WorldWideScience

Sample records for internal reforming molten

  1. Development of large scale internal reforming molten carbonate fuel cell

    Energy Technology Data Exchange (ETDEWEB)

    Sasaki, A.; Shinoki, T.; Matsumura, M. [Mitsubishi Electric Corp., Hyogo (Japan)

    1996-12-31

    Internal Reforming (IR) is a prominent scheme for Molten Carbonate Fuel Cell (MCFC) power generating systems in order to get high efficiency i.e. 55-60% as based on the Higher Heating Value (HHV) and compact configuration. The Advanced Internal Reforming (AIR) technology has been developed based on two types of the IR-MCFC technology i.e. Direct Internal Reforming (DIR) and Indirect Internal Reforming (DIR).

  2. Nickel catalysts for internal reforming in molten carbonate fuel cells

    NARCIS (Netherlands)

    Berger, R.J.; Berger, R.J.; Doesburg, E.B.M.; Doesburg, E.B.M.; van Ommen, J.G.; Ross, J.R.H.; Ross, J.R.H.

    1996-01-01

    Natural gas may be used instead of hydrogen as fuel for the molten carbonate fuel cell (MCFC) by steam reforming the natural gas inside the MCFC, using a nickel catalyst (internal reforming). The severe conditions inside the MCFC, however, require that the catalyst has a very high stability. In

  3. Alkali resistant Ni-loaded yolk-shell catalysts for direct internal reforming in molten carbonate fuel cells

    Science.gov (United States)

    Jang, Won-Jun; Hong, Young Jun; Kim, Hak-Min; Shim, Jae-Oh; Roh, Hyun-Seog; Kang, Yun Chan

    2017-06-01

    A facile and scalable spray pyrolysis process is applied to synthesize multi-shelled Ni-loaded yolk-shell catalysts on various supports (Al2O3, CeO2, ZrO2, and La(OH)3). The prepared catalysts are applied to direct internal reforming (DIR) in a molten carbonate fuel cell (MCFC). Even on exposure to alkali hydroxide vapors, the Ni-loaded yolk-shell catalysts remain highly active for DIR-MCFCs. The Ni@Al2O3 microspheres show the highest conversion (92%) of CH4 and the best stability among the prepared Ni-loaded yolk-shell catalysts. Although the initial CH4 conversion of the Ni@ZrO2 microspheres is higher than that of the Ni@CeO2 microspheres, the Ni@CeO2 microspheres are more stable. The catalytic performance is strongly dependent on the surface area and acidity and also partly dependent on the reducibility. The acidic nature of Al2O3 combined with its high surface area and yolk-shell structure enhances the adsorption of CH4 and resistance against alkali poisoning, resulting in efficient DIR-MCFC reactions.

  4. Non-linear model reduction and control of molten carbonate fuel cell systems with internal reforming

    Energy Technology Data Exchange (ETDEWEB)

    Sheng, Min

    2007-10-12

    Currently, the process design of fuel cells and the development of control strategies is mainly based on heuristic methods. Fuel cell models are often too complex for control purposes, or they are developed for a specific type of fuel cell and valid only in a small range of operation conditions. The application of fuel cell models to controller design is still limited. Furthermore, suitable and simple-to-implement design strategies for fuel cell control remain an open area. There is thus a motivation for simplifying dynamic models for process control applications and for designing suitable control strategies for fuel cells. This is the main objective of this work. As an application example, the 250 kW industrial molten carbonate fuel cell (MCFC) system HotModule by MTU CFC Solutions, Germany is considered. A detailed dynamic two-dimensional spatially distributed cross-flow model of a MCFC from literature is taken as a starting point for the investigation. In Chapter 2, two simplified model versions are derived by incorporating additional physical assumptions. One of the simplified models is extended to a three-dimensional stack model to deal with physical and chemical phenomena in the stack. Simulations of the stack model are performed in Chapter 3 in order to calculate the mass and temperature distributions in the direction perpendicular to the electrode area. The other simplified model forms the basis for a low order reduced model that is derived in Chapter 4. The reduced-order model is constructed by application of the Karhunen-Loeve Galerkin method. The spatial temperature, concentration and potential profiles are approximated by a set of orthogonal time independent spatial basis functions. Problem specific basis functions are generated numerically from simulation data of the detailed reference model. The advantage of this approach is that a small number of basis functions suffices in order to approximate the solution of the detailed model very well. The

  5. Preparation of a Ni-MgO-Al2O3 catalyst with high activity and resistance to potassium poisoning during direct internal reforming of methane in molten carbonate fuel cells

    Science.gov (United States)

    Jang, Won-Jun; Jung, You-Shick; Shim, Jae-Oh; Roh, Hyun-Seog; Yoon, Wang Lai

    2018-02-01

    Steam reforming of methane (SRM) is conducted using a series of Ni-MgO-Al2O3 catalysts for direct internal reforming (DIR) in molten carbonate fuel cells (MCFCs). Ni-MgO-Al2O3 catalysts are prepared by the homogeneous precipitation method with a variety of MgO loading amounts ranging from 3 to 15 wt%. In addition, each precursor concentrations are systemically changed (Ni: 1.2-4.8 mol L-1; Mg: 0.3-1.2 mol L-1; Al: 0.4-1.6 mol L-1) at the optimized composition (10 wt% MgO). The effects of MgO loading and precursor concentration on the catalytic performance and resistance against poisoning of the catalyst by potassium (K) are investigated. The Ni-MgO-Al2O3 catalyst with 10 wt% MgO and the original precursor concentration (Ni: 1.2 mol L-1; Mg: 0.3 mol L-1; Al: 0.4 mol L-1) exhibits the highest CH4 conversion and resistance against K poisoning even at the extremely high gas space velocity (GHSV) of 1,512,000 h-1. Excellent SRM performance of the Ni-MgO-Al2O3 catalyst is attributed to strong metal (Ni) to alumina support interaction (SMSI) when magnesium oxide (MgO) is co-precipitated with the Ni-Al2O3. The enhanced interaction of the Ni with MgO-Al2O3 support is found to protect the active Ni species against K poisoning.

  6. Ethanol steam reforming heated up by molten salt CSP: Reactor assessment

    NARCIS (Netherlands)

    De Falco, Marcello; Gallucci, F.

    2010-01-01

    In this paper hydrogen production via reforming of ethanol has been studied in a novel hybrid plant consisting in a ethanol reformer and a concentrating solar power (CSP) plant using molten salt as heat carrier fluid. The heat needed for the reforming of ethanol has been supplied to the system by

  7. The effect of precipitants on Ni-Al2O3 catalysts prepared by a co-precipitation method for internal reforming in molten carbonate fuel cells

    Science.gov (United States)

    Jung, You-Shick; Yoon, Wang-Lai; Seo, Yong-Seog; Rhee, Young-Woo

    2012-01-01

    Ni-Al2O3 catalysts are prepared via the co-precipitation method using various precipitants: urea, Na2CO3, NaOH, K2CO3, KOH and NH4OH. The effects of the precipitants on the physicochemical properties and catalytic activities of the Ni-Al2O3 catalysts are investigated. The Ni50-urea catalyst displays the largest specific surface area and the highest pore volume. This catalyst also exhibits the highest Ni dispersion and the largest Ni surface area. Ni50-urea catalyst prepared with urea as precipitant and Ni50-K2CO3 catalyst prepared with K2CO3 as precipitant exhibit high pore volumes and good catalytic activities for methane steam reforming. The Ni50-urea catalyst exhibits the best physicochemical properties and shows good catalytic activity and a strong resistance to electrolyte contamination. PMID:22962548

  8. Thermal-hydraulics of internally heated molten salts and application to the Molten Salt Fast Reactor

    Science.gov (United States)

    Fiorina, Carlo; Cammi, Antonio; Luzzi, Lelio; Mikityuk, Konstantin; Ninokata, Hisashi; Ricotti, Marco E.

    2014-04-01

    The Molten Salt Reactors (MSR) are an innovative kind of nuclear reactors and are presently considered in the framework of the Generation IV International Forum (GIF-IV) for their promising performances in terms of low resource utilization, waste minimization and enhanced safety. A unique feature of MSRs is that molten fluoride salts play the distinctive role of both fuel (heat source) and coolant. The presence of an internal heat generation perturbs the temperature field and consequences are to be expected on the heat transfer characteristics of the molten salts. In this paper, the problem of heat transfer for internally heated fluids in a straight circular channel is first faced on a theoretical ground. The effect of internal heat generation is demonstrated to be described by a corrective factor applied to traditional correlations for the Nusselt number. It is shown that the corrective factor can be fully characterized by making explicit the dependency on Reynolds and Prandtl numbers. On this basis, a preliminary correlation is proposed for the case of molten fluoride salts by interpolating the results provided by an analytic approach previously developed at the Politecnico di Milano. The experimental facility and the related measuring procedure for testing the proposed correlation are then presented. Finally, the developed correlation is used to carry out a parametric investigation on the effect of internal heat generation on the main out-of-core components of the Molten Salt Fast Reactor (MSFR), the reference circulating-fuel MSR design in the GIF-IV. The volumetric power determines higher temperatures at the channel wall, but the effect is significant only in case of large diameters and/or low velocities.

  9. Concertina Reforms with International Capital Mobility

    DEFF Research Database (Denmark)

    Kreickemeier, Udo; Raimondos-Møller, Pascalis

    2006-01-01

    reform lowers welfare it lowers market access as well, thereby compromising a second goal that is typically connected with trade liberalisation.JEL-Classification: F11, F13, F15Key words: Trade Policy Reform, International Factor Mobility, Welfare, MarketAccess......We show that the standard concertina result for tariff reforms -i.e. loweringthe highest tariff increases welfare - no longer holds in general if we allow for international capital mobility. The result can break down if the good whose tariff is lowered is not capital intensive. If the concertina...

  10. Fuel cell with internal reforming

    International Nuclear Information System (INIS)

    Maru, H.C.; Patel, P.S.

    1982-01-01

    A fuel cell system provided with a first passage means in communication with and adjacent to a cell diffusion electrode and with a second passage means having a catalyst for reforming hydrocarbons and communicating with the first passage means through a gas porous member. Differential pressure means is further provided to establish a pressure differential between the passage means for promoting reformed gas flow from the second passage means to the first passage means and retarding electrolyte vapor passage from the first passage means to the second passage means

  11. International Aspects of Nigeria's Economic Reforms | Iyoha ...

    African Journals Online (AJOL)

    This paper attempts to draw a relationship between Nigeria's previous failed economic reforms and external influences from international financial institutions, which had constantly resulted in chronic economic misfortunes. Now that homegrown economic programmes are currently being undertaken in Africa through ...

  12. The Twentieth International Symposium on Molten Salts and Ionic Liquids

    Science.gov (United States)

    2016-11-29

    Characteristics of Capacitors Based on Ionic Liquids: From Dielectric Polymers to Redox-Active Adsorbed Species E. Lust, L. Siinor, H. Kurig, T. Romann, V...Tungsten from Super Hard Alloys in Molten Sodium Hydroxide T. Oishi 633 Red-Ox Reactions in Ionic Liquids and Their Impact on Electrodeposition of

  13. A novel configuration for direct internal reforming stacks

    Science.gov (United States)

    Fellows, Richard

    This paper presents a stack concept that can be applied to both molten carbonate fuel cell (MCFC) and solid oxide fuel cell (SOFC) internal reforming stacks. It employs anode recycle and allows the design of very simple system configurations, while giving enhanced efficiencies and high specific power densities. The recycle of anode exit gas to the anode inlet has previously been proposed as a means of preventing carbon deposition in direct internal reforming (DIR) stacks. When applied to a normal stack this reduces the Nernst voltages because the recycle stream is relatively depleted in hydrogen. In the concept proposed here, known as the `Smarter' stack, there are two anode exit streams, one of which is depleted, while the other is relatively undepleted. The depleted stream passes directly to the burner, and the undepleted stream is recycled to the stack inlet. By this means high Nernst voltages are achieved in the stack. The concept has been simulated and assessed for parallel-flow and cross-flow MCFC and SOFC stacks and graphs are presented showing temperature distributions. The `Smarter' stacks employ a high recycle rate resulting in a reduced natural gas concentration at the stack inlet, and this reduces or eliminates the unfavourable temperature dip. Catalyst grading can further improve the temperature distribution. The concept allows simple system configurations in which the need for fuel pre-heat is eliminated. Efficiencies are up to 10 percentage points higher than for conventional stacks with the same cell area and maximum stack temperature. The concept presented here was devised in a project part-funded by the EU, and has been adopted by the European Advanced DIR-MCFC development programme led by BCN.

  14. Internal reforming fuel cell assembly with simplified fuel feed

    Science.gov (United States)

    Farooque, Mohammad; Novacco, Lawrence J.; Allen, Jeffrey P.

    2001-01-01

    A fuel cell assembly in which fuel cells adapted to internally reform fuel and fuel reformers for reforming fuel are arranged in a fuel cell stack. The fuel inlet ports of the fuel cells and the fuel inlet ports and reformed fuel outlet ports of the fuel reformers are arranged on one face of the fuel cell stack. A manifold sealing encloses this face of the stack and a reformer fuel delivery system is arranged entirely within the region between the manifold and the one face of the stack. The fuel reformer has a foil wrapping and a cover member forming with the foil wrapping an enclosed structure.

  15. Demonstration of direct internal reforming for MCFC power plants

    Energy Technology Data Exchange (ETDEWEB)

    Aasberg-Petersen, K.; Christensen, P.S.; Winther, S.K. [HALDOR TOPSOE A/S, Lynby (Denmark)] [and others

    1996-12-31

    The conversion of methane into hydrogen for an MCFC by steam reforming is accomplished either externally or internally in the stack. In the case of external reforming the plant electrical efficiency is 5% abs. lower mainly because more parasitic power is required for air compression for stack cooling. Furthermore, heat produced in the stack must be transferred to the external reformer to drive the endothermic steam reforming reaction giving a more complex plant lay-out. A more suitable and cost effective approach is to use internal steam reforming of methane. Internal reforming may be accomplished either by Indirect Internal Reforming (DIR) and Direct Internal Reforming (DIR) in series or by DIR-only as illustrated. To avoid carbon formation in the anode compartment higher hydrocarbons in the feedstock are converted into hydrogen, methane and carbon oxides by reaction with steam in ail adiabatic prereformer upstream the fuel cell stack. This paper discusses key elements of the desire of both types of internal reforming and presents data from pilot plants with a combined total of more than 10,000 operating hours. The project is being carried out as part of the activities of the European MCFC Consortium ARGE.

  16. Reforming Higher Education in "Transition": Between National and International Reform Initiatives--The Case of Slovenia

    Science.gov (United States)

    Zgaga, Pavel; Miklavic, Klemen

    2011-01-01

    The article analyzes the last two decades of higher education reforms in Slovenia. During the "period of transition," they were led by national as well as international initiatives. At an early stage, the national initiatives were mainly based on criticisms of the last reform made by the former regime, although the generation of new…

  17. International monetary system – between crisis and reform

    Directory of Open Access Journals (Sweden)

    Ramona ORĂŞTEAN

    2013-08-01

    Full Text Available The 2008 global crisis that hit in the heart of the system highlighted main deficiencies and vulnerabilities of the current international monetary system and revived the old concerns about its functioning. The reform of the international monetary system is under discussion again after a long period, during the ’90 crises, especially in Southeast Asia, Russia and Brazil. To explain the relation between crisis and reform, this paper identifies some variables and hypotheses. It also analyses the matters that have sparked interest in reforming the international monetary system, in the context of the causes of the crisis and its vulnerabilities, admitting that the current system is not a perfect one. The paper concludes that it is time for a deep reform of the international monetary system.

  18. Methanol steam reforming promoted by molten salt-modified platinum on alumina catalysts.

    Science.gov (United States)

    Kusche, Matthias; Agel, Friederike; Ní Bhriain, Nollaig; Kaftan, Andre; Laurin, Mathias; Libuda, Jörg; Wasserscheid, Peter

    2014-09-01

    We herein describe a straight forward procedure to increase the performance of platinum-on-alumina catalysts in methanol steam reforming by applying an alkali hydroxide coating according to the "solid catalyst with ionic liquid layer" (SCILL) approach. We demonstrate by diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) and temperature-programmed desorption (TPD) studies that potassium doping plays an important role in the catalyst activation. Moreover, the hygroscopic nature and the basicity of the salt modification contribute to the considerable enhancement in catalytic performance. During reaction, a partly liquid film of alkali hydroxides/carbonates forms on the catalyst/alumina surface, thus significantly enhancing the availability of water at the catalytically active sites. Too high catalyst pore fillings with salt introduce a considerable mass transfer barrier into the system as indicated by kinetic studies. Thus, the optimum interplay between beneficial catalyst modification and detrimental mass transfer effects had to be identified and was found on the applied platinum-on-alumina catalyst at KOH loadings around 7.5 mass%. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  19. Issues of internal control during the reform period

    Directory of Open Access Journals (Sweden)

    O.I. Gresova

    2012-12-01

    Full Text Available The paper considers theoretical and methodological problems of organization and financial control activities, the main problems and reasons causing the need for a unified system of internal financial control in the State Administration of Railway Transport of Ukraine at the stage of the reform.

  20. Globalization and Summit Reform: An Experiment in International ...

    International Development Research Centre (IDRC) Digital Library (Canada)

    2008-06-02

    Jun 2, 2008 ... Featuring a Foreword by Dr Gordon Smith, an Afterword by the Right Honourable Paul Martin, former Prime Minister of Canada, and a glossary of terms, Globalization and Summit Reform provides a unique, insiders' perspective on the process of international governance and its future prospects. A course ...

  1. On Quality Education Reform in International Trade Major

    Science.gov (United States)

    Ma, Jing; Xiao, Jing

    2011-01-01

    The purpose of this paper is to analyze the existing problems of quality education of specialization of international trade in current colleges and universities of China, and then propose several pieces of corresponding suggestion on educational reform. According to the characteristics of college and university education, we shall emphasize on the…

  2. Globalization and Summit Reform: An Experiment in International ...

    International Development Research Centre (IDRC) Digital Library (Canada)

    2 juin 2008 ... Featuring a Foreword by Dr Gordon Smith, an Afterword by the Right Honourable Paul Martin, former Prime Minister of Canada, and a glossary of terms, Globalization and Summit Reform provides a unique, insiders' perspective on the process of international governance and its future prospects. A course ...

  3. High performance internal reforming unit for high temperature fuel cells

    Science.gov (United States)

    Ma, Zhiwen [Sandy Hook, CT; Venkataraman, Ramakrishnan [New Milford, CT; Novacco, Lawrence J [Brookfield, CT

    2008-10-07

    A fuel reformer having an enclosure with first and second opposing surfaces, a sidewall connecting the first and second opposing surfaces and an inlet port and an outlet port in the sidewall. A plate assembly supporting a catalyst and baffles are also disposed in the enclosure. A main baffle extends into the enclosure from a point of the sidewall between the inlet and outlet ports. The main baffle cooperates with the enclosure and the plate assembly to establish a path for the flow of fuel gas through the reformer from the inlet port to the outlet port. At least a first directing baffle extends in the enclosure from one of the sidewall and the main baffle and cooperates with the plate assembly and the enclosure to alter the gas flow path. Desired graded catalyst loading pattern has been defined for optimized thermal management for the internal reforming high temperature fuel cells so as to achieve high cell performance.

  4. Arab Reform Initiative | IDRC - International Development Research ...

    International Development Research Centre (IDRC) Digital Library (Canada)

    The conference will be devoted to an exchange between institutions conducting research on Islamist movements with support from IDRC and ARI. ... International Water Resources Association, in close collaboration with IDRC, is holding a webinar titled “Climate change and adaptive water management: Innovative solutions ...

  5. 76 FR 42625 - International Settlements Policy Reform

    Science.gov (United States)

    2011-07-19

    ... Duplicate, Overlap, or Conflict With the Proposed Rule None. 9. Ordering Clauses It is ordered that... communications, if the agreement is for an international route on the Commission's ``Exclusion List,'' and the..., pursuant to Note 3 to this section. The Commission's ``Exclusion List'' identifies countries and facilities...

  6. 78 FR 11109 - International Settlements Policy Reform

    Science.gov (United States)

    2013-02-15

    ... routes giving U.S. consumers competitive pricing when they make international calls. The Commission also... apply, with the exception of Cuba. The market has seen significant competitive growth since the Commission last reviewed the ISP. Further, in today's competitive market, maintaining the ISP has the...

  7. [Changes necessary for continuing health reform: II. The "internal" change].

    Science.gov (United States)

    Martín Martín, J; de Manuel Keenoy, E; Carmona López, G; Martínez Olmos, J

    1990-01-01

    The article desired organizational and managerial changes in Primary Health Care, so as to develop a sound and feasible social marketing strategy. Key elements that should be changed are: 1. Rigid and centralized administrative structures and procedures. 2. Incentives system centralized and dissociated from the managerial structure. 3. Primary Health Care management units immersed in political conflict. 4. Absence of alternative in the margin. Users cannot choose. 5. Lack of an internal marketing strategy. Several ways of internal markets simulation are assessed as potential means for internal change. The need for an administration reform leading to a less inflexible system in the Spanish national and regional health services in reviewed too. Three changes are considered essential: a) Payment systems in Primary Health Care. b) Modifications in the personnel contracts. c) Reform of the budgeting processes. Specific strategies in each of these issues are suggested, making emphasizing the need of their interrelationship and coherence.

  8. Development of internal manifold heat exchanger (IMHEX reg-sign) molten carbonate fuel cell stacks

    International Nuclear Information System (INIS)

    Marianowski, L.G.; Ong, E.T.; Petri, R.J.; Remick, R.J.

    1991-01-01

    The Institute of Gas Technology (IGT) has been in the forefront of molten carbonate fuel cell (MCFC) development for over 25 years. Numerous cell designs have been tested and extensive tests have been performed on a variety of gas manifolding alternatives for cells and stacks. Based upon the results of these performance tests, IGT's development efforts started focusing on an internal gas manifolding concept. This work, initiated in 1988, is known today as the IMHEX reg-sign concept. MCP has developed a comprehensive commercialization program loading to the sale of commercial units in 1996. MCP's role is in the manufacture of stack components, stack assembly, MCFC subsystem testing, and the design, marketing and construction of MCFC power plants. Numerous subscale (1 ft 2 ) stacks have been operated containing between 3 and 70 cells. These tests verified and demonstrated the viability of internal manifolding from technical (no carbonate pumping), engineering (relaxed part dimensional tolerance requirements), and operational (good gas sealing) aspects. Simplified fabrication, ease of assembly, the elimination of external manifolds and all associated clamping requirements has significantly lowered anticipated stack costs. Ongoing 1 ft 2 stack testing is generating performance and endurance characteristics as a function of system specified operating conditions. Commercial-sized, full-area stacks (10 ft 2 ) are in the process of being assembled and will be tested in November. This paper will review the recent developments the MCFC scale-up and manufacture work of MCP, and the research and development efforts of IGT which support those efforts. 17 figs

  9. Development of internal manifold heat exchanger (IMHEX reg sign ) molten carbonate fuel cell stacks

    Energy Technology Data Exchange (ETDEWEB)

    Marianowski, L.G.; Ong, E.T.; Petri, R.J.; Remick, R.J.

    1991-01-01

    The Institute of Gas Technology (IGT) has been in the forefront of molten carbonate fuel cell (MCFC) development for over 25 years. Numerous cell designs have been tested and extensive tests have been performed on a variety of gas manifolding alternatives for cells and stacks. Based upon the results of these performance tests, IGT's development efforts started focusing on an internal gas manifolding concept. This work, initiated in 1988, is known today as the IMHEX{reg sign} concept. MCP has developed a comprehensive commercialization program loading to the sale of commercial units in 1996. MCP's role is in the manufacture of stack components, stack assembly, MCFC subsystem testing, and the design, marketing and construction of MCFC power plants. Numerous subscale (1 ft{sup 2}) stacks have been operated containing between 3 and 70 cells. These tests verified and demonstrated the viability of internal manifolding from technical (no carbonate pumping), engineering (relaxed part dimensional tolerance requirements), and operational (good gas sealing) aspects. Simplified fabrication, ease of assembly, the elimination of external manifolds and all associated clamping requirements has significantly lowered anticipated stack costs. Ongoing 1 ft{sup 2} stack testing is generating performance and endurance characteristics as a function of system specified operating conditions. Commercial-sized, full-area stacks (10 ft{sup 2}) are in the process of being assembled and will be tested in November. This paper will review the recent developments the MCFC scale-up and manufacture work of MCP, and the research and development efforts of IGT which support those efforts. 17 figs.

  10. Competitive effects and instruments of power sector reforms. International reform concepts blockade structures, risk distribution. A political economy analysis

    International Nuclear Information System (INIS)

    Liebchen, Armin

    2014-01-01

    Power sectors with weak or inadequate competition structures are the rule, despite numerous attempts at reform. But can afford modern economies this defect for a long time? Why can the implementation of competition are blocked so effectively? The author studied international reform experiences and opens up interesting insights that can also reflect on problems of the German energy turnaround: The difficulty of timing and coordination of the reform components, the development of resistance levels of individual interest groups, breach of contract as a rational alternative, causes unwanted price effects, shifting interest situations of major stakeholders, change dynamics impending regulatory risks, pending financing risks, stranded cost-conflict situations for power stations disconnected from the grid and facilities and instruments of a political and regulatory risk management for reforms. With numerous examples, background analyzes and instruments to reform analysis, this book is aimed at investors, policy planners and analysts. [de

  11. International Seminar on the Role of Trade Unions in Educational Reform

    Science.gov (United States)

    Nordahl, K.

    1977-01-01

    Presents the content and conclusions from sessions of an international seminar on the role of trade unions in educational reform, organized by the International Labour Office in May 1976 and held near Oslo, Norway. (MF)

  12. Investigations on a new internally-heated tubular packed-bed methanol–steam reformer

    KAUST Repository

    Nehe, Prashant

    2015-05-01

    Small-scale reformers for hydrogen production through steam reforming of methanol can provide an alternative solution to the demand of continuous supply of hydrogen gas for the operation of Proton Exchange Membrane Fuel Cells (PEMFCs). A packed-bed type reformer is one of the potential designs for such purpose. An externally heated reformer has issues of adverse lower temperature in the core of the reformer and significant heat loss to the environment thus impacting its performance. Experimental and numerical studies on a new concept of internally heated tubular packed-bed methanol-steam reformer have been reported in this paper with improved performance in terms of higher methanol conversion and reduced heat losses to surroundings. CuO/ZnO/Al2O3 is used as the catalyst for the methanol-steam reforming reaction and a rod-type electric heater at the center of the reactor is used for supplying necessary heat for endothermic steam reforming reaction. The vaporizer and the reformer unit with a constant volume catalyst bed are integrated in the annular section of a tubular reformer unit. The performance of the reformer was investigated at various operating conditions like feed rate of water-methanol mixture, mass of the catalyst and reforming temperature. The experimental and numerical results show that the methanol conversion and CO concentration increase with internal heating for a wide range of operating conditions. The developed reformer unit generates 50-80W (based on lower heating value) of hydrogen gas for applications in PEMFCs. For optimized design and operating conditions, the reformer unit produced 298sccm reformed gas containing 70% H2, 27% CO2 and 3% CO at 200-240°C which can produce a power output of 25-32W assuming 60% fuel cell efficiency and 80% of hydrogen utilization in a PEMFC. © 2015 Hydrogen Energy Publications, LLC.

  13. Quench of molten aluminum oxide associated with in-vessel debris retention by RPV internal water

    International Nuclear Information System (INIS)

    Maruyama, Yu; Yamano, Norihiro; Moriyama, Kiyofumi; Park, Hyun Sun; Kudo, Tamotsu; Yang, Yanhua; Sugimoto, Jun

    1999-01-01

    In-vessel debris coolability experiments were performed in ALPHA program at JAERI. Molten aluminum oxide (Al 2 O 3 ) was poured into a pool of water in a lower head experimental vessel. Post-test observation and measurement using an ultrasonic technique indicated the formation of the interfacial gap between the solidified Al 2 O 3 and the vessel wall. Thermal responses of the vessel wall implied that the interfacial gap acted initially as a thermal resistance and water subsequently penetrated into the interfacial gap. The maximum heat flux at the inner surface of the vessel facing to the solidified Al 2 O 3 was roughly evaluated to be ranged from 320 kW/m 2 to 600 kW/m 2 . A post-test analysis was conducted with CAMP code. The influence of the interfacial gap on thermal behavior of Al 2 O 3 and the vessel wall was examined. (authors)

  14. Reforming Investor–State Dispute Settlement: A (Comparative and International) Constitutional Law Framework

    NARCIS (Netherlands)

    Schill, S.W.

    As a result of the steep increase in investment arbitrations, and the problems this has brought to the fore, many reform efforts in international investment law focus on changes to investor–state dispute settlement (ISDS). Reform proposals, however, diverge widely (ranging from exiting the system

  15. Mexico's "ley de narcomenudeo" drug policy reform and the international drug control regime.

    Science.gov (United States)

    Mackey, Tim K; Werb, Daniel; Beletsky, Leo; Rangel, Gudelia; Arredondo, Jaime; Strathdee, Steffanie A

    2014-11-14

    It has been over half a century since the landmark Single Convention on Narcotic Drugs was adopted, for the first time unifying international drug policy under a single treaty aimed at limiting use, manufacture, trade, possession, and trafficking of opiates, cannabis, and other narcotics. Since then, other international drug policy measures have been adopted, largely emphasizing enforcement-based approaches to reducing drug supply and use. Recently, in response to concerns that the historic focus on criminalization and enforcement has had limited effectiveness, international drug policies have begun to undergo a paradigm shift as countries seek to enact their own reforms to partially depenalize or deregulate personal drug use and possession. This includes Mexico, which in 2009 enacted national drug policy reform partially decriminalizing possession of small quantities of narcotics for personal consumption while also requiring drug treatment for repeat offenders. As countries move forward with their own reform models, critical assessment of their legal compatibility and effectiveness is necessary. In this commentary we conduct a critical assessment of the compatibility of Mexico's reform policy to the international drug policy regime and describe its role in the current evolving drug policy environment. We argue that Mexico's reform is consistent with flexibilities allowed under international drug treaty instruments and related commentaries. We also advocate that drug policy reforms and future governance efforts should be based on empirical evidence, emphasize harm reduction practices, and integrate evidence-based evaluation and implementation of drug reform measures.

  16. Healthy incentives: Canadian health reform in an international context

    National Research Council Canada - National Science Library

    Walker, Michael; McArthur, William; Ramsay, Cynthia

    1996-01-01

    .... Since health expenditures are one of the largest and fastest growing segments of provincial budgets, much of the fiscal reform taking place across the country has centred around cuts to health funding...

  17. [Reform efforts in dentistry - national and international approaches].

    Science.gov (United States)

    Kahl-Nieke, Bärbel; Vonneilich, Nico

    2018-02-01

    The Study of dentistry in Germany is in need of reform. The actual regulation on licensing dentists in Germany is from 1955, with the last changes made in 1993. Recently there have been different initiatives related to reform: a national catalogue of competency-based learning objectives in dental education (NKLZ), changes and stipulations in the respective rules relating to undergraduate curriculum in dental medicine, and an initiative of the Germany Ministry of Health to tackle and reorganize dental education in Germany.This article presents and reflects on these reform efforts in the context of actual teaching in Germany, Europe, and the United States.The reform process is an opportunity for dental education in German faculties of medicine. New dentistry programs are allowed at all faculties with model educational programs in medicine. Therefore, an example of actual reform efforts are presented based on the experiences of Hamburg. Research on dental educational programs revealed interesting approaches in dental education in other European faculties of medicine. Selected faculties were visited. These experiences led to the formulation of five main goals of reform: interdisciplinary study, problem- and symptom-based learning, early patient contact, science-based education, and communication training. The main goal is a dental education program designed along science-based, prevention-oriented, multidisciplinary, and individualized dental care that contributes to the life-long oral health of patients.

  18. Flame spread over electrical wire with AC electric fields: Internal circulation, fuel vapor-jet, spread rate acceleration, and molten insulator dripping

    KAUST Repository

    Lim, Seungjae

    2015-04-01

    The effect of electric field on the characteristics of flame spread along a polyethylene (PE) insulated electrical wire was investigated experimentally by varying the AC frequency and voltage applied to the wire. The results showed that the flame spread rate was accelerated due to the convergence of electric flux near the end of wire, having three distinct regimes depending on applied voltage. In each regime, several subregimes could be identified depending on AC frequency. Flame shape (height and width) and slanted direction of the spreading flame were influenced differently. Fuel-vapor jets were ejected from the molten PE surface even for the baseline case without the application of an electric field; this could be attributed to the bursting of fuel vapor bubbles generated from internal boiling at the molten PE surface. An internal circulation of molten-PE was also observed as a result of non-uniform heating by the spreading flame. In the high voltage regime with a high AC frequency, excessive dripping of molten PE led to flame extinction.

  19. Transport phenomena in a steam-methanol reforming microreactor with internal heating

    Energy Technology Data Exchange (ETDEWEB)

    Suh, Jeong-Se; Lee, Ming-Tsang; Greif, Ralph; Grigoropoulos, Costas P. [Department of Mechanical Engineering, University of California at Berkeley, Berkeley, CA 94720-1740 (United States)

    2009-01-15

    An experimental and theoretical study of steam reforming of methanol is carried out in a packed-bed microreactor with internal heating. Experimental results of the methanol conversion and carbon monoxide concentration in an internally heated reformer are compared with those of an externally heated reformer. Higher methanol conversion and carbon monoxide concentration are obtained for internal heating at the same conditions. The results show the conversion efficiency of methanol and CO concentration increase with increasing internal heating rate over the range of operating conditions. A correlation for the conversion efficiency of methanol has been obtained as a function of the internal heating rate and a dimensionless time parameter which represents the ratio of the characteristic time of the methanol flow to the time for chemical reaction. (author)

  20. Control of nuclear energy: new aims for the reform of international institutions

    Energy Technology Data Exchange (ETDEWEB)

    Johnson, B.

    1977-12-01

    Detailed negotiations over a possible package of measures to reform international safeguards and security managements under which nuclear technology is transferred are going on behind closed doors in the ''London Club,'' or Nuclear Suppliers' Group. The talks appear to be chiefly concentrated on bilateral agreements over national measures of control. The author examines some possible aims and functions that seem reasonable targets for negotiated reform over the coming months. These would include: jointly guaranteed supplies of low-enriched uranium for thermal reactors; a new international safeguards system; international nuclear security and safety standards; international agreement on nuclear waste disposal measures; international institutional initiative to promote alternative energy sources; functional reform of the IAEA; and reorganized regulatory review processes at national levels. (MCW)

  1. Fostering Home-Grown Democratic Reform | IDRC - International ...

    International Development Research Centre (IDRC) Digital Library (Canada)

    To support the political and governance-related processes taking place, the Arab Reform Initiative (ARI) has been hard at work carrying out research projects, engaging in collaborative efforts, building local capacity, conducting public opinion surveys and developing a vast network of scholars, activists and practitioners who ...

  2. The Reformed Australian Child Support Scheme: An International Policy Comment.

    Science.gov (United States)

    Harrison, Margaret

    1991-01-01

    Describes antecedents, major objectives, and characteristics of Australian child support reforms in context of their introduction into highly discretionary family law system. Draws parallels with Wisconsin Child Support Assurance System. Discusses findings of Australian Institute of Family Studies evaluation which suggests that the scheme has…

  3. International environmental governance: Lessons learned from Human Rights Institutional Reform

    Energy Technology Data Exchange (ETDEWEB)

    Fauchald, Ole Kristian

    2011-07-01

    This report focuses on the possibility of establishing a High Commissioner for the Environment and transforming the UNEP Governing Council into a Council for the Environment. For this purpose, it considers the parallels between human rights regimes and environmental regimes. It provides a short-list of functions to be covered by a reformed environmental governance regime, and discusses how the reform can be coordinated with UNEP, as well as with the current and future institutional framework for sustainable development. The report also discusses how the reform can be related to fifteen core multilateral environmental agreements. Finally, the report considers how the reform can be carried out through a discussion of five separate options: a decision by the UN General Assembly, by the ECOSOC, or by the UNEP Governing Council, as well as through agreements between conferences of parties of environmental agreements, or directly between states. A main purpose of the report, which has been commissioned by the Norwegian Ministry for the Environment, is to provide input to the preparations for the Rio+20 Conference in 2012.(auth)

  4. Thermodynamic modeling of the power plant based on the SOFC with internal steam reforming of methane

    International Nuclear Information System (INIS)

    Ivanov, Peter

    2007-01-01

    Mathematical model based on the thermodynamic modeling of gaseous mixtures is developed for SOFC with internal steam reforming of methane. Macroscopic porous-electrode theory, including non-linear kinetics and gas-phase diffusion, is used to calculate the reforming reaction and the concentration polarization. Provided the data concerning properties and costs of materials the model is fit for wide range of parametric analysis of thermodynamic cycles including SOFC

  5. The Problem of the United Nations Reforming in the Context of International Relations

    Directory of Open Access Journals (Sweden)

    N V Sepeleva

    2011-06-01

    Full Text Available In the article the author analyzes the reforming of the United Nations and its Security Council, the problems concerning globalization and consequences of the crisis. Particular attention is given to issues of international terrorism, poverty, natural calamities and transnational crime been raised in the Millennium Declaration. Considering the balance of force in the United Nations, the author points out African countries which actively participate in the process of the UN reforming.

  6. Foreign investment, international mergers and the 1993 capital income tax reform in Finland

    OpenAIRE

    Hannu Piekkola

    1995-01-01

    Foreign direct investment in Finland and the 1993 Finnish Capital Income Tax Reform are examined in this article. Under territorial taxation, the most common form of international double taxation relief; the tax reform will encourage new capital investment. New capital investment from the US, which applies worldwide taxation, would be mildly discouraged, and FDI in the form of mergers and acquisitions largely discouraged. In the UK and Japan, the worldwide principle only covers tax rates. Thu...

  7. Public Benefits and Power Sector Reform. Report from an International Workshop

    Energy Technology Data Exchange (ETDEWEB)

    Nilsson, Lars J.; Arvidson, Anders; Eberhard, Anton (eds.)

    2003-10-01

    -offs between potentially conflicting objectives should not be underestimated. However, if reforms are framed around broader development goals priorities will be more explicit, and better informed trade-offs can be made. Perceived conflicts may be removed in the process. Training and capacity building are key approaches to advancing public benefits. Training needs are changing and more specialised training, by topic or country, is needed as reforms evolve. In addition, the target audience should be extended to include a broader range of stakeholders than energy ministries and regulators alone. The international donor community has a specific responsibility to enhance its own capacity in this area as well as to support training and capacity building in order to advance public benefits. Research based analysis and knowledge should be developed and used in training and capacity building, ultimately contributing to shaping policy.

  8. Public Benefits and Power Sector Reform. Report from an International Workshop

    International Nuclear Information System (INIS)

    Nilsson, Lars J.; Arvidson, Anders; Eberhard, Anton

    2003-10-01

    -offs between potentially conflicting objectives should not be underestimated. However, if reforms are framed around broader development goals priorities will be more explicit, and better informed trade-offs can be made. Perceived conflicts may be removed in the process. Training and capacity building are key approaches to advancing public benefits. Training needs are changing and more specialised training, by topic or country, is needed as reforms evolve. In addition, the target audience should be extended to include a broader range of stakeholders than energy ministries and regulators alone. The international donor community has a specific responsibility to enhance its own capacity in this area as well as to support training and capacity building in order to advance public benefits. Research based analysis and knowledge should be developed and used in training and capacity building, ultimately contributing to shaping policy

  9. United Nations Reform: U.S. Policy and International Perspectives

    Science.gov (United States)

    2009-12-15

    and Social Council ( ECOSOC ) to account for growing U.N. membership.1 In the 1970s, as the economic and political gap between developed and developing...U.N. organs, including the Security Council, General Assembly and ECOSOC ,82 and it also attaches particular importance to the implementation of the...www.europa-eu-un.org/articles/ en/article_6242_en.htm. 82 An October 25, 2005 EU paper on ECOSOC reform is available at http://www.europa-eu-un.org

  10. Performance evaluation of a proof-of-concept 70 W internal reforming methanol fuel cell system

    Science.gov (United States)

    Avgouropoulos, G.; Schlicker, S.; Schelhaas, K.-P.; Papavasiliou, J.; Papadimitriou, K. D.; Theodorakopoulou, E.; Gourdoupi, N.; Machocki, A.; Ioannides, T.; Kallitsis, J. K.; Kolb, G.; Neophytides, S.

    2016-03-01

    A proof-of-concept 70 W Internal Reforming Methanol Fuel Cell (IRMFC) stack including Balance-of-Plant (BoP) was designed, assembled and tested. Advent TPS® high-temperature, polymer electrolyte membrane electrode assemblies were employed for fuel cell operation at 200 °C. In order to avoid phosphoric acid poisoning of the reformer, the anode electrocatalyst of each cell was indirectly adjoined, via a separation plate, to a highly active CuMnAlOx catalyst coated onto copper foam, which served as methanol reforming layer. The reformer was in-situ converting the methanol/steam feed to the required hydrogen (internal reforming concept) at 200 °C, which was readily oxidized at the anode electrodes. The operation of the IRMFC was supported through a number of BoP components consisting of a start-up subsystem (air blower, evaporator and monolithic burner), a combined afterburner/evaporator device, methanol/water supply and data acquisition units (reactants/products analysis, temperature control, flow control, system load/output control). Depending on the composition of the liquid MeOH/H2O feed streams, current densities up to 0.18 A cm-2 and power output up to 70 W could be obtained with remarkable repeatability. Specific targets for improvement of the efficiency were identified.

  11. The International Relations Academy and the United Nations System Reform: the case of Brazil

    Directory of Open Access Journals (Sweden)

    Luciana Rezende Campos Oliveira

    2016-12-01

    Full Text Available This article presents how International Relations Academy approaches theUnited Nations System and its reform through the analysis of publications in the field. Were identified both worldwide tendencies, such as the influence of Realism and of security-related themes, and local ones, such as the influence of Brazilian foreign policy in national publications on the matter.

  12. Roles for international military medical services in stability operations (security sector reform).

    Science.gov (United States)

    Bricknell, M C M; Thompson, D

    2007-06-01

    This is the second in a series of three papers that examine the role of international military medical services in stability operations in unstable countries. The paper discusses security sector reform in general terms and highlights the interdependency of the armed forces, police, judiciary and penal systems in creating a 'secure environment'. The paper then looks at components of a local military medical system for a counter-insurgency campaign operating on interior lines and the contribution and challenges faced by the international military medical community in supporting the development of this system. Finally the paper highlights the importance of planning the medical support of the international military personnel who will be supporting wider aspects of security sector reform. The paper is based on background research and my personal experience as Medical Director in the Headquarters of the NATO International Stability Assistance Force in Afghanistan in 2006.

  13. Revisiting Bretton woods: Proposals for reforming the international monetary institutions

    OpenAIRE

    Mikesell, Raymond F.

    1996-01-01

    Raymond F. Mikesell outlines the activities of the International Monetary Fund (IMF) and the World Bank over the course of their history and evaluates the organizations' success in meeting their original and subsequent goals. He analyzes the debate over the IMF's role in managing the international monetary system, managing currency crises, and providing credit to newly capitalist countries and examines proposals that the World Bank do more to promote private investment in developing countries...

  14. Assessing the Effects of the 2003 Resident Duty Hours Reform on Internal Medicine Board Scores

    Science.gov (United States)

    Romano, Patrick S.; Itani, Kamal M.F.; Rosen, Amy K.; Small, Dylan; Lipner, Rebecca S.; Bosk, Charles L.; Wang, Yanli; Halenar, Michael J.; Korovaichuk, Sophia; Even-Shoshan, Orit; Volpp, Kevin G.

    2014-01-01

    Purpose To determine whether the 2003 Accreditation Council for Graduate Medical Education (ACGME) duty hours reform affected medical knowledge as reflected by written board scores for internal medicine (IM) residents. Method The authors conducted a retrospective cohort analysis of postgraduate year 1 (PGY-1) Internal Medicine residents who started training before and after the 2003 duty hour reform using a merged data set of American Board of Internal Medicine (ABIM) Board examination and the National Board of Medical Examiners (NMBE) United States Medical Licensing Examination (USMLE) Step 2 Clinical Knowledge test scores. Specifically, using four regression models, the authors compared IM residents beginning PGY-1 training in 2000 and completing training unexposed to the 2003 duty hours reform (PGY-1 2000 cohort, n = 5,475) to PGY-1 cohorts starting in 2001 through 2005 (n = 28,008), all with some exposure to the reform. Results The mean ABIM board score for the unexposed PGY-1 2000 cohort (n = 5,475) was 491, SD = 85. Adjusting for demographics, program, and USMLE Step 2 exam score, the mean differences (95% CI) in ABIM board scores between the PGY-1 2001, 2002, 2003, 2004 and 2005 cohorts minus the PGY-1 2000 cohort were −5.43 (−7.63, −3.23), −3.44 (−5.65, −1.24), 2.58 (0.36, 4.79), 11.10 (8.88, 13.33) and 11.28 (8.98, 13.58) points respectively. None of these differences exceeded one-fifth of an SD in ABIM board scores. Conclusions The duty hours reforms of 2003 did not meaningfully affect medical knowledge as measured by scores on the ABIM board examinations. PMID:24556772

  15. An Assessment of Molten Metal Detachment Hazards During Electron Beam Welding in the Space Shuttle Bay at LEO for the International Space Welding Experiment

    Science.gov (United States)

    Fragomeni, James M.

    1996-01-01

    In 1997, the United States [NASA] and the Paton Electric Welding Institute are scheduled to cooperate in a flight demonstration on the U.S. Space Shuttle to demonstrate the feasibility of welding in space for a possible repair option for the International Space Station Alpha. This endeavor, known as the International Space Welding Experiment (ISWE), will involve astronauts performing various welding exercises such as brazing, cutting, welding, and coating using an electron beam space welding system that was developed by the E.O. Paton Electric Welding Institute (PWI), Kiev Ukraine. This electron beam welding system known as the "Universal Weld System" consists of hand tools capable of brazing, cutting, autogeneous welding, and coating using an 8 kV (8000 volts) electron beam. The electron beam hand tools have also been developed by the Paton Welding Institute with greater capabilities than the original hand tool, including filler wire feeding, to be used with the Universal Weld System on the U.S. Space Shuttle Bay as part of ISWE. The hand tool(s) known as the Ukrainian Universal Hand [Electron Beam Welding] Tool (UHT) will be utilized for the ISWE Space Shuttle flight welding exercises to perform welding on various metal alloy samples. A total of 61 metal alloy samples, which include 304 stainless steel, Ti-6AI-4V, 2219 aluminum, and 5456 aluminum alloys, have been provided by NASA for the ISWE electron beam welding exercises using the UHT. These samples were chosen to replicate both the U.S. and Russian module materials. The ISWE requires extravehicular activity (EVA) of two astronauts to perform the space shuttle electron beam welding operations of the 61 alloy samples. This study was undertaken to determine if a hazard could exist with ISWE during the electron beam welding exercises in the Space Shuttle Bay using the Ukrainian Universal Weld System with the UHT. The safety issue has been raised with regard to molten metal detachments as a result of several

  16. Energy efficiency of a direct-injection internal combustion engine with high-pressure methanol steam reforming

    International Nuclear Information System (INIS)

    Poran, Arnon; Tartakovsky, Leonid

    2015-01-01

    This article discusses the concept of a direct-injection ICE (internal combustion engine) with thermo-chemical recuperation realized through SRM (steam reforming of methanol). It is shown that the energy required to compress the reformate gas prior to its injection into the cylinder is substantial and has to be accounted for. Results of the analysis prove that the method of reformate direct-injection is unviable when the reforming is carried-out under atmospheric pressure. To reduce the energy penalty resulted from the gas compression, it is suggested to implement a high-pressure reforming process. Effects of the injection timing and the injector's flow area on the ICE-SRM system's fuel conversion efficiency are studied. The significance of cooling the reforming products prior to their injection into the engine-cylinder is demonstrated. We show that a direct-injection ICE with high-pressure SRM is feasible and provides a potential for significant efficiency improvement. Development of injectors with greater flow area shall contribute to further efficiency improvements. - Highlights: • Energy needed to compress the reformate is substantial and has to be accounted for. • Reformate direct-injection is unviable if reforming is done at atmospheric pressure. • Direct-injection engine with high-pressure methanol reforming is feasible. • Efficiency improvement by 12–14% compared with a gasoline-fed engine was shown

  17. Internal steam reforming in solid oxide fuel cells: Status and opportunities of kinetic studies and their impact on modelling

    DEFF Research Database (Denmark)

    Mogensen, David; Grunwaldt, J.-D.; Hendriksen, Peter Vang

    2011-01-01

    of such a system require SOFC models that include accurate description of the steam reforming rate. The objective of this article is to review the reported kinetic expressions for the steam reforming reaction. Extensive work has been performed on traditional catalysts for steam reforming. Because of differences...... modeling, such expression are however lacking, but it may be viable to use measurements on industrial steam reforming catalysts instead. Nevertheless there is a further need for experimental studies on determining the exact steam reforming kinetics for SOFC anodes.......Solid oxide fuel cells (SOFC) systems with internal steam reforming have the potential to become an economically competitive technology for cogeneration power plants, exploiting its significantly higher electrical efficiency compared to existing technologies. Optimal design and operation...

  18. Direct internal steam reforming of ethanol in a solid oxide fuel cell (SOFC) - A thermodynamic analysis

    International Nuclear Information System (INIS)

    Lima da Silva, Aline; De Fraga Malfatti, Celia; Heck, Nestor Cesar; Melo Halmenschlager, Cibele

    2003-01-01

    Among the various types of fuel cells, the solid oxide fuel cell (SOFC) has attracted considerable interest due to the possibility for operation with an internal reformer and higher system efficiency. In SOFC, high operative temperature allows the direct conversion of ethanol into H 2 and CO to take place in the electrochemical cell. Ethanol is considered to be an attractive fuel because it is a renewable energy source and presents some advantages over other green fuels such as safety in storage and handling. Direct internal reforming of ethanol, however, can produce undesirable products that diminish system efficiency and, in the case of carbon deposition over the anode, promote the growth of carbon filaments attached to the anode crystallites which generate massive forces within the electrode structure leading to its rapid breakdown. In this context, a thermodynamic analysis is fundamental to predict the product distribution as well as the conditions favorable for carbon to precipitate inside the cell. Despite of such importance, there are few works in literature dealing with thermodynamic analysis of the direct internal steam reforming of ethanol in fuel cell systems. Hence, the aim of this work is to find appropriate ranges for operating conditions where carbon deposition in SOFC with direct internal reforming operation is not feasible, in temperature range of 500- 1200K. The calculation here is more complicated than that for a reformer because the disappearance of hydrogen and the generation of H 2 O from electrochemical reaction must be taken into account. In the present study, the effects of hydrogen consumption on anode components and on carbon formation are investigated. Equilibrium determinations are performed by the Gibbs energy minimization method, considering the following species: H 2 , H 2 O, CH 4 , CO, CO 2 and C gr . (graphite). The effect of the type of solid electrolyte (oxygen-conducting and hydrogen-conducting) on carbon formation is also

  19. GP-income development in relation to recent health care reforms: an international comparison.

    NARCIS (Netherlands)

    Kroneman, M.; Zee, J. van der

    2011-01-01

    Background: Health care reforms have been introduced in several European countries in the past decade. In most countries, these reforms had (intended and unintended) consequences for the remuneration and incomes of GPs. The reforms can be grouped into two types: incremental reforms and reforms that

  20. Reform by subtraction: the path of denunciation of international drug treaties and reaccession with reservations.

    Science.gov (United States)

    Room, Robin

    2012-09-01

    Almost all countries are parties to the international drug conventions of 1961, 1971 and 1988. These strongly bind parties with respect to their domestic regulation of controlled substances, including requirements that possession, growing or use be a criminal offense and that any regulated market in the substances be limited to use only for medical or scientific purposes. Even where countries have argued they have "wiggle room", reform within the bounds of the conventions has often resulted in "net-widening" which nullifies the intent of the reform. Among the options for effective reform, probably the most immediately viable is the route of denunciation and reaccession with reservations--the route which Bolivia has now taken in order to legalise a regulated domestic market in coca leaves for chewing. The paper considers the existing record of reservations (by more than 30 parties to each of the conventions). Also discussed are the options for response to the reservations by other parties, which vary between the treaties, and how pursuing the option of denunciation and reaccession with reservation might potentially play out. Copyright © 2012 Elsevier B.V. All rights reserved.

  1. International coalitions in Brazil’s foreign policy: security and governance reform

    Directory of Open Access Journals (Sweden)

    Alcides Costa Vaz

    2012-04-01

    Full Text Available The text analyses the relevance and role of international coalitions as instruments and arenas for negotiation in the context of Brazilian foreign policy under Luis Inácio Lula da Silva (2003-2010, and the perspectives they bring to the attainment of the goal of reforming the spaces and instruments of global governance in the political, economic and security spheres. Under Lula da Silva, Brazil supported and resorted intensively to coalitions not only for their instrumental value for consolidating the country’s international presence and actions, but also due to the possibility that they could induce systemic change towards a more uneven pattern of power distribution, thus helping to overcome lasting political and economic international asymmetries.

  2. Reforming the Belgian market for orthotic braces: what can we learn from the international experience?

    Science.gov (United States)

    Simoens, Steven; De Coster, Sandra; Moldenaers, Ingrid; Guillaume, Paul; Depoorter, Antony; Van den Steen, Dirk; Van de Sande, Stefaan; Debruyne, Hans; Ramaekers, Dirk; Lona, Murielle

    2008-05-01

    This article aims to review regulation governing outpatient orthotic braces (neck, wrist and knee braces) in France, the Netherlands and Sweden with a view to reforming the Belgian market. Information about the regulatory framework was derived from an analysis of legal texts and a survey completed by national experts. Strategies to keep down prices include public procurement in Sweden, maximum prices in France, and exclusion of expensive braces from reimbursement in the Netherlands. Reimbursement is linked to a medical indication or a chronic condition in France, the Netherlands and Sweden. To gain reimbursement, the cost-effectiveness of orthotic braces needs to be demonstrated in France and the Netherlands. Orthotic braces tend to be initially prescribed by a specialist physician and distributed by orthotists, medical equipment shops and/or community pharmacies. Extensive government intervention exists in the outpatient orthotic brace market in the countries studied. Our recommendations to reform the Belgian market for prefabricated orthotic braces are to separate reimbursement for service provision from reimbursement for braces; to set prices by means of a tendering process or an international price comparison; and to make reimbursement conditional on effectiveness and cost-effectiveness of braces.

