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Sample records for internal gelation process

  1. Experimental Methodology for Determining Optimum Process Parameters for Production of Hydrous Metal Oxides by Internal Gelation

    Energy Technology Data Exchange (ETDEWEB)

    Collins, J.L.

    2005-10-28

    The objective of this report is to describe a simple but very useful experimental methodology that was used to determine optimum process parameters for preparing several hydrous metal-oxide gel spheres by the internal gelation process. The method is inexpensive and very effective in collection of key gel-forming data that are needed to prepare the hydrous metal-oxide microspheres of the best quality for a number of elements.

  2. Preparation of UN microspheres by internal gelation process

    Energy Technology Data Exchange (ETDEWEB)

    Shirasu, Yoshiro; Yamagishi, Shigeru [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment

    1997-07-01

    UN microspheres were prepared from (UO{sub 3}+C) microspheres internally gelled in a hot silicone oil column. The gel microspheres were calcined at 480degC in nitrogen, after washing and drying. The calcined ones were carbothermically nitrided at 1400-1800degC in a nitrogen-based atmosphere in two ways: one in N{sub 2} followed by N{sub 2}-8%H{sub 2}, and the other in N{sub 2}-8%H{sub 2} only. In both cases, highly pure UN microspheres around 500 ppm of both oxygen and carbon impurities were obtained, although their densities were still low. (author)

  3. Determination of Ideal Broth Formulations Needed to Prepare Hydrous Cerium Oxide Microspheres via the Internal Gelation Process

    Energy Technology Data Exchange (ETDEWEB)

    Collins, Jack Lee [ORNL; Chi, Anthony [ORNL

    2009-02-01

    A simple test tube methodology was used to determine optimum process parameters for preparing hydrous cerium oxide microspheres via the internal gelation process.1 Broth formulations of cerium ammonium nitrate [(NH4)2Ce(NO3)6], hexamethylenetetramine, and urea were found that can be used to prepare hydrous cerium oxide gel spheres in the temperature range of 60 to 90 C. A few gel-forming runs were made in which microspheres were prepared with some of these formulations to be able to equate the test-tube gelation times to actual gelation times. These preparations confirmed that the test-tube methodology is reliable for determining the ideal broth formulations.

  4. Preparation of nuclear fuel spheres by flotation-internal gelation

    Science.gov (United States)

    Haas, P.A.; Fowler, V.L.; Lloyd, M.H.

    1984-12-21

    A simplified internal gelation process is claimed for the preparation of gel spheres of nuclear fuels. The process utilizes perchloroethylene as a gelation medium. Gelation is accomplished by directing droplets of a nuclear fuel broth into a moving volume of hot perchloroethylene (about 85/sup 0/C) in a trough. Gelation takes place as the droplets float on the surface of the perchloroethylene and the resultant gel spheres are carried directly into an ager column which is attached to the trough. The aged spheres are disengaged from the perchloroethylene on a moving screen and are deposited in an aqueous wash column. 3 figs.

  5. Uranium kernel formation via internal gelation

    International Nuclear Information System (INIS)

    Hunt, R.D.; Collins, J.L.

    2004-01-01

    In the 1970s and 1980s, U.S. Department of Energy (DOE) conducted numerous studies on the fabrication of nuclear fuel particles using the internal gelation process. These amorphous kernels were prone to flaking or breaking when gases tried to escape from the kernels during calcination and sintering. These earlier kernels would not meet today's proposed specifications for reactor fuel. In the interim, the internal gelation process has been used to create hydrous metal oxide microspheres for the treatment of nuclear waste. With the renewed interest in advanced nuclear fuel by the DOE, the lessons learned from the nuclear waste studies were recently applied to the fabrication of uranium kernels, which will become tri-isotropic (TRISO) fuel particles. These process improvements included equipment modifications, small changes to the feed formulations, and a new temperature profile for the calcination and sintering. The modifications to the laboratory-scale equipment and its operation as well as small changes to the feed composition increased the product yield from 60% to 80%-99%. The new kernels were substantially less glassy, and no evidence of flaking was found. Finally, key process parameters were identified, and their effects on the uranium microspheres and kernels are discussed. (orig.)

  6. UO2 microspheres obtainment through the internal gelation methods

    International Nuclear Information System (INIS)

    Sterba, M.E.; Gomez Constenla, A.

    1987-01-01

    UO 2 microspheres obtainment process through the internal gelation method which allows the spheres' obtainment of uniform size is detailed herein, varying the same among 0.3 and 1.7 mm of diameter. The sintered density reaches 10.78 g/cm 3 , permitting the fuels fabrication dispersed and vibro-compacted fuels. The trichloroethylene use implementation as gelation agent is described, thus reducing the number of stages in the microspheres fabrication. At the same time, the uranium sun composition has been modified so as to be compatible with the use solvent. (Author)

  7. Internal gelation at PSI. The past and the future

    International Nuclear Information System (INIS)

    Pouchon, Manuel A.; Ingold, Franz

    2009-01-01

    The Paul Scherrer Institute used to be very active in fuel fabrication R and D using the internal gelation process, which is a promising production method for spherical nuclear fuel. Such fuel kernels can be directly packed in a cylindrical cladding (a sphere-pac pin), or they can be coated in the TRISO concept. The internal gelation offers several advantages, as it is aqueous up to the forming of the sphere. Consequently, the process is almost dustless, with lower risk of incorporation. The production does not require mechanical and maintenance intensive equipment, as for example presses and grinding machines necessary for pellet type fuel. Especially for low decontaminated fuel coming from aqueous reprocessing, this offers a great advantage, because the production line can easily be handled remotely in a hot cell. In the past, many different fuel matrices were produced and tested at PSI (carbide, nitride and oxide fuels). The paper summarizes the past activities, and some important findings. Furthermore, future perspectives of this concept are shown. These are especially seen in context of Generation IV nuclear systems such as the sodium cooled fast reactor (SFR), the very high temperature reactor (VHTR), and the gas cooled fast reactor (GFR). The paper describes the former production line, which was a classical internal gelation process. Some advantages and disadvantages of this system will be illustrated which lead to a new project at PSI. A silicon oil-free system will be developed over the next years. The oil as a heat carrier is replaced by a cavity, where microwaves act on falling drops and lead to the desired gelation before the spheres drop into a washing solution. The idea of a microwave gelation has already been tested at several laboratories in the past. The paper gives an overview of these activities. Finally the concept of the new production at PSI is introduced. (author)

  8. Diffusion of Acetic Acid Across Oil/Water Interface in Emulsification-Internal Gelation Process for Preparation of Alginate Gel Beads

    Institute of Scientific and Technical Information of China (English)

    LIU Xiu-dong; YU Wei-ting; LIN Jun-zhang; MA Xiao-jun; YUAN Quan

    2007-01-01

    Alginate has been widely used in cell microencapsulation and drug delivery systems in the form of gel beads or microcapsules. Although an alternative novel emulsification-internal gelation technology has been established and both the properties and the potential applications of the beads in drug delivery systems have been studied, the mechanism has not been well understood compared with the traditional droplet method( external gelation technology). On the basis of our previous knowledge that the novel technology is composed of complicatedly consecutive processes with multistep diffusion and re action, and the diffusion of acetic acid across oil/water interface being the prerequisite that determines the occurrence and rate for the reactions and the structures and properties of final produced gel beads, a special emphasis was placed on the diffusion process. With the aid of diffusion modeling and simple experimental design, the diffusion rate constant and diffusion coefficient of acetic acid across oil/water interface were determined to be in the orders of magnitude of 10-6 and 10-16, respectively. This knowledge will be of particular importance in understanding and interpreting the formation, structure of the gel beads and the relationship between the structure and properties and guiding the preparation and quality control of the gel beads.

  9. Preparation of porous zirconia microspheres by internal gelation method

    International Nuclear Information System (INIS)

    Pathak, Sachin S.; Pius, I.C.; Bhanushali, R.D.; Rao, T.V. Vittal; Mukerjee, S.K.

    2008-01-01

    A modified internal gelation process for the preparation of porous zirconia microspheres has been developed. The conventional method has been modified by adding a surfactant in the feed broth. The effects of variation of surfactant concentration, washing techniques and temperature of calcination on the pore volume and the surface area of the microspheres have been studied. The conditions were optimized to obtain porous stable microspheres suitable for various applications. The microspheres were characterized by surface area analysis, pore volume analysis, thermogravimetric analysis and X-ray diffraction. The ion exchange behavior was studied using pH titration

  10. Process and equipment development for the preparation of UO2 microspheres using trichloroethylene as gelation medium (Paper No. AL-23)

    International Nuclear Information System (INIS)

    Suryanarayana, S.; Kumar, N.; Bamankar, Y.R.; Vaidya, V.N.; Sood, D.D.

    1990-02-01

    Uranium dioxide microspheres have been prepared by internal gelation process, one of the sol-gel routes for fuel fabrication. The process flow sheet for internal gelation has been modified by employing trichloroethylene(TCE) as an alternate gelation medium. Based on the modified flow sheet, a 5Kg/day assembly for the production of UO 2 microspheres has been developed and installed. (author). 1 fig

  11. Rotational and translational diffusions of fluorescent probes during gelation process

    Science.gov (United States)

    Hattori, Yusuke; Panizza, Pascal; Letamendia, Louis; Ushiki, Hideharu

    2006-04-01

    Gelation process has been investigated by using light scattering techniques in recent years. We measured both of rotational and translational motions of fluorescent probes during gelation process. The measurements were performed after the temperature quenched at 30 °C. As the results, rotational diffusion coefficient of fluorescein was decreased after 6.0 × 10 4 s and energy transfer rate was reduced after 2.0 × 10 4 s. We sorted the gelation process into the following three parts, (I) pre-gelation, (II) reduction of translational diffusion (aging), and (III) reduction of rotational diffusion with saturating translational diffusion (post-gelation). The time scale of the process was completely different from the results of other methods.

  12. Research of zirconia-based oxide spheres for CERMET fuel. Production through internal gelation process and the compatibility with Zr, Zircaloy-4 and Si

    International Nuclear Information System (INIS)

    Idemitsu, Kazuya; Inagaki, Yaohiro; Arima, Tatsumi

    2003-05-01

    Optimizing of sol-gel processes was carried out for manufacturing of ziroconium based oxide spheres used in CERMET fuels. In addition, compatibility of CERMET fuels was studied. The Zr 0.85-x Y 0.1 Er 0.05 Ce x O 2 (x=0.0-0.2) oxide spheres were made by preparation of suitable starting materials and the dropping method for an internal gelation process, and thorugh suitable drying, calcination and sintering processes. However, further studies were needed for optimizing the sintering condition. About the reaction of YSZ(yttria-stabilized zirconia) with Zr, Zry4 and Si, isothermal heating tests have been done at the temperature range from 800degC to 1150degC for a maximum of 112 days. Some reactions between YSZ and Zr were observed at temperatures ≥1000degC, which means the formation of a metallic reaction layer at the interface between them and the occurrence of meatallic phases inside the YSZ. Similar results were observed for the YSZ-Zry4 (cladding) system. The YSZ and Si were compatible below the temperature of 1000degC. However, above the temperatures, Si attacked YSZ so that the reaction layers formed on the YSZ side. (author)

  13. Control of Urania Crystallite Size by HMTA-Urea Reactions in the Internal Gelation Process for Preparing (U, Pu)O2Fuel Kernels

    Energy Technology Data Exchange (ETDEWEB)

    Collins, J.L.

    2005-04-26

    In the development of (U,Pu)O{sub 2} kernels by the internal gelation process for the Direct Press Spheroidized process at Oak Ridge National Laboratory, a novel crystal growth step was discovered that made it possible to prepare calcined porous kernels that could be used as direct-press feed for Fast Breeder Reactor pellet fabrication. High-quality pellets were prepared that were near theoretical density and that (upon examination) revealed no evidence of sphere remnants. The controlled crystal growth step involved using hexamethylenetetramine (HMTA)-urea stock solutions that were boiled for 60 min or less. Before this discovery, all the other crystal growth steps (when utilized) could reduce the tap density to only {approx}1.3 g/cm{sup 3}, which was not sufficiently low for use in ideal pellet pressing. The use of the boiled HMTA-urea solution allowed the tap density to be lowered to 0.93 g/cm{sup 3}, with the ideal density being about 1.0 g/cm{sup 3}. This report describes the development of this technology and its scaleup.

  14. Chemical flowsheet conditions for preparing urania spheres by internal gelation

    International Nuclear Information System (INIS)

    Haas, P.A.; Begovich, J.M.; Ryon, A.D.; Vavruska, J.S.

