Accuracy of WWR-M criticality calculations with code MCU-RFFI

Energy Technology Data Exchange (ETDEWEB)

Petrov, Yu V [Petersburg Nuclear Physics Institute RAS, 188350 Gatchina, St. Petersburg (Russian Federation); Erykalov, A N; Onegin, M S [Petersburg Nuclear Physics Institute RAS, 188350 Gatchina, St. Petersburg (Russian Federation)

1999-10-01

The scattering and deviation of fuel element parameters by manufacturing, approximations of the reactor structure in the computer model, the partly inadequate neutron cross sections in the computer codes etc. lead to a discrepancy between the reactivity computations and data. We have compared reactivity calculations using the MCU-RRFI Monte Carlo code of critical assemblies containing WWR-M2 (36 enriched) an WWR-M5 (90%) fuel elements with benchmark experiments. The agreement was about {delta}{rho}{approx_equal}{+-}0.3%. A strong influence of the water ratio on reactivity was shown and a significant heterogeneous effect was found. We have also investigated, by full scale reactor calculations for the RETR program, the contribution to the reactivity of the main reactor structure elements: beryllium reflector, experimental channels irradiation devices inside the core, etc. Calculations show the importance of a more thorough study of the contributions of products of the (n, {alpha}) reaction in the Be reflector to the reactivity. Ways of improving the accuracy of the calculations are discussed. (author)

IV Training program for the staff of the laboratory for the RA reactor exploitation; IV Programi obuke osoblja Laboratorije za eksploataciju reaktora RA

Energy Technology Data Exchange (ETDEWEB)

NONE

1960-07-01

All the staff members of the laboratory for RA reactor exploitation are obliged to learn the following: fundamental properties of the RA reactor, the role and functionality of the reactor components, basic and auxiliary reactor systems, basics of radioactivity, measures for preventing contamination. The personnel working in shifts must be acquainted with the regulations and instructions for reactor operation. Training programs for reactor operators, mechanics, electricians, instrumentators and dosimetrysts are described separately. Svi saradnici Laboratorije za eksploataciju reaktora RA moraju poznavati sledece oblasti: Osnovne karakeristike reaktora RA, princip rada, ulogu i funkcionisanje komponenti reaktora, osnovnih i pomocnih sistema reaktora; osnovne pojmove o radioaktivnom zracenju, mere za sprecavanje kontaminacije. Osoblje koje radi u smenama mora dodatno poznavati propise i uputstva za rad reaktora. Posebno je naveden program obuke operatora reaktora, mehanicara, electricara, instrumentatora, dozimetrista.

Research in nuclear reactor theory and experimental reactors; Istrazivanja u teoriji nuklearnih reaktora i ekspeimentalni reaktori

Energy Technology Data Exchange (ETDEWEB)

Pop-Jordanov, J [Elektrotehnicki fakultet, Beograd (Yugoslavia)

1978-05-15

The paper is devoted to the possibilities of using experimental reactors for scientific research in nuclear power with a stress on problems in nuclear reactor theory. The stationary and nonstationary neutron fields, burnup prediction and analyses as well as fuel element development and the corresponding role of test-reactors were dealt with. It was shown that the investigations in nuclear reactor theory in Yugoslavia were developing continuously and in a useful interaction with experiments on research reactors. The needs for continuing the work on fundamental problems in neutron transport theory and on improving the calculation methods for thermal power reactors, together with the improvement of performances of existing research systems, were pointed out. A new quality in scientific work could be obtained dealing with the problems connected to a possible introduction of test-reactors, and fast systems later on. It was also pleaded for the corresponding orientations in fundamental sciences. (author) Rad je posvecen mogucnostima koriscenja eksperimentalnih reaktora za naucna istrazivanja u nuklearnoj energetici, sa akcentom na probleme teorije nuklearnih reaktora. Obradjena su stacionarna i nestacionarna neutronska polja, predikcija i analize sagorevanja, kao i razvoj gorivnih elemenata te uloga test-reaktora u osvajanju njihove tehnologije. Pokazano je da su se istrazivanja u teoriji nuklearnih reaktora u nas odvijala kontinualno i u korisnoj interakciji sa eksperimentima na istrazivackim reaktorima. Istaknuta je potreba nastavljanja rada na fundamentalnim problemima transportne teorije neutrona i na usavrsavanju metoda proracuna termalnih enerrgetskih reaktora, uz poboljsanje performansi postojecih istrazivackih sistema. Novi kvalitet u naucnom radu bi predstavljala orijentacija na probleme vezane sa eventualnim uvodjenjem test-reaktora, a zatim i brzih sistema. Pledirano je i za odgovarajuca usmeravanja u fundamentalnim naukama. (author)

Problems of space-time behaviour of nuclear reactors; Problemi prostorno-vremenskog ponasanja nuklearnih reaktora

Energy Technology Data Exchange (ETDEWEB)

Obradovic, D [Institut za nuklearne nauke ' Boris Kidric' , Vinca, Belgrade (Yugoslavia)

1966-07-01

This paper covers a review of literature and mathematical methods applied for space-time behaviour of nuclear reactors. The review of literature is limited to unresolved problems and trends of actual research in the field of reactor physics. Dat je pregled literature i matematickih metoda koje se koriste prilikom tretiranja prostorno-vremenskog ponasanja nuklearnih reaktora. Pregled literature ogranicen je na jos neresene probleme i pravce u kojima su danas usmerena istrazivanja u ovoj oblasti fizike nuklearnih reaktora (author)

Diagrams about RA reactor operation, Annex 7; Prilog 7 - Rad reaktora RA po godinama - dijagrami

Energy Technology Data Exchange (ETDEWEB)

Martinc, R [Institute of Nuclear Sciences Boris Kidric, Vinca, Beograd (Serbia and Montenegro)

1976-01-15

This Annex 7 includes diagrams about RA reactor operation (MWh) from 1960-1975; mean values of reactor power per day and month in 1975, and percent of utilisation of experimental space during 1975. [Serbo-Croat] Ovaj prilog sadrzi dijagrame o radu reaktora (MWh) po godinama (1960-1975); srednje vrednosti dnevne snage reaktora u 1975. godini; rad reakrora (MWh) po mesecima u 1975; procenat iskoriscenja eksperimentalnog prostora u 1975. godini.

Annex VII - Diagrams: 1. Reactor operation (1960-1977); 2. Mean daily reactor power density in 1977; 3. Monthly reactor power for 1977; 4. percent of utilization of experimental space in 1977; Prilog VII - Dijagrami: 1. Rad reaktora (MWh) po godinama (1960-1977); 2. Srednja dnevna snaga reaktora u 1977. godini; 3. Rad reaktora (MWh) po mesecima za 1977. godinu i 4. Procenat iskoriscenja eksperimentalnog prostora u 1977. godini

Energy Technology Data Exchange (ETDEWEB)

NONE

1977-12-15

This Annex includes the following diagrams: 1. Annual Reactor RA power production (MWh) for the period from 1960-1977; 2. Mean daily reactor power density MW in 1977; 3. Monthly reactor power production (MWh) for 1977; 4. percent of utilization of experimental space in 1977. [Serbo-Croat] Ovaj prilog sadrzi dijagrame: 1. Rad reaktora (MWh) po godinama (1960-1977); 2. Srednja dnevna snaga reaktora u 1977. godini; 3. Rad reaktora (MWh) po mesecima za 1977. godinu i 4. Procenat iskoriscenja eksperimentalnog prostora u 1977. godini.

Course of pin fuel test In WWR-M reactor core

International Nuclear Information System (INIS)

Zakharov, A.S.; Kirsanov, G.A.; Konoplev, K.A.

2005-01-01

Pin type fuel element (FE) of square form with twisted ribs was developed in VNIINM as an alternative for tube type FE of research reactors. Two variants of full-scale fuel assemblies (FA) are under test in the core of PNPI WWR-M reactor. One FA contains FE with UO 2 LEU and other - UMo LEU. Both types of FE have an aluminum matrix. Results of the first stages of the test are presented. (author)

Future of neutron-physical research at WWR-K reactor

International Nuclear Information System (INIS)

Akhmetov, E. Z.; Ibraev, B.M.

1999-01-01

Very cold neutrons (E nm) mostly indicate wave properties in the course of going through substance. The properties are determined by the value of the relation of neutron wave length to structure dimensions of the object studied. Very cold neutrons usage in nuclear-physical and neutron-optical research, in studying of structure and phase transformation of substances in different aggregative states continues to increase and very cold neutrons scattering method can be applied in those situation when other methods don't help to obtain the result (for example identification of light nuclei by roentgen rays etc.). Currently, we suppose that very cold neutrons can be applied in the course of studying superconductors, biological objects, different polymer systems and liquid crystals. Also it can be applied in radioecology - in determination of trans-uranium and trans-plutonium elements content in soil of territories where underground nuclear explosions were performed. These researches can be implemented at the WWR-K reactor. Its parameters and structure allow creating of 'Time-of-flight spectrometer very cold neutrons and cold neutrons', that functionally consists of the following basic blocks: - neutron conductor of stainless steel gage 50 mm, 8 m length; - switch block; - measurement cryostat chamber; - Vacuum shutters; - Measurement calculation complex. Earlier at the WWR-K the authors obtained maximum fluxes of ultra-cold neutrons (E=10 -7 eV) from vapor-hydrogen moderator at the temperature of 80 K and determined interaction cross-sections of ultra-cold neutrons with gas medium

Possibility for dry storage of the WWR-K reactor spent fuel

International Nuclear Information System (INIS)

Arinkin, F.M.; Belyakova, E.A.; Gizatulin, Sh.Kh.; Khromushin, I.V.; Koltochik, S.N.; Maltseva, R.M.; Medvedeva, Z.V.; Petukhov, V.K.; Soloviev, Yu.A.; Zhotabaev, Zh.R.

2000-01-01

This work is devoted to development of the way for dry storage of spent fuel of the WWR-K reactor. Residual energy release in spent fuel element assembly was determined via fortune combination of calculations and experiments. The depth of fission product occurrence relative to the fuel element shroud surface was found experimentally. The time of fission product release to the fuel element shroud surface was estimated. (author)

Design and experience of HEU and LEU fuel for WWR-M reactor

International Nuclear Information System (INIS)

Enin, A.A.; Erykalov, A.N.; Zakharov, A.S.; Zvezdkin, V.S.; Kirsanov, G.A.; Konoplev, K.A.; L'vov, V.S.; Petroc, Y.V.; Saikov, Y.P.

1997-01-01

A research reactor for providing high neutron fluxes has to have a compact, well breeding core with high specific heat removal. The WWR-M fuel elements meet these demands. They have optimum metal-to-water ratio and the recordly developed specific heat-transfer surface providing in a pool-type reactor at atmospheric pressure the unit heat of (900±100) kW. (author)

Safety report on WWR-S reactor

International Nuclear Information System (INIS)

Horyna, J.; Kaisler, L.; Listik, E.

1981-04-01

The present Safety Report of the WWR-S reactor summarizes findings obtained during the trial and partially also permanent operation of the reactor after two stages of its reconstruction implemented between 1974 and 1976. Most data are presented necessary for assessing probable risks of possible accident conditions whose consequences pose health hazards to individuals of the population, radiation personnel and the facilities themselves. Attention is devoted to the description of the locality, to components and systems, heat removal from the core, design aspects, the quality of new and old parts of the technological circuits, the systems of protection and control, the emergency core cooling system, the problems of radiation safety, and to the safety analyses of the abnormal states envisaged. The Report was compiled with regard to IAEA and CMEA recommendations concerning safe operation of research reactors and to the recommendations and binding decisions of the Czechoslovak Atomic Energy Commission. (author)

Nuclear Reactor RA Safety Report, Vol. 8, Auxiliary system; Izvestaj o sigurnosti nuklearnog reaktora RA, Knjiga 8, Pomocni sistemi

Energy Technology Data Exchange (ETDEWEB)

NONE

1986-11-01

This volume describes RA reactor auxiliary systems, as follows: special ventilation system, special drainage system, hot cells, systems for internal transport. Ventilation system is considered as part of the reactor safety and protection system. Its role is eliminate possible radioactive particles dispersion in the environment. Special drainage system includes pipes and reservoirs with the safety role, meaning absorption or storage of possible radioactive waste water from the reactor building. Hot cells existing in the RA reactor building are designed for production of sealed radioactive sources, including packaging and transport. [Serbo-Croat] Ova knjiga obuhvata opis pomocnih sistem reaktora RA: sistem specijalne ventilacije, sistem specijalne kanalizacije, vruce komore, sistemi za unutrasnji transport. Ventilacioni sistem je znacajan deo sistema zastite i sigurnosti reaktora. Njegova je uloga da onemoguci disperziju radioaktivnih cestica u okolinu. Sistem specijalne kanalizacije sastoji se od agregata, cevovoda i rezervoara sa sigurnosnom armaturom i ima zadatak da prihvata i u sebe deponuje radioaktivne otpadne vode iz objekarta reaktora RA. U zgradi reaktora RA postoje vruce komore koje su namenjene za proizvodnju zatvorenih izvora zracenje, ukljucujuci i mehanicku obradu, prepakivanje i transport.

Irradiation Performance of HTGR Fuel in WWR-K Research Reactor

International Nuclear Information System (INIS)

Ueta, Shohei; Sakaba, Nariaki; Shaimerdenov, Asset; Gizatulin, Shamil; Chekushina, Lyudmila; Chakrov, Petr; Honda, Masaki; Takahashi, Masashi; Kitagawa, Kenichi

2014-01-01

A capsule irradiation test with the high temperature gas-cooled reactor (HTGR) fuel is being carried out using WWR-K research reactor in the Institute of Nuclear Physics of the Republic of Kazakhstan (INP) to attain 100 GWd/t-U of burnup under normal operating condition of a practical small-sized HTGR. This is the first HTGR fuel irradiation test for INP in Kazakhstan collaborated with Japan Atomic Energy Agency (JAEA) in frame of International Science and Technology Center (ISTC) project. In the test, TRISO coated fuel particle with low-enriched UO_2 (less than 10 % of "2"3"5U) is used, which was newly designed by JAEA to extend burnup up to 100 GWd/t-U comparing with that of the HTTR (33 GWd/t-U). Both TRISO and fuel compact as the irradiation test specimen were fabricated in basis of the HTTR fuel technology by Nuclear Fuel Industries, Ltd. in Japan. A helium-gas-swept capsule and a swept-gas sampling device installed in WWR-K were designed and constructed by INP. The irradiation test has been started in October 2012 and will be completed up to the end of February 2015. The irradiation test is in the progress up to 69 GWd/t of burnup, and integrity of new TRISO fuel has been confirmed. In addition, as predicted by the fuel design, fission gas release was observed due to additional failure of as-fabricated SiC-defective fuel. (author)

The Waste Management Plan integration into Decommissioning Plan of the WWR-S research reactor from Romania

International Nuclear Information System (INIS)

Barariu, Gheorghe; Oprescu, Theodor; Filip, Mihaela; Sociu, Florin

2008-01-01

The paper presents the progress of the Radioactive Waste Management Plan which accompanies the Decommissioning Plan for research reactor WWR-S located in Magurele, Ilfov, near Bucharest, Romania. The new variant of the Decommissioning Plan was elaborated taking into account the IAEA recommendation concerning radioactive waste management. A new feasibility study for WWR-S decommissioning was also developed. The preferred safe management strategy for radioactive wastes produced by reactor decommissioning is outlined. The strategy must account for reactor decommissioning, as well as rehabilitation of the existing Radioactive Waste Treatment Plant and the upgrade of the Radioactive Waste Disposal Facility at Baita-Bihor. Furthermore, the final rehabilitation of the laboratories and reusing of cleaned reactor building is envisaged. An inventory of each type of radioactive waste is presented. The proposed waste management strategy is selected in accordance with the IAEA assistance. Environmental concerns are part of the radioactive waste management strategy. (authors)

Operation, maintenance and utilization of the RA reactor, Annual report 1978; Pogon, odrzavanje i eksploatacija reaktora RA, Izvestaj o radu u 1978. godini

Energy Technology Data Exchange (ETDEWEB)

Milosevic, M [Institute of Nuclear Sciences Boris Kidric, Vinca, Beograd (Serbia and Montenegro)

1978-12-15

It has been planned for 1978 that the RA reactor would be operated for 158 dana at nominal power of 6.5 MW meaning production of 24 648 MWh. The plan was fulfilled since 24 652 MWh was produces. Reactor operation for 158 days is relevant to reactor operation for 200 days in the period before 1975. The reason is increased neutron flux achieved due to improved fuel management and the characteristics of the new 80% enriched fuel. At the end of 1978 the reactor core contained 45% of 80% enriched fuel elements. Increase of neutron flux has shortened the typical time needed for irradiation of the most important samples for isotope production. This significant success in reactor operation is at the same time an obligation for increasing its utilization. Some new trends proposed for increasing reactor utilization capacities were presented at the Conference on utilization of research nuclear reactors in Yugoslavia held in May 1978. [Serbo-Croat] Reaktor RA imao je u planu za 1978. godinu 158 dana rada na nominalnoj snazi od 6.5 MW, sto odgovara radu od 24 648 MWh. Ostvareno je 24 652 MWh sto znaci da je plan ostvaren. Rad reaktora od 158 dana odgovara radu reaktora od 200 dana u periodu pre 1975. godine. Razlog je povecanje neutronskog fluksa zahvaljujuci usavrsenom rukovanju gorivom i karakteristikama novog 80% obogacenog goriva. Krajem 1978. godine 45% jezgra reaktora bilo je popunjeno novim 80% obogacenim gorivom. Povecani neutronski fluks omogucio je skracenje vremena ozracivanja vaznih uzoraka za proizvodnju radioaktivnih izotopa. Ovaj znacajan uspeh je istovremeno obaveza znatno veceg iskoriscenja reaktora RA. Rezultati napora da se postigne vece iskoriscenje reaktora RA prezentirani su na Konferenciji o koriscenju nuklearnih reaktora u Jugoslaviji koja je odrzana u maju 1978.

Nuclear Reactor RA Safety Report, Vol. 12, Accidents during reactor operation; Izvestaj o sigurnosti nuklearnog reaktora RA, Knjiga 12, Akcidenti u dosadasnjem radu reaktora

Energy Technology Data Exchange (ETDEWEB)

NONE

1986-11-01

This volume includes description and analysis of typical accidents occurred during operation of RA reactor in chronological order, as follows: contamination of primary coolant circuit; leakage of heavy water from the primary coolant loop; contamination of vertical experimental channel; air contamination in the reactor building and loss of circulation of the primary coolant; failures of the vacuum pump and spent fuel packaging device; rupture of the spent fuel element cladding; dethronement's of capsule for irradiation of fuel element; rupture of the vertical experimental channel and contamination of the surroundings; swelling of a fuel element; appearance of deposits on the surface of the fuel elements cladding. The last chapter describes similar accidents occurred on nuclear reactors in the world. [Serbo-Croat] Ova knjiga sadrzi hronoloski pregled i analizu karakteristika akcidenata u dosadasnjem radu reaktora RA: kontaminacija primarnog kola hladjenja; isticanje teske vode is primarnog kola hladjenje; kontaminacija eksperimentalnog vertikalnog kanala; kontaminacija vazduha u hali reaktora i prestanak cirkulacije primarnog hladioca; otkaz vakum pumpe i uredjaja za prepakivanje ozracenog goriva; proboj kosuljice ozracenog gorivnog elementa; dehermetizacija kapsule za ozracivanje nuklearnog goriva; proboj eksperimentalnog vertikalnog kanala i kontaminacija prostorija; bubrenje gorivnog elementa; pojava taloga na kosuljicama gorivnih elemenata. Poslednje poglavlje opisuje udese na koji su se dogodili na nuklearnim reaktorima u svetu.

RA research nuclear reactor operation in forced regime, Annex 5; Prilog 5 - Rad istrazivackog nuklearnog reaktora RA u forsiranom rezimu, Prvo saopstenje

Energy Technology Data Exchange (ETDEWEB)

Mitrovic, S [Institute of Nuclear Sciences Boris Kidric, Reaktor RA, Vinca, Beograd (Serbia and Montenegro)

1964-12-15

In order to increase the flux and experimental potentials of the RA reactor, properties of the reactor operating in the forced regime have been inspected four times, twice with the spent fuel (core C), and twice with partly fresh fuel (cores E and F). Forced regime means power higher than nominal 6.5 MW. From the analyses of technology parameters during operation in the forced regime at power levels of 7 and 11 MW, state and behaviour of the components, efficiency of the biological protection and other parameters it was concluded that the reactor operation is possible at power levels of 10 MW during a whole year, and under certain conditions even longer operation at power levels up to 15 MW. This paper examines the reactor operation conditions in the forced regime and gives conclusions related to real increase of the experimental possibilities, isotope production and economic factors. Radi povecanja fluksa i eksperimentalnih mogucnosti reaktora RA, cetiri puta su proverene osobine reaktora u forsiranom rezimu, tj. na snagama vecim od nominalne (6,5 MW) i to dva puta sa istrosenim gorivom (jezgro C) i dva puta sa delimicno svezim (jezgra E i F). Iz analize tehnoloskih parametara u toku eksperimentalno rada reaktora u forsiranom rezimu na snagama od 7 do 11 MW, stanja i ponasanja opreme, efikasnosti bioloske zastite i ostalih parametara, zakljucuje se da je moguc permanentan rad reaktora tokom cele godine na snagama do 10 MW, a pod izvesnim uslovima i duzi rad na snagama do 15 MW. U radu su diskutovani uslovi rada reaktora u forsiranom rezimu i donose se zakljucci o realnom povecanju eksperimentalnih mogucnosti, proizvodnje radioizotopa i o ekonomskim faktorima (author)

Neutronics substantiation of possibility for conversion of the WWR-K reactor core to operation with low-enriched fuel

International Nuclear Information System (INIS)

Arinkin, F.M.; Gizatulin, Sh.H.; Zhantikin, T.M.; Koltochnik, S.N.; Takibaev, A.Zh.; Talanov, S.V.; Chakrov, P.V.; Chekushina, L.V.

2002-01-01

The studies are aimed to calculation and experimental justification of possibility for conversion of the WWR-R reactor core to low-enriched nuclear fuel (the 19.75-% enrichment in isotope U-235), resulting in reducing the risk of non-sanctioned proliferation of nuclear materials which can be used as weapons materials. The analysis of available published data, related to problem of reduction of enrichment in the fuel used in research thermal reactors, has been carried out. Basing on the analysis results, reference fuel compositions have been chosen, in particular, uranium dioxide (UO 2 ) in aluminum master form and the UA1 4 alloy. Preliminary calculations have shown that, with the WWR-K reactor core preserved existing critical characteristics (the fuel composition: UA1 4 ), the uranium concentration in the fuel element is to be increased by a factor of 2.0-2.2, being impossible technologically. The calculations have been performed by means of the Monte Carlo computational codes. The program of optimal conversion of the WWR-K reactor core to low-enriched fuel has been developed, including: development of calculation models of the reactor core, composed of various designs of fuel elements and fuel assemblies (FA), on a base of corresponding computational codes (diffusion, statistical, etc.); implementation of experiments in the zero-power reactor (critical assembly) with the WWR-C-type FA, in view of correction of the computational constants used in calculations; implementation of reactor core neutronics calculations, in view of selection of the U-235 optimal content in the low-enriched fuel elements and choice of FA reload strategy at the regime of reactor core after burning; determination of the fuel element specification; determination of the critical and operational loads for the reactor core composed of rod/tubular fuel elements; calculation of the efficiency of the protection control system effectors, optimization of its composition, number and locations in the

RA Research nuclear reactor Part 1, RA Reactor operation and maintenance in 1987; Istrazivacki nuklearni reaktor RA Deo 1 - Pogon i odrzavanje nuklearnog reaktora RA u 1987. godini

Energy Technology Data Exchange (ETDEWEB)

Sotic, O; Martinc, R; Cupac, S; Sulem, B; Badrljica, R; Majstorovic, D; Sanovic, V [Institute of Nuclear Sciences Boris Kidric, Vinca, Beograd (Serbia and Montenegro)

1987-12-15

RA research reacto was not operated due to the prohibition issued in 1984 by the Government of Serbia. Three major tasks were finished in order to fulfill the licensing regulations about safety of nuclear facilities which is the condition for obtaining permanent operation licence. These projects involved construction of the emergency cooling system, reconstruction of the existing special ventilation system, and renewal of the system for electric power supply of the reactor systems. Renewal of the RA reactor instrumentation system was initiated. Design project was done by the Russian Atomenergoeksport, and is foreseen to be completed by the end of 1988. The RA reactor safety report was finished in 1987. This annual report includes 8 annexes concerning reactor operation, activities of services and financial issues, and three special annexes: report on testing the emergency cooling system, report on renewal of the RA reactor and design specifications for reactor renewal and reconstruction. [Serbo-Croat] Reaktor RA nije radio usled zabrane Izvsnog veca Skupstine Srbije od 27. avgusta 1984. U cilju povecanja pouzdanosti rada reaktora a da bi se udovoljilo zakonskim propisima sto je uslov za dobijanje stalne dozvole za rad realizovana su tri velika zahvata na reaktoru RA. Ovi zahvati obuhvatili su izgradnju sistema za hladjenje jezgra reaktora u slucaju nuzde, rekonstukciju postojeceg sistema specijalne ventilacije i rekonstrukciju sistema napajanja elektricnom energijom neophodnih potrosaca reaktora RA. Zapoceti su radovi na modernizaciji intrumentacije reaktora RA, projekat je izradjen u sovjetskoj organizaciji Atomenergoeksport, a trebalo bi da se realizuje do kraja 1989. godine. U cilju povecanja prostora za skladistenje ozracenog nuklearnog goriva i njegovog efikasnijeg koriscenja, izradjen je su projekti za rekonstrukciju postojecih uredjaja za rukovanje gorivom, povecanje smestajnog kapaciteta i preciscavanje vode u bazenima za odlezavanje. Realizaija ovih

Power reactor noise measurements in Hungary

International Nuclear Information System (INIS)

Pallagi, D.; Horanyi, S.; Hargitai, T.

1975-01-01

An outline is given of the history of reactor noise research in Hungary. A brief description is given of studies in the WWR-SM reactor, a modified version of the original WWR-S thermal reactor, for the detection of in-core simulated boiling by analysis of the noise of out-of-core ionization chambers. Coolant velocity measurements by transit time analysis of temperature fluctuations are described. (U.K.)

Nuclear Reactor RA Safety Report, Vol. 14, Safety protection measures; Izvestaj o sigurnosti nuklearnog reaktora RA, Knjiga 14, Sigurnosne zastitne mere

Energy Technology Data Exchange (ETDEWEB)

NONE

1986-11-01

Nuclear reactor accidents can be caused by three type of errors: failure of reactor components including (1) control and measuring instrumentation, (2) errors in operation procedure, (3) natural disasters. Safety during reactor operation are secured during its design and construction and later during operation. Both construction and administrative procedures are applied to attain safe operation. Technical safety features include fission product barriers, fuel elements cladding, primary reactor components (reactor vessel, primary cooling pipes, heat exchanger in the pump), reactor building. Safety system is the system for safe reactor shutdown and auxiliary safety system. RA reactor operating regulations and instructions are administrative acts applied to avoid possible human error caused accidents. [Serbo-Croat] Uzroci udesa na nuklearnim reaktorima mogu se svrstati u jednu od sledece tri grupe: (1) otkaz pojedinih delova opreme, ukljucujuci mernu i kontrolnu instrumentaciju, (2) greske u pogonu i eksploataciji, (3) prirodne nepogode, katastrofe. Bezbednost i sigurnost u radu nuklearnog reaktora osiguravaju se odredjenim merama koje se preduzimaju pri njegovoj izgradnji i kasnije njegovoj elsploataciji. Te mere se mogu podeliti u sledece dve kategorije: (1) mere tehnicke zastite, i (2) administrativne mere. Mere tehnicke zastite sastoje se od barijere fissionih produkata, kosuljice gorivnih elemenata, primarnog kola reaktora RA (reaktorski sud, cevovod primarnog kola, toploizmenjivac u pimpi), zgrada reaktora. Sigurnosni sistem cini sistem za sigurnosno zaustavljanje reaktora i pomocni sigurnosni sistem. Kroz odgovarajuce propise i uputstva za rad na reaktoru RA primenjene su administrativne mere neophodne za sprecavanje udes koji bi mogao nastati kao posledica ljudskog faktora.

Nuclear Reactor RA Safety Report, Vol. 15, Analysis of significant accidents; Izvestaj o sigurnosti nuklearnog reaktora RA, Knjiga 15, Analiza znacajnih akcidenata

Energy Technology Data Exchange (ETDEWEB)

NONE

1986-11-01

Power excursions of the RA reactor a mathematical model of reactor kinetic behaviour was formulated to describe power and temperature coefficients for both reactor fuel and moderator. Computer code TM-1 was written for analysis of possible reactor accidents. Power excursions caused by uncontrolled control rod removal and heavy water flow into the central vertical experimental channel were analyzed. Accidents caused by fuel elements handling were discussed including possible fuel element damage. Although the probability for uncontrolled radioactive materials release into the environment is very low, this type of accidents are analyzed as well including the impact on the personnel and the environment. A separate chapter describes analysis of the loss of flow accident. Safety analysis covers the possible damage of the outer steel Ra reactor vessel and the water screens which are part of the water biological shield. [Serbo-Croat] Radi analize dinamickog ponasanja reaktora RA u toku ekskurzije snage formulisan je matematicki model koji opisuje promene snage i temperature goriva i moderatora. Za analizu predpostavljenih akcidenata realizovan je racunarski program TM-1. Analizirane su ekskurzije snage usled nekontrolisanog izvlacenja kontrolnih sipki i punjenja centralnog vertikalnog eksperimentalnog kanala teskom vodom. Analizirani su akcidenti pri rukovanju nuklearnim gorivom ukljucujuci ostecenje nuklearnog goriva. Iako je verovatnoca za nekontrolisano rasturanje radioaktivnog materijala mala, analizirani su i ovakvi moguci akcidenti koji mogu uticati kako na osoblje reaktora tako i na okolinu. Posebno poglavlje obuhvata analizu akcidenta u slucaju prestanka cirkulacije primarnog hladioca. Analiza sigurnosti reaktora obuhvata i moguce ostecenje spoljasnjeg celicnog suda reaktora RA kao i vodenih ekrana koji su deo vodenog bioloskog stita.

Operation and maintenance of the RA nuclear reactor for 1977, Report Annex I; Rad i iskoriscenost reaktora RA u 1977. godini, izvestaj Prilog I

Energy Technology Data Exchange (ETDEWEB)

Martinc, R; Stanic, A [Institute of Nuclear Sciences Boris Kidric, Vinca, Beograd (Serbia and Montenegro)

1977-12-15

RA reactor operation plan was fulfilled, meaning 28583 MWh. In addition to 183 days of operation at full power, during 1977 the reactor was operated for 14 days at lower power level according to the demand of users. The utilization level of rector irradiation capability (neutron flux and time of operation) was 14%. This annex includes detailed statistical data about reactor operation, utilization, power level, savings concerned with new 80% enriched fuel. All the 9 vertical experimental channels were used for irradiation in the reactor core. Digression from the action plan were caused by refueling and demand od the users. There have been 11 safety shutdowns, of which 6 caused by power cuts, 4 due to failure of the instruments, and 1 due to earthquake in March 1977. [Serbo-Croat] Planirani rad reaktora na nominalnoj snazi ostvaren je u iznosu od 28583 MWh. U toku 1977. godine reaktor je radio 14 dana na manjim snagama i u posebnom eksperimentalnom rezimu na zahtev korisnika. Iskoriscenost kapaciteta reaktora za ozracivanje uzoraka (na bazi neutronskog fluksa i vremena rada reaktora) bila je 41%. Ovaj izvestaj sadrzi detaljne statisticke podatke o radu i iskoriscenosti reaktora, podatke o ustedi goriva prelaskom na 80% obogaceno gorivo. Korisceno je svih 9 vertikalnih eksperimentalnih kanala u aktivnoj zoni. Uzroci odstupanja od plana rada osim zamene goriva bili su zahtevi korisnika. Bilo je 11 sigurnosnih zaustavljanja, 6 usled nestanka napona, 4 usled kvarova opreme i instrumentacije, i 1 put usled zemljotresa u martu.

Operation, safety and utilization of the RA reactor in 1978 - Report; Prilog I - Rad, sigurnost i iskoriscenost reaktora RA u 1978. godini - Izvestaj

Energy Technology Data Exchange (ETDEWEB)

Martinc, R; Stanic, A [Institute of Nuclear Sciences Boris Kidric, Vinca, Beograd (Serbia and Montenegro)

1978-12-15

This report includes a review of work related to development of reactor operation capacities and increase of the RA reactor safety and economic operation. Statistical data about reactor operation and utilization are included as well. Introducing of the new 80% enriched fuel into the the reactor core enabled increase of the neutron flux, i.e. increase of its production capabilities. Safety and optimization analyses concerned with introduction of the new fuel have shown that the most safe and economic procedure was gradual introducing of the highly enriched fuel. This procedure was based on the concept of mixed core configuration with 2% and 80% enriched fuel elements. By applying this original concept the following significant savings were achieved: fuel elements savings, shortening of the annual period of reactor operation, savings in spent fuel casks, electric power savings, slowing down of heavy water degradation. [Serbo-Croat] Ovaj izvestaj sadrzi pregled o radu na razvoju eksploatacionih mogucnosti i povecanju sigurnosti i ekonomicnosti reaktora RA. Prilozeni su i statisticki podaci o radu i iskoriscenosti reaktora u 1978. godini. Uvodjenje novog 80% obogacenog goriva u jezgro reaktora omogucilo je povecanje neutronskog fluksa tj. povecanje njegovoh proizvodnih mogucnosti. Sigurnosne i optimizacione analize uvodjenja novog goriva pokazale su da je nasigurniji i najekonomicniji postupak postupnog uvodjenja visokoobogacenog goriva koji se zasniva na konceptu mesane resetke sa 2% i 80% obogacenim gorivom. Ovaj originalni koncept omogucio je da se postignu znatne ustede u gorivu, skracivanje godisnjeg rada reaktora, usteda sudova za odlaganje isluzenog goriva, usteda elektricne energije, usporavanje degradacije teske vode.

Structure–function analysis and genetic interactions of the SmG, SmE, and SmF subunits of the yeast Sm protein ring

Science.gov (United States)

Schwer, Beate; Kruchten, Joshua; Shuman, Stewart

2016-01-01

A seven-subunit Sm protein ring forms a core scaffold of the U1, U2, U4, and U5 snRNPs that direct pre-mRNA splicing. Using human snRNP structures to guide mutagenesis in Saccharomyces cerevisiae, we gained new insights into structure–function relationships of the SmG, SmE, and SmF subunits. An alanine scan of 19 conserved amino acids of these three proteins, comprising the Sm RNA binding sites or inter-subunit interfaces, revealed that, with the exception of Arg74 in SmF, none are essential for yeast growth. Yet, for SmG, SmE, and SmF, as for many components of the yeast spliceosome, the effects of perturbing protein–RNA and protein–protein interactions are masked by built-in functional redundancies of the splicing machine. For example, tests for genetic interactions with non-Sm splicing factors showed that many benign mutations of SmG, SmE, and SmF (and of SmB and SmD3) were synthetically lethal with null alleles of U2 snRNP subunits Lea1 and Msl1. Tests of pairwise combinations of SmG, SmE, SmF, SmB, and SmD3 alleles highlighted the inherent redundancies within the Sm ring, whereby simultaneous mutations of the RNA binding sites of any two of the Sm subunits are lethal. Our results suggest that six intact RNA binding sites in the Sm ring suffice for function but five sites may not. PMID:27417296

Investigation of material removal rate (MRR) and wire wear ratio (WWR) for alloy Ti6Al4 V exposed to heat treatment processing in WEDM and optimization of parameters using Grey relational analysis

International Nuclear Information System (INIS)

Altug, Mehmet

2016-01-01

The study examines the changes of the microstructural, mechanical and conductivity characteristics of the titanium alloy Ti6Al4 V as a result of heat treatment using wire electrical discharge machining, and their effect on machinability. By means of optical microscopy and scanning electron microscopy (SEM), analyses have been performed to determine various characteristics and additionally, microhardness and conductivity measurements have been conducted. Material removal rate (MRR) and wire wear ratio (WWR) values have been determined by using L18 Taguchi test design. The microstructures of the samples have been changed by thermal procedures. Results have been obtained by using the Grey relational analysis (GRA) optimization technique to solve the maximum MRR and minimum WWR values. The best (highest) MRR value is obtained from sample E which was water quenched in dual phase processing. The microstructure of this sample is composed of primary α and α' phases. The best (lowest) WWR value is obtained from sample A.

Investigation of material removal rate (MRR) and wire wear ratio (WWR) for alloy Ti6Al4 V exposed to heat treatment processing in WEDM and optimization of parameters using Grey relational analysis

Energy Technology Data Exchange (ETDEWEB)

Altug, Mehmet [Inonu Univ., Malatya (Turkey). Dept. of Machine and Metal Technologies

2016-11-01

The study examines the changes of the microstructural, mechanical and conductivity characteristics of the titanium alloy Ti6Al4 V as a result of heat treatment using wire electrical discharge machining, and their effect on machinability. By means of optical microscopy and scanning electron microscopy (SEM), analyses have been performed to determine various characteristics and additionally, microhardness and conductivity measurements have been conducted. Material removal rate (MRR) and wire wear ratio (WWR) values have been determined by using L18 Taguchi test design. The microstructures of the samples have been changed by thermal procedures. Results have been obtained by using the Grey relational analysis (GRA) optimization technique to solve the maximum MRR and minimum WWR values. The best (highest) MRR value is obtained from sample E which was water quenched in dual phase processing. The microstructure of this sample is composed of primary α and α' phases. The best (lowest) WWR value is obtained from sample A.

Structure-function analysis and genetic interactions of the SmG, SmE, and SmF subunits of the yeast Sm protein ring.

Science.gov (United States)

Schwer, Beate; Kruchten, Joshua; Shuman, Stewart

2016-09-01

A seven-subunit Sm protein ring forms a core scaffold of the U1, U2, U4, and U5 snRNPs that direct pre-mRNA splicing. Using human snRNP structures to guide mutagenesis in Saccharomyces cerevisiae, we gained new insights into structure-function relationships of the SmG, SmE, and SmF subunits. An alanine scan of 19 conserved amino acids of these three proteins, comprising the Sm RNA binding sites or inter-subunit interfaces, revealed that, with the exception of Arg74 in SmF, none are essential for yeast growth. Yet, for SmG, SmE, and SmF, as for many components of the yeast spliceosome, the effects of perturbing protein-RNA and protein-protein interactions are masked by built-in functional redundancies of the splicing machine. For example, tests for genetic interactions with non-Sm splicing factors showed that many benign mutations of SmG, SmE, and SmF (and of SmB and SmD3) were synthetically lethal with null alleles of U2 snRNP subunits Lea1 and Msl1. Tests of pairwise combinations of SmG, SmE, SmF, SmB, and SmD3 alleles highlighted the inherent redundancies within the Sm ring, whereby simultaneous mutations of the RNA binding sites of any two of the Sm subunits are lethal. Our results suggest that six intact RNA binding sites in the Sm ring suffice for function but five sites may not. © 2016 Schwer et al.; Published by Cold Spring Harbor Laboratory Press for the RNA Society.

Measurement of zero power reactor dynamic response by cross correlation method; Merenje dinamickog odziva reaktora nulte snage kros korelacionom metodom

Energy Technology Data Exchange (ETDEWEB)

Kostic, Lj; Petrovic, M [Boris Kidric Institute of Nuclear Sciences Vinca, Beograd (Yugoslavia)

1969-07-15

Pulse response is comprehensive description of linear system dynamics. In this paper, cross correlation method was used for measuring the response of zero power reactor. Reactor system was perturbed by pseudo-random signal, which was cross correlated with the reactor signal responding to this perturbation on the digital ZUSE Z-23 computer. Cross-correlation functions were measured for different positions of stochastic oscillator and ionization chamber in the critical system. From numerical processing of performed experimental data, it was concluded that a more powerful faster computer would be needed for processing statistical experiments. In that case it would be possible to obtain information about spatial effects in the reactor and propagation of neutron waves in the multiplication medium. Impulsni odziv je potpuni opis dinamike linearnog sistema. Za merenje impulsnog odziva nultog reaktora, u ovom radu, koriscena je kros korelaciona metoda. Reaktorski sistem je perturbovan pseudoslucajnim signalom, koji je u digitalnom racunaru ZUSE Z-23 kroskorelisan sa signalom odziva reaktora na ove perturbacije. Merene su kroskorelacione funkcije za razlicite polozaje stohastickog oscilatora i jonizacione komore u kriticnom sistemu. Iz numericki obradjivanih eksperimenta namece se kao zakljucak da bi za obradu statistickih eksperimenata kod nultih reaktora bio potreban racunar veceg kapaciteta i brzine. U tom slucaju bi se iz ovako postavljenog eksperimenta moglo doci i do informacija o prostornim efektima u reaktoru i prostiranju neutronskih talasa kroz multiplikativnu sredinu. (author)

Action plan during reactor shutdown in October 1965, Annex 5; Prilog br. 5 - Plan radova u toku stajanja reaktora u mesecu oktobru 1965. godine

Energy Technology Data Exchange (ETDEWEB)

Nikolic, M [Reaktor RA, Odelenje odrzavanja, Institute of Nuclear Sciences Boris Kidric, Vinca, Beograd (Serbia and Montenegro)

1965-12-15

The action plan of the division for reactor maintenance during reactor shutdown includes detailed list of tasks for mechanics, electronic and electrical equipment group during the reactor shutdown period in October 1965. It contains tasks for planned shutdown periods in September, August, July, May, April, March, and February 1965. [Serbo-Croat] Plan radova Odelenja odrzavanja reaktora RA za period stajanja reaktora u oktobru mesecu 1965. sadrzi detaljnu listu zadataka masinske grupe, elektro grupe i elektronske grupe. Ovaj prilog sadrzi i zadatke koji ce biti obavljeni tokom planiranih perioda kada je reaktor zaustavljen u septembru, avgustu, julu, junu, maju, aprilu, martu i februaru 1965.

Operation and maintenance of RA Reactor, Annual report 1977; Pogon i odrzavanje reaktora RA - Izvestaj o radu u 1977. godini

Energy Technology Data Exchange (ETDEWEB)

Milosevic, M et al. [Institute of Nuclear Sciences Boris Kidric, Vinca, Beograd (Serbia and Montenegro)

1977-12-15

During 1977, the RA Reactor was operated at nominal power of 6.5 MW for 183 days. Total production was 28582 MWh which is 10% higher than planned. Second phase of introducing the 80% enriched fuel was fulfilled according to the plan. This means that the reactor core will be filled with highly enriched fuel in 1978. Refueling was done three time during the past year. After completing the first phase of the fuel exchange which was related mostly to reactor safety, the second phase will be devoted to the more efficient increase of neutron flux . This second phase is of utmost importance because higher neutron flux will provide better and more efficient reactor application from economic point of view. This will justify the application of the new more expensive highly enriched fuel. The budget for reactor operation and maintenance is hardly enough to cover the maintenance of the components and instrumentation. During 1977 there were no accidents related nor incidents related to the instrumentation or related to radiation protection. [Serbo-Croat] Reaktor RA je u toku 1977. godine ostvario rad od 28583 MWh odnosno 183 dana rada na nominalnoj snazi, sto u odnosu na plan rada iznosi 10% vise od planiranog. Druga faza uvodjenja 80% obogacenog goriva izvrsena je prema planu sto znaci da ce se punjenje jezgra reaktora 80% gorivom zavrsiti u toku 1978. godine. Izvrsene su tri izmene goriva. Posle isteka prvog dela prelaznog rezima koji je usmeren na maksimalnu sigurnost reaktora preci ce se na drugi deo usmeren na vece i brze povecanje neutronskog fluksa. Druga faza je od izuzetnog znacaja jer ce omoguciti bolje i znatno ekonomicnije koriscenje reaktora i opravdati upotrebu novog i skupljeg goriva. Sredstva za pogon i odrzavanje reaktora RA su jedva dovoljna za odrzavanje neophodnog nivoa opreme. Akcidenata u toku 1977. godine nije bilo ni sa opremom ni u pogledu zastite od zracenja.

Influence of absorbers on the reactivity of the reactor; Odredjivanje uticaja apsorbera na reaktivnost reaktora

Energy Technology Data Exchange (ETDEWEB)

Martinc, R [Institute of Nuclear Sciences Boris Kidric, Vinca, Beograd (Serbia and Montenegro)

1961-12-15

Influence of absorbers on the reactivity of the reactor was calculated by two-group diffusion theory applying corrections for boundary conditions derived from the transport theory because diffusion theory in not applicable in the vicinity of boundary surfaces especially in case of strong absorbers. This report shows the calculations of central absorber efficiency in the core with and without reflector, and efficiency of the group of absorbers randomly placed in the core. Approximation method for determining the efficiency of the absorber is described as well as numerical verification of results. Effective absorber dimensions and the influence of gaps on the reactor dimensions are shown. [Serbo-Croat] Uticaj apsorbera na reaktivnost reaktora racunat je primenom difuzione dvogrupne teorije uz korekcije kod primene granicnih uslova koje daje transportna teorija za efektivne dimenzije apsorbera posto difuziona teorija ne moze da primeni u blizini granicnih povrsina posebno kod jakih apsorbera. U ovom izvestaju dati su proracuni efektivnosti centralnog apsorbera u reflektovanom u nereflektovanom reaktoru, efektivnosti grupe proizvoljno ubacenih apsorbera. Dat je i prikaz aproksimativne metode za odredjivanje efektivnosti apsorbera kao i numericka provera rezultata. Prikazane su efektivne dimenzije apsorbera kao i uticaj supljina na kriticne dimenzije reaktora.

The application of calorimetrical methods in nuclear technology and dosimetry

International Nuclear Information System (INIS)

Kott, J.; Krett, V.; Novotny, J.; Kovar, Z.; Jirousek, V.

1985-01-01

The report reviews theoretical as well as experimental research activities devoted to the possibilities of measuring reactor neutron and photon fields using thermic detectors based on calorimetric principle. There have been worked out theoretical principles of a reactor measuring probe intended in the first place to measuring neutron fluxes under operational temperatures inside power and research reactors, and a new philosophy of measurement has been elaborated. In addition, the report presents the experimental results as obtained on research reactors WWR-S, WWR-SM, RA, and Czechoslovak power reactor A-1 and GDR power reactor WWR-2. These results are given in connection with a newly proposed technique of reactor neutron field detection. The second part of the report presents results of works concerning beam dosimetry with the use of calorimeters

Measurement of graphite and aluminium absorption cross sections via reactor period by danger coefficient method; Merenje apsorpcionih preseka grafita i aluminijuma preko periode reaktora metodom koeficijenta opasnosti

Energy Technology Data Exchange (ETDEWEB)

Petrovic, M; Markovic, V; Velickovic, Lj [Boris Kidric Institute of nuclear sciences, Vinca, Belgrade (Yugoslavia)

1963-07-01

Full text: This activity is a logical continuation of the experiment at the RA reactor during 1962 which was based on compensating the effect by means of control rod. Since results are given with significant errors, new method for measuring the absorption cross sections via reactor period. Experiment was done at the RB reactor which was particularly prepared for this type of experiments. Reactor power was from 50 mW to 2 W. Absorption cross sections were measured for two types of material: domestic graphite No.3 and French graphite 'Pachiney', and two types of aluminium. Total errors in applying this method are {+-} 5%, where the source of major part of error comes from uncertainty of the standard absorption power (previous method gave {+-} 10 do 55% ). Comparison of French graphite absorption cross section obtained via reactor period and via control rod showed approximate agreement with discrepancy of 5.4% which is considered within the precision of this method. Considering the accuracy of measurement results and reactor economy it is concluded that measuring absorption cross sections of samples via period of RB reactor is more favourable than measurements by control rod at the RA reactor. Pun tekst: Ovaj rad predstavlja logican nastavak eksperimenta na reaktoru RA u toku 1962. godine, koji je bazirao na kompenzaciji efekta pomocu kontrolne sipke. Kako su rezultati dati sa velikim greskama, to se prislo novom nacinu merenja apsorpsionih preseka preko periode reaktora. Eksperiment je radjen na reaktoru RB koji je specijalno pripremljen za ovu vrstu eksperimenta. Snaga reaktora se kretala od 50 mW do 2 W. Preko periode reaktora RB odredjeni su apsorpcioni preseci za dve vrste materijala i to: domaci grafit No.3 i francuski 'Pachiney', i dve vrste aluminijuma. Ukupne greske pri ovom nacimu merenja iznose oko {+-} 5%, gde glavni deo greske nosi neodredjenost apsorpcione moci standarda (ranija metoda je dala {+-} 10 do 55% ). Poredjenjem vrednosti apsorpcionih preseka

Experimental RA reactor operation with 80% enriched fuel - Program of experimental operation: a) Program of experimental operation with 80% enriched fuel at low power, b) contents of the experimental operation with 80% enriched fuel at higher power levels; Program probnog rada: a) Program probnog rada reaktora sa 80% obogacenim gorivom na malim snagama, b) sadrzaj programa probnog rada reaktora RA sa 80% obogacenim gorivom na vecim snagama

Energy Technology Data Exchange (ETDEWEB)

Martinc, R; Sotic, O; Skoric, M; Cupac, S; Bulovic, V; Maric, I; Marinkov, L [Institute of Nuclear Sciences Boris Kidric, Vinca, Beograd (Serbia and Montenegro)

1980-10-15

Highly enriched (80%) uranium oxide fuel was regularly used in the mixed reactor core with the 2% enriched fuel since 1976. The most important changes related to reactor operation, in comparison with the original design project were related to reactor core fuelling schemes. At the end of 1979 reactor was shutdown due to the corrosion coating noticed on some fuel elements and due to decrease quality of the heavy water. Subsequently the Sanitary inspector of Serbia has prohibited further reactor operation. Restart of the reactor will not be a simple continuation of operation. It is indispensable to perform complete experimental program including measurements of critical parameters at different power levels for the core with fresh 80% enriched fuel. The aim of this document is to obtain working permission and its contents are in agreement with the procedure demanded by the Safety Committee of the Institute. It includes results of optimization and safety analysis for the initial reactor core. Since the permission for restart is not obtained, a separate RA reactor safety report is prepared in addition to the program for experimental operation. This report includes: detailed program for reactor experimental operation with 80% enriched fuel in the core at low power levels, and contents of the experimental operation with 80% enriched fuel in the core at higher power levels. [Serbo-Croat] Od decembra 1976. godine redovno je korisceno 80% obogaceno gorivo u mesanoj resetki reaktorskog jezgra sa 2% obogacenim gorivom. Najvece izmene na reaktoru u odnosu na originalni projekat izvrsene su u nacinu rukovanja gorivom. Krajem marta 1979. godine obustavljen je rad reaktora usled naslaga na gorivnim elementima i loseg stanja teske vode. Naknadno je izdata zabrana za rad reaktora od strane Sanitarnog inspektora SR Srbije. Ponovno pustanje reaktora u rad nece biti jednostavan nastavak rada. Neophodno je da se izvede kompletan program merenja kriticnih parametara i drugih

Nuclear Reactor RA Safety Report, Vol. 1, Introduction; Izvestaj o sigurnosti nuklearnog reaktora RA, Knjiga 1, Uvod

Energy Technology Data Exchange (ETDEWEB)

NONE

1986-11-01

Based on the agreement between governments of Socialist Federal Republic of Yugoslavia and USSR of January 28 1956, a contract was signed about construction of RA research reactor in the Boris Kidric Institute of nuclear sciences. Building of the RA reactor started in 1956, and has reached criticality in 1959. Since then it has been in almost permanent operation, except for five longer shutdown periods: in 1963 because of heavy water and primary coolant system contamination with cobalt; in 1970 because of transporting the heavy water to France for isotopic regeneration; in 1979/1980 and 1983 because of aluminium oxyhydrate deposition on the fuel element cladding in reactor active region; in 1985/1986 because of ventilation system reconstruction and construction of emergency core cooling system. RA reactor is a heavy water cooled and heavy water moderated research reactor. Since the beginning of its operation, 2% enriched metal uranium fuel was used. From 1976, 80% enriched uranium oxide fuel elements were used partially in some core regions and since 1981 the complete core was filled with this highly enriched fuel. RA reactor was designed to operate under normal conditions at 6.5 MW power and at 10 MW power under forced regime. As a powerful neutron source the reactor was meant to be used for research in the field of reactor and neutron physics, solid state physics, radiation chemistry, biology and radioactive isotopes production. RA reactor was build by Yugoslav companies based on USSR basic design project. Main components of the systems were produced in USSR. [Serbo-Croat] Na osnovu Sporazuma izmedju vlada SFRJ i SSSR od 28. januara 1956. godine, sklopljen je ugovor o izgradnji istrazivackog reaktora RA u Institutu za nuklearne nauke Boris Kidric u Vinci. Reaktor RA je poceo da se gradi 1956. godine, a kriticnost je postigao 1959. godine. Od tada je takoreci neprekidno bio u radu, izuzev u pet slucajeva duzeg stajanja: 1963. godine - zbog kontaminacije teske vode

Measurements at the RA Reactor related to the VISA-2 project - Part 1, Start-up of the RA reactor and measurement of new RA reactor core parameters; Fizicka merenja na reaktoru RA u vezi projekta VISA-2 - I deo, Pustanje u rad reaktora RA i merenje fizickih parametara novog jezgra reaktora RA

Energy Technology Data Exchange (ETDEWEB)

Markovic, H [Institute of Nuclear Sciences Boris Kidric, Vinca, Beograd (Serbia and Montenegro)

1962-07-15

The objective of the measurements was determining the neutron flux in the RA reactor core. Since the number of fuel channels is increased from 56 to 68 within the VISA-2 project, it was necessary to attain criticality of the RA reactor and measure the neutron flux properties. The 'program of RA reactor start-up' has been prepared separately and it is included in this report. Measurements were divided in two phases. First phase was measuring of the neutron flux after the criticality was achieved but at zero power. During phase two measurements were repeated at several power levels, at equilibrium xenon poisoning. This report includes experimental data of flux distributions and absolute values of the thermal and fast neutron flux in the RA reactor experimental channels and values of cadmium ratio for determining the neutron epithermal flux. Data related to calibration of regulatory rods for cold un poisoned core are included. [Serbo-Croat] Svrha merenja je odredjivanje neutronskog fluksa u reaktoru RA. S obzirom na uvecani broj tehnoloskih kanala of 56 na 68 u vezi projekta VISA-2, bilo je potrebno ponovo dovesti reaktora RA do kriticnosti i izvrsiti merenja karakteristika fluksa neutrona. Posebno je pripremljen 'program pustanja u pogon reaktora RA', koji je sadrzan u ovom dokumentu. Program merenja bio je podeljen na dve faze. Prva faza je merenje fluksa pre podizanju reaktora na nominalnu snagu. Slicna merenja vrsena su i na vecim snagama u drugoj fazi, pod uslovima ravnoteznog zatrovanja reaktora ksenonom, jer se tada pokazuju izvesne promene u odgovarajucim karakteristikama fluksa neutrona. Ovaj izvestaj sadrzi merene vrednosti raspodele fluksa i apsolutne vrednosti termalnih i brzih neutrona kao i kadmijumskih odnosa koji su korisceni za odredjivanje fluksa epitermalnih neutrona. Opisana je kalibracija regulacionih sipki za hladan nezatrovan reaktor.

Regulations and instructions for RA reactor operation; Propisi i uputstva za pogon reaktora 'A'

Energy Technology Data Exchange (ETDEWEB)

NONE

1989-07-01

This regulatory guide consists of following 4 chapters: Description of the RA reactor, organization scheme, regulations for performing experiments; Regulations for staff on duty; Instructions for operating the vacuum systems, heavy water and helium systems; and evacuation in case of accident. [Serbo-Croat] Ovaj pravilnik sadrzi sledeca 4 poglavlja: Opis reaktora RA, sema organizacije rada, propisi za izvodjenje eksperimenata; Pravilnik za rad dezurnog osoblja; Uputstva za rada sa vakuum sistemima, sistemom teske vode, sistemom helijuma; evakuacija u slucaju udesa.

Seismic safety review mission Almaty WWR 10 MW research reactor Almaty, Kazakhstan. Final report

International Nuclear Information System (INIS)

Gurpinar, A.; Slemmons, D.B.; David, M.; Masopust, R.

1995-06-01

On the request of the government of Kazakhstan and within the scope of the TC project KAZ/0/004, a seismic safety review mission was conducted in Almaty, 8-19 May 1995 for the WWR 10 Mw research reactor. This review followed the fact finding mission which visited Almaty in November 1993 together with an INSARR mission. At that time some information regarding the seismotectonic setting of the site as well as the seismic capacity of the facility was obtained. This document presents the results of further work carried out on both the issues. It discusses technical session findings on geology, seismology, structures and equipments. In the end conclusions and recommendations of the mission are given. 4 refs, figs, tabs, 18 photos

Production of the sealed gamma-radiation sources of with iridium-192 radionuclide at the WWR-K research reactor

International Nuclear Information System (INIS)

Petukhov, V.K.; Chernayev, V.P.; Chabeyev, N.T.; Ermakov, E.L.; Chakrov, P.V.

2005-01-01

Full text: Conversion orientation of the WWR-K research reactor activity was established after renewal of its operation in 1997. A priority in reactor works was determined in the decision of tasks of practical use of nuclear technologies in a national economy in the next directions: in an industry, public health services and agriculture. The items of prime tasks: development and introduction of radiation technologies and manufacturing of radioisotopes for industry. This task included both scientific and technical program in the list of works of the Republican goals. At the WWR-K reactor within the framework of the this task solution the works on pilot production of the sealed sources of radioactive radiations (SSRR) with Ir-192 radionuclide for an industry of Republic of Kazakhstan were made. Organizational questions related to the Kazakhstan authority body and the regulating documentation were solved the first of all. The second stage was the development of the techniques of creating of devices providing an samples irradiation in reactor, control of sources sealing, measurements of the equivalent radiation doze from sources and high-quality support of SSRR manufacture over all technological way. At the third stage was made a little quantity SSRR with Ir-192 radionuclide, such as GIID-A1 (G6), for 'TEKOPS-660' Gammaray Projectors. This work served as experimental check of the decisions correctness, and has allowed to remove those lacks, to find out which it was possible only during direct manufacturing of radioactive sources. During performance of all these works the following was carried out: development and release of the documents and specifications regulating work on SSRR manufacture at the Institute of Nuclear Physics; personnel preparation and certification; preparation and equipment providing of reactor hot chambers by additional devices for work with irradiated iridium samples; development and manufacturing of the devices for iridium samples irradiation in

Status and future of the WWR-M research reactor in Kiev

Energy Technology Data Exchange (ETDEWEB)

Bazavov, D.A.; Gavrilyuk, V.I.; Kirischuk, V.I.; Kochetkov, V.V.; Lysenko, M.V.; Makarovskiy, V.N.; Scherbachenko, A.M.; Shevel, V.N.; Slisenko, V.I. [Institute for Nuclear Research, Kiev (Ukraine)

2001-07-01

Kiev WWR-M Research Reactor, operated at maximum power of 10 MW, was put into operation in 1960 and during its 40-years history has been used to perform numerous studies in different areas of science and technology. Due to a number of technical problems the Research Reactor, the only one in Ukraine, was shut down in 1993 and then put into operation in 1999 again. Now there is an intention to reconstruct Kiev Research Reactor. The upgraded Research Reactor would allow solving such problems as the safe operation of Ukrainian NPPs, radioisotope production and, naturally, fundamental and applied research. The main problem for the successful operation of Kiev Research Reactor is the management and storage of spent fuel at the site, since after core unloading the spent fuel storage appears to be practically completed. So it is absolutely necessary to ship the most part of the spent fuel for reprocessing and as soon as possible. Besides, there is a need to build up the new spent fuel storage, because the tank of available storage requires careful inspection for corrosion. (author)

Radiation damage in SmS, SmSsub(1-x)Psub(x) and SmB6

International Nuclear Information System (INIS)

Morillo, J.; Bordier, G.; de Novion, C.H.; Senateur, J.P.; Jun, J.

1984-08-01

Large conductivity increases under 21 K electron or neutron irradiations are observed in SmS and SmSsub(1-x)Psub(x). It is shown that they are related to Sm defects. A possible mechanism is 4f electron delocalization around radiation defects. In SmB 6 , the low temperature resistivity increase desappears under 21 K irradiation. The thermal stability of the defects is also investigated up to room temperature

Determination of reactor parameters in a simulated RA reactor lattice by measuring the reactivity level of heavy water in D{sub 2}O moderated RB reactor; Odredjivanje reaktorskih parametara u simuliranoj resetki reaktora RA merenjem reaktivnosti nivoa teske vode u D{sub 2}O moderiranom reaktoru RB

Energy Technology Data Exchange (ETDEWEB)

Takac, S M; Markovic, H D; Dimitrijevic, Z B [Institute of Nuclear Sciences Vinca, Beograd (Serbia and Montenegro)

1974-07-01

Direct method for experimental determination of the neutron age {tau} in the reactor lattice is not developed. Fermi theory for determining {tau} by measuring the reactivity level of the heavy water can be applied for a limited number of reactor lattices. An attempt was made to apply this approach for a complex reactor core with side and upper reflector. As expected the obtained results were not satisfactory, and {tau} was determined by Dessauer formula which gives more realistic estimation of thermalization in the reactor cell. major discrepancies are resulting from the fact that the lower reflector was neglected. But it is possible to to determine {tau} for reactor core with reflectors by additional measurements of axial distribution and other experimental data for {tau}. This is quite tedious numerical procedure. Obtained experimental data for a number of reactor parameters are compared to the initial data of the RA reactor core showing very good agreement. [Serbo-Croat] Ekspeimentalna metoda za direktno odredjivanje starosti neutrona {tau}, u resetki reaktora do danas nije razvijena. Primenjena Fermijeova teorija za odredjivanje {tau} preko merenja reaktivnosti nivoa teske vode, ocigledno se moze koristiti samo na ogranicen spektar reaktorskih resetki. U ovom radu pokusano je da se vidi primenljivost iste u slozenom - bocno i odozdo - reflektovanom jezgru reaktora. Naravno dobijeni rezultati nisu zadovoljili, sto se i moglo ocekivati, pa je {tau} odredjen preko Dessauer-ove formule, sto daje daleko blizu sliku stvarnog stanja procesa termalizacije u celiji reaktora. Ocigledno vece neslaganje primenjene teorije dolazi od zanemarivanja donjeg reflektora u jezgru reaktora. Medjutim, dopnskim merenjem aksijalne raspodele i na osnovu ostalih eksperimentalnih podataka za {tau}, moguce je odrediti eksperimentalno reflektorski koeficijent za visestruko reflektovano jezgro reaktora, sto numericki predstavlja mukotrpan i dugotrajan rad na racunaru. Dobijeni

RA reactor operation and maintenance in 1990 with comparative evaluation from 1986-1990, Part 1; Deo 1 - Pogon i odrzavanje nuklearnog reaktora RA u 1990. godini, uz uporedni pregled za period 1986-1990. godina

Energy Technology Data Exchange (ETDEWEB)

Sotic, O; Cupac, S; Sulem, B; Zivotic, Z; Vasovic, B; Sanovic, V [Institute of Nuclear Sciences Boris Kidric, Vinca, Beograd (Serbia and Montenegro)

1990-12-15

During the previous period RA reactor was not operated because the Committee of Serbian ministry for health and social care has cancelled the operation licence in August 1984. The reason was the non existing emergency cooling system and lack of appropriate filters in the special ventilation system. The new emergency cooling system and the reconstruction of the existing ventilation system were finished in 1989, the conditions for further reactor operation were fulfilled. In the meantime new licensing regulations adopted in 1988 were not demanding the mentioned conditions for reactors operated at power less than 10MW, RA reactor power being 6.5 MW. But the reactor could not be restarted due to planned renewal of the reactor instrumentation. It is planned to exchange the complete instrumentation by the end of 1991. Training program for the staff operating and maintaining the reactor components was prepared in 1985. Reconstruction, modification and construction of components demanded new documentation needed for further safe reactor operation. New version of RA reactor safety report was finished in 1986 according to the recommendations of IAEA and licensing regulations of Yugoslavia. In 1989, new documents were written covering regulations and instructions for reactor operation. The new reactor experimental loop was designed in 1986, and constructed and tested in 1990. All the reactor components were maintained by specific reactor services. Financing of the reactor remains a permanent problem. [Serbo-Croat] U proteklom periodu reaktor RA nije bio u pogonu zato sto je 30. jula 1984. godine Republicki komitet za zdravlje i socijalnu politiku republike Srbije, zabranio njegov rad zbog toga sto reaktor ne poseduje sistem za udesno hladjenje i ne poseduje odgovarajuce filtere u sistemu specijalne ventilacije. Radovi na izgradnji sistema za udesno hladjenje i rekonstrukciji postojeceg sistema specijalne ventilacije zavrseni su 1989. godine. Uslovi za nastavak rada reaktora

Activity of the Service for maintenance of mechanical equipment of the RA reactor - Report, Annex II; Prilog II - Rad sluzbe za odrzavanje masinske opreme reaktora RA u 1979. godini - Izvestaj -

Energy Technology Data Exchange (ETDEWEB)

Radivojevic, J [Institute of Nuclear Sciences Boris Kidric, Vinca, Beograd (Serbia and Montenegro)

1979-12-15

Service for mechanical components at the RA reactor includes: control and maintenance of utility components, mechanical workshop, hot cells and storage. Control and maintenance of main components covers: reactor core, heavy water system, technical water system, gas system. This service is responsible for the following auxiliary systems: transportation units; spent fuel storage pool; special ventilation system; personal protection appliances; hot cells. Maintenance of the reactor building, ventilation, heating, water supply, sewage, fire protection devices, gas and compressed air systems are included. [Serbo-Croat] Sluzba za masinsku opremu nuklearnog reaktora RA obuhvata: kontrolu i odrzavanje masinske opreme postrojenja, masinsku radionicu, vruce komore i prirucni magacin. Kontrola i odrzavanje osnovnih sistema obuhvata centralno telo reaktora, sistem teske vode, sistem tehnicke vode, gasni sistem. Pomocni sistemi koji spadaju u delatnost ove sluzbe su: transportna oprema, bazen za odlezavanje ozracenog goriva, sistem specijalne ventilacije, licna zastitna sredstva, vruce komore. Odrzavanje zgrade reaktora, ventilacije i grejanja, vodovoda i kanalizacije, opreme za protivpozarnu zastitu, instalacije gasa i komprimovanog vazduha su takode zadatak ove Sluzbe.

Experiment on search for neutron-antineutron oscillations using a projected UCN source at the WWR-M reactor

Science.gov (United States)

Fomin, A. K.; Serebrov, A. P.; Zherebtsov, O. M.; Leonova, E. N.; Chaikovskii, M. E.

2017-01-01

We propose an experiment on search for neutron-antineutron oscillations based on the storage of ultracold neutrons (UCN) in a material trap. The sensitivity of the experiment mostly depends on the trap size and the amount of UCN in it. In Petersburg Nuclear Physics Institute (PNPI) a high-intensity UCN source is projected at the WWR-M reactor, which must provide UCN density 2-3 orders of magnitude higher than existing sources. The results of simulations of the designed experimental scheme show that the sensitivity can be increased by ˜ 10-40 times compared to sensitivity of previous experiment depending on the model of neutron reflection from walls.

Regulations for the maintenance division of the RA reactor, Annex 6; Prilog 6 - Pravilnik poslovanja Odelenja odrzavanja i remonta reaktora RA

Energy Technology Data Exchange (ETDEWEB)

Badrljica, R [Reaktor RA, Odelenje odrzavanja, Institute of Nuclear Sciences Boris Kidric, Vinca, Beograd (Serbia and Montenegro)

1965-12-15

The regulations for the Division of reactor maintenance include the organizational scheme, tasks of the Division, and operation procedures for all the staff members. [Serbo-Croat] Pravilnik o radu Odelenja za odrzavanje reaktora RA sadrzi opis organizacione strukture sluzbe, zadataka Odelenja, organizacije rada, nacin poslovanja za sve saradnike Odelenja.

Measurement of the effective resonance integral of natural uranium; Merenje efektivnog rezonantnog integrala prirodnog urana

Energy Technology Data Exchange (ETDEWEB)

Markovic, V; Kocic, A [Institute of nuclear sciences Boris Kidric, Vinca, Beograd (Yugoslavia)

1965-12-15

Good understanding of the nuclear properties of the materials in the reactor core is essential for reactor operation. One of the fundamental properties is the resonance absorption of the fuel, which is directly included in the reactor calculation through resonance escape probability and influences the choice of the materials quality in the core. This paper describes the measurement of resonance absorption integral of the natural uranium as a function of the S/M ratio. Improved experiment planning and analysis of results, as well as improvement of the ROB-1 reactor oscillator device related to the interpretation of results and decrease of reactor drift variations during measurement enabled higher precision of results compared to previous experiments. Poznavanje osobina nuklearnih karakteristika materijala koji ulaze u jezgro nuklearnog reaktora predstavlja bitan faktor u njegovom rezimu rada. Jedna od osnovnih je svakako rezonantna apsorpcija goriva, cija velicina - preko faktora rezonantnog izbegavanja - direktno ulazi u proracun nuklearnih reaktora i utice na izbor kvaliteta materijala koji ga sacinjavaju. U radu se opisuje merenje rezonantnog apsorpcionog integrala prirodnog urana u funkciji odnosa S/M. Bolja postavka eksperimenta i interpretacija rezultata, s jedne strane, i poboljsanje uredjaja reaktorskog oscilatora ROB-1 /1/ u pogledu analize podataka i smanjenja promene drifta reaktora u toku merenja, s druge strane, daju znacaj ovom radu u pogledu dobijanja preciznijih rezultata u odnosu na ranije /2/ (author)

Activity of the Service for maintenance of mechanical structures of the RA reactor - Report for 1980, Annex II; Prilog II - Rad sluzbe za odrzavanje masinske opreme reaktora RA - Izvestaj za 1980. god

Energy Technology Data Exchange (ETDEWEB)

Radivojevic, J [Institute of Nuclear Sciences Boris Kidric, Vinca, Beograd (Serbia and Montenegro)

1980-12-15

Service for mechanical components at the RA reactor includes: control and maintenance of utility components, mechanical workshop, hot cells and storage. Control and maintenance of main components covers: reactor core, heavy water system, technical water system, gas system. This service is responsible for the following auxiliary systems: transportation units; spent fuel storage pool; special ventilation system; personal protection appliances; hot cells. Maintenance of the reactor building, ventilation, heating, water supply, sewage, fire protection devices, gas and compressed air systems are included. [Serbo-Croat] Sluzba za masinsku opremu nuklearnog reaktora RA obuhvata: kontrolu i odrzavanje masinske opreme postrojenja, masinsku radionicu, vruce komore i prirucni magacin. Kontrola i odrzavanje osnovnih sistema obuhvata centralno telo reaktora, sistem teske vode, sistem tehnicke vode, gasni sistem. Pomocni sistemi koji spadaju u delatnost ove sluzbe su: transportna oprema, bazen za odlezavanje ozracenog goriva, sistem specijalne ventilacije, licna zastitna sredstva, vruce komore. Odrzavanje zgrade reaktora, ventilacije i grejanja, vodovoda i kanalizacije, opreme za protivpozarnu zastitu, instalacije gasa i komprimovanog vazduha su takode zadatak ove Sluzbe.

Results of environmental radiation monitoring and meteorology measurements (material prepared for obtaining the licence for RA reactor experimental operation); Rezultati merenja zracenja u okolini i rezultati meteoroloskih merenja (materijal pripremljen radi dobijanja dozvole za pustanje Reaktora RA u probni rad)

Energy Technology Data Exchange (ETDEWEB)

NONE

1980-10-15

According to the demands for obtaining the licence for restarting the Ra reactor and the experimental operation this document includes the radiation monitoring measured data in the working space and environment of the RA reactor, i.e. Boris Kidric Institute. The meteorology measured data are included as well. All the measurements are performed according to the radiation protection program applied actually from the first reactor start-up at the end of 1959. [Serbo-Croat] Saglasno zahtevu za dobijanje dozvole za ponovno pustanje u probni rad reaktora RA, ovaj dokument sadrzi rezultate merenja zracenja u okolini (radnoj i zivotnoj) reaktora RA odnosno instituta 'Boris Kidric' kao i podatke o meteoroloskim merenjima. Sve merenja rade se prema programu mera zastite od zracenja koje se sprovode prakticno od prvog pustanja reaktora u rad krajem 1959. godine.

Instructions for RA reactor decontamination - Annex 10; Prilog 10 - Uputstvo za dekontaminaciju Reaktora RA

Energy Technology Data Exchange (ETDEWEB)

NONE

1963-12-15

Instructions for RA reactor decontamination includes: action plan for decontamination of the heavy water system by 7% water solution of H{sub 3}PO{sub 4} + 2% CrO{sub 3} acid; description of the preparatory work including calculation of the pipes volume and installation of special pipes; detailed instructions for decontamination procedure. [Serbo-Croat] Uputstvo za dekontaminaciju Reaktora RA sadrzi: plan operacija za dekontaminaciju sistema teske vode 7% vodenim rastvorom kiseline H{sub 3}PO{sub 4} + 2% CrO{sub 3}; opis pripremnih radova ukljucujuci proracun zapremine covovoda i montiranje posebnih cevovoda; detaljno uputstvo za izvodjenje operacija pri dekontaminaciji.

Nuclear Reactor RA Safety Report, Vol. 16, Maximum hypothetical accident; Izvestaj o sigurnosti nuklearnog reaktora RA, Knjiga 16, Maksimalni hipoteticki akcident

Energy Technology Data Exchange (ETDEWEB)

NONE

1986-11-15

Fault tree analysis of the maximum hypothetical accident covers the basic elements: accident initiation, phase development phases - scheme of possible accident flow. Cause of the accident initiation is the break of primary cooling pipe, heavy water system. Loss of primary coolant causes loss of pressure in the primary circuit at the coolant input in the reactor vessel. This initiates safety protection system which should automatically shutdown the reactor. Separate chapters are devoted to: after-heat removal, coolant and moderator loss; accident effects on the reactor core, effects in the reactor building, and release of radioactive wastes. [Serbo-Croat] Sema granjanja za maksimalni hipoteticki akcident obuhvata osnovne elemente: pocetak akcidenta, faze razvoja akcidenta i stablo razvoja - sema potencijalnih akcidentnih tokova. Uzrok pocetka akcidenta je pucanje cevovoda primarnog rashladnog sistema jezgra, sistema teske vode. Gubitak primarnog hladioca izaziva pad pritiska u primarnom sistemu hladjenja na ulazu u reaktorski sud. Ovaj poremecaj pobudjuje sigurnosno kolo zastite koje automatski treba da prekine rad reaktora. Posebno je razmatrano generisanje zaostale snage, isticanje hladioca i moderatora, efekti akcidenta na jezgro, efekti u zgradi reaktora, oslobadjanje radioaktivnih produkata.

