WorldWideScience

Sample records for iridium satellite network

  1. Network flexibility of the IRIDIUM (R) Global Mobile Satellite System

    Science.gov (United States)

    Hutcheson, Jonathan; Laurin, Mala

    1995-01-01

    The IRIDIUM system is a global personal communications system supported by a constellation of 66 low earth orbit (LEO) satellites and a collection of earth-based 'gateway' switching installations. Like traditional wireless cellular systems, coverage is achieved by a grid of cells in which bandwidth is reused for spectral efficiency. Unlike any cellular system ever built, the moving cells can be shared by multiple switching facilities. Noteworthy features of the IRIDIUM system include inter-satellite links, a GSM-based telephony architecture, and a geographically controlled system access process. These features, working in concert, permit flexible and reliable administration of the worldwide service area by gateway operators. This paper will explore this unique concept.

  2. Leveraging the NPS Femto Satellite for Alternative Satellite Communication Networks

    Science.gov (United States)

    2017-09-01

    programmed for eventual integration with the Iridium Network , which is then tested. C. THESIS ORGANIZATION The thesis addresses these questions...NPS FEMTO SATELLITE FOR ALTERNATIVE SATELLITE COMMUNICATION NETWORKS by Faisal S. Alshaya September 2017 Co-Advisors: Steven J. Iatrou...TYPE AND DATES COVERED Master’s thesis 4. TITLE AND SUBTITLE LEVERAGING THE NPS FEMTO SATELLITE FOR ALTERNATIVE SATELLITE COMMUNICATION NETWORKS 5

  3. Research of remote control for Chinese Antarctica Telescope based on iridium satellite communication

    Science.gov (United States)

    Xu, Lingzhe; Yang, Shihai

    2010-07-01

    Astronomers are ever dreaming of sites with best seeing on the Earth surface for celestial observation, and the Antarctica is one of a few such sites only left owing to the global air pollution. However, Antarctica region is largely unaccessible for human being due to lacking of fundamental living conditions, travel facilities and effective ways of communication. Worst of all, the popular internet source as a general way of communication scarcely exists there. Facing such a dilemma and as a solution remote control and data transmission for telescopes through iridium satellite communication has been put forward for the Chinese network Antarctic Schmidt Telescopes 3 (AST3), which is currently under all round research and development. This paper presents iridium satellite-based remote control application adapted to telescope control. The pioneer work in China involves hardware and software configuration utilizing techniques for reliable and secure communication, which is outlined in the paper too.

  4. 76 FR 46313 - Notice of Issuance of Final Determination Concerning Iridium Satellite Telephones

    Science.gov (United States)

    2011-08-02

    ... modulates them into radio streams that communicate with the Iridium gateway network infrastructure using a... (DSP) cores, made in China, and two radio frequency (RF) backend chips, made in Taiwan. The bill of... marking of a cellular phone. CBP found that a digital mobile telephone was substantially transformed in...

  5. Development of U.S. Government General Technical Requirements for UAS Flight Safety Systems Utilizing the Iridium Satellite Constellation

    Science.gov (United States)

    Murray, Jennifer; Birr, Richard

    2010-01-01

    This slide presentation reviews the development of technical requirements for Unmanned Aircraft Systems (UAS) utilization of the Iridium Satellite Constellation to provide flight safety. The Federal Aviation Authority (FAA) required an over-the-horizon communication standard to guarantee flight safety before permitting widespread UAS flights in the National Air Space (NAS). This is important to ensure reliable control of UASs during loss-link and over-the-horizon scenarios. The core requirement was to utilize a satellite system to send GPS tracking data and other telemetry from a flight vehicle down to the ground. Iridium was chosen as the system because it is one of the only true satellite systems that has world wide coverage, and the service has a highly reliable link margin. The Iridium system, the flight modems, and the test flight are described.

  6. Earth Radiation Imbalance from a Constellation of 66 Iridium Satellites: Technological Aspects

    Science.gov (United States)

    Wiscombe, W.; Chiu, C. J-Y.

    2012-01-01

    Iridium Communications Inc. is launching a new generation of polar orbiting communication satellites in 2015-2017. Iridium will provide a hosted payload bay on each of the 66 satellites (plus 6 in-space spares). This offers the potential for a paradigm shift in the way we measure Earth radiation imbalance from space, as well as massive cost savings. Because the constellation provides 24/7 global coverage, there is no need to account for diurnal cycle via extrapolations from uncalibrated narrowband geostationary imagers. And the spares can be rolled over to view the Sun and deep space, then transfer their calibration to the other members of the constellation during the frequent cross-overs. In part using simulations of the constellation viewing realistic Earth scenes, this presentation will address the technological aspects of such a constellation: (1) the calibration strategy; (2) the highly-accurate and stable radiometers for measuring outgoing flux; and (3) the GRACE-inspired algorithms for representing the outgoing flux field in spherical harmonics and thus achieving rv500-km spatial resolution and two-hour temporal resolution.

  7. Congestion control and routing over satellite networks

    Science.gov (United States)

    Cao, Jinhua

    ) method and then develop a novel on-demand routing system named Cross Entropy Accelerated Ant Routing System (CEAARS) for regular constellation LEO satellite networks. By implementing simulations on an Iridium-like satellite network, we compare the proposed CEAARS algorithm with the two approaches to adaptive routing protocols on the Internet: distance-vector (DV) and link-state (LS), as well as with the original Cross Entropy Ant Routing System (CEARS). DV algorithms are based on distributed Bellman Ford algorithm, and LS algorithms are implementation of Dijkstras single source shortest path. The results show that CEAARS not only remarkably improves the convergence speed of achieving optimal or suboptimal paths, but also reduces the number of overhead ants (management packets).

  8. Earth Radiation Imbalance from a Constellation of 66 Iridium Satellites: Climate Science Aspects

    Science.gov (United States)

    Wiscombe, W.; Chiu, CJ. Y.

    2012-01-01

    The "global warming hiatus" since the 1998 El Nino, highlighted by Meehl et al., and the resulting "missing energy" problem highlighted by Trenberth et al., has opened the door to a more fundamental view of climate change than mere surface air temperature. That new view is based on two variables which are strongly correlated: the rate of change of ocean heat content d(OHC)/dt; and Earth Radiation Imbalance (ERI) at the top of the atmosphere, whose guesstimated range is 0.4 to 0.9 Watts per square meters (this imbalance being mainly due to increasing CO2). The Argo float array is making better and better measurements of OHC. But existing satellite systems cannot measure ERI to even one significant digit. So, climate model predictions of ERI are used in place of real measurements of it, and the satellite data are tuned to the climate model predictions. Some oceanographers say "just depend on Argo for understanding the global warming hiatus and the missing energy", but we don't think this is a good idea because d(OHC)/dt and ERI have different time scales and are never perfectly correlated. We think the ERB community needs to step up to measuring ERI correctly, just as oceanographers have deployed Argo to measure OHC correctly. This talk will overview a proposed constellation of 66 Earth radiation budget instruments, hosted on Iridium satellites, that will actually be able to measure ERI to at least one significant digit, thus enabling a crucial test of climate models. This constellation will also be able to provide ERI at two-hourly time scales and 500-km spatial scales without extrapolations from uncalibrated narrowband geostationary instruments, using the highly successful methods of GRACE to obtain spatial resolution. This high time resolution would make ERI a synoptic variable like temperature, and allow studies of ERI's response to fast-evolving phenomena like dust storms and hurricanes and even brief excursions of Total Solar Irradiance. Time permitting, we

  9. Reversible switching of the sol- gel transition with ultrasound in rhodium(I) and iridium(I) coordination networks

    NARCIS (Netherlands)

    Paulusse, J.M.J.; Beek, van D.J.M.; Sijbesma, R.P.

    2007-01-01

    Reversible coordination networks were prepared by combining diphenylphosphinite telechelic polytetrahydrofuran (2) with [RhCl(COD)]2 or [IrCl(COD)]2 in chloroform. Both systems resulted in stable gels at concentrations above 50 and 30 g/L for the rhodium(I) and iridium(I) networks, respectively. The

  10. Mobility management in satellite networks

    Science.gov (United States)

    Johanson, Gary A.

    1995-01-01

    This paper addresses the methods used or proposed for use in multi-beam and/or multi-satellite networks designed to provide Mobile Satellite Services (MSS). Specific topics include beam crossover in the North American Mobile Satellite (MSAT) system as well as registration and live call hand-off for a multi-regional geosynchronous (GEO) satellite based system and a global coverage Low Earth Orbiting (LEO) system. In the MSAT system, the individual satellite beams cover very large geographic areas so the need for live call hand-off was not anticipated. This paper discusses the methods used to keep track of the beam location of the users so that incoming call announcements or other messages may be directed to them. Proposed new GEO systems with large numbers of beams will provide much smaller geographic coverage in individual beams and thus the need arises to keep track of the user's location as well as to provide live call hand-off as the user traverses from beam to beam. This situation also occurs in proposed LEO systems where the problems are worsened by the need for satellite to satellite hand-off as well as beam to beam hand-off within a single satellite. The paper discusses methods to accomplish these handoffs and proposes system architectures to address the various hand-off scenarios.

  11. Next generation satellite communications networks

    Science.gov (United States)

    Garland, P. J.; Osborne, F. J.; Streibl, I.

    The paper introduces two potential uses for new space hardware to permit enhanced levels of signal handling and switching in satellite communication service for Canada. One application involves increased private-sector services in the Ku band; the second supports new personal/mobile services by employing higher levels of handling and switching in the Ka band. First-generation satellite regeneration and switching experiments involving the NASA/ACTS spacecraft are described, where the Ka band and switching satellite network problems are emphasized. Second-generation satellite development is outlined based on demand trends for more packet-based switching, low-cost earth stations, and closed user groups. A demonstration mission for new Ka- and Ku-band technologies is proposed, including the payload configuration. The half ANIK E payload is shown to meet the demonstration objectives, and projected to maintain a fully operational payload for at least 10 years.

  12. ERROR-CONTROL CODING OF ADS-B MESSAGES FOR IRIDIUM SATELLITES

    Directory of Open Access Journals (Sweden)

    Volodymyr Kharchenko

    2013-12-01

    Full Text Available For modelling of ADS-B messages transmitting on the base of low-orbit satellite constellation Іrіdіum the model of a communication channel “Aircraft - Satellite - Ground Station” was built using MATLAB Sіmulіnk. This model allowed to investigate dependences of the Bit Error Rate on a type of  signal coding/decoding, ratio Eb/N0 and satellite repeater gain

  13. Gigabit Satellite Network for NASA's Advanced Communication Technology Satellite (ACTS)

    Science.gov (United States)

    Hoder, Douglas; Bergamo, Marcos

    1996-01-01

    The advanced communication technology satellite (ACTS) gigabit satellite network provides long-haul point-to-point and point-to-multipoint full-duplex SONET services over NASA's ACTS. at rates up to 622 Mbit/s (SONET OC-12), with signal quality comparable to that obtained with terrestrial fiber networks. Data multiplexing over the satellite is accomplished using time-division multiple access (TDMA) techniques coordinated with the switching and beam hopping facilities provided by ACTS. Transmissions through the satellite are protected with Reed-Solomon encoding. providing virtually error-free transmission under most weather conditions. Unique to the system are a TDMA frame structure and satellite synchronization mechanism that allow: (a) very efficient utilization of the satellite capacity: (b) over-the-satellite dosed-loop synchronization of the network in configurations with up to 64 ground stations: and (c) ground station initial acquisition without collisions with existing signalling or data traffic. The user interfaces are compatible with SONET standards, performing the function of conventional SONET multiplexers and. as such. can be: readily integrated with standard SONET fiber-based terrestrial networks. Management of the network is based upon the simple network management protocol (SNMP). and includes an over-the-satellite signalling network and backup terrestrial internet (IP-based) connectivity. A description of the ground stations is also included.

  14. Satellite communications network design and analysis

    CERN Document Server

    Jo, Kenneth Y

    2011-01-01

    This authoritative book provides a thorough understanding of the fundamental concepts of satellite communications (SATCOM) network design and performance assessments. You find discussions on a wide class of SATCOM networks using satellites as core components, as well as coverage key applications in the field. This in-depth resource presents a broad range of critical topics, from geosynchronous Earth orbiting (GEO) satellites and direct broadcast satellite systems, to low Earth orbiting (LEO) satellites, radio standards and protocols.This invaluable reference explains the many specific uses of

  15. Satellite Collision Modeling with Physics-Based Hydrocodes: Debris Generation Predictions of the Iridium-Cosmos Collision Event and Other Impact Events

    International Nuclear Information System (INIS)

    Springer, H.K.; Miller, W.O.; Levatin, J.L.; Pertica, A.J.; Olivier, S.S.

    2010-01-01

    Satellite collision debris poses risks to existing space assets and future space missions. Predictive models of debris generated from these hypervelocity collisions are critical for developing accurate space situational awareness tools and effective mitigation strategies. Hypervelocity collisions involve complex phenomenon that spans several time- and length-scales. We have developed a satellite collision debris modeling approach consisting of a Lagrangian hydrocode enriched with smooth particle hydrodynamics (SPH), advanced material failure models, detailed satellite mesh models, and massively parallel computers. These computational studies enable us to investigate the influence of satellite center-of-mass (CM) overlap and orientation, relative velocity, and material composition on the size, velocity, and material type distributions of collision debris. We have applied our debris modeling capability to the recent Iridium 33-Cosmos 2251 collision event. While the relative velocity was well understood in this event, the degree of satellite CM overlap and orientation was ill-defined. In our simulations, we varied the collision CM overlap and orientation of the satellites from nearly maximum overlap to partial overlap on the outermost extents of the satellites (i.e, solar panels and gravity boom). As expected, we found that with increased satellite overlap, the overall debris cloud mass and momentum (transfer) increases, the average debris size decreases, and the debris velocity increases. The largest predicted debris can also provide insight into which satellite components were further removed from the impact location. A significant fraction of the momentum transfer is imparted to the smallest debris (< 1-5mm, dependent on mesh resolution), especially in large CM overlap simulations. While the inclusion of the smallest debris is critical to enforcing mass and momentum conservation in hydrocode simulations, there seems to be relatively little interest in their

  16. Optical burst switching based satellite backbone network

    Science.gov (United States)

    Li, Tingting; Guo, Hongxiang; Wang, Cen; Wu, Jian

    2018-02-01

    We propose a novel time slot based optical burst switching (OBS) architecture for GEO/LEO based satellite backbone network. This architecture can provide high speed data transmission rate and high switching capacity . Furthermore, we design the control plane of this optical satellite backbone network. The software defined network (SDN) and network slice (NS) technologies are introduced. Under the properly designed control mechanism, this backbone network is flexible to support various services with diverse transmission requirements. Additionally, the LEO access and handoff management in this network is also discussed.

  17. Satellite ATM Networks: Architectures and Guidelines Developed

    Science.gov (United States)

    vonDeak, Thomas C.; Yegendu, Ferit

    1999-01-01

    An important element of satellite-supported asynchronous transfer mode (ATM) networking will involve support for the routing and rerouting of active connections. Work published under the auspices of the Telecommunications Industry Association (http://www.tiaonline.org), describes basic architectures and routing protocol issues for satellite ATM (SATATM) networks. The architectures and issues identified will serve as a basis for further development of technical specifications for these SATATM networks. Three ATM network architectures for bent pipe satellites and three ATM network architectures for satellites with onboard ATM switches were developed. The architectures differ from one another in terms of required level of mobility, supported data rates, supported terrestrial interfaces, and onboard processing and switching requirements. The documentation addresses low-, middle-, and geosynchronous-Earth-orbit satellite configurations. The satellite environment may require real-time routing to support the mobility of end devices and nodes of the ATM network itself. This requires the network to be able to reroute active circuits in real time. In addition to supporting mobility, rerouting can also be used to (1) optimize network routing, (2) respond to changing quality-of-service requirements, and (3) provide a fault tolerance mechanism. Traffic management and control functions are necessary in ATM to ensure that the quality-of-service requirements associated with each connection are not violated and also to provide flow and congestion control functions. Functions related to traffic management were identified and described. Most of these traffic management functions will be supported by on-ground ATM switches, but in a hybrid terrestrial-satellite ATM network, some of the traffic management functions may have to be supported by the onboard satellite ATM switch. Future work is planned to examine the tradeoffs of placing traffic management functions onboard a satellite as

  18. Leo satellite-based telecommunication network concepts

    Science.gov (United States)

    Aiken, John G.; Swan, Peter A.; Leopold, Ray J.

    1991-01-01

    Design considerations are discussed for Low Earth Orbit (LEO) satellite based telecommunications networks. The satellites are assumed to be connected to each other via intersatellite links. They are connected to the end user either directly or through gateways to other networks. Frequency reuse, circuit switching, packet switching, call handoff, and routing for these systems are discussed by analogy with terrestrial cellular (mobile radio) telecommunication systems.

  19. An access alternative for mobile satellite networks

    Science.gov (United States)

    Wu, W. W.

    1988-01-01

    Conceptually, this paper discusses strategies of digital satellite communication networks for a very large number of low density traffic stations. These stations can be either aeronautical, land mobile, or maritime. The techniques can be applied to international, domestic, regional, and special purpose satellite networks. The applications can be commercial, scientific, military, emergency, navigational or educational. The key strategy is the use of a non-orthogonal access method, which tolerates overlapping signals. With n being either time or frequency partitions, and with a single overlapping signal allowed, a low cost mobile satellite system can be designed with n squared (n squared + n + 1) number of terminals.

  20. Using satellite communications for a mobile computer network

    Science.gov (United States)

    Wyman, Douglas J.

    1993-01-01

    The topics discussed include the following: patrol car automation, mobile computer network, network requirements, network design overview, MCN mobile network software, MCN hub operation, mobile satellite software, hub satellite software, the benefits of patrol car automation, the benefits of satellite mobile computing, and national law enforcement satellite.

  1. A research on the application of software defined networking in satellite network architecture

    Science.gov (United States)

    Song, Huan; Chen, Jinqiang; Cao, Suzhi; Cui, Dandan; Li, Tong; Su, Yuxing

    2017-10-01

    Software defined network is a new type of network architecture, which decouples control plane and data plane of traditional network, has the feature of flexible configurations and is a direction of the next generation terrestrial Internet development. Satellite network is an important part of the space-ground integrated information network, while the traditional satellite network has the disadvantages of difficult network topology maintenance and slow configuration. The application of SDN technology in satellite network can solve these problems that traditional satellite network faces. At present, the research on the application of SDN technology in satellite network is still in the stage of preliminary study. In this paper, we start with introducing the SDN technology and satellite network architecture. Then we mainly introduce software defined satellite network architecture, as well as the comparison of different software defined satellite network architecture and satellite network virtualization. Finally, the present research status and development trend of SDN technology in satellite network are analyzed.

  2. Interim Service ISDN Satellite (ISIS) network model for advanced satellite designs and experiments

    Science.gov (United States)

    Pepin, Gerard R.; Hager, E. Paul

    1991-01-01

    The Interim Service Integrated Services Digital Network (ISDN) Satellite (ISIS) Network Model for Advanced Satellite Designs and Experiments describes a model suitable for discrete event simulations. A top-down model design uses the Advanced Communications Technology Satellite (ACTS) as its basis. The ISDN modeling abstractions are added to permit the determination and performance for the NASA Satellite Communications Research (SCAR) Program.

  3. Ground test of satellite constellation based quantum communication

    OpenAIRE

    Liao, Sheng-Kai; Yong, Hai-Lin; Liu, Chang; Shentu, Guo-Liang; Li, Dong-Dong; Lin, Jin; Dai, Hui; Zhao, Shuang-Qiang; Li, Bo; Guan, Jian-Yu; Chen, Wei; Gong, Yun-Hong; Li, Yang; Lin, Ze-Hong; Pan, Ge-Sheng

    2016-01-01

    Satellite based quantum communication has been proven as a feasible way to achieve global scale quantum communication network. Very recently, a low-Earth-orbit (LEO) satellite has been launched for this purpose. However, with a single satellite, it takes an inefficient 3-day period to provide the worldwide connectivity. On the other hand, similar to how the Iridium system functions in classic communication, satellite constellation (SC) composed of many quantum satellites, could provide global...

  4. Network Configuration Analysis for Formation Flying Satellites

    Science.gov (United States)

    Knoblock, Eric J.; Wallett, Thomas M.; Konangi, Vijay K.; Bhasin, Kul B.

    2001-01-01

    The performance of two networks to support autonomous multi-spacecraft formation flying systems is presented. Both systems are comprised of a ten-satellite formation, with one of the satellites designated as the central or 'mother ship.' All data is routed through the mother ship to the terrestrial network. The first system uses a TCP/EP over ATM protocol architecture within the formation, and the second system uses the IEEE 802.11 protocol architecture within the formation. The simulations consist of file transfers using either the File Transfer Protocol (FTP) or the Simple Automatic File Exchange (SAFE) Protocol. The results compare the IP queuing delay, IP queue size and IP processing delay at the mother ship as well as end-to-end delay for both systems. In all cases, using IEEE 802.11 within the formation yields less delay. Also, the throughput exhibited by SAFE is better than FTP.

  5. Satellite-Relayed Intercontinental Quantum Network

    Science.gov (United States)

    Liao, Sheng-Kai; Cai, Wen-Qi; Handsteiner, Johannes; Liu, Bo; Yin, Juan; Zhang, Liang; Rauch, Dominik; Fink, Matthias; Ren, Ji-Gang; Liu, Wei-Yue; Li, Yang; Shen, Qi; Cao, Yuan; Li, Feng-Zhi; Wang, Jian-Feng; Huang, Yong-Mei; Deng, Lei; Xi, Tao; Ma, Lu; Hu, Tai; Li, Li; Liu, Nai-Le; Koidl, Franz; Wang, Peiyuan; Chen, Yu-Ao; Wang, Xiang-Bin; Steindorfer, Michael; Kirchner, Georg; Lu, Chao-Yang; Shu, Rong; Ursin, Rupert; Scheidl, Thomas; Peng, Cheng-Zhi; Wang, Jian-Yu; Zeilinger, Anton; Pan, Jian-Wei

    2018-01-01

    We perform decoy-state quantum key distribution between a low-Earth-orbit satellite and multiple ground stations located in Xinglong, Nanshan, and Graz, which establish satellite-to-ground secure keys with ˜kHz rate per passage of the satellite Micius over a ground station. The satellite thus establishes a secure key between itself and, say, Xinglong, and another key between itself and, say, Graz. Then, upon request from the ground command, Micius acts as a trusted relay. It performs bitwise exclusive or operations between the two keys and relays the result to one of the ground stations. That way, a secret key is created between China and Europe at locations separated by 7600 km on Earth. These keys are then used for intercontinental quantum-secured communication. This was, on the one hand, the transmission of images in a one-time pad configuration from China to Austria as well as from Austria to China. Also, a video conference was performed between the Austrian Academy of Sciences and the Chinese Academy of Sciences, which also included a 280 km optical ground connection between Xinglong and Beijing. Our work clearly confirms the Micius satellite as a robust platform for quantum key distribution with different ground stations on Earth, and points towards an efficient solution for an ultralong-distance global quantum network.

  6. Satellite-Relayed Intercontinental Quantum Network.

    Science.gov (United States)

    Liao, Sheng-Kai; Cai, Wen-Qi; Handsteiner, Johannes; Liu, Bo; Yin, Juan; Zhang, Liang; Rauch, Dominik; Fink, Matthias; Ren, Ji-Gang; Liu, Wei-Yue; Li, Yang; Shen, Qi; Cao, Yuan; Li, Feng-Zhi; Wang, Jian-Feng; Huang, Yong-Mei; Deng, Lei; Xi, Tao; Ma, Lu; Hu, Tai; Li, Li; Liu, Nai-Le; Koidl, Franz; Wang, Peiyuan; Chen, Yu-Ao; Wang, Xiang-Bin; Steindorfer, Michael; Kirchner, Georg; Lu, Chao-Yang; Shu, Rong; Ursin, Rupert; Scheidl, Thomas; Peng, Cheng-Zhi; Wang, Jian-Yu; Zeilinger, Anton; Pan, Jian-Wei

    2018-01-19

    We perform decoy-state quantum key distribution between a low-Earth-orbit satellite and multiple ground stations located in Xinglong, Nanshan, and Graz, which establish satellite-to-ground secure keys with ∼kHz rate per passage of the satellite Micius over a ground station. The satellite thus establishes a secure key between itself and, say, Xinglong, and another key between itself and, say, Graz. Then, upon request from the ground command, Micius acts as a trusted relay. It performs bitwise exclusive or operations between the two keys and relays the result to one of the ground stations. That way, a secret key is created between China and Europe at locations separated by 7600 km on Earth. These keys are then used for intercontinental quantum-secured communication. This was, on the one hand, the transmission of images in a one-time pad configuration from China to Austria as well as from Austria to China. Also, a video conference was performed between the Austrian Academy of Sciences and the Chinese Academy of Sciences, which also included a 280 km optical ground connection between Xinglong and Beijing. Our work clearly confirms the Micius satellite as a robust platform for quantum key distribution with different ground stations on Earth, and points towards an efficient solution for an ultralong-distance global quantum network.

  7. Networks for Autonomous Formation Flying Satellite Systems

    Science.gov (United States)

    Knoblock, Eric J.; Konangi, Vijay K.; Wallett, Thomas M.; Bhasin, Kul B.

    2001-01-01

    The performance of three communications networks to support autonomous multi-spacecraft formation flying systems is presented. All systems are comprised of a ten-satellite formation arranged in a star topology, with one of the satellites designated as the central or "mother ship." All data is routed through the mother ship to the terrestrial network. The first system uses a TCP/lP over ATM protocol architecture within the formation the second system uses the IEEE 802.11 protocol architecture within the formation and the last system uses both of the previous architectures with a constellation of geosynchronous satellites serving as an intermediate point-of-contact between the formation and the terrestrial network. The simulations consist of file transfers using either the File Transfer Protocol (FTP) or the Simple Automatic File Exchange (SAFE) Protocol. The results compare the IF queuing delay, and IP processing delay at the mother ship as well as application-level round-trip time for both systems, In all cases, using IEEE 802.11 within the formation yields less delay. Also, the throughput exhibited by SAFE is better than FTP.

  8. MODELING OF ADS-B MESSAGES TRANSMISSION THROUGH SATELLITE TELECOMMUNICATION CHANNEL IRIDIUM USING NETCRACKER PROFESSIONAL 4.1

    Directory of Open Access Journals (Sweden)

    В. Харченко

    2012-04-01

    Full Text Available The model for the traffic analysis in a communication channel "aircraft - satellite - ground station" wasbuilt and used for modeling of transfer ADS-B messages with the help low-orbit satellite complex Іrіdіum.Dependences of factor BER on channel average working load and average utilization time were obtained.Dependences of package failure probabilities on average working load, average utilization time and signaltraveling time were analyzed. The developed model was applied for determination of traffic characteristics ina communication channel "aircraft - satellite - ground station": the dependence of average working load,average channel utilization time and message traveling time on the size of transaction, the dependence oftravelling time on channel delay time were built.

  9. Interworking evolution of mobile satellite and terrestrial networks

    Science.gov (United States)

    Matyas, R.; Kelleher, P.; Moller, P.; Jones, T.

    1993-01-01

    There is considerable interest among mobile satellite service providers in interworking with terrestrial networks to provide a universal global network. With such interworking, subscribers may be provided a common set of services such as those planned for the Public Switched Telephone Network (PSTN), the Integrated Services Digital Network (ISDN), and future Intelligent Networks (IN's). This paper first reviews issues in satellite interworking. Next the status and interworking plans of terrestrial mobile communications service providers are examined with early examples of mobile satellite interworking including a discussion of the anticipated evolution towards full interworking between mobile satellite and both fixed and mobile terrestrial networks.

  10. LTE Adaptation for Mobile Broadband Satellite Networks

    Directory of Open Access Journals (Sweden)

    Bastia Francesco

    2009-01-01

    Full Text Available One of the key factors for the successful deployment of mobile satellite systems in 4G networks is the maximization of the technology commonalities with the terrestrial systems. An effective way of achieving this objective consists in considering the terrestrial radio interface as the baseline for the satellite radio interface. Since the 3GPP Long Term Evolution (LTE standard will be one of the main players in the 4G scenario, along with other emerging technologies, such as mobile WiMAX; this paper analyzes the possible applicability of the 3GPP LTE interface to satellite transmission, presenting several enabling techniques for this adaptation. In particular, we propose the introduction of an inter-TTI interleaving technique that exploits the existing H-ARQ facilities provided by the LTE physical layer, the use of PAPR reduction techniques to increase the resilience of the OFDM waveform to non linear distortion, and the design of the sequences for Random Access, taking into account the requirements deriving from the large round trip times. The outcomes of this analysis show that, with the required proposed enablers, it is possible to reuse the existing terrestrial air interface to transmit over the satellite link.

  11. Full Service ISDN Satellite (FSIS) network model for advanced ISDN satellite design and experiments

    Science.gov (United States)

    Pepin, Gerard R.

    1992-01-01

    The Full Service Integrated Services Digital Network (FSIS) network model for advanced satellite designs describes a model suitable for discrete event simulations. A top down model design uses the Advanced Communications Technology Satellite (ACTS) as its basis. The ACTS and the Interim Service ISDN Satellite (ISIS) perform ISDN protocol analyses and switching decisions in the terrestrial domain, whereas FSIS makes all its analyses and decisions on-board the ISDN satellite.

  12. A demand assignment control in international business satellite communications network

    Science.gov (United States)

    Nohara, Mitsuo; Takeuchi, Yoshio; Takahata, Fumio; Hirata, Yasuo

    An experimental system is being developed for use in an international business satellite (IBS) communications network based on demand-assignment (DA) and TDMA techniques. This paper discusses its system design, in particular from the viewpoints of a network configuration, a DA control, and a satellite channel-assignment algorithm. A satellite channel configuration is also presented along with a tradeoff study on transmission rate, HPA output power, satellite resource efficiency, service quality, and so on.

  13. Satellite communications for the next generation telecommunication services and networks

    Science.gov (United States)

    Chitre, D. M.

    1991-01-01

    Satellite communications can play an important role in provisioning the next-generation telecommunication services and networks, provided the protocols specifying these services and networks are satellite-compatible and the satellite subnetworks, consisting of earth stations interconnected by the processor and the switch on board the satellite, interwork effectively with the terrestrial networks. The specific parameters and procedures of frame relay and broadband integrated services digital network (B-ISDN) protocols which are impacted by a satellite delay. Congestion and resource management functions for frame relay and B-ISDN are discussed in detail, describing the division of these functions between earth stations and on board the satellite. Specific onboard and ground functions are identified as potential candidates for their implementation via neural network technology.

  14. A network architecture for International Business Satellite communications

    Science.gov (United States)

    Takahata, Fumio; Nohara, Mitsuo; Takeuchi, Yoshio

    Demand Assignment (DA) control is expected to be introduced in the International Business Satellte communications (IBS) network in order to cope with a growing international business traffic. The paper discusses the DA/IBS network from the viewpoints of network configuration, satellite channel configuration and DA control. The network configuration proposed here consists of one Central Station with network management function and several Network Coordination Stations with user management function. A satellite channel configuration is also presented along with a tradeoff study on transmission bit rate, high power amplifier output power requirement, and service quality. The DA control flow and protocol based on CCITT Signalling System No. 7 are also proposed.

  15. Screening the collision risk of the Iridium 33 - Cosmos 2251 Clouds

    OpenAIRE

    Rossi, Alessandro; Valsecchi, Giovanni Battista

    2011-01-01

    More than 10 years ago, in Rossi, Valsecchi and Farinella (Nature, 1999), it was shown how a near polar multi-plane constellation such as Iridium is particularly at risk of a collisional cascade if one of its satellites is first accidentally fragmented. Those results are recalled and actualized in the light of the real collision of February 2009, between Iridium 33 and Cosmos 2251. The collision risk, for the remaining Iridium satellites, arising from the two clouds of fragments generated by ...

  16. Iridium: Global OTH data communications for high altitude scientific ballooning

    Science.gov (United States)

    Denney, A.

    beneficial points provided by the Iridium platform include pure global accessibility (as well as polar), cost effectiveness because it is available as a COTS (Commercially Off The Shelf) technology, reliability in that the equipment must operate in extreme conditions (near space), integration and development time into current systems must be minimized. As a bonus Motorola and NAL Research Corporation are developing SBD (Short Burst Data) into the Iridium network. This may lead the way to a global IP (Internet Protocol) node based ballooning platform. The Iridium satellite data modems employ the Iridium Low-Earth Orbit (LEO) satellite network. The scope of this paper is to introduce an OTH communications alternative, albeit not necessarily a primary one, to existing ballooning platforms using COTS based emerging technologies. Design aspects, characteristics, actual flight testing statistics, principles of the Iridium modems and communication paths are described including payload and support instrumentation interfacing. Not limited to high altitude ballooning, the Iridium communications platform opens a new era in remote commanding and data retrieval.

  17. Optical Multiple Access Network (OMAN) for advanced processing satellite applications

    Science.gov (United States)

    Mendez, Antonio J.; Gagliardi, Robert M.; Park, Eugene; Ivancic, William D.; Sherman, Bradley D.

    1991-01-01

    An OMAN breadboard for exploring advanced processing satellite circuit switch applications is introduced. Network architecture, hardware trade offs, and multiple user interference issues are presented. The breadboard test set up and experimental results are discussed.

  18. A Mobile Satellite Experiment (MSAT-X) network definition

    Science.gov (United States)

    Wang, Charles C.; Yan, Tsun-Yee

    1990-01-01

    The network architecture development of the Mobile Satellite Experiment (MSAT-X) project for the past few years is described. The results and findings of the network research activities carried out under the MSAT-X project are summarized. A framework is presented upon which the Mobile Satellite Systems (MSSs) operator can design a commercial network. A sample network configuration and its capability are also included under the projected scenario. The Communication Interconnection aspect of the MSAT-X network is discussed. In the MSAT-X network structure two basic protocols are presented: the channel access protocol, and the link connection protocol. The error-control techniques used in the MSAT-X project and the packet structure are also discussed. A description of two testbeds developed for experimentally simulating the channel access protocol and link control protocol, respectively, is presented. A sample network configuration and some future network activities of the MSAT-X project are also presented.

  19. The 30/20 GHz communications satellite trunking network study

    Science.gov (United States)

    Kolb, W.

    1981-01-01

    Alternative transmission media for a CONUS-wide trunking network in the years 1990 and 2000 are examined. The alternative technologies comprised fiber optic cable, conventional C- and Ku-band satellites, and 30/20 GHz satellites. Three levels of implementation were considered - a 10-city network, a 20-city network, and a 40-city network. The cities selected were the major metropolitan areas with the greatest communications demand. All intercity voice, data, and video traffic carried more than 40 miles was included in the analysis. In the optimized network, traffic transmitted less than 500 miles was found to be better served by fiber optic cable in 1990. By the year 2000, the crossover point would be down to 200 miles, assuming availability of 30/20 GHz satellites.

  20. Research of the key technology in satellite communication networks

    Science.gov (United States)

    Zeng, Yuan

    2018-02-01

    According to the prediction, in the next 10 years the wireless data traffic will be increased by 500-1000 times. Not only the wireless data traffic will be increased exponentially, and the demand for diversified traffic will be increased. Higher requirements for future mobile wireless communication system had brought huge market space for satellite communication system. At the same time, the space information networks had been greatly developed with the depth of human exploration of space activities, the development of space application, the expansion of military and civilian application. The core of spatial information networks is the satellite communication. The dissertation presented the communication system architecture, the communication protocol, the routing strategy, switch scheduling algorithm and the handoff strategy based on the satellite communication system. We built the simulation platform of the LEO satellites networks and simulated the key technology using OPNET.

  1. An Analysis of the FY-1C, Iridium 33, and Cosmos 2251 Fragments

    Science.gov (United States)

    Liou, J.-C.

    2014-01-01

    The beginning of the year 2013 marks the sixth anniversary of the destruction of the Fengyun-1C (FY-1C) weather satellite as the result of an anti-satellite test conducted by China in January 2007 and the fourth anniversary of the accidental collision between Cosmos 2251 and the operational Iridium 33 in February 2009. These two events represent the worst satellite breakups in history. A total of 5579 fragments have been cataloged by the U.S. Space Surveillance Network (SSN), and almost 5000 of them were still in orbit in January 2013. In addition to these cataloged objects, hundreds of thousands (or more) of fragments down to the millimeter size regime were also generated during the breakups. These fragments are too small to be tracked by the SSN, but are large enough to be a safety concern for human space activities and robotic missions in low Earth orbit (LEO, the region below 2000 km altitude). Like their cataloged siblings, many of them remain in orbit today. These two breakup events dramatically changed the landscape of the orbital debris environment in LEO. The spatial density of the cataloged population in January 2013 is shown as the top blue curve. The combined FY-1C, Iridium 33, and Cosmos 2251 fragments (black curve) account for about 50 percent of the cataloged population below an altitude of 1000 km. They are also responsible for the concentrations at 770 km and 850 km, altitudes at which the collisions occurred. The effects of the FY-1C, Iridium 33, and Cosmos 2251 fragments will continue to be felt for decades to come. For example, approximately half of the generated FY-1C fragments will remain in orbit 20 years from now. In general, the Iridium 33 and Cosmos 2251 fragments will decay faster than the FY-1C fragments because of their lower altitudes. Of the Iridium 33 and Cosmos 2251 fragments, the former have much shorter orbital lifetimes than the latter, because lightweight composite materials were heavily used in the construction of the Iridium

  2. High-Performance Computer Modeling of the Cosmos-Iridium Collision

    Energy Technology Data Exchange (ETDEWEB)

    Olivier, S; Cook, K; Fasenfest, B; Jefferson, D; Jiang, M; Leek, J; Levatin, J; Nikolaev, S; Pertica, A; Phillion, D; Springer, K; De Vries, W

    2009-08-28

    This paper describes the application of a new, integrated modeling and simulation framework, encompassing the space situational awareness (SSA) enterprise, to the recent Cosmos-Iridium collision. This framework is based on a flexible, scalable architecture to enable efficient simulation of the current SSA enterprise, and to accommodate future advancements in SSA systems. In particular, the code is designed to take advantage of massively parallel, high-performance computer systems available, for example, at Lawrence Livermore National Laboratory. We will describe the application of this framework to the recent collision of the Cosmos and Iridium satellites, including (1) detailed hydrodynamic modeling of the satellite collision and resulting debris generation, (2) orbital propagation of the simulated debris and analysis of the increased risk to other satellites (3) calculation of the radar and optical signatures of the simulated debris and modeling of debris detection with space surveillance radar and optical systems (4) determination of simulated debris orbits from modeled space surveillance observations and analysis of the resulting orbital accuracy, (5) comparison of these modeling and simulation results with Space Surveillance Network observations. We will also discuss the use of this integrated modeling and simulation framework to analyze the risks and consequences of future satellite collisions and to assess strategies for mitigating or avoiding future incidents, including the addition of new sensor systems, used in conjunction with the Space Surveillance Network, for improving space situational awareness.

  3. Iridium Interfacial Stack (IRIS)

    Science.gov (United States)

    Spry, David James (Inventor)

    2015-01-01

    An iridium interfacial stack ("IrIS") and a method for producing the same are provided. The IrIS may include ordered layers of TaSi.sub.2, platinum, iridium, and platinum, and may be placed on top of a titanium layer and a silicon carbide layer. The IrIS may prevent, reduce, or mitigate against diffusion of elements such as oxygen, platinum, and gold through at least some of its layers.

  4. Satellite network robust QoS-aware routing

    CERN Document Server

    Long, Fei

    2014-01-01

    Satellite Network Robust QoS-aware Routing presents a novel routing strategy for satellite networks. This strategy is useful for the design of multi-layered satellite networks as it can greatly reduce the number of time slots in one system cycle. The traffic prediction and engineering approaches make the system robust so that the traffic spikes can be handled effectively. The multi-QoS optimization routing algorithm can satisfy various potential user requirements. Clear and sufficient illustrations are also presented in the book. As the chapters cover the above topics independently, readers from different research backgrounds in constellation design, multi-QoS routing, and traffic engineering can benefit from the book.   Fei Long is a senior engineer at Beijing R&D Center of 54th Research Institute of China Electronics Technology Group Corporation.

  5. Increasing cellular coverage within integrated terrestrial/satellite mobile networks

    Science.gov (United States)

    Castro, Jonathan P.

    1995-01-01

    When applying the hierarchical cellular concept, the satellite acts as giant umbrella cell covering a region with some terrestrial cells. If a mobile terminal traversing the region arrives to the border-line or limits of a regular cellular ground service, network transition occurs and the satellite system continues the mobile coverage. To adequately assess the boundaries of service of a mobile satellite system an a cellular network within an integrated environment, this paper provides an optimized scheme to predict when a network transition may be necessary. Under the assumption of a classified propagation phenomenon and Lognormal shadowing, the study applies an analytical approach to estimate the location of a mobile terminal based on a reception of the signal strength emitted by a base station.

  6. Hyper Hospital on the satellite multi-media network.

    Science.gov (United States)

    Yamaguchi, T

    1997-01-01

    We have been developing the Hyper Hospital, a network based VR mediated medical care system. The Hyper Hospital is composed of two seamlessly integrated environments, that is, the virtual and the real worlds. Of them, its virtual environment expands the conventional medical care system using the virtual reality technology as a principal human interface and a collaboration tool, in the present study, an attempt to extend the Hyper Hospital system to various modalities of communication network is reported. A satellite communication based multi-media network using Internet protocols with the WWW interface is used. Data transmission rate and other performances were measured under various conditions and the satellite network was shown to be suitable to the Hyper Hospital network.

  7. A Hybrid Satellite-Terrestrial Approach to Aeronautical Communication Networks

    Science.gov (United States)

    Kerczewski, Robert J.; Chomos, Gerald J.; Griner, James H.; Mainger, Steven W.; Martzaklis, Konstantinos S.; Kachmar, Brian A.

    2000-01-01

    Rapid growth in air travel has been projected to continue for the foreseeable future. To maintain a safe and efficient national and global aviation system, significant advances in communications systems supporting aviation are required. Satellites will increasingly play a critical role in the aeronautical communications network. At the same time, current ground-based communications links, primarily very high frequency (VHF), will continue to be employed due to cost advantages and legacy issues. Hence a hybrid satellite-terrestrial network, or group of networks, will emerge. The increased complexity of future aeronautical communications networks dictates that system-level modeling be employed to obtain an optimal system fulfilling a majority of user needs. The NASA Glenn Research Center is investigating the current and potential future state of aeronautical communications, and is developing a simulation and modeling program to research future communications architectures for national and global aeronautical needs. This paper describes the primary requirements, the current infrastructure, and emerging trends of aeronautical communications, including a growing role for satellite communications. The need for a hybrid communications system architecture approach including both satellite and ground-based communications links is explained. Future aeronautical communication network topologies and key issues in simulation and modeling of future aeronautical communications systems are described.

  8. Optical neural network system for pose determination of spinning satellites

    Science.gov (United States)

    Lee, Andrew; Casasent, David

    1990-01-01

    An optical neural network architecture and algorithm based on a Hopfield optimization network are presented for multitarget tracking. This tracker utilizes a neuron for every possible target track, and a quadratic energy function of neural activities which is minimized using gradient descent neural evolution. The neural net tracker is demonstrated as part of a system for determining position and orientation (pose) of spinning satellites with respect to a robotic spacecraft. The input to the system is time sequence video from a single camera. Novelty detection and filtering are utilized to locate and segment novel regions from the input images. The neural net multitarget tracker determines the correspondences (or tracks) of the novel regions as a function of time, and hence the paths of object (satellite) parts. The path traced out by a given part or region is approximately elliptical in image space, and the position, shape and orientation of the ellipse are functions of the satellite geometry and its pose. Having a geometric model of the satellite, and the elliptical path of a part in image space, the three-dimensional pose of the satellite is determined. Digital simulation results using this algorithm are presented for various satellite poses and lighting conditions.

  9. Integration of Satellite and Terrestrial Networks at JPL

    Science.gov (United States)

    Pinck, D. S.

    1995-01-01

    This presentation focuses on the activities at JPL on the integration of satellite and terrestrial networks for mobile and personal communications. Activities fall into two categories: 1)advanced systems work, and 2)laboratory and field experimentation. Results of a workshop held at JPL on PCS integration and interoperability will be presented. Experiments will be described.

  10. Network coding and its applications to satellite systems

    DEFF Research Database (Denmark)

    Vieira, Fausto; Roetter, Daniel Enrique Lucani

    2015-01-01

    Network coding has its roots in information theory where it was initially proposed as a way to improve a two-node communication using a (broadcasting) relay. For this theoretical construct, a satellite communications system was proposed as an illustrative example, where the relay node would be a ...

  11. Iridium complexes for electrocatalysis

    Science.gov (United States)

    Sheehan, Stafford Wheeler; Hintermair, Ulrich; Thomsen, Julianne M; Brudvig, Gary W; Crabtree, Robert H

    2017-10-17

    Solution-phase (e.g., homogeneous) or surface-immobilized (e.g., heterogeneous) electrode-driven oxidation catalysts based on iridium coordination compounds which self-assemble upon chemical or electrochemical oxidation of suitable precursors and methods of making and using thereof are. Iridium species such as {[Ir(LX).sub.x(H.sub.2O).sub.y(.mu.-O)].sub.z.sup.m+}.sub.n wherein x, y, m are integers from 0-4, z and n from 1-4 and LX is an oxidation-resistant chelate ligand or ligands, such as such as 2(2-pyridyl)-2-propanolate, form upon oxidation of various molecular iridium complexes, for instance [Cp*Ir(LX)OH] or [(cod)Ir(LX)] (Cp*=pentamethylcyclopentadienyl, cod=cis-cis,1,5-cyclooctadiene) when exposed to oxidative conditions, such as sodium periodate (NaIO.sub.4) in aqueous solution at ambient conditions.

  12. Iridium: failures & successes

    Science.gov (United States)

    Christensen, CarissaBryce; Beard, Suzette

    2001-03-01

    This paper will provide an overview of the Iridium business venture in terms of the challenges faced, the successes achieved, and the causes of the ultimate failure of the venture — bankruptcy and system de-orbit. The paper will address technical, business, and policy issues. The intent of the paper is to provide a balanced and accurate overview of the Iridium experience, to aid future decision-making by policy makers, the business community, and technical experts. Key topics will include the history of the program, the objectives and decision-making of Motorola, the market research and analysis conducted, partnering strategies and their impact, consumer equipment availability, and technical issues — target performance, performance achieved, technical accomplishments, and expected and unexpected technical challenges. The paper will use as sources trade media and business articles on the Iridium program, technical papers and conference presentations, Wall Street analyst's reports, and, where possible, interviews with participants and close observers.

  13. GSFC network operations with Tracking and Data Relay Satellites

    Science.gov (United States)

    Spearing, R.; Perreten, D. E.

    The Tracking and Data Relay Satellite System (TDRSS) Network (TN) has been developed to provide services to all NASA User spacecraft in near-earth orbits. Three inter-relating entities will provide these services. The TN has been transformed from a network continuously changing to meet User specific requirements to a network which is flexible to meet future needs without significant changes in operational concepts. Attention is given to the evolution of the TN network, the TN capabilities-space segment, forward link services, tracking services, return link services, the three basic capabilities, single access services, multiple access services, simulation services, the White Sands Ground Terminal, the NASA communications network, and the network control center.

  14. ACTS TDMA network control. [Advanced Communication Technology Satellite

    Science.gov (United States)

    Inukai, T.; Campanella, S. J.

    1984-01-01

    This paper presents basic network control concepts for the Advanced Communications Technology Satellite (ACTS) System. Two experimental systems, called the low-burst-rate and high-burst-rate systems, along with ACTS ground system features, are described. The network control issues addressed include frame structures, acquisition and synchronization procedures, coordinated station burst-time plan and satellite-time plan changes, on-board clock control based on ground drift measurements, rain fade control by means of adaptive forward-error-correction (FEC) coding and transmit power augmentation, and reassignment of channel capacities on demand. The NASA ground system, which includes a primary station, diversity station, and master control station, is also described.

  15. Recurrent Neural Networks to Correct Satellite Image Classification Maps

    Science.gov (United States)

    Maggiori, Emmanuel; Charpiat, Guillaume; Tarabalka, Yuliya; Alliez, Pierre

    2017-09-01

    While initially devised for image categorization, convolutional neural networks (CNNs) are being increasingly used for the pixelwise semantic labeling of images. However, the proper nature of the most common CNN architectures makes them good at recognizing but poor at localizing objects precisely. This problem is magnified in the context of aerial and satellite image labeling, where a spatially fine object outlining is of paramount importance. Different iterative enhancement algorithms have been presented in the literature to progressively improve the coarse CNN outputs, seeking to sharpen object boundaries around real image edges. However, one must carefully design, choose and tune such algorithms. Instead, our goal is to directly learn the iterative process itself. For this, we formulate a generic iterative enhancement process inspired from partial differential equations, and observe that it can be expressed as a recurrent neural network (RNN). Consequently, we train such a network from manually labeled data for our enhancement task. In a series of experiments we show that our RNN effectively learns an iterative process that significantly improves the quality of satellite image classification maps.

  16. The Iridium (tm) system: Personal communications anytime, anyplace

    Science.gov (United States)

    Hatlelid, John E.; Casey, Larry

    1993-01-01

    The Iridium system is designed to provide handheld personal communications between diverse locations around the world at any time and without prior knowledge of the location of the personal units. This paper provides an overview of the system, the services it provides, its operation, and an overview of the commercial practices and relatively high volume satellite production techniques which will make the system cost effective. A constellation of 66 satellites will provide an orbiting, spherical-shell, infrastructure for this global calling capability. The satellites act as tall cellular towers and allow convenient operation for portable handheld telephones. The system will provide a full range of services including voice, paging, data, geolocation, and fax capabilities. Motorola is a world leader in the production of high volume, high quality, reliable telecommunications hardware. One of Iridium's goals is to apply these production techniques to high reliability space hardware. Concurrent engineering, high performance work teams, advanced manufacturing technologies, and improved assembly and test methods are some of the techniques that will keep the Iridium system cost effective. Mobile, global, flexible personal communications are coming that will allow anyone to call or receive a call from/to anyplace at anytime. The Iridium system will provide communications where none exist today. This connectivity will allow increased information transfer, open new markets for various business endeavors, and in general increase productivity and development.

  17. Satellite -Based Networks for U-Health & U-Learning

    Science.gov (United States)

    Graschew, G.; Roelofs, T. A.; Rakowsky, S.; Schlag, P. M.

    2008-08-01

    The use of modern Information and Communication Technologies (ICT) as enabling tools for healthcare services (eHealth) introduces new ways of creating ubiquitous access to high-level medical care for all, anytime and anywhere (uHealth). Satellite communication constitutes one of the most flexible methods of broadband communication offering high reliability and cost-effectiveness of connections meeting telemedicine communication requirements. Global networks and the use of computers for educational purposes stimulate and support the development of virtual universities for e-learning. Especially real-time interactive applications can play an important role in tailored and personalised services.

  18. Hardware demonstration of high-speed networks for satellite applications.

    Energy Technology Data Exchange (ETDEWEB)

    Donaldson, Jonathon W.; Lee, David S.

    2008-09-01

    This report documents the implementation results of a hardware demonstration utilizing the Serial RapidIO{trademark} and SpaceWire protocols that was funded by Sandia National Laboratories (SNL's) Laboratory Directed Research and Development (LDRD) office. This demonstration was one of the activities in the Modeling and Design of High-Speed Networks for Satellite Applications LDRD. This effort has demonstrated the transport of application layer packets across both RapidIO and SpaceWire networks to a common downlink destination using small topologies comprised of commercial-off-the-shelf and custom devices. The RapidFET and NEX-SRIO debug and verification tools were instrumental in the successful implementation of the RapidIO hardware demonstration. The SpaceWire hardware demonstration successfully demonstrated the transfer and routing of application data packets between multiple nodes and also was able reprogram remote nodes using configuration bitfiles transmitted over the network, a key feature proposed in node-based architectures (NBAs). Although a much larger network (at least 18 to 27 nodes) would be required to fully verify the design for use in a real-world application, this demonstration has shown that both RapidIO and SpaceWire are capable of routing application packets across a network to a common downlink node, illustrating their potential use in real-world NBAs.

  19. Warm hydroforming of iridium + 0.3 wt % tungsten hemishells

    International Nuclear Information System (INIS)

    Wyder, W.C.

    1976-01-01

    A technique for the production of iridium alloy hemispherical shells to be used for the primary encapsulation of plutonium-238 oxide spheres is described. The encapsulated spheres, 24 per heat source, provide the thermal heat used to drive thermoelectric converters which supply power for the Department of Defense's LES 8/9 satellites. The technique used a standard production type Hydroform machine converted for hot tooling. The iridium alloy discs were canned in stainless steel waster sheets of a larger size than the iridium discs and separated from the latter by tantalum foil barrier discs. The stainless steel was electron beam welded around the edge to form an envelope. The iridium disc assembly was heated to approximately 900 0 C and the tooling to approximately 500 0 C. After forming, the iridium shell was cut to length while in the waster sheet; and the latter was removed by dissolving in hot aqua regia. After removal of the waster sheets, the hemishells were cleaned and heat treated. Production efficiency reached a level of better than 95 percent and was maintained to produce some 600-odd hemishells

  20. Convolutional neural network features based change detection in satellite images

    Science.gov (United States)

    Mohammed El Amin, Arabi; Liu, Qingjie; Wang, Yunhong

    2016-07-01

    With the popular use of high resolution remote sensing (HRRS) satellite images, a huge research efforts have been placed on change detection (CD) problem. An effective feature selection method can significantly boost the final result. While hand-designed features have proven difficulties to design features that effectively capture high and mid-level representations, the recent developments in machine learning (Deep Learning) omit this problem by learning hierarchical representation in an unsupervised manner directly from data without human intervention. In this letter, we propose approaching the change detection problem from a feature learning perspective. A novel deep Convolutional Neural Networks (CNN) features based HR satellite images change detection method is proposed. The main guideline is to produce a change detection map directly from two images using a pretrained CNN. This method can omit the limited performance of hand-crafted features. Firstly, CNN features are extracted through different convolutional layers. Then, a concatenation step is evaluated after an normalization step, resulting in a unique higher dimensional feature map. Finally, a change map was computed using pixel-wise Euclidean distance. Our method has been validated on real bitemporal HRRS satellite images according to qualitative and quantitative analyses. The results obtained confirm the interest of the proposed method.

  1. Satellites

    International Nuclear Information System (INIS)

    Burns, J.A.; Matthews, M.S.

    1986-01-01

    The present work is based on a conference: Natural Satellites, Colloquium 77 of the IAU, held at Cornell University from July 5 to 9, 1983. Attention is given to the background and origins of satellites, protosatellite swarms, the tectonics of icy satellites, the physical characteristics of satellite surfaces, and the interactions of planetary magnetospheres with icy satellite surfaces. Other topics include the surface composition of natural satellites, the cratering of planetary satellites, the moon, Io, and Europa. Consideration is also given to Ganymede and Callisto, the satellites of Saturn, small satellites, satellites of Uranus and Neptune, and the Pluto-Charon system

  2. Satellite Telemetry and Command using Big LEO Mobile Telecommunications Systems

    Science.gov (United States)

    Huegel, Fred

    1998-01-01

    Various issues associated with satellite telemetry and command using Big LEO mobile telecommunications systems are presented in viewgraph form. Specific topics include: 1) Commercial Satellite system overviews: Globalstar, ICO, and Iridium; 2) System capabilities and cost reduction; 3) Satellite constellations and contact limitations; 4) Capabilities of Globalstar, ICO and Iridium with emphasis on Globalstar; and 5) Flight transceiver issues and security.

  3. Signalling design and architecture for a proposed mobile satellite network

    Science.gov (United States)

    Yan, T.-Y.; Cheng, U.; Wang, C.

    1990-01-01

    In a frequency-division/demand-assigned multiple-access (FD/DAMA) architecture, each mobile subscriber must make a connection request to the Network Management Center before transmission for either open-end or closed-end services. Open-end services are for voice calls and long file transfer and are processed on a blocked-call-cleared basis. Closed-end services are for transmitting burst data and are processed on a first-come first-served basis. This paper presents the signalling design and architecture for non-voice services of an FD/DAMA mobile satellite network. The connection requests are made through the recently proposed multiple channel collision resolution scheme which provides a significantly higher throughput than the traditional slotted ALOHA scheme. For non-voice services, it is well known that retransmissions are necessary to ensure the delivery of a message in its entirety from the source to destination. Retransmission protocols for open-end and closed-end data transfer are investigated. The signal structure for the proposed network is derived from X-25 standards with appropriate modifications. The packet types and their usages are described in this paper.

  4. Network design consideration of a satellite-based mobile communications system

    Science.gov (United States)

    Yan, T.-Y.

    1986-01-01

    Technical considerations for the Mobile Satellite Experiment (MSAT-X), the ground segment testbed for the low-cost spectral efficient satellite-based mobile communications technologies being developed for the 1990's, are discussed. The Network Management Center contains a flexible resource sharing algorithm, the Demand Assigned Multiple Access scheme, which partitions the satellite transponder bandwidth among voice, data, and request channels. Satellite use of multiple UHF beams permits frequency reuse. The backhaul communications and the Telemetry, Tracking and Control traffic are provided through a single full-coverage SHF beam. Mobile Terminals communicate with the satellite using UHF. All communications including SHF-SHF between Base Stations and/or Gateways, are routed through the satellite. Because MSAT-X is an experimental network, higher level network protocols (which are service-specific) will be developed only to test the operation of the lowest three levels, the physical, data link, and network layers.

  5. Capacity Model and Constraints Analysis for Integrated Remote Wireless Sensor and Satellite Network in Emergency Scenarios

    Science.gov (United States)

    Zhang, Wei; Zhang, Gengxin; Dong, Feihong; Xie, Zhidong; Bian, Dongming

    2015-01-01

    This article investigates the capacity problem of an integrated remote wireless sensor and satellite network (IWSSN) in emergency scenarios. We formulate a general model to evaluate the remote sensor and satellite network capacity. Compared to most existing works for ground networks, the proposed model is time varying and space oriented. To capture the characteristics of a practical network, we sift through major capacity-impacting constraints and analyze the influence of these constraints. Specifically, we combine the geometric satellite orbit model and satellite tool kit (STK) engineering software to quantify the trends of the capacity constraints. Our objective in analyzing these trends is to provide insights and design guidelines for optimizing the integrated remote wireless sensor and satellite network schedules. Simulation results validate the theoretical analysis of capacity trends and show the optimization opportunities of the IWSSN. PMID:26593919

  6. Capacity Model and Constraints Analysis for Integrated Remote Wireless Sensor and Satellite Network in Emergency Scenarios.

    Science.gov (United States)

    Zhang, Wei; Zhang, Gengxin; Dong, Feihong; Xie, Zhidong; Bian, Dongming

    2015-11-17

    This article investigates the capacity problem of an integrated remote wireless sensor and satellite network (IWSSN) in emergency scenarios. We formulate a general model to evaluate the remote sensor and satellite network capacity. Compared to most existing works for ground networks, the proposed model is time varying and space oriented. To capture the characteristics of a practical network, we sift through major capacity-impacting constraints and analyze the influence of these constraints. Specifically, we combine the geometric satellite orbit model and satellite tool kit (STK) engineering software to quantify the trends of the capacity constraints. Our objective in analyzing these trends is to provide insights and design guidelines for optimizing the integrated remote wireless sensor and satellite network schedules. Simulation results validate the theoretical analysis of capacity trends and show the optimization opportunities of the IWSSN.

  7. Performance Analysis of Space Information Networks with Backbone Satellite Relaying for Vehicular Networks

    Directory of Open Access Journals (Sweden)

    Jian Jiao

    2017-01-01

    Full Text Available Space Information Network (SIN with backbone satellites relaying for vehicular network (VN communications is regarded as an effective strategy to provide diverse vehicular services in a seamless, efficient, and cost-effective manner in rural areas and highways. In this paper, we investigate the performance of SIN return channel cooperative communications via an amplify-and-forward (AF backbone satellite relaying for VN communications, where we assume that both of the source-destination and relay-destination links undergo Shadowed-Rician fading and the source-relay link follows Rician fading, respectively. In this SIN-assisted VN communication scenario, we first obtain the approximate statistical distributions of the equivalent end-to-end signal-to-noise ratio (SNR of the system. Then, we derive the closed-form expressions to efficiently evaluate the average symbol error rate (ASER of the system. Furthermore, the ASER expressions are taking into account the effect of satellite perturbation of the backbone relaying satellite, which reveal the accumulated error of the antenna pointing error. Finally, simulation results are provided to verify the accuracy of our theoretical analysis and show the impact of various parameters on the system performance.

  8. Energy-Efficient Optimal Power Allocation in Integrated Wireless Sensor and Cognitive Satellite Terrestrial Networks.

    Science.gov (United States)

    Shi, Shengchao; Li, Guangxia; An, Kang; Gao, Bin; Zheng, Gan

    2017-09-04

    This paper proposes novel satellite-based wireless sensor networks (WSNs), which integrate the WSN with the cognitive satellite terrestrial network. Having the ability to provide seamless network access and alleviate the spectrum scarcity, cognitive satellite terrestrial networks are considered as a promising candidate for future wireless networks with emerging requirements of ubiquitous broadband applications and increasing demand for spectral resources. With the emerging environmental and energy cost concerns in communication systems, explicit concerns on energy efficient resource allocation in satellite networks have also recently received considerable attention. In this regard, this paper proposes energy-efficient optimal power allocation schemes in the cognitive satellite terrestrial networks for non-real-time and real-time applications, respectively, which maximize the energy efficiency (EE) of the cognitive satellite user while guaranteeing the interference at the primary terrestrial user below an acceptable level. Specifically, average interference power (AIP) constraint is employed to protect the communication quality of the primary terrestrial user while average transmit power (ATP) or peak transmit power (PTP) constraint is adopted to regulate the transmit power of the satellite user. Since the energy-efficient power allocation optimization problem belongs to the nonlinear concave fractional programming problem, we solve it by combining Dinkelbach's method with Lagrange duality method. Simulation results demonstrate that the fading severity of the terrestrial interference link is favorable to the satellite user who can achieve EE gain under the ATP constraint comparing to the PTP constraint.

  9. Network Performance Evaluation of Abis Interface over DVB-S2 in the GSM over Satellite Network

    Directory of Open Access Journals (Sweden)

    S. B. Musabekov

    2010-01-01

    Full Text Available This paper deals with establishing a GSM link over Satellite. Abis interface, which is defined between Base Transceiver Station (BTS and Base Station Controller (BSC, in a GSM network is considered here to be routed over the Satellite. The satellite link enables a quick and cost-effective GSM link in meagerly populated areas. A different scenario comparison was done to understand the impact of Satellite environment on network availability comparing to terrestrial scenario. We have implemented an Abis interface over DVB S2 in NS2 and evaluated the performance over the high delay and loss satellite channel. Network performance was evaluated with respect to Satellite channel delay and DVB S2 encapsulation efficiency under different amount of user traffic and compared with the terrestrial scenario. The results clearly showed an increased amount of SDCCH and TCH channels required in the case of satellite scenario for the same amount of traffic in comparison to conventional terrestrial scenario. We have optimized the parameters based on the simulation results. Link budget estimation considering DVB-S2 platform was done to find satellite bandwidth and cost requirements for different network setups.

  10. Effectiveness evaluation of double-layered satellite network with laser and microwave hybrid links based on fuzzy analytic hierarchy process

    Science.gov (United States)

    Zhang, Wei; Rao, Qiaomeng

    2018-01-01

    In order to solve the problem of high speed, large capacity and limited spectrum resources of satellite communication network, a double-layered satellite network with global seamless coverage based on laser and microwave hybrid links is proposed in this paper. By analyzing the characteristics of the double-layered satellite network with laser and microwave hybrid links, an effectiveness evaluation index system for the network is established. And then, the fuzzy analytic hierarchy process, which combines the analytic hierarchy process and the fuzzy comprehensive evaluation theory, is used to evaluate the effectiveness of the double-layered satellite network with laser and microwave hybrid links. Furthermore, the evaluation result of the proposed hybrid link network is obtained by simulation. The effectiveness evaluation process of the proposed double-layered satellite network with laser and microwave hybrid links can help to optimize the design of hybrid link double-layered satellite network and improve the operating efficiency of the satellite system.

  11. A proposed architecture for a satellite-based mobile communications network - The lowest three layers

    Science.gov (United States)

    Yan, T. Y.; Naderi, F. M.

    1986-01-01

    Architecture for a commercial mobile satellite network is proposed. The mobile satellite system (MSS) is composed of a network management center, mobile terminals, base stations, and gateways; the functions of each component are described. The satellite is a 'bent pipe' that performs frequency translations, and it has multiple UHF beams. The development of the MSS design based on the seven-layer open system interconnection model is examined. Consideration is given to the functions of the physical, data link, and network layers and the integrated adaptive mobile access protocol.

  12. Study on networking issues of medium earth orbit satellite communications systems

    Science.gov (United States)

    Araki, Noriyuki; Shinonaga, Hideyuki; Ito, Yasuhiko

    1993-01-01

    Two networking issues of communications systems with medium earth orbit (MEO) satellites, namely network architectures and location determination and registration methods for hand-held terminals, are investigated in this paper. For network architecture, five candidate architectures are considered and evaluated in terms of signaling traffic. For location determination and registration, two methods are discussed and evaluated.

  13. Satellites vs. fiber optics based networks and services - Road map to strategic planning

    Science.gov (United States)

    Marandi, James H. R.

    An overview of a generic telecommunications network and its components is presented, and the current developments in satellite and fiber optics technologies are discussed with an eye on the trends in industry. A baseline model is proposed, and a cost comparison of fiber- vs satellite-based networks is made. A step-by-step 'road map' to the successful strategic planning of telecommunications services and facilities is presented. This road map provides for optimization of the current and future networks and services through effective utilization of both satellites and fiber optics. The road map is then applied to different segments of the telecommunications industry and market place, to show its effectiveness for the strategic planning of executives of three types: (1) those heading telecommunications manufacturing concerns, (2) those leading communication service companies, and (3) managers of telecommunication/MIS departments of major corporations. Future networking issues, such as developments in integrated-services digital network standards and technologies, are addressed.

  14. In-Space Internet-Based Communications for Space Science Platforms Using Commercial Satellite Networks

    Science.gov (United States)

    Kerczewski, Robert J.; Bhasin, Kul B.; Fabian, Theodore P.; Griner, James H.; Kachmar, Brian A.; Richard, Alan M.

    1999-01-01

    The continuing technological advances in satellite communications and global networking have resulted in commercial systems that now can potentially provide capabilities for communications with space-based science platforms. This reduces the need for expensive government owned communications infrastructures to support space science missions while simultaneously making available better service to the end users. An interactive, high data rate Internet type connection through commercial space communications networks would enable authorized researchers anywhere to control space-based experiments in near real time and obtain experimental results immediately. A space based communications network architecture consisting of satellite constellations connecting orbiting space science platforms to ground users can be developed to provide this service. The unresolved technical issues presented by this scenario are the subject of research at NASA's Glenn Research Center in Cleveland, Ohio. Assessment of network architectures, identification of required new or improved technologies, and investigation of data communications protocols are being performed through testbed and satellite experiments and laboratory simulations.

  15. Design mobile satellite system architecture as an integral part of the cellular access digital network

    Science.gov (United States)

    Chien, E. S. K.; Marinho, J. A.; Russell, J. E., Sr.

    1988-01-01

    The Cellular Access Digital Network (CADN) is the access vehicle through which cellular technology is brought into the mainstream of the evolving integrated telecommunications network. Beyond the integrated end-to-end digital access and per call network services provisioning of the Integrated Services Digital Network (ISDN), the CADN engenders the added capability of mobility freedom via wireless access. One key element of the CADN network architecture is the standard user to network interface that is independent of RF transmission technology. Since the Mobile Satellite System (MSS) is envisioned to not only complement but also enhance the capabilities of the terrestrial cellular telecommunications network, compatibility and interoperability between terrestrial cellular and mobile satellite systems are vitally important to provide an integrated moving telecommunications network of the future. From a network standpoint, there exist very strong commonalities between the terrestrial cellular system and the mobile satellite system. Therefore, the MSS architecture should be designed as an integral part of the CADN. This paper describes the concept of the CADN, the functional architecture of the MSS, and the user-network interface signaling protocols.

