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Sample records for kagome double-layer grid

  1. Prediction of Double Layer Grids' Maximum Deflection Using Neural Networks

    Directory of Open Access Journals (Sweden)

    Reza K. Moghadas

    2008-01-01

    Full Text Available Efficient neural networks models are trained to predict the maximum deflection of two-way on two-way grids with variable geometrical parameters (span and height as well as cross-sectional areas of the element groups. Backpropagation (BP and Radial Basis Function (RBF neural networks are employed for the mentioned purpose. The inputs of the neural networks are the length of the spans, L, the height, h and cross-sectional areas of the all groups, A and the outputs are maximum deflections of the corresponding double layer grids, respectively. The numerical results indicate that the RBF neural network is better than BP in terms of training time and performance generality.

  2. Dynamic properties of three-dimensional piezoelectric Kagome grids

    Science.gov (United States)

    Wu, Zhi-Jing; Li, Feng-Ming

    2015-07-01

    Piezoelectric Kagome grids can be considered as a kind of functional material because they have vibration isolation performance and can transform mechanical energy to electric energy. In this study, the dynamic properties of three-dimensional (3D) piezoelectric Kagome grids without and with material defects are studied based on the frequency-domain responses. The spectral element method (SEM) is adopted to solve a 3D piezoelectric beam which contains bending components in two planes, tensional components, and torsional components. The dynamic stiffness matrix of a spectral piezoelectric beam is derived. Highly accurate solutions in the frequency-domain are obtained by solving the equation of motion of the whole structure. Compared with the results from the FEM and those in the existing literature, it can be seen that the SEM can be effectively used to study the 3D piezoelectric Kagome grids. The band-gap properties of Kagome grid and defect state properties of Kagome grid with material defects are analyzed. The effect of the piezoelectric parameter on the band-gap property is investigated further.

  3. Approximate Critical Load of Cambered Double-Layered Grids by Shell Analogies

    Directory of Open Access Journals (Sweden)

    M.I. Ali

    2012-08-01

    Full Text Available Studies have shown that design of double-layered grids based on classical theories may lead to unsafe design. For square-on-diagonal grids, the load carrying capacity is almost the same as the buckling load. Therefore the buckling load can be used as the critical load in the design. In this study, the non-linear behavior of the grids is considered using shell analogies to determine the critical load. By applying the theorem of study and energy to a dimple, an empirical formula to predict the buckling load of thin spherical shells was derived. Then using finite element modeling, post-buckling load was identified and used to calculate the value of constant C. It is observed that the buckling load is proportional to t2.5, which gives a critical load close to what is observed in experiments and a more realistic load as compared to the Classical theory prediction. Loaddeflection curves drawn for the grids and their equivalent continuum shells correlate closely showing that the findings are valid.

  4. Dynamical Aspects of Electrostatic Double Layers

    DEFF Research Database (Denmark)

    Raadu, M.A.; Juul Rasmussen, J.

    1988-01-01

    Electrostatic double layers have been proposed as an acceleration mechanism in solar flares and other astrophysical objects. They have been extensively studied in the laboratory and by means of computer simulations. The theory of steady-state double layers implies several existence criteria...

  5. Stationary Double Layers in a Collisionless Magnetoplasma

    DEFF Research Database (Denmark)

    Noriyoshi, Sato; Mieno, Tetsu; Hatakeyama, Rikizo;

    1983-01-01

    Stationary double layers are generated in a magnetoplasma by applying potential differences between two heated plates on which the plasma is produced by surface ionization. By measuring the double-layer formation process, a localized potential drop is found to be formed initially in front of the ...

  6. Shear deformation plate continua of large double layered space structures

    Science.gov (United States)

    Hefzy, Mohamed Samir; Nayfeh, Adnan H.

    1986-01-01

    A simple method is presented to model large rigid-jointed lattice structures as continuous elastic media with couple stresses using energy equivalence. In the analysis, the transition from the discrete system to the continuous media is achieved by expanding the displacements and the rotations of the nodal points in a Taylor series about a suitable chosen origin. The strain energy of the continuous media with couple stresses is then specialized to obtain shear deformation plate continua. Equivalent continua for single layered grids, double layered grids, and three-dimensional lattices are then obtained.

  7. Electric fields and double layers in plasmas

    Science.gov (United States)

    Singh, Nagendra; Thiemann, H.; Schunk, R. W.

    1987-05-01

    Various mechanisms for driving double layers in plasmas are briefly described, including applied potential drops, currents, contact potentials, and plasma expansions. Some dynamical features of the double layers are discussed. These features, as seen in simulations, laboratory experiments, and theory, indicate that double layers and the currents through them undergo slow oscillations which are determined by the ion transit time across an effective length of the system in which double layers form. It is shown that a localized potential dip forms at the low potential end of a double layer, which interrupts the electron current through it according to the Langmuir criterion, whenever the ion flux into the double is disrupted. The generation of electric fields perpendicular to the ambient magnetic field by contact potentials is also discussed. Two different situations were considered; in one, a low-density hot plasma is sandwiched between high-density cold plasmas, while in the other a high-density current sheet permeates a low-density background plasma. Perpendicular electric fields develop near the contact surfaces. In the case of the current sheet, the creation of parallel electric fields and the formation of double layers are also discussed when the current sheet thickness is varied. Finally, the generation of electric fields and double layers in an expanding plasma is discussed.

  8. Double layer dynamics in a collisionless magnetoplasma

    DEFF Research Database (Denmark)

    Iizuka, S.; Michelsen, Poul; Juul Rasmussen, Jens

    1985-01-01

    Investigations of double layer dynamics are performed in a Q-machine plasma by applying a positive step potential to a cold end-plate collector. The double layer created at the grounded plasma source just after the pulse is applied propagates towards the collector with the plasma flow speed. Large...... oscillations occur in the plasma current which is related to a recurring formation and propagation of the double layer. The current is limited during the propagation by a growing negative potential dip formed on the low-potential tail. Similar phenomena appear on the low-potential tail of the stationary double...... layer formed by applying a potential difference between two plasma sources...

  9. Double Layer Dynamics in a Collisionless Magnetoplasma

    DEFF Research Database (Denmark)

    Iizuka, S.; Michelsen, Poul; Juul Rasmussen, Jens

    An experimental investigation of the dynamics of double layers is presented. The experiments are performed in a Q-machine plasma and the double layers are generated by applying a positive step potential to a cold collector plate terminating the plasma column. The double layer is created...... at the grounded plasma source just after the pulse is applied and it propagates towards the collector with a speed around the ion acoustic speed. When the collector is biased positively, large oscillations are obserced in the plasma current. These oscillations are found to be related to a recurring formation...... difference is applied between two plasmas in a Q-machine with two sources. In this case a stationary double layer forms in the plasma column, but the low potential tail is subject to "back and forth" oscillations leading to large amplitude current oscillations....

  10. An Electromagnetic GL Double Layered Cloak

    CERN Document Server

    Xie, Ganquan; Xie, Feng; Xie, Lee

    2009-01-01

    In this paper, we propose a new electromagnetic (EM) GL double layered cloak. The GL double layered cloak is consist of two sphere annular layers, $R_1 \\le r \\le R_2$ and $R_2 \\le r \\le R_3$. Two type cloak materials are proposed and installed in the each layer, respectively. The outer layer cloak of the GL double layered cloak has the invisible function, the inner layer cloak has fully absorption function. The GL double layered metamaterials are weak degenerative and weak dispersive. When the source is located outside of the GL double layered cloak, the excited EM wave field propagation outside of the double layered cloak is as same as in free space and never be disturbed by the cloak; also, the exterior EM wave can not penetrate into the inner layer and concealment. When local sources are located inside of the GL double cloaked concealment with the normal EM materials, the excited EM wave is propagating under Maxwell equation governing, it is complete absorbed by the inner layer cloak of GL double cloak and...

  11. Three step double layers in the laboratory. [plasma physics

    Science.gov (United States)

    Bailey, Andrew, III; Hershkowitz, Noah

    1988-01-01

    A new class of stationary double layer structure, with three or more distinct steps, is demonstrated in the laboratory. A large monotonic potential increase results from a series of smaller double layers. In many respects, these double layer structures resemble those inferred from satellite measurements of auroral double layers. This new class of double layer appears to depend on turbulence for its existence and to be a hybrid structure, intermediate between anomalous resistivity and BGK double layers.

  12. 基于栅格尺度的双层融雪径流模型研究及应用%Research and Application of Double-layer Snowmelt Runoff Model Based on Grid Scale

    Institute of Scientific and Technical Information of China (English)

    孟现勇; 乔鹏; 刘志辉; 陈凯

    2013-01-01

    The Juntanghu River Basin in the north Tianshan Mountain was chosen as the study area.A double-layer distributed snowmelt runoff model based on the principle of energy balance and mass balance was developed through digital elevation model (DEM) of the study area watershed information extraction and the world soil database and the national land-use data sets for watershed soil and land cover types of data.The analysis show that the measured and simulated runoff hydrograph in 2009 and 2010 fit the high QR passing rate of 87% and 90.85%.In addition,the combination of snow water equivalent changes in the value of MODIS data is verified to demonstrate the reliability of the model.The model is very useful and will provide a good example for snowmelt flood warning.%以新疆天山北坡军塘湖河流域作为研究区,基于物理机制构建双层分布式融雪径流模型,利用研究区数字高程模型(DEM)提取流域信息,运用GIS技术与遥感技术获取积雪、植被、土壤等与融雪径流模型有关的地表信息,并结合WRF中尺度数值预报模式作为该模型气象驱动数据,对研究区融雪期进行模拟,结果显示:2009、2010年峰值模拟期间,实测与模拟径流过程线拟合度高,QR合格率分别达87%、90.85%.该模型适用性较好,对融雪洪水预警具有一定的参考价值.

  13. Reversible Heating in Electric Double Layer Capacitors.

    Science.gov (United States)

    Janssen, Mathijs; van Roij, René

    2017-03-03

    A detailed comparison is made between different viewpoints on reversible heating in electric double layer capacitors. We show in the limit of slow charging that a combined Poisson-Nernst-Planck and heat equation, first studied by d'Entremont and Pilon [J. Power Sources 246, 887 (2014)JPSODZ0378-775310.1016/j.jpowsour.2013.08.024], recovers the temperature changes as predicted by the thermodynamic identity of Janssen et al. [Phys. Rev. Lett. 113, 268501 (2014)PRLTAO0031-900710.1103/PhysRevLett.113.268501], and disagrees with the approximative model of Schiffer et al. [J. Power Sources 160, 765 (2006)JPSODZ0378-775310.1016/j.jpowsour.2005.12.070] that predominates the literature. The thermal response to the adiabatic charging of supercapacitors contains information on electric double layer formation that has remained largely unexplored.

  14. Double layered tailorable advanced blanket insulation

    Science.gov (United States)

    Falstrup, D.

    1983-01-01

    An advanced flexible reusable surface insulation material for future space shuttle flights was investigated. A conventional fly shuttle loom with special modifications to weave an integral double layer triangular core fabric from quartz yarn was used. Two types of insulating material were inserted into the cells of the fabric, and a procedure to accomplish this was developed. The program is follow up of a program in which single layer rectangular cell core fabrics are woven and a single type of insulating material was inserted into the cells.

  15. Current-free double layers: A review

    Science.gov (United States)

    Singh, Nagendra

    2011-12-01

    During the last decade, there has been an upsurge in the research on current-free DLs (CFDLs). Research includes theory, laboratory measurements, and various applications of CFDLs ranging from plasma thrusters to acceleration of charged particles in space and astrophysical plasmas. The purpose of this review is to present a unified understanding of the basic plasma processes, which lead to the formation of CFDLs. The review starts with the discussion on early research on electric fields and double layers (DLs) and ion acceleration in planar plasma expansion. The review continues with the formation of DLs and rarefaction shocks (RFS) in expanding plasma with two electron populations with different temperatures. The basic theory mitigating the formation of a CFDL by two-electron temperature population is reviewed; we refer to such CFDLs as double layers structures formation by two-temperature electron populations (TET-CFDLs). Application of TET-CFDLS to ion acceleration in laboratory and space plasmas was discussed including the formation of stationary steady-state DLs. A quite different type of CFDLs forms in a helicon plasma device (HPD), in which plasma abruptly expands from a narrow plasma source tube into a wide diffusion tube with abruptly diverging magnetic fields. The formation mechanism of the CFDL in HPD, referred here as current free double layer structure in helicon plasma device (HPD-CFDL), and its applications are reviewed. The formation of a TET-CFDL is due to the self-consistent separation of the two electron populations parallel to the ambient magnetic field. In contrast, a HPD-CFDL forms due to self-consistent separation of electrons and ion perpendicular to the abruptly diverging magnetic field in conjunction with the conducting wall of the expansion chamber in the HPD. One-dimensional theoretical models of CFDLs based on steady-state solution of Vlasov-Poisson system of equations are briefly discussed. Applications of CFDLs ranging from helicon

  16. The electric double layer in hydriding metals

    Directory of Open Access Journals (Sweden)

    K. Jamroziak

    2008-12-01

    Full Text Available Purpose: The effect of penetration hydrogen into fatigue load metals is widely investigated by many researchers.Hydrogen is the chemical element which plays negative role in fatigue durability of structures. It decides on fatiguebrittle cracking. In the paper authors carry out an analysis of fatigue durability. Making use of naturally coming intoexistence the electric double layer phenomenon authors discussed the model of absorbing hydrogen into fatigue gap.Design/methodology/approach: A proposed model of the mechanism of hydrogen absorption by metal wasbased on particle hydrogen and water vapor from the air.Findings: It assumes that the EDL has crucial role in intercepting of polar dipole particles of hydrogenand water’s vapor, especially in an already formed fatigue micro-gaps and gaps by effects of its electrostaticattraction force. The authors assume that the main source of hydrogen is water’s vapor, and number of hydrogendipoles is negligible.Practical implications: The problems of metals’ fragility/durability were also discussed in other papersin which author mainly tried to develop new methods of materials’ production with the consideration of assumedfatigue durability.Originality/value: Currently, in progress are works on proposing a model for hydrogen absorption by metal.Such approach to optimization in production and development of the new technologies is an essence of modernconstructions that work in all variety of mechanical stress conditions.

  17. Double-layered Aurivillius-type ferroelectrics with magnetic moments

    NARCIS (Netherlands)

    Missyul, A. B.; Zvereva, I. A.; Palstra, T. T. M.; Kurbakov, A. I.

    2010-01-01

    We have synthesized the double-layer Aurivillius phase Bi(2)LnNbTiO(9) where Ln = Nd-Gd, Bi. All compounds adopt the orthorhombic polar space group A2(I)am. The magnetic Ln-ion occupies the cuboctahedral position in the middle of the perovskite double-layer, and thus controls the octahedral tilt of

  18. Kagome spin ice

    Science.gov (United States)

    Mellado, Paula

    Spin ice in magnetic pyrochlore oxides is a peculiar magnetic state. Like ordinary water ice, these materials are in apparent violation with the third law of thermodynamics, which dictates that the entropy of a system in thermal equilibrium vanishes as its temperature approaches absolute zero. In ice, a "zero-point" entropy is retained down to low temperatures thanks to a high number of low-energy positions of hydrogen ions associated with the Bernal-Fowler ice-rules. Spins in pyrochlore oxides Ho2Ti 2O7 and Dy2Ti2O7 exhibit a similar degeneracy of ground states and thus also have a sizable zero-point entropy. A recent discovery of excitations carrying magnetic charges in pyrochlore spin ice adds another interesting dimension to these magnets. This thesis is devoted to a theoretical study of a two-dimensional version of spin ice whose spins reside on kagome, a lattice of corner-sharing triangles. It covers two aspects of this frustrated classical spin system: the dynamics of artificial spin ice in a network of magnetic nanowires and the thermodynamics of crystalline spin ice. Magnetization dynamics in artificial spin ice is mediated by the emission, propagation and absorption of domain walls in magnetic nanowires. The dynamics shows signs of self-organized behavior such as avalanches. The theoretical model compares favorably to recent experiments. The thermodynamics of the microscopic version of spin ice on kagome is examined through analytical calculations and numerical simulations. The results show that, in addition to the high-temperature paramagnetic phase and the low-temperature phase with magnetic order, spin ice on kagome may have an intermediate phase with fluctuating spins and ordered magnetic charges. This work is concluded with a calculation of the entropy of kagome spin ice at zero temperature when one of the sublattices is pinned by an applied magnetic field and the system breaks up into independent spin chains, a case of dimensional reduction.

  19. Layered kagome spin ice

    Science.gov (United States)

    Hamp, James; Dutton, Sian; Mourigal, Martin; Mukherjee, Paromita; Paddison, Joseph; Ong, Harapan; Castelnovo, Claudio

    Spin ice materials provide a rare instance of emergent gauge symmetry and fractionalisation in three dimensions: the effective degrees of freedom of the system are emergent magnetic monopoles, and the extensively many `ice rule' ground states are those devoid of monopole excitations. Two-dimensional (kagome) analogues of spin ice have also been shown to display a similarly rich behaviour. In kagome ice however the ground-state `ice rule' condition implies the presence everywhere of magnetic charges. As temperature is lowered, an Ising transition occurs to a charge-ordered state, which can be mapped to a dimer covering of the dual honeycomb lattice. A second transition, of Kosterlitz-Thouless or three-state Potts type, occurs to a spin-ordered state at yet lower temperatures, due to small residual energy differences between charge-ordered states. Inspired by recent experimental capabilities in growing spin ice samples with selective (layered) substitution of non-magnetic ions, in this work we investigate the fate of the two ordering transitions when individual kagome layers are brought together to form a three-dimensional pyrochlore structure coupled by long range dipolar interactions. We also consider the response to substitutional disorder and applied magnetic fields.

  20. Double layer -- a particle accelerator in the magnetosphere

    Energy Technology Data Exchange (ETDEWEB)

    Fu, Xiangrong [Los Alamos National Laboratory

    2015-07-16

    Slides present the material under the following topics: Introduction (What is a double layer (DL)? Why is it important? Key unsolved problems); Theory -- time-independent solutions of 1D Vlasov--Poisson system; Particle-in-cell simulations (Current-driven DLs); and Electron acceleration by DL (Betatron acceleration). Key problems include the generation mechanism, stability, and electron acceleration. In summary, recent observations by Van Allen Probes show large number of DLs in the outer radiation belt, associated with enhanced flux of relativistic electrons. Simulations show that ion acoustic double layers can be generated by field-aligned currents. Thermal electrons can gain energy via betatron acceleration in a dipole magnetic field.

  1. Electric double layer of anisotropic dielectric colloids under electric fields

    Science.gov (United States)

    Han, M.; Wu, H.; Luijten, E.

    2016-07-01

    Anisotropic colloidal particles constitute an important class of building blocks for self-assembly directed by electrical fields. The aggregation of these building blocks is driven by induced dipole moments, which arise from an interplay between dielectric effects and the electric double layer. For particles that are anisotropic in shape, charge distribution, and dielectric properties, calculation of the electric double layer requires coupling of the ionic dynamics to a Poisson solver. We apply recently proposed methods to solve this problem for experimentally employed colloids in static and time-dependent electric fields. This allows us to predict the effects of field strength and frequency on the colloidal properties.

  2. Theory of current-free double layers in plasmas

    Science.gov (United States)

    Goswami, K. S.; Saharia, K.; Schamel, H.

    2008-06-01

    The existence of current-free double layers in unmagnetized plasma is studied by means of the quasipotential method applied to the Vlasov-Poisson system. Crucial for its existence are trapped particle populations that are characterized by notches (dips) in the velocity distribution functions at resonant velocity becoming flat at large amplitude limit. The potential drop across the double layer, or its amplitude ψ, can be arbitrarily strong covering the whole range 0pressures. It is, hence, the effective electron (ion) temperature increase (decrease) with increasing potential, caused by the trapped particles, which is responsible for the existence of this two-parameter family of solutions.

  3. Modal analysis of kagome-lattice structures

    Science.gov (United States)

    Perez, H.; Blakley, S.; Zheltikov, A. M.

    2015-05-01

    The first few lowest order circularly symmetric electromagnetic eigenmodes of a full kagome lattice are compared to those of a kagome lattice with a hexagonal defect. This analysis offers important insights into the physics behind the waveguiding properties of hollow-core fibers with a kagome-lattice cladding.

  4. Wet Permeability Characteristics of Double-layer Knitted Fabrics

    Institute of Scientific and Technical Information of China (English)

    WANG Qi; XI Bai-jun

    2007-01-01

    In order to solve the problem that sweat flows back into the internal layer from the external layer in doublelayer knits, a fabric structure model is set up and the conditions that keep the sweat from flowing back into the internal layer from the external layer are presented. It can be used to improve the design of the double-layer knitstheoretically.

  5. Modeling Electric Double-Layers Including Chemical Reaction Effects

    DEFF Research Database (Denmark)

    Paz-Garcia, Juan Manuel; Johannesson, Björn; Ottosen, Lisbeth M.

    2014-01-01

    A physicochemical and numerical model for the transient formation of an electric double-layer between an electrolyte and a chemically-active flat surface is presented, based on a finite elements integration of the nonlinear Nernst-Planck-Poisson model including chemical reactions. The model works...

  6. Insights from theory and simulation on the electrical double layer.

    Science.gov (United States)

    Henderson, Douglas; Boda, Dezso

    2009-05-28

    Despite the fact that our conceptual understanding of the electrical double layer has advanced during the past few decades, the interpretation of experimental and applied work is still largely based on the venerable Poisson-Boltzmann theory of Gouy, Chapman and Stern. This is understandable since this theory is simple and analytic. However, it is not very accurate because the atomic/molecular nature of the ions/solvent and their correlations are ignored. Simulation and some theoretical studies by ourselves and others that have advanced our understanding are discussed. These studies show that the GCS theory predicts a narrow double layer with monotonic profiles. This is not correct. The double layer is wider, and there can be substantial layering that would be even more pronounced if explicit solvent molecules are considered. For many years, experimental studies of the double layer have been directed to the use of electrochemistry as an analytical tool. This is acceptable for analytic chemistry studies. However, the understanding of electrochemical reactions that typically occur at the electrode surface, where simulation and theory indicate that the GCS theory can have substantial errors, requires modern approaches. New, fundamental experimental studies that would lead to deeper insights using more novel systems would be desirable. Further, biophysics is an interesting field. Recent studies of the selectivity of ion channels and of the adsorption of ions in a binding sites of a protein have shown that the linearized GCS theory has substantial errors.

  7. Electric Double-Layer Capacitors Applying to Voltage Sag Compensator

    Science.gov (United States)

    Nara, Hidetaka

    Recently the electric double-layer capacitor (EDLC) which is rapidly charged and discharged and offers long life, maintenance-free, has been developed as a new energy storage element. Therefore, we developed the uninterruptible power supply as voltage sag compensator utilizing EDLC. This paper describes an abstract of EDLC and applying to voltage sag compensation.

  8. Double-layered cell transfer technology for bone regeneration.

    Science.gov (United States)

    Akazawa, Keiko; Iwasaki, Kengo; Nagata, Mizuki; Yokoyama, Naoki; Ayame, Hirohito; Yamaki, Kazumasa; Tanaka, Yuichi; Honda, Izumi; Morioka, Chikako; Kimura, Tsuyoshi; Komaki, Motohiro; Kishida, Akio; Izumi, Yuichi; Morita, Ikuo

    2016-09-14

    For cell-based medicine, to mimic in vivo cellular localization, various tissue engineering approaches have been studied to obtain a desirable arrangement of cells on scaffold materials. We have developed a novel method of cell manipulation called "cell transfer technology", enabling the transfer of cultured cells onto scaffold materials, and controlling cell topology. Here we show that using this technique, two different cell types can be transferred onto a scaffold surface as stable double layers or in patterned arrangements. Various combinations of adherent cells were transferred to a scaffold, amniotic membrane, in overlapping bilayers (double-layered cell transfer), and transferred cells showed stability upon deformations of the material including folding and trimming. Transplantation of mesenchymal stem cells from periodontal ligaments (PDLSC) and osteoblasts, using double-layered cell transfer significantly enhanced bone formation, when compared to single cell type transplantation. Our findings suggest that this double-layer cell transfer is useful to produce a cell transplantation material that can bear two cell layers. Moreover, the transplantation of an amniotic membrane with PDLSCs/osteoblasts by cell transfer technology has therapeutic potential for bone defects. We conclude that cell transfer technology provides a novel and unique cell transplantation method for bone regeneration.

  9. The electric double layer has a life of its own

    NARCIS (Netherlands)

    Merlet, Céline; Limmer, David T.; Salanne, Mathieu; Van Roij, René; Madden, Paul A.; Chandler, David; Rotenberg, Benjamin

    2014-01-01

    Using molecular dynamics simulations with recently developed importance sampling methods, we show that the differential capacitance of a model ionic liquid based double-layer capacitor exhibits an anomalous dependence on the applied electrical potential. Such behavior is qualitatively incompatible w

  10. Stable kagome lattices from group IV elements

    Science.gov (United States)

    Leenaerts, O.; Schoeters, B.; Partoens, B.

    2015-03-01

    A thorough investigation of three-dimensional kagome lattices of group IV elements is performed with first-principles calculations. The investigated kagome lattices of silicon and germanium are found to be of similar stability as the recently proposed carbon kagome lattice. Carbon and silicon kagome lattices are both direct-gap semiconductors but they have qualitatively different electronic band structures. While direct optical transitions between the valence and conduction bands are allowed in the carbon case, no such transitions can be observed for silicon. The kagome lattice of germanium exhibits semimetallic behavior but can be transformed into a semiconductor after compression.

  11. Localized structures in Kagome lattices

    Energy Technology Data Exchange (ETDEWEB)

    Saxena, Avadh B [Los Alamos National Laboratory; Bishop, Alan R [Los Alamos National Laboratory; Law, K J H [UNIV OF MASSACHUSETTS; Kevrekidis, P G [UNIV OF MASSACHUSETTS

    2009-01-01

    We investigate the existence and stability of gap vortices and multi-pole gap solitons in a Kagome lattice with a defocusing nonlinearity both in a discrete case and in a continuum one with periodic external modulation. In particular, predictions are made based on expansion around a simple and analytically tractable anti-continuum (zero coupling) limit. These predictions are then confirmed for a continuum model of an optically-induced Kagome lattice in a photorefractive crystal obtained by a continuous transformation of a honeycomb lattice.

  12. Double layers in a modestly collisional electronegative discharge

    CERN Document Server

    Sheridan, T E

    1999-01-01

    The effect of ion-neutral collisions on the structure and ion flux emanating from a steady-state, planar discharge with two negative components is investigated. The positive ion component is modelled as a cold fluid subject to constant-mobility collisions, while the electrons and negative ions obey Boltzmann relations. The model includes the collisionless limit. When the negative ions are sufficiently cold three types of discharge structures are found. For small negative ion concentrations or high collisionality, the discharge is 'stratified', with an electronegative core and an electropositive edge. For the opposite conditions, the discharge is 'uniform' with the negative ion density remaining significant at the edge of the plasma. Between these cases lies the special case of a double-layer-stratified discharge, where quasi-neutrality is violated at the edge of the electronegative core. Double-layer-stratified solutions are robust in that they persist for moderate collisionality. Numerical solutions for fini...

  13. The electric double layer has a life of its own

    CERN Document Server

    Merlet, Céline; Salanne, Mathieu; Van Roij, René; Madden, Paul A; Chandler, David; Rotenberg, Benjamin

    2014-01-01

    Using molecular dynamics simulations with recently developed importance sampling methods, we show that the differential capacitance of a model ionic liquid based double-layer capacitor exhibits an anomalous dependence on the applied electrical potential. Such behavior is qualitatively incompatible with standard mean-field theories of the electrical double layer, but is consistent with observations made in experiment. The anomalous response results from structural changes induced in the interfacial region of the ionic liquid as it develops a charge density to screen the charge induced on the electrode surface. These structural changes are strongly influenced by the out-of-plane layering of the electrolyte and are multifaceted, including an abrupt local ordering of the ions adsorbed in the plane of the electrode surface, reorientation of molecular ions, and the spontaneous exchange of ions between different layers of the electrolyte close to the electrode surface. The local ordering exhibits signatures of a fir...

  14. Superconductivity in Electric Double Layer Capacitor under Pressure

    Science.gov (United States)

    McCann, Duncan; Misek, Martin; Kamenev, Konstantin; Huxley, Andrew

    2015-03-01

    Chemical doping generally provides the most common method for tuning into the superconducting state of a material yet can be difficult to control and also potentially introduces structural disorder complicating the underlying physics. Electric Double Layer devices however provide a means to electrostatically dope materials with high electric fields allowing continuous tuning of a 2D superconducting state thus avoiding such issues. One such device is the Electric Double Layer Capacitor which can detect the onset of superconductivity through AC magnetisation measurements. We make use of a similar device in an attempt to electrostatically dope and tune the superconductivity in the cuprate compound La1.93Sr0.07CuO4 as well as investigating whether application of pressure improves its efficiency.

  15. Electrical power generation by mechanically modulating electrical double layers.

    Science.gov (United States)

    Moon, Jong Kyun; Jeong, Jaeki; Lee, Dongyun; Pak, Hyuk Kyu

    2013-01-01

    Since Michael Faraday and Joseph Henry made their great discovery of electromagnetic induction, there have been continuous developments in electrical power generation. Most people today get electricity from thermal, hydroelectric, or nuclear power generation systems, which use this electromagnetic induction phenomenon. Here we propose a new method for electrical power generation, without using electromagnetic induction, by mechanically modulating the electrical double layers at the interfacial areas of a water bridge between two conducting plates. We find that when the height of the water bridge is mechanically modulated, the electrical double layer capacitors formed on the two interfacial areas are continuously charged and discharged at different phases from each other, thus generating an AC electric current across the plates. We use a resistor-capacitor circuit model to explain the results of this experiment. This observation could be useful for constructing a micro-fluidic power generation system in the near future.

  16. Experimental investigation of current free double layers in helicon plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Sahu, B. B. [Department of Applied Sciences and Humanities, Dronacharya College of Engineering, Gurgaon 123506 (India); Tarey, R. D. [Department of Physics, Indian Institute of Technology, New Delhi 110016 (India); Ganguli, A. [Centre for Energy Studies, Indian Institute of Technology, New Delhi 110016 (India)

    2014-02-15

    The paper presents investigations of current free double layer (CFDL) that forms in helicon plasmas. In contrast to the other work reporting on the same subject, in the present investigations the double layer (DL) forms in a mirror-like magnetic field topology. The RF compensated Langmuir probe measurements show multiple DLs, which are in connection with, the abrupt fall of densities along with potential drop of about 24 V and 18 V. The DLs strengths (e ΔV{sub p})/(k T{sub e}) are about 9.5 and 6, and the corresponding widths are about 6 and 5 D lengths. The potential drop is nearly equal to the thermal anisotropies between the two plasma regions forming the DL, which is present in the plateau region of mirror, unlike the earlier studies on the DL formation in the region of strong gradients in the magnetic field. Also, it presents a qualitative discussion on the mechanism of DL formation.

  17. Double-Layer Systems at Zero Magnetic Field

    OpenAIRE

    ~Hanna, C. ~B.; Haas, Dylan; Diaz-Velez, J.C.

    2000-01-01

    We investigate theoretically the effects of intralayer and interlayer exchange in biased double-layer electron and hole systems, in the absence of a magnetic field. We use a variational Hartree-Fock-like approximation to analyze the effects of layer separation, layer density, tunneling, and applied gate voltages on the layer densities and on interlayer phase coherence. In agreement with earlier work, we find that for very small layer separations and low layer densities, an interlayer-correlat...

  18. Carrier relaxation time divergence in single and double layer cuprates

    Science.gov (United States)

    Schneider, M. L.; Rast, S.; Onellion, M.; Demsar, J.; Taylor, A. J.; Glinka, Y.; Tolk, N. H.; Ren, Y. H.; Lüpke, G.; Klimov, A.; Xu, Y.; Sobolewski, R.; Si, W.; Zeng, X. H.; Soukiassian, A.; Xi, X. X.; Abrecht, M.; Ariosa, D.; Pavuna, D.; Krapf, A.; Manzke, R.; Printz, J. O.; Williamsen, M. S.; Downum, K. E.; Guptasarma, P.; Bozovic, I.

    2003-12-01

    We report the transient optical pump-probe reflectivity measurements on single and double layer cuprate single crystals and thin films of ten different stoichiometries. We find that with sufficiently low fluence the relaxation time (tauR) of all samples exhibits a power law divergence with temperature (T): tauR ∝ T^{-3 ± 0.5}. Further, the divergence has an onset temperature above the superconducting transition temperature for all superconducting samples. Possible causes of this divergence are discussed.

  19. Electrostatic supersolitons and double layers at the acoustic speed

    Energy Technology Data Exchange (ETDEWEB)

    Verheest, Frank, E-mail: frank.verheest@ugent.be [Sterrenkundig Observatorium, Universiteit Gent, Krijgslaan 281, B–9000 Gent (Belgium); School of Chemistry and Physics, University of KwaZulu-Natal, Durban 4000 (South Africa); Hellberg, Manfred A., E-mail: hellberg@ukzn.ac.za [School of Chemistry and Physics, University of KwaZulu-Natal, Durban 4000 (South Africa)

    2015-01-15

    Supersolitons are characterized by subsidiary extrema on the sides of a typical bipolar electric field signature or by association with a root beyond double layers in the fully nonlinear Sagdeev pseudopotential description. It has been proven that supersolitons may exist in several plasmas having at least three constituent species, but they cannot be found in weakly nonlinear theory. Another recent aspect of pseudopotential theory is that in certain plasma models and parameter regimes solitons and/or double layers can exist at the acoustic speed, having no reductive perturbation counterparts. Importantly, they signal coexistence between solitons having positive and negative polarity, in that one solution can be realized at a time, depending on infinitesimal perturbations from the equilibrium state. Weaving the two strands together, we demonstrate here that one can even find supersolitons and double layers at the acoustic speed, as illustrated using the model of cold positive and negative ions, in the presence of nonthermal electrons following a Cairns distribution. This model has been discussed before, but the existence and properties of supersolitons at the acoustic speed were not established at the time of publication.

  20. Single and Double-Layer Antireflection Coatings on Silicon

    Science.gov (United States)

    Kavakli, Ýpek Gýrgýn; Kantarli, Kayhan

    2002-09-01

    In this study, the effect of single and double-layer thin film coatings on the reflectance spectrum of silicon surfaces has been investigated. Thin film coatings have been prepared by vacuum evaporation of the materials with suitable refractive index. Reflectance measurements in the visible and near infrared have shown that the coated samples acquire antireflection properties. Thickness and wavelength dependence of the antireflection properties of SiO, CeO2 and ZnS single-layer coatings with optical thickness of one quarter wavelength has been studied. In double-layer coatings, a thin film of SiO, CeO2 and ZnS with optical thickness of quarter wavelength were used as inner layer while a thin film of MgF2 with equal optical thickness was used as outer layer. It was shown that double-layer coatings can produce a significantly broader low reflectance region than does the single-layer coating. The results have been discussed by considering the zero reflectance conditions for the refractive index and the optical thickness of layers.

  1. Large-amplitude double layers in a dusty plasma with an arbitrary streaming ion beam

    Indian Academy of Sciences (India)

    Brindaban Das; Debkumar Ghosh; Prasanta Chatterjee

    2010-06-01

    Formation of large-amplitude double layers in a dusty plasma whose constituents are electrons, ions, warm dust grains and positive ion beam are studied using Sagdeev’s pseudopotential technique. Existence of double layers is investigated. It is found that both the temperature of dust particles and ion beam temperature play significant roles in determining the region of the existence of double layers.

  2. Small amplitude ion-acoustic double layers with cold electron beam and q-nonextensive electrons

    Energy Technology Data Exchange (ETDEWEB)

    Ali Shan, S., E-mail: shaukatshan@gmail.com [Theoretical Plasma Physics Division, PINSTECH, Nilore, 44000 Islamabad (Pakistan); National Centre for Physics (NCP), Shahdra Valley Road, 44000 Islamabad (Pakistan); Department of Mathematics and Applied Physics (DPAM), PIEAS, Islamabad (Pakistan); Saleem, H., E-mail: saleemhpk@hotmail.com [National Centre for Physics (NCP), Shahdra Valley Road, 44000 Islamabad (Pakistan); Department of Mathematics and Applied Physics (DPAM), PIEAS, Islamabad (Pakistan)

    2014-02-01

    Small amplitude ion-acoustic double layers in an unmagnetized and collisionless plasma consisting of cold positive ions, q-nonextensive electrons, and a cold electron beam are investigated. Small amplitude double layer solution is obtained by expanding the Sagdeev potential truncated method. The effects of entropic index q, speed and density of cold electron beam on double layer structures are discussed.

  3. FMR measurements on CoCr/NiFe double layers

    OpenAIRE

    Stam, M.T.H.C.W.; Gerritsma, G.J.; Lodder, J. C.; Popma, Th.J.A.

    1988-01-01

    CoCr/NiFe double layers were measured by ferromagnetic resonance (FMR) for different angles of the applied field. Several resonance curves were observed for CoCr, which are attributed to the different layers of a magnetically stratified CoCr. This was investigated by carrying out FMR measurements on a single CoCr sample and removing successive layers by ion beam milling. The origin of some of the curves is still unclear. One resonance curve is attributed to the top or bulk layer and another t...

  4. Tunable magnetic resonance in double layered metallic structures.

    Science.gov (United States)

    Zhou, L; Zhu, Y Y

    2011-12-01

    Double layered metallic gratings have been investigated both theoretically and experimentally. The authors have reported that tunable magnetic resonance (MR) can be achieved by modulating the vertical chirped width dh which could be controlled conveniently in the common electron and/or ion beam microfabrications. The linear relationship between MR wavelength and dh has been reported. By introducing the difference of electric and magnetic penetration depth, an analytic formula deduced from a modified LC model has shown good agreement with the simulation results, and an effective width for trapezoidal sandwiched microstructures has been presented. Our results may provide an alternative choice for tunable MR and broad bandwidth of magnetic metamaterials.

  5. Carrier Rexlaxation Time Divergence in Single and Double Layer Cuprates.

    Energy Technology Data Exchange (ETDEWEB)

    Schneider, M.; Rast, S.; Onellion, M.; Demsar, J.; Taylor, A. J.; Glinka, Y.; Tolk, N. H.; Ren, Y. H.; Lupke, G.; Klimov, A.; Sobolewski, R.; Xu, Y.; Si, Weidong; Zeng, X. H.; Soukiassian, A.; Xi, X. X.; Abrecht, M.; Ariosa, D.; Pavuna, D.; Drapf, A.; Manzke, R.; Printz, J. O.; Williamsen, M. S.; Downum, K. E.; Guptasarma, P.

    2003-06-20

    We report the transient optical pump-probe reflectivity measurements on single and double layer cuprate single crystals and thin films of ten different stoichiometries. We find that with sufficiently low fluence the relaxation time (tau [sub R] of all samples exhibits a power law divergence with temperature (T): tau [sub R] [proportional to] T[sup -3 [plus or minus] 0.5]. Further, the divergence has an onset temperature above the superconducting transition temperature for all superconducting samples. Possible causes of this divergence are discussed.

  6. Candidate organic electrolytes for electric double-layer capacitor application

    Institute of Scientific and Technical Information of China (English)

    B.Fang; Y.Wei; K.Suzuki; M.Kumagai

    2004-01-01

    Electrolytic conductivity,viscosity and electrochemical behavior were investigated for organic electrolytes based on PC(Propylene carbonate),MAN(Methoxy acetonitrile) and GBL(γ-Butyrolactone) solvents.It was found that 1 mol/L Et4NBF4-MAN had the highest conductivity,lowest viscosity and acceptable potential window.The specific capacitance and energy density obtained from the capacitor using 1 mol/L Et4NBF4-MAN as electrolyte were the highest among all the tested electrolytes.1 mol/L Et4NBF4-GBL also seemed promising to be used in electric double-layer capacitor (EDLCs).

  7. Spatially anisotropic Heisenberg kagome antiferromagnet

    Science.gov (United States)

    Apel, W.; Yavors'kii, T.; Everts, H.-U.

    2007-04-01

    In the search for spin-1/2 kagome antiferromagnets, the mineral volborthite has recently been the subject of experimental studies (Hiroi et al 2001 J. Phys. Soc. Japan 70 3377; Fukaya et al 2003 Phys. Rev. Lett. 91 207603; Bert et al 2004 J. Phys.: Condens. Matter 16 S829; Bert et al 2005 Phys. Rev. Lett. 95 087203). It has been suggested that the magnetic properties of this material are described by a spin-1/2 Heisenberg model on the kagome lattice with spatially anisotropic exchange couplings. We report on investigations of the {\\mathrm {Sp}}(\\mathcal {N}) symmetric generalization of this model in the large \\mathcal {N} limit. We obtain a detailed description of the dependence of possible ground states on the anisotropy and on the spin length S. A fairly rich phase diagram with a ferrimagnetic phase, incommensurate phases with and without long-range order and a decoupled chain phase emerges.

  8. A spin-1 kagome antiferromagnet

    Science.gov (United States)

    Tovar, Mayra; Shtengel, Kirill; Refael, Gil

    2010-03-01

    We study a spin-1 antiferromagnet on the kagom'e lattice. We start by constructing a Klein-type SU(2) symmetric Hamiltonian which contains Heisenberg interactions between nearest and next-nearest neighbors as well as three-body terms. Our model Hamiltonian has an extensive degenerate ground state whose manifold is spanned by the AKLT-like valence bond states. We also perturb the parent Hamiltonian by introducing an enhancement to the nearest neighbor antiferromagnetic Heisenberg interactions. By projecting this perturbation onto the basis spanned by the unperturbed ground states, we derive an effective Hamiltonian which is dual to that of the transverse field antiferromagnetic Ising model on the triangular lattice. Based on the parameters of our model, we find it to be in the order-by-disorder phase. The ground state is a valence bond crystal stabilized by quantum fluctuations. We also discuss excitations, both magnetic and non-magnetic, and address their possible relevance to experiment.

  9. Resonance scattering characteristics of double-layer spherical particles

    Institute of Scientific and Technical Information of China (English)

    Xuejin Dong; Mingxu Su; Xiaoshu Cai

    2012-01-01

    Based on the principle of ultrasonic resonance scattering,sound-scattering characteristics of double-layer spherical particles in water were numerically studied in this paper.By solving the equations of the scattering matrix,the scattering coefficient determined by the boundary conditions can be obtained,thus the expression for the sound-scattering function of a single double-layer spherical particle can be derived.To describe the resonance scattering characteristics of a single particle,the reduced scattering cross section and reduced extinction cross section curves were found through numerical calculation.Similarly,the numerically calculated sound attenuation coefficient curves were used to depict the resonance scattering characteristics of monodisperse and polydisperse particles.The results of numerical calculation showed that,for monodisperse particles,the strength of the resonance was mainly related to the particle size and the total number of particles; while for polydisperse particles,it was primarily affected by the particle size,the coverage of the particle size distribution and the particle concentration.

  10. Partial double-layered patella in a nondysplasic adolescent.

    Science.gov (United States)

    García-Mata, Serafín; Hidalgo-Ovejero, Angel

    2016-11-01

    Double-layered patella (DLP) is a rare patella-formation abnormality reported in association with multiple epiphyseal dysplasia. DLP is one of the five types of bipartite patella, caused by a coronal septum that divides the patella into anterior and posterior segments. Although the double layer of bone has been reported as complete, it may also manifest as partial, as in our case. A 13-year-old male patient attended A&E after accidentally falling and sustaining a direct injury to his left knee, with pain in the anterior surface of the right patella. He was diagnosed with an incomplete vertical fracture of the left patella. An axial view radiography indicated an external partial DLP. No bone dysplasia was found. Computed tomographic scan and MRI showed partial DLP and bone marrow oedema because of the injury in the femoral condyle, but no fracture. The reason for highlighting this type of patella abnormality is to present the case of a patient without bone dysplasia, either partial or incomplete, that has not been reported previously. We also wish to emphasize the importance of not confusing it with a fracture in standard radiographies.

  11. Double layers and double wells in arbitrary degenerate plasmas

    Science.gov (United States)

    Akbari-Moghanjoughi, M.

    2016-06-01

    Using the generalized hydrodynamic model, the possibility of variety of large amplitude nonlinear excitations is examined in electron-ion plasma with arbitrary electron degeneracy considering also the ion temperature effect. A new energy-density relation is proposed for plasmas with arbitrary electron degeneracy which reduces to the classical Boltzmann and quantum Thomas-Fermi counterparts in the extreme limits. The pseudopotential method is employed to find the criteria for existence of nonlinear structures such as solitons, periodic nonlinear structures, and double-layers for different cases of adiabatic and isothermal ion fluids for a whole range of normalized electron chemical potential, η0, ranging from dilute classical to completely degenerate electron fluids. It is observed that there is a Mach-speed gap in which no large amplitude localized or periodic nonlinear excitations can propagate in the plasma under consideration. It is further revealed that the plasma under investigation supports propagation of double-wells and double-layers the chemical potential and Mach number ranges of which are studied in terms of other plasma parameters. The Mach number criteria for nonlinear waves are shown to significantly differ for cases of classical with η0 0 regimes. It is also shown that the localized structure propagation criteria possess significant dissimilarities for plasmas with adiabatic and isothermal ions. Current research may be generalized to study the nonlinear structures in plasma containing positrons, multiple ions with different charge states, and charged dust grains.

  12. A novel vibrational energy harvester with electric double layer electrets

    Science.gov (United States)

    Ono, S.; Miwa, K.; Iori, J.; Mitsuya, H.; Ishibashi, K.; Sano, C.; Toshiyoshi, H.; Fujita, H.

    2016-11-01

    We propose a new type of vibrational energy harvester with an electric double layer (EDL) electrets. Instead of using any external bias-voltage source or dielectric layer on top of the metal electrode to sustain EDL, we succeed to anchor the ions to polymer network to form the EDL electrets. By changing contact area between the EDL electrets and the electrode, large electric current is generated in the circuit. Owing to extremely large capacitance of the EDL electret, vibrational energy harvesters have the unique capability to leverage the high- density charge accumulation to the electrode and obtained current density becomes as high as 200 μA/cm2 with output voltage of 1V even with low frequency vibrations as low as 1 Hz.

  13. Electric Double-layer Capacitor Based on Activated Carbon Material

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    In this study electric double-layer capacitors (EDLCs) based on activated carbon material and organic electrolyte (tetraethyl ammonium tetrafluoroborate) were explored. The fabrication method for EDLC is presented and the performance of EDLC was examined by using the cyclic voltammetry, constant-current charging and discharging technique, electrochemical impedance spectroscopy measurements. Influence of various components and design parameters on the performance of the capacitors were preliminarily investigated. Up to now, EDLC based on carbon materials can deliver 20.7 W/kg at the discharge rate ofI=0.3 mA, together with the energy density of 8.5 Wh/kg. Equivalent series resistance (ESR) is 0.716 Ω.cm2. The specific power of the capacitor is low and further attempts to raise the power capability of the capacitors are necessary. Some considerations are put forward to further improve the performance of EDLC.

  14. Structure and Capacitance of Electrical Double Layers inside Micropores

    Science.gov (United States)

    Feng, Guang; Qiao, Rui; Huang, Jingsong; Sumpter, Bobby G.; Meunier, Vincent

    2010-03-01

    Recent experiments indicate that the specific capacitance of micropores (diameter less than 2nm) increases anomalously as the pore size decreases^[1]. To understand the physical origin of this discovery, we performed a series of molecular dynamics simulations to study the electrical double layers (EDLs) in micropores with different shapes (tube vs slit) and pore sizes (0.668nm - 3.342nm). Several different aqueous electrolytes (K^+, Na^+, Cl^-, and F^- in water) were used in these micropores. We quantified the structure of EDLs inside the pores, and computed the capacitance of EDLs. The scaling of capacitance shows a qualitative agreement with the experimental observations. We attribute the anomalous enhancement of capacitance in micropores to the short-range ionelectrode and ionsolvent interactions.[1] J. Chmiola, G. Yushin, Y. Gogotsi, C. Portet, P. Simon, and P.L. Taberna, Science 2006, 313, 1760.

  15. Propagation characteristics of ion-acoustic double layer in multicomponent inhomogeneous auroral zone plasma

    Indian Academy of Sciences (India)

    HARVINDER KAUR; TARSEM SINGH GILL; PARVEEN BALA

    2017-08-01

    In the present investigation, ion-acoustic double layers in an inhomogeneous plasma consisting of Maxwellian and non-thermal distributions of electrons are studied.We have derived a modified Korteweg–de Vries (mKdV) equation for ion-acoustic double layers propagating in a collisionless inhomogeneous plasma. It is observed that the non-thermal parameters affect the amplitude and width of the double layer which further depend on the density.

  16. Observation of flat band for terahertz coupled plasmon in metallic kagom\\'e lattice

    CERN Document Server

    Nakata, Yosuke; Nakanishi, Toshihiro; Kitano, Masao

    2012-01-01

    We study the dispersion relation of a metamaterial composed of metallic discs and bars arranged to have kagom\\'{e} symmetry and find that a plasmonic flat band is formed by the topological nature of the kagom\\'{e} lattice. To confirm the flat band formation, we fabricate the metamaterial and make transmission measurements in the terahertz regime. Two bands formed by transmission minima that depend on the polarization of the incident terahertz beams are observed. One of the bands corresponds to the flat band as confirmed by the fact that the resonant frequency is almost independent of the incident angle.

  17. Electrochemical double-layer capacitors based on functionalized graphene

    Science.gov (United States)

    Pope, Michael Allan

    Graphene is a promising electrode material for electrochemical double-layer capacitors (EDLCs) used for energy storage due to its high electrical conductivity and theoretical specific surface area. However, the intrinsic capacitance of graphene is known to be low and governed by the electronic side of the interface. Furthermore, graphene tends to aggregate and stack together when processed into thick electrode films. This significantly lowers the ion-accessible specific surface area (SSA). Maximizing both the SSA and the intrinsic capacitance are the main problems addressed in this thesis in an effort to improve the specific capacitance and energy density of EDLCs. In contrast to pristine graphene, functionalized graphene produced by the thermal exfoliation of graphite oxide contains residual functional groups and lattice defects. To study how these properties affect the double-layer capacitance, a model electrode system capable of measuring the intrinsic electrochemical properties of functionalized graphene was developed. To prevent artifacts and uncertainties related to measurements on porous electrodes, the functionalized graphene sheets (FGSs) were assembled as densely tiled monolayers using a Langmuir-Blodgett technique. In this way, charging can be studied in a well-defined 2D geometry. The possibility of measuring and isolating the intrinsic electrochemical properties of FGS monolayers was first demonstrated by comparing capacitance and redox probe measurements carried out on coatings deposited on passivated gold and single crystal graphite substrates. This monolayer system was then used to follow the double-layer capacitance of the FGS/electrolyte interface as the structure and chemistry of graphene was varied by thermal treatments ranging from 300 °C to 2100 °C. Elemental analysis and Raman spectroscopy were used to determine the resulting chemical and structural transformation upon heat treatment. It was demonstrated that intrinsically defective

  18. Anomalous Hall Effect in a Kagome Ferromagnet

    Science.gov (United States)

    Ye, Linda; Wicker, Christina; Suzuki, Takehito; Checkelsky, Joseph; Joseph Checkelsky Team

    The ferromagnetic kagome lattice is theoretically known to possess topological band structures. We have synthesized large single crystals of a kagome ferromagnet Fe3Sn2 which orders ferromagnetically well above room temperature. We have studied the electrical and magnetic properties of these crystals over a broad temperature and magnetic field range. Both the scaling relation of anomalous Hall effect and anisotropic magnetic susceptibility show that the ferromagnetism of Fe3Sn2 is unconventional. We discuss these results in the context of magnetism in kagome systems and relevance to the predicted topological properties in this class of compounds. This research is supported by DMR-1231319.

  19. Junction conditions in quadratic gravity: thin shells and double layers

    CERN Document Server

    Reina, Borja; Vera, Raül

    2015-01-01

    The junction conditions for the most general gravitational theory with a Lagrangian containing terms quadratic in the curvature are derived. We include the cases with a possible concentration of matter on the joining hypersurface -termed as thin shells, domain walls or braneworlds in the literature- as well as the proper matching conditions where only finite jumps of the energy-momentum tensor are allowed. In the latter case we prove that the matching conditions are more demanding than in General Relativity. In the former case, we show that generically the shells/domain walls are of a new kind because they possess, in addition to the standard energy-momentum tensor, a double layer energy-momentum contribution which actually induces an external energy flux vector and an external scalar pressure/tension on the shell. We prove that all these contributions are necessary to make the entire energy-momentum tensor divergence-free, and we present the field equations satisfied by these energy-momentum quantities. The ...

  20. Carbon aerogels for electric double-layer capacitors

    Institute of Scientific and Technical Information of China (English)

    ZHANG Lin; LIU Hongbo; WANG Ming; LIU Wei

    2006-01-01

    In this study, carbon aerogels were derived via the pyrolysis of resorcinol-formaldehyde (RF) aerogels, which were cost-effectively manufactured from RF wet gels by an ambient drying technique instead of conventional supercritical drying. By varying the R/C ratio (molar ratio of resorcinol to catalyst), mesoporous carbon aerogels with high specific surface area were prepared successfully and further investigated as electrode materials for electric double-layer capacitors (EDLCs). The textural properties of carbon aerogels obtained were characterized by nitrogen adsorption/desorption analysis and SEM. The electrochemical performances of carbon aerogels were investigated by impedance spectroscopy, galvanostatic charge/discharge and cyclic voltammetry methods. The results show that BET surface area and specific capacitance increase with R/C ratio, the maximum values of 727 m2·g-1 and 132 F·g-1 are achieved at R/C ratio will of 300. Increasing R/C ratio increase the average pore size of carbon aerogel electrode, which has improved the rate capability. Furthermore, EDLC with carbon aerogel electrodes has an excellent stability at large discharge current and long cycle life.

  1. Transport measurements on individual CuO 2 double layers

    Science.gov (United States)

    Mößle, M.; Kleiner, R.; Gatt, R.; Onellion, M.; Müller, P.

    2000-11-01

    Oxygen loss at the surface of Bi 2Sr 2CaCu 2O 8+ x single crystals provides CuO 2 layers with different critical temperatures. Particularly for overdoped crystals this allows to achieve a T c maximum near the surface. We performed transport measurements of this oxygen depleted layer. Samples were prepared by evaporating four Pb or Ag electrodes on top of freshly cleaved Bi 2Sr 2CaCu 2O 8+ x single crystals. Using overdoped crystals with a bulk T c of 55 to 60 K, the outermost layer was found to be underdoped with T c down to 30 K while the adjacent one was near optimal doping with T c between 80 and 90 K. The T c of the third layer was close to the bulk value. For temperatures above the bulk T c often only one CuO 2 double layer was found to be superconducting. We discuss current transport measurements with current flow along the CuO 2 layers.

  2. Interface phenomena in double-layer organic photoreceptors

    Science.gov (United States)

    Sasvari, G.; Juhasz, C.; Hirsch, J.

    1997-07-01

    Single photogeneration layers of a phthalocyanine pigment dispersed in a polyvinyl butyral binder, and double layers consisting of the photogeneration layer coated with hole transport layers of TPTA, DEH and BD molecularly dispersed in polycarbonate were exposed to single-shot light excitation. The charge collected was measured as a function of temperature, electric field, exposure intensity and duration. The resulting mean transport level of TPTA was found to be 0.17 eV, and that of DEH 0.11 eV, below the valence band of the pigment, but that of BD was found to be 0.09 eV above it. The injection efficiencies were independent of field and amounted to 0953-8984/9/30/015/img1 for TPTA and 0.02 for DEH, at room temperature, but that for BD was 0.1 independently of temperature. Models for the injection efficiencies in these cases are also discussed in this work for the first time.

  3. Lubrication approximation in completed double layer boundary element method

    Science.gov (United States)

    Nasseri, S.; Phan-Thien, N.; Fan, X.-J.

    This paper reports on the results of the numerical simulation of the motion of solid spherical particles in shear Stokes flows. Using the completed double layer boundary element method (CDLBEM) via distributed computing under Parallel Virtual Machine (PVM), the effective viscosity of suspension has been calculated for a finite number of spheres in a cubic array, or in a random configuration. In the simulation presented here, the short range interactions via lubrication forces are also taken into account, via the range completer in the formulation, whenever the gap between two neighbouring particles is closer than a critical gap. The results for particles in a simple cubic array agree with the results of Nunan and Keller (1984) and Stoksian Dynamics of Brady etal. (1988). To evaluate the lubrication forces between particles in a random configuration, a critical gap of 0.2 of particle's radius is suggested and the results are tested against the experimental data of Thomas (1965) and empirical equation of Krieger-Dougherty (Krieger, 1972). Finally, the quasi-steady trajectories are obtained for time-varying configuration of 125 particles.

  4. Fast charging self-powered electric double layer capacitor

    Science.gov (United States)

    Parida, Kaushik; Bhavanasi, Venkateswarlu; Kumar, Vipin; Wang, Jiangxin; Lee, Pooi See

    2017-02-01

    Self-powered electrochemical energy storage devices, which store energy upon application of mechanical force, have emerged as a promising technology for the realization of autonomous systems for maintenance-free, independent and multifunctional operations. However, the existing state-of-the-art technology demonstrates slow self-charging due to slow Faradaic reactions and intercalation mechanism. Here, we report a fast self-charging, self-powered electrochemical energy storage device owing to the formation of an electric double layer with fast adsorption and desorption of ions at the carbon nanotube (CNT) electrode upon application of mechanical force. The device charges up to 70 mV from the open-circuit potential, storing a capacitance of 95 μFcm-2 upon application of a mechanical pressure of 70 N at a frequency of 5 Hz. More importantly, it takes less than 10 s to achieve 90% of the increment in the potential (60 mV), which is more than one order of magnitude faster than all of the previously reported self-powered energy storage devices.

  5. Experimental investigation of double layers in expanding plasmas

    CERN Document Server

    Plihon, N; Corr, C S

    2015-01-01

    Double layers (DLs) have been observed in a plasma reactor composed of a source chamber attached to a larger expanding chamber. Positive ion beams generated across the DL were characterized in the low plasma potential region using retarding field energy analyzers. In electropositive gases, DLs were formed at very low pressures between 0.1 and 1 mTorr with the plasma expansion forced by a strongly diverging magnetic field. The DL remains static, robust to changes in boundary conditions, and its position is related to the magnetic field lines. The voltage drop across the DL increases with decreasing pressure, i.e., with increasing electron temperature around 20 V at 0.17 mTorr. DLs were also observed in electronegative gases without a magnetic field over a greater range of pressure 0.5 to 10 mTorr. The actual profile of the electronegative DL is very sensitive to external parameters and intrusive elements, and they propagate at high negative ion fraction. Electrostatic probes measurements and laser-induced phot...

  6. The double-layered chemical structure in DB white dwarfs

    CERN Document Server

    Althaus, L G

    2004-01-01

    We study the structure and evolution of white dwarf stars with helium-rich atmospheres (DB) in a self-consistent way with the predictions of time-dependent element diffusion. Our treatment of diffusion includes gravitational settling and chemical and thermal diffusion. OPAL radiative opacities for arbitrary metallicity and carbon-and oxygen-rich compositions are employed. Emphasis is placed on the evolution of the diffusion-modeled double-layered chemical structure. This structure, which is characterized by a pure helium envelope atop an intermediate remnant shell rich in helium, carbon and oxygen, is expected for pulsating DB white dwarfs, assuming that they are descendants of hydrogen-deficient PG1159 post-AGB stars. We find that, depending on the stellar mass, if DB white dwarf progenitors are formed with a helium content smaller than \\approx 10^-3 M_*, a single-layered configuration is expected to emerge during the DB pulsation instability strip. We also explore the consequences of diffusively evolving ch...

  7. Plasmons in spatially separated double-layer graphene nanoribbons

    Science.gov (United States)

    Bagheri, Mehran; Bahrami, Mousa

    2014-05-01

    Motivated by innovative progresses in designing multi-layer graphene nanostructured materials in the laboratory, we theoretically investigate the Dirac plasmon modes of a spatially separated double-layer graphene nanoribbon system, made up of a vertically offset armchair and metallic graphene nanoribbon pair. We find striking features of the collective excitations in this novel Coulomb correlated system, where both nanoribbons are supposed to be either intrinsic (undoped/ungated) or extrinsic (doped/gated). In the former, it is shown the low-energy acoustical and the high-energy optical plasmon modes are tunable only by the inter-ribbon charge separation. In the later, the aforementioned plasmon branches are modified by the added doping factor. As a result, our model could be useful to examine the existence of a linear Landau-undamped low-energy acoustical plasmon mode tuned via the inter-ribbon charge separation as well as doping. This study might also be utilized for devising novel quantum optical waveguides based on the Coulomb coupled graphene nanoribbons.

  8. Junction conditions in quadratic gravity: thin shells and double layers

    Science.gov (United States)

    Reina, Borja; Senovilla, José M. M.; Vera, Raül

    2016-05-01

    The junction conditions for the most general gravitational theory with a Lagrangian containing terms quadratic in the curvature are derived. We include the cases with a possible concentration of matter on the joining hypersurface—termed as thin shells, domain walls or braneworlds in the literature—as well as the proper matching conditions where only finite jumps of the energy-momentum tensor are allowed. In the latter case we prove that the matching conditions are more demanding than in general relativity. In the former case, we show that generically the shells/domain walls are of a new kind because they possess, in addition to the standard energy-momentum tensor, a double layer energy-momentum contribution which actually induces an external energy flux vector and an external scalar pressure/tension on the shell. We prove that all these contributions are necessary to make the entire energy-momentum tensor divergence-free, and we present the field equations satisfied by these energy-momentum quantities. The consequences of all these results are briefly analyzed.

  9. Two-dimensional Kagome photonic bandgap waveguide

    DEFF Research Database (Denmark)

    Nielsen, Jens Bo; Søndergaard, Thomas; Libori, Stig E. Barkou;

    2000-01-01

    The transverse-magnetic photonic-bandgap-guidance properties are investigated for a planar two-dimensional (2-D) Kagome waveguide configuration using a full-vectorial plane-wave-expansion method. Single-moded well-localized low-index guided modes are found. The localization of the optical modes...... is investigated with respect to the width of the 2-D Kagome waveguide, and the number of modes existing for specific frequencies and waveguide widths is mapped out....

  10. Finite-Thickness and Charge Relaxation in Double-Layer Interactions

    NARCIS (Netherlands)

    Torres, A.; Roij, R. van; Téllez, G.

    2006-01-01

    We extend the classical Gouy-Chapman model of two planar parallel interacting double-layers, which is used as a first approximation to describe the force between colloidal particles, by considering the finitethickness of the colloids. The formation of two additional double layers due to this finite

  11. Finite-Thickness and Charge Relaxation in Double-Layer Interactions

    NARCIS (Netherlands)

    Torres, A.; Roij, R. van; Téllez, G.

    2006-01-01

    We extend the classical Gouy-Chapman model of two planar parallel interacting double-layers, which is used as a first approximation to describe the force between colloidal particles, by considering the finitethickness of the colloids. The formation of two additional double layers due to this

  12. The electric double layer put to work : thermal physics at electrochemical interfaces

    NARCIS (Netherlands)

    Janssen, M.A.

    2017-01-01

    Where charged electrode surfaces meet fluids that contain mobile ions, so-called electric double layers (EDLs) form to screen the electric surface charge by a diffuse cloud of counterionic charge in the fluid phase. This double layer has been studied for over a century and is of paramount importance

  13. Inference of Polymer Adsorption from Electrical Double Layer Measurements : the Silver Iodide-Polyvinyl Alcohol System

    NARCIS (Netherlands)

    Koopal, L.K.

    1978-01-01

    The purpose of this study was to investigate how the double layer properties of charged particles are modified by the presence of adsorbed polymer molecules and to obtain information on the conformation of the polymer layer from the observed alterations in the double layer properties.In chapter 1. t

  14. Experimental validation of sound field control with a circular double-layer array of loudspeakers

    DEFF Research Database (Denmark)

    Chang, Jiho; Jacobsen, Finn

    2013-01-01

    This paper is concerned with experimental validation of a recently proposed method of controlling sound fields with a circular double-layer array of loudspeakers [Chang and Jacobsen, J. Acoust. Soc. Am. 131(6), 4518-4525 (2012)]. The double-layer of loudspeakers is realized with 20 pairs of closed-box...