Evaluation of Radioisotope Production Process of 153Sm and 153Sm-EDTMP Radiopharmaceuticals

International Nuclear Information System (INIS)

Kadarisman; Sri Hastini; Yayan Tahyan; Abidin; Dadang Hafid; Enny Lestari

2007-01-01

Experiments on the process of 153 Sm radioisotope and labeling of 153 Sm-EDTMP radiopharmaceuticals were carried out. This experiments included preparation of Sm 2 O 3 target, dissolution of post irradiation, determination of radioactivity concentration of 153 Sm radioisotope, radionuclide purity, EDTMP labeling, determination of radiochemical purity and pH. In these experiments the total radioactivity 153 Sm product is round about 2845.83 mCi to 36963.31 mCi, or with the radioactivity concentration between 474 mCi/ml to 6160.55 mCi/ml in the SmCl 3 solution form, each its volume is 6.0 ml, and the samarium content is 5.76 mg/ml, and the radionuclide purity of 153 Sm is 100 %. All of the 153 Sm- EDTMP radiopharmaceuticals product are fulfilled requirements the radioactivity concentration, Sm content, radiochemical purity and pH. The radioactivity concentration of 153 Sm-EDTMP radiopharmaceuticals is 37.50 mCi/ml (minimum) to 283.50 mCi/ml (highest). The pH 7.5 were 8 products, and the rest are pH 8.5. Radiochemical purity of 153 Sm-EDTMP are round about 90.00 % to 99.44 %. (author)

Independent CO{sub 2} loop for cooling the samples irradiated in the RA reactor vertical experimental channels, Task 2.50.05; Nezavisno kolo CO{sub 2} za hladjenje uzoraka ozracivanih u vertikalnim eksperimentalnim kanalima reaktora RA, Zad. 2.50.05

Energy Technology Data Exchange (ETDEWEB)

Stojic, M; Pavicevic, M

1964-07-01

This report contains the following volumes V and VI of the Project 'Independent CO{sub 2} loop for cooling the samples irradiated in RA reactor vertical experimental channels': Design project of the dosimetry control system in the independent CO{sub 2} loop for cooling the samples irradiated in the RA reactor vertical experimental channels, and Safety report for the Independent CO{sub 2} loop for cooling the samples irradiated in the RA reactor vertical experimental channels. Ovaj izvestaj sadrzi dva albuma zadatka 'Nezavisno kolo CO{sub 2} za hladjenje uzoraka ozracivanih u vertikalnim eksperimentalnim kanalima reaktora RA', Zad. 2.50.05: Album V: Predprojekat sistema dozimetrijske kontrole u nezavisnom kolu CO{sub 2} za hladjenje uzoraka ozracivanih u VEK reaktora RA i Album VI: Izvestaj o sigurnosti za nezavisno kolo CO{sub 2} za hladjenje uzoraka ozracivanih u VEK reaktora RA.

RA Research reactor, Part 1, Operation and maintenance of the RA nuclear reactor for 1986; Istrazivacki nuklearni reaktor RA, deo 1, pogon i odrzavanje nukleanog reaktora RA u 1986. godini

Energy Technology Data Exchange (ETDEWEB)

Sotic, O; Martinc, R; Cupac, S; Sulem, B; Badrljica, R; Majstorovic, D; Sanovic, V [Institute of Nuclear Sciences Boris Kidric, Vinca, Beograd (Serbia and Montenegro)

1986-12-01

In order to enable future reliable operation of the RA reactor, according to new licensing regulations, three major tasks started in 1984 were fulfilled: building of the new emergency system, reconstruction of the existing ventilation system, and reconstruction of the power supply system. Simultaneously in 1985/1986 renewal of the instrumentation and reconstruction of the system for handling and storage of the spent fuel in the reactor building have started. Design projects for these tasks are almost finished and the reconstruction of both systems is expected to be finished until 1988 and mid 1989 respectively. RA reactor Safety report was finished according to the recommendations of the IAEA. Investments in 1986 were used for 8000 kg of heavy water, maintenance of reactor systems and supply of new components, reconstruction of reactor systems. This report includes 8 annexes concerning reactor operation, activities of services and financial issues. [Serbo-Croat] Sa ciljem da se obezbedi pouzdan rad reaktora RA a u skladu sa zakonskim propisima, zavrsena su tri velika zahvata zapoceta 1984: izgradnja novog sistema za udesno hladjenje, rekonstrukcija postojeceg sistema za ventilaciju, i modernizacija reaktorske instrumentacije. Istovremeno tokom 1985/1986. zapoceta je modernizacija instrumentacije i rekonstrukcija sistema za rukovanje i skladistenje iskoriscenog goriva u zgradi reaktora. Projekti za navedene radove su vec zavrseni ili su u zavrsnoj fazi, a ocekuje se da ce rekonstrukcija oba sistema biti zavrsena do kraja 1988. odnosno sredine 1989. godine. Izrada izvestaja o sigurnosti reaktora RA, prema preporukama MAAE zavrsena je 1986. Investiciona ulaganja na reaktoru Ra u 1986. iskoriscena su za: nabavku 8000 kg teske vode, za investiciono odrzavanje reaktorskih sistema i nabavku opreme, za rekonstrukciju reaktorskih sistema. Ovaj izvestaj sadrzi 8 priloga koji opisuju rad reaktora, rad strucnih sluzbi i finansiranje.

Application of non-destructive testing and in-service inspections to research reactors and preparation of ISI programme and manual for WWR-C research reactors

International Nuclear Information System (INIS)

Khattab, M.

1996-01-01

The present report gives a review on the results of application of non-destructive testing and in-service inspections to WWR-C reactors in different countries. The major problems related to reactor safety and the procedure of inspection techniques are investigated to collect the experience gained from this type of reactors. Exchangeable experience in solving common problems in similar reactors play an important role in the effectiveness of their rehabilitation programmes. 9 figs., 4 tabs

Experimental study of space dependent nuclear reactor kinetics - Progress report; Eksperimentalno proucavanje prostorno zavisne kinetike nuklearnih reaktora - Izvestaj o napredovanju

Energy Technology Data Exchange (ETDEWEB)

Obradovic, D; Petrovic, M [Institute of nuclear sciences Boris Kidric, Vinca, Beograd (Yugoslavia)

1966-11-15

This paper describes experimental study of space-time behaviour of nuclear reactors by local complex-periodic perturbation of the absorption cross section and by measuring the local reactor response to this perturbation. Perturbation was done by BOR-1 fast oscillator. Cross correlation between the response and the perturbation was done numerically after completing the measurement by using digital computer. Obtained experimental results are preliminary and are measured with significant errors which were analysed in this paper. Results show qualitative agreement with those obtained by theoretical model. This paper is the first progress report in this field in our country. U radu je opisan eksperimentalni prilaz proucavanju prostorno-vremenskog ponasanja nuklearnih reaktora, vrseci lokalnu slozeno-periodicnu perturbaciju apsorpcionog preseka i mereci lokalni odziv reaktora na tu perturbaciju. Perturbacija je vrsena brzim oscilatorom BOR-1. Kroskorelacija izmedju odziva i perturbacije vrsena je numericki posle obavljenog merenja upotrebom digitalne racunske masine. Dobijeni eksperimentalni rezultati imaju preliminarni karakter i odredjeni su sa znatnim eksperimentalnim greskama koje su, u radu analizirane. Izlozeni rezultati pokazuju kvalitativna slaganja sa teorijski dobijenim modelom. Ovaj rad predstavlja prvi izvestaj o napredovanju na ovoj problematici kod nas (author)

RA Research reactor Annual report 1981 - Part 1, Operation, maintenance and utilization of the RA reactor; Istrazivacki nuklearni reaktor RA, Deo 1 - Pogon, odrzavanje i eksploatacija reaktora u 1981. godini

Energy Technology Data Exchange (ETDEWEB)

Sotic, O; Milosevic, M; Martinc, R; Kozomara-Maic, S; Cupac, S; Radivojevic, J; Stamenkovic, D; Skoric, M [Institute of Nuclear Sciences Boris Kidric, Vinca, Beograd (Serbia and Montenegro)

1981-12-15

biggest difficulty was maintenance of reactor instrumentation. During 1981 the reactor was operated safely, there was no accident nor incident that would affect the safety of reactor personnel or the environment. The testing operation will be continued in 1982,and the experience so far shows that the program would be successfully fulfilled on the whole. [Serbo-Croat] Nuklearni reaktor RA prestao je sa radom nakon martovske kampanje 1979. godine usled pojave talozenja oksihidrata aluminijuma na kosuljicama gorivnih elemenata. Odgovarajucim resenjima Sanitarnog inspektorata Republickog sekretarijata za zdravje i socijalnu politiku SR Srbije i generalnog direktora Instituta za nuklearne nauke 'Boris Kidric', Vinca zabranjen je dalji rad reaktora sve dok se ne utvrde uzroci stvaranja oksihidrata aluminijuma i njihovog talozenja, preduzmu mere za njihovo uklanjanje i ne obezbede potrebni uslovi za normalan nastavak rada reaktora. Do kraja 1979. i tokom 1980. godine, nakon niza izvrsenih analiza i utvrdjivanja uzroka koji su doveli do zaustavljanja rada reaktora, izvrsene su sve neophodne pripreme za ponovno pustanje reaktora u rad. Polazeci od cinjenice da na reaktoru RA ne postoji sistem za hladjenje jezgra u slucaju udesa i da ne postoji adekvatan sistem za filtriranje potencijalno zagadjenog vazduha, a saglasno sa novim propisima o pustanju u rad i probnom radu nuklearnih objekata, Sanitarni inspektorat je doneo privremeno resenje kojim se dozvoljava pustanje reaktora u rad, tj. izvodjenje tzv. 'nultog eksperimenta' uz ogranicenje snage na 1% od vrednosti nominalne snage. Na osnovu dobijene dozvole, reaktor RA je ponovo pusten u rad 21. januara 1981. godine, kada je dostignuta kriticnost sa jezgrom sastavljenim iskljucivo od gorivnih elemenata od 80% obogacenog uranijuma. Eksperiment je zavrsen krajem marta, nakon cega je zatrazena dozvola za probni rad na vecim snagama i potom za rad na punoj snazi. Uzimajuci postojece stanje reaktora RA doneto je resenje kojim se

Twenty years of chemistry associated with the needs and utilization of nuclear reactors at the 'Boris Kidric' Institute of nuclear sciences, Vinca, Yugoslavia; Dvadeset godina hemije vezane za potrebe i koriscenje nuklearnih reaktora u Institutu za nuklearne nauke 'Boris kidric' i Vinci

Energy Technology Data Exchange (ETDEWEB)

NONE

1969-07-01

This publication covers nine review papers on the following topics related to the needs and utilization of nuclear reactors in the Boris Kidric Institute of nuclear sciences during previous twenty years: radiochemistry, hot atom chemistry, isotope production, spent nuclear fuel reprocessing, chemistry of transuranium elements; liquid radioactive waste processing, purification of reactor coolant water by inorganic ion exchangers, research related to deuterium concentration processes, and chemical dosimetry at the RA reactor. [Serbo-Croat] Ova publikacija obuhvata devet radova, po sledecim naslovima, a odnose se na potrebe i uslove nuklearnih reaktora u Institutu za nuklearne nauke 'Boris Kidric' tokom prethodnih dvadeset godina: radiohemija, hemija vruceg atoma, proizvodnja radioaktivnih izotopa, prerada isluzenog nuklearnog goriva, hemija transuranskih elemenata, obrada radioaktivnih otpadnih voda, preciscavanje vode za hladjenje nuklearnih reaktora pomocu neorganskih jonoizmenjivaca, istrazivanje procesa za koncentrovanje deuterijuma i hemijska dozimetrija reaktora RA.

Distinguishing a SM-like MSSM Higgs boson from SM Higgs boson ...

Indian Academy of Sciences (India)

We explore the possibility of distinguishing the SM-like MSSM Higgs boson from the SM Higgs boson via Higgs boson pair production at future muon collider. We study the behavior of the production cross-section in SM and MSSM with Higgs boson mass for various MSSM parameters tan and A. We observe that at fixed ...

New AMS method to measure the atom ratio {sup 146}Sm/{sup 147}Sm for a half-life determination of {sup 146}Sm

Energy Technology Data Exchange (ETDEWEB)

Kinoshita, N. [Tandem Accelerator Complex, Research Facility Center for Science and Technology, University of Tsukuba (Japan); Paul, M., E-mail: paul@vms.huji.ac.il [Racah Institute of Physics, Hebrew University, Jerusalem 91904 (Israel); Alcorta, M. [Physics Division, Argonne National Laboratory, Argonne, IL 60439 (United States); Bowers, M.; Collon, P. [Department of Physics, University of Notre Dame, Notre Dame, IN 46556-5670 (United States); Deibel, C.M. [Physics Division, Argonne National Laboratory, Argonne, IL 60439 (United States); Joint Institute for Nuclear Astrophysics, Michigan State University, East Lansing, MI 46624 (United States); DiGiovine, B. [Physics Division, Argonne National Laboratory, Argonne, IL 60439 (United States); Goriely, S. [Universite Libre de Bruxelles, CP-226, Brussels 1050 (Belgium); Greene, J.P.; Henderson, D.J.; Jiang, C.L. [Physics Division, Argonne National Laboratory, Argonne, IL 60439 (United States); Kashiv, Y. [Department of Physics, University of Notre Dame, Notre Dame, IN 46556-5670 (United States); Kay, B.P.; Lee, H.Y.; Marley, S.T. [Physics Division, Argonne National Laboratory, Argonne, IL 60439 (United States); Nakanishi, T. [Faculty of Chemistry, Institute of Science and Engineering, Kanazawa University (Japan); Pardo, R.C.; Patel, N.; Rehm, K.E. [Physics Division, Argonne National Laboratory, Argonne, IL 60439 (United States); Robertson, D. [Department of Physics, University of Notre Dame, Notre Dame, IN 46556-5670 (United States); and others

2013-01-15

The extinct p-process nuclide {sup 146}Sm (t{sub 1/2} = 103 {+-} 5 Myr) is known to have been present in the Early-Solar System and has been proposed as an astrophysical chronometer. {sup 146}Sm is also intensely used to date meteorite and planetary differentiation processes, enhancing the importance of an accurate knowledge of the {sup 146}Sm half-life. We are engaged in a new determination of the {sup 146}Sm half-life in which the {sup 146}Sm/{sup 147}Sm atom ratio is determined by accelerator mass spectrometry at the ATLAS facility of Argonne National Laboratory. In order to reduce systematic errors in the AMS determination of the {sup 146}Sm/{sup 147}Sm ratios (in the range of 10{sup -7}-10{sup -9}), {sup 146}Sm and {sup 147}Sm ions were alternately counted in the same detector in the focal plane of a gas-filled magnet, respectively in continuous-wave and attenuated mode. Quantitative attenuation is obtained with the 12 MHz pulsed and ns-bunched ATLAS beam by chopping beam pulses with an RF sweeper in a ratio (digitally determined) down to 1:10{sup 6}. The experiments and preliminary results are discussed.

24/7 SM slavery.

Science.gov (United States)

Dancer, Peter L; Kleinplatz, Peggy J; Moser, Charles

2006-01-01

This study describes the nature of 24/7 SM slavery as practiced within the SM (sadomasochistic) community. These SM participants, who attempt to live full-time in owner-slave roles, represent a small proportion of those with SM interests. SM slaves have not been studied systematically to determine if and how they differ from other SM practitioners. An online questionnaire was used to obtain responses from individuals who self-identified as slaves. A total of 146 respondents participated, 53% female and 47% male, ranging in age from 18 to 72. We explored the depth of their relationships, how well they approximated "slavery," and how their relationships were structured to maintain distinct roles. Data showed that in long-term SM slave relationships, a power differential exists which extends beyond time-limited SM or sexual interactions. Owners and slaves often use common, daily life experiences or situations, such as the completion of household chores, money management, and morning or evening routines, to distinguish and maintain their respective roles. In addition, contrary to the perception of total submission, results revealed that slaves exercise free will when it is in their best interests to do so. These relationships were long-lasting and satisfying to the respondents.

Distinguishing a SM-like MSSM Higgs boson from SM Higgs boson at muon collider

International Nuclear Information System (INIS)

Singhal, Jai Kumar; Singh, Sardar; Nagawat, Ashok K.

2007-01-01

We explore the possibility of distinguishing the SM-like MSSM Higgs boson from the SM Higgs boson via Higgs boson pair production at future muon collider. We study the behavior of the production cross-section in SM and MSSM with Higgs boson mass for various MSSM parameters tanβ and m A . We observe that at fixed CM energy, in the SM, the total cross-section increases with the increase in Higgs boson mass whereas this trend is reversed for the MSSM. The changes that occur for the MSSM in comparison to the SM predictions are quantified in terms of the relative percentage deviation in cross-section. The observed deviations in cross-section for different choices of Higgs boson masses suggest that the measurements of the cross-section could possibly distinguish the SM-like MSSM Higgs boson from the SM Higgs boson. (author)

Operation and maintenance of the RA Reactor in 1985, Part 1, Annex B - Report of the Technology Service; Deo 1 - Pogon i odrzavanje nuklearnog reaktora RA u 1985. godini - Prilog B - Izvestaj o radu tehnoloske sluzbe

Energy Technology Data Exchange (ETDEWEB)

Martinc, R; Vukadin, Z; Stosic, O; Cupac, S [Institute of Nuclear Sciences Boris Kidric, Vinca, Beograd (Serbia and Montenegro)

1985-12-01

Technology service is established according to the need of unified technology control of the reactor, based on the organizational structure developed in USA, a part of which was applied at the Krsko NPP. Tasks of this service are: regular control and recording of operating reactor parameters under steady state and accidental conditions; control of chemical state of the reactor core (control of Ph values and electro conductivity of the heavy water and technical water); dosimetry parameters control and recording; safety and optimisation analyses when planning reactor core modifications; (changing the type of fuel, design of new components); cooperation with the reactor users during isotope production, activation analyses, application of neutron beams; participating in research programs; planning refueling. The most important task performed by this service was conversion of the core from 2% to 80% enriched fuel elements. A methodology for optimizing the reactor application was developed. Operation of the heavy water purification system, heavy water parameters, and operation of the gas system were controlled. Radiation and contamination levels in the working environment were measured, individual and collective doses. [Serbo-Croat] Tehnoloska sluzba uspostavljena je u skladu sa ispoljenim potrebama jedinstvene tehnoloske kontrole reaktora, oslanjajajucui se na organizacionu semu koja je razvijena u SAD, a cija je jedna varijanta primenjena na NE Krsko. Zadaci sluzbe su obavljanje sledecih zadataka: redovna kontrola i evidencija radnih parametara reaktora u redovnim i akcidentalnim uslovima; kontrola hemijskog rezima u reaktoru (kontrola PH vrednosti i elektroprovodnosti teske i tehnicke vode); kontrola i evidencija tehnicke dozimetrije; sigurnosne i optimizacione analize prilikom planiranja izmena na reaktoru (promene vrste goriva, izgradnja novih elemenata opreme); saradnja sa korisnicima reaktora prilikom prozivodnje izotopa, aktivacione analize, koriscenja

Nuclear Reactor RA Safety Report, Vol. 5, Reactor cooling systems; Izvestaj o sigurnosti nuklearnog reaktora RA, Knjiga 5, Hladjenje reaktora i pripadajuci sistemi

Energy Technology Data Exchange (ETDEWEB)

NONE

1986-11-01

RA reactor cooling system enable cooling during normal operation and under possible accidental conditions and include: technical water system, heavy water system, helium gas system, system for heavy water purification and emergency cooling system. Primary cooling system is a closed heavy water circulation system. Heavy water system is designed to enable permanent circulation and twofold function of heavy water. In the upward direction of cooling it has a coolant role and in the downward direction it is the moderator. Separate part of the primary coolant loop is the system for heavy water purification. This system uses distillation and ion exchange processes. [Serbo-Croat] Sistemi za hladjenje reaktora RA obezbedjuju hladjenje u svim rezimima eksploatacije i potenijalno udesnim satnjim i obuhvataju: sistem tehnicke vode, sistem teske vode, gasni sistem helijuma, sistem za preciscavanje teske vode i sistem za akcidentalno hladjenje. Primarni sistem za hladjenje je zatvoreni cirkulacioni sistem teske vode. Specificnost sistema teske vode vezana je za neprekidnost cirkulacije i razlicite funkcije teske vode. U uzlaznom strujanju, teske vode ima ulogu hladioca a u silaznom ulogu moderatora. Poseban deo primarnog sistema predstavlja sistem za preciscavanje teske vode. Ovaj sistem koristi destilacioni i jonoizmenjivacki postupak.

Calorimetric investigation on the Pb-Sm and Sn-Sm alloys

International Nuclear Information System (INIS)

Berrada, A.-E.-A.; Claire, Y.; Chafik el Idrissi, M.; Castanet, R.

1997-01-01

The integral enthalpy of formation of the Sm-Pb and Sm-Sn melts at 1203 K, h f , was determined by direct reaction calorimetry (drop method) in the Pb and Sn rich sides with the help of a high-temperature Tian-Calvet calorimeter. The results can be fitted respectively with reference to the mole fraction of samarium, x, as follows: f /kJmol -1 =x(1-x)(-109.8 -372.0.7x) with 0 Sm f /kJmol -1 =x(1- x)(-277.0+105.4x) with 0 Sm -1 respectively. Such negative values suggest the existence of a strong short-range order in the liquid state. The stoichiometry and the thermal stability of these associations needs additional thermodynamic determinations concerning mainly the free enthalpy of formation. It will be determined by Knudsen-effusion combined with mass spetrometry in a further work. (orig.)

The physics design of EBR-II; Physique du reacteur EBR-II; Fizicheskij raschet ehksperimental'nogo reaktora - razmnozhitelya EVR-II; Aspectos fisicos del reactor EBR-II

Energy Technology Data Exchange (ETDEWEB)

Loewenstein, W. B. [Argonne National Laboratory, Argonne, IL (United States)

1962-03-15

hexagonal del reactor los datos obtenidos en geometrias simples idealizadas, analiticas o experimentales. Se compara el rendimiento nuclear, incluso el de reproduccion, del reactor real con el del modelo teorico y se describen las variaciones a largo plazo de la reactividad y de la generacion de energia en la envoltura fertil, refiriendolas a los ciclos propuestos para el combustible y la envoltura fertil. La memoria formula consideraciones sobre la seguridad estudiando en particular la introduccion de indices de reactividad normales y anormales y la consecuencia de supuestos efectos de reactividad, que se basan en el comportamiento fisico de la aleacion combustible y de la estructura del reactor, asi como en la extrapolacion al sistema del EBR-II de los experimentos realizados con el conjunto TREAT. Por ultimo, examina el problema de la fusion del cuerpo del reactor EBR-II. (author) [Russian] Vychisleniya statisticheskogo, dinamicheskogo i dlitel'nogo rezhima reaktivnosti ehksperimental'nog o reaktora-razmnozhitel ya EBR-II dayutsya sovmestno s rezul'tatami i analizom ehksperimentov na reaktore EBR-II po dostizheniyu kritichnosti v sukhom sostoyanii i otdel'nykh ehksperimentov na reaktore ZPR-III. Osoboe vnimanie udelyaetsya problemam fizicheskogo rascheta reaktora, kotorye voznikayut posle opredeleniya printsipial'noj skhemy i do sooruzheniya ili vvoda reaktora v ehkspluatatsiyu. Opisyvayutsya analiz bezopasnosti reaktora i soobrazheniya po otsenke opasnostej, a takzheikh vliyanie na raschet reaktora. V doklade opisyvaetsya sposob ispol'zovaniya modeli EBR-II na osnovanii poluchennykh na reaktore ZPR-III dannykh, a takzhe dannykh sukhoj kritichnosti reaktora EBR-II. EHti ehksperimenty, ikh analiz i teoreticheskie vykladki yavlyayutsya osnovoj dlya opredeleniya fizicheskogo povedeniya reaktornoj sistemy. Bolee podrobno issleduyutsya ogranicheniya, prisushchie primeneniyu ehksperimental'nykh dannykh k rassmatrivaemo j ehnergeticheskoj reaktornoj sisteme. Syuda otnosyatsya

Evaluation of the exothermicity of the chemi-ionization reaction Sm + O → SmO+ + e−

International Nuclear Information System (INIS)

Cox, Richard M; Kim, JungSoo; Armentrout, P. B.; Bartlett, Joshua; VanGundy, Robert A.; Heaven, Michael C.; Ard, Shaun G.; Shuman, Nicholas S.; Viggiano, Albert A.; Melko, Joshua J.

2015-01-01

The exothermicity of the chemi-ionization reaction Sm + O → SmO + + e − has been re-evaluated through the combination of several experimental methods. The thermal reactivity (300–650 K) of Sm + and SmO + with a range of species measured using a selected ion flow tube-mass spectrometer apparatus is reported and provides limits for the bond strength of SmO + , 5.661 eV ≤ D 0 (Sm + -O) ≤ 6.500 eV. A more precise value is measured to be 5.72 5 ± 0.07 eV, bracketed by the observed reactivity of Sm + and SmO + with several species using a guided ion beam tandem mass spectrometer (GIBMS). Combined with the established Sm ionization energy (IE), this value indicates an exothermicity of the title reaction of 0.08 ± 0.07 eV, ∼0.2 eV smaller than previous determinations. In addition, the ionization energy of SmO has been measured by resonantly enhanced two-photon ionization and pulsed-field ionization zero kinetic energy photoelectron spectroscopy to be 5.7427 ± 0.0006 eV, significantly higher than the literature value. Combined with literature bond energies of SmO, this value indicates an exothermicity of the title reaction of 0.14 ± 0.17 eV, independent from and in agreement with the GIBMS result presented here. The evaluated thermochemistry also suggests that D 0 (SmO) = 5.83 ± 0.07 eV, consistent with but more precise than the literature values. Implications of these results for interpretation of chemical release experiments in the thermosphere are discussed

Strategisch management (SM)

NARCIS (Netherlands)

Nagel, A.P.; Vercouteren, W.J.J.C.; Hoek, van der N.; Lohman, T.A.M.; Vermeulen, N.

1996-01-01

Kernbegrippen die bij de discussie van strategisch management (SM) aan de orde komen, zijn productinnovatie op ondernemingsniveau (oftewel strategische productinnovatie, SPI) en technologiestrategie. In dit artikel wordt een raamwerk van SM geintroduceerd. Daartoe worden de verschillende fasen van

Operation and maintenance of the RA reactor, RA Research reactor. Annual report 1976; Pogon i odrzavanje reaktora RA, Izvestaj o radu u 1976. godini

Energy Technology Data Exchange (ETDEWEB)

Martinc, R [Institute of Nuclear Sciences Boris Kidric, Vinca, Beograd (Serbia and Montenegro)

1976-12-15

remonta do kojih je dolazilo zbog kvarova (nastalih zbog neizvrsavanja investicionog odrzavanja u toku poslednjih 6 godina) zatim nemogucnost ranijeg pocetka koriscenja novog goriva u reaktoru RA i istrosenosti rezervi starog 2% obogacenog goriva i na kraju zbog obimnog programa eksperimenata u oblasti sigurnosnih analiza vezanih za uvodjenje novog visokoobogacenog goriva u reaktor RA. Na reaktoru RA uspesno su izvrseni eksperimentalni i teorijski radovi u oblasti sigurnosnih analiza za prevodjenje reaktora RA na novo 80% obogaceno gorivo, krunisani eksperimentalnom kampanjom reaktora RA u decembru 1976, kojom se zavrsava 17-to godisnji period koriscenja 2% obogacenog goriva i otpocinje period koriscenja novog 80% obogacenog goriva u reaktoru RA. Ovaj uspeh je od izuzetnog znacaja za reaktor RA i njegove korisnike, jer ce rezultovati u povecanju osnovne proizvodnje neutronskog fluksa od 50%, pri porastu cene kostanja rada reaktora od oko 4%. Podnet je zahtev za konacno odobrenje prelaznog rezima za uvodjenje ovog goriva, kojim se postize usteda od najmanje 2 200 000 dinara. Ovim se obezbedjuje da u 1977. godini i dalje, rad reaktora ne bude vise ometan ''kriticnim'' ili drugim eksperimentima u vezi sa uvodjenjem novog goriva u reaktor. Izvrsen je obiman program remontnih i drugih radova veoma akutne prirode, koji takodje omogucuju nesmetan rad u 1977. godini. Neki od ovih radova nisu radjeni nikad ranije, a drugi nisu radjeni u proteklih 6 godina. Najzacajniji zahvati ove vrste bili su: nabavka Al-cevi od specijalne legure, izrada i montiranje tehnoloskoh kanala; obimno ispitivanje uzroka curenja spoljasnjeg suda; remont teskovodne pumpe; zamena dva vertikalna tehnoloska kanala. Nabavljena je osnovna oprema za izgradnju sistema za hladjenje u slucaju udesa. Izvrseno je opremanje vrucih komora reaktora RA.

Activity of the RA Reactor Physics group in 1980 - Definition of the Operation conditions for future safe and economical RA reactor operation with 80% enriched fuel; Prilog Ia - Rad sluzbe za fiziku reaktora RA u 1980. godini - Definisanje pogonskih uslova za dalji siguran i ekonomican rad reaktora RA sa 80% obogacenim gorivom

Energy Technology Data Exchange (ETDEWEB)

Martinc, R [Institute of Nuclear Sciences Boris Kidric, Vinca, Beograd (Serbia and Montenegro)

1980-12-15

During 1980. the RA reactor was not in operation. That is why this period was devoted to definition of operating conditions for further reactor operation with 80% enriched fuel. The fuel elements which were in the core at the moment of shutdown in March 1979will not be used again (388 80% enriched fuel elements, and 511 2% enriched fuel elements). The reactor will be operated only with 80% enriched fuel, staring with initiat core configuration with 440 elements on the borders gradually changing to equi;librium core with 720 fuel elements. The analyses were concerned with safety issues of future operation. [Serbo-Croat] Reaktor RA tokom 1980 godine nije radio. Zbog toga je ovaj period iskoriscen za intenzivan rad na definisanju pogonskih uslova za dalji rad reaktora sa 80% obogacenim gorivom. Gorivo sa kojim je reaktor prestao da radi marta 1979. godine (388 gorivnih elemenata 80% obogacenoh i 511 elementa 2% obogaceno) nece biti vraceno u jezgro, vec ce reaktor raditi samo sa 80% obogacenim gorivom, pocev od konfiguracije sa 440 elemenata na periferiji do ravnotezne konfiguracije sa 720 elemenata. Sve nalize su se bavile sigurnosnim aspektima rada reaktora sa visokoobogacenim gorivom u jezgru.

Detection of antifungal properties in Lactobacillus paracasei subsp. paracasei SM20, SM29, and SM63 and molecular typing of the strains.

Science.gov (United States)

Schwenninger, Susanne Miescher; von Ah, Ueli; Niederer, Brigitte; Teuber, Michael; Meile, Leo

2005-01-01

Lactobacilli isolated from different food and feed samples such as raw milk, cheese, yoghurt, olives, sour dough, as well as corn and grass silage, were screened for their antifungal activities. Out of 1,424 isolates tested, 82 were shown to be inhibitory to different yeasts (Candida spp. and Zygosaccharomyces bailii) and a Penicillium sp., which were previously isolated from spoiled yoghurt and fruits. Carbohydrate fermentation patterns suggested that a substantial portion, 25%, belonged to the Lactobacillus casei group, including L. casei, L. paracasei, and L. rhamnosus. The isolates SM20 (DSM14514), SM29 (DSM14515), and SM63 (DSM14516) were classified by PCR using species-specific primers to target the corresponding type strains (L. casei, L. paracasei, and L. rhamnosus) as controls. Further molecular typing methods such as randomly amplified polymorphic DNA, pulsed-field gel electrophoresis, and sequencing analysis of the 16S rRNA gene allowed classifying strains SM20, SM29, and SM63 as L. paracasei subsp. paracasei in accordance with the new reclassification of the L. casei group proposed by Collins et al.

Coercivity Recovery Effect of Sm-Fe-Cu-Al Alloy on Sm2Fe17N3 Magnet

Science.gov (United States)

Otogawa, Kohei; Asahi, Toru; Jinno, Miho; Yamaguchi, Wataru; Takagi, Kenta; Kwon, Hansang

2018-03-01

The potential of a Sm-Fe-Cu-Al binder for improvement of the magnetic properties of Sm2Fe17N3 was examined. Transmission electron microscope (TEM) observation of a Sm-Fe-Cu-Al alloy-bonded Sm2Fe17N3 magnet which showed high coercivity revealed that the Sm-Fe-Cu-Al alloy had an effect of removing the surface oxide layer of the Sm2 Fe17N3 grains. However, the Sm-Fe-Cu-Al binder was contaminated by carbon and nitrogen, which originated from the organic solvent used as the milling medium during pulverization. To prevent carbon and nitrogen contamination, the Sm-Fe- Cu-Al alloy was added directly on the surface of the Sm2Fe17N3 grains by sputtering. Comparing the recovered coercivity per unit amount of the added binder the uncontaminated binder-coated sample had a higher coercivity recovery effect than the milled binder-added sample. These results suggested that sufficient addition of the contamination-free Sm-Fe-Cu-Al binder has the possibility to reduce the amount of binder necessary to produce a high coercive Sm2Fe17N3 magnet.

RA reactor action plan for 1977 - Annex VI; Prilog VI - Plan rada reaktora RA za 1977. godinu

Energy Technology Data Exchange (ETDEWEB)

NONE

1976-12-15

In the RA reactor action plan for 1977 it is foreseen that the reactor would be operated for 181 days, mostly at nominal power of 6.5 MW. It is planned to produce 28236 MWh in total. Five reactor core exchanges (refuelling) are planned. The plan includes time for repair of components as well as for cooling. [Serbo-Croat] Plan rada reaktora RA predvidja rad tokom 181 dana, vecim delom na nominalnoj snazi od 6,5 MW tokom 1977. godine. Planirano je da ukupni rad iznosi 28236 MWh. Planom je predvidjeno i pet izmena goriva kao i vreme potrebno za remont opreme i hladjenje.

Wet storage of nuclear spent fuel from nuclear research reactor WWR-S

International Nuclear Information System (INIS)

Dragolici, A. C; Zorliu, A.; Petran, C.; Mincu, I.

2001-01-01

Nuclear research reactor WWR-S of IFIN-HH was commissioned on 29 July 1957 and shut down on December 1997. Now it is in Conservation State. During 40 years , the reactor was operated about 150,000 hours at variable power level ranging within 5 W and 3500 kW, and producing a total power of 9,510 MWday. After 20 years of operation a large number of spent fuel elements became available for storage exceeding the stocking capacity of the small cooling pond near reactor. Therefore, in 1980 the nuclear spent fuel repository was commissioned that contains at present all the fuel elements burnt in the reactor during years, minus 51 S-36 fuel assemblies which are conserved in the cooling pond. This repository contains 4 identical ponds, each of them having the storage capacity of 60 fuel assemblies. Every pond having the outer sizes of 2,750 mm (length) x 900 mm (breadth) x 5,700 mm (depth), is made from a special aluminum alloy (AlMg 3 ), with the walls thickness of 10 mm and bottom thickness of 15 mm. Pond's lids are made of cast iron having the thickness of 500 mm; they provide only the biological protection for the maintenance personnel. A 1.5 m concrete layer ensures the biological protection of the ponds. Over the fuel elements in every pond a 4.5 m water layer is provided, playing the role of biological protection and coolant. Inside the ponds exists an aluminum rack, which contains 60 locations for fuel storage. The spacing between these locations was determined from considerations of criticality and it is was the same with that of the cooling pond near the reactor. To have supplementary protection in the case of an accident which can destroy the entire rack and put together all the fuel elements thus forming critical mass, cadmium plates were placed on the ponds bottom for a better neutron absorption. Exploitation of cooling pond near the WWR-S reactor which has the identical structure with that of nuclear spent fuel repository, demonstrate the reliability and

Seismic examination for assessment of safety of location of atomic energy objects (by the example of the WWR-K reactor, Ala-Tau village)

International Nuclear Information System (INIS)

Belyashova, N.N.

2001-01-01

In the Republic of Kazakhstan there are 3 research reactors (the fourth one is temporarily stopped). One of the reactors in 1998 (WWR-K, situated in the Ala Tau village, nearby Almaty city) was conserved because of a number of reasons. Including the reason of the earth crust geological structure insufficient study for the ensuring the seismic safety of the reactor site location. In 1994-1996 a number of geological-geophysical studies was carried out by Kazakhstan specialists confirming the the geological-geophysical conditions in the reactor site location in view of its safety. These condition are meeting to IAEA requirements and up-to-date standards acting in Kazakhstan

Temperature dependence of spin and orbital magnetic moments of Sm 4f electrons in (Sm, Gd)Al2

International Nuclear Information System (INIS)

Qiao, S.; Kimura, A.; Adachi, H.; Iori, K.; Miyamoto, K.; Xie, T.; Namatame, H.; Taniguchi, M.; Tanaka, A.; Muro, T.; Imada, S.; Suga, S.

2005-01-01

X-ray magnetic circular dichroism studies were carried out on (Sm, Gd)Al 2 , a ferromagnet without net magnetization at a certain compensation temperature. For Sm 4f electrons, the following understandings were obtained: the magnitude of expectation value of orbital magnetic moment (m L Sm ) is always larger than that of spin one (m S Sm ), so the cancellation of total spin and orbital magnetic moments cannot be achieved only by Sm 4f electrons and the contributions from Gd ions and conduction electrons are important; when the temperature decreases, the magnitude of both m L Sm and m S Sm increases and the gross magnetic moment due to the Sm 4f electrons monotonically deviates from zero. These results tell us that the temperature dependence of magnetic moments related with the electrons other than Sm 4f ones may play important roles in the subtle adjustment of the total spin and orbital magnetic moments to the zero magnetization at the compensation temperature

Dielectric spectroscopy of the SmQ* phase

Science.gov (United States)

Perkowski, P.; Bubnov, A.; Piecek, W.; Ogrodnik, K.; Hamplová, V.; Kašpar, M.

2011-11-01

Liquid crystal possessing two biphenyl moieties in the molecular core and lateral chlorine substitution far from the chiral chain has been studied by dielectric spectroscopy. On cooling from the isotropic phase, the material possesses the frustrated smectic Q* (SmQ*) and SmCA* phases. It has been confirmed by dielectric spectroscopy that the SmQ* phase can be related to the SmCA* anti-ferroelectric phase. However, only one relaxation process has been observed in the SmQ* phase, while in the SmCA*, two relaxations are clearly detectable. It seems that the mode found in the SmQ* can be connected with high-frequency anti-phase mode observed in the SmCA* phase. Its relaxation frequency is similar to PH relaxation frequency, but is weaker. The same relaxation has been observed even a few degrees above the SmQ*-Iso phase transition. Another explanation for the mode detected in SmQ* and isotropic phases can be molecular motions around short molecular axis.

Optical isotype shifts of 146Sm and 151Sm

International Nuclear Information System (INIS)

Eastham, D.A.; Walker, P.M.; Griffith, J.A.R.; Evans, D.E.; England, J.G.; Grant, I.S.

1984-01-01

We have measured the optical isotope shifts of 146 Sm and 151 Sm by laser resonance fluorescence. From these measurements the changes in the mean square nuclear radii are: delta 2 > (A=144 to 146)=0.266(10) fm 2 , and delta 2 > (A=151 to 152)=0.262(10) fm 2 . These results, together with those of the stable isotopes, show that the average nuclear expansion of samarium can be accounted for by the liquid drop model with deformations. (orig.)

SM18 Visits and Access

CERN Multimedia

2012-01-01

  VISITS The rules and conditions to be followed for visits in the SM18 Hall are laid out in the EDMS 1205328 document. No visit is allowed without prior reservation.   ACCESS Special access right is needed ONLY from 7 p.m. to 7 a.m. and during week-ends. From 1 December, the current SM18 access database will be closed and a new one “SM18-OWH outside normal hours” started from scratch. Requests, via EDH SM18-OWH, will have to be duly justified.   For further information, please contact Evelyne Delucinge.

HDDR in Sm-Co alloys - a new method for magnetic hardening of Sm-Co permanent magnets

Energy Technology Data Exchange (ETDEWEB)

Kubis, M.; Handstein, A.; Gebel, B.; Mueller, K.-H.; Schultz, L. [Institut fuer Festkoerper- und Werkstofforschung Dresden e.V. (Germany). Inst. fuer Metallische Werkstoffe; Gutfleisch, O. [Institut fuer Festkoerper- und Werkstofforschung Dresden e.V. (Germany). Inst. fuer Metallische Werkstoffe]|[Birmingham Univ. (United Kingdom). School of Metallurgy and Materials

1998-07-01

Investigations on the hydrogen absorption behavior of different Sm-Co alloys with 1:5 and 2:17 structure by differential scanning calorimetry (DSC) at enhanced hydrogen pressures between 1 MPa and 7 MPa indicated different hydrogen absorption events. X-ray diffraction (XRD) studies and microstructural investigations showed clearly the disproportionation of the Sm-Co phases into Sm hydride and Co or Co-rich phases for hydrogen pressures above 0.5 MPa. The favourable effect of high hydrogen pressures can be explained in terms of a decrease of the free enthalpy of the samarium hydride for increasing hydrogen pressures. Additionally, Sm-Co alloys of both types were reactively milled under hydrogen at enhanced temperatures. The reactively milled powders showed again the products of the disproportionation reaction. A recombination of Sm-Co phases by removing the hydrogen in a second heat treatment was successful for both methods. Investigations of the magnetic properties showed coercivities {mu}{sub OJ}H{sub C} of up to 2.1 T for high pressure HDDR powders of SmCo{sub 5} material, demonstrating clearly the positive effect of the hydrogen treatment on the coercivity. The reactively milled powders showed for recombination temperatures {<=}700 C a remanence enhancement which could be attributed to the exchange coupling of the nanoscaled grains. A maximum coercivity {mu}{sub OJ}H{sub C} of 3.7 T was achieved for SmCo{sub 5} and a maximum energy product (BH){sub max} of 82 kJ/m{sup 3} was measured for an Sm-rich Sm{sub 2}Co{sub 17} sample. (orig.)

HDDR in Sm-Co alloys - a new method for magnetic hardening of Sm-Co permanent magnets

International Nuclear Information System (INIS)

Kubis, M.; Handstein, A.; Gebel, B.; Mueller, K.-H.; Schultz, L.; Gutfleisch, O.; Birmingham Univ.

1998-01-01

Investigations on the hydrogen absorption behavior of different Sm-Co alloys with 1:5 and 2:17 structure by differential scanning calorimetry (DSC) at enhanced hydrogen pressures between 1 MPa and 7 MPa indicated different hydrogen absorption events. X-ray diffraction (XRD) studies and microstructural investigations showed clearly the disproportionation of the Sm-Co phases into Sm hydride and Co or Co-rich phases for hydrogen pressures above 0.5 MPa. The favourable effect of high hydrogen pressures can be explained in terms of a decrease of the free enthalpy of the samarium hydride for increasing hydrogen pressures. Additionally, Sm-Co alloys of both types were reactively milled under hydrogen at enhanced temperatures. The reactively milled powders showed again the products of the disproportionation reaction. A recombination of Sm-Co phases by removing the hydrogen in a second heat treatment was successful for both methods. Investigations of the magnetic properties showed coercivities μ OJ H C of up to 2.1 T for high pressure HDDR powders of SmCo 5 material, demonstrating clearly the positive effect of the hydrogen treatment on the coercivity. The reactively milled powders showed for recombination temperatures ≤700 C a remanence enhancement which could be attributed to the exchange coupling of the nanoscaled grains. A maximum coercivity μ OJ H C of 3.7 T was achieved for SmCo 5 and a maximum energy product (BH) max of 82 kJ/m 3 was measured for an Sm-rich Sm 2 Co 17 sample. (orig.)

The Protein Kinase SmSnRK2.6 Positively Regulates Phenolic Acid Biosynthesis in Salvia miltiorrhiza by Interacting with SmAREB1.

Science.gov (United States)

Jia, Yanyan; Bai, Zhenqing; Pei, Tianlin; Ding, Kai; Liang, Zongsuo; Gong, Yuehua

2017-01-01

Subclass III members of the sucrose non-fermenting-1-related protein kinase 2 (SnRK2) play essential roles in both the abscisic acid signaling and abiotic stress responses of plants by phosphorylating the downstream ABA-responsive element (ABRE)-binding proteins (AREB/ABFs). This comprehensive study investigated the function of new candidate genes, namely SmSnRK2.3 , SmSnRK2.6 , and SmAREB1 , with a view to breeding novel varieties of Salvia miltiorrhiza with improved stress tolerance stresses and more content of bioactive ingredients. Exogenous ABA strongly induced the expression of these genes. PlantCARE predicted several hormones and stress response cis -elements in their promoters. SmSnRK2.6 and SmAREB1 showed the highest expression levels in the leaves of S. miltiorrhiza seedlings, while SmSnRK2.3 exhibited a steady expression in their roots, stems, and leaves. A subcellular localization assay revealed that both SmSnRK2.3 and SmSnRK2.6 were located in the cell membrane, cytoplasm, and nucleus, whereas SmAREB1 was exclusive to the nucleus. Overexpressing SmSnRK2.3 did not significantly promote the accumulation of rosmarinic acid (RA) and salvianolic acid B (Sal B) in the transgenic S. miltiorrhiza hairy roots. However, overexpressing SmSnRK2.6 and SmAREB1 increased the contents of RA and Sal B, and regulated the expression levels of structural genes participating in the phenolic acid-branched and side-branched pathways, including SmPAL1 , SmC4H , Sm4CL1 , SmTAT , SmHPPR , SmRAS , SmCHS , SmCCR , SmCOMT , and SmHPPD . Furthermore, SmSnRK2.3 and SmSnRK2.6 interacted physically with SmAREB1. In summary, our results indicate that SmSnRK2.6 is involved in stress responses and can regulate structural gene transcripts to promote greater metabolic flux to the phenolic acid-branched pathway, via its interaction with SmAREB1 , a transcription factor. In this way, SmSnRK2.6 contributes to the positive regulation of phenolic acids in S. miltiorrhiza hairy roots.

The Protein Kinase SmSnRK2.6 Positively Regulates Phenolic Acid Biosynthesis in Salvia miltiorrhiza by Interacting with SmAREB1

Directory of Open Access Journals (Sweden)

Yanyan Jia

2017-08-01

Full Text Available Subclass III members of the sucrose non-fermenting-1-related protein kinase 2 (SnRK2 play essential roles in both the abscisic acid signaling and abiotic stress responses of plants by phosphorylating the downstream ABA-responsive element (ABRE-binding proteins (AREB/ABFs. This comprehensive study investigated the function of new candidate genes, namely SmSnRK2.3, SmSnRK2.6, and SmAREB1, with a view to breeding novel varieties of Salvia miltiorrhiza with improved stress tolerance stresses and more content of bioactive ingredients. Exogenous ABA strongly induced the expression of these genes. PlantCARE predicted several hormones and stress response cis-elements in their promoters. SmSnRK2.6 and SmAREB1 showed the highest expression levels in the leaves of S. miltiorrhiza seedlings, while SmSnRK2.3 exhibited a steady expression in their roots, stems, and leaves. A subcellular localization assay revealed that both SmSnRK2.3 and SmSnRK2.6 were located in the cell membrane, cytoplasm, and nucleus, whereas SmAREB1 was exclusive to the nucleus. Overexpressing SmSnRK2.3 did not significantly promote the accumulation of rosmarinic acid (RA and salvianolic acid B (Sal B in the transgenic S. miltiorrhiza hairy roots. However, overexpressing SmSnRK2.6 and SmAREB1 increased the contents of RA and Sal B, and regulated the expression levels of structural genes participating in the phenolic acid-branched and side-branched pathways, including SmPAL1, SmC4H, Sm4CL1, SmTAT, SmHPPR, SmRAS, SmCHS, SmCCR, SmCOMT, and SmHPPD. Furthermore, SmSnRK2.3 and SmSnRK2.6 interacted physically with SmAREB1. In summary, our results indicate that SmSnRK2.6 is involved in stress responses and can regulate structural gene transcripts to promote greater metabolic flux to the phenolic acid-branched pathway, via its interaction with SmAREB1, a transcription factor. In this way, SmSnRK2.6 contributes to the positive regulation of phenolic acids in S. miltiorrhiza hairy roots.

SM-1420 computer conjugation with the ES-5017 magnetic tape storage device and the SM-6313 printer

International Nuclear Information System (INIS)

Zhurkin, V.V.; Safonov, A.A.; Troitskij, A.N.

1987-01-01

The flow sheets are given and the methods of the technical implementation of expansion units of SM 5002.4 controllers to connect NML ES-5017 and analogue-digital printer ATsPU SM-6818, respectively, to SM-1420 computer are described

Småhuse: Indretning og funktion

DEFF Research Database (Denmark)

Hansen, Ernst Jan de Place; Sigbrand, Lone; Frandsen, Anne Kathrine

Denne anvisning omhandler generelle krav og anbefalinger til indretning og funktion af nybyggede småhuse i henhold til bestemmelserne i Bygningsreglement 2010 (BR10). Småhuse - Indretning og funktionSmåhuse omfatter fritliggende og sammenbyggede enfamiliehuse med lodret lejlighedsskel i indtil...

Excited states in 146Sm and 147Sm

International Nuclear Information System (INIS)

Kownacki, J.; Sujkowski, Z.; Hammaren, E.; Liukkonen, E.; Piiparinen, M.; Lindblad, Th.; Ryde, H.

1979-10-01

The sup(144,146)Nd(α,xn) and sup(146,148)Nd( 3 He,xn) reactions with Esub(α) = 20 - 43 MeV and E 3 sub(He) = 19 - 27 MeV are used to investigate excited states in the isotopes 146 Sm and 147 Sm. The experiments involve measurements of singles γ-ray spectra and conversion electron spectra, γ-ray angular distributions and three parameter (E sub(γ)E sub(γ) time) coincidences. From these experiments information is obtained for states with spin up to I = 13 + and I = 27/2 - , respectively, These states are interpeted within the framework of the cluster-vibration model (CVM) as well as the shell model. (author)

RA reactor Action plan for 1978 - Annex VI; Prilog VI - Plan rada reaktora RA za 1978. godinu

Energy Technology Data Exchange (ETDEWEB)

NONE

1977-12-15

This annex include a detailed monthly action plan of the RA reactor for 1978. It was planned that the reactor will operate at nominal and lower power levels for 158 days. The plan is made with the aim to achieve same annual neutron flux as in 1977, which is somewhat higher then the annual production in the period from 1968-1975. [Serbo-Croat] Ovaj prilog sadrzi detaljan plan rada reaktora RA za 1978. godinu. Planirano je da reaktor radi na nominalnoj snazi of 6,5 MW i na manjim snagama ukupno 158 dana. Plan je napravljen tako da se ostvari godisnja proizvodnja neutronskog fluksa u obimu koji je relaizovan 1977. godine sto je nesto vise od godisnje proizvodnje u periodu 1968-1975.

Operation, maintenance and utilization of the RA reactor, Annual report for 1980; Pogon, odrzavanje i eksploatacija reaktora RA, Izvestaj o radu u 1980. godini

Energy Technology Data Exchange (ETDEWEB)

Milosevic, M [Institute of Nuclear Sciences Boris Kidric, Vinca, Beograd (Serbia and Montenegro)

1980-12-15

During 1980 the activities of RA reactor staff was conducted in two directions: repair works and determination of the state of the existing equipment; and preparing and constructing additional equipment and completing the documentation needed to fulfill the new legal regulations. preparation of the existing equipment for future operation was finished, but construction of the additional equipment (according to the regulations) is not done at planned rate due to different reasons such as lack of budget, administration, import. This report includes a chapter devoted to the analysis of the operation difficulties that caused prohibition of reactor operation as well as difficulties in achievement of the planned activities for 1980. Data about financial issues are included as well. [Serbo-Croat] U toku 1980. godine rad OOUR-a Nuklearni reaktor RA odvijao se u dva smera: remontnim radovima i utvrdjivanju stanja postojece opreme i u pripremi i ugradnji potrebne dodatne opreme i kompletiranju neophodne dokumentacije prema novim zakonskim propisima. Priprema postojece opreme za rad je u potpunosti izvrsena, dok se projekti i ugradnja dodatne opreme (prema zakonskim obavezama) ne odvija potrebnom brzinom zbog raznih objektivnih razloga, kao nedostatak sredstava, odobrenja, uvoza. Ovaj izvestaj sadrzi poglavlje posveceno analizi teskoca u radu koje su dovele do zabrane rada reaktora, i teskoca u realizovanju plana rada u 1980. godini, ako i podatke o finansiranju projekta 'pogon, odrzavanje i eksploatacija reaktora RA'.

Neutron flux calculations for the Rossendorf research reactor in (hex)- and (hex,z)-geometry using SNAP-3D

International Nuclear Information System (INIS)

Koch, R.; Findeisen, A.

1986-04-01

The multigroup neutron diffusion theory code SNAP-3D has been used to perform time independent neutron flux and power calculations of the 10 MW Rossendorf research reactor of the type WWR-SM. The report describes these calculations, as well as the actual reactor configuration, some details of the code SNAP-3D, and two- and three-dimensional reactor models. For evaluating the calculations some flux values and control rod worths have been compared with those of measurements. (author)

Experimental operation of the RA reactor with 4 fuel channels containing 80% enriched dispersion fuel - Operational Report; Radni izvestaj - Eksperimentalna kampanja reaktora RA sa 4 kanala sa 80% obogacenim disperzionim gorivom

Energy Technology Data Exchange (ETDEWEB)

Martinc, R; Milosevic, M; Cupac, S; Kozomara, S [Institute of Nuclear Sciences Boris Kidric, Vinca, Beograd (Serbia and Montenegro)

1976-12-15

usmerene su na prelazni rezim na bazi parcijalnog uvodjenja novog goriva u reaktor, tj. na reaktorsko jezgro sa dve vrste goriva. Cilj ovih analiza i priprema jeste obezbedjivanje svih uslova za siguran rad reaktora RA u prelaznom rezimu. Ove analize i pripreme su uglavnom kompletirane. Medjutim, nedostaje jos eksperimentalni podatak o utrosku goriva za odredjeni rad reaktora na nominalnoj snazi tj. o dnevnom padu ugradjenog viska reaktivnosti. Ovaj podatak neophodan je kod planiranja izmena goriva (kolicine svezeg goriva i ucestanosti izmena) u prelaznom rezimu. Do ovog podatka moze se doci samo putem normalnog rada reaktora u toku vremena znatno duzeg od vremena u kome se uspostavlja ravnotezno zatrovanje, kao vremena izmedju dva prelivanja D{sub 2}O kondenzata u aktivnu zonu RA. U tom smislu je planirana desetodnevna eksperimentalna kampanja u decembru 1976. U ovom izvestaju izlozeni su oni najznacajniji rezultati sigurnosnih analiza i priprema koji ukazuju na potpunu sigurnost rada reaktora tokom ove eksperimentalne kampanje, sa aspekta postovanja ogranicenja najvaznijih parametara koji uticu na sigurnost reaktora, kao sto su reaktivnost, toplotna i temperaturska ogranicenja za gorivo i za reaktor, itd. Podaci koji budu dobijeni iz ove eksperimentalne kampanje su od znacaja jer ce se na osnovu njih konacno definisati dalji protok svezeg novog goriva, tokom prelaznog rezima (author)

Mass of the 158Sm

International Nuclear Information System (INIS)

Zhao Kui; Guo Jiyu; Lu Xiuqin; Cheng Yehao; Huang Xiaolin; Ma Yong; Li Shuyuan; Ruan Ming; Li Zhichang; Jiang Chenglie

1997-01-01

A preliminary result was reported for the experiment to determine the mass of the heavier neutron-rich nucleus 158 Sm using the 160 Gd( 18 O, 20 Ne) two proton transfer reaction in last progress report. The average Q-value of (4.046 +- 0.102) MeV for the 160 Gd( 18 O, 20 Ne) 158 Sm reaction is given. A mass excess for 158 Sm of (-65.738 +- 0.102) MeV was derived. This is the first experimentally measured value of the mass of 158 Sm which is about 450 keV higher than the evaluation value from systematic trends listed in the 1993 atomic mass table. The new prediction shows better agreement with the measured values and a significant improvement over the earlier FRDM (finite-range droplet model) value

Preparation and quality control of {sup 153}Sm radiopharmaceuticals

Energy Technology Data Exchange (ETDEWEB)

Swasono, R Tamat; Widyastuti, W; Purwadi, B; Laksmi, I [Radioisotope Production Center - BATAN, Jakarta (Indonesia)

1998-10-01

The paper summarizes the preparation and quality control of {sup 153}Sm-EDTMP and three {sup 153}Sm-radiosynovectomy agents. Natural and enriched Sm{sub 2}O{sub 3} (98.7% {sup 152}Sm) irradiated in RSG-GAS 30 MW reactor yielded pure and high specific activity {sup 153}Sm. Labeling of EDTMP with {sup 153}Sm was carried out by mixing {sup 153}SmCl{sub 3} solution of pH 4.0 to an EDTMP solution at room temperature then pH adjustment to 8. The {sup 153}Sm-EDTMP complex was separated from the free {sup 153}Sm{sup +3} on a Chelex 100 column. Radiochemical purity was determined by thin layer chromatography using Cellulose sheets and pyridine: ethanol: water (1: 2: 4) mixture as solvent. The {sup 153}Sm-EDTMP has been shown to be stable for two weeks. Three particulate preparations of {sup 153}Sm used for the irradiation of chronic synovitis have been studied. They are hydroxyapatite particles, human serum albumin microspheres and ferric hydroxide macroaggregates. The {sup 153}Sm-ferric hydroxide macroaggregates were prepared in a single step by coprecipitation of {sup 153}Sm in the formation of Fe(OH){sub 3}. Preparation of {sup 153}Sm-labelled hydroxyapatite particles and {sup 153}Sm-labelled albumin microspheres were carried out by {sup 153}Sm labelling of previously prepared particles. Radiolabelling efficiency were greater than 95% for hydroxyapatite particles and macroaggregates and was lower than 20% for albumin microspheres. The particle sizes were inspected using an optical microscope with a haemocytometer and micrometric ocular. (author)

RA reactor operation and maintenance, Annual report 1974; Pogon i odrzavanje reaktora RA - Izvestaj o radu u 1974. godini

Energy Technology Data Exchange (ETDEWEB)

Milosevic, D et al [Institute of Nuclear Sciences Boris Kidric, Vinca, Beograd (Serbia and Montenegro)

1974-12-15

During 1974, RA reactor was operated at nominal power for 194 days and 13 days at lower power levels. The total production was 30711 MWh which is 2.4% higher than planned. Practically there were no discrepancies from the plan. The reactor was used for irradiation and experiments according to the demand of 437 users. This report contains detailed data about reactor power and experiments performed in 1974. Total number of afety shutdowns was 11, of which 8 were caused by power cuts, and 3 due to human error. Maximum individual personnel exposure dose was 50% of the maximum permissible dose. There were no accidents during this year. Decontamination of surfaces was less than during previous years. About 805 m{sup 2} of surfaces and 178 objects were decontaminated. It was concluded that the successful operation in 1974 has a special significance taking into account the financial problems. [Serbo-Croat] Reaktor RA je u 1974. godini radio na nominalnoj snazi 194 dana i 13 dana na manjim snagama. Ukupni rad iznosio je 30711 MWh odnosno 1,4% vise od planiranog. Prakticno nije bilo odstupanja od plana rada. Reaktor je koriscen za ozracivanja i eksperimente za 437 korisnika. Ovaj izvestaj sadrzi detaljne podatke o radu i eksperimentima koji su obavljani. U toku godine bilo je 11 sigurnosnih zaustavljanja, od cega 8 zbog elektricnog napona i 3 usled greske osoblja. Ukupna doza ozracivanja ljudstva bila je manja nego prethodnih godina. Maksimalna doza po oveku bila je 50% manja od maksimalno dozvoljene doze. Nije bilo ni jednog akcidenta. Dekontaminirano je znatno manje povrsina nego ranijih godina, i sakupljeno manje otpada nego prethodnih godina, dok tecnih efluenata nije bilo. Zakljuceno je da uspesan rad reaktora u 1974. godini ima poseban znacaj kada se imaju na umu problemi finansiranja reaktora.

Purification of cooling water for nuclear reactors using ion exchangers; Preciscavanje vode za hladjenje nuklearnih reaktora pomocu neorganskih jonoizmenjivaca

Energy Technology Data Exchange (ETDEWEB)

Ruvarac, A [Institute of Nuclear Sciences Boris Kidric, Vinca, Beograd (Serbia and Montenegro)

1969-07-01

Zirconiumphosphate, zirconiumoxide and natural magnetite as inorganic substances with favourable adsorption properties were the subject of investigations dealing with problems of water purification for nuclear rector cooling. Study on adsorption of impurities form reactor water to 300 deg C and 100 Atm was done by specially constructed autoclaves. On the other hand, a pre-project covering a laboratory plant for investigation of inorganic ion exchangers under real dynamic conditions is given. In order to obtain necessary data on the basis of which techno-economical analyses regarding utilization of zirconiumphosphate, zirconiumoxide and magnetite for water purification is cooling the reactors types BWR and PWR, could be performed, systematic investigations of physical and chemical properties of these substances were commenced. Equilibrium constants have been determined for adsorption processes at different pH values, as well as under various temperatures. Obtained equilibrium constants were used for calculation of thermodynamic quantities {delta}H, {delta}G and {delta}S (author) [Serbo-Croat] Cirkonijumfosfat, cirkonijumoksid i prirodni magnet, kao neorganski materijali sa pogodnim adsorpcionim osobinama, bili su predmet istrazivanja vezanih za probleme preciscavanja vode za hladjenje nuklearnih reaktora. Izucavanje adsorpcije necistoca iz reaktorske vode do 300 deg C i 100 Atm vrseno je pomocu specijalno konstruisanog autoklava, a za ispitivanje neorganskih jonoizmenjivaca pri realnim dinamickim uslovima dat je idejni projekt jednog laboratorijskog postrojenja. Za dobijanje potrebnih podataka, na osnovu kojih se mogu napraviti tehno-ekonomske analize o koriscenju cirkonijumfosfata, cirkoijumoksida i magnetita za preciscavanje vode za hladjenje reaktora tipa BWR i PWR, zapoceto je sa sistematskim proucavanjima fizickih i hemijskih osobina pomenutih materijala, odredjivane su konstante ravnoteze za procese adsorpcije pri razlicitim pH vrednostima, kao i na razlicitim

Computer control system synthesis for nuclear power plants through simplification and partitioning of the complex system model into a set of simple subsystems

International Nuclear Information System (INIS)

Zobor, E.

1978-12-01

The approach chosen is based on the hierarchical control systems theory, however, the fundamentals of other approaches such as the systems simplification and systems partitioning are briefly summarized for introducing the problems associated with the control of large scale systems. The concept of a hierarchical control system acting in broad variety of operating conditions is developed and some practical extensions to the hierarchical control system approach e.g. subsystems measured and controlled with different rates, control of the partial state vector, coordination for autoregressive models etc. are given. Throughout the work the WWR-SM research reactor of the Institute has been taken as a guiding example and simple methods for the identification of the model parameters from a reactor start-up are discussed. Using the PROHYS digital simulation program elaborated in the course of the present research, detailed simulation studies were carried out for investigating the performance of a control system based on the concept and algorithms developed. In order to give a real application evidence, a short description is finally given about the closed-loop computer control system installed - in the framework of a project supported by the Hungarian State Office for Technical Development - at the WWR-SM research reactor where the results obtained in the present IAEA Research Contract were successfully applied and furnished the expected high performance

Study of the absorbers and gaps influence on the reactor reactivity, IZ-061-0071-1961; Ispitivanje uticaja apsorbera i supljina na reaktivnost reaktora, IZ-061-0071-1961

Energy Technology Data Exchange (ETDEWEB)

Martinc, R [Institute of Nuclear Sciences Boris Kidric, Vinca, Beograd (Serbia and Montenegro)

1961-12-15

It has been foreseen by the contract to study theoretically and experimentally the influence of the absorbers and gaps on the reactivity of the reactor. Within theoretical study it was planned to develop a method and find the approximation methods for calculations of these effects. Experimental part include development of equipment and performing the experiment at the RB reactor. Since it has not been possible to perform the experiment due to lack of heavy water, only the theoretical part of the task was completed with additional theoretical study of the VISA-1 experimental loop. This report includes the following annexes: influence of absorbers and gaps on the reactivity of the reactor, and calculation of flux depression in the VISA-1 loop. [Serbo-Croat] Ugovor predvidja teorijske i eksperimentalne radove u vezi ispitivanja uticaja apsorbera i praznina na reaktivnost reaktora. Za teorijski deo predvidjena je razrada metode i nalazenje aproksimativnih metoda za proracun ovih efekata. Eksperimentalni deo predvidja pripremu uredjaj i izvodjenje eksperimenata na reaktoru RB. S obzirom na nedostatak teske vode i nemogucnost izvodjenja eksperimenata, zadatak je obavljan samo teorijski a dodata mu je i teorijska obrada petlje VISA-1. Zadatak sadrzi sledece priloge: uticaj apsorbera i supljina na reaktivnost reaktora i proracun depresije fluksa u petlji VISA-1.

Generation of the problem-dependent data libraries for IFIN-HH WWR-S spent fuel storage criticality and dose calculation

International Nuclear Information System (INIS)

Ene, Daniela; Tigau, F.

1998-01-01

The methods used for the radioactivity inventory calculation and dose evaluation of the fuel elements irradiated in the WWR-S IFIN-HH reactor are discussed in this work. A particular attention is paid to the processed problem-dependent nuclear libraries. SAS2H, a complex sequence of the SCALE-4.3 code system containing the modules BONAMI - NITAWL - XSDRNPM - COUPLE - ORIGEN-S - XSDOSE, has been assimilated on the IFIN-HH computer and applied to update the ORIGEN-S libraries by producing problem-dependent processed data libraries needed to perform the depletion and shielding analysis. This sequence uses one of the eight associated data libraries of the SCALE-4.3 system according to the choice of the user. The method consists in the following analysis processes: i) lattice cell neutron analysis to produce the flux weighting spectrum for activation library updating; ii) update of the nuclear data constants of the ORIGEN-S libraries; iii) depletion and decay analysis for a specified fuel assembly and irradiation history in order to generate gamma and neutron source strength and spectra. iv) one-dimensional radial shielding calculation for the evaluation of the angular neutron and gamma flux at the surface of a spent fuel shipping cask and further calculation of the dose rates at various points outside the cask. An efficient alternative of the calculation sequence mentioned above is the ARP (Automatic Rapid Processing) method conceived in order to generate independently ORIGEN-S libraries and to reduce substantially the running time. The substance of this method is the generation of the problem-dependent libraries from basis libraries a priori created by SAS2H for specific fuel assembly type and further interpolation of two independent variables, enrichment and burnup. Specific applications concerning WWR-S spent fuel were performed: i) generation of three problem-dependent libraries for the S-36 fuel assembly taking into account the maximum value of the burnup of this

Orange and reddish-orange light emitting phosphors: Sm{sup 3+} and Sm{sup 3+}/Eu{sup 3+} doped zinc phosphate glasses

Energy Technology Data Exchange (ETDEWEB)

Meza-Rocha, A.N., E-mail: ameza@fis.cinvestav.mx [Departamento de Física, Universidad Autónoma Metropolitana-Iztapalapa, P.O. Box 55-534, 09340 México D.F., México (Mexico); Speghini, A. [Dipartimento di Biotecnologie, Universita di Verona and INSTM, UdR Verona, Strada Le Grazie 15, I-37314 Verona (Italy); IFAC CNR, Nello Carrara Institute of Applied Physics, MDF Lab, I-50019 Sesto Fiorentino, FI (Italy); Bettinelli, M. [Dipartimento di Biotecnologie, Universita di Verona and INSTM, UdR Verona, Strada Le Grazie 15, I-37314 Verona (Italy); Caldiño, U. [Departamento de Física, Universidad Autónoma Metropolitana-Iztapalapa, P.O. Box 55-534, 09340 México D.F., México (Mexico)

2015-11-15

A spectroscopy study of Sm{sup 3+} and Sm{sup 3+}/Eu{sup 3+} doped zinc phosphate glasses is performed through photoluminescence spectra and decay time profile measurements. Under Sm{sup 3+} excitation at 344 nm, the Sm{sup 3+} singly doped glass shows an orange global emission with x=0.579 and y=0.414 CIE1931 chromaticity coordinates, whereas the Sm{sup 3+}/Eu{sup 3+} co-doped sample exhibits orange overall emissions (x=0.581 and y=0.398, and x=0.595 and y=0.387) and reddish-orange overall emission (x=0.634 and y=0.355) upon excitations at 344, 360 and 393 nm, respectively. Such luminescence from the co-doped sample is originated by the simultaneous emission of Sm{sup 3+} and Eu{sup 3+}. Under Sm{sup 3+} excitation at 344 and 360 nm, the Eu{sup 3+} emission is sensitized and enhanced by Sm{sup 3+} through a non-radiative energy transfer process. The non-radiative nature was inferred from the shortening of the Sm{sup 3+} lifetime observed in the Sm{sup 3+}/Eu{sup 3+} co-doped sample. An analysis of the Sm{sup 3+} emission decay time profiles using the Inokuti–Hirayama model suggests that an electric quadrupole–quadrupole interaction into Sm–Eu clusters might dominate the energy transfer process, with an efficiency of 0.17. - Highlights: • Zinc phosphate glasses are optically activated with Sm{sup 3+}/Eu{sup 3+} (ZPOSmEu). • Non-radiative energy transfer Sm{sup 3+}→Eu{sup 3+} takes place in ZPOSmEu. • ZPOSmEu overall emission can be modulated with the excitation wavelength. • ZPOSmEu might be useful as orange/reddish-orange phosphor for UV-white LEDs.

Safety report for the Independent CO{sub 2} loop for cooling the samples irradiated in the RA reactor vertical experimental channels, Vol. VI; Album VI: Izvestaj o sigurnosti za nezavisno kolo CO{sub 2} za hladjenje uzoraka ozracivanih u VEK reaktora RA

Energy Technology Data Exchange (ETDEWEB)

NONE

1964-07-01

First part of the safety report for the Independent CO{sub 2} loop for cooling the samples irradiated in the RA reactor vertical experimental channels contains descriptions of the independent CO{sub 2} loop, system for regulation, measurement and control od the loop parameters, description of the dosimetry system, and the plan for testing the experimental device before start-up. Second part of this analysis describes the influence of of the experimental device on the reactor operation under steady state conditions as follows: influence of the head of the independent coolant loop on the reactivity of the reactor core and influence on the reactor temperature coefficient. Third part of the report includes the analysis of possible accidents during operation of the independent CO{sub 2} coolant loop in the reactor. Izvestaj o sigurnosti za nezavisno kolo CO{sub 2} za hladjenje uzoraka ozracivanih u VEK reaktora RA sadrzi u prvom delu: opis nezavisnog kola CO{sub 2}, sistema za regulaciju, merenje i kontrolu parametara nezavisnog kola, sistema dozimetrijske kontrole i plan ispitivanja eksperimentalnih uredjaja pre pustanja u rad. Drugi deo ove analize obuhvata uticaj eksperimentalnog uredjaja na reaktor u normalnom rezimu rada i to: uticaj glave petlje nezavisnog kola CO{sub 2} za hladjenje uzoraka na reaktivnost reaktora i uticaj uredjaja na temperaturni koeficijent reaktora. Treci deo sadrzi analizu mogucih akcidenata u toku rada nezavisnog kola CO{sub 2} u reaktoru.

Probing metastable Sm²⁺ and optically stimulated tunnelling emission in YPO₄: Ce, Sm

DEFF Research Database (Denmark)

Prasad, Amit Kumar; Kook, Myung Ho; Jain, Mayank

2017-01-01

When the model dosimetry system YPO4: Ce3+, Sm3+ is exposed to X-rays, the charge state of the dopants changes, becoming Ce4+ and Sm2+ via hole and electron trapping, respectively which are metastable; the original charge states can be achieved through electron transfer back from Sm2+ to Ce4+ via......) and its temperature dependence to provide insights into thermal quenching, and c) the kinetics of localised recombination from Sm2+ to Ce4+ on nanoseconds to seconds time scales using sub-band-edge excitation....

Luminescence properties of the Sm-doped borate glasses

International Nuclear Information System (INIS)

Kindrat, I.I.; Padlyak, B.V.; Drzewiecki, A.