  3. International Institutions and Domestic Reform: Equal Pay and British Membership in the European Economic Community.

    Science.gov (United States)

    Frader, Laura Levine

    2018-03-01

    Despite having been overlooked in the standard histories of the UK and the European Community, gender politics and gender policies played a significant role in Britain's applications for membership in the EEC in the 1960s. Joining the European Community required that Britain comply with Article 119 on equal pay for equal work. A combination of domestic feminist and labour movement activism, the commitment of unions and parties, and the internationalization of formal commitments to women's rights constituted internal and external pressures for the passage of an Equal Pay Act in 1970. The article argues that the formal legislative commitment to gender pay equality, changing public attitudes towards women's employment, and European membership impacted further domestic social policy reform and slowly began to shift government attitudes towards gender equality.

  4. Methanol steam reforming via internal recycle reactor. Paper no. IGEC-1-144

    International Nuclear Information System (INIS)

    Qi, A.; Amphlett, J.C.; Thurgood, C.P.; Peppley, B.A.

    2005-01-01

    Hydrogen generation for PEMFC by methanol steam reforming using a Caldwell internal recycle reactor (IRR) was studied. BASF K3-110 copper-based catalyst was used. The impeller speed and methanol retention time almost proportionally affected the recycle ratio, one of the most direct and important indices to show the gradientlessness of concentration and temperature. When the recycle ratio was greater than 20, internal recycle reactor could be considered as continuously stirred tank reactor (CSTR), one ideal reactor for kinetics studies with no appreciable concentration and temperature gradients. The experiment results via CSTR fit very well with the kinetics model developed using a differential reactor by Peppley et al.. This verified the accuracy of the Peppley model and vice versa. The pseudo first order reaction rate constant developed in the CSTR was found to be 0.1-0.15 mol/bar.kg.s, and the activation energy was 93 kJ/mol, which were in good accordance with Peppley model and other values reported in the literature. However, when the recycle ratio was too low, less than 20 for instance, either because of the high GHSV of reactants or low impeller speed, methanol conversion rate as well as CO 2 , H 2 production rates were well below the values predicted by the Peppley model due to the existence of strong gradients of concentration and temperature. Regardless of the recycle ratio, CO producing rate in the IRR was lower than that via the plug flow reactor (PFR) in terms of Peppley model, which could be presumably ascribed to the strong inhibition effect of hydrogen on the reaction rate of methanol decomposition and reverse water gas shift (WGS) reaction over Cu based catalyst. This characteristic could be of benefit in reactor design to suppress CO yield which will be beneficial for producing PEMFC-grade reformate. (author)

  5. Thermodynamic analysis of direct internal reforming of methane and butane in proton and oxygen conducting fuel cells

    NARCIS (Netherlands)

    Biesheuvel, P.M.; Geerlings, J.J.C.

    2008-01-01

    We present results of a thermodynamic analysis of direct internal reforming fuel cells, based on either a proton conducting fuel cell (FC-H+) or an oxygen ion conducting fuel cell (FC-O2-). We analyze the option of methane as fuel as well as butane. The model self-consistently combines all chemical

  6. Medical education reform in wuhan university, china: a preliminary report of an international collaboration.

    Science.gov (United States)

    Sherer, Renslow; Dong, Hongmei; Yunfeng, Zhou; Stern, Scott; Jiong, Yang; Matlin, Karl; Baoping, Yu; Husain, Aliya N; Morgan, Ivy; Cooper, Brian; Juan, Feng; Mehta, Sujata

    2013-01-01

    In 2008 Wuhan University Medical School in China proposed to reform its curriculum by adapting the curriculum of the University of Chicago Medical School. An assessment of Wuhan University Medical School's traditional curriculum conducted in 2009 informed the reform directions, which included course integration, use of clinical cases, improved relevance of basic sciences to clinical medicine, reduction of lecture time, increase in group and independent learning, and the use of formative assessments. Fifty student volunteers per year were chosen to participate in the reform, and the rest remained in the traditional curriculum. A student survey was conducted in 2011 to evaluate the reform by comparing the attitudes of those in the reform and standard curricula. The reform met the needs of the school, was generally well received, improved satisfaction in reform participants, and had a positive impact on students. Areas needing improvement were also identified.

  7. Rethinking 'flexibilities' in the international drug control system-Potential, precedents and models for reforms.

    Science.gov (United States)

    Collins, John

    2017-01-24

    Much international drug policy debate centres on, what policies are permissible under the international drug treaties, whether member states are openly 'breaching' these treaties by changing national regulatory frameworks and shifting priorities away from a 'war on drugs' approach, and what 'flexibility' exists for policy reform and experimentation at national and local levels. Orthodox interpretations hold that the current system is a US-led 'prohibition regime' that was constructed in an extremely repressive and restrictive manner with almost no flexibility for significant national deviations. This paper challenges these orthodox interpretive frameworks and suggests no absolute and clear dichotomy between strict adherence and 'breaches' of the international treaties. This paper uses historical analysis to highlight the flaws in orthodox policy analyses, which assume a uniform interpretation, implementation and set of policy trajectories towards a 'prohibition regime' in the 20th century. It challenges some existing legal interpretations of the treaties through recourse to historical precedents of flexible interpretation and policy prioritisation. It then examines the legal justifications currently being formulated by member states to explain a shift towards policies which, until recently, have been viewed as outside the permissible scope of the conventions. It then examines a functionalist framework for understanding the likely contours of drug diplomacy in the post-UN General Assembly Special Session (UNGASS) 2016 era. The paper highlights that, contrary to current policy discourses, the international control system has always been implemented in a 'flexible' manner. It demonstrates that drug control goals were repeatedly subsumed to security, development, political stability and population welfare imperatives, or what we might now refer to under the umbrella of 'development issues.' The paper further demonstrates that policy prioritisation, inherent treaty

  8. Emerging markets and the international financial architecture: a blueprint for reform

    Directory of Open Access Journals (Sweden)

    JAN KREGEL

    2015-06-01

    Full Text Available If emerging markets are to achieve their objective of joining the ranks of industrialized, developed countries, they must use their economic and political influence to support radical change in the international financial system. This working paper recommends John Maynard Keynes's "clearing union" as a blueprint for reform of the international financial architecture that could address emerging market grievances more effectively than current approaches. Keynes's proposal for the postwar international system sought to remedy some of the same problems currently facing emerging market economies. It was based on the idea that financial stability was predicated on a balance between imports and exports over time, with any divergence from balance providing automatic financing of the debit countries by the creditor countries via a global clearinghouse or settlement system for trade and payments on current account. This eliminated national currency payments for imports and exports; countries received credits or debits in a notional unit of account fixed to national currency. Since the unit of account could not be traded, bought, or sold, it would not be an international reserve currency. The credits with the clearinghouse could only be used to offset debits by buying imports, and if not used for this purpose they would eventually be extinguished; hence the burden of adjustment would be shared equally - credit generated by surpluses would have to be used to buy imports from the countries with debit balances. Emerging market economies could improve upon current schemes for regionally governed financial institutions by using this proposal as a template for the creation of regional clearing unions using a notional unit of account.

  9. English language examination reform: International trends and a framework for Nepal

    OpenAIRE

    Shrestha, Prithvi

    2018-01-01

    This chapter is based on desk research on examinations and their reforms globally. Although the chapter is about English language examination reforms, it draws on the literature related to general education where relevant. The chapter begins by exploring why governments reform school examinations. In particular, the chapter focuses on the external environment: political, educational and economic factors which influence the nature of school examinations in different ways (Shohamy, 2007). These...

  10. Electrochemical fuel cell generator having an internal and leak tight hydrocarbon fuel reformer

    Science.gov (United States)

    Dederer, Jeffrey T.; Hager, Charles A.

    1998-01-01

    An electrochemical fuel cell generator configuration is made having a generator section which contains a plurality of axially elongated fuel cells, each cell containing a fuel electrode, air electrode, and solid oxide electrolyte between the electrodes, in which axially elongated dividers separate portions of the fuel cells from each other, and where at least one divider also reforms a reformable fuel gas mixture prior to electricity generation reactions, the at least one reformer-divider is hollow having a closed end and an open end entrance for a reformable fuel mixture to pass to the closed end of the divider and then reverse flow and pass back along the hollowed walls to be reformed, and then finally to pass as reformed fuel out of the open end of the divider to contact the fuel cells, and further where the reformer-divider is a composite structure having a gas diffusion barrier of metallic foil surrounding the external walls of the reformer-divider except at the entrance to prevent diffusion of the reformable gas mixture through the divider, and further housed in an outer insulating jacket except at the entrance to prevent short-circuiting of the fuel cells by the gas diffusion barrier.

  11. The electricity industry: international development reform and regulation. Sviluppo internazionale, riforma e regolamentazione dell'industria elettrica

    Energy Technology Data Exchange (ETDEWEB)

    Gulli' , F. (Milan, Univ. Bocconi (Italy). Istituto di Economia delle Fonti di Energia)

    1998-01-01

    This article aims at analysing the relation between reform and internationalization processes of the electricity industry. The analysis focuses on the data concerning the leading european and US utilities. It comes out an interesting result: market organization urges the electric firms to start huge foreign investment programmes, by acquiring existing utilities (distribution companies) or investing in individual power plants (independent power production). In fact the companies involved in the international business are mainly from competitive markets or from countries in which a structural reform is expected. Another interesting result is the importance of the regulation. The companies more involved in the international business are from markets in which price regulation is particularly severe. Finally, the impact of the internationalisation is analysed, with emphasis on the internal firm organization and market structure.

  12. Development of a coal-fueled Internal Manifold Heat Exchanger (IMHEX reg sign ) molten carbonate fuel cell

    Energy Technology Data Exchange (ETDEWEB)

    1991-09-01

    The design of a CGMCFC electric generation plant that will provide a cost of eletricity (COE) which is lower than that of current electric generation technologies and which is competitive with other long-range electric generating systems is presented. This effort is based upon the Internal Manifold Heat Exchanger (IMHEX) technology as developed by the Institute of Gas Technology (IGT). The project was executed by selecting economic and performance objectives for alternative plant arrangements while considering process constraints identified during IMHEX fuel cell development activities at ICT. The four major subsystems of a coal-based MCFC power plant are coal gasification, gas purification, fuel cell power generation and the bottoming cycle. The design and method of operation of each subsystem can be varied, and, depending upon design choices, can have major impact on both the design of other subsystems and the resulting cost of electricity. The challenge of this project was to select, from a range of design parameters, those operating conditions that result in a preferred plant design. Computer modelling was thus used to perform sensitivity analyses of as many system variables as program resources and schedules would permit. In any systems analysis, it is imperative that the evaluation methodology be verifiable and comparable. The TAG Class I develops comparable (if imprecise) data on performance and costs for the alternative cases being studied. It identifies, from a range of options, those which merit more exacting scrutiny to be undertaken at the second level, TAG class II analysis.

  13. Gases in molten salts

    CERN Document Server

    Tomkins, RPT

    1991-01-01

    This volume contains tabulated collections and critical evaluations of original data for the solubility of gases in molten salts, gathered from chemical literature through to the end of 1989. Within the volume, material is arranged according to the individual gas. The gases include hydrogen halides, inert gases, oxygen, nitrogen, hydrogen, carbon dioxide, water vapor and halogens. The molten salts consist of single salts, binary mixtures and multicomponent systems. Included also, is a special section on the solubility of gases in molten silicate systems, focussing on slags and fluxes.

  14. Drawing on international experience to reform the Belgian market for ostomy appliances.

    Science.gov (United States)

    Simoens, Steven; Van den Steen, Dirk; Vanleene, Veerle; De Maré, Luc; Moldenaers, Ingrid; Debruyne, Hans; Ramaekers, Dirk

    2007-02-01

    This article aims to review the regulatory framework governing the Belgian ostomy appliance market in the light of the experience of Denmark, France, the Netherlands and Ontario (Canada) with regulation of ostomy appliances. Information about the regulatory framework was derived from the international literature, analysis of legal texts and a survey completed by national experts. The comparative analysis revealed that these countries have adopted varying approaches towards regulating their domestic ostomy appliance market. Strategies to keep down prices include public procurement in Denmark, maximum prices in France and exclusion of expensive appliances from reimbursement in the Netherlands. To contain public expenditure on ostomy appliances, consumption patterns are monitored in the Netherlands, the quantity of reimbursed appliances is limited in Belgium and public reimbursement is restricted in Ontario. Ostomy appliances are generally distributed by community pharmacies and medical equipment shops. In countries that emphasise home care delivery such as Denmark, domiciliary distributors dominate the market to the detriment of community pharmacies which do not seem to be able to offer this service at a competitive price. An avenue for reforming the Belgian ostomy appliance market is proposed which valorizes the role of ostomy care nurses in guiding the choice of ostomy appliances. Furthermore, it is recommended that a competitive tendering process determines the price of ostomy appliances, that reimbursement for service provision by distributors is separated from reimbursement of appliances, and that patients receive a fixed grant from the third-party payer to buy ostomy appliances.

  15. Parliamentary Reform

    OpenAIRE

    Norton, Philip

    2016-01-01

    The key concept of any study of the role of Parliament focuses on the extent to which it is able to influence and constrain the Executive. Reforming Parliament should seek to strengthen its capacity to do so. A clear distinction ought to be drawn between external and internal reforms of the Parliamentary system. While the former strive to achieve the desired goal through changes in the constitutional framework – e.g. the reform of the House of Lords – the latter aim to improve the working of ...

  16. Commercial Law Reform in territories subject to International Administration. Kosovo & Iraq. Different standards of legitimacy and accountability?

    Directory of Open Access Journals (Sweden)

    Alejandro Carballo Leyda

    2008-01-01

    Full Text Available The paper will address questions of legality and accountability of the legislative functions exerted by international territorial administrations1 in the field of commercial law in two recent scenarios that are theoretically different: a UN-authorized mission under Chapter VII of the UN Chart and that of a strictly Occupying Power. No attempt will be made to study other important and interrelated issues, such as the problematic privatizations carried out in Kosovo and Iraq, which do not seem to be compatible with the obligation of administration of public assets (Art. 55 of the 1907 Hague Regulations.This paper will first provide a brief overview of the deep economic legislative reformation that took place in Iraq and Kosovo during the very early stages. Most of the scholar literature focused on criminal law and human rights aspects, leaving aside commercial law reforms; yet, those profound commercial reforms have resulted in a drastic economic transformation from a planned, centrally controlled, socialist system into a liberal, marketoriented, capitalist economy. The radical nature of those changes raises the question of their conformity with relevant international law and the need for public accountability.Part III will then explore the sources of legality invoked so far (namely UN Mandates, International Humanitarian Law, and authority invested by local intervention by the academic world, experts and intervening actors as basis for the commercial reformation in Kosovo and Iraq, and whether the actual results comply with the discretion vested in the temporal administrations by those sources. Finally, in Part IV problems of judicial review and public accountability in relation to the law-making function of those international administrations in Iraq and Kosovo will be considered.

  17. International trade and carbon emissions: The role of Chinese institutional and policy reforms.

    Science.gov (United States)

    Andersson, Fredrik N G

    2018-01-01

    The carbon dioxide embodied in Chinese exports to developed countries increased rapidly from 1995 to 2008. We test the extent to which institutional reforms in China can explain this increase. We focus on five areas of reforms: trade liberalization, environmental institutions, legal and property rights, institutional risk and exchange rate policy. Our results show that trade liberalization, weak environmental institutions, exchange rate policy, and legal and property rights affect emissions. Our results also indicate that the lack of reform in the utilities sector is an important factor in the rapid increase in embodied emissions. Copyright © 2017 Elsevier Ltd. All rights reserved.

  18. Molten salts and nuclear energy production

    Science.gov (United States)

    Le Brun, Christian

    2007-01-01

    Molten salts (fluorides or chlorides) were considered near the beginning of research into nuclear energy production. This was initially due to their advantageous physical and chemical properties: good heat transfer capacity, radiation insensitivity, high boiling point, wide range solubility for actinides. In addition it was realised that molten salts could be used in numerous situations: high temperature heat transfer, core coolants with solid fuels, liquid fuel in a molten salt reactor, solvents for spent nuclear solid fuel in the case of pyro-reprocessing and coolant and tritium production in the case of fusion. Molten salt reactors, one of the six innovative concepts chosen by the Generation IV international forum, are particularly interesting for use as either waste incinerators or thorium cycle systems. As the neutron balance in the thorium cycle is very tight, the possibility to perform online extraction of some fission product poisons from the salt is very attractive. In this article the most important questions that must be addressed to demonstrate the feasibility of molten salt reactor will be reviewed.

  19. International experience of the civil service performance and possible ways of its application in Ukraine in terms of administration reform

    Directory of Open Access Journals (Sweden)

    Y. Y. Kizilov

    2016-07-01

    Full Text Available In the most countries the deep modernization and reforming of civil service were launched in 70­80 years of the past century and now these processes have given good results. Therefore, it will be useful to adopt a foreign experience on reforming and civil service performance with the aim to determine effective components of civil service performance in Ukraine. The analysis shows that the process of the civil service reforming and development, improving of the performing process are characterized in the world practice as the continental and Anglo­Saxon models, but despite of this most countries have a mixed model of civil service. For modernization of the civil service and approximation to the most preferable type of management in Europe were developed different models, which named «new public administration». In the article the international experience of France, Germany, Great Britain, USA, Japan and other countries on civil service performance in terms of administrative reform was analyzed. It was founded that experience of these countries is very valuable for the development of civil service institute in Ukraine, in particular civil service performance, because these countries made an economic progress and ensured sustainable development. The generalization of the international experience on civil service performance allowed to systemize the development of civil service performance institute in the democratic countries, namely: development of the reform programme and civil service modernization and adoption of new legislation on civil service; optimization and creation new organizational entities in the civil service system; existing of the special institutes of the civil service management; gradual staff reduction of state apparatus; creation of the institute of senior leadership; application of the management methods by the example of private sector; staff rotation; existing of ethic code; ensuring of lifelong education for civil

  20. Large molten pool heat transfer

    International Nuclear Information System (INIS)

    1994-01-01

    This workshop on large molten pool heat transfer is composed of 5 sessions which titles are: feasibility of in-vessel core debris cooling; experiments on molten pool heat transfer; calculational efforts on molten pool convection; heat transfer to the surrounding water, experimental techniques; future experiments and ex-vessel studies (RASPLAV, TOLBIAC, BALI, SULTAN, CORVIS, VULCANO, CORINE programs)

  1. Challenges Related to the Use of Liquid Metal and Molten Salt Coolants in Advanced Reactors. Report of the collaborative project COOL of the International Project on Innovative Nuclear Reactors and Fuel Cycles (INPRO)

    International Nuclear Information System (INIS)

    2013-05-01

    The International Project on Innovative Nuclear Reactors and Fuel Cycles (INPRO) was launched in 2000, based on a resolution by the IAEA General Conference (GC(44)/RES/21). INPRO aims at helping to ensure that nuclear energy is available in the twenty-first century in a sustainable manner, and seeks to bring together all interested Member States, both technology holders and technology users, to jointly consider actions to achieve desired innovations. INPRO is taking care of the specific needs of developing countries. One of the aims of INPRO is to develop options for enhanced sustainability through promotion of technical and institutional innovations in nuclear energy technology through collaborative projects among IAEA Member States. Collaboration among INPRO members is fostered on selected innovative nuclear technologies to bridge technology gaps. Collaborative projects have been selected so that they complement other national and international R and D activities. The INPRO Collaborative Project COOL on Investigation of Technological Challenges Related to the Removal of Heat by Liquid Metal and Molten Salt Coolants from Reactor Cores Operating at High Temperatures investigated the technological challenges of cooling reactor cores that operate at high temperatures in advanced fast reactors, high temperature reactors and accelerator driven systems by using liquid metals and molten salts as coolants. The project was initiated in 2008 and was led by India; experts from Brazil, China, Germany, India, Italy and the Republic of Korea participated and provided chapters of this report. The INPRO Collaborative Project COOL addressed the following fields of research regarding liquid metal and molten salt coolants: (i) survey of thermophysical properties; (ii) experimental investigations and computational fluid dynamics studies on thermohydraulics, specifically pressure drop and heat transfer under different operating conditions; (iii) monitoring and control of coolant

  2. International Comparison of the Influence of Educational Reform on Superintendent Leadership

    Science.gov (United States)

    Björk, Lars G.; Johansson, Olof; Bredeson, Paul

    2014-01-01

    During recent decades, the rise of the global economy launched a wide array of social, economic, and political changes in nations throughout the world. Heightened concern about the quality of schools launched what is arguably the most pervasive, intense, and protracted attempts at educational reform in recent history. Examinations of the…

  3. Finding a suitable catalyst for on-board ethanol reforming using exhaust heat from an internal combustion engine

    OpenAIRE

    Casanovas Grau, Albert; Jiménez Divins, Nuria; Rejas García, Albert; Bosch Tous, Ricardo; Llorca Piqué, Jordi

    2017-01-01

    Ethanol steam reforming with pure ethanol and commercial bioethanol (S/C = 3) was carried out inside the housing of the exhaust gas pipe of a gasoline internal combustion engine (ICE) by using exhaust heat (610–620 °C). Various catalytic honeycombs loaded with potassium-promoted cobalt hydrotalcite and with ceria-based rhodium–palladium catalysts were tested under different reactant loads. The hydrogen yield obtained over the cobalt-based catalytic honeycomb at low load (F/W < 25 mLliq·gcat-1...

  4. Computer simulation on molten ionic salts

    International Nuclear Information System (INIS)

    Kawamura, K.; Okada, I.

    1978-01-01

    The extensive advances in computer technology have since made it possible to apply computer simulation to the evaluation of the macroscopic and microscopic properties of molten salts. The evaluation of the potential energy in molten salts systems is complicated by the presence of long-range energy, i.e. Coulomb energy, in contrast to simple liquids where the potential energy is easily evaluated. It has been shown, however, that no difficulties are encountered when the Ewald method is applied to the evaluation of Coulomb energy. After a number of attempts had been made to approximate the pair potential, the Huggins-Mayer potential based on ionic crystals became the most often employed. Since it is thought that the only appreciable contribution to many-body potential, not included in Huggins-Mayer potential, arises from the internal electrostatic polarization of ions in molten ionic salts, computer simulation with a provision for ion polarization has been tried recently. The computations, which are employed mainly for molten alkali halides, can provide: (1) thermodynamic data such as internal energy, internal pressure and isothermal compressibility; (2) microscopic configurational data such as radial distribution functions; (3) transport data such as the diffusion coefficient and electrical conductivity; and (4) spectroscopic data such as the intensity of inelastic scattering and the stretching frequency of simple molecules. The computed results seem to agree well with the measured results. Computer simulation can also be used to test the effectiveness of a proposed pair potential and the adequacy of postulated models of molten salts, and to obtain experimentally inaccessible data. A further application of MD computation employing the pair potential based on an ionic model to BeF 2 , ZnCl 2 and SiO 2 shows the possibility of quantitative interpretation of structures and glass transformation phenomena

  5. Telecom Reform

    DEFF Research Database (Denmark)

    and information infrastructure issues - for people in government, academia, industry and the consulting community. This book addresses the process of policy and regulatory reform in telecom that is now in its formative stage. It draws on detailed knowledge of industry development and regulatory experience......, as well as expertise in the new technologies, industries, economics, policy development, and law to present and critique the principles, policies and regulatory practices associated with telecom reform. Twenty six international experts address thirty two topics that are essential to successful telecom...

  6. In situ tailored nickel nano-catalyst layer for internal reforming hydrocarbon fueled SOFCs

    OpenAIRE

    Myung, Jaeha; Neagu, Dragos; Tham, Mark; Irvine, John Thomas Sirr

    2015-01-01

    The authors gratefully thank the Engineering and Physical Sciences Research Council (EPSRC) SuperGen Hydrogen Fuel Cells Challenges Flame SOFC Project (Grant No EP/K021036/1) for financial support Conventional Ni cermet anodes suffer from carbon deposition when they are directly used with hydrocarbon fuels due to the negative effects of pyrolysis and Boudouard reactions. In this work, the use of a non-stoichiometric perovskite, La0.8Ce0.1Ni0.4Ti0.6O3, as a reforming layer in reducing atmos...

  7. Terek Area in the Post-Reform Period (1870–1880 years: the Internal Structure and Demography

    Directory of Open Access Journals (Sweden)

    Tatyana E. Gvarliani

    2016-12-01

    Full Text Available The article discusses the internal structure and demographic processes in the Terek region in the post-reform period (1870–1880-ies. As materials there were used the archival documents of the Central state archive of the Republic of North Ossetia-Alania. In addition, there are reflected the scientific research on the topic of publishing. The methodological basis of research are the principles of historicism, objectivity and consistency, suggesting the consideration of each historical event in conjunction with other phenomena and events, taking into account the concrete historical situation and in chronological order; the freedom from addiction and a desire for maximum reliability; the study of all phenomena, events and processes as elements of a single historical process. With the beginning of the post-reform period, the economic activities and life organization of cossacks were as close to a peasant, which makes the cossacks at this time, a special group of peasants of Russia. The cossack society is gradually transformed into peasant communities with their focus on agriculture. However, the development of economic occupations was hampered by maintaining a long military service, which in new terms came to be regarded by the cossacks as a hindrance to normal life. The level of development of agriculture was constrained by low agro-technical culture and preservation, and routine equipment.

  8. Detection and removal of molten salts from molten aluminum alloys

    Energy Technology Data Exchange (ETDEWEB)

    K. Butcher; D. Smith; C. L. Lin; L. Aubrey

    1999-08-02

    Molten salts are one source of inclusions and defects in aluminum ingots and cast shapes. A selective adsorption media was used to remove these inclusions and a device for detection of molten salts was tested. This set of experiments is described and the results are presented and analyzed.

  9. Molten carbonate fuel cell

    Science.gov (United States)

    Kaun, T.D.; Smith, J.L.

    1986-07-08

    A molten electrolyte fuel cell is disclosed with an array of stacked cells and cell enclosures isolating each cell except for access to gas manifolds for the supply of fuel or oxidant gas or the removal of waste gas. The cell enclosures collectively provide an enclosure for the array and effectively avoid the problems of electrolyte migration and the previous need for compression of stack components. The fuel cell further includes an inner housing about and in cooperation with the array enclosure to provide a manifold system with isolated chambers for the supply and removal of gases. An external insulated housing about the inner housing provides thermal isolation to the cell components.

  10. Molten salt reactor concept

    International Nuclear Information System (INIS)

    Sood, D.D.

    1980-01-01

    Molten salt reactor is an advanced breeder concept which is suited for the utilization of thorium for nuclear power production. This reactor is based on the use of solutions of uranium or plutonium fluorides in LiF-BeF 2 -ThF 4 as fuel. Unlike the conventional reactors, no external coolant is used in the reactor core and the fuel salt itself is circulated through heat exchangers to transfer the fission produced heat to a secondary salt (NaF-NaBF 4 ) for steam generation. A part of the fuel stream is continuously processed to isolate 233 Pa, so that it can decay to fissile 233 U without getting converted to 234 Pa, and for the removal of neutron absorbing fission products. This on-line processing scheme makes this reactor concept to achieve a breeding ratio of 1.07 which is the highest for any thermal breeder reactor. Experimental studies at the Bhabha Atomic Research Centre, Bombay, have established the use of plutonium as fuel for this reactor. This molten salt reactor concept is described and the work conducted at the Bhabha Atomic Research Centre is summarised. (auth.)

  11. Molten salt combustion of radioactive wastes

    International Nuclear Information System (INIS)

    Grantham, L.F.; McKenzie, D.E.; Richards, W.L.; Oldenkamp, R.D.

    1976-01-01

    The Atomics International Molten Salt Combustion Process reduces the weight and volume of combustible β-γ contaminated transuranic waste by utilizing air in a molten salt medium to combust organic materials, to trap particulates, and to react chemically with any acidic gases produced during combustion. Typically, incomplete combustion products such as hydrocarbons and carbon monoxide are below detection limits (i.e., 3 ) is directly related to the sodium chloride vapor pressure of the melt; >80% of the particulate is sodium chloride. Essentially all metal oxides (combustion ash) are retained in the melt, e.g., >99.9% of the plutonium, >99.6% of the europium, and >99.9% of the ruthenium are retained in the melt. Both bench-scale radioactive and pilot scale (50 kg/hr) nonradioactive combustion tests have been completed with essentially the same results. Design of three combustors for industrial applications are underway

  12. From Punishment to Education: The International Debate on Juvenile Penal Reform before World War I

    Science.gov (United States)

    Fuchs, Eckhardt

    2015-01-01

    The article addresses international efforts at child protection, emphasizing the criminal law on juveniles before 1914, and focuses on key international organizations and their various conferences and congresses. Although there was an institutional divide between welfare in general, child protection and youth crime, the organizations covered…

  13. Research and development of molten carbonate fuel cell power generation systems. ; Development of stacks and peripheral systems. Yoyu tansan'engata nenryo denchi hatsuden system no kenkyu kaihatsu. ; Sutakku oyobi shuhen system no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    1994-02-01

    This paper reports research and development of molten carbonate fuel cell power generation systems of composite large-capacity type, variation large-capacity type, and internal reforming type. Development works on the composite large-capacity type stacks included trial fabrication of basic modules and composite large-capacity cells, development of high-performance long-life electrodes, electrolyte plates, and high corrosion resistant cell constitutive materials, heat resistant cycling tests and life tests, and development of a technology to use higher pressures in fuel cells, and a technology to cool and seal laminar cells. Development works on the variation large-capacity stacks have performed studies on electrode life extension, pressurized operation technologies, tightening methods, fabrication of thin plate processed separators, electrodes, and electrolyte plates, power generation tests on large-area cells, and cooling characteristics analysis. In order to establish an internal reforming fuel cell technology, elucidation has been given on deactivation mechanisms in internal reforming catalysts, as well as discussions on structures of internal reforming fuel cells. As stack operational researches, evaluation tests have been given on 10-kW and 100-kW class stacks. Discussions have been given on heat exchange type and two-step catalyst combustion type reformers as peripheral devices. 26 figs., 6 tabs.

  14. Improving the health of Indigenous Australians: reforms in nursing education. An opinion piece of international interest.

    Science.gov (United States)

    Turale, S; Miller, M

    2006-09-01

    This paper overviews Indigenous disadvantage in relatively wealthy Australia. It describes efforts to increase the recruitment and retention of Indigenous people in nursing and to reform nursing education to be more inclusive of Indigenous culture, health and history. Indigenous people on average die 17 years younger than non-Indigenous people and have health problems similar to those of people in some underdeveloped countries. Moreover, social injustice and human rights issues affect their health and well-being and educational opportunities. They are under-represented in the health professions, including nursing, often through a lack of educational preparation and historical, socio-economic and cultural factors hindering them from entering and succeeding in university studies. In 2000, a project was funded by the Australian commonwealth government and led by the Indigenous Nursing Education Working Group. This Group worked for five years on a wide range of methods that included consultation within the profession, information dissemination and longitudinal surveying of university schools of nursing and Indigenous support units. Findings show that collaborative efforts between key stakeholders in nursing education appear to be succeeding to increase the numbers of Indigenous students of nursing. Around two-thirds of schools of nursing now include Indigenous content in their undergraduate curricula, but the majority is yet to provide Indigenous cultural awareness/cultural safety training for faculty.

  15. Competitive effects and instruments of power sector reforms. International reform concepts blockade structures, risk distribution. A political economy analysis; Wettbewerbseffekte und Instrumente von Stromsektorreformen. Internationale Reformkonzepte, Blockadestrukturen, Risikoverteilung. Eine politoekonomische Analyse

    Energy Technology Data Exchange (ETDEWEB)

    Liebchen, Armin [Liebchen Consulting, Berlin (Germany)

    2014-07-01

    Power sectors with weak or inadequate competition structures are the rule, despite numerous attempts at reform. But can afford modern economies this defect for a long time? Why can the implementation of competition are blocked so effectively? The author studied international reform experiences and opens up interesting insights that can also reflect on problems of the German energy turnaround: The difficulty of timing and coordination of the reform components, the development of resistance levels of individual interest groups, breach of contract as a rational alternative, causes unwanted price effects, shifting interest situations of major stakeholders, change dynamics impending regulatory risks, pending financing risks, stranded cost-conflict situations for power stations disconnected from the grid and facilities and instruments of a political and regulatory risk management for reforms. With numerous examples, background analyzes and instruments to reform analysis, this book is aimed at investors, policy planners and analysts. [German] Stromsektoren mit schwachen oder unzulaenglichen Wettbewerbsstrukturen sind trotz zahlreicher Reformversuche die Regel. Aber koennen sich moderne Volkswirtschaften diesen Mangel dauerhaft leisten? Warum kann die Einfuehrung von Wettbewerb so wirksam blockiert werden? Der Autor untersucht internationale Reformerfahrungen und eroeffnet interessante Einsichten, die sich auch auf Problemlagen der deutschen Energiewende spiegeln lassen: Die Schwierigkeit des richtigen Timings und der Abstimmung der Reformteile, dem Aufbau von Widerstandslinien einzelner Interessensgruppen, Vertragsbruch als rationaler Alternative, Ursachen unerwuenschter Preiseffekte, sich verschiebenden Interessenslagen wichtiger Akteure, Veraenderungsdynamik drohender Regulierungsrisiken, schwebenden Finanzierungsrisiken, stranded-cost-Konfliktlagen fuer vom Netz genommene Kraftwerke und Moeglichkeiten und Instrumenten eines politisch-regulatorischen Risikomanagements

  16. Managing organizational change in an international scientific network: A study of ICES reform processes

    NARCIS (Netherlands)

    Stange, K.; Olssen, P.; Österblom, H.

    2012-01-01

    Organizations involved in the governance of natural resources are challenged to adjust to the call for more holistic management approaches. This often necessitates organizational change. Here change processes in the International Council for the Exploration of the Sea (ICES) during the years

  17. Norwegian climate policy reforms in the presence of an international quota market

    International Nuclear Information System (INIS)

    Bjertnæs, Geir H.; Tsygankova, Marina; Martinsen, Thomas

    2013-01-01

    This study shows that the second-best optimal difference between tax rates on goods that generate greenhouse gas emissions and non-polluting goods is equal to the quota price plus a Ramsey tax on the quota price when emission quotas are traded between governments and the price elasticity of these goods is identical. This tax difference exceeds the second-best optimal difference between tax rates on goods that generate a negative externality equivalent to the quota price and non-polluting goods. Model simulations show that a unilateral increase in emission tax to above the international quota price generates a welfare gain for Norway. Model simulations also show that an international tax/quota price increase generates a welfare gain (loss) for Norway if Norwegian imports of oil become substantial (marginal) in the long run. - Highlights: • Higher second-best optimal emission tax rate with government quota trading • Optimal second-best emission tax rate exceeds the quota price. • Norwegian emission tax increase above international quota price boosts welfare. • International quota price increase boosts Norwegian welfare

  18. Promoting University and Industry Links at the Regional Level: Comparing China's Reform and International Experience

    Science.gov (United States)

    Po, Yang; Cai, Yuzhuo; Lyytinen, Anu; Hölttä, Seppo

    2016-01-01

    This paper intends to learn from international experiences in order to facilitating China's ongoing regional university transformation with an ultimate goal to enhance the role of university in regional economic development and innovation. In so doing, this paper compares major models of universities of applied sciences (UAS) around the world from…

  19. The OECD and Educational Policy Reform: International Surveys, Governance, and Policy Evidence

    Science.gov (United States)

    Volante, Louis; Fazio, Xavier; Ritzen, Jo

    2017-01-01

    Over the past 50 years, the Organisation for Economic Cooperation and Development (OECD) has increasingly influenced the nature and scope of education policies in primary, secondary, and tertiary sectors around the world. Policy suggestions in these sectors primarily stem from the results of their various international surveys such as the…

  20. Qatari Women in a Corporatized Higher Education Setting: International Reforms and Their Local Bearings

    Science.gov (United States)

    Al-Muftah, Esraa

    2017-01-01

    Discussions of the difficulties Qatari women experience in higher educational settings are unlikely to be found in international organization or government reports on the State of Qatar. Instead, recent reports have tended to gloss over gender inequalities raising a "successful girl discourse." Drawing on my own teaching experience at…

  1. Creating the "International Mind": The League of Nations Attempts to Reform History Teaching, 1920-1939

    Science.gov (United States)

    Osborne, Ken

    2016-01-01

    After the First World War, the League of Nations, through its International Committee on Intellectual Cooperation, attempted to reshape the teaching of history in its member states. The League's supporters realized that its long-term success depended in part on supportive public opinion and that this, in turn, had implications for education. Aware…

  2. Good collaborative practice: reforming capacity building governance of international health research partnerships.

    Science.gov (United States)

    Ward, Claire Leonie; Shaw, David; Sprumont, Dominique; Sankoh, Osman; Tanner, Marcel; Elger, Bernice

    2018-01-08

    In line with the policy objectives of the United Nations Sustainable Development Goals, this commentary seeks to examine the extent to which provisions of international health research guidance promote capacity building and equitable partnerships in global health research. Our evaluation finds that governance of collaborative research partnerships, and in particular capacity building, in resource-constrained settings is limited but has improved with the implementation guidance of the International Ethical Guidelines for Health-related Research Involving Humans by The Council for International Organizations of Medical Sciences (CIOMS) (2016). However, more clarity is needed in national legislation, industry and ethics guidelines, and regulatory provisions to address the structural inequities and power imbalances inherent in international health research partnerships. Most notably, ethical partnership governance is not supported by the principal industry ethics guidelines - the International Conference on Harmonization Technical Requirements for Registration of Pharmaceutical for Human Use (ICH) Good Clinical Practice (ICH-GCP). Given the strategic value of ICH-GCP guidelines in defining the role and responsibility of global health research partners, we conclude that such governance should stipulate the minimal requirements for creating an equitable environment of inclusion, mutual learning, transparency and accountability. Procedurally, this can be supported by i) shared research agenda setting with local leadership, ii) capacity assessments, and iii) construction of a memorandum of understanding (MoU). Moreover, the requirement of capacity building needs to be coordinated amongst partners to support good collaborative practice and deliver on the public health goals of the research enterprise; improving local conditions of health and reducing global health inequality. In this respect, and in order to develop consistency between sources of research governance, ICH

  3. Planar solid oxide fuel cell with staged indirect-internal air and fuel preheating and reformation

    Science.gov (United States)

    Geisbrecht, Rodney A; Williams, Mark C

    2003-10-21

    A solid oxide fuel cell arrangement and method of use that provides internal preheating of both fuel and air in order to maintain the optimum operating temperature for the production of energy. The internal preheat passes are created by the addition of two plates, one on either side of the bipolar plate, such that these plates create additional passes through the fuel cell. This internal preheat fuel cell configuration and method reduce the requirements for external heat exchanger units and air compressors. Air or fuel may be added to the fuel cell as required to maintain the optimum operating temperature through a cathode control valve or an anode control valve, respectively. A control loop comprises a temperature sensing means within the preheat air and fuel passes, a means to compare the measured temperature to a set point temperature and a determination based on the comparison as to whether the control valves should allow additional air or fuel into the preheat or bypass manifolds of the fuel cell.

  4. Slovenian Complementary Health Insurance Reform – Dichotomy between the Internal Market and the Social Dimension

    Directory of Open Access Journals (Sweden)

    Nikolić Bruno

    2015-12-01

    Full Text Available Complementary health insurance is divided between the internal market (market principles and social dimension, wherein the state has an extremely difficult task, as it must create the conditions necessary for the fair and efficient functioning of the health care financing system. Slovenia has failed to successfully accomplish this task, which consists of both ensuring the social dimension and also facilitating the operation of market principles. The aim of this article is not on the functioning of market principles, which are covered by the field of economics, but is instead on analyzing the dichotomy between the internal market (the rules that govern the functioning of the internal market and the social dimension (the rules that enable the exercise of the social function, and, in this light, analyzes the legal regulation of the Slovenian complementary health insurance. Analysis of the legal regulation highlights the shortcomings in ensuring the social dimension, shortcomings which are, with the help of the measures proposed in the concluding section of the article, remedied by the author.

  5. Health policy as a fuzzy concept: methodological problems encountered when evaluating health policy reforms in an international perspective.

    NARCIS (Netherlands)

    Kroneman, M.W.; Zee, J. van der

    1997-01-01

    Investigating health policy reforms at a national level is a troublesome task, since it is difficult to establish exactly when a certain policy change took place and it is also difficult to determine the content of the reform. In this paper three main causes are distinguished that contribute to the

  6. Policy Reforms, Trojan Horses, and Imaginary Friends: The Role of External Stakeholders in Internal Quality Assurance Systems

    Science.gov (United States)

    Rosa, Maria João; Teixeira, Pedro

    2014-01-01

    The governance of higher education has been changing across Europe, most notably in response to the reform agenda that has been pervading many higher education systems. This wave of reforms has given enhanced visibility to external stakeholders, which has been often received with contrasting views. Some regarded it as a factor that would undermine…

  7. Molten material-containing vessel

    International Nuclear Information System (INIS)

    Akagawa, Katsuhiko

    1998-01-01

    The molten material-containing vessel of the present invention comprises a vessel main body having an entrance opened at the upper end, a lid for closing the entrance, an outer tube having an upper end disposed at the lower surface of the lid, extended downwardly and having an closed lower end and an inner tube disposed coaxially with the outer tube. When a molten material is charged from the entrance to the inside of the vessel main body of the molten material-containing vessel and the entrance is closed by the lid, the outer tube and the inner tube are buried in the molten material in the vessel main body, accordingly, a fluid having its temperature elevated by absorption of the heat of the molten material rises along the inner circumferential surface of the outer tube, abuts against the lower surface of the lid and cooled by exchanging heat with the lid and forms a circulating flow. Since the heat in the molten material is continuously absorbed by the fluid, transferred to the lid and released from the lid to the atmospheric air, heat releasing efficiency can be improved compared with conventional cases. (N.H.)

  8. Molten salt reactor type

    International Nuclear Information System (INIS)

    1977-01-01

    This document is one of the three parts of a first volume devoted to the compilations of American data on the molten salt reactor concept. Emphasize is put essentially on the fuel salt of the primary circuit inside which fission reactions occur. The reasons why the (LiF-BeF 2 -ThF 4 -UF 4 ) salt was chosen for the M.S.B.R. concept are examined; the physical, physicochemical and chemical properties of this salt are discussed with its interactions with the structural materials and its evolution in time. An important part of this volume is devoted to the continuous reprocessing of the active salt, the project designers having deemed advisable to take advantage at best from the availability of a continuous purification, in a thermal breeding. The problem of tritium formation and distribution inside the reactor is also envisaged and the fundamentals of the chemistry of the secondary coolant salt are given. The solutions proposed are: the hydrogen scavenging of the primary circuit, a reduction in metal permeability by an oxyde layer deposition on the side in contact with the vapor, and tritium absorption through an isotope exchange with the hydroxifluoroborate [fr

  9. Higher Education Reform: Signs from the End of the Century International Debate

    Directory of Open Access Journals (Sweden)

    Roberto Rodríguez Gómez

    2000-05-01

    Full Text Available During the last ten years of the 20th century, there has been an extensive debate on the worldwide problem of higher education. This article aims at identifying some of the outstanding speakers who have greater impact; as well as briefly summarizing the lines of discussion present in the debate. The text is divided into two sections. The first one deals with the role of different international organizations in defining the public policies on higher education, particularly in Mexico and the Latin American region. The second one includes a commented description of three national cases, where some pronouncements emerged after the constitution of special commissions for the study of higher education: The French case, the United Kingdom’s and the United States’ case.

  10. International politics and national reforms: The dynamics between “competence” and the “inclusive school” in Norwegian education policies

    OpenAIRE

    Arnesen, Anne-Lise

    2011-01-01

    In this article, inclusive education is analysed from the perspective of the interlinked, dynamic relationship between international neo-liberal movements and national policies and practices. The aim is to explore the significance of “competence” in recent Norwegian reforms and the changing position attributed to inclusion. The analysis shows that during a very short period from 1997 to the present date Norway has seen a rapid change from a highly state-regulated system with an expressed emph...

  11. The International Politics of Legal Reforms: Hard Bilateralism, Soft Multilateralism and the World Bank’s “Doing Business” Indicators

    Directory of Open Access Journals (Sweden)

    Yi Shin Tang

    2017-10-01

    Full Text Available Abstract The Law and Development literature still debates on the role of international institutions in promoting legal reforms as a means of inducing economic growth. This article takes one step further by arguing that incremental circumstances compelled such institutions to change from bilaterally-binding pressures to soft-based multilateral strategies, by analyzing the gradual rise of the World Bank’s “Doing Business” initiative.

  12. Supported molten-metal catalysts

    Science.gov (United States)

    Datta, Ravindra; Singh, Ajeet; Halasz, Istvan; Serban, Manuela

    2001-01-01

    An entirely new class of catalysts called supported molten-metal catalysts, SMMC, which can replace some of the existing precious metal catalysts used in the production of fuels, commodity chemicals, and fine chemicals, as well as in combating pollution. SMMC are based on supporting ultra-thin films or micro-droplets of the relatively low-melting (metals and semimetals from groups 1, 12, 13, 14, 15 and 16, of the periodic table, or their alloys and intermetallic compounds, on porous refractory supports, much like supported microcrystallites of the traditional solid metal catalysts. It thus provides orders of magnitude higher surface area than is obtainable in conventional reactors containing molten metals in pool form and also avoids corrosion. These have so far been the chief stumbling blocks in the application of molten metal catalysts.

  13. Ceramics for Molten Materials Transfer

    Science.gov (United States)

    Standish, Evan; Stefanescu, Doru M.; Curreri, Peter A.

    2009-01-01

    The paper reviews the main issues associated with molten materials transfer and handling on the lunar surface during the operation of a hig h temperature electrowinning cell used to produce oxygen, with molten iron and silicon as byproducts. A combination of existing technolog ies and purposely designed technologies show promise for lunar exploi tation. An important limitation that requires extensive investigation is the performance of refractory currently used for the purpose of m olten metal containment and transfer in the lunar environment associa ted with electrolytic cells. The principles of a laboratory scale uni t at a scale equivalent to the production of 1 metric ton of oxygen p er year are introduced. This implies a mass of molten materials to be transferred consistent with the equivalent of 1kg regolithlhr proces sed.

  14. Aluminum titanate crucible for molten uranium

    International Nuclear Information System (INIS)

    Asbury, J.J.

    1975-01-01

    An improved crucible for molten uranium is described. The crucible or crucible liner is formed of aluminum titanate which essentially eliminates contamination of uranium and uranium alloys during molten states thereof. (U.S.)

  15. Analysis of equilibrium and kinetic models of internal reforming on solid oxide fuel cell anodes: Effect on voltage, current and temperature distribution

    Science.gov (United States)

    Ahmed, Khaliq; Fӧger, Karl

    2017-03-01

    The SOFC is well-established as a high-efficiency energy conversion technology with demonstrations of micro-CHP systems delivering 60% net electrical efficiency [1]. However, there are key challenges in the path to commercialization. Foremost among them is stack durability. Operating at high temperatures, the SOFC invariably suffers from thermally induced material degradation. This is compounded by thermal stresses within the SOFC stack which are generated from a number of interacting factors. Modelling is used as a tool for predicting undesirable temperature and current density gradients. For an internal reforming SOFC, fidelity of the model is strongly linked to the representation of the fuel reforming reactions, which dictate species concentrations and net heat release. It is critical for simulation of these profiles that the set of reaction rate expressions applicable for the particular anode catalyst are chosen in the model. A relatively wide spectrum of kinetic correlations has been reported in the literature. This work presents a comparative analysis of the internal distribution of temperature, current, voltage and compositions on a SOFC anode, using various combinations of reaction kinetics and equilibrium expressions for the reactions. The results highlight the significance of the fuel reforming chemistry and kinetics in the prediction of cell performance.

  16. Electrochemical Transfer of S Between Molten Steel and Molten Slag

    Science.gov (United States)

    Kim, Dong-Hyun; Kim, Wook; Kang, Youn-Bae

    2018-02-01

    S transfer between molten steel and molten slag was investigated in view of the electrochemical character of S transfer. C-saturated molten steel containing S was allowed to react with CaO-SiO2-Al2O3-MgO slag at 1673 K (1400 °C) until the two phases arrive at a chemical equilibrium. The application of an electric field of constant current through graphite electrodes lowered the S content in the molten steel below its chemical equilibrium level, and the system arrived at a new equilibrium level (electrochemical equilibrium). However, subsequent shutting off of the electric field did not lead to the system reverting to the original chemical equilibrium: reversion of S was observed but to a limited extent. The application of an electric field of opposite direction or flowing of CO gas allowed significant reversion of S. Side reactions (decomposition of oxide components) were observed, and these were considered to be coupled to the transfer of S. An electrochemical reaction mechanism was proposed based on the experimental observations found in the present study.

  17. Development of a coal-fueled Internal Manifold Heat Exchanger (IMHEX{reg_sign}) molten carbonate fuel cell. Volumes 1--6, Final report

    Energy Technology Data Exchange (ETDEWEB)

    1991-09-01

    The design of a CGMCFC electric generation plant that will provide a cost of eletricity (COE) which is lower than that of current electric generation technologies and which is competitive with other long-range electric generating systems is presented. This effort is based upon the Internal Manifold Heat Exchanger (IMHEX) technology as developed by the Institute of Gas Technology (IGT). The project was executed by selecting economic and performance objectives for alternative plant arrangements while considering process constraints identified during IMHEX fuel cell development activities at ICT. The four major subsystems of a coal-based MCFC power plant are coal gasification, gas purification, fuel cell power generation and the bottoming cycle. The design and method of operation of each subsystem can be varied, and, depending upon design choices, can have major impact on both the design of other subsystems and the resulting cost of electricity. The challenge of this project was to select, from a range of design parameters, those operating conditions that result in a preferred plant design. Computer modelling was thus used to perform sensitivity analyses of as many system variables as program resources and schedules would permit. In any systems analysis, it is imperative that the evaluation methodology be verifiable and comparable. The TAG Class I develops comparable (if imprecise) data on performance and costs for the alternative cases being studied. It identifies, from a range of options, those which merit more exacting scrutiny to be undertaken at the second level, TAG class II analysis.

  18. Electrolysis of a molten semiconductor

    Science.gov (United States)

    Yin, Huayi; Chung, Brice; Sadoway, Donald R.

    2016-01-01

    Metals cannot be extracted by electrolysis of transition-metal sulfides because as liquids they are semiconductors, which exhibit high levels of electronic conduction and metal dissolution. Herein by introduction of a distinct secondary electrolyte, we reveal a high-throughput electro-desulfurization process that directly converts semiconducting molten stibnite (Sb2S3) into pure (99.9%) liquid antimony and sulfur vapour. At the bottom of the cell liquid antimony pools beneath cathodically polarized molten stibnite. At the top of the cell sulfur issues from a carbon anode immersed in an immiscible secondary molten salt electrolyte disposed above molten stibnite, thereby blocking electronic shorting across the cell. As opposed to conventional extraction practices, direct sulfide electrolysis completely avoids generation of problematic fugitive emissions (CO2, CO and SO2), significantly reduces energy consumption, increases productivity in a single-step process (lower capital and operating costs) and is broadly applicable to a host of electronically conductive transition-metal chalcogenides. PMID:27553525

  19. Structure of molten iron chloride

    Energy Technology Data Exchange (ETDEWEB)

    Price, D.L.; Saboungi, M.L. (Argonne National Lab., IL (United States)); Hashimoto, Shinya; Moss, S.C. (Houston Univ., Houston, TX (United States). Dept. of Physics)

    1992-11-01

    The structure of molten FeCl[sub 3] at 320[sup degrees]C has been measured with neutron diffraction at the Intense Pulsed Neutron Source. Results indicate that melting in FeCl[sub 3]is accompanied by a change in local structure from the octahedral environment of the Fe[sup 3[plus

  20. thermic oil and molten salt

    African Journals Online (AJOL)

    Boukelia T.E, Mecibah M.S and Laouafi A

    1 mai 2016 ... [27] Zavoico, AB. Solar Power Tower Design Basis Document. Tech. rep, Sandia National. Laboratories, SAND2001-2100, 2001. How to cite this article: Boukelia T.E, Mecibah M.S and Laouafi A. Performance simulation of parabolic trough solar collector using two fluids (thermic oil and molten salt).

  1. Primary care reform in Central and Eastern Europe: can Belarus be taken as the control group in international comparison?

    NARCIS (Netherlands)

    Boerma, W.G.W.; Rousovich, V.S.; Schellevis, F.G.; Egorov, K.

    2005-01-01

    Background: Health care reform proceeds differently in Belarus. The country has not followed trends visible in most other countries. Financing and provision of health care is still in the hands of the state. Health insurance funds are unknown, private practices are rare and operating outside

  2. Reformas internacionais da educação e formação de professores International reforms in education and teacher training

    Directory of Open Access Journals (Sweden)

    Olgaíses Cabral Maués

    2003-03-01

    Full Text Available A formação de professores está hoje no centro dos acontecimentos do mundo da educação, suscitando aprovações e divergências e apontando para a necessidade de se fazerem reformas na área. Os motivos dessas reformas estão ligados, para alguns, aos resultados negativos do desempenho escolar, que não têm atendido às exigências do mundo do trabalho. Este texto analisa a reforma na formação de professores como uma tendência internacional, ligada às exigências dos organismos multilaterais, que visam atender ao processo de globalização/mundialização. A partir dessa lógica procuram-se identificar os postulados de base da reforma, o quadro conceitual, os aportes metodológicos que vêm dando suporte ao processo. O texto apresenta alguns eixos que sustentam as reformas na formação de professores, tais como: a "universitarização" profissionalização, a ênfase na formação prática/certificação de experiências, a formação contínua e a pedagogia das competências, analisando a importância de cada um no contexto internacional.Teacher training is currently the center of events in the world of education, yielding approval and controversy, and pointing out the need for reforms in the area. Reasons for these reforms, for some, are linked to the negative results in student performance, which have not met the labor market's demands. This text analyzes teacher training reform as an international trend, linked to multilateral agencies' requirements, whose purpose is to serve the process of globalization. Based on this logic, the aim is to identify the premises of such reform, the conceptual framework and the methodological contributions which have supported the process. The text presents some axes which have sustained teacher training reforms, such as: "universitarization"/professionalization, emphasis on practical training/certification of experience, continuous training and competence-based pedagogy, analyzing the importance of

  3. Reforming Romanian energy policy

    International Nuclear Information System (INIS)

    Perkins, S.