  15. Development of high energy density electrical double layer capacitors

    Science.gov (United States)

    Devarajan, Thamarai selvi

    Electrochemical Double Layer capacitors (EDLCs) have shown themselves as a viable energy storage alternative. EDLCs have high power density, faster charge/discharge, wide operating temperature and long cycle life compared to batteries since it stores charge by physical separation. Despites all their advantages, their low energy density stand as a bottleneck for capacitors. This research aims to increase the energy density of EDLC without compromising the power density. Energy is proportional to the square of cell voltage. Cell voltage is mainly dependent on electrolyte breakdown. Electrolytes also provide ions for charge separation and conduction. Therefore various electrolytes (Solutes and Solvents) which can give high concentration, solubility and decomposition potential were characterized in the first part of the research. In that study, a novel ionic liquid OPBF4 had higher capacitance and comparable voltage window compared to commercial TEABF4 in Acetonitrile. However, the increased polarity of the fixed ring O-atom and the ion-ion interaction in OPBF4 was responsible for lowering its conductivity. Oxygenated ionic compounds with alkyl groups had lower stability due to beta elimination between two electron withdrawing atoms. Volume based thermodynamics and quantum chemical calculations were used to calculate ion size, HOMO/LUMO energies, and free energy changes and establish relationship with capacitance, redox potential and melting points respectively. In addition free energy of fusion was used to predict the melting point. Ion size had correlation with capacitance due to compact double layer formation. Free energy changes did not explain the differences in melting point and predicted dielectric constant was inconsistent with the polarity. This is presumably due to using Van der Waals volume instead of crystal structure volume and insufficient incorporation of polarization term. The HOMO/LUMO energies gave direct relation between oxidation and reduction

  16. Deep Penetration of Spudcan Foundation into Double Layered Soils

    Institute of Scientific and Technical Information of China (English)

    LIU Jun; HU Yu-xia; KONG Xian-jing

    2005-01-01

    The spudcan foundation has been widely used in offshore engineering for jack-up rigs. However, "punch through"failure often occurs where a stronger soil layer overlays a softer soil layer. In this study, spudcan penetration into double layered soils is investigated numerically. The soil profile is set up as a stronger soil layer overlaying a softer soil layer,with the soil strength ratio ( bottom soil strength / top soil strength) varied from 0.1 to 1.0 ( 1 means uniform soil). The bearing behaviour is discussed and the bearing capacity factors are given for various cases involving different layer thicknesses and different strength ratios of the two clay layers. The development of the plastic zones and the effect of soil selfweight on the bearing capacity are also discussed. From this study, it is found that, when a spudcan is distant from the soil layer boundary, the spudcan can be analysed with single soil layer data. However, when a spudcan becomes closer to the soil boundary layer, the influence of the lower soft soil layer is significant, and the bearing capacity of the spudcan decreases. The critical distance is an indication of the occurrence of "punch through" failure. The critical distance between the spudcan and the layer boundary is larger for a rough spudcan than the one for a smooth one, and the critical distance decreases with increasing soil strength ratio. The depth of cavity formed during initial spudcan penetration depends on the top layer soil strength, soil strength ratio and unit soil self-weight, and the cavity affects the spudcan bearing behaviour as well.

  17. Energy distribution of elastically scattered electrons from double layer samples

    Science.gov (United States)

    Tőkési, K.; Varga, D.

    2016-02-01

    We present a theoretical description of the spectra of electrons elastically scattered from thin double layered Au-C samples. The analysis is based on the Monte Carlo simulation of the recoil and Doppler effects in reflection and transmission geometries of the scattering at a fixed angle of 44.3 ° and a primary energy of 40 keV. The relativistic correction is taken into account. Besides the experimentally measurable energy distributions the simulations give many partial distributions separately, depending on the number of elastic scatterings (single, and multiple scatterings of different types). Furthermore, we present detailed analytical calculations for the main parameters of the single scattering, taking into account both the ideal scattering geometry, i.e. infinitesimally small angular range, and the effect of the real, finite angular range used in the measurements. We show our results for intensity ratios, peak shifts and broadenings for four cases of measurement geometries and layer thicknesses. While in the peak intensity ratios of gold and carbon for transmission geometries were found to be in good agreement with the results of the single scattering model, especially large deviations were obtained in reflection geometries. The separation of the peaks, depending on the geometry and the thickness, generally smaller, and the peak width generally larger than it can be expected from the nominal values of the primary energy, scattering angle, and mean kinetic energy of the atoms. We also show that the peaks are asymmetric even for the case of the single scattering due to the finite solid angle. Finally, we present a qualitative comparison with the experimental data. We find our resulting energy distribution of elastically scattered electrons to be in good agreement with recent measurements.

  18. Does the plasma radiate near a Double Layer?

    Science.gov (United States)

    Pottelette, Raymond; Berthomier, Matthieu; Pickett, Jolene

    2016-04-01

    Earth is an intense radio source in the kilometer wavelength range. Being a direct consequence of the parallel acceleration processes taking place in the Earth's auroral region, the radiation contains fundamental information on the characteristic spatial and temporal scales of the turbulent accelerating layer. It is now widely assumed that the cyclotron maser instability leads to Auroral Kilometric Radiation (AKR) generation. It has been suggested from the FAST measurements that the AKR results from a so-called horseshoe electron distribution. This distribution is generated when a localized parallel electric field - called Double Layer (DL) - accelerates earthward the electrons that propagate into an increasing magnetic field. The magnetic moment of the electrons is conserved so that their pitch angle is increased. This results in the creation of a horseshoe-like shape for the electron distribution exhibiting large positive velocity gradients in the direction perpendicular to B, thereby providing free energy for the AKR generation which takes place at the local electron gyrofrequency. In these circumstances, the radiation is generated far away (several thousand kilometers) from a DL, because the parallel accelerated electrons need to travel a long distance before forming a horseshoe distribution. From an experimental point of view, it is not an easy task to highlight the presence of DLs, because they are moving transient structures so that high time resolution measurements are needed. A detailed analysis suggests that these large-amplitude parallel electric fields are located inside sharp density gradients at the interface separating the cold, dense ionospheric plasma from the hot, tenuous magnetospheric plasma. We present some FAST observations which illustrate the generation of elementary radiation events in the neighborhood of a DL. The events occur 10 to 20% above the local electron gyrofrequency in association with the presence of nonlinear coherent structures

  19. Electrochemical Double Layered Capacitor Development and Implementation System

    Science.gov (United States)

    Strunk, Gavin P.

    Electrochemical Double Layered Capacitors (EDLC's) are becoming a more popular topic of research for hybrid power systems, especially vehicles. They are known for their high power density, high cycle life, low internal resistance, and wider operating temperature compared to batteries. They are rarely used as a standalone power source; however, because of their lack of energy density compared to batteries and fuel cells. Researchers are now discovering the benefits of using them in hybrid systems. The increased complexity of a hybrid power source presents many challenges. A major drawback of this complexity is the lack of design tools to assist a designer in translating a simulation all the way to a full scale implementation. A full spectrum of tools was designed to assist designers at all stages of implementation including: single cell testing, a multi-cell management system, and a full scale vehicle data acquisition system to monitor performance. First, the full scale vehicle data acquisition is described. The system is isolated from the electric shuttle bus it was tested on to allow the system to be ported to other vehicles and applications. This was done to modularize the system to characterize a wide variety of full scale applications. Next, a single cell test system was designed that allows the designer to characterize cell specifications, as well as, test control and safety systems in a controlled environment. The goal is to ensure safety systems can be thoroughly tested to ensure robustness as the bank is scaled up. This system also includes simulation models that provide examples of using the simulation to predict the behavior of a cell and the test system to validate the results of the simulation. This information is then used by the designer to more effectively design sensor ranges for the bank. Finally, a multi-cell EDLC management system was designed to implement a bank. It incorporates 12 series EDLC cells per control module, and the modular design

  20. RESISTANCE EFFECT OF ELECTRIC DOUBLE LAYER ON LIQUID FLOW IN MICROCHANNEL

    Institute of Scientific and Technical Information of China (English)

    GONG Lei; WU Jian-kang

    2006-01-01

    Poisson-Boltzmann equation for EDL (electric double layer) and NavierStokes equation for liquid flows were numerically solved to investigate resistance effect of electric double layer on liquid flow in microchannel. The dimension analysis indicates that the resistance effect of electric double layer can be estimated by an electric resistance number, which is proportional to the square of the liquid dielectric constant and the solid surface zeta potential, and inverse-proportional to the liquid dynamic viscosity, electric conductivity and the square of the channel width. An "electric current density balancing" (ECDB) condition was proposed to evaluate the flow-induced streaming potential,instead of conventional "electric current balancing" (ECB) condition which may induce spurious local backflow in neighborhood of the solid wall of the microchannel. The numerical results of the flow rate loss ratio and velocity profile are also given to demonstrate the resistance effect of electric double layer in microchannel.

  1. Electron emission from a double-layer metal under femtosecond laser irradiation

    Energy Technology Data Exchange (ETDEWEB)

    Li, Shuchang; Li, Suyu; Jiang, Yuanfei; Chen, Anmin, E-mail: amchen@jlu.edu.cn; Ding, Dajun; Jin, Mingxing, E-mail: mxjin@jlu.edu.cn

    2015-01-01

    In this paper we theoretically investigate electron emission during femtosecond laser ablation of single-layer metal (copper) and double-layer structures. The double-layer structure is composed of a surface layer (copper) and a substrate layer (gold or chromium). The calculated results indicate that the double-layer structure brings a change to the electron emission from the copper surface. Compared with the ablation of a single-layer, a double-layer structure may be helpful to decrease the relaxation time of the electron temperature, and optimize the electron emission by diminishing the tailing phenomenon under the same absorbed laser fluence. With the increase of the absorbed laser fluence, the effect of optimization becomes significant. This study provides a way to optimize the electron emission which can be beneficial to generate laser induced ultrafast electron pulse sources.

  2. Unravelling the electrochemical double layer by direct probing of the solid/liquid interface

    Science.gov (United States)

    Favaro, Marco; Jeong, Beomgyun; Ross, Philip N.; Yano, Junko; Hussain, Zahid; Liu, Zhi; Crumlin, Ethan J.

    2016-08-01

    The electrochemical double layer plays a critical role in electrochemical processes. Whilst there have been many theoretical models predicting structural and electrical organization of the electrochemical double layer, the experimental verification of these models has been challenging due to the limitations of available experimental techniques. The induced potential drop in the electrolyte has never been directly observed and verified experimentally, to the best of our knowledge. In this study, we report the direct probing of the potential drop as well as the potential of zero charge by means of ambient pressure X-ray photoelectron spectroscopy performed under polarization conditions. By analyzing the spectra of the solvent (water) and a spectator neutral molecule with numerical simulations of the electric field, we discern the shape of the electrochemical double layer profile. In addition, we determine how the electrochemical double layer changes as a function of both the electrolyte concentration and applied potential.

  3. Characterization of Microporous Activated Carbon Electrodes for Electric Double-layer Capacitors

    Institute of Scientific and Technical Information of China (English)

    MENG Qing-han; LIU Ling; SONG Huai-he

    2004-01-01

    Activated carbons (ACs) with a wide range of surface areas were made from petroleum coke by means of KOH activation. The electrochemical characterization was carried out for several activated carbons used as polariz able electrodes of electric double-layer capacitors (EDLCs) in an aqueous electrolytic solution. The porous structures and electrochemical double-layer capacitance of the activated carbons were investigated by virtue of nitrogen gas adsorption and constant current cycling(CCC) methods. The relationship among the surface area, pore volume of the activated carbons and specific double-layer capacitance was discussed. It was found that the specific capacitance of ACs increased linearly with the increase of surface area. The presence of mesopores in the activated carbons with very high surface area(>2000 m2/g) was not very effective for them to be used as EDLCs. The influence of chemical characteristics of the activated carbons on the double layer formation could be considered to be negligible.

  4. Epitaxial Growth of High-Quality Silicon Films on Double-Layer Porous Silicon

    Institute of Scientific and Technical Information of China (English)

    黄宜平; 竺士炀; 李爱珍; 王瑾; 黄靖云; 叶志镇

    2001-01-01

    The epitaxial growth of a high-quality silicon layer on double-layer porous silicon by ultra-high vacuum/chemical vapour deposition has been reported. The two-step anodization process results in a double-layer porous silicon structure with a different porosity. This double-layer porous silicon structure and an extended low-temperature annealing in a vacuum system was found to be helpful in subsequent silicon epitaxial growth. X-ray diffraction,cross-sectional transmission electron microscopy and spreading resistance testing were used in this work to study the properties of epitaxial silicon layers grown on the double-layer porous silicon. The results show that the epitaxial silicon layer is of good crystallinity and the same orientation with the silicon substrate and the porous silicon layer.

  5. Anomalous double layer step formation on Si(100) in hydrogen ambient

    Energy Technology Data Exchange (ETDEWEB)

    Doescher, Henning; Kleinschmidt, Peter; Dobrich, Anja; Brueckner, Sebastian; Supplie, Oliver; Luczak, Johannes; Hannappel, Thomas [Helmholtz-Zentrum Berlin fuer Materialien und Energie, Berlin (Germany)

    2011-07-01

    Generation of double layer steps on Si(100) is desirable for subsequent anti-phase domain-free heteroepitaxy of III-V semiconductors. In UHV established procedures exist for the formation of double layer steps at the clean Si(100) surface. In the (metal-organic) vapour phase epitaxy environment the situation is more complicated due to the presence of hydrogen in the process ambient. Both theory and experiment of the hydrogenated surfaces suggest that under equilibrium conditions no preference for double layer steps is to be expected. Previously, we have shown that annealing in hydrogen at near atmospheric pressure leads to termination of the surface by monohydride. Here, we show that a process using Si(100) with an intermediate offcut of 2 in <011> can lead to a double layer stepped surface. Our process consists of deoxidation, homoepitaxial growth employing silane, annealing and slow cooling to 500 C in hydrogen ambient. We observe the formation of double layer steps using Fourier-transform infrared spectroscopy, low-energy electron diffraction and scanning tunneling microscopy. In sharp contrast to established UHV results, the double layer steps are of the D{sub A} type, where dimer rows of the reconstructed surface are parallel to the step edges.

  6. Start-stop and recuperation: DC/DC current inverters with integrated double-layer condensers; Start-Stopp und Rekuperation: DC/DC-Wandler mit integrierten Doppelschichtkondensatoren

    Energy Technology Data Exchange (ETDEWEB)

    Igel, Juergen; Ollhaeuser, Helmut; Jeuck, Marc; Apfelbacher, Thomas [Alcoa/AFL Europe GmbH, Frickenhausen (Germany)

    2008-09-15

    Start-stop systems may be made more efficient, and energy recovery in regenerative brakes may be made more economical. The contribution describes a new DC/DC current inverter with integrated double-layer condensers developed by the electric/electronics department of Alcoa. The so-called Energy Conversion Module (ECM) will result in considerable fuel savings and also help to stabilize board grids which are nearing their limits because of the increasing number of electrified service aggregates. Motor car producers are currently testing the module. (orig.)

  7. Wrinkle Behavior of Hydroforming of Aluminum Alloy Double-Layer Sheets

    Science.gov (United States)

    Zhou, Bin-Jun; Xu, Yong-Chao

    2016-07-01

    In this article, the wrinkling behavior and thickness distribution of 5A06 aluminum alloy sheets in an annealed state with thickness of 1.0 mm and 2.5 mm was numerically and experimentally investigated under different hydraulic pressures in the hydroforming of single-layer and double-layer sheets. Note that, in double-layer sheets hydroforming, an upper-aided sheet is needed. The upper, thicker sheet synchronously deforms with the lower, thinner sheet during hydroforming. When the double-layer sheets are separated, a thinner curved sheet part will be manufactured. As can be seen from the simulation and experimental results, the upper, thicker sheet could effectively suppress the wrinkles of the lower, thinner sheet and improve the thickness distribution due to the increasing anti-wrinkle ability of the formed sheet and the interfacial friction between the double-layer sheets. In addition, the maximum hydraulic pressure can be decreased via hydroforming of double-layer sheets; this approach reduces the drawing force for large sheet parts and meets the requirement of energy conservation.

  8. Enhanced charge separation and oxidation kinetics of BiVO4 photoanode by double layer structure

    Science.gov (United States)

    Yang, Lin; Xiong, Yuli; Dong, Hongmei; Peng, Huarong; Zhang, Yunhuai; Xiao, Peng

    2017-03-01

    Monoclinic bismuth vanadate (BiVO4) is a promising semiconductor for photoelectrochemical water splitting. Here, we developed a facile fabrication of BiVO4 double layer photoanode on the fluorine-doped tin oxide substrate by electrodeposition. The BiVO4 double layer photoanode is composed by a dense BiVO4 film as the inner layer and a nanoporous BiVO4 film as the outer layer. Compared to the BiVO4 single layer photoanode, the optimized BiVO4 double layer photoanode produced a much higher photocurrent of 1.15 mA/cm2 at 0.6 V vs. Ag/AgCl under AM 1.5G (100 mW/cm2) illumination. The results of the photoelectric conversion kinetics for different samples revealed that the charge separation and oxidation kinetics efficiencies for the BiVO4 double layer are 47.2% and 51.6% at 0.6 V vs. Ag/AgCl, while the values for BiVO4 single layer are 32.3% and 35.8%, respectively. The improved photoelectrochemical performance for BiVO4 double layer is mainly ascribed to the decrease of defect state at the interface after inserting a dense BiVO4 as an inner layer to prevent the recombination of photogenerated electron-hole pairs.

  9. Umbilical Cord Mesenchymal Stem Cells Combined With a Collagenfibrin Double-layered Membrane Accelerates Wound Healing.

    Science.gov (United States)

    Nan, Wenbin; Liu, Rui; Chen, Hongli; Xu, Zhihao; Chen, Jiannan; Wang, Manman; Yuan, Zhiqing

    2015-05-01

    The aim of this study was to examine the effects of human umbilical cord mesenchymal stem cells (hUCMSCs) in combination with a collagen-fibrin double-layered membrane on wound healing in mice. A collagen-fibrin double-layered membrane was prepared, and the surface properties of the support material were investigated using a scanning electron microscope. Twenty-four mice were prepared for use as full-thickness skin wound models and randomly divided into 3 groups: group A, a control group in which the wounds were bound using a conventional method; group B, a group treated with hUCMSCs combined with a collagen membrane; and group C, a group treated with hUCMSCs combined with a collagen-fibrin double-layered membrane. The postoperative concrescence of the wounds was observed daily to evaluate the effects of the different treatments. Scanning electron microscope observation showed the collagen-fibrin scaffolds exhibited a highly porous and interconnected structure, and wound healing in the double-layered membrane group was better than in groups A or B. Treatment with hUCMSCs combined with a collagen-fibrin double-layered membrane accelerated wound healing.

  10. Fracture Characteristics Analysis of Double-layer Rock Plates with Both Ends Fixed Condition

    Directory of Open Access Journals (Sweden)

    S. R. Wang

    2014-07-01

    Full Text Available In order to research on the fracture and instability characteristics of double-layer rock plates with both ends fixed, the three-dimension computational model of double-layer rock plates under the concentrated load was built by using PFC3D technique (three-dimension particle flow code, and the mechanical parameters of the numerical model were determined based on the physical model tests. The results showed the instability process of the double-layer rock plates had four mechanical response phases: the elastic deformation stage, the brittle fracture of upper thick plate arching stage, two rock-arch bearing stage and two rock-arch failure stage; moreover, with the rock plate particle radius from small to large change, the maximum vertical force of double rock-arch appeared when the particle size was a certain value. The maximum vertical force showed an upward trend with the increase of the rock plate temperature, and in the case of the same thickness the maximum vertical force increased with the increase of the upper rock plate thickness. When the boundary conditions of double-layer rock plates changed from the hinged support to the fixed support, the maximum horizontal force observably decreased, and the maximum vertical force showed small fluctuations and then tended towards stability with the increase of cohesive strength of double-layer rock plates.

  11. Artificial kagome arrays of nanomagnets: a frozen dipolar spin ice.

    Science.gov (United States)

    Rougemaille, N; Montaigne, F; Canals, B; Duluard, A; Lacour, D; Hehn, M; Belkhou, R; Fruchart, O; El Moussaoui, S; Bendounan, A; Maccherozzi, F

    2011-02-04

    Magnetic frustration effects in artificial kagome arrays of nanomagnets are investigated using x-ray photoemission electron microscopy and Monte Carlo simulations. Spin configurations of demagnetized networks reveal unambiguous signatures of long range, dipolar interaction between the nanomagnets. As soon as the system enters the spin ice manifold, the kagome dipolar spin ice model captures the observed physics, while the short range kagome spin ice model fails.

  12. Artificial Kagome Arrays of Nanomagnets: A Frozen Dipolar Spin Ice

    OpenAIRE

    Rougemaille, N.; Montaigne, F.; Canals, B.; Duluard, A.; D. Lacour; Hehn, M.; Belkhou, R.; Fruchart, O.; Moussaoui, S. El; Bendounan, A.; Maccherozzi, F.

    2011-01-01

    Magnetic frustration effects in artificial kagome arrays of nanomagnets are investigated using x-ray photoemission electron microscopy and Monte Carlo simulations. Spin configurations of demagnetized networks reveal unambiguous signatures of long range, dipolar interaction between the nanomagnets. As soon as the system enters the spin ice manifold, the kagome dipolar spin ice model captures the observed physics, while the short range kagome spin ice model fails.

  13. PT-symmetric phase in kagome photonic lattices

    OpenAIRE

    Chern, Gia-Wei; Saxena, Avadh

    2015-01-01

    Kagome lattice is a two-dimensional network of corner-sharing triangles and is often associated with geometrical frustration. In particular, the frustrated coupling between waveguide modes in a kagome array leads to a dispersionless flat band consisting of spatially localized modes. Here we propose a complex photonic lattice by placing $\\mathcal{PT}$-symmetric dimers at the kagome lattice points. Each dimer corresponds to a pair of strongly coupled waveguides. With balanced arrangement of gai...

  14. High Corrosion-Resistance Double-Layer Ni-P Coating on Steels

    Institute of Scientific and Technical Information of China (English)

    JIANG Hai; LIU Xian-li; JIANG Zhang-hao; LI Guang-yu; LIAN Jian-she; GU Chang-dong

    2004-01-01

    Double-layer Ni-P alloy coating with a thickness about 20 μm and different Ni-P layers was prepared by electroless deposition and its corrosion resistance was studied. The microstructure and corrosion-resistance of the coatings were analyzed by SEM, XRD, electrochemical polarization measurements and salt spray tests. The salt spray tests showed that the double-layer coating exhibits better corrosion resistance. The time of the emergence of the first red rust spot on the coating surface can reach 384 hours, and the gray rusts were firstly emergered during the salt spray tests. The electrochemical analysis revealed that the difference in the corrosion potential between the double layers plays a very important role in protecting the substrate from rusting.

  15. Proton Acceleration with Double-Layer Targets in the Radiation Pressure Dominant Regime

    Institute of Scientific and Technical Information of China (English)

    LU Hai-Yang; WANG Cheng; LIU Jian-Sheng

    2011-01-01

    @@ Acceleration of protons by a circularly polarized laser pulse irradiating on a double-layer target is investigated by a theoretical model and particle-in-cell simulations.The target is made up of a heavy ion layer coated with a proton layer on the rear surface.The results show that when the first layer is transparent induced by the hole-boring effect, the whole proton layer is accelerated by the transmitted laser pulse to high energy with low energy spread.The quality of the proton beam generated from a double-layer target is better than that from a single-layer target.The improvement is attributed to the flat top structure of the electrostatic field caused by the electrons injected into the second layer.It is easier to control the spectrum quality by using a double-layer target rather than using a single-layer one when the radiation pressure acceleration is dominant.

  16. Low frequency solitons and double layers in a magnetized plasma with two temperature electrons

    Energy Technology Data Exchange (ETDEWEB)

    Rufai, O. R. [Department of Physics, University of the Western Cape, Private Bag X17, Bellville 7535 (South Africa); Bharuthram, R. [Office of the Deputy Vice Chancellor (Academic), University of the Western Cape, Bellville (South Africa); Singh, S. V. [Indian Institute of Geomagnetism, New Panvel (W), Navi Mumbai-410218 (India); School of Chemistry and Physics, University of Kwa-Zulu Natal, Durban (South Africa); Lakhina, G. S. [Indian Institute of Geomagnetism, New Panvel (W), Navi Mumbai-410218 (India)

    2012-12-15

    Finite amplitude non-linear ion-acoustic solitary waves and double layers are studied in a magnetized plasma with cold ions fluid and two distinct groups of Boltzmann electrons, using the Sagdeev pseudo-potential technique. The conditions under which the solitary waves and double layers can exist are found both analytically and numerically. We have shown the existence of negative potential solitary waves and double layers for subsonic Mach numbers, whereas in the unmagnetized plasma they can only in the supersonic Mach number regime. For the plasma parameters in the auroral region, the electric field amplitude of the solitary structures comes out to be 49 mV/m which is in agreement of the Viking observations in this region.

  17. Droplet transfer behavior of the stainless steel coated electrode with double-layer coating

    Institute of Scientific and Technical Information of China (English)

    孙咸; 马成勇; 王宝; 张汉谦

    2002-01-01

    In this paper, the droplet transfer behavior of the stainless steel coated electrode with double-layer coating is researched by means of those experimental methods, such as high speed camera, collecting droplet in water, surfacing on the steel plate et al. The results show that the droplet transfer indexes of coated electrode are mainly controlled by the size of droplet, which affects the transfer behavior of droplet. The distribution characteristic of the droplet size of the electrode affects the numerical relationship among droplet transfer indexes. The metallurgical process of the coated electrode with double-layer coating is carried out continuously in different zones. The main reason for the coated electrode with double-layer coating gaining excellent usability quality is that the droplets realize the "quasi flux wall guided transfer pattern".

  18. Interfacial double layer mediated electrochemical growth of thin-walled platinum nanotubes

    Science.gov (United States)

    Zhang, Liqiu; Kim, Sang Min; Cho, Sanghyun; Jang, Hee-Jeong; Liu, Lichun; Park, Sungho

    2017-01-01

    This work demonstrates that thin-walled platinum nanotubes can be readily synthesized by controlling the interfacial double layer in alumina nanochannels. The gradient distribution of ions in nanochannels enables the creation of Pt nanotubes with walls as thin as 5 nm at the top end when using a solution containing polyvinylpyrrolidone (PVP) and chloroplatinic acid (H2PtCl6) under the influence of an electric potential in nanochannels. The highly efficient formation of thin-walled Pt nanotubes is a result of the concentration gradient of {{{{PtCl}}}6}2- and a thick double layer, which was caused by the low concentration of Pt precursors and the enhanced surface charge density induced by protonated PVP steric adsorption. This well-controlled synthesis reveals that the interfacial double layer is a useful tool to tailor the structure of nanomaterials in a nanoscale space, and holds promise in the construction of more complex functional nanostructures.

  19. Megavolt parallel potentials arising from double-layer streams in the Earth's outer radiation belt.

    Science.gov (United States)

    Mozer, F S; Bale, S D; Bonnell, J W; Chaston, C C; Roth, I; Wygant, J

    2013-12-06

    Huge numbers of double layers carrying electric fields parallel to the local magnetic field line have been observed on the Van Allen probes in connection with in situ relativistic electron acceleration in the Earth's outer radiation belt. For one case with adequate high time resolution data, 7000 double layers were observed in an interval of 1 min to produce a 230,000 V net parallel potential drop crossing the spacecraft. Lower resolution data show that this event lasted for 6 min and that more than 1,000,000 volts of net parallel potential crossed the spacecraft during this time. A double layer traverses the length of a magnetic field line in about 15 s and the orbital motion of the spacecraft perpendicular to the magnetic field was about 700 km during this 6 min interval. Thus, the instantaneous parallel potential along a single magnetic field line was the order of tens of kilovolts. Electrons on the field line might experience many such potential steps in their lifetimes to accelerate them to energies where they serve as the seed population for relativistic acceleration by coherent, large amplitude whistler mode waves. Because the double-layer speed of 3100  km/s is the order of the electron acoustic speed (and not the ion acoustic speed) of a 25 eV plasma, the double layers may result from a new electron acoustic mode. Acceleration mechanisms involving double layers may also be important in planetary radiation belts such as Jupiter, Saturn, Uranus, and Neptune, in the solar corona during flares, and in astrophysical objects.

  20. Ferromagnetic resonance and resonance modes in kagome lattices: From an open to a closed kagome structure

    Science.gov (United States)

    Dubowik, J.; Kuświk, P.; Matczak, M.; Bednarski, W.; Stobiecki, F.; Aleshkevych, P.; Szymczak, H.; Kisielewski, M.; Kisielewski, J.

    2016-06-01

    We present ferromagnetic resonance (FMR) investigations of 20 nm thick permalloy (Ni80Fe20 ) elements (width W =200 nm, length L =470 nm, period a =500 nm) arranged in open and closed artificial kagome lattices. The measurements were done at 9.4 and 34 GHz to ensure a saturated or near-saturated magnetic state of the kagome structures. The FMR data are analyzed in the framework of an analytical macrospin model which grasps the essential features of the bulk and edge modes at these microwave frequencies and is in agreement with the results of micromagnetic simulations. Polar plots of the resonance fields versus the field angle made by the direction of the magnetic field with respect to the main symmetry directions of the kagome lattice are compared with the results of the analytical model. The measured FMR spectra with a sixfold rotational symmetry qualitatively reproduce the structure expected from the theory. Magnetic dipolar interactions between the elements of the kagome lattices result in the mixing of edge and bulklike excitations at 9.4 GHz and in a systematic deviation from the model, especially for the closed kagome lattice.

  1. Double-layered target and identification method of individual target correlated with evaporation residues

    Energy Technology Data Exchange (ETDEWEB)

    Kaji, D., E-mail: daiya@riken.jp; Morimoto, K.

    2015-08-21

    A double-layered target system and an identification method (target ID) for individual targets mounted on a rotating wheel using correlation with evaporation residues were newly developed for the study of superheavy elements (SHE). The target system can be used in three modes: conventional single-layered mode, double-layered mode, and energy-degrader mode. The target ID method can be utilized for masking a target, measuring an excitation function without changing the beam energy from the accelerator, and searching for SHE nuclides using multiple targets during a single irradiation.

  2. Impact single versus double layer uterine closure in caesarean section to uterine rupture

    OpenAIRE

    Budi Iman Santoso; Raymond Surya; Rima Irwinda

    2016-01-01

    Caesarean section (CS) is one of the most frequent delivery methods in the world whereas the rates of CS were varied according to developing (from 3.5 to 29.2%) and developed countries (21.1%). The study aims to known the impact of single versus double layer uterine closure to uterine rupture in the history of cesarean section (CS). In this case report, the clinical question is single versus double-layer uterine closure on the previous CS, gives better outcome to reduce the risk of uterine ru...

  3. Influence of window layer thickness on double layer antirefiection coating for triple junction solar cells*

    Institute of Scientific and Technical Information of China (English)

    Wang Lijuan; Zhan Feng; Yu Ying; Zhu Yan; Liu Shaoqing; Huang Shesong; Ni Haiqiao; Niu Zhichuan

    2011-01-01

    The optimization of a SiO2/TiO2, SiO2/ZnS double layer antireflection coating (ARC) on Ga0.5ln0.5P/ln0.02Ga0.98As/Ge solar cells for terrestrial application is discussed. The Al0.5In0.5P window layer thickness is also taken into consideration. It is shown that the optimal parameters of double layer ARC vary with the thickness of the window layer.

  4. Tooth preparation and fabrication of porcelain veneers using a double-layer technique.

    Science.gov (United States)

    Chpindel, P; Cristou, M

    1994-09-01

    This article discusses proper tooth preparation when using the double-layered porcelain technique for constructing porcelain veneers designed to produce strength and translucency. Indications for this technique include color correction, restoration of lost tooth structure or improper tooth size, and overall smile design. A new indication--misalignment--has been added. The objective of this article is to review tooth preparation and double-layered laboratory techniques using hydrothermal ceramics in combination. Four cases are used to illustrate the procedure, concentrating on the correction of misaligned teeth.

  5. Classical topological order in kagome ice

    Energy Technology Data Exchange (ETDEWEB)

    Macdonald, Andrew J; Melko, Roger G [Department of Physics and Astronomy, University of Waterloo, ON, N2L 3G1 (Canada); Holdsworth, Peter C W [Universite de Lyon, Laboratoire de Physique, Ecole Normale Superieure de Lyon, CNRS, 46 Allee d' Italie, 69364 Lyon Cedex 07 (France)

    2011-04-27

    We examine the onset of classical topological order in a nearest neighbour kagome ice model. Using Monte Carlo simulations, we characterize the topological sectors of the ground state using a nonlocal cut measure which circumscribes the toroidal geometry of the simulation cell. We demonstrate that simulations which employ global loop updates that are allowed to wind around the periodic boundaries cause the topological sector to fluctuate, while restricted local loop updates freeze the simulation into one topological sector. The freezing into one topological sector can also be observed in the susceptibility of the real magnetic spin vectors projected onto the kagome plane. The ability of the susceptibility to distinguish between fluctuating and non-fluctuating topological sectors should motivate its use as a local probe of topological order in a variety of related systems.

  6. Localized modes in nonlinear binary kagome ribbons

    OpenAIRE

    Belicev, P. P.; Gligoric, G.; Radosavljevic, A; Maluckov, A.; Stepic, M.; Vicencio, R. A.; Johansson, Magnus

    2015-01-01

    The localized mode propagation in binary nonlinear kagome ribbons is investigated with the premise to ensure controlled light propagation through photonic lattice media. Particularity of the linear system characterized by the dispersionless flat band in the spectrum is the opening of new minigaps due to the "binarism." Together with the presence of nonlinearity, this determines the guiding mode types and properties. Nonlinearity destabilizes the staggered rings found to be nondiffracting in t...

  7. Electric-Field-Induced Superconductivity Detected by Magnetization Measurements of an Electric-Double-Layer Capacitor

    NARCIS (Netherlands)

    Kasahara, Yuichi; Nishijima, Takahiro; Sato, Tatsuya; Takeuchi, Yuki; Ye, Jianting; Yuan, Hongtao; Shimotani, Hidekazu; Iwasa, Yoshihiro

    We report evidence for superconductivity induced by the application of strong electric fields onto the surface of a band insulator, ZrNCl, provided by the observation of a shielding diamagnetic signal. We introduced an electric-double-layer capacitor configuration and in situ magnetization

  8. Vertically aligned carbon nanotubes/diamond double-layered structure for improved field electron emission stability

    Energy Technology Data Exchange (ETDEWEB)

    Yang, L., E-mail: qiaoqin.yang@mail.usask.ca; Yang, Q.; Zhang, C.; Li, Y.S.

    2013-12-31

    A double-layered nanostructure consisting of a layer of vertically aligned Carbon Nanotubes (CNTs) and a layer of diamond beneath has been synthesized on silicon substrate by Hot Filament Chemical Vapor Deposition. The synthesis was achieved by first depositing a layer of diamond on silicon and then depositing a top layer of vertically aligned CNTs by applying a negative bias on the substrate holder. The growth of CNTs was catalyzed by a thin layer of spin-coated iron nitride. The surface morphology and structure of the CNTs/diamond double-layered structure were characterized by Scanning Electron Microscope, Energy Dispersive X-ray spectrum, and Raman Spectroscopy. Their field electron emission (FEE) properties were measured by KEITHLEY 237 high voltage measurement unit, showing much higher FEE current stability than single layered CNTs. - Highlights: • A new double-layered nanostructure consisting of a layer of vertically aligned CNTs and a layer of diamond beneath has been synthesized by hot filament chemical vapor deposition. • This double-layered structure exhibits superior field electron emission stability. • The improvement of emission stability is due to the combination of the unique properties of diamond and CNTs.

  9. Electric double layer transistors with ferroelectric BaTiO3 channels

    NARCIS (Netherlands)

    Ito, M.; Matsubara, Y.; Kozuka, Y.; Takahashi, K. S.; Kagawa, F.; Ye, J. T.; Iwasa, Y.; Ueno, K.; Tokura, Y.; Kawasaki, M.

    2014-01-01

    We report the surface conduction of a BaTiO3 thin film using electric double layer transistor (EDLT) structure. A transistor operation was observed at 220 K with an on/off ratio exceeding 10(5), demonstrating that ionic liquid gating is effective to induce carriers at the surface of ferroelectric ma

  10. Double layered self-expanding metal stents for malignant esophageal obstruction, especially across the gastroesophageal junction

    Institute of Scientific and Technical Information of China (English)

    Min Dae Kim; Su Bum Park; Dae Hwan Kang; Jae Hyung Lee; Cheol Woong Choi; Hyung Wook Kim; Chung Uk Chung

    2012-01-01

    AIM:TO evaluate the clinical outcomes of double-layered self-expanding metal stents (SEMS) for treatment of malignant esophageal obstruction according to whether SEMS crosses the gastroesophageal junction (GEJ).METHODS:Forty eight patients who underwent the SEMS insertion for malignant esophageal obstruction were enrolled.Patients were classified as GEJ group (SEMS across GEHm 18 patients) and non-GEJ group (SEMS above GEJ,30 patients) according to SEMS position.Double layered (outer uncovered and inner covered stent) esophageal stents were placed.RESULTS:The SEMS insertion and the clinical improvement were achieved in all patients in both groups.Stent malfunction occurred in seven patients in the GEJ group and nine patients in the non-GEJ group.Tumor overgrowth occurred in five and eight patients,respectively,food impaction occurred in one patient in each group,and stent migration occurred in one and no patient,respectively.There were no significant differences between the two groups.Reflux esophagitis occurred more frequently in the GEJ group (eight vs five patients,P =0.036) and was controlled by proton pump inhibitor.Aspiration pneumonia occurred in zero and five patients,respectively,and tracheoesophageal fistula occurred in zero and two patients,respectively.CONCLUSION:Double-layered SEMS are a feasible and effective treatment when placed across the GEJ for malignant esophageal obstruction.Double-layered SEMS provide acceptable complications,especially migration,although reflux esophagitis is more common in the GEJ group.

  11. Double layers at amphifunctionally electrified interfaces in the presence of electrolytes containing specifically adsorbing ions

    NARCIS (Netherlands)

    Duval, J.F.L.; Kleijn, J.M.; Lyklema, J.; Leeuwen, van H.P.

    2002-01-01

    Amphifunctional double layers are defined by the coupling of electronic and ionic surface charging processes. They may be present at interfaces of the type metal | oxide layer | solution or semiconducting oxide | solution. In the present paper, the simultaneous effects of charge-determining ions H+/

  12. Internal energy and specific heat in a ferromagnetic-antiferromagnetic double layers

    Institute of Scientific and Technical Information of China (English)

    Jiang Wei; Guo An-Bang

    2007-01-01

    The internal energy and specific heat of a Heisenberg ferro- antiferromagnetic double-layer system are studied by using spin-wave theory and the retarded Green function method at low temperatures. Numerical results show that the antiferromagnetic intralayer coupling J2 has an important influence on internal energy and specific heat for a four-sublattice system with antiferromagnetic (or ferrimagnetic) interlayer couplings.

  13. Small amplitude variable charge dust Bernstein-Greene-Kruskal double layers

    Energy Technology Data Exchange (ETDEWEB)

    Amour, Rabia [Plasma Physics Group, Theoretical Physics Laboratory, Faculty of Sciences - Physics, U.S.T.H.B, Bab-Ezzouar, B.P. 32, El Alia, Algiers 16111 (Algeria); Tribeche, Mouloud [Plasma Physics Group, Theoretical Physics Laboratory, Faculty of Sciences - Physics, U.S.T.H.B, Bab-Ezzouar, B.P. 32, El Alia, Algiers 16111 (Algeria)], E-mail: mouloud-tribeche@lycos.com

    2009-05-11

    A first theoretical attempt is made to investigate small amplitude, variable charge dust Bernstein-Greene-Kruskal (BGK) double layers (DLs). The nature of the dust BGK-DLs (compressive or rarefactive), their strength and thickness depend sensitively on the net negative charge residing on the grain surface, the dust grain dynamics and, more interestingly, on the ion-to-electron temperatures ratio.

  14. Laser cutting silicon-glass double layer wafer with laser induced thermal-crack propagation

    Science.gov (United States)

    Cai, Yecheng; Yang, Lijun; Zhang, Hongzhi; Wang, Yang

    2016-07-01

    This study was aimed at introducing the laser induced thermal-crack propagation (LITP) technology to solve the silicon-glass double layer wafer dicing problems in the packaging procedure of silicon-glass device packaged by WLCSP technology, investigating the feasibility of this idea, and studying the crack propagation process of LITP cutting double layer wafer. In this paper, the physical process of the 1064 nm laser beam interact with the double layer wafer during the cutting process was studied theoretically. A mathematical model consists the volumetric heating source and the surface heating source has been established. The temperature and stress distribution was simulated by using finite element method (FEM) analysis software ABAQUS. The extended finite element method (XFEM) was added to the simulation as the supplementary features to simulate the crack propagation process and the crack propagation profile. The silicon-glass double layer wafer cutting verification experiment under typical parameters was conducted by using the 1064 nm semiconductor laser. The crack propagation profile on the fracture surface was examined by optical microscope and explained from the stress distribution and XFEM status. It was concluded that the quality of the finished fracture surface has been greatly improved, and the experiment results were well supported by the numerical simulation results.

  15. The recording characteristics of particulate double layers with hard-magnetic and soft-magnetic underlayers

    NARCIS (Netherlands)

    Lalbahadoersing, S.; Groenland, J.P.J.; Luitjens, S.B.; Lodder, J.C.

    2002-01-01

    Particulate double-layer tape samples with magnetic underlayers have been investigated by performing magnetic recording measurements and by computer simulation.The presence of soft-magnetic underlayers resulted in decreased signal output and better overwrite behavior. Hard-magnetic underlayers showe

  16. Theoretical analysis and experimental study on the influence of electric double layer on thin film lubrication

    Institute of Scientific and Technical Information of China (English)

    WANG Xin-jie; BAI Shao-xian; HUANG Ping

    2006-01-01

    A new mathematical model for thin film lubrication is established by taking into account the effect of an electric double layer.In the present paper,experiments are carried out on a self-made tester.With a composite block and a rotating disk,influence of electric double layer on thin film lubrication is studied.Two different methods are used to reconstruct the field of electric double layer so as to change its effect.One is to change the ionic concentration of lubricants by adding additives,and the other is to apply an external electric field on friction pairs.According theoretical analysis,both the methods will apparently change the electro-viscosity of the lubricant film so as to change the lubrication performances.After theoretical calculation of electro-viscosity is amended according to the experimental results,the equations of electro-viscosity are presented.The results show that the equivalent viscosity of fluid induced by the effect of electric double layer apparently increases with the decrease of thickness of the film while the lubrication film is thin enough.The effect of electro-viscosity is weakened as the thickness of the film increases.Moreover,the effect of electro-viscosity increases with the increase of external electric field at first.When the voltage reaches a certain value,the electro-viscosity begins to decrease.

  17. Using a double-layered palmaris longus tendon for suspension of facial paralysis

    DEFF Research Database (Denmark)

    Toyserkani, Navid Mohamadpour; Bakholdt, Vivi; Sørensen, Jens Ahm

    2015-01-01

    INTRODUCTION: Facial palsy is a debilitating condition entailing both cosmetic and functional limitations. Static suspension procedures can be performed when more advanced dynamic techniques are not indicated. Since 2006, we have used a double-layered palmaris longus tendon graft through an ovular...

  18. Electric-double-layer potential distribution in multiple-layer immiscible electrolytes

    NARCIS (Netherlands)

    Das, Siddhartha; Hardt, Steffen

    2011-01-01

    In this Brief Report, we calculate the electric-double-layer (EDL) electrostatic potential in a system of several layers of immiscible electrolytes. Verwey-Niessen theory predicts that at the interface between two immiscible electrolytes back-to-back EDLs are formed. The present analysis extends thi

  19. Steric-effect-induced enhancement of electrical-double-layer overlapping phenomena

    NARCIS (Netherlands)

    Das, Siddhartha; Chakraborty, Suman

    2011-01-01

    In this paper, we demonstrate that nontrivial interactions between steric effect and electrical-double-layer (EDL) overlap phenomena may augment the effective extent of EDL overlap in narrow fluidic confinements to a significant extent by virtue of rendering the channel centerline potential tending

  20. Electric-Field-Induced Superconductivity Detected by Magnetization Measurements of an Electric-Double-Layer Capacitor

    NARCIS (Netherlands)

    Kasahara, Yuichi; Nishijima, Takahiro; Sato, Tatsuya; Takeuchi, Yuki; Ye, Jianting; Yuan, Hongtao; Shimotani, Hidekazu; Iwasa, Yoshihiro

    2011-01-01

    We report evidence for superconductivity induced by the application of strong electric fields onto the surface of a band insulator, ZrNCl, provided by the observation of a shielding diamagnetic signal. We introduced an electric-double-layer capacitor configuration and in situ magnetization measureme

  1. Study of the Electrical Double Layer of a Spherical Micelle:Functional Theoretical Approach

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    By using the iterative method in functional theory, an analytic expression of the Poisson-Boltzmann equation (PB eq.), which describes the distribution of the potential of electrical double layer of a spherical micelle, has been carried out under the general potential condition for the first time. The method also can give the radius, the surface potential, and the thickness of the layer.

  2. Electric-Field-Induced Superconductivity Detected by Magnetization Measurements of an Electric-Double-Layer Capacitor

    NARCIS (Netherlands)

    Kasahara, Yuichi; Nishijima, Takahiro; Sato, Tatsuya; Takeuchi, Yuki; Ye, Jianting; Yuan, Hongtao; Shimotani, Hidekazu; Iwasa, Yoshihiro

    2011-01-01

    We report evidence for superconductivity induced by the application of strong electric fields onto the surface of a band insulator, ZrNCl, provided by the observation of a shielding diamagnetic signal. We introduced an electric-double-layer capacitor configuration and in situ magnetization measureme

  3. Expanded graphite—Phenolic resin composites based double layer microwave absorber for X-band applications

    Science.gov (United States)

    Gogoi, Jyoti Prasad; Bhattacharyya, Nidhi Saxena

    2014-11-01

    In this investigation, double layer microwave absorbers are designed and developed with paired combination of 5 wt. %, 7 wt. %, 8 wt. %, and 10 wt. % expanded graphite-novolac phenolic resin (EG-NPR) composites, in the frequency range of 8.2-12.4 GHz. The thickness and compositional combination of the two layers constituting the absorber are optimized to achieve minimum value of reflection loss (dB) and a broad microwave absorption bandwidth. Double layer combinations showing -25 dB absorption bandwidth >2 GHz and -30 dB absorption bandwidth >1 GHz are chosen for fabrication. The total thickness of the fabricated double layer microwave absorber is varied from 3 mm to 3.4 mm. Absorption bandwidths at -10 dB, -20 dB, -25 dB and -30 dB are determined for the fabricated structure. The maximum -25 dB and -30 dB absorption bandwidth of 2.47 GHz and 1.77 GHz, respectively, are observed for the double layer structure with (5 wt. %-8 wt. %) EG-NPR composites with total thickness of 3.2 mm, while -10 dB bandwidth covers the entire X-band range.

  4. Dust acoustic double layers in a magnetized dusty self-gravitating plasma with superthermal particles

    Science.gov (United States)

    Sabetkar, Akbar; Dorranian, Davoud

    2016-08-01

    Our prime objective of this paper is to examine the parametric regimes for the existence and polarity of dust acoustic double layers (DADLs) and its solitary structures arising from a magnetized self-gravitating opposite polarity dust-plasma (OPDP) model. The constituents of the OPDP model are two species of positively and negatively charged dust grains, Maxwellian electrons and kappa distributed ions. Contributions of gravitational force only on dust grains are taken into account. For weakly nonlinear analysis, the multiple time scale technique has been used to construct the extended Korteweg-de Vries (E-KdV) and modified Korteweg-de Vries (M-KdV) equations. They pinpoint the evolution of DADLs and solitary structures associated with dust acoustic (DA) mode, respectively. The relevant configurational parameters in our study include the superthermality of ions (κ), obliqueness of propagation (θ), ion concentration (δi), static magnetic field B0 (via ω c p , ω c n ), and self-gravitational field (via γ), as well as the density (μ0), charge (α), and mass (β) ratio of positive to negative dust species. The proposed OPDP model permits positive and negative double layer polarities, while higher order nonlinear equation dictates us only positive polarity solitary structures. The main modification due to an increase in self-gravitational field (via γ) is an enhancement in the spatial width of double layers, yet leaving their amplitude, phase speed, and polarity practically unaffected. With enhanced superthermality and other intrinsic parameters in OPDP model, there is an opposite trend in both amplitude and width of double layers, while the amplitude and the width of solitary waves (via M-KdV equation) undergo the identical behaviors. In particular, the amplitude of solitary waves manifests monotonic behavior for permissible range of obliqueness θ, whereas this scenario is acceptable to only width of double layers. The results are discussed in the context of

  5. Ion acoustic solitons/double layers in two-ion plasma revisited

    Energy Technology Data Exchange (ETDEWEB)

    Lakhina, G. S., E-mail: gslakhina@gmail.com; Singh, S. V., E-mail: satyavir@iigs.iigm.res.in; Kakad, A. P., E-mail: amar@iigs.iigm.res.in [Indian Institute of Geomagnetism, New Panvel (W), Navi Mumbai 410218 (India)

    2014-06-15

    Ion acoustic solitons and double layers are studied in a collisionless plasma consisting of cold heavier ion species, a warm lighter ion species, and hot electrons having Boltzmann distributions by Sagdeev pseudo-potential technique. In contrast to the previous results, no double layers and super-solitons are found when both the heavy and lighter ion species are treated as cold. Only the positive potential solitons are found in this case. When the thermal effects of the lighter ion species are included, in addition to the usual ion-acoustic solitons occurring at M > 1 (where the Mach number, M, is defined as the ratio of the speed of the solitary wave and the ion-acoustic speed considering temperature of hot electrons and mass of the heavier ion species), slow ion-acoustic solitons/double layers are found to occur at low Mach number (M < 1). The slow ion-acoustic mode is actually a new ion-ion hybrid acoustic mode which disappears when the normalized number density of lighter ion species tends to 1 (i.e., no heavier species). An interesting property of the new slow ion-acoustic mode is that at low number density of the lighter ion species, only negative potential solitons/double layers are found whereas for increasing densities there is a transition first to positive solitons/double layers, and then only positive solitons. The model can be easily applicable to the dusty plasmas having positively charged dust grains by replacing the heavier ion species by the dust mass and doing a simple normalization to take account of the dust charge.

  6. PT-symmetric phase in kagome photonic lattices

    CERN Document Server

    Chern, Gia-Wei

    2015-01-01

    Kagome lattice is a two-dimensional network of corner-sharing triangles and is often associated with geometrical frustration. In particular, the frustrated coupling between waveguide modes in a kagome array leads to a dispersionless flat band consisting of spatially localized modes. Here we propose a complex photonic lattice by placing $\\mathcal{PT}$-symmetric dimers at the kagome lattice points. Each dimer corresponds to a pair of strongly coupled waveguides. With balanced arrangement of gain and loss on individual dimers, the system exhibits a $\\mathcal{PT}$-symmetric phase for finite gain/loss parameter up to a critical value. The beam evolution in this complex kagome waveguide array exhibits a novel oscillatory rotation of optical power along the propagation distance. Long-lived local chiral structures originating from the nearly flat bands of the kagome structure are observed when the lattice is subject to a narrow beam excitation.

  7. PT-symmetric phase in kagome-based photonic lattices.

    Science.gov (United States)

    Chern, Gia-Wei; Saxena, Avadh

    2015-12-15

    The kagome lattice is a two-dimensional network of corner-sharing triangles and is often associated with geometrical frustration. In particular, the frustrated coupling between waveguide modes in a kagome array leads to a dispersionless flat band consisting of spatially localized modes. Here we propose a complex photonic lattice by placing PT-symmetric dimers at the kagome lattice points. Each dimer corresponds to a pair of strongly coupled waveguides. With balanced arrangement of gain and loss on individual dimers, the system exhibits a PT-symmetric phase for finite gain/loss parameter up to a critical value. The beam evolution in this complex kagome waveguide array exhibits a novel oscillatory rotation of optical power along the propagation distance. Long-lived local chiral structures originating from the nearly flat bands of the kagome structure are observed when the lattice is subject to a narrow beam excitation.

  8. Application of double-layered skin phantoms for optical flow imaging during laser tattoo treatments

    Science.gov (United States)

    Lee, Byeong-il; Song, Woosub; Kim, Hyejin; Kang, Hyun Wook

    2016-05-01

    The feasible application of double-layered skin phantoms was evaluated to identify artificial blood flow with a Doppler optical coherence tomography (DOCT) system for laser tattoo treatments. Polydimethylsiloxane (PDMS) was used to fabricate the artificial phantoms with flow channels embedded. A double-integrating sphere system with an inverse adding-doubling method quantified both the absorption and the reduced scattering coefficients for epidermis and dermis phantoms. Both OCT and caliper measurements confirmed the double-layered phantom structure (epidermis = 136 ± 17 µm vs. dermis = 3.0 ± 0.1 mm). The DOCT method demonstrated that high flow rates were associated with high image contrast, visualizing the position and the shape of the flow channel. Application of the channel-embedded skin phantoms in conjunction with DOCT can be a reliable technique to assess dynamic variations in the blood flow during and after laser tattoo treatments.

  9. Dust-ion-acoustic Gardner double layers in a dusty plasma with two-temperature electrons

    Indian Academy of Sciences (India)

    M M Masud; I Tasnim; A A Mamun

    2015-01-01

    The properties of dust-ion-acoustic Gardner double layers (DIA GDLs) in an unmagnetized dusty plasma, whose constituents are negatively-charged stationary dust, inertial ions, and Boltzmann electrons of two distinct temperatures, are rigorously investigated by employing the reductive perturbation method: Gardner approach. The standard Gardner equation is derived, and its double layer (DL) solution is obtained. It has been shown that the properties of the DIA GDLs are significantly modified by some plasma parameters (viz. = e1/e2, e1 = e10/i0, and e2 = e20/i0, where e1 (e2) is the cold (hot) electron temperature, e10 (e20) is the cold (hot) electron number density at equilibrium, and i0 is the ion number density at equilibrium). The implications of our investigation in understanding the basic features of nonlinear electrostatic perturbations observed in many space plasma systems and laboratory devices are briefly discussed.

  10. Resistivity due to weak double layers - A model for auroral arc thickness

    Science.gov (United States)

    Prakash, Manju; Lysak, Robert L.

    1992-01-01

    We have calculated the resistivity due to a sequence of fluctuating weak double layers aligned parallel to the ambient magnetic field line. The average response of an electron drifting through a 1D randomly oriented array of WDLs is studied using a test particle approach. The average is taken over the randomly fluctuating values of the electric field associated with the double layers. Based on our calculations, we estimate that a 350 eV electron energy the thickness of the visual auroral arc is about 2.5 km and that of the auroral fine structure as about 250 m when mapped down to the ionosphere. The significance of our calculations is discussed in the context of magnetosphere-ionosphere coupling.

  11. Double-layered ZnO nanostructures for efficient perovskite solar cells

    KAUST Repository

    Mahmood, Khalid

    2014-01-01

    To date, a single layer of TiO2 or ZnO has been the most successful implementations of any electron transport layer (ETL) in solution-processed perovskite solar cells. In a quest to improve the ETL, we explore a new nanostructured double-layer ZnO film for mesoscopic perovskite-based thin film photovoltaics. This approach yields a maximum power conversion efficiency of 10.35%, which we attribute to the morphology of oxide layer and to faster electron transport. The successful implementation of the low-temperature hydrothermally processed double-layer ZnO film as ETL in perovskite solar cells highlights the opportunities to further improve the efficiencies by focusing on the ETL in this rapidly developing field. This journal is

  12. Four-Electron Systems in a Coupled Double-Layer Quantum Dots

    Institute of Scientific and Technical Information of China (English)

    XIE Wen-Fang

    2003-01-01

    Making use of the method of few-body physics, the energy spectrum of a four-electron system consisting in a vertically coupled double-layer quantum dot as a function of the strength ofa magnetic field is investigated. Discontinuous ground-state transitions induced by an external magnetic field are shown. We find that, in the strong coupling case, the ground-state transitions depend not only on the external magnetic field B but also on the distance d between double-layer quantum dots. However, in the case of weak coupling, the ground-state transitions occur in the new sequence of the values of the magic angular momentum. Hence, the interlayer separation d and electron-electron interaction strongly affect the ground state of the coupled quantum dots.

  13. Controlling spin-orbit interaction in a ferromagnetic Fe/Au double layer

    Science.gov (United States)

    Samarin, Sergey N.; Artamonov, Oleg M.; Baraban, Alexander P.; Kostylev, Mikhail; Guagliardo, Paul; Williams, James F.

    2015-01-01

    Using spin-polarized single- and two-electron spectroscopy, we probe exchange and spin-orbit interaction in a double layer of Fe and Au on W(110) and measure the spin asymmetry of the Bloch spectral density function of the sample. In a 5 ML iron film, the spin-orbit contribution to the measured asymmetry of the (e,2e) spectra was not detectable, whereas a deposition of about 1 ML of gold introduced a substantial spin-orbit component in the measured asymmetry. At the same time, this double layer still exhibits ferromagnetic properties: (i) the spectral density function asymmetry demonstrate imbalance of spin-up and spin-down electron densities in the valence band and (ii) the Stoner excitation asymmetry has almost the same value as in a pure Fe film.

  14. First steps towards the realization of a double layer perceptron based on organic memristive devices

    Directory of Open Access Journals (Sweden)

    A. V. Emelyanov

    2016-11-01

    Full Text Available Memristors are widely considered as promising elements for the efficient implementation of synaptic weights in artificial neural networks (ANNs since they are resistors that keep memory of their previous conductive state. Whereas demonstrations of simple neural networks (e.g., a single-layer perceptron based on memristors already exist, the implementation of more complicated networks is more challenging and has yet to be reported. In this study, we demonstrate linearly nonseparable combinational logic classification (XOR logic task using a network implemented with CMOS-based neurons and organic memrisitive devices that constitutes the first step toward the realization of a double layer perceptron. We also show numerically the ability of such network to solve a principally analogue task which cannot be realized by digital devices. The obtained results prove the possibility to create a multilayer ANN based on memristive devices that paves the way for designing a more complex network such as the double layer perceptron.

  15. Controlling spin–orbit interaction in a ferromagnetic Fe/Au double layer

    Energy Technology Data Exchange (ETDEWEB)

    Samarin, Sergey N.; Kostylev, Mikhail; Williams, James F. [School of Physics, The University of Western Australia, Perth, Western Australia 6009 (Australia); Artamonov, Oleg M.; Baraban, Alexander P. [Research Institute of Physics, St. Petersburg State University, St. Petersburg 199034 (Russian Federation); Guagliardo, Paul [Centre for Microscopy, Characterisation and Analysis, the University of Western Australia, Perth, Western Australia 6009 (Australia)

    2015-01-26

    Using spin-polarized single- and two-electron spectroscopy, we probe exchange and spin–orbit interaction in a double layer of Fe and Au on W(110) and measure the spin asymmetry of the Bloch spectral density function of the sample. In a 5 ML iron film, the spin-orbit contribution to the measured asymmetry of the (e,2e) spectra was not detectable, whereas a deposition of about 1 ML of gold introduced a substantial spin-orbit component in the measured asymmetry. At the same time, this double layer still exhibits ferromagnetic properties: (i) the spectral density function asymmetry demonstrate imbalance of spin-up and spin-down electron densities in the valence band and (ii) the Stoner excitation asymmetry has almost the same value as in a pure Fe film.

  16. A novel controllable double-layer magnetic lattice with cold atoms

    Institute of Scientific and Technical Information of China (English)

    Min Yun; Jianping Yin

    2005-01-01

    We propose a novel array of controllable double-well magnetic microtraps for cold atoms by using an array of square current-carrying wires and two additional bias magnetic fields. Arrays of double layer magnetooptical traps (MOTs) and Ioffe traps can be constructed by using same wire configurations and different currents and bias fields. Furthermore, the array of double-well magnetic microtraps can be continuously evolved as an array of single-well magnetic microtraps by reducing the currents in the wires. Our study shows that our scheme can be used to realize a controllable double-layer magnetic lattice with cold atoms, to form array of Bose-Einstein condensations (BECs), or to study atom interference, and so on.

  17. Acoustic radiation force on a double-layer microsphere by a Gaussian focused beam

    Energy Technology Data Exchange (ETDEWEB)

    Wu, Rongrong; Cheng, Kaixuan; Liu, Jiehui; Mao, Yiwei; Gong, Xiufen [Key Laboratory of Modern Acoustics, Institute of Acoustics, Nanjing University, Nanjing 210093 (China); Liu, Xiaozhou, E-mail: xzliu@nju.edu.cn [Key Laboratory of Modern Acoustics, Institute of Acoustics, Nanjing University, Nanjing 210093 (China); State Key Laboratory of Acoustics, Institute of Acoustics, Chinese Academy of Sciences, Beijing 100190 (China)

    2014-10-14

    A new model for calculating the radiation force on double-layer microsphere is proposed based on the ray acoustics approach. The axial acoustic radiation force resulting from a focused Gaussian beam incident on spherical shells immersed in water is examined theoretically in relation to its thickness and the contents of its double-layer. The attenuation both in the water and inside the sphere is considered in this method, which cannot be ignored while the high frequency ultrasonic is used. Results of numerical calculations are presented for fat and low density polyethylene materials, with the hollow region filled with animal oil, water, or air. These results show how the acoustic impedance and the sound velocity of both layers, together with the thickness of the shell, affect the acoustic radiation force.

  18. Influence of electric double layer on thin film lubrication and elastohydrodynamic lubrication

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    In the present paper, the influence of electric double layer (EDL) on thin film lubricationand elastohydrodynamic lubrication is studied. With modified Reynolds equation for electric doublelayer, the effect of zeta-potential on the film thickness and pressure is numerically calculated. Theresults show that the influence of electric double layer on the lubrication film thickness is significantonly for thin film. The minimum film thickness will increase greatly if the influence of EDL is con-sidered. As the initial film thickness increases, the effect will greatly decrease. The existence ofEDL will decrease the friction coefficient of the lubrication film. Furthermore, the above tendency isstill applicable even if the materials of the friction pair are different.

  19. Spatially Resolved Measurements of a Double Layer in an Argon Helicon Plasma

    Science.gov (United States)

    Aguirre, Evan; Siddiqui, Umair; McKee, John; Scime, Earl

    2015-11-01

    We report 2-dimensional, spatially resolved observations of a double layer in an expanding helicon plasma. These new measurements investigate the origins of previously observed multiple ion beam populations in the downstream plasma. We use Laser Induced Fluorescence (LIF) to measure the ion velocity distribution functions (IVDFs) of argon ions and neutrals both parallel and perpendicular to the background magnetic field and an rf-compensated Langmuir probe to determine the local plasma potential. These are the first multi-dimensional LIF measurements of ion acceleration in a current-free double layer and were obtained with a recently installed, internal scanning probe system in the HELIX-LEIA experimental facility. This work is supported by US National Science Foundation grant number PHY-1360278.

  20. First steps towards the realization of a double layer perceptron based on organic memristive devices

    Science.gov (United States)

    Emelyanov, A. V.; Lapkin, D. A.; Demin, V. A.; Erokhin, V. V.; Battistoni, S.; Baldi, G.; Dimonte, A.; Korovin, A. N.; Iannotta, S.; Kashkarov, P. K.; Kovalchuk, M. V.

    2016-11-01

    Memristors are widely considered as promising elements for the efficient implementation of synaptic weights in artificial neural networks (ANNs) since they are resistors that keep memory of their previous conductive state. Whereas demonstrations of simple neural networks (e.g., a single-layer perceptron) based on memristors already exist, the implementation of more complicated networks is more challenging and has yet to be reported. In this study, we demonstrate linearly nonseparable combinational logic classification (XOR logic task) using a network implemented with CMOS-based neurons and organic memrisitive devices that constitutes the first step toward the realization of a double layer perceptron. We also show numerically the ability of such network to solve a principally analogue task which cannot be realized by digital devices. The obtained results prove the possibility to create a multilayer ANN based on memristive devices that paves the way for designing a more complex network such as the double layer perceptron.

  1. Thermal analysis of double-layer metal films during femtosecond laser heating

    Science.gov (United States)

    Chen, A. M.; Jiang, Y. F.; Sui, L. Z.; Liu, H.; Jin, M. X.; Ding, D. J.

    2011-05-01

    In this paper, the primary interest is the heat effect of the bottom-layer metal on the temperature distribution of the top-layer metal in a double-layer metal structure during femtosecond laser irradiation. The evolution of the surface electron and lattice temperature depends a lot on the thermal parameters of the substrate. The damage threshold can be increased by using a substrate material with high electron-lattice coupling factor. Next, we choose chrome as the bottom-layer material. The results of modeling show that the surface lattice temperature of top-layer gold can be reduced remarkably. For a fixed entire thickness of the double-layer film, there is an optimal proportion of top and bottom layers for which the damage threshold is the highest possible. Also, for increasing the damage threshold, a substrate with higher melting temperature should be chosen.

  2. A new double layer epoxy coating for corrosion protection of Petroleum Equipments

    Directory of Open Access Journals (Sweden)

    Maher A. El Sockarya

    2014-11-01

    Full Text Available Homogeneous epoxy coating containing polymer nanocomposite (PNC was successfully synthesized and applied on carbon steel substrates by room temperature curing of fully mixed epoxy slurry. (PNC containing both ZNO nanoparticles and epoxy hyper branched polymer (EHBP, a new double layer thin film which comprises ZNO-epoxy as a primer coat and ZNO-EHBP-epoxy as a top coat offers better corrosion protection compared to the purely inorganic ZNO-epoxy coating and hybrid ZNO-EHBP-epoxy coating. Chemical structures of synthesized compounds were confirmed by FTIR, H1NMR spectroscopy and GPC. The surface morphology and phase structure of the produced Zno nanoparticles were characterized by scanning electron microscopy SEM, transmission electron microscopy TEM and X-ray diffraction. Chemical resistance of theses coatings to NaOH and HCL was investigated. The effect of incorporating polymer nanocomposite and new double layer coating on corrosion resistance of epoxy coated steel was investigated by salt spray test.