2015-01-01

The optical absorption and photoluminescence (emission and excitation) spectra as well as decay kinetics of a series of the Sm-doped glasses with Li 2 B 4 O 7 , LiKB 4 O 7 , CaB 4 O 7 , and LiCaBO 3 compositions were investigated and analysed. The Li 2 B 4 O 7 :Sm, LiKB 4 O 7 :Sm, CaB 4 O 7 :Sm, and LiCaBO 3 :Sm glasses of high optical quality have been obtained from the corresponding polycrystalline compounds in the air atmosphere, using a standard glass technology. On the basis of electron paramagnetic resonance (EPR) and optical spectra analysis it was shown that the samarium impurity is incorporated into the glass network as Sm 3+ (4f 5 , 6 H 5/2 ) ions, exclusively. All observed 4f – 4f transitions of the Sm 3+ centres in the optical absorption and luminescence spectra of the investigated glasses are identified. Most intense emission band of the Sm 3+ ions peaked about 598 nm ( 4 G 5/2 → 6 H 7/2 transition) is characterised by a single exponential decay with typical lifetime values, which depend on the basic glass composition as well as concentration and local structure of the Sm 3+ luminescence centres. The quantum efficiency has been evaluated for observed transitions of the Sm 3+ centres using obtained experimental lifetimes and radiative lifetimes calculated by Judd–Ofelt theory. The calculated high quantum efficiencies and measured quantum yields of luminescence show that the investigated borate glasses are perspective luminescence materials. Energy transfer from the Ce 3+ non-controlled impurity and intrinsic luminescence centres to the Sm 3+ centres has been observed. Peculiarities of the Sm 3+ local structure in the network of investigated glasses have been discussed based on the obtained spectroscopic results and structural data. - Highlights: • The Sm-doped Li 2 B 4 O 7 , LiKB 4 O 7 , CaB 4 O 7 , and LiCaBO 3 glasses of high quality were obtained. • EPR, optical absorption and luminescence spectra of Sm 3+ ions in obtained glasses were

Acute toxicity of injection of 153Sm-EDTMP

International Nuclear Information System (INIS)

Chen Baiwei; Chai Xuehong

2004-01-01

Sm-153 has several distinct advantages as a radiopharmaceutical for the treat of patients with bone to skeletal metastasis. Sm-153 shows high skeletal uptake and rapid blood and nonosseous tissue clearance. Several paper have considered the toxicity of 153Sm-EDTMP. We report the acute toxicity in mice and rats after injection of 153Sm-EDTMP or unlabeled EDTMP. The EDTMP was injected to mice by 9.76, 7.8, 6.25, 5, 4 mg/Kg. The logarithmic dose of EDTMP were given to mice to determine LD50. The LD50 of EDTMP in mice is 7.1 mg/Kg. The decay of 153Sm-EDTMP for 4 months were injected to mice at dose of 225 mg/Kg. 153Sm-EDTMP were given at 4 difference dosage to rats by 74 MBq/Kg, 370 MBq/Kg, 1110 MBq/Kg, 1850 MBq/Kg. The LD50 of 153Sm-EDTMP in rats is more than 370 MBq/Kg. Although the cold EDTMP LD50 was low, chelated with Sm can decrease it's toxicity. The decay 153Sm-EDTMP can be safe at dose of 225 mg/Kg. The clinical dose will be used at 37 MBq/Kg. So there is no need to consider to acute toxicity in clinical used 153Sm-EDTMP in designated regimen because the safe range is wide enough to cover clinical used. (authors)

Cross-species prophylactic efficacy of Sm-p80-based vaccine and intracellular localization of Sm-p80/Sm-p80 ortholog proteins during development in Schistosoma mansoni, Schistosoma japonicum, and Schistosoma haematobium.

Science.gov (United States)

Molehin, Adebayo J; Sennoune, Souad R; Zhang, Weidong; Rojo, Juan U; Siddiqui, Arif J; Herrera, Karlie A; Johnson, Laura; Sudduth, Justin; May, Jordan; Siddiqui, Afzal A

2017-11-01

Schistosomiasis remains a major global health problem. Despite large-scale schistosomiasis control efforts, clear limitations such as possible emergence of drug resistance and reinfection rates highlight the need for an effective schistosomiasis vaccine. Schistosoma mansoni large subunit of calpain (Sm-p80)-based vaccine formulations have shown remarkable efficacy in protecting against S. mansoni challenge infections in mice and baboons. In this study, we evaluated the cross-species protective efficacy of Sm-p80 vaccine against S. japonicum and S. haematobium challenge infections in rodent models. We also elucidated the expression of Sm-p80 and Sm-p80 ortholog proteins in different developmental stages of S. mansoni, S. haematobium, and S. japonicum. Immunization with Sm-p80 vaccine reduced worm burden by 46.75% against S. japonicum challenge infection in mice. DNA prime/protein boost (1 + 1 dose administered on a single day) resulted in 26.95% reduction in worm burden in S. haematobium-hamster infection/challenge model. A balanced Th1 (IFN-γ, TNF-α, IL-2, and IL-12) and Th2 (IL-4, IgG1) type of responses were observed following vaccination in both S. japonicum and S. haematobium challenge trials and these are associated with the prophylactic efficacy of Sm-p80 vaccine. Immunohistochemistry demonstrated that Sm-p80/Sm-p80 ortholog proteins are expressed in different life cycle stages of the three major human species of schistosomes studied. The data presented in this study reinforce the potential of Sm-p80-based vaccine for both hepatic/intestinal and urogenital schistosomiasis occurring in different geographical areas of the world. Differential expression of Sm-p80/Sm-p80 protein orthologs in different life cycle makes this vaccine potentially useful in targeting different levels of infection, disease, and transmission.

Computerized reactor power regulation with logarithmic controller

International Nuclear Information System (INIS)

Gossanyi, A.; Vegh, E.

1982-11-01

A computerized reactor control system has been operating at a 5 MW WWR-SM research reactor in the Central Research Institute for Physics, Budapest, for some years. This paper describes the power controller used in the SPC operating mode of the system, which operates in a 5-decade wide power range with +-0.5% accuracy. The structure of the controller easily limits the minimal reactor period and produces a reactor transient with constant period if the power demand changes. (author)

Maximum neutron flux at thermal nuclear reactors; Maksimum neutronskog fluksa kod termalnih reaktora

Energy Technology Data Exchange (ETDEWEB)

Strugar, P [Institute of Nuclear Sciences Vinca, Beograd (Serbia and Montenegro)

1968-10-15

Since actual research reactors are technically complicated and expensive facilities it is important to achieve savings by appropriate reactor lattice configurations. There is a number of papers, and practical examples of reactors with central reflector, dealing with spatial distribution of fuel elements which would result in higher neutron flux. Common disadvantage of all the solutions is that the choice of best solution is done starting from the anticipated spatial distributions of fuel elements. The weakness of these approaches is lack of defined optimization criteria. Direct approach is defined as follows: determine the spatial distribution of fuel concentration starting from the condition of maximum neutron flux by fulfilling the thermal constraints. Thus the problem of determining the maximum neutron flux is solving a variational problem which is beyond the possibilities of classical variational calculation. This variational problem has been successfully solved by applying the maximum principle of Pontrjagin. Optimum distribution of fuel concentration was obtained in explicit analytical form. Thus, spatial distribution of the neutron flux and critical dimensions of quite complex reactor system are calculated in a relatively simple way. In addition to the fact that the results are innovative this approach is interesting because of the optimization procedure itself. [Serbo-Croat] Savremeni reaktori za fizicka i tehnoloska istrazivanja predstavljaju tehnicki komplikovanu i skupu masinu. Iz tog razloga su opravdana nastojanja da se podesnim rasporedom goriva u jezgru reaktora dodje do sto ekonomicnijeg rjesenja. U literaturi postoji vise radova, cak i konkretnih realizacija u vidu reaktora sa reflektorom u centru, koji se bave odredjivanjem takve prostorne zavisnosti koncentracije goriva koja pod odredjenim uslovima daje najveci neutronski fluks. Zajednicki nedostatak svih pomenutih rjesenja je u tome sto se polazi od pretpostavljenih prostornih distribucija

Study of fuel element characteristic of SM and SMP (SM-PRIMA) fuel assemblies

International Nuclear Information System (INIS)

Klinov, A.V.; Kuprienko, V.A.; Lebedev, V.A.; Makhin, V.M.; Tuchnin, L.M.; Tsykanov, V.A.

1999-01-01

The paper discusses the techniques and results of reactor tests and post-reactor investigations of the SM reactor fuel elements and fuel elements developed in the process of designing the specialized PRIMA test reactor with the SM reactor fuel elements used as a prototype and which are referred to as the SMP fuel elements. The behavior of fuel elements under normal operating conditions and under deviation from normal operating conditions was studied to verify the calculation techniques, to check the calculation results during preparation of the SM reactor safety substantiation report and to estimate the possibility of using such fuel elements in other projects. During tests of fuel rods under deviation from normal operating conditions their advantages were shown over fuel elements, the components of which were produced using the Al-based alloys. (author)

Opinion about difficulties of RA reactor operation under conditions of high activity of the heavy water system - Annex 2; Prilog 2 - Misljenje o teskocama eksploatacije reaktora RA u uslovima visoke aktivnosti teskovodnog sistema

Energy Technology Data Exchange (ETDEWEB)

Nikolic, M [Institute of Nuclear Sciences Boris Kidric, Vinca, Beograd (Serbia and Montenegro)

1963-12-15

It was concluded that reactor the reactor operation is very dangerous for the reactor installation as well as safety of the staff under conditions of heavy water increased activity. Two fundamental arguments in favour of this conclusion are: insufficient possibility of reactor components inspection during maintenance and operation in the future period; difficulties in prevention of accidents that could occur is equally dangerous for the reactor facility and the environment. Cleaning and decontamination of the complete heavy water system is needed before the reactor operation starts in order to avoid possible failures or accidental events. [Serbo-Croat] Zakljuceno je da je eksploatacija reakora u uslovima postojece aktivnosti teskovodnog sistema veoma opasna po sam reaktor i po personal. Dva osnovna razloga u prilog ovog zakljucka su: nedovoljna mogucnost kontrole ispravnosti svih elemenata reaktora u toku remonta i ekspolatacije u predstojecem periodu; teskoca borbe sa udesima, koji bi se eventualno dogodili podjednako je opasna po instalaciju i okolinu. Pre no sto se nastavi sa daljom ekspolatacijom reaktora potrebno ciscenje, dekontaminacija sistema teske vode kako bi se izbegla moguca ostecenja ili akcidentalne situacije.

Luminescence properties of the Sm-doped borate glasses

Energy Technology Data Exchange (ETDEWEB)

Kindrat, I.I. [University of Zielona Góra, Institute of Physics, Division of Spectroscopy of Functional Materials, 4a Szafrana Street, 65-516 Zielona Góra (Poland); Padlyak, B.V., E-mail: B.Padlyak@if.uz.zgora.pl [University of Zielona Góra, Institute of Physics, Division of Spectroscopy of Functional Materials, 4a Szafrana Street, 65-516 Zielona Góra (Poland); Vlokh Institute of Physical Optics, 23 Dragomanov Street, 79-005 Lviv (Ukraine); Drzewiecki, A. [University of Zielona Góra, Institute of Physics, Division of Spectroscopy of Functional Materials, 4a Szafrana Street, 65-516 Zielona Góra (Poland)

2015-10-15

The optical absorption and photoluminescence (emission and excitation) spectra as well as decay kinetics of a series of the Sm-doped glasses with Li{sub 2}B{sub 4}O{sub 7}, LiKB{sub 4}O{sub 7}, CaB{sub 4}O{sub 7}, and LiCaBO{sub 3} compositions were investigated and analysed. The Li{sub 2}B{sub 4}O{sub 7}:Sm, LiKB{sub 4}O{sub 7}:Sm, CaB{sub 4}O{sub 7}:Sm, and LiCaBO{sub 3}:Sm glasses of high optical quality have been obtained from the corresponding polycrystalline compounds in the air atmosphere, using a standard glass technology. On the basis of electron paramagnetic resonance (EPR) and optical spectra analysis it was shown that the samarium impurity is incorporated into the glass network as Sm{sup 3+} (4f{sup 5}, {sup 6}H{sub 5/2}) ions, exclusively. All observed 4f – 4f transitions of the Sm{sup 3+} centres in the optical absorption and luminescence spectra of the investigated glasses are identified. Most intense emission band of the Sm{sup 3+} ions peaked about 598 nm ({sup 4}G{sub 5/2} → {sup 6}H{sub 7/2} transition) is characterised by a single exponential decay with typical lifetime values, which depend on the basic glass composition as well as concentration and local structure of the Sm{sup 3+} luminescence centres. The quantum efficiency has been evaluated for observed transitions of the Sm{sup 3+} centres using obtained experimental lifetimes and radiative lifetimes calculated by Judd–Ofelt theory. The calculated high quantum efficiencies and measured quantum yields of luminescence show that the investigated borate glasses are perspective luminescence materials. Energy transfer from the Ce{sup 3+} non-controlled impurity and intrinsic luminescence centres to the Sm{sup 3+} centres has been observed. Peculiarities of the Sm{sup 3+} local structure in the network of investigated glasses have been discussed based on the obtained spectroscopic results and structural data. - Highlights: • The Sm-doped Li{sub 2}B{sub 4}O{sub 7}, LiKB{sub 4}O{sub 7}, Ca

Kampen om det sibiriske smør

DEFF Research Database (Denmark)

Larsen, Inge Marie

2001-01-01

Afhandlingen følger opbygningen af og udviklingen i den vestsibiriske smørsektor og den internationale handel med sibirisk smør. Hvordan gik det til, at Rusland blev verdens næststørste smøreksportør? Indfaldsvinkelen er lokal sibirisk, national russisk og global, idet danske og engelske firmaers...

Independent CO{sub 2} loop for cooling the samples irradiated in vertical experimental channels of the RA reactor, Vol. I; Nezavisno kolo CO{sub 2} za hladjenje uzoraka ozracivanih u vertikalnim eksperimentalnim kanalima reaktora RA, Album I

Energy Technology Data Exchange (ETDEWEB)

Pavicevic, M; Pavlovic, A [Institute of Nuclear Sciences Boris Kidric, Vinca, Beograd (Serbia and Montenegro)

1963-06-15

Project 'independent CO{sub 2} loop for cooling the samples irradiated in the vertical experimental channels of the RA reactor' is presented in two volumes: volume I - head of the low temperature coolant loop for reactor RA, and volume II - Outer low-temperature reactor coolant loop. Volume I includes: the design specifications for the head of the low-temperature coolant loop, technical description, thermal calculation, calculations of mechanical loads, antireactivity and activation of the components of the coolant loop head, engineering schemes and drawings, cost estimation data. [Serbo-Croat] Projekat 'Nezavisno kolo CO{sub 2} za hladjenje uzoraka ozracivanih u vertikalnim eksperimentalnim kanalima reaktora RA', sastoji se od dva albuma: album I - Glava niskotemperaturno rashladne petlje za reaktor RA, album II - Spoljno kolo niskotemperaturne rashladne petlje za reaktora. Album I sadrzi projektni zadatak glave niskotemperaturne petlje, tehnicki opis, termicki proracun, proracun mehanickih naprezanja, antireaktivnosti i aktivacije kontrukcionih elemenata glave petlje, konstrukcione seme i crteze glave petlje, predracun.

Curie temperature rising by fluorination for Sm2Fe17

Directory of Open Access Journals (Sweden)

Matahiro Komuro

2013-02-01

Full Text Available Fluorine atoms can be introduced to Sm2Fe17 using XeF2 below 423 K. The resulting fluorinated Sm2Fe17 powders have ferromagnetic phases containing Sm2Fe17FY1(0Sm2Fe17FY2 (1Sm2Fe17, and α-Fe. The unit cell for Sm2Fe17 is elongated by the fluorination. The largest unit cell volume among the rhombohedral Sm2Fe17 compounds is 83.8 nm3, which is 5.8% larger than Sm2Fe17. The rhombohedral Sm2Fe17 with the largest unit cell volume is dissociated above 873 K, and fluorination increases Curie temperature from 403 K for Sm2Fe17 to 675 K. This increase can be explained by the magneto-volume effect.

DNA Vaccine Encoding the Chimeric Form of Schistosoma mansoni Sm-TSP2 and Sm29 Confers Partial Protection against Challenge Infection.

Directory of Open Access Journals (Sweden)

Natan Raimundo Gonçalves de Assis

Full Text Available Schistosomiasis is an important parasitic disease worldwide that affects more than 207 million people in 76 countries and causes approximately 250,000 deaths per year. The best long-term strategy to control schistosomiasis is through immunization combined with drug treatment. Due to the ability of DNA vaccines to generate humoral and cellular immune responses, such vaccines are considered a promising approach against schistosomiasis. Sm29 and tetraspanin-2 (Sm-TSP2 are two proteins that are located in the S. mansoni tegument of adult worms and schistosomula and induce high levels of protection through recombinant protein immunization. In this study, we transfected BHK-21 cells with plasmids encoding Sm29, Sm-TSP2 or a chimera containing both genes. Using RT-PCR analysis and western blot, we confirmed that the DNA vaccine constructs were transcribed and translated, respectively, in BHK-21 cells. After immunization of mice, we evaluated the reduction in worm burden. We observed worm burden reductions of 17-22%, 22%, 31-32% and 24-32% in animals immunized with the pUMVC3/Sm29, pUMVC3/SmTSP-2, pUMVC3/Chimera and pUMVC3/Sm29 + pUMVC3/SmTSP-2 plasmids, respectively. We evaluated the humoral response elicited by DNA vaccines, and animals immunized with pUMVC3/Sm29 and pUMVC3/Sm29 + pUMVC3/SmTSP-2 showed higher titers of anti-Sm29 antibodies. The cytokine profile produced by the spleen cells of immunized mice was then evaluated. We observed higher production of Th1 cytokines, such as TNF-α and IFN-γ, in vaccinated mice and no significant production of IL-4 and IL-5. The DNA vaccines tested in this study showed the ability to generate a protective immune response against schistosomiasis, probably through the production of Th1 cytokines. However, future strategies aiming to optimize the protective response induced by a chimeric DNA construct need to be developed.

DNA Vaccine Encoding the Chimeric Form of Schistosoma mansoni Sm-TSP2 and Sm29 Confers Partial Protection against Challenge Infection

Science.gov (United States)

Gonçalves de Assis, Natan Raimundo; Batistoni de Morais, Suellen; Figueiredo, Bárbara Castro Pimentel; Ricci, Natasha Delaqua; de Almeida, Leonardo Augusto; da Silva Pinheiro, Carina; Martins, Vicente de Paulo; Oliveira, Sergio Costa

2015-01-01

Schistosomiasis is an important parasitic disease worldwide that affects more than 207 million people in 76 countries and causes approximately 250,000 deaths per year. The best long-term strategy to control schistosomiasis is through immunization combined with drug treatment. Due to the ability of DNA vaccines to generate humoral and cellular immune responses, such vaccines are considered a promising approach against schistosomiasis. Sm29 and tetraspanin-2 (Sm-TSP2) are two proteins that are located in the S. mansoni tegument of adult worms and schistosomula and induce high levels of protection through recombinant protein immunization. In this study, we transfected BHK-21 cells with plasmids encoding Sm29, Sm-TSP2 or a chimera containing both genes. Using RT-PCR analysis and western blot, we confirmed that the DNA vaccine constructs were transcribed and translated, respectively, in BHK-21 cells. After immunization of mice, we evaluated the reduction in worm burden. We observed worm burden reductions of 17-22%, 22%, 31-32% and 24-32% in animals immunized with the pUMVC3/Sm29, pUMVC3/SmTSP-2, pUMVC3/Chimera and pUMVC3/Sm29 + pUMVC3/SmTSP-2 plasmids, respectively. We evaluated the humoral response elicited by DNA vaccines, and animals immunized with pUMVC3/Sm29 and pUMVC3/Sm29 + pUMVC3/SmTSP-2 showed higher titers of anti-Sm29 antibodies. The cytokine profile produced by the spleen cells of immunized mice was then evaluated. We observed higher production of Th1 cytokines, such as TNF-α and IFN-γ, in vaccinated mice and no significant production of IL-4 and IL-5. The DNA vaccines tested in this study showed the ability to generate a protective immune response against schistosomiasis, probably through the production of Th1 cytokines. However, future strategies aiming to optimize the protective response induced by a chimeric DNA construct need to be developed. PMID:25942636

Wpływ czasu napowietrzania na pracę reaktora SBR i SBBR

Directory of Open Access Journals (Sweden)

Małgorzata Makowska

2016-06-01

Full Text Available W pracy przedstawiono efekty oczyszczania małych ilości ścieków w bioreaktorach porcjowych. Przebadano dwa równolegle pracujące reaktory, z czego jeden był klasycznym systemem SBR, a drugi to reaktor SBBR ze złożem ruchomym. Obydwa ciągi technologiczne oczyszczały taką samą ilość ścieków bytowych wstępnie podczyszczonych w piaskowniku. Trzy kolejne serie badań różniły się długością napowietrzania. Porównano pracę reaktorów w kolejnych seriach oraz analizowano wyniki uzyskane w obu systemach. Największą skuteczność usuwania związków węgla organicznego (jako ChZT i azotu (jako N-NH4 uzyskano w reaktorze SBBR w trzeciej serii badań (średnio odpowiednio 90 i 62%. Reaktor SBBR pracował bardziej stabilnie oraz usuwał na drodze biologicznej fosfor z największą średnią skutecznością 83% w serii trzeciej. Ścieki oczyszczone w tym reaktorze charakteryzowały się mniejszym stężeniem zawiesiny, co świadczy o skuteczniejszej pracy reaktora z wypełnieniem w fazie sedymentacji.

Magnetic properties of Sm-based filled skutterudite phosphides

Energy Technology Data Exchange (ETDEWEB)

Giri, R.; Sekine, C.; Shimaya, Y.; Shirotani, I.; Matsuhira, K.; Doi, Y.; Hinatsu, Y.; Yokoyama, M.; Amitsuka, H

2003-05-01

Filled skutterudites SmFe{sub 4}P{sub 12} and SmOs{sub 4}P{sub 12} have been prepared at high temperature and high pressure. The temperature dependence of electrical resistivity in both compounds shows metallic behavior. The magnetic susceptibility and specific heat measurements indicate that SmFe{sub 4}P{sub 12} shows a ferromagnetic ordering at 1.5 K, whereas SmOs{sub 4}P{sub 12} is an antiferromagnet with a T{sub N} of 4.6 K.

Arterial injury promotes medial chondrogenesis in Sm22 knockout mice.

Science.gov (United States)

Shen, Jianbin; Yang, Maozhou; Jiang, Hong; Ju, Donghong; Zheng, Jian-Pu; Xu, Zhonghui; Liao, Tang-Dong; Li, Li

2011-04-01

Expression of SM22 (also known as SM22alpha and transgelin), a vascular smooth muscle cells (VSMCs) marker, is down-regulated in arterial diseases involving medial osteochondrogenesis. We investigated the effect of SM22 deficiency in a mouse artery injury model to determine the role of SM22 in arterial chondrogenesis. Sm22 knockout (Sm22(-/-)) mice developed prominent medial chondrogenesis 2 weeks after carotid denudation as evidenced by the enhanced expression of chondrogenic markers including type II collagen, aggrecan, osteopontin, bone morphogenetic protein 2, and SRY-box containing gene 9 (SOX9). This was concomitant with suppression of VSMC key transcription factor myocardin and of VSMC markers such as SM α-actin and myosin heavy chain. The conversion tendency from myogenesis to chondrogenesis was also observed in primary Sm22(-/-) VSMCs and in a VSMC line after Sm22 knockdown: SM22 deficiency altered VSMC morphology with compromised stress fibre formation and increased actin dynamics. Meanwhile, the expression level of Sox9 mRNA was up-regulated while the mRNA levels of myocardin and VSMC markers were down-regulated, indicating a pro-chondrogenic transcriptional switch in SM22-deficient VSMCs. Furthermore, the increased expression of SOX9 was mediated by enhanced reactive oxygen species production and nuclear factor-κB pathway activation. These findings suggest that disruption of SM22 alters the actin cytoskeleton and promotes chondrogenic conversion of VSMCs.

Assessment of microseeds biodegradability of Sm and Sm:Ba splenic implants in rabbits

International Nuclear Information System (INIS)

Siqueira, Savio Lana; Barroso, Thiago Vinicius Villar; Campos, Tarcisio P.R.

2009-01-01

The radioactive interstitial implants have applications in controlling neoplasm in several regions of the human body. Currently the permanent brachytherapy seeds implanted in the spleen and other organs are made of I-125 seeds. After the total emission of radiation, the metal encapsulated seed remains inert in the implanted area. Seeds of bioactive ceramics have been prepared with Sm-152 incorporation to be activated in Sm-153. This study aimed to develop surgical technique for implanting biodegradable micro-seeds in the spleen of the rabbit. Three micro-seeds were introduced by hypodermic needle in the spleen in eight rabbits by median laparotomy. Subsequently, there were clinical and functional reactions of the animal to the implanted foreign body. The other objective was to perform the animal monitoring by radiography, produced in time sequence, and pathological studies of a fragment of the spleens of rabbits. The results show the effectiveness of surgery, the identification of the implanted material by radiography in vivo, and the biocompatibility of micro-seeds most of Sm and Sm:Ba. These seeds of reduced volume, 0.3x 1.6 mm, could be monitored for radiological studies in 2 periods: early and later implant. On the later studies, radiography was taken at 60d post-implant. Biopsies were taken and radiographs of the samples were also performed for evidencing the degradation state of the seeds. The results of the two groups of four rabbits are presented. They show partial degradation of the seed verified by radiographic contrast which is related to the atomic number of the elements and mass density in the seed. The biopsy showed that the ceramic is clearly absorbed by the spleen tissue and form tissue-implant interface. The histological slides showed an inflammatory reaction with presence of fibrosis of the giant cell foreign body. In conclusion, the radiograph shows a suitable noninvasive technique for monitoring the degradation of micro-seed ceramics in vivo

Assessment of microseeds biodegradability of Sm and Sm:Ba splenic implants in rabbits

Energy Technology Data Exchange (ETDEWEB)

Siqueira, Savio Lana; Barroso, Thiago Vinicius Villar [Faculdade de Ciencias Medicas de Minas Gerais, Belo Horizonte, MG (Brazil). Dept. de Anatomia; Campos, Tarcisio P.R., E-mail: campos@nuclear.ufmg.b [Universidade Federal de Minas Gerais (UFMG), Belo Horizonte, MG (Brazil). Programa de Ciencias e Tecnicas Nucleares

2009-07-01

The radioactive interstitial implants have applications in controlling neoplasm in several regions of the human body. Currently the permanent brachytherapy seeds implanted in the spleen and other organs are made of I-125 seeds. After the total emission of radiation, the metal encapsulated seed remains inert in the implanted area. Seeds of bioactive ceramics have been prepared with Sm-152 incorporation to be activated in Sm-153. This study aimed to develop surgical technique for implanting biodegradable micro-seeds in the spleen of the rabbit. Three micro-seeds were introduced by hypodermic needle in the spleen in eight rabbits by median laparotomy. Subsequently, there were clinical and functional reactions of the animal to the implanted foreign body. The other objective was to perform the animal monitoring by radiography, produced in time sequence, and pathological studies of a fragment of the spleens of rabbits. The results show the effectiveness of surgery, the identification of the implanted material by radiography in vivo, and the biocompatibility of micro-seeds most of Sm and Sm:Ba. These seeds of reduced volume, 0.3x 1.6 mm, could be monitored for radiological studies in 2 periods: early and later implant. On the later studies, radiography was taken at 60d post-implant. Biopsies were taken and radiographs of the samples were also performed for evidencing the degradation state of the seeds. The results of the two groups of four rabbits are presented. They show partial degradation of the seed verified by radiographic contrast which is related to the atomic number of the elements and mass density in the seed. The biopsy showed that the ceramic is clearly absorbed by the spleen tissue and form tissue-implant interface. The histological slides showed an inflammatory reaction with presence of fibrosis of the giant cell foreign body. In conclusion, the radiograph shows a suitable noninvasive technique for monitoring the degradation of micro-seed ceramics in vivo

Full instantaneous traversal rupture of the primary loop pipeline

International Nuclear Information System (INIS)

Baytelesov, S.A.; Kungurov, F.R.

2010-01-01

Accident, reflecting full immediate cross rupture of primary loop pipe of WWR-SM research reactor of INP AS RUz is observed in this paper. Calculations for accident situation and analysis for different reactor cores, formed from fully IRT-3M type high enriched fuel (36% enrichment on 235 U), first mixed core, compiled from 16 IRT-3M fuel assemblies and 4 IRT-4M type fuel assemblies with low enriched fuel (19,7% enrichment on 235 U) and the core fully formed from low enriched fuel are carried out

Neutron diffraction radiation of solid solution of carbon and hydrogen in the α-titanium in the homogeneity domain

International Nuclear Information System (INIS)

Mirzaev, B.B.; Khidirov, I.; Mukhtarova, N.N.

2005-01-01

In the work by the neutron-graph the homogeneity domain of the introduction solid solution TiC x H y is determined. The sample neutron grams have been taken on the neutron diffractometer (λ=.1085 nm) installed at the thermal column of the WWR-SM reactor (INF AN RUz). For the phase analysis and estimation of solid solutions homogeneity the X-ray graph was used. X-ray grams were taken on the X-ray diffractometer DRON-3M with use of CuK α radiation (λ=0.015418 nm)

Some aspects related to radioprotection during decommissioning of the WWR-S research reactor

International Nuclear Information System (INIS)

Pantazi, Doina; Stan, Camelia

2007-01-01

Radiological safety management ensures protection of personnel, public and environment. During decommissioning of a WWR-S type research reactor, besides other specific industrial problems, radiation and/or contamination sources will be produced and their effects have to be kept under control. In any decommissioning operation that implies working in a radioactive environment, the main concern being the minimization of the total dose received by the workers. To minimize the possible dose that an individual could receive, prior entering the working area, a definite set of stages of a radiation protection plan, developed according to ALARA principle, should be implemented. Of major interest is estimation the effective dose which operators will receive during a year, considering all operations in that he is involved and all the different possible paths of irradiation or contamination (inhalation, skin penetration, injury, etc.). The estimation of doses received by operating personnel will take into consideration the following steps: - the determination of jobs and events which could involve a significant radiation dose exposure; - whole body and extremities exposure doses should be assessed taking into consideration that the likelihood of contact with radiation and/or contamination sources is higher for hands and legs; - all possible paths of exposure will be identified (external irradiation is the most expected while the internal exposure due to intake could happen following an accidental inhalation of radionuclides or an injury in contaminated medium); - technological controls and administrative measures for exposure minimization will be rigorously implemented; - estimated doses will be compared with maximum permissible levels. The paper describes some general methodologies for computing the total effective doses received by workers involved in decommissioning operations, as well as their application for few special situations, that could contribute significantly to

Degeneracy lifting due to thermal fluctuations around the frustration point between anticlinic antiferroelectric SmC(A)* and synclinic ferroelectric SmC*.

Science.gov (United States)

Sandhya, K L; Chandani, A D L; Fukuda, Atsuo; Vij, Jagdish K; Emelyanenko, A V; Ishikawa, Ken

2013-01-01

In the binary mixture phase diagram of MC881 and MC452, the borderline between anticlinic antiferroelectric SmC(A)(*) and synclinic ferroelectric SmC(*) becomes apparently parallel to the temperature ordinate axis at the critical concentration r(c). The free energy difference between SmC(A)(*) and SmC^{*} is extremely small in a wide temperature range near r(c). In such circumstances, by observing Bragg reflection spectra due to the director helical structure and electric-field-induced birefringence, we have observed the continuous change from SmC(A)(*) to SmC(*) for r/~r(c). These intriguing phenomena have been explained, successfully at least in the high-temperature region, by a thermal equilibrium between the synclinic and anticlinic orderings and the resulting Boltzmann distribution for the ratio between them; the thermal equilibrium is considered to be attained in a nonuniform defect-assisted way through solitary waves moving around dynamically. We have also discussed qualitatively an important role played by the effective long-range interlayer interactions in the low-temperature region.

Synthesis and bio-evaluation of nano-hydroxyapatite trapped by 153Sm

International Nuclear Information System (INIS)

Bing Wenzeng; Luo Shunzhong; Wen Guanghua; Jiang Shubin; Xiong Xiaoling; Liu Guoping

2006-03-01

After nanoHA was synthesized, 153 Sm-EDTMP-nanoHA and 153 Sm-citrate-nanoHA were prepared and proved stable in vitro. ECT images of New Zealand rabbits injected with 153 Sm-EDTMP-nanoHA had better contrast, skeletal figure visible, liver and spleen clear. The images of 153 Sm-citrate-nanoHA showed a similar results but kidney invisible, which meant 153 Sm-citrate-nanoHA showed a similar results but kidney invisible, which meant 153 Sm-citrate-nanoHA was mainly excreted through liver and gall. 153 Sm-EDTMP-nanoHA's half effective inhibition concentrations to SMMC-7721 and MCF-7 cells were 1.98 g/L and 0.075 g/L respectively and 153 Sm-citrate-nanoHA's were 1.89 g/L and 0.094 g/L proportionally. 153 Sm-EDTMP-nanoHA and 153 Sm-citrate-nanoHA were worthy of a further research because their half effective inhibition concentrations were much lower than ones of the single nanoHA. (authors)

checkCIF/PLATON report Datablock: Sm

Indian Academy of Sciences (India)

Moiety formula C59 H45 N2 O6 Sm. Sm (C14 H12 N2) ... 4.0 Ratio. PLAT234_ALERT_4_C Large Hirshfeld Difference O4 -- C24 .. 0.16 Ang. ... outliers and unusual parameters, but every test has its limitations and alerts that are not important.

Nanocrystallization in Cu-Zr-Al-Sm Bulk Metallic Glasses

Science.gov (United States)

Sikan, Fatih; Yasar, Bengisu; Kalay, Ilkay

2018-04-01

The effect of rare-earth element (Sm) microalloying on the thermal stability and crystallization kinetics of melt-spun ribbons and suction-cast rods of Zr48Cu38.4Al9.6Sm4 alloy were investigated using differential scanning calorimetry (DSC), X-ray diffraction (XRD), transmission electron microscopy (TEM), and atom probe tomography (APT). The XRD results of constant heating rate annealing indicated that amorphous Zr48Cu38.4Al9.6Sm4 melt-spun ribbons devitrifies into Cu2Sm at 673 K (400 °C). The sequence continues with the precipitation of Cu10Zr7 and then these two phases coexist. XRD and TEM studies on 1 mm diameter as suction-cast rods indicated the precipitation of 30-nm-mean size Cu2Sm crystals during solidification. TEM investigation of the isothermal crystallization sequence of melt-spun ribbons and 1-mm-diameter suction-cast rods revealed the precipitation of Cu2Sm nanocrystals at the onset of crystallization and the restriction of the growth of these nanocrystals up to 10 nm diameter with further annealing. APT analysis of 1-mm-diameter suction-cast rods showed that the limited growth of Cu2Sm nanocrystals is due to sluggish diffusion of Sm and Al-Zr pile up at the interface.

Gamma ray irradiation characteristics of SM fibers

International Nuclear Information System (INIS)

Ito, Ryuichi; Okano, Hiroaki; Hashiba, Keichi; Nakai, Hisanori

1987-01-01

1.3 μm range single mode (SM) optical fibers have been used for wide application of mainly long distance communication. At present, in order to realize the larger capacity and longer distance between relay points, the development of 1.5 μm range SM fibers of low dispersion and small loss has been actively promoted. As for the radiation withstanding property of SM fibers, report is scarce. The authors reported on the gamma ray irradiation characteristics of 1.3 μm range SM fibers, but since 1.5 μm range SM fibers are designed with the different structure from that of 1.3 μm fibers, it is necessary to evaluate from new viewpoint. In this report, mainly on the structure having triangular distribution, the effect that the manufacturing condition and the structural defects of glass exert on the gamma ray irradiation characteristics is described. The specimens were mainly dispersion shift type fibers (DSF), and for comparison, single window, double window and 1.3 μm SM fibers were examined. Co-60 gamma ray was irradiated, and the optical loss and electron spin resonance were measured. By low temperature and low speed drawing, the good result in the optical loss was obtained. The presence of oxygen at the time of sintering materials had no effect. The dependence of the ESR on the drawing condition was not very remarkable. (Kako, I.)

Radiation protection at the RA Reactor in 1989, Part -2, Decontamination, collection of treatment of fluid and solid radioactive waste, Annex 3; Deo 2 - Zastita od zracenja kod reaktora RA u 1989. godini, Dekontaminacija i intervencija, sakupljanje i obrada tecnih i cvrstih radioaktivnih otpadnih materija za potrebe reaktora RA - Prilog 3

Energy Technology Data Exchange (ETDEWEB)

Mandic, M; Vukovic, Z; Plecas, I; Knezevic, Lj; Lazic, S; Bacic, S [Institute of Nuclear Sciences Boris Kidric, Vinca, Beograd (Serbia and Montenegro)

1989-12-15

Certain amount of solid waste results from RA reactor operation, the mean quantity of which depends on the duration of reactor operation and related activities. During repair, when reactor is not operated as well under accidental conditions, the quantity of waste is higher, dependent on the type of repair and comprehensiveness of decontamination of the working surface, contaminated tools and components. The waste is sorted and packed on the spot where they appeared according to the existing regulations and principles of radiation protection with aim to minimize unnecessary exposure of the radiation protection personnel who deals with control, transport, radioactive waste treatment and decontamination. During exceptional operations (decontamination, repair, bigger volume of contaminated material, etc.) professional staff of the Radiation protection department gives recommendations and helps in planning the actions related to repair, sorting and packaging of radioactive waste in special containers, identification of the contaminants, etc. [Serbo-Croat] Tokom rada reaktora RA dolazi do stvaranja odredjenih cvrstih otpadnih materijala cija prosecna kolicina zavisi od vremena rada reaktora i aktivnosti koje se tamo obavljaju. Tokom remonta, kada reaktor ne radi kao i pri akcidentalnim situacijama nastaju vece kolicine otpadnih materijala koje zavise od obima i vrste remontnih operacija i obima dekontaminacije kontaminirane radne povrsine i kontaminiranog alata, predmeta, opreme, itd. Nastali otpadni materijali se razvrstavaju i pakuju na mestu nastanka prema odgovarajucim propisima u skladu sa principima zastite od zracenja i aspekta bezbednosti u cilju minimiziranja nepotrebnog ozracivanja ljudstva za preuzimanje, kontrolu, transport, naknadnu obradu RAO i dekontaminaciju. Pri nerutinskim operacijama (dekontaminacija, remont, kontaminiarni otpadni materijal velike zapremine i sl.), strucna sluzba Institita ZASTITA pruza strucne konsultacije i pomaze pri planiranju

Studies concerning the preparation of the 153Sm complex with EDTMP (ethylenediaminetetra methylenephosphonic acid) and other 153Sm complexes with other phosphonates, at room temperature

International Nuclear Information System (INIS)

Gasiglia, Haroldo Taurian

2000-01-01

This work presents a study on the preparation of the complexes 1 53S m - EDTMP, 153 Sm - HEDP, 153 Sm - NTMP, 153 Sm - DTPMP and 153 Sm - HDTMP at room temperature. The preparation of the complex 153 Sm - HDTMP, under heating (70 - 72 deg C), was also studied. Several factors affecting the 153 Sm - EDTMP complexing yields were studied, due to its importance for use in Nuclear Medicine. These factors were: the molar ratio [ligand] / [metal], the ligand concentration and the incubation time of the mixture ligand-metal. The preparation of this complex, in low molar ratios, was also investigated. A study of the 153 Sm - EDTMP concerning the 'in vitro' stability, when this complex was prepared in low radioactive concentrations was performed. A study on the temperature influence on its degradation, when this complex was obtained in higher radioactive concentrations, was also performed. The preparation of the complexes 153 Sm - HEDP, 153 Sm - NTMP, 153 Sm - DTPMP and 153 Sm - HDTMP was investigated by preparing the complexes in two situations: high molar ratio and ligand concentration and low molar ratio and ligand concentration. The 'in vitro' stability of each complex, obtained in low radioactive concentration was studied. In the specific case of the complex 153 Sm - HDTMP, its biological distribution in mice was performed. All the complexes were investigated by high performance liquid chromatography (HPLC) and its complexing yields were determined by other three chromatographic processes: ionic exchange, thin layer chromatography (TLC - SG) and paper chromatography. The chromatographic processes were performed by association with specific radiochemical techniques. This work also presents a comparative study on the chromatograms obtained by thin layer chromatography (TLC - SG) and paper chromatography, when evaluated by the technique of cutting the strips into pieces and the chromatograms performed directly on a radiochromatography. The shape of the chromatograms and R

RA Research nuclear reactor, Part I - RA nuclear reactor operation, maintenance and utilization in 1983; Istrazivacki nuklearni reaktor RA - Deo I - Pogon, odrzavanje i eksploatacija nuklearnog reaktora RA u 1983. godini

Energy Technology Data Exchange (ETDEWEB)

Sotic, O; Martinc, R; Kozomara-Maic, S; Cupac, S; Raickovic, N; Radivojevic, J; Badrljica, R; Majstorovic, D; Sanovic, V [Institute of Nuclear Sciences Boris Kidric, Vinca, Beograd (Serbia and Montenegro)

1983-12-15

After regular shutdown in November 1982, inspection of the fuel elements from the RA reactor core which was done from December 1982 - February 1983 has shown that there are deposits of aluminium oxides on the surface of the fuel cladding. After restart The RA reactor was operated at power levels from 1.8 - 2 MW, with 80% enriched uranium dioxide fuel elements. It was found that there was no corrosion of the fuel element cladding and that it was not possible to find the cause of surface deposition on the cladding surfaces without further operation. It was decided to purify the heavy water permanently during operation and to increase the heavy water flow by operating two pumps. This procedure was adopted in order to decrease the possibility of corrosion. The Safety committee of the Institute has approved this procedure for operating the RA reactor in 1983. The core was made of 80% enriched fuel, critical experiments were done until June 1983, and after that the operation was continued at power levels up to 2 MW. [Serbo-Croat] Pregledom nuklearnog goriva iz tehnoloskih kanala reaktora RA koji je izvrsen u periodu decembear 1982-feburuar 1983. godine nakon zaustavljanja reaktora po isteku novembarske kampanje 1982. godine, ustanovljeno je da ponovo dolazi do stvaranja taloga u obliku hidratisanih oksida aluminiuma na kosuljicama gorivnih elemenata. Nakon ponovnog pustanja u rad, reaktor je do novembra 1981. godine neprekidno bio u pogonu na snagama 1,8 - 2 MW. Jezgro je bilo formirano iskljucivo sa od gorivnih elemenata sa 80% obogacenim uran dioksidom. Utvrdjeno je da kosuljica gorivnog elementa nije korodirala, i da se bez nastval rada ne moze utvrditi uzrok pojave taloga na povrsini kosuljice. Da bi se mogucnost korozije aluminjumskih komponenti u primarnom kolu raktora svela na sto manju meru odluceno je da se vrsi neprekidno preciscavanje teske vode i da se istovremeno poveca protok teske vode radom dve pumpe, Komitet za sigurnost Instituta odobrio je ovakav nacin

Calculational investigations and analysis of characteristics of research reactor WWR-M as a source of neutrons for solution of scientific and applied tasks

International Nuclear Information System (INIS)

Vorona, P.M.; Razbudej, V.F.

2010-01-01

Calculational studies and analysis of the neutron fields of WWR-M research reactor of the Institute for Nuclear Research, National Academy of Sciences of Ukraine, as a basic nuclear facility for performing the fundamental and applied investigations and for experimentalindustrial production of radioisotope products for various spheres of application are carried out. The calculations are carried out by the method of statistic tests (Monte Carlo) applying the computer program MCNP-4C. The data on the spectra and the neutron flux density values at the 10 MW reactor power for all technological facilities designed for the works with neutrons: 19 vertical experimental channels for irradiation of specimens and 10 horizontal channels for beams extraction from the reactor are obtained. The effect of the neutron traps (water cavities) mounted in the core on the characteristics of the extracted from the reactor beams is demonstrated. Recommendations associated with optimization of the reactor core are adduced for amplification of its capabilities as a neutron source in experimental researches.

The training of the staff for work with radioactive materials and work on nuclear reactor in the Institute; Obuka kadrova za rukovanje radioizotopima i pogon nuklearnih reaktora u Institutu 'Boris Kidric' - Vinca

Energy Technology Data Exchange (ETDEWEB)

Milosevic, M; Mladjenovic, O; Sotic, O [Institute of Nuclear Sciences Boris Kidric, Vinca, Beograd (Yugoslavia)

1978-05-15

A short informational review of the activities in the 'Boris Kidric' Institute on the training courses for the use of radioactive materials and for operating nuclear reactors including power reactors. The survey of the courses is given in the enclosures. (author) Kratak informativni pregled delatnosti u IBK na kursevima za obuku kadrova u rukovanju readioaktivnim materijalima i pogonu nuklearnih reaktora, ukljucujuci reaktore snage. pregled kurseva i materijala za njih dati su u prilozima. (author)

Structural and Magnetic Properties of Sm Implanted GaN

International Nuclear Information System (INIS)

Li-Juan, Jiang; Xiao-Liang, Wang; Hong-Ling, Xiao; Zhan-Guo, Wang; Chun, Feng; Ming-Lan, Zhang; Jian, Tang

2009-01-01

The structural and magnetic properties of Sm ion-implanted GaN with different Sm concentrations are investigated. XRD results do not show any peaks associated with second phase formation. Magnetic investigations performed by superconducting quantum interference device reveal ferromagnetic behavior with an ordering temperature above room temperature in all the implanted samples, while the effective magnetic moment per Sm obtained from saturation magnetization gives a much higher value than the atomic moment of Sm. These results could be explained by the phenomenological model proposed by Dhar et al. [Phys. Rev. Lett. 94(2005)037205, Phys. Rev. B 72(2005)245203] in terms of a long-range spin polarization of the GaN matrix by the Sm atoms. (condensed matter: electronicstructure, electrical, magnetic, and opticalproperties)

Emission properties of Sm(III) complex having ten-coordination structure

International Nuclear Information System (INIS)

Hasegawa, Yasuchika; Tsuruoka, Shin-ichi; Yoshida, Takahiko; Kawai, Hideki; Kawai, Tsuyoshi

2008-01-01

Sammarium(III) complex having ten-coordination structure, bis-(1,10-phenanthroline)tris-(hexafluoroacetylacetonato)samarium(III) (Sm(hfa) 3 (phen) 2 ) was prepared by chelation of tris-(hexafluoroacetylacetonato) samarium(III) (Sm(hfa) 3 (H 2 O) 2 ) with 1,10-phenantroline (phen). The characteristic ten-coordination structure of Sm(hfa) 3 (phen) 2 was determined by 1 H NMR and elemental analyses. Strong deep-red emission (λ max =643 nm) and narrow emission band (FWHM=5 nm) of Sm(hfa) 3 (phen) 2 originated from electronic allowed transition from characteristics ten coordinate structure. The emission quantum yields Sm(hfa) 3 (phen) 2 excited at absorption bands of ligands and Sm(III) ion were found to be 0.36 and 1.4%, respectively

Phase formation and crystallization behavior of melt spun Sm-Fe-based alloys

International Nuclear Information System (INIS)

Shield, J.E.

1999-01-01

The phase formation and microstructures of Sm-Fe alloys have been investigated at Sm levels of 11 and 17 atomic percent and with alloying additions of Ti and C. At lower Sm content, virtually phase pure SmFe 7 formed, while higher Sm content resulted in the formation of SmFe 7 , SmFe 2 and amorphous phases. The addition of Ti and C resulted in greater stability and a larger volume fraction of the amorphous phase. The binary Sm-Fe alloys at both Sm levels had tremendously variable microstructures, with large discrepancies in grain size and phase distribution from region to region. The addition of Ti and C tended to result in a more homogeneous microstructure, as well as a refinement in the microstructural scale. (orig.)

In vivo and in vitro binding assay of 153Sm-EDTMP

International Nuclear Information System (INIS)

Chen Daming; Wang Yuqing; Jin Xiaohai; Fan Hongqiang; Bai Hongsheng; Jia Bin; Zhang Jingming

1999-01-01

With the waters ultra hydrogel TM 120 μm hplc column (7.7 mm x 300 mm), several experiments have been finished, including the in vitro binding assay of 153 Sm-EDTMP, 153 SmCl 3 with the Cys, BSA, mouse plasma; HPLC analysis of the urine and the extracting solution of liver homogenate after having injected the 153 Sm-EDTMP and 153 SmCl 3 2h; HPLC analysis of the production ( 153 Sm-EDTMP) radiation self-decomposition with large dose. For the HPLC analysis, the condition is the mobile phase of 0.85 mol/mL PBS (pH7.5), flow rate of 0.5 mL/min, sampling of 15 μL. The results are following: (1) The 153 SmCl 3 not only is able to bind with the mouse plasma in vitro, but also is able to be absorbed by liver in vivo; (2) 153 Sm-EDTMP is not bind with the mouse plasma, the Cys and BSA in vitro and vivo; 153 Sm-EDTMP is not found in the extracted solution of liver homogenate at n(EDTMP): n(Sm) ≥ 5:1; 153 Sm-EDTMP is not decomposed in the urine, 1 53 Sm-EDTMP is stable in vivo; (3) 153 Sm-EDTMP radiation self-decomposition is not detected with large dose in the term of validity (6 d), but two small degradation peaks have been found in the production solution after 60 d, the radiochemistry purity of production is always great than 98% during the period

Operation, maintenance and utilization of the RA reactor - Report on operation in 1979; Pogon, odrzavanje i eksploatacija reaktora RA, Izvestaj o radu u 1979. godini

Energy Technology Data Exchange (ETDEWEB)

Milosevic, M

1979-12-15

During 1979 the RA reactor was in operation only three months, i.e. only 24% of the planned activity was achieved. The reactor operation was interrupted in March due to problems that could not be solved by the existing equipment. Alkalinity of the heavy water resulting from the existing ammonia ions could not be removed by the existing distillation system. In addition deposition of aluminium oxyhydrate on the fuel elements was increased. This was noticed during routine control when the reactor was shutdown for refueling. The decision of the Director general of the Institute and sanitary Inspector followed, prohibiting further reactor operation. A separate chapter of this report is devoted to the analysis of the difficulties and possible solution of the problem in cooperation with the experts from different laboratories of the Institute. Aged and damaged instruments at the reactor were not exchange due to lack of budget. During the operation there were no accidents. [Serbo-Croat] U toku 1979. godine plan rada ostvaren je sa 24%, odnosno reaktor je radio samo prva tri meseca. U martu je doslo do prekida rada reaktora zbog pojave koja se nije mogla otkloniti postojecom opremom. Alkalnost teske vode, posledica prisustva amonijum jona, ne moze se odstraniti sistemom destilacije. Pored toga usled dotrajalosti opreme povecano je talozenje aluminijum oksihidroksida na gorivnim elementima. Ova pojava uocena je tokom rutinske kontrole prilikom izmene goriva a usledila je obustava rada resenjem Direktora i sanitarnog inspektora. Posebno poglavlje ovog izvestaja posveceno je analizi teskoca u radu i reaktora i resavanju nastalih problema sa gorivom u saradnji sa saradnicima drugih laboratorija Instituta. Dotrajali uredjaji i oprema nisu zamenjeni usled nedostatka sredstava. U toku rada nije bilo akcidenata.

High coercivity Sm-Co thin films from elemental Sm/Co multilayer deposition and their microstructural aspects

Energy Technology Data Exchange (ETDEWEB)

Krishnan, M. [Surface Engineering Division, CSIR-National Aerospace Laboratories, Bangalore 560 017 (India); Department of Physics, National Institute of Technology Calicut, Calicut 673601 (India); Predeep, P. [Department of Physics, National Institute of Technology Calicut, Calicut 673601 (India); Sridhara Rao, D.V. [Defence Metallurgical Research Laboratories, Hyderabad 500058 (India); Prajapat, C.L.; Singh, M.R. [Technical Physics Division, Bhabha Atomic Research Centre, Mumbai 400085 (India); Barshilia, Harish C. [Surface Engineering Division, CSIR-National Aerospace Laboratories, Bangalore 560 017 (India); Chowdhury, P., E-mail: pchowdhury@nal.res.in [Surface Engineering Division, CSIR-National Aerospace Laboratories, Bangalore 560 017 (India)

2017-05-15

Hard magnetic thin films with high coercivity were fabricated by magnetron sputtering on MgO(100) and quartz substrates. The films were grown by depositing sequentially Sm and Co layers at an elevated substrate temperature of 500 °C. Subsequent post-annealing was carried out at various temperatures in range of 500–700 °C to form Sm-Co hard magnetic thin films. X-ray diffraction studies revealed the formation of randomly oriented SmCo{sub 5} crystallites on quartz substrate, whereas, a textured growth of Sm{sub 2}Co{sub 7} with strong (110) crystalline phases was observed on MgO substrate. Microstructural analyses were carried out using Transmission Electron Microscopy (TEM) for samples grown on MgO substrate at 650 °C and inferred the presence of high density planar defects along with large grain boundaries. Further microdiffraction studies confirmed the presence of SmCo{sub 3} as an impurity phase in the films. Magnetic hysteresis measurements indicate the square hysteresis behaviors with high coercivity value of 3.1 T and 2.7 T for 650 °C annealed samples on both MgO and quartz substrates, respectively. The origin of such high coercivity value was then correlated with pinning type of spin reversal mechanism as confirmed through the analyses of demagnetization curves. The magnetic force microscopy images for films on MgO substrate, annealed at 650 °C, revealed the presence of magnetic domains with size higher than 1 µm. The formed magnetic domains lacked well defined boundaries indicating an enhanced exchange coupling between the grain clusters. - Highlights: • Ewald technique in micromagnetic simulations with periodic boundary conditions. • Effect of micromagnetic parameters on hysteresis in exchange spring magnets. • Importance of the interface exchange coupling for hard-soft nanocomposites. • Geometry dependence of the optimal soft phase size in exchange spring magnets.

Sm29, but not Sm22.6 retains its ability to induce a protective immune response in mice previously exposed to a Schistosoma mansoni infection.

Directory of Open Access Journals (Sweden)

Clarice Carvalho Alves

2015-02-01

Full Text Available BACKGROUND: A vaccine against schistosomiasis would have a great impact in disease elimination. Sm29 and Sm22.6 are two parasite tegument proteins which represent promising antigens to compose a vaccine. These antigens have been associated with resistance to infection and reinfection in individuals living in endemic area for the disease and induced partial protection when evaluated in immunization trials using naïve mice. METHODOLOGY/PRINCIPALS FINDINGS: In this study we evaluated rSm29 and rSm22.6 ability to induce protection in Balb/c mice that had been previously infected with S. mansoni and further treated with Praziquantel. Our results demonstrate that three doses of the vaccine containing rSm29 were necessary to elicit significant protection (26%-48%. Immunization of mice with rSm29 induced a significant production of IL-2, IFN-γ, IL-17, IL-4; significant production of specific antibodies; increased percentage of CD4+ central memory cells in comparison with infected and treated saline group and increased percentage of CD4+ effector memory cells in comparison with naïve Balb/c mice immunized with rSm29. On the other hand, although immunization with Sm22.6 induced a robust immune response, it failed to induce protection. CONCLUSION/SIGNIFICANCE: Our results demonstrate that rSm29 retains its ability to induce protection in previously infected animals, reinforcing its potential as a vaccine candidate.

Hydrogen-induced amorphization of SmFe{sub 3}

Energy Technology Data Exchange (ETDEWEB)

Kubis, M.; Handstein, A.; Gebel, B.; Gutfleisch, O.; Mueller, K.-H.; Schultz, L. [Institut fuer Festkoerper- und Werkstofforschung Dresden e.V. (Germany). Inst. fuer Metallische Werkstoffe

2000-07-01

The hydrogen absorption behavior of SmFe{sub 3} (PuNi{sub 3}-type structure) was observed in the range from 0.05 to 4 MPa by differential scanning calorimetry. The structural changes were observed by X-ray diffraction measurements. For pressures below 0.8 MPa two exothermic reactions were found which are attributed (i) to the interstitial absorption and (ii) to the disproportionation into SmH{sub 2} and {alpha}-Fe. For higher hydrogen pressures, the second exothermic peak occured at significantly lower temperatures and splitted into two peaks. The first one was identified as the exothermic signal of the hydrogen-induced amorphization of the SmFe{sub 3} hydride. The second peak is caused by the precipitation of SmH{sub 2} and {alpha}-Fe from the amorphous material. (orig.)

Preferential removal of Sm by evaporation from Nd-Sm mixture and its application in direct burn-up determination of spent nuclear fuel

International Nuclear Information System (INIS)

Sajimol, R.; Bera, S.; Nalini, S.; Sivaraman, N.; Joseph, M.; Kumar, T.

2016-01-01

Rate of evaporation of Sm and Nd from their mixture was studied based on their ion intensities using thermal ionization mass spectrometry. Because of the comparatively larger evaporation rate of Sm, it was found possible to get the isotopic composition of Nd (fission product monitor) free from isobaric interference of Sm isotopes. The decrease in ion intensity of Sm was studied as a function of time and filament temperature. Based on this study, an easy and time effective method for the determination of burn-up of spent nuclear fuel was examined and the results are compared with that obtained by the conventional method. Typical burn-up value obtained for a pressurized heavy water reactor fuel dissolver solution using the direct method by preferential evaporation of Sm is: 0.84 at.%, whereas the one obtained by the use of conventional method is 0.82 at.%. In both the cases, Nd was employed as the fission product monitor. (author)

High spin states in 143Sm

International Nuclear Information System (INIS)

Raut, R.; Ganguly, S.; Kshetri, R.; Banerjee, P.; Bhattacharya, S.; Dasmahapatra, B.; Mukherjee, A.; Mukherjee, G.; Sarkar, M. Saha; Goswami, A.; Gangopadhyay, G.; Mukhopadhyay, S.; Krishichayan,; Chakraborty, A.; Ghughre, S. S.; Bhattacharjee, T.; Basu, S. K.

2006-01-01

The high spin states of 143 Sm have been studied by in-beam γ-spectroscopy following the reaction 130 Te( 20 Ne,7n) 143 Sm at E lab =137 MeV, using a Clover detector array. More than 50 new gamma transitions have been placed above the previously known J π =23/2 - , 30 ms isomer at 2795 keV. The level scheme of 143 Sm has been extended up to 12 MeV and spin-parity assignments have been made to most of the newly proposed level. Theoretical calculation with the relativistic mean field approach using blocked BCS method, has been performed. A sequence of levels connected by M1 transitions have been observed at an excitation energy ∼8.6 MeV. The sequence appears to be a magnetic rotational band from systematics

Chemical methods for Sm-Nd separation and its application in isotopic geological dating

International Nuclear Information System (INIS)

Guo Qifeng.

1990-01-01

Three chemical methods for Sm-Nd separation are mainly desribed: low chromatography of butamone-ammonium thiocyanate for hight concentration Sm and Nd separation, P 240 column chromatography for medium concentration Sm-Nd separation, and pressure ion exchange for low concentration Sm-Nd. The first Sm-Nd synchrone obtained in China with Sm-Nd methods is introduced and Sm-Nd isotopic geological dating in Early Archaean rocks in eastern Hebei has been determined

Smáčivost povrchových úprav DPS

OpenAIRE

Minář, Jan

2016-01-01

Tato bakalářská práce se zabývá měřením smáčecích charakteristik pomocí metody smáčecích vah u vzorků různých povrchových úprav od firmy Gatema. Věnuje se vlivu izotermálního stárnutí a přetavovacích procesů na smáčecí charakteristiky povrchových úprav ENIG, bezolovnatý HAL a imerzní cín. U povrchové úpravy imerzním cínem je sledován vliv intermetalické vrstvy na celkovou smáčivost. Dále se zabývá smáčivostí vrstvy niklu, po odstripování zlata, u povrchové úpravy ENIG. This bachelor’s thes...

VUV light induced valence degeneration in Sm over-layer on HOPG

International Nuclear Information System (INIS)

Kutluk, G; Nakatake, M; Arita, M; Namatame, H; Taniguchi, M; Ishitobi, Y; Sumida, H

2013-01-01

Systematic investigation of the influence of vacuum ultraviolet (VUV) irradiation on the valence degeneration in a Sm over-layer on a HOPG substrate was performed using in-situ photoemission spectroscopy (XPS, UPS, and ARPES) for the Sm coverage regime of 0.05-3.6 Å. This investigation confirmed that VUV irradiation-induced degeneration of divalent Sm exerts a more profound effect than Sm contamination during photoemission spectroscopy even under UHV. We found that the charge transfer occurs mainly from divalent Sm to the HOPG surface.

β-decay spectroscopy of neutron-rich 160,161,162Sm isotopes

Directory of Open Access Journals (Sweden)

Patel Z.

2016-01-01

Full Text Available Neutron-rich 160,161,162Sm isotopes have been populated at the RIBF, RIKEN via β first time. β-coincident γ rays were observed in all three isotopes including γ rays from the isomeric decay of 160Sm and 162Sm. The isomers in 160Sm and 162Sm have previously been observed but have been populated via β decay for the first time. The isomeric state in 162Sm is assigned a 4−v72+[ 633 ]⊗v12−[ 521 ]${4^ - }v{{7 \\over 2}^ + }\\left[ {633} \\right] \\otimes v{{1 \\over 2}^ - }\\left[ {521} \\right]$ configuration based on the decay pattern. The level schemes of 160Sm and 162Sm are presented. The ground states in the parent nuclei 160Pm and 162Pm are both assigned a 6−v72+[633]⊗π52−[532]${6^ - }v{{7 \\over 2}^ + }\\left[ {633} \\right] \\otimes \\pi {{5 \\over 2}^ - }\\left[ {532} \\right]$ configuration based on the population of states in the daughter nuclei. Blocked BCS calculations were performed to further investigate the spin-parities of the ground states in 160Pm, 161Pm, and 162Pm, and the isomeric state in 162Sm

Higher-order scalar interactions and SM vacuum stability

Energy Technology Data Exchange (ETDEWEB)

Lalak, Zygmunt; Lewicki, Marek; Olszewski, Paweł [Institute of Theoretical Physics, Faculty of Physics, University of Warsawul. Hoża 69, Warsaw (Poland)

2014-05-26

Investigation of the structure of the Standard Model effective potential at very large field strengths opens a window towards new phenomena and can reveal properties of the UV completion of the SM. The map of the lifetimes of the vacua of the SM enhanced by nonrenormalizable scalar couplings has been compiled to show how new interactions modify stability of the electroweak vacuum. Whereas it is possible to stabilize the SM by adding Planck scale suppressed interactions and taking into account running of the new couplings, the generic effect is shortening the lifetime and hence further destabilisation of the SM electroweak vacuum. These findings have been illustrated with phase diagrams of modified SM-like models. It has been demonstrated that stabilisation can be achieved by lowering the suppression scale of higher order operators while picking up such combinations of new couplings, which do not deepen the new minima of the potential. Our results show the dependence of the lifetime of the electroweak minimum on the magnitude of the new couplings, including cases with very small couplings (which means very large effective suppression scale) and couplings vastly different in magnitude (which corresponds to two different suppression scales)

Radiation protection at the RA Reactor in 1996, Part -2, Annex 1, Control of the working environment, dosimetry and radiation protection; Prilog 1 - Zastita od zracenja kod reaktora RA u 1996. godini - Deo 2 - Kontrola radne sredine - dozimetrija i tehnicka zastita kod reaktora RA

Energy Technology Data Exchange (ETDEWEB)

Pavlovic, R; Kalinic, S [Institute of Nuclear Sciences Boris Kidric, Vinca, Beograd (Serbia and Montenegro)

1996-12-01

This report contains data and analysis of the of measured sample results collected during radiation protection control in the working environment of the RA reactor. First part contains basic exposure values and statistical review of the the total number of radiation measurements. It includes contents of radioactive gasses and effluents in the air, as well as the level of surface contamination of clothes and uncovered parts of the personnel bodies. Second part deals with the analysis of personnel doses. Third part of this annex contains basic data about the quantity of collected radioactive waste, total quantity of contaminated and decontaminated surfaces. Previously initiated actions concerning future decision on the status of the RA reactor were continued during 1996. Actions in 1996 were focused to detailed analysis of the conditions of storing the spent fuel in the storage pools and preparing the documentation for decision making about the methods for the improvement of the mentioned conditions. It is stated that there have been no accidents that could cause significant contamination of working surfaces and components nor radiation exposure of the personnel. [Serbo-Croat] U ovom izvestaju prikazani su i analizirani reprezentativni rezultati sakupljeni u okviru kontrole radne sredine i tehnicke zastite od zracenja reaktora RA. U prvom delu izvestaja izlozeni su podaci o osnovnim vidovima izlaganja zracenju i statisticki pregled ukupnog broja radijacionih merenja. Dati su takodje rezultati merenja sadrzaja radioktivnih gasova i aerosola u vazduhu, kao i stepena kontaminacije povrsina, odece i otkrivenih delova tela osoblja. U drugom delu izvestaja izlozeni su rezultati analize ozracivanja radnog osoblja. U trecem delu izvestaja navedeni su osnovni podaci o ukupnim kolicinama sakupljenog radioaktivnog materijala, ukupnoj velicini kontaminiranih i dekontaminiranih povrsina i broju dekontaminiranih predmeta. U 1996. godini nastavljena je akcija zapoceta prethodne

Synthesis and magnetic properties of SmOOH crystals

Energy Technology Data Exchange (ETDEWEB)

Samata, Hiroaki, E-mail: samata@maritime.kobe-u.ac.jp [Graduate School of Maritime Sciences, Kobe University, Fukaeminami, Higashinada, Kobe, Hyogo 658-0022 (Japan); Hanioka, Masashi [Graduate School of Maritime Sciences, Kobe University, Fukaeminami, Higashinada, Kobe, Hyogo 658-0022 (Japan); Ozawa, Tadashi C. [Materials Development Group, Superconducting Properties Unit, National Institute for Materials Science, Sengen, Tsukuba, Ibaraki 305-0047 (Japan)

2016-01-15

Samarium oxyhydroxide (SmOOH) crystals were synthesized using a flux method. The as-grown crystals were yellowish, transparent, and elongated with a maximum length of approximately 1.0 mm. SmOOH adopts a monoclinic structure in the space group P2{sub 1}/m with a=0.4356 nm, b=0.3766 nm, c=0.6139 nm, and β=108.464°. The magnetic susceptibility of the SmOOH crystals exhibited typical Van Vleck paramagnetism, and the experimental data at temperatures above 200 K were in close agreement with the calculated results using a spin-orbit coupling constant λ=443 K (308 cm{sup −1}). - Highlights: • SmOOH crystals were synthesized via flux method and characterized. • Magnetic susceptibilities above 200 K agreed with theoretical Van Vleck values. • Discrepancies were observed at lower temperatures based on the crystalline field.

Sm2, a paralog of the Trichoderma cerato-platanin elicitor Sm1, is also highly important for plant protection conferred by the fungal-root interaction of Trichoderma with maize.

Science.gov (United States)

Gaderer, Romana; Lamdan, Netta L; Frischmann, Alexa; Sulyok, Michael; Krska, Rudolf; Horwitz, Benjamin A; Seidl-Seiboth, Verena

2015-01-16

The proteins Sm1 and Sm2 from the biocontrol fungus Trichoderma virens belong to the cerato-platanin protein family. Members of this family are small, secreted proteins that are abundantly produced by filamentous fungi with all types of life-styles. Some species of the fungal genus Trichoderma are considered as biocontrol fungi because they are mycoparasites and are also able to directly interact with plants, thereby stimulating plant defense responses. It was previously shown that the cerato-platanin protein Sm1 from T. virens - and to a lesser extent its homologue Epl1 from Trichoderma atroviride - induce plant defense responses. The plant protection potential of other members of the cerato-platanin protein family in Trichoderma, however, has not yet been investigated. In order to analyze the function of the cerato-platanin protein Sm2, sm1 and sm2 knockout strains were generated and characterized. The effect of the lack of Sm1 and Sm2 in T. virens on inducing systemic resistance in maize seedlings, challenged with the plant pathogen Cochliobolus heterostrophus, was tested. These plant experiments were also performed with T. atroviride epl1 and epl2 knockout strains. In our plant-pathogen system T. virens was a more effective plant protectant than T. atroviride and the results with both Trichoderma species showed concordantly that the level of plant protection was more strongly reduced in plants treated with the sm2/epl2 knockout strains than with sm1/epl1 knockout strains. Although the cerato-platanin genes sm1/epl1 are more abundantly expressed than sm2/epl2 during fungal growth, Sm2/Epl2 are, interestingly, more important than Sm1/Epl1 for the promotion of plant protection conferred by Trichoderma in the maize-C. heterostrophus pathosystem.

The ternary systems Sc-Sm(Dy)-Si at 870 K

International Nuclear Information System (INIS)

Kotur, B.Ya.; Mokra, I.Ya.; Toporinskij, A.Ya.

1991-01-01

Isothermal cross sections of the ternary systems Sc-Sm-Si and Sc-Dy-Si at 870 K have been plotted. Investigation of scandium and disprosium in ternary systems have been examined by X-ray diffraction and microstructure analysis. Besides literary data on binary systems Sc-Si, Sm-Si, Dy-Si have been used. Formation of limited (Sc-Sm-Si, Sc-Dy-Si) and continuous (Sc-Dy-Si) solid solutions based on bisilicides of Sc and Sm(Dy) is discovered. Two and five ternary compounds in Sc-Sm-Si and Sc-Dy-Si systems have been determined and their crystal structure has been established. When investigating of Sc-(rare earth element)-Si ternary systems and should take into account the specific interaction of scandium and samarium with REE

Klimaforsøg med fravænnede smågrise

DEFF Research Database (Denmark)

Feenstra, A.

Publikationen belyser betydningen af luftfugtighed og ventilationsluftmængder for smågrise. Undersøgelsen var led i bestræbelserne på at nedbringe energiforbruget i smågrisestalde, og resultaterne viser at ventilationsmængden kan formindskes uden skadelige virkninger for dyrene.......Publikationen belyser betydningen af luftfugtighed og ventilationsluftmængder for smågrise. Undersøgelsen var led i bestræbelserne på at nedbringe energiforbruget i smågrisestalde, og resultaterne viser at ventilationsmængden kan formindskes uden skadelige virkninger for dyrene....

Purification of the spliced leader ribonucleoprotein particle from Leptomonas collosoma revealed the existence of an Sm protein in trypanosomes. Cloning the SmE homologue.

Science.gov (United States)

Goncharov, I; Palfi, Z; Bindereif, A; Michaeli, S

1999-04-30

Trans-splicing in trypanosomes involves the addition of a common spliced leader (SL) sequence, which is derived from a small RNA, the SL RNA, to all mRNA precursors. The SL RNA is present in the cell in the form of a ribonucleoprotein, the SL RNP. Using conventional chromatography and affinity selection with 2'-O-methylated RNA oligonucleotides at high ionic strength, five proteins of 70, 16, 13, 12, and 8 kDa were co-selected with the SL RNA from Leptomonas collosoma, representing the SL RNP core particle. Under conditions of lower ionic strength, additional proteins of 28 and 20 kDa were revealed. On the basis of peptide sequences, the gene coding for a protein with a predicted molecular weight of 11.9 kDa was cloned and identified as homologue of the cis-spliceosomal SmE. The protein carries the Sm motifs 1 and 2 characteristic of Sm antigens that bind to all known cis-spliceosomal uridylic acid-rich small nuclear RNAs (U snRNAs), suggesting the existence of Sm proteins in trypanosomes. This finding is of special interest because trypanosome snRNPs are the only snRNPs examined to date that are not recognized by anti-Sm antibodies. Because of the early divergence of trypanosomes from the eukaryotic lineage, the trypanosome SmE protein represents one of the primordial Sm proteins in nature.

Solid-solid synthesis and structural phase transition process of SmF3

Science.gov (United States)

Yan, Qi-Cao; Guo, Xing-Min

2018-04-01

Mazes of contradictory conclusions have been obtained by previous researches about structural phase transition process of SmF3. In this paper, the single crystals of SmF3 (hexagonal and orthorhombic) were prepared by solid-solid synthesis, which have shown gradual changes in crystal growth modes with the increase temperature and holding time. Furthermore, we propose the phase transition process of in SmF3. Hexagonal symmetry of SmF3 (space group Pnma) was prepared firstly by heating Sm2O3 and NH4HF2 over 40 min at 270 °C. And then orthorhombic symmetry of SmF3 (space group P63mc) was obtained by heating hexagonal symmetry over 10 h at 650 °C. The reaction of SmF3 (hexagonal) = SmF3 (orthorhombic) is extremely sluggish at a low temperature (less than 650 °C), which was seen as a Mixed Grown Region.

Synthesis and photoluminescence properties of Sm3+-doped CaWO4 nanoparticles

International Nuclear Information System (INIS)

Xiao Qi; Zhou Qitao; Li Ming

2010-01-01

The Sm 3+ -doped CaWO 4 nanoparticles were synthesized by hydrothermal method. The room temperature photoluminescence (PL) spectra of Sm 3+ -doped CaWO 4 nanoparticles doped with different Sm 3+ concentrations under 405 nm excitation have been investigated. The PL spectra showed four strong emission peaks at 460, 571, 609, and 653 nm. The first emission peak at 460 nm could be due to a structural defect of the lattice, an oxygen-deficient WO 3 complex. The other three emissions at 571, 609, and 653 nm were due to the f-f forbidden transitions of the 4f electrons of Sm 3+ , corresponding to 4 G 5/2 → 6 H 5/2 (571 nm), 6 H 7/2 (609 nm), and 6 H 9/2 (653 nm), respectively. In addition, the optimum Sm 3+ concentration in CaWO 4 nanoparticles for optical emission was determined to be 1.0%. The Sm 3+4 G 5/2 → 6 H 7/2 (609 nm) emission intensity of Sm 3+ -doped CaWO 4 nanoparticles significantly increased with the increase of Sm 3+ concentration, and showed a maximum when Sm 3+ doping content was 1.0%. If Sm 3+ concentration continued to increase, namely more than 1.0%, the Sm 3+4 G 5/2 → 6 H 7/2 emission intensity would decrease. The present materials might be a promising phosphor for white-light LED applications.

Sorption of samarium in soils: influence of soil properties and Sm concentration

Energy Technology Data Exchange (ETDEWEB)

Ramirez-Guinart, Oriol; Salaberria, Aitor; Rigol, Anna; Vidal, Miquel [Analytical Chemistry department, Faculty of Chemistry, University of Barcelona, Marti i Franques 1-11, 08028, Barcelona (Spain)

2014-07-01

Due to the fact that barriers of Deep Geological Repositories (DGR) may lose efficiency before the radioisotopes present in the High Level Radioactive Waste (HLRW) completely decay, it is possible that, in the long-term, radioactive leachates may escape from the DGR and reach the soil and water compartments in the biosphere. Therefore, it is required to examine the interaction and mobility of radionuclides present in the HLRW, or their chemical analogues, to predict the impact of their eventual incorporation in the biosphere and to assess the derived risk. Although relevant data have been recently obtained for a few radionuclides in soils, there are still some important gaps for some radionuclides, such us for samarium (Sm). Sm is a lanthanide that, besides being considered as a natural analogue of actinides, may also be present in HLRW in the form of the radioactive isotope {sup 151}Sm. The main objective of this work was to obtain sorption data (K{sub d}) of {sup 151}Sm gathered from a set of soil samples physicochemical fully-characterized (pH, texture, cationic exchange capacity, soil solution cationic composition, organic matter, carbonate and metallic oxides content, etc.). Additionally, as an alternative for testing sorption capacity of radionuclides in soils is the use of the corresponding stable isotope or a chemical analogue, the influence of Sm concentration was also checked. To evaluate {sup 151}Sm sorption, batch assays were carried out for each soil sample, which consisted in a pre-equilibration step of 2 g of each soil with 50 ml of double deionised water, and a subsequent equilibration step with the same solution, but labelled with {sup 151}Sm. The activity of {sup 151}Sm in initial and final solutions was measured by liquid scintillation and K{sub d} ({sup 151}Sm) data were calculated. The reversibly sorbed fraction was estimated by the application of a single extraction test, with double deionised water, to soil residues coming from the previous

Determination of the {sup 151}Sm half-life

Energy Technology Data Exchange (ETDEWEB)

Be, Marie-Martine; Cassette, Philippe [CEA, LIST, Gif sur Yvette (France). LNE-Laboratoire National Henri Becquerel; Isnard, Helene [CEA-LANIE, Gif sur Yvette (France); and others

2015-07-01

New measurements have been undertaken to determine the half-life of {sup 151}Sm. A pure {sup 151}Sm solution was obtained after chemical separation from a samarium solution resulting from the dissolution of an irradiated samarium sample. The concentration of {sup 151}Sm in the solution was measured by mass spectrometry, combined with the isotope dilution technique. The activity of the solution was measured by liquid scintillation counting by six European laboratories as part of an international comparison. These combined results lead to a half-life of T{sub 1/2} = 94.6(6)a.

