WorldWideScience

Sample records for ir spectral energy

  1. HERUS: the far-IR/submm spectral energy distributions of local ULIRGs and photometric atlas

    Science.gov (United States)

    Clements, D. L.; Pearson, C.; Farrah, D.; Greenslade, J.; Bernard-Salas, Jeronimo; González-Alfonso, E.; Afonso, J.; Efstathiou, A.; Rigopoulou, D.; Lebouteiller, V.; Hurley, P. D.; Spoon, H.

    2018-04-01

    We present the Herschel-SPIRE photometric atlas for a complete flux limited sample of 43 local ultraluminous infrared galaxies (ULIRGs), selected at 60 μm by IRAS, as part of the HERschel ULIRG Survey (HERUS). Photometry observations were obtained using the SPIRE instrument at 250, 350, and 500 μm. We describe these observations, present the results, and combine the new observations with data from IRAS to examine the far-infrared spectral energy distributions (SEDs) of these sources. We fit the observed SEDs of HERUS objects with a simple parametrized modified blackbody model, where temperature and emissivity β are free parameters. We compare the fitted values to those of non-ULIRG local galaxies, and find, in agreement with earlier results, that HERUS ULIRGs have warmer dust (median temperature T = 37.9 ± 4.7 K compared to 21.3 ± 3.4 K) but a similar β distribution (median β = 1.7 compared to 1.8) to the Herschel reference sample (HRS, Cortese et al. 2014) galaxies. Dust masses are found to be in the range of 107.5-109 M⊙, significantly higher than that of HRS sources. We compare our results for local ULIRGs with higher redshift samples selected at 250 and 850 μm. These latter sources generally have cooler dust and/or redder 100-to-250 μm colours than our 60 μm-selected ULIRGs. We show that this difference may in part be the result of the sources being selected at different wavelengths rather than being a simple indication of rapid evolution in the properties of the population.

  2. Camouflage in thermal IR: spectral design

    Science.gov (United States)

    Pohl, Anna; Fagerström, Jan; Kariis, Hans; Lindell, Roland; Hallberg, Tomas; Högström, Herman

    2016-10-01

    In this work a spectral designed coating from SPECTROGON is evaluated. Spectral design in this case means that the coating has a reflectivity equal to one at 3-5 and 8-12 microns were sensors operate and a much lower reflectivity in the other wave length regions. Three boxes are evaluated: one metallic, one black-body and one with a spectral designed surface, all with a 15 W radiator inside the box. It is shown that the box with the spectral designed surface can combine the two good characteristics of the other boxes: low signature from the metallic box and reasonable inside temperature from the black-body box. The measurements were verified with calculations using RadThermIR.

  3. UV TO FAR-IR CATALOG OF A GALAXY SAMPLE IN NEARBY CLUSTERS: SPECTRAL ENERGY DISTRIBUTIONS AND ENVIRONMENTAL TRENDS

    Energy Technology Data Exchange (ETDEWEB)

    Hernandez-Fernandez, Jonathan D.; Iglesias-Paramo, J.; Vilchez, J. M., E-mail: jonatan@iaa.es [Instituto de Astrofisica de Andalucia, Glorieta de la Astronomia s/n, 18008 Granada (Spain)

    2012-03-01

    In this paper, we present a sample of cluster galaxies devoted to study the environmental influence on the star formation activity. This sample of galaxies inhabits in clusters showing a rich variety in their characteristics and have been observed by the SDSS-DR6 down to M{sub B} {approx} -18, and by the Galaxy Evolution Explorer AIS throughout sky regions corresponding to several megaparsecs. We assign the broadband and emission-line fluxes from ultraviolet to far-infrared to each galaxy performing an accurate spectral energy distribution for spectral fitting analysis. The clusters follow the general X-ray luminosity versus velocity dispersion trend of L{sub X} {proportional_to} {sigma}{sup 4.4}{sub c}. The analysis of the distributions of galaxy density counting up to the 5th nearest neighbor {Sigma}{sub 5} shows: (1) the virial regions and the cluster outskirts share a common range in the high density part of the distribution. This can be attributed to the presence of massive galaxy structures in the surroundings of virial regions. (2) The virial regions of massive clusters ({sigma}{sub c} > 550 km s{sup -1}) present a {Sigma}{sub 5} distribution statistically distinguishable ({approx}96%) from the corresponding distribution of low-mass clusters ({sigma}{sub c} < 550 km s{sup -1}). Both massive and low-mass clusters follow a similar density-radius trend, but the low-mass clusters avoid the high density extreme. We illustrate, with ABELL 1185, the environmental trends of galaxy populations. Maps of sky projected galaxy density show how low-luminosity star-forming galaxies appear distributed along more spread structures than their giant counterparts, whereas low-luminosity passive galaxies avoid the low-density environment. Giant passive and star-forming galaxies share rather similar sky regions with passive galaxies exhibiting more concentrated distributions.

  4. Room temperature mid-IR single photon spectral imaging

    DEFF Research Database (Denmark)

    Dam, Jeppe Seidelin; Tidemand-Lichtenberg, Peter; Pedersen, Christian

    2012-01-01

    Spectral imaging and detection of mid-infrared (mid-IR) wavelengths are emerging as an enabling technology of great technical and scientific interest; primarily because important chemical compounds display unique and strong mid-IR spectral fingerprints revealing valuable chemical information. Whi...... 20 % for polarized incoherent light at 3 \\mum. The proposed method is relevant for existing and new mid-IR applications like gas analysis and medical diagnostics....

  5. Constraining Cometary Crystal Shapes from IR Spectral Features

    Science.gov (United States)

    Wooden, D. H.; Lindsay, S.; Harker, D. E.; Kelley, M. S.; Woodward, C. E.; Murphy, J. R.

    2013-12-01

    A major challenge in deriving the silicate mineralogy of comets is ascertaining how the anisotropic nature of forsterite crystals affects the spectral features' wavelength, relative intensity, and asymmetry. Forsterite features are identified in cometary comae near 10, 11.05-11.2, 16, 19, 23.5, 27.5 and 33 μm [1-10], so accurate models for forsterite's absorption efficiency (Qabs) are a primary requirement to compute IR spectral energy distributions (SEDs, λFλ vs. λ) and constrain the silicate mineralogy of comets. Forsterite is an anisotropic crystal, with three crystallographic axes with distinct indices of refraction for the a-, b-, and c-axis. The shape of a forsterite crystal significantly affects its spectral features [13-16]. We need models that account for crystal shape. The IR absorption efficiencies of forsterite are computed using the discrete dipole approximation (DDA) code DDSCAT [11,12]. Starting from a fiducial crystal shape of a cube, we systematically elongate/reduce one of the crystallographic axes. Also, we elongate/reduce one axis while the lengths of the other two axes are slightly asymmetric (0.8:1.2). The most significant grain shape characteristic that affects the crystalline spectral features is the relative lengths of the crystallographic axes. The second significant grain shape characteristic is breaking the symmetry of all three axes [17]. Synthetic spectral energy distributions using seven crystal shape classes [17] are fit to the observed SED of comet C/1995 O1 (Hale-Bopp). The Hale-Bopp crystalline residual better matches equant, b-platelets, c-platelets, and b-columns spectral shape classes, while a-platelets, a-columns and c-columns worsen the spectral fits. Forsterite condensation and partial evaporation experiments demonstrate that environmental temperature and grain shape are connected [18-20]. Thus, grain shape is a potential probe for protoplanetary disk temperatures where the cometary crystalline forsterite formed. The

  6. Mid-Infrared Spectral Properties of IR QSOs

    International Nuclear Information System (INIS)

    Xia, X. Y.; Cao, C.; Mao, S.; Deng, Z. G.

    2008-01-01

    We analyse mid-infrared (MIR) spectroscopic properties for 19 ultra-luminous infrared quasars (IR QSOs) in the local universe based on the spectra from the Infrared Spectrograph on board the Spitzer Space Telescope. The MIR properties of IR QSOs are compared with those of optically-selected Palomar-Green QSOs (PG QSOs) and ultra-luminous infrared galaxies (ULIRGs). The average MIR spectral features from ∼5 to 30 μm, including the spectral slopes, 6.2 μm PAH emission strengths and [NeII] 12.81 μm luminosities of IR QSOs, differ from those of PG QSOs. In contrast, IR QSOs and ULIRGs have comparable PAH and [NeII] luminosities. These results are consistent with IR QSOs being at a transitional stage from ULIRGs to classical QSOs. We also find the correlation between the EW (PAH 6.2 μm) and outflow velocities suggests that star formation activities are suppressed by feedback from AGNs and/or supernovae.

  7. IR spectral analysis for the diagnostics of crust earthquake precursors

    Directory of Open Access Journals (Sweden)

    R. M. Umarkhodgaev

    2012-11-01

    Full Text Available Some possible physical processes are analysed that cause, under the condition of additional ionisation in a pre-breakdown electric field, emissions in the infrared (IR interval. The atmospheric transparency region of the IR spectrum at wavelengths of 7–15 μm is taken into account. This transparency region corresponds to spectral lines of small atmospheric constituents like CH4, CO2, N2O, NO2, NO, and O3. The possible intensities of the IR emissions observable in laboratories and in nature are estimated. The acceleration process of the electrons in the pre-breakdown electrical field before its adhesion to the molecules is analyzed. For daytime conditions, modifications of the adsorption spectra of the scattered solar emissions are studied; for nighttime, variations of emission spectra may be used for the analysis.

  8. IR spectral analysis for the diagnostics of crust earthquake precursors

    Science.gov (United States)

    Umarkhodgaev, R. M.; Liperovsky, V. A.; Mikhailin, V. V.; Meister, C.-V.; Naumov, D. Ju

    2012-04-01

    In regions of future earthquakes, a few days before the seismic shock, the emanation of radon and hydrogen is being observed, which causes clouds of increased ionisation in the atmosphere. In the present work the possible diagnostics of these clouds using infrared (IR) spectroscopy is considered, which may be important and useful for the general geophysical system of earthquake prediction and the observation of industrial emissions of radioactive materials into the atmosphere. Some possible physical processes are analysed, which cause, under the condition of additional ionisation in a pre-breakdown electrical field, emissions in the IR interval. In doing so, the transparency region of the IR spectrum at wavelengths of 7-15 μm is taken into account. This transparency region corresponds to spectral lines of small atmospheric constituents like CH4, CO2, N2O, NO2, NO, and O3. The possible intensities of the IR emissions observable in laboratories and in nature are estimated. The acceleration process of the electrons in the pre-breakdown electrical field before its adhesion to the molecules is analysed. The laboratory equipment for the investigation of the IR absorption spectrum is constructed for the cases of normal and decreased atmospheric pressures. The syntheses of ozone and nitrous oxides are performed in the barrier discharge. It is studied if the products of the syntheses may be used to model atmospheric processes where these components take part. Spectra of products of the syntheses in the wavelength region of 2-10 μm are observed and analysed. A device is created for the syntheses and accumulation of nitrous oxides. Experiments to observe the IR-spectra of ozone and nitrous oxides during the syntheses and during the further evolution of these molecules are performed. For the earthquake prediction, practically, the investigation of emission spectra is most important, but during the laboratory experiments, the radiation of the excited molecules is shifted by a

  9. Metallicity and the spectral energy distribution and spectral types of dwarf O-stars

    NARCIS (Netherlands)

    Mokiem, MR; Martin-Hernandez, NL; Lenorzer, A; de Koter, A; Tielens, AGGA

    We present a systematic study of the effect of metallicity on the stellar spectral energy distribution (SED) of 0 main sequence (dwarf) stars, focussing on the hydrogen and helium ionizing continua, and on the optical and near-IR lines used for spectral classification. The spectra are based on

  10. Metallicity and the spectral energy distribution and spectral types of dwarf O-stars

    NARCIS (Netherlands)

    Mokiem, M.R.; Martín-Hernández, N.L.; Lenorzer, A.; de Koter, A.; Tielens, A.G.G.M.

    2004-01-01

    We present a systematic study of the effect of metallicity on the stellar spectral energy distribution (SED) of O main sequence (dwarf) stars, focussing on the hydrogen and helium ionizing continua, and on the optical and near-IR lines used for spectral classification. The spectra are based on

  11. Spectrally selective solar energy materials

    International Nuclear Information System (INIS)

    Sikkens, M.

    1981-01-01

    The performance and properties of spectrally selective materials are considered and, in particular, the selective absorption of solar radiation by free electrons is discussed, both in a homogeneous material in which these electrons are strongly scattered, and in a composite material consisting of small metal particles in a dielectric host. Such materials can be used as selective absorbers if they are deposited as a thin film onto a metal substrate, the latter providing the required low emittance. This type of selective surfaces is produced by reactive sputtering of Ni in an Ar/CH 4 gas mixture. This method can yield Ni films with a considerable carbon concentration. The carbon concentration can be varied over a wide range by adjusting the partial methane pressure. The associated experimental techniques are discussed. As the carbon concentration increases, the structure of the films changes from a Ni phase in which carbon is dissolved, via an intermediate Ni 3 C phase into an amorphous carbon phase with a high electrical resistivity in which small nickel particles are embedded. Both mechanisms of selective absorption by free electrons are observed and are found to be well described by rather simple models. The best selectivity is obtained at high carbon concentrations where the films consist of nickel particles in carbon. Depending on the film thickness and the substrate material, the solar absorptance varies between 0.78 and 0.90, while the thermal emittance varies between 0.025 and 0.04. Since the films are found to be stable at 400 0 C in vacuum, it appears that these films are good candidates for application in photothermal solar energy conversion at temperature levels around 200 0 C and higher. (Auth.)

  12. Identification of mineral compositions in some renal calculi by FT Raman and IR spectral analysis

    Science.gov (United States)

    Tonannavar, J.; Deshpande, Gouri; Yenagi, Jayashree; Patil, Siddanagouda B.; Patil, Nikhil A.; Mulimani, B. G.

    2016-02-01

    We present in this paper accurate and reliable Raman and IR spectral identification of mineral constituents in nine samples of renal calculi (kidney stones) removed from patients suffering from nephrolithiasis. The identified mineral components include Calcium Oxalate Monohydrate (COM, whewellite), Calcium Oxalate Dihydrate (COD, weddellite), Magnesium Ammonium Phosphate Hexahydrate (MAPH, struvite), Calcium Hydrogen Phosphate Dihydrate (CHPD, brushite), Pentacalcium Hydroxy Triphosphate (PCHT, hydroxyapatite) and Uric Acid (UA). The identification is based on a satisfactory assignment of all the observed IR and Raman bands (3500-400 cm- 1) to chemical functional groups of mineral components in the samples, aided by spectral analysis of pure materials of COM, MAPH, CHPD and UA. It is found that the eight samples are composed of COM as the common component, the other mineral species as common components are: MAPH in five samples, PCHT in three samples, COD in three samples, UA in three samples and CHPD in two samples. One sample is wholly composed of UA as a single component; this inference is supported by the good agreement between ab initio density functional theoretical spectra and experimental spectral measurements of both sample and pure material. A combined application of Raman and IR techniques has shown that, where the IR is ambiguous, the Raman analysis can differentiate COD from COM and PCHT from MAPH.

  13. Identification of mineral compositions in some renal calculi by FT Raman and IR spectral analysis.

    Science.gov (United States)

    Tonannavar, J; Deshpande, Gouri; Yenagi, Jayashree; Patil, Siddanagouda B; Patil, Nikhil A; Mulimani, B G

    2016-02-05

    We present in this paper accurate and reliable Raman and IR spectral identification of mineral constituents in nine samples of renal calculi (kidney stones) removed from patients suffering from nephrolithiasis. The identified mineral components include Calcium Oxalate Monohydrate (COM, whewellite), Calcium Oxalate Dihydrate (COD, weddellite), Magnesium Ammonium Phosphate Hexahydrate (MAPH, struvite), Calcium Hydrogen Phosphate Dihydrate (CHPD, brushite), Pentacalcium Hydroxy Triphosphate (PCHT, hydroxyapatite) and Uric Acid (UA). The identification is based on a satisfactory assignment of all the observed IR and Raman bands (3500-400c m(-1)) to chemical functional groups of mineral components in the samples, aided by spectral analysis of pure materials of COM, MAPH, CHPD and UA. It is found that the eight samples are composed of COM as the common component, the other mineral species as common components are: MAPH in five samples, PCHT in three samples, COD in three samples, UA in three samples and CHPD in two samples. One sample is wholly composed of UA as a single component; this inference is supported by the good agreement between ab initio density functional theoretical spectra and experimental spectral measurements of both sample and pure material. A combined application of Raman and IR techniques has shown that, where the IR is ambiguous, the Raman analysis can differentiate COD from COM and PCHT from MAPH. Copyright © 2015 Elsevier B.V. All rights reserved.

  14. Characterization of protein and carbohydrate mid-IR spectral features in crop residues

    Science.gov (United States)

    Xin, Hangshu; Zhang, Yonggen; Wang, Mingjun; Li, Zhongyu; Wang, Zhibo; Yu, Peiqiang

    2014-08-01

    To the best of our knowledge, a few studies have been conducted on inherent structure spectral traits related to biopolymers of crop residues. The objective of this study was to characterize protein and carbohydrate structure spectral features of three field crop residues (rice straw, wheat straw and millet straw) in comparison with two crop vines (peanut vine and pea vine) by using Fourier transform infrared spectroscopy (FTIR) technique with attenuated total reflectance (ATR). Also, multivariate analyses were performed on spectral data sets within the regions mainly related to protein and carbohydrate in this study. The results showed that spectral differences existed in mid-IR peak intensities that are mainly related to protein and carbohydrate among these crop residue samples. With regard to protein spectral profile, peanut vine showed the greatest mid-IR band intensities that are related to protein amide and protein secondary structures, followed by pea vine and the rest three field crop straws. The crop vines had 48-134% higher spectral band intensity than the grain straws in spectral features associated with protein. Similar trends were also found in the bands that are mainly related to structural carbohydrates (such as cellulosic compounds). However, the field crop residues had higher peak intensity in total carbohydrates region than the crop vines. Furthermore, spectral ratios varied among the residue samples, indicating that these five crop residues had different internal structural conformation. However, multivariate spectral analyses showed that structural similarities still exhibited among crop residues in the regions associated with protein biopolymers and carbohydrate. Further study is needed to find out whether there is any relationship between spectroscopic information and nutrition supply in various kinds of crop residue when fed to animals.

  15. Innovative monolithic detector for tri-spectral (THz, IR, Vis) imaging

    Science.gov (United States)

    Pocas, S.; Perenzoni, M.; Massari, N.; Simoens, F.; Meilhan, J.; Rabaud, W.; Martin, S.; Delplanque, B.; Imperinetti, P.; Goudon, V.; Vialle, C.; Arnaud, A.

    2012-10-01

    Fusion of multispectral images has been explored for many years for security and used in a number of commercial products. CEA-Leti and FBK have developed an innovative sensor technology that gathers monolithically on a unique focal plane arrays, pixels sensitive to radiation in three spectral ranges that are terahertz (THz), infrared (IR) and visible. This technology benefits of many assets for volume market: compactness, full CMOS compatibility on 200mm wafers, advanced functions of the CMOS read-out integrated circuit (ROIC), and operation at room temperature. The ROIC houses visible APS diodes while IR and THz detections are carried out by microbolometers collectively processed above the CMOS substrate. Standard IR bolometric microbridges (160x160 pixels) are surrounding antenna-coupled bolometers (32X32 pixels) built on a resonant cavity customized to THz sensing. This paper presents the different technological challenges achieved in this development and first electrical and sensitivity experimental tests.

  16. Spectral Confirmation of New Galactic LBV and WN Stars Associated With Mid-IR Nebulae

    Science.gov (United States)

    Stringfellow, Guy; Gvaramadze, Vasilii V.

    2014-08-01

    Luminous Blue Variable (LBV) stars represent an extremely rare class and short-lived phase in the lives of very luminous massive stars with high mass loss rates. Extragalactic LBVs are responsible for producing false supernovae (SN), the SN Impostors, and have been directly linked with the progenitors of actual SN, indicating the LBV phase can be a final endpoint for massive star evolution. Yet only a few confirmed LBVs have been identified in the Galaxy. Their stellar evolution is poorly constrained by observations, and the physical reason for their unstable nature, both in terms of moderate spectral and photometric variability of a few magnitudes and the giant eruptions a la η Car that rival SN explosions, remains a mystery. Newly discovered mid-IR shells act as signposts, pointing to the central massive stars (LBV and Wolf-Rayet [WR] stars) that produced them. We have undertaken a spectroscopic survey of possible progenitor stars within these shells and are discovering that many are LBVs and WN-type WR transitional stars. We propose to extend this IR spectral survey to the south to search for new progenitor stars associated with dozens of newly identified shells. This survey should result in a substantial increase of new WRs and candidate LBVs for continued future study. Spectral analysis will yield new insights into the winds and physical properties of these rare and important objects, and lead to a better understanding of the physics driving giant eruptions.

  17. Near-IR Spectral Imaging of Semiconductor Absorption Sites in Integrated Circuits

    Directory of Open Access Journals (Sweden)

    E. C. Samson

    2004-12-01

    Full Text Available We derive spectral maps of absorption sites in integrated circuits (ICs by varying the wavelength of the optical probe within the near-IR range. This method has allowed us to improve the contrast of the acquired images by revealing structures that have a different optical absorption from neighboring sites. A false color composite image from those acquired at different wavelengths is generated from which the response of each semiconductor structure can be deduced. With the aid of the spectral maps, nonuniform absorption was also observed in a semiconductor structure located near an electrical overstress defect. This method may prove important in failure analysis of ICs by uncovering areas exhibiting anomalous absorption, which could improve localization of defective edifices in the semiconductor parts of the microchip

  18. SNSEDextend: SuperNova Spectral Energy Distributions extrapolation toolkit

    Science.gov (United States)

    Pierel, Justin D. R.; Rodney, Steven A.; Avelino, Arturo; Bianco, Federica; Foley, Ryan J.; Friedman, Andrew; Hicken, Malcolm; Hounsell, Rebekah; Jha, Saurabh W.; Kessler, Richard; Kirshner, Robert; Mandel, Kaisey; Narayan, Gautham; Filippenko, Alexei V.; Scolnic, Daniel; Strolger, Louis-Gregory

    2018-05-01

    SNSEDextend extrapolates core-collapse and Type Ia Spectral Energy Distributions (SEDs) into the UV and IR for use in simulations and photometric classifications. The user provides a library of existing SED templates (such as those in the authors' SN SED Repository) along with new photometric constraints in the UV and/or NIR wavelength ranges. The software then extends the existing template SEDs so their colors match the input data at all phases. SNSEDextend can also extend the SALT2 spectral time-series model for Type Ia SN for a "first-order" extrapolation of the SALT2 model components, suitable for use in survey simulations and photometric classification tools; as the code does not do a rigorous re-training of the SALT2 model, the results should not be relied on for precision applications such as light curve fitting for cosmology.

  19. Panchromatic spectral energy distributions of Herschel sources

    Science.gov (United States)

    Berta, S.; Lutz, D.; Santini, P.; Wuyts, S.; Rosario, D.; Brisbin, D.; Cooray, A.; Franceschini, A.; Gruppioni, C.; Hatziminaoglou, E.; Hwang, H. S.; Le Floc'h, E.; Magnelli, B.; Nordon, R.; Oliver, S.; Page, M. J.; Popesso, P.; Pozzetti, L.; Pozzi, F.; Riguccini, L.; Rodighiero, G.; Roseboom, I.; Scott, D.; Symeonidis, M.; Valtchanov, I.; Viero, M.; Wang, L.

    2013-03-01

    Combining far-infrared Herschel photometry from the PACS Evolutionary Probe (PEP) and Herschel Multi-tiered Extragalactic Survey (HerMES) guaranteed time programs with ancillary datasets in the GOODS-N, GOODS-S, and COSMOS fields, it is possible to sample the 8-500 μm spectral energy distributions (SEDs) of galaxies with at least 7-10 bands. Extending to the UV, optical, and near-infrared, the number of bands increases up to 43. We reproduce the distribution of galaxies in a carefully selected restframe ten colors space, based on this rich data-set, using a superposition of multivariate Gaussian modes. We use this model to classify galaxies and build median SEDs of each class, which are then fitted with a modified version of the magphys code that combines stellar light, emission from dust heated by stars and a possible warm dust contribution heated by an active galactic nucleus (AGN). The color distribution of galaxies in each of the considered fields can be well described with the combination of 6-9 classes, spanning a large range of far- to near-infrared luminosity ratios, as well as different strength of the AGN contribution to bolometric luminosities. The defined Gaussian grouping is used to identify rare or odd sources. The zoology of outliers includes Herschel-detected ellipticals, very blue z ~ 1 Ly-break galaxies, quiescent spirals, and torus-dominated AGN with star formation. Out of these groups and outliers, a new template library is assembled, consisting of 32 SEDs describing the intrinsic scatter in the restframe UV-to-submm colors of infrared galaxies. This library is tested against L(IR) estimates with and without Herschel data included, and compared to eightother popular methods often adopted in the literature. When implementing Herschel photometry, these approaches produce L(IR) values consistent with each other within a median absolute deviation of 10-20%, the scatter being dominated more by fine tuning of the codes, rather than by the choice of

  20. Radical protection by differently composed creams in the UV/VIS and IR spectral ranges.

    Science.gov (United States)

    Meinke, Martina C; Syring, Felicia; Schanzer, Sabine; Haag, Stefan F; Graf, Rüdiger; Loch, Manuela; Gersonde, Ingo; Groth, Norbert; Pflücker, Frank; Lademann, Jürgen

    2013-01-01

    Modern sunscreens are well suited to provide sufficient protection in the UV range because the filter substances absorb or scatter UV radiation. Although up to 50% of radicals are formed in the visible and infrared spectral range during solar radiation protection strategies are not provided in this range. Previous investigations of commercially available products have shown that in addition to physical filters, antioxidants (AO) are necessary to provide protective effects in the infrared range by neutralizing already formed radicals. In this study, the efficacy of filter substances and AO to reduce radical formation in both spectral ranges was investigated after UV/VIS or IR irradiation. Optical properties and radical protection were determined for the investigated creams. It was found that organic UV filters lower radical formation in the UV/VIS range to 35% compared to untreated skin, independent of the presence of AO. Further reduction to 14% was reached by addition of 2% physical filters, whereas physical filters alone were ineffective in the UV/VIS range due to the low concentration. In contrast, this filter type reduced radical formation in the IR range significantly to 65%; similar effects were aroused after application of AO. Sunscreens which contain organic UV filters, physical filters and AO ensure protection in the complete solar spectrum. © 2013 The American Society of Photobiology.

  1. Similarity maps and hierarchical clustering for annotating FT-IR spectral images.

    Science.gov (United States)

    Zhong, Qiaoyong; Yang, Chen; Großerüschkamp, Frederik; Kallenbach-Thieltges, Angela; Serocka, Peter; Gerwert, Klaus; Mosig, Axel

    2013-11-20

    Unsupervised segmentation of multi-spectral images plays an important role in annotating infrared microscopic images and is an essential step in label-free spectral histopathology. In this context, diverse clustering approaches have been utilized and evaluated in order to achieve segmentations of Fourier Transform Infrared (FT-IR) microscopic images that agree with histopathological characterization. We introduce so-called interactive similarity maps as an alternative annotation strategy for annotating infrared microscopic images. We demonstrate that segmentations obtained from interactive similarity maps lead to similarly accurate segmentations as segmentations obtained from conventionally used hierarchical clustering approaches. In order to perform this comparison on quantitative grounds, we provide a scheme that allows to identify non-horizontal cuts in dendrograms. This yields a validation scheme for hierarchical clustering approaches commonly used in infrared microscopy. We demonstrate that interactive similarity maps may identify more accurate segmentations than hierarchical clustering based approaches, and thus are a viable and due to their interactive nature attractive alternative to hierarchical clustering. Our validation scheme furthermore shows that performance of hierarchical two-means is comparable to the traditionally used Ward's clustering. As the former is much more efficient in time and memory, our results suggest another less resource demanding alternative for annotating large spectral images.

  2. Planck intermediate results: XLIII. Spectral energy distribution of dust in clusters of galaxies

    DEFF Research Database (Denmark)

    Adam, R.; Ade, P. A R; Aghanim, N.

    2016-01-01

    Although infrared (IR) overall dust emission from clusters of galaxies has been statistically detected using data from the Infrared Astronomical Satellite (IRAS), it has not been possible to sample the spectral energy distribution (SED) of this emission over its peak, and thus to break the degene...

  3. UNTANGLING THE NEAR-IR SPECTRAL FEATURES IN THE PROTOPLANETARY ENVIRONMENT OF KH 15D

    Energy Technology Data Exchange (ETDEWEB)

    Arulanantham, Nicole A.; Herbst, William; Gilmore, Martha S.; Cauley, P. Wilson [Astronomy Department, Wesleyan University, Middletown, CT 06459 (United States); Leggett, S. K., E-mail: nicole.arulanantham@colorado.edu [Gemini Observatory (North), Hilo, HI 96720 (United States)

    2017-01-10

    We report on Gemini/GNIRS observations of the binary T Tauri system V582 Mon (KH 15D) at three orbital phases. These spectra allow us to untangle five components of the system: the photosphere and magnetosphere of star B, the jet, scattering properties of the ring material, and excess near-infrared (near-IR) radiation previously attributed to a possible self-luminous planet. We confirm an early-K subgiant classification for star B and show that the magnetospheric He i emission line is variable, possibly indicating increased mass accretion at certain times. As expected, the H{sub 2} emission features associated with the inner part of the jet show no variation with orbital phase. We show that the reflectance spectrum for the scattered light has a distinctive blue slope and spectral features consistent with scattering and absorption by a mixture of water and methane ice grains in the 1–50 μ m size range. This suggests that the methane frost line is closer than ∼5 au in this system, requiring that the grains be shielded from direct radiation. After correcting for features from the scattered light, jet, magnetosphere, and photosphere, we confirm the presence of leftover near-IR light from an additional source, detectable near minimum brightness. A spectral emission feature matching the model spectrum of a 10 M {sub J}, 1 Myr old planet is found in the excess flux, but other expected features from this model are not seen. Our observations, therefore, tentatively support the picture that a luminous planet is present within the system, although they cannot yet be considered definitive.

  4. EPR and IR spectral investigations on some leafy vegetables of Indian origin

    Science.gov (United States)

    Prasuna, C. P. Lakshmi; Chakradhar, R. P. S.; Rao, J. L.; Gopal, N. O.

    2009-09-01

    EPR spectral investigations have been carried out on four edible leafy vegetables of India, which are used as dietary component in day to day life. In Rumex vesicarius leaf sample, EPR spectral investigations at different temperatures indicate the presence of anti-ferromagnetically coupled Mn(IV)-Mn(IV) complexes. EPR spectra of Trigonella foenum graecum show the presence of Mn ions in multivalent state and Fe 3+ ions in rhombic symmetry. EPR spectra of Basella rubra indicate the presence of Mn(IV)-O-Mn(IV) type complexes. The EPR spectra of Basella rubra have been studied at different temperatures. It is found that the spin population for the resonance signal at g = 2.06 obeys the Boltzmann distribution law. The EPR spectra of Moringa oliefera leaves show the presence of Mn 2+ ions. Radiation induced changes in free radical of this sample have also been studied. The FT-IR spectra of Basella rubra and Moringa oliefera leaves show the evidences for the protein matrix bands and those corresponding to carboxylic C dbnd O bonds.

  5. Detection and classification of salmonella serotypes using spectral signatures collected by fourier transform infrared (FT-IR) spectroscopy

    Science.gov (United States)

    Spectral signatures of Salmonella serotypes namely Salmonella Typhimurium, Salmonella Enteritidis, Salmonella Infantis, Salmonella Heidelberg and Salmonella Kentucky were collected using Fourier transform infrared spectroscopy (FT-IR). About 5-10 µL of Salmonella suspensions with concentrations of 1...

  6. SPATIAL VARIATIONS OF PAH PROPERTIES IN M17SW REVEALED BY SPITZER /IRS SPECTRAL MAPPING

    Energy Technology Data Exchange (ETDEWEB)

    Yamagishi, M. [Institute of Space and Astronautical Science, Japan Aerospace Exploration Agency, Chuo-ku, Sagamihara 252-5210 (Japan); Kaneda, H.; Ishihara, D.; Oyabu, S.; Suzuki, T.; Nishimura, A.; Kohno, M. [Graduate School of Science, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8602 (Japan); Onaka, T.; Ohashi, S. [Graduate School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033 (Japan); Nagayama, T.; Matsuo, M. [Graduate School of Science and Engineering, Kagoshima University, 1-21-35 Korimoto, Kagoshima 890-0065 (Japan); Umemoto, T.; Minamidani, T.; Fujita, S. [Nobeyama Radio Observatory, National Astronomical Observatory of Japan (NAOJ), National Institutes of Natural Sciences (NINS), 462-2, Nobeyama, Minamimaki, Minamisaku, Nagano 384-1305 (Japan); Tsuda, Y., E-mail: yamagish@ir.isas.jaxa.jp [Graduate School of Science and Engineering, Meisei University, 2-1-1 Hodokubo, Hino, Tokyo 191-0042 (Japan)

    2016-12-20

    We present Spitzer /IRS mid-infrared spectral maps of the Galactic star-forming region M17 as well as IRSF/SIRIUS Br γ and Nobeyama 45 m/FOREST {sup 13}CO ( J = 1–0) maps. The spectra show prominent features due to polycyclic aromatic hydrocarbons (PAHs) at wavelengths of 6.2, 7.7, 8.6, 11.3, 12.0, 12.7, 13.5, and 14.2  μ m. We find that the PAH emission features are bright in the region between the H ii region traced by Br γ and the molecular cloud traced by {sup 13}CO, supporting that the PAH emission originates mostly from photo-dissociation regions. Based on the spatially resolved Spitzer /IRS maps, we examine spatial variations of the PAH properties in detail. As a result, we find that the interband ratio of PAH 7.7  μ m/PAH 11.3  μ m varies locally near M17SW, but rather independently of the distance from the OB stars in M17, suggesting that the degree of PAH ionization is mainly controlled by local conditions rather than the global UV environments determined by the OB stars in M17. We also find that the interband ratios of the PAH 12.0  μ m, 12.7  μ m, 13.5  μ m, and 14.2  μ m features to the PAH 11.3  μ m feature are high near the M17 center, which suggests structural changes of PAHs through processing due to intense UV radiation, producing abundant edgy irregular PAHs near the M17 center.

  7. Hybrid nanomaterial and its applications: IR sensing and energy harvesting

    Science.gov (United States)

    Tseng, Yi-Hsuan

    In this dissertation, a hybrid nanomaterial, single-wall carbon nanotubes-copper sulfide nanoparticles (SWNTs-CuS NPs), was synthesized and its properties were analyzed. Due to its unique optical and thermal properties, the hybrid nanomaterial exhibited great potential for infrared (IR) sensing and energy harvesting. The hybrid nanomaterial was synthesized with the non-covalent bond technique to functionalize the surface of the SWNTs and bind the CuS nanoparticles on the surface of the SWNTs. For testing and analyzing the hybrid nanomaterial, SWNTs-CuS nanoparticles were formed as a thin film structure using the vacuum filtration method. Two conductive wires were bound on the ends of the thin film to build a thin film device for measurements and analyses. Measurements found that the hybrid nanomaterial had a significantly increased light absorption (up to 80%) compared to the pure SWNTs. Moreover, the hybrid nanomaterial thin film devices exhibited a clear optical and thermal switching effect, which could be further enhanced up to ten times with asymmetric illumination of light and thermal radiation on the thin film devices instead of symmetric illumination. A simple prototype thermoelectric generator enabled by the hybrid nanomaterials was demonstrated, indicating a new route for achieving thermoelectricity. In addition, CuS nanoparticles have great optical absorption especially in the near-infrared region. Therefore, the hybrid nanomaterial thin films also have the potential for IR sensing applications. The first application to be covered in this dissertation is the IR sensing application. IR thin film sensors based on the SWNTs-CuS nanoparticles hybrid nanomaterials were fabricated. The IR response in the photocurrent of the hybrid thin film sensor was significantly enhanced, increasing the photocurrent by 300% when the IR light illuminates the thin film device asymmetrically. The detection limit could be as low as 48mW mm-2. The dramatically enhanced

  8. THE ORION FINGERS: NEAR-IR SPECTRAL IMAGING OF AN EXPLOSIVE OUTFLOW

    Energy Technology Data Exchange (ETDEWEB)

    Youngblood, Allison; Bally, John [Department of Astrophysical and Planetary Sciences, University of Colorado, UCB 389, Boulder, CO 80309 (United States); Ginsburg, Adam, E-mail: allison.youngblood@colorado.edu [ESO Headquarters, Karl-Schwarzschild-Strasse 2, D-85748 Garching bei München (Germany)

    2016-06-01

    We present near-IR (1.1–2.4 μ m) position–position–velocity cubes of the 500 year old Orion BN/KL explosive outflow with spatial resolution 1″ and spectral resolution 86 km s{sup −1}. We construct integrated intensity maps free of continuum sources of 15 H{sub 2} and [Fe ii] lines while preserving kinematic information of individual outflow features. Included in the detected H{sub 2} lines are the 1-0 S(1) and 1-0 Q(3) transitions, allowing extinction measurements across the outflow. Additionally, we present dereddened flux ratios for over two dozen outflow features to allow for the characterization of the true excitation conditions of the BN/KL outflow. All of the ratios show the dominance of the shock excitation of the H{sub 2} emission, although some features exhibit signs of fluorescent excitation from stellar radiation or J-type shocks. We also detect tracers of the PDR/ionization front north of the Trapezium stars in [O i] and [Fe ii] and analyze other observed outflows not associated with the BN/KL outflow.

  9. Liver Status Assessment by Spectrally and Time Resolved IR Detection of Drug Induced Breath Gas Changes

    Directory of Open Access Journals (Sweden)

    Tom Rubin

    2016-05-01

    Full Text Available The actual metabolic capacity of the liver is crucial for disease identification, liver therapy, and liver tumor resection. By combining induced drug metabolism and high sensitivity IR spectroscopy of exhaled air, we provide a method for quantitative liver assessment at bedside within 20 to 60 min. Fast administration of 13C-labelled methacetin induces a fast response of liver metabolism and is tracked in real-time by the increase of 13CO2 in exhaled air. The 13CO2 concentration increase in exhaled air allows the determination of the metabolic liver capacity (LiMAx-test. Fluctuations in CO2 concentration, pressure and temperature are minimized by special gas handling, and tracking of several spectrally resolved CO2 absorption bands with a quantum cascade laser. Absorption measurement of different 12CO2 and 13CO2 rotation-vibration transitions in the same time window allows for multiple referencing and reduction of systematic errors. This FLIP (Fast liver investigation package setup is being successfully used to plan operations and determine the liver status of patients.

  10. Low-energy levels calculation for 193Ir

    International Nuclear Information System (INIS)

    Zahn, Guilherme Soares; Zamboni, Cibele Bugno; Genezini, Frederico Antonio; Mesa-Hormaza, Joel; Cruz, Manoel Tiago Freitas da

    2006-01-01

    In this work, a model based on single particle plus pairing residual interaction was used to study the low-lying excited states of the 193 Ir nucleus. In this model, the deformation parameters in equilibrium were obtained by minimizing the total energy calculated by the Strutinsky prescription; the macroscopic contribution to the potential was taken from the Liquid Droplet Model, with the shell and paring corrections used as as microscopic contributions. The nuclear shape was described using the Cassinian ovoids as base figures; the single particle energy spectra and wave functions for protons and neutrons were calculated in a deformed Woods-Saxon potential, where the parameters for neutrons were obtained from the literature and the parameters for protons were adjusted in order to describe the main sequence of angular momentum and parity of the band heads, as well as the proton binding energy of 193 Ir. The residual pairing interaction was calculated using the BCS prescription with Lipkin-Nogami approximation. The results obtained for the first three band heads (the 3/2 + ground state, the 1/2 + excited state at E ∼ 73 keV and the the 11/2 - isomeric state at E ∼ 80 keV) showed a very good agreement, but the model so far greatly overestimated the energy of the next band head, a 7/2 - at E ∼ 299 keV. (author)

  11. Choice of Eye-Safe Radiation Wavelength in UV and Near IR Spectral Bands for Remote Sensing

    OpenAIRE

    M. L. Belov; V. A. Gorodnichev; D. A. Kravtsov; A. A. Cherpakova

    2016-01-01

    The introduction of laser remote sensing systems carries a particular risk to the human’s sense of vision. A structure of the eye, and especially the retina, is the main critical organ as related to the laser radiation.The work uses the optical models of the atmosphere, correctly working in both the UV and the near-IR band, to select the eye-safe radiation wavelengths in the UV (0.355 m) and near-IR (~ 1.54 and ~ 2 m) spectral bands from the point of view of recorded lidar signal value to ful...

  12. Wave propagation of spectral energy content in a granular chain

    NARCIS (Netherlands)

    Shrivastava, Rohit Kumar; Luding, Stefan

    2017-01-01

    A mechanical wave is propagation of vibration with transfer of energy and momentum. Understanding the spectral energy characteristics of a propagating wave through disordered granular media can assist in understanding the overall properties of wave propagation through inhomogeneous materials like

  13. Energy Efficient Clothes Dryer with IR Heating and Electrostatic Precipitator

    Energy Technology Data Exchange (ETDEWEB)

    Weaver, Stanton [GE Global Research, Niskayuna, NY (United States)

    2017-12-12

    The project goal was to develop a revolutionary energy saving technology for residential clothes drying. The team developed an IR (infrared) heating system and NESP (Nebulizer and Electro-Static Precipitator) for integration into a ventless clothes dryer. The proposed technology addresses two of the major inefficiencies in current electric vented dryers by providing effective energy transfer for the removal of the water and recapture of the vapor latent heat. The IR heaters operating in the mid wave (2.5-10um) are very efficient as they target the 3-micron peak absorption of the water molecule. This allows direct energy absorption, unlike conventional element heaters where heat is transferred by convection. The low power NESP removes water vapor from the exhausted stream and recaptures the latent heat in the ESP (Electro-Static Precipitator) exchanger section. This allows the warm dry air to be recirculated back into the drum for additional efficiency savings. The remaining majority of the dryer hardware stays the same. Summing the efficiency gain from the two subcomponents we anticipated the EF (Efficiency Factor) to exceed the goal of 4.04. EF is obtained by dividing the weight (lbs) of water removed by the energy (kWhr) used, where the test load size is 8.45 lbs of bone dry clothing wetted to 57.5% or 4.8lbs of water, and dried to a remaining moisture content of 2.5-5%. Additional benefits include not having to recondition (heat or cool) the large amounts of make-up air to replace the air exhausted by a vented dryer. It was anticipated that the NESP/heat exchanger would be the most challenging and highest risk element in the program. Therefore, the team focused their efforts during Phase 1 of the program on the design, construction, testing, and optimization of the NESP/heat exchanger. At the end Phase 1, the team compared the performance of the NESP/heat exchanger with the system level requirements and made a Go/No-Go decision on proceeding with the second

  14. An unbiased spectral line survey toward R CrA IRS7B in the 345 GHz window with ASTE

    DEFF Research Database (Denmark)

    Watanabe, Yoshimasa; Sakai, Nami; Lindberg, Johan

    2012-01-01

    We have conducted a spectral line survey in the 332-364 GHz region with the Atacama Submillimeter Telescope Experiment 10 m telescope toward R CrA IRS7B, a low-mass protostar in the Class 0 or Class 0/I transitional stage. We have also performed some supplementary observations in the 450 GHz band...... corino. These results suggest a weak hot corino activity in R CrA IRS7B. On the other hand, the carbon-chain related molecules, CCH and c-C3H2, are found to be abundant. However, this source cannot be classified as a WCCC source, since long carbon-chain molecules are not detected. If WCCC and hot corino...... chemistry represent the two extremes in chemical compositions of low-mass Class 0 sources, R CrA IRS7B would be a source with a mixture of these two chemical characteristics. The UV radiation from the nearby Herbig Ae star R CrA may also affect the chemical composition. The present line survey demonstrates...

  15. Estimation of spectral reflectance of snow from IRS-1D LISS-III ...

    Indian Academy of Sciences (India)

    R. Narasimhan (Krishtel eMaging) 1461 1996 Oct 15 13:05:22

    Marine and Water Resources Group, Space Applications Centre, Ahmedabad, 380 015, India. The sensor ... snowpack characteristics as a result of various metamorphic processes, with age, can cause varia- tions in its ... estimate the direct radiation income of slopes in ... model are: mean solar exo-atmospheric spectral.

  16. Choice of Eye-Safe Radiation Wavelength in UV and Near IR Spectral Bands for Remote Sensing

    Directory of Open Access Journals (Sweden)

    M. L. Belov

    2016-01-01

    Full Text Available The introduction of laser remote sensing systems carries a particular risk to the human’s sense of vision. A structure of the eye, and especially the retina, is the main critical organ as related to the laser radiation.The work uses the optical models of the atmosphere, correctly working in both the UV and the near-IR band, to select the eye-safe radiation wavelengths in the UV (0.355 m and near-IR (~ 1.54 and ~ 2 m spectral bands from the point of view of recorded lidar signal value to fulfill the tasks of laser sensing the natural formations and laser aerosol sensing in the atmosphere.It is shown that the remote sensing lasers with appropriate characteristics can be selected both in the UV band (at a wavelength of 0.355 μm and in the near-IR band (at wavelengths of 1.54 ~ or ~ 2 μm.Molecular scattering has its maximum (for the selected wavelength at a wavelength of 0.355 μm in the UV band, and the minimum at the wavelengths of 1.54 and 2.09 μm in the near -IR band. The main contribution to the molecular absorption at a wavelength of 0.355 μm is made by ozone. In the near-IR spectral band the radiation is absorbed due to water vapor and carbon dioxide.Calculations show that the total effect of the molecular absorption and scattering has no influence on radiation transmission for both the wavelength of 0.355 μm in the UV band, and the wavelengths of 1.54 and 2.09 μm in the near-IR band for sensing trails ~ 1 km.One of the main factors of laser radiation attenuation in the Earth's atmosphere is radiation scattering by aerosol particles.The results of calculations at wavelengths of 0.355 μm, 1.54 μm and 2.09 μm for the several models of the atmosphere show that a choice of the most effective (in terms of the recorded signal of lidar and eye-safe radiation wavelength depends strongly on the task of sensing.To fulfill the task of laser sensing the natural formations, among the eye-safe wavelengths there is one significantly advantageous

  17. The broadband spectral energy distributions of SDSS blazars

    Science.gov (United States)

    Li, Huai-Zhen; Chen, Luo-En; Jiang, Yun-Guo; Yi, Ting-Feng

    2015-07-01

    We compiled the radio, optical and X-ray data of blazars from the Sloan Digital Sky Survey database, and presented the distribution of luminosities and broadband spectral indices. The distribution of luminosities shows that the averaged luminosity of flat spectrum radio quasars (FSRQs) is larger than that of BL Lacertae (BL Lac) objects. On the other hand, the broadband spectral energy distribution reveals that FSRQs and low energy peaked BL Lac objects have similar spectral properties, but high energy peaked BL Lac objects have a distinct spectral property. This may be due to the fact that different subclasses of blazars have different intrinsic environments and are at different cooling levels. Even so, a unified scheme is also revealed from the color-color diagram, which hints that there are similar physical processes operating in all objects under a range of intrinsic physical conditions or beaming parameters. Supported by the National Natural Science Foundation of China.

  18. Semiconductor lasers with a continuous tuning range above 100 nm in the nearest IR spectral region

    Energy Technology Data Exchange (ETDEWEB)

    Kostin, Yu O; Lobintsov, A A; Shramenko, M V [OOO ' Opton' , Moscow (Russian Federation); Ladugin, M A; Marmalyuk, A A [Open Joint-Stock Company M.F. Stel' makh Polyus Research Institute, Moscow (Russian Federation); Chamorovsky, A Yu [Superlum Ltd., Unit B3, Fota Point Enterprise Park, Carrigtwohill, Co Cork (Ireland); Yakubovich, S D [Moscow State Institute of Radio-Engineering, Electronics and Automation (Technical University), Moscow (Russian Federation)

    2015-08-31

    We have developed two new types of lasers based on quantum-confined semiconductor optical amplifiers with an acousto-optic tunable filter in an external fibre ring cavity. The lasers offer continuous wavelength tuning ranges from 780 to 885 and from 880 to 1010 nm, 20 mW of cw output power, and a tuning rate up to 10{sup 4} nm s{sup -1} at an instantaneous spectral linewidth less than 0.1 nm. (lasers)

  19. Toward optimal spatial and spectral quality in widefield infrared spectromicroscopy of IR labelled single cells.

    Science.gov (United States)

    Mattson, Eric C; Unger, Miriam; Clède, Sylvain; Lambert, François; Policar, Clotilde; Imtiaz, Asher; D'Souza, Roshan; Hirschmugl, Carol J

    2013-10-07

    Advancements in widefield infrared spectromicroscopy have recently been demonstrated following the commissioning of IRENI (InfraRed ENvironmental Imaging), a Fourier Transform infrared (FTIR) chemical imaging beamline at the Synchrotron Radiation Center. The present study demonstrates the effects of magnification, spatial oversampling, spectral pre-processing and deconvolution, focusing on the intracellular detection and distribution of an exogenous metal tris-carbonyl derivative 1 in a single MDA-MB-231 breast cancer cell. We demonstrate here that spatial oversampling for synchrotron-based infrared imaging is critical to obtain accurate diffraction-limited images at all wavelengths simultaneously. Resolution criteria and results from raw and deconvoluted images for two Schwarzschild objectives (36×, NA 0.5 and 74×, NA 0.65) are compared to each other and to prior reports for raster-scanned, confocal microscopes. The resolution of the imaging data can be improved by deconvolving the instrumental broadening that is determined with the measured PSFs, which is implemented with GPU programming architecture for fast hyperspectral processing. High definition, rapidly acquired, FTIR chemical images of respective spectral signatures of the cell 1 and shows that 1 is localized next to the phosphate- and Amide-rich regions, in agreement with previous infrared and luminescence studies. The infrared image contrast, localization and definition are improved after applying proven spectral pre-processing (principal component analysis based noise reduction and RMie scattering correction algorithms) to individual pixel spectra in the hyperspectral cube.

  20. Extending laser plasma accelerators into the mid-IR spectral domain with a next-generation ultra-fast CO2 laser

    Science.gov (United States)

    Pogorelsky, I. V.; Babzien, M.; Ben-Zvi, I.; Polyanskiy, M. N.; Skaritka, J.; Tresca, O.; Dover, N. P.; Najmudin, Z.; Lu, W.; Cook, N.; Ting, A.; Chen, Y.-H.

    2016-03-01

    Expanding the scope of relativistic plasma research to wavelengths longer than the λ/≈   0.8-1.1 μm range covered by conventional mode-locked solid-state lasers would offer attractive opportunities due to the quadratic scaling of the ponderomotive electron energy and critical plasma density with λ. Answering this quest, a next-generation mid-IR laser project is being advanced at the BNL ATF as a part of the user facility upgrade. We discuss the technical approach to this conceptually new 100 TW, 100 fs, λ  =   9-11 μm CO2 laser BESTIA (Brookhaven Experimental Supra-Terawatt Infrared at ATF) that encompasses several innovations applied for the first time to molecular gas lasers. BESTIA will enable new regimes of laser plasma accelerators. One example is shock-wave ion acceleration (SWA) from gas jets. We review ongoing efforts to achieve stable, monoenergetic proton acceleration by dynamically shaping the plasma density profile from a hydrogen gas target with laser-produced blast waves. At its full power, 100 TW BESTIA promises to achieve proton beams at an energy exceeding 200 MeV. In addition to ion acceleration in over-critical plasma, the ultra-intense mid-IR BESTIA will open up new opportunities in driving wakefields in tenuous plasmas, expanding the landscape of laser wakefield accelerator (LWFA) studies into the unexplored long-wavelength spectral domain. Simple wavelength scaling suggests that a 100 TW CO2 laser beam will be capable of efficiently generating plasma ‘bubbles’ a thousand times greater in volume compared with a near-IR solid state laser of an equivalent power. Combined with a femtosecond electron linac available at the ATF, this wavelength scaling will facilitate the study of external seeding and staging of LWFAs.

  1. The source of multi spectral energy of solar energetic electron

    Energy Technology Data Exchange (ETDEWEB)

    Herdiwijaya, Dhani [Astronomy Division and Bosscha Observatory, Faculty Mathematics and Natural Sciences, Intitute Technology of Bandung, Ganesha 10, Bandung, Indonesia 40132 dhani@as.itb.ac.id (Indonesia)

    2015-04-16

    We study the solar energetic electron distribution obtained from ACE and GOES satellites which have different altitudes and electron spectral energy during the year 1997 to 2011. The electron spectral energies were 0.038–0.315 MeV from EPAM instrument onboard ACE satellite and >2 MeV from GOES satellite. We found that the low electron energy has no correlation with high energy. In spite of we have corrected to the altitude differences. It implied that they originated from time dependent events with different sources and physical processes at the solar atmosphere. The sources of multi spectral energetic electron were related to flare and CME phenomena. However, we also found that high energetic electron comes from coronal hole.

  2. Visual Method for Spectral Energy Distribution Calculation of ...

    Indian Academy of Sciences (India)

    Abstract. In this work, we propose to use 'The Geometer's Sketchpad' to the fitting of a spectral energy distribution of blazar based on three effective spectral indices, αRO, αOX, and αRX and the flux density in the radio band. It can make us to see the fitting in detail with both the peak frequency and peak luminosity given ...

  3. Spectral energy distributions of T Tauri stars - disk flaring and limits on accretion

    International Nuclear Information System (INIS)

    Kenyon, S.J.; Hartmann, L.

    1987-01-01

    The Adams et al. (1987) conclusion that much of the IR excess emission in the spectral energy distribution of T Tauri stars arises from reprocessing of stellar radiation by a dusty circumstellar disk is presently supported by analyses conducted in light of various models of these stars' spectra. A low mass reprocessing disk can, however, produce these spectra as well as a massive accretion disk. The detection of possible boundary layer radiation in the optical and near-UV regions poses the strongest limits on accretion rates. Disk accretion in the T Tauri phase does not significantly modify stellar evolution. 85 references

  4. Exchange, x-ray and IR spectral behaviour of lanthanum and praseodymium exchanged zeolite X

    International Nuclear Information System (INIS)

    Das, D.; Upreti, M.C.

    1995-01-01

    Exchange behaviour of lanthanum and praseodymium ions in zeolite X involves three steps: preferential exchange, intrazeolitic exchange and irreversible exchange. At room temperature , higher exchange has been observed with La(III) than with Pr(III) which is attributed to the smaller hydrosphere of lanthanum than praseodymium. IR spectra of these zeolites in KBr pellets show a shift in the major Si-O stretching vibration of 972 cm -1 to higher frequencies. Their x-ray diffraction patterns remain unchanged except a large decrease of the line intensities caused by the absorption of x-rays by heavy La(III) and Pr(III) ions. The present study reports the preparation and physicochemical properties of lanthanum and praseodymium exchanged zeolite X. (author). 12 refs., 3 figs., 3 tabs

  5. Composite multi-lobe descriptor for cross spectral face recognition: matching active IR to visible light images

    Science.gov (United States)

    Cao, Zhicheng; Schmid, Natalia A.

    2015-05-01

    Matching facial images across electromagnetic spectrum presents a challenging problem in the field of biometrics and identity management. An example of this problem includes cross spectral matching of active infrared (IR) face images or thermal IR face images against a dataset of visible light images. This paper describes a new operator named Composite Multi-Lobe Descriptor (CMLD) for facial feature extraction in cross spectral matching of near-infrared (NIR) or short-wave infrared (SWIR) against visible light images. The new operator is inspired by the design of ordinal measures. The operator combines Gaussian-based multi-lobe kernel functions, Local Binary Pattern (LBP), generalized LBP (GLBP) and Weber Local Descriptor (WLD) and modifies them into multi-lobe functions with smoothed neighborhoods. The new operator encodes both the magnitude and phase responses of Gabor filters. The combining of LBP and WLD utilizes both the orientation and intensity information of edges. Introduction of multi-lobe functions with smoothed neighborhoods further makes the proposed operator robust against noise and poor image quality. Output templates are transformed into histograms and then compared by means of a symmetric Kullback-Leibler metric resulting in a matching score. The performance of the multi-lobe descriptor is compared with that of other operators such as LBP, Histogram of Oriented Gradients (HOG), ordinal measures, and their combinations. The experimental results show that in many cases the proposed method, CMLD, outperforms the other operators and their combinations. In addition to different infrared spectra, various standoff distances from close-up (1.5 m) to intermediate (50 m) and long (106 m) are also investigated in this paper. Performance of CMLD is evaluated for of each of the three cases of distances.

  6. CORRELATION ANALYSIS OF IR, 1 H- AND 13 C-NMR SPECTRAL DATA OF N-ALKYL AND N-CYCLOALKYL CYANOACETAMIDES

    Directory of Open Access Journals (Sweden)

    Aleksandar D. Marinković

    2011-09-01

    Full Text Available Linear free energy relationships (LFER were applied to the IR, 1H- and 13C--NMR spectral data in N-alkyl and N-cycloalkyl cyanoacetamides. N-alkyl and N-cycloalkyl cyanocetamides were synthesized from corresponding amine and ethyl cyanoacetate. A number of substituents were employed for alkyl substitution, and fairly good correlations were obtained, using simple Hammett equation. In N-alkyl and N-cycloalkyl cyanoacetamides substituent cause SCS of N-H hydrogen primarily by steric interaction, polar subtituent effect influences SCS shift of C=O carbon, while steric effect of N-alkyl substituent causes IR stretching frequencies of N-H, C=O and CN group. The conformations of investigated compounds have been studied by the use of semiempirical PM6 method, and together with LFER analysis, give a better insight into the influence of such a structure on the transmission of electronic substituent effects. Negative ρ values for several correlations (reverse substituent effect were found.

  7. AN UNBIASED SPECTRAL LINE SURVEY TOWARD R CrA IRS7B IN THE 345 GHz WINDOW WITH ASTE

    International Nuclear Information System (INIS)

    Watanabe, Yoshimasa; Sakai, Nami; Yamamoto, Satoshi; Lindberg, Johan E.; Bisschop, Suzanne E.; Jørgensen, Jes K.

    2012-01-01

    We have conducted a spectral line survey in the 332-364 GHz region with the Atacama Submillimeter Telescope Experiment 10 m telescope toward R CrA IRS7B, a low-mass protostar in the Class 0 or Class 0/I transitional stage. We have also performed some supplementary observations in the 450 GHz band. In total, 16 molecular species are identified in the 332-364 GHz region. Strong emission lines of CN and CCH are observed, whereas complex organic molecules and long carbon-chain molecules, which are characteristics of hot corino and warm carbon-chain chemistry (WCCC) source, respectively, are not detected. The rotation temperature of CH 3 OH is evaluated to be 31 K, which is significantly lower than that reported for the prototypical hot corino IRAS 16293-2422 (∼85 K). The deuterium fractionation ratios for CCH and H 2 CO are obtained to be 0.038 and 0.050, respectively, which are much lower than those in the hot corino. These results suggest a weak hot corino activity in R CrA IRS7B. On the other hand, the carbon-chain related molecules, CCH and c-C 3 H 2 , are found to be abundant. However, this source cannot be classified as a WCCC source, since long carbon-chain molecules are not detected. If WCCC and hot corino chemistry represent the two extremes in chemical compositions of low-mass Class 0 sources, R CrA IRS7B would be a source with a mixture of these two chemical characteristics. The UV radiation from the nearby Herbig Ae star R CrA may also affect the chemical composition. The present line survey demonstrates further chemical diversity in low-mass star-forming regions.

  8. IR SPECTRAL MAPPING OF THE MARTIAN SOUTH POLAR RESIDUAL CAP USING CRISM

    Directory of Open Access Journals (Sweden)

    J. Campbell

    2016-06-01

    Full Text Available Polycyclic aromatic hydrocarbons (PAHs are considered to be important in theories of abiogenesis (Allamandola, 2011 . There is evidence that PAHs have been detected on two icy Saturnian satellites using the Visual and Infrared Mapping Spectrometer (VIMS on the Cassini spacecraft (Cruikshank et al., 2007. The hypothesised presence of PAHs in Mars south polar cap has not been systematically examined even though the Mars south polar cap may allow the preservation of organic molecules that are typically destroyed at the Martian surface by UV radiation (Dartnell et al. 2012. This hypothesis is supported by recent analyses of South Polar Residual Cap (SPRC structural evolution (Thomas et al., 2009 that suggest the possibility that seasonal and long term sublimation may excavate dust particles from within the polar ice. Periodic sublimation is believed to be responsible for the formation of so-called “Swiss Cheese Terrain”, a unique surface feature found only in the Martian south polar residual cap consisting of flat floored, circular depressions (Byrne, 2009. We show the first examples of work towards the detection of PAHs in Swiss Cheese Terrain, using data from the Compact Reconnaissance Imaging Spectrometer for Mars (CRISM, on board NASA’s Mars Reconnaissance Orbiter (MRO. CRISM is designed to search for mineralogical indications of past and present water, thus providing extensive coverage of the south polar cap. In this work, we discuss whether CRISM infrared spectra can be used to detect PAHs in Swiss Cheese Terrain and demonstrate a number of maps showing shifts in spectral profiles over the SPRC.

  9. Mid-IR Reflectance (DRIFT) Spectral Variations in Basaltic Mineralogy with Direction of Impact at Lonar Crater, India

    Science.gov (United States)

    Basavaiah, N.; Chavan, R. S.; Arif, M.

    2012-12-01

    Identification of spectral changes with the direction of impact has important implications for understanding the impact cratering phenomenon occurring on both terrestrial and extraterrestrial planets and also for geology of the crater. Fortuitously, Lonar Impact Crater (India) is the only well-preserved terrestrial simple crater excavated on Deccan basalts and serves as an excellent analogue to craters on Mars and Moon. An ~570 ka old Lonar crater was suggested to be formed by an oblique impact of a chondritic impactor that struck the pre-impact target from the east into a sequence of six basaltic Deccan flows and created a 1.88 km diameter crater with two layers of ejecta blanket. Here we report preliminary laboratory studies of spectral results on fine-grained rock powers (IR (4000-400 cm-1) Diffuse Reflectance Infrared Fourier Transform (DRIFT) spectroscopy. The basalts were collected from two profiles in the east and south sections of the crater wall and the upper most crater rim, which later subdivided into sector-wise samples to carry out a systematic study of spectral properties of Lonar basalts, together with impact related samples of breccias and impact melts. For the first time, data of the shock metamorphism of Lonar basalt is examined using DRIFT spectroscopy. Infrared spectra of rock powders of relatively unshocked and shocked basalts are obtained to document the mineralogical variations and the distribution of primary (e.g. Plagioclase Feldspar, Pyroxene), and secondary Phyllosilicate minerals (e.g. Illite, Smectite, Montmorillonite, Saponite, Serpentine) with direction of impact. The spectral data between pre-impact unshocked and post-impact shocked basalts are interpreted to reflect the effect of shock pressure and alteration that rock have undergone. On western crater rim sector, typical silicate spectral features in 900-1200 cm-1 which attributed to Si-O stretching, are observed to change slightly in the width and shift in position as a result of

  10. GOODS-HERSCHEL: IMPACT OF ACTIVE GALACTIC NUCLEI AND STAR FORMATION ACTIVITY ON INFRARED SPECTRAL ENERGY DISTRIBUTIONS AT HIGH REDSHIFT

    Energy Technology Data Exchange (ETDEWEB)

    Kirkpatrick, Allison; Pope, Alexandra [Department of Astronomy, University of Massachusetts, Amherst, MA 01002 (United States); Alexander, David M. [Department of Physics, Durham University, Durham DH1 3LE (United Kingdom); Charmandaris, Vassilis [Department of Physics and Institute of Theoretical and Computational Physics, University of Crete, GR-71003, Heraklion (Greece); Daddi, Emmanuele; Elbaz, David; Gabor, Jared; Mullaney, James; Pannella, Maurilio; Aussel, Herve; Bournaud, Frederic; Dasyra, Kalliopi [Laboratoire AIM, CEA/DSM-CNRS-Universite Paris Diderot, Irfu/SAp, Orme des Merisiers, F-91191 Gif-sur-Yvette (France); Dickinson, Mark [National Optical Astronomy Observatory, 950 North Cherry Avenue, Tucson, AZ 85719 (United States); Hwang, Ho Seong [Smithsonian Astrophysical Observatory, 60 Garden Street, Cambridge, MA 02138 (United States); Ivison, Rob [UK Astronomy Technology Centre, Royal Observatory, Blackford Hill, Edinburgh, EH9 3HJ (United Kingdom); Scott, Douglas [Department of Physics and Astronomy, University of British Columbia, 6224 Agricultural Road, Vancouver, BC V6T 1Z1 (Canada); Altieri, Bruno; Coia, Daniela [Herschel Science Centre, European Space Astronomy Centre, Villanueva de la Canada, E-28691 Madrid (Spain); Buat, Veronique [Laboratoire d' Astrophysique de Marseille (LAM), Universite d' Aix-Marseille, CNRS, UMR7326, 38 rue F. Joliot-Curie, F-13388 Marseille Cedex 13 (France); Dannerbauer, Helmut, E-mail: kirkpatr@astro.umass.edu [Institut fuer Astrophysik, Universitaet Wien, Tuerkenschanzstrasse 17, A-1180 Wien (Austria); and others

    2012-11-10

    We explore the effects of active galactic nuclei (AGNs) and star formation activity on the infrared (0.3-1000 {mu}m) spectral energy distributions (SEDs) of luminous infrared galaxies from z = 0.5 to 4.0. We have compiled a large sample of 151 galaxies selected at 24 {mu}m (S {sub 24} {approx}> 100 {mu}Jy) in the GOODS-N and ECDFS fields for which we have deep Spitzer IRS spectroscopy, allowing us to decompose the mid-IR spectrum into contributions from star formation and AGN activity. A significant portion ({approx}25%) of our sample is dominated by an AGN (>50% of the mid-IR luminosity) in the mid-IR. Based on the mid-IR classification, we divide our full sample into four sub-samples: z {approx} 1 star-forming (SF) sources, z {approx} 2 SF sources, AGNs with clear 9.7 {mu}m silicate absorption, and AGNs with featureless mid-IR spectra. From our large spectroscopic sample and wealth of multi-wavelength data, including deep Herschel imaging at 100, 160, 250, 350, and 500 {mu}m, we use 95 galaxies with complete spectral coverage to create a composite SED for each sub-sample. We then fit a two-temperature component modified blackbody to the SEDs. We find that the IR SEDs have similar cold dust temperatures, regardless of the mid-IR power source, but display a marked difference in the warmer dust temperatures. We calculate the average effective temperature of the dust in each sub-sample and find a significant ({approx}20 K) difference between the SF and AGN systems. We compare our composite SEDs to local templates and find that local templates do not accurately reproduce the mid-IR features and dust temperatures of our high-redshift systems. High-redshift IR luminous galaxies contain significantly more cool dust than their local counterparts. We find that a full suite of photometry spanning the IR peak is necessary to accurately account for the dominant dust temperature components in high-redshift IR luminous galaxies.

  11. THE ULTRAVIOLET-TO-MID-INFRARED SPECTRAL ENERGY DISTRIBUTION OF WEAK EMISSION LINE QUASARS

    International Nuclear Information System (INIS)

    Lane, Ryan A.; Shemmer, Ohad; Diamond-Stanic, Aleksandar M.; Fan Xiaohui; Anderson, Scott F.; Brandt, W. N.; Schneider, Donald P.; Plotkin, Richard M.; Richards, Gordon T.; Strauss, Michael A.

    2011-01-01

    We present Spitzer Space Telescope photometry of 18 Sloan Digital Sky Survey (SDSS) quasars at 2.7 ≤ z ≤ 5.9 which have weak or undetectable high-ionization emission lines in their rest-frame ultraviolet (UV) spectra (hereafter weak-lined quasars, or WLQs). The Spitzer data are combined with SDSS spectra and ground-based, near-infrared (IR) photometry of these sources to produce a large inventory of spectral energy distributions (SEDs) of WLQs across the rest-frame ∼0.1-5 μm spectral band. The SEDs of our sources are inconsistent with those of BL Lacertae objects which are dominated by synchrotron emission due to a jet aligned close to our line of sight, but are consistent with the SED of ordinary quasars with similar luminosities and redshifts that exhibit a near-to-mid-IR 'bump', characteristic of hot dust emission. This indicates that broad emission lines in WLQs are intrinsically weak, rather than suffering continuum dilution from a jet, and that such sources cannot be selected efficiently from traditional photometric surveys.

  12. THE ULTRAVIOLET-TO-MID-INFRARED SPECTRAL ENERGY DISTRIBUTION OF WEAK EMISSION LINE QUASARS

    Energy Technology Data Exchange (ETDEWEB)

    Lane, Ryan A.; Shemmer, Ohad [Department of Physics, University of North Texas, Denton, TX 76203 (United States); Diamond-Stanic, Aleksandar M. [Center for Astrophysics and Space Sciences, University of California, San Diego, La Jolla, CA 92093 (United States); Fan Xiaohui [Steward Observatory, University of Arizona, 933 North Cherry Avenue, Tucson, AZ 85721 (United States); Anderson, Scott F. [Department of Astronomy, University of Washington, Box 351580, Seattle, WA 98195 (United States); Brandt, W. N.; Schneider, Donald P. [Department of Astronomy and Astrophysics, The Pennsylvania State University, University Park, PA 16802 (United States); Plotkin, Richard M. [Astronomical Institute ' Anton Pannekoek' , University of Amsterdam, Science Park 904, NL-1098 XH Amsterdam (Netherlands); Richards, Gordon T. [Department of Physics, Drexel University, 3141 Chestnut Street, Philadelphia, PA 19104 (United States); Strauss, Michael A., E-mail: RyanLane@my.unt.edu, E-mail: ohad@unt.edu [Princeton University Observatory, Peyton Hall, Princeton, NJ 08544 (United States)

    2011-12-20

    We present Spitzer Space Telescope photometry of 18 Sloan Digital Sky Survey (SDSS) quasars at 2.7 {<=} z {<=} 5.9 which have weak or undetectable high-ionization emission lines in their rest-frame ultraviolet (UV) spectra (hereafter weak-lined quasars, or WLQs). The Spitzer data are combined with SDSS spectra and ground-based, near-infrared (IR) photometry of these sources to produce a large inventory of spectral energy distributions (SEDs) of WLQs across the rest-frame {approx}0.1-5 {mu}m spectral band. The SEDs of our sources are inconsistent with those of BL Lacertae objects which are dominated by synchrotron emission due to a jet aligned close to our line of sight, but are consistent with the SED of ordinary quasars with similar luminosities and redshifts that exhibit a near-to-mid-IR 'bump', characteristic of hot dust emission. This indicates that broad emission lines in WLQs are intrinsically weak, rather than suffering continuum dilution from a jet, and that such sources cannot be selected efficiently from traditional photometric surveys.

  13. Spectral Gap Energy Transfer in Atmospheric Boundary Layer

    Science.gov (United States)

    Bhushan, S.; Walters, K.; Barros, A. P.; Nogueira, M.

    2012-12-01

    Experimental measurements of atmospheric turbulence energy spectra show E(k) ~ k-3 slopes at synoptic scales (~ 600 km - 2000 km) and k-5/3 slopes at the mesoscales (theory, it is expected that a strong backward energy cascade would develop at the synoptic scale, and that circulation would grow infinitely. To limit this backward transfer, energy arrest at macroscales must be introduced. The most commonly used turbulence models developed to mimic the above energy transfer include the energy backscatter model for 2D turbulence in the horizontal plane via Large Eddy Simulation (LES) models, dissipative URANS models in the vertical plane, and Ekman friction for the energy arrest. One of the controversial issues surrounding the atmospheric turbulence spectra is the explanation of the generation of the 2D and 3D spectra and transition between them, for energy injection at the synoptic scales. Lilly (1989) proposed that the existence of 2D and 3D spectra can only be explained by the presence of an additional energy injection in the meso-scale region. A second issue is related to the observations of dual peak spectra with small variance in meso-scale, suggesting that the energy transfer occurs across a spectral gap (Van Der Hoven, 1957). Several studies have confirmed the spectral gap for the meso-scale circulations, and have suggested that they are enhanced by smaller scale vertical convection rather than by the synoptic scales. Further, the widely accepted energy arrest mechanism by boundary layer friction is closely related to the spectral gap transfer. This study proposes an energy transfer mechanism for atmospheric turbulence with synoptic scale injection, wherein the generation of 2D and 3D spectra is explained using spectral gap energy transfer. The existence of the spectral gap energy transfer is validated by performing LES for the interaction of large scale circulation with a wall, and studying the evolution of the energy spectra both near to and far from the wall

  14. Dual-energy contrast-enhanced spectral mammography (CESM).

    Science.gov (United States)

    Daniaux, Martin; De Zordo, Tobias; Santner, Wolfram; Amort, Birgit; Koppelstätter, Florian; Jaschke, Werner; Dromain, Clarisse; Oberaigner, Willi; Hubalek, Michael; Marth, Christian

    2015-10-01

    Dual-energy contrast-enhanced mammography is one of the latest developments in breast care. Imaging with contrast agents in breast cancer was already known from previous magnetic resonance imaging and computed tomography studies. However, high costs, limited availability-or high radiation dose-led to the development of contrast-enhanced spectral mammography (CESM). We reviewed the current literature, present our experience, discuss the advantages and drawbacks of CESM and look at the future of this innovative technique.

  15. Wave propagation of spectral energy content in a granular chain

    Directory of Open Access Journals (Sweden)

    Shrivastava Rohit Kumar

    2017-01-01

    Full Text Available A mechanical wave is propagation of vibration with transfer of energy and momentum. Understanding the spectral energy characteristics of a propagating wave through disordered granular media can assist in understanding the overall properties of wave propagation through inhomogeneous materials like soil. The study of these properties is aimed at modeling wave propagation for oil, mineral or gas exploration (seismic prospecting or non-destructive testing of the internal structure of solids. The focus is on the total energy content of a pulse propagating through an idealized one-dimensional discrete particle system like a mass disordered granular chain, which allows understanding the energy attenuation due to disorder since it isolates the longitudinal P-wave from shear or rotational modes. It is observed from the signal that stronger disorder leads to faster attenuation of the signal. An ordered granular chain exhibits ballistic propagation of energy whereas, a disordered granular chain exhibits more diffusive like propagation, which eventually becomes localized at long time periods. For obtaining mean-field macroscopic/continuum properties, ensemble averaging has been used, however, such an ensemble averaged spectral energy response does not resolve multiple scattering, leading to loss of information, indicating the need for a different framework for micro-macro averaging.

  16. A calibration method for the measurement of IR detector spectral responses using a FTIR spectrometer equipped with a DTGS reference cell

    Science.gov (United States)

    Gravrand, Olivier; Wlassow, J.; Bonnefond, L.

    2014-07-01

    Various high performance IR detectors are today available on the market from QWIPs to narrow gap semiconductor photodiodes, which exhibit various spectral features. In the astrophysics community, the knowledge of the detector spectral shape is of first importance. This quantity (spectral QE or response) is usually measured by means of a monochromator followed by an integrating sphere and compared to a calibrated reference detector. This approach is usually very efficient in the visible range, where all optical elements are very well known, particularly the reference detector. This setup is also widely used in the near IR (up to 3μm) but as the wavelength increases, it becomes less efficient. For instance, the internal emittance of integrating spheres in the IR, and the bad knowledge of reference detectors for longer wavelengths tend to degrade the measurement reliability. Another approach may therefore be considered, using a Fourier transform IR spectrometer (FTIR). In this case, as opposed to the monochromator, the tested detector is not in low flux condition, the incident light containing a mix of different wavelengths. Therefore, the reference detector has to be to be sensitive (and known) in the whole spectral band of interest, because it will sense all those wavelengths at the same time. A popular detector used in this case is a Deuterated Triglycine Sulfate thermal detector (DTGS). Being a pyro detetector, the spectral response of such a detector is very flat, mainly limited by its window. However, the response of such a detector is very slow, highly depending on the temporal frequency of the input signal. Moreover, being a differential detector, it doesn't work in DC. In commercial FTIR spectrometers, the source luminance is usually continuously modulated by the moving interferometer, and the result is that the interferogram mixes optical spectral information (optical path difference) and temporal variations (temporal frequency) so that the temporal

  17. Theoretical studies on photoelectron and IR spectral properties of Br2.-(H2O)n clusters.

    Science.gov (United States)

    Pathak, A K; Mukherjee, T; Maity, D K

    2007-07-28

    We report vertical detachment energy (VDE) and IR spectra of Br2.-.(H2O)n clusters (n=1-8) based on first principles electronic structure calculations. Cluster structures and IR spectra are calculated at Becke's half-and-half hybrid exchange-correlation functional (BHHLYP) with a triple split valence basis function, 6-311++G(d,p). VDE for the hydrated clusters is calculated based on second order Moller-Plesset perturbation (MP2) theory with the same set of basis function. On full geometry optimization, it is observed that conformers having interwater hydrogen bonding among solvent water molecules are more stable than the structures having double or single hydrogen bonded structures between the anionic solute, Br2.-, and solvent water molecules. Moreover, a conformer having cyclic interwater hydrogen bonded network is predicted to be more stable for each size hydrated cluster. It is also noticed that up to four solvent H2O units can reside around the solute in a cyclic interwater hydrogen bonded network. The excess electron in these hydrated clusters is localized over the solute atoms. Weighted average VDE is calculated for each size (n) cluster based on statistical population of the conformers at 150 K. A linear relationship is obtained for VDE versus (n+3)(-1/3) and bulk VDE of Br2.- aqueous solution is calculated as 10.01 eV at MP2 level of theory. BHHLYP density functional is seen to make a systematic overestimation in VDE values by approximately 0.5 eV compared to MP2 data in all the hydrated clusters. It is observed that hydration increases VDE of bromine dimer anion system by approximately 6.4 eV. Calculated IR spectra show that the formation of Br2.--water clusters induces large shifts from the normal O-H stretching bands of isolated water keeping bending modes rather insensitive. Hydrated clusters, Br2.-.(H2O)n, show characteristic sharp features of O-H stretching bands of water in the small size clusters.

  18. Theoretical studies on photoelectron and IR spectral properties of Br2.-(H2O)n clusters

    Science.gov (United States)

    Pathak, A. K.; Mukherjee, T.; Maity, D. K.

    2007-07-01

    We report vertical detachment energy (VDE) and IR spectra of Br2•-•(H2O)n clusters (n=1-8) based on first principles electronic structure calculations. Cluster structures and IR spectra are calculated at Becke's half-and-half hybrid exchange-correlation functional (BHHLYP) with a triple split valence basis function, 6-311++G(d,p). VDE for the hydrated clusters is calculated based on second order Moller-Plesset perturbation (MP2) theory with the same set of basis function. On full geometry optimization, it is observed that conformers having interwater hydrogen bonding among solvent water molecules are more stable than the structures having double or single hydrogen bonded structures between the anionic solute, Br2•-, and solvent water molecules. Moreover, a conformer having cyclic interwater hydrogen bonded network is predicted to be more stable for each size hydrated cluster. It is also noticed that up to four solvent H2O units can reside around the solute in a cyclic interwater hydrogen bonded network. The excess electron in these hydrated clusters is localized over the solute atoms. Weighted average VDE is calculated for each size (n) cluster based on statistical population of the conformers at 150K. A linear relationship is obtained for VDE versus (n+3)-1/3 and bulk VDE of Br2•- aqueous solution is calculated as 10.01eV at MP2 level of theory. BHHLYP density functional is seen to make a systematic overestimation in VDE values by ˜0.5eV compared to MP2 data in all the hydrated clusters. It is observed that hydration increases VDE of bromine dimer anion system by ˜6.4eV. Calculated IR spectra show that the formation of Br2•--water clusters induces large shifts from the normal O-H stretching bands of isolated water keeping bending modes rather insensitive. Hydrated clusters, Br2•-•(H2O)n, show characteristic sharp features of O-H stretching bands of water in the small size clusters.