  16. Scaling of Airborne Ad-hoc Network Metrics with Link Range and Satellite Connectivity

    Directory of Open Access Journals (Sweden)

    Kai-Daniel BÜCHTER

    2018-06-01

    Full Text Available In this contribution, large-scale commercial aeronautical ad-hoc networks are evaluated. The investigation is based on a simulation environment with input from 2016 flight schedule and aircraft performance databases for flight movement modelling, along with a defined infrastructure of ground gateways and communication satellites. A cluster-based algorithm is used to build the communication network topology between aircraft. Cloud top pressure data can be considered to estimate cloud height and evaluate the impact of link obscuration on network availability, assuming a free-space optics-based communication network. The effects of communication range, satellite availability, fleet equipage ratio and clouds are discussed. It is shown how network reach and performance can be enhanced by adding taps to the network in the form of high-speed satellite links. The effect of adding these is two-fold: firstly, network reach can be increased by connecting remote aircraft clusters. Secondly, larger clusters can effectively be split into smaller ones in order to increase performance especially with regard to hop count and available overall capacity. In a realistic scenario concerning communication range and with moderate numbers of high-speed satellite terminals, on average, 78% of all widebody aircraft can be reached. With clouds considered (assuming laser links, this number reduces by 10%.

  17. Design Issues for Traffic Management for the ATM UBR + Service for TCP Over Satellite Networks

    Science.gov (United States)

    Jain, Raj

    1999-01-01

    This project was a comprehensive research program for developing techniques for improving the performance of Internet protocols over Asynchronous Transfer Mode (ATM) based satellite networks. Among the service categories provided by ATM networks, the most commonly used category for data traffic is the unspecified bit rate (UBR) service. UBR allows sources to send data into the network without any feedback control. The project resulted in the numerous ATM Forum contributions and papers.

  18. A Survey of Congestion Control Techniques and Data Link Protocols in Satellite Networks

    OpenAIRE

    Fahmy, Sonia; Jain, Raj; Lu, Fang; Kalyanaraman, Shivkumar

    1998-01-01

    Satellite communication systems are the means of realizing a global broadband integrated services digital network. Due to the statistical nature of the integrated services traffic, the resulting rate fluctuations and burstiness render congestion control a complicated, yet indispensable function. The long propagation delay of the earth-satellite link further imposes severe demands and constraints on the congestion control schemes, as well as the media access control techniques and retransmissi...

  19. Integrating small satellite communication in an autonomous vehicle network: A case for oceanography

    Science.gov (United States)

    Guerra, André G. C.; Ferreira, António Sérgio; Costa, Maria; Nodar-López, Diego; Aguado Agelet, Fernando

    2018-04-01

    Small satellites and autonomous vehicles have greatly evolved in the last few decades. Hundreds of small satellites have been launched with increasing functionalities, in the last few years. Likewise, numerous autonomous vehicles have been built, with decreasing costs and form-factor payloads. Here we focus on combining these two multifaceted assets in an incremental way, with an ultimate goal of alleviating the logistical expenses in remote oceanographic operations. The first goal is to create a highly reliable and constantly available communication link for a network of autonomous vehicles, taking advantage of the small satellite lower cost, with respect to conventional spacecraft, and its higher flexibility. We have developed a test platform as a proving ground for this network, by integrating a satellite software defined radio on an unmanned air vehicle, creating a system of systems, and several tests have been run successfully, over land. As soon as the satellite is fully operational, we will start to move towards a cooperative network of autonomous vehicles and small satellites, with application in maritime operations, both in-situ and remote sensing.

  20. Dynamic communications for small satellites using disruption tolerant network concepts

    NARCIS (Netherlands)

    Giuditta, N.; Gill, E.K.A.; Fernández, B.; Isaac, D.

    2009-01-01

    New network technologies are providing interconnectivity in areas previously unheard of. One of these novel technologies, named Disruption Tolerant Networking (DTN), shows promise for the space industry. In order to study its suitability for University projects, a model of a University space mission

  1. Very Small Satellite Design for Space Sensor Networks

    Science.gov (United States)

    2008-06-01

    Literature Review 25 Clyde Space Power Pumpkin Computer Microhard Comm SSTL GPS User Payload Pumpkin Structure Figure 2-10. CUTE-I CubeSat [69...Structure Pumpkin [244] Skeletonized 155 $1,350* $810* EPS Clyde Space [245] CubeSat EPS 310 $25,240* $19,252* DH Pumpkin [244] FM430 90 $1,200* $720...satellite miniaturisation since 1993 and probably before. Furthermore, the term itself has been diluted from the pure literal form, eventually

  2. An optical sensor network for vegetation phenology monitoring and satellite data calibration

    DEFF Research Database (Denmark)

    Eklundh, L.; Jin, H.; Schubert, P.

    2011-01-01

    -board Aqua and Terra satellite platforms. PAR fluxes are partitioned into reflected and absorbed components for the ground and canopy. The measurements demonstrate that the instrumentation provides detailed information about the vegetation phenology and variations in reflectance due to snow cover variations......We present a network of sites across Fennoscandia for optical sampling of vegetation properties relevant for phenology monitoring and satellite data calibration. The network currently consists of five sites, distributed along an N-S gradient through Sweden and Finland. Two sites are located...... and vegetation development. Valuable information about PAR absorption of ground and canopy is obtained that may be linked to vegetation productivity....

  3. Space Network IP Services (SNIS): An Architecture for Supporting Low Earth Orbiting IP Satellite Missions

    Science.gov (United States)

    Israel, David J.

    2005-01-01

    The NASA Space Network (SN) supports a variety of missions using the Tracking and Data Relay Satellite System (TDRSS), which includes ground stations in White Sands, New Mexico and Guam. A Space Network IP Services (SNIS) architecture is being developed to support future users with requirements for end-to-end Internet Protocol (IP) communications. This architecture will support all IP protocols, including Mobile IP, over TDRSS Single Access, Multiple Access, and Demand Access Radio Frequency (RF) links. This paper will describe this architecture and how it can enable Low Earth Orbiting IP satellite missions.

  4. Wideband Autonomous Cognitive Radios for Networked Satellites Communications, Phase II

    Data.gov (United States)

    National Aeronautics and Space Administration — Wideband Autonomous Cognitive Radios (WACRs) are advanced radios that have the ability to sense state of the RF spectrum and the network and self-optimize its...

  5. Wideband autonomous cognitive radios for networked satellites communications, Phase I

    Data.gov (United States)

    National Aeronautics and Space Administration — There is growing recognition that success in a variety of space mission types can be greatly enhanced by making current communication transceivers and networks...

  6. Road Network Extraction from VHR Satellite Images Using Context Aware Object Feature Integration and Tensor Voting

    Directory of Open Access Journals (Sweden)

    Mehdi Maboudi

    2016-08-01

    Full Text Available Road networks are very important features in geospatial databases. Even though high-resolution optical satellite images have already been acquired for more than a decade, tools for automated extraction of road networks from these images are still rare. One consequence of this is the need for manual interaction which, in turn, is time and cost intensive. In this paper, a multi-stage approach is proposed which integrates structural, spectral, textural, as well as contextual information of objects to extract road networks from very high resolution satellite images. Highlights of the approach are a novel linearity index employed for the discrimination of elongated road segments from other objects and customized tensor voting which is utilized to fill missing parts of the network. Experiments are carried out with different datasets. Comparison of the achieved results with the results of seven state-of-the-art methods demonstrated the efficiency of the proposed approach.

  7. Cyclone track forecasting based on satellite images using artificial neural networks

    OpenAIRE

    Kovordanyi, Rita; Roy, Chandan

    2009-01-01

    Many places around the world are exposed to tropical cyclones and associated storm surges. In spite of massive efforts, a great number of people die each year as a result of cyclone events. To mitigate this damage, improved forecasting techniques must be developed. The technique presented here uses artificial neural networks to interpret NOAA-AVHRR satellite images. A multi-layer neural network, resembling the human visual system, was trained to forecast the movement of cyclones based on sate...

  8. Defense Science Board Task Force on Military Satellite Communication and Tactical Networking. Executive Summary

    Science.gov (United States)

    2017-03-01

    Interface Processor BCT Brigade Combat Team BFT Blue Force Tracking BLOS Beyond Line-of-Sight C2 Command And Control C2E Communications in...Satellite Communications and Tactical Networking Appendix D-2 GIG Global Information Grid GMR Ground Mobile Radio GPS Global Positioning System...System SIPRNet Secret Internet Protocol Router Network SITREPS Situational Reports SMART -T Secure Mobile Anti-Jam Reliable Tactical Terminal SMC Space

  9. Super-Resolution for “Jilin-1” Satellite Video Imagery via a Convolutional Network

    Directory of Open Access Journals (Sweden)

    Aoran Xiao

    2018-04-01

    Full Text Available Super-resolution for satellite video attaches much significance to earth observation accuracy, and the special imaging and transmission conditions on the video satellite pose great challenges to this task. The existing deep convolutional neural-network-based methods require pre-processing or post-processing to be adapted to a high-resolution size or pixel format, leading to reduced performance and extra complexity. To this end, this paper proposes a five-layer end-to-end network structure without any pre-processing and post-processing, but imposes a reshape or deconvolution layer at the end of the network to retain the distribution of ground objects within the image. Meanwhile, we formulate a joint loss function by combining the output and high-dimensional features of a non-linear mapping network to precisely learn the desirable mapping relationship between low-resolution images and their high-resolution counterparts. Also, we use satellite video data itself as a training set, which favors consistency between training and testing images and promotes the method’s practicality. Experimental results on “Jilin-1” satellite video imagery show that this method demonstrates a superior performance in terms of both visual effects and measure metrics over competing methods.

  10. Super-Resolution for "Jilin-1" Satellite Video Imagery via a Convolutional Network.

    Science.gov (United States)

    Xiao, Aoran; Wang, Zhongyuan; Wang, Lei; Ren, Yexian

    2018-04-13

    Super-resolution for satellite video attaches much significance to earth observation accuracy, and the special imaging and transmission conditions on the video satellite pose great challenges to this task. The existing deep convolutional neural-network-based methods require pre-processing or post-processing to be adapted to a high-resolution size or pixel format, leading to reduced performance and extra complexity. To this end, this paper proposes a five-layer end-to-end network structure without any pre-processing and post-processing, but imposes a reshape or deconvolution layer at the end of the network to retain the distribution of ground objects within the image. Meanwhile, we formulate a joint loss function by combining the output and high-dimensional features of a non-linear mapping network to precisely learn the desirable mapping relationship between low-resolution images and their high-resolution counterparts. Also, we use satellite video data itself as a training set, which favors consistency between training and testing images and promotes the method's practicality. Experimental results on "Jilin-1" satellite video imagery show that this method demonstrates a superior performance in terms of both visual effects and measure metrics over competing methods.

  11. Geometric Aspects of Ground Augmentation of Satellite Networks for the Needs of Deformation Monitoring

    Science.gov (United States)

    Protaziuk, Elżbieta

    2016-06-01

    Satellite measurements become competitive in many tasks of engineering surveys, however, in many requiring applications possibilities to apply such solutions are still limited. The possibility to widely apply satellite technologies for displacements measurements is related with new challenges; the most important of them relate to increasing requirements concerning the accuracy, reliability and continuity of results of position determination. One of the solutions is a ground augmentation of satellite network, which intention is to improve precision of positioning, ensure comparable accuracy of coordinates and reduce precision fluctuations over time. The need for augmentation of GNSS is particularly significant in situations: where the visibility of satellites is poor because of terrain obstacles, when the determined position is not precise enough or a satellites constellation does not allow for reliable positioning. Ground based source/sources of satellite signal placed at a ground, called pseudosatellites, or pseudolites were intensively investigated during the last two decades and finally were developed into groundbased, time-synchronized transceivers, that can transmit and receive a proprietary positioning signal. The paper presents geometric aspects of the ground based augmentation of the satellite networks using various quality measures of positioning geometry, which depends on access to the constellation of satellites and the conditions of the observation environment. The issue of minimizing these measures is the key problem that allows to obtain the position with high accuracy. For this purpose, the use of an error ellipsoid is proposed and compared with an error ellipse. The paper also describes the results of preliminary accuracy analysis obtained at test area and a comparison of various measures of the quality of positioning geometry.

  12. The performance evaluation of a new neural network based traffic management scheme for a satellite communication network

    Science.gov (United States)

    Ansari, Nirwan; Liu, Dequan

    1991-01-01

    A neural-network-based traffic management scheme for a satellite communication network is described. The scheme consists of two levels of management. The front end of the scheme is a derivation of Kohonen's self-organization model to configure maps for the satellite communication network dynamically. The model consists of three stages. The first stage is the pattern recognition task, in which an exemplar map that best meets the current network requirements is selected. The second stage is the analysis of the discrepancy between the chosen exemplar map and the state of the network, and the adaptive modification of the chosen exemplar map to conform closely to the network requirement (input data pattern) by means of Kohonen's self-organization. On the basis of certain performance criteria, whether a new map is generated to replace the original chosen map is decided in the third stage. A state-dependent routing algorithm, which arranges the incoming call to some proper path, is used to make the network more efficient and to lower the call block rate. Simulation results demonstrate that the scheme, which combines self-organization and the state-dependent routing mechanism, provides better performance in terms of call block rate than schemes that only have either the self-organization mechanism or the routing mechanism.

  13. Neural network based satellite tracking for deep space applications

    Science.gov (United States)

    Amoozegar, F.; Ruggier, C.

    2003-01-01

    The objective of this paper is to provide a survey of neural network trends as applied to the tracking of spacecrafts in deep space at Ka-band under various weather conditions and examine the trade-off between tracing accuracy and communication link performance.

  14. End-to-end network models encompassing terrestrial, wireless, and satellite components

    Science.gov (United States)

    Boyarko, Chandler L.; Britton, John S.; Flores, Phil E.; Lambert, Charles B.; Pendzick, John M.; Ryan, Christopher M.; Shankman, Gordon L.; Williams, Ramon P.

    2004-08-01

    Development of network models that reflect true end-to-end architectures such as the Transformational Communications Architecture need to encompass terrestrial, wireless and satellite component to truly represent all of the complexities in a world wide communications network. Use of best-in-class tools including OPNET, Satellite Tool Kit (STK), Popkin System Architect and their well known XML-friendly definitions, such as OPNET Modeler's Data Type Description (DTD), or socket-based data transfer modules, such as STK/Connect, enable the sharing of data between applications for more rapid development of end-to-end system architectures and a more complete system design. By sharing the results of and integrating best-in-class tools we are able to (1) promote sharing of data, (2) enhance the fidelity of our results and (3) allow network and application performance to be viewed in the context of the entire enterprise and its processes.

  15. Issues for the integration of satellite and terrestrial cellular networks for mobile communications

    Science.gov (United States)

    Delre, Enrico; Mistretta, Ignazio; Dellipriscoli, Francesco; Settimo, Franco

    1991-01-01

    Satellite and terrestrial cellular systems naturally complement each other for land mobile communications, even though present systems have been developed independently. The main advantages of the integrated system are a faster wide area coverage, a better management of overloading traffic conditions, an extension to geographical areas not covered by the terrestrial network and, in perspective, the provision of only one integrated system for all mobile communications (land, aeronautical, and maritime). To achieve these goals, as far as possible the same protocols of the terrestrial network should be used also for the satellite network. Discussed here are the main issues arising from the requirements of the main integrated system. Some results are illustrated, and possible future improvements due to technical solutions are presented.

  16. Performance Analysis of TCP Enhancements in Satellite Data Networks

    Science.gov (United States)

    Broyles, Ren H.

    1999-01-01

    This research examines two proposed enhancements to the well-known Transport Control Protocol (TCP) in the presence of noisy communication links. The Multiple Pipes protocol is an application-level adaptation of the standard TCP protocol, where several TCP links cooperate to transfer data. The Space Communication Protocol Standard - Transport Protocol (SCPS-TP) modifies TCP to optimize performance in a satellite environment. While SCPS-TP has inherent advantages that allow it to deliver data more rapidly than Multiple Pipes, the protocol, when optimized for operation in a high-error environment, is not compatible with legacy TCP systems, and requires changes to the TCP specification. This investigation determines the level of improvement offered by SCPS-TP's Corruption Mode, which will help determine if migration to the protocol is appropriate in different environments. As the percentage of corrupted packets approaches 5 %, Multiple Pipes can take over five times longer than SCPS-TP to deliver data. At high error rates, SCPS-TP's advantage is primarily caused by Multiple Pipes' use of congestion control algorithms. The lack of congestion control, however, limits the systems in which SCPS-TP can be effectively used.

  17. A Topology Control Strategy with Reliability Assurance for Satellite Cluster Networks in Earth Observation.

    Science.gov (United States)

    Chen, Qing; Zhang, Jinxiu; Hu, Ze

    2017-02-23

    This article investigates the dynamic topology control problemof satellite cluster networks (SCNs) in Earth observation (EO) missions by applying a novel metric of stability for inter-satellite links (ISLs). The properties of the periodicity and predictability of satellites' relative position are involved in the link cost metric which is to give a selection criterion for choosing the most reliable data routing paths. Also, a cooperative work model with reliability is proposed for the situation of emergency EO missions. Based on the link cost metric and the proposed reliability model, a reliability assurance topology control algorithm and its corresponding dynamic topology control (RAT) strategy are established to maximize the stability of data transmission in the SCNs. The SCNs scenario is tested through some numeric simulations of the topology stability of average topology lifetime and average packet loss rate. Simulation results show that the proposed reliable strategy applied in SCNs significantly improves the data transmission performance and prolongs the average topology lifetime.

  18. USING SATELLITE IMAGES FOR WIRELESS NETWORK PLANING IN BAKU CITY

    Directory of Open Access Journals (Sweden)

    M. Gojamanov

    2013-04-01

    Full Text Available It is a well known fact that the Information-Telecommunication and Space research technologies are the fields getting much more benefits from the achievements of the scientific and technical progress. In many cases, these areas supporting each other have improved the conditions for their further development. For instance, the intensive development in the field of the mobile communication has caused the rapid progress of the Space research technologies and vice versa.Today it is impossible to solve one of the most important tasks of the mobile communication as Radio Frecance planning without the 2D and 3D digital maps. The compiling of such maps is much more efficient by means of the space images. Because the quality of the space images has been improved and developed, especially at the both spectral and spatial resolution points. It has been possible to to use 8 Band images with the spatial resolution of 50 sm. At present, in relation to the function 3G of mobile communications one of the main issues facing mobile operator companies is a high-precision 3D digital maps. It should be noted that the number of mobile phone users in the Republic of Azerbaijan went forward other Community of Independent States Countries. Of course, using of aerial images for 3D mapping would be optimal. However, depending on a number of technical and administrative problems aerial photography cannot be used. Therefore, the experience of many countries shows that it will be more effective to use the space images with the higher resolution for these issues. Concerning the fact that the mobile communication within the city of Baku has included 3G function there were ordered stereo images wih the spatial resolution of 50 cm for the 150 sq.km territory occupying the central part of the city in order to compile 3D digital maps. The images collected from the WorldView-2 satellite are 4-Band Bundle(Pan+MS1 stereo images. Such kind of imagery enable to automatically

  19. Using Satellite Images for Wireless Network Planing in Baku City

    Science.gov (United States)

    Gojamanov, M.; Ismayilov, J.

    2013-04-01

    It is a well known fact that the Information-Telecommunication and Space research technologies are the fields getting much more benefits from the achievements of the scientific and technical progress. In many cases, these areas supporting each other have improved the conditions for their further development. For instance, the intensive development in the field of the mobile communication has caused the rapid progress of the Space research technologies and vice versa.Today it is impossible to solve one of the most important tasks of the mobile communication as Radio Frecance planning without the 2D and 3D digital maps. The compiling of such maps is much more efficient by means of the space images. Because the quality of the space images has been improved and developed, especially at the both spectral and spatial resolution points. It has been possible to to use 8 Band images with the spatial resolution of 50 sm. At present, in relation to the function 3G of mobile communications one of the main issues facing mobile operator companies is a high-precision 3D digital maps. It should be noted that the number of mobile phone users in the Republic of Azerbaijan went forward other Community of Independent States Countries. Of course, using of aerial images for 3D mapping would be optimal. However, depending on a number of technical and administrative problems aerial photography cannot be used. Therefore, the experience of many countries shows that it will be more effective to use the space images with the higher resolution for these issues. Concerning the fact that the mobile communication within the city of Baku has included 3G function there were ordered stereo images wih the spatial resolution of 50 cm for the 150 sq.km territory occupying the central part of the city in order to compile 3D digital maps. The images collected from the WorldView-2 satellite are 4-Band Bundle(Pan+MS1) stereo images. Such kind of imagery enable to automatically classificate some required

  20. Classification and Segmentation of Satellite Orthoimagery Using Convolutional Neural Networks

    Directory of Open Access Journals (Sweden)

    Martin Längkvist

    2016-04-01

    Full Text Available The availability of high-resolution remote sensing (HRRS data has opened up the possibility for new interesting applications, such as per-pixel classification of individual objects in greater detail. This paper shows how a convolutional neural network (CNN can be applied to multispectral orthoimagery and a digital surface model (DSM of a small city for a full, fast and accurate per-pixel classification. The predicted low-level pixel classes are then used to improve the high-level segmentation. Various design choices of the CNN architecture are evaluated and analyzed. The investigated land area is fully manually labeled into five categories (vegetation, ground, roads, buildings and water, and the classification accuracy is compared to other per-pixel classification works on other land areas that have a similar choice of categories. The results of the full classification and segmentation on selected segments of the map show that CNNs are a viable tool for solving both the segmentation and object recognition task for remote sensing data.

  1. A space weather forecasting system with multiple satellites based on a self-recognizing network.

    Science.gov (United States)

    Tokumitsu, Masahiro; Ishida, Yoshiteru

    2014-05-05

    This paper proposes a space weather forecasting system at geostationary orbit for high-energy electron flux (>2 MeV). The forecasting model involves multiple sensors on multiple satellites. The sensors interconnect and evaluate each other to predict future conditions at geostationary orbit. The proposed forecasting model is constructed using a dynamic relational network for sensor diagnosis and event monitoring. The sensors of the proposed model are located at different positions in space. The satellites for solar monitoring equip with monitoring devices for the interplanetary magnetic field and solar wind speed. The satellites orbit near the Earth monitoring high-energy electron flux. We investigate forecasting for typical two examples by comparing the performance of two models with different numbers of sensors. We demonstrate the prediction by the proposed model against coronal mass ejections and a coronal hole. This paper aims to investigate a possibility of space weather forecasting based on the satellite network with in-situ sensing.

  2. An artificial neural network ensemble model for estimating global solar radiation from Meteosat satellite images

    International Nuclear Information System (INIS)

    Linares-Rodriguez, Alvaro; Ruiz-Arias, José Antonio; Pozo-Vazquez, David; Tovar-Pescador, Joaquin

    2013-01-01

    An optimized artificial neural network ensemble model is built to estimate daily global solar radiation over large areas. The model uses clear-sky estimates and satellite images as input variables. Unlike most studies using satellite imagery based on visible channels, our model also exploits all information within infrared channels of the Meteosat 9 satellite. A genetic algorithm is used to optimize selection of model inputs, for which twelve are selected – eleven 3-km Meteosat 9 channels and one clear-sky term. The model is validated in Andalusia (Spain) from January 2008 through December 2008. Measured data from 83 stations across the region are used, 65 for training and 18 independent ones for testing the model. At the latter stations, the ensemble model yields an overall root mean square error of 6.74% and correlation coefficient of 99%; the generated estimates are relatively accurate and errors spatially uniform. The model yields reliable results even on cloudy days, improving on current models based on satellite imagery. - Highlights: • Daily solar radiation data are generated using an artificial neural network ensemble. • Eleven Meteosat channels observations and a clear sky term are used as model inputs. • Model exploits all information within infrared Meteosat channels. • Measured data for a year from 83 ground stations are used. • The proposed approach has better performance than existing models on daily basis

  3. A Space Weather Forecasting System with Multiple Satellites Based on a Self-Recognizing Network

    Directory of Open Access Journals (Sweden)

    Masahiro Tokumitsu

    2014-05-01

    Full Text Available This paper proposes a space weather forecasting system at geostationary orbit for high-energy electron flux (>2 MeV. The forecasting model involves multiple sensors on multiple satellites. The sensors interconnect and evaluate each other to predict future conditions at geostationary orbit. The proposed forecasting model is constructed using a dynamic relational network for sensor diagnosis and event monitoring. The sensors of the proposed model are located at different positions in space. The satellites for solar monitoring equip with monitoring devices for the interplanetary magnetic field and solar wind speed. The satellites orbit near the Earth monitoring high-energy electron flux. We investigate forecasting for typical two examples by comparing the performance of two models with different numbers of sensors. We demonstrate the prediction by the proposed model against coronal mass ejections and a coronal hole. This paper aims to investigate a possibility of space weather forecasting based on the satellite network with in-situ sensing.

  4. Mobile satellite business networks: A part of the European mobile system

    Science.gov (United States)

    deMateo, M. L.; Jongejans, A.; Loisy, C.; VanHimbeeck, C.; Marchal, J. P.; Borella, A.; Sartori, M.

    1995-01-01

    The European Space Agency (ESA) is presently procuring an L-band payload EMS, to be embarked on the ITALSAT-2 satellite due for launch in early 1996, in order to promote a regional European mobile system. One of the Land Mobile Communication systems supported by EMS is the MSBN (Mobile Satellite Business Network) voice and data system which will offer the services of a business network on a seamless European coverage. This paper will first recall the characteristics of the MSBN system, which is based on quasi-synchronized CDMA (Code Division Multiple Access) techniques in both directions, and then describe the CDMA receivers implementation. Main validation test results will also be reported confirming predicted performances.

  5. High-latitude poynting flux from combined Iridium and SuperDARN data

    Directory of Open Access Journals (Sweden)

    C. L. Waters

    2004-09-01

    Full Text Available Field-aligned currents convey stress between the magnetosphere and ionosphere, and the associated low altitude magnetic and electric fields reflect the flow of electromagnetic energy to the polar ionosphere. We introduce a new technique to measure the global distribution of high latitude Poynting flux, S||, by combining electric field estimates from the Super Dual Auroral Radar Network (SuperDARN with magnetic perturbations derived using magnetometer data from the Iridium satellite constellation. Spherical harmonic methods are used to merge the data sets and calculate S|| for any magnetic local time (MLT from the pole to 60° magnetic latitude (MLAT. The effective spatial resolutions are 2° MLAT, 2h MLT, and the time resolution is about one hour due to the telemetry rate of the Iridium magnetometer data. The technique allows for the assessment of high-latitude net S|| and its spatial distribution on one hour time scales with two key advantages: (1 it yields the net S|| including the contribution of neutral winds; and (2 the results are obtained without recourse to estimates of ionosphere conductivity. We present two examples, 23 November 1999, 14:00-15:00 UT, and 11 March 2000, 16:00-17:00 UT, to test the accuracy of the technique and to illustrate the distributions of S|| that it gives. Comparisons with in-situ S|| estimates from DMSP satellites show agreement to a few mW/m2 and in the locations of S|| enhancements to within the technique's resolution. The total electromagnetic energy flux was 50GW for these events. At auroral latitudes, S|| tends to maximize in the morning and afternoon in regions less than 5° in MLAT by two hours in MLT having S||=10 to 20mW/m2 and total power up to 10GW. The power poleward of the Region 1 currents is about one

  6. High-latitude poynting flux from combined Iridium and SuperDARN data

    Directory of Open Access Journals (Sweden)

    C. L. Waters

    2004-09-01

    Full Text Available Field-aligned currents convey stress between the magnetosphere and ionosphere, and the associated low altitude magnetic and electric fields reflect the flow of electromagnetic energy to the polar ionosphere. We introduce a new technique to measure the global distribution of high latitude Poynting flux, S||, by combining electric field estimates from the Super Dual Auroral Radar Network (SuperDARN with magnetic perturbations derived using magnetometer data from the Iridium satellite constellation. Spherical harmonic methods are used to merge the data sets and calculate S|| for any magnetic local time (MLT from the pole to 60° magnetic latitude (MLAT. The effective spatial resolutions are 2° MLAT, 2h MLT, and the time resolution is about one hour due to the telemetry rate of the Iridium magnetometer data. The technique allows for the assessment of high-latitude net S|| and its spatial distribution on one hour time scales with two key advantages: (1 it yields the net S|| including the contribution of neutral winds; and (2 the results are obtained without recourse to estimates of ionosphere conductivity. We present two examples, 23 November 1999, 14:00-15:00 UT, and 11 March 2000, 16:00-17:00 UT, to test the accuracy of the technique and to illustrate the distributions of S|| that it gives. Comparisons with in-situ S|| estimates from DMSP satellites show agreement to a few mW/m2 and in the locations of S|| enhancements to within the technique's resolution. The total electromagnetic energy flux was 50GW for these events. At auroral latitudes, S|| tends to maximize in the morning and afternoon in regions less than 5° in MLAT by two hours in MLT having S||=10 to 20mW/m2 and total power up to 10GW. The power poleward of the Region 1 currents is about one-third of the total power, indicating significant energy flux over the polar cap.

  7. Activity of iridium-ruthenium and iridium-rhodium adsorption catalysts in decomposition of hydrogen peroxide

    Energy Technology Data Exchange (ETDEWEB)

    Zubovich, I A; Mikhaylov, V A; Migulina, N N [Yaroslavskij Politekhnicheskij Inst. (USSR)

    1976-06-01

    Experimental data for the activities of iridium-ruthenium and iridium-rhodium adsorption catalysts in the decomposition of hydrogen peroxide are considered and the results of magnetic susceptibility measurements are presented. It is concluded that surface structures (complexes) may be formed and that micro-electronic feaures play a role in heterogeneous catalysis.

  8. Design of an Adaptive-Neural Network Attitude Controller of a Satellite using Reaction Wheels

    Directory of Open Access Journals (Sweden)

    Abbas Ajorkar

    2015-04-01

    Full Text Available In this paper, an adaptive attitude control algorithm is developed based on neural network for a satellite using four reaction wheels in a tetrahedron configuration. Then, an attitude control based on feedback linearization control has been designed and uncertainties in the moment of inertia matrix and disturbances torque have been considered. In order to eliminate the effect of these uncertainties, a multilayer neural network with back-propagation law is designed. In this structure, the parameters of the moment of inertia matrix and external disturbances are estimated and used in feedback linearization control law. Finally, the performance of the designed attitude controller is investigated by several simulations.

  9. Detection of land cover change using an Artificial Neural Network on a time-series of MODIS satellite data

    CSIR Research Space (South Africa)

    Olivier, JC

    2007-11-01

    Full Text Available An Artificial Neural Network (ANN) is proposed to detect human-induced land cover change using a sliding window through a time-series of Moderate Resolution Imaging Spectroradiometer (MODIS) satellite surface reflectance pixel values. Training...

  10. Simultaneous ground-satellite observations of daytime traveling ionospheric disturbances over Japan using the GPS-TEC network and the CHAMP satellite

    Science.gov (United States)

    Moral, A. C.; Shiokawa, K.; Otsuka, Y.; Liu, H.; Nishioka, M.; Tsugawa, T.

    2017-12-01

    We report results of simultaneous ground-satellite measurements of daytime travelling ionospheric disturbances (TIDs) over Japan by using the GEONET GPS receiver network and the CHAMP satellite. For the two years of 2002 and 2008, we examined GPS measurements of TEC (Total Electron Content) and neutral and electron densities measured by CHAMP satellite. Total of fifteen TID events with clear southward moving structures in the GPS-TEC measurements are found by simultaneous ground-satellite measurements. On 2002, simultaneous events are only observed in January (1 event) and February (4 events). On 2008, ten events are observed around winter months (January (3 events), February (5), March (1), and October (1)). Neutral and electron densities measured by CHAMP show quasi-periodic fluctuations throughout the passages for all events. The CHAMP satellite crossed at least one clear TID phase front for all the events. We fitted a sinusoidal function to both ground and satellite data to obtain the frequencies and phase of the observed variations. We calculated the corresponding phase relationships between TEC variations and neutral and electron densities measured by CHAMP to categorize the events. In the presentations we report correspondence of these TID structures seen in the simultaneous ground-satellite observations by GPS-TEC and CHAMP, and discuss their phase relationship to identify the source of the daytime TIDs and specify how much of the observed variations are showing clear frequencies/or not in the nature at middle latitudes.

  11. Broadband and scalable mobile satellite communication system for future access networks

    Science.gov (United States)

    Ohata, Kohei; Kobayashi, Kiyoshi; Nakahira, Katsuya; Ueba, Masazumi

    2005-07-01

    Due to the recent market trends, NTT has begun research into next generation satellite communication systems, such as broadband and scalable mobile communication systems. One service application objective is to provide broadband Internet access for transportation systems, temporal broadband access networks and telemetries to remote areas. While these are niche markets the total amount of capacity should be significant. We set a 1-Gb/s total transmission capacity as our goal. Our key concern is the system cost, which means that the system should be unified system with diversified services and not tailored for each application. As satellites account for a large portion of the total system cost, we set the target satellite size as a small, one-ton class dry mass with a 2-kW class payload power. In addition to the payload power and weight, the mobile satellite's frequency band is extremely limited. Therefore, we need to develop innovative technologies that will reduce the weight and maximize spectrum and power efficiency. Another challenge is the need for the system to handle up to 50 dB and a wide data rate range of other applications. This paper describes the key communication system technologies; the frequency reuse strategy, multiplexing scheme, resource allocation scheme, and QoS management algorithm to ensure excellent spectrum efficiency and support a variety of services and quality requirements in the mobile environment.

  12. The design and networking of dynamic satellite constellations for global mobile communication systems

    Science.gov (United States)

    Cullen, Cionaith J.; Benedicto, Xavier; Tafazolli, Rahim; Evans, Barry

    1993-01-01

    Various design factors for mobile satellite systems, whose aim is to provide worldwide voice and data communications to users with hand-held terminals, are examined. Two network segments are identified - the ground segment (GS) and the space segment (SS) - and are seen to be highly dependent on each other. The overall architecture must therefore be adapted to both of these segments, rather than each being optimized according to its own criteria. Terrestrial networks are grouped and called the terrestrial segment (TS). In the SS, of fundamental importance is the constellation altitude. The effect of the altitude on decisions such as constellation design choice and on network aspects like call handover statistics are fundamental. Orbit resonance is introduced and referred to throughout. It is specifically examined for its useful properties relating to GS/SS connectivities.

  13. A small satellite design for deep space network testing and training

    Science.gov (United States)

    McWilliams, Dennis; Slatton, Clint; Norman, Cassidy; Araiza, Joe; Jones, Jason; Tedesco, Mark; Wortman, Michael; Opiela, John; Lett, Pat; Clavenna, Michael

    1993-05-01

    With the continuing exploration of the Solar System and the reemphasis on Earth focused missions, the need for faster data transmission rates has grown. Ka-band could allow a higher data delivery rate over the current X-band, however the adverse effects of the Earth's atmosphere on Ka are as yet unknown. The Deep Space Network and Jet Propulsion Lab have proposed to launch a small satellite that would simultaneously transmit X and Ka signals to test the viability of switching to Ka-band. The Mockingbird Design Team at the University of Texas at Austin applied small satellite design principles to achieve this objective. The Mockingbird design, named BATSAT, incorporates simple, low-cost systems designed for university production and testing. The BATSAT satellite is a 0.64 m diameter, spherical panel led satellite, mounted with solar cells and omni-directional antennae. The antennae configuration negates the need for active attitude control or spin stabilization. The space-frame truss structure was designed for 11 g launch loads while allowing for easy construction and solar-panel mounting. The communication system transmits at 1 mW by carrying the required Ka and X-band transmitters, as well as an S band transmitter used for DSN training. The power system provides the 8.6 W maximum power requirements via silicon solar arrays and nickel-cadmium batteries. The BATSAT satellite will be lofted into an 1163 km, 70 deg orbit by the Pegasus launch system. This orbit fulfills DSN dish slew rate requirements while keeping the satellite out of the heaviest regions of the Van Allen radiation belts. Each of the three DSN stations capable of receiving Ka-band (Goldstone, Canberra, and Madrid) will have an average of 85 minutes of view-time per day over the satellites ten year design life. Mockingbird Designs hopes that its small satellite design will not only be applicable to this specific mission scenario, but that it could easily be modified for instrument capability for

  14. A small satellite design for deep space network testing and training

    Science.gov (United States)

    Mcwilliams, Dennis; Slatton, Clint; Norman, Cassidy; Araiza, Joe; Jones, Jason; Tedesco, Mark; Wortman, Michael; Opiela, John; Lett, Pat; Clavenna, Michael

    1993-01-01

    With the continuing exploration of the Solar System and the reemphasis on Earth focused missions, the need for faster data transmission rates has grown. Ka-band could allow a higher data delivery rate over the current X-band, however the adverse effects of the Earth's atmosphere on Ka are as yet unknown. The Deep Space Network and Jet Propulsion Lab have proposed to launch a small satellite that would simultaneously transmit X and Ka signals to test the viability of switching to Ka-band. The Mockingbird Design Team at the University of Texas at Austin applied small satellite design principles to achieve this objective. The Mockingbird design, named BATSAT, incorporates simple, low-cost systems designed for university production and testing. The BATSAT satellite is a 0.64 m diameter, spherical panel led satellite, mounted with solar cells and omni-directional antennae. The antennae configuration negates the need for active attitude control or spin stabilization. The space-frame truss structure was designed for 11 g launch loads while allowing for easy construction and solar-panel mounting. The communication system transmits at 1 mW by carrying the required Ka and X-band transmitters, as well as an S band transmitter used for DSN training. The power system provides the 8.6 W maximum power requirements via silicon solar arrays and nickel-cadmium batteries. The BATSAT satellite will be lofted into an 1163 km, 70 deg orbit by the Pegasus launch system. This orbit fulfills DSN dish slew rate requirements while keeping the satellite out of the heaviest regions of the Van Allen radiation belts. Each of the three DSN stations capable of receiving Ka-band (Goldstone, Canberra, and Madrid) will have an average of 85 minutes of view-time per day over the satellites ten year design life. Mockingbird Designs hopes that its small satellite design will not only be applicable to this specific mission scenario, but that it could easily be modified for instrument capability for

  15. Iron-57 and iridium-193 Moessbauer spectroscopic studies of supported iron-iridium catalysts

    International Nuclear Information System (INIS)

    Berry, F.J.; Jobson, S.

    1988-01-01

    57 Fe and 193 Ir Moessbauer spectroscopy shows that silica- and alumina-supported iron-iridium catalysts formed by calcination in air contain mixtures of small particle iron(III) oxide and iridium(IV) oxide. The iridium dioxide in both supported catalysts is reduced in hydrogen to metallic iridium. The α-Fe 2 O 3 in the silica supported materials is predominantly reduced in hydrogen to an iron-iridium alloy whilst in the alumina-supported catalyst the iron is stabilised by treatment in hydrogen as iron(II). Treatment of a hydrogen-reduced silica-supported iron catalyst in hydrogen and carbon monoxide is accompanied by the formation of iron carbides. Carbide formation is not observed when the iron-iridium catalysts are treated in similar atmospheres. The results from the bimetallic catalysts are discussed in terms of the hydrogenation of associatively adsorbed carbon monoxide and the selectivity of supported iron-iridium catalysts to methanol formation. (orig.)

  16. Networks systems and operations. [wideband communication techniques for data links with satellites

    Science.gov (United States)

    1975-01-01

    The application of wideband communication techniques for data links with satellites is discussed. A diagram of the demand assigned voice communications system is provided. The development of prototype integrated spacecraft paramps at S- and C-bands is described and the performance of space-qualified paramps is tabulated. The characteristics of a dual parabolic cylinder monopulse zoom antenna for use with the tracking and data relay satellite system (TDRSS) are analyzed. The development of a universally applicable transponder at S-band is reported. A block diagram of the major subassemblies of the S-band transponder is included. The technology aspects of network timing and synchronization of communication systems are to show the use of the Omega navigation system. The telemetry data compression system used during the Skylab program is evaluated.

  17. Comparing land surface phenology derived from satellite and GPS network microwave remote sensing.

    Science.gov (United States)

    Jones, Matthew O; Kimball, John S; Small, Eric E; Larson, Kristine M

    2014-08-01

    The land surface phenology (LSP) start of season (SOS) metric signals the seasonal onset of vegetation activity, including canopy growth and associated increases in land-atmosphere water, energy and carbon (CO2) exchanges influencing weather and climate variability. The vegetation optical depth (VOD) parameter determined from satellite passive microwave remote sensing provides for global LSP monitoring that is sensitive to changes in vegetation canopy water content and biomass, and insensitive to atmosphere and solar illumination constraints. Direct field measures of canopy water content and biomass changes desired for LSP validation are generally lacking due to the prohibitive costs of maintaining regional monitoring networks. Alternatively, a normalized microwave reflectance index (NMRI) derived from GPS base station measurements is sensitive to daily vegetation water content changes and may provide for effective microwave LSP validation. We compared multiyear (2007-2011) NMRI and satellite VOD records at over 300 GPS sites in North America, and their derived SOS metrics for a subset of 24 homogenous land cover sites to investigate VOD and NMRI correspondence, and potential NMRI utility for LSP validation. Significant correlations (P<0.05) were found at 276 of 305 sites (90.5 %), with generally favorable correspondence in the resulting SOS metrics (r (2)=0.73, P<0.001, RMSE=36.8 days). This study is the first attempt to compare satellite microwave LSP metrics to a GPS network derived reflectance index and highlights both the utility and limitations of the NMRI data for LSP validation, including spatial scale discrepancies between local NMRI measurements and relatively coarse satellite VOD retrievals.

  18. Maritime Aerosol Network optical depth measurements and comparison with satellite retrievals from various different sensors

    Science.gov (United States)

    Smirnov, Alexander; Petrenko, Maksym; Ichoku, Charles; Holben, Brent N.

    2017-10-01

    The paper reports on the current status of the Maritime Aerosol Network (MAN) which is a component of the Aerosol Robotic Network (AERONET). A public domain web-based data archive dedicated to MAN activity can be found at https://aeronet.gsfc.nasa.gov/new_web/maritime_aerosol_network.html . Since 2006 over 450 cruises were completed and the data archive consists of more than 6000 measurement days. In this work, we present MAN observations collocated with MODIS Terra, MODIS Aqua, MISR, POLDER, SeaWIFS, OMI, and CALIOP spaceborne aerosol products using a modified version of the Multi-Sensor Aerosol Products Sampling System (MAPSS) framework. Because of different spatio-temporal characteristics of the analyzed products, the number of MAN data points collocated with spaceborne retrievals varied between 1500 matchups for MODIS to 39 for CALIOP (as of August 2016). Despite these unavoidable sampling biases, latitudinal dependencies of AOD differences for all satellite sensors, except for SeaWIFS and POLDER, showed positive biases against ground truth (i.e. MAN) in the southern latitudes (<50° S), and substantial scatter in the Northern Atlantic "dust belt" (5°-15° N). Our analysis did not intend to determine whether satellite retrievals are within claimed uncertainty boundaries, but rather show where bias exists and corrections are needed.

  19. Optimization of communication network topology for navigation sharing among distributed satellites

    Science.gov (United States)

    Dang, Zhaohui; Zhang, Yulin

    2013-01-01

    Navigation sharing among distributed satellites is quite important for coordinated motion and collision avoidance. This paper proposes optimization methods of the communication network topology to achieve navigation sharing. The whole communication network constructing by inter-satellite links are considered as a topology graph. The aim of this paper is to find the communication network topology with minimum communication connections' number (MCCN) in different conditions. It has found that the communication capacity and the number of channels are two key parameters affecting the results. The model of MCCN topology for navigation sharing is established and corresponding method is designed. Two main scenarios, viz., homogeneous case and heterogeneous case, are considered. For the homogeneous case where each member has the same communication capacity, it designs a construction method (Algorithm 1) to find the MCCN topology. For the heterogeneous case, it introduces a modified genetic algorithm (Algorithm 2) to find the MCCN topology. When considering the fact that the number of channels is limited, the Algorithm 2 is further modified by adding a penalized term in the fitness function. The effectiveness of these algorithms is all proved in theoretical. Three examples are further tested to illustrate the methods developed in this paper.

  20. The Satellite Clock Bias Prediction Method Based on Takagi-Sugeno Fuzzy Neural Network

    Science.gov (United States)

    Cai, C. L.; Yu, H. G.; Wei, Z. C.; Pan, J. D.

    2017-05-01

    The continuous improvement of the prediction accuracy of Satellite Clock Bias (SCB) is the key problem of precision navigation. In order to improve the precision of SCB prediction and better reflect the change characteristics of SCB, this paper proposes an SCB prediction method based on the Takagi-Sugeno fuzzy neural network. Firstly, the SCB values are pre-treated based on their characteristics. Then, an accurate Takagi-Sugeno fuzzy neural network model is established based on the preprocessed data to predict SCB. This paper uses the precise SCB data with different sampling intervals provided by IGS (International Global Navigation Satellite System Service) to realize the short-time prediction experiment, and the results are compared with the ARIMA (Auto-Regressive Integrated Moving Average) model, GM(1,1) model, and the quadratic polynomial model. The results show that the Takagi-Sugeno fuzzy neural network model is feasible and effective for the SCB short-time prediction experiment, and performs well for different types of clocks. The prediction results for the proposed method are better than the conventional methods obviously.

  1. Network Performance and Coordination in the Health, Education, Telecommunications System. Satellite Technology Demonstration, Technical Report No. 0422.

    Science.gov (United States)

    Braunstein, Jean; Janky, James M.

    This paper describes the network coordination for the Health, Education, Telecommunications (HET) system. Specifically, it discusses HET network performance as a function of a specially-developed coordination system which was designed to link terrestrial equipment to satellite operations centers. Because all procedures and equipment developed for…

  2. Iridium emissions from Hawaiian volcanoes

    International Nuclear Information System (INIS)

    Finnegan, D.L.; Zoller, W.H.; Miller, T.M.

    1988-01-01

    Particle and gas samples were collected at Mauna Loa volcano during and after its eruption in March and April, 1984 and at Kilauea volcano in 1983, 1984, and 1985 during various phases of its ongoing activity. In the last two Kilauea sampling missions, samples were collected during eruptive activity. The samples were collected using a filterpack system consisting of a Teflon particle filter followed by a series of 4 base-treated Whatman filters. The samples were analyzed by INAA for over 40 elements. As previously reported in the literature, Ir was first detected on particle filters at the Mauna Loa Observatory and later from non-erupting high temperature vents at Kilauea. Since that time Ir was found in samples collected at Kilauea and Mauna Loa during fountaining activity as well as after eruptive activity. Enrichment factors for Ir in the volcanic fumes range from 10,000 to 100,000 relative to BHVO. Charcoal impregnated filters following a particle filter were collected to see if a significant amount of the Ir was in the gas phase during sample collection. Iridium was found on charcoal filters collected close to the vent, no Ir was found on the charcoal filters. This indicates that all of the Ir is in particulate form very soon after its release. Ratios of Ir to F and Cl were calculated for the samples from Mauna Loa and Kilauea collected during fountaining activity. The implications for the KT Ir anomaly are still unclear though as Ir was not found at volcanoes other than those at Hawaii. Further investigations are needed at other volcanoes to ascertain if basaltic volcanoes other than hot spots have Ir enrichments in their fumes

  3. Iridium emissions from Hawaiian volcanoes

    Science.gov (United States)

    Finnegan, D. L.; Zoller, W. H.; Miller, T. M.

    1988-01-01

    Particle and gas samples were collected at Mauna Loa volcano during and after its eruption in March and April, 1984 and at Kilauea volcano in 1983, 1984, and 1985 during various phases of its ongoing activity. In the last two Kilauea sampling missions, samples were collected during eruptive activity. The samples were collected using a filterpack system consisting of a Teflon particle filter followed by a series of 4 base-treated Whatman filters. The samples were analyzed by INAA for over 40 elements. As previously reported in the literature, Ir was first detected on particle filters at the Mauna Loa Observatory and later from non-erupting high temperature vents at Kilauea. Since that time Ir was found in samples collected at Kilauea and Mauna Loa during fountaining activity as well as after eruptive activity. Enrichment factors for Ir in the volcanic fumes range from 10,000 to 100,000 relative to BHVO. Charcoal impregnated filters following a particle filter were collected to see if a significant amount of the Ir was in the gas phase during sample collection. Iridium was found on charcoal filters collected close to the vent, no Ir was found on the charcoal filters. This indicates that all of the Ir is in particulate form very soon after its release. Ratios of Ir to F and Cl were calculated for the samples from Mauna Loa and Kilauea collected during fountaining activity. The implications for the KT Ir anomaly are still unclear though as Ir was not found at volcanoes other than those at Hawaii. Further investigations are needed at other volcanoes to ascertain if basaltic volcanoes other than hot spots have Ir enrichments in their fumes.

  4. Advanced Communication Technology Satellite (ACTS) Very Small Aperture Terminal (VSAT) Network Control Performance

    Science.gov (United States)

    Coney, T. A.

    1996-01-01

    This paper discusses the performance of the network control function for the Advanced Communications Technology Satellite (ACTS) very small aperture terminal (VSAT) full mesh network. This includes control of all operational activities such as acquisition, synchronization, timing and rain fade compensation as well as control of all communications activities such as on-demand integrated services (voice, video, and date) connects and disconnects Operations control is provided by an in-band orderwire carried in the baseboard processor (BBP) control burst, the orderwire burst, the reference burst, and the uplink traffic burst. Communication services are provided by demand assigned multiple access (DAMA) protocols. The ACTS implementation of DAMA protocols ensures both on-demand and integrated voice, video and data services. Communications services control is also provided by the in-band orderwire but uses only the reference burst and the uplink traffic burst. The performance of the ACTS network control functions have been successfully tested during on-orbit checkout and in various VSAT networks in day to day operations. This paper discusses the network operations and services control performance.

  5. Neural networks based three-axis satellite attitude control using only magnetic torquers

    International Nuclear Information System (INIS)

    Sivaprakash, N.; Shanmugam, J.; Natarajan, P.

    2005-01-01

    Full text: Magnetic control is a favorable way to stabilize small satellites. Often, the hardware is simple and lightweight, and does not degrade or change mass over time. However, a magnetic control system does have some disadvantages and limitations. The control, which is in the form of magnetic moment, can only be applied perpendicular to the local magnetic field. In addition, there is uncertainty in the Earth magnetic field models due to the complicated dynamic nature of the field. Also, the magnetic hardware and the spacecraft can interact, causing both to behave in undesirable ways. To overcome these limitations some intelligence is incorporated in the controller. In this paper, control laws are developed to stabilize spacecraft on Three axes. The motivation for this project is ANUSAT, which is a micro-satellite under development at Anna University in collaboration with ISRO. This control could be carried out solely with satellite's magnetometer measurements and its position in orbit. The magnetic dipole moment for control is: M = K p (B o - B r ) + K d (dB o /dt - dB r /dt) Where B o is the measured magnetic field, B r is the reference magnetic field, and K p and K d are the control position and rate gains respectively. The value of the controller gains are selected by the Intelligent Neural Network System in the feedback path. Control laws are numerically tested to show that the magnetic control system works within resolution limits

  6. Estimation of solar radiation over Turkey using artificial neural network and satellite data

    International Nuclear Information System (INIS)

    Senkal, Ozan; Kuleli, Tuncay

    2009-01-01

    This study introduces artificial neural networks (ANNs) for the estimation of solar radiation in Turkey (26-45 E and 36-42 N). Resilient propagation (RP), Scale conjugate gradient (SCG) learning algorithms and logistic sigmoid transfer function were used in the network. In order to train the neural network, meteorological data for the period from August 1997 to December 1997 for 12 cities (Antalya, Artvin, Edirne, Kayseri, Kuetahya, Van, Adana, Ankara, Istanbul, Samsun, Izmir, Diyarbakir) spread over Turkey were used as training (nine stations) and testing (three stations) data. Meteorological and geographical data (latitude, longitude, altitude, month, mean diffuse radiation and mean beam radiation) are used in the input layer of the network. Solar radiation is the output. However, solar radiation has been estimated as monthly mean daily sum by using Meteosat-6 satellite C3 D data in the visible range over 12 cities in Turkey. Digital counts of satellite data were converted into radiances and these are used to calculate the albedos. Using the albedo, the cloud cover index of each pixel was constructed. Diffuse and direct component of horizontal irradiation were calculated as a function of optical air mass, turbidity factor and Rayleigh optical thickness for clear-sky. Using the relation between clear-sky index and cloud cover index, the solar irradiance for any pixel is calculated for Physical method. RMS between the estimated and ground values for monthly mean daily sum with ANN and Physical method values have been found as 2.32 MJ m -2 (54 W/m 2 ) and 2.75 MJ m -2 (64 W/m 2 ) (training cities), 3.94 MJ m -2 (91 W/m 2 ) and 5.37 MJ m -2 (125 W/m 2 ) (testing cities), respectively

  7. IDMA-Based MAC Protocol for Satellite Networks with Consideration on Channel Quality

    Directory of Open Access Journals (Sweden)

    Gongliang Liu

    2014-01-01

    Full Text Available In order to overcome the shortcomings of existing medium access control (MAC protocols based on TDMA or CDMA in satellite networks, interleave division multiple access (IDMA technique is introduced into satellite communication networks. Therefore, a novel wide-band IDMA MAC protocol based on channel quality is proposed in this paper, consisting of a dynamic power allocation algorithm, a rate adaptation algorithm, and a call admission control (CAC scheme. Firstly, the power allocation algorithm combining the technique of IDMA SINR-evolution and channel quality prediction is developed to guarantee high power efficiency even in terrible channel conditions. Secondly, the effective rate adaptation algorithm, based on accurate channel information per timeslot and by the means of rate degradation, can be realized. What is more, based on channel quality prediction, the CAC scheme, combining the new power allocation algorithm, rate scheduling, and buffering strategies together, is proposed for the emerging IDMA systems, which can support a variety of traffic types, and offering quality of service (QoS requirements corresponding to different priority levels. Simulation results show that the new wide-band IDMA MAC protocol can make accurate estimation of available resource considering the effect of multiuser detection (MUD and QoS requirements of multimedia traffic, leading to low outage probability as well as high overall system throughput.

  8. Modulation Classification of Satellite Communication Signals Using Cumulants and Neural Networks

    Science.gov (United States)

    Smith, Aaron; Evans, Michael; Downey, Joseph

    2017-01-01

    National Aeronautics and Space Administration (NASA)'s future communication architecture is evaluating cognitive technologies and increased system intelligence. These technologies are expected to reduce the operational complexity of the network, increase science data return, and reduce interference to self and others. In order to increase situational awareness, signal classification algorithms could be applied to identify users and distinguish sources of interference. A significant amount of previous work has been done in the area of automatic signal classification for military and commercial applications. As a preliminary step, we seek to develop a system with the ability to discern signals typically encountered in satellite communication. Proposed is an automatic modulation classifier which utilizes higher order statistics (cumulants) and an estimate of the signal-to-noise ratio. These features are extracted from baseband symbols and then processed by a neural network for classification. The modulation types considered are phase-shift keying (PSK), amplitude and phase-shift keying (APSK),and quadrature amplitude modulation (QAM). Physical layer properties specific to the Digital Video Broadcasting - Satellite- Second Generation (DVB-S2) standard, such as pilots and variable ring ratios, are also considered. This paper will provide simulation results of a candidate modulation classifier, and performance will be evaluated over a range of signal-to-noise ratios, frequency offsets, and nonlinear amplifier distortions.

  9. Iridium-192 sources production for brachytherapy use

    International Nuclear Information System (INIS)

    Rostelato, Maria Elisa Chuery Martins

    1997-01-01

    The incidence of cancer increases every year in Brazil and turns out to be one of the most important causes of mortality. Some of the patients are treated with brachytherapy, a form of lesion treatment which is based on the insertion of sources into tumors, in this particular case, activated iridium wires. During this process, the ionizing radiation efficiently destroys the malignant cells. These iridium wires have a nucleus made out of an iridium-platinum alloy 20-30/70-80 of 0,1 mm in diameter either coated by platinum or encased in a platinum tube. The technique consists in irradiating the wire in the reactor neutron flux in order to produce iridium-192. The linear activity goes from 1 mCi/cm to 4 mCi/cm and the basic characteristic, which is required, is the homogeneity of the activation along the wire. It should not present a dispersion exceeding 5% on a wire measuring 50 cm in length, 0.5 mm or 0.3 mm in diameter. Several experiments were carried out in order to define the activation parameters. Wires from different origins were analyzed. It was concluded that United States of America and France wires were found to be perfectly adequate for brachytherapy purposes and have therefore been sent to specialized hospitals and successfully applied to cancer patients. Considering that the major purpose of this work is to make this product more accessible in Brazil, at a cost reflecting the Brazilian reality, the IPEN is promoting the preparation of iridium-192 sources to be used in brachytherapy, on a national level. (author)

  10. Welding of iridium heat source capsule components

    International Nuclear Information System (INIS)

    Mustaleski, T.M.; Yearwood, J.C.; Burgan, C.E.; Green, L.A.

    1991-01-01

    Interplanetary spacecraft have long used radioisotope thermoelectric generators (RTG) to produce power for instrumentation. These RTG produce electrical energy from the heat generated through the radioactive decay of plutonium-238. The plutonium is present as a ceramic pellet of plutonium oxide. The pellet is encapsulated in a containment shell of iridium. Iridium is the material of choice for these capsules because of its compatibility with the plutonium dioxide. The high-energy beam welding (electron beam and laser) processes used in the fabrication of the capsules has not been published. These welding procedures were originally developed at the Mound Laboratories and have been adapted for use at the Oak Ridge Y-12 Plant. The work involves joining of thin material in small sizes to exacting tolerances. There are four different electron beam welds on each capsule, with one procedure being used in three locations. There is also a laser weld used to seal the edges of a sintered frit assembly. An additional electron beam weld is also performed to seal each of the iridium blanks in a stainless steel waster sheet prior to forming. In the transfer of these welding procedures from one facility to another, a number of modifications were necessary. These modifications are discussed in detail, as well as the inherent problems in making welds in material which is only 0.005 in. thick. In summary, the paper discusses the welding of thin components of iridium using the high energy beam processes. While the peculiarities of iridium are pertinent to the discussion, much of the information is of general interest to the users of these processes. This is especially true of applications involving thin materials and high-precision assemblies

  11. A New Damage Assessment Method by Means of Neural Network and Multi-Sensor Satellite Data

    Directory of Open Access Journals (Sweden)

    Alessandro Piscini

    2017-08-01

    Full Text Available Artificial Neural Network (ANN is a valuable and well-established inversion technique for the estimation of geophysical parameters from satellite images. After training, ANNs are able to generate very fast products for several types of applications. Satellite remote sensing is an efficient way to detect and map strong earthquake damage for contributing to post-disaster activities during emergency phases. This work aims at presenting an application of the ANN inversion technique addressed to the evaluation of building collapse ratio (CR, defined as the number of collapsed buildings with respect to the total number of buildings in a city block, by employing optical and SAR satellite data. This is done in order to directly relate changes in images with damage that has occurred during strong earthquakes. Furthermore, once they have been trained, neural networks can be used rapidly at application stage. The goal was to obtain a general tool suitable for re-use in different scenarios. An ANN has been implemented in order to emulate a regression model and to estimate the CR as a continuous function. The adopted ANN has been trained using some features obtained from optical and Synthetic Aperture Radar (SAR images, as inputs, and the corresponding values of collapse ratio obtained from the survey of the 2010 M7 Haiti Earthquake, i.e., as target output. As regards the optical data, we selected three change parameters: the Normalized Difference Index (NDI, the Kullback–Leibler divergence (KLD, and Mutual Information (MI. Concerning the SAR images, the Intensity Correlation Difference (ICD and the KLD parameters have been considered. Exploiting an object-oriented approach, a segmentation of the study area into several regions has been performed. In particular, damage maps have been generated by considering a set of polygons (in which satellite parameters have been calculated extracted from the open source Open Street Map (OSM geo-database. The trained

  12. Evolving earth-based and in-situ satellite network architectures for Mars communications and navigation support

    Science.gov (United States)

    Hastrup, Rolf; Weinberg, Aaron; McOmber, Robert

    1991-09-01

    Results of on-going studies to develop navigation/telecommunications network concepts to support future robotic and human missions to Mars are presented. The performance and connectivity improvements provided by the relay network will permit use of simpler, lower performance, and less costly telecom subsystems for the in-situ mission exploration elements. Orbiting relay satellites can serve as effective navigation aids by supporting earth-based tracking as well as providing Mars-centered radiometric data for mission elements approaching, in orbit, or on the surface of Mars. The relay satellite orbits may be selected to optimize navigation aid support and communication coverage for specific mission sets.

  13. Migration from a terrestrial network to a satellite network - Risks/constraints/payoffs

    Science.gov (United States)

    Homon, K. A.

    The migration method is regarded as a straightforward approach to a customer's requirements while addressing the known constraints. The migration plan organizes, controls, and communicates the extensive number of tasks, schedules, technical details, and node-by-node conversion details using the selected migration method as its cornerstone. It is noted that a successful migration plan must also provide the flexibility and robustness necessary to handle the unforeseen changes that will occur over the three- to four-year migration period. A baseline network provides a solid structural underpinning for the migration plan.

  14. Quantum communication for satellite-to-ground networks with partially entangled states

    International Nuclear Information System (INIS)

    Chen Na; Quan Dong-Xiao; Pei Chang-Xing; Yang-Hong

    2015-01-01

    To realize practical wide-area quantum communication, a satellite-to-ground network with partially entangled states is developed in this paper. For efficiency and security reasons, the existing method of quantum communication in distributed wireless quantum networks with partially entangled states cannot be applied directly to the proposed quantum network. Based on this point, an efficient and secure quantum communication scheme with partially entangled states is presented. In our scheme, the source node performs teleportation only after an end-to-end entangled state has been established by entanglement swapping with partially entangled states. Thus, the security of quantum communication is guaranteed. The destination node recovers the transmitted quantum bit with the help of an auxiliary quantum bit and specially defined unitary matrices. Detailed calculations and simulation analyses show that the probability of successfully transferring a quantum bit in the presented scheme is high. In addition, the auxiliary quantum bit provides a heralded mechanism for successful communication. Based on the critical components that are presented in this article an efficient, secure, and practical wide-area quantum communication can be achieved. (paper)

  15. Long Short-Term Memory Neural Networks for Online Disturbance Detection in Satellite Image Time Series

    Directory of Open Access Journals (Sweden)

    Yun-Long Kong

    2018-03-01

    Full Text Available A satellite image time series (SITS contains a significant amount of temporal information. By analysing this type of data, the pattern of the changes in the object of concern can be explored. The natural change in the Earth’s surface is relatively slow and exhibits a pronounced pattern. Some natural events (for example, fires, floods, plant diseases, and insect pests and human activities (for example, deforestation and urbanisation will disturb this pattern and cause a relatively profound change on the Earth’s surface. These events are usually referred to as disturbances. However, disturbances in ecosystems are not easy to detect from SITS data, because SITS contain combined information on disturbances, phenological variations and noise in remote sensing data. In this paper, a novel framework is proposed for online disturbance detection from SITS. The framework is based on long short-term memory (LSTM networks. First, LSTM networks are trained by historical SITS. The trained LSTM networks are then used to predict new time series data. Last, the predicted data are compared with real data, and the noticeable deviations reveal disturbances. Experimental results using 16-day compositions of the moderate resolution imaging spectroradiometer (MOD13Q1 illustrate the effectiveness and stability of the proposed approach for online disturbance detection.

  16. Neural network multispectral satellite images classification of volcanic ash plumes in a cloudy scenario

    Directory of Open Access Journals (Sweden)

    Matteo Picchiani

    2015-03-01

    Full Text Available This work shows the potential use of neural networks in the characterization of eruptive events monitored by satellite, through fast and automatic classification of multispectral images. The algorithm has been developed for the MODIS instrument and can easily be extended to other similar sensors. Six classes have been defined paying particular attention to image regions that represent the different surfaces that could possibly be found under volcanic ash clouds. Complex cloudy scenarios composed by images collected during the Icelandic eruptions of the Eyjafjallajökull (2010 and Grimsvötn (2011 volcanoes have been considered as test cases. A sensitivity analysis on the MODIS TIR and VIS channels has been performed to optimize the algorithm. The neural network has been trained with the first image of the dataset, while the remaining data have been considered as independent validation sets. Finally, the neural network classifier’s results have been compared with maps classified with several interactive procedures performed in a consolidated operational framework. This comparison shows that the automatic methodology proposed achieves a very promising performance, showing an overall accuracy greater than 84%, for the Eyjafjalla - jökull event, and equal to 74% for the Grimsvötn event. 

  17. A FD/DAMA network architecture for the first generation land mobile satellite services

    Science.gov (United States)

    Yan, T.-Y.; Wang, C.; Cheng, U.; Dessouky, K.; Rafferty, W.

    1989-01-01

    A frequency division/demand assigned multiple access (FD/DAMA) network architecture for the first-generation land mobile satellite services is presented. Rationales and technical approaches are described. In this architecture, each mobile subscriber must follow a channel access protocol to make a service request to the network management center before transmission for either open-end or closed-end services. Open-end service requests will be processed on a blocked call cleared basis, while closed-end requests will be processed on a first-come-first-served basis. Two channel access protocols are investigated, namely, a recently proposed multiple channel collision resolution scheme which provides a significantly higher useful throughput, and the traditional slotted Aloha scheme. The number of channels allocated for either open-end or closed-end services can be adaptively changed according to aggregated traffic requests. Both theoretical and simulation results are presented. Theoretical results have been verified by simulation on the JPL network testbed.

  18. Effective Area and Charge Density of Iridium Oxide Neural Electrodes

    International Nuclear Information System (INIS)

    Harris, Alexander R.; Paolini, Antonio G.; Wallace, Gordon G.

    2017-01-01

    The effective electrode area and charge density of iridium metal and anodically activated iridium has been measured by optical and electrochemical techniques. The degree of electrode activation could be assessed by changes in electrode colour. The reduction charge, activation charge, number of activation pulses and charge density were all strongly correlated. Activated iridium showed slow electron transfer kinetics for reduction of a dissolved redox species. At fast voltammetric scan rates the linear diffusion electroactive area was unaffected by iridium activation. At slow voltammetric scan rates, the steady state diffusion electroactive area was reduced by iridium activation. The steady state current was consistent with a ring electrode geometry, with lateral resistance reducing the electrode area. Slow electron transfer on activated iridium would require a larger overpotential to reduce or oxidise dissolved species in tissue, limiting the electrodes charge capacity but also reducing the likelihood of generating toxic species in vivo.

  19. Assimilation of Real-Time Satellite And Human Sensor Networks for Modeling Natural Disasters

    Science.gov (United States)

    Aulov, O.; Halem, M.; Lary, D. J.