    1979-01-01

    Small, ceramic urania spheres can be prepared for use as nuclear fuel by internal chemical gelation of uranyl nitrate solution droplets. Decomposition of hexamethylenetetramine (HMTA) dissolved in the uranyl nitrate solution releases ammonia to precipitate hydrated UO 3 . Previously established flowsheet conditions have been improved and modified at ORNL and have been applied to prepare dense UO 2 spheres with average diameters of 1200, 300, and 30 μm. Acid-deficient uranyl nitrate (ADUN) solutions up to 3.4 M in uranium with NO 3 - /U mole ratios of 1.5 to 1.7 are prepared by dissolution of U 3 O 8 or UO 3 . Continuous mixing of metered, cooled ADUN containing urea and HMTA solutions provides a smooth, regulated flow of the temperature-sensitive feed solution. The gelation times for solution drops in organic liquids at 45 to 95 0 C depend on both the chemical reaction rates and the rates of heat transfer. The gel properties vary with temperature and other gelation variables. Gelation conditions were determined which allow easy washing, drying, firing, and sintering to produce dense UO 2 spheres of all three sizes. The 1200- and 300-μm UO 2 spheres were pepared by gelation in trichloroethylene at 50 to 65 0 C; 2-ethyl-l-hexanol was used as the gelation medium to prepare 30-μm UO 2 spheres. Washing and drying requirements were determined. The gel dried to 225 0 C contains about 95% UO 3 ; the remaining components are H 2 O, NH 3 - , which are volatilized during firing to UO 2

  15. Development and testing of inorganic sorbents made by the internal gelation process for radionuclide and heavy metal separations

    International Nuclear Information System (INIS)

    Egan, B.Z.; Collins, J.L.; Anderson, K.K.; Chase, C.W.

    1995-01-01

    The objectives of this task are to develop, prepare, and test microspheres and granular forms of inorganic ion exchangers to remove radionuclides and heavy metals from waste streams occurring at various sites. Several inorganic materials, such as hexacyanoferrates, titanates, phosphates, and oxides have high selectivities and efficiencies for separating and removing radionuclides such as uranium, technetium, cesium, and strontium, and metals such as cobalt, silver, zinc, and zirconium from aqueous waste streams. However, these sorbents frequently exist only as powders and consequently are not readily adaptable to continuous processing such as column chromatography. Making these inorganic ion exchangers as microspheres or granular forms improves the flow dynamics for column operations and expands their practical applications. Microspheres of several materials have been prepared at ORNL, and the effectiveness of zirconium monohydrogen phosphate and hydrous titanium oxide microspheres for removing radionuclides from hot cell waste solutions has been demonstrated

  16. Photothermal characterization of the gelation process in Gelidium robustum Agar

    Science.gov (United States)

    Freile-Pelegrín, Y.; Bante, J.; Alvarado-Gil, J. J.; Yánez-Limón, J. M.

    2005-06-01

    Agar is a hydrophilic colloid formed by polysaccharides, whose ability to form reversible gels simply by cooling hot aqueous solutions is the most important property and can be regarded as the prototype and model for all gelling systems. In this paper the evolution of the gelation process of agar obtained from algae of the species Gelidium robustum, using the photopyroelectric technique is reported. It is shown that thermal effusivity increase when the agar is cooled, reaching a maximum value around 37°C. The increase in thermal effusivity can be related to the increasing of the bondings in the gel as temperature decreases, reaching the maximum at the gelation point. The decrease of the thermal effusivity at lower temperature could be due to the syneresis process involving a gradual release of water after gelation.

  17. Production of cerium dioxide microspheres by an internal gelation sol–gel method

    Energy Technology Data Exchange (ETDEWEB)

    Katalenich, Jeffrey A.

    2017-03-27

    An internal gelation sol-gel technique was used to prepare cerium dioxide microspheres with uniform diameters near 100 µm. In this process, chilled aqueous solutions containing cerium, hexamethylenetetramine (HMTA), and urea are transformed into a solid gel by heat addition and are subsequently washed, dried, and sintered to produce pure cerium dioxide. Cerous nitrate and ceric ammonium nitrate solutions were compared for their usefulness in microsphere production. Gelation experiments were performed with both cerous nitrate and ceric ammonium nitrate to determine desirable concentrations of cerium, HMTA, and urea in feed solutions as well as the necessary quantity of ammonium hydroxide added to cerium solutions. Analysis of the pH before and after sample gelation was found to provide a quantitative metric for optimal parameter selection along with subjective evaluations of gel qualities. The time necessary for chilled solutions to gel upon inserting into a hot water bath was determined for samples with a variety of parameters and also used to determine desirable formulations for microsphere production. A technique for choosing the optimal mixture of ceric ammonium nitrate, HMTA, and urea was determined using gelation experiments and used to produce microspheres by dispersion of the feed solution into heated silicone oil. Gelled spheres were washed to remove excess reactants and reaction products before being dried and sintered. X-ray diffraction of air-dried microspheres, sintered microspheres, and commercial CeO2 powders indicated that air-dried and sintered spheres were pure CeO2.

  18. Fabrication of uranium-based ceramics using internal gelation for the conversion of trivalent actinides

    International Nuclear Information System (INIS)

    Daniels, Henrik

    2012-01-01

    Alternative to today's direct final waste disposal strategy of long-lived radionuclides, for example the minor actinides neptunium, americium, curium and californium, is their selective separation from the radioactive wastestream with subsequent transmutation by neutron irradiation. Hereby it is possible to obtain nuclides with a lower risk-potential concerning their radiotoxicity. 1 neutron irradiation can be carried out either with neutron sources or in the next generation of nuclear reactors. Before the treatment, the minor actinides need to be converted in a suitable chemical and physical form. Internal gelation offers a route through which amorphous gel-spheres can be obtained directly from a metal-salt solution. Due to the presence of different types of metal ions as well as changing pH-values in a stock solution, a complex hydrolysis behaviour of these elements before and during gelation occurs. Therefore, investigations with uranium and neodymium as a minor actinide surrogate were carried out. As a result of suitable gelation-parameters, uraniumneodymium gel-spheres were successfully synthesised. The spheres also stayed intact during the subsequent thermal treatment. Based upon these findings, uranium-plutonium and uranium-americium gels were successfully created. For theses systems, the determined parameters for the uraniumneodymium gelation could also be applied. Additionally, investigations to reduce the acidity of uranium-based stock solutions for internal gelation were carried out. The necessary amount of urea and hexamethylenetetramine to induce gelation could hereby be decreased. This lead to a general increase of the gel quality and made it possible to carry out uranium-americium gelation in the first place. To investigate the stability of urea and hexamethylenetetramine, solutions of these chemicals were irradiated with different radiation doses. These chemicals showed a high stability against radiolysis in aqueous solutions.

  19. Chitosan microparticles: influence of the gelation process on the release profile and oral bioavailability of albendazole, a class II compound.

    Science.gov (United States)

    Piccirilli, Gisela N; García, Agustina; Leonardi, Darío; Mamprin, María E; Bolmaro, Raúl E; Salomón, Claudio J; Lamas, María C

    2014-11-01

    Encapsulation of albendazole, a class II compound, into polymeric microparticles based on chitosan-sodium lauryl sulfate was investigated as a strategy to improve drug dissolution and oral bioavailability. The microparticles were prepared by spray drying technique and further characterized by means of X-ray powder diffractometry, infrared spectroscopy and scanning electron microscopy. The formation of a novel polymeric structure between chitosan and sodium lauryl sulfate, after the internal or external gelation process, was observed by infrared spectroscopy. The efficiency of encapsulation was found to be between 60 and 85% depending on the internal or external gelation process. Almost spherically spray dried microparticles were observed using scanning electron microscopy. In vitro dissolution results indicated that the microparticles prepared by internal gelation released 8% of the drug within 30 min, while the microparticles prepared by external gelation released 67% within 30 min. It was observed that the AUC and Cmax values of ABZ from microparticles were greatly improved, in comparison with the non-encapsulated drug. In conclusion, the release properties and oral bioavailability of albendazole were greatly improved by using spraydried chitosan-sodium lauryl sulphate microparticles.

  20. Microspheres Prepared by Internal Gelation - Understanding of HMTA and urea reactions

    International Nuclear Information System (INIS)

    Robisson, A.C.; Dauby, J.; Grandjean, S.; Benay, G.; Modolo, G.

    2008-01-01

    Homogenous microspheres of minor actinide (hereafter MA) compounds are of interest to prevent the generation and dispersal of MA powder at the early stages of the fabrication of targets for homogenous or heterogeneous transmutation. Sol-gel routes are being investigated as one of the possible solutions for producing these homogeneous starting materials. This document describes internal gelation basis experiments led at Cea Marcoule and at the Institute for Energy Research Juelich dedicated to the synthesis of mixed compounds including MAs, particularly mixed actinide-actinide or mixed actinide-inert element compounds. Parameter studies were undertaken by simulating cations in order to scan a larger range of conditions and to optimise more easily gelation conditions. With these experiments, key parameters were put forward and the main successive reactions taking care during gelation were understood. (authors)

  1. Production of Monodisperse Cerium Oxide Microspheres with Diameters near 100 µm by Internal Gelation Sol-Gel Methods

    Energy Technology Data Exchange (ETDEWEB)

    Katalenich, Jeffrey A.; Kitchen, Brian B.; Pierson, Bruce

    2018-05-01

    Internal gelation sol-gel methods have used a variety of sphere forming methods in the past to produce metal oxide microspheres, but typically with poor control over the size uniformity at diameters near 100 µm. This work describes efforts to make and measure internal gelation, sol-gel microspheres with very uniform diameters in the 100 – 200 µm size range using a two-fluid nozzle. A custom apparatus was used to form aqueous droplets of sol-gel feed solutions in silicone oil and heat them to cause gelation of the spheres. Gelled spheres were washed, dried, and sintered prior to mounting on glass slides for optical imaging and analysis. Microsphere diameters and shape factors were determined as a function of silicone oil flow rate in a two-fluid nozzle and the size of a needle dispensing the aqueous sol-gel solution. Nine batches of microspheres were analyzed and had diameters ranging from 65.5 ± 2.4 µm for the smallest needle and fastest silicone oil flow rate to 211 ± 4.7 µm for the largest needle and slowest silicone oil flow rate. Standard deviations for measured diameters were less than 8% for all samples and most were less than 4%. Microspheres had excellent circularity with measured shape factors of 0.9 – 1. However, processing of optical images was complicated by shadow effects in the photoresist layer on glass slides and by overlapping microspheres. Based on calculated flow parameters, microspheres were produced in a simple dripping mode in the two-fluid nozzle. Using flow rates consistent with a simple dripping mode in a two-fluid nozzle configuration allows for very uniform oxide microspheres to be produced using the internal-gelation sol-gel method.

  2. A comparative study of nitride purity and Am fabrication losses in PuN materials by the powder and internal gelation production routes

    Energy Technology Data Exchange (ETDEWEB)

    Hedberg, Marcus, E-mail: marhed@chalmers.se; Ekberg, Christian

    2016-12-15

    Fabrication of plutonium containing fuels through the internal gelation method has mostly been studied in mixed metal systems such as U, Pu or Zr,Pu. In this work production of undiluted PuN has been performed by carbothermal reduction on both oxide powder and Pu microspheres produced by the internal gelation method. Nitride purities reached using the different methods have been studied together with final densities achieved during pellet fabrication as well as losses of ingrown Am during the different production steps. Formation of Pu microspheres was successfully performed using the internal gelation method, although extensive microsphere fracturing occurred during thermal treatment. Final densities of PuN pellets produced by cold pressing and sintering reached 70–80% of theoretical density. Am losses during the carbothermal reduction step was on average about 3.7%. After sintering about 11% of Am was lost in total through the entire production process if sintering in N{sub 2} + 5% H{sub 2} atmosphere while about 50% of the Am in total was lost when using Ar as sintering atmosphere. - Highlights: • Internal gelation Pu based sols was performed. • Nitride formation by carbothermal reduction on Pu microspheres and powders was performed. • Pelletization and sintering of pellets was performed. • Am losses were measured throughout the production steps.