    1993-01-01

    Success in reforming energy sector depends on the implementation of the programme of economic reform agreed in February 1993. The difficulty of the negotiations between the International Monetary Fund and the Romanian government reflects the wider difficulties faced by the economy as a whole. They can be blamed in part on the legacy of uneconomic and inflexible industrial development and in part on opposition from interest groups which stand to lose from reform. Nonetheless, in spite of hesitant approach, the government does appear committed to the economic reform necessary to establish a market-oriented economy. But as the danger of a financial crisis engendered by the inadequately supported short-term borrowing of foreign exchange becomes urgent, the question is whether economic reform can be now implemented fast enough to protect economic enterprises and saving from a debt crisis. The scope for further delay in implementing the 1993 economic reform programme is fast disappearing. Procrastination should not be allowed to threaten the success of the reforms achieved in the energy and other sectors of the economy. 8 refs., 2 figs

  4. Security Sector Reform in Albania

    OpenAIRE

    Abazi, Enika; Bumci, Aldo; Hide, Enri; Rakipi, Albert

    2009-01-01

    International audience; This paper analyses security sector reform (SSR) in Albania. In all its enterprises in reforming the security sector,Albania is assisted by different initiatives and projects that provide expertise and financial support. To assesswhether reforms improved the overall security environment (national and human) of the country, it is necessaryto measure the effectiveness of the various initiatives and projects. This is gauged by how well the initiatives andprojects achieved...

  5. MOLTEN FLUORIDE NUCLEAR REACTOR FUEL

    Science.gov (United States)

    Barton, C.J.; Grimes, W.R.

    1960-01-01

    Molten-salt reactor fuel compositions consisting of mixtures of fluoride salts are reported. In its broadest form, the composition contains an alkali fluoride such as sodium fluoride, zirconium tetrafluoride, and a uranium fluoride, the latter being the tetrafluoride or trifluoride or a mixture of the two. An outstanding property of these fuel compositions is a high coeffieient of thermal expansion which provides a negative temperature coefficient of reactivity in reactors in which they are used.

  6. Partially molten magma ocean model

    International Nuclear Information System (INIS)

    Shirley, D.N.

    1983-01-01

    The properties of the lunar crust and upper mantle can be explained if the outer 300-400 km of the moon was initially only partially molten rather than fully molten. The top of the partially molten region contained about 20% melt and decreased to 0% at 300-400 km depth. Nuclei of anorthositic crust formed over localized bodies of magma segregated from the partial melt, then grew peripherally until they coverd the moon. Throughout most of its growth period the anorthosite crust floated on a layer of magma a few km thick. The thickness of this layer is regulated by the opposing forces of loss of material by fractional crystallization and addition of magma from the partial melt below. Concentrations of Sr, Eu, and Sm in pristine ferroan anorthosites are found to be consistent with this model, as are trends for the ferroan anorthosites and Mg-rich suites on a diagram of An in plagioclase vs. mg in mafics. Clustering of Eu, Sr, and mg values found among pristine ferroan anorthosites are predicted by this model

  7. A Technical Perspective on Molten Aluminum Processing

    Science.gov (United States)

    Waite, Peter

    In today's context of global competitiveness, all factors related to molten metal treatment which directly or indirectly affect product quality, the environment and processing costs must be optimized. In this regard, technology and innovation play a decisive role for the development and implementation of the most appropriate molten metal treatment processes and practices. The following discussion will review the most recent significant developments in the field of molten aluminum processing and outline potential areas for improvement.

  8. Influence of the reprocessing on molten salt reactor behaviour

    OpenAIRE

    Merle-Lucotte, E.; Mathieu, L.; Heuer, D.; Billebaud, A.; Brissot, R.; Le Brun, C.; Liatard, E.; Loiseaux, J.M.; Méplan, O.; Nuttin, A.; Wilson, J.

    2005-01-01

    International audience; The Molten Salt Reactor is one of the systems studied as a Generation IV reactor. Its main characteristic is the strong coupling between neutronics and salt reprocessing. Such nuclear reactors use a liquid fuel which is also the coolant. Elements produced during the reactor's operation, like Fission Products (FP) or TransUranians, modify the neutronic balance of the reactor by capturing neutrons. As the fuel is liquid, samples can be extracted and reprocessed to remove...

  9. On direct internal methane steam reforming kinetics in operating solid oxide fuel cells with nickel-ceria anodes

    Science.gov (United States)

    Thallam Thattai, A.; van Biert, L.; Aravind, P. V.

    2017-12-01

    Major operating challenges remain to safely operate methane fuelled solid oxide fuel cells due to undesirable temperature gradients across the porous anode and carbon deposition. This article presents an experimental study on methane steam reforming (MSR) global kinetics for single operating SOFCs with Ni-GDC (gadolinium doped ceria) anodes for low steam to carbon (S/C) ratios and moderate current densities. The study points out the hitherto insufficient research on MSR global and intrinsic kinetics for operating SOFCs with complete Ni-ceria anodes. Further, it emphasizes the need to develop readily applicable global kinetic models as a subsequent step from previously reported state-of-art and complex intrinsic models. Two rate expressions of the Power law (PL) and Langmuir-Hinshelwood (LH) type have been compared and based on the analysis, limitations of using previously proposed rate expressions for Ni catalytic beds to study MSR kinetics for complete cermet anodes have been identified. Firstly, it has been shown that methane reforming on metallic (Ni) current collectors may not be always negligible, contrary to literature reports. Both PL and LH kinetic models predict significantly different local MSR reaction rate and species partial pressure distributions along the normalized reactor length, indicating a strong need for further experimental verifications.

  10. The molten glass sewing machine

    Science.gov (United States)

    Brun, P.-T.; Inamura, Chikara; Lizardo, Daniel; Franchin, Giorgia; Stern, Michael; Houk, Peter; Oxman, Neri

    2017-04-01

    We present a fluid-instability-based approach for digitally fabricating geometrically complex uniformly sized structures in molten glass. Formed by mathematically defined and physically characterized instability patterns, such structures are produced via the additive manufacturing of optically transparent glass, and result from the coiling of an extruded glass thread. We propose a minimal geometrical model-and a methodology-to reliably control the morphology of patterns, so that these building blocks can be assembled into larger structures with tailored functionally and optically tunable properties. This article is part of the themed issue 'Patterning through instabilities in complex media: theory and applications'.

  11. Structure of molten iron chloride

    Energy Technology Data Exchange (ETDEWEB)

    Price, D.L.; Saboungi, M.L. [Argonne National Lab., IL (United States); Hashimoto, Shinya; Moss, S.C. [Houston Univ., Houston, TX (United States). Dept. of Physics

    1992-11-01

    The structure of molten FeCl{sub 3} at 320{sup degrees}C has been measured with neutron diffraction at the Intense Pulsed Neutron Source. Results indicate that melting in FeCl{sub 3}is accompanied by a change in local structure from the octahedral environment of the Fe{sup 3{plus}} in the solid to an Fe{sub 2}Cl{sub 6} molecular liquid. This behavior is similar to that observed in AlCl{sub 3} and in contrast to that of YCl{sub 3} where an octahedral coordination is preserved on melting. 3 figs, 1 tab, 12 refs.

  12. Niobium electrodeposition from molten fluorides

    International Nuclear Information System (INIS)

    Sartori, A.F.

    1987-01-01

    Niobium electrodeposition from molten alkali fluorides has been studied aiming the application of this technic to the processes of electrorefining and galvanotechnic of this metal. The effects of current density, temperature, niobium concentration in the bath, electrolysis time, substrate nature, ratio between anodic and cathodic areas, electrodes separation and the purity of anodes were investigated in relation to the cathodic current efficiency, electrorefining, electroplating and properties of the deposit and the electrolytic solution. The work also gives the results of the conctruction and operation of a pilot plant for refractory metals electrodeposition and shows the electrorefining and electroplating compared to those obtained at the laboratory scale. (author) [pt

  13. Reforming Copyright in the Context of Exercise of the Human Right to Free Expression on the Internet: An Actual Problems of the Modern International Legal Politics

    Directory of Open Access Journals (Sweden)

    Irina V. Shugurova

    2015-12-01

    Full Text Available The authors discuss major trends in the area of reforming of copyright in the light of full exercise of internationally recognized human right to expression regarding the digital environment, especially the Internet, and demonstrate the significant situation when intellectual property rights, mainly author’s exclusive rights, build a lot of troubles for the information human rights. The article also looks at the changes in the understanding the relation between copyright and the human right to freedom of expression and information on the Internet. Much attention is paid to new moments in the modern doctrine of intellectual property that is inspired by process of digitization of author’s rights. There is conducted the approach to addressing copyright as one of the digital human rights resulted from property rights and right of creators to protection of their moral and economic interests. However, authors of the article departure from postulate that copyright is the human rights to a certain degree only. Moreover, this article examines the international legal approach to seeking the balance between the human right to freedom of expression, opinion and information, on the one hand, and copyright, especially as regards the Internet, on the other hand. There has been argued that key role in elaborating and adopting the principled standards in this sphere belongs to international law, including international law of human rights. In addition, the latter, as authors have ascertained, must correspond to international law of intellectual property rights, international information law, and international competition law. The study focus on various aspects of solving the problem of adapting copyright to the digital environment.

  14. Molten carbonate fuel cell separator

    Science.gov (United States)

    Nickols, R.C.

    1984-10-17

    In a stacked array of molten carbonate fuel cells, a fuel cell separator is positioned between adjacent fuel cells to provide isolation as well as a conductive path therebetween. The center portion of the fuel cell separator includes a generally rectangular, flat, electrical conductor. Around the periphery of the flat portion of the separator are positioned a plurality of elongated resilient flanges which form a gas-tight seal around the edges of the fuel cell. With one elongated flange resiliently engaging a respective edge of the center portion of the separator, the sealing flanges, which are preferably comprised of a noncorrosive material such as an alloy of yttrium, iron, aluminum or chromium, form a tight-fitting wet seal for confining the corrosive elements of the fuel cell therein. This arrangement permits a good conductive material which may be highly subject to corrosion and dissolution to be used in combination with a corrosion-resistant material in the fuel cell separator of a molten carbonate fuel cell for improved fuel cell conductivity and a gas-tight wet seal.

  15. Molten salt reactor related research in Switzerland

    International Nuclear Information System (INIS)

    Krepel, Jiri; Hombourger, Boris; Fiorina, Carlo

    2015-01-01

    Switzerland represented by the Paul Scherrer Institute (PSI) is a member of the Generation IV International Forum (GIF). In the past, the research at PSI focused mainly on HTR, SFR, and GFR. Currently, a research program was established also for Molten Salt Reactors (MSR). Safety is the key point and main interest of the MSR research at the Nuclear Energy and Safety (NES) department of PSI. However, it cannot be evaluated without knowing the system design, fuel chemistry, salt thermal-hydraulics features, safety and fuel cycle approach, and the relevant material and chemical limits. Accordingly, sufficient knowledge should be acquired in the other individual fields before the safety can be evaluated. The MSR research at NES may be divided into four working packages (WP): WP1: MSR core design and fuel cycle, WP2: MSR fuel behavior at nominal and accidental conditions, WP3: MSR thermal-hydraulics and decay heat removal system, WP4: MSR safety, fuel stream, and relevant limits. The WPs are proposed so that there are research topics which can be independently studied within each of them. The work plan of the four WPs is based on several ongoing or past national and international projects relevant to MSR, where NES/PSI participates. At the current stage, the program focuses on several specific and design independent studies. The safety is the key point and main long-term interest of the MSR research at NES. (author)

  16. Investigating Ways to Reform International Education in Confucian Contexts: A Case Study of South Korean Higher Education

    Science.gov (United States)

    Schenck, Andrew; Mottalib, Ramy E.A.; Baldwin, Matthew

    2013-01-01

    The purpose of this study was to explore issues of international education within a Confucian context. Fifteen international learners were purposively sampled from a Korean university; these participants were then given an extensive open-ended interview to elicit information about educational experiences. Data analysis revealed five main issues: a…

  17. Accelerator-driven molten-salt blankets: Physics issues

    International Nuclear Information System (INIS)

    Houts, M.G.; Beard, C.A.; Buksa, J.J.; Davidson, J.W.; Durkee, J.W.; Perry, R.T.; Poston, D.I.

    1994-01-01

    A number of nuclear physics issues concerning the Los Alamos molten-salt accelerator-driven plutonium converter are discussed. General descriptions of several concepts using internal and external moderation are presented. Burnup and salt processing requirement calculations are presented for four concepts, indicating that both the high power density externally moderated concept and an internally moderated concept achieve total plutonium burnups approaching 90% at salt processing rates of less than 2 m 3 per year. Beginning-of-life reactivity temperature coefficients and system kinetic response are also discussed. Future research should investigate the effect of changing blanket composition on operational and safety characteristics

  18. Administrative Reform

    DEFF Research Database (Denmark)

    Plum, Maja

    Through the example of a Danish reform of educational plans in early childhood education, the paper critically addresses administrative educational reforms promoting accountability, visibility and documentation. Drawing on Foucaultian perspectives, the relation between knowledge and governing...... of administrative technology, tracing how the humanistic values of education embed and are embedded within ‘the professional nursery teacher' as an object and subject of administrative practice. Rather than undermining the humanistic potential of education, it is argued that the technology of accounting...

  19. Health care reforms.

    Science.gov (United States)

    Marušič, Dorjan; Prevolnik Rupel, Valentina

    2016-09-01

    In large systems, such as health care, reforms are underway constantly. The article presents a definition of health care reform and factors that influence its success. The factors being discussed range from knowledgeable personnel, the role of involvement of international experts and all stakeholders in the country, the importance of electoral mandate and governmental support, leadership and clear and transparent communication. The goals set need to be clear, and it is helpful to have good data and analytical support in the process. Despite all debates and experiences, it is impossible to clearly define the best approach to tackle health care reform due to a different configuration of governance structure, political will and state of the economy in a country.

  20. Reform and Backlash to Reform

    DEFF Research Database (Denmark)

    Hougaard Jensen, Svend E.; Hagen Jørgensen, Ole

    Using a stochastic general equilibrium model with overlapping generations, this paper studies (i) the effects on both extensive and intensive labor supply responses to changes in fertility rates, and (ii) the potential of a retirement reform to mitigate the effects of fertility changes on labor...... supply. In order to neutralize the effects on effective labor supply of a fertility decline, a retirement reform, designed to increase labor supply at the extensive margin, is found to simultaneously reduce labor supply at the intensive margin. This backlash to retirement reform requires the statutory...

  1. Thermal conductivity of molten metals

    Energy Technology Data Exchange (ETDEWEB)

    Peralta-Martinez, Maria Vita

    2000-02-01

    A new instrument for the measurement of the thermal conductivity of molten metals has been designed, built and commissioned. The apparatus is based on the transient hot-wire technique and it is intended for operation over a wide range of temperatures, from ambient up to 1200 K, with an accuracy approaching 2%. In its present form the instrument operates up to 750 K. The construction of the apparatus involved four different stages, first, the design and construction of the sensor and second, the construction of an electronic system for the measurement and storage of data. The third stage was the design and instrumentation of the high temperature furnace for the melting and temperature control of the sample, and finally, an algorithm was developed for the extraction of the thermal conductivity from the raw measurement data. The sensor consists of a cylindrical platinum-wire symmetrically sandwiched between two rectangular plane sheets of alumina. The rectangular sensor is immersed in the molten metal of interest and a voltage step is applied to the ends of the platinum wire to induce heat dissipation and a consequent temperature rise which, is in part, determined by the thermal conductivity of the molten metal. The process is described by a set of partial differential equations and appropriate boundary conditions rather than an approximate analytical solution. An electronic bridge configuration was designed and constructed to perform the measurement of the resistance change of the platinum wire in the time range 20 {mu}s to 1 s. The resistance change is converted to temperature change by a suitable calibration. From these temperature measurements as a function of time the thermal conductivity of the molten metals has been deduced using the Finite Element Method for the solution of the working equations. This work has achieved its objective of improving the accuracy of the measurement of the thermal conductivity of molten metals from {+-}20% to {+-}2%. Measurements

  2. Molten salt safety study. Final report

    Energy Technology Data Exchange (ETDEWEB)

    1980-01-01

    The considerations concerning safety in using molten salt (40% potassium nitrate, 60% sodium nitrate) in a solar central receiver plant are addressed. The considerations are of a general nature and do not cover any details of equipment or plant operation. The study includes salt chemical reaction, experiments with molten salt, dry storage and handling constraints, and includes data from the National Fire Protection Association. The contents of this report were evaluated by two utility companies and they concluded that no major safety problems exist in using a molten salt solar system.

  3. Pension reform in the European periphery: the role of EU reform advocacy

    NARCIS (Netherlands)

    Stepan, M.; Anderson, K.A.

    2014-01-01

    SUMMARY: This paper analyzes the impact of international reform advocacy on national pension reforms. We analyze European Union (EU) reform advocacy in two EU member states: Greece and Hungary. Although the EU has articulated a fairly coherent template for sustainable pensions, its use of soft

  4. Responding to obesity in Brazil: understanding the international and domestic politics of policy reform through a nested analytic approach to comparative analysis.

    Science.gov (United States)

    Gómez, Eduardo J

    2015-02-01

    Why do governments pursue obesity legislation? And is the case of Brazil unique compared with other nations when considering the politics of policy reform? Using a nested analytic approach to comparative research, I found that theoretical frameworks accounting for why nations implement obesity legislation were not supported with cross-national statistical evidence. I then turned to the case of Brazil's response to obesity at three levels of government, national, urban, and rural, to propose alternative hypotheses for why nations pursue obesity policy. The case of Brazil suggests that the reasons that governments respond are different at these three levels. International forces, historical institutions, and social health movements were factors that prompted national government responses. At the urban and rural government levels, receiving federal financial assistance and human resource support appeared to be more important. The case of Brazil suggests that the international and domestic politics of responding to obesity are highly complex and that national and subnational political actors have different perceptions and interests when pursuing obesity legislation. Copyright © 2015 by Duke University Press.

  5. Le système financier international en temps normal et en temps de crise Quelles reformes?

    OpenAIRE

    AICH, Sarah

    2011-01-01

    Le système financier international en temps normal et en temps de crises Ce mémoire a pour objectif d’étudier Le système financier international, ce système qui ne cesse de connaître des mutations et des évolutions profondes dans le temps et dans l’espace. Plusieurs phénomènes peuvent être mis en oeuvre pour expliquer et identifier l’importance des transformations qu’a connue le système financier international, en effet, y a trente ans, le monde économique est passé d’un système de change ...

  6. Molten salt destruction process for mixed wastes

    International Nuclear Information System (INIS)

    Upadhye, R.S.; Wilder, J.G.; Karisen, C.E.

    1993-01-01

    We are developing an advanced two-stage process for the treatment of mixed wastes, which contain both hazardous and radioactive components (1) The wastes, together with an oxidant gas, such as air, are injected into a bed of molten salt comprising a mixture of sodium-, potassium-, and lithium-carbonates, with a melting point of about 580 degrees C. The organic constituents of the mixed waste are destroyed through the combined effect of pyrolysis and oxidation. Heteroatoms, such as chlorine, in the mixed waste form stable salts, such as sodium chloride, and are retained in the melt. The radioactive actinides in the mixed waste are also retained in the melt because of the combined action of wetting and partial dissolution. The original process, developed by Rockwell International, consists of a one-stage unit, operated at 900-1000 degrees C. The advanced two-stage process has two stages, one for pyrolysis and one for oxidation. The pyrolysis stage is designed to operate at 700 degrees C. The oxidation stage can be operated at a higher temperature, if necessary

  7. Administrative Reform

    DEFF Research Database (Denmark)

    Plum, Maja

    Through the example of a Danish reform of educational plans in early childhood education, the paper critically addresses administrative educational reforms promoting accountability, visibility and documentation. Drawing on Foucaultian perspectives, the relation between knowledge and governing......, implied in the reform, is analysed as a technology of accounting. A technology producing ‘the professional nursery teacher' as a reflective daily researcher, who outlives her pedagogical desire as an analytical care of the optimisation of ‘the learning child'. Thus, the paper analyses the micro physics...... of administrative technology, tracing how the humanistic values of education embed and are embedded within ‘the professional nursery teacher' as an object and subject of administrative practice. Rather than undermining the humanistic potential of education, it is argued that the technology of accounting...

  8. When grammars collide: Harm reduction, drug detention and the challenges of international policy reform efforts in Vietnam.

    Science.gov (United States)

    Edington, Claire; Bayer, Ronald

    2013-01-01

    Throughout the 1990s, a dramatic rise in HIV prevalence rates among drug users in Vietnam attracted the attention of international observers concerned about the prospect of a more generalised epidemic. Vietnam subsequently became the target of extensive funding and advocacy which sought to introduce needle exchange and methadone in a country where drug use was considered a 'social evil', and drug users were subjected to what international observers viewed as draconian incarceration measures. What were the goals of proponents of harm reduction when they came to Vietnam? How did they perceive the state of prevailing approaches to drug users in the context of the Vietnamese HIV epidemic? How did they understand the strategic challenges they faced and the dilemmas they had to confront? Based on in-depth interviews with international harm reduction proponents working in Vietnam, this paper explores the encounter of two grammars of harm reduction, one based on broadly accepted international approaches, the other rooted in Vietnam's own history and politics. From this encounter a set of policies and practices characterised by needle exchange and methadone maintenance emerged, as well as an extensive network of closed centres where tens of thousands of drug users are currently detained.

  9. Molten salts processes and generic simulation

    International Nuclear Information System (INIS)

    Ogawa, Toru; Minato, Kazuo

    2001-01-01

    Development of dry separation process (pyrochemical process) using molten salts for the application of spent-nuclear fuel reprocessing requires a rather complete fundamental database as well as process simulation technique with wide applicability. The present report concerns recent progress and problems in this field taking behaviors of co-electrodeposition of UO 2 and PuO 2 in molten salts as an example, and using analytical simulation of local equilibrium combined with generic diffusion. (S. Ohno)

  10. Molten salts processes and generic simulation

    Energy Technology Data Exchange (ETDEWEB)

    Ogawa, Toru; Minato, Kazuo [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment

    2001-12-01

    Development of dry separation process (pyrochemical process) using molten salts for the application of spent-nuclear fuel reprocessing requires a rather complete fundamental database as well as process simulation technique with wide applicability. The present report concerns recent progress and problems in this field taking behaviors of co-electrodeposition of UO{sub 2} and PuO{sub 2} in molten salts as an example, and using analytical simulation of local equilibrium combined with generic diffusion. (S. Ohno)

  11. The Structure Of Molten Nickel Chloride

    OpenAIRE

    Newport, Robert J.; Howe, R.A.; Wood, N.D.

    1985-01-01

    The structure of molten NiCl2 has been investigated by the scattering of neutrons from isotropically enriched samples. The three partial structure factors relating to Ni-Ni, Cl-Cl and Ni-Cl correlations and the three corresponding radial distribution functions have been determined from the experimental data. The results are compared with those obtained from earlier studies of 2:1 molten salts and are discussed in the context of polarisation and ion size effects.

  12. Controlling the discharge of molten material

    International Nuclear Information System (INIS)

    Geel, J. van; Dobbels, F.; Theunissen, W.

    1980-01-01

    A method and device are described for controlling the discharge of molten material from a melter or an intermediate vessel, in which a primary outflow is fed to an overflow system, the working level of which is regulated by means of pneumatic pressure on a communicating chamber pertaining to the overflow system. Molten material may be led into a primary overflow by means of a pneumatic lift. The material melted may be a glass used for disposing of radioactive liquid wastes. (author)

  13. Electrochemical ion separation in molten salts

    Energy Technology Data Exchange (ETDEWEB)

    Spoerke, Erik David; Ihlefeld, Jon; Waldrip, Karen; Wheeler, Jill S.; Brown-Shaklee, Harlan James; Small, Leo J.; Wheeler, David R.

    2017-12-19

    A purification method that uses ion-selective ceramics to electrochemically filter waste products from a molten salt. The electrochemical method uses ion-conducting ceramics that are selective for the molten salt cations desired in the final purified melt, and selective against any contaminant ions. The method can be integrated into a slightly modified version of the electrochemical framework currently used in pyroprocessing of nuclear wastes.

  14. Molten Metal Explosions are Still Occurring

    Science.gov (United States)

    2009-02-01

    and cast by a variety of methods in the aluminum industry every day, safely and without incident. However, as with other molten substances, molten...Incidents in this operation are predominantly Force 1 with metal popping from unheated troughs, crucibles, ladles , etc. Exceptions are steel drain...thermiting dross into a water puddle and was fatally burned. Casting : Incidents continue to be reported for dc casting arising from bleed-outs

  15. Slab reformer

    Science.gov (United States)

    Spurrier, Francis R. (Inventor); DeZubay, Egon A. (Inventor); Murray, Alexander P. (Inventor); Vidt, Edward J. (Inventor)

    1985-01-01

    Slab-shaped high efficiency catalytic reformer configurations particularly useful for generation of fuels to be used in fuel cell based generation systems. A plurality of structures forming a generally rectangular peripheral envelope are spaced about one another to form annular regions, an interior annular region containing a catalytic bed and being regeneratively heated on one side by a hot combustion gas and on the other side by the gaseous products of the reformation. An integrally mounted combustor is cooled by impingement of incoming oxidant.

  16. Slab reformer

    Science.gov (United States)

    Spurrier, Francis R.; DeZubay, Egon A.; Murray, Alexander P.; Vidt, Edward J.

    1984-02-07

    Slab-shaped high efficiency catalytic reformer configurations particularly useful for generation of fuels to be used in fuel cell based generation systems. A plurality of structures forming a generally rectangular peripheral envelope are spaced about one another to form annular regions, an interior annular region containing a catalytic bed and being regeneratively heated on one side by a hot comubstion gas and on the other side by the gaseous products of the reformation. An integrally mounted combustor is cooled by impingement of incoming oxidant.

  17. Viscosity of Molten Alkaline-Earth Fluorides

    Science.gov (United States)

    Takeda, Osamu; Hoshino, Yosuke; Anbo, Yusuke; Yanagase, Kei-ichi; Aono, Masahiro; Sato, Yuzuru

    2015-04-01

    The viscosities of molten alkaline-earth fluorides were measured using the oscillating crucible method, which is especially suitable for measuring molten salts with low viscosity. The results showed a good Arrhenius linearity over a wide temperature range. The measured viscosities and activation energies increased in the following order: . Judging by the charge density, the viscosity of alkaline-earth fluorides should increase from molten to . However, the results indicate a different tendency, which may be explained by a Coulomb force that is very strong. The low viscosity of can be attributed to a decreased cohesive force, due to a partial loss of the Coulomb force caused by a higher charge density of the material. The viscosities were also compared to those of molten alkali fluorides and alkaline-earth chlorides. The viscosities of molten alkaline-earth fluorides were higher than those of molten alkali fluorides and alkaline-earth chlorides. The viscosity determined in this study was compared to literature values and showed a reasonable value in the relatively low-viscosity region.

  18. Major design issues of molten carbonate fuel cell power generation unit

    Energy Technology Data Exchange (ETDEWEB)

    Chen, T.P.

    1996-04-01

    In addition to the stack, a fuel cell power generation unit requires fuel desulfurization and reforming, fuel and oxidant preheating, process heat removal, waste heat recovery, steam generation, oxidant supply, power conditioning, water supply and treatment, purge gas supply, instrument air supply, and system control. These support facilities add considerable cost and system complexity. Bechtel, as a system integrator of M-C Power`s molten carbonate fuel cell development team, has spent substantial effort to simplify and minimize these supporting facilities to meet cost and reliability goals for commercialization. Similiar to other fuels cells, MCFC faces design challenge of how to comply with codes and standards, achieve high efficiency and part load performance, and meanwhile minimize utility requirements, weight, plot area, and cost. However, MCFC has several unique design issues due to its high operating temperature, use of molten electrolyte, and the requirement of CO2 recycle.

  19. Apparatus for making molten silicon

    Science.gov (United States)

    Levin, Harry (Inventor)

    1988-01-01

    A reactor apparatus (10) adapted for continuously producing molten, solar grade purity elemental silicon by thermal reaction of a suitable precursor gas, such as silane (SiH.sub.4), is disclosed. The reactor apparatus (10) includes an elongated reactor body (32) having graphite or carbon walls which are heated to a temperature exceeding the melting temperature of silicon. The precursor gas enters the reactor body (32) through an efficiently cooled inlet tube assembly (22) and a relatively thin carbon or graphite septum (44). The septum (44), being in contact on one side with the cooled inlet (22) and the heated interior of the reactor (32) on the other side, provides a sharp temperature gradient for the precursor gas entering the reactor (32) and renders the operation of the inlet tube assembly (22) substantially free of clogging. The precursor gas flows in the reactor (32) in a substantially smooth, substantially axial manner. Liquid silicon formed in the initial stages of the thermal reaction reacts with the graphite or carbon walls to provide a silicon carbide coating on the walls. The silicon carbide coated reactor is highly adapted for prolonged use for production of highly pure solar grade silicon. Liquid silicon (20) produced in the reactor apparatus (10) may be used directly in a Czochralski or other crystal shaping equipment.

  20. The mystery of molten metal

    Directory of Open Access Journals (Sweden)

    Natalia Sobczak

    2010-11-01

    Full Text Available Recent advances in scientific understanding of high-temperature materials processing using novel experimental methodologies have shed light on the complex role of surface and interface phenomena. New in-situ studies on molten metal/solid ceramic interactions using a unique experimental complex at the Foundry Research Institute, Krakow, have revealed a number of unusual observations in materials processing at high temperatures. We present some such unusual observations and their explanation with reference to liquid metal processing of Al, Ni, and Ti, and their alloys in contact with oxide ceramics. In particular, we focus on the following aspects: primary oxidation of Al from residual water vapor or oxygen, capillary purification to remove surface oxide, substrate protection by CVD carbon, roughening due to spinel whisker formation, inclusions in castings due to mechanical detachment, floatation due to buoyancy forces, and segregation due to directional solidification, modification of the solid surface morphology by metal vapor ahead of the liquid, and the complication due to multi-component alloys melted in crucibles made from complex oxide-based ceramics. In the case of Ti, rapid reactions with oxides result in undesirable volumetric changes that create difficulty in casting high-quality Ti parts, particularly by investment casting. Nanoscale (e.g., colloidal coatings based on Y2O3 protect crucibles and hold ladles against such attack. Practical insights and recommendations for materials processing emerging from the fundamental studies on high-temperature interfacial phenomena have been described.

  1. European Integration of Ukraine: Tool for Internal Reform, Source of Problems or Pass Ticket to EU Membership?

    Directory of Open Access Journals (Sweden)

    Oleh Poshedin

    2017-06-01

    Full Text Available Despite the signing of the EU-Ukraine Association Agreement, there would seem to be no alternative to the European choice for Ukraine, given the current Russian aggression; there are different views on the objectives and results of the European integration of Ukraine. This article examines three of the most common points of view related to this process: European integration as a tool for internal transformation in Ukraine; European integration as a pass ticket to the EU membership; European integration as a source of problems in Ukraine.

  2. Performance Testing of Molten Regolith Electrolysis with Transfer of Molten Material for the Production of Oxygen and Metals on the Moon

    Science.gov (United States)

    Sibille, Laurent; Sadoway, Donald; Tripathy, Prabhat; Standish, Evan; Sirk, Aislinn; Melendez, Orlando; Stefanescu, Doru

    2010-01-01

    Previously, we have demonstrated the production of oxygen by electrolysis of molten regolith simulants at temperatures near 1600 C. Using an inert anode and suitable cathode, direct electrolysis (no supporting electrolyte) of the molten silicate is carried out, resulting in the production of molten metallic products at the cathode and oxygen gas at the anode. Initial direct measurements of current efficiency have confirmed that the process offer potential advantages of high oxygen production rates in a smaller footprint facility landed on the moon, with a minimum of consumables brought from Earth. We now report the results of a scale-up effort toward the goal of achieving production rates equivalent to 1 metric ton O2/year, a benchmark established for the support of a lunar base. We previously reported on the electrochemical behavior of the molten electrolyte as dependent on anode material, sweep rate and electrolyte composition in batches of 20-200g and at currents of less than 0.5 A. In this paper, we present the results of experiments performed at currents up to 10 Amperes) and in larger volumes of regolith simulant (500 g - 1 kg) for longer durations of electrolysis. The technical development of critical design components is described, including: inert anodes capable of passing continuous currents of several Amperes, container materials selection, direct gas analysis capability to determine the gas components co-evolving with oxygen. To allow a continuous process, a system has been designed and tested to enable the withdrawal of cathodically-reduced molten metals and spent molten oxide electrolyte. The performance of the withdrawal system is presented and critiqued. The design of the electrolytic cell and the configuration of the furnace were supported by modeling the thermal environment of the system in an effort to realize a balance between external heating and internal joule heating. We will discuss the impact these simulations and experimental findings have

  3. Physical properties of molten carbonate electrolyte

    Energy Technology Data Exchange (ETDEWEB)

    Kojima, T.; Yanagida, M.; Tanimoto, K. [Osaka National Research Institute (Japan)] [and others

    1996-12-31

    Recently many kinds of compositions of molten carbonate electrolyte have been applied to molten carbonate fuel cell in order to avoid the several problems such as corrosion of separator plate and NiO cathode dissolution. Many researchers recognize that the addition of alkaline earth (Ca, Sr, and Ba) carbonate to Li{sub 2}CO{sub 3}-Na{sub 2}CO{sub 3} and Li{sub 2}CO{sub 3}-K{sub 2}CO{sub 3} eutectic electrolytes is effective to avoid these problems. On the other hand, one of the corrosion products, CrO{sub 4}{sup 2-} ion is found to dissolve into electrolyte and accumulated during the long-term MCFC operations. This would affect the performance of MCFC. There, however, are little known data of physical properties of molten carbonate containing alkaline earth carbonates and CrO{sub 4}{sup 2-}. We report the measured and accumulated data for these molten carbonate of electrical conductivity and surface tension to select favorable composition of molten carbonate electrolytes.

  4. Electrochemistry of plutonium in molten halides

    International Nuclear Information System (INIS)

    McCurry, L.E.; Moy, G.M.M.; Bowersox, D.F.

    1987-01-01

    The electrochemistry of plutonium in molten halides is of technological importance as a method of purification of plutonium. Previous authors have reported that plutonium can be purified by electrorefining impure plutonium in various molten haldies. Work to eluciate the mechanism of the plutonium reduction in molten halides has been limited to a chronopotentiometric study in LiCl-KCl. Potentiometric studies have been carried out to determine the standard reduction potential for the plutonium (III) couple in various molten alkali metal halides. Initial cyclic voltammetric experiments were performed in molten KCL at 1100 K. A silver/silver chloride (10 mole %) in equimolar NaCl-KCl was used as a reference electrode. Working and counter electrodes were tungsten. The cell components and melt were contained in a quartz crucible. Background cyclic voltammograms of the KCl melt at the tungsten electrode showed no evidence of electroactive impurities in the melt. Plutonium was added to the melt as PuCl/sub 3/, which was prepared by chlorination of the oxide. At low concentrations of PuCl/sub 3/ in the melt (0.01-0.03 molar), no reduction wave due to the reduction of Pu(III) was observed in the voltammograms up to the potassium reduction limit of the melt. However on scan reversal after scanning into the potassium reduction limit a new oxidation wave was observed

  5. New primary energy source by thorium molten-salt reactor technology

    International Nuclear Information System (INIS)

    Furukawa, Kazuo; Kato, Yoshio; Furuhashi, Akira; Numata, Hiroo; Mitachi, Koushi; Yoshioka, Ritsuo; Sato, Yuzuru; Arakawa, Kazuto

    2005-01-01

    Among the next 30 years, we have to implement a practical measure in the global energy/environmental problems, solving the followings: (1) replacing the fossil fuels without CO 2 emission, (2) no severe accidents, (3) no concern on military, (4) minimizing wastes, (5) economical, (6) few R and D investment and (7) rapid/huge global application supplying about half of the total primary energy till 50 years later. For this purpose the following system was proposed: THORIMS-NES [Thorium Molten-Salt Nuclear Energy Synergetic System], which is composed of (A) simple fission Molten-Salt power stations (FUJI), and (B) fissile-producing Accelerator Molten-Salt Breeder (AMSB). It has been internationally prepared a practical Developmental Program for its huge-size industrialization of Th breeding fuel cycle to produce a new rational primary energy. Here it is explained the social meaning, the conceptual system design and technological bases, especially, including the molten fluoride salt technology, which was developed as the triple-functional medium for nuclear-engineering, heat-transfer and chemical engineering. The complex function of this system is fully achieved by the simplified facility using a single phase molten-salt only. (author)

  6. Thorium Molten-Salt Nuclear Energy Synergetics

    International Nuclear Information System (INIS)

    Furukawa, Kazuo; Lecocq, A.; Kato, Yoshio; Mitachi, Kohshi.

    1990-01-01

    In the next century, the 'fission breeder' concept will not be practical to solve the global energy problems, including environmental and North-South problems. As a new measure, a simple rational Th molten salt breeding fuel cycle system, named 'Thorium Molten-Salt Nuclear Energy Synergetics (THORIMS-NES)', which composed of simple power stations and fissile producers, is proposed. This is effective to establish the essential improvement in issues of resources, safety, power-size flexibility, anti-nuclear proliferation and terrorism, radiowaste, economy, etc. securing the simple operation, maintenance, chemical processing, and rational breeding fuel cycle. As examples, 155 MWe fuel self-sustaining power station 'FUJI-II', 7 MWe pilot-plant 'miniFUJI-II', 1 GeV-300 mA proton Accelerator Molten-Salt Breeder 'AMSB', and their combined fuel cycle system are explained. (author)

  7. Experimental studies of actinides in molten salts

    Energy Technology Data Exchange (ETDEWEB)

    Reavis, J.G.

    1985-06-01

    This review stresses techniques used in studies of molten salts containing multigram amounts of actinides exhibiting intense alpha activity but little or no penetrating gamma radiation. The preponderance of studies have used halides because oxygen-containing actinide compounds (other than oxides) are generally unstable at high temperatures. Topics discussed here include special enclosures, materials problems, preparation and purification of actinide elements and compounds, and measurements of various properties of the molten volts. Property measurements discussed are phase relationships, vapor pressure, density, viscosity, absorption spectra, electromotive force, and conductance. 188 refs., 17 figs., 6 tabs.

  8. Experimental studies of actinides in molten salts

    International Nuclear Information System (INIS)

    Reavis, J.G.

    1985-06-01

    This review stresses techniques used in studies of molten salts containing multigram amounts of actinides exhibiting intense alpha activity but little or no penetrating gamma radiation. The preponderance of studies have used halides because oxygen-containing actinide compounds (other than oxides) are generally unstable at high temperatures. Topics discussed here include special enclosures, materials problems, preparation and purification of actinide elements and compounds, and measurements of various properties of the molten volts. Property measurements discussed are phase relationships, vapor pressure, density, viscosity, absorption spectra, electromotive force, and conductance. 188 refs., 17 figs., 6 tabs

  9. Metal Oxide Solubility and Molten Salt Corrosion.

    Science.gov (United States)

    1982-03-29

    soluble oxides that relations like eq. (3) are significant. The oxides of several metal oxides have been found to be amphoteric , i.e., their solution...METAL OXIDE SOLUBILITY AND MOLTEN SALT CORROSION.(U) MAR 82 K H STERN UNCLASSI E DL R L-4772NL EL .2. MICROCOPY RESOLUTION TEST CHART NATIONAL BURALU...METAL OXIDE SOLUBILITY AND MOLTEN SALT Interim report on a continuing CORROSION NRL problem. S. PERFORMING a4. REPORT NUMlER 7. AuTtwORr) S. CONTRACT OR

  10. Process for recovering tritium from molten lithium metal

    Science.gov (United States)

    Maroni, Victor A.

    1976-01-01

    Lithium tritide (LiT) is extracted from molten lithium metal that has been exposed to neutron irradiation for breeding tritium within a thermonuclear or fission reactor. The extraction is performed by intimately contacting the molten lithium metal with a molten lithium salt, for instance, lithium chloride - potassium chloride eutectic to distribute LiT between the salt and metal phases. The extracted tritium is recovered in gaseous form from the molten salt phase by a subsequent electrolytic or oxidation step.

  11. Exergetic, economic, and environmental evaluations and multi-objective optimization of an internal-reforming SOFC-gas turbine cycle coupled with a Rankine cycle

    International Nuclear Information System (INIS)

    Aminyavari, Mehdi; Mamaghani, Alireza Haghighat; Shirazi, Ali; Najafi, Behzad; Rinaldi, Fabio

    2016-01-01

    Highlights: • An exergetic-economic-environmental analysis of an SOFC-GT-ST plant was performed. • Exergetic efficiency and total cost rate of the plant were considered as objectives. • Multi-objective optimization was conducted to obtain a set of optimal solutions. • Exergy destruction rate and capital cost of components of the plant were determined. • The Rankine bottoming cycle enhanced the exergetic efficiency of the plant by 8.84%. - Abstract: In the present study, a detailed thermodynamic model for an internal-reforming solid oxide fuel cell-gas turbine (SOFC-GT) hybrid system integrated with a Rankine (steam) cycle is developed, and exergetic, economic and environmental analyses have been carried out on the plant. Considering the exergetic efficiency and the total cost rate of the system as conflicting objectives, a multi-objective optimization of the system is conducted to determine the optimal design point of the plant. A set of optimal solutions (Pareto front) is achieved, each of which is a trade-off between the chosen objectives. Finally, TOPSIS (Technique for Order Preference by Similarity to an Ideal Solution) decision-making method is used to choose the final optimal design parameters. The results demonstrate that the final optimal design of the proposed plant leads to an exergetic efficiency of 65.11% and total cost rate of 0.13745 €/s. Furthermore, the optimization results reveal that the integration of the Rankine cycle with the SOFC-GT system has led to an 8.84% improvement in the total exergetic efficiency of the plant, producing additional 8439.2 MW h of electricity and avoiding ∼5900 metric tons of carbon dioxide emissions annually.

  12. Steam Reformer With Fibrous Catalytic Combustor

    Science.gov (United States)

    Voecks, Gerald E.

    1987-01-01

    Proposed steam-reforming reactor derives heat from internal combustion on fibrous catalyst. Supplies of fuel and air to combustor controlled to meet demand for heat for steam-reforming reaction. Enables use of less expensive reactor-tube material by limiting temperature to value safe for material yet not so low as to reduce reactor efficiency.

  13. Teachers' Experiences of Science Curriculum Reform

    Science.gov (United States)

    Ryder, Jim; Banner, Indira; Homer, Matt

    2014-01-01

    We report on a three-year study of teachers' experiences of a major reform of the science National Curriculum for 14- to 16-year-olds in England. Teachers' responses to this curriculum reform were guided by: "personal" aims and biography; "internal" features of their workplace such as departmental collegiality; and…

  14. Tariff-Tax Reforms and Market Access

    DEFF Research Database (Denmark)

    Kreickemeier, Udo; Raimondos-Møller, Pascalis

    2006-01-01

    paper examines whether the country that implements such a reform ends up opening up its markets to international trade, i.e. whether its market access improves. It is shown that this is not necessarily so. We also show that, comparing to the reform of only tariffs, the tariff-tax reform is a less......Reducing tariffs and increasing consumption taxes is a standard IMF advice to countries that want to open up their economy without hurting government finances. Indeed, theoretical analysis of such a tariff-tax reform shows an unambiguous increase in welfare and government revenues. The present...... efficient proposal to follow both as far as it concerns market access and welfare.JEL code: F13, H20.Keywords: Market access; tariff reform, consumption tax reform....

  15. Electrochemistry of zirconium in molten chlorides

    NARCIS (Netherlands)

    Xu, L.; Xiao, Y; Xu, Q; Song, Qiushi; Yang, Y.

    2017-01-01

    In this work, the electrochemical behavior of zirconium was studied on an inert molybdenum electrode at 550 °C in a LiCl-KCl-K2ZrF6 molten salt system, which is considered as an ideal electrolyte for the zirconium electrorefining process. Several transient electrochemical

  16. Recent electroanalytical studies in molten fluorides

    International Nuclear Information System (INIS)

    Manning, D.L.; Mamantov, G.

    1976-01-01

    This paper summarizes the voltametric and chronopotentiometric studies of Bi, Fe, Te, oxide and U(IV)/U(III) ratio determinations in molten LiF--BeF 2 --ThF 4 (72-16-12 mole percent) and LiF--BeF 2 --ZrF 4 (65.6-29.4-5.0 mole percent). 54 references, 11 figures

  17. On Electromagnetic Stirring of Molten Metals

    Czech Academy of Sciences Publication Activity Database

    Doležel, Ivo; Šolín, Pavel; Zítka, M.; Ulrych, B.

    2005-01-01

    Roč. 50, č. 1 (2005), s. 35-51 ISSN 0001-7043 R&D Projects: GA ČR(CZ) GA102/03/0047; GA ČR(CZ) GA102/05/0629 Institutional research plan: CEZ:AV0Z20570509 Keywords : electromagnetic stirring * molten metal * induction heating Subject RIV: JA - Electronics ; Optoelectronics, Electrical Engineering

  18. Arbitration Reform

    Directory of Open Access Journals (Sweden)

    Svetlana Stepurina

    2017-01-01

    Full Text Available УДК 347.73:341.63Subject. This informational article highlights recent changes to the Russian legislation on arbitration.Purpose. To highlight the most important aspects of arbitration law reform, and examines the effects they will have on the development of arbitration in RussiaMethodology. The author uses a formal-legal method.Results, scope of application. The author distinguishes the difference between constantly acting arbitration courts and arbitration courts ad hoc. The special status of a number of arbitration institutions (the ICAC and MAC at the Russian Chamber of Commerce and Industry, is contrary to the constitutional principle of equality under the law. A major achievement of the new legislation on arbitration courts is expanding the range arbitrarily disputes.Conclusions. The new legislation more clearly prescribed the interaction of arbitration and state courts, including requiring the latter to promote the arbitrators, acting under the regulations of the permanent arbitration institutions in obtaining evidence.In addition, the reform of the arbitration law have left aside the problem of improving the quality of judicial control over arbitration decisions.The arbitration law will still be able to improve the arbitration, to enhance its credibility and attractiveness for the participants of civil turnover.

  19. Heat transfer behavior of molten nitrate salt

    Science.gov (United States)

    Das, Apurba K.; Clark, Michael M.; Teigen, Bard C.; Fiveland, Woodrow A.; Anderson, Mark H.

    2016-05-01

    The usage of molten nitrate salt as heat transfer fluid and thermal storage medium decouples the generation of electricity from the variable nature of the solar resource, allowing CSP plants to avoid curtailment and match production with demand. This however brings some unique challenges for the design of the molten salt central receiver (MSCR). An aspect critical to the use of molten nitrate (60wt%/40wt% - NaNO3/KNO3) salt as heat transfer fluid in the MSCR is to understand its heat transfer behavior. Alstom collaborated with the University of Wisconsin to conduct a series of experiments and experimentally determined the heat transfer coefficients of molten nitrate salt up to high Reynolds number (Re > 2.0E5) and heat flux (q″ > 1000 kW/m2), conditions heretofore not reported in the literature. A cartridge heater instrumented with thermocouples was installed inside a stainless steel pipe to form an annular test section. The test section was installed in the molten salt flow loop at the University of Wisconsin facility, and operated over a range of test conditions to determine heat transfer data that covered the expected operating regime of a practical molten salt receiver. Heat transfer data were compared to widely accepted correlations found in heat transfer literature, including that of Gnielinski. At lower Reynolds number conditions, the results from this work concurred with the molten salt heat transfer data reported in literature and followed the aforementioned correlations. However, in the region of interest for practical receiver design, the correlations did not accurately model the experimentally determined heat transfer data. Two major effects were observed: (i) all other factors remaining constant, the Nusselt numbers gradually plateaued at higher Reynolds number; and (ii) at higher Reynolds number a positive interaction of heat flux on Nusselt number was noted. These effects are definitely not modeled by the existing correlations. In this paper a new

  20. [International overview of psychiatric reform].

    Science.gov (United States)

    Desviat, Manuel

    2011-12-01

    There has been an increased incidence of mental health problems around the world while psychiatry is experiencing a crisis that concerns its own identity and the definition of the scope of its work. After more than half a century of deinstitutionalized community policies, neoliberal globalization is leading to changes that undermine public attention on mental health, particularly of the disorders that require greater social attention. There have been changes in the responsibility of the state and changes in the type of demand and in the way of understanding disease and its treatment. At the time, compared to the medicalization of society that mediates the expression of needs in health, user movements are beginning to emerge demanding autonomy, full citizenship, empowerment, recovery and advocacy.

  1. Thorium Molten Salt Nuclear Energy Synergetic System (THORIMS-NES)

    International Nuclear Information System (INIS)

    Yoshioka, Ritsuo; Mitachi, Koshi

    2013-01-01

    The authors have been promoting nuclear energy technology based on thorium molten salt as Thorium Molten Salt Nuclear Energy Synergetic System (THORIMS-NES). This system is a combination of fission power reactor of Molten Salt Reactor (MSR), and Accelerator Molten Salt Breeder (AMSB) for production of fissile 233 U with connecting chemical processing facility. In this paper, concept of THORIMS-NES, advantages of thorium and molten salt recent MSR design results such as FUJI-U3 using 233 U fuel, FUJI-Pu, large sized super-FUJI, pilot plant miniFUJI, AMSB, and chemical processing facility are described. (author)

  2. Analysis of molten salt thermal-hydraulics using computational fluid dynamics

    International Nuclear Information System (INIS)

    Yamaji, B.; Csom, G.; Aszodi, A.

    2003-01-01

    To give a good solution for the problem of high level radioactive waste partitioning and transmutation is expected to be a pro missing option. Application of this technology also could extend the possibilities of nuclear energy. Large number of liquid-fuelled reactor concepts or accelerator driven subcritical systems was proposed as transmutors. Several of these consider fluoride based molten salts as the liquid fuel and coolant medium. The thermal-hydraulic behaviour of these systems is expected to be fundamentally different than the behaviour of widely used water-cooled reactors with solid fuel. Considering large flow domains three-dimensional thermal-hydraulic analysis is the method seeming to be applicable. Since the fuel is the coolant medium as well, one can expect a strong coupling between neutronics and thermal-hydraulics too. In the present paper the application of Computational Fluid Dynamics for three-dimensional thermal-hydraulics simulations of molten salt reactor concepts is introduced. In our past and recent works several calculations were carried out to investigate the capabilities of Computational Fluid Dynamics through the analysis of different molten salt reactor concepts. Homogenous single region molten salt reactor concept is studied and optimised. Another single region reactor concept is introduced also. This concept has internal heat exchanges in the flow domain and the molten salt is circulated by natural convection. The analysis of the MSRE experiment is also a part of our work since it may form a good background from the validation point of view. In the paper the results of the Computational Fluid Dynamics calculations with these concepts are presented. In the further work our objective is to investigate the thermal-hydraulics of the multi-region molten salt reactor (Authors)

  3. Development of a safety analysis code for molten salt reactors

    International Nuclear Information System (INIS)

    Zhang Dalin; Qiu Suizheng; Su Guanghui

    2009-01-01

    The molten salt reactor (MSR) well suited to fulfill the criteria defined by the Generation IV International Forum (GIF) is presently revisited all around the world because of different attractive features of current renewed relevance. The MSRs are characterized by using the fluid-fuel, so that their technologies are fundamentally different from those used in the conventional solid-fuel reactors. In this work, in particular, the attention is focused on the safety characteristic analysis of the MSRs, in which a point kinetic model considering the flow effects of the fuel salt is established for the MSRs and calculated by developing a microcomputer code coupling with a simplified heat transfer model in the core. The founded models and developed code are applied to analyze the safety characteristics of the molten salt actinide recycler and transmuter system (MOSART) by simulating three types of basic transient conditions including the unprotected loss of flow, unprotected overcooling accident and unprotected transient overpower. Some reasonable results are obtained for the MOSART, which show that the MOSART conceptual design is an inherently stable reactor design. The present study provides some valuable information for the research and design of the new generation MSRs.

  4. Steepest Ascent Tariff Reform

    DEFF Research Database (Denmark)

    Raimondos-Møller, Pascalis; Woodland, Alan

    2014-01-01

    The policy reform literature is primarily concerned with the construction of reforms that yield welfare gains. By contrast, this paper’s contribution is to develop a theoretical concept for which the focus is upon the sizes of welfare gains accruing from policy reforms rather than upon their signs....... In undertaking this task, and by focusing on tariff reforms, we introduce the concept of a steepest ascent policy reform, which is a locally optimal reform in the sense that it achieves the highest marginal gain in utility of any feasible local reform. We argue that this reform presents itself as a natural...... benchmark for the evaluation of the welfare effectiveness of other popular tariff reforms such as the proportional tariff reduction and the concertina rules, since it provides the maximal welfare gain of all possible local reforms. We derive properties of the steepest ascent tariff reform, construct...