  3. Multianalyte electrochemical biosensor on a monolith electrode by optically scanning the electrical double layer.

    Science.gov (United States)

    Lee, Seung-Woo; Saraf, Ravi F

    2014-07-15

    Redox on an electrode is an interfacial phenomenon that modulates the charge in the electrical double layer (EDL). A novel instrument, the Scanning Electrometer for Electrical Double-layer (SEED) has been developed to measure multiple enzyme reactions on a monolith electrode due to immunospecific binding with a mixture of respective analytes. SEED quantitatively maps the local redox reaction by scanning a laser on the array of enzyme monolayer spots immobilized on the monolith electrode. SEED measures the change in local charge state of the EDL that abruptly changes due to the redox reaction. The measurement spot size defined by the size of the laser beam is ~10 µm. The SEED signal is linearly proportional to the local redox current density and analyte concentration. The specificity is close to 100%. The SEED readout is compatible with microfluidics platform where the signal degrades less than 2% due to the poly(dimethyl siloxane) (PDMS) body.

  4. Surface deformation and geoid anomalies over single and double-layered convective systems

    Science.gov (United States)

    Koch, M.; Yuen, D. A.

    1985-01-01

    Using a primitive variable formulation of the finite-element method, the differences in the surface observables, such as topography and geoid, produced by single- and double-layered thermal convection, were compared. Both constant and depth-dependent viscosities have been considered. For the same Rayleigh number, larger surface perturbations are produced by single-cell convection. For the same Nusselt number, the magnitudes of the surface observables are greater for double-layered convection. For the same surface heat-flux, surface topographies have similar magnitudes, but the relative amplitudes of geoid anomalies depend greatly on the style of viscosity stratification. This difference in the geoid between the two systems increases with greater surface heat-flow, regardless of viscosity structure.

  5. Magnetic Properties of Ferromagnetic Double Layers with Ferrimagnetic Interlayer Coupling at Zero Temperature

    Institute of Scientific and Technical Information of China (English)

    JIANG Wei; ZHU Cheng-Bo; WANG Wei; ZHANG Fan

    2009-01-01

    Spin-wave theory is used to study magnetic properties of ferromagnetic double layers with a ferrimagnetic interlayer coupling at zero temperature.The spin-wave spectra and four sublattices magnetizations and internal energy are calculated by employing retarded Green function technique.The sublattice magnetizations at ground state are smaller than their classical values, owing to the zero-point quantum fluctuations of the spins.

  6. Bias-dependent molecular-level structure of electrical double layer in ionic liquid on graphite.

    Science.gov (United States)

    Black, Jennifer M; Walters, Deron; Labuda, Aleksander; Feng, Guang; Hillesheim, Patrick C; Dai, Sheng; Cummings, Peter T; Kalinin, Sergei V; Proksch, Roger; Balke, Nina

    2013-01-01

    Here we report the bias-evolution of the electrical double layer structure of an ionic liquid on highly ordered pyrolytic graphite measured by atomic force microscopy. We observe reconfiguration under applied bias and the orientational transitions in the Stern layer. The synergy between molecular dynamics simulation and experiment provides a comprehensive picture of structural phenomena and long and short-range interactions, which improves our understanding of the mechanism of charge storage on a molecular level.

  7. Effects of binders on the performance of electric double-layer capacitors of carbon nanotube electrodes

    Institute of Scientific and Technical Information of China (English)

    LI Chensha; WANG Dazhi; ZHANG Baoyou; WANG Xiaofeng; CAO Maosheng; LIANG Ji

    2005-01-01

    Polarizable electrodes of electric double layer capacitor (EDLCs) were made from carhon nanotubes. Effects of different binders, which are phenolic resin (PF) and polytetrafluoroethylene (PTFE), on the properties of polarizable electrodes are studied. Results indicate that the microstructure, pore size distribution and specific capacitance of the electrodes with PTFE binder are superior to those electrodes with PF binder after carbonization. The suitable binder (PTFE) for carbon nanotubes electrodes is proposed.

  8. Double-layer-gate architecture for few-hole GaAs quantum dots

    Science.gov (United States)

    Wang, D. Q.; Hamilton, A. R.; Farrer, I.; Ritchie, D. A.; Klochan, O.

    2016-08-01

    We report the fabrication of single and double hole quantum dots using a double-layer-gate design on an undoped accumulation mode {{Al}}x{{Ga}}1-x{As}/GaAs heterostructure. Electrical transport measurements of a single quantum dot show varying addition energies and clear excited states. In addition, the two-level-gate architecture can also be configured into a double quantum dot with tunable inter-dot coupling.

  9. Quantum Size Effects on Two Electrons and Two Holes in Double-Layer Quantum Dots

    Institute of Scientific and Technical Information of China (English)

    XIE Wen-Fang; ZHU Wu

    2002-01-01

    We propose a procedure to solve exactly the Schrodinger equation for a system of two electrons and two holes in a double-layer quantum dot by using the method of few-body physics. The features of the low-lying spectra have been deduced based on symmetry. The binding energies of the ground state are obtained as a function of the electron-to-hole mass ratio σ for a few values of the quantum dot size.

  10. Oxidation behavior of CNTs and the electric double layer capacitor made of the CNT electrodes

    Institute of Scientific and Technical Information of China (English)

    李辰砂; 王大志; 梁彤祥; 李贵涛; 王晓峰; 曹茂盛; 梁吉

    2003-01-01

    The effect of CO2 oxidized carbon nanotubes (CNTs) on the performance of electric double layer capacitors (EDLCs) was studied. CO2 oxidation increased the specific area and improved the dispersity of CNTs. Specific capacitance of the polarizable electrodes in EDLCs based on the oxidized CNTs were obviously improved and the maximum specific capacitance of 47 F/g was obtained. CO2 oxidizing CNTs is hence an effective way to improve the performances of EDLCs based on the CNT electrodes.

  11. Novel electric double-layer capacitor with a coaxial fiber structure.

    Science.gov (United States)

    Chen, Xuli; Qiu, Longbin; Ren, Jing; Guan, Guozhen; Lin, Huijuan; Zhang, Zhitao; Chen, Peining; Wang, Yonggang; Peng, Huisheng

    2013-11-26

    A coaxial electric double-layer capacitor fiber is developed from the aligned carbon nanotube fiber and sheet, which functions as two electrodes with a polymer gel sandwiched between them. The unique coaxial structure enables a rapid transportation of ions between the two electrodes with a high electrochemical performance. These energy storage fibers are also flexible and stretchable, and can be woven into and widely used for electronic textiles.

  12. Ion-acoustic solitons, double layers and rogue waves in plasma having superthermal electrons

    Science.gov (United States)

    Singh Saini, Nareshpal

    2016-07-01

    Most of the space and astrophysical plasmas contain different type of charged particles with non-Maxwellian velocity distributions (e.g., nonthermal, superthermal, Tsallis ). These distributions are commonly found in the auroral region of the Earth's magnetosphere, planetary magnetosphere, solar and stellar coronas, solar wind, etc. The observations from various satellite missions have confirmed the presence of superthermal particles in space and astrophysical environments. Over the last many years, there have been a much interest in studying the different kind of properties of the electrostatic nonlinear excitations (solitons, double layers, rogue waves etc.) in a multi-component plasmas in the presence of superthermal particles. It has been analyzed that superthermal distributions are more appropriate than Maxwellian distribution for the modeling of space data. It is interesting to study the dynamics of various kinds of solitary waves, Double layers, Shocks etc. in varieties of plasma systems containing different kind of species obeying Lorentzian (kappa-type)/Tsallis distribution. In this talk, I have focused on the study of large amplitude IA solitary structures (bipolar solitary structures, double layers etc.), modulational instability and rogue waves in multicomponent plasmas. The Sagdeev potential method has been employed to setup an energy balance equation, from which we have studied the characteristics of large amplitude solitary waves under the influence of superthermality of charged particles and other plasma parameters. The critical Mach number has been determined, above which solitary structures are observed and its variation with superthermality of electrons and other parameters has also been discussed. Double layers have also been discussed. Multiple scale reductive perturbation method has been employed to derive NLS equation. From the different kind of solutions of this equation, amplitude modulation of envelope solitons and rogue waves have been

  13. Formating double layer mechanism by electric charged particle stream in plasma

    Science.gov (United States)

    Shan-jun, Ma; Qian-li, Yang; Xiao-qing, Li

    1998-08-01

    In this paper, two-fluid equations have been solved after having considered magnetic field generated by charged particle stream. Finally, the distribution of electric field Ez(z, r) and its growth rate γ in plasma have been obtained. From the expression of Ez(z, r) it can be known that the double layer has been formed. With the increase of disturbance γ will be larger, and finally this will result in the interruption of electric current and occurrence of burst.

  14. Study on the Manufacturability Evaluation Based on Double-layer Model of Manufacturing Resources

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    Virtual organization is a new production patter and a principal part in advanced manufacturing systems such as agile manufacturing. Manufacturability evaluation is the necessary condition to form the virtual organization. A new manufacturability evaluation approach is described in this paper, which is carried out based on every process feature under the double-layer model of manufacturing resources proposed by authors. The manufacturing resources that build up the virtual organization are selected according to the results of manufacturability evaluation.

  15. Ionic Liquids as Electrolytes for Electrochemical Double-Layer Capacitors: Structures that Optimize Specific Energy.

    Science.gov (United States)

    Mousavi, Maral P S; Wilson, Benjamin E; Kashefolgheta, Sadra; Anderson, Evan L; He, Siyao; Bühlmann, Philippe; Stein, Andreas

    2016-02-10

    Key parameters that influence the specific energy of electrochemical double-layer capacitors (EDLCs) are the double-layer capacitance and the operating potential of the cell. The operating potential of the cell is generally limited by the electrochemical window of the electrolyte solution, that is, the range of applied voltages within which the electrolyte or solvent is not reduced or oxidized. Ionic liquids are of interest as electrolytes for EDLCs because they offer relatively wide potential windows. Here, we provide a systematic study of the influence of the physical properties of ionic liquid electrolytes on the electrochemical stability and electrochemical performance (double-layer capacitance, specific energy) of EDLCs that employ a mesoporous carbon model electrode with uniform, highly interconnected mesopores (3DOm carbon). Several ionic liquids with structurally diverse anions (tetrafluoroborate, trifluoromethanesulfonate, trifluoromethanesulfonimide) and cations (imidazolium, ammonium, pyridinium, piperidinium, and pyrrolidinium) were investigated. We show that the cation size has a significant effect on the electrolyte viscosity and conductivity, as well as the capacitance of EDLCs. Imidazolium- and pyridinium-based ionic liquids provide the highest cell capacitance, and ammonium-based ionic liquids offer potential windows much larger than imidazolium and pyridinium ionic liquids. Increasing the chain length of the alkyl substituents in 1-alkyl-3-methylimidazolium trifluoromethanesulfonimide does not widen the potential window of the ionic liquid. We identified the ionic liquids that maximize the specific energies of EDLCs through the combined effects of their potential windows and the double-layer capacitance. The highest specific energies are obtained with ionic liquid electrolytes that possess moderate electrochemical stability, small ionic volumes, low viscosity, and hence high conductivity, the best performing ionic liquid tested being 1-ethyl-3

  16. Localized modes in nonlinear photonic kagome nanoribbons

    Energy Technology Data Exchange (ETDEWEB)

    Molina, Mario I., E-mail: mmolina@uchile.cl [Departamento de Física, MSI – Nucleus for Advanced Optics, and Center for Optics and Photonics (CEFOP), Facultad de Ciencias, Universidad de Chile, Santiago (Chile)

    2012-10-01

    We examine localization of light in nonlinear (Kerr) kagome lattices in the shape of narrow strips of varying width. For the narrowest ribbon, the band structure features a flat band leading to linear dynamical trapping of an initially localized excitation. We also find a geometry-induced bistability of the nonlinear modes as the width of the strip is changed. A crossover from one to two dimensions localization behavior is observed as the width is increased, attaining two-dimensional behavior for relatively narrow ribbons.

  17. Asymptotic theory of double layer and shielding of electric field at the edge of illuminated plasma

    Energy Technology Data Exchange (ETDEWEB)

    Benilov, M. S. [Departamento de Física, CCCEE, Universidade da Madeira, Largo do Município, 9000 Funchal (Portugal); Thomas, D. M. [Blackett Laboratory, Imperial College London, Prince Consort Road, London SW7 2BW (United Kingdom)

    2014-04-15

    The method of matched asymptotic expansions is applied to the problem of a collisionless plasma generated by UV illumination localized in a central part of the plasma in the limiting case of small Debye length λ{sub D}. A second-approximation asymptotic solution is found for the double layer positioned at the boundary of the illuminated region and for the un-illuminated plasma for the plane geometry. Numerical calculations for different values of λ{sub D} are reported and found to confirm the asymptotic results. The net integral space charge of the double layer is asymptotically small, although in the plane geometry it is just sufficient to shield the ambipolar electric field existing in the illuminated region and thus to prevent it from penetrating into the un-illuminated region. The double layer has the same mathematical nature as the intermediate transition layer separating an active plasma and a collisionless sheath, and the underlying physics is also the same. In essence, the two layers represent the same physical object: a transonic layer.

  18. Pore Pressure Response to Groundwater Fluctuations in Saturated Double-Layered Soil

    Directory of Open Access Journals (Sweden)

    Hongwei Ying

    2015-01-01

    Full Text Available Analytical solutions are developed for one-dimensional consolidation of double-layered saturated soil subjected to groundwater fluctuations. The solutions are derived by an explicit mathematical procedure using Duhamel’s theorem in conjunction with a Fourier series, when groundwater fluctuation is described by a general time-dependent function and assumed to be the pore water pressure variations at the upper boundary. Taking as an example the harmonic groundwater fluctuation, the relevant response of the excess pore water pressure is discussed in detail, and the main influencing factors of the excess pore pressure distribution are analyzed. A dimensionless parameter θ has been introduced because it significantly affects the phase and the amplitude of excess pore pressures. The influences of the coefficients of permeability and compressibility of soil on the excess pore pressure distribution are different and cannot be incorporated into the coefficient of consolidation in double-layered soil. The relative permeability ratio of two clayey soils also plays an important role on the curves of the distributions of the excess pore pressures. The effects of the thickness of the soil layer on the excess pore pressure distribution should be considered together with the dimensionless parameter θ and the permeability and compressibility of the double-layered soil system.

  19. The electric double layer at a metal electrode in pure water

    Science.gov (United States)

    Brüesch, Peter; Christen, Thomas

    2004-03-01

    Pure water is a weak electrolyte that dissociates into hydronium ions and hydroxide ions. In contact with a charged electrode a double layer forms for which neither experimental nor theoretical studies exist, in contrast to electrolytes containing extrinsic ions like acids, bases, and solute salts. Starting from a self-consistent solution of the one-dimensional modified Poisson-Boltzmann equation, which takes into account activity coefficients of point-like ions, we explore the properties of the electric double layer by successive incorporation of various correction terms like finite ion size, polarization, image charge, and field dissociation. We also discuss the effect of the usual approximation of an average potential as required for the one-dimensional Poisson-Boltzmann equation, and conclude that the one-dimensional approximation underestimates the ion density. We calculate the electric potential, the ion distributions, the pH-values, the ion-size corrected activity coefficients, and the dissociation constants close to the electric double layer and compare the results for the various model corrections.

  20. Effects of fabricated error on transmission performance of double layer frequency selective surface configuration

    Institute of Scientific and Technical Information of China (English)

    HE Bin; SUN Lian-chun

    2005-01-01

    Based on the experimental results, in which the fabricated error of the double layer frequency selective surface (FSS) leads to the transmission loss and the resonant frequency leaves away the design resonant frequency, the inter-layer separation distance (ISD) and the unit cell aligning error (UAE) were used as main variables to study the transmission performance attenuation of the double layer FSS configuration. The numerical analysis model for ISD and UAE was established and also was used to simulate the ring unit cell FSS transmission performance by the finite element and periodic moment methods. The double layer ring aperture FSS configuration designed was used as the numerical model. As a result of the numerical analysis, it is shown that both ISD and UAE produce insertion transmission loss (ITL) and insertion phase distortion (IPD) directly. Furthermore, ISD results in more loss of the amplitude of the transmitted signal for the FSS than UAE. It is significant for the designer of the multiplayer FSS to assign the fabricated error of the FSS dielectric layers. The UAE introduces the insertion phase variation badly.

  1. Magnetohydrodynamic effects on a charged colloidal sphere with arbitrary double-layer thickness.

    Science.gov (United States)

    Hsieh, Tzu H; Keh, Huan J

    2010-10-01

    An analytical study is presented for the magnetohydrodynamic (MHD) effects on a translating and rotating colloidal sphere in an arbitrary electrolyte solution prescribed with a general flow field and a uniform magnetic field at a steady state. The electric double layer surrounding the charged particle may have an arbitrary thickness relative to the particle radius. Through the use of a simple perturbation method, the Stokes equations modified with an electric force term, including the Lorentz force contribution, are dealt by using a generalized reciprocal theorem. Using the equilibrium double-layer potential distribution from solving the linearized Poisson-Boltzmann equation, we obtain closed-form formulas for the translational and angular velocities of the spherical particle induced by the MHD effects to the leading order. It is found that the MHD effects on the particle movement associated with the translation and rotation of the particle and the ambient fluid are monotonically increasing functions of κa, where κ is the Debye screening parameter and a is the particle radius. Any pure rotational Stokes flow of the electrolyte solution in the presence of the magnetic field exerts no MHD effect on the particle directly in the case of a very thick double layer (κa→0). The MHD effect caused by the pure straining flow of the electrolyte solution can drive the particle to rotate, but it makes no contribution to the translation of the particle.

  2. Interaction between electrical double layers of soil colloids and Fe/Al oxides in suspensions.

    Science.gov (United States)

    Hou, Tao; Xu, Renkou; Tiwari, Diwakar; Zhao, Anzhen

    2007-06-15

    Phyllosilicates with net negative surface charge and Fe/Al oxides with net positive surface charge coexist in variable-charge soils, and the interaction between these oppositely charged particles affects the stability of mixed colloids, aggregation, and even the surface chemical properties of variable-charge soils. The interaction of the diffuse layers of electrical double layers between the negatively charged soil colloidal particles and the positively charged particles of goethite or gamma-Al(2)O(3) was investigated in this article through the comparison of zeta potentials between single-soil colloidal systems and binary systems containing soil colloids and Fe/Al oxides. The results showed that the presence of goethite and gamma-Al(2)O(3) increased the zeta potential of the binary system containing soil colloids and Fe/Al oxides, which clearly suggests the overlapping of the diffuse layers in soil colloids and Fe/Al oxides. The overlapping of the diffuse layers leads to a decrease in the effective negative charge density on soil colloid and thus causes a shift of pH-zeta potential curves toward the more positive-value side. The interaction of the electrical double layers is also related to the charge characteristics on the Fe/Al oxides: the higher the positive charge density on Fe/Al oxides, the stronger the interaction of the electrical double layers between the soil colloid particles and the Fe/Al oxides.

  3. Impact single versus double layer uterine closure in caesarean section to uterine rupture

    Directory of Open Access Journals (Sweden)

    Budi Iman Santoso

    2016-07-01

    Full Text Available Caesarean section (CS is one of the most frequent delivery methods in the world whereas the rates of CS were varied according to developing (from 3.5 to 29.2% and developed countries (21.1%. The study aims to known the impact of single versus double layer uterine closure to uterine rupture in the history of cesarean section (CS. In this case report, the clinical question is single versus double-layer uterine closure on the previous CS, gives better outcome to reduce the risk of uterine rupture. To answer this question, we search the evidence from Pub Med and Cochrane database with the keywords: and ldquo;cesarean section" and "uterine rupture" and and ldquo;uterine closure and rdquo;. The inclusion criteria are written in English and focused comparing single and double layer uterine closure to uterine rupture in the previous CS. From the searching literature, we found 3 systematic reviews and 23 articles which were relevant to the topic. After screening the abstract and language, we got 2 systematic reviews and 4 articles. At the end, only 4 articles consisting of 1 systematic review and 3 articles were included to be appraised. Based on evidences, single layer uterine closure did not increase the risk of uterine rupture. Apart from that, shorter operative times and lower estimated blood loss became the superiority of single-layer uterine closure. [Int J Reprod Contracept Obstet Gynecol 2016; 5(7.000: 2074-2078

  4. Hierarchical Supervisor and Agent Routing Algorithm in LEO/MEO Double-layered Optical Satellite Network

    Science.gov (United States)

    Li, Yongjun; Zhao, Shanghong

    2016-09-01

    A novel routing algorithm (Hierarchical Supervisor and Agent Routing Algorithm, HSARA) for LEO/MEO (low earth orbit/medium earth orbit) double-layered optical satellite network is brought forward. The so-called supervisor (MEO satellite) is designed for failure recovery and network management. LEO satellites are grouped according to the virtual managed field of MEO which is different from coverage area of MEO satellite in RF satellite network. In each LEO group, one LEO satellite which has maximal persistent link with its supervisor is called the agent. A LEO group is updated when this optical inter-orbit links between agent LEO satellite and the corresponding MEO satellite supervisor cuts off. In this way, computations of topology changes and LEO group updating can be decreased. Expense of routing is integration of delay and wavelength utilization. HSARA algorithm simulations are implemented and the results are as follows: average network delay of HSARA can reduce 21 ms and 31.2 ms compared with traditional multilayered satellite routing and single-layer LEO satellite respectively; LEO/MEO double-layered optical satellite network can cover polar region which cannot be covered by single-layered LEO satellite and throughput is 1% more than that of single-layered LEO satellite averagely. Therefore, exact global coverage can be achieved with this double-layered optical satellite network.

  5. Symmetry Reduction in the Quantum Kagome Antiferromagnet Herbertsmithite

    Science.gov (United States)

    Zorko, A.; Herak, M.; Gomilšek, M.; van Tol, J.; Velázquez, M.; Khuntia, P.; Bert, F.; Mendels, P.

    2017-01-01

    Employing complementary torque magnetometry and electron spin resonance on single crystals of herbertsmithite, the closest realization to date of a quantum kagome antiferromagnet featuring a spin-liquid ground state, we provide novel insight into different contributions to its magnetism. At low temperatures, two distinct types of defects with different magnetic couplings to the kagome spins are found. Surprisingly, their magnetic response contradicts the threefold symmetry of the ideal kagome lattice, suggesting the presence of a global structural distortion that may be related to the establishment of the spin-liquid ground state.

  6. Substituted Quaternary Ammonium Salts Improve Low-Temperature Performance of Double-Layer Capacitors

    Science.gov (United States)

    Brandon, Erik J.; Smart, Marshall C.; West, William C.

    2011-01-01

    Double-layer capacitors are unique energy storage devices, capable of supporting large current pulses as well as a very high number of charging and discharging cycles. The performance of doublelayer capacitors is highly dependent on the nature of the electrolyte system used. Many applications, including for electric and fuel cell vehicles, back-up diesel generators, wind generator pitch control back-up power systems, environmental and structural distributed sensors, and spacecraft avionics, can potentially benefit from the use of double-layer capacitors with lower equivalent series resistances (ESRs) over wider temperature limits. Higher ESRs result in decreased power output, which is a particular problem at lower temperatures. Commercially available cells are typically rated for operation down to only 40 C. Previous briefs [for example, Low Temperature Supercapacitors (NPO-44386), NASA Tech Briefs, Vol. 32, No. 7 (July 2008), p. 32, and Supercapacitor Electrolyte Solvents With Liquid Range Below 80 C (NPO-44855), NASA Tech Briefs, Vol. 34, No. 1 (January 2010), p. 44] discussed the use of electrolytes that employed low-melting-point co-solvents to depress the freezing point of traditional acetonitrile-based electrolytes. Using these modified electrolyte formulations can extend the low-temperature operational limit of double-layer capacitors beyond that of commercially available cells. This previous work has shown that although the measured capacitance is relatively insensitive to temperature, the ESR can rise rapidly at low temperatures, due to decreased electrolyte conductance within the pores of the high surface- area carbon electrodes. Most of these advanced electrolyte systems featured tetraethylammonium tetrafluoroborate (TEATFB) as the salt. More recent work at JPL indicates the use of the asymmetric quaternary ammonium salt triethylmethylammonium tetrafluoroborate (TEMATFB) or spiro-(l,l')-bipyrrolidium tetrafluoroborate (SBPBF4) in a 1:1 by volume solvent

  7. Topological excitations in a kagome magnet.

    Science.gov (United States)

    Pereiro, Manuel; Yudin, Dmitry; Chico, Jonathan; Etz, Corina; Eriksson, Olle; Bergman, Anders

    2014-09-08

    Chirality--that is, left or right handedness--is present in many scientific areas, and particularly in condensed matter physics. Inversion symmetry breaking relates chirality with skyrmions, which are protected field configurations with particle-like and topological properties. Here we show that a kagome magnet, with Heisenberg and Dzyaloshinskii-Moriya interactions, causes non-trivial topological and chiral magnetic properties. We also find that under special circumstances, skyrmions emerge as excitations, having stability even at room temperature. Chiral magnonic edge states of a kagome magnet offer, in addition, a promising way to create, control and manipulate skyrmions. This has potential for applications in spintronics, that is, for information storage or as logic devices. Collisions between these particle-like excitations are found to be elastic at very low temperature in the skyrmion-skyrmion channel, albeit without mass-conservation. Skyrmion-antiskyrmion collisions are found to be more complex, where annihilation and creation of these objects have a distinct non-local nature.

  8. Improved Performance of Organic Thin Film Transistor with an Inorganic Oxide/Polymer Double-Layer Insulator

    Institute of Scientific and Technical Information of China (English)

    ZHAO Yi-Hua; DONG Gui-Fang; WANG Li-Duo; QIU Yong

    2007-01-01

    We employ the Ta2O5/PVP (poly-4-vinylphenol) double-layer gate insulator to improve the performance of pentacene thin-film transistors. It is found that the double-layer insulator has low leakage current, smooth surface and considerably high capacitance. Compared to Ta2O5 insulator layers, the device with the Ta2O5/PVP double-layer insulator exhibits an enhancement of the Reid-effect mobility from 0.21 to 0.54 cm2 /Vs, and the decreasing threshold voltage from 4.38V to -2.5 V. The results suggest that the Ta2O5/PVP double-layer insulator is a potential gate insulator for fabricating OTFTs with good electrical performance.

  9. Determination of diffuse double layer protonation constants for hydrous ferric oxide (HFO): supporting evidence for the Dzombak and Morel compilation

    CSIR Research Space (South Africa)

    Pretorius, PJ

    1998-01-01

    Full Text Available The acid-base properties of hydrous ferric oxide were studied by glass electrode potentiometry. From the potentiometric data, surface protonation constants were derived according to the Diffuse Double Layer convention. Chemical equilibrium modelling...

  10. Large amplitude ion-acoustic rarefactive and compressive solitons and double layers in a dusty plasma with finite ion temperature

    Science.gov (United States)

    Jain, S. L.; Tiwari, R. S.; Mishra, M. K.

    2015-05-01

    Large amplitude ion-acoustic solitons and double layers are studied using Sagdeev's pseudo potential technique in a collisionless unmagnetized plasma consisting of hot and cold Maxwellian electrons, warm adiabatic ions, and heavily charged massive dust grains. It is found that for the selected set of plasma parameters, the system can support both solitons and double layers in the presence of negative as well as positive dust in the plasma. Further we have also investigated the ranges of parameters for simultaneous existence of both rarefactive and compressive supersonic solitons. The effects of dust concentration and ion temperature on the amplitude and Mach number of the double layer have also been studied. Our findings may be helpful in understanding the formation of non-linear structures, specially the solitons and double layers in space plasma, such as: in interstellar clouds, circumstellar clouds, planetary rings, comets, cometary tails, asteroid zones, auroral plasma, magnetospheric plasma, pulsars, and other astronomical environments and laboratory plasmas.

  11. Optical and Electrical Characteristics of Graphene Double Layer Formed by a Double Transfer of Graphene Single Layers.

    Science.gov (United States)

    Kim, Young Jun; Bae, Gi Yoon; Chun, Sungwoo; Park, Wanjun

    2016-03-01

    We demonstrate formation of double layer graphene by means of a double transfer using two single graphene layers grown by a chemical vapor deposition method. It is observed that shiftiness and broadness in the double-resonance of Raman scattering are much weaker than those of bilayer graphene formed naturally. Transport characteristics examined from transmission line measurements and field effect transistors show the similar behavior with those of single layer graphene. It indicates that interlayer separation, in electrical view, is large enough to avoid correlation between layers for the double layer structure. It is also observed from a transistor with the double layer graphene that molecules adsorpted on two inner graphene surfaces in the double layered structure are isolated and conserved from ambient environment.

  12. Towards understanding the structure and capacitance of electrical double layer in ionic liquids

    Energy Technology Data Exchange (ETDEWEB)

    Fedorov, Maxim V. [Max Planck Institute for Mathematics in the Sciences, D 04103 Leipzig (Germany); Unilever Centre for Molecular Science Informatics, Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge CB2 1EW (United Kingdom); Kornyshev, Alexei A. [Department of Chemistry, Faculty of Natural Sciences, Imperial College London, SW7 2AZ London (United Kingdom)

    2008-10-01

    In order to understand basic principles of the double layer formation in room temperature ionic liquids, we have performed Molecular Dynamic simulations for a simplified system: dense assembly of charged Lennard-Jones spheres between charged walls. For simplicity, in this first investigation we have considered the cations and anions of the same size. We have calculated the corresponding values of the double layer capacitance as a function of the electrode potential and compared the results with existing theories. We have found that the capacitance curve does not follow the U-shape of the Gouy-Chapman theory, but has a bell-shape in agreement with the mean-field theory that takes into account the effect of limited maximum packing of ions. The wings of capacitance decrease inversely proportional to the square root of the electrode potential, as prescribed by the mean-field theory and the charge conservation law at large electrode polarizations. We have found, however, that the mean-field theory does not quantitatively reproduce the simulation results at small electrode potentials, having detected their remarkable overscreening effects (ionic correlations). The plots for the distributions of ions near the electrode at different electrode charges show that for the considered system, unlike it is often assumed, the double layer is not one layer thick. The overscreening effects, dominating near the potential of zero charge (p.z.c.), are suppressed by the high electrode polarizations, following the onset of the so-called 'lattice saturation effect'. The maximum of the capacitance coincides with the p.z.c., but it is true only for this 'symmetric' system. If sizes of cations and anions are different the maximum will be shifted away from the p.z.c., and generally the shape of the capacitance curve could be more complicated. (author)

  13. Large amplitude ion-acoustic double layers in warm dusty plasma

    Science.gov (United States)

    Jain, S. L.; Tiwari, R. S.; Mishra, M. K.

    2015-01-01

    Large amplitude ion-acoustic double layer (IADL) is studied using Sagdeev's pseudo-potential technique in collisionless unmagnetized plasma comprising hot and cold Maxwellian population of electrons, warm adiabatic ions, and dust grains. Variation of both Mach number (M) and amplitude |φ m | of large amplitude IADL with charge, concentration, and mass of heavily charged massive dust grains is investigated for both positive and negative dust in plasma. Our numerical analysis shows that system supports only rarefactive large amplitude IADL for the selected set of plasma parameters. Our investigations for both negative and positive dust grains reveal that ion temperature increases the mobility of ions, resulting in increase in the Mach number of IADL. The larger mobility of ions causes leakage of ions from localized region, resulting into decrease in the amplitude of IADL. Other parameters, e.g. temperature ratio of hot to cold electrons, charge, concentration, mass of heavily charged massive dust grains also play significant role in the properties and existence of double layers. Since it is well established that both positive and negative dust are found in space as well as laboratory plasma, and double layers have a tremendous role to play in astrophysics, we have included both positive and negative dust in our numerical analysis for the study of large amplitude IADL. Further data used for negative dust are close to experimentally observed data. Hence, it is anticipated that our parametric studies for heavily charged (both positive and negative) dust may be useful in understanding laboratory plasma experiments, identifying nonlinear structures in upper part of ionosphere and lower part of magnetosphere structures, and in theoretical research for the study of properties of nonlinear structures.

  14. Thin-shell wormholes with a double layer in quadratic F(R) gravity

    CERN Document Server

    Eiroa, Ernesto F

    2016-01-01

    We present a family of spherically symmetric Lorentzian wormholes in quadratic F(R) gravity, with a thin shell of matter corresponding to the throat. At each side of the shell the geometry has a different constant value of the curvature scalar R. The junction conditions determine the equation of state between the pressure and energy density at the throat, where a double layer is also located. We analyze the stability of the configurations under perturbations preserving the spherical symmetry. In particular, we study thin-shell wormholes with mass and charge. We find that there exist values of the parameters for which stable static solutions are possible.

  15. Grafted, cross-linked carbon black as a double-layer capacitor electrode material

    Energy Technology Data Exchange (ETDEWEB)

    Richner, R.; Mueller, S.; Wokaun, A.

    2001-03-01

    Isocyanate prepolymers readily react with oxidic functional groups on carbon black. On carbon black grafted with diisocyanates, reactive isocyanate groups are available for cross-linking to a polyurethane system. This cross-linked carbon black was considered as a new active material for electrochemical electrodes. Active material for electric double-layer capacitor electrodes was produced which had values of specific capacitance of up to 200 F/g. Cross-linking efficiencies of up to 58 % of the polymers utilised were achieved. (author)

  16. Study on the electric double layer of a cylindrical reverse micelle with functional theoretical approach

    Institute of Scientific and Technical Information of China (English)

    WANG; Zhengwu; GUO; Baomin; ZHANG; Gexin

    2006-01-01

    The iterative method in functional analysis is applied to looking for a solution of the Poisson-Boltzmann equation in order to describe the problems of the distribution of the potentials in the electric double layer (EDL) inside the water pool for a cylindrical inverse micelle. Potentials as a function of the position of a particular point in EDL are computed, which display a quantitative is also shown that in the higher-potential range the iterative calculations can give more accurate results. These results indicate the utility of this functional analysis technique in the description of the properties of EDL for a cylindrical inverse micelle.

  17. Effect of acid oxidization of carbon nanotube electrode on the capacitances of double layer capacitors

    Institute of Scientific and Technical Information of China (English)

    LI; Chensha; WANG; Dazhi; LIANG; Tongxiang; WANG; Xiaofen

    2004-01-01

    Polarizable electrode of electric double layer capacitor was made from carbon nanotubes. The effect of acid oxidation of electrode on the specific capacitance was studied. Oxidation removed the redundant carbon, expanded the pore size and introduced some kinds of functional groups on the surface of CNTs. The specific capacit ance of the electrodes with organic electrolyte was increased from 21.4 to 49.6 F/gafter being oxidized at a volume ratio of H2SO4 to HNO3 of 3:1.

  18. Measurement of the magnetic induction vector in superconductors using a double-layer Hall sensor array

    Science.gov (United States)

    Abulafia, Y.; McElfresh, M.; Shaulov, A.; Yeshurun, Y.; Paltiel, Y.; Majer, D.; Shtrikman, H.; Zeldov, E.

    1998-06-01

    We describe an experimental technique for simultaneous measurement of both the normal (Bz) and the in-plane (Bx) components of the magnetic induction field near the surface of a superconducting sample. This technique utilizes a novel design of a double-layered Hall sensor array fabricated from a GaAs/AlGaAs heterostructure containing two parallel layers of a two-dimensional electron gas. The effectiveness of this technique is demonstrated in measurements of Bx and Bz and the current distribution at the surface of a thin YBa2Cu3O7 crystal.

  19. Double-layer mesh hernioplasty for repairing umbilical hernias in 10 goats*

    OpenAIRE

    2011-01-01

    Umbilical hernias in goats are uncommon and can vary in their etiology and management. Hernioplasty can be done by closing the abdominal wall with a horizontal mattress pattern using absorbable sutures. However, larger defects (hernial ring size >3 cm) generally require the use of prosthetic materials that allow for a tension-free repair. In this study, 10 young female goats with umbilical hernias and hernial ring sizes ranging from 7-10 cm in width were treated using a double-layer polypr...

  20. Analysis of Double Layer and Adsorption Effects at the Alkaline Polymer Electrolyte-Electrode Interface

    Science.gov (United States)

    2011-10-05

    Block 13: Supplementary Note © 2011 . Published in Journal of the Electrochemical Society , Vol. Ed. 0 (2011), (Ed. ). DoD Components reserve a royalty...unlimited. ... 55036.7-CH Journal of The Electrochemical Society , 158 (11) B1423-B1431 (2011) B1423 0013-4651/2011/158(11)/B1423/9/$28.00 © The... Electrochemical Society Analysis of Double Layer and Adsorption Effects at the Alkaline Polymer Electrolyte-Electrode Interface Murat Ünlü,a,∗ Daniel Abbott,b

  1. Dynamic Reliability Evaluation of Double-Layer Cylindrical Latticed Shell under Multi-Support Excitations

    Institute of Scientific and Technical Information of China (English)

    柳春光; 李会军

    2010-01-01

    To overcome the excessive computational cost and/or bad accuracy of traditional approaches,the probabilistic density evolution method(PDEM) is introduced.The dynamic reliability of a double-layer cylindrical latticed shell is evaluated by applying PDEM and Monte Carlo Method(MCM) respectively,and four apparent wave velocities(100 m/s,500 m/s,800 m/s and 1 200 m/s) and five thresholds(0.1 m,0.2 m,0.3 m,0.4 m and 0.5 m) are taken into consideration.Only the difference between threshold and maximal deformation...

  2. Ion-acoustic double layers in the presence of plasma source

    Energy Technology Data Exchange (ETDEWEB)

    Okuda, H.; Ashour-Abdalla, M.

    1981-11-01

    Steady-state plasma turbulence and formation of negative potential spikes and double layers in the presence of ion acoustic instabilities have been studied by means of one-dimensional particle simulations in which velocities of a small fraction of electrons are replaced by the initial drifting Maxwellian at a constant rate. A steady state is found where negative potential spikes appear randomly in space and time giving rise to an anomalous resistivity much greater than previously found. Comparisons of the simulation results with laboratory and space plasmas are discussed.

  3. Electric Double Layer Gate Field-Effect Transistors Based on Si

    Science.gov (United States)

    Yanase, Takashi; Shimada, Toshihiro; Hasegawa, Tetsuya

    2010-04-01

    Electric double layer field-effect transistors (EDL-FETs) were fabricated using single crystal Si wafer as the active semiconductor and various characteristics were studied including dynamic response against step-function gate bias. The static FET mobility was more than 100 cm2 V-1 s-1. The response time of the drain current was 20 µs for ionic liquid and 3 ms for poly(ethylene glycol) (PEG) solution of LiBF4. Unexpected fast response was observed at a certain “speed up bias” condition. This effect will be useful to switching circuits using EDL-FETs.

  4. Arrangements of a pair of loudspeakers for sound field control with double-layer arrays

    DEFF Research Database (Denmark)

    Chang, Jiho; Agerkvist, Finn T.; Olsen, Martin

    2013-01-01

    Recent studies have attempted to control sound fields, and also to reduce room reflections with a circular or spherical array of loudspeakers. One of the attempts was to suppress sound waves propagating to the walls outside the array with a circular double-layer array of loudspeakers. The double....... In order to solve this problem, this study aims to examine several arrangements of a pair of loudspeakers that has a short distance between the acoustic centres. The effect of diffraction of sound waves due to the enclosure of another loudspeaker is investigated in simulations in terms of the position...

  5. Optimization of Magnet Arrangement in Double-Layer Interior Permanent-Magnet Motors

    Science.gov (United States)

    Yamazaki, Katsumi; Kitayuguchi, Kazuya

    The arrangement of permanent magnets in double-layer interior permanent-magnet motors is optimized for variable-speed applications. First, the arrangement of magnets is decided by automatic optimization. Next, the superiority of the optimized motor is discussed by the d- and q-axis equivalent circuits that consider the magnetic saturation of the rotor core. Finally, experimental verification is carried out by using a prototype motor. It is confirmed that the maximum torque of the optimized motor under both low speed and high speed conditions are higher than those of conventional motors because of relatively large q-axis inductance and small d-axis inductance.

  6. Influence of ions on relativistic double layers radiation in astrophysical plasmas

    Directory of Open Access Journals (Sweden)

    AM Ahadi

    2009-12-01

    Full Text Available As double layers (DLs are one of the most important acceleration mechanisms in space as well as in laboratory plasmas, they are studied from different points of view. In this paper, the emitted power and energy radiated from charged particles, accelerated in relativistic cosmic DLs are investigated. The effect of the presence of additional ions in a multi-species plasma, as a real example of astrophysical plasma, is also investigated. Considering the acceleration role of DLs, radiations from accelerated charged particles could be seen as a loss mechanism. These radiations are influenced directly by the additional ion species as well as their relative densities.

  7. Pattern Formation in Double-Layer Kerr Resonators with Coupled Modes

    CERN Document Server

    Bois, Antoine

    2016-01-01

    A double-layer Kerr resonator in which both coupled modes are excited and interact with each other via incoherent cross-phase modulation is investigated to reveal stable localized solutions beyond the usual formation mechanism involving a single mode. Periodic solutions from modulational instability are found to occur at a slight penalty on the nonlinear efficiency, but they stabilize the spatial dynamics, leading to dissipative solitons in previously unattainable regimes. Numerical simulations show paired breather solitons in addition to temporally stable solutions. The results demonstrate coupled modes can increase the stability of Kerr frequency comb generation.

  8. Reducing disorder in artificial kagome ice.

    Science.gov (United States)

    Daunheimer, Stephen A; Petrova, Olga; Tchernyshyov, Oleg; Cumings, John

    2011-10-14

    Artificial spin ice has become a valuable tool for understanding magnetic interactions on a microscopic level. The strength in the approach lies in the ability of a synthetic array of nanoscale magnets to mimic crystalline materials, composed of atomic magnetic moments. Unfortunately, these nanoscale magnets, patterned from metal alloys, can show substantial variation in relevant quantities such as the coercive field, with deviations up to 16%. By carefully studying the reversal process of artificial kagome ice, we can directly measure the distribution of coercivities, and, by switching from disconnected islands to a connected structure, we find that the coercivity distribution can achieve a deviation of only 3.3%. These narrow deviations should allow the observation of behavior that mimics canonical spin-ice materials more closely.

  9. Design Optimization and Testing of an Active Core for Sandwich Panels

    Science.gov (United States)

    2009-07-01

    repeatedly linked cells. Certain unit cell structures such as the Kagome truss (Symons, Hutchinson et al. 2005) holds potential in the design of...34Actuation of the Kagome double layer grid part 1: Prediction of performance of the perfect structure." Journal of Mechanics and Physics of Solids

  10. Numerical well testing interpretation model and applications in crossflow double-layer reservoirs by polymer flooding.

    Science.gov (United States)

    Yu, Haiyang; Guo, Hui; He, Youwei; Xu, Hainan; Li, Lei; Zhang, Tiantian; Xian, Bo; Du, Song; Cheng, Shiqing

    2014-01-01

    This work presents numerical well testing interpretation model and analysis techniques to evaluate formation by using pressure transient data acquired with logging tools in crossflow double-layer reservoirs by polymer flooding. A well testing model is established based on rheology experiments and by considering shear, diffusion, convection, inaccessible pore volume (IPV), permeability reduction, wellbore storage effect, and skin factors. The type curves were then developed based on this model, and parameter sensitivity is analyzed. Our research shows that the type curves have five segments with different flow status: (I) wellbore storage section, (II) intermediate flow section (transient section), (III) mid-radial flow section, (IV) crossflow section (from low permeability layer to high permeability layer), and (V) systematic radial flow section. The polymer flooding field tests prove that our model can accurately determine formation parameters in crossflow double-layer reservoirs by polymer flooding. Moreover, formation damage caused by polymer flooding can also be evaluated by comparison of the interpreted permeability with initial layered permeability before polymer flooding. Comparison of the analysis of numerical solution based on flow mechanism with observed polymer flooding field test data highlights the potential for the application of this interpretation method in formation evaluation and enhanced oil recovery (EOR).

  11. Highly Durable Direct Methanol Fuel Cell with Double-Layered Catalyst Cathode

    Directory of Open Access Journals (Sweden)

    Jing Liu

    2015-01-01

    Full Text Available Polymer electrolyte membrane (PEM is one of the key components in direct methanol fuel cells. However, the PEM usually gets attacked by reactive oxygen species during the operation period, resulting in the loss of membrane integrity and formation of defects. Herein, a double-layered catalyst cathode electrode consisting of Pt/CeO2-C as inner catalyst and Pt/C as outer catalyst is fabricated to extend the lifetime and minimize the performance loss of DMFC. Although the maximum power density of membrane electrode assembly (MEA with catalyst cathode is slightly lower than that of the traditional one, its durability is significantly improved. No obvious degradation is evident in the MEA with double-layered catalyst cathode within durability testing. These results indicated that Pt/CeO2-C as inner cathode catalyst layer greatly improved the stability of MEA. The significant reason for the improved stability of MEA is the ability of CeO2 to act as free-radical scavengers.

  12. Investigation of surface charge density on solid-liquid interfaces by modulating the electrical double layer.

    Science.gov (United States)

    Moon, Jong Kyun; Song, Myung Won; Pak, Hyuk Kyu

    2015-05-20

    A solid surface in contact with water or aqueous solution usually carries specific electric charges. These surface charges attract counter ions from the liquid side. Since the geometry of opposite charge distribution parallel to the solid-liquid interface is similar to that of a capacitor, it is called an electrical double layer capacitor (EDLC). Therefore, there is an electrical potential difference across an EDLC in equilibrium. When a liquid bridge is formed between two conducting plates, the system behaves as two serially connected EDLCs. In this work, we propose a new method for investigating the surface charge density on solid-liquid interfaces. By mechanically modulating the electrical double layers and simultaneously applying a dc bias voltage across the plates, an ac electric current can be generated. By measuring the voltage drop across a load resistor as a function of bias voltage, we can study the surface charge density on solid-liquid interfaces. Our experimental results agree very well with the simple equivalent electrical circuit model proposed here. Furthermore, using this method, one can determine the polarity of the adsorbed state on the solid surface depending on the material used. We expect this method to aid in the study of electrical phenomena on solid-liquid interfaces.

  13. Heat transfer performance of a novel double-layer mini-channel heat sink

    Science.gov (United States)

    Tang, Biao; Zhou, Rui; Bai, Pengfei; Fu, Ting; Lu, Longsheng; Zhou, Guofu

    2017-03-01

    High pressure drop and significant non-uniformity in temperature distribution along the streamwise direction are still challenges to the design of mini-channel heat sink. High density mini-channel arrays with high liquid-wall contact area are usually pursued in a conventional single-layer design of heat sink, which also inevitably brings high pressure drop. A novel double-layer structured heat sink is proposed in this paper. Four heat sinks with various designs in mini-channel density and flow direction were fabricated and studied experimentally on the heat transfer performance. The single factor of heat load does not show obvious effect on the overall thermal resistance of the heat sinks. On the other hand, slight decrease in thermal resistance was found with the increase in heat load at high flow rates. Moreover, a computational fluid dynamics modeling work was conducted. The results indicate that the parallel cross-flow field regulated by the double-layer structure enhances the heat exchange in both horizontal and vertical directions and consequently gives an uniform temperature distribution and high heat transfer efficiency.

  14. Poisson-Helmholtz-Boltzmann model of the electric double layer: analysis of monovalent ionic mixtures.

    Science.gov (United States)

    Bohinc, Klemen; Shrestha, Ahis; Brumen, Milan; May, Sylvio

    2012-03-01

    In the classical mean-field description of the electric double layer, known as the Poisson-Boltzmann model, ions interact exclusively through their Coulomb potential. Ion specificity can arise through solvent-mediated, nonelectrostatic interactions between ions. We employ the Yukawa pair potential to model the presence of nonelectrostatic interactions. The combination of Yukawa and Coulomb potential on the mean-field level leads to the Poisson-Helmholtz-Boltzmann model, which employs two auxiliary potentials: one electrostatic and the other nonelectrostatic. In the present work we apply the Poisson-Helmholtz-Boltzmann model to ionic mixtures, consisting of monovalent cations and anions that exhibit different Yukawa interaction strengths. As a specific example we consider a single charged surface in contact with a symmetric monovalent electrolyte. From the minimization of the mean-field free energy we derive the Poisson-Boltzmann and Helmholtz-Boltzmann equations. These nonlinear equations can be solved analytically in the weak perturbation limit. This together with numerical solutions in the nonlinear regime suggests an intricate interplay between electrostatic and nonelectrostatic interactions. The structure and free energy of the electric double layer depends sensitively on the Yukawa interaction strengths between the different ion types and on the nonelectrostatic interactions of the mobile ions with the surface.

  15. Numerical Well Testing Interpretation Model and Applications in Crossflow Double-Layer Reservoirs by Polymer Flooding

    Directory of Open Access Journals (Sweden)

    Haiyang Yu

    2014-01-01

    Full Text Available This work presents numerical well testing interpretation model and analysis techniques to evaluate formation by using pressure transient data acquired with logging tools in crossflow double-layer reservoirs by polymer flooding. A well testing model is established based on rheology experiments and by considering shear, diffusion, convection, inaccessible pore volume (IPV, permeability reduction, wellbore storage effect, and skin factors. The type curves were then developed based on this model, and parameter sensitivity is analyzed. Our research shows that the type curves have five segments with different flow status: (I wellbore storage section, (II intermediate flow section (transient section, (III mid-radial flow section, (IV crossflow section (from low permeability layer to high permeability layer, and (V systematic radial flow section. The polymer flooding field tests prove that our model can accurately determine formation parameters in crossflow double-layer reservoirs by polymer flooding. Moreover, formation damage caused by polymer flooding can also be evaluated by comparison of the interpreted permeability with initial layered permeability before polymer flooding. Comparison of the analysis of numerical solution based on flow mechanism with observed polymer flooding field test data highlights the potential for the application of this interpretation method in formation evaluation and enhanced oil recovery (EOR.

  16. Weak localization in electric-double-layer gated few-layer graphene

    Science.gov (United States)

    Gonnelli, R. S.; Piatti, E.; Sola, A.; Tortello, M.; Dolcini, F.; Galasso, S.; Nair, J. R.; Gerbaldi, C.; Cappelluti, E.; Bruna, M.; Ferrari, A. C.

    2017-09-01

    We induce surface carrier densities up to  ˜7\\centerdot {{10}14} cm-2 in few-layer graphene devices by electric double layer gating with a polymeric electrolyte. In 3-, 4- and 5-layer graphene below 20-30 K we observe a logarithmic upturn of resistance that we attribute to weak localization in the diffusive regime. By studying this effect as a function of carrier density and with ab initio calculations we derive the dependence of transport, intervalley and phase coherence scattering lifetimes on total carrier density. We find that electron-electron scattering in the Nyquist regime is the main source of dephasing at temperatures lower than 30 K in the  ˜1013 cm-2 to  ˜7\\centerdot {{10}14} cm-2 range of carrier densities. With the increase of gate voltage, transport elastic scattering is dominated by the competing effects due to the increase in both carrier density and charged scattering centers at the surface. We also tune our devices into a crossover regime between weak and strong localization, indicating that simultaneous tunability of both carrier and defect density at the surface of electric double layer gated materials is possible.

  17. Probing the electric field in organic double layer-system by optical second harmonic generation

    Energy Technology Data Exchange (ETDEWEB)

    Lim, Eunju; Shibata, Yoshinori; Manaka, Takaaki [Department of Physical Electronics, Tokyo Institute of Technology, 2-12-1 O-okayama, Meguro-ku, Tokyo 152-8552 (Japan); Iwamoto, Mitsumasa, E-mail: iwamoto@ome.pe.titech.ac.j [Department of Physical Electronics, Tokyo Institute of Technology, 2-12-1 O-okayama, Meguro-ku, Tokyo 152-8552 (Japan)

    2009-11-30

    Optical electric field induced second harmonic generation (EFISHG) measurements were employed to probe the electric field in the active layer of organic field effect transistors (OFETs) and organic light emitting diodes (OLEDs). The OFETs used were double-layered with an active layer of pentacene/poly (3-hexyl thiophene) P3HT on SiO{sub 2} gate insulator with Au source and drain electrodes. It was shown that SHG from the P3HT bottom layer could be selectively probed at a wavelength of 450 nm. Similarly, by using OLEDs comprised of a double layer of Tris(8-hydroxyquinolinato) aluminium (Alq{sub 3}) and N'-di(1-naphthyl)-N,N'-diphenylbenzidine ({alpha}-NPD) with a device structure of indium-zinc oxide (IZO)/{alpha}-NPD/Alq{sub 3}/Al, it was shown that EFISHG from the Alq{sub 3} layer could be selectively probed at a wavelength of 1000 nm by reflective laser beam irradiation from IZO-side. The results show that the spectroscopic nature of materials allows us to selectively probe the electric field distribution in each layer of multi-layer in organic devices.

  18. Theoretical Study of Monolayer and Double-Layer Waveguide Love Wave Sensors for Achieving High Sensitivity.

    Science.gov (United States)

    Li, Shuangming; Wan, Ying; Fan, Chunhai; Su, Yan

    2017-03-22

    Love wave sensors have been widely used for sensing applications. In this work, we introduce the theoretical analysis of the monolayer and double-layer waveguide Love wave sensors. The velocity, particle displacement and energy distribution of Love waves were analyzed. Using the variations of the energy repartition, the sensitivity coefficients of Love wave sensors were calculated. To achieve a higher sensitivity coefficient, a thin gold layer was added as the second waveguide on top of the silicon dioxide (SiO₂) waveguide-based, 36 degree-rotated, Y-cut, X-propagating lithium tantalate (36° YX LiTaO₃) Love wave sensor. The Love wave velocity was significantly reduced by the added gold layer, and the flow of wave energy into the waveguide layer from the substrate was enhanced. By using the double-layer structure, almost a 72-fold enhancement in the sensitivity coefficient was achieved compared to the monolayer structure. Additionally, the thickness of the SiO₂ layer was also reduced with the application of the gold layer, resulting in easier device fabrication. This study allows for the possibility of designing and realizing robust Love wave sensors with high sensitivity and a low limit of detection.

  19. Nonlinear electron acoustic structures generated on the high-potential side of a double layer

    Directory of Open Access Journals (Sweden)

    R. Pottelette

    2009-04-01

    Full Text Available High-time resolution measurements of the electron distribution function performed in the auroral upward current region reveals a large asymmetry between the low- and high-potential sides of a double-layer. The latter side is characterized by a large enhancement of a locally trapped electron population which corresponds to a significant part (~up to 30% of the total electron density. As compared to the background hot electron population, this trapped component has a very cold temperature in the direction parallel to the static magnetic field. Accordingly, the differential drift between the trapped and background hot electron populations generates high frequency electron acoustic waves in a direction quasi-parallel to the magnetic field. The density of the trapped electron population can be deduced from the frequency where the electron acoustic spectrum maximizes. In the auroral midcavity region, the electron acoustic waves may be modulated by an additional turbulence generated in the ion acoustic range thanks to the presence of a pre-accelerated ion beam located on the high-potential side of the double layer. Electron holes characterized by bipolar pulses in the electric field are sometimes detected in correlation with these electron acoustic wave packets.

  20. Strong Deformation of the Thick Electric Double Layer around a Charged Particle during Sedimentation or Electrophoresis.

    Science.gov (United States)

    Khair, Aditya S

    2017-08-15

    The deformation of the electric double layer around a charged colloidal particle during sedimentation or electrophoresis in a binary, symmetric electrolyte is studied. The surface potential of the particle is assumed to be small compared to the thermal voltage scale. Additionally, the Debye length is assumed to be large compared to the particle size. These assumptions enable a linearization of the electrokinetic equations. The particle appears as a point charge in this thick-double-layer limit; the distribution of charge in the diffuse cloud surrounding it is determined by a balance of advection due to the particle motion, Brownian diffusion of ions, and electrostatic screening of the particle by the cloud. The ability of advection to deform the charge cloud from its equilibrium state is parametrized by a Péclet number, Pe. For weak advection (Pe ≪ 1), the cloud is only slightly deformed. In contrast, the cloud can be completely stripped from the particle at Pe ≫ 1; consequently, electrokinetic effects on the particle motion vanish in this regime. Therefore, in sedimentation the drag limits to Stokes' law for an uncharged particle as Pe → ∞. Likewise, the particle velocity for electrophoresis approaches Huckel's result. The strongly deformed cloud at large Pe is predicted to generate a concomitant increase in the sedimentation field in a dilute settling suspension.

  1. Analytical solution of electrohydrodynamic flow and transport in rectangular channels: inclusion of double layer effects

    KAUST Repository

    Joekar-Niasar, V.

    2013-01-25

    Upscaling electroosmosis in porous media is a challenge due to the complexity and scale-dependent nonlinearities of this coupled phenomenon. "Pore-network modeling" for upscaling electroosmosis from pore scale to Darcy scale can be considered as a promising approach. However, this method requires analytical solutions for flow and transport at pore scale. This study concentrates on the development of analytical solutions of flow and transport in a single rectangular channel under combined effects of electrohydrodynamic forces. These relations will be used in future works for pore-network modeling. The analytical solutions are valid for all regimes of overlapping electrical double layers and have the potential to be extended to nonlinear Boltzmann distribution. The innovative aspects of this study are (a) contribution of overlapping of electrical double layers to the Stokes flow as well as Nernst-Planck transport has been carefully included in the analytical solutions. (b) All important transport mechanisms including advection, diffusion, and electromigration have been included in the analytical solutions. (c) Fully algebraic relations developed in this study can be easily employed to upscale electroosmosis to Darcy scale using pore-network modeling. © 2013 Springer Science+Business Media Dordrecht.

  2. Unstacked double-layer templated graphene for high-rate lithium-sulphur batteries

    Science.gov (United States)

    Zhao, Meng-Qiang; Zhang, Qiang; Huang, Jia-Qi; Tian, Gui-Li; Nie, Jing-Qi; Peng, Hong-Jie; Wei, Fei

    2014-03-01

    Preventing the stacking of graphene is essential to exploiting its full potential in energy-storage applications. The introduction of spacers into graphene layers always results in a change in the intrinsic properties of graphene and/or induces complexity at the interfaces. Here we show the synthesis of an intrinsically unstacked double-layer templated graphene via template-directed chemical vapour deposition. The as-obtained graphene is composed of two unstacked graphene layers separated by a large amount of mesosized protuberances and can be used for high-power lithium-sulphur batteries with excellent high-rate performance. Even after 1,000 cycles, high reversible capacities of ca. 530 mA h g-1 and 380 mA h g-1 are retained at 5 C and 10 C, respectively. This type of double-layer graphene is expected to be an important platform that will enable the investigation of stabilized three-dimensional topological porous systems and demonstrate the potential of unstacked graphene materials for advanced energy storage, environmental protection, nanocomposite and healthcare applications.

  3. Relation between the ion size and pore size for an electric double-layer capacitor.

    Science.gov (United States)

    Largeot, Celine; Portet, Cristelle; Chmiola, John; Taberna, Pierre-Louis; Gogotsi, Yury; Simon, Patrice

    2008-03-05

    The research on electrochemical double layer capacitors (EDLC), also known as supercapacitors or ultracapacitors, is quickly expanding because their power delivery performance fills the gap between dielectric capacitors and traditional batteries. However, many fundamental questions, such as the relations between the pore size of carbon electrodes, ion size of the electrolyte, and the capacitance have not yet been fully answered. We show that the pore size leading to the maximum double-layer capacitance of a TiC-derived carbon electrode in a solvent-free ethyl-methylimmidazolium-bis(trifluoro-methane-sulfonyl)imide (EMI-TFSI) ionic liquid is roughly equal to the ion size (approximately 0.7 nm). The capacitance values of TiC-CDC produced at 500 degrees C are more than 160 F/g and 85 F/cm(3) at 60 degrees C, while standard activated carbons with larger pores and a broader pore size distribution present capacitance values lower than 100 F/g and 50 F/cm(3) in ionic liquids. A significant drop in capacitance has been observed in pores that were larger or smaller than the ion size by just an angstrom, suggesting that the pore size must be tuned with sub-angstrom accuracy when selecting a carbon/ion couple. This work suggests a general approach to EDLC design leading to the maximum energy density, which has been now proved for both solvated organic salts and solvent-free liquid electrolytes.

  4. Improved Mechanical Compatibility and Cytocompatibility of Ta/Ti Double-Layered Composite Coating

    Science.gov (United States)

    Ding, Ding; Xie, Youtao; Li, Kai; Huang, Liping; Zheng, Xuebin

    2017-07-01

    In order to improve the mechanical compatibility and cytocompatibility of titanium implants, a composite coating with double layers composed of tantalum and titanium was designed and prepared using plasma spraying technology. In the composite coating, the upper tantalum layer provides a good biocompatibility, and the sublayer of titanium with a porous structure ensures the low elastic modulus. Results show that the fabricated composite coating exhibits a relatively low elastic modulus of 26.7 GPa, which is close to the elastic modulus of human cortical bone. In vitro cytocompatibility evaluation of the composite coating shows that the human bone marrow stromal cells exhibit enhanced adhesion and spreading performance on the double-layered composite coating in comparison with the single-layered titanium coating. In order to eliminate the misgivings of chemical stability of the composite coating in clinical application, electrochemical corrosion of the coating was examined. The results obtained revealed a very weak galvanic corrosion between the tantalum and titanium in the composite coating, which would ensure the safety of the coating in vivo.

  5. Optical Tagging of Ion Beams Accelerated by Double Layers in Laboratory Plasma

    Science.gov (United States)

    Good, Timothy; Aguirre, Evan; Thompson, Derek; Scime, Earl

    2016-10-01

    Experiments in helicon sources that investigate plasma expansion into weakly magnetized, low density regions reveal the production of supersonic ion beams attributed to acceleration by spatially localized double layer structures. Current efforts are aimed at mapping the ion velocity flow field utilizing 2D spatially scanning laser induced fluorescence (LIF) probes that yield metastable ion velocity distribution functions (IVDF) for velocities along and perpendicular to the flow. Observation of metastable ion beams by LIF renders plausible a Lagrangian approach to studying the field-ion interaction via optical tagging. We propose a tagging scheme in which metastable state ion populations are modulated by optical pumping upstream of the double layer and the synchronous detection of LIF at the ion beam velocity is recorded downstream. Besides the unambiguous identification of the source of beam ions, this method can provide detailed dynamical information through time of flight analysis. Preliminary results will be presented. Please include this poster in session that includes poster authored by Evan Aguirre et al.

  6. Double Layers: Potential Formation and Related Nonlinear Phenomena in Plasmas: Proceedings of the 5th Symposium

    Science.gov (United States)

    Iizuka, S.

    1998-02-01

    The Table of Contents for the book is as follows: * PREFACE * INTERNATIONAL SCIENTIFIC COMMITTEE * LOCAL ORGANIZING COMMITTEE AT TOHOKU UNIVERSITY * CHAPTER 1: DOUBLE LAYERS, SHEATHS, AND POTENTIAL STRUCTURES * 1.1 Double Layers * On Fluid Models of Stationary, Acoustic Double Layers (Invited) * Particle Simulation of Double Layer (Invited) * Space-Time Dependence of Non-Steady Double Layers * The Role of Low Energy Electrons for the Generation of Anode Double Layers in Glow Discharges * Arbitrary Amplitude Ion-Acoustic Double Layers in a Dusty Plasma * 1.2 Sheaths * Bounded Plasma Edge Physics as Observed from Simulations in 1D and 2D (Invited) * Control of RF Sheath Structure in RF Diode Discharge * Observation of Density Gradients with Fine Structures and Low Frequency Wave Excitation at the Plasma-Sheath Boundary * Double Sheath Associated with an Electron Emission to a Plasma Containing Negative Ions * Sheath Edge and Floating Potential for Multi-Species Plasmas Including Dust Particles * 1.3 Potential Structures and Oscillations * Potential Structure Formed at a Constriction of a DC He Positive Column and its Coupling with Ionization Wave * Potential Structure in a New RF Magnetron Device with a Hollow Electrode * Potential Disruption in a RF Afterglow Electronegative Plasma * Potential Oscillation in a Strongly Asymmetry RF Discharge Containing Negative Ions * Effects of External Potential Control on Coulomb Dust Behavior * Potential Structure of Carbon Arc Discharge for High-Yield Fullerenes Formation * Control of Axial and Radial Potential Profiles in Tandem Mirrors (Invited) * CHAPTER 2: FIELD-ALIGNED ELECTRIC FIELDS AND RELATED PARTICLE ACCELERATIONS * 2.1 Field-Aligned Potential Formation * Formation of Large Potential Difference in a Plasma Flow along Converging Magnetic Field Lines (Invited) * Presheath Formation in front of an Oblique End-Plate in a Magnetized Sheet Plasma * Plasma Potential Formation Due to ECRH in a Magnetic Well * Electrostatic

  7. Improved Mechanical Compatibility and Cytocompatibility of Ta/Ti Double-Layered Composite Coating

    Science.gov (United States)

    Ding, Ding; Xie, Youtao; Li, Kai; Huang, Liping; Zheng, Xuebin

    2017-08-01

    In order to improve the mechanical compatibility and cytocompatibility of titanium implants, a composite coating with double layers composed of tantalum and titanium was designed and prepared using plasma spraying technology. In the composite coating, the upper tantalum layer provides a good biocompatibility, and the sublayer of titanium with a porous structure ensures the low elastic modulus. Results show that the fabricated composite coating exhibits a relatively low elastic modulus of 26.7 GPa, which is close to the elastic modulus of human cortical bone. In vitro cytocompatibility evaluation of the composite coating shows that the human bone marrow stromal cells exhibit enhanced adhesion and spreading performance on the double-layered composite coating in comparison with the single-layered titanium coating. In order to eliminate the misgivings of chemical stability of the composite coating in clinical application, electrochemical corrosion of the coating was examined. The results obtained revealed a very weak galvanic corrosion between the tantalum and titanium in the composite coating, which would ensure the safety of the coating in vivo.