  3. Study for process and equipment design of wet gelation stages in vibropacking process

    International Nuclear Information System (INIS)

    Tanimoto, Ryoji; Kikuchi, Toshiaki; Tanaka, Hirokazu; Amino, Masaki; Yanai, Minoru

    2004-02-01

    Process and layout design of external wet gelation stages in vibropacking process was examined for the feasibility study of commercialized FBR cycle system. In this study, following process stages for the oxide core fuel production line were covered, that is, solidification, washing, drying, calcination, reduction, sintering stages including interim storage of sintering particles and reagent recovery stage. The main results obtained by this study are as follows: (1) Based on the process examination results conducted previously, process-flow, mass-balance and number of production line/equipment were clarified. The process is covered from the receive tank of feed solution to the interim storage equipment. Reagent recovery process-flow, mass-balance were also clarified. And preliminary design of the main equipment was reexamined. (2) Normal operation procedure and the procedure after process failure were summarized along with a remote automated operation procedure. Operation sequence of each production line was mapped out by using a time-chart. (3) Design outline of reagent recovery equipments, installed to recover waste liquid from the wet gelation stages in the view of environmental impact were examined. Effective techniques such as collection of solvent, residue waste treatment method were examined its applicability and selected. Schematic block diagram was presented. (4) Analytical items and analyzing apparatus were extracted taking into account of quality control and process management. Analytical sample taking position and frequency of sampling were also examined. (5) A schematic layout drawing of main manufacturing process and reagent recovery process was presented taking into account of material handling. (6) A feature of the operating rate at each process stage was examined by analyzing failure rate reliability of each component. applying the reliability-centred method. (RCM), the operating rate was evaluated and annual maintenance period was estimated using

  4. Investigation of small scale sphere-pac fuel fabrication plant with external gelation process

    International Nuclear Information System (INIS)

    Maekawa, Kazuhiko; Yoshimura, Tadahiro; Kikuchi, Toshiaki; Hoshino, Yasushi; Munekata, Hideki; Shimizu, Makoto

    2005-02-01

    In feasibility studies on commercialized FBR cycle system, comprehensive system investigation and properties evaluation for candidate FBR cycle systems have been implemented through view point of safety, economics, environmental burden reduction, non-proliferation resistivity, etc. As part of these studies, an investigation of small scale sphere-pac fuel fabrication plant with external gelation process was conducted. Until last fiscal year, equipment layout in cells and overall layout design of the 200t-HM/y scale fuel fabrication plant were conducted as well as schematical design studies on main equipments in gelation and reagent recovery processes of the plant. System property data concerning economics and environmental burden reduction of fuel fabrication plant was also acquired. In this fiscal year, the processes from vibropacking to fuel assemblies storage were added to the investigation range, and a conceptual design of whole fuel fabrication plant was studied as well as deepening the design study on main equipments. The conceptual design study was mainly conducted for small 50t-HM/y scale plant and a revising investigation was done for 200t-HM/y scale plant. Taking the planed comparative evaluation with pellet fuel fabrication system into account, design of equipments which should be equivalent with pellet system, especially in post-vibropacking processes, were standardized in each system. Based on these design studies, system properties data concerning economics and environmental burden reduction of the plant was also acquired. In comparison with existing design, the cell height was lowered on condition that plug type pneumatic system was adopted and fuel fabrication building was downsized by applying rationalized layout design of pellet system to post-vibropacking processes. Reduction of reagent usage at gelation process and rationalization of sintering and O/M controlling processes etc., are foremost tasks. (author)

  5. Cold gelation of globular proteins

    NARCIS (Netherlands)

    Alting, A.C.

    2003-01-01

    Keywords : globular proteins, whey protein, ovalbumin, cold gelation, disulfide bonds, texture, gel hardnessProtein gelation in food products is important to obtain desirable sensory and textural properties. Cold gelation is a novel method to produce protein-based gels. It is a two step process in

  6. Fabrication of uranium-based ceramics using internal gelation for the conversion of trivalent actinides; Herstellung uranbasierter Keramiken mittel interner Gelierung zur Konversion trivalenter Actinoiden

    Energy Technology Data Exchange (ETDEWEB)

    Daniels, Henrik

    2012-07-01

    Alternative to today's direct final waste disposal strategy of long-lived radionuclides, for example the minor actinides neptunium, americium, curium and californium, is their selective separation from the radioactive wastestream with subsequent transmutation by neutron irradiation. Hereby it is possible to obtain nuclides with a lower risk-potential concerning their radiotoxicity. 1 neutron irradiation can be carried out either with neutron sources or in the next generation of nuclear reactors. Before the treatment, the minor actinides need to be converted in a suitable chemical and physical form. Internal gelation offers a route through which amorphous gel-spheres can be obtained directly from a metal-salt solution. Due to the presence of different types of metal ions as well as changing pH-values in a stock solution, a complex hydrolysis behaviour of these elements before and during gelation occurs. Therefore, investigations with uranium and neodymium as a minor actinide surrogate were carried out. As a result of suitable gelation-parameters, uraniumneodymium gel-spheres were successfully synthesised. The spheres also stayed intact during the subsequent thermal treatment. Based upon these findings, uranium-plutonium and uranium-americium gels were successfully created. For theses systems, the determined parameters for the uraniumneodymium gelation could also be applied. Additionally, investigations to reduce the acidity of uranium-based stock solutions for internal gelation were carried out. The necessary amount of urea and hexamethylenetetramine to induce gelation could hereby be decreased. This lead to a general increase of the gel quality and made it possible to carry out uranium-americium gelation in the first place. To investigate the stability of urea and hexamethylenetetramine, solutions of these chemicals were irradiated with different radiation doses. These chemicals showed a high stability against radiolysis in aqueous solutions.

  7. Effect of Sol Concentration, Aging and Drying Process on Cerium Stabilization Zirconium Gel Produced by External Gelation

    Science.gov (United States)

    Sukarsono, R.; Rachmawati, M.; Susilowati, S. R.; Husnurrofiq, D.; Nurwidyaningrum, K.; Dewi, A. K.

    2018-02-01

    Cerium Stabilized Zirconium gel has been prepared using external gelation process. As the raw materials was used ZrO(NO3)2 and Ce(NO3)4 nitrate salt which was dissolved with water into Zr-Ce nitrate mixture. The concentration of the nitrate salt mixture in the sol solution was varied by varying the concentration of zirconium and cerium nitrate in the sol solution and the addition of PVA and THFA to produce a sol with a viscosity of 40-60 cP. The viscosity range of 40-60cP is the viscosity of the sol solution that was easy to produce a good gel in the gelation apparatus. Sol solution was casted in a gelation column equipped with following tools: a 1 mm diameter drip nozzle which was vibrated to adjust the best frequency and amplitude of vibration, a flow meter to measure the flow rate of sol, flowing of NH3 gas to presolidification process. Gelation column was contained NH4OH solution as gelation medium and gel container to collect gel product. Gel obtained from the gelation process than processed with ageing, washing, drying and calcinations to get round gel and not broken at calcinations up to 500°C. The parameters observed in this research are variation of Zr nitrate concentration, Ce nitrate concentration, ratio of Zr and Ce in the sol and ageing and drying process method which was appropriate to get a good gel. From the gelation processes that has been done, it can be seen that with the presolidification process can be obtained a round gel and without presolidification process, produce not round gel. In the process of ageing to get not broken gel, ageing was done on the rotary flask so that during the ageing, gels rotate in gelation media. Gels, then be washed by dilute ammonium nitrate, demireralized water and iso prophyl alcohol. The washed gel was then dried by vacuum drying to form pores on the gel which become the path for the gases resulting from decomposition of the gel to exit the gel. Vacuum drying can prevent cracking because the pores allow the gel

  8. Production of BCG alginate-PLL microcapsules by emulsification/internal gelation.

    Science.gov (United States)

    Esquisabel, A; Hernández, R M; Igartua, M; Gascón, A R; Calvo, B; Pedraz, J L

    1997-01-01

    A biocompatible emulsification method for microencapsulation of live cells and enzymes within a calcium alginate matrix applied to Bacillus Calmette-Guérin (BCG) has been developed. Small-diameter alginate beads (microcapsules) were formed via internal gelation of an alginate solution emulsified within vegetable oil. Five different oils (sesame, sweet almond, perhydrosqualene, camomile and jojoba) were used. The rheological analysis of the oils showed a Newtonian behaviour, with viscosities = 30.0, 37.7, 51.2, 59.3 and 67.1 mPa.s for perhydrosqualene, jojoba, camomile, sesame and sweet almond oil respectively. The particle size of the microcapsules obtained ranged from 30.3 microns for the microcapsules prepared with sweet almond oil to 57.0 microns for those made with perhydrosqualene. The mean particle diameter obtained was found to be dependent on the viscosity of the oil employed, according to the equation: phi (micron) = 76.6-0.628 eta (mPa.s) (r2 = 0.943). The encapsulated BCG was identified by the Difco TB stain set K, followed by observation under optical microscopy. Freeze-drying of the microcapsules was carried out to ensure their stability during storage. Two batches of microcapsules (those prepared with sesame and jojoba oil) and four types of cryoprotectors (glucose, trehalose, mannitol and sorbitol), at three concentration levels (5, 10 and 20% w/v) were studied. The parameters evaluated were particle size, physical appearance, reconstitution of lyophilizates and microscopical evaluation. For both batches of microcapsules the best results were obtained with trehalose 5%, showing particle sizes of 42.1 microns in the case of the microcapsules prepared with sesame oil, and of 45.3 microns for those prepared with jojoba.

  9. Microspheres Prepared by Internal Gelation for Actinide Co-Conversion - Influence of Organic Precursors in Initial Solution on Structure during Thermal Treatment

    International Nuclear Information System (INIS)

    Benay, G.; Modolo, G.; Robisson, A.C.; Grandjean, S.

    2008-01-01

    The fabrication of fuels or targets for transmutation of minor actinides requires a dust-free process. Such a requirement can be fulfilled by sol-gel methods, which allow the production of microsphere precursors. Internal gelation, one of these methods, was studied at Cea Marcoule and FZ (Forschungszentrum Juelich Germany). A study of the parameters involved in internal gelation (essentially the quantity of organic additives urea and hexa-methylene-tetramine (HMTA) present in the initial solution) was performed. Afterwards, the effects of these parameters on the structural evolution of the microspheres during thermal treatment were studied. It was observed that the structure and density of the microspheres are heavily dependant of the quantity of organic precursors present in the initial solution. Urea in particular has been found to bring porosity to the material, in addition to its catalytic effect on HMTA decomposition. The elimination of these organic compounds is however a major issue which causes the formation of cracks on the microspheres if no optimization is performed. (authors)

  10. Nanospheres of alginate prepared through w/o emulsification and internal gelation with nanoparticles of CaCO3

    NARCIS (Netherlands)

    Paques, J.P.; Sagis, L.M.C.; Rijn, van C.J.M.; Linden, van der E.

    2014-01-01

    Gelled nanospheres of alginate are prepared through a single step technique involving emulsification and gelation. CaCO3 nanoparticles, together with glucono delta-lactone (GDL), are dispersed in an alginate solution, which is subsequently dispersed in an oil phase and followed by gelation of the

  11. Influent of Carbonization of Sol Solution at the External Gelation Process on the Quality of Uranium Oxide Kernel

    International Nuclear Information System (INIS)

    Damunir; Sukarsono

    2007-01-01

    The influent of carbonization of sol solution at the external gelation process on the quality of uranium oxide kernel was done. Variables observed are the influent of carbon, temperature and time of reduction process of U 3 O 8 kernel resulted from carbonization of sol solution. First of all, uranyl nitrate was reacted with 1 M NH 4 OH solution, producing the colloid of UO 3 . Then by mixing and heating up to the temperature of 60-80 °C, the colloid solution was reacted with PVA, mono sorbitol oleate and paraffin producing of uranium-PVA sol. Then sol solution was carbonized with carbon black of mol ratio of carbon to uranium =2.32-6.62, produce of carbide gel. Gel then washed, dried and calcined at 800 °C for 4 hours to produce of U 3 O 8 kernel containing carbon. Then the kernel was reduced by H 2 gas in the medium of N 2 gas at 500-800 °C, 50 mmHg pressure for 3 hours. The process was repeated at 700 °C, 50 mmHg pressure for 1-4 hours. The characterization of chemical properties of the gel grains and uranium oxide kernel using FTIR covering the analysis of absorption band of infra red spectrum of UO 3 , C-OH, NH 3 , C-C, C-H and OH functional group. The physical properties of uranium oxide covering specific surface area, void volume, mean diameter using surface area meter Nova-1000 and as N 2 gas an absorbent. And O/U ratio of uranium dioxide kernel by gravimetry method. The result of experiment showed that carbonization of sol solution at the external gelation process give influencing the quality of uranium oxide kernel. (author)

  12. Incorporation of essential oil in alginate microparticles by multiple emulsion/ionic gelation process.

    Science.gov (United States)

    Hosseini, Seyede Marzieh; Hosseini, Hedayat; Mohammadifar, Mohammad Amin; Mortazavian, Amir Mohammad; Mohammadi, Abdorreza; Khosravi-Darani, Kianoosh; Shojaee-Aliabadi, Saeedeh; Dehghan, Solmaz; Khaksar, Ramin

    2013-11-01

    In this study, an o/w/o multiple emulsion/ionic gelation method was developed for production of alginate microparticles loaded with Satureja hortensis essential oil (SEO). It was found that the essential oil concentration has significant influence on encapsulation efficiency (EE), loading capacity (LC) and size of microparticles. The values of EE, LC and particle mean diameter were about 52-66%, 20-26%, and 47-117 μm, respectively, when the initial SEO content was 1-3% (v/v) .The essential oil-loaded microparticles were porous, as displayed by scanning electron micrograph. The presence of SEO in alginate microparticles was confirmed by Fourier transform-infrared (FT-IR) spectroscopy and differential scanning calorimetry (DSC) analyses. SEO-loaded microparticles showed good antioxidant (with DPPH radical scavenging activity of 40.7-73.5%) and antibacterial properties; this effect was greatly improved when the concentration of SEO was 3% (v/v). S. aureus was found to be the most sensitive bacterium to SEO and showed a highest inhibition zone of 304.37 mm(2) in the microparticles incorporated with 3% (v/v) SEO. In vitro release studies showed an initial burst release and followed by a slow release. In addition, the release of SEO from the microparticles followed Fickian diffusion with acceptable release. Copyright © 2013 Elsevier B.V. All rights reserved.

