observed that by increasing pre-ionization current from 6 kA to 10.6 kA, the output energy increases by about 30% (from 100 to 130 mJ). It is also observed that the emission spectral width reduces by almost 60% by increasing the pre-ionization current. Regular homogeneous and well-developed beam spot (nearly Hat-Top profile) was achieved under these optimized conditions.

  1. X-ray detector for automatic exposure control using ionization chamber filled with xenon gas

    CERN Document Server

    Nakagawa, A; Yoshida, T

    2003-01-01

    This report refers to our newly developed X-ray detector for reliable automatic X-ray exposure control, which is to be widely used for X-ray diagnoses in various clinical fields. This new detector utilizes an ionization chamber filled with xenon gas, in contrast to conventional X-ray detectors which use ionization chambers filled with air. Use of xenon gas ensures higher sensitivity and thinner design of the detector. The xenon gas is completely sealed in the chamber, so that the influence of the changes in ambient environments is minimized. (author)

  2. Fast outflow of neutral and ionized gas from the radio galaxy 3C 293

    OpenAIRE

    Emonts, B. H. C.; Morganti, R.; Oosterloo, T A; Tadhunter, C.N.; van der Hulst, J. M.

    2005-01-01

    Abstract: We detect a fast outflow of neutral and ionized gas with velocities up to about 1000 km/s from the central region of radio galaxy 3C 293. With optical spectroscopy we locate the bulk of the ionized gas outflow at the position of a bright radio hot-spot in the inner radio jet, about 1 kpc east of the nucleus. Given the presence of large amounts of cold gas and the distorted morphology of the radio jet in this region, we argue that the ISM is pushed out by a severe interaction with th...

  3. Study of low work function materials for hot cavity resonance ionization laser ion sources

    CERN Document Server

    Schwellnus, F; Crepieux, B; Fedosseev, V N; Marsh, B A; Mattolat, Ch; Menna, M; Österdahl, F K; Raeder, S; Stora, T; Wendta, K

    2009-01-01

    The selectivity of a hot cavity resonance ionization laser ion source (RILIS) is most often limited by contributions from competing surface ionization of the hot walls of the ionization cavity. In this article we present investigations on the properties of designated high temperature, low work function materials regarding their performance and suitability as cavity material for RILIS. Tungsten test cavities, impregnated with a mixture of barium oxide and strontium oxide (BaOSrO on W), or alternatively gadolinium hexaboride (GdB6) were studied in comparison to a standard tungsten RILIS cavity as being routinely used for hot cavity laser ionization at ISOLDE. Measurement campaigns took place at the off-line mass separators at ISOLDE/CERN, Geneva and RISIKO/University of Mainz.

  4. Study of Low Work Function Materials for Hot Cavity Resonance Ionization Laser Ion Sources

    CERN Document Server

    Catherall, R; Fedosseev, V; Marsh, B; Mattolat, C; Menna, Mariano; Österdahl, F; Raeder, S; Schwellnus, F; Stora, T; Wendt, K; CERN. Geneva. AB Department

    2008-01-01

    The selectivity of a hot cavity resonance ionization laser ion source (RILIS) is most often limited by contributions from competing surface ionization on the hot walls of the ionization cavity. In this article we present investigations on the properties of designated high-temperature, low-work function materials regarding their performance and suitability as cavity material for RILIS. Tungsten test cavities, impregnated with a mixture of barium oxide and strontium oxide (BaOSrO on W), or alternatively gadolinium hexaboride (GdB6) were studied in comparison to a standard tungsten RILIS cavity as being routinely used for hot cavity laser ionization at ISOLDE. Measurement campaigns took place at the off-line mass separators at ISOLDE / CERN, Geneva and RISIKO / University of Mainz.

  5. Plasma Physics Issues in Gas Discharge Laser Development

    Science.gov (United States)

    1991-12-01

    WL-TR-92-2087 PLASMA PHYSICS ISSUES IN GAS DISCHARGE LASER DEVELOPMENT AD-A257 735 ALAN GARSCADDEN MARK J. KUSNER J. GARY EDEN WL/POOC-3 WRIGHT...LASERS INFRARED MOLECULAR jAS LASERS UNCLASSIFIED UNCLASSIFIED UNCLASSIFIED UL Plasma Physics Issues in Gas Discharge Laser Development Alan Garscadden...the close coupling between body of work was not generally useful in laser development . vibrationally excited nitrogen and CO or CO2 . In fact. the First

  6. Selective Strong-Field Enhancement and Suppression of Ionization with Short Laser Pulses

    CERN Document Server

    Hart, Nathan A; Kolomenskii, Alexandre A; Paulus, Gerhard G; Bauer, Dieter; Schuessler, Hans A

    2015-01-01

    We experimentally demonstrate robust selective excitation and attenuation of atomic Rydberg level populations in sodium vapor (Na I) using intense laser pulses in the strong field limit ($> 10^{12} W/cm^{2}$). The coherent control of the atomic population and related ionization channels is realized for intensities above the over-the-barrier ionization intensity. A qualitative model predicts that this strong field coherent control arises through the manifestation of a Freeman resonance.

  7. Unusual Fragmentation of Peptide and Protein in Matrix-assisted Laser Desorption/Ionization Mass Spectrometry

    Institute of Scientific and Technical Information of China (English)

    Mitsuo Takayama

    2001-01-01

    Unusual amine - bond fragmentation on the peptide/protein backbone has been reported using matrix - assisted laser desorption/ionization time - of- flight mass spectrometry (MALDI - TOFMS)The amine - bond cleavage occurred without metastable decay, while the peptide - bond cleavage occurred with metastable decay of peptide ions in a drift region of TOF mass analyzer. It was presumed that the amine - bond cleavage occurred as a non - ergodic process independent of the ionization under MALDI conditions.

  8. Modeling and simulation of two-step resonance ionization processes using CW and pulsed lasers

    CERN Document Server

    de Groote, Ruben; Flanagan, Kieran

    This thesis derives and discusses equations that describe the evolution of atomic systems subjected to two monochromatic and coherent radiation fields and treats both continuous and temporally pulsed irradiation. This theoretical description is de- veloped mainly to understand the influence of the photon field intensities on experimental ionization spectra. The primary ap- plication of this theoretical framework is on methods that rely on resonant laser excitation and non-resonant laser ionization to extract information on the hyperfine structure of atomic systems. In particular, qualitative and quantitative discussions on the laser-related changes in hyperfine splitting extracted from ion- ization spectra are presented. Also, a method for increasing the resolution of resonance ionization techniques (potentially up un- til the natural linewidth of the electronic transitions) is discussed and theoretically justified. Both topics are illustrated with exper- imental data.

  9. Multiphoton ionization of jet-cooled nickelocene with tunable nanosecond laser pulses

    Science.gov (United States)

    Ketkov, Sergey Yu.; Selzle, Heinrich L.; Schlag, Edward W.; Titova, Sofia N.

    2003-08-01

    Efficient multiphoton ionization of nickelocene molecules in a supersonically cooled molecular beam has been performed for the first time with a nanosecond tunable dye laser operating in the 35,000-cm -1 region which corresponds to the lowest Rydberg transition observed in the one-photon absorption spectrum. The time-of-flight mass spectra obtained show strong signals of intact molecular ions Cp 2Ni + (Cp=η 5-C 5H 5) and weaker peaks of fragment ions CpNi +. The conditions have been found for generation of Cp 2Ni + as the only ionic product of multiphoton excitation. The ion signal dependence on the laser intensity and the resonance-enhanced multiphoton ionization spectrum measured at the mass of Cp 2Ni + testify for saturation of absorption and/or ionization steps at the laser pulse intensities used (2-6 MW cm -2). Possible mechanisms of multiphoton processes resulting in formation of the ions observed are discussed.

  10. High-order harmonic generation and multi-photon ionization of Na2 in laser fields

    Institute of Scientific and Technical Information of China (English)

    Zhang Yan-Ping; Zhang Feng-Shou; Meng Ke-Lai; Xiao Guo-Qing

    2007-01-01

    In this paper high-order harmonic generation (HHG) spectra and the ionization probabilities of various charge states of small cluster Na2 in the multiphoton regimes are calculated by using time-dependent local density approximation (TDLDA) for one-colour (1064 nm) and two-colour (1064 nm and 532 nm) ultrashort (25 fs) laser pulses. HHG spectra of Na2 have not the large extent of plateaus due to pronounced collective effects of electron dynamics. In addition, the two-colour laser field can result in the breaking of the symmetry and generation of the even order harmonic such as the second order harmonic. The results of ionization probabilities show that a two-colour laser field can increase the ionization probability of higher charge state.

  11. Gas chromatography coupled to atmospheric pressure ionization mass spectrometry (GC-API-MS): review.

    Science.gov (United States)

    Li, Du-Xin; Gan, Lin; Bronja, Amela; Schmitz, Oliver J

    2015-09-03

    Although the coupling of GC/MS with atmospheric pressure ionization (API) has been reported in 1970s, the interest in coupling GC with atmospheric pressure ion source was expanded in the last decade. The demand of a "soft" ion source for preserving highly diagnostic molecular ion is desirable, as compared to the "hard" ionization technique such as electron ionization (EI) in traditional GC/MS, which fragments the molecule in an extensive way. These API sources include atmospheric pressure chemical ionization (APCI), atmospheric pressure photoionization (APPI), atmospheric pressure laser ionization (APLI), electrospray ionization (ESI) and low temperature plasma (LTP). This review discusses the advantages and drawbacks of this analytical platform. After an introduction in atmospheric pressure ionization the review gives an overview about the history and explains the mechanisms of various atmospheric pressure ionization techniques used in combination with GC such as APCI, APPI, APLI, ESI and LTP. Also new developments made in ion source geometry, ion source miniaturization and multipurpose ion source constructions are discussed and a comparison between GC-FID, GC-EI-MS and GC-API-MS shows the advantages and drawbacks of these techniques. The review ends with an overview of applications realized with GC-API-MS.

  12. Identification of Fatty Acids, Phospholipids, and Their Oxidation Products Using Matrix-Assisted Laser Desorption Ionization Mass Spectrometry and Electrospray Ionization Mass Spectrometry

    Science.gov (United States)

    Harmon, Christopher W.; Mang, Stephen A.; Greaves, John; Finlayson-Pitts, Barbara J.

    2010-01-01

    Electrospray ionization mass spectrometry (ESI-MS) and matrix-assisted laser desorption ionization mass spectrometry (MALDI-MS) have found increasing application in the analysis of biological samples. Using these techniques to solve problems in analytical chemistry should be an essential component of the training of undergraduate chemists. We…

  13. Identification of Fatty Acids, Phospholipids, and Their Oxidation Products Using Matrix-Assisted Laser Desorption Ionization Mass Spectrometry and Electrospray Ionization Mass Spectrometry

    Science.gov (United States)

    Harmon, Christopher W.; Mang, Stephen A.; Greaves, John; Finlayson-Pitts, Barbara J.

    2010-01-01

    Electrospray ionization mass spectrometry (ESI-MS) and matrix-assisted laser desorption ionization mass spectrometry (MALDI-MS) have found increasing application in the analysis of biological samples. Using these techniques to solve problems in analytical chemistry should be an essential component of the training of undergraduate chemists. We…

  14. Prediction of Shock Wave Structure in Weakly Ionized Gas Flow by Solving MGD Equation

    Science.gov (United States)

    Deng, Z. T.; Oviedo-Rojas, Ruben; Chow, Alan; Litchford, Ron J.; Cook, Stephen (Technical Monitor)

    2002-01-01

    This paper reports the recent research results of shockwave structure predictions using a new developed code. The modified Rankine-Hugoniot relations across a standing normal shock wave are discussed and adopted to obtain jump conditions. Coupling a electrostatic body force to the Burnett equations, the weakly ionized flow field across the shock wave was solved. Results indicated that the Modified Rankine-Hugoniot equations for shock wave are valid for a wide range of ionization fraction. However, this model breaks down with small free stream Mach number and with large ionization fraction. The jump conditions also depend on the value of free stream pressure, temperature and density. The computed shock wave structure with ionization provides results, which indicated that shock wave strength may be reduced by existence of weakly ionized gas.

  15. Dissociative multiple ionization of diatomic molecules by extreme-ultraviolet free-electron-laser pulses

    DEFF Research Database (Denmark)

    Madsen, Lars Bojer; Leth, Henriette Astrup

    2011-01-01

    Nuclear dynamics in dissociative multiple ionization processes of diatomic molecules exposed to extreme-ultraviolet free-electron-laser pulses is studied theoretically using the Monte Carlo wave packet approach. By simulated detection of the emitted electrons, the model reduces a full propagation...... of the system to propagations of the nuclear wave packet in one specific electronic charge state at a time. Suggested ionization channels can be examined, and kinetic energy release spectra for the nuclei can be calculated and compared with experiments. Double ionization of O2 is studied as an example, and good...

  16. Non-Sequential Double Ionization by Counter Rotating Circularly Polarized Two-Color Laser Fields

    CERN Document Server

    Eckart, S; Kunitski, M; Hartung, A; Rist, J; Henrichs, K; Schlott, N; Kang, H; Bauer, T; Sann, H; Schmidt, L Ph H; Schöffler, M; Jahnke, T; Dörner, R

    2016-01-01

    We report on non-sequential double ionization of Ar by a laser pulse consisting of two counter rotating circularly polarized fields (390 nm and 780 nm). The double ionization probability depends strongly on the relative intensity of the two fields and shows a "knee"-like structure as function of intensity. We conclude that double ionization is driven by a beam of nearly monoenergetic recolliding electrons, which can be controlled in intensity and energy by the field parameters. The electron momentum distributions show the recolliding electron as well as a second electron which escapes from an intermediate excited state of Ar$^+$.

  17. Optical field ionization of atoms and ions using ultrashort laser pulses

    Energy Technology Data Exchange (ETDEWEB)

    Fittinghoff, D.N.

    1993-12-01

    This dissertation research is an investigation of the strong optical field ionization of atoms and ions by 120-fs, 614-run laser pulses and 130-fs, 800-nm laser pulses. The experiments have shown ionization that is enhanced above the predictions of sequential tunneling models for He{sup +2}, Ne{sup +2} and Ar{sup +2}. The ion yields for He{sup +l}, Ne{sup +l} and Ar{sup +l} agree well with the theoretical predictions of optical tunneling models. Investigation of the polarization dependence of the ionization indicates that the enhancements are consistent with a nonsequential ionization mechanism in which the linearly polarized field drives the electron wavefunction back toward the ion core and causes double ionization through inelastic e-2e scattering. These investigations have initiated a number of other studies by other groups and are of current scientific interest in the fields of high-irradiance laser-matter interactions and production of high-density plasmas. This work involved: (1) Understanding the characteristic nature of the ion yields produced by tunneling ionization through investigation of analytic solutions for tunneling at optical frequencies. (2) Extensive characterization of the pulses produced by 614-nm and 800-ran ultrashort pulse lasers. Absolute calibration of the irradiance scale produced shows the practicality of the inverse problem--measuring peak laser irradiance using ion yields. (3) Measuring the ion yields for three noble gases using linear, circular and elliptical polarizations of laser pulses at 614-nm and 800-nm. The measurements are some of the first measurements for pulse widths as low as 120-fs.

  18. Surface-assisted laser desorption ionization mass spectrometry techniques for application in forensics.

    Science.gov (United States)

    Guinan, Taryn; Kirkbride, Paul; Pigou, Paul E; Ronci, Maurizio; Kobus, Hilton; Voelcker, Nicolas H

    2015-01-01

    Matrix-assisted laser desorption ionization (MALDI) mass spectrometry (MS) is an excellent analytical technique for the rapid and sensitive analysis of macromolecules (>700 Da), such as peptides, proteins, nucleic acids, and synthetic polymers. However, the detection of smaller organic molecules with masses below 700 Da using MALDI-MS is challenging due to the appearance of matrix adducts and matrix fragment peaks in the same spectral range. Recently, nanostructured substrates have been developed that facilitate matrix-free laser desorption ionization (LDI), contributing to an emerging analytical paradigm referred to as surface-assisted laser desorption ionization (SALDI) MS. Since SALDI enables the detection of small organic molecules, it is rapidly growing in popularity, including in the field of forensics. At the same time, SALDI also holds significant potential as a high throughput analytical tool in roadside, work place and athlete drug testing. In this review, we discuss recent advances in SALDI techniques such as desorption ionization on porous silicon (DIOS), nano-initiator mass spectrometry (NIMS) and nano assisted laser desorption ionization (NALDI™) and compare their strengths and weaknesses with particular focus on forensic applications. These include the detection of illicit drug molecules and their metabolites in biological matrices and small molecule detection from forensic samples including banknotes and fingerprints. Finally, the review highlights recent advances in mass spectrometry imaging (MSI) using SALDI techniques.

  19. Laser resonance ionization for ultra-trace analysis on long-lived radioactive isotopes

    Indian Academy of Sciences (India)

    Christopher Geppert; Klaus D A Wendt

    2010-12-01

    Benefiting from the continuous laser developments, resonance ionization can be applied for a variety of experiments on radioactive isotopes, e.g. as a laser ion source for producing pure beams of short-lived isotopes at on-line facilities. In this paper the application of a compact set-up for resonance ionization mass spectrometry for ultra-trace analysis of the long-lived isotope Ca-41 is described. With this set-up a purely optical selectivity of 3 × 109 and an overall detection efficiency of 1.2(4) × 10−5 are demonstrated.

  20. Relativistic semi-classical theory of atom ionization in ultra-intense laser

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    A relativistic semi-classical theory (RSCT) of H-atom ionizationin ultra-intense laser (UIL) is proposed. A relativistic analytical expression for ionization probability of H-atom in its ground state is given. This expression, compared with non-relativistic expression, clearly shows the effects of the magnet vector in the laser, the non-dipole approximation and the relativistic mass-energy relation on the ionization processes. At the same time, we show that under some conditions the relativistic expression reduces to the non-relativistic expression of non-dipole approximation. At last, some possible applications of the relativistic theory are briefly stated.

  1. Recent progress in application of carbon nanomaterials in laser desorption/ionization mass spectrometry.

    Science.gov (United States)

    Wang, Jing; Liu, Qian; Liang, Yong; Jiang, Guibin

    2016-04-01

    Carbon nanomaterials have attracted great interest over past decades owing to their unique physical properties, versatile functionalization chemistry, and biological compatibility. In this article, we review recent progress in application of carbon nanomaterials in laser desorption/ionization mass spectrometry (LDI MS). Various types of carbon nanomaterials, including fullerenes, carbon nanotubes, graphene, carbon nanodots, nanodiamond, nanofibers, nanohorns, and their derivative forms, are involved. The applications of these materials as new matrices or probes in matrix-assisted or surface-enhanced laser desorption/ionization mass spectrometry (MALDI or SELDI MS) are discussed. Finally, we summarize current challenges and give our perspectives on the future of applications of carbon nanomaterials in LDI MS.

  2. Lattice-Boltzmann simulation of laser interaction with weakly ionized helium plasmas.

    Science.gov (United States)

    Li, Huayu; Ki, Hyungson

    2010-07-01

    This paper presents a lattice Boltzmann method for laser interaction with weakly ionized plasmas considering electron impact ionization and three-body recombination. To simulate with physical properties of plasmas, the authors' previous work on the rescaling of variables is employed and the electromagnetic fields are calculated from the Maxwell equations by using the finite-difference time-domain method. To calculate temperature fields, energy equations are derived separately from the Boltzmann equations. In this way, we attempt to solve the full governing equations for plasma dynamics. With the developed model, the continuous-wave CO2 laser interaction with helium is simulated successfully.

  3. Spectral splitting of high order harmonics of ionizing gases irradiated with ultrashort intense laser pulses

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    [1]Chang Zenghu,Rundquist,A.,Wang Haiwen et al.,Generation of coherent soft X-rays a 2.7 nm using high harmonics,Phys.Rev.Lett.,1997,79(16): 2967-2970.[2]Schnurer,M.,Spielmann,Ch.,Wobrauschek,P.et al.,Coherent 0.5 keV X-ray emission from Helium driven by a sub-10-fs laser,Phys.Rev.Lett.,1998,80(15): 3236-3239.[3]Corkum,P.B.,Plasma perspective on strong-field multiphoton ionization,Phys.Rev.Lett.,1993,71(13): 1994-1997.[4]Lewenstein,M.,Balcou,Ph.,Yu.M.et al.,Theory of high-harmonic generation by low frequency laser fields,Phys.Rev.A,1994,49(3): 2117-2132.[5]Li,X.F.,L'Huillier,A.L.,Ferray,M.et al.,Multiple-harmonic generation in rare gases at high laser intensity,Phys.Rev.A,1989,39(11): 5751-5761.[6]L'Huillier,A.,Schafer,K.J.,Kulander,K.C.,Theoretical aspects of intense field harmonic generation,J.Phys.B,1991,24(),3315-3341.[7]L'Huillier,A.,Balcou,Ph.,Candel,S.et al.,Calculation of high-order harmonic-generation processin Xeon at 1064 nm,Phys.Rev.A,1992,46(5): 2778-2790.[8]Balcou,Ph.,L'Huillier,A.,Phase-matching effects in strong-field harmonics generation,Phys.Rev.A,1993,47(2): 1447-1459.[9]Race,S.C.,Burnett,K.,Detailed simulation of plasma-induced spectral blueshifting,Phys.Rev.A,1992,46(2): 1084-1090.[10]Wood,W.M.,Siders,C.W.,Downer,M.C.,Measurement of femtosecond ionization dynamics of atmosphere density gases by spectral blueshifting ,Phys.Rev.Lett.,1991,67(25): 3523-3526.[11]Le Blanc S.P.,Sauerbrey,R.,Rae,S.C.et al.,Spectral blue shifting of a femtosecond laser pulse propagating through a high-pressure gas,J.Opt.Soc.Am.B,1993,10(10): 1801-1809.[12]Le Blanc,S.P.,Sauerbrey,R.,Spectral,temporal,and spatial characteristics of plasma-induced spectral blue shifting and its application to femtosecond pulse measurement,J.Opt.Soc.Am.B,1996,[13](1): 72-88.13.Burnett,N.H.,Corkum,P.B.,Cold-plasma production for recombination extreme-ultraviolet lasers by optical-field-induced ionization,J.Opt.Soc.Am.B,1989,6(6): 1195

  4. Ionization and scintillation response of high-pressure xenon gas to alpha particles

    CERN Document Server

    Álvarez, V; Cárcel, S; Cebrián, S; Cervera, A; Conde, C A N; Dafni, T; Díaz, J; Egorov, M; Esteve, R; Evtoukhovitch, P; Fernandes, L M P; Ferrario, P; Ferreira, A L; Freitas, E D C; Gehman, V M; Gil, A; Goldschmidt, A; Gómez, H; Gómez-Cadenas, J J; González-Díaz, D; Gutiérrez, R M; Hauptman, J; Morata, J A Hernando; Herrera, D C; Irastorza, I G; Jinete, M A; Labarga, L; Laing, A; Liubarsky, I; Lopes, J A M; Lorca, D; Losada, M; Luzón, G; Marí, A; Martín-Albo, J; Miller, T; Moiseenko, A; Monrabal, F; Monteiro, C M B; Mora, F J; Moutinho, L M; Vidal, J Muñoz; da Luz, H Natal; Navarro, G; Nebot, M; Nygren, D; Oliveira, C A B; Palma, R; Pérez, J; Aparicio, J L Pérez; Renner, J; Ripoll, L; Rodríguez, A; Rodríguez, J; Santos, F P; Santos, J M F dos; Segui, L; Serra, L; Shuman, D; Simón, A; Sofka, C; Sorel, M; Toledo, J F; Tomás, A; Torrent, J; Tsamalaidze, Z; Vázquez, D; Veloso, J F C A; Webb, R; White, J T; Yahlali, N

    2012-01-01

    High-pressure xenon gas is an attractive detection medium for a variety of applications in fundamental and applied physics. In this paper we study the transport properties of ionization electrons, and the mechanism of electron-ion recombination, in xenon gas at 10 bar pressure. For this purpose, we use a source of alpha particles in the NEXT-DEMO time projection chamber, the large scale prototype of the NEXT-100 neutrinoless double beta decay experiment, in three different drift electric field configurations. Our electron drift velocity and longitudinal diffusion results are similar to expectations based on available electron scattering cross sections on pure xenon, favoring low-diffusion models. In addition, two types of measurements addressing the connection between the ionization and scintillation yields were performed. On the one hand we observe, for the first time in xenon gas, large event-by-event correlated fluctuations between the ionization and scintillation signals, similarly to what has already bee...

  5. Intense laser induced field ionization of C2H2, C2H4,and C2H6

    Institute of Scientific and Technical Information of China (English)

    GAO Lirong; JI Na; XONG Yijia; TANG Xiaoping; KONG Fan'ao

    2003-01-01

    Using HOMO Field Ionization Model, the tunneling probabilities and the theoretical threshold intensities of the field ionizations of acetylene, ethylene, and ethane in intense laser field are calculated. C2H2, C2H4, and C2H6 were irradiated by 800 nm, 100 fs laser pulses with the intensity range of 1013-1014 W/cm2. A TOF-mass spectrometer was coupled to the laser system and used to experimentally investigate the field ionization of these molecules. The experimental ionization threshold intensities are obtained. The calculating results of the three molecules agree well with the experimental results, indicating that HOMO Field Ionization Model is valid for the ionization of polyatomic molecules in intense laser field.

  6. A critical test for distorted wave theories: laser-assisted single ionization by ion impact

    Energy Technology Data Exchange (ETDEWEB)

    Ciappina, Marcelo [Max-Planck-Institut fuer Physik Komplexer Systeme, Dresden (Germany); Madsen, Lars Bojer [Department of Physics and Astronomy, Univ. of Aarhus (Denmark)

    2008-07-01

    We study single ionization in laser-assisted high-energy non-relativistic ion-atom collisions and show that the low-energy angular differential electron spectrum may be enhanced significantly by a weak external field. With increasing the strength of the assisting field, the energy spectrum develops a plateau with a characteristic cut-off. In the plateau region we predict distinct multiphoton peaks separated by the photon-energy of the laser field. In the present laser-assisted continuum-distorted-wave eikonal-initial-state (LA-CDW-EIS) theory, this effect may be related to the dynamics in the two-body electron-projectile subsystem. The combined process where an electron is ionized by a heavy ion and subsequently moves in the laser field and under the influence of the Coulomb fields of the projectile and the target represents a stringent test for distorted wave theories.

  7. Quantum mechanical theory of collisional ionization in the presence of intense laser radiation

    Science.gov (United States)

    Bellum, J. C.; George, T. F.

    1978-01-01

    The paper presents a quantum mechanical formalism for treating ionizing collisions occurring in the presence of an intense laser field. Both the intense laser radiation and the internal electronic continuum states associated with the emitted electrons are rigorously taken into account by combining discretization techniques with expansions in terms of electronic-field representations for the quasi-molecule-plus-photon system. The procedure leads to a coupled-channel description of the heavy-particle dynamics which involves effective electronic-field potential surfaces and continua. It is suggested that laser-influenced ionizing collisions can be studied to verify the effects of intense laser radiation on inelastic collisional processes. Calculation procedures for electronic transition dipole matrix elements between discrete and continuum electronic states are outlined.

  8. Atmospheric pressure laser-induced acoustic desorption chemical ionization Fourier transform ion cyclotron resonance mass spectrometry for the analysis of complex mixtures.

    Science.gov (United States)

    Nyadong, Leonard; McKenna, Amy M; Hendrickson, Christopher L; Rodgers, Ryan P; Marshall, Alan G

    2011-03-01

    We present a novel nonresonant laser-based matrix-free atmospheric pressure ionization technique, atmospheric pressure laser-induced acoustic desorption chemical ionization (AP/LIAD-CI). The technique decouples analyte desorption from subsequent ionization by reagent ions generated from a corona discharge initiated in ambient air or in the presence of vaporized toluene as a CI dopant at room temperature. Analyte desorption is initiated by a shock wave induced in a titanium foil coated with electrosprayed sample, irradiated from the rear side by high-energy laser pulses. The technique enables facile and independent optimization of the analyte desorption, ionization, and sampling events, for coupling to any mass analyzer with an AP interface. Moreover, the generated analyte ions are efficiently thermalized by collisions with atmospheric gases, thereby reducing fragmentation. We have coupled AP/LIAD-CI to ultrahigh-resolution FT-ICR MS to generate predominantly [M + H](+) or M(+•) ions to resolve and identify thousands of elemental compositions from organic mixtures as complex as petroleum crude oil distillates. Finally, we have optimized the AP/LIAD CI process and investigated ionization mechanisms by systematic variation of placement of the sample, placement of the corona discharge needle, discharge current, gas flow rate, and inclusion of toluene as a dopant.

  9. Ionization of oriented carbonyl-sulfide molecules by intense circularly polarized laser pulses

    CERN Document Server

    Dimitrovski, Darko; Madsen, Lars Bojer; Filsinger, Frank; Meijer, Gerard; Küpper, Jochen; Holmegaard, Lotte; Kalhøj, Line; Nielsen, Jens H; Stapelfeldt, Henrik

    2010-01-01

    We present combined experimental and theoretical results on strong-field ionization of oriented carbonyl-sulphide molecules by circularly-polarized laser pulses. The obtained molecular frame photoelectron angular distributions show pronounced asymmetries perpendicular to the direction of the molecular electric dipole moment. These findings are explained by a tunneling model invoking the laser-induced Stark shifts associated with the dipoles and polarizabilities of the molecule and its unrelaxed cation.

  10. Gas Ionization During Carbothermal Reduction in Microwave Field and Its Effect

    Institute of Scientific and Technical Information of China (English)

    CHEN Jin; SHI Xue-hong; ZHANG Meng; ZHAO Jing

    2009-01-01

    The reduction kinetic condition of the direct solid-phase reduction of metal oxide powder containing coal by microwave heating is better than that by the conventional heating process. The research shows that the gas ionization during carbothermal reduction accelerates the carbon gasification reaction and interface chemical reaction, and it also improves the kinetic conditions of carbothermal reduction. Thus, the formation mechanism and process of gas ionization as well as its effect during the carbothermal reduction of metal oxides containing coal by microwave heating are studied.

  11. Investigations on femtosecond-pulse-driven soft X-ray lasers using a gas puff target irradiated with a Ti:sapphire laser

    Energy Technology Data Exchange (ETDEWEB)

    Fiedorowicz, H.; Bartnik, A.; Szczurek, M. [Military Univ. of Technology, Warsaw (Poland). Inst. of Optoelectronics; Mocek, T.; Shin, H.J.; Cha, Y.H.; Lee, D.G.; Hong, K.H.; Nam, C.H. [Military Univ. of Technology, Warsaw (Poland). Inst. of Optoelectronics; Korea Advanced Inst. of Science and Technology, Taejon (Korea). Dept. of Physics

    2001-07-01

    Experimental investigations on soft X-ray lasers based on optical field ionization of gases with an ultrashort-pulse terawatt laser system are presented. The X-ray laser active medium was created using an elongated gas puff target formed by pulsed injection of a small amount of gas from a high-pressure electromagnetic valve through a nozzle in the form of a slit. The target was irradiated with a laser pulses from a 20-fs. 50-mJ Ti:Sapphire (Ti:S) laser system. Both recombination and collisional soft X-ray laser scheme have been studied. Soft X-ray spectra from nitrogen, oxygen, and xenon targets are presented and discussed. (orig.)

  12. On-line experimental results of an argon gas cell-based laser ion source (KEK Isotope Separation System)

    Science.gov (United States)

    Hirayama, Y.; Watanabe, Y. X.; Imai, N.; Ishiyama, H.; Jeong, S. C.; Jung, H. S.; Miyatake, H.; Oyaizu, M.; Kimura, S.; Mukai, M.; Kim, Y. H.; Sonoda, T.; Wada, M.; Huyse, M.; Kudryavtsev, Yu.; Van Duppen, P.

    2016-06-01

    KEK Isotope Separation System (KISS) has been developed at RIKEN to produce neutron rich isotopes with N = 126 to study the β -decay properties for application to astrophysics. The KISS is an element-selective mass-separation system which consists of an argon gas cell-based on laser ion source for atomic number selection and an ISOL mass-separation system. The argon gas cell of KISS is a key component to stop and collect the unstable nuclei produced in a multi-nucleon transfer reaction, where the isotopes of interest will be selectively ionized using laser resonance ionization. We have performed off- and on-line experiments to study the basic properties of the gas cell as well as of the KISS. We successfully extracted the laser-ionized stable 56Fe (direct implantation of a 56Fe beam into the gas cell) atoms and 198Pt (emitted from the 198Pt target by elastic scattering with a 136Xe beam) atoms from the KISS during the commissioning on-line experiments. We furthermore extracted laser-ionized unstable 199Pt atoms and confirmed that the measured half-life was in good agreement with the reported value.

  13. The highly ionized, high-velocity gas in NGC 6231

    Science.gov (United States)

    Massa, Derck

    2017-02-01

    It is well known that clusters of massive stars are influenced by the presence of strong winds, that they are sources of diffuse X-rays from shocked gas, and that this gas can be vented into the surrounding region or the halo through the champagne effect. However, the details of how these different environments interact and evolve are far from complete. This paper attributes the broad C IVλλ1500 absorption features (extending to -1900 km s-1) that are seen in the spectra of main sequence B stars in NGC 6231 to gas in the cluster environment and not the B stars themselves. It is shown that the presence of a WC star, WR 79, in the cluster makes this gas detectable because its wind enriches the cluster gas with carbon. Given the available data, it is not clear whether the absorbing gas is simply the far wind of WR 79 or a collective cluster wind enriched by carbon from the wind of WR 79. If it is simply due to the wind, then this wind must flow, unimpeded for more than 2 pc, suggesting that the inner region of the cluster is nearly devoid of obstructing material. If it is actually a collective wind from the cluster, then we could be witnessing an important stage of galactic feedback. In either case, the observations provide a unique and significant piece to the puzzle of how massive, open clusters evolve.

  14. The highly ionized, high velocity gas in NGC 6231

    CERN Document Server

    Massa, Derck

    2016-01-01

    It is well known that clusters of massive stars are influenced by the presence of strong winds, that they are sources of diffuse X-rays from shocked gas, and that this gas can be vented into the surrounding region or the halo through the champagne effect. However, the details of how these different environments interact and evolve are far from complete. This paper attributes the broad C IV 1500 absorption features (extending to -1900 \\kms) that are seen in the spectra of main sequence B stars in NGC 6231 to gas in the cluster environment and not the B stars themselves. It is shown that the presence of a WC star, WR 79, in the cluster makes this gas detectable because its wind enriches the cluster gas with carbon. Given the available data, it is not clear whether the absorbing gas is simply the far wind of WR 79 or a collective cluster wind enriched by carbon from the wind of WR 79. If it is simply due to the wind, then this wind must flow, unimpeded for more than 2 pc, suggesting that the inner region of the ...

  15. Ionization and Coulomb explosion of Xenon clusters by intense, few-cycle laser pulses

    CERN Document Server

    Mathur, D

    2010-01-01

    Intense, ultrashort pulses of 800 nm laser light (12 fs, $\\sim$4 optical cycles) of peak intensity 5$\\times$10$^{14}$ W cm$^{-2}$ have been used to irradiate gas-phase Xe$_n$ clusters ($n$=500-25,000) so as to induce multiple ionization and subsequent Coulomb explosion. Energy distributions of exploding ions are measured in the few-cycle domain that does not allow sufficient time for the cluster to undergo Coulomb-driven expansion. This results in overall dynamics that appear to be significantly different to those in the many-cycle regime. One manifestation is that the maximum ion energies are measured to be much lower than those obtained when longer pulses of the same intensity are used. Ion yields are cluster-size independent but polarization dependent in that they are significantly larger when the polarization is perpendicular to the detection axis than along it. This unexpected behavior is qualitatively rationalized in terms of a spatially anisotropic shielding effect induced by the electronic charge clou...

  16. Laser Induced Fluorescence Spectroscopy of Neutral and Ionized Polycyclic Aromatic Hydrocarbons in the Cosmic Simulation Chamber

    Science.gov (United States)

    Bejaoui, Salma; Salama, Farid; Contreras, Cesar; Sciamma O'Brien, Ella; Foing, Bernard; Pascale, Ehrenfreund

    2015-01-01

    Polycyclic aromatic hydrocarbon (PAH) molecules are considered the best carriers to account for the ubiquitous infrared emission bands. PAHs have also been proposed as candidates to explain the diffuse interstellar bands (DIBs), a series of absorption features seen on the interstellar extinction curve and are plausible carriers for the extended red emission (ERE), a photoluminescent process associated with a wide variety of interstellar environments. Extensive efforts have been devoted over the past two decades to characterize the physical and chemical properties of PAH molecules and ions in space. Absorption spectra of PAH molecules and ions trapped in solid matrices have been compared to the DIBs. Absorption spectra of several cold, isolated gas-phase PAHs have also been measured under experimental conditions that mimic the interstellar conditions. The purpose of this study is to provide a new dimension to the existing spectroscopic database of neutral and single ionized PAHs that is largely based on absorption spectra by adding emission spectroscopy data. The measurements are based on the laser induced fluorescence (LIF) technique and are performed with the Pulsed Discharge Nozzle (PDN) of the COSmIC laboratory facility at NASA Ames laboratory. The PDN generates a plasma in a free supersonic jet expansion to simulate the physical and the chemical conditions in interstellar environments. We focus, here, on the fluorescence spectra of large neutral PAHs and their cations where there is a lack of fluorescence spectroscopy data. The astronomical implications of the data (e.g., ERE) are examined.

  17. Gas Immersion Laser Doping for superconducting nanodevices

    Energy Technology Data Exchange (ETDEWEB)

    Chiodi, F. [Institut d’Electronique Fondamentale, CNRS-Université Paris-Sud, F-91405 Orsay (France); Grockowiak, A. [Institut Néel, CNRS, BP 166, F-38042 Grenoble (France); CEA, INAC, UMR-E9001/UJF, LATEQS, 17 Rue des Martyrs, F-38054 Grenoble (France); Duvauchelle, J.E. [CEA, INAC, UMR-E9001/UJF, LATEQS, 17 Rue des Martyrs, F-38054 Grenoble (France); Fossard, F. [Institut d’Electronique Fondamentale, CNRS-Université Paris-Sud, F-91405 Orsay (France); Lefloch, F. [CEA, INAC, UMR-E9001/UJF, LATEQS, 17 Rue des Martyrs, F-38054 Grenoble (France); Klein, T. [Institut Néel, CNRS, BP 166, F-38042 Grenoble (France); Marcenat, C. [CEA, INAC, UMR-E9001/UJF, LATEQS, 17 Rue des Martyrs, F-38054 Grenoble (France); Institut Néel, CNRS, BP 166, F-38042 Grenoble (France); Débarre, D. [Institut d’Electronique Fondamentale, CNRS-Université Paris-Sud, F-91405 Orsay (France)

    2014-05-01

    We have conceived and fabricated Superconductor/Normal metal/Superconductor Josephson junctions made entirely of boron doped Silicon. We have used Gas Immersion Laser Doping to fabricate SN bilayers with good ohmic interfaces and well controlled concentration and doping depth. Standard fabrication processes, optimised for silicon, were employed to nanostructure the bilayers without affecting their transport properties. The junctions thus fabricated are proximity superconducting and show well understood I–V characteristics. This research opens the road to all-silicon, non-dissipative, Josephson Field Effect Transistors.

  18. Threshold ionization spectroscopic investigation of supersonic jet-cooled, laser-desorbed Tryptophan

    Science.gov (United States)

    Taherkhani, Mehran; Armentano, Antonio; Černý, Jiří; Müller-Dethlefs, Klaus

    2016-07-01

    Tryptophan (Trp) was studied by two-colour Photoionization Efficiency (PIE) and Mass Analysed Threshold Ionization (MATI) spectroscopy using a laser desorption apparatus. Conformer A of Trp was excited into the S1 state (34,878 cm-1) and the second laser was scanned around the D0 cation ground and the D1 excited state. No ionization signal into the D0 state could be found, but a clear threshold was observed for the D1 state with an ionization energy of 66,704 ± 3 cm-1 (8.27 eV). This observation is explained in terms of the electronic configurations of the S1 and cationic states.

  19. Laser ionization in {beta} decay studies of Zn and Mn nuclei

    Energy Technology Data Exchange (ETDEWEB)

    Oinonen, M.; Jading, Y.; Koester, U.; Lettry, J.; Ravn, H.; Aystoe, J. [CERN, EP Division/ISOLDE (Switzerland); Dendooven, P.; Huikari, J.; Jokinen, A.; Lipas, P.O.; Nieminen, A.; Peraejaervi, K.; Siiskonen, T. [University of Jyvaeskylae, Department of Physics (Finland); Baumann, P.; Huck, A.; Knipper, A.; Ramdhane, M.; Walter, G. [Institut de Recherches Subatomiques (France); Didierjean, F. [Eurisys Measures (France); Fedoseyev, V.N. [Russian Academy of Sciences, Institute of Spectroscopy (Russian Federation)] (and others)

    2000-08-15

    Resonance ionization laser ion source (RILIS) technique has been used in the {beta}-decay studies of {sup 59}Mn and {sup 58}Zn. The importance of the RILIS for production of these elements is discussed. The properties of the low-lying levels of the studied nuclei are discussed.

  20. Tailored nanopost arrays (NAPA) for laser desorption ionization in mass spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Vertes, Akos; Walker, Bennett N.; Stolee, Jessica A.; Retterer, Scott T.

    2016-11-08

    The production and use of semiconducting nanopost arrays made by nanofabrication is described herein. These nanopost arrays (NAPA) provide improved laser ionization yields and controllable fragmentation with switching or modulation capabilities for mass spectrometric detection and identification of samples deposited on them.

  1. The Origin and the Future of Macromolecule Ionization by Laser Irradiation

    Institute of Scientific and Technical Information of China (English)

    KoichiTanaka

    2004-01-01

    Starting in 1984,a Shimadzu Corporation Central Research Laboratory development team set about the challenge of developinng an instrument for analyzing macromolecules such as proteins. At the time, the conventional consensus among chemists was that, “laser ionization of macromolecules exceeding a molecular weight of 10,000 is imposible”. However, not being a chemist, I was unaware of this widelyheld belief.

  2. Ionization of oriented carbonyl sulfide molecules by intense circularly polarized laser pulses

    DEFF Research Database (Denmark)

    Dimitrovski, Darko; Abu-Samha, Mahmoud; Madsen, Lars Bojer;

    2011-01-01

    of the molecular electric dipole moment. These findings are explained by a tunneling model invoking the laser-induced Stark shifts associated with the dipoles and polarizabilities of the molecule and its unrelaxed cation. The focus of the present article is to understand the strong-field ionization of one...

  3. Tailored nanopost arrays (NAPA) for laser desorption ionization in mass spectrometry

    Science.gov (United States)

    Vertes, Akos; Walker, Bennett N.; Stolee, Jessica A.; Retterer, Scott T.

    2016-11-08

    The production and use of semiconducting nanopost arrays made by nanofabrication is described herein. These nanopost arrays (NAPA) provide improved laser ionization yields and controllable fragmentation with switching or modulation capabilities for mass spectrometric detection and identification of samples deposited on them.

  4. Identification of Bacteria Using Matrix-Assisted Laser Desorption Ionization Time-of-Flight Mass Spectrometry

    Science.gov (United States)

    Kedney, Mollie G.; Strunk, Kevin B.; Giaquinto, Lisa M.; Wagner, Jennifer A.; Pollack, Sidney; Patton, Walter A.