Data about operation and utilization of the RA in 1976 - Report, Annex I; Prilog I - Podaci o radu i iskoriscenosti reaktora RA u 1976. godini - Izvestaj -

Energy Technology Data Exchange (ETDEWEB)

Stanic, A [Institute of Nuclear Sciences Boris Kidric, Vinca, Beograd (Serbia and Montenegro)

1976-12-15

, nemogucnost da se predvidi tacno vreme za eksperimente u okviru (uspesno provedenog) programa prevodjenja reaktora RA na novo visokoobogaceno gorivo, posto neki od ovih eksperimenata takodje nikada ranije nije radjen. Sem toga bilo je i nepredvidjenih vecih remontnih radova zbog nepredvidjenih kvarova. Planirano je 6 izmena goriva koje su ostvarene sa zakasnjenjem. Podaci o planiranom i ostvarenom radu reaktora u 1976. godini prikazani su u ovom izvestaju kao i podaci o prekidu rada. Kracih prekida i sigurnosnih zaustavljanja je bilo 12 u ukupnom trajanju od 64 casa. Reaktor je radio na nominalnoj snazi od 6.5 MW. Akcidenata vecih razmera nije bilo, medjutim dva slucaja mogu se opisati kao akcidentalne situacije po nacinu kako su nastali. Prvi je prskanje cevi kod lezaja teskovodne pumpe a drugi kontaminacija hale i hodnika nastala prilikom pripreme masine za izmenu goriva (izlivanje teske vode). Ovaj prilog sadrzi i podatke o koriscenju eksperimentalnog prostora i iskoriscenosti reaktora.

Anti-skin-aging benefits of exopolymers from Aureobasidium pullulans SM2001.

Science.gov (United States)

Kim, Kyung Hu; Park, Soo Jin; Lee, Ji Eun; Lee, Young Joon; Song, Chang Hyun; Choi, Seong Hun; Ku, Sae Kwang; Kang, Su Jin

2014-01-01

There have been many attempts to search for affordable and effective functional cosmetic ingredients, especially from natural sources. As research into developing a functional cosmetic ingredient, we investigated whether exopolymers from Aureobasidium pullulans SM2001 (E-AP-SM2001) exert antioxidant, antiwrinkle, whitening, and skin moisturizing effects. Antioxidant effects of E-AP-SM2001 were determined by measuring free radical scavenging capacity and superoxide dismutase (SOD)-like activity. Antiwrinkle effects were assessed through the inhibition of hyaluronidase, elastase, collagenase, and matrix metalloproteinase (MMP)-1. Whitening effects were measured by tyrosinase inhibition assay, and by melanin formation test in B16/F10 melanoma cells. Skin moisturizing effects were detected by mouse skin water content test. E-AP-SM2001 showed potent DPPH radical scavenging activity and SOD-like effects. Additionally, hyaluronidase, elastase, collagenase, and MMP-1 activities were significantly inhibited by E-AP-SM2001. We also observed that E-AP-SM2001 effectively reduced melanin production by B16/F10 melanoma cells and mushroom tyrosinase activities. Furthermore, significant increases in skin water content were detected in E-AP-SM2001- treated mouse skin, as compared with vehicle-treated control skin. Notably, a mask pack containing E-AP-SM2001 showed a >twofold more extensive moisturizing effect compared with one containing Saccharomycopsis ferment filtrate. Our results suggest that E-AP-SM2001 has adequate antiaging, antiwrinkle, and whitening benefits and skin moisturizing effect. These effects involve reducing hyaluronidase, elastase, collagenase, and MMP-1 activities, as well as inhibition of melanin production and tyrosinase activities. Therefore, the antioxidant E-AP-SM2001 may serve as a predictable functional ingredient.

Electrochemical preparation of Al–Sm intermetallic compound whisker in LiCl–KCl Eutectic Melts

International Nuclear Information System (INIS)

Ji, De−Bin; Yan, Yong−De; Zhang, Mi−Lin; Li, Xing; Jing, Xiao−Yan; Han, Wei; Xue, Yun; Zhang, Zhi−Jian; Hartmann, Thomas

2015-01-01

Highlights: • The reduction process of Sm(III) was investigated in LiCl–KCl melt on an aluminum electrode at 773 K. • Al–Sm alloy with different phase structure (Al 2 Sm and Al 3 Sm) was prepared by potentiostatic electrolysis on an aluminum electrode with the change of electrolytic potentials and time in LiCl–KCl–SmCl 3 melts. • Al − Sm alloy containing whiskers (Al 4 Sm) was obtained by potentiostatic electrolysis (−2.10 V) on an aluminum electrode for 7 hours with the change of electrolytic temperature and cooling rate in LiCl–KCl–SmCl 3 (16.5 wt. %) melts. The results from micro–hardness test and potentiodynamic polarization test show the micro hardness and corrosion property are remarkably improved with the help of Al–Sm intermetallic compound whiskers. - Abstract: This work presents the electrochemical study of Sm(III) on an aluminum electrode in LiCl–KCl melts at 773 K by different electrochemical methods. Three electrochemical signals in cyclic voltammetry, square wave voltammetry, open circuit chronopotentiometry, and cathode polarization curve are attributed to different kinds of Al–Sm intermetallic compounds, Al 2 Sm, Al 3 Sm, and Al 4 Sm, respectively. Al–Sm alloy with different phase structure (Al 2 Sm and Al 3 Sm) could be obtained by the potentiostatic electrolysis with the change of electrolytic potentials and time. Al–Sm alloy containing whiskers (Al 4 Sm) was obtained by potentiostatic electrolysis (−2.10 V) on an aluminum electrode for 7 hours with the change of electrolytic temperature and cooling rate in LiCl–KCl–SmCl 3 (16.5 wt. %) melts. The XRD and SEM&EDS were employed to investigate the phase composition and microstructure of Al–Sm alloy. SEM analysis shows that lots of needle−like precipitates formed in Al–Sm alloy, and their ratios of length to diameter are found to be greater than 10 to 1. The TEM and electron diffraction pattern were performed to investigate the crystal structure of the

Isotope shifts and hyperfine splittings in 144-154Sm I

International Nuclear Information System (INIS)

England, J.G.; Grant, I.S.; Newton, G.W.A.; Walker, P.M.

1990-01-01

The isotope shifts and hyperfine splittings have been measured in 144-154 Sm I using the crossed-beam laser fluorescence method. Transitions at 598.98 nm and 570.68 nm were investigated for all isotopes except 146 Sm and 153 Sm, in which measurements were only obtained at 570.68 nm. Laser-induced fluorescence has not previously been reported for 145 Sm. The magnetic dipole and electric quadrupole moments of the odd isotopes and the changes in mean square radii of the even ones are shown to be consistent with the information obtained from nuclear spectroscopy. (author)

Guided ion beam and theoretical studies of the bond energy of SmS+

Science.gov (United States)

Armentrout, P. B.; Demireva, Maria; Peterson, Kirk A.

2017-12-01

Previous work has shown that atomic samarium cations react with carbonyl sulfide to form SmS+ + CO in an exothermic and barrierless process. To characterize this reaction further, the bond energy of SmS+ is determined in the present study using guided ion beam tandem mass spectrometry. Reactions of SmS+ with Xe, CO, and O2 are examined. Results for collision-induced dissociation processes with all three molecules along with the endothermicity of the SmS+ + CO → Sm+ + COS exchange reaction are combined to yield D0(Sm+-S) = 3.37 ± 0.20 eV. The CO and O2 reactions also yield a SmSO+ product, with measured endothermicities that indicate D0(SSm+-O) = 3.73 ± 0.16 eV and D0(OSm+-S) = 1.38 ± 0.27 eV. The SmS+ bond energy is compared with theoretical values characterized at several levels of theory, including CCSD(T) complete basis set extrapolations using all-electron basis sets. Multireference configuration interaction calculations with explicit spin-orbit calculations along with composite thermochemistry using the Feller-Peterson-Dixon method and all-electron basis sets were also explored for SmS+, and for comparison, SmO, SmO+, and EuO.

Prediction of the new efficient permanent magnet SmCoNiFe3

Science.gov (United States)

Söderlind, P.; Landa, A.; Locht, I. L. M.; Åberg, D.; Kvashnin, Y.; Pereiro, M.; Däne, M.; Turchi, P. E. A.; Antropov, V. P.; Eriksson, O.

2017-09-01

We propose a new efficient permanent magnet, SmCoNiFe3, which is a development of the well-known SmCo5 prototype. More modern neodymium magnets of the Nd-Fe-B type have an advantage over SmCo5 because of their greater maximum energy products due to their iron-rich stoichiometry. Our new magnet, however, removes most of this disadvantage of SmCo5 while preserving its superior high-temperature efficiency over the neodymium magnets. We show by means of first-principles electronic-structure calculations that SmCoNiFe3 has very favorable magnetic properties and could therefore potentially replace SmCo5 or Nd-Fe-B types in various applications.

Superconductivity in Sm-doped CaFe2As2 single crystals

Science.gov (United States)

Dong-Yun, Chen; Bin-Bin, Ruan; Jia, Yu; Qi, Guo; Xiao-Chuan, Wang; Qing-Ge, Mu; Bo-Jin, Pan; Tong, Liu; Gen-Fu, Chen; Zhi-An, Ren

2016-06-01

In this article, the Sm-doping single crystals Ca1 - x Sm x Fe2As2 (x = 0 ˜ 0.2) were prepared by the CaAs flux method, and followed by a rapid quenching treatment after the high temperature growth. The samples were characterized by structural, resistive, and magnetic measurements. The successful Sm-substitution was revealed by the reduction of the lattice parameter c, due to the smaller ionic radius of Sm3+ than Ca2+. Superconductivity was observed in all samples with onset T c varying from 27 K to 44 K upon Sm-doping. The coexistence of a collapsed phase transition and the superconducting transition was found for the lower Sm-doping samples. Zero resistivity and substantial superconducting volume fraction only happen in higher Sm-doping crystals with the nominal x > 0.10. The doping dependences of the c-axis length and onset T c were summarized. The high-T c observed in these quenched crystals may be attributed to simultaneous tuning of electron carriers doping and strain effect caused by lattice reduction of Sm-substitution. Project supported by the National Natural Science Foundation of China (Grant No. 11474339), the National Basic Research Program of China (Grant Nos. 2010CB923000 and 2011CBA00100), and the Strategic Priority Research Program of the Chinese Academy of Sciences (Grant No. XDB07020100).

Evaluation the homogenisation behaviour of Sm-Fe-Nb materials by Moessbauer spectroscopy

International Nuclear Information System (INIS)

Sinan, S. A.; Muryaed, Y.; Alhweg, F. A.

2004-01-01

The microstructure of cast and annealed Sm-Fe-Nb materials were investigated by Moessbauer spectroscopy. The aim of the present work is to study the effect of Nb additions upon the microstructure of Sm 2 Fe 17 material and evaluation the homogenisation behaviour of different Sm-Fe-Nb materials. The niobium free cast material consisting of the Sm 2 Fe 17 phase and significant amounts of the free iron (α -Fe). Therefore, the homogenisation process is necessary to eliminate the free iron and produce a single Sm 2 Fe 17 phase material. This process takes long annealing time, up to seven days. The Sm 9 .5 Fe 8 7.5 Nb 3 alloy contains the lowest amount of α-Fe among, the Sm-Fe-Nb materials. Thus the homogenisation step was carried out with treatment time (12 hours) smaller than the reported annealing time of Nb-free material (Sm 2 Fe 17 ). Therefore, the addition of at 3% Nb reduces the manufacturing cost of the Sm 2 Fe 17 and makes this based material for permanent magnets, more industrially desirable, due to elimination the free iron with lowest treatment time. Also it was found that the existence of the paramagnetic NbFe 2 phase becomes higher after the homogenisation process, which can be explained due to the diffusion of Nb from Sm 2 Fe 17 phase to paramagnetic NbFe 2 phase, during the annealing process. (authors)

The SM and MIR reactors operation experience

International Nuclear Information System (INIS)

Kuprienko, V.A.; Klinov, A.V.; Svyatkin, M.N.; Shamardin, V.K.

1995-01-01

The SM and MIR operation experience show that continuous work on the problem of ageing, in all its aspects, allows for prolongation of the research plant life cycle by several folds as compared to the initial project. The redesigned SM-3 reactor will operate for another 20 years. The similar result is expected from the MIR planned reconstruction which scope will be the topic of future presentations. (orig.)

Aligned, plasma sprayed SmCo5 deposits

International Nuclear Information System (INIS)

Kumar, K.; Das, D.

1986-01-01

Highly aligned SmCo 5 deposits were produced using plasma spraying. c-axis alignment, normal to the plane of the deposit, was achieved by depositing the Sm-Co alloys on steel substrates maintained at high temperatures. The substrates were heated by the plasma flame to obtain the high temperatures. The attainment of a range of substrate temperatures was made possible through control over the geometry of the substrate

The electrodeposition of 149Sm targets for (n,α) studies

International Nuclear Information System (INIS)

Ingelbrecht, C.; Ambeck-Madsen, J.; Teipel, K.; Robouch, P.; Arana, G.; Pomme, S.

1999-01-01

A method of electrodeposition from ethanol was developed for the production of 149 Sm targets of area 50x60 mm 2 to be used for (n,α) experiments. Targets of 60 μg cm -2 Sm were obtained with a Sm yield of 50% and a Sm mass fraction of 35% after calcination of the layers at 450 deg. C. Target substrates were 20 μm aluminium foils mounted on brass frames. A water cooling jig was constructed to protect the glue used for mounting during the calcination process. The layers were characterized by inductively coupled plasma source mass spectrometry (ICP-MS) and by neutron activation analysis (NAA)

Role of SM22 in the differential regulation of phasic vs. tonic smooth muscle

Science.gov (United States)

Ali, Mehboob

2015-01-01

Preliminary proteomics studies between tonic vs. phasic smooth muscles identified three distinct protein spots identified to be those of transgelin (SM22). The latter was found to be distinctly downregulated in the internal anal sphincter (IAS) vs. rectal smooth muscle (RSM) SMC. The major focus of the present studies was to examine the differential molecular control mechanisms by SM22 in the functionality of truly tonic smooth muscle of the IAS vs. the adjoining phasic smooth muscle of the RSM. We monitored SMC lengths before and after incubation with pFLAG-SM22 (for SM22 overexpression), and SM22 small-interfering RNA. pFLAG-SM22 caused concentration-dependent and significantly greater relaxation in the IAS vs. the RSM SMCs. Conversely, temporary silencing of SM22 caused contraction in both types of the SMCs. Further studies revealed a significant reverse relationship between the levels of SM22 phosphorylation and the amount of SM22-actin binding in the IAS and RSM SMC. Data showed higher phospho-SM22 levels and decreased SM22-actin binding in the IAS, and reverse to be the case in the RSM SMCs. Experiments determining the mechanism for SM22 phosphorylation in these smooth muscles revealed that Y-27632 (Rho kinase inhibitor) but not Gö-6850 (protein kinase C inhibitor) caused concentration-dependent decreased phosphorylation of SM22. We speculate that SM22 plays an important role in the regulation of basal tone via Rho kinase-induced phosphorylation of SM22. PMID:25617350

A metastable Mg11Sm phase obtained by rapid solidification

International Nuclear Information System (INIS)

Budurov, S.

1993-01-01

Molten Mg-Sm alloys with a Sm concentration of 4.93, 6.86, and 8.35 at.% were rapidly soldified with the aid of a shock wave gun device. Investigations of the obtained splats were performed with the aid of DSC, X-ray analysis, and metallography. Rapid soldification of the eutectic MgSm 8.35 alloy forms a new Im3m-type phase. (orig.)

Low temperature preparation and superconductivity of F-doped SmFeAsO

Energy Technology Data Exchange (ETDEWEB)

Chen, Y.L.; Cui, Y.J. [Key Laboratory of Magnetic Levitation Technologies and Maglev Trains (Ministry of Education of China), Superconductivity R and D Center (SRDC), Mail Stop 165, Southwest Jiaotong University, Chengdu, Sichuan 610031 (China); Cheng, C.H. [School of Materials Science and Engineering, University of New South Wales, Sydney, 2052 NSW (Australia); Yang, Y.; Wang, L.; Li, Y.C.; Zhang, Y. [Key Laboratory of Magnetic Levitation Technologies and Maglev Trains (Ministry of Education of China), Superconductivity R and D Center (SRDC), Mail Stop 165, Southwest Jiaotong University, Chengdu, Sichuan 610031 (China); Zhao, Y., E-mail: yzhao@swjtu.edu.c [Key Laboratory of Magnetic Levitation Technologies and Maglev Trains (Ministry of Education of China), Superconductivity R and D Center (SRDC), Mail Stop 165, Southwest Jiaotong University, Chengdu, Sichuan 610031 (China); School of Materials Science and Engineering, University of New South Wales, Sydney, 2052 NSW (Australia)

2010-11-01

A low temperature (1100 deg. C) process of preparing F-doped SmFeAsO samples has been developed using SmF{sub 3} with nanometer scale as the source of fluorine. A series of the SmFeAsO{sub 1-x}F{sub x} (x = 0, 0.05, 0.1, 0.15, 0.2, 0.25, 0.3) samples have been prepared using the present method. Compared with previous reports, the present SmF{sub 3} is more effective to introduce F into SmFeAsO system in which a transition temperature of 39 K can be observed when x = 0.05. The superconductivity is definitely enhanced with the increasing F-doping level. All the samples presented to be layered structure and the crystal particle size is about three times larger with sintering time increasing from 36 h to 48 h. Except for the nanometer scale of SmF{sub 3}, the flux effect of SmF{sub 3} is recognized to be another reason for the decrease of the sintering temperature. Further more, a relatively large amount of SmF{sub 3} was also employed in the raw materials to introduce excessive F and this has induced higher T{sub c} (55 K) in SmFeAsO{sub 0.8}F{sub 0.2+{delta}}system.

The glomerular parietal epithelial cell's responses are influenced by SM22 alpha levels.

Science.gov (United States)

Naito, Shokichi; Pippin, Jeffrey W; Shankland, Stuart J

2014-11-06

Studies have shown in several diseases initially affecting podocytes, that the neighboring glomerular parietal epithelial cells (PECs) are secondarily involved. The PEC response might be reparative under certain circumstances, yet injurious under others. The factors governing these are not well understood. We have shown that SM22α, an actin-binding protein considered a marker of smooth muscle differentiation, is upregulated in podocytes and PECs in several models of podocyte disease. However, the impact of SM22α levels on PECs is not known. Experimental glomerular disease, characterized by primary podocyte injury, was induced in aged-matched SM22α+/+ and SM22α-/-mice by intraperitoneal injection of sheep anti-rabbit glomeruli antibody. Immunostaining methods were employed on days 7 and 14 of disease. The number of PEC transition cells, defined as cells co-expressing a PEC protein (PAX2) and podocyte protein (Synaptopodin) was higher in diseased SM22α-/-mice compared with SM22α+/+mice. WT1 staining along Bowman's capsule is higher in diseased SM22α-/-mice. This was accompanied by increased PEC proliferation (measured by ki-67 staining), and an increase in immunostaining for the progenitor marker NCAM, in a subpopulation of PECs in diseased SM22α-/-mice. In addition, immunostaining for vimentin and alpha smooth muscle actin, markers of epithelial-to-mesenchymal transition (EMT), was lower in diseased SM22α-/-mice compared to diseased SM22α+/+mice. SM22α levels may impact how PECs respond following a primary podocyte injury in experimental glomerular disease. Absent/lower levels favor an increase in PEC transition cells and PECs expressing a progenitor marker, and a lower EMT rate compared to SM22α+/+mice, where SM22 levels are markedly increased in PECs.

Thermogravimetric and Magnetic Studies of the Oxidation and Reduction Reaction of SmCoO3 to Nanostructured Sm2O3 and Co

Science.gov (United States)

Kelly, Brian; Cichocki, Ronald; Poirier, Gerald; Unruh, Karl

The SmCoO3 to nanostructured Sm2O3 and Co oxidation and reduction reaction has been studied by thermogravimetric analysis (TGA) measurements in forming gas (FG) and inert N2 atmospheres, x-ray diffraction (XRD) and vibrating sample magnetometry (VSM). The TGA measurements showed two clearly resolvable reduction processes when heating in FG, from the initial SmCoO3 phase through an intermediate nanostructured mixture of Sm2O3 and CoO when heated to 330°C for several minutes, and then the conversion of CoO to metallic Co when heated above 500°C. These phases were confirmed by XRD and VSM. Similar measurements in N2 yielded little mass change below 900°C and coupled reduction processes at higher temperatures. Isoconversional measurements of the CoO to Co reduction reaction in FG yielded activation energies above 2eV/atom in the nanostructured system. This value is several times larger than those reported in the literature or obtained by similar measurements of bulk mixtures of Sm2O3 and CoO, suggesting the nanostructuring was the source of the large increase in activation energy.

Synthesis and physicochemical analysis of Sm (II, III) acetylacetone chelate complexes

International Nuclear Information System (INIS)

Kostyuk, N.N.; Dik, T.A.; Trebnikov, A.G.

2004-01-01

Sm (II, III) acetylacetone chelate complexes were synthesized by electrochemical method. It was shown that anode dissolution of the metal samarium over acetylacetone leads to formation of the Sm (II, III) chelate complexes: xSm(acac)2 · ySm(acac)3 · zH(acac). Factors x, y and z depend on quantity of the electricity, which flew through the electrolysis cell. The compositions of the obtained substances were confirmed by the physicochemical analysis (ultimate analysis, IR-, mass spectroscopy and thermal analysis (thermogravimetric, isothermal warming-up and differential scanning colorimetry). (Authors)

Study on cellular survival adaptive response induced by low dose irradiation of 153Sm

International Nuclear Information System (INIS)

Zhu Shoupeng; Xiao Dong

1999-01-01

The present study engages in determining whether low dose irradiation of 153 Sm could cut down the responsiveness of cellular survival to subsequent high dose exposure of 153 Sm so as to make an inquiry into approach the protective action of adaptive response by second irradiation of 153 Sm. Experimental results indicate that for inductive low dose of radionuclide 153 Sm 3.7 kBq/ml irradiated beforehand to cells has obvious resistant effect in succession after high dose irradiation of 153 Sm 3.7 x 10 2 kBq/ml was observed. Cells exposed to low dose irradiation of 153 Sm become adapted and therefore the subsequent cellular survival rate induced by high dose of 153 Sm is sufficiently higher than high dose of 153 Sm merely. It is evident that cellular survival adaptive response could be induced by pure low dose irradiation of 153 Sm only

Experiences of activity measurements of primary circuit materials in a WWR-SM research reactor

International Nuclear Information System (INIS)

Elek, A.; Toth, M.; Bakos, L.; Vizdos, G.

1980-01-01

The activity of water and gas samples taken from the primary circuit have been measured nondestructively for more than two years to monitor the technological parameters of the reactor. In the primary water samples 17 fission products and seven activated traces, as well as six radioactive conponents in the gas samples were determined routinely by Ge/Li gamma-spectrometry. (author)

PVD Ti coatings on Sm-Co magnets

International Nuclear Information System (INIS)

Bovda, O.M.; Bovda, V.O.; Garkusha, I.E.; Leonov, S.O.; Onishchenko, L.V.; Tereshin, V.I.; Totrika, O.S.; Chen, C.H.

2008-01-01

The combination of conventional ion-plasma deposition (PVD) and pulsed plasma technologies (PPT) has been applied for rare-earth Sm-Co based magnets, to provide them with enhanced corrosion resistance. The influence of pulsed plasma treatment on Sm-Co magnets with deposited titanium PVD coatings has been investigated. It was revealed that thickness of modified layer significantly depends on the thickness of initial titanium film and plasma treatment regimes. As a result of plasma treatment with energy density of 30 J/cm 2 and pulse duration of ∼ 5 μs fine-grained layer with the thickness of 70 microns has been formed on the Sm-Co magnet with pure titanium film of 50 micron. According to SEM analyses considerable diffusion of titanium to the bulk of the magnet, on the depth of 20 microns, took place. Such reaction enhances strong bonding between the coating and the magnet

Magnetic anisotropies in SmCo thin films

International Nuclear Information System (INIS)

Chen, K.

1993-01-01

A systemic study of the deposition processes and magnetic properties for the Sm-Co film system has been carried out. Films of Sm-Co system with various magnetic anisotropies have been synthesized through sputter deposition in both crystalline and amorphous phases. The origins of various anisotropies have been studied. Thermalized sputter deposition process control was used to synthesize Fe enriched Sm-Co films with rhombohedral Th 2 Zn 17 type structure. The film exhibited unusually strong textures with the crystallographic c axes of the crystallites aligned in the film plane. A large anisotropy was resulted with easy axis in the film plane. A well defined and large in-the-film-plane anisotropy of exceptionally high value of 3.3 x 10 6 erg/cm 3 has been obtained in the amorphous SmCo films by applying a magnetic field in the film plane during deposition. It was found that the in-the-film-plane anisotropy depended essentially on the applied field and Sm concentration. For films not synthesized through thermallized sputtering, the easy axis of the film could reoriented. A perpendicular anisotropy was also presented in the film synthesized through thermallized sputtering deposition. A large in-plane anisotropy was obtained in films deposited above ambient temperatures. It was concluded that the surface induced short range ordering was the origin of the in-the-film-phase anisotropy observed in amorphous film deposited in the presence of a magnetic field. The formation mechanism was different from that of the short range ordering induced by field annealing. The perpendicular anisotropy was shown to be growth induced. Large in-plane anisotropy in amorphous films was resulted form partial crystallization in the film. Both the formation of growth induced structure and partial crystallization in the film prevented the formation of the pair ordering and decreased in-the-film-plane anisotropy

Research reactor RB, technical characteristics and experimental possibilities; Zbornik radova, Konferencija o koriscenju nuklearnih reaktora u Jugoslaviji

Energy Technology Data Exchange (ETDEWEB)

Sotic, O; Vranic, S [Institute of Nuclear Sciences Boris Kidric, Vinca, Beograd (Yugoslavia)

1978-05-15

Nuclear research reactor RB tn the Nuclear Engineering Laboratory at the Institute of Nuclear Sciences 'Boris Kidric' in Vinca is the first reactor system built in Yugoslavia in 1958. In this report, the basic technical characteristics of this reactor are described, as well as the experimental possibilities it offers to the users. Its relatively simple construction and flexibility enables direct measurements of a series of physical parameters, and the absence of the biological protection shield makes it very useful for Various biological and other irradiations and dosimetric measurements Where strong neutron source is required. (author) Istrazivacki nuklearni reaktor RB u Laboratoriji za nuklearnu energetiku i tehnicku fiziku Instituta za nuklearne nauke 'Boris Kidric' u Vinci je prvi reaktorski sistem izgradjen u Jugooslaviji 1958. godine. U ovom radu opisane su osnovne tehnicke karakteristike tog reaktora, kao i mogucnosti za izvodjenje eksperimenata koje on pruza korisnicima. Njegova relativno jednostavna konstrukcija i fleksibilnost omogucavaju da se na njemu izvrse direktna merenja niza fizickih parametara, a s druge strane odsustvo bioloskog zastitnog omotaca cini ga veoma pogodnim za razna bioloska i druga ozracivanja, a takodje i dozimetrijska merenja gde se zahteva snazan izvor neutrona. (author)

Final report on the IAEA research contracts No. 1194/RB, 1194/R1/RB and 1194/R2/RB

International Nuclear Information System (INIS)

Zobor, E.; Janosy, J.S.; Szentgali, A.

1980-09-01

The final report summarizes the research activities made in the framework of the IAEA Research Contracts No. 1194/RB, 1194/R1/RB and 1194/R2/RB. A multilevel hierarchical control system is treated which uses weakly-coupled low dimensional subsystems under the supervision of a dynamic coordinator program. This self-organizing adaptive control system was checked by a 5 MW research reactor. As an example the paper describes the experimental computer control system of the 5 MW WWR-SM research reactor, where the reactor power and outlet temperature have been controlled on the basis of the treated control concept since 1978. (author)

RA reactor operation in 1991, Part 1; Deo 1 - Pogon i odrzavanje nuklearnog reaktora RA u 1991. godini

Energy Technology Data Exchange (ETDEWEB)

Sotic, O; Cupac, S; Sulem, B; Zivotic, Z; Majstorovic, D; Sanovic, V [Institute of Nuclear Sciences Boris Kidric, Vinca, Beograd (Serbia and Montenegro)

1992-01-01

pouzdan rad reaktora i skladu sa novim zakonskim propisima, u toku 1991. zavrseni su radovi na izgradnji sistema za udesno hladjenje, rekonstrukciju postojeceg sistema specijalne ventilacije i rekonstrukciji sistema za napajanje elektricnom energijom. Zapoceti su radovi na modernizaciji instrumentacije reaktora ali njegova realizacija u 1991. godini kasni usled zastoja u isporuci opreme iz Sovjetskog saveza. Izradu ove opreme finansira Medjunarodna agencija za atomsku energiju kroz ugovor sklopljen decembra 1988. godine sa moskovskom firmom Atomenergoexport, ali je MAAE privremeno zabranila isporuke opreme Jugoslaviji iz politickih razloga. Kontrola i odrzavanje opreme, kao i potrebni remontni radovi izvrsavani su redovno u zavisnosti od raspolozivosti rezervnih delova. Obuka postojeceg osoblja sprovodi se redovno ali nedostatak sredstava onemogucava prijem novih radnika sto bi bilo neophodno za rad u smenama i redovno odrzavanje.

Mixed Messages from Garnet Lu-Hf and Sm-Nd Geochronology

Science.gov (United States)

Vervoort, J. D.; Wang, D.; Johnson, T. A.

2017-12-01

Garnet geochronology provides important information on the timing and conditions of metamorphism. As a major indicator mineral formed during metamorphism, its direct dating can not only help establish the timing of metamorphism, provide the "t" for P-T-t paths, but also, if the dated garnet can be placed in a textural context, can provide information on the timing of deformational features. With advances in chemistry and mass spectrometry, garnet Lu-Hf and Sm-Nd geochronology has become an important geochronological tool and we can now reliably (if not routinely) date a wide variety of garnet compositions formed under diverse conditions. In the course of dating a variety of lithologies using both Lu-Hf and Sm-Nd isotope systems, however, some intriguing results have emerged. Although there are many examples where the Lu-Hf and Sm-Nd systems give the same date within uncertainty, there are also many cases where these systems yield significantly different dates, and the differences between these dates can be considerable—many 10's of Ma of and even 100's of Ma. For example, in garnet-bearing Mesoproterozoic gneisses from across the Blue Ridge Province in Virginia, both Lu-Hf and Sm-Nd analyses (determined on the same solutions) define narrow time spans, but with the Sm-Nd dates systematically younger (for orthogneisses Lu-Hf dates are 1032 to 1019 Ma whereas Sm-Nd dates are 965 to 949 Ma—a difference of 67 to 80 Ma). There are many other examples of systematically younger Sm-Nd garnet dates in both the literature and with our ongoing research. Potential explanations for these differences include: 1) strong partitioning of Lu into garnet during growth yielding ages weighted toward the beginning of growth; 2) faster Lu diffusion from high Lu regions after garnet formation, potentially leading to isochron rotation and anomalously old Lu-Hf dates; and 3) differences in closure temperatures of the two isotope systems. We will review several examples of divergent Lu

Theoretical analysis of nuclear reactors (Phase I), I-V, Part III, Reactor poisoning; Razrada metoda teorijske analize nuklearnih reaktora (I faza) I-V, III Deo, Zatrovanje reaktora, I faza

Energy Technology Data Exchange (ETDEWEB)

Pop-Jordanov, J [Institute of Nuclear Sciences Boris Kidric, Vinca, Beograd (Serbia and Montenegro)

1962-07-15

Method was developed for calculation of Xe{sup 135} static effect and kinetic effects of Xe{sup 135} and Sm{sup 149} with separate treatment of iodine effect and influence of reactor poisoning during power increase. Mentioned effects are treated first for uranium fuel and then the basic formulae were generalized for a mixture of fissile material. The annex contains a table with data needed for calculations and the Xe{sup 135} microscopic capture cross section dependent on temperature. Razradjen je metod proracuna statickog efekta Xe{sup 135} zatim kinetickog efekta Xe{sup 135} i Sm{sup 149} sa posebnim tretiranjem jodne jame i promene zatrovanja pri prelazu sa jedne snage na drugu. Navedeni efekti su tretirani prvo za uransko gorivo, a zatim su glavni obrasci uopsteni za smesu fisibilnih materijala. U prilogu su dati u vidu tabele, podaci potrebni za proracun i grafik zavisnosti mikroskopskog preseka zahvata Xe{sup 135} od temperature.

Crystal growth of Sm0.3Tb0.7FeO3 and spin reorientation transition in Sm1−xTbxFeO3 orthoferrite

International Nuclear Information System (INIS)

Wu, Anhua; Wang, Bo; Zhao, Xiangyang; Xie, Tao; Man, Peiwen; Su, Liangbi; Kalashnikova, A.M.; Pisarev, R.V.

2017-01-01

In this work, Sm 0.3 Tb 0.7 FeO 3 single crystal was successfully grown by optical floating zone method. Sm 0.3 Tb 0.7 FeO 3 samples with a-, b-, and c-orientation were manufactured by means of Laue photograph. Magnetic properties of Sm 0.3 Tb 0.7 FeO 3 single crystals are studied over a wide temperature range from 2 to 400 K. Spin reorientation transition from Γ 2 to Γ 4 are observed by means of the temperature dependence of magnetization It indicated the reorientation transition temperature of Sm 1−x Tb x FeO 3 single crystals is lowered with the contents of Tb contents rising based on this work and our previous works, thus the spin reorientation transition temperature can be adjusted through changing the compound in orthoferrites materials, which means that we can get orthoferrites single crystals with high magnetism property in various temperature through material design. - Highlights: • Sm 0.3 Tb 0.7 FeO 3 single crystals with various compounds were successfully grown by optical floating zone method. • The relation between SRT temperature and composition in Sm 1−x Tb x FeO 3 orthoferrite was indicated. • The spin reorientation transition temperature of Sm 1−x Tb x FeO 3 single crystals can be adjusted through changing the compound in orthoferrites materials.

Low temperature features of the local structure of Sm1-xYxS

International Nuclear Information System (INIS)

Menushenkov, A. P.; Chernikov, R. V.; Sidorov, V. V.; Klementiev, K. V.; Alekseev, P. A.; Rybina, A. V.

2007-01-01

The particular features of the local electronic and local crystal structures of the mixed-valence compound Sm 1-x Y x S are studied by the XAFS spectroscopy methods in the temperature range 20-300 K for the yttrium concentration x = 0.17, 0.25, 0.33, and 0.45. The temperature behavior of the valence of Sm, as well as of the lengths and the Debye-Waller factors of the bonds Sm-S, Sm-Sm(Y), Y-S, and Y-Sm(Y), has been determined. The violation of the Vegard law has been observed. A model for the estimation of the energy width of the 4f level and of its position with respect to the Fermi level is proposed

Conceptual Design Plan SM-43 Replacement Project

Energy Technology Data Exchange (ETDEWEB)

University of California, Los Alamos National Laboratory, SCC Project Office

2000-11-01

The Los Alamos National Laboratory Conceptual Design Plan for the SM-43 Replacement Project outlines plans for replacing the SM-43 Administration Building. Topics include the reasons that replacement is considered a necessity; the roles of the various project sponsors; and descriptions of the proposed site and facilities. Also covered in this proposal is preliminary information on the project schedule, cost estimates, acquisition strategy, risk assessment, NEPA strategy, safety strategy, and safeguards and security. Spreadsheets provide further detail on space requirements, project schedules, and cost estimates.

Color tunability of Sm{sup 3+} doped antimony–phosphate glass phosphors showing broadband fluorescence

Energy Technology Data Exchange (ETDEWEB)

Xiao, P. [School of Textile and Material Engineering, Dalian Polytechnic University, Dalian 116034 (China); Zhang, J.J., E-mail: zhangjj@dlpu.edu.cn [School of Textile and Material Engineering, Dalian Polytechnic University, Dalian 116034 (China); Shen, L.F. [Department of Electronic Engineering and State Key Laboratory of Millimeter Waves, City University of Hong Kong, Tat Chee Avenue, Kowloon, Hong Kong (China); Wang, Z.Q. [School of Textile and Material Engineering, Dalian Polytechnic University, Dalian 116034 (China); Pun, E.Y.B. [Department of Electronic Engineering and State Key Laboratory of Millimeter Waves, City University of Hong Kong, Tat Chee Avenue, Kowloon, Hong Kong (China); Lin, H., E-mail: lhai8686@yahoo.com [School of Textile and Material Engineering, Dalian Polytechnic University, Dalian 116034 (China); Department of Electronic Engineering and State Key Laboratory of Millimeter Waves, City University of Hong Kong, Tat Chee Avenue, Kowloon, Hong Kong (China)

2016-10-15

Sm{sup 3+} doped multicomponent antimony phosphate (MSP) luminescent glasses were prepared and tunable white fluorescence has been investigated. Broad visible emission depending on excitation wavelength is validated to be dominated by discrepant Sb{sup 3+} emitting centers. Group of narrow emissions from Sm{sup 3+} is beneficial to adding yellow and red components in Sm{sup 3+} doped MSP glasses, which is strengthened by effective energy transfer from Sb{sup 3+} to Sm{sup 3+}. Excitation wavelength selection and Sm{sup 3+} concentration adjustment are two feasible routes to optimize luminescence color in Sm{sup 3+} doped MSP glasses and the color tunability of fluorescence indicates that amorphous Sm{sup 3+} doped MSP glass phosphors possess potential for ideal white light devices.

Structural and magnetic properties of Fe{sub 2-x}CoSm{sub x}O{sub 4}-nanoparticles and Fe{sub 2-x}CoSm{sub x}O{sub 4}-PDMS magnetoelastomers as a function of Sm content

Energy Technology Data Exchange (ETDEWEB)

Ruiz, Mariano M.; Mietta, Jose L.; Soledad Antonel, P. [Instituto de Quimica Fisica de Materiales, Ambiente y Energia (INQUIMAE), Departamento de Quimica Inorganica, Analitica y Quimica Fisica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Av. Cantilo s/n (1428), Buenos Aires (Argentina); Perez, Oscar E. [Departamento de Industrias, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Av. Cantilo s/n (1428), Buenos Aires (Argentina); Martin Negri, R. [Instituto de Quimica Fisica de Materiales, Ambiente y Energia (INQUIMAE), Departamento de Quimica Inorganica, Analitica y Quimica Fisica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Av. Cantilo s/n (1428), Buenos Aires (Argentina); Jorge, Guillermo, E-mail: gjorge@df.uba.ar [Instituto de Fisica de Buenos Aires, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Av. Cantilo s/n (1428), Buenos Aires (Argentina); Instituto de Ciencias, Universidad Nacional de General Sarmiento, J.M. Gutierrez 1150 (1613), Los Polvorines, Buenos Aires (Argentina)

2013-02-15

We have synthesized magnetic Fe{sub 2-x}CoSm{sub x}O{sub 4} nanoparticles (NPs) by means of the coprecipitation method, varying Sm content from x=0 to x=0.5. Energy-dispersive X-ray spectroscopy showed agreement between the metal proportion of the obtained nanoparticles and the stoichiometric mixture of cations used for the synthesis. Part of the particles were heated at 800 Degree-Sign C, and both were characterized by X-ray diffraction, scanning electron microscope imaging and magnetization measurements. Physical and magnetic properties were analyzed as a function of Sm content, before and after the heating treatment. A phase segregation is found for the calcined nanoparticles with large Sm content. The magnetic remanence, saturation and coercive field were investigated as a function of Sm content for both heated and unheated (as-prepared) particles. Polydimethylsiloxane-NPs magnetoelastomers were prepared and cured under an external uniform magnetic field, obtaining structured anisotropic composites, in which inorganic needles (columnar micrometric structures) oriented in the direction of the magnetic field are formed. Young modulus and remanent magnetic moment were measured and magnetization time relaxation experiments were performed in the directions parallel and perpendicular to the needles in order to determine the magnetic and elastic anisotropy of the composites. The elastic modulus measured parallel to the needles resulted almost twice in magnitude with respect to the perpendicular modulus. The measured magnetic anisotropy of the composites is probably due to the enhanced interparticle interaction within a needle and the freezing of an preferred easy axis distribution among the particles at the curing process. - Highlights: Black-Right-Pointing-Pointer We study magnetic and physical properties of Sm-substituted Fe{sub 2}CoO{sub 4} nanoparticles. Black-Right-Pointing-Pointer Magnetic nanoparticles were synthesized by the coprecipitation method. Black

THE EFFECT OF THE WINDOW-TO-WALL RATIO ON COOLING ENERGY USAGE AND COMFORT TEMPERATURE

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Aris Budhiyanto

2017-12-01

Full Text Available This study presents an investigation of the effect of building envelope, especially glass facade buildings on cooling energy usage and thermal comfort. An office building was modeled with various window-to-wall ratio (WWR using panasap glass with SC=0.58 in order to analyze the effect of the WWR addition on cooling energy usage and comfort temperature. The result suggested that the average increase of the cooling energy usage is about 5.67% per 10% WWR addition, and of the operative temperature ranges from 0.350C to 0.560C per 10% WWR addition. Moreover, the building with above 20% WWR doesn’t provide comfort temperature.

The effect of Sm-doping on optical properties of LaB6 nanoparticles

International Nuclear Information System (INIS)

Chao, Luomeng; Bao, Lihong; Shi, Junjie; Wei, Wei; Tegus, O.; Zhang, Zhidong

2015-01-01

Highlights: • Nanoparticles of Sm-doped LaB 6 have been prepared by solid state reaction. • All samples exhibit high absorbance in NIR range and UV range. • The increase of Sm-doping amount shifts the position of minimum absorptance value. • The optical properties of Sm-doped LaB 6 were interpreted by DFT theory. - Abstract: Nanocrystalline particles of LaB 6 , SmB 6 and Sm-doped LaB 6 have been prepared by a solid-state reaction in order to investigate the optical properties of ternary rare-earth hexaborides. The sizes of prepared nanoparticles range from dozens to more than 200 nm, as confirmed by XRD, SEM and TEM examinations. The optical property concerning the absorption spectra was tested with ultraviolet-visible-near infrared (UV-vis-NIR) absorption spectrum. All samples exhibit high absorbance in NIR range and UV range. The increase of Sm-doping amount shifts the position of minimum absorptance value of LaB 6 to the long-wave direction. Density functional theory (DFT) is employed to interpret the optical properties of Sm-doped LaB 6 , and results indicate that Sm 4f states change the DOS at near Fermi surface of LaB 6 after Sm doping and the reduced number of conduction electrons results into the change of absorption spectra

Electrospinning fabrication and luminescent properties of SrMoO4:Sm3+ nanofibers

International Nuclear Information System (INIS)

Du Pingfan; Song Lixin; Xiong Jie; Cao Houbao; Xi Zhenqiang; Guo Shaoyi; Wang Naiyan; Chen Jianjun

2012-01-01

Highlights: ► SrMoO 4 :Sm 3+ fluorescent nanofibers were fabricated by electrospinning. ► The properties of the SrMoO 4 :Sm 3+ nanofibers were investigated. ► The obtained nanofibers exhibit a fine orange-red fluorescent property. ► The PL intensity of the nanofibers is superior to the nanoparticles counterpart. ► The optimum doping concentration of Sm 3+ in the host lattice is 2 at.%. - Abstract: Samarium ions doped strontium molybdate (SrMoO 4 :Sm 3+ ) nanofibers (NFs) were fabricated by a simple electrospinning process. The obtained SrMoO 4 :Sm 3+ NFs are composed of scheelite-type tetragonal SrMoO 4 phase, and the NFs have an average diameter of ca. 90 nm. Under 275 nm ultraviolet (UV) excitation, the NFs show an orange-red fluorescent property symbolized by a characteristic emission (606 nm) resulting from the 4 G 5/2 → 6 H 7/2 energy level transition of Sm 3+ . And the photoluminescence (PL) emissi on intensity of the SrMoO 4 :Sm 3+ NFs is superior to that of the nanoparticles (NPs) counterpart under the same doping concentrations. The effect of Sm 3+ concentrations on the 4 G 5/2 → 6 H 7/2 emission intensity was also investigated. The result reveals that the concentration quenching will occur when the Sm 3+ content exceeds 2 at.%. In other words, the SrMoO 4 :Sm 3+ NFs have an optimal luminescent performance under such a doping concentration.

Surface coating and magnetic properties of Sm2Fe17Nx materials

International Nuclear Information System (INIS)

Noguchi, K.; Machida, K.; Nishimura, M.; Adachi, G.

1998-01-01

Surface coating for finely ground Sm 2 Fe 17 N x (x=-3) powders (diameter 2 Fe 17 N x and (Zn,In)/Cu/Sm 2 Fe 17 N x , showed good oxidation-resistivity and thermal stability compared with the samples prepared without the Cu metal pre-coating, Zn/Sm 2 Fe 17 N x . The epoxy resin- or In metal-bonded magnets produced from the above coated powders, Zn/Cu/Sm 2 Fe 17 N x and (Zn,In)/Cu/Sm 2 Fe 17 N x , under warm molding conditions provided a flux loss of around -15% after standing in air at 120 C for 1000 h, but 30-40% for the conventional injection-type resin-bonded magnets prepared from Nd-Fe-B powders. (orig.)

Transcription Factor SmWRKY1 Positively Promotes the Biosynthesis of Tanshinones in Salvia miltiorrhiza

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Wenzhi Cao

2018-04-01

Full Text Available Tanshinones, one group of bioactive diterpenes, were widely used in the treatment of cardiovascular diseases. WRKYs play important roles in plant metabolism, but their regulation mechanism in Salvia miltiorrhiza remains elusive. In this study, one WRKY transcription factor SmWRKY1 was isolated and functionally characterized from S. miltiorrhiza. Multiple sequence alignment and phylogenetic tree analysis showed SmWRKY1 shared high homology with other plant WRKYs such as CrWRKY1. SmWRKY1 was found predominantly expressed in leaves and stems, and was responsive to salicylic acid (SA, methyl jasmonate (MeJA, and nitric oxide (NO treatment. Subcellular localization analysis found that SmWRKY1 was localized in the nucleus. Over-expression of SmWRKY1 significantly elevated the transcripts of genes coding for enzymes in the MEP pathway especially 1-deoxy-D-xylulose-5-phosphate synthase (SmDXS and 1-deoxy-D-xylulose-5-phosphate reductoisomerase (SmDXR, resulted in over fivefold increase in tanshinones production in transgenic lines (up to 13.7 mg/g DW compared with the control lines. A dual-luciferase (Dual-LUC assay showed that SmWRKY1 can positively regulate SmDXR expression by binding to its promoter. Our work revealed that SmWRKY1 participated in the regulation of tanshinones biosynthesis and acted as a positive regulator through activating SmDXR in the MEP pathway, thus provided a new insight to further explore the regulation mechanism of tanshinones biosynthesis.

Investigation of the oxidative processes in intermetallic Sm Co5 powder during heat treatment

International Nuclear Information System (INIS)

Talijan, Nadezda M.; Milutinovic-Nikolic, Aleksandra; Stajic-Trosic, Jasna T.; Jovanovic, Zarko D.

1996-01-01

Understanding of the thermal stability of intermetallic Sm Co 5 powder is essential for designing the working atmosphere in all phases of the technological procedure in the production of sintered Sm Co 5 magnets to obtain maximal magnetic properties. The thermal stability of the Sm Co 5 powder with defined chemical composition and particle size was investigated in the interval from 20 to 900 deg C. Commercial Sm Co 5 powder was used in this experiment. The powder was milled in anhydrous toluene in an agate mortar to fine powder of quality used in the production of sintered magnets. All the experiments were carried out with powder of an average particle size of 7.23μm, established by SEM. THe thermal stability of the Sm Co 5 powder in static air atmosphere was investigated by thermogravimetric analysis (TGA) using a DuPont Thermal Analyzer. Investigation of the behaviour of Sm Co 5 powder during heating was carried out using new samples of Sm Co 5 powder for each of the investigated temperature cycles. It was found by TGA that up to 200 deg C, the oxidation of Sm Co 5 was negligible. X-ray diffraction of the thermogravimetric experimental residue of the Sm Co 5 powder, heated at 240 deg C, yielded only the presence of the Sm Co 5 phase. By X-ray diffraction different crystal forms were identified depending on the maximal heating temperature. The following phases were identified: Sm 2 O 3 , Co, Co O, Co 3 O 4 and Sm Co O 3 . According to TG and X-ray results, for each of the investigated temperatures, the corresponding chemical reactions were established. The experimental data from both the thermal and X-ray investigations confirm that the phases of pressing and aligning the Sm Co 5 powder, in the process of producing sintered Sm Co 5 magnets, may be performed without a protective atmosphere. (author)

The biodistribution and kinetics of the 153Sm labelled avidin, streptavidin and biotin

International Nuclear Information System (INIS)

Li Guiping; Zhu Chengmo; Jiang Xufeng; Feng Guowei; Zhang Shengguo

1999-01-01

Due to the high affinity of biotin to Av or SA. The authors labelled a biotin derivative (DTPA-biotin) with 153 Sm and then bound this 153 Sm labelled DTPA-biotin to Av or SA. The in vivo kinetics and biodistribution of 153 Sm labelled Av, SA and DTPA-biotin were studied in the rat and mice. The results demonstrated that 153 Sm-Av cleared from the blood rapidly with high liver and renal uptake; 153 Sm-SA cleared from blood slowly with high retention in liver, spleen and kidney, whereas 153 Sm metabolize more fast, and excreted mainly through the kidney. Thereby, the biodistribution difference of SA and Av mentioned above provided an experimental basis for the selection of different components of A-V system in pre-targeting radio-immuno imaging and radioimmunotherapy

The microwave absorbing properties of SmCo attached single wall carbon nanotube/epoxy composites

International Nuclear Information System (INIS)

Yu, Liming; Li, Bo; Sheng, Leimei; An, Kang; Zhao, Xinluo

2013-01-01

Highlights: •The SmCo nanoparticles attached SWCNTs were prepared by dc arc discharge method. •The nano-composite prepared by a rare earth permanent magnet Sm 2 Co 17 as catalyst. •The SmCo attached SWCNT/epoxy composites have an excellent electromagnetic matching characteristics. •The reflection loss and bandwidth below −20 dB of the composite can reach −23.7 dB, 6.2 GHz, respectively. -- Abstract: The SmCo nanoparticles attached single wall carbon nanotubes (SmCo attached SWCNTs) were prepared by hydrogen dc arc discharge method using 2:17 type SmCo permanent powder as catalyst. The SmCo attached SWCNT/epoxy composites with different doping ratios were investigated in the frequency region of 2–18 GHz. The complex permittivity and permeability of the SmCo attached SWCNT/epoxy composites were calculated. The reflection loss properties were simulated by transmission line theory and the microwave absorptive mechanisms were discussed. The results indicate that, due to the better interfacial polarization absorption mechanism of SmCo attached SWCNTs and the electromagnetic (EM) matching of magnetic loss and dielectric loss, the microwave absorption properties of SmCo attached SWCNT/epoxy are evidently improved. When the SmCo attached SWCNTs is doped by 1 wt%, the composite display a larger and wider absorption peak, and the bandwidth of the reflection loss below −20 dB is larger than 6 GHz with the thickness of 3.3 mm. It is expected that the new SmCo attached SWCNT/epoxy composites will be a good microwave absorbing material for the applications in X band, Ku band, or even K band

Sm 3+-doped polymer optical waveguide amplifiers

Science.gov (United States)

Huang, Lihui; Tsang, Kwokchu; Pun, Edwin Yue-Bun; Xu, Shiqing

2010-04-01

Trivalent samarium ion (Sm 3+) doped SU8 polymer materials were synthesized and characterized. Intense red emission at 645 nm was observed under UV laser light excitation. Spectroscopic investigations show that the doped materials are suitable for realizing planar optical waveguide amplifiers. About 100 μm wide multimode Sm 3+-doped SU8 channel waveguides were fabricated using a simple UV exposure process. At 250 mW, 351 nm UV pump power, a signal enhancement of ˜7.4 dB at 645 nm was obtained for a 15 mm long channel waveguide.

Germinal Center Kinases SmKIN3 and SmKIN24 Are Associated with the Sordaria macrospora Striatin-Interacting Phosphatase and Kinase (STRIPAK) Complex.

Science.gov (United States)

Frey, Stefan; Reschka, Eva J; Pöggeler, Stefanie

2015-01-01

The striatin-interacting phosphatase and kinase (STRIPAK) complex is composed of striatin, protein phosphatase PP2A and protein kinases that regulate development in animals and fungi. In the filamentous ascomycete Sordaria macrospora, it is required for fruiting-body development and cell fusion. Here, we report on the presence and function of STRIPAK-associated kinases in ascomycetes. Using the mammalian germinal center kinases (GCKs) MST4, STK24, STK25 and MINK1 as query, we identified the two putative homologs SmKIN3 and SmKIN24 in S. macrospora. A BLASTP search revealed that both kinases are conserved among filamentous ascomycetes. The physical interaction of the striatin homolog PRO11 with SmKIN3 and SmKIN24 were verified by yeast two-hybrid (Y2H) interaction studies and for SmKIN3 by co-Immunoprecipitation (co-IP). In vivo localization found that both kinases were present at the septa and deletion of both Smkin3 and Smkin24 led to abnormal septum distribution. While deletion of Smkin3 caused larger distances between adjacent septa and increased aerial hyphae, deletion of Smkin24 led to closer spacing of septa and to sterility. Although phenotypically distinct, both kinases appear to function independently because the double-knockout strain ΔSmkin3/ΔSmkin24 displayed the combined phenotypes of each single-deletion strain.

Germinal Center Kinases SmKIN3 and SmKIN24 Are Associated with the Sordaria macrospora Striatin-Interacting Phosphatase and Kinase (STRIPAK Complex.

Directory of Open Access Journals (Sweden)

Stefan Frey

Full Text Available The striatin-interacting phosphatase and kinase (STRIPAK complex is composed of striatin, protein phosphatase PP2A and protein kinases that regulate development in animals and fungi. In the filamentous ascomycete Sordaria macrospora, it is required for fruiting-body development and cell fusion. Here, we report on the presence and function of STRIPAK-associated kinases in ascomycetes. Using the mammalian germinal center kinases (GCKs MST4, STK24, STK25 and MINK1 as query, we identified the two putative homologs SmKIN3 and SmKIN24 in S. macrospora. A BLASTP search revealed that both kinases are conserved among filamentous ascomycetes. The physical interaction of the striatin homolog PRO11 with SmKIN3 and SmKIN24 were verified by yeast two-hybrid (Y2H interaction studies and for SmKIN3 by co-Immunoprecipitation (co-IP. In vivo localization found that both kinases were present at the septa and deletion of both Smkin3 and Smkin24 led to abnormal septum distribution. While deletion of Smkin3 caused larger distances between adjacent septa and increased aerial hyphae, deletion of Smkin24 led to closer spacing of septa and to sterility. Although phenotypically distinct, both kinases appear to function independently because the double-knockout strain ΔSmkin3/ΔSmkin24 displayed the combined phenotypes of each single-deletion strain.

Interaction mode between methylene blue-Sm(III) complex and ...

African Journals Online (AJOL)

Spectroscopic and viscosity methods were applied to investigate the interaction between methylene blue (MB)-Sm(III) complex and herring sperm DNA by using acridine orange as a spectral probe in Tris-HCl buffer (pH 7.40). By means of molar ratio method, the binding ratios between MB-Sm(III)and DNA were determined ...

Coilin phosphorylation mediates interaction with SMN and SmB′

Science.gov (United States)

Toyota, Cory G.; Davis, Misty D.; Cosman, Angela M.; Hebert, Michael D.

2010-01-01

Cajal bodies (CBs) are subnuclear domains that participate in spliceosomal small nuclear ribonucleoprotein (snRNP) biogenesis and play a part in the assembly of the spliceosomal complex. The CB marker protein, coilin, interacts with survival of motor neuron (SMN) and Sm proteins. Several coilin phosphoresidues have been identified by mass spectrometric analysis. Phosphorylation of coilin affects its self-interaction and localization in the nucleus. We hypothesize that coilin phosphorylation also impacts its binding to SMN and Sm proteins. In vitro binding studies with a C-terminal fragment of coilin and corresponding phosphomimics show that SMN binds preferentially to dephosphorylated analogs and that SmB′ binds preferentially to phosphomimetic constructs. Bacterially expressed full-length coilin binds more SMN and SmB′ than does the C-terminal fragment. Co-immunoprecipitation and phosphatase experiments show that SMN also binds dephosphorylated coilin in vivo. These data show that phosphorylation of coilin influences interaction with its target proteins and, thus, may be significant in managing the flow of snRNPs through the CB. PMID:19997741

Coilin phosphorylation mediates interaction with SMN and SmB'.

Science.gov (United States)

Toyota, Cory G; Davis, Misty D; Cosman, Angela M; Hebert, Michael D

2010-04-01

Cajal bodies (CBs) are subnuclear domains that participate in spliceosomal small nuclear ribonucleoprotein (snRNP) biogenesis and play a part in the assembly of the spliceosomal complex. The CB marker protein, coilin, interacts with survival of motor neuron (SMN) and Sm proteins. Several coilin phosphoresidues have been identified by mass spectrometric analysis. Phosphorylation of coilin affects its self-interaction and localization in the nucleus. We hypothesize that coilin phosphorylation also impacts its binding to SMN and Sm proteins. In vitro binding studies with a C-terminal fragment of coilin and corresponding phosphomimics show that SMN binds preferentially to dephosphorylated analogs and that SmB' binds preferentially to phosphomimetic constructs. Bacterially expressed full-length coilin binds more SMN and SmB' than does the C-terminal fragment. Co-immunoprecipitation and phosphatase experiments show that SMN also binds dephosphorylated coilin in vivo. These data show that phosphorylation of coilin influences interaction with its target proteins and, thus, may be significant in managing the flow of snRNPs through the CB.

Dilatometric and dielectric behaviour of Sm modified PCT ceramics

International Nuclear Information System (INIS)

Singh, Sarabjit; Thakur, O.P.; Prakash, Chandra; Raina, K.K.

2005-01-01

Samarium modified PCT ceramics with composition (Pb 0.76-x Sm x Ca 0.24 )(Ti 0.98 Mn 0.02 )O 3 ; x=0-0.08 in steps of 0.02 were prepared by conventional mixed-oxide method. Detailed dilatometric studies were carried out for green specimens in order to study sintering behaviour. Change in the dilatometric behaviour is correlated with the XRD results of powders calcined at different temperatures. Dielectric constant was observed to increase with increasing Sm concentration, which has been attributed to reduced tetragonality and better densification on Sm substitution. SEM micrographs have revealed the grain size of the samples. Ferroelectric hysteresis behaviour was studied for all the compositions

Angle-resolved photoemission investigation of SmB{sub 6}

Energy Technology Data Exchange (ETDEWEB)

Hlawenka, Peter; Rader, Oliver; Siemensmeyer, Konrad; Weschke, Eugen; Varykhalov, Andrei; Rienks, Emile [Helmholtz-Zentrum Berlin (Germany); Shitsevalova, Natalya [Institute for Problems of Material Science, Kiev (Ukraine); Gabani, Slavomir; Flachbart, Karol [IEP, Slovak Academy of Science, Kosice (Slovakia)

2015-07-01

Recently the mixed valence compound SmB{sub 6} has drawn great attention. Theoretically predicted surface states, which should result from a hybridisation of localised f-bands with conduction electrons and a band inversion, would make SmB{sub 6} the first realisation of a so called topological Kondo insulator. Conductivity and transport measurements, as well as spin-resolved photoemission spectroscopy seem to fortify the scenario of a topological nature of the conductive surface. We investigate the surface electronic structure of SmB{sub 6} by means of high resolution angle-resolved photoemission spectroscopy measurements below 1 K. We will present new insights into the surface states that determine the low temperature conductivity of this material.

Labelling of MoAb with 153SmH1ETA: Preliminary results

International Nuclear Information System (INIS)

Ferro-Flores, G.; De, F.; Ramirez, M.; Pedraza-Lopez, M.; Tendilla, J.I.; Melendez-Alafort, L.; Murphy, C.A.

2001-01-01

A method to label MoAb with Sm-153 using 1,5,9,13-tetraazacyclohexadecane N,N',N'',N''' tetraacetic acid (H 4 ETA) as a bifunctional chelator was developed. H 4 ETA and SmH 1 ETA were synthesized in our laboratory and characterized by IR spectroscopy, TGA (thermogravimetric analysis), SEM (Scattering Electronic Microscopy), EDAX (Elemental Dispersion Analysis by X-rays) and EPR (Electron Paramagnetic Resonance) at 6 K. The 153 SmH 1 ETAMoAb was prepared by a simple incubation of the MoAb ior cea1, and the 153 SmH 1 ETA complex at neutral pH and at room temperature for 24 h. The specific activity of the labelled antibody was 111 MBq/mg (3 mCi/mg). Sm-153(III) is commercially available with specific activities up to 318.2 GBq/mg. Therefore, under the conditions described above 153 SmH 1 ETA labelled MoAb could be obtained with specific activity up to 1.14 GBq/mg (30.7 mCi/mg). (author)

Symmetries for SM Alignment in multi-Higgs Doublet Models

CERN Document Server

Pilaftsis, Apostolos

2016-01-01

We derive the complete set of maximal symmetries for Standard Model (SM) alignment that may occur in the tree-level scalar potential of multi-Higgs Doublet Models, with $n > 2$ Higgs doublets. Our results generalize the symmetries of SM alignment, without decoupling of large mass scales or fine-tuning, previously obtained in the context of two-Higgs Doublet Models.

Decommissioning of the research nuclear reactor WWR-S Magurele - Bucharest. General presentation of the project

International Nuclear Information System (INIS)

Dragulescu, Emilian; Dragusin, Mitica; Popa, Victor; Boicu, Alin; Tuca, Carmen; Iorga, Ioan; Vrabie, Ionut; Mustata, Carmen

2003-01-01

A decommissioning project was worked out concerning the nuclear facility research reactor WWR-S Magurele-Bucharest to remove the radioactive and hazardous materials and so to exclude any risk for human health and environment. The project involves the four phases named assessment, development, operations and closeout. There are two major parts to the assesment phase: preliminary characterisation and the review and decision-making process. Characterisation is needed to develop project baseline data, which should include sufficient chemical, physical, and radiological characterisation to meet planning needs. Based on the conclusions of these studies, possible decommissioning alternative will be analyzed and: the best alternative chosen, final goal identified, risk assessments are evaluated. Also, taken into account are: regulations supporting assessment, land use considerations, financial concerns, disposal availability, public involvement, technology developments. After a decommissioning alternative was chosen, detailed engineering will begin following appropriate regulatory guidance. The plan will include characterisation information, namely: review of decommissioning alternatives; justification for the selected alternative; provision for regulatory compliance; predictions of personnel exposure, radioactive waste volume, and cost. Other activities are: scheduling, preparation for decommissioning operations; coordination, documentation, characterization report, feasibility studies, Decommissioning Plan, project daily report, radiological survey, airborne sampling records, termination survey of the site. The operations imply: identification and sequencing the operations on contaminated materials, storing on site the wastes, awaiting processing or disposal, and packaging of materials for transport to processing or disposal facilities.The key operations are: worker protection, health and safety program, review of planing work, work area assessment, work area controls

The constitution of alloys in the Al-rich corner of the Al-Si-Sm ternary system

International Nuclear Information System (INIS)

Markoli, B.; Spaic, S.; Zupanic, F.

2001-01-01

The constitution of alloys and the liquidus surface in the Al-rich corner of the Al-Si-Sm ternary system were determined by the examination of controlled heated and cooled specimens, as well as heat-treated specimens by means of optical and scanning electron microscopy, energy-dispersive X-ray spectroscopy, differential thermal analysis and X-ray diffraction. The Al-rich corner of the Al-Si-Sm ternary system comprises five regions of primary crystallisation (α Al , β Si , Al 3 Sm, Al 2 Si 2 Sm and AlSiSm) with following characteristic invariant reaction sequences: ternary eutectic reaction L → α Al + β Si + Al 2 Si 2 Sm, and two liquidus transition reactions, i. e., L + Al 3 Sm → α Al + AlSiSm, and L + AlSiSm → α Al + Al 2 Si 2 Sm. Along with the position of ternary eutectic and both interstitial points in the Al-rich corner of the Al-Si-Sm ternary system, the temperatures for each reaction were determined. (orig.)

Facile synthesis of Sm-doped BiFeO{sub 3} nanoparticles for enhanced visible light photocatalytic performance

Energy Technology Data Exchange (ETDEWEB)

Hu, Zijun; Chen, Da, E-mail: dchen_80@hotmail.com; Wang, Sen; Zhang, Ning; Qin, Laishun, E-mail: qinlaishun@cjlu.edu.cn; Huang, Yuexiang

2017-06-15

Highlights: • Effective Sm doping into BiFeO{sub 3} nanoparticles was obtained by a facile sol-gel route. • Band gap of Sm-doped BiFeO{sub 3} nanoparticles was regulated by the dopant concentration. • Sm-doped BiFeO{sub 3} nanoparticles exhibited superior photocatalytic activities. • The possible photocatalytic mechanism of Sm-doped BiFeO{sub 3} nanospheres was discussed. - Abstract: In this work, the effect of Sm doping on the structural and photocatalytic properties of BiFeO{sub 3} (BFO) was investigated. A series of Sm doped BFO nanoparticles containing different Sm dopant contents (Bi{sub (1−x)}Sm{sub x}FeO{sub 3}, x = 0.00, 0.01, 0.03, 0.05, 0.07, 0.10) were synthesized via a simple sol-gel route. It was revealed that Sm{sup 3+} ions were successfully doped into BFO nanoparticles, and the band gap value was gradually decreased when increasing Sm dopant concentration. The photocatalytic activity of Sm-doped BFO photocatalyst was significantly affected by the Sm doping content. Compared to pure BFO, the Sm-doped BFO samples exhibited much higher photocatalytic activity. The improved photocatalytic activity of Sm-doped BFO could be attributed to the enhanced visible light absorption and the efficient separation of photogenerated electrons and holes derived from Sm dopant trapping level in the Sm-doped BFO samples. In addition, the possible photocatalytic mechanism of Sm-doped BFO photocatalyst was also proposed.

Lifetime measurements of the excited states in {sup 145} Sm

Energy Technology Data Exchange (ETDEWEB)

El-Badry, A M; Abdel Samie, Sh; Ahmad, A A [Depatment of Physics, Faculty of Science, ElMinia University, ElMinia, (Egypt); Kuroyanagi, T; Odahara, A; Gono, Y; Morinobu, S [Tandem Accelerator Laboratory, Department of Physics, Kyushu University, (Japan)

1997-12-31

Lifetime of the excited levels in {sup 145} Sm has been measured through the {sup 139} La ({sup 10} B, 4 n){sup 145} Sm nuclear reaction. The optimal beam energy of 49 MeV was determined from the measurements of the excitation function and Cascade program. With the possibility of studying lifetime of this nucleus a conventional plunger system have been designed and constructed at kyushu University tandem accelerator laboratory. A La target of 0.22 mg/cm{sup 2} thickness which was evaporated onto a Au foil of 2 mg/cm{sup 2} thickness was used. Since the recoil velocity was estimated to be 1.76 mm/ns (beta 0.00585), the measurable time range resulted in the range from 5 Ps to 5 ns. The single spectra measurements were performed at the 20 plunger positions in the range from 10 {mu} to 10 mm. Analyses of the data were carried using hypermet and/or GF2 program to obtain the lifetimes. A new list of lifetimes for 12 excited states up to 3.922 MeV excitations for {sup 145} Sm were determined for the first time. Decay curves of the these transitions are discussed. The new lifetimes of excited states in {sup 145} Sm enabled us to understand the electromagnetic properties. The deduced transition probabilities were established and compared with that of N = 83 isotones and the closed shell nucleus {sup 144} Sm. In addition, a nuclear structure of {sup 145} Sm have been discussed and proposed in framework of the shell model. 4 figs., 1 tab.

SM*A*S*H (Standard Model*Axion*Seesaw*Higgs portal inflation)

International Nuclear Information System (INIS)

Ringwald, Andreas

2016-10-01

We present a minimal model for particle physics and cosmology. The Standard Model (SM) particle content is extended by three right-handed SM-singlet neutrinos N_i and a vector-like quark Q, all of them being charged under a global lepton number and Peccei-Quinn (PQ) U(1) symmetry which is spontaneously broken by the vacuum expectation value υ_σ∝10"1"1 GeV of a SM-singlet complex scalar field σ. Five fundamental problems - neutrino oscillations, baryogenesis, dark matter, inflation, strong CP problem - are solved at one stroke in this model, dubbed ''SM*A*S*H'' (Standard Model*Axion*Seesaw*Higgs portal inflation). It can be probed decisively by upcoming cosmic microwave background and axion dark matter experiments.

Temperature measurement of the reactor materials samples irradiated in the fuel channels of the RA reactor - Annex 16; Prilog 16 - Merenje temperature uzoraka reaktorskih materijala ozracivanih u gorivnim kanalima reaktora RA

Energy Technology Data Exchange (ETDEWEB)

Nikolic, M; Djalovic, M [Institute of Nuclear Sciences Boris Kidric, Reaktor RA, Vinca, Beograd (Serbia and Montenegro)

1964-12-15

Reactor materials as graphite, stainless steel, magnox, zirconium alloys, etc. were exposed to fast neutron flux inside the fuel elements specially adapted for this purpose. Samples in the form ampoules were placed in capsules inside the fuel channels and cooled by heavy water which cools the fuel elements. In order to monitor the samples temperature 42 thermocouples were placed in the samples. That was necessary for reactor safety reasons and for further interpretation of measured results. Temperature monitoring was done continuously by multichannel milivoltmeters. This paper describes the technique of introducing the thermocouples, compensation instruments, control of the cold ends and adaptation of the instruments for precision (0.5%) temperature measurement in the range 30 deg - 130 deg C; 30 deg - 280 deg C and 30 deg - 80 deg C. Ozracivanje uzoraka materijala za izgradnju reaktora kao sto su grafit, nerdjajuci celik, magnox, legure cirkonijuma, aluminijuma itd. vrseno je u fluksu brzih neutrona unutar samih gorivnih elemenata koji su specijalno adaptirani za ovu svrhu. Uzorci u vidu ampula smesteni su u kapsulu od aluminijuma i postavljeni unutar kanala gde su hladjeni cirkulacijom teske vode koja hladi same gorivne elemente. U cilju kontrole temperature uzoraka radi bezbednosti samog reaktora, kao i radi kasnije interpretacije rezultata ispitivanja radijacionog ostecenja materijala, ugradjeno je 42 termopara u uzorke. Kontrola temperature je vrsena kontinualno visekanalnim registratorima. U radu je prikazana tehnika izvodjenja termoparova, kompenzacionih vodova, kontrola hladnih krajeva i prilagodjenje instrumentacije za merenje i registraciju temperature sa tacnoscu 0,5% u opsezima 30 deg - 130 deg C; 30 deg - 280 deg C i 30 deg - 80 deg C (author)

Tuning the Magnetic Properties and Structural Stabilities of the 2-17-3 Magnets Sm2Fe17X3 (X =C , N) by Substituting La or Ce for Sm

Science.gov (United States)

Pandey, Tribhuwan; Du, Mao-Hua; Parker, David S.

2018-03-01

Designing a permanent magnet with reduced critical rare-earth content is of paramount importance in the development of cost-effective modern technologies. By performing comprehensive first-principles calculations, we investigate the potential avenues for reducing the critical rare-earth content in Sm2Fe17N3 and Sm2Fe17C3 by making a La or Ce substitution for Sm. The calculated magnetic properties of base compounds are in good agreement with the previous low-temperature (4.2-K) experimental measurements, and they show a large axial anisotropy. Although La or Ce substitution results in a slight reduction of magnetic anisotropy, the magnetic moments of Fe atoms mostly remain unchanged. Specifically, large axial anisotropies of 7.2 and 4.1 MJ /m3 are obtained for SmCeFe17 N3 and SmLaFe17 N3 , respectively. These values of anisotropies are comparable to the state-of-the-art permanent magnet Nd2 Fe14 B . The foremost limitation of Sm2 Fe17X3 magnets for practical application is the formation nitrogen or carbon vacancies at high temperatures. By calculating the N- (C)- vacancy formation energy, we show that La or Ce substitution enhances the vacancy formation energy. This enhanced vacancy formation energy will likely improve the thermodynamic stability of these alloys at high temperatures. Therefore, La- or Ce-substituted Sm2Fe17C3 and Sm2Fe17N3 compounds are promising candidates for high-performance permanent magnets with substantially reduced rare-earth content.

Propagation of Nd magnetic phases in Nd/Sm(001) superlattices

International Nuclear Information System (INIS)

Soriano, S; Dufour, C; Dumesnil, K; Stunault, A

2006-01-01

The propagation of Nd long range magnetic order in the hexagonal and cubic sublattices has been investigated in double hexagonal compact Nd/Sm(001) superlattices by resonant x-ray magnetic scattering at the Nd L 2 absorption edge. For a superlattice with 3.7 nm thick Sm layers, the magnetic structure of the hexagonal sublattice propagates coherently through several bilayers, whereas the order in the cubic sublattice remains confined to single Nd blocks. For a superlattice with 1.4 nm thick Sm layers, the magnetic structures of both sublattices appear to propagate coherently through the superlattice. This is the first observation (i) of the long range coherent propagation of Nd order on the cubic sites between Nd blocks and (ii) of a different thickness dependence of the propagation of the Nd magnetic phases associated with the hexagonal and cubic sublattices. The propagation of the Nd magnetic order through Sm is interpreted in terms of generalized susceptibility of the Nd conduction electrons

The simultaneous mass and energy evaporation (SM2E) model.