  19. CO Spectral Line Energy Distributions of Infrared-Luminous Galaxies and Active Galactic Nuclei

    Science.gov (United States)

    Papadopoulos, Padeli P.; van der Werf, Paul; Isaak, Kate; Xilouris, Emmanuel M.

    2010-06-01

    We report on new sensitive CO J = 6-5 line observations of several luminous infrared galaxies (LIRGs; L IR(8-1000 μm) >~ 1011 L sun), 36% (8/22) of them ultraluminous infrared galaxies (ULIRGs) (L IR>1012 L sun), and two powerful local active galactic nuclei (AGNs)—the optically luminous QSO PG 1119+120 and the powerful radio galaxy 3C 293—using the James Clerk Maxwell Telescope on Mauna Kea in Hawaii. We combine these observations with existing low-J CO data and dust emission spectral energy distributions in the far-infrared-submillimeter from the literature to constrain the properties of the star-forming interstellar medium (ISM) in these systems. We then build the first local CO spectral line energy distributions (SLEDs) for the global molecular gas reservoirs that reach up to high J-levels. These CO SLEDs are neither biased by strong lensing (which affects many of those constructed for high-redshift galaxies), nor suffer from undersampling of CO-bright regions (as most current high-J CO observations of nearby extended systems do). We find: (1) a significant influence of dust optical depths on the high-J CO lines, suppressing the J = 6-5 line emission in some of the most IR-luminous LIRGs, (2) low global CO line excitation possible even in vigorously star-forming systems, (3) the first case of a shock-powered high-excitation CO SLED in the radio galaxy 3C 293 where a powerful jet-ISM interaction occurs, and (4) unusually highly excitated gas in the optically powerful QSO PG 1119+120. In Arp 220 and possibly other (U)LIRGs very faint CO J = 6-5 lines can be attributed to significant dust optical depths at short submillimeter wavelengths immersing those lines in a strong dust continuum, and also causing the C+ line luminosity deficit often observed in such extreme starbursts. Re-analysis of the CO line ratios available for submillimeter galaxies suggests that similar dust opacities also may be present in these high-redshift starbursts, with genuinely low

  20. CO SPECTRAL LINE ENERGY DISTRIBUTIONS OF INFRARED-LUMINOUS GALAXIES AND ACTIVE GALACTIC NUCLEI

    International Nuclear Information System (INIS)

    Papadopoulos, Padeli P.; Van der Werf, Paul; Isaak, Kate; Xilouris, Emmanuel M.

    2010-01-01

    We report on new sensitive CO J = 6-5 line observations of several luminous infrared galaxies (LIRGs; L IR (8-1000 μm) ∼> 10 11 L sun ), 36% (8/22) of them ultraluminous infrared galaxies (ULIRGs) (L IR >10 12 L sun ), and two powerful local active galactic nuclei (AGNs)-the optically luminous QSO PG 1119+120 and the powerful radio galaxy 3C 293-using the James Clerk Maxwell Telescope on Mauna Kea in Hawaii. We combine these observations with existing low-J CO data and dust emission spectral energy distributions in the far-infrared-submillimeter from the literature to constrain the properties of the star-forming interstellar medium (ISM) in these systems. We then build the first local CO spectral line energy distributions (SLEDs) for the global molecular gas reservoirs that reach up to high J-levels. These CO SLEDs are neither biased by strong lensing (which affects many of those constructed for high-redshift galaxies), nor suffer from undersampling of CO-bright regions (as most current high-J CO observations of nearby extended systems do). We find: (1) a significant influence of dust optical depths on the high-J CO lines, suppressing the J = 6-5 line emission in some of the most IR-luminous LIRGs, (2) low global CO line excitation possible even in vigorously star-forming systems, (3) the first case of a shock-powered high-excitation CO SLED in the radio galaxy 3C 293 where a powerful jet-ISM interaction occurs, and (4) unusually highly excitated gas in the optically powerful QSO PG 1119+120. In Arp 220 and possibly other (U)LIRGs very faint CO J = 6-5 lines can be attributed to significant dust optical depths at short submillimeter wavelengths immersing those lines in a strong dust continuum, and also causing the C + line luminosity deficit often observed in such extreme starbursts. Re-analysis of the CO line ratios available for submillimeter galaxies suggests that similar dust opacities also may be present in these high-redshift starbursts, with genuinely low

  1. DirtyGrid I: 3D Dust Radiative Transfer Modeling of Spectral Energy Distributions of Dusty Stellar Populations

    Science.gov (United States)

    Law, Ka-Hei; Gordon, Karl D.; Misselt, Karl A.

    2018-06-01

    Understanding the properties of stellar populations and interstellar dust has important implications for galaxy evolution. In normal star-forming galaxies, stars and the interstellar medium dominate the radiation from ultraviolet (UV) to infrared (IR). In particular, interstellar dust absorbs and scatters UV and optical light, re-emitting the absorbed energy in the IR. This is a strongly nonlinear process that makes independent studies of the UV-optical and IR susceptible to large uncertainties and degeneracies. Over the years, UV to IR spectral energy distribution (SED) fitting utilizing varying approximations has revealed important results on the stellar and dust properties of galaxies. Yet the approximations limit the fidelity of the derived properties. There is sufficient computer power now available that it is now possible to remove these approximations and map out of landscape of galaxy SEDs using full dust radiative transfer. This improves upon previous work by directly connecting the UV, optical, and IR through dust grain physics. We present the DIRTYGrid, a grid of radiative transfer models of SEDs of dusty stellar populations in galactic environments designed to span the full range of physical parameters of galaxies. Using the stellar and gas radiation input from the stellar population synthesis model PEGASE, our radiative transfer model DIRTY self-consistently computes the UV to far-IR/sub-mm SEDs for each set of parameters in our grid. DIRTY computes the dust absorption, scattering, and emission from the local radiation field and a dust grain model, thereby physically connecting the UV-optical to the IR. We describe the computational method and explain the choices of parameters in DIRTYGrid. The computation took millions of CPU hours on supercomputers, and the SEDs produced are an invaluable tool for fitting multi-wavelength data sets. We provide the complete set of SEDs in an online table.

  2. Nonlocal Coulomb correlations in pure and electron-doped Sr2IrO4 : Spectral functions, Fermi surface, and pseudo-gap-like spectral weight distributions from oriented cluster dynamical mean-field theory

    Science.gov (United States)

    Martins, Cyril; Lenz, Benjamin; Perfetti, Luca; Brouet, Veronique; Bertran, François; Biermann, Silke

    2018-03-01

    We address the role of nonlocal Coulomb correlations and short-range magnetic fluctuations in the high-temperature phase of Sr2IrO4 within state-of-the-art spectroscopic and first-principles theoretical methods. Introducing an "oriented-cluster dynamical mean-field scheme", we compute momentum-resolved spectral functions, which we find to be in excellent agreement with angle-resolved photoemission spectra. We show that while short-range antiferromagnetic fluctuations are crucial to accounting for the electronic properties of Sr2IrO4 even in the high-temperature paramagnetic phase, long-range magnetic order is not a necessary ingredient of the insulating state. Upon doping, an exotic metallic state is generated, exhibiting cuprate-like pseudo-gap spectral properties, for which we propose a surprisingly simple theoretical mechanism.

  3. Correlation-induced spectral changes and energy conservation

    International Nuclear Information System (INIS)

    Agarwal, G.S.; Wolf, E.

    1996-01-01

    An energy conservation law is derived for fields generated by random, statistically stationary, scalar sources of any state of coherence. It is shown that correlation-induced spectral changes are in strict agreement with this law and that, basic to the understanding of such changes, is a distinction that must be made between the spectrum of a source and the spectrum of the field that the source generates. This distinction, which is obviously relevant for spectroscopy, does not appear to have been previously recognized. copyright 1996 The American Physical Society

  4. Inter-comparison of MARS and FLUKA: Predictions on Energy Deposition in LHC IR Quadrupoles

    CERN Document Server

    Hoa, C; Cerutti, F; Ferrai, A

    2008-01-01

    Detailed modellings of the LHC insertion regions (IR) have earlier been performed to evaluate energy deposition in the IR superconducting magnets [1-4]. Proton-proton collisions at 14 TeV in the centre of mass lead to debris, depositing energy in the IR components. To evaluate uncertainties in those simulations and gain further confidence in the tools and approaches used, inter-comparison calculations have been performed with the latest versions of the FLUKA (2006.3b) [5, 6] and MARS15 [7, 8] Monte Carlo codes. These two codes, used worldwide for multi particle interaction and transport in accelerator, detector and shielding components, have been thoroughly benchmarked by the code authors and the user community (see, for example, recent [9, 10]). In the study described below, a better than 5% agreement was obtained for energy deposition calculated with these two codes - based on different independent physics models - for the identical geometry and initial conditions of a simple model representing the IR5 and ...

  5. Inter-comparison of MARS and FLUKA: Predictions on energy deposition in LHC IR quadrupoles

    International Nuclear Information System (INIS)

    Hoa, Christine; Cerutti, F.; Ferrari, A.; Mokhov, N.V.

    2008-01-01

    Detailed modelings of the LHC insertion regions (IR) have earlier been performed to evaluate energy deposition in the IR superconducting magnets [1-4]. Proton-proton collisions at 14 TeV in the centre of mass lead to debris, depositing energy in the IR components. To evaluate uncertainties in those simulations and gain further confidence in the tools and approaches used, inter-comparison calculations have been performed with the latest versions of the FLUKA (2006.3b) [5, 6] and MARS15 [7, 8] Monte Carlo codes. These two codes, used worldwide for multi particle interaction and transport in accelerator, detector and shielding components, have been thoroughly benchmarked by the code authors and the user community (see, for example, recent [9, 10]). In the study described below, a better than 5% agreement was obtained for energy deposition calculated with these two codes--based on different independent physics models--for the identical geometry and initial conditions of a simple model representing the IR5 and its first quadrupole

  6. Star formation relations and CO spectral line energy distributions across the J-ladder and redshift

    Energy Technology Data Exchange (ETDEWEB)

    Greve, T. R. [Department of Physics and Astronomy, University College London, Gower Street, London WC1E 6BT (United Kingdom); Leonidaki, I.; Xilouris, E. M. [Institute for Astronomy, Astrophysics, Space Applications and Remote Sensing, National Observatory of Athens, GR-15236 Penteli (Greece); Weiß, A.; Henkel, C. [Max-Planck-Institut fur Radioastronomie, Auf dem Hügel 69, D-53121 Bonn (Germany); Zhang, Z.-Y. [UK Astronomy Technology Centre, Science and Technology Facilities Council, Royal Observatory, Blackford Hill, Edinburgh EH9 3HJ (United Kingdom); Van der Werf, P.; Meijerink, R. [Leiden Observatory, Leiden University, PO Box 9513, NL-2300 RA Leiden (Netherlands); Aalto, S. [Department of Earth and Space Sciences, Chalmers University of Technology, Onsala Observatory, 43994 Onsala (Sweden); Armus, L.; Díaz-Santos, T. [Spitzer Science Center, California Institute of Technology, MS 220-6, Pasadena, CA 91125 (United States); Evans, A. S. [Astronomy Department, University of Virginia Charlottesville, VA 22904 (United States); Fischer, J. [Naval Research Laboratory, Remote Sensing Division, 4555 Overlook Avenue SW, Washington, DC 20375 (United States); Gao, Y. [Purple Mountain Observatory, Chinese Academy of Sciences, 2 West Beijing Road, Nanjing 210008 (China); González-Alfonso, E. [Universidad de Alcala de Henares, Departamento de Fśica, Campus Universitario, E-28871 Alcalá de Henares, Madrid (Spain); Harris, A. [Department of Astronomy, University of Maryland, College Park, MD 20742 (United States); Naylor, D. A. [Institute for Space Imaging Science, Department of Physics and Astronomy, University of Lethbridge, Lethbridge, AB T1K 3M4 (Canada); Smith, H. A. [Harvard Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States); Spaans, M., E-mail: t.greve@ucl.ac.uk [Kapteyn Astronomical Institute, University of Groningen, PO Box 800, 9700 AV Groningen (Netherlands); and others

    2014-10-20

    We present FIR [50-300 μm]–CO luminosity relations (i.e., log L{sub FIR}=αlog L{sub CO}{sup ′}+β) for the full CO rotational ladder from J = 1-0 up to J = 13-12 for a sample of 62 local (z ≤ 0.1) (Ultra) Luminous Infrared Galaxies (LIRGs; L {sub IR[8-1000} {sub μm]} > 10{sup 11} L {sub ☉}) using data from Herschel SPIRE-FTS and ground-based telescopes. We extend our sample to high redshifts (z > 1) by including 35 submillimeter selected dusty star forming galaxies from the literature with robust CO observations, and sufficiently well-sampled FIR/submillimeter spectral energy distributions (SEDs), so that accurate FIR luminosities can be determined. The addition of luminous starbursts at high redshifts enlarge the range of the FIR–CO luminosity relations toward the high-IR-luminosity end, while also significantly increasing the small amount of mid-J/high-J CO line data (J = 5-4 and higher) that was available prior to Herschel. This new data set (both in terms of IR luminosity and J-ladder) reveals linear FIR–CO luminosity relations (i.e., α ≅ 1) for J = 1-0 up to J = 5-4, with a nearly constant normalization (β ∼ 2). In the simplest physical scenario, this is expected from the (also) linear FIR–(molecular line) relations recently found for the dense gas tracer lines (HCN and CS), as long as the dense gas mass fraction does not vary strongly within our (merger/starburst)-dominated sample. However, from J = 6-5 and up to the J = 13-12 transition, we find an increasingly sublinear slope and higher normalization constant with increasing J. We argue that these are caused by a warm (∼100 K) and dense (>10{sup 4} cm{sup –3}) gas component whose thermal state is unlikely to be maintained by star-formation-powered far-UV radiation fields (and thus is no longer directly tied to the star formation rate). We suggest that mechanical heating (e.g., supernova-driven turbulence and shocks), and not cosmic rays, is the more likely source of energy for

  7. Identification and characterization of salmonella serotypes using DNA spectral characteristics by fourier transform infrared (FT-IR) spectroscopy

    Science.gov (United States)

    Analysis of DNA samples of Salmonella serotypes (Salmonella Typhimurium, Salmonella Enteritidis, Salmonella Infantis, Salmonella Heidelberg and Salmonella Kentucky) were performed using Fourier transform infrared spectroscopy (FT-IR) spectrometer by placing directly in contact with a diamond attenua...

  8. THE HERSCHEL ORION PROTOSTAR SURVEY: SPECTRAL ENERGY DISTRIBUTIONS AND FITS USING A GRID OF PROTOSTELLAR MODELS

    Energy Technology Data Exchange (ETDEWEB)

    Furlan, E. [Infrared Processing and Analysis Center, California Institute of Technology, 770 S. Wilson Ave., Pasadena, CA 91125 (United States); Fischer, W. J. [Goddard Space Flight Center, 8800 Greenbelt Road, Greenbelt, MD 20771 (United States); Ali, B. [Space Science Institute, 4750 Walnut Street, Boulder, CO 80301 (United States); Stutz, A. M. [Max-Planck-Institut für Astronomie, Königstuhl 17, D-69117 Heidelberg (Germany); Stanke, T. [ESO, Karl-Schwarzschild-Strasse 2, D-85748 Garching bei München (Germany); Tobin, J. J. [National Radio Astronomy Observatory, Charlottesville, VA 22903 (United States); Megeath, S. T.; Booker, J. [Ritter Astrophysical Research Center, Department of Physics and Astronomy, University of Toledo, 2801 W. Bancroft Street, Toledo, OH 43606 (United States); Osorio, M. [Instituto de Astrofísica de Andalucía, CSIC, Camino Bajo de Huétor 50, E-18008 Granada (Spain); Hartmann, L.; Calvet, N. [Department of Astronomy, University of Michigan, 500 Church Street, Ann Arbor, MI 48109 (United States); Poteet, C. A. [New York Center for Astrobiology, Rensselaer Polytechnic Institute, 110 Eighth Street, Troy, NY 12180 (United States); Manoj, P. [Department of Astronomy and Astrophysics, Tata Institute of Fundamental Research, Homi Bhabha Road, Colaba, Mumbai 400005 (India); Watson, D. M. [Department of Physics and Astronomy, University of Rochester, Rochester, NY 14627 (United States); Allen, L., E-mail: furlan@ipac.caltech.edu [National Optical Astronomy Observatory, 950 N. Cherry Avenue, Tucson, AZ 85719 (United States)

    2016-05-01

    We present key results from the Herschel Orion Protostar Survey: spectral energy distributions (SEDs) and model fits of 330 young stellar objects, predominantly protostars, in the Orion molecular clouds. This is the largest sample of protostars studied in a single, nearby star formation complex. With near-infrared photometry from 2MASS, mid- and far-infrared data from Spitzer and Herschel , and submillimeter photometry from APEX, our SEDs cover 1.2–870 μ m and sample the peak of the protostellar envelope emission at ∼100 μ m. Using mid-IR spectral indices and bolometric temperatures, we classify our sample into 92 Class 0 protostars, 125 Class I protostars, 102 flat-spectrum sources, and 11 Class II pre-main-sequence stars. We implement a simple protostellar model (including a disk in an infalling envelope with outflow cavities) to generate a grid of 30,400 model SEDs and use it to determine the best-fit model parameters for each protostar. We argue that far-IR data are essential for accurate constraints on protostellar envelope properties. We find that most protostars, and in particular the flat-spectrum sources, are well fit. The median envelope density and median inclination angle decrease from Class 0 to Class I to flat-spectrum protostars, despite the broad range in best-fit parameters in each of the three categories. We also discuss degeneracies in our model parameters. Our results confirm that the different protostellar classes generally correspond to an evolutionary sequence with a decreasing envelope infall rate, but the inclination angle also plays a role in the appearance, and thus interpretation, of the SEDs.

  9. Fermi energy 5f spectral weight variation in uranium alloys

    Energy Technology Data Exchange (ETDEWEB)

    Denlinger, J.D.; Clack, J.; Allen, J.W. [Univ. of Michigan, Ann Arbor, MI (United States)] [and others

    1997-04-01

    Uranium materials display a wide range of thermal, electrical and magnetic properties, often exotic. For more than a decade there have been efforts to use photoemission spectroscopy to develop a systematic and unified understanding of the 5f electron states giving rise to this behavior. These efforts have been hampered by a paucity of systems where changes in transport properties are accompanied by substantial spectral changes, so as to allow an attempt to correlate the two kinds of properties within some model. The authors have made resonant photoemission measurements to extract the 5f spectral weight in three systems which show varying degrees of promise of permitting such an attempt, Y{sub 1{minus}x}U{sub x}Pd{sub 3}, U(Pd{sub x}Pt{sub 1{minus}x}){sub 3} and U(Pd{sub x}Cu{sub 1{minus}x}){sub 5}. They have also measured U 4f core level spectra. The 4f spectra can be modeled with some success by the impurity Anderson model (IAM), and the 5f spectra are currently being analyzed in that framework. The IAM characterizes the 5f-electrons of a single site by an f binding energy {epsilon}{sub f}, an f Coulomb interaction and a hybridization V to conduction electrons. Latent in the model are the phenomena of 5f mixed valence and the Kondo effect.

  10. Invited Article: Multiple-octave spanning high-energy mid-IR supercontinuum generation in bulk quadratic nonlinear crystals

    Directory of Open Access Journals (Sweden)

    Binbin Zhou

    2016-08-01

    Full Text Available Bright and broadband coherent mid-IR radiation is important for exciting and probing molecular vibrations. Using cascaded nonlinearities in conventional quadratic nonlinear crystals like lithium niobate, self-defocusing near-IR solitons have been demonstrated that led to very broadband supercontinuum generation in the visible, near-IR, and short-wavelength mid-IR. Here we conduct an experiment where a mid-IR crystal is pumped in the mid-IR. The crystal is cut for noncritical interaction, so the three-wave mixing of a single mid-IR femtosecond pump source leads to highly phase-mismatched second-harmonic generation. This self-acting cascaded process leads to the formation of a self-defocusing soliton at the mid-IR pump wavelength and after the self-compression point multiple octave-spanning supercontinua are observed. The results were recorded in a commercially available crystal LiInS2 pumped in the 3-4 μm range with 85 fs 50 μJ pulse energy, with the broadest supercontinuum covering 1.6-7.0 μm. We measured up 30 μJ energy in the supercontinuum, and the energy promises to scale favorably with an increased pump energy. Other mid-IR crystals can readily be used as well to cover other pump wavelengths and target other supercontinuum wavelength ranges.

  11. iSEDfit: Bayesian spectral energy distribution modeling of galaxies

    Science.gov (United States)

    Moustakas, John

    2017-08-01

    iSEDfit uses Bayesian inference to extract the physical properties of galaxies from their observed broadband photometric spectral energy distribution (SED). In its default mode, the inputs to iSEDfit are the measured photometry (fluxes and corresponding inverse variances) and a measurement of the galaxy redshift. Alternatively, iSEDfit can be used to estimate photometric redshifts from the input photometry alone. After the priors have been specified, iSEDfit calculates the marginalized posterior probability distributions for the physical parameters of interest, including the stellar mass, star-formation rate, dust content, star formation history, and stellar metallicity. iSEDfit also optionally computes K-corrections and produces multiple "quality assurance" (QA) plots at each stage of the modeling procedure to aid in the interpretation of the prior parameter choices and subsequent fitting results. The software is distributed as part of the impro IDL suite.

  12. HIGH-REDSHIFT DUST OBSCURED GALAXIES: A MORPHOLOGY-SPECTRAL ENERGY DISTRIBUTION CONNECTION REVEALED BY KECK ADAPTIVE OPTICS

    International Nuclear Information System (INIS)

    Melbourne, J.; Matthews, K.; Soifer, B. T.

    2009-01-01

    A simple optical to mid-IR color selection, R - [24]>14, i.e., f ν (24 μm)/f ν (R) ∼> 1000, identifies highly dust obscured galaxies (DOGs) with typical redshifts of z ∼ 2 ± 0.5. Extreme mid-IR luminosities (L IR > 10 12-14 ) suggest that DOGs are powered by a combination of active galactic nuclei (AGNs) and star formation, possibly driven by mergers. In an effort to compare their photometric properties with their rest-frame optical morphologies, we obtained high-spatial resolution (0.''05-0.''1) Keck Adaptive Optics K'-band images of 15 DOGs. The images reveal a wide range of morphologies, including small exponential disks (eight of 15), small ellipticals (four of 15), and unresolved sources (two of 15). One particularly diffuse source could not be classified because of low signal-to-noise ratio. We find a statistically significant correlation between galaxy concentration and mid-IR luminosity, with the most luminous DOGs exhibiting higher concentration and smaller physical size. DOGs with high concentration also tend to have spectral energy distributions (SEDs) suggestive of AGN activity. Thus, central AGN light may be biasing the morphologies of the more luminous DOGs to higher concentration. Conversely, more diffuse DOGs tend to show an SED shape suggestive of star formation. Two of 15 in the sample show multiple resolved components with separations of ∼1 kpc, circumstantial evidence for ongoing mergers.

  13. THE SPECTRAL ENERGY DISTRIBUTIONS AND INFRARED LUMINOSITIES OF z ≈ 2 DUST-OBSCURED GALAXIES FROM Herschel AND Spitzer

    International Nuclear Information System (INIS)

    Melbourne, J.; Soifer, B. T.; Desai, Vandana; Armus, Lee; Pope, Alexandra; Alberts, Stacey; Dey, Arjun; Jannuzi, B. T.; Bussmann, R. S.

    2012-01-01

    Dust-obscured galaxies (DOGs) are a subset of high-redshift (z ≈ 2) optically-faint ultra-luminous infrared galaxies (ULIRGs, e.g., L IR > 10 12 L ☉ ). We present new far-infrared photometry, at 250, 350, and 500 μm (observed-frame), from the Herschel Space Telescope for a large sample of 113 DOGs with spectroscopically measured redshifts. Approximately 60% of the sample are detected in the far-IR. The Herschel photometry allows the first robust determinations of the total infrared luminosities of a large sample of DOGs, confirming their high IR luminosities, which range from 10 11.6 L ☉ IR (8-1000 μm) 13.6 L ☉ . 90% of the Herschel-detected DOGs in this sample are ULIRGs and 30% have L IR > 10 13 L ☉ . The rest-frame near-IR (1-3 μm) spectral energy distributions (SEDs) of the Herschel-detected DOGs are predictors of their SEDs at longer wavelengths. DOGs with 'power-law' SEDs in the rest-frame near-IR show observed-frame 250/24 μm flux density ratios similar to the QSO-like local ULIRG, Mrk 231. DOGs with a stellar 'bump' in their rest-frame near-IR show observed-frame 250/24 μm flux density ratios similar to local star-bursting ULIRGs like NGC 6240. None show 250/24 μm flux density ratios similar to extreme local ULIRG, Arp 220; though three show 350/24 μm flux density ratios similar to Arp 220. For the Herschel-detected DOGs, accurate estimates (within ∼25%) of total IR luminosity can be predicted from their rest-frame mid-IR data alone (e.g., from Spitzer observed-frame 24 μm luminosities). Herschel-detected DOGs tend to have a high ratio of infrared luminosity to rest-frame 8 μm luminosity (the IR8 = L IR (8-1000 μm)/νL ν (8 μm) parameter of Elbaz et al.). Instead of lying on the z = 1-2 'infrared main sequence' of star-forming galaxies (like typical LIRGs and ULIRGs at those epochs) the DOGs, especially large fractions of the bump sources, tend to lie in the starburst sequence. While, Herschel-detected DOGs are similar to scaled up

  14. Thermodynamics of interacting holographic dark energy with the apparent horizon as an IR cutoff

    International Nuclear Information System (INIS)

    Sheykhi, Ahmad

    2010-01-01

    As soon as an interaction between holographic dark energy and dark matter is taken into account, the identification of an IR cutoff with the Hubble radius H -1 , in a flat universe, can simultaneously drive accelerated expansion and solve the coincidence problem. Based on this, we demonstrate that in a non-flat universe the natural choice for the IR cutoff could be the apparent horizon radius, r-tilde A =1/√(H 2 +k/a 2 ). We show that any interaction of dark matter with holographic dark energy, whose infrared cutoff is set by the apparent horizon radius, implies an accelerated expansion and a constant ratio of the energy densities of both components thus solving the coincidence problem. We also verify that for a universe filled with dark energy and dark matter, the Friedmann equation can be written in the form of the modified first law of thermodynamics, dE = T h dS h + WdV, at the apparent horizon. In addition, the generalized second law of thermodynamics is fulfilled in a region enclosed by the apparent horizon. These results hold regardless of the specific form of dark energy and interaction term. Our study might reveal that in an accelerating universe with spatial curvature, the apparent horizon is a physical boundary from the thermodynamical point of view.

  15. Third-harmonic generation in silicon and photonic crystals of macroporous silicon in the spectral intermediate-IR range; Erzeugung der Dritten Harmonischen in Silizium und Photonischen Kristallen aus makroporoesem Silizium im spektralen mittleren IR-Bereich

    Energy Technology Data Exchange (ETDEWEB)

    Mitzschke, Kerstin

    2007-11-01

    Nonlinear optical spectroscopy is a powerful method to study surface or bulk properties of condensed matter. In centrosymmetric materials like silicon even order nonlinear optical processes are forbidden. Besides self-focussing or self phase modulation third-harmonic-generation (THG) is the simplest process that can be studied. This work demonstrates that THG is a adapted non-contact and non-invasive optical method to get information about bulk structures of silicon and Photonic crystals (PC), consisting of silicon. Until now most studies are done in the visible spectral range being limited by the linear absorption losses. So the extension of THG to the IR spectral range is extremely useful. This will allow the investigation of Photonic Crystals, where frequencies near a photonic bandgap are of special interest. 2D- photonic structures under investigation were fabricated via photoelectrochemical etching of the Si (100) wafer (thickness 500 {mu}m) receiving square and hexagonal arranged pores. The typical periodicity of the structures used is 2 {mu}m and the length of the pores reached to 400 {mu}m. Because of stability the photonic structures were superimposed on silicon substrate. The experimental set-up used for the THG experiments generates tuneable picosecond IR pulses (tuning range 1500-4000 cm{sup -1}). The IR-pulse hit the sample either perpendicular to the sample surface or under an angle {theta}. The sample can be rotated (f) around the surface normal. The generated third harmonic is analysed by a polarizer, spectrally filtered by a polychromator and registered by a CCD camera. The setup can be used either in transmission or in reflection mode. Optical transmission and reflection spectra of the Si bulk correspond well with the theoretical description, a 4-fold and a 8-fold dependencies of the azimuth angle resulting in the structure of the x{sup (3)}-tensor of (100)-Si. The situation changes dramatically if the PC with hexagonal structure is investigated

  16. Dosimetric evaluation of a new OneDose MOSFET for Ir-192 energy

    International Nuclear Information System (INIS)

    Kinhikar, Rajesh A; Sharma, Pramod K; Tambe, Chandrashekhar M; Deshpande, Deepak D

    2006-01-01

    The purpose of this study was to investigate dosimetry (reproducibility, energy correction, relative response with distance from source, linearity with threshold dose, rate of fading, temperature and angular dependence) of a newly designed OneDose TM MOSFET patient dosimetry system for use in HDR brachytherapy with Ir-192 energy. All measurements were performed with a MicroSelectron HDR unit and OneDose MOSFET detectors. All dosimeters were normalized to 3 min post-irradiation to minimize fading effects. All dosimeters gave reproducible readings with mean deviation of 1.8% (SD 0.4) and 2.4% (SD 0.6) for 0 0 and 180 0 incidences, respectively. The mean energy correction factor was found to be 1.1 (range 1.06-1.12). Overall, there was 60% and 40% mean response of the MOSFET at 2 and 3 cm, respectively, from the source. MOSFET results showed good agreement with TLD and parallel plate ion chamber. Linear dose response with threshold voltage shift was observed with applied doses of 0.3 Gy-5 Gy with Ir-192 energy. Linearity (R 2 = 1) was observed in the MOSFET signal with the applied dose range of 0.3 Gy-5 Gy with Ir-192 energy. Fading effects were less than 1% after 10 min and the MOSFET detectors stayed stable (within 5%) over a period of 1 month. The MOSFET response was found to be decreased by approximately 1.5% at 37 deg. C compared to 20 deg. C. The isotropic response of the MOSFET was found to be within ±6%. A maximum deviation of 5.5% was obtained between 0 deg. and 180 deg. for both the axes and this should be considered in clinical applications. The small size, cable-less, instant readout, permanent storage of dose and ease of use make the MOSFET a novel dosimeter and beneficial to patients for skin dose measurements with HDRBT using an Ir-192 source compared to the labour demanding and time-consuming TLDs

  17. Simulated galaxy interactions as probes of merger spectral energy distributions

    Energy Technology Data Exchange (ETDEWEB)

    Lanz, Lauranne; Zezas, Andreas; Smith, Howard A.; Ashby, Matthew L. N.; Fazio, Giovanni G.; Hernquist, Lars [Harvard-Smithsonian Center for Astrophysics, 60 Garden St., Cambridge, MA 02138 (United States); Hayward, Christopher C. [Heidelberger Institut für Theoretische Studien, Schloss-Wolfsbrunnenweg 35, D-69118 Heidelberg (Germany); Brassington, Nicola, E-mail: llanz@ipac.caltech.edu [School of Physics, Astronomy and Mathematics, University of Hertfordshire, College Lane, Hatfield, AL10 9AB (United Kingdom)

    2014-04-10

    We present the first systematic comparison of ultraviolet-millimeter spectral energy distributions (SEDs) of observed and simulated interacting galaxies. Our sample is drawn from the Spitzer Interacting Galaxy Survey and probes a range of galaxy interaction parameters. We use 31 galaxies in 14 systems which have been observed with Herschel, Spitzer, GALEX, and 2MASS. We create a suite of GADGET-3 hydrodynamic simulations of isolated and interacting galaxies with stellar masses comparable to those in our sample of interacting galaxies. Photometry for the simulated systems is then calculated with the SUNRISE radiative transfer code for comparison with the observed systems. For most of the observed systems, one or more of the simulated SEDs match reasonably well. The best matches recover the infrared luminosity and the star formation rate of the observed systems, and the more massive systems preferentially match SEDs from simulations of more massive galaxies. The most morphologically distorted systems in our sample are best matched to the simulated SEDs that are close to coalescence, while less evolved systems match well with the SEDs over a wide range of interaction stages, suggesting that an SED alone is insufficient for identifying the interaction stage except during the most active phases in strongly interacting systems. This result is supported by our finding that the SEDs calculated for simulated systems vary little over the interaction sequence.

  18. Selection effects on GRB spectral-energy correlations

    International Nuclear Information System (INIS)

    Nava, Lara; Ghirlanda, Giancarlo; Ghisellini, Gabriele

    2009-01-01

    Instrumental selection effects can act upon the estimates of the peak energy E peak obs , the fluence F and the peak flux P of GRBs. If this were the case, then the correlations involving the corresponding rest frame quantities (i.e. E peak , E obs and the peak luminosity L iso ) would be questioned. We estimated, as a function of E peak obs , the minimum peak flux necessary to trigger a GRB and the minimum fluence a burst must have to determine the value of E peak obs by considering different instruments (BATSE, Swift, BeppoSAX). We find that the latter dominates over the former. We then study the E peak obs -fluence (and flux) correlation in the observer plane. GRBs with redshift show well defined E peak obs -F and E peak obs -P correlations: in this planes the selection effects are present, but do not determine the found correlations. This is not true for Swift GRBs with redshift, for which the spectral analysis threshold does affect their distribution in the observer planes. Extending the sample to GRBs without z, we still find a significant E peak obs -F correlation, although with a larger scatter than that defined by GRBs with redshift. We find that 6% are outliers of the Amati correlation. The E peak obs -P correlation of GRBs with or without redshift is the same and no outlier is found among bursts without redshift.

  19. Effect of source encapsulation on the energy spectra of sup 192 Ir and sup 137 Cs seed sources

    Energy Technology Data Exchange (ETDEWEB)

    Thomason, C [Wisconsin Univ., Madison, WI (USA). Dept. of Medical Physics; Mackie, T R [Wisconsin Univ., Madison, WI (USA). Dept. of Medical Physics Wisconsin Univ., Madison, WI (USA). Dept. of Human Oncology; Lindstrom, M J [Wisconsin Univ., Madison, WI (USA). Biostatistics Center

    1991-04-01

    The effect of source encapsulation on the energy spectra of {sup 192}Ir and {sup 137}Cs seed sources, both with stainless steel and with platinum encapsulation, was determined from results of Monte Carlo simulation. The fractional scatter dose around these sources has also been determined from Monte Carlo simulation. The platinum-encapsulated {sup 192}Ir source exhibited greater attenuation of the primary spectrum, as expected, and, consistent with this greater attenuation, exhibited more scattered radiation. Significantly less scatter was seen with the {sup 137}Cs source than with either {sup 192}Ir source, as is consistent with the higher-energy photons from {sup 137}Cs. (author).

  20. UV-Vis-IR spectral complex refractive indices and optical properties of brown carbon aerosol from biomass burning

    Science.gov (United States)

    Sumlin, Benjamin J.; Heinson, Yuli W.; Shetty, Nishit; Pandey, Apoorva; Pattison, Robert S.; Baker, Stephen; Hao, Wei Min; Chakrabarty, Rajan K.

    2018-02-01

    Constraining the complex refractive indices, optical properties and size of brown carbon (BrC) aerosols is a vital endeavor for improving climate models and satellite retrieval algorithms. Smoldering wildfires are the largest source of primary BrC, and fuel parameters such as moisture content, source depth, geographic origin, and fuel packing density could influence the properties of the emitted aerosol. We measured in situ spectral (375-1047 nm) optical properties of BrC aerosols emitted from smoldering combustion of Boreal and Indonesian peatlands across a range of these fuel parameters. Inverse Lorenz-Mie algorithms used these optical measurements along with simultaneously measured particle size distributions to retrieve the aerosol complex refractive indices (m = n + iκ). Our results show that the real part n is constrained between 1.5 and 1.7 with no obvious functionality in wavelength (λ), moisture content, source depth, or geographic origin. With increasing λ from 375 to 532 nm, κ decreased from 0.014 to 0.003, with corresponding increase in single scattering albedo (SSA) from 0.93 to 0.99. The spectral variability of κ follows the Kramers-Kronig dispersion relation for a damped harmonic oscillator. For λ ≥ 532 nm, both κ and SSA showed no spectral dependency. We discuss differences between this study and previous work. The imaginary part κ was sensitive to changes in FPD, and we hypothesize mechanisms that might help explain this observation.

  1. X-ray-phase and IR-spectral study of clay rocks mineral content of the Caspian Sea Gulf depression

    International Nuclear Information System (INIS)

    Zakonov, A.N.; Mukhanova, M.U.

    2000-01-01

    Samples of clays selected from different oil fields (Sazankurak, Kemerkol, Kozha and others) and deposition depths are examined on both the X-ray diffractometers (Dron-2 and Dron-4) and the infrared-spectrometers (IR-20). In this diagnostic the American file with different minerals X-ray systematized data is used. The X-ray reflections, which are in compliance with suitable inter-plane distances and clay impurities reflex intensities are determined. With confirmation purpose for mineral content correctness obtained according X-ray-phase analysis the infrared-spectrometric method is used, in which principal attention was paid to absorption field (3,400-3,700 cm -1 ) of H 2 O and OH valency frequency vibrations

  2. Aqueous Cation-Amide Binding: Free Energies and IR Spectral Signatures by Ab Initio Molecular Dynamics

    Czech Academy of Sciences Publication Activity Database

    Pluhařová, Eva; Baer, M. D.; Mundy, C. J.; Schmidt, B.; Jungwirth, Pavel

    2014-01-01

    Roč. 5, č. 13 (2014), s. 2235-2240 ISSN 1948-7185 R&D Projects: GA MŠk LH12001 Institutional support: RVO:61388963 Keywords : sodium * calcium * N -methylacetamide * peptide bond * umbrella sampling Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 7.458, year: 2014

  3. Exchange bias energy in Co/Pt/IrMn multilayers with perpendicular and in-plane anisotropy

    International Nuclear Information System (INIS)

    Czapkiewicz, M.; Stobiecki, T.; Rak, R.; Zoladz, M.; Dijken, S. van

    2007-01-01

    The magnetization reversal process in perpendicularly biased [Pt/Co] 3 /d Pt Pt/IrMn and in-plane biased Co/d Pt Pt/IrMn multilayers with 0nm= Pt = Pt =0.1nm. In both cases, the existence of large exchange bias fields correlates with a high domain density during magnetization reversal. The interface exchange coupling energy is larger for the in-plane biased films than for the perpendicularly biased multilayers

  4. Raman and Mid-IR Spectral Analysis of the Atacamite-Structure Hydroxyl/Deuteroxyl Nickel Chlorides Ni2(OH/D)3Cl

    Institute of Scientific and Technical Information of China (English)

    LIU Xiao-Dong; Hagihala Masato; ZHENG Xu-Guang; MENG Dong-Doug; GUO Qi-Xin

    2011-01-01

    @@ Vibrational spectra(Raman 4000-95cm-1 and mid-IR 4000-400cm-1) of the atacamite-structure Ni2(OH)3Cl,including a rarely reported kind of asymmetric trimetric hydrogen bond, as a member of the geometrically frustrated material series and its deuteride Ni2(OD)3Cl are, to the best of our knowledge, reported for the first time and analyzed at room temperature.Through a comparative study of four spectra according to their crystal structural parameters, we assign OH stretching modes v(OH) in a functional group region(3700-3400 cm-1) and their deformation modes δ(NiOH/D) in the correlation peak region(900-600 cm-1)with the corresponding mode frequency ratios ωv(OD)/ωv(OH)≈73% and ωδ(NiOD)/ωδ(NiOH)≈75%, and further self-consistently suggest NiO and Ni-Cl related modes in the fingerprint region(500-200cm-1 and 200-Ocm-1, respectively) by use of the unified six-ligand NiO5Cl and NiO4Cl2 frames.This report may contribute to the spectral analysis of other hydroxyl transition-metal halides and to the understanding of the fundamental physics of their exotic magnetic geometrical frustration property from the spectral changes around the corresponding low transition temperatures.

  5. Spectral and dual-energy X-ray imaging for medical applications

    Science.gov (United States)

    Fredenberg, Erik

    2018-01-01

    Spectral imaging is an umbrella term for energy-resolved X-ray imaging in medicine. The technique makes use of the energy dependence of X-ray attenuation to either increase the contrast-to-noise ratio, or to provide quantitative image data and reduce image artefacts by so-called material decomposition. Spectral imaging is not new, but has gained interest in recent years because of rapidly increasing availability of spectral and dual-energy CT and the dawn of energy-resolved photon-counting detectors. This review examines the current technological status of spectral and dual-energy imaging and a number of practical applications of the technology in medicine.

  6. Investigation on water content in fresco mock-ups in the microwave and near-IR spectral regions

    International Nuclear Information System (INIS)

    Magrini, Donata; Riminesi, Cristiano; Cucci, Costanza; Olmi, Roberto; Picollo, Marcello

    2017-01-01

    Water diffusion inside masonry is responsible for the majority of the decay phenomena observed in wall paintings and frescos. Thus, the diagnostics of moisture and water content and their monitoring represent a key issue. In order to preserve the integrity of surfaces of artistic interest, investigations by means of non-destructive techniques (NDT) are preferred over others. The aim of this research is to determine methodologies to quantify the moisture content (MC) of frescos by means of the integrated use of two non-invasive techniques, namely fiber optic reflectance spectroscopy (FORS) in the near-IR region and evanescent field dielectrometry (EFD) in the microwave range. The FORS technique has been employed in order to assess the amount of water adsorbed from the surface by means of an analysis of the reflectance spectra in the Vis–NIR (350-2200 nm) range. This technique investigates the electronic and vibrational transitions that are characteristic of each compound and enables their identification. The water content is evaluated on the basis of the 1920 nm and 1450 nm absorption bands. The EFD system consists of a resonant probe connected to a network analyzer. The resonance frequency of the cavity under different moisture-content conditions of frescos is in the 1.0–1.5 GHz range. The device makes it possible to compute, in real time, the MC from a measurement of the transmission coefficient (amplitude versus frequency) through the probe. Fresco mock-ups have been prepared in collaboration with the Opificio delle Pietre Dure in order to recreate most of the possible chromatic shades obtained by mixing iron oxides and hydroxide-based pigments. Measurements were performed by employing both techniques on fresco models after wet-dry cycles obtained by means of poultices with a known water content. The results obtained with these two techniques were compared, and cross relationships between the EFD and FORS data were defined. (paper)

  7. Spectral filter for splitting a beam with electromagnetic radiation having wavelengths in the extreme ultraviolet (EUV) or soft X-Ray (Soft X) and the infrared (IR) wavelength range

    NARCIS (Netherlands)

    van Goor, F.A.; Bijkerk, Frederik; van den Boogaard, Toine; van den Boogaard, A.J.R.; van der Meer, R.

    2012-01-01

    Spectral filter for splitting the primary radiation from a generated beam with primary electromagnetic radiation having a wavelength in the extreme ultraviolet (EUV radiation) or soft X-ray (soft X) wavelength range and parasitic radiation having a wavelength in the infrared wavelength range (IR

  8. Spectrally and Energy Efficient OFDM (SEE-OFDM) for Intensity Modulated Optical Wireless Systems

    OpenAIRE

    Lam, Emily; Wilson, Sarah Kate; Elgala, Hany; Little, Thomas D. C.

    2015-01-01

    Spectrally and energy efficient orthogonal frequency division multiplexing (SEE-OFDM) is an optical OFDM technique based on combining multiple asymmetrically clipped optical OFDM (ACO-OFDM) signals into one OFDM signal. By summing different components together, SEE-OFDM can achieve the same spectral efficiency as DC-biased optical OFDM (DCO-OFDM) without an energy-inefficient DC-bias. This paper introduces multiple methods for decoding a SEE-OFDM symbol and shows that an iterative decoder wit...

  9. Electron-energy-loss spectral library and its application to materials science

    Energy Technology Data Exchange (ETDEWEB)

    Zaluzec, N.J.

    1983-09-01

    An electron energy loss spectral library can be an invaluable tool in materials research from a fundamental as well as a practical standpoint. Although it will not alleviate all the complications associated with quantification, this type of library can help to elucidate details of spectral profiles previously found intractable. This work was supported by the US Department of Energy. The author also wishes to express his gratitude to the organizing committee for partial financial support provided to attend this meeting.

  10. THE IMPACT OF EVOLVING INFRARED SPECTRAL ENERGY DISTRIBUTIONS OF GALAXIES ON STAR FORMATION RATE ESTIMATES

    Energy Technology Data Exchange (ETDEWEB)

    Nordon, R.; Lutz, D.; Genzel, R.; Berta, S.; Wuyts, S.; Magnelli, B.; Foerster Schreiber, N. M.; Poglitsch, A.; Popesso, P. [Max-Planck-Institut fuer extraterrestrische Physik, Postfach 1312, 85741 Garching (Germany); Altieri, B. [Herschel Science Centre, European Space Astronomy Centre, ESA, Villanueva de al Canada, 28691 Madrid (Spain); Andreani, P. [ESO, Karl-Schwarzschild-Str. 2, D-85748 Garching (Germany); Aussel, H.; Daddi, E. [Laboratoire AIM, CEA/DSM-CNRS-Universite Paris Diderot, IRFU/Service d' Astrophysique, Bat.709, CEA-Saclay, 91191 Gif-sur-Yvette Cedex (France); Bongiovanni, A.; Cepa, J.; Perez Garcia, A. M. [Instituto de Astrofisica de Canarias, 38200 La Laguna, Tenerife (Spain); Cimatti, A. [Dipartimento di Astronomia, Universita di Bologna, Via Ranzani 1, 40127 Bologna (Italy); Fadda, D. [IPAC, California Institute of Technology, Pasadena, CA 91125 (United States); Lagache, G. [Institut d' Astrophysique Spatiale (IAS), Bat 121, Universite de Paris XI, 91450 Orsay Cedex (France); Maiolino, R., E-mail: nordon@mpe.mpg.de [INAF-Osservatorio Astronomico di Roma, via di Frascati 33, 00040 Monte Porzio Catone (Italy); and others

    2012-02-01

    We combine Herschel-Photodetector Array Camera and Spectrometer (PACS) data from the PACS Evolutionary Probe (PEP) program with Spitzer 24 {mu}m and 16 {mu}m photometry and ultra deep Infrared Spectrograph (IRS) mid-infrared spectra to measure the mid- to far-infrared spectral energy distribution (SED) of 0.7 < z < 2.5 normal star-forming galaxies (SFGs) around the main sequence (the redshift-dependent relation of star formation rate (SFR) and stellar mass). Our very deep data confirm from individual far-infrared detections that z {approx} 2 SFRs are overestimated if based on 24 {mu}m fluxes and SED templates that are calibrated via local trends with luminosity. Galaxies with similar ratios of rest-frame {nu}L{sub {nu}}(8) to 8-1000 {mu}m infrared luminosity (LIR) tend to lie along lines of constant offset from the main sequence. We explore the relation between SED shape and offset in specific star formation rate (SSFR) from the redshift-dependent main sequence. Main-sequence galaxies tend to have a similar {nu}L{sub {nu}}(8)/LIR regardless of LIR and redshift, up to z {approx} 2.5, and {nu}L{sub {nu}}(8)/LIR decreases with increasing offset above the main sequence in a consistent way at the studied redshifts. We provide a redshift-independent calibration of SED templates in the range of 8-60 {mu}m as a function of {Delta}log(SSFR) offset from the main sequence. Redshift dependency enters only through the evolution of the main sequence with time. Ultra deep IRS spectra match these SED trends well and verify that they are mostly due to a change in ratio of polycyclic aromatic hydrocarbon (PAH) to LIR rather than continua of hidden active galactic nuclei (AGNs). Alternatively, we discuss the dependence of {nu}L{sub {nu}}(8)/LIR on LIR. The same {nu}L{sub {nu}}(8)/LIR is reached at increasingly higher LIR at higher redshift, with shifts relative to local by 0.5 and 0.8 dex in log(LIR) at redshifts z {approx} 1 and z {approx} 2. Corresponding SED template calibrations

  11. Image enhancement by spectral-error correction for dual-energy computed tomography.

    Science.gov (United States)

    Park, Kyung-Kook; Oh, Chang-Hyun; Akay, Metin

    2011-01-01

    Dual-energy CT (DECT) was reintroduced recently to use the additional spectral information of X-ray attenuation and aims for accurate density measurement and material differentiation. However, the spectral information lies in the difference between low and high energy images or measurements, so that it is difficult to acquire accurate spectral information due to amplification of high pixel noise in the resulting difference image. In this work, an image enhancement technique for DECT is proposed, based on the fact that the attenuation of a higher density material decreases more rapidly as X-ray energy increases. We define as spectral error the case when a pixel pair of low and high energy images deviates far from the expected attenuation trend. After analyzing the spectral-error sources of DECT images, we propose a DECT image enhancement method, which consists of three steps: water-reference offset correction, spectral-error correction, and anti-correlated noise reduction. It is the main idea of this work that makes spectral errors distributed like random noise over the true attenuation and suppressed by the well-known anti-correlated noise reduction. The proposed method suppressed noise of liver lesions and improved contrast between liver lesions and liver parenchyma in DECT contrast-enhanced abdominal images and their two-material decomposition.

  12. Free-air ionization chamber, FAC-IR-300, designed for medium energy X-ray dosimetry

    International Nuclear Information System (INIS)

    Mohammadi, S.M.; Tavakoli-Anbaran, H.; Zeinali, H.Z.

    2017-01-01

    The primary standard for X-ray photons is based on parallel-plate free-air ionization chamber (FAC). Therefore, the Atomic Energy Organization of Iran (AEOI) is tried to design and build the free-air ionization chamber, FAC-IR-300, for low and medium energy X-ray dosimetry. The main aim of the present work is to investigate specification of the FAC-IR-300 ionization chamber and design it. FAC-IR-300 dosimeter is composed of two parallel plates, a high voltage (HV) plate and a collector plate, along with a guard electrode that surrounds the collector plate. The guard plate and the collector were separated by an air gap. For obtaining uniformity in the electric field distribution, a group of guard strips was used around the ionization chamber. These characterizations involve determining the exact dimensions of the ionization chamber by using Monte Carlo simulation and introducing correction factors.

  13. Energy Efficient LED Spectrally Matched Smart Lighting, Phase II

    Data.gov (United States)

    National Aeronautics and Space Administration — Innovative Imaging and Research and the University of Houston Clear Lake have teamed to develop a widely extensible, affordable, energy efficient, smart lighting...

  14. A mass and energy conserving spectral element atmospheric dynamical core on the cubed-sphere grid

    International Nuclear Information System (INIS)

    Taylor, M A; Edwards, J; Thomas, S; Nair, R

    2007-01-01

    We present results from a conservative formulation of the spectral element method applied to global atmospheric circulation modeling. Exact local conservation of both mass and energy is obtained via a new compatible formulation of the spectral element method. Compatibility insures that the key integral property of the divergence and gradient operators required to show conservation also hold in discrete form. The spectral element method is used on a cubed-sphere grid to discretize the horizontal directions on the sphere. It can be coupled to any conservative vertical/radial discretization. The accuracy and conservation properties of the method are illustrated using a baroclinic instability test case

  15. Examining the structural evolution of bicarbonate–water clusters: insights from photoelectron spectroscopy, basin-hopping structural search, and comparison with available IR spectral studies

    Energy Technology Data Exchange (ETDEWEB)

    Wen, Hui [Chinese Academy of Sciences (CAS), Hefei (China). Lab. of Atmospheric Physico-Chemistry, Anhui Inst. of Optics & Fine Mechanics; Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Physical Sciences Division; Hou, Gao-Lei [Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Physical Sciences Division; Liu, Yi-Rong [Chinese Academy of Sciences (CAS), Hefei (China). Lab. of Atmospheric Physico-Chemistry, Anhui Inst. of Optics & Fine Mechanics; Wang, Xue-Bin [Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Physical Sciences Division; Huang, Wei [Chinese Academy of Sciences (CAS), Hefei (China). Lab. of Atmospheric Physico-Chemistry, Anhui Inst. of Optics & Fine Mechanics; Univ. of Science and Technology of China, Hefei (China). School of Environmental Science & Optoelectronic Technology

    2016-05-31

    Bicarbonate serves a crucial biochemical role in the physiological pH buffering system and also has important atmospheric implications. In the current study, HCO3$-$(H2O)n (n = 0-13) clusters were successfully produced via electrospray ionization of corresponding bulk salt solution, and were characterized by combining negative ion photoelectron spectroscopy and theoretical calculations. The photoelectron spectra reveal that the electron binding energy monotonically increases with the cluster size up to n = 10 and remains largely the same after n > 10. The photo-detaching feature of the solute HCO3$-$itself, which dominates in the small clusters, diminishes with increase of water coverage. Based on the charge distribution and molecular orbital analyses, the universal high electron binding energy tail that dominates in the larger clusters can be attributed to ionization of water. Thus, the transition of ionization from solute to solvent at the size larger than n=10 has been observed. Extensive theoretical structural search based on the Basin-Hopping unbiased method was carried out, and a plethora of low energy isomers have been obtained for each medium and large size. By comparing the simulated photoelectron spectra and calculated electron binding energies with the experiments, as well as by comparing the simulated infrared spectra with previously reported IR spectra, the probable global minima and the structural evolutionary routes are presented. The nature of bicarbonate-water interactions are mainly electrostatic as implied by the electron localization function (ELF) analysis.

  16. Proposals of electronic-vibrational energy relaxation studies by using laser pulses synchronized with IR-SR pulses

    International Nuclear Information System (INIS)

    Nakagawa, Hideyuki

    2000-01-01

    Synchrotron radiation is expected to be the sharp infrared light source for the advanced experiments on IR and FIR spectroscopy in wide research fields. Especially, synchronized use of SR with VIS and/or UV laser light is to be a promising technique for the research on the dynamical properties of the photo-excited states in condensed materials. Some proposals are attempted for high resolution IR spectroscopy to elucidate fine interaction of molecular ions in crystalline solids with their environmental field and for time-resolved IR spectroscopic studies on the electronic and vibrational energy relaxation by using laser pulses synchronized with IR-SR pulses. Several experimental results are presented in relevance to the subjects; on high-resolution FTIR spectra of cyanide ions and metal cyanide complexes in cadmium halide crystals, on the energy up-conversion process among the vibrational levels of cyanide ions in alkali halide crystals, and on the electronic-to-vibrational energy conversion process in metal cyanide complexes. (author)

  17. Time evolution of the energy confinement time, internal inductance and effective edge safety factor on IR-T1 tokamak

    International Nuclear Information System (INIS)

    Salar Elahi, A; Ghoranneviss, M

    2010-01-01

    An attempt is made to investigate the time evolution of the energy confinement time, internal inductance and effective edge safety factor on IR-T1 tokamak. For this purpose, four magnetic pickup coils were designed, constructed and installed on the outer surface of the IR-T1 and then the Shafranov parameter (asymmetry factor) was obtained from them. On the other hand, also a diamagnetic loop was designed and installed on IR-T1 and poloidal beta was determined from it. Therefore, the internal inductance and effective edge safety factor were measured. Also, the time evolution of the energy confinement time was measured using the diamagnetic loop. Experimental results on IR-T1 show that the maximum energy confinement time (which corresponds to minimum collisions, minimum microinstabilities and minimum transport) is at low values of the effective edge safety factor (2.5 eff (a) i <0.72). The results obtained are in agreement with those obtained with the theoretical approach [1-5].

  18. Guided-wave approaches to spectrally selective energy absorption

    Science.gov (United States)

    Stegeman, G. I.; Burke, J. J.

    1987-01-01

    Results of experiments designed to demonstrate spectrally selective absorption in dielectric waveguides on semiconductor substrates are reported. These experiments were conducted with three waveguides formed by sputtering films of PSK2 glass onto silicon-oxide layers grown on silicon substrates. The three waveguide samples were studied at 633 and 532 nm. The samples differed only in the thickness of the silicon-oxide layer, specifically 256 nm, 506 nm, and 740 nm. Agreement between theoretical predictions and measurements of propagation constants (mode angles) of the six or seven modes supported by these samples was excellent. However, the loss measurements were inconclusive because of high scattering losses in the structures fabricated (in excess of 10 dB/cm). Theoretical calculations indicated that the power distribution among all the modes supported by these structures will reach its steady state value after a propagation length of only 1 mm. Accordingly, the measured loss rates were found to be almost independent of which mode was initially excited. The excellent agreement between theory and experiment leads to the conclusion that low loss waveguides confirm the predicted loss rates.

  19. Energy relaxation in IR laser excited Hg1-xCdxTe

    International Nuclear Information System (INIS)

    Storebo, A K; Brudevoll, T; Olsen, O; Norum, O C; Breivik, M

    2009-01-01

    IR laser excitation of Hg l-x Cd x Te by low-fluence femtosecond and high fluence microsecond pulses was explored for the technologically important alloy fractions x ∼ 0.2 and x ∼ 0.28. We have used first principles (LAPW) electronic structure calculations and finite element modelling, supported by Monte Carlo simulation for the description of femtosecond pulse carrier relaxation and the transport parameters. Laser wavelengths considered were 6.4 - 10.6 μm for x ∼ 0.2 and 3.8 - 4.8 μm for x ∼ 0.28, with an incident 1 microsecond pulse fluence of 2 J/cm 2 . Many energy transfer mechanisms are invoked due to the long timescales of the microsecond pulses, and a main challenge is therefore to elucidate how these interplay in situations away from thermal equilibrium. Mechanisms studied include one- and two-photon absorption (OPA and TPA) across the band gap, inter-valence band absorption (IVA) between light- and heavy hole bands, electron-hole recombination/impact ionization, band gap renormalisation, intra-band free carrier absorption (FCA), excess carrier temperatures, non-equilibrium phonon generation, and refractive index changes. In the high fluence case, lattice temperatures evolve considerably during the laser pulse in response to the heated carriers. The chosen photon energies lie just above the band gap at the starting lattice temperature of 77 K, and nonlinear effects therefore dominate as the material heats up and the band gap begins to exceed the photon energy. Because of the low photon energy we must rely on Auger recombination, inter-valence band absorption and free carrier absorption to heat the carrier plasma. Although some Hg l-x Cd x Te material parameters are now relatively well known, existing data for many of the processes are inadequate for cases far away from thermal equilibrium. Furthermore, the role of Auger recombination in relation to non-intrinsic recombination has been a matter of debate lately. In this respect, information from

  20. Coordination-resolved local bond relaxation, electron binding-energy shift, and Debye temperature of Ir solid skins

    Energy Technology Data Exchange (ETDEWEB)

    Bo, Maolin [Key Laboratory of Low-Dimensional Materials and Application Technologies, Ministry of Education, Xiangtan University, Xiangtan, Hunan 411105 (China); Wang, Yan [Key Laboratory of Low-Dimensional Materials and Application Technologies, Ministry of Education, Xiangtan University, Xiangtan, Hunan 411105 (China); School of Information and Electronic Engineering, Hunan University of Science and Technology, Xiangtan, Hunan 411201 (China); Huang, Yongli, E-mail: huangyongli@xtu.edu.cn [Key Laboratory of Low-Dimensional Materials and Application Technologies, Ministry of Education, Xiangtan University, Xiangtan, Hunan 411105 (China); Yang, Xuexian [Department of Physics, Jishou University, Jishou, Hunan 416000 (China); Yang, Yezi [Key Laboratory of Low-Dimensional Materials and Application Technologies, Ministry of Education, Xiangtan University, Xiangtan, Hunan 411105 (China); Li, Can [Center for Coordination Bond Engineering, School of Materials Science and Engineering, China Jiliang University, Hangzhou 330018 (China); Sun, Chang Q., E-mail: ecqsun@ntu.edu.sg [Key Laboratory of Low-Dimensional Materials and Application Technologies, Ministry of Education, Xiangtan University, Xiangtan, Hunan 411105 (China); NOVITAS, School of Electrical and Electronic Engineering, Nanyang Technological University, Singapore 639798 (Singapore)

    2014-11-30

    Highlights: • Cohesive energy of the representative bond determines the core-level shift. • XPS derives the energy level of an isolated atom and its bulk shift. • XPS derives the local bond length, bond energy, binding energy density. • Thermal XPS resolves the Debye temperature and atomic cohesive energy. - Abstract: Numerical reproduction of the measured 4f{sub 7/2} energy shift of Ir(1 0 0), (1 1 1), and (2 1 0) solid skins turns out the following: (i) the 4f{sub 7/2} level of an isolated Ir atom shifts from 56.367 eV to 60.332 eV by 3.965 eV upon bulk formation; (ii) the local energy density increases by up to 130% and the atomic cohesive energy decreases by 70% in the skin region compared with the bulk values. Numerical match to observation of the temperature dependent energy shift derives the Debye temperature that varies from 285.2 K (Surface) to 315.2 K (Bulk). We clarified that the shorter and stronger bonds between under-coordinated atoms cause local densification and quantum entrapment of electron binding energy, which perturbs the Hamiltonian and the core shifts in the skin region.

  1. Role of Al coordination in barium phosphate glasses on the emission features of Ho{sup 3+} ion in the visible and IR spectral ranges

    Energy Technology Data Exchange (ETDEWEB)

    Satyanarayana, T.; Kalpana, T.; Ravi Kumar, V. [Department of Physics, Acharya Nagarjuna University-Nuzvid Campus, Nuzvid-521 201, A.P. (India); Veeraiah, N., E-mail: nvr8@rediffmail.co [Department of Physics, Acharya Nagarjuna University-Nuzvid Campus, Nuzvid-521 201, A.P. (India)

    2010-03-15

    The glasses of the composition (39-x)BaO-xAl{sub 2}O{sub 3}-60P{sub 2}O{sub 5}:1.0Ho{sub 2}O{sub 3} (in mol%) with x value ranging from 1.0 to 4.0 have been synthesized. The IR spectral studies of these glasses have indicated that there is a gradual transformation of Al{sup 3+} ions from tetrahedral to octahedral with increase in the concentration of Al{sub 2}O{sub 3} up to 3.0 mol%. Optical absorption and fluorescence spectra (in the visible and NIR regions) of these glasses have been recorded at room temperature. The Judd-Ofelt theory could successfully be applied to characterize the absorption and luminescence spectra of Ho{sup 3+} ions in these glasses. From the luminescence spectra, various radiative properties like transition probability A, branching ratio beta{sub r}, the radiative lifetime tau{sub r} and emission cross-section sigma{sup E} for various emission levels of these glasses have been evaluated. The radiative lifetime of the {sup 5}S{sub 2}->{sup 5}I{sub 8} (green emission) transition has also been measured. The variations observed in these parameters have been discussed in the light of varying co-ordinations (tetrahedral and octahedral positions) of Al{sup 3+} ions in the glass network. The influence of hydroxyl groups on the luminescence efficiency of the transition {sup 5}S{sub 2}->{sup 5}I{sub 8} has also been discussed. Finally the optimum concentration of Al{sub 2}O{sub 3} for getting maximum luminescence output has also been identified and reported.

  2. Spectral and energy efficiency analysis of uplink heterogeneous networks with small-cells on edge

    KAUST Repository

    Shakir, Muhammad Zeeshan

    2014-12-01

    This paper presents a tractable mathematical framework to analyze the spectral and energy efficiency of an operator initiated deployment of the small-cells (e.g., femtocells) where the small-cell base stations are deliberately positioned around the edge of the macrocell. The considered deployment facilitates the cell-edge mobile users in terms of their coverage, spectral, and energy efficiency and is referred to as cell-on-edge (COE) configuration. The reduction in energy consumption is achieved by considering fast power control where the mobile users transmit with adaptive power to compensate the path loss, shadowing and fading. In particular, we develop a moment generating function (MGF) based approach to derive analytical bounds on the area spectral efficiency and exact expressions for the energy efficiency of the mobile users in the considered COE configuration over generalized-K fading channels. Besides the COE configuration, the derived bounds are also shown to be useful in evaluating the performance of random small-cell deployments, e.g., uniformly distributed small-cells. Simulation results are presented to demonstrate the improvements in spectral and energy efficiency of the COE configuration with respect to macro-only networks and other unplanned deployment strategies. © 2014 Elsevier B.V. All rights reserved.

  3. High-Energy, Multi-Octave-Spanning Mid-IR Sources via Adiabatic Difference Frequency Generation

    Science.gov (United States)

    2016-10-17

    MASSACHUSETTS AVE CAMBRIDGE , MA 02139-4301 US 8. PERFORMING ORGANIZATION REPORT NUMBER 9. SPONSORING/MONITORING AGENCY NAME(S) AND ADDRESS(ES) AF Office...ADFG) stage, illustrated in Fig. 2. This system represents a very simple extension of a near-IR OPCPA system to octave-spanning mid-IR, requiring...retrieved, as shown in Fig. 10. For illustration , 3 pulse shapes were selected. First, a simple linear chirp was applied to show that the pulse can be

  4. Energy-beam processing studies on Ta/U and Ir/Ta systems

    International Nuclear Information System (INIS)

    Kaufmann, E.N.; Peercy, P.S.; Jacobson, D.C.; Draper, C.W.; Huegel, F.J.; Echer, C.J.; Makowiecki, D.M.; Balser, J.D.

    1983-01-01

    Films of Ta metal on uranium and of Ir metal on tantalum have been irradiated and melted by pulses from Q-switched Ruby and frequency-doubled Nd:YAG lasers to investigate the nature of the resulting mixtures in light of the very different binary-phase diagrams of the two systems. In addition, a two-phase Ir-Ta alloy has been surface-processed with CW CO 2 -laser radiation and with an electron beam in order to study microstructure refinement and test the advantage of using alloys as opposed to film-on-substrate combinations for the development of claddings

  5. Maximizing the spectral and energy efficiency of ARQ with a fixed outage probability

    KAUST Repository

    Hadjtaieb, Amir; Chelli, Ali; Alouini, Mohamed-Slim

    2015-01-01

    This paper studies the spectral and energy efficiency of automatic repeat request (ARQ) in Nakagami-m block-fading channels. The source encodes each packet into L similar sequences and transmits them to the destination in the L subsequent time slots

  6. Localness of energy cascade in hydrodynamic turbulence, II. Sharp spectral filter

    Energy Technology Data Exchange (ETDEWEB)

    Aluie, Hussein [Los Alamos National Laboratory; Eyink, Gregory L [JOHNS HOPKINS UNIV.

    2009-01-01

    We investigate the scale-locality of subgrid-scale (SGS) energy flux and interband energy transfers defined by the sharp spectral filter. We show by rigorous bounds, physical arguments, and numerical simulations that the spectral SGS flux is dominated by local triadic interactions in an extended turbulent inertial range. Interband energy transfers are also shown to be dominated by local triads if the spectral bands have constant width on a logarithmic scale. We disprove in particular an alternative picture of 'local transfer by nonlocal triads,' with the advecting wavenumber mode at the energy peak. Although such triads have the largest transfer rates of all individual wavenumber triads, we show rigorously that, due to their restricted number, they make an asymptotically negligible contribution to energy flux and log-banded energy transfers at high wavenumbers in the inertial range. We show that it is only the aggregate effect of a geometrically increasing number of local wavenumber triads which can sustain an energy cascade to small scales. Furthermore, nonlocal triads are argued to contribute even less to the space-average energy flux than is implied by our rigorous bounds, because of additional cancellations from scale-decorrelation effects. We can thus recover the -4/3 scaling of nonlocal contributions to spectral energy flux predicted by Kraichnan's abridged Lagrangian-history direct-interaction approximation and test-field model closures. We support our results with numerical data from a 512{sup 3} pseudospectral simulation of isotropic turbulence with phase-shift dealiasing. We also discuss a rigorous counterexample of Eyink [Physica D 78, 222 (1994)], which showed that nonlocal wavenumber triads may dominate in the sharp spectral flux (but not in the SGS energy flux for graded filters). We show that this mathematical counter example fails to satisfy reasonable physical requirements for a turbulent velocity field, which are employed in our

  7. Protonation of benzimidazoles and 1,2,3-benzotriazoles Solid-state linear dichroic infrared (IR-LD) spectral analysis and ab initio calculations

    Science.gov (United States)

    Ivanova, Bojidarka B.; Pindeva, Liliya I.

    2006-09-01

    IR-LD spectroscopic data obtained by the orientated solid samples as a suspension in a nematic liquid crystal of 1-hydroxy-1,2,3-benzotriazole, 2-methyl-, 2-acetonitrilebenzimidazoles and their protonated salts have been presented. The stereo-structures have been predicted and compared with theoretical ones. The IR-characteristic bands assignments of all molecule systems have been achieved.

  8. FT-Raman, FT-IR and UV-visible spectral investigations and ab initio computations of anti-epileptic drug: Vigabatrin

    Science.gov (United States)

    Edwin, Bismi; Joe, I. Hubert

    2013-10-01

    Vibrational analysis of anti-epileptic drug vigabatrin, a structural GABA analog was carried out using NIR FT-Raman and FTIR spectroscopic techniques. The equilibrium geometry, various bonding features and harmonic vibrational wavenumbers were studied using density functional theory method. The detailed interpretation of the vibrational spectra has been carried out with the aid of VEDA.4 program. Vibrational spectra, natural bond orbital analysis and optimized molecular structure show clear evidence for the effect of electron charge transfer on the activity of the molecule. Predicted electronic absorption spectrum from TD-DFT calculation has been compared with the UV-vis spectrum. The Mulliken population analysis on atomic charges and the HOMO-LUMO energy were also calculated. Good consistency is found between the calculated results and experimental data for the electronic absorption as well as IR and Raman spectra. The blue-shifting of the Csbnd C stretching wavenumber reveals that the vinyl group is actively involved in the conjugation path. The NBO analysis confirms the occurrence of intramolecular hyperconjugative interactions resulting in ICT causing stabilization of the system.

  9. FT-Raman, FT-IR and UV-visible spectral investigations and ab initio computations of anti-epileptic drug: vigabatrin.

    Science.gov (United States)

    Edwin, Bismi; Joe, I Hubert

    2013-10-01

    Vibrational analysis of anti-epileptic drug vigabatrin, a structural GABA analog was carried out using NIR FT-Raman and FTIR spectroscopic techniques. The equilibrium geometry, various bonding features and harmonic vibrational wavenumbers were studied using density functional theory method. The detailed interpretation of the vibrational spectra has been carried out with the aid of VEDA.4 program. Vibrational spectra, natural bond orbital analysis and optimized molecular structure show clear evidence for the effect of electron charge transfer on the activity of the molecule. Predicted electronic absorption spectrum from TD-DFT calculation has been compared with the UV-vis spectrum. The Mulliken population analysis on atomic charges and the HOMO-LUMO energy were also calculated. Good consistency is found between the calculated results and experimental data for the electronic absorption as well as IR and Raman spectra. The blue-shifting of the C-C stretching wavenumber reveals that the vinyl group is actively involved in the conjugation path. The NBO analysis confirms the occurrence of intramolecular hyperconjugative interactions resulting in ICT causing stabilization of the system. Copyright © 2013 Elsevier B.V. All rights reserved.

  10. Investigation of JI and DI CMOS FXR response at different spectral energies

    International Nuclear Information System (INIS)

    Honnold, V.R.; Goldberg, M.; Schreiner, W.A.; Witteles, A.A.

    1975-01-01

    The transient response of both junction isolated (JI) and dielectrically isolated (DI) CMOS circuits has been investigated in three FXR environments of differing energy spectrums. The offset recovery times have been measured and analyzed for both structures. It is shown that while the DI circuit (HD4007) did not exhibit a four layer type latchup action, its transient response persisted for a time longer than is expected for this type of device. A possible mechanism for this observed response is developed and discussed. JI circuits (CD4007) exposed under the same conditions exhibited four layer device action and one sample at low spectral energies latched-up. The conditions for the latchup to occur including the four layer device paths are discussed. Finally, the dependence of the x-ray transient response on the spectral energy is considered. For the lower energy FXR source, latchup was observed in a CD4007 sample. This latchup was not observed at more than double the dose rate when a high energy FXR was used. This result is attributed to dose enhancement, and a device enhancement factor may also be involved. The dose enhancement factor is estimated from the work of Long, and points up the importance of accounting for the spectral energy content in simulating a given nuclear threat spectrum

  11. A bulk micromachined lead zinconate titanate cantilever energy harvester with inter-digital IrO(x) electrodes.

    Science.gov (United States)

    Park, Jongcheol; Park, Jae Yeong

    2013-10-01

    A piezoelectric vibration energy harvester with inter-digital IrO(x) electrode was developed by using silicon bulk micromachining technology. Most PZT cantilever based energy harvesters have utilized platinum electrode material. However, the PZT fatigue characteristics and adhesion/delamination problems caused by the platinum electrode might be serious problem in reliability of energy harvester. To address these problems, the iridium oxide was newly applied. The proposed energy harvester was comprised of bulk micromachined silicon cantilever with 800 x 1000 x 20 microm3, which having a silicon supporting membrane, sol-gel-spin coated Pb(Zr52, Ti48)O3 thin film, and sputtered inter-digitally shaped IrO(x) electrodes, and silicon inertial mass with 1000 x 1000 x 500 microm3 to adjust its resonant frequency. The fabricated energy harvester generated 1 microW of electrical power to 470 komega of load resistance and 1.4 V(peak-to-peak) from a vibration of 0.4 g at 1.475 kHz. The corresponding power density was 6.25 mW x cm(-3) x g(-2). As expected, its electrical failure was significantly improved.

  12. Exchange bias energy in Co/Pt/IrMn multilayers with perpendicular and in-plane anisotropy

    Energy Technology Data Exchange (ETDEWEB)

    Czapkiewicz, M. [Department of Electronics, AGH University of Science and Technology, 30-059 Cracow (Poland)]. E-mail: czapkiew@agh.edu.pl; Stobiecki, T. [Department of Electronics, AGH University of Science and Technology, 30-059 Cracow (Poland); Rak, R. [Department of Electronics, AGH University of Science and Technology, 30-059 Cracow (Poland); Zoladz, M. [Department of Electronics, AGH University of Science and Technology, 30-059 Cracow (Poland); Dijken, S. van [CRANN and School of Physics, Trinity College, Dublin 2 (Ireland)

    2007-09-15

    The magnetization reversal process in perpendicularly biased [Pt/Co]{sub 3}/d{sub Pt} Pt/IrMn and in-plane biased Co/d{sub Pt} Pt/IrMn multilayers with 0nm=energy is larger for the in-plane biased films than for the perpendicularly biased multilayers.

  13. Quantitative analysis of the dual-energy CT virtual spectral curve for focal liver lesions characterization

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Qi, E-mail: wq20@hotmail.com; Shi, Gaofeng, E-mail: gaofengs62@sina.com; Qi, Xiaohui, E-mail: qixiaohui1984@163.com; Fan, Xueli, E-mail: 407849960@qq.com; Wang, Lijia, E-mail: 893197597@qq.com

    2014-10-15

    Highlights: • We establish a feasible method using the virtual spectral curves (VSC) to differentiate focal liver lesions using DECT. • Our study shows the slope of the VSC can be used to differentiate between hemangioma, HCC, metastasis and cyst. • Importantly, the diagnostic specificities associated with using the slope to diagnose both hemangioma and cysts were 100%. - Abstract: Objective: To assess the usefulness of the spectral curve slope of dual-energy CT (DECT) for differentiating between hepatocellular carcinoma (HCC), hepatic metastasis, hemangioma (HH) and cysts. Methods: In total, 121 patients were imaged in the portal venous phase using dual-energy mode. Of these patients, 23 patients had HH, 28 patients had HCC, 40 patients had metastases and 30 patients had simple cysts. The spectral curves of the hepatic lesions were derived from the 40–190 keV levels of virtual monochromatic spectral imaging. The spectral curve slopes were calculated from 40 to 110 keV. The slopes were compared using the Kruskal–Wallis test. Receiver operating characteristic curves (ROC) were used to determine the optimal cut-off value of the slope of the spectral curve to differentiate between the lesions. Results: The spectral curves of the four lesion types had different baseline levels. The HH baseline level was the highest followed by HCC, metastases and cysts. The slopes of the spectral curves of HH, HCC, metastases and cysts were 3.81 ± 1.19, 1.49 ± 0.57, 1.06 ± 0.76 and 0.13 ± 0.17, respectively. These values were significantly different (P < 0.008). Based on ROC analysis, the respective diagnostic sensitivity and specificity were 87% and 100% for hemangioma (cut-off value ≥ 2.988), 82.1% and 65.9% for HCC (cut-off value 1.167–2.998), 65.9% and 59% for metastasis (cut-off value 0.133–1.167) and 44.4% and 100% for cysts (cut-off value ≤ 0.133). Conclusion: Quantitative analysis of the DECT spectral curve in the portal venous phase can be used to

  14. Coherent Structures and Spectral Energy Transfer in Turbulent Plasma: A Space-Filter Approach

    Science.gov (United States)

    Camporeale, E.; Sorriso-Valvo, L.; Califano, F.; Retinò, A.

    2018-03-01

    Plasma turbulence at scales of the order of the ion inertial length is mediated by several mechanisms, including linear wave damping, magnetic reconnection, the formation and dissipation of thin current sheets, and stochastic heating. It is now understood that the presence of localized coherent structures enhances the dissipation channels and the kinetic features of the plasma. However, no formal way of quantifying the relationship between scale-to-scale energy transfer and the presence of spatial structures has been presented so far. In the Letter we quantify such a relationship analyzing the results of a two-dimensional high-resolution Hall magnetohydrodynamic simulation. In particular, we employ the technique of space filtering to derive a spectral energy flux term which defines, in any point of the computational domain, the signed flux of spectral energy across a given wave number. The characterization of coherent structures is performed by means of a traditional two-dimensional wavelet transformation. By studying the correlation between the spectral energy flux and the wavelet amplitude, we demonstrate the strong relationship between scale-to-scale transfer and coherent structures. Furthermore, by conditioning one quantity with respect to the other, we are able for the first time to quantify the inhomogeneity of the turbulence cascade induced by topological structures in the magnetic field. Taking into account the low space-filling factor of coherent structures (i.e., they cover a small portion of space), it emerges that 80% of the spectral energy transfer (both in the direct and inverse cascade directions) is localized in about 50% of space, and 50% of the energy transfer is localized in only 25% of space.

  15. The effect of host star spectral energy distribution and ice-albedo feedback on the climate of extrasolar planets.

    Science.gov (United States)

    Shields, Aomawa L; Meadows, Victoria S; Bitz, Cecilia M; Pierrehumbert, Raymond T; Joshi, Manoj M; Robinson, Tyler D

    2013-08-01

    Planetary climate can be affected by the interaction of the host star spectral energy distribution with the wavelength-dependent reflectivity of ice and snow. In this study, we explored this effect with a one-dimensional (1-D), line-by-line, radiative transfer model to calculate broadband planetary albedos as input to a seasonally varying, 1-D energy balance climate model. A three-dimensional (3-D) general circulation model was also used to explore the atmosphere's response to changes in incoming stellar radiation, or instellation, and surface albedo. Using this hierarchy of models, we simulated planets covered by ocean, land, and water-ice of varying grain size, with incident radiation from stars of different spectral types. Terrestrial planets orbiting stars with higher near-UV radiation exhibited a stronger ice-albedo feedback. We found that ice extent was much greater on a planet orbiting an F-dwarf star than on a planet orbiting a G-dwarf star at an equivalent flux distance, and that ice-covered conditions occurred on an F-dwarf planet with only a 2% reduction in instellation relative to the present instellation on Earth, assuming fixed CO(2) (present atmospheric level on Earth). A similar planet orbiting the Sun at an equivalent flux distance required an 8% reduction in instellation, while a planet orbiting an M-dwarf star required an additional 19% reduction in instellation to become ice-covered, equivalent to 73% of the modern solar constant. The reduction in instellation must be larger for planets orbiting cooler stars due in large part to the stronger absorption of longer-wavelength radiation by icy surfaces on these planets in addition to stronger absorption by water vapor and CO(2) in their atmospheres, which provides increased downwelling longwave radiation. Lowering the IR and visible-band surface ice and snow albedos for an M-dwarf planet increased the planet's climate stability against changes in instellation and slowed the descent into global ice

  16. Critically Evaluated Energy Levels, Spectral Lines, Transition Probabilities, and Intensities of Neutral Vanadium (V i)

    Energy Technology Data Exchange (ETDEWEB)

    Saloman, Edward B. [Dakota Consulting, Inc., 1110 Bonifant Street, Suite 310, Silver Spring, MD 20910 (United States); Kramida, Alexander [National Institute of Standards and Technology, Gaithersburg, MD 20899 (United States)

    2017-08-01

    The energy levels, observed spectral lines, and transition probabilities of the neutral vanadium atom, V i, have been compiled. Also included are values for some forbidden lines that may be of interest to the astrophysical community. Experimental Landé g -factors and leading percentage compositions for the levels are included where available, as well as wavelengths calculated from the energy levels (Ritz wavelengths). Wavelengths are reported for 3985 transitions, and 549 energy levels are determined. The observed relative intensities normalized to a common scale are provided.