    2007-01-01

    Matrix-assisted laser desorption ionization time-of-flight mass spectrometry (MALDI-TOF MS or simply MALDI) has become ubiquitous in the identification and analysis of biomacromolecules. As a technique that allows for the molecular weight determination of otherwise nonvolatile molecules, MALDI has had a profound impact in the molecular…

  5. Target Plate Material Influence on Fullerene-C60 Laser Desorption/Ionization Efficiency.

    Science.gov (United States)

    Zeegers, Guido P; Günthardt, Barbara F; Zenobi, Renato

    2016-04-01

    Systematic laser desorption/ionization (LDI) experiments of fullerene-C60 on a wide range of target plate materials were conducted to gain insight into the initial ion formation in matrix-assisted laser desorption/ionization (MALDI) mass spectrometry. The positive and negative ion signal intensities of precursor, fragment, and cluster ions were monitored, varying both the laser fluence (0-3.53 Jcm(-2)) and the ion extraction delay time (0-950 ns). The resulting species-specific ion signal intensities are an indication for the ionization mechanisms that contribute to LDI and the time frames in which they operate, providing insight in the (MA)LDI primary ionization. An increasing electrical resistivity of the target plate material increases the fullerene-C60 precursor and fragment anion signal intensity. Inconel 625 and Ti90/Al6/V4, both highly electrically resistive, provide the highest anion signal intensities, exceeding the cation signal intensity by a factor ~1.4 for the latter. We present a mechanism based on transient electrical field strength reduction to explain this trend. Fullerene-C60 cluster anion formation is negligible, which could be due to the high extraction potential. Cluster cations, however, are readily formed, although for high laser fluences, the preferred channel is formation of precursor and fragment cations. Ion signal intensity depends greatly on the choice of substrate material, and careful substrate selection could, therefore, allow for more sensitive (MA)LDI measurements. Graphical Abstract ᅟ.

  6. Target Plate Material Influence on Fullerene-C60 Laser Desorption/Ionization Efficiency

    Science.gov (United States)

    Zeegers, Guido P.; Günthardt, Barbara F.; Zenobi, Renato

    2016-04-01

    Systematic laser desorption/ionization (LDI) experiments of fullerene-C60 on a wide range of target plate materials were conducted to gain insight into the initial ion formation in matrix-assisted laser desorption/ionization (MALDI) mass spectrometry. The positive and negative ion signal intensities of precursor, fragment, and cluster ions were monitored, varying both the laser fluence (0-3.53 Jcm-2) and the ion extraction delay time (0-950 ns). The resulting species-specific ion signal intensities are an indication for the ionization mechanisms that contribute to LDI and the time frames in which they operate, providing insight in the (MA)LDI primary ionization. An increasing electrical resistivity of the target plate material increases the fullerene-C60 precursor and fragment anion signal intensity. Inconel 625 and Ti90/Al6/V4, both highly electrically resistive, provide the highest anion signal intensities, exceeding the cation signal intensity by a factor ~1.4 for the latter. We present a mechanism based on transient electrical field strength reduction to explain this trend. Fullerene-C60 cluster anion formation is negligible, which could be due to the high extraction potential. Cluster cations, however, are readily formed, although for high laser fluences, the preferred channel is formation of precursor and fragment cations. Ion signal intensity depends greatly on the choice of substrate material, and careful substrate selection could, therefore, allow for more sensitive (MA)LDI measurements.

  7. Ionizations and fragmentations of benzene, methylbenzene, and chlorobenzene in strong IR and UV laser fields

    Institute of Scientific and Technical Information of China (English)

    张军峰; 吕航; 左万龙; 徐海峰; 金明星; 丁大军

    2015-01-01

    Ionizations and fragmentations of benzene, methylbenzene, and chlorobenzene are studied in linearly polarized 50-fs, 800-nm and 400-nm strong laser fields using a time-of-flight mass spectrometer. It is shown that at low laser intensity, the parent ions are dominant for any one of the molecules in an 800-nm strong laser field, while extensive fragmentation is observed in a 400-nm laser field, which can be understood by the resonant photon absorption of molecular cations. The ratio of the yield of the parent ion to the yield of the total ion for each molecule is measured as a function of laser intensity in a range from 1.01013 W/cm2 to 4.01014 W/cm2, in either the 800-nm or 400-nm laser field. The results show that the fragmentation of the aromatic molecules increases significantly as the laser intensity is increased. Possible mechanisms for fragmentation in strong laser fields are discussed. Finally, the saturation intensity of ionization of the titled molecules is also determined.

  8. Solar-pumped gas laser development

    Science.gov (United States)

    Wilson, J. W.

    1981-01-01

    The direct conversion of solar radiation into an inverted population for extraction in an optical cavity holds promise as a relatively simple system design. Broad-band photoabsorption in the visible or near-UV range is required to excite large volumes of gas and to ensure good solar absorption efficiency. The state excited must be a metastable state which is not quenched by the parent gas. The emission bandwidth must be less than approximately 10 A. The system should show chemical reversibility and an insensitivity to increasing temperature. Other properties such as good quantum efficiency and kinetic efficiency are also implied. A search of electronic-vibrational transitions in diatomic molecules satisfying these conditions is now in progress. A photodissociation-pumped atomic iodine laser is now being tested under solar pumping conditions. Photodissociation studies for thallium spin-flip metastable formation will begin in the near future.

  9. Manganese oxide nanoparticle-assisted laser desorption/ionization mass spectrometry for medical applications

    Directory of Open Access Journals (Sweden)

    Shu Taira, Kenji Kitajima, Hikaru Katayanagi, Eiichiro Ichiishi and Yuko Ichiyanagi

    2009-01-01

    Full Text Available We prepared and characterized manganese oxide magnetic nanoparticles (d =5.6 nm and developed nanoparticle-assited laser desorption/ionization (nano-PALDI mass spectrometry. The nanoparticles had MnO2 and Mn2O3 cores conjugated with hydroxyl and amino groups, and showed paramagnetism at room temperature. The nanoparticles worked as an ionization assisting reagent in mass spectroscopy. The mass spectra showed no background in the low m/z. The nanoparticles could ionize samples of peptide, drug and proteins (approx. 5000 Da without using matrix, i.e., 2,5-dihydroxybenzoic acid (DHB, 4-hydroxy-α-cinnamic acid (CHCA and liquid matrix, as conventional ionization assisting reagents. Post source decay spectra by nano-PALDI mass spectrometry will yield information of the chemical structure of analytes.

  10. Spatially resolved integral field spectroscopy of the ionized gas in IZw18

    CERN Document Server

    Kehrig, C; Perez-Montero, E; Iglesias-Paramo, J; Hernandez-Fernandez, J D; Puertas, S Duarte; Brinchmann, J; Durret, F; Kunth, D

    2016-01-01

    We present a detailed 2D study of the ionized ISM of IZw18 using new PMAS-IFU optical observations. IZw18 is a high-ionization galaxy which is among the most metal-poor starbursts in the local Universe. This makes IZw18 a local benchmark for understanding the properties most closely resembling those prevailing at distant starbursts. Our IFU-aperture (~ 1.4 kpc x 1.4 kpc) samples the entire IZw18 main body and an extended region of its ionized gas. Maps of relevant emission lines and emission line ratios show that higher-excitation gas is preferentially located close to the NW knot and thereabouts. We detect a Wolf-Rayet feature near the NW knot. We derive spatially resolved and integrated physical-chemical properties for the ionized gas in IZw18. We find no dependence between the metallicity-indicator R23 and the ionization parameter (as traced by [OIII]/[OII]) across IZw18. Over ~ 0.30 kpc^2, using the [OIII]4363 line, we compute Te[OIII] values (~ 15000 - 25000 K), and oxygen abundances are derived from the...

  11. Stabilization of gas-filled surge arrester’s characteristics by use of ionizing radiation

    Directory of Open Access Journals (Sweden)

    Brajović Dragan V.

    2012-01-01

    Full Text Available This paper investigates the stabilization of electrical discharges in gases by means of external ionizing radiation. Discharges in a gas-filled surge arrester model were studied in both passive and active regimes of the device. An originally developed model of the gas-filled surge arrester was used. Gas pressure and the interelectrode gap were the variable parameters in our measurements. Applied radiation types included α-particles, γ-rays, X-rays, and neutrons. Measurements were performed under highly controlled laboratory conditions. The combined measurement uncertainty of the applied procedure was estimated as being under the 5% level. The results obtained are followed by a theoretical explanation. The crucial result is the conclusion that ionizing radiation does not necessarily degrade the gas-filled surge arrester’s functionality but that it, rather, improves it under certain conditions.

  12. Baryonic Distributions in Galaxy Dark Matter Haloes I: New Observations of Neutral and Ionized Gas Kinematics

    CERN Document Server

    Richards, Emily E; Barnes, K L; Staudaher, S; Dale, D A; Braun, T T; Wavle, D C; Dalcanton, J J; Bullock, J S; Chandar, R

    2016-01-01

    We present a combination of new and archival neutral hydrogen (HI) observations and new ionized gas spectroscopic observations for sixteen galaxies in the statistically representative EDGES kinematic sample. HI rotation curves are derived from new and archival radio synthesis observations from the Very Large Array (VLA) as well as processed data products from the Westerbork Radio Synthesis Telescope (WSRT). The HI rotation curves are supplemented with optical spectroscopic integral field unit (IFU) observations using SparsePak on the WIYN 3.5 m telescope to constrain the central ionized gas kinematics in twelve galaxies. The full rotation curves of each galaxy are decomposed into baryonic and dark matter halo components using 3.6$\\mu$m images from the Spitzer Space Telescope for the stellar content, the neutral hydrogen data for the atomic gas component, and, when available, CO data from the literature for the molecular gas component. Differences in the inferred distribution of mass are illustrated under fixe...

  13. Field emission mechanism from nanotubes through gas ionization induced nanoscale surface charging

    CERN Document Server

    Zhan, Changhua

    2012-01-01

    Experimental evidences reported in this letter show that the gas ionization induced positive charge accumulation can lead to the electron field emission from carbon nanotubes (CNTs) in an electrode system with proper range of gap spacing, where the CNT film with ethocel was covered with ZnO nanorods. The hypothesis for illustration is suggested that: 1) the cosmic ray ionization frequency increases 108~1010 times due to the metastable population resulted from the interaction between the gases and the CNTs; 2) the flux of positive charges is enhanced in the converged field due to the ZnO nanostructures. The resulted positive charge local density is high enough to trigger the field emission of the CNTs. The methodology may be useful in particle detectors and ionization gas sensors.

  14. Thermoregulated Nitric Cryosystem for Cooling Gas-Filled Detectors of Ionizing Radiation

    Directory of Open Access Journals (Sweden)

    Zharkov I.P.

    2015-09-01

    Full Text Available Cryosystem for cooling and filling of gas-filled detectors of ionizing radiation with compressed inert gas on the basis of wide-nitrogen cryostat, which provides detetector temperature control in a range of 173 — 293 K and its stabilization with accuracy of ± 1°. The work was carried out within the Ukraine — NATO Program of Collaboration, Grant SfP #984655.

  15. Excitation of the diffuse ionized gas in galaxies

    Directory of Open Access Journals (Sweden)

    Crystal L. Martin

    2000-01-01

    Full Text Available Se revisan las propiedades del gas ionizado difuso (DIG en galaxias cercanas con formaci on estelar, enfatizando la evidencia para un mecanismo de excitaci on adicional a la fotoionizaci on estelar. Discuto la pregunta frecuentemente hecha sobre si el DIG en galaxias externas es similar al medio ionizado tibio (WIM descrito en esta reuni on por Reynolds y Ha ner.

  16. Kinematics of the ionized gas in the Local Group irregular galaxy IC 1613

    CERN Document Server

    Valdez-Gutierrez, M; Georgiev, L; Borissova, J; Kurtev, R

    2000-01-01

    We present Halpha and [SII] observations for the Local Group irregular galaxy IC 1613 using the PUMA scanning Fabry-Perot interferometer. Our goal is to analyze the kinematics of the ionized gas in the complex sample of superbubbles located in the whole extension of our field (10 arcmin), which includes most of the optical emission of this galaxy, and to study the inter-relationship between young stellar associations and nebulae based on a previous study that we have made on the stellar associations of the central region of this galaxy. The ionized gas in this galaxy is distributed in classical HII regions and in a series of superbubbles (also called giant shells) covering a large fraction of the optical extent of the galaxy. We present a catalog of kinematical properties of both the HII regions of this galaxy and the superbubbles. We have also compared the kinematics of the ionized gas in HII regions to search for possible dynamic differences between neutral and ionized gas.

  17. Molecular ionization of cyclohexanone in femtosecond laser fields: An application of ADK theory

    Science.gov (United States)

    Wang, Q. Q.; Mineo, H.; Wu, D.; Jin, M. X.; Chin, C. H.; Teranishi, Y.; Chao, S. D.; Ding, D.; Lin, S. H.

    2009-08-01

    The mechanisms of ionization and dissociation of cyclohexanone (C6H10O) in a 90 fs, 788 nm linearly polarized laser field ranging from 1013 to 1014 W/cm2 by a time-of-flight mass spectrometer (TOF-MS) have been investigated. The ion yields as a function of laser intensity have been measured experimentally. By comparison with the Ammosov-Delone-Krainov (ADK) theory based on a hydrogen-like model, the ionization mechanism of cyclohexanone in this intense femtosecond laser field has been understood. Considering the importance of molecular nuclear motions, we propose that the Franck-Condon (F-C) factor can provide the excess vibrational energy in the molecular ion. This energy is required for the decomposition of the molecular ion which finally results in the observed mass spectrum.

  18. Superelastic rescattering in single ionization of helium in strong laser fields

    Science.gov (United States)

    Li, Zhi-Chao; Jaron-Becker, Agnieszka; He, Feng

    2016-10-01

    Rescattering is a central process in ultrafast physics, in which an electron, freed from an atom and accelerated by a laser field, loses its energy by producing high-order harmonics or multiple ionization. Here, taking helium as a prototypical atom, we demonstrate numerically superelastic rescattering in single ionization of an atom. In this scenario, the absorption of a high-energy extreme ultraviolet photon leads to emission of one electron and excitation of the second one into its first excited state, forming He+*. A time-delayed midinfrared laser pulse accelerates the freed electron, drives it back to the He+*, and induces the transition of the bound electron to the ground state of the ion. Identification of the superelastic rescattering process in the photoelectron momentum spectra provides a means to determine the photoelectron momentum at the time of rescattering without using any information of the time-delayed probe laser pulse.

  19. Multiple ionization in strong fields

    OpenAIRE

    Rudenko, A; Moshammer, R; Schröter, C; Zrost, K.; Feuerstein, B.; de Jesus, V.; Ullrich, J.

    2005-01-01

    Single and multiple ionization of rare gas atoms by 25 and 7 fs intense laser pulses has been studied using a "Reaction Microscope”. For single ionization of He, Ne and Ar in the tunnelling regime, surprising and distinct patterns have been observed in high-resolution low-energy electron spectra. Mechanisms of double and multiple ionization were elucidated and partly identified via recoil-ion momentum distributions and correlated electron spectra. For Ne the highly correlated “instantaneous” ...

  20. Improving the Selectivity of the ISOLDE Resonance Ionization Laser Ion Source and In-Source Laser Spectroscopy of Polonium

    CERN Document Server

    Fink, Daniel Andreas; Jochim, Selim

    Exotic atomic nuclei far away from stability are fascinating objects to be studied in many scientic elds such as atomic-, nuclear-, and astrophysics. Since these are often short-lived isotopes, it is necessary to couple their production with immediate extraction and delivery to an experiment. This is the purpose of the on-line isotope separator facility, ISOLDE, at CERN. An essential aspect of this laboratory is the Resonance Ionization Laser Ion Source (RILIS) because it provides a fast and highly selective means of ionizing the reaction products. This technique is also a sensitive laser-spectroscopy tool for the development and improvement of electron excitation schemes for the resonant laser photoionization and the study of the nuclear structure or fundamental atomic physics. Each of these aspects of the RILIS applications are subjects of this thesis work: a new device for the suppression of unwanted surface ionized contaminants in RILIS ion beams, known as the Laser Ion Source and Trap (LIST), was impleme...

  1. Calculation of laser induced impulse based on the laser supported detonation wave model with dissociation, ionization and radiation

    Energy Technology Data Exchange (ETDEWEB)

    Gan, Li, E-mail: ligan0001@gmail.com; Mousen, Cheng; Xiaokang, Li [College of Aerospace Science and Engineering, National University of Defense Technology, Changsha (China)

    2014-03-15

    In the laser intensity range that the laser supported detonation (LSD) wave can be maintained, dissociation, ionization and radiation take a substantial part of the incidence laser energy. There is little treatment on the phenomenon in the existing models, which brings obvious discrepancies between their predictions and the experiment results. Taking into account the impact of dissociation, ionization and radiation in the conservations of mass, momentum and energy, a modified LSD wave model is developed which fits the experimental data more effectively rather than the existing models. Taking into consideration the pressure decay of the normal and the radial rarefaction, the laser induced impulse that is delivered to the target surface is calculated in the air; and the dependencies of impulse performance on laser intensity, pulse width, ambient pressure and spot size are indicated. The results confirm that the dissociation is the pivotal factor of the appearance of the momentum coupling coefficient extremum. This study focuses on a more thorough understanding of LSD and the interaction between laser and matter.

  2. SFC-APLI-(TOF)MS: Hyphenation of Supercritical Fluid Chromatography to Atmospheric Pressure Laser Ionization Mass Spectrometry.

    Science.gov (United States)

    Klink, Dennis; Schmitz, Oliver Johannes

    2016-01-05

    Atmospheric-pressure laser ionization mass spectrometry (APLI-MS) is a powerful method for the analysis of polycyclic aromatic hydrocarbon (PAH) molecules, which are ionized in a selective and highly sensitive way via resonance-enhanced multiphoton ionization. APLI was presented in 2005 and has been hyphenated successfully to chromatographic separation techniques like high performance liquid chromatography (HPLC) and gas chromatography (GC). In order to expand the portfolio of chromatographic couplings to APLI, a new hyphenation setup of APLI and supercritical-fluid chromatography (SFC) was constructed and aim of this work. Here, we demonstrate the first hyphenation of SFC and APLI in a simple designed way with respect to different optimization steps to ensure a sensitive analysis. The new setup permits qualitative and quantitative determination of native and also more polar PAH molecules. As a result of the altered ambient characteristics within the source enclosure, the quantification of 1-hydroxypyrene (1-HP) in human urine is possible without prior derivatization. The limit of detection for 1-HP by SFC-APLI-TOF(MS) was found to be 0.5 μg L(-1), which is lower than the 1-HP concentrations found in exposed persons.

  3. Hot-cavity studies for the Resonance Ionization Laser Ion Source

    Energy Technology Data Exchange (ETDEWEB)

    Henares, J.L., E-mail: henares@ganil.fr [GANIL, BP 55027, 14076 Caen Cedex 5 (France); Lecesne, N.; Hijazi, L.; Bastin, B. [GANIL, BP 55027, 14076 Caen Cedex 5 (France); Kron, T. [Johannes Gutenberg-Universität Mainz, Staudinger Weg 7, 55099 Mainz (Germany); Lassen, J. [TRIUMF, 4004 Wesbrook Mall, Vancouver, BC, Canada V6T 2A3 (Canada); Le Blanc, F. [IPN Orsay, BP 1-91406 Orsay (France); Leroy, R.; Osmond, B. [GANIL, BP 55027, 14076 Caen Cedex 5 (France); Raeder, S. [Johannes Gutenberg-Universität Mainz, Staudinger Weg 7, 55099 Mainz (Germany); KU Leuven, Oude Markt 13, 3000 Leuven (Belgium); Schneider, F.; Wendt, K. [Johannes Gutenberg-Universität Mainz, Staudinger Weg 7, 55099 Mainz (Germany)

    2016-09-11

    The Resonance Ionization Laser Ion Source (RILIS) has emerged as an important technique in many Radioactive Ion Beam (RIB) facilities for its reliability, and ability to ionize target elements efficiently and element selectively. GISELE is an off-line RILIS test bench to study the implementation of an on-line laser ion source at the GANIL separator facility. The aim of this project is to determine the best technical solution which combines high selectivity and ionization efficiency with small ion beam emittance and stable long term operation. The ion source geometry was tested in several configurations in order to find a solution with optimal ionization efficiency and beam emittance. Furthermore, a low work function material was tested to reduce the contaminants and molecular sidebands generated inside the ion source. First results with ZrC ionizer tubes will be presented. Furthermore, a method to measure the energy distribution of the ion beam as a function of the time of flight will be discussed.

  4. Hole dynamics and spin currents after ionization in strong circularly polarized laser fields

    CERN Document Server

    Barth, Ingo

    2014-01-01

    We apply the time-dependent analytical R-matrix theory to develop a movie of hole motion in a Kr atom upon ionization by strong circularly polarized field. We find rich hole dynamics, ranging from rotation to swinging motion. The motion of the hole depends on the final energy and the spin of the photoelectron and can be controlled by the laser frequency and intensity. Crucially, hole rotation is a purely non-adiabatic effect, completely missing in the framework of quasistatic (adiabatic) tunneling theories. We explore the possibility to use hole rotation as a clock for measuring ionization time. Analysing the relationship between the relative phases in different ionization channels we show that in the case of short-range electron-core interaction the hole is always initially aligned along the instantaneous direction of the laser field, signifying zero delays in ionization. Finally, we show that strong-field ionization in circular fields creates spin currents (i.e. different flow of spin-up and spin-down densi...

  5. Pyroelectricity Assisted Infrared-Laser Desorption Ionization (PAI-LDI) for Atmospheric Pressure Mass Spectrometry

    Science.gov (United States)

    Li, Yanyan; Ma, Xiaoxiao; Wei, Zhenwei; Gong, Xiaoyun; Yang, Chengdui; Zhang, Sichun; Zhang, Xinrong

    2015-08-01

    A new atmospheric pressure ionization method termed pyroelectricity-assisted infrared laser desorption ionization (PAI-LDI) was developed in this study. The pyroelectric material served as both sample target plate and enhancing ionization substrate, and an IR laser with wavelength of 1064 nm was employed to realize direct desorption and ionization of the analytes. The mass spectra of various compounds obtained on pyroelectric material were compared with those of other substrates. For the five standard substances tested in this work, LiNbO3 substrate produced the highest ion yield and the signal intensity was about 10 times higher than that when copper was used as substrate. For 1-adamantylamine, as low as 20 pg (132.2 fmol) was successfully detected. The active ingredient in (Compound Paracetamol and 1-Adamantylamine Hydrochloride Capsules), 1-adamantylamine, can be sensitively detected at an amount as low as 150 pg, when the medicine stock solution was diluted with urine. Monosaccharide and oligosaccharides in Allium Cepa L. juice was also successfully identified with PAI-LDI. The method did not require matrix-assisted external high voltage or other extra facility-assisted set-ups for desorption/ionization. This study suggested exciting application prospect of pyroelectric materials in matrix- and electricity-free atmospheric pressure mass spectrometry research.

  6. Pathways of the single and double ionization of H$_2$ in intense laser field

    CERN Document Server

    Sami, Firoozeh; Shokri, Babak

    2010-01-01

    The time dependent Schr\\"{o}dinger and Newton equations are solved simultaneously for the electrons and the nuclei of H$_2$ respectively. The electrons and nuclei dynamics is separated on the base of the adiabatic approximation. The soft-core potential is used to model the electrostatic interaction between the electrons and the nuclei. The high intensity ultrashort laser pulse is used in three different wavelengths, 390 nm, 532 nm and 780 nm and a sinus second order envelope function is used for all of laser fields. The distinguishable pathways and regions of the single and sequential double ionization are determined and discussed. It is shown that there are two distinguishable pathways for the single ionization and four distinct pathways for the sequential double ionization. It is also shown that there are two different regions which are related to the single ionization. Three different regions can also be recognized which are related to the double ionization. The bound-hardening is observed for the initial ...

  7. Ionization and bound-state relativistic quantum dynamics in laser-driven multiply charged ions

    Energy Technology Data Exchange (ETDEWEB)

    Hetzheim, Henrik

    2009-01-14

    The interaction of ultra-strong laser fields with multiply charged hydrogen-like ions can be distinguished in an ionization and a bound dynamics regime. Both are investigated by means of numerically solving the Dirac equation in two dimensions and by a classical relativistic Monte-Carlo simulation. For a better understanding of highly nonlinear physical processes the development of a well characterized ultra-intense relativistic laser field strength has been driven forward, capable of studying e.g. the magnetic field effects of the laser resulting in an additional electron motion in the laser propagation direction. A novel method to sensitively measure these ultra-strong laser intensities is developed and employed from the optical via the UV towards the XUV frequency regime. In the bound dynamics field, the determination of multiphoton transition matrixelements has been investigated between different bound states via Rabi oscillations. (orig.)

  8. Temporal characterization of ultrashort ionization-injected electron bunches generated from a laser wakefield accelerator

    CERN Document Server

    Zhang, C J; Wan, Y; Guo, B; Pai, C -H; Wu, Y P; Li, F; Chu, H -H; Gu, Y Q; Mori, W B; Joshi, C; Wang, J; Lu, W

    2016-01-01

    A new concept to diagnose the temporal characteristics of ultrashort electron bunches generated from a laser wakefield accelerator is described. When the ionization-injected bunch interacts with the back of the drive laser it is deflected and stretched along the direction of the electric field of the laser. Upon exiting the plasma if the bunch goes through a narrow slit in front of the dipole magnet that disperses the electrons in the plane of the laser polarization, it can form a series of bunchlets that have different energies but separated by half a laser wavelength. By analyzing the modulated energy spectrum, the beam current profile and the longitudinal (energy versus time) phase space are recovered. This concept is demonstrated through particle-in-cell simulations and experiment.

  9. Laser Desorption Ionization Mass Spectrometry Imaging of Drosophila Brain Using Matrix Sublimation versus Modification with Nanoparticles.

    Science.gov (United States)

    Phan, Nhu T N; Mohammadi, Amir Saeid; Dowlatshahi Pour, Masoumeh; Ewing, Andrew G

    2016-02-02

    Laser desorption ionization mass spectrometry (LDI-MS) is used to image brain lipids in the fruit fly, Drosophila, a common invertebrate model organism in biological and neurological studies. Three different sample preparation methods, including sublimation with two common organic matrixes for matrix-assisted laser desorption ionization (MALDI) and surface-assisted laser desorption ionization (SALDI) using gold nanoparticles, are examined for sample profiling and imaging the fly brain. Recrystallization with trifluoroacetic acid following matrix deposition in MALDI is shown to increase the incorporation of biomolecules with one matrix, resulting in more efficient ionization, but not for the other matrix. The key finding here is that the mass fragments observed for the fly brain slices with different surface modifications are significantly different. Thus, these approaches can be combined to provide complementary analysis of chemical composition, particularly for the small metabolites, diacylglycerides, phosphatidylcholines, and triacylglycerides, in the fly brain. Furthermore, imaging appears to be beneficial using modification with gold nanoparticles in place of matrix in this application showing its potential for cellular and subcellular imaging. The imaging protocol developed here with both MALDI and SALDI provides the best and most diverse lipid chemical images of the fly brain to date with LDI.

  10. Polycyclic aromatic hydrocarbon ionization as a tracer of gas flows through protoplanetary disk gaps

    CERN Document Server

    Maaskant, K M; Waters, L B F M; Tielens, A G G M

    2014-01-01

    Planet-forming disks of gas and dust around young stars contain polycyclic aromatic hydrocarbons (PAHs). We aim to characterize how the charge state of PAHs can be used as a probe of flows of gas through protoplanetary gaps. In this context, our goal is to understand the PAH spectra of four transitional disks. In addition, we want to explain the observed correlation between PAH ionization (traced by the 6.2/11.3 feature ratio) and the disk mass (traced by the 1.3 mm luminosity). We implement a model to calculate the charge state of PAHs in the radiative transfer code MCMax. The emission spectra and ionization balance are calculated. A benchmark modeling grid is presented that shows how PAH ionization and luminosity behave as a function of star and disk properties. The PAH ionization is most sensitive to ultraviolet (UV) radiation and the electron density. In optically thick disks, where the UV field is low and the electron density is high, PAHs are predominantly neutral. Ionized PAHs trace low-density optical...

  11. Outflows of very ionized gas in the center of Seyfert galaxies: kinematics and physical conditions

    CERN Document Server

    Rodríguez-Ardila, A; Viegas, S; Grünwald, R; Rodriguez-Ardila, Alberto

    2006-01-01

    Mid-resolution spectra are used to deduce the size and kinematics of the coronal gas in a sample of Seyfert galaxies by means of observations of the [FeXI], [FeX], [FeVII], [SiVI] and [SiVII] lines. These coronal lines (CL) extend from the unresolved nucleus up to a few tens to a few hundreds of parsecs. The region of the highest ionized ions studied, [FeXI] and [FeX], is the least spatially extended, and concentrates at the center; intermediate ionization lines extend from the nucleus up to a few tens to a few hundred parsecs; lower [OIII]-like ions are known to extendin the kpc range. All together indicates a stratification in the ionized gas, usually interpreted in terms of nuclear photoionization as the driving ionization mechanism. However, CL profiles show various peculiarities: they are broader by a factor of two than lower ionization lines, the broadening being in terms of asymmetric blue wings, and their centroid position at the nucleus is blueshifted by a few hundreds of km/s. Moreover, in NGC1386 a...

  12. Derivatization of small biomolecules for optimized matrix-assisted laser desorption/ionization mass spectrometry.

    Science.gov (United States)

    Tholey, Andreas; Wittmann, Christoph; Kang, Min-Jung; Bungert, Ditte; Hollemeyer, Klaus; Heinzle, Elmar

    2002-09-01

    Matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI-TOFMS) is a powerful tool for the measurement of low molecular mass compounds of biological interest. The limitations for this method are the volatility of many analytes, possible interference with matrix signals or bad ionization or desorption behavior of the compounds. We investigated the application of well-known and straightforward one-pot derivatization procedures to circumvent these problems. The derivatizations tested allow the measurement and the labeling of alcohols, aldehydes and ketones, carboxylic acids, alpha-ketocarboxylic acids and amines.

  13. Hydrodynamics of Exploding Foil X-Ray Lasers with Time-Dependent Ionization Effect

    Science.gov (United States)

    Wang, Yu; Su, Dandan; Li, Yingjun

    2016-12-01

    A simple modified model is presented based on R. A. London's self-similarity model on time-independent ionization hydrodynamics of exploding foil X-ray lasers. In our model, the time-dependent ionization effect is under consideration and the average ion charge depends on the temperature. Then we obtain the new scaling laws for temperature, scale length and electron density, which have better agreement with experimental results. supported by National Natural Science Foundation of China (Nos. 11574390, 11374360, 41472130) and the National Basic Research Program of China (No. 2013CBA01504)

  14. Supersonic propagation of ionization waves in an under-dense, laser-produced plasma

    Energy Technology Data Exchange (ETDEWEB)

    Constantin, C; Back, C A; Fournier, K B; Gregori, G; Landen, O L; Glenzer, S H; Dewald, E L; Miller, M C

    2004-10-22

    We observe a laser-driven supersonic ionization wave heating a mm-scale plasma of sub-critical density up to 2-3 keV electron temperatures. Propagation velocities initially 10 times the sound speed were measured by means of time-resolved x-ray imaging diagnostics. The measured ionization wave trajectory is modeled analytically and by a 2D radiation-hydrodynamics code. The comparison to the modeling suggests that nonlocal heat transport effects may contribute to the attenuation of the heat wave propagation.

  15. Gas dynamic lasers. Citations from the NTIS data base

    Science.gov (United States)

    Carrigan, B.

    1980-07-01

    The citations cover research on kinetic and energy transfer processes, design, optics, nozzles, and performance of gas and chemical lasers relying on gas dynamic effects for lasing enhancement. Diffusion and flow studies specifically applicable to such lasers are also included. This updated bibliography contains 253 citations, 6 of which are new entries to the previous edition.

  16. Study of ionization losses in He-based gas mixtures

    CERN Document Server

    Borsato, E; Dal Corso, F; Morandin, M; Posocco, M; Stroili, R; Voci, C; Buccheri, A; Ferroni, F; Lacava, F; Lamanna, E; Mazzoni, M A; Morganti, S; Pastore, F C; Piredda, G; Pontecorvo, L

    1999-01-01

    Helium based gas mixtures are particularly interesting since they have a good tracking resolution because of the reduced multiple scattering. We have studied the differential energy loss dE/dx in several mixtures, He-isobutane and He-ethane. We present results from measurements performed with electrons, pions and protons in the momentum range between 1 and 5 GeV/c obtained in a prototype drift chamber with a 3 cm cell. The results show that helium performs well in measuring energy losses for charged particles.

  17. Integral-Field Stellar and Ionized Gas Kinematics of Peculiar Virgo Cluster Spiral Galaxies

    CERN Document Server

    Cortés, J R; Hardy, E

    2014-01-01

    We present the stellar and ionized gas kinematics of 13 bright peculiar Virgo cluster galaxies observed with the DensePak Integral Field Unit at the WIYN 3.5-meter telescope, to seek kinematic evidence that these galaxies have experienced gravitational interactions or gas stripping. 2-Dimensional maps of the stellar velocity $V$, and stellar velocity dispersion $\\sigma$ and the ionized gas velocity (H$\\beta$ and/or [\\ion{O}{3}]) are presented for galaxies in the sample. The stellar rotation curves and velocity dispersion profiles are determined for 13 galaxies, and the ionized gas rotation curves are determined for 6 galaxies. Misalignments between the optical and kinematical major axis are found in several galaxies. While in some cases this is due to a bar, in other cases it seems associated with a gravitational interaction or ongoing ram pressure stripping. Non-circular gas motions are found in nine galaxies, with various causes including bars, nuclear outflows, or gravitational disturbances. Several galaxi...

  18. Fast outflow of neutral and ionized gas from the radio galaxy 3C 293

    CERN Document Server

    Emonts, B H C; Oosterloo, T A; Tadhunter, C N; Van der Hulst, J M

    2005-01-01

    We detect a fast outflow of neutral and ionized gas with velocities up to about 1000 km/s from the central region of radio galaxy 3C 293. With optical spectroscopy we locate the bulk of the ionized gas outflow at the position of a bright radio hot-spot in the inner radio jet, about 1 kpc east of the nucleus. Given the presence of large amounts of cold gas and the distorted morphology of the radio jet in this region, we argue that the ISM is pushed out by a severe interaction with the radio plasma. The similarity of the outflow of HI with the ionized gas outflow that we see at the position of the radio hot-spot suggests that despite the high energies involved in the jet-ISM interaction, part of the gas stays, or becomes again, neutral. In this paper we also present the detection of HI emission in three nearby companions of 3C 293.

  19. Assisting Gas Optimization in CO2 Laser Welding

    DEFF Research Database (Denmark)

    Gong, Hui; Olsen, Flemming Ove

    1996-01-01

    High quality laser welding is achieved under the condition of optimizing all process parameters. Assisting gas plays an important role for sound welds. In the conventional welding process assisting gas is used as a shielding gas to prevent that the weld seam oxidates. In the laser welding process...... assisting gas is also needed to control the laser induced plasma.Assisting gas is one of the most important parameters in the laser welding process. It is responsible for obtaining a quality weld which is characterized by deep penetration, no interior imperfections, i.e. porosity, no crack, homogeneous seam...... are applied with three different flow rates for each of the gases. A number of systematic laboratory experiments is carried out by employing various experimental designs, 33 and 32 Factorial Design. In the experiments a CO2 laser is used to weld thin sheets of mild steel. The welding specimens are evaluated...

  20. IONIZED GAS IN THE FIRST 10 kpc OF THE INTERSTELLAR GALACTIC HALO: METAL ION FRACTIONS

    Energy Technology Data Exchange (ETDEWEB)

    Howk, J. Christopher [Department of Physics, University of Notre Dame, Notre Dame, IN 46556 (United States); Consiglio, S. Michelle, E-mail: jhowk@nd.edu, E-mail: smconsiglio@ucla.edu [Current address: Department of Physics and Astronomy, University of California, Los Angeles, Los Angeles, CA 90095 (United States)

    2012-11-10

    We present direct measures of the ionization fractions of several sulfur ions in the Galactic warm ionized medium (WIM). We obtained high-resolution ultraviolet absorption-line spectroscopy of post-asymptotic giant branch stars in the globular clusters Messier 3 [(l, b) = (42.{sup 0}2, +78.{sup 0}7), d = 10.2 kpc, and z = 10.0 kpc] and Messier 5 [(l, b) = (3.{sup 0}9, +46.{sup 0}8), d = 7.5 kpc, and z = +5.3 kpc] with the Hubble Space Telescope and Far Ultraviolet Spectroscopic Explorer to measure, or place limits on, the column densities of S I, S II, S III, S IV, S VI, and H I. These clusters also house millisecond pulsars, whose dispersion measures give an electron column density from which we infer the H II column in these directions. We find fractions of S{sup +2} in the WIM for the M 3 and M 5 sight lines x(S{sup +2}) {identical_to} N(S{sup +2})/N(S) = 0.33 {+-} 0.07 and 0.47 {+-} 0.09, respectively, with variations perhaps related to location. With negligible quantities of the higher ionization states, we conclude that S{sup +} and S{sup +2} account for all of the S in the WIM. We extend the methodology to study the ion fractions in the warm and hot ionized gas of the Milky Way, including the high ions Si{sup +3}, C{sup +3}, N{sup +4}, and O{sup +5}. The vast majority of the Galactic ionized gas is warm (T {approx} 10{sup 4} K) and photoionized (the WIM) or very hot (T > 4 Multiplication-Sign 10{sup 5} K) and collisionally ionized. The common tracer of ionized gas beyond the Milky Way, O{sup +5}, traces <1% of the total ionized gas mass of the Milky Way.

  1. Hose Instability and Wake Generation By An Intense Electron Beam in a Self-Ionized Gas

    Energy Technology Data Exchange (ETDEWEB)

    Deng, S.; Barnes, C.D.; Clayton, C.E.; O' Connell, C.; Decker, F.J.; Fonseca, R.A.; Huang, C.; Hogan, M.J.; Iverson, R.; Johnson, D.K.; Joshi, C.; Katsouleas, T.; Krejcik,; Lu, W.; Mori, W.B.; Muggli, P.; Oz, E.; Tsung, F.; Walz, D.; Zhou, M.; /Southern California U. /UCLA /SLAC

    2006-04-12

    The propagation of an intense relativistic electron beam through a gas that is self-ionized by the beam's space charge and wakefields is examined analytically and with 3D particle-in-cell simulations. Instability arises from the coupling between a beam and the offset plasma channel it creates when it is perturbed. The traditional electron hose instability in a preformed plasma is replaced with this slower growth instability depending on the radius of the ionization channel compared to the electron blowout radius. A new regime for hose stable plasma wakefield acceleration is suggested.

  2. Optically-Based Diagnostics for Gas-Phase Laser Development

    Science.gov (United States)

    2010-08-01

    Phase Laser Development Acknowledgement of Support and Disclaimer This material is based upon work supported by Air Force Office of Scientific...00-2010 4. TITLE AND SUBTITLE Optically-Based Diagnostics for Gas-Phase Laser Development 5a. CONTRACT NUMBER 5b. GRANT NUMBER 5c. PROGRAM...Sciences Inc. Role of Optical Diagnostics in High Energy Gas Laser Development  Chemically rich, energetic, reacting flow with competing phenomena

  3. Ionized gas velocity dispersion and multiple supernova explosions

    CERN Document Server

    Vasiliev, Evgenii O; Shchekinov, Yuri A

    2014-01-01

    Using 3D numerical simulations we study the evolution of the H$\\alpha$ intensity and velocity dispersion for single and multiple supenova (SN) explosions. We find that the $I_{\\rm H\\alpha}-\\sigma$ diagram obtained for simulated gas flows is similar in shape to that observed in dwarf galaxies. We conclude that colliding SN shells with significant difference in age are resposible for high velocity dispersion that reaches values high as $\\simgt 100$kms$^{-1}$. Such a high velocity dispersion could be hardly got for a single SN remnant. Peaks of velocity dispersion on the $I_{\\rm H\\alpha}-\\sigma$ diagram may correspond to several stand-alone or merged SN remnants with moderately different ages. The procedure of the spatial resolution degrading in the H$\\alpha$ intensity and velocity dispersion maps makes the simulated $I_{\\rm H\\alpha}-\\sigma$ diagrams close to those observed in dwarf galaxies not only in shape, but also quantitatively.

  4. Isobutane Made Practical as a Reagent Gas for Chemical Ionization Mass Spectrometry

    Science.gov (United States)

    Newsome, G. Asher; Steinkamp, F. Lucus; Giordano, Braden C.

    2016-11-01

    As a reagent gas for positive- and negative-mode chemical ionization mass spectrometry (CI-MS), isobutane ( i-C4H10) produces superior analyte signal abundance to methane. Isobutane has never been widely adopted for CI-MS because it fouls the ion source more rapidly and produces positive CI spectra that are more strongly dependent on reagent gas pressure compared with methane. Isobutane was diluted to various concentrations in argon for use as a reagent gas with an unmodified commercial gas chromatograph-mass spectrometer. Analyte spectra were directly compared using methane, isobutane, and isobutane/argon mixtures. A mixture of 10% i-C4H10 in argon produced twice the positive-mode analyte signal of methane, equal to pure isobutane, and reduced spectral dependence on reagent gas pressure. Electron capture negative chemical ionization using 1% i-C4H10 in argon tripled analyte signal compared with methane and was reproducible, unlike pure isobutane. The operative lifetime of the ion source using isobutane/argon mixtures was extended exponentially compared with pure isobutane, producing stable and reproducible CI signal throughout. By diluting the reagent gas in an inert buffer gas, isobutane CI-MS experiments were made as practical to use as methane CI-MS experiments but with superior analytical performance.

  5. Plume collimation for laser ablation electrospray ionization mass spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Vertes, Akos; Stolee, Jessica A.

    2016-06-07

    In various embodiments, a device may generally comprise a capillary having a first end and a second end; a laser to emit energy at a sample in the capillary to ablate the sample and generate an ablation plume in the capillary; an electrospray apparatus to generate an electrospray plume to intercept the ablation plume to produce ions; and a mass spectrometer having an ion transfer inlet to capture the ions. The ablation plume may comprise a collimated ablation plume. The device may comprise a flow cytometer. Methods of making and using the same are also described.

  6. Plume collimation for laser ablation electrospray ionization mass spectrometry

    Science.gov (United States)

    Vertes, Akos; Stolee, Jessica A.

    2016-06-07

    In various embodiments, a device may generally comprise a capillary having a first end and a second end; a laser to emit energy at a sample in the capillary to ablate the sample and generate an ablation plume in the capillary; an electrospray apparatus to generate an electrospray plume to intercept the ablation plume to produce ions; and a mass spectrometer having an ion transfer inlet to capture the ions. The ablation plume may comprise a collimated ablation plume. The device may comprise a flow cytometer. Methods of making and using the same are also described.

  7. Plume collimation for laser ablation electrospray ionization mass spectrometry

    Science.gov (United States)

    Vertes, Akos; Stolee, Jessica A.

    2014-09-09

    In various embodiments, a device may generally comprise a capillary having a first end and a second end; a laser to emit energy at a sample in the capillary to ablate the sample and generate an ablation plume in the capillary; an electrospray apparatus to generate an electrospray plume to intercept the ablation plume to produce ions; and a mass spectrometer having an ion transfer inlet to capture the ions. The ablation plume may comprise a collimated ablation plume. The device may comprise a flow cytometer. Methods of making and using the same are also described.