  8. Fabrication and characterization of short-period double-layer cross-grating with holographic lithography

    Science.gov (United States)

    Lin, Cunbao; Yan, Shuhua; You, Fusheng

    2017-01-01

    A cross-grating with short period and double layer is designed, and a method combining holographic lithography and lithography-etch-lithography-etch is proposed to manufacture it. The scalar diffraction theory and the rigorous coupled wave analysis are employed to analyze the diffraction characteristics of the double-layer cross-grating (DLCG). It reveals that the efficiencies of the (±1,±1) orders possess perfect complementarity under normal incidence. The equivalent high efficiency for TE and TM polarization can be realized which means the high signal-to-noise ratio and fringe contrast can be simultaneously achieved for heterodyne grating interferometers (HGIs). Furthermore, a gold-coated DLCG with grating pitch of 2 μm and pattern area of 60 mm×60 mm etched on the quartz substrate is fabricated with the proposed method. The displacement resolution, measurement range and long-term stability can be reliably guaranteed for HGIs with this grating. The characteristics of the DLCG are also experimentally tested and compared with the theoretical analysis. Reasonable consistency is obtained and the capabilities of both the DLCG and the fabrication method are verified.

  9. Investigation of thermally stimulated properties of SHI beam irradiated polycarbonate/polystyrene double layered samples

    Science.gov (United States)

    Rathore, Bhupendra Singh; Gaur, Mulayam Singh; Singh, Kripa Shanker

    2011-12-01

    The double layered samples of polycarbonate/polystyrene (PC/PS) have been prepared by solvent casting method and irradiated with 55 MeV C 5+ beam at different ion fluences range from 1 × 10 11 to 1 × 10 13 ion/cm 2. The effect of swift heavy ion (SHI) beam in interfacial phenomena, phase change, dielectric relaxation, degradation temperature, stability, charge storage and transport mechanism of PC/PS pristine and irradiated double layered samples have been investigated by thermally stimulated discharge current (TSDC), differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). TSDC show α, β-relaxation peaks shifted to the lower temperatures side with increase of fluence. The activation energy and relaxation time decrease, while the depolarization current and charge released increase with increase in the ion fluences. DSC curve show the glass transition temperature ( T g) and heat capacity decreases with increase in the ion fluences. The TGA characteristics represent the thermal stability, which is found to be decreased with increase in the ion fluences.

  10. Self-consistent electrostatic simulations of reforming double layers in the downward current region of the aurora

    Energy Technology Data Exchange (ETDEWEB)

    Gunell, H.; Keyser, J. de [Belgian Institute for Space Aeronomy, Brussels (Belgium); Andersson, L. [Colorado Univ., Boulder, CO (United States). Lab. for Atmospheric and Space Physics; Mann, I. [EISCAT Scientific Association, Kiruna (Sweden); Umeaa Univ. (Sweden). Dept. of Physics

    2015-07-01

    The plasma on a magnetic field line in the downward current region of the aurora is simulated using a Vlasov model. It is found that an electric field parallel to the magnetic fields is supported by a double layer moving toward higher altitude. The double layer accelerates electrons upward, and these electrons give rise to plasma waves and electron phase-space holes through beam-plasma interaction. The double layer is disrupted when reaching altitudes of 1- 2 Earth radii where the Langmuir condition no longer can be satisfied due to the diminishing density of electrons coming up from the ionosphere. During the disruption the potential drop is in part carried by the electron holes. The disruption creates favourable conditions for double layer formation near the ionosphere and double layers form anew in that region. The process repeats itself with a period of approximately 1 min. This period is determined by how far the double layer can reach before being disrupted: a higher disruption altitude corresponds to a longer repetition period. The disruption altitude is, in turn, found to increase with ionospheric density and to decrease with total voltage. The current displays oscillations around a mean value. The period of the oscillations is the same as the recurrence period of the double layer formations. The oscillation amplitude increases with increasing voltage, whereas the mean value of the current is independent of voltage in the 100 to 800V range covered by our simulations. Instead, the mean value of the current is determined by the electron density at the ionospheric boundary.

  11. Thickness dependence of the levitation performance of double-layer high-temperature superconductor bulks above a magnetic rail

    Energy Technology Data Exchange (ETDEWEB)

    Sun, R.X.; Zheng, J.; Liao, X.L.; Che, T.; Gou, Y.F.; He, D.B.; Deng, Z.G., E-mail: zgdeng@gmail.com

    2014-10-15

    Highlights: • Thickness optimization of double-layer bulk HTSC arrangement is studied. • The new bulk HTSC arrangement makes better use of the flux distribution of the magnetic rails. • Levitation performance can be enhanced with the optimization. • The optimization can meet large levitation force requirements for HTS Maglev system. - Abstract: A double-layer high-temperature superconductor (HTSC) arrangement was proposed and proved to be able to bring improvements to both levitation force and guidance force compared with present single-layer HTSC arrangement. To fully exploit the applied magnetic field by a magnetic rail, the thickness dependence of a double-layer HTSC arrangement on the levitation performance was further investigated in the paper. In this study, the lower-layer bulk was polished step by step to different thicknesses, and the upper-layer bulk with constant thickness was directly superimposed on the lower-layer one. The levitation force and the force relaxation of the double-layer HTSC arrangement were measured above a Halbach magnetic rail. Experimental result shows that a bigger levitation force and a less levitation force decay could be achieved by optimizing the thickness of the lower-layer bulk HTSC. This thickness optimization method could be applied together with former reported double-layer HTSC arrangement method with aligned growth sector boundaries pattern. This series of study on the optimized combination method do bring a significant improvement on the levitation performance of present HTS maglev systems.

  12. Double-layer indium doped zinc oxide for silicon thin-film solar cell prepared by ultrasonic spray pyrolysis

    Institute of Scientific and Technical Information of China (English)

    Jiao Bao-Chen; Zhang Xiao-Dan; Wei Chang-Chun; Sun Jian; Ni Jian; Zhao Ying

    2011-01-01

    Indium doped zinc oxide (ZnO:In) thin films were prepared by ultrasonic spray pyrolysis on corning eagle 2000 glass substrate. 1 and 2 at.% indium doped single-layer ZnO:In thin films with different amounts of acetic acid added in the initial solution were fabricated. The 1 at.% indium doped single-layers have triangle grains. The 2 at.% indium doped single-layer with 0.18 acetic acid adding has the resistivity of 6.82 × 10-3 Ω· cm and particle grains. The double-layers structure is designed to fabricate the ZnO:In thin film with low resistivity (2.58×10-3 Ω· cm) and good surface morphology. It is found that the surface morphology of the double-layer ZnO:In film strongly depends on the substrate-layer, and the second-layer plays a large part in the resistivity of the double-layer ZnO:In thin film. Both total and direct transmittances of the double-layer ZnO:In film are above 80% in the visible light region. Single junction a-Si:H solar cell based on the double-layer ZnO:In as front electrode is also investigated.

  13. Double-Layer Gadolinium Zirconate/Yttria-Stabilized Zirconia Thermal Barrier Coatings Deposited by the Solution Precursor Plasma Spray Process

    Science.gov (United States)

    Jiang, Chen; Jordan, Eric H.; Harris, Alan B.; Gell, Maurice; Roth, Jeffrey

    2015-08-01

    Advanced thermal barrier coatings (TBCs) with lower thermal conductivity, increased resistance to calcium-magnesium-aluminosilicate (CMAS), and improved high-temperature capability, compared to traditional yttria-stabilized zirconia (YSZ) TBCs, are essential to higher efficiency in next generation gas turbine engines. Double-layer rare-earth zirconate/YSZ TBCs are a promising solution. From a processing perspective, solution precursor plasma spray (SPPS) process with its unique and beneficial microstructural features can be an effective approach to obtaining the double-layer microstructure. Previously durable low-thermal-conductivity YSZ TBCs with optimized layered porosity, called the inter-pass boundaries (IPBs) were produced using the SPPS process. In this study, an SPPS gadolinium zirconate (GZO) protective surface layer was successfully added. These SPPS double-layer TBCs not only retained good cyclic durability and low thermal conductivity, but also demonstrated favorable phase stability and increased surface temperature capabilities. The CMAS resistance was evaluated with both accumulative and single applications of simulated CMAS in isothermal furnaces. The double-layer YSZ/GZO exhibited dramatic improvement in the single application, but not in the continuous one. In addition, to explore their potential application in integrated gasification combined cycle environments, double-layer TBCs were tested under high-temperature humidity and encouraging performance was recorded.

  14. Design and Testing of an Active Core for Sandwich Panels

    Science.gov (United States)

    2008-03-01

    structures such as the Kagome truss (Hutchinson, Wicks et al. 2003; Symons, Hutchinson et al. 2005) holds potential in the design of morphing structures that...New Yourk, John Wiley and Sons, Inc. Hutchinson, R. G., N. Wicks, et al. (2003). " Kagome plate structures for actuation." International Journal of...Optimization 12(2): 18. Symons, D. D., R. G. Hutchinson, et al. (2005). "Actuation of the Kagome double layer grid part 1: Prediction of performance

  15. Double layer formation in the expanding region of an inductively coupled electronegative plasma

    CERN Document Server

    Plihon, N; Chabert, P

    2015-01-01

    Double-layers (DLs) were observed in the expanding region of an inductively coupled plasma with $\\text{Ar}/\\text{SF}\\_6$ gas mixtures. No DL was observed in pure argon or $\\text{SF}\\_6$ fractions below few percent. They exist over a wide range of power and pressure although they are only stable for a small window of electronegativity (typically between 8\\% and 13\\% of $\\text{SF}\\_6$ at 1mTorr), becoming unstable at higher electronegativity. They seem to be formed at the boundary between the source tube and the diffusion chamber and act as an internal boundary (the amplitude being roughly 1.5$\\frac{kT\\_e}{e}$)between a high electron density, high electron temperature, low electronegativity plasma upstream (in the source), and a low electron density, low electron temperature, high electronegativity plasma downstream.

  16. Tunable multi-band chiral metamaterials based on double-layered asymmetric split ring resonators

    Science.gov (United States)

    Jia, Xiuli; Wang, Xiaoou; Meng, Qingxin; Zhou, Zhongxiang

    2016-07-01

    We have numerically demonstrated chiral metamaterials based on double-layered asymmetric Au film with hollow out design of split ring resonators on either side of the polyimide. Multiple electric dipoles and magnetic dipoles resulted from parallel and antiparallel currents between the eight split ring resonators. Multi-band circular dichroism is found in the visible frequency regime by studying the transmission properties. Huge optical activity and the induced multi-band negative refractive index are obtained at resonance by calculating the optical activity and ellipticity of the transmitted E-fields. Chirality parameter and effective refractive index are retrieved to illustrate the tunable optical properties of the metamaterials. The underlying mechanisms for the observed circular dichroism are analyzed. These metamaterials would offer flexible electromagnetic applications in the infrared and visible regime.

  17. Up and down translocation events and electric double-layer formation inside solid-state nanopores.

    Science.gov (United States)

    Zanjani, Mehdi B; Engelke, Rebecca E; Lukes, Jennifer R; Meunier, Vincent; Drndić, Marija

    2015-08-01

    We present a theoretical study of nanorod translocation events through solid-state nanopores of different sizes which result in positive or negative ion conductance changes. Using theoretical models, we show that positive conductance changes or up events happen for nanopore diameters smaller than a transition diameter dt, and negative conductance changes or down events occur for nanopore diameters larger than dt. We investigate the underlying physics of such translocation phenomena and describe the significance of the electric double-layer effects for nanopores with small diameters. Furthermore, for nanopores with large diameters, it is shown that a geometric model, formulated based on the nanoparticle blockade inside the nanopore, provides a straightforward and reasonably accurate prediction of ion conductance change. Based on this concept, we also implement a method to distinguish and detect nanorods of different sizes by focusing solely on the sign and not the exact value of the conductance change.

  18. A double-layer based model of ion confinement in electron cyclotron resonance ion source

    Energy Technology Data Exchange (ETDEWEB)

    Mascali, D., E-mail: davidmascali@lns.infn.it; Neri, L.; Celona, L.; Castro, G.; Gammino, S.; Ciavola, G. [Istituto Nazionale di Fisica Nucleare, Laboratori Nazionali del Sud, via S. Sofia 62, 95123 Catania (Italy); Torrisi, G. [Istituto Nazionale di Fisica Nucleare, Laboratori Nazionali del Sud, via S. Sofia 62, 95123 Catania (Italy); Università Mediterranea di Reggio Calabria, Dipartimento di Ingegneria dell’Informazione, delle Infrastrutture e dell’Energia Sostenibile, Via Graziella, I-89100 Reggio Calabria (Italy); Sorbello, G. [Istituto Nazionale di Fisica Nucleare, Laboratori Nazionali del Sud, via S. Sofia 62, 95123 Catania (Italy); Università degli Studi di Catania, Dipartimento di Ingegneria Elettrica Elettronica ed Informatica, Viale Andrea Doria 6, 95125 Catania (Italy)

    2014-02-15

    The paper proposes a new model of ion confinement in ECRIS, which can be easily generalized to any magnetic configuration characterized by closed magnetic surfaces. Traditionally, ion confinement in B-min configurations is ascribed to a negative potential dip due to superhot electrons, adiabatically confined by the magneto-static field. However, kinetic simulations including RF heating affected by cavity modes structures indicate that high energy electrons populate just a thin slab overlapping the ECR layer, while their density drops down of more than one order of magnitude outside. Ions, instead, diffuse across the electron layer due to their high collisionality. This is the proper physical condition to establish a double-layer (DL) configuration which self-consistently originates a potential barrier; this “barrier” confines the ions inside the plasma core surrounded by the ECR surface. The paper will describe a simplified ion confinement model based on plasma density non-homogeneity and DL formation.

  19. Investigation of Interface between Ge Electrodes and Ionic Liquid Electrolytes for Electric Double Layer Capacitors

    Science.gov (United States)

    Abeysinghe, R. M.; Oguchi, H.; Kuwano, H.

    2016-11-01

    This study discusses novel way of use of ionic liquids to develop Ge-based electrodes for electric double layer capacitors (EDLC). We found that ionic liquids change their electrochemical properties depending on the amount of the absorbed water. Wet ionic liquids work as solvents to dissolve Ge and make porous structures, whereas dry ones work as electrolytes of the EDLCs. The former property was used to increase surface area of the electrodes which is desired to increase the capacity of EDLCs. This method showed another advantage in contrast to the dry ionic liquids; wet ones could fill the complex Ge pores in parallel to porous structure formation. Finally, after porous formation, we dried the ionic liquid at 100 °C and prepared the EDLCs composed of Ge porous electrodes. Cyclic voltammetry and impedance measurements indicated that the obtained devices can work as EDLCs.

  20. Electron-acoustic solitary pulses and double layers in multi-component plasmas

    CERN Document Server

    Mannan, A; Shukla, P K

    2013-01-01

    We consider the nonlinear propagation of fi?nite amplitude electron-acoustic waves (EAWs) in multi-component plasmas composed of two distinct groups of electrons (cold and hot components), and non-isothermal ions. We use the continuity and momentum equations for cold inertial electrons, Boltzmann law for inertialess hot electrons, non-isothermal density distribution for hot ions, and Poisson's equation to derive an energy integral with a modi?ed Sagdeev potential (MSP) for nonlinear EAWs. The MSP is analyzed to demonstrate the existence of arbitrary amplitude EA solitary pulses (EASPs) and EA double layers (EA-DLs). Small amplitude limits have also been considered and analytical results for EASPs and EA-DLs are presented. The implication of our results to space and laboratory plasmas is briely discussed.

  1. A micro-structured Si-based electrodes for high capacity electrical double layer capacitors

    Science.gov (United States)

    Krikscikas, Valdas; Oguchi, Hiroyuki; Yanazawa, Hiroshi; Hara, Motoaki; Kuwano, Hiroki

    2014-11-01

    We challenged to make basis for Si electrodes of electric double layer capacitors (EDLC) used as a power source of micro-sensor nodes. Mcroelectromechanical systems (MEMS) processes were successfully introduced to fabricate micro-structured Si-based electrodes to obtain high surface area which leads to high capacity of EDLCs. Study of fundamental properties revealed that the microstructured electrodes benefit from good wettability to electrolytes, but suffer from electric resistance. We found that this problem can be solved by metal-coating of the electrode surface. Finally we build an EDLC consisting of Au-coated micro-structured Si electrodes. This EDLC showed capacity of 14.3 mF/cm2, which is about 530 times larger than that of an EDLC consisting of flat Au electrodes.

  2. One-step Double-layer Thermal Evaporation Method for Organic Light Emitting Diodes

    Science.gov (United States)

    Kee, Y. Y.; Yong, T. K.; Ong, D. S.; Tou, T. Y.

    2011-03-01

    A new one-step double-layer thermal evaporation method was used to fabricate organic light emitting diodes (OLEDs) with device structure of: ITO (anode)/N,N_-diphenyl-N,N_-bis(3-methylphenyl)-1,1_-diphenyl-4,4_-diamine (TPD) /tris-(8-hydroxyquinoline)aluminum(3) (Alq3)/Al (cathode). These OLEDs were fabricated in cleanroom on the ITO-coated glass with a sheet resistivity of 20Ω/sq and an optical transmittance of 90%. The I-V and brightness characteristic showed that the new method could produce better performance achieving lower turn-on voltage (-2V), higher peak current efficiency (+29%) and higher brightness (+36%).

  3. Carbon-Nanotube-Based Electrochemical Double-Layer Capacitor Technologies for Spaceflight Applications

    Science.gov (United States)

    Arepalli, S.; Fireman, H.; Huffman, C.; Maloney, P.; Nikolaev, P.; Yowell, L.; Kim, K.; Kohl, P. A.; Higgins, C. D.; Turano, S. P.

    2005-01-01

    Electrochemical double-layer capacitors, or supercapacitors, have tremendous potential as high-power energy sources for use in low-weight hybrid systems for space exploration. Electrodes based on single-wall carbon nanotubes (SWCNTs) offer exceptional power and energy performance due to the high surface area, high conductivity, and the ability to functionalize the SWCNTs to optimize capacitor properties. This paper will report on the preparation of electrochemical capacitors incorporating SWCNT electrodes and their performance compared with existing commercial technology. Preliminary results indicate that substantial increases in power and energy density are possible. The effects of nanotube growth and processing methods on electrochemical capacitor performance is also presented. The compatibility of different SWCNTs and electrolytes was studied by varying the type of electrolyte ions that accumulate on the high-surface-area electrodes.

  4. A 130 GHz Electro-Optic Ring Modulator with Double-Layer Graphene

    Directory of Open Access Journals (Sweden)

    Lei Wu

    2017-02-01

    Full Text Available The optical absorption coefficient of graphene will change after injecting carriers. Based on this principle, a high-speed double-layer graphene electro-optic modulator with a ring resonator structure was designed in this paper. From the numerical simulations, we designed a modulator. Its optical bandwidth is larger than 130 GHz, the switching energy is 0.358 fJ per bit, and the driven voltage is less than 1.2 V. At the same time, the footprint of the proposed modulator is less than 10 microns squared, which makes the process compatible with the Complementary Metal Oxide Semiconductors (CMOS process. This will provide the possibility for the on-chip integration of the photoelectric device.

  5. Using a double-layered palmaris longus tendon for suspension of facial paralysis

    DEFF Research Database (Denmark)

    Toyserkani, Navid Mohamadpour; Bakholdt, Vivi; Sørensen, Jens Ahm

    2015-01-01

    INTRODUCTION: Facial palsy is a debilitating condition entailing both cosmetic and functional limitations. Static suspension procedures can be performed when more advanced dynamic techniques are not indicated. Since 2006, we have used a double-layered palmaris longus tendon graft through an ovular...... follow-up of 49 months (range: 3-89 months). 93% noted an improvement of their facial appearance at follow-up. Seven out of 11 patients with preoperative problems with speech noted an improvement at follow-up. Eight out of 12 patients with preoperative problems with oral competence noted an improvement......, and it improves the quality of life of patients with facial palsy. It is an acceptable alternative when more advanced procedures are not indicated. FUNDING: not relevant. TRIAL REGISTRATION: not relevant....

  6. Molecular Simulations of Graphene-Based Electric Double-Layer Capacitors

    Science.gov (United States)

    Kalluri, Raja K.; Konatham, Deepthi; Striolo, Alberto

    2011-03-01

    Towards deploying renewable energy sources it is crucial to develop efficient and cost-effective technologies to store electricity. Traditional batteries are plagued by a number of practical problems that at present limit their widespread applicability. One possible solution is represented by electric double-layer capacitors (EDLCs). To deploy EDLCs at the large scale it is necessary to better understand how electrolytes pack and diffuse within narrow charged pores. We present here simulation results for the concentrated aqueous solutions of NaCl, CsCl, and NaI confined within charged graphene-based porous materials. We discuss how the structure of confined water, the salt concentration, the ions size, and the surface charge density determine the accumulation of electrolytes within the porous network. Our results, compared to data available for bulk systems, are critical for relating macroscopic observations to molecular-level properties of the confined working fluids. Research supported by the Department of Energy.

  7. Reciprocity in spatial evolutionary public goods game on double-layered network

    Science.gov (United States)

    Kim, Jinho; Yook, Soon-Hyung; Kim, Yup

    2016-08-01

    Spatial evolutionary games have mainly been studied on a single, isolated network. However, in real world systems, many interaction topologies are not isolated but many different types of networks are inter-connected to each other. In this study, we investigate the spatial evolutionary public goods game (SEPGG) on double-layered random networks (DRN). Based on the mean-field type arguments and numerical simulations, we find that SEPGG on DRN shows very rich interesting phenomena, especially, depending on the size of each layer, intra-connectivity, and inter-connected couplings, the network reciprocity of SEPGG on DRN can be drastically enhanced through the inter-connected coupling. Furthermore, SEPGG on DRN can provide a more general framework which includes the evolutionary dynamics on multiplex networks and inter-connected networks at the same time.

  8. Secondary Activation of Commercial Activated Carbon and its Application in Electric Double Layer Capacitor

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    The cheap commercial activated carbon (AC) was improved through the secondary activation under steam in the presence of FeCl2 catalyst in the temperature range of 800-950℃ and its application in electric double layer capacitors (EDLCs) with organic electrolyte was studied. The re-activation of AC results in the increases in both specific capacitance and high rate capability of EDLCs. For AC treated under optimized conditions, its discharge specific capacitance increases up to 55.65 F/g, an increase of about 33% as compared to the original AC, and the high rate capability was increased significantly. The good performances of EDLC with improved AC were correlated to the increasing mesoporous ratio.

  9. Large-amplitude ion-acoustic double layers in multispecies plasma

    Science.gov (United States)

    Jain, S. L.; Tiwari, R. S.; Sharma, S. R.

    1990-06-01

    The effect of second-ion species on the characteristics of large-amplitude ion-acoustic double layers (IADL) in a collisionless, unmagnetized plasma (consisting of hot and cold Maxwellian populations of electrons and two cold-ion species with different masses, concentrations, and charge states) is investigated. After deriving the criteria for the existence of large-amplitude IADL, it is found that the presence of a positive-ion impurity does not considerably modify the characteristics of large-amplitude IADL. However, the presence of negative-ion impurity significantly changes the characteristics of a large-amplitude IADL. An analytic discussion of small-amplitude IADL using a reductive perturbation method is also presented.

  10. Theoretical analysis of transverse impact response in double layer graphene sheets

    Directory of Open Access Journals (Sweden)

    Toshiaki Natsuki

    2016-01-01

    Full Text Available In designing future nanoscale devices or nanostructures as new element in structural mechanics, it is very important to predict the responses for these elements against various mechanical loading conditions. In this letter, an analytical solution of the impact response in double layer graphene sheets (DLGSs is presented using a continuum mechanics theory. In this analytical model, the DLGSs are considered as a layer stack of two individual graphene sheet (GS bound together by van der Waals (vdW forces. The influence of impact velocity and mass on the impact response are predicted by using numerical simulation. The result shows that impact response of GSs subjected to nanomass has exceedingly short times with picoseconds order.

  11. Study on Electric Double Layer of a Cylindrical Particle with Functional Theoretical Approach

    Institute of Scientific and Technical Information of China (English)

    WANG,Zheng-Wu; LIU,Xue-Min; YU,Hui-Xin; ZHOU,Ming; JIN,Jian

    2007-01-01

    A new method, i.e. the iterative method in functional theory, was introduced to solve analytically the nonlinear Poisson-Boltzmann (PB) equation under general potential ψ condition for the electric double layer of a charged cylindrical colloid particle in a symmetrical electrolyte solution. The iterative solutions of ψ are expressed as functions of the distance from the axis of the particle with solution parameters: the concentration of ions c, the aggregation number of ions in a unit length m, the dielectric constant ε, the system temperature T and so on. The relative errors show that generally only the first and the second iterative solutions can give accuracy higher than 97%. From the second iterative solution the radius and the surface potential of a cylinder have been defined and the corresponding values have been estimated with the solution parameters. Furthermore, the charge density, the activity coefficient of ions and the osmotic coefficient of solvent were also discussed.

  12. Cooperation of micro- and meso-porous carbon electrode materials in electric double-layer capacitors

    Energy Technology Data Exchange (ETDEWEB)

    Zheng, Cheng [State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 5625 Renmin Street, Changchun 130022, Jilin Province (China); Graduate University of Chinese Academy of Sciences, Beijing 100039 (China); Qi, Li; Wang, Hongyu [State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 5625 Renmin Street, Changchun 130022, Jilin Province (China); Yoshio, Masaki [Advanced Research Center, Saga University, 1341 Yoga-machi, Saga 840-0047 (Japan)

    2010-07-01

    The capacitive characteristics of micro- and meso-porous carbon materials have been compared in cyclic voltammetric studies and galvanostatic charge-discharge tests. Meso-porous carbon can keep certain high capacitance values at high scan rates, whereas micro-porous carbon possesses very high capacitance values at low scan rates but fades quickly as the scan rate rises up. For better performance of electric double-layer capacitors (EDLCs), the cooperative application of both kinds of carbon materials has been proposed in the following two ways: mixing both kinds of carbons in the same electrode or using the asymmetric configuration of carbon electrodes in the same EDLC. The cooperative effect on the electrochemical performance has also been addressed. (author)

  13. Spreading of Electrolyte Drops on Charged Surfaces: Electric Double Layer Effects on Drop Dynamics

    Science.gov (United States)

    Bae, Kyeong; Sinha, Shayandev; Chen, Guang; Das, Siddhartha

    2015-11-01

    Drop spreading is one of the most fundamental topics of wetting. Here we study the spreading of electrolyte drops on charged surfaces. The electrolyte solution in contact with the charged solid triggers the formation of an electric double layer (EDL). We develop a theory to analyze how the EDL affects the drop spreading. The drop dynamics is studied by probing the EDL effects on the temporal evolution of the contact angle and the base radius (r). The EDL effects are found to hasten the spreading behaviour - this is commensurate to the EDL effects causing a ``philic'' tendency in the drops (i.e., drops attaining a contact angle smaller than its equilibrium value), as revealed by some of our recent papers. We also develop scaling laws to illustrate the manner in which the EDL effects make the r versus time (t) variation deviate from the well known r ~tn variation, thereby pinpointing the attainment of different EDL-mediated spreading regimes.

  14. Rational design of new electrolyte materials for electrochemical double layer capacitors

    Science.gov (United States)

    Schütter, Christoph; Husch, Tamara; Viswanathan, Venkatasubramanian; Passerini, Stefano; Balducci, Andrea; Korth, Martin

    2016-09-01

    The development of new electrolytes is a centerpiece of many strategies to improve electrochemical double layer capacitor (EDLC) devices. We present here a computational screening-based rational design approach to find new electrolyte materials. As an example application, the known chemical space of almost 70 million compounds is investigated in search of electrochemically more stable solvents. Cyano esters are identified as especially promising new compound class. Theoretical predictions are validated with subsequent experimental studies on a selected case. These studies show that based on theoretical predictions only, a previously untested, but very well performing compound class was identified. We thus find that our rational design strategy is indeed able to successfully identify completely new materials with substantially improved properties.

  15. Toward high-energy laser-driven ion beams: Nanostructured double-layer targets

    Science.gov (United States)

    Passoni, M.; Sgattoni, A.; Prencipe, I.; Fedeli, L.; Dellasega, D.; Cialfi, L.; Choi, Il Woo; Kim, I. Jong; Janulewicz, K. A.; Lee, Hwang Woon; Sung, Jae Hee; Lee, Seong Ku; Nam, Chang Hee

    2016-06-01

    The development of novel target concepts is crucial to make laser-driven acceleration of ion beams suitable for applications. We tested double-layer targets formed of an ultralow density nanostructured carbon layer (˜7 mg/cm 3 , 8 - 12 μ m -thick) deposited on a μ m -thick solid Al foil. A systematic increase in the total number of the accelerated ions (protons and C6 + ) as well as enhancement of both their maximum and average energies was observed with respect to bare solid foil targets. Maximum proton energies up to 30 MeV were recorded. Dedicated three-dimensional particle-in-cell simulations were in remarkable agreement with the experimental results, giving clear indication of the role played by the target nanostructures in the interaction process.

  16. Design, fabrication and characterization of a double layer solid oxide fuel cell (DLFC)

    Science.gov (United States)

    Wang, Guangjun; Wu, Xiangying; Cai, Yixiao; Ji, Yuan; Yaqub, Azra; Zhu, Bin

    2016-11-01

    A double layer solid oxide fuel cell (DLSOFC) without using the electrolyte (layer) has been designed by integrating advantages of positive electrode material of lithium ion battery(LiNi0.8Co0.15Al0.05O2) and oxygen-permeable membranes material (trace amount cobalt incorporated terbium doped ceria, TDC + Co) based on the semiconductor physics principle. Instead of using an electrolyte layer, the depletion layer between the anode and cathode served as an electronic insulator to block the electrons but to maintain the electrolyte function for ionic transport. Thus the device with two layers can realize the function of SOFC and at the same time avoids the electronic short circuiting problem. Such novel DLFC showed good performance at low temperatures, for instance, a maximum power density of 230 mWcm-2 was achieved at 500 °C. The working principle of the new device is presented.

  17. Si/Ge double-layered nanotube array as a lithium ion battery anode.

    Science.gov (United States)

    Song, Taeseup; Cheng, Huanyu; Choi, Heechae; Lee, Jin-Hyon; Han, Hyungkyu; Lee, Dong Hyun; Yoo, Dong Su; Kwon, Moon-Seok; Choi, Jae-Man; Doo, Seok Gwang; Chang, Hyuk; Xiao, Jianliang; Huang, Yonggang; Park, Won Il; Chung, Yong-Chae; Kim, Hansu; Rogers, John A; Paik, Ungyu

    2012-01-24

    Problems related to tremendous volume changes associated with cycling and the low electron conductivity and ion diffusivity of Si represent major obstacles to its use in high-capacity anodes for lithium ion batteries. We have developed a group IVA based nanotube heterostructure array, consisting of a high-capacity Si inner layer and a highly conductive Ge outer layer, to yield both favorable mechanics and kinetics in battery applications. This type of Si/Ge double-layered nanotube array electrode exhibits improved electrochemical performances over the analogous homogeneous Si system, including stable capacity retention (85% after 50 cycles) and doubled capacity at a 3C rate. These results stem from reduced maximum hoop strain in the nanotubes, supported by theoretical mechanics modeling, and lowered activation energy barrier for Li diffusion. This electrode technology creates opportunities in the development of group IVA nanotube heterostructures for next generation lithium ion batteries.

  18. Double-Layer Magnetic Nanoparticle-Embedded Silica Particles for Efficient Bio-Separation.

    Directory of Open Access Journals (Sweden)

    San Kyeong

    Full Text Available Superparamagnetic Fe3O4 nanoparticles (NPs based nanomaterials have been exploited in various biotechnology fields including biomolecule separation. However, slow accumulation of Fe3O4 NPs by magnets may limit broad applications of Fe3O4 NP-based nanomaterials. In this study, we report fabrication of Fe3O4 NPs double-layered silica nanoparticles (DL MNPs with a silica core and highly packed Fe3O4 NPs layers. The DL MNPs had a superparamagnetic property and efficient accumulation kinetics under an external magnetic field. Moreover, the magnetic field-exposed DL MNPs show quantitative accumulation, whereas Fe3O4 NPs single-layered silica nanoparticles (SL MNPs and silica-coated Fe3O4 NPs produced a saturated plateau under full recovery of the NPs. DL MNPs are promising nanomaterials with great potential to separate and analyze biomolecules.

  19. The Comparison of Engineering Properties Between Single and Double Layer Porous Asphalt made of Packing Gradation

    Directory of Open Access Journals (Sweden)

    Hardiman M. Y

    2008-01-01

    Full Text Available is paper presents the comparison of engineering properties between single and double layer porous asphalt (SLPA and DLPA made of packing gradation. Three nominal maximum aggregate sizes (NMAS were tested each made up of 10, 14, and 20 mm for SLPA. While for the DLPA with 30, 20, and 15 mm top layer are made of 10 and 14 mm NMAS, with a base layer of 20 mm NMAS. Total thickness of all mixes is 70 mm. Binders used are 60/70 penetration base bitumen and polymer binder styrene-butadiene-styrene (SBS. The result shows that the properties of SLPA mix namely permeability and resistance to abrasion loss decreases when the NMAS in SLPA decreases. The abrasion loss of DLPA mixes increases when the porous asphalt top layer thickness decreases, while drainage time value decreases. However, SLPA with 20 mm NMAS exhibits higher abrasion loss compared to all DLPA mixes.

  20. Large-area WSe2 electric double layer transistors on a plastic substrate

    KAUST Repository

    Funahashi, Kazuma

    2015-04-27

    Due to the requirements for large-area, uniform films, currently transition metal dichalcogenides (TMDC) cannot be used in flexible transistor industrial applications. In this study, we first transferred chemically grown large-area WSe2 monolayer films from the as-grown sapphire substrates to the flexible plastic substrates. We also fabricated electric double layer transistors using the WSe2 films on the plastic substrates. These transistors exhibited ambipolar operation and an ON/OFF current ratio of ∼104, demonstrating chemically grown WSe2 transistors on plastic substrates for the first time. This achievement can be an important first step for the next-generation TMDC based flexible devices. © 2015 The Japan Society of Applied Physics.

  1. Role of nonthermal electrons on dust ion acoustic double layer with variable dust charge

    Science.gov (United States)

    Borah, Prathana; Gogoi, Deepshikha; Das, Nilakshi

    2016-01-01

    The presence of nonthermal electron may play an important role in the formation of nonlinear structures in plasma. On the other hand, fluctuation of dust charge is an important and unique feature of complex plasma and it gives rise to a dissipative effect in the system leading to the formation of nonlinear structures due to the balance between nonlinearity and dissipation. In this paper, the propagation of nonlinear dust ion acoustic (DIA) wave in unmagnetized collisionless dusty plasma consisting of ions, nonthermal electrons and dust grains with variable negative charge has been investigated using the Sagdeev potential method. The existence domain of rarefactive double layer (DL) in the DIA wave has been investigated for the range of plasma parameters. The real potential has been obtained by numerically solving the Poisson equation and dust charging equation. It is observed that the presence of nonthermal electrons strengthens the DIA DL.

  2. Synthesis of carbon fibers with branched nanographene sheets for electrochemical double layer capacitor application.

    Science.gov (United States)

    Matsushima, Masahiro; Kalita, Golap; Kato, Kimitoshi; Noda, Mikio; Uchida, Hideo; Wakita, Koichi; Umeno, Masayoshi; Tanemura, Masaki

    2014-03-01

    We demonstrate a one step technique to synthesis the carbon fibers (CNFs) with branched nanographene sheets by the pulsed discharge (PD) plasma chemical vapor deposition (CVD) process. Highly crystalline branched nanographene sheets were directly grown from the surface of the carbon fibers to obtain a three dimensional (3D) nanostructure. The growth process can be explained from the catalyst support growth of the CNFs, and subsequently nucleation and growth of the nanographene sheets from the crystalline surface of the CNF. The deposited nanostructured films with different pulse discharge were used as an electrode for electrochemical double-layer capacitors (EDLC). It is observed that the capacitance is dependent on the morphology of the electrode materials and an optimum capacitance is obtained with the branched nanographene on CNFs.

  3. Impedance analysis of porous carbon electrodes to predict rate capability of electric double-layer capacitors

    Science.gov (United States)

    Yoo, Hyun Deog; Jang, Jong Hyun; Ryu, Ji Heon; Park, Yuwon; Oh, Seung M.

    2014-12-01

    Electrochemical impedance analysis is performed to predict the rate capability of two commercial activated carbon electrodes (RP20 and MSP20) for electric double-layer capacitor. To this end, ac impedance data are fitted with an equivalent circuit that comprises ohmic resistance and impedance of intra-particle pores. To characterize the latter, ionic accessibility into intra-particle pores is profiled by using the fitted impedance parameters, and the profiles are transformed into utilizable capacitance plots as a function of charge-discharge rate. The rate capability that is predicted from the impedance analysis is well-matched with that observed from a charge-discharge rate test. It is found that rate capability is determined by ionic accessibility as well as ohmic voltage drop. A lower value in ionic accessibility for MSP20 is attributed to smaller pore diameter, longer length, and higher degree of complexity in pore structure.

  4. Electric double layer at the interface of ionic liquid-dielectric liquid under electric field.

    Science.gov (United States)

    Lee, D W; Im, D J; Kang, I S

    2013-02-12

    The structure of the electric double layer (EDL) is analyzed in order to understand the electromechanical behavior of the interface of ionic liquid-dielectric liquid. The modified Poisson-Boltzmann equation proposed by Bazant et al. is solved to see the crowding and the overscreening effects that are the characteristics of an ionic liquid (Bazant, M. Z.; Storey, B. D.; Kornyshev, A. A. Double layer in ionic liquids: Overscreening versus crowding. Phys. Rev. Lett. 2011, 106, 046102.). From the simple one-dimensional (1-D) analysis, it is found that the changes of the composition and the material properties in the EDL are negligible except under some extreme conditions such as strong electric field over O(10(8)) V/m. From the electromechanical view points, an ionic liquid behaves like a pure conductor at the interface with a dielectric liquid. Based on these findings, three specific application problems are considered. In the first, a new method is suggested for measuring the interfacial tension of an ionic liquid-dielectric liquid system. The deformation of a charged ionic liquid droplet translating between two electrodes is used for this measurement. The second is for the Taylor cone problem, which includes an extreme electric field condition near the tip. The size of the critical region, where the EDL effect should be considered, is estimated by using the 1-D analysis result. Numerical computation is also performed to see the profiles of electric potential and the electric stress along the interface of the Taylor cone. Lastly, the electrowetting problem of the ionic liquid is considered. The discrepancies in the results of previous workers are interpreted by using the results of the present work. It is shown that all the results might be consistent if the leaking of the dielectric layer and/or the adsorption of ions is considered.

  5. Evaluation of molecular dynamics simulation methods for ionic liquid electric double layers

    Science.gov (United States)

    Haskins, Justin B.; Lawson, John W.

    2016-05-01

    We investigate how systematically increasing the accuracy of various molecular dynamics modeling techniques influences the structure and capacitance of ionic liquid electric double layers (EDLs). The techniques probed concern long-range electrostatic interactions, electrode charging (constant charge versus constant potential conditions), and electrolyte polarizability. Our simulations are performed on a quasi-two-dimensional, or slab-like, model capacitor, which is composed of a polarizable ionic liquid electrolyte, [EMIM][BF4], interfaced between two graphite electrodes. To ensure an accurate representation of EDL differential capacitance, we derive new fluctuation formulas that resolve the differential capacitance as a function of electrode charge or electrode potential. The magnitude of differential capacitance shows sensitivity to different long-range electrostatic summation techniques, while the shape of differential capacitance is affected by charging technique and the polarizability of the electrolyte. For long-range summation techniques, errors in magnitude can be mitigated by employing two-dimensional or corrected three dimensional electrostatic summations, which led to electric fields that conform to those of a classical electrostatic parallel plate capacitor. With respect to charging, the changes in shape are a result of ions in the Stern layer (i.e., ions at the electrode surface) having a higher electrostatic affinity to constant potential electrodes than to constant charge electrodes. For electrolyte polarizability, shape changes originate from induced dipoles that soften the interaction of Stern layer ions with the electrode. The softening is traced to ion correlations vertical to the electrode surface that induce dipoles that oppose double layer formation. In general, our analysis indicates an accuracy dependent differential capacitance profile that transitions from the characteristic camel shape with coarser representations to a more diffuse

  6. Molecular dynamics simulation studies of ionic liquid electrolytes for electric double layer capacitors

    Science.gov (United States)

    Hu, Zongzhi

    Molecular Dynamics (MD) simulation has been performed on various Electric Double Layer Capacitors (EDLCs) systems with different Room Temperature Ionic Liquids (RTILs) as well as different structures and materials of electrodes using a computationally efficient, low cost, united atom (UA)/explicit atom (EA) force filed. MD simulation studies on two 1-butyl-3-methylimidazolium (BMIM) based RTILs, i.e., [BMIM][BF4] and [BMIM][PF6], have been conducted on both atomic flat and corrugated graphite as well as (001) and (011) gold electrode surfaces to understand the correlations between the Electric Double Layer (EDL) structure and their corresponding differential capacitance (DC). Our MD simulations have strong agreement with some experimental data. The structures of electrodes also have a strong effect on the capacitance of EDLCs. MD simulations have been conducted on RTILs of N-methyl-N- propylpyrrolidinium [pyr13] and bis(fluorosulfonyl)imide (FSI) as well as [BMIM][PF6] on both curvature electrodes (fullerenes, nanotube, nanowire) and atomic flat electrode surfaces. It turns out that the nanowire electrode systems have the largest capacitance, following by fullerene systems. Nanotube electrode systems have the smallest capacitance, but they are still larger than that of atomically flat electrode system. Also, RTILs with slightly different chemical structure such as [Cnmim], n = 2, 4, 6, and 8, FSI and bis(trifluoromethylsulfonyl)imide (TFSI), have been examined by MD simulation on both flat and nonflat graphite electrode surfaces to study the effect of cation and anion's chemical structures on EDL structure and DC. With prismatic (nonflat) graphite electrodes, a transition from a bell-shape to a camel-shape DC dependence on electrode potential was observed with increase of the cation alkyl tail length for FSI systems. In contrast, the [Cnmim][TFSI] ionic liquids generated only a camel-shape DC on the rough surface regardless of the length of alkyl tail.

  7. Transmission upper limit of band-pass double-layer FSS and method of transmission performance improvement

    Institute of Scientific and Technical Information of China (English)

    Minjie Huang; Zhijun Meng

    2015-01-01

    The transmission upper limit of a double-layer frequency selective surface (FSS) with two infinitely thin metal arrays is pre-sented based on the study of the general equivalent transmission line model of a double-layer FSS. Results of theoretical analyses, numerical simulations and experiments show that this transmis-sion upper limit is independent of the array and the element, which indicates that it is impossible to achieve a transmission upper limit higher than this one under a given incident and dielectric-supporting condition by the design of the periodic array. Both the applicable condition and the possible application of the transmis-sion upper limit are discussed. The results show that the transmis-sion upper limit not only has a good reachability, but also provides a key to effectively improve the transmission performance of a double-layer FSS or more complex frequency selective structures.

  8. Ion-acoustic double layers in a five component cometary plasma with kappa described electrons and ions

    Science.gov (United States)

    Michael, Manesh; Venugopal, C.; Sreekala, G.; Willington, Neethu Theresa; Sebastian, Sijo

    2016-07-01

    We investigate the propagation characteristics of Ion-acoustic solitons and double layers in a five component cometary plasma consisting of positively and negatively charged oxygen ions, kappa described hydrogen ions, hot solar electrons, and slightly colder cometary electrons. The KdV and modified KdV equations are derived for the system and its solution is plotted for different kappa values and negatively charged oxygen ion densities. It is found that the strength of double layer increases with increasing spectral indices. It, however, decreases with increasing negatively charged oxygen ion densities. The parameter for the transition from compressive to rarefactive soliton is also specified. The presence of negatively charged oxygen ions can significantly affect the nonlinearity coefficients (both quadratic and cubic) of a double layer.

  9. Magnetic phase diagrams of classical triangular and kagome antiferromagnets

    Energy Technology Data Exchange (ETDEWEB)

    Gvozdikova, M V [Department of Physics, Kharkov National University, 61077 Kharkov (Ukraine); Melchy, P-E; Zhitomirsky, M E, E-mail: mike.zhitomirsky@cea.fr [Service de Physique Statistique, Magnetisme et Supraconductivite, UMR-E9001 CEA-INAC/UJF, 17 rue des Martyrs, 38054 Grenoble (France)

    2011-04-27

    We investigate the effect of geometrical frustration on the H-T phase diagrams of the classical Heisenberg antiferromagnets on triangular and kagome lattices. The phase diagrams for the two models are obtained from large-scale Monte Carlo simulations. For the kagome antiferromagnet, thermal fluctuations are unable to lift degeneracy completely and stabilize translationally disordered multipolar phases. We find a substantial difference in the temperature scales of the order by disorder effect related to different degeneracy of the low- and the high-field classical ground states in the kagome antiferromagnet. In the low-field regime, the Kosterlitz-Thouless transition into a spin-nematic phase is produced by unbinding of half-quantum vortices.

  10. Unconventional fermi surface instabilities in the kagome Hubbard model.

    Science.gov (United States)

    Kiesel, Maximilian L; Platt, Christian; Thomale, Ronny

    2013-03-22

    We investigate the competing Fermi surface instabilities in the kagome tight-binding model. Specifically, we consider on-site and short-range Hubbard interactions in the vicinity of van Hove filling of the dispersive kagome bands where the fermiology promotes the joint effect of enlarged density of states and nesting. The sublattice interference mechanism devised by Kiesel and Thomale [Phys. Rev. B 86, 121105 (2012)] allows us to explain the intricate interplay between ferromagnetic fluctuations and other ordering tendencies. On the basis of the functional renormalization group used to obtain an adequate low-energy theory description, we discover finite angular momentum spin and charge density wave order, a twofold degenerate d-wave Pomeranchuk instability, and f-wave superconductivity away from van Hove filling. Together, this makes the kagome Hubbard model the prototypical scenario for several unconventional Fermi surface instabilities.

  11. Small-Pitch Kagome Hollow-Core Photonic Crystal Fibre

    Institute of Scientific and Technical Information of China (English)

    MENG Jia; HOU Lan-Tian; ZHOU Gui-Yao; WANG Kang; CHEN Chao

    2008-01-01

    @@ A hollow-core photonic crystal fibre (HC-PCF) based on small-pitch kagome lattice cladding is designed and fabricated. The pitch of the fibre is only 2.45 μm and it corresponds to a region of low normalized frequency which has never been investigated before. Both experiments and calculations show that this kagome HC-PCF has a broad optical transmission band from 400 nm to 900 nm, covering the whole visible and near infrared region of the spectrum. Additionally, the loss curve of the fibre is fiat in the visible region and the minimum of the loss achieves 0.16d B/m, which is lower than the loss of the kagome HC-PCFs reported before. Furthermore, this fibre can well confine the modes in the air core. No surface modes can be detected in the surrounding silica of the hollow core.

  12. Design of a Kagome lattice from soft anisotropic particles.

    Science.gov (United States)

    Fejer, Szilard N; Wales, David J

    2015-09-07

    We present a simple model of triblock Janus particles based on discoidal building blocks, which can form energetically stabilized Kagome structures. We find 'magic number' global minima in small clusters whenever particle numbers are compatible with a perfect Kagome structure, without constraining the accessible three-dimensional configuration space. The preference for planar structures with two bonds per patch among all other possible minima on the landscape is enhanced when sedimentation forces are included. For the building blocks in question, structures containing three bonds per patch become progressively higher in energy compared to Kagome structures as sedimentation forces increase. Rearrangements between competing structures, as well as ring formation mechanisms are characterised and found to be highly cooperative.

  13. Space Group Symmetry Fractionalization in a Chiral Kagome Heisenberg Antiferromagnet.

    Science.gov (United States)

    Zaletel, Michael P; Zhu, Zhenyue; Lu, Yuan-Ming; Vishwanath, Ashvin; White, Steven R

    2016-05-13

    The anyonic excitations of a spin liquid can feature fractional quantum numbers under space group symmetries. Detecting these fractional quantum numbers, which are analogs of the fractional charge of Laughlin quasiparticles, may prove easier than the direct observation of anyonic braiding and statistics. Motivated by the recent numerical discovery of spin-liquid phases in the kagome Heisenberg antiferromagnet, we theoretically predict the pattern of space group symmetry fractionalization in the kagome lattice SO(3)-symmetric chiral spin liquid. We provide a method to detect these fractional quantum numbers in finite-size numerics which is simple to implement in the density matrix renormalization group. Applying these developments to the chiral spin liquid phase of a kagome Heisenberg model, we find perfect agreement between our theoretical prediction and numerical observations.

  14. Vibrational Properties of a Two-Dimensional Silica Kagome Lattice.

    Science.gov (United States)

    Björkman, Torbjörn; Skakalova, Viera; Kurasch, Simon; Kaiser, Ute; Meyer, Jannik C; Smet, Jurgen H; Krasheninnikov, Arkady V

    2016-12-27

    Kagome lattices are structures possessing fascinating magnetic and vibrational properties, but in spite of a large body of theoretical work, experimental realizations and investigations of their dynamics are scarce. Using a combination of Raman spectroscopy and density functional theory calculations, we study the vibrational properties of two-dimensional silica (2D-SiO2), which has a kagome lattice structure. We identify the signatures of crystalline and amorphous 2D-SiO2 structures in Raman spectra and show that, at finite temperatures, the stability of 2D-SiO2 lattice is strongly influenced by phonon-phonon interaction. Our results not only provide insights into the vibrational properties of 2D-SiO2 and kagome lattices in general but also suggest a quick nondestructive method to detect 2D-SiO2.

  15. Magnetic phase diagrams of classical triangular and kagome antiferromagnets.

    Science.gov (United States)

    Gvozdikova, M V; Melchy, P-E; Zhitomirsky, M E

    2011-04-27

    We investigate the effect of geometrical frustration on the H-T phase diagrams of the classical Heisenberg antiferromagnets on triangular and kagome lattices. The phase diagrams for the two models are obtained from large-scale Monte Carlo simulations. For the kagome antiferromagnet, thermal fluctuations are unable to lift degeneracy completely and stabilize translationally disordered multipolar phases. We find a substantial difference in the temperature scales of the order by disorder effect related to different degeneracy of the low- and the high-field classical ground states in the kagome antiferromagnet. In the low-field regime, the Kosterlitz-Thouless transition into a spin-nematic phase is produced by unbinding of half-quantum vortices.

  16. Single mode propagation through a terahertz kagome microstructured fiber

    Science.gov (United States)

    Anthony, Jessienta; Leonhardt, Rainer; Argyros, Alexander; Leon-Saval, Sergio

    2011-08-01

    We report measurements for hollow core kagome microstructured Terahertz (THz) fiber characterized with the THz-time domain spectroscopy (THz-TDS). To achieve good mode overlap between the input beam and the fiber mode distribution, we incorporate specially designed THz lenses in our experimental setup. The experimental observations show that only the fundamental mode is guided in the fiber core. The time domain scans and their spectral information show air-guidance over a large frequency range from 0.6 to at least 1.1 THz. Within this frequency bandwidth, low transmission amplitudes at certain frequencies are identified as the frequency cut-offs for the kagome structure is observed. The measured transmission of the kagome fibers shows the characteristics of the inhibited coupling mechanism. We estimate high coupling efficiencies, as high as 60%, have been achieved in our experiments.

  17. Sub-Grid Modeling of Electrokinetic Effects in Micro Flows

    Science.gov (United States)

    Chen, C. P.

    2005-01-01

    Advances in micro-fabrication processes have generated tremendous interests in miniaturizing chemical and biomedical analyses into integrated microsystems (Lab-on-Chip devices). To successfully design and operate the micro fluidics system, it is essential to understand the fundamental fluid flow phenomena when channel sizes are shrink to micron or even nano dimensions. One important phenomenon is the electro kinetic effect in micro/nano channels due to the existence of the electrical double layer (EDL) near a solid-liquid interface. Not only EDL is responsible for electro-osmosis pumping when an electric field parallel to the surface is imposed, EDL also causes extra flow resistance (the electro-viscous effect) and flow anomaly (such as early transition from laminar to turbulent flow) observed in pressure-driven microchannel flows. Modeling and simulation of electro-kinetic effects on micro flows poses significant numerical challenge due to the fact that the sizes of the double layer (10 nm up to microns) are very thin compared to channel width (can be up to 100 s of m). Since the typical thickness of the double layer is extremely small compared to the channel width, it would be computationally very costly to capture the velocity profile inside the double layer by placing sufficient number of grid cells in the layer to resolve the velocity changes, especially in complex, 3-d geometries. Existing approaches using "slip" wall velocity and augmented double layer are difficult to use when the flow geometry is complicated, e.g. flow in a T-junction, X-junction, etc. In order to overcome the difficulties arising from those two approaches, we have developed a sub-grid integration method to properly account for the physics of the double layer. The integration approach can be used on simple or complicated flow geometries. Resolution of the double layer is not needed in this approach, and the effects of the double layer can be accounted for at the same time. With this

  18. Electron Doping a Kagome Spin Liquid

    Science.gov (United States)

    Kelly, Z. A.; Gallagher, M. J.; McQueen, T. M.

    2016-10-01

    Herbertsmithite, ZnCu3 (OH )6Cl2 , is a two-dimensional kagome lattice realization of a spin liquid, with evidence for fractionalized excitations and a gapped ground state. Such a quantum spin liquid has been proposed to underlie high-temperature superconductivity and is predicted to produce a wealth of new states, including a Dirac metal at 1 /3 electron doping. Here, we report the topochemical synthesis of electron-doped ZnLix Cu3 (OH )6Cl2 from x =0 to x =1.8 (3 /5 per Cu2 + ). Contrary to expectations, no metallicity or superconductivity is induced. Instead, we find a systematic suppression of magnetic behavior across the phase diagram. Our results demonstrate that significant theoretical work is needed to understand and predict the role of doping in magnetically frustrated narrow band insulators, particularly the interplay between local structural disorder and tendency toward electron localization, and pave the way for future studies of doped spin liquids.

  19. Localized modes in nonlinear binary kagome ribbons.

    Science.gov (United States)

    Beličev, P P; Gligorić, G; Radosavljević, A; Maluckov, A; Stepić, M; Vicencio, R A; Johansson, M

    2015-11-01

    The localized mode propagation in binary nonlinear kagome ribbons is investigated with the premise to ensure controlled light propagation through photonic lattice media. Particularity of the linear system characterized by the dispersionless flat band in the spectrum is the opening of new minigaps due to the "binarism." Together with the presence of nonlinearity, this determines the guiding mode types and properties. Nonlinearity destabilizes the staggered rings found to be nondiffracting in the linear system, but can give rise to dynamically stable ringlike solutions of several types: unstaggered rings, low-power staggered rings, hour-glass-like solutions, and vortex rings with high power. The type of solutions, i.e., the energy and angular momentum circulation through the nonlinear lattice, can be controlled by suitable initial excitation of the ribbon. In addition, by controlling the system "binarism" various localized modes can be generated and guided through the system, owing to the opening of the minigaps in the spectrum. All these findings offer diverse technical possibilities, especially with respect to the high-speed optical communications and high-power lasers.

  20. A Kagome Map of Spin Liquidsx

    Science.gov (United States)

    Essafi, Karim; Benton, Owen; Jaubert, Ludovic D. C.

    Competing interactions in frustrated magnets prevent ordering down to very low temperatures and stabilize exotic highly degenerate phases where strong correlations coexist with fluctuations. We study a very general nearest-neighbour Heisenberg spin model Hamiltonian on the kagome lattice which consist of Dzyaloshinskii-Moriya, ferro- and antiferromagnetic interactions. We present a three-fold mapping which transforms the well-known Heisenberg antiferromagnet (HAF) and XXZ model onto two lines of time-reversal Hamiltonians. The mapping is exact for both classical and quantum spins, i.e. preserves the energy spectrums of the HAF and XXZ model. As a consequence, our three-fold mapping gives rise to a connected network of quantum spin liquids centered around the Ising antiferromagnet. We show that this quantum disorder spreads over an extended region of the phase diagram at linear order in spin wave theory, which overlaps with the parameter region of Herbertsmithite ZnCu3(OH)6Cl2. At the classical level, all the phases have an extensively degenerate ground-state which present a variety of properties such as ferromagnetically induced pinch points in the structure factor and spontaneous scalar chirality which was absent in the original HAF and XXZ models. This work was supported by the Okinawa Institute of Science and Technology Graduate University.

  1. Determination of effective mechanical properties of a double-layer beam by means of a nano-electromechanical transducer

    Energy Technology Data Exchange (ETDEWEB)

    Hocke, Fredrik; Pernpeintner, Matthias; Gross, Rudolf, E-mail: rudolf.gross@wmi.badw.de [Walther-Meißner-Institut, Bayerische Akademie der Wissenschaften, D-85748 Garching (Germany); Nanosystems Initiative Munich, D-80799 München (Germany); Physik-Department, Technische Universität München, D-85748 Garching (Germany); Zhou, Xiaoqing; Kippenberg, Tobias J. [École Polytechnique Fédérale de Lausanne, CH-1015 Lausanne (Switzerland); Schliesser, Albert [École Polytechnique Fédérale de Lausanne, CH-1015 Lausanne (Switzerland); Niels Bohr Institute, University of Copenhagen, DK-2100 Copenhagen (Denmark); Huebl, Hans, E-mail: hans.huebl@wmi.badw.de [Walther-Meißner-Institut, Bayerische Akademie der Wissenschaften, D-85748 Garching (Germany); Nanosystems Initiative Munich, D-80799 München (Germany)

    2014-09-29

    We investigate the mechanical properties of a doubly clamped, double-layer nanobeam embedded into an electromechanical system. The nanobeam consists of a highly pre-stressed silicon nitride and a superconducting niobium layer. By measuring the mechanical displacement spectral density both in the linear and the nonlinear Duffing regime, we determine the pre-stress and the effective Young's modulus of the nanobeam. An analytical double-layer model quantitatively corroborates the measured values. This suggests that this model can be used to design mechanical multilayer systems for electro- and optomechanical devices, including materials controllable by external parameters such as piezoelectric, magnetostrictive, or in more general multiferroic materials.

  2. Using copper substrate to enhance electron field emission properties of carbon nanotube/diamond double-layered structure

    Science.gov (United States)

    Yang, Lezhi; Sujith Kumar, C. S.; Li, Yuan-shi; Niakan, Hamid; Zhang, Chunzi; Hirose, Akira; Aravind, Suresh; Yang, Qiaoqin

    2015-01-01

    Vertically aligned carbon nanotube (CNT)/diamond double-layered structure was synthesized on copper (Cu) substrate by hot-filament chemical vapor deposition. The structure was characterized by scanning electron microscopy, transmission electron microscopy, and Raman spectroscopy. The results show that the diamond layer has good adhesion to the Cu substrate and the CNTs have direct contact with the diamond layer. Field electron emission measurement shows that the double-layered structure on copper has very good emission stability and a much lower turn-on field than that on silicon (Si).

  3. Kagome network compounds and their novel magnetic properties.

    Science.gov (United States)

    Pati, Swapan K; Rao, C N R

    2008-10-21

    Compounds possessing the Kagome network are truly interesting because of their unusual low-energy properties. They exhibit magnetic frustration because of the triangular lattice inherent to the hexagonal bronze structure they possess, as indeed demonstrated by some of the Fe(3+) jarosites, but this is not the general case. Kagome compounds formed by transition metal ions with varying spins exhibit novel magnetic properties, some even showing evidence for magnetic order and absence of frustration. We describe the structure and magnetic properties of this interesting class of materials and attempt to provide an explanation for the variety of properties on the basis of theoretical considerations.

  4. Domain-wall spin dynamics in kagome antiferromagnets.

    Science.gov (United States)

    Lhotel, E; Simonet, V; Ortloff, J; Canals, B; Paulsen, C; Suard, E; Hansen, T; Price, D J; Wood, P T; Powell, A K; Ballou, R

    2011-12-16

    We report magnetization and neutron scattering measurements down to 60 mK on a new family of Fe based kagome antiferromagnets, in which a strong local spin anisotropy combined with a low exchange path network connectivity lead to domain walls intersecting the kagome planes through strings of free spins. These produce unfamiliar slow spin dynamics in the ordered phase, evolving from exchange-released spin flips towards a cooperative behavior on decreasing the temperature, probably due to the onset of long-range dipolar interaction. A domain structure of independent magnetic grains is obtained that could be generic to other frustrated magnets.

  5. 双层Boussinesq水波方程%A Double-layer Depth-averaged Boussinesq Model for Water Wave

    Institute of Scientific and Technical Information of China (English)

    刘忠波; 房克照; 吕林

    2015-01-01

    从Laplace方程出发,推导了一组适应于波浪在非平整地形上传播的双层Boussinesq水波方程,方程以双层水深积分平均速度表达且具有二阶全非线性特征。通过在动量方程中引入高阶色散项和非线性项进一步提高了方程的色散性和非线性性能。常水深情况下,分析了方程的色散关系和二阶波幅传递函数,并与Stokes解析解进行了比较。结果表明,在0.3%误差下方程可适用水深达kh≈6,在此水深范围内二阶波幅传递函数误差在10%以内。在非交错网格下,建立了基于有限差分方法和混合4阶Adams-Bashforth-Moulton时间积分格式的一维数值模型,模拟了波浪在潜堤上的传播变形,并与实验结果进行了对比,吻合程度较好。%A double-layer depth-averaged Boussinesq-type model for wave propagation over an un-even bottom is derived. The governing equations are formulated in two depth-averaged velocities within each water layer and of the second-order fully nonlinearity. To improve the model properties, high-er-order terms are introduced to momentum equations and theoretical analyses are made to investi-gate the linear dispersive and nonlinear properties. The optimized model equations show good dis-persion property up to kh≈6 within 0.3%error, and the second nonlinear characteristics are optimized to kh≈6 within 10%error. Based on finite difference method and a composite fourth order Adams-Bashforth-Moulton time integration, one-dimensional equations are solved numerically on non-stag-gered grids. Regular wave evolution over a submerged breakwater is simulated and the computation-al results are compared with the experimental data, the good agreements are found.

  6. New Approach for High-Voltage Electrical Double-Layer Capacitors Using Vertical Graphene Nanowalls with and without Nitrogen Doping.

    Science.gov (United States)

    Chi, Yu-Wen; Hu, Chi-Chang; Shen, Hsiao-Hsuan; Huang, Kun-Ping

    2016-09-14

    Integrating various devices to achieve high-performance energy storage systems to satisfy various demands in modern societies become more and more important. Electrical double-layer capacitors (EDLCs), one kind of the electrochemical capacitors, generally provide the merits of high charge-discharge rates, extremely long cycle life, and high efficiency in electricity capture/storage, leading to a desirable device of electricity management from portable electronics to hybrid vehicles or even smart grid application. However, the low cell voltage (2.5-2.7 V in organic liquid electrolytes) of EDLCs lacks the direct combination of Li-ion batteries (LIBs) and EDLCs for creating new functions in future applications without considering the issue of a relatively low energy density. Here we propose a guideline, "choosing a matching pair of electrode materials and electrolytes", to effectively extend the cell voltage of EDLCs according to three general strategies. Based on the new strategy proposed in this work, materials with an inert surface enable to tolerate a wider potential window in commercially available organic electrolytes in comparison with activated carbons (ACs). The binder-free, vertically grown graphene nanowalls (GNW) and nitrogen-doped GNW (NGNW) electrodes respectively provide good examples for extending the upper potential limit of a positive electrode of EDLCs from 0.1 to 1.5 V (vs Ag/AgNO3) as well as the lower potential limit of a negative electrode of EDLCs from -2.0 V to ca. -2.5 V in 1 M TEABF4/PC (propylene carbonate) compared to ACs. This newly designed asymmetric EDLC exhibits a cell voltage of 4 V, specific energy of 52 Wh kg(-1) (ca. a device energy density of 13 Wh kg(-1)), and specific power of 8 kW kg(-1) and ca. 100% retention after 10,000 cycles charge-discharge, reducing the series number of EDLCs to enlarge the module voltage and opening the possibility for directly combining EDLCs and LIBs in advanced applications.

  7. Building high-efficiency CdS/CdSe-sensitized solar cells with a hierarchically branched double-layer architecture.

    Science.gov (United States)

    Zhu, Zonglong; Qiu, Jianhang; Yan, Keyou; Yang, Shihe

    2013-05-22

    We report a double-layer architecture for a photoanode of quantum-dot-sensitized solar cells (QDSSCs), which consists of a ZnO nanorod array (NR) underlayer and a ZnO nanotetrapod (TP) top layer. Such double-layer and branching strategies have significantly increased the power conversion efficiency (PCE) to as high as 5.24%, nearly reaching the record PCE of QDSSCs based on TiO2. Our systematic studies have shown that the double-layer strategy could significantly reduce charge recombination at the interface between the charge collection anode (FTO) and ZnO nanostructure because of the strong and compact adhesion of the NRs and enhance charge transport due to the partially interpenetrating contact between the NR and TP layers, leading to improved open-circuit voltage (Voc) and short-circuit current density (Jsc). Also, when the double layer was subjected to further branching, a large increase in Jsc and, to a lesser extent, the fill factor (FF) has resulted from increases in quantum-dot loading, enhanced light scattering, and reduced series resistance.