  5. Feet sunk in molten aluminium: The burn and its prevention.

    Science.gov (United States)

    Alonso-Peña, David; Arnáiz-García, María Elena; Valero-Gasalla, Javier Luis; Arnáiz-García, Ana María; Campillo-Campaña, Ramón; Alonso-Peña, Javier; González-Santos, Jose María; Fernández-Díaz, Alaska Leonor; Arnáiz, Javier

    2015-08-01

    Nowadays, despite improvements in safety rules and inspections in the metal industry, foundry workers are not free from burn accidents. Injuries caused by molten metals include burns secondary to molten iron, aluminium, zinc, copper, brass, bronze, manganese, lead and steel. Molten aluminium is one of the most common causative agents of burns (60%); however, only a few publications exist concerning injuries from molten aluminium. The main mechanisms of lesion from molten aluminium include direct contact of the molten metal with the skin or through safety apparel, or when the metal splash burns through the pants and rolls downward along the leg. Herein, we report three cases of deep dermal burns after 'soaking' the foot in liquid aluminium and its evolutive features. This paper aims to show our experience in the management of burns due to molten aluminium. We describe the current management principles and the key features of injury prevention. Copyright © 2014 Elsevier Ltd and ISBI. All rights reserved.

  6. A comparison of higher education reforms in Egypt and Morocco

    OpenAIRE

    Kohstall, Florian

    2012-01-01

    This doctoral thesis examines the impact of international aid agencies on the reform agenda of North African countries. It analyses and compares the paths of higher education reform (1997-2007) in Egypt and Morocco, using analytical instruments pertaining to new approaches in public policy theory. For a long time, both countries appeared relatively immune against reform pressure from outside. Still, the analysis of their reform processes shows that the internationalization of higher educa...

  7. Catalytic Partial Oxidation Reforming of JP8 AND S8

    Science.gov (United States)

    2007-06-01

    Heats of Combustion for fuels and reformate..................................................... 44 Table 5: Design points for Aspen reformer with...value for CO. By reforming JP8 to produce hydrogen , fuels burn more efficiently and emissions are reduced. The current internal combustion engines are...in production of hydrogen as well as a decrease in the amount of heat used in the steam reforming. 19 III. Methodology Aspen Fuel Processor

  8. WORLD BANK: Status of Grievance Process Reform

    National Research Council Canada - National Science Library

    1999-01-01

    In June 1998, in response, to concerns about the fairness of its employee grievance process and as part of a broader effort to reform its human resource policies, the World Bank appointed an internal...

  9. Reform in Turkish Elementary Mathematics Curriculum

    OpenAIRE

    BABADOĞAN, Cem; OLKUN, Sinan

    2006-01-01

    Disappointed from such major international studies as TIMSS, PISA, PIRLS andsome internal indicators such as national university entrance examination, the Turkish Ministry ofNational Education initiated a massive reform movement in education. These reforms includedeveloping new curricula for both elementary and secondary education and developing teachercompetencies. The purpose of this paper is to present an evaluation of the elementary schoolmathematics curriculum, which is a part of the ref...

  10. 26 CFR 301.9100-12T - Various elections under the Tax Reform Act of 1976.

    Science.gov (United States)

    2010-04-01

    ... 26 Internal Revenue 18 2010-04-01 2010-04-01 false Various elections under the Tax Reform Act of... Internal Revenue Laws § 301.9100-12T Various elections under the Tax Reform Act of 1976. (a) Elections covered by temporary rules. The sections of the Internal Revenue Code of 1954, or of the Tax Reform Act of...

  11. Molten-salt reactor information system

    International Nuclear Information System (INIS)

    Haubenreich, P.N.; Cardwell, D.W.; Engel, J.R.

    1975-06-01

    The Molten-Salt Reactor Information System (MSRIS) is a computer-based file of abstracts of documents dealing with the technology of molten-salt reactors. The file is stored in the IBM-360 system at ORNL, and may be searched through the use of established interactive computer programs from remote terminals connected to the computer via telephone lines. The system currently contains 373 entries and is subject to updating and expansion as additional information is developed. The nature and general content of the data file, a general approach for obtaining information from it, and the manner in which material is added to the file are described. Appendixes provide the list of keywords currently in use, the subject categories under which information is filed, and simplified procedures for searching the file from remote terminals. (U.S.)

  12. Mixing of zeolite powders and molten salt

    International Nuclear Information System (INIS)

    Pereira, C.; Zyryanov, V.N.; Lewis, M.A.; Ackerman, J.P.

    1996-01-01

    Transuranics and fission products in a molten salt can be incorporated into zeolite A by an ion exchange process and by a batch mixing or blending process. The zeolite is then mixed with glass and consolidated into a monolithic waste form for geologic disposal. Both processes require mixing of zeolite powders with molten salt at elevated temperatures (>700 K). Complete occlusion of salt and a uniform distribution of chloride and fission products are desired for incorporation of the powders into the final waste form. The relative effectiveness of the blending process was studied over a series of temperature, time, and composition profiles. The major criteria for determining the effectiveness of the mixing operations were the level and uniformity of residual free salt in the mixtures. High operating temperatures (>775 K) improved salt occlusion. Reducing the chloride levels in the mixture to below 80% of the full salt capacity of the zeolite significantly reduced the free salt level in the final product

  13. 26 CFR 1.9006 - Statutory provisions; Tax Reform Act of 1969.

    Science.gov (United States)

    2010-04-01

    ... 26 Internal Revenue 13 2010-04-01 2010-04-01 false Statutory provisions; Tax Reform Act of 1969. 1...) INCOME TAX (CONTINUED) INCOME TAXES Tax Reform Act of 1969 § 1.9006 Statutory provisions; Tax Reform Act of 1969. Section 946 of the Tax Reform Act of 1969 (83 Stat. 729) provides as follows: Sec. 946...

  14. The politics of immigration reform.

    Science.gov (United States)

    Simpson, A K

    1984-01-01

    The US is the target for international migration, now more than ever. Population growth and economic stragnation in the Third World are increasing the pressures for out-migration, and current immigration law is wholly incapable of responding to the ever increasing flow of illegal immigrants. Border apprehensions of illegal aliens in the US were up 40% during 1983, and total apprehensions reached 1.25 million by the year's end. Recent public opinion polls have disclosed that an overwhelming majority of the American public demands immigration reform, and yet we as a nation have been distinctly unwilling or unable to respond to this clear public sentiment. This paper discusses the politics of the "Simpson-Mazzoli" Immigration Reform and Control Act, previous immigration legislation, current counterproposals for US immigration policy, and the political realities of immigration reform.

  15. Molten-Salt Depleted-Uranium Reactor

    OpenAIRE

    Dong, Bao-Guo; Dong, Pei; Gu, Ji-Yuan

    2015-01-01

    The supercritical, reactor core melting and nuclear fuel leaking accidents have troubled fission reactors for decades, and greatly limit their extensive applications. Now these troubles are still open. Here we first show a possible perfect reactor, Molten-Salt Depleted-Uranium Reactor which is no above accident trouble. We found this reactor could be realized in practical applications in terms of all of the scientific principle, principle of operation, technology, and engineering. Our results...

  16. Electrochemical studies in molten sodium fluoroborate

    International Nuclear Information System (INIS)

    Brigaudeau, M.; Wagner, J.F.

    1979-01-01

    Physical properties of sodium fluoroborate are recalled and first results obtained during experimental study of molten NaBF 4 are exposed. The system Cu/CuF is used as an indicator of fluoride ion activity and dissociation constant of the solvent is determined by adding NaF to NaBF 4 saturated with BF 3 at a pressure of 1 atm and found equal to 2.7x10 -3 [fr

  17. Drug Pricing Reforms

    DEFF Research Database (Denmark)

    Kaiser, Ulrich; Mendez, Susan J.; Rønde, Thomas

    2015-01-01

    Reference price systems for prescription drugs have found widespread use as cost containment tools. Under such regulatory regimes, patients co-pay a fraction of the difference between pharmacy retail price of the drug and a reference price. Reference prices are either externally (based on drug...... prices in other countries) or internally (based on domestic drug prices) determined. In a recent study, we analysed the effects of a change from external to internal reference pricing in Denmark in 2005, finding that the reform led to substantial reductions in prices, producer revenues, and expenditures...... for patients and the health insurance system. We also estimated an increase in consumer welfare but the size effect depends on whether or not perceived quality differences between branded and other drugs are taken into account....

  18. Destruction of high explosives and wastes containing high explosives using the molten salt destruction process

    International Nuclear Information System (INIS)

    Upadhye, R.S.; Brummond, W.A.; Pruneda, C.O.

    1992-01-01

    This paper reports the Molten Salt Destruction (MSD) Process which has been demonstrated for the destruction of HE and HE-containing wastes. MSD has been used by Rockwell International and by Anti-Pollution Systems to destroy hazardous wastes. MSD converts the organic constituents (including the HE) of the waste into non-hazardous substances such as carbon dioxide, nitrogen and water. In the case of HE-containing mixed wastes, any actinides in the waste are retained in the molten salt, thus converting the mixed wastes into low-level wastes. (Even though the MSD process is applicable to mixed wastes, this paper will emphasize HE-treatment.) The destruction of HE is accomplished by introducing it, together with oxidant gases, into a crucible containing a molten salt, such as sodium carbonate, or a suitable mixture of the carbonates of sodium, potassium, lithium and calcium. The temperature of the molten salt can be between 400 to 900 degrees C. The combustible organic components of the waste react with oxygen to produce carbon dioxide, nitrogen and steam

  19. Thermal Characterization of Molten Salt Systems

    Energy Technology Data Exchange (ETDEWEB)

    Toni Y. Gutknecht; Guy L. Fredrickson

    2011-09-01

    The phase stability of molten salts in an electrorefiner (ER) may be adversely affected by the buildup of sodium, fission products, and transuranics in the electrolyte. Potential situations that need to be avoided are the following: (1) salt freezing due to an unexpected change in the liquidus temperature, (2) phase separation or non-homogeneity of the molten salt due to the precipitation of solids or formation of immiscible liquids, and (3) any mechanism that can result in the separation and concentration of fissile elements from the molten salt. Any of these situations would result in an off-normal condition outside the established safety basis for electrorefiner (ER) operations. The stability (and homogeneity) of the phases can potentially be monitored through the thermal characterization of the salts, which can be a function of impurity concentration. This report describes the experimental results of typical salts compositions, which consist of chlorides of potassium, lithium, strontium, samarium, praseodymium, lanthanum, barium, cerium, cesium, neodymium, sodium and gadolinium chlorides as a surrogate for both uranium and plutonium, used for the processing of used nuclear fuels.

  20. Supported Molten Metal Membranes for Hydrogen Separation

    Energy Technology Data Exchange (ETDEWEB)

    Datta, Ravindra [Worcester Polytechnic Inst., Worcester, MA (United States). Dept. of Chemical Engineering; Ma, Yi Hua [Worcester Polytechnic Inst., Worcester, MA (United States). Dept. of Chemical Engineering; Yen, Pei-Shan [Worcester Polytechnic Inst., Worcester, MA (United States). Dept. of Chemical Engineering; Deveau, Nicholas [Worcester Polytechnic Inst., Worcester, MA (United States). Dept. of Chemical Engineering; Fishtik, Ilie [Worcester Polytechnic Inst., Worcester, MA (United States). Dept. of Chemical Engineering; Mardilovich, Ivan [Worcester Polytechnic Inst., Worcester, MA (United States). Dept. of Chemical Engineering

    2013-09-30

    We describe here our results on the feasibility of a novel dense metal membrane for hydrogen separation: Supported Molten Metal Membrane, or SMMM. The goal in this work was to develop these new membranes based on supporting thin films of low-melting, non- precious group metals, e.g., tin (Sn), indium (In), gallium (Ga), or their alloys, to provide a flux and selectivity of hydrogen that rivals the conventional but substantially more expensive palladium (Pd) or Pd alloy membranes, which are susceptible to poisoning by the many species in the coal-derived syngas, and further possess inadequate stability and limited operating temperature range. The novelty of the technology presented numerous challenges during the course of this project, however, mainly in the selection of appropriate supports, and in the fabrication of a stable membrane. While the wetting instability of the SMMM remains an issue, we did develop an adequate understanding of the interaction between molten metal films with porous supports that we were able to find appropriate supports. Thus, our preliminary results indicate that the Ga/SiC SMMM at 550 °C has a permeance that is an order of magnitude higher than that of Pd, and exceeds the 2015 DOE target. To make practical SMM membranes, however, further improving the stability of the molten metal membrane is the next goal. For this, it is important to better understand the change in molten metal surface tension and contact angle as a function of temperature and gas-phase composition. A thermodynamic theory was, thus, developed, that is not only able to explain this change in the liquid-gas surface tension, but also the change in the solid-liquid surface tension as well as the contact angle. This fundamental understanding has allowed us to determine design characteristics to maintain stability in the face of changing gas composition. These designs are being developed. For further progress, it is also important to understand the nature of solution and

  1. Tritium loss in molten flibe systems

    International Nuclear Information System (INIS)

    Longhurst, G.R.; Anderl, R.A.; Scott Willms, R.

    2000-01-01

    An emerging issue relative to beryllium technology in fusion involves tritium interactions with molten beryllium-bearing salts. Innovative designs for fusion reactors, both magnetic and inertially confined, feature the molten salt mixture 2LiF.BeF 2 , commonly called Flibe, as a tritium breeder and coolant. Tritium is bred in the Flibe as neutrons from the plasma are absorbed by Li atoms, which then transmute to tritium and helium. Transmutation of tritium from Be also occurs. Among the issues to be resolved for such coolant systems is the potential loss of tritium from the Flibe coolant to the walls of the system, particularly through heat exchanger tubes, and from there into secondary coolants or working fluids and the environment. Effectively removing tritium from Flibe in clean-up units is also important. In quiescent or low Reynolds number flow, tritium movement through Flibe is governed by diffusion. For Flibe in turbulent flow, as in heat exchanger tubes, transport is by turbulent mixing, and the same flow conditions and structural design features that maximize heat transfer to the heat exchanger walls will enhance the transport of tritium to those same surfaces. Analyses have been performed to estimate the fractional loss of tritium through heat exchanger tubes and release rates from Flibe droplets in vacuum disengagers in molten Flibe systems. The calculations suggest unacceptably large losses of tritium through heat exchanger tubes. The gravity of the implications of these estimates calls for experimental verification to determine if tritium losses through molten Flibe heat exchangers or other Flibe systems can really be so high and whether vacuum disengagers will really work. There is also a need for better information on evolution of tritium from Flibe droplets in a vacuum. Several experiments are presently being planned to address these issues and are discussed. These include experiments to induce tritium in Flibe using spontaneous fission neutrons

  2. Molten metal feed system controlled with a traveling magnetic field

    International Nuclear Information System (INIS)

    Praeg, W.F.

    1991-01-01

    This patent describes a continuous metal casting system in which the feed of molten metal controlled by means of a linear induction motor capable of producing a magnetic traveling wave in a duct that connects a reservoir of molten metal to a caster. The linear induction motor produces a traveling magnetic wave in the duct in opposition to the pressure exerted by the head of molten metal in the reservoir

  3. Concept of the demonstration molten salt unit for the transuranium elements transmutation

    International Nuclear Information System (INIS)

    Alekseev, P.; Dudnikov, A.; Prusakov, V.; Subbotin, S.; Zakirov, R.; Lelek, V.; Peka, I.

    1999-01-01

    In this report it is considered fluorine reprocessing of spent fuel and fluoride molten salt reactor in critical and subcritical modes for plutonium and minor actinides burning. International collaboration for creation of such system is proposed. It is without any doubt that additional neutron source in the core will have positive influence on the transmutation process in the reactor. On the other side there is a lot of problems to realize it technically and to ensure stable work of the whole complex. (Authors)

  4. Studies on components for a molten salt reactor

    International Nuclear Information System (INIS)

    Nejedly, M.; Matal, O.

    2003-01-01

    The aim is contribute to a design of selected components of molten salt reactors with fuel in the molten fluoride salt matrix. Molten salt reactors (MSRs) permit the utilization of plutonium and minor actinides as new nuclear fuel from a traditional nuclear power station with production of electric energy. Results of preliminary feasibility studies of an intermediate heat exchanger, a small power molten salt pump and a modular conception of a steam generator for a demonstration unit of the MSR (30 MW) are summarized. (author)

  5. Crust formation and its effect on the molten pool coolability

    Energy Technology Data Exchange (ETDEWEB)

    Park, R.J.; Lee, S.J.; Sim, S.K. [Korea Atomic Energy Research Institute, Taejon (Korea, Republic of)

    1995-09-01

    Experimental and analytical studies of the crust formation and its effect on the molten pool coolability have been performed to examine the crust formation process as a function of boundary temperatures as well as to investigate heat transfer characteristics between molten pool and overlying water in order to evaluate coolability of the molten pool. The experimental test results have shown that the surface temperature of the bottom plate is a dominant parameter in the crust formation process of the molten pool. It is also found that the crust thickness of the case with direct coolant injection into the molten pool is greater than that of the case with a heat exchanger. Increasing mass flow rate of direct coolant injection to the molten pool does not affect the temperature of molten pool after the crust has been formed in the molten pool because the crust behaves as a thermal barrier. The Nusselt number between the molten pool and the coolant of the case with no crust formation is greater than that of the case with crust formation. The results of FLOW-3D analyses have shown that the temperature distribution contributes to the crust formation process due to Rayleigh-Benard natural convection flow.

  6. Accelerator molten-salt breeding and thorium fuel cycle

    International Nuclear Information System (INIS)

    Furukawa, Kazuo; Nakahara, Yasuaki; Kato, Yoshio; Ohno, Hideo; Mitachi, Kohshi.

    1990-01-01

    The recent efforts at the development of fission energy utilization have not been successful in establishing fully rational technology. A new philosophy should be established on the basis of the following three principles: (1) thorium utilization, (2) molten-salt fuel concept, and (3) separation of fissile-breeding and power-generating functions. Such philosophy is called 'Thorium Molten-Salt Nuclear Energy Synergetics [THORIMS-NES]'. The present report first addresses the establishment of 233 U breeding fuel cycle, focusing on major features of the Breeding and Chemical Processing Centers and a small molten-salt power station (called FUJI-II). The development of fissile producing breeders is discussed in relation to accelerator molten-salt breeder (AMSB), impact fusion molten-salt breeder, and inertial-confined fusion hybrid molten-salt breeder. Features of the accelerator molten-salt breeder are described, focusing on technical problems with accelerator breeders (or spallators), design principle of the accelerator molten-salt breeder, selection of molten salt compositions, and nuclear- and reactor-chemical aspects of AMSB. Discussion is also made of further research and development efforts required in the future for AMSB. (N.K.)

  7. China's Health Reform Update.

    Science.gov (United States)

    Liu, Gordon G; Vortherms, Samantha A; Hong, Xuezhi

    2017-03-20

    China experienced both economic and epistemological transitions within the past few decades, greatly increasing demand for accessible and affordable health care. These shifts put significant pressure on the existing outdated, highly centralized bureaucratic system. Adjusting to growing demands, the government has pursued a new round of health reforms since the late 2000s; the main goals are to reform health care financing, essential drug policies, and public hospitals. Health care financing reform led to universal basic medical insurance, whereas the public hospital reform required more complex measures ranging from changes in regulatory, operational, and service delivery settings to personnel management. This article reviews these major policy changes and the literature-based evidence of the effects of reforms on cost, access, and quality of care. It then highlights the outlook for future reforms. We argue that a better understanding of the unintended consequences of reform policies and of how practitioners' and patients' interests can be better aligned is essential for reforms to succeed.

  8. Molten salt reactors and molten salt carriers for industrial heat supply

    International Nuclear Information System (INIS)

    Novikov, V.M.

    1987-01-01

    Structure of industrial heat needs has been analysed. It is shown that main part of heat consumers - 80% demands temperature level up to 600 0 C. Temperature rise from 600 0 C up to 950 0 C could add only about 3% of heat consumers. It is shown that molten salt reactors with out-let temperature 700 0 C meet these conditions optimally

  9. Electrorecovery of tantalum in molten fluorides

    International Nuclear Information System (INIS)

    Espinola, A.; Dutra, A.J.B.; Silva, F.T. da

    1988-01-01

    Considering the privileged situation of Brazil as a productor of tantaliferous minerals, the authors have in view the development of a technology for production of metallic tantalum via molten salts electrolysis; this has the advantage of improving the aggregate value of exportation products, additionally to tantalum oxide and tantalum concentrates. Having in view the preliminary determintion of better conditions of temperature, electrolyte composition and current density for this process, electrolysis were conducted with a solvent composed of an eutetic mixture of lithium, sodium and potassium fluoride for dipotassium fluotantalate and occasionally for tantalum oxide. Current efficiencies as high as 83% were obtained in favoured conditions. (author) [pt

  10. Apparatus for controlling molten core debris

    International Nuclear Information System (INIS)

    Golden, M.P.; Tilbrook, R.W.; Heylmun, N.F.

    1972-01-01

    Disclosed is an apparatus for containing, cooling, diluting, dispersing and maintaining subcritical the molten core debris assumed to melt through the bottom of a nuclear reactor pressure vessel in the unlikely event of a core meltdown. The apparatus is basically a sacrificial bed system which includes an inverted conical funnel, a core debris receptacle including a spherical dome, a spherically layered bed of primarily magnesia bricks, a cooling system of zig-zag piping in graphite blocks about and below the bed and a cylindrical liner surrounding the graphite blocks including a steel shell surrounded by firebrick. Tantalum absorber rods are used in the receptacle and bed. 9 claims, 22 figures

  11. Applications of molten salts in plutonium processing

    International Nuclear Information System (INIS)

    Bowersox, D.F.; Christensen, D.C.; Williams, J.D.

    1987-01-01

    Plutonium is efficiently recovered from scrap at Los Alamos by a series of chemical reactions and separations conducted at temperatures ranging from 700 to 900 0 C. These processes usually employ a molten salt or salt eutectic as a heat sink and/or reaction medium. Salts for these operations were selected early in the development cycle. The selection criteria are being reevaluated. In this article we describe the processes now in use at Los Alamos and our studies of alternate salts and eutectics

  12. A Decade of Reform

    International Development Research Centre (IDRC) Digital Library (Canada)

    Ongoing waves of enterprise-management reforms,. – Broader economic and social reforms pertaining to the environment in which the enterprises operate;. – Ambitious efforts to upgrade the technology of enterprises through the procurement (often from abroad) of advanced production technology; and. – S&T reforms ...

  13. NiO-ScSZ and Ni 0.9Mg 0.1O-ScSZ-based anodes under internal dry reforming of simulated biogas mixtures

    Science.gov (United States)

    Shiratori, Y.; Sasaki, K.

    Solid oxide fuel cells (SOFCs) with NiO-ScSZ and Ni 0.9Mg 0.1O-ScSZ-based anodes were operated by directly feeding a fuel mixture of CH 4, CO 2 and N 2 (CH 4 to CO 2 ratio of 3:2). Stable operation under constant current load (200 mA cm -2) was achieved with a NiO-ScSZ type anode during 200 h operating hours at 900 °C. Less stable operation occurred with a Ni 0.9Mg 0.1O-ScSZ type anode. In the case of SOFC with Ni 0.9Mg 0.1O-ScSZ as the anode, the methane reforming activity was higher than that with NiO-ScSZ. This was explained by change in the microstructure promoting reforming reactions. However, the addition of MgO resulted in degradation of electrochemical performance due to increase in ohmic resistance of the anode material during operation.

  14. The effect of coupled mass transport and internal reforming on modeling of solid oxide fuel cells part II: Benchmarking transient response and dynamic model fidelity assessment

    Science.gov (United States)

    Albrecht, Kevin J.; Braun, Robert J.

    2016-02-01

    One- and 'quasi' two-dimensional (2-D) dynamic, interface charge transport models of a solid oxide fuel cell (SOFC) developed previously in a companion paper, are benchmarked against other models and simulated to evaluate the effects of coupled transport and chemistry. Because the reforming reaction can distort the concentration profiles of the species within the anode, a 'quasi' 2-D model that captures porous media mass transport and electrochemistry is required. The impact of a change in concentration at the triple-phase boundary is twofold wherein the local Nernst potential and anode exchange current densities are influenced, thereby altering the current density and temperature distributions of the cell. Thus, the dynamic response of the cell models are compared, and benchmarked against previous channel-level models to gauge the relative importance of capturing in-situ reforming phenomena on cell performance. Simulation results indicate differences in the transient electrochemical response for a step in current density where the 'quasi' 2-D model predicts a slower rise and fall in cell potential due to the additional volume of the porous media and mass transport dynamics. Delays in fuel flow rate are shown to increase the difference observed in the electrochemical response of the cells.

  15. Production of Oxygen from Lunar Regolith using Molten Oxide Electrolysis

    Science.gov (United States)

    Sibille, Laurent; Sadoway, Donald R.; Sirk, Aislinn; Tripathy, Prabhat; Melendez, Orlando; Standish, Evan; Dominquez, Jesus A.; Stefanescu, Doru M.; Curreri, Peter A.; Poizeau, Sophie

    2009-01-01

    This slide presentation reviews the possible use of molten oxide electrolysis to extract oxygen from the Lunar Regolith. The presentation asserts that molten regolith electrolysis has advanced to be a useful method for production of oxygen and metals in situ on the Moon. The work has demonstrated an 8 hour batch of electrolysis at 5 amps using Iridium inert anodes.

  16. Method of making molten carbonate fuel cell ceramic matrix tape

    Science.gov (United States)

    Maricle, Donald L.; Putnam, Gary C.; Stewart, Jr., Robert C.

    1984-10-23

    A method of making a thin, flexible, pliable matrix material for a molten carbonate fuel cell is described. The method comprises admixing particles inert in the molten carbonate environment with an organic polymer binder and ceramic particle. The composition is applied to a mold surface and dried, and the formed compliant matrix material removed.

  17. Advancing Molten Salts and Fuels at Sandia National Laboratories

    Energy Technology Data Exchange (ETDEWEB)

    Rodriguez, Salvador B. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

    2017-09-26

    SNL has a combination of experimental facilities, nuclear engineering, nuclear security, severe nuclear accidents, and nuclear safeguards expertise that can enable significant progress towards molten salts and fuels for Molten Salt Reactors (MSRs). The following areas and opportunities are discussed in more detail in this white paper.

  18. Heat balance of a molten carbonate fuel cell production hydrogen for a polymer electrolyte fuel cell-CoCell; Waermehaushalt einer Karbonat-Brennstoffzelle zur Wasserstoffherstellung fuer eine Polymerelektrolyt-Brennstoffzelle

    Energy Technology Data Exchange (ETDEWEB)

    Adamek, L.

    2006-10-17

    Molten carbonate fuel cells (MCFC) are being used in decentralised power plants, as they can reform hydrocarbon bound fuels internally, e.g. natural gas with a energy density of 10 kWh/m{sup 3} at standard conditions, and the efficiency of this mode of operation is around 50 %. However in comparison to other fuel cell systems the power density is only 5 kW/m{sup 3}. The power density of a polymerelectrolyte fuel cell (PEFC) is much higher (50 kW/m{sup 3}). These systems can be run with an efficiency of 50 %, too. Therefore they need hydrogen as a fuel, with an energy density of 2,9 kWh/m{sup 3} at standard conditions. Efficiency decreases to 35 to 40% using Methane as fuel, because of the reforming losses. The power density than is 6 kW/m3 and therefore as high as for a MCFC-system. Acombination of MCFC and PEFC, the so called CoCell, offers the following advantages: - A highly energetic, hydrocarbon based fuel can be used, e.g. Methane. - A high electrical efficiency is achieved. - The power density of this system is higher than for a fuel cell with reformer. In the CoCell the MCFC is working as electricity producing reformer for the PEFC. The off heat of the MCFC is used for reforming, whereby hydrogen is available, being utilised further in the power dense PEFC. The reforming capacity of the MCFC is limited by the internal heat balance. If the endothermic reforming consumes more heat than supplied by the material streams and the fuel cell waste heat, the stack cools down. The performance of such a combined fuel cell system has been evaluated in this thesis using the thermodynamic simulation software Aspen. Calculations reducing the utilisation in the MCFC by various heating techniques showed, that additional heat is supplied most efficiently by increasing the current density of the MCFC. Thereby the stack is heated electrically and the power density of the system is increased by the improved power density of the MCFC. The reduction of the utilisation is achieved

  19. Transient simulation of molten salt central receiver

    Science.gov (United States)

    Doupis, Dimitri; Wang, Chuan; Carcorze-Soto, Jorge; Chen, Yen-Ming; Maggi, Andrea; Losito, Matteo; Clark, Michael

    2016-05-01

    Alstom is developing concentrated solar power (CSP) utilizing 60/40wt% NaNO3-KNO3 molten salt as the working fluid in a tower receiver for the global renewable energy market. In the CSP power generation cycle, receivers undergo a daily cyclic operation due to the transient nature of solar energy. Development of robust and efficient start-up and shut-down procedures is critical to avoiding component failures due to mechanical fatigue resulting from thermal transients, thus maintaining the performance and availability of the CSP plant. The Molten Salt Central Receiver (MSCR) is subject to thermal transients during normal daily operation, a cycle that includes warmup, filling, operation, draining, and shutdown. This paper describes a study to leverage dynamic simulation and finite element analysis (FEA) in development of start-up, shutdown, and transient operation concepts for the MSCR. The results of the FEA also verify the robustness of the MSCR design to the thermal transients anticipated during the operation of the plant.

  20. Organic waste processing using molten salt oxidation

    Energy Technology Data Exchange (ETDEWEB)

    Adamson, M. G., LLNL

    1998-03-01

    Molten Salt Oxidation (MSO) is a thermal means of oxidizing (destroying) the organic constituents of mixed wastes, hazardous wastes, and energetic materials while retaining inorganic and radioactive constituents in the salt. For this reason, MSO is considered a promising alternative to incineration for the treatment of a variety of organic wastes. The U. S. Department of Energy`s Office of Environmental Management (DOE/EM) is currently funding research that will identify alternatives to incineration for the treatment of organic-based mixed wastes. (Mixed wastes are defined as waste streams which have both hazardous and radioactive properties.) One such project is Lawrence Livermore National Laboratory`s Expedited Technology Demonstration of Molten Salt Oxidation (MSO). The goal of this project is to conduct an integrated demonstration of MSO, including off-gas and spent salt treatment, and the preparation of robust solid final forms. Livermore National Laboratory (LLNL) has constructed an integrated pilot-scale MSO treatment system in which tests and demonstrations are presently being performed under carefully controlled (experimental) conditions. The system consists of a MSO process vessel with dedicated off-gas treatment, a salt recycle system, feed preparation equipment, and equipment for preparing ceramic final waste forms. In this paper we describe the integrated system and discuss its capabilities as well as preliminary process demonstration data. A primary purpose of these demonstrations is to identify the most suitable waste streams and waste types for MSO treatment.

  1. Advances in molten salt electrochemistry towards future energy systems

    International Nuclear Information System (INIS)

    Ito, Yasuhiko

    2005-01-01

    This review article describes some selected novel molten salt electrochemical processes which have been created/developed by the author and his coworkers, with emphasis on the applications towards future energy systems. After showing a perspective of the applications of molten salt electrochemistry from the viewpoints of energy and environment, several selected topics are described in detail, which include nitride fuel cycle in a nuclear field, hydrogen energy system coupled with ammonia economy, thermally regenerative fuel cell systems, novel Si production process for solar cell and novel molten salt electrochemical processes for various energy and environment related functional materials including nitrides, rare earth-transition metal alloys, fine particles obtained by plasma-induced electrolysis, and carbon film. And finally, the author stresses again, the importance and potential of molten salt electrochemistry, and encourages young students, scientists and researchers to march in a procession hand in hand towards a bright future of molten salts. (author)

  2. Fundamental stack and system issues in molten carbonate fuel cell development

    Science.gov (United States)

    Williams, M. C.; Parsons, E. L., Jr.; Mayfield, M. J.

    Stack research and system issues in molten carbonate fuel cell (MCFC) technology development and commercialization are discussed within context of status of MCFC development and commercialization in US. Status of MCFC development is addressed. Major known fundamental stack research issues remaining for the MCFC technology are identified and discussed. The cathode remains a focal point of performance improvement and cost reduction. The various aspects of MCFC power plant network and systems issues are also addressed and discussed. These include cost, heat loss management, startup and shutdown modes, dynamic response, footprint, packaging and integration, parasitic power losses, pressurization, and reforming. Potential of MCFC networks is discussed. With the initial demonstration of full-area, full-height 250-kW to 2-MW MCFC power plants, the spatial configuration of the MCFC stacks into networks in the fuel cell power plant takes on importance for the first time.

  3. Electricity reform in developing and transition countries: A reappraisal

    International Nuclear Information System (INIS)

    Williams, J.H.; Ghanadan, R.

    2006-01-01

    Since about 1990, many developing and transition countries have undertaken market-oriented reforms in their electric power sectors. Despite the widespread adoption of a standard policy model, reform processes and outcomes have often failed to meet expectations. Drawing on an extensive literature review and case studies in Asia, Africa, Latin America, and Eastern Europe, this paper describes common features of non-OECD electricity reform and reappraises reform policies and underlying assumptions. Comparison with the sector-focused policy goals of deregulation in OECD countries highlights the importance of national fiscal crises, macroeconomic reforms, and persuasion by multilateral lenders in shaping non-OECD reforms. It also makes clear reform's dependence on attracting foreign capital, and consequent vulnerability to volatile international financial conditions. Case studies of Bolivia, Ghana, India, Poland, and Thailand illustrate reform's diverse pathways and problems in different settings. A broad range of non-OECD reform experiences indicates that disappointing results have often resulted from a narrow focus on finance and cost recovery, inflexibly applied. The paper concludes that improving reform will require emphasizing a broader set of objectives, including service provision, public benefits, effective regulation, and social/political legitimacy. Above all, reforms must be based on realistic assessments of national needs and capabilities. (author)

  4. Parametric study of natural circulation flow in molten salt fuel in molten salt reactor

    Energy Technology Data Exchange (ETDEWEB)

    Pauzi, Anas Muhamad, E-mail: Anas@uniten.edu.my [Centre of Nuclear Energy, Universiti Tenaga Nasional (UNITEN), Jalan IKRAM-UNITEN, 43000 Kajang, Selangor (Malaysia); Cioncolini, Andrea; Iacovides, Hector [School of Mechanical, Aerospace, and Civil Engineering (MACE), University of Manchester, Oxford Road, M13 9PL Manchester (United Kingdom)

    2015-04-29

    The Molten Salt Reactor (MSR) is one of the most promising system proposed by Generation IV Forum (GIF) for future nuclear reactor systems. Advantages of the MSR are significantly larger compared to other reactor system, and is mainly achieved from its liquid nature of fuel and coolant. Further improvement to this system, which is a natural circulating molten fuel salt inside its tube in the reactor core is proposed, to achieve advantages of reducing and simplifying the MSR design proposed by GIF. Thermal hydraulic analysis on the proposed system was completed using a commercial computation fluid dynamics (CFD) software called FLUENT by ANSYS Inc. An understanding on theory behind this unique natural circulation flow inside the tube caused by fission heat generated in molten fuel salt and tube cooling was briefly introduced. Currently, no commercial CFD software could perfectly simulate natural circulation flow, hence, modeling this flow problem in FLUENT is introduced and analyzed to obtain best simulation results. Results obtained demonstrate the existence of periodical transient nature of flow problem, hence improvements in tube design is proposed based on the analysis on temperature and velocity profile. Results show that the proposed system could operate at up to 750MW core power, given that turbulence are enhanced throughout flow region, and precise molten fuel salt physical properties could be defined. At the request of the authors and the Proceedings Editor the name of the co-author Andrea Cioncolini was corrected from Andrea Coincolini. The same name correction was made in the Acknowledgement section on page 030004-10 and in reference number 4. The updated article was published on 11 May 2015.

  5. Study on electrolytic reduction with controlled oxygen flow for iron from molten oxide slag containing FeO

    Directory of Open Access Journals (Sweden)

    Gao Y.M.

    2013-01-01

    Full Text Available A ZrO2-based solid membrane electrolytic cell with controlled oxygen flow was constructed: graphite rod /[O]Fe+C saturated / ZrO2(MgO/(FeO slag/iron crucible. The feasibility of extraction of iron from molten oxide slag containing FeO at an applied voltage was investigated by means of the electrolytic cell. The effects of some important process factors on the FeO electrolytic reduction with the controlled oxygen flow were discussed. The results show that: solid iron can be extracted from molten oxide slag containing FeO at 1450ºC and an applied potential of 4V. These factors, such as precipitation and growth of solid iron dendrites, change of the cathode active area on the inner wall of the iron crucible and ion diffusion flux in the molten slag may affect the electrochemical reaction rate. The reduction for Fe2+ ions mainly appears on new iron dendrites of the iron crucible cathode, and a very small amount of iron are also formed on the MSZ (2.18% MgO partially stabilized zirconia tube/slag interface due to electronic conductance of MSZ tube. Internal electronic current through MSZ tube may change direction at earlier and later electrolytic reduction stage. It has a role of promoting electrolytic reduction for FeO in the molten slag at the earlier stage, but will lower the current efficiency at the later stage. The final reduction ratio of FeO in the molten slag can achieve 99%. A novel electrolytic method with controlled oxygen flow for iron from the molten oxide slag containing FeO was proposed. The theory of electrolytic reduction with the controlled oxygen flow was developed.

  6. Molten Fuel-Coolant Interactions induced by coolant injection into molten fuel

    International Nuclear Information System (INIS)

    Park, H.S.; Yamano, Norihiko; Maruyama, Yu; Moriyama, Kiyofumi; Yang, Y.; Sugimoto, Jun

    1999-01-01

    To investigate Molten Fuel-Coolant Interactions (MFCIs) in various contact geometries, an experimental program, called MUSE (MUlti-configurations in Steam Explosions), has been initiated under the ALPHA program at JAERI in Japan. The first series of MUSE test has been focused on the coolant injection (CI) and stratified modes of FCIs using water as coolant and molten thermite as molten fuel. The effects of water jet subcooling, jet dynamics, jet shape and system constraint on FCIs energetic in these modes were experimentally investigated by precisely measuring their mechanical energy release in the MUSE facility. It was observed that measured mechanical energy increased with increasing of jet subcooling in a weakly constraint system but decreased in a strongly constraint system. FCI energetic also increased with increasing of water jet velocity. These results suggested that the penetration and dispersion phenomena of a water jet inside a melt determined the mixing conditions of FCIs in these contact modes and consequently played important roles on FCI energetics. To understand fundamental physics of these phenomena and possible mixing conditions in the MUSE tests, a set of visualization tests with several pairs of jet-pool liquids in non-boiling and isothermal conditions were carried out. Numerical simulations of a water jet penetrating into a water pool at non-boiling conditions showed similar behaviors to those observed in the visualization tests. (author)

  7. Structure of partly quenched molten copper chloride

    International Nuclear Information System (INIS)

    Pastore, G.; Tosi, M.P.

    1995-09-01

    The structural modifications induced in a model of molten CuCl by quenching the chlorine component into a microporous disordered matrix are evaluated using the hypernetted-chain closure in Ornstein-Zernike relations for the pair distribution functions in random systems. Aside from obvious changes in the behaviour of long-wavelength density fluctuations, the main effect of partial quenching is an enhanced delocalization of the Cu + ions. The model suggests that the ionic mobility in a superionic glass is enhanced relative to the melt at the same temperature and density. Only very minor quantitative differences are found in the structural functions when the replica Ornstein-Zernike relations derived by Given and Stell for a partly quenched system are simplified to those given earlier by Madden and Glandt. (author). 19 refs, 6 figs

  8. Single ion dynamics in molten sodium bromide

    Energy Technology Data Exchange (ETDEWEB)

    Alcaraz, O.; Trullas, J. [Departament de Física i Enginyeria Nuclear, Universitat Politècnica de Catalunya, 08034 Barcelona (Spain); Demmel, F. [ISIS Facility, Rutherford Appleton Laboratory, Didcot OX11 0QX (United Kingdom)

    2014-12-28

    We present a study on the single ion dynamics in the molten alkali halide NaBr. Quasielastic neutron scattering was employed to extract the self-diffusion coefficient of the sodium ions at three temperatures. Molecular dynamics simulations using rigid and polarizable ion models have been performed in parallel to extract the sodium and bromide single dynamics and ionic conductivities. Two methods have been employed to derive the ion diffusion, calculating the mean squared displacements and the velocity autocorrelation functions, as well as analysing the increase of the line widths of the self-dynamic structure factors. The sodium diffusion coefficients show a remarkable good agreement between experiment and simulation utilising the polarisable potential.

  9. Sugar-induced molten-globule model.

    Science.gov (United States)

    Davis-Searles, P R; Morar, A S; Saunders, A J; Erie, D A; Pielak, G J

    1998-12-01

    Proteins denature at low pH because of intramolecular electrostatic repulsions. The addition of salt partially overcomes this repulsion for some proteins, yielding a collapsed conformation called the A-state. A-states have characteristics expected for the molten globule, a notional kinetic protein folding intermediate. Here we show that the addition of neutral sugars to solutions of acid-denatured equine ferricytochrome c induces formation of the A-state in the absence of added salt. We characterized the structure and stability of the sugar-induced A-state with circular dichroism spectropolarimetry (CD) and NMR-monitored hydrogen-deuterium exchange experiments. We also examined the stability of the sugar-induced A-state as a function of sugar size and concentration. The results are interpreted using several models and we conclude that the stabilizing effect is consistent with increased steric repulsion between the protein and the sugar solutions.

  10. Corrosion study in molten fluoride salt

    International Nuclear Information System (INIS)

    Keny, S.J.; Kumbhar, A.G.; Rangarajan, S.; Gupta, V.K.; Maheshwari, N.K.; Vijayan, P.K.

    2013-01-01

    Corrosion behaviors of two alloys viz. Inconel 625 and Inconel 617 were tested in molten fluoride salts of lithium, sodium and potassium (FLiNaK) in the temperature range of 550-750 ℃ in a nickel lined Inconel vessel. Electrochemical polarization (Tafel plot) technique was used for this purpose. For both alloys, the corrosion rate was found to increase sharply beyond 650 ℃ . At 600 ℃ , Inconel 625 showed a decreasing trend in the corrosion rate over a period of 24 hours, probably due to changes in the surface conditions. After fifteen days, re-testing of Inconel 625 in the same melt showed an increase in the corrosion rate. Inconel 625 was found to be more corrosion resistant than Inconel 617. (author)

  11. Electrocrystallisation of tantalum in molten fluoride media

    Energy Technology Data Exchange (ETDEWEB)

    Massot, L. [Laboratoire de Genie Chimique UMR 5503, Departement Procedes Electrochimiques et Materiaux, Universite Paul Sabatier, 118 route de Narbonne, 31062 Toulouse Cedex (France)]. E-mail: massot@chimie.ups-tlse.fr; Chamelot, P. [Laboratoire de Genie Chimique UMR 5503, Departement Procedes Electrochimiques et Materiaux, Universite Paul Sabatier, 118 route de Narbonne, 31062 Toulouse Cedex (France); Palau, P. [Pechiney CRV-UR GP, Parc Economique Centr' Alp, BP27, 38340 Voreppe (France); Taxil, P. [Laboratoire de Genie Chimique UMR 5503, Departement Procedes Electrochimiques et Materiaux, Universite Paul Sabatier, 118 route de Narbonne, 31062 Toulouse Cedex (France)

    2005-09-20

    The electrochemical nucleation of tantalum in molten alkaline fluoride media is investigated using chronoamperometry in the 670-750 deg C temperature range to optimize the operating conditions for preparing tantalum coatings for anode materials. Chronoamperometric results show that the electrodeposition process involves progressive nucleation with diffusion-controlled growth of the nuclei, which was confirmed by scanning electron microscopy. The influence of the temperature and the overpotential on the nucleation site densities is considered. Once the deposit has been obtained, plotting the roughness of the tantalum coatings as a function of the current densities reveals a minimum at about 80 mA/cm{sup 2}. This minimum is considered by the authors as a consequence of the progressive nucleation.

  12. 30th November 2010 - Norwegian Ministry of Government Administration, Reform and Church Affairs State Secretary R. Valle signing the guest book with Head of International Relations F. Pauss and Director for Research and Scientific Computing S. Bertolucci; visiting CERN Computer Centre with Information Technology Department Head F. Hemmer.

    CERN Multimedia

    Maximilien Brice

    2010-01-01

    30th November 2010 - Norwegian Ministry of Government Administration, Reform and Church Affairs State Secretary R. Valle signing the guest book with Head of International Relations F. Pauss and Director for Research and Scientific Computing S. Bertolucci; visiting CERN Computer Centre with Information Technology Department Head F. Hemmer.

  13. Stable colloids in molten inorganic salts

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Hao; Dasbiswas, Kinjal; Ludwig, Nicholas B.; Han, Gang; Lee, Byeongdu; Vaikuntanathan, Suri; Talapin, Dmitri V.

    2017-02-15

    A colloidal solution is a homogeneous dispersion of particles or droplets of one phase (solute) in a second, typically liquid, phase (solvent). Colloids are ubiquitous in biological, chemical and technological processes1, 2, homogenizing highly dissimilar constituents. To stabilize a colloidal system against coalescence and aggregation, the surface of each solute particle is engineered to impose repulsive forces strong enough to overpower van der Waals attraction and keep the particles separated from each other2. Electrostatic stabilization3, 4 of charged solutes works well in solvents with high dielectric constants, such as water (dielectric constant of 80). In contrast, colloidal stabilization in solvents with low polarity, such as hexane (dielectric constant of about 2), can be achieved by decorating the surface of each particle of the solute with molecules (surfactants) containing flexible, brush-like chains2, 5. Here we report a class of colloidal systems in which solute particles (including metals, semiconductors and magnetic materials) form stable colloids in various molten inorganic salts. The stability of such colloids cannot be explained by traditional electrostatic and steric mechanisms. Screening of many solute–solvent combinations shows that colloidal stability can be traced to the strength of chemical bonding at the solute–solvent interface. Theoretical analysis and molecular dynamics modelling suggest that a layer of surface-bound solvent ions produces long-ranged charge-density oscillations in the molten salt around solute particles, preventing their aggregation. Colloids composed of inorganic particles in inorganic melts offer opportunities for introducing colloidal techniques to solid-state science and engineering applications.

  14. Fast Spectrum Molten Salt Reactor Options

    Energy Technology Data Exchange (ETDEWEB)

    Gehin, Jess C [ORNL; Holcomb, David Eugene [ORNL; Flanagan, George F [ORNL; Patton, Bruce W [ORNL; Howard, Rob L [ORNL; Harrison, Thomas J [ORNL

    2011-07-01

    During 2010, fast-spectrum molten-salt reactors (FS-MSRs) were selected as a transformational reactor concept for light-water reactor (LWR)-derived heavy actinide disposition by the Department of Energy-Nuclear Energy Advanced Reactor Concepts (ARC) program and were the subject of a preliminary scoping investigation. Much of the reactor description information presented in this report derives from the preliminary studies performed for the ARC project. This report, however, has a somewhat broader scope-providing a conceptual overview of the characteristics and design options for FS-MSRs. It does not present in-depth evaluation of any FS-MSR particular characteristic, but instead provides an overview of all of the major reactor system technologies and characteristics, including the technology developments since the end of major molten salt reactor (MSR) development efforts in the 1970s. This report first presents a historical overview of the FS-MSR technology and describes the innovative characteristics of an FS-MSR. Next, it provides an overview of possible reactor configurations. The following design features/options and performance considerations are described including: (1) reactor salt options-both chloride and fluoride salts; (2) the impact of changing the carrier salt and actinide concentration on conversion ratio; (3) the conversion ratio; (4) an overview of the fuel salt chemical processing; (5) potential power cycles and hydrogen production options; and (6) overview of the performance characteristics of FS-MSRs, including general comparative metrics with LWRs. The conceptual-level evaluation includes resource sustainability, proliferation resistance, economics, and safety. The report concludes with a description of the work necessary to begin more detailed evaluation of FS-MSRs as a realistic reactor and fuel cycle option.

  15. Narrative medicine and healthcare reform.

    Science.gov (United States)

    Lewis, Bradley E

    2011-03-01

    Narrative medicine is one of medicine's most important internal reforms, and it should be a critical dimension of healthcare debate. Healthcare reform must eventually ask not only how do we pay for healthcare and how do we distribute it, but more fundamentally, what kind of healthcare do we want? It must ask, in short, what are the goals of medicine? Yet, even though narrative medicine is crucial to answering these pivotal and inescapable questions, it is not easy to describe. Many of its core claims go against the grain of common sense thinking about medicine. This article argues that the best way to understand narrative medicine is to tell a story that puts its emergence in historical context.

  16. Curriculum reform and the market

    DEFF Research Database (Denmark)

    Petersen, Karen Bjerg

    2011-01-01

    A neo-liberal discourse in the 2000s has been prevalent not only in international and Danish educational policy contexts, but also within a specific area, namely the education of adult immigrants in Denmark. With the adoption of a new law in 2003 high-stakes testing, standards, new market economy...... in Denmark. Based on studies of curriculum reform and research about headmasters’ and teachers’ attitudes the article addresses paradoxes rising in the wake of the neo-liberal education policy. Despite the intention of high-stakes testing to increase adult migrants’ language and employment related....... Teachers furthermore find the new working conditions stressing. It is discussed whether a neo-liberal discourse in adult teaching is ‘dumping down’ the intentions of curriculum and education reform....

  17. Curriculum reform and the market

    DEFF Research Database (Denmark)

    Petersen, Karen Bjerg

    2012-01-01

    A neo-liberal discourse in the 2000s has been prevalent not only in international and Danish educational policy contexts, but also within a specific area, namely the education of adult immigrants in Denmark. With the adoption of a new law in 2003 high-stakes testing, standards, new market economy...... in Denmark. Based on studies of curriculum reform and research about headmasters’ and teachers’ attitudes the article addresses paradoxes rising in the wake of the neo-liberal education policy. Despite the intention of high-stakes testing to increase adult migrants’ language and employment related....... Teachers furthermore find the new working conditions stressing. It is discussed whether a neo-liberal discourse in adult teaching is ‘dumping down’ the intentions of curriculum and education reform....

  18. Heat and Fission Product Transport in a Molten U-Zr-O Pool With Crust

    International Nuclear Information System (INIS)

    Yun, J.I.; Suh, K.Y.; Kang, C.S.

    2002-01-01

    Heat transfer and fluid flow in a molten pool are influenced by internal volumetric heat generated from the radioactive decay of fission product species retained in the pool. The pool superheat is determined based on the overall energy balance that equates the heat production rate to the heat loss rate. Decay heat of fission products in the pool was estimated by product of the mass concentration and energy conversion factor of each fission product. For the calculation of heat generation rate in the pool, twenty-nine elements were chosen and classified by their chemical properties. The mass concentration of a fission product is obtained from released fraction and the tabular output of the ORIGEN 2 code. The initial core and pool inventories at each time can also be estimated using ORIGEN 2. The released fraction of each fission product is calculated based on the bubble dynamics and mass transport. Numerical analysis was performed for the TMI-2 accident. The pool is assumed to be a partially filled hemispherical geometry and the change of pool geometry during the numerical calculation was neglected. Results of the numerical calculation revealed that the peak temperature of the molten pool significantly decreased and most of the volatile fission products were released from the molten pool during the accident. (authors)

  19.  Railway Reforms

    DEFF Research Database (Denmark)

    Asmild, Mette; Holvad, Torben; Hougaard, Jens Leth

    This paper considers railway operations in 23 European countries during 1995-2001, where a series of reform initiatives were launched by the European Commission, and analyses whether these reform initiatives improved the operating efficiency of the railways. Efficiency is measured using Multi-dir...... empirical evidence that accounting separation is important for improving operating efficiency for both material and staff costs, whereas other reforms only influenced one of these factors...

  20. Lesotho - Land Administration Reform

    Data.gov (United States)

    Millennium Challenge Corporation — Michigan State University was assigned to design the impact evaluation (IE) of the Land Administration Reform Project (LARP) funded under the Millennium Challenge...

  1. Philippines - Revenue Administration Reform

    Data.gov (United States)

    Millennium Challenge Corporation — The Millennium Challenge Account-Philippines' (MCA-P) implementation of the Revenue Administration Reform Project (RARP) is expected to improve tax administration,...

  2. Higher Education Reforms: Latin America in Comparative Perspective

    Science.gov (United States)

    Bernasconi, Andrés; Celis, Sergio

    2017-01-01

    This article introduces a special issue of EPAA/AAPE devoted to recent higher education reforms in Latin America. The last two decades have seen much policy development in higher education in the region, examined and discussed by scholars in each country, but dialog with the international literature on higher education reform, or an explicit…

  3. Facing the Challenges of Educational Reform in the Arab World

    Science.gov (United States)

    Karami Akkary, Rima

    2014-01-01

    This paper pinpoints and discusses key aspects of the current approaches to school reform in the Arab world against the backdrop of what is accepted as the best practice in the international literature on effective school reform and educational change. The main goal of the paper is to highlight deeply ingrained assumptions and practices that are…

  4. A Decade of Reform: Science and Technology Policy in China ...

    International Development Research Centre (IDRC) Digital Library (Canada)

    In 1995, and at the request of the Chinese government, Canada's International Development Research Centre ( IDRC ) assembled a team of experts to assess the reforms to China's S&T sector — reforms that began in 1985 as an initiative of the State Science and Technology Commission (SSTC) of China. A Decade of ...

  5. Applying Concepts of Critical Pedagogy to Qatar's Educational Reform

    Science.gov (United States)

    Romanowski, Michael H.; Amatullah, Tasneem

    2016-01-01

    Qatar is in the midst of a systemic education reform, Education For a New Era, steered by RAND's (a nonprofit research organization) analysis and report of Qatar's Educational system. Driven by a neoliberal agenda, the reform includes international curricula, curriculum standards, teacher licensure, and professional standards for school leaders…

  6. Boric ester-type molten salt via dehydrocoupling reaction.

    Science.gov (United States)

    Matsumi, Noriyoshi; Toyota, Yoshiyuki; Joshi, Prerna; Puneet, Puhup; Vedarajan, Raman; Takekawa, Toshihiro

    2014-11-14

    Novel boric ester-type molten salt was prepared using 1-(2-hydroxyethyl)-3-methylimidazolium chloride as a key starting material. After an ion exchange reaction of 1-(2-hydroxyethyl)-3-methylimidazolium chloride with lithium (bis-(trifluoromethanesulfonyl) imide) (LiNTf2), the resulting 1-(2-hydroxyethyl)-3-methylimidazolium NTf2 was reacted with 9-borabicyclo[3.3.1]nonane (9-BBN) to give the desired boric ester-type molten salt in a moderate yield. The structure of the boric ester-type molten salt was supported by 1H-, 13C-, 11B- and 19F-NMR spectra. In the presence of two different kinds of lithium salts, the matrices showed an ionic conductivity in the range of 1.1 × 10⁻⁴-1.6 × 10⁻⁵ S cm⁻¹ at 51 °C. This was higher than other organoboron molten salts ever reported.