Science.gov (United States)

Choudhary, Rehan; Klauda, Jeffery B

2016-01-01

In this article, the Simultaneous Mass and Energy Evaporation (SM2E) model is presented. The SM2E model is based on theoretical models for mass and energy transfer. The theoretical models systematically under or over predicted at various flow conditions: laminar, transition, and turbulent. These models were harmonized with experimental measurements to eliminate systematic under or over predictions; a total of 113 measured evaporation rates were used. The SM2E model can be used to estimate evaporation rates for pure liquids as well as liquid mixtures at laminar, transition, and turbulent flow conditions. However, due to limited availability of evaporation data, the model has so far only been tested against data for pure liquids and binary mixtures. The model can take evaporative cooling into account and when the temperature of the evaporating liquid or liquid mixture is known (e.g., isothermal evaporation), the SM2E model reduces to a mass transfer-only model.

X-ray induced Sm{sup 3+} to Sm{sup 2+} conversion in fluorophosphate and fluoroaluminate glasses for the monitoring of high-doses in microbeam radiation therapy

Energy Technology Data Exchange (ETDEWEB)

Vahedi, Shahrzad; Okada, Go; Morrell, Brian; Muzar, Edward; Koughia, Cyril; Kasap, Safa [Department of Electrical and Computer Engineering, University of Saskatchewan, Saskatoon, Saskatchewan S7N 5A9 (Canada); Edgar, Andy; Varoy, Chris [School of Chemical and Physical Sciences and MacDiarmid Institute, Victoria University of Wellington, Kelburn Parade (New Zealand); Belev, George; Wysokinski, Tomasz [Canadian Light Source, Inc., University of Saskatchewan, Saskatoon, Saskatchewan S7N 0X4 (Canada); Chapman, Dean [Department of Anatomy and Cell Biology, University of Saskatchewan, Saskatoon, Saskatchewan S7N 5E5 (Canada)

2012-10-01

Fluorophosphate and fluoroaluminate glasses doped with trivalent samarium were evaluated as sensors of x-ray radiation for microbeam radiation therapy at the Canadian Light Source using the conversion of trivalent Sm{sup 3+} to the divalent form Sm{sup 2+}. Both types of glasses show similar conversion rates and may be used as a linear sensor up to {approx}150 Gy and as a nonlinear sensor up to {approx}2400 Gy, where saturation is reached. Experiments with a multi-slit collimator show high spatial resolution of the conversion pattern; the pattern was acquired by a confocal fluorescence microscopy technique. The effects of previous x-ray exposure may be erased by annealing at temperatures exceeding the glass transition temperature T{sub g} while annealing at T{sub A} < T{sub g} enhances the Sm conversion. This enhancement is explained by a thermally stimulated relaxation of host glass ionic matrix surrounding x-ray induced Sm{sup 2+} ions. In addition, some of the Sm{sup 3+}-doped glasses were codoped with Eu{sup 2+}-ions but the results show that there is no marked improvement in the conversion efficiency by the introduction of Eu{sup 2+}.

The constitution of alloys in the Al-rich corner of the Al-Si-Sm ternary system

Energy Technology Data Exchange (ETDEWEB)

Markoli, B.; Spaic, S. [Ljubljana Univ. (Slovenia). Faculty of Natural Science and Engineering; Zupanic, F. [Maribor Univ. (Slovenia). Faculty of Mechanical Engineering

2001-09-01

The constitution of alloys and the liquidus surface in the Al-rich corner of the Al-Si-Sm ternary system were determined by the examination of controlled heated and cooled specimens, as well as heat-treated specimens by means of optical and scanning electron microscopy, energy-dispersive X-ray spectroscopy, differential thermal analysis and X-ray diffraction. The Al-rich corner of the Al-Si-Sm ternary system comprises five regions of primary crystallisation ({alpha}{sub Al}, {beta}{sub Si}, Al{sub 3}Sm, Al{sub 2}Si{sub 2}Sm and AlSiSm) with following characteristic invariant reaction sequences: ternary eutectic reaction L {yields} {alpha}{sub Al} + {beta}{sub Si} + Al{sub 2}Si{sub 2}Sm, and two liquidus transition reactions, i. e., L + Al{sub 3}Sm {yields} {alpha}{sub Al} + AlSiSm, and L + AlSiSm {yields} {alpha}{sub Al} + Al{sub 2}Si{sub 2}Sm. Along with the position of ternary eutectic and both interstitial points in the Al-rich corner of the Al-Si-Sm ternary system, the temperatures for each reaction were determined. (orig.)

In vivo efficacy of SM-8668 (Sch 39304), a new oral triazole antifungal agent.

Science.gov (United States)

Tanio, T; Ichise, K; Nakajima, T; Okuda, T

1990-06-01

SM-8668 (Sch 39304) is a new oral antifungal agent which we evaluated in comparison with fluconazole in various fungal infection models. The prophylactic effect of SM-8668 was excellent against systemic candidiasis, aspergillosis, and cryptococcosis in mice. The 50% effective dose for SM-8668 was assessed at 10 days after infection and was 0.18, 3.7, and 5.9 mg/kg (body weight), respectively, for the above-mentioned fungal diseases. Fluconazole was about four times less effective than SM-8668 against systemic candidiasis and was only slightly effective at doses of 80 and 25 mg/kg against systemic aspergilosis and cryptococcosis, respectively. SM-8668 was also about four to eight times more active than fluconazole against vaginal candidiasis in rats and against dermatophytic infection in guinea pigs. In addition, topical SM-8668 was as effective as topical miconazole or tioconazole against skin mycosis in guinea pigs. After oral administration, SM-8668 showed a maximum concentration in serum similar to that of fluconazole in both mice and rats, but the elimination half-life and area under the serum concentration-time curve for SM-8668 were twice those for fluconazole.

Combustion synthesis of micron-sized Sm2Co17 particles via mechanochemical processing

International Nuclear Information System (INIS)

Liu, W.; McCormick, P.G.

1998-01-01

Full text: The spontaneous formation of Sm 2 Co 17 micron-sized particles via a mechanically induced combustion reaction has been investigated. Sm 2 Co 17 alloy particles of 0.1--2 μm in size embedded in a CaO matrix formed directly via a combustion reaction induced by milling the powder mixture of Sm 2 O 3 , CoO, CaO and Ca over a critical time. The micron-sized Sm 2 Co 17 particles were found to have the TbCu 7 -type structure and characterized by a coercivity value of 7.8 kOe while embedded in the CaO matrix. The effect of subsequent heat treatment on the structure and magnetic properties of as-milled samples was also investigated. Removal of the CaO by a carefully controlled washing process yielded micron-sized Sm 2 Co 17 particles without significant oxidation of the particles. These fine Sm 2 Co 17 particles can be used to produce anisotropic bulk or bonded magnets

Radiation protection at the RA Reactor in 1997, Part -2, Annex 1, Control of the working environment, dosimetry and radiation protection; Prilog 1 - Zastita od zracenja kod reaktora RA u 1997. godini - Deo 2 - Kontrola radne sredine - dozimetrija i tehnicka zastita kod reaktora RA

Energy Technology Data Exchange (ETDEWEB)

Pavlovic, R; Kalinic, S [Vinca Institute of Nuclear Sciences, Beograd (Serbia and Montenegro)

1997-12-01

This report contains data and analysis of the of measured sample results collected during radiation protection control in the working environment of the RA reactor. First part contains basic exposure values and statistical review of the the total number of radiation measurements. It includes contents of radioactive gasses and effluents in the air, as well as the level of surface contamination of clothes and uncovered parts of the personnel bodies. Second part deals with the analysis of personnel doses. Third part of this annex contains basic data about the quantity of collected radioactive waste, total quantity of contaminated and decontaminated surfaces. Previously initiated actions concerning future decision on the status of the RA reactor were continued during 1997. Actions in 1997 were focused to detailed analysis of the conditions of storing the spent fuel in the storage pools and preparing the documentation for decision making about the methods for the improvement of the mentioned conditions. After adopting the procedures, detailed preparations, and purchasing the needed equipment, the first phase of remedial action, the removal of the sludge from the bottom of the spent fuel storage pool was started in September 1997. It is stated that there have been no accidents that could cause significant contamination of working surfaces and components nor radiation exposure of the personnel. [Serbo-Croat] U ovom izvestaju prikazani su i analizirani reprezentativni rezultati sakupljeni u okviru kontrole radne sredine i tehnicke zastite od zracenja reaktora RA. U prvom delu izvestaja izlozeni su podaci o osnovnim vidovima izlaganja zracenju i statisticki pregled ukupnog broja radiacionih merenja. Dati su takodje rezultati merenja sadrzaja radioktivnih gasova i aerosola u vazduhu, kao i stepena kontaminacije povrsina, odece i otkrivenih delova tela osoblja. U drugom delu izvestaja izlozeni su rezultati analize ozracivanja radnog osoblja. U trecem delu izvestaja navedeni

Structural and magnetic properties of SmCo-based magnetic films grown by electron-beam evaporation

Energy Technology Data Exchange (ETDEWEB)

Saravanan, P., E-mail: psdrdo@gmail.com [Defence Metallurgical Research Laboratory, Hyderabad 500058 (India); Vinod, V.T.P.; Černík, Miroslav [Institute for Nanomaterials, Advanced Technologies and Innovation, Department of Natural Sciences, Technical University of Liberec, Studentská 1402/2, Liberec 1, 461 17 (Czech Republic); Vishnuraj, R.; Arout Chelvane, J.; Kamat, S.V. [Defence Metallurgical Research Laboratory, Hyderabad 500058 (India); Hsu, Jen-Hwa, E-mail: jhhsu@phys.ntu.edu.tw [Department of Physics, National Taiwan University, Taipei 106, Taiwan (China)

2015-07-01

Sub-micron thick Sm–Co films (200 and 300 nm) with selective phase composition are grown on Si (100) substrates by electron-beam evaporation using Sm-lean alloy targets such as Sm{sub 4}Co{sub 96} and Sm{sub 8}Co{sub 92}. The structural and magnetic properties of Sm–Co films are characterized by x-ray diffraction (XRD), field-emission scanning electron microscopy (FESEM) and super-conducting quantum interference device (SQUID) magnetometer. The Sm–Co films obtained with the Sm{sub 4}Co{sub 96} target exhibit Sm{sub 2}Co{sub 17} as a prominent phase; while the films produced with the Sm{sub 8}Co{sub 92} target show Sm{sub 2}Co{sub 7} as a major phase. Both the Sm–Co films reveal granular morphology; however, the estimated grain size values are slightly lower in the case of Sm{sub 2}Co{sub 7} films, irrespective of their thicknesses. Coercivity (H{sub c}) values of 1.48 and 0.9 kOe are achieved for the as-grown 200-nm thick Sm{sub 2}Co{sub 17} and Sm{sub 2}Co{sub 7}-films. Temperature-dependent magnetization studies confirm that the demagnetization behaviors of these films are consistent with respect to the identified phase composition. Upon rapid thermal annealing, maximum H{sub c} value of 8.4 kOe is achieved for the 200 nm thick Sm{sub 2}Co{sub 17}-films. As far as e-beam evaporated Sm–Co films are concerned, this H{sub c} value is one of the best values reported so far. - Highlights: • Electron-beam evaporation was exploited to grow sub-μm thick Sm–Co films. • Sm{sub 2}Co{sub 7} and Sm{sub 2}Co{sub 17} magnetic phases were crystallized using Sm-lean alloy targets. • Both 200 and 300-nm thick Sm–Co films revealed distinct granular morphology. • Sm–Co films of lower thickness exhibited high H{sub c} and low M{sub s} and vice-versa. • Coercivity value of 8.4 kOe achieved for the 200-nm thick Sm{sub 2}Co{sub 17}-films after RTA.

Quality control of baby food products on the basis of results obtained using the instrumental neutron-activation analysis technique

International Nuclear Information System (INIS)

Mukhammedov, S.; Khaydarov, A.; Pardaev, O.

2013-01-01

The purpose of this study was to use the instrumental neutron-activation analysis (INAA) to determine the elemental composition of some kind of imported baby food products (BFP) and to compare the results with the permissible contents. The nuclear reactor WWR-SM of INP has been used to develop INAA to study the mineral composition of some children's food products. The concentration of 26 trace elements, including Mg, Ca, Fe, Zn, etc. was found. The comparison of the results with regulation contents and the daily data on food needs have shown that the investigated group of BFP does not meet the requirements for all trace and macro elements composition. (authors)

Blue-green and red photoluminescence in CaTiO3:Sm

International Nuclear Information System (INIS)

Figueiredo, Alberthmeiry T. de; Longo, Valeria M.; Lazaro, Sergio de; Mastelaro, Valmor R.; De Vicente, Fabio S.; Hernandes, Antonio C.; Siu Li, Maximo; Varela, Jose A.; Longo, Elson

2007-01-01

Blue-green and red photoluminescence (PL) emission in structurally disordered CaTiO 3 :Sm (CT:Sm) powders was observed at room temperature with laser excitation at 350.7 nm. The perovskite-like titanate CT:Sm powders prepared by a soft chemical processing at different temperatures of annealing were structurally characterized by X-ray diffraction (XRD) and X-ray absorption near-edge structure (XANES). The results indicate that the generation of the broad PL band is related to order-disorder degree in the perovskite-like structure

Analysis of urine samples from metastatic bone cancer patients administered 153Sm-EDTMP

International Nuclear Information System (INIS)

Goeckeler, W.F.; Stoneburner, L.K.; Price, D.R.; Fordyce, W.A.

1993-01-01

153 Sm-EDTMP is currently undergoing clinical evaluation as a radiotherapeutic agent for the relief of pain associated with cancer metastatic to bone. These clinical studies have demonstrated biodistributions similar to those seen earlier in animals, namely, rapid clearance from blood, selective uptake in bone and in particular metastatic bone lesions. The radioactivity not deposited in bone is cleared through the kidneys into the urine. In this study, urine samples collected from 9 patients injected with 153 Sm-EDTMP underwent complexation analysis via Pharmacia SP-Sephadex C25 cation exchange chromatography. The results showed 96.9 ± 1.7% of the radioactivity in the urine to be present as a complex of 153 Sm. An HPLC method was developed and it was demonstrated that different complexes of 153 Sm could be separated. A non-radioactive analytical standard of the Sm-EDTMP chelate was synthesized, characterized and shown to have the same HPLC retention profile as the 153 -EDTMP drug product. HPLC analysis was performed on six urine samples and in each case a single radioactivity peak with an elution profile the same as that of a 153 Sm-EDTMP standard was observed. These results indicate that the 153 Sm-EDTMP chelate is excreted intact in the urine of patients. (Author)

Enhancing Sm{sup 3+} red emission via energy transfer from Bi{sup 3+}→Sm{sup 3+} based on terbium bridge mechanism in Ca{sub 2}Al{sub 2}SiO{sub 7} phosphors

Energy Technology Data Exchange (ETDEWEB)

Li, Minhong; Wang, LiLi; Ran, Weiguang; Ren, Chunyan; Song, Zeling; Shi, Jinsheng, E-mail: jsshiqn@aliyun.com

2017-04-15

Currently, the key change for white-LED is to improve the luminescence efficiency of red phosphor. Sm{sup 3+} activated phosphor was considered due to suitable emission position of red light. However, the luminescence intensity in the red region is weak. For enhancing red-emitting of Sm{sup 3+}, Bi{sup 3+} and Tb{sup 3+} ions were introduced into Ca{sub 2}Al{sub 2}SiO{sub 7}:Sm{sup 3+} phosphors based on the concept of energy transfer. For Ca{sub 2}Al{sub 2}SiO{sub 7}:Bi{sup 3+}, Sm{sup 3+} samples, it can be observed that the energy transfer process was blocked. Hence, Tb{sup 3+} was introduced into Ca{sub 2}Al{sub 2}SiO{sub 7}:Bi{sup 3+}, Sm{sup 3+} samples to increase Sm{sup 3+} luminescence intensity based on Bi{sup 3+}→Tb{sup 3+}→Sm{sup 3+} energy transfer process. Compared with Sm{sup 3+} single-doped Ca{sub 2}Al{sub 2}SiO{sub 7} phosphor, the luminescence intensity of Sm{sup 3+} was enhanced by 2.6 times. It can be found that Tb{sup 3+} ions play a role of storing the energy or transfer bridge from Bi{sup 3+}→ Sm{sup 3+} by investigating the Ca{sub 2}Al{sub 2}SiO{sub 7}:Bi{sup 3+}, Tb{sup 3+} and Ca{sub 2}Al{sub 2}SiO{sub 7}:Tb{sup 3+}, Sm{sup 3+} energy transfer mechanism. All these results suggest that terbium branch mechanism plays an important role on enhancing activators luminescence intensity.

Structure of smAKAP and its regulation by PKA-mediated phosphorylation

Science.gov (United States)

Burgers, Pepijn P.; Bruystens, Jessica; Burnley, Rebecca J.; Nikolaev, Viacheslav O.; Keshwani, Malik; Wu, Jian; Janssen, Bert J. C.; Taylor, Susan S.; Heck, Albert J. R.; Scholten, Arjen

2016-01-01

The A-kinase anchoring protein (AKAP) smAKAP has three extraordinary features; it is very small, it is anchored directly to membranes by acyl motifs, and it interacts almost exclusively with the type I regulatory subunits (RI) of cAMP-dependent kinase (PKA). Here, we determined the crystal structure of smAKAP’s A-kinase binding domain (smAKAP-AKB) in complex with the dimerization/docking (D/D) domain of RIα which reveals an extended hydrophobic interface with unique interaction pockets that drive smAKAP’s high specificity for RI subunits. We also identify a conserved PKA phosphorylation site at Ser66 in the AKB domain which we predict would cause steric clashes and disrupt binding. This correlates with in vivo colocalization and fluorescence polarization studies, where Ser66 AKB phosphorylation ablates RI binding. Hydrogen/deuterium exchange studies confirm that the AKB helix is accessible and dynamic. Furthermore, full-length smAKAP as well as the unbound AKB is predicted to contain a break at the phosphorylation site, and circular dichroism measurements confirm that the AKB domain loses its helicity following phosphorylation. As the active site of PKA’s catalytic subunit does not accommodate α-helices, we predict that the inherent flexibility of the AKB domain enables its phosphorylation by PKA. This represents a novel mechanism, whereby activation of anchored PKA can terminate its binding to smAKAP affecting the regulation of localized cAMP signaling events. PMID:27028580

Hydrogen stability of SmCo5 permanent magnet

International Nuclear Information System (INIS)

Lukin, A.; Rabinovich, Y.; Bala, H.

2001-01-01

The present work has been performed with purpose to determine the level of hydrogen stability of sintered SmCo 5 permanent magnets by means of accelerated tests, to study the effect of hydrogen on the magnetic and mechanical properties of the permanent magnets and to establish the criteria of hydrogenation level and the activation energy of this process. In addition, the effect of hydrogen on the properties of sintered SmCo 5 permanent magnets in specific conditions of exploitation and storage durability of instruments was studied

RA reactor operation and maintenance in 1994, Part 1; Deo 1 - Pogon i odrzavanje nuklearnog reaktora RA u 1994. godini

Energy Technology Data Exchange (ETDEWEB)

Sotic, O; Cupac, S; Sulem, B; Zivotic, Z; Mikic, N; Tanaskovic, M [Institute of Nuclear Sciences Boris Kidric, Vinca, Beograd (Serbia and Montenegro)

1994-12-01

During the previous period RA reactor was not operated because the Committee of Serbian ministry for health and social care has cancelled the operation licence in August 1984. The reason was the non existing emergency cooling system and lack of appropriate filters in the special ventilation system. The planned major tasks were fulfilled: building of the new emergency cooling system, reconstruction of the existing ventilation system, and renewal of the reactor power supply system. The existing RA reactor instrumentation was dismantled, only the part needed for basic measurements when reactor is not operated, was maintained. Renewal of the reactor instrumentation was started but but it is behind the schedule because the delivery of components from USSR was stopped for political reasons. The spent fuel elements used from the very beginning of reactor operation are stored in the existing pools. Project concerned with increase of the storage space and the efficiency of handling the spent fuel elements has started in 1988 and was fulfilled in 1990. Control and maintenance of the reactor instrumentation and tools was done regularly but dependent on the availability of the spare parts. Training of the existing personnel and was done regularly, but the new staff has no practical training since the reactor is not operated. Lack of financial support influenced strongly the status of RA reactor. [Serbo-Croat] U proteklom periodu reaktor RA nije bio u pogonu zato sto je 30. jula Republicki komitet za zdravlje i socijalnu politiku republike Srbije, zabranio njegov rad zbog toga sto reaktor ne poseduje sistem za udesno hladjenje i ne poseduje odgovarajuce filtere u sistemu specijalne ventilacije. Zavrseni su radovi na izgradnji sistema za udesno hladjenje, rekonstrukciji postojeceg sistema specijalne ventilacije i rekonstrukciji sistema za napajanje elektricnom energijom. Zapoceti su radovi na modernizaciji, odnosno zameni instrumentacije reaktora ali njegova realizacija kasni

Structural and electrical properties of Sm{sup 3+} substituted PZT ceramics

Energy Technology Data Exchange (ETDEWEB)

Pandey, S.K. [Solid State Physics Laboratory, Timarpur, Delhi 110 054 (India)], E-mail: 628@ssplnet.org; Thakur, O.P.; Bhattacharya, D.K. [Solid State Physics Laboratory, Timarpur, Delhi 110 054 (India); Prakash, Chandra [DRDO Bhawan, DHQ, New Delhi 110 011 (India); Chatterjee, Ratnamala [Department of Physics, Indian Institute of Technology, New Delhi 110 016 (India)

2009-01-22

Samarium modified lead zirconate titanate (PSZT: Pb{sub 1-x}Sm{sub x}(Zr{sub 0.65}Ti{sub 0.35})O{sub 3}: x = 0, 0.02, 0.04, 0.06) ceramics were synthesized by solid state ceramic route. XRD shows single-phase formation with rhombohedral structure up to x = 0.04. With Sm-substitution, the grain size first increases up to x = 0.02 and then decreases. A metal/ferroelectric/metal (MFM) structure was made by depositing gold electrode on the flat surfaces for electrical measurements. All samples show normal ferroelectric behaviour, however, a squareness of P-E loop (polarization vs. electric field) was observed to increase with Sm content. Higher electromechanical coupling coefficients (K{sub p} and K{sub t}) have been achieved for the PZT with 6 mol% Sm substitution and having fine grain size.

Simplified syntheses of the water-soluble chiral shift reagents Sm-(R)-pdta and Sm-(S)-pdta

Czech Academy of Sciences Publication Activity Database

Hrubá, L.; Buděšínský, Miloš; Pícha, Jan; Jiráček, Jiří; Vaněk, Václav

2013-01-01

Roč. 54, č. 47 (2013), s. 6296-6297 ISSN 0040-4039 Institutional support: RVO:61388963 Keywords : NMR * chiral shift reagents * Sm-pdta * PDTA * samarium * 1,2-diaminopropane Subject RIV: CC - Organic Chemistry Impact factor: 2.391, year: 2013

Standard enthalpy of formation of Sm6UO12 acid dissolution calorimetry

International Nuclear Information System (INIS)

Venkata Krishnan, R.; Jogeswararao, G.; Ananthasivan, K.

2016-01-01

The standard molar enthalpies of formation of Δ f (298 K) of Sm 6 UO 12 have been determined by using an indigenously developed isoperibol acid solution calorimeter. The water equivalent of this calorimeter was determined by electrical calibration. The accuracy of measurement were determined by using standard materials KCl and tris(hydroxyl methyl) amino-methane (TRIS) and was found to be within ±2%. The enthalpies of solution at 298 K of Sm 2 O 3 , UO 3 and Sm 6 UO 12 were measured by using this calorimeter. From these experimental results the enthalpies of formation of Sm 6 UO 12 at 298 K were computed by using Hess's law of summation. (author)

Enhanced protective efficacy of a chimeric form of the schistosomiasis vaccine antigen Sm-TSP-2.

Directory of Open Access Journals (Sweden)

Mark S Pearson

Full Text Available The large extracellular loop of the Schistosoma mansoni tetraspanin, Sm-TSP-2, when fused to a thioredoxin partner and formulated with Freund's adjuvants, has been shown to be an efficacious vaccine against murine schistosomiasis. Moreover, Sm-TSP-2 is uniquely recognised by IgG(1 and IgG(3 from putatively resistant individuals resident in S. mansoni endemic areas in Brazil. In the present study, we expressed Sm-TSP-2 at high yield and in soluble form in E. coli without the need for a solubility enhancing fusion partner. We also expressed in E. coli a chimera called Sm-TSP-2/5B, which consisted of Sm-TSP-2 fused to the immunogenic 5B region of the hookworm aspartic protease and vaccine antigen, Na-APR-1. Sm-TSP-2 formulated with alum/CpG showed significant reductions in adult worm and liver egg burdens in two separate murine schistosomiasis challenge studies. Sm-TSP-2/5B afforded significantly greater protection than Sm-TSP-2 alone when both antigens were formulated with alum/CpG. The enhanced protection obtained with the chimeric fusion protein was associated with increased production of anti-Sm-TSP-2 antibodies and IL-4, IL-10 and IFN-γ from spleen cells of vaccinated animals. Sera from 666 individuals from Brazil who were infected with S. mansoni were screened for potentially deleterious IgE responses to Sm-TSP-2. Anti-Sm-TSP-2 IgE to this protein was not detected (also shown previously for Na-APR-1, suggesting that the chimeric antigen Sm-TSP-2/5B could be used to safely and effectively vaccinate people in areas where schistosomes and hookworms are endemic.

Brillouin spectroscopy with surface acoustic waves on intermediate valent, doped SmS

International Nuclear Information System (INIS)

Schaerer, U.; Jung, A.; Wachter, P.

1998-01-01

Brillouin scattering on surface acoustic waves is a very powerful tool to determine the elastic constants of intermediate valent crystals, since the method is non-destructive and no mechanical contact is needed. A strong evidence for intermediate valence is a negative value of Poisson's ratio, which describes the behavior of the volume under uniaxial pressure. SmS by itself makes a semiconductor-metal transition at a pressure of more than 6.5 kbar. When substituting the divalent Sm by a trivalent cation, like Y, La or Tm, SmS can become - depending on the doping concentration - intermediate valent without any applied, external pressure. In this work, we will present measurements of the velocities of the surface acoustic waves and the calculation of the elastic constants of La- and Tm-doped SmS compounds. We found a clear dependence of Poisson's ratio on the doping concentration and on the valence of the materials. Furthermore, we will discuss the mechanism leading to intermediate valence when substituting Sm. Besides the internal, chemical pressure, which is produced by the built in trivalent cations with their smaller ionic radii, we have clear evidence, that the free electrons in the 5d band, induced by the substituting atoms, also play an important role in making doped SmS intermediate valent. (orig.)

Isolated centres versus defect associates in Sm3+-doped CeO2: a spectroscopic investigation

International Nuclear Information System (INIS)

Tiseanu, Carmen; Avram, Daniel; Cojocaru, Bogdan; Parvulescu, Vasile I; Vela-Gonzalez, Andrea V; Sanchez-Dominguez, Margarita

2013-01-01

The interactions between Sm 3+ and oxygen vacancies in CeO 2 are probed by the use of tuneable laser excited time-resolved photoluminescence and Raman spectroscopies. It is found that Sm 3+ (with doping concentrations of 0.1, 0.3, 1 and 5 wt%) substitutes largely for Ce 4+ in sites with cubic symmetry and the corresponding emission is sensitized via the Ce 4+ –O 2− charge-transfer band of CeO 2 . It is established from the photoluminescence spectra measured at long delay after the laser pulse that the local environment around cubic Sm 3+ centres is not changed with concentration and ceria size. In addition to cubic symmetry Sm 3+ centres, low-symmetry Sm 3+ centres tentatively assigned to the Sm 3+ –oxygen vacancy associates of nearest-neighbour type are also observed. Their emission is preferentially excited via the weak f–f absorption transitions of Sm 3+ . A relatively strong concentration-induced quenching of Sm 3+ emission was inferred from the decrease in the average emission lifetimes from 2.1 ms (0.1 wt%) to 0.87 ms (5 wt%). The local environments of Sm 3+ and Eu 3+ in CeO 2 are also compared on the basis of their emission spectra and decays. (paper)

Chilean experience in production of therapeutic radiopharmaceuticals labelled with 153Sm and 166Ho

International Nuclear Information System (INIS)

Chandia, M.; Gil, M.G.; Tomicic, M.; Araya, G.; Olea, E.; Chong, G.

1998-01-01

153 Samarium ( 153 Sm) and 166 Holmium ( 166 Ho) were produced at the Nuclear Center of La Reina Research Reactor, Chilean Nuclear Energy Commission. 153 Sm-EDTMP (Ethylenediaminetetramethylene Phosphonate) used for clinical trial of therapy for painful skeletal metastases and labeled particles such as 166 Ho-FHMA (ferric hydroxide macroagregattes) and 153 Sm-HAP (hydroxiapatite particles) used for radiation synevectomy, were labeled. Radionuclide purity of both radionuclides was analyzed by gamma spectrometry using a multichannel gamma spectrometer. Radiochemical labeled reaction parameters of 153 Sm-EDTMP such as: Sm/EDTMP molar ratio, 153 Sm specific activity, labeled pH and temperature, were determined in order to get high radiolabeling yields. Radiochemical Quality Controls of 153 Sm-EDTMP using different chromatographic systems were carried out in order to determine labeling yields. Bodistribution studies were achieved in mice by dissection of animals and by autoradiography of histological slices in rats, after 2h post injection. 153 Sm-HAP and 166 Ho-FHMA labeled particles were prepared using the methods described. Radiochemical purity, in case of radiolabeled particles was carried out by centrifugation, measuring activity in the supernatant and in particles pellet. Physical parameters, such as particle size and range of the radiopharmaceuticals based on particles labeling were evaluated in order to determine the ideal conditions to obtain particles size range between 10 - 40μ. In vitro labeling stability for over seven days and wash out activity by incubation in human synovial fluid after 6 and 24h post labeling, was also studied. 153 Sm-EDTMP was easily labeled with a Radiochemical purity over 99.5% and stable for over 7 days. Biodistribution studies in mice give more than 50% of ID uptake in bone and less than 0,1% in liver this was correlated by autoradiographic image. 153 Sm-HAP and 166 Ho-FHMA were also labeling obtaining radiochemical purity over 95

Real-time observation of growth and orientation of Sm-Ba-Cu-O phases on a Sm-211 whisker substrate by high-temperature optical microscopy

Czech Academy of Sciences Publication Activity Database

Sun, J.L.; Huang, Y.B.; Cheng, L.; Yao, X.; Lai, Y.J.; Jirsa, Miloš

2009-01-01

Roč. 9, č. 2 (2009), 898-902 ISSN 1528-7483 R&D Projects: GA ČR GA202/08/0722 Institutional research plan: CEZ:AV0Z10100520 Keywords : high-temperature optical microscopy * growth and orientation of Sm-Ba-Cu-O phases * Sm-211 whisker substrate Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 4.162, year: 2009

Coercive force changes in Sm(CoFeCuZr)z during step-like heat treatments

International Nuclear Information System (INIS)

Puzanova, T.Z.; Shchegoleva, N.N.; Sakhnova, L.V.; Majkov, V.G.; Shur, Ya.S.; Nikolaeva, N.V.

1987-01-01

Sm(Co 0.67 Fe 0.22 Cu 0.08 Zr 0.03 ) 8.35 alloy, contaning two homogeneous solid solutions SmM 6.85 and SmM 7.75 (M=Co, Fe, Cu, Zr) after high-temperature treatment, is investigated. It is shown, that after isothermal tempering at 800 deg C, SmM 6.85 and SmM 7.75 are close by microstructure and their coercive forces change in a different way during step-like cooling within 700-400 deg C interval. Possibility of producing material, single-phase in magnetic relation, is discussed

Cytogenetic effect of {sup 153} Sm-EDTMP in peripheral lymphocytes of patients with metastatic cancer; Efeito citogenetico do {sup 153} Sm-EDTMP em linfocitos perifericos de pacientes com cancer metastatico

Energy Technology Data Exchange (ETDEWEB)

Silva, Marcia Augusta da

2001-07-01

The {sup 153}Sm-EDTMP is a radiopharmaceutical used in nuclear medicine with promising results for the relief of metastatic pain. Therefore, there are few knowledge about the effects of {sup 153}Sm-EDTMP at cellular level. The present study was conduced with the aim of evaluating the cytogenetic effects of {sup 153}Sm-EDTMP in peripheral lymphocytes from patients with bone metastasis (with and without previous radio and/or chemotherapy) by the chromosome aberration technique, either in vivo or in vitro. For that, the blood samples were collected before and one hour after the endovenous administration of {sup 153}Sm-EDTMP (mean activity of 42.53+/-5.31 MBq/kg body weight), taking into account the rapid blood clearance. The principal types of structural chromosome aberrations found gaps and breaks, acentric fragments centric rings, double minutes and dicentrics. The statistical analysis showed that the group submitted to previous radio and chemotherapy before {sup 153}Sm-EDTMP administration showed significant difference in chromosome aberrations frequency one hour after the treatment. The analysis of the chromosome modal number and the kinetics of cellular cycle showed no statistical difference among the groups, suggesting that the treatment with {sup 153}Sm-EDTMP, did not influence these parameters. The carrier molecule, EDTMP, did not influence the induction of chromosome aberration. In relation to the in vitro assays, the obtained data of peripheral lymphocytes of healthy donors and patients with no previous treatment exposed to different radioactive concentration of {sup 153}Sm-EDTMP (0.046 - 1.110 MBq/mL) were better adjusted by linear regression model (Y=A+BX). The chromosome damage induced by {sup 153}Sm-EDTMP observed in vitro was about 2 fold higher than that found in vivo for the group of patients with no previous treatment. The obtained data showed that the therapy with {sup 153}Sm-EDTMP induced a few quantity of cytogenetic damages in peripheral

SmShb, the SH2-Containing Adaptor Protein B of Schistosoma mansoni Regulates Venus Kinase Receptor Signaling Pathways.

Directory of Open Access Journals (Sweden)

Marion Morel

Full Text Available Venus kinase receptors (VKRs are invertebrate receptor tyrosine kinases (RTKs formed by an extracellular Venus Fly Trap (VFT ligand binding domain associated via a transmembrane domain with an intracellular tyrosine kinase (TK domain. Schistosoma mansoni VKRs, SmVKR1 and SmVKR2, are both implicated in reproductive activities of the parasite. In this work, we show that the SH2 domain-containing protein SmShb is a partner of the phosphorylated form of SmVKR1. Expression of these proteins in Xenopus oocytes allowed us to demonstrate that the SH2 domain of SmShb interacts with the phosphotyrosine residue (pY979 located in the juxtamembrane region of SmVKR1. This interaction leads to phosphorylation of SmShb on tyrosines and promotes SmVKR1 signaling towards the JNK pathway. SmShb transcripts are expressed in all parasite stages and they were found in ovary and testes of adult worms, suggesting a possible colocalization of SmShb and SmVKR1 proteins. Silencing of SmShb in adult S. mansoni resulted in an accumulation of mature sperm in testes, indicating a possible role of SmShb in gametogenesis.

SmShb, the SH2-Containing Adaptor Protein B of Schistosoma mansoni Regulates Venus Kinase Receptor Signaling Pathways.

Science.gov (United States)

Morel, Marion; Vanderstraete, Mathieu; Cailliau, Katia; Hahnel, Steffen; Grevelding, Christoph G; Dissous, Colette

2016-01-01

Venus kinase receptors (VKRs) are invertebrate receptor tyrosine kinases (RTKs) formed by an extracellular Venus Fly Trap (VFT) ligand binding domain associated via a transmembrane domain with an intracellular tyrosine kinase (TK) domain. Schistosoma mansoni VKRs, SmVKR1 and SmVKR2, are both implicated in reproductive activities of the parasite. In this work, we show that the SH2 domain-containing protein SmShb is a partner of the phosphorylated form of SmVKR1. Expression of these proteins in Xenopus oocytes allowed us to demonstrate that the SH2 domain of SmShb interacts with the phosphotyrosine residue (pY979) located in the juxtamembrane region of SmVKR1. This interaction leads to phosphorylation of SmShb on tyrosines and promotes SmVKR1 signaling towards the JNK pathway. SmShb transcripts are expressed in all parasite stages and they were found in ovary and testes of adult worms, suggesting a possible colocalization of SmShb and SmVKR1 proteins. Silencing of SmShb in adult S. mansoni resulted in an accumulation of mature sperm in testes, indicating a possible role of SmShb in gametogenesis.

Synthesis, characterization and antimicrobial activity of some nitrilotriacetic acid−V(III, −Sn(II, −Sm(II and −Sm(III complexes

Directory of Open Access Journals (Sweden)

Mohsen S. Asker

2011-04-01

Full Text Available Four new complexes [V(NTA(H2O 2]•H2O (1, H[Sn(NTA] (2, H[Sm(NTA]•H2O (3, and [Sm(NTA(H2O 2]•H2O (4 were obtained during the reactions of metal salts (VCl3, SnCl2•2H2O, SnCl4, Sm(NO32•6H2O and SmCl3•6H2O with nitrilotriacetic acid, H3NTA. The infrared and 1H-NMR spectra of the solid complexes have been obtained and assigned. Thermogravimetric analyses were also carried out. The data obtained agree with the proposed structures and show that the complexes decomposed to the corresponding metal oxide. The ligand and their metal complexes were screened for their antimicrobial activities by the agar-well diffusion technique using DMSO as a solvent against the following bacterial species: Bacillus subtilis, Staphylococcus aureus, Escherichia coli and Pseudomonas aeruginosa and antifungal activity against Aspergillus niger, Aspergillus flavus, Saccharomyces cerevisiae and Candida albicans. The obtained results were compared with some types of known antibiotics. The minimum inhibitory concentration (MIC values were calculated at 30 °C for 24−48 h. The activity data show that the complexes are more potent antimicrobials than the parent ligand.

Luminescence and energy transfer of Sm3+ and Eu3+ in Ca2PO4Cl

International Nuclear Information System (INIS)

Wang, Zhijun; Li, Panlai; Yang, Zhiping; Guo, Qinglin

2014-01-01

Sm 3+ , Eu 3+ , and Sm 3+ –Eu 3+ doped Ca 2 PO 4 Cl phosphors are synthesized by a solid-state method. Ca 2 PO 4 Cl:Sm 3+ can produce red emission under the 400 nm radiation excitation, and the emission peak is located at 601 nm, which is assigned to the 4 G 5/2 → 6 H 7/2 transition of Sm 3+ . Ca 2 PO 4 Cl:Eu 3+ can create red emission under the 392 nm radiation excitation, and the strongest peak is located at 620 nm, which is attributed to the 5 D 0 → 7 F 2 transition of Eu 3+ . The energy transfer from Sm 3+ to Eu 3+ in Ca 2 PO 4 Cl has been validated and the critical distance (R c ) of Sm 3+ to Eu 3+ in Ca 2 PO 4 Cl is calculated to be 1.14 nm. With increasing Eu 3+ doping concentration, the energy transfer efficiency (Sm 3+ →Eu 3+ ) gradually increases to 53.7%. The luminescence property of Ca 2 PO 4 Cl:Sm 3+ , Eu 3+ can be tuned by properly tuning the relative ratio of Sm 3+ –Eu 3+ , and the emission intensity of Ca 2 PO 4 Cl:Eu 3+ can be greatly enhanced by codoped Sm 3+ . - Highlights: • Ca 2 PO 4 Cl:Sm 3+ , Eu 3+ can produce red emission under the 400 nm radiation excitation. • The energy transfer from Sm 3+ to Eu 3+ in Ca 2 PO 4 Cl has been validated. • The critical distance of Sm 3+ to Eu 3+ in Ca 2 PO 4 Cl is calculated to be 1.14 nm

Synthesis and DNA interaction of a Sm(III) complex of a Schiff base ...

African Journals Online (AJOL)

The interaction between the Sm(III) complex of an ionic Schiff base [HL]-, derived from vanillin and L-tryptophan, and herring sperm DNA at physiological pH (7.40) has been studied by UV-Vis absorption, fluorescence and viscosity methods. The binding ratios nSm(III) : nK[HL] = 1:1 and nSm(III)L: nDNA =5:1 were confirmed ...

Nuclear translocation of the cytoskeleton-associated protein, smALP, upon induction of skeletal muscle differentiation

International Nuclear Information System (INIS)

Cambier, Linda; Pomies, Pascal

2011-01-01

Highlights: → The cytoskeleton-associated protein, smALP, is expressed in differentiated skeletal muscle. → smALP is translocated from the cytoplasm to the nucleus of C2C12 myoblasts upon induction of myogenesis. → The differentiation-dependent nuclear translocation of smALP occurs in parallel with the nuclear accumulation of myogenin. → The LIM domain of smALP is essential for the nuclear accumulation of the protein. → smALP might act in the nucleus to control some critical aspect of the muscle differentiation process. -- Abstract: The skALP isoform has been shown to play a critical role in actin organization and anchorage within the Z-discs of skeletal muscles, but no data is available on the function of the smALP isoform in skeletal muscle cells. Here, we show that upon induction of differentiation a nuclear translocation of smALP from the cytoplasm to the nucleus of C2C12 myoblasts, concomitant to an up-regulation of the protein expression, occurs in parallel with the nuclear accumulation of myogenin. Moreover, we demonstrate that the LIM domain of smALP is essential for the nuclear translocation of the protein.

Standard Missile-6 (SM-6)

Science.gov (United States)

2016-12-01

attack or Anti-Ship Cruise Missiles in flight. The SM-6 ERAM program is an evolutionary, capabilities based acquisition program that will use spiral ...Prior SAR Total O&S Estimates - Dec 2014 SAR 460.3 Programmatic/Planning Factors 0.0 Cost Estimating Methodology 0.0 Cost Data Update 0.0 Labor Rate

Influences of the amount of ligand on the biochemical properties of 153Sm-HEDTMP

International Nuclear Information System (INIS)

Yang Yuqing; Luo Shunzhong; Wang Guanquan; He Jiaheng; Pu Manfei; Bing Wenzeng

2002-01-01

The Effect of the amount of ligand HEDTMP on biochemical properties of 153 Sm-HEDTMP is studied. The biochemical properties include partition coefficient of 153 Sm-HEDTMP in n-octanol-water which is measured by shake-flask method, combination characteristic with BSA (bovine serum albumin) which is measured through precipitation by TCA (trichloroacetic acid) and adsorption characteristic on HA (hydroxyapatite) which is measured with the same method used in 153 Sm-EDTMP. It is found that, with the increasing in the amount of ligand, partition coefficient of 153 Sm-HEDTMP. It is found that, with the increase in the amount of ligand, partition coefficient of 153 Sm-HEDTMP in n-octanol-water decreases, so does combination percentage with BSA, but the adsorption percentage on HA shows a little and unremarkable decrease. Considering the relationships between these three biochemical properties and in vivo metabolism of 153 Sm-HEDTMP this study supports the view that an appropriate high amount of ligand should be applied in practical use

External exposure in radionuclide therapy with 153 Sm

Energy Technology Data Exchange (ETDEWEB)

Rezio, M.T.; Vieira, M.R. [Instituto Portugues Oncologia de Francisco Gentil, CROL, Lisboa (Portugal)

2006-07-01

Full text of publication follows: Aim: The radiopharmaceutical 153 Sm is an beta emitter used in metastatic bone pain palliation. The prescribed activity is 37 MBq/kg body weight.. The aim of this study is to measure the dose rate of the patients during 4 to 6 hours after 153 Sm - E.D.T.M.P. administration in order to prevent external exposure of nursing staff, family members and general public. Material and Methods: Twelve patients were treated with 153 Sm in our department. External exposure rates( {mu}Sv/h) at different times and at one meter were measured, with a Geiger-Muller detector. Results: The mean dose rate at one meter was 12 {mu}Sv/h, one hour after injection and 3{mu} Sv/h, 6 hours after injection. Conclusion: The policy in our department is to keep the patient in the hospital 4-6 h, due to the risk of contamination. Based on our results, the external exposure of the nursing staff, family members and the general public is very low, in agreement with other studies. (authors)

External exposure in radionuclide therapy with 153 Sm

International Nuclear Information System (INIS)

Rezio, M.T.; Vieira, M.R.

2006-01-01

Full text of publication follows: Aim: The radiopharmaceutical 153 Sm is an beta emitter used in metastatic bone pain palliation. The prescribed activity is 37 MBq/kg body weight.. The aim of this study is to measure the dose rate of the patients during 4 to 6 hours after 153 Sm - E.D.T.M.P. administration in order to prevent external exposure of nursing staff, family members and general public. Material and Methods: Twelve patients were treated with 153 Sm in our department. External exposure rates( μSv/h) at different times and at one meter were measured, with a Geiger-Muller detector. Results: The mean dose rate at one meter was 12 μSv/h, one hour after injection and 3μ Sv/h, 6 hours after injection. Conclusion: The policy in our department is to keep the patient in the hospital 4-6 h, due to the risk of contamination. Based on our results, the external exposure of the nursing staff, family members and the general public is very low, in agreement with other studies. (authors)

Safety analysis for testing operation of the RA reactor in the Boris Kidric Institute, Vinca; Analiza sigurnosti rada reaktora 'RA' za probni rad u Institutu za nuklearne nauke 'Boris Kidric' - Vinca

Energy Technology Data Exchange (ETDEWEB)

Milosevic, M et al. [Institute of Nuclear Sciences Boris Kidric, Vinca, Beograd (Serbia and Montenegro)

1980-09-15

This safety report covers detailed description of the RA reactor core, reactor components, coolant system, control system, safety system, reactor building including site characteristics. A separate chapter is devoted to radiation protection and radioactive waste management. Organizational structure od the reactor staff as well as training program are included. The last chapter includes detailed emergency plans for three accidents classified in three categories. [Serbo-Croat] Ovaj izvestaj sadrzi detaljan opis reaktora RA, sistema za hladjenje, kontolno-sigurnosnog sistema, elektricnog sistema, zgrade sa instalacijama, ukljucujuci karakteristike lokacije. Posebno poglavlje opisuje sistem zastite od zracenja i rukovanje radioaktivnim otpadom. Opisana je organizacija rada i program obuke osoblja. Poslednje poglavlje sadrzi detaljan plan mera za slucaj udesa klasifikovanih u tri kategorije.

Preparation and Luminescent Properties of the antibacterial materials of the La3+ Doped Sm3+-Hydroxyapatite

Science.gov (United States)

Lv, Yuguang; Shi, Qi; Jin, Yuling; Ren, Hengxin; Qin, Yushan; Wang, Bo; Song, Shanshan

2018-03-01

In this paper, the La3+-doped Sm3+ hydroxyapatite (La/Sm/HAP) complexes were prepared by a precipitation method. The sample was defined by IR spectra, fluorescence spectra and X ray diffraction analysis et al. The structure of complexes were discussed. The emission wavelength of heat treatment of Sm3+ do not change, but will affect the intensity of the peak Sm3+ luminescence properties and the occupy hydroxyapatite in the lattice Ca( II )and Ca( I ) loci with Sm3+ doped concentration and the proportion of the sintering temperature change and change: The nano hydroxyapatite complex of the La3+ doped samarium obtain the good fluorescence intensity, by La3+ doping content of Sm3+ were hydroxyapatite 6% (La3+, Sm3+ mole ratio) device. The complex of La3+ doped samarium HAP have Stable chemical property, fluorescence property and excellent biological activity. The ligand HAP absorbs energy or captures an electron-hole pair and then transfers it to the lanthanide ions. The catalytic activity influence of the La3+-doped Sm3+hydroxyapatite was discussed, the La/Sm/HAP had excellent antibacterial property, which used as potential biological antibacterial material.

RA Reactor; Reaktor RA

Energy Technology Data Exchange (ETDEWEB)

NONE

1989-07-01

This chapter includes the following: General description of the RA reactor, organization of work, responsibilities of leadership and operators team, regulations concerning operation and behaviour in the reactor building, regulations for performing experiments, regulations and instructions for inserting samples into experimental channels. [Serbo-Croat] Ovo (prvo) poglavlje sadrzi sledece: Opis reaktora RA; semu organizacije rada i rukovodjenja; prava i duznosti direktora i rukovodioca pogona reaktora, propise o rezimu rada i kretanja u zgradi reaktora, propise o izvodjenju eksperimenata, propise o unosenju uzoraka u eksperimentalne kanale reaktora.

Three-loop SM beta-functions for matrix Yukawa couplings

Directory of Open Access Journals (Sweden)

A.V. Bednyakov

2014-10-01

Full Text Available We present the extension of our previous results for three-loop Yukawa coupling beta-functions to the case of complex Yukawa matrices describing the flavour structure of the SM. The calculation is carried out in the context of unbroken phase of the SM with the help of the MINCER program in a general linear gauge and cross-checked by means of MATAD/BAMBA codes. In addition, ambiguities in Yukawa matrix beta-functions are studied.

Optical imaging of the transport properties of S-Sm-S junctions

International Nuclear Information System (INIS)

Tsumura, K; Nomura, S; Akazaki, T; Takayanagi, H

2009-01-01

We study the optical effects on superconductor-normal metal superconductor (S-Sm-S) junctions composed of two-dimensional electron gas (2DEG) in a GaAs/AlGaAs heterostructure and NbN superconducting electrodes. When the whole junction area was illuminated at λ = 800 nm, we observe a reduction in the normal resistance due to an increase in the sheet carrier density of the 2DEG, and the enhancement of the Andreev reflection probability. To reveal its origin, we performed scanning photo-voltage measurement by employing an optical microscope. The obtained image plots show maxima and minima of the photo-voltage change along the S-Sm interfaces. Those structures are considered to reflect the modulation of the barrier height at S-Sm interface and the increase in the scattering by photo-generated carriers. It is demonstrated that the scanning photo-voltage measurement is one of the most powerful tools as a local probe of the transport properties of S-Sm-S junctions.

The direct limit on the Higgs Mass and the SM Fit

International Nuclear Information System (INIS)

Chanowitz, Michael S.

2003-01-01

Because of two 3σ anomalies, the Standard Model (SM) fit of the precision electroweak data has a poor confidence level, CL = 0.02. Since both anomalies involve challenging systematic issues, it might appear that the SM could still be valid if the anomalies resulted from underestimated systematic error. Indeed the CL of the global fit could then increase to 0.71, but that fit predicts a small Higgs boson mass, m H = 45 GeV, that is inconsistent at 95% CL with the lower limit, m H > 114 GeV, established by direct searches. The data then favor new physics whether the anomalous measurements are excluded from the fit or not, and the Higgs boson mass cannot be predicted until the new physics is understood. Some measure of statistical fluctuation would be needed to maintain the validity of the SM. New physics is favored, but the SM is not definitively excluded

Subcoulomb fusion of 16O in odd Sm isotopes

International Nuclear Information System (INIS)

Pacheco, A.J.

1989-01-01

Cross sections for the formation of evaporation residues were measured for the reaction of 16 O with the odd 147 Sm and 149 Sm nuclei at near barrier energies. The results are well described by statistical model calculations. Fusion cross sections as a function of energy do not show any unusual behaviour that could be attributed to the presence of unpaired nucleons. An analysis based on a one-dimensional penetration model that includes the effect of permanent quadrupolar deformations shows that the extracted values of the parameter β 2 follow the systematics established by the rest of the even samarium isotopes. The dependence of β 2 on the mass of the target nucleus indicates that the influence exerted by collective aspects upon the subbarrier fusion process increases rapidly as a function of the number of neutrons added to the spherical semimagic 144 Sm nucleus. (Author) [es

Modified chemical synthesis of porous α-Sm{sub 2}S{sub 3} thin films

Energy Technology Data Exchange (ETDEWEB)

Kumbhar, V.S.; Jagadale, A.D. [Thin Film Physics Laboratory, Department of Physics, Shivaji University, Kolhapur, (M.S.) 416004 (India); Gaikwad, N.S. [Rayat Shikshan Sanstha, Satara, (M.S.) 415 001 (India); Lokhande, C.D., E-mail: l_chandrakant@yahoo.com [Thin Film Physics Laboratory, Department of Physics, Shivaji University, Kolhapur, (M.S.) 416004 (India)

2014-08-15

Highlights: • A novel chemical route to prepare α-Sm{sub 2}S{sub 3} thin films. • A porous honeycomb like morphology of the α-Sm{sub 2}S{sub 3} thin film. • An application of α-Sm{sub 2}S{sub 3} thin film toward its supercapacitive behaviour. - Abstract: The paper reports synthesis of porous α-Sm{sub 2}S{sub 3} thin films using modified chemical synthesis, also known as successive ionic layer adsorption and reaction (SILAR) method. The X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), atomic force microscopy (AFM), wettability and ultraviolet–visible spectroscopy (UV–vis) techniques are used for the study of structural, elemental, morphological and optical properties of α-Sm{sub 2}S{sub 3} films. An orthorhombic crystal structure of α-Sm{sub 2}S{sub 3} is resulted from XRD study. The SEM and AFM observations showed highly porous α-Sm{sub 2}S{sub 3} film surface. An optical band gap of 2.50 eV is estimated from optical absorption spectrum. The porous α-Sm{sub 2}S{sub 3} thin film tuned for supercapacitive behaviour using cyclic voltammetry and galvanostatic charge discharge showed a specific capacitance and energy density of 294 Fg{sup –1} and 48.9 kW kg{sup –1}, respectively in 1 M LiClO{sub 4}–propylene carbonate electrolyte.

Formation of SmFe5(0001) ordered alloy thin films on Cu(111) single-crystal underlayers

International Nuclear Information System (INIS)

Yabuhara, Osamu; Ohtake, Mitsuru; Nukaga, Yuri; Futamoto, Masaaki; Kirino, Fumiyoshi

2010-01-01

SmFe 5 (0001) single-crystal thin films are prepared by molecular beam epitaxy employing Cu(111) single-crystal underlayers on MgO(111) substrates. The Cu atoms diffuse into the Sm-Fe layer and substitute the Fe sites in SmFe 5 structure forming an alloy compound of Sm(Fe,Cu) 5 . The Sm(Fe,Cu) 5 film is more Cu enriched with increasing the substrate temperature. The Cu underlayer plays an important role in assisting the formation of the ordered phase.

First measurement of 153Sm in the SIR

International Nuclear Information System (INIS)

Michotte, C.; Ratel, G.; Lucas, L.

1999-01-01

In June 1998, the NIST sent to the International Reference System (SIR) a solution of 153 Sm standardized in a 4π ionization chamber. As this radionuclide had not previously been measured in the SIR, the resulting equivalent activity A e,NIST is compared with the value calculated from the efficiency curve of the SIR. However, problems occurred owing to the presence of 154 Eu and 156 Eu impurities in the solution. The manner in which the final equivalent activity value for this solution of 153 Sm has been deduced is described in this report. (authors)

The neutron EDM in the SM: a review

International Nuclear Information System (INIS)

Dar, Shahida

2000-08-01

We review the status of the electric dipole moment (EDM) of neutron in the Standard Model (SM). The contributions of the strong and electroweak interactions are discussed separately. In each case the structure of Lagrangian and the sources of CP violation are specified, and subsequently calculational details are given. These two contributions to the neutron EDM exist in any extension of the SM including supersymmetry, two-doublet models as well as models with more than three generations of fermions. We briefly discuss the status of the neutron EDM in such extensions and give the relevant literature. (author)

Power Reactor Design at Zero Power; Etudes de Reacteurs de Puissance, au Moyen de Machines de Puissance Zero; Konstruktsiya ehnergeticheskogo reaktora nulevoj moshchnosti; Diseno de Reactores Generadores con Ayuda de Reactores de Potencia Nula

Energy Technology Data Exchange (ETDEWEB)

Redman, W. C.; Plumlee, K. E.; Baird, Q. L. [Argonne National Laboratory, Argonne, IL (United States)

1964-02-15

revela que el Laboratorio de Argonne ha venido basindose ampliamente en los sistemas exponenciales y criticos para llevar a cabo sus trabajos en materia de estudio de reactores. Los autores sugieren el papel futuro de estos sistemas al resumir brevemente los programas de trabajo, en curso de ejecucion o en proyecto, mediante los reactores de potencia nula que actualmente existen en Argonne y los que ese Laboratorio proyecta construit. (author) [Russian] Rjalis- sledovatel'skih reaktorov dlja central'nyh jelektrostancij, reaktorov v kachestve dvigate- lej, reaktorov dlja proizvodstva izotopov i ispytatel'nyh reaktorov byl issledovan na Argonskih reaktorah nulevoj moshhnosti, a svjazannye jeksponencial'nye i chisto kriticheskie sborki pozvolili poluchit' osnovnye dannye. Dlja togo, chtoby dat' nagljadnoe predstavle- nie o poslednih jeksperimentah i prodemonstrirovat' bol'shoe raznoobrazie dannyh o kon- strukcii reaktora, kotorye mozhno poluchit' v sistemah s maloj plotnost'ju nejtronnogo poto- ka, rassmatrivajutsja sledujushhie jeksperimental'nye programmy: 1. Izuchenie svojstv torievo-uranovogo topliva v tjazheloj vode s osobym uporom na trebova- nija, pred{sup j}avljaemye k konstrukcii vtoroj aktivnoj zony dlja Argonskogo jeksperimental'- nogo kipjashhego reaktora. 2. Maket predpologaemogo issledovatel'skogo reaktora s vysokoj plotnost'ju nejtronnogo potoka dlja podtverzhdenija raschetov konstrukcii, vybora optimal'noj geometrii i ocenki vlijanija vygoranija topliva. 3. Opredelenie harakteristik raspredelenija jenergii i vlijanija na reaktivnost' zatoplenija toplivnogo jelementa dlja kombinirovannyh ispytanij kipjashhego reaktora s peregrevom. 4. Konstrukcija aktivnoj zony proizvodjashhego plutonij reaktora-razmnozhitelja na bystryh nejtronah na urane - 235 s natrievym ohlazhdeniem kak pervoj zagruzki dlja Argonskogo jeksperimental'nogo reaktora-razmnozhitelja II. 5. Issledovanie harakteristik reaktora s vzaimodejstvujushhimi zonami na teplovyh i byst- ryh nejtronah. Pri

Sm-Nd isotope system of oldest granulites of Anabar Shield

International Nuclear Information System (INIS)

Spiridonov, V.G.; Sukhanov, M.K.; Karpenko, S.F.; Lyalikov, A.V.; AN SSSR, Moscow

1991-01-01

The first results of applying Sm-Nd method for dating the oldest basic and ultrabasic rocks of the Anabar Shield are presented. The content and isotopic composition of Sm and Nd were determined by the methods of mass-spectroscopy with isotopic dilution. The obtained values of metamorphic ages (3063 ± 80 million years) are in good agreement with U-Pb method data for zircon

Microstructure and corrosion resistance of Sm-containing Al-Mn-Si-Fe-Cu alloy

Directory of Open Access Journals (Sweden)

Han Yuyin

2017-12-01

Full Text Available Optimizing alloy composition is an effective way to improve physical and chemical properties of automobile heat exchanger materials.A Sm-containing Al-Mn-Si-Fe-Cu alloy was investigated through transmission electron microscopy,scanning electron microscopy,and electrochemical measurement.Experimental results indicated that main phases distributed in the alloy wereα-Al(Mn,FeSi,Al2Sm and Al10Cu7Sm2.Alloying with Sm element could refine the precipitated α-Al(Mn,FeSi phase.Polarization testing results indicated that the corrosion surfacewas mainly composed of pitting pits and corrosion products.Sea water acetic acid test(SWAAT showed that corrosion loss increased first and then slowed downwith increase of the corrosion time.

Formation of hydroxyl radical (sm-bulletOH) in illuminated surface waters contaminated with acidic mine drainage

International Nuclear Information System (INIS)

Allen, J.M.; Lucas, S.; Allen, S.K.

1996-01-01

Formation rates and steady-state concentrations of hydroxyl radical ( sm-bullet OH) in illuminated surface water samples collected in west-central Indiana that receive acidic mine drainage runoff are reported. Formation rates for sm-bullet OH in samples were measured by the addition of 1 x 10 -3 M benzene prior to illuminate in order to effectively scavenge all of the sm-bullet OH formed, thereby yielding phenol. The sm-bullet OH formation rates were calculated from the measured phenol formation rates. Steady-state concentrations of sm-bullet OH were measured by the addition of 5 x 10 -7 M nitrobenzene to the samples prior to illumination. Estimated sunlight sm-bullet OH formation rates range from 16 microM h -1 to 265 microM h -1 . Estimated sunlight steady-state sm-bullet OH concentrations range from 6.7 x 10 -15 to 4.0 x 10 -12 M. Both the formation rates and steady-state concentrations for sm-bullet OH are thus two to three orders of magnitude higher than values reported in the literature for other sunlit surface water samples. Due to the very high rates of formation and steady-state concentrations for sm-bullet OH in these samples, the authors conclude that aqueous-phase reactions involving sm-bullet OH represent a significant pathway by which organic pollutants in illuminated surface waters receiving acidic mine drainage runoff may be consumed

Preparation of Sm3H7 nanoparticles and their application in ammonia synthesis

International Nuclear Information System (INIS)

Liu Tong; Zhang Yaohua; Li Xingguo

2006-01-01

Sm 3 H 7 nanoparticles have been successfully produced by hydrogen plasma-metal reaction (HPMR) method, and then used to synthesize ammonia at 298 K and 1 atm. The morphologies of the Sm 3 H 7 nanoparticles before and after reaction were investigated by transmission electron microscopy, and the crystal structures at different steps by X-ray diffraction. Nessler's test was adopted to detect ammonia. It was found that the passivated Sm 3 H 7 nanoparticles possess polyhedron shape and smooth surface, with the average size of about 50 nm and the specific surface area 11.2 m 2 g -1 . It was proposed that Sm 3 H 7 nanoparticles react with oxygen and nitrogen to form ammonia, but ammonia production is not observable in the case of coarse particles. After ammonia synthesis, the morphology of Sm 3 H 7 nanoparticles changes into spongy surface and the mean particle size and specific surface area increase to 100 nm and 28.6 m 2 g -1 , respectively, due to the release of hydrogen. The hydrogen conversion percentage from samarium hydride is estimated to be 1.5%. Without O 2 , Sm 3 H 7 nanoparticles cannot react with N 2 or N 2 + H 2 at 298 K and 1 atm

Theoretical analysis of nuclear reactors (Phase I), I-V, Part V, Determining the fine flux distribution; Razrada metoda teorijske analize nuklearnih reaktora (I faza) I-V, V Deo, Odredjivanje fine raspodele fluksa

Energy Technology Data Exchange (ETDEWEB)

Pop-Jordanov, J [Institute of Nuclear Sciences Boris Kidric, Vinca, Beograd (Serbia and Montenegro)

1962-07-15

Mono energetic neutron transport equation was solved by Carlson numerical method in cylindrical geometry. S{sub n} code was developed for the digital computer ZUSE Z23. Neutron flux distribution was determined for the RA reactor cell by applying S{sub 4} approximation. Reactor cell was treated as D{sub 2}O-U-D{sub 2}O system. Time of iteration was 185 s. Resena je transportna monoenergetska jednacina numerickom metodom Carlsona u cilindricnoj geometriji. Razvijanje S{sub n} kod za digitalnu masinu ZUSE-Z 23. Odredjena je raspodela fluksa u celiji reaktora RA S{sub 4} aproksimacijom. Celija je tretirana kao D{sub 2}O-U-D{sub 2}O. Vreme iteracije je 185 sec (author)

Measurements of neutron flux in the RA reactor; Merenje karakteristika neutronskog fluksa u reaktoru RA

Energy Technology Data Exchange (ETDEWEB)

Raisic, N [Institute of Nuclear Sciences Boris Kidric, Vinca, Beograd (Serbia and Montenegro)

1961-12-15

This report includes the following separate parts: Thermal neutron flux in the experimental channels od RA reactor; Epithermal neutron flux in the experimental channels od RA reactor; Fast neutron flux in the experimental channels od RA reactor; Thermal neutron flux in the thermal column and biological experimental channel; Neutronic measurements in the RA reactor cell; Temperature reactivity coefficient of the RA reactor; design of the device for measuring the activity of wire. [Serbo-Croat] Ovaj izvestaj sadrzi sledece referate: Fluks termalnih neutrona u eksperimentalnim kanalima reaktora RA; Fluks epitermalnih neutrona u eksperimentalnim kanalima reaktora RA; Fluks brzih neutrona u eksperimentalnim kanalima reaktora RA; Fluks termalnih neurona u termalnoj koloni i bioloskom eksperimentalnom kanalu; Neutronska merenja u elementarnoj celiji reaktora RA; Temperaturni koeficijent reaktivnosti reaktora RA; Projekat uredjaja za merenje radioaktivnosti zice.

Exopolysaccharides play a role in the swarming of the benthic bacterium Pseudoalteromonas sp. SM9913

Directory of Open Access Journals (Sweden)

Ang eLiu

2016-04-01

Full Text Available Most marine bacteria secrete exopolysaccharide (EPS, which is important for bacterial survival in the marine environment. However, it is still unclear whether the self-secreted EPS is involved in marine bacterial motility. Here we studied the role of EPS in the lateral flagella-driven swarming motility of benthic bacterium Pseudoalteromonas sp. SM9913 (SM9913 by a comparison of wild SM9913 and ΔepsT, an EPS synthesis defective mutant. Reduction of EPS production in ΔepsT did not affect the growth rate or the swimming motility, but significantly decreased the swarming motility on a swarming plate, suggesting that the EPS may play a role in SM9913 swarming. However, the expression and assembly of lateral flagella in ΔepsT were not affected. Instead, ΔepsT had a different swarming behavior from wild SM9913. The swarming of ΔepsT did not have an obvious rapid swarming period, and its rate became much lower than that of wild SM9913 after 35 h incubation. An addition of surfactin or SM9913 EPS on the surface of the swarming plate could rescue the swarming level. These results indicate that the self-secreted EPS is required for the swarming of SM9913. This study widens our understanding of the function of the EPS of benthic bacteria.

Operating Experience with the BR-5 Reactor; Experience acquise aupres du reacteur BR-5; Opyt ehkspluatatsii reaktora BR-5; Experiencia practica con el reactor BR-5

Energy Technology Data Exchange (ETDEWEB)

Lejpunskij, A. I.; Kazachkovskij, O. D.; Pinkhasik, M. S.; Aristarkhov, N. N.; Karpov, A. V.; Larin, E. P.; Efimov, I. A.

1963-10-15

remontnykh rabot na radioaktivnom zhidkometallicheskom konture reaktora na bystrykh nejtronakh BR-5. Osveshchayutsya voprosy ehkspluatatsii reaktora posle dostizheniya proektnogo 2%-nogo vygoraniya topliva pri nalichii nekotorogo narusheniya plotnosti otdel'nykh teplovydelyaptsikh ehlementov. Provoditsya opyt po razgruzke aktivnoj zony, issledovaniyu sostoyaniya i germetichnosti teplovydelyaptsikh ehlementov, dezaktivatsii oborudovaniya i truboprovodov I radioaktivnogo kontura posle dostizheniya 5% vygoraniya topliva. (author)

Functional organization of the Sm core in the crystal structure of human U1 snRNP.

Science.gov (United States)

Weber, Gert; Trowitzsch, Simon; Kastner, Berthold; Lührmann, Reinhard; Wahl, Markus C

2010-12-15

U1 small nuclear ribonucleoprotein (snRNP) recognizes the 5'-splice site early during spliceosome assembly. It represents a prototype spliceosomal subunit containing a paradigmatic Sm core RNP. The crystal structure of human U1 snRNP obtained from natively purified material by in situ limited proteolysis at 4.4 Å resolution reveals how the seven Sm proteins, each recognize one nucleotide of the Sm site RNA using their Sm1 and Sm2 motifs. Proteins D1 and D2 guide the snRNA into and out of the Sm ring, and proteins F and E mediate a direct interaction between the Sm site termini. Terminal extensions of proteins D1, D2 and B/B', and extended internal loops in D2 and B/B' support a four-way RNA junction and a 3'-terminal stem-loop on opposite sides of the Sm core RNP, respectively. On a higher organizational level, the core RNP presents multiple attachment sites for the U1-specific 70K protein. The intricate, multi-layered interplay of proteins and RNA rationalizes the hierarchical assembly of U snRNPs in vitro and in vivo.

Experimental study on Response Parameters of Ni-rich NiTi Shape Memory Alloy during Wire Electric Discharge Machining

Science.gov (United States)

Bisaria, Himanshu; Shandilya, Pragya

2018-03-01

Nowadays NiTi SMAs are gaining more prominence due to their unique properties such as superelasticity, shape memory effect, high fatigue strength and many other enriched physical and mechanical properties. The current studies explore the effect of machining parameters namely, peak current (Ip), pulse off time (TOFF), and pulse on time (TON) on wire wear ratio (WWR), and dimensional deviation (DD) in WEDM. It was found that high discharge energy was mainly ascribed to high WWR and DD. The WWR and DD increased with the increase in pulse on time and peak current whereas high pulse off time was favourable for low WWR and DD.

Negative pressure driven phase transformation in Sr doped SmCoO₃.

Science.gov (United States)

Arshad Farhan, M; Javed Akhtar, M

2010-02-24

Atomistic computer simulation techniques based on energy minimization procedures are utilized for the structural investigation of perovskite-type SmCoO(3). A reliable potential model is derived which reproduces both cubic as well as orthorhombic phases of SmCoO(3). We observe a negative chemical pressure induced structural phase transformation from distorted perovskite (orthorhombic) to perfect perovskite (cubic) due to the substitution of Sr(2 + ) at the Sm(3 + ) sites. However, external hydrostatic pressure shows isotropic compression and no pressure-induced structural transformation is observed up to 100 GPa. To maintain the electroneutrality of the system, charge compensation is through oxygen vacancies which results in the brownmillerite-type structure. A defect model is proposed, which is consistent with experimental results. The solution energies for divalent and trivalent cations are also calculated. These results show that the cations having ionic radii less than 0.75 Å will occupy the Co sites and those with ionic radii larger than 0.75 Å will substitute at the Sm sites.

Multiple magnetic transitions in SmCoAsO

Directory of Open Access Journals (Sweden)

Yongliang Chen

2011-12-01

Full Text Available The magnetic properties of SmCoAsO have been investigated. Our results differ from early observations. Complicated magnetism consists of antiferromagnetic, ferromagnetic, ferrimagnetic and paramagnetic, even diamagnetism at low field has been observed. A metamagnetic transition was observed, resulting from a canting of the spins. The interaction between two Co sublattices with canted-structure might take responsibility for the multiple magnetic transitions. Electrical resistivity data indicate that SmCoAsO is metallic conductor with room temperature resistivity of 0.51669 mΩ-cm. Negative magnetoresistance effect suggests a significant suppression of spin-flip scattering by the applied magnetic field. The magnetic phase diagram has been established.

Cytogenetic analysis of {sup 153} Sm-EDTMP in peripheral lymphocytes from patients with bone cancer metastasis; Analise citogenetica do {sup 153} Sm-EDTMP em linfocitos perifericos de pacientes com cancer osseo matastatico

Energy Technology Data Exchange (ETDEWEB)

Silva, M.A. da; Suzuki, M.F.; Rogero, J.R.; Okazaki, K. [Instituto de Pesquisas Energeticas e Nucleares (IPEN), Sao Paulo, SP (Brazil); Guimaraes, M.I.C.C.; Buchpiguel, C.A. [Sao Paulo Univ., SP (Brazil). Faculdade de Medicina. Centro de Medicina Nuclear

2002-07-01

The {sup 153} Sm-EDTMP is a radiopharmaceutical used in nuclear medicine with promising results for the relief of metastatic pain. Therefore, there are few knowledge about the effects of {sup 153} Sm-EDTMP at cellular level. The present study was conducted with the aim of evaluating the cytogenetic effects of {sup 153} Sm-EDTMP in peripheral lymphocytes from patients with bone metastasis (with and without previous radio and/or chemotherapy) by the chromosome aberration technique. For that, the blood samples were collected before and one hour after the endovenous administrations of {sup 153} Sm-EDTMP (mean activity of 42.53 {+-} 5.31 MBq/kg body weight), taking into account the rapid blood clearance. The principal types of structural chromosome aberrations found gaps and breaks, acentric fragments centric rings, double minutes and dicentrics. The statistical analysis showed that the group submitted to previous radio and chemotherapy before{sup 153} Sm-EDTMP administration showed significant difference in chromosome aberrations frequency one hour after the treatment. The analysis of the chromosome modal number and the kinetics of cellular cycle showed no statistical difference among the groups, suggesting that the treatment with {sup 153} Sm-EDTMP, did not influence these parameters. The obtained data showed that the therapy with {sup 153} Sm-EDTMP induced a few quantity of cytogenetic damages in peripheral lymphocytes one hour after its administration in patients, although, theoretically, a long term stochastic effect cannot be disregarded. (author)

Autophagic kinases SmVPS34 and SmVPS15 are required for viability in the filamentous ascomycete Sordaria macrospora.

Science.gov (United States)

Voigt, Oliver; Herzog, Britta; Jakobshagen, Antonia; Pöggeler, Stefanie

2014-01-01

Autophagy is a tightly controlled degradation process of all eukaryotes. It includes the sequestration of cytoplasmic contents and organelles within a double-membraned autophagosome. Autophagy involves core autophagy related (atg) genes as well as genes regulating vesicle trafficking. Previously, we analyzed the impact of proteins of the core autophagic machinery SmATG7, SmATG8 and SmATG4 on the sexual and vegetative development of the filamentous ascomycete Sordaria macrospora. While deletion of Smatg8 and Smatg4 abolished fruiting-body formation and impaired vegetative growth, Smatg7 is required for viability. In yeast, the phosphatidylinositol 3-kinase vacuolar protein sorting 34 (Vps34) and its myristoylated membrane targeting unit, the protein kinase Vps15 have been shown to be important regulators of autophagy and vacuolar protein sorting. However, their exact role in filamentous ascomycetes remains elusive. To determine the function of Smvps34 and Smvps15 we isolated genes with high sequence similarity to Saccharomyces cerevisiae VPS34 and VPS15. For both genes we were not able to generate a homokaryotic knockout mutant in S. macrospora, suggesting that Smvps34 and Smvps15 are required for viability. Furthermore, we analyzed the repertoire of vps genes encoded by S. macrospora and could identify putative homologs of nearly all of the 61 VPS genes of S. cerevisiae. Copyright © 2013 Elsevier GmbH. All rights reserved.