  13. Fabrication and Characterization of Device Pressure Regulation System Orifice of Manufacturing Process Gel Uranium Column Gelation External

    International Nuclear Information System (INIS)

    Triyono; Sutarni; Indra Suryawan

    2009-01-01

    The device pressure regulation orifice system of manufacturing process gel uranium on external column gelation has been made and characterized. The device consists : compressor 5.75-6.75 kg / cm 2 , air container tank, power supply 24 volts dc, solenoid valve 24 volts dc, pressure indicator 0-100 mbar, pressure indicator 0-250 mbar, mechanical valve and power electric 380 volts 50 Hz. The activity includes: installation device system and characterization with pressure variation orifice 5-75 mbar on the compressor 5.75-6.5 kg/cm 2 continuously for 1 minute. The method of installation i.e: wiring and piping to first component and support component (compressor and pressure air indicator, air container tank and pressure air indicator, solenoid valve, power supply 220 volts / 24 volts dc and orifice). After apparatus installed has been tested by the characterization without feed under air pressure varied to orifice of 5-75 mbar and device characterization with variation diameter orifice of 0.5-1 mm and orifice pressure of 5-75 mbar. The result in the characterization an every component good function, can be operation by input pressure range of 15-185 mbar orifice pressure range of 5-75 mbar. The characterization result device pressure regulation orifice system showed that: the system can be good operation of air pressure regulation orifice between 5-75 mbar with diameter orifice 0.5 mm to result gelation range of 10-25 piece / minute with variation air pressure input between 15-185 mbar of air pressure compressor 5.75-6.5 kg cm 2 . (author)

  14. The Effect of Various Acids to the Gelation Process to the Silica Gel Characteristic Using Organic Silica

    Science.gov (United States)

    Rahman, NA; Widiyastuti, W.; Sigit, D.; Ajiza, M.; Sujana, W.

    2018-01-01

    Bagasse ash is solid waste of cane sugar industry which contain of silica more than 51%. Some previous study of silica gel from bagasse ash have been conducted often and been applied. This study concerns about the effect of various acid used in the process of gelation to the characteristic of silica gel produced. Then, this silica gel will be used as adsorbent. As that, the silica gel must fulfill the requirements of adsorbent, as have good pores characteristics, fit in mesoporous size so that adsorbent diffusion process is not disturbed. A fitted pores size of silica gel can be prepared by managing acid concentration used. The effect of acid, organic acid (tartaric acid) and inorganic acid (hydrochloric acid), is investigated in detail. The acid is added into sodium silicate solution in that the gel is formed, the pores structures can be investigated with BET, the crystal form is analyzed with XRD and the pore structure is analyzed visually with SEM. By managing the acid concentration added, it gets the effect of acid to the pore structure of silica gel. The bigger concentration is, the bigger the pore’s size of silica gel produced.

  15. Studying the gelation process of titanium isopropoxide by method of positron annihilation spectroscopy; Studium procesu gelacie izopropoxidu titaniciteho metodou pozitronovej anihilacnej spektroskopie

    Energy Technology Data Exchange (ETDEWEB)

    Nyblova, D.; Jesenak, K. [Univerzita Komenskeho, Prirodovedecka fakulta, Katedra anorganickej chemie, 84215 Bratislava (Slovakia); Sausa, O. [Slovenska akademia vied, Fyzikalny ustav, 84511 Bratislava (Slovakia)

    2013-04-16

    Thank to its harmlessness titanium dioxide is widely utilized material. One of the new areas to use titanium dioxide is photocatalysis, which could be the way to e.g. remove organic pollutants from water or air. Titanium dioxide based gels are perspective form of TiO{sub 2} for photocatalysis because of their high porosity thus high surface area. Positron annihilation spectroscopy is a physical method to study microporous structure and electron energy distribution in materials. We studied gelation process of titanium isopropoxide in ethanol with various amount of water catalyzed by hydrochloric acid by positron annihilation lifetime spectroscopy and doppler broadening of annihilation line in this work. Positronium is weakly formed in TiO{sub 2} in general wherefore it cannot be monitored by positron annihilation spectroscopy very well. Gelation process can be monitored through pick-off annihilation of ortho-positronium. (authors)

  16. Influence of THFA on the surface area and porosity of U3O8 kernel of produced by external gelation process

    International Nuclear Information System (INIS)

    Susilowati, Sri Rinanti; Triyono; Nawangsih, Endang; Widiyati, Sri

    2013-01-01

    The research of the influence of THFA on the surface area and porosity of U 3 O 8 by kernel external gelation results has done. U 3 0 8 kernel made by external gelation process using uranyl nitrate solution with various concentration of THFA in sol solution. UN solution preparation by dissolving UO 3 powder into 7N HNO 3 at a temperature of 60 °C with a certain amount and volume, resulting in a solution of uranyl nitrate with high uranium concentrations but low acidity. Preparation of sol begins by dissolving 1.8 9 of polyvinyl alcohol in demineralized water at 70 °C, the volume varied tetrahydrofurfural alcohol, then added a solution of UN stirring constantly until homogeneous. Sol solution was then dripped in 7N ammonia in the medium gelation column. Gel ADU diaging in ammonia solution 7N for 30 minutes, then washed with ammonia 2.5% and n propanol. ADU gel diameter was measured using calipers. ADU silenced gel at room temperature 48 hours and then dried in an oven 100 °C at a rate of temperature rising 5°C/minutes. After drying, the gel ADU calcined at 600°C with an increase rate of 5°C/minutes for 2 hours. Kernel density U 3 O 8 then analyzed, surface area, mean pore radius and total pore volume. U 3 O 8 best kernel at 2.5% THFA concentration conditions, because it has a high density is 7.877 g/mL and extensive porosity and lower surface area is 5,180 % and 4,898 m 2 /g. (author)

  17. Gelation induced supramolecular chirality: chirality transfer, amplification and application.

    Science.gov (United States)

    Duan, Pengfei; Cao, Hai; Zhang, Li; Liu, Minghua

    2014-08-14

    Supramolecular chirality defines chirality at the supramolecular level, and is generated from the spatial arrangement of component molecules assembling through non-covalent interactions such as hydrogen bonding, van der Waals interactions, π-π stacking, hydrophobic interactions and so on. During the formation of low molecular weight gels (LMWGs), one kind of fascinating soft material, one frequently encounters the phenomenon of chirality as well as chiral nanostructures, either from chiral gelators or even achiral gelators. A view of gelation-induced supramolecular chirality will be very helpful to understand the self-assembly process of the gelator molecules as well as the chiral structures, the regulation of the chirality in the gels and the development of the "smart" chiral materials such as chiroptical devices, catalysts and chiral sensors. It necessitates fundamental understanding of chirality transfer and amplification in these supramolecular systems. In this review, recent progress in gelation-induced supramolecular chirality is discussed.

  18. Positionally isomeric organic gelators: structure-gelation study, racemic versus enantiomeric gelators, and solvation effects.

    Science.gov (United States)

    Caplar, Vesna; Frkanec, Leo; Sijaković Vujicić, Natasa; Zinić, Mladen

    2010-03-08

    Low molecular weight gelator molecules consisting of aliphatic acid, amino acid (phenylglycine), and omega-aminoaliphatic acid units have been designed. By varying the number of methylene units in the aliphatic and omega-aminoaliphatic acid chains, as defined by descriptors m and n, respectively, a series of positionally isomeric gelators having different positions of the peptidic hydrogen-bonding unit within the gelator molecule has been obtained. The gelation properties of the positional isomers have been determined in relation to a defined set of twenty solvents of different structure and polarity and analyzed in terms of gelator versatility (G(ver)) and effectiveness (G(eff)). The results of gelation tests have shown that simple synthetic optimizations of a "lead gelator molecule" by variation of m and n, end-group polarity (carboxylic acid versus sodium carboxylate), and stereochemistry (racemate versus optically pure form) allowed the identification of gelators with tremendously improved versatility (G(ver)) and effectiveness (G(eff)). Dramatic differences in G(eff) values of up to 70 times could be observed between pure racemate/enantiomer pairs of some gelators, which were manifested even in the gelation of very similar solvents such as isomeric xylenes. The combined results of spectroscopic ((1)H NMR, FTIR), electron microscopy (TEM), and X-ray diffraction studies suggest similar organization of the positionally isomeric gelators at the molecular level, comprising parallel beta-sheet hydrogen-bonded primary assemblies that form inversed bilayers at a higher organizational level. Differential scanning calorimetry (DSC) studies of selected enantiomer/racemate gelator pairs and their o- and p-xylene gels revealed the simultaneous presence of different polymorphs in the racemate gels. The increased gelation effectiveness of the racemate compared to that of the single enantiomer is most likely a consequence of its spontaneous resolution into enantiomeric

  19. Photoinduced gelation by stilbene oxalyl amide compounds.

    Science.gov (United States)

    Miljanić, Snezana; Frkanec, Leo; Meić, Zlatko; Zinić, Mladen

    2005-03-29

    Oxalyl amide derivatives bearing 4-dodecyloxy-stilbene as a cis-trans photoisomerizing unit were synthesized. The trans derivative acted as a versatile gelator of various organic solvents, whereas the corresponding cis derivative showed a poor gelation ability or none at all. In diluted solution (c = 2.0 x10(-5) mol dm(-3), ethanol), the cis isomer was photochemically converted into the trans isomer within 4 min. Depending on the radiation wavelength, the trans isomer was stable or liable to photodecomposition. When exposed to irradiation, a concentrated solution of the cis isomer (c = 2.0 x 10(-2) mol dm(-3), ethanol) turned into a gel. The FT-Raman, FT-IR, and 1H NMR spectra demonstrated that the gelation process occurred because of a rapid cis --> trans photoisomerization followed by a self-assembly of the trans molecules. Apart from the formation of hydrogen bonding between the oxalyl amide parts of the molecules, confirmed by FT-IR spectroscopy, it was assumed that the pi-pi stacking between the trans-stilbene units of the molecule and a lipophilic interaction between long alkyl chains were the interactions responsible for gelation.

  20. Gelation on heating of supercooled gelatin solutions.

    Science.gov (United States)

    Guigo, Nathanaël; Sbirrazzuoli, Nicolas; Vyazovkin, Sergey

    2012-04-23

    Diluted (1.0-1.5 wt%) aqueous gelatin solutions have been cooled to -10 °C at a cooling rate 20 °C min(-1) without freezing and detectable gelation. When heated at a constant heating rate (0.5 -2 °C min(-1)), the obtained supercooled solutions demonstrate an atypical process of gelation that has been characterized by regular and stochastically modulated differential scanning calorimetry (DSC) as well as by isoconversional kinetic analysis. The process is detectable as an exothermic peak in the total heat flow of regular DSC and in the nonreversing heat flow of stochastically modulated DSC. Isoconversional kinetic analysis applied to DSC data reveals that the effective activation energy of the process increases from approximately 75 to 200 kJ mol(-1) as a supercooled solution transforms to gel on continuous heating. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  1. Gelation under shear

    Energy Technology Data Exchange (ETDEWEB)

    Butler, B.D.; Hanley, H.J.M.; Straty, G.C. [National Institute of Standards and Technology, Boulder, CO (United States); Muzny, C.D. [Univ. of Colorado, Boulder, CO (United States)

    1995-12-31

    An experimental small angle neutron scattering (SANS) study of dense silica gels, prepared from suspensions of 24 nm colloidal silica particles at several volume fractions {theta} is discussed. Provided that {theta}{approx_lt}0.18, the scattered intensity at small wave vectors q increases as the gelation proceeds, and the structure factor S(q, t {yields} {infinity}) of the gel exhibits apparent power law behavior. Power law behavior is also observed, even for samples with {theta}>0.18, when the gel is formed under an applied shear. Shear also enhances the diffraction maximum corresponding to the inter-particle contact distance of the gel. Difficulties encountered when trying to interpret SANS data from these dense systems are outlined. Results of computer simulations intended to mimic gel formation, including computations of S(q, t), are discussed. Comments on a method to extract a fractal dimension characterizing the gel are included.

  2. Rational Design of Molecular Gelator - Solvent Systems Guided by Solubility Parameters

    Science.gov (United States)

    Lan, Yaqi

    Self-assembled architectures, such as molecular gels, have attracted wide interest among chemists, physicists and engineers during the past decade. However, the mechanism behind self-assembly remains largely unknown and no capability exists to predict a priori whether a small molecule will gelate a specific solvent or not. The process of self-assembly, in molecular gels, is intricate and must balance parameters influencing solubility and those contrasting forces that govern epitaxial growth into axially symmetric elongated aggregates. Although the gelator-gelator interactions are of paramount importance in understanding gelation, the solvent-gelator specific (i.e., H-bonding) and nonspecific (dipole-dipole, dipole-induced and instantaneous dipole induced forces) intermolecular interactions are equally important. Solvent properties mediate the self-assembly of molecular gelators into their self-assembled fibrillar networks. Herein, solubility parameters of solvents, ranging from partition coefficients (logP), to Henry's law constants (HLC), to solvatochromic ET(30) parameters, to Kamlet-Taft parameters (beta, alpha and pi), to Hansen solubility parameters (deltap, deltad, deltah), etc., are correlated with the gelation ability of numerous classes of molecular gelators. Advanced solvent clustering techniques have led to the development of a priori tools that can identify the solvents that will be gelled and not gelled by molecular gelators. These tools will greatly aid in the development of novel gelators without solely relying on serendipitous discoveries.