  8. Characterization of aromaticity in analogues of titan's atmospheric aerosols with two-step laser desorption ionization mass spectrometry

    Science.gov (United States)

    Mahjoub, Ahmed; Schwell, Martin; Carrasco, Nathalie; Benilan, Yves; Cernogora, Guy; Szopa, Cyril; Gazeau, Marie-Claire

    2016-10-01

    The role of polycyclic aromatic hydrocarbons (PAH) and Nitrogen containing PAH (PANH) as intermediates of aerosol production in the atmosphere of Titan has been a subject of controversy for a long time. An analysis of the atmospheric emission band observed by the Visible and Infrared Mapping Spectrometer (VIMS) at 3.28 μm suggests the presence of neutral polycyclic aromatic species in the upper atmosphere of Titan. These molecules are seen as the counter part of negative and positive aromatics ions suspected by the Plasma Spectrometer onboard the Cassini spacecraft, but the low resolution of the instrument hinders any molecular speciation. In this work we investigate the specific aromatic content of Titan's atmospheric aerosols through laboratory simulations. We report here the selective detection of aromatic compounds in tholins, Titan's aerosol analogs, produced with a capacitively coupled plasma in a N2:CH4 95:5 gas mixture. For this purpose, Two-Step Laser Desorption Ionization Time-of-Flight Mass Spectrometry (L2DI-TOF-MS) technique is used to analyze the so produced analogs. This analytical technique is based on the ionization of molecules by Resonance Enhanced Multi-Photon Ionization (REMPI) using a λ=248 nm wavelength laser which is selective for aromatic species. This allows for the selective identification of compounds having at least one aromatic ring. Our experiments show that tholins contain a trace amount of small PAHs with one to three aromatic rings. Nitrogen containing PAHs (PANHs) are also detected as constituents of tholins. Molecules relevant to astrobiology are detected as is the case of the substituted DNA base adenine.

  9. Collinear resonant ionization laser spectroscopy of rare francium isotopes

    CERN Multimedia

    Neyens, G; Flanagan, K; Rajabali, M M; Le blanc, F M; Ware, T; Procter, T J

    2008-01-01

    We propose a programme of collinear resonant ionization spectroscopy (CRIS) of the francium isotopes up to and including $^{201}$Fr and $^{218,219}$Fr. This work aims at answering questions on the ordering of quantum states, and effect of the ($\\pi s_{1/2}^{-1}$)1/2$^{+}$ intruder state, which is currently believed to be the ground state of $^{199}$Fr. This work will also study the edge of the region of reflection asymmetry through measurement of the moments and radii of $^{218,219}$Fr. This proposal forms the first part of a series of experiments that will study nuclei in this region of the nuclear chart. Based on the success of this initial proposal it is the intention of the collaboration to perform high resolution measurements on the isotopes of radium and radon that surround $^{201}$Fr and $^{218}$Fr and thus providing a comprehensive description of the ground state properties of this region of the nuclear chart. Recent in-source spectroscopy measurements of lead, bismuth and polonium have demonstrated a...

  10. A Simple Method for the Evaluation of the Pulse Width of an Ultraviolet Femtosecond Laser Used in Two-Photon Ionization Mass Spectrometry

    Directory of Open Access Journals (Sweden)

    Tomoko Imasaka

    2016-05-01

    Full Text Available A simple method was proposed for on-site evaluation of the pulse width of an ultraviolet femtosecond laser coupled with a mass spectrometer. This technique was based on measurement of a two-photon ionization signal in mass spectrometry by translation of the prism in the pulse compressor of the femtosecond laser. The method was applied to optical pulses that were emitted at wavelengths of 267, 241, and 219 nm; the latter two pulses were generated by four-wave Raman mixing using the third harmonic emission of a Ti:sapphire laser (267 nm in hydrogen gas. The measurement results show that this approach is useful for evaluation of the pulse width of the ultraviolet femtosecond laser used in mass spectrometry for trace analysis of organic compounds.

  11. Relativistic features and time delay of laser-induced tunnel-ionization

    CERN Document Server

    Yakaboylu, Enderalp; Bauke, Heiko; Hatsagortsyan, Karen Z; Keitel, Christoph H

    2013-01-01

    The electron dynamics in the classically forbidden region during relativistic tunnel-ionization process is investigated. The classical forbidden region in the relativistic regime is identified by defining a gauge invariant total energy operator. Introducing position dependent energy levels inside the tunneling barrier, we demonstrate that the relativistic tunnel-ionization can be well described by a one-dimensional intuitive picture. This picture predicts that, in contrast to the well-known nonrelativisitic regime, the ionized electron wave packet in the relativistic regime arises with a momentum shift along the laser propagation direction. This is compatible with results from a strong field approximation calculation where the binding potential is assumed to be zero-range. Further, the tunneling time delay, stemming from Wigner's definition, is investigated for model configurations of tunneling and compared with results obtained from the exact propagator. By adapting Wigner's time delay definition the tunneli...

  12. Subpicosecond pulse laser absorption by an overdense plasma with variable ionization.

    Science.gov (United States)

    Zhidkov, A; Sasaki, A

    1999-06-01

    Transient ionization of an overdense plasma produced by a subpicosecond, p-polarized obliquely incident pulse laser of moderate intensity (10(16)-10(18) W/cm(2)) changes the plasma heat transfer via processes dominated by the return current and the absorption rate via ion acceleration. To explore the effect of variable ionization, a hybrid one-dimensional electro-magnetic particle-in-cell method that conforms to a direct solution of the Fokker-Planck-Landau equation is applied. A method that includes the Langevin equation to account for Coulomb collisions and the average ion model to calculate the nonlocal thermodynamic equilibrium ionization balance provides good agreement between the computed absorption and the measured results.

  13. Ionized and neutral gas in the peculiar star/cluster complex in NGC 6946

    CERN Document Server

    Efremov, Yu N; Alfaro, E J; Boomsma, R; Bastian, N; Larsen, S; Sanchez-Gil, M C; Silchenko, O K; García-Lorenzo, B; Muñoz-Tunón, C; Hodge, P W

    2007-01-01

    The characteristics of ionized and HI gas in the peculiar star/cluster complex in NGC 6946, obtained with the 6-m telescope (BTA) SAO RAS, the Gemini North telescope, and the Westerbork Synthesis Radio Telescope (WSRT), are presented. The complex is unusual as hosting a super star cluster, the most massive known in an apparently non-interacting giant galaxy. It contains a number of smaller clusters and is bordered by a sharp C-shaped rim. We found that the complex is additionally unusual in having peculiar gas kinematics. The velocity field of the ionized gas reveals a deep oval minimum, ~300 pc in size, centered 7" east of the supercluster. The Vr of the ionized gas in the dip center is 100 km/s lower than in its surroundings, and emission lines within the dip appear to be shock excited. This dip is near the center of an HI hole and a semi-ring of HII regions. The HI (and less certainly, HII) velocity fields reveal expansion, with the velocity reaching ~30 km/s at a distance about 300 pc from the center of e...

  14. Generation of naphthoquinone radical anions by electrospray ionization: solution, gas-phase, and computational chemistry studies.

    Science.gov (United States)

    Vessecchi, Ricardo; Naal, Zeki; Lopes, José N C; Galembeck, Sérgio E; Lopes, Norberto P

    2011-06-02

    Radical anions are present in several chemical processes, and understanding the reactivity of these species may be described by their thermodynamic properties. Over the last years, the formation of radical ions in the gas phase has been an important issue concerning electrospray ionization mass spectrometry studies. In this work, we report on the generation of radical anions of quinonoid compounds (Q) by electrospray ionization mass spectrometry. The balance between radical anion formation and the deprotonated molecule is also analyzed by influence of the experimental parameters (gas-phase acidity, electron affinity, and reduction potential) and solvent system employed. The gas-phase parameters for formation of radical species and deprotonated species were achieved on the basis of computational thermochemistry. The solution effects on the formation of radical anion (Q(•-)) and dianion (Q(2-)) were evaluated on the basis of cyclic voltammetry analysis and the reduction potentials compared with calculated electron affinities. The occurrence of unexpected ions [Q+15](-) was described as being a reaction between the solvent system and the radical anion, Q(•-). The gas-phase chemistry of the electrosprayed radical anions was obtained by collisional-induced dissociation and compared to the relative energy calculations. These results are important for understanding the formation and reactivity of radical anions and to establish their correlation with the reducing properties by electrospray ionization analyses.

  15. Application of atmospheric pressure ionization mass spectrometry to cover gas analysis in fast reactors

    CERN Document Server

    Harano, H

    2002-01-01

    This paper proposes to apply atmospheric pressure ionization mass spectrometry to on-line real-time monitoring gas analysis in fast reactors. The experimental results have shown that the quantitative analysis of the low ppt level can be achieved for all isotopes of krypton and xenon contained in argon except for the species, sup 7 sup 8 Kr, sup 8 sup 0 Kr, sup 1 sup 2 sup 4 Xe and sup 1 sup 2 sup 6 Xe that suffer interference by cluster ions. The excellent sensitivity is attributed to an ion concentration effect in an atmospheric pressure ionization process driven by the difference in ionization potential between argon and krypton or xenon. The detection limits (3 sigma) are estimated to be 20 ppt for sup 8 sup 4 Kr and 2.3 ppt for sup 1 sup 3 sup 2 Xe in the present condition.

  16. ANALYSIS OF THE DIFFUSE IONIZED GAS DATABASE: DIGEDA

    Directory of Open Access Journals (Sweden)

    Nahiely Flores-Fajardo

    2009-01-01

    Full Text Available Los estudios del Gas Ionizado Difuso (DIG, hasta el momento se han hecho sin un consenso del criterio estricto para diferenciar entre el DIG y las regiones H II. En este trabajo recopilamos las mediciones de las l neas en emisi n de 29 galaxias disponibles en la literatura, creando la primera base de datos del DIG (DI- GEDA. Haciendo uso de esta base, analizamos las propiedades globales del DIG a partir de los cocientes de l neas [N II]-6583/H , [O I]-6300/H , [O III]-5007/H y [S II]-6716/H , as como la medida de emisi n de H . Este an lisis nos permiti concluir que el cociente [N II]/H es un criterio general para diferenciar si una regi n en emisi n es DIG o regi n H II, mientras que la EM(H es una cantidad til nicamente cuando consideramos galaxias por separado. Finalmente, encontramos que las regiones clasi cadas como DIG en galaxias Irr parecen tener un comportamiento m s cercano al de las regiones H II que al DIG en galaxias espirales.

  17. Ion intensity and thermal proton transfer in ultraviolet matrix-assisted laser desorption/ionization.

    Science.gov (United States)

    Lu, I-Chung; Lee, Chuping; Chen, Hui-Yuan; Lin, Hou-Yu; Hung, Sheng-Wei; Dyakov, Yuri A; Hsu, Kuo-Tung; Liao, Chih-Yu; Lee, Yin-Yu; Tseng, Chien-Ming; Lee, Yuan-Tseh; Ni, Chi-Kung

    2014-04-17

    The ionization mechanism of ultraviolet matrix-assisted laser desorption/ionization (UV-MALDI) was investigated by measuring the total cation intensity (not including sodiated and potasiated ions) as a function of analyte concentration (arginine, histidine, and glycine) in a matrix of 2,4,6-trihydroxyacetophenone (THAP). The total ion intensity increased up to 55 times near the laser fluence threshold as the arginine concentration increased from 0% to 1%. The increases were small for histidine, and a minimal increase occurred for glycine. Time-resolved fluorescence intensity was employed to investigate how analytes affected the energy pooling of the matrix. No detectable energy pooling was observed for pure THAP and THAP/analyte mixtures. The results can be described by using a thermal proton transfer model, which suggested that thermally induced proton transfer is crucial in the primary ion generation in UV-MALDI.

  18. Applications of electrospray laser desorption ionization mass spectrometry for document examination.

    Science.gov (United States)

    Cheng, Sy-Chyi; Lin, Yu-Shan; Huang, Ming-Zong; Shiea, Jentaie

    2010-01-01

    We have employed electrospray laser desorption ionization mass spectrometry (ELDI-MS) to rapidly characterize certain classes of compounds--the inks within the characters made by inks and inkjet printer on regular paper and the chemical compounds within thermal papers. This ELDI-MS approach allowed the ink and paper samples to be distinguished in terms of their chemical compositions. Sample pretreatment was unnecessary and the documents were practically undamaged after examination. The ink chemicals on the documents were desorbed through laser irradiation (sampling spot area: <100 microm(2)); the desorbed molecules then entered an electrospray plume--prepared from an acidic methanol/water solution (50%)--where they became ionized through fusion or ion-molecule reactions with the charged solvent species and droplets in the plume.

  19. Multielectron dissociative ionization of methane and formaldehyde molecules with optimally tailored intense femtosecond laser pulses

    Science.gov (United States)

    Irani, E.; Anvari, A.; Sadighi-Bonabi, R.; Monfared, M.

    2017-10-01

    The multielectron dissociative ionization of CH4 and CH2O molecules has been investigated using optimum convolution of different dual tailored short laser pulses. Based on three dimensional molecular dynamics simulations and TDDFT approach, the dissociation probability is enhanced by designing the dual chirped-chirped laser pulses and chirped-ordinary laser pulses for formaldehyde molecule. However, it is interesting to notice that the sensitivity of enhanced dissociation probability into different tailored laser pulses is not significant for methane molecule. In this presented modifications, time variation of bond length, velocity, time dependent electron localization function and evolution of the efficient occupation states are presented to analyze the time evolution of molecular dynamics. This work is proved to be a potential way to reduce the controlling costs with a currently available pulse shaping technology.

  20. Qualitative Gas Chromatography-Mass Spectrometry Analyses Using Amines as Chemical Ionization Reagent Gases

    Science.gov (United States)

    Little, James L.; Howard, Adam S.

    2013-12-01

    Ammonia is a very useful chemical ionization (CI) reagent gas for the qualitative analyses of compounds by positive ion gas chromatography-mass spectrometry (GCMS). The gas is readily available, inexpensive, and leaves no carbon contamination in the MS source. Compounds of interest to our laboratory typically yield abundant protonated or ammoniated species, which are indicative of a compound's molecular weight. Nevertheless, some labile compounds fragment extensively by substitution and elimination reactions and yield no molecular weight information. In these cases, a CI reagent gas mixture of methylamine in methane prepared dynamically was found to be very useful in obtaining molecular weight data. Likewise, deuterated ammonia and deuterated methylamine are useful CI reagent gases for determining the exchangeable protons in organic compounds. Deuterated methylamine CI reagent gas is conveniently prepared by dynamically mixing small amounts of methylamine with excess deuterated ammonia.

  1. Characterization of aromaticity in analogues of titan's atmospheric aerosols with two-step laser desorption ionization mass spectrometry

    CERN Document Server

    Mahjoub, Ahmed; Carrasco, Nathalie; Benilan, Yves; Cernogora, Guy; Szopa, Cyril; Gazeau, Marie-Claire

    2016-01-01

    The role of polycyclic aromatic hydrocarbons (PAH) and Nitrogen containing PAH (PANH) as intermediates of aerosol production in the atmosphere of Titan has been a subject of controversy for a long time. An analysis of the atmospheric emission band observed by the Visible and Infrared Mapping Spectrometer (VIMS) at 3.28 micrometer suggests the presence of neutral polycyclic aromatic species in the upper atmosphere of Titan. These molecules are seen as the counter part of negative and positive aromatics ions suspected by the Plasma Spectrometer onboard the Cassini spacecraft, but the low resolution of the instrument hinders any molecular speciation. In this work we investigate the specific aromatic content of Titan's atmospheric aerosols through laboratory simulations. We report here the selective detection of aromatic compounds in tholins, Titan's aerosol analogues, produced with a capacitively coupled plasma in a N2:CH4 95:5 gas mixture. For this purpose, Two-Step Laser Desorption Ionization Time-of-Flight Ma...

  2. Analysis of Amphiphilic Lipids and Hydrophobic Proteins Using Nonresonant Femtosecond Laser Vaporization with Electrospray Post-Ionization

    Science.gov (United States)

    Brady, John J.; Judge, Elizabeth J.; Levis, Robert J.

    2011-04-01

    Amphiphilic lipids and hydrophobic proteins are vaporized at atmospheric pressure using nonresonant 70 femtosecond (fs) laser pulses followed by electrospray post-ionization prior to being transferred into a time-of-flight mass spectrometer for mass analysis. Measurements of molecules on metal and transparent dielectric surfaces indicate that vaporization occurs through a nonthermal mechanism. The molecules analyzed include the lipids 1-monooleoyl-rac-glycerol, 1,2-dihexanoyl- sn-glycero-3-phosphocholine, 1,2-dimyristoyl- sn-glycero-3-phosphocholine, and the hydrophobic proteins gramicidin A, B, and C. Vaporization of lipids from blood and milk are also presented to demonstrate that lipids in complex systems can be transferred intact into the gas phase for mass analysis.

  3. GISELE: A resonant ionization laser ion source for the production of radioactive ions at GANIL

    Energy Technology Data Exchange (ETDEWEB)

    Lecesne, N.; Alves-Conde, R.; De Oliveira, F.; Dubois, M.; Flambard, J. L.; Franberg, H.; Jardin, P.; Leroy, R.; Pacquet, J. Y.; Pichard, A.; Saint-Laurent, M. G. [GANIL, BP 55027, 14076 Caen Cedex 5 (France); Coterreau, E.; Le Blanc, F.; Olivier, A. [IPN Orsay, BP 1-91406 Orsay (France); Gottwald, T.; Mattolat, C.; Wendt, K. [Johannes Gutenberg-Universitaet Mainz, Staudinger Weg 7, 55099 Mainz (Germany); Lassen, J. [TRIUMF, 4004 Wesbrook Mall, Vancouver, British Columbia V6T 2A3 (Canada); Rothe, S. [Department of Engineering, CERN, CH-1211 Geneva 23 (Switzerland)

    2010-02-15

    SPIRAL2 is the new project under construction at GANIL to produce radioactive ion beams and in particular neutron rich ion beams. For the past 10 yr SPIRAL1 at GANIL has been delivering accelerated radioactive ion beams of gases. Both facilities now need to extend the range of radioactive ion beams produced to condensable elements. For that purpose, a resonant ionization laser ion source, funded by the French Research National Agency, is under development at GANIL, in collaboration with IPN Orsay, University of Mainz (Germany) and TRIUMF, Vancouver (Canada). A description of this project called GISELE (GANIL Ion Source using Electron Laser Excitation) is presented.

  4. A compact spark pre-ionized pulser sustainer TE–CO2 laser

    Indian Academy of Sciences (India)

    N S Benerji; Neeraj Varshnay; Lala Abhinandan; U Nundy

    2004-06-01

    A compact spark pre-ionized pulser sustainer TE–CO2 laser that can produce an output energy of one joule with an overall efficiency of 12.4% is presented. Optical pulses have durations of 7.15 s FWHM. Here, the laser uses all solid-state excitation (ASSE) circuit and the discharge formed between two uniform field electrodes placed 1.5 cm apart ultimately leads to a discharge volume of 50 cm × 1.5 cm × 1.5 cm.

  5. GISELE: A resonant ionization laser ion source for the production of radioactive ions at GANIL

    CERN Document Server

    Lecesne, N; Wendt, K; Mattolat, C; Rothe, S; Pichard, A; Pacquet, J Y; Dubois, M; Coterreau, E; Franberg, H; Leroy, R; Gottwald, T; Alves-Conde, R; Flambard, J L; De Oliveira, F; Le Blanc, F; Jardin, P; Olivier, A; Lassen, J

    2010-01-01

    SPIRAL2 is the new project under construction at GANIL to produce radioactive ion beams and in particular neutron rich ion beams. For the past 10 yr SPIRAL1 at GANIL has been delivering accelerated radioactive ion beams of gases. Both facilities now need to extend the range of radioactive ion beams produced to condensable elements. For that purpose, a resonant ionization laser ion source, funded by the French Research National Agency, is under development at GANIL, in collaboration with IPN Orsay, University of Mainz (Germany) and TRIUMF, Vancouver (Canada). A description of this project called GISELE (GANIL Ion Source using Electron Laser Excitation) is presented.

  6. Laser Microdissection and Atmospheric Pressure Chemical Ionization Mass Spectrometry Coupled for Multimodal Imaging

    Energy Technology Data Exchange (ETDEWEB)

    Lorenz, Matthias [ORNL; Ovchinnikova, Olga S [ORNL; Kertesz, Vilmos [ORNL; Van Berkel, Gary J [ORNL

    2013-01-01

    This paper describes the coupling of ambient laser ablation surface sampling, accomplished using a laser capture microdissection system, with atmospheric pressure chemical ionization mass spectrometry for high spatial resolution multimodal imaging. A commercial laser capture microdissection system was placed in close proximity to a modified ion source of a mass spectrometer designed to allow for sampling of laser ablated material via a transfer tube directly into the ionization region. Rhodamine 6G dye of red sharpie ink in a laser etched pattern as well as cholesterol and phosphatidylcholine in a cerebellum mouse brain thin tissue section were identified and imaged from full scan mass spectra. A minimal spot diameter of 8 m was achieved using the 10X microscope cutting objective with a lateral oversampling pixel resolution of about 3.7 m. Distinguishing between features approximately 13 m apart in a cerebellum mouse brain thin tissue section was demonstrated in a multimodal fashion including co-registered optical and mass spectral chemical images.

  7. Ionization and acceleration of heavy ions in high-Z solid target irradiated by high intensity laser

    OpenAIRE

    Kawahito, D.; Kishimoto, Y

    2016-01-01

    In the interaction between high intensity laser and solid film, an ionization dynamics inside the solid is dominated by fast time scale convective propagation of the internal sheath field and the slow one by impact ionization due to heated high energy electrons coupled with nonlocal heat transport. Furthermore, ionization and acceleration due to the localized external sheath field which co- propagates with Al ions constituting the high energy front in the vacuum region. Through this process, ...

  8. An evaluation of the spectral properties of nerve agents for laser ionization mass spectrometry.

    Science.gov (United States)

    Imasaka, Tomoko; Imasaka, Totaro

    2014-01-01

    Excitation energies, oscillator strengths, and vacuum-ultraviolet/deep-ultraviolet absorption spectra were calculated for nerve agents, such as sarin, soman, VX, tabun, mustard gas, and analogs. We used time-dependent density functional theory (TD-DFT) methods that included B3LYP combined with basis sets of cc-pVDZ and cc-pVTZ, and ωB97XD with cc-pVTZ. The vertical ionization energies were also calculated for these compounds, in order to collect additional information relative to the optimal pathways for multiphoton ionization in mass spectrometry.

  9. Third Harmonic Generation of a Short Pulse Laser in a Tunnel Ionizing Plasma: Effect of Self-Defocusing

    Directory of Open Access Journals (Sweden)

    Niti Kant

    2013-08-01

    Full Text Available Third harmonic generation of a Gaussian short pulse laser in a tunnel ionizing plasma is investigated. A Gaussian short pulse laser propagating through a tunnel ionizing plasma generates third harmonic wave. Inhomogeneity of the electric field along the wavefront of the fundamental laser pulse causes more ionization along the axis of propagation while less ionization off axis, leading to strong density gradient with its maximum on the axis of propagation. The medium acts like a diverging lens and pulse defocuses strongly. The normalized third harmonic amplitude varies periodically with the distance with successive maxima acquiring lower value. The self-defocusing of the fundamental laser pulse decays the intensity of the third harmonic pulse.

  10. Experimental research on benzene detection using ion mobility spectrometer with a laser ionization source

    Institute of Scientific and Technical Information of China (English)

    LIU Xian-yun; KONG Xiang-he; JI Ren-dong; ZHANG Shu-dong

    2006-01-01

    An ion mobility spectrometer equipped with a laser ionization source is used for the sensitive detection of benzene.Mobility spectra of the benzene are presented.We also discussed the mobility spectra at various concentrations and drift voltages.Detection limits are determined to be in the upper ppbv range.In the end,the advantages and possibilities of this technique are briefly discussed.

  11. The structure of radiative shock waves. III. The model grid for partially ionized hydrogen gas

    CERN Document Server

    Fadeyev, Y A; Fadeyev, Yu. A.

    2001-01-01

    The grid of the models of radiative shock waves propagating through partially ionized hydrogen gas with temperature 3000K <= T_1 <= 8000K and density 10^{-12} gm/cm^3 <= \\rho_1 <= 10^{-9}gm/cm^3 is computed for shock velocities 20 km/s <= U_1 <= 90 km/s. The fraction of the total energy of the shock wave irreversibly lost due to radiation flux ranges from 0.3 to 0.8 for 20 km/s <= U_1 <= 70 km/s. The postshock gas is compressed mostly due to radiative cooling in the hydrogen recombination zone and final compression ratios are within 1 <\\rho_N/\\rho_1 \\lesssim 10^2, depending mostly on the shock velocity U_1. The preshock gas temperature affects the shock wave structure due to the equilibrium ionization of the unperturbed hydrogen gas, since the rates of postshock relaxation processes are very sensitive to the number density of hydrogen ions ahead the discontinuous jump. Both the increase of the preshock gas temperature and the decrease of the preshock gas density lead to lower postsh...

  12. Ionized gas disks in Elliptical and S0 galaxies at $z<1$

    CERN Document Server

    Jaffe, Yara L; Ziegler, Bodo; Kuntschner, Harald; Zaritsky, Dennis; Rudnick, Gregory; Poggianti, Bianca M; Hoyos, Carlos; Halliday, Claire; Demarco, Ricardo

    2014-01-01

    We analyse the extended, ionized-gas emission of 24 early-type galaxies (ETGs) at $0ionization and favour star-formation as the main cause of the observed emission. Ten galaxies have disturbed gas kinematics, while 14 have rotating gas disks. In addition, 15 galaxies are in the field, while 9 are in the infall regions of clusters. This implies that, if the gas has an internal origin, this is likely stripped as the galaxies get closer to the cluster centre. If the gas instead comes from an external source, then our results suggest that this is more likely acquired outside the cluster environment, where galaxy-galaxy interactions more commonly take place. We analyse the Tully-Fisher relation of the ETGs with gas disks, and compare them to EDisCS spirals. Taking a matched range of redshifts, $M_{B}<-20$, and excluding galaxies with large velocity uncertainties, we find that, at fixed rotational velocity, ETGs ar...

  13. A novel sample preparation method of matrix-assisted laser desorption/ionization time of flight mass spectrometry for polystyrene

    Institute of Scientific and Technical Information of China (English)

    Shu Zhang; Zhen Wen Zhao; Lei Xiong; Bin Xin; Wei Hua Hu; Shao Xiang Xiong

    2007-01-01

    A novel sample preparation method of matrix-assisted laser desorption/ionization mass spectrometry for polystyrene was reported.Compared to the conventional dried-droplet method, the efficiency of ionization and signal intensity of mass spectra were improved.The mechanism was also analyzed.

  14. Fully differential cross sections for ion-atom impact ionization in the presence of a laser field

    Energy Technology Data Exchange (ETDEWEB)

    Ciappina, M F [Max Planck Institute for the Physics of Complex Systems, Noethnitzer Str 38, D-01187, Dresden (Germany)

    2007-11-14

    We study fully differential cross sections (FDCS) for single ionization of helium by ion impact in the presence of a laser field. The field is assumed to have linear polarization, to be weak compared to the typical atomic field, and we use a frequency corresponding to a CO{sub 2} laser. We employ the continuum distorted wave-eikonal initial state (CDW-EIS) to describe our FDCS in the laser background. Analysing our numerical results we explore the dependence of the FDCS on the laser field properties as well as on the ionized electron parameters.

  15. Synthesis of refractory organic matter in the ionized gas phase of the solar nebula.

    Science.gov (United States)

    Kuga, Maïa; Marty, Bernard; Marrocchi, Yves; Tissandier, Laurent

    2015-06-01

    In the nascent solar system, primitive organic matter was a major contributor of volatile elements to planetary bodies, and could have played a key role in the development of the biosphere. However, the origin of primitive organics is poorly understood. Most scenarios advocate cold synthesis in the interstellar medium or in the outer solar system. Here, we report the synthesis of solid organics under ionizing conditions in a plasma setup from gas mixtures (H2(O)-CO-N2-noble gases) reminiscent of the protosolar nebula composition. Ionization of the gas phase was achieved at temperatures up to 1,000 K. Synthesized solid compounds share chemical and structural features with chondritic organics, and noble gases trapped during the experiments reproduce the elemental and isotopic fractionations observed in primitive organics. These results strongly suggest that both the formation of chondritic refractory organics and the trapping of noble gases took place simultaneously in the ionized areas of the protoplanetary disk, via photon- and/or electron-driven reactions and processing. Thus, synthesis of primitive organics might not have required a cold environment and could have occurred anywhere the disk is ionized, including in its warm regions. This scenario also supports N2 photodissociation as the cause of the large nitrogen isotopic range in the solar system.

  16. Detailed instantaneous ionization rate of H$_2^+$ in intense laser field

    CERN Document Server

    Vafaee, M; Vafaee, Z; Katanforoush, A; Vafaee, Mohsen; Sabzyan, Hassan; Vafaee, Zahra; Katanforoush, Ali

    2006-01-01

    Component of the instantaneous ionization rate (IIR) is introduced and calculated for H$_2^+$ in a linearly polarized laser field with $1.0 \\times 10^{14}$W cm$^{-2}$ intensity and $\\lambda \\sim 1064 $nm wavelength by direct solution of the fixed-nuclei full dimensional time-dependent Schr \\"odinger equation. The component ionization rates, calculated for different values of inter-nuclear distance, are compared with those calculated via the virtual detector method (VD). Details of the time dependent behavior of the outgoing and incoming electron wavepakets of the H$_2^+$ system in intense laser field at attosecond time scale are studied based on the calculated component ionization rates. It has been shown clearly that the positive signals of the IIR (outgoing electron wavepacket signals) are strong and sharp but the negative signals of the IIR (returning electron wavepacket signals) are smooth and weak. It is also shown that for H-H distance R<5.6, when the laser pulse is turned on with a ramp, the R-depen...

  17. Multiphoton ionization of jet-cooled nickelocene with tunable nanosecond laser pulses

    Energy Technology Data Exchange (ETDEWEB)

    Ketkov, Sergey Yu.; Selzle, Heinrich L.; Schlag, Edward W.; Titova, Sofia

    2003-08-15

    Efficient multiphoton ionization of nickelocene molecules in a supersonically cooled molecular beam has been performed for the first time with a nanosecond tunable dye laser operating in the 35,000-cm{sup -1} region which corresponds to the lowest Rydberg transition observed in the one-photon absorption spectrum. The time-of-flight mass spectra obtained show strong signals of intact molecular ions Cp{sub 2}Ni{sup +} (Cp={eta}{sup 5}-C{sub 5}H{sub 5}) and weaker peaks of fragment ions CpNi{sup +}. The conditions have been found for generation of Cp{sub 2}Ni{sup +} as the only ionic product of multiphoton excitation. The ion signal dependence on the laser intensity and the resonance-enhanced multiphoton ionization spectrum measured at the mass of Cp{sub 2}Ni{sup +} testify for saturation of absorption and/or ionization steps at the laser pulse intensities used (2-6 MW cm{sup -2}). Possible mechanisms of multiphoton processes resulting in formation of the ions observed are discussed.

  18. All-solid-state deep ultraviolet laser for single-photon ionization mass spectrometry.

    Science.gov (United States)

    Yuan, Chengqian; Liu, Xianhu; Zeng, Chenghui; Zhang, Hanyu; Jia, Meiye; Wu, Yishi; Luo, Zhixun; Fu, Hongbing; Yao, Jiannian

    2016-02-01

    We report here the development of a reflectron time-of-flight mass spectrometer utilizing single-photon ionization based on an all-solid-state deep ultraviolet (DUV) laser system. The DUV laser was achieved from the second harmonic generation using a novel nonlinear optical crystal KBe2BO3F2 under the condition of high-purity N2 purging. The unique property of this laser system (177.3-nm wavelength, 15.5-ps pulse duration, and small pulse energy at ∼15 μJ) bears a transient low power density but a high single-photon energy up to 7 eV, allowing for ionization of chemicals, especially organic compounds free of fragmentation. Taking this advantage, we have designed both pulsed nanospray and thermal evaporation sources to form supersonic expansion molecular beams for DUV single-photon ionization mass spectrometry (DUV-SPI-MS). Several aromatic amine compounds have been tested revealing the fragmentation-free performance of the DUV-SPI-MS instrument, enabling applications to identify chemicals from an unknown mixture.

  19. Optimization of the ionization time of an atom with tailored laser pulses: a theoretical study

    CERN Document Server

    Kammerlander, David; Marques, Miguel A L

    2016-01-01

    How fast can a laser pulse ionize an atom? We address this question by considering pulses that carry a fixed time-integrated energy per-area, and finding those that achieve the double requirement of maximizing the ionization that they induce, while having the shortest duration. We formulate this double-objective quantum optimal control problem by making use of the Pareto approach to multi-objetive optimization, and the differential evolution genetic algorithm. The goal is to find out how much a precise time-profiling of ultra-fast, large-bandwidth pulses may speed up the ionization process with respect to simple-shape pulses. We work on a simple one-dimensional model of hydrogen-like atoms (the P\\"oschl-Teller potential), that allows to tune the number of bound states that play a role in the ionization dynamics. We show how the detailed shape of the pulse accelerates the ionization process, and how the presence or absence of bound states influences the velocity of the process.

  20. Discovery of Multiple, Ionization-Created Anions in Gas Mixtures Containing CS2 and O2

    CERN Document Server

    Snowden-Ifft, Daniel P

    2013-01-01

    The use of negative ions in TPCs has several advantages for high-resolution rare- event detection experiments. The DRIFT experiment, for example, has taken full advantage of this technique over the past decade in a directional search for dark matter. This paper focuses on the surprising discovery of multiple species of ionization-created CS2 anions, called minority carriers, in gas mixtures containing electronegative CS2 and O2, identified by their slightly different drift velocities. Measurements of minority carriers in gas mixtures of CS2, CF4 and O2 are reported in an effort to understand the nature of these charge carriers. Regardless of the micro-physics however, this discovery offers significant practical advantages for experiments such as DRIFT, where the difference in arrival time may be used to fiducialize the original ionization event without an external start pulse.

  1. Comparative mass spectrometric analyses of Photofrin oligomers by fast atom bombardment mass spectrometry, UV and IR matrix-assisted laser desorption/ionization mass spectrometry, electrospray ionization mass spectrometry and laser desorption/jet-cooling photoionization mass spectrometry.

    Science.gov (United States)

    Siegel, M M; Tabei, K; Tsao, R; Pastel, M J; Pandey, R K; Berkenkamp, S; Hillenkamp, F; de Vries, M S

    1999-06-01

    Photofrin (porfimer sodium) is a porphyrin derivative used in the treatment of a variety of cancers by photodynamic therapy. This oligomer complex and a variety of porphyrin monomers, dimers and trimers were analyzed with five different mass spectral ionization techniques: fast atom bombardment, UV and IR matrix-assisted laser desorption/ionization, electrospray ionization, and laser desorption/jet-cooling photoionization. All five approaches resulted in very similar oligomer distributions with an average oligomer length of 2.7 +/- 0.1 porphyrin units. In addition to the Photofrin analysis, this study provides a side-by-side comparison of the spectra for the five different mass spectrometric techniques.

  2. A VUV photoionization measurement and ab-initio calculation of the ionization energy of gas phase SiO2

    Energy Technology Data Exchange (ETDEWEB)

    Kostko, Oleg; Ahmed, Musahid; Metz, Ricardo B.

    2008-12-05

    In this work we report on the detection and vacuum-ultraviolet (VUV) photoionization of gas phase SiO2 generated in situ via laser ablation of silicon in a CO2 molecular beam. The resulting species are investigated by single photon ionization with tunable VUV synchrotron radiation and mass analyzed using reflectron mass spectrometry. Photoionization efficiency (PIE) curves are recorded for SiO and SiO2 and ionization energy estimates are revealed from such measurements. A state-to-state ionizationenergy of 12.60 (+-0.05) eV is recorded by fitting two prominent peaks in the PIE curve for the following process: 1SUM O-Si-O --> 2PRODg [O-Si-O]+. Electronic structure calculations aid in the interpretation of the photoionization process and allow for identification of the symmetric stretch of 2PRODg [O-Si-O]+ which is observed in the PIE spectrum to be 0.11 eV (890 cm-1) above the ground state of the cation and agrees with the 892 cm-1 symmetric stretch frequency calculated at the CCSD(T)/aug-cc-pVTZ level.

  3. A Pre-ionization System to Limit Neutral Gas in a Compact Toroid Injector

    Science.gov (United States)

    Allfrey, Ian; Roche, Thomas; Matsumoto, Tadafumi; Garate, Eusebio; Gota, Hiroshi; Asai, Tomohiko; the TAE Team

    2016-10-01

    Fusion plasmas require long lifetimes and high temperatures, both of which are limited by particle loss, among other factors. Therefore, refueling a long-lived advanced beam-driven field-reversed configuration (FRC) plasma in C-2U is necessary, and injecting a supersonic compact toroid (CT) is an effective means of introducing particles into the FRC core. However, neutral gas that trails the CT into the target chamber cools the FRC. Pre-ionization (PI) system assists the break down between electrodes of the CT injector (CTI), so the amount of introduced gas can be lowered by up to a factor of two, effectively increasing the ionization fraction; thus, reducing the amount of neutral gas in the system. Additionally, the PI decreases the delay in CTI breakdown so a highly reproducible operation is achievable. The PI system consists of a fast, high voltage, pulse discharge circuit coupled to a Teflon insulated semi-rigid coaxial cable inserted into the CTI. System details and experimental data will be presented, in addition to issues such as the introduction of impurities and pre-ionizer lifetime.

  4. Thin films deposited by laser ablation for the measurement of the ionizing and non-ionizing radiation; Peliculas delgadas depositadas por ablacion laser para la medicion de radiacion ionizante y no ionizante

    Energy Technology Data Exchange (ETDEWEB)

    Villarreal B, J.E.; Escobar A, L.; Camps, E.; Romero, S.; Gonzalez, P.; Salinas, B. [Instituto Nacional de Investigaciones Nucleares, A.P. 18-1027, 11801 Mexico D.F. (Mexico)

    2001-07-01

    In this work the obtained results to synthesize thin films of amorphous carbon with incorporated nitrogen and hydrogen are presented, as well as thin films of aluminium oxide using the laser ablation technique. The thin films were exposed to ionizing radiation (gamma rays of a {sup 60} Co source, beta radiation of a {sup 90} Sr source) and a non-ionizing radiation (UV radiation). The obtained results show that it is possible to obtain materials in thin film form with thickness of hundreds of nanometers, which present thermoluminescent response when being irradiated with ionizing radiation and non-ionizing radiation. (Author)

  5. Breakdown voltage reduction by field emission in multi-walled carbon nanotubes based ionization gas sensor

    Energy Technology Data Exchange (ETDEWEB)

    Saheed, M. Shuaib M.; Muti Mohamed, Norani; Arif Burhanudin, Zainal, E-mail: zainabh@petronas.com.my [Centre of Innovative Nanostructures and Nanodevices, Universiti Teknologi PETRONAS, Bandar Seri Iskandar, 31750 Tronoh, Perak (Malaysia)

    2014-03-24

    Ionization gas sensors using vertically aligned multi-wall carbon nanotubes (MWCNT) are demonstrated. The sharp tips of the nanotubes generate large non-uniform electric fields at relatively low applied voltage. The enhancement of the electric field results in field emission of electrons that dominates the breakdown mechanism in gas sensor with gap spacing below 14 μm. More than 90% reduction in breakdown voltage is observed for sensors with MWCNT and 7 μm gap spacing. Transition of breakdown mechanism, dominated by avalanche electrons to field emission electrons, as decreasing gap spacing is also observed and discussed.

  6. Polycyclic aromatic hydrocarbon ionization as a tracer of gas flows through protoplanetary disk gaps

    OpenAIRE

    Maaskant, K. M.; Min, M.; Waters, L. B. F. M.; Tielens, A. G. G. M.

    2014-01-01

    Context. Planet-forming disks of gas and dust around young stars contain polycyclic aromatic hydrocarbons (PAHs). Aims. We aim to characterize how the charge state of PAHs can be used as a probe of flows of gas through protoplanetary gaps. In this context, our goal is to understand the PAH spectra of four transitional disks. In addition, we want to explain the observed correlation between PAH ionization (traced by the I6.2/I11.3 feature ratio) and the disk mass (traced by the 1.3 mm luminosit...

  7. Non-traditional applications of laser desorption/ionization mass spectrometry

    Science.gov (United States)

    McAlpin, Casey R.

    Seven studies were carried out using laser desorption/ionization mass spectrometry (LDI MS) to develop enhanced methodologies for a variety of analyte systems by investigating analyte chemistries, ionization processes, and elimination of spectral interferences. Applications of LDI and matrix assisted laser/desorption/ionization (MALDI) have been previously limited by poorly understood ionization phenomena, and spectral interferences from matrices. Matrix assisted laser desorption ionization MS is well suited to the analysis of proteins. However, the proteins associated with bacteriophages often form complexes which are too massive for detection with a standard MALDI mass spectrometer. As such, methodologies for pretreatment of these samples are discussed in detail in the first chapter. Pretreatment of bacteriophage samples with reducing agents disrupted disulfide linkages and allowed enhanced detection of bacteriophage proteins. The second chapter focuses on the use of MALDI MS for lipid compounds whose molecular mass is significantly less than the proteins for which MALDI is most often applied. The use of MALDI MS for lipid analysis presented unique challenges such as matrix interference and differential ionization efficiencies. It was observed that optimization of the matrix system, and addition of cationization reagents mitigated these challenges and resulted in an enhanced methodology for MALDI MS of lipids. One of the challenges commonly encountered in efforts to expand MALDI MS applications is as previously mentioned interferences introduced by organic matrix molecules. The third chapter focuses on the development of a novel inorganic matrix replacement system called metal oxide laser ionization mass spectrometry (MOLI MS). In contrast to other matrix replacements, considerable effort was devoted to elucidating the ionization mechanism. It was shown that chemisorption of analytes to the metal oxide surface produced acidic adsorbed species which then

  8. Role of direct laser acceleration in energy gained by electrons in a laser wakefield accelerator with ionization injection

    CERN Document Server

    Shaw, J L; Vafaei-Najafabadi, N; Marsh, K A; Lemos, N; Mori, W B; Joshi, C

    2014-01-01

    We have investigated the role that the transverse electric field of the laser plays in the acceleration of electrons in a laser wakefield accelerator (LWFA) operating in the quasi-blowout regime through particle-in-cell code simulations. In order to ensure that longitudinal compression and/or transverse focusing of the laser pulse is not needed before the wake can self-trap the plasma electrons, we have employed the ionization injection technique. Furthermore, the plasma density is varied such that at the lowest densities, the laser pulse occupies only a fraction of the first wavelength of the wake oscillation (the accelerating bucket), whereas at the highest density, the same duration laser pulse fills the entire first bucket. Although the trapped electrons execute betatron oscillations due to the ion column in all cases, at the lowest plasma density they do not interact with the laser field and the energy gain is all due to the longitudinal wakefield. However, as the density is increased, there can be a sig...