Giant magnetic coercivity in YNi{sub 4}B-type SmNi{sub 3}TB (T=Mn–Cu) solid solutions

Energy Technology Data Exchange (ETDEWEB)

Yao, Jinlei; Yan, Chang [Research Center for Solid State Physics and Materials, School of Mathematics and Physics, Suzhou University of Science and Technology, Suzhou 215009 (China); Yapaskurt, V.O. [Department of Petrology, Geological Faculty Moscow State University, Leninskie Gory, Moscow 119992 (Russian Federation); Morozkin, A.V., E-mail: morozkin@tech.chem.msu.ru [Department of Chemistry, Moscow State University, Leninskie Gory, House 1, Building 3, GSP-2, Moscow 119992 (Russian Federation)

2016-12-01

The effects of transition metal substitution for Ni on the magnetic properties of the YNi{sub 4}B-type SmNi{sub 4}B via SmNi{sub 3}TB (T=Mn, Fe, Co, Cu) solid solutions have been investigated. SmNi{sub 4}B, SmNi{sub 3}MnB, SmNi{sub 3}FeB, SmNi{sub 3}CoB and SmNi{sub 3}CuB show ferromagnetic ordering at 40 K, 210 K, 322 K, 90 K and 57 K and field sensitive metamagnetic-like transitions at 15 K, 100 K, 185 K, 55 K and 15 K in a magnetic field of 10 kOe, respectively. The magnetocaloric effects of SmNi{sub 3}TB (T=Mn–Cu) were calculated in terms of isothermal magnetic entropy change (ΔS{sub m}). The magnetic entropy ΔS{sub m} reaches value of –0.94 J/kg K at 40 K for SmNi{sub 4}B, –1.5 J/kg K at 205 K for SmNi{sub 3}MnB, –0.54 J/kg K at 320 K for SmNi{sub 3}FeB, –0.49 J/kg K at 90 K for SmNi{sub 3}CoB and –0.54 J/kg K at 60 K for SmNi{sub 3}CuB in field change of 0–50 kOe around the Curie temperature. They show positive ΔS{sub m} of +0.71 J/kg K at ~10 K for SmNi{sub 4}B, +1.69 J/kg K at 30 K for SmNi{sub 3}MnB, +0.89 J/kg K at 110 K for SmNi{sub 3}FeB, +1.08 J/kg K at 25 K for SmNi{sub 3}CoB and +1.12 J/kg K at 10 K for SmNi{sub 3}CuB in field change of 0–50 kOe around the low temperature metamagnetic-like transition. Below the field induced transition temperature (change of magnetic structure), SmNi{sub 3}TB (T=Mn–Cu) exhibits giant magnetic coercivity of 74 kOe at 5 K for SmNi{sub 4}B, 69 kOe at 20 K (90 kOe at 10 K) for SmNi{sub 3}MnB, 77 kOe at 60 K for SmNi{sub 3}FeB, 88 kOe at 20 K for SmNi{sub 3}CoB and 52 kOe at 5 K for SmNi{sub 3}CuB. - Highlights: • YNi{sub 4}B-type SmNi{sub 3}{Mn, Fe, Co, Ni, Cu}B exhibit the Curie points at 39–322 K. • SmNi{sub 3}{Mn, Fe, Co, Ni, Cu}B show field induced transition at 15–185 K. • SmNi{sub 3}MnB shows huge magnetic hysteresis with coercive field of 69 kOe at 20 K. • SmNi{sub 3}FeB shows huge magnetic hysteresis with coercive field of 77 kOe at 60 K. • SmNi{sub 3}CoB shows giant coercive

Complexes of Sm(III) and Dy(III) with piperazines

Energy Technology Data Exchange (ETDEWEB)

Manhas, B S; Trikha, A K [Punjabi Univ., Patiala (India). Dept. of Chemistry; Singh, M [Guru Nanak Dev Univ., Amritsar (India). Dept. of Chemistry

1981-09-01

Complexes of SmCl/sub 3/, DyCl/sub 3/, Sm(NO/sub 3/)/sub 3/ and Dy(NO/sub 3/) with piperazine, N-methylpiperazine, 2-methylpiperazine, N-phenyl-piperazine and N, N'-dimethyl-piperazine have been prepared and characterized on the basis of elemental analyses, IR and electronic reflectance spectra and magnetic susceptibility measurements. IR data indicate that the ligands are coordinated in the chair conformation giving polymeric bridged complexes and that the nitrate group is bidentate. Coordination numbers from 6 to 12 are proposed for the lanthanide ions.

Bioactivity assays and application of 125I labeled human mouse chimeric anti-CD22 monoclonal antibody SM03

International Nuclear Information System (INIS)

Lu Pingping; Meng Zhiyun; Dou Guifang; Wu Yingliang; Wang Minwei

2008-01-01

To investigate the bioactivity and application of 125 I labeled human mouse chimeric monoclonal SM03, SM03 was labeled with 125 I using Indogen method. The labeled mixture was purified by Sephacryl S-300 HR separation chromospectry. The purity and concentration of separated fractions were determined by HPLC and Protein Assay Kit, respectively. Competitive binding method and ELISA method were used for bioactivity assays. 125 I-SM03 was applied to screen cell lines which express the most abundant CD22 antigen. The purity and recovery of 125 I-SM03 were >99% and >47%, respectively. The bioactivity of 125 I- SM03 and SM03 hasn't significant difference in statistics. Ramos cell line had the strongest special radioactivity when 125 I-SM03 bound with in Raji, Daudi and Ramos cell lines. Indogen method is a good way to label Human mouse chimeric anti-CD22 monoclonal antibody SM03 and the label will not affect the activity of SM03. The 125 I-SM03 not only can be used for detect agent, but also may be put into market for NHL therapy. (authors)

Apparent partition coefficient in octanol-water and binding percentage to BSA of 153Sm(113,117Snm) complexes

International Nuclear Information System (INIS)

Yang Yuqing; Luo Shunzhong; Wang Guanquan; He Jiaheng; Bing Wenzeng; Pu Manfei; Wei Hongyuan; Wang Wenjin

2004-01-01

Apparent partition coefficient in octanol-water and binding percentage to BSA of 153 Sm-NTMP, 153 Sm-HEDTMP, 153 Sm-DCTMP, 153 Sm-EDTMP, 153 Sm-DTPMP, 113,117 Sn m -EDTMP, 113,117 Sn m -HEDTMP, 113,117 Sn m -DTPMP are measured. The results show that there is a linear relationship between the relative magnitude of the apparent partition coefficient in octanol-water and the relative magnitude of the binding percentage to BSA of these 153 Sm( 113,117 Sn m ) complexes. This linear relationship provides a new method for determination of the apparent partition coefficient in octanol-water of 153 Sm( 113,117 Sn m ) complexes of this kind. This linear relationship also implicates that hydrophobic force plays an important role in the binding of 153 Sm( 113,117 Sn m ) complexes to BSA

Phase evolution and its effects on the magnetic performance of nanocrystalline SmCo7 alloy

International Nuclear Information System (INIS)

Zhang Zhexu; Song Xiaoyan; Xu Wenwu

2011-01-01

The evolution of the phase constitution and the microstructure, as well as their effects on magnetic performance, were investigated systematically using a prepared nanocrystalline single-phase SmCo 7 alloy as the starting material for a series of annealing processes. The SmCo 7 (1:7 H) phase was discovered to have a good single-phase stability from room temperature up to 600 deg. C. The destabilization of the SmCo 7 phase results in the formation of the Sm 2 Co 17 (2:17 R) and SmCo 5 (1:5 H) phases, which exist as phase-transformation twins and particulate precipitates, respectively, with a completely coherent relationship with the 1:7 H parent phase. For the first time the formation mechanism of the 2:17 R phase-transformation twins has been proposed, in which the ordered substitution of 1/3 of the Sm atoms by Co-Co dumbbell pairs along two particular crystal directions was demonstrated. The characteristic width values of the 2:17 R phase-transformation twins, as deduced from this model of the mechanism, were unambiguously verified by the experimental results. Among the SmCo 7 alloys with various phase constitutions and microstructures, the best magnetic properties were obtained in the nanocrystalline 1:7 H single-phase alloys. The present work may promote a new understanding of nanoscale-stabilized single-phase SmCo 7 and its potential applications as unique high-temperature permanent magnets.

Study on irradiation conditions of producing 153Sm with natural abundance samarium target

International Nuclear Information System (INIS)

Du Jin; Jin Xiaohai; Bai Hongsheng; Liu Yuemin; Chen Daming; Wang Fan

1998-01-01

Irradiation conditions of natural abundance 152 Sm targets in different forms are studied in the heavy water reactor and the light water swimming pool reactor at the China Institute of Atomic Energy. The result shows that the specific activity of 153 Sm in liquid form target irradiated in the light water swimming pool reactor is two times greater than that in solid form target. The radionuclide purity of 153 Sm is more than 99%, which can meet the needs of clinical application

Cytogenetic effect of 153 Sm-EDTMP in peripheral lymphocytes of patients with metastatic cancer

International Nuclear Information System (INIS)

Silva, Marcia Augusta da

2001-01-01

The 153 Sm-EDTMP is a radiopharmaceutical used in nuclear medicine with promising results for the relief of metastatic pain. Therefore, there are few knowledge about the effects of 153 Sm-EDTMP at cellular level. The present study was conduced with the aim of evaluating the cytogenetic effects of 153 Sm-EDTMP in peripheral lymphocytes from patients with bone metastasis (with and without previous radio and/or chemotherapy) by the chromosome aberration technique, either in vivo or in vitro. For that, the blood samples were collected before and one hour after the endovenous administration of 153 Sm-EDTMP (mean activity of 42.53+/-5.31 MBq/kg body weight), taking into account the rapid blood clearance. The principal types of structural chromosome aberrations found gaps and breaks, acentric fragments centric rings, double minutes and dicentrics. The statistical analysis showed that the group submitted to previous radio and chemotherapy before 153 Sm-EDTMP administration showed significant difference in chromosome aberrations frequency one hour after the treatment. The analysis of the chromosome modal number and the kinetics of cellular cycle showed no statistical difference among the groups, suggesting that the treatment with 153 Sm-EDTMP, did not influence these parameters. The carrier molecule, EDTMP, did not influence the induction of chromosome aberration. In relation to the in vitro assays, the obtained data of peripheral lymphocytes of healthy donors and patients with no previous treatment exposed to different radioactive concentration of 153 Sm-EDTMP (0.046 - 1.110 MBq/mL) were better adjusted by linear regression model (Y=A+BX). The chromosome damage induced by 153 Sm-EDTMP observed in vitro was about 2 fold higher than that found in vivo for the group of patients with no previous treatment. The obtained data showed that the therapy with 153 Sm-EDTMP induced a few quantity of cytogenetic damages in peripheral lymphocytes on hour after its administration in

Enhanced Photoluminescence of Sm3+/Bi3+ Co-Doped La2O3 Nanophosphors by Combustion Synthesis

Science.gov (United States)

Zhang, Ying; Wu, Muying; Zhang, W. F.

Nanosized La2O3:Sm3+ and La2O3:Sm3+, Bi3+ phosphor powders were prepared via combustion synthesis. The structures and morphology were examined using powder X-ray diffraction and transmission electron microscope, respectively. The photoluminescence spectra were investigated at different doping concentrations of Sm3+ and Bi3+ ions. The results indicate that La2O3:Sm3+ (Bi3+) exhibited good crystallinity and spherical-like particles. All phosphors give emission bands centered at 564, 608 and 650 nm corresponding to 4G5/2→6HJ (J=5/2, 7/2 and 9/2) transitions of Sm3+ ions, respectively. Interestingly, the emission intensity of Sm3+ ions is significantly enhanced with the addition of Bi3+ ions to La2O3:Sm3+ and the maximum occurs at a Bi3+ concentration of 0.8 mol%. The La2O3:Sm3+, Bi3+ phosphor with highly enhanced luminescence is very encouraging for applications in display and tunable solid lasers.

Photoluminescence properties of a new orange-red-emitting Sm(3+)-La3SbO7 phosphor.

Science.gov (United States)

Li, Zeng-Mei; Deng, Li-Gang; Zhao, Shan-Cang; Zhang, Shu-Qiu; Guo, Chang-Ying; Liang, Jing-Yun; Yue, Hui; Wan, Chun-Yan

2016-03-01

The antimonate compound La3SbO7 has high chemical stability, lattice stiffness and thermal stability. Orange-red-emitting antimonate-based phosphors La3SbO7:xSm(3+) (x = 0.02, 0.05, 0.08, 0.10, 0.15, 0.20 and 0.25) were synthesized. The phase structure and photoluminescence properties of these phosphors were investigated. The emission spectrum obtained on excitation at 407 nm contained exclusively the characteristic emissions of Sm(3+) at 568, 608, 654 and 716 nm, which correspond to the transitions from (4)G5/2 to (6)H5/2, (6)H7/2, (6)H9/2 and (6)H11/2 of Sm(3+), respectively. The strongest emission was located at 608 nm due to the (4)G5/2→(6)H7/2 transition of Sm(3+), generating bright orange-red light. The critical quenching concentration of Sm(3+) in La3SbO7:Sm(3+) phosphor was determined as 10% and the energy transfer between Sm(3+) was found to be through an exchange interaction. The International Commission on Illumination chromaticity coordinates of the La3SbO7:0.10Sm(3+) phosphors are located in the orange-red region. The La3SbO7:Sm(3+) phosphors may be potentially used as red phosphors for white light-emitting diodes. Copyright © 2015 John Wiley & Sons, Ltd.

Experimental cross section for the {sup 152}Sm(n, γ){sup 153}Sm reaction at 0.0334 eV

Energy Technology Data Exchange (ETDEWEB)

Uddin, M. Shuza; Datta, Tapash Kumar; Hossain, Syed Mohammod; Zakaria, A.K.M.; Islam, Mohammad Amirul; Naher, Kamrun; Shariff, M. Asad; Yunus, S.M. [Atomic Energy Research Establishment, Dhaka (Bangladesh). Inst. of Nuclear Science and Technology; Afroze, Nasmin [Atomic Energy Research Establishment, Dhaka (Bangladesh). Inst. of Nuclear Science and Technology; Jahangirnagar Univ., Dhaka (Bangladesh). Dept. of Physics; Islam, S.M. Ajharul [Jahangirnagar Univ., Dhaka (Bangladesh). Dept. of Physics

2014-10-01

The neutron capture cross section for the {sup 152}Sm(n, γ){sup 153}Sm reaction at an energy of 0.0334 eV was measured for the first time using monochromatic neutrons of a powder diffractometer at the TRIGA Mark II nuclear reactor at Dhaka, Bangladesh. The {sup 197}Au(n, γ){sup 198}Au reaction was used to monitor the neutron beam intensity. The radioactivity of the products was determined via high resolution γ-ray spectrometry. The obtained cross section value is 184 ± 22b, which is consistent with both the ENDF/B-VII and TENDL-2012 data libraries. The measured value at 0.0334 eV and the previous data at 0.0536 eV confirm the reliability of the data in the above libraries. (orig.)

INTERACTION MODE BETWEEN METHYLENE BLUE-Sm(III ...

African Journals Online (AJOL)

Preferred Customer

between methylene blue (MB)-Sm(III) complex and herring sperm DNA by using acridine orange .... the complex was recorded as KBr pellets on Spectrum One FTIR system (PE Company, USA), ..... mechanism of drugs and drug design.

Formation of SmFe{sub 5}(0001) ordered alloy thin films on Cu(111) single-crystal underlayers

Energy Technology Data Exchange (ETDEWEB)

Yabuhara, Osamu; Ohtake, Mitsuru; Nukaga, Yuri; Futamoto, Masaaki [Faculty of Science and Engineering, Chuo University, 1-13-27 Kasuga, Bunkyo-ku, Tokyo 112-8551 (Japan); Kirino, Fumiyoshi, E-mail: yabuhara@futamoto.elect.chuo-u.ac.j [Graduate School of Fine Arts, Tokyo National University of Fine Arts and Music, 12-8 Ueno-koen, Taito-ku, Tokyo 110-8714 (Japan)

2010-01-01

SmFe{sub 5}(0001) single-crystal thin films are prepared by molecular beam epitaxy employing Cu(111) single-crystal underlayers on MgO(111) substrates. The Cu atoms diffuse into the Sm-Fe layer and substitute the Fe sites in SmFe{sub 5} structure forming an alloy compound of Sm(Fe,Cu){sub 5}. The Sm(Fe,Cu){sub 5} film is more Cu enriched with increasing the substrate temperature. The Cu underlayer plays an important role in assisting the formation of the ordered phase.

Investigations on optical properties of Sm3+ ion doped boro-phosphate glasses

Science.gov (United States)

Vijayakumar, R.; Suthanthirakumar, P.; Karthikeyan, P.; Marimuthu, K.

2015-06-01

The Sm3+ doped Boro-phosphate glasses with the chemical composition 60H3BO3+20Li2CO3+10ZnO+(10-x) H6NO4P+xSm2O3 (where x= 0.1, 0.5, 1 and 2 in wt%) have been prepared by melt quenching technique. The prepared glasses were characterized through optical absorption and luminescence spectral measurements. The band gap energies corresponding to the direct and indirect allowed transitions and the Urbach's energy values were estimated from the absorption spectra. Judd-Ofelt intensity parameters have been derived to predict the radiative properties of the various emission transitions. In order to identify the emission color of the prepared glasses, the emission intensities were analyzed using CIE 1931 color chromaticity diagram. The energy transfer process takes place between Sm3+-Sm3+ ions through cross-relaxation mechanism have also been investigated and the results were discussed and reported.

Crystal structure of Sm(NO3)3x6H2O

International Nuclear Information System (INIS)

Espenbetov, A.A.; Gerr, R.G.; Struchkov, Yu.T.; Sal'nikova, N.A.; Akimov, V.M.; Odinets, Z.K.

1985-01-01

X-ray diffraction study of a salt, prepared when mixing concentrated nitric acid solutions of NaNO 3 and Sm(NO 3 ) 3 , has been carried out. It is established, that the salt is a concretion of two crystals: NaNO 3 and Sm(NO 3 ) 3 x6H 2 O (1). X-ray diffraction study of 1 is carried out (lambda Mo, diffractometer, 1511 reflections, the method of heavy atom, the least square method in anisotropic approximation up to R=0.0348). The crystals of 1 are triclinic: a=6.755, b=9.168, c=11.684 A, α=69.93, β=88.86, γ=69.28, Z=2, Fedorov group P anti 1. Symmetery of 10-vertex coordination polyhedron (CP) of Sm atom is close to Csub(s). Sm atom coordination can be described as 4;5:1. Four H 2 O molecules are included into CP, at the expense of two remaining H 2 O molecules CP are bound with each other

Origin of perpendicular magnetic anisotropy of SmCo5 thin films with Cu underlayer

International Nuclear Information System (INIS)

Sayama, Junichi; Mizutani, Kazuki; Asahi, Toru; Ariake, Jun; Ouchi, Kazuhiro; Osaka, Tetsuya

2006-01-01

Effects of the Cu underlayer thickness and the addition of Cu to a Sm-Co layer on magnetic properties and microstructure of SmCo 5 thin films exhibiting perpendicular magnetic anisotropy were studied. The origin of the perpendicular magnetic anisotropy was discussed from these experimental results. A thick Cu underlayer of more than 100 nm brought about high perpendicular magnetic anisotropy leading to the squareness ratio equal to unity. The Cu addition enhanced the perpendicular magnetic anisotropy and reduced the Cu underlayer thickness required to obtain the squareness ratio of unity. X-ray diffractometry showed that the crystalline orientation of the Sm-Co layer did not correlate with that of the Cu underlayer. Auger electron spectroscopy revealed that Cu atoms were diffused up to the Sm-Co layer from the Cu underlayer. From the results, Cu atoms existing in the Sm-Co layer were suggested to be strongly related with an appearance of the perpendicular magnetic anisotropy by introducing the Cu underlayer

Recycling of SmCo5 magnets by HD process

Science.gov (United States)

Eldosouky, Anas; Škulj, Irena

2018-05-01

Hydrogen decrepitation process has been applied for the first time for the direct recycling of SmCo5 magnets. Industrially produced sintered SmCo5 magnets were decrepitated by hydrogen gas at a pressure of 1 bar to 9.5 bar at room temperature in a planetary rotating jar. After decrepitation, the starting sintered magnets were reduced to a powder with a particle size of less than 200 μm. The produced powder was used for the preparation of recycled SmCo5 magnets. Scanning electron microscopy, energy-dispersive X-ray spectroscopy, X-ray diffraction studies and magnetic measurements were used to follow the decrepitation and the sintering processes. The measured remanence and maximum energy product of the recycled magnet are 0.94 T and 171.1 kJ/m3, respectively, in comparison with 0.91 T and 156.8 kJ/m3, respectively for the original magnet before recycling. It was also observed that, there is refinement in the microstructure after recycling in comparison to the original magnet.

New NaSrPO4:Sm phosphor as orange-red emitting material

Indian Academy of Sciences (India)

Because NaSr1−xPO4:xSm3+ phosphor features a high colour-rendering index and chemical stability, it is potentially ... use blue LED chips (GaN or InGaN) with a yellow phosphor ... excitation by doping Sm3+ rare earth ions into a suitable.

The Material Supply Adjustment Process in RAMF-SM, Step 2

Science.gov (United States)

2016-06-01

I N S T I T U T E F O R D E F E N S E A N A L Y S E S The Material Supply Adjustment Process in RAMF-SM, Step 2 Eleanor L. Schwartz James S...5564 The Material Supply Adjustment Process in RAMF-SM, Step 2 Eleanor L. Schwartz James S. Thomason, Project Leader This page is intentionally blank...9 1. Inputs and Outputs .......................................................................................10 2. Specific Steps of the PEAP

Polarized spectral properties of Sm3+:LiYF4 crystal

International Nuclear Information System (INIS)

Wang, G.Q.; Lin, Y.F.; Gong, X.H.; Chen, Y.J.; Huang, J.H.; Luo, Z.D.; Huang, Y.D.

2014-01-01

A trivalent samarium-doped LiYF 4 single crystal was grown by the vertical Bridgman technique. Its polarized absorption and fluorescence spectra and fluorescence decay curves were recorded at room temperature. On the basis of the Judd–Ofelt theory, the spectral parameters of the Sm 3+ :LiYF 4 crystal were calculated. The emission cross sections for the 4 G 5/2 → 6 H J (J=5/2, 7/2. 9/2, and 11/2) transitions of special interest for visible laser application were obtained by the Fuchtbauer–Ladenburg formula. -- Highlights: • Polarized spectral properties of Sm 3+ :LiYF 4 crystal at room temperature were analyzed in detail. • The emission cross sections for the transitions of special interest for visible laser application are calculated. • Sm 3+ :LiYF 4 is a promising laser material for 401 nm GaN LD pumped 605 nm visible laser

Observation of dipole bands in 144Sm

International Nuclear Information System (INIS)

Raut, R.; Ganguly, S.; Kshetri, R.; Banerjee, P.; Bhattacharya, S.; Dasmahapatra, B.; Mukherjee, A.; Sahasarkar, M.; Goswami, A.; Basu, S.K.; Bhattacharjee, T.; Mukherjee, G.; Chakraborty, A.; Ghughre, S.S.; Krishichayan; Mukhopadhyay, S.; Gangopadhyay, G.; Singh, A.K.

2007-01-01

The nucleus 144 Sm (Z=62, N=82), with its proximity to the shell closure and possibilities of particles and holes occupying high j orbitals, following appropriate excitations, is a suitable system for observation of dipole (MR) bands

Safety and feasibility of percutaneous vertebroplasty with radioactive {sup 153}Sm PMMA in an animal model

Energy Technology Data Exchange (ETDEWEB)

Lu Jun [Department of Radiotherapy, Xijing Hospital, Fourth Military Medical University, 15 West Changle Road, Xi' an 710032, Shaanxi Province (China); Deng Jinglan, E-mail: dengjinglan@gmail.com [Department of Nuclear Medicine, Xijing Hospital, Fourth Military Medical University, 15 West Changle Road, Xi' an 710032, Shaanxi Province (China); Zhao Haitao [Department of Radiology, Xijing Hospital, Fourth Military Medical University, 15 West Changle Road, Xi' an 710032, Shaanxi Province (China); Shi Mei [Department of Radiotherapy, Xijing Hospital, Fourth Military Medical University, 15 West Changle Road, Xi' an 710032, Shaanxi Province (China); Wang Jing [Department of Nuclear Medicine, Xijing Hospital, Fourth Military Medical University, 15 West Changle Road, Xi' an 710032, Shaanxi Province (China); Zhao Lina [Department of Radiotherapy, Xijing Hospital, Fourth Military Medical University, 15 West Changle Road, Xi' an 710032, Shaanxi Province (China)

2011-05-15

Purpose: We investigated the safety and feasibility of the combination of samarium-153-ethylenediamine tetramethylene phosphonate ({sup 153}Sm-EDTMP)-incorporated bone cement (BC) with percutaneous vertebroplasty (PVP) in dogs. Methods and materials: {sup 153}Sm-EDTMP-incorporated BC was prepared by combining solid {sup 153}Sm-EDTMP and polymethylmethacrylate (PMMA) immediately before PVP. It was then injected into the vertebrae of four healthy mongrel dogs (two males and two females) by PVP under CT guidance. Each dog was subjected to five PVP sessions at a {sup 153}Sm-EDTMP dose of 30-70 mCi. The suppressive effect of local injection of {sup 153}Sm-EDTMP on the hematopoietic system was evaluated through counting of peripheral blood cells. Distribution of {sup 153}Sm-EDTMP-incorporated BC and the status of tissues adjacent to injected vertebrae were evaluated with SPECT, CT and MRI. Histopathology was carried out to assess the influence of PVP on the vertebra and adjacent tissues at the microscopic level. Results: PVP was done successfully, and all dogs exhibited normal behavior and stable physical signs after procedures. {sup 153}Sm-EDTMP-incorporated BC was concentrated mainly in target vertebrae, and the peripheral blood cells remained within normal range. The spinal cord and tissues around BC did not exhibit signs of injury even when the dosage of {sup 153}Sm-EDTMP increased from 30 mCi to 70 mCi. Conclusion: A dose lower than 70 mCi of {sup 153}Sm is safe when it was injected into vertebrae. {sup 153}Sm-EDTMP-incorporated BC did not influence the effect of PVP. This means might strengthen anti-tumor activity locally for vertebra with osseous metastasis without damaging adjacent tissues.

Sm/Ti co-substituted bismuth ferrite multiferroics: reciprocity between tetragonality and piezoelectricity.

Science.gov (United States)

Jha, Pardeep K; Jha, Priyanka A; Singh, Prabhakar; Ranjan, Rajeev; Dwivedi, R K

2017-10-04

BiFeO 3 (BFO) systems co-modified with Ti, Sm and Sm-Ti have been investigated for piezoelectricity together with dielectric and multiferroic properties. Structural studies revealed the coexistence of orthorhombic and rhombohedral (R3c) phases for x > 0.12. Impurity phases were shown to have hardly any effect on the remanent magnetization, which rather depends on the Fe-O-Fe bond angle. The dielectric loss was reduced considerably by substitution. A correlation between the piezoelectric coefficient and tetragonality was observed in these samples. BFO co-substituted with Sm-Ti exhibited a high piezoelectric coefficient with better ferroic properties, which revealed a unique combination of green piezoelectricity and multiferroicity.

Evaluation of the biological and scanning distribution of hydroxyapatite-153Sm radiotherapeutic agent

International Nuclear Information System (INIS)

Herrera, J.; Paredes, N.; Portilla, A.; Miranda, J.; Carrillo, D.

1999-01-01

Fixation of 153 Sm labeled hydroxyapatite (HA) in the synovial capsule and extra articular localization were evaluated by means of biological distribution tests and gamma scanning studies. These were carried out using HA- 153 Sm with particle size ranging between 5 and μm, and radiochemical purity above 99%. Animal models used were wistar rats and new zealand rabbits. Rabbits were injected with 7,4 MBq of HA- 153 Sm while rats received between 1,85 and 92,6 MBq of HA- 153 Sm. In both cases injection was given in the intra articular area. After injection, scanning images were obtained in rabbits on the 1 st , 3 rd and 7 st day and in rats on the 2 nd and 7 th day. Biological distribution studies are conducted in the 2 hours to 9 days range in rats and one the 7 th day in rabbits. No extra articular localization of HA- 153 Sm was found in scanning conducted on rabbits by the 1 st , 3 rd and 7 st day after injection, neither on rats by the 2 nd and 7 th day. Biological distributions for rabbits and rats show localization above 99% in the intra articular area, during the evaluated periods of time. The evaluations of the biological distribution and the scintigraphic images show that fixation of HA- 153 Sm in the synovial capsule up to the 9 th day is very high

CDCC calculations of fusion of 6Li with targets 144Sm and 154Sm: effect of resonance states

Science.gov (United States)

Gómez Camacho, A.; Lubian, J.; Zhang, H. Q.; Zhou, Shan-Gui

2017-12-01

Continuum Discretized Coupled-Channel (CDCC) model calculations of total, complete and incomplete fusion cross sections for reactions of the weakly bound 6Li with 144,154Sm targets at energies around the Coulomb barrier are presented. In the cluster structure frame of 6Li→α+d, short-range absorption potentials are considered for the interactions between the ground state of the projectile 6Li and α-d fragments with the target. In order to separately calculate complete and incomplete fusion and to reduce double-counting, the corresponding absorption potentials are chosen to be of different range. Couplings to low-lying excited states 2+, 3- of 144Sm and 2+, 4+ of 154Sm are included. So, the effect on total fusion from the excited states of the target is investigated. Similarly, the effect on fusion due to couplings to resonance breakup states of 6Li, namely, l=2, J π =3+,2+,1+ is also calculated. The latter effect is determined by using two approaches, (a) by considering only resonance state couplings and (b) by omitting these states from the full discretized energy space. Among other things, it is found that both resonance and non-resonance continuum breakup couplings produce fusion suppression at all the energies considered. A. Gómez Camacho from CONACYT, México, J. Lubian from CNPq, FAPERJ, Pronex, Brazil. S.G.Z was partly supported by the NSF of China (11120101005, 11275248, 11525524, 11621131001, 11647601, 11711540016), 973 Program of China (2013CB834400) and the Key Research Program of Frontier Sciences of CAS. H.Q.Z. from NSF China (11375266)

Plasmon-enhanced luminescence of Sm complex using silver nanoparticles in Polyvinyl Alcohol

Energy Technology Data Exchange (ETDEWEB)

Kaur, Gagandeep; Verma, R.K.; Rai, D.K. [Laser and Spectroscopy Laboratory, Department of Physics, Banaras Hindu University, India 221005 (India); Rai, S.B., E-mail: sbrai49@yahoo.co.in [Laser and Spectroscopy Laboratory, Department of Physics, Banaras Hindu University, India 221005 (India)

2012-07-15

Silver (Ag) nanoparticles (NPs) were prepared by laser ablation in water with an aim to enhance the luminescence of rare earth coordinated complex in polymer host. A fixed concentration of the complex containing Samarium (Sm), Salicylic acid (Sal) and 1, 10-phenanthroline (Phen) were combined with different concentrations of silver NPs in PolyVinyl Alcohol at room temperature. Absorption spectrum and XRD patterns of the sample show that the Sm(Sal){sub 3}Phen complex is accompanied by Ag NPs. The luminescence from the complex was recorded in the presence and absence of Ag NPs using two different excitation wavelengths viz. 400 and 355 nm. Of these, 400 nm radiation falls in the surface plasmon resonance of Ag NPs. It was found that the Ag NPs led to a significant enhancement in luminescence of the complex. Surprisingly, a high concentration of Ag NPs tends to quench the luminescence. - Highlights: Black-Right-Pointing-Pointer Sm complex with Ag nanoparticles in PVA was prepared at room temperature. Black-Right-Pointing-Pointer UV-vis absorption and XRD confirms the presence of Sm complex and Ag NPs. Black-Right-Pointing-Pointer Enhancement in luminescence of complex was observed with Ag NPs. Black-Right-Pointing-Pointer Coupling between radiative transitions of Sm and SPR of NPs enhances the emission. Black-Right-Pointing-Pointer The higher concentration of Ag NPs quenches the luminescence of the complex.

Sm isotope composition and Sm/Eu ratio determination in an irradiated 153Eu sample by ion exchange chromatography-quadrupole inductively coupled plasma mass spectrometry combined with double spike isotope dilution technique

International Nuclear Information System (INIS)

Bourgeois, M.; Isnard, H.; Gourgiotis, A.; Stadelmann, G.; Gautier, C.; Mialle, S.; Nonell, A.; Chartier, F.

2011-01-01

Within the framework of the research undertaken by the French Atomic Energy Commission on transmutation of long-lived radionuclides, targets of highly enriched actinides and fission products were irradiated in the fast neutron reactor Phenix. Precise and accurate measurements of the isotopic and elemental composition of the enriched elements are therefore required. In order to obtain the uncertainties of several per mil and to reduce handling time and exposure to analyst on radioactive material, the on-line coupling of ion exchange chromatography with quadrupole inductively coupled plasma mass spectrometry has been associated with the technique of the double spike isotope dilution. We present in this paper the results obtained on an irradiated sample of Europium oxide powder (enriched at 99.13% in 153 Eu). After irradiation of around 5 mg of Eu 2 O 3 powder the theoretical calculations predict the formation of several micrograms of gadolinium and samarium isotopes. In relation to the very high activity of the sample after irradiation and the very low quantity of Sm formed, the on-line ion exchange chromatography separation of Gd, Sm and Eu before Sm isotope ratio measurements has been developed for the quantification of the 152 Sm/ 153 Eu ratio. These on-line measurements were associated with the double spike isotope dilution technique after calibration of a 147 Sm/ 151 Eu spike solution. The external reproducibility of Sm isotopic ratios was determined to be around 0.5% (2 σ) resulting in a final uncertainty on the 152 Sm/ 153 Eu ratio of around 1% (2 σ). These on-line measurements present therefore a robust and high-throughput alternative to the thermal-ionisation mass spectrometry technique used so far in combination with off-line chromatographic separation, particularly in nuclear applications where characterisation of high activity sample solutions is required. (authors)

Octupole excitations in 146Sm

International Nuclear Information System (INIS)

Bizzeti, P.G.; Bizzetti-Sona, A.M.

1998-01-01

The mean lives of the lowest 9 - and 12 + states of 146 Sm have been measured by means of the RDM. Their (preliminary) values are r m (9 - )=0.97±0.05 ns and r m (12 + )=15±2 ps, respectively. The strengths of the collective E3 transitions of the 12 + →9 - →6 6 cascade are compared with the corresponding ones in 148 Gd

Project RA Research nuclear reactor - Annual report 1993 with comparative review for the period 1991 - 1993; Projekat Istrazivacki nuklearni reaktor RA - Izvestaj za 1993. godinu, uz uporedni pregled za period 1991 - 1993

Energy Technology Data Exchange (ETDEWEB)

NONE

1993-12-15

Research reactor RA Annual report for year 1993 is divided into two main parts to cover: (1) operation and maintenance and (2) activities related to radiation protection. First part includes 8 annexes describing reactor operation, activities of services for maintenance of reactor components and instrumentation, financial report and staffing. The ninth separate annex deals with the feasibility of RA reactor applications. Second part of the report is devoted to radiation protection issues and contains 4 annexes with data about radiation control of the working environment and reactor environment, description of decontamination activities, collection of radioactive wastes, and meteorology data. [Serbo-Croat] Godisnji izvestaj o radu nuklearnog reaktora RA za 1993. godinu sastoji se od dva dela: prvi deo obuhvata pogon i odzavanje reaktora RA, a drugi poslove zastite od zracenja na reaktoru RA. Prvi deo sadrzi 8 priloga, koji opisuju rad reaktora i poslove sluzbi za odrzavanje opreme i komponenti, finansijski izvestaj, kadrovsku strukturu osoblja reaktora. Poseban prilog razmatra mogucnosti koriscenja istrazivackog reaktora RA. Drugi deo izvestaja o poslovima zastite od zracenja sadrzi 4 priloga sa podacima radijacione kontrole radne sredine i okoline reaktora, opis poslova dekontaminacije i sakupljanja radioaktivnih materija, kao i meteoroloske podatke.

Catalytic properties of oxygen adsorbed on NiO-Sm/sub 2/O/sub 3/ binary oxides

Energy Technology Data Exchange (ETDEWEB)

Tadasu, Y.; Niwa, H.; Matsuda, Y.

1978-02-01

Various rare earths were screened as promoters for a nickel oxidation catalyst, and samarium (Sm) was selected for further studies. The activity of a physical mixture of NiO/Sm/sub 2/O/sub 3/ and SiC for the oxidation of 500 ppm nitric oxide with 5% oxygen in nitrogen to nitrogen dioxide at 320/sup 0/C went through a maximum with increasing Sm/sub 2/O/sub 3/ content of the catalyst. The most active catalyst, which contained 3.75% Sm/sub 2/O/sub 3/, was 3.7 times as active as pure nickel oxide. Temperature-programed desorption of oxygen from the catalysts revealed three peaks, ..cap alpha.. at 220/sup 0/-230/sup 0/C ..beta.. at 370/sup 0/-380/sup 0/C, and ..gamma.. at 530/sup 0/-540/sup 0/C, for all catalysts except pure Sm/sub 2/O/sub 3/. The amount of adsorbed oxygen increased with increasing Sm/sub 2/O/sub 3/ content to 3.75%, and then decreased with further Sm/sub 2/O/sub 3/ increases. The catalytic activity was correlated to oxygen in the ..beta..-state. Graphs, spectra, and table.

Report of the Service for maintenance of mechanical structures - Annex 2; Prilog 2 - Rad sluzbe za odrzavanje masinske opreme

Energy Technology Data Exchange (ETDEWEB)

Radivojevic, J [Institute of Nuclear Sciences Boris Kidric, Vinca, Beograd (Serbia and Montenegro)

1976-01-15

This Annex 2 describes the organizational structure and activities of the Service for maintenance of the mechanical structures of the RA reactor, inspection and maintenance of of reactor components, workshop and storage of spare parts at the reactor. Mechanical structures of the RA reactor included are: heavy water system, gas systems, technical water system, reactor core, and transportation equipment. [Serbo-Croat] Pored opisa organizacije rada sluzbe za odrzavanje masinske opreme reaktora RA, ovaj prilog sadrzi: podatke o stanju, reviziji i remontu masinske opreme reaktora RA, prirucne radionice i magacina. Masinska oprema reaktora RA obuhvata: sistem teske vode, gasne sisteme, sistem tehnicke vode, centralno telo reaktora, transportnu opremu.

Preparation and structure characterization of SmCo5(0001) epitaxial thin films grown on Cu(111) underlayers

International Nuclear Information System (INIS)

Ohtake, Mitsuru; Nukaga, Yuri; Futamoto, Masaaki; Kirino, Fumiyoshi

2009-01-01

SmCo 5 (0001) epitaxial films were prepared on Cu(111) single-crystal underlayers formed on Al 2 O 3 (0001) substrates at 500 deg. C. The nucleation and growth mechanism of (0001)-oriented SmCo 5 crystal on Cu(111) underlayer is investigated and a method to control the nucleation is proposed. The SmCo 5 epitaxial thin film formed directly on Cu underlayer consists of two types of domains whose orientations are rotated around the film normal by 30 deg. each other. By introducing a thin Co seed layer on the Cu underlayer, a SmCo 5 (0001) single-crystal thin film is successfully obtained. Nucleation of SmCo 5 crystal on Cu underlayer seems controllable by varying the interaction between the Cu underlayer and the SmCo 5 layer

Sierra/SM theory manual.

Energy Technology Data Exchange (ETDEWEB)

Crane, Nathan Karl

2013-07-01

Presented in this document are the theoretical aspects of capabilities contained in the Sierra/SM code. This manuscript serves as an ideal starting point for understanding the theoretical foundations of the code. For a comprehensive study of these capabilities, the reader is encouraged to explore the many references to scientific articles and textbooks contained in this manual. It is important to point out that some capabilities are still in development and may not be presented in this document. Further updates to this manuscript will be made as these capabilites come closer to production level.

The QCD/SM Working Group: Summary Report

International Nuclear Information System (INIS)

Dobbs, M.

2004-01-01

Among the many physics processes at TeV hadron colliders, we look most eagerly for those that display signs of the Higgs boson or of new physics. We do so however amid an abundance of processes that proceed via Standard Model (SM) and in particular Quantum Chromodynamics (QCD) interactions, and that are interesting in their own right. Good knowledge of these processes is required to help us distinguish the new from the known. Their theoretical and experimental study teaches us at the same time more about QCD/SM dynamics, and thereby enables us to further improve such distinctions. This is important because it is becoming increasingly clear that the success of finding and exploring Higgs boson physics or other New Physics at the Tevatron and LHC will depend significantly on precise understanding of QCD/SM effects for many observables. To improve predictions and deepen the study of QCD/SM signals and backgrounds was therefore the ambition for our QCD/SM working group at this Les Houches workshop. Members of the working group made significant progress towards this on a number of fronts. A variety of tools were further developed, from methods to perform higher order perturbative calculations or various types of resummation, to improvements in the modeling of underlying events and parton showers. Furthermore, various precise studies of important specific processes were conducted. A significant part of the activities in Les Houches revolved around Monte Carlo simulation of collision events. A number of contributions in this report reflect the progress made in this area. At present a large number of Monte Carlo programs exist, each written with a different purpose and employing different techniques. Discussions in Les Houches revealed the need for an accessible primer on Monte Carlo programs, featuring a listing of various codes, each with a short description, but also providing a low-level explanation of the underlying methods. This primer has now been compiled and a

Correlation between the nanocrystalline Sm(Fe,Mo){sub 12} and its out of equilibrium phase Sm(Fe,Mo){sub 10}

Energy Technology Data Exchange (ETDEWEB)

Khazzan, S. [CMTR, ICMPE, UMR7182, CNRS - Université Paris Est, 2-8 rue Henri Dunant, F-94320 Thiais (France); Laboratoire Matériaux Organisation et Propriétés, Faculté des Sciences de Tunis, Université de Tunis El Manar, 2092 Tunis (Tunisia); Bessais, L., E-mail: bessais@glvt.cnrs.fr [CMTR, ICMPE, UMR7182, CNRS - Université Paris Est, 2-8 rue Henri Dunant, F-94320 Thiais (France); Van Tendeloo, G. [EMAT, University of Antwerp, B-2020 Antwerp (Belgium); Mliki, N. [Laboratoire Matériaux Organisation et Propriétés, Faculté des Sciences de Tunis, Université de Tunis El Manar, 2092 Tunis (Tunisia)

2014-08-01

Nanostructured Sm–Fe–Mo semi-hard magnetic material exhibiting enhanced magnetic properties can be produced by ball milling followed by recrystallization. Milled samples were annealed for 30 min in a vacuum at different temperatures (T{sub A}) between 700 and 1190 °C. The effects of heat treatment and Mo content on structural and magnetic property changes have been investigated by means of X-ray diffraction using the Rietveld method, transmission electron microscopy and magnetic measurements. For samples annealed at T{sub A}>900°C the tetragonal ThMn{sub 12}-type structure is identified, while for 700Sm(Fe{sub 1−x}Mo{sub x}){sub 10}, correlated with structural transformation towards its equilibrium derivative I4/mmm Sm(Fe{sub 1−x}Mo{sub x}){sub 12}. A maximum of the coercive field H{sub C} (H{sub C}>5kOe) has been observed for the new hexagonal P6/mmm phase suggesting that nanocrystalline Sm(Fe,Mo){sub 10}, is a semi-hard material, and is potential candidate for magnetic recording. - Highlights: • A study of the structure and magnetic properties of SmFeMo compound. • A new out of equilibrium P6/mmm-type structure was found. • Correlation between the 1/12 phase and its out of equilibrium 1/10 phase.

Level Lifetime Measurements in ^150Sm

Science.gov (United States)

Barton, C. J.; Krücken, R.; Beausang, C. W.; Caprio, M. A.; Casten, R. F.; Cooper, J. R.; Hecht, A. A.; Newman, H.; Novak, J. R.; Pietralla, N.; Wolf, A.; Zyromski, K. E.; Zamfir, N. V.; Börner, H. G.

2000-10-01

Shape/phase coexistence and the evolution of structure in the region around ^152Sm have recently been of great interest. Experiments performed at WNSL, Yale University, measured the lifetime of low spin states in a target of ^150Sm with the recoil distance method (RDM) and the Doppler-shift attenuation method (DSAM). The low spin states, both yrast and non-yrast, were populated via Coulomb excitation with a beam of ^16O. The experiments were performed with the NYPD plunger in conjunction with the SPEEDY γ-ray array. The SCARY array of solar cells was used to detect backward scattered projectiles, selecting forward flying Coulomb excited target nuclei. The measured lifetimes yield, for example, B(E2) values for transitions such as the 2^+2 arrow 2^+1 and the 2^+3 arrow 0^+_1. Data from the RDM measurment and the DSAM experiment will be presented. This work was supported by the US DOE under grants DE-FG02-91ER-40609 and DE-FG02-88ER-40417.

Schistosome tegumental ecto-apyrase (SmATPDase1 degrades exogenous pro-inflammatory and pro-thrombotic nucleotides

Directory of Open Access Journals (Sweden)

Akram A. Da’dara

2014-03-01

Full Text Available Schistosomes are parasitic worms that can survive in the hostile environment of the human bloodstream where they appear refractory to both immune elimination and thrombus formation. We hypothesize that parasite migration in the bloodstream can stress the vascular endothelium causing this tissue to release chemicals alerting responsive host cells to the stress. Such chemicals are called damage associated molecular patterns (DAMPs and among the most potent is the proinflammatory mediator, adenosine triphosphate (ATP. Furthermore, the ATP derivative ADP is a pro-thrombotic molecule that acts as a strong activator of platelets. Schistosomes are reported to possess at their host interactive tegumental surface a series of enzymes that could, like their homologs in mammals, degrade extracellular ATP and ADP. These are alkaline phosphatase (SmAP, phosphodiesterase (SmNPP-5 and ATP diphosphohydrolase (SmATPDase1. In this work we employ RNAi to knock down expression of the genes encoding these enzymes in the intravascular life stages of the parasite. We then compare the abilities of these parasites to degrade exogenously added ATP and ADP. We find that only SmATPDase1-suppressed parasites are significantly impaired in their ability to degrade these nucleotides. Suppression of SmAP or SmNPP-5 does not appreciably affect the worms’ ability to catabolize ATP or ADP. These findings are confirmed by the functional characterization of the enzymatically active, full-length recombinant SmATPDase1 expressed in CHO-S cells. The enzyme is a true apyrase; SmATPDase1 degrades ATP and ADP in a cation dependent manner. Optimal activity is seen at alkaline pH. The Km of SmATPDase1 for ATP is 0.4 ± 0.02 mM and for ADP, 0.252 ± 0.02 mM. The results confirm the role of tegumental SmATPDase1 in the degradation of the exogenous pro-inflammatory and pro-thrombotic nucleotides ATP and ADP by live intravascular stages of the parasite. By degrading host inflammatory signals

Microstructural changes during the slow-cooling annealing of nanocrystalline SmCo 2:17 type magnets

International Nuclear Information System (INIS)

Romero, S.A.; Campos, M.F. de; Castro, J.A. de; Moreira, A.J.; Landgraf, F.J.G.

2013-01-01

Highlights: ► Use of the Stoner-Wohlfarth Callen Liu Cullen model in 2:17 type magnets. ► Data suggest exchange coupling between Sm2(CoFe)17 and Sm(CoCu)5 phases. ► It is given structural data for phase Sm0.33Zr0.67TM3, with TM=Co,Fe,Cu. ► The beneficial effect of the slow cooling treatment is explained. - Abstract: The microstructure and magnetic properties of 2:17 type isotropic magnets were investigated. The slow cooling heat treatment (cooling at 1 °C/min from 820 to 400 °C, and isothermal treatment during 24 h) was interrupted after the temperatures of 820, 700, 600 and 500 °C and their hysteresis were measured with fields up to 9 T. The fully heat treated sample presented coercivity (μ 0 H) of 3.32 T, after 24 h at 400 °C. The microstructure was investigated with SEM–FEG (Scanning Electron Microscope with Field Emission Gun) and X-ray Diffraction Rietveld analysis. The application of the Stoner–Wohlfarth–Callen–Liu–Cullen (SW–CLC) model points out exchange coupling between ferromagnetic Sm 2 (CoFe) 17 nanocells and ferromagnetic Sm(CoCu) 5 present at the cell boundary phase. The results are interpreted with the double shell model: first-a cobalt-rich ferromagnetic Sm(CoCu) 5 shell originates exchange coupling and second-a copper-rich paramagnetic Sm(CuCo) 5 shell produces magnetic decoupling. This double shell helps to maximize coercivity and remanence. The anisotropy field of the Sm 2 (CoFe) 17 cell phase was estimated in 7 T with the SW–CLC model.

Recycled Sm-Co bonded magnet filaments for 3D printing of magnets

Science.gov (United States)

Khazdozian, Helena A.; Manzano, J. Sebastián; Gandha, Kinjal; Slowing, Igor I.; Nlebedim, Ikenna C.

2018-05-01

Recycling of rare earth elements, such as Sm and Nd, is one technique towards mitigating long-term supply and cost concerns for materials and devices that depend on these elements. In this work recycled Sm-Co powder recovered from industrial grinding swarfs, or waste material from magnet processing, was investigated for use in preparation of filament for 3D printing of bonded magnets. Recycled Sm-Co powder recovered from swarfs was blended into polylactic acid (PLA). Up to 20 vol.% of the recycled Sm-Co in PLA was extruded at 160°C to produce a filament. It was demonstrated that no degradation of magnetic properties occurred due to the preparation or extrusion of the bonded magnet material. Good uniformity of the magnetic properties is exhibited throughout the filament, with the material first extruded being the exception. The material does exhibit some magnetic anisotropy, allowing for the possibility of the development of anisotropic filaments. This work provides a path forward for producing recycled magnetic filament for 3D printing of permanent magnets.

Magneto-optical imaging of iron-oxypnictide SmFeAsO1-xFx and SmFeAsO1-y

International Nuclear Information System (INIS)

Tamegai, T.; Nakajima, Y.; Tsuchiya, Y.; Iyo, A.; Miyazawa, K.; Shirage, P.M.; Kito, H.; Eisaki, H.

2009-01-01

We have prepared iron-oxypnictide SmFeAsO 1-x F x by ambient-pressure technique and SmFeAsO 1-y by high-pressure technique, and characterized their bulk and local magnetic properties by using SQUID magnetometer and magneto-optical imaging. While the high-pressure samples have densities close to the theoretical value, the ambient-pressure samples have several small voids. Despite these structural differences between the two kinds of samples, they both have superconducting transition temperature above 50 K. In addition, magneto-optical images for both samples show similar kinds of inhomogeneities with large current concentrated in several grains and with small intergranular current. The estimated intragranular currents for both samples are over 10 5 A/cm 2 at low temperatures and low fields.

The dynamics of the laser-induced metal-semiconductor phase transition of samarium sulfide (SmS)

International Nuclear Information System (INIS)

Kaempfer, Tino

2009-01-01

The present thesis is dedicated to the experimental study of the metal-semiconductor phase transition of samarium sulfide (SmS): Temperature- and time-resolved experiments on the characterization of the phase transition of mixed-valence SmS samples (M-SmS) are presented. The measurement of the dynamics of the laser-induced phase transition pursues via time-resolved ultrashort-time microscopy and by X-ray diffraction with sub-picosecond time resolution. The electronic and structural processes, which follow an excitation of M-SmS with infrared femtosecond laser pulses, are physically interpreted on the base of the results obtained in this thesis and model imaginations. [de

Effect of the addition of Sm2O3 on the microstructure of laser cladding alloy coating layers

Science.gov (United States)

Zhang, Shi Hong; Li, Ming Xi; Cho, Tong Yul; Yoon, Jae Hong; Fang, Wei; Joo, Yun Kon; Kang, Jin Ho; Lee, Chan Gyu

2008-06-01

The effects on the microstructures and phases of coating layers by the addition of micron-sized (m) and nano-sized (n) (m&n) Sm2O3 powders were investigated. The coating materials, which were prepared by means of 2.0 kW CO2 laser cladding, consist of a powder mixture of m Ni-based alloy (NBA) powders comprising 1.5 wt.% m Sm2O3 and 3.0% n Sm2O3 powders. The results indicate that γ-Ni, Cr23C6 and Ni3B are the primary phases of the NBA coatings. The Fe7Sm and Ni3Si phases are highlighted by the addition of m&n Sm2O3 powders. From the substrate, planar crystal layers are first grown in all NBA and m&n Sm2O3/NBA coatings. The dendrite growth then occurs as a result of the addition of the m Sm2O3 powder, and the equiaxed dendrite growth occurs as a result of the addition of the n Sm2O3. With the addition of a rare earth oxide such as Sm2O3 powder, the width of the planar crystal becomes smaller than that of the NBA coating.

Optic and electro-optic investigations on SmQ, SmCA* and L phases in highly chiral compounds

International Nuclear Information System (INIS)

Manai, M.; Gharbi, A.; Marcerou, J.P.; Nguyen, H.T.; Rouillon, J.C.

2005-01-01

Chiral molecules give rise to a large variety of mesophases. Well-known examples are cholesteric or ferroelectric smectic phases where the chirality tends to favor a macroscopic twist. Furthermore, the molecular core length (l) plays an important role on the range of the mesophases and on the temperature (T NI ) for the onset of orientational order. The tendency for T NI is to increase (going over 200 - bar C for some compounds) with increasing l. We report in this paper on a selection of compounds which have been designed in order to favor an anticlinic smectic ordering together with high chirality. As a common feature, they have a long rigid core with four benzene rings and a chiral chain (usually the same) at each end. They display a locally anisotropic liquid phase referred to as ''L phase'' in a large temperature range between T NI and the low temperature SmQ or SmC A * phase. Optical rotatory power (ORP), birefringence and electro-optic studies have been performed with these compounds

Anmeldelse af: Bruner og de små børns læring

DEFF Research Database (Denmark)

Christensen, Bodil

2013-01-01

Anmeldelse af: Bruner og de små børns læring - en introduktion af Sandra Smidt, Hans Reitzels Forlag, 2013.......Anmeldelse af: Bruner og de små børns læring - en introduktion af Sandra Smidt, Hans Reitzels Forlag, 2013....

Analysis of the magnetic anisotropy in SmCo5 and GdCo5

International Nuclear Information System (INIS)

Zhao, T.; Jin, H.; Groessinger, R.; Kou, X.; Kirchmayr, H.R.

1991-01-01

The temperature dependence of the magnetic anisotropy constant K 1 for SmCo 5 and GdCo 5 is well reproduced by calculations based on a single-ion model taking into account the anisotropies of the R--Co exchange interaction and the Co-sublattice magnetic moment. The anisotropy of the R--Co exchange interaction plays an important role in reproducing the experimental K 1 (T) for SmCo 5 and GdCo 5 . It is found that the absolute value of the second order crystalline electric field parameter A 0 2 in SmCo 5 decreases monotonically with increasing temperature

Fabrication and properties of SmFe2-PZT magnetoelectric thin films

KAUST Repository

Giouroudi, Ioanna

2013-05-17

Magnetoelectric (ME) thin film composites are attracting a continually increasing interest due to their unique features and potential applications in multifunctional microdevices and integrated units such as sensors, actuators and energy harvesting modules. By combining piezoelectric and highly magnetostrictive thin films, the potentialities of these materials increase. In this paper we report the fabrication of SmFe2 and PZT thin films and the investigation of their properties. First of all, a ~ 400 nm thin SmFe film was deposited on top of Si/SiO2 substrate by magnetron sputter deposition. Afterwards, a 140 nm Pt bottom electrode was sputtered on top of the SmFe film forming a bottom electrode. Spin coating was employed for the deposition of the 150 nm thin PZT layer. A PZT solution with 10 %Pb excess was utilized for this fabrication step. Finally, circular Pt top electrodes were sputtered as top electrodes. This paper focuses on the microstructure of the individual films characterized by X-Ray diffractometer (XRD) and scanning electron microscopy (SEM). A piezoelectric evaluation system, aixPES, with TF2000E analyzer component was used for the electric hysteresis measurements of PZT thin films and a vibrating sample magnetometer (VSM) was employed for the magnetic characterization of the SmFe. The developed thin films and the fabricated double layer SmFe-PZT exhibit both good ferromagnetic and piezoelectric responses which predict a promising ME composite structure. The quantitative chemical composition of the samples was confirmed by energy dispersive spectroscopy (EDX). © (2013) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.

Fabrication and properties of SmFe2-PZT magnetoelectric thin films

KAUST Repository

Giouroudi, Ioanna; Alnassar, Mohammed; Kosel, Jü rgen

2013-01-01

Magnetoelectric (ME) thin film composites are attracting a continually increasing interest due to their unique features and potential applications in multifunctional microdevices and integrated units such as sensors, actuators and energy harvesting modules. By combining piezoelectric and highly magnetostrictive thin films, the potentialities of these materials increase. In this paper we report the fabrication of SmFe2 and PZT thin films and the investigation of their properties. First of all, a ~ 400 nm thin SmFe film was deposited on top of Si/SiO2 substrate by magnetron sputter deposition. Afterwards, a 140 nm Pt bottom electrode was sputtered on top of the SmFe film forming a bottom electrode. Spin coating was employed for the deposition of the 150 nm thin PZT layer. A PZT solution with 10 %Pb excess was utilized for this fabrication step. Finally, circular Pt top electrodes were sputtered as top electrodes. This paper focuses on the microstructure of the individual films characterized by X-Ray diffractometer (XRD) and scanning electron microscopy (SEM). A piezoelectric evaluation system, aixPES, with TF2000E analyzer component was used for the electric hysteresis measurements of PZT thin films and a vibrating sample magnetometer (VSM) was employed for the magnetic characterization of the SmFe. The developed thin films and the fabricated double layer SmFe-PZT exhibit both good ferromagnetic and piezoelectric responses which predict a promising ME composite structure. The quantitative chemical composition of the samples was confirmed by energy dispersive spectroscopy (EDX). © (2013) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.

Multi-factor analysis on events related to hematological toxicity in 153Sm-EDTMP palliative therapy for skeletal metastases

International Nuclear Information System (INIS)

Zhan Hongwei; Yu Xiaoling; Ye Xiaojuan; Bao Chengkan; Sun Da; He Gangqiang

2006-01-01

Objective: To investigate the clinical factors related to hematological toxicity induced by intravenous samarium-153 ethylenediaminetetramethylene phosphonic acid ( 153 Sm-EDTMP) treatment. Methods A total of 206 patients with bony metastases treated with 153 Sm-EDTMP were retrospectively analyzed. Logistic regression (SPSS 10.0 for Windows) and correlation analysis were used to evaluate the factors concerned. Results: Age of the patient, number of bone metastatic lesion, chemotherapy before 153 Sm-EDTMP therapy, concurrent radiotherapy and repeat-times of 153 Sm-EDTMP treatments were found the individual factors related to hematological toxicity. Chemotherapy before 153 Sm-EDTMP, concurrent radiotherapy, medication for normal blood counting and repeat-times of 153 Sm-EDTMP treatments were the hematological toxicity factors in multi-factor analysis. Conclusion: In 153 Sm-EDTMP therapy, several factors were found related to hematological toxicity suggesting more attention be paid to the change of blood cell counting after the palliative therapy. (authors)

Effects of substrate temperature and Cu underlayer thickness on the formation of SmCo5(0001) epitaxial thin films

International Nuclear Information System (INIS)

Ohtake, Mitsuru; Nukaga, Yuri; Futamoto, Masaaki; Kirino, Fumiyoshi

2010-01-01

SmCo 5 (0001) epitaxial thin films were prepared on Cu(111) underlayers heteroepitaxially grown on Al 2 O 3 (0001) single-crystal substrates by molecular beam epitaxy. The effects of substrate temperature and Cu underlayer thickness on the crystallographic properties of SmCo 5 (0001) epitaxial films were investigated. The Cu atoms of underlayer diffuse into the SmCo 5 film and substitute the Co sites in SmCo 5 structure forming an alloy compound of Sm(Co,Cu) 5 . The ordered phase formation is enhanced with increasing the substrate temperature and with increasing the Cu underlayer thickness. The Cu atom diffusion into the SmCo 5 film is assisting the formation of Sm(Co,Cu) 5 ordered phase.

Absorption Spectra of BaF2 Sm2O3, Sm, Gd, and Ho Plasmas

Science.gov (United States)

Martin, Michael; Bastiani-Ceccotti, Serena

2009-11-01

Knowledge of the opacities of high Z element plasmas is important in indirect drive ICF and the study of stellar evolution. There are few experimental measurements of this quantity, and its theoretical determination is difficult due to the number of possible bound electron configurations. This study aims to better the theoretical understanding of this parameter by looking at the 3d-4f transitions of BaF2, Sm2O3, Sm, Gd, and Ho plasmas at the LULI2000 facility. The plasmas are produced by radiative heating and are cold, 15 -- 40 eV, and relatively dense, ˜ .01gm/cm^3 A plasma is produced by a .5 ns laser pulse irradiating a gold hohlraum and then probed by an x-ray source created by a gold foil irradiated by a 10 ps laser pulse. The transmission is found with simultaneous source and absorption measurements by an x-ray spectrometer in the 8 - 20 å range We will compare the results with statistical atomic structure codes. From this experiment we will gain further insight into the spectral broadening of neighboring Z elements due to changing plasma temperature and into mixture thermodynamics. This is a first step towards an experimental study of astrophysical domains.

SmCL3, a gastrodermal cysteine protease of the human blood fluke Schistosoma mansoni.

Directory of Open Access Journals (Sweden)

Jan Dvorák

2009-06-01

Full Text Available Blood flukes of the genus Schistosoma are platyhelminth parasites that infect 200 million people worldwide. Digestion of nutrients from the host bloodstream is essential for parasite development and reproduction. A network of proteolytic enzymes (proteases facilitates hydrolysis of host hemoglobin and serum proteins.We identified a new cathepsin L termed SmCL3 using PCR strategies based on S. mansoni EST sequence data. An ortholog is present in Schistosoma japonicum. SmCL3 was heterologously expressed as an active enzyme in the yeast, Pichia pastoris. Recombinant SmCL3 has a broad pH activity range against peptidyl substrates and is inhibited by Clan CA protease inhibitors. Consistent with a function in degrading host proteins, SmCL3 hydrolyzes serum albumin and hemoglobin, is localized to the adult gastrodermis, and is expressed mainly in those life stages infecting the mammalian host. The predominant form of SmCL3 in the parasite exists as a zymogen, which is unusual for proteases. This zymogen includes an unusually long prodomain with alpha helical secondary structure motifs. The striking specificity of SmCL3 for amino acids with large aromatic side chains (Trp and Tyr at the P2 substrate position, as determined with positional scanning-synthetic combinatorial library, is consistent with a molecular model that shows a large and deep S2 pocket. A sequence similarity network (SSN view clusters SmCL3 and other cathepsins L in accordance with previous large-scale phylogenetic analyses that identify six super kingdoms.SmCL3 is a gut-associated cathepsin L that may contribute to the network of proteases involved in degrading host blood proteins as nutrients. Furthermore, this enzyme exhibits some unusual sequence and biophysical features that may result in additional functions. The visualization of network inter-relationships among cathepsins L suggests that these enzymes are suitable 'marker sequences' for inclusion in future phylogenetic analyses.

Decay spectroscopy of 160Sm: The lightest four-quasiparticle K isomer

Directory of Open Access Journals (Sweden)

Z. Patel

2016-02-01

Full Text Available The decay of a new four-quasiparticle isomeric state in 160Sm has been observed using γ-ray spectroscopy at the RIBF, RIKEN. The four-quasiparticle state is assigned a 2π⊗2ν π52−[532], π52+[413], ν52−[523], ν72+[633] configuration. The half-life of this (11+ state is measured to be 1.8(4 μs. The (11+ isomer decays into a rotational band structure, based on a (6− ν52−[523]⊗ν72+[633] bandhead, consistent with the gK−gR values. This decays to a (5− two-proton quasiparticle state, which in turn decays to the ground state band. Potential energy surface and blocked-BCS calculations were performed in the deformed midshell region around 160Sm. They reveal a significant influence from β6 deformation and that 160Sm is the best candidate for the lightest four-quasiparticle K isomer to exist in this region. The relationship between reduced hindrance and isomer excitation energy for E1 transitions from multiquasiparticle states is considered with the new data from 160Sm. The E1 data are found to agree with the existing relationship for E2 transitions.

Photoluminescence characteristics of reddish-orange Eu{sup 3+} or Sm{sup 3+} singly-doped and Eu{sup 3+} and Sm{sup 3+} co-doped KZnGd(PO{sub 4}){sub 2} phosphors

Energy Technology Data Exchange (ETDEWEB)

Jeong, Jun Ho; Bandi, Vengala Rao; Grandhe, Bhaskar Kumar; Jang, Ki Wan; Lee, Ho Sueb [Changwon National University, Changwon (Korea, Republic of); Yi, Soung Soo [Silla University, Busan (Korea, Republic of); Jeong, Jung Hyun [Pukyong National University, Busan (Korea, Republic of)

2011-02-15

Eu{sup 3+} or Sm{sup 3+} singly-doped and Eu{sup 3+} and Sm{sup 3+} co-doped KZnGd(PO{sub 4}){sub 2} phosphors were synthesized by using a conventional solid state reaction method at 750 .deg. C. The emission spectra of KZnGd{sub 1-x}(PO{sub 4}){sub 2}:Eu{sup 3+}{sub x} with {lambda}{sub ex} = 395 nm and KZnGd{sub 1-y}(PO{sub 4}){sub 2}:Sm{sup 3+}{sub y} with {lambda}{sub ex} = 403 nm phosphors showed intense {sup 5}D{sub 0} {yields} {sup 7}F{sub 1}, {sup 4}G{sub 5/2} {yields} {sup 6}H{sub 7/2} emission transitions at 595 nm and 599 nm, respectively. The optimum relative intensity of the KZnGd{sub 1-x-y}(PO{sub 4}){sub 2}:Eu{sup 3+}{sub x} , Sm{sup 3+}{sub y} phosphor was obtained for the doping concentrations of (x = 0.09, y = 0.01). In addition, the temperature dependent luminescence intensity of the synthesized phosphors was investigated and the thermal stability of the KZnGd(PO{sub 4}){sub 2}:Eu{sup 3+} phosphor was found to be higher than that of standard YAG:Ce{sup 3+} and KZnGd{sub 1-x-y}(PO{sub 4}){sub 2}:Eu{sup 3+}{sub x} Sm{sup 3+}{sub y} under near ultra-violet (NUV) light emitting diode excitation (LED). Therefore, we suggest that Eu{sup 3+} or Sm{sup 3+} singly-doped and Eu{sup 3+} and Sm{sup 3+} co-doped KZnGd(PO{sub 4}){sub 2} phosphors should be efficient for different red-color-emitting display device applications and NUV-LED-based white-light-emitting diodes.

Cytogenetic analysis of 153 Sm-EDTMP in peripheral lymphocytes from patients with bone cancer metastasis

International Nuclear Information System (INIS)

Silva, M.A. da; Suzuki, M.F.; Rogero, J.R.; Okazaki, K.; Guimaraes, M.I.C.C.; Buchpiguel, C.A.

2002-01-01

The 153 Sm-EDTMP is a radiopharmaceutical used in nuclear medicine with promising results for the relief of metastatic pain. Therefore, there are few knowledge about the effects of 153 Sm-EDTMP at cellular level. The present study was conducted with the aim of evaluating the cytogenetic effects of 153 Sm-EDTMP in peripheral lymphocytes from patients with bone metastasis (with and without previous radio and/or chemotherapy) by the chromosome aberration technique. For that, the blood samples were collected before and one hour after the endovenous administrations of 153 Sm-EDTMP (mean activity of 42.53 ± 5.31 MBq/kg body weight), taking into account the rapid blood clearance. The principal types of structural chromosome aberrations found gaps and breaks, acentric fragments centric rings, double minutes and dicentrics. The statistical analysis showed that the group submitted to previous radio and chemotherapy before 153 Sm-EDTMP administration showed significant difference in chromosome aberrations frequency one hour after the treatment. The analysis of the chromosome modal number and the kinetics of cellular cycle showed no statistical difference among the groups, suggesting that the treatment with 153 Sm-EDTMP, did not influence these parameters. The obtained data showed that the therapy with 153 Sm-EDTMP induced a few quantity of cytogenetic damages in peripheral lymphocytes one hour after its administration in patients, although, theoretically, a long term stochastic effect cannot be disregarded. (author)

Petri nets SM-cover-based on heuristic coloring algorithm

Science.gov (United States)

Tkacz, Jacek; Doligalski, Michał

2015-09-01

In the paper, coloring heuristic algorithm of interpreted Petri nets is presented. Coloring is used to determine the State Machines (SM) subnets. The present algorithm reduces the Petri net in order to reduce the computational complexity and finds one of its possible State Machines cover. The proposed algorithm uses elements of interpretation of Petri nets. The obtained result may not be the best, but it is sufficient for use in rapid prototyping of logic controllers. Found SM-cover will be also used in the development of algorithms for decomposition, and modular synthesis and implementation of parallel logic controllers. Correctness developed heuristic algorithm was verified using Gentzen formal reasoning system.

Electron back scattered diffraction study of SmCo magnets

International Nuclear Information System (INIS)

Yonamine, T.; Fukuhara, M.; Machado, R.; Missell, F.P.

2008-01-01

The remanence and energy product of permanent magnets is a strong function of their crystallographic texture. Electron back scattered diffraction (EBSD) is a tool for texture analysis providing information about the atomic layers up to 50 nm below the surface of the material. This paper discusses experimental requirements for performing EBSD measurements on rare-earth permanent magnets and presents results on commercial SmCo magnet material. EBSD measurements proved to be very sensitive to misaligned grains and were sensitive to texture in good agreement with information provided by X-ray diffraction scans. Results for nanostructured Sm(CoFeCuZr) z magnets are also discussed

Isomer decay spectroscopy of 164Sm and 166Gd: midshell collectivity around N=100.

Science.gov (United States)

Patel, Z; Söderström, P-A; Podolyák, Zs; Regan, P H; Walker, P M; Watanabe, H; Ideguchi, E; Simpson, G S; Liu, H L; Nishimura, S; Wu, Q; Xu, F R; Browne, F; Doornenbal, P; Lorusso, G; Rice, S; Sinclair, L; Sumikama, T; Wu, J; Xu, Z Y; Aoi, N; Baba, H; Bello Garrote, F L; Benzoni, G; Daido, R; Fang, Y; Fukuda, N; Gey, G; Go, S; Gottardo, A; Inabe, N; Isobe, T; Kameda, D; Kobayashi, K; Kobayashi, M; Komatsubara, T; Kojouharov, I; Kubo, T; Kurz, N; Kuti, I; Li, Z; Matsushita, M; Michimasa, S; Moon, C-B; Nishibata, H; Nishizuka, I; Odahara, A; Şahin, E; Sakurai, H; Schaffner, H; Suzuki, H; Takeda, H; Tanaka, M; Taprogge, J; Vajta, Zs; Yagi, A; Yokoyama, R

2014-12-31

Excited states in the N=102 isotones 166Gd and 164Sm have been observed following isomeric decay for the first time at RIBF, RIKEN. The half-lives of the isomeric states have been measured to be 950(60) and 600(140) ns for 166Gd and 164Sm, respectively. Based on the decay patterns and potential energy surface calculations, including β6 deformation, a spin and parity of 6- has been assigned to the isomeric states in both nuclei. Collective observables are discussed in light of the systematics of the region, giving insight into nuclear shape evolution. The decrease in the ground-band energies of 166Gd and 164Sm (N=102) compared to 164Gd and 162Sm (N=100), respectively, presents evidence for the predicted deformed shell closure at N=100.

Isomer Decay Spectroscopy of Sm 164 and Gd 166 : Midshell Collectivity Around N =100

Science.gov (United States)

Patel, Z.; Söderström, P.-A.; Podolyák, Zs.; Regan, P. H.; Walker, P. M.; Watanabe, H.; Ideguchi, E.; Simpson, G. S.; Liu, H. L.; Nishimura, S.; Wu, Q.; Xu, F. R.; Browne, F.; Doornenbal, P.; Lorusso, G.; Rice, S.; Sinclair, L.; Sumikama, T.; Wu, J.; Xu, Z. Y.; Aoi, N.; Baba, H.; Bello Garrote, F. L.; Benzoni, G.; Daido, R.; Fang, Y.; Fukuda, N.; Gey, G.; Go, S.; Gottardo, A.; Inabe, N.; Isobe, T.; Kameda, D.; Kobayashi, K.; Kobayashi, M.; Komatsubara, T.; Kojouharov, I.; Kubo, T.; Kurz, N.; Kuti, I.; Li, Z.; Matsushita, M.; Michimasa, S.; Moon, C.-B.; Nishibata, H.; Nishizuka, I.; Odahara, A.; Şahin, E.; Sakurai, H.; Schaffner, H.; Suzuki, H.; Takeda, H.; Tanaka, M.; Taprogge, J.; Vajta, Zs.; Yagi, A.; Yokoyama, R.

2014-12-01

Excited states in the N =102 isotones Gd 166 and Sm 164 have been observed following isomeric decay for the first time at RIBF, RIKEN. The half-lives of the isomeric states have been measured to be 950(60) and 600(140) ns for Gd 166 and Sm 164 , respectively. Based on the decay patterns and potential energy surface calculations, including β6 deformation, a spin and parity of 6- has been assigned to the isomeric states in both nuclei. Collective observables are discussed in light of the systematics of the region, giving insight into nuclear shape evolution. The decrease in the ground-band energies of Gd 166 and Sm 164 (N =102 ) compared to Gd 164 and Sm 162 (N =100 ), respectively, presents evidence for the predicted deformed shell closure at N =100 .

Evidentiation of Paramyosin (Sm-97 as a Modulating Antigen on Granulomatous Hypersensitivity to Schistosoma mansoni Eggs

Directory of Open Access Journals (Sweden)

Hirsch Cristine

1997-01-01

Full Text Available A Schistosoma mansoni adult worm anionic fraction (PIII has previously been shown to protect mice against challenge infection and to reduce pulmonary and hepatic granulomatous hypersensitivity. Serum from PIII-immunized rabbit was used to screen a lgt11 cDNA library from S. mansoni adult worm in order to identify antigens capable of modulating granulomatous hypersensitivity. We obtained four clones with 400 (Sm-III.11, 900 (Sm-III.16, 1100 (Sm-III.10 and 1300 (Sm-III.12 bp of length. All clone-specific antibodies were able to recognize most of the PIII components. The sequence analysis showed that these clones presented high homology with S. mansoni paramyosin (Sm-97. These findings ascribe a new function to this antigen with an important role in modulation of granulomatous hypersensitivity to S. mansoni eggs

Synthesis, characterization and thermal expansion studies on ThO2-SmO1.5 solid solutions

International Nuclear Information System (INIS)

Panneerselvam, G.; Antony, M.P.