  17. Simultaneous spectral and temporal analyses of kinetic energies in nonequilibrium systems: theory and application to vibrational relaxation of O-D stretch mode of HOD in water.

    Science.gov (United States)

    Jeon, Jonggu; Lim, Joon Hyung; Kim, Seongheun; Kim, Heejae; Cho, Minhaeng

    2015-05-28

    A time series of kinetic energies (KE) from classical molecular dynamics (MD) simulation contains fundamental information on system dynamics. It can also be analyzed in the frequency domain through Fourier transformation (FT) of velocity correlation functions, providing energy content of different spectral regions. By limiting the FT time span, we have previously shown that spectral resolution of KE evolution is possible in the nonequilibrium situations [Jeon and Cho, J. Chem. Phys. 2011, 135, 214504]. In this paper, we refine the method by employing the concept of instantaneous power spectra, extending it to reflect an instantaneous time-correlation of velocities with those in the future as well as with those in the past, and present a new method to obtain the instantaneous spectral density of KE (iKESD). This approach enables the simultaneous spectral and temporal resolution of KE with unlimited time precision. We discuss the formal and novel properties of the new iKESD approaches and how to optimize computational methods and determine parameters for practical applications. The method is specifically applied to the nonequilibrium MD simulation of vibrational relaxation of the OD stretch mode in a hydrated HOD molecule by employing a hybrid quantum mechanical/molecular mechanical (QM/MM) potential. We directly compare the computational results with the OD band population relaxation time profiles extracted from the IR pump-probe measurements for 5% HOD in water. The calculated iKESD yields the OD bond relaxation time scale ∼30% larger than the experimental value, and this decay is largely frequency-independent if the classical anharmonicity is accounted for. From the integrated iKESD over intra- and intermolecular bands, the major energy transfer pathways were found to involve the HOD bending mode in the subps range, then the internal modes of the solvent until 5 ps after excitation, and eventually the solvent intermolecular modes. Also, strong hydrogen

  18. Effect of structural modulation and thickness of a graphene overlayer on the binding energy of the Rashba-type surface state of Ir(111)

    International Nuclear Information System (INIS)

    Sánchez-Barriga, J; Marchenko, D; Rader, O; Varykhalov, A; Bihlmayer, G; Wortmann, D

    2013-01-01

    The Ir(111) surface is known to host a surface state with a giant spin–orbit splitting due to the Rashba effect. This surface state is stable even in air when Ir is protected with an epitaxial graphene overlayer. In the present paper, we reveal an effect allowing one to tune the binding energy of this spin-split surface state up and down and demonstrate the practical application of this effect by two different approaches. The first approach is related to a decoration of the moiré pattern of single-layer graphene on Ir(111) by self-assembled nanoclusters of different compositions. The clusters locally pin graphene to the Ir substrate and enhance the amplitude of its structural corrugation, which, in turn, leads to an increase in the surface state binding energy. The second approach is related to the synthesis of few-layer graphene on Ir(111) by segregation of carbon. Additional graphene layers induce a shift of the Ir surface state towards lower binding energies and bring it almost to the Fermi level. Based on density functional calculations performed for the graphene/Ir(111) system, we show that in both cases the effect causing the binding energy shifts is intimately related to the distance between graphene and the Ir surface, which is subject to change due to deposition of clusters or by increasing the amount of graphene overlayers. In contrast, the observed spin–orbit splitting of the Ir(111) surface state remains remarkably robust and constant in all cases. Our theoretical analysis reveals that such stability can be explained by the localization properties of the Ir surface state that is a deep surface resonance. (paper)

  19. Energy Calibration of the Pixels of Spectral X-ray Detectors

    CERN Document Server

    Panta, Raj Kumar; Bell, Stephen T; Anderson, Nigel G; Butler, Anthony P; Butler, Philip H

    2015-01-01

    The energy information acquired using spectral X-ray detectors allows noninvasive identification and characterization of chemical components of a material. To achieve this, it is important that the energy response of the detector is calibrated. The established techniques for energy calibration are not practical for routine use in pre-clinical or clinical research environment. This is due to the requirements of using monochromatic radiation sources such as synchrotron, radio-isotopes, and prohibitively long time needed to set up the equipment and make measurements. To address these limitations, we have developed an automated technique for calibrating the energy response of the pixels in a spectral X-ray detector that runs with minimal user intervention. This technique uses the X-ray tube voltage (kVp) as a reference energy, which is stepped through an energy range of interest. This technique locates the energy threshold where a pixel transitions from not-counting (off) to counting (on). Similarly, we have deve...

  20. Quantitative material decomposition using spectral computed tomography with an energy-resolved photon-counting detector

    International Nuclear Information System (INIS)

    Lee, Seungwan; Choi, Yu-Na; Kim, Hee-Joung

    2014-01-01

    Dual-energy computed tomography (CT) techniques have been used to decompose materials and characterize tissues according to their physical and chemical compositions. However, these techniques are hampered by the limitations of conventional x-ray detectors operated in charge integrating mode. Energy-resolved photon-counting detectors provide spectral information from polychromatic x-rays using multiple energy thresholds. These detectors allow simultaneous acquisition of data in different energy ranges without spectral overlap, resulting in more efficient material decomposition and quantification for dual-energy CT. In this study, a pre-reconstruction dual-energy CT technique based on volume conservation was proposed for three-material decomposition. The technique was combined with iterative reconstruction algorithms by using a ray-driven projector in order to improve the quality of decomposition images and reduce radiation dose. A spectral CT system equipped with a CZT-based photon-counting detector was used to implement the proposed dual-energy CT technique. We obtained dual-energy images of calibration and three-material phantoms consisting of low atomic number materials from the optimal energy bins determined by Monte Carlo simulations. The material decomposition process was accomplished by both the proposed and post-reconstruction dual-energy CT techniques. Linear regression and normalized root-mean-square error (NRMSE) analyses were performed to evaluate the quantitative accuracy of decomposition images. The calibration accuracy of the proposed dual-energy CT technique was higher than that of the post-reconstruction dual-energy CT technique, with fitted slopes of 0.97–1.01 and NRMSEs of 0.20–4.50% for all basis materials. In the three-material phantom study, the proposed dual-energy CT technique decreased the NRMSEs of measured volume fractions by factors of 0.17–0.28 compared to the post-reconstruction dual-energy CT technique. It was concluded that the

  1. Maximizing the spectral and energy efficiency of ARQ with a fixed outage probability

    KAUST Repository

    Hadjtaieb, Amir

    2015-10-05

    This paper studies the spectral and energy efficiency of automatic repeat request (ARQ) in Nakagami-m block-fading channels. The source encodes each packet into L similar sequences and transmits them to the destination in the L subsequent time slots. The destination combines the L sequences using maximal ratio combining and tries to decode the information. In case of decoding failure, the destination feeds back a negative acknowledgment and then the source sends the same L sequences to the destination. This process continues until successful decoding occurs at the destination with no limit on the number of retransmissions. We consider two optimization problems. In the first problem, we maximize the spectral efficiency of the system with respect to the rate for a fixed power. In the second problem, we maximize the energy efficiency with respect to the transmitted power for a fixed rate. © 2015 IEEE.

  2. A rediscussion of the atmospheric extinction and the absolute spectral-energy distribution of Vega

    International Nuclear Information System (INIS)

    Hayes, D.S.; Latham, D.W.

    1975-01-01

    For both the Lick and the Palomar calibrations of the spectral-energy distribution of Vega, the atmospheric extinction was treated incorrectly. We present a model for extinction in the Earth's atmosphere and use this model to calculate corrections to the Lick and Palomar calibrations. We also describe a method that can be used to fabricate mean extinction coefficients for any mountain observatory. We combine selected portions of the corrected Lick and corrected Palomar calibrations with the new Mount Hopkins calibration to generate an absolute spectral-energy distibution of Vega over the wavelength range 3300--10,800 A. Until better measurements become available, we recommend the use of this calibration for all practical applications

  3. Algorithms for spectral calibration of energy-resolving small-pixel detectors

    International Nuclear Information System (INIS)

    Scuffham, J; Veale, M C; Wilson, M D; Seller, P

    2013-01-01

    Small pixel Cd(Zn)Te detectors often suffer from inter-pixel variations in gain, resulting in shifts in the individual energy spectra. These gain variations are mainly caused by inclusions and defects within the crystal structure, which affect the charge transport within the material causing a decrease in the signal pulse height. In imaging applications, spectra are commonly integrated over a particular peak of interest. This means that the individual pixels must be accurately calibrated to ensure that the same portion of the spectrum is integrated in every pixel. The development of large-area detectors with fine pixel pitch necessitates automated algorithms for this spectral calibration, due to the very large number of pixels. Algorithms for automatic spectral calibration require accurate determination of characteristic x-ray or photopeak positions on a pixelwise basis. In this study, we compare two peak searching spectral calibration algorithms for a small-pixel CdTe detector in gamma spectroscopic imaging. The first algorithm uses rigid search ranges to identify peaks in each pixel spectrum, based on the average peak positions across all pixels. The second algorithm scales the search ranges on the basis of the position of the highest-energy peak relative to the average across all pixels. In test spectra acquired with Tc-99m, we found that the rigid search algorithm failed to correctly identify the target calibraton peaks in up to 4% of pixels. In contrast, the scaled search algorithm failed in only 0.16% of pixels. Failures in the scaled search algorithm were attributed to the presence of noise events above the main photopeak, and possible non-linearities in the spectral response in a small number of pixels. We conclude that a peak searching algorithm based on scaling known peak spacings is simple to implement and performs well for the spectral calibration of pixellated radiation detectors

  4. Optimal Monochromatic Energy Levels in Spectral CT Pulmonary Angiography for the Evaluation of Pulmonary Embolism

    Science.gov (United States)

    Wu, Huawei; Zhang, Qing; Hua, Jia; Hua, Xiaolan; Xu, Jianrong

    2013-01-01

    Background The aim of this study was to determine the optimal monochromatic spectral CT pulmonary angiography (sCTPA) levels to obtain the highest image quality and diagnostic confidence for pulmonary embolism detection. Methods The Institutional Review Board of the Shanghai Jiao Tong University School of Medicine approved this study, and written informed consent was obtained from all participating patients. Seventy-two patients with pulmonary embolism were scanned with spectral CT mode in the arterial phase. One hundred and one sets of virtual monochromatic spectral (VMS) images were generated ranging from 40 keV to 140 keV. Image noise, clot diameter and clot to artery contrast-to-noise ratio (CNR) from seven sets of VMS images at selected monochromatic levels in sCTPA were measured and compared. Subjective image quality and diagnostic confidence for these images were also assessed and compared. Data were analyzed by paired t test and Wilcoxon rank sum test. Results The lowest noise and the highest image quality score for the VMS images were obtained at 65 keV. The VMS images at 65 keV also had the second highest CNR value behind that of 50 keV VMS images. There was no difference in the mean noise and CNR between the 65 keV and 70 keV VMS images. The apparent clot diameter correlated with the keV levels. Conclusions The optimal energy level for detecting pulmonary embolism using dual-energy spectral CT pulmonary angiography was 65–70 keV. Virtual monochromatic spectral images at approximately 65–70 keV yielded the lowest image noise, high CNR and highest diagnostic confidence for the detection of pulmonary embolism. PMID:23667583

  5. New IR-UV gas sensor to energy and transport sector

    Energy Technology Data Exchange (ETDEWEB)

    Fateev, A.; Clausen, S.

    2010-12-15

    In situ simultaneous measurements of gas temperature and gas composition are of great interest in combustion research and give useful information about conditions, chemical reactions and gas mixing in many industrial processes. An optically based technique is beneficial because it is non-intrusive, accurate, fast and can be performed in situ for various extremely hard conditions. In humid and hot gas flows UV technique is more sensitive than FTIR one for fast gas concentration measurements of NO and SO{sub 2} and gives a great opportunity for simultaneous measurements of O{sub 2} concentration. Analysis of the fine structure of the UV absorption bands of, for example, NO, SO{sub 2} or O{sub 2} allows also to determine a value of the gas temperature. Absorption cross sections of CO{sub 2}, H{sub 2}O and SO{sub 2} measured using Risoe DTU's hot gas cell facility at elevated temperatures up to 1500 deg. C are reported. Design of a new developed 9-m long water-cooled fiber-optic probe with removable optical head suitable for fast IR/UV local gas absorption/emission measurements is described. The probe performance was successfully tested in several trial measurements on full scale multi-fuel fired boiler. A concept of fast time/spectralresolved measurements has been used in measurements on a large ship engine based on IR and UV broad band spectroscopy. (Author)

  6. Use of thulium-sensitized rare earth-doped low phonon energy crystalline hosts for IR sources.

    Science.gov (United States)

    Ganem, Joseph; Bowman, Steven R

    2013-11-01

    Crystalline hosts with low phonon energies enable novel energy transfer processes when doped with rare earth ions. Two applications of energy transfer for rare earth ions in thulium-sensitized low phonon energy crystals that result in infrared luminescence are discussed. One application is an endothermic, phonon-assisted cross-relaxation process in thulium-doped yttrium chloride that converts lattice phonons to infrared emission, which raises the possibility of a fundamentally new method for achieving solid-state optical cooling. The other application is an optically pumped mid-IR phosphor using thulium-praseodymium-doped potassium lead chloride that converts 805-nm diode light to broadband emission from 4,000 to 5,500 nm. These two applications in chloride crystals are discussed in terms of critical radii calculated from Forster-Dexter energy transfer theory. It is found that the critical radii for electric dipole-dipole interactions in low phonon energy chloride crystals are comparable to those in conventional oxide and fluoride crystals. It is the reduction in multi-phonon relaxation rates in chloride crystals that enable these additional energy transfer processes and infrared luminescence.

  7. Results of the studies on energy deposition in IR6 superconducting magnets from continuous beam loss on the TCDQ system

    CERN Document Server

    Bracco, C; Presland, A; Redaelli, S; Sarchiapone, L; Weiler, T

    2007-01-01

    A single sided mobile graphite diluter block TCDQ, in combination with a two-sided secondary collimator TCS and an iron shield TCDQM, will be installed in front of the superconducting quadrupole Q4 magnets in IR6, in order to protect it and other downstream LHC machine elements from destruction in the event of a beam dump that is not synchronised with the abort gap. The TCDQ will be positioned close to the beam, and will intercept the particles from the secondary halo during low beam lifetime. Previous studies (1-4) have shown that the energy deposited in the Q4 magnet coils can be close to or above the quench limit. In this note the results of the latest FLUKA energy deposition simulations for Beam 2 are described, including an upgrade possibility for the TCDQ system with an additional shielding device. The results are discussed in the context of the expected performance levels for the different phases of LHC operation.

  8. Deuterium depleted water effect on seawater spectral energy and marine phytoplankton

    International Nuclear Information System (INIS)

    Mirza, Maria; Zaharia, Mihaela; Cristescu, T.M.; Titescu, Gh.

    2002-01-01

    Solar radiation is the primary source of new energy in most aquatic ecosystems and it is the sun variability in amount and spectral distribution that drives many of the changes in material flux on different time and space scales. The dependency of ecosystem dynamics on sunlight is largely attributable to the simple fact that plants require solar radiation to carry out photosynthesis. The resulting primary production (the rate of the plant growth and reproduction) is an index of aquatic processes, including food web dynamics and biogeochemical cycling of compounds that affect everything from aquatic chemistry to regional and global weather patterns. Light dependent processes in plants (photo-synthesis, photoinhibition, phototaxis and photoprotection) and in aquatic environment, animal vision and microbial mediation of the photo-dissociation of chemical have evolved over millennia and most of them are regulated or at least influenced by the spectral composition of the light field The paper deals with the investigation of relations between water spectral energy modified by deuterium depleted water (DDW) and the microphyte alga Tetraselmis suecica or the total marine micro-phytoplankton growth. (authors)

  9. Dual energy spectral CT imaging for the evaluation of small hepatocellular carcinoma microvascular invasion.

    Science.gov (United States)

    Yang, Chuang-Bo; Zhang, Shuang; Jia, Yong-Jun; Yu, Yong; Duan, Hai-Feng; Zhang, Xi-Rong; Ma, Guang-Ming; Ren, Chenglong; Yu, Nan

    2017-10-01

    To study the clinical value of dual-energy spectral CT in the quantitative assessment of microvascular invasion of small hepatocellular carcinoma. This study was approved by our ethics committee. 50 patients with small hepatocellular carcinoma who underwent contrast enhanced spectral CT in arterial phase (AP) and portal venous phase (VP) were enrolled. Tumour CT value and iodine concentration (IC) were measured from spectral CT images. The slope of spectral curve, normalized iodine concentration (NIC, to abdominal aorta) and ratio of IC difference between AP and VP (RIC AP-VP : [RIC AP-VP =(IC AP -IC VP )/IC AP ]) were calculated. Tumours were identified as either with or without microvascular invasion based on pathological results. Measurements were statistically compared using independent samples t test. The receiver operating characteristic (ROC) analysis was used to evaluate the diagnostic performance of tumours microvascular invasion assessment. The 70keV images were used to simulate the results of conventional CT scans for comparison. 56 small hepatocellular carcinomas were detected with 37 lesions (Group A) with microvascular invasion and 19 (Group B) without. There were significant differences in IC, NIC and slope in AP and RIC AP-VP between Group A (2.48±0.70mg/ml, 0.23±0.05, 3.39±1.01 and 0.28±0.16) and Group B (1.65±0.47mg/ml, 0.15±0.05, 2.22±0.64 and 0.03±0.24) (all phepatocellular carcinoma with and without microvascular invasion. Quantitative iodine concentration measurement in spectral CT may be used to provide a new method to improve the evaluation for small hepatocellular carcinoma microvascular invasion. Copyright © 2017 Elsevier B.V. All rights reserved.

  10. Toward Improved Modeling of Spectral Solar Irradiance for Solar Energy Applications: Preprint

    Energy Technology Data Exchange (ETDEWEB)

    Xie, Yu [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Sengupta, Manajit [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

    2017-10-19

    This study introduces the National Renewable Energy Laboratory's (NREL's) recent efforts to extend the capability of the Fast All-sky Radiation Model for Solar applications (FARMS) by computing spectral solar irradiances over both horizontal and inclined surfaces. A new model is developed by computing the optical thickness of the atmosphere using a spectral irradiance model for clear-sky conditions, SMARTS2. A comprehensive lookup table (LUT) of cloud bidirectional transmittance distribution functions (BTDFs) is precomputed for 2002 wavelength bands using an atmospheric radiative transfer model, libRadtran. The solar radiation transmitted through the atmosphere is given by considering all possible paths of photon transmission and the relevent scattering and absorption attenuation. Our results indicate that this new model has an accuracy that is similar to that of state-of-the-art radiative transfer models, but it is significantly more efficient.

  11. Planck early results. XV. Spectral energy distributions and radio continuum spectra of northern extragalactic radio sources

    DEFF Research Database (Denmark)

    Aatrokoski, J.; Lähteenmäki, A.; Lavonen, N.

    2011-01-01

    Spectral energy distributions (SEDs) and radio continuum spectra are presented for a northern sample of 104 extragalactic radio sources, based on the Planck Early Release Compact Source Catalogue (ERCSC) and simultaneous multifrequency data. The nine Planck frequencies, from 30 to 857 GHz......, are complemented by a set of simultaneous observations ranging from radio to gamma-rays. This is the first extensive frequency coverage in the radio and millimetre domains for an essentially complete sample of extragalactic radio sources, and it shows how the individual shocks, each in their own phase...... of development, shape the radio spectra as they move in the relativistic jet. The SEDs presented in this paper were fitted with second and third degree polynomials to estimate the frequencies of the synchrotron and inverse Compton (IC) peaks, and the spectral indices of low and high frequency radio data...

  12. Recent Advances in Cardiac Computed Tomography: Dual Energy, Spectral and Molecular CT Imaging

    Science.gov (United States)

    Danad, Ibrahim; Fayad, Zahi A.; Willemink, Martin J.; Min, James K.

    2015-01-01

    Computed tomography (CT) evolved into a powerful diagnostic tool and it is impossible to imagine current clinical practice without CT imaging. Due to its widespread availability, ease of clinical application, superb sensitivity for detection of CAD, and non-invasive nature, CT has become a valuable tool within the armamentarium of the cardiologist. In the last few years, numerous technological advances in CT have occurred—including dual energy CT (DECT), spectral CT and CT-based molecular imaging. By harnessing the advances in technology, cardiac CT has advanced beyond the mere evaluation of coronary stenosis to an imaging modality tool that permits accurate plaque characterization, assessment of myocardial perfusion and even probing of molecular processes that are involved in coronary atherosclerosis. Novel innovations in CT contrast agents and pre-clinical spectral CT devices have paved the way for CT-based molecular imaging. PMID:26068288

  13. Study of the spectral and energy characteristics of lasing in the green spectral region by lithium fluoride with radiation color centers

    Energy Technology Data Exchange (ETDEWEB)

    Voitovich, A.P.; Kalinov, V.S.; Mikhnov, S.A.; Ovseichuk, S.I.

    1987-06-01

    The spectral and energy characteristics of lasers utilizing lithium fluoride with F2 and F3(+) color centers in transverse and longitudinal pumping schemes are studied. The feasibility of obtaining stable narrow-band radiation in the 510-570 nm range using a selective resonator is demonstrated. Consideration is given to the effect of lithium-fluoride crystal processing by excimer laser radiation at a wavelength of 308 nm on the spectroscopic and lasing characteristics of the F3(+) color center. After this processing, the laser efficiency in the green spectral region increases by more than a factor of two (reaching an efficiency of 14 percent). 7 references.

  14. Anomalous High-Energy Waterfall-Like Electronic Structure in 5 d Transition Metal Oxide Sr2IrO4 with a Strong Spin-Orbit Coupling

    Science.gov (United States)

    Liu, Yan; Yu, Li; Jia, Xiaowen; Zhao, Jianzhou; Weng, Hongming; Peng, Yingying; Chen, Chaoyu; Xie, Zhuojin; Mou, Daixiang; He, Junfeng; Liu, Xu; Feng, Ya; Yi, Hemian; Zhao, Lin; Liu, Guodong; He, Shaolong; Dong, Xiaoli; Zhang, Jun; Xu, Zuyan; Chen, Chuangtian; Cao, Gang; Dai, Xi; Fang, Zhong; Zhou, X. J.

    2015-08-01

    The low energy electronic structure of Sr2IrO4 has been well studied and understood in terms of an effective Jeff = 1/2 Mott insulator model. However, little work has been done in studying its high energy electronic behaviors. Here we report a new observation of the anomalous high energy electronic structure in Sr2IrO4. By taking high-resolution angle-resolved photoemission measurements on Sr2IrO4 over a wide energy range, we have revealed for the first time that the high energy electronic structures show unusual nearly-vertical bands that extend over a large energy range. Such anomalous high energy behaviors resemble the high energy waterfall features observed in the cuprate superconductors. While strong electron correlation plays an important role in producing high energy waterfall features in the cuprate superconductors, the revelation of the high energy anomalies in Sr2IrO4, which exhibits strong spin-orbit coupling and a moderate electron correlation, points to an unknown and novel route in generating exotic electronic excitations.

  15. Anomalous High-Energy Waterfall-Like Electronic Structure in 5 d Transition Metal Oxide Sr2IrO4 with a Strong Spin-Orbit Coupling.

    Science.gov (United States)

    Liu, Yan; Yu, Li; Jia, Xiaowen; Zhao, Jianzhou; Weng, Hongming; Peng, Yingying; Chen, Chaoyu; Xie, Zhuojin; Mou, Daixiang; He, Junfeng; Liu, Xu; Feng, Ya; Yi, Hemian; Zhao, Lin; Liu, Guodong; He, Shaolong; Dong, Xiaoli; Zhang, Jun; Xu, Zuyan; Chen, Chuangtian; Cao, Gang; Dai, Xi; Fang, Zhong; Zhou, X J

    2015-08-12

    The low energy electronic structure of Sr2IrO4 has been well studied and understood in terms of an effective Jeff = 1/2 Mott insulator model. However, little work has been done in studying its high energy electronic behaviors. Here we report a new observation of the anomalous high energy electronic structure in Sr2IrO4. By taking high-resolution angle-resolved photoemission measurements on Sr2IrO4 over a wide energy range, we have revealed for the first time that the high energy electronic structures show unusual nearly-vertical bands that extend over a large energy range. Such anomalous high energy behaviors resemble the high energy waterfall features observed in the cuprate superconductors. While strong electron correlation plays an important role in producing high energy waterfall features in the cuprate superconductors, the revelation of the high energy anomalies in Sr2IrO4, which exhibits strong spin-orbit coupling and a moderate electron correlation, points to an unknown and novel route in generating exotic electronic excitations.

  16. ENERGY-DEPENDENT POWER SPECTRAL STATES AND ORIGIN OF APERIODIC VARIABILITY IN BLACK HOLE BINARIES

    International Nuclear Information System (INIS)

    Yu Wenfei; Zhang Wenda

    2013-01-01

    We found that the black hole candidate MAXI J1659–152 showed distinct power spectra, i.e., power-law noise (PLN) versus band-limited noise (BLN) plus quasi-periodic oscillations (QPOs) below and above about 2 keV, respectively, in observations with Swift and the Rossi X-ray Timing Explorer during the 2010 outburst, indicating a high energy cutoff of the PLN and a low energy cutoff of the BLN and QPOs around 2 keV. The emergence of the PLN and the fading of the BLN and QPOs initially took place below 2 keV when the source entered the hard intermediate state and settled in the soft state three weeks later. The evolution was accompanied by the emergence of the disk spectral component and decreases in the amplitudes of variability in the soft and hard X-ray bands. Our results indicate that the PLN is associated with an optically thick disk in both hard and intermediate states, and the power spectral state is independent of the X-ray energy spectral state in a broadband view. We suggest that in the hard or intermediate state, the BLN and QPOs emerge from the innermost hot flow subjected to Comptonization, while the PLN originates from the optically thick disk farther out. The energy cutoffs of the PLN and the BLN or QPOs then follow the temperature of the seed photons from the inner edge of the optically thick disk, while the high frequency cutoff of the PLN follows the orbital frequency of the inner edge of the optically thick disk as well.

  17. The importance of spectral separation: an assessment of dual-energy spectral separation for quantitative ability and dose efficiency.

    Science.gov (United States)

    Krauss, Bernhard; Grant, Katharine L; Schmidt, Bernhard T; Flohr, Thomas G

    2015-02-01

    One method to acquire dual-energy (DE) computed tomography (CT) data is to perform CT scans at 2 different x-ray tube voltages, typically 80 and 140 kV, either as 2 separate scans, by means of rapid kV switching, or with the use of 2 x-ray sources as in dual-source CT (DSCT) systems. In DSCT, it is possible to improve spectral separation with tin prefiltration (Sn) of the high-kV beam. Recently, x-ray tube voltages beyond the established range of 80 to 140 kV were commercially introduced, which enable additional voltage combinations for DE acquisitions, such as 80/150 Sn or 90/150 Sn kV. Here, we investigate the DE performance of several x-ray tube voltages and prefilter combinations on 2 DSCT scanners and the impact of the spectra on quantitative analysis and dose efficiency. Circular phantoms of different sizes (10-40 cm in diameter) equipped with cylindrical inserts containing water and diluted iodine contrast agent (14.5 mg/cm) were scanned using 2 different DSCT systems (SOMATOM Definition Flash and SOMATOM Force; Siemens AG, Forchheim, Germany). Five x-ray tube voltage combinations (80/140 Sn, 100/140 Sn, 80/150 Sn, 90/150 Sn, and 100/150 Sn kV) were investigated, and the results were compared with the previous standard acquisition technique (80/140 kV). As an example, 80/140 Sn kV means that 1 x-ray tube of the DSCT system was operated at 80 kV, whereas the other was operated at 140 kV with additional tin prefiltration (Sn). Dose values in terms of computed tomography dose index (CTDIvol) were kept constant between the different voltage combinations but adjusted with regard to object size according to automatic exposure control recommendations. Reconstructed images were processed using linear blending of the low- and high-kV CT images to combined images, as well as 3-material decomposition techniques to generate virtual noncontrast (VNC) images and iodine images. Contrast and pixel noise were evaluated, as well as DE ratios, which are defined as the CT value

  18. MULTIMODE quantum calculations of vibrational energies and IR spectrum of the NO⁺(H₂O) cluster using accurate potential energy and dipole moment surfaces.

    Science.gov (United States)

    Homayoon, Zahra

    2014-09-28

    A new, full (nine)-dimensional potential energy surface and dipole moment surface to describe the NO(+)(H2O) cluster is reported. The PES is based on fitting of roughly 32,000 CCSD(T)-F12/aug-cc-pVTZ electronic energies. The surface is a linear least-squares fit using a permutationally invariant basis with Morse-type variables. The PES is used in a Diffusion Monte Carlo study of the zero-point energy and wavefunction of the NO(+)(H2O) and NO(+)(D2O) complexes. Using the calculated ZPE the dissociation energies of the clusters are reported. Vibrational configuration interaction calculations of NO(+)(H2O) and NO(+)(D2O) using the MULTIMODE program are performed. The fundamental, a number of overtone, and combination states of the clusters are reported. The IR spectrum of the NO(+)(H2O) cluster is calculated using 4, 5, 7, and 8 modes VSCF/CI calculations. The anharmonic, coupled vibrational calculations, and IR spectrum show very good agreement with experiment. Mode coupling of the water "antisymmetric" stretching mode with the low-frequency intermolecular modes results in intensity borrowing.

  19. MULTIMODE quantum calculations of vibrational energies and IR spectrum of the NO+(H2O) cluster using accurate potential energy and dipole moment surfaces

    Science.gov (United States)

    Homayoon, Zahra

    2014-09-01

    A new, full (nine)-dimensional potential energy surface and dipole moment surface to describe the NO+(H2O) cluster is reported. The PES is based on fitting of roughly 32 000 CCSD(T)-F12/aug-cc-pVTZ electronic energies. The surface is a linear least-squares fit using a permutationally invariant basis with Morse-type variables. The PES is used in a Diffusion Monte Carlo study of the zero-point energy and wavefunction of the NO+(H2O) and NO+(D2O) complexes. Using the calculated ZPE the dissociation energies of the clusters are reported. Vibrational configuration interaction calculations of NO+(H2O) and NO+(D2O) using the MULTIMODE program are performed. The fundamental, a number of overtone, and combination states of the clusters are reported. The IR spectrum of the NO+(H2O) cluster is calculated using 4, 5, 7, and 8 modes VSCF/CI calculations. The anharmonic, coupled vibrational calculations, and IR spectrum show very good agreement with experiment. Mode coupling of the water "antisymmetric" stretching mode with the low-frequency intermolecular modes results in intensity borrowing.

  20. MULTIMODE quantum calculations of vibrational energies and IR spectrum of the NO{sup +}(H{sub 2}O) cluster using accurate potential energy and dipole moment surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Homayoon, Zahra, E-mail: zhomayo@emory.edu [Cherry L. Emerson Center for Scientific Computation and Department of Chemistry, Emory University, Atlanta, Georgia 30322 (United States)

    2014-09-28

    A new, full (nine)-dimensional potential energy surface and dipole moment surface to describe the NO{sup +}(H{sub 2}O) cluster is reported. The PES is based on fitting of roughly 32 000 CCSD(T)-F12/aug-cc-pVTZ electronic energies. The surface is a linear least-squares fit using a permutationally invariant basis with Morse-type variables. The PES is used in a Diffusion Monte Carlo study of the zero-point energy and wavefunction of the NO{sup +}(H{sub 2}O) and NO{sup +}(D{sub 2}O) complexes. Using the calculated ZPE the dissociation energies of the clusters are reported. Vibrational configuration interaction calculations of NO{sup +}(H{sub 2}O) and NO{sup +}(D{sub 2}O) using the MULTIMODE program are performed. The fundamental, a number of overtone, and combination states of the clusters are reported. The IR spectrum of the NO{sup +}(H{sub 2}O) cluster is calculated using 4, 5, 7, and 8 modes VSCF/CI calculations. The anharmonic, coupled vibrational calculations, and IR spectrum show very good agreement with experiment. Mode coupling of the water “antisymmetric” stretching mode with the low-frequency intermolecular modes results in intensity borrowing.

  1. MULTIMODE quantum calculations of vibrational energies and IR spectrum of the NO+(H2O) cluster using accurate potential energy and dipole moment surfaces

    International Nuclear Information System (INIS)

    Homayoon, Zahra

    2014-01-01

    A new, full (nine)-dimensional potential energy surface and dipole moment surface to describe the NO + (H 2 O) cluster is reported. The PES is based on fitting of roughly 32 000 CCSD(T)-F12/aug-cc-pVTZ electronic energies. The surface is a linear least-squares fit using a permutationally invariant basis with Morse-type variables. The PES is used in a Diffusion Monte Carlo study of the zero-point energy and wavefunction of the NO + (H 2 O) and NO + (D 2 O) complexes. Using the calculated ZPE the dissociation energies of the clusters are reported. Vibrational configuration interaction calculations of NO + (H 2 O) and NO + (D 2 O) using the MULTIMODE program are performed. The fundamental, a number of overtone, and combination states of the clusters are reported. The IR spectrum of the NO + (H 2 O) cluster is calculated using 4, 5, 7, and 8 modes VSCF/CI calculations. The anharmonic, coupled vibrational calculations, and IR spectrum show very good agreement with experiment. Mode coupling of the water “antisymmetric” stretching mode with the low-frequency intermolecular modes results in intensity borrowing

  2. PECASE: Multi-Spectral Photon Detection in Polymer/Nanoparticle Composites-Toward IR Photodectors and Solar Cells Applicable to Unmanned Vehicles

    Science.gov (United States)

    2016-03-31

    on Organic Solar Cells The maximum amount of surfactant that can be included in the AIR-MAPLE target and still yield photovoltaic function was...in Polymer/Nanoparticle Composites-Toward IR Photodectors and Solar Cells Applicable to Sb. GRANT NUMBER Unmanned Vehicles N00014-1 0-1-0481 Sc...photodetectors and solar cells deposited by RIR-MAPLE, and developing a simulation tool for optoelectronic device performance that accounts for RIR

  3. SPECTRAL ENERGY DISTRIBUTION OF MARKARIAN 501: QUIESCENT STATE VERSUS EXTREME OUTBURST

    International Nuclear Information System (INIS)

    Acciari, V. A.; Benbow, W.; Arlen, T.; Aune, T.; Beilicke, M.; Buckley, J. H.; Bugaev, V.; Dickherber, R.; Boettcher, M.; Boltuch, D.; Bradbury, S. M.; Cannon, A.; Cesarini, A.; Ciupik, L.; Cui, W.; Finley, J. P.; Duke, C.; Errando, M.; Falcone, A.; Finnegan, G.

    2011-01-01

    The very high energy (VHE; E > 100 GeV) blazar Markarian 501 (Mrk 501) has a well-studied history of extreme spectral variability and is an excellent laboratory for studying the physical processes within the jets of active galactic nuclei. However, there are few detailed multiwavelength studies of Mrk 501 during its quiescent state, due to its low luminosity. A short-term multiwavelength study of Mrk 501 was coordinated in 2009 March, focusing around a multi-day observation with the Suzaku X-ray satellite and including γ-ray data from VERITAS, MAGIC, and the Fermi Gamma-ray Space Telescope with the goal of providing a well-sampled multiwavelength baseline measurement of Mrk 501 in the quiescent state. The results of these quiescent-state observations are compared to the historically extreme outburst of 1997 April 16, with the goal of examining variability of the spectral energy distribution (SED) between the two states. The derived broadband SED shows the characteristic double-peaked profile. We find that the X-ray peak shifts by over two orders of magnitude in photon energy between the two flux states while the VHE peak varies little. The limited shift in the VHE peak can be explained by the transition to the Klein-Nishina (KN) regime. Synchrotron self-Compton models are matched to the data and the implied KN effects are explored.

  4. Spectral Energy Distribution of Markarian 501: Quiescent State Versus Extreme Outburst

    Science.gov (United States)

    Acciari, V. A.; Arlen, T.; Aune, T.; Beilicke, M.; Benbow, W.; Böttcher, M.; Boltuch, D.; Bradbury, S. M.; Buckley, J. H.; Bugaev, V.; Cannon, A.; Cesarini, A.; Ciupik, L.; Cui, W.; Dickherber, R.; Duke, C.; Errando, M.; Falcone, A.; Finley, J. P.; Finnegan, G.; Fortson, L.; Furniss, A.; Galante, N.; Gall, D.; Godambe, S.; Grube, J.; Guenette, R.; Gyuk, G.; Hanna, D.; Holder, J.; Huang, D.; Hui, C. M.; Humensky, T. B.; Imran, A.; Kaaret, P.; Karlsson, N.; Kertzman, M.; Kieda, D.; Konopelko, A.; Krawczynski, H.; Krennrich, F.; Madhavan, A. S.; Maier, G.; McArthur, S.; McCann, A.; Moriarty, P.; Ong, R. A.; Otte, A. N.; Pandel, D.; Perkins, J. S.; Pichel, A.; Pohl, M.; Quinn, J.; Ragan, K.; Reyes, L. C.; Reynolds, P. T.; Roache, E.; Rose, H. J.; Schroedter, M.; Sembroski, G. H.; Steele, D.; Swordy, S. P.; Theiling, M.; Thibadeau, S.; Varlotta, A.; Vassiliev, V. V.; Vincent, S.; Wakely, S. P.; Ward, J. E.; Weekes, T. C.; Weinstein, A.; Weisgarber, T.; Williams, D. A.; Wood, M.; Zitzer, B.; VERITAS Collaboration; Aleksić, J.; Antonelli, L. A.; Antoranz, P.; Backes, M.; Barrio, J. A.; Bastieri, D.; Becerra González, J.; Bednarek, W.; Berdyugin, A.; Berger, K.; Bernardini, E.; Biland, A.; Blanch, O.; Bock, R. K.; Boller, A.; Bonnoli, G.; Bordas, P.; Borla Tridon, D.; Bosch-Ramon, V.; Bose, D.; Braun, I.; Bretz, T.; Camara, M.; Carmona, E.; Carosi, A.; Colin, P.; Colombo, E.; Contreras, J. L.; Cortina, J.; Covino, S.; Dazzi, F.; De Angelis, A.; De Cea del Pozo, E.; De Lotto, B.; De Maria, M.; De Sabata, F.; Delgado Mendez, C.; Diago Ortega, A.; Doert, M.; Domínguez, A.; Dominis Prester, D.; Dorner, D.; Doro, M.; Elsaesser, D.; Errando, M.; Ferenc, D.; Fonseca, M. V.; Font, L.; García López, R. J.; Garczarczyk, M.; Gaug, M.; Giavitto, G.; Godinović, N.; Hadasch, D.; Herrero, A.; Hildebrand, D.; Höhne-Mönch, D.; Hose, J.; Hrupec, D.; Jogler, T.; Klepser, S.; Krähenbühl, T.; Kranich, D.; Krause, J.; La Barbera, A.; Leonardo, E.; Lindfors, E.; Lombardi, S.; Longo, F.; López, M.; Lorenz, E.; Majumdar, P.; Makariev, M.; Maneva, G.; Mankuzhiyil, N.; Mannheim, K.; Maraschi, L.; Mariotti, M.; Martínez, M.; Mazin, D.; Meucci, M.; Miranda, J. M.; Mirzoyan, R.; Miyamoto, H.; Moldón, J.; Moralejo, A.; Nieto, D.; Nilsson, K.; Orito, R.; Oya, I.; Paoletti, R.; Paredes, J. M.; Partini, S.; Pasanen, M.; Pauss, F.; Pegna, R. G.; Perez-Torres, M. A.; Persic, M.; Peruzzo, L.; Pochon, J.; Prada, F.; Prada Moroni, P. G.; Prandini, E.; Puchades, N.; Puljak, I.; Reichardt, I.; Reinthal, R.; Rhode, W.; Ribó, M.; Rico, J.; Rissi, M.; Rügamer, S.; Saggion, A.; Saito, K.; Saito, T. Y.; Salvati, M.; Sánchez-Conde, M.; Satalecka, K.; Scalzotto, V.; Scapin, V.; Schultz, C.; Schweizer, T.; Shayduk, M.; Shore, S. N.; Sierpowska-Bartosik, A.; Sillanpää, A.; Sitarek, J.; Sobczynska, D.; Spanier, F.; Spiro, S.; Stamerra, A.; Steinke, B.; Storz, J.; Strah, N.; Struebig, J. C.; Suric, T.; Takalo, L.; Tavecchio, F.; Temnikov, P.; Terzić, T.; Tescaro, D.; Teshima, M.; Torres, D. F.; Vankov, H.; Wagner, R. M.; Weitzel, Q.; Zabalza, V.; Zandanel, F.; Zanin, R.; MAGIC Collaboration; Paneque, D.; Hayashida, M.

    2011-03-01

    The very high energy (VHE; E > 100 GeV) blazar Markarian 501 (Mrk 501) has a well-studied history of extreme spectral variability and is an excellent laboratory for studying the physical processes within the jets of active galactic nuclei. However, there are few detailed multiwavelength studies of Mrk 501 during its quiescent state, due to its low luminosity. A short-term multiwavelength study of Mrk 501 was coordinated in 2009 March, focusing around a multi-day observation with the Suzaku X-ray satellite and including γ-ray data from VERITAS, MAGIC, and the Fermi Gamma-ray Space Telescope with the goal of providing a well-sampled multiwavelength baseline measurement of Mrk 501 in the quiescent state. The results of these quiescent-state observations are compared to the historically extreme outburst of 1997 April 16, with the goal of examining variability of the spectral energy distribution (SED) between the two states. The derived broadband SED shows the characteristic double-peaked profile. We find that the X-ray peak shifts by over two orders of magnitude in photon energy between the two flux states while the VHE peak varies little. The limited shift in the VHE peak can be explained by the transition to the Klein-Nishina (KN) regime. Synchrotron self-Compton models are matched to the data and the implied KN effects are explored.

  5. Integrated Spectral Energy Distributions and Absorption Feature Indices of Single Stellar Populations

    OpenAIRE

    Zhang, Fenghui; Han, Zhanwen; Li, Lifang; Hurley, Jarrod R.

    2004-01-01

    Using evolutionary population synthesis, we present integrated spectral energy distributions and absorption-line indices defined by the Lick Observatory image dissector scanner (referred to as Lick/IDS) system, for an extensive set of instantaneous burst single stellar populations (SSPs). The ages of the SSPs are in the range 1-19 Gyr and the metallicities [Fe/H] are in the range -2.3 - 0.2. Our models use the rapid single stellar evolution algorithm of Hurley, Pols and Tout for the stellar e...

  6. Spectral energy transfer of atmospheric gravity waves through sum and difference nonlinear interactions

    Energy Technology Data Exchange (ETDEWEB)

    Huang, K.M. [Wuhan Univ. (China). School of Electronic Information; Chinese Academey of Sciences, Hefei (China). Key Lab. of Geospace Environment; Embry Riddle Aeronautical Univ., Daytona Beach, FL (United States). Dept. of Physical Science; Ministry of Education, Wuhan (China). Key Lab. of Geospace Environment and Geodesy; State Observatory for Atmospheric Remote Sensing, Wuhan (China); Liu, A.Z.; Li, Z. [Embry Riddle Aeronautical Univ., Daytona Beach, FL (United States). Dept. of Physical Science; Zhang, S.D.; Yi, F. [Wuhan Univ. (China). School of Electronic Information; Ministry of Education, Wuhan (China). Key Lab. of Geospace Environment and Geodesy; State Observatory for Atmospheric Remote Sensing, Wuhan (China)

    2012-07-01

    Nonlinear interactions of gravity waves are studied with a two-dimensional, fully nonlinear model. The energy exchanges among resonant and near-resonant triads are examined in order to understand the spectral energy transfer through interactions. The results show that in both resonant and near-resonant interactions, the energy exchange between two high frequency waves is strong, but the energy transfer from large to small vertical scale waves is rather weak. This suggests that the energy cascade toward large vertical wavenumbers through nonlinear interaction is inefficient, which is different from the rapid turbulence cascade. Because of considerable energy exchange, nonlinear interactions can effectively spread high frequency spectrum, and play a significant role in limiting wave amplitude growth and transferring energy into higher altitudes. In resonant interaction, the interacting waves obey the resonant matching conditions, and resonant excitation is reversible, while near-resonant excitation is not so. Although near-resonant interaction shows the complexity of match relation, numerical experiments show an interesting result that when sum and difference near-resonant interactions occur between high and low frequency waves, the wave vectors tend to approximately match in horizontal direction, and the frequency of the excited waves is also close to the matching value. (orig.)

  7. CANDELS: CORRELATIONS OF SPECTRAL ENERGY DISTRIBUTIONS AND MORPHOLOGIES WITH STAR FORMATION STATUS FOR MASSIVE GALAXIES AT z ∼ 2

    International Nuclear Information System (INIS)

    Wang Tao; Gu Qiusheng; Huang Jiasheng; Fang Guanwen; Fazio, G. G.; Faber, S. M.; McGrath, Elizabeth J.; Kocevski, Dale; Wuyts, Stijn; Yan Haojing; Dekel, Avishai; Guo Yicheng; Ferguson, Henry C.; Grogin, Norman; Lotz, Jennifer M.; Lucas, Ray A.; Koekemoer, A. M.; Weiner, Benjamin; Hathi, Nimish P.; Kong Xu

    2012-01-01

    We present a study on spectral energy distributions, morphologies, and star formation for an IRAC-selected extremely red object sample in the GOODS Chandra Deep Field-South. This work was enabled by new HST/WFC3 near-IR imaging from the CANDELS survey as well as the deepest available X-ray data from Chandra 4 Ms observations. This sample consists of 133 objects with the 3.6 μm limiting magnitude of [3.6] = 21.5 and is approximately complete for galaxies with M * > 10 11 M ☉ at 1.5 ≤ z ≤ 2.5. We classify this sample into two types, quiescent and star-forming galaxies (SFGs), in the observed infrared color-color ([3.6]–[24] versus K – [3.6]) diagram. The further morphological study of this sample shows a consistent result with the observed color classification. The classified quiescent galaxies are bulge dominated and SFGs in the sample have disk or irregular morphologies. Our observed infrared color classification is also consistent with the rest-frame color (U – V versus V – J) classification. We also found that quiescent and SFGs are well separated in the nonparametric morphology parameter (Gini versus M 20 ) diagram measuring their concentration and clumpiness: quiescent galaxies have a Gini coefficient higher than 0.58 and SFGs have a Gini coefficient lower than 0.58. We argue that the star formation quenching process must lead to or be accompanied by the increasing galaxy concentration. One prominent morphological feature of this sample is that disks are commonly seen in this massive galaxy sample at 1.5 ≤ z ≤ 2.5: 30% of quiescent galaxies and 70% of SFGs with M * > 10 11 M ☉ have disks in their rest-frame optical morphologies. The prevalence of these extended, relatively undisturbed disks challenges the merging scenario as the main mode of massive galaxy formation.

  8. A Different View of Solar Spectral Irradiance Variations: Modeling Total Energy over Six-Month Intervals.

    Science.gov (United States)

    Woods, Thomas N; Snow, Martin; Harder, Jerald; Chapman, Gary; Cookson, Angela

    A different approach to studying solar spectral irradiance (SSI) variations, without the need for long-term (multi-year) instrument degradation corrections, is examining the total energy of the irradiance variation during 6-month periods. This duration is selected because a solar active region typically appears suddenly and then takes 5 to 7 months to decay and disperse back into the quiet-Sun network. The solar outburst energy, which is defined as the irradiance integrated over the 6-month period and thus includes the energy from all phases of active region evolution, could be considered the primary cause for the irradiance variations. Because solar cycle variation is the consequence of multiple active region outbursts, understanding the energy spectral variation may provide a reasonable estimate of the variations for the 11-year solar activity cycle. The moderate-term (6-month) variations from the Solar Radiation and Climate Experiment (SORCE) instruments can be decomposed into positive (in-phase with solar cycle) and negative (out-of-phase) contributions by modeling the variations using the San Fernando Observatory (SFO) facular excess and sunspot deficit proxies, respectively. These excess and deficit variations are fit over 6-month intervals every 2 months over the mission, and these fitted variations are then integrated over time for the 6-month energy. The dominant component indicates which wavelengths are in-phase and which are out-of-phase with solar activity. The results from this study indicate out-of-phase variations for the 1400 - 1600 nm range, with all other wavelengths having in-phase variations.

  9. Critically Evaluated Energy Levels, Spectral Lines, Transition Probabilities, and Intensities of Singly Ionized Vanadium (V ii)

    Energy Technology Data Exchange (ETDEWEB)

    Saloman, Edward B. [Dakota Consulting, Inc., 1110 Bonifant Street, Suite 310, Silver Spring, MD 20910 (United States); Kramida, Alexander [National Institute of Standards and Technology, Gaithersburg, MD 20899 (United States)

    2017-08-01

    The energy levels, observed spectral lines, and transition probabilities of singly ionized vanadium, V ii, have been compiled. The experimentally derived energy levels belong to the configurations 3 d {sup 4}, 3 d {sup 3} ns ( n  = 4, 5, 6), 3 d {sup 3} np , and 3 d {sup 3} nd ( n  = 4, 5), 3 d {sup 3}4 f , 3 d {sup 2}4 s {sup 2}, and 3 d {sup 2}4 s 4 p . Also included are values for some forbidden lines that may be of interest to the astrophysical community. Experimental Landé g -factors and leading percentages for the levels are included when available, as well as Ritz wavelengths calculated from the energy levels. Wavelengths and transition probabilities are reported for 3568 and 1896 transitions, respectively. From the list of observed wavelengths, 407 energy levels are determined. The observed intensities, normalized to a common scale, are provided. From the newly optimized energy levels, a revised value for the ionization energy is derived, 118,030(60) cm{sup −1}, corresponding to 14.634(7) eV. This is 130 cm{sup −1} higher than the previously recommended value from Iglesias et al.

  10. Determination of the Spectral Index in the Fission Spectrum Energy Regime

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Amy Sarah [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2016-05-16

    Neutron reaction cross sections play a vital role in tracking the production and destruction of isotopes exposed to neutron fluence. They are central to the process of reconciling the initial and final atom inventories. Measurements of irradiated samples by radiochemical methods in tangent with an algorithm are used to evaluate the fluence a sample is exposed to over the course of the irradiation. This algorithm is the Isotope Production Code (IPC) created and used by the radiochemistry data assessment team at Los Alamos National Laboratory (LANL). An integral result is calculated by varying the total neutron fluence seen by a sample. A sample, irradiated in a critical assembly, will be exposed to a unique neutron flux defined by the neutron source and distance of the sample from the source. Neutron cross sections utilized are a function of the hardness of the neutron spectrum at the location of irradiation. A spectral index is used an indicator of the hardness of the neutron spectrum. Cross sections fit forms applied in IPC are collapsed from a LANL 30-group energy structure. Several decades of research and development have been performed to formalize the current IPC cross section library. Basis of the current fission spectrum neutron reaction cross section library is rooted in critical assembly experiments performed from the 1950’s through the early 1970’s at LANL. The focus of this report is development of the spectral index used an indicator of the hardness of the neutron spectrum in the fission spectrum energy regime.

  11. Planck Early Results. XV. Spectral Energy Distributions and Radio Continuum Spectra of Northern Extragalactic Radio Sources

    Science.gov (United States)

    Aatrokoski, J.; Ade, P. A. R.; Aghanim, N.; Aller, H. D.; Aller, M. F.; Angelakis, E.; Amaud, M.; Ashdown, M.; Aumont, J.; Baccigalupi, C.; hide

    2011-01-01

    Spectral energy distributions (SEDs) and radio continuum spectra are presented for a northern sample of 104 extragalactic radio sources. based on the Planck Early Release Compact Source Catalogue (ERCSC) and simultaneous multi frequency data. The nine Planck frequencies, from 30 to 857 GHz, are complemented by a set of simultaneous observations ranging from radio to gamma-rays. This is the first extensive frequency coverage in the radio and millimetre domains for an essentially complete sample of extragalactic radio sources, and it shows how the individual shocks, each in their own phase of development, shape the radio spectra as they move in the relativistic jet. The SEDs presented in this paper were fitted with second and third degree polynomials to estimate the frequencies of the synchrotron and inverse Compton (IC) peaks, and the spectral indices of low and high frequency radio data, including the Planck ERCSC data, were calculated. SED modelling methods are discussed, with an emphasis on proper. physical modelling of the synchrotron bump using multiple components. Planck ERCSC data also suggest that the original accelerated electron energy spectrum could be much harder than commonly thought, with power-law index around 1.5 instead of the canonical 2.5. The implications of this are discussed for the acceleration mechanisms effective in blazar shock. Furthermore in many cases the Planck data indicate that gamma-ray emission must originate in the same shocks that produce the radio emission.

  12. High energy QCD scattering, the shape of gravity on an IR brane, and the Froissart bound

    International Nuclear Information System (INIS)

    Giddings, Steven B.

    2003-01-01

    High-energy scattering in nonconformal gauge theories is investigated using the AdS/conformal field theory (CFT) dual string-gravity theory. It is argued that strong-gravity processes, such as black hole formation, play an important role in the dual dynamics. Further information about this dynamics is found by performing a linearized analysis of gravity for a mass near an infrared brane; this gives the far field approximation to black hole or other strong-gravity effects, and in particular allows us to estimate their shape. From this shape, one can infer a total scattering cross section that grows with center of mass energy as ln 2 E, saturating the Froissart bound

  13. Spectral Characterization of the Wave Energy Resource for Puerto Rico (PR) and the United States Virgin Islands (USVI)

    Science.gov (United States)

    Garcia, C. G.; Canals, M.; Irizarry, A. A.

    2016-02-01

    Nowadays a significant amount of wave energy assessments have taken place due to the development of the ocean energy markets worldwide. Energy contained in surface gravity waves is scattered along frequency components that can be described using wave spectra. Correspondingly, characterization and quantification of harvestable wave energy is inherently dictated by the nature of the two-dimensional wave spectrum. The present study uses spectral wave data from the operational SWAN-based CariCOOS Nearshore Wave Model to evaluate the capture efficiency of multiple wave energy converters (WEC). This study revolves around accurately estimating available wave energy as a function of varying spectral distributions, effectively providing a detailed insight concerning local wave conditions for PR and USVI and the resulting available-energy to generated-power ratio. Results in particular, provide a comprehensive characterization of three years' worth of SWAN-based datasets by outlining where higher concentrations of wave energy are localized in the spectrum. Subsequently, the aforementioned datasets were processed to quantify the amount of energy incident on two proposed sites located in PR and USVI. Results were largely influenced by local trade wind activity, which drive predominant sea states, and the amount of North-Atlantic swells that propagate towards the region. Each wave event was numerically analyzed in the frequency domain to evaluate the capacity of a WEC to perform under different spectral distribution scenarios, allowing for a correlation between electrical power output and spectral energy distribution to be established.

  14. Aspects of the UV/IR correspondence : energy broadening and string fluctuations

    CERN Document Server

    Hatta, Y; Mueller, A H; Triantafyllopoulos, D N

    2011-01-01

    We show that a source which radiates in the vacuum of the strongly coupled N=4 SYM theory produces an energy distribution which, in the supergravity approximation, has the same space-time pattern as the corresponding classical distribution: the radiation propagates at the speed of light without broadening. We illustrate this on the basis of several examples: a small perturbation propagating down a steady string, a massless particle falling into AdS_5, and the decay of a time-like wave-packet. A similar observation was made in Phys. Rev. D81 (2010) 126001 for the case of a rotating string. In all these cases, the absence of broadening is related to the fact that the energy backreaction on the boundary arises exclusively from the bulk perturbation at, or near, the boundary. This is so since bulk sources which propagate in AdS_5 at the speed of light do not generate any energy on the boundary. We interpret these features as an artifact of the supergravity approximation, which fails to encode quantum mechanical f...

  15. Energy calibration issues in nuclear resonant vibrational spectroscopy: observing small spectral shifts and making fast calibrations.

    Science.gov (United States)

    Wang, Hongxin; Yoda, Yoshitaka; Dong, Weibing; Huang, Songping D

    2013-09-01

    The conventional energy calibration for nuclear resonant vibrational spectroscopy (NRVS) is usually long. Meanwhile, taking NRVS samples out of the cryostat increases the chance of sample damage, which makes it impossible to carry out an energy calibration during one NRVS measurement. In this study, by manipulating the 14.4 keV beam through the main measurement chamber without moving out the NRVS sample, two alternative calibration procedures have been proposed and established: (i) an in situ calibration procedure, which measures the main NRVS sample at stage A and the calibration sample at stage B simultaneously, and calibrates the energies for observing extremely small spectral shifts; for example, the 0.3 meV energy shift between the 100%-(57)Fe-enriched [Fe4S4Cl4](=) and 10%-(57)Fe and 90%-(54)Fe labeled [Fe4S4Cl4](=) has been well resolved; (ii) a quick-switching energy calibration procedure, which reduces each calibration time from 3-4 h to about 30 min. Although the quick-switching calibration is not in situ, it is suitable for normal NRVS measurements.

  16. CO-ANALYSIS OF SOLAR MICROWAVE AND HARD X-RAY SPECTRAL EVOLUTIONS. I. IN TWO FREQUENCY OR ENERGY RANGES

    International Nuclear Information System (INIS)

    Song Qiwu; Huang Guangli; Nakajima, Hiroshi

    2011-01-01

    Solar microwave and hard X-ray spectral evolutions are co-analyzed in the 2000 June 10 and 2002 April 10 flares, and are simultaneously observed by the Owens-Valley Solar Array in the microwave band and by Yohkoh/Hard X-ray Telescope or RHESSI in the hard X-ray band, with multiple subpeaks in their light curves. The microwave and hard X-ray spectra are fitted by a power law in two frequency ranges of the optical thin part and two photon energy ranges, respectively. Similar to an earlier event in Shao and Huang, the well-known soft-hard-soft pattern of the lower energy range changed to the hard-soft-hard (HSH) pattern of the higher energy range during the spectral evolution of each subpeak in both hard X-ray flares. This energy dependence is actually supported by a positive correlation between the overall light curves and spectral evolution in the lower energy range, while it becomes an anti-correlation in the higher energy range. Regarding microwave data, the HSH pattern appears in the spectral evolution of each subpeak in the lower frequency range, which is somewhat similar to Huang and Nakajima. However, it returns back to the well-known pattern of soft-hard-harder for the overall spectral evolution in the higher frequency range of both events. This frequency dependence is confirmed by an anti-correlation between the overall light curves and spectral evolution in the lower frequency range, but it becomes a positive correlation in the higher frequency range. The possible mechanisms are discussed, respectively, for reasons why hard X-ray and microwave spectral evolutions have different patterns in different energy and frequency intervals.

  17. Analysis of spectral effects on the energy yield of different PV (photovoltaic) technologies: The case of four specific sites

    International Nuclear Information System (INIS)

    Alonso-Abella, M.; Chenlo, F.; Nofuentes, G.; Torres-Ramírez, M.

    2014-01-01

    This work is aimed at looking into the impact of the solar spectrum distribution on the energy yield of some PV (photovoltaic) materials on both monthly and annual time scales. The relative spectral responses of eight different PV solar cells – representative of each considered technology – have been selected. Modeling solar spectra in four sites located in the north hemisphere together with a 12-month experimental campaign in which spectral irradiances were periodically recorded in two of these sites located in Spain have provided highly interesting results. Regardless of the site, the considered amorphous silicon and cadmium telluride PV cells experience the most noticeable modeled and experimental variations of their monthly spectral gains, whilst flatter seasonal ones are identified in the remaining considered PV technologies. Thus, the maximum monthly variations of these spectral gains take place in the a-Si PV cell, ranging from −16% (winter) to 4% (summer) in Stuttgart. Anyway, the monthly spread of the spectral effects decreases as the latitude of the site does. Last, the impact of the solar spectrum distribution is remarkably reduced when the period of integration is enlarged up to a year. In fact, annual spectral gains keep below 2.2% for all the studied technologies and sites. - Highlights: • Monthly and annual spectral effects on eight different PV (photovoltaic) technologies studied. • Modeled spectra in four sites combined with relative spectral responses. • Measured spectra (12 months) in two sites combined with relative spectral responses. • Higher bandgap technologies: noticeable monthly variations in their spectral gains. • Annual spectral gains keep below 2.2% for all the studied technologies and sites

  18. Thermo spectral analysis (TSA) of living human skin by FT-IR -Development of a diagnostic method for the early detection of chronic diseases

    Science.gov (United States)

    Folberth, W.; Heim, G.

    1985-12-01

    A Fourier spectrometer was used in order to measure the spectral emissivity E(k) of human skin in the FIR region k=190-420 cm-1. Three studies on patient groups with defined chronic diseases have been performed: patients with untreated bronchial carcinoma, patients with rheumatic arthritis and patients with chronic renal insufficiency. In comparison with a symptomfree control group all patient groups show significant differences in E(k). As result of a discriminant analysis a separation of 95.7% between carcinoma patients and control persons is possible. The separation quotes between the other groups indicate that patients with malignant neoplasms can be discriminated from other chronically ill persons.

  19. Combined two-photon excitation and d → f energy-transfer in Ir/lanthanide dyads with time-gated selection from a two-component emission spectrum.

    Science.gov (United States)

    Edkins, Robert M; Sykes, Daniel; Beeby, Andrew; Ward, Michael D

    2012-10-14

    In a pair of Ir/Eu and Ir/Tb dyads, two-photon excitation of the Ir-phenylpyridine chromophore at 780 nm is followed by partial d → f energy-transfer to give a combination of short-lived Ir-based (blue) and long-lived lanthanide-based (red or green) emission; these components can be selected separately by time-gated detection.

  20. Synthesis and IR spectral study of MoO2Cl2 molecular complex with acetoacetanilides. Crystal structure of MoO2Cl2 complex with acetoacet-2-toluidine

    International Nuclear Information System (INIS)

    Abramenko, V.L.; Sergienko, V.S.; Churakov, A.V.

    2000-01-01

    Certain MoO 2 Cl 2 complexes with acetoacetanilide derivatives were synthesized, two IR spectral study being performed. Crystal and molecular structure of MoO 2 Cl 2 complex with acetoacet-2-toluidine (HL) was determined using X-ray diffraction analysis. The crystals are monoclinic, a = 7.621 (7), b = 9.498 (3), c = 19.980 (9) A, β = 95.16 (7), Z = 4, sp.gr. P2 1 /n. Coordination polyhedron of Mo atom is a distorted octahedron with two O oxoatoms in cis-position, two Cl atom in mutual trans-position and two O(HL) atoms in trans-positions in reference to O(oxo) [ru

  1. Tracing the Jet Contribution to the Mid-IR over the 2005 Outburst of GRO J1655-40 via Broadband Spectral Modeling

    Science.gov (United States)

    Migliari, S.; Tomsick, J. A.; Markoff, S.; Kalemci, E.; Bailyn, C. D.; Buxton, M.; Corbel, S; Fender, R. P.; Kaaret, P.

    2007-01-01

    We present new results from a multi-wavelength (radio/infrared/optical/X-ray) study of the black hole Xray binary GRO 51655-40 during its 2005 outburst. We detected, for the first time, mid-infrared emission at 24 micron from the compact jet of a black hole X-ray binary during its hard state, when the source shows emission from a radio compact jet, as well as a strong non-thermal hard X-ray component. These detections strongly constrain the optically thick part of the synchrotron spectrum of the compact jet, which is consistent with it being flat over 4 orders of magnitude in frequency. Moreover, using this unprecedented coverage, and especially thanks to the new Spitzer observations, we can test broadband disk and jet models during the hard state. Two of the hard-state broadband spectra are reasonably well fitted using a jet model with parameters that overall are similar to those previously found for Cyg X-1 and GX 339-4. Differences are also present; most notably, the jet power in GRO J1655-40 appears to be a factor of at least approximately 3-5 higher (depending on the distance) than those of Cyg X-1 and GX-339-4 at comparable disk luminosities. Furthermore, a few discrepancies between the model and the data, previously not found for the other two black hole systems for which there was no mid-IR/IR and optical coverage, are evident, and will help to constrain and refine theoretical models.

  2. Toward accurate prediction of potential energy surfaces and the spectral density of hydrogen bonded systems

    International Nuclear Information System (INIS)

    Rekik, Najeh

    2014-01-01

    Despite the considerable progress made in quantum theory and computational methods, detailed descriptions of the potential energy surfaces of hydrogen-bonded systems have not yet been achieved. In addition, the hydrogen bond (H-bond) itself is still so poorly understood at the fundamental level that it remains unclear exactly what geometry constitutes a “real” H-bond. Therefore, in order to investigate features essential for hydrogen bonded complexes, a simple, efficient, and general method for calculating matrix elements of vibrational operators capable of describing the stretching modes and the H-bond bridges of hydrogen-bonded systems is proposed. The derived matrix elements are simple and computationally easy to evaluate, which makes the method suitable for vibrational studies of multiple-well potentials. The method is illustrated by obtaining potential energy surfaces for a number of two-dimensional systems with repulsive potentials chosen to be in Gaussian form for the stretching mode and of the Morse-type for the H-bond bridge dynamics. The forms of potential energy surfaces of weak and strong hydrogen bonds are analyzed by varying the asymmetry of the Gaussian potential. Moreover, the choice and applicability of the selected potential for the stretching mode and comparison with other potentials used in the area of hydrogen bond research are discussed. The approach for the determination of spectral density has been constructed in the framework of the linear response theory for which spectral density is obtained by Fourier transform of the autocorrelation function of the dipole moment operator of the fast mode. The approach involves anharmonic coupling between the high frequency stretching vibration (double well potential) and low-frequency donor-acceptor stretching mode (Morse potential) as well as the electrical anharmonicity of the dipole moment operator of the fast mode. A direct relaxation mechanism is incorporated through a time decaying exponential

  3. Energy profile, spectroscopic (FT-IR, FT-Raman and FT-NMR) and DFT studies of 4-bromoisophthalic acid

    Science.gov (United States)

    Arjunan, V.; Thirunarayanan, S.; Mohan, S.

    2018-04-01

    The stable conformer of 4-bromoisophthalic acid (BIPA) has been identified by potential energy profile analysis. All the structural parameters of 4-bromoisophthalic acid are determined by B3LYP method with 6-311++G**, 6-31G** and cc-pVTZ basis sets. The fundamental vibrations are analysed with the use of FT-IR (4000-400 cm-1) and FT-Raman (4000-100 cm-1) spectra. The harmonic vibrational frequencies are theoretically calculated and compared with experimental FTIR and FT-Raman frequencies. The 1H and 13C NMR spectra have been analysed and compared with theoretical 1H and 13C NMR chemical shifts calculated by gauge independent atomic orbital (GIAO) method. The electronic properties, such as HOMO (highest occupied molecular orbital) and LUMO (lowest unoccupied molecular orbital) energies are determined by B3LYP/cc-pVTZ method. The electron density distribution and site of chemical reactivity of BIPA molecule have been obtained by mapping electron density isosurface with molecular electrostatic potential (MEP). Stability of the molecules arising from hyperconjugative interactions, charge delocalizations have been analysed by using natural bond orbital (NBO) analysis. The thermodynamic properties and atomic natural charges of the compound are analysed and the reactive sites of the molecule are identified. The global and local reactivity descriptors are evaluated to analyse the chemical reactivity and site selectivity of molecule through Fukui functions.

  4. Virtual Non-Contrast CT Using Dual-Energy Spectral CT: Feasibility of Coronary Artery Calcium Scoring

    OpenAIRE

    Song, Inyoung; Yi, Jeong Geun; Park, Jeong Hee; Kim, Sung Mok; Lee, Kyung Soo; Chung, Myung Jin

    2016-01-01

    Objective To evaluate the feasibility of coronary artery calcium scoring based on three virtual noncontrast-enhanced (VNC) images derived from single-source spectral dual-energy CT (DECT) as compared with true noncontrast-enhanced (TNC) images. Materials and Methods This prospective study was conducted with the approval of our Institutional Review Board. Ninety-seven patients underwent noncontrast CT followed by contrast-enhanced chest CT using single-source spectral DECT. Iodine eliminated V...

  5. COMBINED ANALYSIS OF IMAGES AND SPECTRAL ENERGY DISTRIBUTIONS OF TAURUS PROTOSTARS

    International Nuclear Information System (INIS)

    Gramajo, Luciana V.; Gomez, Mercedes; Whitney, Barbara A.; Robitaille, Thomas P.

    2010-01-01

    We present an analysis of spectral energy distributions (SEDs), near- and mid-infrared images, and Spitzer spectra of eight embedded Class I/II objects in the Taurus-Auriga molecular cloud. The initial model for each source was chosen using the grid of young stellar objects (YSOs) and SED fitting tool of Robitaille et al. Then the models were refined using the radiative transfer code of Whitney et al. to fit both the spectra and the infrared images of these objects. In general, our models agree with previous published analyses. However, our combined models should provide more reliable determinations of the physical and geometrical parameters since they are derived from SEDs, including the Spitzer spectra, covering the complete spectral range; and high-resolution near-infrared and Spitzer IRAC images. The combination of SED and image modeling better constrains the different components (central source, disk, envelope) of the YSOs. Our derived luminosities are higher, on average, than previous estimates because we account for the viewing angles (usually nearly edge-on) of most of the sources. Our analysis suggests that the standard rotating collapsing protostar model with disks and bipolar cavities works well for the analyzed sample of objects in the Taurus molecular cloud.

  6. A spectral chart method for estimating the mean turbulent kinetic energy dissipation rate

    Science.gov (United States)

    Djenidi, L.; Antonia, R. A.

    2012-10-01

    We present an empirical but simple and practical spectral chart method for determining the mean turbulent kinetic energy dissipation rate DNS spectra, points to this scaling being also valid at small Reynolds numbers, provided effects due to inhomogeneities in the flow are negligible. The methods avoid the difficulty associated with estimating time or spatial derivatives of the velocity fluctuations. It also avoids using the second hypothesis of K41, which implies the existence of a -5/3 inertial subrange only when the Taylor microscale Reynods number R λ is sufficiently large. The method is in fact applied to the lower wavenumber end of the dissipative range thus avoiding most of the problems due to inadequate spatial resolution of the velocity sensors and noise associated with the higher wavenumber end of this range.The use of spectral data (30 ≤ R λ ≤ 400) in both passive and active grid turbulence, a turbulent mixing layer and the turbulent wake of a circular cylinder indicates that the method is robust and should lead to reliable estimates of < \\varepsilon rangle in flows or flow regions where the first similarity hypothesis should hold; this would exclude, for example, the region near a wall.

  7. Differential diagnosis between benign and malignant pleural effusion with dual-energy spectral CT.

    Science.gov (United States)

    Zhang, Xirong; Duan, Haifeng; Yu, Yong; Ma, Chunling; Ren, Zhanli; Lei, Yuxin; He, Taiping; Zhang, Ming

    2018-01-01

    of 100% and specificity of 71.4% with area-under-curve of 0.933 for differentiating benign from malignant effusion. The CT value measurement at both high and low energy levels and the effective atomic number obtained in a single spectral CT scan can assist the differential diagnosis of benign from malignant pleural effusion.Combining them with patient age and disease history can further improve diagnostic performance. Clinical findings and Spectral CT imaging can provide significant evidences about the nature of pleural effusion.

  8. The spectral energy distributions of isolated neutron stars in the resonant cyclotron scattering model

    Science.gov (United States)

    Tong, Hao; Xu, Renxin

    2013-03-01

    The X-ray dim isolated neutron stars (XDINSs) are peculiar pulsar-like objects, characterized by their very well Planck-like spectrum. In studying their spectral energy distributions, the optical/UV excess is a long standing problem. Recently, Kaplan et al. (2011) have measured the optical/UV excess for all seven sources, which is understandable in the resonant cyclotron scattering (RCS) model previously addressed. The RCS model calculations show that the RCS process can account for the observed optical/UV excess for most sources. The flat spectrum of RX J2143.0+0654 may due to contribution from bremsstrahlung emission of the electron system in addition to the RCS process.

  9. Optimized Energy Efficiency and Spectral Efficiency Resource Allocation Strategies for Phantom Cellular Networks

    KAUST Repository

    Abdelhady, Amr, M.; Amin, Osama; Alouini, Mohamed-Slim

    2016-01-01

    Multi-teir hetrogeneous networks have become an essential constituent for next generation cellular networks. Meanwhile, energy efficiency (EE) has been considered a critical design criterion along with the traditional spectral efficiency (SE) metric. In this context, we study power and spectrum allocation for the recently proposed two-teir architecture known as Phantom cellular networks. The optimization framework includes both EE and SE, where we propose an algorithm that computes the SE and EE resource allocation for Phantom cellular networks. Then, we compare the performance of both design strategies versus the number of users, and the ration of Phantom cellresource blocks to the total number or resource blocks. We aim to investigate the effect of some system parameters to acheive improved SE or EE performance at a non-significant loss in EE or SE performance, respectively. It was found that the system parameters can be tuned so that the EE solution does not yield a significant loss in the SE performance.

  10. Energy and spectral efficiency analysis for selective ARQ multi-channel systems

    KAUST Repository

    Shafique, Taniya

    2017-07-31

    In this paper, we develop selective retransmission schemes for multiple-channel systems. The proposed schemes are selective automatic repeat request with fixed bandwidth (SARQ-FB), selective chase combining with fixed bandwidth (SCC-FB) and selective automatic repeat request with variable bandwidth (SARQ-VB). The main objective of the proposed schemes is to use the available power and bandwidth budget effectively along with the selective retransmission to deliver the required data successfully within a limited number of transmissions. To investigate the performance of each scheme, we first analyze the average spectral and energy efficiency and derive closed form expressions for each scheme. Then, we compare the EE and SE of each scheme through numerical results.

  11. A dust spectral energy distribution model with hierarchical Bayesian inference - I. Formalism and benchmarking

    Science.gov (United States)

    Galliano, Frédéric

    2018-05-01

    This article presents a new dust spectral energy distribution (SED) model, named HerBIE, aimed at eliminating the noise-induced correlations and large scatter obtained when performing least-squares fits. The originality of this code is to apply the hierarchical Bayesian approach to full dust models, including realistic optical properties, stochastic heating, and the mixing of physical conditions in the observed regions. We test the performances of our model by applying it to synthetic observations. We explore the impact on the recovered parameters of several effects: signal-to-noise ratio, SED shape, sample size, the presence of intrinsic correlations, the wavelength coverage, and the use of different SED model components. We show that this method is very efficient: the recovered parameters are consistently distributed around their true values. We do not find any clear bias, even for the most degenerate parameters, or with extreme signal-to-noise ratios.

  12. Optimized Energy Efficiency and Spectral Efficiency Resource Allocation Strategies for Phantom Cellular Networks

    KAUST Repository

    Abdelhady, Amr, M.

    2016-01-06

    Multi-teir hetrogeneous networks have become an essential constituent for next generation cellular networks. Meanwhile, energy efficiency (EE) has been considered a critical design criterion along with the traditional spectral efficiency (SE) metric. In this context, we study power and spectrum allocation for the recently proposed two-teir architecture known as Phantom cellular networks. The optimization framework includes both EE and SE, where we propose an algorithm that computes the SE and EE resource allocation for Phantom cellular networks. Then, we compare the performance of both design strategies versus the number of users, and the ration of Phantom cellresource blocks to the total number or resource blocks. We aim to investigate the effect of some system parameters to acheive improved SE or EE performance at a non-significant loss in EE or SE performance, respectively. It was found that the system parameters can be tuned so that the EE solution does not yield a significant loss in the SE performance.

  13. Effect of H{sup +} implantation on the optical properties of semi-insulating GaAs crystals in the IR spectral region

    Energy Technology Data Exchange (ETDEWEB)

    Klyui, N. I.; Lozinskii, V. B., E-mail: lvb@isp.kiev.ua [Jilin University, College of Physics (China); Liptuga, A. I.; Dikusha, V. N. [National Academy of Sciences of Ukraine, Lashkaryov Institute of Semiconductor Physics (Ukraine); Oksanych, A. P.; Kogdas’, M. G.; Perekhrest, A. L.; Pritchin, S. E. [Kremenchug National University (Ukraine)

    2017-03-15

    The optical properties of semi-insulating GaAs crystals subjected to multienergy hydrogen-ion implantation and treatment in a high-frequency electromagnetic field are studied in the infrared spectral region. It is established that such combined treatment provides a means for substantially increasing the transmittance of GaAs crystals to values characteristic of crystals of high optical quality. On the basis of analysis of the infrared transmittance and reflectance data, Raman spectroscopy data, and atomic-force microscopy data on the surface morphology of the crystals, a physical model is proposed to interpret the effects experimentally observed in the crystals. The model takes into account the interaction of radiation defects with the initial structural defects in the crystals as well as the effect of compensation of defect centers by hydrogen during high-frequency treatment.

  14. Effect of H+ implantation on the optical properties of semi-insulating GaAs crystals in the IR spectral region

    International Nuclear Information System (INIS)

    Klyui, N. I.; Lozinskii, V. B.; Liptuga, A. I.; Dikusha, V. N.; Oksanych, A. P.; Kogdas’, M. G.; Perekhrest, A. L.; Pritchin, S. E.

    2017-01-01

    The optical properties of semi-insulating GaAs crystals subjected to multienergy hydrogen-ion implantation and treatment in a high-frequency electromagnetic field are studied in the infrared spectral region. It is established that such combined treatment provides a means for substantially increasing the transmittance of GaAs crystals to values characteristic of crystals of high optical quality. On the basis of analysis of the infrared transmittance and reflectance data, Raman spectroscopy data, and atomic-force microscopy data on the surface morphology of the crystals, a physical model is proposed to interpret the effects experimentally observed in the crystals. The model takes into account the interaction of radiation defects with the initial structural defects in the crystals as well as the effect of compensation of defect centers by hydrogen during high-frequency treatment.