    2011-12-01

    We describe the development of underlying technologies needed to address the merging of a web of real time satellite sensor Web (SSW) and Human Sensor Web (HSW) needed to augment the US response to extreme events. As an initial prototyping step and use case scenario, we consider the development of two major system tools that can be transitioned from research to the responding operational agency for mitigating coastal oil spills. These tools consist of the capture of Situation Aware (SA) Social Media (SM) Data, and assimilation of the processed information into forecasting models to provide incident decision managers with interactive virtual spatial temporal animations superimposed with probabilistic data estimates. The system methodologies are equally applicable to the wider class of extreme events such as plume dispersions from volcanoes or massive fires, major floods, hurricane impacts, radioactive isotope dispersions from nuclear accidents, etc. A successful feasibility demonstration of this technology has been shown in the case of the Deepwater Horizon Oil Spill where Human Sensor Networks have been combined with a geophysical model to perform parameter assessments. Flickr images of beached oil were mined from the spill area, geolocated and timestamped and converted into geophysical data. This data was incorporated into General NOAA Operational Modeling Environment (GNOME), a Lagrangian forecast model that uses near real-time surface winds, ocean currents, and satellite shape profiles of oil to generate a forecast of plume movement. As a result, improved estimates of diffusive coefficients and rates of oil spill were determined. Current approaches for providing satellite derived oil distributions are collected from a satellite sensor web of operational and research sensors from many countries, and a manual analysis is performed by NESDIS. A real time SA HSW processing system based on geolocated SM data from sources such as Twitter, Flickr, YouTube etc., greatly

  20. A Topology Control Strategy with Reliability Assurance for Satellite Cluster Networks in Earth Observation

    Directory of Open Access Journals (Sweden)

    Qing Chen

    2017-02-01

    Full Text Available This article investigates the dynamic topology control problemof satellite cluster networks (SCNs in Earth observation (EO missions by applying a novel metric of stability for inter-satellite links (ISLs. The properties of the periodicity and predictability of satellites’ relative position are involved in the link cost metric which is to give a selection criterion for choosing the most reliable data routing paths. Also, a cooperative work model with reliability is proposed for the situation of emergency EO missions. Based on the link cost metric and the proposed reliability model, a reliability assurance topology control algorithm and its corresponding dynamic topology control (RAT strategy are established to maximize the stability of data transmission in the SCNs. The SCNs scenario is tested through some numeric simulations of the topology stability of average topology lifetime and average packet loss rate. Simulation results show that the proposed reliable strategy applied in SCNs significantly improves the data transmission performance and prolongs the average topology lifetime.

  1. Artificial Neural Networks to reconstruct incomplete satellite data: application to the Mediterranean Sea Surface Temperature

    Directory of Open Access Journals (Sweden)

    E. Pisoni

    2008-02-01

    Full Text Available Satellite data can be very useful in applications where extensive spatial information is needed, but sometimes missing data due to presence of clouds can affect data quality. In this study a methodology for pre-processing sea surface temperature (SST data is proposed. The methodology, that processes measures in the visible wavelength, is based on an Artificial Neural Network (ANN system. The effectiveness of the procedure has been also evaluated comparing results obtained using an interpolation method. After the methodology has been identified, a validation is performed on 3 different episodes representative of SST variability in the Mediterranean sea. The proposed technique can process SST NOAA/AVHRR data to simulate severe storm episodes by means of prognostic meteorological models.

  2. Coupling of ground biosensor networks for water monitoring with satellite observations in assessing Leptospirosis

    Science.gov (United States)

    Skouloudis, A. N.; Rickerby, D. G.

    2012-12-01

    Leptospirosis became recently a major public-health problem that is closely related with the environment (Nature review Oct 2009, Vol 7, pp 736-747). This disease originates from zoonotic pathogens associated with asymptomatic rodent carriers. Unfortunately, it effects human populations via various direct and indirect routes. This disease can claim many victims with large outbreaks during natural disasters or floods occurring during seasonal conditions. The severity of the illness ranges from subclinical infection to a fulminating fatal disease. Improved water quality monitoring techniques based on biosensor, optical, micro-fluidic and information technologies are leading to radical changes in our ability to perceive and monitor the aquatic environment. Biosensors are capable of providing specific, high spatial resolution information and allow unattended operation that will be particularly useful for water borne related diseases. Current research on biosensors is leading to solutions to problems for several contaminants that were previously irresolvable due to their high degree of complexity. Networking of the sensors enables sensitive monitoring systems allowing real-time monitoring of pollutants and facilitates data transmission between the measurement points and central control stations for continuous surveillance and to provide an early warning capability. The application of intelligent biosensor networks for water quality monitoring and detection of localized sources of pollution are discussed together with the setting up of a methodology that utilizes images from satellite coupled with in-situ sensors for anticipating the zones of potential evolution of this disease and assessing the population at risk. Environmental and climatic conditions that are associated the outbreaks are described and the rational of combining earth observations coupled with advanced in-situ biosensors is explained. The implementation of sensor networks for data collection and exposure

  3. Impedance analysis of nanostructured iridium oxide electrocatalysts

    International Nuclear Information System (INIS)

    Sunde, Svein; Lervik, Ingrid Anne; Tsypkin, Mikhail; Owe, Lars-Erik

    2010-01-01

    Impedance data were collected for nanostructured iridium oxide (NIROF) at potentials below those at which the oxygen evolution reaction commences. The measurements included thin oxide films covered by a protective Nafion TM layer and thicker composite Nafion TM -oxide electrodes. The time constants for the low-frequency diffusion process were approximately the same for both types of electrodes, indicating diffusion in individual particles in the porous electrode rather than across the film. The diffusion process involves trapping of the diffusion species. The impedance data indicated that there were no significant variations in conductivity of the oxides with potential, as opposed to what appears to be the case for anodically formed iridium oxide films (AIROF). This is interpreted to reflect differences in electronic structure between NIROF and AIROF.

  4. Estimating surface longwave radiative fluxes from satellites utilizing artificial neural networks

    Science.gov (United States)

    Nussbaumer, Eric A.; Pinker, Rachel T.

    2012-04-01

    A novel approach for calculating downwelling surface longwave (DSLW) radiation under all sky conditions is presented. The DSLW model (hereafter, DSLW/UMD v2) similarly to its predecessor, DSLW/UMD v1, is driven with a combination of Moderate Resolution Imaging Spectroradiometer (MODIS) level-3 cloud parameters and information from the European Centre for Medium-Range Weather Forecasts (ECMWF) ERA-Interim model. To compute the clear sky component of DSLW a two layer feed-forward artificial neural network with sigmoid hidden neurons and linear output neurons is implemented; it is trained with simulations derived from runs of the Rapid Radiative Transfer Model (RRTM). When computing the cloud contribution to DSLW, the cloud base temperature is estimated by using an independent artificial neural network approach of similar architecture as previously mentioned, and parameterizations. The cloud base temperature neural network is trained using spatially and temporally co-located MODIS and CloudSat Cloud Profiling Radar (CPR) and the Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observation (CALIPSO) Cloud-Aerosol Lidar with Orthogonal Polarization (CALIOP) observations. Daily average estimates of DSLW from 2003 to 2009 are compared against ground measurements from the Baseline Surface Radiation Network (BSRN) giving an overall correlation coefficient of 0.98, root mean square error (rmse) of 15.84 W m-2, and a bias of -0.39 W m-2. This is an improvement over an earlier version of the model (DSLW/UMD v1) which for the same time period has an overall correlation coefficient 0.97 rmse of 17.27 W m-2, and bias of 0.73 W m-2.

  5. Virtual target tracking (VTT) as applied to mobile satellite communication networks

    Science.gov (United States)

    Amoozegar, Farid

    1999-08-01

    Traditionally, target tracking has been used for aerospace applications, such as, tracking highly maneuvering targets in a cluttered environment for missile-to-target intercept scenarios. Although the speed and maneuvering capability of current aerospace targets demand more efficient algorithms, many complex techniques have already been proposed in the literature, which primarily cover the defense applications of tracking methods. On the other hand, the rapid growth of Global Communication Systems, Global Information Systems (GIS), and Global Positioning Systems (GPS) is creating new and more diverse challenges for multi-target tracking applications. Mobile communication and computing can very well appreciate a huge market for Cellular Communication and Tracking Devices (CCTD), which will be tracking networked devices at the cellular level. The objective of this paper is to introduce a new concept, i.e., Virtual Target Tracking (VTT) for commercial applications of multi-target tracking algorithms and techniques as applied to mobile satellite communication networks. It would be discussed how Virtual Target Tracking would bring more diversity to target tracking research.

  6. Classification of boreal forest by satellite and inventory data using neural network approach

    Science.gov (United States)

    Romanov, A. A.

    2012-12-01

    The main objective of this research was to develop methodology for boreal (Siberian Taiga) land cover classification in a high accuracy level. The study area covers the territories of Central Siberian several parts along the Yenisei River (60-62 degrees North Latitude): the right bank includes mixed forest and dark taiga, the left - pine forests; so were taken as a high heterogeneity and statistically equal surfaces concerning spectral characteristics. Two main types of data were used: time series of middle spatial resolution satellite images (Landsat 5, 7 and SPOT4) and inventory datasets from the nature fieldworks (used for training samples sets preparation). Method of collecting field datasets included a short botany description (type/species of vegetation, density, compactness of the crowns, individual height and max/min diameters representative of each type, surface altitude of the plot), at the same time the geometric characteristic of each training sample unit corresponded to the spatial resolution of satellite images and geo-referenced (prepared datasets both of the preliminary processing and verification). The network of test plots was planned as irregular and determined by the landscape oriented approach. The main focus of the thematic data processing has been allocated for the use of neural networks (fuzzy logic inc.); therefore, the results of field studies have been converting input parameter of type / species of vegetation cover of each unit and the degree of variability. Proposed approach involves the processing of time series separately for each image mainly for the verification: shooting parameters taken into consideration (time, albedo) and thus expected to assess the quality of mapping. So the input variables for the networks were sensor bands, surface altitude, solar angels and land surface temperature (for a few experiments); also given attention to the formation of the formula class on the basis of statistical pre-processing of results of

  7. Simultaneous iridium catalysed oxidation and enzymatic reduction employing orthogonal reagents

    NARCIS (Netherlands)

    Mutti, Francesco G.; Orthaber, Andreas; Schrittwieser, Joerg H.; Vries, Johannes G. de; Pietschnig, Rudolf; Kroutil, Wolfgang

    2010-01-01

    An iridium catalysed oxidation was coupled concurrently to an asymmetric biocatalytic reduction in one-pot; thus it was shown for the first time that iridium- and alcohol dehydrogenase-catalysed redox reactions are compatible. As a model system racemic chlorohydrins were transformed to

  8. pH-sensor properties of electrochemically grown iridium oxide

    NARCIS (Netherlands)

    Olthuis, Wouter; Robben, M.A.M.; Bergveld, Piet; Bos, M.; van der Linden, W.E.

    1990-01-01

    The open-circuit potential of an electrochemically grown iridium oxide film is measured and shows a pH sensitivity between −60 and −80 mV/pH. This sensitivity is found to depend on the state of oxidation of the iridium oxide film; for a higher state of oxidation (or more of the oxide in the high

  9. Weldability of general purpose heat source new-process iridium

    International Nuclear Information System (INIS)

    Kanne, W.R.

    1987-01-01

    Weldability tests on General Purpose Heat Source (GPHS) iridium capsules showed that a new iridium fabrication process reduced susceptibility to underbead cracking. Seventeen capsules were welded (a total of 255 welds) in four categories and the number of cracks in each weld was measured

  10. Synthesis of benzimidazoles via iridium-catalyzed acceptorless dehydrogenative coupling.

    Science.gov (United States)

    Sun, Xiang; Lv, Xiao-Hui; Ye, Lin-Miao; Hu, Yu; Chen, Yan-Yan; Zhang, Xue-Jing; Yan, Ming

    2015-07-21

    Iridium-catalyzed acceptorless dehydrogenative coupling of tertiary amines and arylamines has been developed. A number of benzimidazoles were prepared in good yields. An iridium-mediated C-H activation mechanism is suggested. This finding represents a novel strategy for the synthesis of benzimidazoles.

  11. Using remote sensing satellite data and artificial neural network for prediction of potato yield in Bangladesh

    Science.gov (United States)

    Akhand, Kawsar; Nizamuddin, Mohammad; Roytman, Leonid; Kogan, Felix

    2016-09-01

    Potato is one of the staple foods and cash crops in Bangladesh. It is widely cultivated in all of the districts and ranks second after rice in production. Bangladesh is the fourth largest potato producer in Asia and is among the world's top 15 potato producing countries. The weather condition for potato cultivation is favorable during the sowing, growing and harvesting period. It is a winter crop and is cultivated during the period of November to March. Bangladesh is mainly an agricultural based country with respect to agriculture's contribution to GDP, employment and consumption. Potato is a prominent crop in consideration of production, its internal demand and economic value. Bangladesh has a big economic activities related to potato cultivation and marketing, especially the economic relations among farmers, traders, stockers and cold storage owners. Potato yield prediction before harvest is an important issue for the Government and the stakeholders in managing and controlling the potato market. Advanced very high resolution radiometer (AVHRR) based satellite data product vegetation health indices VCI (vegetation condition index) and TCI (temperature condition index) are used as predictors for early prediction. Artificial neural network (ANN) is used to develop a prediction model. The simulated result from this model is encouraging and the error of prediction is less than 10%.

  12. Using artificial neural network and satellite data to predict rice yield in Bangladesh

    Science.gov (United States)

    Akhand, Kawsar; Nizamuddin, Mohammad; Roytman, Leonid; Kogan, Felix; Goldberg, Mitch

    2015-09-01

    Rice production in Bangladesh is a crucial part of the national economy and providing about 70 percent of an average citizen's total calorie intake. The demand for rice is constantly rising as the new populations are added in every year in Bangladesh. Due to the increase in population, the cultivation land decreases. In addition, Bangladesh is faced with production constraints such as drought, flooding, salinity, lack of irrigation facilities and lack of modern technology. To maintain self sufficiency in rice, Bangladesh will have to continue to expand rice production by increasing yield at a rate that is at least equal to the population growth until the demand of rice has stabilized. Accurate rice yield prediction is one of the most important challenges in managing supply and demand of rice as well as decision making processes. Artificial Neural Network (ANN) is used to construct a model to predict Aus rice yield in Bangladesh. Advanced Very High Resolution Radiometer (AVHRR)-based remote sensing satellite data vegetation health (VH) indices (Vegetation Condition Index (VCI) and Temperature Condition Index (TCI) are used as input variables and official statistics of Aus rice yield is used as target variable for ANN prediction model. The result obtained with ANN method is encouraging and the error of prediction is less than 10%. Therefore, prediction can play an important role in planning and storing of sufficient rice to face in any future uncertainty.

  13. Iridium Interfacial Stack - IrIS

    Science.gov (United States)

    Spry, David

    2012-01-01

    Iridium Interfacial Stack (IrIS) is the sputter deposition of high-purity tantalum silicide (TaSi2-400 nm)/platinum (Pt-200 nm)/iridium (Ir-200 nm)/platinum (Pt-200 nm) in an ultra-high vacuum system followed by a 600 C anneal in nitrogen for 30 minutes. IrIS simultaneously acts as both a bond metal and a diffusion barrier. This bondable metallization that also acts as a diffusion barrier can prevent oxygen from air and gold from the wire-bond from infiltrating silicon carbide (SiC) monolithically integrated circuits (ICs) operating above 500 C in air for over 1,000 hours. This TaSi2/Pt/Ir/Pt metallization is easily bonded for electrical connection to off-chip circuitry and does not require extra anneals or masking steps. There are two ways that IrIS can be used in SiC ICs for applications above 500 C: it can be put directly on a SiC ohmic contact metal, such as Ti, or be used as a bond metal residing on top of an interconnect metal. For simplicity, only the use as a bond metal is discussed. The layer thickness ratio of TaSi2 to the first Pt layer deposited thereon should be 2:1. This will allow Si from the TaSi2 to react with the Pt to form Pt2Si during the 600 C anneal carried out after all layers have been deposited. The Ir layer does not readily form a silicide at 600 C, and thereby prevents the Si from migrating into the top-most Pt layer during future anneals and high-temperature IC operation. The second (i.e., top-most) deposited Pt layer needs to be about 200 nm to enable easy wire bonding. The thickness of 200 nm for Ir was chosen for initial experiments; further optimization of the Ir layer thickness may be possible via further experimentation. Ir itself is not easily wire-bonded because of its hardness and much higher melting point than Pt. Below the iridium layer, the TaSi2 and Pt react and form desired Pt2Si during the post-deposition anneal while above the iridium layer remains pure Pt as desired to facilitate easy and strong wire-bonding to the Si

  14. Problems associated with iridium-192 wire implants

    International Nuclear Information System (INIS)

    Arnott, S.J.; Law, J.; Ash, D.; Flynn, A.; Paine, C.H.; Durrant, K.R.; Barber, C.D.; Dixon-Brown, A.

    1985-01-01

    Three incidents are reported, from different radiotherapy centres, in which an implanted iridium-192 wire remained in the tissues of a patient after withdrawal of the plastic tubing in which it was contained. In each case the instrument used to cut the wire had probably formed a hook on the end of the wire which caused it to catch in the tissues. Detailed recommendations are made for avoiding such incidents in the future, the most important of which is that the patient should be effectively monitored after the supposed removal of all radioactive sources. (author)

  15. Precise orbit determination for BDS3 experimental satellites using iGMAS and MGEX tracking networks

    Science.gov (United States)

    Li, Xingxing; Yuan, Yongqiang; Zhu, Yiting; Huang, Jiande; Wu, Jiaqi; Xiong, Yun; Zhang, Xiaohong; Li, Xin

    2018-04-01

    In this contribution, we focus on the precise orbit determination (POD) for BDS3 experimental satellites with the international GNSS Monitoring and Assessment System (iGMAS) and Multi-GNSS Experiment (MGEX) tracking networks. The datasets of DOY (day of year) 001-230 in 2017 are analyzed with different processing strategies. By comparing receiver clock biases and receiver B1I-B3I DCBs, it is confirmed that there is no obvious systematic bias between experimental BDS3 and BDS2 in the common B1I and B3I signals, which indicates that experimental BDS3 and BDS2 can be treated as one system when performing combined POD. With iGMAS-only BDS3 stations, the 24-h overlap RMS of BDS3 + BDS2 + GPS combined POD is 24.3, 16.1 and 8.4 cm in along-track, cross-track and radial components, which is better than BDS3-only POD by 80-90% and better than BDS3+BDS2 combined POD by about 10%. With more stations (totally 20 stations from both iGMAS and MGEX) and the proper ambiguity resolution strategy (GEO ambiguities are float and BDS3 ambiguities are fixed), the performance of BDS3 POD can be further improved to 14.6, 7.9 and 3.7 cm, respectively, in along-track, cross-track and radial components, which is comparable to the performance of BDS2 POD. The 230-day SLR validations of C32, C33 and C34 show that the mean differences of - 3.48 , 7.81 and 8.19 cm can be achieved, while the STD is 13.35, 13.46 and 13.11 cm, respectively. Furthermore, the 230-day overlap comparisons reveal that C31 most likely still uses an orbit-normal mode and exhibits similar orbit modeling problems in orbit-normal periods as found in most of the BDS2 satellites.

  16. Robust adjustment of a geodetic network measured by satellite technology in the Dargovských Hrdinov suburb

    Directory of Open Access Journals (Sweden)

    Slavomír Labant

    2011-12-01

    Full Text Available This article addresses the adjustment of a 3D geodetic network in the Dargovských Hrdinov suburbs using Global Navigation SatelliteSystems (GNSS for the purposes of deformation analysis. The advantage of using the GNSS compared to other terrestrial technology is thatit is not influenced by unpredictability in the ground level atmosphere and individual visibilities between points in the observed network arenot necessary. This article also includes the planning of GNSS observations using Planning Open Source software from Trimble as well assubsequent observations at individual network points. The geodetic network is processing on the basis of the Gauss-Markov model usingthe least square method and robust adjustment. From robust methods, Huber’s Robust M-estimation and Hampel’s Robust M-estimationwere used. Individual adjustments were tested and subsequently the results of analysis were graphically visualised using absolute confidenceellipsoids.

  17. Local network interconnection through a satellite point-to-multipoint link. Ph.D. Thesis - Ecole Nationale Superieure des Telecommunications, 6 Jul. 1985

    Science.gov (United States)

    Duarte, O. Muniz Bandeira

    1986-01-01

    Four architectures to implement a point to multipoint satellite link protocol for communication services offered by the Telecom 1 satellite network are presented. A safe communication service with error correction and flow control facilities is described. It is shown that a time transparent communication system combines simplicity and cost advantages.

  18. An up-link power control for demand assignment International Business Satellite Communications Network

    Science.gov (United States)

    Nohara, Mitsuo; Takeuchi, Yoshio; Takahata, Fumio

    Up-link power control (UPC) is one of the essential technologies to provide efficient satellite communication systems operated at frequency bands above 10 GHz. A simple and cost-effective UPC scheme applicable to a demand assignment international business satellite communications system has been developed. This paper presents the UPC scheme, including the hardware implementation and its performance.

  19. Combined Geometric and Neural Network Approach to Generic Fault Diagnosis in Satellite Actuators and Sensors

    DEFF Research Database (Denmark)

    Baldi, P.; Blanke, Mogens; Castaldi, P.

    2016-01-01

    This paper presents a novel scheme for diagnosis of faults affecting the sensors measuring the satellite attitude, body angular velocity and flywheel spin rates as well as defects related to the control torques provided by satellite reaction wheels. A nonlinear geometric design is used to avoid t...

  20. Dialing long distance : communications to northern operations like the MGP require sophisticated satellite networks for voice, data

    Energy Technology Data Exchange (ETDEWEB)

    Cook, D.

    2006-04-15

    Telecommunications will play a major role in the construction of the Mackenzie Gas Project due to the remoteness of its location and the volume of communication data required to support the number of people involved and the amount of construction activity. While suppliers for communications tools have not yet been identified, initial telecommunications plans call for the installation of communication equipment at all camps, major facility sites and construction locations. Equipment will be housed in self-contained, climate-controlled buildings called telecommunication service modules (TSMs), which will be connected to each other as well as to existing public communications networks. The infrastructure will support telephone and fax systems; Internet and electronic mail services; multiple channel very high frequency radios; air-to-ground communication at airstrips and helipads; ship-to-shore at barge landings; closed circuit television; satellite community antenna television; CBC radio broadcast; public address systems; security systems; and supervisory control and data acquisition (SCADA) systems. An Internet Protocol (IP) network with a voice telephone system will be implemented along with a geostationary orbit satellite network. Satellite servers and real-time data services will be used. Car kits that allow call and battery-operated self-contained telemetry devices designed to communicate via a satellite system have been commissioned for the project that are capable of providing cost-efficient and reliable asset tracking and fleet management in remote regions and assisting in deployment requirements. It was concluded that many of today's mega-projects are the driving factors behind new telecommunications solutions in remote areas. 1 fig.

  1. Reservation centre of Telecom I satellite French Telecommunication network offers a new service of switched digital circuit

    Science.gov (United States)

    Felix, J.

    The management center and new circuit switching services offered by the French Telecom I network are described. Attention is focused on business services. The satellite has a 125 Mbit/sec capability distributed over 5 frequency bands, yielding the equivalent of 1800 channels. Data are transmitted in digitized bursts with TDMA techniques. Besides the management center, Telecom I interfaces with 310 local network antennas with access managed by the center through a reservation service and protocol assignment. The center logs and supervises alarms and network events, monitors traffic, logs taxation charges and manages the man-machine dialog for TDMA and terrestrial operations. Time slots are arranged in terms of minimal 10 min segments. The reservations can be directly accessed by up to 1000 terminals. All traffic is handled on a call-by-call basis.

  2. Iridium Catalysis: Reductive Conversion of Glucan to Xylan

    DEFF Research Database (Denmark)

    Pedersen, Martin Jæger; Madsen, Robert; Clausen, Mads Hartvig

    2018-01-01

    By using iridium catalysed dehydrogenative decarbonylation, we converted a partly protected cellobioside into a fully protected xylobioside. We demonstrate good yields with two different aromatic ester protecting groups. The resulting xylobioside was directly used as glycosyl donor in further...

  3. Laser welding parameters for manufacturing iridium-192 (Ir-192) source

    International Nuclear Information System (INIS)

    Anung Pujiyanto; Moch Subechi; Hotman Lubis; Diandono KY

    2013-01-01

    Number of cervical cancer patients in Indonesia is growing every year. One of cervical cancer treatment was fairly effective use brachytherapy treatment with radioisotope sources of iridium-192. Manufacturing of iridium sources for brachytherapy can be done by incorporating the iridium-192 into stainless steel microcapsules then welding using laser welder which the quality of the welding of iridium source (Ir-192) was determined by the welding parameters such as full power, energy frequency, average power and speed. Based on the result of leakage test using pressure -20 inch Hg and tensile test 2.5 bar showed the welding parameters III and IV did not have leakage and damaged. So that parameters III and IV are recommended to be applied to Ir-192 HDR's source. (author)

  4. Growth and characterization of iridium dioxide nanorods

    International Nuclear Information System (INIS)

    Chen, R.S.; Huang, Y.S.; Liang, Y.M.; Tsai, D.S.; Tiong, K.K.

    2004-01-01

    Conductive iridium dioxide (IrO 2 ) nanorods have been successfully grown on the Si(1 0 0) substrates via metalorganic chemical vapor deposition (MOCVD). A wedge-shaped morphology and naturally formed sharp tips are observed for IrO 2 nanorods using field-emission scanning electron microscopy (FESEM). High-resolution transmission electron microscopy (TEM) image and electron diffraction pattern show the growth of IrO 2 nanorods preferentially along c-axis. Structure and composition of IrO 2 nanorods have also been characterized using the techniques of Raman spectroscopy and X-ray photoelectron spectroscopy (XPS), respectively. It is noted that the IrO 2 nanorods are self-mediated instead of the conventional vapor-liquid-solid (VLS) approach or catalyst-mediated method

  5. Iridium complexes for the application of photodynamic therapy

    Directory of Open Access Journals (Sweden)

    SHI Min

    2015-10-01

    Full Text Available Photodynamic therapy can destruct tumor cells by singlet oxygen which is generated via a photodynamic reaction of the photosensitizer under a specfic excitation wavelength.Due to the heavy atom effect of metal iridium,iridiumcomplexes are excited by suitable light and then reach their excited triple state through intersystem crossing.The excited iridium complexes transfer energy to oxygen molecules to produce singlet oxygen for photodynamic therapy.

  6. Orbit and clock determination of BDS regional navigation satellite system based on IGS M-GEX and WHU BETS tracking network

    Science.gov (United States)

    GENG, T.; Zhao, Q.; Shi, C.; Shum, C.; Guo, J.; Su, X.

    2013-12-01

    BeiDou Navigation Satellite System (BDS) began to provide the regional open service on December 27th 2012 and will provide the global open service by the end of 2020. Compared to GPS, the space segment of BDS Regional System consists of 5 Geostationary Earth Orbit satellites (GEO), 5 Inclined Geosynchronous Orbit satellites (IGSO) and 4 Medium Earth orbit (MEO) satellites. Since 2011, IGS Multiple-GNSS Experiment (M-GEX) focuses on tracking the newly available GNSS signals. This includes all signals from the modernized satellites of the GPS and GLONASS systems, as well as signals of the BDS, Galileo and QZSS systems. Up to now, BDS satellites are tracked by around 25 stations with a variety of different antennas and receivers from different GNSS manufacture communities in M-GEX network. Meanwhile, there are 17 stations with Unicore Communications Incorporation's GPS/BDS receivers in BeiDou Experimental Tracking Stations (BETS) network by Wuhan University. In addition, 5 BDS satellites have been tracking by the International Laser Ranging Service (ILRS). BDS performance is expected to be further studied by the GNSS communities. Following an introduction of the BDS system and above different tracking network, this paper discusses the achieved BDS characterization and performance assessment. Firstly, the BDS signal and measurement quality are analyzed with different antennas and receivers in detail compared to GPS. This includes depth of coverage for satellite observation, carrier-to-noise-density ratios, code noise and multipath, carrier phase errors. Secondly, BDS Precise Orbit Determination (POD) is processed. Different arc lengths and sets of orbit parameters are tested using Position And Navigation Data Analysis software (PANDA) which is developed at the Wuhan University. GEO, IGSO and MEO satellites orbit quality will be assessed using overlap comparison, 2-day orbit fit and external validations with Satellite Laser Range (SLR). Then BDS satellites are equipped

  7. Design of a search and rescue terminal based on the dual-mode satellite and CDMA network

    Science.gov (United States)

    Zhao, Junping; Zhang, Xuan; Zheng, Bing; Zhou, Yubin; Song, Hao; Song, Wei; Zhang, Meikui; Liu, Tongze; Zhou, Li

    2010-12-01

    The current goal is to create a set of portable terminals with GPS/BD2 dual-mode satellite positioning, vital signs monitoring and wireless transmission functions. The terminal depends on an ARM processor to collect and combine data related to vital signs and GPS/BD2 location information, and sends the message to headquarters through the military CDMA network. It integrates multiple functions as a whole. The satellite positioning and wireless transmission capabilities are integrated into the motherboard, and the vital signs sensors used in the form of belts communicate with the board through Bluetooth. It can be adjusted according to the headquarters' instructions. This kind of device is of great practical significance for operations during disaster relief, search and rescue of the wounded in wartime, non-war military operations and other special circumstances.

  8. Long Term Measurement of the Earth's Radiation Budget using a constellation of Broadband Radiometers hosted on Iridium NEXT

    Science.gov (United States)

    Gupta, Om Prakash; Thoma, Donald; Chaloner, Chris; Russell, Jacqueline; Simpson, Bill; Spilling, David; Morris, Nigel; Caldwell, Martin; Oneill, Alan

    possible changes in this quantity are of particular interest. This proposed configuration of twelve ERB sensors on NEXT has been analyzed in a detailed study by this team and demonstrated to have compatibility with proposed NEXT satellites. This study has also demonstrated the following: 1. Full globe coverage, including the poles, and 3 hourly temporal resolution even at the equator 2. Spatial coverage with a swath of each sensor of 1000 km and resolution of 10 km at nadir 3. LEO orbits which are not sun-synchronous so aliasing effects, which are always a concern with single sensors in sun-synchronous orbits, are no longer of concern 4. Twelve sensors in orbit simultaneously, with frequent near-coincidences at high latitudes, so cross-calibration will become a normal part of the system operation. Cross-calibration will also be possible against current sensors such as CERES in LEO and GERB in GEO and offers the possibly of combined products with the sensors. 5. The data stream will be in real-time via the NEXT communications network 6. System robustness is assured since loss of a sensor or satellite is not mission critical 7. Low risk and short lead times because heritage sensors are to be deployed 8. Low chance of launch delays or mission creep, since timing is crucial to the Iridium's business 9. Planned long constellation design life reduces long term cost and continuity problems 10. Near-certain continuity missions as follow-on constellations are part of the host's business plans 11. A move to truly operational observations using real, rather than virtual, constellation 12. A significantly lower cost alternative to traditional methods for collecting this data.

  9. Satellite- and Epoch Differenced Precise Point Positioning Based on a Regional Augmentation Network

    Directory of Open Access Journals (Sweden)

    Bin Wu

    2012-06-01

    Full Text Available Precise Point Positioning (PPP has been demonstrated as a simple and effective approach for user positioning. The key issue in PPP is how to shorten convergence time and improve positioning efficiency. Recent researches mainly focus on the ambiguity resolution by correcting residual phase errors at a single station. The success of this approach (referred to hereafter as NORM-PPP is subject to how rapidly one can fix wide-lane and narrow-lane ambiguities to achieve the first ambiguity-fixed solution. The convergence time of NORM-PPP is receiver type dependent, and normally takes 15–20 min. Different from the general algorithm and theory by which the float ambiguities are estimated and the integer ambiguities are fixed, we concentrate on a differential PPP approach: the satellite- and epoch differenced (SDED approach. In general, the SDED approach eliminates receiver clocks and ambiguity parameters and thus avoids the complicated residual phase modeling procedure. As a further development of the SDED approach, we use a regional augmentation network to derive tropospheric delay and remaining un-modeled errors at user sites. By adding these corrections and applying the Robust estimation, the weak mathematic properties due to the ED operation is much improved. Implementing this new approach, we need only two epochs of data to achieve PPP positioning converging to centimeter-positioning accuracy. Using seven days of GPS data at six CORS stations in Shanghai, we demonstrate the success rate, defined as the case when three directions converging to desired positioning accuracy of 10 cm, reaches 100% when the interval between the two epochs is longer than 15 min. Comparing the results of 15 min’ interval to that of 10 min’, it is observed that the position RMS improves from 2.47, 3.95, 5.78 cm to 2.21, 3.93, 4.90 cm in the North, East and Up directions, respectively. Combining the SDED coordinates at the starting point and the ED relative

  10. Three-month performance evaluation of the Nanometrics, Inc., Libra Satellite Seismograph System in the northern California Seismic Network

    Science.gov (United States)

    Oppenheimer, David H.

    2000-01-01

    In 1999 the Northern California Seismic Network (NCSN) purchased a Libra satellite seismograph system from Nanometrics, Inc to assess whether this technology was a cost-effective and robust replacement for their analog microwave system. The system was purchased subject to it meeting the requirements, criteria and tests described in Appendix A. In early 2000, Nanometrics began delivery of various components of the system, such as the hub and remote satellite dish and mounting hardware, and the NCSN installed and assembled most equipment in advance of the arrival of Nanometrics engineers to facilitate the configuration of the system. The hub was installed in its permanent location, but for logistical reasons the "remote" satellite hardware was initially configured at the NCSN for testing. During the first week of April Nanometrics engineers came to Menlo Park to configure the system and train NCSN staff. The two dishes were aligned with the satellite, and the system was fully operational in 2 days with little problem. Nanometrics engineers spent the remaining 3 days providing hands-on training to NCSN staff in hardware/software operation, configuration, and maintenance. During the second week of April 2000, NCSN staff moved the entire remote system of digitizers, dish assembly, and mounting hardware to Mammoth Lakes, California. The system was reinstalled at the Mammoth Lakes water treatment plant and communications successfully reestablished with the hub via the satellite on 14 April 2000. The system has been in continuous operation since then. This report reviews the performance of the Libra system for the three-month period 20 April 2000 through 20 July 2000. The purpose of the report is to assess whether the system passed the acceptance tests described in Appendix A. We examine all data gaps reported by NCSN "gap list" software and discuss their cause.

  11. A neural network detection system for lower-hybrid cavities in electron plasma density measured by the FREJA satellite

    International Nuclear Information System (INIS)

    Waldemark, J.; Karlsson, Jan

    1995-03-01

    This paper presents a lower-hybrid cavity detection system, CDS, for measurements of electron plasma density on the FREJA satellite wave experiment. The system can reduce the amount of data to be analysed by as much as 96% and still retain more than 85% of the desired information. The CDS is a combination of a hybrid neural network, HNN and expert rules. The HNN is a Self Organizing Map, SOM, combined with a feed forward back propagation neural net, BP. The CDS can be controlled by the user to operate with various degrees of sensitivity. Maximum detection capability is as high as 95% with data reduction lowered to 85%. 10 refs

  12. A CDMA Spotbeam Architecture for the Next Generation Satellite System (NGSS) for the Aeronautical Telecommunications Network (ATN)

    Science.gov (United States)

    Raghavan, Rajesh S.; Shamma, Mohammed A.

    2003-01-01

    This paper will present work being done to model and simulate a CDMA based Mobile Satellite System architecture for providing all or part of the future Air Traffic Management (ATM) services. Such a system, will help in relieving the dependence on ground based networks, if not eliminate it. Additionally such an architecture can be used in parallel or as a supplementary service along with ground based links to help alleviate any capacity bottlenecks, or in areas where such services are difficult to make available such as in oceanic, remote areas outside the jet highways, or in developing countries where ground services are less available.

  13. A dense camera network for cropland (CropInsight) - developing high spatiotemporal resolution crop Leaf Area Index (LAI) maps through network images and novel satellite data

    Science.gov (United States)

    Kimm, H.; Guan, K.; Luo, Y.; Peng, J.; Mascaro, J.; Peng, B.

    2017-12-01

    Monitoring crop growth conditions is of primary interest to crop yield forecasting, food production assessment, and risk management of individual farmers and agribusiness. Despite its importance, there are limited access to field level crop growth/condition information in the public domain. This scarcity of ground truth data also hampers the use of satellite remote sensing for crop monitoring due to the lack of validation. Here, we introduce a new camera network (CropInsight) to monitor crop phenology, growth, and conditions that are designed for the US Corn Belt landscape. Specifically, this network currently includes 40 sites (20 corn and 20 soybean fields) across southern half of the Champaign County, IL ( 800 km2). Its wide distribution and automatic operation enable the network to capture spatiotemporal variations of crop growth condition continuously at the regional scale. At each site, low-maintenance, and high-resolution RGB digital cameras are set up having a downward view from 4.5 m height to take continuous images. In this study, we will use these images and novel satellite data to construct daily LAI map of the Champaign County at 30 m spatial resolution. First, we will estimate LAI from the camera images and evaluate it using the LAI data collected from LAI-2200 (LI-COR, Lincoln, NE). Second, we will develop relationships between the camera-based LAI estimation and vegetation indices derived from a newly developed MODIS-Landsat fusion product (daily, 30 m resolution, RGB + NIR + SWIR bands) and the Planet Lab's high-resolution satellite data (daily, 5 meter, RGB). Finally, we will scale up the above relationships to generate high spatiotemporal resolution crop LAI map for the whole Champaign County. The proposed work has potentials to expand to other agro-ecosystems and to the broader US Corn Belt.

  14. Test of Neural Network Techniques using Simulated Dual-Band Data of LEO Satellites

    Science.gov (United States)

    2010-09-01

    component to allow for glinting surfaces, such as solar panels. Radiant intensities are calculated for a blue band (468-495 nm) and a red band (738-765...When a satellite is visible for at least one of the observation sites, OSC is used to calculate radiant intensity in the blue and red spectral bands...Input node, aji , contains the ith value of radiant intensity for the jth pass of a satellite. In this work, the n input nodes are values of radiant

  15. IMT-2000 Satellite Standards with Applications to Mobile Air Traffic Communications Networks

    Science.gov (United States)

    Shamma, Mohammed A.

    2004-01-01

    The International Mobile Telecommunications - 2000 (IMT-2000) standard and more specifically the Satellite component of it, is investigated as a potential alternative for communications to aircraft mobile users en-route and in terminal area. Its application to Air Traffic Management (ATM) communication needs is considered. A summary of the specifications of IMT-2000 satellite standards are outlined. It is shown via a system research analysis that it is possible to support most air traffic communication needs via an IMT-2000 infrastructure. This technology can compliment existing, or future digital aeronautical communications technologies such as VDL2, VDL3, Mode S, and UAT.

  16. Energy-Efficient Transmissions for Remote Wireless Sensor Networks: An Integrated HAP/Satellite Architecture for Emergency Scenarios

    Science.gov (United States)

    Dong, Feihong; Li, Hongjun; Gong, Xiangwu; Liu, Quan; Wang, Jingchao

    2015-01-01

    A typical application scenario of remote wireless sensor networks (WSNs) is identified as an emergency scenario. One of the greatest design challenges for communications in emergency scenarios is energy-efficient transmission, due to scarce electrical energy in large-scale natural and man-made disasters. Integrated high altitude platform (HAP)/satellite networks are expected to optimally meet emergency communication requirements. In this paper, a novel integrated HAP/satellite (IHS) architecture is proposed, and three segments of the architecture are investigated in detail. The concept of link-state advertisement (LSA) is designed in a slow flat Rician fading channel. The LSA is received and processed by the terminal to estimate the link state information, which can significantly reduce the energy consumption at the terminal end. Furthermore, the transmission power requirements of the HAPs and terminals are derived using the gradient descent and differential equation methods. The energy consumption is modeled at both the source and system level. An innovative and adaptive algorithm is given for the energy-efficient path selection. The simulation results validate the effectiveness of the proposed adaptive algorithm. It is shown that the proposed adaptive algorithm can significantly improve energy efficiency when combined with the LSA and the energy consumption estimation. PMID:26404292

  17. Energy-Efficient Transmissions for Remote Wireless Sensor Networks: An Integrated HAP/Satellite Architecture for Emergency Scenarios

    Directory of Open Access Journals (Sweden)

    Feihong Dong

    2015-09-01

    Full Text Available A typical application scenario of remote wireless sensor networks (WSNs is identified as an emergency scenario. One of the greatest design challenges for communications in emergency scenarios is energy-efficient transmission, due to scarce electrical energy in large-scale natural and man-made disasters. Integrated high altitude platform (HAP/satellite networks are expected to optimally meet emergency communication requirements. In this paper, a novel integrated HAP/satellite (IHS architecture is proposed, and three segments of the architecture are investigated in detail. The concept of link-state advertisement (LSA is designed in a slow flat Rician fading channel. The LSA is received and processed by the terminal to estimate the link state information, which can significantly reduce the energy consumption at the terminal end. Furthermore, the transmission power requirements of the HAPs and terminals are derived using the gradient descent and differential equation methods. The energy consumption is modeled at both the source and system level. An innovative and adaptive algorithm is given for the energy-efficient path selection. The simulation results validate the effectiveness of the proposed adaptive algorithm. It is shown that the proposed adaptive algorithm can significantly improve energy efficiency when combined with the LSA and the energy consumption estimation.

  18. Energy-Efficient Transmissions for Remote Wireless Sensor Networks: An Integrated HAP/Satellite Architecture for Emergency Scenarios.

    Science.gov (United States)

    Dong, Feihong; Li, Hongjun; Gong, Xiangwu; Liu, Quan; Wang, Jingchao

    2015-09-03

    A typical application scenario of remote wireless sensor networks (WSNs) is identified as an emergency scenario. One of the greatest design challenges for communications in emergency scenarios is energy-efficient transmission, due to scarce electrical energy in large-scale natural and man-made disasters. Integrated high altitude platform (HAP)/satellite networks are expected to optimally meet emergency communication requirements. In this paper, a novel integrated HAP/satellite (IHS) architecture is proposed, and three segments of the architecture are investigated in detail. The concept of link-state advertisement (LSA) is designed in a slow flat Rician fading channel. The LSA is received and processed by the terminal to estimate the link state information, which can significantly reduce the energy consumption at the terminal end. Furthermore, the transmission power requirements of the HAPs and terminals are derived using the gradient descent and differential equation methods. The energy consumption is modeled at both the source and system level. An innovative and adaptive algorithm is given for the energy-efficient path selection. The simulation results validate the effectiveness of the proposed adaptive algorithm. It is shown that the proposed adaptive algorithm can significantly improve energy efficiency when combined with the LSA and the energy consumption estimation.

  19. Combined Geometric and Neural Network Approach to Generic Fault Diagnosis in Satellite Reaction Wheels

    DEFF Research Database (Denmark)

    Baldi, P.; Blanke, Mogens; Castaldi, P.

    2015-01-01

    This paper suggests a novel diagnosis scheme for detection, isolation and estimation of faults affecting satellite reaction wheels. Both spin rate measurements and actuation torque defects are dealt with. The proposed system consists of a fault detection and isolation module composed by a bank of...

  20. Determination of traces of iridium with thiodibenzoylmethane by substoichiometric isotope dilution analysis

    International Nuclear Information System (INIS)

    Roebisch, G.; Bansse, W.; Ludwig, E.

    1980-01-01

    Iridium(III or IV) reacts with thiodibenzoylmethane on heating at pH 6 to form a 1:3 complex, which can be concentrated by extraction into chloroform. Based on this reaction, a reproducible, selective determination of iridium is achieved by means of substoichiometric isotope dilution analysis, based on 192 Ir. The linear range is 1-11 nmol of iridium. (Auth.)

  1. A feed-forward Hopfield neural network algorithm (FHNNA) with a colour satellite image for water quality mapping

    Science.gov (United States)

    Asal Kzar, Ahmed; Mat Jafri, M. Z.; Hwee San, Lim; Al-Zuky, Ali A.; Mutter, Kussay N.; Hassan Al-Saleh, Anwar

    2016-06-01

    There are many techniques that have been given for water quality problem, but the remote sensing techniques have proven their success, especially when the artificial neural networks are used as mathematical models with these techniques. Hopfield neural network is one type of artificial neural networks which is common, fast, simple, and efficient, but it when it deals with images that have more than two colours such as remote sensing images. This work has attempted to solve this problem via modifying the network that deals with colour remote sensing images for water quality mapping. A Feed-forward Hopfield Neural Network Algorithm (FHNNA) was modified and used with a satellite colour image from type of Thailand earth observation system (THEOS) for TSS mapping in the Penang strait, Malaysia, through the classification of TSS concentrations. The new algorithm is based essentially on three modifications: using HNN as feed-forward network, considering the weights of bitplanes, and non-self-architecture or zero diagonal of weight matrix, in addition, it depends on a validation data. The achieved map was colour-coded for visual interpretation. The efficiency of the new algorithm has found out by the higher correlation coefficient (R=0.979) and the lower root mean square error (RMSE=4.301) between the validation data that were divided into two groups. One used for the algorithm and the other used for validating the results. The comparison was with the minimum distance classifier. Therefore, TSS mapping of polluted water in Penang strait, Malaysia, can be performed using FHNNA with remote sensing technique (THEOS). It is a new and useful application of HNN, so it is a new model with remote sensing techniques for water quality mapping which is considered important environmental problem.

  2. Network Analysis for the Identification of Differentially Expressed Hub Genes Using Myogenin Knock-down Muscle Satellite Cells.

    Directory of Open Access Journals (Sweden)

    Adeel Malik

    Full Text Available Muscle, a multinucleate syncytium formed by the fusion of mononuclear myoblasts, arises from quiescent progenitors (satellite cells via activation of muscle-specific transcription factors (MyoD, Myf5, myogenin: MYOG, and MRF4. Subsequent to a decline in Pax7, induction in the expression of MYOG is a hallmark of myoblasts that have entered the differentiation phase following cell cycle withdrawal. It is evident that MYOG function cannot be compensated by any other myogenic regulatory factors (MRFs. Despite a plethora of information available regarding MYOG, the mechanism by which MYOG regulates muscle cell differentiation has not yet been identified. Using an RNA-Seq approach, analysis of MYOG knock-down muscle satellite cells (MSCs have shown that genes associated with cell cycle and division, DNA replication, and phosphate metabolism are differentially expressed. By constructing an interaction network of differentially expressed genes (DEGs using GeneMANIA, cadherin-associated protein (CTNNA2 was identified as the main hub gene in the network with highest node degree. Four functional clusters (modules or communities were identified in the network and the functional enrichment analysis revealed that genes included in these clusters significantly contribute to skeletal muscle development. To confirm this finding, in vitro studies revealed increased expression of CTNNA2 in MSCs on day 12 compared to day 10. Expression of CTNNA2 was decreased in MYOG knock-down cells. However, knocking down CTNNA2, which leads to increased expression of extracellular matrix (ECM genes (type I collagen α1 and type I collagen α2 along with myostatin (MSTN, was not found significantly affecting the expression of MYOG in C2C12 cells. We therefore propose that MYOG exerts its regulatory effects by acting upstream of CTNNA2, which in turn regulates the differentiation of C2C12 cells via interaction with ECM genes. Taken together, these findings highlight a new

  3. Improving information dissemination in sparse vehicular networks by adding satellite communication

    NARCIS (Netherlands)

    Kloiber, Bernhard; Strang, Thomas; Spijker, Hanno; Heijenk, Geert

    Information dissemination in pure Vehicular Ad Hoc NETworks (VANETs) such as ITS-G5 becomes problematic when the network is sparse. In situations where the number of vehicles, that can act as a communication node, is insufficiently low, e.g. in rural areas, during night-time or because of a low

  4. Pseudo Last Useful Instant Queuing Strategy for Handovers in Low Earth Orbit Mobile Satellite Networks

    OpenAIRE

    W. Kiamouche; M. Benslama

    2008-01-01

    This paper presents an alternative strategy of queuing handover called Pseudo Last Useful Instant PLUI scheme for Low Earth Orbit Mobile Satellite Systems LEO MSSs. The PLUI scheme uses the same approach as the Last Useful Instant LUI scheme previously proposed in literature, with less complex implementation. Simulation tests were carried out using Dynamic Channel Allocation DCA in order to evaluate the performance of this scheme and also an analytical approach has been p...

  5. An advanced OBP-based payload operating in an asynchronous network for future data relay satellites utilising CCSDS-standard data structures

    Science.gov (United States)

    Grant, M.; Vernucci, A.

    1991-01-01

    A possible Data Relay Satellite System (DRSS) topology and network architecture is introduced. An asynchronous network concept, whereby each link (Inter-orbit, Inter-satellite, Feeder) is allowed to operate on its own clock, without causing loss of information, in conjunction with packet data structures, such as those specified by the CCSDS for advanced orbiting systems is discussed. A matching OBP payload architecture is described, highlighting the advantages provided by the OBP-based concept and then giving some indications on the OBP mass/power requirements.

  6. Extraction of Built-Up Areas Using Convolutional Neural Networks and Transfer Learning from SENTINEL-2 Satellite Images

    Science.gov (United States)

    Bramhe, V. S.; Ghosh, S. K.; Garg, P. K.

    2018-04-01

    With rapid globalization, the extent of built-up areas is continuously increasing. Extraction of features for classifying built-up areas that are more robust and abstract is a leading research topic from past many years. Although, various studies have been carried out where spatial information along with spectral features has been utilized to enhance the accuracy of classification. Still, these feature extraction techniques require a large number of user-specific parameters and generally application specific. On the other hand, recently introduced Deep Learning (DL) techniques requires less number of parameters to represent more abstract aspects of the data without any manual effort. Since, it is difficult to acquire high-resolution datasets for applications that require large scale monitoring of areas. Therefore, in this study Sentinel-2 image has been used for built-up areas extraction. In this work, pre-trained Convolutional Neural Networks (ConvNets) i.e. Inception v3 and VGGNet are employed for transfer learning. Since these networks are trained on generic images of ImageNet dataset which are having very different characteristics from satellite images. Therefore, weights of networks are fine-tuned using data derived from Sentinel-2 images. To compare the accuracies with existing shallow networks, two state of art classifiers i.e. Gaussian Support Vector Machine (SVM) and Back-Propagation Neural Network (BP-NN) are also implemented. Both SVM and BP-NN gives 84.31 % and 82.86 % overall accuracies respectively. Inception-v3 and VGGNet gives 89.43 % of overall accuracy using fine-tuned VGGNet and 92.10 % when using Inception-v3. The results indicate high accuracy of proposed fine-tuned ConvNets on a 4-channel Sentinel-2 dataset for built-up area extraction.

  7. EXTRACTION OF BUILT-UP AREAS USING CONVOLUTIONAL NEURAL NETWORKS AND TRANSFER LEARNING FROM SENTINEL-2 SATELLITE IMAGES

    Directory of Open Access Journals (Sweden)

    V. S. Bramhe

    2018-04-01

    Full Text Available With rapid globalization, the extent of built-up areas is continuously increasing. Extraction of features for classifying built-up areas that are more robust and abstract is a leading research topic from past many years. Although, various studies have been carried out where spatial information along with spectral features has been utilized to enhance the accuracy of classification. Still, these feature extraction techniques require a large number of user-specific parameters and generally application specific. On the other hand, recently introduced Deep Learning (DL techniques requires less number of parameters to represent more abstract aspects of the data without any manual effort. Since, it is difficult to acquire high-resolution datasets for applications that require large scale monitoring of areas. Therefore, in this study Sentinel-2 image has been used for built-up areas extraction. In this work, pre-trained Convolutional Neural Networks (ConvNets i.e. Inception v3 and VGGNet are employed for transfer learning. Since these networks are trained on generic images of ImageNet dataset which are having very different characteristics from satellite images. Therefore, weights of networks are fine-tuned using data derived from Sentinel-2 images. To compare the accuracies with existing shallow networks, two state of art classifiers i.e. Gaussian Support Vector Machine (SVM and Back-Propagation Neural Network (BP-NN are also implemented. Both SVM and BP-NN gives 84.31 % and 82.86 % overall accuracies respectively. Inception-v3 and VGGNet gives 89.43 % of overall accuracy using fine-tuned VGGNet and 92.10 % when using Inception-v3. The results indicate high accuracy of proposed fine-tuned ConvNets on a 4-channel Sentinel-2 dataset for built-up area extraction.

  8. pH sensors based on iridium oxide

    International Nuclear Information System (INIS)

    Tarlov, M.J.; Kreider, K.G.; Semancik, S.; Huang, P.

    1990-03-01

    Results are presented on the pH-potential response of dc magnetron reactively sputtered iridium oxide films. The films exhibit a nearly Nernstian response to pH, no hysteresis effects, and minimal response to ionic interferences. Sensitivity to certain redox species is observed, however. In addition, methods are discussed for preparing model iridium oxide sensor surfaces for ultrahigh vacuum surface analytical studies. Stoichiometric IrO 2 -like surfaces are shown to be relatively inert to gas phase water. However, hydroxylation of IrO 2 -like surfaces can be induced by rf water plasma treatment. 17 refs., 5 figs

  9. Welding iridium heat-source capsules for space missions

    International Nuclear Information System (INIS)

    Kanne, W.R. Jr.

    1982-03-01

    A remote computer-controlled welding station was developed to encapsulate radioactive PuO 2 in iridium. Weld quench cracking caused an interruption in production of capsules for upcoming space missions. Hot crack sensitivity of the DOP-26 iridium alloy was associated with low melting constituents in the grain boundaries. The extent of cracking was reduced but could not be eliminated by changes to the welding operation. An ultrasonic test was developed to detect underbead cracks exceeding a threshold size. Production was continued using the ultrasonic test to reject capsules with detectable cracks

  10. The role of iridium in the work-function behavior of dilute-solution tungsten, iridium alloys

    International Nuclear Information System (INIS)

    D'Cruz, L.A.

    1991-01-01

    Requirements of thermionic electrode materials have emphasized the need for substantial improvements in microstructural stability, strength and creep resistance at service temperatures in excess of 2,500K. This study utilized both chemical alloying and mechanical alloying procedures for the addition of iridium to submicron W powder followed by cold compaction and sintering. The shrinkage characteristics and microstructural development were studied in iridium-added tungsten compacts with a range of additive levels. An electron-emission study was subsequently carried out in order to evaluate the work-function behavior of the consolidated alloys. The work function was obtained from current-emission measurements from the electrode surface under UHV conditions in the temperature range of 1,800 to 2,500K using a Vacuum Emission Vehicle (VEV). The data show that the magnitude of the work function in these alloys varied with temperature and was sensitive to sub-surface iridium content

  11. Satellite laser ranging to low Earth orbiters: orbit and network validation

    Science.gov (United States)

    Arnold, Daniel; Montenbruck, Oliver; Hackel, Stefan; Sośnica, Krzysztof

    2018-04-01

    Satellite laser ranging (SLR) to low Earth orbiters (LEOs) provides optical distance measurements with mm-to-cm-level precision. SLR residuals, i.e., differences between measured and modeled ranges, serve as a common figure of merit for the quality assessment of orbits derived by radiometric tracking techniques. We discuss relevant processing standards for the modeling of SLR observations and highlight the importance of line-of-sight-dependent range corrections for the various types of laser retroreflector arrays. A 1-3 cm consistency of SLR observations and GPS-based precise orbits is demonstrated for a wide range of past and present LEO missions supported by the International Laser Ranging Service (ILRS). A parameter estimation approach is presented to investigate systematic orbit errors and it is shown that SLR validation of LEO satellites is not only able to detect radial but also along-track and cross-track offsets. SLR residual statistics clearly depend on the employed precise orbit determination technique (kinematic vs. reduced-dynamic, float vs. fixed ambiguities) but also reveal pronounced differences in the ILRS station performance. Using the residual-based parameter estimation approach, corrections to ILRS station coordinates, range biases, and timing offsets are derived. As a result, root-mean-square residuals of 5-10 mm have been achieved over a 1-year data arc in 2016 using observations from a subset of high-performance stations and ambiguity-fixed orbits of four LEO missions. As a final contribution, we demonstrate that SLR can not only validate single-satellite orbit solutions but also precise baseline solutions of formation flying missions such as GRACE, TanDEM-X, and Swarm.

  12. DeepSAT's CloudCNN: A Deep Neural Network for Rapid Cloud Detection from Geostationary Satellites

    Science.gov (United States)

    Kalia, S.; Li, S.; Ganguly, S.; Nemani, R. R.

    2017-12-01

    Cloud and cloud shadow detection has important applications in weather and climate studies. It is even more crucial when we introduce geostationary satellites into the field of terrestrial remotesensing. With the challenges associated with data acquired in very high frequency (10-15 mins per scan), the ability to derive an accurate cloud/shadow mask from geostationary satellite data iscritical. The key to the success for most of the existing algorithms depends on spatially and temporally varying thresholds, which better capture local atmospheric and surface effects.However, the selection of proper threshold is difficult and may lead to erroneous results. In this work, we propose a deep neural network based approach called CloudCNN to classifycloud/shadow from Himawari-8 AHI and GOES-16 ABI multispectral data. DeepSAT's CloudCNN consists of an encoder-decoder based architecture for binary-class pixel wise segmentation. We train CloudCNN on multi-GPU Nvidia Devbox cluster, and deploy the prediction pipeline on NASA Earth Exchange (NEX) Pleiades supercomputer. We achieved an overall accuracy of 93.29% on test samples. Since, the predictions take only a few seconds to segment a full multi-spectral GOES-16 or Himawari-8 Full Disk image, the developed framework can be used for real-time cloud detection, cyclone detection, or extreme weather event predictions.

  13. Object-Oriented Analysis of Satellite Images Using Artificial Neural Networks for Post-Earthquake Buildings Change Detection

    Science.gov (United States)

    Khodaverdi zahraee, N.; Rastiveis, H.

    2017-09-01

    Earthquake is one of the most divesting natural events that threaten human life during history. After the earthquake, having information about the damaged area, the amount and type of damage can be a great help in the relief and reconstruction for disaster managers. It is very important that these measures should be taken immediately after the earthquake because any negligence could be more criminal losses. The purpose of this paper is to propose and implement an automatic approach for mapping destructed buildings after an earthquake using pre- and post-event high resolution satellite images. In the proposed method after preprocessing, segmentation of both images is performed using multi-resolution segmentation technique. Then, the segmentation results are intersected with ArcGIS to obtain equal image objects on both images. After that, appropriate textural features, which make a better difference between changed or unchanged areas, are calculated for all the image objects. Finally, subtracting the extracted textural features from pre- and post-event images, obtained values are applied as an input feature vector in an artificial neural network for classifying the area into two classes of changed and unchanged areas. The proposed method was evaluated using WorldView2 satellite images, acquired before and after the 2010 Haiti earthquake. The reported overall accuracy of 93% proved the ability of the proposed method for post-earthquake buildings change detection.

  14. North American Tropospheric Ozone Profiles from IONS (INTEX Ozonesonde Network Study, 2004, 2006): Ozone Budgets, Polution Statistics, Satellite Retrievals

    Science.gov (United States)

    Dougherty, M.; Thompson, A. M.; Witte, J. C.; Miller, S. K.; Oltmans, S. J.; Cooper, O. R.; Tarasick, D. W.; Chatfield, R. B.; Taubman, B. F.; Joseph, E.; Baumgardner, D.; Merrill, J. T.; Morris, G. A.; Rappenglueck, B.; Lefer, B.; Forbes, G.; Newchurch, M. J.; Schmidlin, F. J.; Pierce, R. B.; Leblanc, T.; Dubey, M.; Minschwaner, K.

    2007-12-01

    During INTEX-B (both Milagro and IMPEX phases in Spring 2006) and during the summer TEXAQS- 2006/GOMACCS period, the INTEX Ozonesonde Network Study (IONS-06) coordinated ozonesonde launches over North America for Aura overpasses. IONS-06 supported aircraft operations and provided profiles for ozone budgets and pollution transport, satellite validation and evaluation of models. In contrast to IONS-04, IONS-06 had a greater range (all but one 2004 IONS site plus a dozen in California, New Mexico, Mexico City, Barbados and southwestern Canada), yielding more than 700 profiles. Tropospheric pollution statistics to guide Aura satellite retrievals and contrasts in UT-LS (upper tropospheric-lower stratospheric) ozone between 2004 and 2006 are presented. With IONS-04 dominated by low-pressure conditions over northeastern North America, UT ozone originated 25% from the stratosphere [Thompson et al., 2007a,b] with significant amounts from aged or relatively fresh pollution and lightning [Cooper et al., 2006; Morris et al., 2006]. Both IONS-04 and IONS-06 summer periods displayed a persistent UT ozone maximum [Cooper et al., 2007] over the south-central US. March 2006 IONS sondes over Mexico manifested persistent UT/LS gravity wave influence and more sporadic pollution. Regional and seasonal contrasts in IONS-06 ozone distributions are described. intexb/ions06.html

  15. Maritime Aerosol Network as a Component of AERONET - First Results and Comparison with Global Aerosol Models and Satellite Retrievals

    Science.gov (United States)

    Smirnov, A.; Holben, B. N.; Giles, D. M.; Slutsker, I.; O'Neill, N. T.; Eck, T. F.; Macke, A.; Croot, P.; Courcoux, Y.; Sakerin, S. M.; hide

    2011-01-01

    The Maritime Aerosol Network (MAN) has been collecting data over the oceans since November 2006. Over 80 cruises were completed through early 2010 with deployments continuing. Measurement areas included various parts of the Atlantic Ocean, the Northern and Southern Pacific Ocean, the South Indian Ocean, the Southern Ocean, the Arctic Ocean and inland seas. MAN deploys Microtops handheld sunphotometers and utilizes a calibration procedure and data processing traceable to AERONET. Data collection included areas that previously had no aerosol optical depth (AOD) coverage at all, particularly vast areas of the Southern Ocean. The MAN data archive provides a valuable resource for aerosol studies in maritime environments. In the current paper we present results of AOD measurements over the oceans, and make a comparison with satellite AOD retrievals and model simulations.

  16. Maritime aerosol network as a component of AERONET – first results and comparison with global aerosol models and satellite retrievals

    Directory of Open Access Journals (Sweden)

    A. Smirnov

    2011-03-01

    Full Text Available The Maritime Aerosol Network (MAN has been collecting data over the oceans since November 2006. Over 80 cruises were completed through early 2010 with deployments continuing. Measurement areas included various parts of the Atlantic Ocean, the Northern and Southern Pacific Ocean, the South Indian Ocean, the Southern Ocean, the Arctic Ocean and inland seas. MAN deploys Microtops hand-held sunphotometers and utilizes a calibration procedure and data processing traceable to AERONET. Data collection included areas that previously had no aerosol optical depth (AOD coverage at all, particularly vast areas of the Southern Ocean. The MAN data archive provides a valuable resource for aerosol studies in maritime environments. In the current paper we present results of AOD measurements over the oceans, and make a comparison with satellite AOD retrievals and model simulations.

  17. Phosphorescent systems based on iridium(III) complexes

    NARCIS (Netherlands)

    Ulbricht, C.

    2009-01-01

    Phosphorescent iridium(III)-based complexes are experiencing a growing interest in a number of research fields. Aside from lighting and display technologies (i.e. OLEDs and LECs), they find use in various applications such as biolabeling, sensors, solar cells and water splitting. In particular, the

  18. Iridium Sulfide and Ir Promoted Mo Based Catalysts.

    Czech Academy of Sciences Publication Activity Database

    Vít, Zdeněk

    2007-01-01

    Roč. 322, - (2007), s. 142-151 ISSN 0926-860X R&D Projects: GA ČR(CZ) GA104/06/0870 Institutional research plan: CEZ:AV0Z40720504 Keywords : iridium sulfide * IrMo catalyst * hydrodesulfurization Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 3.166, year: 2007

  19. Asymmetric Hydrogenation of Quinoxalines Catalyzed by Iridium/PipPhos

    NARCIS (Netherlands)

    Mrsic, Natasa; Jerphagnon, Thomas; Minnaard, Adriaan J.; Feringa, Ben L.; de Vries, Johannes G.

    2009-01-01

    A catalyst made in situ from the (cyclooctadiene)iridium chloride dimer, [Ir(COD)Cl](2), and the monodentate phosphoramidite ligand (S)-PipPhos was used in the enantioselective hydrogenation of 2- and 2,6-substituted quinoxalines. In the presence of piperidine hydrochloride as additive full

  20. Prototyping iridium coated mirrors for x-ray astronomy

    Science.gov (United States)

    Döhring, Thorsten; Probst, Anne-Catherine; Stollenwerk, Manfred; Emmerich, Florian; Stehlíková, Veronika; Inneman, Adolf

    2017-05-01

    X-ray astronomy uses space-based telescopes to overcome the disturbing absorption of the Earth's atmosphere. The telescope mirrors are operating at grazing incidence angles and are coated with thin metal films of high-Z materials to get sufficient reflectivity for the high-energy radiation to be observed. In addition the optical payload needs to be light-weighted for launcher mass constrains. Within the project JEUMICO, an acronym for "Joint European Mirror Competence", the Aschaffenburg University of Applied Sciences and the Czech Technical University in Prague started a collaboration to develop mirrors for X-ray telescopes. The X-ray telescopes currently developed within this Bavarian- Czech project are of Lobster eye type optical design. Corresponding mirror segments use substrates of flat silicon wafers which are coated with thin iridium films, as this material is promising high reflectivity in the X-ray range of interest. The deposition of the iridium films is based on a magnetron sputtering process. Sputtering with different parameters, especially by variation of the argon gas pressure, leads to iridium films with different properties. In addition to investigations of the uncoated mirror substrates the achieved surface roughness has been studied. Occasional delamination of the iridium films due to high stress levels is prevented by chromium sublayers. Thereby the sputtering parameters are optimized in the context of the expected reflectivity of the coated X-ray mirrors. In near future measurements of the assembled mirror modules optical performances are planned at an X-ray test facility.

  1. Dose determination in breast tumor in brachytherapy using Iridium-192

    International Nuclear Information System (INIS)

    Okuno, S.F.

    1984-01-01

    Thermoluminescent dosimetry studies in vivo and in vitro aiming to determing radiation dose in the breast tumor, in brachytherapy using Iridium-192 was done. The correlation between radiation doses in tumor and external surface of the breast was investigated for correcting the time interval of radiation source implantation. (author) [pt

  2. Handbook of satellite applications

    CERN Document Server

    Madry, Scott; Camacho-Lara, Sergio

    2017-01-01

    The first edition of this ground breaking reference work was the most comprehensive reference source available about the key aspects of the satellite applications field. This updated second edition covers the technology, the markets, applications and regulations related to satellite telecommunications, broadcasting and networking—including civilian and military systems; precise satellite navigation and timing networks (i.e. GPS and others); remote sensing and meteorological satellite systems. Created under the auspices of the International Space University based in France, this brand new edition is now expanded to cover new innovative small satellite constellations, new commercial launching systems, innovation in military application satellites and their acquisition, updated appendices, a useful glossary and more.

  3. A new generic method for the semi-automatic extraction of river and road networks in low and mid-resolution satellite images

    Energy Technology Data Exchange (ETDEWEB)

    Grazzini, Jacopo [Los Alamos National Laboratory; Dillard, Scott [PNNL; Soille, Pierre [EC JRC

    2010-10-21

    This paper addresses the problem of semi-automatic extraction of road or hydrographic networks in satellite images. For that purpose, we propose an approach combining concepts arising from mathematical morphology and hydrology. The method exploits both geometrical and topological characteristics of rivers/roads and their tributaries in order to reconstruct the complete networks. It assumes that the images satisfy the following two general assumptions, which are the minimum conditions for a road/river network to be identifiable and are usually verified in low- to mid-resolution satellite images: (i) visual constraint: most pixels composing the network have similar spectral signature that is distinguishable from most of the surrounding areas; (ii) geometric constraint: a line is a region that is relatively long and narrow, compared with other objects in the image. While this approach fully exploits local (roads/rivers are modeled as elongated regions with a smooth spectral signature in the image and a maximum width) and global (they are structured like a tree) characteristics of the networks, further directional information about the image structures is incorporated. Namely, an appropriate anisotropic metric is designed by using both the characteristic features of the target network and the eigen-decomposition of the gradient structure tensor of the image. Following, the geodesic propagation from a given network seed with this metric is combined with hydrological operators for overland flow simulation to extract the paths which contain most line evidence and identify them with the target network.

  4. Self-Assembled Core-Satellite Gold Nanoparticle Networks for Ultrasensitive Detection of Chiral Molecules by Recognition Tunneling Current.