2008-01-01

Full text: A highly homogeneous Th 1-x Sm x O 2 ; 0 ≤ x ≤ 0.8 solid solutions were synthesized by co-precipitation technique and the co-precipitated samples were sintered at 1473 K. Compositions of the solid solutions were characterized by standard wet-chemical analysis. X-ray diffraction measurements were performed in the sintered pellets for structural analysis, lattice parameter calculation and determination of solid solubility of SmO 1.5 in ThO 2 matrix. Bulk and theoretical densities of solid solutions were also determined. A fluorite structure was observed for ThO 2 -SmO 1.5 solid solutions with 0-55.2 mol % SmO 1.5 . Their thermal expansion coefficients were measured using high temperature X-ray diffraction technique. The mean linear thermal expansivity, αm for ThO 2 -SmO 1.5 solid solutions containing 17.9, 41.7 and 52.0 mole percent of SmO 1.5 were determined in the temperature range 298 to 2000 K for the first time. The mean linear thermal expansion coefficients for ThO 2 -SmO 1.5 solid solutions are 10.47x10 -6 K -1 , 11.16x10 -6 K -1 and 11.45x10 -6 K -1 , respectively. The percentage linear thermal expansion in this temperature range, for ThO 2 -SmO 1.5 solid solutions containing 17.9, 41.7 and 52.0 mol % SmO 1.5 are 1.82,1.94 and 1.99 respectively. It is suggested that the solid solutions are stable up to 2000 K. It is also suggested that the effect and nature of the dopant are the important parameters influenced in the thermal expansion of the ThO 2

Luminescence studies of Sm(III) and Cm(III) complexes in NaSCN/DHDECMP extraction systems

CERN Document Server

Chung, D Y; Kimura, T

1999-01-01

Laser-induced fluorescence (LIF) studies of Sm(III) and Cm(III) complexes in the NaSCN/DHDECMP solvent extraction system were carried out. Luminescence lifetimes were measured to determine the number of water molecules coordinated to Sm(III), Tb(III), Dy(III), and Cm(III) in the sodium thiocyanate solution and in the DHDECMP phase. The hydration number of Sm(III), Tb(III), Dy(III), and Cm(III) in the sodium thiocyanate solution decreased linearly with increasing sodium thiocyanate concentration. The hydration numbers of Sm(III), Dy(III), and Cm(III) in the DHDECMP phase decreased with increasing sodium thiocyanate concentration. The water molecules in the inner coordination sphere of Sm(III) and Dy(III) extracted into the DHDECMP were not completely removed at low sodium thiocyanate concentration but decreased with increasing sodium thiocyanate concentration. However, in the case of Cm(III) extracted into the DHDECMP phase from the sodium thiocyanate solution, there was no water in the inner coordination sphe...

Radiological site assessment at sun rose claim utilizing ScanPlot{sup SM} technology

Energy Technology Data Exchange (ETDEWEB)

Downey, H., E-mail: heath.downey@amecfw.com [Amec Foster Wheeler, Portland, ME (United States)

2015-07-01

ScanPlot{sup SM} gamma spectroscopy land survey system was utilized for the overland survey of uranium at the Sun Rose Claim in the Northwest Territories. The Sun Rose Claim is a former uranium exploration site and previous investigations had identified uranium ore and waste rock. ScanPlot{sup SM} radiological scan surveys were performed utilizing a backpack system. ScanPlot{sup SM} platform utilized spectroscopy grade sodium iodide detectors configured for optimal spatial coverage and radiation detection. Survey locations were recorded using an on-board global positioning system (GPS). The radiological spectral data from the radiation detectors is automatically logged and linked with the GPS coordinates to an on-board computer to create isocontour figures using a color scale to represent radioactivity levels. The advantage of utilizing the ScanPlot{sup SM} system for this assessment is that the nature and extent of uranium is provided without having to collect and assay a large number of samples. (author)

Effects of Sm addition on microstructure and mechanical properties of a Mg-10Y alloy

Directory of Open Access Journals (Sweden)

Li Quanan

2014-01-01

Full Text Available To further increase the mechanical properties, 0.5wt.% Sm was introduced to a Mg-10Y alloy in this study. The effects of Sm addition on the microstructures and mechanical properties of the Mg-10Y alloy, especially the aged Mg-10Y alloy, were investigated. The microstructure observation and tensile tests were performed by using an optical microscopy, a scanning electron microscopy and a universal material testing machine, respectively. The phase analysis was performed using X-ray diffractometer. The results show that the 0.5wt.% Sm addition can not only promote the formation of fine and dispersed Mg24Y5 phases, but also improve their morphology and distribution; it also increases the thermal stability of Mg24Y5 phases. Sm addition is seen to increase the ultimate tensile strength of Mg-10Y alloy at elevated temperatures (200, 250, 300 and 350 ℃, while decrease the elongation. But the elongation is still up to 7.5% even at 350 ℃. In the range of 250 ℃ to 300℃, the ultimate tensile strength of the alloy reaches its maximum (with a range average of 235 MPa and is not sensitive to the temperature change, which is very useful to the application of heat-resistant magnesium alloys. Even at 350 ℃, the ultimate tensile strength of Mg-10Y-0.5Sm is still up to 155 MPa. Considering both of the ultimate tensile strength and elongation, the maximum application temperature of the Mg-10Y-0.5Sm alloy can be up to 300 ℃. The strengthening mechanisms of Mg-10Y-0.5Sm alloy are mainly attributed to dispersion strengthening of Mg24Y5 phase particles with a certain solubility of Sm and grain refinement strengthening of α-Mg matrix.

Preparation, microstructure and magnetic properties of Sm(Co,Hf){sub 7}/Co nanocomposite particles by polyol method

Energy Technology Data Exchange (ETDEWEB)

Bu, Shao-Jing; Duan, Xiu-Li; Han, Xu-Hao; Sun, Ji-Bing, E-mail: hbgdsjb@126.com; Chi, Xiang; Cui, Chun-Xiang

2017-02-01

Hard/soft Sm-Co/Co nanocomposite particles were prepared by reducing CoCl{sub 2}·6H{sub 2}O in the solution containing ball-milled Sm(Co, Hf){sub 7} particles by a simple polyol method with ethylene glycol as the solvent. Phase composition, microstructure and magnetic properties of the particles were analyzed by XRD, TEM (HRTEM) and VSM, respectively. It has been found that Sm-Co/Co core/shell structure is formed in which the Co shell is 3–5 nm in thickness and mainly exists in hcp-Co phase. At the same time, fcc-Co tends to nucleate and grow independently between Sm-Co particles. The formation mechanism of Sm-Co/Co composite particles is discussed and corresponding model is established. Sm-Co/Co composite particles perform obvious remanence enhancement effects especially after being heated at 450 °C for 15 min.

Crystal structure and magnetic properties of a nitrogenated melt-spun Sm[sub 2]Fe[sub 17] compound

Energy Technology Data Exchange (ETDEWEB)

Yang, Choong-Jin [Electromagnetic Materials Laboratory, Research Institute of Industrial Science and Technology, P.O. Box 135, 790-330 Pohang (Korea, Republic of); Lee, Woo-Young [Electromagnetic Materials Laboratory, Research Institute of Industrial Science and Technology, P.O. Box 135, 790-330 Pohang (Korea, Republic of); Choi, Seung-Duck [Electromagnetic Materials Laboratory, Research Institute of Industrial Science and Technology, P.O. Box 135, 790-330 Pohang (Korea, Republic of)

1994-05-15

Sm[sub 2]Fe[sub 17]N[sub 2.9] compound powders were prepared from parent alloys of Sm[sub 2]Fe[sub 17] which were made by both arc melting and rapid solidification processes. The cast Sm[sub 2]Fe[sub 17] contained mixed phases of SmFe[sub 3] and [alpha]-Fe, and correspondingly formed less Sm[sub 2]Fe[sub 17]N[sub x] with a rather large amount of residual [alpha]-Fe after nitrogenation. The melt-spun Sm[sub 2]Fe[sub 17] compound, however, was single phase and exhibited a negligible amount of residual [alpha]+Fe after nitrogenation. The residual amount of free iron was found to increase as a function of milling time and to impede the development of promising permanent magnetic properties. The melt-spun Sm[sub 2]Fe[sub 17]N[sub x] compound powders exhibited a coercivity value [sub i]H[sub c] of 5 kOe, which is double that of the as-cast Sm[sub 2]Fe[sub 17]N[sub x] powders and a high remanence B[sub r]=60 e.m.u. g[sup -1]. The average magnetic moment of Fe atoms in the crystal is estimated to be 2.29 [mu][sub B] and the Fe atom in the 6c site exhibits the highest magnetic moment of 2.65 [mu][sub B]. The expansion in the c axial direction of the nitrogenated crystal was found to be mainly due to extension of Sm(6c)-Fe(c) and Fe(18f)-Fe(18f) distances. ((orig.))

RB research nuclear reactor - Annual report for 1986, I - III; Istrazivacki nuklearni reaktor RB (Izvestaj o radu u 1986. godini), I-III

Energy Technology Data Exchange (ETDEWEB)

Markovic, H; Pesic, M; Vranic, S; Petronijevic, M; Jevremovic, M; Ilic, I [Boris Kidric Institute of Nuclear Sciences Vinca, Beograd (Yugoslavia)

1987-07-01

This report includes data concerning the RB reactor operation in 1986, state of the reactor components, data about the employed personnel and the database of experimental and other reactor related devices. It is made of 3 parts: Engineering description and operation of the RB reactor including dosimetry, reactor staff data and financial report; Reactor facility components and maintenance; RB reactor operation and utilization in 1986. Izvestaj pokazuje podatke o radu reaktora RB u toku 1986. godine, stanje reaktorske opreme, podatke o angazovanom osoblju na reaktoru i datoteku sa podacima o eksperimentalnoj i drugoj opremi reaktora RB. Sastoji se od 3 dela: tehnicki opis, pogon i rad reaktora, oprema postrojenja i njeno odrzavanje, koriscenje reaktora u 1986. godini.

The Syk kinase SmTK4 of Schistosoma mansoni is involved in the regulation of spermatogenesis and oogenesis.

Directory of Open Access Journals (Sweden)

Svenja Beckmann

2010-02-01

Full Text Available The signal transduction protein SmTK4 from Schistosoma mansoni belongs to the family of Syk kinases. In vertebrates, Syk kinases are known to play specialized roles in signaling pathways in cells of the hematopoietic system. Although Syk kinases were identified in some invertebrates, their role in this group of animals has not yet been elucidated. Since SmTK4 is the first Syk kinase from a parasitic helminth, shown to be predominantly expressed in the testes and ovary of adult worms, we investigated its function. To unravel signaling cascades in which SmTK4 is involved, yeast two-/three-hybrid library screenings were performed with either the tandem SH2-domain, or with the linker region including the tyrosine kinase domain of SmTK4. Besides the Src kinase SmTK3 we identified a new Src kinase (SmTK6 acting upstream of SmTK4 and a MAPK-activating protein, as well as mapmodulin acting downstream. Their identities and colocalization studies pointed to a role of SmTK4 in a signaling cascade regulating the proliferation and/or differentiation of cells in the gonads of schistosomes. To confirm this decisive role we performed biochemical and molecular approaches to knock down SmTK4 combined with a novel protocol for confocal laser scanning microscopy for morphological analyses. Using the Syk kinase-specific inhibitor Piceatannol or by RNAi treatment of adult schistosomes in vitro, corresponding phenotypes were detected in the testes and ovary. In the Xenopus oocyte system it was finally confirmed that Piceatannol suppressed the activity of the catalytic kinase domain of SmTK4. Our findings demonstrate a pivotal role of SmTK4 in gametogenesis, a new function for Syk kinases in eukaryotes.

Effect of temperature on the luminescence of Sm{sup 3+} ions in YAM crystals

Energy Technology Data Exchange (ETDEWEB)

Kaczkan, M. [Institute of Microelectronics and Optoelectronics PW, ul. Koszykowa 75, 00-662 Warsaw (Poland); Boruc, Z., E-mail: z.boruc@stud.elka.pw.edu.pl [Institute of Microelectronics and Optoelectronics PW, ul. Koszykowa 75, 00-662 Warsaw (Poland); Turczyński, S. [Institute of Electronic Materials Technology, ul. Wólczyńska 133, 01-919 Warsaw (Poland); Malinowski, M. [Institute of Microelectronics and Optoelectronics PW, ul. Koszykowa 75, 00-662 Warsaw (Poland)

2014-11-05

Highlights: • Different concentration Sm{sup 3+}-doped Y{sub 4}Al{sub 2}O{sub 9} crystals are fabricated by μ-pulling down method. • Thermally activated {sup 4}F{sub 3/2} → {sup 6}H{sub 5/2} emission of Sm{sup 3+} in YAM is studied. • Temperature dependent quenching mechanism of the {sup 4}G{sub 5/2} luminescence is proposed. - Abstract: The spectroscopic features of samarium Sm{sup 3+} activated Y{sub 4}Al{sub 2}O{sub 9} (YAM) crystals are presented and discussed. Temperature sensing properties of Sm{sup 3+}:YAM phosphor was demonstrated over the 300–1200 K range. Temperature dependent luminescence spectra and decay curves for the {sup 4}G{sub 5/2} level of Sm{sup 3+} in YAM were measured. Ratio of the fluorescence intensities arising from the two close lying {sup 4}F{sub 3/2} and {sup 4}G{sub 5/2} levels (with energy separation of ΔE ∼ 1000 cm{sup −1}) followed a straight line pattern, which confirms the Boltzmann distribution of the population, and can be used to measure temperature. The lifetime for the {sup 4}G{sub 5/2} level in 1% Sm doped sample decreases from 1.65 to 0.08 ms with heating from room temperature to 1200 K. This behavior of decays is discussed in terms of radiative and multiphonon decays as well as cross-relaxation dependence on temperature.

Photoluminescence characteristics of Sm{sup 3+}-doped Ba{sub 2}CaWO{sub 6} as new orange–red emitting phosphors

Energy Technology Data Exchange (ETDEWEB)

Yu, Ruiijn [College of Science, Northwest A and F University, Yangling, Shaanxi 712100 (China); Department of Physics, Pukyong National University, Busan 608-737 (Korea, Republic of); Department of Physics, Changwon National University, Changwon 641-773 (Korea, Republic of); Mi Noh, Hyeon; Kee Moon, Byung; Chun Choi, Byung [Department of Physics, Pukyong National University, Busan 608-737 (Korea, Republic of); Hyun Jeong, Jung, E-mail: jhjeong@pknu.ac.kr [Department of Physics, Pukyong National University, Busan 608-737 (Korea, Republic of); Sueb Lee, Ho [Department of Physics, Changwon National University, Changwon 641-773 (Korea, Republic of); Jang, Kiwan, E-mail: kwjang@changwon.ac.kr [Department of Physics, Changwon National University, Changwon 641-773 (Korea, Republic of); Soo Yi, Soung [Department of Electronic Material Engineering, Silla University, Busan 617-736 (Korea, Republic of)

2014-08-01

The orange–red emitting Ba{sub 2}CaWO{sub 6}:xSm{sup 3+} (0.01≤x≤0.25) phosphors were synthesized via solid state reaction process. The crystal structure of the phosphor was characterized by XRD. The photoluminescence excitation and emission spectra, concentration effect were investigated. The results show an efficient energy transfer from WO{sub 6}{sup 6−} group to Sm{sup 3+} occurs. The emission spectra of the Ba{sub 2}CaWO{sub 6}:Sm{sup 3+} phosphors consisted of some sharp emission peaks of Sm{sup 3+} ions centre at 579 nm, 618 nm, 625 nm, and 675 nm. The strongest one is located at 610 nm due to {sup 4}G{sub 5/2}→{sup 6}H{sub 7/2} transition of Sm{sup 3+}, generating bright orange–red light. The optimum dopant concentration of Sm{sup 3+} ions in Ba{sub 2}CaWO{sub 6}:xSm{sup 3+} is around 5 mol% and the critical transfer distance of Sm{sup 3+} is calculated as 18 Å. The fluorescence lifetime of Sm{sup 3+} in Ba{sub 2}CaWO{sub 6}:0.05Sm{sup 3+} is 2.36 ms. The Ba{sub 2}CaWO{sub 6}:Sm{sup 3+} phosphors may be potentially used as orange–red phosphors for white light-emitting diodes. - Highlights: • A new host-sensitized Sm{sup 3+}-doped Ba{sub 2}CaWO{sub 6} phosphor was firstly synthesized. • Its structure, luminescent properties are well studied and characterized. • There exists an efficient energy transfer from WO{sub 6}{sup 6−} group to Sm{sup 3+}. • The thermal quenching properties of Ba{sub 2}CaWO{sub 6}:Sm{sup 3+} was firstly evaluated.

Effects of Sm addition on electromagnetic interference shielding property of Mg-Zn-Zr alloys

Energy Technology Data Exchange (ETDEWEB)

Yang, Chubin [Chongqing University, College of Materials Science and Engineering, National Engineering Research Center for Magnesium Alloy, Chongqing (China); Gannan Normal University, Jiangxi Provincial Engineering Research Center for Magnesium Alloy, Ganzhou (China); Pan, Fusheng; Chen, Xianhua [Chongqing University, College of Materials Science and Engineering, National Engineering Research Center for Magnesium Alloy, Chongqing (China); Luo, Ning [Gannan Normal University, Jiangxi Provincial Engineering Research Center for Magnesium Alloy, Ganzhou (China)

2017-06-15

The electromagnetic interference (EMI) shielding of Sm-containing magnesium alloys in the 30-1500 MHz testing frequency range was investigated by coaxial cable method. The results demonstrated that Mg-3Zn alloys displayed the best electromagnetic shielding property. When 0.5 wt% of Zr was added for crystal grain refinement, the shielding effectiveness (SE) was apparently reduced. The addition of the rare earth element Sm in ZK magnesium alloys can improve the electromagnetic interference shielding of magnesium alloys. The main reason for the differences in electromagnetic interference shielding of magnesium alloys was the change in conductivity. The addition of Zr in Mg-Zn alloys can refine the grains and consequently improve the grain boundary area significantly. Therefore, the number of irregularly arranged atoms at the grain boundaries increased, decreasing the conductivity of magnesium alloys and leading to a decrease in the electromagnetic interference shielding. Following the Sm addition, the Mg-Zn-Sm phase was precipitated at the grain boundaries and in cores. The precipitation of Sm-containing rare earth phases could consume the solid-soluted Zn atoms within the Mg, resulting in an increase in electrical conductivity and electromagnetic interference shielding improvement. (orig.)

Fluorescence microscopic and microautoradiographic studies on apoptosis of bone tumor cells induced by 153Sm-EDTMP

International Nuclear Information System (INIS)

Zhu Shoupeng; Xiao Dong; Han Xiaofeng

1997-09-01

The apoptosis of bone tumor cells treated with internal irradiation by 153 Sm-EDTMP was studied. The morphological changes in bone tumor cells were observed by fluorescence microscopic and microautoradiographic observations. It was found that bone tumor cells internally irradiated with 153 Sm-EDTMP, displayed significant nuclear fragmentation and marked pyknosis as well as apoptotic bodies formation. The microautoradiographic study showed that 153 Sm-EDTMP could permeate through cell membrane and displayed membrane-seeking condensation in tumor cells. Soon afterwards 153 Sm-EDTMP could be phagocytized by the tumor cells and distributed in cytoplasm and nucleus in the form of phagosome. With the prolongation of observing time, the membrane-bounded apoptotic bodies was observed. With the lengthening of internal irradiation time by 153 Sm-EDTMP, the inhibition rate of proliferation of bone tumor cells increased progressively. (10 refs., 9 figs., 1 tab.)

Småföretagarnas Bootstrapping : en kvantitativ studie om hur småföretagens bootstrappinganvändning förklaras utifrån företagens livscykel

OpenAIRE

Karlsson, Anton; Nilsson, Pontus

2017-01-01

Arbetslösheten i Sverige uppgick under 2017 års första månad till 7,3 procent. En aktuell faktor för att minska arbetslösheten är entreprenörskap. Entreprenörskap är en viktig del i utvecklingen för att driva småföretag. Småföretagen svarar för en betydande del av Sveriges sysselsättning, men lider av låg överlevnadsgrad. För att öka sannolikheten för överlevnad använder många småföretag olika bootstrappingmetoder. Syftet med bootstrapping är att finna lösningar på resursbehov och kan därför ...

Thermal decomposition of the Fe17 Sm2 N3 phase

International Nuclear Information System (INIS)

Cabral, F.A.O.; Gama, S.; Morais, E. de; Sanjurjo, N.L.; Ribeiro, C.A.

1996-01-01

We studied the high temperature decomposition mechanism for the Fe 17 Sm 2 N 3 phase using several different experimental techniques, as thermomagnetic and thermogravimetric analyses. Our results slow that the decomposition occurs in a two step scheme. In the first reaction we have the formation of Sm N and a solid solution of nitrogen in iron. In the second step, this solid solution degases, and we observe the evolution of nitrogen over a broad temperature range. (author)

Production of SmCo5 alloy by calciothermic reduction of samarium oxide

International Nuclear Information System (INIS)

Krishnan, T.S.; Gupta, C.K.

1988-01-01

Among the established permanent magnets, SmCo 5 magnet occupies the foremost position as it offers a unique combination of high energy product, coercivity and curie temperature. The SmCo 5 magnets are thus extensively used for high field applications. These are also best suited for use in environments where high demagnetizing field and high temperature are operative. Also, for applications where high performance and miniaturization are the over-riding considerations, the choice again falls on SmCo 5 magnets. The main deterrent to the widespread use of SmCo 5 magnet is its high cost. Both samarium and cobalt metals are high priced, and the magnets prepared from their directly melted alloy are thus naturally very expensive. An alternate process involving calcium reduction of their oxide intermediates has, therefore, been studied and the alloy prepared by this process has been evaluated and found satisfactory for magnet production. The process essentially involves compaction of the charge mix containing samarium oxide, cobalt oxide (or metal) and calcium metal and reduction of the charge compact at 1000-1300 degrees C in hydrogen atmosphere, followed by water and acid leaching, drying and classification

Surface properties of SmB{sub 6} from X-ray photoemission spectroscopy

Energy Technology Data Exchange (ETDEWEB)

Heming, Nadine; Treske, Uwe; Knupfer, Martin; Koitzsch, Andreas [Institute for Solid State Research, IFW Dresden (Germany); Buechner, Bernd [Institute for Solid State Research, IFW Dresden (Germany); Institut fuer Festkoerperphysik, TU Dresden (Germany); Inosov, Dmytro [Institut fuer Festkoerperphysik, TU Dresden (Germany); Shitsevalova, Natalya Y.; Filipov, Volodymyr B. [Institute for Problems of Material Science, Kiev (Ukraine); Kraus, Stephan [BESSY II, Berlin (Germany)

2015-07-01

The mixed valence compound SmB{sub 6} has been well known for its anomalous low temperature resistivity behavior for decades: At temperatures below 50 K, SmB{sub 6} transmutes from a metal to an insulator but shows residual resistivity for temperatures less than 5 K. Renewed interest in this material comes from theoretical proposals, predicting topological protected surface states making this compound the prime candidate for the new material class of ''Topological Kondo Insulators''. Indeed, elaborate transport experiments have evidenced that the residual conductivity occurs only at the surface. However, it is generally well known that the surface of f-systems undergoes valence changes and reconstructions, which may also influence the surface properties of this material. Applying surface sensitive soft X-ray photoemission spectroscopy, we have investigated the surface properties of freshly cleaved SmB{sub 6} single crystals at 15 K monitoring the Sm valance, the chemical state of boron as well as the surface stoichiometry, and also the development of these over time and with increased temperature: We have found that the surface shows an unexpected complexity stemming from both intrinsic and extrinsic changes.

An electrochemical approach for removal of radionuclidic contaminants of Eu from 153Sm for effective use in metastatic bone pain palliation.

Science.gov (United States)

Chakravarty, Rubel; Chakraborty, Sudipta; Khan, Mohammed Sahiralam; Ram, Ramu; Sarma, Haladhar Dev; Dash, Ashutosh

2018-03-01

Thermal neutron activation of 152 Sm [ 152 Sm(n,γ) 153 Sm] using natural or isotopically enriched (by 152 Sm) samarium target is the established route for production of 153 Sm used for preparation of 153 Sm-EDTMP for pain palliation in cancer patients with disseminated bone metastases. However, some long-lived radionuclidic contaminants of Eu, such as, 154 Eu (t ½ =8.6y) are also produced during the target activation process. This leads to detectable amount of Eu radionuclidic contaminants in patients' skeleton even years after administration with therapeutic doses of 153 Sm-EDTMP. Further, the presence of such contaminants in 153 Sm raises concerns related to radioactive waste management. The aim of the present study was to develop and demonstrate a viable method for large-scale purification of 153 Sm from radionuclidic contaminants of Eu. A radiochemical separation procedure adopting electroamalgamation approach has been critically evaluated. The influence of different experimental parameters for the quantitative removal radionuclidic contaminants of Eu from 153 Sm was investigated and optimized. The effectiveness of the method was demonstrated by purification of ~37 GBq of 153 Sm in several batches. As a proof of concept, 153 Sm-EDTMP was administered in normal Wistar rats and ex vivo γ-spectrometry of bone samples were carried out. After carrying out the electrolysis under the optimized conditions, the radionuclidic contaminants of Eu could not be detected in purified 153 Sm solution by γ-spectrometry. The overall yield of 153 Sm obtained after the purification process was >85%. The reliability of this approach was amply demonstrated in several batches, wherein the performance remained consistent. Ex vivo γ-spectrometry of bone samples of Wistar rats administered with 153 Sm-EDTMP (prepared using electrochemically purified 153 Sm) did not show photo peaks corresponding to radionuclidic contaminants of Eu. A viable electrochemical strategy for the large

Effect of samarium (Sm) addition on the microstructures and mechanical properties of Al–7Si–0.7Mg alloys

International Nuclear Information System (INIS)

Qiu, Hongxu; Yan, Hong; Hu, Zhi

2013-01-01

Highlights: •Sm affected the secondary dendrite arm spacing of Al–7Si–0.7Mg alloy. •The coarse plate-like eutectic silicon was fully modified into a fine branched and particle structure when 0.6 wt.% Sm added. •The tensile properties were enhanced by the addition of Sm. •Sm has marked effects on eutectic temperature and the latent heat ΔH R on remelting behavior. •The morphology and chemical composition of Sm-rich intermetallics were studied. -- Abstract: The effects of samarium (Sm) additions (0–0.9 wt.%) on the microstructures and mechanical properties of Al–7Si–0.7Mg alloys have been studied in this article. The microstructures of the as-cast samples were examined by optical microscopy (OM) and scanning electron microscopy (SEM). The experimental results indicated that the rare earth Sm affected the secondary dendrite arm spacing (SDAS) of Al–7Si–0.7Mg alloy. And it was found that Sm had great modification effects on the microstructures of eutectic silicon. When 0.6 wt.% Sm was added to the alloy, the coarse plate-like eutectic silicon was fully modified into a fine fibrous structure; the dendrites of Al–7Si–0.7Mg alloy was best refined. The mechanical properties were investigated by tensile test. The findings indicate that the tensile properties and elongation were improved by the addition of Sm. And a good combination of ultimate tensile strength (215 MPa) and elongation (3.3%) was obtained when the Sm addition was up to 0.6 wt.%. Furthermore the results of thermal analysis reveal that Sm addition had marked effects on eutectic temperature and the latent heat ΔH R on remelting behavior

Soil Moisture Active Passive Mission L4_SM Data Product Assessment (Version 2 Validated Release)

Science.gov (United States)

Reichle, Rolf Helmut; De Lannoy, Gabrielle J. M.; Liu, Qing; Ardizzone, Joseph V.; Chen, Fan; Colliander, Andreas; Conaty, Austin; Crow, Wade; Jackson, Thomas; Kimball, John;

CCSDS SM and C Mission Operations Interoperability Prototype

Science.gov (United States)

Lucord, Steven A.

2010-01-01

This slide presentation reviews the prototype of the Spacecraft Monitor and Control (SM&C) Operations for interoperability among other space agencies. This particular prototype uses the German Space Agency (DLR) to test the ideas for interagency coordination.

Influence of annealing and nitrogenation on structure and magnetic properties of mechanically alloyed Sm-Fe powders

International Nuclear Information System (INIS)

Teresiak, A.; Kubis, M.; Mattern, N.; Wolf, M.; Mueller, K.-H.

1998-01-01

Sm-Fe-N compounds were prepared by mechanical alloying, subsequent annealing and nitrogenation. For crystal structure investigations of the non-equilibrium phases Sm 2 Fe 17+x and Sm 2 Fe 17+x N y , respectively, formed at the various annealing temperatures T A , XRD with following Rietveld analysis was used. For T A between 600 C and 750 C a modified hexagonal TbCu 7 structure (space group P6/mmm) was found in which the Fe(2c) site is replaced by the partially (1/3) and randomly occupied Fe(61) site. The approximated composition is SmFe 8.8-9.0 . The nitrogenated alloys crystallize in the same structure for 600 C A A ≤ 900 C a disordered modified Th 2 Zn 17 structure (space group R anti 3m) was found that is formed by introducing additional Fe (6c) and Sm(3a) positions. The degree of order of the Sm- and Fe-atoms in c-direction increases with increasing annealing temperature. The completely ordered stoichiometric Sm 2 Fe 17 structure could not be reached by annealing the ball milled elemental powders. The nitrided alloys already form this intermediate structure at T A = 750 C. The interstitial nitrogen occupies the 9e site. The estimated nitrogen content is higher in the hexagonal phases than in the rhombohedral phase. Optimum magnetic properties, in particular a coercitivity μ 01 H C = 3.7 T and a good squareness of the demagnetization curve, were obtained for T A = 750 C. Here we found a nitrogen content of y = 3 for Sm 2 Fe 17+x N y . (orig.)

Study of 148-152Sm nuclei employing γ - derived from B(E2) values and level energies

International Nuclear Information System (INIS)

Sharma, Aparna; Varshney, A.K.; Singh, M.; Gupta, D.K.; Singh, Yuvraj; Gupta, K.K.; Bihari, Chhail; Varshney, Mani

2011-01-01

The study of samarium nuclei has been a challenging theoretical problem, since they lie in the range from near spherical to well deformed shapes. 148 Sm was believed to be basically spherical while 154 Sm is thought to be well deformed nucleus and 150-15 '2Sm are transitional nuclei

153Sm-HM for arthritic knee pain. Estimated dosimetry

International Nuclear Information System (INIS)

Hardy-Pérez, Alberto E.; Torres-García, Eugenio; Mitsoura, Eleni; Jiménez-Mancilla, Nallely P.; Arteaga-de-Murphy, Consuelo; Pedraza-López, Martha

2012-01-01

Osteoarthritis is the most common type of arthropathy and after cardiovascular diseases is the most disabling disease in developing countries. The dosimetry for the clinical application of 153-samarium-hydroxymacroaggregates ( 153 Sm-HM) for radiation synovectomy (RSV) and palliative treatment for arthritic pain, as far as we know, has not been reported. The aim of this research was to estimate the radiation dose necessary for synovial ablation and pain palliation with minimum risk to the patient. 153 Sm-HM (370 MBq) was administered intra-articularly in a patient with severe knee pain and hindered motility. Regions of interest drawn on sequential, conjugated, anterior and posterior scintigraphy images were used to obtain the respective activity. The data was entered into a knee joint histological-geometric model designed with micrometric dimensions to represent the synovial cell layers. The Monte Carlo code was used to calculate the absorbed dose in each of the 12 model-cells representing the distance from the synovial liquid to the cartilage or bone. The absorbed dose in the synovial cavity was 114 Gy which is sufficient energy for RSV. The treated patient referred little pain and higher motility with no adverse reactions. 153 Sm-HM is a potentially valid radiopharmaceutical for RSV, which effectively palliates knee pain.

First-order-reversal-curve analysis of exchange-coupled SmCo/NdFeB nanocomposite alloys

International Nuclear Information System (INIS)

Pan, Mingxiang; Zhang, Pengyue; Ge, Hongliang; Yu, Nengjun; Wu, Qiong

2014-01-01

Exchange-coupled SmCo 5 /Nd 2 Fe 14 B nanocomposite magnets have been fabricated by ball milling of the micrometer sized SmCo 5 and Nd 2 Fe 14 B powders. The influence of Nd 2 Fe 14 B content on the microstructure and magnetic properties of these hybrid alloys was investigated. The alloys that show strong intergrain exchange-coupling behavior with (BH) max =2.95 MGOe was obtained when the two hard phases are well coupled. A first-order-reversal-curve (FORC) analysis was performed for both SmCo 5 single-phase magnet and SmCo 5 /Nd 2 Fe 14 B hybrid magnet; the FORC diagrams results show two major peaks for the hybrid magnets. In both cases, the magnetization reversal behaviors for these alloys were discussed in detail and are consistent with the results of δM plots. - Highlights: • Exchange-coupled SmCo 5 /Nd 2 Fe 14 B nanocomposite magnets were studied. • Magnetization reversal behaviors of the hybrid magnet were discussed. • The FORCs analysis is taken to identify the optimal conditions for hybrid magnet

Model SM-1 ballast density gauge

International Nuclear Information System (INIS)

Gao Weixiang; Fang Jidong; Zhang Xuejuan; Zhang Reilin; Gao Wanshan

1990-05-01

The ballast density is one of the principal parameters for roadbed operating state. It greatly affects the railroad stability, the accumulation of railroad residual deformation and the amount of work for railroad maintenance. SM-1 ballast density gauge is designed to determine the density of ballast by using the effect of γ-ray passed through the ballast. Its fundamentals, construction, specifications, application and economic profit are described

Molecular Characterization of the Schistosoma mansoni Zinc Finger Protein SmZF1 as a Transcription Factor

Science.gov (United States)

D'Astolfo, Diego S.; Cardoso, Fernanda C.; Rajão, Matheus A.; Mourão, Marina M.; Gava, Elisandra; Oliveira, Sérgio C.; Macedo, Andréa M.; Machado, Carlos R.; Pena, Sérgio D. J.; Kitten, Gregory T.; Franco, Glória R.

2009-01-01

Background During its development, the parasite Schistosoma mansoni is exposed to different environments and undergoes many morphological and physiological transformations as a result of profound changes in gene expression. Characterization of proteins involved in the regulation of these processes is of importance for the understanding of schistosome biology. Proteins containing zinc finger motifs usually participate in regulatory processes and are considered the major class of transcription factors in eukaryotes. It has already been shown, by EMSA (Eletrophoretic Mobility Shift Assay), that SmZF1, a S. mansoni zinc finger (ZF) protein, specifically binds both DNA and RNA oligonucleotides. This suggests that this protein might act as a transcription factor in the parasite. Methodology/Principal Findings In this study we extended the characterization of SmZF1 by determining its subcellular localization and by verifying its ability to regulate gene transcription. We performed immunohistochemistry assays using adult male and female worms, cercariae and schistosomula to analyze the distribution pattern of SmZF1 and verified that the protein is mainly detected in the cells nuclei of all tested life cycle stages except for adult female worms. Also, SmZF1 was heterologously expressed in mammalian COS-7 cells to produce the recombinant protein YFP-SmZF1, which was mainly detected in the nucleus of the cells by confocal microscopy and Western blot assays. To evaluate the ability of this protein to regulate gene transcription, cells expressing YFP-SmZF1 were tested in a luciferase reporter system. In this system, the luciferase gene is downstream of a minimal promoter, upstream of which a DNA region containing four copies of the SmZF1 putative best binding site (D1-3DNA) was inserted. SmZF1 increased the reporter gene transcription by two fold (p≤0.003) only when its specific binding site was present. Conclusion Taken together, these results strongly support the hypothesis

Investigations on optical properties of Sm{sup 3+} ion doped boro-phosphate glasses

Energy Technology Data Exchange (ETDEWEB)

Vijayakumar, R.; Suthanthirakumar, P.; Karthikeyan, P.; Marimuthu, K., E-mail: mari-ram2000@yahoo.com [Department of Physics, Gandhigram Rural Institute – Deemed University, Gandhigram – 624302 (India)

2015-06-24

The Sm{sup 3+} doped Boro-phosphate glasses with the chemical composition 60H{sub 3}BO{sub 3}+20Li{sub 2}CO{sub 3}+10ZnO+(10−x) H{sub 6}NO{sub 4}P+xSm{sub 2}O{sub 3} (where x= 0.1, 0.5, 1 and 2 in wt%) have been prepared by melt quenching technique. The prepared glasses were characterized through optical absorption and luminescence spectral measurements. The band gap energies corresponding to the direct and indirect allowed transitions and the Urbach’s energy values were estimated from the absorption spectra. Judd-Ofelt intensity parameters have been derived to predict the radiative properties of the various emission transitions. In order to identify the emission color of the prepared glasses, the emission intensities were analyzed using CIE 1931 color chromaticity diagram. The energy transfer process takes place between Sm{sup 3+}−Sm{sup 3+} ions through cross-relaxation mechanism have also been investigated and the results were discussed and reported.

Magnetic leverage effects in amorphous SmCo/CoAlZr heterostructures

International Nuclear Information System (INIS)

Procter, R. A.; Hase, T. P. A.; Magnus, F.; Andersson, G.; Hjörvarsson, B.; Sánchez-Hanke, C.

2015-01-01

Although magnetic heterostructures are the basis of many magnetic technologies, the mechanisms involved in magnetization reversals in such structures are not fully understood, especially in amorphous multilayers. Here, we report on the SmCo/CoAlZr system and exploit resonant magnetic x-ray scattering to probe the element specific magnetization reversals. When combined into a tri-layer structure, two different switching fields and reversal mechanisms are observed for the Sm and Co sub-lattices. We argue that the decoupling of the sub-lattices arises from the local distribution of atomic species within the amorphous matrix leading to a strong magnetic leverage effect and exchange pinning. The decoupling arises due to strong interactions between regions of high Co density which span the interface. The relatively sparse interactions between Sm and Co induce a localized pinning of the Co-rich areas, resulting in an exchange bias in minor loops and an enhanced coercivity

Magnetic leverage effects in amorphous SmCo/CoAlZr heterostructures

Energy Technology Data Exchange (ETDEWEB)

Procter, R. A., E-mail: r.a.procter@warwick.ac.uk; Hase, T. P. A. [Department of Physics, University of Warwick, Coventry CV4 7AL (United Kingdom); Magnus, F.; Andersson, G.; Hjörvarsson, B. [Department of Physics and Astronomy, Uppsala University, Box 516, 751 20 Uppsala (Sweden); Sánchez-Hanke, C. [National Synchrotron Light Source, Brookhaven National Laboratory, Upton, New York 11973 (United States)

2015-08-10

Although magnetic heterostructures are the basis of many magnetic technologies, the mechanisms involved in magnetization reversals in such structures are not fully understood, especially in amorphous multilayers. Here, we report on the SmCo/CoAlZr system and exploit resonant magnetic x-ray scattering to probe the element specific magnetization reversals. When combined into a tri-layer structure, two different switching fields and reversal mechanisms are observed for the Sm and Co sub-lattices. We argue that the decoupling of the sub-lattices arises from the local distribution of atomic species within the amorphous matrix leading to a strong magnetic leverage effect and exchange pinning. The decoupling arises due to strong interactions between regions of high Co density which span the interface. The relatively sparse interactions between Sm and Co induce a localized pinning of the Co-rich areas, resulting in an exchange bias in minor loops and an enhanced coercivity.

Plasma spraying of hard magnetic coatings based on Sm-Co alloys

International Nuclear Information System (INIS)

KrasnoyarskiyRabochiy prospect, Krasnoyarsk, 660014 (Russian Federation))" data-affiliation=" (Siberian State Aerospace University named after Academician M.F. Reshetnev 31 KrasnoyarskiyRabochiy prospect, Krasnoyarsk, 660014 (Russian Federation))" >Saunin, V N; KrasnoyarskiyRabochiy prospect, Krasnoyarsk, 660014 (Russian Federation))" data-affiliation=" (Siberian State Aerospace University named after Academician M.F. Reshetnev 31 KrasnoyarskiyRabochiy prospect, Krasnoyarsk, 660014 (Russian Federation))" >Telegin, S V

2015-01-01

Our research is focused on the formation of hard magnetic coatings by plasma spraying an arc-melted Sm-Co powder. We have studied basic magnetic characteristics depending on the components ratio in the alloy. A sample with a 40 wt.% Sm coating exhibits the highest coercive force (63 kOe) as compared to near-to-zero coercive force in the starting powder. X-ray structure analysis of the starting alloy and the coating reveals that the amount of SmCo 5 phase in the sprayed coating increases occupying up to 2/3 of the sample. We have also studied temperature dependence of the coating and have been able to obtain plasma sprayed permanent magnets operating within the temperature range from -100 to +500 °C. The technique used does not involve any additional thermal treatment and allows a coating to be formed right on the magnetic conductor surface irrespective of the conductor geometry

Electrical resistivity, optical and magnetic properties of the layered oxyselenide SmCuOSe

International Nuclear Information System (INIS)

Llanos, Jaime; Pena, Octavio

2005-01-01

The electrical and magnetic properties of the tetragonal phase SmCuOSe are reported as a function of the temperature. The optical properties were studied by means of diffuse reflectance spectrum in the UV-Vis range. The electrical resistivity measurements as well as diffuse reflectance spectrum show that SmCuOSe is a semiconductor with an optical band gap (E g ) of 2.6eV. In this phase, Cu is at its monovalent oxidation state and, as such, it does not contribute to the total magnetic moment, whereas Sm is in its 3+ oxidation state, with a large VanVleck contribution due to the admixture of the fundamental state with higher energy levels

A study of 153Sm-citrate-hydroxyapatite synovectomy in knee synovitis with rheumatoid arthritis

International Nuclear Information System (INIS)

Fan Yanggang; Li Guohua; Yao Guozhong; Zhang Qingcheng; Li Guangming

2006-01-01

Objective: To investigate the efficacy and safety of 153 Sm-citrate-hydroxyapatite (HA) synovectomy in knee synovitis with rheumatoid arthritis (RA). Methods: In 43 RA patients ineffective to routine anti-rheumatic drugs (DMMARDs) therapy, radiation synovectomy was performed by 153 Sm-citrate-HA in 67 joints and its efficacy and safety were evaluated. Results: Radioactivity was evenly distributed as observed by gamma camera after injection. In 8 cases leakage of radioactivity was detected after 24 h, and accounted to 153 Sm-citrate-HA synovectomy is effective after short-term and medium-term follow-up and it is a safe procedure. (authors)

Trials to optimize dosimetry for 153Sm-EDTMP therapy to improve therapeutic effects

International Nuclear Information System (INIS)

Riccabona, G.; Moncayo-Naveda, R.; Oberlandstaetter, M.; Donnemiller, E.; Kendler, D.

2001-01-01

In a trial to improve results of therapy with 153 Sm-EDTMP for pain control in patients with disseminated bone metastases dosimetric studies were performed. Out of 30 treated patients 8 were selected for the study at random (5 breast Ca., 3 prostate Ca.). Whole body retention (WBR) of 99m Tc-DPD and 99m Tc-EDTMP was compared with WBR of 153 Sm-EDTMP. Volume of metastases and regional 99 m Tc-phosphonate uptake were assessed by SPECT and conjugated whole body scan data after phantom studies. Effective half-life was estimated also. Clinically results of pain control, side effects and changes of in vitro parameters were followed after therapy for up to 8 months. Therapy was performed in these patients with 55,5 MBq/kg body weight. Results showed an identical pattern of radioactivity distribution on 99 Tc-phosphonate and 153 Sm-EDTMP posttherapy scans, WBR of tracers and therapeutic agent was similar. Tumour volumes were 151-652 mL, count ratios metastases/normal bone 1,72-2,41, so that 6-50% of applied 153 Sm-EDTMP were concentrated in bone lesions. This gave dose estimates of 2,8-13,7 Gy in metastases. Evaluation of clinical results showed that the majority of very good results were observed in patients receiving > 10 Gy (n=3) while with lower doses only 1/4 responded very well. 1 patient was lost to follow-up due to death in the first month after therapy. Moderate and transient myelodepression (platelets) was seen in 3/7 patients without relation to Gy applied. As obviously 153 Sm concentration is not homogenous in bone metastases it can be assumed, that in border zones between tumour and bone 30-40 Gy can be delivered when 10 Gy are calculated for the whole lesion, which would explain the satisfactory therapeutic effect in our study. The dosimetric approach to 153 Sm-EDTMP therapy could necessitate the application of higher amounts of 153 Sm-EDTMP to reach adequate radiation doses in lesions without necessarily increasing risk of myelodepression and with even

The Preparation and Optical Properties of Novel LiLa(MoO42:Sm3+,Eu3+ Red Phosphor

Directory of Open Access Journals (Sweden)

Jiaxi Wang

2018-02-01

Full Text Available Novel LiLa1−x−y(MoO42:xSm3+,yEu3+ (in short: LL1−x−yM:xSm3+,yEu3+ double molybdate red phosphors were synthesized by a solid-state reaction at as low temperature as 610 °C. The optimal doping concentration of Sm3+ in LiLa1−x(MoO42:xSm3+ (LL1−xM:xSm3+ phosphor is x = 0.05 and higher concentrations lead to emission quenching by the electric dipole—electric dipole mechanism. In the samples co-doped with Eu3+ ions, the absorption spectrum in the near ultraviolet and blue regions became broader and stronger than these of the Sm3+ single-doped samples. The efficient energy transfer from Sm3+ to Eu3+ was found and the energy transfer efficiency was calculated. Under the excitation at 403 nm, the chromaticity coordinates of LL0.95−yM:0.05Sm3+,yEu3+ approach to the NTSC standard values (0.670, 0.330 continuously with increasing Eu3+ doping concentration. The phosphor exhibits high luminous efficiency under near UV or blue light excitation and remarkable thermal stability. At 150 °C, the integrated emission intensity of the Eu3+ remained 85% of the initial intensity at room temperature and the activation energy is calculated to be 0.254 eV. The addition of the LL0.83M:0.05Sm3+,0.12Eu3+ red phosphors can improve the color purity and reduce the correlated color temperature of WLED lamps. Hence, LL1−x−yM:xSm3+,yEu3+ is a promising WLED red phosphor.

Prion-like nanofibrils of small molecules (PriSM): A new frontier at the intersection of supramolecular chemistry and cell biology.

Science.gov (United States)

Zhou, Jie; Du, Xuewen; Xu, Bing

2015-01-01

Formed by non-covalent interactions and not defined at genetic level, the assemblies of small molecules in biology are complicated and less explored. A common morphology of the supramolecular assemblies of small molecules is nanofibrils, which coincidentally resembles the nanofibrils formed by proteins such as prions. So these supramolecular assemblies are termed as prion-like nanofibrils of small molecules (PriSM). Emerging evidence from several unrelated fields over the past decade implies the significance of PriSM in biology and medicine. This perspective aims to highlight some recent advances of the research on PriSM. This paper starts with description of the intriguing similarities between PriSM and prions, discusses the paradoxical features of PriSM, introduces the methods for elucidating the biological functions of PriSM, illustrates several examples of beneficial aspects of PriSM, and finishes with the promises and current challenges in the research of PriSM. We anticipate that the research of PriSM will contribute to the fundamental understanding at the intersection of supramolecular chemistry and cell biology and ultimately lead to a new paradigm of molecular (or supramolecular) therapeutics for biomedicine.

Nondestructive analysis of RA reactor fuel burnup, Program for burnup calculation base on relative yield of {sup 106}Ru, {sup 134}Cs and {sup 137}Cs in the irradiated fuel; Nedestruktivno odredjivanje izgaranja goriva reaktora RA, Program za izracunavanje izgaranja na osnovu relativne zastupljenosti {sup 106}Ru, {sup 134}Cs i {sup 137}Cs u ozracenom gorivu

Energy Technology Data Exchange (ETDEWEB)

Bulovic, V F [Institute of nuclear sciences Boris Kidric, Vinca, Beograd (Yugoslavia)

1971-07-01

Burnup of low enriched metal uranium fuel of the RA reactor is described by two chain reactions. Energy balance and material changes in the fuel are described by systems of differential equations. Numerical integration of these equations is base on the the reactor operation data. Neutron flux and percent of Uranium-235 or more frequently yield of epithermal neutrons in the neutron flux, is determined by iteration from the measured contents of {sup 106}Ru, {sup 134}Cs and {sup 137}Cs in the irradiated fuel. The computer program was written in FORTRAN-IV. Burnup is calculated by using the measured activities of fission products. Burnup results are absolute values. Sagorevanje maloobogacenog uranskog metalnog goriva reaktora RA je opisano dvema lancanim reakcijama. Energetski bilans i materijalne promene u gorivu su opisane sistemima diferencijalnih jednacina. Numericka integracija jednacina se vrsi na osnovu podataka u dinamici rada reaktora. Fluks reaktorskih neutrona i procenat urana-235 ili ucesce epitermalnih neutrona u fluksu, odredjuje se iterativno na osnovu izmerenog sadrzaja {sup 106}Ru, {sup 134}Cs i {sup 137}Cs u ozracenom gorivu. Program je napisan u FORTRAN-u IV u jednom bloku, bez podprograma. Izracunavanje izgaranja je zasnovano na izmerenim kolicnicima aktivnosti fisionih produkata. Rezultati izgaranja imaju apsolutni karakter (author)

Report of the Technology Service - Annex B; Prilog B - Izvestaj o radu tehnoloske sluzbe

Energy Technology Data Exchange (ETDEWEB)

Martinc, R; Cupac, S; Vukadin, Z; Stosic, T; Sotic, O [Institute of Nuclear Sciences Boris Kidric, Vinca, Beograd (Serbia and Montenegro)

1986-12-01

This report describes the organisational structure of the technology service and its activities and tasks: routine control of reactor parameters and cooperation with the reactor users; development of methodology of reactor control and its application; control of heavy water and gas system operation; dosimetry measurements of contamination in the reactor building; technical aspects of radiation protection; decontamination and accident analysis. Separate chapter describes building of the reactor experimental loop for irradiation of fuel elements and construction materials, which will be placed in the central experimental channel VK-5. [Serbo-Croat] Ovaj izvestaj opisuje organizacionu semu tehnoloske sluzbe i zadatke koje ona obavlja: rutinska kontrola reaktorsko-fizickih parametara reaktora i saradnja sa korisnicima reaktora, razvojni rad na metodologiji kontrole reaktora i njegovog koriscenja, kontrola rezima rada teskovodnog i gasnog sistema, dozimetrija i tehnicka zastita od zracenja u zgradi reaktora, dekontaminacija i akcidentalna analiza. Posebno poglavlje opisuje izgradnju eksperimentale petlje za ozracivanje gorivnih elemenata i konstrukcionih materijala koja ce biti postavljena u centralnom eksperimentalnom kanalu VK-5 reaktora RA, koja je projektovana kao slozena eksperimentalna instalacija.

Measurement of N and C diffusion in Sm2Fe17 by magnetic relaxation

International Nuclear Information System (INIS)

Mommer, N.; Hirscher, M.; Gerlach, M.; Van Lier, J.; Kronmueller, H.; Kubis, M.; Mueller, K.-H.

1998-01-01

Magnetic after-effect (MAE) measurements of nitrided and carburized Sm 2 Fe 17 compounds were performed in the temperature range of 140 K to 480 K. Both nitrided and carburized compounds show relaxation maxima at 285 and 300 K, respectively, which are absent in pure Sm 2 Fe 17 compounds. Therefore, these relaxation maxima are attributed to jumps of interstitially dissolved nitrogen or carbon atoms. Numerical evaluation yielded an activation enthalpy Q N (0.84±0.05) eV and a pre-exponential factor τ 0 N =3.10 -15±1 s for the short-range diffusion of N atoms. The corresponding values for the carbon diffusion are Q C =(0.91±0.05) eV and τ 0 C =1.10 -15±1 s. The carbon and nitrogen content of the samples was determined from the increase in mass during nitrogenation or carburization to Sm 2 Fe 17 N 1.2 and Sm 2 Fe 17 C 2.6 . (orig.)

Solid-state amorphization of SmFe3 by hydrogenation

International Nuclear Information System (INIS)

Mueller, K.H.; Kubis, M.; Handstein, A.; Gutfleisch, O.

2000-01-01

Hydrogen-induced amorphization (HIA) has received much attention as a method for the preparation of amorphous compounds since its discovery by Yeh et al. Meanwhile it has been observed for a large number of intermetallic compounds with C15, C23, B8 2 , DO 19 and L1 2 structures. E.G. the C15 Laves-type compounds (MgCu 2 -type structure) of rare earth (R) - transition metal (T) compounds RT 2 show HIA for R = Y, Ce, Pr, Nd, Sm, Gd, Tb, Dy, Ho and Er. Aoki et al. postulated that new amorphizing compounds can be expected at high hydrogen pressures. In this work, the structural changes of SmFe 3 (PuNi 3 -type structure) during heating in high hydrogen pressures are reported

RA Research reactor, Part 1, Operation and maintenance of the RA nuclear reactor for 1988; Istrazivacki nuklearni reaktor RA, deo 1, pogon i odrzavanje nukleanog reaktora RA u 1988. godini

Energy Technology Data Exchange (ETDEWEB)

Sotic, O; Martinc, R; Cupac, S; Sulem, B; Badrljica, R; Majstorovic, D; Sanovic, V [Institute of Nuclear Sciences Boris Kidric, Vinca, Beograd (Serbia and Montenegro)

1988-12-15

According to the action plan for 1988, operation of the RA reactor should have been restarted in October, but the operating license was not obtained. Control and maintenance of the reactor components was done regularly and efficiently dependent on the availability of the spare parts. The major difficulty was maintenance of the reactor instrumentation. Period of the reactor shutdown was used for repair of the heavy water pumps in the primary coolant loop. With the aim to ensure future safe and reliable reactor operation, action were started concerning renewal of the reactor instrumentation. Design project was done by the soviet company Atomenergoeksport. The contract for constructing this equipment was signed, and it is planned that the equipment will be delivered by the end of 1990. In order to increase the space for storage of the irradiated fuel elements and its more efficient usage, projects were started concerned with reconstruction of the existing fuel handling equipment, increase of the storage space and purification of the water in the fuel storage pools. These projects are scheduled to be finished in mid 1989. This report includes 8 annexes concerning reactor operation, activities of services and financial issues. [Serbo-Croat] Prema planu za 1988. godinu, reaktor RA je trebalo da pusten u rad oktobra meseca, medjutim nije dobio dozvolu za nastavak rada. Kontrola i odrzavanje opreme izvrsavani su redovno i efikasno, u granicama koje su diktirane raspolozivoscu repromaterijala i rezervnih delova. Najvecu poteskocu pricinjavalo je odrzavanje instrumentacije. Period stajanja u 1988. godini iskoriscen je za remont teskovodnih pumpi u primarnom kolu hladjenja. U cilju povecanja pouzdanosti rada reaktora zapoceti su radovi na modernizaciji instrumentacije, projekat je izradjen u sovjetskoj organizaciji Atomenergoeksport, sklopljen je ugovor o izradi ove opreme koja bi trebalo da bude isporucena do kraja 1990. U cilju povecanja prostora za skladistenje ozracenog

High spin states in 143Sm

International Nuclear Information System (INIS)

Raut, R.; Ganguly, S.; Kshetri, R.; Mukherjee, G.; Mukherjee, A.; Banerjee, P.; Saha Sarkar, M.; Bhattacharya, S.; Goswami, A.; Bhattacharjee, T.; Basu, S.K.; Mukhopadhyaya, S.; Krishichayan; Chakraborty, A.; Gangopadhyay, G.

2004-01-01

Large amount of experimental data has been obtained in the recent past on several Nd (Z=60) and Pm (Z=61) isotopes near N=82 shell closure which exhibits an irregular yrast sequence, typical of a non-spherical shape at low spins. The nucleus 143 Sm (Z=62) with a single neutron hole in the N=82 closed shell was investigated as a part of this proposed study

Microstructure, magnetic and Moessbauer studies on spark-plasma sintered Sm-Co-Fe/Fe(Co) nanocomposite magnets

Energy Technology Data Exchange (ETDEWEB)

Rao, N V Rama; Saravanan, P; Gopalan, R; Raja, M Manivel; Rao, D V Sreedhara; Chandrasekaran, V [Defence Metallurgical Research Laboratory, Hyderabad-500 058 (India); Sivaprahasam, D [International Advanced Research Centre for Powder Metallurgy and New Materials Hyderabad-500 005 (India); Ranganathan, R [Saha Institute of Nuclear Physics, Kolkata-700 064 (India)], E-mail: rg_gopy@yahoo.com

2008-03-21

Nanocomposite powders comprising Sm-Co-Fe intermetallic phases and Fe(Co) were synthesized by high-energy ball milling and were consolidated into bulk magnets by the spark-plasma sintering (SPS) technique. While the microstructure of the SPS samples was characterized by transmission electron microscopy (TEM), the solubility of Fe in different phases was investigated using Moessbauer spectroscopy. TEM studies revealed that the spark-plasma sintered sample has Sm(Co,Fe){sub 5} as a major phase with Sm{sub 2}(Co,Fe){sub 17}, Sm(Co,Fe){sub 2} and Fe(Co) as secondary phases. The size of the nanocrystalline grains of all these phases was found to be in the range 50-100 nm. The Moessbauer spectra of the as-milled powders exhibited two different subspectra: a sextet corresponding to the Fe phase and a broad sextet associated with the Fe(Co) phase; while that of the SPS sample showed four different subspectra: a sextet corresponding to Fe and other three sextets corresponding to the Fe(Co), Sm(Co,Fe){sub 5} and Sm{sub 2}(Co,Fe){sub 17} phases; these results are in accordance with the TEM observation. Recoil magnetization and reversible susceptibility measurements revealed magnetically single phase behaviour of the SPS magnets.

Discovery of SM Higgs Boson in ATLAS Experiment

Indian Academy of Sciences (India)

Home; Journals; Resonance – Journal of Science Education; Volume 18; Issue 3. Discovery of SM Higgs Boson in ATLAS Experiment. Prafulla Kumar Behera. General Article Volume 18 Issue 3 March 2013 pp 248-263. Fulltext. Click here to view fulltext PDF. Permanent link:

Targeted radiotherapy with Sm-153-EDTMP in nine cases of canine primary bone tumours

Directory of Open Access Journals (Sweden)

R.J. Milner

1998-07-01

Full Text Available Nine dogs with primary bone tumours were treated with Samarium-153-EDTMP (Sm-153- EDTMP. Conventional treatment protocols were precluded by the size of the dogs and the owners' refusal of limb amputation. All the tumours were of the appendicular skeleton; 4 were confirmed osteosarcomas. The other 5 tumours were radiologically suspect for osteosarcoma. Bone scans were performed on all dogs using Technetium-99m-methylene diphosphonate (Tc-99m-MDP before administration of Sm-153-EDTMP. Regions of interest were identified over the contralateral limb at the same site as the tumour and counts per pixel were recorded for the tumour and contralateral limb and expressed as a ratio. The dogs were given 1 injection of 37 MBq/kg (1 mCi/kg of Sm-153-EDTMP intravenously. Thoracic and primary tumour site radiographs were taken at monthly or 2-monthly intervals to monitor progression of the primary tumour and search for evidence of metastasis. Two dogs showed no response to treatment, with an increase in bone pain, and were euthanased within 1 month. In 1 dog, a tumour of the scapula underwent complete involution and the dog is considered free of disease at 20 months post Sm-153-EDTMP treatment. The overall tumourcidal effect of a single dose of Sm-153-EDTMP on primary bone tumours was difficult to evaluate in this group of dogs, as, with one exception, all the primary tumours progressed over time and the dogs were euthanased. Pain control, for which Sm-155-EDTMP is used in man, was not evident, except in the dog that responded completely to treatment.

Coercivity in SmCo hard magnetic films for MEMS applications

Energy Technology Data Exchange (ETDEWEB)

Pina, E. [Instituto de Magnetismo Aplicado, RENFE-UCM, Universidad Complutense de Madrid, P.O. Box 155, 28230 Las Rozas, Madrid (Spain)]. E-mail: epina@renfe.es; Palomares, F.J. [Instituto de Ciencia de Materiales de Madrid-CSIC, c/ Sor Juana Ines de la Cruz s/n, 28049 Madrid (Spain); Garcia, M.A. [Instituto de Magnetismo Aplicado, RENFE-UCM, Universidad Complutense de Madrid, P.O. Box 155, 28230 Las Rozas, Madrid (Spain); Cebollada, F. [Departamento de Fisica Aplicada a las Telecomunicaciones, EUITT-UPM, Crtra. De Valencia km 7, 28031 Madrid (Spain); Hoyos, A. de [Instituto de Magnetismo Aplicado, RENFE-UCM, Universidad Complutense de Madrid, P.O. Box 155, 28230 Las Rozas, Madrid (Spain); Romero, J.J. [Instituto de Magnetismo Aplicado, RENFE-UCM, Universidad Complutense de Madrid, P.O. Box 155, 28230 Las Rozas, Madrid (Spain); Hernando, A. [Instituto de Magnetismo Aplicado, RENFE-UCM, Universidad Complutense de Madrid, P.O. Box 155, 28230 Las Rozas, Madrid (Spain); Unidad asociada ICMM-IMA. P.O. Box 155, 28230 Las Rozas Madrid (Spain); Gonzalez, J.M. [Unidad asociada ICMM-IMA. P.O. Box 155, 28230 Las Rozas Madrid (Spain)

2005-04-15

In this work we have investigated the thermal dependence of coercivity in 1.5 {mu}m thick SmCo{sub 5} films fabricated by sputtering technique. Samples were deposited onto Si substrates kept at different temperatures. Samples grown below 450 deg. C are amorphous, present low coercivity and require further crystallization processes in order to obtain the 1:5 SmCo hard phase. Samples grown at 450 deg. C are nanocrystalline in the as-deposited state and exhibit high room temperature in-plane coercivity. Correlation between the thermal dependence of coercivity and the nanostructure has been analyzed in the frame of the so-called micromagnetic model.

Coercivity in SmCo hard magnetic films for MEMS applications

International Nuclear Information System (INIS)

Pina, E.; Palomares, F.J.; Garcia, M.A.; Cebollada, F.; Hoyos, A. de; Romero, J.J.; Hernando, A.; Gonzalez, J.M.

2005-01-01

In this work we have investigated the thermal dependence of coercivity in 1.5 μm thick SmCo 5 films fabricated by sputtering technique. Samples were deposited onto Si substrates kept at different temperatures. Samples grown below 450 deg. C are amorphous, present low coercivity and require further crystallization processes in order to obtain the 1:5 SmCo hard phase. Samples grown at 450 deg. C are nanocrystalline in the as-deposited state and exhibit high room temperature in-plane coercivity. Correlation between the thermal dependence of coercivity and the nanostructure has been analyzed in the frame of the so-called micromagnetic model

First-order-reversal-curve analysis of exchange-coupled SmCo/NdFeB nanocomposite alloys

Energy Technology Data Exchange (ETDEWEB)

Pan, Mingxiang; Zhang, Pengyue, E-mail: Zhang_pengyue@cjlu.edu.cn; Ge, Hongliang; Yu, Nengjun; Wu, Qiong

2014-06-01

Exchange-coupled SmCo{sub 5}/Nd{sub 2}Fe{sub 14}B nanocomposite magnets have been fabricated by ball milling of the micrometer sized SmCo{sub 5} and Nd{sub 2}Fe{sub 14}B powders. The influence of Nd{sub 2}Fe{sub 14}B content on the microstructure and magnetic properties of these hybrid alloys was investigated. The alloys that show strong intergrain exchange-coupling behavior with (BH){sub max}=2.95 MGOe was obtained when the two hard phases are well coupled. A first-order-reversal-curve (FORC) analysis was performed for both SmCo{sub 5} single-phase magnet and SmCo{sub 5}/Nd{sub 2}Fe{sub 14}B hybrid magnet; the FORC diagrams results show two major peaks for the hybrid magnets. In both cases, the magnetization reversal behaviors for these alloys were discussed in detail and are consistent with the results of δM plots. - Highlights: • Exchange-coupled SmCo{sub 5}/Nd{sub 2}Fe{sub 14}B nanocomposite magnets were studied. • Magnetization reversal behaviors of the hybrid magnet were discussed. • The FORCs analysis is taken to identify the optimal conditions for hybrid magnet.

Hydrogenation-disproportionation-desorption-recombination in Sm2Fe16M (M=Al, Ga and Si) and magnetic properties of their carburized powders

International Nuclear Information System (INIS)

Kubis, M.; Rave, W.; Cao, L.; Gebel, B.; Mueller, K.-H.; Schultz, L.

1998-01-01

The application of the hydrogenation-disproportionation-desorption-recombination (HDDR) process in Sm 2 Fe 16 M (M=Al,Ga and Si) was investigated. The hydrogen absorption behaviour was studied by temperature-pressure analysis (TPA). In the temperature range between 500 and 800 C, Sm 2 Fe 16 M samples with M=Ga and Si show a weaker hydrogen absorption than Sm 2 Fe 16 Al. This was confirmed by X-ray diffraction which showed a complete disproportionation of Sm 2 Fe 16 Al into SmH z (1.9 2 Fe 16 Ga and Sm 2 Fe 16 Si exhibit a fraction of undecomposed material with the Th 2 Zn 17 -type structure after the disproportionation procedure. These results point to a stabilization of Sm 2 Fe 16 M against disproportionation by hydrogen for M=Ga and Si. The magnetization processes of carburized HDDR powders were studied by VSM measurements and Kerr microscopy. The demagnetization curve of our HDDR processed Sm 2 Fe 16 AlC y is well shaped, whereas those of Sm 2 Fe 16 GaC y and Sm 2 Fe 16 SiC y show a large decrease of the polarization at low fields. The favourable behaviour of Sm 2 Fe 16 AlC y is due to a homogeneous submicron grain structure. In Sm 2 Fe 16 GaC y and Sm 2 Fe 16 SiC y samples, an additional, magnetically soft phase with larger domains was observed which causes the low coercivity. As a consequence, HDDR was only favourable for the preparation of Sm 2 Fe 16 MC y hard magnets with M=Al but not for M=Ga and Si. Optimization of the HDDR process in Sm 2 Fe 16 Al and subsequent nitrogenation or carburization led to coercivities of μ 0j H c =2.9 and 2.5 T, respectively. (orig.)

I-1 General; I-1 Opsti deo

Energy Technology Data Exchange (ETDEWEB)

NONE

1960-07-01

General part of the regulations and instructions for operation of the RA reactor includes fundamental data about the reactor properties, biological shields, purpose of reactor operation, organizational scheme, rights and responsibilities of the head of laboratory, leaders of the working teams and all the staff of the laboratory for RA reactor exploitation. Opsti deo knjige propisa i uputstva za rad reaktora sadrzi osnovne podatke o reaktoru, biloskoj zastiti, nameni reaktora, prava i duznosti nacelnika, sefova smena i osoblja laboratorije za eksploataciju reaktora RA.

Regulations and instructions; Propisi i uputstva

Energy Technology Data Exchange (ETDEWEB)

NONE

1960-07-01

Regulations and instructions for operating the RA reactor consist of the following chapters: general regulations with the fundamental RA reactor characteristics, operating regulations and instructions for the personnel on duty, regulations for accidental conditions, training program for the staff of the Laboratory for reactor operation. Propisi i uputstva za rad reaktora RA sadrze sledeca poglavlja: opsti deo sa kratkim opisom karakteristika reaktora RA, propisi za rad dezurnog osoblja, propisi za slucaj udesa, program obuke osoblja Laboratorije za eksploataciju reaktora RA.

Layered SmBaCuCoO5+δ and SmBaCuFeO5+δ perovskite oxides as cathode materials for proton-conducting SOFCs

International Nuclear Information System (INIS)

Nian Qiong; Zhao Ling; He Beibei; Lin Bin; Peng Ranran; Meng Guangyao; Liu Xingqin

2010-01-01

A dense BaCe 0.8 Sm 0.2 O 5+δ (BCS) electrolyte was fabricated on a porous anode by in situ drop-coating to develop a simple and cost-effective route to fabricate proton-conducting solid oxide fuel cells (SOFCs). Layered perovskite-structure oxides SmBaCuCoO 5+δ (SBCC) and SmBaCuFeO 5+δ (SBCF) were prepared and the electrical conductivity, the thermal expansion coefficient and electrochemical performance were investigated as potential cathode materials for proton-conducting SOFCs. Thermal expansion coefficients of SBCC and SBCF were suitable for BCS electrolyte and the electrical conductivity of the SBCC is higher than that of the SBCF. The maximum power density of 449 mW cm 2 and 333 mW cm 2 at 700 o C were obtained for the SBCC/BCS/NiO-BCS and SBCF/BCS/NiO-BCS cells, respectively. The interfacial polarization resistances for SBCC and SBCF cathode are as low as 0.137 Ω cm -2 and 0.196 Ω cm -2 at 700 o C, respectively. The results indicate that the SBCC and SBCF are promising cathode materials for proton-conducting SOFCs.

SM+Top at the LHC

CERN Document Server

McCarthy, Tom; The ATLAS collaboration

2018-01-01

This overview talk highlights some of the latest results by the ATLAS, CMS & LHCb collaborations. A particular focus is placed on some of the rarer Standard Model processes which have recently become accessible with the large set of proton-proton collision data collected during the successful second run of the LHC at $\\sqrt{s}$ = 13 TeV. Searches and cross-section measurements involving top quark signatures are given prominence, as well as those targeting highly boosted objects such as SM W/Z and Higgs bosons, and which consequently feature large-R jets and substructure techniques.

Energy transfer mechanism from Gd3+ to Sm3+ in K3Gd(PO4)2:Sm3+ phosphor

International Nuclear Information System (INIS)

Gupta, Palvi; Bedyal, A K; Kumar, Vinay; Khajuria, Y; Sharma, Vishal; Ntwaeaborwa, O M; Swart, H C

2015-01-01

Undoped K 3 Gd(PO 4 ) 2 and trivalent samarium (0.5–2.5 mol%) doped K 3 Gd(PO 4 ) 2 phosphors were synthesized by the solid-state method. The phase formation, optical and luminescence properties were investigated by x-ray diffraction (XRD), diffuse reflectance (DR) spectroscopy, and photoluminescence (PL) spectroscopy. The fluorescence decay spectra of the obtained phosphors were also recorded to study the energy transfer from sensitizer (Gd 3+ ) to activator (Sm 3+ ). Energy transfer effects from sensitizer to activator caused by rare-earth ions were mainly observed in the obtained PL and lifetime spectra. The decay curves of K 3 Gd(PO 4 ) 2 phosphor with different Sm 3+ ions concentrations were found to be non-exponential and the data is well fitted with the Inokuti–Hirayama (I–H) model. The energy transfer parameters such as critical distance for the transfer processes were determined. The Commission Internationale de l’Eclairage (CIE) chromatic coordinates and color-correlated temperature were also determined for the prepared phosphor. (paper)

Efficacy of synovectomy in haemophilic patients with 153Sm-Hydroxyapatite

International Nuclear Information System (INIS)

Calegaro, J.U.M; Paula, J.C; Machado, J; Cruz, J.S

2006-01-01

Introduction - We preconized the use of 153 Sm-Hydroxyapatite (HYP) in the synoviorthesis of haemophilic patients (pts) by physical, chemical and biological characteristics. The real efficacy is being confirmed by the actual experience over the previous results. These are the first results with 153 Sm-HYP in our literature review. Material and Methods - Fifteen pts. were treated, all males, with ages between 15 and 31 years (average = 22,8 years old), with an intraarticular injection of 185 MBq (5mCi) of 153 Sm-HYP, totalizing 29 joints: 12 knees, 11 elbows, 4 ankles and 2 shoulders. The 153 Sm, produced by IPEN/CNEN - Sao Paulo, targeted hydroxyapatite particles with a diameter between 1-10μm, radiochemical purity superior to 95% and stability of 96,6% 1440min after the labeling process. The intraarticular punction was made after local antiseptic, aspirating synovial fluid, injecting 0,5 ml of radioactive solution and flushing the tract with a saline with a total volume no greater than 1,5 ml. The images were obtained 2 and 24h after injection in all pts in a large field of view gamma-camera. The clinical evaluation was made before and one year after it, using objective (range of motion, joint tenderness, degree of joint effusion) and subjective criteria (joint pain by visual scale and joint aspect). The response were graded: 1 - Excellent (E); 2 - Good (G); 3 - Mild (M); 4 - Bad (B); 5 - Worse (W). The reduction in clotting factor use and heamarthroses were others aspects evaluated. Results - The scintigrafies showed homogeneous distribution of the material in joints (2h) and no articular scape (24h). The was a reduction of 34% in the clotting factor use and of 51,4% in haemarthroses including the poor responses in knees. The results by patients were: 53,3% E, 20% G, 13,3% M, 13,3% B, 0% W and by joints were 47,75 with excellent and good responses and 84,75% when included the mild group. There was no patient without response. Few patients (4) had local pain in

Shape coexistence in 140Sm and the onset of deformation below N=82 from lifetime measurements

Science.gov (United States)

Cardona, M. A.; Lunardi, S.; Bazzacco, D.; de Angelis, G.; Roca, V.

1991-08-01

Different deformations for the two bands built above the (πh11/2)2 10+ and the (νh11/2)-2 10+ states in 140Sm have been determined from lifetime measurements using the reaction 106Pd(37Cl,p2n)140Sm at 143 MeV. The β values derived for the N=78 and N=80 core nuclei, coexisting in 140Sm, complete the systematics of nuclear deformation from N=72 to 80.

Data concerning operation and application of RA reactor in 1975, Annex 1; Prilog 1 - Podaci o radu i iskoriscenosti reaktora RA u 1975. godini

Energy Technology Data Exchange (ETDEWEB)

Stanic, A [Institute of Nuclear Sciences Boris Kidric, Vinca, Beograd (Serbia and Montenegro)

1976-01-15

RA reactor was operating according to the plan for 1975 adopted in December of the previous year. It was planned for reactor to be operated at nominal power first 10-20 days each month, three following days were reserved for different power levels according to the users' demand. Four fuel exchanges were planned and fulfilled with minor delay. Data concerning planned and real operation, as well as delays from the plan and shorter interruptions are presented in tables of this Annex. It is shown that all the delays and interruptions which amounted to 104 hours were compensated. [Serbo-Croat] Reaktor RA je radio prema planu rada za 1975. godinu, nacinjenom u decembru prethodne godine. Planirano je da reaktor radi neprekidno prvih 10-20 dana u mesecu na nominalnoj snazi, tri sledeca dana je rezervisano za rad na drugim snagama zavisno od potreba korisnuka. Planirane su i 4 izmene goriva. Podaci o planiranom i ostvarenom radu kao i odstupanjima od plana i kracim prekidima u radu reaktora dati su u tabelama ovog priloga. Vidi se da su sva odstupanja i prekidi u ukupnom trajanju od 104 sata u celini nadoknadjeni.