  3. Licensing Process for International Projects

    International Nuclear Information System (INIS)

    Raetzke, Christan

    2014-01-01

    Christan Raetzke, lawyer, then outlined why nuclear constructions were always international projects and in which cases it would make sense to also make the licensing process be international. His law consulting firm CONLAR focuses specifically on design review so he could adequately present why an international process would make a lot of sense without being a loss of sovereignty

  4. Precipitation and ultimate pH effect on chemical and gelation properties of protein prepared by isoelectric solubilization/precipitation process from pale, soft, exudative (PSE)-like chicken breast meat1.

    Science.gov (United States)

    Zhao, X; Xing, T; Chen, X; Han, M-Y; Li, X; Xu, X-L; Zhou, G-H

    2017-05-01

    Pale, soft, exudative (PSE)-like chicken breast is considered deteriorated raw material in the poultry meat industry that has inferior processing ability. The chemical and gelation properties of PSE-like chicken breast meat paste were studied. These pastes were prepared by the pH adjustment method and protein isolation using the isoelectric solubilization/precipitation (ISP) process from PSE-like chicken meat. The ISP-isolated samples were solubilized at pH 11.0 and recovered at pH 5.5 and 6.2. The ultimate pH of the ISP-isolated protein and meat paste was adjusted to 6.2 and 7.0. The ultimate pH in this article referred to the final pH of the extracted protein and meat paste. Higher reactive sulfhydryl content and surface hydrophobicity were found in the precipitation at pH 6.2 than at pH 5.5. However, various ultimate pH values showed no significant influence on the surface hydrophobicity. The hardness of gel, as measured by textural profile analysis, was improved using 6.2 as the precipitation pH compared with pH 5.5. The viscoelastic modulus (G΄) of gel pastes prior to the thermal gelation was higher with ISP treatment. However, lower G΄ was seen after thermal gelation compared with the control. Dynamic rheological measurement demonstrated a different gel-forming mechanism for protein precipitated at pH values of 5.5 and 6.2 compared with the meat paste. The cooking loss showed that the recovered protein failed to form a gel with good water-retention capacity unless the ultimate pH was adjusted to 7.0. Gels made from protein extracted by the ISP method had higher yellowness and lower redness values, probably due to protein denaturation. Precipitation at pH 6.2 formed a harder gel with lower water-retention ability than that at pH 5.5, and this result was possibly due to higher surface hydrophobicity and S-S bridge formation. Overall, network characteristics of ISP-treated protein gels were strongly dependent on precipitation pH and ultimate pH. © 2016

  5. IS OFFSHORING AN INTERNATIONAL PROCESS

    Directory of Open Access Journals (Sweden)

    Paulo Roberto Gião

    2012-01-01

    Full Text Available This article proposes to analyze the applicability of transaction cost economics - TCE (Coase, 1937; Williamson, 1975, 1979 through its characteristic make-or-buy expression, considering the offshoring pace and emerging economy firms. The make-or-buy decision must be flexible enough to explain offshoring characteristics and developed and emerging economy firms scenarios. As secondary objectives, and to show the trail to the main purpose, two research questions were identified and discussed during the paper: Is offshoring process an international movement only from developed countries to emerging economies? Is the main reason of offshoring the looking for low-cost work / activities? To achieve the proposed objectives, the structure of this paper begins with a reasonable or acceptable definition of offshoring. Some reasons (or “the reason” for the process are also another important starting point. The majority of articles referee the idea that low-cost is the main reason for offshoring, and if it is correct, transaction cost economics seems to be a good basis for our analysis purpose and integrative intention. Also some literature connections between offshoring and TCE are presented and, naturally TCE is presented in highlights for understanding these connections. Ending this section, some different arguments based on newer researches are presented by some authors presenting another perspective as the main reason. After this theoretical approach, a scenario analysis and some discussions are presented based on all possible interactions among firm from developed (DC and emerging economies (EE and examples of international corporations are presented to clarify and improve the understanding of our research questions and to build new contributions to international business theory.

  6. Intermediate Compound Preparation Using Modified External Gelation Method and Thermal Treatment Equipment Development for UCO Kernel

    Energy Technology Data Exchange (ETDEWEB)

    Jeong, Kyung Chai; Eom, Sung Ho; Kim, Yeon Ku; Yeo, Seoung Hwan; Kim, Young Min; Cho, Moon Sung [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2016-10-15

    VHTR (Very High Temperature Gas Reactor) fuel technology is being actively developed in the US, China, Japan, and Korea for a Next Generation Nuclear Plant (NGNP). The concept of fuel of a VHTR is based on a sphere kernel of UO{sub 2} or UCO, with multiple coating layers to create a gas-tight particle. The fuel particle of a VHTR in the US is based on microspheres containing a UCO, mixture compound of UO{sub 2} and UC{sub 2} , coated particles with multi carbon layers and a SiC layer. This was first prepared through an internal gelation method at ORNL in the late 1970s. This study presents; (1) C-ADU gel particles were prepared using a modified sol-gel process. The particles fabricated with a KAERI-established gelation and AWD processes showed good sphericity and no cracks were found on the surfaces. (2) High temperature rotating furnace was designed and fabricated in our laboratory, and the maximum operation temperature was about 2000℃. The furnace was equipped with Mo crucible and graphite heating system, and now it is being operated. (3) Well-prepared C-ADU gel particles were converted into UCO compounds using high temperature rotating furnace, and the physical properties of the UCO kernels will be analyzed.

  7. Oxidative enzymatic gelation of sugar beet pectin for emulsion stabilization

    DEFF Research Database (Denmark)

    Abang Zaidel, Dayang Norulfairuz; Meyer, Anne S.

    2013-01-01

    Pectin from sugar beet is derived from the sugar beet pulp residue which results when sugar beets are processed for sucrose extraction. The sugar beet pectin has poor gelationability by the classic divalentcation molecular mechanism because of a relatively high acetylation degree and short...... polygalacturonate backbone chain length. However, due to the feruloyl-substitutions on the side chains, the sugar beet pectic polysaccharides can be cross-linked via enzyme catalyzed oxidation. The enzyme kinetics and functionality of such oxidativelycross-linked sugar beet pectin, in relation to stabilizing...... emulsions has recently been investigated in model food emulsions. This paper reviews the pectin chemistry, enzymatic oxidative gelation mechanisms, interaction mechanisms of the sugar beet pectin with the emulsion droplets and explores how the gelation affects the rheology and stability of emulsion systems...

  8. Studies on gelation of sodium silicate hydrosol for immobilization of high level liquid waste (HLLW).

    Energy Technology Data Exchange (ETDEWEB)

    Abdel Raouf, M W [Hot Lab. Centre, Atomic Energy Authority, Cairo (Egypt); Sharaf El-deen, A N; El-Dessouky, M M [Military Technical College, Kobry El-Kobbah, Cairo (Egypt)

    1995-10-01

    Immobilization of the simulated high-level liquid waste (HLLW) was performed via the gelation with sodium silicate hydrosol at room temperature. The simulated waste in this study, was represented by the electrolytes of Li, Na, K, Cs, Co and Sr at different concentrations. Specific loading of the liquid waste with 0.6 M Mg (NO{sub 3})2 and tailoring with Al salts were tried during most of the gelation processes. Mineral acid (HCl or {sub 3}) were added during the gelation processes to achieve the gel point, especially when lower concentrations of the simulated waste were used. The obtained hydrogel were dried to obtain the solid gel form. The gelation processes were investigated in terms of the different factors that affected them, namely: temperature, pH, changes in the concentration of the initial hydrosol and the used electrolytes. The efficiency of the gelation processes was investigated from the ratio of the amount of simulated waste reacted (m mole) to the initial silicate used (m mole), i.e. X value. Lower X values were observed when using multi valent cations (higher polarizing power). A special effect of increasing the sorption of metal cations in the silica matrix was observed when Al{sup 3+} replaced Si{sup 4+} in the three-dimensional network structure of the matrix. 3 figs., 7 tabs.

  9. Internal quality assurance reviews: challenges and processes ...

    African Journals Online (AJOL)

    Internal quality assurance reviews: challenges and processes – Walter Sisulu University\\'s Business, Management Sciences and Law Faculty. ... This article examines some of the challenges and processes followed by six of the departments ...

  10. Coordination Processes in International Organisations

    DEFF Research Database (Denmark)

    Nedergaard, Peter

    2008-01-01

    The EU is not a member of the International Labour Organisation (ILO), but relatively elaborate EU coordination takes place anyway. This paper addresses two research questions: 1) How is it possible to evaluate the coordination of the EU in its specific observable configuration in the ILO?, and 2......-à-vis their principals, the Member States. The Commission is the leading agent in the phase leading up to the Conference; the Presidency then takes over. On the one hand, due to the Treaty obligations and their interpretations by the Court of Justice, both the Presidency and the Commission are kept within tight limits...... by the principals. On the other hand, both before and during the Conference, the Member States accept the so-called discursive coordination of the Commission, which seems to be of great (but often neglected) importance. Owing to the organisational set-up in which coordination takes place, the EU is able...

  11. Gelation and interfacial behaviour of vegetable proteins

    NARCIS (Netherlands)

    Vliet, T. van; Martin, A.H.; Bos, M.A.

    2002-01-01

    Recent studies on gelation and interfacial properties of vegetable protiens are reviewed. Attention is focused on legume proteins, mainly soy proteins, and on wheat proteins. The rheological properteis of vegetable protein gels as a function of heating time or temperature is discussed as well as the

  12. Gelation and interfacial behaviour of vegetable proteins

    NARCIS (Netherlands)

    Vliet, van T.; Martin, A.H.; Bos, M.A.

    2002-01-01

    Recent studies on gelation and interfacial properties of vegetable proteins are reviewed. Attention is focused on legume proteins, mainly soy proteins, and on wheat proteins. The rheological properties of vegetable protein gels as a function of heating time or temperature is discussed as well as the

  13. Reversible thermal gelation in soft spheres

    DEFF Research Database (Denmark)

    Kapnistos, M.; Vlassopoulos, D.; Fytas, G.

    2000-01-01

    Upon heating, concentrated solutions of star polymers and block copolymer micelles in a good solvent, representing soft spheres, undergo a reversible gelation. This phenomenon is attributed to the formation of clusters causing a partial dynamic arrest of the swollen interpenetrating spheres at hi...

  14. Performance test of a vertically-directed electric-field cavity resonator made for the rapid gelation apparatus with microwave heating

    International Nuclear Information System (INIS)

    Yamagishi, Shigeru; Ogawa, Toru; Hasegawa, Atsushi.

    1996-06-01

    A cavity resonator with vertically-directed electric field was produced and attached to 'the rapid gelation apparatus with microwave heating' previously reported. Using the rapid gelation apparatus, drops of a simulated solution and of U-containing solutions for internal gelation were heated. The results indicated that the heating required for gelation of the U-containing solutions was possible. However, the electric field strength in the cavity resonator at that time was comparable to that causing the discharge due to the gaseous ammonia released from the heated drops. As a result, gel microspheres were not obtained in a stable state. The discussion suggests that the stable gelation would be realized by improving the cavity resonator shape and/or by modifying the power supply accompanied with using a power stabilizer. (author)

  15. The International harmonisation process of Accounting Standards

    OpenAIRE

    Fritz, Susanne; Lämmle, Christina

    2003-01-01

    Background: Growth in international trade and capital flows has triggered a rising economic integration. Because of these developments there has been an international homogenising effect upon many customs, practices and institutions. In business life it led among other things to a desire to harmonise Accounting Standards among countries. Purpose: Our purpose is to answer the question: What is the international harmonisation process of Accounting Standards, what is its status quo and how impo...