  7. Degassing of molten alloys with the assistance of ultrasonic vibration

    Science.gov (United States)

    Han, Qingyou; Xu, Hanbing; Meek, Thomas T.

    2010-03-23

    An apparatus and method are disclosed in which ultrasonic vibration is used to assist the degassing of molten metals or metal alloys thereby reducing gas content in the molten metals or alloys. High-intensity ultrasonic vibration is applied to a radiator that creates cavitation bubbles, induces acoustic streaming in the melt, and breaks up purge gas (e.g., argon or nitrogen) which is intentionally introduced in a small amount into the melt in order to collect the cavitation bubbles and to make the cavitation bubbles survive in the melt. The molten metal or alloy in one version of the invention is an aluminum alloy. The ultrasonic vibrations create cavitation bubbles and break up the large purge gas bubbles into small bubbles and disperse the bubbles in the molten metal or alloy more uniformly, resulting in a fast and clean degassing.

  8. System Requirements Document for the Molten Salt Reactor Experiment

    Energy Technology Data Exchange (ETDEWEB)

    Aigner, R.D.

    2000-04-01

    The purpose of the conversion process is to convert the {sup 233}U fluoride compounds that are being extracted from the Molten Salt Reactor Experiment (MSRE) equipment to a stable oxide for long-term storage at Bldg. 3019.

  9. Large Scale Inert Anode for Molten Oxide Electrolysis, Phase I

    Data.gov (United States)

    National Aeronautics and Space Administration — Molten oxide electrolysis is a demonstrated laboratory-scale process for producing oxygen from the JSC-1a lunar simulant; however, critical subsystems necessary for...

  10. Advanced Instrumentation for Molten Salt Flow Measurements at NEXT

    Science.gov (United States)

    Tuyishimire, Olive

    2017-09-01

    The Nuclear Energy eXperiment Testing (NEXT) Lab at Abilene Christian University is building a Molten Salt Loop to help advance the technology of molten salt reactors (MSR). NEXT Lab's aim is to be part of the solution for the world's top challenges by providing safe, clean, and inexpensive energy, clean water and medical Isotopes. Measuring the flow rate of the molten salt in the loop is essential to the operation of a MSR. Unfortunately, there is no flow meter that can operate in the high temperature and corrosive environment of a molten salt. The ultrasonic transit time method is proposed as one way to measure the flow rate of high temperature fluids. Ultrasonic flow meter uses transducers that send and receive acoustic waves and convert them into electrical signals. Initial work presented here focuses on the setup of ultrasonic transducers. This presentation is the characterization of the pipe-fluid system with water as a baseline for future work.

  11. High Surface Iridium Anodes for Molten Oxide Electrolysis, Phase I

    Data.gov (United States)

    National Aeronautics and Space Administration — Processing of lunar regolith into oxygen for habitat and propulsion is needed to support future space missions. Direct electrochemical reduction of molten regolith...

  12. High Surface Iridium Anodes for Molten Oxide Electrolysis Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Processing of lunar regolith into oxygen for habitat and propulsion is needed to support future space missions. Direct electrochemical reduction of molten regolith...

  13. Boric Ester-Type Molten Salt via Dehydrocoupling Reaction

    Directory of Open Access Journals (Sweden)

    Noriyoshi Matsumi

    2014-11-01

    Full Text Available Novel boric ester-type molten salt was prepared using 1-(2-hydroxyethyl-3-methylimidazolium chloride as a key starting material. After an ion exchange reaction of 1-(2-hydroxyethyl-3-methylimidazolium chloride with lithium (bis-(trifluoromethanesulfonyl imide (LiNTf2, the resulting 1-(2-hydroxyethyl-3-methylimidazolium NTf2 was reacted with 9-borabicyclo[3.3.1]nonane (9-BBN to give the desired boric ester-type molten salt in a moderate yield. The structure of the boric ester-type molten salt was supported by 1H-, 13C-, 11B- and 19F-NMR spectra. In the presence of two different kinds of lithium salts, the matrices showed an ionic conductivity in the range of 1.1 × 10−4–1.6 × 10−5 S cm−1 at 51 °C. This was higher than other organoboron molten salts ever reported.

  14. Fission product removal from molten salt using zeolite

    International Nuclear Information System (INIS)

    Pereira, C.; Babcock, B.D.

    1996-01-01

    Spent nuclear fuel (SNF) can be treated in a molten salt electrorefiner for conversion into metal and mineral waste forms for geologic disposal. The fuel is dissolved in molten chloride salt. Non-transuranic fission products in the molten salt are ion-exchanged into zeolite A, which is subsequently mixed with glass and consolidated. Zeolite was found to be effective in removing fission product cations from the molten salt. Breakthrough of cesium and the alkaline earths occurred more rapidly than was observed for the rare earths. The effluent composition as a function of time is presented, as well as results for the distribution of fission products along the length of the column. Effects of temperature and salt flow rate are also discussed

  15. Advanced Additive Manufacturing Feedstock from Molten Regolith Electrolysis

    Data.gov (United States)

    National Aeronautics and Space Administration — Demonstrate the feasibility of Molten Regolith Electrolysis (MRE) Reactor start by initiating resistive-heating of the regolith past its melting point using...

  16. Dynamics and control of molten-salt breeder reactor

    Directory of Open Access Journals (Sweden)

    Vikram Singh

    2017-08-01

    Full Text Available Preliminary results of the dynamic analysis of a two-fluid molten-salt breeder reactor (MSBR system are presented. Based on an earlier work on the preliminary dynamic model of the concept, the model presented here is nonlinear and has been revised to accurately reflect the design exemplified in ORNL-4528. A brief overview of the model followed by results from simulations performed to validate the model is presented. Simulations illustrate stable behavior of the reactor dynamics and temperature feedback effects to reactivity excursions. Stable and smooth changes at various nodal temperatures are also observed. Control strategies for molten-salt reactor operation are discussed, followed by an illustration of the open-loop load-following capability of the molten-salt breeder reactor system. It is observed that the molten-salt breeder reactor system exhibits “self-regulating” behavior, minimizing the need for external controller action for load-following maneuvers.

  17. Molten fluoride mixtures as possible fission reactor fuels

    Energy Technology Data Exchange (ETDEWEB)

    Grimes, W.R.

    1978-01-01

    Molten mixtures of fluorides with UF/sub 4/ as a component have been used as combined fuel and primary heat transfer agent in experimental high-temperature reactors and have been proposed for use in breeders or converters of /sup 233/U from thorium. Such use places stringent and diverse demands upon the fluid fuel. A brief review of chemical behavior of molten fluorides is given to show some of their strengths and weaknesses for such service.

  18. Iliopsoas Tendon Reformation after Psoas Tendon Release

    Directory of Open Access Journals (Sweden)

    K. Garala

    2013-01-01

    Full Text Available Internal snapping hip syndrome, or psoas tendonitis, is a recognised cause of nonarthritic hip pain. The majority of patients are treated conservatively; however, occasionally patients require surgical intervention. The two surgical options for iliopsoas tendinopathy are step lengthening of the iliopsoas tendon or releasing the tendon at the lesser trochanter. Although unusual, refractory snapping usually occurs soon after tenotomy. We report a case of a 47-year-old active female with internal snapping and pain following an open psoas tenotomy. Postoperatively she was symptom free for 13 years. An MRI arthrogram revealed reformation of a pseudo iliopsoas tendon reinserting into the lesser trochanter. The pain and snapping resolved after repeat iliopsoas tendon release. Reformation of tendons is an uncommon sequela of tenotomies. However the lack of long-term studies makes it difficult to calculate prevalence rates. Tendon reformation should be included in the differential diagnosis of failed tenotomy procedures after a period of symptom relief.

  19. Steam Methane Reformation Testing for Air-Independent Solid Oxide Fuel Cell Systems

    Science.gov (United States)

    Mwara, Kamwana N.

    2015-01-01

    Recently, NASA has been looking into utilizing landers that can be propelled by LOX-CH (sub 4), to be used for long duration missions. Using landers that utilize such propellants, also provides the opportunity to use solid oxide fuel cells as a power option, especially since they are able to process methane into a reactant through fuel reformation. One type of reformation, called steam methane reformation, is a process to reform methane into a hydrogen-rich product by reacting methane and steam (fuel cell exhaust) over a catalyst. A steam methane reformation system could potentially use the fuel cell's own exhaust to create a reactant stream that is hydrogen-rich, and requires less internal reforming of the incoming methane. Also, steam reformation may hold some advantages over other types of reforming, such as partial oxidation (PROX) reformation. Steam reformation does not require oxygen, while up to 25 percent can be lost in PROX reformation due to unusable CO (sub 2) reformation. NASA's Johnson Space Center has conducted various phases of steam methane reformation testing, as a viable solution for in-space reformation. This has included using two different types of catalysts, developing a custom reformer, and optimizing the test system to find the optimal performance parameters and operating conditions.

  20. Russian electricity reform. Emerging challenges and opportunities

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2005-07-01

    The Russian Government is pursuing a strategy of very high economic growth, with the objective of doubling gross domestic product in ten years. It recognises the central role the electricity sector has to play to achieve this target and has embarked on a highly ambitious program of electricity reform. If it is to succeed, the reform program will have to create market structures, market rules and a regulatory framework that will foster competitive wholesale and retail electricity markets. At the same time, it will have to deal with sensitive social issues related to tariff rebalancing and the removal of cross subsidies. Only competitive markets based on transparent prices that reflect costs can deliver the efficient, reliable and internationally competitive performance needed to meet the government's economic targets. Such markets are essential to attract new investment that will be required to ensure security of electricity supply after 2010. This book focuses on key aspects of the proposed reform that could have an important bearing on its success. It also raises concerns as to the pace of reform in related areas, such as the need for complementary reforms in the Russian natural gas sector. The IEA commends the Russian Government on its efforts to embrace this electricity reform - a key element critical to meeting the challenges ahead in terms of its economic growth and energy security. 17 figs., 10 tabs., 3 maps.

  1. Novel waste printed circuit board recycling process with molten salt

    Science.gov (United States)

    Riedewald, Frank; Sousa-Gallagher, Maria

    2015-01-01

    The objective of the method was to prove the concept of a novel waste PCBs recycling process which uses inert, stable molten salts as the direct heat transfer fluid and, simultaneously, uses this molten salt to separate the metal products in either liquid (solder, zinc, tin, lead, etc.) or solid (copper, gold, steel, palladium, etc.) form at the operating temperatures of 450–470 °C. The PCB recovery reactor is essentially a U-shaped reactor with the molten salt providing a continuous fluid, allowing molten salt access from different depths for metal recovery. A laboratory scale batch reactor was constructed using 316L as suitable construction material. For safety reasons, the inert, stable LiCl–KCl molten salts were used as direct heat transfer fluid. Recovered materials were washed with hot water to remove residual salt before metal recovery assessment. The impact of this work was to show metal separation using molten salts in one single unit, by using this novel reactor methodology. • The reactor is a U-shaped reactor filled with a continuous liquid with a sloped bottom representing a novel reactor concept. • This method uses large PCB pieces instead of shredded PCBs as the reactor volume is 2.2 L. • The treated PCBs can be removed via leg B while the process is on-going. PMID:26150977

  2. Thinking about Tax Reform.

    Science.gov (United States)

    Boskin, Michael J.

    1985-01-01

    Providing pre-college teachers with an analysis of tax reform is the primary goal of this publication. The present tax system is both inefficient and inequitable. Three goals of tax reform proposals are detailed: (1) fairness--the dimensions of horizontal equity, or equal treatment of equals however defined, and vertical equity, reflecting the…

  3. Tax Reform & University Development.

    Science.gov (United States)

    Myers, John Holt

    This brochure discusses the implications of the Tax Reform Act of 1969 for university and college development officers charged with the responsibility for solicitation of gifts, bequests and grants from foundations. The solicitation of deferred gifts, bequests and grants from foundations is discussed in chapter one in relation to tax reform and…

  4. Life After Tax Reform.

    Science.gov (United States)

    Clotfelter, Charles T.

    1987-01-01

    The impact of the Tax Reform Act of 1986 on higher education is discussed. Background on the tax reform movement and the specific provisions of the 1986 law are examined. The law will reduce private donations, raise the cost of college, and raise the cost of operating institutions. (MLW)

  5. Influence of geometry on pressure and velocity distribution in packed-bed methanol steam reforming reactor

    Science.gov (United States)

    Ivanović, Ivana; Sedmak, Aleksandar; Milošević, Miloš; Cvetković, Ivana; Pohar, Andrej; Likozar, Blaž

    2017-07-01

    The main tasks of this research is to propose several changes in the packed bed micro methanol steam reformer geometry in order to ensure its performance. The reformer is an integral part of the existing indirect internal reforming high temperature PEMFC and most of its geometry is already defined. The space for remodeling is very limited.

  6. Higher Education Reform in Italy: Tightening Regulation Instead of Steering at a Distance

    Science.gov (United States)

    Donina, Davide; Meoli, Michele; Paleari, Stefano

    2015-01-01

    In December 2010, a comprehensive reform (Law 240/2010, or "Gelmini reform") changed the institutional governance and internal organization of Italian state universities. This paper investigates the redefinition of the state role in the light of public management reform narratives, linking them to the Governance Equalizer Model to…

  7. Polarization and Policy Reform : Anti-Corruption Policymaking in Sub-Saharan Africa

    NARCIS (Netherlands)

    Torenvlied, René; Klein Haarhuis, Carolien M.

    2008-01-01

    The ability of political systems to adopt policy reforms contributes to their internal stability. This article analyses 29 anti-corruption reforms in seven sub-Saharan countries. It seeks to explain the level of adopted reform in these countries from conflicts of interests between policy actors. Two

  8. Health reform through tax reform: a primer.

    Science.gov (United States)

    Furman, Jason

    2008-01-01

    Tax incentives for employer-sponsored insurance and other medical spending cost about $200 billion annually and have pervasive effects on coverage and costs. This paper surveys a range of proposals to reform health care, either by adding new tax incentives or by limiting or replacing the existing tax incentives. Replacing the current tax preference for insurance with an income-related, refundable tax credit has the potential to expand coverage and reduce inefficient spending at no net federal cost. But such an approach by itself would entail substantial risks, so complementary reforms to the insurance market are essential to ensure success.

  9. The Danish Police Reform

    DEFF Research Database (Denmark)

    Degnegaard, Rex; Mark, Sofie

    2013-01-01

    and private organisations doing business-in-society. The case concerns the reformation of the Danish Police. In 2007 the Danish Police started implementing an extensive reform that affected all parts of the organisation. Despite thorough planning of the process including several change management initiatives...... for organisations to work with transparency and involvement with the aim of upholding and further developing a social responsibility to their environment. This case on the other hand takes an inside-out perspective on social responsibility by illustrating how social responsibility is necessary for public......, the reform process was problematic and the following years were challenging and filled with changes and turbulence. Media, politicians and the police itself directed heavy criticism towards the effects of the reform and reviews of the reform as well as of the work of the police were carried out resulting...

  10. FY 1999 Report on the technical results. Part 2-1. Development of fuel cell power generation technologies (Research and development of molten carbonate fuel cell power generation system); 1999 nendo nenryo denchi hatsuden gijutsu kaihatsu seika hokokusho. 2-1. Yoyu tansan'engata nenryo denchi (hatsuden system no kenkyu kaihatsu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-05-01

    This research and development project is aimed at modification and improvement of the stacking technologies, to improve service life and performance of the molten carbonate fuel cell power generation system and reduce its cost. For the cross-flow type stack, optimization of the anode firing conditions leads to controlled reduction of the fine pores, and incorporation of the cathode with MgO successfully leads to controlled elution of NiO and Ni short-cut. For the separator, the service life is extended by treatment of the material with Al and controlling its rigidity. The cell life prediction method is improved to enhance its accuracy. The cell life of -4.3mV/1,000h is achieved by these technologies. For the parallel-flow type stack, the electrodes are improved to achieve the cell life of -1.4mV/1,000h, the technologies for producing the separator for a 1m{sup 2} class unit are developed, and the basic structures of a large-capacity stack are designed. For the internal reforming type, a 200kW class reforming stack is constructed, and operated for 5,259 hours. The causes for electrolyte loss are analyzed by developing the relationships between operating temperature and electrolyte loss, electrolyte mass and sustainability of the cell characteristics, and steam partial pressure over the cathode and electrolyte loss, and also by testing the Ni short-cut. (NEDO)

  11. Report on achievement in developing fuel cell power generation technology in fiscal 1998. Research and development of molten carbonate fuel cell power generation system (Test of the research result report); 1998 nendo nenryo denchi hatsuden gijutsu kaihatsu seika hokokusho. Yoyu tansan'engata nenryo denchi hatsuden system no kenkyu kaihatsu (kenkyu seika no honbun)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-05-01

    This paper summarizes the text of the research result report in the separate volume II-1 from among the fiscal 1998 report on the achievement made on researching and developing a molten carbonate fuel cell (MCFC) power generation system. For the AC-DC type system whose high performance and large capacity stacks are being developed, detail designs were made on 250-kW class stack module assembly and installation procedure. At the same time, processing and forming were continued on such main components as electrodes, electrolyte plates and separators. The cells were assembled as modules, sintered, installed and adjusted. Aids were given by the process and control (PAC) test on devices and piping of the fuel cell system block. Cell life extension is also under study. For the parallel flow type stack, two 250-kW stacks were fabricated, and an overall adjustment test was begun thereon in March. For the reformer, an internal reforming system was developed for the 200-kW class system, whose adjustment test is scheduled for April 1999. Capacity increase is also under discussion. For practical use of MCFC, stack life of 40,000 hours is said required. The current status is at the level of exceeding 10,000 hours, but the necessity is seen in suppressing voltage drop associated with lapse of time. (NEDO)

  12. Molten metal reactor and method of forming hydrogen, carbon monoxide and carbon dioxide using the molten alkaline metal reactor

    Science.gov (United States)

    Bingham, Dennis N.; Klingler, Kerry M.; Turner, Terry D.; Wilding, Bruce M.

    2012-11-13

    A molten metal reactor for converting a carbon material and steam into a gas comprising hydrogen, carbon monoxide, and carbon dioxide is disclosed. The reactor includes an interior crucible having a portion contained within an exterior crucible. The interior crucible includes an inlet and an outlet; the outlet leads to the exterior crucible and may comprise a diffuser. The exterior crucible may contain a molten alkaline metal compound. Contained between the exterior crucible and the interior crucible is at least one baffle.

  13. Molten Salt Breeder Reactor Analysis Methods

    Energy Technology Data Exchange (ETDEWEB)

    Park, Jinsu; Jeong, Yongjin; Lee, Deokjung [Ulsan National Institute of Science and Technology, Ulsan (Korea, Republic of)

    2015-05-15

    Utilizing the uranium-thorium fuel cycle shows considerable potential for the possibility of MSR. The concept of MSBR should be revised because of molten salt reactor's advantage such as outstanding neutron economy, possibility of continuous online reprocessing and refueling, a high level of inherent safety, and economic benefit by keeping off the fuel fabrication process. For the development of MSR research, this paper provides the MSBR single-cell, two-cell and whole core model for computer code input, and several calculation results including depletion calculation of each models. The calculations are carried out by using MCNP6, a Monte Carlo computer code, which has CINDER90 for depletion calculation using ENDF-VII nuclear data. From the calculation results of various reactor design parameters, the temperature coefficients are all negative at the initial state and MTC becomes positive at the equilibrium state. From the results of core rod worth, the graphite control rod alone cannot makes the core subcritical at initial state. But the equilibrium state, the core can be made subcritical state only by graphite control rods. Through the comparison of the results of each models, the two-cell method can represent the MSBR core model more accurately with a little more computational resources than the single-cell method. Many of the thermal spectrum MSR have adopted a multi-region single-fluid strategy.

  14. Fragmentation of molten core material by sodium

    International Nuclear Information System (INIS)

    Chu, T.Y.

    1982-01-01

    A series of scoping experiments was performed to study the fragmentation of prototypic high temperature melts in sodium. The quantity of melt involved was at least one order of magnitude larger than previous experiments. Two modes of contact were used: melt streaming into sodium and sodium into melt. The average bulk fragment size distribution was found to be in the range of previous data and the average size distribution was found to be insensitive to mode of contact. SEM studies showed that the metal component typically fragmented in the molten phase while the oxide component fragmented in the solid phase. For UO 2 -ZrO 2 /stainless steel melts no sigificant spatial separation of the metal and oxide was observed. The fragment size distribution was stratified vertically in the debris bed in all cases. While the bulk fragment size showed generally consistent trends, the individual experiments were sufficiently different to cause different degrees of stratification in the debris bed. For the highly stratified beds the permeability can decrease by as much as a factor of 20 from the bottom to the top of the bed

  15. Molten aluminum alloy fuel fragmentation experiments

    International Nuclear Information System (INIS)

    Gabor, J.D.; Purviance, R.T.; Cassulo, J.C.; Spencer, B.W.

    1992-01-01

    Experiments were conducted in which molten aluminum alloys were injected into a 1.2 m deep pool of water. The parameters varied were (i) injectant material (8001 aluminum alloy and 12.3 wt% U-87.7 wt% Al), (ii) melt superheat (O to 50 K), (iii) water temperature (313, 343 and 373 K) and (iv) size and geometry of the pour stream (5, 10 and 20 mm diameter circular and 57 mm annular). The pour stream fragmentation was dominated by surface tension with large particles (∼30 mm) being formed from varicose wave breakup of the 10-mm circular pours and from the annular flow off a 57 mm diameter tube. The fragments produced by the 5 mm circular et were smaller (∼ mm), and the 20 mm jet which underwent sinuous wave breakup produced ∼100 mm fragments. The fragments froze to form solid particles in 313 K water, and when the water was ≥343 K, the melt fragments did not freeze during their transit through 1.2 m of water

  16. Was the early Earth completely molten?

    Science.gov (United States)

    Turcotte, D. L.; Pflugrath, J. C.

    1984-01-01

    The nature of the interior of the primitive Earth was examined. The question is posted: was the Earth a cold solid or was it a hot liquid, much like a lava lakes seen in today's volcanic cauldrons. The various energy sources available to heat the primitive Earth to see if they are sufficient to cause melting were analyzed. The two largest contributors to the Earth's early heat appear to be the heat due to accretion and the heat of core formation. The Earth formed by the accretion of particles ranging in size from millimeters to hundreds of kilometers and each impact into the protoearth provided more energy to heat the body. It is found that early in the Earth's history, the sinking of iron to the center of the Earth to form the core released a substantial amount of energy; enough to heat the entire Earth an average 2000 deg C. Mechanisms for the removal of such a large amount of heat appear inadequate to prevent substantial melting, and it is assumed that the Earth was completely molten, i.e., a magma ocean at one time early in its history.

  17. Molten salt destruction process for mixed wastes

    International Nuclear Information System (INIS)

    Upadhye, R.S.; Wilder, J.G.; Karlsen, C.E.

    1993-04-01

    We are developing an advanced two-stage process for the treatment of mixed wastes, which contain both hazardous and radioactive components. The wastes, together with an oxidant gas, such as air, are injected into a bed of molten salt comprising a mixture of sodium-, potassium-, and lithium-carbonates, with a melting point of about 580 degree C. The organic constituents of the mixed waste are destroyed through the combined effect of pyrolysis and oxidation. Heteroatoms. such as chlorine, in the mixed waste form stable salts, such as sodium chloride, and are retained in the melt. The radioactive actinides in the mixed waste are also retained in the melt because of the combined action of wetting and partial dissolution. The original process, consists of a one-stage unit, operated at 900--1000 degree C. The advanced two-stage process has two stages, one for pyrolysis and one for oxidation. The pyrolysis stage is designed to operate at 700 degree C. The oxidation stage can be operated at a higher temperature, if necessary

  18. Shear rheology of molten crumb chocolate.

    Science.gov (United States)

    Taylor, J E; Van Damme, I; Johns, M L; Routh, A F; Wilson, D I

    2009-03-01

    The shear rheology of fresh molten chocolate produced from crumb was studied over 5 decades of shear rate using controlled stress devices. The Carreau model was found to be a more accurate description than the traditional Casson model, especially at shear rates between 0.1 and 1 s(-1). At shear rates around 0.1 s(-1) (shear stress approximately 7 Pa) the material exhibited a transition to a solid regime, similar to the behavior reported by Coussot (2005) for other granular suspensions. The nature of the suspension was explored by investigating the effect of solids concentration (0.20 chocolate was then compared with the rheology of (1) a synthetic chocolate, which contained sunflower oil in place of cocoa butter, and (2) a suspension of sugar of a similar size distribution (volume mean 15 mum) in cocoa butter and emulsifier. The chocolate and synthetic chocolate showed very similar rheological profiles under both steady shear and oscillatory shear. The chocolate and the sugar suspension showed similar Krieger-Dougherty dependency on volume fraction, and a noticeable transition to a stiff state at solids volume fractions above approximately 0.5. Similar behavior has been reported by Citerne and others (2001) for a smooth peanut butter, which had a similar particle size distribution and solids loading to chocolate. The results indicate that the melt rheology of the chocolate is dominated by hydrodynamic interactions, although at high solids volume fractions the emulsifier may contribute to the departure of the apparent viscosity from the predicted trend.

  19. Electrochemistry of uranium in molten LiF-CaF2

    OpenAIRE

    Nourry, Christophe; Soucek, Pavel; Massot, Laurent; Malmbeck, Rikard; Chamelot, Pierre; Glatz, Jean-Paul

    2012-01-01

    International audience; This article is focused on the electrochemical behaviour of U ions in molten LiF-CaF2 (79-21 wt.%) eutectic. On aWelectrode, U(III) is reduced in one step to U metal and U(III) can be also oxidised to U(IV). Both systems were studied by cyclic and square wave voltammetry. Reversibility of both systems for both techniques was verified and number of exchanged electrons was determined, as well as diffusion coefficients for U(III) and U(IV). The results are in a good agree...

  20. Publicity as an Instrument of Reform.

    Science.gov (United States)

    Caudill, Susan

    Albert Einstein and the Emergency Committee of Atomic Scientists (ECAS) conducted a reform-based public communication campaign for the international control of atomic energy after the Second World War. The Committee raised funds and sought publicity for its proposed solution to the problem of war and the management of peace. Its solution was the…

  1. Education Reform Sparks Teacher Protest in Mexico

    Science.gov (United States)

    Levinson, Bradley A.

    2014-01-01

    The current tumult in the Mexican education arena has deep roots in politics and tradition, but it is latter-day global competition and international measures of student performance that are driving reform efforts. Teacher strikes and demonstrations are not new in Mexico, but issues raised by today's protesting teachers represent a combination of…

  2. Economic democracy and financial reform in Vanuatu

    DEFF Research Database (Denmark)

    Pacheco Cueva, Vladimir

    2007-01-01

    commercial lending criteria. The article relies on financial hegemony theory in order to explain Vanuatu's role within larger international financial structures and rationale for reform. The discussion shows that foreign banking institutions are not interested in broadening credit access to poorer sections...

  3. Curriculum reform at Chinese medical schools: what have we learned?

    Science.gov (United States)

    Huang, Lei; Cheng, Liming; Cai, Qiaoling; Kosik, Russell Olive; Huang, Yun; Zhao, Xudong; Xu, Guo-Tong; Su, Tung-Ping; Chiu, Allen Wen-Hsiang; Fan, Angela Pei-Chen

    2014-12-01

    Curriculum reform at Chinese medical schools has attracted a lot of attention recently. Several leading medical schools in China have undergone exploratory reforms and in so doing, have accumulated significant experience and have made considerable progress. An analysis of the reforms conducted by 38 Chinese medical colleges that were targeted by the government for upgrade was performed. Drawing from both domestic and international literature, we designed a questionnaire to determine what types of curricular reforms have occurred at these institutions and how they were implemented. Major questions touched upon the purpose of the reforms, curricular patterns, improvements in teaching methods post-reform, changes made to evaluation systems post-reform, intra-university reform assessment, and what difficulties the schools faced when instituting the reforms. Besides the questionnaire, relevant administrators from each medical school were also interviewed to obtain more qualitative data. Out of the 38 included universities, twenty-five have undergone major curricular reforms. Among them, 60.0% adopted an organ system-based curriculum model, 32.0% adopted a problem-based curriculum model, and 8.0% adopted a hybrid curriculum model. About 60.0% of the schools' reforms involved both the "pre-clinical" and the "clinical" curricula, 32.0% of the schools' reforms were limited to the "pre-clinical" curricula, and 8.0% of the schools' reforms only involved the "clinical" curricula. Following curricular reform, 60.0% of medical schools experienced an overall reduction in teaching hours, 76.0% reported an increase in their students' clinical skills, and 60.0% reported an increase in their students' research skills. Medical curricular reform is still in its infancy in China. The republic's leading medical schools have engaged in various approaches to bring innovative teaching methods to their respective institutions. However, due to limited resources and the shackle of traditional

  4. Advances in reforming and partial oxidation of hydrocarbons for hydrogen production and fuel cell applications

    OpenAIRE

    Sengodan, Sivaprakash; Lan, Rong; Humphreys, John; Du, Dongwei; Xu, Wei; Wang, Huanting; Tao, Shanwen

    2017-01-01

    One of the most attractive routes for the production of hydrogen or syngas for use in fuel cell applications is the reforming and partial oxidation of hydrocarbons. The use of hydrocarbons in high temperature fuel cells is achieved through either external or internal reforming. Reforming and partial oxidation catalysis to convert hydrocarbons to hydrogen rich syngas plays an important role in fuel processing technology. The current research in the area of reforming and partial oxidation of me...

  5. Reforming Educational Reform: A Democratic Perspective

    Science.gov (United States)

    Green, J.

    2005-05-01

    This essay examines the status of educational reform in the United States as represented by the current Bush administration's program titled "No Child Left Behind" (NCLB). Employing the techniques of critical theory and logical analysis, contemporary reform efforts are compared with other, more progressive, educational reform movements in an effort to gain perspective and conceptual "traction" as it were, in differentiating such movements. Criteria are established for the assessment and evaluation of reform movements. These are employed in judging the efficacy of NCLB's aim, content, and methods, as well as the results of its program following four years of implementation. The merits of the centrality of standardized testing, pre-ordained curricular content, and exclusively didactic teaching methodologies are criticized, along with the extra-school societal forces which ordain these and determine their prominence in the NCLB program. The essentialism adopted by NCLB is, moreover, evaluated in the light of pragmatic, phenomenological, and postmodern educational theory. Arguing that the school is always and inevitably an instrument of societal forces, interests, and groups, it is contended that these not only be acknowledged, but that avenues be formalized for a thorough going and continuous educational "conversation," to borrow Rorty's term, for an amicable resolution of the issues of education's aim(s), content, and methods.

  6. Security Sector Reform in Liberia: Mixed Results from Humble Beginnings

    National Research Council Canada - National Science Library

    Malan, Mark

    2008-01-01

    The reform and the democratic control of the security sector and the joining together of security and development have become a major focus of international intervention into post-conflict societies...

  7. THE REFORM OF NATIONAL SOCIAL-ECONOMIC SYSTEMS AND EUROPEAN REFORM

    Directory of Open Access Journals (Sweden)

    Carmen RADU

    2016-06-01

    Full Text Available The paper proposes to analyze from a national and European perspective the reform possibilities of public policies which regard the social-economic sphere. We thus take into consideration the analysis of the public policies’ evolution regarding the health system, pensions system, demographic stimulation and the undertaking of key-structural reforms for economy and administration. Resources marked as necessary for a reform are burdened by new challenges emerged on the international agenda: a new economic crisis with starting point in China, managing evolutions on fuel markets, managing the refugees exodus situation which forces the European Union’s frontiers, etc. Establishing social-economic security at national level as well as in the European Union depends on the pragmatism of economic and social policies as well as on the courage to start a reform.

  8. Supported Molten Metal Catalysis. A New Class of Catalysts

    Energy Technology Data Exchange (ETDEWEB)

    Ravindra Datta; Ajeet Singh; Manuela Serban; Istvan Halasz

    2006-06-02

    We describe a new class of heterogeneous catalysts called supported molten metal catalysis (SMMC), in which molten metal catalysts are dispersed as nanodroplets on the surface of porous supports, allowing much larger active surface area than is possible in conventional contacting techniques for catalytic metals that are molten under reaction conditions, thus greatly enhancing their activity and potential utility. Specific examples of different types of reactions are provided to demonstrate the broad applicability of the technique in designing active, selective, and stable new catalysts. It is shown that dispersing the molten metal on a support in the suggested manner can enhance the rate of a reaction by three to four orders of magnitude as a result of the concomitant increase in the active surface area. New reaction examples include {gamma}-Al{sub 2}O{sub 3} supported molten Te (melting point 450 C) and Ga (MP 30 C) catalysts for bifunctional methylcyclohexane dehydrogenation. These catalysts provide activity similar to conventional Pt-based catalysts for this with better resistance to coking. In addition, results are described for a controlled pore glass supported molten In (MP 157 C) catalyst for the selective catalytic reduction of NO with ethanol in the presence of water, demonstrating activities superior to conventional catalysts for this reaction. A discussion is also provided on the characterization of the active surface area and dispersion of these novel supported catalysts. It is clear based on the results described that the development of new active and selective supported molten metal catalysts for practical applications is entirely plausible.

  9. Multi-fuel reformers for fuel cells used in transportation. Phase 1: Multi-fuel reformers

    Science.gov (United States)

    1994-05-01

    DOE has established the goal, through the Fuel Cells in Transportation Program, of fostering the rapid development and commercialization of fuel cells as economic competitors for the internal combustion engine. Central to this goal is a safe feasible means of supplying hydrogen of the required purity to the vehicular fuel cell system. Two basic strategies are being considered: (1) on-board fuel processing whereby alternative fuels such as methanol, ethanol or natural gas stored on the vehicle undergo reformation and subsequent processing to produce hydrogen, and (2) on-board storage of pure hydrogen provided by stationary fuel processing plants. This report analyzes fuel processor technologies, types of fuel and fuel cell options for on-board reformation. As the Phase 1 of a multi-phased program to develop a prototype multi-fuel reformer system for a fuel cell powered vehicle, the objective of this program was to evaluate the feasibility of a multi-fuel reformer concept and to select a reforming technology for further development in the Phase 2 program, with the ultimate goal of integration with a DOE-designated fuel cell and vehicle configuration. The basic reformer processes examined in this study included catalytic steam reforming (SR), non-catalytic partial oxidation (POX) and catalytic partial oxidation (also known as Autothermal Reforming, or ATR). Fuels under consideration in this study included methanol, ethanol, and natural gas. A systematic evaluation of reforming technologies, fuels, and transportation fuel cell applications was conducted for the purpose of selecting a suitable multi-fuel processor for further development and demonstration in a transportation application.

  10. Catalytic reforming methods

    Science.gov (United States)

    Tadd, Andrew R; Schwank, Johannes

    2013-05-14

    A catalytic reforming method is disclosed herein. The method includes sequentially supplying a plurality of feedstocks of variable compositions to a reformer. The method further includes adding a respective predetermined co-reactant to each of the plurality of feedstocks to obtain a substantially constant output from the reformer for the plurality of feedstocks. The respective predetermined co-reactant is based on a C/H/O atomic composition for a respective one of the plurality of feedstocks and a predetermined C/H/O atomic composition for the substantially constant output.

  11. Experimental research on the dynamic behaviors of the keyhole and molten pool in laser deep-penetration welding

    Science.gov (United States)

    Zhang, Yi; Lin, Qida; Yin, Xuni; Li, Simeng; Deng, Jiquan

    2018-04-01

    Both the morphology and temperature are two important characteristics of the keyhole and the molten pool in laser deep-penetration welding. The modified ‘sandwich’ method was adopted to overcome the difficulty in obtaining inner information about the keyhole and the molten pool. Based on this method, experimental platforms were built for observing the variations in the surface morphology, the longitudinal keyhole profile and the internal temperature. The experimental results of three dynamic behaviors exbibit as follows. The key factor, which makes the pool width go into a quasi-steady state, lies in the balance between the vortex and the sideways flows around the keyhole. Experimental observation shows that the keyhole goes through three stages in laser welding: the rapid drilling stage, the slow drilling stage and the quasi-steady state. The time for achieving a relative fixed keyhole depth is close to the formation time of the maximum pool width. The internal temperatures inside the keyhole and the molten pool first experience a rapid increase, then a decrease and finally go into a quasi-steady state. Compared to that in the unstable stage, the liquid–metal uphill formed in the stable stage of laser welding has less influence on the internal temperature.

  12. The adherence of education reform to international education policy. A brief overview of the path from the General Law of the Education System (LOGSE of 1990 to the Law for the Improvement of Education Quality (LOMCE of 2013

    Directory of Open Access Journals (Sweden)

    Blas Cabrera Montoya

    2016-01-01

    Full Text Available The aim of this paper is to illustrate the continuities of educational reforms in the Spanish democracy, and especially between the General Law of the Education System (LOGSE of 1990 and the Law for the Improvement of Education Quality (LOMCE of 2013. In order to do so we will examine what we consider to be the three main concerns on which current educational patterns are based: first, the crisis of the traditional materials and symbolic functions of universal education systems under capitalism, which entails a slowtransformation in mentalities regarding the social importance of education; secondly, the inevitable dependence of virtually all Spanish education legislation in democracy to the provisions of Article 27 of the Spanish Constitution of 1978; and finally, the greater role that the laws attribute to international assessment and accountability in Spain. This last point is the most important new feature of educational policy in the last twenty five years.

  13. Thermodynamical simulation for solid oxide (SOFC) type fuel cells with ethanol direct internal reforming; Simulacao termodinamica para celulas a combustivel do tipo SOFC com reforma interna direta do etanol

    Energy Technology Data Exchange (ETDEWEB)

    Silva, Aline Lima da; Malfatti, Celia de Fraga; Heck, Nestor Cezar [Universidade Federal do Rio Grande do Sul (UFRGS), Porto Alegre, RS (Brazil). Programa de Pos-Graduacao em Engenharia de Minas, Metalurgica e de Materiais (PPGEM)]. E-mail: als14br2000@yahoo.com.br; Mello, Celso Gustavo [Universidade Federal do Rio Grande do Sul (UFRGS), Porto Alegre, RS (Brazil). Programa de Pos-Graduacao em Engenharia Quimica (PPGEQ); Halmenschlager, Cibele Melo [Universidade Federal do Rio Grande do Sul (UFRGS), Porto Alegre, RS (Brazil). Programa de Pos-Graduacao em Engenharia de Minas, Metalurgica e de Materiais (PPGEM). Lab. de Materiais Ceramicos

    2008-07-01

    In SOFC, high operative temperature allows the direct conversion of ethanol into H{sub 2} to take place in the electrochemical cell. Direct internal reforming of ethanol, however, can produce undesirable products that diminish system efficiency and, in the case of carbon deposition over the anode, may occur the breakdown of the electrode. In this way, thermodynamic analysis is fundamental to predict the product distribution as well as the conditions favorable for carbon to precipitate inside the cell. Equilibrium determinations are performed by the Gibbs energy minimization method, using the GRG algorithm. Thermodynamic conditions for carbon deposition were analyzed, in order to establish temperature ranges and H{sub 2}O/ethanol ratios where carbon precipitation is not feasible. A mathematical relationship between Lagrange multipliers and carbon activity is presented, unveiling the carbon activity in atmosphere. The effect of the type of solid electrolyte (O{sup 2-} or H{sup +} conducting) on carbon formation is also investigated. The results of this work are in agreement with previous results reported in literature using the stoichiometric method. (author)

  14. LIFE Materails: Molten-Salt Fuels Volume 8

    Energy Technology Data Exchange (ETDEWEB)

    Moir, R; Brown, N; Caro, A; Farmer, J; Halsey, W; Kaufman, L; Kramer, K; Latkowski, J; Powers, J; Shaw, H; Turchi, P

    2008-12-11

    The goals of the Laser Inertial Fusion Fission Energy (LIFE) is to use fusion neutrons to fission materials with no enrichment and minimum processing and have greatly reduced wastes that are not of interest to making weapons. Fusion yields expected to be achieved in NIF a few times per day are called for with a high reliable shot rate of about 15 per second. We have found that the version of LIFE using TRISO fuel discussed in other volumes of this series can be modified by replacing the molten-flibe-cooled TRISO fuel zone with a molten salt in which the same actinides present in the TRISO particles are dissolved in the molten salt. Molten salts have the advantage that they are not subject to radiation damage, and hence overcome the radiation damage effects that may limit the lifetime of solid fuels such as TRISO-containing pebbles. This molten salt is pumped through the LIFE blanket, out to a heat exchanger and back into the blanket. To mitigate corrosion, steel structures in contact with the molten salt would be plated with tungsten or nickel. The salt will be processed during operation to remove certain fission products (volatile and noble and semi-noble fission products), impurities and corrosion products. In this way neutron absorbers (fission products) are removed and neutronics performance of the molten salt is somewhat better than that of the TRISO fuel case owing to the reduced parasitic absorption. In addition, the production of Pu and rare-earth elements (REE) causes these elements to build up in the salt, and leads to a requirement for a process to remove the REE during operation to insure that the solubility of a mixed (Pu,REE)F3 solid solution is not exceeded anywhere in the molten salt system. Removal of the REE will further enhance the neutronics performance. With molten salt fuels, the plant would need to be safeguarded because materials of interest for weapons are produced and could potentially be removed.

  15. Non-catalytic recuperative reformer

    Science.gov (United States)

    Khinkis, Mark J.; Kozlov, Aleksandr P.; Kurek, Harry

    2015-12-22

    A non-catalytic recuperative reformer has a flue gas flow path for conducting hot flue gas from a thermal process and a reforming mixture flow path for conducting a reforming mixture. At least a portion of the reforming mixture flow path is embedded in the flue gas flow path to permit heat transfer from the hot flue gas to the reforming mixture. The reforming mixture flow path contains substantially no material commonly used as a catalyst for reforming hydrocarbon fuel (e.g., nickel oxide, platinum group elements or rhenium), but instead the reforming mixture is reformed into a higher calorific fuel via reactions due to the heat transfer and residence time. In a preferred embodiment, extended surfaces of metal material such as stainless steel or metal alloy that are high in nickel content are included within at least a portion of the reforming mixture flow path.

  16. Application of lithium in molten-salt reduction processes

    International Nuclear Information System (INIS)

    Gourishankar, K. V.

    1998-01-01

    Metallothermic reductions have been extensively studied in the field of extractive metallurgy. At Argonne National Laboratory (ANL), we have developed a molten-salt based reduction process using lithium. This process was originally developed to reduce actinide oxides present in spent nuclear fuel. Preliminary thermodynamic considerations indicate that this process has the potential to be adapted for the extraction of other metals. The reduction is carried out at 650 C in a molten-salt (LiCl) medium. Lithium oxide (Li 2 O), produced during the reduction of the actinide oxides, dissolves in the molten salt. At the end of the reduction step, the lithium is regenerated from the salt by an electrowinning process. The lithium and the salt from the electrowinning are then reused for reduction of the next batch of oxide fuel. The process cycle has been successfully demonstrated on an engineering scale in a specially designed pyroprocessing facility. This paper discusses the applicability of lithium in molten-salt reduction processes with specific reference to our process. Results are presented from our work on actinide oxides to highlight the role of lithium and its effect on process variables in these molten-salt based reduction processes

  17. Overview on CO2 valorisation: challenge of molten carbonates

    Directory of Open Access Journals (Sweden)

    Déborah eChery

    2015-10-01

    Full Text Available The capture and utilisation of CO2 is becoming progressively one of the significant challenges in the field of energetic resources. Whatever the energetic device, it is impossible to avoid completely the production of greenhouse gas, even parting from renewable energies. Transforming CO2 in a valuable fuel, such as alcohols, CO or even C, could constitute a conceptual revolution in the energetic bouquet offering a huge application domain. Although several routes have been tested for this purpose, on which a general panorama will be given here, molten carbonates are attracting a renewed interest aiming at dissolving and reducing carbon dioxide in such melts. Because of their unique properties, molten carbonates are already used as electrolytes in molten carbonate fuel cells; they can also provoke a breakthrough in a new economy considering CO2 as an energetic source rather than a waste. Molten carbonates science and technology is becoming a strategic field of research for energy and environmental issues. Our aim in this review is to put in evidence the benefits of molten carbonates to valorise CO2 and to show that it is one of the most interesting routes for such application.

  18. Social Security Reform

    National Research Council Canada - National Science Library

    Nuschler, Dawn

    2005-01-01

    .... In recent years, reform ideas have ranged from relatively minor changes to the current pay-as-you-go social insurance system to a redesigned program based on personal savings and investments modeled after IRAs and 401(k...

  19. High temperature nuclear heat for isothermal reformer

    International Nuclear Information System (INIS)

    Epstein, M.

    2000-01-01

    the heat to the reformer and condense on its walls. Three configurations can be conceived. The vapors of the sodium are condensed on the outside surface of the reformer tube and the liquid is then drained into a pool-boiling-He/Na heat exchanger. Another option is internal heating of an annular catalyst bed reformer with a sodium heat pipe, for instance. The third option is reformer tubes immersed inside the boiling medium. In all cases means for the enhancement of heat transfer can be applied. The use of condensing metal vapors increases the heat transfer compared to the convective reformer, resulting in more compact reformers. The safety aspects of this approach are twofold: (a) Additional physical separation between the nuclear reactor coolant and the chemical plant. This will enable to reduce the operating pressure inside the reformer, thus reducing the working temperature and increasing the extent on the reaction and the CH 4 conversion. (b) In case of a failure in the chemical plant. the liquid metal can be used as a safety buffer. In this event, the vapors of the medium material are diverted and condensed in an emergency condenser and returned to the pool boiling by natural circulation, avoiding the need to reduce immediately the power rating of the nuclear reactor or even its complete shutdown. (author)

  20. Reformer Fuel Injector

    Science.gov (United States)

    Suder, Jennifer L.

    2004-01-01

    Today's form of jet engine power comes from what is called a gas turbine engine. This engine is on average 14% efficient and emits great quantities of green house gas carbon dioxide and air pollutants, Le. nitrogen oxides and sulfur oxides. The alternate method being researched involves a reformer and a solid oxide fuel cell (SOFC). Reformers are becoming a popular area of research within the industry scale. NASA Glenn Research Center's approach is based on modifying the large aspects of industry reforming processes into a smaller jet fuel reformer. This process must not only be scaled down in size, but also decrease in weight and increase in efficiency. In comparison to today's method, the Jet A fuel reformer will be more efficient as well as reduce the amount of air pollutants discharged. The intent is to develop a 10kW process that can be used to satisfy the needs of commercial jet engines. Presently, commercial jets use Jet-A fuel, which is a kerosene based hydrocarbon fuel. Hydrocarbon fuels cannot be directly fed into a SOFC for the reason that the high temperature causes it to decompose into solid carbon and Hz. A reforming process converts fuel into hydrogen and supplies it to a fuel cell for power, as well as eliminating sulfur compounds. The SOFC produces electricity by converting H2 and CO2. The reformer contains a catalyst which is used to speed up the reaction rate and overall conversion. An outside company will perform a catalyst screening with our baseline Jet-A fuel to determine the most durable catalyst for this application. Our project team is focusing on the overall research of the reforming process. Eventually we will do a component evaluation on the different reformer designs and catalysts. The current status of the project is the completion of buildup in the test rig and check outs on all equipment and electronic signals to our data system. The objective is to test various reformer designs and catalysts in our test rig to determine the most

  1. The Danish school reform

    DEFF Research Database (Denmark)

    Bager, Ann; Mølholm, Martin; Horsbøl, Anders

    The paper presents a methodological framework for the study of the discursive emergence of the recent Danish School reform (2014). The framework will enable discourse scholars to hold an actively involved position in changing and furthering plurivocal processes of translations, negotiations...... and implementation of the reform. The framework is operationalized through research-based participatory collaborative processes involving local actors in two Danish public schools. It interlinks diverse discourse strategies and perceptive distances that traditionally belong to separate branches within discourse...

  2. Psychiatric reform in Greece: an overview.

    Science.gov (United States)

    Giannakopoulos, George; Anagnostopoulos, Dimitris C

    2016-12-01

    Leros became infamous worldwide in the 1980s because of a scandal in its mental institution, the Leros asylum. The scandal provoked universal outrage and the international pressure triggered the Greek mental health reform. Under the reform projects Leros I and Leros II (1990-1994), numerous interventions took place in the Leros asylum as part of deinstitutionalisation. Following that, the Psychargos programme advanced developments for community-based services. Deinstitutionalisation and development of community mental health services have advanced significantly since the 1980s. However, this reform is still incomplete, given that sectorisation, adequate primary care policies, inter-sectoral coordination and specialised services are under-developed. This problematic situation is further complicated by the severe impact of the current financial crisis.

  3. Design of a nuclear steam reforming plant

    International Nuclear Information System (INIS)

    Malherbe, J.

    1980-01-01

    The design of a plant for the steam reforming of methane using a High Temperature Reactor has been studied by CEA in connection with the G.E.G.N. This group of companies (CEA, GAZ DE FRANCE, CHARBONNAGES DE FRANCE, CREUSOT-LOIRE, NOVATOME) is in charge of studying the feasibility of the coal gasification process by using a nuclear reactor. The process is based on the hydrogenation of the coal in liquid phase with hydrogen produced by a methane steam reformer. The reformer plant is fed by a pipe of natural gas or SNG. The produced hydrogen feeds the gasification plant which could not be located on the same site. An intermediate hydrogen storage between the two plants could make the coupling more flexible. The gasification plant does not need a great deal of heat and this heat can be satisfied mostly by internal heat exchanges

  4. Electricity sector reform in Greece

    International Nuclear Information System (INIS)

    Iliadou, Ekaterini N.

    2009-01-01

    This paper provides an outlook of the electricity market reform in Greece which started in 2001 and is still developing slowly. This is related to the persisting dominance of the incumbent company and the specificities of the electricity sector of Greece which is heavily dependent on indigenous lignite firing generation, while being located in the periphery of the EU internal electricity and gas markets. Competition through enhancing electricity trade in the region is limited to date, as the establishment of an internal market in South East Europe also progresses slowly. Development of competition through gas-firing generation by new entrants has been the priority adopted by State and Regulator's policies. However, the gas supply market in Greece and in the region still lags behind. (author)

  5. Science Education Reform in Qatar: Progress and Challenges

    Science.gov (United States)

    Said, Ziad

    2016-01-01

    Science education reform in Qatar has had limited success. In the Trends in International Mathematics and Science Study (TIMMS), Qatari 4th and 8th grade students have shown progress in science achievement, but they remain significantly below the international average. Also, in the Program for International Student Assessment (PISA), Qatari…

  6. Immigration reform, American style.

    Science.gov (United States)

    Papademetriou, D G

    1984-01-01

    This article reviews the background of the proposed Immigration and Reform Act (also known as the Simpson-Mazzoli bill), which seeks to overhaul US immigration law for the first time since 1952. This bill is consistent with President Reagan's hard line on border enforcement and mandates stiff penalties for those who transport illegal aliens for commercial advantage or private profit. It further offers Mexico preferential treatment in immigration (40,000 additional visas/year). It includes an amnesty program to offer legal status to qualified illegal residents. The bill directs the President to develop a secure national worker identification system and would create a large-scale temporary foreign agricultural program for perishable commodities. Agricultural workers' families would not be eligible to accompany them unless they also obtain temporary visas. Foreign temporary workers, employable only in cases where local domestic workers are not available, must be provided with wages and working conditions equal to those prevailing among domestic workers. Stiff penalties are stipulated for employers who fail to abide with the terms of the program. In the author's opinion, this bill fails to appreciate the global character of international migration and its complexity. It relects a fundamental ambivalence about a strictly controlled main gate versus a back door approach to immigration as well as the conflicting images of the US as a nation of immigrants versus the historical reality of American nativism and xenophobia. Needed are comprehensive initiatives whose mutually reinforcing components can address the multiple dimensions of the immigration problem within a framework that does not ignore workers who have contributed to the economic well-being of the US, regardless of their legal status.

  7. Global implications of China's healthcare reform.

    Science.gov (United States)

    Yan, Fei; Tang, Shenglan; Zhang, Jian

    2016-01-01

    The ongoing healthcare reform in China has a powerful spillover effect beyond the health sector and the borders of China. A successful completion of the Chinese reform will offer a new model for social justice development, shift the global economy toward sustainability and create a new hub for science and technology in medical and health science. However, reforming the healthcare system in the most populated country is a daunting task. China will not live up to its promise, and all the potentials may end with hype not hope if coherent national strategies are not constructed and state-of-the-art navigation is not achieved with staggering domestic and global challenges. The cost of failure will be immensely high, socioeconomic costs for Chinese and an opportunity cost for the world as a whole. A full appreciation of the global implications of China's healthcare reform is crucial in keeping China receptive toward good practices evidence-approved elsewhere and open minded to fulfill its international obligations. More critically, the appreciation yields constructive engagements from global community toward a joint development and global prosperity. The current report provides a multiple disciplinary assessment on the global implications of the healthcare reform in China. Copyright © 2014 John Wiley & Sons, Ltd.

  8. Presence of Li Clusters in Molten LiCl-Li

    Science.gov (United States)

    Merwin, Augustus; Phillips, William C.; Williamson, Mark A.; Willit, James L.; Motsegood, Perry N.; Chidambaram, Dev

    2016-05-01

    Molten mixtures of lithium chloride and metallic lithium are of significant interest in various metal oxide reduction processes. These solutions have been reported to exhibit seemingly anomalous physical characteristics that lack a comprehensive explanation. In the current work, the physical chemistry of molten solutions of lithium chloride and metallic lithium, with and without lithium oxide, was investigated using in situ Raman spectroscopy. The Raman spectra obtained from these solutions were in agreement with the previously reported spectrum of the lithium cluster, Li8. This observation is indicative of a nanofluid type colloidal suspension of Li8 in a molten salt matrix. It is suggested that the formation and suspension of lithium clusters in lithium chloride is the cause of various phenomena exhibited by these solutions that were previously unexplainable.