Outcomes of polio eradication activities in Uttar Pradesh, India: the Social Mobilization Network (SM Net and Core Group Polio Project (CGPP

Directory of Open Access Journals (Sweden)

Singh Vibha

2011-05-01

Full Text Available Abstract Background The primary strategy to interrupt transmission of wild poliovirus in India is to improve supplemental immunization activities and routine immunization coverage in priority districts with a focus on 107 high-risk blocks of western Uttar Pradesh and central Bihar. Villages or urban areas with a history of wild poliovirus transmission, or hard-to-reach or resistant populations are categorized as high-risk areas within blocks. The Social Mobilization Network (SM Net was formed in Uttar Pradesh in 2003 to support polio eradication efforts through improved planning, implementation and monitoring of social mobilization activities in those high-risk areas. In this paper, we examine the vaccination outcomes in districts of SM Net where the CORE Group works. Methods We carried out a secondary data analysis of routine monitoring information collected by the SM Net and the Government of India. These data include information about vaccination outcomes in SM Net areas and non-SM Net areas within the districts where the CORE Group operates. Statistical analysis was used to compare, between SM Net and non-SM Net areas, vaccination outcomes considered sensitive to social mobilization efforts of the SM Net. We employed Generalized Estimating Equations (GEE statistical method to account for Intra-cluster Correlation (ICC, and used 'Quasi-likelihood under the independence model criterion (QIC' as the model selection method. Results Vaccination outcomes in SM Net areas were as high as or higher than in non-SM Net areas. There was considerable variation in vaccination outcomes between districts. Conclusions While not conclusive, the results suggest that the social mobilization efforts of the SM Net and the CORE Group are helping to increase vaccination levels in high-risk areas of Uttar Pradesh. Vaccination outcomes in CORE Group areas were equal or higher than in non-CORE, non-SM Net areas. This occurred even though SM Net areas are those with

Electronic structure and magnetic anisotropy of Sm2Fe17Nx

Science.gov (United States)

Akai, Hisazumi; Ogura, Masako

2014-03-01

Electronic structure and magnetic properties of Sm2Fe17Nx are studies on the basis of the first-principles electronic structure calculation in the framework of the density functional theory within the local density and coherent potential approximations. The magnetic anisotropy of the system as a function of nitrogen concentration x is discussed by taking account not only of the crystal field effects but also of the effects of the f-electron transfer from Sm to the neighboring sites. Also discussed is the magnetic transition temperature that is estimated by mapping the system into a Heisenberg model. The results show the crystalline magnetic anisotropy changes its direction from in-plane to uniaxial ones as x increases. It takes the maximum value near x ~ 2 . 8 and then decreases slightly towards x = 3 . The mechanism for these behaviors is discussed in the light of the results of detailed calculations on the bonding properties between Sm and its neighboring N. This work was partly supported by Elements Strategy Initiative Center for Magnetic Materials Project, the Ministry of Education, Culture, Sports, Science and Technology, Japan.

Study of hydrogenation of Sm2Fe17-yGay by means of X-ray diffraction

International Nuclear Information System (INIS)

Teresiak, A.; Uhlemann, M.; Kubis, M.; Gebel, B.; Mattern, N.; Mueller, K.-H.

2000-01-01

The hydrogenation process of Sm 2 Fe 17-y Ga y (y=0-2) was studied. X-ray investigations show a decreasing hydrogen solubility in the intermetallic alloy with increasing Ga-content from 4.0±0.3 atoms per formula unit for Sm 2 Fe 17 to 2.85±0.05 for Sm 2 Fe 15 Ga 2 . The larger Ga atoms reduce the size of the interstitial sites and thereby the maximum hydrogen concentration is decreased. The behaviour of the lattice parameters a and c with increasing Ga content points to a changed hydrogen distribution on the interstitial sites, becoming more statistical. In situ observations by means of high temperature X-ray diffraction show that the hydrogen absorption process is diffusion controlled. The hydrogen absorption starts at an annealing temperature of 120-140 C in all cases. The solubility of hydrogen decreases with increasing temperature. The hydrogen is completely desorbed above 350 C in all cases. The absorption/desorption process is reversible between room temperature and 400 C. Annealing at temperatures above 400 C leads to the decomposition of the Sm 2 Fe 17 phase, indicated by emerging of α-Fe. The formation of SmH x is established at 600 C. The decomposition temperature increases with increasing Ga-content. Up to 750 C, only Sm 2 Fe 17 is completely decomposed. (orig.)

Importance of fines in smart water enhanced oil recovery (SmW-EOR) for chalk outcrops

DEFF Research Database (Denmark)

Chakravarty, Krishna Hara; Fosbøl, Philip Loldrup; Thomsen, Kaj

2015-01-01

In SmW-EOR it is generally believed that precipitation of brines must be avoided since it can have a negative impact on the SmW sweep efficiency. But substitution of Mg2+ by Ca2+ on calcite surfaces (a well-accepted phenomenon) can change the brine combination and enhance the possibility of fine ......W-EOR experiments reported in literature. Both the amount of available soluble SO4 2- (aq) in the solution and the amount of CaSO4 precipitation has been calculated and correlated to the corresponding oil recovery.......In SmW-EOR it is generally believed that precipitation of brines must be avoided since it can have a negative impact on the SmW sweep efficiency. But substitution of Mg2+ by Ca2+ on calcite surfaces (a well-accepted phenomenon) can change the brine combination and enhance the possibility of fine...

Ra reactor operation plan for 1976 - Annex 6; Prilog 6 - Plan rada reaktora RA za 1976. godinu

Energy Technology Data Exchange (ETDEWEB)

Martinc, R [Institute of Nuclear Sciences Boris Kidric, Vinca, Beograd (Serbia and Montenegro)

1976-01-15

Contrary to previous years the RA reactor operation plan for 1976 is conditioned by more uncertainties than ever for the following reasons. It is planned for February to repair the components in order to eliminate the consequences of leaking from the vertical experimental channel VK-4 which happened in december 1975. Apart from this, measurements related to transfer of the core to highly enriched fuel under minimum power are foreseen to be performed in February. In April, it would be indispensable to locate the point of He gas leaking and its prevention. Core transfer to highly enriched fuel is planned for April for testing of the fuel elements under operating conditions and step by step increase of the power density up to the nominal power. Complete plan for core transfer would be available by the end of February 1976. It is planned to make-up for the mentioned delays from May-December 1976. [Serbo-Croat] Za razliku od prethodnih godina izrada plana rada reaktora RA za 1976. godinu vezana je za mnogo vise neizvesnosti nego ikada ranije iz sledecih razloga. U februaru se vrsi remont opreme i uklanjanja posledica procurivanja vertikalnog eksperimentalog kanala VK-4, koje se dogodilo decembra 1975. Sem toga u februaru se vrse merenja na minimalnim snagama u sklopu priprema za prelazak na novo gorivo. U aprilu ce biti neophodno lociranje mesta gde istice He gas kao i otklanjanje uzroka ovog curenja. Planirano je da se u aprilu ubaci novo gorivo u jezgro u cilju testiranja pod radnim uslovima uz postepeno povecanje snage do nominalne. Planirano je da se smanjeni obim rada usled navedenih uslova nadoknadi u potpunosti u periodu maj-decembar 1976.

The Preparation and Optical Properties of Novel LiLa(MoO4)2:Sm3+,Eu3+ Red Phosphor

Science.gov (United States)

Luo, Li; Huang, Baoyu; He, Jingqi; Zhang, Wei; Zhao, Weiren; Wang, Jianqing

2018-01-01

Novel LiLa1−x−y(MoO4)2:xSm3+,yEu3+ (in short: LL1−x−yM:xSm3+,yEu3+) double molybdate red phosphors were synthesized by a solid-state reaction at as low temperature as 610 °C. The optimal doping concentration of Sm3+ in LiLa1−x(MoO4)2:xSm3+ (LL1−xM:xSm3+) phosphor is x = 0.05 and higher concentrations lead to emission quenching by the electric dipole—electric dipole mechanism. In the samples co-doped with Eu3+ ions, the absorption spectrum in the near ultraviolet and blue regions became broader and stronger than these of the Sm3+ single-doped samples. The efficient energy transfer from Sm3+ to Eu3+ was found and the energy transfer efficiency was calculated. Under the excitation at 403 nm, the chromaticity coordinates of LL0.95−yM:0.05Sm3+,yEu3+ approach to the NTSC standard values (0.670, 0.330) continuously with increasing Eu3+ doping concentration. The phosphor exhibits high luminous efficiency under near UV or blue light excitation and remarkable thermal stability. At 150 °C, the integrated emission intensity of the Eu3+ remained 85% of the initial intensity at room temperature and the activation energy is calculated to be 0.254 eV. The addition of the LL0.83M:0.05Sm3+,0.12Eu3+ red phosphors can improve the color purity and reduce the correlated color temperature of WLED lamps. Hence, LL1−x−yM:xSm3+,yEu3+ is a promising WLED red phosphor. PMID:29443910

Production of medical radioisotope 153Sm in the Tehran Research Reactor (TRR) through theoretical calculations and practical tests

International Nuclear Information System (INIS)

Forughi, Sh.; Hamidi, S.; Khalafi, H.; Sheibani, Sh.; Shahidi, A.

2013-01-01

Highlights: ► Production of 153 Sm isotope by neutron activation in a nuclear reactor was studied. ► Optimal parameters for weight and irradiation time were found. ► This study led to an empirical correction factor (kf). ► Kf enhanced the production procedure of the 153 Sm radioisotope. ► The results led to nearly 60% decrease in the amount of material used in the production process. - Abstract: The feasibility of producing 2000–3000 mCi 153 Sm by irradiation of 152 Sm in 5 MW TRR was studied via TRR core simulation. In this study the cross-section of 152 Sm (n,γ) 153 Sm reaction from ENDF/B library was used. The effective activation cross section for production of 153 Sm is obtained using the neutron spectra in different irradiation channel of the core. The activity of the simulated samples is calculated using the obtained fluxes and cross sections. Then samples were prepared and irradiated under different conditions and fluxes. The final production’s specific activity was measured by the standard dose calibrator ISOMED 1010. By comparison of the theoretical calculations and actual measurements, an empirical correction factor (K f ) was obtained, which is helpful in production procedure of the 153 Sm radioisotope. The optimal weight of the samples and irradiation time was studied according to the flux calculations based on the location of the sample and saturated activity calculation. In order to test the proposed conditions, samples were prepared and were irradiated under the proposed conditions. According to the compared results with the initial irradiation condition, the new proposed sample which weighed 4 mg of Sm 2 O 3 is acceptable for the labeling, therefore this study led to nearly 60% decrease in the amount of material used in the production process

Discovery of SM Higgs Boson in ATLAS Experiment

Indian Academy of Sciences (India)

IAS Admin

ics, Higgs boson, particle detec- tors, trigger, grid computing. Discovery of SM Higgs Boson in ATLAS Experiment. Prafulla Kumar Behera. Prafulla Kumar Behera is an experimental high energy physicist at the. IITM, Chennai. He has participated in many large-scale collider experiments namely. BELLE at Japan, BABAR.

Benign prostatic hypertrophy with high levels of gamma-seminoprotein (gamma-Sm), prostate specific antigen: report of two cases

OpenAIRE

浅川, 正純; 安本, 亮二; 上水流, 雅人; 前川, 正信

1988-01-01

gamma-Seminoprotein (gamma-Sm) is recently being noted as a tumor marker of prostatic cancer. However, since gamma-Sm is a specific antigen against the prostatic tissue, high levels are also observed in patients with benign prostatic hypertrophy (BPH). In this report, two patients with BPH who had high levels of gamma-Sm were studied.

High-Performance Epoxy-Resin-Bonded Magnets Produced from the Sm2Fe17Nx Powders Coated by Copper and Zinc Metals

Science.gov (United States)

Noguchi, Kenji; Machida, Ken-ichi; Adachi, Gin-ya

2001-04-01

Fine powders of Sm2Fe17Nx coated with copper metal reduced from CuCl2 and/or zinc metal subsequently derived by photo-decomposition of diethylzinc [Zn(C2H5)2] were prepared, and their magnetic properties were characterized in addition to those of epoxy-resin-bonded magnets produced from the coated powders (Cu/Sm2Fe17Nx, Zn/Sm2Fe17Nx and Zn/Cu/Sm2Fe17Nx). The remanence (Br) and maximum energy product [(\\mathit{BH})max] of double metal-coated Zn/Cu/Sm2Fe17Nx powders were maintained at higher levels than those of single Zn metal-coated Sm2Fe17Nx ones (Zn/Sm2Fe17Nx) even after heat treatment at 673 K since the oxidation resistance and thermal stability were effectively improved by formation of the thick and uniform protection layer on the surface of Sm2Fe17Nx particles. Moreover, the epoxy-resin-bonded magnets produced from the Zn/Cu/Sm2Fe17Nx powders possessed good corrosion resistance in air at 393 K which it resulted in the smaller thermal irreversible flux loss than that of uncoated and single Zn metal-coated Sm2Fe17Nx powders in the temperature range of above 393 K.

Influence of annealing and nitrogenation on structure and magnetic properties of mechanically alloyed Sm-Fe powders

Energy Technology Data Exchange (ETDEWEB)

Teresiak, A.; Kubis, M.; Mattern, N.; Wolf, M.; Mueller, K.-H. [Institut fuer Festkoerper- und Werkstofforschung Dresden e.V. (Germany)

1998-07-01

Sm-Fe-N compounds were prepared by mechanical alloying, subsequent annealing and nitrogenation. For crystal structure investigations of the non-equilibrium phases Sm{sub 2}Fe{sub 17+x} and Sm{sub 2}Fe{sub 17+x}N{sub y}, respectively, formed at the various annealing temperatures T{sub A}, XRD with following Rietveld analysis was used. For T{sub A} between 600 C and 750 C a modified hexagonal TbCu{sub 7} structure (space group P6/mmm) was found in which the Fe(2c) site is replaced by the partially (1/3) and randomly occupied Fe(61) site. The approximated composition is SmFe{sub 8.8-9.0}. The nitrogenated alloys crystallize in the same structure for 600 C < T{sub A} < 700 C. In this case the interstitial nitrogen randomly occupies the 3f site partially (1/3). For 800 C {<=} T{sub A} {<=} 900 C a disordered modified Th{sub 2}Zn{sub 17} structure (space group R anti 3m) was found that is formed by introducing additional Fe (6c) and Sm(3a) positions. The degree of order of the Sm- and Fe-atoms in c-direction increases with increasing annealing temperature. The completely ordered stoichiometric Sm{sub 2}Fe{sub 17} structure could not be reached by annealing the ball milled elemental powders. The nitrided alloys already form this intermediate structure at T{sub A} = 750 C. The interstitial nitrogen occupies the 9e site. The estimated nitrogen content is higher in the hexagonal phases than in the rhombohedral phase. Optimum magnetic properties, in particular a coercitivity {mu}{sub 01}H{sub C} = 3.7 T and a good squareness of the demagnetization curve, were obtained for T{sub A} = 750 C. Here we found a nitrogen content of y = 3 for Sm{sub 2}Fe{sub 17+x}N{sub y}. (orig.)

SmD1 Modulates the miRNA Pathway Independently of Its Pre-mRNA Splicing Function.

Directory of Open Access Journals (Sweden)

Xiao-Peng Xiong

2015-08-01

Full Text Available microRNAs (miRNAs are a class of endogenous regulatory RNAs that play a key role in myriad biological processes. Upon transcription, primary miRNA transcripts are sequentially processed by Drosha and Dicer ribonucleases into ~22-24 nt miRNAs. Subsequently, miRNAs are incorporated into the RNA-induced silencing complexes (RISCs that contain Argonaute (AGO family proteins and guide RISC to target RNAs via complementary base pairing, leading to post-transcriptional gene silencing by a combination of translation inhibition and mRNA destabilization. Select pre-mRNA splicing factors have been implicated in small RNA-mediated gene silencing pathways in fission yeast, worms, flies and mammals, but the underlying molecular mechanisms are not well understood. Here, we show that SmD1, a core component of the Drosophila small nuclear ribonucleoprotein particle (snRNP implicated in splicing, is required for miRNA biogenesis and function. SmD1 interacts with both the microprocessor component Pasha and pri-miRNAs, and is indispensable for optimal miRNA biogenesis. Depletion of SmD1 impairs the assembly and function of the miRISC without significantly affecting the expression of major canonical miRNA pathway components. Moreover, SmD1 physically and functionally associates with components of the miRISC, including AGO1 and GW182. Notably, miRNA defects resulting from SmD1 silencing can be uncoupled from defects in pre-mRNA splicing, and the miRNA and splicing machineries are physically and functionally distinct entities. Finally, photoactivatable-ribonucleoside-enhanced crosslinking and immunoprecipitation (PAR-CLIP analysis identifies numerous SmD1-binding events across the transcriptome and reveals direct SmD1-miRNA interactions. Our study suggests that SmD1 plays a direct role in miRNA-mediated gene silencing independently of its pre-mRNA splicing activity and indicates that the dual roles of splicing factors in post-transcriptional gene regulation may be

Parallel multispot smFRET analysis using an 8-pixel SPAD array

Science.gov (United States)

Ingargiola, A.; Colyer, R. A.; Kim, D.; Panzeri, F.; Lin, R.; Gulinatti, A.; Rech, I.; Ghioni, M.; Weiss, S.; Michalet, X.

2012-02-01

Single-molecule Förster resonance energy transfer (smFRET) is a powerful tool for extracting distance information between two fluorophores (a donor and acceptor dye) on a nanometer scale. This method is commonly used to monitor binding interactions or intra- and intermolecular conformations in biomolecules freely diffusing through a focal volume or immobilized on a surface. The diffusing geometry has the advantage to not interfere with the molecules and to give access to fast time scales. However, separating photon bursts from individual molecules requires low sample concentrations. This results in long acquisition time (several minutes to an hour) to obtain sufficient statistics. It also prevents studying dynamic phenomena happening on time scales larger than the burst duration and smaller than the acquisition time. Parallelization of acquisition overcomes this limit by increasing the acquisition rate using the same low concentrations required for individual molecule burst identification. In this work we present a new two-color smFRET approach using multispot excitation and detection. The donor excitation pattern is composed of 4 spots arranged in a linear pattern. The fluorescent emission of donor and acceptor dyes is then collected and refocused on two separate areas of a custom 8-pixel SPAD array. We report smFRET measurements performed on various DNA samples synthesized with various distances between the donor and acceptor fluorophores. We demonstrate that our approach provides identical FRET efficiency values to a conventional single-spot acquisition approach, but with a reduced acquisition time. Our work thus opens the way to high-throughput smFRET analysis on freely diffusing molecules.

Ba2ZnWO6:Sm3+ as promising orange-red emitting phosphors: Photoluminescence properties and energy transfer process

Science.gov (United States)

Chen, Peng; Hu, Wenyuan; Yang, Dingming; Zhu, Jiayi; Zhang, Jing; Wu, Yadong

2018-02-01

Novel orange-red emitting phosphors, Ba2Zn1-xWO6:xSm3+ (x = 0.03, 0.04, 0.05, 0.06 and 0.07) (BZW:Sm3+), were prepared using a high-temperature solid-state reaction method. Their crystal structure and photoluminescence properties were characterized and the mechanism of energy transfers between Ba2ZnWO6 and Sm3+ elucidated in detail. It was found that the phosphors had a cubic structure with space group Fm 3 bar m . They can be excited by near-ultraviolet light, and the characteristic emissions of Sm3+ ions are observed at 564 nm, 598 nm and 645 nm, corresponding to 4G5/2 → 6H5/2, 4G5/2 → 6H7/2 and 4G5/2 → 6H9/2 transitions, respectively. The 4G5/2 → 6H9/2 transitions shows the greatest intensity, which indicates that Sm3+ ions occupy the noncentrosymmetric sites. The optimal doping concentration of Sm3+ ions in Ba2ZnWO6 is about 5 mol% and the phenomenon of concentration quenching occurs when the content of Sm3+ ions exceeds 5 mol%. All results show that the Ba2ZnWO6:Sm3+ phosphor holds great promise for use in high-quality white light-emitting diodes.

Exchange-coupled nanoscale SmCo/NdFeB hybrid magnets

Energy Technology Data Exchange (ETDEWEB)

Wang, Dapeng; Poudyal, Narayan; Rong, Chuanbing; Zhang, Ying; Kramer, Matthew J.; Liu, J. Ping

2012-05-11

Nanoscalehybridmagnets containing SmCo5 and Nd2Fe14B hard magnetic phases have been produced via a novel “in-one-pot” processing route. The grain size of the processed bulk composite materials is controlled below 20 nm. The refinement of the nanoscale morphology leads to effective inter-phase exchange coupling that results in single-phase like magnetic properties. Energy product of 14 MGOe was obtained in the isotropic nanocomposite magnets at room temperature. At elevated temperatures, the hybridmagnets have greatly improved thermal stability compared to the Nd2Fe14B single-phase counterpart and have substantially increased magnetization and energy products compared to the single-phase SmCo5 counterpart.

Små stater i den perfekte storm

DEFF Research Database (Denmark)

Carstensen, Martin B.

2016-01-01

Til trods for at Irland og Island siden 2008 har gennemlevet nogle af historiens største finansielle og økonomiske kriser, nyder de to små åbne økonomier nu relativt høje vækstrater og lav arbejdsløshed og anses som succeshistorier. I begge lande har krisehåndteringen haft fokus på at genoprette ...

Voltage color tunable OLED with (Sm,Eu)-β-diketonate complex blend

Science.gov (United States)

Reyes, R.; Cremona, M.; Teotonio, E. E. S.; Brito, H. F.; Malta, O. L.

2004-09-01

Light emission from organic electroluminescent diodes (OLEDs) in which mixed samarium and europium β-diketonate complexes, [Sm 0.7Eu 0.3(TTA) 3(TPPO) 2], was used as the emitting layer is described. The electroluminescence spectra exhibit narrow peaks arising from 4f-intraconfigurational transitions of the Sm 3+ and Eu 3+ ions and a broad emission band attributed to the electrophosphorescence of the TTA ligand. The intensity ratio of the peaks determined by the bias voltage applied to the OLED, together with the ligand electrophosphorescence, allows to obtain a voltage-tunable color light source.

Thermochemical studies on complex of [Sm(o-NBA)_3phen]_2

Institute of Scientific and Technical Information of China (English)

肖圣雄; 张建军; 李旭; 李强国; 任宁; 李环

2010-01-01

A ternary complex [Sm(o-NBA)3phen]2 (o-NBA: o-Nitrobenzoate; phen: 1,10-phenanthroline) was synthesized and characterized by elemental analysis, IR, molar conductance, and thermogravimetric analysis. The dissolution enthalpies of SmCl3·6H2O(s), o-HNBA(s) and phen·H2O(s) in mixed solvent (VHCl :VDMF :VDMSO=2:2:1) were determined by calorimetry at 298.15 K. The enthalpy change of the reaction was determined to be rHmΔθ=252.49±1.60 kJ/mol. Using the relevant data in the literature and a thermochemical recycle ...

Optimal power allocation for SM-OFDM systems with imperfect channel estimation

International Nuclear Information System (INIS)

Yu, Feng; Song, Lijun; Lei, Xia; Xiao, Yue; Jiang, Zhao Xiang; Jin, Maozhu

2016-01-01

This paper analyses the bit error rate (BER) of the spatial modulation orthogonal frequency division multiplex (SM-OFDM) system and derives the optimal power allocation between the data and the pilot symbols by minimizing the upper bound for the BER operating with imperfect channel estimation. Furthermore, we prove the proposed optimal power allocation scheme applies to all generalized linear interpolation techniques with the minimum mean square error (MMSE) channel estimation . Simulation results show that employing the proposed optimal power allocation provides a substantial gain in terms of the average BER performance for the SM-OFDM system compared to its equal-power-allocation counterpart.

Study of the WWR-S IFIN-HH reactor main components stare, after 40 years working, using nondestructive methods

International Nuclear Information System (INIS)

Dragolici, A. C.; Zorliu, A.; Ripeanu, R.; Petran, C.; Mincu, I.

2000-01-01

The main goal of these investigations was to establish the security level after 40 years of working of the WWR-S research reactor of Horia Hulubei National Institute of Research and Development for Physics and Nuclear Engineering, Bucharest-Magurele. The purpose of these investigations was: checking the functionality and the physical integrity of the main components of the reactor. The physical integrity of the components is usually affected by slow processes, such as: corrosion, erosion, aging, deformations and initially hidden flaws with very slow evolutions. The methods used to determine the effects of these processes and to infer conclusions about the physical integrity of the facility are: visualizations by optical means (endoscopy and video camera), examination using ultrasounds and gammagraphy. The objective of the endoscopic checking was the view of the state of interior surfaces of the tubes and pipes, specially the inaccessible areas of the non-dismantling parts of the reactor. Big size components, such as reactor vessel, the biologic protection vessel and the main large diameter pipes of the primary cooling system, were investigated using a special device that contains a video camera connected to a PC. To obtain more information regarding the evolution of the corrosion spots, scratches and harmed areas on the investigated surfaces, their depth was checked by ultrasounds, and the welding seams structure was determined by gammagraphy. A table is given with some significant results obtained from ultrasound measurements in different points of reactor vessel, thermal column, horizontal tubes, etc. After these tests, the conclusions are: the maximum corrosion depth is 0.2 mm; - scratches are superficially, not exceeding 0.2-0.5 mm; - the traces of harmed areas are produced by the electromagnetic device utilization used for manipulation of aluminium capsules which contain irradiated substances. They are superficial, with maximum area of about 1 cm 2 ; the

Targeted radiotherapy of osteosarcoma using 153Sm-EDTMP. A new promising approach

International Nuclear Information System (INIS)

Bruland, Oe.S.; Skretting, A.; Solheim, Oe.P.; Aas, M.

1996-01-01

We report a case where targeted radionuclide therapy using 153 Sm-EDTMP gave substantial palliative effect. A 35-year-old male with a primary osteosarcoma located in the first lumbar vertebra relapsed with progressive back pain after conventional treatment modalities had failed. He became bedridden, and developed paraparesis and impaired bladder function. On a diagnostic bone-scan intense radioactivity was localized in the tumor. He therefore was given 153 Sm-EDTMP treatment twice, 8 weeks apart, 35 and 32 MBq/kg body weight respectively. After a few days the pain was significantly relieved and by the second radionuclide treatment the pareses subsided. For six months he was able to be up and about without any neurological signs or detectable metastases. Eventually, however, he experienced increasing local pain, developed paraparesis, was re-operated but died 4 months later. The dramatic transient improvement observed in this case warrants further exploration using 153 Sm-EDTMP as a boost technique, supplementary to conventiontal external radiotherapy. (orig.)

Exchange-coupled nanoscale SmCo/NdFeB hybrid magnets

Energy Technology Data Exchange (ETDEWEB)

Wang Dapeng; Poudyal, Narayan; Rong, Chuanbing [Department of Physics, University of Texas at Arlington, Arlington, TX 76019 (United States); Zhang Ying [Department of Physics, University of Texas at Arlington, Arlington, TX 76019 (United States); Materials Science and Engineering, Ames Laboratory, USDOE, Iowa State University, Ames, IA 50011 (United States); Kramer, M.J. [Materials Science and Engineering, Ames Laboratory, USDOE, Iowa State University, Ames, IA 50011 (United States); Liu, J. Ping, E-mail: pliu@uta.edu [Department of Physics, University of Texas at Arlington, Arlington, TX 76019 (United States)

2012-09-15

Nanoscale hybrid magnets containing SmCo{sub 5} and Nd{sub 2}Fe{sub 14}B hard magnetic phases have been produced via a novel 'in-one-pot' processing route. The grain size of the processed bulk composite materials is controlled below 20 nm. The refinement of the nanoscale morphology leads to effective inter-phase exchange coupling that results in single-phase like magnetic properties. Energy product of 14 MGOe was obtained in the isotropic nanocomposite magnets at room temperature. At elevated temperatures, the hybrid magnets have greatly improved thermal stability compared to the Nd{sub 2}Fe{sub 14}B single-phase counterpart and have substantially increased magnetization and energy products compared to the single-phase SmCo{sub 5} counterpart. - Highlights: Black-Right-Pointing-Pointer We realize interphase exchange coupling in nanoscale SmCo{sub 5}/Nd{sub 2}Fe{sub 14}B magnets. Black-Right-Pointing-Pointer We observe homogenously distributed two-phase grains with size smaller than 20 nm. Black-Right-Pointing-Pointer We observe a common Curie temperature in the hybrid magnet. Black-Right-Pointing-Pointer High-temperature magnetic properties of the hybrid magnets greatly improved. Black-Right-Pointing-Pointer Plastic deformation of composite materials leads to self-nanoscaling of grains.

Research nuclear reactor RA - Annual Report 1975. Operation and maintenance; Istrazivacki nuklearni reaktor RA - Izvestaj za 1975. godinu - Pogon i odrzavanje

Energy Technology Data Exchange (ETDEWEB)

Martinc, R [Institute of Nuclear Sciences Boris Kidric, Vinca, Beograd (Serbia and Montenegro)

1976-01-15

The plan for 1975 was successfully fulfilled. This is reflected in research related to improvement of operating properties of the RA reactor, mostly due to the effort of the RA staff employed in operation and maintenance of the reactor. Fuel saving achieved by this activity amounted to about 38% (80% enriched fuel). Preliminary work is done, concerned with new reactor core with highly enriched fuel. This is a significant saving as well. New fuel elements have arrived at the end of this year. It is going to enable increase of neutron flux by 50% without changing the nominal operating power. The possibility of further improvement of the reactor are analyzed, to enable material testing and production of radioactive sources. Mid term plan for reactor operation was made according to this analysis. It is planned to further increase the neutron flux in isolated smaller zones, and building new experimental loops with cooling and fast neutron converters. Much was done to increase the safety level of reactor operation and preparing the safety report. [Serbo-Croat] Izvrsenje zadataka u 1975. godini bilo je uspesno. To se ogleda u povecanju istrazivackog rada vezanog za poboljsanje eksploatacionih karakteristika reaktora RA, pretezno koriscenjem sopstvenog kadra angazovanog u pogonu i odrzavanju reaktora. Ovim radom postignuta je usteda goriva od oko 38% (80% obogaceno gorivo). Izvrseni su preliminarni radovi na prevodjenju reaktora RA na novo gorivo, sto je takodje velika usteda. Novo gorivo je stiglo krajem godine i ono ce obezbediti porast neutronskog fluksa od 50%, bez promene nominalne snage reaktora. Izvrsena je analiza mogucnosti daljeg usavrsavanja reaktora za potrebe ispitivanja materijala kao i proizvodnju radioaktivnih izvora. Na osnovu ove analize nacinjen je srednjorocni program rada reaktora RA sa tezistem na daljem povecanju fluksa u izdvojenim manjim zonama i ugradnju 'hladjenih petlji' i brzih konvertora. Mnogo je ucinjeno na povecanju stepena sigurnosti

Review of electroweak fits of the SM and beyond, after the Higgs discovery -- with Gfitter

CERN Document Server

Baak, M

2014-01-01

We present an update of the global Standard Model (SM) fit to electroweak precision data under the assumption that the new particle discovered at the LHC is the SM Higgs boson. In this scenario all parameters entering the calculations of electroweak precision observables are known, allowing to over-constrain the SM at the electroweak scale and to assert its validity. Within the SM the W boson mass and the effective weak mixing angle can now be accurately predicted from the global fit. Their results exceed in precision the direct measurements. A determination of the S , T and U parameters, which parametrize the oblique vacuum corrections, is given. We examine the impact of the STU observables on a model of modified couplings of the Higgs boson to gauge bosons, and compare this with the corresponding analysis of LHC measurements of the signal strength of Higgs channels. Future measurements at the International Linear Collider (ILC) promise to improve significantly the experimental precision of key observables u...

Influence of silver nanoparticles on the spectroscopic properties of Sm3+ doped boro-phosphate glasses

Science.gov (United States)

Suthanthirakumar, P.; Marimuthu, K.

2016-05-01

The Sm3+ doped novel boro-phosphate glasses containing silver nanoparticles (NPs) (SmBPxA) have been prepared following the melt quenching technique and their structural and spectroscopic behavior were studied through HR-TEM, optical absorption and photoluminescence spectral measurements. The TEM analysis validates the existence of Ag NPs with an average diameter of ~8 nm. The Surface plasmon resonance (SPR) band of silver NPs was found at around 600 nm from the absorption spectrum of the Sm3+ ions free glass sample. The optical band gap energy (Eopt) corresponding to the direct and indirect allowed transitions and the Urbach energy (ΔE) values were determined from the absorption spectral measurements. The luminescence intensity is found to get enhance when the Ag NPs were embedded along with the Sm3+ ions in the prepared glasses due to the local electric field effect around the rare earth (RE) ion site produced by the SPR of Ag NPs.

Luminescence properties of phosphate phosphor Ba{sub 3}Y(PO{sub 4}){sub 3}:Sm{sup 3+}

Energy Technology Data Exchange (ETDEWEB)

Yang, Fu [College of Science, Hebei North University, Zhangjiakou 075000 (China); Liu, Yufeng, E-mail: liuyufeng4@126.com [State Key Lab of Power Systems, Department of Thermal Engineering, Tsinghua University, Beijing 100084 (China); Tian, Xiaodong; Dong, Guoyi [College of Physics Science and Technology, Hebei University, Baoding 071002 (China); Yu, Quanmao [Institute of Functional Materials, Jiangxi University of Finance & Economics, Nanchang 330013 (China)

2015-05-15

A series of reddish orange-emitting phosphate phosphors Ba{sub 3}Y{sub 1−x}(PO{sub 4}){sub 3}:xSm{sup 3+}(0.01≤x≤0.20) were synthesized by solid-state reaction. X-ray diffraction and photoluminescence spectra were utilized to characterize the structure and luminescence properties of as-synthesized phosphors. The optimized phosphors Ba{sub 3}Y{sub 0.95}(PO{sub 4}){sub 3}:0.05Sm{sup 3+} present several excitation bands from 300 to 500 nm, and exhibit intense reddish orange-emitting properties. The energy transfer type between Sm{sup 3+} ions was confirmed as d–d interaction by using Van Uitert model. The chromatic properties of the typical sample Ba{sub 3}Y(PO{sub 4}){sub 3}:0.05Sm{sup 3+} phosphor have been found to have chromaticity coordinates of (0.583, 0.405), which are located in reddish orange region under the excitation of 401 nm. These results indicated that Ba{sub 3}Y(PO{sub 4}){sub 3}:Sm{sup 3+} phosphors have potential applications in the field of lighting and display due to their effective excitation in the near-ultraviolet range. - Graphical abstract: The color coordinates for 5 mol% Sm{sup 3+} doped Ba{sub 3}Y(PO{sub 4}){sub 3} phosphor were calculated to be (0.583, 0.405), which are located in reddish orange region under the excitation of 401 nm. The peaks of Ba{sub 3}Y{sub 0.95}(PO{sub 4}){sub 3}:0.05Sm{sup 3+} phosphor with the highest emission intensity at 600 nm are broader than those of Y{sub 2}O{sub 3}:Eu{sup 3+} and Y{sub 2}O{sub 2}S:Eu{sup 3+} phosphors. All these characteristics suggest that Ba{sub 3}Y(PO{sub 4}){sub 3}:Sm{sup 3+} phosphors are suitable for near-UV (370–410 nm) excitation and can be applicable to near UV-based WLEDs. ▪ - Highlights: • Different concentration Sm{sup 3+}-doped Ba{sub 3}Y(PO{sub 4}){sub 3} phosphors were fabricated by solid state method. • The optimized phosphors present the several excitation bands from 300 to 500 nm. • The Ba{sub 3}Y(PO{sub 4}){sub 3}:Sm{sup 3+} shows bright reddish orange

Effects of nanostructuring on luminescence properties of SrS:Ce,Sm phosphor: An experimental and phenomenological study

Science.gov (United States)

Yazdanmehr, Mohsen; Sadeghi, Hossein; Tehrani, Masoud Kavosh; Hashemifar, Seyed Javad; Mahdavi, Mohammad

2018-01-01

In this work, we employ various experimental techniques to illustrate the effects of nanostructuring on improvement of the luminescence properties of the polycrystalline SrS co-activated by cerium and samarium dopants (SrS : Ce , Sm). The nano and microstructure SrS : Ce , Sm powders were synthesized by the co-precipitation and solid state diffusion methods, respectively, followed by the spark plasma sintering (SPS) process to densify powders into pellet shape. It is observed that the photo-luminescence (PL), radio-luminescence (RL), and optically stimulated luminescence (OSL) emission intensity of the nanostructure samples are significantly improved with respect to the microstructure samples. Moreover, by using an accurate photomultiplier tube, we measured the CW-OSL decay curves of the samples to demonstrate much higher and faster sensitivity of the nanostructure SrS : Ce , Sm for in-flight and online OSL radiation dosimetry. The obtained absorption and emission spectra are used for phenomenology of the electronic band structure of the SrS : Ce , Sm micro and nano-phosphors inside the band gap. The proposed phenomenological electronic structures are then used to clarify the role of Ce3+ and Sm3+ localized energy levels in the luminescence properties of the nano and microstructure samples. It is argued that electronic transitions from the 2T2g state of Ce3+ and the 4G5/2 state of Sm3+ have strong contribution to the PL and RL emission spectra, while in the OSL mechanism, the Sm3+ 4G5/2 state is mainly responsible for electrons trapping.

The monoclonal antibody SM5-1 recognizes a fibronectin variant which is widely expressed in melanoma

Directory of Open Access Journals (Sweden)

Guo Yajun

2006-01-01

Full Text Available Abstract Background Previously we have generated the monoclonal antibody SM5-1 by using a subtractive immunization protocol of human melanoma. This antibody exhibits a high sensitivity for primary melanomas of 99% (248/250 tested and for metastatic melanoma of 96% (146/151 tested in paraffin embedded sections. This reactivity is superior to the one obtained by HMB-45, anti-MelanA or anti-Tyrosinase and is comparable to anti-S100. However, as compared to anti-S100, the antibody SM5-1 is highly specific for melanocytic lesions since 40 different neoplasms were found to be negative for SM5-1 by immunohistochemistry. The antigen recognized by SM5-1 is unknown. Methods In order to characterize the antigen recognized by mAb SM5-1, a cDNA library was constructed from the metastatic human melanoma cell line SMMUpos in the Uni-ZAP lambda phage and screened by mAb SM5-1. The cDNA clones identified by this approach were then sequenced and subsequently analyzed. Results Sequence analysis of nine independent overlapping clones (length 3100–5600 bp represent fibronectin cDNA including the ED-A, but not the ED-B region which are produced by alternative splicing. The 89aa splicing variant of the IIICS region was found in 8/9 clones and the 120aa splicing variant in 1/9 clones, both of which are included in the CS1 region of fibronectin being involved in melanoma cell adhesion and spreading. Conclusion The molecule recognized by SM5-1 is a melanoma associated FN variant expressed by virtually all primary and metastatic melanomas and may play an important role in melanoma formation and progression. This antibody is therefore not only of value in immunohistochemistry, but potentially also for diagnostic imaging and immunotherapy.

Structural and luminescence properties of Sm3+ -doped bismuth phosphate glass for orange-red photonic applications.

Science.gov (United States)

Damodaraiah, S; Reddy Prasad, V; Ratnakaram, Y C

2018-05-01

In the present study, the effect of bismuth oxide (Bi 2 O 3 ) content on the structural and optical properties of 0.5Sm 3+ -doped phosphate glass and the effect of concentration on structural and optical properties of Sm 3+ -doped bismuth phosphate (BiP) glass were studied. Structural characterization was accomplished using X-ray diffraction (XRD), scanning electron microscopy (SEM) with energy dispersive spectroscopy (EDS), Fourier transform infrared (FTIR) spectroscopy and 31 P nuclear magnetic resonance (NMR) spectroscopy. Optical properties were studied using absorption, photoluminescence and decay measurements. Using optical absorption spectra, Judd-Ofelt parameters were derived to determine the local structure and bonding in the vicinity of Sm 3+ ions. The emission spectra of Sm 3+ -doped BiP glass showed two intense emission bands, 4 G 5/2 → 6 H 7/2 (orange) and 4 G 5/2 → 6 H 9/2 (red) for which the stimulated emission cross-sections (σ e ) and branching ratios (β) were found to be higher. The quantum efficiencies were also calculated from decay measurements recorded for the 4 G 5/2 level of Sm 3+ ions. The suitable combination of Bi 2 O 3 (10 mol%) and Sm 3+ (0.5 mol%) ions in these glasses acted as an efficient lasing material and might be suitable for the development of visible orange-red photonic materials. Copyright © 2018 John Wiley & Sons, Ltd.

Molecular characterization and expression analysis of Lily-type lectin ( SmLTL) in turbot Scophthalmus maximus, and its response to Vibrio anguillarum

Science.gov (United States)

Xia, Dandan; Ma, Aijun; Huang, Zhihui; Shang, Xiaomei; Cui, Wenxiao; Yang, Zhi; Qu, Jiangbo

2018-03-01

A full-length lily-type lectin ( SmLTL) was identified from turbot ( Scophthalmus maximus) in this study. By searching database for protein identification and function prediction, SmLTL were confirmed. The full-length cDNA of SmLTL is composed of 569 bp and contains a 339 bp ORF that encodes 112 amino acid residues. The SmLTL peptide is characterized by a specific β-prism architecture and contains three mannose binding sites in a three-fold internal repeat between amino acids 30-99; two of the repeats share the classical mannose binding domain (QxDxNxVxY) while the third binding site was similar to other fish-specific binding motifs (TxTxGxRxV). The primary, secondary, and tertiary structures of SmLTL were predicted and analyzed, indicating that the SmLTL protein was hydrophilic, contained 5.36% α-helices, 39.29% extended strands, 16.07% β-folds, and 39.29% random coils, and three β-folds. Quantitative realtime polymerase chain reaction (qPCR) analysis revealed that the SmLTL mRNA was abundantly expressed in skin, gill, and intestine. Low levels of SmLTL expression were observed in other tissues. The expression of SmLTL in gill, skin and intestine increased at mRNA level after stimulation of Vibrio anguillarum, our results suggest that SmLTL serve as the first line of defence against microbial infections and play a pivotal role in the innate mucosal immune system. The current study indicates that SmLTL is a member of the lilytype lectin family and the information reported here will provide an important foundation for future research on the role of this protein.

YEZÎDÎSM AND THE HARRÂNÎ TRACES IN YEZÎDÎSM ABSTRACT YEZÎDÎLİK VE YEZÎDÎLİKTE HARRÂNÎ İZLERİ

Directory of Open Access Journals (Sweden)

Sami KILIÇ

2011-09-01

Full Text Available According to many sources of Islam, Yezîdîsm was founded by the people who were follower of sufi Sheikh Adi b. Musafir who lived in the 12 th century and it is defined as an Islamic source syncretic sect or current that regards Yezid b. Muaviye as a superhuman being. Yezîdîsm has been discussed among one of the groups about the name of its source, process of its formation and ideas.Yezîdîsm that extends a syncretic content was affected by Harrânîs which occured with the effect of paganist, plotiest Mesopotamia, Iran religions, Judaism and Christianity. In many sources the religions written above are said to contribute Yezîdîsm but in which situations and how they contributed is not indicated. In some sources only some information is available about them. In this study as it is a detailed subject to determine which religions contributed to the Yezîdîsm, we restricted the subject only whith the Harrânîsm. We tried to interpret similiar things while determining the traces and effects of Yezîdîsm in Harrânîs. So, we aimed to illuminate some beliefs and practises in Yezîdîsm in the back plan of history. Yezîdîlik, İslam kaynaklarının çoğunda, XII. Yüzyılda yaşamış olan mutasavvıf şeyh Adî b. Müsâfir’i takip edenler tarafından kurulmuş ve Yezîd b. Muâviye’nin insanüstü bir varlık olduğu esasına dayanan İslam kaynaklı senkretik bir mezhep veya akım olarak tanımlanmaktadır. Bununla birlikte Yezîdîlik, isminin kaynağı, teşekkül süreci ve görüşlerinin menşei konusunda en çok tartışılan dini-sosyal gruplardan biridir. Senkretik bir yapı arz eden Yezîdîliğe, özellikle paganist ve politeist Mezopotamya dinlerinin etkisiyle oluşan Harrânîler, İran dinleri, Yahudilik, Hıristiyanlık ve İslam’ın tesir ettiği, kaynaklarda ifade edilmektedir. Birçok kaynakta bu dinlerin Yezîdîliğe tesir ettiği bildirilmekte, ancak bu dinlerin hangi noktalarda ve nasıl etki etti

Permanent magnets prepared from Sm10.5Fe88.5Zr1.0Ny without homogenization

International Nuclear Information System (INIS)

Gebel, B.; Kubis, M.; Mueller, K.-H.

1997-01-01

In as-cast Sm 2 Fe 17 the high amount of α-Fe caused by a peritectic reaction can be considerably reduced by a small addition of about 1 at% Zr. X-ray diffraction showed that as-cast Sm 10.5 Fe 88.5 Zr 1.0 mainly consists of a phase with the Th 2 Zn 17 -type structure and SmFe 3 . Non-homogenized Sm 10.5 Fe 88.5 Zr 1.0 was milled and (i) annealed in vacuum or (ii) treated with a hydrogenation-disproportionation-desorp tion-recombination (HDDR) process. The annealed and subsequently nitrogenated powder is magnetically anisotropic and has a coercivity μ 0J H C up to 2.0 T and an energy product (BH) max up to 136 kJ/m 3 . HDDR-treated and nitrogenated powder is isotropic and exhibits values of μ 0J H C = 3.1 T and (BH) max 103 kJ/m 3 . Consequently, Sm 10.5 Fe 88.5 Zr 1.0 N y (y ∼ 16) permanent magnets with very good properties can be prepared without the time-consuming homogenization procedure. (orig.)

Rb-Sr and Sm-Nd chronology and genealogy of mare basalts from the Sea of Tranquility

Science.gov (United States)

Papanastassiou, D. A.; Depaolo, D. J.; Wasserburg, G. J.

1977-01-01

Rb-Sr and Sm-Nd ages of two Apollo 11 mare basalts, high-K basalt 10072 and low-K basalt 10062, are reported. Rb-Sr, Sm-Nd, and Ar-40-Ar-39 ages are in good agreement and indicate an extensive time interval for filling of the Sea of Tranquility, presumably by thin lava flows, in agreement with similar observations for the Ocean of Storms. Initial Sr and Nd isotopic compositions on Apollo 11 basalts reveal at least two parent sources producing basalts. The Sm-Nd isotopic data demonstrate that low-K and high-Ti basalts from Apollo 11 and 17 derived from distinct reservoirs, while low-Ti Apollo 15 mare basalt sources have Sm/Nd similar to the sources of Apollo 11 basalts. Groupings of mare basalt based on Ti content and on isotopic data do not coincide.

Preparation and characterization of SiO2:Sm3+ nanotube arrays with 1.06 μm laser antireflective property

International Nuclear Information System (INIS)

Tan, Wei-min; Huang, Ning; Wang, Li-jun; Song, Tian-shun; Lu, Chun-hua; Wang, Liu-fang; Zhang, Jun-zhi

2013-01-01

SiO 2 : Sm 3+ nanotube arrays with excellent antireflective property at 1.06 μm were synthesized by a template-assisted sol–gel process. The molecular structure, morphology and optical properties of the fabricated SiO 2 :Sm 3+ nanotube arrays were investigated by a Fourier transform infrared spectroscope (FTIR), a Scanning electron microscope (SEM), and a spectro-fluorometer, respectively. The experimental results demonstrate that the SiO 2 :Sm 3+ nanotube arrays were formed via the AAO membrane during the sol–gel process. The remarkable antireflective characteristic of about 0.166% at 1.06 μm was attributed to the drastic decrease of effective refraction index which enhances the matching effect between air and substrate. As well as the absorption performance of Sm3+ at 1.06 μm which consumes the energies of incident light. - Graphical abstract: Directional aligned SiO 2 :Sm 3+ nanotube arrays were synthesized in AAO template by sol–gel process, and the antiflective performance of arrays is prominent comparing to the blank AAO template. Highlights: ► SiO 2 :Sm 3+ nanotube arrays are synthesized by a template-assisted sol–gel process. ► SiO 2 :Sm 3+ nanotube arrays have remarkable antireflective properties at 1.06 μm. ► The subwavelength structure results in a decrease of effective refraction index. ► The absorption performance of Sm 3+ at 1.06 μm consume the energies of incident light

Evaluation of energy deposition by 153Sm in small samples

International Nuclear Information System (INIS)

Cury, M.I.C.; Siqueira, P.T.D.; Yoriyaz, H.; Coelho, P.R.P.; Da Silva, M.A.; Okazaki, K.

2002-01-01

Aim: This work presents evaluations of the absorbed dose by 'in vitro' blood cultures when mixed with 153 Sm solutions of different concentrations. Although 153 Sm is used as radiopharmaceutical mainly due to its beta emission, which is short-range radiation, it also emits gamma radiation which has a longer-range penetration. Therefore it turns to be a difficult task to determine the absorbed dose by small samples where the infinite approximation is no longer valid. Materials and Methods: MCNP-4C (Monte Carlo N - Particle transport code) has been used to perform the evaluations. It is not a deterministic code that calculates the value of a specific quantity solving the physical equations involved in the problem, but a virtual experiment where the events related to the problems are simulated and the concerned quantities are tallied. MCNP also stands out by its possibilities to specify geometrically any problem. However, these features, among others, turns MCNP in a time consuming code. The simulated problem consists of a cylindrical plastic tube with 1.5 cm internal diameter and 0.1cm thickness. It also has 2.0 cm height conic bottom end, so that the represented sample has 4.0 ml ( consisted by 1 ml of blood and 3 ml culture medium). To evaluate the energy deposition in the blood culture in each 153 Sm decay, the problem has been divided in 3 steps to account to the β- emissions (which has a continuum spectrum), gammas and conversion and Auger electrons emissions. Afterwards each emission contribution was weighted and summed to present the final value. Besides this radiation 'fragmentation', simulations were performed for many different amounts of 153 Sm solution added to the sample. These amounts cover a range from 1μl to 0.5 ml. Results: The average energy per disintegration of 153 Sm is 331 keV [1]. Gammas account for 63 keV and β-, conversion and Auger electrons account for 268 keV. The simulations performed showed an average energy deposition of 260 ke

Influence of Sm{sup 3+} substitution on the mutiferroic effect in NdCrTiO{sub 5}

Energy Technology Data Exchange (ETDEWEB)

Qian, X.L., E-mail: xiaolongqian@shu.edu.cn [Materials Genome Institute, Shanghai University, Shanghai 200444 (China); Department of Physics, Shanghai University, Shanghai 200444 (China); Fang, Y.F.; Kang, J.; Cao, S.X. [Materials Genome Institute, Shanghai University, Shanghai 200444 (China); Department of Physics, Shanghai University, Shanghai 200444 (China); Zhang, J.C., E-mail: jczhang@shu.edu.cn [Materials Genome Institute, Shanghai University, Shanghai 200444 (China); Department of Physics, Shanghai University, Shanghai 200444 (China)

2016-08-15

The effects of Sm{sup 3+} substitution on the magnetic and electric properties of NdCrTiO{sub 5} are investigated by magnetization and polarization measurements. X-ray diffraction patterns confirm that our samples are single phase with an orthorhombic crystal structure in the space group of Pbam. The DC magnetization study at an external field of 0.1 T reveals the variation of the anti-ferromagnetic transition temperature. The disappearance of the ferroelectricity–paraelectricity phase transition in Nd{sub 0.5}Sm{sub 0.5}CrTiO{sub 5} indicates the suppression on the linear magnetoelectric coupling by Sm{sup 3+}. The disparate 3d−4f interactions between Sm and Cr potentially affect the mutiferroic effect in this system.

Transition to intermediate valence state and x-ray photoemission in Sm/sub 1-x/Gd/sub x/S

International Nuclear Information System (INIS)

Campagna, M.; Chui, S.T.; Wertheim, G.K.; Tosatti, E.

1976-01-01

We report a systematic x-ray photoemission study of the alloys Sm 1 /sub -//subx/Gd/subx/S for 0 2+ → Sm 3+ photoemission line shape using a model which has some similarities with the Jaccarino-Walker model for magnetic alloys. It assumes the existence of only two different kinds of Sm 2+ ions in Sm 1 /sub -//subx/Gd/subx/S for x approximately-less-than 16%. We discuss possible reasons for the fact that Gd does not show the usual clustering effects known to occur in many substitutional rare-earth alloys. Lattice-constant measurements for various substituents further illustrate the importance of electronic effects in the phase transition

X(5 Symmetry to 152Sm

Directory of Open Access Journals (Sweden)

Eid S. A.

2016-07-01

Full Text Available The excited positive and negative parity states, potential energy surfaces, V ( ; , electromagnetic transition probabilities, B ( E 1, B ( E 2, electric monopole strength X ( E 0 = E 2 and staggering e ect, I = 1, were calculated successfully using the inter- acting boson approximation model IBA -1. The calculated values are compared to the available experimental data and show reasonable agreement. The energy ratios and contour plot of the potential energy surfaces show that 152 Sm is an X (5 candidate.

The isolation and the separation of Sm, Gd, Dy by extraction

International Nuclear Information System (INIS)

Biyantoro, D.; Lahagu, F.; Basuki, K.T.; Handini, T.; Rosyidin

1996-01-01

The isolation of yttrium and separation of Sm, Gd, y with extraction has been investigated. The steps of the process include of this research were the production the concentrate of lanthanide, the dilution, the isolation of yttrium, and the separation of the Sm, Gd, Dy. The first step was the digestion of xenotime sand, the extraction, the dilution, the filtration, the precipitation, the baking production a lanthanide oxide. The step was the separation of yttrium, the stripping, and the calcination production of yttrium oxide. And the third process was the separation of Sm, Gd, Dy by extraction process using method liquid-liquid extraction with extractant of D 2 EHPA and a solvent of dodecane. From the result have been found concentration of yttrium oxide = 88,71 %. The optimum condition of the separation of Gd/Dy have been found : the concentration of HNO 3 = 0,5 M, time of extraction = 15 minutes, and the concentration of extractant = 30 % D 2 EHPA in dodecane. The results of this condition were the distribution coefficient of Gd = 2,226, the distribution coefficient of Dy = 3,762, and the separation factor of Gd/Dy = 0,592. (author)

Growth and characterization of Sm3+ doped cerium oxalate single crystals

Directory of Open Access Journals (Sweden)

Minu Mary C

2016-07-01

Full Text Available Single crystals of Sm3+ doped cerium oxalate decahydrate were synthesized using single diffusion gel technique and the conditions influencing the size, morphology, nucleation density and quality of the crystals were optimized. Highly transparent single crystals of average size 3 mm × 2 mm × 1 mm with well-defined hexagonal morphology were grown during a time period of two weeks. X-ray powder diffraction analysis revealed that the grown crystals crystallize in the monoclinic system with space group P21/c as identical with the pure cerium oxalate. The various functional groups of the oxalate ligand and the water of crystallization were identified by Fourier transform infrared spectroscopy. The photoluminescence spectrum of the Sm3+ doped cerium oxalate indicated that the Sm3+ ions are optically active in the cerium oxalate matrix. The crystal has a strong and efficient orange red emission with a wavelength peak at 595 nm and hence can be effectively used for optical amplification. Microhardness measurements of the crystal revealed that they belong to the soft material category.

Structure and Phase Transformation in the Giant Magnetostriction Laves-Phase SmFe₂

Energy Technology Data Exchange (ETDEWEB)

Liu, Xiaonan; Lin, Kun; Gao, Qilong; Zhu, He; Li, Qiang; Cao, Yili; Liu, Zhanning; You, Li; Chen, Jun; Ren, Yang [Argonne National Laboratory, X-Ray Science Division, Argonne, Illinois 60439, United States; Huang, Rongjin [Key Laboratory; Lapidus, Saul H. [Argonne National Laboratory, X-Ray Science Division, Argonne, Illinois 60439, United States; Xing, Xianran

2017-10-13

As one class of the most important intermetallic compounds, the binary Laves-phase is well-known for their abundant magnetic properties. Samarium-iron alloy system, SmFe₂, is a prototypical Laves compound that shows strong negative magnetostriction but relatively weak magnetocrystalline anisotropy. SmFe₂ has been identified as a cubic Fd$ \\overline{3}\\ $m structure at room temperature, however, the cubic symmetry does not match the spontaneous magnetization along the [111]_cubic direction. Here we studied the crystal structure of SmFe₂ by high-resolution synchrotron X-ray powder diffraction and X-ray total scattering methods. SmFe₂ is found to adopt a centrosymmetric trigonal R$ \\overline{3}\\ $m structure at room temperature, which transforms to an orthorhombic Imma structure at 200 K. This transition is in agreement with the changes of easy magnetization direction from [111]_cubic to [110]_cubic direction, and is further evidenced by the inflexion of thermal expansion behavior, the sharp decline of the magnetic susceptibility in the FC-ZFC curve, and the anomaly in the specific heat capacity measurement. The revised structure and phase transformation of SmFe₂ could be useful to understand the magnetostriction and related physical properties of other RM₂-type pseudo-cubic Laves-phase intermetallic compounds.

Interplay between surface and bulk states in the Topological Kondo Insulator SmB6

Science.gov (United States)

Biswas, Sangram; Hatnean, Monica Ciomaga; Balakrishnan, Geetha; Bid, Aveek

Kondo insulator SmB6 is predicted to have topologically protected conducting surface states(TSS). We have studied electrical transport through surface states(SS) at ultra-low temperatures in single crystals of SmB6 using local-nonlocal transport scheme and found a large nonlocal signal at temperatures lower than bulk Kondo gap scale. Using resistance fluctuation spectroscopy, we probed the local and nonlocal transport channels and showed that at low temperatures, transport in this system takes place only through SS. The measured noise in this temperature range arises due to Universal Conductance Fluctuations whose statistics was found to be consistent with theoretical predictions for that of 2D systems in the Symplectic symmetry class. We studied the temperature dependence of noise and found that, unlike the topological insulators of the dichalcogenide family, the noise in surface and bulk conduction channels in SmB6 are uncorrelated - at sufficiently low temperatures, the bulk has no discernible contribution to electrical transport in SmB6 making it an ideal platform for probing the physics of TSS. Nanomission, Department of Science & Technology (DST) and Indian Institute of Scienc and EPSRC, UK, Grant EP/L014963/1.

Autophagy-Associated Protein SmATG12 Is Required for Fruiting-Body Formation in the Filamentous Ascomycete Sordaria macrospora.

Science.gov (United States)

Werner, Antonia; Herzog, Britta; Frey, Stefan; Pöggeler, Stefanie

2016-01-01

In filamentous fungi, autophagy functions as a catabolic mechanism to overcome starvation and to control diverse developmental processes under normal nutritional conditions. Autophagy involves the formation of double-membrane vesicles, termed autophagosomes that engulf cellular components and bring about their degradation via fusion with vacuoles. Two ubiquitin-like (UBL) conjugation systems are essential for the expansion of the autophagosomal membrane: the UBL protein ATG8 is conjugated to the lipid phosphatidylethanolamine and the UBL protein ATG12 is coupled to ATG5. We recently showed that in the homothallic ascomycete Sordaria macrospora autophagy-related genes encoding components of the conjugation systems are required for fruiting-body development and/or are essential for viability. In the present work, we cloned and characterized the S. macrospora (Sm)atg12 gene. Two-hybrid analysis revealed that SmATG12 can interact with SmATG7 and SmATG3. To examine its role in S. macrospora, we replaced the open reading frame of Smatg12 with a hygromycin resistance cassette and generated a homokaryotic ΔSmatg12 knockout strain, which displayed slower vegetative growth under nutrient starvation conditions and was unable to form fruiting bodies. In the hyphae of S. macrospora EGFP-labeled SmATG12 was detected in the cytoplasm and as punctate structures presumed to be phagophores or phagophore assembly sites. Delivery of EGFP-labelled SmATG8 to the vacuole was entirely dependent on SmATG12.

The monomeric orphan nuclear receptor Schistosoma mansoni Ftz-F1 dimerizes specifically and functionally with the schistosome RXR homologue, SmRXR1

International Nuclear Information System (INIS)

Bertin, Benjamin; Caby, Stephanie; Oger, Frederik; Sasorith, Souphatta; Wurtz, Jean-Marie; Pierce, Raymond J.

2005-01-01

In an attempt to understand development and differentiation processes of the parasitic blood fluke Schistosoma mansoni, several members of the nuclear receptor superfamily were cloned, including SmFtz-F1 (S. mansoni Fushi Tarazu-factor 1). The Ftz-F1 nuclear receptor subfamily only contains orphan receptors that bind to their response element as monomers. Whereas SmFtz-F1 displays these basic functional properties, we have identified an original and specific interaction between SmFtz-F1 and the schistosome RXR homologue, SmRXR1. The mammalian two-hybrid assay showed that the D, E, and F domains of SmFtz-F1 were capable of interacting specifically with the E domain of SmRXR1 but not with that of mouse RXRα. Using three-dimensional LBD homology modelling and structure-guided mutagenesis, we were able to demonstrate the essential role of exposed residues located in the dimerization interfaces of both receptors in the maintenance of the interaction. Cotransfection experiments with constructions encoding full-length nuclear receptors show that SmRXR1 potentiates the transcriptional activity of SmFtz-F1 from various promoters. Nevertheless, the lack of identification of a dimeric response element for this SmFtz-F1/SmRXR1 heterodimer seems to indicate a 'tethering' mechanism. Thus, our results suggest for the first time that a member of the Ftz-F1 family could heterodimerize functionally with a homologue of the universal heterodimerization partner of nuclear receptors. This unique property confirms that SmFtz-F1 may be involved in the development and differentiation of schistosome-specific structures

Site-selective laser spectroscopy of Sm{sup 3+} ions in Y{sub 4}Al{sub 2}O{sub 9}

Energy Technology Data Exchange (ETDEWEB)

Kaczkan, M., E-mail: m.kaczkan@elka.pw.edu.pl [Institute of Microelectronics and Optoelectronics, Koszykowa 75, Warsaw 00-662 (Poland); Boruc, Z. [Institute of Microelectronics and Optoelectronics, Koszykowa 75, Warsaw 00-662 (Poland); Turczyński, S.; Pawlak, D. [Institute of Electronic Materials Technology, Wolczynska 133, Warsaw 01-919 (Poland); Malinowski, M. [Institute of Microelectronics and Optoelectronics, Koszykowa 75, Warsaw 00-662 (Poland)

2016-02-15

Sm{sup 3+} doped Y{sub 4}Al{sub 2}O{sub 9} (YAM) crystals were prepared by the micro-pulling down method. Optical-absorption and laser-selective-excitation techniques along with luminescence decays have been used to reveal that Sm{sup 3+} ions in YAM normally occupy four sites, which were characterized and discussed. The comprehensive sets of Stark energy levels of the four Sm{sup 3+} centers in YAM were established. The intensity ratio of forced electric dipole ({sup 4}G{sub 5/2} → {sup 6}H{sub 9/2}) and magnetic dipole ({sup 4}G{sub 5/2} → {sup 6}H{sub 5/2}) transitions has been used to estimate the degree of asymmetry of Sm{sup 3+} sites. The lifetime of Sm{sup 3+} ions and the cross-relaxation rates were experimentally determined as a function of concentration for two distinct crystallographic Sm{sup 3+} centers. The dependencies of the nearest surroundings on the relaxation of the {sup 4}G{sub 5/2} excited state was discussed.

Functional organization of the Sm core in the crystal structure of human U1 snRNP.

OpenAIRE

Weber, G.; Trowitzsch, S.; Kastner, B.; Lührmann, R.; Wahl, M.

2010-01-01

The U1 small nuclear ribonucleoprotein initiates the assembly of the spliceosome. Here, the structure of the natively purified U1 small nuclear ribonucleoprotein particle reveals the core Sm protein ring and its interactions with the Sm site in the small nuclear RNA.

Highly anisotropic SmCo5 nanoflakes by surfactant-assisted ball milling at low temperature

International Nuclear Information System (INIS)

Liu, Lidong; Zhang, Songlin; Zhang, Jian; Ping Liu, J.; Xia, Weixing; Du, Juan; Yan, Aru; Yi, Jianhong; Li, Wei; Guo, Zhaohui

2015-01-01

Surfactant-assisted ball milling (SABM) has been shown to be a promising method for preparing rare earth-transition metal (RE-TM) nanoflakes and nanoparticles. In this work, we prepared SmCo 5 nanoflakes by SABM at low temperature, and 2-methyl pentane and trioctylamine were specially selected as solvent and surfactant, respectively, due to their low melting points. The effects of milling temperature on the morphology, microstructure and magnetic performance of SmCo 5 nanoflakes were investigated systematically. Comparing with the samples milled at room temperature, the SmCo 5 nanoflakes prepared at low temperature displayed more homogeneous morphology and lower oxygen content. Remarkably, better crystallinity, better grain alignment and larger remanence ratio were shown in the samples milled at low temperature, which resulted from the distinct microstructure caused by low milling temperature. The differences in structural evolution between the SmCo 5 nanoflakes milled at room temperature and low temperature, including the formation of nanocrystalline, grain boundary sliding, grain rotation, et al., were discussed. It was found that lowering the temperature of SABM was a powerful method for the fabrication of RE-TM nanoflakes, which showed better hard magnetic properties and lower oxygen content. This was important for the preparation of high-performance sintered magnets, bonded magnets and nanocomposite magnets. - Highlights: • We prepare SmCo 5 nanoflakes by surfactant-assisted ball milling at low temperature. • Better grain alignment and higher remanence ratio are achieved. • The oxygen content is reduced by lowering the milling temperature. • A distinct microstructural evolution caused by low milling temperature is clarified

Characterization on the coatings of Ni-base alloy with nano- and micron-size Sm2O3 addition prepared by laser deposition

International Nuclear Information System (INIS)

Zhang Shihong; Li Mingxi; Yoon, Jae Hong; Cho, Tong Yul

2008-01-01

The coating materials are the powder mixture of micron-size Ni-base alloy powders with both 1.5 wt.% micron-size and nano-size Sm 2 O 3 powders, which are prepared on Q235 steel plate by 2.0 kW CO 2 laser deposition. The results indicate that with rare earth oxide Sm 2 O 3 addition, the width of planar crystallization is smaller than that of the Ni-base alloy coatings. Micron- and nano-Sm 2 O 3 /Ni-base alloy coatings have similar microstructure showing the primary phase of γ-Ni dendrite and eutectic containing γ-Ni and Cr 23 C 6 phases. However, compared to micron-Sm 2 O 3 /Ni-base alloy, preferred orientation of γ-Ni dendrite of nano-Sm 2 O 3 /Ni-base alloy is weakened. Planar crystal of several-μm thickness is first grown and then dendrite growth is observed at 1.5% micron-Sm 2 O 3 /Ni-base alloy coating whereas equiaxed dendrite is grown at 1.5% nano-Sm 2 O 3 /Ni-base alloy coating. Hardness and wear resistance of the coating improves with decreasing Sm 2 O 3 size from micron to nano. The improvement on tribological property of nano-Sm 2 O 3 /Ni-base alloy over micron-Sm 2 O 3 /Ni-base alloy coatings can be attributed to the better resistance of equiaxed dendrite to adhesion interactions during the wear process. In 6 M HNO 3 solution, the corrosion resistance is greatly improved with nano-Sm 2 O 3 addition since the decrease of corrosion ratio along grain-boundary in nano-Sm 2 O 3 /Ni-base alloy coating contributes to harmonization of corrosion potential

Crystalline α-Sm2S3 nanowires: Structure and optical properties of an unusual intrinsically degenerate semiconductor

International Nuclear Information System (INIS)

Marin, Chris M.; Wang, Lu; Brewer, Joseph R.; Mei, Wai-Ning; Cheung, Chin Li

2013-01-01

Highlights: ► Developed a rapid synthetic method to generate thin films of α-Sm 2 S 3 nanowires. ► Calculated the electronic structure of α-Sm 2 S 3 by density functional theory. ► Predicted that α-Sm 2 S 3 is an intrinsically degenerate p-type semiconductor. ► Found that the gap in the band states of α-Sm 2 S 3 could be engineered to 1.3 eV via sulfur vacancy. -- Abstract: The lanthanide sulfides have long been a promising class of semiconductors because of their infrared-to-visible range band gaps and excellent thermoelectric properties. However, their applications have been limited due to their time consuming conventional synthetic processes and the lack of sufficient understanding of their electronic properties. To address these shortcomings, here we report a rapid, chemical vapor deposition route which results in thin films of crystalline α-phase samarium sesquisulfide (α-Sm 2 S 3 ) nanowires within a few hours, rather than the typical 4–7 days required in previous synthetic processes. In addition, density functional theory was, for the first time, utilized to calculate the electronic band structure of α-Sm 2 S 3 in order to shed insight into the interpretation of their UV–Vis absorption spectrum. We found that the theoretical direct gap in the band states of α-Sm 2 S 3 is 1.7 eV. Computation results suggest that this gap can be tuned to a solar optimal ∼1.3 eV via systematic sulfur vacancy sites engineered into the crystal structure. Most significantly, the degenerate semiconductor-like behavior long observed in lanthanide sulfide samples have been shown to be present even in the ideal α-Sm 2 S 3 structure, suggesting that the observed heavily p-type behavior is an unusual intrinsic property of the material resulting from the Fermi level being located significantly below the optically active 1.7 eV band edge

A Sm-Nd isotopic study of atmospheric dusts and particulates from major river systems

International Nuclear Information System (INIS)

Goldstein, S.L.; Cambridge Univ.; O'Nions, R.K.; Hamilton, P.J.

1984-01-01

143 Nd/ 144 Nd ratios, and Sm and Nd abundances, are reported for particulates from major and minor rivers of the Earth, continental sediments, and aeolian dusts collected over the Atlantic, Pacific, and Indian Oceans. Overall, Sm/Nd ratios and Nd isotopic compositions in contemporary continental erosion products vary within the small ranges of 147 Sm/ 144 Nd=0.115 +- 0.01 and 143 Nd/ 144 Nd=0.51204 +- 0.0002 (epsilonsub(Nd)=-11.4 +- 4). The average period of residence in the continental crust is estimated to be 1.70 +- 0.35 Ga. These results combined with data from the literature have implications for the age, history, and composition of the sedimentary mass and the continental crust: (1) The average 'crustal residence age' of the whole sedimentary mass is about 1.9 Ga. (2) The range of Nd isotope compositions in the continent derived particulate input to the oceans is the same as Atlantic sediments and seawater, but lower than those of the Pacific, demonstrating the importance of Pacific volcanism to Pacific Nd chemistry. (3) The average ratio of Sm/Nd is about 0.19 in the upper continental crust, and has remained so since the early Archean. This precludes the likelihood of major mafic to felsic or felsic to mafic trends in the overall composition of the upper continental crust through Earth history. (4) Sediments appear to be formed primarily by erosion of continental crust having similar Sm/Nd ratios, rather than by mixing of mafic and felsic compositions. (5) The average ratio of 143 Nd/ 144 Nd approx.= 0.5117 (epsilonsub(Nd) approx.= -17) in the upper continental crust, assuming its mean age is about 2 Ga. (6) The uniformity of the Sm-Nd isotopic systematics in river and aeolian particulates primarily reflects efficient recycling of old sediment by sedimentary processes on a short time scale compared to the amount of time the material has resided in the crust. (orig.)

Valence, magnetism and conduction in the intermediate valence compounds: the case SmB6

International Nuclear Information System (INIS)

Derr, J.

2006-09-01

In some rare earth based compounds, the 4f level is situated so close to the Fermi level that the valence of the compound can become intermediate between two integer values. The so called 'intermediate valence' compound of Samarium hexaboride (SmB 6 ) is one typical example of the exciting physics which can result from this quantum equilibrium between two valence configurations. The first configuration (Sm 2+ ) corresponds to an insulating and non magnetic state whereas the second one (Sm 3+ ) would theoretically give a magnetic and metallic ground state. This dissertation deals with the influence of pressure on this equilibrium. Specific heat measurements under pressure evidenced a new long range magnetic ordering for pressures higher than p c ∼ 10 GPa. On another hand, transport measurements measured for the first time in good conditions of hydrostatics found a reliable and reproducible critical pressure for the insulator to metal transition equal to p c . The phase diagram of SmB 6 is now well known and the observation for the first time of a magnetic anomaly in the high pressure resistivity curves certifies that the onset of the magnetic phase really coincide with the closure of the gap. This change at the critical pressure p c is discussed in a general frame taking into account the Kondo lattice temperature as a key parameter for the renormalization of the wavefunction from one integer configuration to the other whereas the valence itself is still intermediate. This general idea seems to be valid also for other systems studied in this dissertation like SmS or TmSe and could even be valid for more general cases (Ytterbium, Cerium). In the same time, resistivity measurements under uniaxial stress were undertaken. The result is a strong anisotropy effect observed on the pressure dependence of the residual resistivity in the compound SmB 6 . The comparison with the transport under hydrostatic conditions enables us to consider a new idea for the nature of the gap

SM4MQ: A Semantic Model for Multidimensional Queries

DEFF Research Database (Denmark)

Varga, Jovan; Dobrokhotova, Ekaterina; Romero, Oscar

2017-01-01

metadata artifacts (e.g., queries) to assist users with the analysis. However, modeling and sharing of most of these artifacts are typically overlooked. Thus, in this paper we focus on the query metadata artifact in the Exploratory OLAP context and propose an RDF-based vocabulary for its representation......, sharing, and reuse on the SW. As OLAP is based on the underlying multidimensional (MD) data model we denote such queries as MD queries and define SM4MQ: A Semantic Model for Multidimensional Queries. Furthermore, we propose a method to automate the exploitation of queries by means of SPARQL. We apply...... the method to a use case of transforming queries from SM4MQ to a vector representation. For the use case, we developed the prototype and performed an evaluation that shows how our approach can significantly ease and support user assistance such as query recommendation....

En rejse i hverdagen - de små skridt

DEFF Research Database (Denmark)

Nielsen, Trine Mønsted

Projektet konkluderer, at der er potentiale for alle små og mellemstore virksomheder (SMV'er) i at arbejde aktivt med bæredygtighed som en del af deres forretningsudvikling. Rapporten indeholder resultater om, hvordan SMV'er arbejder med bæredygtighed, hvilken værdi de får ud af indsatsen og hvil...

Biofilm Formation and Heat Stress Induce Pyomelanin Production in Deep-Sea Pseudoalteromonas sp. SM9913.

Science.gov (United States)

Zeng, Zhenshun; Cai, Xingsheng; Wang, Pengxia; Guo, Yunxue; Liu, Xiaoxiao; Li, Baiyuan; Wang, Xiaoxue

2017-01-01