  15. Virtual non-contrast CT using dual energy spectral CT: Feasibility of coronary artery calcium scoring

    International Nuclear Information System (INIS)

    Song, In Young; Yi, Jeong Geun; Park, Jeong Hee; Lee, Sung Mok; Lee, Kyung Soo; Chung, Myung Jin

    2016-01-01

    To evaluate the feasibility of coronary artery calcium scoring based on three virtual noncontrast-enhanced (VNC) images derived from single-source spectral dual-energy CT (DECT) as compared with true noncontrast-enhanced (TNC) images. This prospective study was conducted with the approval of our Institutional Review Board. Ninety-seven patients underwent noncontrast CT followed by contrast-enhanced chest CT using single-source spectral DECT. Iodine eliminated VNC images were reconstructed using two kinds of 2-material decomposition algorithms (material density iodine-water pair [MDW], material density iodine-calcium pair [MDC]) and a material suppressed algorithm (material suppressed iodine [MSI]). Two readers independently quantified calcium on VNC and TNC images. The Spearman correlation coefficient test and Bland-Altman method were used for statistical analyses. Coronary artery calcium scores from all three VNC images showed excellent correlation with those from the TNC images (Spearman's correlation coefficient [ρ] = 0.94, 0.88, and 0.89 for MDW, MDC, and MSI, respectively; p < 0.001 for all pairs). Measured coronary calcium volumes from VNC images also correlated well with those from TNC images (ρ = 0.92, 0.87, and 0.91 for MDW, MDC, and MSI, respectively; p < 0.001 for all pairs). Among the three VNC images, coronary calcium from MDW correlated best with that from TNC. The coronary artery calcium scores and volumes were significantly lower from the VNC images than from the TNC images (p < 0.001 for all pairs). The use of VNC images from contrast-enhanced CT using dual-energy material decomposition/suppression is feasible for coronary calcium scoring. The absolute value from VNC tends to be smaller than that from TNC

  16. Virtual non-contrast CT using dual energy spectral CT: Feasibility of coronary artery calcium scoring

    Energy Technology Data Exchange (ETDEWEB)

    Song, In Young; Yi, Jeong Geun; Park, Jeong Hee [Dept. of Radiology, Konkuk University School of Medicine, Seoul (Korea, Republic of); Lee, Sung Mok; Lee, Kyung Soo; Chung, Myung Jin [Dept. of Radiology, Samsung Medical Center, Sungkyunkwan University School of Medicine, Seoul (Korea, Republic of)

    2016-06-15

    To evaluate the feasibility of coronary artery calcium scoring based on three virtual noncontrast-enhanced (VNC) images derived from single-source spectral dual-energy CT (DECT) as compared with true noncontrast-enhanced (TNC) images. This prospective study was conducted with the approval of our Institutional Review Board. Ninety-seven patients underwent noncontrast CT followed by contrast-enhanced chest CT using single-source spectral DECT. Iodine eliminated VNC images were reconstructed using two kinds of 2-material decomposition algorithms (material density iodine-water pair [MDW], material density iodine-calcium pair [MDC]) and a material suppressed algorithm (material suppressed iodine [MSI]). Two readers independently quantified calcium on VNC and TNC images. The Spearman correlation coefficient test and Bland-Altman method were used for statistical analyses. Coronary artery calcium scores from all three VNC images showed excellent correlation with those from the TNC images (Spearman's correlation coefficient [ρ] = 0.94, 0.88, and 0.89 for MDW, MDC, and MSI, respectively; p < 0.001 for all pairs). Measured coronary calcium volumes from VNC images also correlated well with those from TNC images (ρ = 0.92, 0.87, and 0.91 for MDW, MDC, and MSI, respectively; p < 0.001 for all pairs). Among the three VNC images, coronary calcium from MDW correlated best with that from TNC. The coronary artery calcium scores and volumes were significantly lower from the VNC images than from the TNC images (p < 0.001 for all pairs). The use of VNC images from contrast-enhanced CT using dual-energy material decomposition/suppression is feasible for coronary calcium scoring. The absolute value from VNC tends to be smaller than that from TNC.

  17. Multiple-octave spanning high-energy mid-IR supercontinuum generation in bulk quadratic nonlinear crystals

    DEFF Research Database (Denmark)

    Zhou, Binbin; Bache, Morten

    2016-01-01

    Bright and broadband coherent mid-IR radiation is important for exciting and probing molecular vibrations. Using cascaded nonlinearities in conventional quadratic nonlinear crystals like lithium niobate, self-defocusing near-IR solitons have been demonstrated that led to very broadband...

  18. Differentiation of urinary calculi with dual energy CT: effect of spectral shaping by high energy tin filtration.

    Science.gov (United States)

    Thomas, Christoph; Krauss, Bernhard; Ketelsen, Dominik; Tsiflikas, Ilias; Reimann, Anja; Werner, Matthias; Schilling, David; Hennenlotter, Jörg; Claussen, Claus D; Schlemmer, Heinz-Peter; Heuschmid, Martin

    2010-07-01

    In dual energy (DE) computed tomography (CT), spectral shaping by additional filtration of the high energy spectrum can theoretically improve dual energy contrast. The aim of this in vitro study was to examine the influence of an additional tin filter for the differentiation of human urinary calculi by dual energy CT. A total of 36 pure human urinary calculi (uric acid, cystine, calciumoxalate monohydrate, calciumoxalate dihydrate, carbonatapatite, brushite, average diameter 10.5 mm) were placed in a phantom and imaged with 2 dual source CT scanners. One scanner was equipped with an additional tin (Sn) filter. Different combinations of tube voltages (140/80 kV, 140/100 kV, Sn140/100 kV, Sn140/80 kV, with Sn140 referring to 140 kV with the tin filter) were applied. Tube currents were adapted to yield comparable dose indices. Low- and high energy images were reconstructed. The calculi were segmented semiautomatically in the datasets and DE ratios (attenuation@low_kV/attenuation@high_kV) and were calculated for each calculus. DE contrasts (DE-ratio_material1/DE-ratio_material2) were computed for uric acid, cystine and calcified calculi and compared between the combinations of tube voltages. Using exclusively DE ratios, all uric acid, cystine and calcified calculi (as a group) could be differentiated in all protocols; the calcified calculi could not be differentiated among each other in any examination protocol. The highest DE ratios and DE contrasts were measured for the Sn140/80 protocol (53%-62% higher DE contrast than in the 140/80 kV protocol without additional filtration). The DE ratios and DE contrasts of the 80/140 kV and 100/Sn140 kV protocols were comparable. Uric acid, cystine and calcified calculi could be reliably differentiated by any of the protocols. A dose-neutral gain of DE contrast was found in the Sn-filter protocols, which might improve the differentiation of smaller calculi (Sn140/80 kV) and improve image quality and calculi differentiation in

  19. Spectral-Efficiency - Illumination Pareto Front for Energy Harvesting Enabled VLC System

    KAUST Repository

    Abdelhady, Amr Mohamed Abdelaziz

    2017-12-13

    The continuous improvement in optical energy harvesting devices motivates visible light communication (VLC) system developers to utilize such available free energy sources. An outdoor VLC system is considered where an optical base station sends data to multiple users that are capable of harvesting the optical energy. The proposed VLC system serves multiple users using time division multiple access (TDMA) with unequal time and power allocation, which are allocated to improve the system performance. The adopted optical system provides users with illumination and data communication services. The outdoor optical design objective is to maximize the illumination, while the communication design objective is to maximize the spectral efficiency (SE). The design objectives are shown to be conflicting, therefore, a multiobjective optimization problem is formulated to obtain the Pareto front performance curve for the proposed system. To this end, the marginal optimization problems are solved first using low complexity algorithms. Then, based on the proposed algorithms, a low complexity algorithm is developed to obtain an inner bound of the Pareto front for the illumination-SE tradeoff. The inner bound for the Pareto-front is shown to be close to the optimal Pareto-frontier via several simulation scenarios for different system parameters.

  20. Solution Structures of Highly Active Molecular Ir Water-Oxidation Catalysts from Density Functional Theory Combined with High-Energy X-ray Scattering and EXAFS Spectroscopy.

    Science.gov (United States)

    Yang, Ke R; Matula, Adam J; Kwon, Gihan; Hong, Jiyun; Sheehan, Stafford W; Thomsen, Julianne M; Brudvig, Gary W; Crabtree, Robert H; Tiede, David M; Chen, Lin X; Batista, Victor S

    2016-05-04

    The solution structures of highly active Ir water-oxidation catalysts are elucidated by combining density functional theory, high-energy X-ray scattering (HEXS), and extended X-ray absorption fine structure (EXAFS) spectroscopy. We find that the catalysts are Ir dimers with mono-μ-O cores and terminal anionic ligands, generated in situ through partial oxidation of a common catalyst precursor. The proposed structures are supported by (1)H and (17)O NMR, EPR, resonance Raman and UV-vis spectra, electrophoresis, etc. Our findings are particularly valuable to understand the mechanism of water oxidation by highly reactive Ir catalysts. Importantly, our DFT-EXAFS-HEXS methodology provides a new in situ technique for characterization of active species in catalytic systems.

  1. Spectral heterogeneity and carotenoid-to-bacteriochlorophyll energy transfer in LH2 light-harvesting complexes from Allochromatium vinosum.

    Science.gov (United States)

    Magdaong, Nikki M; LaFountain, Amy M; Hacking, Kirsty; Niedzwiedzki, Dariusz M; Gibson, George N; Cogdell, Richard J; Frank, Harry A

    2016-02-01

    Photosynthetic organisms produce a vast array of spectral forms of antenna pigment-protein complexes to harvest solar energy and also to adapt to growth under the variable environmental conditions of light intensity, temperature, and nutrient availability. This behavior is exemplified by Allochromatium (Alc.) vinosum, a photosynthetic purple sulfur bacterium that produces different types of LH2 light-harvesting complexes in response to variations in growth conditions. In the present work, three different spectral forms of LH2 from Alc. vinosum, B800-820, B800-840, and B800-850, were isolated, purified, and examined using steady-state absorption and fluorescence spectroscopy, and ultrafast time-resolved absorption spectroscopy. The pigment composition of the LH2 complexes was analyzed by high-performance liquid chromatography, and all were found to contain five carotenoids: lycopene, anhydrorhodovibrin, spirilloxanthin, rhodopin, and rhodovibrin. Spectral reconstructions of the absorption and fluorescence excitation spectra based on the pigment composition revealed significantly more spectral heterogeneity in these systems compared to LH2 complexes isolated from other species of purple bacteria. The data also revealed the individual carotenoid-to-bacteriochlorophyll energy transfer efficiencies which were correlated with the kinetic data from the ultrafast transient absorption spectroscopic experiments. This series of LH2 complexes allows a systematic exploration of the factors that determine the spectral properties of the bound pigments and control the rate and efficiency of carotenoid-to-bacteriochlorophyll energy transfer.

  2. Energy relaxation in IR laser excited Hg{sub 1-x}Cd{sub x}Te

    Energy Technology Data Exchange (ETDEWEB)

    Storebo, A K; Brudevoll, T [FFI - Norwegian Defence Research Establishment, PO Box 25, NO-2027 Kjeller, Norway NTNU (Norwegian University of Science and Technology) (Norway); Olsen, O; Norum, O C [Department of Physics and Department of Electronics and Telecommunications NO-7491 Trondheim (Norway); Breivik, M, E-mail: asta-katrine.storebo@ffi.n [Department of Electronics and Telecommunications NO-7491 Trondheim (Norway)

    2009-11-15

    IR laser excitation of Hg{sub l-x}Cd{sub x}Te by low-fluence femtosecond and high fluence microsecond pulses was explored for the technologically important alloy fractions x {approx} 0.2 and x {approx} 0.28. We have used first principles (LAPW) electronic structure calculations and finite element modelling, supported by Monte Carlo simulation for the description of femtosecond pulse carrier relaxation and the transport parameters. Laser wavelengths considered were 6.4 - 10.6 {mu}m for x {approx} 0.2 and 3.8 - 4.8 {mu}m for x {approx} 0.28, with an incident 1 microsecond pulse fluence of 2 J/cm{sup 2}. Many energy transfer mechanisms are invoked due to the long timescales of the microsecond pulses, and a main challenge is therefore to elucidate how these interplay in situations away from thermal equilibrium. Mechanisms studied include one- and two-photon absorption (OPA and TPA) across the band gap, inter-valence band absorption (IVA) between light- and heavy hole bands, electron-hole recombination/impact ionization, band gap renormalisation, intra-band free carrier absorption (FCA), excess carrier temperatures, non-equilibrium phonon generation, and refractive index changes. In the high fluence case, lattice temperatures evolve considerably during the laser pulse in response to the heated carriers. The chosen photon energies lie just above the band gap at the starting lattice temperature of 77 K, and nonlinear effects therefore dominate as the material heats up and the band gap begins to exceed the photon energy. Because of the low photon energy we must rely on Auger recombination, inter-valence band absorption and free carrier absorption to heat the carrier plasma. Although some Hg{sub l-x}Cd{sub x}Te material parameters are now relatively well known, existing data for many of the processes are inadequate for cases far away from thermal equilibrium. Furthermore, the role of Auger recombination in relation to non-intrinsic recombination has been a matter of debate

  3. Spectral and Energy Efficiencies in mmWave Cellular Networks for Optimal Utilization

    Directory of Open Access Journals (Sweden)

    Abdulbaset M. Hamed

    2018-01-01

    Full Text Available Millimeter wave (mmWave spectrum has been proposed for use in commercial cellular networks to relieve the already severely congested microwave spectrum. Thus, the design of an efficient mmWave cellular network has gained considerable importance and has to take into account regulations imposed by government agencies with regard to global warming and sustainable development. In this paper, a dense mmWave hexagonal cellular network with each cell consisting of a number of smaller cells with their own Base Stations (BSs is presented as a solution to meet the increasing demand for a variety of high data rate services and growing number of users of cellular networks. Since spectrum and power are critical resources in the design of such a network, a framework is presented that addresses efficient utilization of these resources in mmWave cellular networks in the 28 and 73 GHz bands. These bands are already an integral part of well-known standards such as IEEE 802.15.3c, IEEE 802.11ad, and IEEE 802.16.1. In the analysis, a well-known accurate mmWave channel model for Line of Sight (LOS and Non-Line of Sight (NLOS links is used. The cellular network is analyzed in terms of spectral efficiency, bit/s, energy efficiency, bit/J, area spectral efficiency, bit/s/m2, area energy efficiency, bit/J/m2, and network latency, s/bit. These efficiency metrics are illustrated, using Monte Carlo simulation, as a function of Signal-to-Noise Ratio (SNR, channel model parameters, user distance from BS, and BS transmission power. The efficiency metrics for optimum deployment of cellular networks in 28 and 73 GHz bands are identified. Results show that 73 GHz band achieves better spectrum efficiency and the 28 GHz band is superior in terms of energy efficiency. It is observed that while the latter band is expedient for indoor networks, the former band is appropriate for outdoor networks.

  4. FERMI LARGE AREA TELESCOPE OBSERVATIONS OF MARKARIAN 421: THE MISSING PIECE OF ITS SPECTRAL ENERGY DISTRIBUTION

    International Nuclear Information System (INIS)

    Abdo, A. A.; Ackermann, M.; Ajello, M.; Bechtol, K.; Berenji, B.; Blandford, R. D.; Bloom, E. D.; Borgland, A. W.; Buehler, R.; Baldini, L.; Bellazzini, R.; Bregeon, J.; Brez, A.; Ballet, J.; Barbiellini, G.; Bastieri, D.; Bonamente, E.; Bouvier, A.; Brigida, M.; Bruel, P.

    2011-01-01

    We report on the γ-ray activity of the high-synchrotron-peaked BL Lacertae object Markarian 421 (Mrk 421) during the first 1.5 years of Fermi operation, from 2008 August 5 to 2010 March 12. We find that the Large Area Telescope (LAT) γ-ray spectrum above 0.3 GeV can be well described by a power-law function with photon index Γ = 1.78 ± 0.02 and average photon flux F(> 0.3 GeV) = (7.23 ± 0.16) x 10 -8 ph cm -2 s -1 . Over this time period, the Fermi-LAT spectrum above 0.3 GeV was evaluated on seven-day-long time intervals, showing significant variations in the photon flux (up to a factor ∼3 from the minimum to the maximum flux) but mild spectral variations. The variability amplitude at X-ray frequencies measured by RXTE/ASM and Swift/BAT is substantially larger than that in γ-rays measured by Fermi-LAT, and these two energy ranges are not significantly correlated. We also present the first results from the 4.5 month long multifrequency campaign on Mrk 421, which included the VLBA, Swift, RXTE, MAGIC, the F-GAMMA, GASP-WEBT, and other collaborations and instruments that provided excellent temporal and energy coverage of the source throughout the entire campaign (2009 January 19 to 2009 June 1). During this campaign, Mrk 421 showed a low activity at all wavebands. The extensive multi-instrument (radio to TeV) data set provides an unprecedented, complete look at the quiescent spectral energy distribution (SED) for this source. The broadband SED was reproduced with a leptonic (one-zone synchrotron self-Compton) and a hadronic model (synchrotron proton blazar). Both frameworks are able to describe the average SED reasonably well, implying comparable jet powers but very different characteristics for the blazar emission site.

  5. A spectral chart method for estimating the mean turbulent kinetic energy dissipation rate

    Energy Technology Data Exchange (ETDEWEB)

    Djenidi, L.; Antonia, R.A. [The University of Newcastle, School of Engineering, Newcastle, NSW (Australia)

    2012-10-15

    We present an empirical but simple and practical spectral chart method for determining the mean turbulent kinetic energy dissipation rate left angle {epsilon}right angle in a variety of turbulent flows. The method relies on the validity of the first similarity hypothesis of Kolmogorov (C R (Doklady) Acad Sci R R SS, NS 30:301-305, 1941) (or K41) which implies that spectra of velocity fluctuations scale on the kinematic viscosity {nu} and left angle {epsilon}right angle at large Reynolds numbers. However, the evidence, based on the DNS spectra, points to this scaling being also valid at small Reynolds numbers, provided effects due to inhomogeneities in the flow are negligible. The methods avoid the difficulty associated with estimating time or spatial derivatives of the velocity fluctuations. It also avoids using the second hypothesis of K41, which implies the existence of a -5/3 inertial subrange only when the Taylor microscale Reynolds number R{sub {lambda}} is sufficiently large. The method is in fact applied to the lower wavenumber end of the dissipative range thus avoiding most of the problems due to inadequate spatial resolution of the velocity sensors and noise associated with the higher wavenumber end of this range.The use of spectral data (30 {<=} R{sub {lambda}}{<=} 400) in both passive and active grid turbulence, a turbulent mixing layer and the turbulent wake of a circular cylinder indicates that the method is robust and should lead to reliable estimates of left angle {epsilon}right angle in flows or flow regions where the first similarity hypothesis should hold; this would exclude, for example, the region near a wall. (orig.)

  6. Optimized energy of spectral CT for infarct imaging: Experimental validation with human validation.

    Science.gov (United States)

    Sandfort, Veit; Palanisamy, Srikanth; Symons, Rolf; Pourmorteza, Amir; Ahlman, Mark A; Rice, Kelly; Thomas, Tom; Davies-Venn, Cynthia; Krauss, Bernhard; Kwan, Alan; Pandey, Ankur; Zimmerman, Stefan L; Bluemke, David A

    Late contrast enhancement visualizes myocardial infarction, but the contrast to noise ratio (CNR) is low using conventional CT. The aim of this study was to determine if spectral CT can improve imaging of myocardial infarction. A canine model of myocardial infarction was produced in 8 animals (90-min occlusion, reperfusion). Later, imaging was performed after contrast injection using CT at 90 kVp/150 kVpSn. The following reconstructions were evaluated: Single energy 90 kVp, mixed, iodine map, multiple monoenergetic conventional and monoenergetic noise optimized reconstructions. Regions of interest were measured in infarct and remote regions to calculate contrast to noise ratio (CNR) and Bhattacharya distance (a metric of the differentiation between regions). Blinded assessment of image quality was performed. The same reconstruction methods were applied to CT scans of four patients with known infarcts. For animal studies, the highest CNR for infarct vs. myocardium was achieved in the lowest keV (40 keV) VMo images (CNR 4.42, IQR 3.64-5.53), which was superior to 90 kVp, mixed and iodine map (p = 0.008, p = 0.002, p energy in conjunction with noise-optimized monoenergetic post-processing improves CNR of myocardial infarct delineation by approximately 20-25%. Published by Elsevier Inc.

  7. Spectral Energy Distribution and Radio Halo of NGC 253 at Low Radio Frequencies

    Energy Technology Data Exchange (ETDEWEB)

    Kapińska, A. D.; Staveley-Smith, L.; Meurer, G. R.; For, B.-Q. [International Centre for Radio Astronomy Research (ICRAR), University of Western Australia, 35 Stirling Hwy, WA 6009 (Australia); Crocker, R. [Research School of Astronomy and Astrophysics, Australian National University, Canberra, ACT 2611 (Australia); Bhandari, S.; Callingham, J. R.; Gaensler, B. M.; Hancock, P. J.; Lenc, E. [ARC Centre of Excellence for All-Sky Astrophysics (CAASTRO), Sydney NSW (Australia); Hurley-Walker, N.; Seymour, N. [International Centre for Radio Astronomy Research (ICRAR), Curtin University, Bentley, WA 6102 (Australia); Offringa, A. R. [Netherlands Institute for Radio Astronomy (ASTRON), P.O. Box 2, 7990 AA Dwingeloo (Netherlands); Hanish, D. J. [Spitzer Science Center, California Institute of Technology, MC 220-6, 1200 East California Boulevard, Pasadena, CA 91125 (United States); Ekers, R. D.; Bell, M. E. [CSIRO Astronomy and Space Science (CASS), P.O. Box 76, Epping, NSW 1710 (Australia); Dwarakanath, K. S. [Raman Research Institute, Bangalore 560080 (India); Hindson, L. [Centre of Astrophysics Research, University of Hertfordshire, College Lane, Hatfield AL10 9AB (United Kingdom); Johnston-Hollitt, M. [School of Chemical and Physical Sciences, Victoria University of Wellington, P.O. Box 600, Wellington 6140 (New Zealand); McKinley, B., E-mail: anna.kapinska@uwa.edu.au [School of Physics, The University of Melbourne, Parkville, VIC 3010 (Australia); and others

    2017-03-20

    We present new radio continuum observations of NGC 253 from the Murchison Widefield Array at frequencies between 76 and 227 MHz. We model the broadband radio spectral energy distribution for the total flux density of NGC 253 between 76 MHz and 11 GHz. The spectrum is best described as a sum of a central starburst and extended emission. The central component, corresponding to the inner 500 pc of the starburst region of the galaxy, is best modeled as an internally free–free absorbed synchrotron plasma, with a turnover frequency around 230 MHz. The extended emission component of the spectrum of NGC 253 is best described as a synchrotron emission flattening at low radio frequencies. We find that 34% of the extended emission (outside the central starburst region) at 1 GHz becomes partially absorbed at low radio frequencies. Most of this flattening occurs in the western region of the southeast halo, and may be indicative of synchrotron self-absorption of shock-reaccelerated electrons or an intrinsic low-energy cutoff of the electron distribution. Furthermore, we detect the large-scale synchrotron radio halo of NGC 253 in our radio images. At 154–231 MHz the halo displays the well known X-shaped/horn-like structure, and extends out to ∼8 kpc in the z -direction (from the major axis).

  8. Area Spectral Efficiency and Energy Efficiency Tradeoff in Ultradense Heterogeneous Networks

    Directory of Open Access Journals (Sweden)

    Lanhua Xiang

    2017-01-01

    Full Text Available In order to meet the demand of explosive data traffic, ultradense base station (BS deployment in heterogeneous networks (HetNets as a key technique in 5G has been proposed. However, with the increment of BSs, the total energy consumption will also increase. So, the energy efficiency (EE has become a focal point in ultradense HetNets. In this paper, we take the area spectral efficiency (ASE into consideration and focus on the tradeoff between the ASE and EE in an ultradense HetNet. The distributions of BSs in the two-tier ultradense HetNet are modeled by two independent Poisson point processes (PPPs and the expressions of ASE and EE are derived by using the stochastic geometry tool. The tradeoff between the ASE and EE is formulated as a constrained optimization problem in which the EE is maximized under the ASE constraint, through optimizing the BS densities. It is difficult to solve the optimization problem analytically, because the closed-form expressions of ASE and EE are not easily obtained. Therefore, simulations are conducted to find optimal BS densities.

  9. CANDELS: CORRELATIONS OF SPECTRAL ENERGY DISTRIBUTIONS AND MORPHOLOGIES WITH STAR FORMATION STATUS FOR MASSIVE GALAXIES AT z {approx} 2

    Energy Technology Data Exchange (ETDEWEB)

    Wang Tao; Gu Qiusheng [School of Astronomy and Space Science, Nanjing University, Nanjing 210093 (China); Huang Jiasheng; Fang Guanwen; Fazio, G. G. [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States); Faber, S. M.; McGrath, Elizabeth J.; Kocevski, Dale [University of California Observatories/Lick Observatory, University of California, Santa Cruz, CA 95064 (United States); Wuyts, Stijn [Max-Planck-Institut fuer Extraterrestrische Physik, Giessenbachstrasse, 85748 Garching (Germany); Yan Haojing [Department of Physics and Astronomy, University of Missouri, Columbia, MO 65211 (United States); Dekel, Avishai [Racah Institute of Physics, The Hebrew University, Jerusalem 91904 (Israel); Guo Yicheng [Astronomy Department, University of Massachusetts, 710 N. Pleasant Street, Amherst, MA 01003 (United States); Ferguson, Henry C.; Grogin, Norman; Lotz, Jennifer M.; Lucas, Ray A.; Koekemoer, A. M. [Space Telescope Science Institute, 3700 San Martin Dr., Baltimore, MD 21218 (United States); Weiner, Benjamin [Steward Observatory, University of Arizona, 933 North Cherry Avenue, Tucson, AZ 85721 (United States); Hathi, Nimish P. [Carnegie Observatories, 813 Santa Barbara Street, Pasadena, CA 91101 (United States); Kong Xu, E-mail: taowang@nju.edu.cn [Center for Astrophysics, University of Science and Technology of China, Hefei 230026 (China)

    2012-06-20

    We present a study on spectral energy distributions, morphologies, and star formation for an IRAC-selected extremely red object sample in the GOODS Chandra Deep Field-South. This work was enabled by new HST/WFC3 near-IR imaging from the CANDELS survey as well as the deepest available X-ray data from Chandra 4 Ms observations. This sample consists of 133 objects with the 3.6 {mu}m limiting magnitude of [3.6] = 21.5 and is approximately complete for galaxies with M{sub *} > 10{sup 11} M{sub Sun} at 1.5 {<=} z {<=} 2.5. We classify this sample into two types, quiescent and star-forming galaxies (SFGs), in the observed infrared color-color ([3.6]-[24] versus K - [3.6]) diagram. The further morphological study of this sample shows a consistent result with the observed color classification. The classified quiescent galaxies are bulge dominated and SFGs in the sample have disk or irregular morphologies. Our observed infrared color classification is also consistent with the rest-frame color (U - V versus V - J) classification. We also found that quiescent and SFGs are well separated in the nonparametric morphology parameter (Gini versus M{sub 20}) diagram measuring their concentration and clumpiness: quiescent galaxies have a Gini coefficient higher than 0.58 and SFGs have a Gini coefficient lower than 0.58. We argue that the star formation quenching process must lead to or be accompanied by the increasing galaxy concentration. One prominent morphological feature of this sample is that disks are commonly seen in this massive galaxy sample at 1.5 {<=} z {<=} 2.5: 30% of quiescent galaxies and 70% of SFGs with M{sub *} > 10{sup 11} M{sub Sun} have disks in their rest-frame optical morphologies. The prevalence of these extended, relatively undisturbed disks challenges the merging scenario as the main mode of massive galaxy formation.

  10. The influence of compressibility on nonlinear spectral energy transfer - Part 2: Effect on hypersonic boundary layer transition

    Science.gov (United States)

    Mittal, Ankita; Girimaji, Sharath

    2017-11-01

    We examine the effect of compressible spectral energy transfer in the nonlinear regime of transition to turbulence of hypersonic boundary layers. The nature of spectral energy transfer between perturbation modes is profoundly influenced by two compressibility mechanisms. First and foremost, the emergence of nonlinear pressure-dilatation mechanism leads to kinetic-internal energy exchange within the perturbation field. Such interchange is absent in incompressible flow as pressure merely reorients the perturbation amplitude vector while conserving kinetic energy. Secondly, the nature of triadic interactions also changes due to variability in density. In this work, we demonstrate that the efficiency of nonlinear spectral energy transfer is diminished in compressible boundary layers. Emergence of new perturbation modes or `broad-banding' of the perturbation field is significantly delayed in comparison to incompressible boundary layer undergoing transition. A significant amount of perturbation energy is transformed to internal energy and thus unavailable for `tripping' the flow into turbulent state. These factors profoundly change the nature of the nonlinear stage of transition in compressible boundary layer leading to delayed onset of full-fledged turbulence.

  11. The Renormalization-Group Method in the Problem on Calculation of the Spectral Energy Density of Fluid Turbulence

    Science.gov (United States)

    Teodorovich, E. V.

    2018-03-01

    In order to find the shape of energy spectrum within the framework of the model of stationary homogeneous isotropic turbulence, the renormalization-group equations, which reflect the Markovian nature of the mechanism of energy transfer along the wavenumber spectrum, are used in addition to the dimensional considerations and the energy balance equation. For the spectrum, the formula depends on three parameters, namely, the wavenumber, which determines the upper boundary of the range of the turbulent energy production, the spectral flux through this boundary, and the fluid kinematic viscosity.

  12. Resource allocation for phantom cellular networks: Energy efficiency vs spectral efficiency

    KAUST Repository

    Abdelhady, Amr Mohamed Abdelaziz; Amin, Osama; Alouini, Mohamed-Slim

    2016-01-01

    Multi-tier heterogeneous networks have become an essential constituent for next generation cellular networks. Mean-while, energy efficiency (EE) has been considered a critical design criterion along with the traditional spectral efficiency (SE) metric. In this context, we study power and spectrum allocation for the recently proposed two-tier network architecture known as phantom cellular networks. The optimization framework includes both EE and SE, where we propose an algorithm that finds the SE and EE resource allocation strategies for phantom cellular networks. Then, we compare the performance of both design strategies versus the number of users, and phantom cells share of the total number of available resource blocks. We aim to investigate the effect of some system parameters to achieve improved SE performance at a non-significant loss in EE performance, or vice versa. It was found that increasing phantom cells share of resource blocks decreases the SE performance loss due to EE optimization when compared with the optimized SE performance. © 2016 IEEE.

  13. CO Spectral Line Energy Distributions in Galactic Sources: Empirical Interpretation of Extragalactic Observations

    Energy Technology Data Exchange (ETDEWEB)

    Indriolo, Nick; Bergin, E. A. [Department of Astronomy, University of Michigan, 1085 S. University Avenue, Ann Arbor, MI 48109 (United States); Goicoechea, J. R.; Cernicharo, J. [Grupo de Astrofísica Molecular, Instituto de Ciencia de Materiales de Madrid (CSIC) E-28049 Madrid (Spain); Gerin, M.; Gusdorf, A. [LERMA, Observatoire de Paris, PSL Research University, CNRS, Sorbonne Universités, UPMC Univ. Paris 06, École normale supérieure, F-75005, Paris (France); Lis, D. C. [LERMA, Observatoire de Paris, PSL Research University, CNRS, Sorbonne Universités, UPMC Univ. Paris 06, F-75014, Paris (France); Schilke, P., E-mail: nindriolo@stsci.edu [I. Physikalisches Institut der Universität zu Köln, Zülpicher Str. 77, D-50937 Köln (Germany)

    2017-02-10

    The relative populations in rotational transitions of CO can be useful for inferring gas conditions and excitation mechanisms at work in the interstellar medium. We present CO emission lines from rotational transitions observed with Herschel /HIFI in the star-forming cores Orion S, Orion KL, Sgr B2(M), and W49N. Integrated line fluxes from these observations are combined with those from Herschel /PACS observations of the same sources to construct CO spectral line energy distributions (SLEDs) from 5≤ J{sub u} ≤ 48. These CO SLEDs are compared to those reported in other galaxies, with the intention of empirically determining which mechanisms dominate excitation in such systems. We find that CO SLEDs in Galactic star-forming cores cannot be used to reproduce those observed in other galaxies, although the discrepancies arise primarily as a result of beam filling factors. The much larger regions sampled by the Herschel beams at distances of several megaparsecs contain significant amounts of cooler gas, which dominate the extragalactic CO SLEDs, in contrast to observations of Galactic star-forming regions, which are focused specifically on cores containing primarily hot molecular gas.

  14. Energy Efficiency - Spectral Efficiency Trade-off: A Multiobjective Optimization Approach

    KAUST Repository

    Amin, Osama

    2015-04-23

    In this paper, we consider the resource allocation problem for energy efficiency (EE) - spectral efficiency (SE) trade-off. Unlike traditional research that uses the EE as an objective function and imposes constraints either on the SE or achievable rate, we propound a multiobjective optimization approach that can flexibly switch between the EE and SE functions or change the priority level of each function using a trade-off parameter. Our dynamic approach is more tractable than the conventional approaches and more convenient to realistic communication applications and scenarios. We prove that the multiobjective optimization of the EE and SE is equivalent to a simple problem that maximizes the achievable rate/SE and minimizes the total power consumption. Then we apply the generalized framework of the resource allocation for the EE-SE trade-off to optimally allocate the subcarriers’ power for orthogonal frequency division multiplexing (OFDM) with imperfect channel estimation. Finally, we use numerical results to discuss the choice of the trade-off parameter and study the effect of the estimation error, transmission power budget and channel-to-noise ratio on the multiobjective optimization.

  15. Resource allocation for phantom cellular networks: Energy efficiency vs spectral efficiency

    KAUST Repository

    Abdelhady, Amr M.

    2016-07-26

    Multi-tier heterogeneous networks have become an essential constituent for next generation cellular networks. Mean-while, energy efficiency (EE) has been considered a critical design criterion along with the traditional spectral efficiency (SE) metric. In this context, we study power and spectrum allocation for the recently proposed two-tier network architecture known as phantom cellular networks. The optimization framework includes both EE and SE, where we propose an algorithm that finds the SE and EE resource allocation strategies for phantom cellular networks. Then, we compare the performance of both design strategies versus the number of users, and phantom cells share of the total number of available resource blocks. We aim to investigate the effect of some system parameters to achieve improved SE performance at a non-significant loss in EE performance, or vice versa. It was found that increasing phantom cells share of resource blocks decreases the SE performance loss due to EE optimization when compared with the optimized SE performance. © 2016 IEEE.

  16. Modelling performance of a small array of Wave Energy Converters: Comparison of Spectral and Boussinesq models

    International Nuclear Information System (INIS)

    Greenwood, Charles; Christie, David; Venugopal, Vengatesan; Morrison, James; Vogler, Arne

    2016-01-01

    This paper presents results from numerical simulations of three Oscillating Wave Surge Converters (OWSC) using two different computational models, Boussinesq wave (BW) and Spectral wave (SW) of the commercial software suite MIKE. The simulation of a shallow water wave farm applies alternative methods for implementing a frequency dependent absorption in both the BW and SW models, where energy extraction is based on experimental data from a scaled Oyster device. The effects of including wave diffraction within the SW model is tested by using diffraction smoothing steps and various directional wave conditions. The results of this study reveal important information on the models realms of validity that is heavily dependent on the incident sea state and the removal of diffraction for the SW model. This yields an increase in simulation accuracy for far-field disturbances when diffraction is entirely removed. This highlights specific conditions where the BW and SW model may thrive but also regions where reduced performance is observed. The results presented in this paper have not been validated with real sea site wave device array performance, however, the methodology described would be useful to device developers to arrive at preliminary decisions on array configurations and to minimise negative environmental impacts.

  17. SURVEY DESIGN FOR SPECTRAL ENERGY DISTRIBUTION FITTING: A FISHER MATRIX APPROACH

    International Nuclear Information System (INIS)

    Acquaviva, Viviana; Gawiser, Eric; Bickerton, Steven J.; Grogin, Norman A.; Guo Yicheng; Lee, Seong-Kook

    2012-01-01

    The spectral energy distribution (SED) of a galaxy contains information on the galaxy's physical properties, and multi-wavelength observations are needed in order to measure these properties via SED fitting. In planning these surveys, optimization of the resources is essential. The Fisher Matrix (FM) formalism can be used to quickly determine the best possible experimental setup to achieve the desired constraints on the SED-fitting parameters. However, because it relies on the assumption of a Gaussian likelihood function, it is in general less accurate than other slower techniques that reconstruct the probability distribution function (PDF) from the direct comparison between models and data. We compare the uncertainties on SED-fitting parameters predicted by the FM to the ones obtained using the more thorough PDF-fitting techniques. We use both simulated spectra and real data, and consider a large variety of target galaxies differing in redshift, mass, age, star formation history, dust content, and wavelength coverage. We find that the uncertainties reported by the two methods agree within a factor of two in the vast majority (∼90%) of cases. If the age determination is uncertain, the top-hat prior in age used in PDF fitting to prevent each galaxy from being older than the universe needs to be incorporated in the FM, at least approximately, before the two methods can be properly compared. We conclude that the FM is a useful tool for astronomical survey design.

  18. Energy Efficiency - Spectral Efficiency Trade-off: A Multiobjective Optimization Approach

    KAUST Repository

    Amin, Osama; Bedeer, Ebrahim; Ahmed, Mohamed; Dobre, Octavia

    2015-01-01

    In this paper, we consider the resource allocation problem for energy efficiency (EE) - spectral efficiency (SE) trade-off. Unlike traditional research that uses the EE as an objective function and imposes constraints either on the SE or achievable rate, we propound a multiobjective optimization approach that can flexibly switch between the EE and SE functions or change the priority level of each function using a trade-off parameter. Our dynamic approach is more tractable than the conventional approaches and more convenient to realistic communication applications and scenarios. We prove that the multiobjective optimization of the EE and SE is equivalent to a simple problem that maximizes the achievable rate/SE and minimizes the total power consumption. Then we apply the generalized framework of the resource allocation for the EE-SE trade-off to optimally allocate the subcarriers’ power for orthogonal frequency division multiplexing (OFDM) with imperfect channel estimation. Finally, we use numerical results to discuss the choice of the trade-off parameter and study the effect of the estimation error, transmission power budget and channel-to-noise ratio on the multiobjective optimization.

  19. A novel approach for characterizing broad-band radio spectral energy distributions

    Science.gov (United States)

    Harvey, V. M.; Franzen, T.; Morgan, J.; Seymour, N.

    2018-05-01

    We present a new broad-band radio frequency catalogue across 0.12 GHz ≤ ν ≤ 20 GHz created by combining data from the Murchison Widefield Array Commissioning Survey, the Australia Telescope 20 GHz survey, and the literature. Our catalogue consists of 1285 sources limited by S20 GHz > 40 mJy at 5σ, and contains flux density measurements (or estimates) and uncertainties at 0.074, 0.080, 0.119, 0.150, 0.180, 0.408, 0.843, 1.4, 4.8, 8.6, and 20 GHz. We fit a second-order polynomial in log-log space to the spectral energy distributions of all these sources in order to characterize their broad-band emission. For the 994 sources that are well described by a linear or quadratic model we present a new diagnostic plot arranging sources by the linear and curvature terms. We demonstrate the advantages of such a plot over the traditional radio colour-colour diagram. We also present astrophysical descriptions of the sources found in each segment of this new parameter space and discuss the utility of these plots in the upcoming era of large area, deep, broad-band radio surveys.

  20. HERSCHEL OBSERVATIONS AND UPDATED SPECTRAL ENERGY DISTRIBUTIONS OF FIVE SUNLIKE STARS WITH DEBRIS DISKS

    International Nuclear Information System (INIS)

    Dodson-Robinson, Sarah E.; Su, Kate Y. L.; Bryden, Geoff; Harvey, Paul; Green, Joel D.

    2016-01-01

    Observations from the Herschel Space Observatory have more than doubled the number of wide debris disks orbiting Sunlike stars to include over 30 systems with R  > 100 AU. Here, we present new Herschel PACS and reanalyzed Spitzer MIPS photometry of five Sunlike stars with wide debris disks, from Kuiper Belt size to R  > 150 AU. The disk surrounding HD 105211 is well resolved, with an angular extent of >14″ along the major axis, and the disks of HD 33636, HD 50554, and HD 52265 are extended beyond the PACS point-spread function size (50% of energy enclosed within radius 4.″23). HD 105211 also has a 24 μ m infrared excess, which was previously overlooked, because of a poorly constrained photospheric model. Archival Spitzer IRS observations indicate that the disks have small grains of minimum radius a min  ∼ 3 μ m, although a min is larger than the radiation-pressure blowout size in all systems. If modeled as single-temperature blackbodies, the disk temperatures would all be <60 K. Our radiative transfer models predict actual disk radii approximately twice the radius of a model blackbody disk. We find that the Herschel photometry traces dust near the source population of planetesimals. The disk luminosities are in the range 2 × 10 −5  ⩽  L / L ⊙  ⩽ 2 × 10 −4 , consistent with collisions in icy planetesimal belts stirred by Pluto-size dwarf planets.

  1. HERSCHEL OBSERVATIONS AND UPDATED SPECTRAL ENERGY DISTRIBUTIONS OF FIVE SUNLIKE STARS WITH DEBRIS DISKS

    Energy Technology Data Exchange (ETDEWEB)

    Dodson-Robinson, Sarah E. [Department of Physics and Astronomy, University of Delaware, 217 Sharp Lab, Newark, DE 19716 (United States); Su, Kate Y. L. [Steward Observatory, Department of Astronomy, University of Arizona, 933 North Cherry Avenue, Tucson, AZ 85721 (United States); Bryden, Geoff [Jet Propulsion Laboratory, California Institute of Technology, 4800 Oak Grove Drive, Pasadena, CA 91109 (United States); Harvey, Paul; Green, Joel D., E-mail: sdr@udel.edu [Astronomy Department, University of Texas, 2515 Speedway Drive C1400, Austin, TX 78712 (United States)

    2016-12-20

    Observations from the Herschel Space Observatory have more than doubled the number of wide debris disks orbiting Sunlike stars to include over 30 systems with R  > 100 AU. Here, we present new Herschel PACS and reanalyzed Spitzer MIPS photometry of five Sunlike stars with wide debris disks, from Kuiper Belt size to R  > 150 AU. The disk surrounding HD 105211 is well resolved, with an angular extent of >14″ along the major axis, and the disks of HD 33636, HD 50554, and HD 52265 are extended beyond the PACS point-spread function size (50% of energy enclosed within radius 4.″23). HD 105211 also has a 24 μ m infrared excess, which was previously overlooked, because of a poorly constrained photospheric model. Archival Spitzer IRS observations indicate that the disks have small grains of minimum radius a {sub min} ∼ 3 μ m, although a {sub min} is larger than the radiation-pressure blowout size in all systems. If modeled as single-temperature blackbodies, the disk temperatures would all be <60 K. Our radiative transfer models predict actual disk radii approximately twice the radius of a model blackbody disk. We find that the Herschel photometry traces dust near the source population of planetesimals. The disk luminosities are in the range 2 × 10{sup −5} ⩽  L / L {sub ⊙} ⩽ 2 × 10{sup −4}, consistent with collisions in icy planetesimal belts stirred by Pluto-size dwarf planets.

  2. Spectral Modeling of Residual Stress and Stored Elastic Strain Energy in Thermal Barrier Coatings

    Energy Technology Data Exchange (ETDEWEB)

    Donegan, Sean; Rolett, Anthony

    2013-12-31

    Solutions to the thermoelastic problem are important for characterizing the response under temperature change of refractory systems. This work extends a spectral fast Fourier transform (FFT) technique to analyze the thermoelastic behavior of thermal barrier coatings (TBCs), with the intent of probing the local origins of failure in TBCs. The thermoelastic FFT (teFFT) approach allows for the characterization of local thermal residual stress and strain fields, which constitute the origins of failure in TBC systems. A technique based on statistical extreme value theory known as peaks-over-threshold (POT) is developed to quantify the extreme values ("hot spots") of stored elastic strain energy (i.e., elastic energy density, or EED). The resolution dependence of the teFFT method is assessed through a sensitivity study of the extreme values in EED. The sensitivity study is performed both for the local (point-by-point) eld distributions as well as the grain scale eld distributions. A convergence behavior to a particular distribution shape is demonstrated for the local elds. The grain scale fields are shown to exhibit a possible convergence to a maximum level of EED. To apply the teFFT method to TBC systems, 3D synthetic microstructures are created to approximate actual TBC microstructures. The morphology of the grains in each constituent layer as well as the texture is controlled. A variety of TBC materials, including industry standard materials and potential future materials, are analyzed using the teFFT. The resulting hot spots are quantified using the POT approach. A correlation between hot spots in EED and interface rumpling between constituent layers is demonstrated, particularly for the interface between the bond coat (BC) and the thermally grown oxide (TGO) layer.

  3. Modelling the cosmic spectral energy distribution and extragalactic background light over all time

    Science.gov (United States)

    Andrews, S. K.; Driver, S. P.; Davies, L. J. M.; Lagos, C. d. P.; Robotham, A. S. G.

    2018-02-01

    We present a phenomological model of the cosmic spectral energy distribution (CSED) and the integrated galactic light (IGL) over all cosmic time. This model, based on an earlier model by Driver et al., attributes the cosmic star formation history (CSFH) to two processes - first, chaotic clump accretion and major mergers, resulting in the early-time formation of bulges and secondly, cold gas accretion, resulting in late-time disc formation. Under the assumption of a Universal Chabrier initial mass function, we combine the Bruzual & Charlot stellar libraries, the Charlot & Fall dust attenuation prescription and template spectra for emission by dust and active galactic nuclei to predict the CSED - pre- and post-dust attenuation - and the IGL throughout cosmic time. The phenomological model, as constructed, adopts a number of basic axioms and empirical results and has minimal free parameters. We compare the model output, as well as predictions from the semi-analytic model GALFORM to recent estimates of the CSED out to z = 1. By construction, our empirical model reproduces the full energy output of the Universe from the ultraviolet to the far-infrared extremely well. We use the model to derive predictions of the stellar and dust mass densities, again finding good agreement. We find that GALFORM predicts the CSED for z < 0.3 in good agreement with the observations. This agreement becomes increasingly poor towards z = 1, when the model CSED is ˜50 per cent fainter. The latter is consistent with the model underpredicting the CSFH. As a consequence, GALFORM predicts a ˜30 per cent fainter IGL.

  4. The radio spectral energy distribution of infrared-faint radio sources

    Science.gov (United States)

    Herzog, A.; Norris, R. P.; Middelberg, E.; Seymour, N.; Spitler, L. R.; Emonts, B. H. C.; Franzen, T. M. O.; Hunstead, R.; Intema, H. T.; Marvil, J.; Parker, Q. A.; Sirothia, S. K.; Hurley-Walker, N.; Bell, M.; Bernardi, G.; Bowman, J. D.; Briggs, F.; Cappallo, R. J.; Callingham, J. R.; Deshpande, A. A.; Dwarakanath, K. S.; For, B.-Q.; Greenhill, L. J.; Hancock, P.; Hazelton, B. J.; Hindson, L.; Johnston-Hollitt, M.; Kapińska, A. D.; Kaplan, D. L.; Lenc, E.; Lonsdale, C. J.; McKinley, B.; McWhirter, S. R.; Mitchell, D. A.; Morales, M. F.; Morgan, E.; Morgan, J.; Oberoi, D.; Offringa, A.; Ord, S. M.; Prabu, T.; Procopio, P.; Udaya Shankar, N.; Srivani, K. S.; Staveley-Smith, L.; Subrahmanyan, R.; Tingay, S. J.; Wayth, R. B.; Webster, R. L.; Williams, A.; Williams, C. L.; Wu, C.; Zheng, Q.; Bannister, K. W.; Chippendale, A. P.; Harvey-Smith, L.; Heywood, I.; Indermuehle, B.; Popping, A.; Sault, R. J.; Whiting, M. T.

    2016-10-01

    Context. Infrared-faint radio sources (IFRS) are a class of radio-loud (RL) active galactic nuclei (AGN) at high redshifts (z ≥ 1.7) that are characterised by their relative infrared faintness, resulting in enormous radio-to-infrared flux density ratios of up to several thousand. Aims: Because of their optical and infrared faintness, it is very challenging to study IFRS at these wavelengths. However, IFRS are relatively bright in the radio regime with 1.4 GHz flux densities of a few to a few tens of mJy. Therefore, the radio regime is the most promising wavelength regime in which to constrain their nature. We aim to test the hypothesis that IFRS are young AGN, particularly GHz peaked-spectrum (GPS) and compact steep-spectrum (CSS) sources that have a low frequency turnover. Methods: We use the rich radio data set available for the Australia Telescope Large Area Survey fields, covering the frequency range between 150 MHz and 34 GHz with up to 19 wavebands from different telescopes, and build radio spectral energy distributions (SEDs) for 34 IFRS. We then study the radio properties of this class of object with respect to turnover, spectral index, and behaviour towards higher frequencies. We also present the highest-frequency radio observations of an IFRS, observed with the Plateau de Bure Interferometer at 105 GHz, and model the multi-wavelength and radio-far-infrared SED of this source. Results: We find IFRS usually follow single power laws down to observed frequencies of around 150 MHz. Mostly, the radio SEDs are steep (α IFRS show statistically significantly steeper radio SEDs than the broader RL AGN population. Our analysis reveals that the fractions of GPS and CSS sources in the population of IFRS are consistent with the fractions in the broader RL AGN population. We find that at least % of IFRS contain young AGN, although the fraction might be significantly higher as suggested by the steep SEDs and the compact morphology of IFRS. The detailed multi

  5. Mid-IR laser system for advanced neurosurgery

    Science.gov (United States)

    Klosner, M.; Wu, C.; Heller, D. F.

    2014-03-01

    We present work on a laser system operating in the near- and mid-IR spectral regions, having output characteristics designed to be optimal for cutting various tissue types. We provide a brief overview of laser-tissue interactions and the importance of controlling certain properties of the light beam. We describe the principle of operation of the laser system, which is generally based on a wavelength-tunable alexandrite laser oscillator/amplifier, and multiple Raman conversion stages. This configuration provides robust access to the mid-IR spectral region at wavelengths, pulse energies, pulse durations, and repetition rates that are attractive for neurosurgical applications. We summarize results for ultra-precise selective cutting of nerve sheaths and retinas with little collateral damage; this has applications in procedures such as optic-nerve-sheath fenestration and possible spinal repair. We also report results for cutting cornea, and dermal tissues.

  6. Determination of the electron-hole pair creation energy for semiconductors from the spectral responsivity of photodiodes

    CERN Document Server

    Scholze, F; Kuschnerus, P; Rabus, H; Richter, M; Ulm, G

    2000-01-01

    Ionizing radiation can be detected by the measurement of the charge carriers produced in a detector. The improved semiconductor technology now allows detectors operating near the physical limits of the detector materials to be designed. The mean energy required for producing an electron-hole pair, W, is a material property of the semiconductor. Here, the determination of W from the spectral responsivity of photodiodes is demonstrated. Using spectrally dispersed synchrotron radiation, different types of semiconductor photodiodes have been examined in the UV-, VUV-, and soft X-ray spectral range. Their spectral responsivity was determined with relative uncertainties between 0.4% and 1% using a cryogenic electrical-substitution radiometer as primary detector standard. Results are presented for silicon n-on-p junction photodiodes and for GaAsP/Au Schottky diodes at room temperature. The investigations for silicon covered the complete spectral range from 3 to 1500 eV, yielding a constant value W=(3.66+-0.03) eV fo...

  7. Dual-Energy Computed Tomography Gemstone Spectral Imaging: A Novel Technique to Determine Human Cardiac Calculus Composition.

    Science.gov (United States)

    Cheng, Ching-Li; Chang, Hsiao-Huang; Ko, Shih-Chi; Huang, Pei-Jung; Lin, Shan-Yang

    2016-01-01

    Understanding the chemical composition of any calculus in different human organs is essential for choosing the best treatment strategy for patients. The purpose of this study was to assess the capability of determining the chemical composition of a human cardiac calculus using gemstone spectral imaging (GSI) mode on a single-source dual-energy computed tomography (DECT) in vitro. The cardiac calculus was directly scanned on the Discovery CT750 HD FREEdom Edition using GSI mode, in vitro. A portable fiber-optic Raman spectroscopy was also applied to verify the quantitative accuracy of the DECT measurements. The results of spectral DECT measurements indicate that effective Z values in 3 designated positions located in this calculus were 15.02 to 15.47, which are close to values of 15.74 to 15.86, corresponding to the effective Z values of calcium apatite and hydroxyapatite. The Raman spectral data were also reflected by the predominant Raman peak at 960 cm for hydroxyapatite and the minor peak at 875 cm for calcium apatite. A potential single-source DECT with GSI mode was first used to examine the morphological characteristics and chemical compositions of a giant human cardiac calculus, in vitro. The CT results were consistent with the Raman spectral data, suggesting that spectral CT imaging techniques could be accurately used to diagnose and characterize the compositional materials in the cardiac calculus.

  8. A TALE OF TWO NARROW-LINE REGIONS: IONIZATION, KINEMATICS, AND SPECTRAL ENERGY DISTRIBUTIONS FOR A LOCAL PAIR OF MERGING OBSCURED ACTIVE GALAXIES

    Energy Technology Data Exchange (ETDEWEB)

    Hainline, Kevin N.; Hickox, Ryan C.; Chen, Chien-Ting; Carroll, Christopher M.; Jones, Mackenzie L.; Zervos, Alexandros S. [Department of Physics and Astronomy, Dartmouth College, Hanover, NH 03755 (United States); Goulding, Andrew D. [Department Astrophysical Sciences, Princeton University, Princeton, NJ 08544 (United States)

    2016-05-20

    We explore the gas ionization and kinematics, as well as the optical-IR spectral energy distributions for UGC 11185, a nearby pair of merging galaxies hosting obscured active galactic nuclei (AGNs), also known as SDSS J181611.72+423941.6 and J181609.37+423923.0 (J1816NE and J1816SW, z ≈ 0.04). Due to the wide separation between these interacting galaxies (∼23 kpc), observations of these objects provide a rare glimpse of the concurrent growth of supermassive black holes at an early merger stage. We use BPT line diagnostics to show that the full extent of the narrow-line emission in both galaxies is photoionized by an AGN, and confirm the existence of a 10 kpc-scale ionization cone in J1816NE, while in J1816SW the AGN narrow-line region is much more compact (1–2 kpc) and relatively undisturbed. Our observations also reveal the presence of ionized gas that nearly spans the entire distance between the galaxies, which is likely in a merger-induced tidal stream. In addition, we carry out a spectral analysis of the X-ray emission using data from XMM-Newton . These galaxies represent a useful pair to explore how the [O iii] luminosity of an AGN is dependent on the size of the region used to explore the extended emission. Given the growing evidence for AGN “flickering” over short timescales, we speculate that the appearances and impacts of these AGNs may change multiple times over the course of the galaxy merger, which is especially important given that these objects are likely the progenitors of the types of systems commonly classified as “dual AGNs.”.

  9. Broadly tunable picosecond ir source

    International Nuclear Information System (INIS)

    Campillo, A.J.; Hyer, R.C.; Shapiro, S.L.

    1979-01-01

    A completely grating tuned (1.9 to 2.4 μm) picosecond traveling wave IR generator capable of controlled spectral bandwidth operation down to the Fourier Transform limit is reported. Subsequent down conversion in CdSe extends tuning to 10 to 20 μm

  10. Revisiting the Correlations of Peak Luminosity with Spectral Lag and Peak Energy of the Observed Gamma-ray Bursts

    Directory of Open Access Journals (Sweden)

    Yun-A Jo

    2016-12-01

    Full Text Available An analysis of light curves and spectra of observed gamma-ray bursts in gamma-ray ranges is frequently demanded because the prompt emission contains immediate details regarding the central engine of gamma-ray bursts (GRBs. We have revisited the relationship between the collimation-corrected peak luminosity and the spectral lag, investigating the lag-luminosity relationships in great detail by focusing on spectral lags resulting from all possible combinations of channels. Firstly, we compiled the opening angle data and demonstrated that the distribution of opening angles of 205 long GRBs is represented by a double Gaussian function having maxima at ~ 0.1 and ~ 0.3 radians. We confirmed that the peak luminosity and the spectral lag are anti-correlated, both in the observer frame and in the source frame. We found that, in agreement with our previous conclusion, the correlation coefficient improves significantly in the source frame. It should be noted that spectral lags involving channel 2 (25-50 keV yield high correlation coefficients, where Swift/Burst Alert Telescope (BAT has four energy channels (channel 1: 15-25 keV, channel 2: 25-50 keV, channel 3: 50-100 keV, channel 4: 100-200 keV. We also found that peak luminosity is positively correlated with peak energy.

  11. Development of Neutron Energy Spectral Signatures for Passive Monitoring of Spent Nuclear Fuels in Dry Cask Storage

    Science.gov (United States)

    Harkness, Ira; Zhu, Ting; Liang, Yinong; Rauch, Eric; Enqvist, Andreas; Jordan, Kelly A.

    2018-01-01

    Demand for spent nuclear fuel dry casks as an interim storage solution has increased globally and the IAEA has expressed a need for robust safeguards and verification technologies for ensuring the continuity of knowledge and the integrity of radioactive materials inside spent fuel casks. Existing research has been focusing on "fingerprinting" casks based on count rate statistics to represent radiation emission signatures. The current research aims to expand to include neutron energy spectral information as part of the fuel characteristics. First, spent fuel composition data are taken from the Next Generation Safeguards Initiative Spent Fuel Libraries, representative for Westinghouse 17ˣ17 PWR assemblies. The ORIGEN-S code then calculates the spontaneous fission and (α,n) emissions for individual fuel rods, followed by detailed MCNP simulations of neutrons transported through the fuel assemblies. A comprehensive database of neutron energy spectral profiles is to be constructed, with different enrichment, burn-up, and cooling time conditions. The end goal is to utilize the computational spent fuel library, predictive algorithm, and a pressurized 4He scintillator to verify the spent fuel assemblies inside a cask. This work identifies neutron spectral signatures that correlate with the cooling time of spent fuel. Both the total and relative contributions from spontaneous fission and (α,n) change noticeably with respect to cooling time, due to the relatively short half-life (18 years) of the major neutron source 244Cm. Identification of this and other neutron spectral signatures allows the characterization of spent nuclear fuels in dry cask storage.

  12. Front Surface Tandem Filters using Sapphire (Al2O3) Substrates for Spectral Control in thermophotovoltaic Energy Conversion Systems

    International Nuclear Information System (INIS)

    T Rahmlow, Jr.; J Lazo-Wasem; E Gratrix; P Fourspring; D DePoy

    2005-01-01

    Front surface filters provide an effective means of improving thermophotovoltaic (TPV) system efficiency through spectral control of incident radiant energy. A front surface filter reflects the below band gap photons that can not be converted by the TPV cell back towards the high temperature radiator and allows convertible above band gap photons to pass through the filter into the TPV cell for conversion to electricity. The best spectral control efficiency to date has been demonstrated by front surface, tandem filters that combine an interference filter and an InPAs layer (plasma filter) in series. The InPAs material is a highly doped, epitaxially grown layer on an InP substrate. These tandem filter designs have been fabricated with energy and angle weighted spectral efficiencies of 76% for TPV cells with a 2.08(micro)m (0.6eV) band gap [1]. An alternative to the InPAs layer on an InP substrate is an Al 2 O 3 (sapphire) substrate. The use of Al 2 O 3 may increase transmission of above band gap photons, increase the mechanical strength of the tandem filter, and lower the cost of the tandem filter, all at the expense of lower spectral efficiency. This study presents design and fabrication results for front surface tandem filters that use an Al 2 O 3 substrate for 2.08(micro)m band gap TPV cells

  13. Global Infrared–Radio Spectral Energy Distributions of Galactic Massive Star-Forming Regions

    Science.gov (United States)

    Povich, Matthew Samuel; Binder, Breanna Arlene

    2018-01-01

    We present a multiwavelength study of 30 Galactic massive star-forming regions. We fit multicomponent dust, blackbody, and power-law continuum models to 3.6 µm through 10 mm spectral energy distributions obtained from Spitzer, MSX, IRAS, Herschel, and Planck archival survey data. Averaged across our sample, ~20% of Lyman continuum photons emitted by massive stars are absorbed by dust before contributing to the ionization of H II regions, while ~50% of the stellar bolometric luminosity is absorbed and reprocessed by dust in the H II regions and surrounding photodissociation regions. The most luminous, infrared-bright regions that fully sample the upper stellar initial mass function (ionizing photon rates NC ≥ 1050 s–1 and total infrared luminosity LTIR ≥ 106.8 L⊙) have higher percentages of absorbed Lyman continuum photons (~40%) and dust-reprocessed starlight (~80%). The monochromatic 70-µm luminosity L70 is linearly correlated with LTIR, and on average L70/LTIR = 50%, in good agreement with extragalactic studies. Calibrated against the known massive stellar content in our sampled H II regions, we find that star formation rates based on L70 are in reasonably good agreement with extragalactic calibrations, when corrected for the smaller physical sizes of the Galactic regions. We caution that absorption of Lyman continuum photons prior to contributing to the observed ionizing photon rate may reduce the attenuation-corrected Hα emission, systematically biasing extragalactic calibrations toward lower star formation rates when applied to spatially-resolved studies of obscured star formation.This work was supported by the National Science Foundation under award CAREER-1454333.

  14. Spectral energy distribution variations of nearby Seyfert galaxies during AGN watch monitoring programs

    Science.gov (United States)

    Kilerci Eser, Ece; Vestergaard, M.

    2018-02-01

    We present and analyse quasi-simultaneous multi-epoch spectral energy distributions (SEDs) of seven reverberation-mapped active galactic nuclei (AGNs) for which accurate black hole mass measurements and suitable archival data are available from the `AGN Watch' monitoring programs. We explore the potential of optical-UV and X-ray data, obtained within 2 d, to provide more accurate SED-based measurements of individual AGN and quantify the impact of source variability on key measurements typically used to characterize the black hole accretion process plus on bolometric correction factors at 5100 Å, 1350 Å and for the 2-10 keV X-ray band, respectively. The largest SED changes occur on long time-scales (≳1 year). For our small sample, the 1μm to 10 keV integrated accretion luminosity typically changes by 10 per cent on short time-scales (over 20 d), by ˜30 per cent over a year, but can change by 100 per cent or more for individual AGN. The extreme ultraviolet (EUV) gap is the most uncertain part of the intrinsic SED, introducing a ˜25 per cent uncertainty in the accretion-induced luminosity, relative to the model independent interpolation method that we adopt. That aside, our analysis shows that the uncertainty in the accretion-induced luminosity, the Eddington luminosity ratio and the bolometric correction factors can be reduced (by a factor of two or more) by use of the SEDs built from data obtained within 20 d. However, \\dot{M} and η are mostly limited by the unknown EUV emission and the unknown details of the central engine and our aspect angle.

  15. Spectral energy distribution analysis of class I and class II FU Orionis stars

    Energy Technology Data Exchange (ETDEWEB)

    Gramajo, Luciana V.; Gómez, Mercedes [Observatorio Astronómico, Universidad Nacional de Córdoba, Argentina, Laprida 854, 5000 Córdoba (Argentina); Rodón, Javier A., E-mail: luciana@oac.uncor.edu, E-mail: mercedes@oac.uncor.edu, E-mail: jrodon@eso.org [European Southern Observatory, Alonso de Córdova 3107, Vitacura, Casilla 19001, Santiago 19 (Chile)

    2014-06-01

    FU Orionis stars (FUors) are eruptive pre-main sequence objects thought to represent quasi-periodic or recurring stages of enhanced accretion during the low-mass star-forming process. We characterize the sample of known and candidate FUors in a homogeneous and consistent way, deriving stellar and circumstellar parameters for each object. We emphasize the analysis in those parameters that are supposed to vary during the FUor stage. We modeled the spectral energy distributions of 24 of the 26 currently known FUors, using the radiative transfer code of Whitney et al. We compare our models with those obtained by Robitaille et al. for Taurus class II and I sources in quiescence periods by calculating the cumulative distribution of the different parameters. FUors have more massive disks: we find that ∼80% of the disks in FUors are more massive than any Taurus class II and I sources in the sample. Median values for the disk mass accretion rates are ∼10{sup –7} M {sub ☉} yr{sup –1} versus ∼10{sup –5} M {sub ☉} yr{sup –1} for standard young stellar objects (YSOs) and FUors, respectively. While the distributions of envelope mass accretion rates for class I FUors and standard class I objects are similar, FUors, on average, have higher envelope mass accretion rates than standard class II and class I sources. Most FUors (∼70%) have envelope mass accretion rates above 10{sup –7} M {sub ☉} yr{sup –1}. In contrast, 60% of the classical YSO sample has an accretion rate below this value. Our results support the current scenario in which changes experimented by the circumstellar disk explain the observed properties of these stars. However, the increase in the disk mass accretion rate is smaller than theoretically predicted, although in good agreement with previous determinations.

  16. HerMES: Spectral energy distributions of submillimeter galaxies at z > 4

    International Nuclear Information System (INIS)

    Huang, J.-S.; Rigopoulou, D.; Magdis, G.; Rowan-Robinson, M.; Clements, D. L.; Dai, Y.; Fazio, G. G.; Bock, J. J.; Burgarella, D.; Chapman, S.; Cooray, A.; Farrah, D.; Glenn, J.; Oliver, S.; Smith, A. J.; Wang, L.; Page, M.; Symeonidis, M.; Riechers, D.; Roseboom, I.

    2014-01-01

    We present a study of the infrared properties for a sample of seven spectroscopically confirmed submillimeter galaxies (SMGs) at z > 4.0. By combining ground-based near-infrared, Spitzer IRAC and MIPS, Herschel SPIRE, and ground-based submillimeter/millimeter photometry, we construct their spectral energy distributions (SEDs) and a composite model to fit the SEDs. The model includes a stellar emission component at λ rest < 3.5 μm, a hot dust component peaking at λ rest ∼ 5 μm, and cold dust component which becomes significant for λ rest > 50 μm. Six objects in the sample are detected at 250 and 350 μm. The dust temperatures for the sources in this sample are in the range of 40-80 K, and their L FIR ∼ 10 13 L ☉ qualifies them as hyper-luminous infrared galaxies. The mean FIR-radio index for this sample is around (q) = 2.2 indicating no radio excess in their radio emission. Most sources in the sample have 24 μm detections corresponding to a rest-frame 4.5 μm luminosity of Log 10 (L 4.5 /L ☉ ) = 11 ∼ 11.5. Their L 4.5 /L FIR ratios are very similar to those of starburst-dominated SMGs at z ∼ 2. The L CO – L FIR relation for this sample is consistent with that determined for local ULIRGs and SMGs at z ∼ 2. We conclude that SMGs at z > 4 are hotter and more luminous in the FIR but otherwise very similar to those at z ∼ 2. None of these sources show any sign of the strong QSO phase being triggered.

  17. Semiconductor detectors in current energy dispersive X-ray spectral analysis

    Energy Technology Data Exchange (ETDEWEB)

    Betin, J; Zhabin, E; Krampit, I; Smirnov, V

    1980-04-01

    A review is presented of the properties of semiconductor detectors and of the possibilities stemming therefrom of using the detectors in X-ray spectral analysis in industries, in logging, in ecology and environmental control, in medicine, etc.

  18. Spectral-Efficiency - Illumination Pareto Front for Energy Harvesting Enabled VLC System

    KAUST Repository

    Abdelhady, Amr Mohamed Abdelaziz; Amin, Osama; Chaaban, Anas; Alouini, Mohamed-Slim

    2017-01-01

    . The adopted optical system provides users with illumination and data communication services. The outdoor optical design objective is to maximize the illumination, while the communication design objective is to maximize the spectral efficiency (SE). The design

  19. Spectral and energy efficiency analysis of uplink heterogeneous networks with small-cells on edge

    KAUST Repository

    Shakir, Muhammad Zeeshan; Tabassum, Hina; Qaraqe, Khalid A.; Serpedin, Erchin; Alouini, Mohamed-Slim

    2014-01-01

    by considering fast power control where the mobile users transmit with adaptive power to compensate the path loss, shadowing and fading. In particular, we develop a moment generating function (MGF) based approach to derive analytical bounds on the area spectral

  20. Synthesis, electronic structure investigation of 3-pentyl-2,6-di(furan-2-yl)piperidin-4-one by FT-IR, FT-Raman and UV-Visible spectral studies and ab initio/DFT calculations.

    Science.gov (United States)

    Arockia Doss, M; Savithiri, S; Rajarajan, G; Thanikachalam, V; Anbuselvan, C

    2015-12-05

    FT-IR and FT-Raman spectra of 3-pentyl-2,6-di(furan-2-yl) piperidin-4-one (3-PFPO) were recorded in the solid phase. The structural and spectroscopic analyses of 3-PFPO were made by using B3LYP/HF level with 6-311++G(d, p) basis set. The fundamental vibrations are assigned on the basis of the total energy distribution (TED) of the vibrational modes, calculated with scaled quantum mechanics (SQM) method and PQS program. Comparison of the observed fundamental vibrational frequencies of 3-PFPO with calculated results by HF and DFT methods indicates that B3LYP is superior to HF method for molecular vibrational problems. The electronic properties such as excitation energies, oscillator strength, wavelengths and HOMO-LUMO energies were obtained by time-dependent DFT (TD-DFT) approach. The polarizability and first order hyperpolarizability of the title molecule were calculated and interpreted. The hyperconjugative interaction energy (E((2))) and electron densities of donor (i) and acceptor (j) bonds were calculated using NBO analysis. In addition, MEP and atomic charges of carbon, nitrogen, oxygen and hydrogen were calculated using B3LYP/6-311++G(d, p) level theory. Moreover, thermodynamic properties (heat capacities, entropy and enthalpy) of the title compound at different temperatures were calculated in gas phase. Copyright © 2015 Elsevier B.V. All rights reserved.

  1. Upconversion applied for mid-IR hyperspectral image acquisition

    DEFF Research Database (Denmark)

    Tidemand-Lichtenberg, Peter; Kehlet, Louis Martinus; Sanders, Nicolai Højer

    2015-01-01

    Different schemes for upconversion mid-IR hyperspectral imaging is implemented and compared in terms of spectral coverage, spectral resolution, speed and noise. Phasematch scanning and scanning of the object within the field of view is considered....

  2. Quantitative gas analysis with FT-IR

    DEFF Research Database (Denmark)

    Bak, J.; Larsen, A.

    1995-01-01

    Calibration spectra of CO in the 2.38-5100 ppm concentration range (22 spectra) have been measured with a spectral resolution of 4 cm(-1), in the mid-IR (2186-2001 cm(-1)) region, with a Fourier transform infrared (FT-IR) instrument. The multivariate calibration method partial least-squares (PLS1...

  3. Enhancing inhibition-induced plasticity in tinnitus--spectral energy contrasts in tailor-made notched music matter.

    Directory of Open Access Journals (Sweden)

    Alwina Stein

    Full Text Available Chronic tinnitus seems to be caused by reduced inhibition among frequency selective neurons in the auditory cortex. One possibility to reduce tinnitus perception is to induce inhibition onto over-activated neurons representing the tinnitus frequency via tailor-made notched music (TMNM. Since lateral inhibition is modifiable by spectral energy contrasts, the question arises if the effects of inhibition-induced plasticity can be enhanced by introducing increased spectral energy contrasts (ISEC in TMNM. Eighteen participants suffering from chronic tonal tinnitus, pseudo randomly assigned to either a classical TMNM or an ISEC-TMNM group, listened to notched music for three hours on three consecutive days. The music was filtered for both groups by introducing a notch filter centered at the individual tinnitus frequency. For the ISEC-TMNM group a frequency bandwidth of 3/8 octaves on each side of the notch was amplified, additionally, by about 20 dB. Before and after each music exposure, participants rated their subjectively perceived tinnitus loudness on a visual analog scale. During the magnetoencephalographic recordings, participants were stimulated with either a reference tone of 500 Hz or a test tone with a carrier frequency representing the individual tinnitus pitch. Perceived tinnitus loudness was significantly reduced after TMNM exposure, though TMNM type did not influence the loudness ratings. Tinnitus related neural activity in the N1m time window and in the so called tinnitus network comprising temporal, parietal and frontal regions was reduced after TMNM exposure. The ISEC-TMNM group revealed even enhanced inhibition-induced plasticity in a temporal and a frontal cortical area. Overall, inhibition of tinnitus related neural activity could be strengthened in people affected with tinnitus by increasing spectral energy contrast in TMNM, confirming the concepts of inhibition-induced plasticity via TMNM and spectral energy contrasts.

  4. 40 CFR Table E-2 to Subpart E of... - Spectral Energy Distribution and Permitted Tolerance for Conducting Radiative Tests

    Science.gov (United States)

    2010-07-01

    ... Permitted Tolerance for Conducting Radiative Tests E Table E-2 to Subpart E of Part 53 Protection of... Reference Methods and Class I and Class II Equivalent Methods for PM2.5 or PM10â2.5 Pt. 53, Subpt. E, Table E-2 Table E-2 to Subpart E of Part 53—Spectral Energy Distribution and Permitted Tolerance for...

  5. The efficacy of the use of IR laser phototherapy associated to biphasic ceramic graft and guided bone regeneration on surgical fractures treated with miniplates: a Raman spectral study on rabbits.

    Science.gov (United States)

    Pinheiro, Antonio L B; Santos, Nicole Ribeiro Silva; Oliveira, Priscila Chagas; Aciole, Gilberth Tadeu Santos; Ramos, Thais Andrade; Gonzalez, Tayná Assunção; da Silva, Laís Nogueira; Barbosa, Artur Felipe Santos; Silveira, Landulfo

    2013-02-01

    The aim of the present study was to assess, by Raman spectroscopy, the repair of surgical fractures fixed with internal rigid fixation (IRF) treated or not with IR laser (λ780 nm, 50 mW, 4 × 4 J/cm(2) = 16 J/cm(2), ϕ = 0.5 cm(2), CW) associated or not to the use of hydroxyapatite and guided bone regeneration (GBR). Surgical tibial fractures were created under general anesthesia on 15 rabbits that were divided into five groups, maintained on individual cages, at day/night cycle, fed with solid laboratory pelted diet and had water ad libitum. The fractures in groups II, III, IV and V were fixed with miniplates. Animals in groups III and V were grafted with hydroxyapatite and GBR technique used. Animals in groups IV and V were irradiated at every other day during 2 weeks (4 × 4 J/cm(2), 16 J/cm(2) = 112 J/cm(2)). Observation time was that of 30 days. After animal death, specimens were taken and kept in liquid nitrogen and used for Raman spectroscopy. Raman spectroscopy showed significant differences between groups (p < 0.001). Basal readings showed mean value of 1,234 ± 220.1. Group internal rigid fixation + biomaterial + laser showed higher readings (3,521 ± 2,670) and group internal rigid fixation + biomaterial the lowest (212.2 ± 119.8). In conclusion, the results of the present investigation are important clinically as spectral analysis of bone component evidenced increased levels of CHA on fractured sites by using the association of laser light to a ceramic graft.

  6. IDEN2-A program for visual identification of spectral lines and energy levels in optical spectra of atoms and simple molecules

    Science.gov (United States)

    Azarov, V. I.; Kramida, A.; Vokhmentsev, M. Ya.

    2018-04-01

    The article describes a Java program that can be used in a user-friendly way to visually identify spectral lines observed in complex spectra with theoretically predicted transitions between atomic or molecular energy levels. The program arranges various information about spectral lines and energy levels in such a way that line identification and determination of positions of experimentally observed energy levels become much easier tasks that can be solved fast and efficiently.

  7. Time evolution of the spectral break in the high-energy extra component of GRB 090926A

    Science.gov (United States)

    Yassine, M.; Piron, F.; Mochkovitch, R.; Daigne, F.

    2017-10-01

    Aims: The prompt light curve of the long GRB 090926A reveals a short pulse 10 s after the beginning of the burst emission, which has been observed by the Fermi observatory from the keV to the GeV energy domain. During this bright spike, the high-energy emission from GRB 090926A underwent a sudden hardening above 10 MeV in the form of an additional power-law component exhibiting a spectral attenuation at a few hundreds of MeV. This high-energy break has been previously interpreted in terms of gamma-ray opacity to pair creation and has been used to estimate the bulk Lorentz factor of the outflow. In this article, we report on a new time-resolved analysis of the GRB 090926A broadband spectrum during its prompt phase and on its interpretation in the framework of prompt emission models. Methods: We characterized the emission from GRB 090926A at the highest energies with Pass 8 data from the Fermi Large Area Telescope (LAT), which offer a greater sensitivity than any data set used in previous studies of this burst, particularly in the 30-100 MeV energy band. Then, we combined the LAT data with the Fermi Gamma-ray Burst Monitor (GBM) in joint spectral fits to characterize the time evolution of the broadband spectrum from keV to GeV energies. We paid careful attention to the systematic effects that arise from the uncertainties on the LAT response. Finally, we performed a temporal analysis of the light curves and we computed the variability timescales from keV to GeV energies during and after the bright spike. Results: Our analysis confirms and better constrains the spectral break, which has been previously reported during the bright spike. Furthermore, it reveals that the spectral attenuation persists at later times with an increase of the break characteristic energy up to the GeV domain until the end of the prompt phase. We discuss these results in terms of keV-MeV synchroton radiation of electrons accelerated during the dissipation of the jet energy and inverse Compton

  8. The troposphere-to-stratosphere transition in kinetic energy spectra and nonlinear spectral fluxes as seen in ECMWF analyses

    Science.gov (United States)

    Burgess, A. B. H.; Erler, A. R.; Shepherd, T. G.

    2012-04-01

    We present spectra, nonlinear interaction terms, and fluxes computed for horizontal wind fields from high-resolution meteorological analyses made available by ECMWF for the International Polar Year. Total kinetic energy spectra clearly show two spectral regimes: a steep spectrum at large scales and a shallow spectrum in the mesoscale. The spectral shallowing appears at ~200 hPa, and is due to decreasing rotational power with height, which results in the shallower divergent spectrum dominating in the mesoscale. The spectra we find are steeper than those observed in aircraft data and GCM simulations. Though the analyses resolve total spherical harmonic wavenumbers up to n = 721, effects of dissipation on the fluxes and spectra are visible starting at about n = 200. We find a weak forward energy cascade and a downscale enstrophy cascade in the mesoscale. Eddy-eddy nonlinear kinetic energy transfers reach maximum amplitudes at the tropopause, and decrease with height thereafter; zonal mean-eddy transfers dominate in the stratosphere. In addition, zonal anisotropy reaches a minimum at the tropopause. Combined with strong eddy-eddy interactions, this suggests flow in the tropopause region is very active and bears the greatest resemblance to isotropic turbulence. We find constant enstrophy flux over a broad range of wavenumbers around the tropopause and in the upper stratosphere. A relatively constant spectral enstrophy flux at the tropopause suggests a turbulent inertial range, and that the enstrophy flux is resolved. A main result of our work is its implications for explaining the shallow mesoscale spectrum observed in aircraft wind measurements, GCM studies, and now meteorological analyses. The strong divergent component in the shallow mesoscale spectrum indicates unbalanced flow, and nonlinear transfers decreasing quickly with height are characteristic of waves, not turbulence. Together with the downscale flux of energ y through the shallow spectral range, these

  9. Influence of Desorption Conditions on Analyte Sensitivity and Internal Energy in Discrete Tissue or Whole Body Imaging by IR-MALDESI

    Science.gov (United States)

    Rosen, Elias P.; Bokhart, Mark T.; Ghashghaei, H. Troy; Muddiman, David C.

    2015-06-01

    Analyte signal in a laser desorption/postionization scheme such as infrared matrix-assisted laser desorption electrospray ionization (IR-MALDESI) is strongly coupled to the degree of overlap between the desorbed plume of neutral material from a sample and an orthogonal electrospray. In this work, we systematically examine the effect of desorption conditions on IR-MALDESI response to pharmaceutical drugs and endogenous lipids in biological tissue using a design of experiments approach. Optimized desorption conditions have then been used to conduct an untargeted lipidomic analysis of whole body sagittal sections of neonate mouse. IR-MALDESI response to a wide range of lipid classes has been demonstrated, with enhanced lipid coverage received by varying the laser wavelength used for mass spectrometry imaging (MSI). Targeted MS2 imaging (MS2I) of an analyte, cocaine, deposited beneath whole body sections allowed determination of tissue-specific ion response factors, and CID fragments of cocaine were monitored to comment on wavelength-dependent internal energy deposition based on the "survival yield" method.