  8. Thickness dependence of the levitation performance of double-layer high-temperature superconductor bulks above a magnetic rail

    Science.gov (United States)

    Sun, R. X.; Zheng, J.; Liao, X. L.; Che, T.; Gou, Y. F.; He, D. B.; Deng, Z. G.

    2014-10-01

    A double-layer high-temperature superconductor (HTSC) arrangement was proposed and proved to be able to bring improvements to both levitation force and guidance force compared with present single-layer HTSC arrangement. To fully exploit the applied magnetic field by a magnetic rail, the thickness dependence of a double-layer HTSC arrangement on the levitation performance was further investigated in the paper. In this study, the lower-layer bulk was polished step by step to different thicknesses, and the upper-layer bulk with constant thickness was directly superimposed on the lower-layer one. The levitation force and the force relaxation of the double-layer HTSC arrangement were measured above a Halbach magnetic rail. Experimental result shows that a bigger levitation force and a less levitation force decay could be achieved by optimizing the thickness of the lower-layer bulk HTSC. This thickness optimization method could be applied together with former reported double-layer HTSC arrangement method with aligned growth sector boundaries pattern. This series of study on the optimized combination method do bring a significant improvement on the levitation performance of present HTS maglev systems.

  9. Variable Charge and Electrical Double Layer of Mineral-Water Interfaces: Silver Halides versus Metal (Hydr)Oxides

    NARCIS (Netherlands)

    Hiemstra, T.

    2012-01-01

    Classically, silver (Ag) halides have been used to understand thermodynamic principles of the charging process and the corresponding development of the electrical double layer (EDL). A mechanistic approach to the processes on the molecular level has not yet been carried out using advanced surface co

  10. Evidence of double layer/capacitive charging in carbon nanomaterial-based solid contact polymeric ion-selective electrodes.

    Science.gov (United States)

    Cuartero, Maria; Bishop, Josiah; Walker, Raymart; Acres, Robert G; Bakker, Eric; De Marco, Roland; Crespo, Gaston A

    2016-08-11

    This paper presents the first direct spectroscopic evidence for double layer or capacitive charging of carbon nanomaterial-based solid contacts in all-solid-state polymeric ion-selective electrodes (ISEs). Here, we used synchrotron radiation-X-ray photoelectron spectroscopy (SR-XPS) and SR valence band (VB) spectroscopy in the elucidation of the charging mechanism of the SCs.

  11. Development and design of double-layer co-injection moulded soy protein based drug delivery devices

    NARCIS (Netherlands)

    Vaz, C.M.; Doeveren, van P.F.N.M.; Reis, R.L.; Cunha, A.M.

    2003-01-01

    Novel double-layer delivery devices based on soy protein derived materials were designed and produced using an innovative two material co-injection moulding technique. It was demonstrated that the viscosity ratio between core and skin layer materials played an important role in the formation of the

  12. On the theory of electric double layer with explicit account of a polarizable co-solvent.

    Science.gov (United States)

    Budkov, Yu A; Kolesnikov, A L; Kiselev, M G

    2016-05-14

    We present a continuation of our theoretical research into the influence of co-solvent polarizability on a differential capacitance of the electric double layer. We formulate a modified Poisson-Boltzmann theory, using the formalism of density functional approach on the level of local density approximation taking into account the electrostatic interactions of ions and co-solvent molecules as well as their excluded volume. We derive the modified Poisson-Boltzmann equation, considering the three-component symmetric lattice gas model as a reference system and minimizing the grand thermodynamic potential with respect to the electrostatic potential. We apply present modified Poisson-Boltzmann equation to the electric double layer theory, showing that accounting for the excluded volume of co-solvent molecules and ions slightly changes the main result of our previous simplified theory. Namely, in the case of small co-solvent polarizability with its increase under the enough small surface potentials of electrode, the differential capacitance undergoes the significant growth. Oppositely, when the surface potential exceeds some threshold value (which is slightly smaller than the saturation potential), the increase in the co-solvent polarizability results in a differential capacitance decrease. However, when the co-solvent polarizability exceeds some threshold value, its increase generates a considerable enhancement of the differential capacitance in a wide range of surface potentials. We demonstrate that two qualitatively different behaviors of the differential capacitance are related to the depletion and adsorption of co-solvent molecules at the charged electrode. We show that an additive of the strongly polarizable co-solvent to an electrolyte solution can shift significantly the saturation potential in two qualitatively different manners. Namely, a small additive of strongly polarizable co-solvent results in a shift of saturation potential to higher surface potentials. On

  13. Magnetic properties of doped kagomé antiferromagnet

    Science.gov (United States)

    Koretsune, Takashi; Ogata, Masao

    In order to clarify the carrier doping effect in the frustrated system, we study the t-J model on the kagomé lattice using high-temperature expansion method. As in the triangular lattice [T. Koretsune, M. Ogata, Phys. Rev. Lett. 89 (2002) 116401], the sign of hopping integral t is important in the kagomé lattice. When tOgata, J. Phys. Soc. Japan 72 (2003) 2437]. On the contrary, in the case of t>0, it is found that uniform spin susceptibility is strongly suppressed with hole doping. The peak of spin susceptibility, which is expected to be around T=J/20 in the Heisenberg model, goes to high temperature region. Furthermore, short-range magnetic correlation is enhanced with hole doping. This is interesting since nearest-neighbor spin correlation without hole doping itself is strongly enhanced by quantum fluctuation. These behavior are qualitatively similar to those of the triangular lattice. However, the difference from non-frustrated lattices as square lattice is more prominent in the kagomé lattice, which is related to the fact that frustration in the kagomé lattice is strong enough to destabilize the magnetic order in the Heisenberg model even at T=0.

  14. No crystallization to honeycomb or Kagome in free space

    Energy Technology Data Exchange (ETDEWEB)

    Grivopoulos, Symeon [Department of Mechanical Engineering, University of California, Santa Barbara, CA 93106-5070 (United States)

    2009-03-20

    It is intuitive that if an infinite system of particles that interact through an isotropic potential has a crystalline ground state at zero chemical potential, it is of high symmetry. Here, we present an argument why a honeycomb or a Kagome structure cannot be the ground state at zero chemical potential, for a large class of potentials in R{sup 2}.

  15. Langevin-Poisson-EQT: A dipolar solvent based quasi-continuum approach for electric double layers

    Science.gov (United States)

    Mashayak, S. Y.; Aluru, N. R.

    2017-01-01

    Water is a highly polar solvent. As a result, electrostatic interactions of interfacial water molecules play a dominant role in determining the distribution of ions in electric double layers (EDLs). Near a surface, an inhomogeneous and anisotropic arrangement of water molecules gives rise to pronounced variations in the electrostatic and hydration energies of ions. Therefore, a detailed description of the structural and dielectric properties of water is important to study EDLs. However, most theoretical models ignore the molecular effects of water and treat water as a background continuum with a uniform dielectric permittivity. Explicit consideration of water polarization and hydration of ions is both theoretically and numerically challenging. In this work, we present an empirical potential-based quasi-continuum theory (EQT) for EDL, which incorporates the polarization and hydration effects of water explicitly. In EQT, water molecules are modeled as Langevin point dipoles and a point dipole based coarse-grained model for water is developed systematically. The space dependence of the dielectric permittivity of water is included in the Poisson equation to compute the electrostatic potential. In addition, to reproduce hydration of ions, ion-water coarse-grained potentials are developed. We demonstrate the EQT framework for EDL by simulating NaCl aqueous electrolyte confined inside slit-like capacitor channels at various ion concentrations and surface charge densities. We show that the ion and water density predictions from EQT agree well with the reference molecular dynamics simulations.

  16. An Optical Wavefront Sensor Based on a Double Layer Microlens Array

    Directory of Open Access Journals (Sweden)

    Hsiang-Chun Wei

    2011-10-01

    Full Text Available In order to determine light aberrations, Shack-Hartmann optical wavefront sensors make use of microlens arrays (MLA to divide the incident light into small parts and focus them onto image planes. In this paper, we present the design and fabrication of long focal length MLA with various shapes and arrangements based on a double layer structure for optical wavefront sensing applications. A longer focal length MLA could provide high sensitivity in determining the average slope across each microlens under a given wavefront, and spatial resolution of a wavefront sensor is increased by numbers of microlenses across a detector. In order to extend focal length, we used polydimethysiloxane (PDMS above MLA on a glass substrate. Because of small refractive index difference between PDMS and MLA interface (UV-resin, the incident light is less refracted and focused in further distance. Other specific focal lengths could also be realized by modifying the refractive index difference without changing the MLA size. Thus, the wavefront sensor could be improved with better sensitivity and higher spatial resolution.

  17. Electrical Double-Layer Capacitors in Hybrid Topologies —Assessment and Evaluation of Their Performance

    Directory of Open Access Journals (Sweden)

    Joeri Van Mierlo

    2012-11-01

    Full Text Available PHEVs and BEVs make use of battery cells optimized for high energy rather than for high power. This means that the power abilities of these batteries are limited. In order to enhance their performance, a hybrid Rechargeable Energy Storage System (RESS architecture can be used combining batteries with electrical-double layer capacitors (EDLCs. Such a hybridized architecture can be accomplished using passive or active systems. In this paper, the characteristics of these topologies have been analyzed and compared based on a newly developed hybridization simulation tool for association of lithium-ion batteries and EDLCs. The analysis shows that the beneficial impact of the EDLCs brings about enhanced battery performances in terms of energy efficiency and voltage drops, rather than extension of vehicle range. These issues have been particularly studied for the passive and active hybrid topologies. The classical passive and active topologies being expensive and less beneficial in term of cost, volume and weight, a new hybrid configuration based on the parallel combination of lithium-ion and EDLCs on cell level has been proposed in this article. This topology allows reducing cost, volume, and weight and system complexity in a significant way. Furthermore, a number of experimental setups have illustrated the power of the novel topology in terms of battery capacity increase and power capabilities during charging and discharging. Finally, a unique cycle life test campaign demonstrated that the lifetime of highly optimized lithium-ion batteries can be extended up to 30%–40%.

  18. Numerical simulation of proton distribution with electric double layer in extended nanospaces.

    Science.gov (United States)

    Chang, Chih-Chang; Kazoe, Yutaka; Morikawa, Kyojiro; Mawatari, Kazuma; Yang, Ruey-Jen; Kitamori, Takehiko

    2013-05-01

    Understanding the properties of liquid confined in extended nanospaces (10-1000 nm) is crucial for nanofluidics. Because of the confinement and surface effects, water may have specific structures and reveals unique physicochemical properties. Recently, our group has developed a super resolution laser-induced fluorescence (LIF) technique to visualize proton distribution with the electrical double layer (EDL) in a fused-silica extended nanochannel (Kazoe, Y.; Mawatari, K.; Sugii, Y.; Kitamori, T. Anal. Chem.2011, 83, 8152). In this study, based on the coupling of the Poisson-Boltzmann theory and site-dissociation model, the effect of specific water properties in an extended nanochannel on formation of EDL was investigated by comparison of numerical results with our previous experimental results. The numerical results of the proton distribution with a lower dielectric constant of approximately 17 were shown to be in good agreement with our experimental results, which confirms our previous observation showing a lower water permittivity in an extended nanochannel. In addition, the higher silanol deprotonation rate in extended nanochannels was also demonstrated, which is supported by our previous results of NMR and streaming current measurements. The present results will be beneficial for a further understanding of interfacial chemistry, fluid physics, and electrokinetics in extended nanochannels.

  19. Evolution of Multiple Double Layer in Glow discharge and its inherent Properties

    Science.gov (United States)

    Alex, Prince; A, Saravanan; Sinha, Suraj

    2016-10-01

    Formation and evolution of multiple anodic double layers (MADLs) were experimentally studied in glow discharge plasma. The boundary condition for the existence of MADL was identified in terms of threshold bias and ambient working pressure. The MADL formation is accompanied by an explosive growth in anode current and consequent current-voltage characteristics follows a hysteresis loop. The analysis yield that stable MADLs is only observed when the control voltage V2 is between a certain critical values (Vq > νte MADL completely transforms to an intense high current carrying unstable anode glow. The floating potential analysis carried out using three axially positioned electrostatic probes shows a bipolar signature of DL with as the control parameter is varied. The floating potential analysis also shows that hysteresis arises due to the difference in magnitude of electric field required to align the space charges in the DL sheet at the control voltage changes forward and backward. The effect of pressure on MADL indicates that the MADL structure advances towards anode surface as the pressure is increases. The power dumped (W) in the MADL is estimated to decrease with increase in pressure while the same increase in the anode glow.

  20. Evaluation of Constant Potential Method in Simulating Electric Double-Layer Capacitors

    CERN Document Server

    Wang, Zhenxing; Olmsted, David L; Asta, Mark; Laird, Brian B

    2014-01-01

    A major challenge in the molecular simulation of electric double layer capacitors (ELDCs) is the choice of an appropriate model for the electrode. Typically, in such simulations the electrode surface is modeled using a uniform fixed charge on each of the electrode atoms, which ignores the electrode response to local charge fluctuations induced by charge fluctuations in the electrolyte. In this work, we evaluate and compare this Fixed Charge Method (FCM) with the more realistic Constant Potential Method (CPM), [Reed, et al., J. Chem. Phys., 126, 084704 (2007)], in which the electrode charges fluctuate in order to maintain constant electric potential in each electrode. For this comparison, we utilize a simplified LiClO$_4$-acetonitrile/graphite EDLC. At low potential difference ($\\Delta\\Psi\\le 2V$), the two methods yield essentially identical results for ion and solvent density profiles; however, significant differences appear at higher $\\Delta\\Psi$. At $\\Delta\\Psi\\ge 4V$, the CPM ion density profiles show sign...

  1. Electrochemical cell studies based on non-aqueous magnesium electrolyte for electric double layer capacitor applications

    Energy Technology Data Exchange (ETDEWEB)

    Chandrasekaran, Ramasamy; Ishikawa, Masashi [Department of Chemistry and Materials Engineering, Faculty of Chemistry, Materials and Bioengineering, Kansai University, 3-3-35 Yamate-cho, Suita 564-8680 (Japan); Koh, Meiten; Yamauchi, Akiyoshi [Chemical Division, Fundamental Research Department, Daikin Industries Ltd., 1-1 Nishihitotsuya, Settsu 565-8585 (Japan)

    2010-01-15

    Performances of electric double layer capacitors (EDLCs) based on an activated carbon electrode with acetonitrile (ACN), propylene carbonate (PC), or a ternary electrolyte, i.e., PC:ethylene carbonate (EC):diethyl carbonate (DEC), at 1 mol dm{sup -3} of magnesium perchlorate [Mg(ClO{sub 4}){sub 2}] salt have been investigated. The electrochemical responses were studied by impedance spectroscopy, cyclic voltammetry, and galvanostatic charge-discharge experiments at 25 C in a three-electrode configuration. For a comparative evaluation, lithium perchlorate (LiClO{sub 4}) salt-based systems were also evaluated. All the observed results showed typical EDLC characteristics within the potential range between 0 and 1 V vs. an Ag/Ag{sup +} reference electrode. The Mg-based systems exhibited similar or rather better performances than the corresponding Li-based electrolytes; in particular, the rate capability of Mg-based ACN and PC electrolytes was much better than the corresponding Li-based electrolytes, indicating the high accessibility and utility of activated carbon pores by solvated Mg ions. (author)

  2. Porous carbon with tailored pore size for electric double layer capacitors application

    Science.gov (United States)

    Chen, Hao; Wang, Fang; Tong, Shanshan; Guo, Shuangling; Pan, Xiumei

    2012-06-01

    A series of porous carbon samples as electric double layer capacitor electrode materials were prepared by a pyrolysis process using phenol formaldehyde resin (PF) as precursors and KOH/ZnCl2 as activation agents. Porous carbon samples were characterized by thermogravimetric analysis, X ray diffraction, nitrogen adsorption/desorption isotherms and transmission electron microscopy. The results showed that the KOH/ZnCl2/PF mass mixing ratio and activation temperature had a remarkable effect on the porosity, the specific surface area and the pore size of the carbons. The prepared carbon material PC-6 exhibits a high specific capacitance of 141.56 F/g and a average specific energy of 74.13 Wh/kg at a current density of 120 mA/g in the electrolyte of 1 M Et3MeNBF4/PC, and the average specific energy still remained 49.48 Wh/kg even at a high current density of 2000 mA/g. The excellent electrochemical behavior of PC-6 can be attributed to the highly development pore structure.

  3. High-Surface-Area Nitrogen-Doped Reduced Graphene Oxide for Electric Double-Layer Capacitors.

    Science.gov (United States)

    Youn, Hee-Chang; Bak, Seong-Min; Kim, Myeong-Seong; Jaye, Cherno; Fischer, Daniel A; Lee, Chang-Wook; Yang, Xiao-Qing; Roh, Kwang Chul; Kim, Kwang-Bum

    2015-06-08

    A two-step method consisting of solid-state microwave irradiation and heat treatment under NH3 gas was used to prepare nitrogen-doped reduced graphene oxide (N-RGO) with a high specific surface area (1007 m(2)  g(-1) ), high electrical conductivity (1532 S m(-1) ), and low oxygen content (1.5 wt %) for electrical double-layer capacitor applications. The specific capacitance of N-RGO was 291 F g(-1) at a current density of 1 A g(-1) , and a capacitance of 261 F g(-1) was retained at 50 A g(-1) , which indicated a very good rate capability. N-RGO also showed excellent cycling stability and preserved 96 % of the initial specific capacitance after 100 000 cycles. Near-edge X-ray absorption fine-structure spectroscopy results provided evidenced for the recovery of π conjugation in the carbon networks with the removal of oxygenated groups and revealed chemical bonding of the nitrogen atoms in N-RGO. The good electrochemical performance of N-RGO is attributed to its high surface area, high electrical conductivity, and low oxygen content.

  4. Steric effects in the dynamics of electrolytes at large applied voltages: I. Double-layer charging

    CERN Document Server

    Kilic, M S; Ajdari, A; Kilic, Mustafa Sabri; Bazant, Martin Z.; Ajdari, Armand

    2006-01-01

    The classical Poisson-Boltzmann (PB) theory of electrolytes assumes a dilute solution of point charges with mean-field electrostatic forces. Even for very dilute solutions, however, it predicts absurdly large ion concentrations (exceeding close packing) for surface potentials of only a few tenths of a volt, which are often exceeded, e.g. in microfluidic pumps and electrochemical sensors. Since the 1950s, several modifications of the PB equation have been proposed to account for the finite size of ions in equilibrium, but in this two-part series, we consider steric effects on diffuse charge dynamics (in the absence of electro-osmotic flow). In this first part, we review the literature and analyze two simple models for the charging of a thin double layer, which must form a condensed layer of close-packed ions near the surface at high voltage. A surprising prediction is that the differential capacitance typically varies non-monotonically with the applied voltage, and thus so does the response time of an electrol...

  5. Boosted output performance of triboelectric nanogenerator via electric double layer effect

    Science.gov (United States)

    Chun, Jinsung; Ye, Byeong Uk; Lee, Jae Won; Choi, Dukhyun; Kang, Chong-Yun; Kim, Sang-Woo; Wang, Zhong Lin; Baik, Jeong Min

    2016-10-01

    For existing triboelectric nanogenerators (TENGs), it is important to explore unique methods to further enhance the output power under realistic environments to speed up their commercialization. We report here a practical TENG composed of three layers, in which the key layer, an electric double layer, is inserted between a top layer, made of Al/polydimethylsiloxane, and a bottom layer, made of Al. The efficient charge separation in the middle layer, based on Volta's electrophorus, results from sequential contact configuration of the TENG and direct electrical connection of the middle layer to the earth. A sustainable and enhanced output performance of 1.22 mA and 46.8 mW cm-2 under low frequency of 3 Hz is produced, giving over 16-fold enhancement in output power and corresponding to energy conversion efficiency of 22.4%. Finally, a portable power-supplying system, which provides enough d.c. power for charging a smart watch or phone battery, is also successfully developed.

  6. Influence of binder solvent on carbon-layer structure in electrical-double-layer capacitors

    Indian Academy of Sciences (India)

    A Banerjee; P Suresh Kumar; A K Shukla

    2013-09-01

    Porous activated-carbons with a large surface-area have been the most common materials for electrical-double-layer capacitors (EDLCs). These carbons having a wide pore distribution ranges from micropores to macropores in conjunction with a random pore connection that facilitates the high specific-capacitance values. Pore distribution plays a central role in controlling the capacitance value of EDLCs, since electrolyte distribution inside the active material mainly depends on the pore distribution. This has a direct influence on the distribution of resistance and capacitance values within the electrode. As a result, preparation of electrodes remains a vital issue in realising high-performance EDLCs. Generally, carbon materials along with some binders are dispersed into a solvent and coated onto the current collectors. This study examines the role of binder solvents used for the carbon-ink preparation on the microstructure of the electrodes and the consequent performance of the EDLCs. It is observed that the physical properties of the binder solvent namely its dielectric constant, viscosity and boiling point have important role in determining the pore-size distribution as well as the microstructure of electrodes which influence their specific capacitance values.

  7. Investigation of the impact of stacking pressure on a double-layer supercapacitor

    Energy Technology Data Exchange (ETDEWEB)

    Gourdin, Gerald; Meehan, Alexa; Qu, Deyang [Department of Chemistry, University of Massachusetts Boston, 100 Morrissey Blvd., Boston, MA 02135 (United States); Jiang, Thomas; Smith, Patricia [Naval Surface Warfare Center, Carderock Division, 9500 MacArthur Blvd., West Bethesda, MD 20817 (United States)

    2011-01-01

    There are two important steps necessary for the optimization of electrochemical double-layer capacitors (EDLC): maximizing the volumetric capacitance and minimizing the ohmic resistance. The application of force during the assembly of an EDLC cell is one way to achieve this optimization. The effect of the application of force on the performance characteristics of EDLC cells, assembled using porous activated carbon electrodes, was determined. It was shown that applying force to the body of the cell during assembly only provides a significant increase in the performance of the EDLC with the initial application. The results showed that any increase in the applied force beyond that initial stage does not result in a subsequent increase in performance and can result in a substantial decrease in the performance characteristics of the EDLC cell. Furthermore, it was concluded that the substantial decrease shown was attributed to an alteration of the physical structure of the porous material, which produced significant decreases in the accessible surface area and the material resistance of the activated carbon electrodes. (author)

  8. Preparation of porous carbon sphere from waste sugar solution for electric double-layer capacitor

    Science.gov (United States)

    Hao, Zhi-Qiang; Cao, Jing-Pei; Wu, Yan; Zhao, Xiao-Yan; Zhuang, Qi-Qi; Wang, Xing-Yong; Wei, Xian-Yong

    2017-09-01

    Waste sugar solution (WSS), which contains abundant 2-keto-L-gulonic acid, is harmful to the environment if discharged directly. For value-added utilization of the waste resource, a novel process is developed for preparation of porous carbon spheres by hydrothermal carbonization (HTC) of WSS followed by KOH activation. Additionally, the possible preparation mechanism of carbon spheres is proposed. The effects of hydrothermal and activation parameters on the properties of the carbon sphere are also investigated. The carbon sphere is applied to electric double-layer capacitor and its electrochemical performance is studied. These results show that the carbon sphere obtained by HTC at 180 °C for 12 h with the WSS/deionized water volume ratio of 2/3 possess the highest specific capacitance under identical activation conditions. The specific capacitance of the carbon spheres can reach 296.1 F g-1 at a current density of 40 mA g-1. Besides, excellent cycle life and good capacitance retention (89.6%) are observed at 1.5 A g-1 after 5000 cycles. This study not only provides a facile and potential method for the WSS treatment, but also achieves the high value-added recycling of WSS for the preparation of porous carbon spheres with superior electrochemical properties.

  9. Edge effects in vertically-oriented graphene based electric double-layer capacitors

    Science.gov (United States)

    Yang, Huachao; Yang, Jinyuan; Bo, Zheng; Zhang, Shuo; Yan, Jianhua; Cen, Kefa

    2016-08-01

    Vertically-oriented graphenes (VGs) have been demonstrated as a promising active material for electric double-layer capacitors (EDLCs), partially due to their edge-enriched structure. In this work, the 'edge effects', i.e., edges as the promoters of high capacitance, in VG based EDLCs are investigated with experimental research and numerical simulations. VGs with diverse heights (i.e., edge-to-basal ratios) and edge densities are prepared with varying the plasma-enabled growth time and employing different plasma sources. Electrochemical measurements show that the edges play a predominant role on the charge storage behavior of VGs. A simulation is further conducted to unveil the roles of the edges on the separation and adsorption of ions within VG channels. The initial charge distribution of a VG plane is obtained with density functional theory (DFT) calculations, which is subsequently applied to a molecular dynamics (MD) simulation system to gain the insights into the microscope EDLC structures. Compared with the basal planes, the edges present higher initial charge density (by 4.2 times), higher ion packing density (by 2.6 times), closer ion packing location (by 0.8 Å), and larger ion separation degree (by 14%). The as-obtained findings will be instructive in designing the morphology and structure of VGs for enhanced capacitive performances.

  10. Solitary and double-layer structures in quantum bi-ion plasma

    Science.gov (United States)

    Shahmansouri, Mehran; Tribeche, Mouloud

    2016-06-01

    Weak ion-acoustic solitary waves (IASWs) in an unmagnetized quantum plasmas having two-fluid ions and fluid electrons are considered. Using the one-dimensional quantum hydrodynamics model and then the reductive perturbation technique, a generalized form of nonlinear quantum Korteweg-de Vries (KdV) equation governing the dynamics of weak ion acoustic solitary waves is derived. The effects of ion population, warm ion temperature, quantum diffraction, and polarity of ions on the nonlinear properties of these IASWs are analyzed. It is found that our present plasma model may support compressive as well as rarefactive solitary structures. Furthermore, formation and characteristics properties of IA double layers in the present bi-ion plasma model are investigated. The results of this work should be useful and applicable in understanding the wide relevance of nonlinear features of localized electro-acoustic structures in laboratory and space plasma, such as in super-dense astrophysical objects [24] and in the Earth's magnetotail region (Parks [43]. The implications of our results in some space plasma situations are discussed.

  11. High Power Density Electric Double Layer Capacitor with Improved Activated Carbon

    Institute of Scientific and Technical Information of China (English)

    杨辉; 姜慧君; 陆天虹

    2003-01-01

    The improvement on commercial activated carbon(AC)through the reactivation under steam in the presence of NiCl2 catalyst leads to the increases of both energy and power densities of electri double layer(dl)capacitors.When AC was treated at 875℃ for 1h,its discharge specific capacitance increasesup to53.67F·g-1,an increase of about 25?compered to the as-received AC.Moreover,a significant increase in high rate capability of electric dl capatior was found after the improvements.Surprsingly,both the treated and untreated AC samples showed simiiar specific surface area and pore size distribution,but some changes in the surface groups and their concentrations after reactivation were verified by X-photoelectron spectra.Thus,it is reasonable to conclude that the decrease in the surface concentration of the carbonyl-containing specles for the improved AC results in an increase of accessibility of the pores to the organic electrolyte ion,causing the enhancements of both the specific capacitance and high rate capability.

  12. One-step synthesis of hierarchically porous carbons for high-performance electric double layer supercapacitors

    Science.gov (United States)

    Zhang, Haitao; Zhang, Lei; Chen, Jun; Su, Hai; Liu, Fangyan; Yang, Weiqing

    2016-05-01

    With plenty of unique porous structure at micro-/nano scale, hierarchically porous carbons (HPCs) are promising for usage in advanced electric double layer supercapacitors (EDLCs) as the electrode materials. However, wide-range adoption of HPC for practical application is largely shadowed by its extremely complex synthesis process with considerably low production efficiency. Herein we reported a simple template-free, one-step sintering method, to massively produce the HPCs for high-performance EDLCs. Resorting to the 3D structure modification of the wide pore size distribution, high surface area of HPCs (up to 3000 m2 g-1) was achieved. By using 1 M Na2SO4 as electrolyte, the as-fabricated HPCs based EDLCs can be operated reversibly over a wide voltage window of 1.6 V with superior specific capacitance of 240 F g-1 under a current density of 0.5 A g-1. In the meanwhile, the EDLCs exhibit excellent rate capability (high power density of 16 kW kg-1 at 10.2 Wh kg-1) and long-term cycling stability with 9% loss of its initial capacitance after 2000 cycles. This output performance distinguished itself among most of the carbon-based EDLCs with neutral aqueous electrolyte. Thus, the template-free one-step sintering method produced HPCs for EDLCs represents a new approach for high-performance energy storage.

  13. Electro-acoustic solitary waves and double layers in a quantum plasma

    Science.gov (United States)

    Dip, P. R.; Hossen, M. A.; Salahuddin, M.; Mamun, A. A.

    2017-02-01

    A meticulous theoretical investigation has carried out to study the properties related to the higher-order nonlinearity of the electro-acoustic waves, specifically ion-acoustic (IA) waves in an unmagnetized, collisionless, quantum electron-positron-ion (EPI) plasma. The plasma system is supposed to be formed of positively charged inertial heavy ions, inertialess electrons and positrons. The reductive perturbation technique is employed to derive the modified Korteweg-de Vries (mK-dV) equation to analyze the solitary waves (SWs), and the standard Gardner (SG) equation to analyze the higher-order SWs as well as double layers (DLs). The basic features (viz. amplitude, width, phase speed, etc.) of the IA SWs and DLs are examined. The comparison between the mK-dV SWs and SG SWs is also made. It is found that the amplitude, width, phase speed, etc. of the IA SWs and DLs are significantly modified by the effects of the both Fermi temperatures as well as pressures and Bohm potentials of electrons and positrons. Our findings may be useful in explaining the physics behind the formation of the IA waves in both astrophysical and laboratory EPI plasmas (viz. white dwarfs, laser-solid matter interaction experiments, etc.).

  14. Ion-acoustic double layers in magnetized positive-negative ion plasmas with nonthermal electrons

    Science.gov (United States)

    El-Labany, S. K.; Sabry, R.; El-Taibany, W. F.; Elghmaz, E. A.

    2012-07-01

    The nonlinear ion-acoustic double layers (IADLs) in a warm magnetoplasma with positive-negative ions and nonthermal electrons are investigated. For this purpose, the hydrodynamic equations for the positive-negative ions, nonthermal electron density distribution, and the Poisson equation are used to derive a modified Zakharov-Kuznetsov (MZK) equation, in the small amplitude regime. It is found that compressive and rarefactive IADLs strongly depend on the mass and density ratios of the negative-to-positive ions as well as the nonthermal electron parameter. Also, it is shown that there are one critical value for the density ratio of the negative-to-positive ions ( ν), the ratio between unperturbed electron-to-positive ion density ( μ), and the nonthermal electron parameter ( β), which decide the existence of positive and negative IADLs. The present study is applied to examine the small amplitude nonlinear IADL excitations for the (H+, O2-) and (H+,H-) plasmas, where they are found in the D- and F-regions of the Earth's ionosphere. This investigation should be helpful in understanding the salient features of the nonlinear IADLs in either space or laboratory plasmas where two distinct groups of ions and non-Boltzmann distributed electrons are present.

  15. Dust-ion-acoustic double layers in multi-ion dusty plasma

    Energy Technology Data Exchange (ETDEWEB)

    Mamun, A. A. [Jahangirnagar University, Department of Physics (Bangladesh); Deeba, F., E-mail: farah.ju35@gmail.com [Dhaka University of Engineering and Technology, Department of Physics (Bangladesh)

    2015-08-15

    A theoretical investigation has been made on nonplanar (cylindrical and spherical) dust-ionacoustic (DIA) double layers (DLs) in a multi-ion dusty plasma system containing inertial positive and negative ions and arbitrarily charged stationary dust. The dust particles have been considered as arbitrarily (either positively or negatively) charged in order to observe the effects of the dust polarity on the DIA DLs. The ion species were considered to be at different temperatures to observe the effects of the temperatures on that waves. The modified Gardner equation, which has been derived by employing the reductive perturbation method, has been used to analyze time-dependent nonplanar and planar DIA DLs. It has been found that the time evolution of DIA DLs is significantly modified not only by the nonplanar geometry, but also by the polarity, temperature, and mass ratio of the constituent particles. It has been also found that the amplitude of cylindrical DIA DL structures is larger than that of 1D planar ones, but smaller than that of the spherical ones.

  16. Influence of Shrinkage on Air and Water Vapour Permeability of Double-Layered Weft Knitted Fabrics

    Directory of Open Access Journals (Sweden)

    Asta BIVAINYTĖ

    2012-09-01

    Full Text Available Water vapour permeability and transport depends on the properties of the fibre and knitted fabric structure. It was designed double-layered fabrics knitted in plain plating pattern whose inner side was  made from synthetic fibres the PES, PA, PP, and Coolmax® (tetra-channel fibres by DuPont which do not absorb moisture and on the surface of the wear – natural cotton and bamboo fibres which have good absorption properties. In the present research it was established that the air permeability of all fabrics after washing and drying cycle decreased. It occurred because of the influence of shrinkage during washing and drying under the impact of moisture, heat, and mechanical action. After washing and drying cycle, the water vapour permeability of fabrics knitted from bamboo and synthetic yarns blend decreased predominantly and became similar to fabrics knitted from cotton and respective synthetic yarns blend. The water vapour permeability of fabrics knitted from cotton and synthetic yarns blend decreased significant less. Depending on the knitting structure, the most decrease of water vapour permeability was estimated to the plain plated fabrics.DOI: http://dx.doi.org/10.5755/j01.ms.18.3.2438

  17. Evolution of electronic states in n-type copper oxide superconductor via electric double layer gating.

    Science.gov (United States)

    Jin, Kui; Hu, Wei; Zhu, Beiyi; Kim, Dohun; Yuan, Jie; Sun, Yujie; Xiang, Tao; Fuhrer, Michael S; Takeuchi, Ichiro; Greene, Richard L

    2016-01-01

    The occurrence of electrons and holes in n-type copper oxides has been achieved by chemical doping, pressure, and/or deoxygenation. However, the observed electronic properties are blurred by the concomitant effects such as change of lattice structure, disorder, etc. Here, we report on successful tuning the electronic band structure of n-type Pr2-xCexCuO4 (x = 0.15) ultrathin films, via the electric double layer transistor technique. Abnormal transport properties, such as multiple sign reversals of Hall resistivity in normal and mixed states, have been revealed within an electrostatic field in range of -2 V to + 2 V, as well as varying the temperature and magnetic field. In the mixed state, the intrinsic anomalous Hall conductivity invokes the contribution of both electron and hole-bands as well as the energy dependent density of states near the Fermi level. The two-band model can also describe the normal state transport properties well, whereas the carrier concentrations of electrons and holes are always enhanced or depressed simultaneously in electric fields. This is in contrast to the scenario of Fermi surface reconstruction by antiferromagnetism, where an anti-correlation is commonly expected.

  18. Important parameters affecting the cell voltage of aqueous electrical double-layer capacitors

    Science.gov (United States)

    Wu, Tzu-Ho; Hsu, Chun-Tsung; Hu, Chi-Chang; Hardwick, Laurence J.

    2013-11-01

    This study discusses and demonstrates how the open-circuit potential and charges stored in the working potential window on positive and negative electrodes affect the cell voltage of carbon-based electrical double-layer capacitors (EDLCs) in aqueous electrolytes. An EDLC consisting of two activated carbon electrodes is employed as the model system for identifying these key parameters although the potential window of water decomposition can be simply determined by voltammetric methods. First, the capacitive performances of an EDLC with the same charge on positive and negative electrodes are evaluated by cyclic voltammetric, charge-discharge, electrochemical impedance spectroscopic (EIS) analyses, and inductance-capacitance-resistance meter (LCR meter). The principles for obtaining the highest acceptable cell voltage of such symmetric ECs with excellent reversibility and capacitor-like behaviour are proposed. Aqueous charge-balanced EDLCs can be operated as high as 2.0 V with high energy efficiency (about 90%) and only 4% capacitance loss after the 600-cycle stability checking. The necessity of charge balance (but not capacitance balance) for positive and negative electrodes is substantiated from the lower acceptable cell voltage of charge-unbalanced EDLCs.

  19. Anomalous or regular capacitance? The influence of pore size dispersity on double-layer formation

    Science.gov (United States)

    Jäckel, N.; Rodner, M.; Schreiber, A.; Jeongwook, J.; Zeiger, M.; Aslan, M.; Weingarth, D.; Presser, V.

    2016-09-01

    The energy storage mechanism of electric double-layer capacitors is governed by ion electrosorption at the electrode surface. This process requires high surface area electrodes, typically highly porous carbons. In common organic electrolytes, bare ion sizes are below one nanometer but they are larger when we consider their solvation shell. In contrast, ionic liquid electrolytes are free of solvent molecules, but cation-anion coordination requires special consideration. By matching pore size and ion size, two seemingly conflicting views have emerged: either an increase in specific capacitance with smaller pore size or a constant capacitance contribution of all micro- and mesopores. In our work, we revisit this issue by using a comprehensive set of electrochemical data and a pore size incremental analysis to identify the influence of certain ranges in the pore size distribution to the ion electrosorption capacity. We see a difference in solvation of ions in organic electrolytes depending on the applied voltage and a cation-anion interaction of ionic liquids in nanometer sized pores.

  20. Double-layer weekly sustained release transdermal patch containing gestodene and ethinylestradiol.

    Science.gov (United States)

    Gao, Yanli; Liang, Jinying; Liu, Jianping; Xiao, Yan

    2009-07-30

    The combination therapy of gestodene (GEST) and ethinylestradiol (EE) has shown advanced contraception effect and lower side effect. The present study was designed to develop a weekly sustained release matrix type transdermal patch containing GEST and EE using blends of different polymeric combinations. The multiple-layer technique was adopted in order to maintain a steady permeation flux for 7 days. The effects of polymer types, polymer ratios, permeation enhancers, drug loadings and drug ratios in different layers on the skin permeations of the drugs were evaluated using excised mice skin. Polariscope examination was carried out to observe the drug distribution behavior. The formulation with the mixture of polyvinyl alcohol (PVA) and polyvinyl pyrrolidone (PVP) (7:1) was found to provide the regular release and propylene glycol (PG) could enhance the permeation fluxes of drugs. Double-layer transdermal drug delivery system (TDDS) could sustain the steady permeation flux of drugs for 7 days when the ratio of drug in drug release layer and drug reservoir layer was 1:4 with the identical total drug amount. The in vitro transdermal permeation fluxes were 0.377 microg/cm(2)/h and 0.092 microg/cm(2)/h, for GEST and EE respectively. The uniformity of dosage units test showed that the distribution of drugs in the matrix was homogeneous, which was further demonstrated by the polariscope result. The developed transdermal delivery system containing GEST and EE could be a promising non-oral contraceptive method.

  1. Electric potential calculation in molecular simulation of electric double layer capacitors.

    Science.gov (United States)

    Wang, Zhenxing; Olmsted, David L; Asta, Mark; Laird, Brian B

    2016-11-23

    For the molecular simulation of electric double layer capacitors (EDLCs), a number of methods have been proposed and implemented to determine the one-dimensional electric potential profile between the two electrodes at a fixed potential difference. In this work, we compare several of these methods for a model LiClO4-acetonitrile/graphite EDLC simulated using both the traditional fixed-charged method (FCM), in which a fixed charge is assigned a priori to the electrode atoms, or the recently developed constant potential method (CPM) (2007 J. Chem. Phys. 126 084704), where the electrode charges are allowed to fluctuate to keep the potential fixed. Based on an analysis of the full three-dimensional electric potential field, we suggest a method for determining the averaged one-dimensional electric potential profile that can be applied to both the FCM and CPM simulations. Compared to traditional methods based on numerically solving the one-dimensional Poisson's equation, this method yields better accuracy and no supplemental assumptions.

  2. Bimodal behaviour of charge carriers in graphene induced by electric double layer

    Science.gov (United States)

    Tsai, Sing-Jyun; Yang, Ruey-Jen

    2016-01-01

    A theoretical investigation is performed into the electronic properties of graphene in the presence of liquid as a function of the contact area ratio. It is shown that the electric double layer (EDL) formed at the interface of the graphene and the liquid causes an overlap of the conduction bands and valance bands and increases the density of state (DOS) at the Fermi energy (EF). In other words, a greater number of charge carriers are induced for transport and the graphene changes from a semiconductor to a semimetal. In addition, it is shown that the dependence of the DOS at EF on the contact area ratio has a bimodal distribution which responses to the experimental observation, a pinnacle curve. The maximum number of induced carriers is expected to occur at contact area ratios of 40% and 60%. In general, the present results indicate that modulating the EDL provides an effective means of tuning the electronic properties of graphene in the presence of liquid. PMID:27464986

  3. Evolution of electronic states in n-type copper oxide superconductor via electric double layer gating

    Science.gov (United States)

    Jin, Kui; Hu, Wei; Zhu, Beiyi; Kim, Dohun; Yuan, Jie; Sun, Yujie; Xiang, Tao; Fuhrer, Michael S.; Takeuchi, Ichiro; Greene, Richard. L.

    2016-01-01

    The occurrence of electrons and holes in n-type copper oxides has been achieved by chemical doping, pressure, and/or deoxygenation. However, the observed electronic properties are blurred by the concomitant effects such as change of lattice structure, disorder, etc. Here, we report on successful tuning the electronic band structure of n-type Pr2−xCexCuO4 (x = 0.15) ultrathin films, via the electric double layer transistor technique. Abnormal transport properties, such as multiple sign reversals of Hall resistivity in normal and mixed states, have been revealed within an electrostatic field in range of −2 V to + 2 V, as well as varying the temperature and magnetic field. In the mixed state, the intrinsic anomalous Hall conductivity invokes the contribution of both electron and hole-bands as well as the energy dependent density of states near the Fermi level. The two-band model can also describe the normal state transport properties well, whereas the carrier concentrations of electrons and holes are always enhanced or depressed simultaneously in electric fields. This is in contrast to the scenario of Fermi surface reconstruction by antiferromagnetism, where an anti-correlation is commonly expected. PMID:27221198

  4. Corrosion behaviors of arc spraying single and double layer coatings in simulated Dagang soil solution

    Institute of Scientific and Technical Information of China (English)

    LIN Bi-lan; LU Xin-ying; LI Long

    2009-01-01

    Three kinds of single layer coatings of Zn,Zn15Al,316L stainless steel and two kinds of double layer coatings with inner layer of Zn or Zn15Al and outer layer of 316L stainless steel by arc spraying were developed to protect the metal ends of prestressed high-strength concrete (PHC) pipe piles against soil corrosion.The corrosion behaviors of the coated Q235 steel samples in the simulated Dagang soil solution were investigated by potentiodynamic polarization,electrochemical impedance spectroscopy (EIS) and natural immersion tests.The results show that the corrosion of the matrix Q235 steel is effectively inhibited by Zn,Zn15Al,Zn+316L and Zn15Al+316L coatings.The corrosion rate value of Zn15Al coated samples is negative.The corrosion products on Zn and Zn15Al coated samples are compact and firm.The corrosion resistance indexes of both Zn and Zn15Al coated samples are improved significantly with corrosion time,and the latter are more outstanding than the former.But the corrosion resistance of 316L coated samples is decreased quickly with the increase in immersion time.When the coatings are sealed with epoxy resin,the corrosion resistance of the coatings will be enhanced significantly.

  5. Osmotic pressure of ionic liquids in an electric double layer: Prediction based on a continuum model.

    Science.gov (United States)

    Moon, Gi Jong; Ahn, Myung Mo; Kang, In Seok

    2015-12-01

    An analysis has been performed for the osmotic pressure of ionic liquids in the electric double layer (EDL). By using the electromechanical approach, we first derive a differential equation that is valid for computing the osmotic pressure in the continuum limit of any incompressible fluid in EDL. Then a specific model for ionic liquids proposed by Bazant et al. [M. Z. Bazant, B. D. Storey, and A. A. Kornyshev, Phys. Rev. Lett. 106, 046102 (2011)] is adopted for more detailed computation of the osmotic pressure. Ionic liquids are characterized by the correlation and the steric effects of ions and their effects are analyzed. In the low voltage cases, the correlation effect is dominant and the problem becomes linear. For this low voltage limit, a closed form formula is derived for predicting the osmotic pressure in EDL with no overlapping. It is found that the osmotic pressure decreases as the correlation effect increases. The osmotic pressures at the nanoslit surface and nanoslit centerline are also obtained for the low voltage limit. For the cases of moderately high voltage with high correlation factor, approximate formulas are derived for estimating osmotic pressure values based on the concept of a condensed layer near the electrode. In order to corroborate the results predicted by analytical studies, the full nonlinear model has been solved numerically.

  6. An all-solid-state electrochemical double-layer capacitor based on a plastic crystal electrolyte

    Directory of Open Access Journals (Sweden)

    Ali eaabouimrane

    2015-08-01

    Full Text Available A plastic crystal, solid electrolyte was prepared by mixing tetrabutylammonium hexafluorophosphate salt, (C4H94NPF6, (10 molar % with succinonitrile, SCN, (N C−CH2−CH2−C N, [SCN-10%TBA-PF6]. The resultant waxy material shows a plastic crystalline phase that extend from -36 °C up to its melting at 23 °C. It shows a high ionic conductivity reaching 4 × 10−5 S/cm in the plastic crystal phase (15 °C and ~ 3 × 10−3 S/cm in the molten state (25 °C. These properties along with the high electrochemical stability rendered the use of this material as an electrolyte in an electrochemical double-layer capacitor (EDLC. The EDLC was assembled and its performance was tested by cyclic voltammetry, AC impedance spectroscopy and galvanostatic charge-discharge methods. Specific capacitance values in the range of 4-7 F/g. (of electrode active material were obtained in the plastic crystal phase at 15 °C, that although compare well with those reported for some polymer electrolytes, can be still enhanced with further development of the device and its components, and only demonstrate their great potential use for capacitors as a new application.

  7. Double-layer parallelization for hydrological model calibration on HPC systems

    Science.gov (United States)

    Zhang, Ang; Li, Tiejian; Si, Yuan; Liu, Ronghua; Shi, Haiyun; Li, Xiang; Li, Jiaye; Wu, Xia

    2016-04-01

    Large-scale problems that demand high precision have remarkably increased the computational time of numerical simulation models. Therefore, the parallelization of models has been widely implemented in recent years. However, computing time remains a major challenge when a large model is calibrated using optimization techniques. To overcome this difficulty, we proposed a double-layer parallel system for hydrological model calibration using high-performance computing (HPC) systems. The lower-layer parallelism is achieved using a hydrological model, the Digital Yellow River Integrated Model, which was parallelized by decomposing river basins. The upper-layer parallelism is achieved by simultaneous hydrological simulations with different parameter combinations in the same generation of the genetic algorithm and is implemented using the job scheduling functions of an HPC system. The proposed system was applied to the upstream of the Qingjian River basin, a sub-basin of the middle Yellow River, to calibrate the model effectively by making full use of the computing resources in the HPC system and to investigate the model's behavior under various parameter combinations. This approach is applicable to most of the existing hydrology models for many applications.

  8. Electric double layer and electrokinetic potential of pectic macromolecules in sugar beet

    Directory of Open Access Journals (Sweden)

    Kuljanin Tatjana A.

    2008-01-01

    Full Text Available Electrokinetic potential is an important property of colloidal particles and, regarding the fact that it is a well defined and easily measurable property, it is considered to be a permanent characteristic of a particular colloidal system. In fact, it is a measure of electrokinetic charge that surrounds the colloidal particle in a solution and is in direct proportion with the mobility of particles in an electric field. Gouy-Chapman-Stern-Graham's model of electric double layer was adopted and it was proven experimentally that the addition of Cu++ ions to sugar beet pectin caused a reduction in the negative electrokinetic potential proportional to the increase of Cu++ concentration. Higher Cu++ concentrations increased the proportion of cation specific adsorption (Cu++ and H+ with regard to electrostatic Coulombic forces. Consequently, there is a shift in the shear plane between the fixed and diffuse layers directed towards the diffuse layer, i.e. towards its compression and decrease in the electrokinetic potential or even charge inversion of pectin macromolecules.

  9. On the generation of double layers from ion- and electron-acoustic instabilities

    Science.gov (United States)

    Fu, Xiangrong; Cowee, Misa M.; Gary, S. Peter; Winske, Dan

    2016-03-01

    A plasma double layer (DL) is a nonlinear electrostatic structure that carries a uni-polar electric field parallel to the background magnetic field due to local charge separation. Past studies showed that DLs observed in space plasmas are mostly associated with the ion acoustic instability. Recent Van Allen Probes observations of parallel electric field structures traveling much faster than the ion acoustic speed have motivated a computational study to test the hypothesis that a new type of DLs—electron acoustic DLs—generated from the electron acoustic instability are responsible for these electric fields. Nonlinear particle-in-cell simulations yield negative results, i.e., the hypothetical electron acoustic DLs cannot be formed in a way similar to ion acoustic DLs. Linear theory analysis and the simulations show that the frequencies of electron acoustic waves are too high for ions to respond and maintain charge separation required by DLs. However, our results do show that local density perturbations in a two-electron-component plasma can result in unipolar-like electric field structures that propagate at the electron thermal speed, suggesting another potential explanation for the observations.

  10. Thermal characteristics of double-layer thin film target ablated by femtosecond laser pulses

    Institute of Scientific and Technical Information of China (English)

    Gao Xun; Song Xiao-Wei; Lin Jing-Quan

    2011-01-01

    Thermal characteristics of tightly-contacted copper-gold double-layer thin film target under ablation of femtosecond laser pulses are investigated by using a two-temperature theoretical model. Numerical simulation shows that electron heat flux varies significantly on the boundary of copper-gold film with different maximal electron temperature of 1.15 × 103 K at 5 ps after ablating laser pulse in gold and copper films, which can reach a balance around 12.6 ps and 8.2 ps for a single and double pulse ablation, respectively, and in the meantime, the lattice temperature difference crossing the gold-copper interface is only about 0.04 × 103 K at the same time scale. It is also found that electron-lattice heat relaxation time increases linearly with laser fluence in both single and double pulse ablation, and a sudden change of the relaxation time appears after the laser energy density exceeds the ablation threshold.

  11. The Double Layer Methodology and the Validation of Eigenbehavior Techniques Applied to Lifestyle Modeling

    Science.gov (United States)

    Lamichhane, Bishal

    2017-01-01

    A novel methodology, the double layer methodology (DLM), for modeling an individual's lifestyle and its relationships with health indicators is presented. The DLM is applied to model behavioral routines emerging from self-reports of daily diet and activities, annotated by 21 healthy subjects over 2 weeks. Unsupervised clustering on the first layer of the DLM separated our population into two groups. Using eigendecomposition techniques on the second layer of the DLM, we could find activity and diet routines, predict behaviors in a portion of the day (with an accuracy of 88% for diet and 66% for activity), determine between day and between individual similarities, and detect individual's belonging to a group based on behavior (with an accuracy up to 64%). We found that clustering based on health indicators was mapped back into activity behaviors, but not into diet behaviors. In addition, we showed the limitations of eigendecomposition for lifestyle applications, in particular when applied to noisy and sparse behavioral data such as dietary information. Finally, we proposed the use of the DLM for supporting adaptive and personalized recommender systems for stimulating behavior change. PMID:28133607

  12. Electric potential calculation in molecular simulation of electric double layer capacitors

    Science.gov (United States)

    Wang, Zhenxing; Olmsted, David L.; Asta, Mark; Laird, Brian B.

    2016-11-01

    For the molecular simulation of electric double layer capacitors (EDLCs), a number of methods have been proposed and implemented to determine the one-dimensional electric potential profile between the two electrodes at a fixed potential difference. In this work, we compare several of these methods for a model LiClO4-acetonitrile/graphite EDLC simulated using both the traditional fixed-charged method (FCM), in which a fixed charge is assigned a priori to the electrode atoms, or the recently developed constant potential method (CPM) (2007 J. Chem. Phys. 126 084704), where the electrode charges are allowed to fluctuate to keep the potential fixed. Based on an analysis of the full three-dimensional electric potential field, we suggest a method for determining the averaged one-dimensional electric potential profile that can be applied to both the FCM and CPM simulations. Compared to traditional methods based on numerically solving the one-dimensional Poisson’s equation, this method yields better accuracy and no supplemental assumptions.

  13. Tetramethylammonium tetrafluoroborate: The smallest quaternary ammonium tetrafluoroborate salt for use in electrochemical double layer capacitors

    Science.gov (United States)

    Park, Sieun; Kim, Ketack

    2017-01-01

    Tetramethylammonium (TMA) ion is the smallest quaternary ammonium ion (QAI) that can be used in electrochemical double layer capacitor (EDLC) applications. Small ions improve the capacitance of EDLCs by increasing the adsorbed ionic density. Herein, we first report the utilization of TMA BF4 in EDLCs and the properties of the smallest QAI are investigated. However, because of the poor solubility of TMA BF4, it must be combined with another salt, forming a binary-salt electrolyte. In this study, the maximum TMA BF4 concentration used was 5 mol%. These binary salt mixtures contain a conventional electrolyte salt such as tetraethylammonium BF4, trimethylethylammonium BF4, or spiro-bipyrrolidinium BF4. In addition, 4-5 mol% TMA BF4 was added to the conventional salt solution and a binary-salt electrolyte was obtained, leading to 12-13% increase in the capacitance compared to that of a 100 mol% conventional electrolyte at 10 A g-1. This work proposes a new method to improve the performance of EDLCs by using binary-salt electrolytes.

  14. Elucidating the DEP phenomena using a volumetric polarization approach with consideration of the electric double layer.

    Science.gov (United States)

    Zhao, Yu; Brcka, Jozef; Faguet, Jacques; Zhang, Guigen

    2017-03-01

    Dielectrophoretic (DEP) phenomena have been explored to great success for various applications like particle sorting and separation. To elucidate the underlying mechanism and quantify the DEP force experienced by particles, the point-dipole and Maxwell Stress Tensor (MST) methods are commonly used. However, both methods exhibit their own limitations. For example, the point-dipole method is unable to fully capture the essence of particle-particle interactions and the MST method is not suitable for particles of non-homogeneous property. Moreover, both methods fare poorly when it comes to explaining DEP phenomena such as the dependence of crossover frequency on medium conductivity. To address these limitations, the authors have developed a new method, termed volumetric-integration method, with the aid of computational implementation, to reexamine the DEP phenomena, elucidate the governing mechanism, and quantify the DEP force. The effect of an electric double layer (EDL) on particles' crossover behavior is dealt with through consideration of the EDL structure along with surface ionic/molecular adsorption, unlike in other methods, where the EDL is accounted for through simply assigning a surface conductance value to the particles. For validation, by comparing with literature experimental data, the authors show that the new method can quantify the DEP force on not only homogeneous particles but also non-homogeneous ones, and predict particle-particle interactions fairly accurately. Moreover, the authors also show that the predicted dependence of crossover frequency on medium conductivity and particle size agrees very well with experimental measurements.

  15. Electrochemical cell studies based on non-aqueous magnesium electrolyte for electric double layer capacitor applications

    Science.gov (United States)

    Chandrasekaran, Ramasamy; Koh, Meiten; Yamauchi, Akiyoshi; Ishikawa, Masashi

    Performances of electric double layer capacitors (EDLCs) based on an activated carbon electrode with acetonitrile (ACN), propylene carbonate (PC), or a ternary electrolyte, i.e., PC:ethylene carbonate (EC):diethyl carbonate (DEC), at 1 mol dm -3 of magnesium perchlorate [Mg(ClO 4) 2] salt have been investigated. The electrochemical responses were studied by impedance spectroscopy, cyclic voltammetry, and galvanostatic charge-discharge experiments at 25 °C in a three-electrode configuration. For a comparative evaluation, lithium perchlorate (LiClO 4) salt-based systems were also evaluated. All the observed results showed typical EDLC characteristics within the potential range between 0 and 1 V vs. an Ag/Ag + reference electrode. The Mg-based systems exhibited similar or rather better performances than the corresponding Li-based electrolytes; in particular, the rate capability of Mg-based ACN and PC electrolytes was much better than the corresponding Li-based electrolytes, indicating the high accessibility and utility of activated carbon pores by solvated Mg ions.

  16. Low-energy spin dynamics of the s = 1/2 kagome system herbertsmithite.

    Science.gov (United States)

    Nilsen, G J; de Vries, M A; Stewart, J R; Harrison, A; Rønnow, H M

    2013-03-13

    The low-energy (ε = ħω kagome candidate herbertsmithite are probed in the presence of magnetic fields up to 2.5 T. The zero-field spectra reveal a very weak continuum of scattering at T = 10 K and a broad inelastic peak centred at ε(max) = 0.2 meV at lower temperatures, T kagome planes and moments in the kagome layers.

  17. Ground-state phase diagram of the Kondo lattice model on triangular-to-kagome lattices

    OpenAIRE

    Akagi, Yutaka; Motome, Yukitoshi

    2012-01-01

    We investigate the ground-state phase diagram of the Kondo lattice model with classical localized spins on triangular-to-kagome lattices by using a variational calculation. We identify the parameter regions where a four-sublattice noncoplanar order is stable with a finite spin scalar chirality while changing the lattice structure from triangular to kagome continuously. Although the noncoplanar spin states appear in a wide range of parameters, the spin configurations on the kagome network beco...

  18. High applicability of two-dimensional phosphorous in Kagome lattice predicted from first-principles calculations

    OpenAIRE

    Peng-Jen Chen; Horng-Tay Jeng

    2016-01-01

    A new semiconducting phase of two-dimensional phosphorous in the Kagome lattice is proposed from first-principles calculations. The band gaps of the monolayer (ML) and bulk Kagome phosphorous (Kagome-P) are 2.00 and 1.11 eV, respectively. The magnitude of the band gap is tunable by applying the in-plane strain and/or changing the number of stacking layers. High optical absorption coefficients at the visible light region are predicted for multilayer Kagome-P, indicating potential applications ...

  19. Double layering of a thermochemical plume in the upper mantle beneath Hawaii

    Science.gov (United States)

    Ballmer, M. D.; Ito, G.; Wolfe, C. J.; Cadio, C.; Solomon, S. C.

    2012-04-01

    that the small-scale convection that develops within the hot pancake2 is sufficient to support rejuvenated and arch volcanism, as well as to account for the apparent decrease of the geoid-to-topography ratio (GTR) along the Hawaiian Swell. The double layering of hot plume material (DEP and shallow pancake) forms a thick and asymmetric feature. Seismic resolution tests indicate that this double layering can account for the thick and asymmetric low-velocity body as imaged by PLUME. We also show that thermochemical plumes with slightly larger volumes of eclogitic material display pulsations from the DEP upwards, a behavior that can explain temporal variability of Hawaiian hotspot volcanism3. Finally, models with a diffuse distribution of eclogite in the plume give rise to bilateral asymmetry in the predicted contribution of mafic material to partial melting. Such lateral variability in the source of volcanism has been proposed to account for the prominent Loa-versus-Kea geochemical trends in Hawaiian lavas¹. Building on previous work for the lower mantle, our results reveal the relevance of thermochemical convection for the upper mantle, specifically for the overall dynamics of mantle plumes, the genesis of intraplate volcanism, and ocean-island geochemistry. ¹Sobolev, A.V., A.W. Hofmann, S.V. Sobolev, I.K. Nikogosian (2005) Nature 434, 590-597. 2Ballmer, M.D., G. Ito, J. van Hunen, P.J. Tackley (2011) Nature Geosci. 4, 457-460. 3van Ark, E., J. Lin (2004) J. Geophys. Res. 109, B11401.

  20. Subsurface volatile content of martian double-layer ejecta (DLE) craters

    Science.gov (United States)

    Viola, Donna; McEwen, Alfred S.; Dundas, Colin M.; Byrne, Shane

    2017-03-01

    Excess ice is widespread throughout the martian mid-latitudes, particularly in Arcadia Planitia, where double-layer ejecta (DLE) craters also tend to be abundant. In this region, we observe the presence of thermokarstically-expanded secondary craters that likely form from impacts that destabilize a subsurface layer of excess ice, which subsequently sublimates. The presence of these expanded craters shows that excess ice is still preserved within the adjacent terrain. Here, we focus on a 15-km DLE crater that contains abundant superposed expanded craters in order to study the distribution of subsurface volatiles both at the time when the secondary craters formed and, by extension, remaining today. To do this, we measure the size distribution of the superposed expanded craters and use topographic data to calculate crater volumes as a proxy for the volumes of ice lost to sublimation during the expansion process. The inner ejecta layer contains craters that appear to have undergone more expansion, suggesting that excess ice was most abundant in that region. However, both of the ejecta layers had more expanded craters than the surrounding terrain. We extrapolate that the total volume of ice remaining within the entire ejecta deposit is as much as 74 km3 or more. The variation in ice content between the ejecta layers could be the result of (1) volatile preservation from the formation of the DLE crater, (2) post-impact deposition in the form of ice lenses; or (3) preferential accumulation or preservation of subsequent snowfall. We have ruled out (2) as the primary mode for ice deposition in this location based on inconsistencies with our observations, though it may operate in concert with other processes. Although none of the existing DLE formation hypotheses are completely consistent with our observations, which may merit a new or modified mechanism, we can conclude that DLE craters contain a significant quantity of excess ice today.

  1. Synthesis, characterization, and antimicrobial properties of novel double layer nanocomposite electrospun fibers for wound dressing applications

    Science.gov (United States)

    Hassiba, Alaa J; El Zowalaty, Mohamed E; Webster, Thomas J; Abdullah, Aboubakr M; Nasrallah, Gheyath K; Khalil, Khalil Abdelrazek; Luyt, Adriaan S; Elzatahry, Ahmed A

    2017-01-01

    Herein, novel hybrid nanomaterials were developed for wound dressing applications with antimicrobial properties. Electrospinning was used to fabricate a double layer nanocomposite nanofibrous mat consisting of an upper layer of poly(vinyl alcohol) and chitosan loaded with silver nanoparticles (AgNPs) and a lower layer of polyethylene oxide (PEO) or polyvinylpyrrolidone (PVP) nanofibers loaded with chlorhexidine (as an antiseptic). The top layer containing AgNPs, whose purpose was to protect the wound site against environmental germ invasion, was prepared by reducing silver nitrate to its nanoparticulate form through interaction with chitosan. The lower layer, which would be in direct contact with the injured site, contained the antibiotic drug needed to avoid wound infections which would otherwise interfere with the healing process. Initially, the upper layer was electrospun, followed sequentially by electrospinning the second layer, creating a bilayer nanofibrous mat. The morphology of the nanofibrous mats was studied by scanning electron microscopy and transmission electron microscopy, showing successful nanofiber production. X-ray diffraction confirmed the reduction of silver nitrate to AgNPs. Fourier transform infrared spectroscopy showed a successful incorporation of the material used in the produced nanofibrous mats. Thermal studies carried out by thermogravimetric analysis indicated that the PVP–drug-loaded layer had the highest thermal stability in comparison to other fabricated nanofibrous mats. Antimicrobial activities of the as-synthesized nanofibrous mats against Staphylococcus aureus, Escherichia coli, Pseudomonas aeruginosa, and Candida albicans were determined using disk diffusion method. The results indicated that the PEO–drug-loaded mat had the highest antibacterial activity, warranting further attention for numerous wound-healing applications. PMID:28356737

  2. Subsurface volatile content of martian double-layer ejecta (DLE) craters

    Science.gov (United States)

    Viola, Donna; McEwen, Alfred S.; Dundas, Colin M.; Byrne, Shane

    2017-01-01

    Excess ice is widespread throughout the martian mid-latitudes, particularly in Arcadia Planitia, where double-layer ejecta (DLE) craters also tend to be abundant. In this region, we observe the presence of thermokarstically-expanded secondary craters that likely form from impacts that destabilize a subsurface layer of excess ice, which subsequently sublimates. The presence of these expanded craters shows that excess ice is still preserved within the adjacent terrain. Here, we focus on a 15-km DLE crater that contains abundant superposed expanded craters in order to study the distribution of subsurface volatiles both at the time when the secondary craters formed and, by extension, remaining today. To do this, we measure the size distribution of the superposed expanded craters and use topographic data to calculate crater volumes as a proxy for the volumes of ice lost to sublimation during the expansion process. The inner ejecta layer contains craters that appear to have undergone more expansion, suggesting that excess ice was most abundant in that region. However, both of the ejecta layers had more expanded craters than the surrounding terrain. We extrapolate that the total volume of ice remaining within the entire ejecta deposit is as much as 74 km3 or more. The variation in ice content between the ejecta layers could be the result of (1) volatile preservation from the formation of the DLE crater, (2) post-impact deposition in the form of ice lenses; or (3) preferential accumulation or preservation of subsequent snowfall. We have ruled out (2) as the primary mode for ice deposition in this location based on inconsistencies with our observations, though it may operate in concert with other processes. Although none of the existing DLE formation hypotheses are completely consistent with our observations, which may merit a new or modified mechanism, we can conclude that DLE craters contain a significant quantity of excess ice today.

  3. Synthesis, characterization, and antimicrobial properties of novel double layer nanocomposite electrospun fibers for wound dressing applications.