    Science.gov (United States)

    Zhang, Yuanchao; Liu, Jingquan; Li, Da; Dai, Xing; Yan, Fuhua; Conlan, Xavier A; Zhou, Ruhong; Barrow, Colin J; He, Jin; Wang, Xin; Yang, Wenrong

    2016-05-24

    Chirality sensing is a very challenging task. Here, we report a method for ultrasensitive detection of chiral molecule l/d-carnitine based on changes in the recognition tunneling current across self-assembled core-satellite gold nanoparticle (GNP) networks. The recognition tunneling technique has been demonstrated to work at the single molecule level where the binding between the reader molecules and the analytes in a nanojunction. This process was observed to generate a unique and sensitive change in tunneling current, which can be used to identify the analytes of interest. The molecular recognition mechanism between amino acid l-cysteine and l/d-carnitine has been studied with the aid of SERS. The different binding strength between homo- or heterochiral pairs can be effectively probed by the copper ion replacement fracture. The device resistance was measured before and after the sequential exposures to l/d-carnitine and copper ions. The normalized resistance change was found to be extremely sensitive to the chirality of carnitine molecule. The results suggested that a GNP networks device optimized for recognition tunneling was successfully built and that such a device can be used for ultrasensitive detection of chiral molecules.

  5. Implementation of a light-route TDMA communications satellite system for advanced business networks

    Science.gov (United States)

    Hanson, B.; Smalley, A.; Zuliani, M.

    The application of Light Route TDMA systems to various business communication requirements is discussed. It is noted that full development of this technology for use in advanced business networks will be guided by considerations of flexibility, reliability, security, and cost. The implementation of the TDMA system for demonstrating these advantages to a wide range of public and private organizations is described in detail. Among the advantages offered by this system are point-to-point and point-to-multipoint (broadcast) capability; the ability to vary the mix and quantity of services between destinations in a fully connected mesh network on an almost instantaneous basis through software control; and enhanced reliability with centralized monitor, alarm and control functions by virtue of an overhead channel.

  6. Method of Performance-Aware Security of Unicast Communication in Hybrid Satellite Networks

    Science.gov (United States)

    Roy-Chowdhury, Ayan (Inventor); Baras, John S. (Inventor)

    2014-01-01

    A method and apparatus utilizes Layered IPSEC (LES) protocol as an alternative to IPSEC for network-layer security including a modification to the Internet Key Exchange protocol. For application-level security of web browsing with acceptable end-to-end delay, the Dual-mode SSL protocol (DSSL) is used instead of SSL. The LES and DSSL protocols achieve desired end-to-end communication security while allowing the TCP and HTTP proxy servers to function correctly.

  7. A global network for the control of snail-borne disease using satellite surveillance and geographic information systems.

    Science.gov (United States)

    Malone, J B; Bergquist, N R; Huh, O K; Bavia, M E; Bernardi, M; El Bahy, M M; Fuentes, M V; Kristensen, T K; McCarroll, J C; Yilma, J M; Zhou, X N

    2001-04-27

    At a team residency sponsored by the Rockefeller Foundation in Bellagio, Italy, 10-14 April 2000 an organizational plan was conceived to create a global network of collaborating health workers and earth scientists dedicated to the development of computer-based models that can be used for improved control programs for schistosomiasis and other snail-borne diseases of medical and veterinary importance. The models will be assembled using GIS methods, global climate model data, sensor data from earth observing satellites, disease prevalence data, the distribution and abundance of snail hosts, and digital maps of key environmental factors that affect development and propagation of snail-borne disease agents. A work plan was developed for research collaboration and data sharing, recruitment of new contributing researchers, and means of access of other medical scientists and national control program managers to GIS models that may be used for more effective control of snail-borne disease. Agreement was reached on the use of compatible GIS formats, software, methods and data resources, including the definition of a 'minimum medical database' to enable seamless incorporation of results from each regional GIS project into a global model. The collaboration plan calls for linking a 'central resource group' at the World Health Organization, the Food and Agriculture Organization, Louisiana State University and the Danish Bilharziasis Laboratory with regional GIS networks to be initiated in Eastern Africa, Southern Africa, West Africa, Latin America and Southern Asia. An Internet site, www.gnosisGIS.org, (GIS Network On Snail-borne Infections with special reference to Schistosomiasis), has been initiated to allow interaction of team members as a 'virtual research group'. When completed, the site will point users to a toolbox of common resources resident on computers at member organizations, provide assistance on routine use of GIS health maps in selected national disease control

  8. Saved by Iridium? An Alternative to GPS

    Science.gov (United States)

    2012-05-17

    know this. The enemy presents itself at any time, at any place, in many shapes and forms, often for no apparent reason. As Ecclesiastes 9:18 states...These physical architectures correspond to ground operations in scenarios ranging from complete air superiority to completely denied airspace.”86 A...not interfere with today’s GPS architectures .88 The second developed alternative from Dr. Asher’s group is the Rapidly Deployable Satellite

  9. FCJ-140 Radio Feeds, Satellite Feeds, Network Feeds: Subjectivity Across the Straits of Gibraltar.

    Directory of Open Access Journals (Sweden)

    Nicholas Knouf

    2012-07-01

    Full Text Available This paper engages with the practices surrounding the two fadaiat encounters that took place simultaneously in Spain and Morocco in the summers of 2004 and 2005 (see http://fadaiat.net/ .  The fadaiat project focused on the question of immigration to Europe, specifically from northern Africa, and the ‘Fortress Europe’ responses by European Union governments.  Participants in fadaiat included academic scholars, free software developers, artists, and activists, forming a meta-network that created bridges across disparate communities and practices.  In particular, the participation of the Spanish collective hackitectura was key; they describe themselves as a ‘posse of architects, hackers and social activists experimenting in the merging territories of recombining spatial cyborgs composed by physical spaces, ICT networks and bodies’.  hackitectura led the development of both a temporary civil, non-commercial wireless link across the straits of Gibraltar between Tarifa, Spain and Tangier, Morocco, as well as an entirely free software audio/video streaming system, that enabled participants on both sides to come together independently of the restrictions normally placed on such movement by immigration laws.The importance of free software for fadaiat extends beyond its purely instrumental use as an agent for disrupting state control.  Indeed, the imagery of computation and free software – networks, links, patches, nodes, penguins – pervades the documentation of the project.  Rave parties simulcast across the straits are as important as the discussions and software produced.  I suggest that this can be understood as developing new forms of subjectivity, in the sense given by Felix Guattari, and therefore link the fadaiat project to earlier pirate radio practices, especially Radio Alice in Bologna, Italy, in which Guattari was involved.

  10. The Development of a Field Services Network for a Satellite-Based Educational Telecommunications Experiment. Satellite Technology Demonstration, Technical Report No. 0333.

    Science.gov (United States)

    Anderson, Frank; And Others

    The Satellite Technology Demonstration (STD) of the Federation of Rocky Mountain States (FRMS) employed a technical delivery system to merge effectively hardware and software, products and services. It also needed a nontechnical component to insure product and service acceptance. Accordingly, the STD's Utilization Component was responsible for…

  11. A projector of iridium 192 wires: motivations and preliminary studies

    International Nuclear Information System (INIS)

    Cosset, J.M.; Gerbaulet, A.; Chassagne, D.

    1979-01-01

    Though the majority of procedures involved in curietherapy with Iridium 192 wires cause very few problems concerning radiation protection, this is not true in all cases: in elderly of debilitated patients, young children, or when using special techniques (curietherapy for prostate of bladder cancers for example). In these cases, the need for frequent treatment exposes the therapists to increased doses. The projector of Iridium 192 wires was conceived in order to reduce this irradiated hazard. A simple manipulation places the radioactive wires in a lead container during treatment, and then replaces them in the right position after therapy. This apparatus appears to offer the possibility of: an almost total protection of the therapists, and thus an opportunity for enlarging the indications for curietherapy; an improved quality of treatment to the patient during the application [fr

  12. Hierarchical graph-based segmentation for extracting road networks from high-resolution satellite images

    Science.gov (United States)

    Alshehhi, Rasha; Marpu, Prashanth Reddy

    2017-04-01

    Extraction of road networks in urban areas from remotely sensed imagery plays an important role in many urban applications (e.g. road navigation, geometric correction of urban remote sensing images, updating geographic information systems, etc.). It is normally difficult to accurately differentiate road from its background due to the complex geometry of the buildings and the acquisition geometry of the sensor. In this paper, we present a new method for extracting roads from high-resolution imagery based on hierarchical graph-based image segmentation. The proposed method consists of: 1. Extracting features (e.g., using Gabor and morphological filtering) to enhance the contrast between road and non-road pixels, 2. Graph-based segmentation consisting of (i) Constructing a graph representation of the image based on initial segmentation and (ii) Hierarchical merging and splitting of image segments based on color and shape features, and 3. Post-processing to remove irregularities in the extracted road segments. Experiments are conducted on three challenging datasets of high-resolution images to demonstrate the proposed method and compare with other similar approaches. The results demonstrate the validity and superior performance of the proposed method for road extraction in urban areas.

  13. Diphosphinoazine Rhodium(I) and Iridium(I) Complexes

    Czech Academy of Sciences Publication Activity Database

    Pošta, Martin; Čermák, Jan; Vojtíšek, P.; Císařová, I.

    2006-01-01

    Roč. 71, č. 2 (2006), s. 197-206 ISSN 0010-0765 R&D Projects: GA ČR(CZ) GA203/01/0554; GA ČR(CZ) GA203/99/M037 Institutional research plan: CEZ:AV0Z40720504 Keywords : diphosphinoazines * rhodium complexes * iridium complexes Subject RIV: CC - Organic Chemistry Impact factor: 0.881, year: 2006

  14. Synthesis, structure, redox and spectra of green iridium complexes ...

    Indian Academy of Sciences (India)

    Reactions of IrCl3 ⋅ H2O with the ligands, 2-[(phenylamino)phenylazo]pyridine (HL1a) and 2-[(-tolylamino)phenylazo]pyridine (HL1b) produce [Ir(L1)2]Cl (L1 = L1a, [1]Cl and L1 = L1b, [2]Cl) along with many unidentified products. The iridium complexes have been characterized by various techniques such as X-ray ...

  15. Tracking and Data Relay Satellite System user impact and network compatibility study. [antenna design and telecommunication links

    Science.gov (United States)

    1973-01-01

    The report contains data on antenna configurations for the low data rate users of the Tracking and Data Relay Satellite System (TDRSS). It treats the coverage and mutual visibility considerations between the user satellites and the relay satellites and relates these considerations to requirements of antenna beamwidth and fractional user orbital coverage. A final section includes user/TDRS telecommunication link budgets and forward and return link data rate tradeoffs.

  16. Estimation of corn yield using multi-temporal optical and radar satellite data and artificial neural networks

    Science.gov (United States)

    Fieuzal, R.; Marais Sicre, C.; Baup, F.

    2017-05-01

    The yield forecasting of corn constitutes a key issue in agricultural management, particularly in the context of demographic pressure and climate change. This study presents two methods to estimate yields using artificial neural networks: a diagnostic approach based on all the satellite data acquired throughout the agricultural season, and a real-time approach, where estimates are updated after each image was acquired in the microwave and optical domains (Formosat-2, Spot-4/5, TerraSAR-X, and Radarsat-2) throughout the crop cycle. The results are based on the Multispectral Crop Monitoring experimental campaign conducted by the CESBIO (Centre d'Études de la BIOsphère) laboratory in 2010 over an agricultural region in southwestern France. Among the tested sensor configurations (multi-frequency, multi-polarization or multi-source data), the best yield estimation performance (using the diagnostic approach) is obtained with reflectance acquired in the red wavelength region, with a coefficient of determination of 0.77 and an RMSE of 6.6 q ha-1. In the real-time approach the combination of red reflectance and CHH backscattering coefficients provides the best compromise between the accuracy and earliness of the yield estimate (more than 3 months before the harvest), with an R2 of 0.69 and an RMSE of 7.0 q ha-1 during the development of the central stem. The two best yield estimates are similar in most cases (for more than 80% of the monitored fields), and the differences are related to discrepancies in the crop growth cycle and/or the consequences of pests.

  17. Reverse saturable absorption (RSA) in fluorinated iridium derivatives

    Science.gov (United States)

    Ferry, Michael J.; O'Donnell, Ryan M.; Bambha, Neal; Ensley, Trenton R.; Shensky, William M.; Shi, Jianmin

    2017-08-01

    The photophysical properties of cyclometallated iridium compounds are beneficial for nonlinear optical (NLO) applications, such as the design of reverse saturable absorption (RSA) materials. We report on the NLO characterization of a family of compounds of the form [Ir(pbt)2(LX)], where pbt is 2-phenylbenzothiazole and LX is a beta-diketonate ligand. In particular, we investigate the effects of trifluoromethylation on compound solubility and photophysics compared to the parent acetylacetonate (acac) version. The NLO properties, such as the singlet and triplet excited-state cross sections, of these compounds were measured using the Z-scan technique. The excited-state lifetimes were determined from visible transient absorption spectroscopy.

  18. Angular absorption of iridium - ICW12 needles: practical considerations

    International Nuclear Information System (INIS)

    Szymczyk, W.; Lesiak, J.

    1984-01-01

    An analysis was made of two potential sources of error in Ir 192 dosimetry: the effect of angular absorption and the differences in the ionization constants found in literature. Corrections for selfabsorption in the ICW12 iridium source were determined from measurements and calculations. It was found that the decrease in the dose caused by the angular absorption in the central therapeutic area of a typical implantation can exceed 5 percent. The need for employing the concept of ''constant exposure rate'' is stressed as well as that for using angular absorption in the form of absorption. 13 refs., 6 figs., 1 tab. (author)

  19. Surface temperature monitoring by integrating satellite data and ground thermal camera network on Solfatara Crater in Campi Flegrei volcanic area (Italy)

    Science.gov (United States)

    Buongiorno, M. F.; Musacchio, M.; Silvestri, M.; Vilardo, G.; Sansivero, F.; caPUTO, T.; bellucci Sessa, E.; Pieri, D. C.

    2017-12-01

    Current satellite missions providing imagery in the TIR region at high spatial resolution offer the possibility to estimate the surface temperature in volcanic area contributing in understanding the ongoing phenomena to mitigate the volcanic risk when population are exposed. The Campi Flegrei volcanic area (Italy) is part of the Napolitan volcanic district and its monitored by INGV ground networks including thermal cameras. TIRS on LANDSAT and ASTER on NASA-TERRA provide thermal IR channels to monitor the evolution of the surface temperatures on Campi Flegrei area. The spatial resolution of the TIR data is 100 m for LANDSAT8 and 90 m for ASTER, temporal resolution is 16 days for both satellites. TIRNet network has been developed by INGV for long-term volcanic surveillance of the Flegrei Fields through the acquisition of thermal infrared images. The system is currently comprised of 5 permanent stations equipped with FLIR A645SC thermo cameras with a 640x480 resolution IR sensor. To improve the systematic use of satellite data in the monitor procedures of Volcanic Observatories a suitable integration and validation strategy is needed, also considering that current satellite missions do not provide TIR data with optimal characteristics to observe small thermal anomalies that may indicate changes in the volcanic activity. The presented procedure has been applied to the analysis of Solfatara Crater and is based on 2 different steps: 1) parallel processing chains to produce ground temperature data both from satellite and ground cameras; 2) data integration and comparison. The ground cameras images generally correspond to views of portion of the crater slopes characterized by significant thermal anomalies due to fumarole fields. In order to compare the satellite and ground cameras it has been necessary to take into account the observation geometries. All thermal images of the TIRNet have been georeferenced to the UTM WGS84 system, a regular grid of 30x30 meters has been

  20. Wave activity (planetary, tidal) throughout the middle atmosphere (20-100km) over the CUJO network: Satellite (TOMS) and Medium Frequency (MF) radar observations

    OpenAIRE

    A. H. Manson; C. E. Meek; T. Chshyolkova; S. K. Avery; D. Thorsen; J. W. MacDougall; W. Hocking; Y. Murayama; K. Igarashi

    2005-01-01

    Planetary and tidal wave activity in the tropopause-lower stratosphere and mesosphere-lower thermosphere (MLT) is studied using combinations of ground-based (GB) and satellite instruments (2000-2002). The relatively new MFR (medium frequency radar) at Platteville (40° N, 105° W) has provided the opportunity to create an operational network of middle-latitude MFRs, stretching from 81° W-142° E, which provides winds and tides 70-100km. CUJO (Canada U.S. Japan Opp...

  1. Microindentation hardness evaluation of iridium alloy clad vent set cups

    International Nuclear Information System (INIS)

    Ulrich, G.B.; DeRoos, L.F.; Stinnette, S.E.

    1993-01-01

    An iridium alloy, DOP-26, is used as cladding for 238 PuO 2 fuel in radioisotope heat sources for space power systems. Presently, DOP-26 iridium alloy clad vent sets (CVS) are being manufactured at the Oak Ridge Y-12 Plant for potential use in the National Aeronautics and Space Administration's Cassini mission to Saturn. Wrought/ground/stress relieved blanks are warm formed into CVS cups. These cups are then annealed to recrystallize the material for subsequent fabrication/assembly operations as well as for final use. One of the cup manufacturing certification requirements is to test for Vickers microindentation hardness. New microindentation hardness specification limits, 210 to 310 HV, have been established for a test load of 1000 grams-force (gf). The original specification limits, 250 to 350 HV, were for 200 gf testing. The primary reason for switching to a higher test load was to reduce variability in the test data. The DOP-26 alloy exhibits microindentation hardness load dependence, therefore, new limits were needed for 1000 gf testing. The new limits were established by testing material from 15 CVS cups using 200 gf and 1000 gf loads and then statistically analyzing the data. Additional work using a Knoop indenter and a 10 gf load indicated that the DOP-26 alloy grain boundaries have higher hardnesses than the grain interiors

  2. Iridium-192 implants in the treatment of tonsillar region malignancies

    International Nuclear Information System (INIS)

    Puthawala, A.A.; Syed, A.M.; Gates, T.C.

    1985-01-01

    A total of 127 patients with histologically proved diagnosis of carcinoma of the tonsillar region and soft palate were treated over the past ten years utilizing interstitial iridium-192 implants. Eighty patients were treated for primary tumors and 47 patients for either recurrent or persistent tumors after definitive irradiation and/or surgery. All patients with primary tumors were treated by a combination of external megavoltage irradiation and interstitial iridium-192 implants, whereas patients with recurrent tumors were treated by interstitial implants alone. In the primary group, 95% of patients with T1 and T2 lesions and 79% with T3 and T4 lesions achieved complete local tumor control. The three-year absolute disease-free survival rate was 72%. Seventy-five percent local tumor control was obtained in patients with recurrent disease, with two-year absolute disease-free survival of 42%. Treatment-related complications such as soft-tissue necrosis or osteoradionecrosis occurred in 6% of patients in the primary group and 23% in recurrent group. This treatment regimen offers an excellent locoregional control with no significant functional or esthetic impairment. Most patients with primary lesions who fail this regimen can be salvaged by surgery or reirradiation using interstitial implants

  3. Dosimetry of wires and single ribbons of Iridium 192

    International Nuclear Information System (INIS)

    Mazzucco, L.D.

    1998-01-01

    The objective of this work is in order to present in table formats the dosimetry of wires and single ribbons of Iridium with lengths 1-12 cm for each one linear source along the bisector which is perpendicular at tissue sources (water) computed for linear activity 1 mCi/cm in the case of wires, and 1 mCi/seed for ribbons. The above tables are of direct use, adaptable at particular cases so they facilitate logarithmic graphics of doses in function of the distance for interpolation and use in the treatments planning. It was shown that for two sources with identical linear activity and total length, one of the equidistant seeds at 1 cm (ribbon) and one wire on the other hand, the differences in dose rates in near positions can be about the 15% so corroborating that it is not possible to use wire tables for seeds neither vice versa. Moreover it was elaborated tables of practical direct use for dose rate in water at c Gy/hr for wires and Ribbons 1-12 cm length and from 0.5-10 cm of distance in the perpendicular bisector at the Iridium implant. (Author)

  4. Iridium catalyzed growth of vertically aligned CNTs by APCVD

    International Nuclear Information System (INIS)

    Sahoo, R.K.; Jacob, C.

    2014-01-01

    Highlights: • Growth of uniform-diameter vertically-aligned multi-walled CNTs by APCVD. • Use of high melting point low carbon solubility iridium nanoparticles as catalyst. • Optimization of growth time for uniform sized, uniformly aligned CNTs. • Growth model for the various features in the vertically aligned CNTs is proposed. - Abstract: Vertically aligned carbon nanotubes (VA-CNTs) have been synthesized using high temperature catalyst nanoparticles of iridium. The catalyst layer was prepared by DC sputtering. Particle density, circularity and average particle size of the catalyst were analyzed using field emission scanning electron microscopy. The alignment, morphology and the length of the as-grown CNTs were analyzed using field-emission scanning electron microscopy. High resolution transmission electron microscopy was carried out to observe the layers of graphitic stacking which form the carbon nanotubes. Micro Raman measurement was used for the analysis of the graphitic crystallinity of the as-grown carbon nano structures. Effects of growth time variation on growth morphology and alignment have been studied. The alignment has been explained on the basis of the crowding effect of the neighboring nanoparticles

  5. Iridium catalyzed growth of vertically aligned CNTs by APCVD

    Energy Technology Data Exchange (ETDEWEB)

    Sahoo, R.K.; Jacob, C., E-mail: cxj14_holiday@yahoo.com

    2014-07-01

    Highlights: • Growth of uniform-diameter vertically-aligned multi-walled CNTs by APCVD. • Use of high melting point low carbon solubility iridium nanoparticles as catalyst. • Optimization of growth time for uniform sized, uniformly aligned CNTs. • Growth model for the various features in the vertically aligned CNTs is proposed. - Abstract: Vertically aligned carbon nanotubes (VA-CNTs) have been synthesized using high temperature catalyst nanoparticles of iridium. The catalyst layer was prepared by DC sputtering. Particle density, circularity and average particle size of the catalyst were analyzed using field emission scanning electron microscopy. The alignment, morphology and the length of the as-grown CNTs were analyzed using field-emission scanning electron microscopy. High resolution transmission electron microscopy was carried out to observe the layers of graphitic stacking which form the carbon nanotubes. Micro Raman measurement was used for the analysis of the graphitic crystallinity of the as-grown carbon nano structures. Effects of growth time variation on growth morphology and alignment have been studied. The alignment has been explained on the basis of the crowding effect of the neighboring nanoparticles.

  6. Microindentation hardness evaluation of iridium alloy clad vent set cups

    International Nuclear Information System (INIS)

    Ulrich, G.B.; DeRoos, L.F.; Stinnette, S.E.

    1992-01-01

    An iridium alloy, DOP-26, is used as cladding for 238 PuO 2 fuel in radioisotope heat sources for space power systems. Presently, DOP-26 iridium alloy clad vent sets (CVS) are being manufactured at the Oak Ridge Y-12 Plant for potential use in the National Aeronautics and Space Administration's Cassini mission to Saturn. Wrought/ground/stress relieved blanks are warm formed into CVS cups. These cups are then annealed to recrystallize the material for subsequent fabrication/assembly operations as well as for final use. One of the cup manufacturing certification requirements is to test for Vickers microindentation hardness. New microindentation hardness specification limits, 210 to 310 HV, have been established for a test load of 1000 grams-force (gf). The original specification limits, 250 to 350 HV, were for 200 gf testing. The primary reason for switching to a higher test load was to reduce variability in the test data. The DOP-26 alloy exhibits microindentation hardness load dependence, therefore, new limits were needed for 1000 gf testing. The new limits were established by testing material from 15 CVS cups using 200 gf and 1000 gf loads and then statistically analyzing the data. Additional work using a Knoop indenter and a 10 gf load indicated that the DOP-26 alloy grain boundaries have higher hardnesses than the grain interiors

  7. Incorporation of iridium into electrodeposited rhenium–nickel alloys

    International Nuclear Information System (INIS)

    Cohen Sagiv, Maayan; Eliaz, Noam; Gileadi, Eliezer

    2013-01-01

    Rhenium (Re), a refractory metal that has gained significant recognition as a high performance engineering material, is mostly used in military, aircraft and aerospace applications, as well as for catalysis in the petrochemical industry. However, its performance at high temperature in humid air is limited by the formation of rhenium heptoxide (Re 2 O 7 ), which penetrates the grain boundaries and causes brittleness. Improvement of this is being sought through the incorporation of iridium (Ir) into Re deposits. To this end, suitable plating baths for Re–Ir–Ni coatings were developed. These alloys were deposited from different aqueous solutions on copper substrates under galvanostatic conditions, in a three-electrode cell. The plating bath consisted of iridium tri-chloride, ammonium perrhenate and nickel sulfamate as the electroactive species, and citric acid as the complexing agent. The effects of bath composition and operating conditions on the Faradaic efficiency (FE), partial current densities, as well as on the thickness of the coatings and their composition were studied. Re–Ir–Ni coatings as thick as 18 μm, with Re-content as high as 73 at.% and Ir-content as high as 29 at.%, were obtained, using different plating baths. A mechanism of the electrochemical process was suggested. It was found that both an HCP Ir 0.4 Re 0.6 phase and an HCP Ni phase with nanometric crystallites were formed, possibly together with a hexagonal nickel hydride (Ni 2 H) phase

  8. Dynamic high-temperature characterization of an iridium alloy in tension

    Energy Technology Data Exchange (ETDEWEB)

    Song, Bo [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Nelson, Kevin [Sandia National Lab. (SNL-CA), Livermore, CA (United States); Jin, Helena [Sandia National Lab. (SNL-CA), Livermore, CA (United States); Lipinski, Ronald J. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Bignell, John [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Ulrich, G. B. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); George, E. P. [Ruhr Univ., Bochum (Germany)

    2015-09-01

    Iridium alloys have been utilized as structural materials for certain high-temperature applications, due to their superior strength and ductility at elevated temperatures. The mechanical properties, including failure response at high strain rates and elevated temperatures of the iridium alloys need to be characterized to better understand high-speed impacts at elevated temperatures. A DOP-26 iridium alloy has been dynamically characterized in compression at elevated temperatures with high-temperature Kolsky compression bar techniques. However, the dynamic high-temperature compression tests were not able to provide sufficient dynamic high-temperature failure information of the iridium alloy. In this study, we modified current room-temperature Kolsky tension bar techniques for obtaining dynamic tensile stress-strain curves of the DOP-26 iridium alloy at two different strain rates (~1000 and ~3000 s-1) and temperatures (~750°C and ~1030°C). The effects of strain rate and temperature on the tensile stress-strain response of the iridium alloy were determined. The DOP-26 iridium alloy exhibited high ductility in stress-strain response that strongly depended on both strain rate and temperature.

  9. The feasibility of retrieving vertical temperature profiles from satellite nadir UV observations: A sensitivity analysis and an inversion experiment with neural network algorithms

    International Nuclear Information System (INIS)

    Sellitto, P.; Del Frate, F.

    2014-01-01

    Atmospheric temperature profiles are inferred from passive satellite instruments, using thermal infrared or microwave observations. Here we investigate on the feasibility of the retrieval of height resolved temperature information in the ultraviolet spectral region. The temperature dependence of the absorption cross sections of ozone in the Huggins band, in particular in the interval 320–325 nm, is exploited. We carried out a sensitivity analysis and demonstrated that a non-negligible information on the temperature profile can be extracted from this small band. Starting from these results, we developed a neural network inversion algorithm, trained and tested with simulated nadir EnviSat-SCIAMACHY ultraviolet observations. The algorithm is able to retrieve the temperature profile with root mean square errors and biases comparable to existing retrieval schemes that use thermal infrared or microwave observations. This demonstrates, for the first time, the feasibility of temperature profiles retrieval from space-borne instruments operating in the ultraviolet. - Highlights: • A sensitivity analysis and an inversion scheme to retrieve temperature profiles from satellite UV observations (320–325 nm). • The exploitation of the temperature dependence of the absorption cross section of ozone in the Huggins band is proposed. • First demonstration of the feasibility of temperature profiles retrieval from satellite UV observations. • RMSEs and biases comparable with more established techniques involving TIR and MW observations

  10. Improved monitoring of phytoplankton bloom dynamics in a Norwegian fjord by integrating satellite data, pigment analysis, and Ferrybox data with a coastal observation network

    Science.gov (United States)

    Volent, Zsolt; Johnsen, Geir; Hovland, Erlend K.; Folkestad, Are; Olsen, Lasse M.; Tangen, Karl; Sørensen, Kai

    2011-01-01

    Monitoring of the coastal environment is vitally important as these areas are of economic value and at the same time highly exposed to anthropogenic influence, in addition to variation of environmental variables. In this paper we show how the combination of bio-optical data from satellites, analysis of water samples, and a ship-mounted automatic flow-through sensor system (Ferrybox) can be used to detect and monitor phytoplankton blooms both spatially and temporally. Chlorophyll a (Chl a) data and turbidity from Ferrybox are combined with remotely sensed Chl a and total suspended matter from the MERIS instrument aboard the satellite ENVISAT (ENVIronmental SATellite) European Space Agency. Data from phytoplankton speciation and enumeration obtained by a national coastal observation network consisting of fish farms and the Norwegian Food Safety Authority are supplemented with data on phytoplankton pigments. All the data sets are then integrated in order to describe phytoplankton bloom dynamics in a Norwegian fjord over a growth season, with particular focus on Emiliania huxleyi. The approach represents a case example of how coastal environmental monitoring can be improved with existing instrument platforms. The objectives of the paper is to present the operative phytoplankton monitoring scheme in Norway, and to present an improved model of how such a scheme can be designed for a large part of the world's coastal areas.

  11. Satellite retrievals of Karenia brevis harmful algal blooms in the West Florida shelf using neural networks and impacts of temporal variabilities

    Science.gov (United States)

    El-Habashi, Ahmed; Duran, Claudia M.; Lovko, Vincent; Tomlinson, Michelle C.; Stumpf, Richard P.; Ahmed, Sam

    2017-07-01

    We apply a neural network (NN) technique to detect/track Karenia brevis harmful algal blooms (KB HABs) plaguing West Florida shelf (WFS) coasts from Visible-Infrared Imaging Radiometer Suite (VIIRS) satellite observations. Previously KB HABs detection primarily relied on the Moderate Resolution Imaging Spectroradiometer Aqua (MODIS-A) satellite, depending on its remote sensing reflectance signal at the 678-nm chlorophyll fluorescence band (Rrs678) needed for normalized fluorescence height and related red band difference retrieval algorithms. VIIRS, MODIS-A's successor, does not have a 678-nm channel. Instead, our NN uses Rrs at 486-, 551-, and 671-nm VIIRS channels to retrieve phytoplankton absorption at 443 nm (a). The retrieved a images are next filtered by applying limits, defined by (i) low Rrs551-nm backscatter and (ii) a minimum a value associated with KB HABs. The filtered residual images are then converted to show chlorophyll-a concentrations [Chla] and KB cell counts. VIIRS retrievals using our NN and five other retrieval algorithms were compared and evaluated against numerous in situ measurements made over the four-year 2012 to 2016 period, for which VIIRS data are available. These comparisons confirm the viability and higher retrieval accuracies of the NN technique, when combined with the filtering constraints, for effective detection of KB HABs. Analysis of these results as well as sequential satellite observations and recent field measurements underline the importance of short-term temporal variabilities on retrieval accuracies.

  12. Balancing activity, stability and conductivity of nanoporous core-shell iridium/iridium oxide oxygen evolution catalysts

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Yong-Tae; Lopes, Pietro Papa; Park, Shin-Ae; Lee, A-Yeong; Lim, Jinkyu; Lee, Hyunjoo; Back, Seoin; Jung, Yousung; Danilovic, Nemanja; Stamenkovic, Vojislav; Erlebacher, Jonah; Snyder, Joshua; Markovic, Nenad M.

    2017-11-13

    The selection of oxide materials for catalyzing the Oxygen Evolution Reaction in acid-based electrolyzers must be guided by the proper balance between activity, stability and conductivity – a challenging mission of great importance for delivering affordable and environmentally friendly hydrogen. Here we report that the highly conductive nanoporous architecture of an iridium oxide shell on a metallic iridium core, formed through the fast dealloying of osmium from an Ir25Os75 alloy, exhibits an exceptional balance between oxygen evolution activity and stability as quantified by the Activity-Stability FactorASF. Based on this metric, the nanoporous Ir/IrO2 morphology of dealloyed Ir25Os75 shows a factor of ~30 improvement ASFrelative to conventional Ir-based oxide materials and a ~8 times improvement over dealloyed Ir25Os75 nanoparticles due to optimized stability and conductivity, respectively. We propose that the Activity-Stability FactorASF is the key “metric” for determining the technological relevance of oxide-based anodic water electrolyzer catalysts.

  13. A preliminary study of factors affecting the calibration stability of the iridium versus iridium-40 percent rhodium thermocouple

    Science.gov (United States)

    Ahmed, Shaffiq; Germain, Edward F.; Daryabeigi, Kamran; Alderfer, David W.; Wright, Robert E.

    1987-01-01

    An iridium versus iridium-40% rhodium thermocouple was studied. Problems associated with the use of this thermocouple for high temperature applications (up to 2000 C) were investigated. The metallurgical studies included X-ray, macroscopic, resistance, and metallographic studies. The thermocouples in the as-received condition from the manufacturer revealed large amounts of internal stress caused by cold working during manufacturing. The thermocouples also contained a large amount of inhomogeneities and segregations. No phase transformations were observed in the alloy up to 1100 C. It was found that annealing the thermocouple at 1800 C for two hours, and then at 1400 C for 2 to 3 hours yielded a fine grain structure, relieving some of the strains, and making the wire more ductile. It was also found that the above annealing procedure stabilized the thermal emf behavior of the thermocouple for application below 1800 C (an improvement from + or - 1% to + or - 0.02% within the range of the test parameters used).

  14. ESA's satellite communications programme

    Science.gov (United States)

    Bartholome, P.

    1985-02-01

    The developmental history, current status, and future plans of the ESA satellite-communications programs are discussed in a general survey and illustrated with network diagrams and maps. Consideration is given to the parallel development of national and European direct-broadcast systems and telecommunications networks, the position of the European space and electronics industries in the growing world market, the impact of technological improvements (both in satellite systems and in ground-based networks), and the technological and commercial advantages of integrated space-terrestrial networks. The needs for a European definition of the precise national and international roles of satellite communications, for maximum speed in implementing such decisions (before the technology becomes obsolete), and for increased cooperation and standardization to assure European equipment manufacturers a reasonable share of the market are stressed.

  15. Iridium Oxide pH Sensor Based on Stainless Steel Wire for pH Mapping on Metal Surface

    Science.gov (United States)

    Shahrestani, S.; Ismail, M. C.; Kakooei, S.; Beheshti, M.; Zabihiazadboni, M.; Zavareh, M. A.

    2018-03-01

    A simple technique to fabricate the iridium oxide pH sensor is useful in several applications such as medical, food processing and engineering material where it is able to detect the changes of pH. Generally, the fabrication technique can be classified into three types: electro-deposition iridium oxide film (EIrOF), activated iridium oxide film (AIROF) and sputtering iridium oxide film (SIROF). This study focuses on fabricating electrode, calibration and test. Electro-deposition iridium oxide film is a simple and effective method of fabricating this kind of sensor via cyclic voltammetry process. The iridium oxide thick film was successfully electrodeposited on the surface of stainless steel wire with 500 cycles of sweep potential. A further analysis under FESEM shows detailed image of iridium oxide film which has cauliflower-liked microstructure. EDX analysis shows the highest element present are iridium and oxygen which concluded that the process is successful. The iridium oxide based pH sensor has shown a good performance in comparison to conventional glass pH sensor when it is being calibrated in buffer solutions with 2, 4, 7 and 9 pH values. The iridium oxide pH sensor is specifically designed to measure the pH on the surface of metal plate.

  16. Citizen-Enabled Aerosol Measurements for Satellites (CEAMS): A Network for High-Resolution Measurements of PM2.5 and Aerosol Optical Depth

    Science.gov (United States)

    Pierce, J. R.; Volckens, J.; Ford, B.; Jathar, S.; Long, M.; Quinn, C.; Van Zyl, L.; Wendt, E.

    2017-12-01

    Atmospheric particulate matter with diameter smaller than 2.5 μm (PM2.5) is a pollutant that contributes to the development of human disease. Satellite-derived estimates of surface-level PM2.5 concentrations have the potential to contribute greatly to our understanding of how particulate matter affects health globally. However, these satellite-derived PM2.5 estimates are often uncertain due to a lack of information about the ratio of surface PM2.5 to aerosol optical depth (AOD), which is the primary aerosol retrieval made by satellite instruments. While modelling and statistical analyses have improved estimates of PM2.5:AOD, large uncertainties remain in situations of high PM2.5 exposure (such as urban areas and in wildfire-smoke plumes) where the health impacts of PM2.5 may be the greatest. Surface monitoring networks for co-incident PM2.5 and AOD measurements are extremely rare, even in the North America. To provide constraints for the PM2.5:AOD relationship, we have developed a relatively low-cost (application (iOS and Android). Sun photometry is performed across 4 discrete wavelengths that match those reported by the Aerosol Robotic Network (AERONET). Aerosol concentration is reported using both time-integrated filter mass (analyzed in an academic laboratory and reported as a 24-48hr average) and a continuous PM sensor within the instrument. Citizen scientists use the device to report daily AOD and PM2.5 measurements made in their backyards to a central server for data display and download. In this presentation, we provide an overview of (1) AOD and PM2.5 measurement calibration; (2) citizen recruiting and training efforts; and (3) results from our pilot citizen-science measurement campaign.

  17. An iron-57 Moessbauer spectroscopic study of titania-supported iron- and iron-iridium catalysts

    International Nuclear Information System (INIS)

    Berry, F.J.; Jobson, S.

    1992-01-01

    57 Fe Moessbauer spectroscopy shows that titania-supported iron is reduced by treatment in hydrogen at significantly lower temperatures than corresponding silica- and alumina-supported catalysts. The metallic iron formed under hydrogen at 600deg C is partially converted to carbide by treatment in carbon monoxide and hydrogen. In contrast to its alumina- and silica-supported counterparts, the remainder of the titania-supported iron is unchanged by this gaseous mixture. The 57 Fe Moessbauer spectra of EXAFS show that iron and iridium in the titania-supported iron-iridium catalysts are reduced in hydrogen at even lower temperatures and, after treatment at 600deg C, are predominantly present as the iron-iridium alloy. The treatment of these reduced catalysts in carbon monoxide and hydrogen is shown by Moessbauer spectroscopy and EXAFS to induce the segregation of iron from the iron-iridium alloy and its conversion to iron oxide. (orig.)

  18. Effect of the lead screen in the radiographic image using iridium 192 as a source

    International Nuclear Information System (INIS)

    Garate Rojas, M.

    1983-01-01

    It's presented the effect of the lead screen in the image obtained on an impressionable film used in industrial gammagraphy. The source used was Iridium 192 and the tests were simulated like a real inspection. (E.G.) [pt

  19. Iridium-catalyst-based autonomous bubble-propelled graphene micromotors with ultralow catalyst loading.

    Science.gov (United States)

    Wang, Hong; Sofer, Zdeněk; Eng, Alex Yong Sheng; Pumera, Martin

    2014-11-10

    A novel concept of an iridium-based bubble-propelled Janus-particle-type graphene micromotor with very high surface area and with very low catalyst loading is described. The low loading of Ir catalyst (0.54 at %) allows for fast motion of graphene microparticles with high surface area of 316.2 m(2)  g(-1). The micromotor was prepared with a simple and scalable method by thermal exfoliation of iridium-doped graphite oxide precursor composite in hydrogen atmosphere. Oxygen bubbles generated from the decomposition of hydrogen peroxide at the iridium catalytic sites provide robust propulsion thrust for the graphene micromotor. The high surface area and low iridium catalyst loading of the bubble-propelled graphene motors offer great possibilities for dramatically enhanced cargo delivery. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  20. Influence of iridium on the reactivity of LaFeO3 base perovskites

    DEFF Research Database (Denmark)

    Kindermann, L.; Das, D.; Bahadur, D.

    1998-01-01

    The influence of iridium on the reactivity of powder mixtures made of perovskites and 8 mol% yttria stabilized zirconia (8 YSZ) is reported. Iridium is added to the perovskites of the composition (La0.6M0.4)(z)Fe0.8TM0.2O3-delta (M = Sr, Ca; TM = Mn, Co; z = 0.90, 1.00) via the gaseous phase....... Iridium is present in the perovskite lattice as Ir4+ replacing iron as is evident from XRD and TEM/EDX results. Compatibility studies carried out at 1000 degrees C demonstrate that iridium has considerable influence on the reactivity. The results are discussed with respect to the stability...... of the perovskites, thermodynamic activities, Ir(IV)-O bonding, tolerance factor and oxygen migration....

  1. Low-Stress Iridium Coatings for Thin-Shell X-Ray Telescopes, Phase II

    Data.gov (United States)

    National Aeronautics and Space Administration — We propose to develop and commercialize a new type of low-stress iridium (Ir) X-ray mirror coating technology that can be used for the construction of...

  2. Postimpact examinations of three DOP 4 iridium shells from simulant fuel sphere assemblies

    International Nuclear Information System (INIS)

    Cramer, E.M.; Hecker, S.S.

    1975-12-01

    Three fuel sphere assemblies, with thoria in doped iridium containment shells, were examined after a simulated earth impact from an aborted orbital mission of a multihundred-watt thermoelectric heat source. The extent of deformation of each unit was measured. Damage to the containment shells was minimal in comparison to that in undoped iridium. Metallographic sections from critical areas indicated that superficial grain boundary cracking in weld zones and microscopic cracking in regions of maximum diameter had occurred in addition to local thinning and coining. The improved properties of the doped iridium are attributed to the retention of a small grain size and to an additional fracture resistance over iridium of a comparable grain size, imparted by either a change in grain boundary chemistry or the flow characteristics of the doped material

  3. Enantioselective synthesis of almorexant via iridium-catalysed intramolecular allylic amidation

    NARCIS (Netherlands)

    Fananas Mastral, Martin; Teichert, Johannes F.; Fernandez-Salas, Jose Antonio; Heijnen, Dorus; Feringa, Ben L.

    2013-01-01

    An enantioselective synthesis of almorexant, a potent antagonist of human orexin receptors, is presented. The chiral tetrahydroisoquinoline core structure was prepared via iridium-catalysed asymmetric intramolecular allylic amidation. Further key catalytic steps of the synthesis include an oxidative

  4. Electron beam welding of iridium heat source capsules

    International Nuclear Information System (INIS)

    Mustaleski, T.M.; Yearwood, J.C.; Burgan, C.E.; Green, L.A.

    1991-01-01

    The development of the welding procedures for the production of DOP-26 iridium alloy cups for heat source encapsulation is described. All the final assembly welds were made using the electron beam welding process. The welding of the 0.13-mm weld shield required the use of computer controlled X-Y table and a run-off tab. Welding of the frit vent to the cup required that a laser weld be made to hold the frit assembly edges together for the final electron beam weld. Great care is required in tooling design and beam placement to achieve acceptable results. Unsuccessful attempts to use laser beam welding for heat shield butt weld are discussed

  5. Enantiomeric separation of iridium (III) complexes using HPLC chiral stationary phases based on amylose derivatives

    International Nuclear Information System (INIS)

    Kim, Hee Eun; Seo, Na Hyeon; Hyun, Myung Ho

    2016-01-01

    Cyclometalated iridium (III) complexes formed with three identical cyclometalating (C-N) ligands (homoleptic) or formed with two cyclometalating (C-N) ligands and one ancillary (LX) ligand (heteroleptic) have been known as highly phosphorescent materials and, thus, they have been utilized as efficient phosphorescent dopants in organic light emitting diodes (OLEDs) 1–3 or as effective phosphorescent chemosensors. 4–7 Cylometalated iridium (III) complexes are chiral compounds consisting of lambda (Λ, left-handed) and delta (Δ, right-handed) isomers. Racemic cyclometa- lated iridium (III) complexes emit light with no net polarization, but optically active cyclometalated iridium (III) complexes emit circularly polarized light. 8,9 Circularly polarized light can be used in various fields including highly efficient three dimensional electronic devices, photo nic devices for optical data storage, biological assays, and others. 8,9 In order to obtain optically active cylometalated iridium (III) complexes and to determine the enantiomeric composition of optically active cylometalated iridium (III) complexes, liquid chromatogr aphic enantiomer separation method on chiral stationary phases (CSPs) has been used. For example, Okamoto and coworkers first reported the high performance liquid chromatographic (HPLC) direct enantiomeric separation of two homoleptic cylometalated iridium (III) complexes on immobilized amylose tris(3,5- dimethylphenylcarbamate) (Chiralpak IA), coated cellulose tris(3,5-dimethylphenylcarbamate) (Chiralc el OD), and coated cellulose tris(4-methylbenzoate) (Chiralce l OJ). 10 Supercritical fluid chromatography (SFC) was also used by Bernhard and coworkers for the enantiomeric separation of cylometalated iridium (III) complexes on coated amylose tris(3,5-dimethylphenylcarbamate) (Chiralpak AD-H). 8 However, the general use of the HPLC method for the direct enantiomeric separation of homoleptic

  6. Iridium-Catalyzed Condensation of Primary Amines To Form Secondary Amines

    DEFF Research Database (Denmark)

    Lorentz-Petersen, Linda Luise Reeh; Jensen, Paw; Madsen, Robert

    2009-01-01

    Symmetric secondary amines are readily obtained by heating a neat primary amine with 0.5 mol% of bis(dichloro[eta(5)-pentamethylcyclopentadienyl]iridium). The products are isolated by direct distillation in good yields.......Symmetric secondary amines are readily obtained by heating a neat primary amine with 0.5 mol% of bis(dichloro[eta(5)-pentamethylcyclopentadienyl]iridium). The products are isolated by direct distillation in good yields....

  7. Enantiomeric separation of iridium (III) complexes using HPLC chiral stationary phases based on amylose derivatives

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Hee Eun; Seo, Na Hyeon; Hyun, Myung Ho [Dept. of Chemistry and Chemistry Institute for Functional Materials, Pusan National University, Busan (Korea, Republic of)

    2016-12-15

    Cyclometalated iridium (III) complexes formed with three identical cyclometalating (C-N) ligands (homoleptic) or formed with two cyclometalating (C-N) ligands and one ancillary (LX) ligand (heteroleptic) have been known as highly phosphorescent materials and, thus, they have been utilized as efficient phosphorescent dopants in organic light emitting diodes (OLEDs) 1–3 or as effective phosphorescent chemosensors. 4–7 Cylometalated iridium (III) complexes are chiral compounds consisting of lambda (Λ, left-handed) and delta (Δ, right-handed) isomers. Racemic cyclometa- lated iridium (III) complexes emit light with no net polarization, but optically active cyclometalated iridium (III) complexes emit circularly polarized light. 8,9 Circularly polarized light can be used in various fields including highly efficient three dimensional electronic devices, photo nic devices for optical data storage, biological assays, and others. 8,9 In order to obtain optically active cylometalated iridium (III) complexes and to determine the enantiomeric composition of optically active cylometalated iridium (III) complexes, liquid chromatogr aphic enantiomer separation method on chiral stationary phases (CSPs) has been used. For example, Okamoto and coworkers first reported the high performance liquid chromatographic (HPLC) direct enantiomeric separation of two homoleptic cylometalated iridium (III) complexes on immobilized amylose tris(3,5- dimethylphenylcarbamate) (Chiralpak IA), coated cellulose tris(3,5-dimethylphenylcarbamate) (Chiralc el OD), and coated cellulose tris(4-methylbenzoate) (Chiralce l OJ). 10 Supercritical fluid chromatography (SFC) was also used by Bernhard and coworkers for the enantiomeric separation of cylometalated iridium (III) complexes on coated amylose tris(3,5-dimethylphenylcarbamate) (Chiralpak AD-H). 8 However, the general use of the HPLC method for the direct enantiomeric separation of homoleptic.

  8. Iridium-Knife: Another knife in radiation oncology.

    Science.gov (United States)

    Milickovic, Natasa; Tselis, Nikolaos; Karagiannis, Efstratios; Ferentinos, Konstantinos; Zamboglou, Nikolaos

    Intratarget dose escalation with superior conformity is a defining feature of three-dimensional (3D) iridium-192 ( 192 Ir) high-dose-rate (HDR) brachytherapy (BRT). In this study, we analyzed the dosimetric characteristics of interstitial 192 Ir HDR BRT for intrathoracic and cerebral malignancies. We examined the dose gradient sharpness of HDR BRT compared with that of linear accelerator-based stereotactic radiosurgery and stereotactic body radiation therapy, usually called X-Knife, to demonstrate that it may as well be called a Knife. Treatment plans for 10 patients with recurrent glioblastoma multiforme or intrathoracic malignancies, five of each entity, treated with X-Knife (stereotactic radiosurgery for glioblastoma multiforme and stereotactic body radiation therapy for intrathoracic malignancies) were replanned for simulated HDR BRT. For 3D BRT planning, we used identical structure sets and dose prescription as for the X-Knife planning. The indices for qualitative treatment plan analysis encompassed planning target volume coverage, conformity, dose falloff gradient, and the maximum dose-volume limits to different organs at risk. Volume coverage in HDR plans was comparable to that calculated for X-Knife plans with no statistically significant difference in terms of conformity. The dose falloff gradient-sharpness-of the HDR plans was considerably steeper compared with the X-Knife plans. Both 3D 192 Ir HDR BRT and X-Knife are effective means for intratarget dose escalation with HDR BRT achieving at least equal conformity and a steeper dose falloff at the target volume margin. In this sense, it can reasonably be argued that 3D 192 Ir HDR BRT deserves also to be called a Knife, namely Iridium-Knife. Copyright © 2017 American Brachytherapy Society. Published by Elsevier Inc. All rights reserved.

  9. Single step radiolytic synthesis of iridium nanoparticles onto graphene oxide

    International Nuclear Information System (INIS)

    Rojas, J.V.; Molina Higgins, M.C.; Toro Gonzalez, M.; Castano, C.E.

    2015-01-01

    Graphical abstract: - Highlights: • Ir nanoparticles were synthesized through a single step gamma irradiation process. • Homogeneously distributed Ir nanoparticles on graphene oxide are ∼2.3 nm in size. • Ir−O bonds evidenced the interaction of the nanoparticles with the support. - Abstract: In this work a new approach to synthesize iridium nanoparticles on reduced graphene oxide is presented. The nanoparticles were directly deposited and grown on the surface of the carbon-based support using a single step reduction method through gamma irradiation. In this process, an aqueous isopropanol solution containing the iridium precursor, graphene oxide, and sodium dodecyl sulfate was initially prepared and sonicated thoroughly to obtain a homogeneous dispersion. The samples were irradiated with gamma rays with energies of 1.17 and 1.33 MeV emitted from the spontaneous decay of the 60 Co irradiator. The interaction of gamma rays with water in the presence of isopropanol generates highly reducing species homogeneously distributed in the solution that can reduce the Ir precursor down to a zero valence state. An absorbed dose of 60 kGy was used, which according to the yield of reducing species is sufficient to reduce the total amount of precursor present in the solution. This novel approach leads to the formation of 2.3 ± 0.5 nm Ir nanoparticles distributed along the surface of the support. The oxygenated functionalities of graphene oxide served as nucleation sites for the formation of Ir nuclei and their subsequent growth. XPS results revealed that the interaction of Ir with the support occurs through Ir−O bonds.

  10. Real-time clock and orbit calculation of the GPS satellite constellation based on observation data of RTIGS-station network

    International Nuclear Information System (INIS)

    Thaler, G.

    2011-01-01

    Due to the development of faster communication networks and improving computer technology beside postprocessing techniques real-time applications and services are more and more created and used in the eld of precise positioning and navigation using global navigation satellite systems (GNSS) like GPS. Data formats like RTCM (NTRIP) or RTIGS serve in this manner as basic tool to transmit real-time GNSS observation data to a eld of users. To handle this trend to real-time, the International GNSS Service (IGS) or more precisely the Real-Time Working Group (RTWG) of the IGS started to establish a global GNSS station network several years ago. These reference stations (RTIGS stations) transmit their observation data in real-time via the open internet to registerd users to support the development of potential new real-time products and services. One example for such a new real-time application based on the observations of the RTIGS network is the software RTIGU-Control developed within this PHD thesis. RTIGU-Control fulls 2 main tasks. The rst task is the monitoring (integrity) of the predicted IGS orbit and clock products (IGU products) using real-time observations from the station network. The second task deals with calculating more precise satellite and station clock corrections compared to the predicted values of the IGU solutions based on the already very precise IGU orbit solutions. In a rst step RTIGU-Control calculates based on the IGU orbit predictions together with code-smoothed station observations precise values for the satellite and station clock corrections.The code-smoothed observations are additionally corrected for several corrections eecting the GNSS observations (for example the delay of the signal propagation time due to the atmosphere, relativistic eects, etc.). The second calculation step deals with monitoring the IGU predicted orbits using the calculated clock solution in the calculation step before and again the corrected real-time observations

  11. Synthesis and characterization of low-valence actinide phosphide tellurides and ternary selenium-halide iridium complexes; Synthese und Charakterisierung niedervalenter Actinoidphosphidtelluride und ternaerer Selen-Halogenid-Komplexe des Iridiums

    Energy Technology Data Exchange (ETDEWEB)

    Stolze, Karoline

    2016-04-07

    The thesis on the synthesis and characterization of low-valence actinide phosphide tellurides and ternary selenium-halide iridium complexes includes two parts: a description of the experimental synthesis of UPTe and U2PTe2O and ThPTe and the synthesis of selenium-chloride iridium complexes and selenium-bromide iridium complexes. The characterization included X-ray diffraction and phase studies.

  12. Randomness-Based Scale-Chromatic Image Analysis for Interactive Mapping on Satellite-Roadway-Vehicle Network

    Directory of Open Access Journals (Sweden)

    Kohji Kamejima

    2007-08-01

    Full Text Available A new framework is presented for integrating satellite/avionics sensors with onboard vision to support information intensive maneuvering. Real time bindings of the bird's eye observation and the driver's view via GPS provides \\textit{as-is} basis for perception and decision. Randomness-based roadway pattern model is implemented by fractal coding scheme associating bird's eye and frontal views. The feasibility of the framework with resquirements for vison system is discussed through concept modeling and experimental studies.

  13. Randomness-Based Scale-Chromatic Image Analysis for Interactive Mapping on Satellite-Roadway-Vehicle Network

    Directory of Open Access Journals (Sweden)

    Kohji Kamejima

    2007-08-01

    Full Text Available A new framework is presented for integrating satellite/avionics sensors with onboard vision to support information intensive maneuvering. Real time bindings of the bird's eye observation and the driver's view via GPS provides extit{as-is} basis for perception and decision. Randomness-based roadway pattern model is implemented by fractal coding scheme associating bird's eye and frontal views. The feasibility of the framework with resquirements for vison system is discussed through concept modeling and experimental studies.

  14. Dynamic High-Temperature Characterization of an Iridium Alloy in Compression at High Strain Rates

    Energy Technology Data Exchange (ETDEWEB)

    Song, Bo [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States). Experimental Environment Simulation Dept.; Nelson, Kevin [Sandia National Lab. (SNL-CA), Livermore, CA (United States). Mechanics of Materials Dept.; Lipinski, Ronald J. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States). Advanced Nuclear Fuel Cycle Technology Dept.; Bignell, John L. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States). Structural and Thermal Analysis Dept.; Ulrich, G. B. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Radioisotope Power Systems Program; George, E. P. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Radioisotope Power Systems Program

    2014-06-01

    Iridium alloys have superior strength and ductility at elevated temperatures, making them useful as structural materials for certain high-temperature applications. However, experimental data on their high-temperature high-strain-rate performance are needed for understanding high-speed impacts in severe elevated-temperature environments. Kolsky bars (also called split Hopkinson bars) have been extensively employed for high-strain-rate characterization of materials at room temperature, but it has been challenging to adapt them for the measurement of dynamic properties at high temperatures. Current high-temperature Kolsky compression bar techniques are not capable of obtaining satisfactory high-temperature high-strain-rate stress-strain response of thin iridium specimens investigated in this study. We analyzed the difficulties encountered in high-temperature Kolsky compression bar testing of thin iridium alloy specimens. Appropriate modifications were made to the current high-temperature Kolsky compression bar technique to obtain reliable compressive stress-strain response of an iridium alloy at high strain rates (300 – 10000 s-1) and temperatures (750°C and 1030°C). Uncertainties in such high-temperature high-strain-rate experiments on thin iridium specimens were also analyzed. The compressive stress-strain response of the iridium alloy showed significant sensitivity to strain rate and temperature.

  15. Formation of nano iridium oxide: material properties and neural cell culture

    International Nuclear Information System (INIS)

    Lee, In-Seop; Whang, Chung-Nam; Lee, Young-Hee; Hwan Lee, Gun; Park, Bong-Joo; Park, Jong-Chul; Seo, Won-Seon; Cui Fuzhai

    2005-01-01

    Iridium film with the thickness of 30 and 60 nm were formed on both Si wafer and commercially pure (CP) Ti by electron beam evaporation. The thin iridium film showed the identical charge injection capability with the bulk Ir. However, the charge injection value of iridium film was decreased with continuous potential cycling when the deposited iridium became depleted due to the formation of oxide. The number of cycles at which the charge injection value decreased was 800 and 1600 cycles for the 30- and 60-nm-thick Ir film, respectively. FE-SEM observations on the cross section of Ir film clearly showed the thicker iridium oxide was formed with the more potential cycling. Ar ion beam etching to substrates before deposition certainly improved the adhesion strength of Ir film enough to resist to the strain induced by the larger volume occupation of iridium oxide. Swiss 3T3 fibroblasts culture on Ir and Ir oxide showed no cytotoxicity. Also, embryonic cortical neural cell culture on electrode indicated neurons adhered and survived by the formation of neurofilament

  16. Cooperative and cognitive satellite systems

    CERN Document Server

    Chatzinotas, Symeon; De Gaudenzi, Riccardo

    2015-01-01

    Cooperative and Cognitive Satellite Systems provides a solid overview of the current research in the field of cooperative and cognitive satellite systems, helping users understand how to incorporate state-of-the-art communication techniques in innovative satellite network architectures to enable the next generation of satellite systems. The book is edited and written by top researchers and practitioners in the field, providing a comprehensive explanation of current research that allows users to discover future technologies and their applications, integrate satellite and terrestrial systems

  17. Prediction of geomagnetic storm using neural networks: Comparison of the efficiency of the Satellite and ground-based input parameters

    International Nuclear Information System (INIS)

    Stepanova, Marina; Antonova, Elizavieta; Munos-Uribe, F A; Gordo, S L Gomez; Torres-Sanchez, M V

    2008-01-01

    Different kinds of neural networks have established themselves as an effective tool in the prediction of different geomagnetic indices, including the Dst being the most important constituent for determination of the impact of Space Weather on the human life. Feed-forward networks with one hidden layer are used to forecast the Dst variation, using separately the solar wind paramenters, polar cap index, and auroral electrojet index as input parameters. It was found that in all three cases the storm-time intervals were predicted much more precisely as quite time intervals. The majority of cross-correlation coefficients between predicted and observed Dst of strong geomagnetic storms are situated between 0.8 and 0.9. Changes in the neural network architecture, including the number of nodes in the input and hidden layers and the transfer functions between them lead to an improvement of a network performance up to 10%.

  18. A Neutral-Network-Fusion Architecture for Automatic Extraction of Oceanographic Features from Satellite Remote Sensing Imagery

    National Research Council Canada - National Science Library

    Askari, Farid

    1999-01-01

    This report describes an approach for automatic feature detection from fusion of remote sensing imagery using a combination of neural network architecture and the Dempster-Shafer (DS) theory of evidence...

  19. Technical comparison of several global mobile satellite communications systems

    Science.gov (United States)

    Comparetto, Gary M.

    The era of satellite-based mobile satellite communications (MSC) systems started with the first MARISAT satellite which was launched into a geostationary orbit over the Pacific Ocean in 1976 to provide communications between ships and shore stations. The combination of high cost and unacceptably large equipment has kept the space-based MSC systems from appealing to the wider market of personal mobile communications. The progress made over the last ten years, however, in digital voice processing, satellite technology, and component miniaturization has resulted in the viability of satellite-based mobile satellite communications systems to meet the growing market in personal mobile communications using handsets similar to those currently in use with land-based cellular systems. Three of the more mature LEO/MEO satellite systems are addressed in this paper including GLOBALSTAR, Iridium, and Odyssey. The system architectures of each system are presented along with a description of the satellite and user handset designs and the multiaccess techniques employed. It will be shown that, although a number of similarities exist among the system addressed, each system is unique in a variety of significant design areas. It is concluded that the technical feasibility of satellite-based mobile satellite communications systems seems to be secure. It will be challenging, however, for the vendors to actually develop and deploy these systems in a cost effective, timely, and reliable way that meets a continually evolving set of requirements based upon a rapidly changing technology base.

  20. Simple, Accurate, Low-cost RO Science with the Iridium-NEXT Satellite Constellation

    Science.gov (United States)

    Meehan, T.; Mannucci, A. J.

    2011-12-01

    Over the last decade, a disparate collection of GNSS-RO instruments have been measuring the refractivity of the Earth's ionosphere and atmosphere. These measurements have proven to be robust and precise data sets for operational weather, climate and geospace sciences. Future GNSS-RO weather and science will most benefit from a large number of profiles (10000+/day), with lower latency and greater accuracy in the lowest 5 km altitude. For weather, latencies below 90 minutes are required, 30 minutes desired. Space weather latency requirements are more stringent, with 15 minutes being a long sought goal. Climate studies benefit from averaging measurements uniformly distributed over the Earth, acquired over decades, with local time sampling errors minimized by dense coverage or well designed orbits. There's much more of course, because space GNSS science is still nascent but with gathering momentum among the international community. Although individual GNSS-RO instruments are relatively cheap as space hardware goes, growing the measurement density can be costly when a dozen or more are required for a single program. In this presentation, we propose a novel technique for greatly reducing the cost of a constellation of GNSS-RO instruments and discuss the science trade-offs of this approach versus the more traditional GNSS-RO designs.

  1. H31G-1596: DeepSAT's CloudCNN: A Deep Neural Network for Rapid Cloud Detection from Geostationary Satellites

    Science.gov (United States)

    Kalia, Subodh; Ganguly, Sangram; Li, Shuang; Nemani, Ramakrishna R.

    2017-01-01

    Cloud and cloud shadow detection has important applications in weather and climate studies. It is even more crucial when we introduce geostationary satellites into the field of terrestrial remote sensing. With the challenges associated with data acquired in very high frequency (10-15 mins per scan), the ability to derive an accurate cloud shadow mask from geostationary satellite data is critical. The key to the success for most of the existing algorithms depends on spatially and temporally varying thresholds,which better capture local atmospheric and surface effects.However, the selection of proper threshold is difficult and may lead to erroneous results. In this work, we propose a deep neural network based approach called CloudCNN to classify cloudshadow from Himawari-8 AHI and GOES-16 ABI multispectral data. DeepSAT's CloudCNN consists of an encoderdecoder based architecture for binary-class pixel wise segmentation. We train CloudCNN on multi-GPU Nvidia Devbox cluster, and deploy the prediction pipeline on NASA Earth Exchange (NEX) Pleiades supercomputer. We achieved an overall accuracy of 93.29% on test samples. Since, the predictions take only a few seconds to segment a full multispectral GOES-16 or Himawari-8 Full Disk image, the developed framework can be used for real-time cloud detection, cyclone detection, or extreme weather event predictions.

  2. Recognition and characterization of networks of water bodies in the Arctic ice-wedge polygonal tundra using high-resolution satellite imagery

    Science.gov (United States)

    Skurikhin, A. N.; Gangodagamage, C.; Rowland, J. C.; Wilson, C. J.

    2013-12-01

    Arctic lowland landscapes underlain by permafrost are often characterized by polygon-like patterns such as ice-wedge polygons outlined by networks of ice wedges and complemented with polygon rims, troughs, shallow ponds and thermokarst lakes. Polygonal patterns and corresponding features are relatively easy to recognize in high spatial resolution satellite imagery by a human, but their automated recognition is challenging due to the variability in their spectral appearance, the irregularity of individual trough spacing and orientation within the patterns, and a lack of unique spectral response attributable to troughs with widths commonly between 1 m and 2 m. Accurate identification of fine scale elements of ice-wedge polygonal tundra is important as their imprecise recognition may bias estimates of water, heat and carbon fluxes in large-scale climate models. Our focus is on the problem of identification of Arctic polygonal tundra fine-scale landscape elements (as small as 1 m - 2 m width). The challenge of the considered problem is that while large water bodies (e.g. lakes and rivers) can be recognized based on spectral response, reliable recognition of troughs is more difficult. Troughs do not have unique spectral signature, their appearance is noisy (edges are not strong), their width is small, and they often form connected networks with ponds and lakes, and thus they have overlapping spectral response with other water bodies and surrounding non-water bodies. We present a semi-automated approach to identify and classify Arctic polygonal tundra landscape components across the range of spatial scales, such as troughs, ponds, river- and lake-like objects, using high spatial resolution satellite imagery. The novelty of the approach lies in: (1) the combined use of segmentation and shape-based classification to identify a broad range of water bodies, including troughs, and (2) the use of high-resolution WorldView-2 satellite imagery (with resolution of 0.6 m) for this

  3. Animal Telemetry Network Data Assembly Center: Phase 2

    Science.gov (United States)

    2015-09-30

    sampling of the Pacific bluefin tuna data and no white shark data from TOPP, as well as a small sample of the Atlantic bluefin tuna data from TAG and...Satellite Relay Data Logger, Fastloc GPS), Wildlife Computers (SPOT and SPLASH) 2) Acoustic data ( white sharks ) via automated Iridium satellite...Computers MK10, MiniPAT) that report throughout the year (e.g. blue marlin from the IGFA Great Marlin Race), and then take approximately 20 days to

  4. Predictive fault-tolerant control of an all-thruster satellite in 6-DOF motion via neural network model updating

    Science.gov (United States)

    Tavakoli, M. M.; Assadian, N.

    2018-03-01

    The problem of controlling an all-thruster spacecraft in the coupled translational-rotational motion in presence of actuators fault and/or failure is investigated in this paper. The nonlinear model predictive control approach is used because of its ability to predict the future behavior of the system. The fault/failure of the thrusters changes the mapping between the commanded forces to the thrusters and actual force/torque generated by the thruster system. Thus, the basic six degree-of-freedom kinetic equations are separated from this mapping and a set of neural networks are trained off-line to learn the kinetic equations. Then, two neural networks are attached to these trained networks in order to learn the thruster commands to force/torque mappings on-line. Different off-nominal conditions are modeled so that neural networks can detect any failure and fault, including scale factor and misalignment of thrusters. A simple model of the spacecraft relative motion is used in MPC to decrease the computational burden. However, a precise model by the means of orbit propagation including different types of perturbation is utilized to evaluate the usefulness of the proposed approach in actual conditions. The numerical simulation shows that this method can successfully control the all-thruster spacecraft with ON-OFF thrusters in different combinations of thruster fault and/or failure.