  9. Completing electron scattering studies with the inert gas column:e - Rn scattering and Ionization

    CERN Document Server

    Joshi, Foram M; Chaudhari, Asha S; Modi, Hitesh S; Pindaria, Manish J

    2016-01-01

    Interest in the inert or noble- gas atoms in general arises because they are ideal as test systems for various theoretical models of electron scattering and also since their interaction processes serve as reference for the determination of instrumental responses in electron scattering experiments. The ionization cross section data of ground state inert gas atoms He through Xe are considered to be benchmark data. Our aim in this paper is to provide theoretical results on electron scattering with Radon atoms, as it would complete the studies on the entire inert gas column. That is possible with this particular column only, in view of the preceding literature on He through Xe . Inert gas radon is radioactive, and would be a difficult target for electron scattering experiments. In the present calculations, the complications arising from radioactivity are not considered. We provide hitherto unavailable cross sections on atomic radon, and also provide opportunity of the comparison of electron impact cross sections ...

  10. Ambient Mass Spectrometry Imaging with Picosecond Infrared Laser Ablation Electrospray Ionization (PIR-LAESI).

    Science.gov (United States)

    Zou, Jing; Talbot, Francis; Tata, Alessandra; Ermini, Leonardo; Franjic, Kresimir; Ventura, Manuela; Zheng, Jinzi; Ginsberg, Howard; Post, Martin; Ifa, Demian R; Jaffray, David; Miller, R J Dwayne; Zarrine-Afsar, Arash

    2015-12-15

    A picosecond infrared laser (PIRL) is capable of cutting through biological tissues in the absence of significant thermal damage. As such, PIRL is a standalone surgical scalpel with the added bonus of minimal postoperative scar tissue formation. In this work, a tandem of PIRL ablation with electrospray ionization (PIR-LAESI) mass spectrometry is demonstrated and characterized for tissue molecular imaging, with a limit of detection in the range of 100 nM for reserpine or better than 5 nM for verapamil in aqueous solution. We characterized PIRL crater size using agar films containing Rhodamine. PIR-LAESI offers a 20-30 μm vertical resolution (∼3 μm removal per pulse) and a lateral resolution of ∼100 μm. We were able to detect 25 fmol of Rhodamine in agar ablation experiments. PIR-LAESI was used to map the distribution of endogenous methoxykaempferol glucoronide in zebra plant (Aphelandra squarrosa) leaves producing a localization map that is corroborated by the literature. PIR-LAESI was further used to image the distribution inside mouse kidneys of gadoteridol, an exogenous magnetic resonance contrast agent intravenously injected. Parallel mass spectrometry imaging (MSI) using desorption electrospray ionization (DESI) and matrix assisted laser desorption ionization (MALDI) were performed to corroborate PIR-LAESI images of the exogenous agent. We further show that PIR-LAESI is capable of desorption ionization of proteins as well as phospholipids. This comparative study illustrates that PIR-LAESI is an ion source for ambient mass spectrometry applications. As such, a future PIRL scalpel combined with secondary ionization such as ESI and mass spectrometry has the potential to provide molecular feedback to guide PIRL surgery.

  11. Dissociative ionization and Coulomb explosion of CH3I in intense femto second laser fields

    Science.gov (United States)

    Zhang, Dongdong; Luo, Sizuo; Xu, Haifeng; Jin, Mingxing; Liu, Fuchun; Yan, Bing; Wang, Zhigang; Liu, Hang; Jiang, Dianwu; Eppink, André; Roeterdink, Wim; Stolte, Steven; Ding, Dajun

    2017-06-01

    The interaction of CH3I molecules with 100 fs 800 nm linearly polarized laser fields has been investigated at the intensity region from 2.6 × 1014 to 5.8 × 1014 W/cm2 by means of a velocity map imaging method. The kinetic energy distribution of the various atomic fragment ions I q+ ( q = 1-3) has been measured and reproduced by a fit of multiple Gaussian functions. Several dissociative ionization and Coulomb explosion channels were identified for I q+ ( q = 1-3). As expected for a geometric alignment dominated interaction process the anisotropic angular recoil distributions of the atomic ion fragments are peaked in the laser polarization direction. The kinetic energy release (KER) of I q+ ( q = 1-3) depending upon the laser intensity has been investigated. The relative weight of the various contributions from the identified dissociative ionization (DI) and Coulomb explosion (CE) channels is found to depend strongly on the laser intensity.

  12. GAS ACCRETION IS DOMINATED BY WARM IONIZED GAS IN MILKY WAY MASS GALAXIES AT z {approx} 0

    Energy Technology Data Exchange (ETDEWEB)

    Joung, M. Ryan; Putman, Mary E.; Bryan, Greg L.; Fernandez, Ximena; Peek, J. E. G., E-mail: moo@astro.columbia.edu [Department of Astronomy, Columbia University, 550 West 120th Street, New York, NY 10027 (United States)

    2012-11-10

    We perform high-resolution hydrodynamic simulations of a Milky Way mass galaxy in a fully cosmological setting using the adaptive mesh refinement code, Enzo, and study the kinematics of gas in the simulated galactic halo. We find that the gas inflow occurs mostly along filamentary structures in the halo. The warm-hot (10{sup 5} K 10{sup 6} K) ionized gases are found to dominate the overall mass accretion in the system (with M-dot = 3-5 M {sub Sun} yr{sup -1}) over a large range of distances, extending from the virial radius to the vicinity of the disk. Most of the inflowing gas (by mass) does not cool, and the small fraction that manages to cool does so primarily close to the galaxy (R {approx}< 100 kpc, with more pronounced cooling at smaller R), perhaps comprising the neutral gas that may be detectable as, e.g., high-velocity clouds. The neutral clouds are embedded within larger, accreting filamentary flows, and represent only a small fraction of the total mass inflow rate. The inflowing gas has relatively low metallicity (Z/Z {sub Sun} < 0.2). The outer layers of the filamentary inflows are heated due to compression as they approach the disk. In addition to the inflow, we find high-velocity, metal-enriched outflows of hot gas driven by supernova feedback. Our results are consistent with observations of halo gas at low z.

  13. Multiphoton Ionization as a clock to Reveal Molecular Dynamics with Intense Short X-ray Free Electron Laser Pulses

    CERN Document Server

    Fang, L; Murphy, B; Tarantelli, F; Kukk, E; Cryan, J P; Glownia, M; Bucksbaum, P H; Coffee, R N; Chen, M; Buth, C; Berrah, N

    2013-01-01

    We investigate molecular dynamics of multiple ionization in N2 through multiple core-level photoabsorption and subsequent Auger decay processes induced by intense, short X-ray free electron laser pulses. The timing dynamics of the photoabsorption and dissociation processes is mapped onto the kinetic energy of the fragments. Measurements of the latter allow us to map out the average internuclear separation for every molecular photoionization sequence step and obtain the average time interval between the photoabsorption events. Using multiphoton ionization as a tool of multiple-pulse pump-probe scheme, we demonstrate the modi?cation of the ionization dynamics as we vary the x-ray laser pulse duration.

  14. A LASER ION-SOURCE FOR ONLINE MASS SEPARATION

    NARCIS (Netherlands)

    VANDUPPEN, P; DENDOOVEN, P; HUYSE, M; VERMEEREN, L; QAMHIEH, ZN; SILVERANS, RE; VANDEWEERT, E

    1992-01-01

    A laser ion source based on resonance photo ionization in a gas cell is proposed. The gas cell, filled with helium, consists of a target chamber in which the recoil products are stopped and neutralized, and an ionization chamber where the atoms of interest are selectively ionized by the laser light.

  15. Resistance of YAG:Nd sup 3+ laser frequency converters to ionizing radiation

    Science.gov (United States)

    Zakharkin, B. I.; Kulevskiy, L. A.; Nikolayev, V. N.; Toropkin, G. N.

    1986-02-01

    This study presents a review of published work on the radiation resistance of YAG:Nd sup 3+ laser frequency converters, and describes the results of experiments on the influence of gamma-irradiation of nonlinear crystals on the output characteristics of YAG:Nd sup 3+ lasers with second-harmonic generation inside or outside the cavity. The influence of radiation on the optical properties of nonlinear crystals is investigated. It is found that radiation degrades the generation of optical harmonics in YAG:ND sup 3+ lasers employing nonlinear elements made of SDA, DSDA, LiIO3 and DKDR crystals, starting at doses of 10 to the 5th power - 10 to the 6th power rad. Deuterized nonlinear crystals are found to be more resistant to ionizing radiation.

  16. The tunneling model of laser-induced ionization and its failure at low frequencies

    CERN Document Server

    Reiss, H R

    2014-01-01

    The tunneling model of ionization applies only to longitudinal fields: quasistatic electric fields that do not propagate. Laser fields are transverse: plane wave fields that possess the ability to propagate. Although there is an approximate connection between the effects of longitudinal and transverse fields in a useful range of frequencies, that equivalence fails completely at very low frequencies. Insight into this breakdown is given by an examination of radiation pressure, which is a unique transverse-field effect whose relative importance increases rapidly as the frequency declines. Radiation pressure can be ascribed to photon momentum, which does not exist for longitudinal fields. Two major consequences are that the near-universal acceptance of a static electric field as the zero frequency limit of a laser field is not correct; and that the numerical solution of the dipole-approximate Schr\\"{o}dinger equation for laser effects is inapplicable as the frequency declines. These problems occur because the ma...

  17. LIF-imaging and gas-phase diagnostics of laser desorbed MALDI-matrix plumes

    Energy Technology Data Exchange (ETDEWEB)

    Puretzky, A.A.; Geohegan, D.B. [Oak Ridge National Lab., TN (United States). Solid State Div.

    1997-07-01

    The first gated LIF-imaging and absorption spectroscopy has been performed on laser desorbed plumes from organic crystals which are commonly used as MALDI (Matrix Assisted Laser Desorption Ionization) matrices. These plasma diagnostic techniques, including ion probe measurements were employed to investigate the desorbed products, densities, fractional ionization, and velocity distributions of the plume of ejecta which is typically employed as the main desorption product in the mass spectrometry analysis of large biomolecules. Ultraviolet pulsed 193-nm and 248-nm irradiation of 3-hydroxypicolinic acid (3-HPA) crystals were studied to understand the effect of very different gas-phase absorption cross sections measured here for this material. In both cases, LIF imaging revealed two plume components: a fast (maximum {approximately} 0.1 cm/{micro}s) low-intensity component which appear to be 3-HPA fragments, and a slower component of 3-HPA expanding at 0.05 cm/{micro}s. In the case of ArF-laser irradiation, optical absorption spectroscopy indicated a breaking of the intramolecular hydrogen bond in the gas-phase matrix material.

  18. A novel benzene quantitative analysis method using miniaturized metal ionization gas sensor and non-linear bistable dynamic system.

    Science.gov (United States)

    Tang, Xuxiang; Liu, Fuqi

    2015-01-01

    In this paper, a novel benzene quantitative analysis method utilizing miniaturized metal ionization gas sensor and non-linear bistable dynamic system was investigated. Al plate anodic gas-ionization sensor was installed for electrical current-voltage data measurement. Measurement data was analyzed by non-linear bistable dynamics system. Results demonstrated that this method realized benzene concentration quantitative determination. This method is promising in laboratory safety management in benzene leak detection.

  19. Internal energy deposition and ion fragmentation in atmospheric-pressure mid-infrared laser ablation electrospray ionization.

    Science.gov (United States)

    Nemes, Peter; Huang, Hehua; Vertes, Akos

    2012-02-21

    Mid-infrared laser ablation of water-rich targets at the maximum of the 2.94 μm absorption band is a two-step process initiated by phase explosion followed by recoil pressure induced material ejection. Particulates and/or droplets ejected by this high temperature high pressure process can be ionized for mass spectrometry by charged droplets from an electrospray. In order to gauge the internal energy introduced in this laser ablation electrospray ionization (LAESI®) process, we apply the survival yield method and compare the results with electrospray ionization (ESI) and matrix-assisted laser desorption ionization (MALDI). The results indicate that LAESI yields ions with internal energies indistinguishable from those produced by ESI. This finding is consistent with the recoil pressure induced ejection of low micrometre droplets that does not significantly change the internal energy of solute molecules.

  20. Identification of Microalgae by Laser Desorption/Ionization Mass Spectrometry Coupled with Multiple Nanomatrices.

    Science.gov (United States)

    Peng, Lung-Hsiang; Unnikrishnan, Binesh; Shih, Chi-Yu; Hsiung, Tung-Ming; Chang, Jeng; Hsu, Pang-Hung; Chiu, Tai-Chia; Huang, Chih-Ching

    2016-04-01

    In this study, we demonstrate a simple method to identify microalgae by surface-assisted laser desorption/ionization mass spectrometry (SALDI-MS) using three different substrates: HgSe, HgTe, and HgTeSe nanostructures. The fragmentation/ionization processes of complex molecules in algae varied according to the heat absorption and transfer efficiency of the nanostructured matrices (NMs). Therefore, the mass spectra obtained for microalgae showed different patterns of m/z values for different NMs. The spectra contained both significant and nonsignificant peaks. Constructing a Venn diagram with the significant peaks obtained for algae when using HgSe, HgTe, and HgTeSe NMs in m/z ratio range 100-1000, a unique relationship among the three sets of values was obtained. This unique relationship of sets is different for each species of microalgae. Therefore, by observing the particular relationship of sets, we successfully identified different algae such as Isochrysis galbana, Emiliania huxleyi, Thalassiosira weissflogii, Nannochloris sp., Skeletonema cf. costatum, and Tetraselmis chui. This simple and cost-effective SALDI-MS analysis method coupled with multi-nanomaterials as substrates may be extended to identify other microalgae and microorganisms in real samples. Graphical Abstract Identification of microalgae by surface-assisted laser desorption/ionization mass spectrometry coupled with three different mercury-based nanosubstrates.

  1. The Resonance Ionization Laser Ion Source RILIS - leading all-rounder of on-line ion sources

    Energy Technology Data Exchange (ETDEWEB)

    Rothe, Sebastian [CERN, Geneva (Switzerland); Institut fuer Physik, Univ. Mainz (Germany); Fedosseev, Valentin; Fink, Daniel; Seliverstov, Maxim [CERN, Geneva (Switzerland); Rossel, Ralf [CERN, Geneva (Switzerland); Institut fuer Physik, Univ. Mainz (Germany); Hochschule RheinMain, Wiesbaden (Germany); Wendt, Klaus [Institut fuer Physik, Univ. Mainz (Germany)

    2012-07-01

    The resonance ionization laser ion source (RILIS) of the on-line isotope separator facility ISOLDE at CERN, is based on the method of stepwise resonant laser excitation and ionization of atoms. The element selectivity of the RILIS complements the mass selection process of the ISOLDE separator magnets to provide high purity ion beams of many isotopes. The RILIS, which now includes two complementary and independent tunable laser systems (dye and titanium:sapphire lasers), has been significantly improved since its first demonstration of selective ionization of Yb isotopes in 1992. Today, on account of the high degree of selectivity for the 27 elements now offered, the annual operation of RILIS exceeds 2500 h, making it the most versatile and commonly used ion source at ISOLDE. The use of a narrow band dye laser enables precision in-source laser spectroscopy of isotope shifts and hyperfine structures of isotopes far from stability as well as the production of isomer pure beams as has been demonstrated for Ag, Cu, Pb, Bi, Po, and Tl. A recent upgrade of the RILIS comprises the incorporation of a complementary all solid state laser system as well as the Laser Ion Source Trap (LIST), which greatly enhances selectivity by suppressing any surface ionized isobars.

  2. Fabry-Perot observations of the ionized gas in NGC 3938

    CERN Document Server

    Jiménez-Vicente, J; Rozas, M; Castaneda, H O; Porcel, C

    1999-01-01

    The nearly face-on spiral galaxy NGC 3938 has been observed in the $H_\\alpha$ line with the TAURUS II Fabry-Perot interferometer at the William Herschel Telescope in order to study the kinematics of the ionized gas. We are able to construct intensity, velocity and velocity dispersion maps for this galaxy. The rotation curve of the galaxy is calculated up to 4.5 radial scale lengths from the galactic centre. The residual velocity field shows very small values with no systematic pattern. The mean velocity dispersion is approximately constant with radius at about 11 km/s as previously reported for the neutral and molecular gas. We have also studied the relation between intensity and velocity dispersion for the ionized gas. We have found that this distribution is compatible with a turbulent gas relaxing to a Kolmogorov type turbulence as the stationary regime. The average dispersion varies with intensity as $\\sigma which the dispersion is kept almost constant at a value of about 19 km/s.

  3. Efficient laser desorption ionization mass spectrometry of polycyclic aromatic hydrocarbons using excitation energy transfer from anthracene

    Energy Technology Data Exchange (ETDEWEB)

    Fujimori, Kensuke [Department of Chemistry, Graduate School of Science and Engineering, Tokyo Metropolitan University, 1-1 Minami-Osawa, Hachioji-shi, Tokyo 192-0397 (Japan); Fujino, Tatsuya, E-mail: fujino@tmu.ac.jp [Department of Chemistry, Graduate School of Science and Engineering, Tokyo Metropolitan University, 1-1 Minami-Osawa, Hachioji-shi, Tokyo 192-0397 (Japan)

    2013-06-20

    Highlights: ► Femtomolar detection of PAHs such as perylene and benzopyrene was achieved. ► Photoexcited anthracene molecules transferred their energy to PAHs. ► Electronically excited PAHs were then excited to be ions. ► Two-photon ionization process was necessary to complete the ionization process. ► The number of defect sites could be reduced by the annealing procedure. - Abstract: Polycyclic aromatic hydrocarbons (PAHs), such as perylene and benzopyrene, doped at amounts on the order of femtomol (∼10{sup −15} mol) in anthracene crystals could be detected by laser desorption ionization mass spectrometry. Sensitivity was roughly 10{sup 3} times higher than that of LDI method in our experimental conditions. It was revealed from the excitation power dependence of the peak intensity of PAHs on the mass spectra that two-photon excitation in one UV pulse was necessary to complete the ionization process. It was also clarified that the number of defect sites that trap excitons generated in anthracene crystals could be reduced by the annealing procedure, by which an efficient energy transfer between anthracene and PAHs became possible.

  4. Precise Calculation of Single and Double Ionization of Hydrogen Molecule in Intense Laser Pulses

    CERN Document Server

    Vafaee, Mohsen; Shokri, Babak

    2010-01-01

    In this paper, a new simulation box is introduced for two electronic systems in intense laser pulses. In this box, the region of hydrogen molecule, single ionization and second ionization are precisely recognized and time dependent of population of these regions are reported. In addition, a new regions is introduced and characterized as quasi-double ionization regions and the time dependent population of these regions are calculated and compared at different intensities. The special character of the simulation box is that it is designed in order that to assure the overall second ionization is taken to account. In this study, the dynamics of the electrons and the nuclei of hydrogen molecule are separated based on the adiabatic approximation. The time dependent Schr\\"{o}dinger and Newton equations are solved simultaneously for the electrons and the nuclei respectively. Four different intensities are used in the simulation; $ 1\\times10^{14} $, $ 5\\times10^{14} $, $ 1\\times10^{15} $ and $ 5\\times10^{15} $ W cm$^{...

  5. Atmospheric pressure ionization and gas phase ion mobility studies of isomeric dihalogenated benzenes using different ionization techniques

    Science.gov (United States)

    Borsdorf, H.; Nazarov, E. G.; Eiceman, G. A.

    2004-03-01

    Ion mobility spectrometry (IMS) featuring different ionization techniques was used to analyze isomeric ortho-, meta- and para-dihalogenated benzenes in order to assess how structural features affect ion formation and drift behavior. The structure of the product ions formed was investigated by atmospheric pressure chemical ionization (APCI) mass spectrometry (MS) and IMS-MS coupling. Photoionization provided [M]+ ions for chlorinated and fluorinated compounds while bromine was cleaved from isomers of dibromobenzene and bromofluorobenzene. This ionization technique does not permit the different isomers to be distinguished. Comparable ions and additional clustered ions were obtained using 63Ni ionization. Depending on the chemical constitution, different clustered ions were observed in ion mobility spectra for the separate isomers of dichlorobenzene and dibromobenzene. Corona discharge ionization permits the most sensitive detection of dihalogenated compounds. Only clustered product ions were obtained. Corona discharge ionization enables the classification of different structural isomers of dichlorobenzene, dibromobenzene and bromofluorobenzene.

  6. Modeling of gas ionization and plasma flow in ablative pulsed plasma thrusters

    Science.gov (United States)

    Huang, Tiankun; Wu, Zhiwen; Liu, Xiangyang; Xie, Kan; Wang, Ningfei; Cheng, Yue

    2016-12-01

    A one-dimensional model to study the gas ionization and plasma flow in ablative pulsed plasma thrusters(APPTs) is established in this paper. The discharge process of the APPT used in the LES-6 satellite is simulated to validate the model. The simulation results for the impulse bit and propellant utilization give values of 29.05 μN s and 9.56%, respectively, which are in good agreement with experimental results. To test the new ionization sub-model, the discharge process of a particular APPT, XPPT-1, is simulated, and a numerical result for the propellant utilization of 62.8% is obtained, which also agrees well with experiment. The gas ionization simulation results indicate that an APPT with a lower average propellant ablation rate and higher average electric field intensity between electrodes should have higher propellant utilization. The plasma density distribution between the electrodes of APPTs can also be obtained using the new model, and the numerical results show that the plasma generation and flow are discontinuous, which is in good agreement with past experimental results of high-speed photography. This model provides a new tool with which to study the physical mechanisms of APPTs and a reference for the design of high-performance APPTs.

  7. Gas chromatography-microchip atmospheric pressure chemical ionization-mass spectrometry.

    Science.gov (United States)

    Ostman, Pekka; Luosujärvi, Laura; Haapala, Markus; Grigoras, Kestas; Ketola, Raimo A; Kotiaho, Tapio; Franssila, Sami; Kostiainen, Risto

    2006-05-01

    An atmospheric pressure chemical ionization (APCI) microchip is presented for combining a gas chromatograph (GC) to a mass spectrometer (MS). The chip includes capillary insertion channel, stopper, vaporizer channel, nozzle and nebulizer gas inlet fabricated on the silicon wafer, and a platinum heater sputtered on a glass wafer. These two wafers are joined by anodic bonding creating a two-dimensional version of an APCI microchip. The sample from GC is directed via heated transfer line capillary to the vaporizer channel of the APCI chip. The etched nozzle forms narrow sample plume, which is ionized by an external corona discharge needle, and the ions are analyzed by a mass spectrometer. The GC-microchip APCI-MS combination provides an efficient method for qualitative and quantitative analysis. The spectra produced by microchip APCI show intensive protonated molecule and some fragmentation products as in classical chemical ionization for structure elucidation. In quantitative analysis the GC-microchip APCI-MS showed good linearity (r(2) = 0.9989) and repeatability (relative standard deviation 4.4%). The limits of detection with signal-to-noise ratio of three were between 0.5 and 2 micromol/L with MS mode using selected ion monitoring and 0.05 micromol/L with MS/MS using multiple reaction monitoring.

  8. Gas chromatography interfaced with atmospheric pressure ionization-quadrupole time-of-flight-mass spectrometry by low-temperature plasma ionization

    DEFF Research Database (Denmark)

    Norgaard, Asger W.; Kofoed-Sorensen, Vivi; Svensmark, Bo

    2013-01-01

    A low temperature plasma (LTP) ionization interface between a gas chromatograph (GC) and an atmospheric pressure inlet mass spectrometer, was constructed. This enabled time-of-flight mass spectrometric detection of GC-eluting compounds. The performance of the setup was evaluated by injection...

  9. Modeling of static and flowing-gas diode pumped alkali lasers

    Science.gov (United States)

    Barmashenko, Boris D.; Auslender, Ilya; Yacoby, Eyal; Waichman, Karol; Sadot, Oren; Rosenwaks, Salman

    2016-03-01

    Modeling of static and flowing-gas subsonic, transonic and supersonic Cs and K Ti:Sapphire and diode pumped alkali lasers (DPALs) is reported. A simple optical model applied to the static K and Cs lasers shows good agreement between the calculated and measured dependence of the laser power on the incident pump power. The model reproduces the observed threshold pump power in K DPAL which is much higher than that predicted by standard models of the DPAL. Scaling up flowing-gas DPALs to megawatt class power is studied using accurate three-dimensional computational fluid dynamics model, taking into account the effects of temperature rise and losses of alkali atoms due to ionization. Both the maximum achievable power and laser beam quality are estimated for Cs and K lasers. The performance of subsonic and, in particular, supersonic DPALs is compared with that of transonic, where supersonic nozzle and diffuser are spared and high power mechanical pump (needed for recovery of the gas total pressure which strongly drops in the diffuser), is not required for continuous closed cycle operation. For pumping by beams of the same rectangular cross section, comparison between end-pumping and transverse-pumping shows that the output power is not affected by the pump geometry, however, the intensity of the output laser beam in the case of transverse-pumped DPALs is strongly non-uniform in the laser beam cross section resulting in higher brightness and better beam quality in the far field for the end-pumping geometry where the intensity of the output beam is uniform.

  10. High performance mini-gas chromatography-flame ionization detector system based on micro gas chromatography column

    Science.gov (United States)

    Zhu, Xiaofeng; Sun, Jianhai; Ning, Zhanwu; Zhang, Yanni; Liu, Jinhua

    2016-04-01

    Monitoring Volatile organic compounds (VOCs) was a very important measure for preventing environmental pollution, therefore, a mini gas chromatography (GC) flame ionization detector (FID) system integrated with a mini H2 generator and a micro GC column was developed for environmental VOC monitoring. In addition, the mini H2 generator was able to make the system explode from far away due to the abandoned use of a high pressure H2 source. The experimental result indicates that the fabricated mini GC FID system demonstrated high repeatability and very good linear response, and was able to rapidly monitor complicated environmental VOC samples.

  11. Quantum dots assisted laser desorption/ionization mass spectrometric detection of carbohydrates: qualitative and quantitative analysis.

    Science.gov (United States)

    Bibi, Aisha; Ju, Huangxian

    2016-04-01

    A quantum dots (QDs) assisted laser desorption/ionization mass spectrometric (QDA-LDI-MS) strategy was proposed for qualitative and quantitative analysis of a series of carbohydrates. The adsorption of carbohydrates on the modified surface of different QDs as the matrices depended mainly on the formation of hydrogen bonding, which led to higher MS intensity than those with conventional organic matrix. The effects of QDs concentration and sample preparation method were explored for improving the selective ionization process and the detection sensitivity. The proposed approach offered a new dimension to the application of QDs as matrices for MALDI-MS research of carbohydrates. It could be used for quantitative measurement of glucose concentration in human serum with good performance. The QDs served as a matrix showed the advantages of low background, higher sensitivity, convenient sample preparation and excellent stability under vacuum. The QDs assisted LDI-MS approach has promising application to the analysis of carbohydrates in complex biological samples.

  12. Laser-controlled dissociation and ionization pathways in electronically excited AsH3

    Science.gov (United States)

    Koplitz, B.; Xu, Z.; Wittig, C.

    1988-03-01

    Experiments involving 193 nm AsH3 excitation are described. With ≥25 ns delay between the firing of photolysis and probe lasers, product H atoms are detected by two-frequency, two-photon ionization (121.6 nm+364.7 nm) via Lyman-α. However, temporally overlapping the photolysis and ``probe'' beams enables ionization to complete with dissociation. The resulting AsH+x signal displays a marked dependence on the near-UV frequency, and AsH+x peaks are accompanied by dips in the H-atom signal. Delay and near-UV frequency control the competition between the different pathways, and the overall effect is both easily induced and macroscopic. Applications may be found in the photoassisted growth of semiconductor materials.

  13. Laser-enhanced ionization detection of trace copper in high salt matrices.

    Science.gov (United States)

    Havrilla, G J; Carter, C C

    1987-09-01

    Laser-enhanced ionization (LEI) is used to determine trace levels of metals in high salt matrices, an analysis that is difficult by conventional methods. Copper is presented in detail to demonstrate the capability of the method. Three-dimensional spectra of the stepwise excitation of copper are presented which illustrate the one photon, stepwise, and two-photon transitions. Seven copper transitions have been studied for analytical utility, and detection limits have been determined for each. Ionization interferences were accommodated by both matrix matching and separation of the interferences using ion exchange resin. Absolute determinations at the 0.05-ng level are possible with the use of a Teflon microsampling cup for low volume quantitative analysis. In addition to copper, silver, cobalt, iron, and nickel have been detected within the same dye tuning range. Twelve new LEI transitions have been identified for these elements along with detection limits.

  14. Nanoscale Electron Bunching in Laser-Triggered Ionization Injection in Plasma Accelerators

    Science.gov (United States)

    Xu, X. L.; Pai, C.-H.; Zhang, C. J.; Li, F.; Wan, Y.; Wu, Y. P.; Hua, J. F.; Lu, W.; An, W.; Yu, P.; Joshi, C.; Mori, W. B.

    2016-07-01

    Ionization injection is attractive as a controllable injection scheme for generating high quality electron beams using plasma-based wakefield acceleration. Because of the phase-dependent tunneling ionization rate and the trapping dynamics within a nonlinear wake, the discrete injection of electrons within the wake is nonlinearly mapped to a discrete final phase space structure of the beam at the location where the electrons are trapped. This phenomenon is theoretically analyzed and examined by three-dimensional particle-in-cell simulations which show that three-dimensional effects limit the wave number of the modulation to between >2 k0 and about 5 k0, where k0 is the wave number of the injection laser. Such a nanoscale bunched beam can be diagnosed by and used to generate coherent transition radiation and may find use in generating high-power ultraviolet radiation upon passage through a resonant undulator.

  15. The Wigner time delay for laser induced tunnel-ionization via the electron propagator

    CERN Document Server

    Yakaboylu, Enderalp; Hatsagortsyan, Karen Z

    2014-01-01

    Recent attoclock experiments using the attsecond angular streaking technique enabled the measurement of the tunneling time delay during laser induced strong field ionization. Theoretically the tunneling time delay is commonly modelled by the Wigner time delay concept which is derived from the derivative of the electron wave function phase with respect to energy. Here, we present an alternative method for the calculation of the Wigner time delay by using the fixed energy propagator. The developed formalism is applied to the nonrelativistic as well as to the relativistic regime of the tunnel-ionization process from a zero-range potential, where in the latter regime the propagator can be given by means of the proper-time method.

  16. Nano-scale electron bunching in laser-triggered ionization injection in plasma accelerators

    CERN Document Server

    Xu, X L; Li, F; Wan, Y; Wu, Y P; Hua, J F; Pai, C -H; Lu, W; An, W; Yu, P; Mori, W B; Joshi, C

    2015-01-01

    Ionization injection is attractive as a controllable injection scheme for generating high quality electron beams using plasma-based wakefield acceleration. Due to the phase dependent tunneling ionization rate and the trapping dynamics within a nonlinear wake, the discrete injection of electrons within the wake is nonlinearly mapped to discrete final phase space structure of the beam at the location where the electrons are trapped. This phenomenon is theoretically analyzed and examined by three-dimensional particle-in-cell simulations which show that three dimensional effects limit the wave number of the modulation to between $> 2k_0$ and about $5k_0$, where $k_0$ is the wavenumber of the injection laser. Such a nano-scale bunched beam can be diagnosed through coherent transition radiation upon its exit from the plasma and may find use in generating high-power ultraviolet radiation upon passage through a resonant undulator.

  17. A huge reservoir of ionized gas around the Milky Way: Accounting for the Missing Mass?

    CERN Document Server

    Gupta, A; Krongold, Y; Nicastro, F; Galeazzi, M

    2012-01-01

    Most of the baryons from galaxies have been "missing" and several studies have attempted to map the circumgalactic medium (CGM) of galaxies in their quest. Recent studies with the Hubble Space Telescope have shown that many galaxies contain a large reservoir of ionized gas with temperatures of about 10^5 K. Here we report on X-ray observations made with the Chandra X-ray Observatory probing an even hotter phase of the CGM of our Milky Way at about 10^6 K. We show that this phase of the CGM is massive, extending over a large region around the Milky Way, with a radius of over 100 kpc. The mass content of this phase is over ten billion solar masses, many times more than that in cooler gas phases and comparable to the total baryonic mass in the disk of the Galaxy. The missing mass of the Galaxy appears to be in this warm-hot gas phase.

  18. Imaging spectrophotometry of ionized gas in NGC 1068. I - Kinematics of the narrow-line region

    Science.gov (United States)

    Cecil, Gerald; Bland, Jonathan; Tully, R. Brent

    1990-01-01

    The kinematics of collisionally excited forbidden N II 6548, 6583 across the inner 1 arcmin diameter of the nearby Seyfert galaxy NGC 1068 is mapped using an imaging Fabry-Perot interferometer and low-noise CCD. The stack of monochromatic images, which spatially resolved the high-velocity gas, was analyzed for kinematic and photometric content. Profiles agree well with previous long-slit work, and their complete spatial coverage makes it possible to constrain the gas volume distribution. It is found that the narrow-line region is distributed in a thick center-darkened, line-emitting cylinder that envelopes the collimated radio jet. Three distinct kinematic subsystems, of which the cylinder is composed, are discussed in detail. Detailed behavior of the emission-line profiles, at the few points in the NE quadrant with simple kinematics, argues that the ionized gas develops a significant component of motion perpendicular to the jet axis.

  19. Gas Chromatography/Atmospheric Pressure Chemical Ionization Tandem Mass Spectrometry for Fingerprinting the Macondo Oil Spill.

    Science.gov (United States)

    Lobodin, Vladislav V; Maksimova, Ekaterina V; Rodgers, Ryan P

    2016-07-05

    We report the first application of a new mass spectrometry technique (gas chromatography combined to atmospheric pressure chemical ionization tandem mass spectrometry, GC/APCI-MS/MS) for fingerprinting a crude oil and environmental samples from the largest accidental marine oil spill in history (the Macondo oil spill, the Gulf of Mexico, 2010). The fingerprinting of the oil spill is based on a trace analysis of petroleum biomarkers (steranes, diasteranes, and pentacyclic triterpanes) naturally occurring in crude oil. GC/APCI enables soft ionization of petroleum compounds that form abundant molecular ions without (or little) fragmentation. The ability to operate the instrument simultaneously in several tandem mass spectrometry (MS/MS) modes (e.g., full scan, product ion scan, reaction monitoring) significantly improves structural information content and sensitivity of analysis. For fingerprinting the oil spill, we constructed diagrams and conducted correlation studies that measure the similarity between environmental samples and enable us to differentiate the Macondo oil spill from other sources.

  20. Fully Automated Laser Ablation Liquid Capture Sample Analysis using NanoElectrospray Ionization Mass Spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Lorenz, Matthias [ORNL; Ovchinnikova, Olga S [ORNL; Van Berkel, Gary J [ORNL

    2014-01-01

    RATIONALE: Laser ablation provides for the possibility of sampling a large variety of surfaces with high spatial resolution. This type of sampling when employed in conjunction with liquid capture followed by nanoelectrospray ionization provides the opportunity for sensitive and prolonged interrogation of samples by mass spectrometry as well as the ability to analyze surfaces not amenable to direct liquid extraction. METHODS: A fully automated, reflection geometry, laser ablation liquid capture spot sampling system was achieved by incorporating appropriate laser fiber optics and a focusing lens into a commercially available, liquid extraction surface analysis (LESA ) ready Advion TriVersa NanoMate system. RESULTS: Under optimized conditions about 10% of laser ablated material could be captured in a droplet positioned vertically over the ablation region using the NanoMate robot controlled pipette. The sampling spot size area with this laser ablation liquid capture surface analysis (LA/LCSA) mode of operation (typically about 120 m x 160 m) was approximately 50 times smaller than that achievable by direct liquid extraction using LESA (ca. 1 mm diameter liquid extraction spot). The set-up was successfully applied for the analysis of ink on glass and paper as well as the endogenous components in Alstroemeria Yellow King flower petals. In a second mode of operation with a comparable sampling spot size, termed laser ablation/LESA , the laser system was used to drill through, penetrate, or otherwise expose material beneath a solvent resistant surface. Once drilled, LESA was effective in sampling soluble material exposed at that location on the surface. CONCLUSIONS: Incorporating the capability for different laser ablation liquid capture spot sampling modes of operation into a LESA ready Advion TriVersa NanoMate enhanced the spot sampling spatial resolution of this device and broadened the surface types amenable to analysis to include absorbent and solvent resistant

  1. Gas-self-filter-based erbium-doped fiber loop laser for gas detection.

    Science.gov (United States)

    Guo, Kaikai; Lou, Xiutao; Yan, Chunsheng; Mei, Liang

    2014-08-01

    An erbium-doped fiber (EDF) loop laser, based on a gas-self-filter (GSF), is developed with single or multiple wavelength emission. The GSF is a type of Mach-Zehnder interferometer with a gas cell in one arm. By matching the destructive wavelength of the interferometer with the gas absorption line, the self-filtering function is achieved. A GSF-based multi-wavelength laser with a side-mode suppression ratio of ~50  dB is performed. As an example, C₂H₂ gas is detected using a single-wavelength GSF-based laser with correlation spectroscopy, and a good linearity of the measurement is obtained. The present laser has the potential advantage for multiple gas detection, e.g., being free of wavelength calibration.

  2. omniSpect: an open MATLAB-based tool for visualization and analysis of matrix-assisted laser desorption/ionization and desorption electrospray ionization mass spectrometry images.

    Science.gov (United States)

    Parry, R Mitchell; Galhena, Asiri S; Gamage, Chaminda M; Bennett, Rachel V; Wang, May D; Fernández, Facundo M

    2013-04-01

    We present omniSpect, an open source web- and MATLAB-based software tool for both desorption electrospray ionization (DESI) and matrix-assisted laser desorption ionization (MALDI) mass spectrometry imaging (MSI) that performs computationally intensive functions on a remote server. These functions include converting data from a variety of file formats into a common format easily manipulated in MATLAB, transforming time-series mass spectra into mass spectrometry images based on a probe spatial raster path, and multivariate analysis. OmniSpect provides an extensible suite of tools to meet the computational requirements needed for visualizing open and proprietary format MSI data.

  3. SIMULATION OF THE LASER DISCHARGE IN A SUPERSONIC GAS FLOW

    Directory of Open Access Journals (Sweden)

    Tropina, A. A.

    2013-06-01

    Full Text Available A heat model of the laser discharge in a supersonic turbulent gas flow has been developed. A numerical investigation of the error of the method of velocity measurements, which is based on the nitrogen molecules excitation, has been carried out. It is shown that fast gas heating by the discharge causes the velocity profiles deformation.

  4. A DC excited waveguide multibeam CO2 laser using high frequency pre-ionization technique

    Indian Academy of Sciences (India)

    S V Deshmukh; C Rajagopalan

    2003-12-01

    High power industrial multibeam CO2 lasers consist of a large number of closely packed parallel glass discharge tubes sharing a common plane parallel resonator. Every discharge tube forms an independent resonator. When discharge tubes of smaller diameter are used and the Fresnel number $ \\ll 1$ for all resonators, they operate in waveguide mode. Waveguide modes have excellent discrimination of higher order modes. A DC excited waveguide multibeam CO2 laser is reported having six glass discharge tubes. Simultaneous excitation of DC discharge in all sections is achieved by producing pre-ionization using an auxiliary high frequency pulsed discharge along with its other advantages. Maximum 170 W output power is obtained with all beams operating in EH11 waveguide mode. The specific power of 28 W/m is much higher as compared to similar AC excited waveguide multibeam CO2 lasers. Theoretical analysis shows that all resonators of this laser will support only EH11 mode. This laser is successfully used for woodcutting.

  5. Laser Induced Fluorescence Spectroscopy of Neutral and Ionized Polycyclic Aromatic Hydrocarbons in a Cosmic Simulation Chamber

    Science.gov (United States)

    Bejaoui, Salma; Salama, Farid

    2015-08-01

    Polycyclic aromatic hydrocarbon (PAH) molecules are considered the best carriers to account for the ubiquitous infrared emission bands. PAHs have also been proposed as candidates to explain the diffuse interstellar bands (DIBs), a series of absorption features seen on the interstellar extinction curve and are plausible carriers for the extended red emission (ERE), a photoluminescent process associated with a wide variety of interstellar environments. Extensive efforts have been devoted over the past two decades to characterize the physical and chemical properties of PAH molecules and ions in space. Absorption spectra of PAH molecules and ions trapped in solid matrices have been compared to the DIBs [1, 2]. Absorption spectra of several cold, isolated gas-phase PAHs have also been measured under experimental conditions that mimic the interstellar conditions [see 3 for a review]. The purpose of this study is to provide a new dimension to the existing spectroscopic database of neutral and single ionized PAHs that is largely based on absorption spectra by adding emission spectroscopy data. The measurements are based on the laser-induced fluorescence (LIF) technique [4] and are performed with the Pulsed Discharge Nozzle (PDN) of the COSmIC laboratory facility at NASA Ames laboratory. The PDN generates plasma in a free supersonic jet expansion to simulate the physical and the chemical conditions in interstellar environments. We focus, here, on the fluorescence spectra of large neutral PAHs and their cations where there is a lack of fluorescence spectroscopy data. The astronomical implications of the data (e.g., ERE) are examinedReferences[1] F. Salama, E. Bakes, L.J. Allamandola, A.G.G.M. Tielens, Astrophys. J., 458 (1996) p.621[2] F. Salama, The ISO Revolution, EDP Sciences, Les Ulis, France (1999) p.65[3] Salama F., In Organic Matter in Space, IAU Symposium 251, Kwok & Sandford Eds.Cambridge University Press,4, S251,(2008), p. 357 (2008) and references therein.[4

  6. "Magic" Ionization Mass Spectrometry

    Science.gov (United States)

    Trimpin, Sarah

    2016-01-01

    The systematic study of the temperature and pressure dependence of matrix-assisted ionization (MAI) led us to the discovery of the seemingly impossible, initially explained by some reviewers as either sleight of hand or the misinterpretation by an overzealous young scientist of results reported many years before and having little utility. The "magic" that we were attempting to report was that with matrix assistance, molecules, at least as large as bovine serum albumin (66 kDa), are lifted into the gas phase as multiply charged ions simply by exposure of the matrix:analyte sample to the vacuum of a mass spectrometer. Applied heat, a laser, or voltages are not necessary to achieve charge states and ion abundances only previously observed with electrospray ionization (ESI). The fundamentals of how solid phase volatile or nonvolatile compounds are converted to gas-phase ions without added energy currently involves speculation providing a great opportunity to rethink mechanistic understanding of ionization processes used in mass spectrometry. Improved understanding of the mechanism(s) of these processes and their connection to ESI and matrix-assisted laser desorption/ionization may provide opportunities to further develop new ionization strategies for traditional and yet unforeseen applications of mass spectrometry. This Critical Insights article covers developments leading to the discovery of a seemingly magic ionization process that is simple to use, fast, sensitive, robust, and can be directly applied to surface characterization using portable or high performance mass spectrometers.

  7. Cosmetic Analysis Using Matrix-Assisted Laser Desorption/Ionization Mass Spectrometry Imaging (MALDI-MSI

    Directory of Open Access Journals (Sweden)

    Rodrigo Ramos Catharino

    2013-03-01

    Full Text Available A new “omic” platform—Cosmetomics—that proves to be extremely simple and effective in terms of sample preparation and readiness for data acquisition/interpretation is presented. This novel approach employing Matrix-Assisted Laser Desorption/Ionization Mass Spectrometry Imaging (MALDI-MSI for cosmetic analysis has proven to readily identify and quantify compounds of interest. It also allows full control of all the production phases, as well as of the final product, by integration of both analytical and statistical data. This work has focused on products of daily use, namely nail polish, lipsticks and eyeliners of multiple brands sold in the worldwide market.