    Science.gov (United States)

    Hassiba, Alaa J; El Zowalaty, Mohamed E; Webster, Thomas J; Abdullah, Aboubakr M; Nasrallah, Gheyath K; Khalil, Khalil Abdelrazek; Luyt, Adriaan S; Elzatahry, Ahmed A

    2017-01-01

    Herein, novel hybrid nanomaterials were developed for wound dressing applications with antimicrobial properties. Electrospinning was used to fabricate a double layer nanocomposite nanofibrous mat consisting of an upper layer of poly(vinyl alcohol) and chitosan loaded with silver nanoparticles (AgNPs) and a lower layer of polyethylene oxide (PEO) or polyvinylpyrrolidone (PVP) nanofibers loaded with chlorhexidine (as an antiseptic). The top layer containing AgNPs, whose purpose was to protect the wound site against environmental germ invasion, was prepared by reducing silver nitrate to its nanoparticulate form through interaction with chitosan. The lower layer, which would be in direct contact with the injured site, contained the antibiotic drug needed to avoid wound infections which would otherwise interfere with the healing process. Initially, the upper layer was electrospun, followed sequentially by electrospinning the second layer, creating a bilayer nanofibrous mat. The morphology of the nanofibrous mats was studied by scanning electron microscopy and transmission electron microscopy, showing successful nanofiber production. X-ray diffraction confirmed the reduction of silver nitrate to AgNPs. Fourier transform infrared spectroscopy showed a successful incorporation of the material used in the produced nanofibrous mats. Thermal studies carried out by thermogravimetric analysis indicated that the PVP-drug-loaded layer had the highest thermal stability in comparison to other fabricated nanofibrous mats. Antimicrobial activities of the as-synthesized nanofibrous mats against Staphylococcus aureus, Escherichia coli, Pseudomonas aeruginosa, and Candida albicans were determined using disk diffusion method. The results indicated that the PEO-drug-loaded mat had the highest antibacterial activity, warranting further attention for numerous wound-healing applications.

  4. Forming double layer-encapsulated quantum dots for bio-imaging and cell targeting

    Science.gov (United States)

    Fahmi, Mochamad Zakki; Chang, Jia-Yaw

    2013-01-01

    We report a simple and effective approach for the preparation of double layer-encapsulated quantum dots (DL-Qdots) composed of alkyl-capping ligands to interdigitate with hydrophobic, protective agents on the surface of AgInS2/ZnS quantum dots (Qdots), which allow phase transfer of hydrophobic Qdots from the organic phase into the aqueous phase. The alkyl-capping ligands consist of a hydrophobic, aliphatic chain and different functional terminal groups (e.g., carboxyl, amine, hydroxyl, and thiol groups) that can serve as reactive sites to chemically couple with other materials. The resulting DL-Qdots bearing various functional groups retain good fluorescence properties and show excellent solubility as well as stability over a range of pH in the aqueous phase. Cytotoxicity studies of DL-Qdots bearing carboxyl groups (DL-Qdots-COOH) were carried out against human cervical (HeLa) cancer cells to elicit no apparent toxicity even at high concentrations of 300 μg mL-1 and 24 h of incubation. To demonstrate their potential biomedical application, DL-Qdots-COOH were further conjugated with folate for staining in HeLa, human liver carcinoma (HepG2), and human breast (MCF-7) cancer cells. Confocal imaging characterization revealed that folate-conjugated DL-Qdots could target most specifically and effectively HeLa cells via folate receptor-mediated targeted delivery compared to HepG2 and MCF-7 cells. The generality and simplicity of this newly developed strategy can possibly be extended to a large variety of hydrophobic Qdots and nanocrystals whose surface protective agents have a long aliphatic chain.

  5. Reconsidering Ampere’s Double Layer Representation for Magnetic Field, Evaluation in a NDE Dection of a zero volume crack

    Directory of Open Access Journals (Sweden)

    M. Poloujadoff

    2014-04-01

    Full Text Available The paper has two different objectives. The first one is to  show that Ampere’s double layer method, which is equivalent  to one of the Maxwell equations, leads to the integration of a  simple closed form expression, thus avoiding the need to solve  complicated partial differential equations. The second aim is  to study the case of a zero volume defect in a NDE problem by  a perturbation method and the introduction of a double layer.  The combination of these two techniques leads to a very fast  solution of the problem. A practical example including

  6. Small-amplitude shock waves and double layers in dusty plasmas with opposite polarity charged dust grains

    Science.gov (United States)

    Amina, M.; Ema, S. A.; Mamun, A. A.

    2017-06-01

    Theoretical investigation is carried out for understanding the properties of nonlinear dust-acoustic (DA) waves in an unmagnetized dusty plasma whose constituents are massive, micron-sized, positive and negatively charged inertial dust grains along with q (nonextensive) distributed electrons and ions. The reductive perturbation method is employed in order to derive two types of nonlinear dynamical equations, namely, Burgers equation and modified Gardner equation (Gardner equation with dissipative term). They are also numerically analyzed to investigate the basic features (viz., polarity, amplitude, width, etc.) of shock waves and double layers. It has been observed that the effects of nonextensivity, opposite polarity charged dust grains, and different dusty plasma parameters have significantly modified the fundamental properties of shock waves and double layers. The results of this investigation may be used for researches of the nonlinear wave propagation in laboratory and space plasmas.

  7. Minimization of Cogging Force in Fractional-Slot Permanent Magnet Linear Motors with Double-Layer Concentrated Windings

    Directory of Open Access Journals (Sweden)

    Qian Wang

    2016-11-01

    Full Text Available Permanent magnet linear motors (PMLMs with double-layer concentrated windings generally show significant cogging forces due to the introduction of auxiliary teeth for eliminating the end-effect induced phase unbalance, even when the fractional-slot technology is applied. This paper presents a novel approach to reduce the cogging force by adjusting the armature core dimensions in fractional-slot PMLMs with double-layer concentrated windings, together with magnet skewing. It is shown that the proposed technique is capable of reducing the cogging force of the motor in an effective way, with the peak value minimized to less than 0.4% of the rated thrust force in the case study. Such a technique can also be applicable to other linear motors with appropriate changes.

  8. Defect guidance in kagome-clad fibers: the role of photonic band gaps and self-similarity of the lattice

    Science.gov (United States)

    Perez, H.; Zheltikov, A. M.

    2017-01-01

    We examine the influence of the structural self-similarity of the kagome lattice on the defect modes and waveguiding properties of hollow-core kagome-cladding fibers. We show that the guidance of such fibers is influenced by photonic band gaps (PBGs) which appear for a subset of the kagome lattice. Using these insights, we provide design considerations to further decrease loss in kagome-clad fibers.

  9. A Novel Degradation Estimation Method for a Hybrid Energy Storage System Consisting of Battery and Double-Layer Capacitor

    OpenAIRE

    Yuanbin Yu; Dongdong Zhang; Haitao Min; Yi Tang; Tao Zhu(GCAP-CASPER, Physics Department, Baylor University, One Bear Place, # 97316, Waco, TX 76798-7316, U.S.A.)

    2016-01-01

    This paper presents a new method for battery degradation estimation using a power-energy (PE) function in a battery/ultracapacitor hybrid energy storage system (HESS), and the integrated optimization which concerns both parameters matching and control for HESS has been done as well. A semiactive topology of HESS with double-layer capacitor (EDLC) coupled directly with DC-link is adopted for a hybrid electric city bus (HECB). In the purpose of presenting the quantitative relationship between s...

  10. Typhoon disaster zoning and prevention criteria——A double layer nested multi-objective probability model and its application

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    For prevention and mitigation of typhoon disasters in China, in this paper a double layer nested multi-objective probability model of typhoon disaster zoning and prevention criteria is proposed. The multivariate compound extreme value distribution (MCEVD) is used to predict the joint probability of seven typhoon characteristics and corresponding typhoon induced disasters. Predicted results can be used for both typhoon disaster zoning and corresponding prevention criteria along China coast.

  11. Typhoon disaster zoning and prevention criteria——A double layer nested multiobjective probability model and its application

    Institute of Scientific and Technical Information of China (English)

    LIU DeFu; PANG Liang; XIE BoTao; WU YuanKang

    2008-01-01

    For prevention and mitigation of typhoon disasters in China,in this paper a double layer nested multi-objective probability model of typhoon disaster zoning and prevention criteria is proposed.The multivariate compound extreme value distri-bution (MCEVD) is used to predict the joint probability of seven typhoon charac-teristics and corresponding typhoon induced disasters.Predicted results can be used for both typhoon disaster zoning and corresponding prevention criteria along China coast.

  12. Electrochemistry of silver iodide the capacity of the double layer at the silver iodide-water interface

    NARCIS (Netherlands)

    Lyklema, J.; Overbeek, J.Th.G.

    1961-01-01

    A method is described for obtaining differential double layer capacities on silver iodide. Especially the influence of the nature and concentration of indifferent electrolytes was investigated, viz., the nitrates of Li·, K·, Rb·, NH4·, H·, Tl·, Mg··, Ba··, Co··, Cd··, Pb··, La···, Th····, the fluori

  13. The effects of crystallographic surface inhomogeneity on double-layer structure and adsorption properties of cadmium electrodes

    Energy Technology Data Exchange (ETDEWEB)

    Korotkov, A.P.; Bezlepkina, E.B.; Damaskin, B.B.; Golov, E.F.

    1986-04-01

    At Cd electrodes, electric double-layer structure was studied in solutions of surface-inactive electrolytes, while the adsorption properties were studied in solutions containing surface-active organic cations. Splitting of the adsorption-desorption peak of tetrabutylammonium ions was found at a polished polycrystalline Cd electrode. The splitting was not seen in solutions containing tetrapropyl- or tetraethylammonium ions, nor at a cadmium surface renewed by cutting inside the solution.

  14. High-Performance Humidity Sensors Based on Double-Layer ZnO-TiO2 Nanofibers via Electrospinning

    Institute of Scientific and Technical Information of China (English)

    YUE Xue-Jun; HONG Tian-Sheng; XU Xing; LI Zhen

    2011-01-01

    ZnO and TiOi nanofibers are synthesized via electrospinning methods and characterized by x-ray diffraction, scanning electron microscopy, and transmission electron microscopy. Humidity sensors with double-layer sensing Sims are fabricated by spinning the ZnO and TiOz nanofibers on ceramic substrates sequentially. Compared with sensors loading only one type of nanoBber, the double-layer sensors exhibit much better sensing properties. The corresponding impedance changes more than four orders of magnitude within the whole humidity range from 11% to 95% relative humidity, and the response and recovery times are about 11 and 7s, respectively. Maximum hysteresis is around 1.5% RH, and excellent stability is also observed after 180 days. The humidity sensing mechanism is discussed in terms of the sensor structure. The experimental results provide a possible route for the design and fabrication of high performance humidity sensors based on one-dimensional nanomaterials.%@@ ZnO and TiO2 nanofibers are synthesized via electrospinning methods and characterized by x-ray diffraction,scanning electron microscopy,and transmission electron microscopy.Humidity sensors with double-layer sensing films are fabricated by spinning the ZnO and TiO2 nanofibers on ceramic substrates sequentially.Compared with sensors loading only one type of nanofiber,the double-layer sensors exhibit much better sensing properties.The corresponding impedance changes more than four orders of magnitude within the whole humidity range from 11%to 95%relative humidity,and the response and recovery times are about 11 and 7s,respectively.Maximum hysteresis is around 1.5%RH,and excellent stability is also observed after 180 days.The humidity sensing mechanism is discussed in terms of the sensor structure.The experimental results provide a possible route for the design and fabrication of high performance humidity sensors based on one-dimensional nanomaterials.

  15. Electrochemical Electron Transfer and Proton-Coupled Electron Transfer: Effects of Double Layer and Ionic Environment on Solvent Reorganization Energies

    Energy Technology Data Exchange (ETDEWEB)

    Ghosh, Soumya; Soudackov, Alexander; Hammes-Schiffer, Sharon

    2016-06-14

    Electron transfer and proton coupled electron transfer (PCET) reactions at electrochemical interfaces play an essential role in a broad range of energy conversion processes. The reorganization energy, which is a measure of the free energy change associated with solute and solvent rearrangements, is a key quantity for calculating rate constants for these reactions. We present a computational method for including the effects of the double layer and ionic environment of the diffuse layer in calculations of electrochemical solvent reorganization energies. This approach incorporates an accurate electronic charge distribution of the solute within a molecular-shaped cavity in conjunction with a dielectric continuum treatment of the solvent, ions, and electrode using the integral equations formalism polarizable continuum model. The molecule-solvent boundary is treated explicitly, but the effects of the electrode-double layer and double layer-diffuse layer boundaries, as well as the effects of the ionic strength of the solvent, are included through an external Green’s function. The calculated total reorganization energies agree well with experimentally measured values for a series of electrochemical systems, and the effects of including both the double layer and ionic environment are found to be very small. This general approach was also extended to electrochemical PCET and produced total reorganization energies in close agreement with experimental values for two experimentally studied PCET systems. This research was supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center, funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences.

  16. Organic double layer element driven by triboelectric nanogenerator: Study of carrier behavior by non-contact optical method

    Science.gov (United States)

    Chen, Xiangyu; Taguchi, Dai; Manaka, Takaaki; Iwamoto, Mitsumasa

    2016-02-01

    By using optical electric-field-induced second-harmonic generation (EFISHG) technique, we studied carrier behavior caused by contact electrification (CE) in an organic double-layer element. This double-layer sample was half suspended in the open air, where one electrode (anode or cathode) was connected with a Cu foil for electrification while the other electrode was floated. Results showed two distinct carrier behaviors, depending on the (anode or cathode) connections to the Cu foil, and these carrier behaviors were analyzed based on the Maxwell-Wagner model. The double-layer sample works as a simple solar cell device. The photovoltaic effect and CE process have been proved to be two paralleled effects without strong interaction with each other, while photoconductivity changing in the sample can enhance the relaxation of CE induced charges. By probing the carrier behavior in this half-suspended device, the EFISHG technique has been demonstrated to be an effective non-contact method for clarifying the CE effect on related energy harvesting devices and electronics devices. Meanwhile, the related physical analysis in this letter is also useful for elucidating the fundamental characteristic of hybrid energy system based on solar cell and triboelectric nanogenerator.

  17. Quantum spin liquid in a breathing kagome lattice

    Science.gov (United States)

    Schaffer, Robert; Huh, Yejin; Hwang, Kyusung; Kim, Yong Baek

    2017-02-01

    Motivated by recent experiments on the vanadium oxyfluoride material DQVOF, we examine possible spin liquid phases on a breathing kagome lattice of S =1 /2 spins. By performing a projective symmetry group analysis, we determine the possible phases for both fermionic and bosonic Z2 spin liquids on this lattice, and establish the correspondence between the two. The nature of the ground state of the Heisenberg model on the isotropic kagome lattice is a hotly debated topic, with both Z2 and U(1) spin liquids argued to be plausible ground states. Using variational Monte Carlo techniques, we show that a gapped Z2 spin liquid emerges as the clear ground state in the presence of this breathing anisotropy. Our results suggest that the breathing anisotropy helps to stabilize this spin liquid ground state, which may aid us in understanding the results of experiments and help to direct future numerical studies on these systems.

  18. Topological Magnon Bands in a Kagome Lattice Ferromagnet.

    Science.gov (United States)

    Chisnell, R; Helton, J S; Freedman, D E; Singh, D K; Bewley, R I; Nocera, D G; Lee, Y S

    2015-10-02

    There is great interest in finding materials possessing quasiparticles with topological properties. Such materials may have novel excitations that exist on their boundaries which are protected against disorder. We report experimental evidence that magnons in an insulating kagome ferromagnet can have a topological band structure. Our neutron scattering measurements further reveal that one of the bands is flat due to the unique geometry of the kagome lattice. Spin wave calculations show that the measured band structure follows from a simple Heisenberg Hamiltonian with a Dzyaloshinkii-Moriya interaction. This serves as the first realization of an effectively two-dimensional topological magnon insulator--a new class of magnetic material that should display both a magnon Hall effect and protected chiral edge modes.

  19. Magnetization plateaus of dipolar spin ice on kagome lattice

    Energy Technology Data Exchange (ETDEWEB)

    Xie, Y. L.; Wang, Y. L.; Yan, Z. B.; Liu, J.-M., E-mail: liujm@nju.edu.cn [Laboratory of Solid State Microstructures, Nanjing University, Nanjing 210093 (China)

    2014-05-07

    Unlike spin ice on pyrochlore lattice, the spin ice structure on kagome lattice retains net magnetic charge, indicating non-negligible dipolar interaction in modulating the spin ice states. While it is predicted that the dipolar spin ice on kagome lattice exhibits a ground state with magnetic charge order and √3 × √3 spin order, our work focuses on the magnetization plateau of this system. By employing the Wang-Landau algorithm, it is revealed that the lattice exhibits the fantastic three-step magnetization in response to magnetic field h along the [10] and [01] directions, respectively. For the h//[1 0] case, an additional √3/6M{sub s} step, where M{sub s} is the saturated magnetization, is observed in a specific temperature range, corresponding to a new state with charge order and short-range spin order.

  20. Thermal Hall Effect of Spin Excitations in a Kagome Magnet.

    Science.gov (United States)

    Hirschberger, Max; Chisnell, Robin; Lee, Young S; Ong, N P

    2015-09-04

    At low temperatures, the thermal conductivity of spin excitations in a magnetic insulator can exceed that of phonons. However, because they are charge neutral, the spin waves are not expected to display a thermal Hall effect. However, in the kagome lattice, theory predicts that the Berry curvature leads to a thermal Hall conductivity κ(xy). Here we report observation of a large κ(xy) in the kagome magnet Cu(1-3, bdc) which orders magnetically at 1.8 K. The observed κ(xy) undergoes a remarkable sign reversal with changes in temperature or magnetic field, associated with sign alternation of the Chern flux between magnon bands. The close correlation between κ(xy) and κ(xx) firmly precludes a phonon origin for the thermal Hall effect.

  1. Topological Magnon Bands in a Kagome Lattice Ferromagnet

    Science.gov (United States)

    Chisnell, R.; Helton, J. S.; Freedman, D. E.; Singh, D. K.; Bewley, R. I.; Nocera, D. G.; Lee, Y. S.

    2015-10-01

    There is great interest in finding materials possessing quasiparticles with topological properties. Such materials may have novel excitations that exist on their boundaries which are protected against disorder. We report experimental evidence that magnons in an insulating kagome ferromagnet can have a topological band structure. Our neutron scattering measurements further reveal that one of the bands is flat due to the unique geometry of the kagome lattice. Spin wave calculations show that the measured band structure follows from a simple Heisenberg Hamiltonian with a Dzyaloshinkii-Moriya interaction. This serves as the first realization of an effectively two-dimensional topological magnon insulator—a new class of magnetic material that should display both a magnon Hall effect and protected chiral edge modes.

  2. Linear spin-wave study of a quantum kagome ice

    Science.gov (United States)

    Owerre, S. A.; Burkov, A. A.; Melko, Roger G.

    2016-04-01

    We present a large-S study of a quantum spin ice Hamiltonian, introduced by Huang et al. [Phys. Rev. Lett. 112, 167203 (2014), 10.1103/PhysRevLett.112.167203], on the kagome lattice. This model involves a competition between the frustrating Ising term of classical kagome ice, a Zeeman magnetic field h , and a nearest-neighbor transverse spin-flip term SixSjx-SiySjy . Recent quantum Monte Carlo (QMC) simulations by Carrasquilla et al. [Nat. Commun. 6, 7421 (2015), 10.1038/ncomms8421], uncovered lobes of a disordered phase for large Ising interaction and h ≠0 —a putative quantum spin liquid phase. Here, we examine the nature of this model using large-S expansion. We show that the ground state properties generally have the same trends with those observed in QMC simulations. In particular, the large-S ground state phase diagram captures the existence of the disordered lobes.

  3. Damped Topological Magnons in the Kagome-Lattice Ferromagnets

    Science.gov (United States)

    Chernyshev, A. L.; Maksimov, P. A.

    2016-10-01

    We demonstrate that interactions can substantially undermine the free-particle description of magnons in ferromagnets on geometrically frustrated lattices. The anharmonic coupling, facilitated by the Dzyaloshinskii-Moriya interaction, and a highly degenerate two-magnon continuum yield a strong, nonperturbative damping of the high-energy magnon modes. We provide a detailed account of the effect for the S =1 /2 ferromagnet on the kagome lattice and propose further experiments.

  4. Nature of chiral spin liquids on the kagome lattice

    Science.gov (United States)

    Wietek, Alexander; Sterdyniak, Antoine; Läuchli, Andreas M.

    2015-09-01

    We investigate the stability and the nature of the chiral spin liquids which were recently uncovered in extended Heisenberg models on the kagome lattice. Using a Gutzwiller projected wave function approach, i.e., a parton construction, we obtain large overlaps with ground states of these extended Heisenberg models. We further suggest that the appearance of the chiral spin liquid in the time-reversal invariant case is linked to a classical transition line between two magnetically ordered phases.

  5. Striped spin liquid crystal ground state instability of kagome antiferromagnets.

    Science.gov (United States)

    Clark, Bryan K; Kinder, Jesse M; Neuscamman, Eric; Chan, Garnet Kin-Lic; Lawler, Michael J

    2013-11-01

    The Dirac spin liquid ground state of the spin 1/2 Heisenberg kagome antiferromagnet has potential instabilities. This has been suggested as the reason why it does not emerge as the ground state in large-scale numerical calculations. However, previous attempts to observe these instabilities have failed. We report on the discovery of a projected BCS state with lower energy than the projected Dirac spin liquid state which provides new insight into the stability of the ground state of the kagome antiferromagnet. The new state has three remarkable features. First, it breaks spatial symmetry in an unusual way that may leave spinons deconfined along one direction. Second, it breaks the U(1) gauge symmetry down to Z(2). Third, it has the spatial symmetry of a previously proposed "monopole" suggesting that it is an instability of the Dirac spin liquid. The state described herein also shares a remarkable similarity to the distortion of the kagome lattice observed at low Zn concentrations in Zn-paratacamite and in recently grown single crystals of volborthite suggesting it may already be realized in these materials.

  6. Synthesis, characterization, and antimicrobial properties of novel double layer nanocomposite electrospun fibers for wound dressing applications

    Directory of Open Access Journals (Sweden)

    Hassiba AJ

    2017-03-01

    Full Text Available Alaa J Hassiba,1 Mohamed E El Zowalaty,2 Thomas J Webster,3–5 Aboubakr M Abdullah,6 Gheyath K Nasrallah,7 Khalil Abdelrazek Khalil,8 Adriaan S Luyt,6 Ahmed A Elzatahry1 1Materials Science and Technology Program, College of Arts and Sciences, Qatar University, Doha, Qatar; 2School of Health Sciences, University of KwaZulu-Natal, Durban, South Africa; 3Department of Chemical Engineering, 4Department of Bioengineering, Northeastern University, Boston, MA, USA; 5Center of Excellence for Advanced Materials Research, King Abdulaziz University, Jeddah, Saudi Arabia; 6Center for Advanced Materials, 7Department of Biomedical Science, College of Health Sciences, Biomedical Research Center, Qatar University, Doha, Qatar; 8Department of Mechanical Engineering, College of Engineering, University of Sharjah, Sharjah, United Arab Emirates Abstract: Herein, novel hybrid nanomaterials were developed for wound dressing applications with antimicrobial properties. Electrospinning was used to fabricate a double layer nanocomposite nanofibrous mat consisting of an upper layer of poly(vinyl alcohol and chitosan loaded with silver nanoparticles (AgNPs and a lower layer of polyethylene oxide (PEO or polyvinylpyrrolidone (PVP nanofibers loaded with chlorhexidine (as an antiseptic. The top layer containing AgNPs, whose purpose was to protect the wound site against environmental germ invasion, was prepared by reducing silver nitrate to its nanoparticulate form through interaction with chitosan. The lower layer, which would be in direct contact with the injured site, contained the antibiotic drug needed to avoid wound infections which would otherwise interfere with the healing process. Initially, the upper layer was electrospun, followed sequentially by electrospinning the second layer, creating a bilayer nanofibrous mat. The morphology of the nanofibrous mats was studied by scanning electron microscopy and transmission electron microscopy, showing successful nanofiber

  7. Optical and photoelectrochemical studies on Ag{sub 2}O/TiO{sub 2} double-layer thin films

    Energy Technology Data Exchange (ETDEWEB)

    Li, Chuan, E-mail: cli10@yahoo.com [Department of Biomedical Engineering, National Yang Ming University, Taipei, Taiwan 11221 (China); Department of Mechanical Engineering, National Central University, Jhongli, Taoyuan, Taiwan 32001 (China); Hsieh, J.H. [Department of Materials Engineering, Ming Chi University of Technology, Taishan, Taipei, Taiwan 24301 (China); Cheng, J.C. [Department of Electronic Engineering, National Taipei University of Technology, Taipei, Taiwan 10608 (China); Huang, C.C. [Department of Biomedical Engineering, National Yang Ming University, Taipei, Taiwan 11221 (China)

    2014-11-03

    When two different oxides films stacked together, if the absorption (upper) layer has both its conduction and valence bands more negatively lower than that of the layer underneath, then the photo-excited electrons can be forwarded to the underneath layer to become an effect of energy storage. Recent studies discovered that the double-layers of Cu{sub 2}O/TiO{sub 2} films possess such capacity. In order to investigate this specific phenomenon, we use a DC magnetron reactive sputtering to deposit a double-layer of Ag{sub 2}O/TiO{sub 2} films on glass substrate. The film thicknesses of the double-layer are 300 nm and 200 nm respectively. X-Ray diffraction (XRD), scanning electron microscope (SEM) and UV–VIS–NIR photospectrometer and photoluminance tests were used to study the structure, morphology, optical absorption and band gaps of the stacked films. From XRD and SEM, we can confirm the microstructures of each layer. The UV–VIS–NIR spectrum revealed that the optical absorption of Ag{sub 2}O/TiO{sub 2} fell in between the single film of Ag{sub 2}O and TiO{sub 2}. Further, two band gaps were estimated for Ag{sub 2}O/TiO{sub 2} films based on the Beer-Lambert law and Tauc plot. Photoluminance and photoelectrochemical tests indicated that delayed emission by electron-hole recombination and photoelectrical current was effectively support the mechanism of electrons transfer from Ag{sub 2}O to TiO{sub 2} at Ag{sub 2}O/TiO{sub 2} interface in the double-layer films. - Highlights: • A double-layer of Ag{sub 2}O/TiO{sub 2} films was deposited on glass substrate by sputtering. • XRD confirms the nanocrystalline structures of the stack deposited films. • UV–VIS–NIR spectroscopy shows the enhanced of optical absorption in Ag{sub 2}O/TiO{sub 2}. • Photoluminance and photoelectrochemical tests show electron-hole separation effect.

  8. Barlowite: A Spin-1/2 Antiferromagnet with a Geometrically Perfect Kagome Motif.

    Science.gov (United States)

    Han, Tian-Heng; Singleton, John; Schlueter, John A

    2014-11-28

    We present thermodynamic studies of a new spin-1/2 antiferromagnet containing undistorted kagome lattices-barlowite Cu_{4}(OH)_{6}FBr. Magnetic susceptibility gives θ_{CW}=-136  K, while long-range order does not happen until T_{N}=15  K with a weak ferromagnetic moment μkagome lattice makes charge doping promising.

  9. Critical properties of a dilute O(n) model on the kagome lattice

    NARCIS (Netherlands)

    Li, B.; Guo, W.; Blöte, H.W.J.

    2008-01-01

    A critical dilute O(n) model on the kagome lattice is investigated analytically and numerically. We employ a number of exact equivalences which, in a few steps, link the critical O(n) spin model on the kagome lattice to the exactly solvable critical q-state Potts model on the honeycomb lattice with

  10. Low Loss Single-Mode Porous-Core Kagome Photonic Crystal Fiber for THz Wave Guidance

    DEFF Research Database (Denmark)

    Hasanuzzaman, G. K. M.; Habib, Selim; Abdur Razzak, S. M.;

    2015-01-01

    A novel porous-core kagome lattice photonic crystal fiber (PCF) is designed and analyzed in this paper for terahertz (THz) wave guidance. Using finite element method (FEM), properties of the proposed kagome lattice PCF are simulated in details including the effective material loss (EML...

  11. Generation of a VUV-to-visible Raman frequency comb in hydrogen-filled kagom\\'e photonic crystal fiber

    OpenAIRE

    Mridha, M. K.; Novoa, D.; Bauerschmidt, S. T.; Abdolvand, A.; Russell, P. St. J.

    2016-01-01

    We report the generation of a purely vibrational Raman comb, extending from the vacuum ultraviolet (184 nm) to the visible (478 nm), in hydrogen-filled kagom\\'e-style photonic crystal fiber pumped at 266 nm. Stimulated Raman scattering and molecular modulation processes are enhanced by higher Raman gain in the ultraviolet. Owing to the pressure-tunable normal dispersion landscape of the fiber-gas system in the ultraviolet, higher-order anti-Stokes bands are generated preferentially in higher-...

  12. Evidence for a gapped spin-liquid ground state in a kagome Heisenberg antiferromagnet.

    Science.gov (United States)

    Fu, Mingxuan; Imai, Takashi; Han, Tian-Heng; Lee, Young S

    2015-11-06

    The kagome Heisenberg antiferromagnet is a leading candidate in the search for a spin system with a quantum spin-liquid ground state. The nature of its ground state remains a matter of active debate. We conducted oxygen-17 single-crystal nuclear magnetic resonance (NMR) measurements of the spin-1/2 kagome lattice in herbertsmithite [ZnCu3(OH)6Cl2], which is known to exhibit a spinon continuum in the spin excitation spectrum. We demonstrated that the intrinsic local spin susceptibility χ(kagome), deduced from the oxygen-17 NMR frequency shift, asymptotes to zero below temperatures of 0.03J, where J ~ 200 kelvin is the copper-copper superexchange interaction. Combined with the magnetic field dependence of χ(kagome) that we observed at low temperatures, these results imply that the kagome Heisenberg antiferromagnet has a spin-liquid ground state with a finite gap.

  13. Anatomy of the Pulsating Double Layer Source in the Earth's Magnetotail

    Directory of Open Access Journals (Sweden)

    D. V. Sarafopoulos

    2015-07-01

    Full Text Available This investigation is composed of an observational part, plus a new theoretical model interpreting the related exhibited satellite datasets through an entirely new approach concerning the substorm's ultimate excitation mechanism. First, we present a few representative case studies showing the Bz component of the magnetic field to develop quasi-periodic negative deflections with periodicities ranging from T=15 to 60s in the central plasma sheet (CPS with persistent tailward plasma flows. The wave activity of Bz is much lower outside the CPS, while occasionally almost a monochromatic response is identified. In certain cases, a profound change of frequency is evident and happens most probably due to the Doppler-effect; there is a relation between the plasma velocity enhancement and the increase of frequency. When comparing the amplitude of Bz deflections to the lobe magnetic field, one plausibly may infer that the deflections reflect the very dynamics of the source itself. Therefore, we put forward the concept about "a pulsating source", and more specifically, we adopt the pulsating "twin Double Layer (DL structure" as the ultimate mechanism converting magnetic energy to kinetic. The DL acts either as a resistor or a capacitor and the twin-DL structure approximately behaves in a way similar to the cardiac cycle with repeated, rhythmic contractions and expansions. The contraction phase represents the abrupt local thinning of the plasma sheet (PS that terminates explosively, heating the plasma and accelerating energetic particles. The expansion phase corresponds to a local distention of the source, which also terminates explosively. The DLs are oppositely polarized depending on the range of Rc whether it fulfills the condition rgi ≤ Rc < 9 rgi or rge < Rc < rgi, where rgi (rge and Rc are the ion (electron gyro-radius and the curvature radius of the local magnetic field, respectively. In more detail, the "akis structure", as it was earlier

  14. Double-layered covered stent for the treatment of malignant oesophageal obstructions: Systematic review and meta-analysis

    Science.gov (United States)

    Hussain, Zeiad; Diamantopoulos, Athanasios; Krokidis, Miltiadis; Katsanos, Konstantinos

    2016-01-01

    AIM To investigate the efficacy of double-layered covered stent in the treatment of malignant oesophageal obstructions. METHODS A systematic review and meta-analysis was performed following the PRISMA process. PubMed (Medline), EMBASE (Excerpta Medical Database), AMED (Allied and Complementary medicine Database), Scopus and online content, were searched for studies reporting on the NiTi-S polyurethane-covered double oesophageal stent for the treatment of malignant dysphagia. Weighted pooled outcomes were synthesized with a random effects model to account for clinical heterogeneity. All studies reporting the outcome of palliative management of dysphagia due to histologically confirmed malignant oesophageal obstruction using double-layered covered nitinol stent were included. The level of statistical significance was set at α = 0.05. RESULTS Six clinical studies comprising 250 patients in total were identified. Pooled technical success of stent insertion was 97.2% (95%CI: 94.8%-98.9%; I2 = 5.8%). Pooled complication rate was 27.6% (95%CI: 20.7%-35.2%; I2 = 41.9%). Weighted improvement of dysphagia on a scale of 0-5 scoring system was -2.00 [95%CI: -2.29%-(-1.72%); I2 = 87%]. Distal stent migration was documented in 10 out of the 250 cases examined. Pooled stent migration rate was 4.7% (95%CI: 2.5%-7.7%; I2 = 0%). Finally, tumour overgrowth was reported in 34 out of the 250 cases with pooled rate of tumour overgrowth of 11.2% (95%CI: 3.7%-22.1%; I2 = 82.2%). No funnel plot asymmetry to suggest publication bias (bias = 0.39, P = 0.78). In the sensitivity analysis all results were largely similar between the fixed and random effects models. CONCLUSION The double-layered nitinol stent provides immediate relief of malignant dysphagia with low rates of stent migration and tumour overgrowth PMID:27678367

  15. FTRIFS biosensor based on double layer porous silicon as a LC detector for target molecule screening from complex samples.

    Science.gov (United States)

    Shang, Yunling; Zhao, Weijie; Xu, Erchao; Tong, Changlun; Wu, Jianmin

    2010-01-15

    Post-column identification of target compounds in complex samples is one of the major tasks in drug screening and discovery. In this work, we demonstrated that double layer porous silicon (PSi) attached with affinity ligand could serve as a sensing element for post-column detection of target molecule by Fourier transformed reflectometric interference spectroscopy (FTRIFS), in which trypsin and its inhibitor were used as the model probe-target system. The double layer porous silicon was prepared by electrical etching with a current density of 500 mA/cm(2), followed by 167 mA/cm(2). Optical measurements indicated that trypsin could infiltrate into the outer porous layer (porosity 83.6%), but was excluded by the bottom layer (porosity 52%). The outer layer, attached with trypsin by standard amino-silane and glutaraldehyde chemistry, could specifically bind with the trypsin inhibitor, acting as a sample channel, while the bottom layer served as a reference signal channel. The binding event between the attached trypsin and trypsin inhibitor samples could be detected by FTRIFS in real-time through monitoring the optical thickness change of the porous silicon layer. The baseline drift caused by sample matrix variation could be effectively eliminated by a signal correction method. Optical signals had a linear relationship with the concentration of trypsin inhibitor in the range of 10-200 ng mL(-1). The FTRIFS biosensor based on double layer porous silicon could be combined with a UV detector for screening the target molecule from complex component mixtures separated by a LC column. Using an LC-UV-FTRIFS system, a fraction containing a trypsin inhibitor could be separated from a soybean extract sample and identified in real-time.

  16. The fabrication of a double-layer atom chip with through silicon vias for an ultra-high-vacuum cell

    Science.gov (United States)

    Chuang, Ho-Chiao; Lin, Yun-Siang; Lin, Yu-Hsin; Huang, Chi-Sheng

    2014-04-01

    This study presents a double-layer atom chip that provides users with increased diversity in the design of the wire patterns and flexibility in the design of the magnetic field. It is more convenient for use in atomic physics experiments. A negative photoresist, SU-8, was used as the insulating layer between the upper and bottom copper wires. The electrical measurement results show that the upper and bottom wires with a width of 100 µm can sustain a 6 A current without burnout. Another focus of this study is the double-layer atom chips integrated with the through silicon via (TSV) technique, and anodically bonded to a Pyrex glass cell, which makes it a desired vacuum chamber for atomic physics experiments. Thus, the bonded glass cell not only significantly reduces the overall size of the ultra-high-vacuum (UHV) chamber but also conducts the high current from the backside to the front side of the atom chip via the TSV under UHV (9.5 × 10-10 Torr). The TSVs with a diameter of 70 µm were etched through by the inductively coupled plasma ion etching and filled by the bottom-up copper electroplating method. During the anodic bonding process, the electroplated copper wires and TSVs on atom chips also need to pass the examination of the required bonding temperature of 250 °C, under an applied voltage of 1000 V. Finally, the UHV test of the double-layer atom chips with TSVs at room temperature can be reached at 9.5 × 10-10 Torr, thus satisfying the requirements of atomic physics experiments under an UHV environment.

  17. The role of enamel proteins in protecting mature human enamel against acidic environments: a double layer force spectroscopy study.

    Science.gov (United States)

    Lubarsky, Gennady V; D'Sa, Raechelle A; Deb, Sanjukta; Meenan, Brian J; Lemoine, Patrick

    2012-12-01

    Characterisation of the electrostatic properties of dental enamel is important for understanding the interfacial processes that occur on a tooth surface and how these relate to the natural ability of our teeth to withstand chemical attack from the acids in many soft drinks. Whereas, the role of the mineral component of the tooth enamel in providing this resistance to acid erosion has been studied extensively, the influence of proteins that are also present within the structure is not well understood. In this paper, we report for the first time the use of double-layer force spectroscopy to directly measure electrostatic forces on as received and hydrazine-treated (deproteinated) enamel surfaces in solutions with different pH to determine how the enamel proteins influence acid erosion surface potential and surface charge of human dental enamel. The deproteination of the treated samples was confirmed by the loss of the amide bands (~1,300-1,700 cm(-1)) in the FTIR spectrum of the sample. The force characteristics observed were found to agree with the theory of electrical double layer interaction under the assumption of constant potential and allowed the surface charge per unit area to be determined for the two enamel surfaces. The values and, importantly, the sign of these adsorbed surface charges indicates that the protein content of dental enamel contributes significantly to the electrostatic double layer formation near the tooth surface and in doing so can buffer the apatite crystals against acid attack. Moreover, the electrostatic interactions within this layer are a driving factor for the mineral transfer from the tooth surface and the initial salivary pellicle formation.

  18. Suppression of ion conductance by electro-osmotic flow in nano-channels with weakly overlapping electrical double layers

    Science.gov (United States)

    Liu, Yang; Guo, Lingzi; Zhu, Xin; Ran, Qiushi; Dutton, Robert

    2016-08-01

    This theoretical study investigates the nonlinear ionic current-voltage characteristics of nano-channels that have weakly overlapping electrical double layers. Numerical simulations as well as a 1-D mathematical model are developed to reveal that the electro-osmotic flow (EOF) interplays with the concentration-polarization process and depletes the ion concentration inside the channels, thus significantly suppressing the channel conductance. The conductance may be restored at high electrical biases in the presence of recirculating vortices within the channels. As a result of the EOF-driven ion depletion, a limiting-conductance behavior is identified, which is intrinsically different from the classical limiting-current behavior.

  19. Improved photovoltaic efficiency on TiO{sub 2}/In{sub 2}S{sub 3} double layered electrodes

    Energy Technology Data Exchange (ETDEWEB)

    Kim, A-Young; Senthil, T.S.; Kwak, Byeong Sub; Kang, Misook, E-mail: mskang@ynu.ac.kr

    2015-01-15

    To enhance the photovoltaic efficiency of TiO{sub 2} multilayer, a scattering layer of In{sub 2}S{sub 3} particle is designed in dye-sensitized solar cell system. The SEM image of In{sub 2}S{sub 3} powder shows micro-sized 3D chrysanthemum-like shapes are formed by aggregation of wedge like nanosheets. The efficiency of the dye-sensitized solar cells assembled with In{sub 2}S{sub 3} scattering layer is higher than the DSSC assembled with double layered TiO{sub 2} electrode. The short-circuit current density increases approximately 21.65% over TiO{sub 2}/1.0 wt.% In{sub 2}S{sub 3}-DSSC and the incident photon-to-current conversion efficiency in the maximum peak also enhances about 17% compared to the DSSC assembled with double layered TiO{sub 2} electrode. Eventually, the maximum conversion efficiency obtained for TiO{sub 2}/1.0 wt.% In{sub 2}S{sub 3}-DSSC is 5.80%. This result indicates that the double layered TiO{sub 2}/In{sub 2}S{sub 3} electrode acts as a scattering layer of incident light path and that an increasing array of current density is obtained with more photons, which thus improves the quantum efficiency. - Highlights: • In{sub 2}S{sub 3} powder showed micro-sized 3D chrysanthemum-like shape. • In{sub 2}S{sub 3}-DSSCs exhibited the higher efficiencies than on the double layered TiO{sub 2}-DSSC. • The efficiency of TiO{sub 2}/1.0 wt.% In{sub 2}S{sub 3}-DSSC was approximately 5.80%. • TiO{sub 2}/1.0 wt.% In{sub 2}S{sub 3}-DSSC showed the slower recombination time than TiO{sub 2}/TiO{sub 2}-DSSC. • Electrons donated from dye-LUMO easily transferred to the conduction band of In{sub 2}S{sub 3}.

  20. New design of electric double layer capacitors with aqueous LiOH electrolyte as alternative to capacitor with KOH solution

    Science.gov (United States)

    Stepniak, Izabela; Ciszewski, Aleksander

    Activated carbon (AC) fiber cloths and a hydrophobic microporous polypropylene (PP) membrane, both modified with lithiated acetone oligomers, were used as electrodes and a separator in electric double layer capacitors (EDLCs) with aqueous lithium hydroxide (LiOH) as the electrolyte. Electrochemical characteristics of EDLCs were investigated by cyclic voltammetry (CV), galvanostatic charge-discharge cycle tests and impedance spectroscopy (EIS), compared with a case of the capacitor with aqueous potassium hydroxide (KOH) as an electrolyte. As a result, the capacitor with LiOH aqueous solution and a modified separator and electrodes was found to exhibit higher specific capacitance, maximum energy stored and maximum power than that with KOH aqueous solution.

  1. Physical and Mechanical Evaluation of Silicone-Based Double-Layer Adhesive Patch Intended for Keloids and Scar Treatment Therapy

    Directory of Open Access Journals (Sweden)

    Barbara Mikolaszek

    2016-11-01

    Full Text Available Growing interest in silicone elastomers for pharmaceutical purposes is due to both their beneficial material effect for scar treatment and their potential as drug carriers. Regarding their morphological structure, silicone polymers possess unique properties, which enable a wide range of applicability possibilities. The present study focused on developing a double-layer adhesive silicone film (DLASil by evaluating its physical and mechanical properties, morphology, and stability. DLASil suitability for treatment of scars and keloids was evaluated by measurement of tensile strength, elasticity modulus, and elongation. The results indicated that mechanical and physical properties of the developed product were satisfying.

  2. Suppression of ion conductance by electro-osmotic flow in nano-channels with weakly overlapping electrical double layers

    Directory of Open Access Journals (Sweden)

    Yang Liu

    2016-08-01

    Full Text Available This theoretical study investigates the nonlinear ionic current-voltage characteristics of nano-channels that have weakly overlapping electrical double layers. Numerical simulations as well as a 1-D mathematical model are developed to reveal that the electro-osmotic flow (EOF interplays with the concentration-polarization process and depletes the ion concentration inside the channels, thus significantly suppressing the channel conductance. The conductance may be restored at high electrical biases in the presence of recirculating vortices within the channels. As a result of the EOF-driven ion depletion, a limiting-conductance behavior is identified, which is intrinsically different from the classical limiting-current behavior.

  3. High-quality ion beams from a nanometric double-layer target and their application to hadron-therapy

    CERN Document Server

    Grech, M; Nuter, R; Grémillet, L; Lefebvre, E

    2010-01-01

    The production of ion beams from the interaction of a circularly polarized laser pulse with a nanometric double-layer target is discussed in the regime where all electrons are expelled from the target by the laser radiation pressure. Quasi-monochromatic, well-collimated ion beams are observed in two-dimensional particle-in-cell simulations. The ion beam properties are derived from a simple analytical model, and the possibility to control those properties by using a laser-pulse with sharp-rising edge is discussed. Application to hadron-therapy is finally considered.

  4. Studies on electrical double layer capacitor with a low-viscosity ionic liquid 1-ethyl-3-methylimidazolium tetracyanoborate as electrolyte

    Indian Academy of Sciences (India)

    G P Pandey; S A Hashmi

    2013-08-01

    The performance of an electrical double layer capacitor (EDLC) composed of high surface area activated carbon electrodes and a new ionic liquid, 1-ethyl-3-methylimidazolium tetracyanoborate, [EMIm]TCB, as the electrolyte has been investigated by impedance spectroscopy, cyclic voltammetry and galvanostatic charge–discharge studies. The high ionic conductivity (∼1.3 × 10-2 S cm-1 at 20 °C) and low viscosity (∼22 cP) of the ionic liquid, [EMIm]TCB, make it attractive as electrolyte for its use in EDLCs. The optimum capacitance value of 195.5 F g-1 of activated carbon has been achieved with stable cyclic performance.

  5. Temperature-Induced Magnetization Reorientation in GdFeCo/TbFeCo Exchange-Coupled Double Layer Films

    Institute of Scientific and Technical Information of China (English)

    王现英; 张约品; 李佐宜; 沈德芳; 干福熹

    2003-01-01

    GdFeCo/TbFeCo exchange-coupled double-layer (ECDL) films used for centre aperture type magnetically in duced super resolution were investigated through experiments and theoretical calculation. The ECDL films were prepared by the magnetron sputtering method. Polar Kerr effect measurements showed that magnetization reorientation occurred in the GdFeCo layer with the temperature rising, which was subsequently analysed by the micromagnetic calculation based on the mean-field theory and a continuum model. Theoretical analysis is in agreement well with the experimental results.

  6. Preliminary study on piezoresistive and piezoelectric properties of a double-layer soft material for tactile sensing

    Directory of Open Access Journals (Sweden)

    Dan He

    2015-06-01

    Full Text Available This paper describes a double-layer simplified sensor unit based on the interesting electromechanical properties of MWNT mixed by polymer composite and PVDF films, which is envisaged to imitate the distributed tactile receptors of human hands so as to help the disabled to recover the basic tactile perception. This paper shows the fabrication and performance research of such a new piezoelectric-piezoresistive composite material which indicates a promising .application in prosthtic hand.DOI: http://dx.doi.org/10.5755/j01.ms.21.2.6454

  7. High applicability of two-dimensional phosphorous in Kagome lattice predicted from first-principles calculations.

    Science.gov (United States)

    Chen, Peng-Jen; Jeng, Horng-Tay

    2016-03-16

    A new semiconducting phase of two-dimensional phosphorous in the Kagome lattice is proposed from first-principles calculations. The band gaps of the monolayer (ML) and bulk Kagome phosphorous (Kagome-P) are 2.00 and 1.11 eV, respectively. The magnitude of the band gap is tunable by applying the in-plane strain and/or changing the number of stacking layers. High optical absorption coefficients at the visible light region are predicted for multilayer Kagome-P, indicating potential applications for solar cell devices. The nearly dispersionless top valence band of the ML Kagome-P with high density of states at the Fermi level leads to superconductivity with Tc of ~9 K under the optimal hole doping concentration. We also propose that the Kagome-P can be fabricated through the manipulation of the substrate-induced strain during the process of the sample growth. Our work demonstrates the high applicability of the Kagome-P in the fields of electronics, photovoltaics, and superconductivity.

  8. Spontaneous formation of kagome network and Dirac half-semimetal on a triangular lattice

    Science.gov (United States)

    Akagi, Yutaka; Motome, Yukitoshi

    2015-04-01

    In spin-charge coupled systems, geometrical frustration of underlying lattice structures can give rise to nontrivial magnetic orders and electronic states. Here we explore such a possibility in the Kondo lattice model with classical localized spins on a triangular lattice by using a variational calculation and simulated annealing. We find that the system exhibits a four-sublattice collinear ferrimagnetic phase at 5/8 filling for a large Hund's-rule coupling. In this state, the system spontaneously differentiates into the up-spin kagome network and the isolated down-spin sites, which we call the kagome network formation. In the kagome network state, the system becomes Dirac half-semimetallic: The electronic structure shows a massless Dirac node at the Fermi level, and the Dirac electrons are almost fully spin polarized due to the large Hund's-rule coupling. We also study the effect of off-site Coulomb repulsion in the kagome network phase where the system is effectively regarded as a 1/3-filling spinless fermion system on the kagome lattice. We find that, at the level of the mean-field approximation, a √{3 }×√{3 } -type charge order occurs in the kagome network state, implying the possibility of fractional charge excitations in this triangular lattice system. Moreover, we demonstrate that the kagome network formation with fully polarized Dirac electrons are controllable by an external magnetic field.

  9. DSI: Distributed Service Integration for Service Grid

    Institute of Scientific and Technical Information of China (English)

    YANG GuangWen(杨广文); SHI ShuMing(史树明); WANG DingXing(王鼎兴); HUANG QiFeng(黄启锋); LIU XueZheng(刘学铮)

    2003-01-01

    This paper presents DSI, a distributed service discovery and integration utility for service grid. The goal of DSI is efficiently to improve service publishing, deletion and lookup,decentralized control, scalability, and availability. DSI comprises a logically global metadata pool and a double-layered DHT (Distributed Hash Table). Efficient service publishing and lookup are achieved by adopting DHT. Clean service deletion is guaranteed by time-stamping. And system availability is improved by replication combined with automatic indexer selection. Experiments show that DSI can achieve short response time, low processing cost and high availability.

  10. Rate of thermal transitions in kagome spin ice

    Science.gov (United States)

    Liashko, S. Y.; Uzdin, V. M.; Jónsson, H.

    2016-08-01

    The rate of thermal transitions in a kagome spin ice element is calculated using harmonic transition state theory for magnetic systems. Each element consists of six prolate magnetic islands. Minimum energy paths on the multidimensional energy surface are found to estimate activation energy. Vibrational frequencies are also calculated to estimate the rate of the various transitions. An overall transition rate between equivalent ground states is calculated by using the stationary state approximation including all possible transition paths. The resulting transition rate is in a good agreement with experimentally measured lifetime.

  11. Discrete flat-band solitons in the Kagome lattice

    CERN Document Server

    Vicencio, Rodrigo A

    2013-01-01

    We consider a model for a two-dimensional Kagome-lattice with defocusing nonlinearity, and show that families of localized discrete solitons may bifurcate from localized linear modes of the flat band with zero power threshold. Such fundamental nonlinear modes exist for arbitrarily strong nonlinearity, and correspond to unique configurations in the limit of zero inter-site coupling. We analyze their linear stability, and show that by choosing dynamical perturbations close to soft internal modes, a switching between solitons of different families may be obtained. In a window of small values of norm, a symmetry-broken localized state is found as the lowest-energy state.

  12. Confined spin wave spectra of Kagome artificial spin ice arrays

    Science.gov (United States)

    Panagiotopoulos, I.

    2017-01-01

    The spin wave modes of elongated magnetic islands arranged in Kagome artificial spin-ice arrays are micromagnetically simulated in the frequency regime between 3 and 16 GHz. The edge modes are more suitable in order to detect the signatures of various types of local order of the spin-ice lattice as they are much more sensitive to the magnetic configurations of neighboring elements. The spectra of arrays consisting up to 30 elements can be decomposed to those originating from local magnetic states of their vertices.

  13. Wave propagation in reconfigurable magneto-elastic kagome lattice structures

    Science.gov (United States)

    Schaeffer, Marshall; Ruzzene, Massimo

    2015-05-01

    The paper discusses the wave propagation characteristics of two-dimensional magneto-elastic kagome lattices. Mechanical instabilities caused by magnetic interactions are exploited in combination with particle contact to bring about changes in the topology and stiffness of the lattices. The analysis uses a lumped mass system of particles, which interact through axial and torsional elastic forces as well as magnetic forces. The propagation of in-plane waves is predicted by applying Bloch theorem to lattice unit cells with linearized interactions. Elastic wave dispersion in these lattices before and after topological changes is compared, and large differences are highlighted.

  14. Topologically nontrivial magnons at an interface of two kagome ferromagnets

    Science.gov (United States)

    Mook, Alexander; Henk, Jürgen; Mertig, Ingrid

    2015-06-01

    Magnon band structures of topological magnon insulators exhibit a nontrivial topology due to the Dzyaloshinskii-Moriya interaction, which manifests itself by topologically protected edge magnons. Bringing two topological magnon insulators into contact can lead to nontrivial unidirectional magnons located at their common interface. We study theoretically interfaces of semi-infinite kagome ferromagnets in various topological phases, with a focus on the formation and the confinement of nontrivial interface magnons. We analyze generic magnon dispersions with respect to the number of band gaps and the respective winding numbers. Eventually, we prove that interfaces of topologically identical phases can host nontrivial interface magnons as well.

  15. Propagation and ghosts in the classical kagome antiferromagnet.

    Science.gov (United States)

    Robert, J; Canals, B; Simonet, V; Ballou, R

    2008-09-12

    We investigate the classical spin dynamics of the kagome antiferromagnet by combining Monte Carlo and spin dynamics simulations. We show that this model has two distinct low temperature dynamical regimes, both sustaining propagative modes. The expected gauge invariance type of the low energy, low temperature, out-of-plane excitations is also evidenced in the nonlinear regime. A detailed analysis of the excitations allows us to identify ghosts in the dynamical structure factor, i.e., propagating excitations with a strongly reduced spectral weight. We argue that these dynamical extinction rules are of geometrical origin.

  16. Gapless chiral spin liquid in a kagome Heisenberg model

    Science.gov (United States)

    Bieri, Samuel; Messio, Laura; Bernu, Bernard; Lhuillier, Claire

    2015-08-01

    Motivated by recent experiments on the Heisenberg S =1 /2 quantum spin liquid candidate material kapellasite, we classify all possible chiral (time-reversal symmetry breaking) spin liquids with fermionic spinons on the kagome lattice. We obtain the phase diagram for the physically relevant extended Heisenberg model, comparing the energies of a wide range of microscopic variational wave functions. We propose that, at low temperature, kapellasite exhibits a gapless chiral spin liquid phase with spinon Fermi surfaces. This two-dimensional state inherits many properties of the nearby one-dimensional phase of decoupled antiferromagnetic spin chains, but also shows some remarkable differences. We discuss the spin structure factors and other physical properties.

  17. Density matrix renormalization group numerical study of the kagome antiferromagnet.

    Science.gov (United States)

    Jiang, H C; Weng, Z Y; Sheng, D N

    2008-09-12

    We numerically study the spin-1/2 antiferromagnetic Heisenberg model on the kagome lattice using the density-matrix renormalization group method. We find that the ground state is a magnetically disordered spin liquid, characterized by an exponential decay of spin-spin correlation function in real space and a magnetic structure factor showing system-size independent peaks at commensurate magnetic wave vectors. We obtain a spin triplet excitation gap DeltaE(S=1)=0.055+/-0.005 by extrapolation based on the large size results, and confirm the presence of gapless singlet excitations. The physical nature of such an exotic spin liquid is also discussed.

  18. Ion-acoustic solitons, double layers and supersolitons in a plasma with two ion- and two electron species

    Energy Technology Data Exchange (ETDEWEB)

    Olivier, C. P., E-mail: colivier@sansa.org.za; Maharaj, S. K., E-mail: smaharaj@sansa.org.za [South African National Space Agency (SANSA) Space Science, P. O. Box 32, Hermanus 7200 (South Africa); Bharuthram, R., E-mail: rbharuthram@uwc.ac.za [University of the Western Cape, Robert Sobukwe Road, Bellville 7535 (South Africa)

    2015-08-15

    The polarity of ion-acoustic solitons that arise in a plasma with two (same mass, different temperature) ion species and two (different temperature) electron species is investigated. Two different fluid models are compared. The first model treats all species as adiabatic fluids, while the second model treats the ion species as adiabatic, and the electron species as isothermal. Nonlinear structures are analysed via the reductive perturbation analysis and pseudo-potential analysis. Each model supports both slow and fast ion-acoustic solitons, associated with the two (slow and fast) ion-acoustic speeds. The models support both positive and negative polarity solitons associated with the slow ion-acoustic speed. Moreover, results are in good agreement, and both models support positive and negative polarity double layers. For the fast ion-acoustic speed, the first model supports only positive polarity solitons, while the second model supports solitons of both polarity, coexistence of positive and negative polarity solitons, double layers and supersolitons. A novel feature of our analysis is the evaluation of nonlinear structures at critical number densities where polarity changes occur. This analysis shows that solitons that occur at the acoustic speed are neither a necessary nor a sufficient condition for the phenomenon of coexistence. The relationship between the existence regions of supersolitons and soliton polarity is also discussed.

  19. Enhanced absorption properties of ordered mesoporous carbon/Co-doped ordered mesoporous carbon double-layer absorbers

    Science.gov (United States)

    Guo, Shao-Li; Wang, Liu-Ding; Wang, Yi-Ming; Wu, Hong-Jing; Shen, Zhong-Yuan

    2013-04-01

    Ordered mesoporous carbon (OMC) and metal-doped (M-doped) OMC composites are prepared, and their electromagnetic (EM) parameters are measured. Using the measured EM parameters we calculate the EM wave absorption properties of a double-layer absorber, which is composed of OMC as an absorbing layer and M-doped OMC as the matching layer. The calculated results show that the EM wave absorption performance of OMC/OMC—Co (2.2 mm/2.1 mm) is improved remarkably. The obtained effective absorption bandwidth is up to 10.3 GHz and the minimum reflection loss reaches -47.6 dB at 14.3 GHz. The enhanced absorption property of OMC/OMC—Co can be attributed to the impedance match between the air and the absorber. Moreover, it can be found that for the absorber with a given matching layer, a larger value of Δtanδɛ(= tanδ69 absorbing - tanδɛ matching) can induce better absorption performance, indicating that the difference in impedance between the absorbing layer and the matching layer plays an important role in improving the absorption property of double-layer absorbers.

  20. A novel double-layer molecularly imprinted polymer film based surface plasmon resonance for determination of testosterone in aqueous media

    Science.gov (United States)

    Tan, Yuan; Jing, Lijing; Ding, Yonghong; Wei, Tianxin

    2015-07-01

    This work aimed to prepare a novel double-layer structure molecularly imprinted polymer film (MIF) on the surface plasmon resonance (SPR) sensor chips for detection of testosterone in aqueous media. The film was synthesized by in-situ UV photo polymerization. Firstly, the modification of gold surface of SPR chip was performed by 1-dodecanethiol. Then double-layer MIF was generated on the 1-dodecanethiol modified gold surface. The non-modified and imprinted surfaces were characterized by atomic force microscopy (AFM), fourier transform infrared (FTIR) spectroscopy and contact angle measurements. Analysis of SPR spectroscopy showed that the imprinted sensing film displayed good selectivity for testosterone compared to other analogues and the non-imprinted polymer film (NIF). Within the concentrations range of 1 × 10-12-1 × 10-8 mol/L, the coupling angle changes of SPR were linear with the negative logarithm of testosterone concentrations (R2 = 0.993). Based on a signal/noise ratio of three, the detection limit was estimated to be 10-12 mol/L. Finally, the developed MIF was successfully applied to the seawater detection of testosterone. The results in the experiments suggested that a combination of SPR sensing with MIF was a promising alternative method for detection of testosterone in aqueous media.

  1. Double-layered TiO2-SiO2 nanostructured films with self-cleaning and antireflective properties.

    Science.gov (United States)

    Zhang, Xintong; Fujishima, Akira; Jin, Ming; Emeline, Alexei V; Murakami, Taketoshi

    2006-12-21

    Dual function of self-cleaning and antireflection can be created in double-layered TiO2-SiO2 nanostructured films. The film were prepared by (1) layer-by-layer deposition of multilayered SiO2 nanoparticles with polydiallyldimethylammonium (PDDA) cations, (2) layer-by-layer deposition of multilayered titanate nanosheets with polications on PDDA/SiO2 multilayer films, and (3) burning out the polymer and converting titanate nanosheets into TiO2 by hearing at 500 degrees C. The as-prepared films, consisting of a porous SiO2 bottom layer and a dense TiO2 top layer, improved the transmittance of glass or quartz substrates, as demonstrated by transmission spectra collected at normal incidence. The photocatalytic properties of the films were studied by the change of the water contact angle together with the decay of the IR absorption of the hydrocarbon chain of octadecylphosphonic-acid-modified films under 2.6 mW cm-2 UV illumination. Both the antireflective and the photocatalytic properties of the films were dependent on the number of PDDA/nanosheet bilayers deposited. however, excellent surface wettability of the films for water was obtained, independent of the preparation conditions. The experimental findings are discussed in terms of the special structure of the double-layered nanostructured film.

  2. Performance of Electric Double Layer Capacitors using Active Carbons Prepared from Petroleum Coke by KOH and Vapor Re-Etching

    Institute of Scientific and Technical Information of China (English)

    2003-01-01

    The electrochemical storage of energy in a special kind of active carbon materials used as capacitor electrodes isconsidered. Pet roleum coke was used for preparation of carbons with different porosities by KOH and vapor etchingwith catalysis of FeCl3 in turn. Carbon electrodes were fabricated and used as electrodes of double layer capacitors.Nitrogen adsorption was used to characterize the porous structure of the carbons. The electrochemical performanceof the capacitors in 6 mol/L KOH was investigated with constant current charge and discharge experiments. Aspecific capacitance larger than 160 F/g was achieved with an electrode composed of 75% active carbon with aspecific surface area of 1180 m2/g and 20% graphite as conductive agent. Evaluation of capacitor performance wasconducted by different techniques, e.g. voltammetry and impedance spectroscopy. Characteristics of the capacitorwere also discussed. A hybrid power source consisting of nickel- hydrogen and double layer capacitor was demonstratedby powering successfully a simulated power load encountered in communication equipment.

  3. Local semi-empirical formulae for the contact values of the singlet distribution functions of a double layer.

    Science.gov (United States)

    Silvestre-Alcantara, Whasington; Bhuiyan, Lutful Bari; Henderson, Douglas

    2010-05-13

    The electrochemical double layer is an important practical and theoretical problem. Generally speaking, experiment gives valuable information about quantities, such as potential differences, that involve integrals of density and charge profiles but does not provide direct information about the profiles themselves. Computer simulations have given numerical information about these profiles. However, explicit expressions are useful in understanding these data. For some years an exact expression has been known for the contact value of total density profile of the ions in the double layer but, until recently, an expression for the contact value of the more important charge profile has been lacking. A few years ago, a semi-empirical local result for the charge profile, valid at low electrode charge, was proposed and, very recently, extended to higher electrode charge. This expression contains a parameter; the effect of variations in this parameter is explored in this paper and the result is compared with a large set of simulation data for the contact values of various profiles that we have accumulated in the past few years. The agreement of the semi-empirical expression with our simulation results is excellent. The best values for this parameter are fairly close to the value suggested by theory.

  4. Rapid recovery of polycrystalline silicon from kerf loss slurry using double-layer organic solvent sedimentation method

    Science.gov (United States)

    Xing, Peng-fei; Guo, Jing; Zhuang, Yan-xin; Li, Feng; Tu, Gan-feng

    2013-10-01

    The rapid development of photovoltaic (PV) industries has led to a shortage of silicon feedstock. However, more than 40% silicon goes into slurry wastes due to the kerf loss in the wafer slicing process. To effectively recycle polycrystalline silicon from the kerf loss slurry, an innovative double-layer organic solvent sedimentation process was presented in the paper. The sedimentation velocities of Si and SiC particles in some organic solvents were investigated. Considering the polarity, viscosity, and density of solvents, the chloroepoxy propane and carbon tetrachloride were selected to separate Si and SiC particles. It is found that Si and SiC particles in the slurry waste can be successfully separated by the double-layer organic solvent sedimentation method, which can greatly reduce the sedimentation time and improve the purity of obtained Si-rich and SiC-rich powders. The obtained Si-rich powders consist of 95.04% Si, and the cast Si ingot has 99.06% Si.

  5. Size asymmetric hard spheres as a convenient model for the capacitance of the electrical double layer of an ionic liquid.

    Science.gov (United States)

    Lamperski, Stanisław; Sosnowska, Joanna; Bhuiyan, Lutful Bari; Henderson, Douglas

    2014-01-07

    Even though ionic liquids are composed of nonspherical ions, it is shown here that the general features of the capacitance of an electrical double layer can be obtained using a charged hard sphere model. We have shown in our earlier studies that at high electrolyte concentrations or large magnitudes of the electrode charge density the fact that the ions have a finite size, and are not point ions, cause the capacitance near the potential of zero charge to increase and change from a minimum to a maximum as the ionic concentration is increased and to decrease as the magnitude of the electrode charge density increases. Here, we show that the asymmetry of the capacitance of an ionic liquid can be explained qualitatively by using spherical ions of different size without attempting to introduce the ionic shape in a detailed manner. This means that the general features of the capacitance of the double layer of an ionic liquid can be studied without using a complex model, although the study of the density or charge profiles of an ionic fluid would require one. However, this is often unnecessary in the analysis of many experiments.