  5. Study and development of an Iridium-192 seed for use in ophthalmic cancer

    International Nuclear Information System (INIS)

    Mattos, Fabio Rodrigues de

    2013-01-01

    Even ocular tumors are not among the cases with a higher incidence, they affect the population, especially children. The Institute of Energy and Nuclear Research (IPEN-CNEN/SP) in partnership with Escola Paulista de Medicina (UNIFESP), created a project to develop and implement a alternative treatment for ophthalmic cancer that use brachytherapy iridium-192 seeds. The project arose by reason of the Escola Paulista treat many cancer cases within the Unified Health System (SUS) and the research experience of sealed radioactive sources group at IPEN. The methodology was developed from the available infrastructure and the experience of researchers. The prototype seed presents with a core (192-iridium alloy of iridium-platinum) of 3.0 mm long sealed by a capsule of titanium of 0.8 mm outside diameter, 0.05 mm wall thickness and 4,5mm long. This work aims to study and develop a seed of iridium-192 from a platinum-iridium alloy. No study on the fabrication of these seeds was found in available literature. It was created a methodology that involved: characterization of the material used in the core, creation of device for neutron activation irradiation and and seed sealing tests. As a result, proved the feasibility of the method. As a suggestion for future work, studies regarding metrology and dosimetry of these sources and improvement of the methodology should be carried out, for future implementation in national scope. (author)

  6. Development of iridium coated x-ray mirrors for astronomical applications

    Science.gov (United States)

    Döhring, Thorsten; Probst, Anne-Catherine; Emmerich, Florian; Stollenwerk, Manfred; Stehlíková, Veronika; Friedrich, Peter; Damm, Christine

    2017-08-01

    Future space-based X-ray observatories need to be very lightweight for launcher mass constraints. Therefore they will use a reduced mirror thickness, which results in the additional requirement of low coating stress to avoid deformation of the initial precisely shaped mirror substrates. Due to their excellent reflection properties iridium coatings are sometimes applied for grazing incidence mirrors in astronomical X-ray telescopes. At Aschaffenburg University of Applied Sciences the coating of thin iridium films by an RF-magnetron sputtering technique is under development. The work is embedded in collaborations with the Max-Planck-Institute for Extraterrestrial Physics in Germany, the Czech Technical University in Prague, the Osservatorio Astronomico di Brera in Italy, the German Leibniz Institute for Solid State and Materials Research in Dresden, and the French Institute Fresnel. Sputtering with different parameters leads to iridium films with different properties. The current work is focused on the microstructure of the iridium coatings to study the influence of the substrate and of the argon gas pressure on the thin film growing process. Correlations between coating density, surface micro-roughness, the crystalline structure of the iridium layers, and the expected reflectivity of the X-ray mirror as well as coating stress effects are presented and discussed. The final goal of the project is to integrate the produced prototype mirrors into an X-ray telescope module. On a longer timescale measurements of the mirror modules optical performance are planned at the X-ray test facility PANTER.

  7. Integrated Satellite-HAP Systems

    DEFF Research Database (Denmark)

    Cianca, Ernestina; De Sanctis, Mauro; De Luise, Aldo

    2005-01-01

    Thus far, high-altitude platform (HAP)-based systems have been mainly conceived as an alternative to satellites for complementing the terrestrial network. This article aims to show that HAP should no longer be seen as a competitor technology by investors of satellites, but as a key element for an...

  8. Iridium containing honeycomb Delafossites by topotactic cation exchange.

    Science.gov (United States)

    Roudebush, John H; Ross, K A; Cava, R J

    2016-06-07

    We report the structure and magnetic properties of two new iridium-based honeycomb Delafossite compounds, Cu3NaIr2O6 and Cu3LiIr2O6, formed by a topotactic cation exchange reaction. The starting materials Na2IrO3 and Li2IrO3, which are based on layers of IrO6 octahedra in a honeycomb lattice separated by layers of alkali ions, are transformed to the title compounds by a topotactic exchange reaction through heating with CuCl below 450 °C; higher temperature reactions cause decomposition. The new compounds display dramatically different magnetic behavior from their parent compounds - Cu3NaIr2O6 has a ferromagnetic like magnetic transition at 10 K, while Cu3LiIr2O6 retains the antiferromagnetic transition temperature of its parent compound but displays significantly stronger dominance of antiferromagnetic coupling between spins. These results reveal that a surprising difference in the magnetic interactions between the magnetic Ir ions has been induced by a change in the non-magnetic interlayer species. A combination of neutron and X-ray powder diffraction is used for the structure refinement of Cu3NaIr2O6 and both compounds are compared to their parent materials.

  9. [New calculation algorithms in brachytherapy for iridium 192 treatments].

    Science.gov (United States)

    Robert, C; Dumas, I; Martinetti, F; Chargari, C; Haie-Meder, C; Lefkopoulos, D

    2018-05-18

    Since 1995, the brachytherapy dosimetry protocols follow the methodology recommended by the Task Group 43. This methodology, which has the advantage of being fast, is based on several approximations that are not always valid in clinical conditions. Model-based dose calculation algorithms have recently emerged in treatment planning stations and are considered as a major evolution by allowing for consideration of the patient's finite dimensions, tissue heterogeneities and the presence of high atomic number materials in applicators. In 2012, a report from the American Association of Physicists in Medicine Radiation Therapy Task Group 186 reviews these models and makes recommendations for their clinical implementation. This review focuses on the use of model-based dose calculation algorithms in the context of iridium 192 treatments. After a description of these algorithms and their clinical implementation, a summary of the main questions raised by these new methods is performed. Considerations regarding the choice of the medium used for the dose specification and the recommended methodology for assigning materials characteristics are especially described. In the last part, recent concrete examples from the literature illustrate the capabilities of these new algorithms on clinical cases. Copyright © 2018 Société française de radiothérapie oncologique (SFRO). Published by Elsevier SAS. All rights reserved.

  10. Neural network-based segmentation of satellite imagery for estimating house cluster of an urban settlement from Google Earth images

    International Nuclear Information System (INIS)

    Wardaya, P D; Ridha, S

    2014-01-01

    In this paper a backpropagation neural network is utilized to perform house cluster segmentation from Google Earth data. The algorithm is subjected to identify houses in the image based on the RGB pattern within each pixel. Training data is given through cropping selection for a target that is a house cluster and a non object. The algorithm assigns 1 to a pixel belong to a class of object and 0 to a class of non object. The resulting outcome, a binary image, is then utilized to perform quantification to estimate the number of house clusters. The number of the hidden layer is varying in order to find its effect to the neural network performance and total computational time

  11. Determination of surface coverage of catalysts : temperature programmed experiments on platinum and iridium sponge catalysts after low temperature ammonia oxidation

    NARCIS (Netherlands)

    van den Broek, A.C.M.; Grondelle, van J.; Santen, van R.A.

    1999-01-01

    The activity of iridium and platinum sponge catalysts was studied in the low temperature gas phase oxidation of ammonia with oxygen. Under the reaction conditions used, iridium was found to be more active and more selective to nitrogen than platinum. Furthermore it was established from activity

  12. Saturn satellites

    International Nuclear Information System (INIS)

    Ruskol, E.L.

    1981-01-01

    The characteristics of the Saturn satellites are discussed. The satellites close to Saturn - Janus, Mimas, Enceladus, Tethys, Dione and Rhea - rotate along the circular orbits. High reflectivity is attributed to them, and the density of the satellites is 1 g/cm 3 . Titan is one of the biggest Saturn satellites. Titan has atmosphere many times more powerful than that of Mars. The Titan atmosphere is a peculiar medium with a unique methane and hydrogen distribution in the whole Solar system. The external satellites - Hyperion, Japetus and Phoebe - are poorly investigated. Neither satellite substance density, nor their composition are known. The experimental data on the Saturn rings obtained on the ''Pioneer-11'' and ''Voyager-1'' satellites are presented [ru

  13. A study on the relationship between iridium concentration in hen eggshell and iridium-enriched feed by NAA

    International Nuclear Information System (INIS)

    Yang Gaochuang; Mao Xueying; Wang Jinchun; Lu Yali; Ouyang Hong; Zhang Zhaohui; Chai Zhifang

    2001-01-01

    Four hens were fed by adding ammonium hexachloroiridate into their forage. After two weeks, Ir concentration in three fractions (eggshell, albumen, egg yolk) of their eggs were measured by instrumental neutron activation analysis (INAA). Ir was present in all the three parts of the eggs. Further, the highest concentration of Ir was found in the egg yolk fraction, about 10 times higher than that in the eggshell and albumen. Moreover, the longer the Ir-containing feed was used, the higher the Ir concentration in the egg fractions was. After 4-6 day feeding, the Ir concentration became stable. The experimental results indicated that the Ir concentration was about 2-7 x 10 -10 g/g in the eggshell fraction compared to 5.6 x 10 -7 g/g in feed. Therefore, the ratio from the feed over the eggshell via gastrointestinal pathway was estimated to be about 0.08%. The new result is useful to evaluate the iridium-enriched eggshell fossils of dinosauria and to interpret the origin of the mass extinction of dinosauria at the end of Cretaceous. (author)

  14. A study on the relationship between iridium concentration in hen eggs and the iridium-enriched feed stuff by INAA

    International Nuclear Information System (INIS)

    Yang Gaochuang; Mao Xueying; Lu Yali; Ouyang Hong; Wang Jinchun; Zhang Zhaohui; Chai Zhifang

    2000-01-01

    Several hens were fed by adding ammonium chloroiridate into their forage. After two weeks, the Ir concentration in three fractions (eggshell, albumen, egg yolk) of their eggs were measured by INAA. Ir was found in all of the three parts. However, the highest concentration of Ir was found in the egg yolk fraction, which was about 10 times higher than that in the eggshell and albumen. Moreover, the longer the Ir-containing feed stuff was used, the higher the Ir concentration in the egg fractions was. After 7-8 days feeding, it kept stable. On the other hand, as soon as adding the Ir-containing additives were stopped, the Ir concentration in the egg fractions fell down quickly. The experimental results indicated that the ratio from the feedstuff to the eggshell via gastrointestinal pathway to be about 0.07 percent. The new result might be beneficial to explain the iridium-enriched dinosaur eggshell fossils and to interpret the origin of the mass extinct event of dinosaur occurred at the end of Cretaceous

  15. Development of an Iridium-192 seed for use in ophthalmic brachytherapy

    International Nuclear Information System (INIS)

    Mattos, Fabio R.; Rostelato, Maria Elisa C.M.; Zeituni, Carlos; Moura, Joao A.; Costa, Osvaldo L.; Feher, Anselmo; Moura, Eduardo S.; Souza, Carla D.; Peleias Junior, Fernando S.

    2011-01-01

    The Institute for Energy and Nuclear Research (IPEN), in partnership with the School or Medicine (UNIFESP), created a project that aims to develop and implement an ophthalmic therapeutic treatment for cancer with Iridium-192 seeds. The School of Medicine treats many cancer cases in the SUS (Brazilian Public Health System), and brachytherapy group of IPEN has extensive experience in prototype sources. The seed to be manufactured will perform as follows: a core of Iridium-192 is packaged inside small cylindrical seeds consist of a titanium capsule of 0.8 mm outer diameter, 0.05 mm wall thickness and 4 5 mm in length. The core is an alloy of platinum-iridium (20/80) of 3.0 mm in length and 0.3 mm in diameter. Material analysis, neutron activation and activity measurements were carried out. (author)

  16. Experimental and Theoretical Mechanistic Investigation of the Iridium-Catalyzed Dehydrogenative Decarbonylation of Primary Alcohols

    DEFF Research Database (Denmark)

    Olsen, Esben Paul Krogh; Singh, Thishana; Harris, Pernille

    2015-01-01

    The mechanism for the iridium-BINAP catalyzed dehydrogenative decarbonylation of primary alcohols with the liberation of molecular hydrogen and carbon monoxide was studied experimentally and computationally. The reaction takes place by tandem catalysis through two catalytic cycles involving...... cycles. One carbon monoxide ligand was shown to remain coordinated to iridium throughout the reaction, and release of carbon monoxide was suggested to occur from a dicarbonyl complex. IrH2Cl(CO)(rac-BINAP) was also synthesized and detected in the dehydrogenation of benzyl alcohol. In the same experiment......, IrHCl2(CO)(rac-BINAP) was detected from the release of HCl in the dehydrogenation and subsequent reaction with IrCl(CO)(rac-BINAP). This indicated a substitution of chloride with the alcohol to form a square planar iridium alkoxo complex that could undergo a beta-hydride elimination. A KIE of 1...

  17. Wave activity (planetary, tidal throughout the middle atmosphere (20-100km over the CUJO network: Satellite (TOMS and Medium Frequency (MF radar observations

    Directory of Open Access Journals (Sweden)

    A. H. Manson

    2005-02-01

    Full Text Available Planetary and tidal wave activity in the tropopause-lower stratosphere and mesosphere-lower thermosphere (MLT is studied using combinations of ground-based (GB and satellite instruments (2000-2002. The relatively new MFR (medium frequency radar at Platteville (40° N, 105° W has provided the opportunity to create an operational network of middle-latitude MFRs, stretching from 81° W-142° E, which provides winds and tides 70-100km. CUJO (Canada U.S. Japan Opportunity comprises systems at London (43° N, 81° W, Platteville (40° N, 105° W, Saskatoon (52° N, 107° W, Wakkanai (45° N, 142° E and Yamagawa (31° N, 131° E. It offers a significant 7000-km longitudinal sector in the North American-Pacific region, and a useful range of latitudes (12-14° at two longitudes. Satellite data mainly involve the daily values of the total ozone column measured by the Earth Probe (EP TOMS (Total Ozone Mapping Spectrometer and provide a measure of tropopause-lower stratospheric planetary wave activity, as well as ozone variability. Climatologies of ozone and winds/tides involving frequency versus time (wavelet contour plots for periods from 2-d to 30-d and the interval from mid 2000 to 2002, show that the changes with altitude, longitude and latitude are very significant and distinctive. Geometric-mean wavelets for the region of the 40° N MFRs demonstrate occasions during the autumn, winter and spring months when there are similarities in the spectral features of the lower atmosphere and at mesopause (85km heights. Both direct planetary wave (PW propagation into the MLT, nonlinear PW-tide interactions, and disturbances in MLT tides associated with fluctuations in the ozone forcing are considered to be possible coupling processes. The complex horizontal wave numbers of the longer period oscillations are provided in frequency contour plots for the TOMS satellite data to demonstrate the differences between lower atmospheric and MLT wave motions and their

  18. Wave activity (planetary, tidal) throughout the middle atmosphere (20-100km) over the CUJO network: Satellite (TOMS) and Medium Frequency (MF) radar observations

    Science.gov (United States)

    Manson, A. H.; Meek, C. E.; Chshyolkova, T.; Avery, S. K.; Thorsen, D.; MacDougall, J. W.; Hocking, W.; Murayama, Y.; Igarashi, K.

    2005-02-01

    Planetary and tidal wave activity in the tropopause-lower stratosphere and mesosphere-lower thermosphere (MLT) is studied using combinations of ground-based (GB) and satellite instruments (2000-2002). The relatively new MFR (medium frequency radar) at Platteville (40° N, 105° W) has provided the opportunity to create an operational network of middle-latitude MFRs, stretching from 81° W-142° E, which provides winds and tides 70-100km. CUJO (Canada U.S. Japan Opportunity) comprises systems at London (43° N, 81° W), Platteville (40° N, 105° W), Saskatoon (52° N, 107° W), Wakkanai (45° N, 142° E) and Yamagawa (31° N, 131° E). It offers a significant 7000-km longitudinal sector in the North American-Pacific region, and a useful range of latitudes (12-14°) at two longitudes. Satellite data mainly involve the daily values of the total ozone column measured by the Earth Probe (EP) TOMS (Total Ozone Mapping Spectrometer) and provide a measure of tropopause-lower stratospheric planetary wave activity, as well as ozone variability. Climatologies of ozone and winds/tides involving frequency versus time (wavelet) contour plots for periods from 2-d to 30-d and the interval from mid 2000 to 2002, show that the changes with altitude, longitude and latitude are very significant and distinctive. Geometric-mean wavelets for the region of the 40° N MFRs demonstrate occasions during the autumn, winter and spring months when there are similarities in the spectral features of the lower atmosphere and at mesopause (85km) heights. Both direct planetary wave (PW) propagation into the MLT, nonlinear PW-tide interactions, and disturbances in MLT tides associated with fluctuations in the ozone forcing are considered to be possible coupling processes. The complex horizontal wave numbers of the longer period oscillations are provided in frequency contour plots for the TOMS satellite data to demonstrate the differences between lower atmospheric and MLT wave motions and their

  19. Wave activity (planetary, tidal throughout the middle atmosphere (20-100km over the CUJO network: Satellite (TOMS and Medium Frequency (MF radar observations

    Directory of Open Access Journals (Sweden)

    A. H. Manson

    2005-02-01

    Full Text Available Planetary and tidal wave activity in the tropopause-lower stratosphere and mesosphere-lower thermosphere (MLT is studied using combinations of ground-based (GB and satellite instruments (2000-2002. The relatively new MFR (medium frequency radar at Platteville (40° N, 105° W has provided the opportunity to create an operational network of middle-latitude MFRs, stretching from 81° W-142° E, which provides winds and tides 70-100km. CUJO (Canada U.S. Japan Opportunity comprises systems at London (43° N, 81° W, Platteville (40° N, 105° W, Saskatoon (52° N, 107° W, Wakkanai (45° N, 142° E and Yamagawa (31° N, 131° E. It offers a significant 7000-km longitudinal sector in the North American-Pacific region, and a useful range of latitudes (12-14° at two longitudes. Satellite data mainly involve the daily values of the total ozone column measured by the Earth Probe (EP TOMS (Total Ozone Mapping Spectrometer and provide a measure of tropopause-lower stratospheric planetary wave activity, as well as ozone variability.

    Climatologies of ozone and winds/tides involving frequency versus time (wavelet contour plots for periods from 2-d to 30-d and the interval from mid 2000 to 2002, show that the changes with altitude, longitude and latitude are very significant and distinctive. Geometric-mean wavelets for the region of the 40° N MFRs demonstrate occasions during the autumn, winter and spring months when there are similarities in the spectral features of the lower atmosphere and at mesopause (85km heights. Both direct planetary wave (PW propagation into the MLT, nonlinear PW-tide interactions, and disturbances in MLT tides associated with fluctuations in the ozone forcing are considered to be possible coupling processes. The complex horizontal wave numbers of the longer period oscillations are provided in frequency contour plots for the TOMS satellite data to demonstrate the differences between lower atmospheric

  20. Interstitial curietherapy with iridium 192 applied to small cancers of the rectum

    International Nuclear Information System (INIS)

    Papillon, J.; Montbarbon, J.F.; Gerard, J.P.

    1975-01-01

    Intracavity irradiation aimed at curing cancers of the rectum mainly calls on contact radiotherapy but also on interstitial curietherapy. Iridium curietherapy has replaced radium-therapy owing to the better homogeneousness of its action and precise method of assay. It uses a 2 pronged fork containing 2 iridium wires which can be very simply placed in position. It is applied on the one hand to the base of the ulcerated tumour, after abrasion by contactotherapy and on the other hand as a method of prophylactic irradiation after exeresis of a malignant or degenerated polyp where the scar is badly adapted to contactotherapy [fr

  1. Iridium/Bipyridine-Catalyzed ortho-Selective C-H Borylation of Phenol and Aniline Derivatives.

    Science.gov (United States)

    Li, Hong-Liang; Kanai, Motomu; Kuninobu, Yoichiro

    2017-11-03

    An iridium-catalyzed ortho-selective C-H borylation of phenol and aniline derivatives has been successfully developed. Iridium/bipyridine-catalyzed C-H borylation generally occurred at the meta- and para-positions of aromatic substrates. Introduction of an electron-withdrawing substituent on the bipyridine-type ligand and a methylthiomethyl group on the hydroxy and amino groups of the phenol and aniline substrates, however, dramatically altered the regioselectivity, affording exclusively ortho-borylated products. The reaction proceeded in good to excellent yields with good functional group tolerance. C-H borylation was applied to the synthesis of a calcium receptor modulator.

  2. Synthesis of Fluoroalkoxy Substituted Arylboronic Esters by Iridium-Catalyzed Aromatic C–H Borylation

    KAUST Repository

    Batool, Farhat

    2015-08-17

    The preparation of fluoroalkoxy arylboronic esters by iridium-catalyzed aromatic C–H borylation is described. The fluoroalkoxy groups employed include trifluoromethoxy, difluoromethoxy, 1,1,2,2-tetrafluoroethoxy, and 2,2-difluoro-1,3-benzodioxole. The borylation reactions were carried out neat without the use of a glovebox or Schlenk line. The regioselectivities available through the iridium-catalyzed C–H borylation are complementary to those obtained by the electrophilic aromatic substitution reactions of fluoroalkoxy arenes. Fluoroalkoxy arylboronic esters can serve as versatile building blocks.

  3. Assessment of radiation exposure of personnel during clinical application of radioactive iridium

    Energy Technology Data Exchange (ETDEWEB)

    Dworakowski, M; Krystman-Mazgajska, E; Wysopolski, J [Instytut Onkologii, Warsaw (Poland); Centralne Lab. Ochrony Radiologicznej, Warsaw (Poland))

    1975-01-01

    The authors describe the results of measurements of doses and the evaluation of radiation exposure of the personnel of the Department of General Oncology working with application of radioactive iridium for interstitial and superficial treatment of neoplasma. The doses were measured by the photographic method simultaneously at six sites of the body: on the forehead, left side of the chest, 4th fingers of both hands, and on the left and right sides of the trunk at the level of gonads. The authors believe that introduction of iridium in place of radium will improve the conditions of work from the standpoint of protection against radioactivity.

  4. Synthesis of Fluoroalkoxy Substituted Arylboronic Esters by Iridium-Catalyzed Aromatic C–H Borylation

    KAUST Repository

    Batool, Farhat; Parveen, Shehla; Emwas, Abdul-Hamid M.; Sioud, Salim; Gao, Xin; Munawar, Munawar A.; Chotana, Ghayoor A.

    2015-01-01

    The preparation of fluoroalkoxy arylboronic esters by iridium-catalyzed aromatic C–H borylation is described. The fluoroalkoxy groups employed include trifluoromethoxy, difluoromethoxy, 1,1,2,2-tetrafluoroethoxy, and 2,2-difluoro-1,3-benzodioxole. The borylation reactions were carried out neat without the use of a glovebox or Schlenk line. The regioselectivities available through the iridium-catalyzed C–H borylation are complementary to those obtained by the electrophilic aromatic substitution reactions of fluoroalkoxy arenes. Fluoroalkoxy arylboronic esters can serve as versatile building blocks.

  5. High Strain Rate Testing of Welded DOP-26 Iridium

    Energy Technology Data Exchange (ETDEWEB)

    Schneibel, J. H. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Miller, R. G. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Carmichael, C. A. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Fox, E. E. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Ulrich, G. B. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); George, E. P. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

    2017-08-01

    The iridium alloy DOP-26 is used to produce Clad Vent Set cups that protect the radioactive fuel in radioisotope thermoelectric generators (RTGs) which provide electric power for spacecraft and rovers. In a previous study, the tensile properties of DOP-26 were measured over a wide range of strain rates and temperatures and reported in ORNL/TM-2007/81. While that study established the properties of the base material, the fabrication of the heat sources requires welding, and the mechanical properties of welded DOP-26 have not been extensively characterized in the past. Therefore, this study was undertaken to determine the mechanical properties of DOP-26 specimens containing a transverse weld in the center of their gage sections. Tensile tests were performed at room temperature, 750, 900, and 1090°C and engineering strain rates of 1×10-3 and 10 s-1. Room temperature testing was performed in air, while testing at elevated temperatures was performed in a vacuum better than 1×10-4 Torr. The welded specimens had a significantly higher yield stress, by up to a factor of ~2, than the non-welded base material. The yield stress did not depend on the strain rate except at 1090°C, where it was slightly higher for the faster strain rate. The ultimate tensile stress, on the other hand, was significantly higher for the faster strain rate at temperatures of 750°C and above. At 750°C and above, the specimens deformed at 1×10-3 s-1 showed pronounced necking resulting sometimes in perfect chisel-edge fracture. The specimens deformed at 10 s-1 exhibited this fracture behavior only at the highest test temperature, 1090°C. Fracture occurred usually in the fusion zone of the weld and was, in most cases, primarily intergranular.

  6. Postoperative irradiation of endometrial cancer by iridium afterloading technique

    International Nuclear Information System (INIS)

    Kucera, H.; Weghaupt, K.

    1988-01-01

    From 1981 to 1986 708 patients were operated and postoperativly treated by total hysterectomy, bilateral salpingo-oophorectomy and postoperative vaginal irradiation with high-dose-afterloading (iridium 192). A percutaneous irradiation (cobalt 60) was done in stage I cases only when myometrial infiltration was deep. Highly differentiated tumors with infiltration of the first and second thirth of the myometrium were treated by vaginal irradiation alone. Poorly differentiated tumors with infiltration of the second and third thirth of the myometrium were treated by vaginal and percutaneous irradiation. A group of 125 cases with good prognosis and with postoperative vaginal irradiation alone had the same five-year-survival of 83% as a group of 152 cases with bad prognosis treated by vaginal and percutaneous irrradiation. This result shows clearly the importance of additional irradiation of the pelvis in cases with bad prognosis factors. The incidence of radiation side effect in all 708 cases was: cystitis 4.6%, proctitis 5.2%, vaginal or rectal ulcera 1.4% and fistulas 0.2%. Cases with vaginal irradiation alone and with the optimal intravaginal fraction dose of 700 cGy (twice) had the lowest level of side effects: cystitis 3.8% proctitis 2.1%, vaginal necrosis 0.7%, no further severe complications. None of the patients with postoperative vaginal irradiation alone had a vaginal recurrence. The incidence of recurrences in 708 patients was 1.6%. All recurrence cases in stage I (0.7%) had bad prognosis factors and were treated with vaginal and percutaneous irradiation. (orig./MG) [de

  7. Blue phosphorescent mono-cyclometalated iridium(III) complexes

    Energy Technology Data Exchange (ETDEWEB)

    Ham, Ho Wan; Yang, Yoon A; Kim, Young Sik [Hongik University, Seoul (Korea, Republic of)

    2010-12-15

    New deep blue phosphorescent iridium(III) complexes comprised of one cyclometalate, two phosphines trans to each other and two cis-ancillary ligands, such as Ir(F{sub 2}Meppy)(PPh{sub 2}Me){sub 2}(H)(Cl), Ir(F{sub 2}Meppy)(PPh{sub 2}Me){sub 2}(H)(NCMe){sup +}, and Ir(F{sub 2}Meppy)(PPh{sub 2}Me){sub 2}(H)(CN), [F{sub 2}Meppy = 2-(2', 4'- difluorophenyl)-4-methyl-pyridine] were synthesized and studied to tune the phosphorescence wavelength to the deep blue region and to enhance the luminescence efficiencies. We investigated the strong field effects of ancillary ligands to gain insight into the factors responsible for the emission color change and the different luminescence efficiency. Reducing the molecular weight of the phosphine ligand with PPh{sub 2}Me leads to more efficient deep-blue organic light-emitting devices (OLED) by thermal processing instead of through solution processing. The electron-withdrawing difluoro group substituted on the phenyl ring, the electron-donating methyl group on the pyridyl ring, and the cyano strong field ancillary ligand increased the HOMO-LUMO gap and achieved a hypsochromic shift in the emission color. As a result, the maximum emission spectra of Ir(F{sub 2}Meppy)-(PPh{sub 2}Me){sub 2}(H)(Cl), Ir(F{sub 2}Meppy)(PPh{sub 2}Me){sub 2}(H)(NCMe){sup +}, and Ir(F{sub 2}Meppy)(PPh{sub 2}Me){sub 2-}(H)(CN) were in the ranges of 440.5, 437, 436 nm, respectively.

  8. Blue phosphorescent mono-cyclometalated iridium(III) complexes

    International Nuclear Information System (INIS)

    Ham, Ho Wan; Yang, Yoon A; Kim, Young Sik

    2010-01-01

    New deep blue phosphorescent iridium(III) complexes comprised of one cyclometalate, two phosphines trans to each other and two cis-ancillary ligands, such as Ir(F 2 Meppy)(PPh 2 Me) 2 (H)(Cl), Ir(F 2 Meppy)(PPh 2 Me) 2 (H)(NCMe) + , and Ir(F 2 Meppy)(PPh 2 Me) 2 (H)(CN), [F 2 Meppy = 2-(2', 4'- difluorophenyl)-4-methyl-pyridine] were synthesized and studied to tune the phosphorescence wavelength to the deep blue region and to enhance the luminescence efficiencies. We investigated the strong field effects of ancillary ligands to gain insight into the factors responsible for the emission color change and the different luminescence efficiency. Reducing the molecular weight of the phosphine ligand with PPh 2 Me leads to more efficient deep-blue organic light-emitting devices (OLED) by thermal processing instead of through solution processing. The electron-withdrawing difluoro group substituted on the phenyl ring, the electron-donating methyl group on the pyridyl ring, and the cyano strong field ancillary ligand increased the HOMO-LUMO gap and achieved a hypsochromic shift in the emission color. As a result, the maximum emission spectra of Ir(F 2 Meppy)-(PPh 2 Me) 2 (H)(Cl), Ir(F 2 Meppy)(PPh 2 Me) 2 (H)(NCMe) + , and Ir(F 2 Meppy)(PPh 2 Me) 2- (H)(CN) were in the ranges of 440.5, 437, 436 nm, respectively.

  9. Centriolar satellites

    DEFF Research Database (Denmark)

    Tollenaere, Maxim A X; Mailand, Niels; Bekker-Jensen, Simon

    2015-01-01

    Centriolar satellites are small, microscopically visible granules that cluster around centrosomes. These structures, which contain numerous proteins directly involved in centrosome maintenance, ciliogenesis, and neurogenesis, have traditionally been viewed as vehicles for protein trafficking...... highlight newly discovered regulatory mechanisms targeting centriolar satellites and their functional status, and we discuss how defects in centriolar satellite components are intimately linked to a wide spectrum of human diseases....

  10. Polish and European SST Assets: the Solaris-Panoptes Global Network of Robotic Telescopes and the Borowiec Satellite Laser Ranging System

    Science.gov (United States)

    Konacki, M.; Lejba, P.; Sybilski, P.; Pawłaszek, R.; Kozłowski, S.; Suchodolski, T.; Litwicki, M.; Kolb, U.; Burwitz, V.; Baader, J.; Groot, P.; Bloemen, S.; Ratajczak, M.; Helminiak, K.; Borek, R.; Chodosiewicz, P.

    2016-09-01

    We present the assets of the Nicolaus Copernicus Astronomical Center, Space Research Center (both of the Polish Academy of Sciences), two Polish companies Sybilla Technologies, Cillium Engineering and a non-profit research foundation Baltic Institute of Technology. These assets are enhanced by telescopes belonging to The Open University (UK), the Max Planck Institute for Extraterrestrial Physics and in the future the Radboud University. They consist of the Solaris-Panoptes global network of optical robotic telescopes and the satellite laser ranging station in Borowiec, Poland. These assets will contribute to the Polish and European Space Surveillance and Tracking (SST) program. The Solaris component is composed of four autonomous observatories in the Southern Hemisphere. Solaris nodes are located at the South African Astronomical Observatory (Solaris-1 and Solaris-2), Siding Spring Observatory, Australia (Solaris-3) and Complejo Astronomico El Leoncito, Argentina (Solaris-4). They are equipped with 0.5-m telescopes on ASA DDM-160 direct drive mounts, Andor iKon-L cameras and housed in 3.5-m Baader Planetarium (BP) clamshell domes. The Panoptes component is a network of telescopes operated by software from Sybilla Technologies. It currently consists of 4 telescopes at three locations, all on GM4000 mounts. One 0.36-m (Panoptes-COAST, STL- 1001E camera, 3.5 BP clamshell dome) and one 0.43-m (Panoptes-PIRATE, FLI 16803 camera, 4.5-m BP clamshell dome, with planned exchange to 0.63-m) telescope are located at the Teide Observatory (Tenerfie, Canary Islands), one 0.6-m (Panoptes-COG, SBIG STX 16803 camera, 4.5-m BP clamshell dome) telescope in Garching, Germany and one 0.5-m (Panoptes-MAM, FLI 16803 camera, 4.5-m BP slit dome) in Mammendorf, Germany. Panoptes-COAST and Panoptes-PIRATE are owned by The Open University (UK). Panoptes-COG is owned by the Max Planck Institute

  11. On the role of visible radiation in ozone profile retrieval from nadir UV/VIS satellite measurements: An experiment with neural network algorithms inverting SCIAMACHY data

    International Nuclear Information System (INIS)

    Sellitto, P.; Di Noia, A.; Del Frate, F.; Burini, A.; Casadio, S.; Solimini, D.

    2012-01-01

    Theoretical evidence has been given on the role of visible (VIS) radiation in enhancing the accuracy of ozone retrievals from satellite data, especially in the troposphere. However, at present, VIS is not being systematically used together with ultraviolet (UV) measurements, even when possible with one single instrument, e.g., the SCanning Imaging Absorption spectroMeter for Atmospheric CartograpHY (SCIAMACHY). Reasons mainly reside in the defective performance of optimal estimation and regularization algorithms caused by inaccurate modeling of VIS interaction with aerosols or clouds, as well as in inconsistent intercalibration between UV and VIS measurements. Here we intend to discuss the role of VIS radiation when it feeds a retrieval algorithm based on Neural Networks (NNs) that does not need a forward radiative transfer model and is robust with respect to calibration errors. The NN we designed was trained with a set of ozonesondes (OSs) data and tested over an independent set of OS measurements. We compared the ozone concentration profiles retrieved from UV-only with those retrieved from UV plus VIS nadir data taken by SCIAMACHY. We found that VIS radiation was able to yield more than 10% increase of accuracy and to substantially reduce biases of retrieved profiles at tropospheric levels.

  12. Interim Service ISDN Satellite (ISIS) simulator development for advanced satellite designs and experiments

    Science.gov (United States)

    Pepin, Gerard R.

    1992-01-01

    The simulation development associated with the network models of both the Interim Service Integrated Services Digital Network (ISDN) Satellite (ISIS) and the Full Service ISDN Satellite (FSIS) architectures is documented. The ISIS Network Model design represents satellite systems like the Advanced Communications Technology Satellite (ACTS) orbiting switch. The FSIS architecture, the ultimate aim of this element of the Satellite Communications Applications Research (SCAR) Program, moves all control and switching functions on-board the next generation ISDN communications satellite. The technical and operational parameters for the advanced ISDN communications satellite design will be obtained from the simulation of ISIS and FSIS engineering software models for their major subsystems. Discrete event simulation experiments will be performed with these models using various traffic scenarios, design parameters, and operational procedures. The data from these simulations will be used to determine the engineering parameters for the advanced ISDN communications satellite.

  13. Tropical Tropospheric Ozone from SHADOZ (Southern Hemisphere ADditional Ozonesondes) Network: A Project for Satellite Research, Process Studies, Education

    Science.gov (United States)

    Thompson, Anne M.; Witte, Jacquelyn C.; Oltmans, Samuel J.; Schmidlin, Francis J.; Coetzee, G. J. R.; Hoegger, Bruno; Kirchhoff, V. W. J. H.; Ogawa, Toshihiro; Kawakami, Shuji; Posny, Francoise

    2002-01-01

    The first climatological overview of total, stratospheric and tropospheric ozone in the southern hemisphere tropical and subtropics is based on ozone sounding data from 10 sites comprising the Southern Hemisphere Additional OZonesondes (SHADOZ) network. The period covered is 1998-2000. Observations were made over: Ascension Island; Nairobi, Kenya; Irene, South Africa; Reunion Island; Watukosek, Java; Fiji; Tahiti; American Samoa; San Cristobal, Galapagos; Natal, Brazil. Campaign data were collected on a trans-Atlantic oceanographic cruise and during SAFARI-2000 in Zambia. The ozone data, with simultaneous temperature profiles to approx. 7 hPa and relative humidity to approx. 200 hPa, reside at: . SHADOZ ozone time-series and profiles give a perspective on tropical total, stratospheric and tropospheric ozone. Prominent features are highly variable tropospheric ozone and a zonal wave-one pattern in total (and tropospheric) column ozone. Total, stratospheric and tropospheric column ozone amounts peak between August and November and are lowest between March and May. Tropospheric ozone variability over the Indian and Pacific Ocean displays influences of the Indian Ocean Dipole and convective mixing. Pollution transport from Africa and South America is a seasonal feature. Tropospheric ozone seasonality over the Atlantic Basin shows effects of regional subsidence and recirculation as well as biomass burning. Dynamical and chemical influences appear to be of comparable magnitude though model studies are needed to quantify this.

  14. Satellite Communications

    Indian Academy of Sciences (India)

    First page Back Continue Last page Overview Graphics. Satellite Communications. Arthur C Clarke wrote a seminal paper in 1945 in wireless world. Use three satellites in geo-synchronous orbit to enable intercontinental communications. System could be realised in '50 to 100 years'

  15. Satellite Communication and Long Distance Education

    OpenAIRE

    Hafied Cangara

    2016-01-01

    Since Indonesia introduced communication satellite for telecommunication network, the satellite has brought a number of advantages for national development in various areas, such as telephone network, mass media development, business, education, politics, security and national defence as well as regional and International cooperation. In education, satellite communication could be used for long-distance learning as implemented by 13 state universities in eastern parts of Indonesia. It is also...

  16. A pH Sensor Based on a Stainless Steel Electrode Electrodeposited with Iridium Oxide

    Science.gov (United States)

    Martinez, C. C. M.; Madrid, R. E.; Felice, C. J.

    2009-01-01

    A simple procedure to make an iridium oxide (IrO[subscript 2]) electrodeposited pH sensor, that can be used in a chemical, biomedical, or materials laboratory, is presented here. Some exercises, based on this sensor, that can be used to teach important concepts in the field of biomedical, biochemical, tissue, or materials engineering, are also…

  17. Preparation and determination of kerma for Iridium 192 sources of low dose rate for brachytherapy

    International Nuclear Information System (INIS)

    Tendilla, J.I.; Tovar M, V.; Mitsoura, E.; Aguilar H, F.; Alanis M, J.

    2000-01-01

    The practice of Brachytherapy with Iridium-192 sources of low dose rate (0.4 - 0.8 Gy/h) is a technique used in the treatment of diverse illnesses. in this work the preparation, quality control and calibration are presented in terms of kerma in air of Iridium-192 using as target these recycled Iridium-Platinum wires. The targets were obtained as decayed sources of different radio therapeutical centers in the country and they were characterized by Scanning electron microscopy in order to determine their chemical composition. Subsequently it was developed an experimental design to establish the effect of neutron flux, geometrical array and irradiation time over the activity and percentage of the sources homogeneity. The homogeneity was determined by auto radiography and by Gamma spectroscopy. Once the optimal irradiation conditions were established, it is determined the apparent activity and kerma in air using a well type ionization chamber with traceability to a primary laboratory. Iridium-192 sources were obtained with an average homogeneity 96 %, apparent activity 282.129 ± 0.531 M Bq and kerma in air 0.03200 ± 0.00006 m Gy m/h A. (Author)

  18. Measurements of iridium and the meteoric impact hypothesis at cretaceous end

    International Nuclear Information System (INIS)

    Sircilli Neto, F.

    1986-12-01

    Both instrumental and radiochemical neutron activation analysis methods were developed for trace-element determination, such as iridium and gold, for application in cosmochemistry. The magnitude of the determined concentrations is in the range of parts per billion. In the instrumental method 1.5 grams of sample were submitted to irradiation by 10 13 thermal neutrons.cm -2 .s -1 during 32 hours. The gamma spectrometry is carried out with 10 to 12 hours counting time after 40 days of decay. In the radiochemical analysis a method of radiochemical separation of noble metals based on tellurium coprecipitation is implanted for iridium and gold determinations. As an application of the instrumental neutron activation analysis, preliminary iridium concentrations are measured for the first time in sedimentary rocks collected in the Brazilian territory. These techniques for determinations of iridium will be useful to check the asteroid impact hypothesis, which is supposed to be the cause of the great Cretaceous/Tertiary mass extinction, using samples collected in the South Hemisphere. (Author) [pt

  19. Iridium-Catalyzed Asymmetric Intramolecular Allylic Amidation : Enantioselective Synthesis of Chiral Tetrahydroisoquinolines and Saturated Nitrogen Heterocycles

    NARCIS (Netherlands)

    Teichert, Johannes F.; Fañanás-Mastral, Martín; Feringa, Bernard

    2011-01-01

    For the first time iridium catalysis has been used for the synthesis of chiral tetrahydroisoquinolines with excellent yields and high enantioselectivities (see scheme; cod=1,5-cyclooctadiene, DBU=1,8-diazabicyclo[5.4.0]undec-7-ene). These products are important chiral building blocks for the

  20. Report of Iridium/{sup 238}PuO{sub 2} Compatibility Test

    Energy Technology Data Exchange (ETDEWEB)

    Taylor, D.H.

    2001-08-09

    This study indicates that the chemical purity of the fuel used presently to fabricate fueled clad vent sets will not present any special problems to the performance of the fueled clad vent sets as intended. However, cation impurities in the fuel can have a deleterious effect on the iridium cladding and vents and should be minimized as much as practical.

  1. Single orientation graphene synthesized on iridium thin films grown by molecular beam epitaxy

    Energy Technology Data Exchange (ETDEWEB)

    Dangwal Pandey, A., E-mail: arti.pandey@desy.de; Grånäs, E.; Shayduk, R.; Noei, H.; Vonk, V. [Deutsches Elektronen-Synchrotron (DESY), D-22607 Hamburg (Germany); Krausert, K.; Franz, D.; Müller, P.; Keller, T. F.; Stierle, A., E-mail: andreas.stierle@desy.de [Deutsches Elektronen-Synchrotron (DESY), D-22607 Hamburg (Germany); Fachbereich Physik, Universität Hamburg, D-22607 Hamburg (Germany)

    2016-08-21

    Heteroepitaxial iridium thin films were deposited on (0001) sapphire substrates by means of molecular beam epitaxy, and subsequently, one monolayer of graphene was synthesized by chemical vapor deposition. The influence of the growth parameters on the quality of the Ir films, as well as of graphene, was investigated systematically by means of low energy electron diffraction, x-ray reflectivity, x-ray diffraction, Auger electron spectroscopy, scanning electron microscopy, and atomic force microscopy. Our study reveals (111) oriented iridium films with high crystalline quality and extremely low surface roughness, on which the formation of large-area epitaxial graphene is achieved. The presence of defects, like dislocations, twins, and 30° rotated domains in the iridium films is also discussed. The coverage of graphene was found to be influenced by the presence of 30° rotated domains in the Ir films. Low iridium deposition rates suppress these rotated domains and an almost complete coverage of graphene was obtained. This synthesis route yields inexpensive, air-stable, and large-area graphene with a well-defined orientation, making it accessible to a wider community of researchers for numerous experiments or applications, including those which use destructive analysis techniques or irreversible processes. Moreover, this approach can be used to tune the structural quality of graphene, allowing a systematic study of the influence of defects in various processes like intercalation below graphene.

  2. Triazole-pyridine ligands: a novel approach to chromophoric iridium arrays

    NARCIS (Netherlands)

    Juríček, M.; Felici, M.; Contreras-Carballada, P.; Lauko, J.; Bou, S.R.; Kouwer, P.H.J.; Brouwer, A.M.; Rowan, A.E.

    2011-01-01

    We describe a novel modular approach to a series of luminescent iridium complexes bearing triazole-pyridine-derived ligands that were conveniently prepared by using "click" chemistry. One, two or three triazole-pyridine units were effectively built into the heteroaromatic macromolecule using

  3. Synthesis and Luminescence Properties of Iridium(III Azide- and Triazole-Bisterpyridine Complexes

    Directory of Open Access Journals (Sweden)

    Timothy W. Schmidt

    2013-07-01

    Full Text Available We describe here the synthesis of azide-functionalised iridium(III bisterpyridines using the “chemistry on the complex” strategy. The resulting azide-complexes are then used in the copper(I-catalysed azide-alkyne Huisgen 1,3-dipolar cycloaddition “click chemistry” reaction to from the corresponding triazole-functionalised iridium(III bisterpyridines. The photophysical characteristics, including lifetimes, of these compounds were also investigated. Interestingly, oxygen appears to have very little effect on the lifetime of these complexes in aqueous solutions. Unexpectedly, sodium ascorbate acid appears to quench the luminescence of triazole-functionalised iridium(III bisterpyridines, but this effect can be reversed by the addition of copper(II sulfate, which is known to oxidize ascorbate under aerobic conditions. The results demonstrate that iridium(III bisterpyridines can be functionalized for use in “click chemistry” facilitating the use of these photophysically interesting complexes in the modification of polymers or surfaces, to highlight just two possible applications.

  4. Mechanistic investigation of the iridium-catalysed alkylation of amines with alcohols

    DEFF Research Database (Denmark)

    Fristrup, Peter; Tursky, Matyas; Madsen, Robert

    2012-01-01

    where the intermediate aldehyde stays coordinated to the iridium catalyst and reacts with the amine to give a hemiaminal which is also bound to the catalyst. Dehydration to the imine and reduction to the product amine also takes place without breaking the coordination to the catalyst. The fact...

  5. Asymmetric hydrogenation of quinolines catalyzed by iridium complexes of monodentate BINOL-derived phosphoramidites

    NARCIS (Netherlands)

    Mrsic, Natasa; Lefort, Laurent; Boogers, Jeroen A. F.; Minnaard, Adriaan J.; Feringa, Ben L.; de Vries, Johannes G.; Mršić, Nataša

    The monodentate BINOL-derived phosphoramidite PipPhos is used as ligand for the iridium-catalyzed asymmetric hydrogenation of 2- and 2,6-substituted quinolines. If tri-ortho-tolylphosphine and/or chloride salts are used as additives enantioselectivities are strongly enhanced up to 89%. NMR indicates

  6. The asymmetric rotator model applied to odd-mass iridium isotopes

    International Nuclear Information System (INIS)

    Piepenbring, R.

    1980-04-01

    The method of inversion of the eigenvalue problem previously developed for nuclei with axial symmetry is extended to asymmetric equilibrium shapes. This new approach of the asymmetric rotator model is applied to the odd-mass iridium isotopes. A satisfactory and coherent description of the observed energy spectra is obtained, especially for the lighter isotopes

  7. Electrogenerated chemiluminescence of a cationic cyclometalated iridium complex–Nafion modified electrode in neutral aqueous solution

    International Nuclear Information System (INIS)

    Dong, YongPing; Ni, ZiYue; Zhang, Jing; Tong, BiHai; Chu, XiangFeng

    2013-01-01

    Electrogenerated chemiluminescence (ECL) of a cationic cyclometalated iridium complex, [(pqcm) 2 Ir(bpy)](PF 6 ) (1, pqcmH=2-phenyl-quinoline-4-carboxylic acid methyl ester, bpy=2,2′-bipyridine), was investigated at a bare glassy carbon electrode in CH 3 CN solution and 4 ECL peaks were observed. Then, the ECL of the iridium complex was studied in neutral phosphate buffer solution (PBS) by immobilizing it on a glassy carbon electrode. Two closely located ECL peaks were obtained at 1.07 and 1.40 V when the potential was scanned from −3.00 V to 2.20 V, while only one broad ECL peak located around −2.0 V was obtained when the potential was scanned from 2.20 V to −3.00 V. In the presence of oxalate, one ECL peak located around 1.22 V could be obtained except the broad ECL peak located at −2.00 V. The ECL peak at positive potential range was enhanced more than one magnitude in the presence of Nafion and was nearly 5-times higher than that of Ru(bpy) 3 2+ –Nafion modified electrode, suggesting that the synthesized iridium complex has great application potential in ECL detection. The ECL spectra of iridium complex were identical to its photoluminescence spectrum, indicating the same metal-to-ligand charge transfer (MLCT) excited states. The mechanisms of ECL were proposed based on the experimental results. The present ECL sensor gave a linear response for the oxalate concentration from 1.0×10 −6 to 1.0×10 −4 mol L −1 with a detection limit (S/N=3) of 9.1×10 −7 mol L −1 . -- Graphical abstract: Electrochemiluminescence (ECL) of immobilized novel cationic cyclometalated iridium complex in neutral phosphate buffer solution is reported for the first time. The intensity of iridium complex ECL is 5-times higher than that of Ru(bpy) 3 2+ ECL. Highlights: ► Cationic cyclometalated iridium complex was modified on a bare electrode. ► Electrochemiluminescence (ECL) of the modified electrode was studied. ► The ECL intensity is higher than that of Ru

  8. Production of iridium-192 radiation sources: Indian Experience

    International Nuclear Information System (INIS)

    Sastry, K.V.S.; Kolhe, O.T.; Nagarja, P.S.; Paramr, Y.D.

    2002-01-01

    Board of Radiation and Isotope Technology (BRIT), a unit under the Department of Atomic Energy is fabricating and supplying Ir-192 industrial radiography sources for various models of radiography cameras for use in the industry for non-destructive testing. Basically these sources are fabricated by encapsulating the required quantity of the activity in stainless steel 316 L capsules using Tungsten Inert gas welding process and crimping/attaching to the respective pigtail assemblies of the radiography cameras. The inactive iridium pellets are irradiated in the DHRUVA reactor at a flux on 1.8 X 10 14 n/cm 2 /sec. The performance classification of these source encapsulation for various conditions of normal and accidental nature are tested by subjecting the prototype sources as per the standard laid down by the regulatory authority, Atomic Energy Regulatory Board, in India. The sources are fabricated as per the national and international standards. Activity of the sources varies from 37O GBq (10 Ci ) to 2.96 TBq (80 Ci ) source strength depending on the requirement of the user. The specific activity of the Ir-192 sources supplied is around 7.4 TBq/gm (200 Ci/gm ). Quality control /Assurance for the manufacture of the source begins from the procurement of the raw material and ends with the finished source. Ir- 192 in the form of -0.3 mm diameter (0.1 mm dia wire of Ir-25 % and Pt-75% sheathed in pure platinum of 0.1 mm thick) is being supplied for use in the treatment of cancer of cervix, tongue etc. by brachytherapy. This is supplied in lengths of 50 cm / 100 cm with 37 - 185 GBq/cm ( 1-5 mCi/cm) activity. Annually 925 TBq (25 kCi) of Ir-192 for industrial radiography and about 60 meters of wire for brachytherapy are being fabricated and supplied. Because of the quality of these sources BRIT not only caters to the Indian industry but also is able to export sources to the third world countries. (Author)

  9. Testing of electroformed deposited iridium/powder metallurgy rhenium rockets

    Science.gov (United States)

    Reed, Brian D.; Dickerson, Robert

    1996-01-01

    High-temperature, oxidation-resistant chamber materials offer the thermal margin for high performance and extended lifetimes for radiation-cooled rockets. Rhenium (Re) coated with iridium (Ir) allow hours of operation at 2200 C on Earth-storable propellants. One process for manufacturing Ir/Re rocket chambers is the fabrication of Re substrates by powder metallurgy (PM) and the application of Ir coatings by using electroformed deposition (ED). ED Ir coatings, however, have been found to be porous and poorly adherent. The integrity of ED Ir coatings could be improved by densification after the electroforming process. This report summarizes the testing of two 22-N, ED Ir/PM Re rocket chambers that were subjected to post-deposition treatments in an effort to densify the Ir coating. One chamber was vacuum annealed, while the other chamber was subjected to hot isostatic pressure (HIP). The chambers were tested on gaseous oxygen/gaseous hydrogen propellants, at mixture ratios that simulated the oxidizing environments of Earth-storable propellants. ne annealed ED Ir/PM Re chamber was tested for a total of 24 firings and 4.58 hr at a mixture ratio of 4.2. After only 9 firings, the annealed ED Ir coating began to blister and spall upstream of the throat. The blistering and spalling were similar to what had been experienced with unannealed, as-deposited ED Ir coatings. The HIP ED Ir/PM Re chamber was tested for a total of 91 firings and 11.45 hr at mixture ratios of 3.2 and 4.2. The HIP ED Ir coating remained adherent to the Re substrate throughout testing; there were no visible signs of coating degradation. Metallography revealed, however, thinning of the HIP Ir coating and occasional pores in the Re layer upstream of the throat. Pinholes in the Ir coating may have provided a path for oxidation of the Re substrate at these locations. The HIP ED Ir coating proved to be more effective than vacuum annealed and as-deposited ED Ir. Further densification is still required to

  10. High temperature reactive ion etching of iridium thin films with aluminum mask in CF4/O2/Ar plasma

    Directory of Open Access Journals (Sweden)

    Chia-Pin Yeh

    2016-08-01

    Full Text Available Reactive ion etching (RIE technology for iridium with CF4/O2/Ar gas mixtures and aluminum mask at high temperatures up to 350 °C was developed. The influence of various process parameters such as gas mixing ratio and substrate temperature on the etch rate was studied in order to find optimal process conditions. The surface of the samples after etching was found to be clean under SEM inspection. It was also shown that the etch rate of iridium could be enhanced at higher process temperature and, at the same time, very high etching selectivity between aluminum etching mask and iridium could be achieved.

  11. Antiferromagnetic iridium-manganese intermediate layers for perpendicular recording media (invited)

    Science.gov (United States)

    Srinivasan, Kumar; Piramanayagam, S. N.; Sbiaa, Rachid; Kay, Yew Seng; Tan, Hang Khume; Wong, Seng Kai

    2009-04-01

    Current generation of cobalt-oxide-based perpendicular magnetic recording media uses single or dual ruthenium intermediate layers in order to grow crystallographically textured, and magnetically isolated granular media. In this work, the potential advantages of an antiferromagnetic iridium-manganese intermediate layer directly under the recording layer are highlighted. Owing to its close lattice matching with hexagonal cobalt, iridium-manganese which has the L12, or AuCu3-type crystal structure, can support the heteroepitaxial growth of the cobalt-based recording layer. In one of the media schemes described here, (111) textured iridium-manganese thin film was grown on 7.5 nm thick ruthenium layer. On the iridium-manganese as segregation layer, the Co-oxide-based magnetic recording layer showed perpendicular texture with Δθ50 below 4°, coercivity of over 4000 Oe alongside magnetic exchange decoupling, average grain sizes of 6 nm with distributions under 14%, and improved thermal stability. Measurements of the anisotropy constant did not show any significant change and even an IrMn capping layer was observed to improve the thermal stability. The possible mechanisms through which the IrMn layer could affect the thermal stability are hypothesized. The initial layers of the magnetic recording layer on IrMn segregation layers also showed exchange-decoupled and segregated grains, which is unlike that observed on Ru segregation layers. In a second media scheme, (111) textured iridium-manganese thin film was grown on a crystalline soft magnetic underlayer belonging on top of amorphous soft underlayers. In this scheme, partial pinning of the soft underlayer due to exchange-bias interaction with the IrMn layer was observed. This scheme offers the possibility to reduce the intermediate layer thickness, thus improve media writability, and with further optimization, could potentially facilitate the approach toward 1 Tbits/in.2.

  12. Nanoporous sputtered platinum-iridium-thinfilms for medical and energy applications; Nanoporoese gesputterte Platin-Iridium-Schichten fuer Anwendungen in der Medizin- und Energietechnik

    Energy Technology Data Exchange (ETDEWEB)

    Ganske, Gerald

    2012-10-05

    Sputtering makes it possible to create thinfilms of only a few atom layers and to customize them for special applications by adjusting the deposition parameters. In this work interface-layers are deposited and characterized in biological systems as stimulation electrodes for neural cells and as catalysts in hydrogen fuel cells. First of all, highly porous platinum films were created by sputtering at a pressure of 9 Pa and low power of less than 100 W. These parameters are an ideal compromise between deposition rate, porosity and disordered crystal structure of the layers. Investigations on co-sputtered platinum-iridium-films (PtIr) showed that these films form homogeneous structures and no distinction between the separate layers is possible. It was demonstrated that these films obtain the crystal structure of Pt as well as the finer cauliflower-like structure of iridium, if the atoms reach the substrate surface only with their thermal energy. Furthermore, it was shown that the film composition reflects the sputtering power of the separate targets in a linear way. The structure of the films can be predicted by means of monte-carlo-simulation, which was verified by SEM-pictures. The ratio of the sputtering power can be used to control the amount of interface elements which was confirmed by electrochemical tests. Electrode materials for the stimulation of neural cells need a large electrochemically active surface that allows for an interface between electron and ion conductivity. Test on platinum, iridium and PtIr have shown that the films sputtered at the lowest impact energy do have the largest active surface as well as the largest charge delivery capacity (CDC). Iridium films show the highest CDC (48 mC/cm{sup 2}), followed by platinum-iridium (2 mC/cm{sup 2}, 100 W power at both targets) and pure platinum (16 mC/cm{sup 2}). This can be explained by the large surface area of iridium and its electrochemical activation process. Although PtIr layers also show an

  13. Satellite Communications

    CERN Document Server

    Pelton, Joseph N

    2012-01-01

    The field of satellite communications represents the world's largest space industry. Those who are interested in space need to understand the fundamentals of satellite communications, its technology, operation, business, economic, and regulatory aspects. This book explains all this along with key insights into the field's future growth trends and current strategic challenges. Fundamentals of Satellite Communications is a concise book that gives all of the key facts and figures as well as a strategic view of where this dynamic industry is going. Author Joseph N. Pelton, PhD, former Dean of the International Space University and former Director of Strategic Policy at Intelstat, presents a r

  14. Satellite Communications for ATM

    Science.gov (United States)

    Shamma, Mohammed A.

    2003-01-01

    This presentation is an overview on Satellite Communication for the Aeronautical Telecommunication Management (ATM) research. Satellite Communications are being considered by the FAA and NASA as a possible alternative to the present and future ground systems supporting Air Traffic Communications. The international Civil Aviation Organization (ICAO) have in place Standards and Recommended Practices (SARPS) for the Aeronautical Mobile Satellite Services (AMSS) which is mainly derived from the pre-existing Inmarsat service that has been in service since the 1980s. The Working Group A of the Aeronautical Mobile Communication Panel of ICAO has also been investigating SARPS for what is called the Next Generation Satellite Service (NGSS) which conforms less to the Inmarsat based architecture and explores wider options in terms of satellite architectures. Several designs are being proposed by Firms such as Boeing, ESA, NASA that are geared toward full or secondary usage of satellite communications for ATM. Satellite communications for ATM can serve several purposes ranging from primary usage where ground services would play a minimal backup role, to an integrated solution where it will be used to cover services, or areas that are less likely to be supported by the proposed and existing ground infrastructure. Such Integrated roles can include usage of satellite communications for oceanic and remote land areas for example. It also can include relieving the capacity of the ground network by providing broadcast based services of Traffic Information Services messages (TIS-B), or Flight Information Services (FIS-B) which can take a significant portion of the ground system capacity. Additionally, satellite communication can play a backup role to support any needs for ground replacement, or additional needed capacity even after the new digital systems are in place. The additional bandwidth that can be provided via satellite communications can also open the door for many new

  15. Satellite myths

    Science.gov (United States)

    Easton, Roger L.; Hall, David

    2008-01-01

    Richard Corfield's article “Sputnik's legacy” (October 2007 pp23-27) states that the satellite on board the US Vanguard rocket, which exploded during launch on 6 December 1957 two months after Sputnik's successful take-off, was “a hastily put together contraption of wires and circuitry designed only to send a radio signal back to Earth”. In fact, the Vanguard satellite was developed over a period of several years and put together carefully using the best techniques and equipment available at the time - such as transistors from Bell Laboratories/Western Electric. The satellite contained not one but two transmitters, in which the crystal-controlled oscillators had been designed to measure both the temperature of the satellite shell and of the internal package.

  16. Satellite Geomagnetism

    DEFF Research Database (Denmark)

    Olsen, Nils; Stolle, Claudia

    2012-01-01

    Observations of Earth’s magnetic field from space began more than 50 years ago. A continuous monitoring of the field using low Earth orbit (LEO) satellites, however, started only in 1999, and three satellites have taken highprecision measurements of the geomagnetic field during the past decade....... The unprecedented time-space coverage of their data opened revolutionary new possibilities for monitoring, understanding, and exploring Earth’s magnetic field. In the near future, the three-satellite constellation Swarm will ensure continuity of such measurement and provide enhanced possibilities to improve our...... ability to characterize and understand the many sources that contribute to Earth’s magnetic field. In this review, we summarize investigations of Earth’s interior and environment that have been possible through the analysis of high-precision magnetic field observations taken by LEO satellites....

  17. An alternative approach for estimating above ground biomass using Resourcesat-2 satellite data and artificial neural network in Bundelkhand region of India.

    Science.gov (United States)

    Deb, Dibyendu; Singh, J P; Deb, Shovik; Datta, Debajit; Ghosh, Arunava; Chaurasia, R S

    2017-10-20

    Determination of above ground biomass (AGB) of any forest is a longstanding scientific endeavor, which helps to estimate net primary productivity, carbon stock and other biophysical parameters of that forest. With advancement of geospatial technology in last few decades, AGB estimation now can be done using space-borne and airborne remotely sensed data. It is a well-established, time saving and cost effective technique with high precision and is frequently applied by the scientific community. It involves development of allometric equations based on correlations of ground-based forest biomass measurements with vegetation indices derived from remotely sensed data. However, selection of the best-fit and explanatory models of biomass estimation often becomes a difficult proposition with respect to the image data resolution (spatial and spectral) as well as the sensor platform position in space. Using Resourcesat-2 satellite data and Normalized Difference Vegetation Index (NDVI), this pilot scale study compared traditional linear and nonlinear models with an artificial intelligence-based non-parametric technique, i.e. artificial neural network (ANN) for formulation of the best-fit model to determine AGB of forest of the Bundelkhand region of India. The results confirmed the superiority of ANN over other models in terms of several statistical significance and reliability assessment measures. Accordingly, this study proposed the use of ANN instead of traditional models for determination of AGB and other bio-physical parameters of any dry deciduous forest of tropical sub-humid or semi-arid area. In addition, large numbers of sampling sites with different quadrant sizes for trees, shrubs, and herbs as well as application of LiDAR data as predictor variable were recommended for very high precision modelling in ANN for a large scale study.

  18. Interim Service ISDN Satellite (ISIS) hardware experiment development for advanced ISDN satellite designs and experiments

    Science.gov (United States)

    Pepin, Gerard R.

    1992-01-01

    The Interim Service Integrated Service Digital Network (ISDN) Satellite (ISIS) Hardware Experiment Development for Advanced Satellite Designs describes the development of the ISDN Satellite Terminal Adapter (ISTA) capable of translating ISDN protocol traffic into Time Division Multiple Access (TDMA) signals for use by a communications satellite. The ISTA connects the Type 1 Network Termination (NT1) via the U-interface on the line termination side of the CPE to the RS-499 interface for satellite uplink. The same ISTA converts in the opposite direction the RS-499 to U-interface data with a simple switch setting.

  19. Interim Service ISDN Satellite (ISIS) hardware experiment design for advanced ISDN satellite design and experiments

    Science.gov (United States)

    Pepin, Gerard R.

    1992-01-01

    The Interim Service Integrated Services Digital Network (ISDN) Satellite (ISIS) Hardware Experiment Design for Advanced Satellite Designs describes the design of the ISDN Satellite Terminal Adapter (ISTA) capable of translating ISDN protocol traffic into time division multiple access (TDMA) signals for use by a communications satellite. The ISTA connects the Type 1 Network Termination (NT1) via the U-interface on the line termination side of the CPE to the V.35 interface for satellite uplink. The same ISTA converts in the opposite direction the V.35 to U-interface data with a simple switch setting.

  20. Boomerang Satellites

    Science.gov (United States)

    Hesselbrock, Andrew; Minton, David A.

    2017-10-01

    We recently reported that the orbital architecture of the Martian environment allows for material in orbit around the planet to ``cycle'' between orbiting the planet as a ring, or as coherent satellites. Here we generalize our previous analysis to examine several factors that determine whether satellites accreting at the edge of planetary rings will cycle. In order for the orbiting material to cycle, tidal evolution must decrease the semi-major axis of any accreting satellites. In some systems, the density of the ring/satellite material, the surface mass density of the ring, the tidal parameters of the system, and the rotation rate of the primary body contribute to a competition between resonant ring torques and tidal dissipation that prevent this from occurring, either permanently or temporarily. Analyzing these criteria, we examine various bodies in our solar system (such as Saturn, Uranus, and Eris) to identify systems where cycling may occur. We find that a ring-satellite cycle may give rise to the current Uranian ring-satellite system, and suggest that Miranda may have formed from an early, more massive Uranian ring.

  1. Commercial satellite broadcasting for Europe

    Science.gov (United States)

    Forrest, J. R.

    1988-12-01

    A review is presented of the current television broadcasting situation in European countries, which involves a varied mix of terrestrial VHF or UHF systems and cable networks. A small market has emerged in Europe for receivers using the low-power telecommunications satellite transmission between the program providers and cable network companies. This is expected to change with the launch of medium-power pan-European telecommunication satellites (e.g. ASTRA, EUTELSAT II), which are now directly addressing the market of home reception. DBS (direct broadcast satellite) in the UK, using the D-MAC transmission standard, will offer three additional television channels, data broadcasting services, and a planned evolution to compatible forms of wide-screen, high-definition television. Comments are given on receiver and conditional access system standardization. Some views are expressed on satellite broadcasting as part of an overall broadcasting framework for the future.

  2. Implantation of the maxillary antrum for delivery of iridium brachytherapy and microwave induced hyperthermia

    International Nuclear Information System (INIS)

    Coughlin, C.T.; Wong, T.Z.; Geurkink, N.

    1985-01-01

    A 63 year-old male was referred tp Dartmouth in March 1984 for a locally advanced recurrent squamous cell carcinoma of the left maxillary antrum. This had been initially diagnosed in January 1983 by a Caldwell-Luc procedure and had failed partial resection, external radiation therapy, and multiagent chemotherapy. Our initial evaluation revealed disease replacing the left maxillary antrum, extending into the pterygomaxillary fossa, the lateral aspect of the superior alveloar ridge, and into the soft palate. He was taken to the operating room and under general anesthesia was implanted the 7 catheters through this tumor volume. Two days later a therapeutic (>42 0 C for 1 hour) hyperthermia treatment was administered followed by iridium placement. A second heating was performed upon removal of the iridium and was accomplished without major side effects. Thermometry data and follow-up are presented

  3. Intercalating cobalt between graphene and iridium (111): Spatially dependent kinetics from the edges

    Science.gov (United States)

    Vlaic, Sergio; Rougemaille, Nicolas; Kimouche, Amina; Burgos, Benito Santos; Locatelli, Andrea; Coraux, Johann

    2017-10-01

    Using low-energy electron microscopy, we image in real time the intercalation of a cobalt monolayer between graphene and the (111) surface of iridium. Our measurements reveal that the edges of a graphene flake represent an energy barrier to intercalation. Based on a simple description of the growth kinetics, we estimate this energy barrier and find small, but substantial, local variations. These local variations suggest a possible influence of the graphene orientation with respect to its substrate and of the graphene edge termination on the energy value of the barrier height. Besides, our measurements show that intercalated cobalt is energetically more favorable than cobalt on bare iridium, indicating a surfactant role of graphene.

  4. Surface studies of iridium-alloy grain boundaries associated with weld cracking

    International Nuclear Information System (INIS)

    Mosley, W.C.

    1982-01-01

    Plutonium-238 oxide fuel pellets for the General Purpose Heat Source (GPHS) Radioisotopic Thermoelectric Generators to be used on the NASA Galileo Mission to Jupiter and the International Solar Polar Mission are produced and encapsulated in iridium alloy at the Savannah River Plant (SRP). Underbead cracks occasionally occur in the girth weld on the iridium-alloy-clad vent sets in the region where the gas tungsten arc is quenched. Grain-boundary structures and compositions were characterized by scanning electron microscopy/x-ray energy spectroscopy, electron microprobe analysis and scanning Auger microprobe analysis to determine the cause of weld quench area cracking. Results suggest that weld quench area cracking may be caused by gas porosity or liquation in the grain boundaries

  5. Phosphorescent Organic Light-Emitting Devices: Working Principle and Iridium Based Emitter Materials

    Directory of Open Access Journals (Sweden)

    Emil J. W. List

    2008-08-01

    Full Text Available Even though organic light-emitting device (OLED technology has evolved to a point where it is now an important competitor to liquid crystal displays (LCDs, further scientific efforts devoted to the design, engineering and fabrication of OLEDs are required for complete commercialization of this technology. Along these lines, the present work reviews the essentials of OLED technology putting special focus on the general working principle of single and multilayer OLEDs, fluorescent and phosphorescent emitter materials as well as transfer processes in host materials doped with phosphorescent dyes. Moreover, as a prototypical example of phosphorescent emitter materials, a brief discussion of homo- and heteroleptic iridium(III complexes is enclosed concentrating on their synthesis, photophysical properties and approaches for realizing iridium based phosphorescent polymers.