  9. Deuterium retention in molten salt electrodeposition tungsten coatings

    International Nuclear Information System (INIS)

    Zhou, Hai-Shan; Xu, Yu-Ping; Sun, Ning-Bo; Zhang, Ying-Chun; Oya, Yasuhisa; Zhao, Ming-Zhong; Mao, Hong-Min; Ding, Fang; Liu, Feng; Luo, Guang-Nan

    2016-01-01

    Highlights: • We investigate D retention in electrodeposition W coatings. • W coatings are exposed to D plasmas in the EAST tokamak. • A cathodic current density dependence on D retention is found. • Electrodeposition W exhibits lower D retention than VPS-W. - Abstract: Molten salt electrodeposition is a promising technology to manufacture the first wall of a fusion reactor. Deuterium (D) retention behavior in molten salt electrodeposition tungsten (W) coatings has been investigated by D-plasma exposure in the EAST tokamak and D-ion implantation in an ion beam facility. Tokamak exposure experiments demonstrate that coatings prepared with lower current density exhibit less D retention and milder surface damage. Deuterium-ion implantation experiments indicate the D retention in the molten salt electrodeposition W is less than that in vacuum plasma spraying W and polycrystalline W.

  10. Critical survey on electrode aging in molten carbonate fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Kinoshita, K.

    1979-12-01

    To evaluate potential electrodes for molten carbonate fuel cells, we reviewed the literature pertaining to these cells and interviewed investigators working in fuel cell technology. In this critical survey, the effect of three electrode aging processes - corrosion or oxidation, sintering, and poisoning - on these potential fuel-cell electrodes is presented. It is concluded that anodes of stabilized nickel and cathodes of lithium-doped NiO are the most promising electrode materials for molten carbonate fuel cells, but that further research and development of these electrodes are needed. In particular, the effect of contaminants such as H/sub 2/S and HCl on the nickel anode must be investigated, and methods to improve the physical strength and to increase the conductivity of NiO cathodes must be explored. Recommendations are given on areas of applied electrode research that should accelerate the commercialization of the molten carbonate fuel cell. 153 references.

  11. First principles molecular dynamics of molten NaCl

    Science.gov (United States)

    Galamba, N.; Costa Cabral, B. J.

    2007-03-01

    First principles Hellmann-Feynman molecular dynamics (HFMD) results for molten NaCl at a single state point are reported. The effect of induction forces on the structure and dynamics of the system is studied by comparison of the partial radial distribution functions and the velocity and force autocorrelation functions with those calculated from classical MD based on rigid-ion and shell-model potentials. The first principles results reproduce the main structural features of the molten salt observed experimentally, whereas they are incorrectly described by both rigid-ion and shell-model potentials. Moreover, HFMD Green-Kubo self-diffusion coefficients are in closer agreement with experimental data than those predicted by classical MD. A comprehensive discussion of MD results for molten NaCl based on different ab initio parametrized polarizable interionic potentials is also given.

  12. Stability of Sodium Electrodeposited From a Series of Room Temperature Chloroaluminate Molten Salts

    National Research Council Canada - National Science Library

    Gray, Gary

    1996-01-01

    .... This work&involved the synthesis of room temperature molten salts and the examination of the electrochemical and transport properties of these salts with the goal of developing a room temperature molten salt...

  13. Molten salt reactors. Synthesis of studies realized between 1973 and 1983. Metallic materials file

    International Nuclear Information System (INIS)

    1983-03-01

    Metallic materials for molten salt reactors are studied. The corrosion of steels by the eutectic LiF-BeF 2 and molten lead is examined. Fabrication, aging and welding of molybdenum or TZM tubes are also examined. [fr

  14. Feasibility study of hydrogen generator with molten slag granulation

    Energy Technology Data Exchange (ETDEWEB)

    Akiyama, T.; Mizuochi, T. [Graduate School of Engineering, Osaka Pref. Univ., Sakai, Osaka (Japan); Yagi, J.I.; Nogami, H. [Inst. of Multidisciplinary Research for Advanced Materials, Tohoku Univ., Aobaku, Sendai (Japan)

    2004-02-01

    A huge amount of hot molten oxides, such as steelmaking slag and molten municipal waste, is discharged at present without heat recovery, in spite of its very high potential. For example, hot molten slag as a byproduct in the Japanese steelmaking industry, over 1723 K in temperature, reaches as much as 30 million tonnes annually. To recover heat of the viscous slag chemically, the strongly endothermic reaction CH{sub 4}+H{sub 2}O {yields} 3H{sub 2}+CO was selected and then the property of dry granulation of the molten slag by rotary cup atomizer (RCA) for expanding surface area of the slag was experimentally studied. The purpose of this paper was, therefore, to study slag granulation under various conditions for promoting heat exchange between slag and gas, in which the influence of the rotating speed and the shape of the cup on the slag drop size was mainly examined. The collected slag drops were correlated with operating conditions such as rotating speed, cup shape, etc. Most significantly, the molten slag was successfully granulated under the dry conditions without water impingement. The rotating speed of the cup influenced the diameter and shape of the slag drops very strongly. The higher rotating speed made the slag drops smaller, more spherical and uniform. Drops with 5 to 6 mm of average dimension were obtained at a rotating speed of 15 rps (900 rpm), and drops with about 1 mm at 50 rps (3000 rpm). In the former case, the shape of the obtained drops changed from spherical to ribbon-like. These results will be useful to establish new heat recovery processes with hydrogen generation from molten slag with many benefits. Energy analysis and cost evaluation were also conducted, to study the benefit of the proposed process. (orig.)

  15. Beryllium research on FFHR molten salt blanket

    International Nuclear Information System (INIS)

    Terai, T.; Tanaka, S.; Sze, D.-K.

    2000-01-01

    Force-free helical reactor, FFHR, is a demo-relevant heliotron-type D-T fusion reactor based on the great amount of R and D results obtained in the LHD project. Since 1993, collaboration works have made great progress in design studies of FFHR with standing on the major advantage of current-less steady operation with no dangerous plasma disruptions. There are two types of reference designs, FFHR-1 and FFHR-2, where molten Flibe (LiF-BeF2) is utilized as tritium breeder and coolant. In this paper, we present the outline of FFHR blanket design and some related R and D topics focusing on Be utilization. Beryllium is used as a neutron multiplier in the design and Be pebbles are placed in the front part of the tritium breeding zone. In a Flibe blanket, HF (TF) generated due to nuclear transmutation will be a problem because of its corrosive property. Though nickel-based alloys are thought to be intact in such a corrosive environment, FFHR blanket design does not adopt the alloys because of their induced radioactivity. The present candidate materials for the structure are low-activated ferritic steel (JLF-1), V-4Cr-4Ti, etc. They are capable to be corroded by HF in the operation condition, and Be is expected to work as a reducing agent in the system as well. Whether Be pebbles placed in a Flibe flow can work well or not is a very important matter. From this point, Be solubility in Flibe, reaction rate of the Redox reaction with TF in the liquid and on the surface of Be pebbles under irradiation, flowing behavior of Flibe through a Be pebble bed, etc. should be investigated. In 1997, in order to establish more practical and new data bases for advanced design works, we started a collaboration work of R and D on blanket engineering, where the Be research above mentioned is included. Preliminary dipping-test of Be sheets and in-situ tritium release experiment from Flibe with Be sheets have got started. (orig.)

  16. Electrochemical Deposition of High Purity Silicon from Molten Salts

    Science.gov (United States)

    Haarberg, Geir Martin

    Several approaches were tried in order to develop an electrochemical route for producing high purity silicon from molten salts. SiO2, K2SiF6 and metallurgical silicon were used as the source of silicon. Molten electrolytes based on chloride (CaCl2-NaCl) and fluoride (LiF-KF) at temperatures from 550 - 900 oC were used. Transient electrochemical techniques were used to study the electrochemical behaviour of dissolved silicon species. Electrolysis experiments were carried out to deposit silicon.

  17. Electrochemical Deposition of High Purity Silicon in Molten Salts

    Science.gov (United States)

    Haarberg, Geir Martin

    Several approaches were tried in order to develop an electrochemical route for producing high purity silicon from molten salts. SiO2, K2SiF6 and metallurgical silicon were used as the source of silicon. Molten electrolytes based on chloride (CaCl2-NaCl) and fluoride (LiF-KF) at temperatures from 550 - 900 °C were used. Transient electrochemical techniques were used to study the electrochemical behaviour of dissolved silicon species. Electrolysis experiments were carried out to deposit silicon.

  18. Boric Ester-Type Molten Salt via Dehydrocoupling Reaction

    OpenAIRE

    Noriyoshi Matsumi; Yoshiyuki Toyota; Prerna Joshi; Puhup Puneet; Raman Vedarajan; Toshihiro Takekawa

    2014-01-01

    Novel boric ester-type molten salt was prepared using 1-(2-hydroxyethyl)-3-methylimidazolium chloride as a key starting material. After an ion exchange reaction of 1-(2-hydroxyethyl)-3-methylimidazolium chloride with lithium (bis-(trifluoromethanesulfonyl) imide) (LiNTf2), the resulting 1-(2-hydroxyethyl)-3-methylimidazolium NTf2 was reacted with 9-borabicyclo[3.3.1]nonane (9-BBN) to give the desired boric ester-type molten salt in a moderate yield. The structure of the boric ester-type molt...

  19. Fabrication of catalytic electrodes for molten carbonate fuel cells

    Science.gov (United States)

    Smith, James L.

    1988-01-01

    A porous layer of catalyst material suitable for use as an electrode in a molten carbonate fuel cell includes elongated pores substantially extending across the layer thickness. The catalyst layer is prepared by depositing particulate catalyst material into polymeric flocking on a substrate surface by a procedure such as tape casting. The loaded substrate is heated in a series of steps with rising temperatures to set the tape, thermally decompose the substrate with flocking and sinter bond the catalyst particles into a porous catalytic layer with elongated pores across its thickness. Employed as an electrode, the elongated pores provide distribution of reactant gas into contact with catalyst particles wetted by molten electrolyte.

  20. Study of an F center in molten KCl

    Energy Technology Data Exchange (ETDEWEB)

    Parrinello, M.; Rahman, A.

    1984-01-15

    It is shown that a discretized version of Feynman's path integral provides a convenient tool for the numerical investigation of the properties of an electron solvated in molten KCl. The binding energy, the magnetic susceptibility, and the pair correlation functions are calculated. The local structure around the solute electron appears to be different from that of an F center in the solid. The Feynman path of the electron dissolved in molten KCl is highly localized thus justifying the F center model. The effect of varying the e/sup -/-K/sup +/ pseudopotential is also reported.

  1. Renewing Liquid Fueled Molten Salt Reactor Research and Development

    Science.gov (United States)

    Towell, Rusty; NEXT Lab Team

    2016-09-01

    Globally there is a desperate need for affordable, safe, and clean energy on demand. More than anything else, this would raise the living conditions of those in poverty around the world. An advanced reactor that utilizes liquid fuel and molten salts is capable of meeting these needs. Although, this technology was demonstrated in the Molten Salt Reactor Experiment (MSRE) at ORNL in the 60's, little progress has been made since the program was cancelled over 40 years ago. A new research effort has been initiated to advance the technical readiness level of key reactor components. This presentation will explain the motivation and initial steps for this new research initiative.

  2. Molten Triazolium Chloride Systems as New Aluminum Battery Electrolytes

    DEFF Research Database (Denmark)

    Vestergaard, B.; Bjerrum, Niels; Petrushina, Irina

    1993-01-01

    The possibility of using molten mixtures of 1,4-dimethyl-1,2,4-triazolium chloride (DMTC) and aluminum chloride (AlCl3) as secondary battery electrolytes was studied, in some cases extended by the copresence of sodium chloride. DMTC-AlCl, mixtures demonstrated high specific conductivity in a wide...... of milliamperes per square centimeter) was observed at 0.344 V on the acidic sodium tetrachloroaluminate background, involving a free triazolium radical mechanism. Molten DMTC-AlCl3 electrolytes are acceptable for battery performance and both the aluminum anode and the triazolium electrolyte can be used as active...

  3. Transfer characteristics of a lithium chloride–potassium chloride molten salt

    OpenAIRE

    Eve Mullen; Ross Harris; Dave Graham; Chris Rhodes; Zara Hodgson

    2017-01-01

    Pyroprocessing is an alternative method of reprocessing spent fuel, usually involving the dissolving spent fuel in a molten salt media. The National Nuclear Laboratory designed, built, and commissioned a molten salt dynamics rig to investigate the transfer characteristics of molten lithium chloride–potassium chloride eutectic salt. The efficacy and flow characteristics of a high-temperature centrifugal pump and argon gas lift were obtained for pumping the molten salt at temperatures up to 500...

  4. Distinctions, Affiliations, and Professional Knowledge in Financial Reform Expert Groups

    DEFF Research Database (Denmark)

    Seabrooke, Leonard; Tsingou, Eleni

    2014-01-01

    to understand the different stresses in reports with and without clear mandates, and the role of important members of the policy community in promoting particular reform ideas. The contribution finds that differences in ideas emerging from the financial reform expert groups reflect nested power relationships......Who determines what ideas matter in reform debates? This contribution examines reform proposals from the expert groups that emerged during the recent international financial crisis. To do so it follows fractal distinctions – distinctions that replicate themselves in subsequent iterations – among...... the reports. Fractal distinctions, such as between ‘behaviour’ or ‘system’ as a reform focus, allow us to locate the object of regulation within expert groups, the experts' professional context and the politics behind the commissioning of work. Analysing fractal distinctions provides a useful way...

  5. Distinctions, Affiliations, and Professional Knowledge in Financial Reform Commissions

    DEFF Research Database (Denmark)

    Seabrooke, Leonard; Tsingou, Eleni

    the different stresses in reports with and without clear mandates, and the role of important members of the policy community in promoting particular reform ideas. The article finds that differences in ideas emerging from the financial reform expert groups reflect nested power relationships in the commissioning......Who determines what ideas matter in reform debates? This article examines reform proposals from the expert groups that emerged during the recent international financial crisis. To do so it follows fractal distinctions - distinctions that replicate themselves in subsequent iterations – among...... the reports. Fractal distinctions, such as between ‘behavior’ or ‘system’ as a reform focus, allow us to locate the object of regulation within expert groups, experts’ professional context, and the politics behind the commissioning of work. Analyzing fractal distinctions provides a useful way to understand...

  6. Distinctions, Affiliations, and Professional Knowledge in Financial Reform Commissions

    DEFF Research Database (Denmark)

    Seabrooke, Leonard; Tsingou, Eleni

    the reports. Fractal distinctions, such as between ‘behavior’ or ‘system’ as a reform focus, allow us to locate the object of regulation within expert groups, experts’ professional context, and the politics behind the commissioning of work. Analyzing fractal distinctions provides a useful way to understand...... the different stresses in reports with and without clear mandates, and the role of important members of the policy community in promoting particular reform ideas. The article finds that differences in ideas emerging from the financial reform expert groups reflect nested power relationships in the commissioning......Who determines what ideas matter in reform debates? This article examines reform proposals from the expert groups that emerged during the recent international financial crisis. To do so it follows fractal distinctions - distinctions that replicate themselves in subsequent iterations – among...

  7. Thermochemical investigation of molten fluoride salts for Generation IV nuclear applications - an equilibrium exercise

    NARCIS (Netherlands)

    van der Meer, J.P.M.

    2006-01-01

    The concept of the Molten Salt Reactor, one of the so-called Generation IV future reactors, is that the fuel, a fissile material, which is dissolved in a molten fluoride salt, circulates through a closed circuit. The heat of fission is transferred to a second molten salt coolant loop, the heat of

  8. Adaptability of competitive electricity reforms a modular analysis

    Energy Technology Data Exchange (ETDEWEB)

    Dubois, Ute [ADIS-GRJM, Universite de Paris Sud 11, Campus de Fontenay, Batiment C, 27 avenue Lombart, F-92260 Fontenay aux Roses (France)], E-mail: ute.dubois@u-psud.fr

    2009-04-15

    Among the competitive electricity reforms that have been implemented in Europe and the US for the last 18 years, none has 'survived' over several years without major changes. Their changing nature raises the question of their adaptability. Two characteristics of reforms play a key role on their adaptation properties. Firstly, they are 'modular' objects in the sense of [Baldwin, C., 2008. Where do transactions come from? Modularity, transactions, and the boundaries of firms. Industrial and Corporate Change 17 (1), 155-195]. Secondly, they are produced in an institutional process which leads to 'incomplete' rules and designs [Pistor, K., Xu, C., 2003. Incomplete law. International Law and Politics 35, 931-1013]. We propose a typology of adaptations based on the framework proposed by [Williamson, O.E., 1991. Comparative economic organization: the analysis of discrete structural alternatives. Administrative Science Quarterly 36 (2), 269-296] for contracts: (1) in case of small disturbances, adaptations are realized quasi-automatically, by autonomous decisions of the institutions governing the implementation of reforms; (2) in case of middle-range disturbances, adaption is made by Coasian bargaining; (3) finally, in case of strong disturbances, or when bargaining is not feasible, the adaptation of reforms is in the hands of legislative and executive institutions [North, D.C., 2005. Le processus du developpement economique. Editions d'Organisation]. These institutions can reform the reforms [Joskow, P.L., 2006. Introduction to electricity sector liberalization: lessons learned from cross-country studies. In: Sioshansi, F.P. (Ed.), Electricity Market Reform: An International Perspective. Elsevier, Amsterdam, pp. 1-32; Hogan, W.W., 2002. Electricity market restructuring: reforms of reforms. Journal of Regulatory Economics 21, 103-132]. The role of these types of adaptations in each electricity reform is a consequence of the allocation of

  9. Adaptability of competitive electricity reforms. A modular analysis

    Energy Technology Data Exchange (ETDEWEB)

    Dubois, Ute [ADIS-GRJM, Universite de Paris Sud 11, Campus de Fontenay, Batiment C, 27 avenue Lombart, F-92260 Fontenay aux Roses (France)

    2009-04-15

    Among the competitive electricity reforms that have been implemented in Europe and the US for the last 18 years, none has 'survived' over several years without major changes. Their changing nature raises the question of their adaptability. Two characteristics of reforms play a key role on their adaptation properties. Firstly, they are 'modular' objects in the sense of [Baldwin, C., 2008. Where do transactions come from? Modularity, transactions, and the boundaries of firms. Industrial and Corporate Change 17 (1), 155-195]. Secondly, they are produced in an institutional process which leads to 'incomplete' rules and designs [Pistor, K., Xu, C., 2003. Incomplete law. International Law and Politics 35, 931-1013]. We propose a typology of adaptations based on the framework proposed by [Williamson, O.E., 1991. Comparative economic organization: the analysis of discrete structural alternatives. Administrative Science Quarterly 36 (2), 269-296] for contracts: (1) in case of small disturbances, adaptations are realized quasi-automatically, by autonomous decisions of the institutions governing the implementation of reforms; (2) in case of middle-range disturbances, adaption is made by Coasian bargaining; (3) finally, in case of strong disturbances, or when bargaining is not feasible, the adaptation of reforms is in the hands of legislative and executive institutions [North, D.C., 2005. Le processus du developpement economique. Editions d'Organisation]. These institutions can reform the reforms [Joskow, P.L., 2006. Introduction to electricity sector liberalization: lessons learned from cross-country studies. In: Sioshansi, F.P. (Ed.), Electricity Market Reform: An International Perspective. Elsevier, Amsterdam, pp. 1-32; Hogan, W.W., 2002. Electricity market restructuring: reforms of reforms. Journal of Regulatory Economics 21, 103-132]. The role of these types of adaptations in each electricity reform is a consequence of the allocation of

  10. Adaptability of competitive electricity reforms a modular analysis

    International Nuclear Information System (INIS)

    Dubois, Ute

    2009-01-01

    Among the competitive electricity reforms that have been implemented in Europe and the US for the last 18 years, none has 'survived' over several years without major changes. Their changing nature raises the question of their adaptability. Two characteristics of reforms play a key role on their adaptation properties. Firstly, they are 'modular' objects in the sense of [Baldwin, C., 2008. Where do transactions come from? Modularity, transactions, and the boundaries of firms. Industrial and Corporate Change 17 (1), 155-195]. Secondly, they are produced in an institutional process which leads to 'incomplete' rules and designs [Pistor, K., Xu, C., 2003. Incomplete law. International Law and Politics 35, 931-1013]. We propose a typology of adaptations based on the framework proposed by [Williamson, O.E., 1991. Comparative economic organization: the analysis of discrete structural alternatives. Administrative Science Quarterly 36 (2), 269-296] for contracts: (1) in case of small disturbances, adaptations are realized quasi-automatically, by autonomous decisions of the institutions governing the implementation of reforms; (2) in case of middle-range disturbances, adaption is made by Coasian bargaining; (3) finally, in case of strong disturbances, or when bargaining is not feasible, the adaptation of reforms is in the hands of legislative and executive institutions [North, D.C., 2005. Le processus du developpement economique. Editions d'Organisation]. These institutions can reform the reforms [Joskow, P.L., 2006. Introduction to electricity sector liberalization: lessons learned from cross-country studies. In: Sioshansi, F.P. (Ed.), Electricity Market Reform: An International Perspective. Elsevier, Amsterdam, pp. 1-32; Hogan, W.W., 2002. Electricity market restructuring: reforms of reforms. Journal of Regulatory Economics 21, 103-132]. The role of these types of adaptations in each electricity reform is a consequence of the allocation of rights to the regulator, to

  11. MOLTEN CARBONATE FUEL CELL PRODUCT DESIGN IMPROVEMENT

    Energy Technology Data Exchange (ETDEWEB)

    H.C. Maru; M. Farooque

    2003-03-01

    The program efforts are focused on technology and system optimization for cost reduction, commercial design development, and prototype system field trials. The program is designed to advance the carbonate fuel cell technology from full-size field test to the commercial design. FuelCell Energy, Inc. (FCE) is in the later stage of the multiyear program for development and verification of carbonate fuel cell based power plants supported by DOE/NETL with additional funding from DOD/DARPA and the FuelCell Energy team. FCE has scaled up the technology to full-size and developed DFC{reg_sign} stack and balance-of-plant (BOP) equipment technology to meet product requirements, and acquired high rate manufacturing capabilities to reduce cost. FCE has designed submegawatt (DFC300A) and megawatt (DFC1500 and DFC3000) class fuel cell products for commercialization of its DFC{reg_sign} technology. A significant progress was made during the reporting period. The reforming unit design was optimized using a three-dimensional stack simulation model. Thermal and flow uniformities of the oxidant-In flow in the stack module were improved using computational fluid dynamics based flow simulation model. The manufacturing capacity was increased. The submegawatt stack module overall cost was reduced by {approx}30% on a per kW basis. An integrated deoxidizer-prereformer design was tested successfully at submegawatt scale using fuels simulating digester gas, coal bed methane gas and peak shave (natural) gas.

  12. Rorty the Reformer?

    Directory of Open Access Journals (Sweden)

    Harvey Cormier

    2008-12-01

    Full Text Available Rorty should be read as a reformer, rather than a revolutionary transformer. While the reformer aims to improve what is already good, the revolutionary transformer seeks to dispense with the merely good in a quest for the absolutely best. For Rorty this choice was a bad choice. In order to make the case that Rorty was a reformer,we explicate Rorty’s views on truth. These views argue that we can obtain consensus about what is worth preserving and improving without reference to either rightness, truth, or objectivity. For after all, there is no way for philosophers to get outside the circle of language within which we debate about what we take to be authoritative and aceptable.

  13. [Bio-oil production from biomass pyrolysis in molten salt].

    Science.gov (United States)

    Ji, Dengxiang; Cai, Tengyue; Ai, Ning; Yu, Fengwen; Jiang, Hongtao; Ji, Jianbing

    2011-03-01

    In order to investigate the effects of pyrolysis conditions on bio-oil production from biomass in molten salt, experiments of biomass pyrolysis were carried out in a self-designed reactor in which the molten salt ZnCl2-KCl (with mole ratio 7/6) was selected as heat carrier, catalyst and dispersion agent. The effects of metal salt added into ZnCl2-KCl and biomass material on biomass pyrolysis were discussed, and the main compositions of bio-oil were determined by GC-MS. Metal salt added into molten salt could affect pyrolysis production yields remarkably. Lanthanon salt could enhance bio-oil yield and decrease water content in bio-oil, when mole fraction of 5.0% LaCl3 was added, bio-oil yield could reach up to 32.0%, and water content of bio-oil could reduce to 61.5%. The bio-oil and char yields were higher when rice straw was pyrolysed, while gas yield was higher when rice husk was used. Metal salts showed great selectivity on compositions of bio-oil. LiCl and FeCl2 promoted biomass to pyrolyse into smaller molecular weight compounds. CrCl3, CaCl2 and LaCl3 could restrain second pyrolysis of bio-oil. The research provided a scientific reference for production of bio-oil from biomass pyrolysis in molten salt.

  14. Treatment of plutonium process residues by molten salt oxidation

    International Nuclear Information System (INIS)

    Stimmel, J.; Wishau, R.; Ramsey, K.B.; Montoya, A.; Brock, J.; Heslop, M.

    1999-01-01

    Molten Salt Oxidation (MSO) is a thermal process that can remove more than 99.999% of the organic matrix from combustible 238 Pu material. Plutonium processing residues are injected into a molten salt bed with an excess of air. The salt (sodium carbonate) functions as a catalyst for the conversion of the organic material to carbon dioxide and water. Reactive species such as fluorine, chlorine, bromine, iodine, sulfur, phosphorous and arsenic in the organic waste react with the molten salt to form the corresponding neutralized salts, NaF, NaCl, NaBr, NaI, Na 2 SO 4 , Na 3 PO 4 and NaAsO 2 or Na 3 AsO4. Plutonium and other metals react with the molten salt and air to form metal salts or oxides. Saturated salt will be recycled and aqueous chemical separation will be used to recover the 238 Pu. The Los Alamos National Laboratory system, which is currently in the conceptual design stage, will be scaled down from current systems for use inside a glovebox

  15. Treatment of plutonium process residues by molten salt oxidation

    Energy Technology Data Exchange (ETDEWEB)

    Stimmel, J.; Wishau, R.; Ramsey, K.B.; Montoya, A.; Brock, J. [Los Alamos National Lab., NM (United States); Heslop, M. [Naval Surface Warfare Center (United States). Indian Head Div.; Wernly, K. [Molten Salt Oxidation Corp. (United States)

    1999-04-01

    Molten Salt Oxidation (MSO) is a thermal process that can remove more than 99.999% of the organic matrix from combustible {sup 238}Pu material. Plutonium processing residues are injected into a molten salt bed with an excess of air. The salt (sodium carbonate) functions as a catalyst for the conversion of the organic material to carbon dioxide and water. Reactive species such as fluorine, chlorine, bromine, iodine, sulfur, phosphorous and arsenic in the organic waste react with the molten salt to form the corresponding neutralized salts, NaF, NaCl, NaBr, NaI, Na{sub 2}SO{sub 4}, Na{sub 3}PO{sub 4} and NaAsO{sub 2} or Na{sub 3}AsO4. Plutonium and other metals react with the molten salt and air to form metal salts or oxides. Saturated salt will be recycled and aqueous chemical separation will be used to recover the {sup 238}Pu. The Los Alamos National Laboratory system, which is currently in the conceptual design stage, will be scaled down from current systems for use inside a glovebox.

  16. Conceptual design of Indian molten salt breeder reactor

    Indian Academy of Sciences (India)

    reactor was found to be stable and self-regulating. 4.2 Molten-salt reactor experiment (MSRE) [6]. As ARE had .... Continuous monitoring of the atmo- sphere was carried out by Health Physics Group of ... (4) Breeding ratio should be such that a self-sustaining operation of the reactor is achieved after accounting for losses in ...

  17. X-Ray Investigations on Molten Cu-Sb Alloys

    Science.gov (United States)

    Halm, Th.; Neumann, H.; Hoyer, W.

    1994-05-01

    Using X-ray diffraction, structure factors and pair correlation functions of several molten Cu-Sb alloys and pure antimony were determined and compared with published structural, thermodynamic and electronic properties. The eutectic concentration Cu37Sb63 was investigated in dependence on temperature, and a model structure factor was calculated applying a segregation model.

  18. Thermodynamic characterization of salt components for Molten Salt Reactor fuel

    NARCIS (Netherlands)

    Capelli, E.

    2016-01-01

    The Molten Salt Reactor (MSR) is a promising future nuclear fission reactor technology with excellent performance in terms of safety and reliability, sustainability, proliferation resistance and economics. For the design and safety assessment of this concept, it is extremely important to have a

  19. 30 CFR 56.16013 - Working with molten metal.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Working with molten metal. 56.16013 Section 56.16013 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL MINE SAFETY AND HEALTH SAFETY AND HEALTH STANDARDS-SURFACE METAL AND NONMETAL MINES Materials Storage...

  20. 30 CFR 57.16013 - Working with molten metal.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Working with molten metal. 57.16013 Section 57.16013 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL MINE SAFETY AND HEALTH SAFETY AND HEALTH STANDARDS-UNDERGROUND METAL AND NONMETAL MINES Materials...

  1. Metal halide reduction with molten sodium/potassium alloy

    International Nuclear Information System (INIS)

    Martin, W.

    1986-01-01

    A method of obtaining a desired metal, selected from the group consisting of titanium, aluminium, iron, manganese, hafnium, zirconium, tantalum, vanadium, uranium and tungsten, which comprises reacting a halide of the desired metal with an alkali metal reducing agent at temperature at which the reducing agent is molten, in order to produce the desired metal and halide of the metal reducing agent

  2. Nucleation of metals by redox processes in glass molten media

    International Nuclear Information System (INIS)

    Laurent, Y.; Turmel, J.M.; Verdier, P.

    1997-01-01

    Nitrogen incorporation into an aluminosilicate glass network changes greatly its physico-chemical properties. M-Si-Al-O-N (M = Li, Mg, Ca, Ln) oxynitride glasses are chemically inert. However, the presence of N 3- ions in molten glass gives to the glass medium a reducing character. This work concerns the study of redox reactions in molten glass between nitrogen and oxides of the first transition series of the periodic table, cadmium and lead. In situ precipitation of metallic particles from the corresponding oxides is demonstrated by X-ray diffraction and EDS data. However, the reduction of pure TiO 2 and V 2 O 5 gives rise to the corresponding nitrides, i.e. TiN and VN. The redox reaction occurs with nitrogen release. The low solubility of metals in the molten glass media forces metal migration out off the glass and consequently favors metal recovery. This oxidation-reduction process in molten media can be envisaged as industrially useful for recovering metals in industrial wastes. (authors)

  3. Nonmetal-metal transition in metal–molten-salt solutions

    NARCIS (Netherlands)

    Silvestrelli, P.-L.; Alavi, A.; Parrinello, M.; Frenkel, D.

    1996-01-01

    The method of ab initio molecular dynamics, based on finite-temperature density-functional theory, is used to study the nonmetal-metal transition in two different metal–molten-salt solutions, Kx(KCl)1-x and Nax(NaBr)1-x. As the excess metal concentration is increased the electronic density becomes

  4. Study of an F center in molten KCl

    Energy Technology Data Exchange (ETDEWEB)

    Parrinello, M.; Rahman, A.

    1983-05-01

    It is shown that a discretized version of Feynman's path integral provides a convenient tool for the numerical investigation of the properties of an electron solvated in molten KCl. The binding energy and the pair correlation functions are calculated. The local structure around the solute electron appears to be different from that of an F center in the solid.

  5. Fluid Mechanics Of Molten Metal Droplets In Additive Manufacturing

    Czech Academy of Sciences Publication Activity Database

    Tesař, Václav; Šonský, Jiří

    2016-01-01

    Roč. 4, č. 4 (2016), s. 403-412 ISSN 2046-0546 R&D Projects: GA ČR GA13-23046S Institutional support: RVO:61388998 Keywords : additive manufacturing * droplets * molten metal Subject RIV: BK - Fluid Dynamics http://www.witpress.com/elibrary/cmem-volumes/4/4/1545

  6. Ion diffusion related to structure in molten salts

    International Nuclear Information System (INIS)

    Tosi, M.P.

    1996-08-01

    A model first developed by Zwanzig to derive transport coefficients in cold dense fluids directly from the Green-Kubo time correlation formulae allows one to relate macroscopic diffusion coefficients to the local fluid structure. Applications to various ionic diffusion processes in molten salts are reviewed. Consequences of partial structural quenching are also discussed. (author). 28 refs, 3 tabs

  7. Research and development issues for molten carbonate fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Krumpelt, M.

    1996-04-01

    This paper describes issues pertaining to the development of molten carbonate fuel cells. In particular, the corrosion resistance and service life of nickel oxide cathodes is described. The resistivity of lithium oxide/iron oxides and improvement with doping is addressed.

  8. Electromagnetic Stirring of Molten Metal in Induction Crucible Furnace

    Czech Academy of Sciences Publication Activity Database

    Barglik, J.; Doležel, Ivo; Škopek, M.; Ulrych, B.

    2002-01-01

    Roč. 47, č. 3 (2002), s. 229-242 ISSN 0001-7043 R&D Projects: GA MŠk LN00B084; GA MŠk ME 542 Grant - others:PSC(PL) BK/RM3/405/01 Keywords : Electromagnetic stirring * molten metal * induction heating Subject RIV: JA - Electronics ; Optoelectronics, Electrical Engineering

  9. Release properties of UC sub x and molten U targets

    CERN Document Server

    Roussière, B; Sauvage, J; Bajeat, O; Barre, N; Clapier, F; Cottereau, E; Donzaud, C; Ducourtieux, M; Essabaa, S; Guillemaud-Müller, D; Lau, C; Lefort, H; Liang, C F; Le Blanc, F; Müller, A C; Obert, J; Pauwels, N; Potier, J C; Pougheon, F; Proust, J; Sorlin, O; Verney, D; Wojtasiewicz, A

    2002-01-01

    The release properties of UC sub x and molten U thick targets associated with a Nier-Bernas ion source have been studied. Two experimental methods are used to extract the release time. Results are presented and discussed for Kr, Cd, I and Xe.

  10. Electrode reaction mechanisms in molten carbonate fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Selman, J.R.; Nishina, T.; Lin, Y.P.; Yeager, E.B.; Tryk, D.A.

    1989-07-01

    This report describes the results of a joint research effort at Illinois Institute of Technology (IIT) and Case Western Reserve University (CWRU) to elucidate the reaction mechanism of oxygen reduction at the cathode of the molten carbonate fuel cell (MCFC). This research project was aimed at developing novel experimental approaches to the chemistry and electrode kinetics of oxygen reduction under MCFC conditions, and improving our fundamental understanding of the reaction mechanism as it applies to the MCFC. IIT's contribution was focused on developing and using rotating electrodes with well-defined mass-transfer properties, to characterize the electrode kinetics of oxygen reduction in molten carbonate. CWRU's contribution was focused on developing and using micro-electrodes for the same purpose, and also on developing spectroscopic cells and carrying out various types of spectroscopic measurements to characterize the oxygen species in molten carbonate under MCFC conditions. This report is divided into two main parts. Part 1 provides the technical background of the questions concerning oxygen reduction in molten carbonate as they apply to the MCFC system. The methodological approach and the objectives of the research are also presented. The second part describes the development of the rotating electrodes, micro-electrodes and spectroscopic cells and the results of measurements, as well as the interpretation of the data. Conclusions of this project, including some recommendations for further research, are also given in this part. 111 refs., 69 figs., 7 tabs.

  11. Iran, reform, revolution or resignation?; Iran: reforme, revolution ou resignation?

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2005-07-01

    This document is an information report made by the French commission of economic affairs after a visit of a delegation of members of the French parliament in Iran in April 15-18, 2003. The report describes: 1 - the international political situation of Iran; 2 - the domestic political situation of Iran: political institutions, yearn of change; 3 - the economic trades that would be possible to develop: economic and financial situation of Iran, fossil fuel resources, economic reforms to be implemented; 4 - the French-Iranian economical cooperation to be strengthened: French companies in Iran, towards a new era in bilateral economic relations, the challenge of the adhesion to the world trade organization (WTO). (J.S.)

  12. Management of reforming of housing-and-communal services

    Science.gov (United States)

    Skripnik, Oksana

    2017-10-01

    The international experience of reforming of housing and communal services is considered. The main scientific and methodical approaches of system transformation of the housing sphere are analyzed in the article. The main models of reforming are pointed out, interaction of participants of structural change process from the point of view of their commercial and social importance is characterized, advantages and shortcomings are revealed, model elements of the reform transformations from the point of view of the formation of investment appeal, competitiveness, energy efficiency and social importance of the carried-out actions are allocated.

  13. Measuring and Explaining regulatory Reform in the EU

    DEFF Research Database (Denmark)

    Citi, Manuele; Justesen, Mogens Kamp

    Over the last three decades, EU regulation of the internal market has become highly pervasive, affecting practically all the domains of European citizens’ lives. Many studies have focused on understanding the process and causes of regulatory reform. However, these have typically been small...... different sectors, and analyse the dynamics of regulatory reform in the EU. Using time series analysis of count data, we find evidence that the number of winning coalitions in the Council and the size of EU membership have a significant impact on regulatory reform in the EU. However, the political (left...

  14. A miniature fuel reformer system for portable power sources

    Science.gov (United States)

    Dolanc, Gregor; Belavič, Darko; Hrovat, Marko; Hočevar, Stanko; Pohar, Andrej; Petrovčič, Janko; Musizza, Bojan

    2014-12-01

    A miniature methanol reformer system has been designed and built to technology readiness level exceeding a laboratory prototype. It is intended to feed fuel cells with electric power up to 100 W and contains a complete setup of the technological elements: catalytic reforming and PROX reactors, a combustor, evaporators, actuation and sensing elements, and a control unit. The system is engineered not only for performance and quality of the reformate, but also for its lightweight and compact design, seamless integration of elements, low internal electric consumption, and safety. In the paper, the design of the system is presented by focussing on its miniaturisation, integration, and process control.

  15. Supplying Fe from molten coal ash to revive kelp community

    Energy Technology Data Exchange (ETDEWEB)

    Matsumoto, K.; Yamamoto, M.; Sadakata, M. [University of Tokyo, Tokyo (Japan)

    2006-02-15

    The phenomenon of a kelp-dominated community changing to a crust-dominated community, which is called 'barren-ground', is progressing in the world, and causing serious social problems in coastal areas. Among several suggested causes of 'barren-ground', we focused on the lack of Fe in seawater. Kelp needs more than 200 nM of Fe to keep its community. However there are the areas where the concentration of Fe is less than 1 nM, and the lack of Fe leads to the 'barren-ground.' Coal ash is one of the appropriate materials to compensate the lack of Fe for the kelp growth, because the coal ash is a waste from the coal combustion process and contains more than 5 wt% of Fe. The rate of Fe elution from coal fly ash to water can be increased by 20 times after melting in Ar atmosphere, because 39 wt% of the Fe(III) of coal fly ash was reduced to Fe(II). Additionally molten ash from the IGCC (integrated coal gasification combined cycle) furnace in a reducing atmosphere and one from a melting furnace pilot plant in an oxidizing atmosphere were examined. Each molten ash was classified into two groups; cooled rapidly with water and cooled slowly without water. The flux of Fe elution from rapidly cooled IGCC molten ash was the highest; 9.4 x 10{sup -6} g m{sup -2} d{sup -1}. It was noted that the coal ash melted in a reducing atmosphere could elute Fe effectively, and the dissolution of the molten ash itself controlled the rate of Fe elution in the case of rapidly cooled molten ash.

  16. Propagation mechanisms of molten fuel/moderator interactions

    International Nuclear Information System (INIS)

    Frost, D.L.; Ciccarelli, G.

    1991-06-01

    It is well known that a vapor explosion can result when molten is suddenly brought into contact with a cold volatile liquid such as water. However, the rapid melt fragmentation and heat transfer processes that occur during a propagating melt-water interaction are poorly understood. Experiments were carried out in the present work to investigate the fragmentation processes for single molten metal drops in water. To determine the time scale for the fragmentation of a drop, liquid metal drops (in thermal equilibrium with the water) as well as hot molten drops surrounded by a vapor film were subjected to underwater shocks with overpressures of up to about 20 MPa. In the hot molten drop tests, the induction time for the initiation of the explosion is typically less than 100 μs; at a corresponding time in the cold drop tests, very little or no direct hydrodynamic fragmentation of the drop has occurred. Therefore, in the hot drop case the fragmentation of the drop is dominated by thermal effects; i.e., the heat transfer from the melt to the water leads to violent boiling, pressurization, and drop fragmentation. The melt-water interaction consists of several cycles involving bubble growth and collapse. The strength of the interaction was not found to be a strong function of initial shock pressure (for molten tin drops with trigger pressures of up to 20 MPa), but depends on the thermal energy in the melt: high-temperature thermite drops generated a larger first bubble than lower temperature melt drops. A model for the fine fragmentation process for a hot drop is proposed that is based on thermal effects. The fragmentation processes governed by thermal effects observed in the present experiments are expected to play an important role in the escalation of a local interaction to a large-scale coherent vapor explosion, and are not accounted for in current transient models for propagating vapor explosions

  17. Abatement of tetrafluoromethane by chemical absorption with molten aluminum.

    Science.gov (United States)

    Shi, Zhongning; Cao, Dao; Tang, Wei; Hu, Xianwei; Wang, Zhaowen

    2017-12-15

    Chemical absorption with molten aluminum to abate tetrafluoromethane (CF 4 ) was investigated in this paper. The experiments were conducted at a series of different temperatures of 973 K, 1003 K, 1103 K, and 1188 K and the abatement rate of CF 4 was calculated. It was found that CF 4 can be adsorbed firstly and then react with molten aluminum automatically. The initial abatement rate of CF 4 in molten aluminum was 3.10 × 10 -2  mol·m -3 ·s -1 at 973 K, while it reached its maximum value of 1.08 × 10 -1  mol·m -3 ·s -1 at the temperature of 1103 K. The highest abatement efficiency was 48.4%, reached at 1003 K. Higher temperatures up to 1188 K did not affect the abatement efficiency, however, they accelerated slightly the initial reaction rate. The products of the chemical absorption are white solid AlF 3 and black graphite powder identified by XRD and SEM-EDS analysis. Due to density differences, solid AlF 3 and graphite powder in the product tend to accumulate on the top of molten aluminum where they form two separate layers. This makes them recover more easily. The gas-liquid reaction process between CF 4 and molten aluminum is accorded with the two-film theory model, diffusion process is considered to be the control step of the whole process. Copyright © 2017 Elsevier Ltd. All rights reserved.

  18. Molten salt oxidation of mixed waste: Preliminary bench-scale experiments without radioactivity

    International Nuclear Information System (INIS)

    Haas, P.A.; Rudolph, J.C.; Bell, J.T.

    1994-06-01

    Molten salt oxidation (MSO) is a process in which organic wastes are oxidized by sparging them with air through a bed of molten sodium carbonate (bp 851 degrees C) at ≥ 900 degrees C. This process is readily applicable to the mixed waste because acidic products from Cl, S, P, etc., in the waste, along with most metals and most radionuclides, are retained within the melt as oxides or salts. Rockwell International has studied the application of MSO to various wastes, including some mixed waste. A unit used by Rockwell to study the mixed waste treatment is presently in use at Oak Ridge National Laboratory (ORNL). ORNL's studies to date have concentrated on chemical flowsheet questions. Concerns that were studied included carbon monoxide (CO) emissions, NO x , emissions, and metal retention under a variety of conditions. Initial experiments show that CO emissions increase with increasing NaCl content in the melt, increasing temperature, and increasing airflow. Carbon monoxide content is especially high (> 2000 ppm) with high chlorine content (> 10%). Thermal NO x , emissions are relatively low ( x , The metal contents of the melt and of knockout pot samples of condensed salt show high volatilities of Cs as CsCl. Average condensed salt concentrations were 60% for barium and 100% for strontium and cobalt. The cerium disappeared -- perhaps from deposition on the alumina reactor walls

  19. Computational study of the mixed cooling effects on the in-vessel retention of a molten pool in a nuclear reactor

    International Nuclear Information System (INIS)

    Kim, Byung Seok; Sohn, Chang Hyun; Ahn, Kwang Il

    2004-01-01

    The retention of a molten pool vessel cooled by internal vessel reflooding and/or external vessel reactor cavity flooding has been considered as one of severe accident management strategies. The present numerical study investigates the effect of both internal and external vessel mixed cooling on an internally heated molten pool. The molten pool is confined in a hemispherical vessel with reference to the thermal behavior of the vessel wall. In this study, our numerical model used a scaled-down reactor vessel of a KSNP (Korea Standard Nuclear Power) reactor design of 1000 MWe (a pressurized water reactor with a large and dry containment). Well-known temperature-dependent boiling heat transfer curves are applied to the internal and external vessel cooling boundaries. Radiative heat transfer has been considered in the case of dry internal vessel boundary condition. Computational results show that the external cooling vessel boundary conditions have better effectiveness than internal vessel cooling in the retention of the melt pool vessel failure

  20. Numerical analysis of crust formation in molten core-concrete interaction using MPS method

    International Nuclear Information System (INIS)

    Seiichi, Koshizuka; Shoji, Matsuura; Mizue, Sekine; Yoshiaki, Oka

    2001-01-01

    A two-dimensional code is developed for molten core-concrete interaction (MCCI) based on Moving Particle Semi-implicit (MPS) method. Heat transfer is calculated without any specific correlations. A particle can be changed to a moving (fluid) or fixed (solid) particle corresponding to its enthalpy, which provide the phase change model for particles. The phase change model is verified by one-dimensional test calculations. Nucleate boiling and radiation heat transfers are considered between the core debris and the water pool. The developed code is applied to SWISS-2 experiment in which stainless steel is used as the melt material. Calculated heat flux to the water pool agrees well with the experiment, though the ablation speed in the concrete is a little slower. A stable crust is formed in a short time after water is poured in and the heat flux to the water pool rapidly decreases. MACE-M0 using corium is also analyzed. The ablation speed of concrete is slower than that of SWISS-2 because of low heat conduction in corium. An unlimited geometry is analyzed by setting the cyclic boundary condition on the sides. When the crust is broken by the decomposition gas, heat transfer to the water pool is kept high for a longer time because the crust re-formation is delayed. (author)

  1. Comprehensive Immigration Reform: Becoming Americans - U.S. Immigrant Integration

    OpenAIRE

    Rumbaut, RG

    2007-01-01

    Hearing on 'Comprehensive Immigration Reform: Becoming Americans - US Immigrant Integration,' Subcommittee on Immigration, Citizenship, Refugees, Border Security, and International Law of the Committee on the Judiciary, House of Representatives, Serial No. 110-27. May 16, 2007. Abstract: In this statement to a House Hearing on comprehensive immigration reform focusing on immigrant integration, English and foreign language competencies, preferences and use among immigrants and thei...

  2. Energy policies in the European Union. Germany's ecological tax reform

    International Nuclear Information System (INIS)

    Welfens, P.J.J.; Jungmittag, A.; Meyer, B.; Jasinski, P.

    2001-01-01

    The chapters discuss the following aspects: 1. Energy policy as a strategic element of economic policy in dynamic open economies. 2. Phasing out nuclear energy and core elements of sustainable energy strategy. 3. Ecological tax reform: Theory, modified double dividend and international aspects. 4. The policy framework in Europe and Germany. 5. Optimal ecological tax reform: Options and recommendations for an EU-action plan. 6. Conclusions. (orig./CB)

  3. Iran, reform, revolution or resignation?

    International Nuclear Information System (INIS)

    2005-01-01

    This document is an information report made by the French commission of economic affairs after a visit of a delegation of members of the French parliament in Iran in April 15-18, 2003. The report describes: 1 - the international political situation of Iran; 2 - the domestic political situation of Iran: political institutions, yearn of change; 3 - the economic trades that would be possible to develop: economic and financial situation of Iran, fossil fuel resources, economic reforms to be implemented; 4 - the French-Iranian economical cooperation to be strengthened: French companies in Iran, towards a new era in bilateral economic relations, the challenge of the adhesion to the world trade organization (WTO). (J.S.)

  4. Systemic Reform and Organizational Change

    Science.gov (United States)

    Fusarelli, Bonnie C.; Fusarelli, Lance D.

    2003-01-01

    In this article, the authors explore whether educational systems have the institutional capacity to implement comprehensive, systemic reform, as envisioned in legislation such as No Child Left Behind. Drawing upon evidence from various state-level reform initiatives, the authors highlight the ways in which systemic reform appears to positively…

  5. Reforming Technical and Technological Education.

    Science.gov (United States)

    Wilson, David N.

    1993-01-01

    Review of technical and technological educational reform in Brazil, Canada, Germany, Great Britain, Indonesia, Malaysia, Singapore, and Sweden shows that reform takes time to complete effectively, long-term approaches are needed, and reform is linked to industrial development, regional cooperation, and decentralized decision making. (SK)

  6. How to Reform Business Licenses

    OpenAIRE

    International Finance Corporation; World Bank

    2010-01-01

    Reforming business licenses is part of a suite of products delivered by the World Bank group's investment climate advisory services, under the business operations practice. The approach to reforms highlighted in this handbook fits into the broader policy framework for business licensing reform and simplification. The framework paper provides the context for business licensing practices; es...

  7. Transfer characteristics of a lithium chloride–potassium chloride molten salt

    Directory of Open Access Journals (Sweden)

    Eve Mullen

    2017-12-01

    Full Text Available Pyroprocessing is an alternative method of reprocessing spent fuel, usually involving the dissolving spent fuel in a molten salt media. The National Nuclear Laboratory designed, built, and commissioned a molten salt dynamics rig to investigate the transfer characteristics of molten lithium chloride–potassium chloride eutectic salt. The efficacy and flow characteristics of a high-temperature centrifugal pump and argon gas lift were obtained for pumping the molten salt at temperatures up to 500°C. The rig design proved suitable on an industrial scale and transfer methods appropriate for use in future molten salt systems. Corrosion within the rig was managed, and melting techniques were optimized to reduce stresses on the rig. The results obtained improve the understanding of molten salt transport dynamics, materials, and engineering design issues and support the industrialization of molten salts pyroprocessing.

  8. Educational Reform in Turkey

    Science.gov (United States)

    Lindquist, Cynthia

    2017-01-01

    As a country seeking admission to the European Union, this paper explores educational reforms in Turkey that enhance its possible entry into the European Union and changes still needed for it to be an equal partner. An overview of the school system in Turkey is provided including information on teacher training and preparation, special education…

  9. Sex and School Reform.

    Science.gov (United States)

    Cuban, Larry

    1986-01-01

    Predicts that reformers will not attack sex education as an inappropriate addition to otherwise rigorous academic programs. Examines (1) some of the political, social, and practical reasons behind this avoidance and (2) the ineffectiveness of existing programs in preventing teenage pregnancies. Suggests that sex education programs may even hinder…

  10. Reforming Water, Adding Women?

    International Development Research Centre (IDRC) Digital Library (Canada)

    Karen Kershaw

    Strong state-civil society collaboration: alternatives. • 1997: first sector reform project launched (Ghogha) ... management? • What role does civil society (NGOs, CBOs, networks, academia) play in this process? ... campaigns, folk media, street theatre, engage communities. • Technical training for women, socially excluded ...

  11. Comments on regulatory reform

    International Nuclear Information System (INIS)

    Hendrie, J.M.

    1982-01-01

    Nuclear regulatory reform is divided into two parts. The first part contains all those matters for which new legislation is required. The second part concerns all those matters that are within the power of the Commission under existing statutes. Recommendations are presented

  12. Reform: Learning from Japan.

    Science.gov (United States)

    Barnes, Michael

    1999-01-01

    Examining differences between education in the United States and in Japan means analyzing cultural dissimilarities. An overview of Japan's educational makeup, curriculum, and graduation rates provides background in comparing educational systems for future reforms. This paper examines Japanese school structures, government support, institutional…

  13. Drug pricing reform in China: analysis of piloted approaches and potential impact of the reform.

    Science.gov (United States)

    Chen, Yixi; Hu, Shanlian; Dong, Peng; Kornfeld, Åsa; Jaros, Patrycja; Yan, Jing; Ma, Fangfang; Toumi, Mondher

    2016-01-01

    In 2009, the Chinese government launched a national healthcare reform programme aiming to control healthcare expenditure and increase the quality of care. As part of this programme, a new drug pricing reform was initiated on 1 June 2015. The objective of this study was to describe the changing landscape of drug pricing policy in China and analyse the potential impact of the reform. The authors conducted thorough research on the drug pricing reform using three Chinese databases (CNKI, Wanfang, and Weipu), Chinese health authority websites, relevant press releases, and pharmaceutical blogs and discussion forums. This research was complemented with qualitative research based on targeted interviews with key Chinese opinion leaders representing the authorities' and prescribers' perspectives. With the current reform, the government has attempted to replace its direct control over the prices of reimbursable drugs with indirect, incentive-driven influence. Although the exact implementation of the reform remains unclear at the moment, the changes introduced so far and the pilot project designs indicate that China is considering adaptation of some form of internal and external reference pricing policies, commonly used in the Organisation for Economic Co-operation and Development countries. Several challenges related to the potential new mechanism were identified: 1) the risk of hospital underfunding, if hospital funding reform is not prioritised; 2) the risk of promoting the use of cheap, low-quality drugs, if a reliable quality control system is not in place and discrepancy between the available drugs is present; 3) the risk of increasing disparity in access to care between poor and rich regions, in case of country-wide price convergence; and 4) the risk of industry underinvestment, resulting in reduced competition, issues with quality and sustainability of supply, and potentially negative social impact. Foreign pricing policies cannot be transferred to China without

  14. ‘Covenanting for Justice’? On the Accra Document, Reformed Theology and Reformed Ecclesiology

    Directory of Open Access Journals (Sweden)

    Dirkie J. Smit

    2009-11-01

    Full Text Available The essay provides a brief summary of the main argument of the Accra Document drafted by the World Alliance of Reformed Churches and entitled ‘Covenanting for Justice in the Economy and the Earth’. The focus is on discovering and describing the internal structure, the logic and focus, and thereby some of the most important implicit and explicit theological and ecclesiological convictions, suppositions and claims of the document, as far as possible in its own terminology. It then offers a tentative theological assessment, pointing out four very typical Reformed characteristics of the document, including its typical confessional nature and style. It finally suggests some ecclesiological implications arising from the document, again calling to mind four very specific characteristics of Reformed ecclesiology. On the whole, the essay serves as an invitation to further study, discussion and refl ection on the challenges and calling implied in the document.