  6. Enhanced absorption properties of ordered mesoporous carbon/Co-doped ordered mesoporous carbon double-layer absorbers

    Institute of Scientific and Technical Information of China (English)

    Guo Shao-Li; Wang Liu-Ding; Wang Yi-Ming; Wu Hong-Jing; Shen Zhong-Yuan

    2013-01-01

    Ordered mesoporous carbon (OMC) and metal-doped (M-doped) OMC composites are prepared,and their electromagnetic (EM) parameters are measured.Using the measured EM parameters we calculate the EM wave absorption properties of a double-layer absorber,which is composed of OMC as an absorbing layer and M-doped OMC as the matching layer.The calculated results show that the EM wave absorption performance of OMC/OMC-Co (2.2 mm/2.1 mm) is improved remarkably.The obtained effective absorption bandwidth is up to 10.3 GHz and the minimum reflection loss reaches -47.6 dB at 14.3 GHz.The enhanced absorption property of OMC/OMC-Co can be attributed to the impedance match between the air and the absorber.Moreover,it can be found that for the absorber with a given matching layer,a larger value of △tanδε (=tan δε absorbing--tan δε matching) can induce better absorption performance,indicating that the difference in impedance between the absorbing layer and the matching layer plays an important role in improving the absorption property of double-layer absorbers.

  7. Yttria-stabilized zirkonia / gadolinium zirconate double-layer plasma-sprayed thermal barrier coating systems (TBCs)

    Energy Technology Data Exchange (ETDEWEB)

    Bakan, Emine

    2015-07-01

    Thermal barrier coating (TBC) research and development is driven by the desirability of further increasing the maximum inlet temperature in a gas turbine engine. A number of new top coat ceramic materials have been proposed during the last decades due to limited temperature capability (1200 C) of the state-of-the-art yttria-stabilized zirconia (7 wt. % Y{sub 2}O{sub 3}-ZrO{sub 2}, YSZ) at long term operation. Zirconate pyrochlores of the large lanthanides((Gd → La){sub 2}Zr{sub 2}O{sub 7}) have been particularly attractive due to their higher temperature phase stability than that of the YSZ. Nonetheless, the issues related with the implementation of pyrochlores such as low fracture toughness and formation of deleterious interphases with thermally grown oxide (TGO, Al{sub 2}O{sub 3}) were reported. The implication was the requirement of an interlayer between the pyrochlores and TGO, which introduced double-layer systems to the TBC literature. Furthermore, processability issues of pyrochlores associated with the different evaporation rates of lanthanide oxides and zirconia resulting in unfavorable composition variations in the coatings were addressed in different studies. After all, although the material properties are available, there is a paucity of data in the literature concerning the properties of the coatings made of pyrochlores. From the processability point of view the most reported pyrochlore is La{sub 2}Zr{sub 2}O{sub 7}. Hence, the goal of this research was to investigate plasma-sprayed Gd{sub 2}Zr{sub 2}O{sub 7} (GZO) coatings and YSZ/GZO double-layer TBC systems. Three main topics were examined based on processing, performance and properties: (i) the plasma spray processing of the GZO and its impact on the microstructural and compositional properties of the GZO coatings; (ii) the cycling lifetime of the YSZ/GZO double-layer systems under thermal gradient at a surface temperature of 1400 C; (iii) the properties of the GZO and YSZ coatings such as

  8. Generation of a VUV-to-visible Raman frequency comb in hydrogen-filled kagom\\'e photonic crystal fiber

    CERN Document Server

    Mridha, M K; Bauerschmidt, S T; Abdolvand, A; Russell, P St J

    2016-01-01

    We report the generation of a purely vibrational Raman comb, extending from the vacuum ultraviolet (184 nm) to the visible (478 nm), in hydrogen-filled kagom\\'e-style photonic crystal fiber pumped at 266 nm. Stimulated Raman scattering and molecular modulation processes are enhanced by higher Raman gain in the ultraviolet. Owing to the pressure-tunable normal dispersion landscape of the fiber-gas system in the ultraviolet, higher-order anti-Stokes bands are generated preferentially in higher-order fiber modes. The results pave the way towards tunable fiber-based sources of deep- and vacuum ultraviolet light for applications in, e.g., spectroscopy and biomedicine.

  9. The Heisenberg antiferromagnet on the square-kagomé lattice

    Directory of Open Access Journals (Sweden)

    J. Richter

    2009-01-01

    Full Text Available We discuss the ground state, the low-lying excitations as well as high-field thermodynamics of the Heisenberg antiferromagnet on the two-dimensional square-kagomé lattice. This magnetic system belongs to the class of highly frustrated spin systems with an infinite non-trivial degeneracy of the classical ground state as it is also known for the Heisenberg antiferromagnet on the kagomé and on the star lattice. The quantum ground state of the spin-half system is a quantum paramagnet with a finite spin gap and with a large number of non-magnetic excitations within this gap. We also discuss the magnetization versus field curve that shows a plateaux as well as a macroscopic magnetization jump to saturation due to independent localized magnon states. These localized states are highly degenerate and lead to interesting features in the low-temperature thermodynamics at high magnetic fields such as an additional low-temperature peak in the specific heat and an enhanced magnetocaloric effect.

  10. Pulsed field magnetization in rare-earth kagome systems

    Science.gov (United States)

    Hoch, M. J. R.; Zhou, H. D.; Mun, E.; Harrison, N.

    2016-02-01

    The rare-earth kagome systems R 3Ga5SiO14 (R  =  Nd or Pr) exhibit cooperative paramagnetism at low temperatures. Evidence for correlated spin clusters in these weakly frustrated systems has previously been obtained from neutron scattering and from ESR and NMR results. The present pulsed field (0-60 T, 25 ms) magnetization measurements made on single crystals of Nd3Ga5SiO14 (NGS) and Pr3Ga5SiO14 (PGS) at temperatures down to 450 mK have revealed striking differences in the magnetic responses of the two materials. For NGS the magnetization shows a low field plateau, saturation in high transient fields, and significant hysteresis while the PGS magnetization does not saturate in transient fields up to 60 T and shows no hysteresis or plateaus. Nd3+ is a Kramers ion while Pr3+ is a non-Kramers ion and the crystal field effects are quite different in the two systems. For the conditions used in the experiments the magnetization behavior is not in agreement with Heisenberg model predictions for kagome systems in which easy-axis anisotropy is much larger than the exchange coupling. The extremely slow spin dynamics found below 4 K in NGS is, however, consistent with the model for Kramers ions and provides a basis for explaining the pulsed field magnetization features.

  11. Theory of quantum kagome ice and vison zero modes

    Science.gov (United States)

    Huang, Yi-Ping; Hermele, Michael

    2017-02-01

    We derive an effective Z2 gauge theory to describe the quantum kagome ice (QKI) state that has been observed by Carrasquilla et al. [Nat. Commun. 6, 7421 (2015), 10.1038/ncomms8421] in Monte Carlo studies of the S =1/2 kagome XYZ model in a Zeeman field. The numerical results on QKI are consistent with, but do not confirm or rule out, the hypothesis that it is a Z2 spin liquid. Our effective theory allows us to explore this hypothesis and make a striking prediction for future numerical studies, namely, that symmetry-protected vison zero modes arise at lattice disclination defects, leading to a Curie defect term in the spin susceptibility, and a characteristic (Ndis-1 )ln2 contribution to the entropy, where Ndis is the number of disclinations. Only the Z2 Ising symmetry is required to protect the vison zero modes. This is remarkable because a unitary Z2 symmetry cannot be responsible for symmetry-protected degeneracies of local degrees of freedom. We also discuss other signatures of symmetry fractionalization in the Z2 spin liquid, and phase transitions out of the Z2 spin liquid to nearby ordered phases.

  12. Pulsed field magnetization in rare-earth kagome systems.

    Science.gov (United States)

    Hoch, M J R; Zhou, H D; Mun, E; Harrison, N

    2016-02-03

    The rare-earth kagome systems R 3Ga5SiO14 (R  =  Nd or Pr) exhibit cooperative paramagnetism at low temperatures. Evidence for correlated spin clusters in these weakly frustrated systems has previously been obtained from neutron scattering and from ESR and NMR results. The present pulsed field (0-60 T, 25 ms) magnetization measurements made on single crystals of Nd3Ga5SiO14 (NGS) and Pr3Ga5SiO14 (PGS) at temperatures down to 450 mK have revealed striking differences in the magnetic responses of the two materials. For NGS the magnetization shows a low field plateau, saturation in high transient fields, and significant hysteresis while the PGS magnetization does not saturate in transient fields up to 60 T and shows no hysteresis or plateaus. Nd(3+) is a Kramers ion while Pr(3+) is a non-Kramers ion and the crystal field effects are quite different in the two systems. For the conditions used in the experiments the magnetization behavior is not in agreement with Heisenberg model predictions for kagome systems in which easy-axis anisotropy is much larger than the exchange coupling. The extremely slow spin dynamics found below 4 K in NGS is, however, consistent with the model for Kramers ions and provides a basis for explaining the pulsed field magnetization features.

  13. Kagome lattice from an exciton-polariton perspective

    Science.gov (United States)

    Gulevich, D. R.; Yudin, D.; Iorsh, I. V.; Shelykh, I. A.

    2016-09-01

    We study a system of microcavity pillars arranged into a kagome lattice. We show that polarization-dependent tunnel coupling of microcavity pillars leads to the emergence of the effective spin-orbit interaction consisting of the Dresselhaus and Rashba terms, similar to the case of polaritonic graphene studied earlier. The appearance of the effective spin-orbit interaction combined with the time-reversal symmetry breaking resulting from the application of the magnetic field leads to the nontrivial topological properties of the Bloch bundles of polaritonic wave function. These are manifested in the opening of the gap in the band structure and topological edge states localized on the boundary. Such states are analogs of the edge states arising in topological insulators. Our study of polarization properties of the edge states clearly demonstrates that opening of the gap is associated with the band inversion in the region of the Dirac points of the Brillouin zone where the two bands corresponding to polaritons of opposite polarizations meet. For one particular type of boundary we observe a highly nonlinear energy dispersion of the edge state which makes a polaritonic kagome lattice a promising system for observation of edge state solitons.

  14. Supersymmetry protected topological phases of isostatic lattices and kagome antiferromagnets

    Science.gov (United States)

    Lawler, Michael J.

    2016-10-01

    I generalize the theory of phonon topological band structures of isostatic lattices to frustrated antiferromagnets. I achieve this with a discovery of a many-body supersymmetry (SUSY) in the phonon problem of balls and springs and its connection to local constraints satisfied by ground states. The Witten index of the SUSY model demands the Maxwell-Calladine index of mechanical structures. "Spontaneous supersymmetry breaking" is identified as the need to gap all modes in the bulk to create the topological isostatic lattice state. Since ground states of magnetic systems also satisfy local constraint conditions (such as the vanishing of the total spin on a triangle), I identify a similar SUSY structure for many common models of antiferromagnets including the square, triangluar, kagome, pyrochlore nearest-neighbor antiferromagnets, and the J2=J1/2 square-lattice antiferromagnet. Remarkably, the kagome family of antiferromagnets is the analog of topological isostatic lattices among this collection of models. Thus, a solid-state realization of the theory of phonon topological band structure may be found in frustrated magnetic materials.

  15. Chiral spin liquid in a frustrated anisotropic kagome Heisenberg model.

    Science.gov (United States)

    He, Yin-Chen; Sheng, D N; Chen, Yan

    2014-04-04

    Kalmeyer-Laughlin (KL) chiral spin liquid (CSL) is a type of quantum spin liquid without time-reversal symmetry, and it is considered as the parent state of an exotic type of superconductor--anyon superconductor. Such an exotic state has been sought for more than twenty years; however, it remains unclear whether it can exist in a realistic system where time-reversal symmetry is breaking (T breaking) spontaneously. By using the density matrix renormalization group, we show that KL CSL exists in a frustrated anisotropic kagome Heisenberg model, which has spontaneous T breaking. We find that our model has two topological degenerate ground states, which exhibit nonvanishing scalar chirality order and are protected by finite excitation gap. Furthermore, we identify this state as KL CSL by the characteristic edge conformal field theory from the entanglement spectrum and the quasiparticles braiding statistics extracted from the modular matrix. We also study how this CSL phase evolves as the system approaches the nearest-neighbor kagome Heisenberg model.

  16. Superfluidity of bosons in kagome lattices with frustration.

    Science.gov (United States)

    You, Yi-Zhuang; Chen, Zhu; Sun, Xiao-Qi; Zhai, Hui

    2012-12-28

    In this Letter we consider spinless bosons in a kagome lattice with nearest-neighbor hopping and on-site interaction, and the sign of hopping is inverted by insetting a π flux in each triangle of the kagome lattice so that the lowest single particle band is perfectly flat. We show that in the high-density limit, despite the infinite degeneracy of the single particle ground states, interaction will select out the Bloch state at the K point of the Brillouin zone for boson condensation at the lowest temperature. As the temperature increases, the single-boson superfluid order can be easily destroyed, while an exotic triple-boson paired superfluid order will remain. We establish that this trion superfluid exists in a broad temperature regime until the temperature is increased to the same order of hopping and then the system turns into normal phases. Finally, we show that time-of-flight measurement of the momentum distribution and its noise correlation can be used to distinguish these three phases.

  17. Topological thermal Hall effect in frustrated kagome antiferromagnets

    Science.gov (United States)

    Owerre, S. A.

    2017-01-01

    In frustrated magnets the Dzyaloshinsky-Moriya interaction (DMI) arising from spin-orbit coupling can induce a magnetic long-range order. Here, we report a theoretical prediction of the thermal Hall effect in frustrated kagome magnets such as KCr3(OH) 6(SO4) 2 and KFe3(OH) 6(SO4)2 . The thermal Hall effects in these materials are induced by scalar spin chirality as opposed to DMI in previous studies. The scalar spin chirality originates from the magnetic-field-induced chiral spin configuration due to noncoplanar spin textures, but in general it can be spontaneously developed as a macroscopic order parameter in chiral quantum spin liquids. Therefore, we infer that there is a possibility of the thermal Hall effect in frustrated kagome magnets such as herbertsmithite ZnCu3(OH) 6Cl2 and the chromium compound Ca10Cr7O28 , although they also show evidence of magnetic long-range order in the presence of applied magnetic field or pressure.

  18. Topological Phases of Interacting Bosons on the Kagome Lattice

    Science.gov (United States)

    Roychowdhury, Krishanu; Bhattacharjee, Subhro; Pollmann, Frank

    2015-03-01

    We consider an extended Hubbard model of hard core bosons including nearest-neighbour hopping and long range repulsive interactions on a kagome lattice. The system is an insulator at commensurate fillings of 1/6, 1/3 and 1/2 and can be mapped to different dimer models on the triangular lattice (depending on the filling). We focus on the filling of 1/3, which transforms to a fully packed loop (FPL) model, and derive the full phase diagram in the low-energy subspace. Similar to the quantum dimer model and easy-axis kagome antiferromagnetic model studied before, we find an extended region of a gapped Z2 liquid with vison excitations. The gauge fluctuations, responsible for the vison modes, are dictated by the action of an even Ising gauge theory. In the ordered phase, where the vison gap closes, we observe a 3-fold rotationally symmetric loop ordering and present the critical theory for the amplitude fluctuations of the condensed modes. We also speculate the phase diagram for the fermionic counterpart of the model at all the above mentioned fractional fillings.

  19. Guiding properties of kagome-lattice hollow-core fibers

    Science.gov (United States)

    Coscelli, E.; Poli, F.; Passaro, D.; Cucinotta, A.; Selleri, S.

    2010-04-01

    Photonic crystal fibers with kagome lattice are a particular kind of micostructured hollow-core fibers whose cross-section is characterized by a web of thin silica struts intersecting in a Star-of-David pattern. Such fibers show unusual properties, such as light confinement in the air-core in absence of a full photonic bandgap. The primary design parameter for such fibers is the strut thickness, which is responsible for the position and the width of the transmission bands. In this paper the guiding properties of hollow-core photonic crystal fibers with kagome lattice are investigated by means of a full-vector modal solver based on the finite element method. The fundamental mode effective index and confinement loss have been evaluated in a wide wavelength range, spanning from 300 nm to 1600 nm, accounting for the influence of the silica strut width on the transmission window. Moreover, the effects of selective alteration of the width and the shape of the silica struts surrounding the core have been analyzed. Simulation results show that the core-surrounding silica ring has the strongest effect on the transmission band, the loss level and the resonance wavelength position and, consequently, it should be carefully controlled during the fiber fabrication.

  20. Coherent potential approximation of random nearly isostatic kagome lattice.

    Science.gov (United States)

    Mao, Xiaoming; Lubensky, T C

    2011-01-01

    The kagome lattice has coordination number 4, and it is mechanically isostatic when nearest-neighbor sites are connected by central-force springs. A lattice of N sites has O(√N) zero-frequency floppy modes that convert to finite-frequency anomalous modes when next-nearest-neighbor (NNN) springs are added. We use the coherent potential approximation to study the mode structure and mechanical properties of the kagome lattice in which NNN springs with spring constant κ are added with probability P=Δz/4, where Δz=z-4 and z is the average coordination number. The effective medium static NNN spring constant κ(m) scales as P(2) for P≪κ and as P for P≫κ, yielding a frequency scale ω*~Δz and a length scale l*~(Δz)(-1). To a very good approximation at small nonzero frequency, κ(m)(P,ω)/κ(m)(P,0) is a scaling function of ω/ω*. The Ioffe-Regel limit beyond which plane-wave states become ill-defined is reached at a frequency of order ω*.

  1. Directed self-assembly of a colloidal kagome lattice.

    Science.gov (United States)

    Chen, Qian; Bae, Sung Chul; Granick, Steve

    2011-01-20

    A challenging goal in materials chemistry and physics is spontaneously to form intended superstructures from designed building blocks. In fields such as crystal engineering and the design of porous materials, this typically involves building blocks of organic molecules, sometimes operating together with metallic ions or clusters. The translation of such ideas to nanoparticles and colloidal-sized building blocks would potentially open doors to new materials and new properties, but the pathways to achieve this goal are still undetermined. Here we show how colloidal spheres can be induced to self-assemble into a complex predetermined colloidal crystal-in this case a colloidal kagome lattice-through decoration of their surfaces with a simple pattern of hydrophobic domains. The building blocks are simple micrometre-sized spheres with interactions (electrostatic repulsion in the middle, hydrophobic attraction at the poles, which we call 'triblock Janus') that are also simple, but the self-assembly of the spheres into an open kagome structure contrasts with previously known close-packed periodic arrangements of spheres. This open network is of interest for several theoretical reasons. With a view to possible enhanced functionality, the resulting lattice structure possesses two families of pores, one that is hydrophobic on the rims of the pores and another that is hydrophilic. This strategy of 'convergent' self-assembly from easily fabricated colloidal building blocks encodes the target supracolloidal architecture, not in localized attractive spots but instead in large redundantly attractive regions, and can be extended to form other supracolloidal networks.

  2. Fluorescence anisotropy excitation by polarization-shaped laser pulses after transmission through a kagome fiber

    Science.gov (United States)

    Otto, J.; Patas, A.; Althoff, J.; Lindinger, A.

    2016-08-01

    We report improved fluorescence contrast between dyes by two-photon excitation with polarization-shaped laser pulses after transmission through a kagome fiber utilizing the anisotropy of the dye molecules. Particularly phase- and polarization-tailored pulse shapes are employed for two-photon excited fluorescence of dyes in a liquid environment at the distal end of the kagome fiber. The distortions due to the optical fiber properties are precompensated in order to receive predefined polarization-shaped laser pulses after the kagome fiber. This enables to optimally excite one dye in one polarization direction and simultaneously the other dye in the other polarization direction. The presented method has a high potential for endoscopic applications due to the unique properties of kagome fibers for guiding ultrashort laser pulses.

  3. μ SR insight into the impurity problem in quantum kagome antiferromagnets

    Science.gov (United States)

    Gomilšek, M.; Klanjšek, M.; Pregelj, M.; Luetkens, H.; Li, Y.; Zhang, Q. M.; Zorko, A.

    2016-07-01

    Impurities, which are unavoidable in real materials, may play an important role in the magnetism of frustrated spin systems with a spin-liquid ground state. We address the impurity issue in quantum kagome antiferromagnets by investigating ZnCu3(OH) 6SO4 (Zn-brochantite) by means of muon spin spectroscopy. We show that muons dominantly couple to impurities, originating from Cu-Zn intersite disorder, and that the impurity spins are highly correlated with the kagome spins, allowing us to probe the host kagome physics via a Kondo-like effect. The low-temperature plateau in the impurity susceptibility suggests that the kagome spin-liquid ground state is gapless. The corresponding spin fluctuations exhibit an unconventional spectral density and a nontrivial field dependence.

  4. A test resonator for Kagome Hollow-core Photonic Crystal Fibers for resonant rotation sensing

    Science.gov (United States)

    Fsaifes, Ihsan; Feugnet, Gilles; Ravaille, Alexia; Debord, Benoït; Gérôme, Frédéric; Baz, Assaad; Humbert, Georges; Benabid, Fetah; Schwartz, Sylvain; Bretenaker, Fabien

    2017-01-01

    We build ring resonators to assess the potentialities of Kagome Hollow-Core Photonic Crystal Fibers for future applications to resonant rotation sensing. The large mode diameter of Kagome fibers permits to reduce the free space fiber-to-fiber coupling losses, leading to cavities with finesses of about 30 for a diameter equal to 15 cm. Resonance linewidths of 3.2 MHz with contrasts as large as 89% are obtained. Comparison with 7-cell photonic band gap (PBG) fiber leads to better finesse and contrast with Kagome fiber. Resonators based on such fibers are compatible with the angular random walk required for medium to high performance rotation sensing. The small amount of light propagating in silica should also permit to further reduce the Kerr-induced non-reciprocity by at least three orders of magnitudes in 7-cell Kagome fiber compared with 7-cell PBG fiber.

  5. Vibration band-gap properties of three-dimensional Kagome lattices using the spectral element method

    Science.gov (United States)

    Wu, Zhi-Jing; Li, Feng-Ming; Zhang, Chuanzeng

    2015-04-01

    The spectral element method (SEM) is extended to investigate the vibration band-gap properties of three-dimensional (3D) Kagome lattices. The dynamic stiffness matrix of the 3D element which contains bending, tensional and torsional components is derived. The spectral equations of motion of the whole 3D Kagome lattice are then established. Comparing with frequency-domain solutions calculated by the finite element method (FEM), the accuracy and the feasibility of the SEM solutions are verified. It can be shown that the SEM is suitable for analyzing the vibration band-gap properties. Due to the band-gap characteristics, the periodic 3D Kagome lattice has the performance of vibration isolation. The influences of the structural and material parameters on the vibration band-gaps are discussed and a new type of 3D Kagome lattice is designed to obtain the improved vibration isolation capability.

  6. Modified kagome physics in the natural spin-1/2 kagome lattice systems - kapellasite Cu3Zn(OH)6Cl2 and haydeeite Cu3Mg(OH)6Cl2

    OpenAIRE

    Janson, O.; Richter, J.; Rosner, H

    2008-01-01

    The recently discovered natural minerals Cu3Zn(OH)6Cl2 and Cu3Mg(OH)6Cl2 are spin 1/2 systems with an ideal kagome geometry. Based on electronic structure calculations, we develop a realistic model which includes couplings across the kagome hexagons beyond the original kagome model that are intrinsic in real kagome materials. Exact diagonalization studies for the derived model reveal a strong impact of these couplings on the magnetic ground state. Our predictions could be compared to and supp...

  7. Modified kagome physics in the natural spin-1/2 kagome lattice systems: kapellasite Cu3Zn(OH)6Cl2 and haydeeite Cu3Mg(OH)6Cl2.

    Science.gov (United States)

    Janson, O; Richter, J; Rosner, H

    2008-09-05

    The recently discovered natural minerals Cu3Zn(OH)6Cl2 and Cu3Mg(OH)6Cl2 are spin 1/2 systems with an ideal kagome geometry. Based on electronic structure calculations, we develop a realistic model which includes couplings across the kagome hexagons beyond the original kagome model that are intrinsic in real kagome materials. Exact diagonalization studies for the derived model reveal a strong impact of these couplings on the magnetic ground state. Our predictions could be compared to and supplied with neutron scattering, thermodynamic data, and NMR data.

  8. Finite-temperature transition of the antiferromagnetic Heisenberg model on a distorted kagome lattice.

    Science.gov (United States)

    Masuda, Hiroshi; Okubo, Tsuyoshi; Kawamura, Hikaru

    2012-08-03

    Motivated by the recent experiment on kagome-lattice antiferromagnets, we study the zero-field ordering behavior of the antiferromagnetic classical Heisenberg model on a uniaxially distorted kagome lattice by Monte Carlo simulations. A first-order transition, which has no counterpart in the corresponding undistorted model, takes place at a very low temperature. The origin of the transition is ascribed to a cooperative proliferation of topological excitations inherent to the model.

  9. Extremely Low Loss THz Guidance Using Kagome Lattice Porous Core Photonic Crystal Fiber

    DEFF Research Database (Denmark)

    Hossain, Anwar; Hasanuzzaman, G.K.M.; Habib, Selim;

    2015-01-01

    A novel porous core Kagome lattice photonic crystal fiber is proposed for extremely low loss THz waves guiding. It has been reported that 82.5% of bulk effective material loss of Topas can be reduced......A novel porous core Kagome lattice photonic crystal fiber is proposed for extremely low loss THz waves guiding. It has been reported that 82.5% of bulk effective material loss of Topas can be reduced...

  10. Models for guidance in kagome-structured hollow-core photonic crystal fibres.

    Science.gov (United States)

    Pearce, G J; Wiederhecker, G S; Poulton, C G; Burger, S; St J Russell, P

    2007-10-01

    We demonstrate by numerical simulation that the general features of the loss spectrum of photonic crystal fibres (PCF) with a kagome structure can be explained by simple models consisting of thin concentric hexagons or rings of glass in air. These easily analysed models provide increased understanding of the mechanism of guidance in kagome PCF, and suggest ways in which the high-loss resonances in the loss spectrum may be shifted.

  11. Selectivity Enhancement by Using Double-Layer MOX-Based Gas Sensors Prepared by Flame Spray Pyrolysis (FSP

    Directory of Open Access Journals (Sweden)

    Julia Rebholz

    2016-09-01

    Full Text Available Here we present a novel concept for the selective recognition of different target gases with a multilayer semiconducting metal oxide (SMOX-based sensor device. Direct current (DC electrical resistance measurements were performed during exposure to CO and ethanol as single gases and mixtures of highly porous metal oxide double- and single-layer sensors obtained by flame spray pyrolysis. The results show that the calculated resistance ratios of the single- and double-layer sensors are a good indicator for the presence of specific gases in the atmosphere, and can constitute some building blocks for the development of chemical logic devices. Due to the inherent lack of selectivity of SMOX-based gas sensors, such devices could be especially relevant for domestic applications.

  12. Selectivity Enhancement by Using Double-Layer MOX-Based Gas Sensors Prepared by Flame Spray Pyrolysis (FSP).

    Science.gov (United States)

    Rebholz, Julia; Grossmann, Katharina; Pham, David; Pokhrel, Suman; Mädler, Lutz; Weimar, Udo; Barsan, Nicolae

    2016-09-06

    Here we present a novel concept for the selective recognition of different target gases with a multilayer semiconducting metal oxide (SMOX)-based sensor device. Direct current (DC) electrical resistance measurements were performed during exposure to CO and ethanol as single gases and mixtures of highly porous metal oxide double- and single-layer sensors obtained by flame spray pyrolysis. The results show that the calculated resistance ratios of the single- and double-layer sensors are a good indicator for the presence of specific gases in the atmosphere, and can constitute some building blocks for the development of chemical logic devices. Due to the inherent lack of selectivity of SMOX-based gas sensors, such devices could be especially relevant for domestic applications.

  13. Surface Broken Symmetry on Orthorhombic Double-layer Sr3(Ru1-xMnx)2 O7

    Science.gov (United States)

    Chen, Chen; Nascimento, V. B.; Diao, Zhenyu; Zhang, Jiandi; Jin, Rongying; Plummer, E. W.

    The surface of double-layered ruthenate Sr3Ru2O7 exhibits octahedra tilt distortion and an enhanced rotational distortion caused by the broken symmetry. Previous LEED IV calculation reveals that the tilt angle is (2.5+/-1.7)°at 80 K (B. Hu et. al., Physical Review B 81, 184104 (2010). A glideline symmetry and a mirror symmetry along this direction are both broken. Results from LEED IV simulations show that both broken symmetries originate from the emergence of surface tilt. The degree of broken symmetry is more sensitive to the tilt angle, thus producing a smaller error than from conventional LEED IV calculation. When Mn doping is induced into the compound, the tilt is removed and the symmetry of the LEED pattern returns to what is expected for rotation, two glide planes and four-fold symmetry. Supported by NSF DMR-1002622.

  14. Quantum Disordered State without Frustration in the Double Layer Heisenberg Antiferromagnet —Dimer Expansion and Projector Monte Carlo Study—

    Science.gov (United States)

    Hida, Kazuo

    1992-03-01

    The quantum disordered state (QDOS) of the spin 1/2 double layer square lattice Heisenberg antiferromagnet is studied. Using the dimer expansion from the limit of the large interlayer coupling J', the staggered susceptibility χ, the antiferromagnetic structure factor Sπ and the antiferromagnetic correlation length ξ are calculated up to the 6-th order in the intralayer coupling J. The ratio analysis shows that the QDOS becomes unstable against the Néel ordering at J'/J≃2.56. The critical exponents are not inconsistent with the universality class of the 3-dimensional classical Heisenberg model, suggesting that our QDOS corresponds to that expected in the 2-dimensional square lattice Heisenberg antiferromagnet with unphysically small spin (<0.276). The results of the projector Monte Carlo simulation also confirms the dimer expansion results.

  15. Effect of UV-light illumination on oxide-based electric-double-layer thin-film transistors

    Science.gov (United States)

    Zhou, Jumei; Hu, Yunping

    2017-01-01

    Indium–tin-oxide (ITO)-based thin-film transistors (TFTs) were fabricated using porous SiO2 deposited by plasma-enhanced chemical vapor deposition and Al2O3 deposited by atomic layer deposition as dielectrics. The results showed that the porous SiO2 film exhibited a high electric-double-layer (EDL) capacitance. Devices gated by the EDL dielectric exhibited a high drain current on/off ratio of >106 and a low operation voltage of illuminated by 254 nm UV light, ITO-based EDL TFTs gated by a single SiO2 dielectric displayed weak photo-responses. However, devices gated by a stacked Al2O3/EDL dielectric displayed a high photo responsivity of more than 104 with a gate bias of ‑0.5 V (depletion state).

  16. Preparation and characterization of double layer thin films ZnO/ZnO:Ag for methylene blue photodegradation

    Energy Technology Data Exchange (ETDEWEB)

    Wibowo, Singgih, E-mail: singgih@st.fisika.undip.ac.id; Sutanto, Heri, E-mail: herisutanto@undip.ac.id [Department of Physics, Faculty of Science and Mathematics, Diponegoro University (Indonesia)

    2016-02-08

    Double layer (DL) thin films of zinc oxide and silver-doped zinc oxide (ZnO/ZnO:Ag) were deposited on glass substrate by sol-gel spray coating technique. The prepared thin films were subjected for optical and photocatalytic studies. UV-visible transmission spectra shows that the subtitution of Ag in ZnO leads to band gap reduction. The influence of Ag doping on the photocatalytic activity of ZnO for the degradation of methylene blue dye was studied under solar radiation. The light absorption over an extended visible region by Ag ion doping in ZnO film contributed equally to improve the photocatalytic activity up to 98.29%.

  17. Preparation and characterization of double layer thin films ZnO/ZnO:Ag for methylene blue photodegradation

    Science.gov (United States)

    Wibowo, Singgih; Sutanto, Heri

    2016-02-01

    Double layer (DL) thin films of zinc oxide and silver-doped zinc oxide (ZnO/ZnO:Ag) were deposited on glass substrate by sol-gel spray coating technique. The prepared thin films were subjected for optical and photocatalytic studies. UV-visible transmission spectra shows that the subtitution of Ag in ZnO leads to band gap reduction. The influence of Ag doping on the photocatalytic activity of ZnO for the degradation of methylene blue dye was studied under solar radiation. The light absorption over an extended visible region by Ag ion doping in ZnO film contributed equally to improve the photocatalytic activity up to 98.29%.

  18. Task-oriented design of a fully pre-stressed double-layer six-component force/torque sensor

    Science.gov (United States)

    Wang, Hang; Hou, Yulei; Yao, Jiantao; Wang, Zhijun; Zhao, Yongsheng

    2010-08-01

    This paper presents a method to study and design a fully pre-stressed double-layer six-component force/torque sensor. The structure characteristic of the fully pre-stressed sensor is analyzed. In order to achieve the best performance, the static mathematical model is built by using screw theory. Based on the task ellipsoid, the task model of the pre-stressed force sensor is built. The relationship between the sensor and the task is studied systematically. And the mathematic description of task-oriented performance evaluation of the fully pre-stressed sensor is proposed. The key parameters of the fully pre-stressed force sensor satisfying the purpose of the task are obtained. The research results of this paper are useful for the further research and practical application of the six-component force sensor.

  19. A 4 Farad high energy electrochemical double layer capacitor prototype operating at 3.2 V (IES prototype)

    Science.gov (United States)

    Varzi, A.; Schütter, C.; Krummacher, J.; Raccichini, R.; Wolff, C.; Kim, G.-T.; Rösler, S.; Blumenröder, B.; Schubert, T.; Passerini, S.; Balducci, A.

    2016-09-01

    In this manuscript we report about the realization and testing of a high-voltage electrochemical double layer capacitor (EDLC) prototype (IES prototype), which has been assembled using innovative electrode and electrolyte components. The IES prototype displays a nominal capacitance of 4 F, a maximum voltage of 3.2 V and its maximal energy and power are in the order of 37 Wh kg-1 and 65 kW kg-1, respectively. Furthermore, it also displays good cycling stability, high capacitance retention after 80 h float test and acceptable self-discharge. Taking into account substantial improvements of the cell design and assembly procedure, the performance of the IES prototype indicates that the components utilized in this device might be suitable alternatives to the state-of-the-art materials used in high energy EDLCs.

  20. Analysis of transmitting characteristics of high-transparency double-layer metallic meshes with submillimeter period using an analytical model.

    Science.gov (United States)

    Lu, Zhengang; Tan, Jiubin

    2008-10-10

    The transmitting characteristics of high-transparency double-layer metallic meshes with submillimeter period were analyzed using an analytical model, which was established using angular spectrum propagation theory and verified through experiments. It was found through analysis that rotating misalignment has significant effect on the distribution of diffraction spot intensity. Large period and small linewidth can be used to obtain high transmittance and low levels of stray light. Substrate thickness has little effect on transmitting characteristics of mesh, and so it is a variable free to choose in optimizing shielding characteristics of mesh. We think, together with other ways and means of optimizing shielding characteristics of mesh, the model can also be used for the optimization of a high-pass mesh filter.

  1. Optimization of SiNx Single and Double Layer ARC for Silicon Thin Film Solar Cells on Glass

    Directory of Open Access Journals (Sweden)

    M. Beye

    2013-06-01

    Full Text Available The aim of this study is the optimization of the antireflection effect of SiN in silicon on glass based structure. A numerical calculation is performed and a SiNx double stack antireflection coating is found to have significant advantages over single-layer due to their broad-range coverage of the solar spectrum. Moreover, it was found that minimum reflection losses is obtained for SiN/SiN double-layer ARC with refractive indexes of 1.9 et 2.3 for the top and the bottom layer, respectively. The effect of the incident angle on reflectance is also studied. The numerical optimization procedure and its results are presented.

  2. Enhancing the capacitances of electric double layer capacitors based on carbon nanotube electrodes by carbon dioxide activation and acid oxidization

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    Polarizable electrodes of electric double layer capacitors(EDLCs) were made from carbon nanotubes(CNTs).Effect of carbon dioxide activation together with acid oxidation for the electrodes on the characteristics and performances of electrodes and EDLCs was studied.Carbon dioxide activation changed the microstructure of the electrodes,increased the effective surface area of CNTs and optimized the distribution of apertures of the electrodes.Acid oxidization modified the surface characteristics of CNTs.Based on the polarizable electrodes treated by carbon dioxide activation and acid oxidization,the performances of EDLCs were greatly enhanced.The specific capacitance of the electrodes with organic electrolyte was increased from 21.8 F/g to 60.4 F/g.

  3. Exploring new scaling regimes for streaming potential and electroviscous effects in a nanocapillary with overlapping electric double layers.

    Science.gov (United States)

    Das, Siddhartha; Guha, Arnab; Mitra, Sushanta K

    2013-12-04

    In this paper, we unravel new scaling regimes for streaming potential and electroviscous effects in a nanocapillary with thick overlapping Electric Double Layers (EDLs). We observe that the streaming potential, for a given value of the capillary zeta (ζ) potential, varies with the EDL thickness and a dimensionless parameter R, quantifying the conduction current. Depending on the value of R, variation of the streaming potential with the EDL thickness demonstrates distinct scaling regimes: one can witness a Quadratic Regime where the streaming potential varies as the square of the EDL thickness, a Weak Regime where the streaming potential shows a weaker variation with the EDL thickness, and a Saturation Regime where the streaming potential ceases to vary with the EDL thickness. Effective viscosity, characterizing the electroviscous effect, obeys the variation of the streaming potential for smaller EDL thickness values; however, for larger EDL thickness the electroosmotic flow profile dictates the electroviscous effect, with insignificant contribution of the streaming potential.

  4. Preparation of polyurea/melamine formaldehyde double-layered self-healing microcapsules and investigation on core fraction.

    Science.gov (United States)

    Ming, Yaoqiang; Hu, Jianfeng; Xing, Junheng; Wu, Minghua; Qu, Jinqing

    2016-06-01

    Moisture curing type self-healing microcapsules become more attractive, while instability of active core material crippled the efficiency of self-healing behaviour. Polyurea (PU)/melamine formaldehyde (MF) double-layered self-healing microcapsules containing isophorone diisocyanate (IPDI) core with high and stable core fraction were prepared. The structure, morphology, particle size and distribution were studied with Fourier transform infra-red spectroscopy, optical microscopy, scanning electron microscopy and Mastersizer 3000. The influences of process conditions were investigated to uncover the principle of core fraction and morphology of microcapsules. The core fraction of microcapsules was reduced with the increase of ageing time, and microcapsules prepared with ice-bath, polyetheramine (PEA) and prepolymer of melamine formaldehyde (P-MF) had higher core fraction and better morphology. PEA D230 and 1500 rpm agitation rate were chosen according to optimised trade-offs in the core fraction and morphology of the microcapsules.

  5. Al-Si alloy point contact formation and rear surface passivation for silicon solar cells using double layer porous silicon

    Science.gov (United States)

    Moumni, Besma; Ben Jaballah, Abdelkader; Bessais, Brahim

    2012-10-01

    Lowering the rear surface recombination velocities by a dielectric layer has fascinating advantages compared with the standard fully covered Al back-contact silicon solar cells. In this work the passivation effect by double layer porous silicon (PS) (wide band gap) and the formation of Al-Si alloy in narrow p-type Si point contact areas for rear passivated solar cells are analysed. As revealed by Fourier transform infrared spectroscopy, we found that a thin passivating aluminum oxide (Al2O3) layer is formed. Scanning electron microscopy analysis performed in cross sections shows that with bilayer PS, liquid Al penetrates into the openings, alloying with the Si substrate at depth and decreasing the contact resistivity. At the solar cell level, the reduction in the contact area and resistivity leads to a minimization of the fill factor losses.

  6. Double-layered reconstruction of the nasal floor in complete cleft deformity of the primary palate using superfluous lip tissue.

    Science.gov (United States)

    Park, Young-Wook; Kwon, Kwang-Jun; Kim, Min-Keun

    2015-12-01

    After cleft lip repair, many patients suffer from nasolabial fistulas, asymmetrical nasal floor, or an indistinct nostril sill, as well as intraoral wound dehiscence and subsequent scar contracture of surgical wounds leading to vestibular stenosis. For successful primary nasolabial repair of complete cleft deformity of the primary palate, cleft surgeons need special care in reconstructing the sound nasal floor. Especially when the cleft gap is wide or when any type of nasoalveolar molding therapy was not performed, three-dimensional reconstruction of the nasal floor is critical for a balanced nasal shape. In this study, the author describes an effective method for reconstructing a double-layered nasal floor using two mucosal flaps from both sides of the fissured upper lip. This is a report of six patients with unilateral or bilateral complete cleft of the primary palate with a detailed description of the surgical technique and a literature review.

  7. Effects of electrolytic composition on the electric double-layer capacitance at smooth-surface carbon electrodes in organic media

    Energy Technology Data Exchange (ETDEWEB)

    Kim, In-Tae; Egashira, Minato; Yoshimoto, Nobuko [Graduate School of Science and Engineering, Yamaguchi University, 2-16-1, Tokiwadai, Ube, 755-8611 (Japan); Morita, Masayuki, E-mail: morita@yamaguchi-u.ac.j [Graduate School of Science and Engineering, Yamaguchi University, 2-16-1, Tokiwadai, Ube, 755-8611 (Japan)

    2010-09-01

    As a fundamental research on the optimization of electrolyte composition in practical electrochemical capacitor device, double-layer capacitance at Glassy Carbon (GC) and Boron-doped Diamond (BDD), as typical smooth-surface carbon electrodes, has been studied as a function of the electrolyte composition in organic media. Specific capacitance (differential capacitance: F cm{sup -2}) determined by an AC impedance method, in which no contribution of mass-transport effects is included, corresponded well to integrated capacitance evaluated by conventional cyclic voltammetry. The specific capacitance at the GC electrode varied with polarized potential and showed clear PZC (potential of zero charge), while the potential dependence of the capacitance at BDD was very small. The effects of the solvent and the electrolytic salt on the capacitance behavior were common for both electrodes. That is, the sizes of the solvent molecule and the electrolytic ion (cation) strongly affected the capacitance at these smooth-surface carbon electrodes.

  8. Effect of Strong Acid Functional Groups on Electrode Rise Potential in Capacitive Mixing by Double Layer Expansion

    KAUST Repository

    Hatzell, Marta C.

    2014-12-02

    © 2014 American Chemical Society. The amount of salinity-gradient energy that can be obtained through capacitive mixing based on double layer expansion depends on the extent the electric double layer (EDL) is altered in a low salt concentration (LC) electrolyte (e.g., river water). We show that the electrode-rise potential, which is a measure of the EDL perturbation process, was significantly (P = 10-5) correlated to the concentration of strong acid surface functional groups using five types of activated carbon. Electrodes with the lowest concentration of strong acids (0.05 mmol g-1) had a positive rise potential of 59 ± 4 mV in the LC solution, whereas the carbon with the highest concentration (0.36 mmol g-1) had a negative rise potential (-31 ± 5 mV). Chemical oxidation of a carbon (YP50) using nitric acid decreased the electrode rise potential from 46 ± 2 mV (unaltered) to -6 ± 0.5 mV (oxidized), producing a whole cell potential (53 ± 1.7 mV) that was 4.4 times larger than that obtained with identical electrode materials (from 12 ± 1 mV). Changes in the EDL were linked to the behavior of specific ions in a LC solution using molecular dynamics and metadynamics simulations. The EDL expanded in the LC solution when a carbon surface (pristine graphene) lacked strong acid functional groups, producing a positive-rise potential at the electrode. In contrast, the EDL was compressed for an oxidized surface (graphene oxide), producing a negative-rise electrode potential. These results established the linkage between rise potentials and specific surface functional groups (strong acids) and demonstrated on a molecular scale changes in the EDL using oxidized or pristine carbons.

  9. The fabrication of double layer tubular vascular tissue engineering scaffold via coaxial electrospinning and its 3D cell coculture.

    Science.gov (United States)

    Ye, Lin; Cao, Jie; Chen, Lamei; Geng, Xue; Zhang, Ai-Ying; Guo, Lian-Rui; Gu, Yong-Quan; Feng, Zeng-Guo

    2015-12-01

    A continuous electrospinning technique was applied to fabricate double layer tubular tissue engineering vascular graft (TEVG) scaffold. The luminal layer was made from poly(ɛ-caprolac-tone)(PCL) ultrafine fibers via common single axial electrospinning followed by the outer layer of core-shell structured nanofibers via coaxial electrospinning. For preparing the outer layernano-fibers, the PCL was electrospun into the shell and both bovine serum albumin (BSA) and tetrapeptide val-gal-pro-gly (VAPG) were encapsulated into the core. The core-shell structure in the outer layer fibers was observed by transmission electron microscope (TEM). The in vitro release tests exhibited the sustainable release behavior of BSA and VAPG so that they provided a better cell growth environment in the interior of tubular scaffold wall. The in vitro culture of smooth muscle cells (SMCs) demonstrated their potential to penetrate into the scaffold wall for the 3D cell culture. Subsequently, 3D cell coculture was conducted. First, SMCs were seeded on the luminal surface of the scaffold and cultured for 5 days, and then endothelial cells (ECs) were also seeded on the luminal surface and cocultured with SMCs for another 2 days. After stained with antibodies, 3D cell distribution on the scaffold was revealed by confocal laser scanning microscopy (CLSM) where ECs were mainly located on the luminal surface whereas SMCs penetrated into the surface and distributed inside the scaffold wall. This double layer tubular scaffold with 3D cell distribution showed the promise to develop it into a novel TEVG for clinical trials in the near future.

  10. A novel double-layer molecularly imprinted polymer film based surface plasmon resonance for determination of testosterone in aqueous media

    Energy Technology Data Exchange (ETDEWEB)

    Tan, Yuan; Jing, Lijing; Ding, Yonghong; Wei, Tianxin, E-mail: txwei@bit.edu.cn

    2015-07-01

    Highlights: • The in-situ photo-grafting polymerization method was used to prepare the polymer film. • The synthesized MIF was layer stucture film. • The MIF exhibited good imprinting effect and highly selectivity. - Abstract: This work aimed to prepare a novel double-layer structure molecularly imprinted polymer film (MIF) on the surface plasmon resonance (SPR) sensor chips for detection of testosterone in aqueous media. The film was synthesized by in-situ UV photo polymerization. Firstly, the modification of gold surface of SPR chip was performed by 1-dodecanethiol. Then double-layer MIF was generated on the 1-dodecanethiol modified gold surface. The non-modified and imprinted surfaces were characterized by atomic force microscopy (AFM), fourier transform infrared (FTIR) spectroscopy and contact angle measurements. Analysis of SPR spectroscopy showed that the imprinted sensing film displayed good selectivity for testosterone compared to other analogues and the non-imprinted polymer film (NIF). Within the concentrations range of 1 × 10{sup −12}–1 × 10{sup −8} mol/L, the coupling angle changes of SPR were linear with the negative logarithm of testosterone concentrations (R{sup 2} = 0.993). Based on a signal/noise ratio of three, the detection limit was estimated to be 10{sup −12} mol/L. Finally, the developed MIF was successfully applied to the seawater detection of testosterone. The results in the experiments suggested that a combination of SPR sensing with MIF was a promising alternative method for detection of testosterone in aqueous media.

  11. Study of Electrical Conduction Mechanism of Organic Double-Layer Diode Using Electric Field Induced Optical Second Harmonic Generation Measurement.

    Science.gov (United States)

    Nishi, Shohei; Taguchi, Dai; Manaka, Takaaki; Iwamoto, Mitsumasa

    2016-04-01

    By using electric field induced optical second harmonic generation (EFISHG) and current voltage (I-V) measurements, we studied the electrical transport mechanism of organic double-layer diodes with a structure of Au/N, N'-di-[(1-naphthyl)-N, N'-diphenyl]-(1,1'-biphenyl)-4,4'-diamine (a-NPD)/poly(methyl methacrylate) (PMMA)/indium zinc oxide (IZO). Here the α-NPD is a carrier transport layer and the PMMA is an electrical insulating layer. The current level was very low, but the I-V characteristics showed a rectifying behavior. The EFISHG measurement selectively and directly probed the electric field across the α-NPD layer, and showed that the electric field across the a-NPD layer is completely relaxed owing to the charge accumulation at the a-NPD/PMMA interface in the region V > 0, whereas the carrier accumulation was not significant in the region V < 0. On the basis of these experimental results, we proposed a model of the rectification. Further, by coupling the I-V characteristics with the EFISHG measurement, the I-V characteristics of the diodes were well converted into the current-electric field (I-E) characteristics of the α-NPD layer and the PMMA layer. The I-E characteristics suggested the Schottky-type conduction governs the carrier transport. We conclude that the I-V measurement coupled with the EFISHG measurement is very useful to study carrier transport mechanism of the organic double-layer diodes.

  12. Single versus double-layer uterine closure at cesarean: impact on lower uterine segment thickness at next pregnancy.

    Science.gov (United States)

    Vachon-Marceau, Chantale; Demers, Suzanne; Bujold, Emmanuel; Roberge, Stephanie; Gauthier, Robert J; Pasquier, Jean-Charles; Girard, Mario; Chaillet, Nils; Boulvain, Michel; Jastrow, Nicole

    2017-07-01

    Uterine rupture is a potential life-threatening complication during a trial of labor after cesarean delivery. Single-layer closure of the uterus at cesarean delivery has been associated with an increased risk of uterine rupture compared with double-layer closure. Lower uterine segment thickness measurement by ultrasound has been used to evaluate the quality of the uterine scar after cesarean delivery and is associated with the risk of uterine rupture. To estimate the impact of previous uterine closure on lower uterine segment thickness. Women with a previous single low-transverse cesarean delivery were recruited at 34-38 weeks' gestation. Transabdominal and transvaginal ultrasound evaluation of the lower uterine segment thickness was performed by a sonographer blinded to clinical data. Previous operative reports were reviewed to obtain the type of previous uterine closure. Third-trimester lower uterine segment thickness at the next pregnancy was compared according to the number of layers sutured and according to the type of thread for uterine closure, using weighted mean differences and multivariate logistic regression analyses. Of 1613 women recruited, with operative reports available, 495 (31%) had a single-layer and 1118 (69%) had a double-layer closure. The mean third-trimester lower uterine segment thickness was 3.3 ± 1.3 mm and the proportion with lower uterine segment thickness cesarean delivery is associated with a thicker third-trimester lower uterine segment and a reduced risk of lower uterine segment thickness <2.0 mm in the next pregnancy. The type of thread for uterine closure has no significant impact on lower uterine segment thickness. Copyright © 2017 Elsevier Inc. All rights reserved.

  13. A novel porous anionic metal–organic framework with pillared double-layer structure for selective adsorption of dyes

    Energy Technology Data Exchange (ETDEWEB)

    Sheng, Shu-Nan; Han, Yi; Wang, Bin; Zhao, Cui; Yang, Fan; Zhao, Min-Jian; Xie, Ya-Bo, E-mail: xieyabo@bjut.edu.cn; Li, Jian-Rong

    2016-01-15

    A novel porous anionic metal–organic framework, (Me{sub 2}NH{sub 2}){sub 2}[Zn{sub 2}L{sub 1.5}bpy]·2DMF (BUT-201; H{sub 4}L=4,8-disulfonaphthalene-2,6-dicarboxylic acid; bpy=4,4-bipyridine; DMF=N,N-dimethylformamide), with pillared double-layer structure has been synthesized through the reaction of a sulfonated carboxylic acid ligand and Zn(NO{sub 3}){sub 2}·6H{sub 2}O with 4,4-bipyridine as a co-ligand. It is found that BUT-201 can rapidly adsorb cationic dyes with a smaller size such as Methylene Blue (MB) and Acriflavine Hydrochloride (AH) by substitution of guest (CH{sub 3}){sub 2}NH{sub 2}{sup +}, but has no adsorption towards the cationic dyes with a lager size such as Methylene Violet (MV), the anionic dyes like C. I. Acid Yellow 1 (AY1) and neutral dyes like C. I. Solvent Yellow 7 (SY7), respectively. The results show that the adsorption behavior of BUT-201 relates not only to the charge but also to the size/shape of dyes. Furthermore, the adsorbed dyes can be gradually released in the methanol solution of LiNO{sub 3}. - Graphical abstract: A porous anionic metal–organic framework (BUT-201) can selectively adsorb the cationic dyes by cationic guest molecule substitution, and the adsorbed dyes can be gradually released in the methanol solution of LiNO{sub 3}. - Highlights: • An anionic metal-organic framework (BUT-201) has been synthesized and characterized. • BUT-201 has a three-dimensional (3D) pillared double-layer structure. • BUT-201 can selectively and rapidly adsorb cationic dyes. • The adsorbed dyes can be gradually released in the methanol solution of LiNO{sub 3}.

  14. Double layer electric fields aiding the production of energetic flat-top distributions and superthermal electrons within the exhausts from magnetic reconnection

    CERN Document Server

    Egedal, Jan; Le, Ari; Borg, Anette L

    2015-01-01

    Using a kinetic simulation of magnetic reconnection it was recently shown that magnetic-field-aligned electric fields (E||) can be present over large spatial scales in reconnection exhausts. The largest values of E|| are observed within double layers. The existence of double layers in the Earth's magnetosphere is well documented. In our simulation their formation is triggered by large parallel streaming of electrons into the reconnection region. These parallel electron fluxes are required for maintaining quasi-neutrality of the reconnection region and increase with decreasing values of the normalized electron pressure upstream of the reconnection region. A threshold normalized pressure is derived for strong double layers to develop. We also document how the electron confinement, provided in part by the structure in E||, allows sustained energization by perpendicular electric fields. The energization is a consequence of the confined electrons' chaotic orbital motion that includes drifts aligned with the reconn...

  15. Homogeneous double-layer amorphous Si-doped indium oxide thin-film transistors for control of turn-on voltage

    Science.gov (United States)

    Kizu, Takio; Aikawa, Shinya; Nabatame, Toshihide; Fujiwara, Akihiko; Ito, Kazuhiro; Takahashi, Makoto; Tsukagoshi, Kazuhito

    2016-07-01

    We fabricated homogeneous double-layer amorphous Si-doped indium oxide (ISO) thin-film transistors (TFTs) with an insulating ISO cap layer on top of a semiconducting ISO bottom channel layer. The homogeneously stacked ISO TFT exhibited high mobility (19.6 cm2/V s) and normally-off characteristics after annealing in air. It exhibited normally-off characteristics because the ISO insulator suppressed oxygen desorption, which suppressed the formation of oxygen vacancies (VO) in the semiconducting ISO. Furthermore, we investigated the recovery of the double-layer ISO TFT, after a large negative shift in turn-on voltage caused by hydrogen annealing, by treating it with annealing in ozone. The recovery in turn-on voltage indicates that the dense VO in the semiconducting ISO can be partially filled through the insulator ISO. Controlling molecule penetration in the homogeneous double layer is useful for adjusting the properties of TFTs in advanced oxide electronics.

  16. Patterning Graphitic C-N Sheets into a Kagome Lattice for Magnetic Materials.

    Science.gov (United States)

    Li, Xiaowei; Zhou, Jian; Wang, Qian; Kawazoe, Yushiyuki; Jena, Puru

    2013-01-17

    We propose porous C-N-based structures for biocompatible magnetic materials that do not contain even a single metal ion. Using first-principles calculations based on density functional theory, we show that when patterned in the form of a kagome lattice, nonmagnetic g-C3N4 not only becomes ferromagnetic but also its magnetic properties can be further enhanced by applying external strain. Similarly, the magnetic moment per atom in ferromagnetic g-C4N3 is increased three fold when patterned into a kagome lattice. The Curie temperature of g-C3N4 kagome lattice is 100 K, while that of g-C4N3 kagome lattice is much higher, namely, 520 K. To date, all of the synthesized two- and three-dimensional magnetic kagome structures contain metal ions and are toxic. The objective of our work is to stimulate an experimental effort to develop nanopatterning techniques for the synthesis of g-C3N4- and g-C4N3-based kagome lattices.

  17. Two-dimensional Kagome phosphorus and its edge magnetism: a density functional theory study.

    Science.gov (United States)

    Yu, Guodong; Jiang, Liwei; Zheng, Yisong

    2015-07-01

    By means of density functional theory calculations, we predict a new two-dimensional phosphorus allotrope with the Kagome-like lattice(Kagome-P). It is an indirect gap semiconductor with a band gap of 1.64 eV. The gap decreases sensitively with the compressive strain. In particular, shrinking the lattice beyond 13% can drive it into metallic state. In addition, both the AA and AB stacked Kagome-P multi-layer structures exhibit a bandgap much smaller than 1.64 eV. Edges in the Kagome-P monolayer probably suffer from the edge reconstruction. An isolated zigzag edge can induce antiferromagnetic (AF) ordering with a magnetic transition temperature of 23 K. More importantly, when applying a stretching strain beyond 4%, such an edge turns to possess a ferromagnetic ground state. A very narrow zigzag-edged Kagome-P ribbon displays the spin moment distribution similar to the zigzag-edged graphene nanoribbon because of the coupling between the opposites edges. But the inter-edge coupling in the Kagome-P ribbon vanishes more rapidly as the ribbon width increases. These properties make it a promising material in spintronics.

  18. Two-dimensional Kagome phosphorus and its edge magnetism: a density functional theory study

    Science.gov (United States)

    Yu, Guodong; Jiang, Liwei; Zheng, Yisong

    2015-06-01

    By means of density functional theory calculations, we predict a new two-dimensional phosphorus allotrope with the Kagome-like lattice(Kagome-P). It is an indirect gap semiconductor with a band gap of 1.64 eV. The gap decreases sensitively with the compressive strain. In particular, shrinking the lattice beyond 13% can drive it into metallic state. In addition, both the AA and AB stacked Kagome-P multi-layer structures exhibit a bandgap much smaller than 1.64 eV. Edges in the Kagome-P monolayer probably suffer from the edge reconstruction. An isolated zigzag edge can induce antiferromagnetic (AF) ordering with a magnetic transition temperature of 23 K. More importantly, when applying a stretching strain beyond 4%, such an edge turns to possess a ferromagnetic ground state. A very narrow zigzag-edged Kagome-P ribbon displays the spin moment distribution similar to the zigzag-edged graphene nanoribbon because of the coupling between the opposites edges. But the inter-edge coupling in the Kagome-P ribbon vanishes more rapidly as the ribbon width increases. These properties make it a promising material in spintronics.

  19. SISGR: Improved Electrical Energy Storage with Electrochemical Double Layer Capacitance Based on Novel Carbon Electrodes, New Electrolytes, and Thorough Development of a Strong Science Base

    Energy Technology Data Exchange (ETDEWEB)

    Ruoff, Rodney S. [PI; Alam, Todd M. [co-PI; Bielawski, Christopher W. [co-PI; Chabal, Yves [co-PI; Hwang, Gyeong [co-PI; Ishii, Yoshitaka [co-PI; Rogers, Robin [co-PI

    2014-07-23

    The broad objective of the SISGR program is to advance the fundamental scientific understanding of electrochemical double layer capacitance (EDLC) and thus of ultracapacitor systems composed of a new type of electrode based on chemically modified graphene (CMG) and (primarily) with ionic liquids (ILs) as the electrolyte. Our team has studied the interplay between graphene-based and graphene-derived carbons as the electrode materials in electrochemical double layer capacitors (EDLC) systems on the one hand, and electrolytes including novel ionic liquids (ILs), on the other, based on prior work on the subject.

  20. The influence of ion binding and ion specific potentials on the double layer pressure between charged bilayers at low salt concentrations

    Science.gov (United States)

    Bostrom, M.; Lima, E. R. A.; Tavares, F. W.; Ninham, B. W.

    2008-04-01

    Measurements of surface forces between double-chained cationic bilayers adsorbed onto molecularly smooth mica surfaces across different millimolar salt solutions have revealed a large degree of ion specificity [Pashley et al., J. Phys. Chem. 90, 1637 (1986)]. This has been interpreted in terms of highly specific anion binding to the adsorbed bilayers. We show here that inclusion in the double layer theory of nonspecific ion binding and ion specific nonelectrostatic potentials acting between ions and the two surfaces can account for the phenomenon. It also gives the right Hofmeister series for the double layer pressure.

  1. On the study of ion-acoustic solitary waves and double-layers in a drift multicomponent plasma with electron-inertia

    Indian Academy of Sciences (India)

    S N Paul; S Chattopadhyaya; S K Bhattacharya; B Bera

    2003-06-01

    Using the pseudopotential method, theoretical investigation has been made on the first-order Korteweg-deVries ion-acoustic solitons in a multicomponent plasma consisting of warm positive ions, negative ions and isothermal electrons. The effects of electron-inertia and drift motion of the ions on the amplitudes and widths of the solitons have been studied in a plasma having (H+, Cl-), (H+, O-), (He+, H-) and (He+, O-) ions. Ion-acoustic double-layers have also been investigated for such plasmas. It has been found that drift velocity and electron-inertia have significant contribution on the formation of double-layers in multicomponent plasma.

  2. The quantum anomalous Hall effect in kagomé lattices.

    Science.gov (United States)

    Zhang, Zhi-Yong

    2011-09-14

    The quantum anomalous Hall (QAH) effect in kagomé lattices is investigated in the presence of both Rashba spin-orbit coupling and an exchange field. In addition to the gap at the Dirac points as found in graphene, a new topological energy gap is opened at the Γ point. With the Fermi energy lying in the first gap, the Chern number = 2 as in graphene, whereas with it lying in the second one, = 1. The distribution of Berry curvature is obtained to reveal the nontrivial topological properties in momentum space. For stripes with 'armchair' and 'zigzag' edges, the topological characteristics of gapless edge states on the genus g = 2 Riemann surface are studied. The obtained nonzero winding numbers also demonstrate the QAH effe

  3. Fragmentation of magnetism in artificial kagome dipolar spin ice.

    Science.gov (United States)

    Canals, Benjamin; Chioar, Ioan-Augustin; Nguyen, Van-Dai; Hehn, Michel; Lacour, Daniel; Montaigne, François; Locatelli, Andrea; Menteş, Tevfik Onur; Burgos, Benito Santos; Rougemaille, Nicolas

    2016-05-13

    Geometrical frustration in magnetic materials often gives rise to exotic, low-temperature states of matter, such as the ones observed in spin ices. Here we report the imaging of the magnetic states of a thermally active artificial magnetic ice that reveal the fingerprints of a spin fragmentation process. This fragmentation corresponds to a splitting of the magnetic degree of freedom into two channels and is evidenced in both real and reciprocal space. Furthermore, the internal organization of both channels is interpreted within the framework of a hybrid spin-charge model that directly emerges from the parent spin model of the kagome dipolar spin ice. Our experimental and theoretical results provide insights into the physics of frustrated magnets and deepen our understanding of emergent fields through the use of tailor-made magnetism.

  4. Possible SU(3) chiral spin liquid on the kagome lattice

    Science.gov (United States)

    Wu, Ying-Hai; Tu, Hong-Hao

    2016-11-01

    We propose an SU(3) symmetric Hamiltonian with short-range interactions on the kagome lattice and show that it hosts an Abelian chiral spin liquid (CSL) state. We provide numerical evidence based on exact diagonalization to show that this CSL state is stabilized in an extended region of the parameter space and can be viewed as a lattice version of the Halperin 221 fractional quantum Hall state of two-component bosons. We also construct a parton wave function for this CSL state and demonstrate that its variational energies are in good agreement with exact diagonalization results. The parton description further supports that the CSL is characterized by a chiral edge conformal field theory of the SU (3) 1 Wess-Zumino-Witten type.

  5. A two-dimensional spin liquid in quantum kagome ice.

    Science.gov (United States)

    Carrasquilla, Juan; Hao, Zhihao; Melko, Roger G

    2015-06-22

    Actively sought since the turn of the century, two-dimensional quantum spin liquids (QSLs) are exotic phases of matter where magnetic moments remain disordered even at zero temperature. Despite ongoing searches, QSLs remain elusive, due to a lack of concrete knowledge of the microscopic mechanisms that inhibit magnetic order in materials. Here we study a model for a broad class of frustrated magnetic rare-earth pyrochlore materials called quantum spin ices. When subject to an external magnetic field along the [111] crystallographic direction, the resulting interactions contain a mix of geometric frustration and quantum fluctuations in decoupled two-dimensional kagome planes. Using quantum Monte Carlo simulations, we identify a set of interactions sufficient to promote a groundstate with no magnetic long-range order, and a gap to excitations, consistent with a Z2 spin liquid phase. This suggests an experimental procedure to search for two-dimensional QSLs within a class of pyrochlore quantum spin ice materials.

  6. Monte Carlo simulations of ABC stacked kagome lattice films.

    Science.gov (United States)

    Yerzhakov, H V; Plumer, M L; Whitehead, J P

    2016-05-18

    Properties of films of geometrically frustrated ABC stacked antiferromagnetic kagome layers are examined using Metropolis Monte Carlo simulations. The impact of having an easy-axis anisotropy on the surface layers and cubic anisotropy in the interior layers is explored. The spin structure at the surface is shown to be different from that of the bulk 3D fcc system, where surface axial anisotropy tends to align spins along the surface [1 1 1] normal axis. This alignment then propagates only weakly to the interior layers through exchange coupling. Results are shown for the specific heat, magnetization and sub-lattice order parameters for both surface and interior spins in three and six layer films as a function of increasing axial surface anisotropy. Relevance to the exchange bias phenomenon in IrMn3 films is discussed.