  6. Extrahepatic bile duct carcinoma treated by intraluminal irradiation with iridium-192 wire. Report of a case

    Energy Technology Data Exchange (ETDEWEB)

    Ikeda, H; Kuroda, T; Uchida, H [Osaka Univ. (Japan). Faculty of Medicine

    1980-08-01

    A 57-year-old male with obstructive jaundice was diagnosed extrahepatic bile duct carcinoma at bifurcation by percutaneous transhepatic cholangiography (PTC). He was treated 3,300 rad of external irradiation and then intraluminal irradiation using the Iridium-192 wire by two times with the aid of PTC internal drainage, each was given by the dose of 1,600 rad at 5 mm inside the tumor from the PTC-tube. He had been well for about 1 year and then died because of ascites and cachexia. Autopsy revealed only microscopic tumor cells remaining around the common duct below the cystic junction. It was confirmed that intraluminal irradiation using the Iridium-192 wire was potentially curable and easily applicable to the bile duct carcinoma.

  7. Extrahepatic bile duct carcinoma treated by intraluminal irradiation with iridium-192 wire

    International Nuclear Information System (INIS)

    Ikeda, Hiro; Kuroda, Tomosumi; Uchida, Hideo

    1980-01-01

    A 57-year-old male with obstructive jaundice was diagnosed extrahepatic bile duct carcinoma at bifurcation by percutaneous transhepatic cholangiography (PTC). He was treated 3,300 rad of external irradiation and then intraluminal irradiation using the Iridium-192 wire by two times with the aid of PTC internal drainage, each was given by the dose of 1,600 rad at 5 mm inside the tumor from the PTC-tube. He had been well for about 1 year and then died because of ascites and cachexia. Autopsy revealed only microscopic tumor cells remaining around the common duct below the cystic junction. It was confirmed that intraluminal irradiation using the Iridium-192 wire was potentially curable and easily applicable to the bile duct carcinoma. (author)

  8. Grain Growth and Precipitation Behavior of Iridium Alloy DOP-26 During Long Term Aging

    Energy Technology Data Exchange (ETDEWEB)

    Pierce, Dean T. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Muralidharan, Govindarajan [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Fox, Ethan E. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Cox, Victoria A. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Geer, Tom [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

    2017-05-01

    The influence of long term aging on grain growth and precipitate sizes and spatial distribution in iridium alloy DOP-26 was studied. Samples of DOP-26 were fabricated using the new process, recrystallized for 1 hour (h) at 1375 C, then aged at either 1300, 1400, or 1500 C for times ranging from 50 to 10,000 h. Grain size measurements (vertical and horizontal mean linear intercept and horizontal and vertical projection) and analyses of iridium-thorium precipitates (size and spacing) were made on the longitudinal, transverse, and rolling surfaces of the as-recrystallized and aged specimens from which the two-dimensional spatial distribution and mean sizes of the precipitates were obtained. The results obtained from this study are intended to provide input to grain growth models.

  9. Electro-catalytic oxidation of ethanol on platinum-iridium mixtures supported on glassy carbon

    International Nuclear Information System (INIS)

    Rodriguez, Henry; Hoyos Bibian

    2004-01-01

    Electro-catalytic oxidation of ethanol on platinum-iridium mixtures supported on glassy carbon was studied, in acid media at different temperatures and concentrations. During the maturation time of deposited iridium, the surface is covered by an irreversible oxide formation, which affects the behavior of the catalytic mixture. The Pt 7 0 Ir 3 0 and Pt 9 0 Ir 1 0 mixtures seem to be a little more active than the Pt/C electrode at potentials below 800 mV (vs. HRE). In all electrodes appears two reactions: partial ethanol oxidation to produce acetaldehyde (main path of reaction at low temperatures and high electrode coverage with ethanol adsorption residues) and the total oxidation to carbon dioxide which is considerable at potential above 800 mV and it is increased with increasing temperature

  10. Interaction of an iridium-clad RTG heat source unit with a simulated terrestrial environment

    International Nuclear Information System (INIS)

    Patterson, J.H.; Herrera, B.; Nelson, G.B.; Matlack, G.M.; Waterbury, G.R.

    1976-02-01

    An iridium-clad, 100-W 238 PuO 2 sphere, a prototype for the multihundred-watt radioisotope thermoelectric generator, was exposed for 1 y to a simulated temperate humid climate in an environmental test chamber containing sandy soil. The hot sphere sank into the soil after the first rain, then gradually acquired a hard crust around it as a result of the rainwater reacting with the hot soil during successive rains. Time and temperature profiles of the sphere were recorded during the weekly rains, and the air and rainwater that percolated through the soil were monitored for plutonium. No plutonium was released from the sphere. Aside from the crust formation, very little reaction occurred between the hot iridium shell and the soil

  11. Activities of Canadian Satellite Communications, Inc.

    Science.gov (United States)

    1992-12-01

    Canadian Satellite Communications (Cancom) has as its core business the provision of television and radio signals to cable systems in Canada, with the objective of making affordable broadcast signals available to remote and/or small communities. Cancom also provides direct-to-home services to backyard receiving dishes, as well as satellite digital data business communications services, satellite business television, and satellite network services. Its business communication services range from satellite links for big-city businesses with small branch operations located far from major centers, to a mobile messaging and tracking system for the trucking industry. Revenues in 1992 totalled $48,212,000 and net income was just over $7 million. Cancom bought 10 percent interest in Leosat Corp. of Washington, DC, who are seeking approval to operate a position locator network from low-orbit satellites. Cancom has also become a partner in SovCan Star Satellite Communications Inc., which will build an international satellite system in partnership with Russia. The first satellite in this east-west business network will be placed in a Russian orbital slot over the Atlantic by 1996, and a second satellite will follow for the Pacific region. This annual report of Cancom's activities for 1992 includes financial statements and a six year financial review.

  12. An iridium abundance anomaly at the palynological Cretaceous-Tertiary boundary in northern New Mexico

    Science.gov (United States)

    Orth, C.J.; Gilmore, J.S.; Knight, J.D.; Pillmore, C.L.; Tschudy, R.H.; Fassett, J.E.

    1981-01-01

    An iridium abundance anomaly, with concentrations up to 5000 parts per trillion over a background level of 4 to 20 parts per trillion, has been located in sedimentary rocks laid down under freshwater swamp conditions in the Raton Basin of northeastern New Mexico. The anomaly occurs at the base of a coal bed, at the same stratigraphic position at which several well-known species of Cretaceous-age pollen became extinct. Copyright ?? 1981 AAAS.

  13. Sterically directed iridium-catalyzed hydrosilylation of alkenes in the presence of alkynes.

    Science.gov (United States)

    Muchnij, Jill A; Kwaramba, Farai B; Rahaim, Ronald J

    2014-03-07

    A selective iridium catalyzed hydrosilylation of alkenes in the presence of more reactive alkynes is described. By utilizing [IrCl(COD)]2 in the presence of excess COD, hydrosilylation of alkenes and alkynes with ethynylsilanes is achieved with good chemo- and regioselectivity. This approach goes against the traditional reactivity trends of platinum and rhodium catalysts and allows access to highly substituted silicon alkyne tethers.

  14. Substrate-induced antiferromagnetism of ultrathin iron overlayers on the iridium and rhodium (001) surfaces

    Czech Academy of Sciences Publication Activity Database

    Máca, František; Kudrnovský, Josef; Drchal, Václav; Turek, Ilja; Bengone, O.; Redinger, J.

    2009-01-01

    Roč. 11, - (2009), s. 38-40 ISSN 1642-6037 R&D Projects: GA ČR GA202/07/0456; GA MŠk OC09028 Institutional research plan: CEZ:AV0Z10100520; CEZ:AV0Z20410507 Keywords : iridium * rhodium * iron * magnetismus in thin layers * density functional calculations Subject RIV: BM - Solid Matter Physics ; Magnetism

  15. Ammonia synthesis in the presence of rhodium-ruthenium-iridium carbonyl clusters

    International Nuclear Information System (INIS)

    Fedoseev, I.V.; Solov'ev, N.V.

    2007-01-01

    Researches in the field of platinum metal coordination compounds, where nitrogen enters as a ligand in coordination sphere of metal, are discussed. Results of experiments on the ammonia synthesis during the CO+N 2 mixture passing through alkali solution containing mixture of carbonyl clusters of rhodium, ruthenium and iridium at atmospheric pressure are given. Technique of the experiment and steps of assumed reactions of nitrogen fixation by Rh, Ir and Ru carbonyl clusters are demonstrated [ru

  16. Transformation of a Cp*-iridium(III) precatalyst for water oxidation when exposed to oxidative stress.

    Science.gov (United States)

    Zuccaccia, Cristiano; Bellachioma, Gianfranco; Bortolini, Olga; Bucci, Alberto; Savini, Arianna; Macchioni, Alceo

    2014-03-17

    The reaction of [Cp*Ir(bzpy)NO3 ] (1; bzpy=2-benzoylpyridine, Cp*=pentamethylcyclopentadienyl anion), a competent water-oxidation catalyst, with several oxidants (H2 O2 , NaIO4 , cerium ammonium nitrate (CAN)) was studied to intercept and characterize possible intermediates of the oxidative transformation. NMR spectroscopy and ESI-MS techniques provided evidence for the formation of many species that all had the intact Ir-bzpy moiety and a gradually more oxidized Cp* ligand. Initially, an oxygen atom is trapped in between two carbon atoms of Cp* and iridium, which gives an oxygen-Ir coordinated epoxide, whereas the remaining three carbon atoms of Cp* are involved in a η(3) interaction with iridium (2 a). Formal addition of H2 O to 2 a or H2 O2 to 1 leads to 2 b, in which a double MeCOH functionalization of Cp* is present with one MeCOH engaged in an interaction with iridium. The structure of 2 b was unambiguously determined in the solid state and in solution by X-ray single-crystal diffractometry and advanced NMR spectroscopic techniques, respectively. Further oxidation led to the opening of Cp* and transformation of the diol into a diketone with one carbonyl coordinated at the metal (2 c). A η(3) interaction between the three non-oxygenated carbons of "ex-Cp*" and iridium is also present in both 2 b and 2 c. Isolated 2 b and mixtures of 2 a-c species were tested in water-oxidation catalysis by using CAN as sacrificial oxidant. They showed substantially the same activity than 1 (turnover frequency values ranged from 9 to 14 min(-1) ). © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  17. Assessment of cirrus cloud and aerosol radiative effect in South-East Asia by ground-based NASA MPLNET lidar network data and CALIPSO satellite measurements

    Science.gov (United States)

    Lolli, Simone; Campbell, James R.; Lewis, Jasper R.; Welton, Ellsworth J.; Di Girolamo, Paolo; Fatkhuroyan, Fatkhuroyan; Gu, Yu; Marquis, Jared W.

    2017-10-01

    Aerosol, together with cirrus clouds, play a fundamental role in the earth-atmosphere system radiation budget, especially at tropical latitudes, where the Earth surface coverage by cirrus cloud can easily reach 70%. In this study we evaluate the combined aerosol and cirrus cloud net radiative effects in a wild and barren region like South East Asia. This part of the world is extremely vulnerable to climate change and it is source of important anthropogenic and natural aerosol emissions. The analysis has been carried out by computing cirrus cloud and aerosol net radiative effects through the Fu-Liou-Gu atmospheric radiative transfer model, adequately adapted to input lidar measurements, at surface and top-of-the atmosphere. The aerosol radiative effects were computed respectively using the retrieved lidar extinction from Cloud-Aerosol Lidar with Orthogonal Polarization in 2011 and 2012 and the lidar on-board of Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observations for the South East Asia Region (27N-12S, 77E-132E) with 5° x 5° spatial resolution. To assess the cirrus cloud radiative effect, we used the ground-based Micro Pulse Lidar Network measurements at Singapore permanent observational site. Results put in evidence that strong aerosol emission areas are related on average to a net surface cooling. On the contrary, cirrus cloud radiative effect shows a net daytime positive warming of the system earth-atmosphere. This effect is weak over the ocean where the albedo is lower and never counter-balances the net cooling produced by aerosols. The net cooling is stronger in 2011, with an associated reduction in precipitations by the four of the five rain-gauges stations deployed in three regions as Sumatra, Kalimantan and Java with respect to 2012. We can speculate that aerosol emissions may be associated with lower rainfall, however some very important phenomena as El Nino Southern Oscillation , Madden-Julian Oscillation, Monsoon and Indian Dipole are not

  18. Neutron activation determination of iridium, gold, platinum, and silver in geologic samples

    International Nuclear Information System (INIS)

    Millard, H.T.

    1986-01-01

    Low-level methods for the determination of iridium and other noble metals have been important in recent years due to interest in locating abundance anomalies associated with the Cretaceous/Tertiary (K/T) boundary. Typical iridium anomalies are in the range of 1 to 100 ppb. Thus methods with detection limits near 0.1 ppb should be adequate to detect K/T boundary anomalies. Radiochemical neutron activation analysis methods continue to be required although instrumental neutron activation analysis techniques employing elaborate gamma-counters are under development. In the procedure employed in this study samples irradiated in the epithermal neutron facility of the U.S. Geological Survey TRIGA Reactor are treated with a mini-fire assay technique. The iridium, gold, and silver are collected in a 1-gram metallic lead button. Primary contaminants at this stage are arsenic and antimony. These can be removed by heating the button with a mixture of sodium peroxide and sodium hydroxide. The resulting 0.2-gram lead bead is counted in a Compton suppression spectrometer. Carrier yields are determined by reirradiation of the lead beads. This procedure has been applied to the U.S.G.S. Standard Rock PCC-1. and samples from K/T boundary sites in the Western Interior of North America. (author)

  19. Production of iridium-alloy clad vent sets for the Cassini mission to Saturn

    International Nuclear Information System (INIS)

    Helle, K.J.; Moore, J.P.

    1995-01-01

    Martin Marietta Energy Systems, Inc., has successfully produced the iridium-alloy clad vent sets required for encapsulation of plutonia for the National Aeronautics and Space Administration Cassini mission to Saturn. Numerous improvements were made to the manufacturing process in various areas including dye-penetrant examination of cups, foil part stamping, chemical analysis, tungsten fixturing for laser welding, and enhanced inspections at high magnification. In addition, systems were initiated to ensure process control, and a detailed quality and technical surveillance program was prepared and followed to detect any incipient production problem early in the process so that corrective action could be taken immediately. The quality of the resulting iridium components has been high, and production yields have been above 90%. During the course of the production campaign for the Cassini mission, worker efficiencies lowered production costs, and further cost reductions are possible if operations are consolidated into a single area and bare-forming of the iridium alloys cups can be qualified for flight-quality clad vent sets

  20. Development and characterisation of iridium-192 seeds for brachytherapy treatment of ocular tumors

    International Nuclear Information System (INIS)

    Peleias Jr, F.S.; Zeituni, C.A.; Souza, C.D.; Rostelato, M.E.CM.; Mattos, F.R.; Banega, M.A.G.; Rodrigues, B.T.; Tiezzi, R.; Oliveira, T.B.; Feher, A.; Moura, J.A.; Costa, O.L.

    2014-01-01

    Even ocular tumors are not amongst the cases with a high incidence, they affect the population, particularly children. The Institute of Energy and Nuclear Research (IPEN-CNEN/SP) in partnership with Escola Paulista de Medicina (UNIFESP), created a project to develop an alternative treatment for ophthalmic cancer that uses iridium-192 seeds in brachytherapy. This work aims to study and develop a seed of iridium-192 from a platinum-iridium alloy The prototype seed has a 3.0 mm long core sealed by a titanium capsule of 0.8 mm of outer diameter, 0.05 mm of wall thickness and 4.5 mm long. We developed a methodology that covered: characterisation of the material used in the core, creation of a device for neutron activation of the cores and leakage tests. The results show that this methodology is feasible. As a suggestion for future work, studies regarding metrology and dosimetry of these sources should be carried out. (authors)

  1. Synthesis and electrophosphorescence of iridium complexes containing benzothiazole-based ligands.

    Science.gov (United States)

    Liu, Di; Ren, Huicai; Deng, Lijun; Zhang, Ting

    2013-06-12

    Four heteroleptic bis-cyclometalated iridium(III) complexes containing 2-aryl-benzothiazole ligands, in which the aryl is dibenzofuran-2-yl [Ir(O-bt)2(acac)], dibenzothiophene-2-yl [Ir(S-bt)2(acac)], dibenzothiophene-S,S-dioxide-2-yl [Ir(SO2-bt)2(acac)] and 4-(diphenylphosphoryl)phenyl [Ir(PO-bt)2(acac)], have been synthesized and characterized for use in organic light-emitting diodes (OLEDs). These complexes emit bright yellow (551 nm) to orange-red (598 nm) phosphorescence at room temperature, the peak wavelengths of which can be finely tuned depending upon the electronic properties of the aryl group in the 2-position of benzothiazole. The strong electron-withdrawing aryls such as dibenzothiophene-S,S-dioxide2-yl and 4-(diphenylphosphoryl)phenyl caused bathochromatic shift of the iridium complex phosphorescence. These iridium complexes were used as doped emitters to fabricate yellow to orange-red OLEDs and good performance was obtained. In particular, a maximum luminance efficiency of 58.4 cd A(-1) (corresponding to 30.6 lm W(-1) and 19%) with CIE coordinates of (0.45, 0.52) was achieved for Ir(O-bt)2(acac)-based yellow device. Furthermore, the yellow emitting Ir(S-bt)2(acac) was used to fabricate two-element white OLED that exhibited a high efficiency of 32.4 cd A(-1) with CIE coordinates of (0.28, 0.44).

  2. Synthesis and Electroluminescent Property of New Orange Iridium Compounds for Flexible White Organic Light Emitting Diodes.

    Science.gov (United States)

    Lee, Ho Won; Jeong, Hyunjin; Kim, Young Kwan; Ha, Yunkyoung

    2015-10-01

    Recently, white organic light-emitting diodes (OLEDs) have aroused considerable attention because they have the potential of next-generation flexible displays and white illuminated applications. White OLED applications are particularly heading to the industry but they have still many problems both materials and manufacturing. Therefore, we proposed that the new iridium compounds of orange emitters could be demonstrated and also applied to flexible white OLEDs for verification of potential. First, we demonstrated the chemical properties of new orange iridium compounds. Secondly, conventional two kinds of white phosphorescent OLEDs were fabricated by following devices; indium-tin oxide coated glass substrate/4,4'-bis[N-(napthyl)-N-phenylamino]biphenyl/N,N'-dicarbazolyl-3,5-benzene doped with blue and new iridium compounds for orange emitting 8 wt%/1,3,5-tris[N-phenylbenzimidazole-2-yl]benzene/lithium quinolate/aluminum. In addition, we fabricated white OLEDs using these emitters to verify the potential on flexible substrate. Therefore, this work could be proposed that white light applications can be applied and could be extended to additional research on flexible applications.

  3. Satellite Radio

    Indian Academy of Sciences (India)

    Satellites have been a highly effective platform for multi- form broadcasts. This has led to a ... diversity offormats, languages, genre, and a universal reach that cannot be met by .... programs can be delivered to whom it is intended. In the case of.

  4. Development of Iridium Solid-state Reference Electrode for the Water Chemistry Status Measurement in Nuclear Power Plants

    International Nuclear Information System (INIS)

    Ku, Heekwon; Lim, Dongseok; Cho, Jaeseon

    2013-01-01

    The result of ECP measurement of piping material in nuclear power plant at low temperature using the developed iridium (SSRE) reference electrode is approximately -0.370V. Based on the various results of this study, the developed iridium (SSRE) reference electrode can be applied to the water chemistry environments of nuclear power plant. Various metallic materials used in a nuclear power plant have been exposed to a variety of water chemistry environments and the corrosion of metallic materials occurs due to the reactions between metal structures and water chemistry environments. Therefore, the management of the water chemistry factors is needed to prevent corrosion. The chemical factors affecting the corrosion are pH and Electrochemical Corrosion Potential (ECP). The world-wide studies suggest that ECP and pH are effective indicators for preventing the material damage from water chemistry condition. ECP and pH should be measured as the reference electrodes, and should show stable potential characteristics with fast responses. In this study, the iridium reference electrodes using a solid-state metal oxide electrode has been developed to measure effective indicators such as ECP and pH. The iridium (SSRE) reference electrode for the ECP measurement in water chemistry environment of nuclear power plants has been developed. A calibration for water chemistry measurement was performed by potential measurement of iridium (SSRE) reference electrode with Ag/AgCl (SSRE) reference electrode. The result exhibited a stable potential for 117 hours and a super-Nernst ian response with 63.12mV/p H. In this study, the iridium (SSRE) reference electrode shows super-Nernst ian characteristic and it may be caused by the property of electrolytically coated iridium oxide. Considering the long-term stability of the developed electrode, it is possible to apply as a reference electrode through calibration procedure

  5. LEOPACK The integrated services communications system based on LEO satellites

    Science.gov (United States)

    Negoda, A.; Bunin, S.; Bushuev, E.; Dranovsky, V.

    LEOPACK is yet another LEO satellite project which provides global integrated services for 'business' communications. It utilizes packet rather then circuit switching in both terrestrial and satellite chains as well as cellular approach for frequencies use. Original multiple access protocols and decentralized network control make it possible to organize regionally or logically independent and world-wide networks. Relatively small number of satellites (28) provides virtually global network coverage.

  6. Satellite Communications Using Commercial Protocols

    Science.gov (United States)

    Ivancic, William D.; Griner, James H.; Dimond, Robert; Frantz, Brian D.; Kachmar, Brian; Shell, Dan

    2000-01-01

    NASA Glenn Research Center has been working with industry, academia, and other government agencies in assessing commercial communications protocols for satellite and space-based applications. In addition, NASA Glenn has been developing and advocating new satellite-friendly modifications to existing communications protocol standards. This paper summarizes recent research into the applicability of various commercial standard protocols for use over satellite and space- based communications networks as well as expectations for future protocol development. It serves as a reference point from which the detailed work can be readily accessed. Areas that will be addressed include asynchronous-transfer-mode quality of service; completed and ongoing work of the Internet Engineering Task Force; data-link-layer protocol development for unidirectional link routing; and protocols for aeronautical applications, including mobile Internet protocol routing for wireless/mobile hosts and the aeronautical telecommunications network protocol.

  7. Scientific Satellites

    Science.gov (United States)

    1967-01-01

    noise signal level exceeds 10 times the normal background. EXPERIMENTS FOR SATELLITE ASTRONOMY 615 ANTENNA MONOPOLE -., PREAMPLFE = BANDPASS-FILTER...OUTPUT TO AND DETECTOR TELEMETRYCHANNELS (18) CALIBRATION NOISE MATRIX CLOCK NOISE SOURCE ’ON’ SOURCE COMMAND F ROM PROGRAMERP ANTENNA MONOPOLE FIGURE 13...Animal Tempera- ture Sensing for Studying the Effect of Prolonged Orbital Flight on the Circadian Rhythms of Pocket Mice . Unmanned Spacecraft Meeting

  8. Launching the First Indian Satellite

    Indian Academy of Sciences (India)

    long run, this is not bad since it generates self-confidence and self-reliance - which in the final analysis are .... hopes to find some new X-ray sources. The second ... from the state of health of the satellite can be judged. A tracking network gives ...

  9. Solar satellites

    Energy Technology Data Exchange (ETDEWEB)

    Poher, C.

    1982-01-01

    A reference system design, projected costs, and the functional concepts of a satellite solar power system (SSPS) for converting sunlight falling on solar panels of a satellite in GEO to a multi-GW beam which could be received by a rectenna on earth are outlined. Electricity transmission by microwaves has been demonstrated, and a reference design system for supplying 5 GW dc to earth was devised. The system will use either monocrystalline Si or concentrator GaAs solar cells for energy collection in GEO. Development is still needed to improve the lifespan of the cells. Currently, the cell performance degrades 50 percent in efficiency after 7-8 yr in space. Each SSPS satellite would weigh either 34,000 tons (Si) or 51,000 tons (GaAs), thereby requiring the fabrication of a heavy lift launch vehicle or a single-stage-to-orbit transport in order to minimize launch costs. Costs for the solar panels have been estimated at $500/kW using the GaAs technology, with transport costs for materials to GEO being $40/kg.

  10. Solar satellites

    Science.gov (United States)

    Poher, C.

    A reference system design, projected costs, and the functional concepts of a satellite solar power system (SSPS) for converting sunlight falling on solar panels of a satellite in GEO to a multi-GW beam which could be received by a rectenna on earth are outlined. Electricity transmission by microwaves has been demonstrated, and a reference design system for supplying 5 GW dc to earth was devised. The system will use either monocrystalline Si or concentrator GaAs solar cells for energy collection in GEO. Development is still needed to improve the lifespan of the cells. Currently, the cell performance degrades 50 percent in efficiency after 7-8 yr in space. Each SSPS satellite would weigh either 34,000 tons (Si) or 51,000 tons (GaAs), thereby requiring the fabrication of a heavy lift launch vehicle or a single-stage-to-orbit transport in order to minimize launch costs. Costs for the solar panels have been estimated at $500/kW using the GaAs technology, with transport costs for materials to GEO being $40/kg.

  11. Study of neutron deficient iridium isotopes by using laser spectroscopy; Etude des noyaux d'iridium deficients en neutrons par spectroscopie laser

    Energy Technology Data Exchange (ETDEWEB)

    Verney, D

    2000-12-19

    Resonance ionization spectroscopy was performed on neutron deficient iridium isotopes {sup 182-189}Ir, {sup 186}Ir{sup m} and stable isotopes {sup 191,193}Ir. Hyperfine spectra were recorded from the optical transition at 351,7 nm between the 5d{sup 7}6s{sup 2} {sup 4}F{sub 9/2} ground state and the 5d{sup 7}6s6p {sup 6}F{sub 11/2} excited state. Radioactive iridium isotopes were obtained from {beta}{sup +}/EC decay of radioactive mercury nuclei deposited on a graphite substrate. The radioactive mercury nuclei were produced at the ISOLDE facility at CERN through spallation reactions, by bombarding a molten lead target with the 1 GeV proton beam delivered by the PS-Booster. Magnetic dipole moments and spectroscopic quadrupole moments were extracted from the hyperfine spectra. The mean square charge radius variations, as deduced from the measured isotopic shift, show a sharp change between {sup 187}Ir and {sup 186}Ir{sup g}, accompanied by a sudden increase in deformation: from {beta}2 {approx} 0,16 to {beta}2 > 0, 2. These results were analysed in the framework of an axial rotor plus one or two quasiparticles. The wave functions of the osmium and platinum cores which are used in order to describe the iridium nuclei were calculated from the HF+BCS method with the Skyrme SIII effective interaction. The cores were constrained to take the deformation parameters extracted from the isotopic shift measurements. One shows then that this sudden deformation change corresponds also to a change in the proton state that describes the odd nuclei ground state or that participates in the coupling with the neutron in odd-odd nuclei. This state is identified with the {pi}3/2{sup +}[402] orbital for the smaller deformations nuclei and with the {pi}1/2{sup -}[541] orbital stemming from the h{sub 9/2} subshell for bigger deformations nuclei. (author)

  12. Development of accurate mass spectrometric routine and reference methods for the determination of trace amounts of iridium and rhodium in photographic emulsionsf

    NARCIS (Netherlands)

    Krystek, Petra; Heumann, Klaus G.

    1999-01-01

    For the determination of trace amounts of iridium and rhodium in photographic emulsions different sample treatment procedures were coupled with inductively coupled plasma mass spectrometry (ICP-MS) and, for iridium, also with negative thermal ionisation isotope dilution mass spectrometry (NTI-IDMS)

  13. Networking

    OpenAIRE

    Rauno Lindholm, Daniel; Boisen Devantier, Lykke; Nyborg, Karoline Lykke; Høgsbro, Andreas; Fries, de; Skovlund, Louise

    2016-01-01

    The purpose of this project was to examine what influencing factor that has had an impact on the presumed increasement of the use of networking among academics on the labour market and how it is expressed. On the basis of the influence from globalization on the labour market it can be concluded that the globalization has transformed the labour market into a market based on the organization of networks. In this new organization there is a greater emphasis on employees having social qualificati...

  14. Security Concepts for Satellite Links

    Science.gov (United States)

    Tobehn, C.; Penné, B.; Rathje, R.; Weigl, A.; Gorecki, Ch.; Michalik, H.

    2008-08-01

    The high costs to develop, launch and maintain a satellite network makes protecting the assets imperative. Attacks may be passive such as eavesdropping on the payload data. More serious threat are active attacks that try to gain control of the satellite, which may lead to the total lost of the satellite asset. To counter these threats, new satellite and ground systems are using cryptographic technologies to provide a range of services: confidentiality, entity & message authentication, and data integrity. Additionally, key management cryptographic services are required to support these services. This paper describes the key points of current satellite control and operations, that are authentication of the access to the satellite TMTC link and encryption of security relevant TM/TC data. For payload data management the key points are multi-user ground station access and high data rates both requiring frequent updates and uploads of keys with the corresponding key management methods. For secure satellite management authentication & key negotiation algorithms as HMAC-RIPEMD160, EC- DSA and EC-DH are used. Encryption of data uses algorithms as IDEA, AES, Triple-DES, or other. A channel coding and encryption unit for payload data provides download data rates up to Nx250 Mbps. The presented concepts are based on our experience and heritage of the security systems for all German MOD satellite projects (SATCOMBw2, SAR-Lupe multi- satellite system and German-French SAR-Lupe-Helios- II systems inter-operability) as well as for further international (KOMPSAT-II Payload data link system) and ESA activities (TMTC security and GMES).

  15. Effects of DeOrbitSail as applied to Lifetime predictions of Low Earth Orbit Satellites

    Science.gov (United States)

    Afful, Andoh; Opperman, Ben; Steyn, Herman

    2016-07-01

    Orbit lifetime prediction is an important component of satellite mission design and post-launch space operations. Throughout its lifetime in space, a spacecraft is exposed to risk of collision with orbital debris or operational satellites. This risk is especially high within the Low Earth Orbit (LEO) region where the highest density of space debris is accumulated. This paper investigates orbital decay of some LEO micro-satellites and accelerating orbit decay by using a deorbitsail. The Semi-Analytical Liu Theory (SALT) and the Satellite Toolkit was employed to determine the mean elements and expressions for the time rates of change. Test cases of observed decayed satellites (Iridium-85 and Starshine-1) are used to evaluate the predicted theory. Results for the test cases indicated that the theory fitted observational data well within acceptable limits. Orbit decay progress of the SUNSAT micro-satellite was analysed using relevant orbital parameters derived from historic Two Line Element (TLE) sets and comparing with decay and lifetime prediction models. This paper also explored the deorbit date and time for a 1U CubeSat (ZACUBE-01). The use of solar sails as devices to speed up the deorbiting of LEO satellites is considered. In a drag sail mode, the deorbitsail technique significantly increases the effective cross-sectional area of a satellite, subsequently increasing atmospheric drag and accelerating orbit decay. The concept proposed in this study introduced a very useful technique of orbit decay as well as deorbiting of spacecraft.

  16. Nuclear resonance scattering study of iridates, iridium and antimony based pyrochlores

    International Nuclear Information System (INIS)

    Alexeev, P.

    2017-04-01

    This thesis shows the first synchrotron-based Moessbauer spectroscopy studies on iridium containing compounds and first vibrational spectroscopy on Sb containing compounds carried out at the P01 beamline of PETRA III. In this context, two types of X-ray monochromators have been developed: a monochromator for 73 keV photons with medium energy resolution, and a high-resolution backscattering monochromator based on a sapphire crystal. The monochromator for 73 keV X-rays is the key instrument for hyperfine spectroscopy on Iridium compounds, while the sapphire backscattering monochromator is purposed to vibrational spectroscopy on any Moessbauer resonances with the transition energies in the 20-50 keV range. Additionally, the signal detection for nuclear resonance scattering experiments at the beamline was significantly improved during this work, inspired by the high energies and low lifetimes of the employed resonances. The first synchrotron-based hyperfine spectroscopy on Iridium-containing compounds was demonstrated by NRS on 73 keV resonance in "1"9"3Ir. The results can be interpreted by dynamical theory of nuclear resonance scattering. In this work, special emphasis is set onto the electronic and magnetic properties of Ir nuclei in IrO_2 and in Ruddlesden-Popper (RP) phases of strontium iridates Sr_n_+_1Ir_nO_3_n_+_1 (n=0,1). These systems are well-suited for studies with X-ray scattering techniques, since the scattered signal contains vast information about the widely tunable crystallographic and electronic structure of these systems; furthermore, studies with X-rays are less limited by absorption from iridium as it is the case for neutron scattering experiments. The hyperfine parameters in IrO_2, SrIrO_3 and Sr_2IrO_4 have been measured via Nuclear Forward Scattering for the first time. Using the dynamical theory of NRS, the temperature and magnetic field dependence of the electric field gradient and magnetic hyperfine field on Ir nucleus have been determined for

  17. Nuclear resonance scattering study of iridates, iridium and antimony based pyrochlores

    Energy Technology Data Exchange (ETDEWEB)

    Alexeev, P.

    2017-04-15

    This thesis shows the first synchrotron-based Moessbauer spectroscopy studies on iridium containing compounds and first vibrational spectroscopy on Sb containing compounds carried out at the P01 beamline of PETRA III. In this context, two types of X-ray monochromators have been developed: a monochromator for 73 keV photons with medium energy resolution, and a high-resolution backscattering monochromator based on a sapphire crystal. The monochromator for 73 keV X-rays is the key instrument for hyperfine spectroscopy on Iridium compounds, while the sapphire backscattering monochromator is purposed to vibrational spectroscopy on any Moessbauer resonances with the transition energies in the 20-50 keV range. Additionally, the signal detection for nuclear resonance scattering experiments at the beamline was significantly improved during this work, inspired by the high energies and low lifetimes of the employed resonances. The first synchrotron-based hyperfine spectroscopy on Iridium-containing compounds was demonstrated by NRS on 73 keV resonance in {sup 193}Ir. The results can be interpreted by dynamical theory of nuclear resonance scattering. In this work, special emphasis is set onto the electronic and magnetic properties of Ir nuclei in IrO{sub 2} and in Ruddlesden-Popper (RP) phases of strontium iridates Sr{sub n+1}Ir{sub n}O{sub 3n+1} (n=0,1). These systems are well-suited for studies with X-ray scattering techniques, since the scattered signal contains vast information about the widely tunable crystallographic and electronic structure of these systems; furthermore, studies with X-rays are less limited by absorption from iridium as it is the case for neutron scattering experiments. The hyperfine parameters in IrO{sub 2}, SrIrO{sub 3} and Sr{sub 2}IrO{sub 4} have been measured via Nuclear Forward Scattering for the first time. Using the dynamical theory of NRS, the temperature and magnetic field dependence of the electric field gradient and magnetic hyperfine field

  18. Satellite Communication and Long Distance Education

    Directory of Open Access Journals (Sweden)

    Hafied Cangara

    2016-02-01

    Full Text Available Since Indonesia introduced communication satellite for telecommunication network, the satellite has brought a number of advantages for national development in various areas, such as telephone network, mass media development, business, education, politics, security and national defence as well as regional and international cooperation. In education, satellite communication could be used for long-distance learning as implemented by 13 state universities in eastern parts of Indonesia. It is also possible to develop the Open University System in teaching and learning process, particularly since the internet technology has been intensively used

  19. Techniques for Achieving Zero Stress in Thin Films of Iridium, Chromium, and Nickel

    Science.gov (United States)

    Broadway, David M.; O'Dell, Stephen L.; Ramsey, Brian D.; Weimer, Jeffrey

    2015-01-01

    We examine techniques for achieving zero intrinsic stress in thin films of iridium, chromium, and nickel deposited by magnetron sputter deposition. The intrinsic stress is further correlated to the microstructural features and physical properties such as surface roughness and optical density at a scale appropriate to soft X-ray wavelengths. The examination of the stress in these materials is motivated by efforts to advance the optical performance of light-weight X-ray space telescopes into the regime of sub-arcsecond resolution through various deposition techniques that rely on control of the film stress to values within 10-100 MPa. A characteristic feature of the intrinsic stress behavior in chromium and nickel is their sensitivity to the magnitude and sign of the intrinsic stress with argon gas pressure and deposition rate, including the existence of a critical argon process pressure that results in zero film stress which scales linearly with the atomic mass of the sputtered species. While the effect of stress reversal with argon pressure has been previously reported by Hoffman and others for nickel and chromium, we report this effect for iridium. In addition to stress reversal, we identify zero stress in the optical functioning iridium layer shortly after island coalescence for low process pressures at a film thickness of approximately 35nm. The measurement of the low values of stress during deposition was achieved with the aid of a sensitive in-situ instrument capable of a minimum detectable level of stress, assuming a 35nm thick film, in the range of 0.40-6.0 MPa for oriented crystalline silicon substrate thicknesses of 70-280 microns, respectively.

  20. A colorimetric and luminescent dual-modal assay for Cu(II ion detection using an iridium(III complex.

    Directory of Open Access Journals (Sweden)

    Dik-Lung Ma

    Full Text Available A novel iridium(III complex-based chemosensor bearing the 5,6-bis(salicylideneimino-1,10-phenanthroline ligand receptor was developed, which exhibited a highly sensitive and selective color change from colorless to yellow and a visible turn-off luminescence response upon the addition of Cu(II ions. The interactions of this iridium(III complex with Cu2+ ions and thirteen other cations have been investigated by UV-Vis absorption titration, emission titration, and 1H NMR titration.

  1. Synthesis and structural studies of Cp{sup *} rhodium and Cp{sup *} iridium complexes of picolinic hydrazine ligand

    Energy Technology Data Exchange (ETDEWEB)

    Palepu, Narasinga Rao; Kollipara, Mohan Rao [Centre for Advanced Studies in Chemistry, North-Eastern Hill University, Shillong (India); Kaminsky Werner [Dept. of Chemistry, University of Washington, Seattle (United States)

    2017-01-15

    A series of Cp{sup *}Rh and Cp{sup *}Ir complexes of picolinic hydrazine ligand are synthesized and characterized. Picolinic hydrazine has yielded only dinuclear complexes in the case of rhodium metal whereas both mono and dinuclear complexes with iridium metal. Iridium complexes are formed as quaternary salts by the migration of the N–H proton onto the adjacent amine group of the hydrazine after binding to the metal. Picolinic hydrazine acts as nitrogen and oxygen donor ligand in the form of bi and tetradentate bonding modes.

  2. Palynological and iridium anomalies at Cretaceous-Tertiary boundary, south-central Saskatchewan

    Science.gov (United States)

    Nichols, D.J.; Jarzen, D.M.; Orth, C.J.; Oliver, P.Q.

    1986-01-01

    The Cretaceous-Tertiary boundary in south-central Saskatchewan is marked by coincident anomalies in abundance of iridium and fern spores at the extinction level of a suite of Cretaceous pollen taxa. Evidence of disruption of the terrestrial flora includes the fern-spore abundance anomaly and local extinction of as much as 30 percent of angiosperm species. The reorganized earliest Tertiary flora is made up largely of surviving species that assumed new roles of dominance. Persistence of climatically sensitive taxa across the boundary indicates that if paleoclimate was altered by the terminal Cretaceous event, it returned quickly to the pre-event condition.

  3. A calorimetric particle detector using an iridium superconducting phase transition thermometer

    International Nuclear Information System (INIS)

    Frank, M.; Dummer, D.; Cooper, S.; Igalson, J.; Proebst, F.; Seidel, W.

    1994-01-01

    We report on a calorimetric particles detector consisting of an 18.3 g silicon crystal and an iridium superconducting phase transition thermometer. The cryogenic calorimeter and the associated apparatus are described in detail. The pulses from irradiation with an α-particle source have a large unexpected overshoot in addition to the component expected from a naive thermal model. The pulse height spectrum displays an energy resolution of 1 percent FWHM at 6 MeV and good linearity. The noise, electrothermal feedback, and position dependence are discussed. (orig.)

  4. Hydrogen transfer reduction of polyketones catalyzed by iridium complexes: a novel route towards more biocompatible materials.

    Science.gov (United States)

    Milani, Barbara; Crottib, Corrado; Farnetti, Erica

    2008-09-14

    Transfer hydrogenation from 2-propanol to CO/4-methylstyrene and CO/styrene polyketones was catalyzed by [Ir(diene)(N-N)X] (N-N = nitrogen chelating ligand; X = halogen) in the presence of a basic cocatalyst. The reactions were performed using dioxane as cosolvent, in order to overcome problems due to low polyketone solubility. The polyalcohols were obtained in yields up to 95%, the conversions being markedly dependent on the nature of the ligands coordinated to iridium as well as on the experimental conditions.

  5. Solid-state electrochromic cell with anodic iridium oxide film electrodes

    International Nuclear Information System (INIS)

    Dautremont-Smith, W.C.; Beni, G.; Schiavone, L.M.; Shay, J.L.

    1979-01-01

    A new solid-state electrochromic cell has been fabricated using an anodic iridium oxide film (AIROF) display electrode. The cell has the symmetric sandwich structure AIROFvertical-barNafionvertical-barAIROF, with the Nafion solid electrolyte opacified by an in situ precipitation technique. A symmetric square-wave voltage of 1.5 V amplitude produces clearly perceivable color changes from pale to dark blue-gray in approx. =1 sec when viewed in diffuse reflection. Good open-circuit optical memory is exhibited:

  6. Chlorido(η4-1,5-cyclooctadiene[(pentafluoroethyldiphenylphosphane]iridium(I

    Directory of Open Access Journals (Sweden)

    Russell G. Baughman

    2011-01-01

    Full Text Available The title structure,[IrCl(C8H12(C14H10F5P], reveals that (C2F5PPh2 (pentafluoroethyldiphenylphosphane or pfepp disrupts the iridium dimer [(codIrCl]2 (cod = cycloocta-1,5-diene by rupturing the bridging chloride ligands and binding in the open coordination site to form (codIr(pfeppCl with the IrI atom in a distorted square-planar coordination environment. The structure deviates very little from the IrI–triphenylphosphine analog, although a significantly (∼20σ shorter Ir—P bond is noted for the title compound.

  7. Lewis Base Activation of Silyl Acetals: Iridium-Catalyzed Reductive Horner-Wadsworth-Emmons Olefination.

    Science.gov (United States)

    Dakarapu, Udaya Sree; Bokka, Apparao; Asgari, Parham; Trog, Gabriela; Hua, Yuanda; Nguyen, Hiep H; Rahman, Nawal; Jeon, Junha

    2015-12-04

    A Lewis base promoted deprotonative pronucleophile addition to silyl acetals has been developed and applied to the iridium-catalyzed reductive Horner-Wadsworth-Emmons (HWE) olefination of esters and the chemoselective reduction of the resulting enoates. Lewis base activation of silyl acetals generates putative pentacoordinate silicate acetals, which fragment into aldehydes, silanes, and alkoxides in situ. Subsequent deprotonative metalation of phosphonate esters followed by HWE with aldehydes furnishes enoates. This operationally convenient, mechanistically unique protocol converts the traditionally challenging aryl, alkenyl, and alkynyl esters to homologated enoates at room temperature within a single vessel.

  8. Satellite communications: possibilities and problems

    International Nuclear Information System (INIS)

    Hine, M.

    1986-01-01

    Communication links via satellites are becoming available in Europe, both as part of the development of the telephone system and as special services aimed at data traffic. They offer the possibility of speeds between 50 kb/s and 2 Mb/s, without the problems and long term commitments of long distance land lines. Such links are provided by the PTT's as circuits which can be booked for variable periods, and have error rates which can be very low and well controlled. Problems in networking can arise from the satellite delay, particularly if errors occur in the local connections, and from the leased circuit and tariff philosophies of the PTT's. (Auth.)

  9. An introduction to optimal satellite range scheduling

    CERN Document Server

    Vázquez Álvarez, Antonio José

    2015-01-01

    The satellite range scheduling (SRS) problem, an important operations research problem in the aerospace industry consisting of allocating tasks among satellites and Earth-bound objects, is examined in this book. SRS principles and solutions are applicable to many areas, including: Satellite communications, where tasks are communication intervals between sets of satellites and ground stations Earth observation, where tasks are observations of spots on the Earth by satellites Sensor scheduling, where tasks are observations of satellites by sensors on the Earth. This self-contained monograph begins with a structured compendium of the problem and moves on to explain the optimal approach to the solution, which includes aspects from graph theory, set theory, game theory and belief networks. This book is accessible to students, professionals and researchers in a variety of fields, including: operations research, optimization, scheduling theory, dynamic programming and game theory. Taking account of the distributed, ...

  10. Satellite-Based Sunshine Duration for Europe

    Directory of Open Access Journals (Sweden)

    Bodo Ahrens

    2013-06-01

    Full Text Available In this study, two different methods were applied to derive daily and monthly sunshine duration based on high-resolution satellite products provided by the European Organisation for the Exploitation of Meteorological Satellites (EUMETSAT Satellite Application Facility on Climate Monitoring using data from Meteosat Second Generation (MSG SEVIRI (Spinning Enhanced Visible and Infrared Imager. The satellite products were either hourly cloud type or hourly surface incoming direct radiation. The satellite sunshine duration estimates were not found to be significantly different using the native 15-minute temporal resolution of SEVIRI. The satellite-based sunshine duration products give additional spatial information over the European continent compared with equivalent in situ-based products. An evaluation of the satellite sunshine duration by product intercomparison and against station measurements was carried out to determine their accuracy. The satellite data were found to be within ±1 h/day compared to high-quality Baseline Surface Radiation Network or surface synoptic observations (SYNOP station measurements. The satellite-based products differ more over the oceans than over land, mainly because of the treatment of fractional clouds in the cloud type-based sunshine duration product. This paper presents the methods used to derive the satellite sunshine duration products and the performance of the different retrievals. The main benefits and disadvantages compared to station-based products are also discussed.

  11. Oxidation of iridium coating on rhenium coated graphite at elevated temperature in stagnated air

    International Nuclear Information System (INIS)

    Huang, Yongle; Bai, Shuxin; Zhang, Hong; Ye, Yicong

    2015-01-01

    Highlights: • Continuous and dense Ir coatings were prepared on graphite by electrodepostion. • The purification of the as-prepared Ir coating was higher than about 99.98%. • The Ir/Re/C specimen kept integrity without significant failures after oxidation. • The average oxidation rate of the Ir coating was about 0.219 mg/(cm 2 min). • Penetrating holes at gains boundaries resulted in the failure of the Ir coating. - Abstract: Continuous and dense iridium coatings were prepared on the rhenium coated graphite specimens by electrodeposition. The iridium/rhenium coated graphite (Ir/Re/C) specimens were oxidized at elevated temperatures in stagnated air for 3600 s. The purification of the as-prepared Ir coating was higher than about 99.98% with the main impurity elements Si, Al, Fe and Ru. After oxidation, the Ir/Re/C specimens kept integrity without significant failures and the average oxidation rate was about 0.219 mg/(cm 2 min). Pores were found at the grain boundaries and concentrated to penetrating holes with the growth of Ir grains, which resulted in disastrous failures of the Ir coating

  12. Oxidation of iridium coating on rhenium coated graphite at elevated temperature in stagnated air

    Energy Technology Data Exchange (ETDEWEB)

    Huang, Yongle; Bai, Shuxin, E-mail: NUDT_MSE_501@163.com; Zhang, Hong; Ye, Yicong

    2015-02-15

    Highlights: • Continuous and dense Ir coatings were prepared on graphite by electrodepostion. • The purification of the as-prepared Ir coating was higher than about 99.98%. • The Ir/Re/C specimen kept integrity without significant failures after oxidation. • The average oxidation rate of the Ir coating was about 0.219 mg/(cm{sup 2} min). • Penetrating holes at gains boundaries resulted in the failure of the Ir coating. - Abstract: Continuous and dense iridium coatings were prepared on the rhenium coated graphite specimens by electrodeposition. The iridium/rhenium coated graphite (Ir/Re/C) specimens were oxidized at elevated temperatures in stagnated air for 3600 s. The purification of the as-prepared Ir coating was higher than about 99.98% with the main impurity elements Si, Al, Fe and Ru. After oxidation, the Ir/Re/C specimens kept integrity without significant failures and the average oxidation rate was about 0.219 mg/(cm{sup 2} min). Pores were found at the grain boundaries and concentrated to penetrating holes with the growth of Ir grains, which resulted in disastrous failures of the Ir coating.

  13. Colorimetric and luminescent bifunctional iridium(III) complexes for the sensitive recognition of cyanide ions

    Science.gov (United States)

    Chen, Xiudan; Wang, Huili; Li, Jing; Hu, Wenqin; Li, Mei-Jin

    2017-02-01

    Two new cyclometalated iridium(III) complexes [(ppy)2Irppz]Cl (1) and [(ppy)2Irbppz]Cl (2) (where ppy = 2-phenylpyridine, ppz = 4,7-phenanthrolino-5,6:5,6-pyrazine, bppz = 2.3-di-2-pyridylpyrazine), were designed and synthesized. The structure of [(ppy)2Irppz]Cl was determined by single crystal X-ray diffraction. Their photophysical properties were also studied. This kind of complexes could coordinate with Cu2 +, the photoluminescence (PL) of the complex was quenched, and the color changed from orange-red to green. The forming M-Cu (M: complexes 1 and 2) ensemble could be further utilized as a colorimetric and emission ;turn-on; bifunctional detection for CN-, especially for complex 1-Cu2 + showed a high sensitivity toward CN- with a limit of diction is 97 nM. Importantly, this kind of iridium(III) complexes shows a unique recognition of cyanide ions over other anions which makes it an eligible sensing probe for cyanide ions.

  14. Detection of triglyceride using an iridium nano-particle catalyst based amperometric biosensor.

    Science.gov (United States)

    Liao, Wei-Yin; Liu, Chung-Chiun; Chou, Tse-Chuan

    2008-12-01

    The detection and quantification of triglyceride (TG) using an iridium nano-particle modified carbon based biosensor was successfully carried out in this study. The detection procedures were based on the electrochemical detection of enzymatically produced NADH. TG was hydrolyzed by lipase and the glycerol produced was catalytically oxidized by NAD-dependent glycerol dehydrogenase producing NADH in a solution containing NAD(+). Glyceryl tributyrate, a short chain triglyceride, was chosen as the substrate for the evaluation of this TG biosensor in bovine serum and human serum. A linear response to glyceryl tributyrate in the concentration range of 0 to 10 mM and a sensitivity of 7.5 nA mM(-1) in bovine serum and 7.0 nA mM(-1) in human serum were observed experimentally. The potential interference of species such as uric acid (UA) and ascorbic acid (AA) was assessed. The incorporation of a selected surfactant and an increase in the incubation temperature appeared to enhance the performance of this biosensor. The conditions for the determination of TG levels in bovine serum using this biosensor were optimized, with sunflower seed oil being used as an analyte to simulate the detection of TG in blood. The experimental results demonstrated that this iridium nano-particle modified working electrode based biosensor provided a relatively simple means for the accurate determination of TG in serum.

  15. Thermal hydraulic modelling of the Mo and Iridium irradiation facilities of the RA10 reactor

    International Nuclear Information System (INIS)

    Gramajo, M.; García, J.; Marcel, C.P.

    2013-01-01

    The RA-10 reactor is a multipurpose, open pool research reactor. The core consists of a rectangular array of MTR type fuel. The produced thermal power is 30 MW which is extracted by the refrigeration system via an ascendant flow through the core. The core reflector is D 2 O contained in a watertight tank. The design of the reactor includes a number of out-core facilities which are meant to be used for industrial, medical and research purposes. Among all the facilities, the most important ones are the Molybdenum and Iridium ones which we modeled in this work. During the normal operation of the reactor, the manipulation and the on-line extraction of the irradiation facilities is foreseen. Therefore the study of the head loss during the normal operation as well as during the extraction maneuvers plays a relevant role in the design and safety analysis. In this work a CFD commercial code is use dto perform the calculations needed to guarantee the design requirements.In addition, a full detailed geometric model for both, the Molybdenum and Iridium facilities,is used to perform the required simulations. The obtained results allow to evaluating the thermal-hydraulic performance of the proposed facilities designs. (author)

  16. Adsorption and desorption of hydrogen and carbon monoxide were studied on alumina-supported iridium catalysts

    Energy Technology Data Exchange (ETDEWEB)

    Etherton, B.P.

    1980-01-01

    The adsorption and desorption of hydrogen and carbon monoxide were studied on alumina-supported iridium catalysts which were examined by a scanning transmission electron microscope (STEM). The metal particle size and number of particles per area of catalyst increased with increasing metal loading. The particles were approx. 10 A. in diameter, cubo-octahedral shaped, and approx. 80-90% disperse. The STEM electron beam caused negligible damage to the samples. Hydrogen adsorption measurements showed that the hydrogen-iridium atom ratio was 1.2:1-1.3:1 and increased with decreasing metal loading. Temperature-programed desorption showed four types of adsorbed hydrogen desorbing at -90/sup 0/C (I), 15/sup 0/C (IV), 115/sup 0/C (II), and 245/sup 0/C (III). Types II and IV desorb from single atom sites and Types I and III from multiple atom sites. Type I is in rapid equilibrium with the gas phase. All desorption processes appear to be first order. Carbon monoxide adsorbed nondissociatively at 25/sup 0/C with approx. 0.7:1 CO/Ir atom ratio. It adsorbed primarily in linear forms at low coverage, but a bridged form appeared at high coverage.

  17. Adsorption and the initial stages of samarium condensation on iridium coated by graphite monolayer

    International Nuclear Information System (INIS)

    Abdullaev, R.M.; Tontegode, A.Ya.; Yusifov, F.K.

    1978-01-01

    Adsorption and the initial stages of vacuum samarium condensation on iridium coated by graphite monolayer (valent-saturated neutral substrate) were studied by the thermodesorption mass-spectrometry and thermoemission methods, and were compared with samarium adsorption and condensation on iridium. Desorption heat of samarium atoms with thin coating of Ir-C, equal to E approximately 1.9 eV has been determined. For desorption with Ir E is approximately 6 eV. Such a great difference in desorption heats is connected with the reduction of covalent constituent of adsorption bond in a neutral substrate. Samarium on Ir-C is found to be condensated in two states: loosely bound and tightly bound which sharply differ in properties. The tightly bound state is characterized by abnormally low vapour pressure. Possible nature of this state is discussed. Double effect on the condensation of the substrate valent saturation is noted. On the one hand, the reduction of the particle bond with the substrate decreases their concentration on the surface, preventing condensation. On the other hand, the release of the valent eloctrons of adatous brings about strong lateral interaction between them, which in its turn, promotes condensation during eased migration on the neutral substrate

  18. Efficiency Control in Iridium Complex-Based Phosphorescent Light-Emitting Diodes

    Directory of Open Access Journals (Sweden)

    Boucar Diouf

    2012-01-01

    Full Text Available Key factors to control the efficiency in iridium doped red and green phosphorescent light emitting diodes (PhOLEDs are discussed in this review: exciton confinement, charge trapping, dopant concentration and dopant molecular structure. They are not independent from each other but we attempt to present each of them in a situation where its specific effects are predominant. A good efficiency in PhOLEDs requires the triplet energy of host molecules to be sufficiently high to confine the triplet excitons within the emitting layer (EML. Furthermore, triplet excitons must be retained within the EML and should not drift into the nonradiative levels of the electron or hole transport layer (resp., ETL or HTL; this is achieved by carefully choosing the EML’s adjacent layers. We prove how reducing charge trapping results in higher efficiency in PhOLEDs. We show that there is an ideal concentration for a maximum efficiency of PhOLEDs. Finally, we present the effects of molecular structure on the efficiency of PhOLEDs using red iridium complex dopant with different modifications on the ligand to tune its highest occupied molecular orbital (HOMO and lowest unoccupied molecular orbital (LUMO energies.

  19. Synthesis and green electrophosphorescence of a novel cyclometalated iridium complex in polymer light-emitting diodes

    Energy Technology Data Exchange (ETDEWEB)

    Wu Lilan [Department of Chemistry, National Cheng Kung University, Tainan, Taiwan 70101 (China); Tsai Sunghao [Institute of Electro-Optical Science and Engineering, National Cheng Kung University, Tainan, Taiwan 70101 (China); Guo Tzungfang [Institute of Electro-Optical Science and Engineering, National Cheng Kung University, Tainan, Taiwan 70101 (China); Yang Chenghsien [Carbon Nanocapsules Research Department, Nano-Powder and Thin Film Technology Center, ITRI South, Tainan, Taiwan 709 (China)]. E-mail: jasonyang0606@yahoo.com.tw; Sun, I-W. [Department of Chemistry, National Cheng Kung University, Tainan, Taiwan 70101 (China)]. E-mail: iwsun@mail.ncku.edu.tw

    2007-10-15

    Abstact: In this paper, we synthesized a new complex bis(dibenzo[f,h]quinolinato-N,C {sup 2'}) iridium(III) acetylactonate ((DBQ){sub 2}Ir(acac)) having a longer conjugate system than bis(2-phenylpyridinato-N,C {sup 2'}) iridium(III) acetylacetonate ((PPY){sub 2}Ir(acac)). Interestingly (DBQ){sub 2}Ir(acac) emits at the same wavelength as (photoluminescence of 530 nm) (PPY){sub 2}Ir(acac). A high-efficiency electrophosphorescent polymer light-emitting diodes was constructed by using (DBQ){sub 2}Ir(acac) as the dopant, and a blend of poly(vinylcarbazole) (PVK) with 2-tert-butylphenyl-5-biphenyl-1,3,4-oxadiazol (PBD) as the host material. The electroluminescence efficiency of 9.5 cd/A is reported for the device doped with 3 wt% of (DBQ){sub 2}Ir(acac). In this device, the emission from the PVK or PBD host was effectively inhibited with the using (DBQ){sub 2}Ir(acac) . Emission from the dopant molecules in such devices involve localization of the injected electron and hole on the metal-organic center. This can occur by a variety of mechanisms, including Foerster and Dexter energy transfer from the host transport material to the dopant, and direct trapping of both electrons and holes on the metal-organic center.

  20. Geostationary Satellite (GOES) Images

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — Visible and Infrared satellite imagery taken from radiometer instruments on SMS (ATS) and GOES satellites in geostationary orbit. These satellites produced...

  1. Muscle invasive bladder cancer treated by transurethral resection, followed by external beam radiation and interstitial iridium-192

    NARCIS (Netherlands)

    A. Wijnmaalen (Arendjan); P.A. Helle (Peter); P.C.M. Koper (Peter); P.P. Jansen (Peter); P. Hanssens (Patrick); C.G.G. Boeken Kruger (Cornelis); W.L.J. van Putten (Wim)

    1997-01-01

    textabstractPurpose: To evaluate the results of transurethral resection (TUR), external beam radiotherapy (EBRT), and interstitial radiation (IRT) with iridium-192, using the afterloading technique in patients with muscle invasive bladder cancer. Methods and Materials: From May 1989 until September

  2. Determination of iridium in the Bering Sea and Arctic Ocean seawaters by anion exchange preconcentration-neutron activation analysis

    International Nuclear Information System (INIS)

    Li Shihong; Mao Xueying; Chai Zhifang

    2004-01-01

    Anion exchange method is investigated to separate and enrich iridium in seawater by radiotracer 192 Ir. The adsorption of Ir in the resin increases with the decreasing acidity in the 0.05-1.2 mol/L HCl media, The recovery of iridium in pH=1.5 seawater reaches 89% by a single anion-exchange column. The polyethylene container of acidity of pH=1.5 are suitable for storing trace Ir in seawater. An anion exchange preconcentration-neutron activation analysis procedure is developed to determine iridium in seawaters sampled from the Bering Sea and Arctic Ocean at different depth. The reagent blank value of the whole procedures is (0.18-0.20) x 10 -12 g Ir. The iridium concentrations in the Bering Sea and Arctic Ocean seawater samples are (0.85-3.58) x 10 -12 g/L (0-3504 m) and (1.26-1.97) x 10 -12 g/L (25-1900 m), respectively

  3. Phosphorescence Imaging of Living Cells with Amino Acid-Functionalized Tris(2-phenylpyridine)iridium(III) Complexes

    NARCIS (Netherlands)

    Steunenberg, P.; Ruggi, A.; Berg, van den N.S.; Buckle, T.; Kuil, J.; Leeuwen, van F.W.B.; Velders, A.H.

    2012-01-01

    A series of nine luminescent cyclometalated octahedral iridium(III) tris(2-phenylpyridine) complexes has been synthesized, functionalized with three different amino acids (glycine, alanine, and lysine), on one, two, or all three of the phenylpyridine ligands. All starting complexes and final

  4. Mono and dinuclear iridium, rhodium and ruthenium complexes containing chelating carboxylato pyrazine ligands: Synthesis, molecular structure and electrochemistry

    Czech Academy of Sciences Publication Activity Database

    Govindaswamy, P.; Therrien, B.; Süss-Fink, G.; Štěpnička, P.; Ludvík, Jiří

    2007-01-01

    Roč. 692, č. 8 (2007), s. 1661-1671 ISSN 0022-328X R&D Projects: GA MŠk LC510; GA MŠk(CZ) LC06070 Institutional research plan: CEZ:AV0Z40400503 Keywords : dinuclear complexes * iridium * rhodium * ruthenium * electrochemistry Subject RIV: CG - Electrochemistry Impact factor: 2.168, year: 2007

  5. UV-light promoted C-H bond activation of benzene and fluorobenzenes by an iridium(i) pincer complex.

    Science.gov (United States)

    Hauser, Simone A; Emerson-King, Jack; Habershon, Scott; Chaplin, Adrian B

    2017-03-28

    Iridium(i) carbonyl complex [Ir(2,6-(P t Bu 2 CH 2 ) 2 C 6 H 3 )(CO)] undergoes reversible C-H bond activation of benzene and a series of fluorobenzenes on UV irradiation. Exclusive ortho-selectivity is observed in reactions of fluorobenzene and 1,2-difluorobenzene.

  6. UV-light promoted C–H bond activation of benzene and fluorobenzenes by an iridium(i) pincer complex

    OpenAIRE

    Hauser, Simone A.; Emerson-King, Jack; Habershon, Scott; Chaplin, Adrian B.

    2017-01-01

    Iridium(I) carbonyl complex [Ir(2,6-(PtBu2CH2)2C6H3)(CO)] undergoes reversible C–H bond activation of benzene and a series of fluorobenzenes on UV irradiation. Exclusive ortho-selectivity is observed in reactions of fluorobenzene and 1,2-difluorobenzene.\\ud \\ud

  7. Regio- and Enantioselective N-Allylations of Imidazole, Benzimidazole, and Purine Heterocycles Catalyzed by Single-Component Metallacyclic Iridium Complexes

    Science.gov (United States)

    Stanley, Levi M.

    2010-01-01

    Highly regio- and enantioselective iridium-catalyzed N-allylations of benzimidazoles, imidazoles, and purines have been developed. N-Allylated benzimidazoles and imidazoles were isolated in high yields (up to 97%) with high branched-to-linear selectivity (up to 99:1) and enantioselectivity (up to 98% ee) from the reactions of benzimidazole and imidazole nucleophiles with unsymmetrical allylic carbonates in the presence of single component, ethylene-bound, metallacyclic iridium catalysts. N-Allylated purines were also obtained in high yields (up to 91%) with high N9:N7 selectivity (up to 96:4), high branched-to-linear selectivity (98:2), and high enantioselectivity (up to 98% ee) under similar conditions. The reactions encompass a range of benzimidazole, imidazole, and purine nucleophiles, as well as a variety of unsymmetrical aryl, heteroaryl, and aliphatic allylic carbonates. Competition experiments between common amine nucleophiles and the heterocyclic nitrogen nucleophiles studied in this work illustrate the effect of nucleophile pKa on the rate of iridium-catalyzed N-allylation reactions. Kinetic studies on the allylation of benzimidazole catalyzed by metallacyclic iridium-phosphoramidite complexes, in combination with studies on the deactivation of these catalysts in the presence of heterocyclic nucleophiles, provide insight into the effects of the structure of the phosphoramidite ligands on the stability of the metallacyclic catalysts. The data obtained from these studies has led to the development of N-allylations of benzimidazoles and imidazoles in the absence of an exogenous base. PMID:19480431

  8. A Software Implementation of a Satellite Interface Message Processor.

    Science.gov (United States)

    Eastwood, Margaret A.; Eastwood, Lester F., Jr.

    A design for network control software for a computer network is described in which some nodes are linked by a communications satellite channel. It is assumed that the network has an ARPANET-like configuration; that is, that specialized processors at each node are responsible for message switching and network control. The purpose of the control…

  9. The effect of surface depletion on the work function of arc-melted dilute solution tungsten-iridium alloys

    International Nuclear Information System (INIS)

    D'Cruz, L.A.; Bosch, D.R.; Jacobson, D.L.

    1991-01-01

    The requirements of thermionic electrode materials have emphasized the need for substantial improvements in microstructural stability, strength, and creep resistance at service temperature in excess of 2,500K. The present work extends an earlier study of the effective work function trends of a series of dilute solution tungsten, iridium alloys with iridium contents of 1, 3, and 5 wt%. Since the lifetime of candidate electrode materials is an important consideration, the present work attempts to evaluate the repeatability of the work function trends in these alloys. The effective work function was obtained from measurements of the current emitted from the electrode surface under UHV conditions in the temperature range of 1,800-2,500K using a Vacuum Emission Vehicle (VEV). The data generated in this work have been compared with data obtained in earlier studies performed on these alloys. It was found that the magnitude of the effective work function of these alloys was affected by changes in the subsurface iridium concentration. Furthermore, these alloys exhibited a dependence of the work function on temperature, after prolonged exposure to elevated temperatures. Such a temperature dependence can be explained by diffusion-controlled changes in the coverage of an iridium monolayer on the surface. It is proposed that the significant difference in effective work function trends obtained after prolonged exposure to elevated temperatures is a direct consequence of changes in the coverage of an iridium-rich monolayer on the electrode surface. The constitution of such a surface layer, however, would be governed by composition changes in the subsurface regions of the electrode caused thermally-activated transport processes

  10. Kids Interactive Telecommunications Project by Satellite (KITES): A Telecommunications Partnership To Empower Middle School Students.

    Science.gov (United States)

    LeBaron, John

    Kids Interactive Telecommunications Project by Satellite (KITES) is a cooperative international telecommunications partnership involving the University of Lowell, Digital's corporate video network, Videostar Connections Inc. (a satellite networking broker), PanAmSat (a satellite operator), and several other public education institutions in…

  11. Shadow imaging of geosynchronous satellites

    Science.gov (United States)

    Douglas, Dennis Michael

    Geosynchronous (GEO) satellites are essential for modern communication networks. If communication to a GEO satellite is lost and a malfunction occurs upon orbit insertion such as a solar panel not deploying there is no direct way to observe it from Earth. Due to the GEO orbit distance of ~36,000 km from Earth's surface, the Rayleigh criteria dictates that a 14 m telescope is required to conventionally image a satellite with spatial resolution down to 1 m using visible light. Furthermore, a telescope larger than 30 m is required under ideal conditions to obtain spatial resolution down to 0.4 m. This dissertation evaluates a method for obtaining high spatial resolution images of GEO satellites from an Earth based system by measuring the irradiance distribution on the ground resulting from the occultation of the satellite passing in front of a star. The representative size of a GEO satellite combined with the orbital distance results in the ground shadow being consistent with a Fresnel diffraction pattern when observed at visible wavelengths. A measurement of the ground shadow irradiance is used as an amplitude constraint in a Gerchberg-Saxton phase retrieval algorithm that produces a reconstruction of the satellite's 2D transmission function which is analogous to a reverse contrast image of the satellite. The advantage of shadow imaging is that a terrestrial based redundant set of linearly distributed inexpensive small telescopes, each coupled to high speed detectors, is a more effective resolved imaging system for GEO satellites than a very large telescope under ideal conditions. Modeling and simulation efforts indicate sub-meter spatial resolution can be readily achieved using collection apertures of less than 1 meter in diameter. A mathematical basis is established for the treatment of the physical phenomena involved in the shadow imaging process. This includes the source star brightness and angular extent, and the diffraction of starlight from the satellite

  12. Tracking and data relay satellite system (TDRSS) capabilities

    Science.gov (United States)

    Spearing, R. E.