  15. 26 CFR 1.170-3 - Contributions or gifts by corporations (before amendment by Tax Reform Act of 1969).

    Science.gov (United States)

    2010-04-01

    ... Tax Reform Act of 1969). (a) In general. The deduction by a corporation in any taxable year for... 26 Internal Revenue 3 2010-04-01 2010-04-01 false Contributions or gifts by corporations (before amendment by Tax Reform Act of 1969). 1.170-3 Section 1.170-3 Internal Revenue INTERNAL REVENUE SERVICE...

  16. Fossil fuel subsidy reform: lessons from the Indonesian case

    International Nuclear Information System (INIS)

    Savatic, Filip

    2016-10-01

    Global assessments of consumption and the Indonesian case show the relevance of non-household consumers of subsidized energy products. As shown in this study, understanding in more nuance how reforms affect them has the potential to improve the reforms that will be developed by policy-makers worldwide. Further study can reinforce the many benefits of successful reform for the countries and societies slowly turning away from these policies of the past. Estimates regarding the amount of public funds utilized to subsidize the production or consumption of fossil fuels are staggering. For 2011, they range from $83 billion in OECD member states, to nearly $4.1 trillion worldwide if environmental externalities are considered. Numerous studies have demonstrated that subsidies repress economic growth, undermine energy sector investment, increase public debt, benefit wealthy citizens over the poor, instigate a rise in illicit activities, and engender greater global and local pollution. The negative effects of fossil fuel subsidies have led numerous governments to reform their energy policies. There has also been a growing international consensus in favor of reform. While the components of successful reform programs have been identified through past case studies, the nature of reforms adopted by several governments that target non-households have not been systematically examined. Since the late 1990s, the Indonesian government has implemented numerous reforms of its fossil fuel subsidies, including measures targeting household as well as non-household energy consumption. In doing so, it has incurred significant fiscal savings. However, an innovative budgetary analysis reveals that households receive a minority, and a declining share, of fossil fuel subsidy funds. This is the case despite the fact that subsidies were implemented to ensure poor households have access to cheap energy. These findings demonstrate the need to consider non-household sectors in the design of fossil

  17. Pending reforms: challenges to governabilty in Brazil

    Directory of Open Access Journals (Sweden)

    Sonia Fleury

    2012-04-01

    Full Text Available After President Lula’s two terms of office, the election of Dilma Rousseff generated all kinds of different expectations, whether because of the candidate’s lack of a political career within the Workers’ Party (PT, or because of her rather uncharismatic personality and poor propensity towards political negotiations with the allied parties that favoured the governability of the previous term of office. The country she has inherited is in a much better situation than the one inherited by the first PT government, with a stabilised economy and inflation under control. The sustainable policies for reducing poverty have generated conditions that encourage the enlargement of the middle class which, together with the creation of popular credit mechanisms, have served to halt the effects of the world crisis and have generated enormous expectations of social mobility. This scenario, together with the country’s increasingly recognised presence as an important international actor, provides unprecedented possibilities for the advancement of the “development with social inclusion” project. Nevertheless, certain reforms still need to be implemented that could threaten governability: political reform, federative agreement and tax reform, as well as social reforms.

  18. International

    International Nuclear Information System (INIS)

    Anon.

    1997-01-01

    This rubric reports on 10 short notes about international economical facts about nuclear power: Electricite de France (EdF) and its assistance and management contracts with Eastern Europe countries (Poland, Hungary, Bulgaria); Transnuclear Inc. company (a 100% Cogema daughter company) acquired the US Vectra Technologies company; the construction of the Khumo nuclear power plant in Northern Korea plays in favour of the reconciliation between Northern and Southern Korea; the delivery of two VVER 1000 Russian reactors to China; the enforcement of the cooperation agreement between Euratom and Argentina; Japan requested for the financing of a Russian fast breeder reactor; Russia has planned to sell a floating barge-type nuclear power plant to Indonesia; the control of the Swedish reactor vessels of Sydkraft AB company committed to Tractebel (Belgium); the renewal of the nuclear cooperation agreement between Swiss and USA; the call for bids from the Turkish TEAS electric power company for the building of the Akkuyu nuclear power plant answered by three candidates: Atomic Energy of Canada Limited (AECL), Westinghouse (US) and the French-German NPI company. (J.S.)

  19. Plasma devices for hydrocarbon reformation

    KAUST Repository

    Cha, Min Suk

    2017-02-16

    Plasma devices for hydrocarbon reformation are provided. Methods of using the devices for hydrocarbon reformation are also provided. The devices can include a liquid container to receive a hydrocarbon source, and a plasma torch configured to be submerged in the liquid. The plasma plume from the plasma torch can cause reformation of the hydrocarbon. The device can use a variety of plasma torches that can be arranged in a variety of positions in the liquid container. The devices can be used for the reformation of gaseous hydrocarbons and/or liquid hydrocarbons. The reformation can produce methane, lower hydrocarbons, higher hydrocarbons, hydrogen gas, water, carbon dioxide, carbon monoxide, or a combination thereof.

  20. Validation of the TRACE code for the system dynamic simulations of the molten salt reactor experiment and the preliminary study on the dual fluid molten salt reactor

    Energy Technology Data Exchange (ETDEWEB)

    He, Xun

    2016-06-14

    Molten Salt Reactor (MSR), which was confirmed as one of the six Generation IV reactor types by the GIF (Generation IV International Forum in 2008), recently draws a lot of attention all around the world. Due to the application of liquid fuels the MSR can be regarded as the most special one among those six GEN-IV reactor types in a sense. A unique advantage of using liquid nuclear fuel lies in that the core melting accident can be thoroughly eliminated. Besides, a molten salt reactor can have several fuel options, for instance, the fuel can be based on {sup 235}U, {sup 232}Th-{sup 233}U, {sup 238}U-{sup 239}Pu cycle or even the spent nuclear fuel (SNF), so the reactor can be operated as a breeder or as an actinides burner both with fast, thermal or epi-thermal neutron spectrum and hence, it has excellent features of the fuel sustainability and for the non-proliferation. Furthermore, the lower operating pressure not only means a lower risk of the explosion as well as the radioactive leakage but also implies that the reactor vessel and its components can be lightweight, thus lowering the cost of equipments. So far there is no commercial MSR being operated. However, the MSR concept and its technical validation dates back to the 1960s to 1970s, when the scientists and engineers from ORNL (Oak Ridge National Laboratory) in the United States managed to build and run the world's first civilian molten salt reactor called MSRE (Molten Salt Reactor Experiment). The MSRE was an experimental liquid-fueled reactor with 10 MW thermal output using {sup 4}LiF-BeF{sub 2}-ZrF{sub 4}-UF{sub 4} as the fuel also as the coolant itself. The MSRE is usually taken as a very important reference case for many current researches to validate their codes and simulations. Without exception it works also as a benchmark for this thesis. The current thesis actually consists of two main parts. The first part is about the validation of the current code for the old MSRE concept, while the second

  1. Molecular dynamic simulation study of molten cesium

    Directory of Open Access Journals (Sweden)

    Yeganegi Saeid

    2017-01-01

    Full Text Available Molecular dynamics simulations were performed to study thermodynamics and structural properties of expanded caesium fluid. Internal pressure, radial distribution functions (RDFs, coordination numbers and diffusion coefficients have been calculated at temperature range 700–1600 K and pressure range 100–800 bar. We used the internal pressure to predict the metal–non-metal transition occurrence region. RDFs were calculated at wide ranges of temperature and pressure. The coordination numbers decrease and positions of the first peak of RDFs slightly increase as the temperature increases and pressure decreases. The calculated self-diffusion coefficients at various temperatures and pressures show no distinct boundary between Cs metallic fluid and its expanded fluid where it continuously increases with temperature.

  2. Dataset: A Transnational Network of Social Reform in the Nineteenth Century: Visitors to Social Reform Congresses 1840-1880

    NARCIS (Netherlands)

    Leonards, C.G.T.M.; Randeraad, N.

    2009-01-01

    Using international congresses as nodes, scientists and philanthropists expanded an expert network in social reform from the 1850s onward. The project explores both the impact of international expertise on the national and local level of governance and vice-versa. The database contains records on

  3. Methane steam reforming kinetics over Ni-YSZ anodematerials for Solid Oxide FuelCells

    DEFF Research Database (Denmark)

    Mogensen, David

    of internal reforming has to be carefully controlled. The objective of this thesis is to make such a careful control possible by examining the rate of internal steam reforming in SOFCs. The catalytic steam reforming activity of Ni-YSZ anode material was tested both in a packed bed reactor to determine...... energy. The overall efficiency of a fuel cell system operating on natural gas can be significantly improved by having part of the steam reforming take place inside the SOFC stack. In order to avoid large temperature gradients as a result of the highly endothermal steam reforming reaction, the amount...... accurately predict the steam reforming rate in a stack from the rate expression obtained from the packed bed experiments. During the experiments a previously unreported long term dynamic behavior of the catalyst was observed. After startup, the initial high reactivity was slowly reduced by a factor 5-10 over...

  4. Methane steam reforming kinetics over Ni-YSZ anode materials for Solid Oxide Fuel Cells

    DEFF Research Database (Denmark)

    Mogensen, David

    of internal reforming has to be carefully controlled. The objective of this thesis is to make such a careful control possible by examining the rate of internal steam reforming in SOFCs. The catalytic steam reforming activity of Ni-YSZ anode material was tested both in a packed bed reactor to determine...... energy. The overall efficiency of a fuel cell system operating on natural gas can be significantly improved by having part of the steam reforming take place inside the SOFC stack. In order to avoid large temperature gradients as a result of the highly endothermal steam reforming reaction, the amount...... accurately predict the steam reforming rate in a stack from the rate expression obtained from the packed bed experiments. During the experiments a previously unreported long term dynamic behavior of the catalyst was observed. After startup, the initial high reactivity was slowly reduced by a factor 5-10 over...

  5. A numerical analysis of molten metal drop and coolant interaction

    International Nuclear Information System (INIS)

    Cao, X.; Hajima, Ryoichi; Furuta, Kazuo; Kondo, Shunsuke

    2000-01-01

    The interaction of molten metal drop and coolant is numerically analyzed to investigate the mechanism of fragmentation in vapor explosion. The numerical study is carried out by using a developed simulation code based on multi-phase thermal hydraulic model, which includes physical phenomena required for the analysis: heat transfer, mass change, liquid evaporation and treatment of surface. Several computational techniques are also implemented to improve the efficiency and stability of the numerical scheme. The obtained numerical results show that the growth of spikes on the molten metal drop surface is similar to that observed in Ciccarelli's experiment. The numerical study suggests that quick growth of spikes is the essential mechanism of fragmentation, which is caused by Taylor instability. (author)

  6. A facile molten-salt route to graphene synthesis.

    Science.gov (United States)

    Liu, Xiaofeng; Giordano, Cristina; Antonietti, Markus

    2014-01-15

    Efficient synthetic routes are continuously pursued for graphene in order to implement its applications in different areas. However, direct conversion of simple monomers to graphene through polymerization in a scalable manner remains a major challenge for chemists. Herein, a molten-salt (MS) route for the synthesis of carbon nanostructures and graphene by controlled carbonization of glucose in molten metal chloride is reported. In this process, carbohydrate undergoes polymerization in the presence of strongly interacting ionic species, which leads to nanoporous carbon with amorphous nature and adjustable pore size. At a low precursor concentration, the process converts the sugar molecules (glucose) to rather pure few-layer graphenes. The MS-derived graphenes are strongly hydrophobic and exhibit remarkable selectivity and capacity for absorption of organics. The methodology described may open up a new avenue towards the synthesis and manipulation of carbon materials in liquid media. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  7. Uranium (III) precipitation in molten chloride by wet argon sparging

    Science.gov (United States)

    Vigier, Jean-François; Laplace, Annabelle; Renard, Catherine; Miguirditchian, Manuel; Abraham, Francis

    2016-06-01

    In the context of pyrochemical processes for nuclear fuel treatment, the precipitation of uranium (III) in molten salt LiCl-CaCl2 (30-70 mol%) at 705 °C is studied. First, this molten chloride is characterized with the determination of the water dissociation constant. With a value of 10-4.0, the salt has oxoacid properties. Then, the uranium (III) precipitation using wet argon sparging is studied. The salt is prepared using UCl3 precursor. At the end of the precipitation, the salt is totally free of solubilized uranium. The main part is converted into UO2 powder but some uranium is lost during the process due to the volatility of uranium chloride. The main impurity of the resulting powder is calcium. The consequences of oxidative and reductive conditions on precipitation are studied. Finally, coprecipitation of uranium (III) and neodymium (III) is studied, showing a higher sensitivity of uranium (III) than neodymium (III) to precipitation.

  8. Using physical properties of molten glass to estimate glass composition

    International Nuclear Information System (INIS)

    Choi, Kwan Sik; Yang, Kyoung Hwa; Park, Jong Kil

    1997-01-01

    A vitrification process is under development in KEPRI for the treatment of low-and medium-level radioactive waste. Although the project is for developing and building Vitrification Pilot Plant in Korea, one of KEPRI's concerns is the quality control of the vitrified glass. This paper discusses a methodology for the estimation of glass composition by on-line measurement of molten glass properties, which could be applied to the plant for real-time quality control of the glass product. By remotely measuring viscosity and density of the molten glass, the glass characteristics such as composition can be estimated and eventually controlled. For this purpose, using the database of glass composition vs. physical properties in isothermal three-component system of SiO 2 -Na 2 O-B 2 O 3 , a software TERNARY has been developed which determines the glass composition by using two known physical properties (e.g. density and viscosity)

  9. Cracking of crude oil in the molten metals

    Directory of Open Access Journals (Sweden)

    Marat A. Glikin

    2014-03-01

    Full Text Available In this paper is investigated the process of crude oil and its individual fractions cracking in the molten metals medium to produce light petroleum products. Thermodynamic calculations demonstrate the possibility of using lead and tin including alloys thereof as the melt. The cracking of West Siberian crude oil is studied at temperatures 400-600 °C. It is detected that as the temperature increases there is increase of aromatic hydrocarbons and olefins content in gasoline while naphthenes, n- and i-paraffins content reduces. Optimal temperature for cracking in molten metals is ~500 °C. The use of a submerged nozzle increases the yield of light petroleum products by ~2%. The research octane number of gasoline produced is 82-87 points. It is determined that the yield of light petroleum products depending on the experimental conditions is increased from 46.9 to 55.1-61.3% wt.   

  10. Burning molten metallic spheres: One class of ball lightning?

    Science.gov (United States)

    Stephan, Karl D.; Massey, Nathan

    2008-08-01

    Abrahamson and Dinniss [2000. Ball lightning caused by oxidation of nanoparticle networks from normal lightning strikes on soil. Nature 403, 519-521] proposed a theory of ball lighting in which silicon nanoparticles undergo slow oxidation and emit light. Paiva et al. [2007. Production of ball-lightning-like luminous balls by electrical discharges in silicon. Physical Review Letters 98, 048501] reported that an electric arc to silicon produced long-lasting luminous white spheres showing many characteristics of ball lightning. We show experimentally that these consist of burning molten silicon spheres with diameters in the 0.1-1 mm range. The evidence of our experiments leads us to propose that a subset of ball lightning events may consist of macro-scale molten spheres of burning metallic materials likely to be ejected from a conventional lightning strike to earth.

  11. Wettability of TiAlN films by molten aluminum

    Energy Technology Data Exchange (ETDEWEB)

    Shen Ping [Joining and Welding Research Institute, Osaka University, 11-1 Mihogaoka Ibaraki, Osaka, 567-0047 (Japan) and Key Laboratory of Automobile Materials, Department of Materials Science and Engineering, Jilin University, No. 5988 Renmin Street, Changchun, 130025 (China)]. E-mail: shenping@jlu.edu.cn; Nose, Masateru [Department of Industrial Art and Craft, Takaoka National College, 180 Futagami-machi, Takaoka City, Toyama 933-8588 (Japan); Fujii, Hidetoshi [Joining and Welding Research Institute, Osaka University, 11-1 Mihogaoka Ibaraki, Osaka, 567-0047 (Japan); Nogi, Kiyoshi [Joining and Welding Research Institute, Osaka University, 11-1 Mihogaoka Ibaraki, Osaka, 567-0047 (Japan)

    2006-12-05

    In this study, we made an attempt to measure the wettability of the TiAlN films by molten Al at temperatures between 1073 K and 1273 K using an improved sessile drop method. The true contact angles cannot be obtained for the films deposited on the stainless steel and tungsten substrates due to considerable interdiffusion or reaction between molten Al and the substrate constituents. For the films deposited on the stable alumina single crystals and in contact with clean Al, the true contact angles are possible in the range of 80-100 deg. at 1173-1273 K and the work of adhesion is 0.77-1.08 J m{sup -2}. In the case of oxidized Al, typically at T < 1173 K, however, the wettability and the adhesion are significantly decreased.

  12. Structure Formation Mechanisms during Solid Ti with Molten Al Interaction

    International Nuclear Information System (INIS)

    Gurevich, L; Pronichev, D; Trunov, M

    2016-01-01

    The study discuses advantages and disadvantages of previously proposed mechanisms of the formation of structure between solid Ti and molten Al and presents a new mechanism based on the reviewed and experimental data. The previously proposed mechanisms were classified into three groups: mechanisms of precipitation, mechanisms of destruction and mechanisms of chemical interaction between intermetallics and melt. The reviewed mechanisms did not explain the formation of heterogeneous interlayer with globular aluminide particles and thin layers of pure Al, while the present study reveals variation in the solid Ti/molten Al reaction kinetics during various phases of laminated metal-intermetallic composite formation. The proposed mechanism considers formed during composite fabrication thin oxide interlayers between Ti and Al evolution and its impact on the intermetallic compound formation and explains the initial slow rate of intermetallic interlayer formation and its subsequent acceleration when the oxide foils are ruptured. (paper)

  13. Electrodeposition of alloys or compounds in molten salts and applications

    Directory of Open Access Journals (Sweden)

    Taxil P.

    2003-01-01

    Full Text Available This article deals with the different modes of preparation of alloys or intermetallic compounds using the electrodeposition in molten salts, more particularly molten alkali fluorides. The interest in this process is to obtain new materials for high technology, particularly the compounds of reactive components such as actinides, rare earth and refractory metals. Two ways of preparation are considered: (i electrocoating of the more reactive metal on a cathode made of the noble one and reaction between the two metals in contact, and (ii electrocoating on an inert cathode of the intermetallic compound by coreduction of the ions of each elements. The kinetic is controlled by the reaction at the electrolyte interface. A wide bibliographic survey on the preparation of various compounds (intermetallic compounds, borides, carbides… is given and a special attention is paid to the own experience of the authors in the preparation of these compounds and interpretation of their results.

  14. Molten salt treatment to minimize and optimize waste

    International Nuclear Information System (INIS)

    Gat, U.; Crosley, S.M.; Gay, R.L.

    1993-01-01

    A combination molten salt oxidizer (MSO) and molten salt reactor (MSR) is described for treatment of waste. The MSO is proposed for contained oxidization of organic hazardous waste, for reduction of mass and volume of dilute waste by evaporation of the water. The NTSO residue is to be treated to optimize the waste in terms of its composition, chemical form, mixture, concentration, encapsulation, shape, size, and configuration. Accumulations and storage are minimized, shipments are sized for low risk. Actinides, fissile material, and long-lived isotopes are separated and completely burned or transmuted in an MSR. The MSR requires no fuel element fabrication, accepts the materials as salts in arbitrarily small quantities enhancing safety, security, and overall acceptability

  15. Electromagnetic valve for controlling the flow of molten, magnetic material

    Science.gov (United States)

    Richter, Tomas

    1998-01-01

    An electromagnetic valve for controlling the flow of molten, magnetic material is provided, which comprises an induction coil for generating a magnetic field in response to an applied alternating electrical current, a housing, and a refractory composite nozzle. The nozzle is comprised of an inner sleeve composed of an erosion resistant refractory material (e.g., a zirconia ceramic) through which molten, magnetic metal flows, a refractory outer shell, and an intermediate compressible refractory material, e.g., unset, high alumina, thermosetting mortar. The compressible refractory material is sandwiched between the inner sleeve and outer shell, and absorbs differential expansion stresses that develop within the nozzle due to extreme thermal gradients. The sandwiched layer of compressible refractory material prevents destructive cracks from developing in the refractory outer shell.

  16. Steam explosion studies with single drops of molten refractory materials

    International Nuclear Information System (INIS)

    Nelson, L.S.

    1980-01-01

    Laser heating, levitation melting, and metal combustion were used to prepare individual drops of molten refractory materials which simulate LWR fuel melt products. Drop temperatures ranged from approx. = 1500 to > 3000K. These drops, several millimeters in diameter, were injected into water and subjected to pressure transients (approx. = 1MPa peak pressures) generated by a submerged exploding bridgewire. Molten oxides of Fe, Al and Zr could be induced to explode with bridgewire initiation. High speed films showed the explosions with exceptional clarity, and pressure transducer records could be correlated with individual frames in the films. Pressure spikes one or two MPa high were generated whenever an explosion occurred. Debris particles were mostly spheroidal, with diameters in the range 10 to 1000 μm

  17. Polyethylene encapsulation of molten salt oxidation mixed low-level radioactive salt residues

    International Nuclear Information System (INIS)

    Lageraaen, P.R.; Kalb, P.D.; Grimmett, D.L.; Gay, R.L.; Newman, C.D.

    1995-01-01

    A limited scope treatability study was conducted for polyethylene encapsulation of salt residues generated by a Molten Salt Oxidation (MSO) technology demonstration at the Energy Technology Engineering Center (ETEC), operated by Rockwell International for the US Department of Energy (DOE). During 1992 and 1993, ETEC performed a demonstration with a prototype MSO unit and treated approximately 50 gallons of mixed waste comprised of radioactively contaminated oils produced by hot cell operations. A sample of the mixed waste contaminated spent salt was used during the BNL polyethylene encapsulation treatability study. A nominal waste loading of 50 wt % was successfully processed and waste form test specimens were made for Toxicity Characteristic Leaching Procedure (TCLP) testing. The encapsulated product was compared with base-line TCLP results for total chromium and was found to be well within allowable EPA guidelines

  18. MYRRHA ADS DATABASE: Part I. Thermophysical properties of molten lead-bismuth eutectic. Version 1

    International Nuclear Information System (INIS)

    Sobolev, V.

    2005-11-01

    This report is an update of the internal SCK-CEN report IR-18 'Database of thermal properties for the melted lead-bismuth eutectic' issued in 2002. This compilation takes into account larger amount of original sources and, partially, the work performed in the framework of the preparation of a 'zero' version of the HLMC Handbook by the OECD/NEA Working Group on LBE Technology. An analysis is performed of the previous recommendations using some general physical laws and referencing to the properties of lead and bismuth. The updated and extended version of the molten LBE thermal properties database is developed and the correlations are proposed for the design calculations of ADS MYRRHA. (author)

  19. Decommissioning the Los Alamos Molten Plutonium Reactor Experiment (LAMPRE I)

    International Nuclear Information System (INIS)

    Harper, J.R.; Garde, R.

    1981-11-01

    The Los Alamos Molten Plutonium Reactor Experiment (LAMPRE I) was decommissioned at the Los Alamos National Laboratory, Los Alamos, New Mexico, in 1980. The LAMPRE I was a sodium-cooled reactor built to develop plutonium fuels for fast breeder applications. It was retired in the mid-1960s. This report describes the decommissioning procedures, the health physics programs, the waste management, and the costs for the operation

  20. Fission product ion exchange between zeolite and a molten salt

    Science.gov (United States)

    Gougar, Mary Lou D.

    The electrometallurgical treatment of spent nuclear fuel (SNF) has been developed at Argonne National Laboratory (ANL) and has been demonstrated through processing the sodium-bonded SNF from the Experimental Breeder Reactor-II in Idaho. In this process, components of the SNF, including U and species more chemically active than U, are oxidized into a bath of lithium-potassium chloride (LiCl-KCl) eutectic molten salt. Uranium is removed from the salt solution by electrochemical reduction. The noble metals and inactive fission products from the SNF remain as solids and are melted into a metal waste form after removal from the molten salt bath. The remaining salt solution contains most of the fission products and transuranic elements from the SNF. One technique that has been identified for removing these fission products and extending the usable life of the molten salt is ion exchange with zeolite A. A model has been developed and tested for its ability to describe the ion exchange of fission product species between zeolite A and a molten salt bath used for pyroprocessing of spent nuclear fuel. The model assumes (1) a system at equilibrium, (2) immobilization of species from the process salt solution via both ion exchange and occlusion in the zeolite cage structure, and (3) chemical independence of the process salt species. The first assumption simplifies the description of this physical system by eliminating the complications of including time-dependent variables. An equilibrium state between species concentrations in the two exchange phases is a common basis for ion exchange models found in the literature. Assumption two is non-simplifying with respect to the mathematical expression of the model. Two Langmuir-like fractional terms (one for each mode of immobilization) compose each equation describing each salt species. The third assumption offers great simplification over more traditional ion exchange modeling, in which interaction of solvent species with each other

  1. Renewable energy and the role of molten salts and carbon

    Directory of Open Access Journals (Sweden)

    Fray D.

    2013-01-01

    Full Text Available Molten carbonate fuel cells have been under development for a number of years and reliable units are successfully working at 250kW scale and demonstration units have produced up to 2 MW. Although these cells cannot be considered as renewable as the fuel, hydrogen or carbon monoxide is consumed and not regenerated, the excellent reliability of such a cell can act as a stimulus to innovative development of similar cells with different outcomes. Molten salt electrolytes based upon LiCl - Li2O can be used to convert carbon dioxide, either drawn from the output of a conventional thermal power station or from the atmosphere, to carbon monoxide or carbon. Recently, dimensionally stable anodes have been developed for molten salt electrolytes, based upon alkali or alkaline ruthenates which are highly electronically conducting and these may allow the concept of high temperature batteries to be developed in which an alkali or alkaline earth element reacts with air to form oxides when the battery is discharging and the oxide decomposes when the battery is being recharged. Batteries using these concepts may be based upon the Hall-Heroult cell, which is used worldwide for the production of aluminium on an industrial scale, and could be used for load levelling. Lithium ion batteries are, at present, the preferred energy source for cars in 2050 as there are sufficient lithium reserves to satisfy the world’s energy needs for this particular application. Graphite is used in lithium ion batteries as the anode but the capacity is relatively low. Silicon and tin have much higher capacities and the use of these materials, encapsulated in carbon nanotubes and nanoparticles will be described. This paper will review these interesting developments and demonstrate that a combination of carbon and molten salts can offer novel ways of storing energy and converting carbon dioxide into useful products.

  2. Molten carbonate fuel cell cathode with mixed oxide coating

    Science.gov (United States)

    Hilmi, Abdelkader; Yuh, Chao-Yi

    2013-05-07

    A molten carbonate fuel cell cathode having a cathode body and a coating of a mixed oxygen ion conductor materials. The mixed oxygen ion conductor materials are formed from ceria or doped ceria, such as gadolinium doped ceria or yttrium doped ceria. The coating is deposited on the cathode body using a sol-gel process, which utilizes as precursors organometallic compounds, organic and inorganic salts, hydroxides or alkoxides and which uses as the solvent water, organic solvent or a mixture of same.

  3. Electrodeposition of niobium and titanium in molten salts

    International Nuclear Information System (INIS)

    Sartori, A.F.; Chagas, H.C.

    1988-01-01

    The electrodeposition of niobium and titanium in molten fluorides from the additions of fluorine niobates and fluorine titanates of potassium is described in laboratory and pilot scale. The temperature influence, the current density and the time deposition over the current efficiency, the deposits structure and the deposits purity are studied. The conditions for niobium coating over copper and carbon steel and for titanium coating over carbon steel are also presented. (C.G.C.) [pt

  4. Lithium-Boron Alloy Anodes for Molten Salt Batteries (II)

    Science.gov (United States)

    1978-05-15

    Eagle - Picher Industries, Inc. Electronics Division, Couples Dept. Attn: D. R. Cottingham J. Dines D. L. Smith J. Wilson P. 0. Box 47 Joplin, MO 64801... Eagle - Picher Industries, Inc. Miami Research Laboratories Attn: P. E. Grayson 200 Ninth Avenue, N.E. Miami, OK 74354 ESB Research Center Attn: Library...777.. -~ -- NSWC/WOL TR 78-63 LITHIUM-BORON ALLOY ANODES FOR MOLTEN SALT BATTERIES (11) BY S.DALLEK, D. W. ERNST, 0 B. F. LARRICK Ott RESEARCH AND

  5. Prediction of current distribution in a molten carbonate fuel cell

    Energy Technology Data Exchange (ETDEWEB)

    Sampath, V.; Selman, J.R.; Sammells, A.F.

    1978-01-01

    A mathematical model has been developed to predict the performance of a molten carbonate fuel cell as a function of anode and cathode gas compositions, gas flow rates, and polarization characteristics. The effect of gas flow modes such as crossflow and coflow and the effect of higher pressures on the current distribution are studied. The predicted polarization curves agree well with the experimentally generated polarization curves. Conditions for incorporating a microscopic porous electrode model into the overall model development are briefly outlined.

  6. The Danish school reform

    DEFF Research Database (Denmark)

    Bager, Ann; Mølholm, Martin; Horsbøl, Anders

    (Latour), e.g. civil service and municipal practices and texts, into the organizational practices of two local schools. On the basis of these analyses, we will establish a participatory process in which local actors are involved in the co-creation of new plurivocal and egalitarian dialogue designs......The paper presents a methodological framework for the study of the discursive emergence of the recent Danish School reform (2014). The framework will enable discourse scholars to hold an actively involved position in changing and furthering plurivocal processes of translations, negotiations...... and implementation of the reform. The framework is operationalized through research-based participatory collaborative processes involving local actors in two Danish public schools. It interlinks diverse discourse strategies and perceptive distances that traditionally belong to separate branches within discourse...

  7. Methanol partial oxidation reformer

    Science.gov (United States)

    Ahmed, Shabbir; Kumar, Romesh; Krumpelt, Michael

    1999-01-01

    A partial oxidation reformer comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell.

  8. Reforming process. Reformierungsverfahren

    Energy Technology Data Exchange (ETDEWEB)

    McCoy, C.S.

    1982-05-19

    A naphta fraction is subjected to a catalytic reforming process in several series-connected reactors. The first reactor is equipped with a moving catalyst bed containing not more the 30% of volume of the total catalyst amount. The other reactors are designed as packed-bed systems. The content of coke deposited on the catalyst of the first reactor owing to the reforming process is maintained at below 1% of weight. This is effected by periodic removal of a proportion of the contaminated catalyst from the bottom part of the bed, by its regeneration and re-feeding to the top part of the bed. This results in prolonged service life of the catalyst and simultaneous improvement of the anti-knock value of the product.

  9. Candidate molten salt investigation for an accelerator driven subcritical core

    Science.gov (United States)

    Sooby, E.; Baty, A.; Beneš, O.; McIntyre, P.; Pogue, N.; Salanne, M.; Sattarov, A.

    2013-09-01

    We report a design for accelerator-driven subcritical fission in a molten salt core (ADSMS) that utilizes a fuel salt composed of NaCl and transuranic (TRU) chlorides. The ADSMS core is designed for fast neutronics (28% of neutrons >1 MeV) to optimize TRU destruction. The choice of a NaCl-based salt offers benefits for corrosion, operating temperature, and actinide solubility as compared with LiF-based fuel salts. A molecular dynamics (MD) code has been used to estimate properties of the molten salt system which are important for ADSMS design but have never been measured experimentally. Results from the MD studies are reported. Experimental measurements of fuel salt properties and studies of corrosion and radiation damage on candidate metals for the core vessel are anticipated. A special thanks is due to Prof. Paul Madden for introducing the ADSMS group to the concept of using the molten salt as the spallation target, rather than a conventional heavy metal spallation target. This feature helps to optimize this core as a Pu/TRU burner.

  10. Design of a helium-cooled molten salt fusion breeder

    Science.gov (United States)

    Moir, R. W.; Lee, J. D.; Fulton, F. J.; Huegel, F.; Neef, W. S., Jr.; Sherwood, A. E.; Berwald, D. H.; Whitley, R. H.; Wong, C. P. C.; Devan, J. H.

    1985-02-01

    A new conceptual blanket design for a fusion reactor is discussed which produces fissile material for fission power plants. Fission is suppressed by using beryllium, rather than uranium, to multiply neutrons and also by minimizing the fissile inventory. The molten-salt breeding media (LiF + BeF2 + TghF4) is circulated through the blanket and on to the online processing system where (233)U and tritium are continuously removed. Helium cools the blanket including the steel pipes containing the molten salt. Austenitic steel was chosen because of its ease of fabrication, adequate radiation-damage lifetime, and low corrosion rate by molten salt. Safety is enhanced because the afterheat is low and the blanket materials do not react with air or water. The fusion breeder based on a pre-MARS mirror is estimated to cost $4.9B or 2.35 time an LWR of the same power. The estimated present value cost of the (233)U produced is $40/g if utility financed or $16/g if government financed.

  11. Characteristics of solidified products containing radioactive molten salt waste.

    Science.gov (United States)

    Park, Hwan-Seo; Kim, In-Tae; Cho, Yong-Zun; Eun, Hee-Chul; Kim, Joon-Hyung

    2007-11-01

    The molten salt waste from a pyroprocess to recover uranium and transuranic elements is one of the problematic radioactive wastes to be solidified into a durable wasteform for its final disposal. By using a novel method, named as the GRSS (gel-route stabilization/solidification) method, a molten salt waste was treated to produce a unique wasteform. A borosilicate glass as a chemical binder dissolves the silicate compounds in the gel products to produce one amorphous phase while most of the phosphates are encapsulated by the vitrified phase. Also, Cs in the gel product is preferentially situated in the silicate phase, and it is vitrified into a glassy phase after a heat treatment. The Sr-containing phase is mainly phosphate compounds and encapsulated by the glassy phase. These phenomena could be identified by the static and dynamic leaching test that revealed a high leach resistance of radionuclides. The leach rates were about 10(-3) - 10(-2) g/m2 x day for Cs and 10(-4) - 10(-3) g/m2 x day for Sr, and the leached fractions of them were predicted to be 0.89% and 0.39% at 900 days, respectively. This paper describes the characteristics of a unique wasteform containing a molten salt waste and provides important information on a newly developed immobilization technology for salt wastes, the GRSS method.

  12. Structure and thermodynamic properties of molten alkali chlorides

    International Nuclear Information System (INIS)

    Ballone, P.; Pastore, G.; Tosi, M.P.; Trieste Univ.

    1984-03-01

    Self-consistent calculations of partial pair distribution functions and thermodynamic properties are presented for molten alkali chlorides in a non-polarizable-ion model. The theory starts from the hypernetted chain approximation and analyzes the role of bridge diagrams both for a two-component ionic plasma on a neutralizing background and for a binary ionic liquid of cations and anions. A simple account of excluded-volume effects suffices for a good description of the pair distribution functions in the two-component plasma, in analogy with earlier work on one-component fluids. The interplay of Coulomb attractions and repulsions in the molten salt requires, on the other hand, the inclusion of (i) excluded-volume effects for the various ion pairs as in a mixture of hard spheres with non-additive radii and (ii) medium-range Coulomb effects reflected mainly in the like-ion correlations. All these effects are included approximately in an empirical evaluation of the bridge functions, with numerical results which compare very well with computer simulation data. A detailed discussion of the results against experimental structural data is then given in the case of molten sodium chloride. (author)

  13. Molten salt processing of mixed wastes with offgas condensation

    International Nuclear Information System (INIS)

    Cooper, J.F.; Brummond, W.; Celeste, J.; Farmer, J.; Hoenig, C.; Krikorian, O.H.; Upadhye, R.; Gay, R.L.; Stewart, A.; Yosim, S.

    1991-01-01

    We are developing an advanced process for treatment of mixed wastes in molten salt media at temperatures of 700--1000 degrees C. Waste destruction has been demonstrated in a single stage oxidation process, with destruction efficiencies above 99.9999% for many waste categories. The molten salt provides a heat transfer medium, prevents thermal surges, and functions as an in situ scrubber to transform the acid-gas forming components of the waste into neutral salts and immobilizes potentially fugitive materials by a combination of particle wetting, encapsulation and chemical dissolution and solvation. Because the offgas is collected and assayed before release, and wastes containing toxic and radioactive materials are treated while immobilized in a condensed phase, the process avoids the problems sometimes associated with incineration processes. We are studying a potentially improved modification of this process, which treats oxidizable wastes in two stages: pyrolysis followed by catalyzed molten salt oxidation of the pyrolysis gases at ca. 700 degrees C. 15 refs., 5 figs., 1 tab

  14. Uranium (III) precipitation in molten chloride by wet argon sparging

    Energy Technology Data Exchange (ETDEWEB)

    Vigier, Jean-François, E-mail: jean-francois.vigier@ec.europa.eu [CEA, Nuclear Energy Division, Radiochemistry & Processes Department, F-30207 Bagnols sur Cèze (France); Unité de Catalyse et de Chimie du Solide, UCCS UMR CNRS 8181, Univ. Lille Nord de France, ENSCL-USTL, B.P. 90108, 59652 Villeneuve d' Ascq Cedex (France); Laplace, Annabelle [CEA, Nuclear Energy Division, Radiochemistry & Processes Department, F-30207 Bagnols sur Cèze (France); Renard, Catherine [Unité de Catalyse et de Chimie du Solide, UCCS UMR CNRS 8181, Univ. Lille Nord de France, ENSCL-USTL, B.P. 90108, 59652 Villeneuve d' Ascq Cedex (France); Miguirditchian, Manuel [CEA, Nuclear Energy Division, Radiochemistry & Processes Department, F-30207 Bagnols sur Cèze (France); Abraham, Francis [Unité de Catalyse et de Chimie du Solide, UCCS UMR CNRS 8181, Univ. Lille Nord de France, ENSCL-USTL, B.P. 90108, 59652 Villeneuve d' Ascq Cedex (France)

    2016-06-15

    In the context of pyrochemical processes for nuclear fuel treatment, the precipitation of uranium (III) in molten salt LiCl-CaCl{sub 2} (30–70 mol%) at 705 °C is studied. First, this molten chloride is characterized with the determination of the water dissociation constant. With a value of 10{sup −4.0}, the salt has oxoacid properties. Then, the uranium (III) precipitation using wet argon sparging is studied. The salt is prepared using UCl{sub 3} precursor. At the end of the precipitation, the salt is totally free of solubilized uranium. The main part is converted into UO{sub 2} powder but some uranium is lost during the process due to the volatility of uranium chloride. The main impurity of the resulting powder is calcium. The consequences of oxidative and reductive conditions on precipitation are studied. Finally, coprecipitation of uranium (III) and neodymium (III) is studied, showing a higher sensitivity of uranium (III) than neodymium (III) to precipitation. - Highlights: • Precipitation of Uranium (III) is quantitative in molten salt LiCl-CaCl{sub 2} (30–70 mol%). • The salt is oxoacid with a water dissociation constant of 10{sup −4.0} at 705 °C. • Volatility of uranium chloride is strongly reduced in reductive conditions. • Coprecipitation of U(III) and Nd(III) leads to a consecutive precipitation of the two elements.

  15. Corrosion resistance of metals and alloys in molten alkalies

    International Nuclear Information System (INIS)

    Zarubitskij, O.G.; Dmitruk, B.F.; Minets, L.A.

    1979-01-01

    Literature data on the corrosion of non-ferrous and noble metals, iron and steels in the molten alkalis and mixtures of their base are presented. It is shown that zirconium, niobium and tantalum are characterized by high corrosion stability in the molten NaOH. Additions of NaOH and KOH to the alkali chloride melts result in a 1000 time decrease of zirconium corrosion rate at 850 deg. The data testify to the characteristic passivating properties of OH - ions; Mo and W do not possess an ability to selfpassivation in hydroxide melts. Corrosion resistance of carbon and chromium-nickel steels in hydroxide melts depends considerably on the temperature, electrolyte composition and atmosphere over them. At the temperatures up to 600 deg C chromium-nickel steel is corrosion resistant in the molten alkali only in the inert atmosphere. Corrosion rate of chromium-nickel alloy is the lower the less chromium and the more nickel it contains. For the small installations the 4Kh18N25S2 and Kh23N28M3D3T steels can be recommended

  16. Socially Improving Tax Reforms

    OpenAIRE

    Duclos, Jean-Yves; Makdissi, Paul; Wodon, Quentin

    2008-01-01

    This paper proposes graphical methods to determine whether commodity-tax changes are "socially improving", in the sense of improving social welfare or decreasing poverty for large classes of social welfare and poverty indices. It also derives estimators of critical poverty lines and economic efficiency ratios which can be used to characterize socially-improving tax reforms. The statistical properties of the various estimators are derived in order to make the method implementable using survey ...

  17. Environmental fiscal reforms

    OpenAIRE

    Ashish Chaturvedi; Manjeet S. Saluja; Abhijit Banerjee; Rachna Arora

    2014-01-01

    The paper presents concepts and instruments of environmental fiscal reforms (EFR) and their application in the Indian context. EFR can lead to environmental improvement more efficiently and cost effectively than traditional regulation. There is substantial experience of successful EFR implementation in the European Union. India has also adopted some EFR measures such as deregulation of petrol prices, coal cess, and subsidy for setting up common effluent treatment plants. The challenges of imp...

  18. The moral economy of austerity: analysing UK welfare reform.

    Science.gov (United States)

    Morris, Lydia

    2016-03-01

    This paper notes the contemporary emergence of 'morality' in both sociological argument and political rhetoric, and analyses its significance in relation to ongoing UK welfare reforms. It revisits the idea of 'moral economy' and identifies two strands in its contemporary application; that all economies depend on an internal moral schema, and that some external moral evaluation is desirable. UK welfare reform is analysed as an example of the former, with reference to three distinct orientations advanced in the work of Freeden (1996), Laclau (2014), and Lockwood (1996). In this light, the paper then considers challenges to the reform agenda, drawn from third sector and other public sources. It outlines the forms of argument present in these challenges, based respectively on rationality, legality, and morality, which together provide a basis for evaluation of the welfare reforms and for an alternative 'moral economy'. © London School of Economics and Political Science 2016.

  19. Online monitoring of corrosion behavior in molten metal using laser-induced breakdown spectroscopy

    Science.gov (United States)

    Zeng, Qiang; Pan, Congyuan; Li, Chaoyang; Fei, Teng; Ding, Xiaokang; Du, Xuewei; Wang, Qiuping

    2018-04-01

    The corrosion behavior of structure materials in direct contact with molten metals is widespread in metallurgical industry. The corrosion of casting equipment by molten metals is detrimental to the production process, and the corroded materials can also contaminate the metals being produced. Conventional methods for studying the corrosion behavior by molten metal are offline. This work explored the application of laser-induced breakdown spectroscopy (LIBS) for online monitoring of the corrosion behavior of molten metal. The compositional changes of molten aluminum in crucibles made of 304 stainless steel were obtained online at 1000 °C. Several offline techniques were combined to determine the corrosion mechanism, which was highly consistent with previous studies. Results proved that LIBS was an efficient method to study the corrosion mechanism of solid materials in molten metal.

  20. Lithuanian way of reforms to electricity market

    International Nuclear Information System (INIS)

    Bacauskas, A.

    2002-01-01

    Lithuania has inherited a structure of the energy industry, which originally has been developed not for the country, as an independent state, but according to the provisions of the former USSR energy policy, covering energy demand of whole region, including the Baltic countries, Belarus and the Kaliningrad region of Russia. The Lithuanian power system is interconnected by high voltage power lines and operates in parallel with Latvian, Estonian, Russian and Belarus power systems. During twelve years of independence the power sector passed significant changes from a vertically integrated monopoly to some separate power companies and meets EU requirements to an internal electricity market. The main issues of reforms: transparency of costs, commercial relations in power sector, fulfilment of the Electricity Directive 96/92/EU. The Lithuanian electricity market is small and inefficient. Current reforms of a power sector are directed to create the common Baltic electricity market. (author)

  1. Conditions for successful land reform in Africa

    Directory of Open Access Journals (Sweden)

    JA Groenewald

    2004-11-01

    Full Text Available Land reform has traditionally had two objectives: equity and productivity. Food insecurity and the need for agriculture to contribute to development emphasise the need to maintain and improve productivity while improving equitability. Land must foster production and agriculture must attract good human material. The following areas need to be considered in policy formulation and delivery: an effective institutional framework involving all the relevant public and private bodies; efficient fiscal planning is essential; potentially successful farmers must be selected and given special support, including extension and adult education; complementary services and infrastructure are needed; prioritisation of functions and land tenure reform is often necessary. In addition, international agricultural markets are very important for Africa.  Wealthy nations should cease trade-distorting protection of their own farmers.

  2. State-of-the-Art Report on Molten Corium Concrete Interaction and Ex-Vessel Molten Core Coolability

    International Nuclear Information System (INIS)

    Bonnet, Jean-Michel; Cranga, Michel; Vola, Didier; Marchetto, Cathy; Kissane, Martin; ); Robledo, Fernando; Farmer, Mitchel T.; Spengler, Claus; Basu, Sudhamay; Atkhen, Kresna; Fargette, Andre; Fisher, Manfred; Foit, Jerzi; Hotta, Akitoshi; Morita, Akinobu; Journeau, Christophe; Moiseenko, Evgeny; Polidoro, Franco; Zhou, Quan

    2017-01-01

    Activities carried out over the last three decades in relation to core-concrete interactions and melt coolability, as well as related containment failure modes, have significantly increased the level of understanding in this area. In a severe accident with little or no cooling of the reactor core, the residual decay heat in the fuel can cause the core materials to melt. One of the challenges in such cases is to determine the consequences of molten core materials causing a failure of the reactor pressure vessel. Molten corium will interact, for example, with structural concrete below the vessel. The reaction between corium and concrete, commonly referred to as MCCI (molten core concrete interaction), can be extensive and can release combustible gases. The cooling behaviour of ex-vessel melts through sprays or flooding is also complex. This report summarises the current state of the art on MCCI and melt coolability, and thus should be useful to specialists seeking to predict the consequences of severe accidents, to model developers for severe-accident computer codes and to designers of mitigation measures

  3. Thorium cycle and molten salt reactors: field parameters and field constraints investigations toward 'thorium molten salt reactor' definition

    International Nuclear Information System (INIS)

    Mathieu, L.

    2005-09-01

    Producing nuclear energy in order to reduce the anthropic CO 2 emission requires major technological advances. Nuclear plants of 4. generation have to respond to several constraints, as safety improvements, fuel breeding and radioactive waste minimization. For this purpose, it seems promising to use Thorium Cycle in Molten Salt Reactors. Studies on this domain have already been carried out. However, the final concept suffered from serious issues and was discontinued. A new reflection on this topic is being led in order to find acceptable solutions, and to design the Thorium Molten Salt Reactor concept. A nuclear reactor is simulated by the coupling of a neutron transport code with a materials evolution code. This allows us to reproduce the reactor behavior and its evolution all along its operation. Thanks to this method, we have studied a large number of reactor configurations. We have evaluated their efficiency through a group of constraints they have to satisfy. This work leads us to a better understanding of many physical phenomena controlling the reactor behavior. As a consequence, several efficient configurations have been discovered, allowing the emergence of new points of view in the research of Molten Salt Reactors. (author)

  4. Coupled optical and thermal detailed simulations for the accurate evaluation and performance improvement of molten salts solar towers

    Science.gov (United States)

    García-Barberena, Javier; Mutuberria, Amaia; Palacin, Luis G.; Sanz, Javier L.; Pereira, Daniel; Bernardos, Ana; Sanchez, Marcelino; Rocha, Alberto R.

    2017-06-01

    The National Renewable Energy Centre of Spain, CENER, and the Technology & Innovation area of ACS Cobra, as a result of their long term expertise in the CSP field, have developed a high-quality and high level of detail optical and thermal simulation software for the accurate evaluation of Molten Salts Solar Towers. The main purpose of this software is to make a step forward in the state-of-the-art of the Solar Towers simulation programs. Generally, these programs deal with the most critical systems of such plants, i.e. the solar field and the receiver, on an independent basis. Therefore, these programs typically neglect relevant aspects in the operation of the plant as heliostat aiming strategies, solar flux shapes onto the receiver, material physical and operational limitations, transient processes as preheating and secure cloud passing operating modes, and more. The modelling approach implemented in the developed program consists on effectively coupling detailed optical simulations of the heliostat field with also detailed and full-transient thermal simulations of the molten salts tube-based external receiver. The optical model is based on an accurate Monte Carlo ray-tracing method which solves the complete solar field by simulating each of the heliostats at once according to their specific layout in the field. In the thermal side, the tube-based cylindrical external receiver of a Molten Salts Solar Tower is modelled assuming one representative tube per panel, and implementing the specific connection layout of the panels as well as the internal receiver pipes. Each tube is longitudinally discretized and the transient energy and mass balances in the temperature dependent molten salts and steel tube models are solved. For this, a one dimensional radial heat transfer model based is used. The thermal model is completed with a detailed control and operation strategy module, able to represent the appropriate operation of the plant. An integration framework has been

  5. Hybrid Molten Bed Gasifier for High Hydrogen Syngas Production

    Energy Technology Data Exchange (ETDEWEB)

    Rue, David [Gas Technology Institute, Des Plaines, IL (United States)

    2017-05-23

    The techno-economic analyses of the hybrid molten bed gasification technology and laboratory testing of the HMB process were carried out in this project by the Gas Technology Institute and partner Nexant, Inc. under contract with the US Department of Energy’s National Energy Technology Laboratory. This report includes the results of two complete IGCC and Fischer-Tropsch TEA analyses comparing HMB gasification with the Shell slagging gasification process as a base case. Also included are the results of the laboratory simulation tests of the HMB process using Illinois #6 coal fed along with natural gas, two different syngases, and steam. Work in this 18-month project was carried out in three main Tasks. Task 2 was completed first and involved modeling, mass and energy balances, and gasification process design. The results of this work were provided to Nexant as input to the TEA IGCC and FT configurations studied in detail in Task 3. The results of Task 2 were also used to guide the design of the laboratory-scale testing of the HMB concept in the submerged combustion melting test facility in GTI’s industrial combustion laboratory. All project work was completed on time and budget. A project close-out meeting reviewing project results was conducted on April 1, 2015 at GTI in Des Plaines, IL. The hybrid molten bed gasification process techno-economic analyses found that the HMB process is both technically and economically attractive compared with the Shell entrained flow gasification process. In IGCC configuration, HMB gasification provides both efficiency and cost benefits. In Fischer-Tropsch configuration, HMB shows small benefits, primarily because even at current low natural gas prices, natural gas is more expensive than coal on an energy cost basis. HMB gasification was found in the TEA to improve the overall IGCC economics as compared to the coal only Shell gasification process. Operationally, the HMB process proved to be robust and easy to operate. The burner

  6. On the chemical constitution of a molten oxide core of a fast breeder reactor

    International Nuclear Information System (INIS)

    Hodkin, D.J.; Potter, P.E.

    1980-01-01

    A knowledge of the chemical constitution of a molten oxide fast reactor core is of great importance in the assessment of heat transfer from a cooling molten pool of debris and in the selection of materials for the construction of sacrificial beds for core containment. In this paper we describe some thermodynamic assessments of the likely chemical constitution of a molten oxide core, and then support our assessments by experimental observations

  7. Molten salt oxidation of organic hazardous waste with high salt content.

    Science.gov (United States)

    Lin, Chengqian; Chi, Yong; Jin, Yuqi; Jiang, Xuguang; Buekens, Alfons; Zhang, Qi; Chen, Jian

    2018-02-01

    Organic hazardous waste often contains some salt, owing to the widespread use of alkali salts during industrial manufacturing processes. These salts cause complications during the treatment of this type of waste. Molten salt oxidation is a flameless, robust thermal process, with inherent capability of destroying the organic constituents of wastes, while retaining the inorganic ingredients in the molten salt. In the present study, molten salt oxidation is employed for treating a typical organic hazardous waste with a high content of alkali salts. The hazardous waste derives from the production of thiotriazinone. Molten salt oxidation experiments have been conducted using a lab-scale molten salt oxidation reactor, and the emissions of CO, NO, SO 2 , HCl and dioxins are studied. Impacts are investigated from the composition of the molten salts, the types of feeding tube, the temperature of molten carbonates and the air factor. Results show that the waste can be oxidised effectively in a molten salt bath. Temperature of molten carbonates plays the most important role. With the temperature rising from 600 °C to 750 °C, the oxidation efficiency increases from 91.1% to 98.3%. Compared with the temperature, air factor has but a minor effect, as well as the composition of the molten salts and the type of feeding tube. The molten carbonates retain chlorine with an efficiency higher than 99.9% and the emissions of dioxins are below 8 pg TEQ g -1 sample. The present study shows that molten salt oxidation is a promising alternative for the disposal of organic hazardous wastes containing a high salt content.

  8. Maintaining molten salt electrolyte concentration in aluminum-producing electrolytic cell

    Energy Technology Data Exchange (ETDEWEB)

    Barnett, Robert J.; Mezner, Michael B.; Bradford, Donald R

    2005-01-04

    A method of maintaining molten salt concentration in a low temperature electrolytic cell used for production of aluminum from alumina dissolved in a molten salt electrolyte contained in a cell free of frozen crust wherein volatile material is vented from the cell and contacted and captured on alumina being added to the cell. The captured volatile material is returned with alumina to cell to maintain the concentration of the molten salt.

  9. Chronopotentiometry of refractory metals, actinides and oxyanions in molten salts: A review

    Science.gov (United States)

    Bansal, Narottam P.

    1992-01-01

    The applications of chronopotentiometry to the study of electrochemical behavior of three technologically important areas of refractory metals, actinides, and oxyanions in molten salts are critically reviewed. Chronopotentiometry is a very versatile diagnostic tool to understand the reaction mechanism of the electrode processes for the electrochemical reduction/oxidation of these electroactive species in molten salt solutions. Well adherent, compact, and uniformly thick coatings of refractory metals may be electrodeposited from their solutions in molten salts.