  7. Magnetic Properties and Thermal Entanglement on a Triangulated Kagome Lattice

    CERN Document Server

    Ananikian, N S; Chakhmakhchyan, L A; Kocharian, A N

    2011-01-01

    The magnetic and entanglement thermal (equilibrium) properties in spin-1/2 Ising-Heisenberg model on a triangulated Kagome lattice are analyzed by means of variational mean-field like treatment based on Gibbs-Bogoliubov inequality. Because of the separable character of Ising-type exchange interactions between the Heisenberg trimers the calculation of quantum entanglement in a self-consistent field can be performed for each of the trimers individually. The concurrence in terms of three qubit isotropic Heisenberg model in effective Ising field is non-zero even in the absence of a magnetic field. The magnetic and entanglement properties exhibit common (plateau and peak) features observable via (antferromagnetic) coupling constant and external magnetic field. The critical temperature for the phase transition and threshold temperature for concurrence coincide in the case of antiferromagnetic coupling between qubits. The existence of entangled and disentangled phases in saturated and frustrated phases is establishe...

  8. PT-symmetry and kagome lattices (Conference Presentation)

    Science.gov (United States)

    Saxena, Avadh; Chern, Gia-Wei

    2016-09-01

    We consider a complex photonic lattice by placing PT-symmetric dimers at the Kagome lattice points. This lattice is a two-dimensional network of corner-sharing triangles. Each dimer represents a pair of strongly coupled waveguides. The frustrated coupling between waveguide modes results in a dispersionless flat band comprising spatially localized modes. For a balanced arrangement of gain and loss on each dimer, up to a critical value of the gain/loss parameter the system exhibits a PT-symmetric phase. The beam evolution in the waveguide array leads to an oscillatory rotation of the optical power. We observe local chiral structures with a narrow beam excitation. We also study nonlinearity and disorder in this set up.

  9. The quantum anomalous Hall effect in kagome lattices

    Energy Technology Data Exchange (ETDEWEB)

    Zhang Zhiyong, E-mail: zyzhang@nju.edu.cn [Department of Physics, Nanjing University, Nanjing 210093 (China)

    2011-09-14

    The quantum anomalous Hall (QAH) effect in kagome lattices is investigated in the presence of both Rashba spin-orbit coupling and an exchange field. In addition to the gap at the Dirac points as found in graphene, a new topological energy gap is opened at the {Gamma} point. With the Fermi energy lying in the first gap, the Chern number c = 2 as in graphene, whereas with it lying in the second one, c = 1. The distribution of Berry curvature is obtained to reveal the nontrivial topological properties in momentum space. For stripes with 'armchair' and 'zigzag' edges, the topological characteristics of gapless edge states on the genus g = 2 Riemann surface are studied. The obtained nonzero winding numbers also demonstrate the QAH effect. (paper)

  10. Quantum Hall effect in kagome lattices under staggered magnetic field

    Energy Technology Data Exchange (ETDEWEB)

    Zhang Zhiyong, E-mail: zyzhang@nju.edu.cn [Department of Physics, Nanjing University, Nanjing 210093 (China)

    2011-10-26

    The interplay of staggered magnetic field (SMF) and uniform magnetic field (UMF) on the quantum Hall effect (QHE) in kagome lattices is investigated in the weak UMF limit. The topological band gaps coming from SMF are robust against UMF although the extended bands split into a series of Landau levels. With SMF applied, in the unconventional QHE region, one plateau of Hall conductance becomes wider and the others are compressed. Meanwhile, one of the two series of integer Hall plateaus splits and the resulting two series of Hall plateaus still exhibit the integer behavior. The Hall conductance varies with SMF step by step with the step height being e{sup 2}/h or 2e{sup 2}/h according to the QHE being conventional or unconventional. In the transitional regions, redistribution of Chern numbers happens even in the weak UMF limit. (paper)

  11. Fragmentation of magnetism in artificial kagome dipolar spin ice

    Science.gov (United States)

    Canals, Benjamin; Chioar, Ioan-Augustin; Nguyen, Van-Dai; Hehn, Michel; Lacour, Daniel; Montaigne, François; Locatelli, Andrea; Menteş, Tevfik Onur; Burgos, Benito Santos; Rougemaille, Nicolas

    2016-05-01

    Geometrical frustration in magnetic materials often gives rise to exotic, low-temperature states of matter, such as the ones observed in spin ices. Here we report the imaging of the magnetic states of a thermally active artificial magnetic ice that reveal the fingerprints of a spin fragmentation process. This fragmentation corresponds to a splitting of the magnetic degree of freedom into two channels and is evidenced in both real and reciprocal space. Furthermore, the internal organization of both channels is interpreted within the framework of a hybrid spin-charge model that directly emerges from the parent spin model of the kagome dipolar spin ice. Our experimental and theoretical results provide insights into the physics of frustrated magnets and deepen our understanding of emergent fields through the use of tailor-made magnetism.

  12. Strongly interacting particles on an anisotropic kagome lattice

    Energy Technology Data Exchange (ETDEWEB)

    Hotta, Chisa; Pollmann, Frank, E-mail: chisa@cc.kyoto-su.ac.j [Kyoto Sangyo University, Department of Physics, Faculty of Science, Kyoto 603-8555, Japan Department of Physics, University of California, Berkeley, CA94720 (United States)

    2009-01-01

    We study a model of strongly interacting spinless fermions and hard-core bosons on an anisotropic kagome lattice near 2/3-filling. Our main focus lies on the strongly anisotropic case in which the nearest-neighbor repulsions V and V' are large compared to the hopping amplitudes |t| and |t'|. When t = t' = 0, the system has a charge ordered insulating ground state where the charges align in striped configurations. Doping one electron or hole into the ground state yields an anisotropic metal at V' > V, where the particle fractionalizes along the V'-bonds while propagates along the V-bonds in a one-body like manner. The sixth order ring exchange processes around the hexagonal unit of the lattice play a crucial role in forming a bound state of fractional charges.

  13. Strongly interacting particles on an anisotropic kagome lattice

    Science.gov (United States)

    Hotta, Chisa; Pollmann, Frank

    2009-01-01

    We study a model of strongly interacting spinless fermions and hard-core bosons on an anisotropic kagome lattice near 2/3-filling. Our main focus lies on the strongly anisotropic case in which the nearest-neighbor repulsions V and V' are large compared to the hopping amplitudes |t| and |t'|. When t = t' = 0, the system has a charge ordered insulating ground state where the charges align in striped configurations. Doping one electron or hole into the ground state yields an anisotropic metal at V' > V, where the particle fractionalizes along the V'-bonds while propagates along the V-bonds in a one-body like manner. The sixth order ring exchange processes around the hexagonal unit of the lattice play a crucial role in forming a bound state of fractional charges.

  14. Kapellasite: a kagome quantum spin liquid with competing interactions.

    Science.gov (United States)

    Fåk, B; Kermarrec, E; Messio, L; Bernu, B; Lhuillier, C; Bert, F; Mendels, P; Koteswararao, B; Bouquet, F; Ollivier, J; Hillier, A D; Amato, A; Colman, R H; Wills, A S

    2012-07-20

    Magnetic susceptibility, NMR, muon spin relaxation, and inelastic neutron scattering measurements show that kapellasite, Cu3Zn(OH)6Cl2, a geometrically frustrated spin-1/2 kagome antiferromagnet polymorphic with herbertsmithite, is a gapless spin liquid showing unusual dynamic short-range correlations of noncoplanar cuboc2 type which persist down to 20 mK. The Hamiltonian is determined from a fit of a high-temperature series expansion to bulk susceptibility data and possesses competing exchange interactions. The magnetic specific heat calculated from these exchange couplings is in good agreement with experiment. The temperature dependence of the magnetic structure factor and the muon relaxation rate are calculated in a Schwinger-boson approach and compared to experimental results.

  15. Tunable anisotropic superfluidity in an optical kagome superlattice

    Science.gov (United States)

    Zhang, Xue-Feng; Wang, Tao; Eggert, Sebastian; Pelster, Axel

    2015-07-01

    We study the phase diagram of the Bose-Hubbard model on the kagome lattice with a broken sublattice symmetry. Such a superlattice structure can naturally be created and tuned by changing the potential offset of one sublattice in the optical generation of the frustrated lattice. The superstructure gives rise to a rich quantum phase diagram, which is analyzed by combining quantum Monte Carlo simulations with the generalized effective potential Landau theory. Mott phases with noninteger filling and a characteristic order along stripes are found, which show a transition to a superfluid phase with an anisotropic superfluid density. Surprisingly, the direction of the superfluid anisotropy can be tuned by changing the particle number, the hopping strength, or the interaction. Finally, we discuss characteristic signatures of anisotropic phases in time-of-flight absorption measurements.

  16. Monte Carlo simulations of ABC stacked kagome lattice films

    Science.gov (United States)

    Yerzhakov, H. V.; Plumer, M. L.; Whitehead, J. P.

    2016-05-01

    Properties of films of geometrically frustrated ABC stacked antiferromagnetic kagome layers are examined using Metropolis Monte Carlo simulations. The impact of having an easy-axis anisotropy on the surface layers and cubic anisotropy in the interior layers is explored. The spin structure at the surface is shown to be different from that of the bulk 3D fcc system, where surface axial anisotropy tends to align spins along the surface [1 1 1] normal axis. This alignment then propagates only weakly to the interior layers through exchange coupling. Results are shown for the specific heat, magnetization and sub-lattice order parameters for both surface and interior spins in three and six layer films as a function of increasing axial surface anisotropy. Relevance to the exchange bias phenomenon in IrMn3 films is discussed.

  17. Fractionalized spin-wave continuum in kagome spin liquids

    Science.gov (United States)

    Mei, Jia-Wei; Wen, Xiao-Gang

    Motivated by spin-wave continuum (SWC) observed in recent neutron scattering experiments in Herbertsmithite, we use Gutzwiller-projected wave functions to study dynamic spin structure factor S (q , ω) of spin liquid states on the kagome lattice. Spin-1 excited states in spin liquids are represented by Gutzwiller-projected two-spinon excited wave functions. We investigate three different spin liquid candidates, spinon Fermi-surface spin liquid (FSL), Dirac spin liquid (DSL) and random-flux spin liquid (RSL). FSL and RSL have low energy peaks in S (q , ω) at K points in the extended magnetic Brillouin zone, in contrast to experiments where low energy peaks are found at M points. There is no obviuos contradiction between DSL and neutron scattering measurements. Besides a fractionalized spin (i.e. spin-1/2), spinons in DSL carry a fractionalized crystal momentum which is potentially detectable in SWC in the neutron scattering measurements.

  18. Grid Computing

    Indian Academy of Sciences (India)

    2016-05-01

    A computing grid interconnects resources such as high performancecomputers, scientific databases, and computercontrolledscientific instruments of cooperating organizationseach of which is autonomous. It precedes and is quitedifferent from cloud computing, which provides computingresources by vendors to customers on demand. In this article,we describe the grid computing model and enumerate themajor differences between grid and cloud computing.

  19. Charge Efficiency: A Functional Tool to Probe the Double-Layer Structure Inside of Porous Electrodes and Application in the Modeling of Capacitive Deionization

    NARCIS (Netherlands)

    Zhao, R.; Biesheuvel, P.M.; Miedema, H.; Bruning, H.; Wal, van der A.

    2010-01-01

    Porous electrodes are important in many physical-chemical processes including capacitive deionization (CDI), a desalination technology where ions are adsorbed from solution into the electrostatic double layers formed at the electrode/solution interface inside of two juxtaposed porous electrodes. A k

  20. Dichotomy of the electronic structure and superconductivity between single-layer and double-layer FeSe/SrTiO3 films.

    Science.gov (United States)

    Liu, Xu; Liu, Defa; Zhang, Wenhao; He, Junfeng; Zhao, Lin; He, Shaolong; Mou, Daixiang; Li, Fangsen; Tang, Chenjia; Li, Zhi; Wang, Lili; Peng, Yingying; Liu, Yan; Chen, Chaoyu; Yu, Li; Liu, Guodong; Dong, Xiaoli; Zhang, Jun; Chen, Chuangtian; Xu, Zuyan; Chen, Xi; Ma, Xucun; Xue, Qikun; Zhou, X J

    2014-09-23

    The latest discovery of possible high-temperature superconductivity in the single-layer FeSe film grown on a SrTiO3 substrate has generated much attention. Initial work found that, while the single-layer FeSe/SrTiO3 film exhibits a clear signature of superconductivity, the double-layer film shows an insulating behaviour. Such a marked layer-dependent difference is surprising and the underlying origin remains unclear. Here we report a comparative angle-resolved photoemission study between the single-layer and double-layer FeSe/SrTiO3 films annealed in vacuum. We find that, different from the single-layer FeSe/SrTiO3 film, the double-layer FeSe/SrTiO3 film is hard to get doped and remains in the semiconducting/insulating state under an extensive annealing condition. Such a behaviour originates from the much reduced doping efficiency in the bottom FeSe layer of the double-layer FeSe/SrTiO3 film from the FeSe-SrTiO3 interface. These observations provide key insights in understanding the doping mechanism and the origin of superconductivity in the FeSe/SrTiO3 films.

  1. Vibrational Stark Effect to Probe the Electric-Double Layer of the Ionic Liquid-Metal Electrodes

    Science.gov (United States)

    Garcia Rey, Natalia; Moore, Alexander Knight; Toyouchi, Shuichi; Dlott, Dana

    2017-06-01

    Vibrational sum frequency generation (VSFG) spectroscopy is used to study the effect of room temperature ionic liquids (RTILs) in situ at the electrical double layer (EDL). RTILs have been recognized as electrolytes without solvent for applications in batteries, supercapacitors and electrodeposition^{1}. The molecular response of the RTIL in the EDL affects the performance of these devices. We use the vibrational Stark effect on CO as a probe to detect the changes in the electric field affected by the RTIL across the EDL on metal electrodes. The Stark effect is a shift in the frequency in response to an externally applied electric field and also influenced by the surrounding electrolyte and electrode^{2}. The CO Stark shift is monitored by the CO-VSFG spectra on Pt or Ag in a range of different imidazolium-based RTILs electrolytes, where their composition is tuned by exchanging the anion, the cation or the imidazolium functional group. We study the free induction decay (FID)^{3} of the CO to monitor how the RTIL structure and composition affect the vibrational relaxation of the CO. Combining the CO vibrational Stark effect and the FID allow us to understand how the RTIL electrochemical response, molecular orientation response and collective relaxation affect the potential drop of the electric field across the EDL, and, in turn, how determines the electrical capacitance or reactivity of the electrolyte/electrode interface. ^{1}Fedorov, M. V.; Kornyshev, A. A., Ionic Liquids at Electrified Interfaces. Chem. Rev. 2014, 114, 2978-3036. ^{2} (a) Lambert, D. K., Vibrational Stark Effect of Adsorbates at Electrochemical Interfaces. Electrochim. Acta 1996, 41, 623-630. (b) Oklejas, V.; Sjostrom, C.; Harris, J. M., SERS Detection of the Vibrational Stark Effect from Nitrile-Terminated SAMs to Probe Electric Fields in the Diffuse Double-Layer. J. Am. Chem. Soc. 2002, 124, 2408-2409. ^{3}Symonds, J. P. R.; Arnolds, H.; Zhang, V. L.; Fukutani, K.; King, D. A

  2. A Prospective Randomized Clinical Trial of Single vs. Double Layer Closure of Hysterotomy at the Time of Cesarean Delivery: The Effect on Uterine Scar Thickness.

    Science.gov (United States)

    Bamberg, C; Dudenhausen, J W; Bujak, V; Rodekamp, E; Brauer, M; Hinkson, L; Kalache, K; Henrich, W

    2016-09-14

    Purpose: We undertook a randomized clinical trial to examine the outcome of a single vs. a double layer uterine closure using ultrasound to assess uterine scar thickness. Materials and Methods: Participating women were allocated to one of three uterotomy suture techniques: continuous single layer unlocked suturing, continuous locked single layer suturing, or double layer suturing. Transvaginal ultrasound of uterine scar thickness was performed 6 weeks and 6 - 24 months after Cesarean delivery. Sonographers were blinded to the closure technique. Results: An "intent-to-treat" and "as treated" ANOVA analysis included 435 patients (n = 149 single layer unlocked suturing, n = 157 single layer locked suturing, and n = 129 double layer suturing). 6 weeks postpartum, the median scar thickness did not differ among the three groups: 10.0 (8.5 - 12.3 mm) single layer unlocked vs. 10.1 (8.2 - 12.7 mm) single layer locked vs. 10.8 (8.1 - 12.8 mm) double layer; (p = 0.84). At the time of the second follow-up, the uterine scar was not significantly (p = 0.06) thicker if the uterus had been closed with a double layer closure 7.3 (5.7 - 9.1 mm), compared to single layer unlocked 6.4 (5.0 - 8.8 mm) or locked suturing techniques 6.8 (5.2 - 8.7 mm). Women who underwent primary or elective Cesarean delivery showed a significantly (p = 0.03, p = 0.02, "as treated") increased median scar thickness after double layer closure vs. single layer unlocked suture. Conclusion: A double layer closure of the hysterotomy is associated with a thicker myometrium scar only in primary or elective Cesarean delivery patients.

  3. A Study on Load Carrying Capacity of Fly Ash Based Polymer Concrete Columns Strengthened Using Double Layer GFRP Wrapping

    Directory of Open Access Journals (Sweden)

    S. Nagan

    2014-01-01

    Full Text Available This paper investigates the suitability of glass fiber reinforced polymer (GFRP sheets in strengthening of fly ash based polymer members under compression. Experimental results revealed that load carrying capacity of the confined columns increases with GFRP sheets wrapping. Altogether 18 specimens of M30 and G30 grade short columns were fabricated. The G30 specimens were prepared separately in 8 molarity and 12 molarity of sodium hydroxide concentration. Twelve specimens for low calcium fly ash based reinforced polymer concrete and six specimens of ordinary Portland cement reinforced concrete were cast. Three specimens from each molarity fly ash based reinforced polymer concrete and ordinary Portland cement reinforced concrete were wrapped with double layer of GFRP sheets. The load carrying capacity of fly ash based polymer concrete was tested and compared with control specimens. The results show increase in load carrying capacity and ductility index for all strengthened elements. The maximum increase in load carrying capacity was 68.53% and is observed in strengthened G30 specimens.

  4. Improved performance of Li-ion cells under pulsed load using double-layer capacitors in a hybrid circuit mode

    Energy Technology Data Exchange (ETDEWEB)

    ROTH,EMANUEL P.; NAGASUBRAMANIAN,GANESAN

    2000-02-07

    Electrical characteristics of hybrid power sources consisting of Li-ion cells and double-layer capacitors were studied at 25 C and {minus}20 C. The cells were initially evaluated for pulse performance and then measured in hybrid modes of operation where they were coupled with the high-power capacitors. Cells manufactured by Panasonic measured at 25 C delivered full capacities of 0.76 Ah for pulses up to 3A and cells from A and T delivered full capacities of 0.73 Ah for pulses up to 4A. Measured cell resistances were 0.15 ohms and 0.12 ohms, respectively. These measurements were repeated at {minus}20 C. Direct coupling of the cells and capacitors (coupled hybrid) using 10F Panasonic capacitors in a 8F series/parallel combination extended the full capacity pulse limits (3.0V threshold) to 5.6A for the Panasonic cells and to 9A for the A and T cells. A similar arrangement using 100F capacitors from Elna in a 60F combination increased the Panasonic cell limit to 10 A. Operation in an uncoupled hybrid mode using uncoupled cell/capacitor discharge allowed fill cell capacity usage at 25 C up to the capacitor discharge limit and showed a factor of 5 improvement in delivered capacity at {minus}20 C.

  5. Estimation of Bidirectional Buck/boost DC/DC Converters with Electric Double-Layer Capacitors for Energy Storage Systems

    Science.gov (United States)

    Funabiki, Shigeyuki; Yamamoto, Masayoshi

    Renewable energy such as wind force and solar light has collected the attention as alternative energy sources of fossil fuel. An energy storage system with an electric double-layer capacitor (EDLC), which balances the demand and supply power, is required in order to introduce the electric power generating system that utilizes renewable energy. Currently, the research and development of these energy storage systems are actively carried out. In the energy storage system with an EDLC, the DC/DC converter having the function of the bidirectional power flow and the buck/boost performance is essential as an interface and power control circuit. There are two types of the bidirectional buck/boost DC/DC converters. One type consists of two buck/boost DC/DC converters with one reactor. The other type consists of two sets of two-quadrant DC/DC converters with one reactor. This paper discusses the comparison of these types of DC/DC converters with bidirectional power flow and buck/boost performance. The two types of DC/DC converters are estimated for their application to the energy storage system with the EDLC. As the voltage endurance of the device is lower and the mean current is smaller in the latter type of converter despite of having twice the number of devices compared to the former, the latter type of converter has the advantage of a smaller reactor, i.e., core volume and loss, and lower loss in the converter.

  6. Design and numerical simulation of a silicon-based linear polarizer with double-layered metallic nano-gratings

    Science.gov (United States)

    Lin, Yu; Hu, Jingpei; Wang, Chinhua

    2016-10-01

    With the increasing demand for linearly polarized elements with high performance in many fields and applications, design and fabrication of sub-wavelength metallic linear polarizer have made tremendous progress in recent years. In this paper, we proposed a novel structure of a silicon-based linear polarizer working in the infrared (3-5μm) waveband with a double-layered metallic grating structure. A two-layer metallic grating with a transition layer of low refractive index is fabricated on a silicon substrate. In contrast to those conventional single layer metallic polarizing grating, the multilayer polarizing structure has the advantages of easy fabrication and high performance. Numerical simulation results show that an extinction ratio of linear polarization can be up to 58.5dB and the TM-polarized light transmission is greater than 90%. The behaviors and advantages of the proposed multilayer polarizer are compared with that of a traditional single-layer metallic grating. The proposed silicon-based linear polarizer will have great potential applications in real-time polarization imaging with high extinction ratio and high transmission.

  7. An ether-functionalised cyclic sulfonium based ionic liquid as an electrolyte for electrochemical double layer capacitors

    Science.gov (United States)

    Neale, Alex R.; Murphy, Sinead; Goodrich, Peter; Schütter, Christoph; Hardacre, Christopher; Passerini, Stefano; Balducci, Andrea; Jacquemin, Johan

    2016-09-01

    A novel cyclic sulfonium cation-based ionic liquid (IL) with an ether-group appendage and the bis{(trifluoromethyl)sulfonyl}imide anion was synthesised and developed for electrochemical double layer capacitor (EDLC) testing. The synthesis and chemical-physical characterisation of the ether-group containing IL is reported in parallel with a similarly sized alkyl-functionalised sulfonium IL. Results of the chemical-physical measurements demonstrate how important transport properties, i.e. viscosity and conductivity, can be promoted through the introduction of the ether-functionality without impeding thermal, chemical or electrochemical stability of the IL. Although the apparent transport properties are improved relative to the alkyl-functionalised analogue, the ether-functionalised sulfonium cation-based IL exhibits moderately high viscosity, and poorer conductivity, when compared to traditional EDLC electrolytes based on organic solvents (propylene carbonate and acetonitrile). Electrochemical testing of the ether-functionalised sulfonium IL was conducted using activated carbon composite electrodes to inspect the performance of the IL as a solvent-free electrolyte for EDLC application. Good cycling stability was achieved over the studied range and the performance was comparable to other solvent-free, IL-based EDLC systems. Nevertheless, limitations of the attainable performance are primarily the result of sluggish transport properties and a restricted operative voltage of the IL, thus highlighting key aspects of this field which require further attention.

  8. The Equivalent Electrokinetic Circuit Model of Ion Concentration Polarization Layer: Electrical Double Layer, Extended Space Charge and Electro-convection

    Science.gov (United States)

    Cho, Inhee; Huh, Keon; Kwak, Rhokyun; Lee, Hyomin; Kim, Sung Jae

    2016-11-01

    The first direct chronopotentiometric measurement was provided to distinguish the potential difference through the extended space charge (ESC) layer which is formed with the electrical double layer (EDL) near a perm-selective membrane. From this experimental result, the linear relationship was obtained between the resistance of ESC and the applied current density. Furthermore, we observed the step-wise distributions of relaxation time at the limiting current regime, confirming the existence of ESC capacitance other than EDL's. In addition, we proposed the equivalent electrokinetic circuit model inside ion concentration polarization (ICP) layer under rigorous consideration of EDL, ESC and electro-convection (EC). In order to elucidate the voltage configuration in chronopotentiometric measurement, the EC component was considered as the "dependent voltage source" which is serially connected to the ESC layer. This model successfully described the charging behavior of the ESC layer with or without EC, where both cases determined each relaxation time, respectively. Finally, we quantitatively verified their values utilizing the Poisson-Nernst-Planck equations. Therefore, this unified circuit model would provide a key insight of ICP system and potential energy-efficient applications.

  9. Grafting effect on the wetting and electrochemical performance of carbon cloth electrode and polypropylene separator in electric double layer capacitor

    Science.gov (United States)

    Stepniak, Izabela; Ciszewski, Aleksander

    Activated carbon (AC) fiber cloths and hydrophobic microporous polypropylene (PP) membrane, both modified by plasma-induced graft polymerization of acrylic acid (AAc) under UV irradiation, and filled with saturated lithium hydroxide solution were used as electrodes, a separator and electrolyte in electric double layer capacitors (EDLCs). The modification process changed the hydrophobic character of AC and PP materials to hydrophilic, made them wettable and serviceable as components of an electrochemical capacitor. The presence of poly(acrylic acid) on the AC and PP surface was confirmed by SEM and XPS methods. Electrochemical characteristics of EDLCs were investigated by cyclic voltammetry and galvanostatic charge-discharge cycle tests and also by impedance spectroscopy. At the 1000th cycle of potential cycling (1 A g -1) the specific capacitance of 110 F g -1 was obtained with a specific energy of 11 Wh kg -1 at power density of 1 kW kg -1. The above results provide valuable information which may be used when developing novel compositions of EDLCs.

  10. Gamma-ray double-layered transmission exposure buildup factors of some engineering materials, a comparative study

    Science.gov (United States)

    Mann, Kulwinder Singh; Heer, Manmohan Singh; Rani, Asha

    2016-08-01

    Comparative study on various deterministic methods and formulae of double layered transmission exposure buildup factors (DLEBF) for point isotropic gamma-ray sources has been performed and the results are provided here. This investigation has been performed on some commonly available engineering materials for the purpose of gamma-ray shielding. In reality, the presence of air around the gamma-ray shield motivated to focus this study on exposure buildup factor (EBF). DLEBF have been computed at four energies viz. 0.5, 1.0, 2.0 and 3.0 MeV for various combinations of the chosen five samples taken two at a time with combined optical thickness up to 8 mean free path (mfp). For the necessary computations for DLEBF, a computer program (BUF-toolkit) has been designed. Comparison of Monte Carlo (EGS4-code) and Geometric Progression (G.P.) fitting point kernel methods were done for DLEBF computation. It is concluded that empirical formula given by Lin and Jiang using EBF computed by G.P. fitting formula is the most accurate and easiest method for DLEBF computations. It was observed that DLEBF values at selected energies for two layered slabs with an orientation (low-Z material followed by high-Z material) were lower than the opposite orientation. For optical thickness up to 8 mfp and chosen energy range (0.5-3.0 MeV), Aluminum-Lime Stone shield, appears to provide the best protection against the gamma-rays.

  11. Effect of ion charges on the electric double layer capacitance of activated carbon in aqueous electrolyte systems

    Science.gov (United States)

    Icaza, Juan C.; Guduru, Ramesh K.

    2016-12-01

    Carbon based electrochemical double layer capacitors (EDLCs) are known for high power density, but their energy density is limited due to surface characteristics of the electrode materials as well as the size and charge of the ions used in the electrolyte. Therefore, considering the current demand for enhanced energy density devices, we investigated the use of multivalent electrolytes to increase the capacitance of activated carbon (AC) based EDLCs. As part of these studies, we examined the effect of the charge of the multivalent ions on the capacitive behavior of microporous AC electrodes and compared with the univalent Li+ system. We performed impedance and cyclic voltammetry measurements on AC electrodes in a symmetric two electrode configuration to determine the impedance and capacitance with respect to varying charge and concentration of the ions in the aqueous nitrate electrolytes. These studies clearly demonstrated an increased capacitance with Mg2+ and Al3+ implying the possible effects of ion mobility and electrolyte conductivity in addition to the multivalent charge. These preliminary observations clearly point to the importance of selection of electrolyte ions with more charge, conductivity, and suitable size with respect to the pore size of the electrodes in order to increase the capacitance of EDLCs.

  12. Superwetting double-layer polyester materials for effective removal of both insoluble oils and soluble dyes in water.

    Science.gov (United States)

    Li, Bucheng; Wu, Lei; Li, Lingxiao; Seeger, Stefan; Zhang, Junping; Wang, Aiqin

    2014-07-23

    Inspired by the mussel adhesive protein and the lotus leaf, Ag-based double-layer polyester (DL-PET) textiles were fabricated for effective removal of organic pollutants in water. The DL-PET textiles are composed of a top superamphiphilic layer and a bottom superhydrophobic/superoleophilic layer. First, the PET textiles were modified with a layer of polydopamine (PDA) and deposited with Ag nanoparticles to form the PET@PDA@Ag textiles. The top superamphiphilic layer, formed by immobilizing Ag3PO4 nanoparticles on the PET@PDA@Ag textile, shows excellent visible-light photocatalytic activity. The bottom superhydrophobic/superoleophilic layer, formed by modifying the PET@PDA@Ag textile using dodecyl mercaptan, is mechanically, environmentally, and chemically very stable. The water-insoluble oils with low surface tension can penetrate both layers of the DL-PET textiles, while the water with soluble organic dyes can only selectively wet the top layer owing to their unique wettability. Consequently, the water-soluble organic contaminants in the collected water can be decomposed by the Ag3PO4 nanoparticles of the top layer under visible-light irradiation or even sunlight in room conditions. Thus, the DL-PET textiles can remove various kinds of organic pollutants in water including both insoluble oils and soluble dyes. The DL-PET textiles feature unique wettability, high oil/water separation efficiency, and visible-light photocatalytic activity.

  13. A Novel Degradation Estimation Method for a Hybrid Energy Storage System Consisting of Battery and Double-Layer Capacitor

    Directory of Open Access Journals (Sweden)

    Yuanbin Yu

    2016-01-01

    Full Text Available This paper presents a new method for battery degradation estimation using a power-energy (PE function in a battery/ultracapacitor hybrid energy storage system (HESS, and the integrated optimization which concerns both parameters matching and control for HESS has been done as well. A semiactive topology of HESS with double-layer capacitor (EDLC coupled directly with DC-link is adopted for a hybrid electric city bus (HECB. In the purpose of presenting the quantitative relationship between system parameters and battery serving life, the data during a 37-minute driving cycle has been collected and decomposed into discharging/charging fragments firstly, and then the optimal control strategy which is supposed to maximally use the available EDLC energy is presented to decompose the power between battery and EDLC. Furthermore, based on a battery degradation model, the conversion of power demand by PE function and PE matrix is applied to evaluate the relationship between the available energy stored in HESS and the serving life of battery pack. Therefore, according to the approach which could decouple parameters matching and optimal control of the HESS, the process of battery degradation and its serving life estimation for HESS has been summed up.

  14. Realization of Colored Multicrystalline Silicon Solar Cells with SiO2/SiNx:H Double Layer Antireflection Coatings

    Directory of Open Access Journals (Sweden)

    Minghua Li

    2013-01-01

    Full Text Available We presented a method to use SiO2/SiNx:H double layer antireflection coatings (DARC on acid textures to fabricate colored multicrystalline silicon (mc-Si solar cells. Firstly, we modeled the perceived colors and short-circuit current density (Jsc as a function of SiNx:H thickness for single layer SiNx:H, and as a function of SiO2 thickness for the case of SiO2/SiNx:H (DARC with fixed SiNx:H (refractive index n=2.1 at 633 nm, and thickness = 80 nm. The simulation results show that it is possible to achieve various colors by adjusting the thickness of SiO2 to avoid significant optical losses. Therefore, we carried out the experiments by using electron beam (e-beam evaporation to deposit a layer of SiO2 over the standard SiNx:H for 156×156 mm2 mc-Si solar cells which were fabricated by a conventional process. Semisphere reflectivity over 300 nm to 1100 nm and I-V measurements were performed for grey yellow, purple, deep blue, and green cells. The efficiency of colored SiO2/SiNx:H DARC cells is comparable to that of standard SiNx:H light blue cells, which shows the potential of colored cells in industrial applications.

  15. Mechanical Properties of Double-Layer and Graded Composite Coatings of YSZ Obtained by Atmospheric Plasma Spraying

    Science.gov (United States)

    Carpio, Pablo; Rayón, Emilio; Salvador, María Dolores; Lusvarghi, Luca; Sánchez, Enrique

    2016-04-01

    Double-layer and graded composite coatings of yttria-stabilized zirconia were sprayed on metallic substrates by atmospheric plasma spray. The coating architecture was built up by combining two different feedstocks: one micro- and one nanostructured. Microstructural features and mechanical properties (hardness and elastic modulus) of the coatings were determined by FE-SEM microscopy and nanoindentation technique, respectively. Additional adherence and scratch tests were carried out in order to assess the failure mechanisms occurring between the layers comprising the composites. Microstructural inspection of the coatings confirms the two-zone microstructure. This bimodal microstructure which is exclusive of the layer obtained from the nanostructured feedstock negatively affects the mechanical properties of the whole composite. Nanoindentation tests suitably reproduce the evolution of mechanical properties through coatings thickness on the basis of the position and/or amount of nanostructured feedstock used in the depositing layer. Adhesion and scratch tests show the negative effect on the coating adhesion of layer obtained from the nanostructured feedstock when this layer is deposited on the bond coat. Thus, the poor integrity of this layer results in lower normal stresses required to delaminate the coating in the adhesion test as well as minor critical load registered by using the scratch test.

  16. Extended-gate-type IGZO electric-double-layer TFT immunosensor with high sensitivity and low operation voltage

    Science.gov (United States)

    Liang, Lingyan; Zhang, Shengnan; Wu, Weihua; Zhu, Liqiang; Xiao, Hui; Liu, Yanghui; Zhang, Hongliang; Javaid, Kashif; Cao, Hongtao

    2016-10-01

    An immunosensor is proposed based on the indium-gallium-zinc-oxide (IGZO) electric-double-layer thin-film transistor (EDL TFT) with a separating extended gate. The IGZO EDL TFT has a field-effect mobility of 24.5 cm2 V-1 s-1 and an operation voltage less than 1.5 V. The sensors exhibit the linear current response to label-free target immune molecule in the concentrations ranging from 1.6 to 368 × 10-15 g/ml with a detection limit of 1.6 × 10-15 g/ml (0.01 fM) under an ultralow operation voltage of 0.5 V. The IGZO TFT component demonstrates a consecutive assay stability and recyclability due to the unique structure with the separating extended gate. With the excellent electrical properties and the potential for plug-in-card-type multifunctional sensing, extended-gate-type IGZO EDL TFTs can be promising candidates for the development of a label-free biosensor for public health applications.

  17. Homoclinic behaviors and chaotic motions of double layered viscoelastic nanoplates based on nonlocal theory and extended Melnikov method.

    Science.gov (United States)

    Wang, Yu; Li, Feng-Ming; Wang, Yi-Ze

    2015-06-01

    The nonlinear dynamical equations are established for the double layered viscoelastic nanoplates (DLNP) subjected to in-plane excitation based on the nonlocal theory and von Kármán large deformation theory. The extended high dimensional homoclinic Melnikov method is employed to study the homoclinic phenomena and chaotic motions for the parametrically excited DLNP system. The criteria for the homoclinic transverse intersection for both the asynchronous and synchronous buckling cases are proposed. Lyapunov exponents and phase portraits are obtained to verify the Melnikov-type analysis. The influences of structural parameters on the transverse homoclinic orbits and homoclinic bifurcation sets are discussed for the two buckling cases. Some novel phenomena are observed in the investigation. It should be noticed that the nonlocal effect on the homoclinic behaviors and chaotic motions is quite remarkable. Hence, the small scale effect should be taken into account for homoclinic and chaotic analysis for nanostructures. It is significant that the nonlocal effect on the homoclinic phenomena for the asynchronous buckling case is quite different from that for the synchronous buckling case. Moreover, due to the van der Walls interaction between the layers, the nonlocal effect on the homoclinic behaviors and chaotic motions for high order mode is rather tiny under the asynchronous buckling condition.

  18. A Novel Method for Fabricating Double Layers Porous Anodic Alumina in Phosphoric/Oxalic Acid Solution and Oxalic Acid Solution

    Directory of Open Access Journals (Sweden)

    Yanfang Xu

    2016-01-01

    Full Text Available A novel method for fabricating ordered double layers porous anodic alumina (DL-PAA with controllable nanopore size was presented. Highly ordered large pore layer with interpore distance of 480 nm was fabricated in phosphoric acid solution with oxalic acid addition at the potential of 195 V and the small pore layer was fabricated in oxalic acid solution at the potential from 60 to 100 V. Experimental results show that the thickness of large pore layer is linearly correlative with anodizing time, and pore diameter is linearly correlative with pore widening time. When the anodizing potential in oxalic acid solution was adjusted from 60 to 100 V, the small pore layers with continuously tunable interpore distance from 142 to 241 nm and pore density from 1.94×109 to 4.89×109 cm−2 were obtained. And the interpore distance and the pore density of small pore layers are closely correlative with the anodizing potential. The fabricated DL-PAA templates can be widely utilized for fabrication of ordered nanomaterials, such as superhydrophobic or gecko-inspired adhesive materials and metal or semiconductor nanowires.

  19. Effect of ion beam on the characteristics of ion acoustic Gardner solitons and double layers in a multicomponent superthermal plasma

    Science.gov (United States)

    Kaur, Nimardeep; Singh, Kuldeep; Saini, N. S.

    2017-09-01

    The nonlinear propagation of ion acoustic solitary waves (IASWs) is investigated in an unmagnetized plasma composed of a positive warm ion fluid, two temperature electrons obeying kappa type distribution and penetrated by a positive ion beam. The reductive perturbation method is used to derive the nonlinear equations, namely, Korteweg-de Vries (KdV), modified KdV (mKdV), and Gardner equations. The characteristic features of both compressive and rarefactive nonlinear excitations from the solution of these equations are studied and compared in the context with the observation of the He+ beam in the polar cap region near solar maximum by the Dynamics Explorer 1 satellite. It is observed that the superthermality and density of cold electrons, number density, and temperature of the positive ion beam crucially modify the basic properties of compressive and rarefactive IASWs in the KdV and mKdV regimes. It is further analyzed that the amplitude and width of Gardner solitons are appreciably affected by different plasma parameters. The characteristics of double layers are also studied in detail below the critical density of cold electrons. The theoretical results may be useful for the observation of nonlinear excitations in laboratory and ion beam driven plasmas in the polar cap region near solar maximum and polar ionosphere as well in Saturn's magnetosphere, solar wind, pulsar magnetosphere, etc., where the population of two temperature superthermal electrons is present.

  20. Relationship between space charge and effective pore size of nanoporous electrode in electric double-layer capacitor

    Institute of Scientific and Technical Information of China (English)

    Daisuke Tashima; Masahisa Otsubo

    2011-01-01

    The space-charge distributions of electric double-layer capacitors (EDLCs),which are energy storage devices,were examined with the pulsed electroacoustic (PEA) method. It was found that the experimental results could be influenced by the reflection and penetration of sound waves when the space-charge distributions of EDLCs were measured with the PEA method. This is because EDLCs have a five-layer structure consisting of three materials (aluminum,cellulose,and activated carbon). We calculated the reflection wave components that influenced the charge density through the acoustic impedance and the relative permittivity of the materials. In this way,we found that the changes in the space-charge distributions of EDLCs and their charge characteristics corresponded closely. We determined that measuring the spacecharge distributions with the PEA method was effective for evaluating the charge accumulation of EDLCs.In this study,a polarized electrode was prepared for use in EDLCs. The ratio of the surface area to the average pore diameter of the polarized electrode was measured with the nitrogen adsorption method at 77 K. The relationship between the ratio of the surface area to the average pore size and the space-charge distributions of EDLCs is also discussed in this paper.

  1. Probing the characteristics of casein as green binder for non-aqueous electrochemical double layer capacitors' electrodes

    Science.gov (United States)

    Varzi, Alberto; Raccichini, Rinaldo; Marinaro, Mario; Wohlfahrt-Mehrens, Margret; Passerini, Stefano

    2016-09-01

    Casein from bovine milk is evaluated in this work as binding agent for electrochemical double layer capacitors (EDLCs) electrodes. It is demonstrated that casein provides excellent adhesion strength to the current collector (1187 kPa compared to 51 kPa achieved with PVdF), thus leading to mechanically stable electrodes. At the same time, it offers high thermal stability (above 200 °C) and electrochemical stability in organic electrolytes. Apparently though, the casein-based electrodes offer lower electronic conductivity than those based on other state-of-the-art binders, which can limit the rate performance of the resulting EDLC. In the attempt of improving the electrochemical performance, it is found that the application of a pressing step can solve this issue, leading to excellent rate capability (up to 84% capacitance retention at 50 mA cm-2) and cycling stability (96.8% after 10,000 cycles at 10 mA cm-2) in both PC- and ACN-based electrolytes. Although the adhesive power casein is known since ancient times, this report presents the first proof of concept of its employment in electrochemical power sources.

  2. Fundamental measure theory for the electric double layer: implications for blue-energy harvesting and water desalination

    Science.gov (United States)

    Härtel, Andreas; Janssen, Mathijs; Samin, Sela; van Roij, René

    2015-05-01

    Capacitive mixing (CAPMIX) and capacitive deionization (CDI) are promising candidates for harvesting clean, renewable energy and for the energy efficient production of potable water, respectively. Both CAPMIX and CDI involve water-immersed porous carbon (supercapacitors) electrodes at voltages of the order of hundreds of millivolts, such that counter-ionic packing is important for the electric double layer (EDL) which forms near the surfaces of these porous materials. Thus, we propose a density functional theory (DFT) to model the EDL, where the White-Bear mark II fundamental measure theory functional is combined with a mean-field Coulombic and a mean spherical approximation-type correction to describe the interplay between dense packing and electrostatics, in good agreement with molecular dynamics simulations. We discuss the concentration-dependent potential rise due to changes in the chemical potential in capacitors in the context of an over-ideal theoretical description and its impact on energy harvesting and water desalination. Compared to less elaborate mean-field models our DFT calculations reveal a higher work output for blue-energy cycles and a higher energy demand for desalination cycles.

  3. Reevaluation of Performance of Electric Double-layer Capacitors from Constant-current Charge/Discharge and Cyclic Voltammetry.

    Science.gov (United States)

    Allagui, Anis; Freeborn, Todd J; Elwakil, Ahmed S; Maundy, Brent J

    2016-12-09

    The electric characteristics of electric-double layer capacitors (EDLCs) are determined by their capacitance which is usually measured in the time domain from constant-current charging/discharging and cyclic voltammetry tests, and from the frequency domain using nonlinear least-squares fitting of spectral impedance. The time-voltage and current-voltage profiles from the first two techniques are commonly treated by assuming ideal SsC behavior in spite of the nonlinear response of the device, which in turn provides inaccurate values for its characteristic metrics. In this paper we revisit the calculation of capacitance, power and energy of EDLCs from the time domain constant-current step response and linear voltage waveform, under the assumption that the device behaves as an equivalent fractional-order circuit consisting of a resistance Rs in series with a constant phase element (CPE(Q, α), with Q being a pseudocapacitance and α a dispersion coefficient). In particular, we show with the derived (Rs, Q, α)-based expressions, that the corresponding nonlinear effects in voltage-time and current-voltage can be encompassed through nonlinear terms function of the coefficient α, which is not possible with the classical RsC model. We validate our formulae with the experimental measurements of different EDLCs.

  4. Ion size effects on the electric double layer of a spherical particle in a realistic salt-free concentrated suspension.

    Science.gov (United States)

    Roa, Rafael; Carrique, Félix; Ruiz-Reina, Emilio

    2011-05-28

    A new modified Poisson-Boltzmann equation accounting for the finite size of the ions valid for realistic salt-free concentrated suspensions has been derived, extending the formalism developed for pure salt-free suspensions [Roa et al., Phys. Chem. Chem. Phys., 2011, 13, 3960-3968] to real experimental conditions. These realistic suspensions include water dissociation ions and those generated by atmospheric carbon dioxide contamination, in addition to the added counterions released by the particles to the solution. The electric potential at the particle surface will be calculated for different ion sizes and compared with classical Poisson-Boltzmann predictions for point-like ions, as a function of particle charge and volume fraction. The realistic predictions turn out to be essential to achieve a closer picture of real salt-free suspensions, and even more important when ionic size effects are incorporated to the electric double layer description. We think that both corrections have to be taken into account when developing new realistic electrokinetic models, and surely will help in the comparison with experiments for low-salt or realistic salt-free systems. This journal is © the Owner Societies 2011

  5. Reduced-graphene-oxide-and-strontium-titanate-based double-layered composite: an efficient microwave-absorbing material

    Indian Academy of Sciences (India)

    SUKANTA DAS; S K SAHU; RAMESH ORAON; P C ROUTRAY; H BASKEY; G C NAYAK

    2017-04-01

    Microwave-absorbing materials based on reduced graphene oxide (r-GO)/ strontium titanate were prepared by embedding in epoxy matrix. R-GO and strontium titanate were synthesized and characterized before composite fabrication. Microstructures of the constituent elements were studied by scanning electron microscopy and X-ray diffraction (XRD). Microwave absorption capabilities of the composite absorbers were investigated using a Vector Network Analyser in the range 8–12 GHz. A maximum reflection loss of $−$7.5 and $−$16.4 dB was obtained at 9.3 and 12.08 GHz, respectively, for 2% (w/w) r-GO-loaded epoxy composites. A maximum attenuation of $−$12.8 dB at 9.3 GHz was obtained for the strontium titanate/epoxy composite. However, double-layer composite with r-GO/strontium titanate/epoxy composition showed the maximum reflection loss of $−$15.1 dB at 9.47 GHz and $−$9.65 dB at 12.3 GHz. All the results are discussed in terms of complex permeability and permittivity. The study revealed that intrinsic conductivity and polarization of the r-GO particles and dielectric polarization of the strontium titanate within epoxy matrix contribute to the microwave absorption.

  6. Magnetization-induced double-layer capacitance enhancement in active carbon/Fe3O4 nanocomposites

    Institute of Scientific and Technical Information of China (English)

    Guoxiang Wang; Hongfeng Xu; Lu Lu; Hong Zhao

    2014-01-01

    The effects of magnetic fields on electrochemical processes have made a great impact on both theoretical and practical significances in im-proving capacitor performance. In this study, active carbon/Fe3O4-NPs nanocomposites (AC/Fe3O4-NPs) were synthesized using a facile hy-drothermal method and ultrasonic technique. Transmission electron micrographs (TEM) showed that Fe3O4 nanoparticles (Fe3O4-NPs) grew along the edge of AC. AC/Fe3O4-NPs nanocomposites were further used as an electrochemical electrode, and its electrochemical performance was tested under magnetization and non-magnetization conditions, respectively, in a three-electrode electrochemical device. Micro-magnetic field could improve the electric double-layer capacitance, reduce the charge transfer resistance, and enhance the discharge performance. The capacitance enhancement of magnetized electrode was increased by 33.1%at the current density of 1 A/g, and the energy density was improved to 15.97 Wh/kg, due to the addition of magnetic particles.

  7. Reevaluation of Performance of Electric Double-layer Capacitors from Constant-current Charge/Discharge and Cyclic Voltammetry

    Science.gov (United States)

    Allagui, Anis; Freeborn, Todd J.; Elwakil, Ahmed S.; Maundy, Brent J.

    2016-12-01

    The electric characteristics of electric-double layer capacitors (EDLCs) are determined by their capacitance which is usually measured in the time domain from constant-current charging/discharging and cyclic voltammetry tests, and from the frequency domain using nonlinear least-squares fitting of spectral impedance. The time-voltage and current-voltage profiles from the first two techniques are commonly treated by assuming ideal SsC behavior in spite of the nonlinear response of the device, which in turn provides inaccurate values for its characteristic metrics. In this paper we revisit the calculation of capacitance, power and energy of EDLCs from the time domain constant-current step response and linear voltage waveform, under the assumption that the device behaves as an equivalent fractional-order circuit consisting of a resistance Rs in series with a constant phase element (CPE(Q, α), with Q being a pseudocapacitance and α a dispersion coefficient). In particular, we show with the derived (Rs, Q, α)-based expressions, that the corresponding nonlinear effects in voltage-time and current-voltage can be encompassed through nonlinear terms function of the coefficient α, which is not possible with the classical RsC model. We validate our formulae with the experimental measurements of different EDLCs.

  8. Synthesis of highly fluorescent silica nanoparticles in a reverse microemulsion through double-layered doping of organic fluorophores

    Energy Technology Data Exchange (ETDEWEB)

    Yoo, Hyojong, E-mail: hyojong@hallym.ac.kr; Pak, Joonsung [Hallym University, Department of Chemistry (Korea, Republic of)

    2013-05-15

    Water-soluble, highly fluorescent double-layered silica nanoparticles (FL-DLSN) have been successfully synthesized through a reverse (water-in-oil) microemulsion method. The microemulsion was prepared by mixing a surfactant (Brij35), co-surfactant, organic solvent, water, and fluorescein as an organic fluorophore. The sizes of the silica nanoparticles were successfully controlled in the reverse microemulsion using Brij35 by changing the water-to-Brij35 ratio and by adding HCl. Initially, tetraethylorthosilicate was hydrolyzed by adding NH{sub 4}OH as a catalyst and then polymerized to generate core fluorescent silica nanoparticles with fluorescein. 3-(Aminopropyl)triethoxysilane (APTS) was sequentially added into the reaction mixture, and reacted on the surface of pre-generated core silica nanoparticles to form the second layer in the form of a shell. The second silica layer that was derived from the condensation of APTS effectively protected the fluorescein dye within the silica matrix. This is a novel and simple synthetic approach to generate highly fluorescent, monodispersed silica nanoparticles by doping organic molecules into a silica matrix.Graphical Abstract.

  9. Poly(Acrylic acid–Based Hybrid Inorganic–Organic Electrolytes Membrane for Electrical Double Layer Capacitors Application

    Directory of Open Access Journals (Sweden)

    Chiam-Wen Liew

    2016-05-01

    Full Text Available Nanocomposite polymer electrolyte membranes (NCPEMs based on poly(acrylic acid(PAA and titania (TiO2 are prepared by a solution casting technique. The ionic conductivity of NCPEMs increases with the weight ratio of TiO2.The highest ionic conductivity of (8.36 ± 0.01 × 10−4 S·cm−1 is obtained with addition of 6 wt % of TiO2 at ambient temperature. The complexation between PAA, LiTFSI and TiO2 is discussed in Attenuated total reflectance-Fourier Transform Infrared (ATR-FTIR studies. Electrical double layer capacitors (EDLCs are fabricated using the filler-free polymer electrolyte or the most conducting NCPEM and carbon-based electrodes. The electrochemical performances of fabricated EDLCs are studied through cyclic voltammetry (CV and galvanostatic charge-discharge studies. EDLC comprising NCPEM shows the specific capacitance of 28.56 F·g−1 (or equivalent to 29.54 mF·cm−2 with excellent electrochemical stability.

  10. Preparation of hierarchical porous carbon from waste printed circuit boards for high performance electric double-layer capacitors

    Science.gov (United States)

    Du, Xuan; Wang, Li; Zhao, Wei; Wang, Yi; Qi, Tao; Li, Chang Ming

    2016-08-01

    Renewable clean energy and resources recycling have become inevitable choices to solve worldwide energy shortages and environmental pollution problems. It is a great challenge to recycle tons of waste printed circuit boards (PCB) produced every year for clean environment while creating values. In this work, low cost, high quality activated carbons (ACs) were synthesized from non-metallic fractions (NMF) of waste PCB to offer a great potential for applications of electrochemical double-layer capacitors (EDLCs). After recovering metal from waste PCB, hierarchical porous carbons were produced from NMF by carbonization and activation processes. The experimental results exhibit that some pores were formed after carbonization due to the escape of impurity atoms introduced by additives in NMF. Then the pore structure was further tailored by adjusting the activation parameters. Roles of micropores and non-micropores in charge storage were investigated when the hierarchical porous carbons were applied as electrode of EDLCs. The highest specific capacitance of 210 F g-1 (at 50 mA g-1) and excellent rate capability were achieved when the ACs possessing a proper micropores/non-micropores ratio. This work not only provides a promising method to recycle PCB, but also investigates the structure tailoring arts for a rational hierarchical porous structure in energy storage/conversion.

  11. High performance spectral-phase surface plasmon resonance biosensors based on single- and double-layer schemes

    Science.gov (United States)

    Wang, Cheng; Ho, Ho-Pui; Shum, Ping

    2013-03-01

    We have investigated the surface plasmon resonance (SPR) phase change across a range of excitation wavelengths (i.e. spectral-phase) using the Fresnel's equations and Transfer Matrix technique with emphasis on optimizing refractive index sensing performance. Having evaluated the phase change characteristics upon varying different sets of parameters, our results indicate the possibility of achieving extremely high resolution within a wide range of sample refractive index (1.3330-1.3505) at a fixed angle of incidence. We also demonstrate that the double-layer (silver/gold or copper/gold) configuration holds very promising characteristics for SPR sensing, and it is possible to achieve a detection limit of 7.9×10-9 RIU (refractive index unit) if one uses a phase measurement resolution of 2×10-4 rad. Among all the factors, material of the metal film and its thickness are found to affect performance most. This work provides a comprehensive analysis of the interplay between various system parameters.

  12. Impact of single- vs double-layer closure on adverse outcomes and uterine scar defect: a systematic review and metaanalysis.

    Science.gov (United States)

    Roberge, Stéphanie; Demers, Suzanne; Berghella, Vincenzo; Chaillet, Nils; Moore, Lynne; Bujold, Emmanuel

    2014-11-01

    A systematic review and metaanalysis were performed through electronic database searches to estimate the effect of uterine closure at cesarean on the risk of adverse maternal outcome and on uterine scar evaluated by ultrasound. Randomized controlled trials, which compared single vs double layers and locking vs unlocking sutures for uterine closure of low transverse cesarean, were included. Outcomes were short-term complications (endometritis, wound infection, maternal infectious morbidity, blood transfusion, duration of surgical procedure, length of hospital stay, mean blood loss), uterine rupture or dehiscence at next pregnancy, and uterine scar evaluation by ultrasound. Twenty of 1278 citations were included in the analysis. We found that all types of closure were comparable for short-term maternal outcomes, except for single-layer closure, which had shorter operative time (-6.1 minutes; 95% confidence interval [CI], -8.7 to -3.4; P type of uterine closure for optimal maternal outcomes and is insufficient to conclude about the risk of uterine rupture. Single-layer closure and locked first layer are possibly coupled with thinner residual myometrium thickness.

  13. Collisionless Electron-ion Shocks in Relativistic Unmagnetized Jet-ambient Interactions: Non-thermal Electron Injection by Double Layer

    Science.gov (United States)

    Ardaneh, Kazem; Cai, Dongsheng; Nishikawa, Ken-Ichi

    2016-08-01

    The course of non-thermal electron ejection in relativistic unmagnetized electron-ion shocks is investigated by performing self-consistent particle-in-cell simulations. The shocks are excited through the injection of a relativistic jet into ambient plasma, leading to two distinct shocks (referred to as the trailing shock and leading shock) and a contact discontinuity. The Weibel-like instabilities heat the electrons up to approximately half of the ion kinetic energy. The double layers formed in the trailing and leading edges then accelerate the electrons up to the ion kinetic energy. The electron distribution function in the leading edge shows a clear, non-thermal power-law tail which contains ˜1% of electrons and ˜8% of the electron energy. Its power-law index is -2.6. The acceleration efficiency is ˜23% by number and ˜50% by energy, and the power-law index is -1.8 for the electron distribution function in the trailing edge. The effect of the dimensionality is examined by comparing the results of three-dimensional simulations with those of two-dimensional simulations. The comparison demonstrates that electron acceleration is more efficient in two dimensions.

  14. Collisionless electron-ion shocks in relativistic unmagnetized jet-ambient interactions: Non-thermal electron injection by double layer

    CERN Document Server

    Ardaneh, Kazem; Nishikawa, Ken-Ichi

    2016-01-01

    The course of non-thermal electron ejection in relativistic unmagnetized electron-ion shocks is investigated by performing self-consistent particle-in-cell simulations. The shocks are excited through the injection of relativistic jet into ambient plasma, leading to two distinct shocks (named as the trailing shock and leading shock) and a contact discontinuity. The Weibel-like instabilities heat the electrons up to approximately half of ion kinetic energy. The double layers formed in the trailing and leading edges then accelerated the electrons by the ion kinetic energy. The electron distribution function in the leading edge shows a clear non-thermal power-law tail which contains $\\sim1\\%$ of electrons and $\\sim8\\%$ of electron energy. Its power-law index is -2.6. The acceleration efficiency is $\\sim23\\%$ by number and $\\sim50\\%$ by energy and the power-law index is -1.8 for electron distribution function in the trailing edge. The effect of the dimensionality is examined by comparing results of 3D simulation w...

  15. Structure of electric double layers in capacitive systems and to what extent (classical) density functional theory describes it

    Science.gov (United States)

    Härtel, Andreas

    2017-10-01

    Ongoing scientific interest is aimed at the properties and structure of electric double layers (EDLs), which are crucial for capacitive energy storage, water treatment, and energy harvesting technologies like supercapacitors, desalination devices, blue engines, and thermocapacitive heat-to-current converters. A promising tool to describe their physics on a microscopic level is (classical) density functional theory (DFT), which can be applied in order to analyze pair correlations and charge ordering in the primitive model of charged hard spheres. This simple model captures the main properties of ionic liquids and solutions and it predicts many of the phenomena that occur in EDLs. The latter often lead to anomalous response in the differential capacitance of EDLs. This work constructively reviews the powerful theoretical framework of DFT and its recent developments regarding the description of EDLs. It explains to what extent current approaches in DFT describe structural ordering and in-plane transitions in EDLs, which occur when the corresponding electrodes are charged. Further, the review briefly summarizes the history of modeling EDLs, presents applications, and points out limitations and strengths in present theoretical approaches. It concludes that DFT as a sophisticated microscopic theory for ionic systems is expecting a challenging but promising future in both fundamental research and applications in supercapacitive technologies.

  16. Insights into the effects of solvent properties in graphene based electric double-layer capacitors with organic electrolytes

    Science.gov (United States)

    Zhang, Shuo; Bo, Zheng; Yang, Huachao; Yang, Jinyuan; Duan, Liangping; Yan, Jianhua; Cen, Kefa

    2016-12-01

    Organic electrolytes are widely used in electric double-layer capacitors (EDLCs). In this work, the microstructure of planar graphene-based EDLCs with different organic solvents are investigated with molecular dynamics simulations. Results show that an increase of solvent polarity could weaken the accumulation of counter-ions nearby the electrode surface, due to the screen of electrode charges and relatively lower ionic desolvation. It thus suggests that solvents with low polarity could be preferable to yield high EDL capacitance. Meanwhile, the significant effects of the size and structure of solvent molecules are reflected by non-electrostatic molecule-electrode interactions, further influencing the adsorption of solvent molecules on electrode surface. Compared with dimethyl carbonate, γ-butyrolactone, and propylene carbonate, acetonitrile with relatively small-size and linear structure owns weak non-electrostatic interactions, which favors the easy re-orientation of solvent molecules. Moreover, the shift of solvent orientation in surface layer, from parallel orientation to perpendicular orientation relative to the electrode surface, deciphers the solvent twin-peak behavior near negative electrode. The as-obtained insights into the roles of solvent properties on the interplays among particles and electrodes elucidate the solvent influences on the microstructure and capacitive behavior of EDLCs using organic electrolytes.

  17. Homoclinic behaviors and chaotic motions of double layered viscoelastic nanoplates based on nonlocal theory and extended Melnikov method

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Yu; Wang, Yi-Ze [School of Astronautics, Harbin Institute of Technology, P. O. Box 137, Harbin 150001 (China); Li, Feng-Ming, E-mail: fmli@bjut.edu.cn [School of Astronautics, Harbin Institute of Technology, P. O. Box 137, Harbin 150001 (China); College of Mechanical Engineering, Beijing University of Technology, Beijing 100124 (China)

    2015-06-15

    The nonlinear dynamical equations are established for the double layered viscoelastic nanoplates (DLNP) subjected to in-plane excitation based on the nonlocal theory and von Kármán large deformation theory. The extended high dimensional homoclinic Melnikov method is employed to study the homoclinic phenomena and chaotic motions for the parametrically excited DLNP system. The criteria for the homoclinic transverse intersection for both the asynchronous and synchronous buckling cases are proposed. Lyapunov exponents and phase portraits are obtained to verify the Melnikov-type analysis. The influences of structural parameters on the transverse homoclinic orbits and homoclinic bifurcation sets are discussed for the two buckling cases. Some novel phenomena are observed in the investigation. It should be noticed that the nonlocal effect on the homoclinic behaviors and chaotic motions is quite remarkable. Hence, the small scale effect should be taken into account for homoclinic and chaotic analysis for nanostructures. It is significant that the nonlocal effect on the homoclinic phenomena for the asynchronous buckling case is quite different from that for the synchronous buckling case. Moreover, due to the van der Walls interaction between the layers, the nonlocal effect on the homoclinic behaviors and chaotic motions for high order mode is rather tiny under the asynchronous buckling condition.

  18. A Double-Layered Covered Biliary Metal Stent for the Management of Unresectable Malignant Biliary Obstruction: A Multicenter Feasibility Study

    Science.gov (United States)

    Park, Jin-Seok; Jeong, Seok; Lee, Don Haeng; Moon, Jong Ho; Lee, Kyu Taek; Dong, Seok Ho

    2016-01-01

    Background/Aims The covered self-expandable metal stent (CMS) was developed to prevent tumor ingrowth-induced stent occlusion during the treatment of malignant biliary obstruction. However, complications such as cholecystitis, pancreatitis, and stent migration can occur after the endoscopic insertion of CMSs. The aim of the present study was to assess the efficacy and safety of a double-layered CMS (DCMS) for the management of malignant bile duct obstruction. Methods DCMSs were endoscopically introduced into 59 patients with unresectable malignant extrahepatic biliary obstruction at four tertiary referral centers, and the patient medical records were retrospectively reviewed. Results Both the technical and functional success rates were 100%. Procedure-related complications including pancreatitis, cholangitis, stent migration, and liver abscess occurred in five patients (8.5%). The median follow-up period was 265 days (range, 31 to 752 days). Cumulative stent patency rates were 68.2% and 40.8% at 6 and 12 months, respectively. At the final follow-up, the rate of stent occlusion was 33.9% (20/59), and the median stent patency period was 276 days (range, 2 to 706 days). Conclusions The clinical outcomes of DCMSs were comparable to the outcomes previously reported for CMSs with respect to stent patency period and complication rates. PMID:27172927

  19. Introduction of electric double layer capacitors in the solar-EV; Solar denki jidosha eno denki nijuso condenser no oyo

    Energy Technology Data Exchange (ETDEWEB)

    Fujinaka, M. [Tokyo Denki University, Tokyo (Japan)

    1996-10-27

    A basic experiment was carried out on a supplementary power supply, in which solar cells and electric double layer capacitors(EDLC) were combined for a DC/DC converter, for the use of a solar-electric vehicle (S-EV); and in actuality, an S-EV was loaded with the power supply with a running test conducted on a public road. The EDLC was found effective and useful for avoiding temporary lowering of voltage and momentary break. An electric supply was thereby made possible for an emergency light without the use of the DC/DC converter. However, in a tunnel or a night driving and in case of failure of the DC/DC converter, an operating time of only 7 minutes or so was affordable with the EDLC having a capacity of 100F. Moreover, particularly with a heavy load, it was impossible to maintain a voltage for many hours. Under the circumstances, an S-EV design would primarily require two sets of independent DC/DC converter loaded in the future. The EDLC, young after it was developed, still has a small energy density compared with a lead storage battery. Yet, an EDLC with a higher performance being developed, there is a possibility that it will be applied to S-EV`s by utilizing its characteristics such as a high efficiency and a long service life. 4 refs., 8 figs.

  20. In situ NMR and electrochemical quartz crystal microbalance techniques reveal the structure of the electrical double layer in supercapacitors.

    Science.gov (United States)

    Griffin, John M; Forse, Alexander C; Tsai, Wan-Yu; Taberna, Pierre-Louis; Simon, Patrice; Grey, Clare P

    2015-08-01

    Supercapacitors store charge through the electrosorption of ions on microporous electrodes. Despite major efforts to understand this phenomenon, a molecular-level picture of the electrical double layer in working devices is still lacking as few techniques can selectively observe the ionic species at the electrode/electrolyte interface. Here, we use in situ NMR to directly quantify the populations of anionic and cationic species within a working microporous carbon supercapacitor electrode. Our results show that charge storage mechanisms are different for positively and negatively polarized electrodes for the electrolyte tetraethylphosphonium tetrafluoroborate in acetonitrile; for positive polarization charging proceeds by exchange of the cations for anions, whereas for negative polarization, cation adsorption dominates. In situ electrochemical quartz crystal microbalance measurements support the NMR results and indicate that adsorbed ions are only partially solvated. These results provide new molecular-level insight, with the methodology offering exciting possibilities for the study of pore/ion size, desolvation and other effects on charge storage in supercapacitors.