    1985-10-01

    The Tracking and Data Relay Satellite System (TDRSS) is the latest implementation to tracking and data acquisition network for near-earth orbiting satellite support designed to meet the requirements of the current and projected (to the year 2000) satellite user community. The TDRSS consists of a space segment (SS) and a ground segment (GS) that fit within NASA's Space Network (SN) complex controlled at the Goddard Space Flight Center. The SS currently employs a single satellite, TDRS-1, with two additional satellites to be deployed in January 1986 and July 1986. The GS contains the communications and equipment required to manage the three TDR satellites and to transmit and receive information to and from TDRSS user satellites. Diagrams and tables illustrating the TDRSS signal characteristics, the situation of TDRSS within the SN, the SN operations and element interrelationships, as well as future plans for new missions are included.

  13. Iodine Satellite

    Science.gov (United States)

    Kamhawi, Hani; Dankanich, John; Martinez, Andres; Petro, Andrew

    2015-01-01

    The Iodine Satellite (iSat) spacecraft will be the first CubeSat to demonstrate high change in velocity from a primary propulsion system by using Hall thruster technology and iodine as a propellant. The mission will demonstrate CubeSat maneuverability, including plane change, altitude change and change in its closest approach to Earth to ensure atmospheric reentry in less than 90 days. The mission is planned for launch in fall 2017. Hall thruster technology is a type of electric propulsion. Electric propulsion uses electricity, typically from solar panels, to accelerate the propellant. Electric propulsion can accelerate propellant to 10 times higher velocities than traditional chemical propulsion systems, which significantly increases fuel efficiency. To enable the success of the propulsion subsystem, iSat will also demonstrate power management and thermal control capabilities well beyond the current state-of-the-art for spacecraft of its size. This technology is a viable primary propulsion system that can be used on small satellites ranging from about 22 pounds (10 kilograms) to more than 1,000 pounds (450 kilograms). iSat's fuel efficiency is ten times greater and its propulsion per volume is 100 times greater than current cold-gas systems and three times better than the same system operating on xenon. iSat's iodine propulsion system consists of a 200 watt (W) Hall thruster, a cathode, a tank to store solid iodine, a power processing unit (PPU) and the feed system to supply the iodine. This propulsion system is based on a 200 W Hall thruster developed by Busek Co. Inc., which was previously flown using xenon as the propellant. Several improvements have been made to the original system to include a compact PPU, targeting greater than 80 percent reduction in mass and volume of conventional PPU designs. The cathode technology is planned to enable heaterless cathode conditioning, significantly increasing total system efficiency. The feed system has been designed to

  14. Land mobile satellite services in Europe

    Science.gov (United States)

    Bartholomé, P.; Berretta, G.; Rogard, R.

    The demand for land-mobile communications on a Europe-wide basis is an important and pressing problem. The pan-European cellular network now in the planning stage will be slow in coming and it will have its limitations. A regional satellite system for Europe to complement the cellular network is the only practical way to satisfy a specialised market that encompasses a population of several hundred thousand mobiles, including road vehicles, merchant shipping, fishing boats, and trains. The deployment of a regional system would take place in a number of phases, the first being based on a simple payload embarked on a host satellite belonging to a European organisation. Further phases will involve the development of more advanced payloads on dedicated satellites. For the long-term future, the use of satellites in highly inclined orbits is being considered as a means of improving their visibility and hence the service quality.

  15. High power communication satellites power systems study

    International Nuclear Information System (INIS)

    Josloff, A.T.; Peterson, J.R.

    1994-01-01

    This paper discusses a DOE-funded study to evaluate the commercial attractiveness of high power communication satellites and assesses the attributes of both conventional photovoltaic and reactor power systems. This study brings together a preeminent US Industry/Russian team to cooperate on the role of high power communication satellites in the rapidly expanding communications revolution. These high power satellites play a vital role in assuring availability of universally accessible, wide bandwidth communications, for high definition TV, super computer networks and other services. Satellites are ideally suited to provide the wide bandwidths and data rates required and are unique in the ability to provide services directly to the users. As new or relocated markets arise, satellites offer a flexibility that conventional distribution services cannot match, and it is no longer necessary to be near population centers to take advantage of the telecommunication revolution. The geopolitical implications of these substantially enhanced communications capabilities will be significant

  16. Asteroid Satellites

    Science.gov (United States)

    Merline, W. J.

    2001-11-01

    Discovery and study of small satellites of asteroids or double asteroids can yield valuable information about the intrinsic properties of asteroids themselves and about their history and evolution. Determination of the orbits of these moons can provide precise masses of the primaries, and hence reliable estimates of the fundamental property of bulk density. This reveals much about the composition and structure of the primary and will allow us to make comparisons between, for example, asteroid taxonomic type and our inventory of meteorites. The nature and prevalence of these systems will also give clues as to the collisional environment in which they formed, and have further implications for the role of collisions in shaping our solar system. A decade ago, binary asteroids were more of a theoretical curiosity. In 1993, the Galileo spacecraft allowed the first undeniable detection of an asteroid moon, with the discovery of Dactyl, a small moon of Ida. Since that time, and particularly in the last year, the number of known binaries has risen dramatically. Previously odd-shaped and lobate near-Earth asteroids, observed by radar, have given way to signatures indicating, almost certainly, that at least four NEAs are binary systems. The tell-tale lightcurves of several other NEAs reveal a high likelihood of being double. Indications are that among the NEAs, there may be a binary frequency of several tens of percent. Among the main-belt asteroids, we now know of 6 confirmed binary systems, although their overall frequency is likely to be low, perhaps a few percent. The detections have largely come about because of significant advances in adaptive optics systems on large telescopes, which can now reduce the blurring of the Earth's atmosphere to compete with the spatial resolution of space-based imaging (which itself, via HST, is now contributing valuable observations). Most of these binary systems have similarities, but there are important exceptions. Searches among other

  17. Influence of iridium doping in MgB2 superconducting wires

    DEFF Research Database (Denmark)

    Grivel, Jean-Claude

    2018-01-01

    MgB2 wires with iridium doping were manufactured using the in-situ technique in a composite Cu-Nb sheath. Reaction was performed at 700°C, 800°C or 900°C for 1h in argon atmosphere. A maximum of about 1.5 at.% Ir replaces Mg in MgB2. The superconducting transition temperature is slightly lowered...... by Ir doping. The formation of IrMg3 and IrMg4 secondary phase particles is evidenced, especially for a nominal stoichiometry with 2.0 at.% Ir doping. The critical current density and accommodation field of the wires are strongly dependent on the Ir content and are generally weakened in the presence...

  18. Hot rocket plume experiment - Survey and conceptual design. [of rhenium-iridium bipropellants

    Science.gov (United States)

    Millard, Jerry M.; Luan, Taylor W.; Dowdy, Mack W.

    1992-01-01

    Attention is given to a space-borne engine plume experiment study to fly an experiment which will both verify and quantify the reduced contamination from advanced rhenium-iridium earth-storable bipropellant rockets (hot rockets) and provide a correlation between high-fidelity, in-space measurements and theoretical plume and surface contamination models. The experiment conceptual design is based on survey results from plume and contamination technologists throughout the U.S. With respect to shuttle use, cursory investigations validate Hitchhiker availability and adaptability, adequate remote manipulator system (RMS) articulation and dynamic capability, acceptable RMS attachment capability, adequate power and telemetry capability, and adequate flight altitude and attitude/orbital capability.

  19. Radiation dose evaluation for hypothetical accident with transport package containing Iridium-192 source

    International Nuclear Information System (INIS)

    Trontl, K.; Bace, M.; Pevec, D.

    2002-01-01

    The aim of this paper is to evaluate dose rates for a hypothetical accident with transport package containing Iridium-192 source and to design additional shielding necessary for the safe unloading of the container, assuming that during the unloading process the whole contents of a radioactive source is unshielded and that the operation is going to take place at the site where a working area exists in the vicinity of the unloading location. Based on the calculated radiation dose rates, a single arrangement of the additional concrete shields necessary for reduction of the gamma dose rates to the permitted level is proposed. The proposed solution is optimal considering safety on one hand and costs on the other.(author)

  20. Leach test of six 192-iridium pellets based on the IAEA 'special form' test procedures

    International Nuclear Information System (INIS)

    Gordon, G.; Gerdingh, R.

    1981-07-01

    The designation 'special form' may be applied to indispersible solid radioactive material if the material meets the requirements of the tests described in the International Atomic Energy Agency Regulations for the Safe Transport of Radioactive Type Materials. This report presents the procedures and results of a leach test performed as specified in the regulations on 6 'as received' active 192-iridium pellets. Mechanical tests were not carried out prior to or following the leach test. The activity of each of the first 6 water baths was found to be between 2.3 and 12.6 μCi, (8.5 x 10 4 and 4.7 x 10 5 Bq) and of the second 6, between 1.3 to 6.0 μCi, (4.8 x 10 4 to 2.2 x 10 5 Bq) thus exceeding the allowable limit

  1. Enantiopure Ferrocene-Based Planar-Chiral Iridacycles: Stereospecific Control of Iridium-Centred Chirality.

    Science.gov (United States)

    Arthurs, Ross A; Ismail, Muhammad; Prior, Christopher C; Oganesyan, Vasily S; Horton, Peter N; Coles, Simon J; Richards, Christopher J

    2016-02-24

    Reaction of [IrCp*Cl2 ]2 with ferrocenylimines (Fc=NAr, Ar=Ph, p-MeOC6 H4 ) results in ferrocene C-H activation and the diastereoselective synthesis of half-sandwich iridacycles of relative configuration Sp *,RIr *. Extension to (S)-2-ferrocenyl-4-(1-methylethyl)oxazoline gave highly diastereoselective control over the new elements of planar chirality and metal-based pseudo-tetrahedral chirality, to give both neutral and cationic half-sandwich iridacycles of absolute configuration Sc ,Sp ,RIr . Substitution reactions proceed with retention of configuration, with the planar chirality controlling the metal-centred chirality through an iron-iridium interaction in the coordinatively unsaturated cationic intermediate. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  2. Transpapillary iridium-192 wire in the treatment of malignant bile duct obstruction

    International Nuclear Information System (INIS)

    Levitt, M.D.; Laurence, B.H.; Cameron, F.; Klemp, P.F.B.

    1988-01-01

    Twenty four patients with malignant bile duct obstruction were treated with intraluminal radiotherapy using iridium-192 wire inserted through an endoscopically placed nasobiliary catheter. Biliary drainage after treatment was maintained by an endoprosthesis. The median dose of intraluminal radiotherapy was 6000 cGy; two patients with cholangiocarcinoma were given a second course because of disease extension; four patients with pancreatic carcinoma received additional external irradiation (3000 cGy). There was one early death from a cerebrovascular accident (30 day mortality, 4.2%). Cholangitis (30%) was the major early complication and stent blockage (40%) the major late complication; there were no complications directly attributable to radiotherapy. The median survival for patients with pancreatic carcinoma was 250 days and for cholangiocarcinoma, 300 days. This method is technically feasible and may prove safer than the transhepatic technique. The ability of intraluminal irradiation to improve palliation or lengthen survival in patients with malignant bile duct obstruction remains uncertain. (author)

  3. Development and application of an iridium tracer for tracking tailings in the central Red Sea

    International Nuclear Information System (INIS)

    Schnier, C.; Fanger, H.U.

    1983-01-01

    In order to investigate the distribution of disposed tailings, the element iridium was applied as a tracer during the prepilot mining test in the Red Sea 1979. In the sediment matrix, Ir can be detected in quantities as small as 25 x 10 -12 g by means of neutron activation analysis. The tracer was obtained by melting down a mixture of 50 kg quartz and 1 kg IrO 2 , then grinding and pulverizing the material to an appropriate grain size distribution. An amount of 480 m 3 tracer-added tailings was disposed in a depth of 400 m close to the Atlantis II deep. Subsequently, in the period 1 month to 2 1/2 years later, 32 sediment samples were taken from the deposition area and analysed for Ir. The Ir concentration observed were surprisingly low and give only vague indications of the spreading of the tailings. (orig.) [de

  4. Catalytic dehydroaromatization of n-alkanes by pincer-ligated iridium complexes

    Science.gov (United States)

    Ahuja, Ritu; Punji, Benudhar; Findlater, Michael; Supplee, Carolyn; Schinski, William; Brookhart, Maurice; Goldman, Alan S.

    2011-02-01

    Aromatic hydrocarbons are among the most important building blocks in the chemical industry. Benzene, toluene and xylenes are obtained from the high temperature thermolysis of alkanes. Higher alkylaromatics are generally derived from arene-olefin coupling, which gives branched products—that is, secondary alkyl arenes—with olefins higher than ethylene. The dehydrogenation of acyclic alkanes to give alkylaromatics can be achieved using heterogeneous catalysts at high temperatures, but with low yields and low selectivity. We present here the first catalytic conversion of n-alkanes to alkylaromatics using homogeneous or molecular catalysts—specifically ‘pincer’-ligated iridium complexes—and olefinic hydrogen acceptors. For example, the reaction of n-octane affords up to 86% yield of aromatic product, primarily o-xylene and secondarily ethylbenzene. In the case of n-decane and n-dodecane, the resulting alkylarenes are exclusively unbranched (that is, n-alkyl-substituted), with selectivity for the corresponding o-(n-alkyl)toluene.

  5. Iridium-191m radionuclide angiocardiography detection and quantitation of left-to-rigth shunts

    International Nuclear Information System (INIS)

    Treves, S.; Fujii, A.; Cheng, C.; Kuruc, A.

    1983-01-01

    The purpose of this study was to determine whether Iridium-191m (Ir-191m) could replace Technetium-99m (Tc-99m) in the detection and quantitation of left-to-right shunts. It was demonstrated that Ir-191m radionuclide angiography is a safe, rapid, and accurate method for the detection and quantitation of left-to-right shunts with very low radiation dose to the patient. It is also possible with this radiotracer to evaluate other aspects of the anatomy and physiology of the circulation such as ventricular function, patency of major vessels, renal and cerebral perfusion. Further improvements on 0s-191 production, generator design and gamma cameras would expand the use of this ultrashort-lived radionuclide

  6. Neutron activation determination of iridium, gold, platinum, and silver in geologic samples

    International Nuclear Information System (INIS)

    Millard, H.T. Jr.

    1987-01-01

    In the procedure developed in this study, samples irradiated in the epithermal neutron facility of the U.S. Geological Survey TRIGA Reactor (Denver, Colorado) are treated with a mini-free assay technique. The iridium, gold, and silver are collected in a 1-gram metallic lead button. Primary contaminants at this stage are arsenic and antimony. These can be removed by heating the button with a mixture of sodium peroxide and sodium hydroxide. The resulting 0.2-gram lead bead is counted in a Compton suppression spectrometer. Carrier yields are determined by reirradiation of the lead beads. This procedure was applied to the U.S.G.S. Standard Rock PCC-1 and samples from K-T boundary sites in the Western Interior of North America. (author)

  7. Transpapillary iridium-192 wire in the treatment of malignant bile duct obstruction

    Energy Technology Data Exchange (ETDEWEB)

    Levitt, M D; Laurence, B H; Cameron, F; Klemp, P F.B.

    1988-02-01

    Twenty four patients with malignant bile duct obstruction were treated with intraluminal radiotherapy using iridium-192 wire inserted through an endoscopically placed nasobiliary catheter. Biliary drainage after treatment was maintained by an endoprosthesis. The median dose of intraluminal radiotherapy was 6000 cGy; two patients with cholangiocarcinoma were given a second course because of disease extension; four patients with pancreatic carcinoma received additional external irradiation (3000 cGy). There was one early death from a cerebrovascular accident (30 day mortality, 4.2%). Cholangitis (30%) was the major early complication and stent blockage (40%) the major late complication; there were no complications directly attributable to radiotherapy. The median survival for patients with pancreatic carcinoma was 250 days and for cholangiocarcinoma, 300 days. This method is technically feasible and may prove safer than the transhepatic technique. The ability of intraluminal irradiation to improve palliation or lengthen survival in patients with malignant bile duct obstruction remains uncertain.

  8. Intra-operative placement of catheters for interstitial microwave-induced hyperthermia and iridium brachytherapy

    International Nuclear Information System (INIS)

    Coughlin, C.T.; Wong, T.Z.; Strohbehn, J.W.; Colacchio, T.A.; Belch, R.Z.; Sutton, J.E. Jr.; Douple, E.B.

    1984-01-01

    The authors have previously described a system for delivery of microwave-induced hyperthermia utilizing flexible coaxial cables that are modified to serve as microwave antennas. These small (--1.6mm o.d.) antennas ae introduced into 2mm o.d. nylon catheters implanted in the tumor. This system has been further modified for use in the treatment of surgically unresectible abdominal, pelvic, and head and neck tumors. The modifications are described that were used to treat two pelvic, one upper abdominal, and one base of tongue tumor. The nylon catheters are implanted during surgery. After a short recovery period, the microwave antennas are inserted and the tumor region is heated for --1hr. The antennas are removed, iridium-192 seeds are placed in the catheters, 2800 - 5000 rad (CGy) doses are delivered, followed by a 1hr hyperthermia treatment. The temperature distributions and future applications are discussed

  9. Cyclometalated Iridium(III) Carbene Phosphors for Highly Efficient Blue Organic Light-Emitting Diodes.

    Science.gov (United States)

    Chen, Zhao; Wang, Liqi; Su, Sikai; Zheng, Xingyu; Zhu, Nianyong; Ho, Cheuk-Lam; Chen, Shuming; Wong, Wai-Yeung

    2017-11-22

    Five deep blue carbene-based iridium(III) phosphors were synthesized and characterized. Interestingly, one of them can be fabricated into deep blue, sky blue and white organic light-emitting diodes (OLEDs) through changing the host materials and exciton blocking layers. These deep and sky blue devices exhibit Commission Internationale de l'Éclairage (CIE) coordinates of (0.145, 0.186) and (0.152, 0.277) with external quantum efficiency (EQE) of 15.2% and 9.6%, respectively. The EQE of the deep blue device can be further improved up to 19.0% by choosing a host with suitable energy level of its lowest unoccupied molecular orbital (LUMO).

  10. Trends in communications satellites

    CERN Document Server

    Curtin, Denis J

    1979-01-01

    Trends in Communications Satellites offers a comprehensive look at trends and advances in satellite communications, including experimental ones such as NASA satellites and those jointly developed by France and Germany. The economic aspects of communications satellites are also examined. This book consists of 16 chapters and begins with a discussion on the fundamentals of electrical communications and their application to space communications, including spacecraft, earth stations, and orbit and wavelength utilization. The next section demonstrates how successful commercial satellite communicati

  11. Method of making a long life high current density cathode from tungsten and iridium powders using a quaternary compound as the impregnant

    International Nuclear Information System (INIS)

    Branovich, L.E.; Smith, B.; Freemen, G.L.; Eckart, D.W.

    1990-01-01

    This patent describes a method of making a long life high current density cathode. It is suitable for operation in microwave devices. It is made from tungsten and iridium powders using a quaternary compound including barium, oxygen, a metal selected from the group consisting of osmium, iridium, rhodium, and rhenium, and a metal selected from the group consisting of strontium, calcium, scandium, and titanium as the impregnant

  12. Sol-Gel Deposition of Iridium Oxide for Biomedical Micro-Devices

    Directory of Open Access Journals (Sweden)

    Cuong M. Nguyen

    2015-02-01

    Full Text Available Flexible iridium oxide (IrOx-based micro-electrodes were fabricated on flexible polyimide substrates using a sol-gel deposition process for utilization as integrated pseudo-reference electrodes for bio-electrochemical sensing applications. The fabrication method yields reliable miniature on-probe IrOx electrodes with long lifetime, high stability and repeatability. Such sensors can be used for long-term measurements. Various dimensions of sol-gel iridium oxide electrodes including 1 mm × 1 mm, 500 µm × 500 µm, and 100 µm × 100 µm were fabricated. Sensor longevity and pH dependence were investigated by immersing the electrodes in hydrochloric acid, fetal bovine serum (FBS, and sodium hydroxide solutions for 30 days. Less pH dependent responses, compared to IrOx electrodes fabricated by electrochemical deposition processes, were measured at 58.8 ± 0.4 mV/pH, 53.8 ± 1.3 mV/pH and 48 ± 0.6 mV/pH, respectively. The on-probe IrOx pseudo-reference electrodes were utilized for dopamine sensing. The baseline responses of the sensors were higher than the one using an external Ag/AgCl reference electrode. Using IrOx reference electrodes integrated on the same probe with working electrodes eliminated the use of cytotoxic Ag/AgCl reference electrode without loss in sensitivity. This enables employing such sensors in long-term recording of concentrations of neurotransmitters in central nervous systems of animals and humans.

  13. Influence of oxidation state on the pH dependence of hydrous iridium oxide films

    International Nuclear Information System (INIS)

    Steegstra, Patrick; Ahlberg, Elisabet

    2012-01-01

    Many electrochemical reactions taking place in aqueous solution consume or produce protons. The pH in the diffusion layer can therefore be significantly altered during the reaction and there is a need for in situ pH measurements tracing this near surface pH. In the present paper the rotating ring disc technique was used to measure near surface pH changes during oxygen reduction, utilising hydrous iridium oxide as the pH sensing probe. Before such experiments a good understanding of the pH sensing properties of these films is required and the impact of the oxidation state of the film on the pH sensing properties was investigated as well as the influence of solution redox species. The pH sensitivity (depicted by dE/dpH) was found to depend on the average oxidation state of the film in a manner resembling the cyclic voltammetry response. In all cases the pH response is “supernernstian” with more than one proton per electron. The origin of this behaviour is discussed in the context of acid-base properties of the film and the existence of both hydrous and anhydrous oxide phases. The pH response depends also on the redox properties of the solution but can be optimised for various purposes by conditioning the film at different potentials. This was clearly illustrated by adding hydrogen peroxide, an intermediate in the oxygen reduction reaction, to the solution. It was shown that hydrous iridium oxide can be used as a reliable in situ pH sensor provided that care is taken to optimise the oxidation state of the film.

  14. Sol-Gel Deposition of Iridium Oxide for Biomedical Micro-Devices

    Science.gov (United States)

    Nguyen, Cuong M.; Rao, Smitha; Yang, Xuesong; Dubey, Souvik; Mays, Jeffrey; Cao, Hung; Chiao, Jung-Chih

    2015-01-01

    Flexible iridium oxide (IrOx)-based micro-electrodes were fabricated on flexible polyimide substrates using a sol-gel deposition process for utilization as integrated pseudo-reference electrodes for bio-electrochemical sensing applications. The fabrication method yields reliable miniature on-probe IrOx electrodes with long lifetime, high stability and repeatability. Such sensors can be used for long-term measurements. Various dimensions of sol-gel iridium oxide electrodes including 1 mm × 1 mm, 500 μm × 500 μm, and 100 μm × 100 μm were fabricated. Sensor longevity and pH dependence were investigated by immersing the electrodes in hydrochloric acid, fetal bovine serum (FBS), and sodium hydroxide solutions for 30 days. Less pH dependent responses, compared to IrOx electrodes fabricated by electrochemical deposition processes, were measured at 58.8 ± 0.4 mV/pH, 53.8 ± 1.3 mV/pH and 48 ± 0.6 mV/pH, respectively. The on-probe IrOx pseudo-reference electrodes were utilized for dopamine sensing. The baseline responses of the sensors were higher than the one using an external Ag/AgCl reference electrode. Using IrOx reference electrodes integrated on the same probe with working electrodes eliminated the use of cytotoxic Ag/AgCl reference electrode without loss in sensitivity. This enables employing such sensors in long-term recording of concentrations of neurotransmitters in central nervous systems of animals and humans. PMID:25686309

  15. Bibliographies on radiation chemistry. 9. Metal ions and complexes. Part A: Cobalt, rhodium, iridium

    Energy Technology Data Exchange (ETDEWEB)

    Hoffman, M Z; Ross, A B

    1986-01-01

    The one-electron oxidation and reduction of metal ions and complexes can yield species in unusual oxidation states, and ligand-radicals coordinated to the central metal. These often unstable species can be mechanistically important intermediates in thermal, photochemical, and electrochemical reactions involving metal-containing substances. Their generation via radiolysis provides an alternate means of characterizing them using kinetic and spectroscopic techniques. We hope these bibliographies on the radiation chemistry of metal ions and complexes, presented according to periodic groups, will prove useful to researchers in metallo-redox chemistry. These bibliographies contain only primary literature sources; reviews are not included. However, a list of general review articles on the radiation chemistry of metal ions and complexes is presented here in the first section which covers cobalt, rhodium and iridium, Group 9 in the new IUPAC notation. Additional parts of the bibliography are planned, covering other periodic groups. Part A of the bibliography was prepared by a search of the Radiation Chemistry Data Center Bibliographic Data Base (RCDCbib) through January 1986 for papers on rhodium, iridium and cobalt compounds, and radiolysis (both continuous and pulsed). Papers in which the use of metal compounds was incidental to the primary objective of the study were excluded. Excluded also were publications in unrefereed and obscure sources such as meeting proceedings, internal reports, dissertations, and patents. The majority of the studies in the resultant compilation deal with experiments performed on solutions, mainly aqueous, although a substantial fraction is devoted to solid-state esr measurements. The references are listed in separate sections for each of the metals, and are presented in approximate chronological order.

  16. Wave Activity (Planetary, Tidal) throughout the Middle Atmoshere (25-100 km) over the CUJO Network: Satellite and Medium Frequency (MF) Radar Observations

    Science.gov (United States)

    Manson, A.; Meek, C.; Chshyolkova, T.; Avery, S.; Thorsen, D.; MacDougall, J.; Hocking, W.; Murayama, Y.; Igarashi, K.

    Planetary and tidal wave activity in the mesosphere-lower thermosphere (MLT), and assessment of wave activity sources in the lower atmosphere, are studied using combinations of ground based (GB) and satellite instruments (2000-2002). CUJO (Canada U.S. Japan Opportunity) comprises MF radar (MFR) systems at London (43°N, 81°W), Platteville (40°N, 105°W), Saskatoon (52°N, 107°W), Wakkanai (45°N, 142°E) and Yamagawa (31°N, 131°E). It offers a significant mid-latitude 7,000 km longitudinal sector in the North American-Pacific region, and a useful range of latitudes (12-14°) at two longitudes. CUJO provides winds and tides 70-100km. Satellite data include the daily values of the total ozone column measured by the Earth Probe (EP) TOMS (Total Ozone Mapping Spectrometer) and provides a measure of tropopause-lower stratospheric planetary wave activity as well as ozone variability. The so-called UKMO data (an assimilation system) are used for correlative purposes with the TOMS data. Climatologies of ozone and winds/tides involving frequency versus time (wavelet) contour plots for periods from 2-d to 30-d and the interval from mid 2000 to 2002, show that the changes with altitude, longitude and latitude are very significant and distinctive. Geometric-mean wavelets for the region of the 40°N MFRs demonstrate occasions during the autumn, winter and spring months when there are similarities in the spectral features of the lower atmosphere and at mesopause (85km) heights. Both direct planetary wave (PW) propagation into the MLT, non-linear PW-tide interactions, and disturbances in MLT tides associated with fluctuations in the ozone forcing are considered to be possible coupling processes. The complex horizontal wave numbers of the longer period oscillations are provided in frequency contour plots for the TOMS and UKMO data to demonstrate the differences between lower atmospheric and MLT wave motions and their directions of propagation.

  17. Cross section of α-induced reactions on iridium isotopes obtained from thick target yield measurement for the astrophysical γ process

    Directory of Open Access Journals (Sweden)

    T. Szücs

    2018-01-01

    Full Text Available The stellar reaction rates of radiative α-capture reactions on heavy isotopes are of crucial importance for the γ process network calculations. These rates are usually derived from statistical model calculations, which need to be validated, but the experimental database is very scarce. This paper presents the results of α-induced reaction cross section measurements on iridium isotopes carried out at first close to the astrophysically relevant energy region. Thick target yields of 191Ir(α,γ195Au, 191Ir(α,n194Au, 193Ir(α,n196mAu, 193Ir(α,n196Au reactions have been measured with the activation technique between Eα=13.4 MeV and 17 MeV. For the first time the thick target yield was determined with X-ray counting. This led to a previously unprecedented sensitivity. From the measured thick target yields, reaction cross sections are derived and compared with statistical model calculations. The recently suggested energy-dependent modification of the α+nucleus optical potential gives a good description of the experimental data.

  18. Satellite switched FDMA advanced communication technology satellite program

    Science.gov (United States)

    Atwood, S.; Higton, G. H.; Wood, K.; Kline, A.; Furiga, A.; Rausch, M.; Jan, Y.

    1982-01-01

    The satellite switched frequency division multiple access system provided a detailed system architecture that supports a point to point communication system for long haul voice, video and data traffic between small Earth terminals at Ka band frequencies at 30/20 GHz. A detailed system design is presented for the space segment, small terminal/trunking segment at network control segment for domestic traffic model A or B, each totaling 3.8 Gb/s of small terminal traffic and 6.2 Gb/s trunk traffic. The small terminal traffic (3.8 Gb/s) is emphasized, for the satellite router portion of the system design, which is a composite of thousands of Earth stations with digital traffic ranging from a single 32 Kb/s CVSD voice channel to thousands of channels containing voice, video and data with a data rate as high as 33 Mb/s. The system design concept presented, effectively optimizes a unique frequency and channelization plan for both traffic models A and B with minimum reorganization of the satellite payload transponder subsystem hardware design. The unique zoning concept allows multiple beam antennas while maximizing multiple carrier frequency reuse. Detailed hardware design estimates for an FDMA router (part of the satellite transponder subsystem) indicate a weight and dc power budget of 353 lbs, 195 watts for traffic model A and 498 lbs, 244 watts for traffic model B.

  19. Network topology analysis.

    Energy Technology Data Exchange (ETDEWEB)

    Kalb, Jeffrey L.; Lee, David S.

    2008-01-01

    Emerging high-bandwidth, low-latency network technology has made network-based architectures both feasible and potentially desirable for use in satellite payload architectures. The selection of network topology is a critical component when developing these multi-node or multi-point architectures. This study examines network topologies and their effect on overall network performance. Numerous topologies were reviewed against a number of performance, reliability, and cost metrics. This document identifies a handful of good network topologies for satellite applications and the metrics used to justify them as such. Since often multiple topologies will meet the requirements of the satellite payload architecture under development, the choice of network topology is not easy, and in the end the choice of topology is influenced by both the design characteristics and requirements of the overall system and the experience of the developer.

  20. IMPLEMENTATION OF AERONAUTICAL LOCAL SATELLITE AUGMENTATION SYSTEM

    Directory of Open Access Journals (Sweden)

    Stojce Ilcev

    2011-03-01

    Full Text Available Abstract. This paper introduces development and implementation of new Local Satellite AugmentationSystem as an integration component of the Regional Satellite Augmentation System (RSAS employingcurrent and new Satellite Communications, Navigation and Surveillance (CNS for improvement of the AirTraffic Control (ATC and Air Traffic Management (ATM and for enhancement safety systems includingtransport security and control of flights in all stages, airport approaching, landing, departures and allmovements over airport surface areas. The current first generation of the Global Navigation Satellite SystemGNSS-1 applications are represented by fundamental military solutions for Position, Velocity and Time ofthe satellite navigation and determination systems such as the US GPS and Russian GLONASS (Former-USSR requirements, respectively. The establishment of Aeronautical CNS is also discussed as a part ofGlobal Satellite Augmentation Systems of GPS and GLONASS systems integrated with existing and futureRSAS and LSAS in airports areas. Specific influence and factors related to the Comparison of the Currentand New Aeronautical CNS System including the Integration of RSAS and GNSS solutions are discussedand packet of facts is determined to maximize the new satellite Automatic Dependent Surveillance System(ADSS and Special Effects of the RSAS Networks. The possible future integration of RSAS and GNSS andthe common proposal of the satellite Surface Movement Guidance and Control are presented in thechangeless ways as of importance for future enfacements of ATC and ATM for any hypothetical airportinfrastructure.Keywords: ADSS, ATC, ATM, CNS, GSAS, LRAS, RSAS, SMGC, Special Effects of RSAS.

  1. SOVCAN STAR: An international satellite system

    Science.gov (United States)

    Skatchkov, Valery A.

    SOVCAN STAR is a Russian-Canadian cooperative venture company formed to manufacture, test, launch and operate a Ku-band satellite system. Drawing on the more than twenty years communications satellite experience of the founding companies, the SOVCAN STAR satellites are being designed to be competitive and cost effective. They will be equipped with 24 transponders and four steerable antennas. The design allows the operators to switch individual transponders between the various antenna coverage beams. These satellites will offer a high degree of operational flexibility and performance. The SOVCAN STAR strategy is to develop a network of satellites in parallel with the growth and evolution of the traffic requirements. Such an approach minimizes the technical, schedule and program risks while at the same time significantly reduces the financial exposure. The first SOVCAN STAR satellite will be commissioned in 1996 and operated at 14 deg W. The beams will be aligned to North America and Europe offering International service between Canada, the Eastern U.S.A., Europe, Russia and the Western C.I.S. Republics. The second SOVCAN STAR satellite will be commissioned a year later and operated at 145 deg E. This satellite will cover the Western Pacific Ocean, Eastern Asia and Australasia.

  2. Network speech systems technology program

    Science.gov (United States)

    Weinstein, C. J.

    1981-09-01

    This report documents work performed during FY 1981 on the DCA-sponsored Network Speech Systems Technology Program. The two areas of work reported are: (1) communication system studies in support of the evolving Defense Switched Network (DSN) and (2) design and implementation of satellite/terrestrial interfaces for the Experimental Integrated Switched Network (EISN). The system studies focus on the development and evaluation of economical and endurable network routing procedures. Satellite/terrestrial interface development includes circuit-switched and packet-switched connections to the experimental wideband satellite network. Efforts in planning and coordination of EISN experiments are reported in detail in a separate EISN Experiment Plan.

  3. Satellite image collection optimization

    Science.gov (United States)

    Martin, William

    2002-09-01

    Imaging satellite systems represent a high capital cost. Optimizing the collection of images is critical for both satisfying customer orders and building a sustainable satellite operations business. We describe the functions of an operational, multivariable, time dynamic optimization system that maximizes the daily collection of satellite images. A graphical user interface allows the operator to quickly see the results of what if adjustments to an image collection plan. Used for both long range planning and daily collection scheduling of Space Imaging's IKONOS satellite, the satellite control and tasking (SCT) software allows collection commands to be altered up to 10 min before upload to the satellite.

  4. Synthesis and optoelectronic properties of oxadiazole-functionalized iridium complexes in the poly(vinylcarbazole)-hosted devices

    International Nuclear Information System (INIS)

    Wu Zhonglian; Luo Cuiping; Jiang Changyun; Zhu Meixiang; Cao, Yong; Zhu Weiguo

    2008-01-01

    A class of oxadiazole-functionalized iridium complexes was used as phosphor emitters in poly (vinylcarbazole)-hosted devices. Efficient green electrophosphorescences were achieved in the devices with a maximum luminance efficiency of 9.3 cd/A at 10.6 mA/cm 2 and brightness of 3882 cd/m 2 at 92.1 mA/cm 2 . More importantly, the iridium complexes-doped devices exhibited a low turn-on voltage of 7.0 V and an applied voltage of 9.2 V at 500 cd/m 2 . The good optoelectronic properties of the complexes were attributed to the enhanced electron-injection and transport properties resulting from the effect of oxadiazole ligands in the complexes

  5. Synthesis and crystal structure of the iridium(I) carbene complex with a pair of hydrogen wing tips

    Energy Technology Data Exchange (ETDEWEB)

    Huang, H.-Y.; Chen, Z.-M.; Wang, Y.; Wu, E.-M.; Wang, G. [Jiangsu Institute of Nuclear Medicine, Ministry of Health, Key Laboratory of Molecular Nuclear Medicine (China); Jiang, M.-J., E-mail: jmj16888@126.com [Nanjing Medical University, Affiliated Wuxi Peoples Hospital, Wuxi Institute of Translational Medicine, Department of Clinical Laboratory Science (China)

    2016-12-15

    The iridium(I) cyclooctadiene complex with two (3-tert-butylimidazol-2-ylidene) ligands [(H-Im{sup t}Bu){sub 2}Ir(COD)]{sup +}PF{sub 6}{sup −} (C{sub 22}H{sub 32}PF{sub 6}IrN{sub 4}) has been prepared, and its crystal structure is determined by X-ray diffraction. Complex exhibits slightly distorted square planar configurations around the metal atom, which is coordinated by two H-Im{sup t}Bu ligands and one cyclooctadiene group. The new iridium carbene complex has a pair of hydrogen wing tips. The Ir−C{sub carbene} bond lengths are 2.066(5) and 2.052(5) Å, and the bond angle C−Ir−C between these bonds is 95.54(19)°. The dihedral angle between two imidazol-2-ylidene rings is 86.42°.

  6. Iridium anomaly in the cretaceous-paleogene boundary at Højerup (Stevns Klint, Denmark and Woodside Creek (New Zealand: The question of an enormous proportion of extraterrestrial component

    Directory of Open Access Journals (Sweden)

    Premović Pavle I.

    2012-01-01

    Full Text Available The Cretaceous-Paleogene boundary clays at Højerup and Woodside Creek show anomalous enrichments of iridium compared with the marine sedimentary rocks. For the average iridium content of 465 ppb in CI chondrite the estimate of the carbonaceous chondritic proportions in the decarbonated iridium-rich boundary layers, based on the integrated iridium fluencies, is about 26% at Højerup and 65% at Woodside Creek. These proportions are most likely too high due to a significant Ir influx from the nearby marine or continental site to these sections.

  7. 3,9-Dithia-6-azaundecane-appended Iridium (III) Complex for the Selective Detection of Hg2+ in Aqueous Acetonitrile

    International Nuclear Information System (INIS)

    Ann, Jee Hye; Li, Yinan; Hyun, Myung Ho

    2012-01-01

    Detection of mercuric ion (Hg 2+ ) originated from natural or industrial sources is very important because it is extremely toxic even at low levels and causes serious environmental and health problems. Consequently, many efforts have been devoted to the development of sensitive chemosensors for the detection of Hg 2+ . For example, various fluorescent chemosensors based on rhodamine, nitrobenzoxadiazole, fluorescein, boradiazaindacene (BODIPY), dansyl, pyrene, or other fluorophores have been developed for the selective detection of Hg 2+ . While various fluorescent chemosensors for the selective detection of Hg 2+ have been developed, phosphorescent chemosensors for the selective detection of Hg 2+ are relatively rare. Among various phosphors, iridium (III) complexes with sulfur containing cyclometalated ligands have been used as phosphorescent chemosensors for the selective detection of Hg 2+ . Azacrown ether-appended iridium (III) complex developed in our laboratory has also been utilized as a phosphorescent chemosensor for the selective detection of Hg 2+ . As an another iridium (III) complex-based phosphorescent chemosensors for the selective detection of Hg 2+ , in this study, we wish to prepare iridium (III) complex containing two 3,9-dithia-6-azaundecane units as chelating ligands for metal ions. Some fluorophores containing 3,9-dithia-6-azaundecane unit have been successfully applied for the selective detection of Hg 2+ . In this instance, iridium (III) complex containing two 3,9-dithia-6-azaundecane units is expected to be useful as a phosphorescent chemosensor for the selective detection of Hg 2+ . Iridium (III) complex containing two 3,9-dithia-6-azaundecane units was prepared starting from 2-phenylpyridine according to the procedure shown in Scheme 1. 2-Phenylpyridine was transformed into chloride bridged dimeric iridium complex, [(ppy) 2 IrCl] 2 , via the reported procedure. By treating [(ppy) 2 IrCl] 2 with 4,4'-bis(bromomethyl)-2,2'-bipyridine, which

  8. 3,9-Dithia-6-azaundecane-appended Iridium (III) Complex for the Selective Detection of Hg{sup 2+} in Aqueous Acetonitrile

    Energy Technology Data Exchange (ETDEWEB)

    Ann, Jee Hye; Li, Yinan; Hyun, Myung Ho [Pusan National Univ., Busan (Korea, Republic of)

    2012-10-15

    Detection of mercuric ion (Hg{sup 2+}) originated from natural or industrial sources is very important because it is extremely toxic even at low levels and causes serious environmental and health problems. Consequently, many efforts have been devoted to the development of sensitive chemosensors for the detection of Hg{sup 2+}. For example, various fluorescent chemosensors based on rhodamine, nitrobenzoxadiazole, fluorescein, boradiazaindacene (BODIPY), dansyl, pyrene, or other fluorophores have been developed for the selective detection of Hg{sup 2+}. While various fluorescent chemosensors for the selective detection of Hg{sup 2+} have been developed, phosphorescent chemosensors for the selective detection of Hg{sup 2+} are relatively rare. Among various phosphors, iridium (III) complexes with sulfur containing cyclometalated ligands have been used as phosphorescent chemosensors for the selective detection of Hg{sup 2+}. Azacrown ether-appended iridium (III) complex developed in our laboratory has also been utilized as a phosphorescent chemosensor for the selective detection of Hg{sup 2+}. As an another iridium (III) complex-based phosphorescent chemosensors for the selective detection of Hg{sup 2+}, in this study, we wish to prepare iridium (III) complex containing two 3,9-dithia-6-azaundecane units as chelating ligands for metal ions. Some fluorophores containing 3,9-dithia-6-azaundecane unit have been successfully applied for the selective detection of Hg{sup 2+}. In this instance, iridium (III) complex containing two 3,9-dithia-6-azaundecane units is expected to be useful as a phosphorescent chemosensor for the selective detection of Hg{sup 2+}. Iridium (III) complex containing two 3,9-dithia-6-azaundecane units was prepared starting from 2-phenylpyridine according to the procedure shown in Scheme 1. 2-Phenylpyridine was transformed into chloride bridged dimeric iridium complex, [(ppy){sub 2}IrCl]{sub 2}, via the reported procedure. By treating [(ppy){sub 2}Ir

  9. Determination of iridium at low levels (sub ng g-1) in geological materials by neutron activation analysis

    International Nuclear Information System (INIS)

    Morcelli, Claudia Petronilho Ribeiro

    1999-01-01

    The analysis of the platinum group elements (PGE: Ru, Rh, Pd, Os, Ir and Pt) in geological materials is difficult, due to the low concentrations of these elements (ng g -1 or sub ng g -1 ) and their heterogeneous distribution in many geological matrices. The determination of PGE has attracted great interest due not only to the increasing utilization of these elements in modern industry, but also to the information that these elements can provide on mantle processes. The determination of very low amounts of iridium is particularly important on account of some anomalous concentrations of iridium in sedimentary rock samples, related to the impact of an extraterrestrial object responsible for extinctions at the Cretaceous-Tertiary (K-T) boundary. In the present paper, a radiochemical neutron activation method for the determination of iridium in geological materials is presented. The procedure consisted of thermal neutron irradiation of about 500 mg of the sample, followed by sintering with sodium peroxide, precipitation with tellurium and high resolution gamma-ray spectrometry with a hyper-pure Ge detector. The accuracy and precision of the procedure were evaluated by analysis of the certified reference material SARM-7 (South Africa Bureau of Standards) and W-1 (USGS). The detection limit for the analytical conditions employed was 0.004 ng g -1 . The procedure was applied to the reference materials TDB-1 and WGB-1 (CANMET), which present provisional values for Ir, and to the reference materials GXR-3, GXR-5 and GXR- 6 (USGS), which do not present information values for Ir. This work is a contribution to Ir values in these reference materials. As an example of application of the method to real samples, the developed procedure was employed in the determination of iridium in basalts from Parana basin, collected in Bom Guara do Sul, Santa Catarina, provided by the Geosciences Institute of the University of Campinas. (author)

  10. Diastereo- and enantioselective iridium-catalyzed allylation of cyclic ketone enolates: synergetic effect of ligands and barium enolates.

    Science.gov (United States)

    Chen, Wenyong; Chen, Ming; Hartwig, John F

    2014-11-12

    We report asymmetric allylic alkylation of barium enolates of cyclic ketones catalyzed by a metallacyclic iridium complex containing a phosphoramidite ligand derived from (R)-1-(2-naphthyl)ethylamine. The reaction products contain adjacent quaternary and tertiary stereocenters. This process demonstrates that unstabilized cyclic ketone enolates can undergo diastereo- and enantioselective Ir-catalyzed allylic substitution reactions with the proper choice of enolate countercation. The products of these reactions can be conveniently transformed to various useful polycarbocyclic structures.

  11. Iridium-coated micropore x-ray optics using dry etching of a silicon wafer and atomic layer deposition.

    Science.gov (United States)

    Ogawa, Tomohiro; Ezoe, Yuichiro; Moriyama, Teppei; Mitsuishi, Ikuyuki; Kakiuchi, Takuya; Ohashi, Takaya; Mitsuda, Kazuhisa; Putkonen, Matti

    2013-08-20

    To enhance x-ray reflectivity of silicon micropore optics using dry etching of silicon (111) wafers, iridium coating is tested by use of atomic layer deposition. An iridium layer is successfully formed on sidewalls of tiny micropores with a pore width of 20 μm and depth of 300 μm. The film thickness is ∼20  nm. An enhanced x-ray reflectivity compared to that of silicon is confirmed at Ti Kα 4.51 keV, for what we believe to be the first time, with this type of optics. Some discrepancies from a theoretical reflectivity curve of iridium-coated silicon are noticed at small incident angles <1.3°. When a geometrical shadowing effect due to occultation by a ridge existing on the sidewalls is taken into account, the observed reflectivity becomes well represented by the modified theoretical curve. An estimated surface micro roughness of ∼1  nm rms is consistent with atomic force microscope measurements of the sidewalls.

  12. Structural characterization and comparison of iridium, platinum and gold/palladium ultra-thin film coatings for STM of biomolecules

    Energy Technology Data Exchange (ETDEWEB)

    Sebring, R.; Arendt, P.; Imai, B.; Bradbury, E.M.; Gatewood, J. [Los Alamos National Lab., NM (United States); Panitz, J. [Univ. of New Mexico, Albuquerque, NM (United States). Dept. of Physics and Astronomy; Yau, P. [Univ. of California, Davis, CA (United States)

    1997-10-30

    Scanning tunneling microscopy (STM) is capable of atomic resolution and is ideally suited for imaging surfaces with uniform work function. A biological sample on a conducting substrate in air does not meet this criteria and requires a conductive coating for stable and reproducible STM imaging. In this paper, the authors describe the STM and transmission electron microscopy (TEM) characterization of ultra-thin ion-beam sputtered films of iridium and cathode sputtered gold/palladium and platinum films on highly ordered pyrolytic graphite (HOPG) which were developed for use as biomolecule coatings. The goals were the development of metal coatings sufficiently thin and fine grained that 15--20 {angstrom} features of biological molecules could be resolved using STM, and the development of a substrate/coating system which would allow complementary TEM information to be obtained for films and biological molecules. The authors demonstrate in this paper that ion-beam sputtered iridium on highly ordered pyrolytic graphite (HOPG) has met both these goals. The ion-beam sputtered iridium produced a very fine grained (< 10 {angstrom}) continuous film at 5--6 {angstrom} thickness suitable for stable air STM imaging. In comparison, cathode sputtered platinum produced 16 {angstrom} grains with the thinnest continuous film at 15 {angstrom} thickness, and the sputtered gold/palladium produced 25 {angstrom} grains with the thinnest continuous film at 18 {angstrom} thickness.

  13. The determination, by atomic-absorption spectrophotometry using electrothermal atomization, of platinum, palladium, rhodium, ruthenium, and iridium

    International Nuclear Information System (INIS)

    Haines, J.; Robert, R.V.D.

    1982-01-01

    A method that involves measurement by atomic-absorption spectrophotometry using electrothermal atomization has been developed for the determination of trace quantities of platinum, palladium, rhodium, ruthenium, and iridium in mineralogical samples. The elements are separated and concentrated by fusion, nickel sulphide being used as the collector, and the analyte elements are measured in the resulting acid solution. An organic extraction procedure was found to offer no advantages over the proposed method. Mutual interferences between the five platinum-group metals examined, as well as interferences from gold, silver, and nickel were determined. The accuracy of the measurement was established by the analysis of a platinum-ore reference material. The lower limits of determination of each of the analyte elements in a sample material are as follows: platinum 1,6μg/l, palladium 0,2μg/1, rhodium 0,5μg/l, ruthenium 3μg/l, and iridium 2,5μg/l. The relative standard deviations range from 0,05 for rhodium to 0.08 for iridium. The method, which is described in detail in the Appendix, is applicable to the determination of these elements in ores, tailings, and geological materials in which the total concentration of the noble metals is less than 1g/t

  14. Osmium-191 → iridium-191m radionuclide generator: development and clinical application. Progress report, March 1, 1981-February 28, 1982

    International Nuclear Information System (INIS)

    Treves, S.; Cheng, C.

    1981-01-01

    A prototype osmium-191 (T 1/2 = 16 days) → iridium-191m (T 1/2 = 4.9 seconds) generator designed for first pass radionuclide angiography was developed in our laboratory (Os-191 → Ir-191m). Our generator had 14 to 20% Ir-191m yield and a 1 to 3 x 10 -3 % Os-191 breakthrough. Iridium-191m decays with emission of a 65 and a 129 keV photon in 50% and 25% abundance respectively. This radionuclide is advantageous for angiography since it provides higher photon flux and results in much lower radiation dose to the patient than Tc-99m. One objective of this research is to improve the Os-191 → Ir-191m generator for first pass radionuclide angiography at an increase in the Ir-191m yield and a decrease in the Os-191 breakthrough. In addition, we would like to develop an Os-191 → Ir-191m generator for continuous infusion which will be used for ECG gated blood pool ventriculography, venography, and arteriography. Another approach will be to develop a carrier free Os-191 → Ir-191m generator in combination with organic or inorganic exchangers. Iridium-191m from our current generator has been employed successfully in two patient studies for the quantitation left-to-right shunting and the measurement of right and left ventricular ejection fractions. These types of studies will be expanded and further evaluated

  15. Denying Access to Commercial Communications Satellites

    National Research Council Canada - National Science Library

    Washington, Tania

    1999-01-01

    .... Commercial systems such as Orion, Panamsat, Iridium and Globalstar will provide the U.S. military and its potential adversaries with a relatively inexpensive and highly effective means to increase the command, control and communications (C3...

  16. GPS Satellite Simulation Facility

    Data.gov (United States)

    Federal Laboratory Consortium — The GPS satellite simulation facility consists of a GPS satellite simulator controlled by either a Silicon Graphics Origin 2000 or PC depending upon unit under test...

  17. Integration of Satellite and Terrestrial Systems in Future Multimedia Communications

    OpenAIRE

    Evans, Barry; Werner, Markus; Lutz, Erich; Bousquet, Michel; Corazza, Giovanni E; Maral, Gerard; Rumeau, Robert; Ferro, Erina

    2005-01-01

    In this article we examine the role of satellite communications in future telecommunication networks and service provision. Lessons from the past indicate that satellites are successful as a result of their wide area coverage or speed to market for new services. Niche areas such as coverage of air and sea will persist, but for land masses convergence of fixed, mobile, and broadcasting will dictate that the only way forward for satellites is in an integrated format with terrestrial systems. We...

  18. Web Transfer Over Satellites Being Improved

    Science.gov (United States)

    Allman, Mark

    1999-01-01

    Extensive research conducted by NASA Lewis Research Center's Satellite Networks and Architectures Branch and the Ohio University has demonstrated performance improvements in World Wide Web transfers over satellite-based networks. The use of a new version of the Hypertext Transfer Protocol (HTTP) reduced the time required to load web pages over a single Transmission Control Protocol (TCP) connection traversing a satellite channel. However, an older technique of simultaneously making multiple requests of a given server has been shown to provide even faster transfer time. Unfortunately, the use of multiple simultaneous requests has been shown to be harmful to the network in general. Therefore, we are developing new mechanisms for the HTTP protocol which may allow a single request at any given time to perform as well as, or better than, multiple simultaneous requests. In the course of study, we also demonstrated that the time for web pages to load is at least as short via a satellite link as it is via a standard 28.8-kbps dialup modem channel. This demonstrates that satellites are a viable means of accessing the Internet.

  19. Ultrafine Iridium Oxide Nanorods Synthesized by Molten Salt Method toward Electrocatalytic Oxygen and Hydrogen Evolution Reactions

    International Nuclear Information System (INIS)

    Ahmed, Jahangeer; Mao, Yuanbing

    2016-01-01

    Highlights: • Ultrafine iridium oxide nanorods were synthesized by a molten salt method at 650 °C. • They show enhanced electrocatalytic activity to oxygen and hydrogen evolution reactions. • These results are comparable with, and in most cases, higher than reported data in the literature. • This study reports a novel synthetic process for IrO_2 but also a high efficient IrO_2 nanostructure. • These IrO_2 NRs are expected to serve as a benchmark to develop active electrocatalysts. - Abstract: Ultrafine iridium oxide nanorods (IrO_2 NRs) were successfully synthesized using a molten salt method at 650 °C. The structural and morphological characterizations of these IrO_2 NRs were carried out by powder X-ray diffraction, Raman spectroscopy and electron microscopic techniques. Compared to commercial IrO_2 nanoparticles (IrO_2 NPs) and previous reports, these IrO_2 NRs show enhanced electrocatalytic activity to oxygen and hydrogen evolution reactions by passing either N_2 or O_2 gas in a 0.5 M KOH electrolyte before electrochemical measurements, including cyclic voltammetry, chronoamperometry and electrochemical impedance spectroscopy. Specifically, the current densities from the as-synthesized IrO_2 NRs and commercial IrO_2 NPs were measured in 0.5 M KOH electrolyte to be 70 and 58 (OER, deaerated, at 0.6 V versus Ag/AgCl), 71 and 61 (OER, O_2, from −0.10 to 1.0 V versus Ag/AgCl at 50 mV/s), and 25 and 14 (HER, deaerated, at −1.4 V versus Ag/AgCl) mA/cm"2, respectively. These results are comparable with, and in most cases, higher than reported data in the literature. Therefore, the current study reports not only a novel synthetic process for IrO_2 but also a high efficient IrO_2 nanostructure, and it is expected that these IrO_2 NRs can serve as a benchmark in the development of active OER and HER (photo)electrocatalysts for various applications.

  20. Separation of rhodium(III and iridium(IV chlorido species by quaternary diammonium centres hosted on silica microparticles

    Directory of Open Access Journals (Sweden)

    A. Majavu

    2017-12-01

    Full Text Available Silica gel was functionalized with six different quaternary diammonium centres derived from ethylenediamine (EDA, tetramethylenediamine (TMDA, hexamethylenediamine (HMDA, 1,8-diaminooctane (OMDA, 1,10-diaminodecane (DMDA and 1,12-diaminododecane (DDMDA to produce Si-QUAT EDA, Si-QUAT TMDA, Si-QUAT HMDA, Si-QUAT OMDA, Si-QUAT DMDA and Si-QUAT DDMDA, respectively. The synthesized silica-based resins were characterized by means of FTIR, XPS, SEM, BET surface area, thermogravimetric analysis and elemental analysis. The materials were used to investigate the adsorption and separation of [RhCl5(H2O]2− and [IrCl6]2−. Batch studies (equilibrium and kinetic studies were conducted to study the adsorption of [RhCl5(H2O]2− and [IrCl6]2− onto Si-QUAT EDA, Si-QUAT TMDA, Si-QUAT HMDA, Si-QUAT OMDA, Si-QUAT DMDA and Si-QUAT DDMDA using single metal aqueous solutions. The Freundlich isotherm confirmed multilayer adsorption and the Freundlich constant (kf displayed the following ascending order; Si-QUAT EDA, Si-QUAT TMDA, Si-QUAT HMDA, Si-QUAT OMDA and Si-QUAT DMDA, and a decrease in kf for Si-QUAT DDMDA. Kinetic studies suggest a pseudo-first order kinetic model. Column studies were also conducted for a binary mixture of these metal ion chlorido species ([RhCl5(H2O]2− and [IrCl6]2−. The iridium loading capacities increased as the carbon spacer between the diammonium centres increased in the following order; Si-QUAT EDA, Si-QUAT TMDA, Si-QUAT HMDA, Si-QUAT OMDA and Si-QUAT DMDA (4.56 mg/g, 6.88 mg/g, 14.63 mg/g, 19.01 mg/g and 29.35 mg/g, respectively. It was observed that the iridium loading capacity of Si-QUAT DDMDA decreased to 8.90 mg/g. This paper presents iridium-specific materials that could be applied in solutions of secondary PGMs sources containing rhodium and iridium as well as in feed solutions from ore processing. Keywords: Silica gel, Quaternary diammonium centres, Rhodium, Iridium, Separation

  1. Influence of the profile of Iridium-192 wire in measurements of quality control for use in brachytherapy

    International Nuclear Information System (INIS)

    Costa, Osvaldo L.; Zeituni, Carlos A.; Rostelato, Maria Elisa C.M.; Moura, Joao A.; Feher, Anselmo; Moura, Eduardo S.; Souza, Carla D.; Somessari, Samir L.; Peleias Junior, Fernando S.; Mattos, Fabio R.

    2013-01-01

    Brachytherapy is a method used in the treatment of cancerous tumors, by ionizing radiation produced by sources, introduced into the tumor area, this method seeks a more direct to the tumor, thereby maximizing the radiation dose to diseased tissue, while minimizing the dose to healthy tissues. One of the radionuclides used in brachytherapy is iridium-192. The Radiation Technology Center (CTR), of the Nuclear and Energy Research Institute (IPEN), has produced commercially, since 1998, iridium-192 wires used in low dose rate (LDR) brachytherapy. To produce this radionuclides, firstly an iridium-platinum wire is irradiated in the nuclear reactor IEA-R1 for 30 hours, with a neutron flux of 5x 10 13 n cm -2 s -1 , the wire is left to decay by 30 days to remove the main contaminants, and then goes through a quality control, before being sent to the hospital. In this quality control is checked the radiation homogeneity along each centimeter of the wire. To implement this procedure, is used a device, consisting of an ionization chamber, surrounded by a lead shield, with a samol 1 cm wide slit, linked to the ionization chamber is a voltage source, and a Keithley 617 electrometer, 2 minutes is the range used to measure the charge by the electrometer. The iridium wire is considered in accordance, when there is no variation higher than 5%, between the average measures and the maximum and minimum values. However, due to design features of the measurement system, the wire may appear to the detector through the slit in larger sizes than the ideal, improperly influencing the final quality control. This paper calculates the difference in size of these variations in profile, and their influence on the final count, it compares the actual values obtained, and describes the improvements, made in quality control procedures, that provided more accurate measurement data, analyzes the results, and suggests changes in devices, aimed at further improving the quality control of iridium-192

  2. High power communication satellites power systems study

    Science.gov (United States)

    Josloff, Allan T.; Peterson, Jerry R.

    1995-01-01

    This paper discusses a planned study to evaluate the commercial attractiveness of high power communication satellites and assesses the attributes of both conventional photovoltaic and reactor power systems. These high power satellites can play a vital role in assuring availability of universally accessible, wide bandwidth communications, for high definition TV, super computer networks and other services. Satellites are ideally suited to provide the wide bandwidths and data rates required and are unique in the ability to provide services directly to the users. As new or relocated markets arise, satellites offer a flexibility that conventional distribution services cannot match, and it is no longer necessary to be near population centers to take advantage of the telecommunication revolution. The geopolitical implications of these substantially enhanced communications capabilities can be significant.

  3. Space industrialization - Education. [via communication satellites

    Science.gov (United States)

    Joels, K. M.

    1978-01-01

    The components of an educational system based on, and perhaps enhanced by, space industrialization communications technology are considered. Satellite technology has introduced a synoptic distribution system for various transmittable educational media. The cost of communications satellite distribution for educational programming has been high. It has, therefore, been proposed to utilize Space Shuttle related technology and Large Space Structures (LSS) to construct a system with a quantum advancement in communication capability and a quantum reduction in user cost. LSS for communications purposes have three basic advantages for both developed and emerging nations, including the ability to distribute signals over wide geographic areas, the reduced cost of satellite communications systems versus installation of land based systems, and the ability of a communication satellite system to create instant educational networks.

  4. Meteorological satellite systems

    CERN Document Server

    Tan, Su-Yin

    2014-01-01

    “Meteorological Satellite Systems” is a primer on weather satellites and their Earth applications. This book reviews historic developments and recent technological advancements in GEO and polar orbiting meteorological satellites. It explores the evolution of these remote sensing technologies and their capabilities to monitor short- and long-term changes in weather patterns in response to climate change. Satellites developed by various countries, such as U.S. meteorological satellites, EUMETSAT, and Russian, Chinese, Japanese and Indian satellite platforms are reviewed. This book also discusses international efforts to coordinate meteorological remote sensing data collection and sharing. This title provides a ready and quick reference for information about meteorological satellites. It serves as a useful tool for a broad audience that includes students, academics, private consultants, engineers, scientists, and teachers.

  5. Theory of geostationary satellites

    CERN Document Server

    Zee, Chong-Hung

    1989-01-01

    Geostationary or equatorial synchronous satellites are a daily reminder of our space efforts during the past two decades. The nightly television satellite weather picture, the intercontinental telecommunications of television transmissions and telephone conversations, and the establishrnent of educational programs in remote regions on Earth are constant reminders of the presence of these satellites. As used here, the term 'geo­ stationary' must be taken loosely because, in the long run, the satellites will not remain 'stationary' with respect to an Earth-fixed reference frame. This results from the fact that these satellites, as is true for all satellites, are incessantly subject to perturbations other than the central-body attraction of the Earth. Among the more predominant pertur­ bations are: the ellipticity of the Earth's equator, the Sun and Moon, and solar radiation pressure. Higher harmonics of the Earth's potential and tidal effects also influence satellite motion, but they are of second­ order whe...

  6. Integrating Data Streams from in-situ Measurements, Social Networks and Satellite Earth Observation to Augment Operational Flood Monitoring and Forecasting: the 2017 Hurricane Season in the Americas as a Large-scale Test Case

    Science.gov (United States)

    Matgen, P.; Pelich, R.; Brangbour, E.; Bruneau, P.; Chini, M.; Hostache, R.; Schumann, G.; Tamisier, T.

    2017-12-01

    Hurricanes Harvey, Irma and Maria generated large streams of heterogeneous data, coming notably from three main sources: imagery (satellite and aircraft), in-situ measurement stations and social media. Interpreting these data streams brings critical information to develop, validate and update prediction models. The study addresses existing gaps in the joint extraction of disaster risk information from multiple data sources and their usefulness for reducing the predictive uncertainty of large-scale flood inundation models. Satellite EO data, most notably the free-of-charge data streams generated by the Copernicus program, provided a wealth of high-resolution imagery covering the large areas affected. Our study is focussing on the mapping of flooded areas from a sequence of Sentinel-1 SAR imagery using a classification algorithm recently implemented on the European Space Agency's Grid Processing On Demand environment. The end-to-end-processing chain provided a fast access to all relevant imagery and an effective processing for near-real time analyses. The classification algorithm was applied on pairs of images to rapidly and automatically detect, record and disseminate all observable changes of water bodies. Disaster information was also retrieved from photos as well as texts contributed on social networks and the study shows how this information may complement EO and in-situ data and augment information content. As social media data are noisy and difficult to geo-localize, different techniques are being developed to automatically infer associated semantics and geotags. The presentation provides a cross-comparison between the hazard information obtained from the three data sources. We provide examples of how the generated database of geo-localized disaster information was finally integrated into a large-scale hydrodynamic model of the Colorado River emptying into the Matagorda Bay on the Gulf of Mexico in order to reduce its predictive uncertainty. We describe the

  7. Study and development of an Iridium-192 seed for use in ophthalmic cancer; Estudo e desenvolvimento de uma semente de iridio-192 para aplicacao em cancer oftalmico

    Energy Technology Data Exchange (ETDEWEB)

    Mattos, Fabio Rodrigues de

    2013-07-01

    Even ocular tumors are not among the cases with a higher incidence, they affect the population, especially children. The Institute of Energy and Nuclear Research (IPEN-CNEN/SP) in partnership with Escola Paulista de Medicina (UNIFESP), created a project to develop and implement a alternative treatment for ophthalmic cancer that use brachytherapy iridium-192 seeds. The project arose by reason of the Escola Paulista treat many cancer cases within the Unified Health System (SUS) and the research experience of sealed radioactive sources group at IPEN. The methodology was developed from the available infrastructure and the experience of researchers. The prototype seed presents with a core (192-iridium alloy of iridium-platinum) of 3.0 mm long sealed by a capsule of titanium of 0.8 mm outside diameter, 0.05 mm wall thickness and 4,5mm long. This work aims to study and develop a seed of iridium-192 from a platinum-iridium alloy. No study on the fabrication of these seeds was found in available literature. It was created a methodology that involved: characterization of the material used in the core, creation of device for neutron activation irradiation and and seed sealing tests. As a result, proved the feasibility of the method. As a suggestion for future work, studies regarding metrology and dosimetry of these sources and improvement of the methodology should be carried out, for future implementation in national scope. (author)

  8. Closed-shell and open-shell square-planar iridium nitrido complexes

    Science.gov (United States)

    Scheibel, Markus G.; Askevold, Bjorn; Heinemann, Frank W.; Reijerse, Edward J.; de Bruin, Bas; Schneider, Sven

    2012-07-01

    Coupling reactions of nitrogen atoms represent elementary steps to many important heterogeneously catalysed reactions, such as the Haber-Bosch process or the selective catalytic reduction of NOx to give N2. For molecular nitrido (and related oxo) complexes, it is well established that the intrinsic reactivity, for example nucleophilicity or electrophilicity of the nitrido (or oxo) ligand, can be attributed to M-N (M-O) ground-state bonding. In recent years, nitrogen (oxygen)-centred radical reactivity was ascribed to the possible redox non-innocence of nitrido (oxo) ligands. However, unequivocal spectroscopic characterization of such transient nitridyl {M=N•} (or oxyl {M-O•}) complexes remained elusive. Here we describe the synthesis and characterization of the novel, closed-shell and open-shell square-planar iridium nitrido complexes [IrN(Lt-Bu)]+ and [IrN(Lt-Bu)] (Lt-Bu=N(CHCHP-t-Bu2)2). Spectroscopic characterization and quantum chemical calculations for [IrN(Lt-Bu)] indicate a considerable nitridyl, {Ir=N•}, radical character. The clean formation of IrI-N2 complexes via binuclear coupling is rationalized in terms of nitrido redox non-innocence in [IrN(Lt-Bu)].

  9. Atmospheric behavior of urban diesel soot tagged with an iridium tracer

    International Nuclear Information System (INIS)

    Suarez, A.E.; Caffrey, P.F.; Borgoul, P.V.; Ondov, J.M.

    1995-01-01

    An important source of polynuclear aromatic hydrocarbons depositing to the Chesapeake Bay is diesel emissions, including, those from the heavily-industrial City of Baltimore which lies 3 of diesel fuel burned by the City of Baltimore's sanitation truck fleet for a 20-day period in August, 1995. Size-segregated aerosol was collected daily using 80-L min -1 dichotomous samplers at four land-bas3ed sites and aboard ship at two locations on the Chesapeake Bay. Shipboard samples were collected on the EPA's Research Vessel Anderson, either east or southeast of Baltimore, off Annapolis. Three of the land sites, i.e., those at Catonsville, MD, the Eastern Avenue Fire Station (14 km from the Bay), and the Coast Guard Station at Still pond (30 km northeast of Baltimore) were chosen to be aligned with prevailing westerly winds. The fourth site was located on Hart Miller Island, about 14 km southeast of the Fire Station to take advantage of drainage flow along the Patapsco River. In addition, 10-stage Micro-Orifice Impactors were operated daily aboard ship and at all but the Catonsville site. Deposition plates were exposed aboard ship and at two of the land sites. Finally, several samples of tagged diesel emissions were collected with an MOI mounted on one of the sanitation trucks. Iridium and ≤ 40 other elements were determined by neutron activation analysis or X-ray fluorescence; graphitic carbon by light transmission, and aerosol mass by gravimetry

  10. Performance enhancement in organic photovoltaic solar cells using iridium (Ir) ultra-thin surface modifier (USM)

    Science.gov (United States)

    Pandey, Rina; Lim, Ju Won; Kim, Jung Hyuk; Angadi, Basavaraj; Choi, Ji Won; Choi, Won Kook

    2018-06-01

    In this study, Iridium (Ir) metallic layer as an ultra-thin surface modifier (USM) was deposited on ITO coated glass substrate using radio frequency magnetron sputtering for improving the photo-conversion efficiency of organic photovoltaic cells. Ultra-thin Ir acts as a surface modifier replacing the conventional hole transport layer (HTL) PEDOT:PSS in organic photovoltaic (OPV) cells with two different active layers P3HT:PC60BM and PTB7:PC70BM. The Ir USM (1.0 nm) coated on ITO glass substrate showed transmittance of 84.1% and work function of >5.0 eV, which is higher than that of ITO (4.5-4.7 eV). The OPV cells with Ir USM (1.0 nm) exhibits increased power conversion efficiency of 3.70% (for P3HT:PC60BM active layer) and 7.28% (for PTB7:PC70BM active layer) under 100 mW/cm2 illumination (AM 1.5G) which are higher than those of 3.26% and 6.95% for the same OPV cells but with PEDOT:PSS as HTL instead of Ir USM. The results reveal that the chemically stable Ir USM layer could be used as an alternative material for PEDOT:PSS in organic photovoltaic cells.