  8. Measurement of Chiral Recognition Properties of Crown Ethers Using Matrix Assisted Laser Desorption Ionization Mass Spectrometry

    OpenAIRE

    SAWADA, Masami; Harada, Manabu; TAKAI, Yoshio; NAKANO, Kazurou; Kuroda, Masao; ARAKAWA, Ryuichi; 荒川, 隆一

    2000-01-01

    Hydrogen bonding host-guest complex ions between chiral crown ethers and chiral amino acid ester salts, detected by matrix assisted laser desorption ionization (MALDI) mass spectrometry (MS) with a DHBA or MSA matrix, were studied on the view point of chiral recognition properties of the chiral crown hosts. The chiral recognition property (IR/IS-dn value≅1.0) obtained by the present MALDI-MS is sharply different from the IR/IS-dn value obtained by FAB-MS or ESI-MS (≠1.0) in the same host-gues...

  9. DYNAMO II: Coupled Stellar and Ionized Gas Kinematics in Two Low Redshift Clumpy Disks

    CERN Document Server

    Bassett, Robert; Fisher, David B; Green, Andrew W; Wisnioski, Emily; Obreschkow, Danail; Cooper, Erin Mentuch; Abraham, Roberto G; Damjanov, Ivana; McGregor, Peter J

    2014-01-01

    We study the spatially resolved stellar kinematics of two star-forming galaxies at z = 0.1 from the larger DYnamics of Newly Assembled Massive Objects (DYNAMO) sample. These galaxies, which have been characterized by high levels of star formation and large ionized gas velocity dispersions, are considered possible analogs to high-redshift clumpy disks. They were observed using the GMOS instrument in integral field spectroscopy (IFS) mode at the Gemini Observatory with high spectral resolution (R=5400, equivalent to 24 km/s at the observed wavelengths) and 6 hour exposure times in order to measure the resolved stellar kinematics via absorption lines. We also obtain higher-quality emission line kinematics than previous observations. The spatial resolution (1.2 kpc) is sufficient to show that the ionized gas in these galaxies (as traced by H-beta emission) is morphologically irregular, forming multiple giant clumps while stellar continuum light is smooth and well described by an exponential profile. Clumpy gas mo...

  10. Determination of polycyclic aromatic hydrocarbons and their nitro-, amino-derivatives absorbed on particulate matter 2.5 by multiphoton ionization mass spectrometry using far-, deep-, and near-ultraviolet femtosecond lasers.

    Science.gov (United States)

    Tang, Yuanyuan; Imasaka, Tomoko; Yamamoto, Shigekazu; Imasaka, Totaro

    2016-06-01

    Multiphoton ionization processes of parent-polycyclic aromatic hydrocarbons (PPAHs), nitro-PAHs (NPAHs), and amino-PAHs (APAHs) were examined by gas chromatography combined with time-of-flight mass spectrometry using a femtosecond Ti:sapphire laser as the ionization source. The efficiency of multiphoton ionization was examined using lasers emitting in the far-ultraviolet (200 nm), deep-ultraviolet (267 nm), and near-ultraviolet (345 nm) regions. The largest signal intensities were obtained when the far-ultraviolet laser was employed. This favorable result can be attributed to the fact that these compounds have the largest molar absorptivities in the far-ultraviolet region. On the other hand, APAHs were ionized more efficiently than NPAHs in the near-ultraviolet region because of their low ionization energies. A sample extracted from a real particulate matter 2.5 (PM2.5) sample was measured, and numerous signal peaks arising from PAH and its analogs were observed at 200 nm. On the other hand, only a limited number of signed peaks were observed at 345 nm, some of which were signed to PPAHs, NPAHs, and APAHs. Thus, multiphoton ionization mass spectrometry has potential for the use in comprehensive analysis of toxic environmental pollutants. Copyright © 2016 Elsevier Ltd. All rights reserved.

  11. Preparation of the spacer for narrow electrode gap configuration in ionization-based gas sensor

    Energy Technology Data Exchange (ETDEWEB)

    Saheed, Mohamed Shuaib Mohamed; Mohamed, Norani Muti; Burhanudin, Zainal Arif [Electrical and Electronic Engineering, Universiti Teknologi PETRONAS, Seri Iskandar, Tronoh, Perak. (Malaysia); Fundamental and Applied Science, Universiti Teknologi PETRONAS, Seri Iskandar, Tronoh, Perak. (Malaysia); Electrical and Electronic Engineering, Universiti Teknologi PETRONAS, Seri Iskandar, Tronoh, Perak. (Malaysia)

    2012-09-26

    Carbon nanotubes (CNTs) have started to be developed as the sensing element for ionization-based gas sensors due to the demand for improved sensitivity, selectivity, stability and other sensing properties beyond what can be offered by the conventional ones. Although these limitations have been overcome, the problems still remain with the conventional ionization-based gas sensors in that they are bulky and operating with large breakdown voltage and high temperature. Recent studies have shown that the breakdown voltage can be reduced by using nanostructured electrodes and narrow electrode gap. Nanostructured electrode in the form of aligned CNTs array with evenly distributed nanotips can enhance the linear electric field significantly. The later is attributed to the shorter conductivity path through narrow electrode gap. The paper presents the study on the design consideration in order to realize ionization based gas sensor using aligned carbon nanotubes array in an optimum sensor configuration with narrow electrode gap. Several deposition techniques were studied to deposit the spacer, the key component that can control the electrode gap. Plasma spray deposition, electron beam deposition and dry oxidation method were employed to obtain minimum film thickness around 32 {mu}m. For plasma spray method, sand blasting process is required in order to produce rough surface for strong bonding of the deposited film onto the surface. Film thickness, typically about 39 {mu}m can be obtained. For the electron beam deposition and dry oxidation, the film thickness is in the range of nanometers and thus unsuitable to produce the spacer. The deposited multilayer film consisting of copper, alumina and ferum on which CNTs array will be grown was found to be removed during the etching process. This is attributed to the high etching rate on the thin film which can be prevented by reducing the rate and having a thicker conductive copper film.

  12. Planar Laser-Based QEPAS Trace Gas Sensor

    Directory of Open Access Journals (Sweden)

    Yufei Ma

    2016-06-01

    Full Text Available A novel quartz enhanced photoacoustic spectroscopy (QEPAS trace gas detection scheme is reported in this paper. A cylindrical lens was employed for near-infrared laser focusing. The laser beam was shaped as a planar line laser between the gap of the quartz tuning fork (QTF prongs. Compared with a spherical lens-based QEPAS sensor, the cylindrical lens-based QEPAS sensor has the advantages of easier laser beam alignment and a reduction of stringent stability requirements. Therefore, the reported approach is useful in long-term and continuous sensor operation.

  13. The electrical simulation of a gas discharge excited copper laser

    Science.gov (United States)

    Buckley, J. M.; Maitland, Arthur

    1992-12-01

    A circuit model of a gas laser discharge for use with simulator packages such as SPICE to describe the behavior of the combined circuit representing a copper vapor laser with its modulator drive is presented. The laser tube and discharge combination is treated as a transmission line with time-varying impedance elements for which the time variation is achieved by the introduction of controlled voltage and current sources. Theoretical and experimental results are compared. The model is used on a day-to-day basis to assist in interpreting the circuit behavior of laboratory lasers during their operation in order to reduce stress on the power switch (thyratron) and other components.

  14. Self-detection of x-ray Fresnel transmissivity using photoelectron-induced gas ionization

    OpenAIRE

    Stoupin, Stanislav

    2015-01-01

    Electric response of an x-ray mirror enclosed in a gas flow ionization chamber was studied under the conditions of total external reflection for hard x-rays. It is shown that the electric response of the system as a function of the incidence angle is defined by x-ray Fresnel transmissivity and photon-electron attenuation properties of the mirror material. A simple interpretation of quantum yield of the system is presented. The approach could serve as a basis for non-invasive in-situ diagnosti...

  15. Investigation of thin ZnO layers in view of laser desorption-ionization

    Energy Technology Data Exchange (ETDEWEB)

    Grechnikov, A A; Borodkov, A S [Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences, 19 Kosygin Str., 119991 Moscow (Russian Federation); Georgieva, V B [Georgi Nadjakov Institute of Solid State Physics, Bulgarian Academy of Sciences, 72 Tzarigradsko Chaussee, 1784 Sofia (Bulgaria); Alimpiev, S S; Nikiforov, S M; Simanovsky, Ya O [General Physics Institute, Russian Academy of Sciences, 38 Vavilov Str., 119991 Moscow (Russian Federation); Dimova-Malinovska, D; Angelov, O I, E-mail: lazarova@issp.bas.b [Laboratory for Solar Energy and New Energy Sources, Bulgarian Academy of Sciences, 72 Tzarigradsko Chaussee, 1784 Sofia (Bulgaria)

    2010-04-01

    Thin zinc oxide films (ZnO) were developed as a matrix-free platform for surface assisted laser desorption-ionization (SALDI) time-of-flight mass spectrometry. The ZnO films were deposited by RF magnetron sputtering of ZnO ceramic targets in Ar atmospheres on monocrystalline silicon. The generation under UV (355 nm) laser irradiation of positive ions of atenolol, reserpine and gramicidin S from the ZnO layers deposited was studied. All analytes tested were detected as protonated molecules with no or very structure-specific fragmentation. The mass spectra obtained showed low levels of chemical background noise. All ZnO films studied exhibited high stability and good reproducibility. The detection limits for test analytes are in the 10 femtomol range.

  16. Intra- and intercycle interference of electron emission in laser assisted XUV atomic ionization

    CERN Document Server

    Gramajo, Ana Alicia; Garibotti, Carlos Roberto; Arbó, Diego

    2016-01-01

    We study the ionization of atomic hydrogen in the direction of polarization due to a linearly polarized XUV pulse in the presence a strong field IR. We describe the photoelectron spectra as an interference problem in the time domain. Electron trajectories steming from different optical laser cycles give rise to intercycle interference energy peaks known as sidebands. These sidebands are modulated by a grosser structure coming from the intracycle interference of the two electron trajectories born during the same optical cycle. We make use of a simple semiclassical model which offers the possibility to establish a connection between emission times and the photoelectron kinetic energy. We compare the semiclassical predictions with the continuum-distorted wave strong field approximation and the ab initio solution of the time dependent Schr\\"odinger equation. We analyze such interference pattern as a function of the time delay between the IR and XUV pulse and also as a function of the laser intensity.

  17. Relativistic electronic dressing in laser-assisted ionization of atomic hydrogen by electron impact

    CERN Document Server

    Attaourti, Y

    2004-01-01

    Within the framework of the coplanar binary geometry where it is justified to use plane wave solutions for the study of the $(e,2e)$ reaction and in the presence of a circularly polarized laser field, we introduce as a first step the DVRPWBA1 (Dirac-Volkov Plane Wave Born Approximation1) where we take into account only the relativistic dressing of the incident and scattered electrons. Then, we introduce the DVRPWBA2 (Dirac-Volkov Plane Wave Born Approximation2) where we take totally into account the relativistic dressing of the incident, scattered and ejected electrons. We then compare the corresponding triple differential cross sections for laser-assisted ionization of atomic hydrogen by electron impact both for the non relativistic and the relativistic regime.

  18. Determination of iodine in oyster tissue by isotope dilution laser resonance ionization mass spectrometry.

    Science.gov (United States)

    Fassett, J D; Murphy, T J

    1990-02-15

    The technique of laser resonance ionization mass spectrometry has been combined with isotope dilution analysis to determine iodine in oyster tissue. The long-lived radioisotope, 129I, was used to spike the samples. Samples were equilibrated with the 129I, wet ashed under controlled conditions, and iodine separated by coprecipitation with silver chloride. The analyte was dried as silver ammonium iodide upon a tantalum filament from which iodine was thermally desorbed in the resonance ionization mass spectrometry instrument. A single-color, two-photon resonant plus one-photon ionization scheme was used to form positive iodine ions. Long-lived iodine signals were achieved from 100 ng of iodine. The precision of 127I/129I measurement has been evaluated by replicate determinations of the spike, the spike calibration samples, and the oyster tissue samples and was 1.0%. Measurement precision among samples was 1.9% for the spike calibration and 1.4% for the oyster tissue. The concentration of iodine determined in SRM 1566a, Oyster Tissue, was 4.44 micrograms/g with an estimate of the overall uncertainty for the analysis of +/- 0.12 microgram/g.

  19. Determination of nitrogen monoxide in high purity nitrogen gas with an atmospheric pressure ionization mass spectrometer

    Science.gov (United States)

    Kato, K.

    1985-01-01

    An atmospheric pressure ionization mass spectrometric (API-MS) method was studied for the determination of residual NO in high purity N2 gas. The API-MS is very sensitive to NO, but the presence of O2 interferes with the NO measurement. Nitrogen gas in cylinders as sample gas was mixed with NO standard gas and/or O2 standard gas, and then introduced into the API-MS. The calibration curves of NO and O2 has linearity in the region of 0 - 2 ppm, but the slopes changed with every cylinder. The effect of O2 on NO+ peak was additive and proportional to O2 concentration in the range of 0 - 0.5 ppm. The increase in NO+ intensity due to O2 was (0.07 - 0.13)%/O2, 1 ppm. Determination of NO and O2 was carried out by the standard addition method to eliminate the influence of variation of slopes. The interference due to O2 was estimated from the product of the O2 concentration and the ratio of slope A to Slope B. Slope A is the change in the NO+ intensity with the O2 concentration. Slope B is the intensity with O2 concentration.

  20. Overview literature on matrix assisted laser desorption ionization mass spectroscopy (MALDI MS): basics and its applications in characterizing polymeric materials

    Indian Academy of Sciences (India)

    R N Jagtap; A H Ambre

    2005-10-01

    Matrix assisted laser desorption ionization mass spectroscopy (MALDI MS) is a technique which allows the measurement of molecular mass > 200,000 Daltons by ionization and vapourization without degradation. This technique is useful for the mass analysis of synthetic polymers, which have very low volatility. The basic principles of and its applications for polymer characterization have been discussed in this paper. In addition, the possibilities of combining MALDI MS with chromatographic and other analytical techniques have also been discussed.

  1. Ionized gas outflows and global kinematics of low-z luminous star-forming galaxies

    Science.gov (United States)

    Arribas, S.; Colina, L.; Bellocchi, E.; Maiolino, R.; Villar-Martín, M.

    2014-08-01

    We study the kinematic properties of the ionised gas outflows and ambient interstellar medium (ISM) in a large and representative sample of local luminous and ultra-luminous infrared galaxies (U/LIRGs) (58 systems, 75 galaxies) at galactic and sub-galactic (i.e., star-forming clumps) scales, thanks to integral field spectroscopy (IFS)-based high signal-to-noise integrated spectra. The velocity dispersion of the ionized ISM in U/LIRGs (⟨ σ ⟩ ~ 70 km s-1) is larger than in lower luminosity local star-forming galaxies (⟨ σ ⟩ ~ 25 km s-1). While for isolated disc LIRGs star formation appears to sustain turbulence, gravitational energy release associated with interactions and mergers plays an important role in driving σ in the U/LIRG range. We find that σ has a dependency on the star formation rate density (ΣSFR), which is weaker than expected if it were driven by the energy released by the starburst. The relatively small role of star formation (SF) driving the σ in U/LIRGs is reinforced by the lack of an increase in σ associated with high luminosity SF clumps. We also find that the impact of an active galactic nucleus (AGN) in ULIRGs is strong, increasing on average σ by a factor 1.5. Low-z U/LIRGs cover a range of velocity dispersion (σ ~ 30 to 100 km s-1) and star formation rate density (ΣSFR ~ 0.1 to 20 M⊙ yr-1 kpc-2) similar to those of high-z SFGs. Moreover, the observed weak dependency of σ on ΣSFR for local U/LIRGs (σ ∝ ΣSFR+0.06) is in very good agreement with that measured in some high-z samples. The presence of ionized gas outflows in U/LIRGs seems universal based on the detection of a broad, usually blueshifted, Hα line. The observed dependency of the maximum velocity of the outflow (Vmax) on the star formation rate (SFR) is of the type Vmax(non - AGN) ∝ SFR(LIR)+ 0.24. We find that AGNs in U/LIRGs are able to generate faster (~×2) and more massive (~× 1.4) ionized gas outflows than pure starbursts. The derived ionized mass

  2. Highly ionized gas on galaxy scales: mapping the interacting Seyfert galaxy LEDA 135736

    CERN Document Server

    Gerssen, J; Christensen, L; Bower, R G; Wild, V

    2008-01-01

    We have used the VIMOS IFU to map the properties of the Seyfert 1.9 galaxy LEDA 135736. These maps reveal a number of interesting features including: an Extended Narrow Line Region detectable out to 9 kpc, an area of intense star formation located at a projected distance of 12 kpc from the centre, an elliptical companion galaxy, and kinematic features, aligned along the long-axis of the ENLR, that are consistent with radio jet-driven mass outflow. We propose that the ENLR results from extra-planar gas ionized by the AGN, and that the AGN in turn might be triggered by interaction with the companion galaxy, which can also explain the burst of star formation and morphological features. Only about two percent of the ENLR's kinetic energy is in the mass outflow. We infer from this that the bulk of mechanical energy imparted by the jet is used to heat this gas.

  3. Dynamic self-organization phenomena in complex ionized gas systems: new paradigms and technological aspects

    Science.gov (United States)

    Vladimirov, S. V.; Ostrikov, K.

    2004-04-01

    An overview of dynamic self-organization phenomena in complex ionized gas systems, associated physical phenomena, and industrial applications is presented. The most recent experimental, theoretical, and modeling efforts to understand the growth mechanisms and dynamics of nano- and micron-sized particles, as well as the unique properties of the plasma-particle systems (colloidal, or complex plasmas) and the associated physical phenomena are reviewed and the major technological applications of micro- and nanoparticles are discussed. Until recently, such particles were considered mostly as a potential hazard for the microelectronic manufacturing and significant efforts were applied to remove them from the processing volume or suppress the gas-phase coagulation. Nowadays, fine clusters and particulates find numerous challenging applications in fundamental science as well as in nanotechnology and other leading high-tech industries.

  4. A sensitive gas chromatography detector based on atmospheric pressure chemical ionization by a dielectric barrier discharge.

    Science.gov (United States)

    Kirk, Ansgar T; Last, Torben; Zimmermann, Stefan

    2017-02-03

    In this work, we present a novel concept for a gas chromatography detector utilizing an atmospheric pressure chemical ionization which is initialized by a dielectric barrier discharge. In general, such a detector can be simple and low-cost, while achieving extremely good limits of detection. However, it is non-selective apart from the use of chemical dopants. Here, a demonstrator manufactured entirely from fused silica capillaries and printed circuit boards is shown. It has a size of 75×60×25mm(3) and utilizes only 2W of power in total. Unlike other known discharge detectors, which require high-purity helium, this detector can theoretically be operated using any gas able to form stable ion species. Here, purified air is used. With this setup, limits of detection in the low parts-per-billion range have been obtained for acetone.

  5. Even-parity Rydberg and autoionizing states of lutetium by laser resonance-ionization spectroscopy

    Science.gov (United States)

    Li, R.; Lassen, J.; Zhong, Z. P.; Jia, F. D.; Mostamand, M.; Li, X. K.; Reich, B. B.; Teigelhöfer, A.; Yan, H.

    2017-05-01

    Multistep laser resonance ionization spectroscopy of lutetium (Lu) has been performed at TRIUMF's off-line laser ion source test stand. The even-parity Rydberg series 6 s2n d 2D3 /2 , 6 s2n d 2D5 /2 , and 6 s2n s 2S1 /2 were observed converging to the 6 s2 ionization potential. The experimental results have been compared to those of previous work. Fifty-one levels of Rydberg series 6 s2n d 2D5 /2 and 52 levels of Rydberg series 6 s2n s 2S1 /2 were reported. Additionally, six even-parity autoionization (AI) series converging to Lu ionic states 5 d 6 s 3D1 and 5 d 6 s 3D2 were observed. The level energies of these AI states were measured. The configurations of the AI states were assigned by relativistic multichannel theory within the framework of multichannel quantum defect theory.

  6. Early-stage plasma dynamics with air ionization during ultrashort laser ablation of metal

    Energy Technology Data Exchange (ETDEWEB)

    Hu Wenqian; Shin, Yung C.; King, Galen [School of Mechanical Engineering, Purdue University, West Lafayette, Indiana 47907 (United States)

    2011-09-15

    In this study, the early-stage plasma evolution generated by an ultrashort laser pulse is investigated through pump-probe shadowgraph measurements and simulations. The measurements are performed to show the evolution of the plasma front, while the simulation model is used to further investigate the evolution process and mechanism. Specifically, the laser pulse propagation in air is simulated using the beam propagation method with the slowly varying envelope approximation. The lattice dynamics, the electron dynamics and the multi-scattering event, and the evolution of charged particles (free electrons and ions), are simulated using a molecular dynamics method, a Monte Carlo method, and a particle-in-cell method, respectively. With this simulation model, the refractive index and plasma evolutions are calculated and compared with measured results to validate the simulation model. Different plasma expansion processes, caused by the air ionization, are found with the focal point slightly above and below the target. Air ionization occurs in both cases, but their primary mechanisms are shown to be different.

  7. Above-Threshold Ionization of Quasiperiodic Structures by Low-Frequency Laser Fields

    Science.gov (United States)

    Catoire, F.; Bachau, H.

    2015-10-01

    We investigate the theoretical problem of the photoelectron cutoff change in periodical structures induced by an infrared laser field. We use a one-dimensional Kronig-Penney potential including a finite number of wells, and the analysis is fulfilled by resolving the time-dependent Schrödinger equation. The electron spectra, calculated for an increasing number of wells, clearly show that a plateau quickly appears as the periodic nature of the potential builds up, even at a moderate intensity (10 TW /cm2 ). Varying the intensity from 10 to 30 TW /cm2 we observe a net increase of both the yield and accessible energy range of the ionization spectrum. In order to gain insight into the dynamics of the system at these intensities, we use an analytical approach, based on exact solutions of the full Hamiltonian in a periodic potential. We show that the population transfers efficiently from lower to upper bands when the Bloch and laser frequencies become comparable. The model leads to a quantitative prediction of the intensity range where ionization enters the nonperturbative regime. Moreover, it reveals the physics underlying the increase of the photoelectron energy cutoff at moderate intensities, as observed experimentally.

  8. Low-power laser irradiation did not stimulate breast cancer cells following ionizing radiation

    Science.gov (United States)

    Silva, C. R.; Camargo, C. F. M.; Cabral, F. V.; Ribeiro, M. S.

    2016-03-01

    Cancer has become a public health problem worldwide. Radiotherapy may be a treatment to a number of types of cancer, frequently using gamma-radiation with sources such as 137Cs and 60Co, with varying doses, dose rates, and exposure times to obtain a better as a stimulant for cell proliferation and tissue healing process. However, its effects on cancer cells are not yet well elucidated. The purpose of this work was to evaluate the effects of the LPL on breast cancer cultures after ionizing radiation. The breast cancer-MDA-MB-231 cells were gamma irradiated by a 60Co source, with dose of 2.5 Gy. After 24h, cells were submitted to LPL irradiation using a red laser emitting at λ= 660 nm, with output power of 40 mW and exposure time of 30 s and 60 s. The plates were uniformly irradiated, with energy of 1.2 J and 2.4 J, respectively. Cell viability was analyzed using the exclusion method with trypan blue. Our results show that breast cancer cells submitted to LPL after ionizing radiation remained 95 % viable. No statistically significant differences were observed between laser and control untreated cells, (P > 0.05). These findings suggest that LPL did not influenced cancer cells viability.

  9. Particle production in reflection and transmission mode laser ablation: implications for laserspray ionization.

    Science.gov (United States)

    Musapelo, Thabiso; Murray, Kermit K

    2013-07-01

    Particles were ablated from laser desorption and inlet ionization matrix thin films with a UV laser in reflection and transmission geometries. Particle size distributions were measured with a combined scanning mobility particle sizer (SMPS) and aerodynamic particle sizer (APS) system that measured particles in the size range from 10 nm to 20 μm. The matrixes investigated were 2,5-dihydroxybenzoic acid (DHB), α-cyano-4-hydroxycinnamic acid (CHCA), sinapic acid (SA), 2,5-dihydroxy-acetophenone (DHAP), and 2-nitrophloroglucinol (NPG). Nanoparticles with average diameters between 20 and 120 nm were observed in both transmission and reflection geometry. The particle mass distribution was significantly different in reflection and transmission geometry. In reflection geometry, approximately equal mass was distributed between particles in the 20 to 450 nm range of diameters and particles in the 450 nm to 1.5 μm diameter range. In transmission mode, the particle mass distribution was dominated by large particles in the 2 to 20 μm diameter range. Ablation of inlet ionization matrices DHAP and NPG produced particles that were 3 to 4 times smaller compared with the other matrices. The results are consistent with ion formation by nanoparticle melting and breakup or melting and breakup of the large particles through contact with heated inlet surfaces. ᅟ

  10. X-ray emissions by inner-shell ionization in laser-cluster interaction

    Science.gov (United States)

    Kishimoto, Y.; Nishiyama, H.; Masaki, T.; Moribayashi, K.; Fukuda, Y.; Li, J. Q.

    2006-10-01

    The dynamics of clusters irradiated by high intensity laser pulse has been interested due to its unique nature of the interaction different from other conventional targets and various applications have been proposed [1]. Specifically, an enhanced electric field that is more than one order of magnitude greater than the applied laser field is found to be produced due to the polarization effect near cluster surface. Generation of anomalously high charge state ions and associated short pulse X-rays were observed [2]. Based on simulation studies utilizing our particle code including atomic and relaxation processes [3] incorporated with a perturbation analyses of inner-shell ionization, we have investigated the properties of X-rays from F,O,N,C,B,Be,Li-like argon ions. With an increase of laser intensity, the X-ray pulse length becomes short, comparable to the order of incident laser pulse. [1] Y. Kishimoto et al., Phys. Plasmas 9, 589 (2002) [2] Y. Fukuda et al., Laer and Particle Beams 22, 215 (2004) [3] Y. Fukuda et al., Phys. Rev. A 73, 031201(R) (2006)

  11. New approaches in clinical application of laser-driven ionizing radiation

    Science.gov (United States)

    Hideghéty, Katalin; Szabó, Rita Emilia; Polanek, Róbert; Szabó, Zoltán.; Brunner, Szilvia; Tőkés, Tünde

    2017-05-01

    The planned laser-driven ionizing beams (photon, very high energy electron, proton, carbon ion) at laser facilities have the unique property of ultra-high dose rate (>Gy/s-10), short pulses, and at ELI-ALPS high repetition rate, carry the potential to develop novel laser-driven methods towards compact hospital-based clinical application. The enhanced flexibility in particle and energy selection, the high spatial and time resolution and extreme dose rate could be highly beneficial in radiotherapy. These approaches may increase significantly the therapeutic index over the currently available advanced radiation oncology methods. We highlight two nuclear reactionbased binary modalities and the planned radiobiology research. Boron Neutron Capture Therapy is an advanced cell targeted modality requiring 10B enriched boron carrier and appropriate neutron beam. The development of laser-based thermal and epithermal neutron source with as high as 1010 fluence rate could enhance the research activity in this promising field. Boron-Proton Fusion reaction is as well as a binary approach, where 11B containing compounds are accumulated into the cells, and the tumour selectively irradiated with protons. Due to additional high linear energy transfer alpha particle release of the BPFR and the maximum point of the Bragg-peak is increased, which result in significant biological effect enhancement. Research at ELI-ALPS on detection of biological effect differences of modified or different quality radiation will be presented using recently developed zebrafish embryo and rodent models.

  12. Turbulent Dynamo in a Conducting Fluid and a Partially Ionized Gas

    Science.gov (United States)

    Xu, Siyao; Lazarian, A.

    2016-12-01

    By following the Kazantsev theory and taking into account both microscopic and turbulent diffusion of magnetic fields, we develop a unified treatment of the kinematic and nonlinear stages of a turbulent dynamo process, and we study the dynamo process for a full range of magnetic Prandtl number P m and ionization fractions. We find a striking similarity between the dependence of dynamo behavior on P m in a conducting fluid and { R } (a function of ionization fraction) in a partially ionized gas. In a weakly ionized medium, the kinematic stage is largely extended, including not only exponential growth but a new regime of dynamo characterized by a linear-in-time growth of magnetic field strength, and the resulting magnetic energy is much higher than the kinetic energy carried by viscous-scale eddies. Unlike the kinematic stage, the subsequent nonlinear stage is unaffected by microscopic diffusion processes and has a universal linear-in-time growth of magnetic energy with the growth rate as a constant fraction 3/38 of the turbulent energy transfer rate, showing good agreement with earlier numerical results. Applying the analysis to the first stars and galaxies, we find that the kinematic stage is able to generate a field strength only an order of magnitude smaller than the final saturation value. But the generation of large-scale magnetic fields can only be accounted for by the relatively inefficient nonlinear stage and requires longer time than the free-fall time. It suggests that magnetic fields may not have played a dynamically important role during the formation of the first stars.

  13. Investigation on Soft X-Ray Lasers with a Picosecond-Laser-Irradiated Gas Puff Target

    Energy Technology Data Exchange (ETDEWEB)

    Fiedorowiez, H; Bartnik, A; Jarocki, R; Rakowski, R; Dunn, J; Smith, R F; Hunter, J; Hilsen, J; Shlyaptsev, V N

    2002-10-09

    We present results of experimental studies on transient gain soft x-ray lasers with a picosecond-laser-irradiated gas puff target. The target in a form of an elongated gas sheet is formed by pulsed injection of gas through a slit nozzle using a high-pressure electromagnetic valve developed and characterized at the Institute of Optoelectronics. The x-ray laser experiments were performed at the Lawrence Livermore National Laboratory using the tabletop Compact Multipulse Terawatt (COMET) laser to irradiate argon, krypton or xenon gas puff targets. Soft x-ray lasing in neon-like argon on the 3p-3s transition at 46.9 nm and the 3d-3p transition at 45.1 nm have been demonstrated, however, no amplification for nickel-like krypton or xenon was observed. Results of the experiments are presented and discussed.

  14. Generation of Low Absolute Energy Spread Electron Beams in Laser Wakefield Acceleration Using Tightly Focused Laser through Near-Ionization-Threshold Injection

    CERN Document Server

    Li, F; Wan, Y; Wu, Y P; Hua, J F; Pai, C H; Lu, W; Mori, W B; Joshi, C

    2015-01-01

    An enhanced ionization injection scheme using a tightly focused laser pulse with intensity near the ionization potential to trigger the injection process in a mismatched pre-plasma channel has been proposed and examined via multi-dimensional particle-in-cell simulations. The core idea of the proposed scheme is to lower the energy spread of trapped beams by shortening the injection distance. We have established theory to precisely predict the injection distance, as well as the ionization degree of injection atoms/ions, electron yield and ionized charge. We have found relation between injection distance and laser and plasma parameters, giving a strategy to control injection distance hence optimizing beam's energy spread. In the presented simulation example, we have investigated the whole injection and acceleration in detail and found some unique features of the injection scheme, like multi-bunch injection, unique longitudinal phase-space distribution, etc. Ultimate electron beam has a relative energy spread (rm...

  15. Ionization and acceleration of heavy ions in high-Z solid target irradiated by high intensity laser

    Science.gov (United States)

    Kawahito, D.; Kishimoto, Y.

    2016-05-01

    In the interaction between high intensity laser and solid film, an ionization dynamics inside the solid is dominated by fast time scale convective propagation of the internal sheath field and the slow one by impact ionization due to heated high energy electrons coupled with nonlocal heat transport. Furthermore, ionization and acceleration due to the localized external sheath field which co- propagates with Al ions constituting the high energy front in the vacuum region. Through this process, the maximum charge state and then q/A increase in the rear side, so that ions near the front are further accelerated to high energy.

  16. Ionized Gas in Damped Lyman Alpha Protogalaxies II. Comparison Between Models and the Kinematic Data

    CERN Document Server

    Wolfe, A M; Wolfe, Arthur M.

    2000-01-01

    We test semi-analytic models for galaxy formation with accurate kinematic data of damped Lyman alpha protogalaxies (DLAs) presented in the companion paper I. The models envisage centrifugally supported exponential disks at the centers of dark matter halos which are filled with ionized gas undergoing radial infall to the disks. The halo masses are drawn from cross-section weighted mass distributions predicted by CDM cosmogonies, or by the null hypothesis (TF model) that the dark matter mass distribution has not evolved since z ~ 3. In our models, C IV absorption lines detected in DLAs arise in infalling ionized clouds while the low-ion absorption lines arise from neutral gas in the disks. Using Monte Carlo methods we find: (a) The CDM models are incompatible with the low-ion statistics at more than 99% confidence whereas some TF models cannot be excluded at more than 88% confidence. (b) Both CDM and TF models agree with the observed distribution of C IV velocity widths. (c) The CDM models generate differences ...

  17. High-field plasma acceleration in a high-ionization-potential gas.

    Science.gov (United States)

    Corde, S; Adli, E; Allen, J M; An, W; Clarke, C I; Clausse, B; Clayton, C E; Delahaye, J P; Frederico, J; Gessner, S; Green, S Z; Hogan, M J; Joshi, C; Litos, M; Lu, W; Marsh, K A; Mori, W B; Vafaei-Najafabadi, N; Walz, D; Yakimenko, V

    2016-06-17

    Plasma accelerators driven by particle beams are a very promising future accelerator technology as they can sustain high accelerating fields over long distances with high energy efficiency. They rely on the excitation of a plasma wave in the wake of a drive beam. To generate the plasma, a neutral gas can be field-ionized by the head of the drive beam, in which case the distance of acceleration and energy gain can be strongly limited by head erosion. Here we overcome this limit and demonstrate that electrons in the tail of a drive beam can be accelerated by up to 27 GeV in a high-ionization-potential gas (argon), boosting their initial 20.35 GeV energy by 130%. Particle-in-cell simulations show that the argon plasma is sustaining very high electric fields, of ∼150 GV m(-1), over ∼20 cm. The results open new possibilities for the design of particle beam drivers and plasma sources.

  18. Effect of dimethylamine on the gas phase sulfuric acid concentration measured by Chemical Ionization Mass Spectrometry

    Science.gov (United States)

    Rondo, L.; Ehrhart, S.; Kürten, A.; Adamov, A.; Bianchi, F.; Breitenlechner, M.; Duplissy, J.; Franchin, A.; Dommen, J.; Donahue, N. M.; Dunne, E. M.; Flagan, R. C.; Hakala, J.; Hansel, A.; Keskinen, H.; Kim, J.; Jokinen, T.; Lehtipalo, K.; Leiminger, M.; Praplan, A.; Riccobono, F.; Rissanen, M. P.; Sarnela, N.; Schobesberger, S.; Simon, M.; Sipilä, M.; Smith, J. N.; Tomé, A.; Tröstl, J.; Tsagkogeorgas, G.; Vaattovaara, P.; Winkler, P. M.; Williamson, C.; Wimmer, D.; Baltensperger, U.; Kirkby, J.; Kulmala, M.; Petäjä, T.; Worsnop, D. R.; Curtius, J.

    2016-03-01

    Sulfuric acid is widely recognized as a very important substance driving atmospheric aerosol nucleation. Based on quantum chemical calculations it has been suggested that the quantitative detection of gas phase sulfuric acid (H2SO4) by use of Chemical Ionization Mass Spectrometry (CIMS) could be biased in the presence of gas phase amines such as dimethylamine (DMA). An experiment (CLOUD7 campaign) was set up at the CLOUD (Cosmics Leaving OUtdoor Droplets) chamber to investigate the quantitative detection of H2SO4 in the presence of dimethylamine by CIMS at atmospherically relevant concentrations. For the first time in the CLOUD experiment, the monomer sulfuric acid concentration was measured by a CIMS and by two CI-APi-TOF (Chemical Ionization-Atmospheric Pressure interface-Time Of Flight) mass spectrometers. In addition, neutral sulfuric acid clusters were measured with the CI-APi-TOFs. The CLOUD7 measurements show that in the presence of dimethylamine (dimethylamine dramatically changes the H2SO4 cluster distribution compared to binary (H2SO4-H2O) conditions, the CIMS detection efficiency does not seem to depend substantially on whether an individual H2SO4 monomer is clustered with a DMA molecule. The experimental observations are supported by numerical simulations based on A Self-contained Atmospheric chemistry coDe coupled with a molecular process model (Sulfuric Acid Water NUCleation) operated in the kinetic limit.

  19. Development of Gas Ionization Chambers with Coplanar Electrodes for Alpha-ray Spectrometry

    Science.gov (United States)

    Iwasaki, Kenta; Tanaka, Naomichi; Murakami, Kohei; Kusano, Hiroki; Shibamura, Eido; Hasebe, Nobuyuki; Miyajima, Mitsuhiro

    A large-area alpha-ray spectrometer is required to measure the low level alpha emitters in environmental samples, which may be distributed in the vicinity of nuclear power plants. A gas ionization chamber with a coplanar electrode has attractive features such as with mechanical ruggedness, easy handling, easy fabrication of large electrode, and relatively well-known performance. We have investigated the performance of a gas ionization chamber with a coplanar electrode for alpha-ray spectrometry, particularly in the energy resolution. The present experiment shows that the energy resolution in the full width at half maximum (FWHM) is 129 keV (= 2.7%) for alpha-rays from Np with an energy of 4.78 MeV, 120 keV (= 2.2%) for those with 5.49 MeV from Am, and 109 keV (= 1.9%) for those with 5.81 MeV from Cm. It is found that the energy resolution obtained at the present experiment is dominated in the electronic noise caused by the large capacitance existed between the collecting anode (CA) and non-collecting anode (NCA) in the coplanar electrode.

  20. Extraplanar diffuse ionized gas in a small sample of nearby edge-on galaxies

    CERN Document Server

    Rossa, J

    2000-01-01

    We present narrowband H-alpha imaging data of a small survey of nearby edge-on spiral galaxies, aiming at the detection of `extraplanar' diffuse ionized gas (DIG). A few of our studied edge-on spirals show signs of disk-halo interaction (DHI), where extended line emission far above the galactic plane of these galaxies is detected. In some cases an extraplanar diffuse ionized gas (eDIG) layer is discovered, e.g., NGC4634, NGC 3044, while other galaxies show only filamentary features reaching into the halo (e.g., IC 2531) and some galaxies show no sign of eDIG at all. The extraplanar distances of the DIG layer in our narrowband H-alpha images reach values of z<= 2 kpc above the galactic plane. The derived star formation rates (SFRs) from the H-alpha flux of the studied galaxies range from 0.05-0.7 M_{sun}/yr, neglecting a correction for internal absorption. The variation of the SFR values among our sample galaxies reflects the diversity of star formation within this sample. A diagnostic diagram is introduced...

  1. Testing a Dynamical Equilibrium Model of the Extraplanar Diffuse Ionized Gas in NGC 891

    CERN Document Server

    Boettcher, Erin; Gallagher, J S; Benjamin, Robert A

    2016-01-01

    The observed scale heights of extraplanar diffuse ionized gas (eDIG) layers exceed their thermal scale heights by a factor of a few in the Milky Way and other nearby edge-on disk galaxies. Here, we test a dynamical equilibrium model of the extraplanar diffuse ionized gas layer in NGC 891, where we ask whether the thermal, turbulent, magnetic field, and cosmic ray pressure gradients are sufficient to support the layer. In optical emission line spectroscopy from the SparsePak integral field unit on the WIYN 3.5-meter telescope, the H-alpha emission in position-velocity space suggests that the eDIG is found in a ring between galactocentric radii of R_min = 2 kpc. We find that the thermal (sigma_th = 11 km/s) and turbulent (sigma_turb = 25 km/s) velocity dispersions are insufficient to satisfy the hydrostatic equilibrium equation given an exponential electron scale height of h_z = 1.0 kpc. Using a literature analysis of radio continuum observations from the CHANG-ES survey, we demonstrate that the magnetic field ...

  2. Observations of Feedback from Radio-Quiet Quasars: I. Extents and Morphologies of Ionized Gas Nebulae

    CERN Document Server

    Liu, Guilin; Greene, Jenny E; Nesvadba, Nicole P H; Liu, Xin

    2013-01-01

    Black hole feedback -- the strong interaction between the energy output of supermassive black holes and their surrounding environments -- is routinely invoked to explain the absence of overly luminous galaxies, the black hole vs. bulge correlations and the similarity of black hole accretion and star formation histories. Yet direct probes of this process in action are scarce and limited to small samples of active nuclei. We present Gemini IFU observations of the distribution of ionized gas around luminous, obscured, radio-quiet (RQ) quasars at z~0.5. We detect extended ionized gas nebulae via [O III]5007 emission in every case, with a mean diameter of 28 kpc. These nebulae are nearly perfectly round. The regular morphologies of nebulae around RQ quasars are in striking contrast with lumpy or elongated nebulae seen around radio galaxies at low and high redshifts. We present the uniformly measured size-luminosity relationship of [O III] nebulae around Seyfert 2 galaxies and type 2 quasars spanning 6 orders of ma...

  3. Effect of dimethylamine on the gas phase sulfuric acid concentration measured by Chemical Ionization Mass Spectrometry

    CERN Document Server

    Rondo, L.; Kürten, A.; Adamov, A.; Bianchi, F.; Breitenlechner, M.; Duplissy, J.; Franchin, A.; Dommen, J.; Donahue, N. M.; Dunne, E. M.; Flagan, R. C.; Hakala, J.; Hansel, A.; Keskinen, H.; Kim, J.; Jokinen, T.; Lehtipalo, K.; Leiminger, M.; Praplan, A.; Riccobono, F.; Rissanen, M. P.; Sarnela, N.; Schobesberger, S.; Simon, M.; Sipilä, M.; Smith, J. N.; Tomé, A.; Tröstl, J.; Tsagkogeorgas, G.; Vaattovaara, P.; Winkler, P. M.; Williamson, C.; Wimmer, D.; Baltensperger, U.; Kirkby, J.; Kulmala, M.; Petäjä, T.; Worsnop, D. R.; Curtius, J.

    2016-01-01

    Sulfuric acid is widely recognized as a very important substance driving atmospheric aerosolnucleation. Based on quantum chemical calculations it has been suggested that the quantitative detectionof gas phase sulfuric acid (H2SO4) by use of Chemical Ionization Mass Spectrometry (CIMS) could be biased inthe presence of gas phase amines such as dimethylamine (DMA). An experiment (CLOUD7 campaign) was setup at the CLOUD (Cosmics Leaving OUtdoor Droplets) chamber to investigate the quantitative detection ofH2SO4in the presence of dimethylamine by CIMS at atmospherically relevant concentrations. For the first time inthe CLOUD experiment, the monomer sulfuric acid concentration was measured by a CIMS and by two CI-APi-TOF(Chemical Ionization-Atmospheric Pressure interface-Time Of Flight) mass spectrometers. In addition, neutralsulfuric acid clusters were measured with the CI-APi-TOFs. The CLOUD7 measurements show that in the presenceof dimethylamine (<5 to 70 pptv) the sulfuric acid monomer measured by the CIMS...