  10. The molten salt reactor: R and D status and perspectives in Europe

    International Nuclear Information System (INIS)

    Renault, Claude; Delpech, Sylvie; Merle-Lucotte, Elsa; Konings, Rudy; Hron, Miloslav; Ignatiev, Victor

    2010-01-01

    The paper concentrates on molten salt fast reactor (MSFR) concepts which are receiving most attention in the EU context. It shows the main R and D achievements and some remaining issues to be addressed in such essential areas as (a) reactor conceptual design, (b) molten salt properties, (c) fuel salt clean-up scheme and (d) high temperature materials. The status and perspectives of molten salt reactor R and D efforts in Europe are then discussed

  11. Study of the pyrochemical treatment-recycling process of the Molten Salt Reactor fuel

    International Nuclear Information System (INIS)

    Boussier, H.; Heuer, D.

    2010-01-01

    The Separation Processes Studies Laboratory (Commissariat a l'energie Atomique) has made a preliminary assessment of the reprocessing system associated with Molten Salt Fast Reactor (MSFR). The scheme studied in this paper is based on the principle of reductive extraction and metal transfer that constituted the core process designed for the Molten Salt Breeder Reactor (MSBR), although the flow diagram has been adapted to the current needs of the Molten Salt Reactor Fast (MSFR).

  12. Steam reformer with catalytic combustor

    Science.gov (United States)

    Voecks, Gerald E. (Inventor)

    1990-01-01

    A steam reformer is disclosed having an annular steam reforming catalyst bed formed by concentric cylinders and having a catalytic combustor located at the center of the innermost cylinder. Fuel is fed into the interior of the catalytic combustor and air is directed at the top of the combustor, creating a catalytic reaction which provides sufficient heat so as to maintain the catalytic reaction in the steam reforming catalyst bed. Alternatively, air is fed into the interior of the catalytic combustor and a fuel mixture is directed at the top. The catalytic combustor provides enhanced radiant and convective heat transfer to the reformer catalyst bed.

  13. Education Reform in Hong Kong

    Directory of Open Access Journals (Sweden)

    Chris Dowson

    2000-05-01

    Full Text Available Since the early 1990s, the pace of educational reform in Hong Kong has accelerated and broadened to incorporate almost all areas of schooling. The reforms introduced during this period can be subsumed under what has generally been labelled the quality movement. In this paper, we review and comment on a number of policy reform initiatives in the four areas of "Quality Education," English Language Benchmarking, Initial Teacher Training and the Integration of Pupils with Special Needs into Ordinary Classrooms. Following a brief description of each policy initiative, the reforms are discussed in terms of their consistency, coherence and cultural fit.

  14. Rheological behavior and constitutive equations of heterogeneous titanium-bearing molten slag

    Science.gov (United States)

    Jiang, Tao; Liao, De-ming; Zhou, Mi; Zhang, Qiao-yi; Yue, Hong-rui; Yang, Song-tao; Duan, Pei-ning; Xue, Xiang-xin

    2015-08-01

    Experimental studies on the rheological properties of a CaO-SiO2-Al2O3-MgO-TiO2-(TiC) blast furnace (BF) slag system were conducted using a high-temperature rheometer to reveal the non-Newtonian behavior of heterogeneous titanium-bearing molten slag. By measuring the relationships among the viscosity, the shear stress and the shear rate of molten slags with different TiC contents at different temperatures, the rheological constitutive equations were established along with the rheological parameters; in addition, the non-Newtonian fluid types of the molten slags were determined. The results indicated that, with increasing TiC content, the viscosity of the molten slag tended to increase. If the TiC content was less than 2wt%, the molten slag exhibited the Newtonian fluid behavior when the temperature was higher than the critical viscosity temperature of the molten slag. In contrast, the molten slag exhibited the non-Newtonian pseudoplastic fluid characteristic and the shear thinning behavior when the temperature was less than the critical viscosity temperature. However, if the TiC content exceeded 4wt%, the molten slag produced the yield stress and exhibited the Bingham and plastic pseudoplastic fluid behaviors when the temperature was higher and lower than the critical viscosity temperature, respectively. When the TiC content increased further, the yield stress of the molten slag increased and the shear thinning phenomenon became more obvious.

  15. Future Perfect? Conflict and Agency in Higher Education Reform in Poland

    Science.gov (United States)

    Szkudlarek, Tomasz; Stankiewicz, Lukasz

    2014-01-01

    The paper is based on an analysis of interviews with individuals engaged in systemic reform of higher education (HE) in Poland. The reform is perceived as controversial: it is supported by the media and claimed to be in line with the expectations of external stakeholders of HE, as well as being congruent with Poland's international commitments; at…

  16. Public Sector Reform: Which way are we headed? An overview of recent literature and research

    NARCIS (Netherlands)

    Vries, M.S. de; Nemec, J.

    2012-01-01

    This paper investigates recent literature and research on public sector reform and aims to answer the question to what degree public administration systems and reforms are still influenced by recommendations flowing from the NPM tradition. This paper distinguishes two dimensions of NPM: the internal

  17. Putting Trade Logistics Reform “on the Map” in Armenia

    OpenAIRE

    Gabrielyan, Gagik; Huria, Ankur; Nazaryan, Arsen

    2012-01-01

    Armenia did it through trade logistics reform - with help from International Finance Corporation's (IFC's) Armenia doing business reform and regulatory simplification project, launched in February 2009. The project team builds constructive relationships-including well-designed and consistent communication-with the Ministry of Economy, the customs service, and the private sector to identify...

  18. 26 CFR 1.615-9 - Notification under Tax Reform Act of 1969.

    Science.gov (United States)

    2010-04-01

    ... 26 Internal Revenue 7 2010-04-01 2010-04-01 true Notification under Tax Reform Act of 1969. 1.615...) INCOME TAX (CONTINUED) INCOME TAXES (CONTINUED) Natural Resources § 1.615-9 Notification under Tax Reform... whom the taxpayer's income tax return is required to be filed. If the election is made within the time...

  19. Unintended consequences or ambivalent policy objectives? Conflict minerals and mining reform in the DR Congo

    NARCIS (Netherlands)

    J.A. Diemel (Jose); D.J.M. Hilhorst (Thea)

    2018-01-01

    textabstractSince the early 2000s, the government of the Democratic Republic of Congo and the international community have initiated a reform process in the artisanal mining sector to break the linkages between mineral extraction and violent conflict. Research on the reforms reaches

  20. The Use (and Misuse) of PISA in Guiding Policy Reform: The Case of Spain

    Science.gov (United States)

    Choi, Álvaro; Jerrim, John

    2016-01-01

    In 2013 Spain introduced a series of educational reforms explicitly inspired by the Programme for International Student Assessment (PISA) 2012 results. These reforms were mainly implemented in secondary education--based upon the assumption that this is where Spain's educational problems lie. This paper questions this assumption by attempting to…

  1. Reform of the Method for Evaluating the Teaching of Medical Linguistics to Medical Students

    Science.gov (United States)

    Zhang, Hongkui; Wang, Bo; Zhang, Longlu

    2014-01-01

    Explorating reform of the teaching evaluation method for vocational competency-based education (CBE) curricula for medical students is a very important process in following international medical education standards, intensify ing education and teaching reforms, enhancing teaching management, and improving the quality of medical education. This…

  2. The Cheney-Powell Congressional Reform Act: Completing the Defense Reform Agenda

    Science.gov (United States)

    1991-04-05

    problem definition . 11 A near unanimous viewpoint in the reform literature is that change was and is required in both the Administration (primarily DOD...rivalries, competing agendas of civilian and military hierarchies, internal and external lobbying efforts, penchants for the ease of salami slice...Schott. "Defense Efficiencies in the 1990s." The Washington Quarterly, Vol. 12, Spring 1990, pp. 115-128. Du Boff, Richard B. "What Military Spending

  3. Molten carbonate fuel cell product design improvement

    Energy Technology Data Exchange (ETDEWEB)

    P. Voyentzie; T. Leo; A. Kush; L. Christner; G. Carlson; C. Yuh

    1998-12-20

    Drawing on the manufacture, field test, and post-test experience of the sixteen Santa Clara Demonstration Project (SCDP) stacks, ERC is finalizing the next generation commercial entry product design. The second generation cells are 50% larger in area, 40% lighter on equal geometric area basis, and 30% thinner than the earlier design. These improvements have resulted in doubling of the full-height stack power. A low-cost and high-strength matrix has also been developed for improving product ruggedness. The low-cost advanced cell design incorporating these improvements has been refined through six short stack tests. Power production per cell of two times the SCDP maximum power operation, over ten thermal cycles, and overall operating flexibility with respect to load and thermal changes have been demonstrated in these short stack tests. An internally insulated stack enclosure has been designed and fabricated to eliminate the need for an inert gas environment during operation. ERC has acquired the capability for testing 400kW full-height direct fuel ceil (DFC) stack and balance-of-plant equipment. With the readiness of the power plant test facility, the cell package design, and the stack module, full-height stack testing has begun. The first full- height stack incorporating the post-SCDP second generation design was completed. The stack reached a power level of 253 kW, setting a world record for the highest power production from the advanced fuel cell system. Excellent performance uniformity at this power level affirmed manufacturing reproducibility of the components at the factory. This unoptimized small size test has achieved pipeline natural gas to DC electricity conversion efficiency of 47% (based on lower heating value - LHV) including the parasitic power consumed by the BOP equipment; that should translate to more than 50% efficiency in commercial operation, before employing cogeneration. The power plant system also operated smoothly. With the success of this

  4. MOLTEN CARBONATE FUEL CELL PRODUCT DESIGN IMPROVEMENT

    Energy Technology Data Exchange (ETDEWEB)

    H.C. Maru; M. Farooque

    2005-03-01

    The program was designed to advance the carbonate fuel cell technology from full-size proof-of-concept field test to the commercial design. DOE has been funding Direct FuelCell{reg_sign} (DFC{reg_sign}) development at FuelCell Energy, Inc. (FCE, formerly Energy Research Corporation) from an early state of development for stationary power plant applications. The current program efforts were focused on technology and system development, and cost reduction, leading to commercial design development and prototype system field trials. FCE, in Danbury, CT, is a world-recognized leader for the development and commercialization of high efficiency fuel cells that can generate clean electricity at power stations, or at distributed locations near the customers such as hospitals, schools, universities, hotels and other commercial and industrial applications. FCE has designed three different fuel cell power plant models (DFC300A, DFC1500 and DFC3000). FCE's power plants are based on its patented DFC{reg_sign} technology, where a hydrocarbon fuel is directly fed to the fuel cell and hydrogen is generated internally. These power plants offer significant advantages compared to the existing power generation technologies--higher fuel efficiency, significantly lower emissions, quieter operation, flexible siting and permitting requirements, scalability and potentially lower operating costs. Also, the exhaust heat by-product can be used for cogeneration applications such as high-pressure steam, district heating and air conditioning. Several sub-MW power plants based on the DFC design are currently operating in Europe, Japan and the US. Several one-megawatt power plant design was verified by operation on natural gas at FCE. This plant is currently installed at a customer site in King County, WA under another US government program and is currently in operation. Because hydrogen is generated directly within the fuel cell module from readily available fuels such as natural gas and

  5. Reform Drivers and Reform Obstacles in Natural Resource Management

    DEFF Research Database (Denmark)

    Gezelius, Stig S.; Raakjær, Jesper; Hegland, Troels Jacob

    2010-01-01

    ABSTRACT: The ability to transform historical learning into institutional reform is a key to success in the management of common pool natural resources. Based on a model of institutional inertia and a comparative analysis of Northeast Atlantic fisheries management from 1945 to the present....... Institutional inertia entails that large-scale management reform tends to be crisis driven....

  6. Novel Reforming Catalysts

    Energy Technology Data Exchange (ETDEWEB)

    Pfefferle, Lisa D; Haller, Gary L

    2012-10-16

    Aqueous phase reforming is useful for processing oxygenated hydrocarbons to hydrogen and other more useful products. Current processing is hampered by the fact that oxide based catalysts are not stable under high temperature hydrothermal conditions. Silica in the form of structured MCM-41 is thermally a more stable support for Co and Ni than conventional high surface area amorphous silica but hydrothermal stability is not demonstrated. Carbon nanotube supports, in contrast, are highly stable under hydrothermal reaction conditions. In this project we show that carbon nanotubes are stable high activity/selectivity supports for the conversion of ethylene glycol to hydrogen.

  7. Reforming Russian civil Procedure

    OpenAIRE

    MALESHIN DMITRY; SILVESTRI ELISABETTA; SITDIKOV RUSLAN; VALEEV DAMIR

    2016-01-01

    The II Annual symposium of the journal Herald of Civil Procedure ‘2015: the Civil Procedure 2.0: reform and Current state’took place on october 9, 2015, at the Faculty of Law of kazan (Volga region) Federal university. the symposium is now an established tradition for the university. In 2015 it brought together in kazan eminent scholars of civil procedure from cities across the whole of russia: Moscow, st. Petersburg, saratov, Ekaterinburg, omsk, samara, Nizhnekamsk and others. this large-sca...

  8. Reforming Russian Civil Procedur

    OpenAIRE

    Dmitry Maleshin; Elisabetta Silvestri; Ruslan Sitgikov; Damir Valeev

    2016-01-01

    The II Annual Symposium of the journal Herald of Civil Procedure ‘2015: The Civil Procedure 2.0: Reform and Current State’ took place on October 9, 2015, at the Faculty of Law of Kazan (Volga region) Federal University.The Symposium is now an established tradition for the University. In 2015 it brought together in Kazan eminent scholars of civil procedure from cities across the whole of Russia: Moscow, St. Petersburg, Saratov, Ekaterinburg, Omsk, Samara, Nizhnekamsk and others. This large-sca...

  9. Environmental fiscal reforms

    Directory of Open Access Journals (Sweden)

    Ashish Chaturvedi

    2014-09-01

    Full Text Available The paper presents concepts and instruments of environmental fiscal reforms (EFR and their application in the Indian context. EFR can lead to environmental improvement more efficiently and cost effectively than traditional regulation. There is substantial experience of successful EFR implementation in the European Union. India has also adopted some EFR measures such as deregulation of petrol prices, coal cess, and subsidy for setting up common effluent treatment plants. The challenges of implementing EFR measures in India are also discussed, including inadequate analysis, policy framework and institutional capacity, as well as conflict with poverty reduction and building political support.

  10. Medical Education and Curriculum Reform: Putting Reform Proposals in Context

    Directory of Open Access Journals (Sweden)

    Daniel Kam Yin Chan, MD, MB.BS, MHA

    2004-01-01

    Full Text Available The purpose of this paper is to elaborate criteria by which the principles of curriculum reform can be judged. To this end, the paper presents an overview of standard critiques of medical education and examines the ways medical curriculum reforms have responded to these critiques. The paper then sets out our assessment of these curriculum reforms along three parameters: pedagogy, educational context, and knowledge status. Following on from this evaluation of recent curriculum reforms, the paper puts forward four criteria with which to gauge the adequacy medical curriculum reform. These criteria enable us to question the extent to which new curricula incorporate methods and approaches for ensuring that its substance: overcomes the traditional opposition between clinical and resource dimensions of care; emphasizes that the clinical work needs to be systematized in so far as that it feasible; promotes multi-disciplinary team work, and balances clinical autonomy with accountability to non-clinical stakeholders.

  11. 26 CFR 1.673(b)-1 - Income payable to charitable beneficiaries before amendment by Tax Reform Act of 1969).

    Science.gov (United States)

    2010-04-01

    ... before amendment by Tax Reform Act of 1969). 1.673(b)-1 Section 1.673(b)-1 Internal Revenue INTERNAL REVENUE SERVICE, DEPARTMENT OF THE TREASURY (CONTINUED) INCOME TAX (CONTINUED) INCOME TAXES Grantors and... amendment by Tax Reform Act of 1969). (a) Pursuant to section 673(b) a grantor is not treated as an owner of...

  12. 26 CFR 1.269-6 - Relationship of section 269 to section 382 before the Tax Reform Act of 1986.

    Science.gov (United States)

    2010-04-01

    ... before the Tax Reform Act of 1986. 1.269-6 Section 1.269-6 Internal Revenue INTERNAL REVENUE SERVICE, DEPARTMENT OF THE TREASURY (CONTINUED) INCOME TAX (CONTINUED) INCOME TAXES Items Not Deductible § 1.269-6 Relationship of section 269 to section 382 before the Tax Reform Act of 1986. Section 269 and §§ 1.269-1...

  13. 26 CFR 1.706-2T - Temporary regulations; question and answer under the Tax Reform Act of 1984.

    Science.gov (United States)

    2010-04-01

    ... the Tax Reform Act of 1984. 1.706-2T Section 1.706-2T Internal Revenue INTERNAL REVENUE SERVICE, DEPARTMENT OF THE TREASURY (CONTINUED) INCOME TAX (CONTINUED) INCOME TAXES Partners and Partnerships § 1.706-2T Temporary regulations; question and answer under the Tax Reform Act of 1984. Question 1: For...

  14. Capturing molten globule state of α-lactalbumin through constant pH molecular dynamics simulations

    Science.gov (United States)

    Bhattacharjee, Nicholus; Rani, Pooja; Biswas, Parbati

    2013-03-01

    The recently developed methods of constant pH molecular dynamics directly captures the correlation between protonation and conformation to probe protein structure, function, and dynamics. In this work, we investigate the effect of pH on the conformational properties of the protein human α-lactalbumin. Constant pH simulations at both acidic and alkaline medium indicate the formation of the molten globule state, which is in accordance with the previous experimental observations (especially, in acidic medium). The size of the protein measured by its radius of gyration (RG) exhibits a marked increase in both acidic and alkaline medium, which matches with the corresponding experimentally observed value of RG found in the molten globule. The probability of native contacts is also considerably reduced at acidic and basic pH as compared to that of native structure crystallized at neutral pH. The mean fractal dimension D2 of the protein records a sharp increase in basic medium as compared to those in neutral and acidic solutions implying a significant pH induced conformational change. The mean square fluctuations of all residues of the entire protein are found to increase by several folds in both acidic and basic medium, which may be correlated with the normalized solvent accessibility of the residues indicating role of solvent accessible surface area on protein internal dynamics. The helices comprising the α-domain of the protein are moderately preserved in the acidic and alkaline pH. However, the β-sheet structures present in the β-domain are completely disrupted in both acidic as well as basic pH.

  15. Sensitivity and Uncertainty Study for Thermal Molten Salt Reactors

    Science.gov (United States)

    Bidaud, Adrien; Ivanona, Tatiana; Mastrangelo, Victor; Kodeli, Ivo

    2006-04-01

    The Thermal Molten Salt Reactor (TMSR) using the thorium cycle can achieve the GEN IV objectives of economy, safety, non-proliferation and durability. Its low production of higher actinides, coupled with its breeding capabilities - even with a thermal spectrum - are very valuable characteristics for an innovative reactor. Furthermore, the thorium cycle is more flexible than the uranium cycle since only a small fissile inventory (Molten Salt Breeder Reactor (MSBR). The MSBR concept was developed at Oak Ridge National Laboratory (ORNL) in the 1970's based on the Molten Salt Reactor Experiment (MSRE). The main goals of our current studies are to achieve a reactor concept that enables breeding, improved safety and having chemical reprocessing needs reduced and simplified as much as reasonably possible. The neutronic properties of the new TMSR concept are presented in this paper. As the temperature coefficient is close to zero, we will see that the moderation ratio cannot be chosen to simultaneously achieve a high breeding ratio, long graphite lifetime and low uranium inventory. It is clear that any safety margin taken due to uncertainty in the nuclear data will significantly reduce the capability of this concept, thus a sensitivity analysis is vital to propose measurements which would allow to reduce at present high uncertainties in the design parameters of this reactor. Two methodologies, one based on OECD/NEA deterministic codes and one on IPPE (Obninsk) stochastic code, are compared for keff sensitivity analysis. The uncertainty analysis of keff using covariance matrices available in evaluated files has been performed. Furthermore, a comparison of temperature coefficient sensitivity profiles is presented for the most important reactions. These results are used to review the nuclear data needs for the TMSR thorium fuelled reactor.

  16. Metal-carbide multilayers for molten Pu containment

    International Nuclear Information System (INIS)

    Summers, T.S.E.; Curtis, P.G.; Juntz, R.S.; Krueger, R.L.

    1991-12-01

    Multilayers composed of nine or ten alternating layers of Ta or W and TaC were studied for the feasibility of their use in containing molten plutonium (Pu) at 1200 degrees C. Single layers of W and TaC were also investigated. A two-source electron beam evaporation process was developed to deposit these coatings onto the inside surface of hemispherical Ta cups about 38 mm in diameter. Pu testing was done by melting Pu in the coated hemispherical cups and holding them under vacuum at 1200 degrees C for two hours. Metallographic examination and microprobe analysis of cross sections showed that Pu had penetrated to the Ta substrate in all cases to some extent. Full penetration to the outer surface of the Ta substrate, however, occurred in only a few of the samples. The fact that full penetration occurred in any of the samples suggests that it would have occurred in uncoated Ta under these testing conditions which in turn suggests that the multilayer coatings do afford some protection against Pu attack. The TaC used for these specimens was wet by Pu under these testing conditions, and following testing, Pu was found uniformly distributed throughout the carbide layers which appeared to be rather porous. Pu was seen in the W and Ta layers only when exposed directly to molten Pu during testing or near defects suggesting that Pu penetrated the multilayers at defects in the coating and traveled parallel to the layers along the carbide layers. These results indicate that the use of alternating metal and ceramic layers for Pu containment should be possible through the use of nonporous ceramic that is not wet by molten Pu and defect-free films

  17. Molten salt reactors: A new beginning for an old idea

    International Nuclear Information System (INIS)

    LeBlanc, David

    2010-01-01

    Molten salt reactors have seen a marked resurgence of interest over the past decade, highlighted by their inclusion as one of six Generation IV reactor types. The most active development period however was between the mid 1950s and early 1970s at Oak Ridge National Laboratories (ORNL) and any new re-examination of this concept must bear in mind the far different priorities then in place. High breeding ratios and short doubling times were paramount and this guided the evolution of the Molten Salt Breeder Reactor (MSBR) program. As the inherent advantages of the molten salt concept have become apparent to an increasing number of researchers worldwide it is important to not simply look to continue where ORNL left off but to return to basics in order to offer the best design using updated goals and abilities. A major potential change to the traditional Single Fluid, MSBR design and a subject of this presentation is a return to the mode of operation that ORNL proposed for the majority of its MSR program. That being the Two Fluid design in which separate salts are used for fissile 233 UF 4 and fertile ThF 4 . Oak Ridge abandoned this promising route due to what was known as the 'plumbing problem'. It will be shown that a simple yet crucial modification to core geometry can solve this problem and enable the many advantages of the Two Fluid design. In addition, another very promising route laid out by ORNL was simplified Single Fluid converter reactors that could obtain far superior lifetime uranium utilization than LWR or CANDU without the need for any fuel processing beyond simple chemistry control. Updates and potential improvements to this very attractive concept will also be explored.

  18. Regulatory reform of Finnish environmental policy

    Energy Technology Data Exchange (ETDEWEB)

    Sairinen, R.

    2000-07-01

    used and developed not because of common strategy, but because of the desire to experiment (voluntary agreements), situational power relations (carbon taxation) or international pressures (EIA Act). However, during the 1990s, the environmental governing systems and modes have changed significantly in Finland. The EU membership, deregulation, the limitations of 'command and control' instruments as well as new administrative cultures have created permanent pressures for the advancement of regulatory reform.

  19. Ecological tax reform

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-12-31

    An environmental tax reform is seen by many as a possible solution to some crucial problems of modern society - pollution, excessive resource consumption and unemployment. Changes in the system of taxation are here seen as a long term process, one that must cheapen the costs of labour and make the costs of resource use more expensive - a process which can also create major changes in our society as to conceptions of quality, work, consumption etc. The conference presented proposals for an ecological tax and duty system that would contribute to: Changing technology so that it becomes more resource and energy effective. Changing the economic mechanisms so that resource consumption and pollution become more expensive while human resources become cheaper. Changing personal life styles and values so that material consumption becomes less decisive for our choices and priorities. An environmental tax reform is neither without problems nor painless. An economy and an industrial sector based on increasing consumption of energy and raw materials will, in the long run, lead to drawbacks that far outweigh those that are connected with an economic re-orientation whose driving force is another conception of nature. (EG)

  20. Land Reform : Reconcentration Risks

    Directory of Open Access Journals (Sweden)

    Gilda Diniz dos Santos

    2016-10-01

    Full Text Available The Agrarian Reform, from the 1988 Federal Constitution, is premised on state intervention in private property in the event of breach of the property social function and the consequent allocation of such areas for the landless rural workers, making it beneficiaries of agricultural policy. The need for intervention arises especially evil and historical land concentration in Brazil, which favored the existence and maintenance of a class of landless laborers, with no room to work and production, even though subsistence. After state intervention and from the creation of the settlement project, a number of public policies implemented by INCRA - National Institute of Colonization and Agrarian Reform, such as credits and technical assistance. It has been provided in the Constitution titration of such beneficiaries, however, in 2014, it was promulgated and publicized the Law 13,001, which will implement a massive policy titration, which will lead the transfer of public assets to the private and in consequence the alternative this particular also sell to third parties, which brings the unwanted possibility of re-concentration.

  1. Small School Reform

    Directory of Open Access Journals (Sweden)

    Carroll E. Bronson

    2013-05-01

    Full Text Available This qualitative ethnographic case study explored the evolution of a public urban high school in its 3rd year of small school reform. The study focused on how the high school proceeded from its initial concept, moving to a small school program, and emerging as a new small high school. Data collection included interviews, observations, and document review to develop a case study of one small high school sharing a multiplex building. The first key finding, “Too Many Pieces, Not Enough Glue,” revealed that the school had too many new programs starting at once and they lacked a clear understanding of their concept and vision for their new small school, training on the Montessori philosophies, teaching and learning in small schools, and how to operate within a teacher-cooperative model. The second key finding, “A Continuous Struggle,” revealed that the shared building space presented problems for teachers and students. District policies remain unchanged, resulting in staff and students resorting to activist approaches to get things done. These findings offer small school reform leaders suggestions for developing and sustaining a small school culture and cohesion despite the pressures to revert back to top-down, comprehensive high school norms.

  2. Ecological tax reform

    International Nuclear Information System (INIS)

    1996-01-01

    An environmental tax reform is seen by many as a possible solution to some crucial problems of modern society - pollution, excessive resource consumption and unemployment. Changes in the system of taxation are here seen as a long term process, one that must cheapen the costs of labour and make the costs of resource use more expensive - a process which can also create major changes in our society as to conceptions of quality, work, consumption etc. The conference presented proposals for an ecological tax and duty system that would contribute to: Changing technology so that it becomes more resource and energy effective. Changing the economic mechanisms so that resource consumption and pollution become more expensive while human resources become cheaper. Changing personal life styles and values so that material consumption becomes less decisive for our choices and priorities. An environmental tax reform is neither without problems nor painless. An economy and an industrial sector based on increasing consumption of energy and raw materials will, in the long run, lead to drawbacks that far outweigh those that are connected with an economic re-orientation whose driving force is another conception of nature. (EG)

  3. Pension Reform in China.

    Science.gov (United States)

    Liu, Tao; Sun, Li

    2016-01-01

    This article analyzes China's pension arrangement and notes that China has recently established a universal non-contributory pension plan covering urban non-employed workers and all rural residents, combined with the pension plan covering urban employees already in place. Further, in the latest reform, China has discontinued the special pension plan for civil servants and integrated this privileged welfare class into the urban old-age pension insurance program. With these steps, China has achieved a degree of universalism and integration of its pension arrangement unprecedented in the non-Western world. Despite this radical pension transformation strategy, we argue that the current Chinese pension arrangement represents a case of "incomplete" universalism. First, its benefit level is low. Moreover, the benefit level varies from region to region. Finally, universalism in rural China has been undermined due to the existence of the "policy bundle." Additionally, we argue that the 2015 pension reform has created a situation in which the stratification of Chinese pension arrangements has been "flattened," even though it remains stratified to some extent.

  4. Education Finance Reform in Tennessee.

    Science.gov (United States)

    Green, Harry A.

    1999-01-01

    The Education Improvement Act instigated funding allocation reform, equalization and equity, system accountability, systemwide report cards, value-added assessment, and governance reform. The most dissatisfied educators are those in large, wealthier urban systems. Horizontal equity, accountability, and test results have improved throughout the…

  5. Reforming Teacher Education in Tanzania

    Science.gov (United States)

    Hardman, Frank; Abd-Kadir, Jan; Tibuhinda, Audax

    2012-01-01

    It is widely acknowledged that in order to improve the quality of education in primary schools in developing countries there is a need to place pedagogy and its training implications at the centre of teacher education reform. Like many countries in Eastern and Southern Africa, Tanzania has introduced various initiatives and reforms to improve the…

  6. Local Tax Reform in Pennsylvania.

    Science.gov (United States)

    Hartman, William T.

    This report reviews local tax reform and describes an approach to simulating the effects of proposed tax reform on local school districts in Pennsylvania. The microcomputer spreadsheet simulation led to the development of a model able to meet the feasibility criteria established for such a simulation model. The model was designed to input…

  7. Tax Reform and Environmental Taxation

    OpenAIRE

    Gilbert E. Metcalf

    2005-01-01

    I measure the industry impacts of an environmental tax reform where a carbon tax is used to finance full or partial corporate tax integration. I find that the industry impacts of such a reform are likely to be modest (in the sense of impacts on returns on equity).

  8. George's Complaint: Reforming the Dragon

    Science.gov (United States)

    Buxton, Bruce

    2007-01-01

    The evangelical tone and history of American culture has long been identified as a force for anti-intellectualism. The metaphors of educational reform are a demonstration of how this plays out. The very nature of the positivist social science research used to support proposed reform is anti-intellectual and feeds a debate that favors extremes over…

  9. Free Speech and Campaign Reform.

    Science.gov (United States)

    Sharp, Harry, Jr.

    The Federal Election Campaign Act of 1971, a political campaign reform measure, was enacted to limit campaign contributions and independent expenditures, to mandate disclosure of contributors, and to establish public financing of campaigns, all to minimize the opportunity for political corruption. Unfortunate implications of such reform on the…

  10. The Danish Regulatory Reform of Telecommunications

    DEFF Research Database (Denmark)

    Skouby, Knud Erik

    1998-01-01

    An overview of the liberalisation process and regulatory reform of telecommunications in Denmark......An overview of the liberalisation process and regulatory reform of telecommunications in Denmark...

  11. Implementing Comprehensive Reform: Implications for Practice

    Science.gov (United States)

    Stout, Karen A.

    2016-01-01

    This chapter describes the challenges and practical barriers community colleges face when implementing comprehensive reform, exploring how reforms are leading to some improvements but not often scaled improvements.

  12. Implementing Lean Health Reforms in Saskatchewan

    Directory of Open Access Journals (Sweden)

    Greg Marchildon

    2013-07-01

    Full Text Available Saskatchewan has gone further than any other Canadian province in implementing health system process improvements using Lean, a production line discipline that originated with the automobile industry. The goal of the Lean reform is to reduce waste and improve quality and overall health system performance by long-term changes in behaviour. Lean enjoys a privileged position on the provincial government’s agenda because of the policy’s championing by the Deputy Minister of Health and the policy’s fit with the government’s patient-centred care agenda. The implementation of reform depends on a major investment of time in the training and Lean-certification of key leaders and managers in the provincial health system. The Saskatchewan Union of Nurses, the union representing the single largest group of health workers in the province, has agreed to co-operate with the provincial government in implementing Lean-type reforms. Thus far, the government has had limited independent evaluation of Lean while internal evaluations claim some successes.

  13. Local coordination of polyvalent metal ions in molten halide mixtures

    International Nuclear Information System (INIS)

    Akdeniz, Z.; Tosi, M.P.

    1989-07-01

    Ample experimental evidence is available in the literature on the geometry and the stability of local coordination for polyvalent metal ions in molten mixtures of their halides with alkali halides. Recent schemes for classifying this evidence are discussed. Dissociation of tetrahedral halocomplexes in good ionic systems can be viewed as a classical Mott problem of bound-state stability in a conducting matrix. More generally, structural coordinates can be constructed from properties of the component elements, to separate out systems with long-lived fourfold or sixfold coordination and to distinguish between these. (author). 11 refs, 1 fig

  14. Energy Dissipation Rate in an Agitated Crucible Containing Molten Metal

    Science.gov (United States)

    Li, Tao; Shimasaki, Shin-ichi; Narita, Shunsuke; Taniguchi, Shoji

    2017-10-01

    The energy dissipation rate (EDR) is an important parameter for characterizing the behavior of inclusion coagulation in agitated molten metal. To clarify the inclusion coagulation mechanism, we review previous water model studies by particularly focusing on the relation between the impeller torque and the EDR of the fluid, which indicates the ratio of energy dissipated in the viscous medium to the energy inputted by the rotating impeller. In the present study, simulations coupled with experiments were performed to determine the relation between the torque and the effective EDR for water and liquid Al in crucibles with and without baffles.

  15. Precipitation of lamellar gold nanocrystals in molten polymers

    Science.gov (United States)

    Palomba, M.; Carotenuto, G.

    2016-05-01

    Non-aggregated lamellar gold crystals with regular shape (triangles, squares, pentagons, etc.) have been produced by thermal decomposition of gold chloride (AuCl) molecules in molten amorphous polymers (polystyrene and poly(methyl methacrylate)). Such covalent inorganic gold salt is high soluble into non-polar polymers and it thermally decomposes at temperatures compatible with the polymer thermal stability, producing gold atoms and chlorine radicals. At the end of the gold precipitation process, the polymer matrix resulted chemically modified because of the partial cross-linking process due to the gold atom formation reaction.

  16. CAPTURING EXHAUST CO2 GAS USING MOLTEN CARBONATE FUEL CELLS

    Directory of Open Access Journals (Sweden)

    Prateek Dhawan

    2016-03-01

    Full Text Available Carbon dioxide is considered as one of the major contenders when the question of greenhouse effect arises. So for any industry or power plant it is of utmost importance to follow certain increasingly stringent environment protection rules and laws. So it is significant to keep eye on any possible methods to reduce carbon dioxide emissions in an efficient way. This paper reviews the available literature so as to try to provide an insight of the possibility of using Molten Carbonate Fuel Cells (MCFCs as the carbon capturing and segregating devices and the various factors that affect the performance of MCFCs during the process of CO2 capture.

  17. Fission product behavior in the Molten Salt Reactor Experiment

    International Nuclear Information System (INIS)

    Compere, E.L.; Kirslis, S.S.; Bohlmann, E.G.; Blankenship, F.F.; Grimes, W.R.

    1975-10-01

    Essentially all the fission product data for numerous and varied samples taken during operation of the Molten Salt Reactor Experiment or as part of the examination of specimens removed after particular phases of operation are reported, together with the appropriate inventory or other basis of comparison, and relevant reactor parameters and conditions. Fission product behavior fell into distinct chemical groups. Evidence for fission product behavior during operation over a period of 26 months with 235 U fuel (more than 9000 effective full-power hours) was consistent with behavior during operation using 233 U fuel over a period of about 15 months (more than 5100 effective full-power hours)

  18. All ceramic structure for molten carbonate fuel cell

    Science.gov (United States)

    Smith, James L.; Kucera, Eugenia H.

    1992-01-01

    An all-ceramic molten carbonate fuel cell having a composition formed of a multivalent metal oxide or oxygenate such as an alkali metal, transition metal oxygenate. The structure includes an anode and cathode separated by an electronically conductive interconnect. The electrodes and interconnect are compositions ceramic materials. Various combinations of ceramic compositions for the anode, cathode and interconnect are disclosed. The fuel cell exhibits stability in the fuel gas and oxidizing environments. It presents reduced sealing and expansion problems in fabrication and has improved long-term corrosion resistance.

  19. Concept of an electron accelerator driven molten salt subcritical reactor

    International Nuclear Information System (INIS)

    Brolly, A.; Vertes, P.

    2005-01-01

    Concept and analysis of an electron accelerator driven molten salt subcritical system are presented. The analysis covers the neutron source optimization and burnup history with continuous feeding of TRU into the reactor. Effect of long time operation on TRU consumption and corresponding energy production is considered. It seems that with an electron accelerator of 150 MeV energy and with technically acceptable current it is possible to maintain a subcritical reactor on a reasonable power level while it consumes considerable amount of TRU coming from online chemical processing of spent fuels. (authors)

  20. Neutron scattering on molten Ge-Sn-Te alloys

    Science.gov (United States)

    Halm, Th; Hinz, W.; Hoyer, W.

    1995-01-01

    Three molten ternary Ge-Sn-Te alloys lying on the quasibinary line Ge-SnTe, and the binary equiatomic alloys SnTe and GeTe have been investigated by neutron "time-of-flight" experiments. Published thermodynamic results are interpreted in terms of the coexistence of SnTe and Ge microgroupings in the melt. Using the experimental obtained data of the binary liquid alloy Sn50Te50 and of liquid Ge the structure factors of the ternary melts are calculated on the base of a microheterogeneous model.

  1. Recovery of protactinium from molten fluoride nuclear fuel compositions

    Science.gov (United States)

    Baes, C.F. Jr.; Bamberger, C.; Ross, R.G.

    1973-12-25

    A method is provided for separating protactinium from a molten fluonlde salt composition consisting essentially of at least one alkali and alkaline earth metal fluoride and at least one soluble fluoride of uranium or thorium which comprises oxidizing the protactinium in said composition to the + 5 oxidation state and contacting said composition with an oxide selected from the group consisting of an alkali metal oxide, an alkaline earth oxide, thorium oxide, and uranium oxide, and thereafter isolating the resultant insoluble protactinium oxide product from said composition. (Official Gazette)

  2. SYNTHESIS OF ALUMINIUM BORATE WHISKERS THROUGH WET MOLTEN SALT METHOD

    Directory of Open Access Journals (Sweden)

    Xue Zhang

    2017-12-01

    Full Text Available Aluminium borate (Al₄B₂O₉ whiskers were successfully synthesized by the wet molten salt method at 800 oC through control the aluminum/boron atomic ratio and synthesis temperature. The as-received Al₄B₂O₉ whiskers were characterized by scanning electron microscopy (SEM, X-ray diffraction (XRD and thermal analysis. A solution-liquid-solid (SLS mechanism was proposed for the growth mechanism of the whiskers on the basis of the experimental phenomena and the TG-DSC data of the mixed raw materials.

  3. Concentratin fluctuations and ionic core polarization in molten salt mixtures

    International Nuclear Information System (INIS)

    Akdeniz, Z.; Senatore, G.; Tose, M.P.

    1980-09-01

    The activity coefficient and the heat of mixing of molten alkali-halide mixtures with a common ion are analyzed through the use of thermodynamic fluctuation theory and of a charged-hard-spheres model for the ionic interactions. A strain contribution is isolated and evaluated with the help of experimental data, and a Coulomb contribution is estimated within the mean spherical approximation. The difference between these contributions and experiment is attributed to electronic polarizability of the ionic cores by displaying its correlation with appropriate polarization parameters. (author)

  4. Molten LWR core material interactions with water and with concrete

    International Nuclear Information System (INIS)

    Dahlgren, D.A.; Buxton, L.D.; Muir, J.F.; Murfin, W.B.; Nelson, L.S.; Powers, D.A.

    1977-01-01

    Nuclear power reactors are designed and operated to minimize the possibility of fuel melting. Nevertheless, in order to assess the risks associated with reactor operation, a realistic assessment is required for postulated accident sequences in which melting occurs. To investigate the experimental basis of the fuel melt accident analyses, a comprehensive review was performed at Sandia Laboratories. The results of that study indicated several phenomenological areas where additional experimental data should be gathered to verify common assumptions made in risk studies. In particular, vapor explosions and molten core material/concrete interactions were identified for further study. Results of these studies are presented

  5. Strategic planning for molten carbonate fuel cell development and commercialization

    Science.gov (United States)

    Williams, M. C.; Mayfield, M. J.

    The molten carbonate fuel cell (MCFC), a high-temperature fuel cell, is a promising energy conversion product for generating electricity. Natural gas availability appears to play a key role in MCFC commercialization; natural gas MCFC and Integrated Gasification MCFC (IGMCFC) are emerging power generation options that are responsive to requirements of Clean Air Act amendments and to guidance in National Energy Strategy. Goal of DOE IGMCFC program is to demonstrate the commercial readiness of this technology by the year 2010. DOE MCFC development objectives and planned activities are outlined.

  6. Polymer Coated Electrodes in Ambient Temperature Molten Salts.

    Science.gov (United States)

    1983-08-01

    PERFORMING ORG. REPORT NUMBER ~7. AUTHOR(*) S. CONTRACT OR GRANT NuMBER(a) P.G. Pickup and Robert A. Osteryoung N00014-79-C-0682 9. PERFORMING ORGANIZATION...glassy carbon ..-r electrodes in various compositions of the am- blent temperature molten salt system aluminum 00 6 ov chloride:n-butylpyridinium...Or TrVT AJf A I I START SECO:REFERENCES N HERE. 1. R. W. Murray, ’Chemically Modified Elect- rodes", Chapter 3 in Electroanalytical Chemistry, Vol. 13

  7. Optical absorption of dilute solutions of metals in molten salts

    Energy Technology Data Exchange (ETDEWEB)

    Senatore, G.; Parrinello, M.; Tosi, M.P. (Trieste Univ. (Italy). Ist. di Fisica Teorica; Gruppo Nazionale di Struttura dell material del CNR, Trieste (Italy); International Centre for Theoretical Physics, Trieste (Italy))

    1978-12-23

    The theory of liquid structure for fluids of charged hard spheres is applied to an evaluation of the F-centre model for valence electrons in metal-molten salt solutions at high dilution. Minimization of the free energy yields the groundstate radius of the elctron bubble and hence the optical excitation energy in a Franck-Condon transition, the shift and broadening of the transition due to fluctuations in the bubble radius, the volume of mixing, and the activity of the salt in the solution.

  8. Transmutation and inventory analysis in an ATW molten salt system

    Energy Technology Data Exchange (ETDEWEB)

    Sisolak, J.E.; Truebenbach, M.T.; Henderson, D.L. [Univ. of Wisconsin, Madison, WI (United States)

    1995-10-01

    As an extension of earlier work to determine the equilibrium state of an ATW molten salt, power producing, reactor/transmuter, the WAIT code provides a time dependent view of material inventories and reactor parameters. By considering several cases, the authors infer that devices of this type do not reach equilibrium for dozens of years, and that equilibrium design calculations are inapplicable over most of the reactor life. Fissile inventory and k{sub eff} both vary by factors of 1.5 or more between reactor startup and ultimate convergence to equilibrium.

  9. Solid-electrolyte oxide-ion electrode for molten nitrates

    Energy Technology Data Exchange (ETDEWEB)

    Nissen, D.A.

    1981-10-01

    An oxide ion sensitive electrode of the type Pb, PbO/ZrO/sub 2/(Y/sub 2/O/sub 3/)// was constructed and its performance tested in the binary, equimolar molten salt NaNO/sub 3/-KNO/sub 3/ over the temperature range 336 to 350/sup 0/C. The response of this electrode to oxide ion concentrations over the range 10/sup -6/ to 10/sup -10/ moles/kg is linearly dependent upon log (0/sup =/), and dE/dlog(0/sup =/) corresponds to a two-electron process.

  10. Molten salt/metal extractions for recovery of transuranic elements

    International Nuclear Information System (INIS)

    Chow, L.S.; Basco, J.K.; Ackerman, J.P.; Johnson, T.R.

    1992-01-01

    The integral fast reactor (EFR) is an advanced reactor concept that incorporates metallic driver and blanket fuels, an inherently safe, liquid-sodium-cooled, pool-type, reactor design, and on-site pyrochemical reprocessing (including electrorefining) of spent fuels and wastes. This paper describes a pyrochemical method that is being developed at Argonne National Laboratory to recover transuranic elements from the EFR electrorefiner process salt. The method uses multistage extractions between molten chloride salts and cadmium metal at high temperatures. The chemical basis of the salt extraction method, the test equipment, and a test plan are discussed

  11. Diffusion Welding of Alloys for Molten Salt Service - Status Report

    Energy Technology Data Exchange (ETDEWEB)

    Denis Clark; Ronald Mizia

    2012-05-01

    The present work is concerned with heat exchanger development for molten salt service, including the proposed molten salt reactor (MSR), a homogeneous reactor in which the fuel is dissolved in a circulating fluid of molten salt. It is an outgrowth of recent work done under the Next Generation Nuclear Plant (NGNP) program; what the two reactor systems have in common is an inherently safe nuclear plant with a high outlet temperature that is useful for process heat as well as more conventional generation The NGNP program was tasked with investigating the application of a new generation of nuclear power plants to a variety of energy needs. One baseline reactor design for this program is a high temperature, gas-cooled reactor (HTGR), which provides many options for energy use. These might include the conventional Rankine cycle (steam turbine) generation of electricity, but also other methods: for example, Brayton cycle (gas turbine) electrical generation, and the direct use of the high temperatures characteristic of HTGR output for process heat in the chemical industry. Such process heat is currently generated by burning fossil fuels, and is a major contributor to the carbon footprint of the chemical and petrochemical industries. The HTGR, based on graphite fuel elements, can produce very high output temperatures; ideally, temperatures of 900 C or even greater, which has significant energy advantages. Such temperatures are, of course, at the frontiers of materials limitations, at the upper end of the performance envelope of the metallic materials for which robust construction codes exist, and within the realm of ceramic materials, the fabrication and joining of which, on the scale of large energy systems, are at an earlier stage of development. A considerable amount of work was done in the diffusion welding of materials of interest for HTGR service with alloys such as 617 and 800H. The MSR output temperature is also materials limited, and is projected at about 700 C

  12. Diffusion Welding of Alloys for Molten Salt Service - Status Report

    Energy Technology Data Exchange (ETDEWEB)

    Denis Clark; Ronald Mizia; Piyush Sabharwall

    2012-09-01

    The present work is concerned with heat exchanger development for molten salt service, including the proposed molten salt reactor (MSR), a homogeneous reactor in which the fuel is dissolved in a circulating fluid of molten salt. It is an outgrowth of recent work done under the Next Generation Nuclear Plant (NGNP) program; what the two reactor systems have in common is an inherently safe nuclear plant with a high outlet temperature that is useful for process heat as well as more conventional generation The NGNP program was tasked with investigating the application of a new generation of nuclear power plants to a variety of energy needs. One baseline reactor design for this program is a high temperature, gas-cooled reactor (HTGR), which provides many options for energy use. These might include the conventional Rankine cycle (steam turbine) generation of electricity, but also other methods: for example, Brayton cycle (gas turbine) electrical generation, and the direct use of the high temperatures characteristic of HTGR output for process heat in the chemical industry. Such process heat is currently generated by burning fossil fuels, and is a major contributor to the carbon footprint of the chemical and petrochemical industries. The HTGR, based on graphite fuel elements, can produce very high output temperatures; ideally, temperatures of 900 °C or even greater, which has significant energy advantages. Such temperatures are, of course, at the frontiers of materials limitations, at the upper end of the performance envelope of the metallic materials for which robust construction codes exist, and within the realm of ceramic materials, the fabrication and joining of which, on the scale of large energy systems, are at an earlier stage of development. A considerable amount of work was done in the diffusion welding of materials of interest for HTGR service with alloys such as 617 and 800H. The MSR output temperature is also materials limited, and is projected at about 700

  13. Molten material relocation into the lower plenum: a status report

    International Nuclear Information System (INIS)

    1998-09-01

    This report, prepared by the task group 'Degraded Core Cooling' (DCC) for the CSNI, summarizes the experimental and theoretical knowledge of molten material relocation from a degraded core to the lower plenum of the reactor vessel under the main severe accident scenarios envisaged for both PWRs and BWRs, and boundary conditions. Consequences of movement of material to the lower head are considered with respect to the potential for reactor pressure vessel failure. The following models are reviewed: SCDAP/RELAP5, ICARE/CATHARE, ATHLET-CD/KESS, MELCOR, MAAP4, ESCADRE, etc.

  14. Corrosion-Resistant Container for Molten-Material Processing

    Science.gov (United States)

    Stern, Theodore G.; McNaul, Eric

    2010-01-01

    In a carbothermal process, gaseous methane is passed over molten regolith, which is heated past its melting point to a temperature in excess of 1,625 C. At this temperature, materials in contact with the molten regolith (or regolith simulant) corrode and lose their structural properties. As a result, fabricating a crucible to hold the molten material and providing a method of contact heating have been problematic. Alternative containment approaches use a large crucible and limit the heat zone of the material being processed, which is inefficient because of volume and mass constraints. Alternative heating approaches use non-contact heating, such as by laser or concentrated solar energy, which can be inefficient in transferring heat and thus require higher power heat sources to accomplish processing. The innovation is a combination of materials, with a substrate material having high structural strength and stiffness and high-temperature capability, and a coating material with a high corrosion resistance and high-temperature capability. The material developed is a molybdenum substrate with an iridium coating. Creating the containment crucible or heater jacket using this material combination requires only that the molybdenum, which is easily processed by conventional methods such as milling, electric discharge machining, or forming and brazing, be fabricated into an appropriate shape, and that the iridium coating be applied to any surfaces that may come in contact with the corrosive molten material. In one engineering application, the molybdenum was fashioned into a container for a heat pipe. Since only the end of the heat pipe is used to heat the regolith, the container has a narrowing end with a nipple in which the heat pipe is snugly fit, and the external area of this nipple, which contacts the regolith to transfer heat into it, is coated with iridium. At the time of this reporting, no single material has been found that can perform the functions of this combination

  15. Large longitude libration of Mercury reveals a molten core.

    Science.gov (United States)

    Margot, J L; Peale, S J; Jurgens, R F; Slade, M A; Holin, I V

    2007-05-04

    Observations of radar speckle patterns tied to the rotation of Mercury establish that the planet occupies a Cassini state with obliquity of 2.11 +/- 0.1 arc minutes. The measurements show that the planet exhibits librations in longitude that are forced at the 88-day orbital period, as predicted by theory. The large amplitude of the oscillations, 35.8 +/- 2 arc seconds, together with the Mariner 10 determination of the gravitational harmonic coefficient C22, indicates that the mantle of Mercury is decoupled from a core that is at least partially molten.

  16. 26 CFR 1.267(a)-2T - Temporary regulations; questions and answers arising under the Tax Reform Act of 1984 (temporary).

    Science.gov (United States)

    2010-04-01

    ... arising under the Tax Reform Act of 1984 (temporary). 1.267(a)-2T Section 1.267(a)-2T Internal Revenue... Not Deductible § 1.267(a)-2T Temporary regulations; questions and answers arising under the Tax Reform...) take into account changes made to section 267(b) by section 174 of the Tax Reform Act of 1984 (without...

  17. Abortion law reform in Nepal.

    Science.gov (United States)

    Upreti, Melissa

    2014-08-01

    Across four decades of political and social action, Nepal changed from a country strongly enforcing oppressive abortion restrictions, causing many poor women's long imprisonment and high rates of abortion-related maternal mortality, into a modern democracy with a liberal abortion law. The medical and public health communities supported women's rights activists in invoking legal principles of equality and non-discrimination as a basis for change. Legislative reform of the criminal ban in 2002 and the adoption of an Interim Constitution recognizing women's reproductive rights as fundamental rights in 2007 inspired the Supreme Court in 2009 to rule that denial of women's access to abortion services because of poverty violated their constitutional rights. The government must now provide services under criteria for access without charge, and services must be decentralized to promote equitable access. A strong legal foundation now exists for progress in social justice to broaden abortion access and reduce abortion stigma. Copyright © 2014 International Federation of Gynecology and Obstetrics. Published by Elsevier Ireland Ltd. All rights reserved.

  18. Reforming the Tax Mix in Canada

    Directory of Open Access Journals (Sweden)

    Bev Dahlby

    2012-04-01

    Full Text Available Periodically, tax systems need major reforms to remove the “barnacles” that accumulate under the short-term pressures of political expediency and to adapt to the long-term forces of technological and economic change. The current fiscal and economic problems that confront the provinces require an assessment of much-needed reforms. Raising tax revenue imposes large costs on our society, not only because of the administration and compliance costs of collecting taxes, but because taxes distort economic decisions in the private sector. This is especially true of provincial corporate income taxes. Taxing highly mobile corporate capital and corporate profits encourages firms to shift their investments and profits across provincial and international boundaries. The provinces would enjoy significant boosts to economic growth and efficiency gains by enacting a revenue-neutral switch from corporate to sales or personal income taxes. For Alberta, such a shift would yield up to $40 per dollar of tax revenue shifted from corporate to personal income taxes; for fiscal year 2011-12, this would amount to a percapita welfare gain of roughly $19,000. Other options for tax reform are also discussed in this paper, including the adoption of a penny tax to the GST to fund infrastructure spending by municipalities. However, we think this would saddle the private sector with significant compliance costs and create major economic distortions between neighbouring municipalities by creating an incentive to shop where the penny tax proposal was not adopted. In surveying the most pressing tax reform issues facing Canada, we offer policymakers a firm basis for coming to grips with them, so they can treat tax dollars with the care and foresight Canadians expect.

  19. Topological switching between an alpha-beta parallel protein and a remarkably helical molten globule.

    NARCIS (Netherlands)

    Nabuurs, S.M.; Westphal, A.H.; Toorn, M. aan den; Lindhoud, S.; Mierlo, C.P. van

    2009-01-01

    Partially folded protein species transiently exist during folding of most proteins. Often these species are molten globules, which may be on- or off-pathway to native protein. Molten globules have a substantial amount of secondary structure but lack virtually all the tertiary side-chain packing

  20. Topological switching between an a-ß parallel protein and a remarkably helical molten globule.

    NARCIS (Netherlands)

    Nabuurs, S.M.; Westphal, A.H.; Toorn, aan den M.; Lindhoud, S.; Mierlo, van C.P.M.

    2009-01-01

    Partially folded protein species transiently exist during folding of most proteins. Often these species are molten globules, which may be on- or off-pathway to native protein. Molten globules have a substantial amount of secondary structure but lack virtually all the tertiary side-chain packing