  16. The Study of the Influence of Urea and Hexa Methylene Tetramine (HMTA) Additive on the Total Gelation Process of Uranium on the Chemical Characteristic of the Poly (Uranate-Vinyl Alcohol) Gel

    International Nuclear Information System (INIS)

    Damunir

    2007-01-01

    The study of the influence of urea and Hexa methylene tetramine (HMTA) additive on the total gelation process of uranium on the chemical characteristic of the poly (uranate-vinyl alcohol) gel was done. First of all the 1M uranyl nitrate solution was heated at 70 °C, then variation the 1,2,3,4 and 5M urea additive was studied. Urea was added to the hot solution, and stirred for 10 minutes, producing the colloid particles of UO 3 . The mixing and heating up for 20 minutes, the colloid of UO 3 solution reacted by mixed of THF-PVA 1:1 solution. The solution was cooled at 32°C for 2 hours, and then variation the 1,2,3,4 and 5M HMTA additive was studied. HMTA was added into solution at 32°C and was stirred to form the homogenous sol solution. For the poly (urinate-vinyl) gel formation, the sol solution was dropped to the medium solution of 5M NH 5 OH at ambient condition. Gel formatted was microsphere then soaked, washed by NH 4 OH and hot water to release the chemical matters which were unreacted, was dried at 60°C and then dried at 150°C for 4 hours. The chemical characteristic of gel was made, covering the analyzed of colour, shape and diameter microsphere using optical microscope. Next, the analysis of molecular composition of the gel, using Fourier transform infra red spectroscopic (FTIR), was made. The analytical were the qualitative analysis of the absorption band of infra red spectrum on O-U-O-U-O bond, U-O bond and NH 3 , C-OH, C-H and OH functional group at 300-4000 wave numbers. The result of the research showed that the addition of urea and HMTA additive influences on chemical characteristic of the poly (uranate-vinyl alcohol) gel. The optimum condition was at 2-3 M urea and 2- M HMTA concentration. The analyze of absorption band of infra red spectrum showed that the molecular composition of poly (vinyl alcohol) gel was the uranium trioxide, ammonia, water and polyvinyl alcohol molecular contain with the molecular formulas of [2UO 3 .2 NH 3 .H 2 O

  17. RESEARCH ON THE INTERNATIONAL ACCOUNTING HARMONIZATION PROCESS

    Directory of Open Access Journals (Sweden)

    Tatiana Danescu

    2016-12-01

    Full Text Available During the last decades, the need of harmonization of the financial reporting frameworks has become more acute, mostly because the capital markets are not restricted anymore by country borders and capital movement has outlined the phenomenon of globalization and internationalism. A significant step in harmonizing the financial reporting was done in the process of normalization through different sets of rules and principles, recognized and applied in many states are the International Financial Reporting Standards (IFRS. The process of international recognition of these standards continues along with conceptual development which is based on epistemological research on specific markets, industries, economies open to international capital flows. In this context it becomes of interest to identify and understand generally accepted and applied accounting elements which carry forward the accounting harmonization process along with factors and circumstances that create diversity in nationally applied financial reporting frameworks.

  18. Internal process: what is abstraction and distortion process?

    Science.gov (United States)

    Fiantika, F. R.; Budayasa, I. K.; Lukito, A.

    2018-03-01

    Geometry is one of the branch of mathematics that plays a major role in the development of science and technology. Thus, knowing the geometry concept is needed for students from their early basic level of thinking. A preliminary study showed that the elementary students have difficulty in perceiving parallelogram shape in a 2-dimention of a cube drawing as a square shape. This difficulty makes the students can not solve geometrical problems correctly. This problem is related to the internal thinking process in geometry. We conducted the exploration of students’ internal thinking processes in geometry particularly in distinguishing the square and parallelogram shape. How the students process their internal thinking through distortion and abstraction is the main aim of this study. Analysis of the geometrical test and deep interview are used in this study to obtain the data. The result of this study is there are two types of distortion and abstraction respectively in which the student used in their internal thinking processes.

  19. Fine-Tuning of Saponification-Triggered Gelation by Strategic Modification of Peripheral Substituents: Gelation Regulators.

    Science.gov (United States)

    Kumar, Ashish; Singh, Roop Shikha; Kumar, Amit; Ali, Afsar; Biswas, Arnab; Pandey, Daya Shankar

    2016-09-19

    A pioneering approach towards controlling the efficiency of saponification assisted gelation in ethyl ester based Zn II -complexes have been described. Using four new ester containing bis-salen Zn II complexes (C1-C4) involving different para-azo phenyl substituted ligands it has been clearly shown that gelation efficiency is greatly influenced by the electronic effects of the substituents (-H (C1), -CH 3 (C2), -NO 2 (C3), and -OCH 3 (C4)). Morphological, photophysical, and rheological investigations corroborated the experimental observations well and established that gelation efficiency was enhanced with electron-withdrawing characteristics of substituents (C4

  20. Enzyme catalyzed oxidative gelation of sugar beet pectin: Kinetics and rheology

    DEFF Research Database (Denmark)

    Abang Zaidel, Dayang Norulfairuz; Chronakis, Ioannis S.; Meyer, Anne S.

    2012-01-01

    Sugar beet pectin (SBP) is a marginally utilized co-processing product from sugar production from sugar beets. In this study, the kinetics of oxidative gelation of SBP, taking place via enzyme catalyzed cross-linking of ferulic acid moieties (FA), was studied using small angle oscillatory...

  1. The Metal Effect on Self-Assembling of Oxalamide Gelators Explored by Mass Spectrometry and DFT Calculations

    Science.gov (United States)

    Dabić, Dario; Brkljačić, Lidija; Tandarić, Tana; Žinić, Mladen; Vianello, Robert; Frkanec, Leo; Kobetić, Renata

    2018-01-01

    Gels formed by self-assembly of small organic molecules are of wide interest as dynamic soft materials with numerous possible applications, especially in terms of nanotechnology for functional and responsive biomaterials, biosensors, and nanowires. Four bis-oxalamides were chosen to show if electrospray ionization mass spectrometry (ESI-MS) could be used as a prediction of a good gelator and also to shed light on the gelation processes. By inspecting the gelation of several solvent, we showed that bis(amino acid)oxalamide 1 proved to be the most efficient, also being able of forming the largest observable assemblies in the gas phase. The formation of singly charged assemblies holding from one up to six monomer units is the outcome of the strong intermolecular H-bonds, particularly among terminal carboxyl groups. The variation of solvents from polar aprotic towards polar protic did not have any significant effects on the size of the assemblies. The addition of a salt such as NaOAc or Mg(OAc)2, depending on the concentration, altered the assembling. Computational analysis at the DFT level aided in the interpretation of the observed trends and revealed that individual gelator molecules spontaneously assemble to higher aggregates, but the presence of the Na+ cation disrupts any gelator organization since it becomes significantly more favorable for gelator molecules to bind Na+ cations up to the 3:1 ratio than to self-assemble, being fully in line with experimental observations reported here. [Figure not available: see fulltext.

  2. Oxalyl retro-peptide gelators. Synthesis, gelation properties and stereochemical effects.

    Science.gov (United States)

    Makarević, Janja; Jokić, Milan; Frkanec, Leo; Caplar, Vesna; Sijaković Vujičić, Nataša; Zinić, Mladen

    2010-10-04

    In this work we report on gelation properties, self-assembly motifs, chirality effects and morphological characteristics of gels formed by chiral retro-dipeptidic gelators in the form of terminal diacids (1a-5a) and their dimethyl ester (1b-5b) and dicarboxamide (1c-5c) derivatives. Terminal free acid retro-dipeptides (S,S)-bis(LeuLeu) 1a, (S,S)-bis(PhgPhg) 3a and (S,S)-bis(PhePhe) 5a showed moderate to excellent gelation of highly polar water/DMSO and water/DMF solvent mixtures. Retro-peptides incorporating different amino acids (S,S)-(LeuPhg) 2a and (S,S)-(PhgLeu) 4a showed no or very weak gelation. Different gelation effectiveness was found for racemic and single enantiomer gelators. The heterochiral (S,R)-1c diastereoisomer is capable of immobilizing up to 10 and 4 times larger volumes of dichloromethane/DMSO and toluene/DMSO solvent mixtures compared to homochiral (S,S)-1c. Based on the results of (1)H NMR, FTIR, CD investigations, molecular modeling and XRPD studies of diasteroisomeric diesters (S,S)-1b/(S,R)-1b and diacids (S,S)-1b/(S,R)-1a, a basic packing model in their gel aggregates is proposed. The intermolecular hydrogen bonding between extended gelator molecules utilizing both, the oxalamide and peptidic units and layered organization were identified as the most likely motifs appearing in the gel aggregates. Molecular modeling studies of (S,S)-1a/(S,R)-1a and (S,S)-1b/(S,R)-1b diasteroisomeric pairs revealed a decisive stereochemical influence yielding distinctly different low energy conformations: those of (S,R)-diastereoisomers with lipophilic i-Bu groups and polar carboxylic acid or ester groups located on the opposite sides of the oxalamide plane resembling bola amphiphilic structures and those of (S,S)-diasteroisomers possessing the same groups located at both sides of the oxalamide plane. Such conformational characteristics were found to strongly influence both, gelator effectiveness and morphological characteristics of gel aggregates.

  3. Oxalyl retro-peptide gelators. Synthesis, gelation properties and stereochemical effects

    Directory of Open Access Journals (Sweden)

    Janja Makarević

    2010-10-01

    Full Text Available In this work we report on gelation properties, self-assembly motifs, chirality effects and morphological characteristics of gels formed by chiral retro-dipeptidic gelators in the form of terminal diacids (1a–5a and their dimethyl ester (1b–5b and dicarboxamide (1c–5c derivatives. Terminal free acid retro-dipeptides (S,S-bis(LeuLeu 1a, (S,S-bis(PhgPhg 3a and (S,S-bis(PhePhe 5a showed moderate to excellent gelation of highly polar water/DMSO and water/DMF solvent mixtures. Retro-peptides incorporating different amino acids (S,S-(LeuPhg 2a and (S,S-(PhgLeu 4a showed no or very weak gelation. Different gelation effectiveness was found for racemic and single enantiomer gelators. The heterochiral (S,R-1c diastereoisomer is capable of immobilizing up to 10 and 4 times larger volumes of dichloromethane/DMSO and toluene/DMSO solvent mixtures compared to homochiral (S,S-1c. Based on the results of 1H NMR, FTIR, CD investigations, molecular modeling and XRPD studies of diasteroisomeric diesters (S,S-1b/(S,R-1b and diacids (S,S-1b/(S,R-1a, a basic packing model in their gel aggregates is proposed. The intermolecular hydrogen bonding between extended gelator molecules utilizing both, the oxalamide and peptidic units and layered organization were identified as the most likely motifs appearing in the gel aggregates. Molecular modeling studies of (S,S-1a/(S,R-1a and (S,S-1b/(S,R-1b diasteroisomeric pairs revealed a decisive stereochemical influence yielding distinctly different low energy conformations: those of (S,R-diastereoisomers with lipophilic i-Bu groups and polar carboxylic acid or ester groups located on the opposite sides of the oxalamide plane resembling bola amphiphilic structures and those of (S,S-diasteroisomers possessing the same groups located at both sides of the oxalamide plane. Such conformational characteristics were found to strongly influence both, gelator effectiveness and morphological characteristics of gel aggregates.

  4. Processes of international collaboration in management research

    DEFF Research Database (Denmark)

    Jonsen, Karsten; Butler, Christina; Mäkelä, Kristiina

    2013-01-01

    Scientists and academics increasingly work on collaborative projects and write papers in international research teams. This trend is driven by greater publishing demands in terms of the quality and breadth of data and analysis methods, which tend to be difficult to achieve without collaborating...... across institutional and national boundaries. Yet, our understanding of the collaborative processes in an academic setting and the potential tensions associated with them remains limited. We use a reflexive, autoethnographic approach to explicitly investigate our own experiences of international...... collaborative research. We offer systematic insights into the social and intellectual processes of academic collaborative writing, identifying six lessons and two key tensions that influence the success of international research teams. Our findings may benefit the formation of future coauthor teams...

  5. Streamlining the Bankability Process using International Standards

    Energy Technology Data Exchange (ETDEWEB)

    Kurtz, Sarah [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Repins, Ingrid L [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Kelly, George [Sunset Technology, Mount Airy, MD; Ramu, Govind [SunPower, San Jose, California; Heinz, Matthias [TUV Rheinland, Cologne, Germany; Chen, Yingnan [CGC (China General Certification Center), Beijing; Wohlgemuth, John [PowerMark, Union Hall, VA; Lokanath, Sumanth [First Solar, Tempe, Arizona; Daniels, Eric [Suncycle USA, Frederick MD; Hsi, Edward [Swiss RE, Zurich, Switzerland; Yamamichi, Masaaki [RTS, Trumbull, CT

    2017-09-27

    NREL has supported the international efforts to create a streamlined process for documenting bankability and/or completion of each step of a PV project plan. IECRE was created for this purpose in 2014. This poster describes the goals, current status of this effort, and how individuals and companies can become involved.

  6. Agency Agreements Process Champion Support Intern

    Science.gov (United States)

    Miksa, Ember

    2018-01-01

    This document will provide information on the 2018 Spring semester NIFS Intern who represented the Office of Chief Financial Officer (OCFO) as a Reimbursable Accountant at Kennedy Space Center (KSC). This intern supported the Agency Agreements Process Champions and Team Lead, Susan Kroskey, Sandy Massey and Mecca Murphy, with major initiatives to advance the KSC OCFO's vision of creating and innovating healthy financial management practices that maximize the value of resources entrusted to NASA. These initiatives include, but are not limited to: updating the Agency Guidance and NASA Procedural Guidance 9090.1 Agreements, implementing a new budget structure to be utilized across all centers, submitting a Call Request (CRQ) to enhance non-federal customer reporting, initiating a discussion to incorporate a 3-year funding program for NASA agreements, and undertaking the Office of Inspector General (OIG) Audit. In support of these initiatives, this intern identified technical methods to enhance and reduce the workload of financial processes for reimbursable and non-reimbursable agreements, prepared reports in support of accounting functions, and performed administrative work and miscellaneous technical tasks in support of the OCFO as requested. In conclusion of the internship, the intern will become knowledgeable on reimbursable accounting, reimbursable policy, types of reimbursable agreements, the agreements process, estimated pricing reports, and the roles and responsibilities of the Financial Accounting and Financial Services offices.