  4. Classical electron ionization mass spectra in gas chromatography/mass spectrometry with supersonic molecular beams.

    Science.gov (United States)

    Gordin, Alexander; Fialkov, Alexander B; Amirav, Aviv

    2008-09-01

    A major benefit of gas chromatography/mass spectrometry (GC/MS) with a supersonic molecular beam (SMB) interface and its fly-through ion source is the ability to obtain electron ionization of vibrationally cold molecules (cold EI), which show enhanced molecular ions. However, GC/MS with an SMB also has the flexibility to perform 'classical EI' mode of operation which provides mass spectra to mimic those in commercial 70 eV electron ionization MS libraries. Classical EI in SMB is obtained through simple reduction of the helium make-up gas flow rate, which reduces the SMB cooling efficiency; hence the vibrational temperatures of the molecules are similar to those in traditional EI ion sources. In classical EI-SMB mode, the relative abundance of the molecular ion can be tuned and, as a result, excellent identification probabilities and very good matching factors to the NIST MS library are obtained. Classical EI-SMB with the fly-through dual cage ion source has analyte sensitivity similar to that of the standard EI ion source of a basic GC/MS system. The fly-through EI ion source in combination with the SMB interface can serve for cold EI, classical EI-SMB, and cluster chemical ionization (CCI) modes of operation, all easily exchangeable through a simple and quick change (not involving hardware). Furthermore, the fly-through ion source eliminates sample scattering from the walls of the ion source, and thus it offers full sample inertness, tailing-free operation, and no ion-molecule reaction interferences. It is also robust and enables increased column flow rate capability without affecting the sensitivity.

  5. Selective gas sensing for photonic crystal lasers

    DEFF Research Database (Denmark)

    Smith, Cameron; Christiansen, Mads Brøkner; Buss, Thomas

    2011-01-01

    We facilitate photonic crystal lasers to sense gases via an additional swelling polymer film. We describe the transduction transfer function and experimentally demonstrate an enhanced ethanol vapor sensitivity over 15 dB with low humidity crosstalk.......We facilitate photonic crystal lasers to sense gases via an additional swelling polymer film. We describe the transduction transfer function and experimentally demonstrate an enhanced ethanol vapor sensitivity over 15 dB with low humidity crosstalk....

  6. A VUV Photoionization and Ab Initio Determination of the Ionization Energy of a Gas-Phase Sugar (Deoxyribose).

    Science.gov (United States)

    Ghosh, Debashree; Golan, Amir; Takahashi, Lynelle K; Krylov, Anna I; Ahmed, Musahid

    2012-01-05

    The ionization energy of gas-phase deoxyribose was determined using tunable vacuum ultraviolet synchrotron radiation coupled to an effusive thermal source. Adiabatic and vertical ionization energies of the ground and first four excited states of α-pyranose, the structure that dominates in the gas phase, were calculated using high-level electronic structure methods. An appearance energy of 9.1(±0.05) eV was recorded, which agrees reasonably well with a theoretical value of 8.8 eV for the adiabatic ionization energy. A clear picture of the dissociative photoionization dynamics of deoxyribose emerges from the fragmentation pattern recorded using mass spectrometry and from ab initio molecular dynamics calculations. The experimental threshold 9.4 (±0.05) eV for neutral water elimination upon ionization is captured well in the calculations, and qualitative insights are provided by molecular orbital analysis and molecular dynamics snapshots along the reaction coordinate.

  7. Laser photoacoustics for gas analysis and materials testing

    Science.gov (United States)

    Sigrist, Markus W.

    1995-07-01

    The application of laser photoacoustics to two different areas is discussed. First, laser-induced spallation and interferometric detection of transient surface displacements is proposed as a powerful noncontact tool for the investigation of adhesion properties of solid surface coatings. Results for nickel and plasma-sprayed ceramic coatings are presented. Delamination processes at the interface between substrate and coating could be detected with excellent spatial and temporal resolution and adhesion strengths in the 0.2 to 2 GPa range be determined. Second, laser photoacoustic spectroscopy is applied to trace gas monitoring. An automated mobile CO2$ laser photoacoustic system is employed for in situ air monitoring with parts per billion sensitivity in industrial, urban, and rural environments. An improvement in detection selectivity for multicomponent gas mixtures is achieved with a continuously tunable high- pressure CO2 laser with a narrow linewidth of 0.017 cm-1. A CO laser photoacoustic system previously used for the analysis of motor vehicle exhausts is now employed for studying dimerization phenomena in fatty acid vapors. Finally, emphasis is put on the development of widely tunable, narrow-band, mid-IR laser sources based on optical parametric oscillation or difference frequency generation employing tunable diode lasers and AgGaSe2 as nonlinear material.

  8. Laser Gas-Analyser for Monitoring a Source of Gas Pollution

    Directory of Open Access Journals (Sweden)

    V. A. Gorodnichev

    2015-01-01

    Full Text Available Currently, the problem of growing air pollution of the Earth is of relevance. Many countries have taken measures to protect the environment in order to limit the negative anthropogenic impacts.In such a situation an objective information on the actual content of pollutants in the atmosphere is of importance. For operational inspection of the pollutant concentrations and for monitoring pollution sources, it is necessary to create high-speed high-sensitivity gas analysers.Laser meters are the most effective to provide operational remote and local inspection of gas pollution of the Earth atmosphere.Laser meter for routine gas analysis should conduct operational analysis of the gas mixture (air. For this a development of appropriate information support is required.Such information support should include a database with absorption coefficients of pollutants (specific to potential sources of pollution at possible measuring wavelengths (holding data for a particular emitter of the laser meter and an efficient algorithms to search the measuring wavelengths and conduct a quantitative analysis of gas mixtures.Currently, the issues, important for practice and related to the development of information support for the laser gas analyzer to conduct important for practice routine measurements remain unclear.In this paper we develop an algorithm to provide an operational search of the measuring wavelengths of laser gas analyser and an algorithm to recover quantitively the gaseous component concentrations of controlled gas mixture from the laser multi-spectral measurements that take into account a priori information about the source-controlled gas pollution and do not require a large amount of computation. The method of mathematical simulation shows the effectiveness of the algorithms described both for seach of measuring wavelengths and for quantitative analysis of gas releases.

  9. Quasi-monoenergetic electron beams from a few-terawatt laser driven plasma acceleration using a nitrogen gas jet

    Science.gov (United States)

    Rao, B. S.; Moorti, A.; Chakera, J. A.; Naik, P. A.; Gupta, P. D.

    2017-06-01

    An experimental investigation on the laser plasma acceleration of electrons has been carried out using 3 TW, 45 fs duration titanium sapphire laser pulse interaction with a nitrogen gas jet at an intensity of 2 × 1018 W cm-2. We have observed the stable generation of a well collimated electron beam with divergence and pointing variation ˜10 mrad from nitrogen gas jet plasma at an optimum plasma density around 3 × 1019 cm-3. The energy spectrum of the electron beam was quasi-monoenergetic with an average peak energy and a charge around 25 MeV and 30 pC respectively. The results will be useful for better understanding and control of ionization injection and the laser wakefield acceleration (LWFA) of electrons in high-Z gases and also towards the development of practical LWFA for various applications including injectors for high energy accelerators.

  10. Supression of laser breakdown by pulsed nonequilibrium ns discharge

    Science.gov (United States)

    Starikovskiy, A. Y.; Semenov, I. E.; Shneider, M. N.

    2016-10-01

    The avalanche ionization induced by infrared laser pulses was investigated in a pre-ionized argon gas. Pre-ionization was created by a high-voltage pulsed nanosecond discharge developed in the form of a fast ionization wave. Then, behind the front of ionization wave additional avalanche ionization was initiated by the focused Nd-YAG laser pulse. It was shown that the gas pre-ionization inhibits the laser spark generation. It was demonstrated that the suppression of laser spark development in the case of strong gas pre-ionization is because of fast electron energy transfer from the laser beam focal region. The main mechanism of this energy transfer is free electrons diffusion.

  11. Laser spectroscopy of gas confined in nanoporous materials

    CERN Document Server

    Svensson, Tomas

    2009-01-01

    We show that high-resolution laser spectroscopy can probe surface interactions of gas confined in nano-cavities of porous materials. We report on strong line broadening and unfamiliar lineshapes due to tight confinement, as well as signal enhancement due to multiple photon scattering. This new domain of laser spectroscopy constitute a challenge for the theory of collisions and spectroscopic lineshapes, and open for new ways of analyzing porous materials and processes taking place therein.

  12. Dissociation and Ionization of Quasi-Periodically Vibrating H2+ in Intense Few-Cycle Mid-Infrared Laser Fields

    Science.gov (United States)

    Jiang, Shicheng; Yu, Chao; Yuan, Guanglu; Wu, Tong; Lu, Ruifeng

    2017-02-01

    Using quantum mechanics calculations, we theoretically study the dissociation and ionization dynamics of the hydrogen-molecule ion in strong laser fields. Having prepared the nuclear wave packet of H2+ in a specific vibrational state, a pump laser is used to produce a vibrational excitation, leading to quasi-periodical vibration without ionization. Then, a time-delayed few-cycle laser is applied to trigger the dissociation or ionization of H2+. Both the time delay and the intensity of the probe laser alter the competition between dissociation and ionization. We also explore the dependence of kinetic-energy release spectra of fragments on the time delay, showing that the channels of above-threshold dissociation and below-threshold dissociation are opened and closed periodically. Also, dissociation from different channels is influenced by nuclear motion. The dissociation mechanism has been described in detail using the Floquet picture. This work provides a useful method for steering the electronic and nuclear dynamics of diatomic molecules in intense laser fields.

  13. On- and off-axis spectral emission features from laser-produced gas breakdown plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Harilal, S. S.; Skrodzki, P. J.; Miloshevsky, A.; Brumfield, B. E.; Phillips, M. C.; Miloshevsky, G.

    2017-06-01

    Laser-heated gas breakdown plasmas or sparks emit profoundly in the ultraviolet and visible region of the electromagnetic spectrum with contributions from ionic, atomic, and molecular species. Laser created kernels expand into a cold ambient with high velocities during its early lifetime followed by confinement of the plasma kernel and eventually collapse. However, the plasma kernels produced during laser breakdown of gases are also capable of exciting and ionizing the surrounding ambient medium. Two mechanisms can be responsible for excitation and ionization of surrounding ambient: viz. photoexcitation and ionization by intense ultraviolet emission from the sparks produced during the early times of its creation and/or heating by strong shocks generated by the kernel during its expansion into the ambient. In this study, an investigation is made on the spectral features of on- and off-axis emission features of laser-induced plasma breakdown kernels generated in atmospheric pressure conditions with an aim to elucidate the mechanisms leading to ambient excitation and emission. Pulses from an Nd:YAG laser emitting at 1064 nm with 6 ns pulse duration are used to generate plasma kernels. Laser sparks were generated in air, argon, and helium gases to provide different physical properties of expansion dynamics and plasma chemistry considering the differences in laser absorption properties, mass density and speciation. Point shadowgraphy and time-resolved imaging were used to evaluate the shock wave and spark self-emission morphology at early and late times while space and time resolved spectroscopy is used for evaluating the emission features as well as for inferring plasma fundaments at on- and off-axis. Structure and dynamics of the plasma kernel obtained using imaging techniques are also compared to numerical simulations using computational fluid dynamics code. The emission from the kernel showed that spectral features from ions, atoms and molecules are separated in

  14. Tunable single-photon ionization TOF mass spectrometry using laser-produced plasma as the table-top VUV light source.

    Science.gov (United States)

    Di Palma, Tonia M; Prati, Maria V; Borghese, Antonio

    2009-12-01

    Here we report on a laser plasma-based tunable VUV photoionization time-of-flight (TOF) mass spectrometer conceived mainly to study complex gaseous mixtures. Ionizing photons at tunable vacuum UV (VUV) wavelengths are generated by a gas-target laser-produced plasma, spectrally dispersed in the range 100-160 nm and efficiently focused onto a sample molecular beam. As a test case, we studied the exhaust gas of a four-stroke moped, a typical example of a complex gaseous mixture. Due to the VUV "soft" ionization, the mass spectra are less congested and more easily interpretable. Substituted benzene derivatives are found to give the most intense signals. Several aliphatic hydrocarbons are also detected. The use of tunable VUV radiation allowed the investigation of the contribution of isomers in the mass spectrum from the onset and shape of the photoionization efficiency spectra. Semiquantitative analysis was performed using known literature data detailing the photoionization cross sections. Our findings suggest that using combined data on the mass/photoionization efficiency spectra may be very helpful for a comprehensive analysis of complex gaseous mixtures.

  15. High-Resolution Live-Cell Imaging and Analysis by Laser Desorption/Ionization Droplet Delivery Mass Spectrometry.

    Science.gov (United States)

    Lee, Jae Kyoo; Jansson, Erik T; Nam, Hong Gil; Zare, Richard N

    2016-05-17

    We have developed a new ambient-ionization mass spectrometric technique named laser desorption/ionization droplet delivery mass spectrometry (LDIDD-MS). LDIDD-MS permits high-resolution, high-sensitivity imaging of tissue samples as well as measurements of both single-cell apoptosis and live-cell exocytosis. A pulsed (15 Hz) UV laser beam (266 nm) is focused on a surface covered with target analytes to trigger their desorption and ionization. A spray of liquid droplets is simultaneously directed onto the laser-focused surface region to capture the ionized analytes and deliver them to a mass spectrometer. The approach of rapid and effective capturing of molecules after laser desorption/ionization allows the limit of detection for the amino acid lysine to be as low as 2 amol under ambient ionization conditions. Two-dimensional maps of the desorbed/ionized species are recorded by moving the sample on an XY translational stage. The spatial resolution for imaging with LDIDD-MS was determined to be 2.4 μm for an ink-printed pattern and 3 μm for mouse brain tissue. We applied LDIDD-MS to single-cell analysis of apoptotic HEK cells. Differences were observed in the profiles of fatty acids and lipids between healthy HEK cells and those undergoing apoptosis. We observed upregulation of phosphatidylcholine (PC) with a relatively shorter carbon chain length and downregulation of PC with a relatively longer carbon chain length. We also applied LDIDD-MS for a real-time direct measurements of live-cell exocytosis. The catecholamine dopamine and trace amines (phenethylamine and tyramine) were detected from live PC12 cells without damaging them.

  16. Note: Infrared laser diagnostics for deuterium gas puff Z pinches

    Science.gov (United States)

    Ivanov, V. V.; McKee, E. S.; Hammel, B. D.; Darling, T. W.; Swanson, K. J.; Covington, A. M.

    2017-07-01

    Deuterium gas puff Z pinches have been used for generation of strong neutron fluxes on the MA class pulse power machines. Due to the low electron density of deuterium Z-pinch plasma, regular laser diagnostics in the visible range cannot be used for observation and study of the pinch. Laser probing at the wavelength of 1064 nm was used for visualization of deuterium plasma. Infrared schlieren and interferometry diagnostics showed the deuterium gas puff plasma dynamics, instabilities, and allowed for the reconstruction of the profile of the plasma density.

  17. The influence of variation of electroconductivity on ionized gas flow in the boundary layer along a porous wall

    Directory of Open Access Journals (Sweden)

    Savić Slobodan

    2006-01-01

    Full Text Available This paper investigates ionized gas flow in the boundary layer when its electroconductivity is varied. The flow is planar and the contour is porous. At first, it is assumed that the ionized gas electroconductivity σ depends only on the longitudinal variable. Then we adopt that it is a function of the ratio of the longitudinal velocity and the velocity at the outer edge of the boundary layer. For both electroconductivity variation laws, by application of the general similarity method, the governing boundary layer equations are brought to a generalized form and numerically solved in a four-parametric three times localized approximation. Based on many tabular solutions, we have shown diagrams of the most important nondimensional values and characteristic boundary layer functions for both of the assumed laws. Finally, some conclusions about influence of certain physical values on ionized gas flow in the boundary layer have been drawn. .

  18. Terahertz Emission Dependence on the Fundamental Optical Intensity in Generating Terahertz Waves from Two-Color Laser-Induced Gas Plasma

    Institute of Scientific and Technical Information of China (English)

    DAI Hou-Mei; LIU Jin-Song

    2011-01-01

    A transient photocurrent model is used to explain terahertz ermission from gas plasma irritated by two-color laser pulses,with one the second harmonic of the other.Taking multiple degrees of ionization into account,the gas ionization process at different laser intensities from 1014 W/cm2 to 1015 W/cm2 is discussed.The results show that when Iω ≥ 6 × 1014 W/cm2,double ionization plays an important role in producing electrons.The corresponding terahertz spectra and waveforms are calculated,showing that increasing laser intensity can broaden the spectra to high frequencies and enhance the terahertz field.A promising method for generating terahertz (THz) waves involves emission from laser induced gas plasmas,which was first introduced hy Hamster et al.[1,2] By focusing laser femtosecond pulses with intensity greater than the thresholl for ionization of the gas molecules,one can obtain significant plasma formation.The ionized electrons will then accelerate by the lapser ponderomotive force,thus an electromagnetic pulse at THz frcqucncies can be produced.Since then,other plasma-based THz generation scheines have been proposed.L(o)ffler et al.,[3,4] applied an external dc bias to the plasma region,leading to an approximately one order of magnitude increase in the THz field strength.%A transient photocurrent model is used to explain terahertz emission from gas plasma irritated by two-color laser pulses, with one the second harmonic of the other. Taking multiple degrees of iom'xntion into account, the gas ionizntion process at different laser intensities from 1014 W/cm2 to 1015 W/cm2 is discussed. The results show that when /w > 6 X 1014 W/cin2, double ionization plays an important role in producing electrons. The corresponding terahertz spectra and waveforms are calculated, showing that increasing laser intensity can broaden the spectra to high frequencies and enhance the terahertz Geld.

  19. Development of an Ionization Scheme for Gold using the Selective Laser Ion Source at the On-Line Isotope Separator ISOLDE

    CERN Document Server

    Fedosseev, V; Marsh, B A; CERN. Geneva. AB Department

    2006-01-01

    At the ISOLDE on-line isotope separation facility, the resonance ionization laser ion source (RILIS) can be used to ionize reaction products as they effuse from the target. The RILIS process of laser step-wise resonance ionization of atoms in a hot metal cavity provides a highly element selective stage in the preparation of the radioactive ion beam. As a result, the ISOLDE mass separators can provide beams of a chosen isotope with greatly reduced isobaric contamination. The number of elements available at RILIS has been extended to 26, with the addition of a new three-step ionization scheme for gold. The optimal ionization scheme was determined during an extensive study of the atomic energy levels and auto-ionizing states of gold, carried out by means of in-source resonance ionization spectroscopy. Details of the ionization scheme and a summary of the spectroscopy study are presented.

  20. Thermal proton transfer reactions in ultraviolet matrix-assisted laser desorption/ionization.

    Science.gov (United States)

    Chu, Kuan Yu; Lee, Sheng; Tsai, Ming-Tsang; Lu, I-Chung; Dyakov, Yuri A; Lai, Yin Hung; Lee, Yuan-Tseh; Ni, Chi-Kung

    2014-03-01

    One of the reasons that thermally induced reactions are not considered a crucial mechanism in ultraviolet matrix-assisted laser desorption ionization (UV-MALDI) is the low ion-to-neutral ratios. Large ion-to-neutral ratios (10(-4)) have been used to justify the unimportance of thermally induced reactions in UV-MALDI. Recent experimental measurements have shown that the upper limit of the total ion-to-neutral ratio is approximately 10(-7) at a high laser fluence and less than 10(-7) at a low laser fluence. Therefore, reexamining the possible contributions of thermally induced reactions in MALDI may be worthwhile. In this study, the concept of polar fluid was employed to explain the generation of primary ions in MALDI. A simple model, namely thermal proton transfer, was used to estimate the ion-to-neutral ratios in MALDI. We demonstrated that the theoretical calculations of ion-to-neutral ratios exhibit the same trend and similar orders of magnitude compared with those of experimental measurements. Although thermal proton transfer may not generate all of the ions observed in MALDI, the calculations demonstrated that thermally induced reactions play a crucial role in UV-MALDI.

  1. Above-threshold ionization and photoelectron spectra in atomic systems driven by strong laser fields

    CERN Document Server

    Suárez, Noslen; Ciappina, Marcelo; Biegert, Jens; Lewenstein, Maciej

    2015-01-01

    Above-threshold ionization (ATI) results from strong field laser-matter interaction and it is one of the fundamental processes that may be used to extract electron structural and dynamical information about the atomic or molecular target. Moreover, it can also be used to characterize the laser field itself. Here, we develop an analytical description of ATI, which extends the theoretical Strong Field Approximation (SFA), for both the direct and re-scattering transition amplitudes in atoms. From a non-local, but separable potential, the bound-free dipole and the re-scattering transition matrix elements are analytically computed. In comparison with the standard approaches to the ATI process, our analytical derivation of the re-scattering matrix elements allows us to study directly how the re-scattering process depends on the atomic target and laser pulse features -we can turn on and off contributions having different physical origins or corresponding to different physical mechanisms. We compare SFA results with ...

  2. Nonadiabatic tunnel ionization of current-carrying orbitals of prealigned linear molecules in strong circularly polarized laser fields

    Science.gov (United States)

    Liu, Kunlong; Barth, Ingo

    2016-10-01

    We derive the analytical formula of the ratio of the ionization rates of degenerate valence π± orbitals of prealigned linear molecules in strong circularly polarized (CP) laser fields. Interestingly, our theory shows that the ionization ratio for molecular orbitals with opposite azimuthal quantum numbers ±|m | (e.g., π±) is identical to that for atomic orbitals with the same ±|m | (e.g., p±). In general, the electron counter-rotating to the CP laser field tunnels more easily, not only for atoms but also for linear molecules. Our theoretical predictions are then verified by numerically solving the three-dimensional time-dependent Schrödinger equation for the ionization of the prealigned nitric oxide (NO) molecule in strong CP laser fields. Due to the spin-orbital coupling in the electronic ground state of NO and the sensitivity of ionization to the sense of electron rotation, the ionization of NO in CP fields can produce spin-polarized photoelectrons with high controllability of spin polarization up to 100 % .

  3. Pressure of a partially ionized hydrogen gas: numerical results from exact low temperature expansions

    Energy Technology Data Exchange (ETDEWEB)

    Alastuey, A. [Laboratoire de Physique, ENS Lyon, CNRS, Lyon (France); Ballenegger, V. [Institut UTINAM, Universite de Franche-Comte, CNRS, Besancon (France)

    2010-01-15

    We consider a partially ionized hydrogen gas at low densities, where it reduces almost to an ideal mixture made with hydrogen atoms in their ground-state, ionized protons and ionized electrons. By performing systematic low-temperature expansions within the physical picture, in which the system is described as a quantum electron-proton plasma interacting via the Coulomb potential, exact formulae for the first.ve leading corrections to the ideal Saha equation of state have been derived[A. Alastuey, V. Ballenegger et al., J. Stat. Phys. 130, 1119 (2008)]. Those corrections account for all effects of interactions and thermal excitations up to order exp(E{sub H} /kT) included, where E{sub H} {approx_equal} -13.6 eV is the ground state energy of the hydrogen atom. Among the.ve leading corrections, three are easy to evaluate, while the remaining ones involve suitably truncated internal partition functions of H{sub 2} molecules and H{sup -} and H{sub 2}{sup +} ions, for which no analytical formulae are available in closed form. We estimate those partitions functions at.nite temperature via a simple phenomenology based on known values of rotational and vibrational energies. This allows us to compute numerically the leading deviations to the Saha pressure along several isotherms and isochores. Our values are compared with those of the OPAL tables (for pure hydrogen) calculated within the ACTEX method (copyright 2010 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  4. IZI: Inferring the Gas Phase Metallicity (Z) and Ionization Parameter (q) of Ionized Nebulae using Bayesian Statistics

    CERN Document Server

    Blanc, Guillermo A; Vogt, Frédéric P A; Dopita, Michael A

    2014-01-01

    We present a new method for inferring the metallicity (Z) and ionization parameter (q) of HII regions and star-forming galaxies using strong nebular emission lines (SEL). We use Bayesian inference to derive the joint and marginalized posterior probability density functions for Z and q given a set of observed line fluxes and an input photo-ionization model. Our approach allows the use of arbitrary sets of SELs and the inclusion of flux upper limits. The method provides a self-consistent way of determining the physical conditions of ionized nebulae that is not tied to the arbitrary choice of a particular SEL diagnostic and uses all the available information. Unlike theoretically calibrated SEL diagnostics the method is flexible and not tied to a particular photo-ionization model. We describe our algorithm, validate it against other methods, and present a tool that implements it called IZI. Using a sample of nearby extra-galactic HII regions we assess the performance of commonly used SEL abundance diagnostics. W...

  5. Numerical simulations of turbulent ionized gas flows in the circumsolar protoplanetary disk

    Science.gov (United States)

    Marov, M. Ya.; Kuksa, M. M.

    2015-09-01

    An axisymmetric protoplanetary disk model that takes into account the interaction of turbulent gas flows with the magnetic field is considered. A closed system of equations of homogeneous compressible magnetohydrodynamics in the regime of developed turbulence in the gravitational and magnetic fields of a star has been constructed. Apart from the traditional probability-theoretical averaging of the MHD equations, the weighted Favre averaging is used. The approach by A.V. Kolesnichenko and M.Ya. Marov to modeling the turbulent transport coefficients in a weakly ionized disk has been implemented. It allows the inverse effects of the generated magnetic field on a turbulent gas flow and the dissipation of turbulence through kinematic and magnetic viscosities to be taken into account. A parallel code for numerically solving the system of averaged MHD equations has been developed. The averaged gas density and velocity distributions as well as the configuration of the disk's intrinsic magnetic field at a distance of 1 AU from the star have been obtained through numerical simulations. The assumption that the vertical (parallel to the disk's rotation axis) magnetic induction component changes much more profoundly in height than in radius and, hence, gives grounds to take into account its gradient in the model of the turbulent kinematic viscosity coefficient has been confirmed.

  6. Identifying Extraplanar Diffuse Ionized Gas in a Sample of MaNGA Galaxies

    Science.gov (United States)

    Hubbard, Ryan J.; Diamond-Stanic, Aleksandar M.; MaNGA Team

    2016-01-01

    The efficiency with which galaxies convert gas into stars is driven by the continuous cycle of accretion and feedback processes within the circumgalactic medium. Extraplanar diffuse ionized gas (eDIG) can provide insights into the tumultuous processes that govern the evolution of galactic disks because eDIG emission traces both inflowing and outflowing gas. With the help of state-of-the-art, spatially-resolved spectroscopy from MaNGA (Mapping Nearby Galaxies at Apache Point Observatory), we developed a computational method to identify eDIG based on the strength of and spatial extent of optical emission lines for a diverse sample of 550 nearby galaxies. This sample includes roughly half of the MaNGA galaxies that will become publicly available in summer 2016 as part of the Thirteenth Data Release of the Sloan Digital Sky Survey. We identified signatures of eDIG in 8% of the galaxies in this sample, and we found that these signatures are particularly common among galaxies with active star formation and inclination angles >45 degrees. Our analysis of the morphology, incidence, and kinematics of eDIG has important implications for current models of accretion and feedback processes that regulate star formation in galaxies. We acknowledge support from the Astrophysics REU program at the University of Wisconsin-Madison, the National Astronomy Consortium, and The Grainger Foundation.

  7. Ionized gas pressure correlates with star formation intensity in nearby starbursts

    Science.gov (United States)

    Jiang, Tianxing; Malhotra, Sangeeta; Yang, Huan

    2016-06-01

    We estimate the electron density of the ionized gas and thus the thermal pressure in HII regions; and compare that to the SFR (star formation rate) surface density for a combined sample of about 40 green peas and Lyman Break Analogs at z SII] 6716 / 6731). We find that the SFR surface density is correlated with the electron density and the thermal pressure in HII regions for the star-forming galaxies with SFR surface density above a certain threshold. This work shows quantitatively the correlation between SFR surface density and electron density and that between SFR surface density and the thermal pressure in HII regions for the nearby starburst galaxies. This is consistent with theoretical models of disks (e.g. Kim et al. (2011) if we assume that the thermal pressure in HII regions is comparable to the total diffuse gas pressure at the midplane of the diffuse neutral gas. It is also in agreement with the results from star-forming galaxies at z ~ 2.5. We might infer that the starburst galaxies at low-redshift (z < 0.3) share similar physical properties to the galaxies at high redshift (z ~ 2.5).

  8. Properties of the ionized gas of circumnuclear star-forming regions in early type spirals

    CERN Document Server

    Diaz, Angeles I; Terlevich, Elena; Terlevich, Roberto

    2008-01-01

    (Abbr.) A study of cicumnuclear star-forming regions (CNSFRs) in several early type spirals has been made in order to investigate their main properties: stellar and gas kinematics, dynamical masses, ionising stellar masses, chemical abundances and other properties of the ionised gas. Both high resolution (R$ \\sim $20000) and moderate resolution (R ~ 5000) have been used. In some cases these regions, about 100 to 150 pc in size, are seen to be composed of several individual star clusters with sizes between 1.5 and 4.9 pc estimated from Hubble Space Telescope (HST) images. Stellar and gas velocity dispersions are found to differ by about 20 to 30 km/s with the H$\\beta$ emission lines being narrower than both the stellar lines and the [OIII] $\\lambda$ 5007 \\AA lines. The twice ionized oxygen, on the other hand, shows velocity dispersions comparable to those shown by stars. We have applied the virial theorem to estimate dynamical masses of the clusters, assuming that systems are gravitationally bounded and spheri...

  9. Pahs, Ionized Gas, and Molecular Hydrogen in Brightest Cluster Galaxies of Cool Core Clusters of Galaxies

    CERN Document Server

    Donahue, Megan; O'Connell, Robert W; Voit, G Mark; Hoffer, Aaron; McNamara, Brian R; Nulsen, Paul E J

    2011-01-01

    We present measurements of 5-25 {\\mu}m emission features of brightest cluster galaxies (BCGs) with strong optical emission lines in a sample of 9 cool-core clusters of galaxies observed with the Infrared Spectrograph on board the Spitzer Space Telescope. These systems provide a view of dusty molecular gas and star formation, surrounded by dense, X-ray emitting intracluster gas. Past work has shown that BCGs in cool-core clusters may host powerful radio sources, luminous optical emission line systems, and excess UV, while BCGs in other clusters never show this activity. In this sample, we detect polycyclic aromatic hydrocarbons (PAHs), extremely luminous, rotationally-excited molecular hydrogen line emission, forbidden line emission from ionized gas ([Ne II] and [Ne III]), and infrared continuum emission from warm dust and cool stars. We show here that these BCGs exhibit more luminous forbidden neon and H2 rotational line emission than star-forming galaxies with similar total infrared luminosities, as well as ...

  10. Measurement of photon flux with a miniature gas ionization chamber in a Material Testing Reactor

    Energy Technology Data Exchange (ETDEWEB)

    Fourmentel, D., E-mail: damien.fourmentel@cea.fr [CEA, DEN, DER, Instrumentation Sensors and Dosimetry Laboratory, Cadarache, F-13108 St-Paul-Lez-Durance (France); Filliatre, P.; Villard, J.F.; Lyoussi, A. [CEA, DEN, DER, Instrumentation Sensors and Dosimetry Laboratory, Cadarache, F-13108 St-Paul-Lez-Durance (France); Reynard-Carette, C. [Aix-Marseille Université, LISA EA 4672, cedex 20, Marseille 13397 (France); Carcreff, H. [CEA, DEN, DRSN, Saclay, F-91191 Gif-sur-Yvette (France)

    2013-10-01

    Nuclear heating measurements in Material Testing Reactors (MTR) are crucial for the design of the experimental devices and the prediction of the temperature of the hosted samples. Nuclear heating in MTR materials (except fuel) is mainly due to the energy deposition by the photon flux. Therefore, the photon flux is a key input parameter for the computer codes which simulate nuclear heating and temperature reached by samples/devices under irradiation. In the Jules Horowitz MTR under construction at the CEA Cadarache, the maximal expected nuclear heating levels will be about 15 to 18 W g{sup −1} and it will be necessary to assess this parameter with the best accuracy. An experiment was performed at the OSIRIS reactor to combine neutron flux, photon flux and nuclear heating measurements to improve the knowledge of the nuclear heating in MTR. There are few appropriate sensors for selective measurement of the photon flux in MTR even if studies and developments are ongoing. An experiment, called CARMEN-1, was conducted at the OSIRIS MTR and we used in particular a gas ionization chamber based on miniature fission chamber design to measure the photon flux. In this paper, we detail Monte-Carlo simulations to analyze the photon fluxes with ionization chamber measurements and we compare the photon flux calculations to the nuclear heating measurements. These results show a good accordance between photon flux measurements and nuclear heating measurement and allow improving the knowledge of these parameters.

  11. The Connection Between Reddening, Gas Covering Fraction, and the Escape of Ionizing Radiation at High Redshift

    CERN Document Server

    Reddy, Naveen A; Pettini, Max; Bogosavljevic, Milan; Shapley, Alice

    2016-01-01

    We use a large sample of galaxies at z~3 to establish a relationship between reddening, neutral gas covering fraction (fcov(HI)), and the escape of ionizing photons at high redshift. Our sample includes 933 galaxies at z~3, 121 of which have very deep spectroscopic observations (>7 hrs) in the rest-UV (lambda=850-1300 A) with Keck/LRIS. Based on the high covering fraction of outflowing optically-thick HI indicated by the composite spectra of these galaxies, we conclude that photoelectric absorption, rather than dust attenuation, dominates the depletion of ionizing photons. By modeling the composite spectra as the combination of an unattenuated stellar spectrum including nebular continuum emission with one that is absorbed by HI and reddened by a line-of-sight extinction, we derive an empirical relationship between E(B-V) and fcov(HI). Galaxies with redder UV continua have larger covering fractions of HI characterized by higher line-of-sight extinctions. Our results are consistent with the escape of Lya throug...

  12. Measurement of the first Townsend ionization coefficient in a methane-based tissue-equivalent gas

    Science.gov (United States)

    Petri, A. R.; Gonçalves, J. A. C.; Mangiarotti, A.; Botelho, S.; Bueno, C. C.

    2017-03-01

    Tissue-equivalent gases (TEGs), often made of a hydrocarbon, nitrogen, and carbon dioxide, have been employed in microdosimetry for decades. However, data on the first Townsend ionization coefficient (α) in such mixtures are scarce, regardless of the chosen hydrocarbon. In this context, measurements of α in a methane-based tissue-equivalent gas (CH4 - 64.4%, CO2 - 32.4%, and N2 - 3.2%) were performed in a uniform field configuration for density-normalized electric fields (E/N) up to 290 Td. The setup adopted in our previous works was improved for operating at low pressures. The modifications introduced in the apparatus and the experimental technique were validated by comparing our results of the first Townsend ionization coefficient in nitrogen, carbon dioxide, and methane with those from the literature and Magboltz simulations. The behavior of α in the methane-based TEG was consistent with that observed for pure methane. All the experimental results are included in tabular form in the Supplementary material.

  13. Chemical abundances and properties of the ionized gas in NGC 1705

    CERN Document Server

    Annibali, F; Pasquali, A; Aloisi, A; Mignoli, M; Romano, D

    2015-01-01

    We obtained [O III] narrow-band imaging and multi-slit MXU spectroscopy of the blue compact dwarf (BCD) galaxy NGC 1705 with FORS2@VLT to derive chemical abundances of PNe and H II regions and, more in general, to characterize the properties of the ionized gas. The auroral [O III]\\lambda4363 line was detected in all but one of the eleven analyzed regions, allowing for a direct estimate of their electron temperature. The only object for which the [O III]\\lambda4363 line was not detected is a possible low-ionization PN, the only one detected in our data. For all the other regions, we derived the abundances of Nitrogen, Oxygen, Neon, Sulfur and Argon out to ~1 kpc from the galaxy center. We detect for the first time in NGC 1705 a negative radial gradient in the oxygen metallicity of -0.24 \\pm 0.08 dex kpc^{-1}. The element abundances are all consistent with values reported in the literature for other samples of dwarf irregular and blue compact dwarf galaxies. However, the average (central) oxygen abundance, 12 +...

  14. Ionization of one- and three-dimensionally-oriented asymmetric-top molecules by intense circularly polarized femtosecond laser pulses

    DEFF Research Database (Denmark)

    Hansen, Jonas Lerche; Holmegaard, Lotte; Kalhøj, Line;

    2011-01-01

    are quantum-state selected using a deflector and three-dimensionally (3D) aligned and oriented adiabatically using an elliptically polarized laser pulse in combination with a static electric field. A characteristic splitting in the molecular frame photoelectron momentum distribution reveals the position......We present a combined experimental and theoretical study on strong-field ionization of a three-dimensionally-oriented asymmetric top molecule, benzonitrile (C7H5N), by circularly polarized, nonresonant femtosecond laser pulses. Prior to the interaction with the strong field, the molecules...... of the nodal planes of the molecular orbitals from which ionization occurs. The experimental results are supported by a theoretical tunneling model that includes and quantifies the splitting in the momentum distribution. The focus of the present article is to understand strong-field ionization from 3D...

  15. Wavelength dependent photoelectron circular dichroism of limonene studied by femtosecond multiphoton laser ionization and electron-ion coincidence imaging

    Science.gov (United States)

    Rafiee Fanood, Mohammad M.; Janssen, Maurice H. M.; Powis, Ivan

    2016-09-01

    Enantiomers of the monoterpene limonene have been investigated by (2 + 1) resonance enhanced multiphoton ionization and photoelectron circular dichroism employing tuneable, circularly polarized femtosecond laser pulses. Electron imaging detection provides 3D momentum measurement while electron-ion coincidence detection can be used to mass-tag individual electrons. Additional filtering, by accepting only parent ion tagged electrons, can be then used to provide discrimination against higher energy dissociative ionization mechanisms where more than three photons are absorbed to better delineate the two photon resonant, one photon ionization pathway. The promotion of different vibrational levels and, tentatively, different electronic ion core configurations in the intermediate Rydberg states can be achieved with different laser excitation wavelengths (420 nm, 412 nm, and 392 nm), in turn producing different state distributions in the resulting cations. Strong chiral asymmetries in the lab frame photoelectron angular distributions are quantified, and a comparison made with a single photon (synchrotron radiation) measurement at an equivalent photon energy.

  16. Basic matrices in the analysis of non-covalent complexes by matrix-assisted laser desorption/ionization mass spectrometry

    NARCIS (Netherlands)

    Jespersen, S.; Niessen, W.M.A.; Tjaden, U.R.; Greef, J. van der

    1998-01-01

    A number of potential matrix candidates were investigated with regard to the importance of the pH in the matrix-assisted laser desorption/ionization mass spectrometry (MALDI/MS) analysis of non-covalently bound protein complexes. The matrices examined were 2,5-dihydroxybenzoic acid (DHB), 4-hydroxy-

  17. Combining Laser Ablation/Liquid Phase Collection Surface Sampling and High-Performance Liquid Chromatography Electrospray Ionization Mass Spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Ovchinnikova, Olga S [ORNL; Kertesz, Vilmos [ORNL; Van Berkel, Gary J [ORNL

    2011-01-01

    This paper describes the coupling of ambient pressure transmission geometry laser ablation with a liquid phase sample collection method for surface sampling and ionization with subsequent mass spectral analysis. A commercially available autosampler was adapted to produce a liquid droplet at the end of the syringe injection needle while in close proximity to the surface to collect the sample plume produced by laser ablation. The sample collection was followed by either flow injection or a high performance liquid chromatography (HPLC) separation of the extracted components and detection with electrospray ionization mass spectrometry (ESI-MS). To illustrate the analytical utility of this coupling, thin films of a commercial ink sample containing rhodamine 6G and of mixed isobaric rhodamine B and 6G dyes on glass microscope slides were analyzed. The flow injection and HPLC/ESI-MS analysis revealed successful laser ablation, capture and, with HPLC, the separation of the two compounds. The ablated circular area was about 70 m in diameter for these experiments. The spatial sampling resolution afforded by the laser ablation, as well as the ability to use sample processing methods like HPLC between the sample collection and ionization steps, makes this combined surface sampling/ionization technique a highly versatile analytical tool.

  18. Development of matrix-assisted laser desorption ionization-mass spectrometry imaging (MALDI-MSI) for plant metabolite analysis

    Energy Technology Data Exchange (ETDEWEB)

    Korte, Andrew R [Iowa State Univ., Ames, IA (United States)

    2014-12-01

    This thesis presents efforts to improve the methodology of matrix-assisted laser desorption ionization-mass spectrometry imaging (MALDI-MSI) as a method for analysis of metabolites from plant tissue samples. The first chapter consists of a general introduction to the technique of MALDI-MSI, and the sixth and final chapter provides a brief summary and an outlook on future work.

  19. Basic matrices in the analysis of non-covalent complexes by matrix-assisted laser desorption/ionization mass spectrometry

    NARCIS (Netherlands)

    Jespersen, S.; Niessen, W.M.A.; Tjaden, U.R.; Greef, J. van der

    1998-01-01

    A number of potential matrix candidates were investigated with regard to the importance of the pH in the matrix-assisted laser desorption/ionization mass spectrometry (MALDI/MS) analysis of non-covalently bound protein complexes. The matrices examined were 2,5-dihydroxybenzoic acid (DHB), 4-hydroxy-

  20. Application of matrix-assisted laser desorption/ionization to on-line aerosol time-of-flight mass spectrometry

    NARCIS (Netherlands)

    Stowers, M.A.; Wuijckhuijse, A.L. van; Marijnissen, J.C.M.; Scarlett, B.; Baar, B.L.M. van; Kientz, Ch.E.

    2000-01-01

    Matrix-assisted laser desorption/ionization (MALDI) mass spectra were obtained from single biological aerosol particles using an aerosol time-of- flight mass spectrometer (ATOFMS). The inlet to the ATOFMS was coupled with an evaporation/condensation flow cell that allowed the aerosol to be coated wi

  1. Ammonium Ion Exchanged Zeolite for Laser Desorption/Ionization Mass Spectrometry of Phosphorylated Peptides

    Directory of Open Access Journals (Sweden)

    Mengrui Yang

    2015-01-01

    Full Text Available α-Cyano-4-hydroxycinnamic acid (CHCA, an organic matrix molecule for matrix-assisted laser desorption/ionization mass spectrometry, was adsorbed to NH4+-type zeolite surface, and this new matrix was used for the detection of low-molecular-weight compounds. It was found that this matrix could simplify the mass spectrum in the low-molecular-weight region and prevent interference from fragments and alkali metal ion adducted species. CHCA adsorbed to NH4+-type ZSM5 zeolite (CHCA/NH4ZSM5 was used to measure atropine and aconitine, two toxic alkaloids in plants. In addition, CHCA/NH4ZSM5 enabled us to detect phosphorylated peptides; peaks of the protonated peptides had higher intensities than the peaks observed using CHCA only.

  2. Large Scale Nanoparticle Screening for Small Molecule Analysis in Laser Desorption Ionization Mass Spectrometry.

    Science.gov (United States)

    Yagnik, Gargey B; Hansen, Rebecca L; Korte, Andrew R; Reichert, Malinda D; Vela, Javier; Lee, Young Jin

    2016-09-20

    Nanoparticles (NPs) have been suggested as efficient matrixes for small molecule profiling and imaging by laser-desorption ionization mass spectrometry (LDI-MS), but so far there has been no systematic study comparing different NPs in the analysis of various classes of small molecules. Here, we present a large scale screening of 13 NPs for the analysis of two dozen small metabolite molecules. Many NPs showed much higher LDI efficiency than organic matrixes in positive mode and some NPs showed comparable efficiencies for selected analytes in negative mode. Our results suggest that a thermally driven desorption process is a key factor for metal oxide NPs, but chemical interactions are also very important, especially for other NPs. The screening results provide a useful guideline for the selection of NPs in the LDI-MS analysis of small molecules.

  3. Electron spectra from ionizing collisions in a dense laser-excited Na beam.

    Science.gov (United States)

    Babenko, E.; Ramos, G.; Smith, W. W.