  10. Metal artefact reduction in gemstone spectral imaging dual-energy CT with and without metal artefact reduction software

    International Nuclear Information System (INIS)

    Lee, Young Han; Song, Ho-Taek; Kim, Sungjun; Suh, Jin-Suck; Park, Kwan Kyu

    2012-01-01

    To assess the usefulness of gemstone spectral imaging (GSI) dual-energy CT (DECT) with/without metal artefact reduction software (MARs). The DECTs were performed using fast kV-switching GSI between 80 and 140 kV. The CT data were retro-reconstructed with/without MARs, by different displayed fields-of-view (DFOV), and with synthesised monochromatic energy in the range 40-140 keV. A phantom study of size and CT numbers was performed in a titanium plate and a stainless steel plate. A clinical study was performed in 26 patients with metallic hardware. All images were retrospectively reviewed in terms of the visualisation of periprosthetic regions and the severity of beam-hardening artefacts by using a five-point scale. The GSI-MARs reconstruction can markedly reduce the metal-related artefacts, and the image quality was affected by the prosthesis composition and DFOV. The spectral CT numbers of the prosthesis and periprosthetic regions showed different patterns on stainless steel and titanium plates. Dual-energy CT with GSI-MARs can reduce metal-related artefacts and improve the delineation of the prosthesis and periprosthetic region. We should be cautious when using GSI-MARs because the image quality was affected by the prosthesis composition, energy (in keV) and DFOV. The metallic composition and size should be considered in metallic imaging with GSI-MARs reconstruction. circle Metal-related artefacts can be troublesome on musculoskeletal computed tomography (CT). circle Gemstone spectral imaging (GSI) with dual-energy CT (DECT) offers a novel solution circle GSI and metallic artefact reduction software (GSI-MAR) can markedly reduce these artefacts. circle However image quality is influenced by the prosthesis composition and other parameters. circle We should be aware about potential overcorrection when using GSI-MARs. (orig.)

  11. Cluster pattern analysis of energy deposition sites for the brachytherapy sources 103Pd, 125I, 192Ir, 137Cs, and 60Co.

    Science.gov (United States)

    Villegas, Fernanda; Tilly, Nina; Bäckström, Gloria; Ahnesjö, Anders

    2014-09-21

    Analysing the pattern of energy depositions may help elucidate differences in the severity of radiation-induced DNA strand breakage for different radiation qualities. It is often claimed that energy deposition (ED) sites from photon radiation form a uniform random pattern, but there is indication of differences in RBE values among different photon sources used in brachytherapy. The aim of this work is to analyse the spatial patterns of EDs from 103Pd, 125I, 192Ir, 137Cs sources commonly used in brachytherapy and a 60Co source as a reference radiation. The results suggest that there is both a non-uniform and a uniform random component to the frequency distribution of distances to the nearest neighbour ED. The closest neighbouring EDs show high spatial correlation for all investigated radiation qualities, whilst the uniform random component dominates for neighbours with longer distances for the three higher mean photon energy sources (192Ir, 137Cs, and 60Co). The two lower energy photon emitters (103Pd and 125I) present a very small uniform random component. The ratio of frequencies of clusters with respect to 60Co differs up to 15% for the lower energy sources and less than 2% for the higher energy sources when the maximum distance between each pair of EDs is 2 nm. At distances relevant to DNA damage, cluster patterns can be differentiated between the lower and higher energy sources. This may be part of the explanation to the reported difference in RBE values with initial DSB yields as an endpoint for these brachytherapy sources.

  12. Impaired Insulin Signaling is Associated with Hepatic Mitochondrial Dysfunction in IR+/−-IRS-1+/− Double Heterozygous (IR-IRS1dh Mice

    Directory of Open Access Journals (Sweden)

    Andras Franko

    2017-05-01

    Full Text Available Mitochondria play a pivotal role in energy metabolism, but whether insulin signaling per se could regulate mitochondrial function has not been identified yet. To investigate whether mitochondrial function is regulated by insulin signaling, we analyzed muscle and liver of insulin receptor (IR+/−-insulin receptor substrate-1 (IRS-1+/− double heterozygous (IR-IRS1dh mice, a well described model for insulin resistance. IR-IRS1dh mice were studied at the age of 6 and 12 months and glucose metabolism was determined by glucose and insulin tolerance tests. Mitochondrial enzyme activities, oxygen consumption, and membrane potential were assessed using spectrophotometric, respirometric, and proton motive force analysis, respectively. IR-IRS1dh mice showed elevated serum insulin levels. Hepatic mitochondrial oxygen consumption was reduced in IR-IRS1dh animals at 12 months of age. Furthermore, 6-month-old IR-IRS1dh mice demonstrated enhanced mitochondrial respiration in skeletal muscle, but a tendency of impaired glucose tolerance. On the other hand, 12-month-old IR-IRS1dh mice showed improved glucose tolerance, but normal muscle mitochondrial function. Our data revealed that deficiency in IR/IRS-1 resulted in normal or even elevated skeletal muscle, but impaired hepatic mitochondrial function, suggesting a direct cross-talk between insulin signaling and mitochondria in the liver.

  13. Semiconductor detectors in current energy dispersive X-ray spectral analysis

    International Nuclear Information System (INIS)

    Betin, J.; Zhabin, E.; Krampit, I.; Smirnov, V.

    1980-01-01

    A review is presented of the properties of semiconductor detectors and of the possibilities stemming therefrom of using the detectors in X-ray spectral analysis in industries, in logging, in ecology and environmental control, in medicine, etc. (M.S.)

  14. FUNDAMENTAL PARAMETERS AND SPECTRAL ENERGY DISTRIBUTIONS OF YOUNG AND FIELD AGE OBJECTS WITH MASSES SPANNING THE STELLAR TO PLANETARY REGIME

    Energy Technology Data Exchange (ETDEWEB)

    Filippazzo, Joseph C.; Rice, Emily L. [Department of Engineering Science and Physics, College of Staten Island, City University of New York, 2800 Victory Blvd, Staten Island, NY 10314 (United States); Faherty, Jacqueline; Cruz, Kelle L. [Department of Astrophysics, American Museum of Natural History, New York, NY 10024 (United States); Van Gordon, Mollie M. [Department of Geography, University of California, Berkeley, CA 94720 (United States); Looper, Dagny L. [Tisch School of the Arts, New York University, New York, NY 10003 (United States)

    2015-09-10

    We combine optical, near-infrared, and mid-infrared spectra and photometry to construct expanded spectral energy distributions for 145 field age (>500 Myr) and 53 young (lower age estimate <500 Myr) ultracool dwarfs (M6-T9). This range of spectral types includes very low mass stars, brown dwarfs, and planetary mass objects, providing fundamental parameters across both the hydrogen and deuterium burning minimum masses for the largest sample assembled to date. A subsample of 29 objects have well constrained ages as probable members of a nearby young moving group. We use 182 parallaxes and 16 kinematic distances to determine precise bolometric luminosities (L{sub bol}) and radius estimates from evolutionary models give semi-empirical effective temperatures (T{sub eff}) for the full range of young and field age late-M, L, and T dwarfs. We construct age-sensitive relationships of luminosity, temperature, and absolute magnitude as functions of spectral type and absolute magnitude to disentangle the effects of degenerate physical parameters such as T{sub eff}, surface gravity, and clouds on spectral morphology. We report bolometric corrections in J for both field age and young objects and find differences of up to a magnitude for late-L dwarfs. Our correction in Ks shows a larger dispersion but not necessarily a different relationship for young and field age sequences. We also characterize the NIR–MIR reddening of low gravity L dwarfs and identify a systematically cooler T{sub eff} of up to 300 K from field age objects of the same spectral type and 400 K cooler from field age objects of the same M{sub H} magnitude.

  15. Spectral Analysis, Synthesis, & Energy Distributions of Nearby E+A Galaxies Using SDSS-IV MaNGA

    Science.gov (United States)

    Weaver, Olivia A.; Anderson, Miguel Ricardo; Wally, Muhammad; James, Olivia; Falcone, Julia; Liu, Allen; Wallack, Nicole; Liu, Charles; SDSS Collaboration

    2017-01-01

    Utilizing data from the Mapping Nearby Galaxies at APO (MaNGA) Survey (MaNGA Product Launch-4, or MPL-4), of the latest generation of the Sloan Digital Sky Survey (SDSS-IV), we identified nine post-starburst (E+A) systems that lie within the Green Valley transition zone. We identify the E+A galaxies by their SDSS single fiber spectrum and u-r color, then confirmed their classification as post-starburst by coding/plotting methods and spectral synthesis codes (FIREFLY and PIPE3D), as well as with their Spectral Energy Distributions (SEDs) from 0.15 µm to 22 µm, using GALEX, SDSS, 2MASS, and WISE data. We produced maps of gaussian-fitted fluxes, equivalent widths, stellar velocities, metallicities and age. We also produced spectral line ratio diagrams to classify regions of stellar populations of the galaxies. We found that our sample of E+As retain their post-starburst properties across the entire galaxy, not just at their center. We detected matching a trend line in the ultraviolet and optical bands, consistent with the expected SEDs for an E+A galaxy, and also through the J, H and Ks bands, except for one object. We classified one of the nine galaxies as a luminous infrared galaxy, unusual for a post-starburst object. Our group seeks to further study stellar population properties, spectral energy distributions and quenching properties in E+A galaxies, and investigate their role in galaxy evolution as a whole. This work was supported by the Alfred P. Sloan Foundation via the SDSS-IV Faculty and Student Team (FAST) initiative, ARC Agreement #SSP483 to the CUNY College of Staten Island. This work was also supported by grants to The American Museum of Natural History, and the CUNY College of Staten Island through from National Science Foundation.

  16. Dust spectral energy distributions of nearby galaxies: an insight from the Herschel Reference Survey

    Science.gov (United States)

    Ciesla, L.; Boquien, M.; Boselli, A.; Buat, V.; Cortese, L.; Bendo, G. J.; Heinis, S.; Galametz, M.; Eales, S.; Smith, M. W. L.; Baes, M.; Bianchi, S.; De Looze, I.; di Serego Alighieri, S.; Galliano, F.; Hughes, T. M.; Madden, S. C.; Pierini, D.; Rémy-Ruyer, A.; Spinoglio, L.; Vaccari, M.; Viaene, S.; Vlahakis, C.

    2014-05-01

    Although it accounts only for a small fraction of the baryonic mass, dust has a profound impact on the physical processes at play in galaxies. Thus, to understand the evolution of galaxies, it is essential not only to characterize dust properties per se, but also in relation to global galaxy properties. To do so, we derive the dust properties of galaxies in a volume limited, K-band selected sample, the Herschel Reference Survey (HRS). We gather infrared photometric data from 8 μm to 500 μm from Spitzer, WISE, IRAS, and Herschel for all of the HRS galaxies. Draine & Li (2007, ApJ, 663, 866) models are fit to the data from which the stellar contribution has been carefully removed. We find that our photometric coverage is sufficient to constrain all of the parameters of the Draine & Li models and that a strong constraint on the 20-60 μm range is mandatory to estimate the relative contribution of the photo-dissociation regions to the infrared spectral energy distribution (SED). The SED models tend to systematically underestimate the observed 500 μm flux densities, especially for low-mass systems. We provide the output parameters for all of the galaxies, i.e., the minimum intensity of the interstellar radiation field, the fraction of polycyclic aromatic hydrocarbon (PAH), the relative contribution of PDR and evolved stellar population to the dust heating, the dust mass, and the infrared luminosity. For a subsample of gas-rich galaxies, we analyze the relations between these parameters and the main integrated properties of galaxies, such as stellar mass, star formation rate, infraredluminosity, metallicity, Hα and H-band surface brightness, and the far-ultraviolet attenuation. A good correlation between the fraction of PAH and the metallicity is found, implying a weakening of the PAH emission in galaxies with low metallicities and, thus, low stellar masses. The intensity of the diffuse interstellar radiation field and the H-band and Hα surface brightnesses are

  17. Localized Spectral Analysis of Fluctuating Power Generation from Solar Energy Systems

    Directory of Open Access Journals (Sweden)

    Johan Nijs

    2007-01-01

    Full Text Available Fluctuations in solar irradiance are a serious obstacle for the future large-scale application of photovoltaics. Occurring regularly with the passage of clouds, they can cause unexpected power variations and introduce voltage dips to the power distribution system. This paper proposes the treatment of such fluctuating time series as realizations of a stochastic, locally stationary, wavelet process. Its local spectral density can be estimated from empirical data by means of wavelet periodograms. The wavelet approach allows the analysis of the amplitude of fluctuations per characteristic scale, hence, persistence of the fluctuation. Furthermore, conclusions can be drawn on the frequency of occurrence of fluctuations of different scale. This localized spectral analysis was applied to empirical data of two successive years. The approach is especially useful for network planning and load management of power distribution systems containing a high density of photovoltaic generation units.

  18. Process and device of elementary and chemical analysis of a sample through a spectral analysis of the secondary electron energies

    International Nuclear Information System (INIS)

    Le Gressus, Claude; Massignon, Daniel; Sopizet, Rene.

    1975-01-01

    The present invention relates to a method of chemical and elementary analysis of samples through a spectral analysis of secondary electrons (Auger electrons) emitted from said sample under a primary monokinetic electron beam concentrated on its surface. Said method is characterized in that the intensity of the primary monokinetic electron beam emitted from an electron gun is modulated at a frequency ω; and in that the secondary electrons of energy E emitted from the sample are then collected. A reference voltage corresponding to the modulation in intensity of the primary electron beam is applied at the input of a phase sensitive detector together with a voltage proportional to the intensity of the flux of said collected secondary electrons to obtain at the output of said detector a voltage proportional to the number of the secondary electrons of energy E. The secondary emission energy spectrum of the sample is then plotted [fr

  19. The color of X-rays Spectral X-ray computed tomography using energy sensitive pixel detectors

    CERN Document Server

    Schioppa, Enrico Junior

    Energy sensitive X-ray imaging detectors are produced by connecting a semiconductor sensor to a spectroscopic pixel readout chip. In this thesis, the applicability of such detectors to X-ray Computed Tomography (CT) is studied. A prototype Medipix based silicon detector is calibrated using X-ray fluorescence. The charge transport properties of the sensor are characterized using a high energy beam of charged particles at the Super Proton Synchrotron (SPS) at the European Center for Nuclear Research (CERN). Monochromatic X-rays at the European Synchrotron Radiation Facility (ESRF) are used to determined the energy response function. These data are used to implement a physics-based CT projection operator that accounts for the transmission of the source spectrum through the sample and detector effects. Based on this projection operator, an iterative spectral CT reconstruction algorithm is developed by extending an Ordered Subset Expectation Maximization (OSEM) method. Subsequently, a maximum likelihood based algo...

  20. THE INFLUENCE OF THE EXTREME ULTRAVIOLET SPECTRAL ENERGY DISTRIBUTION ON THE STRUCTURE AND COMPOSITION OF THE UPPER ATMOSPHERE OF EXOPLANETS

    Energy Technology Data Exchange (ETDEWEB)

    Guo, J. H. [Yunnan Observatories, Chinese Academy of Sciences, P.O. Box 110, Kunming 650011 (China); Ben-Jaffel, Lotfi, E-mail: guojh@ynao.ac.cn, E-mail: bjaffel@iap.fr [Sorbonne Universités, UPMC Univ. Paris 6 et CNRS, UMR 7095, Institut Astrophysique de Paris, F-75014 Paris (France)

    2016-02-20

    By varying the profiles of stellar extreme ultraviolet (EUV) spectral energy distributions (SEDs), we tested the influences of stellar EUV SEDs on the physical and chemical properties of an escaping atmosphere. We apply our model to study four exoplanets: HD 189733b, HD 209458b, GJ 436b, and Kepler-11b. We find that the total mass loss rates of an exoplanet, which are determined mainly by the integrated fluxes, are moderately affected by the profiles of the EUV SED, but the composition and species distributions in the atmosphere can be dramatically modified by the different profiles of the EUV SED. For exoplanets with a high hydrodynamic escape parameter (λ), the amount of atomic hydrogen produced by photoionization at different altitudes can vary by one to two orders of magnitude with the variation of stellar EUV SEDs. The effect of photoionization of H is prominent when the EUV SED is dominated by the low-energy spectral region (400–900 Å), which pushes the transition of H/H{sup +} to low altitudes. In contrast, the transition of H/H{sup +} moves to higher altitudes when most photons are concentrated in the high-energy spectral region (50–400 Å). For exoplanets with a low λ, the lower temperatures of the atmosphere make many chemical reactions so important that photoionization alone can no longer determine the composition of the escaping atmosphere. For HD 189733b, it is possible to explain the time variability of Lyα between 2010 and 2011 by a change in the EUV SED of the host K-type star, yet invoking only thermal H i in the atmosphere.

  1. The Flare Irradiance Spectral Model (FISM) and its Contributions to Space Weather Research, the Flare Energy Budget, and Instrument Design

    Science.gov (United States)

    Chamberlin, Phillip

    2008-01-01

    The Flare Irradiance Spectral Model (FISM) is an empirical model of the solar irradiance spectrum from 0.1 to 190 nm at 1 nm spectral resolution and on a 1-minute time cadence. The goal of FISM is to provide accurate solar spectral irradiances over the vacuum ultraviolet (VUV: 0-200 nm) range as input for ionospheric and thermospheric models. The seminar will begin with a brief overview of the FISM model, and also how the Solar Dynamics Observatory (SDO) EUV Variability Experiment (EVE) will contribute to improving FISM. Some current studies will then be presented that use FISM estimations of the solar VUV irradiance to quantify the contributions of the increased irradiance from flares to Earth's increased thermospheric and ionospheric densites. Initial results will also be presented from a study looking at the electron density increases in the Martian atmosphere during a solar flare. Results will also be shown quantifying the VUV contributions to the total flare energy budget for both the impulsive and gradual phases of solar flares. Lastly, an example of how FISM can be used to simplify the design of future solar VUV irradiance instruments will be discussed, using the future NOAA GOES-R Extreme Ultraviolet and X-Ray Sensors (EXIS) space weather instrument.

  2. A gamma-ray burst with a high-energy spectral component inconsistent with the synchrotron shock model.

    Science.gov (United States)

    González, M M; Dingus, B L; Kaneko, Y; Preece, R D; Dermer, C D; Briggs, M S

    2003-08-14

    Gamma-ray bursts are among the most powerful events in nature. These events release most of their energy as photons with energies in the range from 30 keV to a few MeV, with a smaller fraction of the energy radiated in radio, optical, and soft X-ray afterglows. The data are in general agreement with a relativistic shock model, where the prompt and afterglow emissions correspond to synchrotron radiation from shock-accelerated electrons. Here we report an observation of a high-energy (multi-MeV) spectral component in the burst of 17 October 1994 that is distinct from the previously observed lower-energy gamma-ray component. The flux of the high-energy component decays more slowly and its fluence is greater than the lower-energy component; it is described by a power law of differential photon number index approximately -1 up to about 200 MeV. This observation is difficult to explain with the standard synchrotron shock model, suggesting the presence of new phenomena such as a different non-thermal electron process, or the interaction of relativistic protons with photons at the source.

  3. A study on spectral energy for the end of the twentieth century the basis of the NCEP reanalysis-II

    Science.gov (United States)

    Aranha, A. F.; Veiga, J. A.; Yoshida, M. C.

    2013-05-01

    The energy cycle proposed by Lorenz (1955) is composed of the behavior of the average energy from the atmosphere and characteristics of atmospheric energy deviations from this average, respectively called basic state and perturbed state. However, it is possible to discretize the energy contained in the atmosphere disturbed state, decomposing the fields of the various disturbances or harmonics wave type, so as to measure and analyze the energy of these disorders according to their number or wavelength, this methodology described second Saltzman (1957). Therefore, in view of the spectral analysis as a methodological basis, this work aims to study the energy contained by the atmosphere in disturbed state. Considering the terms of power generation potential available for nth waves due to diabatic heating, represented by (G(n)), potential energy of nth wave (P(n)) and kinetic energy of nth wave (K(n)) and the conversion of energy between the energy nth kinetic and potential energy of waves nth waves given by (C(n)). The variables used in the calculation of the terms above are, temperature (T) orthogonal components of the wind (u, v, w) and geopotential height (G) from a data set from the National Center for Environmental Prediction (NCEP) considering daily shared values on a regular grid with a spatial resolution of 2.5° × 2.5°, distributed in 12 pressure levels (1000, 925, 850, 700, 600, 500, 400, 300, 250, 200, 150, 100 hPa ) for the 1970 to 1999 period. The results show that for kinetic energy of disturbance to nth wave, the amount of energy is somewhat dammed during for the first 10 wave numbers in this range are the planetary waves and waves. Observing this way, we can conclude that these waves are responsible for much of the kinetic energy in disturbed state. A characteristic and a difference in the distribution of energy between kinetic energy and potential energy disturbed total available to disturbance, is the derivative of the energy wavenumber presented by

  4. Improved Correction of IR Loss in Diffuse Shortwave Measurements: An ARM Value-Added Product

    Energy Technology Data Exchange (ETDEWEB)

    Younkin, K; Long, CN

    2003-11-01

    Simple single black detector pyranometers, such as the Eppley Precision Spectral Pyranometer (PSP) used by the Atmospheric Radiation Measurement (ARM) Program, are known to lose energy via infrared (IR) emission to the sky. This is especially a problem when making clear-sky diffuse shortwave (SW) measurements, which are inherently of low magnitude and suffer the greatest IR loss. Dutton et al. (2001) proposed a technique using information from collocated pyrgeometers to help compensate for this IR loss. The technique uses an empirically derived relationship between the pyrgeometer detector data (and alternatively the detector data plus the difference between the pyrgeometer case and dome temperatures) and the nighttime pyranometer IR loss data. This relationship is then used to apply a correction to the diffuse SW data during daylight hours. We developed an ARM value-added product (VAP) called the SW DIFF CORR 1DUTT VAP to apply the Dutton et al. correction technique to ARM PSP diffuse SW measurements.

  5. Single-source dual-energy spectral multidetector CT of pancreatic adenocarcinoma: Optimization of energy level viewing significantly increases lesion contrast

    International Nuclear Information System (INIS)

    Patel, B.N.; Thomas, J.V.; Lockhart, M.E.; Berland, L.L.; Morgan, D.E.

    2013-01-01

    Aim: To evaluate lesion contrast in pancreatic adenocarcinoma patients using spectral multidetector computed tomography (MDCT) analysis. Materials and methods: The present institutional review board-approved, Health Insurance Portability and Accountability Act of 1996 (HIPAA)-compliant retrospective study evaluated 64 consecutive adults with pancreatic adenocarcinoma examined using a standardized, multiphasic protocol on a single-source, dual-energy MDCT system. Pancreatic phase images (35 s) were acquired in dual-energy mode; unenhanced and portal venous phases used standard MDCT. Lesion contrast was evaluated on an independent workstation using dual-energy analysis software, comparing tumour to non-tumoural pancreas attenuation (HU) differences and tumour diameter at three energy levels: 70 keV; individual subject-optimized viewing energy level (based on the maximum contrast-to-noise ratio, CNR); and 45 keV. The image noise was measured for the same three energies. Differences in lesion contrast, diameter, and noise between the different energy levels were analysed using analysis of variance (ANOVA). Quantitative differences in contrast gain between 70 keV and CNR-optimized viewing energies, and between CNR-optimized and 45 keV were compared using the paired t-test. Results: Thirty-four women and 30 men (mean age 68 years) had a mean tumour diameter of 3.6 cm. The median optimized energy level was 50 keV (range 40–77). The mean ± SD lesion contrast values (non-tumoural pancreas – tumour attenuation) were: 57 ± 29, 115 ± 70, and 146 ± 74 HU (p = 0.0005); the lengths of the tumours were: 3.6, 3.3, and 3.1 cm, respectively (p = 0.026); and the contrast to noise ratios were: 24 ± 7, 39 ± 12, and 59 ± 17 (p = 0.0005) for 70 keV, the optimized energy level, and 45 keV, respectively. For individuals, the mean ± SD contrast gain from 70 keV to the optimized energy level was 59 ± 45 HU; and the mean ± SD contrast gain from the optimized energy level to 45 ke

  6. Single-source dual-energy spectral multidetector CT of pancreatic adenocarcinoma: optimization of energy level viewing significantly increases lesion contrast.

    Science.gov (United States)

    Patel, B N; Thomas, J V; Lockhart, M E; Berland, L L; Morgan, D E

    2013-02-01

    To evaluate lesion contrast in pancreatic adenocarcinoma patients using spectral multidetector computed tomography (MDCT) analysis. The present institutional review board-approved, Health Insurance Portability and Accountability Act of 1996 (HIPAA)-compliant retrospective study evaluated 64 consecutive adults with pancreatic adenocarcinoma examined using a standardized, multiphasic protocol on a single-source, dual-energy MDCT system. Pancreatic phase images (35 s) were acquired in dual-energy mode; unenhanced and portal venous phases used standard MDCT. Lesion contrast was evaluated on an independent workstation using dual-energy analysis software, comparing tumour to non-tumoural pancreas attenuation (HU) differences and tumour diameter at three energy levels: 70 keV; individual subject-optimized viewing energy level (based on the maximum contrast-to-noise ratio, CNR); and 45 keV. The image noise was measured for the same three energies. Differences in lesion contrast, diameter, and noise between the different energy levels were analysed using analysis of variance (ANOVA). Quantitative differences in contrast gain between 70 keV and CNR-optimized viewing energies, and between CNR-optimized and 45 keV were compared using the paired t-test. Thirty-four women and 30 men (mean age 68 years) had a mean tumour diameter of 3.6 cm. The median optimized energy level was 50 keV (range 40-77). The mean ± SD lesion contrast values (non-tumoural pancreas - tumour attenuation) were: 57 ± 29, 115 ± 70, and 146 ± 74 HU (p = 0.0005); the lengths of the tumours were: 3.6, 3.3, and 3.1 cm, respectively (p = 0.026); and the contrast to noise ratios were: 24 ± 7, 39 ± 12, and 59 ± 17 (p = 0.0005) for 70 keV, the optimized energy level, and 45 keV, respectively. For individuals, the mean ± SD contrast gain from 70 keV to the optimized energy level was 59 ± 45 HU; and the mean ± SD contrast gain from the optimized energy level to 45 keV was 31 ± 25 HU (p = 0

  7. The spectral energy distribution of the scattered light from dark clouds

    Science.gov (United States)

    Mattila, Kalevi; Schnur, G. F. O.

    1989-01-01

    A dark cloud is exposed to the ambient radiation field of integrated starlight in the Galaxy. Scattering of starlight by the dust particles gives rise to a diffuse surface brightness of the dark nebula. The intensity and the spectrum of this diffuse radiation can be used to investigate, e.g., the scattering parameters of the dust, the optical thickness of the cloud, and as a probe of the ambient radiation field at the location of the cloud. An understanding of the scattering process is also a prerequisite for the isolation of broad spectral features due to fluorescence or to any other non-scattering origin of the diffuse light. Model calculations are presented for multiple scattering in a spherical cloud. These calculations show that the different spectral shapes of the observed diffuse light can be reproduced with standard dust parameters. The possibility to use the observed spectrum as a diagnostic tool for analyzing the thickness of the cloud and the dust particle is discussed.

  8. Residual energy deposition in dental enamel during IR laser ablation at 2.79, 2.94, 9.6, and 10.6 μm

    Science.gov (United States)

    Ragadio, Jerome N.; Lee, Christian K.; Fried, Daniel

    2000-03-01

    The objective of this study was to measure the residual heat deposition during laser ablation at those IR laser wavelengths best suited for the removal of dental caries. The principal factor limiting the rate of laser ablation of dental hard tissue is the risk of excessive heat accumulation in the tooth, which has the potential for causing damage to the pulp. Optimal laser ablation systems minimize the residual energy deposition in the tooth by transferring deposited laser energy to kinetic and internal energy of ejected tissue components. The residual heat deposition in the tooth was measured at laser wavelengths of 2.79, 2.94, 9.6 and 10.6 micrometer and pulse widths of 150 ns - 150 microsecond(s) . The residual energy was at a minimum for fluences well above the ablation threshold where it saturates at values from 25 - 70% depending on pulse duration and wavelength for the systems investigated. The lowest values of the residual energy were measured for short (less than 20 microseconds) CO2 laser pulses at 9.6 micrometer and for Q-switched erbium laser pulses. This work was supported by NIH/NIDCR R29DE12091 and the Center for Laser Applications in Medicine, DOE DEFG0398ER62576.

  9. Fault feature extraction of planet gear in wind turbine gearbox based on spectral kurtosis and time wavelet energy spectrum

    Science.gov (United States)

    Kong, Yun; Wang, Tianyang; Li, Zheng; Chu, Fulei

    2017-09-01

    Planetary transmission plays a vital role in wind turbine drivetrains, and its fault diagnosis has been an important and challenging issue. Owing to the complicated and coupled vibration source, time-variant vibration transfer path, and heavy background noise masking effect, the vibration signal of planet gear in wind turbine gearboxes exhibits several unique characteristics: Complex frequency components, low signal-to-noise ratio, and weak fault feature. In this sense, the periodic impulsive components induced by a localized defect are hard to extract, and the fault detection of planet gear in wind turbines remains to be a challenging research work. Aiming to extract the fault feature of planet gear effectively, we propose a novel feature extraction method based on spectral kurtosis and time wavelet energy spectrum (SK-TWES) in the paper. Firstly, the spectral kurtosis (SK) and kurtogram of raw vibration signals are computed and exploited to select the optimal filtering parameter for the subsequent band-pass filtering. Then, the band-pass filtering is applied to extrude periodic transient impulses using the optimal frequency band in which the corresponding SK value is maximal. Finally, the time wavelet energy spectrum analysis is performed on the filtered signal, selecting Morlet wavelet as the mother wavelet which possesses a high similarity to the impulsive components. The experimental signals collected from the wind turbine gearbox test rig demonstrate that the proposed method is effective at the feature extraction and fault diagnosis for the planet gear with a localized defect.

  10. Multi-energy spectral CT: adding value in emergency body imaging.

    Science.gov (United States)

    Punjabi, Gopal V

    2018-04-01

    Most vendors offer scanners capable of dual- or multi-energy computed tomography (CT) imaging. Advantages of multi-energy CT scanning include superior tissue characterization, detection of subtle iodine uptake differences, and opportunities to reduce contrast dose. However, utilization of this technology in the emergency department (ED) remains low. The purpose of this pictorial essay is to illustrate the value of multi-energy CT scanning in emergency body imaging.

  11. Dual-energy approach to contrast-enhanced mammography using the balanced filter method: spectral optimization and preliminary phantom measurement.

    Science.gov (United States)

    Saito, Masatoshi

    2007-11-01

    Dual-energy contrast agent-enhanced mammography is a technique of demonstrating breast cancers obscured by a cluttered background resulting from the contrast between soft tissues in the breast. The technique has usually been implemented by exploiting two exposures to different x-ray tube voltages. In this article, another dual-energy approach using the balanced filter method without switching the tube voltages is described. For the spectral optimization of dual-energy mammography using the balanced filters, we applied a theoretical framework reported by Lemacks et al. [Med. Phys. 29, 1739-1751 (2002)] to calculate the signal-to-noise ratio (SNR) in an iodinated contrast agent subtraction image. This permits the selection of beam parameters such as tube voltage and balanced filter material, and the optimization of the latter's thickness with respect to some critical quantity-in this case, mean glandular dose. For an imaging system with a 0.1 mm thick CsI:T1 scintillator, we predict that the optimal tube voltage would be 45 kVp for a tungsten anode using zirconium, iodine, and neodymium balanced filters. A mean glandular dose of 1.0 mGy is required to obtain an SNR of 5 in order to detect 1.0 mg/cm2 iodine in the resulting clutter-free image of a 5 cm thick breast composed of 50% adipose and 50% glandular tissue. In addition to spectral optimization, we carried out phantom measurements to demonstrate the present dual-energy approach for obtaining a clutter-free image, which preferentially shows iodine, of a breast phantom comprising three major components-acrylic spheres, olive oil, and an iodinated contrast agent. The detection of iodine details on the cluttered background originating from the contrast between acrylic spheres and olive oil is analogous to the task of distinguishing contrast agents in a mixture of glandular and adipose tissues.

  12. Dual-energy approach to contrast-enhanced mammography using the balanced filter method: Spectral optimization and preliminary phantom measurement

    International Nuclear Information System (INIS)

    Saito, Masatoshi

    2007-01-01

    Dual-energy contrast agent-enhanced mammography is a technique of demonstrating breast cancers obscured by a cluttered background resulting from the contrast between soft tissues in the breast. The technique has usually been implemented by exploiting two exposures to different x-ray tube voltages. In this article, another dual-energy approach using the balanced filter method without switching the tube voltages is described. For the spectral optimization of dual-energy mammography using the balanced filters, we applied a theoretical framework reported by Lemacks et al. [Med. Phys. 29, 1739-1751 (2002)] to calculate the signal-to-noise ratio (SNR) in an iodinated contrast agent subtraction image. This permits the selection of beam parameters such as tube voltage and balanced filter material, and the optimization of the latter's thickness with respect to some critical quantity--in this case, mean glandular dose. For an imaging system with a 0.1 mm thick CsI:Tl scintillator, we predict that the optimal tube voltage would be 45 kVp for a tungsten anode using zirconium, iodine, and neodymium balanced filters. A mean glandular dose of 1.0 mGy is required to obtain an SNR of 5 in order to detect 1.0 mg/cm 2 iodine in the resulting clutter-free image of a 5 cm thick breast composed of 50% adipose and 50% glandular tissue. In addition to spectral optimization, we carried out phantom measurements to demonstrate the present dual-energy approach for obtaining a clutter-free image, which preferentially shows iodine, of a breast phantom comprising three major components - acrylic spheres, olive oil, and an iodinated contrast agent. The detection of iodine details on the cluttered background originating from the contrast between acrylic spheres and olive oil is analogous to the task of distinguishing contrast agents in a mixture of glandular and adipose tissues

  13. MARS Spectral Imaging: From High-Energy Physics to a Biomedical Business

    CERN Multimedia

    CERN. Geneva

    2017-01-01

    Abstract MARS spectral scanners provide colour X-Ray images. Current MARS pre-clinical scanners enable researchers and clinicians to measure biochemical and physiological processes in specimens, and animal models of disease. The scanners have developed from a 10 year scientific collaboration between New Zealand and CERN. In parallel a company, MARS Bioimaging Ltd, was founded to commercialise the technology by productising the scanner and selling it to biomedical users around the world. The New Zealand team is now more than 30 people including staff and students from the fields of physics, engineering, computing, maths, radiology, cardiology, biochemistry, oncology, and orthopaedics. Current work with pre-clinical scanners has concluded that the technology will be  useful in heart disease, stroke, arthritis, joint replacements, and cancer. In late 2014, the government announced funding for NZ to build a MARS scanner capable of imaging humans. Bio Professor Anthony Butler is a radiologist wit...

  14. Spectral, energy, and time parameters of two-photon fluorescence of 2,5-diphenyloxazole polycrystals

    International Nuclear Information System (INIS)

    Agal'tsov, A.M.; Gorelik, V.S.; Rakhmatullaev, I.A.

    1995-01-01

    Two-photon fluorescence (TPF) spectra of 2,5-diphenyloxazole polycrystals (known in the literature as PPO) were obtained and studied as a function of the pump power and time delay. The fluorescence spectrum shape observed upon two-photon excitation is shown to be distinctly different from that observed upon electron-beam excitation. It is shown that high pump powers result in stimulated fluorescence. PPO exhibits a high TPF quantum yield, the integrated conversion efficiency of exciting radiation to TPF being 40%. The TPF decay time is measured to be 20 ns. The spectral data obtained for PPO polycrystals can be used in the development of new TPF light sources tunable in the UV region. 10 refs., 4 figs., 1 tab

  15. The spectral energy distribution and nature of the symbiotic system AS 296 in outburst

    International Nuclear Information System (INIS)

    Munari, U.; Whitelock, P.A.

    1989-01-01

    Photometry covering the spectral range 0.36 to 5 μm is reported for the symbiotic star As 296 about two months after the onset of the first recorded nova-like outburst. Analysis of published pre-outburst photometry provides evidence for the presence of an accreting white dwarf of high luminosity. This information together with the new observations is used to eliminate, for the 1988 event, various mechanisms which have been suggested for the outbursts in symbiotic objects. It is shown that hydrogen burning of accreted material can produce the white dwarf luminosity during quiescence. The outburst is then the result of a thermonuclear runaway in the unburnt material. The evidence is somewhat conflicting on the question of degeneracy conditions prior to the thermonuclear runaway. (author)

  16. Energy-efficient VCSEL-based multiGigabit IR-UWB over Fiber with Airlink Transmission System

    DEFF Research Database (Denmark)

    Rodes Lopez, Roberto; Pham, Tien Thang; Jensen, Jesper Bevensee

    2010-01-01

    We propose VCSEL based impulse-radio ultrawideband technology for energy efficient high-speed wireless networks; with full passive signal distribution, from the central office to the home with high-speed wireless connection to the final user.......We propose VCSEL based impulse-radio ultrawideband technology for energy efficient high-speed wireless networks; with full passive signal distribution, from the central office to the home with high-speed wireless connection to the final user....

  17. Relativistic band-structure calculations for CeTIn sub 5 (T=Ir and Co) and analysis of the energy bands by using tight-binding method

    CERN Document Server

    Maehira, T; Ueda, K; Hasegawa, A

    2003-01-01

    In order to investigate electronic properties of recently discovered heavy fermion superconductors CeTIn sub 5 (T=Ir and Co), we employ the relativistic linear augmented-plane-wave (RLAPW) method to clarify the energy band structures and Fermi surfaces of those materials. The obtained energy bands mainly due to the large hybridization between Ce 4 f and In 5 p states well reproduce the Fermi surfaces consistent with the de Haas-van Alphen experimental results. However, when we attempt to understand magnetism and superconductively in CeTIn sub 5 from the microscopic viewpoint, the energy bands obtained in the RLAPW method are too complicated to analyze the system by further including electron correlations. Thus, it is necessary to prepare a more simplified model, keeping correctly the essential characters of the energy bands obtained in the band-structure calculation. For the purpose, we construct a tight-binding model for CeTIn sub 5 by including f-f and p-p hoppings as well as f-p hybridization, which are ex...

  18. Determination of solar energy fluctuations in the lower atmosphere using spectral analysis techniques

    International Nuclear Information System (INIS)

    Njau, E.C.

    1984-10-01

    An expression for the direct solar energy incident upon an arbitrary portion of the Earth's surface over an arbitrary duration of time (>2 days) has been formulated as a product of a continuous solar energy signal function and a correspondingly continuous time-dependent sampling function. The energy density spectrum of this product is then evaluated, and its predictions are compared with observations. Predicted periodicities agree well with both short-term and long-term observations. The implication of this work to meteorological and climatic studies is briefly discussed. (author)

  19. Efficiency of free-energy calculations of spin lattices by spectral quantum algorithms

    International Nuclear Information System (INIS)

    Master, Cyrus P.; Yamaguchi, Fumiko; Yamamoto, Yoshihisa

    2003-01-01

    Ensemble quantum algorithms are well suited to calculate estimates of the energy spectra for spin-lattice systems. Based on the phase estimation algorithm, these algorithms efficiently estimate discrete Fourier coefficients of the density of states. Their efficiency in calculating the free energy per spin of general spin lattices to bounded error is examined. We find that the number of Fourier components required to bound the error in the free energy due to the broadening of the density of states scales polynomially with the number of spins in the lattice. However, the precision with which the Fourier components must be calculated is found to be an exponential function of the system size

  20. Application of a Laplace transform pair model for high-energy x-ray spectral reconstruction.

    Science.gov (United States)

    Archer, B R; Almond, P R; Wagner, L K

    1985-01-01

    A Laplace transform pair model, previously shown to accurately reconstruct x-ray spectra at diagnostic energies, has been applied to megavoltage energy beams. The inverse Laplace transforms of 2-, 6-, and 25-MV attenuation curves were evaluated to determine the energy spectra of these beams. The 2-MV data indicate that the model can reliably reconstruct spectra in the low megavoltage range. Experimental limitations in acquiring the 6-MV transmission data demonstrate the sensitivity of the model to systematic experimental error. The 25-MV data result in a physically realistic approximation of the present spectrum.

  1. THE ROLE OF THE ACCRETION DISK, DUST, AND JETS IN THE IR EMISSION OF LOW-LUMINOSITY ACTIVE GALACTIC NUCLEI

    Energy Technology Data Exchange (ETDEWEB)

    Mason, R. E. [Gemini Observatory, Northern Operations Center, 670 N. A' ohoku Place, Hilo, HI 96720 (United States); Ramos Almeida, C. [Instituto de Astrofísica de Canarias, C/Vía Láctea, s/n, E-38205 La Laguna, Tenerife (Spain); Levenson, N. A. [Gemini Observatory, Southern Operations Center, c/o AURA, Casilla 603, La Serena (Chile); Nemmen, R. [NASA Goddard Space Flight Center, Greenbelt, MD 20771 (United States); Alonso-Herrero, A., E-mail: rmason@gemini.edu [Instituto de Física de Cantabria, CSIC-UC, Avenida de los Castros s/n, E-39005 Santander (Spain)

    2013-11-10

    We use recent high-resolution infrared (IR; 1-20 μm) photometry to examine the origin of the IR emission in low-luminosity active galactic nuclei (LLAGN). The data are compared with published model fits that describe the spectral energy distribution (SED) of LLAGN in terms of an advection-dominated accretion flow, truncated thin accretion disk, and jet. The truncated disk in these models is usually not luminous enough to explain the observed IR emission, and in all cases its spectral shape is much narrower than the broad IR peaks in the data. Synchrotron radiation from the jet appears to be important in very radio-loud nuclei, but the detection of strong silicate emission features in many objects indicates that dust must also contribute. We investigate this point by fitting the IR SED of NGC 3998 using dusty torus and optically thin (τ{sub mid-IR} ∼ 1) dust shell models. While more detailed modeling is necessary, these initial results suggest that dust may account for the nuclear mid-IR emission of many LLAGN.

  2. A High Energy and High Efficiency Spectral Shaping Single Frequency Fiber Laser, Phase I

    Data.gov (United States)

    National Aeronautics and Space Administration — This SBIR phase I project proposes a tunable single frequency high energy fiber laser system for coherent Lidar systems for remote sensing. Current state-of-art...

  3. A High Energy and High Efficiency Spectral Shaping Single Frequency Fiber Laser, Phase II

    Data.gov (United States)

    National Aeronautics and Space Administration — This SBIR phase II project proposes a single frequency high energy fiber laser system for coherent Lidar systems for remote sensing. Current state-of-art...

  4. The energy and spectral characteristics of a room-temperature pulsed laser on a ZnS:Fe2+ polycrystal

    Science.gov (United States)

    Firsov, K. N.; Gavrishchuk, E. M.; Ikonnikov, V. B.; Kazantsev, S. Yu; Kononov, I. G.; Kotereva, T. V.; Savin, D. V.; Timofeeva, N. A.

    2016-04-01

    The energy and spectral characteristics of a laser on a ZnS:Fe2+ polycrystal operating at room temperature have been studied. The laser was pumped by a non-chain electro-discharge HF laser with a full-width at half-maximum pulse duration of ~140 ns. The diameter of the pumping radiation spot on the crystal surface was 3.8& mm. The two-sided diffuse doping of a polycrystalline CVD-ZnS sample with the surfaces preliminarily coated by high-purity iron films was performed in the process of hot isostatic pressing (HIP) in an argon atmosphere at a pressure of 100 MPa and temperature of 1290 °C. Increasing the duration of the HIP treatment from 54 h to 72 h made it possible to obtain twice the doping depth, and correspondingly, twice the length of active medium. As a result, the slope laser efficiency with respect to the absorbed energy was raised by a factor of 1.75 as compared to the value obtained in our earlier work with a polycrystalline sample. The generation energy was 25 mJ at a slope efficiency of ηslope = 35%. It was established that the generation spectra of the laser with a non-selective resonator have a linear structure with intervals between the neighboring lines of δλ 6 ÷ 8 nm, which is spurious for solid-state lasers. The spectral structure observed is not related to the elements inside the resonator, which might form Fabry-Perot interferometers.

  5. Evaluation of dual energy spectral CT in differentiating metastatic from non-metastatic lymph nodes in rectal cancer: Initial experience

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Huanhuan [Department of Radiology, Ruijin Hospital Affiliated to Shanghai Jiaotong University, School of Medicine, Shanghai 200025 (China); Department of Radiology, Xinhua Hospital affiliated to Shanghai Jiaotong University School of Medicine (China); Yan, Fuhua; Pan, Zilai; Lin, Xiaozhu; Luo, Xianfu; Shi, Cen [Department of Radiology, Ruijin Hospital Affiliated to Shanghai Jiaotong University, School of Medicine, Shanghai 200025 (China); Chen, Xiaoyan [Department of Pathology, Ruijin Hospital Affiliated to Shanghai Jiaotong University, School of Medicine, Shanghai 200025 (China); Wang, Baisong [Department of Biomedical Statistics, Shanghai Jiaotong University, School of Medicine, Shanghai 200025 (China); Zhang, Huan, E-mail: huanzhangy@126.com [Department of Radiology, Ruijin Hospital Affiliated to Shanghai Jiaotong University, School of Medicine, Shanghai 200025 (China)

    2015-02-15

    Highlights: • Colorectal cancer is the third most prevalent cancer and the status of the regional lymph nodes in rectal cancer is considered to be one of the most powerful prognostic factor in the absence of distant metastatic disease. Detecting LNs metastasis is still a challenging problem due to the presence of microscopic metastasis or inflammatory swelling of LNs. • We investigated the value of dual energy spectral CT in differentiating metastatic from non-metastatic lymph nodes in rectal cancer. Our study demonstrated that the quantitative normalized iodine concentration (nIC) could be useful for differentiating metastatic and non-metastatic lymph nodes. The combination of nIC in portal venous phase and conventional size criterion could improve the diagnostic accuracy, sensitivity, specificity, positive predictive value and negative predictive value of rectal cancer. - Abstract: Objectives: To investigate the value of dual energy spectral CT (DEsCT) imaging in differentiating metastatic from non-metastatic lymph nodes in rectal cancer. Methods: Fifty-five patients with rectal cancer underwent the arterial phase (AP) and portal venous phase (PP) contrast-enhanced DEsCT imaging. The virtual monochromatic images and iodine-based material decomposition images derived from DEsCT imaging were interpreted for lymph nodes (LNs) measurement. The short axis diameter and the normalized iodine concentration (nIC) of metastatic and non-metastatic LNs were measured. The two-sample t test was used to compare the short axis diameters and nIC values of metastatic and non-metastatic LNs. ROC analysis was performed to assess the diagnostic performance. Results: One hundred and fifty two LNs including 92 non-metastatic LNs and 60 metastatic LNs were matched using the radiological-pathological correlation. The mean short axis diameter of metastatic LNs was significantly larger than that of the non-metastatic LNs (7.28 ± 2.28 mm vs. 4.90 ± 1.64 mm, P < 0.001). The mean n

  6. Grading and quantification of hip osteoarthritis severity by analyzing the spectral energy distribution of radiographic hip joint space

    International Nuclear Information System (INIS)

    Boniatis, I; Costaridou, L; Panayiotakis, G; Panagiotopoulos, E

    2009-01-01

    An image analysis system is proposed for the assessment of hip osteoarthritis (OA) severity. Sixty four hips (18 normal, 46 osteoarthritic), corresponding to 32 patients of unilateral or bilateral hip OA were studied. Employing custom developed software, 64 Region Of Interest (ROI) images of Hip Joint Spaces (HJSs) were delineated on patients' digitized radiographs. The Fourier spectrum of each HJS-ROI was computed and expressed in polar coordinates. Spectral signatures, quantifying the radial and angular distribution of HJS spectral energy were formed. Signature descriptors were generated and utilized in the design of a two-level hierarchical decision tree, used for the grading of the severity of the disease. Accordingly, at Level 1, implemented by a multiple classifier system, the discrimination between normal and osteoarthritic hips was performed. At Level 2, the hips that had been successfully characterized as osteoarthritic at Level 1, were further characterized as of 'Mild / Moderate' or 'Severe' OA, by the Bayes classifier. A signature descriptors based regression model was designed, so as to quantify OA-severity. The system graded OA reliably, given that the accomplished classification accuracies for Level 1 and Level 2 were 98.4% and 100%, respectively. OA-severity values, expressed by HJS-narrowing, correlated highly (r = 0.9, p < 0.001) with values predicted by the model. The system may contribute to OA-patient management.

  7. A novel construction of complex-valued Gaussian processes with arbitrary spectral densities and its application to excitation energy transfer.

    Science.gov (United States)

    Chen, Xin; Cao, Jianshu; Silbey, Robert J

    2013-06-14

    The recent experimental discoveries about excitation energy transfer (EET) in light harvesting antenna (LHA) attract a lot of interest. As an open non-equilibrium quantum system, the EET demands more rigorous theoretical framework to understand the interaction between system and environment and therein the evolution of reduced density matrix. A phonon is often used to model the fluctuating environment and convolutes the reduced quantum system temporarily. In this paper, we propose a novel way to construct complex-valued Gaussian processes to describe thermal quantum phonon bath exactly by converting the convolution of influence functional into the time correlation of complex Gaussian random field. Based on the construction, we propose a rigorous and efficient computational method, the covariance decomposition and conditional propagation scheme, to simulate the temporarily entangled reduced system. The new method allows us to study the non-Markovian effect without perturbation under the influence of different spectral densities of the linear system-phonon coupling coefficients. Its application in the study of EET in the Fenna-Matthews-Olson model Hamiltonian under four different spectral densities is discussed. Since the scaling of our algorithm is linear due to its Monte Carlo nature, the future application of the method for large LHA systems is attractive. In addition, this method can be used to study the effect of correlated initial condition on the reduced dynamics in the future.

  8. FT-Raman, FT-IR spectra and total energy distribution of 3-pentyl-2,6-diphenylpiperidin-4-one: DFT method.

    Science.gov (United States)

    Subashchandrabose, S; Saleem, H; Erdogdu, Y; Rajarajan, G; Thanikachalam, V

    2011-11-01

    FT-Raman and FT-IR spectra were recorded for 3-pentyl-2,6-diphenylpiperidin-4-one (PDPO) sample in solid state. The equilibrium geometries, harmonic vibrational frequencies, infrared and the Raman scattering intensities were computed using DFT/6-31G(d,p) level. Results obtained at this level of theory were used for a detailed interpretation of the infrared and Raman spectra, based on the total energy distribution (TED) of the normal modes. Molecular parameters such as bond lengths, bond angles and dihedral angles were calculated and compared with X-ray diffraction data. This comparison was good agreement. The intra-molecular charge transfer was calculated by means of natural bond orbital analysis (NBO). Hyperconjugative interaction energy was more during the π-π* transition. Energy gap of the molecule was found using HOMO and LUMO calculation, hence the less band gap, which seems to be more stable. Atomic charges of the carbon, nitrogen and oxygen were calculated using same level of calculation. Copyright © 2011 Elsevier B.V. All rights reserved.

  9. Nano Energy Harvesting with Plasmonic Nano-Antennas: A review of MID-IR Rectenna and Application

    Directory of Open Access Journals (Sweden)

    R. Citroni

    2017-03-01

    Full Text Available Over the past decade, unmanned air vehicles are gaining more and more interest and popularity in particular miniaturized small flight objects named NAVs (Nano Air Vehicles. One of the main considerations when building or buying a drone is the flight time and range. The flight time is nowadays a drawback for miniature unmanned aerial vehicles (UAVs. It is limited to few minutes before requiring a forced recovery to replace exhausted batteries. Currently the batteries are the dominant technology, which possess limited operation in time and energy. The real viability to extending flight time (FT of NAVs is possible exploring new and more disruptive alternative solution able either to recharge a battery, or even to directly power the NAVs during the flight. Plasmonic Nano Energy harvester is an attractive technology to extending the FT extracting the energy in mid-infrared radiation emitted from Earth’s surface with Rectenna tuned to mid-infrared wavelengths (7 –14 um with a peak wavelength of about10um . In this review the concepts emerging from this work identify and suggest how this novel harvester can constantly supply these flying objects for the whole day.

  10. The embedded young stars in the Taurus-Auriga molecular cloud. I - Models for spectral energy distributions

    Science.gov (United States)

    Kenyon, Scott J.; Calvet, Nuria; Hartmann, Lee

    1993-01-01

    We describe radiative transfer calculations of infalling, dusty envelopes surrounding pre-main-sequence stars and use these models to derive physical properties for a sample of 21 heavily reddened young stars in the Taurus-Auriga molecular cloud. The density distributions needed to match the FIR peaks in the spectral energy distributions of these embedded sources suggest mass infall rates similar to those predicted for simple thermally supported clouds with temperatures about 10 K. Unless the dust opacities are badly in error, our models require substantial departures from spherical symmetry in the envelopes of all sources. These flattened envelopes may be produced by a combination of rotation and cavities excavated by bipolar flows. The rotating infall models of Terebey et al. (1984) models indicate a centrifugal radius of about 70 AU for many objects if rotation is the only important physical effect, and this radius is reasonably consistent with typical estimates for the sizes of circumstellar disks around T Tauri stars.

  11. A standard comparison of spectral properties and energy response for a number of ultraviolet dosimeters

    International Nuclear Information System (INIS)

    Abu Kassem, I.; Bero, M.

    2013-09-01

    The radio-chromic chemical radiation dosimeters are materials that change their optical properties (Spectrique optical absorbance and optical density) due to radiation absorption. These detectors are used for dose measurements of ionizing radiation (γ and X-rays). It was established that these detectors could be used for ultraviolet radiation dose measurements. So, the aim of this work is to study and compare the metrological properties of two radiation chemical detectors, FXG gel and EBT2 Gafchromic film. The FXG gel is prepared directly at laboratory but EBT2 gafchromic film is a self developed radiation sensible film which is available as commercial product. This work focuses on realizing a comparison study between FXG and EBT2 detector metrological properties. It consists of studying optical and spectral properties of the detectors responsivity, radiation and temporal stability, linearity and total detected dose level. The results showed that the studied detectors present a very good responsivity to UVA radiation, high stability in optical absorbance under UVA radiation and good linearity over wide radiation level which contains the solar UVA radiation level reaching the earth surface. But, the EBT2 film presents two time higher total detection dose level than FXG gel, moreover, due to the simplicity of use, it was possible to test the use of EBT2 film for direct solar UVA radiation measurement. The two studied chemical detector (FXG gel and EBT2 film) provide a direct second order mathematical relation between the applied radiation dose and the optical absorbance changes with a very good approximation and suitable uncertainty (Measurement results relative dispersion is about 5%). It is possible to study the EBT2 film optical density variation as a function of UVA dose using directly a portable densitometer (author).

  12. Virtual Non-Contrast CT Using Dual-Energy Spectral CT: Feasibility of Coronary Artery Calcium Scoring.

    Science.gov (United States)

    Song, Inyoung; Yi, Jeong Geun; Park, Jeong Hee; Kim, Sung Mok; Lee, Kyung Soo; Chung, Myung Jin

    2016-01-01

    To evaluate the feasibility of coronary artery calcium scoring based on three virtual noncontrast-enhanced (VNC) images derived from single-source spectral dual-energy CT (DECT) as compared with true noncontrast-enhanced (TNC) images. This prospective study was conducted with the approval of our Institutional Review Board. Ninety-seven patients underwent noncontrast CT followed by contrast-enhanced chest CT using single-source spectral DECT. Iodine eliminated VNC images were reconstructed using two kinds of 2-material decomposition algorithms (material density iodine-water pair [MDW], material density iodine-calcium pair [MDC]) and a material suppressed algorithm (material suppressed iodine [MSI]). Two readers independently quantified calcium on VNC and TNC images. The Spearman correlation coefficient test and Bland-Altman method were used for statistical analyses. Coronary artery calcium scores from all three VNC images showed excellent correlation with those from the TNC images (Spearman's correlation coefficient [ρ] = 0.94, 0.88, and 0.89 for MDW, MDC, and MSI, respectively; p VNC images also correlated well with those from TNC images (ρ = 0.92, 0.87, and 0.91 for MDW, MDC, and MSI, respectively; p VNC images, coronary calcium from MDW correlated best with that from TNC. The coronary artery calcium scores and volumes were significantly lower from the VNC images than from the TNC images (p VNC images from contrast-enhanced CT using dual-energy material decomposition/suppression is feasible for coronary calcium scoring. The absolute value from VNC tends to be smaller than that from TNC.

  13. Atmospheric Entry Experiments at IRS

    Science.gov (United States)

    Auweter-Kurtz, M.; Endlich, P.; Herdrich, G.; Kurtz, H.; Laux, T.; Löhle, S.; Nazina, N.; Pidan, S.

    2002-01-01

    Entering the atmosphere of celestial bodies, spacecrafts encounter gases at velocities of several km/s, thereby being subjected to great heat loads. The thermal protection systems and the environment (plasma) have to be investigated by means of computational and ground facility based simulations. For more than a decade, plasma wind tunnels at IRS have been used for the investigation of TPS materials. Nevertheless, ground tests and computer simulations cannot re- place space flights completely. Particularly, entry mission phases encounter challenging problems, such as hypersonic aerothermodynamics. Concerning the TPS, radiation-cooled materials used for reuseable spacecrafts and ablator tech- nologies are of importance. Besides the mentioned technologies, there is the goal to manage guidance navigation, con- trol, landing technology and inflatable technologies such as ballutes that aim to keep vehicles in the atmosphere without landing. The requirement to save mass and energy for planned interplanetary missions such as Mars Society Balloon Mission, Mars Sample Return Mission, Mars Express or Venus Sample Return mission led to the need for manoeuvres like aerocapture, aero-breaking and hyperbolic entries. All three are characterized by very high kinetic vehicle energies to be dissipated by the manoeuvre. In this field flight data are rare. The importance of these manoeuvres and the need to increase the knowledge of required TPS designs and behavior during such mission phases point out the need of flight experiments. As result of the experience within the plasma diagnostic tool development and the plasma wind tunnel data base, flight experiments like the PYrometric RE-entry EXperiment PYREX were developed, fully qualified and successfully flown. Flight experiments such as the entry spectrometer RESPECT and PYREX on HOPE-X are in the conceptual phase. To increase knowledge in the scope of atmospheric manoeuvres and entries, data bases have to be created combining both

  14. The odd-proton effects on the potential energy surfaces of odd mass Tl, Au, Ir and Re isotopes

    CERN Document Server

    De Wieclawik, W; Larsson, S E; Leander, G; Vieu, C; Dionisio, J S

    1976-01-01

    The total potential energy surfaces of thallium, gold, iridium and rhenium odd mass isotopes are calculated microscopically as functions of the quadrupole deformation, epsilon /sub 2/, when the odd protons occupy definite orbitals. The nuclear shapes and the static equilibrium deformations of these nuclei are deduced from the results of these calculations for the proton orbitals nearest to the Fermi level. The influence of the hexadecapole deformation, epsilon /sub 4/, on these results is investigated too. Finally, a few experimental data available for these odd mass nuclei are correlated to the corresponding theoretical results. (16 refs).

  15. Application of the Cavity theory in the calibration of the powder TLD-100 for energies of 60 Co, 137 Cs, 192 Ir and RX 50, 250 k Vp

    International Nuclear Information System (INIS)

    Loaiza C, S.P.; Alvarez R, J.T.

    2006-01-01

    A powder lot TLD-100 (LiF:Mg,Ti) in absorbed dose terms in water D w for the following radiation sources: 60 Co, 137 Cs and RX 50 and 250 k Vp is calibrated; to continuation is made a lineal interpolation of the TLD response in function of the effective energy of the sources to calibrate a source of 192 Ir. The calibration of those fields in D w are carried out with aid of the Bragg-Gray cavity theory, the one which finds implicit in the following protocols: IAEA-TRS 398 for the 60 Co and the AAPM TG61 for X Rays of 50 and 250 k Vp. Additionally the AAPM protocol TG43 to determine the D w in function of the kerma intensity S k in the case of the 137 Cs is used. The calibration curves for the response of the TLD-100 R TLD vs D w , corresponding to each one of the sources already mentioned are constructed. The R TLD vs D w by least heavy square by means of a second order polynomial that corrects the supralineality of the response is adjusted. The curves are validated by lack of LOF adjustment and by the Anderson Darling normality test. Later the factors of sensitivity (F s ) for the sources of 192 Ir: Micro Selectron and Vari Source are interpolated, used respectively in the A and B hospitals for treatments of brachytherapy of high dose rate (HDR), the expanded uncertainties associated to the D w and F s are also determined. Finally, an acrylic phantom and a couple of capsules are already sent to the hospitals mentioned, to verify a nominal D w of 2 Gy, in a case an underestimate in 5.5% in the imparted D w and in other an overestimation in a range of -1.5 to -8.0% was obtained. The obtained results in this work establish the bases for the development of a national dosimetric quality control program for brachytherapy of HDR with sources of 192 Ir. (Author)

  16. Plasma jet in M87: energy balance and the spectral index

    International Nuclear Information System (INIS)

    Galeev, A.A.

    1985-01-01

    The author's theory of ultrarelativistic-electron acceleration through Cerenkov resonance with magnetoacoustic waves that are generated by an ion beam reflected from a shock front is applied to calculate the parameters and radiation spectrum of the plasma jet emerging from the nucleus of the galaxy M87. The abrupt steepening of the optical spectrum toward short wavelengths may indicate that the higher-energy electrons, accelerated predominantly along the magnetic fieldlines, are experiencing too little scattering with respect to pitch angle. In the soft x-ray range the spectrum flattens again because MHD turbulence in the plasma jet reinstates the pitch-angle scattering. At the highest energies, synchrotron losses once more steepen the spectrum

  17. High efficiency thermal to electric energy conversion using selective emitters and spectrally tuned solar cells

    Science.gov (United States)

    Chubb, Donald L.; Flood, Dennis J.; Lowe, Roland A.

    1992-01-01

    Thermophotovoltaic (TPV) systems are attractive possibilities for direct thermal-to-electric energy conversion, but have typically required the use of black body radiators operating at high temperatures. Recent advances in both the understanding and performance of solid rare-earth oxide selective emitters make possible the use of TPV at temperatures as low as 1500 K. Depending on the nature of parasitic losses, overall thermal-to-electric conversion efficiencies greater than 20 percent are feasible.

  18. Spectral correction factors for conventional neutron dosemeters used in high-energy neutron environments

    International Nuclear Information System (INIS)

    Lee, K.W.; Sheu, R.J.

    2015-01-01

    High-energy neutrons (>10 MeV) contribute substantially to the dose fraction but result in only a small or negligible response in most conventional moderated-type neutron detectors. Neutron dosemeters used for radiation protection purpose are commonly calibrated with 252 Cf neutron sources and are used in various workplace. A workplace-specific correction factor is suggested. In this study, the effect of the neutron spectrum on the accuracy of dose measurements was investigated. A set of neutron spectra representing various neutron environments was selected to study the dose responses of a series of Bonner spheres, including standard and extended-range spheres. By comparing 252 Cf-calibrated dose responses with reference values based on fluence-to-dose conversion coefficients, this paper presents recommendations for neutron field characterisation and appropriate correction factors for responses of conventional neutron dosemeters used in environments with high-energy neutrons. The correction depends on the estimated percentage of high-energy neutrons in the spectrum or the ratio between the measured responses of two Bonner spheres (the 4P6-8 extended-range sphere versus the 6'' standard sphere). (authors)

  19. Energy Levels and Spectral Lines of Li Atoms in White Dwarf Strength Magnetic Fields

    Science.gov (United States)

    Zhao, L. B.

    2018-04-01

    A theoretical approach based on B-splines has been developed to calculate atomic structures and discrete spectra of Li atoms in a strong magnetic field typical of magnetic white dwarf stars. Energy levels are presented for 20 electronic states with the symmetries 20+, 20‑, 2(‑1)+, 2(‑1)‑, and 2(‑2)+. The magnetic field strengths involved range from 0 to 2350 MG. The wavelengths and oscillator strengths for the electric dipole transitions relevant to these magnetized atomic states are reported. The current results are compared to the limited theoretical data in the literature. A good agreement has been found for the lower energy levels, but a significant discrepancy is clearly visible for the higher energy levels. The existing discrepancies of the wavelengths and oscillator strengths are also discussed. Our investigation shows that the spectrum data of magnetized Li atoms previously published are obviously far from meeting requirements of analyzing discrete atomic spectra of magnetic white dwarfs with lithium atmospheres.

  20. X-ray dual energy spectral parameter optimization for bone Calcium/Phosphorus mass ratio estimation

    International Nuclear Information System (INIS)

    Sotiropoulou, P I; Martini, N D; Koukou, V N; Nikiforidis, G C; Fountos, G P; Michail, C M; Valais, I G; Kandarakis, I S

    2015-01-01

    Calcium (Ca) and Phosphorus (P) bone mass ratio has been identified as an important, yet underutilized, risk factor in osteoporosis diagnosis. The purpose of this simulation study is to investigate the use of effective or mean mass attenuation coefficient in Ca/P mass ratio estimation with the use of a dual-energy method. The investigation was based on the minimization of the accuracy of Ca/P ratio, with respect to the Coefficient of Variation of the ratio. Different set-ups were examined, based on the K-edge filtering technique and single X-ray exposure. The modified X-ray output was attenuated by various Ca/P mass ratios resulting in nine calibration points, while keeping constant the total bone thickness. The simulated data were obtained considering a photon counting energy discriminating detector. The standard deviation of the residuals was used to compare and evaluate the accuracy between the different dual energy set-ups. The optimum mass attenuation coefficient for the Ca/P mass ratio estimation was the effective coefficient in all the examined set-ups. The variation of the residuals between the different set-ups was not significant. (paper)

  1. Determination of urinary stone composition using dual-energy spectral CT: Initial in vitro analysis

    International Nuclear Information System (INIS)

    Li, X.-H.; Zhao, R.; Liu, B.; Yu, Y.-Q.

    2013-01-01

    Aim: To evaluate the feasibility of determining the chemical composition of urinary stones using computed tomography (CT) spectral imaging (SI) Materials and methods: Two hundred and ten urinary stones were scanned in vitro using the SI mode and conventional polychromatic imaging (CPI; 120 kVp) mode. The radiodensity at 50 keV and 120 kVp, the mean calcium density (CD), and the water density (WD) were measured using the 50 keV images, 120 kVp images, calcium-based images, and water-based images, respectively. These parameters and the calcium–water ratio (CWR) were compared between different types of stones. CWR was defined as: CWR = ‌calcium density/water density‌. Results: According to the results determined by infrared spectroscopy, 116 pure urinary stones were divided into five groups: uric acid (UA, n = 16), struvite (STR, n = 23), cystine (CYS, n = 10), calcium phosphate (CaP, n = 29), and calcium oxalate (COX, n = 38). CD, CWR, and the radiodensity of stones at 50 keV CT imaging of each group were as follows: UA (−3.55 ± 10.85 mg/ml, 0.03 ± 0.05, 510.08 ± 157.29 HU); STR (224.99 ± 64.28 mg/ml, 0.19 ± 0.07, 1058.58 ± 260.13 HU); CYS (139.67 ± 34.66 mg/ml, 0.13 ± 0.03, 725.75 ± 142.35 HU); CaP (619.39 ± 26.13 mg/ml, 0.69 ± 0.11, 2617.46 ± 186.22 HU); COX (518.61 ± 95.5 mg/ml, 0.58 ± 0.1, 2247.47 ± 379.51 HU). The differences in the CD, CRW, and radiodensity of stones at 50 keV CT imaging among the groups were statistically significant by binary comparison (p < 0.05). There were no significant differences in the radiodensity of stones at 120 keV CT imaging between UA and CYS (p = 0.267), CaP and COX (p = 0.065), and in the WD between STR and CYS (p = 0.108). Conclusion: SI provides a novel method to better characterize pure urinary stones using the mean CD, CWR, and the radiodensity of stones at 50 keV CT imaging

  2. Investigation of energy band alignments and interfacial properties of rutile NMO2/TiO2 (NM = Ru, Rh, Os, and Ir) by first-principles calculations.

    Science.gov (United States)

    Yang, Chen; Zhao, Zong-Yan

    2017-11-08

    In the field of photocatalysis, constructing hetero-structures is an efficient strategy to improve quantum efficiency. However, a lattice mismatch often induces unfavorable interfacial states that can act as recombination centers for photo-generated electron-hole pairs. If the hetero-structure's components have the same crystal structure, this disadvantage can be easily avoided. Conversely, in the process of loading a noble metal co-catalyst onto the TiO 2 surface, a transition layer of noble metal oxides is often formed between the TiO 2 layer and the noble metal layer. In this article, interfacial properties of hetero-structures composed of a noble metal dioxide and TiO 2 with a rutile crystal structure have been systematically investigated using first-principles calculations. In particular, the Schottky barrier height, band bending, and energy band alignments are studied to provide evidence for practical applications. In all cases, no interfacial states exist in the forbidden band of TiO 2 , and the interfacial formation energy is very small. A strong internal electric field generated by interfacial electron transfer leads to an efficient separation of photo-generated carriers and band bending. Because of the differences in the atomic properties of the components, RuO 2 /TiO 2 and OsO 2 /TiO 2 hetero-structures demonstrate band dividing, while RhO 2 /TiO 2 and IrO 2 /TiO 2 hetero-structures have a pseudo-gap near the Fermi energy level. Furthermore, NMO 2 /TiO 2 hetero-structures show upward band bending. Conversely, RuO 2 /TiO 2 and OsO 2 /TiO 2 hetero-structures present a relatively strong infrared light absorption, while RhO 2 /TiO 2 and IrO 2 /TiO 2 hetero-structures show an obvious absorption edge in the visible light region. Overall, considering all aspects of their properties, RuO 2 /TiO 2 and OsO 2 /TiO 2 hetero-structures are more suitable than others for improving the photocatalytic performance of TiO 2 . These findings will provide useful information

  3. 3D modeling of satellite spectral images, radiation budget and energy budget of urban landscapes

    Science.gov (United States)

    Gastellu-Etchegorry, J. P.

    2008-12-01

    DART EB is a model that is being developed for simulating the 3D (3 dimensional) energy budget of urban and natural scenes, possibly with topography and atmosphere. It simulates all non radiative energy mechanisms (heat conduction, turbulent momentum and heat fluxes, water reservoir evolution, etc.). It uses DART model (Discrete Anisotropic Radiative Transfer) for simulating radiative mechanisms: 3D radiative budget of 3D scenes and their remote sensing images expressed in terms of reflectance or brightness temperature values, for any atmosphere, wavelength, sun/view direction, altitude and spatial resolution. It uses an innovative multispectral approach (ray tracing, exact kernel, discrete ordinate techniques) over the whole optical domain. This paper presents two major and recent improvements of DART for adapting it to urban canopies. (1) Simulation of the geometry and optical characteristics of urban elements (houses, etc.). (2) Modeling of thermal infrared emission by vegetation and urban elements. The new DART version was used in the context of the CAPITOUL project. For that, districts of the Toulouse urban data base (Autocad format) were translated into DART scenes. This allowed us to simulate visible, near infrared and thermal infrared satellite images of Toulouse districts. Moreover, the 3D radiation budget was used by DARTEB for simulating the time evolution of a number of geophysical quantities of various surface elements (roads, walls, roofs). Results were successfully compared with ground measurements of the CAPITOUL project.

  4. Photosystem Trap Energies and Spectrally-Dependent Energy-Storage Efficiencies in the Chl d-Utilizing Cyanobacterium, Acaryochloris Marina

    Science.gov (United States)

    Mielke, Steven P.; Kiang, Nancy Y.; Blankenship, Robert E.; Mauzerall, David

    2012-01-01

    Acaryochloris marina is the only species known to utilize chlorophyll (Chl) d as a principal photopigment. The peak absorption wavelength of Chl d is redshifted approx. 40 nm in vivo relative to Chl a, enabling this cyanobacterium to perform oxygenic phototrophy in niche environments enhanced in far-red light. We present measurements of the in vivo energy-storage (E-S) efficiency of photosynthesis in A. marina, obtained using pulsed photoacoustics (PA) over a 90-nm range of excitation wavelengths in the red and far-red. Together with modeling results, these measurements provide the first direct observation of the trap energies of PSI and PSII, and also the photosystem-specific contributions to the total E-S efficiency. We find the maximum observed efficiency in A. marina (40+/-1% at 735 nm) is higher than in the Chl a cyanobacterium Synechococcus leopoliensis (35+/-1% at 690 nm). The efficiency at peak absorption wavelength is also higher in A. marina (36+/-1% at 710 nm vs. 31+/-1% at 670 nm). In both species, the trap efficiencies are approx. 40% (PSI) and approx. 30% (PSII). The PSI trap in A. marina is found to lie at 740+/-5 nm, in agreement with the value inferred from spectroscopic methods. The best fit of the model to the PA data identifies the PSII trap at 723+/-3 nm, supporting the view that the primary electron-donor is Chl d, probably at the accessory (ChlD1) site. A decrease in efficiency beyond the trap wavelength, consistent with uphill energy transfer, is clearly observed and fit by the model. These results demonstrate that the E-S efficiency in A. marina is not thermodynamically limited, suggesting that oxygenic photosynthesis is viable in even redder light environments.

  5. High-energy kHz mid-IR tunable PPSLT-based OPO pumped at 1064 nm

    Energy Technology Data Exchange (ETDEWEB)

    Gaydardzhiev, A; Chuchumishev, D; Draganov, D; Buchvarov, I [Department of Physics, Sofia University, 5 James Bourchier Blvd., BG-1164, Sofia (Bulgaria)

    2012-06-30

    We report a single-frequency sub-nanosecond optical parametric oscillator (OPO) based on periodically poled stoichiometric lithium tantalate (PPSLT), pumped by a 1064-nm amplified microchip laser at a repetition rate of 0.5 kHz. Using a 11-mm-long PPSLT crystal polled with three different domain periods (30.2, 30.3, 30.4 {mu}m) and changing the temperature of the crystal from 20 Degree-Sign C to 265 Degree-Sign C, we have achieved wavelength tuning between 2990 nm and 3500 nm. The high nonlinearity of the used medium and the large aperture (2 mm) ensure the maximum idler output energy of {approx}0.5 mJ in the whole tuning range, corresponding to average {approx}10.5 % idler conversion efficiency and {approx}250 mW of average power. Sub-nanosecond pulse durations have been obtained for the idler at 0.88-ns pulse duration of the pump.

  6. Low energy spectral index and Ep evolution of quasi-thermal photosphere emission of gamma-ray bursts

    International Nuclear Information System (INIS)

    Deng, Wei; Zhang, Bing

    2014-01-01

    Recent observations by the Fermi satellite suggest that a photosphere emission component is contributing to the observed spectrum of many gamma-ray bursts (GRBs). One important question is whether the photosphere component can interpret the typical 'Band' function of GRBs with a typical low energy photon spectral index α ∼ –1. We perform a detailed study of the photosphere emission spectrum by progressively introducing several physical ingredients previously not fully incorporated, including the probability distribution of the location of a dynamically evolving photosphere, superposition of emission from an equal arrival time 'volume' in a continuous wind, the evolution of optical depth of a wind with finite but evolving outer boundary, as well as the effect of different top-hat wind luminosity (L w ) profiles. By assuming a comoving blackbody spectrum emerging from the photosphere, we find that for an outflow with a constant or increasing L w , the low-energy spectrum below the peak energy (E p ), can be modified to F ν ∼ ν 1.5 (α ∼ +0.5). A softer (–1 < α < +0.5) or flat (α = –1) spectrum can be obtained during the L w decreasing phase or high-latitude-emission-dominated phase. We also study the evolution of E p as a function of wind and photosphere luminosity in this photosphere model. An E p – L tracking pattern can be reproduced if a certain positive dependence between the dimensionless entropy η and L w is introduced. However, the hard-to-soft evolution pattern cannot be reproduced unless a contrived condition is invoked. In order to interpret the Band spectrum, a more complicated photosphere model or a different energy dissipation and radiation mechanism is needed.

  7. Observational study on the fine structure and dynamics of a solar jet. II. Energy release process revealed by spectral analysis

    Science.gov (United States)

    Sakaue, Takahito; Tei, Akiko; Asai, Ayumi; Ueno, Satoru; Ichimoto, Kiyoshi; Shibata, Kazunari

    2018-01-01

    We report on a solar jet phenomenon associated with the C5.4 class flare on 2014 November 11. The data of the jet was provided by the Solar Dynamics Observatory, the X-Ray Telescope (XRT) aboard Hinode, and the Interface Region Imaging Spectrograph and Domeless Solar Telescope (DST) at Hida Observatory, Kyoto University. These plentiful data enabled us to present this series of papers to discuss all the processes of the observed phenomena, including energy storage, event trigger, and energy release. In this paper, we focus on the energy release process of the observed jet, and mainly describe our spectral analysis on the Hα data of DST to investigate the internal structure of the Hα jet and its temporal evolution. This analysis reveals that in the physical quantity distributions of the Hα jet, such as line-of-sight velocity and optical thickness, there is a significant gradient in the direction crossing the jet. We interpret this internal structure as the consequence of the migration of the energy release site, based on the idea of ubiquitous reconnection. Moreover, by measuring the horizontal flow of the fine structures in the jet, we succeeded in deriving the three-dimensional velocity field and the line-of-sight acceleration field of the Hα jet. The analysis result indicates that part of the ejecta in the Hα jet experienced additional acceleration after it had been ejected from the lower atmosphere. This secondary acceleration was found to occur in the vicinity of the intersection between the trajectories of the Hα jet and the X-ray jet observed by Hinode/XRT. We propose that a fundamental cause of this phenomenon is magnetic reconnection involving the plasmoid in the observed jet.

  8. DUST SPECTRAL ENERGY DISTRIBUTIONS IN THE ERA OF HERSCHEL AND PLANCK: A HIERARCHICAL BAYESIAN-FITTING TECHNIQUE

    International Nuclear Information System (INIS)

    Kelly, Brandon C.; Goodman, Alyssa A.; Shetty, Rahul; Stutz, Amelia M.; Launhardt, Ralf; Kauffmann, Jens

    2012-01-01

    We present a hierarchical Bayesian method for fitting infrared spectral energy distributions (SEDs) of dust emission to observed fluxes. Under the standard assumption of optically thin single temperature (T) sources, the dust SED as represented by a power-law-modified blackbody is subject to a strong degeneracy between T and the spectral index β. The traditional non-hierarchical approaches, typically based on χ 2 minimization, are severely limited by this degeneracy, as it produces an artificial anti-correlation between T and β even with modest levels of observational noise. The hierarchical Bayesian method rigorously and self-consistently treats measurement uncertainties, including calibration and noise, resulting in more precise SED fits. As a result, the Bayesian fits do not produce any spurious anti-correlations between the SED parameters due to measurement uncertainty. We demonstrate that the Bayesian method is substantially more accurate than the χ 2 fit in recovering the SED parameters, as well as the correlations between them. As an illustration, we apply our method to Herschel and submillimeter ground-based observations of the star-forming Bok globule CB244. This source is a small, nearby molecular cloud containing a single low-mass protostar and a starless core. We find that T and β are weakly positively correlated—in contradiction with the χ 2 fits, which indicate a T-β anti-correlation from the same data set. Additionally, in comparison to the χ 2 fits the Bayesian SED parameter estimates exhibit a reduced range in values.

  9. The Spectral Energy Distributions of z ~ 8 Galaxies from the IRAC Ultra Deep Fields: Emission Lines, Stellar Masses, and Specific Star Formation Rates at 650 Myr

    Science.gov (United States)

    Labbé, I.; Oesch, P. A.; Bouwens, R. J.; Illingworth, G. D.; Magee, D.; González, V.; Carollo, C. M.; Franx, M.; Trenti, M.; van Dokkum, P. G.; Stiavelli, M.