  7. Model-based internal wave processing

    Energy Technology Data Exchange (ETDEWEB)

    Candy, J.V.; Chambers, D.H.

    1995-06-09

    A model-based approach is proposed to solve the oceanic internal wave signal processing problem that is based on state-space representations of the normal-mode vertical velocity and plane wave horizontal velocity propagation models. It is shown that these representations can be utilized to spatially propagate the modal (dept) vertical velocity functions given the basic parameters (wave numbers, Brunt-Vaisala frequency profile etc.) developed from the solution of the associated boundary value problem as well as the horizontal velocity components. Based on this framework, investigations are made of model-based solutions to the signal enhancement problem for internal waves.

  8. Effect of the molecular weight of a neutral polysaccharide on soy protein gelation.

    Science.gov (United States)

    Monteiro, Sónia R; Lopes-da-Silva, José A

    2017-12-01

    The effects of galactomannans with different molecular weights on the heat-induced gelation characteristics of soybean protein were investigated using dynamic small-strain rheometry, under conditions where the proteins carry a net negative charge (pH7). Microstructure of the resulting gels was investigated by confocal laser scanning microscopy. Phase-separated systems were obtained with different morphologies and degree of phase separation, depending on both biopolymer concentrations and polysaccharide molecular weight. In general, a gelling enhancing effect on soy proteins was verified, despite extensive phase-separation processes observed at the higher polysaccharide molecular weight. This effect was demonstrated by an increase of the gelation rate, a decrease in the temperature at the onset of gelation, and an increase of gel stiffness and elastic character, with the length of polysaccharide chains. Overall, the results obtained established that the judicious selection of the galactomannan molecular weight may be used to modify the structure and gelation properties of soy proteins, originating a diversity of rheological characteristics and microstructures that will impact on the design of novel food formulations. Copyright © 2017 Elsevier Ltd. All rights reserved.

  9. Heat stability and acid gelation properties of calcium-enriched reconstituted skim milk affected by ultrasonication.

    Science.gov (United States)

    Chandrapala, Jayani; Bui, Don; Kentish, Sandra; Ashokkumar, Muthupandian

    2014-05-01

    The aggregation of proteins after heating of calcium-fortified milks has been an ongoing problem in the dairy industry. This undesirable effect restricts the manufacture of calcium rich dairy products. To overcome this problem, a completely new approach in controlling the heat stability of dairy protein solutions, developed in our lab, has been employed. In this approach, high intensity, low frequency ultrasound is applied for a very short duration after a pre-heating step at ⩾70 °C. The ultrasound breaks apart whey/whey and whey/casein aggregates through the process of acoustic cavitation. Protein aggregates do not reform on subsequent post-heating, thereby making the systems heat stable. In this paper, the acid gelation properties of ultrasonicated calcium-enriched skim milks have also been investigated. It is shown that ultrasonication alone does not change the gelation properties significantly whereas a sequence of preheating (72 °C/1 min) followed by ultrasonication leads to decreased gelation times, decreased gel syneresis and increased skim milk viscosity in comparison to heating alone. Overall, ultrasonication has the potential to provide calcium-fortified dairy products with increased heat stability. However, enhanced gelation properties can only be achieved when ultrasonication is completed in conjunction with heating.

  10. Gelation And Mechanical Response of Patchy Rods

    Science.gov (United States)

    Kazem, Navid; Majidi, Carmel; Maloney, Craig

    We perform Brownian Dynamics simulations to study the gelation of suspensions of attractive, rod-like particles. We show that details of the particle-particle interactions can dramatically affect the dynamics of gelation and the structure and mechanics of the networks that form. If the attraction between the rods is perfectly smooth along their length, they will collapse into compact bundles. If the attraction is sufficiently corrugated or patchy, over time, a rigid space spanning network forms. We study the structure and mechanical properties of the networks that form as a function of the fraction of the surface that is allowed to bind. Surprisingly, the structural and mechanical properties are non-monotonic in the surface coverage. At low coverage, there are not a sufficient number of cross-linking sites to form networks. At high coverage, rods bundle and form disconnected clusters. At intermediate coverage, robust networks form. The elastic modulus and yield stress are both non-monotonic in the surface coverage. The stiffest and strongest networks show an essentially homogeneous deformation under strain with rods re-orienting along the extensional axis. Weaker, clumpy networks at high surface coverage exhibit relatively little re-orienting with strong non-affine deformation. These results suggest design strategies for tailoring surface interactions between rods to yield rigid networks with optimal properties. National Science Foundation and the Air Force Office of Scientific Research.

  11. 2016 International Conference on Software Process Improvement

    CERN Document Server

    Muñoz, Mirna; Rocha, Álvaro; Feliu, Tomas; Peña, Adriana

    2017-01-01

    This book offers a selection of papers from the 2016 International Conference on Software Process Improvement (CIMPS’16), held between the 12th and 14th of October 2016 in Aguascalientes, Aguascalientes, México. The CIMPS’16 is a global forum for researchers and practitioners to present and discuss the most recent innovations, trends, results, experiences and concerns in the different aspects of software engineering with a focus on, but not limited to, software processes, security in information and communication technology, and big data. The main topics covered include: organizational models, standards and methodologies, knowledge management, software systems, applications and tools, information and communication technologies and processes in non-software domains (mining, automotive, aerospace, business, health care, manufacturing, etc.) with a clear focus on software process challenges.

  12. THE INTERNAL AUDIT AS COGNITIVE PROCESS

    Directory of Open Access Journals (Sweden)

    D. Petrascu

    2016-11-01

    Full Text Available The term AUDIT generally comes from the Latin word "audire" to listen and to inform others, from today's Anglo-Saxon countries, this term has the meaning of a revision of the accounting information and of those of a different nature, realized by an independent professional, in view of expressing an opinion regarding the regularity and honesty of the audited information (1 §tefan Craciun, Audit financiar §i audit intern, The Economic Publishing House, Bucharest, 2004, page 22. In a general register, an audit has the purpose to grant an entity added value by a systematic and methodic approach, evaluating the risk management processes, the control processes and the governing processes, all of which are materialized within an objective and professional report.

  13. International Political Processes of Integration of Education

    Directory of Open Access Journals (Sweden)

    Marina M. Lebedeva

    2017-09-01

    Full Text Available Introduction: the study of the international dimension of education is usually reduced to a comparative analysis of the characteristics of education in different countries. The situation began to change at the end of 20th – beginning of 21st centuries due to the rapid development of globalisation processes (the formation of a transparency of national borders and integration (deepening the cooperation between countries based on intergovernmental agreements. It had an impact on education, which was intensively internationalised (to acquire a wide international dimension. Despite the possible setbacks the process of internationalisation of education, the general vector of development is that this process will increase. The purpose of this article is to analyse what new challenges and opportunities are opened due to internationalisation of education (Russian education in particular. Materials and Methods: the study is based on the principles according to which education, on the one hand, depends on the transformation of the global political organisation of the world, on another hand – it is contributing to this transformation. Materials for the study are based on international agreements, which in particular are adopted in the framework of the Bologna process, and the results of scientific works of Russian and foreign scholars. Descriptive and comparative metho ds of analysis are widely used. Results: the analysis of the processes of internationalisation of education in the world has shown that, along with its traditional directions and aspects. It was noted that university begins to play a special role in the current world. It is shown that the specificity of education in Russia, which took shape due to a large terri¬tory and historical traditions, should be taken into account when forming a strategy for the development of the internationalisation of education in the country. Discussion and Conclusions: the specificity of Russia creates a risk

  14. Ultrasound- and Temperature-Induced Gelation of Gluconosemicarbazide Gelator in DMSO and Water Mixtures

    Directory of Open Access Journals (Sweden)

    Mothukunta Himabindu

    2017-04-01

    Full Text Available We have developed amphiphilic supramolecular gelators carrying glucose moiety that could gel a mixture of dimethyl sulfoxide (DMSO and water upon heating as well as ultrasound treatment. When the suspension of gluconosemicarbazide was subjected to ultrasound treatment, gelation took place at much lower concentrations compared to thermal treatment, and the gels transformed into a solution state at higher temperatures compared to temperature-induced gels. The morphology was found to be influenced by the nature of the stimulus and presence of salts such as KCl, NaCl, CaCl2 and surfactant (sodium dodecyl sulphate at a concentration of 0.05 M. The gel exhibited impressive tolerance to these additives, revealing the stability and strength of the gels. Fourier transform infrared spectroscopy (FTIR revealed the presence of the intermolecular hydrogen bonding interactions while differential scanning calorimetry (DSC and rheological studies supported better mechanical strength of ultrasound-induced (UI gels over thermally-induced (TI gels.

  15. Study of the gelation behaviour of Brazilian waxy crude oils

    Energy Technology Data Exchange (ETDEWEB)

    Ziglio, C.M.; Sant' Ana, D.F. [Petroleo Brasileiro S.A., Petrobras, Rio de Janeiro (Brazil)

    2008-07-01

    The precipitation of wax from crude oil results in the formation of a paraffin network which evolves into a gel structure, causing a major operating issue for the petroleum industry. A gelled oil in a pipeline may need a very high re-start pressure that is beyond the capacity of the pump. The gelation of the oil can also develop into a wax deposit on the pipeline wall that restricts the flow of crude oil. Rheometry tests were used in this study to determine the yielding process of wax gels formed by the cooling of Brazilian crude oils. The effect of selected chemical additives on the gel strength was also examined. Dynamic rheology was used to study the oil-gel transition under quiescent conditions. Two rheological methods were used to study the gel yield stress, which is related to the gel strength. In the Creep and Recovery method, a stress was applied to the sample for a short period while the resulting deformation was measured. The stress was then removed to allow the sample to recover the gel structure. The steps of creep and recovery were repeated with an increasing stress value. The yield stress was identified as the minimum stress to cause an irreversible deformation in the sample. The yield stress of the gelled oil was estimated through dynamic measurements. Gel breakdown occurred when the sample was submitted to a critical strain, which is related to the yield stress value. This study showed that the gelation temperature can be reduced considerably by adding small amounts of readily available additives. These additives have an influence on yield stress values. In a cold re-start situation, they can reduce the pump pressure.

  16. Preparation of ThO2 sols having colloid-size distributions suitable for gelation into microspheres

    International Nuclear Information System (INIS)

    Yamagishi, Shigeru; Takahashi, Yoshihisa; Shiba, Koreyuki

    1984-01-01

    Production conditions of ThO 2 sols suitable for gelling into crackfree microspheres in an external gelation process were studied. The sols were prepared under pH control and colloid size distributions of the resulting sols were determined. The gelation was carried out by using hexone as a drop formation medium and ammonia as a gelling agent. The crackfree gelation was achieved by the use of ThO 2 sols produced under favorable pH, which were large in colloid size and high in colloid fraction. ''Preneutralization'' preceding the pH control is also important for the good sols. Analyzing the colloid fraction, colloid size and crystallite size of sol, it was found that, under the favorable pH, colloid nuclei generating at early stages grow in the form of single-crystals with their number kept constant and, after cooling, they exist as polycrystalline colloids. The mechanism of cracking is also discussed. (author)

  17. Internal Heterogeneous Processes in Aluminum Combustion

    Science.gov (United States)

    Dreizin, E. L.

    1999-01-01

    This paper discusses the aluminum particle combustion mechanism which has been expanded by inclusion of gas dissolution processes and ensuing internal phase transformations. This mechanism is proposed based on recent normal and microgravity experiments with particles formed and ignited in a pulsed micro-arc. Recent experimental findings on the three stages observed in Al particle combustion in air and shows the burning particle radiation, trajectory (streak), smoke cloud shapes, and quenched particle interiors are summarized. During stage I, the radiation trace is smooth and the particle flame is spherically symmetric. The temperature measured using a three-color pyrometer is close to 3000 K. Because it exceeds the aluminum boiling point (2730 K), this temperature most likely characterizes the vapor phase flame zone rather than the aluminum surface. The dissolved oxygen content within particles quenched during stage I was below the detection sensitivity (about 1 atomic %) for Wavelength Dispersive Spectroscopy (WDS). After an increase in the radiation intensity (and simultaneous decrease in the measured color temperature from about 3000 to 2800 K) indicative of the transition to stage II combustion, the internal compositions of the quenched particles change. Both oxygen-rich (approx. 10 atomic %) and oxygen-lean (combustion behavior and the evolution of its internal composition, the change from the spherically symmetric to asymmetric flame shape occurring upon the transition from stage I to stage II combustion could not be understood based only on the fact that dissolved oxygen is detected in the particles. The connection between the two phenomena appeared even less significant because in earlier aluminum combustion studies carried in O2/Ar mixtures, flame asymmetry was not observed as opposed to experiments in air or O2/CO mixtures. It has been proposed that the presence of other gases, i.e., hydrogen, or nitrogen causes the change in the combustion regime.