    2000-06-01

    We report low-energy (Europhysics Letters 23), 567 (1993). At higher, saturating intensity in our dense beam, we see multiple peaks, with the extra peaks attributed to 3p+3d associative ionization(AI)(E.Babenko, C.Tapalian and W.W.Smith, Chem. Phys. Lett. 244), 121 (1995). and superelastic electron scattering from excited states. The main, broad AI peak at 1.1 eV reflects the vibrorotational distribution of the product Na_2^+ dimer ions, consistent with a simple long-range model of the collision process. A broad, low energy peak at 0.35 eV is tentatively attributed to excitation of the dissociative ^2Σ_u^+ state of the Na_2^+ dimer. Analogous spectra were taken when the 3p and 5s states were selectively laser excited.

  4. High-Order Above-Threshold Ionization of H+ in Intense Laser Field

    Institute of Scientific and Technical Information of China (English)

    GUO Ying-Chun; FU Pan-Ming; WANG Bing-Bing

    2009-01-01

    The nonperturbative quantum electrodynamics method proposed by Fu et al.[Phys.Rev.A 75 (2007) 063419]is employed to study the high-order above-threshold ionization (ATI) of a diatomic molecule. Based on this frequency-domain theory,the high-order ATI process can be regarded as ATI followed by laser-assisted collision,where the total transition amplitude is the coherent summation of the contributions from each ATI channel.The angular-resolved ATI spectrum,which agrees with the results by Becket et al.based on the time-domain method,is obtained by this frequency domain theory.Furthermore,it is demonstrated that the interference characteristics representing the molecular structure in the ATI spectrum originates from the recollision of the electron with two-centre ion in each ATI channel.

  5. Direct Surface Analysis of Fungal Species by Matrix-assisted Laser Desorption/Ionization Mass Spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Valentine, Nancy B.(BATTELLE (PACIFIC NW LAB)); Wahl, Jon H.(BATTELLE (PACIFIC NW LAB)); Kingsley, Mark T.(BATTELLE (PACIFIC NW LAB)); Wahl, Karen L.(BATTELLE (PACIFIC NW LAB))

    2001-12-01

    Intact spores and/or hyphae of Aspergillus niger, Rhizopus oryzae, Trichoderma reesei and Phanerochaete chrysosporium are analyzed by matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI-TOF-MS). This study investigates various methods of sample preparation and matrices to determine optimum collection and analysis criteria for fungal analysis by MALDI-MS. Fungi are applied to the MALDI sample target as untreated, sonicated, acid/heat treated, or blotted directly from the fungal culture with double-stick tape. Ferulic acid or sinapinic acid matrix solution is layered over the dried samples and analyzed by MALDI-MS. Statistical analysis of the data show that simply using double stick tape to collect and transfer to a MALDI sample plate typically worked as well as the other preparation methods, but requires the least sample handling.

  6. Laser Welding Test Results with Gas Atmospheres in Welding Chamber

    Energy Technology Data Exchange (ETDEWEB)

    Joung, Chang-Young; Hong, Jin-Tae; Ahn, Sung-Ho; Heo, Sung-Ho; Jang, Seo-Yun; Yang, Tae-Ho [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2015-10-15

    The weld beads of specimens welded under identical conditions in the helium and argon gas were cleaner, more regular, and steadier than those in a vacuum. The penetration depth of the FZ in the vacuum was much deeper than those in the helium and argon gas. To measure the irradiation properties of nuclear fuel in a test reactor, a nuclear fuel test rod instrumented with various sensors must be fabricated with assembly processes. A laser welding system to assemble the nuclear fuel test rod was designed and fabricated to develop various welding technologies of the fuel test rods to joint between a cladding tube and end-caps. It is an air-cooling optical fiber type and its emission modes are a continuous (CW) mode of which the laser generates continuous emission, and pulse (QCW) mode in which the laser internally generates sequences of pulses. We considered the system welding a sample in a chamber that can weld a specimen in a vacuum and inert gas atmosphere, and the chamber was installed on the working plate of the laser welding system. In the chamber, the laser welding process should be conducted to have no defects on the sealing area between a cladding tube and an end-cap.

  7. Investigation of the threshold intensity versus gas pressure in the breakdown of helium by 248 nm laser radiation

    Science.gov (United States)

    Gamal, Yosr E. E.-D.; Abdellatif, Galila

    2014-10-01

    An investigation of the unexpectedly strong dependence of the threshold intensity on the gas pressure in the experimental study on the breakdown of He by short laser wavelength (Turcu et al., in Opt Commun, 134:66-68, 1997) is presented. A modified electron cascade model is applied (Evans and Gamal, in J Phys D Appl Phys, 13:1447-1458, 1980). Computations revealed reasonable agreement between the calculated thresholds and the measured ones. Moreover, the calculated electron energy distribution function and its parameters proved that multiphoton ionization of ground and excited atoms is the main source for the seed electrons, which contributes to the breakdown of helium. The effect of diffusion losses over pressures <1,000 Torr elucidated the origin of the strong dependence of the threshold intensity on the gas pressure. Collisional ionization dominates only at high pressures. No evidence for recombination losses is observed for pressures up to 3,000 Torr.

  8. Revisiting the quantitative features of surface-assisted laser desorption/ionization mass spectrometric analysis.

    Science.gov (United States)

    Wu, Ching-Yi; Lee, Kai-Chieh; Kuo, Yen-Ling; Chen, Yu-Chie

    2016-10-28

    Surface-assisted laser desorption/ionization (SALDI) coupled with mass spectrometry (MS) is frequently used to analyse small organics owing to its clean background. Inorganic materials can be used as energy absorbers and the transfer medium to facilitate the desorption/ionization of analytes; thus, they are used as SALDI-assisting materials. Many studies have demonstrated the usefulness of SALDI-MS in quantitative analysis of small organics. However, some characteristics occurring in SALDI-MS require certain attention to ensure the reliability of the quantitative analysis results. The appearance of a coffee-ring effect in SALDI sample preparation is the primary factor that can affect quantitative SALDI-MS analysis results. However, to the best of our knowledge, there are no reports relating to quantitative SALDI-MS analysis that discuss or consider this effect. In this study, the coffee-ring effect is discussed using nanoparticles and nanostructured substrates as SALDI-assisting materials to show how this effect influences SALDI-MS analysis results. Potential solutions for overcoming the existing problems are also suggested.This article is part of the themed issue 'Quantitative mass spectrometry'.

  9. Non-constant ponderomotive energy in above threshold ionization by intense short laser pulses

    CERN Document Server

    Della Picca, Renata; Garibotti, Carlos Roberto; López, Sebastián David; Arbó, Diego

    2015-01-01

    We analyze the contribution of the quiver kinetic energy acquired by an electron in an oscillating electric field to the energy balance in atomic ionization processes by a short laser pulse. Due to the time dependence of this additional kinetic energy, a temporal average is assumed to maintain a stationary energy conservation rule. This rule is used to predict the position of the peaks observed in the photo electron spectra (PE). For a flat top pulse envelope, the mean value of the quiver energy over the whole pulse leads to the concept of ponderomotive energy $U_{p}$. However for a short pulse with a fast changing field intensity a stationarity approximation could not be precise. We check these concepts by studying first the photoelectron (PE) spectrum within the Semiclassical Model (SCM) for a multiple steps pulses. The SCM offers the possibility to establish a connection between emission times and the PE spectrum in the energy domain. We show that PE substructures stem from ionization at different times ma...

  10. Rapid measurement of phytosterols in fortified food using gas chromatography with flame ionization detection.

    Science.gov (United States)

    Duong, Samantha; Strobel, Norbert; Buddhadasa, Saman; Stockham, Katherine; Auldist, Martin; Wales, Bill; Orbell, John; Cran, Marlene

    2016-11-15

    A novel method for the measurement of total phytosterols in fortified food was developed and tested using gas chromatography with flame ionization detection. Unlike existing methods, this technique is capable of simultaneously extracting sterols during saponification thus significantly reducing extraction time and cost. The rapid method is suitable for sterol determination in a range of complex fortified foods including milk, cheese, fat spreads, oils and meat. The main enhancements of this new method include accuracy and precision, robustness, cost effectiveness and labour/time efficiencies. To achieve these advantages, quantification and the critical aspects of saponification were investigated and optimised. The final method demonstrated spiked recoveries in multiple matrices at 85-110% with a relative standard deviation of 1.9% and measurement uncertainty value of 10%. Copyright © 2016 Elsevier Ltd. All rights reserved.

  11. Accurate Structure Parameters for Tunneling Ionization Rates of Gas-Phase Linear Molecules

    Science.gov (United States)

    Zhao, Song-Feng; Li, Jian-Ke; Wang, Guo-Li; Li, Peng-Cheng; Zhou, Xiao-Xin

    2017-03-01

    In the molecular Ammosov–Delone–Krainov (MO-ADK) model of Tong et al. [Phys. Rev. A 66 (2002) 033402], the ionization rate depends on the structure parameters of the molecular orbital from which the electron is removed. We determine systematically and tabulate accurate structure parameters of the highest occupied molecular orbital (HOMO) for 123 gas-phase linear molecules by solving time-independent Schrödinger equation with B-spline functions and molecular potentials which are constructed numerically using the modified Leeuwen–Baerends (LBα) model. Supported by National Natural Science Foundation of China under Grant Nos. 11664035, 11674268, 11465016, 11364038, 11364039, the Specialized Research Fund for the Doctoral Program of Higher Education of China under Grant No. 20116203120001 and the Basic Scientific Research Foundation for Institution of Higher Learning of Gansu Province

  12. Self-detection of x-ray Fresnel transmittivity using photoelectron-induced gas ionization

    CERN Document Server

    Stoupin, Stanislav

    2015-01-01

    Electric response of an x-ray mirror enclosed in a gas flow ionization chamber was studied under the conditions of total external reflection for hard x-rays. It is shown that the electric response of the system as a function of the incidence angle is defined by x-ray Fresnel transmittivity and photon-electron attenuation properties of the mirror material. A simple interpretation of quantum yield of the system is presented. The approach provides non-invasive in-situ diagnostics of hard x-ray optics, easy access to complementary x-ray transmittivity data in x-ray reflectivity experiments and can also pave the way to novel schemes for angle and energy resolving x-ray detectors.

  13. Halpha and [S II] emission from warm ionized gas in the Scutum-Centaurus Arm

    CERN Document Server

    Hill, Alex S; Haffner, L Matthew; Gostisha, Martin; Barger, Kathleen A

    2014-01-01

    We present Wisconsin H-Alpha Mapper [S II] {\\lambda}6716 and H{\\alpha} spectroscopic maps of the warm ionized medium (WIM) in the Scutum-Centaurus Arm at Galactic longitudes 310{\\deg} = 100 R. The line ratio is better correlated with H{\\alpha} intensity than with height above the plane, indicating that the physical conditions within the WIM vary systematically with electron density. We argue that the variation of the line ratio with height is a consequence of the decrease of electron density with height. Our results reinforce the well-established picture in which the diffuse H{\\alpha} emission is due primarily to emission from in situ photoionized gas, with scattered light only a minor contributor.

  14. Ionized gas (plasma) delivery of reactive oxygen species (ROS) into artificial cells

    Science.gov (United States)

    Hong, Sung-Ha; Szili, Endre J.; Jenkins, A. Toby A.; Short, Robert D.

    2014-09-01

    This study was designed to enhance our understanding of how reactive oxygen species (ROS), generated ex situ by ionized gas (plasma), can affect the regulation of signalling processes within cells. A model system, comprising of a suspension of phospholipid vesicles (cell mimics) encapsulating a ROS reporter, was developed to study the plasma delivery of ROS into cells. For the first time it was shown that plasma unequivocally delivers ROS into cells over a sustained period and without compromising cell membrane integrity. An important consideration in cell and biological assays is the presence of serum, which significantly reduced the transfer efficiency of ROS into the vesicles. These results are key to understanding how plasma treatments can be tailored for specific medical or biotechnology applications. Further, the phospholipid vesicle ROS reporter system may find use in other studies involving the application of free radicals in biology and medicine.

  15. Self-detection of x-ray Fresnel transmissivity using photoelectron-induced gas ionization

    Energy Technology Data Exchange (ETDEWEB)

    Stoupin, Stanislav, E-mail: sstoupin@aps.anl.gov [Advanced Photon Source, Argonne National Laboratory, Lemont, Illinois 60439 (United States)

    2016-01-25

    Electric response of an x-ray mirror enclosed in a gas flow ionization chamber was studied under the conditions of total external reflection for hard x-rays. It is shown that the electric response of the system as a function of the incidence angle is defined by x-ray Fresnel transmissivity and photon-electron attenuation properties of the mirror material. A simple interpretation of quantum yield of the system is presented. The approach could serve as a basis for non-invasive in situ diagnostics of hard x-ray optics, easy access to complementary x-ray transmissivity data in x-ray reflectivity experiments, and might also pave the way to advanced schemes for angle and energy resolving x-ray detectors.

  16. Self-detection of x-ray Fresnel transmissivity using photoelectron-induced gas ionization

    Science.gov (United States)

    Stoupin, Stanislav

    2016-01-01

    Electric response of an x-ray mirror enclosed in a gas flow ionization chamber was studied under the conditions of total external reflection for hard x-rays. It is shown that the electric response of the system as a function of the incidence angle is defined by x-ray Fresnel transmissivity and photon-electron attenuation properties of the mirror material. A simple interpretation of quantum yield of the system is presented. The approach could serve as a basis for non-invasive in situ diagnostics of hard x-ray optics, easy access to complementary x-ray transmissivity data in x-ray reflectivity experiments, and might also pave the way to advanced schemes for angle and energy resolving x-ray detectors.

  17. Determination of selected fatty acids in dried sweat spot using gas chromatography with flame ionization detection.

    Science.gov (United States)

    Kanďár, Roman; Drábková, Petra; Andrlová, Lenka; Kostelník, Adam; Čegan, Alexander

    2016-11-01

    A method is described for the determination of fatty acids in dried sweat spot and plasma samples using gas chromatography with flame ionization detection. Plasma and dried sweat spot samples were obtained from a group of blood donors. The sweat was collected from each volunteer during exercise. Sweat was spotted onto collection paper containing butylated hydroxytoluene. Fatty acids were derivatized with acetyl chloride in methanol to form methyl esters of fatty acids. The fatty acids in dried sweat spot samples treated with butylated hydroxytoluene and stored at -20°C were stable for 3 months. Our results indicate that sweat contains, among fatty acids with short chain, also fatty acids with long chain and unsaturated fatty acids. Linear relationships between percentage content of selected fatty acids in dried sweat spot and plasma were observed. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  18. The detection of dissolved gases in transformer oil by gas chromatography with helium ionization detector

    Science.gov (United States)

    Deng, Xian-qin; Fang, Hua; Li, Min-xian

    2017-07-01

    The GC-PDD with the technology of valve cutting and helium ionization detector was used to analyze the dissolved gases in ultra-high voltage(UHV) and extra-high voltage(EHV) transformer oil. The detection limit(DL) reached ppb grade, especially for the featuring gas—C2H2 and H2, whose DL could reach 5ppb and 11ppb respectively. The test reproducibility of the instrument was about 1% and the correlation coefficient of standard curve-r is greater or equal to 0.99, which showed obvious advantage compared with normal GC. In addition, the auxiliary gas of H2 was not used in this instrument, which completely improved the safety performance. Thus, the application of GC-PDD has significant meaning in warning potential malfunction inside the ultra-high voltage transformer in advance.

  19. Laser ablation plume expansion into an ambient gas

    DEFF Research Database (Denmark)

    Amoruso, S.; Schou, Jørgen; Lunney, J.G.

    2009-01-01

    The use of an ambient gas is a well-established method employed in pulsed laser deposition (PLD) with nanosecond pulses and has been extensively studied in this context. Most of the existing treatments of the plume expansion are tackled by using complex numerical modeling involving specific target...

  20. Photoacoustic Spectroscopy with Quantum Cascade Lasers for Trace Gas Detection

    Directory of Open Access Journals (Sweden)

    Gaetano Scamarcio

    2006-10-01

    Full Text Available Various applications, such as pollution monitoring, toxic-gas detection, noninvasive medical diagnostics and industrial process control, require sensitive and selectivedetection of gas traces with concentrations in the parts in 109 (ppb and sub-ppb range.The recent development of quantum-cascade lasers (QCLs has given a new aspect toinfrared laser-based trace gas sensors. In particular, single mode distributed feedback QCLsare attractive spectroscopic sources because of their excellent properties in terms of narrowlinewidth, average power and room temperature operation. In combination with these lasersources, photoacoustic spectroscopy offers the advantage of high sensitivity and selectivity,compact sensor platform, fast time-response and user friendly operation. This paper reportsrecent developments on quantum cascade laser-based photoacoustic spectroscopy for tracegas detection. In particular, different applications of a photoacoustic trace gas sensoremploying a longitudinal resonant cell with a detection limit on the order of hundred ppb ofozone and ammonia are discussed. We also report two QC laser-based photoacousticsensors for the detection of nitric oxide, for environmental pollution monitoring andmedical diagnostics, and hexamethyldisilazane, for applications in semiconductormanufacturing process.

  1. Laser ablation plume expansion into an ambient gas

    DEFF Research Database (Denmark)

    Amoruso, S.; Schou, Jørgen; Lunney, J.G.

    2009-01-01

    The use of an ambient gas is a well-established method employed in pulsed laser deposition (PLD) with nanosecond pulses and has been extensively studied in this context. Most of the existing treatments of the plume expansion are tackled by using complex numerical modeling involving specific target...

  2. Properties of a weakly ionized NO gas sensor based on multi-walled carbon nanotubes

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Jingyuan; Zhang, Yong, E-mail: zhyong@mail.xjtu.edu.cn; Pan, Zhigang; Yang, Shuang; Shi, Jinghui; Li, Shengtao; Min, Daomin; Wang, Xiaohua; Liu, Dingxin; Yang, Aijun [State Key Laboratory of Electrical Insulation and Power Equipment, Xi' an Jiaotong University, Xi' an 710-049 (China); Li, Xin [Vacuum Micro-Electronic and Micro-Electronic Mechanical Institute, School of Electronics and Information Engineering, Xi' an Jiaotong University, Xi' an 710049 (China)

    2015-08-31

    Nitric oxide NO is one of the major targets for environmental monitoring, but the existing NO sensors are limited by their low sensitivity and narrow test range. Here, a NO gas sensor employing multiwalled carbon nanotubes (MWCNTs) was fabricated, and its properties in NO–N{sub 2} mixture were investigated from both emission and ionization. The current I{sub e} passing through the nanotubes cathode was found to decrease with increasing NO concentration and increase linearly in different slopes with the extracting voltage U{sub e}. It is shown that the Schottky barrier of the MWCNTs calculated by I{sub e} increased with NO concentration due to the adsorption of NO gas, which restrained the electron emission and consequently weakened the ionization. The positive ion currents I{sub c} passing through the collecting electrode at different voltages of U{sub e} were found to monotonically decrease with increasing NO concentration, which was induced by both of the reduced electron emission and the consumption of the two excited metastable states N{sub 2}(A{sup 3}∑{sub u}{sup +}) and N{sub 2}(a′{sup 1}∑{sub u}{sup −}) by NO. The sensor exhibited high sensitivity at the low temperature of 30 °C. The calculated conductivity was found to be able to take place of I{sub c} for NO detection in a wide voltage range of 80–150 V U{sub e}.

  3. Laser Accelerated Ions from a Shock Compressed Gas Foil

    CERN Document Server

    Helle, M H; Kaganovich, D; Chen, Y; Palastro, J P; Ting, A

    2016-01-01

    We present results of energetic laser-ion acceleration from a tailored, near solid density gas target. Colliding hydrodynamic shocks compress a pure hydrogen gas jet into a 70 {\\mu}m thick target prior to the arrival of the ultra-intense laser pulse. A density scan reveals the transition from a regime characterized by a wide angle, low energy beam to one of a more focused beam with a high energy halo. In the latter case, three dimensional simulations show the formation of a Z-pinch driven by the axial current resulting from laser wakefield accelerated electrons. Ions at the rear of the target are then accelerated by a combination of space charge fields from accelerated electrons and Coulombic repulsion as the pinch dissipates.

  4. The Connection Between Reddening, Gas Covering Fraction, and the Escape of Ionizing Radiation at High Redshift

    Science.gov (United States)

    Reddy, Naveen A.; Steidel, Charles C.; Pettini, Max; Bogosavljević, Milan; Shapley, Alice E.

    2016-09-01

    Using a large sample of spectroscopically confirmed z∼ 3 galaxies, we establish an empirical relationship between reddening (E(B-V)), neutral gas covering fraction ({f}{{cov}}({{H}} {{I}})), and the escape of ionizing (Lyman continuum, LyC) photons. Our sample includes 933 galaxies at z∼ 3,121 of which have deep spectroscopic observations (≳ 7 hr) at 850≲ {λ }{{rest}}≲ 1300 Å with the Low Resolution Imaging Spectrograph on Keck. The high covering fraction of outflowing optically thick {{H}} {{I}} indicated by the composite spectra of these galaxies implies that photoelectric absorption, rather than dust attenuation, dominates the depletion of LyC photons. By modeling the composite spectra as the combination of an unattenuated stellar spectrum including nebular continuum emission with one that is absorbed by {{H}} {{I}} and reddened by a line-of-sight extinction, we derive an empirical relationship between E(B-V) and {f}{{cov}}({{H}} {{I}}). Galaxies with redder UV continua have larger covering fractions of {{H}} {{I}} characterized by higher line-of-sight extinctions. We develop a model which connects the ionizing escape fraction with E(B-V), and which may be used to estimate the ionizing escape fraction for an ensemble of galaxies. Alternatively, direct measurements of the escape fraction for our sample allow us to constrain the intrinsic LyC-to-UV flux density ratio to be }{{int}}≳ 0.20, a value that favors stellar population models that include weaker stellar winds, a flatter initial mass function, and/or binary evolution. Last, we demonstrate how the framework discussed here may be used to assess the pathways by which ionizing radiation escapes from high-redshift galaxies. Based on data obtained at the W.M. Keck Observatory, which is operated as a scientific partnership among the California Institute of Technology, the University of California, and NASA, and was made possible by the generous financial support of the W.M. Keck Foundation.

  5. Internal standards for use in the comprehensive analysis of polychlorinated aromatic hydrocarbons using gas chromatography combined with multiphoton ionization mass spectrometry.

    Science.gov (United States)

    Li, Adan; Imasaka, Totaro

    2016-10-28

    To decrease health-risks to humans, non-toxic compounds were evaluated for use as internal standards for calibrating data obtained by gas chromatography/multiphoton ionization mass spectrometry (GC-MPI-MS) using an ultraviolet femtosecond laser as the ionization source. The retention time in the mass chromatogram was calibrated using a retention index, in which a series of n-alkanes was employed as internal standards for evaluating the retention times for polychlorinated dibenzo-p-dioxins (PCDDs), polychlorinated dibenzofurans (PCDFs), and polychlorinated biphenyls (PCBs). To compensate for changes in signal intensity in MPI-MS, the dependence of signal intensity on the laser pulse energy was investigated for the dioxin-like compounds, in addition to five non-toxic aromatic hydrocarbons, that were used as internal standards. Based on their similar behavior,the non-toxic PCDD/PCDF, its (13)C-isotope, and pentachlorobenzene behave similarly, we conclude that they can be used for calibrating the signal intensities in MPI-MS. Copyright © 2016 Elsevier B.V. All rights reserved.

  6. High-Intensity Femtosecond Laser Interaction with Rare Gas Clusters

    Institute of Scientific and Technical Information of China (English)

    林亚风; 钟钦; 曾淳; 陈哲

    2001-01-01

    With a 45 fs multiterawatt 790 nm laser system and jets of argon and krypton atomic clusters, a study of the interaction of fs intense laser pulses with large size rare gas dusters was conducted. The maximum laser intensity of about 7 × 1016 W/cm2 and dusters composed of thousands of atoms which were determined through Rayleigh scattering measurements were involved inthe experiments. On the one hand, the results indicate that the interaction is strongly cluster size dependent. The stronger the interaction, the larger the clusters are. On the other hand, a saturation followed by a drop of the energy of ions ejected from the interaction will occur when the laser intensity exceeds a definite value for clusters of a certain size.

  7. Novel Galvanic Nanostructures of Ag and Pd for Efficient Laser Desorption/Ionization of Low Molecular Weight Compounds

    Science.gov (United States)

    Silina, Yuliya E.; Meier, Florian; Nebolsin, Valeriy A.; Koch, Marcus; Volmer, Dietrich A.

    2014-05-01

    A simple approach for synthesis of palladium and silver nanostructures with readily adjustable morphologies was developed using galvanic electrochemical deposition, for application to surface-assisted laser desorption/ionization (SALDI) of small biological molecules. A range of fatty acids, triglycerides, carbohydrates, and antibiotics were investigated to assess the performance of the new materials. Intense analyte cations were generated from the galvanic surfaces upon UV laser irradiation such as potassium adducts for a film thickness 120 nm. Possible laser desorption/ionization mechanisms of these galvanic structures are discussed. The films exhibited self-organizing abilities and adjustable morphologies by changing electrochemical parameters. They did not require any stabilizing agents and were inexpensive and very easy to produce. SALDI analysis showed that the materials were stable under ambient conditions and analytical results with excellent measurement reproducibility and detection sensitivity similar to MALDI were obtained. Finally, we applied the galvanic surfaces to fast screening of natural oils with minimum sample preparation.

  8. Ionized gas kinematics of galaxies in the CALIFA survey. I. Velocity fields, kinematic parameters of the dominant component, and presence of kinematically distinct gaseous systems

    NARCIS (Netherlands)

    García-Lorenzo, B.; Márquez, I.; Barrera-Ballesteros, J. K.; Masegosa, J.; Husemann, B.; Falcón-Barroso, J.; Lyubenova, M.; Sánchez, S. F.; Walcher, J.; Mast, D.; García-Benito, R.; Méndez-Abreu, J.; van de Ven, G.; Spekkens, K.; Holmes, L.; Monreal-Ibero, A.; del Olmo, A.; Ziegler, B.; Bland-Hawthorn, J.; Sánchez-Blázquez, P.; Iglesias-Páramo, J.; Aguerri, J. A. L.; Papaderos, P.; Gomes, J. M.; Marino, R. A.; González Delgado, R. M.; Cortijo-Ferrero, C.; López-Sánchez, A. R.; Bekeraitė, S.; Wisotzki, L.; Bomans, D.

    2015-01-01

    Context. Ionized gas kinematics provide important clues to the dynamical structure of galaxies and hold constraints to the processes driving their evolution. Aims: The motivation of this work is to provide an overall characterization of the kinematic behavior of the ionized gas of the galaxies inclu

  9. Advantages of Atmospheric Pressure Chemical Ionization in Gas Chromatography Tandem Mass Spectrometry: Pyrethroid Insecticides as a Case Study

    NARCIS (Netherlands)

    Portolés, T.; Mol, J.G.J.; Sancho, J.V.; Hernández, F.

    2012-01-01

    Gas chromatography coupled to mass spectrometry (GC/MS) has been extensively applied for determination of volatile, nonpolar, compounds in many applied fields like food safety, environment, or toxicology. The wide majority of methods reported use electron ionization (EI), which may result in extensi

  10. Evaluation of gas chromatography – electron ionization – full scan high resolution Orbitrap mass spectrometry for pesticide residue analysis

    NARCIS (Netherlands)

    Mol, Hans G.J.; Tienstra, Marc; Zomer, Paul

    2016-01-01

    Gas chromatography with electron ionization and full scan high resolution mass spectrometry with an Orbitrap mass analyzer (GC-EI-full scan Orbitrap HRMS) was evaluated for residue analysis. Pesticides in fruit and vegetables were taken as an example application. The relevant aspects for GC-MS

  11. Determination of BROMATE AT PARTS-PER-TRILLION LEVELS BY GAS CHROMATOGRAPHY-MASS SPECTROMETRY WITH NEGATIVE CHEMICAL IONIZATION

    Science.gov (United States)

    The ozonation of bromide-containing source waters produces bromate as a class 2B carcinogenic disinfection by-product. The present work describes the determination of bromate by gas chromatography-negative chemical ionization mass spectrometry (GC-NCIMS) following a bromate react...

  12. Enhanced capabilities for imaging gangliosides in murine brain with matrix-assisted laser desorption/ionization and desorption electrospray ionization mass spectrometry coupled to ion mobility separation.

    Science.gov (United States)

    Škrášková, Karolina; Claude, Emmanuelle; Jones, Emrys A; Towers, Mark; Ellis, Shane R; Heeren, Ron M A

    2016-07-15

    The increased interest in lipidomics calls for improved yet simplified methods of lipid analysis. Over the past two decades, mass spectrometry imaging (MSI) has been established as a powerful technique for the analysis of molecular distribution of a variety of compounds across tissue surfaces. Matrix-assisted laser desorption/ionization (MALDI) MSI is widely used to study the spatial distribution of common lipids. However, a thorough sample preparation and necessity of vacuum for efficient ionization might hamper its use for high-throughput lipid analysis. Desorption electrospray ionization (DESI) is a relatively young MS technique. In DESI, ionization of molecules occurs under ambient conditions, which alleviates sample preparation. Moreover, DESI does not require the application of an external matrix, making the detection of low mass species more feasible due to the lack of chemical matrix background. However, irrespective of the ionization method, the final information obtained during an MSI experiment is very complex and its analysis becomes challenging. It was shown that coupling MSI to ion mobility separation (IMS) simplifies imaging data interpretation. Here we employed DESI and MALDI MSI for a lipidomic analysis of the murine brain using the same IMS-enabled instrument. We report for the first time on the DESI IMS-MSI of multiply sialylated ganglioside species, as well as their acetylated versions, which we detected directly from the murine brain tissue. We show that poly-sialylated gangliosides can be imaged as multiply charged ions using DESI, while they are clearly separated from the rest of the lipid classes based on their charge state using ion mobility. This represents a major improvement in MSI of intact fragile lipid species. We additionally show that complementary lipid information is reached under particular conditions when DESI is compared to MALDI MSI.

  13. Formation of Metal-Related Ions in Matrix-Assisted Laser Desorption Ionization

    Science.gov (United States)

    Lee, Chuping; Lu, I.-Chung; Hsu, Hsu Chen; Lin, Hou-Yu; Liang, Sheng-Ping; Lee, Yuan-Tseh; Ni, Chi-Kung

    2016-09-01

    In a study of the metal-related ion generation mechanism in matrix-assisted laser desorption ionization (MALDI), crystals of matrix used in MALDI were grown from matrix- and salt-containing solutions. The intensities of metal ion and metal adducts of the matrix ion obtained from unwashed crystals were higher than those from crystals washed with deionized water, indicating that metal ions and metal adducts of the matrix ions are mainly generated from the surface of crystals. The contributions of preformed metal ions and metal adducts of the matrix ions inside the matrix crystals were minor. Metal adducts of the matrix and analyte ion intensities generated from a mixture of dried matrix, salt, and analyte powders were similar to or higher than those generated from the powder of dried droplet crystals, indicating that the contributions of the preformed metal adducts of the matrix and analyte ions were insignificant. Correlation between metal-related ion intensity fluctuation and protonated ion intensity fluctuation was observed, indicating that the generation mechanism of the metal-related ions is similar to that of the protonated ions. Because the thermally induced proton transfer model effectively describes the generation of the protonated ions, we suggest that metal-related ions are mainly generated from the salt dissolution in the matrix melted by the laser.

  14. Very metal-poor galaxies: ionized gas kinematics in nine objects

    CERN Document Server

    Moiseev, A V; Kniazev, A Y

    2010-01-01

    The study of ionized gas morphology and kinematics in nine eXtremely Metal-Deficient (XMD) galaxies with the scanning Fabry-Perot interferometer on the SAO 6-m telescope is presented. Some of these very rare objects (with currently known range of O/H of 7.12 < 12+log(O/H) < 7.65, or Zo/35 < Z < Zo/10) are believed to be the best proxies of `young' low-mass galaxies in the high-redshift Universe. One of the main goals of this study is to look for possible evidence of star formation (SF) activity induced by external perturbations. Recent results from HI mapping of a small subsample of XMD star-forming galaxies provided confident evidence for the important role of interaction-induced SF. Our observations provide complementary or new information that the great majority of the studied XMD dwarfs have strongly disturbed gas morphology and kinematics or the presence of detached components. We approximate the observed velocity fields by simple models of a rotating tilted thin disc, which allow us the robu...

  15. Dust trap formation in a non-self-sustained discharge with external gas ionization

    Energy Technology Data Exchange (ETDEWEB)

    Filippov, A. V., E-mail: fav@triniti.ru; Babichev, V. N.; Pal’, A. F.; Starostin, A. N.; Cherkovets, V. E.; Rerikh, V. K.; Taran, M. D. [Troitsk Institute for Innovation and Fusion Research (Russian Federation)

    2015-11-15

    Results from numerical studies of a non-self-sustained gas discharge containing micrometer dust grains are presented. The non-self-sustained discharge (NSSD) was controlled by a stationary fast electron beam. The numerical model of an NSSD is based on the diffusion drift approximation for electrons and ions and self-consistently takes into account the influence of the dust component on the electron and ion densities. The dust component is described by the balance equation for the number of dust grains and the equation of motion for dust grains with allowance for the Stokes force, gravity force, and electric force in the cathode sheath. The interaction between dust grains is described in the self-consistent field approximation. The height of dust grain levitation over the cathode is determined and compared with experimental results. It is established that, at a given gas ionization rate and given applied voltage, there is a critical dust grain size above which the levitation condition in the cathode sheath cannot be satisfied. Simulations performed for the dust component consisting of dust grains of two different sizes shows that such grains levitate at different heights, i.e., size separation of dust drains levitating in the cathode sheath of an NSSD takes place.

  16. Ionized gas kinematics within the inner kiloparsec of the Seyfert galaxy NGC 1365

    CERN Document Server

    Lena, Davide; Storchi-Bergmann, Thaisa; Couto, Guilherme S; Schnorr-Muller, Allan; Riffel, Rogemar A

    2016-01-01

    We observed the nuclear region of the galaxy NGC 1365 with the integral field unit of the Gemini Multi Object Spectrograph mounted on the GEMINI-South telescope. The field of view covers $13^{\\prime\\prime} \\times 6^{\\prime\\prime}$ ($1173 \\times 541$ pc$^{2}$) centered on the nucleus, at a spatial resolution of $52$ pc. The spectral coverage extends from $5600$ \\AA\\ to $7000$ \\AA, at a spectral resolution $R=1918$. NGC 1365 hosts a Seyfert 1.8 nucleus, and exhibits a prominent bar extending out to $100^{\\prime\\prime}$ (9 kpc) from the nucleus. The field of view lies within the inner Lindblad resonance. Within this region, we found that the kinematics of the ionized gas (as traced by [OI], [NII], H$\\alpha$, and [SII]) is consistent with rotation in the large-scale plane of the galaxy. While rotation dominates the kinematics, there is also evidence for a fan-shaped outflow, as found in other studies based on the [OIII] emission lines. Although evidence for gas inflowing along nuclear spirals has been found in a ...

  17. Numerical studies of the behavior of ionized residual gas in an energy recovering linac

    Science.gov (United States)

    Pöplau, Gisela; van Rienen, Ursula; Meseck, Atoosa

    2015-04-01

    Next generation light sources such as energy recovering linacs (ERLs) are highly sensitive to instabilities due to ionized residual gas, which must be mitigated for successful operation. Vacuum pumps are insufficient for removal of the ions, as the ions are trapped by the beam's electrical potential. Two effective measures are (i) introducing clearing gaps in the bunch train, and (ii) installing clearing electrodes which pull out the trapped ions from the electrical potential of the beam. In this paper, we present numerical studies on the behavior of ion clouds that interact with bunch trains in an ERL taking into account the effects of the clearing gaps and clearing electrodes. We present simulations with different compositions of the residual gas. Simulations are done using the MOEVE PIC Tracking software package developed at Rostock University, which has been upgraded to include the behavior of ion clouds in the environment of additional electromagnetic fields, such as generated by clearing electrodes. The simulations use the parameters of the Berlin Energy Recovery Linac Project (bERLinPro) to allow for the deduction of appropriate measures for bERLinPro 's design and operation.

  18. The Prevalence of Ionized Gas Outflows in Type 2 AGNs II. 3-D Biconical Outflow Models

    CERN Document Server

    Bae, Hyun-Jin

    2016-01-01

    We present 3-D models of biconical outflows combined with a thin dust plane for investigating the physical properties of the ionized gas outflows and their effect on the observed gas kinematics in type 2 active galactic nuclei (AGNs). Using a set of input parameters, we construct a number of models in 3-D and calculate the spatially integrated velocity and velocity dispersion for each model. We find that three primary parameters, i.e., intrinsic velocity, bicone inclination, and the amount of dust extinction, mainly determine the simulated velocity and velocity dispersion. Velocity dispersion increases as the intrinsic velocity or the bicone inclination increases, while velocity (i.e., velocity shift with respect to systemic velocity) increases as the amount of dust extinction increases. Simulated emission-line profiles well reproduce the observed [O III] line profiles, e.g., a narrow core and a broad wing components. By comparing model grids and Monte Carlo simulations with the observed [O III] velocity-velo...

  19. Gas-phase pesticide measurement using iodide ionization time-of-flight mass spectrometry

    Directory of Open Access Journals (Sweden)

    T. Murschell

    2017-06-01

    Full Text Available Volatilization and subsequent processing in the atmosphere are an important environmental pathway for the transport and chemical fate of pesticides. However, these processes remain a particularly poorly understood component of pesticide lifecycles due to analytical challenges in measuring pesticides in the atmosphere. Most pesticide measurements require long (hours to days sampling times coupled with offline analysis, inhibiting observation of meteorologically driven events or investigation of rapid oxidation chemistry. Here, we present chemical ionization time-of-flight mass spectrometry with iodide reagent ions as a fast and sensitive measurement of four current-use pesticides. These semi-volatile pesticides were calibrated with injections of solutions onto a filter and subsequently volatilized to generate gas-phase analytes. Trifluralin and atrazine are detected as iodide–molecule adducts, while permethrin and metolachlor are detected as adducts between iodide and fragments of the parent analyte molecule. Limits of detection (1 s are 0.37, 0.67, 0.56, and 1.1 µg m−3 for gas-phase trifluralin, metolachlor, atrazine, and permethrin, respectively. The sensitivities of trifluralin and metolachlor depend on relative humidity, changing as much as 70 and 59, respectively, as relative humidity of the sample air varies from 0 to 80 %. This measurement approach is thus appropriate for laboratory experiments and potentially near-source field measurements.

  20. Functionalization of silicon nanowire arrays by silver nanoparticles for the laser desorption ionization mass spectrometry analysis of vegetable oils.

    Science.gov (United States)

    Picca, Rosaria Anna; Calvano, Cosima Damiana; Lo Faro, Maria Josè; Fazio, Barbara; Trusso, Sebastiano; Ossi, Paolo Maria; Neri, Fortunato; D'Andrea, Cristiano; Irrera, Alessia; Cioffi, Nicola

    2016-09-01

    In this work, novel hybrid nanostructured surfaces, consisting of dense arrays of silicon nanowires (SiNWs) functionalized by Ag nanoparticles (AgNP/SiNWs), were used for the laser desorption/ionization time-of-flight mass spectrometry (LDI-TOF MS) analysis of some typical unsaturated food components (e.g. squalene, oleic acid) to assess their MS performance. The synthesis of the novel platforms is an easy, cost-effective process based on the maskless wet-etching preparation at room temperature of SiNWs followed by their decoration with AgNPs, produced by pulsed laser deposition. No particular surface pretreatment or addition of organic matrixes/ionizers was necessary. Moreover, oil extracts (e.g. extra virgin olive oil, peanut oil) could be investigated on AgNP/SiNWs surfaces, revealing their different MS profiles. It was shown that such substrates operate at reduced laser energy, typically generating intense silver cluster ions and analyte adducts. A comparison with bare SiNWs was also performed, indicating the importance of AgNP density on NW surface. In this case, desorption/ionization on silicon was invoked as probable LDI mechanism. Finally, the influence of SiNW length and surface composition on MS results was assessed. The combination of typical properties of SiNWs (hydrophobicity, antireflectivity) with ionization ability of metal NPs can be a valid methodology for the further development of nanostructured surfaces in LDI-TOF MS applications. Copyright © 2016 John Wiley & Sons, Ltd.

  1. The ionized gas in the central region of NGC 5253: 2D mapping of the physical and chemical properties

    CERN Document Server

    Monreal-Ibero, Ana; Vilchez, Jose M

    2012-01-01

    ABRIDGED: NGC5253 was previously studied by our group with the aim to elucidate in detail the starburst interaction processes. Some open issues regarding the 2D structure of the main properties of the ionized gas remain to be addressed. Using IFS data obtained with FLAMES, we derived 2D maps for different tracers of electron density (n_e), electron temperature (T_e) and ionization degree. The maps for n_e as traced by several line ratios are compatible with a 3D stratified view of the nebula with the highest n_e in the innermost layers and a decrease of n_e outwards. To our knowledge, this is the first time that a T_e map based on [SII] lines for an extragalactic object is presented. The joint interpretation of our two T_e maps is consistent with a T_e structure in 3D with higher temperatures close to the main ionizing source surrounded by a colder and more diffuse component. The highest ionization degree is found at the peak of emission for the gas with relatively high ionization in the main GHIIR and lower ...

  2. Resonant holographic measurements of laser ablation plume expansion in vacuum and argon gas backgrounds

    Energy Technology Data Exchange (ETDEWEB)

    Lindley, R.A. [Michigan Univ., Ann Arbor, MI (United States)

    1993-10-01

    This thesis discusses the following on resonant holographic measurements of laser ablation plume expansion: Introduction to laser ablation; applications of laser ablation; The study of plume expansion; holographic interferometry; resonant holographic interferometry; accounting for finite laser bandwidth; The solution for doppler broadening and finite bandwidth; the main optical table; the lumonics laser spot shape; developing and reconstructing the holograms; plume expansion in RF/Plasma Environments; Determining {lambda}{sub o}; resonant refraction effects; fringe shift interpretation; shot-to-shot consistency; laser ablation in vacuum and low pressure, inert, background gas; theoretically modeling plume expansion in vacuum and low pressure, inert, background gas; and laser ablation in higher pressure, inert, background gas.

  3. Use of electron ionization and atmospheric pressure chemical ionization in gas chromatography coupled to time-of-flight mass spetrometry for screening and identification of organic pollutants in waters

    NARCIS (Netherlands)

    Portoles, T.; Mol, J.G.J.; Sancho, J.V.; Hernandez, F.

    2014-01-01

    A new approach has been developed for multiclass screening of organic contaminants in water based on the use of gas chromatography coupled to hybrid quadrupole high-resolution time-of-flight mass spectrometry with atmospheric pressure chemical ionization (GC–(APCI)QTOF MS). The soft ionization promo

  4. Single shot laser multiphoton ionization detection of UF/sub 5/ following the 266 nm photodissociation of UF/sub 6/

    Energy Technology Data Exchange (ETDEWEB)

    Chou, J.S.; Sumida, D.; Stuke, M.; Wittig, C.

    1982-10-01

    By using laser multiphoton ionization and time-of-flight mass filter, nascent uranium pentafluoride has been detected from the 266 nm laser photodissociation of uranium hexafluoride, following a single laser firing. The method can be used to monitor these species under conditions wherein isotopically selective excitation is responsible for the dissociation of uranium hexafluoride. 10 references, 2 figures.