  11. Nanocomposites of iridium oxide and conducting polymers as electroactive phases in biological media.

    Science.gov (United States)

    Moral-Vico, J; Sánchez-Redondo, S; Lichtenstein, M P; Suñol, C; Casañ-Pastor, N

    2014-05-01

    Much effort is currently devoted to implementing new materials in electrodes that will be used in the central nervous system, either for functional electrostimulation or for tests on nerve regeneration. Their main aim is to improve the charge capacity of the electrodes, while preventing damaging secondary reactions, such as peroxide formation, occurring while applying the electric field. Thus, hybrids may represent a new generation of materials. Two novel hybrid materials are synthesized using three known biocompatible materials tested in the neural system: polypyrrole (PPy), poly(3,4-ethylenedioxythiophene) (PEDOT) and iridium oxide (IrO2). In particular, PPy-IrO2 and PEDOT-IrO2 hybrid nanocomposite materials are prepared by chemical polymerization in hydrothermal conditions, using IrO2 as oxidizing agent. The reaction yields a significant ordered new hybrid where the conducting polymer is formed around the IrO2 nanoparticles, encapsulating them. Scanning electron microscopy and backscattering techniques show the extent of the encapsulation. Both X-ray photoelectron and Fourier transform infrared spectroscopies identify the components of the phases, as well as the absence of impurities. Electrochemical properties of the final phases in powder and pellet form are evaluated by cyclic voltammetry. Biocompatibility is tested with MTT toxicity tests using primary cultures of cortical neurons grown in vitro for 6 and 9days. Copyright © 2013 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

  12. Synthesis of 2.5 nm colloidal iridium nanoparticles with strong surface enhanced Raman scattering activity

    International Nuclear Information System (INIS)

    Cui, Malin; Zhao, Yuan; Wang, Chan; Song, Qijun

    2016-01-01

    Colloidal iridium nanoparticles (IrNPs) were synthesized through an environmentally friendly approach by using trisodium citrate as the capping molecule in an aqueous medium. The resulting colloidal IrNPs have a typical diameter of 2.5 nm and display absorption bands at 250, 400 and 600 nm. They possess uniform morphology, good dispersibility, excellent stability in water, and exhibit strong surface enhanced Raman scattering (SERS) activity with an enhancement factor (EF) of 3.5 × 10 5 at the 1512 cm -1 peak when using Rhodamine 6G as the probe molecule. The excellent SERS performance of the IrNPs was exemplarily applied to the determination of the industrial colorant Sudan Red I. The peak intensity of the Raman band at 1236 cm -1 is linearly related to the concentration of Sudan Red I which can be determined by SERS in the 2 nM to 8 μM concentration range with a limit of detection as low as 0.6 nM. In our perception, this strong SERS activity of the IrNPs has a large potential in the SERS-based quantitation of various chemical substances. (author)

  13. Phase and group velocities for Lamb waves in DOP-26 iridium alloy sheet

    International Nuclear Information System (INIS)

    Simpson, W.A.; McGuire, D.J.

    1994-07-01

    The relatively coarse grain structure of iridium weldments limits the ultrasonic inspection of these structures to frequencies in the low megahertz range. As the material thickness is nominally 0.635 mm for clad vent set capsules, the low frequencies involved necessarily entail the generation of Lamb waves m the specimen. These waves are, of course, dispersive and detailed knowledge of both the phase and group velocities is required in order to determine accurately the location of flaws detected using Lamb waves. Purpose of this study is to elucidate the behavior of Lamb waves propagating in the capsule alloy and to quantify the velocities so that accurate flaw location is ensured. We describe a numerical technique for computing the phase velocities of Lamb waves (or of any other type of guided wave) and derive the group velocities from this information. A frequency-domain method is described for measuring group velocity when multiple Lamb modes are present and mutually interfering in the time domain, and experimental confirmation of the group velocity is presented for the capsule material

  14. Instrumental measurement of iridium abundances in the part-per-trillion range following neutron activation

    International Nuclear Information System (INIS)

    Alvarez, L.W.; Asaro, F.; Goulding, F.S.; Landis, D.A.; Madden, N.W.; Malone, D.F.

    1988-01-01

    An automated gamma-ray coincidence spectrometer has been constructed which, following neutron activation, can measure iridium (Ir) abundances of the order of 25 parts-per-trillion (ppt) in rock samples 500 times more rapidly than previously possible by instrumental techniques used at the Lawrence Berkeley Laboratory. Twin intrinsic Ge gamma-ray detectors count coincidences between the 316.5 and 468.1 keV gamma rays of 192 Ir, and together with a mineral-oil-based Compton suppression shield provide a sensitivity of 50 ppt Ir in 7 minute measurements of 100 mg limestone samples subsequent to irradiation in the University of Missouri reactor. Over 3000 samples have been measured, and in collaboration with many geologists and paleontologists from around the world, anomalous amounts of Ir have been detected in rocks with approximate ages of 12, 39, 67, 91, 150 and 3500 million years. Modifications are nearly complete to measure ten other elements very important to geochemical studies simultaneously (in the singles rather than the coincidence mode) with the Ir measurements

  15. An iridium oxide microelectrode for monitoring acute local pH changes of endothelial cells.

    Science.gov (United States)

    Ng, Shu Rui; O'Hare, Danny

    2015-06-21

    pH sensors were fabricated by anodically electrodepositing iridium oxide films (AEIROFs) onto microelectrodes on chips and coated with poly(ethyleneimine) (PEI) for mechanical stability. These demonstrate super-Nernstian response to pH from pH 4.0 to 7.7 in chloride-free phosphate buffer. The surface of the chip was coated with fibronectin for the attachment of porcine aortic endothelial cells (PAECs). The working capability of the pH sensor for monitoring acute local pH changes was investigated by stimulating the PAECs with thrombin. Our results show that thrombin induced acute extracellular acidification of PAECs and dissolution of fibronectin, causing the local pH to decrease. The use of PD98059, a mitogen-activated protein kinase (MAPK) inhibitor, reduced extracellular acidification and an increase in local pH was observed. This study shows that our pH sensors can facilitate the investigation of acute cellular responses to stimulation by monitoring the real-time, local pH changes of cells attached to the sensors.

  16. Electron-beam welding of thorium-doped iridium alloy sheets

    International Nuclear Information System (INIS)

    David, S.A.; Liu, C.T.; Hudson, J.D.

    1979-04-01

    Modified iridium alloys containing 100 ppM Th were found to be very susceptible to hot-cracking during gas tungsten-arc and electron-beam welding. However, the electron-beam welding process showed greater promise of success in welding these alloys, in particular Ir--0.3% W doped with 200 ppM Th and 50 ppM Al. The weldability of this particular alloy was extremely sensitive to the welding parameters, such as beam focus condition and welding speed, and the resulting fusion zone structure. At low speed successful electron-beam welds were made over a narrow range of beam focus conditions. However, at high speeds successful welds can be made over an extended range of focus conditions. The fusion zone grain structure is a strong function of welding speed and focus condition, as well. In the welds that showed hot-cracking, a region of positive segregation of thorium was identified at the fusion boundary. This highly thorium-segregated region seems to act as a potential source for the nucleation of a liquation crack, which later grows as a centerline crack

  17. New Therapeutic Agent against Arterial Thrombosis: An Iridium(III-Derived Organometallic Compound

    Directory of Open Access Journals (Sweden)

    Chih-Wei Hsia

    2017-12-01

    Full Text Available Platelet activation plays a major role in cardio and cerebrovascular diseases, and cancer progression. Disruption of platelet activation represents an attractive therapeutic target for reducing the bidirectional cross talk between platelets and tumor cells. Platinum (Pt compounds have been used for treating cancer. Hence, replacing Pt with iridium (Ir is considered a potential alternative. We recently developed an Ir(III-derived complex, [Ir(Cp*1-(2-pyridyl-3-(2-hydroxyphenylimidazo[1,5-a]pyridine Cl]BF4 (Ir-11, which exhibited strong antiplatelet activity; hence, we assessed the therapeutic potential of Ir-11 against arterial thrombosis. In collagen-activated platelets, Ir-11 inhibited platelet aggregation, adenosine triphosphate (ATP release, intracellular Ca2+ mobilization, P-selectin expression, and OH· formation, as well as the phosphorylation of phospholipase Cγ2 (PLCγ2, protein kinase C (PKC, mitogen-activated protein kinases (MAPKs, and Akt. Neither the adenylate cyclase inhibitor nor the guanylate cyclase inhibitor reversed the Ir-11-mediated antiplatelet effects. In experimental mice, Ir-11 prolonged the bleeding time and reduced mortality associated with acute pulmonary thromboembolism. Ir-11 plays a crucial role by inhibiting platelet activation through the inhibition of the PLCγ2–PKC cascade, and the subsequent suppression of Akt and MAPK activation, ultimately inhibiting platelet aggregation. Therefore, Ir-11 can be considered a new therapeutic agent against either arterial thrombosis or the bidirectional cross talk between platelets and tumor cells.

  18. Thermal stability of pulsed laser deposited iridium oxide thin films at low oxygen atmosphere

    Science.gov (United States)

    Gong, Yansheng; Wang, Chuanbin; Shen, Qiang; Zhang, Lianmeng

    2013-11-01

    Iridium oxide (IrO2) thin films have been regarded as a leading candidate for bottom electrode and diffusion barrier of ferroelectric capacitors, some process related issues need to be considered before integrating ferroelectric capacitors into memory cells. This paper presents the thermal stability of pulsed laser deposited IrO2 thin films at low oxygen atmosphere. Emphasis was given on the effect of post-deposition annealing temperature at different oxygen pressure (PO2) on the crystal structure, surface morphology, electrical resistivity, carrier concentration and mobility of IrO2 thin films. The results showed that the thermal stability of IrO2 thin films was strongly dependent on the oxygen pressure and annealing temperature. IrO2 thin films can stably exist below 923 K at PO2 = 1 Pa, which had a higher stability than the previous reported results. The surface morphology of IrO2 thin films depended on PO2 and annealing temperature, showing a flat and uniform surface for the annealed films. Electrical properties were found to be sensitive to both the annealing temperature and oxygen pressure. The room-temperature resistivity of IrO2 thin films with a value of 49-58 μΩ cm increased with annealing temperature at PO2 = 1 Pa. The thermal stability of IrO2 thin films as a function of oxygen pressure and annealing temperature was almost consistent with thermodynamic calculation.

  19. Global iridium anomaly, mass extinction, and redox change at the Devonian-Carboniferous boundary

    Energy Technology Data Exchange (ETDEWEB)

    Wang, K. (Geological Survey of Canada, Calgary, Alberta (Canada) Univ. of Calgary, Alberta (Canada)); Attrep, M. Jr.; Orth, C.J. (Los Alamos National Lab., NM (United States))

    1993-12-01

    Iridium abundance anomalies have been found on a global scale in the Devonian-Carboniferous (D-C) boundary interval, which records one of the largest Phanerozoic mass-extinction events, an event that devastated many groups of living organisms, such as plants, ammonoids, trilobites, conodonts, fish, foraminiferans, brachiopods, and ostracodes. At or very close to the D-C boundary, there exists a geographically widespread black-shale interval, and Ir abundances reach anomalous maxima of 0.148 ppb (Montagne Noire, France), 0.138 ppb (Alberta, Canada) 0.140 ppb (Carnic Alps, Austria), 0.156 ppb (Guangxi, China), 0.258 ppb (Guizhou, China), and 0.250 ppb (Oklahoma). The discovery of global D-C Ir anomalies argues for an impact-extinction model. However, nonchondritic ratios of Ir to other important elements and a lack of physical evidence (shocked quartz, microtektites) do not support such a scenario. The fact that all Ir abundance maxima are at sharp redox boundaries in these sections leads us to conclude that the Ir anomalies likely resulted from a sudden change in paleo-redox conditions during deposition and/or early diagenesis. 36 refs., 2 figs., 1 tab.

  20. Atomic structure of self-organizing iridium induced nanowires on Ge(001)

    Energy Technology Data Exchange (ETDEWEB)

    Kabanov, N.S., E-mail: n.kabanov@utwente.nl [Faculty of Physics, Moscow State University, 119991 (Russian Federation); Physics of Interfaces and Nanomaterials, MESA+ Institute for Nanotechnology, University of Twente, P. O. Box 217, Enschede 7500 AE (Netherlands); Heimbuch, R.; Zandvliet, H.J.W. [Physics of Interfaces and Nanomaterials, MESA+ Institute for Nanotechnology, University of Twente, P. O. Box 217, Enschede 7500 AE (Netherlands); Saletsky, A.M.; Klavsyuk, A.L. [Faculty of Physics, Moscow State University, 119991 (Russian Federation)

    2017-05-15

    Highlights: • Ir/Ge(001) structure has been studied with DFT calculations and scanning tunneling microscopy. • Ir/Ge(001) nanowires are composed of Ge atoms and Ir atoms are located in subsurface positions. • The regions in the vicinity of the nanowires are very dynamic, even at temperatures as low as 77 K. - Abstract: The atomic structure of self-organizing iridium (Ir) induced nanowires on Ge(001) is studied by density functional theory (DFT) calculations and variable-temperature scanning tunneling microscopy. The Ir induced nanowires are aligned in a direction perpendicular to the Ge(001) substrate dimer rows, have a width of two atoms and are completely kink-less. Density functional theory calculations show that the Ir atoms prefer to dive into the Ge(001) substrate and push up the neighboring Ge substrate atoms. The nanowires are composed of Ge atoms and not Ir atoms as previously assumed. The regions in the vicinity of the nanowires are very dynamic, even at temperatures as low as 77 K. Time-resolved scanning tunneling microscopy measurements reveal that this dynamics is caused by buckled Ge substrate dimers that flip back and forth between their two buckled configurations.

  1. New cyclometalated iridium(III) complex as a phosphorescent dopant in organic light emitting devices

    Science.gov (United States)

    Ivanov, P.; Tomova, R.; Petrova, P.; Stanimirov, S.; Petkov, I.

    2014-05-01

    A new cyclometalated iridium (III) bis[2-(4-chlorophenyl)benzothiazolato-N,C2]-acetylacetonate, (Cl-bt)2Ir(acac), was synthesized and identified by 1H NMR and elemental analysis. The application was studied of the new compound as a dopant in the hole transporting layer (HTL) of the following organic light emitting diode (OLED) structure: HTL/EL/ETL, where HTL was 4,4'-bis(9H-carbazol-9-yl)biphenyl (CBP) or N,N'-bis(3-methylphenyl)-N,N'-diphenylbenzidine (TPD), incorporated in a poly(N-vinylcarbazole) (PVK) matrix; EL was an electroluminescent layer of bis(8-hydroxy-2-methylquinoline)-(4-phenylpheno-xy) aluminum (BAlq); and ETL was an electron-transporting layer of bis[2-(2-benzothiazoly) phenolato]zinc(II) (Zn(btz)2). We established that the electroluminescence spectra of the OLEDs at different dopant concentrations were basically the sum of the greenish-blue emission of BAlq and the yellowish-green emission of the Ir complex. It was also found that increasing the dopant concentration resulted in an increase in the relative electroluminescent intensity of the Ir complex emission, while that of BAlq decreased, thus a fine tuning of the OLED color was observed.

  2. Determination of the tissue inhomogeneity correction in high dose rate Brachytherapy for Iridium-192 source

    Directory of Open Access Journals (Sweden)

    Barlanka Ravikumar

    2012-01-01

    Full Text Available In Brachytherapy treatment planning, the effects of tissue heterogeneities are commonly neglected due to lack of accurate, general and fast three-dimensional (3D dose-computational algorithms. In performing dose calculations, it is assumed that the tumor and surrounding tissues constitute a uniform, homogeneous medium equivalent to water. In the recent past, three-dimensional computed tomography (3D-CT based treatment planning for Brachytherapy applications has been popularly adopted. However, most of the current commercially available planning systems do not provide the heterogeneity corrections for Brachytherapy dosimetry. In the present study, we have measured and quantified the impact of inhomogeneity caused by different tissues with a 0.015 cc ion chamber. Measurements were carried out in wax phantom which was employed to measure the heterogeneity. Iridium-192 (192 Ir source from high dose rate (HDR Brachytherapy machine was used as the radiation source. The reduction of dose due to tissue inhomogeneity was measured as the ratio of dose measured with different types of inhomogeneity (bone, spleen, liver, muscle and lung to dose measured with homogeneous medium for different distances. It was observed that different tissues attenuate differently, with bone tissue showing maximum attenuation value and lung tissue resulting minimum value and rest of the tissues giving values lying in between those of bone and lung. It was also found that inhomogeneity at short distance is considerably more than that at larger distances.

  3. Recovery from Iridium-192 flakes of a radioactive source for industrial use after a radiation incident

    International Nuclear Information System (INIS)

    Cruz, W.H.; Zapata, L.A.

    2013-01-01

    The Iridium-192 ( 192 Ir) is the most used and ideal for industrial radiography applications, especially in petrochemical plants and pipelines and provides better contrast sensitivity for thick (25.4 mm). This source has constructive sealed double encapsulation, the internal capsule containing stainless steel to radioactive material in the form of flakes and welded with TIG process. The radiological incident happened at a gas station fuel sales in circumstances in which there was a homogeneity test welds a tank, the flakes or Ir-192 fell off his ponytail and left scattered over an area of 2 m 2 , some fell flat areas and other land so collected in lead shielding and metal container and ground source. Full recovery of the leaflets was performed at the Division of radioactive waste management (GRRA) gaining a total of 22 flakes with no radiation risk to staff performance and installation and the conclusion was reached that the misapplicaion of TIG welding was the main cause the incident. (author)

  4. Versatile deprotonated NHC: C,N-bridged dinuclear iridium and rhodium complexes

    Directory of Open Access Journals (Sweden)

    Albert Poater

    2016-01-01

    Full Text Available Bearing the versatility of N-heterocyclic carbene (NHC ligands, here density functional theory (DFT calculations unravel the capacity of coordination of a deprotonated NHC ligand (pNHC to generate a doubly C2,N3-bridged dinuclear complex. Here, in particular the discussion is based on the combination of the deprotonated 1-arylimidazol (aryl = mesityl (Mes with [M(cod(μ-Cl] (M = Ir, Rh generated two geometrical isomers of complex [M(cod{µ-C3H2N2(Mes-κC2,κN3}]2. The latter two isomers display conformations head-to-head (H-H and head-to-tail (H-T of CS and C2 symmetry, respectively. The isomerization from the H-H to the H-T conformation is feasible, whereas next substitutions of the cod ligand by CO first, and PMe3 later confirm the H-T coordination as the thermodynamically preferred. It is envisaged the exchange of the metal, from iridium to rhodium, confirming here the innocence of the nature of the metal for such arrangements of the bridging ligands.

  5. BOWIEITE: A NEW RHODIUM-IRIDIUM-PLATINUM SULFIDE IN PLATINUM-ALLOY NUGGETS, GOODNEWS BAY, ALASKA.

    Science.gov (United States)

    Desborough, George A.; Criddle, Alan J.

    1984-01-01

    Bowieite (Rh,Ir,Pt)//2S//3, a new mineral species, is found in three nuggets of platinum from Goodnews Bay, Alaska. In linearly polarized reflected light, and compared to the host, higher reflecting white platinum-iridium alloy, bowieite is pale gray to pale gray-brown; neither bireflectance nor reflectance pleochroism is apparent. With polars crossed, its anisotropic rotation tints vary from gray to dark brown. Luminance values (relative to the CIE illuminant C) for R//1 and R//2, computed from full spectral data for the most bireflectant grain, are 45. 8% and 48. 2% in air, and 30. 5% and 33. 0% in oil, respectively. VHN//1//0//0 1288 (858 to 1635). Bowieite is orthorhombic, space group Pnca, with a 8. 454(7) -8. 473(8), b 5. 995(1)-6. 002(7), c 6. 143(1)-6. 121(8) A, Z equals 4. Some grains that are 2. 6 to 3. 8 atomic % metal-deficient occur as an optically coherent rim on bowieite; the rim and the bowieite grain are not optically continuous.

  6. Radiation control in the intensive care unit for high intensity iridium-192 brain implants

    International Nuclear Information System (INIS)

    Sewchand, W.; Drzymala, R.E.; Amin, P.P.; Salcman, M.; Salazar, O.M.

    1987-01-01

    A bedside lead cubicle was designed to minimize the radiation exposure of intensive care unit staff during routine interstitial brain irradiation by removable, high intensity iridium-192. The cubicle shields the patient without restricting intensive care routines. The design specifications were confirmed by exposure measurements around the shield with an implanted anthropomorphic phantom simulating the patient situation. The cubicle reduces the exposure rate around an implant patient by as much as 90%, with the exposure level not exceeding 0.1 mR/hour/mg of radium-equivalent 192 Ir. Evaluation of data accumulated for the past 3 years has shown that the exposure levels of individual attending nurses are 0.12 to 0.36 mR/mg of radium-equivalent 192 Ir per 12-hour shift. The corresponding range for entire nursing teams varies between 0.18 and 0.26. A radiation control index (exposure per mg of radium-equivalent 192 Ir per nurse-hour) is thus defined for individual nurses and nursing teams; this index is a significant guide to the planning of nurse rotations for brain implant patients with various 192 Ir loads. The bedside shield reduces exposure from 192 Ir implants by a factor of about 20, as expected, and the exposure from the lower energy radioisotope iodine-125 is barely detectable

  7. Iridium Clusters Encapsulated in Carbon Nanospheres as Nanocatalysts for Methylation of (Bio)Alcohols.

    Science.gov (United States)

    Liu, Qiang; Xu, Guoqiang; Wang, Zhendong; Liu, Xiaoran; Wang, Xicheng; Dong, Linlin; Mu, Xindong; Liu, Huizhou

    2017-12-08

    C-H methylation is an attractive chemical transformation for C-C bonds construction in organic chemistry, yet efficient methylation of readily available (bio)alcohols in water using methanol as sustainable C1 feedstock is limited. Herein, iridium nanocatalysts encapsulated in yolk-shell-structured mesoporous carbon nanospheres (Ir@YSMCNs) were synthesized for this transformation. Monodispersed Ir clusters (ca. 1.0 nm) were encapsulated in situ and spatially isolated within YSMCNs by a silica-assisted sol-gel emulsion strategy. A selection of (bio)alcohols (19 examples) was selectively methylated in aqueous phase with good-to-high yields over the developed Ir@YSMCNs. The improved catalytic efficiencies in terms of activity and selectivity together with the good stability and recyclability were contributable to the ultrasmall Ir clusters with oxidation chemical state as a consequence of the confinement effect of YSMCNs with interconnected nanostructures. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  8. Single Pot Selective Hydrogenation of Furfural to 2-Methylfuran Over Carbon Supported Iridium Catalysts

    KAUST Repository

    Date, Nandan S; Hengne, Amol Mahalingappa; Huang, Kuo-Wei; Chikate, Rajeev C.; Rode, C. V.

    2018-01-01

    Various iridium supported carbon catalysts were prepared and screened for direct hydrogenation of furfural (FFR) to 2-methyl furan (2-MF). Amongest these, 5% Ir/C showed excellent results with complete FFR conversion and highest selectivity of 95% to 2-MF at very low H2 pressure of 100 psig. Metallic (Iro) and oxide ( IrO2) phases of Ir catalyzed first step hydrogenation involving FFR to FAL and subsequent hydrogenation to 2-MF,respecively. This was confirmed by XPS analysis and some controlled experiments. At low temperature of 140 oC, almost equal selectivities of FAL (42%) and 2-MF (43%) were observed, while higher temperature (220oC) favored selective hydrodeoxygenation. At optimized temperature, 2-MF formed selectively while higher pressure and higher catalyst loading favored ring hydrogenation of furfural rather than side chain hydrogenation. With combination of several control experimental results and detailed catalyst characterization, a plausible reaction pathway has been proposed for selective formation of 2-MF. The selectivity to various other products in FFR hydrogenation can be manipulated by tailoring the reaction conditions over the same catalyst.

  9. Single Pot Selective Hydrogenation of Furfural to 2-Methylfuran Over Carbon Supported Iridium Catalysts

    KAUST Repository

    Date, Nandan S

    2018-03-20

    Various iridium supported carbon catalysts were prepared and screened for direct hydrogenation of furfural (FFR) to 2-methyl furan (2-MF). Amongest these, 5% Ir/C showed excellent results with complete FFR conversion and highest selectivity of 95% to 2-MF at very low H2 pressure of 100 psig. Metallic (Iro) and oxide ( IrO2) phases of Ir catalyzed first step hydrogenation involving FFR to FAL and subsequent hydrogenation to 2-MF,respecively. This was confirmed by XPS analysis and some controlled experiments. At low temperature of 140 oC, almost equal selectivities of FAL (42%) and 2-MF (43%) were observed, while higher temperature (220oC) favored selective hydrodeoxygenation. At optimized temperature, 2-MF formed selectively while higher pressure and higher catalyst loading favored ring hydrogenation of furfural rather than side chain hydrogenation. With combination of several control experimental results and detailed catalyst characterization, a plausible reaction pathway has been proposed for selective formation of 2-MF. The selectivity to various other products in FFR hydrogenation can be manipulated by tailoring the reaction conditions over the same catalyst.

  10. Iridium concentration and noble gas composition of Cretaceous-Tertiary boundary clay from Stevens Klint, Denmark

    International Nuclear Information System (INIS)

    Osawa, Takahito; Hatsukawa, Yuichi; Nagao, Keisuke; Koizumi, Mitsuo; Oshima, Masumi; Toh, Yosuke; Kimura, Atsushi; Furutaka, Kazuyoshi

    2009-01-01

    The Cretaceous-Tertiary (K-T) boundary about 65 million years ago records a mass extinction event caused by a bolide impact. K-T boundary clay collected from Stevns Klint, Denmark was investigated in this work. Iridium concentrations of eight clays across the K-T boundary were determined using a multiple gamma-ray analysis system after neutron activation. Anomalously high Ir concentrations were detected in five marl samples, with the highest concentration being 29.9 ppb. Four samples were analyzed for all noble gases. NO extraterrestrial Ar, Kr, and Xe were discovered in any of the samples, although most of the 3 He which was detected was extraterrestrial. Solar-like Ne was observed only in the sample SK4, which had an Ir concentration of 14.3 ppb, indicating the presence of micrometeorites. The solar-like Ne clearly did not originate from an asteroid/comet associated with the bolide impact, as that asteroid is thought to have been extremely large. Also, because there was no sign of a high accretion rate of micrometeorites at the boundary it could not be ascertained whether the solar-like Ne was related to a catastrophic event that led to the extinction of the dinosaurs. (author)

  11. Local structure of Iridium organometallic catalysts covalently bonded to carbon nanotubes.

    Science.gov (United States)

    Blasco, J.; Cuartero, V.; Subías, G.; Jiménez, M. V.; Pérez-Torrente, J. J.; Oro, L. A.; Blanco, M.; Álvarez, P.; Blanco, C.; Menéndez, R.

    2016-05-01

    Hybrid catalysts based on Iridium N-heterocyclic carbenes anchored to carbon nanotubes (CNT) have been studied by XAFS spectroscopy. Oxidation of CNT yields a large amount of functional groups, mainly hydroxyl groups at the walls and carboxylic groups at the tips, defects and edges. Different kinds of esterification reactions were performed to functionalize oxidized CNT with imidazolium salts. Then, the resulting products were reacted with an Ir organometallic compound to form hybrid catalysts efficient in hydrogen transfer processes. XANES spectroscopy agree with the presence of Ir(I) in these catalysts and the EXAFS spectra detected differences in the local structure of Ir atoms between the initial Ir organometallic compound and the Ir complexes anchored to the CNT. Our results confirm that the halide atom, present in the Ir precursor, was replaced by oxygen from -OH groups at the CNT wall in the first coordination shell of Ir. The lability of this group accounts for the good recyclability and the good efficiency shown by these hybrid catalysts.

  12. Protected transitional solution to transformational satellite communications

    Science.gov (United States)

    Brand, Jerry C.

    2005-06-01

    As the Warfighter progresses into the next generation battlefield, transformational communications become evident as an enabling technology. Satellite communications become even more vital as the battles range over greater non-contiguous spaces. While current satellite communications provide suitable beyond line-of-sight communications and the Transformational Communications Architecture (TCA) sets the stage for sound information exchange, a realizable transition must occur to ensure successful succession to this higher level. This paper addresses the need for a planned escalation to the next generation satellite communications architecture and offers near-term alternatives. Commercial satellite systems continue to enable the Warfighter to reach back to needed information resources, providing a large majority of available bandwidth. Four areas of concentration for transition include encrypted Telemetry, Tracking and Control (or Command) (TT&C), encrypted and covered data, satellite attack detection and protection, and operational mobility. Solution methodologies include directly embedding COMSEC devices in the satellites and terminals, and supplementing existing terminals with suitable equipment and software. Future satellites planned for near-term launches can be adapted to include commercial grade and higher-level secure equipment. Alternately, the expected use of programmable modems (Software Defined Radios (SDR)) enables incorporation of powerful cipher methods approaching military standards as well as waveforms suitable for on-the-move operation. Minimal equipment and software additions on the satellites can provide reasonable attack detection and protection methods in concert with the planned satellite usage. Network management suite modifications enable cohesive incorporation of these protection schemes. Such transitional ideas offer a smooth and planned transition as the TCA takes life.

  13. Communication satellite applications

    Science.gov (United States)

    Pelton, Joseph N.

    The status and future of the technologies, numbers and services provided by communications satellites worldwide are explored. The evolution of Intelsat satellites and the associated earth terminals toward high-rate all-digital telephony, data, facsimile, videophone, videoconferencing and DBS capabilities are described. The capabilities, services and usage of the Intersputnik, Eutelsat, Arabsat and Palapa systems are also outlined. Domestic satellite communications by means of the Molniya, ANIK, Olympus, Intelsat and Palapa spacecraft are outlined, noting the fast growth of the market and the growing number of different satellite manufacturers. The technical, economic and service definition issues surrounding DBS systems are discussed, along with presently operating and planned maritime and aeronautical communications and positioning systems. Features of search and rescue and tracking, data, and relay satellite systems are summarized, and services offered or which will be offered by every existing or planned communication satellite worldwide are tabulated.

  14. Communication satellites to enter a new age of flexibility

    Science.gov (United States)

    Balty, Cédric; Gayrard, Jean-Didier; Agnieray, Patrick

    2009-07-01

    To cope with the economical and technical evolutions of the communication market and to better compete with or complement terrestrial networks, satellite operators are requiring more flexible satellites. It allows a better fleet planning potential and back-up policy, a more standardized and efficient procurement process, mission adaptation to market evolution and the possibility of early entry in new markets. New technologies that are developed either for terrestrial networks or for space defense applications would become soon available to satellite and equipment manufacturers. A skilful mix of these new technologies with the older and more mature ones should boost satellite performances and bring flexibility to the new generation of communication satellites. This paper reviews the economical and technical environment of the space communication business for the next decade. It identifies the needs and levels of flexibility that are required by the market but also allowed by technologies, in both a top-down and bottom-up approach.

  15. Satellite services system overview

    Science.gov (United States)

    Rysavy, G.

    1982-01-01

    The benefits of a satellite services system and the basic needs of the Space Transportation System to have improved satellite service capability are identified. Specific required servicing equipment are discussed in terms of their technology development status and their operative functions. Concepts include maneuverable television systems, extravehicular maneuvering unit, orbiter exterior lighting, satellite holding and positioning aid, fluid transfer equipment, end effectors for the remote manipulator system, teleoperator maneuvering system, and hand and power tools.

  16. Real-time monitoring of seismic data using satellite telemetry

    Directory of Open Access Journals (Sweden)

    L. Merucci

    1997-06-01

    Full Text Available This article describes the ARGO Satellite Seismic Network (ARGO SSN as a reliable system for monitoring, collection, visualisation and analysis of seismic and geophysical low-frequency data, The satellite digital telemetry system is composed of peripheral geophysical stations, a centraI communications node (master sta- tion located in CentraI Italy, and a data collection and processing centre located at ING (Istituto Nazionale di Geofisica, Rome. The task of the peripheral stations is to digitalise and send via satellite the geophysical data collected by the various sensors to the master station. The master station receives the data and forwards them via satellite to the ING in Rome; it also performs alI the monitoring functions of satellite communications. At the data collection and processing centre of ING, the data are received and analysed in real time, the seismic events are identified and recorded, the low-frequency geophysical data are stored. In addition, the generaI sta- tus of the satellite network and of each peripheral station connected, is monitored. The procedure for analysjs of acquired seismic signals allows the automatic calculation of local magnitude and duration magnitude The communication and data exchange between the seismic networks of Greece, Spain and Italy is the fruit of a recent development in the field of technology of satellite transmission of ARGO SSN (project of European Community "Southern Europe Network for Analysis of Seismic Data"

  17. Mixed N-Heterocyclic Carbene-Bis(oxazolinyl)borato Rhodium and Iridium Complexes in Photochemical and Thermal Oxidative Addition Reactions

    Energy Technology Data Exchange (ETDEWEB)

    Xu, Songchen [Ames Laboratory; Manna, Kuntal [Ames Laboratory; Ellern, Arkady [Ames Laboratory; Sadow, Aaron D [Ames Laboratory

    2014-12-08

    In order to facilitate oxidative addition chemistry of fac-coordinated rhodium(I) and iridium(I) compounds, carbene–bis(oxazolinyl)phenylborate proligands have been synthesized and reacted with organometallic precursors. Two proligands, PhB(OxMe2)2(ImtBuH) (H[1]; OxMe2 = 4,4-dimethyl-2-oxazoline; ImtBuH = 1-tert-butylimidazole) and PhB(OxMe2)2(ImMesH) (H[2]; ImMesH = 1-mesitylimidazole), are deprotonated with potassium benzyl to generate K[1] and K[2], and these potassium compounds serve as reagents for the synthesis of a series of rhodium and iridium complexes. Cyclooctadiene and dicarbonyl compounds {PhB(OxMe2)2ImtBu}Rh(η4-C8H12) (3), {PhB(OxMe2)2ImMes}Rh(η4-C8H12) (4), {PhB(OxMe2)2ImMes}Rh(CO)2 (5), {PhB(OxMe2)2ImMes}Ir(η4-C8H12) (6), and {PhB(OxMe2)2ImMes}Ir(CO)2 (7) are synthesized along with ToMM(η4-C8H12) (M = Rh (8); M = Ir (9); ToM = tris(4,4-dimethyl-2-oxazolinyl)phenylborate). The spectroscopic and structural properties and reactivity of this series of compounds show electronic and steric effects of substituents on the imidazole (tert-butyl vs mesityl), effects of replacing an oxazoline in ToM with a carbene donor, and the influence of the donor ligand (CO vs C8H12). The reactions of K[2] and [M(μ-Cl)(η2-C8H14)2]2 (M = Rh, Ir) provide {κ4-PhB(OxMe2)2ImMes'CH2}Rh(μ-H)(μ-Cl)Rh(η2-C8H14)2 (10) and {PhB(OxMe2)2ImMes}IrH(η3-C8H13) (11). In the former compound, a spontaneous oxidative addition of a mesityl ortho-methyl to give a mixed-valent dirhodium species is observed, while the iridium compound forms a monometallic allyl hydride. Photochemical reactions of dicarbonyl compounds 5 and 7 result in C–H bond oxidative addition providing the compounds {κ4-PhB(OxMe2)2ImMes'CH2}RhH(CO) (12) and {PhB(OxMe2)2ImMes}IrH(Ph)CO (13). In 12, oxidative addition results in cyclometalation of the mesityl ortho-methyl similar to 10, whereas the iridium compound reacts with the benzene solvent to give a rare crystallographically characterized cis

  18. Study of LEO-SAT microwave link for broad-band mobile satellite communication system

    Science.gov (United States)

    Fujise, Masayuki; Chujo, Wataru; Chiba, Isamu; Furuhama, Yoji; Kawabata, Kazuaki; Konishi, Yoshihiko

    1993-01-01

    In the field of mobile satellite communications, a system based on low-earth-orbit satellites (LEO-SAT's) such as the Iridium system has been proposed. The LEO-SAT system is able to offer mobile telecommunication services in high-latitude areas. Rain degradation, fading and shadowing are also expected to be decreased when the system is operated at a high elevation angle. Furthermore, the propagation delay generated in the LEO-SAT system is less pronounced than that in the geostationary orbit satellite (GEO-SAT) system and, in voice services, the effect of the delay is almost negligible. We proposed a concept of a broad-band mobile satellite communication system with LEO-SAT's and Optical ISL. In that system, a fixed L-band (1.6/1.5 GHz) multibeam is used to offer narrow band service to the mobile terminals in the entire area covered by a LEO-SAT and steerable Ka-band (30/20 GHz) spot beams are used for the wide band service. In this paper, we present results of a study of LEO-SAT microwave link between a satellite and a mobile terminal for a broad-band mobile satellite communication system. First, the results of link budget calculations are presented and the antennas mounted on satellites are shown. For a future mobile antenna technology, we also show digital beamforming (DBF) techniques. DBF, together with modulation and/or demodulation, is becoming a key technique for mobile antennas with advanced functions such as antenna pattern calibration, correction, and radio interference suppression. In this paper, efficient DBF techniques for transmitting and receiving are presented. Furthermore, an adaptive array antenna system suitable for this LEO-SAT is presented.

  19. Hybrid white organic light-emitting devices based on phosphorescent iridium-benzotriazole orange-red and fluorescent blue emitters

    Energy Technology Data Exchange (ETDEWEB)

    Xia, Zhen-Yuan, E-mail: xiazhenyuan@hotmail.com [Key Laboratory for Advanced Materials and Institute of Fine Chemicals, East China University of Science and Technology, Shanghai 200237 (China); Su, Jian-Hua [Key Laboratory for Advanced Materials and Institute of Fine Chemicals, East China University of Science and Technology, Shanghai 200237 (China); Chang, Chi-Sheng; Chen, Chin H. [Display Institute, Microelectronics and Information Systems Research Center, National Chiao Tung University, Hsinchu, Taiwan 300 (China)

    2013-03-15

    We demonstrate that high color purity or efficiency hybrid white organic light-emitting devices (OLEDs) can be generated by integrating a phosphorescent orange-red emitter, bis[4-(2H-benzotriazol-2-yl)-N,N-diphenyl-aniline-N{sup 1},C{sup 3}] iridium acetylacetonate, Ir(TBT){sub 2}(acac) with fluorescent blue emitters in two different emissive layers. The device based on deep blue fluorescent material diphenyl-[4-(2-[1,1 Prime ;4 Prime ,1 Double-Prime ]terphenyl-4-yl-vinyl)-phenyl]-amine BpSAB and Ir(TBT){sub 2}(acac) shows pure white color with the Commission Internationale de L'Eclairage (CIE) coordinates of (0.33,0.30). When using sky-blue fluorescent dopant N,N Prime -(4,4 Prime -(1E,1 Prime E)-2,2 Prime -(1,4-phenylene)bis(ethene-2,1-diyl) bis(4,1-phenylene))bis(2-ethyl-6-methyl-N-phenylaniline) (BUBD-1) and orange-red phosphor with a color-tuning phosphorescent material fac-tris(2-phenylpyridine) iridium (Ir(ppy){sub 3} ), it exhibits peak luminance yield and power efficiency of 17.4 cd/A and 10.7 lm/W, respectively with yellow-white color and CIE color rendering index (CRI) value of 73. - Highlights: Black-Right-Pointing-Pointer An iridium-based orange-red phosphor Ir(TBT){sub 2}(acac) was applied in hybrid white OLEDs. Black-Right-Pointing-Pointer Duel- and tri-emitter WOLEDs were achieved with either high color purity or efficiency performance. Black-Right-Pointing-Pointer Peak luminance yield of tri-emitter WOLEDs was 17.4 cd/A with yellow-white color and color rendering index (CRI) value of 73.

  20. Satellite outreach in Asia and the Pacific.

    Science.gov (United States)

    1977-01-01

    Communication by satellite is rapidly changing information exchange in Asia, especially for rural areas. The integrated education planned for satellite networks includes family planning as part of general development. A series of conferences has already been held successfully via satellite for family planning associations who are members of the East and Southeast Asia and Oceania Region of the International Planned Parenthood Federation. These included a conference on nursing training. In India the Satellite Instructional Television Experiment (SITE) made history during its 1-year trial. By 1981 the entire nation is to be linked by satellite. The question is whether the television education will truly change rural life or whether it will become merely a diversion. In Indonesia, satellites were chosen as the fastest way to obtain interisland communication. The Domsat system links the entire 13,000-island archipelago and is already being used for emergency communications. The system, which was developed in 1 1/2 years by the Hughes Aircraft Corporation will be used for teaching basic health, hygiene, and family planning. It will be several years before Domsat is fully operational, but it bears watching.

  1. A highly selective and non-reaction based chemosensor for the detection of Hg2+ ions using a luminescent iridium(III complex.

    Directory of Open Access Journals (Sweden)

    Daniel Shiu-Hin Chan

    Full Text Available We report herein a novel luminescent iridium(III complex with two hydrophobic carbon chains as a non-reaction based chemosensor for the detection of Hg(2+ ions in aqueous solution (<0.002% of organic solvent attributed to the probe solution. Upon the addition of Hg(2+ ions, the emission intensity of the complex was significantly enhanced and this change could be monitored by the naked eye under UV irradiation. The iridium(III complex shows high specificity for Hg(2+ ions over eighteen other cations. The system is capable of detecting micromolar levels of Hg(2+ ions, which is within the range of many chemical systems.

  2. The brachytherapy with low dose-rate iridium for prostate cancer

    International Nuclear Information System (INIS)

    Momma, Tetsuo; Saito, Shiro; Ohki, Takahiro; Satoh, Hiroyuki; Toya, Kazuhito; Dokiya, Takushi; Murai, Masaru

    2000-01-01

    Brachytherapy as an option for the treatment of prostate cancer has been commonly performed in USA. As the permanent seeding of the radioactive materials is strictly restricted by the law in Japan, brachytherapy must be performed by the temporary implant. This treatment has been performed at a few facilities in Japan mostly using high dose-rate iridium. Only our facility has been using low dose-rate iridium (LDR-Ir) for prostate cancer. This study evaluates the clinical results of the treatment. Since December 1997 to December 1999, 26 patients with histologically diagnosed as prostate cancer (Stage B, 92%; Stage C, 8%) underwent brachytherapy. Twenty-two patients received brachytherapy alone, three were treated with a combination of brachytherapy and external beam radiotherapy (ERT) and one was treated with a combination of brachytherapy and neoadjuvant endocrine therapy. Patients ranged in age from 61 to 84 (median 76) years old. Treatment was initiated with perineal needle placement. From 10 to 14 needles were placed through the holes on the template which was fixed to the stabilizer of the transrectal ultrasound probe. After the needle placement, CT scan was performed to draw distribution curves for the treatment planning. LDR-Ir wires were introduced to the sheath and indwelled during the time calculated from dosimetry. Peripheral dose was 70 Gy for the monotherapy of brachytherapy. For the combination therapy, 40 Gy was given by brachytherapy and 36 Gy with ERT afterwards. LDR-Ir wires were removed after completion of the radiation and patients were followed with serum PSA level and annual biopsy. During 2 to 26 (median 12) months follow-up, 8 out of 9 patients with initial PSA level above 20 ng/ml showed PSA failure. All 13 patients with initial PSA level lower than 20 ng/ml were free from PSA failure. Eight out of 11 patients with Gleason's score 7 or higher showed PSA failure, and all 14 patients (including three patients with combined therapy) with

  3. User-friendly aerobic reductive alkylation of iridium(III) porphyrin chloride with potassium hydroxide: scope and mechanism.

    Science.gov (United States)

    Zuo, Huiping; Liu, Zhipeng; Yang, Wu; Zhou, Zhikuan; Chan, Kin Shing

    2015-12-21

    Alkylation of iridium 5,10,15,20-tetrakistolylporphyrinato carbonyl chloride, Ir(ttp)Cl(CO) (1), with 1°, 2° alkyl halides was achieved to give (ttp)Ir-alkyls in good yields under air and water compatible conditions by utilizing KOH as the cheap reducing agent. The reaction rate followed the order: RCl < RBr < RI (R = alkyl), and suggests an SN2 pathway by [Ir(I)(ttp)](-). Ir(ttp)-adamantyl was obtained under N2 when 1-bromoadamantane was utilized, which could only undergo bromine atom transfer pathway. Mechanistic investigations reveal a substrate dependent pathway of SN2 or halogen atom transfer.

  4. Muscle invasive bladder cancer treated by transurethral resection, followed by external beam radiation and interstitial iridium-192

    International Nuclear Information System (INIS)

    Wijnmaalen, Arendjan; Helle, Peter A.; Koper, Peter C.M.; Jansen, Peter P.; Hanssens, Patrick E.J.; Boeken Kruger, Cornelis G.G.; Putten, Wim L.J. van

    1996-01-01

    Purpose: In our center interstitial radiation has played an important role in the treatment of bladder cancer patients for over 40 years. Radium needles, that were initially used, were replaced by caesium needles in 1983, whereas the afterloading iridium wire technique was adopted in 1989. Patients with solitary tumors (T1, T2 and T3) with a surface diameter of < 5 cm are considered for interstitial radiation. In this study we report on the results of the afterloading iridium wire technique in patients with muscle invasive bladder cancer. Materials and Methods: From May 1989 to September 1993 interstitial radiation using iridium wires was part of the treatment in 46 patients with muscle invasive bladder cancer (37 T2, 9 T3). The mean age was 67 years. After transurethral resection of all visible tumor (if possible), in most cases 40 Gy (20 x 2.0 Gy, midplane dose) external beam radiation was delivered to the true pelvis, followed by 30 Gy interstitial radiation using iridium-192 wires covering the tumor area in the bladder. Results: After a median follow-up of 26 months, bladder relapses occurred in 7 patients. In 5 of them the tumor relapsed in the initial area, in 1 patient elsewhere in the bladder and in 1 patient tumor recurred in and outside the initial site. Recurrence was superficial (T1) in 4 patients. A relapse in the urethra was found once. Metastases developed in 13 patients, in 8 without bladder relapse. During the observation period 17 patients died, 13 due to bladder cancer. The actuarial bladder relapse-free survival at 4 years was 74% and 82% for T2 and T3 tumors, respectively. The actuarial distant metastases-free survival was 65% for both categories. No serious toxicity was recorded. Conclusion: In a selected group of patients with muscle invasive bladder cancer transurethral resection in combination with external beam and interstitial radiation provides an excellent opportunity to preserve the bladder with a high chance of success. Development of

  5. A Framework for Developing Artificial Intelligence for Autonomous Satellite Operations

    Science.gov (United States)

    Anderson, Jason L.; Kurfess, Franz J.; Puig-Suari, Jordi

    2009-09-01

    In the world of educational satellites, student teams manually conduct operations daily. Educational satellites typically travel in a Low Earth Orbit allowing communication for approximately thirty minutes each day. Manual operations during these times is manageable for student teams as the required manpower is minimal. The international Global Educational Network for Satellite Operations (GENSO), however, promises satellite contact upwards of sixteen hours per day by connecting earth stations globally through the Internet. This large increase in satellite communication time makes manual student operations unreasonable and alternatives must be explored. This paper introduces a framework to conduct autonomous satellite operations using different AI methodologies. This paper additionally demonstrates the framework's usability by introducing a sample rule-based implementation for Cal Poly's CubeSat, CP3.

  6. Development of a new osmium-191: Iridium-191m radionuclide generator: Final report

    International Nuclear Information System (INIS)

    Treves, S.; Packard, A.B.

    1986-01-01

    The use of iridium-191m (T/sub 1/2/ = 5s) for first-pass radionuclide angiography offers the potential advantages of lower patient radiation dose and the ability to obtain repeated studies without interference from the previously administered radioisotope. These potential advantages have been offset by the absence of satisfactory 191 Os-/sup 191m/Ir generators. The goal of this project was, therefore, the development of an 191 Os-/sup 191m/Ir generator that would be suitable for clinical use. This goal was first sought through modifications of an existing 191 Os-/sup 191m/Ir generator design (i.e., changes in the ion exchange material and eluent) but these changes did not lead to the required improvements. A new approach was then undertaken in which different chemical forms of the 191 Os parent were evaluated in prototype generators. The complex trans-dioxobisoxalatoosmate (VI) led to a generator with higher /sup 191m/Ir yield (25 to 30%/mL) and lower 191 Os breakthrough ( -4 %) with a more physiologically compatible eluent than had been previously achieved. Toxicity studies were conducted on the eluate and an IND subsequently obtained. While this is not a final solution to the problem of developing a clinically acceptable 191 Os-/sup 191m/Ir generator, the ''oxalate'' generator is the most significant improvement of the 191 Os-/sup 191m/Ir generator to date and will be used in an expanded program of clinical studies. 16 refs., 16 tabs

  7. Iridium-192 curietherapy for T1 and T2 epidermoid carcinomas of the floor of mouth

    International Nuclear Information System (INIS)

    Mazeron, J.J.; Grimard, L.; Raynal, M.; Haddad, E.; Piedbois, P.; Martin, M.; Marinello, G.; Nair, R.C.; Le Bourgeois, J.P.; Pierquin, B.

    1990-01-01

    From 1970 to 1986, 117 patients with T1 (47) or T2 (70) epidermoid carcinomas of the floor of the mouth (SCC) were treated by iridium-192 implantation (192 Ir). The dose was prescribed according to the Paris System and varied over those years. Follow-up information was available on 116 patients. There were 46 T1N0, 47 T2N0, and 23 T2N1-3. Neck management varied for the 93 N0 patients consisting of surveillance (24 T1, 17 T2) or elective neck dissection (22 T1:all pN-, 30 T2: 20 pN-, 10 pN+). Cause specific survival rates were 94% for T1N0, 61.5% for T2N0, and 28% for T2N1-3 at 5 years. Primary local control was 93.5%, 74.5%, and 65%, respectively, and 98%, 79%, and 65% after salvage. Patients with gingival extension or a tumor size over 3 cm (T2b) had a local control of 50% (9/18) and 58% (15/26), respectively. Nodal control was 93.5% for Stage I, 85% for Stage II, and 48% for T2N1-3 patients. There was no difference in nodal control with regard to treatment policy for Stage I-II patients. There were few complications including three deaths: two from surgery and one from 192 Ir. Nodal status, tumor size defined as T1, T2a (less than or equal to 3 cm), T2b (greater than 3 cm), and gingival extension were the only independent prognostic factors. The management of T1N0 and T2N0 SCC by 192 Ir to a dose of 65 or 70 Gy, using the Paris System, is recommended for lesions 3 cm or less and without gingival extension

  8. Theoretical characterization and design of highly efficient iridium (III) complexes bearing guanidinate ancillary ligand.

    Science.gov (United States)

    Ren, Xin-Yao; Wu, Yong; Wang, Li; Zhao, Liang; Zhang, Min; Geng, Yun; Su, Zhong-Min

    2014-06-01

    A density functional theory/time-depended density functional theory was used to investigate the synthesized guanidinate-based iridium(III) complex [(ppy)2Ir{(N(i)Pr)2C(NPh2)}] (1) and two designed derivatives (2 and 3) to determine the influences of different cyclometalated ligands on photophysical properties. Except the conventional discussions on geometric relaxations, absorption and emission properties, many relevant parameters, including spin-orbital coupling (SOC) matrix elements, zero-field-splitting parameters, radiative rate constants (kr) and so on were quantitatively evaluated. The results reveal that the replacement of the pyridine ring in the 2-phenylpyridine ligand with different diazole rings cannot only enlarge the frontier molecular orbital energy gaps, resulting in a blue-shift of the absorption spectra for 2 and 3, but also enhance the absorption intensity of 3 in the lower-energy region. Furthermore, it is intriguing to note that the photoluminescence quantum efficiency (ΦPL) of 3 is significantly higher than that of 1. This can be explained by its large SOC value(n=3-4) and large transition electric dipole moment (μS3), which could significantly contribute to a larger kr. Besides, compared with 1, the higher emitting energy (ET1) and smaller (2) value for 3 may lead to a smaller non-radiative decay rate. Additionally, the detailed results also indicate that compared to 1 with pyridine ring, 3 with imidazole ring performs a better hole injection ability. Therefore, the designed complex 3 can be expected as a promising candidate for highly efficient guanidinate-based phosphorescence emitter for OLEDs applications. Copyright © 2014 Elsevier Inc. All rights reserved.

  9. Strong ligand field effects of blue phosphorescent mono-cyclometalated iridium(III) complexes

    International Nuclear Information System (INIS)

    Ham, Ho Wan; Jung, Kyung Yoon; Kim, Young Sik

    2010-01-01

    A series of mono-cyclometalated blue phosphorescent iridium(III) complexes with two phosphines trans to each other and two cis-ancillary ligands, such as Ir(F 2 Meppy)(PPhMe 2 ) 2 (H)(Cl), [Ir(F 2 Meppy)(PPhMe 2 ) 2 (H)(NCMe)] + and Ir(F 2 Meppy)(PPhMe 2 ) 2 -(H)(CN), [F 2 Meppy = 2-(2',4'-difluorophenyl)-4-methyl-pyridine] were synthesized and studied to tune the phosphorescence wavelength to the deep blue region and to enhance the luminescence efficiencies. We investigate the electron-withdrawing capabilities of ancillary ligands using the DFT and TD-DFT calculations on the ground and excited states of the three complexes to gain insight into the factors responsible for the emission color change and the different luminescence efficiency. Reducing the molecular weight of phosphine ligand with PPhMe 2 leads to a strategy of the efficient deep blue organic light-emitting devices (OLED) by thermal processing instead of the solution processing. The electron-withdrawing difluoro group substituted on the phenyl ring and the cyano strong field ancillary ligand in the trans position to the carbon atom of phenyl ring increased HOMO-LUMO gap and achieved the hypsochromic shift in emission color. As a result, the maximum emission spectra of Ir(F 2 Meppy)(PPhMe 2 ) 2 (H)(Cl), [Ir(F 2 Meppy)(PPhMe 2 ) 2 (H)-(NCMe)] + and Ir(F 2 Meppy)(PPh-Me 2 ) 2 (H)(CN) were in the ranges of 446, 440, 439 nm, respectively.

  10. Strong ligand field effects of blue phosphorescent mono-cyclometalated iridium(III) complexes

    Energy Technology Data Exchange (ETDEWEB)

    Ham, Ho Wan [Department of Information Display, Hongik University, Seoul, 121-791 (Korea, Republic of); Jung, Kyung Yoon [International Design School for Advanced Studies, Hongik University, Seoul 121-791 (Korea, Republic of); Kim, Young Sik, E-mail: youngkim@hongik.ac.k [Department of Information Display, Hongik University, Seoul, 121-791 (Korea, Republic of)

    2010-09-01

    A series of mono-cyclometalated blue phosphorescent iridium(III) complexes with two phosphines trans to each other and two cis-ancillary ligands, such as Ir(F{sub 2}Meppy)(PPhMe{sub 2}){sub 2}(H)(Cl), [Ir(F{sub 2}Meppy)(PPhMe{sub 2}){sub 2}(H)(NCMe)]{sup +} and Ir(F{sub 2}Meppy)(PPhMe{sub 2}){sub 2}-(H)(CN), [F{sub 2}Meppy = 2-(2',4'-difluorophenyl)-4-methyl-pyridine] were synthesized and studied to tune the phosphorescence wavelength to the deep blue region and to enhance the luminescence efficiencies. We investigate the electron-withdrawing capabilities of ancillary ligands using the DFT and TD-DFT calculations on the ground and excited states of the three complexes to gain insight into the factors responsible for the emission color change and the different luminescence efficiency. Reducing the molecular weight of phosphine ligand with PPhMe{sub 2} leads to a strategy of the efficient deep blue organic light-emitting devices (OLED) by thermal processing instead of the solution processing. The electron-withdrawing difluoro group substituted on the phenyl ring and the cyano strong field ancillary ligand in the trans position to the carbon atom of phenyl ring increased HOMO-LUMO gap and achieved the hypsochromic shift in emission color. As a result, the maximum emission spectra of Ir(F{sub 2}Meppy)(PPhMe{sub 2}){sub 2}(H)(Cl), [Ir(F{sub 2}Meppy)(PPhMe{sub 2}){sub 2}(H)-(NCMe)]{sup +} and Ir(F{sub 2}Meppy)(PPh-Me{sub 2}){sub 2} (H)(CN) were in the ranges of 446, 440, 439 nm, respectively.

  11. Laminar iridium coating produced by pulse current electrodeposition from chloride molten salt

    Energy Technology Data Exchange (ETDEWEB)

    Zhu, Li’an, E-mail: mr_zla@163.com; Bai, Shuxin; Zhang, Hong; Ye, Yicong

    2013-10-01

    Due to the unique physical and chemical properties, Iridium (Ir) is one of the most promising oxidation-resistant coatings for refractory materials above 1800 °C in aerospace field. However, the Ir coatings prepared by traditional methods are composed of columnar grains throughout the coating thickness. The columnar structure of the coating is considered to do harm to its oxidation resistance. The laminar Ir coating is expected to have a better high-temperature oxidation resistance than the columnar Ir coating does. The pulse current electrodeposition, with three independent parameters: average current density (J{sub m}), duty cycle (R) and pulse frequency (f), is considered to be a promising method to fabricate layered Ir coating. In this study, laminar Ir coatings were prepared by pulse current electrodeposition in chloride molten salt. The morphology, roughness and texture of the coatings were determined by scanning electron microscope (SEM), profilometer and X-ray diffraction (XRD), respectively. The results showed that the laminar Ir coatings were composed of a nucleation layer with columnar structure and a growth layer with laminar structure. The top surfaces of the laminar Ir coatings consisted of cauliflower-like aggregates containing many fine grains, which were separated by deep grooves. The laminar Ir coating produced at the deposition condition of 20 mA/cm{sup 2} (J{sub m}), 10% (R) and 6 Hz (f) was quite smooth (R{sub a} 1.01 ± 0.09 μm) with extremely high degree of preferred orientation of 〈1 1 1〉, and its laminar structure was well developed with clear boundaries and uniform thickness of sub-layers.

  12. Satellite medical centers project

    Science.gov (United States)

    Aggarwal, Arvind

    2002-08-01

    World class health care for common man at low affordable cost: anywhere, anytime The project envisages to set up a national network of satellite Medical centers. Each SMC would be manned by doctors, nurses and technicians, six doctors, six nurses, six technicians would be required to provide 24 hour cover, each SMC would operate 24 hours x 7 days. It would be equipped with the Digital telemedicine devices for capturing clinical patient information and investigations in the form of voice, images and data and create an audiovisual text file - a virtual Digital patient. Through the broad band connectivity the virtual patient can be sent to the central hub, manned by specialists, specialists from several specialists sitting together can view the virtual patient and provide a specialized opinion, they can see the virtual patient, see the examination on line through video conference or even PCs, talk to the patient and the doctor at the SMC and controlle capturing of information during examination and investigations of the patient at the SMC - thus creating a virtual Digital consultant at the SMC. Central hub shall be connected to the doctors and consultants in remote locations or tertiary care hospitals any where in the world, thus creating a virtual hub the hierarchical system shall provide upgradation of knowledge to thedoctors in central hub and smc and thus continued medical education and benefit the patient thru the world class treatment in the smc located at his door step. SMC shall be set up by franchisee who shall get safe business opportunity with high returns, patients shall get Low cost user friendly worldclass health care anywhere anytime, Doctors can get better meaningful selfemplyment with better earnings, flexibility of working time and place. SMC shall provide a wide variety of services from primary care to world class Global consultation for difficult patients.

  13. Satellite Communications Industry

    Science.gov (United States)

    1993-04-01

    Ariane $loom SAJAC 1 Hughes Satellite Japan 06/94 $150m SAJAC 2 Hughes Satellite Japan -- (spare) $150m SatcomHl GE GE Americom /95 $50m SOLIDARIDAD ...1 Hughes SCT (Mexico) 11/93 Ariane $loom SOLIDARIDAD 2 Hughes SCT (Mexico) /94 $loom Superbird Al Loral Space Com Gp (Jap) 11/92 Ariane $175m

  14. Partnership via Satellite.

    Science.gov (United States)

    Powell, Marie Clare

    1980-01-01

    Segments of the 1980 National Catholic Educational Association (NCEA) conference were to be telecast nationally by satellite. The author briefly explains the satellite transmission process and advises Catholic educators on how to pick up the broadcast through their local cable television system. (SJL)

  15. The satellite situation center

    International Nuclear Information System (INIS)

    Teague, M.J.; Sawyer, D.M.; Vette, J.I.

    1982-01-01

    Considerations related to the early planning for the International Magnetospheric Study (IMS) took into account the desirability of an establishment of specific entities for generating and disseminating coordination information for both retrospective and predictive periods. The organizations established include the IMS/Satellite Situation Center (IMS/SSC) operated by NASA. The activities of the SSC are related to the preparation of reports on predicted and actually achieved satellite positions, the response to inquiries, the compilation of information on satellite experiments, and the issue of periodic status summaries. Attention is given to high-altitude satellite services, other correlative satellite services, non-IMS activities of the SSC, a summary of the SSC request activity, and post-IMS and future activities

  16. Simobiz-Simulation Tool to Study the Impact of Small Satellites in Mobile Market

    Science.gov (United States)

    Burlacu, M.-M.; Kohlenberg, J.; Prathaban, M.

    2008-08-01

    Interest in small satellites is growing fast world- wide. Businesses, governments, universities and other organizations around the world are starting their own small satellite programs. The surveys conducted by the space agencies and universities shows a promising increase in the use of small satellites for commercial applications. More number of operators offers or plans to offer mobile phone services by satellite. With the help of cost effective small satellite, mobile operators can be able to provide the services cheaper. Hence, it is always interesting to study the effect of low cost small satellite over the mobile market. In this article, we present SmartSim (Small Satellites Mobile Market Simulator) - the new module of Simobiz business simulation game, in which we have implemented two operators, a normal satellite operator and a nanosatellite operator, with specific terminals and services. Our main focus in this work is to understand the future market of small satellite in mobile telecommunication network.

  17. Grain growth behavior and high-temperature high-strain-rate tensile ductility of iridium alloy DOP-26

    International Nuclear Information System (INIS)

    McKamey, C.G.; Gubbi, A.N.; Lin, Y.; Cohron, J.W.; Lee, E.H.; George, E.P.

    1998-04-01

    This report summarizes results of studies conducted to date under the Iridium Alloy Characterization and Development subtask of the Radioisotope Power System Materials Production and Technology Program to characterize the properties of the new-process iridium-based DOP-26 alloy used for the Cassini space mission. This alloy was developed at Oak Ridge National Laboratory (ORNL) in the early 1980's and is currently used by NASA for cladding and post-impact containment of the radioactive fuel in radioisotope thermoelectric generator (RTG) heat sources which provide electric power for interplanetary spacecraft. Included within this report are data generated on grain growth in vacuum or low-pressure oxygen environments; a comparison of grain growth in vacuum of the clad vent set cup material with sheet material; effect of grain size, test temperature, and oxygen exposure on high-temperature high-strain-rate tensile ductility; and grain growth in vacuum and high-temperature high-strain-rate tensile ductility of welded DOP-26. The data for the new-process material is compared to available old-process data

  18. Dosimetry of wires and single ribbons of Iridium 192; Dosimetria de alambres y ribbons individuales de Iridio-192

    Energy Technology Data Exchange (ETDEWEB)

    Mazzucco, L.D. [Centro Medico Nuclear S.R.L. San Juan (Argentina)

    1998-12-31

    The objective of this work is in order to present in table formats the dosimetry of wires and single ribbons of Iridium with lengths 1-12 cm for each one linear source along the bisector which is perpendicular at tissue sources (water) computed for linear activity 1 mCi/cm in the case of wires, and 1 mCi/seed for ribbons. The above tables are of direct use, adaptable at particular cases so they facilitate logarithmic graphics of doses in function of the distance for interpolation and use in the treatments planning. It was shown that for two sources with identical linear activity and total length, one of the equidistant seeds at 1 cm (ribbon) and one wire on the other hand, the differences in dose rates in near positions can be about the 15% so corroborating that it is not possible to use wire tables for seeds neither vice versa. Moreover it was elaborated tables of practical direct use for dose rate in water at c Gy/hr for wires and Ribbons 1-12 cm length and from 0.5-10 cm of distance in the perpendicular bisector at the Iridium implant. (Author)

  19. Limited external irradiation and interstitial 192iridium implant in the treatment of squamous cell carcinoma of the tonsillar region

    International Nuclear Information System (INIS)

    Puthawala, A.A.; Syed, A.M.; Eads, D.L.; Neblett, D.; Gillin, L.; Gates, T.C.

    1985-01-01

    Between January 1976 and March 1982, 80 patients with histologically proven diagnosis of squamous cell carcinoma of the tonsillar region were treated with definitive radiotherapy. Sixty-five (81%) of these patients had locally advanced tumors (Stage III and IV); 49% of patients had clinically palpable cervical lymphadenopathy. All patients received a combined external megavoltage and interstitial irradiation. The dose of external irradiation was limited to 4500-5000 cGy over 41/2 to 51/2 weeks. This was followed by interstitial 192 iridium implants to doses of 2000-2500 cGy in 50-60 hours for T1, T2 lesions and 3000-4000 cGy in 60-100 hours for T3, T4 lesions. The neck masses were also separately implanted to deliver additional doses of 2000-4000 cGy in 50-80 hours. Overall local tumor control was observed in 84% of patients with a minimum follow-up period of 2 years. An absolute 3-year disease free survival of the entire group was 72%. Treatment related complications such as soft tissue necrosis or osteoradionecrosis occurred in 6% (5/80) of patients. The salvage of neck failures and local failures was possible in 78 and 38% of patients, respectively, either by surgery or by re-irradiation employing interstitial 192 iridium implants. Functional and esthetic integrity was well preserved in most cases

  20. Synthesis of a red electrophosphorescent heteroleptic iridium complex and its application in efficient polymer light-emitting diodes

    International Nuclear Information System (INIS)

    Zhang Xiuju; Xu Yunhua; Sun Yiheng; Shi Huahong; Zhu Xuhui; Cao Yong

    2007-01-01

    The preparation and characterization of a heteroleptic iridium complex [2-(benzo[b]thiophen-2-yl)pyridine]Ir(III)[2-(4H-1,2,4-triazol-3-yl) pyridine] [(Btp) 2 Ir(PZ)] were reported (2-(benzo[b]thiophen-2-yl)pyridine = Btp; 2-(4H-1,2,4-triazol-3-yl)pyridine = PZ). Electrophosphorescence was investigated in the device structure [indium-tin-oxide (ITO)/poly(ethlenedioxythiophene) (PEDOT)/poly(vinylcarbazole)(PVK)/Poly(9,9-dioctylfluorenyl-2,7-diyl) end capped with dimethylphenyl (PFO): (Btp) 2 Ir(PZ)/Ba/Al] by using this iridium complex as guest and PFO as host. The red electrophosphorescent devices showed a peak emission at approximately 604 nm and shoulder at 654 nm with the Commission International de'Eclairage (CIE) coordinates of (0.64, 0.35) and external quantum efficiency of 7.7% at a doping concentration of 8 wt.% without an electron-transporting material in the emitting layer