    2013-11-01

    Using new ultradeep Spitzer/InfraRed Array Camera (IRAC) photometry from the IRAC Ultra Deep Field program, we investigate the stellar populations of a sample of 63 Y-dropout galaxy candidates at z ~ 8, only 650 Myr after the big bang. The sources are selected from HST/ACS+WFC3/IR data over the Hubble Ultra Deep Field (HUDF), two HUDF parallel fields, and wide area data over the CANDELS/GOODS-South. The new Spitzer/IRAC data increase the coverage in [3.6] and [4.5] to ~120h over the HUDF reaching depths of ~28 (AB,1σ). The improved depth and inclusion of brighter candidates result in direct >=3σ InfraRed Array Camera (IRAC) detections of 20/63 sources, of which 11/63 are detected at >=5σ. The average [3.6]-[4.5] colors of IRAC detected galaxies at z ~ 8 are markedly redder than those at z ~ 7, observed only 130 Myr later. The simplest explanation is that we witness strong rest-frame optical emission lines (in particular [O III] λλ4959, 5007 + Hβ) moving through the IRAC bandpasses with redshift. Assuming that the average rest-frame spectrum is the same at both z ~ 7 and z ~ 8 we estimate a rest-frame equivalent width of {W}_{[O\\,\\scriptsize{III}]\\ \\lambda \\lambda 4959,5007+H\\beta }=670^{+260}_{-170} Å contributing 0.56^{+0.16}_{-0.11} mag to the [4.5] filter at z ~ 8. The corresponding {W}_{H\\alpha }=430^{+160}_{-110} Å implies an average specific star formation rate of sSFR=11_{-5}^{+11} Gyr-1 and a stellar population age of 100_{-50}^{+100} Myr. Correcting the spectral energy distribution for the contribution of emission lines lowers the average best-fit stellar masses and mass-to-light ratios by ~3 ×, decreasing the integrated stellar mass density to \\rho ^*(z=8,M_{\\rm{UV}}Universities for Research in Astronomy, Inc., under NASA contract NAS 5-26555. These observations are associated with programs #11563, 9797. Based on observations with the Spitzer Space Telescope, which is operated by the Jet Propulsion Laboratory, California Institute of

  10. THE SPECTRAL ENERGY DISTRIBUTIONS OF z ∼ 8 GALAXIES FROM THE IRAC ULTRA DEEP FIELDS: EMISSION LINES, STELLAR MASSES, AND SPECIFIC STAR FORMATION RATES AT 650 MYR

    Energy Technology Data Exchange (ETDEWEB)

    Labbé, I.; Bouwens, R. J.; Franx, M. [Leiden Observatory, Leiden University, NL-2300 RA Leiden (Netherlands); Oesch, P. A.; Illingworth, G. D.; Magee, D.; González, V. [UCO/Lick Observatory, University of California, Santa Cruz, CA 95064 (United States); Carollo, C. M. [Institute for Astronomy, ETH Zurich, 8092 Zurich (Switzerland); Trenti, M. [Kavli Institute for Cosmology and Institute of Astronomy, University of Cambridge, Cambridge (United Kingdom); Van Dokkum, P. G. [Department of Astronomy, Yale University, New Haven, CT 06520 (United States); Stiavelli, M. [Space Telescope Science Institute, Baltimore, MD 21218 (United States)

    2013-11-10

    Using new ultradeep Spitzer/InfraRed Array Camera (IRAC) photometry from the IRAC Ultra Deep Field program, we investigate the stellar populations of a sample of 63 Y-dropout galaxy candidates at z ∼ 8, only 650 Myr after the big bang. The sources are selected from HST/ACS+WFC3/IR data over the Hubble Ultra Deep Field (HUDF), two HUDF parallel fields, and wide area data over the CANDELS/GOODS-South. The new Spitzer/IRAC data increase the coverage in [3.6] and [4.5] to ∼120h over the HUDF reaching depths of ∼28 (AB,1σ). The improved depth and inclusion of brighter candidates result in direct ≥3σ InfraRed Array Camera (IRAC) detections of 20/63 sources, of which 11/63 are detected at ≥5σ. The average [3.6]-[4.5] colors of IRAC detected galaxies at z ∼ 8 are markedly redder than those at z ∼ 7, observed only 130 Myr later. The simplest explanation is that we witness strong rest-frame optical emission lines (in particular [O III] λλ4959, 5007 + Hβ) moving through the IRAC bandpasses with redshift. Assuming that the average rest-frame spectrum is the same at both z ∼ 7 and z ∼ 8 we estimate a rest-frame equivalent width of contributing 0.56{sup +0.16}{sub -0.11} mag to the [4.5] filter at z ∼ 8. The corresponding W{sub Hα}=430{sup +160}{sub -110} Å implies an average specific star formation rate of sSFR=11{sub -5}{sup +11} Gyr{sup –1} and a stellar population age of 100{sub -50}{sup +100} Myr. Correcting the spectral energy distribution for the contribution of emission lines lowers the average best-fit stellar masses and mass-to-light ratios by ∼3 ×, decreasing the integrated stellar mass density to ρ{sup *}(z=8,M{sub UV}<-18)=0.6{sup +0.4}{sub -0.3}×10{sup 6} M{sub sun} Mpc{sup –3}.

  11. The B3-VLA CSS sample. VIII. New optical identifications from the Sloan Digital Sky Survey The ultraviolet-optical spectral energy distribution of the young radio sources

    Science.gov (United States)

    Fanti, C.; Fanti, R.; Zanichelli, A.; Dallacasa, D.; Stanghellini, C.

    2011-04-01

    Context. Compact steep-spectrum radio sources and giga-hertz peaked spectrum radio sources (CSS/GPS) are generally considered to be mostly young radio sources. In recent years we studied at many wavelengths a sample of these objects selected from the B3-VLA catalog: the B3-VLA CSS sample. Only ≈60% of the sources were optically identified. Aims: We aim to increase the number of optical identifications and study the properties of the host galaxies of young radio sources. Methods: We cross-correlated the CSS B3-VLA sample with the Sloan Digital Sky Survey (SDSS), DR7, and complemented the SDSS photometry with available GALEX (DR 4/5 and 6) and near-IR data from UKIRT and 2MASS. Results: We obtained new identifications and photometric redshifts for eight faint galaxies and for one quasar and two quasar candidates. Overall we have 27 galaxies with SDSS photometry in five bands, for which we derived the ultraviolet-optical spectral energy distribution (UV-O-SED). We extended our investigation to additional CSS/GPS selected from the literature. Most of the galaxies show an excess of ultra-violet (UV) radiation compared with the UV-O-SED of local radio-quiet ellipticals. We found a strong dependence of the UV excess on redshift and analyzed it assuming that it is generated either from the nucleus (hidden quasar) or from a young stellar population (YSP). We also compare the UV-O-SEDs of our CSS/GPS sources with those of a selection of large size (LSO) powerful radio sources from the literature. Conclusions: If the major process of the UV excess is caused by a YSP, our conclusion is that it is the result of the merger process that also triggered the onset of the radio source with some time delay. We do not see evidence for a major contribution from a YSP triggered by the radio sources itself. Appendices A-G are only available in electronic form at http://www.aanda.org

  12. 2.5 TW, two-cycle IR laser pulses via frequency domain optical parametric amplification.

    Science.gov (United States)

    Gruson, V; Ernotte, G; Lassonde, P; Laramée, A; Bionta, M R; Chaker, M; Di Mauro, L; Corkum, P B; Ibrahim, H; Schmidt, B E; Legaré, F

    2017-10-30

    Broadband optical parametric amplification in the IR region has reached a new milestone through the use of a non-collinear Frequency domain Optical Parametric Amplification system. We report a laser source delivering 11.6 fs pulses with 30 mJ of energy at a central wavelength of 1.8 μm at 10 Hz repetition rate corresponding to a peak power of 2.5 TW. The peak power scaling is accompanied by a pulse shortening of about 20% upon amplification due to the spectral reshaping with higher gain in the spectral wings. This source paves the way for high flux soft X-ray pulses and IR-driven laser wakefield acceleration.

  13. Energy dispersive CdTe and CdZnTe detectors for spectral clinical CT and NDT applications

    Energy Technology Data Exchange (ETDEWEB)

    Barber, W.C., E-mail: william.barber@dxray.com [DxRay, Inc., Northridge, CA (United States); Interon AS, Asker (Norway); Wessel, J.C. [DxRay, Inc., Northridge, CA (United States); Interon AS, Asker (Norway); Nygard, E. [Interon AS, Asker (Norway); Iwanczyk, J.S. [DxRay, Inc., Northridge, CA (United States)

    2015-06-01

    We are developing room temperature compound semiconductor detectors for applications in energy-resolved high-flux single x-ray photon-counting spectral computed tomography (CT), including functional imaging with nanoparticle contrast agents for medical applications and non-destructive testing (NDT) for security applications. Energy-resolved photon-counting can provide reduced patient dose through optimal energy weighting for a particular imaging task in CT, functional contrast enhancement through spectroscopic imaging of metal nanoparticles in CT, and compositional analysis through multiple basis function material decomposition in CT and NDT. These applications produce high input count rates from an x-ray generator delivered to the detector. Therefore, in order to achieve energy-resolved single photon counting in these applications, a high output count rate (OCR) for an energy-dispersive detector must be achieved at the required spatial resolution and across the required dynamic range for the application. The required performance in terms of the OCR, spatial resolution, and dynamic range must be obtained with sufficient field of view (FOV) for the application thus requiring the tiling of pixel arrays and scanning techniques. Room temperature cadmium telluride (CdTe) and cadmium zinc telluride (CdZnTe) compound semiconductors, operating as direct conversion x-ray sensors, can provide the required speed when connected to application specific integrated circuits (ASICs) operating at fast peaking times with multiple fixed thresholds per pixel provided the sensors are designed for rapid signal formation across the x-ray energy ranges of the application at the required energy and spatial resolutions, and at a sufficiently high detective quantum efficiency (DQE). We have developed high-flux energy-resolved photon-counting x-ray imaging array sensors using pixellated CdTe and CdZnTe semiconductors optimized for clinical CT and security NDT. We have also fabricated high

  14. The value of energy spectral CT in the differential diagnosis between benign and malignant soft tissue masses of the musculoskeletal system

    Energy Technology Data Exchange (ETDEWEB)

    Sun, Xin [Department of Radiology, The Affiliated Hospital of Qingdao University, Qingdao, Shandong (China); Shao, Xiaodong [Department of Radiology, Qingdao Municipal Hospital, Qingdao, Shandong (China); Chen, Haisong, E-mail: chsEJR@163.com [Department of Radiology, The Affiliated Hospital of Qingdao University, Qingdao, Shandong (China)

    2015-06-15

    Highlights: • Different types of tissues have different types of spectral curves. • We find that spectral curve is useful in the differential diagnosis of benign and malignant tumor of the musculoskeletal system. • Arc shaped curve is a specific sign for tumors containing abundant fat. - Abstract: Objective: To explore the value of energy spectral CT in the differential diagnosis between benign and malignant tumor of the musculoskeletal system. Methods: Energy spectral CT scan was performed on 100 patients with soft tissue mass caused by musculoskeletal tumors found by MRI. Solid areas with homogenous density were chosen as region of interests (ROI), avoiding necrosis, hemorrhage and calcification region. Select the optimal keV on single energy images, and then the keV–CT curve was automatically generated. All 100 cases of tumors proved by histological examination were divided into four groups, 38 cases were in benign group, 10 cases in borderline group, 49 cases in malignant group, and 3 cases of lipoma (that were analyzed separately since its curve was arc shaped, significantly different from other curves). The formula used to calculate the slope of spectral curve was as follows: slope = (Hu40 keV − Hu80 keV)/40. As the slope was steep within the range of 40–80 keV based on preliminary observations, 40 keV and 80 keV were used as the reference points to calculate the slope value of the energy spectral curve. Kruskal–Wallis rank sum test was applied for statistical analysis, and P < 0.05 was considered to indicate a statistically significant difference. Results: The spectral curve of benign group was gradually falling type with a mean slope of 0.75 ± 0.30, that of malignant group was sharply falling type with a mean slope of 1.64 ± 1.00, and that of borderline group was a falling type between the above two groups with a mean slope of 1.34 ± 0.45. The differences of slopes between benign and malignant group, benign and borderline group were of

  15. WE-FG-207B-03: Multi-Energy CT Reconstruction with Spatial Spectral Nonlocal Means Regularization

    Energy Technology Data Exchange (ETDEWEB)

    Li, B [University of Texas Southwestern Medical Center, Dallas, TX (United States); Southern Medical University, Guangzhou, Guangdong (China); Shen, C; Ouyang, L; Yang, M; Jiang, S; Jia, X [University of Texas Southwestern Medical Center, Dallas, TX (United States); Zhou, L [Southern Medical University, Guangzhou, Guangdong (China)

    2016-06-15

    Purpose: Multi-energy computed tomography (MECT) is an emerging application in medical imaging due to its ability of material differentiation and potential for molecular imaging. In MECT, image correlations at different spatial and channels exist. It is desirable to incorporate these correlations in reconstruction to improve image quality. For this purpose, this study proposes a MECT reconstruction technique that employes spatial spectral non-local means (ssNLM) regularization. Methods: We consider a kVp-switching scanning method in which source energy is rapidly switched during data acquisition. For each energy channel, this yields projection data acquired at a number of angles, whereas projection angles among channels are different. We formulate the reconstruction task as an optimziation problem. A least square term enfores data fidelity. A ssNLM term is used as regularization to encourage similarities among image patches at different spatial locations and channels. When comparing image patches at different channels, intensity difference were corrected by a transformation estimated via histogram equalization during the reconstruction process. Results: We tested our method in a simulation study with a NCAT phantom and an experimental study with a Gammex phantom. For comparison purpose, we also performed reconstructions using conjugate-gradient least square (CGLS) method and conventional NLM method that only considers spatial correlation in an image. ssNLM is able to better suppress streak artifacts. The streaks are along different projection directions in images at different channels. ssNLM discourages this dissimilarity and hence removes them. True image structures are preserved in this process. Measurements in regions of interests yield 1.1 to 3.2 and 1.5 to 1.8 times higher contrast to noise ratio than the NLM approach. Improvements over CGLS is even more profound due to lack of regularization in the CGLS method and hence amplified noise. Conclusion: The

  16. The value of energy spectral CT in the differential diagnosis between benign and malignant soft tissue masses of the musculoskeletal system.

    Science.gov (United States)

    Sun, Xin; Shao, Xiaodong; Chen, Haisong

    2015-06-01

    To explore the value of energy spectral CT in the differential diagnosis between benign and malignant tumor of the musculoskeletal system. Energy spectral CT scan was performed on 100 patients with soft tissue mass caused by musculoskeletal tumors found by MRI. Solid areas with homogenous density were chosen as region of interests (ROI), avoiding necrosis, hemorrhage and calcification region. Select the optimal keV on single energy images, and then the keV-CT curve was automatically generated. All 100 cases of tumors proved by histological examination were divided into four groups, 38 cases were in benign group, 10 cases in borderline group, 49 cases in malignant group, and 3 cases of lipoma (that were analyzed separately since its curve was arc shaped, significantly different from other curves). The formula used to calculate the slope of spectral curve was as follows: slope=(Hu40 keV-Hu80 keV)/40. As the slope was steep within the range of 40-80 keV based on preliminary observations, 40 keV and 80 keV were used as the reference points to calculate the slope value of the energy spectral curve. Kruskal-Wallis rank sum test was applied for statistical analysis, and Pbenign and malignant group, benign and borderline group were of statistical significance (Pbenign and malignant tumor of the musculoskeletal system. Arc shaped curve is a specific sign for tumors containing abundant fat. Copyright © 2015 Elsevier Ireland Ltd. All rights reserved.

  17. Oxadiazole-carbazole polymer (POC)-Ir(ppy)3 tunable emitting composites

    Science.gov (United States)

    Bruno, Annalisa; Borriello, Carmela; Di Luccio, Tiziana; Sessa, Lucia; Concilio, Simona; Haque, Saif A.; Minarini, Carla

    2017-04-01

    POC polymer is an oxadiazole-carbazole copolymer we have previously synthetized and established as light emitting material in Organic Light Emitting Devices (OLEDs), although POC quantum yield emission efficiency and color purity still need to be enhanced. On the other hand, tris[2-phenylpyridinato-C2,N]iridium(III) (Ir(ppy)3) complexes, namely Ir(ppy)3 are among the brightest luminophores employed in green light emitting devices. Our aim, in this work, is to take advantage of Ir(ppy)3 bright emission by combining the Ir complex with blue emitting POC to obtain tunable light emitting composites over a wide range of the visible spectrum. Here we have investigated the optical proprieties POC based nanocomposites with different concentrations of Ir(ppy)3, ranging from 1 to 10 wt%. Both spectral and time resolved fluorescence measurements show an efficient energy transfer from the polymer to the dopants, resulting in white-emitting composites. The most intense and stable emission has been found when POC was doped with about 5 wt% concentration of Ir(ppy)3.

  18. Study on IR Properties of Reduced Graphene Oxide

    Science.gov (United States)

    Ma, Deyue; Li, Xiaoxia; Guo, Yuxiang; Zeng, Yurun

    2018-01-01

    Firstly, the reduced graphene oxide was prepared by modified hummer method and characterized. Then, the complex refractive index of reduced graphene oxide in IR band was tested and its IR absorption and radiation properties were researched by correlated calculation. The results show that reduced graphene oxide prepared by hummer method are multilayered graphene with defects and functional groups on its surface. Its absorption in near and far IR bands is strong, but it’s weaker in middle IR band. At the IR atmosphere Window, its normal spectral emissivity decreases with wavelength increasing, and its total normal spectral emissivity in 3 ∼ 5μm and 8 ∼ 14μm are 0.75 and 0.625, respectively. Therefore, reduced graphene oxide can be used as IR absorption and coating materials and have a great potential in microwave and infrared compatible materials.

  19. NEW OPTICAL/ULTRAVIOLET COUNTERPARTS AND THE SPECTRAL ENERGY DISTRIBUTIONS OF NEARBY, THERMALLY EMITTING, ISOLATED NEUTRON STARS

    International Nuclear Information System (INIS)

    Kaplan, D. L.; Kamble, A.; Van Kerkwijk, M. H.; Ho, W. C. G.

    2011-01-01

    We present Hubble Space Telescope optical and ultraviolet photometry for five nearby, thermally emitting neutron stars. With these measurements, all seven such objects have confirmed optical and ultraviolet counterparts. Combining our data with archival space-based photometry, we present spectral energy distributions for all sources and measure the 'optical excess': the factor by which the measured photometry exceeds that extrapolated from X-ray spectra. We find that the majority have optical and ultraviolet fluxes that are inconsistent with that expected from thermal (Rayleigh-Jeans) emission, exhibiting more flux at longer wavelengths. We also find that most objects have optical excesses between 5 and 12, but that one object (RX J2143.0+0654) exceeds the X-ray extrapolation by a factor of more than 50 at 5000 A, and that this is robust to uncertainties in the X-ray spectra and absorption. We consider explanations for this ranging from atmospheric effects, magnetospheric emission, and resonant scattering, but find that none is satisfactory.

  20. Modeling Well Sampled Composite Spectral Energy Distributions of Distant Galaxies via an MCMC-driven Inference Framework

    Science.gov (United States)

    Pasha, Imad; Kriek, Mariska; Johnson, Benjamin; Conroy, Charlie

    2018-01-01

    Using a novel, MCMC-driven inference framework, we have modeled the stellar and dust emission of 32 composite spectral energy distributions (SEDs), which span from the near-ultraviolet (NUV) to far infrared (FIR). The composite SEDs were originally constructed in a previous work from the photometric catalogs of the NEWFIRM Medium-Band Survey, in which SEDs of individual galaxies at 0.5 MIPS 24 μm was added for each SED type, and in this work, PACS 100 μm, PACS160 μm, SPIRE 25 μm, and SPIRE 350 μm photometry have been added to extend the range of the composite SEDs into the FIR. We fit the composite SEDs with the Prospector code, which utilizes an MCMC sampling to explore the parameter space for models created by the Flexible Stellar Population Synthesis (FSPS) code, in order to investigate how specific star formation rate (sSFR), dust temperature, and other galaxy properties vary with SED type.This work is also being used to better constrain the SPS models within FSPS.

  1. Photochemical Energy Storage and Electrochemically Triggered Energy Release in the Norbornadiene-Quadricyclane System: UV Photochemistry and IR Spectroelectrochemistry in a Combined Experiment.

    Science.gov (United States)

    Brummel, Olaf; Waidhas, Fabian; Bauer, Udo; Wu, Yanlin; Bochmann, Sebastian; Steinrück, Hans-Peter; Papp, Christian; Bachmann, Julien; Libuda, Jörg

    2017-07-06

    The two valence isomers norbornadiene (NBD) and quadricyclane (QC) enable solar energy storage in a single molecule system. We present a new photoelectrochemical infrared reflection absorption spectroscopy (PEC-IRRAS) experiment, which allows monitoring of the complete energy storage and release cycle by in situ vibrational spectroscopy. Both processes were investigated, the photochemical conversion from NBD to QC using the photosensitizer 4,4'-bis(dimethylamino)benzophenone (Michler's ketone, MK) and the electrochemically triggered cycloreversion from QC to NBD. Photochemical conversion was obtained with characteristic conversion times on the order of 500 ms. All experiments were performed under full potential control in a thin-layer configuration with a Pt(111) working electrode. The vibrational spectra of NBD, QC, and MK were analyzed in the fingerprint region, permitting quantitative analysis of the spectroscopic data. We determined selectivities for both the photochemical conversion and the electrochemical cycloreversion and identified the critical steps that limit the reversibility of the storage cycle.

  2. Formulation of the energetic spectral distribution of in pile neutron flux (energies greater than a few hundred electron volts) (1963); Formulation des repartitions spectrales energetiques de flux neutroniques en pile (energies superieures a quelques centaines d'electrons-volts) (1963)

    Energy Technology Data Exchange (ETDEWEB)

    Genthon, J P [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1964-07-01

    In the present report an expression is deduced for the spectral distribution of flux of over a few hundred electron volts; it is valid for most cases of thermal neutron reactors. This expression is: {psi}(E) = K [{psi}{sub o}(E) + h {psi}{sub e}(E)] {psi}{sub o}(E) is the so-called 'homogeneous' constituent of the flux; it corresponds approximately to the case of an infinite homogeneous medium; it is of the type: Y(V - E) e{sup (b{radical}}{sup E)}/E + Y(E-V) F E{sup {upsilon}} e{sup -{beta}}{sup E} The parameters V and F are such that {psi}{sub o}(E) and its derivative are continuous at the junction energy V. {psi}{sub e}(E) is the 'heterogeneous' constituent of the flux; it is of the type: E{sup {upsilon}} e{sup -{beta}}{sup E}. The various parameters of {psi}(E) are on the one hand characteristic of the nature of the reactor moderator, and on the other hand determined by a resonant flux measurement and one, or possibly two, measurements using a fast neutron threshold detector. We have been led furthermore to define an expression for the threshold reaction section which is more exact than the conventional transition function. (author) [French] Il est etabli, dans le present rapport, une formulation {psi}(E) des repartitions spectrales de flux au-dessus de quelques centaines d'electron-s volts, valable dans la majeure partie des cas de piles dites a neutrons thermiques. Cette formulation s'exprime: {psi}(E) = K [{psi}{sub o}(E) + h {psi}{sub e}(E)] {psi}{sub o}(E) est la composante dite 'homogene' du flux; elle correspond a peu pres au cas d'un milieu infini homogene; elle est du type: Y(V - E) e{sup (b{radical}}{sup E)}/E + Y(E-V) F E{sup {upsilon}} e{sup -{beta}}{sup E} les parametres V et F sont tels que {psi}{sub o}(E) et sa derivee soient continues a l'energie de jonction V. {psi}{sub e} est la composante dite 'heterogene' du flux ; elle est du type: E{sup {upsilon}} e{sup -{beta}}{sup E}. Les differents parametres de {psi}(E) sont, d'une part

  3. Preliminary study on the differentiation between parapelvic cyst and hydronephrosis with non-calculous using only pre-contrast dual-energy spectral CT scans

    Science.gov (United States)

    Han, Dong; Ma, Guangming; Wei, Lequn; Ren, Chenglong; Zhou, Jieli; Shen, Chen

    2017-01-01

    Objective: To investigate the value of using the quantitative parameters from only the pre-contrast dual-energy spectral CT imaging for distinguishing between parapelvic cyst and hydronephrosis with non-calculous (HNC). Methods: This retrospective study was approved by the institutional review board. 28 patients with parapelvic cyst and 24 patients with HNC who underwent standard pre-contrast and multiphase contrast-enhanced dual-energy spectral CT imaging were retrospectively identified. The parapelvic cyst and HNC were identified using the contrast-enhanced scans, and their CT number in the 70-keV monochromatic images, effective atomic number (Zeff), iodine concentration (IC) and water concentration in the pre-contrast images were measured. The slope of the spectral curve (λ) was calculated. The difference in the measurements between parapelvic cyst and HNC was statistically analyzed using SPSS® v. 19.0 (IBM Corp., New York, NY; formerly SPSS Inc., Chicago, IL) statistical software. Receiver-operating characteristic analysis was performed to assess the diagnostic performance. Results: The CT numbers in the 70-keV images, Zeff and IC values were statistically different between parapelvic cyst and HNC (all p  0.05). Conclusion: The quantitative parameters obtained in the pre-contrast dual-energy spectral CT imaging may be used to differentiate between parapelvic cyst and HNC. Advances in knowledge: The pre-contrast dual-energy spectral CT scans may be used to screen parapelvic cysts for patients who are asymptomatic, thereby avoiding contrast-enhanced CT or CT urography examination for these patients to reduce ionizing radiation dose and contrast dose. PMID:28281789

  4. Simulation of breaking waves using the high-order spectral method with laboratory experiments: wave-breaking energy dissipation

    Science.gov (United States)

    Seiffert, Betsy R.; Ducrozet, Guillaume

    2018-01-01

    We examine the implementation of a wave-breaking mechanism into a nonlinear potential flow solver. The success of the mechanism will be studied by implementing it into the numerical model HOS-NWT, which is a computationally efficient, open source code that solves for the free surface in a numerical wave tank using the high-order spectral (HOS) method. Once the breaking mechanism is validated, it can be implemented into other nonlinear potential flow models. To solve for wave-breaking, first a wave-breaking onset parameter is identified, and then a method for computing wave-breaking associated energy loss is determined. Wave-breaking onset is calculated using a breaking criteria introduced by Barthelemy et al. (J Fluid Mech https://arxiv.org/pdf/1508.06002.pdf, submitted) and validated with the experiments of Saket et al. (J Fluid Mech 811:642-658, 2017). Wave-breaking energy dissipation is calculated by adding a viscous diffusion term computed using an eddy viscosity parameter introduced by Tian et al. (Phys Fluids 20(6): 066,604, 2008, Phys Fluids 24(3), 2012), which is estimated based on the pre-breaking wave geometry. A set of two-dimensional experiments is conducted to validate the implemented wave breaking mechanism at a large scale. Breaking waves are generated by using traditional methods of evolution of focused waves and modulational instability, as well as irregular breaking waves with a range of primary frequencies, providing a wide range of breaking conditions to validate the solver. Furthermore, adjustments are made to the method of application and coefficient of the viscous diffusion term with negligible difference, supporting the robustness of the eddy viscosity parameter. The model is able to accurately predict surface elevation and corresponding frequency/amplitude spectrum, as well as energy dissipation when compared with the experimental measurements. This suggests the model is capable of calculating wave-breaking onset and energy dissipation

  5. Clinical utility of dual-energy contrast-enhanced spectral mammography for breast microcalcifications without associated mass: a preliminary analysis.

    Science.gov (United States)

    Cheung, Yun-Chung; Tsai, Hsiu-Pei; Lo, Yung-Feng; Ueng, Shir-Hwa; Huang, Pei-Chin; Chen, Shin-Chih

    2016-04-01

    To assess the utility of dual-energy contrast-enhanced spectral mammography (DE-CESM) for evaluation of suspicious malignant microcalcifications. Two hundred and fifty-six DE-CESMs were reviewed from 2012-2013, 59 cases fulfilled the following criteria and were enrolled for analysis: (1) suspicious malignant microcalcifications (BI-RADS 4) on mammogram, (2) no related mass, (3) with pathological diagnoses. The microcalcification morphology and associated enhancement were reviewed to analyse the accuracy of the diagnosis and cancer size measurements versus the results of pathology. Of the 59 microcalcifications, 22 were diagnosed as cancers, 19 were atypical lesions and 18 were benign lesions. Twenty (76.9 %) cancers, three (11.55 %) atypia and three (11.55 %) benign lesions revealed enhancement. The true-positive rate of intermediate- and high-concern microcalcifications was significantly higher than that of low-concern lesions (93.75 % vs. 50 %). Overall, the diagnostic sensitivity of enhancement was 90.9 %, with 83.78 % specificity, 76.92 % positive predictive value, 93.94 % negative predictive value and 86.4 % accuracy. Performance was good (AUC = 0.87) according to a ROC curve and cancer size correlation with a mean difference of 0.05 cm on a Bland-Altman plot. DE-CESM provides additional enhancement information for diagnosing breast microcalcifications and measuring cancer sizes with high correlation to surgicohistology. • DE-CESM provides additional enhancement information for diagnosing suspicious breast microcalcifications. • The enhanced cancer size closely correlates to microscopy by Bland-Altman plot. • DE-CESM could be considered for evaluation of suspicious malignant microcalcifications.

  6. C IV EMISSION AND THE ULTRAVIOLET THROUGH X-RAY SPECTRAL ENERGY DISTRIBUTION OF RADIO-QUIET QUASARS

    International Nuclear Information System (INIS)

    Kruczek, Nicholas E.; Richards, Gordon T.; Deo, Rajesh P.; Krawczyk, Coleman M.; Gallagher, S. C.; Hall, Patrick B.; Hewett, Paul C.; Leighly, Karen M.; Proga, Daniel

    2011-01-01

    In the rest-frame ultraviolet (UV), two of the parameters that best characterize the range of emission-line properties in quasar broad emission-line regions are the equivalent width and the blueshift of the C IV λ1549 line relative to the quasar rest frame. We explore the connection between these emission-line properties and the UV through X-ray spectral energy distribution (SED) for radio-quiet (RQ) quasars. Our sample consists of a heterogeneous compilation of 406 quasars from the Sloan Digital Sky Survey (at z > 1.54) and Palomar-Green survey (at z < 0.4) that have well-measured C IV emission-line and X-ray properties (including 164 objects with measured Γ). We find that RQ quasars with both strong C IV emission and small C IV blueshifts can be classified as 'hard-spectrum' sources that are (relatively) strong in the X-ray as compared to the UV. On the other hand, RQ quasars with both weak C IV emission and large C IV blueshifts are instead 'soft-spectrum' sources that are (relatively) weak in the X-ray as compared to the UV. This work helps to further bridge optical/soft X-ray 'eigenvector 1' relationships to the UV and hard X-ray. Based on these findings, we argue that future work should consider systematic errors in bolometric corrections (and thus accretion rates) that are derived from a single mean SED. Detailed analysis of the C IV emission line may allow for SED-dependent corrections to these quantities.

  7. Spectrally selective glazings

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-08-01

    Spectrally selective glazing is window glass that permits some portions of the solar spectrum to enter a building while blocking others. This high-performance glazing admits as much daylight as possible while preventing transmission of as much solar heat as possible. By controlling solar heat gains in summer, preventing loss of interior heat in winter, and allowing occupants to reduce electric lighting use by making maximum use of daylight, spectrally selective glazing significantly reduces building energy consumption and peak demand. Because new spectrally selective glazings can have a virtually clear appearance, they admit more daylight and permit much brighter, more open views to the outside while still providing the solar control of the dark, reflective energy-efficient glass of the past. This Federal Technology Alert provides detailed information and procedures for Federal energy managers to consider spectrally selective glazings. The principle of spectrally selective glazings is explained. Benefits related to energy efficiency and other architectural criteria are delineated. Guidelines are provided for appropriate application of spectrally selective glazing, and step-by-step instructions are given for estimating energy savings. Case studies are also presented to illustrate actual costs and energy savings. Current manufacturers, technology users, and references for further reading are included for users who have questions not fully addressed here.

  8. Extending Supernova Spectral Templates for Next Generation Space Telescope Observations

    Science.gov (United States)

    Roberts-Pierel, Justin; Rodney, Steven A.; Steven Rodney

    2018-01-01

    Widely used empirical supernova (SN) Spectral Energy Distributions (SEDs) have not historically extended meaningfully into the ultraviolet (UV), or the infrared (IR). However, both are critical for current and future aspects of SN research including UV spectra as probes of poorly understood SN Ia physical properties, and expanding our view of the universe with high-redshift James Webb Space Telescope (JWST) IR observations. We therefore present a comprehensive set of SN SED templates that have been extended into the UV and IR, as well as an open-source software package written in Python that enables a user to generate their own extrapolated SEDs. We have taken a sampling of core-collapse (CC) and Type Ia SNe to get a time-dependent distribution of UV and IR colors (U-B,r’-[JHK]), and then generated color curves are used to extrapolate SEDs into the UV and IR. The SED extrapolation process is now easily duplicated using a user’s own data and parameters via our open-source Python package: SNSEDextend. This work develops the tools necessary to explore the JWST’s ability to discriminate between CC and Type Ia SNe, as well as provides a repository of SN SEDs that will be invaluable to future JWST and WFIRST SN studies.

  9. Evaluation of low-energy contrast-enhanced spectral mammography images by comparing them to full-field digital mammography using EUREF image quality criteria

    OpenAIRE

    Lalji, U. C.; Jeukens, C. R. L. P. N.; Houben, I.; Nelemans, P. J.; van Engen, R. E.; van Wylick, E.; Beets-Tan, R. G. H.; Wildberger, J. E.; Paulis, L. E.; Lobbes, M. B. I.

    2015-01-01

    Objective Contrast-enhanced spectral mammography (CESM) examination results in a low-energy (LE) and contrast-enhanced image. The LE appears similar to a full-field digital mammogram (FFDM). Our aim was to evaluate LE CESM image quality by comparing it to FFDM using criteria defined by the European Reference Organization for Quality Assured Breast Screening and Diagnostic Services (EUREF). Methods A total of 147 cases with both FFDM and LE images were independently scored by two experienced r...

  10. Contrast Dose and Radiation Dose Reduction in Abdominal Enhanced Computerized Tomography Scans with Single-phase Dual-energy Spectral Computerized Tomography Mode for Children with Solid Tumors

    OpenAIRE

    Tong Yu; Jun Gao; Zhi-Min Liu; Qi-Feng Zhang; Yong Liu; Ling Jiang; Yun Peng

    2017-01-01

    Background: Contrast dose and radiation dose reduction in computerized tomography (CT) scan for adult has been explored successfully, but there have been few studies on the application of low-concentration contrast in pediatric abdominal CT examinations. This was a feasibility study on the use of dual-energy spectral imaging and adaptive statistical iterative reconstruction (ASiR) for the reduction of radiation dose and iodine contrast dose in pediatric abdominal CT patients with solid tumors...

  11. Single-energy pediatric chest computed tomography with spectral filtration at 100 kVp: effects on radiation parameters and image quality

    International Nuclear Information System (INIS)

    Bodelle, Boris; Fischbach, Constanze; Booz, Christian; Yel, Ibrahim; Frellesen, Claudia; Kaup, Moritz; Beeres, Martin; Vogl, Thomas J.; Scholtz, Jan-Erik

    2017-01-01

    Most of the applied radiation dose at CT is in the lower photon energy range, which is of limited diagnostic importance. To investigate image quality and effects on radiation parameters of 100-kVp spectral filtration single-energy chest CT using a tin-filter at third-generation dual-source CT in comparison to standard 100-kVp chest CT. Thirty-three children referred for a non-contrast chest CT performed on a third-generation dual-source CT scanner were examined at 100 kVp with a dedicated tin filter with a tube current-time product resulting in standard protocol dose. We compared resulting images with images from children examined using standard single-source chest CT at 100 kVp. We assessed objective and subjective image quality and compared radiation dose parameters. Radiation dose was comparable for children 5 years old and younger, and it was moderately decreased for older children when using spectral filtration (P=0.006). Effective tube current increased significantly (P=0.0001) with spectral filtration, up to a factor of 10. Signal-to-noise ratio and image noise were similar for both examination techniques (P≥0.06). Subjective image quality showed no significant differences (P≥0.2). Using 100-kVp spectral filtration chest CT in children by means of a tube-based tin-filter on a third-generation dual-source CT scanner increases effective tube current up to a factor of 10 to provide similar image quality at equivalent dose compared to standard single-source CT without spectral filtration. (orig.)

  12. Single-energy pediatric chest computed tomography with spectral filtration at 100 kVp: effects on radiation parameters and image quality

    Energy Technology Data Exchange (ETDEWEB)

    Bodelle, Boris; Fischbach, Constanze; Booz, Christian; Yel, Ibrahim; Frellesen, Claudia; Kaup, Moritz; Beeres, Martin; Vogl, Thomas J.; Scholtz, Jan-Erik [Goethe University of Frankfurt, Department of Diagnostic and Interventional Radiology, Frankfurt (Germany)

    2017-06-15

    Most of the applied radiation dose at CT is in the lower photon energy range, which is of limited diagnostic importance. To investigate image quality and effects on radiation parameters of 100-kVp spectral filtration single-energy chest CT using a tin-filter at third-generation dual-source CT in comparison to standard 100-kVp chest CT. Thirty-three children referred for a non-contrast chest CT performed on a third-generation dual-source CT scanner were examined at 100 kVp with a dedicated tin filter with a tube current-time product resulting in standard protocol dose. We compared resulting images with images from children examined using standard single-source chest CT at 100 kVp. We assessed objective and subjective image quality and compared radiation dose parameters. Radiation dose was comparable for children 5 years old and younger, and it was moderately decreased for older children when using spectral filtration (P=0.006). Effective tube current increased significantly (P=0.0001) with spectral filtration, up to a factor of 10. Signal-to-noise ratio and image noise were similar for both examination techniques (P≥0.06). Subjective image quality showed no significant differences (P≥0.2). Using 100-kVp spectral filtration chest CT in children by means of a tube-based tin-filter on a third-generation dual-source CT scanner increases effective tube current up to a factor of 10 to provide similar image quality at equivalent dose compared to standard single-source CT without spectral filtration. (orig.)

  13. Neutron spectrum perturbations due to scattering materials and their effect on the average neutron energy, the spectral index, and the hardness parameter

    International Nuclear Information System (INIS)

    Wright, H.L.; Meason, J.L.; Wolf, M.; Harvey, J.T.

    1976-01-01

    Measurements have been performed on the perturbing effect of a number of scattering materials by the 'free-field' neutron leakage spectrum from a Godiva Type Critical Assembly (White Sands Missile Range Fast Burst Reactor). The results of these measurements are interpreted in relation to some of the general parameters characterizing a neutron environment, namely, the average neutron energy >10 KeV, the spectral index and the hardness parameter. Three neutron spectrum measurements have been performed, each under different experimental configurations of scattering materials. Results from these measurements show the following with relation to the spectral index: (1) The neutron environment on the core surface and at 12-inches from the core surface (free-field) yield a spectral index of 6.8, (2) The neutron environment behind a 4.75-inch Plexiglas plate yield 4.6 for the spectral index and (3) The neutron environment behind a 2-inch aluminum plate yield 6.7 for the spectral index. It is concluded that the core surface and the 12-inch from core surface neutron environment are identical with the 'free-field' neutron environment at 20-inches when considering only those neutrons with energy >10 KeV. On the other hand, it appears that the 4.75 inches of Plexiglas severely perturbs the 'free-field' neutron environment, i.e., a much harder neutron spectrum >10 KeV. In the situation where 2-inches of aluminum is used as the perturbing medium, essentially no change in the neutron spectrum >10 KeV is noted

  14. Experimental determination of spectral ratios and of neutrons energy spectrum in the fuel of the IPEN/MB-01 nuclear reactor

    International Nuclear Information System (INIS)

    Nunes, Beatriz Guimaraes

    2012-01-01

    This study aims to determine the spectral ratios and the neutron energy spectrum inside the fuel of IPEN/MB-01 Nuclear Reactor. These parameters are of great importance to accurately determine spectral physical parameters of nuclear reactors like reaction rates, fuel lifetime and also security parameters such as reactivity. For the experiment, activation detectors in the form of thin metal foils were introduced in a collapsible fuel rod. Then the rod was placed in the central position of the core which has a standard rectangular configuration of 26 x 28 fuel rods. There were used activation detectors from different elements such Au-197, U-238, Sc-45, Ni-58, Mg-24, Ti-47 and In-115 to cover a large range of the neutron energy spectrum. After the irradiation, the activation detectors were submitted to gamma spectrometry using a counting system with high purity Germanium, to obtain the reaction rates (saturation activity) per target nucleus. The spectral ratios were compared with calculated values obtained by the Monte Carlo method using the MCNP-4C code. The neutron energy spectrum was obtained inside the fuel rod using the SANDBP code with an input spectrum obtained by the MCNP-4C code, based on the saturation activity per target nucleus values of the activation detectors irradiated. (author)

  15. The X-Shooter spectral library

    NARCIS (Netherlands)

    Chen, Y. P.; Trager, S. C.; Peletier, R. F.; Lançon, A.; Prugniel, Ph.; Koleva, M.

    2012-01-01

    We are building a new spectral library with the X-Shooter instrument on ESO's VLT: XSL, the X-Shooter Spectral Library. We present our progress in building XSL, which covers the wavelength range from the near-UV to the near-IR with a resolution of R˜10000. As of now we have collected spectra for

  16. Silicon Nanowires for Solar Thermal Energy Harvesting: an Experimental Evaluation on the Trade-off Effects of the Spectral Optical Properties.

    Science.gov (United States)

    Sekone, Abdoul Karim; Chen, Yu-Bin; Lu, Ming-Chang; Chen, Wen-Kai; Liu, Chia-An; Lee, Ming-Tsang

    2016-12-01

    Silicon nanowire possesses great potential as the material for renewable energy harvesting and conversion. The significantly reduced spectral reflectivity of silicon nanowire to visible light makes it even more attractive in solar energy applications. However, the benefit of its use for solar thermal energy harvesting remains to be investigated and has so far not been clearly reported. The purpose of this study is to provide practical information and insight into the performance of silicon nanowires in solar thermal energy conversion systems. Spectral hemispherical reflectivity and transmissivity of the black silicon nanowire array on silicon wafer substrate were measured. It was observed that the reflectivity is lower in the visible range but higher in the infrared range compared to the plain silicon wafer. A drying experiment and a theoretical calculation were carried out to directly evaluate the effects of the trade-off between scattering properties at different wavelengths. It is clearly seen that silicon nanowires can improve the solar thermal energy harnessing. The results showed that a 17.8 % increase in the harvest and utilization of solar thermal energy could be achieved using a silicon nanowire array on silicon substrate as compared to that obtained with a plain silicon wafer.

  17. TORUS AND ACTIVE GALACTIC NUCLEUS PROPERTIES OF NEARBY SEYFERT GALAXIES: RESULTS FROM FITTING INFRARED SPECTRAL ENERGY DISTRIBUTIONS AND SPECTROSCOPY

    International Nuclear Information System (INIS)

    Alonso-Herrero, Almudena; Ramos Almeida, Cristina; Mason, Rachel; Asensio Ramos, Andres; Rodriguez Espinosa, Jose Miguel; Perez-Garcia, Ana M.; Roche, Patrick F.; Levenson, Nancy A.; Elitzur, Moshe; Packham, Christopher; Young, Stuart; Diaz-Santos, Tanio

    2011-01-01

    We used the CLUMPY torus models and a Bayesian approach to fit the infrared spectral energy distributions and ground-based high angular resolution mid-infrared spectroscopy of 13 nearby Seyfert galaxies. This allowed us to put tight constraints on torus model parameters such as the viewing angle i, the radial thickness of the torus Y, the angular size of the cloud distribution σ torus , and the average number of clouds along radial equatorial rays N 0 . We found that the viewing angle i is not the only parameter controlling the classification of a galaxy into type 1 or type 2. In principle, type 2s could be viewed at any viewing angle i as long as there is one cloud along the line of sight. A more relevant quantity for clumpy media is the probability for an active galactic nucleus (AGN) photon to escape unabsorbed. In our sample, type 1s have relatively high escape probabilities, P esc ∼ 12%-44%, while type 2s, as expected, tend to have very low escape probabilities. Our fits also confirmed that the tori of Seyfert galaxies are compact with torus model radii in the range 1-6 pc. The scaling of the models to the data also provided the AGN bolometric luminosities L bol (AGN), which were found to be in good agreement with estimates from the literature. When we combined our sample of Seyfert galaxies with a sample of PG quasars from the literature to span a range of L bol (AGN) ∼ 10 43 -10 47 erg s -1 , we found plausible evidence of the receding torus. That is, there is a tendency for the torus geometrical covering factor to be lower (f 2 ∼ 0.1-0.3) at high AGN luminosities than at low AGN luminosities (f 2 ∼ 0.9-1 at ∼10 43 -10 44 erg s -1 ). This is because at low AGN luminosities the tori appear to have wider angular sizes (larger σ torus ) and more clouds along radial equatorial rays. We cannot, however, rule out the possibility that this is due to contamination by extended dust structures not associated with the dusty torus at low AGN luminosities

  18. A full-spectral Bayesian reconstruction approach based on the material decomposition model applied in dual-energy computed tomography

    International Nuclear Information System (INIS)

    Cai, C.; Rodet, T.; Mohammad-Djafari, A.; Legoupil, S.

    2013-01-01

    Purpose: Dual-energy computed tomography (DECT) makes it possible to get two fractions of basis materials without segmentation. One is the soft-tissue equivalent water fraction and the other is the hard-matter equivalent bone fraction. Practical DECT measurements are usually obtained with polychromatic x-ray beams. Existing reconstruction approaches based on linear forward models without counting the beam polychromaticity fail to estimate the correct decomposition fractions and result in beam-hardening artifacts (BHA). The existing BHA correction approaches either need to refer to calibration measurements or suffer from the noise amplification caused by the negative-log preprocessing and the ill-conditioned water and bone separation problem. To overcome these problems, statistical DECT reconstruction approaches based on nonlinear forward models counting the beam polychromaticity show great potential for giving accurate fraction images.Methods: This work proposes a full-spectral Bayesian reconstruction approach which allows the reconstruction of high quality fraction images from ordinary polychromatic measurements. This approach is based on a Gaussian noise model with unknown variance assigned directly to the projections without taking negative-log. Referring to Bayesian inferences, the decomposition fractions and observation variance are estimated by using the joint maximum a posteriori (MAP) estimation method. Subject to an adaptive prior model assigned to the variance, the joint estimation problem is then simplified into a single estimation problem. It transforms the joint MAP estimation problem into a minimization problem with a nonquadratic cost function. To solve it, the use of a monotone conjugate gradient algorithm with suboptimal descent steps is proposed.Results: The performance of the proposed approach is analyzed with both simulated and experimental data. The results show that the proposed Bayesian approach is robust to noise and materials. It is also

  19. Design and simulations of a spectral efficient optical code division multiple access scheme using alternated energy differentiation and single-user soft-decision demodulation

    Science.gov (United States)

    A. Garba, Aminata

    2017-01-01

    This paper presents a new approach to optical Code Division Multiple Access (CDMA) network transmission scheme using alternated amplitude sequences and energy differentiation at the transmitters to allow concurrent and secure transmission of several signals. The proposed system uses error control encoding and soft-decision demodulation to reduce the multi-user interference at the receivers. The design of the proposed alternated amplitude sequences, the OCDMA energy modulators and the soft decision, single-user demodulators are also presented. Simulation results show that the proposed scheme allows achieving spectral efficiencies higher than several reported results for optical CDMA and much higher than the Gaussian CDMA capacity limit.

  20. IOT Overview: IR Instruments

    Science.gov (United States)

    Mason, E.

    In this instrument review chapter the calibration plans of ESO IR instruments are presented and briefly reviewed focusing, in particular, on the case of ISAAC, which has been the first IR instrument at VLT and whose calibration plan served as prototype for the coming instruments.

  1. Importance of the green color, absorption gradient, and spectral absorption of chloroplasts for the radiative energy balance of leaves.

    Science.gov (United States)

    Kume, Atsushi

    2017-05-01

    Terrestrial green plants absorb photosynthetically active radiation (PAR; 400-700 nm) but do not absorb photons evenly across the PAR waveband. The spectral absorbance of photosystems and chloroplasts is lowest for green light, which occurs within the highest irradiance waveband of direct solar radiation. We demonstrate a close relationship between this phenomenon and the safe and efficient utilization of direct solar radiation in simple biophysiological models. The effects of spectral absorptance on the photon and irradiance absorption processes are evaluated using the spectra of direct and diffuse solar radiation. The radiation absorption of a leaf arises as a consequence of the absorption of chloroplasts. The photon absorption of chloroplasts is strongly dependent on the distribution of pigment concentrations and their absorbance spectra. While chloroplast movements in response to light are important mechanisms controlling PAR absorption, they are not effective for green light because chloroplasts have the lowest spectral absorptance in the waveband. With the development of palisade tissue, the incident photons per total palisade cell surface area and the absorbed photons per chloroplast decrease. The spectral absorbance of carotenoids is effective in eliminating shortwave PAR (solar radiation. However, most of the near infrared radiation is unabsorbed and heat stress is greatly reduced. The incident solar radiation is too strong to be utilized for photosynthesis under the current CO 2 concentration in the terrestrial environment. Therefore, the photon absorption of a whole leaf is efficiently regulated by photosynthetic pigments with low spectral absorptance in the highest irradiance waveband and through a combination of pigment density distribution and leaf anatomical structures.

  2. Characteristics of Ir/Au transition edge sensor

    International Nuclear Information System (INIS)

    Kunieda, Yuichi; Ohno, Masashi; Nakazawa, Masaharu; Takahashi, Hiroyuki; Fukuda, Daiji; Ohkubo, Masataka

    2004-01-01

    A new type of microcalorimeter has been developed using a transition edge sensor (TES) and an electro-thermal feedback (ETF) method to achieve higher energy resolution and higher count rate. We are developing a superconducting Ir-based transition edge sensor (TES) microcalorimeters. To improve thermal conductivity and achieve higher energy resolution with an Ir-TES, we fabricated an Ir/Au bilayer TES by depositing gold on Ir and investigated the influence of intermediate between superconducting and normal states at the transition edge for signal responses by microscopic observation in the Ir/Au-TES. (T. Tanaka)

  3. A SEARCH FOR SPECTRAL HYSTERESIS AND ENERGY-DEPENDENT TIME LAGS FROM X-RAY AND TeV GAMMA-RAY OBSERVATIONS OF Mrk 421

    International Nuclear Information System (INIS)

    Abeysekara, A. U.; Flinders, A.; Archambault, S.; Feng, Q.; Archer, A.; Buckley, J. H.; Bugaev, V.; Benbow, W.; Cerruti, M.; Bird, R.; Buchovecky, M.; Cardenzana, J. V; Eisch, J. D.; Chen, X.; Ciupik, L.; Connolly, M. P.; Cui, W.; Finley, J. P.; Falcone, A.; Fleischhack, H.

    2017-01-01

    Blazars are variable emitters across all wavelengths over a wide range of timescales, from months down to minutes. It is therefore essential to observe blazars simultaneously at different wavelengths, especially in the X-ray and gamma-ray bands, where the broadband spectral energy distributions usually peak. In this work, we report on three “target-of-opportunity” observations of Mrk 421, one of the brightest TeV blazars, triggered by a strong flaring event at TeV energies in 2014. These observations feature long, continuous, and simultaneous exposures with XMM-Newton (covering the X-ray and optical/ultraviolet bands) and VERITAS (covering the TeV gamma-ray band), along with contemporaneous observations from other gamma-ray facilities (MAGIC and Fermi -Large Area Telescope) and a number of radio and optical facilities. Although neither rapid flares nor significant X-ray/TeV correlation are detected, these observations reveal subtle changes in the X-ray spectrum of the source over the course of a few days. We search the simultaneous X-ray and TeV data for spectral hysteresis patterns and time delays, which could provide insight into the emission mechanisms and the source properties (e.g., the radius of the emitting region, the strength of the magnetic field, and related timescales). The observed broadband spectra are consistent with a one-zone synchrotron self-Compton model. We find that the power spectral density distribution at ≳4 × 10 −4 Hz from the X-ray data can be described by a power-law model with an index value between 1.2 and 1.8, and do not find evidence for a steepening of the power spectral index (often associated with a characteristic length scale) compared to the previously reported values at lower frequencies.

  4. A SEARCH FOR SPECTRAL HYSTERESIS AND ENERGY-DEPENDENT TIME LAGS FROM X-RAY AND TeV GAMMA-RAY OBSERVATIONS OF Mrk 421

    Energy Technology Data Exchange (ETDEWEB)

    Abeysekara, A. U.; Flinders, A. [Department of Physics and Astronomy, University of Utah, Salt Lake City, UT 84112 (United States); Archambault, S.; Feng, Q. [Physics Department, McGill University, Montreal, QC H3A 2T8 (Canada); Archer, A.; Buckley, J. H.; Bugaev, V. [Department of Physics, Washington University, St. Louis, MO 63130 (United States); Benbow, W.; Cerruti, M. [Fred Lawrence Whipple Observatory, Harvard-Smithsonian Center for Astrophysics, Amado, AZ 85645 (United States); Bird, R.; Buchovecky, M. [Department of Physics and Astronomy, University of California, Los Angeles, CA 90095 (United States); Cardenzana, J. V; Eisch, J. D. [Department of Physics and Astronomy, Iowa State University, Ames, IA 50011 (United States); Chen, X. [Institute of Physics and Astronomy, University of Potsdam, D-14476 Potsdam-Golm (Germany); Ciupik, L. [Astronomy Department, Adler Planetarium and Astronomy Museum, Chicago, IL 60605 (United States); Connolly, M. P. [School of Physics, National University of Ireland Galway, University Road, Galway (Ireland); Cui, W.; Finley, J. P. [Department of Physics and Astronomy, Purdue University, West Lafayette, IN 47907 (United States); Falcone, A. [Department of Astronomy and Astrophysics, 525 Davey Lab, Pennsylvania State University, University Park, PA 16802 (United States); Fleischhack, H. [DESY, Platanenallee 6, D-15738 Zeuthen (Germany); Collaboration: VERITAS Collaboration; MAGIC Collaboration; and others

    2017-01-01

    Blazars are variable emitters across all wavelengths over a wide range of timescales, from months down to minutes. It is therefore essential to observe blazars simultaneously at different wavelengths, especially in the X-ray and gamma-ray bands, where the broadband spectral energy distributions usually peak. In this work, we report on three “target-of-opportunity” observations of Mrk 421, one of the brightest TeV blazars, triggered by a strong flaring event at TeV energies in 2014. These observations feature long, continuous, and simultaneous exposures with XMM-Newton (covering the X-ray and optical/ultraviolet bands) and VERITAS (covering the TeV gamma-ray band), along with contemporaneous observations from other gamma-ray facilities (MAGIC and Fermi -Large Area Telescope) and a number of radio and optical facilities. Although neither rapid flares nor significant X-ray/TeV correlation are detected, these observations reveal subtle changes in the X-ray spectrum of the source over the course of a few days. We search the simultaneous X-ray and TeV data for spectral hysteresis patterns and time delays, which could provide insight into the emission mechanisms and the source properties (e.g., the radius of the emitting region, the strength of the magnetic field, and related timescales). The observed broadband spectra are consistent with a one-zone synchrotron self-Compton model. We find that the power spectral density distribution at ≳4 × 10{sup −4} Hz from the X-ray data can be described by a power-law model with an index value between 1.2 and 1.8, and do not find evidence for a steepening of the power spectral index (often associated with a characteristic length scale) compared to the previously reported values at lower frequencies.

  5. Joint IAEA/NEA IRS guidelines

    International Nuclear Information System (INIS)

    1997-01-01

    The Incident Reporting System (IRS) is an international system jointly operated by the International Atomic Energy Agency (IAEA) and the Nuclear Energy Agency of the Organization for Economic Cooperation and Development (OECD/NEA). The fundamental objective of the IRS is to contribute to improving the safety of commercial nuclear power plants (NPPs) which are operated worldwide. This objective can be achieved by providing timely and detailed information on both technical and human factors related to events of safety significance which occur at these plants. The purpose of these guidelines, which supersede the previous IAEA Safety Series No. 93 (Part II) and the NEA IRS guidelines, is to describe the system and to give users the necessary background and guidance to enable them to produce IRS reports meeting a high standard of quality while retaining the high efficiency of the system expected by all Member States operating nuclear power plants

  6. Contrast Dose and Radiation Dose Reduction in Abdominal Enhanced Computerized Tomography Scans with Single-phase Dual-energy Spectral Computerized Tomography Mode for Children with Solid Tumors.

    Science.gov (United States)

    Yu, Tong; Gao, Jun; Liu, Zhi-Min; Zhang, Qi-Feng; Liu, Yong; Jiang, Ling; Peng, Yun

    2017-04-05

    Contrast dose and radiation dose reduction in computerized tomography (CT) scan for adult has been explored successfully, but there have been few studies on the application of low-concentration contrast in pediatric abdominal CT examinations. This was a feasibility study on the use of dual-energy spectral imaging and adaptive statistical iterative reconstruction (ASiR) for the reduction of radiation dose and iodine contrast dose in pediatric abdominal CT patients with solid tumors. Forty-five patients with solid tumors who had initial CT (Group B) and follow-up CT (Group A) after chemotherapy were enrolled. The initial diagnostic CT scan (Group B) was performed using the standard two-phase enhanced CT with 320 mgI/ml concentration contrast, and the follow-up scan (Group A) was performed using a single-phase enhanced CT at 45 s after the beginning of the 270 mgI/ml contrast injection using spectral mode. Forty percent ASiR was used for the images in Group B and monochromatic images with energy levels ≥60 keV in Group A. In addition, filtered back-projection (FBP) reconstruction was used for monochromatic images hounsfield unit (HU). The abdominal organs of Groups A and B had similar degrees of absolute and relative enhancement (t = 0.36 and -1.716 for liver, -0.153 and -1.546 for pancreas, and 2.427 and 0.866 for renal cortex, all P> 0.05). Signal-to-noise ratio of the abdominal organs was significantly lower in Group A than in Group B (t = -8.11 for liver, -7.83 for pancreas, and -5.38 for renal cortex, all P 3, indicating clinically acceptable image quality. Single-phase, dual-energy spectral CT used for children with solid abdominal tumors can reduce contrast dose and radiation dose and can also maintain clinically acceptable image quality.

  7. On the signatures of companion formation in the spectral energy distributions of Sz54 and Sz59—the young stars with protoplanetary disks

    Science.gov (United States)

    Zakhozhay, O. V.

    2017-07-01

    We study spectral energy distributions of two young systems Sz54 and Sz59, that belong to Chameleon II star forming region. The results of the modeling indicate that protoplanetary disks of these systems contain gaps in the dust component. These gaps could be a result of a planetary or brown dwarf companion formation, because the companion would accumulate a disk material, moving along its orbit. In a present work we have determined physical characteristics of the disks. We also discuss possible companion characteristics, based on the geometrical parameters of the gaps.

  8. The mean photon energy anti E{sub F} at the point of measurement determines the detector-specific radiation quality correction factor k{sub Q,M} in {sup 192}Ir brachytherapy dosimetry

    Energy Technology Data Exchange (ETDEWEB)

    Chofor, Ndimofor; Harder, Dietrich; Selbach, Hans-Joachim; Poppe, Bjoern [University of Oldenburg and Pius-Hospital Oldenburg (Germany). Medical Radiation Physics Group

    2016-11-01

    The application of various radiation detectors for brachytherapy dosimetry has motivated this study of the energy dependence of radiation quality correction factor k{sub Q,M}, the quotient of the detector responses under calibration conditions at a {sup 60}Co unit and under the given non-reference conditions at the point of measurement, M, occurring in photon brachytherapy. The investigated detectors comprise TLD, radiochromic film, ESR, Si diode, plastic scintillator and diamond crystal detectors as well as ionization chambers of various sizes, whose measured response-energy relationships, taken from the literature, served as input data. Brachytherapy photon fields were Monte-Carlo simulated for an ideal isotropic {sup 192}Ir point source, a model spherical {sup 192}Ir source with steel encapsulation and a commercial HDR GammaMed Plus source. The radial source distance was varied within cylindrical water phantoms with outer radii ranging from 10 to 30 cm and heights from 20 to 60 cm. By application of this semiempirical method - originally developed for teletherapy dosimetry - it has been shown that factor k{sub Q,M} is closely correlated with a single variable, the fluence-weighted mean photon energy anti E{sub F} at the point of measurement. The radial profiles of anti E{sub F} obtained with either the commercial {sup 192}Ir source or the two simplified source variants show little variation. The observed correlations between parameters k{sub Q,M} and anti E{sub F} are represented by fitting formulae for all investigated detectors, and further variation of the detector type is foreseen. The herewith established close correlation of radiation quality correction factor k{sub Q,M} with local mean photon energy anti E{sub F} can be regarded as a simple regularity, facilitating the practical application of correction factor k{sub Q,M} for in-phantom dosimetry around {sup 192}Ir brachytherapy sources. anti E{sub F} values can be assessed by Monte Carlo simulation or

  9. Spectral stratigraphy

    Science.gov (United States)

    Lang, Harold R.

    1991-01-01

    A new approach to stratigraphic analysis is described which uses photogeologic and spectral interpretation of multispectral remote sensing data combined with topographic information to determine the attitude, thickness, and lithology of strata exposed at the surface. The new stratigraphic procedure is illustrated by examples in the literature. The published results demonstrate the potential of spectral stratigraphy for mapping strata, determining dip and strike, measuring and correlating stratigraphic sequences, defining lithofacies, mapping biofacies, and interpreting geological structures.

  10. Spectral multi-energy CT texture analysis with machine learning for tissue classification: an investigation using classification of benign parotid tumours as a testing paradigm.

    Science.gov (United States)

    Al Ajmi, Eiman; Forghani, Behzad; Reinhold, Caroline; Bayat, Maryam; Forghani, Reza

    2018-06-01

    There is a rich amount of quantitative information in spectral datasets generated from dual-energy CT (DECT). In this study, we compare the performance of texture analysis performed on multi-energy datasets to that of virtual monochromatic images (VMIs) at 65 keV only, using classification of the two most common benign parotid neoplasms as a testing paradigm. Forty-two patients with pathologically proven Warthin tumour (n = 25) or pleomorphic adenoma (n = 17) were evaluated. Texture analysis was performed on VMIs ranging from 40 to 140 keV in 5-keV increments (multi-energy analysis) or 65-keV VMIs only, which is typically considered equivalent to single-energy CT. Random forest (RF) models were constructed for outcome prediction using separate randomly selected training and testing sets or the entire patient set. Using multi-energy texture analysis, tumour classification in the independent testing set had accuracy, sensitivity, specificity, positive predictive value, and negative predictive value of 92%, 86%, 100%, 100%, and 83%, compared to 75%, 57%, 100%, 100%, and 63%, respectively, for single-energy analysis. Multi-energy texture analysis demonstrates superior performance compared to single-energy texture analysis of VMIs at 65 keV for classification of benign parotid tumours. • We present and validate a paradigm for texture analysis of DECT scans. • Multi-energy dataset texture analysis is superior to single-energy dataset texture analysis. • DECT texture analysis has high accura\\cy for diagnosis of benign parotid tumours. • DECT texture analysis with machine learning can enhance non-invasive diagnostic tumour evaluation.

  11. Monitoring combat wound healing by IR hyperspectral imaging

    Science.gov (United States)

    Howle, Chris R.; Spear, Abigail M.; Gazi, Ehsan; Crane, Nicole J.

    2016-03-01

    In recent conflicts, battlefield injuries consist largely of extensive soft injuries from blasts and high energy projectiles, including gunshot wounds. Repair of these large, traumatic wounds requires aggressive surgical treatment, including multiple surgical debridements to remove devitalised tissue and to reduce bacterial load. Identifying those patients with wound complications, such as infection and impaired healing, could greatly assist health care teams in providing the most appropriate and personalised care for combat casualties. Candidate technologies to enable this benefit include the fusion of imaging and optical spectroscopy to enable rapid identification of key markers. Hence, a novel system based on IR negative contrast imaging (NCI) is presented that employs an optical parametric oscillator (OPO) source comprising a periodically-poled LiNbO3 (PPLN) crystal. The crystal operates in the shortwave and midwave IR spectral regions (ca. 1.5 - 1.9 μm and 2.4 - 3.8 μm, respectively). Wavelength tuning is achieved by translating the crystal within the pump beam. System size and complexity are minimised by the use of single element detectors and the intracavity OPO design. Images are composed by raster scanning the monochromatic beam over the scene of interest; the reflection and/or absorption of the incident radiation by target materials and their surrounding environment provide a method for spatial location. Initial results using the NCI system to characterise wound biopsies are presented here.

  12. Diagnostics of Coronal Magnetic Fields through the Hanle Effect in UV and IR Lines

    Energy Technology Data Exchange (ETDEWEB)

    Raouafi, Nour E. [The John Hopkins University Applied Physics Laboratory, Laurel, MD (United States); Riley, Pete [Predictive Science Inc., San Diego, CA (United States); Gibson, Sarah [High Altitude Observatory, National Center for Atmospheric Research, Boulder, CO (United States); Fineschi, Silvano [The Astrophysical Observatory of Turin, National Institute for Astrophysics, Turin (Italy); Solanki, Sami K., E-mail: noureddine.raouafi@jhuapl.edu [Max-Planck-Institut für Sonnensystemforschung, Göttingen (Germany); School of Space Research, Kyung Hee University, Yongin, South (Korea, Republic of)

    2016-06-22

    The plasma thermodynamics in the solar upper atmosphere, particularly in the corona, are dominated by the magnetic field, which controls the flow and dissipation of energy. The relative lack of knowledge of the coronal vector magnetic field is a major handicap for progress in coronal physics. This makes the development of measurement methods of coronal magnetic fields a high priority in solar physics. The Hanle effect in the UV and IR spectral lines is a largely unexplored diagnostic. We use magnetohydrodynamic (MHD) simulations to study the magnitude of the signal to be expected for typical coronal magnetic fields for selected spectral lines in the UV and IR wavelength ranges, namely the H i Ly-α and the He i 10,830 Å lines. We show that the selected lines are useful for reliable diagnosis of coronal magnetic fields. The results show that the combination of polarization measurements of spectral lines with different sensitivities to the Hanle effect may be most appropriate for deducing coronal magnetic properties from future observations.

  13. A UV to mid-IR study of AGN selection

    Energy Technology Data Exchange (ETDEWEB)

    Chung, Sun Mi; Kochanek, Christopher S. [Department of Astronomy, The Ohio State University, 140 West 18th Avenue, Columbus, OH 43210 (United States); Assef, Roberto [Núcleo de Astronomía de la Facultad de Ingeniería, Universidad Diego Portales, Av. Ejército Libertador 441, Santiago (Chile); Brown, Michael J. I. [School of Physics, Monash University, Clayton, Vic 3800 (Australia); Stern, Daniel [Jet Propulsion Laboratory, California Institute of Technology, 4800 Oak Grove Drive, Mail Stop 169-221, Pasadena, CA 91109 (United States); Jannuzi, Buell T. [Department of Astronomy and Steward Observatory, University of Arizona, Tucson, AZ 85721 (United States); Gonzalez, Anthony H. [Department of Astronomy, University of Florida, Gainesville, FL 32611 (United States); Hickox, Ryan C. [Department of Physics and Astronomy, Dartmouth College, 6127 Wilder Laboratory, Hanover, NH 03755 (United States); Moustakas, John [Department of Physics and Astronomy, Siena College, 515 Loudon Road, Loudonville, NY 12211 (United States)

    2014-07-20

    We classify the spectral energy distributions (SEDs) of 431,038 sources in the 9 deg{sup 2} Boötes field of the NOAO Deep Wide-Field Survey (NDWFS). There are up to 17 bands of data available per source, including ultraviolet (GALEX), optical (NDWFS), near-IR (NEWFIRM), and mid-infrared (IRAC and MIPS) data, as well as spectroscopic redshifts for ∼20,000 objects, primarily from the AGN and Galaxy Evolution Survey. We fit galaxy, active galactic nucleus (AGN), stellar, and brown dwarf templates to the observed SEDs, which yield spectral classes for the Galactic sources and photometric redshifts and galaxy/AGN luminosities for the extragalactic sources. The photometric redshift precision of the galaxy and AGN samples are σ/(1 + z) = 0.040 and σ/(1 + z) = 0.169, respectively, with the worst 5% outliers excluded. On the basis of the χ{sub ν}{sup 2} of the SED fit for each SED model, we are able to distinguish between Galactic and extragalactic sources for sources brighter than I = 23.5 mag. We compare the SED fits for a galaxy-only model and a galaxy-AGN model. Using known X-ray and spectroscopic AGN samples, we confirm that SED fitting can be successfully used as a method to identify large populations of AGNs, including spatially resolved AGNs with significant contributions from the host galaxy and objects with the emission line ratios of 'composite' spectra. We also use our results to compare with the X-ray, mid-IR, optical color, and emission line ratio selection techniques. For an F-ratio threshold of F > 10, we find 16,266 AGN candidates brighter than I = 23.5 mag and a surface density of ∼1900 AGN deg{sup –2}.

  14. Probing the very-high-energy gamma-ray spectral curvature in the blazar PG 1553+113 with the MAGIC telescopes

    CERN Document Server

    Aleksić, J.; Antonelli, L A; Antoranz, P; Babic, A; Bangale, P; Barrio, J A; González, J Becerra; Bednarek, W; Bernardini, E; Biasuzzi, B; Biland, A; Blanch, O; Bonnefoy, S; Bonnoli, G; Borracci, F; Bretz, T; Carmona, E; Carosi, A; Colin, P; Colombo, E; Contreras, J.L; Cortina, J; Covino, S; Da Vela, P; Dazzi, F; De Angelis, A; De Caneva, G; De Lotto, B; Wilhelmi, E de Oña; Mendez, C Delgado; Prester, D Dominis; Dorner, D; Doro, M; Einecke, S; Eisenacher, D; Elsaesser, D; Fidalgo, D; Fonseca, M.V; Font, L; Frantzen, K; Fruck, C; Galindo, D; López, R J García; Garczarczyk, M; Terrats, D Garrido; Gaug, M; Godinović, N; Muñoz, A González; Gozzini, S R; Hadasch, D; Hanabata, Y; Hayashida, M; Herrera, J; Hose, J; Hrupec, D; Idec, W; Kadenius, V; Kellermann, H; Knoetig, M L; Kodani, K; Konno, Y; Krause, J; Kubo, H; Kushida, J; La Barbera, A; Lelas, D; Lewandowska, N; Lindfors, E; Lombardi, S; Longo, F; López, M; López-Coto, R; López-Oramas, A; Lorenz, E; Lozano, I; Makariev, M; Mallot, K; Maneva, G; Mannheim, K; Maraschi, L; Marcote, B; Mariotti, M; Martínez, M; Mazin, D; Menzel, U; Miranda, J M; Mirzoyan, R; Moralejo, A; Munar-Adrover, P; Nakajima, D; Neustroev, V; Niedzwiecki, A; Nilsson, K; Nishijima, K; Noda, K; Orito, R; Overkemping, A; Paiano, S; Palatiello, M; Paneque, D; Paoletti, R; Paredes, J M; Paredes-Fortuny, X; Persic, M; Poutanen, J; Moroni, P G Prada; Prandini, E; Puljak, I; Reinthal, R; Rhode, W; Ribó, M; Rico, J; Garcia, J Rodriguez; Rügamer, S; Saito, T; Saito, K; Satalecka, K; Scalzotto, V; Scapin, V; Schultz, C; Schweizer, T; Sillanpää, A; Sitarek, J; Snidaric, I; Sobczynska, D; Spanier, F; Stamerra, A; Steinbring, T; Storz, J; Strzys, M; Takalo, L; Takami, H; Tavecchio, F; Temnikov, P; Terzić, T; Tescaro, D; Teshima, M; Thaele, J; Tibolla, O; Torres, D F; Toyama, T; Treves, A; Vogler, P; Will, M; Zanin, R; D'Ammando, F; Lähteenmäki, A; Tornikoski, M; Hovatta, T; Readhead, A C S; Max-Moerbeck, W; Richards, J.L

    2015-01-01

    PG 1553+113 is a very-high-energy (VHE, E>100 GeV) gamma-ray emitter classified as a BL Lac object. Its redshift is constrained by intergalactic absorption lines in the range 0.40.2). The observed curvature is compatible with the extragalactic background light (EBL) imprint predicted by the current generation of EBL models assuming a redshift z~0.4. New constraints on the redshift were derived from the VHE spectrum. These constraints are compatible with previous limits and suggest that the source is most likely located around the optical lower limit, z=0.4. Finally, we find that the synchrotron self-Compton (SSC) model gives a satisfactory description of the observed multi-wavelength spectral energy distribution during the flare.

  15. Dust-deficient Palomar-Green Quasars and the Diversity of AGN Intrinsic IR Emission

    Energy Technology Data Exchange (ETDEWEB)

    Lyu, Jianwei; Rieke, G. H. [Steward Observatory, University of Arizona, 933 North Cherry Avenue, Tucson, AZ 85721 (United States); Shi, Yong, E-mail: jianwei@email.arizona.edu [School of Astronomy and Space Science, Nanjing University, Nanjing 210093 (China)

    2017-02-01

    To elucidate the intrinsic broadband infrared (IR) emission properties of active galactic nuclei (AGNs), we analyze the spectral energy distributions (SEDs) of 87 z ≲ 0.5 Palomar-Green (PG) quasars. While the Elvis AGN template with a moderate far-IR correction can reasonably match the SEDs of the AGN components in ∼60% of the sample (and is superior to alternatives such as that by Assef), it fails on two quasar populations: (1) hot-dust-deficient (HDD) quasars that show very weak emission thoroughly from the near-IR to the far-IR, and (2) warm-dust-deficient (WDD) quasars that have similar hot dust emission as normal quasars but are relatively faint in the mid- and far-IR. After building composite AGN templates for these dust-deficient quasars, we successfully fit the 0.3–500 μm SEDs of the PG sample with the appropriate AGN template, an infrared template of a star-forming galaxy, and a host galaxy stellar template. 20 HDD and 12 WDD quasars are identified from the SED decomposition, including seven ambiguous cases. Compared with normal quasars, the HDD quasars have AGNs with relatively low Eddington ratios and the fraction of WDD quasars increases with AGN luminosity. Moreover, both the HDD and WDD quasar populations show relatively stronger mid-IR silicate emission. Virtually identical SED properties are also found in some quasars from z = 0.5 to 6. We propose a conceptual model to demonstrate that the observed dust deficiency of quasars can result from a change of structures of the circumnuclear tori that can occur at any cosmic epoch.

  16. Spectral reflectance relationships to leaf water stress

    Science.gov (United States)

    Ripple, William J.

    1986-01-01

    Spectral reflectance data were collected from detached snapbean leaves in the laboratory with a multiband radiometer. Four experiments were designed to study the spectral response resulting from changes in leaf cover, relative water content of leaves, and leaf water potential. Spectral regions included in the analysis were red (630-690 nm), NIR (760-900 nm), and mid-IR (2.08-2.35 microns). The red and mid-IR bands showed sensitivity to changes in both leaf cover and relative water content of leaves. The NIR was only highly sensitive to changes in leaf cover. Results provided evidence that mid-IR reflectance was governed primarily by leaf moisture content, although soil reflectance was an important factor when leaf cover was less than 100 percent. High correlations between leaf water potentials and reflectance were attributed to covariances with relative water content of leaves and leaf cover.

  17. Diagnosing x-ray power and energy of tungsten wire array z-pinch with a flat spectral response x-ray diode

    International Nuclear Information System (INIS)

    Wang, Kun-lun; Ren, Xiao-dong; Huang, Xian-bin; Zhang, Si-qun; Zhou, Shao-tong; Dan, Jia-kun; Li, Jing; Xu, Qiang; Ouyang, Kai; Cai, Hong-chun; Wei, Bing; Ji, Ce; Feng, Shu-ping; Wang, Meng; Xie, Wei-ping; Deng, Jian-jun

    2015-01-01

    Fast z-pinch is a very efficient way of converting electromagnetic energy to radiation. With an 8-10 MA current on primary test stand facility, about 1 MJ electromagnetic energy is delivered to vacuum chamber, which heats z-pinch plasma to radiate soft x-ray. To develop a pulsed high power x-ray source, we studied the applicability of diagnosing x-ray power from tungsten wire array z-pinch with a flat spectral response x-ray diode (FSR-XRD). The detector was originally developed to diagnose radiation of a hohlraum in SG-III prototype laser facility. It utilized a gold cathode XRD and a specially configured compound gold filter to yield a nearly flat spectral response in photon energy range of 0.1-4 keV. In practice, it was critical to avoid surface contamination of gold cathode. It is illustrated that an exposure of an XRD to multiple shots caused a significant change of response. Thus, in diagnosing x-ray power and energy, we used each XRD in only one shot after calibration. In a shot serial, output of FSR-XRD was compared with output of a nickel bolometer. In these shots, the outputs agreed with each other within their uncertainties which were about 12% for FSR-XRD and about 15% for bolometer. Moreover, the ratios between the FSR-XRD and the bolometer among different shots were explored. In 8 shots, the standard deviation of the ratio was 6%. It is comparable to XRD response change of 7%

  18. Linearly Polarized IR Spectroscopy Theory and Applications for Structural Analysis

    CERN Document Server

    Kolev, Tsonko

    2011-01-01

    A technique that is useful in the study of pharmaceutical products and biological molecules, polarization IR spectroscopy has undergone continuous development since it first emerged almost 100 years ago. Capturing the state of the science as it exists today, "Linearly Polarized IR Spectroscopy: Theory and Applications for Structural Analysis" demonstrates how the technique can be properly utilized to obtain important information about the structure and spectral properties of oriented compounds. The book starts with the theoretical basis of linear-dichroic infrared (IR-LD) spectroscop

  19. ChromAIX2: A large area, high count-rate energy-resolving photon counting ASIC for a Spectral CT Prototype

    Science.gov (United States)

    Steadman, Roger; Herrmann, Christoph; Livne, Amir

    2017-08-01

    Spectral CT based on energy-resolving photon counting detectors is expected to deliver additional diagnostic value at a lower dose than current state-of-the-art CT [1]. The capability of simultaneously providing a number of spectrally distinct measurements not only allows distinguishing between photo-electric and Compton interactions but also discriminating contrast agents that exhibit a K-edge discontinuity in the absorption spectrum, referred to as K-edge Imaging [2]. Such detectors are based on direct converting sensors (e.g. CdTe or CdZnTe) and high-rate photon counting electronics. To support the development of Spectral CT and show the feasibility of obtaining rates exceeding 10 Mcps/pixel (Poissonian observed count-rate), the ChromAIX ASIC has been previously reported showing 13.5 Mcps/pixel (150 Mcps/mm2 incident) [3]. The ChromAIX has been improved to offer the possibility of a large area coverage detector, and increased overall performance. The new ASIC is called ChromAIX2, and delivers count-rates exceeding 15 Mcps/pixel with an rms-noise performance of approximately 260 e-. It has an isotropic pixel pitch of 500 μm in an array of 22×32 pixels and is tile-able on three of its sides. The pixel topology consists of a two stage amplifier (CSA and Shaper) and a number of test features allowing to thoroughly characterize the ASIC without a sensor. A total of 5 independent thresholds are also available within each pixel, allowing to acquire 5 spectrally distinct measurements simultaneously. The ASIC also incorporates a baseline restorer to eliminate excess currents induced by the sensor (e.g. dark current and low frequency drifts) which would otherwise cause an energy estimation error. In this paper we report on the inherent electrical performance of the ChromAXI2 as well as measurements obtained with CZT (CdZnTe)/CdTe sensors and X-rays and radioactive sources.