  5. In-gas-cell laser spectroscopy for magnetic dipole moment of $^{199}$Pt toward $N=$ 126

    CERN Document Server

    Hirayama, Y; Watanabe, Y X; Jeong, S C; Jung, H S; Kakiguchi, Y; Kimura, S; Moon, J Y; Oyaizu, M; Park, J H; Schury, P; Wada, M; Miyatake, H

    2016-01-01

    Magnetic dipole moment and mean-square charge radius of $^{199}$Pt ($I^{\\pi}=$ 5/2$^-$) have been evaluated for the first time from the investigation of the hyperfine splitting of the $\\lambda_1=$ 248.792 nm transition by in-gas-cell laser ionization spectroscopy. Neutron-rich nucleus $^{199}$Pt was produced by multi-nucleon transfer reaction at the KISS where the nuclear spectroscopy in the vicinity of $N=$ 126 is planed from the aspect of an astrophysical interest as well as the nuclear structure. Measured magnetic dipole moment $+$0.63(13)$\\mu_{\\rm N}$ is consistent with the systematics of those of nuclei with $I^{\\pi}=$ 5/2$^-$. The deformation parameter $|^{1/2}|$ evaluated from the isotope shift indicates the gradual shape change to spherical shape of platinum isotopes with increasing neutron number toward $N=$ 126.

  6. A Study of the r-Process Path Nuclides,$^{137,138,139}$Sb using the Enhanced Selectivity of Resonance Ionization Laser Ionization

    CERN Multimedia

    Walters, W

    2002-01-01

    The particular features of the r-process abundances with 100 < A < 150 have demonstrated the close connection between knowledge of nuclear structure and decay along the r-process path and the astrophysical environement in which these elements are produced. Key to this connection has been the measurement of data for nuclides (mostly even-N nuclides) that lie in the actual r-process path. Such data are of direct use in r-process calculations and they also serve to refine and test the predictive power of nuclear models where little or no data now exist. In this experiment we seek to use the newly developed ionization scheme for the Resonance Ionization Laser Ion Source (RILIS) to achieve selective ionization of neutron-rich antimony isotopes in order to measure the decay properties of r-process path nuclides $^{137,138,139}$Sb. These properties include the half-lives, delayed neutron branches, and daughter $\\gamma$-rays. The new nuclear structure data for the daughter Te nuclides is also of considerable in...

  7. Depth profiling of inks in authentic and counterfeit banknotes by electrospray laser desorption ionization/mass spectrometry.

    Science.gov (United States)

    Kao, Yi-Ying; Cheng, Sy-Chyi; Cheng, Chu-Nian; Shiea, Jentaie

    2016-01-01

    Electrospray laser desorption ionization is an ambient ionization technique that generates neutrals via laser desorption and ionizes those neutrals in an electrospray plume and was utilized to characterize inks in different layers of copy paper and banknotes of various currencies. Depth profiling of inks was performed on overlapping color bands on copy paper by repeatedly scanning the line with a pulsed laser beam operated at a fixed energy. The molecules in the ink on a banknote were desorbed by irradiating the banknote surface with a laser beam operated at different energies, with results indicating that different ions were detected at different depths. The analysis of authentic $US100, $100 RMB and $1000 NTD banknotes indicated that ions detected in 'color-shifting' and 'typography' regions were significantly different. Additionally, the abundances of some ions dramatically changed with the depth of the aforementioned regions. This approach was used to distinguish authentic $1000 NTD banknotes from counterfeits. Copyright © 2015 John Wiley & Sons, Ltd. Copyright © 2015 John Wiley & Sons, Ltd.

  8. Simulation of ionization-front-forming process at injection of relativistic electron beam with a gas chamber

    Energy Technology Data Exchange (ETDEWEB)

    Dolya, S.N.; Zhidkov, E.P.; Rubin, S.B.; Semerdzhiev, Kh.I.

    1982-01-01

    The methodical work on creation of computer program for numerical study of the processes of forming and motion of a virtual cathode at the injection of relativistic electron beam into a short cylindrical chamber, filled with gas, has been carried out. The obtained plots of the distributions of fields, potential and density appearing out of ion and electron gas of the beam itself are presented. The dependence of cross-section ionization on the electron velocity has been taken into account at the calculation; the resonance contribution into summarized cross-section of ionization was simulated. It is shown that the injection into the chamber without gas, some oscillations of the virtual cathode are observed. At the presence of the final front of the beam, the fields level at the initial stage is smaller than for the beam with a sharp front. However, in some time the field amplitudes are compared. The motion of simulated probe ions in the chamber is analyzed.

  9. An ultraviolet/infrared matrix-assisted laser desorption ionization sample stage integrating scanning knife-edge and slit devices for laser beam analysis.

    Science.gov (United States)

    Soltwisch, Jens; Dreisewerd, Klaus

    2011-05-15

    A sample stage is described that allows the on-line analysis of laser intensity profiles and spot sizes directly in the ion source of a matrix-assisted laser desorption ionization (MALDI) mass spectrometer. The detector uses either a scanning knife-edge or a narrow slit in combination with diffusing disks for scattering of photons and a pyroelectric sensor for recording the light pulses. The setup was integrated into the sample holder of a oMALDI2(TM) ion source (AB Sciex) and allows parallel analysis of UV- and IR-laser beams at typical UV-/IR-MALDI laser fluences. The concept could be especially useful for a precise control of the laser spot size in MALDI imaging applications. Copyright © 2011 John Wiley & Sons, Ltd.

  10. HST/COS Observations of Ionized Gas Accretion at the Disk–Halo Interface of M33

    Science.gov (United States)

    Zheng, Y.; Peek, J. E. G.; Werk, J. K.; Putman, M. E.

    2017-01-01

    We report the detection of accreting ionized gas at the disk–halo interface of the nearby galaxy M33. We analyze Hubble Space Telescope/Cosmic Origins Spectrograph absorption-line spectra of seven ultraviolet-bright stars evenly distributed across the disk of M33. We find Si iv absorption components consistently redshifted relative to the bulk M33's ISM absorption along all the sightlines. The Si iv detection indicates an enriched, disk-wide, ionized gas inflow toward the disk. This inflow is most likely multi-phase as the redshifted components can also be observed in ions with lower ionization states (e.g., S ii, P ii, Fe ii, Si ii). Kinematic modeling of the inflow is consistent with an accreting layer at the disk–halo interface of M33, which has an accretion velocity of {110}-20+15 {km} {{{s}}}-1 at a distance of {1.5}-1.0+1.0 kpc above the disk. The modeling indicates a total mass of ∼3.9 × 107 M⊙ for the accreting material at the disk–halo interface on the near side of the M33 disk, with an accretion rate of ∼2.9 M⊙ yr‑1. The high accretion rate and the level of metal enrichment suggest the inflow is likely to be the fallback of M33 gas from a galactic fountain and/or the gas pulled loosed during a close interaction between M31 and M33. Our study of M33 is the first to unambiguously reveal the existence of a disk-wide, ionized gas inflow beyond the Milky Way, providing a better understanding of gas accretion in the vicinity of a galaxy disk.

  11. Laser-plasma interactions in large gas-filled hohlraums

    Energy Technology Data Exchange (ETDEWEB)

    Turner, R.E.; Powers, L.V.; Berger, R.L. [and others

    1996-06-01

    Indirect-drive targets planned for the National Ignition Facility (NIF) laser consist of spherical fuel capsules enclosed in cylindrical Au hohlraums. Laser beams, arranged in cylindrical rings, heat the inside of the Au wall to produce x rays that in turn heat and implode the capsule to produce fusion conditions in the fuel. Detailed calculations show that adequate implosion symmetry can be maintained by filling the hohlraum interior with low-density, low-Z gases. The plasma produced from the heated gas provides sufficient pressure to keep the radiating Au surface from expanding excessively. As the laser heats this gas, the gas becomes a relatively uniform plasma with small gradients in velocity and density. Such long-scale-length plasmas can be ideal mediums for stimulated Brillouin Scattering (SBS). SBS can reflect a large fraction of the incident laser light before it is absorbed by the hohlraum; therefore, it is undesirable in an inertial confinement fusion target. To examine the importance of SBS in NIF targets, the authors used Nova to measure SBS from hohlraums with plasma conditions similar to those predicted for high-gain NIF targets. The plasmas differ from the more familiar exploding foil or solid targets as follows: they are hot (3 keV); they have high electron densities (n{sub e}=10{sup 21}cm{sup {minus}3}); and they are nearly stationary, confined within an Au cylinder, and uniform over large distances (>2 mm). These hohlraums have <3% peak SBS backscatter for an interaction beam with intensities of 1-4 x 10{sup 15} W/cm{sup 2}, a laser wavelength of 0.351{micro}m, f/4 or f/8 focusing optics, and a variety of beam smoothing implementations. Based on these conditions the authors conclude that SBS does not appear to be a problem for NIF targets.

  12. Laser deposition of sulfonated phthalocyanines for gas sensors

    Energy Technology Data Exchange (ETDEWEB)

    Fitl, Premysl, E-mail: fitlp@vscht.cz [Department of Physics and Measurements, Institute of Chemical Technology Prague, Technicka 5, Prague 6 CZ-166 28 (Czech Republic); Department of Analysis of Functional Materials, Institute of Physics AS CR v.v.i, Na Slovance 1999/2, Prague 8 CZ-182 21 (Czech Republic); Vrnata, Martin; Kopecky, Dusan; Vlcek, Jan; Skodova, Jitka [Department of Physics and Measurements, Institute of Chemical Technology Prague, Technicka 5, Prague 6 CZ-166 28 (Czech Republic); Bulir, Jiri; Novotny, Michal; Pokorny, Petr [Department of Analysis of Functional Materials, Institute of Physics AS CR v.v.i, Na Slovance 1999/2, Prague 8 CZ-182 21 (Czech Republic)

    2014-05-01

    Thin layers of nickel and copper tetrasulfonated phthalocyanines (NiPcTS and CuPcTS) were prepared by Matrix Assisted Pulsed Laser Evaporation method. The depositions were carried out with KrF excimer laser (energy density of laser radiation E{sub L} = 0.1–0.5 J cm{sup −2}) from dimethylsulfoxide matrix. For both materials the ablation threshold E{sub L-th} was determined. The following properties of deposited layers were characterized: (a) chemical composition (FTIR spectra); (b) morphology (SEM and AFM portraits); and (c) impedance of gas sensors based on NiPcTS and CuPcTS layers in the presence of two analytes – hydrogen and ozone. The prepared sensors exhibit response to 1000 ppm of hydrogen and 100 ppb of ozone even at laboratory temperature.

  13. Laser deposition of sulfonated phthalocyanines for gas sensors

    Science.gov (United States)

    Fitl, Premysl; Vrnata, Martin; Kopecky, Dusan; Vlcek, Jan; Skodova, Jitka; Bulir, Jiri; Novotny, Michal; Pokorny, Petr

    2014-05-01

    Thin layers of nickel and copper tetrasulfonated phthalocyanines (NiPcTS and CuPcTS) were prepared by Matrix Assisted Pulsed Laser Evaporation method. The depositions were carried out with KrF excimer laser (energy density of laser radiation EL = 0.1-0.5 J cm-2) from dimethylsulfoxide matrix. For both materials the ablation threshold EL-th was determined. The following properties of deposited layers were characterized: (a) chemical composition (FTIR spectra); (b) morphology (SEM and AFM portraits); and (c) impedance of gas sensors based on NiPcTS and CuPcTS layers in the presence of two analytes - hydrogen and ozone. The prepared sensors exhibit response to 1000 ppm of hydrogen and 100 ppb of ozone even at laboratory temperature.

  14. Tailor-Made Stable Zr(IV)-Based Metal-Organic Frameworks for Laser Desorption/Ionization Mass Spectrometry Analysis of Small Molecules and Simultaneous Enrichment of Phosphopeptides.

    Science.gov (United States)

    Chen, Lianfang; Ou, Junjie; Wang, Hongwei; Liu, Zhongshan; Ye, Mingliang; Zou, Hanfa

    2016-08-10

    Although thousands of metal-organic frameworks (MOFs) have been fabricated and widely applied in gas storage/separations, adsorption, catalysis, and so on, few kinds of MOFs have been used as adsorption materials while simultaneously serving as matrixes to analyze small molecules for laser desorption/ionization mass spectrometry (LDI-MS). Herein, a new concept is introduced to design and synthesize MOFs as both adsorption materials and matrixes according to the structure of ligands and common matrixes. The proof of concept design was demonstrated by selection of 2,5-pyridinedicarboxylic acid (PDC) and 2,5-dihydroxyterephthalic acid (DHT) as ligands for synthesis of MOFs. Two Zr(IV)-based MOFs of UiO-66-PDC and UiO-66-(OH)2 were synthesized and applied for the first time as new matrixes for analysis of small molecules by matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI-TOF-MS). Both of them showed low matrix interferences, high ionization efficiency, and good reproducibility when used as matrixes. A variety of small molecules, including saccharides, amino acids, nucleosides, peptides, alkaline drugs, and natural products, were analyzed. In addition, UiO-66-(OH)2 exhibited potential for application in the quantitative determination of glucose and pyridoxal 5'-phosphate. Furthermore, thanks to its intrinsically large surface area and highly ordered pores, UiO-66-(OH)2 also showed sensitive and specific enrichment of phosphopeptides prior to MS analysis. These results demonstrated that this strategy can be used to efficiently screen tailor-made MOFs as matrixes to analyze small molecules by MALDI-TOF-MS.

  15. IZI: INFERRING THE GAS PHASE METALLICITY (Z) AND IONIZATION PARAMETER (q) OF IONIZED NEBULAE USING BAYESIAN STATISTICS

    Energy Technology Data Exchange (ETDEWEB)

    Blanc, Guillermo A. [Observatories of the Carnegie Institution for Science, 813 Santa Barbara Street, Pasadena, CA 91101 (United States); Kewley, Lisa; Vogt, Frédéric P. A.; Dopita, Michael A. [Research School of Astronomy and Astrophysics, Australian National University, Cotter Road, Weston, ACT 2611 (Australia)

    2015-01-10

    We present a new method for inferring the metallicity (Z) and ionization parameter (q) of H II regions and star-forming galaxies using strong nebular emission lines (SELs). We use Bayesian inference to derive the joint and marginalized posterior probability density functions for Z and q given a set of observed line fluxes and an input photoionization model. Our approach allows the use of arbitrary sets of SELs and the inclusion of flux upper limits. The method provides a self-consistent way of determining the physical conditions of ionized nebulae that is not tied to the arbitrary choice of a particular SEL diagnostic and uses all the available information. Unlike theoretically calibrated SEL diagnostics, the method is flexible and not tied to a particular photoionization model. We describe our algorithm, validate it against other methods, and present a tool that implements it called IZI. Using a sample of nearby extragalactic H II regions, we assess the performance of commonly used SEL abundance diagnostics. We also use a sample of 22 local H II regions having both direct and recombination line (RL) oxygen abundance measurements in the literature to study discrepancies in the abundance scale between different methods. We find that oxygen abundances derived through Bayesian inference using currently available photoionization models in the literature can be in good (∼30%) agreement with RL abundances, although some models perform significantly better than others. We also confirm that abundances measured using the direct method are typically ∼0.2 dex lower than both RL and photoionization-model-based abundances.

  16. Fibre lasers for photo-acoustic gas spectroscopy

    Science.gov (United States)

    Arsad, Norhana; Stewart, George

    2011-05-01

    We report here on the use of fiber lasers for recovery of gas absorption line shapes by photo-acoustic spectroscopy. We demonstrate the principle of operation using an erbium-doped fiber, stabilized using a length of un-pumped doped fibre as a saturable absorber. Intensity modulation of the laser output for phase sensitive detection is performed by modulation of the pump current while the wavelength is scanned through the absorption line by a PZT on a fibre Bragg grating. This avoids the distortions that arise in recovered signals due to simultaneous wavelength and intensity modulation, as is the case with conventional DFB diode lasers. Furthermore, the near zero off-line signals with photo-acoustic spectroscopy means that high modulation indices can be used with simple intensity modulation of the fiber laser output. The modulation frequency is set to the acoustic resonance frequency of the gas cell and measurements are made on the P17 absorption line of acetylene at 1535.39nm showing good agreement with the theoretical line-shape profile.

  17. Use of x-ray radiation to preionize the active medium in high-pressure gas lasers

    Energy Technology Data Exchange (ETDEWEB)

    Kozyrev, A.V.; Korolev, Y.D.; Mesyats, G.A.; Novoselov, Y.N.; Prokhorov, A.M.; Skakun, V.S.; Tarasenko, V.F.; Genkin, S.A.

    1984-03-01

    Estimates are given of the ionization of a gas by x-ray radiation and it is shown that it is possible to lower the x-ray quantum energy to 50 keV with no significant loss in the utilization efficiency of the radiation. The results are given of an experimental investigation of an XeCl laser using x-ray preionization. The specific output energy obtained (>1 J/liter) confirmed the efficiency of using x rays for preionization. The state of the surfaces and of the electrode design influenced the output energy.

  18. Application of parylene for surface (polymer) enhanced laser desorption/ionization of synthetic polymers.

    Science.gov (United States)

    Miksa, Beata J; Sochacki, Marek; Sroka-Bartnicka, Anna; Uznański, Paweł; Nosal, Andrzej; Potrzebowski, Marek J

    2013-04-15

    Synthetic polymers of molecular masses up to a few kDa can be analyzed without the use of any matrix by direct laser desorption/ionization mass spectrometry (LDI-MS). In this technique, the surface of the sample plate plays a crucial role, and many attempts have been made to understand the influence of the surface on the ease of desorption. Since this technique requires no tedious sample pretreatment, it is a promising method for the rapid characterization of various synthetic polymers. Parylene (poly(p-xylylenes), PPX) was tested as a surface support for studying the molecular masses of biocompatible polymers: poly(ethylene glycol) (PEG), poly(L-lactide) (PLLA), and poly(methyl methacrylate) (PMMA). The average molecular masses of the polymers were: PEG (600.0 Da and 3.5 kDa), PMMA (2.0 kDa), and PLLA (2.8 kDa). LDI mass spectra of polymers deposited on parylene were enhanced by a factor of two over those obtained directly from the gold target plate. Modification of the surface of the target plate by the addition of a PPX layer extended the functionality of LDI-TOF MS, especially for the analysis of low-mass compounds. The LDI analysis using the PPX-coated target plate provided details of polymers including: end-group, composition, monomer unit, and molecular mass distribution. The average molecular weights of four tested polymers on the gold target plate and the PPX support were unchanged, indicating that sample degradation was not occurring despite the high energy of the laser beam. The LDI investigations showed that the PPX support boosted ion yields by a factor of two compared with the gold target plate. Copyright © 2013 John Wiley & Sons, Ltd.

  19. Excitation, two-center interference and the orbital geometry in laser-induced nonsequential double ionization of diatomic molecules

    CERN Document Server

    Shaaran, T; Faria, C Figueira de Morisson

    2011-01-01

    We address the influence of the molecular orbital geometry and of the molecular alignment with respect to the laser-field polarization on laser-induced nonsequential double ionization of diatomic molecules for different molecular species, namely $\\mathrm{N}_2$ and $\\mathrm{Li}_2$. We focus on the recollision excitation with subsequent tunneling ionization (RESI) mechanism, in which the first electron, upon return, promotes the second electron to an excited state, from where it subsequently tunnels. We show that the electron-momentum distributions exhibit interference maxima and minima due to the electron emission at spatially separated centers. We provide generalized analytical expressions for such maxima or minima, which take into account $s$ $p$ mixing and the orbital geometry. The patterns caused by the two-center interference are sharpest for vanishing alignment angle and get washed out as this parameter increases. Apart from that, there exist features due to the geometry of the lowest occupied molecular ...

  20. Ionization in Orthogonal Two-Color Laser Fields - Origin and Phase Dependence of Trajectory-Resolved Coulomb Effects

    CERN Document Server

    Richter, Martin; Schöffler, Markus; Jahnke, Till; Schmidt, Lothar Ph H; Dörner, Reinhard

    2016-01-01

    We report on electron momentum distributions from single ionization of Ar in strong orthogonally polarized two-color (OTC) laser fields measured with the COLTRIMS technique. We study the effect of Coulomb focusing whose signature is a cusp like feature in the center of the electron momentum spectrum. While the direct electrons show the expected strong dependence on the phase between the two colors, surprisingly the Coulomb focused structure is almost not influenced by the weak second harmonic streaking field. This effect is explained by the use of a CTMC simulation which describes the tunneled electron wave packet in terms of classical trajectories under the influence of the combined Coulomb- and OTC laser field. We find a subtle interplay between the initial momentum of the electron upon tunneling, the ionization phase and the action of the Coulomb field that makes the Coulomb focused part of the momentum spectrum apparently insensitive to the weaker streaking field.

  1. TiO(2) printed aluminum foil: single-use film for a laser desorption/ionization target plate.

    Science.gov (United States)

    Bi, Hongyan; Qiao, Liang; Busnel, Jean-Marc; Devaud, Valerie; Liu, Baohong; Girault, Hubert H

    2009-02-01

    Single-use aluminum foil-based laser desorption/ionization (LDI) target plates have been developed for mass spectrometry (MS) analysis and provide detection results comparable to those of commercial stainless steel plates while offering a convenient way to avoid the time-consuming surface cleaning process. Additionally, arrays of TiO(2) nanoparticle spots are coated on the foil either by screen-printing or rotogravure-printing followed by sintering to form a mesoporous layer spot to act as an anchor for sample deposition. These TiO(2) spots offer further functions to the Al foil, such as matrix-free laser desorption/ionization or specific affinity for in situ enrichment of phosphopeptides. The single-use TiO(2)-Al foils are cheap to produce, easy to use, and well suited for high-throughput proteomics research. They can also be of interest for protein post-translational modifications study.

  2. Supercritical carbon dioxide extraction of electrolyte from spent lithium ion batteries and its characterization by gas chromatography with chemical ionization

    Science.gov (United States)

    Mönnighoff, Xaver; Friesen, Alex; Konersmann, Benedikt; Horsthemke, Fabian; Grützke, Martin; Winter, Martin; Nowak, Sascha

    2017-06-01

    The aging products of the electrolyte from a commercially available state-of-the-art 18650-type cell were investigated. During long term cycling a huge difference in their performance and lifetime at different temperatures was observed. By interpretation of a strong capacity fading of cells cycled at 20 °C compared to cells cycled at 45 °C a temperature depending aging mechanism was determined. To investigate the influence of the electrolyte on this fading, the electrolyte was extracted by supercritical fluid extraction (SFE) and then analyzed by gas chromatography (GC) with electron impact (EI) ionization and mass selective detection. To obtain more information with regard to the identification of unknown decomposition products further analysis with positive chemical ionization (PCI) and negative chemical ionization (NCI) was performed. 17 different volatile organic aging products were detected and identified. So far, seven of them were not yet known in literature and several formation pathways were postulated taking previously published literature into account.

  3. Diffuse gas in retired galaxies: nebular emission templates and constraints on the sources of ionization

    Science.gov (United States)

    Johansson, Jonas; Woods, Tyrone E.; Gilfanov, Marat; Sarzi, Marc; Chen, Yan-Mei; Oh, Kyuseok

    2016-10-01

    We present emission-line templates for passively-evolving (`retired') galaxies, useful for investigation of the evolution of the interstellar medium in these galaxies, and characterization of their high-temperature source populations. The templates are based on high signal-to-noise (>800) co-added spectra (3700-6800 Å) of ˜11 500 gas-rich Sloan Digital Sky Survey galaxies devoid of star formation and active galactic nuclei. Stacked spectra are provided for the entire sample and sub-samples binned by mean stellar age. In our previous paper, Johansson et al., these spectra provided the first measurements of the He II 4686 Å line in passively-evolving galaxies, and the observed He II/Hβ ratio constrained the contribution of accreting white dwarfs (the `single-degenerate' scenario) to the Type Ia supernova rate. In this paper, the full range of unambiguously detected emission lines are presented. Comparison of the observed [O I] 6300 Å/Hα ratio with photoionization models further constrains any high-temperature single-degenerate scenario for Type Ia supernovae (with 1.5 ≲ T/105 K ≲ 10) to ≲3-6 per cent of the observed rate in the youngest age bin (i.e. highest SN Ia rate). Hence, for the same temperatures, in the presence of an ambient population of post-asymptotic giant branch stars, we exclude additional high-temperature sources with a combined ionizing luminosity of ≈1.35 × 1030 L⊙/M⊙,* for stellar populations with mean ages of 1-4 Gyr. Furthermore, we investigate the extinction affecting both the stellar and nebular continuum. The latter shows about five times higher values. This contradicts isotropically distributed dust and gas that renders similar extinction values for both cases.

  4. Hα and [SII] Emission from Warm Ionized Gas in the Scutum-Centaurus Arm

    Science.gov (United States)

    Hill, Alex S.; Benjamin, Robert A.; Haffner, L. Matthew; Gostisha, Martin C.; Barger, Kathleen A.

    2014-06-01

    We present Wisconsin H-Alpha Mapper [SII] λ6716 and Hα spectroscopic maps of the warm ionized medium (WIM) in the Scutum-Centaurus Arm at Galactic longitudes 310° extinction-corrected Hα intensities (I_{{H} \\alpha }^c), we measure an exponential scale height of electron density squared in the arm of H_{n_e^2}= 0.30 \\, {kpc} (assuming a distance of 3.5 kpc), intermediate between that observed in the inner Galaxy and in the Perseus Arm. The [S II]/Hα line ratio is enhanced at large |z| and in sightlines with faint I_{{H} \\alpha }^c. We find that the [S II]/Hα line ratio has a power-law relationship with I_{{H} \\alpha }^c from a value of ≈1.0 at I_{{H} \\alpha }^creinforce the well-established picture in which the diffuse Hα emission is due primarily to emission from in situ photoionized gas, with scattered light only a minor contributor.

  5. Nearby early-type galaxies with ionized gas VI. The Spitzer-IRS view

    CERN Document Server

    Panuzzo, P; Bressan, A; Vega, O; Annibali, F; Buson, L M; Clemens, M S; Zeilinger, W W

    2010-01-01

    We present low resolution Spitzer-IRS spectra of 40 ETGs, selected from a sample of 65 ETGs showing emission lines in their optical spectra. We homogeneously extract the mid-infrared (MIR) spectra, and after the proper subtraction of a "passive" ETG template, we derive the intensity of the ionic and molecular lines and of the polycyclic aromatic hydrocarbon emission features. We use MIR diagnostic diagrams to investigate the powering mechanisms of the ionized gas. The mid-infrared spectra of early-type galaxies show a variety of spectral characteristics. We empirically sub-divide the sample into five classes of spectra with common characteristics. Class-0, accounting for 20% of the sample, are purely passive ETGs with neither emission lines nor PAH features. Class-1 show emission lines but no PAH features, and account for 17.5% of the sample. Class-2, in which 50% of the ETGs are found, as well as having emission lines, show PAH features with unusual ratios, e.g. 7.7 {\\mu}m/11.3 {\\mu}m \\leq 2.3. Class-3 objec...

  6. Kinematical analysis of the ionized gas in the nuclear region of NGC 4214

    CERN Document Server

    Maíz-Appelániz, J; Mas-Hesse, J M; Tenorio-Tagle, G

    1999-01-01

    We present in this paper a detailed study of the kinematical properties of the ionized gas around the young massive star clusters in the nucleus of NGC 4214. The analysis is based on bidimensional spectroscopical data, allowing to derive the spatial variation of different properties (intensity, velocity and width / line splitting) of the emission lines H\\alpha and [O III] \\lambda 5007 along the nuclear region. We have found that the Giant H II region around the two most massive clusters in NGC 4214 (A and B) is resolved into two clearly separated regions. We have not detected superbubbles with the properties we would expect according to the evolutionary state of the stellar clusters, but just a partial ring feature around the most massive one and two expanding shells around cluster B. The first expanding shell seems to have experienced blowout, whereas the second one is still complete. A possible explanation to this phenomenon is that the most massive stars in a starburst spend a large fraction of their lives...

  7. ALMA View of the Galactic Center Mini-spiral: Ionized Gas Flows around Sagittarius A*

    CERN Document Server

    Tsuboi, Masato; Uehara, Kenta; Miyawaki, Ryosuke; Tsutsumi, Takahiro; Miyazaki, Atsushi; Miyoshi, Makoto

    2016-01-01

    We have performed the observation of the "Galactic Center Mini-spiral(GCMS)" in H42alpha recombination line as a part of the first large-scale mosaic observation in the Sagittarius A complex using Atacama Millimeter/sub-millimeter Array (ALMA). We revealed the kinematics of the ionized gas streamers of the GCMS. Especially we found that the streamer corresponding to the Bar of the GCMS has a Keplerian orbit with high eccentricity which is independent from the Keplerian orbits of the other streamers of the GCMS. The periastron is probably located within the Bondi accretion radius derived from X-ray observation. In addition, we estimated the LTE electron temperature in the sub-structures of the GCMS from the line-continuum flux density ratio. The electron temperatures are in the range of T* e=(6-13)x10^3 K. We confirmed the previously claimed tendency that the electron temperatures increase toward Sgr A*. We also found that the electron temperature at the positive velocity end of the Bar is twice as high as tha...

  8. Integral Field Unit Observations of NGC 4302: Kinematics of the Diffuse Ionized Gas Halo

    CERN Document Server

    Heald, G H; Benjamin, R A; Bershady, M A; Heald, George H.; Rand, Richard J.; Benjamin, Robert A.; Bershady, Matthew A.

    2007-01-01

    We present moderate resolution spectroscopy of extraplanar diffuse ionized gas (EDIG) emission in the edge-on spiral galaxy NGC 4302. The spectra were obtained with the SparsePak integral field unit (IFU) at the WIYN Observatory. The spectra are used to construct position-velocity (PV) diagrams at several ranges of heights above the midplane. Azimuthal velocities are directly extracted from the PV diagrams using the envelope tracing method, and indicate an extremely steep dropoff in rotational velocity with increasing height, with magnitude ~30 km/s/kpc. We find evidence for a radial variation in the velocity gradient on the receding side. We have also performed artificial observations of galaxy models in an attempt to match the PV diagrams. The results of a statistical analysis also favor a gradient of ~30 km/s/kpc. We compare these results with an entirely ballistic model of disk-halo flow, and find a strong dichotomy between the observed kinematics and those predicted by the model. The disagreement is wors...

  9. A new horizon in secondary neutral mass spectrometry: post-ionization using a VUV free electron laser

    Energy Technology Data Exchange (ETDEWEB)

    Veryovkin, Igor V.; Calaway, Wallis F.; Moore, Jerry F.; Pellin, Michael J.; Lewellen, John W.; Li, Yuelin; Milton, Stephen V.; King, Bruce V.; Petravic, Mladen

    2004-06-15

    A new time-of-flight (TOF) mass spectrometer incorporating post-ionization of sputtered neutral species with tunable vacuum ultraviolet (VUV) light generated by a free electron laser (FEL) has been developed. Capabilities of this instrument, called SPIRIT, were demonstrated by experiments with photoionization of sputtered neutral gold atoms with 125 nm light generated by the VUV FEL located at Argonne National Laboratory (ANL). In a separate series of experiments with a fixed wavelength VUV light source, a 157 nm F{sub 2} laser, a useful yield (atoms detected per atoms sputtered) of about 12% and a mass resolution better than 1500 were demonstrated for molybdenum.

  10. In situ diagnostics of the decomposition of silacyclobutane on a hot filament by vacuum ultraviolet laser ionization mass spectrometry.

    Science.gov (United States)

    Shi, Y J; Lo, B; Tong, L; Li, X; Eustergerling, B D; Sorensen, T S

    2007-05-01

    The gas-phase reaction products of silacyclobutane (SCB) and 1, 1-dideuterio-silacyclobutane (SCB-d(2)) from a hot-wire chemical vapor deposition (HWCVD) chamber were diagnosed in situ using vacuum ultraviolet (VUV) laser single-photon ionization (SPI) coupled with time-of-flight (TOF) mass spectrometry. The SCB molecule was found to decompose at a filament temperature as low as 900 degrees C. Both Si- (silylene, methylsilylene, and silene) and C-containing (ethene and propene) species were produced from the SCB decomposition on the filament. Ethene and propene were detected by the mass spectrometer. It is demonstrated that the formation of ethene is favored over that of propene. The experimental study of hot-wire decomposition of SCB-d(2) shows that propene is most likely produced by a process that is initiated by a 1,2-H(D) migration to form n-propylsilylene, followed by an equilibration with silacyclopropane, which then decomposes to propene. The detection of ethene in our experiment indicates that a competitive route of fragmentation exists for SCB decomposition on the filament. It has been shown that this competitive route occurs without H/D scrambling. The highly reactive silylene, silene, and methylsilylene species produced from SCB decomposition underwent either insertion reactions into the Si-H bonds of the parent molecule or pi-type addition reaction across the double and triple CC bonds. The dimerization product of silene, 1,3-disilacyclobutane, at m/z = 88 was also observed.

  11. Calibration of matrix-assisted laser desorption/ionization time-of-flight peptide mass fingerprinting spectra

    DEFF Research Database (Denmark)

    Hjernø, Karin; Højrup, Peter

    2007-01-01

    This chapter describes a number of aspects important for calibration of matrix-assisted laser desorption/ionization time-of-flight spectra prior to peptide mass fingerprinting searches. Both multipoint internal calibration and mass defect-based calibration is illustrated. The chapter describes ho...... potential internal calibrants, like tryptic autodigest peptides and keratin-related peptides, can be identified and used for high-precision calibration. Furthermore, the construction of project/user-specific lists of potential calibrants is illustrated....

  12. Application of nanodiamonds in human body fluid analysis by matrix-assisted laser desorption/ionization mass spectrometry

    Institute of Scientific and Technical Information of China (English)

    Xianglei Kong

    2008-01-01

    Direct mass spectrometric analysis of complex biological samples is very important and challenging. In this paper, nanodiamonds have been successfully used in matrix-assisted laser desorption/ionization mass spectrometric analysis of human serum and urine. As a practical tool and platform, it can be widely used in the field of humoral proteomics, and it plays a very promising role in clinical diagnosis, including identification of novel disease-associated biomarkers.

  13. Nanoparticle-assisted laser desorption/ionization mass spectrometry: Novel sample preparation methods and nanoparticle screening for plant metabolite imaging

    Energy Technology Data Exchange (ETDEWEB)

    Yagnik, Gargey B. [Iowa State Univ., Ames, IA (United States)

    2016-02-19

    The main goal of the presented research is development of nanoparticle based matrix-assisted laser desorption ionization-mass spectrometry (MALDI-MS). This dissertation includes the application of previously developed data acquisition methods, development of novel sample preparation methods, application and comparison of novel nanoparticle matrices, and comparison of two nanoparticle matrix application methods for MALDI-MS and MALDI-MS imaging.

  14. Black phosphorus-assisted laser desorption ionization mass spectrometry for the determination of low-molecular-weight compounds in biofluids.

    Science.gov (United States)

    He, Xiao-Mei; Ding, Jun; Yu, Lei; Hussain, Dilshad; Feng, Yu-Qi

    2016-09-01

    Quantitative analysis of small molecules by matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI-TOF MS) has been a challenging task due to matrix-derived interferences in low m/z region and poor reproducibility of MS signal response. In this study, we developed an approach by applying black phosphorus (BP) as a matrix-assisted laser desorption ionization (MALDI) matrix for the quantitative analysis of small molecules for the first time. Black phosphorus-assisted laser desorption/ionization mass spectrometry (BP/ALDI-MS) showed clear background and exhibited superior detection sensitivity toward quaternary ammonium compounds compared to carbon-based materials. By combining stable isotope labeling (SIL) strategy with BP/ALDI-MS (SIL-BP/ALDI-MS), a variety of analytes labeled with quaternary ammonium group were sensitively detected. Moreover, the isotope-labeled forms of analytes also served as internal standards, which broadened the analyte coverage of BP/ALDI-MS and improved the reproducibility of MS signals. Based on these advantages, a reliable method for quantitative analysis of aldehydes from complex biological samples (saliva, urine, and serum) was successfully established. Good linearities were obtained for five aldehydes in the range of 0.1-20.0 μM with correlation coefficients (R (2)) larger than 0.9928. The LODs were found to be 20 to 100 nM. Reproducibility of the method was obtained with intra-day and inter-day relative standard deviations (RSDs) less than 10.4 %, and the recoveries in saliva samples ranged from 91.4 to 117.1 %. Taken together, the proposed SIL-BP/ALDI-MS strategy has proved to be a reliable tool for quantitative analysis of aldehydes from complex samples. Graphical Abstract An approach for the determination of small molecules was developed by using black phosphorus (BP) as a matrix-assisted laser desorption ionization (MALDI) matrix.

  15. Dissociative ionization of H2+ using intense femtosecond XUV laser pulses

    CERN Document Server

    Yue, Lun

    2014-01-01

    The dissociative ionization of H2+ interacting with intense, femtosecond extreme-ultraviolet laser pulses is investigated theoretically. This is done by numerical propagation of the time-dependent Schr\\"{o}dinger equation for a colinear one-dimensional model of H2+, with electronic and nuclear motion treated exactly within the limitations of the model. The joint-energy spectra (JES) are extracted for the fragmented electron and nuclei by means of the t-SURFF method. The dynamic interference effect, which was first observed in one-electron atomic systems, is in the present work observed for H2+, emerging as interference patterns in the JES. The photoelectron spectrum and the nuclear energy spectrum is obtained by integration of the JES. Without the JES, the photoelectron spectrum itself is shown to be inadequate for the observation of the dynamic interference effect. The resulting JES are analyzed in terms of two models. In one model the wave function is expanded in terms of the "essential" states of the syste...

  16. Determination of stimulants using gas chromatography/high-resolution time-of-flight mass spectrometry and a soft ionization source.

    Science.gov (United States)

    Lopez-Avila, Viorica; Cooley, James; Urdahl, Randall; Thevis, Mario

    2012-12-15

    The aim of this study was to investigate the mass spectral fragmentation of a small set of stimulants in a high-resolution time-of-flight mass spectrometer equipped with a soft ionization source using vacuum ultraviolet (VUV) photons emitted from different plasma gases. It was postulated that the use of a plasma gas such as Xe, which emits photons at a lower energy than Kr or Ar, would lead to softer ionization of the test compounds, and thus to less fragmentation. A set of nine stimulants: cocaine, codeine, nicotine, methadone, phenmetrazine, pentylenetetrazole, niketamide, fencamfamine, and caffeine, was analyzed by gas chromatography/time-of-flight mass spectrometry (GC/TOFMS) in positive ion mode with this soft ionization source, using either Xe, Kr, or Ar as plasma gases. Working solutions of the test compounds at 0.1 to 100 ng/μL were used to establish instrument sensitivity and linearity. All test compounds, except methadone and pentylenetetrazole, exhibited strong molecular ions and no fragmentation with Xe-microplasma photoionization (MPPI). Methadone exhibited significant fragmentation not only with Xe, but also with Kr and Ar, and pentylenetetrazole could not be ionized with Xe, probably because its ionization energy is above 8.44 eV. The Kr- and Ar-MPPI mass spectra of the test compounds showed that the relative intensity of the molecular ion decreased as the photon energy increased. When coupled to a TOF mass spectrometer this soft ionization source has demonstrated signal-to-noise (S/N) ratios from 7 to 730 at 100 pg per injection (depending on the compound), and a dynamic range of three orders of magnitude (100 pg to 100 ng) for some of the test compounds. Copyright © 2012 John Wiley & Sons, Ltd.

  17. Effects of argon gas flow rate on laser-welding.

    Science.gov (United States)

    Takayama, Yasuko; Nomoto, Rie; Nakajima, Hiroyuki; Ohkubo, Chikahiro

    2012-01-01

    The purpose of this study was to evaluate the effects of the rate of argon gas flow on joint strength in the laser-welding of cast metal plates and to measure the porosity. Two cast plates (Ti and Co-Cr alloy) of the same metal were abutted and welded together. The rates of argon gas flow were 0, 5 and 10 L/min for the Co-Cr alloy, and 5 and 10 L/min for the Ti. There was a significant difference in the ratio of porosity according to the rate of argon gas flow in the welded area. Argon shielding had no significant effect on the tensile strength of Co-Cr alloy. The 5 L/min specimens showed greater tensile strength than the 10 L/min specimens for Ti. Laser welding of the Co-Cr alloy was influenced very little by argon shielding. When the rate of argon gas flow was high, joint strength decreased for Ti.

  18. Shield gas induced cracks during nanosecond-pulsed laser irradiation of Zr-based metallic glass

    Energy Technology Data Exchange (ETDEWEB)

    Huang, Hu; Noguchi, Jun; Yan, Jiwang [Keio University, Department of Mechanical Engineering, Faculty of Science and Technology, Yokohama (Japan)

    2016-10-15

    Laser processing techniques have been given increasing attentions in the field of metallic glasses (MGs). In this work, effects of two kinds of shield gases, nitrogen and argon, on nanosecond-pulsed laser irradiation of Zr-based MG were comparatively investigated. Results showed that compared to argon gas, nitrogen gas remarkably promoted the formation of cracks during laser irradiation. Furthermore, crack formation in nitrogen gas was enhanced by increasing the peak laser power intensity or decreasing the laser scanning speed. X-ray diffraction and micro-Raman spectroscopy indicated that the reason for enhanced cracks in nitrogen gas was the formation of ZrN. (orig.)

  19. Shield gas induced cracks during nanosecond-pulsed laser irradiation of Zr-based metallic glass

    Science.gov (United States)

    Huang, Hu; Noguchi, Jun; Yan, Jiwang

    2016-10-01

    Laser processing techniques have been given increasing attentions in the field of metallic glasses (MGs). In this work, effects of two kinds of shield gases, nitrogen and argon, on nanosecond-pulsed laser irradiation of Zr-based MG were comparatively investigated. Results showed that compared to argon gas, nitrogen gas remarkably promoted the formation of cracks during laser irradiation. Furthermore, crack formation in nitrogen gas was enhanced by increasing the peak laser power intensity or decreasing the laser scanning speed. X-ray diffraction and micro-Raman spectroscopy indicated that the reason for enhanced cracks in nitrogen gas was the formation of ZrN.

  20. Electron kinetics dependence on gas pressure in laser-induced oxygen plasma experiment: Theoretical analysis

    Science.gov (United States)

    Gamal, Yosr E. E.-D.; Abdellatif, Galila

    2017-08-01

    A study is performed to investigate the dependency of threshold intensity on gas pressure observed in the measurements of the breakdown of molecular oxygen that carried out by Phuoc (2000) [1]. In this experiment, the breakdown was induced by 532 nm laser radiation of pulse width 5.5 ns and spot size of 8.5 μm, in oxygen over a wide pressure range (190-3000 Torr). The analysis aimed to explore the electron kinetic reliance on gas pressure for the separate contribution of each of the gain and loss processes encountered in this study. The investigation is based on an electron cascade model applied previously in Gamal and Omar (2001) [2] and Gaabour et al. (2013) [3]. This model solves numerically a differential equation designates the time evolution of the electron energy distribution, and a set of rate equations that describe the change of excited states population. The numerical examination of the electron energy distribution function and its parameters revealed that photo-ionization of the excited molecules plays a significant role in enhancing the electron density growth rate over the whole tested gas pressure range. This process is off set by diffusion of electrons out of the focal volume in the low-pressure regime. At atmospheric pressure electron, collisional processes dominate and act mainly to populate the excited states. Hence photo-ionization becomes efficient and compete with the encountered loss processes (electron diffusion, vibrational excitation of the ground state molecules as well as two body attachments). At high pressures ( 3000 Torr) three body attachments are found to be the primary cause of losses which deplete the electron density and hence results in the slow decrease of the threshold intensity.