  20. On the Spatially Resolved Star Formation History in M51. I. Hybrid UV+IR Star Formation Laws and IR Emission from Dust Heated by Old Stars

    Science.gov (United States)

    Eufrasio, R. T.; Lehmer, B. D.; Zezas, A.; Dwek, E.; Arendt, R. G.; Basu-Zych, A.; Wiklind, T.; Yukita, M.; Fragos, T.; Hornschemeier, A. E.; Markwardt, L.; Ptak, A.; Tzanavaris, P.

    2017-12-01

    We present LIGHTNING, a new spectral energy distribution fitting procedure, capable of quickly and reliably recovering star formation history (SFH) and extinction parameters. The SFH is modeled as discrete steps in time. In this work, we assumed lookback times of 0-10 Myr, 10-100 Myr, 0.1-1 Gyr, 1-5 Gyr, and 5-13.6 Gyr. LIGHTNING consists of a fully vectorized inversion algorithm to determine SFH step intensities and combines this with a grid-based approach to determine three extinction parameters. We apply our procedure to the extensive far-UV-to-far-IR photometric data of M51, convolved to a common spatial resolution and pixel scale, and make the resulting maps publicly available. We recover, for M51a, a peak star formation rate (SFR) between 0.1 and 5 Gyr ago, with much lower star formation activity over the past 100 Myr. For M51b, we find a declining SFR toward the present day. In the outskirt regions of M51a, which includes regions between M51a and M51b, we recover an SFR peak between 0.1 and 1 Gyr ago, which corresponds to the effects of the interaction between M51a and M51b. We utilize our results to (1) illustrate how UV+IR hybrid SFR laws vary across M51 and (2) provide first-order estimates for how the IR luminosity per unit stellar mass varies as a function of the stellar age. From the latter result, we find that IR emission from dust heated by stars is not always associated with young stars and that the IR emission from M51b is primarily powered by stars older than 5 Gyr.

  1. IR Spectroscopy. An introduction

    International Nuclear Information System (INIS)

    Guenzler, H.; Gremlich, H.U.

    2002-01-01

    The following topics are dealt with: absorption and molecular design, spectrometers, sample preparation, qualitative spectral interpretation and assertions, near-infrared and far-infrared spectroscopy, reference spectra and expert systems

  2. Direct glycan structure determination of intact N-linked glycopeptides by low-energy collision-induced dissociation tandem mass spectrometry and predicted spectral library searching.

    Science.gov (United States)

    Pai, Pei-Jing; Hu, Yingwei; Lam, Henry

    2016-08-31

    Intact glycopeptide MS analysis to reveal site-specific protein glycosylation is an important frontier of proteomics. However, computational tools for analyzing MS/MS spectra of intact glycopeptides are still limited and not well-integrated into existing workflows. In this work, a new computational tool which combines the spectral library building/searching tool, SpectraST (Lam et al. Nat. Methods2008, 5, 873-875), and the glycopeptide fragmentation prediction tool, MassAnalyzer (Zhang et al. Anal. Chem.2010, 82, 10194-10202) for intact glycopeptide analysis has been developed. Specifically, this tool enables the determination of the glycan structure directly from low-energy collision-induced dissociation (CID) spectra of intact glycopeptides. Given a list of possible glycopeptide sequences as input, a sample-specific spectral library of MassAnalyzer-predicted spectra is built using SpectraST. Glycan identification from CID spectra is achieved by spectral library searching against this library, in which both m/z and intensity information of the possible fragmentation ions are taken into consideration for improved accuracy. We validated our method using a standard glycoprotein, human transferrin, and evaluated its potential to be used in site-specific glycosylation profiling of glycoprotein datasets from LC-MS/MS. In addition, we further applied our method to reveal, for the first time, the site-specific N-glycosylation profile of recombinant human acetylcholinesterase expressed in HEK293 cells. For maximum usability, SpectraST is developed as part of the Trans-Proteomic Pipeline (TPP), a freely available and open-source software suite for MS data analysis. Copyright © 2016 Elsevier B.V. All rights reserved.

  3. Airborne pipeline leak detection: UV or IR?

    Science.gov (United States)

    Babin, François; Gravel, Jean-François; Allard, Martin

    2016-05-01

    This paper presents a study of different approaches to the measurement of the above ground vapor plume created by the spill caused by a small 0.1 l/min (or less) leak in an underground liquid petroleum pipeline. The scenarios are those for the measurement from an airborne platform. The usual approach is that of IR absorption, but in the case of liquid petroleum products, there are drawbacks that will be discussed, especially when using alkanes to detect a leak. The optical measurements studied include UV enhanced Raman lidar, UV fluorescence lidar and IR absorption path integrated lidars. The breadboards used for testing the different approaches will be described along with the set-ups for leak simulation. Although IR absorption would intuitively be the most sensitive, it is shown that UV-Raman could be an alternative. When using the very broad alkane signature in the IR, the varying ground spectral reflectance are a problem. It is also determined that integrated path measurements are preferred, the UV enhanced Raman measurements showing that the vapor plume stays very close to the ground.

  4. SYNTHESIS, IR AND NMR SPECTRAL CORRELATIONS IN SOME ...

    African Journals Online (AJOL)

    Preferred Customer

    reaction of interest to chemists up to date in the fields of macrocyclic and supramolecular chemistry. The diimines or bisimines or bis-Schiff's bases also been ... [12] have studied the effects of substituent on infrared C=N, nuclear magnetic ...

  5. Power scaling of ultrafast mid-IR source enabled by high-power fiber laser technology

    International Nuclear Information System (INIS)

    Zhou, Gengji

    2017-11-01

    Ultrafast laser sources with high repetition-rate (>10 MHz) and tunable in the mid-infrared (IR) wavelength range of 7-18 μm hold promise for many important spectroscopy applications. Currently, these ultrafast mid- to longwavelength-IR sources can most easily be achieved via difference-frequency generation (DFG) between a pump beam and a signal beam. However, current ultrafast mid- to longwavelength-IR sources feature a low average power, which limits their applications. In this thesis, we propose and demonstrate a novel approach to power scaling of DFG-based ultrafast mid-IR laser sources. The essence of this novel approach is the generation of a high-energy signal beam. Both the pump beam and the signal beam are derived from a home-built Yb-fiber laser system that emits 165-fs pulses centered at 1035 nm with 30-MHz repetition rate and 14.5-W average power (corresponding to 483-nJ pulse energy). We employ fiber-optic self-phase modulation (SPM) to broaden the laser spectrum and generate isolated spectral lobes. Filtering the rightmost spectral lobe leads to femtosecond pulses with >10 nJ pulse energy. Tunable between 1.1-1.2 μm, this SPM-enabled ultrafast source exhibits ∝100 times higher pulse energy than can be obtained from Raman soliton sources in this wavelength range. We use this SPM-enabled source as the signal beam and part of the Yb-fiber laser output as the pump beam. By performing DFG in GaSe crystals, we demonstrate that power scaling of a DFG-based mid-IR source can be efficiently achieved by increasing the signal energy. The resulting mid-IR source is tunable from 7.4 μm to 16.8 μm. Up to 5.04-mW mid-IR pulses centered at 11 μm are achieved. The corresponding pulse energy is 167 pJ, representing nearly one order of magnitude improvement compared with other reported DFG-based mid-IR sources at this wavelength. Despite of low pulse energy, Raman soliton sources have become a popular choice as the signal source. We carry out a detailed study on

  6. Power scaling of ultrafast mid-IR source enabled by high-power fiber laser technology

    Energy Technology Data Exchange (ETDEWEB)

    Zhou, Gengji

    2017-11-15

    Ultrafast laser sources with high repetition-rate (>10 MHz) and tunable in the mid-infrared (IR) wavelength range of 7-18 μm hold promise for many important spectroscopy applications. Currently, these ultrafast mid- to longwavelength-IR sources can most easily be achieved via difference-frequency generation (DFG) between a pump beam and a signal beam. However, current ultrafast mid- to longwavelength-IR sources feature a low average power, which limits their applications. In this thesis, we propose and demonstrate a novel approach to power scaling of DFG-based ultrafast mid-IR laser sources. The essence of this novel approach is the generation of a high-energy signal beam. Both the pump beam and the signal beam are derived from a home-built Yb-fiber laser system that emits 165-fs pulses centered at 1035 nm with 30-MHz repetition rate and 14.5-W average power (corresponding to 483-nJ pulse energy). We employ fiber-optic self-phase modulation (SPM) to broaden the laser spectrum and generate isolated spectral lobes. Filtering the rightmost spectral lobe leads to femtosecond pulses with >10 nJ pulse energy. Tunable between 1.1-1.2 μm, this SPM-enabled ultrafast source exhibits ∝100 times higher pulse energy than can be obtained from Raman soliton sources in this wavelength range. We use this SPM-enabled source as the signal beam and part of the Yb-fiber laser output as the pump beam. By performing DFG in GaSe crystals, we demonstrate that power scaling of a DFG-based mid-IR source can be efficiently achieved by increasing the signal energy. The resulting mid-IR source is tunable from 7.4 μm to 16.8 μm. Up to 5.04-mW mid-IR pulses centered at 11 μm are achieved. The corresponding pulse energy is 167 pJ, representing nearly one order of magnitude improvement compared with other reported DFG-based mid-IR sources at this wavelength. Despite of low pulse energy, Raman soliton sources have become a popular choice as the signal source. We carry out a detailed study on

  7. Energy Calibration of a Silicon-Strip Detector for Photon-Counting Spectral CT by Direct Usage of the X-ray Tube Spectrum

    Science.gov (United States)

    Liu, Xuejin; Chen, Han; Bornefalk, Hans; Danielsson, Mats; Karlsson, Staffan; Persson, Mats; Xu, Cheng; Huber, Ben

    2015-02-01

    The variation among energy thresholds in a multibin detector for photon-counting spectral CT can lead to ring artefacts in the reconstructed images. Calibration of the energy thresholds can be used to achieve homogeneous threshold settings or to develop compensation methods to reduce the artefacts. We have developed an energy-calibration method for the different comparator thresholds employed in a photon-counting silicon-strip detector. In our case, this corresponds to specifying the linear relation between the threshold positions in units of mV and the actual deposited photon energies in units of keV. This relation is determined by gain and offset values that differ for different detector channels due to variations in the manufacturing process. Typically, the calibration is accomplished by correlating the peak positions of obtained pulse-height spectra to known photon energies, e.g. with the aid of mono-energetic x rays from synchrotron radiation, radioactive isotopes or fluorescence materials. Instead of mono-energetic x rays, the calibration method presented in this paper makes use of a broad x-ray spectrum provided by commercial x-ray tubes. Gain and offset as the calibration parameters are obtained by a regression analysis that adjusts a simulated spectrum of deposited energies to a measured pulse-height spectrum. Besides the basic photon interactions such as Rayleigh scattering, Compton scattering and photo-electric absorption, the simulation takes into account the effect of pulse pileup, charge sharing and the electronic noise of the detector channels. We verify the method for different detector channels with the aid of a table-top setup, where we find the uncertainty of the keV-value of a calibrated threshold to be between 0.1 and 0.2 keV.

  8. Measurement of high-energy (10–60 keV) x-ray spectral line widths with eV accuracy

    Energy Technology Data Exchange (ETDEWEB)

    Seely, J. F., E-mail: seelyjf@gmail.com; Feldman, U. [Artep Inc., 2922 Excelsior Springs Court, Ellicott City, Maryland 21042 (United States); Glover, J. L.; Hudson, L. T.; Ralchenko, Y.; Henins, Albert [National Institute of Standards and Technology, Gaithersburg, Maryland 20899 (United States); Pereira, N. [Ecopulse Inc., P. O. Box 528, Springfield, Virginia 22152 (United States); Di Stefano, C. A.; Kuranz, C. C.; Drake, R. P. [University of Michigan, Ann Arbor, Michigan 48109 (United States); Chen, Hui; Williams, G. J.; Park, J. [Lawrence Livermore National Laboratory, Livermore, California 94551 (United States)

    2014-11-15

    A high resolution crystal spectrometer utilizing a crystal in transmission geometry has been developed and experimentally optimized to measure the widths of emission lines in the 10–60 keV energy range with eV accuracy. The spectrometer achieves high spectral resolution by utilizing crystal planes with small lattice spacings (down to 2d = 0.099 nm), a large crystal bending radius and Rowland circle diameter (965 mm), and an image plate detector with high spatial resolution (60 μm in the case of the Fuji TR image plate). High resolution W L-shell and K-shell laboratory test spectra in the 10–60 keV range and Ho K-shell spectra near 47 keV recorded at the LLNL Titan laser facility are presented. The Ho K-shell spectra are the highest resolution hard x-ray spectra recorded from a solid target irradiated by a high-intensity laser.

  9. Evaluation of intensity and energy interaction parameters for the complexation of Pr(III) with selected nucleoside and nucleotide through absorption spectral studies

    Science.gov (United States)

    Bendangsenla, N.; Moaienla, T.; David Singh, Th.; Sumitra, Ch.; Rajmuhon Singh, N.; Indira Devi, M.

    2013-02-01

    The interactions of Pr(III) with nucleosides and nucleotides have been studied in different organic solvents employing absorption difference and comparative absorption spectrophotometry. The magnitudes of the variations in both energy and intensity interaction parameters were used to explore the degree of outer and inner sphere co-ordination, incidence of covalency and the extent of metal 4f-orbital involvement in chemical bonding. Various electronic spectral parameters like Slater-Condon (Fk), Racah (Ek), Lande parameter (ξ4f), Nephelauxatic ratio (β), bonding (b1/2), percentage covalency (δ) and intensity parameters like oscillator strength (P) and Judd Ofelt electronic dipole intensity parameter (Tλ, λ = 2, 4, 6) have been evaluated. The variation of these evaluated parameters were employed to interpret the nature of binding of Pr(III) with different ligands i.e. Adenosine/ATP in presence and absence of Ca2+.

  10. Observations of the Hubble Deep Field with the Infrared Space Observatory .5. Spectral energy distributions, starburst models and star formation history

    DEFF Research Database (Denmark)

    Rowan Robinson, M.; Mann, R.G.; Oliver, S.J.

    1997-01-01

    We have modelled the spectral energy distributions of the 13 Hubble Deep Field (HDF) galaxies reliably detected by the Infrared Space Observatory (ISO). For two galaxies the emission detected by ISO is consistent with being starlight or the infrared 'cirrus' in the galaxies. For the remaining II...... galaxies there is a clear midinfrared excess, which we interpret as emission from dust associated with a strong starburst. 10 of these galaxies are spirals or interacting pairs, while the remaining one is an elliptical with a prominent nucleus and broad emission lines. We give a new discussion of how...... compared with nearby normal galaxies, We discuss the implications of our detections for the history of star and heavy element formation in the Universe, Although uncertainties in the calibration, reliability of source detection, associations and starburst models remain, it is clear that dust plays...

  11. Spectral studies of 2-pyrazoline derivatives: structural elucidation through single crystal XRD and DFT calculations.

    Science.gov (United States)

    Chinnaraja, D; Rajalakshmi, R; Srinivasan, T; Velmurugan, D; Jayabharathi, J

    2014-04-24

    A series of biologically active N-thiocarbamoyl pyrazoline derivatives have been synthesized using anhydrous potassium carbonate as the catalyst. All the synthesized compounds were characterized by FT-IR, (1)H NMR, (13)C NMR spectral studies, LCMS, CHN Analysis and X-ray diffraction analysis (compound 7). In order to supplement the XRD parameters, molecular modelling was carried out by Gaussian 03W. From the optimized structure, the energy, dipolemoment and HOMO-LUMO energies of all the systems were calculated. Copyright © 2014 Elsevier B.V. All rights reserved.

  12. The color of X-rays: Spectral X-ray computed tomography using energy sensitive pixel detectors

    NARCIS (Netherlands)

    Schioppa, E.J.

    2014-01-01

    Energy sensitive X-ray imaging detectors are produced by connecting a semiconductor sensor to a spectroscopic pixel readout chip. In this thesis, the applicability of such detectors to X-ray Computed Tomography (CT) is studied. A prototype Medipix based silicon detector is calibrated using X-ray

  13. Pixelated coatings and advanced IR coatings

    Science.gov (United States)

    Pradal, Fabien; Portier, Benjamin; Oussalah, Meihdi; Leplan, Hervé

    2017-09-01

    Reosc developed pixelated infrared coatings on detector. Reosc manufactured thick pixelated multilayer stacks on IR-focal plane arrays for bi-spectral imaging systems, demonstrating high filter performance, low crosstalk, and no deterioration of the device sensitivities. More recently, a 5-pixel filter matrix was designed and fabricated. Recent developments in pixelated coatings, shows that high performance infrared filters can be coated directly on detector for multispectral imaging. Next generation space instrument can benefit from this technology to reduce their weight and consumptions.

  14. Inhomogeneous spectral moment sum rules for the retarded Green function and self-energy of strongly correlated electrons or ultracold fermionic atoms in optical lattices

    International Nuclear Information System (INIS)

    Freericks, J. K.; Turkowski, V.

    2009-01-01

    Spectral moment sum rules are presented for the inhomogeneous many-body problem described by the fermionic Falicov-Kimball or Hubbard models. These local sum rules allow for arbitrary hoppings, site energies, and interactions. They can be employed to quantify the accuracy of numerical solutions to the inhomogeneous many-body problem such as strongly correlated multilayered devices, ultracold atoms in an optical lattice with a trap potential, strongly correlated systems that are disordered, or systems with nontrivial spatial ordering such as a charge-density wave or a spin-density wave. We also show how the spectral moment sum rules determine the asymptotic behavior of the Green function, self-energy, and dynamical mean field when applied to the dynamical mean-field theory solution of the many-body problem. In particular, we illustrate in detail how one can dramatically reduce the number of Matsubara frequencies needed to solve the Falicov-Kimball model while still retaining high precision, and we sketch how one can incorporate these results into Hirsch-Fye quantum Monte Carlo solvers for the Hubbard (or more complicated) models. Since the solution of inhomogeneous problems is significantly more time consuming than periodic systems, efficient use of these sum rules can provide a dramatic speed up in the computational time required to solve the many-body problem. We also discuss how these sum rules behave in nonequilibrium situations as well, where the Hamiltonian has explicit time dependence due to a driving field or due to the time-dependent change in a parameter such as the interaction strength or the origin of the trap potential.

  15. Effect of a novel intracycle motion correction algorithm on dual-energy spectral coronary CT angiography: A study with pulsating coronary artery phantom at high heart rates

    Energy Technology Data Exchange (ETDEWEB)

    Xing, Yan; Zhao, Yuan; Pan, Cun Xue; Azati, Gulina; Wang, Yan Wei; Liu, Wen Ya [Imaging Center, The First Affiliated Hospital of Xinjiang Medical University, Xinjiang (China); Guo, Ning [CT Imaging Research Center, GE Healthcare, Beijing (China)

    2017-11-15

    Using a pulsating coronary artery phantom at high heart rate settings, we investigated the efficacy of a motion correction algorithm (MCA) to improve the image quality in dual-energy spectral coronary CT angiography (CCTA). Coronary flow phantoms were scanned at heart rates of 60–100 beats/min at 10-beats/min increments, using dual-energy spectral CT mode. Virtual monochromatic images were reconstructed from 50 to 90 keV at 10-keV increments. Two blinded observers assessed image quality using a 4-point Likert Scale (1 = non-diagnostic, 4 = excellent) and the fraction of interpretable segments using MCA versus conventional algorithm (CA). Comparison of variables was performed with the Wilcoxon rank sum test and McNemar test. At heart rates of 70, 80, 90, and 100 beats/min, images with MCA were rated as higher image scores compared to those with CA on monochromatic levels of 50, 60, and 70 keV (each p < 0.05). Meanwhile, at a heart rate of 90 beats/min, image interpretability was improved by MCA at a monochromatic level of 60 keV (p < 0.05) and 70 keV (p < 0.05). At a heart rate of 100 beats/min, image interpretability was improved by MCA at monochromatic levels of 50 keV (from 69.4% to 86.1%, p < 0.05), 60 keV (from 55.6% to 83.3%, p < 0.05) and 70 keV (from 33.3% to 69.3%, p < 0.05). Low-keV monochromatic images combined with MCA improves image quality and image interpretability in CCTAs at high heart rates.

  16. Ames S-32 O-16 O-18 Line List for High-Resolution Experimental IR Analysis

    Science.gov (United States)

    Huang, Xinchuan; Schwenke, David W.; Lee, Timothy J.

    2016-01-01

    By comparing to the most recent experimental data and spectra of the SO2 628 ?1/?3 bands (see Ulenikov et al., JQSRT 168 (2016) 29-39), this study illustrates the reliability and accuracy of the Ames-296K SO2 line list, which is accurate enough to facilitate such high-resolution spectroscopic analysis. The SO2 628 IR line list is computed on a recently improved potential energy surface (PES) refinement, denoted Ames-Pre2, and the published purely ab initio CCSD(T)/aug-cc-pVQZ dipole moment surface. Progress has been made in both energy level convergence and rovibrational quantum number assignments agreeing with laboratory analysis models. The accuracy of the computed 628 energy levels and line list is similar to what has been achieved and reported for SO2 626 and 646, i.e. 0.01-0.03 cm(exp -1) for bands up to 5500 cm(exp -1). During the comparison, we found some discrepancies in addition to overall good agreements. The three-IR-list based feature-by-feature analysis in a 0.25 cm(exp -1) spectral window clearly demonstrates the power of the current Ames line lists with new assignments, correction of some errors, and intensity contributions from varied sources including other isotopologues. We are inclined to attribute part of detected discrepancies to an incomplete experimental analysis and missing intensity in the model. With complete line position, intensity, and rovibrational quantum numbers determined at 296 K, spectroscopic analysis is significantly facilitated especially for a spectral range exhibiting such an unusually high density of lines. The computed 628 rovibrational levels and line list are accurate enough to provide alternatives for the missing bands or suspicious assignments, as well as helpful to identify these isotopologues in various celestial environments. The next step will be to revisit the SO2 828 and 646 spectral analyses.

  17. Methanol decomposition and oxidation on Ir(111)

    NARCIS (Netherlands)

    Weststrate, C.J.; Ludwig, W.; Bakker, J.W.; Gluhoi, A.C.; Nieuwenhuys, B.E.

    2007-01-01

    The adsorption, decompn., and oxidn. of methanol (CH3OH) has been studied on Ir(111) using temp.-programmed desorption and high-energy resoln. fast XPS. Mol. methanol desorption from a methanol-satd. surface at low temp. shows three desorption peaks, around 150 K (alpha ), around 170 K (beta 1), and

  18. Spectral range calculation inside the Research Irradiating Facility Army Technology Center using code MCNPX and comparison with the spectra of energy Caesium 137 raised in laboratory

    International Nuclear Information System (INIS)

    Gomes, Renato G.; Rebello, Wilson F.; Cavaliere, Marcos Paulo; Vellozo, Sergio O.; Moreira Junior, Luis; Vital, Helio C.; Silva, Ademir X.

    2013-01-01

    Using the MCNPX code, the objective was to calculate by means of computer simulation spectroscopy range inside the irradiation chamber upper radiator gamma research irradiating facility Army Technology Center (CTEx). The calculations were performed in the spectral range usual 2 points for research purposes irradiating the energy spectra of gamma rays from the source of Cesium chloride 137. Sought the discretization of the spectrum in 100 channels at points of upper bound of 1cm higher and lower dose rates previously known. It was also conducted in the laboratory lifting the spectrum of Cesium-137 source using NaI scintillator detector and multichannel analyzer. With the source spectrum Cesium-137 contained in the literature and raised in the laboratory, both used as reference for comparison and analysis in terms of probability of emission maximum of 0.661 MeV The spectra were quite consistent in terms of the behavior of the energy distributions with scores. The position of maximum dose rate showed absorption detection almost maximum energy of 0.661 MeV photopeak In the spectrum of the position of minimum dosage rate, it was found that due to the removal of the source point of interest, some loss detection were caused by Compton scattering. (author)

  19. Multichannel Dynamic Fourier-Transform IR Spectrometer

    Science.gov (United States)

    Balashov, A. A.; Vaguine, V. A.; Golyak, Il. S.; Morozov, A. N.; Khorokhorin, A. I.

    2017-09-01

    A design of a multichannel continuous scan Fourier-transform IR spectrometer for simultaneous recording and analysis of the spectral characteristics of several objects is proposed. For implementing the design, a multi-probe fiber is used, constructed from several optical fibers connected into a single optical connector and attached at the output of the interferometer. The Fourier-transform spectrometer is used as a signal modulator. Each fiber is individually mated with an investigated sample and a dedicated radiation detector. For the developed system, the radiation intensity of the spectrometer is calculated from the condition of the minimum spectral resolution and parameters of the optical fibers. Using the proposed design, emission spectra of a gas-discharge neon lamp have been recorded using a single fiber 1 mm in diameter with a numerical aperture NA = 0.22.

  20. Third-generation intelligent IR focal plane arrays

    Science.gov (United States)

    Caulfield, H. John; Jack, Michael D.; Pettijohn, Kevin L.; Schlesselmann, John D.; Norworth, Joe

    1998-03-01

    SBRC is at the forefront of industry in developing IR focal plane arrays including multi-spectral technology and '3rd generation' functions that mimic the human eye. 3rd generation devices conduct advanced processing on or near the FPA that serve to reduce bandwidth while performing needed functions such as automatic target recognition, uniformity correction and dynamic range enhancement. These devices represent a solution for processing the exorbitantly high bandwidth coming off large area FPAs without sacrificing systems sensitivity. SBRC's two-color approach leverages the company's HgCdTe technology to provide simultaneous multiband coverage, from short through long wave IR, with near theoretical performance. IR systems that are sensitive to different spectral bands achieve enhanced capabilities for target identification and advanced discrimination. This paper will provide a summary of the issues, the technology and the benefits of SBRC's third generation smart and two-color FPAs.

  1. Spectral measurements of few-electron uranium ions produced and trapped in a high-energy electron beam ion trap

    International Nuclear Information System (INIS)

    Beiersdorfer, P.

    1994-01-01

    Measurements of 2s l/2 -2p 3/2 electric dipole and 2p 1/2 -2p 3/2 magnetic dipole and electric quadrupole transitions in U 82+ through U 89+ have been made with a high-resolution crystal spectrometer that recorded the line radiation from stationary ions produced and trapped in a high-energy electron beam ion trap. From the measurements we infer -39.21 ± 0.23 eV for the QED contribution to the 2s 1/2 -2p 3/2 transition energy of lithiumlike U 89+ . A comparison between our measurements and various computations illustrates the need for continued improvements in theoretical approaches for calculating the atomic structure of ions with two or more electrons in the L shell

  2. High efficiency direct thermal to electric energy conversion from radioisotope decay using selective emitters and spectrally tuned solar cells

    Science.gov (United States)

    Chubb, Donald L.; Flood, Dennis J.; Lowe, Roland A.

    1993-01-01

    Thermophotovoltaic (TPV) systems are attractive possibilities for direct thermal-to-electric energy conversion, but have typically required the use of black body radiators operating at high temperatures. Recent advances in both the understanding and performance of solid rare-earth oxide selective emitters make possible the use of TPV at temperatures as low as 1200K. Both selective emitter and filter system TPV systems are feasible. However, requirements on the filter system are severe in order to attain high efficiency. A thin-film of a rare-earth oxide is one method for producing an efficient, rugged selective emitter. An efficiency of 0.14 and power density of 9.2 W/KG at 1200K is calculated for a hypothetical thin-film neodymia (Nd2O3) selective emitter TPV system that uses radioisotope decay as the thermal energy source.

  3. High efficiency direct thermal to electric energy conversion from radioisotope decay using selective emitters and spectrally tuned solar cells

    International Nuclear Information System (INIS)

    Chubb, D.L.; Flood, D.J.; Lowe, R.A.

    1993-08-01

    Thermophotovoltaic (TPV) systems are attractive possibilities for direct thermal-to-electric energy conversion, but have typically required the use of black body radiators operating at high temperatures. Recent advances in both the understanding and performance of solid rare-earth oxide selective emitters make possible the use of TPV at temperatures as low as 1200K. Both selective emitter and filter system TPV systems are feasible. However, requirements on the filter system are severe in order to attain high efficiency. A thin-film of a rare-earth oxide is one method for producing an efficient, rugged selective emitter. An efficiency of 0.14 and power density of 9.2 W/KG at 1200K is calculated for a hypothetical thin-film neodymia (Nd2O3) selective emitter TPV system that uses radioisotope decay as the thermal energy source

  4. The design and application of a multi-band IR imager

    Science.gov (United States)

    Li, Lijuan

    2018-02-01

    Multi-band IR imaging system has many applications in security, national defense, petroleum and gas industry, etc. So the relevant technologies are getting more and more attention in rent years. As we know, when used in missile warning and missile seeker systems, multi-band IR imaging technology has the advantage of high target recognition capability and low false alarm rate if suitable spectral bands are selected. Compared with traditional single band IR imager, multi-band IR imager can make use of spectral features in addition to space and time domain features to discriminate target from background clutters and decoys. So, one of the key work is to select the right spectral bands in which the feature difference between target and false target is evident and is well utilized. Multi-band IR imager is a useful instrument to collect multi-band IR images of target, backgrounds and decoys for spectral band selection study at low cost and with adjustable parameters and property compared with commercial imaging spectrometer. In this paper, a multi-band IR imaging system is developed which is suitable to collect 4 spectral band images of various scenes at every turn and can be expanded to other short-wave and mid-wave IR spectral bands combination by changing filter groups. The multi-band IR imaging system consists of a broad band optical system, a cryogenic InSb large array detector, a spinning filter wheel and electronic processing system. The multi-band IR imaging system's performance is tested in real data collection experiments.

  5. SU-F-T-630: Energy Spectral Study On Lipiodol After Trans-Arterial Chemoembolization Using the Flattened and Unflattened Photon Beams

    Energy Technology Data Exchange (ETDEWEB)

    Kawahara, D [Radiation Therapy Section, Department of Clinical Support, Hiroshima University Hospital, Hiroshima (Japan); Medical and Dental Sciences Course, Graduate School of Biomedical & Health Sciences, Hiroshima University, Hiroshima (Japan); Ozawa, S; Nagata, Y [Department of Radiation Oncology, Institute of Biomedical & Health Sciences, Hiroshima University, Hiroshima (Japan); Hiroshima High-Precision Radiotherapy Cancer Center, Hiroshima (Japan); Saito, A; Nishio, T; Suzuki, T [Department of Radiation Oncology, Institute of Biomedical & Health Sciences, Hiroshima University, Hiroshima (Japan); Hioki, K; Masuda, H; Okumura, T; Ochi, Y; Nakashima, T; Ohno, Y [Radiation Therapy Section, Department of Clinical Support, Hiroshima University Hospital, Hiroshima (Japan); Tanaka, S [Department of Nuclear Engineering and Management, School of Engineering, University of Tokyo, Tokyo (Japan)

    2016-06-15

    Purpose: SBRT combining transarterial chemoembolization with Lipiodol is expected to improve local control. Our showed that the dose enhancement effect in the Lipiodol with 10X flattening filter free (FFF) was inserted. This study was to investigate the energy fluence variations of electron in the Lipiodol using flattened (FF) and FFF beams. Methods: FF and FFF for 6X and 10X beams by TrueBeam were used in this study. The Lipiodol (3 X 3 X 3 cm{sup 3}) was located at the depth of 5 cm in water, the dose enhancement factor (DEF) and energy fluence were calculated by Monte Carlo (MC) calculations (PHITS). Results: DEFs with FF and FFF of 6X were 17.1% and 24.3% at rebuild-up region in the Lipiodol (5.3cm depth), 7.0% and 17.0% at the center of Lipiodol (6.5cm depth), and −13.2% and −8.2% at behind Lipiodol (8.3cm depth). DEFs with FF and FFF of 10X were 21.7% and 15.3% at rebuild-up region, 8.2% and 10.5% at the center of Lipiodol, and −14.0% and −8.6% at behind Lipiodol. Spectral results showed that the FFF beam contained more low-energy (0–0.3MeV) component of electrons than FF beam, and FF beam contained more high-energy (over 0.3MeV) electrons than FFF beam in Lipiodol. Behind the Lipiodol, build-down effect with FF beam was larger than FFF beam because FF beam contained more high energy electrons. The difference of DEFs between FFF and FF beams for 6X were larger than for 10X. This is because 10X beam contained more high-energy electrons. Conclusion: It was found that the 6XFFF beam gives the largest change of energy fluence and the largest DEF in this study. These phenomena are mainly caused by component of low-energy electrons, and this energy is almost correspond to the boundary of photo electronic dominant and Compton scattering dominant region for photon beams.

  6. A Multiwavelength Study of a Sample of 70 μm Selected Galaxies in the COSMOS Field : I. Spectral Energy Distributions and Luminosities

    NARCIS (Netherlands)

    Kartaltepe, Jeyhan S.; Sanders, D. B.; Le Floc'h, E.; Frayer, D. T.; Aussel, H.; Arnouts, S.; Ilbert, O.; Salvato, M.; Scoville, N. Z.; Surace, J.; Yan, L.; Brusa, M.; Capak, P.; Caputi, K.; Carollo, C. M.; Civano, F.; Elvis, M.; Faure, C.; Hasinger, G.; Koekemoer, A. M.; Lee, N.; Lilly, S.; Liu, C. T.; McCracken, H. J.; Schinnerer, E.; Smolčić, V.; Taniguchi, Y.; Thompson, D. J.; Trump, J.

    We present a large robust sample of 1503 reliable and unconfused 70 μm selected sources from the multiwavelength data set of the Cosmic Evolution Survey. Using the Spitzer IRAC and MIPS photometry, we estimate the total infrared (IR) luminosity, L IR (8-1000 μm), by finding the best-fit template

  7. Autoionizing energy levels and extended spectral analysis of copper-like gallium and germanium (Ga III, Ge IV)

    International Nuclear Information System (INIS)

    Ryabtsev, A.N.; Wyart, J.F.

    1987-01-01

    The spark spectra of doubly ionized gallium and triply ionized germanium have been observed. Lines broadened by autoionization have been attributed to 3d 9 4p 2 - 3d 10 4p transitions on the basis of parametric studies of the configurations 3d 9 4p 2 + 3d 9 4s4d. Line strengths and autoionization widths support the identifications. The analysis of the 3d 10 nl system has been corrected and extended. The ionization energy of Ge IV is 368 720 cm -1 ± 10 cm -1 . (orig.)

  8. HIGH ENERGY SPECTRAL EVOLUTION OF V404 CYGNI DURING THE 2015 JUNE OUTBURST AS OBSERVED BY INTEGRAL

    Energy Technology Data Exchange (ETDEWEB)

    Natalucci, Lorenzo; Fiocchi, Mariateresa; Bazzano, Angela; Ubertini, Pietro [Istituto di Astrofisica e Planetologia Spaziali, INAF, Via Fosso del Cavaliere 100, I-00133 Roma (Italy); Roques, Jean-Pierre; Jourdain, Elisabeth [Université de Toulouse, UPS-OMP CNRS, IRAP, 9 Av. Colonel Roche, BP 44346, F-31028 Toulouse cedex 4 (France)

    2015-11-01

    The black hole binary GS 2023+338 exhibited an unprecedently bright outburst in 2015 June. On 2015 June 17, the high energy instruments on board INTEGRAL detected an extremely variable emission during both bright and low luminosity phases, with dramatic variations of the hardness ratio on timescales of approximately seconds. The analysis of the IBIS and SPI data reveals the presence of hard spectra in the brightest phases, compatible with thermal Comptonization with a temperature of kT{sub e} ∼ 40 keV. The seed photon’s temperature is best fit by kT{sub 0} ∼ 7 keV, which is too high to be compatible with blackbody emission from the disk. This result is consistent with the seed photons being provided by a different source, which we hypothesize to be a synchrotron driven component in the jet. During the brightest phase of flares, the hardness shows a complex pattern of correlation with flux, with the maximum energy released in the range of 40–100 keV. The hard-X-ray variability for E > 50 keV is correlated with flux variations in the softer band, showing that the overall source variability cannot originate entirely from absorption, but at least part of it is due to the central accreting source.

  9. Data fusion of Landsat TM and IRS images in forest classification

    Science.gov (United States)

    Guangxing Wang; Markus Holopainen; Eero Lukkarinen

    2000-01-01

    Data fusion of Landsat TM images and Indian Remote Sensing satellite panchromatic image (IRS-1C PAN) was studied and compared to the use of TM or IRS image only. The aim was to combine the high spatial resolution of IRS-1C PAN to the high spectral resolution of Landsat TM images using a data fusion algorithm. The ground truth of the study was based on a sample of 1,020...

  10. IR-IR Conformation Specific Spectroscopy of Na+(Glucose) Adducts

    Science.gov (United States)

    Voss, Jonathan M.; Kregel, Steven J.; Fischer, Kaitlyn C.; Garand, Etienne

    2018-01-01

    We report an IR-IR double resonance study of the structural landscape present in the Na+(glucose) complex. Our experimental approach involves minimal modifications to a typical IR predissociation setup, and can be carried out via ion-dip or isomer-burning methods, providing additional flexibility to suit different experimental needs. In the current study, the single-laser IR predissociation spectrum of Na+(glucose), which clearly indicates contributions from multiple structures, was experimentally disentangled to reveal the presence of three α-conformers and five β-conformers. Comparisons with calculations show that these eight conformations correspond to the lowest energy gas-phase structures with distinctive Na+ coordination. [Figure not available: see fulltext.

  11. L-H bifurcations as phase transitions, the role of zonal flows and the spectral energy transfer

    International Nuclear Information System (INIS)

    Shats, M.G.; Punzmann, H.; Xia, H.; Solomon, W.M.

    2003-01-01

    An overview of new results related to the physics of confinement bifurcations in the H-1 heliac is presented. A macroscopic description of the transport modifications across L-H transitions in H-1 suggests several analogies between these bifurcations and phase transitions. Among them is the nucleation in phase transitions which is manifested in the plasma both in time and in space. A microscopic picture reveals the importance of zonal flows, or time-varying shear radial electric field in the spatio-temporal structure of confinement bifurcations. In particular, the effect of zonal flows on the fluctuation-driven transport in H-1 is discussed. Finally, new results on the mechanism of generation of large coherent structures and zonal flows are reviewed. It is shown that inverse energy cascades in turbulent spectra are responsible for the structure generation in H-1. (orig.)

  12. Ultraviolet spectral energy differences affect the ability of sunscreen lotions to prevent ultraviolet-radiation-induced immunosuppression

    International Nuclear Information System (INIS)

    Roberts, L.K.; Beasley, D.G.; Learn, D.B.; Giddens, L.D.; Beard, J.; Stanfield, J.W.

    1996-01-01

    Acute exposure to UV radiation causes immunosuppression of contact hypersensitivity (CH) responses. Past studies conducted with unfiltered sunlamps emitting non-solar spectrum UV power (wavelengths below 295 nm) or using excessive UV doses have suggested sunscreens may not prevent UV-induced immunosuppression in mice. This study was thus designed to evaluate critically the effects of different UV energy spectra on the immune protection capacity of sunscreen lotions. Minimum immune suppression doses (MISD), i.e. the lowest UV dose to cause ∼ 50% suppression of the CH response to dinitrofluorobenzene in C3H mice, were established for three artificial UV sources. The MISD for each UV source was 0.25 kJ/m 2 for unfiltered FS20 sunlamps (FS), 0.90 kJ/m 2 for Kodacel-filtered FS20 sunlamps (KFS), which do not emit UV power at wavelengths 2 for a 1000 W filtered xenon arc lamp solar simulator. Using MISD as baseline, sunscreens with labeled sun protection factors (SPF) of 2, 8, 15 and 30 were tested with each UV source to establish their relative immune protection factors. The immune protection factor of each sunscreen exceeded its labeled SPF in tests conducted with the solar simulator, which has a UV power spectrum (295-400 nm) similar to that of sunlight. Conversely, sunscreen immune protection factors were significantly less than the labeled SPF in tests conducted with FS and KFS. Comparison of the immunosuppression effectiveness spectra showed that relatively small amounts of nonsolar spectrum UV energy, i.e. UVC (200-290 nm) and/or shorter wavelength UVB (between 290 and 295 nm), produced by FS and KFS contributes significantly to the induction of immunosuppression. (Author)

  13. Potential energy and dipole moment surfaces for HF@C60: Prediction of spectral and electric response properties

    Science.gov (United States)

    Kalugina, Yulia N.; Roy, Pierre-Nicholas

    2017-12-01

    We present a five-dimensional potential energy surface (PES) for the HF@C60 system computed at the DF-LMP2/cc-pVTZ level of theory. We also calculated a five-dimensional dipole moment surface (DMS) based on DFT(PBE0)/cc-pVTZ calculations. The HF and C60 molecules are considered rigid with bond length rHF = 0.9255 Å (gas phase ground rovibrational state geometry). The C60 geometry is of Ih symmetry. The ab initio points were fitted to obtain a PES in terms of bipolar spherical harmonics. The minimum of the PES corresponds to a geometry where the center of mass of HF is located 0.11 Å away from the center of the cage with an interaction energy of -6.929 kcal/mol. The DMS was also represented in terms of bipolar spherical harmonics. The PES was used to calculate the rotation-translation bound states of HF@C60, and good agreement was found relative to the available experimental data [A. Krachmalnicoff et al., Nat. Chem. 8, 953 (2016)] except for the splitting of the first rotational excitation levels. We propose an empirical adjustment to the PES in order to account for the experimentally observed symmetry breaking. The form of that effective PES is additive. We also propose an effective Hamiltonian with an adjusted rotational constant in order to quantitatively reproduce the experimental results including the splitting of the first rotational state. We use our models to compute the molecular volume polarizability of HF confined by C60 and obtain good agreement with experiment.

  14. High-temperature partition functions, specific heats and spectral radiative properties of diatomic molecules with an improved calculation of energy levels

    Science.gov (United States)

    Qin, Z.; Zhao, J. M.; Liu, L. H.

    2018-05-01

    The level energies of diatomic molecules calculated by the frequently used Dunham expansion will become less accurate for high-lying vibrational and rotational levels. In this paper, the potential curves for the lower-lying electronic states with accurate spectroscopic constants are reconstructed using the Rydberg-Klein-Rees (RKR) method, which are extrapolated to the dissociation limits by fitting of the theoretical potentials, and the rest of the potential curves are obtained from the ab-initio results in the literature. Solving the rotational dependence of the radial Schrödinger equation over the obtained potential curves, we determine the rovibrational level energies, which are then used to calculate the equilibrium and non-equilibrium thermodynamic properties of N2, N2+, NO, O2, CN, C2, CO and CO+. The partition functions and the specific heats are systematically validated by available data in the literature. Finally, we calculate the radiative source strengths of diatomic molecules in thermodynamic equilibrium, which agree well with the available values in the literature. The spectral radiative intensities for some diatomic molecules in thermodynamic non-equilibrium are calculated and validated by available experimental data.

  15. Characterization by Fourier transform infrared spectroscopy (FT-IR) and 2D IR correlation spectroscopy of a carbosilane dendrimer with peripheral ammonium groups

    Energy Technology Data Exchange (ETDEWEB)

    Popescu, Maria-Cristina, E-mail: cpopescu@icmpp.ro [' Petru Poni' Institute of Macromolecular Chemistry (Romania); Gomez, Rafael; Mata, Fco Javier de la; Rasines, Beatriz [Universidad de Alcala, Departamento de Quimica Inorganica (Spain); Simionescu, Bogdan C. [' Petru Poni' Institute of Macromolecular Chemistry (Romania)

    2013-06-15

    Fourier transform infrared spectroscopy and 2D correlation spectroscopy were used to study the microstructural changes occurring on heating of a new carbosilane dendrimer with peripheral ammonium groups. Temperature-dependent spectral variations in the 3,010-2,710, 1,530-1,170, and 1,170-625 cm{sup -1} regions were monitored during the heating process. The dependence, on temperature, of integral absorptions and position of spectral bands was established and the spectral modifications associated with molecular conformation rearrangements, allowing molecular shape changes, were found. Before 180 Degree-Sign C, the studied carbosilane dendrimer proved to be stable, while at higher temperatures it oxidizes and Si-O groups appear. 2D IR correlation spectroscopy gives new information about the effect of temperature on the structure and dynamics of the system. Synchronous and asynchronous spectra indicate that, at low temperature, conformational changes of CH{sub 3} and CH{sub 3}-N{sup +} groups take place first. With increasing temperature, the intensity variation of the CH{sub 2}, C-N, Si-C and C-C groups from the dendritic core is faster than that of the terminal units. This indicates that, with increasing temperature, the segments of the dendritic core obtain enough energy to change their conformation more easily as compared to the terminal units, due to their internal flexibility.

  16. Characterization by Fourier transform infrared spectroscopy (FT-IR) and 2D IR correlation spectroscopy of a carbosilane dendrimer with peripheral ammonium groups

    International Nuclear Information System (INIS)

    Popescu, Maria-Cristina; Gómez, Rafael; Mata, Fco Javier de la; Rasines, Beatriz; Simionescu, Bogdan C.

    2013-01-01

    Fourier transform infrared spectroscopy and 2D correlation spectroscopy were used to study the microstructural changes occurring on heating of a new carbosilane dendrimer with peripheral ammonium groups. Temperature-dependent spectral variations in the 3,010–2,710, 1,530–1,170, and 1,170–625 cm −1 regions were monitored during the heating process. The dependence, on temperature, of integral absorptions and position of spectral bands was established and the spectral modifications associated with molecular conformation rearrangements, allowing molecular shape changes, were found. Before 180 °C, the studied carbosilane dendrimer proved to be stable, while at higher temperatures it oxidizes and Si–O groups appear. 2D IR correlation spectroscopy gives new information about the effect of temperature on the structure and dynamics of the system. Synchronous and asynchronous spectra indicate that, at low temperature, conformational changes of CH 3 and CH 3 –N + groups take place first. With increasing temperature, the intensity variation of the CH 2 , C–N, Si–C and C–C groups from the dendritic core is faster than that of the terminal units. This indicates that, with increasing temperature, the segments of the dendritic core obtain enough energy to change their conformation more easily as compared to the terminal units, due to their internal flexibility.

  17. IR and the Earth

    DEFF Research Database (Denmark)

    Corry, Olaf; Stevenson, Hayley

    2017-01-01

    , in the end, one finite interconnected space. Together these two starting points make for the basic conundrum of Inter- national Relations and the Earth: how does a divided world live on a single globe? This introduction first provides an overview of the recent rise of ‘the environment’ in international......, ‘what has the environment ever done for IR?’, before the plan for the rest of the book sketches the content and direction of the ensuing chapters that explore the problematique of International Relations and the Earth....

  18. Improving the spectral analysis of Fluorescence Resonance Energy Transfer in live cells: application to interferon receptors and Janus kinases.

    Science.gov (United States)

    Krause, Christopher D; Digioia, Gina; Izotova, Lara S; Pestka, Sidney

    2013-10-01

    The observed Fluorescence Resonance Energy Transfer (FRET) between fluorescently labeled proteins varies in cells. To understand how this variation affects our interpretation of how proteins interact in cells, we developed a protocol that mathematically separates donor-independent and donor-dependent excitations of acceptor, determines the electromagnetic interaction of donors and acceptors, and quantifies the efficiency of the interaction of donors and acceptors. By analyzing large populations of cells, we found that misbalanced or insufficient expression of acceptor or donor as well as their inefficient or reversible interaction influenced FRET efficiency in vivo. Use of red-shifted donors and acceptors gave spectra with less endogenous fluorescence but produced lower FRET efficiency, possibly caused by reduced quenching of red-shifted fluorophores in cells. Additionally, cryptic interactions between jellyfish FPs artefactually increased the apparent FRET efficiency. Our protocol can distinguish specific and nonspecific protein interactions even within highly constrained environments as plasma membranes. Overall, accurate FRET estimations in cells or within complex environments can be obtained by a combination of proper data analysis, study of sufficient numbers of cells, and use of properly empirically developed fluorescent proteins. Copyright © 2013 Elsevier Ltd. All rights reserved.

  19. Material decomposition through weighted imaged subtraction in dual-energy spectral mammography with an energy-resolved photon-counting detector using Monte Carlo Simulation

    Energy Technology Data Exchange (ETDEWEB)

    Eom, Ji Soo; Kang, Soon Cheol; Lee, Seung Wan [Konyang University, Daejeon (Korea, Republic of)

    2017-09-15

    Mammography is commonly used for screening early breast cancer. However, mammographic images, which depend on the physical properties of breast components, are limited to provide information about whether a lesion is malignant or benign. Although a dual-energy subtraction technique decomposes a certain material from a mixture, it increases radiation dose and degrades the accuracy of material decomposition. In this study, we simulated a breast phantom using attenuation characteristics, and we proposed a technique to enable the accurate material decomposition by applying weighting factors for the dual-energy mammography based on a photon-counting detector using a Monte Carlo simulation tool. We also evaluated the contrast and noise of simulated breast images for validating the proposed technique. As a result, the contrast for a malignant tumor in the dual-energy weighted subtraction technique was 0.98 and 1.06 times similar than those in the general mammography and dual-energy subtraction techniques, respectively. However the contrast between malignant and benign tumors dramatically increased 13.54 times due to the low contrast of a benign tumor. Therefore, the proposed technique can increase the material decomposition accuracy for malignant tumor and improve the diagnostic accuracy of mammography.

  20. Noncommutativity from spectral flow

    Energy Technology Data Exchange (ETDEWEB)

    Heinzl, Thomas; Ilderton, Anton [School of Mathematics and Statistics, University of Plymouth, Drake Circus, Plymouth PL4 8AA (United Kingdom)

    2007-07-27

    We investigate the transition from second- to first-order systems. Quantum mechanically, this transforms configuration space into phase space and hence introduces noncommutativity in the former. This transition may be described in terms of spectral flow. Gaps in the energy or mass spectrum may become large which effectively truncates the available state space. Using both operator and path integral languages we explicitly discuss examples in quantum mechanics (light-front) quantum field theory and string theory.

  1. Spectral and Energy Efficient Low-Overhead Uplink and Downlink Channel Estimation for 5G Massive MIMO Systems

    Directory of Open Access Journals (Sweden)

    Imran Khan

    2018-01-01

    Full Text Available Uplink and Downlink channel estimation in massive Multiple Input Multiple Output (MIMO systems is an intricate issue because of the increasing channel matrix dimensions. The channel feedback overhead using traditional codebook schemes is very large, which consumes more bandwidth and decreases the overall system efficiency. The purpose of this paper is to decrease the channel estimation overhead by taking the advantage of sparse attributes and also to optimize the Energy Efficiency (EE of the system. To cope with this issue, we propose a novel approach by using Compressed-Sensing (CS, Block Iterative-Support-Detection (Block-ISD, Angle-of-Departure (AoD and Structured Compressive Sampling Matching Pursuit (S-CoSaMP algorithms to reduce the channel estimation overhead and compare them with the traditional algorithms. The CS uses temporal-correlation of time-varying channels to produce Differential-Channel Impulse Response (DCIR among two CIRs that are adjacent in time-slots. DCIR has greater sparsity than the conventional CIRs as it can be easily compressed. The Block-ISD uses spatial-correlation of the channels to obtain the block-sparsity which results in lower pilot-overhead. AoD quantizes the channels whose path-AoDs variation is slower than path-gains and such information is utilized for reducing the overhead. S-CoSaMP deploys structured-sparsity to obtain reliable Channel-State-Information (CSI. MATLAB simulation results show that the proposed CS based algorithms reduce the feedback and pilot-overhead by a significant percentage and also improve the system capacity as compared with the traditional algorithms. Moreover, the EE level increases with increasing Base Station (BS density, UE density and lowering hardware impairments level.

  2. Detailed IR aperture measurements

    CERN Document Server

    Bruce, Roderik; Garcia Morales, Hector; Giovannozzi, Massimo; Hermes, Pascal Dominik; Mirarchi, Daniele; Quaranta, Elena; Redaelli, Stefano; Rossi, Carlo; Skowronski, Piotr Krzysztof; Wretborn, Sven Joel; CERN. Geneva. ATS Department

    2016-01-01

    MD 1673 was carried out on October 5 2016, in order to investigate in more detail the available aperture in the LHC high-luminosity insertions at 6.5 TeV and β∗=40 cm. Previous aperture measurements in 2016 during commissioning had shown that the available aperture is at the edge of protection, and that the aperture bottleneck at β∗=40 cm in certain cases is found in the separation plane instead of in the crossing plane. Furthermore, the bottlenecks were consistently found in close to the upstream end of Q3 on the side of the incoming beam, and not in Q2 on the outgoing beam as expected from calculations. Therefore, this MD aimed at measuring IR1 and IR5 separately (at 6.5 TeV and β∗=40 cm, for 185 µrad half crossing angle), to further localize the bottlenecks longitudinally using newly installed BLMs, investigate the difference in aperture between Q2 and Q3, and to see if any aperture can be gained using special orbit bumps.

  3. Optical characterization, 1.5 μm emission and IR-to-visible energy upconversion in Er3+-doped fluorotellurite glasses

    International Nuclear Information System (INIS)

    Rodriguez-Mendoza, U.R.; Lalla, E.A.; Caceres, J.M.; Rivera-Lopez, F.; Leon-Luis, S.F.; Lavin, V.

    2011-01-01

    The optical properties of Er 3+ ions in a novel glass based on TeO 2 -PbF 2 -AlF 3 oxyfluoride tellurites have been investigated using steady-state and time-resolved spectroscopies as a function of the rare-earth doping concentration. Basic optical characterizations have been performed measuring and calculating the absorption and emission spectra and the cross-sections, the Judd-Ofelt intensity parameters, the radiative probabilities and the fluorescence decays and lifetimes. Special attention has been devoted to the broad 4 I 13/2 → 4 I 15/2 emission transition at around 1.53 μm since, with a wide broadening of around 70 nm and a relative long lifetime of around 3 ms compared to others glass hosts, it shows potential applications in the design of erbium-doped fiber amplifiers. The absorption, the stimulated emission and the gain cross-sections of this transition have been obtained and compared with that obtained in different hosts. Finally, infrared-to-visible upconversion processes exciting at around 800 nm have been analyzed and different mechanisms involved in the energy conversion have been proposed. - Research highlights: → Broadened emission bands and high absorption and emission cross-sections for the transition 4 I 15/2 → 4 I 13/2 suitable for EDFAs. → Efficient green upconverted emission. → High value of C DA (6) energy transfer parameter.

  4. Evaluation of low-energy contrast-enhanced spectral mammography images by comparing them to full-field digital mammography using EUREF image quality criteria.

    Science.gov (United States)

    Lalji, U C; Jeukens, C R L P N; Houben, I; Nelemans, P J; van Engen, R E; van Wylick, E; Beets-Tan, R G H; Wildberger, J E; Paulis, L E; Lobbes, M B I

    2015-10-01

    Contrast-enhanced spectral mammography (CESM) examination results in a low-energy (LE) and contrast-enhanced image. The LE appears similar to a full-field digital mammogram (FFDM). Our aim was to evaluate LE CESM image quality by comparing it to FFDM using criteria defined by the European Reference Organization for Quality Assured Breast Screening and Diagnostic Services (EUREF). A total of 147 cases with both FFDM and LE images were independently scored by two experienced radiologists using these (20) EUREF criteria. Contrast detail measurements were performed using a dedicated phantom. Differences in image quality scores, average glandular dose, and contrast detail measurements between LE and FFDM were tested for statistical significance. No significant differences in image quality scores were observed between LE and FFDM images for 17 out of 20 criteria. LE scored significantly lower on one criterion regarding the sharpness of the pectoral muscle (p < 0.001), and significantly better on two criteria on the visualization of micro-calcifications (p = 0.02 and p = 0.034). Dose and contrast detail measurements did not reveal any physical explanation for these observed differences. Low-energy CESM images are non-inferior to FFDM images. From this perspective FFDM can be omitted in patients with an indication for CESM. • Low-energy CESM images are non-inferior to FFDM images. • Micro-calcifications are significantly more visible on LE CESM than on FFDM. • There is no physical explanation for this improved visibility of micro-calcifications. • There is no need for an extra FFDM when CESM is indicated.

  5. Impact of metal artifact reduction software on image quality of gemstone spectral imaging dual-energy cerebral CT angiography after intracranial aneurysm clipping

    Energy Technology Data Exchange (ETDEWEB)

    Dunet, Vincent; Bernasconi, Martine; Hajdu, Steven David; Meuli, Reto Antoine; Zerlauth, Jean-Baptiste [Lausanne University Hospital, Department of Diagnostic and Interventional Radiology, Lausanne (Switzerland); Daniel, Roy Thomas [Lausanne University Hospital, Department of Neurosurgery, Lausanne (Switzerland)

    2017-09-15

    We aimed to assess the impact of metal artifact reduction software (MARs) on image quality of gemstone spectral imaging (GSI) dual-energy (DE) cerebral CT angiography (CTA) after intracranial aneurysm clipping. This retrospective study was approved by the institutional review board, which waived patient written consent. From January 2013 to September 2016, single source DE cerebral CTA were performed in 45 patients (mean age: 60 ± 9 years, male 9) after intracranial aneurysm clipping and reconstructed with and without MARs. Signal-to-noise (SNR), contrast-to-noise (CNR), and relative CNR (rCNR) ratios were calculated from attenuation values measured in the internal carotid artery (ICA) and middle cerebral artery (MCA). Volume of clip and artifacts and relative clip blurring reduction (rCBR) ratios were also measured at each energy level with/without MARs. Variables were compared between GSI and GSI-MARs using the paired Wilcoxon signed-rank test. MARs significantly reduced metal artifacts at all energy levels but 130 and 140 keV, regardless of clips' location and number. The optimal rCBR was obtained at 110 and 80 keV, respectively, on GSI and GSI-MARs images, with up to 96% rCNR increase on GSI-MARs images. The best compromise between metal artifact reduction and rCNR was obtained at 70-75 and 65-70 keV for GSI and GSI-MARs images, respectively, with up to 15% rCBR and rCNR increase on GSI-MARs images. MARs significantly reduces metal artifacts on DE cerebral CTA after intracranial aneurysm clipping regardless of clips' location and number. It may be used to reduce radiation dose while increasing CNR. (orig.)

  6. Direct Determination of Molecular Weight Distribution of Calf-Thymus DNAs and Study of Their Fragmentation under Ultrasonic and Low-Energy IR Irradiations. A Charge Detection Mass Spectrometry Investigation.

    Science.gov (United States)

    Halim, Mohammad A; Bertorelle, Franck; Doussineau, Tristan; Antoine, Rodolphe

    2018-06-09

    Calf-thymus (CT-DNA) is widely used as binding agent. The commercial samples are known to be "highly polymerized DNA" samples. CT-DNA is known to be fragile in particular upon ultrasonic wave irradiation. Degradation products might have dramatic consequence on its bio-sensing activity, and an accurate determination of the molecular weight distribution and stability of commercial samples is highly demanded. We investigated the sensitivity of charge detection mass spectrometry (CDMS), a single-molecule MS method, both with single-pass and ion trap CDMS ("Benner" trap) modes to the determination of the composition and stability (under multiphoton IR irradiation) of calf-thymus DNAs. We also investigated the changes of molecular weight distributions in the course of sonication by irradiating ultrasonic wave to CT-DNA. We report for the first time, the direct molecular weight (MW) distribution of DNA sodium salt from calf-thymus revealing two populations at high (~10 MDa) and low (~3 MDa) molecular weights. We evidence a transition between the high-MW to the low-MW distribution, confirming that the low-MW distribution results from degradation of CT-DNA. Finally, we report also IRMPD experiments carried out on trapped single-stranded linear DNAs from calf-thymus allowing to extract their activation energy for unimolecular dissociation. We show that single-pass CDMS is a direct, efficient and accurate MS-based approach to determine the composition of calf-thymus DNAs. Furthermore, ion trap CDMS allows us to evaluate the stability (both under multiphoton IR irradiation and in the course of sonication by irradiating ultrasonic wave) of calf-thymus DNAs. This article is protected by copyright. All rights reserved.

  7. Design and analysis of an energy-efficient O-QPSK coherent IR-UWB transceiver with a 0.52° RMS phase-noise fractional synthesizer

    Science.gov (United States)

    Ying, Yutong; Lin, Fujiang; Bai, Xuefei

    2018-03-01

    This paper explores an energy-efficient pulsed ultra-wideband (UWB) radio-frequency (RF) front-end chip fabricated in 0.18-μm CMOS technology, including a transmitter, receiver, and fractional synthesizer. The transmitter adopts a digital offset quadrature phase-shift keying (O-QPSK) modulator and passive direct-phase multiplexing technology, which are energy- and hardware-efficient, to enhance the data rate for a given spectrum. A passive mixer and a capacitor cross-coupled (CCC) source-follower driving amplifier (DA) are also designed for the transmitter to further reduce the low power consumption. For the receiver, a power-aware low-noise amplifier (LNA) and a quadrature mixer are applied. The LNA adopts a CCC boost common-gate amplifier as the input stage, and its current is reused for the second stage to save power. The mixer uses a shared amplification stage for the following passive IQ mixer. Phase noise suppression of the phase-locked loop (PLL) is achieved by utilizing an even-harmonics-nulled series-coupled quadrature oscillator (QVCO) and an in-band noise-aware charge pump (CP) design. The transceiver achieves a measured data rate of 0.8 Gbps with power consumption of 16 mW and 31.5 mW for the transmitter and the receiver, respectively. The optimized integrated phase noise of the PLL is 0.52° at 4.025 GHz. Project supported by the National Science and Technology Major Project of China (No. 2011ZX03004-002-01).

  8. FELI linac for IR- and UV-FEL facilities

    International Nuclear Information System (INIS)

    Tomimasu, T.; Morii, Y.; Abe, S.

    1995-01-01

    FELI linac and IR-FEL facilities are now under construction and electron beams of 30-75MeV will be used for FIR- and IR-FEL experiments in this summer. It is composed of a 5-MeV electron injector and seven ETL type accelerating waveguides with a length of 2.93m (2π/3 mode, linearly tapered type). The injector consists of a 150-kV DC thermoionic triode gun operated by a 178.5-MHz and 500-ps pulser, a 714-MHz prebuncher (SHB), and a 2856-MHz standing wave type buncher (SWB). The linac is operated in three modes of 24μs, 12.5μs and 0.5μs. With a choice of three modes, the maximum beam loaded energy can be changed from 165 MeV to 288 MeV. The linac beam is sent to four vertical type undulators using S-type BT systems installed at 30-MeV, 75-MeV, 120-MeV, and 165-MeV sections at a 24-μs pulse beam load. The beam, once used for lasing at 30-MeV section or at 75-MeV section, can be bent back to the following accelerating waveguide and is reaccelerated and reused for lasing. Parameters of four undulators and intended FEL applications are shown. FEL spectral widths and wavelength limitations are also reviewed and discussed for 0.3μm FEL oscillations FELI is aiming at by the end of 1996. (author)

  9. Characterization and identification of microorganisms by FT-IR microspectrometry

    Science.gov (United States)

    Ngo-Thi, N. A.; Kirschner, C.; Naumann, D.

    2003-12-01

    We report on a novel FT-IR approach for microbial characterization/identification based on a light microscope coupled to an infrared spectrometer which offers the possibility to acquire IR-spectra of microcolonies containing only few hundred cells. Microcolony samples suitable for FT-IR microspectroscopic measurements were obtained by a replica technique with a stamping device that transfers spatially accurate cells of microcolonies growing on solid culture plates to a special, IR-transparent or reflecting stamping plate. High quality spectra could be recorded either by applying the transmission/absorbance or the reflectance/absorbance mode of the infrared microscope. Signal to noise ratios higher than 1000 were obtained for microcolonies as small as 40 μm in diameter. Reproducibility levels were established that allowed species and strain identification. The differentiation and classification capacity of the FT-IR microscopic technique was tested for different selected microorganisms. Cluster and factor analysis methods were used to evaluate the complex spectral data. Excellent discrimination between bacteria and yeasts, and at the same time Gram-negative and Gram-positive bacterial strains was obtained. Twenty-two selected strains of different species within the genus Staphylococcus were repetitively measured and could be grouped into correct species cluster. Moreover, the results indicated that the method allows also identifications at the subspecies level. Additionally, the new approach allowed spectral mapping analysis of single colonies which provided spatially resolved characterization of growth heterogeneity within complex microbial populations such as colonies.

  10. Traction Inverter Open Switch Fault Diagnosis Based on Choi–Williams Distribution Spectral Kurtosis and Wavelet-Packet Energy Shannon Entropy

    Directory of Open Access Journals (Sweden)

    Shuangshuang Lin

    2017-09-01

    Full Text Available In this paper, a new approach for fault detection and location of open switch faults in the closed-loop inverter fed vector controlled drives of Electric Multiple Units is proposed. Spectral kurtosis (SK based on Choi–Williams distribution (CWD as a statistical tool can effectively indicate the presence of transients and locations in the frequency domain. Wavelet-packet energy Shannon entropy (WPESE is appropriate for the transient changes detection of complex non-linear and non-stationary signals. Based on the analyses of currents in normal and fault conditions, SK based on CWD and WPESE are combined with the DC component method. SK based on CWD and WPESE are used for the fault detection, and the DC component method is used for the fault localization. This approach can diagnose the specific locations of faulty Insulated Gate Bipolar Transistors (IGBTs with high accuracy, and it requires no additional devices. Experiments on the RT-LAB platform are carried out and the experimental results verify the feasibility and effectiveness of the diagnosis method.

  11. Effects of the Distributions of Energy or Charge Transfer Rates on Spectral Hole Burning in Pigment-Protein Complexes at Low Temperatures

    Energy Technology Data Exchange (ETDEWEB)

    Herascu, N.; Ahmouda, S.; Picorel, R.; Seibert, M.; Jankowiak, R.; Zazubovich, V.

    2011-12-22

    Effects of the distributions of excitation energy transfer (EET) rates (homogeneous line widths) on the nonphotochemical (resonant) spectral hole burning (SHB) processes in photosynthetic chlorophyll-protein complexes (reaction center [RC] and CP43 antenna of Photosystem II from spinach) are considered. It is demonstrated that inclusion of such a distribution results in somewhat more dispersive hole burning kinetics. More importantly, however, inclusion of the EET rate distributions strongly affects the dependence of the hole width on the fractional hole depth. Different types of line width distributions have been explored, including those resulting from Foerster type EET between weakly interacting pigments as well as Gaussian ones, which may be a reasonable approximation for those resulting, for instance, from so-called extended Foerster models. For Gaussian line width distributions, it is possible to determine the parameters of both line width and tunneling parameter distributions from SHB data without a priori knowledge of any of them. Concerning more realistic asymmetric distributions, we demonstrate, using the simple example of CP43 antenna, that one can use SHB modeling to estimate electrostatic couplings between pigments and support or exclude assignment of certain pigment(s) to a particular state.

  12. FIRST INTEGRAL OBSERVATIONS OF V404 CYGNI DURING THE 2015 OUTBURST: SPECTRAL BEHAVIOR IN THE 20–650 KeV ENERGY RANGE

    Energy Technology Data Exchange (ETDEWEB)

    Roques, Jean-Pierre; Jourdain, Elisabeth [Université Toulouse, UPS-OMP, CNRS, IRAP, 9 Av. Roche, BP 44346, F-31028 Toulouse (France); Bazzano, Angela; Fiocchi, Mariateresa; Natalucci, Lorenzo; Ubertini, Pietro [Istituto di Astrofisica e Planetologia Spaziali, INAF, Via Fosso del Cavaliere 100, I-00133 Roma, Italy (Italy)

    2015-11-01

    In 2015 June, the source V404 Cygni (= GS2023+38) underwent an extraordinary outburst. We present the results obtained during the first revolution dedicated to this target by the INTEGRAL mission and focus on the spectral behavior in the hard X-ray domain, using both SPI and IBIS instruments. The source exhibits extreme variability and reaches fluxes of several tens of Crab. However, the emission between 20 and 650 keV can be understood in terms of two main components, varying on all the observable timescales, similar to what is observed in the persistent black hole system Cyg X-1. The low-energy component (up to ∼200 keV) presents a rather unusual shape, probably due to the intrinsic source variability. Nonetheless, a satisfactory description is obtained with a Comptonization model, if an unusually hot population of seed photons (kT{sub 0} ∼ 7 keV) is introduced. Above this first component, a clear excess extending up to 400–600 keV leads us to investigate a scenario where an additional (cutoff) power law could correspond to the contribution of the jet synchrotron emission, as proposed in Cyg X-1. A search for an annihilation feature did not provide any firm detection, with an upper limit of 2 × 10{sup −4} ph cm{sup −2} s{sup −1} (2σ) for a narrow line centered at 511 keV, on the averaged obtained spectrum.

  13. Using Large-Eddy Simulations to Define Spectral and Coherence Characteristics of the Hurricane Boundary Layer for Wind-Energy Applications

    Science.gov (United States)

    Worsnop, Rochelle P.; Bryan, George H.; Lundquist, Julie K.; Zhang, Jun A.

    2017-10-01

    Offshore wind-energy development is planned for regions where hurricanes commonly occur, such as the USA Atlantic Coast. Even the most robust wind-turbine design (IEC Class I) may be unable to withstand a Category-2 hurricane (hub-height wind speeds >50 m s^{-1}). Characteristics of the hurricane boundary layer that affect the structural integrity of turbines, especially in major hurricanes, are poorly understood, primarily due to a lack of adequate observations that span typical turbine heights (wind profiles of an idealized Category-5 hurricane at high spatial (10 m) and temporal (0.1 s) resolution. By comparison with unique flight-level observations from a field project, we find that a relatively simple configuration of the Cloud Model I model accurately represents the properties of Hurricane Isabel (2003) in terms of mean wind speeds, wind-speed variances, and power spectra. Comparisons of power spectra and coherence curves derived from our hurricane simulations to those used in current turbine design standards suggest that adjustments to these standards may be needed to capture characteristics of turbulence seen within the simulated hurricane boundary layer. To enable improved design standards for wind turbines to withstand hurricanes, we suggest modifications to account for shifts in peak power to higher frequencies and greater spectral coherence at large separations.

  14. The IRS-1 signaling system.

    Science.gov (United States)

    Myers, M G; Sun, X J; White, M F

    1994-07-01

    Insulin-receptor substrate 1 (IRS-1) is a principal substrate of the receptor tyrosine kinase for insulin and insulin-like growth factor 1, and a substrate for a tyrosine kinase activated by interleukin 4. IRS-1 undergoes multisite tyrosine phosphorylation and mediates downstream signals by 'docking' various proteins that contain Src homology 2 domains. IRS-1 appears to be a unique molecule; however, 4PS, a protein found mainly in hemopoietic cells, may represent another member of this family.

  15. Growth and phase transformations of Ir on Ge(111)

    Science.gov (United States)

    Mullet, C. H.; Stenger, B. H.; Durand, A. M.; Morad, J. A.; Sato, Y.; Poppenheimer, E. C.; Chiang, S.

    2017-12-01

    The growth of Ir on Ge(111) as a function of temperature between 23 °C and 820 °C is characterized with low energy electron microscopy (LEEM), low energy electron diffraction (LEED), scanning tunneling microscopy (STM), and x-ray photoemission spectroscopy (XPS). Deposition onto a substrate at 350 °C revealed a novel growth mode consisting of multilayer Ir islands with (√3 × √3)R30° (abbreviated as √3) structure interconnected by ;bridges; of single-layer Ir several atoms wide. For deposition onto substrates above 500 °C, the √3 Ir phase grows with dendritic morphology, and substrate step bunches act as barriers to √3 Ir growth. LEEM images showed Stranski-Krastanov growth for 650-820 °C: after the √3 phase covers the surface, corresponding to 2 monolayers (ML) Ir coverage, multilayer hexagonal-shaped Ir islands form, surrounded by regions of IrGe alloy. Hexagonal-shaped Ir islands also formed upon heating 1.2 ML of √3 Ir beyond 830 °C, which resulted in the elimination of √3 structure from the surface. The transformation from √3 to (1 × 1) structure upon heating to 830 °C was an irreversible surface phase transition. Annealing > 2.0 ML of Ir in the √3 phase above the 830 °C disorder temperature, followed by cooling, produced a (3 × 1) structure. Subsequent heating and cooling through 830 °C give evidence for a reversible (3 × 1) to (1 × 1) phase transition.

  16. Spectral features in the cosmic ray fluxes

    Science.gov (United States)

    Lipari, Paolo

    2018-01-01

    The cosmic ray energy distributions contain spectral features, that is narrow energy regions where the slope of the spectrum changes rapidly. The identification and study of these features is of great importance to understand the astrophysical mechanisms of acceleration and propagation that form the spectra. In first approximation a spectral feature is often described as a discontinuous change in slope, however very valuable information is also contained in its width, that is the length of the energy interval where the change in spectral index develops. In this work we discuss the best way to define and parameterize the width a spectral feature, and for illustration discuss some of the most prominent known structures.

  17. Rayleigh imaging in spectral mammography

    Science.gov (United States)

    Berggren, Karl; Danielsson, Mats; Fredenberg, Erik

    2016-03-01

    Spectral imaging is the acquisition of multiple images of an object at different energy spectra. In mammography, dual-energy imaging (spectral imaging with two energy levels) has been investigated for several applications, in particular material decomposition, which allows for quantitative analysis of breast composition and quantitative contrast-enhanced imaging. Material decomposition with dual-energy imaging is based on the assumption that there are two dominant photon interaction effects that determine linear attenuation: the photoelectric effect and Compton scattering. This assumption limits the number of basis materials, i.e. the number of materials that are possible to differentiate between, to two. However, Rayleigh scattering may account for more than 10% of the linear attenuation in the mammography energy range. In this work, we show that a modified version of a scanning multi-slit spectral photon-counting mammography system is able to acquire three images at different spectra and can be used for triple-energy imaging. We further show that triple-energy imaging in combination with the efficient scatter rejection of the system enables measurement of Rayleigh scattering, which adds an additional energy dependency to the linear attenuation and enables material decomposition with three basis materials. Three available basis materials have the potential to improve virtually all applications of spectral imaging.

  18. Development of pixellated Ir-TESs

    Science.gov (United States)

    Zen, Nobuyuki; Takahashi, Hiroyuki; Kunieda, Yuichi; Damayanthi, Rathnayaka M. T.; Mori, Fumiakira; Fujita, Kaoru; Nakazawa, Masaharu; Fukuda, Daiji; Ohkubo, Masataka

    2006-04-01

    We have been developing Ir-based pixellated superconducting transition edge sensors (TESs). In the area of material or astronomical applications, the sensor with few eV energy resolution and over 1000 pixels imaging property is desired. In order to achieve this goal, we have been analyzing signals from pixellated TESs. In the case of a 20 pixel array of Ir-TESs, with 45 μm×45 μm pixel sizes, the incident X-ray signals have been classified into 16 groups. We have applied numerical signal analysis. On the one hand, the energy resolution of our pixellated TES is strongly degraded. However, using pulse shape analysis, we can dramatically improve the resolution. Thus, we consider that the pulse signal analysis will lead this device to be used as a practical photon incident position identifying TES.

  19. Development of pixellated Ir-TESs

    International Nuclear Information System (INIS)

    Zen, Nobuyuki; Takahashi, Hiroyuki; Kunieda, Yuichi; Dayanthi, Rathnayaka M.T.; Mori, Fumiakira; Fujita, Kaoru; Nakazawa, Masaharu; Fukuda, Daiji; Ohkubo, Masataka

    2006-01-01

    We have been developing Ir-based pixellated superconducting transition edge sensors (TESs). In the area of material or astronomical applications, the sensor with few eV energy resolution and over 1000 pixels imaging property is desired. In order to achieve this goal, we have been analyzing signals from pixellated TESs. In the case of a 20 pixel array of Ir-TESs, with 45 μmx45 μm pixel sizes, the incident X-ray signals have been classified into 16 groups. We have applied numerical signal analysis. On the one hand, the energy resolution of our pixellated TES is strongly degraded. However, using pulse shape analysis, we can dramatically improve the resolution. Thus, we consider that the pulse signal analysis will lead this device to be used as a practical photon incident position identifying TES

  20. Development of Ir/Au-TES microcalorimeter

    International Nuclear Information System (INIS)

    Kunieda, Yuichi; Fukuda, Daiji; Ohno, Masashi; Nakazawa, Masaharu; Takahashi, Hiroyuki; Ataka, Manabu; Ohkubo, Masataka; Hirayama, Fuminori

    2004-01-01

    We are developing X-ray microcalorimeters using transition edge sensors (TES) for high resolution x-ray spectroscopy. Microcalorimeters are thermal detectors which measure the energy of an incident x-ray photon using a TES thermometer operated at a sharp transition edge between normal and superconducting states. TES microcalorimeters can achieve faster response than conventional microcalorimeters by keeping the operating point of TES in the transition region through the use of strong negative electrothermal feedback (ETF). We developed a bilayer TES where a normal metal Au was deposited on a superconductor Ir in order to improve the thermal conductivity of the Ir-TES. We investigated resistance-temperature characteristics. As a result, it showed a very sharp transition within 1 mK at the temperature of 110 mK. The energy resolution of 9.4 eV (FWHM) was achieved for a 5899 eV Mn K al line. (author)

  1. Hybrid spectral CT reconstruction.

    Directory of Open Access Journals (Sweden)

    Darin P Clark

    Full Text Available Current photon counting x-ray detector (PCD technology faces limitations associated with spectral fidelity and photon starvation. One strategy for addressing these limitations is to supplement PCD data with high-resolution, low-noise data acquired with an energy-integrating detector (EID. In this work, we propose an iterative, hybrid reconstruction technique which combines the spectral properties of PCD data with the resolution and signal-to-noise characteristics of EID data. Our hybrid reconstruction technique is based on an algebraic model of data fidelity which substitutes the EID data into the data fidelity term associated with the PCD reconstruction, resulting in a joint reconstruction problem. Within the split Bregman framework, these data fidelity constraints are minimized subject to additional constraints on spectral rank and on joint intensity-gradient sparsity measured between the reconstructions of the EID and PCD data. Following a derivation of the proposed technique, we apply it to the reconstruction of a digital phantom which contains realistic concentrations of iodine, barium, and calcium encountered in small-animal micro-CT. The results of this experiment suggest reliable separation and detection of iodine at concentrations ≥ 5 mg/ml and barium at concentrations ≥ 10 mg/ml in 2-mm features for EID and PCD data reconstructed with inherent spatial resolutions of 176 μm and 254 μm, respectively (point spread function, FWHM. Furthermore, hybrid reconstruction is demonstrated to enhance spatial resolution within material decomposition results and to improve low-contrast detectability by as much as 2.6 times relative to reconstruction with PCD data only. The parameters of the simulation experiment are based on an in vivo micro-CT experiment conducted in a mouse model of soft-tissue sarcoma. Material decomposition results produced from this in vivo data demonstrate the feasibility of distinguishing two K-edge contrast agents with

  2. Hybrid spectral CT reconstruction

    Science.gov (United States)

    Clark, Darin P.

    2017-01-01

    Current photon counting x-ray detector (PCD) technology faces limitations associated with spectral fidelity and photon starvation. One strategy for addressing these limitations is to supplement PCD data with high-resolution, low-noise data acquired with an energy-integrating detector (EID). In this work, we propose an iterative, hybrid reconstruction technique which combines the spectral properties of PCD data with the resolution and signal-to-noise characteristics of EID data. Our hybrid reconstruction technique is based on an algebraic model of data fidelity which substitutes the EID data into the data fidelity term associated with the PCD reconstruction, resulting in a joint reconstruction problem. Within the split Bregman framework, these data fidelity constraints are minimized subject to additional constraints on spectral rank and on joint intensity-gradient sparsity measured between the reconstructions of the EID and PCD data. Following a derivation of the proposed technique, we apply it to the reconstruction of a digital phantom which contains realistic concentrations of iodine, barium, and calcium encountered in small-animal micro-CT. The results of this experiment suggest reliable separation and detection of iodine at concentrations ≥ 5 mg/ml and barium at concentrations ≥ 10 mg/ml in 2-mm features for EID and PCD data reconstructed with inherent spatial resolutions of 176 μm and 254 μm, respectively (point spread function, FWHM). Furthermore, hybrid reconstruction is demonstrated to enhance spatial resolution within material decomposition results and to improve low-contrast detectability by as much as 2.6 times relative to reconstruction with PCD data only. The parameters of the simulation experiment are based on an in vivo micro-CT experiment conducted in a mouse model of soft-tissue sarcoma. Material decomposition results produced from this in vivo data demonstrate the feasibility of distinguishing two K-edge contrast agents with a spectral

  3. Interpretation of IR and Raman spectra of dopamine neurotransmitter and effect of hydrogen bond in HCl

    Science.gov (United States)

    Yadav, T.; Mukherjee, V.

    2018-05-01

    The potential energy scanning with respect to the different dihedral angles were performed to search possible numbers of dopamine (neutral) conformers and further, fifteen conformers of dopamine were identified on the basis of energy minima. Vibrational frequencies were calculated for all the conformers of dopamine. Density functional theory was employed to carry out all the computations. The exchange correlation functional B3LYP and the basis set 6-31++G(d,p) were included in DFT calculation. The FTIR and FT-Raman spectra of dopamine hydrochloride were also recorded in the spectral region 400-4000 cm-1 and 50-4000 cm-1 respectively. The normal coordinate analysis was also performed to scale DFT calculated force constants and to calculate potential energy distributions. The detailed vibrational spectral analysis and the assignments of the bands, done on the best-fit basis comparison of the experimentally obtained and theoretically calculated IR and Raman spectra, match quite well indicating DFT calculations as very accurate source of normal mode assignments. The interaction of the most stable conformer of dopamine with HCl was also studied to know the effect of hydrogen bond on its geometry and dynamics. The stability of the dopamine in isolated and protonated forms arising from hyperconjugative interactions was also analyzed by natural bond orbital analysis.

  4. Robustness of the charge-ordered phases in IrTe2 against photoexcitation

    Science.gov (United States)

    Monney, C.; Schuler, A.; Jaouen, T.; Mottas, M.-L.; Wolf, Th.; Merz, M.; Muntwiler, M.; Castiglioni, L.; Aebi, P.; Weber, F.; Hengsberger, M.

    2018-02-01

    We present a time-resolved angle-resolved photoelectron spectroscopy study of IrTe2, which undergoes two first-order structural and charge-ordered phase transitions on cooling below 270 K and below 180 K. The possibility of inducing a phase transition by photoexcitation with near-infrared femtosecond pulses is investigated in the charge-ordered phases. We observe changes of the spectral function occurring within a few hundreds of femtoseconds and persisting up to several picoseconds, which we interpret as a partial photoinduced phase transition (PIPT). The necessary time for photoinducing these spectral changes increases with increasing photoexcitation density and reaches time scales longer than the rise time of the transient electronic temperature. We conclude that the PIPT is driven by a transient increase of the lattice temperature following the energy transfer from the electrons. However, the photoinduced changes of the spectral function are small, which indicates that the low-temperature phase is particularly robust against photoexcitation. We suggest that the system might be trapped in an out-of-equilibrium state, for which only a partial structural transition is achieved.

  5. MO-FG-CAMPUS-IeP1-01: Alternative K-Edge Filters for Low-Energy Image Acquisition in Contrast Enhanced Spectral Mammography

    Energy Technology Data Exchange (ETDEWEB)

    Shrestha, S; Vedantham, S; Karellas, A [University of Massachusetts Medical School, Worcester, MA (United States)

    2016-06-15

    Purpose: In Contrast Enhanced Spectral Mammography (CESM), Rh filter is often used during low-energy image acquisition. The potential for using Ag, In and Sn filters, which exhibit K-edge closer to, and just below that of Iodine, instead of the Rh filter, was investigated for the low-energy image acquisition. Methods: Analytical computations of the half-value thickness (HVT) and the photon fluence per mAs (photons/mm2/mAs) for 50µm Rh were compared with other potential K-edge filters (Ag, In and Sn), all with K-absorption edge below that of Iodine. Two strategies were investigated: fixed kVp and filter thickness (50µm for all filters) resulting in HVT variation, and fixed kVp and HVT resulting in variation in Ag, In and Sn thickness. Monte Carlo simulations (GEANT4) were conducted to determine if the scatter-to-primary ratio (SPR) and the point spread function of scatter (scatter PSF) differed between Rh and other K-edge filters. Results: Ag, In and Sn filters (50µm thick) increased photon fluence/mAs by 1.3–1.4, 1.8–2, and 1.7–2 at 28-32 kVp compared to 50µm Rh, which could decrease exposure time. Additionally, the fraction of spectra closer to and just below Iodine’s K-edge increased with these filters, which could improve post-subtraction image contrast. For HVT matched to 50µm Rh filtered spectra, the thickness range for Ag, In, and Sn were (41,44)µm, (49,55)µm and (45,53)µm, and increased photon fluence/mAs by 1.5–1.7, 1.6–2, and 1.6–2.2, respectively. Monte Carlo simulations showed that neither the SPR nor the scatter PSF of Ag, In and Sn differed from Rh, indicating no additional detriment due to x-ray scatter. Conclusion: The use of Ag, In and Sn filters for low-energy image acquisition in CESM is potentially feasible and could decrease exposure time and may improve post-subtraction image contrast. Effect of these filters on radiation dose, contrast, noise and associated metrics are being investigated. Funding Support: Supported in

  6. Spectral Shifting in Nondestructive Assay Instrumentation

    Energy Technology Data Exchange (ETDEWEB)

    Trellue, Holly Renee [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Nettleton, Anthony Steven [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Tutt, James Robert [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Menlove, Howard Olsen [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); LaFleur, Adrienne Marie [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Tobin, Stephen Joseph [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2016-11-17

    This project involves spectrum tailoring research that endeavors to better distinguish energies of gamma rays using different spectral material thicknesses and determine neutron energies by coating detectors with various materials.

  7. FT-IR spectroscopy of lipoproteins—A comparative study

    Science.gov (United States)

    Krilov, Dubravka; Balarin, Maja; Kosović, Marin; Gamulin, Ozren; Brnjas-Kraljević, Jasminka

    2009-08-01

    FT-IR spectra, in the frequency region 4000-600 cm -1, of four major lipoprotein classes: very low density lipoprotein (VLDL), low density lipoprotein (LDL) and two subclasses of high density lipoproteins (HDL 2 and HDL 3) were analyzed to obtain their detailed spectral characterization. Information about the protein domain of particle was obtained from the analysis of amide I band. The procedure of decomposition and curve fitting of this band confirms the data already known about the secondary structure of two different apolipoproteins: apo A-I in HDL 2 and HDL 3 and apo B-100 in LDL and VLDL. For information about the lipid composition and packing of the particular lipoprotein the well expressed lipid bands in the spectra were analyzed. Characterization of spectral details in the FT-IR spectrum of natural lipoprotein is necessary to study the influence of external compounds on its structure.

  8. The effect of polyhedral oligomeric silsesquioxane dispersant and low surface energy additives on spectrally selective paint coatings with self-cleaning properties

    Energy Technology Data Exchange (ETDEWEB)

    Jerman, Ivan; Kozelj, Matjaz; Orel, Boris [National Institute of Chemistry, Hajdrihova 19, SI-1000 Ljubljana (Slovenia)

    2010-02-15

    Thickness-Insensitive Spectrally Selective (TISS) paint coatings were made of fluoropolymer resin binder (Lumiflon (LF), Asahi Glass Co., Ltd., Japan) and their water- and oil-repellent properties were obtained (contact angle: {theta}{sub water}{proportional_to}150 , {theta}{sub n-hexadecane}{proportional_to}55 ) by the addition of Polyhedral Oligomeric Silsesquioxane (POSS) characterized by amino (AP), isooctyl (IO) and perfluoro (PF) groups (i.e. AP{sub 2}IO{sub 4}PF{sub 2}) attached on the silsesquioxane cube (-SiO{sub 3/2}){sub 8}. Paint dispersions were made by modifying of black spinel pigment with trisilanol isobutyl (IB{sub 7}T{sub 7}(OH){sub 3}) POSS dispersant and with a single-capped silane isobutyltrimethoxysilane (IBTMS). Infrared and {sup 29}Si NMR spectra measurements were used for the identification of the structural characteristic of the corresponding POSS compounds. Surface free energy values of the pure cross-linked (no pigment added) LF binder which was determined from the measured contact angles for water, diiodomethane and formamide revealed the {gamma}{sup tot} value of the LF unpigmented resin with added AP{sub 2}IO{sub 4}PF{sub 2} T{sub 8} POSS was about 16.4 mN/m, which led to the {theta}{sub water}{proportional_to}110 , indicating enhancement of the hydrophobicity of the pure LF resin binder ({theta}{sub water}{proportional_to}89 ). SEM micrographs, which were used for the assessment of the TISS paint coating surface morphology confirmed the beneficial dispersive effect of IB{sub 7} T{sub 7}(OH){sub 3} dispersant as compared to the IBTMS silane. The presence of large Aluminium flake pigment and finely ground black pigment led to the formation of TISS paint coating surface, which exhibited bi-hierarchical roughness, resulting in water sliding angles of less than 10 , indicating the possible self-cleaning effect ({theta}{sub water}>150 and {theta}{sub n-hexadecane}{proportional_to}55 ). The use of POSS dispersant and POSS low surface energy

  9. Quantum mechanical study and spectroscopic (FT-IR, FT-Raman, UV-Visible) study, potential energy surface scan, Fukui function analysis and HOMO-LUMO analysis of 3-tert-butyl-4-methoxyphenol by DFT methods.

    Science.gov (United States)

    Saravanan, S; Balachandran, V

    2014-09-15

    This study represents an integral approach towards understanding the electronic and structural aspects of 3-tert-butyl-4-methoxyphenol (TBMP). Fourier-transform Infrared (FT-IR) and Fourier-transform Raman (FT-Raman) spectra of TBMP was recorded in the region 4000-400 cm(-1) and 3500-100 cm(-1), respectively. The molecular structures, vibrational wavenumbers, infrared intensities and Raman activities were calculated using DFT (B3LYP and LSDA) methods using 6-311++G (d,p) basis set. The most stable conformer of TBMP was identified from the computational results. The assignments of vibrational spectra have been carried out with the help of normal co-ordinate analysis (NCA) following the scaled quantum mechanical force field (SQMFF) methodology. The first order hyperpolarizability (β0) and related properties (β, α0 and Δα) of TBMP have been discussed. The stability and charge delocalization of the molecule was studied by Natural Bond Orbital (NBO) analysis. UV-Visible spectrum and effects of solvents have been discussed and the electronic properties such as HOMO and LUMO energies were determined by time-dependent TD-DFT approach with B3LYP/6-311++G (d,p) level of theory. The molecule orbital contributions are studied by density of energy states (DOSs). The reactivity sites are identified by mapping the electron density into electrostatic potential surface (MEP). Mulliken analysis of atomic charges is also calculated. The thermodynamic properties at different temperatures were calculated, revealing the correlations between standard heat capacities, standard entropy and standard enthalpy changes with temperatures. Global hardness, global softness, global electrophilicity and ionization potential of the title compound are determined. Copyright © 2014 Elsevier B.V. All rights reserved.

  10. Lyα-EMITTING GALAXIES AT z = 2.1: STELLAR MASSES, DUST, AND STAR FORMATION HISTORIES FROM SPECTRAL ENERGY DISTRIBUTION FITTING

    International Nuclear Information System (INIS)

    Guaita, Lucia; Padilla, Nelson; Acquaviva, Viviana; Gawiser, Eric; Bond, Nicholas A.; Kurczynski, Peter; Ciardullo, Robin; Gronwall, Caryl; Treister, Ezequiel; Lira, Paulina; Schawinski, Kevin

    2011-01-01

    We study the physical properties of 216 z ≅ 2.1 Lyα-emitting galaxies (LAEs) discovered in an ultra-deep narrow- MUSYC image of the ECDF-S. We fit their stacked spectral energy distribution (SED) using Charlot and Bruzual templates. We consider star formation histories (SFHs) parameterized by the e-folding time parameter τ, allowing for exponentially decreasing (τ > 0), exponentially increasing (τ * /M sun ) = 8.6[8.4-9.1], E(B - V) = 0.22[0.00-0.31], τ = -0.02[(- 4)-18] Gyr, and age SF = 0.018[0.009-3] Gyr. Thus, we obtain robust measurements of low stellar mass and dust content, but we cannot place meaningful constraints on the age or SFH of the LAEs. We also calculate the instantaneous SFR to be 35[0.003-170] M sun yr -1 , with its average over the last 100 Myr before observation giving (SFR) 100 = 4[2-30] M sun yr -1 . When we compare the results for the same SFH, typical LAEs at z ≅ 2.1 appear dustier and show higher instantaneous SFRs than z ≅ 3.1 LAEs, while the observed stellar masses of the two samples seem consistent. Because the majority are low-mass galaxies, our typical LAEs appear to occupy the low-mass end of the distribution of star-forming galaxies at z ∼ 2. We perform SED fitting on several sub-samples selected based on photometric properties and find that LAE sub-samples at z ≅ 2.1 exhibit heterogeneous properties. The typical IRAC-bright, UV-bright, and red LAEs have the largest stellar mass and dust reddening. The typical UV-faint, IRAC-faint, and high EW LAE sub-samples appear less massive ( 9 M sun ) and less dusty, with E(B - V) consistent with zero.

  11. A jet-dominated model for a broad-band spectral energy distribution of the nearby low-luminosity active galactic nucleus in M94

    Science.gov (United States)

    van Oers, Pieter; Markoff, Sera; Uttley, Phil; McHardy, Ian; van der Laan, Tessel; Donovan Meyer, Jennifer; Connors, Riley

    2017-06-01

    We have compiled a new multiwavelength spectral energy distribution (SED) for the closest obscured low-ionization emission-line region active galactic nucleus (AGN), NGC 4736, also known as M94. The SED comprises mainly high-resolution (mostly sub-arcsecond, or, at the distance to M94, ≲23 pc from the nucleus) observations from the literature, archival data, as well as previously unpublished sub-millimetre data from the Plateau de Bure Interferometer (PdBI) and the Combined Array for Research in Millimeter-wave Astronomy, in conjunction with new electronic MultiElement Radio Interferometric Network (e-MERLIN) L-band (1.5 GHz) observations. Thanks to the e-MERLIN resolution and sensitivity, we resolve for the first time a double structure composed of two radio sources separated by ˜1 arcsec, previously observed only at higher frequency. We explore this data set, which further includes non-simultaneous data from the Very Large Array, the Gemini telescope, the Hubble Space Telescope and the Chandra X-ray observatory, in terms of an outflow-dominated model. We compare our results with previous trends found for other AGN using the same model (NGC 4051, M81*, M87 and Sgr A*), as well as hard- and quiescent-state X-ray binaries. We find that the nuclear broad-band spectrum of M94 is consistent with a relativistic outflow of low inclination. The findings in this work add to the growing body of evidence that the physics of weakly accreting black holes scales with mass in a rather straightforward fashion.

  12. Salinity and spectral reflectance of soils

    Science.gov (United States)

    Szilagyi, A.; Baumgardner, M. F.

    1991-01-01

    The basic spectral response related to the salt content of soils in the visible and reflective IR wavelengths is analyzed in order to explore remote sensing applications for monitoring processes of the earth system. The bidirectional reflectance factor (BRF) was determined at 10 nm of increments over the 520-2320-nm spectral range. The effect of salts on reflectance was analyzed on the basis of 162 spectral measurements. MSS and TM bands were simulated within the measured spectral region. A strong relationship was found in variations of reflectance and soil characteristics pertaining to salinization and desalinization. Although the individual MSS bands had high R-squared values and 75-79 percent of soil/treatment combinations were separable, there was a large number of soil/treatment combinations not distinguished by any of the four highly correlated MSS bands under consideration.

  13. SH2-B promotes insulin receptor substrate 1 (IRS1)- and IRS2-mediated activation of the phosphatidylinositol 3-kinase pathway in response to leptin.

    Science.gov (United States)

    Duan, Chaojun; Li, Minghua; Rui, Liangyou

    2004-10-15

    Leptin regulates energy homeostasis primarily by binding and activating its long form receptor (LRb). Deficiency of either leptin or LRb causes morbid obesity. Leptin stimulates LRb-associated JAK2, thus initiating multiple pathways including the Stat3 and phosphatidylinositol (PI) 3-kinase pathways that mediate leptin biological actions. Here we report that SH2-B, a JAK2-interacting protein, promotes activation of the PI 3-kinase pathway by recruiting insulin receptor substrate 1 (IRS1) and IRS2 in response to leptin. SH2-B directly bound, via its PH and SH2 domain, to both IRS1 and IRS2 both in vitro and in intact cells and mediated formation of a JAK2/SH2-B/IRS1 or IRS2 tertiary complex. Consequently, SH2-B dramatically enhanced leptin-stimulated tyrosine phosphorylation of IRS1 and IRS2 in HEK293 cells stably expressing LRb, thus promoting association of IRS1 and IRS2 with the p85 regulatory subunit of PI 3-kinase and phosphorylation and activation of Akt. SH2-B mutants with lower affinity for IRS1 and IRS2 exhibited reduced ability to promote association of JAK2 with IRS1, tyrosine phosphorylation of IRS1, and association of IRS1 with p85 in response to leptin. Moreover, deletion of the SH2-B gene impaired leptin-stimulated tyrosine phosphorylation of endogenous IRS1 in mouse embryonic fibroblasts (MEF), which was reversed by reintroduction of SH2-B. Similarly, SH2-B promoted growth hormone-stimulated tyrosine phosphorylation of IRS1 in both HEK293 and MEF cells. Our data suggest that SH2-B is a novel mediator of the PI 3-kinase pathway in response to leptin or other hormones and cytokines that activate JAK2.

  14. Spectral Imaging by Upconversion

    DEFF Research Database (Denmark)

    Dam, Jeppe Seidelin; Pedersen, Christian; Tidemand-Lichtenberg, Peter

    2011-01-01

    We present a method to obtain spectrally resolved images using upconversion. By this method an image is spectrally shifted from one spectral region to another wavelength. Since the process is spectrally sensitive it allows for a tailored spectral response. We believe this will allow standard...... silicon based cameras designed for visible/near infrared radiation to be used for spectral images in the mid infrared. This can lead to much lower costs for such imaging devices, and a better performance....

  15. IR technology for enhanced force protection by AIM

    Science.gov (United States)

    Breiter, R.; Ihle, T.; Rode, W.; Wendler, J.; Rühlich, I.; Haiml, M.; Ziegler, J.

    2008-04-01

    In all recent missions our forces are faced with various types of asymmetric threads like snipers, IEDs, RPGs or MANPADS. 2 nd and 3 rd Gen IR technology is a backbone of modern force protection by providing situational awareness and accurate target engagement at day/night. 3 rd Gen sensors are developed for thread warning capabilities by use of spectral or spatial information. The progress on a dual-color IR module is discussed in a separate paper [1]. A 1024x256 SWIR array with flexure bearing compressor and pulse tube cold finger provides > 50,000h lifetime for space or airborne hyperspectral imaging in pushbroom geometry with 256 spectral channels for improved change detection and remote sensing of IEDs or chemical agents. Similar concepts are pursued in the LWIR with either spectroscopic imaging or a system of LWIR FPA combined with a cooled tunable Laser to do spectroscopy with stimulated absorption of specific wavelengths. AIM introduced the RangIR sight to match the requirements of sniper teams, AGLs and weapon stations, extending the outstanding optronic performance of the fielded HuntIR with position data of a target by a laser range finder (LRF), a 3 axis digital magnetic compass (DMC) and a ballistic computer for accurate engagement of remote targets. A version with flexure bearing cooler with >30,000h life time is being developed for continuous operation in e.g. gunfire detection systems. This paper gives an overview of AIM's technologies for enhanced force protection.

  16. Spectrally-engineered solar thermal photovoltaic devices

    Science.gov (United States)

    Lenert, Andrej; Bierman, David; Chan, Walker; Celanovic, Ivan; Soljacic, Marin; Wang, Evelyn N.; Nam, Young Suk; McEnaney, Kenneth; Kraemer, Daniel; Chen, Gang

    2018-03-27

    A solar thermal photovoltaic device, and method of forming same, includes a solar absorber and a spectrally selective emitter formed on either side of a thermally conductive substrate. The solar absorber is configured to absorb incident solar radiation. The solar absorber and the spectrally selective emitter are configured with an optimized emitter-to-absorber area ratio. The solar thermal photovoltaic device also includes a photovoltaic cell in thermal communication with the spectrally selective emitter. The spectrally selective emitter is configured to permit high emittance for energies above a bandgap of the photovoltaic cell and configured to permit low emittance for energies below the bandgap.

  17. [Spectral characteristics of decomposition of incorporated straw in compound polluted arid loess].

    Science.gov (United States)

    Fan, Chun-Hui; Zhang, Ying-Chao; Xu, Ji-Ting; Wang, Jia-Hong

    2014-04-01

    The original loess from western China was used as soil sample, the spectral methods of scanning electron microscope-energy dispersive X-ray spectroscopy (SEM-EDS), elemental analysis, Fourier transform infrared spectroscopy (FT-IR) and 13C nuclear magnetic resonance (13C NMR) were used to investigate the characteristics of decomposed straw and formed humic acids in compound polluted arid loess. The SEM micrographs show the variation from dense to decomposed surface, and finally to damaged structure, and the EDS data reveal the phenomenon of element transfer. The newly-formed humic acids are of low aromaticity, helpful for increasing the activity of organic matters in loess. The FTIR spectra in the whole process are similar, indicating the complexity of transformation dynamics of humic acids. The molecular structure of humic acids becomes simpler, shown from 13C NMR spectra. The spectral methods are useful for humic acids identification in loess region in straw incorporation process.

  18. Investigation of spectral characteristics of tunnel photodiodes based on DLC nanofilms

    Science.gov (United States)

    Akchurin, Garif G.; Aban'shin, Nickolay P.; Avetisyan, Yuri A.; Akchurin, Georgy G.; Kochubey, Vyacheslav I.; Yakunin, Alexander N.

    2018-04-01

    The tunneling photo effect has been studied in a microdiode with an electrostatic field localized at an emitter based on a nanosized DLC structure. It is established the photocurrent, when the carbon nanoemitter is exposed by laser and tunable low-coherent radiation in the spectral range from UV to near IR with photons of low energy (below work function). A linear dependence of the photocurrent on the level of optical power in the range of micro- and milliwatt power is established. The effect of saturation of the current-voltage characteristics of the tunnel photocurrent associated with a finite concentration of non-equilibrium photoelectrons is observed. The observed spectral Watt-Amper characteristics can be adequately interpreted using a modified Fowler-Nordheim equation for non-equilibrium photoelectrons.

  19. Spectral Decomposition Algorithm (SDA)

    Data.gov (United States)

    National Aeronautics and Space Administration — Spectral Decomposition Algorithm (SDA) is an unsupervised feature extraction technique similar to PCA that was developed to better distinguish spectral features in...

  20. Spatially resolved star formation and dust attenuation in Mrk 848: Comparison of the integral field spectra and the UV-to-IR SED

    Science.gov (United States)

    Yuan, Fang-Ting; Argudo-Fernández, María; Shen, Shiyin; Hao, Lei; Jiang, Chunyan; Yin, Jun; Boquien, Médéric; Lin, Lihwai

    2018-05-01

    We investigate the star formation history and the dust attenuation in the galaxy merger Mrk 848. Thanks to the multiwavelength photometry from the ultraviolet (UV) to the infrared (IR), and MaNGA's integral field spectroscopy, we are able to study this merger in a detailed way. We divide the whole merger into the core and tail regions, and fit both the optical spectrum and the multi-band spectral energy distribution (SED) to models to obtain the star formation properties for each region respectively. We find that the color excess of stars in the galaxy E(B-V)sSED measured with the multi-band SED fitting is consistent with that estimated both from the infrared excess (the ratio of IR to UV flux) and from the slope of the UV continuum. Furthermore, the reliability of the E(B-V)sSED is examined with a set of mock SEDs, showing that the dust attenuation of the stars can be well constrained by the UV-to-IR broadband SED fitting. The dust attenuation obtained from optical continuum E(B-V)sspec is only about half of E(B-V)sSED. The ratio of the E(B-V)sspec to the E(B-V)g obtained from the Balmer decrement is consistent with the local value (around 0.5). The difference between the results from the UV-to-IR data and the optical data is consistent with the picture that younger stellar populations are attenuated by an extra dust component from the birth clouds compared to older stellar populations which are only attenuated by the diffuse dust. Both with the UV-to-IR SED fitting and the spectral fitting, we find that there is a starburst younger than 100 Myr in one of the two core regions, consistent with the scenario that the interaction-induced gas inflow can enhance the star formation in the center of galaxies.

  1. Low loss mid-IR transmission bands using silica hollow-core anisotropic anti-resonant fibers

    DEFF Research Database (Denmark)

    Habib, Selim; Bang, Ole; Bache, Morten

    2016-01-01

    In this paper, a node-free anisotropic hollow-core anti-resonant fiber has been proposed to give low transmission loss in the near-IR to mid-IR spectral regime. The proposed silica-based fiber design shows transmission loss below 10 dB/km at 2.94 μm with multiple low loss transmission bands. Tran...

  2. Spectral and thermal investigation of tetrabenzoylacetonatobenzoylacetonediuranyl

    International Nuclear Information System (INIS)

    Kostyuk, N.N.; Dik, T.A.; Klavsut', G.N.; Umrejko, D.S.

    1989-01-01

    Uranium(6) compound with benzoylacetone (NBA) of [(UO 2 ) 2 (NBA)(BA) 4 ] composition was prepared by the method of electrochemical synthesis in oxidizing medium. Spectral and thermal investigation (data of IR, Raman spectra, TG, DTA) was conducted to show that four NBA molecules entered the compound as acidoligands and one NBA molecule (being a bridge) - as neutral ligand in keto-form. Mechanism of thermal decomposition was suggested and kinetic parameters of thermolysis of examined substance were calculated

  3. Limiting absorption principle at low energies for a mathematical model of weak interaction: the decay of a boson; Proprietes spectrales et principe d'absorption limite a faible energie pour un modele mathematique d'interaction faible: la desintegration d'un boson

    Energy Technology Data Exchange (ETDEWEB)

    Barbarouxa, J.M. [Centre de Physique Theorique, 13 - Marseille (France); Toulon-Var Univ. du Sud, Dept. de Mathematiques, 83 - La Garde (France); Guillot, J.C. [Centre de Mathematiques Appliquees, UMR 7641, Ecole Polytechnique - CNRS, 91 - Palaiseau (France)

    2009-09-15

    We study the spectral properties of a Hamiltonian describing the weak decay of spin 1 massive bosons into the full family of leptons. We prove that the considered Hamiltonian is self-adjoint, with a unique ground state and we derive a Mourre estimate and a limiting absorption principle above the ground state energy and below the first threshold, for a sufficiently small coupling constant. As a corollary, we prove absence of eigenvalues and absolute continuity of the energy spectrum in the same spectral interval. (authors)

  4. Infrared (IR) photon-sensitive spectromicroscopy in a cryogenic environment

    Science.gov (United States)

    Pereverzev, Sergey

    2016-06-14

    A system designed to suppress thermal radiation background and to allow IR single-photon sensitive spectromicroscopy of small samples by using both absorption, reflection, and emission/luminescence measurements. The system in one embodiment includes: a light source; a plurality of cold mirrors configured to direct light along a beam path; a cold or warm sample holder in the beam path; windows of sample holder (or whole sample holder) are transparent in a spectral region of interest, so they do not emit thermal radiation in the same spectral region of interest; a cold monochromator or other cold spectral device configured to direct a selected fraction of light onto a cold detector; a system of cold apertures and shields positioned along the beam path to prevent unwanted thermal radiation from arriving at the cold monochromator and/or the detector; a plurality of optical, IR and microwave filters positioned along the beam path and configured to adjust a spectral composition of light incident upon the sample under investigation and/or on the detector; a refrigerator configured to maintain the detector at a temperature below 1.0K; and an enclosure configured to: thermally insulate the light source, the plurality of mirrors, the sample holder, the cold monochromator and the refrigerator.

  5. Dual-Energy Contrast-Enhanced Spectral Mammography: Enhancement Analysis on BI-RADS 4 Non-Mass Microcalcifications in Screened Women.

    Directory of Open Access Journals (Sweden)

    Yun-Chung Cheung

    Full Text Available Mammography screening is a cost-efficient modality with high sensitivity for detecting impalpable cancer with microcalcifications, and results in reduced mortality rates. However, the probability of finding microcalcifications without associated cancerous masses varies. We retrospectively evaluated the diagnosis and cancer probability of the non-mass screened microcalcifications by dual-energy contrast-enhanced spectral mammography (DE-CESM.With ethical approval from our hospital, we enrolled the cases of DE-CESM for analysis under the following inclusion criteria: (1 referrals due to screened BI-RADS 4 microcalcifications; (2 having DE-CESM prior to stereotactic biopsy; (3 no associated mass found by sonography and physical examination; and (4 pathology-based diagnosis using stereotactic vacuum-assisted breast biopsy. We analyzed the added value of post-contrast enhancement on DE-CESM.A total of 94 biopsed lesions were available for analysis in our 87 women, yielding 27 cancers [19 ductal carcinoma in situ (DCIS, and 8 invasive ductal carcinoma (IDC], 32 pre-malignant and 35 benign lesions. Of these 94 lesions, 33 showed associated enhancement in DE-CESM while the other 61 did not. All 8 IDC (100% and 16 of 19 DCIS (84.21% showed enhancement, but the other 3 DCIS (15.79% did not. Overall sensitivity, specificity, positive predictive value, negative predictive value and accuracy were 88.89%, 86.56%, 72.72%, 95.08% and 87.24%, respectively. The performances of DE-CESM on both amorphous and pleomorphic microcalcifications were satisfactory (AUC 0.8 and 0.92, respectively. The pleomorphous microcalcifications with enhancement showed higher positive predictive value (90.00% vs 46.15%, p = 0.013 and higher cancer probability than the amorphous microcalcifications (46.3% VS 15.1%. The Odds Ratio was 4.85 (95% CI: 1.84-12.82.DE-CESM might provide added value in assessing the non-mass screened breast microcalcification, with enhancement favorable to the

  6. Dual-Energy Contrast-Enhanced Spectral Mammography: Enhancement Analysis on BI-RADS 4 Non-Mass Microcalcifications in Screened Women.

    Science.gov (United States)

    Cheung, Yun-Chung; Juan, Yu-Hsiang; Lin, Yu-Ching; Lo, Yung-Feng; Tsai, Hsiu-Pei; Ueng, Shir-Hwa; Chen, Shin-Cheh

    2016-01-01

    Mammography screening is a cost-efficient modality with high sensitivity for detecting impalpable cancer with microcalcifications, and results in reduced mortality rates. However, the probability of finding microcalcifications without associated cancerous masses varies. We retrospectively evaluated the diagnosis and cancer probability of the non-mass screened microcalcifications by dual-energy contrast-enhanced spectral mammography (DE-CESM). With ethical approval from our hospital, we enrolled the cases of DE-CESM for analysis under the following inclusion criteria: (1) referrals due to screened BI-RADS 4 microcalcifications; (2) having DE-CESM prior to stereotactic biopsy; (3) no associated mass found by sonography and physical examination; and (4) pathology-based diagnosis using stereotactic vacuum-assisted breast biopsy. We analyzed the added value of post-contrast enhancement on DE-CESM. A total of 94 biopsed lesions were available for analysis in our 87 women, yielding 27 cancers [19 ductal carcinoma in situ (DCIS), and 8 invasive ductal carcinoma (IDC)], 32 pre-malignant and 35 benign lesions. Of these 94 lesions, 33 showed associated enhancement in DE-CESM while the other 61 did not. All 8 IDC (100%) and 16 of 19 DCIS (84.21%) showed enhancement, but the other 3 DCIS (15.79%) did not. Overall sensitivity, specificity, positive predictive value, negative predictive value and accuracy were 88.89%, 86.56%, 72.72%, 95.08% and 87.24%, respectively. The performances of DE-CESM on both amorphous and pleomorphic microcalcifications were satisfactory (AUC 0.8 and 0.92, respectively). The pleomorphous microcalcifications with enhancement showed higher positive predictive value (90.00% vs 46.15%, p = 0.013) and higher cancer probability than the amorphous microcalcifications (46.3% VS 15.1%). The Odds Ratio was 4.85 (95% CI: 1.84-12.82). DE-CESM might provide added value in assessing the non-mass screened breast microcalcification, with enhancement favorable to the

  7. SPECTRAL ENERGY DISTRIBUTIONS OF YOUNG STARS IN IC 348: THE ROLE OF DISKS IN ANGULAR MOMENTUM EVOLUTION OF YOUNG, LOW-MASS STARS

    International Nuclear Information System (INIS)

    Le Blanc, Thompson S.; Stassun, Keivan G.; Covey, Kevin R.

    2011-01-01

    Theoretical work suggests that a young star's angular momentum content and rotation rate may be strongly influenced by magnetic interactions with its circumstellar disk. A generic prediction of these 'disk-locking' theories is that a disk-locked star will be forced to co-rotate with the Keplerian angular velocity of the inner edge of the disk; that is, the disk's inner-truncation radius should equal its co-rotation radius. These theories have also been interpreted to suggest a gross correlation between young stars' rotation periods and the structural properties of their circumstellar disks, such that slowly rotating stars possess close-in disks that enforce the star's slow rotation, whereas rapidly rotating stars possess anemic or evacuated inner disks that are unable to brake the stars and instead the stars spin up as they contract. To test these expectations, we model the spectral energy distributions (SEDs) of 33 young stars in IC 348 with known rotation periods and infrared excesses indicating the presence of circumstellar disks. For each star, we match the observed SED, typically sampling 0.6-8.0 μm, to a grid of 200,000 pre-computed star+disk radiative transfer models, from which we infer the disk's inner-truncation radius. We then compare this truncation radius to the disk's co-rotation radius, calculated from the star's measured rotation period. We do not find obvious differences in the disk truncation radii of slow rotators versus rapid rotators. This holds true both at the level of whether close-in disk material is present at all, and in analyzing the precise location of the inner disk edge relative to the co-rotation radius among the subset of stars with close-in disk material. One interpretation is that disk locking is unimportant for the IC 348 stars in our sample. Alternatively, if disk locking does operate, then it must operate on both the slow and rapid rotators, potentially producing both spin-up and spin-down torques, and the transition from the

  8. CCD and IR array controllers

    Science.gov (United States)

    Leach, Robert W.; Low, Frank J.

    2000-08-01

    A family of controllers has bene developed that is powerful and flexible enough to operate a wide range of CCD and IR focal plane arrays in a variety of ground-based applications. These include fast readout of small CCD and IR arrays for adaptive optics applications, slow readout of large CCD and IR mosaics, and single CCD and IR array operation at low background/low noise regimes as well as high background/high speed regimes. The CCD and IR controllers have a common digital core based on user- programmable digital signal processors that are used to generate the array clocking and signal processing signals customized for each application. A fiber optic link passes image data and commands to VME or PCI interface boards resident in a host computer to the controller. CCD signal processing is done with a dual slope integrator operating at speeds of up to one Megapixel per second per channel. Signal processing of IR arrays is done either with a dual channel video processor or a four channel video processor that has built-in image memory and a coadder to 32-bit precision for operating high background arrays. Recent developments underway include the implementation of a fast fiber optic data link operating at a speed of 12.5 Megapixels per second for fast image transfer from the controller to the host computer, and supporting image acquisition software and device drivers for the PCI interface board for the Sun Solaris, Linux and Windows 2000 operating systems.

  9. Manual for IRS Coding. Joint IAEA/NEA International Reporting System for Operating Experience

    International Nuclear Information System (INIS)

    2011-01-01

    The International Reporting System for Operating Experience (IRS) is jointly operated by the International Atomic Energy Agency (IAEA) and the Nuclear Energy Agency of the Organisation for Economic Co-operation and Development (OECD/NEA). In early 2010, the IAEA and OECD/NEA jointly issued the IRS Guidelines, which described the reporting system and process and gave users the necessary elements to enable them to produce IRS reports to a high standard of quality while retaining the effectiveness of the system expected by all Member States operating nuclear power plants. The purpose of the present Manual for IRS Coding is to provide supplementary guidance specifically on the coding element of IRS reports to ensure uniform coding of events that are reported through IRS. This Coding Manual does not supersede the IRS Guidelines, but rather, supports users and preparers in achieving a consistent and high level of quality in their IRS reports. Consistency and high quality in the IRS reports allow stakeholders to search and retrieve specific event information with ease. In addition, well-structured reports also enhance the efficient management of the IRS database. This Coding Manual will give specific guidance on the application of each section of the IRS codes, with examples where necessary, of when and how these codes are to be applied. As this reporting system is owned by the Member States, this manual has been developed and approved by the IRS National Coordinators with the assistance of the IAEA and NEA secretariats

  10. A broadband beam-steered fiber mm-wave link with high energy-spectral-spatial efficiency for 5G coverage

    NARCIS (Netherlands)

    Cao, Z.; Zhao, X.; Jiao, Y.; Deng, X.; Tessema, N.; Raz, O.; Koonen, A.M.J.

    2017-01-01

    Utilizing an integrated optical-tunable-delay-line, reversely-modulated single sideband modulation, and Nyquist subcarrier modulation, we demonstrate an 8 Gbps mm-wave beam steered link with a spatial-spectral efficiency of 16 bits/s/Hz.

  11. A spectral study of the elementary step of proton transfer in heterogeneous acid catalysis

    Energy Technology Data Exchange (ETDEWEB)

    Kazanskii, V B

    1977-09-01

    A spectral study of the elementary step of proton transfer in heterogeneous acid catalysis involved a determination of the potential curves of the OH bond in surface hydroxyl groups (e.g., those on silica, NaHY zeolite, or glass) of differing acidity from IR stretching frequency data in the overtone region; a calculation of the activation energies for proton transfer during acid catalysis from the changes in the curve forms after adsorption of various molecules (e.g., water, ammonia, benzene, toluene, xylenes, acetone, and cyclohexane); and a comparison of the IR predictions with quantum-chemical calculations of the potential curves. The results appear to furnish a new criterion for the coordinate of reactions involving Broensted sites: if the activation energy measured during actual catalysis is close to that calculated from the IR stretching data, the reaction proceeds by the stepwise mechanism of acid catalysis; but if these values differ greatly, the reaction involves a concerted mechanism (i.e., activation of the adsorbed molecule without involvement of OH groups). Tables, graphs, and 15 references.

  12. Density functional study of the L10-αIrV transition in IrV and RhV

    International Nuclear Information System (INIS)

    Mehl, Michael J.; Hart, Gus L.W.; Curtarolo, Stefano

    2011-01-01

    Research highlights: → The computational determination of the ground state of a material can be a difficult task, particularly if the ground state is uncommon and so not found in usual databases. In this paper we consider the alpha-IrV structure, a low temperature structure found only in two compounds, IrV and RhV. In both cases this structure can be considered as a distorted tetragonal structure, and the tetragonal 'L1 0 ' structure is the high temperature structure for both compounds. We show, however, that the logical path for the transition from the L1 0 to the alpha-IrV structure is energetically forbidden, and find a series of unstable and metastable structures which have a lower energy than the L1 0 phase, but are higher in energy than the alpha-IrV phase. We also consider the possibility of the alpha-IrV structure appearing in neighboring compounds. We find that both IrTi and RhTi are candidates. - Abstract: Both IrV and RhV crystallize in the αIrV structure, with a transition to the higher symmetry L1 0 structure at high temperature, or with the addition of excess Ir or Rh. Here we present evidence that this transition is driven by the lowering of the electronic density of states at the Fermi level of the αIrV structure. The transition has long been thought to be second order, with a simple doubling of the L1 0 unit cell due to an unstable phonon at the R point (0 1/2 1/2). We use first-principles calculations to show that all phonons at the R point are, in fact, stable, but do find a region of reciprocal space where the L1 0 structure has unstable (imaginary frequency) phonons. We use the frozen phonon method to examine two of these modes, relaxing the structures associated with the unstable phonon modes to obtain new structures which are lower in energy than L1 0 but still above αIrV. We examine the phonon spectra of these structures as well, looking for instabilities, and find further instabilities, and more relaxed structures, all of which have

  13. Large-format platinum silicide microwave kinetic inductance detectors for optical to near-IR astronomy.

    Science.gov (United States)

    Szypryt, P; Meeker, S R; Coiffard, G; Fruitwala, N; Bumble, B; Ulbricht, G; Walter, A B; Daal, M; Bockstiegel, C; Collura, G; Zobrist, N; Lipartito, I; Mazin, B A

    2017-10-16

    We have fabricated and characterized 10,000 and 20,440 pixel Microwave Kinetic Inductance Detector (MKID) arrays for the Dark-speckle Near-IR Energy-resolved Superconducting Spectrophotometer (DARKNESS) and the MKID Exoplanet Camera (MEC). These instruments are designed to sit behind adaptive optics systems with the goal of directly imaging exoplanets in a 800-1400 nm band. Previous large optical and near-IR MKID arrays were fabricated using substoichiometric titanium nitride (TiN) on a silicon substrate. These arrays, however, suffered from severe non-uniformities in the TiN critical temperature, causing resonances to shift away from their designed values and lowering usable detector yield. We have begun fabricating DARKNESS and MEC arrays using platinum silicide (PtSi) on sapphire instead of TiN. Not only do these arrays have much higher uniformity than the TiN arrays, resulting in higher pixel yields, they have demonstrated better spectral resolution than TiN MKIDs of similar design. PtSi MKIDs also do not display the hot pixel effects seen when illuminating TiN on silicon MKIDs with photons with wavelengths shorter than 1 µm.

  14. Total spectral distributions from Hawking radiation

    Energy Technology Data Exchange (ETDEWEB)

    Broda, Boguslaw [University of Lodz, Department of Theoretical Physics, Faculty of Physics and Applied Informatics, Lodz (Poland)

    2017-11-15

    Taking into account the time dependence of the Hawking temperature and finite evaporation time of the black hole, the total spectral distributions of the radiant energy and of the number of particles have been explicitly calculated and compared to their temporary (initial) blackbody counterparts (spectral exitances). (orig.)

  15. Using Fourier transform IR spectroscopy to analyze biological materials

    Science.gov (United States)

    Baker, Matthew J; Trevisan, Júlio; Bassan, Paul; Bhargava, Rohit; Butler, Holly J; Dorling, Konrad M; Fielden, Peter R; Fogarty, Simon W; Fullwood, Nigel J; Heys, Kelly A; Hughes, Caryn; Lasch, Peter; Martin-Hirsch, Pierre L; Obinaju, Blessing; Sockalingum, Ganesh D; Sulé-Suso, Josep; Strong, Rebecca J; Walsh, Michael J; Wood, Bayden R; Gardner, Peter; Martin, Francis L

    2015-01-01

    IR spectroscopy is an excellent method for biological analyses. It enables the nonperturbative, label-free extraction of biochemical information and images toward diagnosis and the assessment of cell functionality. Although not strictly microscopy in the conventional sense, it allows the construction of images of tissue or cell architecture by the passing of spectral data through a variety of computational algorithms. Because such images are constructed from fingerprint spectra, the notion is that they can be an objective reflection of the underlying health status of the analyzed sample. One of the major difficulties in the field has been determining a consensus on spectral pre-processing and data analysis. This manuscript brings together as coauthors some of the leaders in this field to allow the standardization of methods and procedures for adapting a multistage approach to a methodology that can be applied to a variety of cell biological questions or used within a clinical setting for disease screening or diagnosis. We describe a protocol for collecting IR spectra and images from biological samples (e.g., fixed cytology and tissue sections, live cells or biofluids) that assesses the instrumental options available, appropriate sample preparation, different sampling modes as well as important advances in spectral data acquisition. After acquisition, data processing consists of a sequence of steps including quality control, spectral pre-processing, feature extraction and classification of the supervised or unsupervised type. A typical experiment can be completed and analyzed within hours. Example results are presented on the use of IR spectra combined with multivariate data processing. PMID:24992094

  16. PEP-II IR-2 Alignment

    International Nuclear Information System (INIS)

    Seryi, A

    2004-01-01

    This paper describes the first results and preliminary analysis obtained with several alignment monitoring systems recently installed in the PEP-II interaction region. The hydrostatic level system, stretched wire system, and laser tracker have been installed in addition to the existing tiltmeters and LVDT sensors. These systems detected motion of the left raft, which correlated primarily with the low energy ring (LER) current. The motion is of the order of 120 micrometers. The cause was identified as synchrotron radiation heating the beampipe, causing its expansion which then results in its deformation and offset of the IR quadrupoles. We also discuss further plans on measurements, analysis and means to counteract this motion

  17. Ion beam synthesis of IrSi3 by implantation of 2 MeV Ir ions

    International Nuclear Information System (INIS)

    Sjoreen, T.P.; Chisholm, M.F.; Hinneberg, H.J.

    1992-11-01

    Formation of a buried IrSi 3 layer in (111) oriented Si by ion implantation and annealing has been studied at an implantation energy of 2 MeV for substrate temperatures of 450--550C. Rutherford backscattering (RBS), ion channeling and cross-sectional transmission electron microscopy showed that a buried epitaxial IrSi 3 layer is produced at 550C by implanting ≥ 3.4 x 10 17 Ir/cm 2 and subsequently annealing for 1 h at 1000C plus 5 h at 1100C. At a dose of 3.4 x 10 17 Ir/cm 2 , the thickness of the layer varied between 120 and 190 nm and many large IrSi 3 precipitates were present above and below the film. Increasing the dose to 4.4 x 10 17 Ir/cm 2 improved the layer uniformity at the expense of increased lattice damage in the overlying Si. RBS analysis of layer formation as a function of substrate temperature revealed the competition between the mechanisms for optimizing surface crystallinity vs. IrSi 3 layer formation. Little apparent substrate temperature dependence was evident in the as-implanted state but after annealing the crystallinity of the top Si layer was observed to deteriorate with increasing substrate temperature while the precipitate coarsening and coalescence improved

  18. The early phases of galaxy clusters formation in IR: coupling hydrodynamical simulations with GRASIL-3D

    Science.gov (United States)

    Granato, Gian Luigi; Ragone-Figueroa, Cinthia; Domínguez-Tenreiro, Rosa; Obreja, Aura; Borgani, Stefano; De Lucia, Gabriella; Murante, Giuseppe

    2015-06-01

    We compute and study the infrared and sub-mm properties of high-redshift (z ≳ 1) simulated clusters and protoclusters. The results of a large set of hydrodynamical zoom-in simulations including active galactic nuclei (AGN) feedback, have been treated with the recently developed radiative transfer code GRASIL-3D, which accounts for the effect of dust reprocessing in an arbitrary geometry. Here, we have slightly generalized the code to adapt it to the present purpose. Then we have post-processed boxes of physical size 2 Mpc encompassing each of the 24 most massive clusters identified at z = 0, at several redshifts between 0.5 and 3, producing IR and sub-mm mock images of these regions and spectral energy distributions (SEDs) of the radiation coming out from them. While this field is in its infancy from the observational point of view, rapid development is expected in the near future thanks to observations performed in the far-IR and sub-mm bands. Notably, we find that in this spectral regime our prediction are little affected by the assumption required by this post-processing, and the emission is mostly powered by star formation (SF) rather than accretion on to super massive black hole (SMBH). The comparison with the little observational information currently available, highlights that the simulated cluster regions never attain the impressive star formation rates suggested by these observations. This problem becomes more intriguing taking into account that the brightest cluster galaxies (BCGs) in the same simulations turn out to be too massive. It seems that the interplay between the feedback schemes and the star formation model should be revised, possibly incorporating a positive feedback mode.

  19. Lanthanide ions as absorption spectral probes in biochemical reactions

    International Nuclear Information System (INIS)

    Misra, S.N.

    1989-01-01

    The interactions of adenine, adenosine, adenosine 5'-monophosphate, 5'-diphosphate and 5'-triphosphate with Pr(III) and Nd(III) in different stoichiometries and at varying pH levels have been investigated by electronic spectral studies. The intra 4f-4f transitions yield sharp bands which were analysed individually by Gaussian curve analysis. The energy interaction (Fsup(k),Esup(k)) spin orbit interaction (ζ4f), bonding(b), nephelauxetic (β,δ) and intensity parameters (Tsub(τ.P)) have been computed on HP-1000/45 computer using regression analyses refined by least square fit. The nature of bonding, coordination environment, outer and inner sphere coordination have been interpreted in terms of the magnitude of these parameters as compared to the lanthanide free ion. In order to supplicate the solution studies the crystalline compounds of AMP, ADP and ATP with Pr(III) and Nd(III) have been isolated and characterized by IR, 1 H and 31 P NMR studies. The infrared spectral data indicated weak interaction with the imidazole nitrogen of adenine moiety and bidentate attachment of oxygen. (author). 10 refs

  20. Nonlinear spectral mixing theory to model multispectral signatures

    Energy Technology Data Exchange (ETDEWEB)

    Borel, C.C. [Los Alamos National Lab., NM (United States). Astrophysics and Radiation Measurements Group

    1996-02-01

    Nonlinear spectral mixing occurs due to multiple reflections and transmissions between discrete surfaces, e.g. leaves or facets of a rough surface. The radiosity method is an energy conserving computational method used in thermal engineering and it models nonlinear spectral mixing realistically and accurately. In contrast to the radiative transfer method the radiosity method takes into account the discreteness of the scattering surfaces (e.g. exact location, orientation and shape) such as leaves and includes mutual shading between them. An analytic radiosity-based scattering model for vegetation was developed and used to compute vegetation indices for various configurations. The leaf reflectance and transmittance was modeled using the PROSPECT model for various amounts of water, chlorophyll and variable leaf structure. The soil background was modeled using SOILSPEC with a linear mixture of reflectances of sand, clay and peat. A neural network and a geometry based retrieval scheme were used to retrieve leaf area index and chlorophyll concentration for dense canopies. Only simulated canopy reflectances in the 6 visible through short wave IR Landsat TM channels were used. The authors used an empirical function to compute the signal-to-noise ratio of a retrieved quantity.

  1. Spectral ellipsometry of nanodiamond composite

    International Nuclear Information System (INIS)

    Yastrebov, S.G.; Ivanov-Omskij, V.I.; Gordeev, S.K.; Garriga, M.; Alonso, I.A.

    2006-01-01

    Methods of spectral ellipsometry were applied for analysis of optical properties of nanodiamond based composite in spectral region 1.4-5 eV. The nanocomposite was synthesized by molding of ultradispersed nanodiamond powder in the course of heterogeneous chemical reaction of decomposition of methane, forming pyrocarbon interconnecting nanodiamond grains. The energy of σ + π plasmon of pyrocarbon component of nanodiamond composite was restored which proves to be ∼ 24 eV; using this value, an estimation was done of pyrocarbon matrix density, which occurs to be 2 g/cm 3 [ru

  2. Fluorescence, aggregation properties and FT-IR microspectroscopy of elastin and collagen fibers.

    Science.gov (United States)

    Vidal, Benedicto de Campos

    2014-10-01

    Histological and histochemical observations support the hypothesis that collagen fibers can link to elastic fibers. However, the resulting organization of elastin and collagen type complexes and differences between these materials in terms of macromolecular orientation and frequencies of their chemical vibrational groups have not yet been solved. This study aimed to investigate the macromolecular organization of pure elastin, collagen type I and elastin-collagen complexes using polarized light DIC-microscopy. Additionally, differences and similarities between pure elastin and collagen bundles (CB) were investigated by Fourier transform-infrared (FT-IR) microspectroscopy. Although elastin exhibited a faint birefringence, the elastin-collagen complex aggregates formed in solution exhibited a deep birefringence and formation of an ordered-supramolecular complex typical of collagen chiral structure. The FT-IR study revealed elastin and CB peptide NH groups involved in different types of H-bonding. More energy is absorbed in the vibrational transitions corresponding to CH, CH2 and CH3 groups (probably associated with the hydrophobicity demonstrated by 8-anilino-1-naphtalene sulfonic acid sodium salt [ANS] fluorescence), and to νCN, δNH and ωCH2 groups of elastin compared to CB. It is assumed that the α-helix contribution to the pure elastin amide I profile is 46.8%, whereas that of the B-sheet is 20% and that unordered structures contribute to the remaining percentage. An FT-IR profile library reveals that the elastin signature within the 1360-1189cm(-1) spectral range resembles that of Conex-Toray aramid fibers. Copyright © 2014 Elsevier GmbH. All rights reserved.

  3. Massive Young Stellar Objects in the Galactic Center. 1; Spectroscopic Identification from Spitzer/IRS Observations

    Science.gov (United States)

    An, Deokkeun; Ramirez, Solange V.; Sellgren, Kris; Arendt, Richard G.; Boogert, A. C. Adwin; Robitaille, Thomas P.; Schultheis, Mathias; Cotera, Angela S.; Smith, Howard A.; Stolovy, Susan R.

    2011-01-01

    We present results from our spectroscopic study, using the Infrared Spectrograph (IRS) onboard the Spitzer Space Telescope, designed to identify massive young stellar objects (YSOs) in the Galactic Center (GC). Our sample of 107 YSO candidates was selected based on IRAC colors from the high spatial resolution, high sensitivity Spitzer/IRAC images in the Central Molecular Zone (CMZ), which spans the central approximately 300 pc region of the Milky Way Galaxy. We obtained IRS spectra over 5 micron to 35 micron using both high- and low-resolution IRS modules. We spectroscopically identify massive YSOs by the presence of a 15.4 micron shoulder on the absorption profile of 15 micron CO2 ice, suggestive of CO2 ice mixed with CH30H ice on grains. This 15.4 micron shoulder is clearly observed in 16 sources and possibly observed in an additional 19 sources. We show that 9 massive YSOs also reveal molecular gas-phase absorption from C02, C2H2, and/or HCN, which traces warm and dense gas in YSOs. Our results provide the first spectroscopic census of the massive YSO population in the GC. We fit YSO models to the observed spectral energy distributions and find YSO masses of 8 - 23 solar Mass, which generally agree with the masses derived from observed radio continuum emission. We find that about 50% of photometrically identified YSOs are confirmed with our spectroscopic study. This implies a preliminary star formation rate of approximately 0.07 solar mass/yr at the GC.

  4. FT-IR Microspectroscopy of Rat Ear Cartilage.

    Directory of Open Access Journals (Sweden)

    Benedicto de Campos Vidal

    Full Text Available Rat ear cartilage was studied using Fourier transform-infrared (FT-IR microspectroscopy to expand the current knowledge which has been established for relatively more complex cartilage types. Comparison of the FT-IR spectra of the ear cartilage extracellular matrix (ECM with published data on articular cartilage, collagen II and 4-chondroitin-sulfate standards, as well as of collagen type I-containing dermal collagen bundles (CBs with collagen type II, was performed. Ear cartilage ECM glycosaminoglycans (GAGs were revealed histochemically and as a reduction in ECM FT-IR spectral band heights (1140-820 cm-1 after testicular hyaluronidase digestion. Although ear cartilage is less complex than articular cartilage, it contains ECM components with a macromolecular orientation as revealed using polarization microscopy. Collagen type II and GAGs, which play a structural role in the stereo-arrangement of the ear cartilage, contribute to its FT-IR spectrum. Similar to articular cartilage, ear cartilage showed that proteoglycans add a contribution to the collagen amide I spectral region, a finding that does not recommend this region for collagen type II quantification purposes. In contrast to articular cartilage, the symmetric stretching vibration of -SO3- groups at 1064 cm-1 appeared under-represented in the FT-IR spectral profile of ear cartilage. Because the band corresponding to the asymmetric stretching vibration of -SO3- groups (1236-1225 cm-1 overlapped with that of amide III bands, it is not recommended for evaluation of the -SO3- contribution to the FT-IR spectrum of the ear cartilage ECM. Instead, a peak (or shoulder at 1027-1016 cm-1 could be better considered for this intent. Amide I/amide II ratios as calculated here and data from the literature suggest that protein complexes of the ear cartilage ECM are arranged with a lower helical conformation compared to pure collagen II. The present results could motivate further studies on this tissue

  5. Study on seasonal IR signature change of a ship by considering seasonal marine environmental conditions

    Science.gov (United States)

    Kim, Do-Hwi; Han, Kuk-Il; Choi, Jun-Hyuk; Kim, Tae-Kuk

    2017-05-01

    Infrared (IR) signal emitted from objects over 0 degree Kelvin has been used to detect and recognize the characteristics of those objects. Recently more delicate IR sensors have been applied for various guided missiles and they affect a crucial influence on object's survivability. Especially, in marine environment it is more vulnerable to be attacked by IR guided missiles since there are nearly no objects for concealment. To increase the survivability of object, the IR signal of the object needs to be analyzed properly by considering various marine environments. IR signature of a naval ship consists of the emitted energy from ship surface and the reflected energy by external sources. Surface property such as the emissivity and the absorptivity on the naval ship varies with different paints applied on the surface and the reflected IR signal is also affected by the surface radiative property, the sensor's geometric position and various climatic conditions in marine environment. Since the direct measurement of IR signal using IR camera is costly and time consuming job, computer simulation methods are developing rapidly to replace those experimental tasks. In this study, we are demonstrate a way of analyzing the IR signal characteristics by using the measured background IR signals using an IR camera and the estimated target IR signals from the computer simulation to find the seasonal trends of IR threats of a naval ship. Through this process, measured weather data are used to analyze more accurate IR signal conditions for the naval ship. The seasonal change of IR signal contrast between the naval ship and the marine background shows that the highest contrast radiant intensity (CRI) value is appeared in early summer.

  6. A spectral nodal method for eigenvalue S{sub N} transport problems in two-dimensional rectangular geometry for energy multigroup nuclear reactor global calculations

    Energy Technology Data Exchange (ETDEWEB)

    Silva, Davi Jose M.; Alves Filho, Hermes; Barros, Ricardo C., E-mail: davijmsilva@yahoo.com.br, E-mail: halves@iprj.uerj.br, E-mail: rcbarros@pq.cnpq.br [Universidade do Estado do Rio de Janeiro (UERJ), Nova Friburgo, RJ (Brazil). Programa de Pos-Graduacao em Modelagem Computacional

    2015-07-01

    A spectral nodal method is developed for multigroup x,y-geometry discrete ordinates (S{sub N}) eigenvalue problems for nuclear reactor global calculations. This method uses the conventional multigroup SN discretized spatial balance nodal equations with two non-standard auxiliary equations: the spectral diamond (SD) auxiliary equations for the discretization nodes inside the fuel regions, and the spectral Green's function (SGF) auxiliary equations for the non-multiplying regions, such as the baffle and the reactor. This spectral nodal method is derived from the analytical general solution of the SN transverse integrated nodal equations with constant approximations for the transverse leakage terms within each discretization node. The SD and SGF auxiliary equations have parameters, which are determined to preserve the homogeneous and the particular components of these local general solutions. Therefore, we refer to the offered method as the hybrid SD-SGF-Constant Nodal (SD-SGF-CN) method. The S{sub N} discretized spatial balance equations, together with the SD and the SGF auxiliary equations form the SD-SGF-CN equations. We solve the SD-SGF-CN equations by using the one-node block inversion inner iterations (NBI), wherein the most recent estimates for the incoming group node-edge average or prescribed boundary conditions are used to evaluate the outgoing group node-edge average fluxes in the directions of the S{sub N} transport sweeps, for each estimate of the dominant eigenvalue in the conventional Power outer iterations. We show in numerical calculations that the SD-SGF-CN method is very accurate for coarse-mesh multigroup S{sub N} eigenvalue problems, even though the transverse leakage terms are approximated rather simply. (author)

  7. A spectral nodal method for eigenvalue SN transport problems in two-dimensional rectangular geometry for energy multigroup nuclear reactor global calculations

    International Nuclear Information System (INIS)

    Silva, Davi Jose M.; Alves Filho, Hermes; Barros, Ricardo C.

    2015-01-01

    A spectral nodal method is developed for multigroup x,y-geometry discrete ordinates (S N ) eigenvalue problems for nuclear reactor global calculations. This method uses the conventional multigroup SN discretized spatial balance nodal equations with two non-standard auxiliary equations: the spectral diamond (SD) auxiliary equations for the discretization nodes inside the fuel regions, and the spectral Green's function (SGF) auxiliary equations for the non-multiplying regions, such as the baffle and the reactor. This spectral nodal method is derived from the analytical general solution of the SN transverse integrated nodal equations with constant approximations for the transverse leakage terms within each discretization node. The SD and SGF auxiliary equations have parameters, which are determined to preserve the homogeneous and the particular components of these local general solutions. Therefore, we refer to the offered method as the hybrid SD-SGF-Constant Nodal (SD-SGF-CN) method. The S N discretized spatial balance equations, together with the SD and the SGF auxiliary equations form the SD-SGF-CN equations. We solve the SD-SGF-CN equations by using the one-node block inversion inner iterations (NBI), wherein the most recent estimates for the incoming group node-edge average or prescribed boundary conditions are used to evaluate the outgoing group node-edge average fluxes in the directions of the S N transport sweeps, for each estimate of the dominant eigenvalue in the conventional Power outer iterations. We show in numerical calculations that the SD-SGF-CN method is very accurate for coarse-mesh multigroup S N eigenvalue problems, even though the transverse leakage terms are approximated rather simply. (author)

  8. Spectral Line Shapes. Proceedings

    International Nuclear Information System (INIS)

    Zoppi, M.; Ulivi, L.

    1997-01-01

    These proceedings represent papers presented at the 13th International Conference on Spectral Line Shapes which was held in Firenze,Italy from June 16-21, 1996. The topics covered a wide range of subjects emphasizing the physical processes associated with the formation of line profiles: high and low density plasma; atoms and molecules in strong laser fields, Dopple-free and ultra-fine spectroscopy; the line shapes generated by the interaction of neutrals, atoms and molecules, where the relavant quantities are single particle properties, and the interaction-induced spectroscopy. There were 131 papers presented at the conference, out of these, 6 have been abstracted for the Energy Science and Technology database

  9. The Effect of Substrate Emissivity on the Spectral Emission of a Hot-Gas Overlayer

    Science.gov (United States)

    2015-12-30

    The spectral radiosity , denoted by Js(0, λ, Ts, Tsurf) accounts for both the emitted spectral energy and the reflected spectral energy from the...spectral intensity emitted from the window is given by I(λ, Twin) = εwinI(λ, Twin)BB where εwin is the spectral emissivity. The spectral radiosity incident... radiosity , one determines that the window contributes 6.1% reflected radiation to the observed signal from the anode. Figure 9. Anode-Window Geometry

  10. Spectral gamuts and spectral gamut mapping

    Science.gov (United States)

    Rosen, Mitchell R.; Derhak, Maxim W.

    2006-01-01

    All imaging devices have two gamuts: the stimulus gamut and the response gamut. The response gamut of a print engine is typically described in CIE colorimetry units, a system derived to quantify human color response. More fundamental than colorimetric gamuts are spectral gamuts, based on radiance, reflectance or transmittance units. Spectral gamuts depend on the physics of light or on how materials interact with light and do not involve the human's photoreceptor integration or brain processing. Methods for visualizing a spectral gamut raise challenges as do considerations of how to utilize such a data-set for producing superior color reproductions. Recent work has described a transformation of spectra reduced to 6-dimensions called LabPQR. LabPQR was designed as a hybrid space with three explicit colorimetric axes and three additional spectral reconstruction axes. In this paper spectral gamuts are discussed making use of LabPQR. Also, spectral gamut mapping is considered in light of the colorimetric-spectral duality of the LabPQR space.

  11. Alkoholio ir tabako pasiūlos ir paklausos teisinio reguliavimo raida Lietuvos Respublikoje: problemos ir sprendimai

    OpenAIRE

    Mockevičius, Arminas

    2014-01-01

    Viešosios teisės magistro studijų programos studento Armino Mockevičiaus buvo parašytas magistro baigiamasis darbas „Alkoholio ir tabako pasiūlos ir paklausos teisinio reguliavimo raida Lietuvos Respublikoje: problemos ir sprendimai“. Šis darbas parašytas Vilniuje, 2014 metais, Mykolo Romerio universiteto Teisės fakulteto Konstitucinės ir administracinės teisės institute, vadovaujant dr. Gintautui Vilkeliui, apimtis 98 p. Darbo tikslas yra atskleisti alkoholio ir tabako pasiūlos ir paklau...

  12. Spectral analysis of the structure of ultradispersed diamonds

    Science.gov (United States)

    Uglov, V. V.; Shimanski, V. I.; Rusalsky, D. P.; Samtsov, M. P.

    2008-07-01

    The structure of ultradispersed diamonds (UDD) is studied by spectral methods. The presence of diamond crystal phase in the UDD is found based on x-ray analysis and Raman spectra. The Raman spectra also show sp2-and sp3-hybridized carbon. Analysis of IR absorption spectra suggests that the composition of functional groups present in the particles changes during the treatment.

  13. Strong-Field Physics with Mid-IR Fields

    Directory of Open Access Journals (Sweden)

    Benjamin Wolter

    2015-06-01

    Full Text Available Strong-field physics is currently experiencing a shift towards the use of mid-IR driving wavelengths. This is because they permit conducting experiments unambiguously in the quasistatic regime and enable exploiting the effects related to ponderomotive scaling of electron recollisions. Initial measurements taken in the mid-IR immediately led to a deeper understanding of photoionization and allowed a discrimination among different theoretical models. Ponderomotive scaling of rescattering has enabled new avenues towards time-resolved probing of molecular structure. Essential for this paradigm shift was the convergence of two experimental tools: (1 intense mid-IR sources that can create high-energy photons and electrons while operating within the quasistatic regime and (2 detection systems that can detect the generated high-energy particles and image the entire momentum space of the interaction in full coincidence. Here, we present a unique combination of these two essential ingredients, namely, a 160-kHz mid-IR source and a reaction microscope detection system, to present an experimental methodology that provides an unprecedented three-dimensional view of strong-field interactions. The system is capable of generating and detecting electron energies that span a 6 order of magnitude dynamic range. We demonstrate the versatility of the system by investigating electron recollisions, the core process that drives strong-field phenomena, at both low (meV and high (hundreds of eV energies. The low-energy region is used to investigate recently discovered low-energy structures, while the high-energy electrons are used to probe atomic structure via laser-induced electron diffraction. Moreover, we present, for the first time, the correlated momentum distribution of electrons from nonsequential double ionization driven by mid-IR pulses.

  14. Comprehensive spectral and instrumental approaches for the easy monitoring of features and purity of different carbon nanostructures for nanocomposite applications

    International Nuclear Information System (INIS)

    Boccaleri, Enrico; Arrais, Aldo; Frache, Alberto; Gianelli, Walter; Fino, Paolo; Camino, Giovanni

    2006-01-01

    A wide series of carbon nanostructures (ranging from fullerenes, through carbon nanotubes, up to carbon nanofibers) promise to change several fields in material science, but a real industrial implementation depends on their availability at reasonable prices with affordable and reproducible degrees of purity. In this study we propose simple instrumental approaches to efficiently characterize different commercial samples, particularly for qualitative evaluation of impurities, the discrimination of their respective spectral features and, when possible, for quantitative determination. We critically discuss information that researchers in the field of nanocomposite technology can achieve in this aim by spectral techniques such as Raman and FT-IR spectroscopy, thermo-gravimetrical analysis, mass spectrometry-hyphenated thermogravimetry, X-ray diffraction and energy dispersive spectroscopy. All these can be helpful, in applied research on material science, for a fast reliable monitoring of the actual purity of carbon products in both commercial and laboratory-produced samples as well as in composite materials

  15. Thermally Resilient, Broadband Optical Absorber from UV to IR Derived from Carbon Nanostructures

    Science.gov (United States)

    Kaul, Anupama B.; Coles, James B.

    2012-01-01

    Optical absorber coatings have been developed from carbon-based paints, metal blacks, or glassy carbon. However, such materials are not truly black and have poor absorption characteristics at longer wavelengths. The blackness of such coatings is important to increase the accuracy of calibration targets used in radiometric imaging spectrometers since blackbody cavities are prohibitively large in size. Such coatings are also useful potentially for thermal detectors, where a broadband absorber is desired. Au-black has been a commonly used broadband optical absorber, but it is very fragile and can easily be damaged by heat and mechanical vibration. An optically efficient, thermally rugged absorber could also be beneficial for thermal solar cell applications for energy harnessing, particularly in the 350-2,500 nm spectral window. It has been demonstrated that arrays of vertically oriented carbon nanotubes (CNTs), specifically multi-walled-carbon- nanotubes (MWCNTs), are an exceptional optical absorber over a broad range of wavelengths well into the infrared (IR). The reflectance of such arrays is 100x lower compared to conventional black materials, such as Au black in the spectral window of 350-2,500 nm. Total hemispherical measurements revealed a reflectance of approximately equal to 1.7% at lambda approximately equal to 1 micrometer, and at longer wavelengths into the infrared (IR), the specular reflectance was approximately equal to 2.4% at lambda approximately equal to 7 micrometers. The previously synthesized CNTs for optical absorber applications were formed using water-assisted thermal chemical vapor deposition (CVD), which yields CNT lengths in excess of 100's of microns. Vertical alignment, deemed to be a critical feature in enabling the high optical absorption from CNT arrays, occurs primarily via the crowding effect with thermal CVD synthesized CNTs, which is generally not effective in aligning CNTs with lengths less than 10 m. Here it has been shown that the

  16. A Resolved and Asymmetric Ring of PAHs within the Young Circumstellar Disk of IRS 48

    Energy Technology Data Exchange (ETDEWEB)

    Schworer, Guillaume; Lacour, Sylvestre; Du Foresto, Vincent Coudé [LESIA, Observatoire de Paris, PSL Research University, CNRS, Sorbonne Universits, UPMC Univ. Paris 06, Univ. Paris Diderot, Sorbonne Paris Cité (France); Huélamo, Nuria [Dpto. Astrofísica, Centro de Astrobiología (INTA-CSIC), ESAC Campus, P.O. Box 78, E-28691, Villanueva de la Cañada (Spain); Pinte, Christophe; Chauvin, Gaël [Univ. Grenoble Alpes, IPAG, F-38000 Grenoble, France CNRS, IPAG, F-38000 Grenoble (France); Ehrenreich, David [Observatoire de l’Université de Genève, 51 chemin des Maillettes, 1290 Versoix (Switzerland); Girard, Julien [European Southern Observatory, Alonso de Cordova 3107, Casilla 19001 Vitacura, Santiago 19 (Chile); Tuthill, Peter [Sydney Institute for Astronomy, School of Physics, The University of Sydney, NSW 2006 (Australia)

    2017-06-20

    For one decade, the spectral type and age of the ρ Oph object IRS-48 were subject to debate and mystery. Modeling its disk with mid-infrared to millimeter observations led to various explanations to account for the complex intricacy of dust holes and gas-depleted regions. We present multi-epoch high-angular-resolution interferometric near-infrared data of spatially resolved emissions in the first 15 au of IRS-48, known to have very strong polycyclic aromatic hydrocarbon (PAH) emissions within this dust-depleted region. We make use of new Sparse-Aperture-Masking data to instruct a revised radiative-transfer model, where spectral energy distribution fluxes and interferometry are jointly fitted. Neutral and ionized PAH, very small grains (VSG), and classical silicates are incorporated into the model; new stellar parameters and extinction laws are explored. A bright (42 L {sub ⊙}) and hence large (2.5 R {sub ⊙}) central star with A {sub v} = 12.5 mag and R {sub v} = 6.5 requires less near-infrared excess: the inner-most disk at ≈1 au is incompatible with the interferometric data. The revised stellar parameters place this system on a 4 Myr evolutionary track, four times younger than the previous estimations, which is in better agreement with the surrounding ρ Oph region and disk-lifetime observations. The disk-structure solution converges to a classical-grain outer disk from 55 au combined with an unsettled and fully resolved VSG and PAH ring, between 11 and 26 au. We find two overluminosities in the PAH ring at color-temperatures consistent with the radiative transfer simulations; one follows a Keplerian circular orbit at 14 au. We show a depletion of a factor of ≈5 of classical dust grains up to 0.3 mm compared to very small particles: the IRS-48 disk is nearly void of dust grains in the first 55 au. A 3.5 M {sub Jup} planet on a 40 au orbit can qualitatively explain the new disk structure.

  17. Characterization of Hydrogen Bonds by IR Spectroscopy

    Directory of Open Access Journals (Sweden)

    Vojta, D.

    2012-05-01

    Full Text Available In the identification and quantification of hydrogen bond, as one of the most abundant non-covalent interactions in phenomena like self-assembly and molecular recognition, IR spectrosopy has been employed as the most sensitive method. The performance of the high dilution method enables determination of the stability constant of hydrogen-bonded complex as one of the most important thermodynamic quantities used in their characterization. However, the alleged experimental simplicity of the mentioned method is loaded with errors originating not only from researcher intervention but also independent from it. The second source of error is particularly emphasized and elaborated in this paper, which is designed as the recipe for the successful characterization of hydrogen bonds. Besides the enumeration of all steps in the determination of hydrogen-bonded stability constants, the reader can be acquainted with the most important ex perimental conditions that should be fulfilled in order to minimize the naturally occurring errors in this type of investigation. In the spectral analysis, the application of both uni- and multivariate approach has been discussed. Some computer packages, considering the latter, are mentioned, described, and recommended. KUI -10/2012Received August 1, 2011Accepted October 24, 2011

  18. Near diffraction limited mid-IR spectromicroscopy using frequency upconversion

    DEFF Research Database (Denmark)

    Sanders, Nicolai Højer; Dam, Jeppe Seidelin; Tidemand-Lichtenberg, Peter

    2014-01-01

    morphological and spectral imaging. Recent developments in nonlinear frequency upconversion, have demonstrated the potential to perform both imaging and spectroscopy in the mid-IR range at unparalleled low levels of illumination, the low upconversion detector noise being orders of magnitude below competing...... technologies. With these applications in mind, we have incorporated microscopy optics into an image upconversion system, achieving near diffraction limited spatial resolution in the 3 μm range. Spectroscopic information is further acquired by appropriate control of the phase match condition of the upconversion...

  19. Portable compact multifunction IR calibrator

    International Nuclear Information System (INIS)

    Wyatt, C.L.; Jacobsen, L.; Steed, A.

    1988-01-01

    A compact portable multifunction calibrator designed for future sensor systems is described which enables a linearity calibration for all detectors simultaneously using a near small-area source, a high-resolution mapping of the focal plane with 10 microrad setability and with a blur of less than 100 microrad, system spectral response calibration (radiometer) using a Michelson interferometer source, relative spectral response (spectrometer) using high-temperature external commercial blackbody simulators, and an absolute calibration using an internal low-temperature extended-area source. 5 references

  20. Oferta ir akceptas vartojimo sutartyse

    OpenAIRE

    Ežerskytė, Ramunė

    2011-01-01

    Sutarčiai sudaryti paprastai reikia, kad viena šalis pasiūlytų sudaryti sutartį (oferta), o kita šalis sutiktų su pasiūlymu (akceptas). Sutarčių įvairovėje išskiriamos vartojimo sutartys, kurios dėl silpnesnės šalies apsaugos principo įgyvendinimo pasižymi tam tikrais ypatumais. Vartojimo sutarčių sudarymas pateikiant ofertą ir akceptą yra šio magistro baigiamojo darbo objektas. Magistro baigiamąjį darbą sudaro trys dalys. Pirmojoje darbo dalyje analizuojama vartojimo sutarties sąvoka ir spec...

  1. Optical properties of reduced graphene oxide and CuFe2O4 composites in the IR region

    Science.gov (United States)

    Ma, De-yue; Li, Xiao-xia; Guo, Yu-xiang; Zeng, Yu-run

    2018-01-01

    The complex refractive index of reduced graphene oxide and CuFe2O4 composites prepared by hydrothermal method was calculated using infrared Micro-reflective spectra and K-K relation, and the calculation errors were analyzed according to its IR transmission and spectral reflectivity calculated by Fresnel formula. And then normal emissivity of the composite in IR atmospheric window was calculated by means of Fresnel formula and modified refraction angle formula. The calculation accuracy was verified by comparing measured normal total emissivity with the calculated one. The results show that complex refractive index and normal emissivity calculated by the formulas have a high accuracy. It has been found that the composite has a good absorption and radiation characteristics in IR atmospheric window and a strong scattering ability in middle IR region by analyzing its extinction, absorption and radiation properties in IR region. Therefore, it may be used as IR absorption, extinction and radiation materials in some special fields.

  2. Chemical profiling and adulteration screening of Aquilariae Lignum Resinatum by Fourier transform infrared (FT-IR) spectroscopy and two-dimensional correlation infrared (2D-IR) spectroscopy

    Science.gov (United States)

    Qu, Lei; Chen, Jian-bo; Zhang, Gui-Jun; Sun, Su-qin; Zheng, Jing

    2017-03-01

    As a kind of expensive perfume and valuable herb, Aquilariae Lignum Resinatum (ALR) is often adulterated for economic motivations. In this research, Fourier transform infrared (FT-IR) spectroscopy is employed to establish a simple and quick method for the adulteration screening of ALR. First, the principal chemical constituents of ALR are characterized by FT-IR spectroscopy at room temperature and two-dimensional correlation infrared (2D-IR) spectroscopy with thermal perturbation. Besides the common cellulose and lignin compounds, a certain amount of resin is the characteristic constituent of ALR. Synchronous and asynchronous 2D-IR spectra indicate that the resin (an unstable secondary metabolite) is more sensitive than cellulose and lignin (stable structural constituents) to the thermal perturbation. Using a certified ALR sample as the reference, the infrared spectral correlation threshold is determined by 30 authentic samples and 6 adulterated samples. The spectral correlation coefficient of an authentic ALR sample to the standard reference should be not less than 0.9886 (p = 0.01). Three commercial adulterated ALR samples are identified by the correlation threshold. Further interpretation of the infrared spectra of the adulterated samples indicates the common adulterating methods - counterfeiting with other kind of wood, adding ingredient such as sand to increase the weight, and adding the cheap resin such as rosin to increase the content of resin compounds. Results of this research prove that FT-IR spectroscopy can be used as a simple and accurate quality control method of ALR.

  3. IL 6: 2D-IR spectroscopy: chemistry and biophysics in real time

    International Nuclear Information System (INIS)

    Bredenbeck, Jens

    2010-01-01

    Pulsed multidimensional experiments, daily business in the field of NMR spectroscopy, have been demonstrated only relatively recently in IR spectroscopy. Similar as nuclear spins in multidimensional NMR, molecular vibrations are employed in multidimensional IR experiments as probes of molecular structure and dynamics, albeit with femtosecond time resolution. Different types of multidimensional IR experiments have been implemented, resembling basic NMR experiments such as NOESY, COSY and EXSY. In contrast to one-dimensional linear spectroscopy, such multidimensional experiments reveal couplings and correlations of vibrations, which are closely linked to molecular structure and its change in time. The use of mixed IR/VIS pulse sequences further extends the potential of multidimensional IR spectroscopy, enabling studies of ultrafast non-equilibrium processes as well as surface specific, highly sensitive experiments. A UV/VIS pulse preceding the IR pulse sequence can be used to prepare the system under study in a non-equilibrium state. 2D-IR snapshots of the evolving non-equilibrium system are then taken, for example during a photochemical reaction or during the photo-cycle of a light sensitive protein. Preparing the system in a non-equilibrium state by UV/Vis excitation during the IR pulse sequence allows for correlating states of reactant and product of the light triggered process via their 2D-IR cross peaks - a technique that has been used to map the connectivity between different binding sites of a ligand as it migrates through a protein. Introduction of a non-resonant VIS pulse at the end of the IR part of the experiment allows to selectively up-convert the infrared signal of interfacial molecules to the visible spectral range by sum frequency generation. In this way, femtosecond interfacial 2D-IR spectroscopy can be implemented, achieving sub-monolayer sensitivity. (author)

  4. Method for the determination of the spectral composition of power-full energy-rich deuteron bundles generated in the plasma focus

    International Nuclear Information System