  18. Processes of Internal and International Migration from Chitwan, Nepal.

    Science.gov (United States)

    Bohra, Pratikshya; Massey, Douglas S

    2009-01-01

    In this study we examine which factors predict internal and international migration from Chitwan, a flat valley located in the South-Central region of Nepal, seeking to measure the effect of theoretically specified variables such as human capital, social capital, physical capital, and neighborhood socioeconomic conditions while controlling for demographic variables. We use data from the Chitwan Valley Family Study (CVFS) to estimate a series of discrete time event history models of first and repeat migration to three competing destinations: other locations within Chitwan, other districts within Nepal, and places outside of Nepal. Results support hypotheses derived from neoclassical economics, the theory of new economics of migration, social capital theory, and cumulative causation theory. Our results underscore the need for a synthetic theoretical model that incorporates factors operating at the individual, household, and community levels. The use of multiple explanatory models yields a clearer picture of the forces driving internal and international migration from rural districts in developing nations such as Nepal.

  19. Permit processes for nuclear power. International lessons

    International Nuclear Information System (INIS)

    Gaahlin, Emil; Nilsson, Isabelle; Pettersson, Maria; Soederholm, Patrik

    2010-01-01

    permitting process in the country as well as important planned (or recently introduced) changes in the relevant legislation. The analysis also presents the role of the regulating authorities as well as other key actors in the process, and outlines the different steps of the permitting processes, including the relationships between the different permits. We also address the responsibility for the radioactive waste and dismantling, and how these issues come into the licensing process. Important differences and similarities across the various countries are highlighted, with special emphasis on parallels to the Swedish legislation. The report then analyzes a number of important legal and political issues of a principal nature in the permitting of nuclear power plants. We compare how the different countries differ on these grounds, and also emphasize some overall lessons and practical experiences of nuclear power development internationally. Three broad issues are discussed. The first of these concerns the notion of nuclear power as a highly political issue, and we analyze the role of the public opinion, the extent to which the regulatory process is independent of policy decisions, as well as the allocation of political power between the national and local levels in the respective countries. Not the least the last issue has been in focus in some of the countries that have reformed their permitting process, and there exist significant inter-country differences. The second issue concerns how a number of countries - most notably the USA and Great Britain - have attempted to streamline their plant permitting processes for new nuclear power. These reforms are characterized by, for instance, a combined construction and operation license, the selection (and exclusion) of geographical locations for new installations, as well as attempts to achieve standardizations of nuclear reactor designs. We pay particular attention to the issues of reactor design standardization, including the scope

  20. Factors influencing chymosin-induced gelation of milk from individual dairy cows

    DEFF Research Database (Denmark)

    Gustavsson, F.; Glantz, M; Buitenhuis, Albert Johannes

    2014-01-01

    the variation of gelation properties in this sample set. Non-coagulating milk was suggested to have lower ionic and total calcium content as well as lower relative concentrations of β-lactoglobulin than coagulating milk. The lower total calcium content in non-coagulating milk poses a problem as the difference...... calcium content, phosphorous content and casein micelle size on chymosin-induced gelation was determined in milk from 98 Swedish Red cows. The study showed that protein content and total calcium content, ionic calcium concentration and casein micelle size were the most important factors explaining...... was, theoretically, four times larger than the amount of calcium that is normally added in cheese processing...

  1. Pectin gelation with chlorhexidine: Physico-chemical studies in dilute solutions.

    Science.gov (United States)

    Lascol, Manon; Bourgeois, Sandrine; Guillière, Florence; Hangouët, Marie; Raffin, Guy; Marote, Pedro; Lantéri, Pierre; Bordes, Claire

    2016-10-05

    Low methoxyl pectin is known to gel with divalent cations (e.g. Ca(2+), Zn(2+)). In this study, a new way of pectin gelation in the presence of an active pharmaceutical ingredient, chlorhexidine (CX), was highlighted. Thus chlorhexidine interactions with pectin were investigated and compared with the well-known pectin/Ca(2+) binding model. Gelation mechanisms were studied by several physico-chemical methods such as zeta potential, viscosity, size measurements and binding isotherm was determined by Proton Nuclear Magnetic Resonance Spectroscopy ((1)H NMR). The binding process exhibited similar first two steps for both divalent ions: a stoichiometric monocomplexation of the polymer followed by a dimerization step. However, stronger interactions were observed between pectin and chlorhexidine. Moreover, the dimerization step occurred under stoichiometric conditions with chlorhexidine whereas non-stoichiometric conditions were involved with calcium ions. In the case of chlorhexidine, an additional intermolecular binding occurred in a third step. Copyright © 2016 Elsevier Ltd. All rights reserved.

  2. Nozzleless Fabrication of Oil-Core Biopolymeric Microcapsules by the Interfacial Gelation of Pickering Emulsion Templates.

    Science.gov (United States)

    Leong, Jun-Yee; Tey, Beng-Ti; Tan, Chin-Ping; Chan, Eng-Seng

    2015-08-05

    Ionotropic gelation has been an attractive method for the fabrication of biopolymeric oil-core microcapsules due to its safe and mild processing conditions. However, the mandatory use of a nozzle system to form the microcapsules restricts the process scalability and the production of small microcapsules (microcapsules through ionotropic gelation at the interface of an O/W Pickering emulsion. This approach involves the self-assembly of calcium carbonate (CaCO3) nanoparticles at the interface of O/W emulsion droplets followed by the addition of a polyanionic biopolymer into the aqueous phase. Subsequently, CaCO3 nanoparticles are dissolved by pH reduction, thus liberating Ca(2+) ions to cross-link the surrounding polyanionic biopolymer to form a shell that encapsulates the oil droplet. We demonstrate the versatility of this method by fabricating microcapsules from different types of polyanionic biopolymers (i.e., alginate, pectin, and gellan gum) and water-immiscible liquid cores (i.e., palm olein, cyclohexane, dichloromethane, and toluene). In addition, small microcapsules with a mean size smaller than 100 μm can be produced by selecting the appropriate conventional emulsification methods available to prepare the Pickering emulsion. The simplicity and versatility of this method allows biopolymeric microcapsules to be fabricated with ease by ionotropic gelation for numerous applications.

  3. Acid-Induced Cold Gelation of Globular Proteins: Effects of Protein Aggregate Characteristics and Disulfide Bonding on Rheological Properties

    NARCIS (Netherlands)

    Alting, A.C.; Weijers, M.; Hoog, E.H.A. de; Pijpekamp, A.M. van de; Cohen Stuart, M.A.; Hamer, R.J.; Kruif, C.G. de; Visschers, R.W.

    2004-01-01

    The process of cold gelation of ovalbumin and the properties of the resulting cold-set gels were compared to those of whey protein isolate. Under the chosen heating conditions, most protein was organized in aggregates. For both protein preparations, the aggregates consisted of covalently linked

  4. Organic Gelators as Growth Control Agents for Stable and Reproducible Hybrid Perovskite-Based Solar Cells

    KAUST Repository

    Masi, Sofia

    2017-03-03

    Low-molecular-weight organic gelators are widely used to influence the solidification of polymers, with applications ranging from packaging items, food containers to organic electronic devices, including organic photovoltaics. Here, this concept is extended to hybrid halide perovskite-based materials. In situ time-resolved grazing incidence wide-angle X-ray scattering measurements performed during spin coating reveal that organic gelators beneficially influence the nucleation and growth of the perovskite precursor phase. This can be exploited for the fabrication of planar n-i-p heterojunction devices with MAPbI3 (MA = CH3NH3+) that display a performance that not only is enhanced by ≈25% compared to solar cells where the active layer is produced without the use of a gelator but that also features a higher stability to moisture and a reduced hysteresis. Most importantly, the presented approach is straightforward and simple, and it provides a general method to render the film formation of hybrid perovskites more reliable and robust, analogous to the control that is afforded by these additives in the processing of commodity “plastics.”

  5. A dynamic balanced scorecard for identification internal process factor

    Directory of Open Access Journals (Sweden)

    Javad sofiyabadi

    2012-08-01

    Full Text Available We present a dynamic balanced score card (BSC to investigate the strategic internal process management factors. The proposed dynamic BSC emphasizes on internal processes aspect, and using VIKOR and Shannon Entropy, determinants the internal processes, process management and improvement and all important factors are ranked. The current study first introduces dynamic BSC and examines effective factors on the process. The proposed model focuses on internal processes perspective of BSC and determines importance degree of each factor is used using VIKOR decision-making techniques.

  6. Using Reporting in the Internal Communication Process of the Company

    OpenAIRE

    Cornel Marian Iosif

    2013-01-01

    Internal communication can be regarded either as a subsistent process of the organization, or as a process helping to decode and more easily understand them. Organizations are based on the internal communication process, because without it, information, ideas could not be sent, the organization’s goals and values could not be built, and its organizational culture would simply not exist. The internal communication process is centered on sending ideas, information in the organization. Thi...

  7. Automated Internal Revenue Processing System: A Panacea For ...

    African Journals Online (AJOL)

    Automated Internal Revenue Processing System: A Panacea For Financial ... for the collection and management of internal revenue which is the financial ... them, computational errors, high level of redundancy and inconsistencies in record, ...

  8. Washing of Uranium Gel Resulted from Gelation Using Ammonia

    International Nuclear Information System (INIS)

    Nurwijayadi; Bangun-Wasito; Sukarsono; Endang-Nawangsih

    2000-01-01

    Washing of uranium gel resulted from gelation using ammonia underconcentration of 1, 2.5, 3, 4 and 5 % has been carried out. The sol wasprepared by reacting uranyl nitrate, urea and HMTA at 5 o C. The resulted solwas dropped into a column containing paraffin oil at temperature of 95 o C.The resulted gel color was orange. It was simmered in a 2.5 % ammoniasolution for 24 hours. After that, the gel was washed in an ammonia solutionunder a concentration variation. The best washing process occurred at ammoniaconcentration of 2.5 % with most absorbed ion nitrate, i.e. 292.2 ppm. Theresulted true density using N 2 was about 8.3 - 8.6 g/ml, specific surfacearea using multi point BET was about 1.5 - 3.1 m 2 /g, average pore radius was22.27 -41.22 A and total pore volume was 3.55 x 10 -3 cc/g. (author)

  9. Proceedings of XXIV international mineral processing congress

    Energy Technology Data Exchange (ETDEWEB)

    Wang Dianzuo; Sun Chuan Yao; Wang Fu Liang; Zhang Li Cheng; Han Long (eds.)

    2008-07-01

    Topics covered in volume 1 include applied mineralogy, comminution, classification, physical separation, flotation chemistry, sulphide flotation, non-sulphide flotation and reagent in mineral industry. Volume 2 covers processing of complex ores, processing of industrial minerals and coal, solid liquid separation, dispersion and aggregation, process simulation, expert systems and control of mineral processing, biohydrometallurgy, and mineral chemical processing. Volume 3 contains powder technology, mineral materials, treatment and recycling for solid wastes, waste water treatment, secondary resource recovery, soil remediation, concentrator engineering and process design, and application of mineral processing in related industry. It includes a CD-ROM of the proceedings.

  10. In Situ Observations of Thermoreversible Gelation and Phase Separation of Agarose and Methylcellulose Solutions under High Pressure.

    Science.gov (United States)

    Kometani, Noritsugu; Tanabe, Masahiro; Su, Lei; Yang, Kun; Nishinari, Katsuyoshi

    2015-06-04

    Thermoreversible sol-gel transitions of agarose and methylcellulose (MC) aqueous solutions on isobaric cooling or heating under high pressure up to 400 MPa have been investigated by in situ observations of optical transmittance and falling-ball experiments. For agarose, which undergoes the gelation on cooling, the application of pressure caused a gradual rise in the cloud-point temperature over the whole pressure range examined, which is almost consistent with the pressure dependence of gelling temperature estimated by falling-ball experiments, suggesting that agarose gel is stabilized by compression and that the gelation occurs nearly in parallel with phase separation under ambient and high-pressure conditions. For MC, which undergoes the gelation on heating, the cloud-point temperature showed a slight rise with an initial elevation of pressure up to ∼150 MPa, whereas it showed a marked depression above 200 MPa. In contrast, the gelling temperature of MC, which is nearly identical to the cloud-point temperature at ambient pressure, showed a monotonous rise with increasing pressure up to 350 MPa, which means that MC undergoes phase separation prior to gelation on heating under high pressure above 200 MPa. Similar results were obtained for the melting process of MC gel on cooling. The unique behavior of the sol-gel transition of MC under high pressure has been interpreted in terms of the destruction of hydrophobic hydration by compression.

  11. Silica-gel structural characterization during the initial phases of gelation and drying

    International Nuclear Information System (INIS)

    Ferreira, Max Passos

    1996-01-01

    For centuries, glasses and ceramics have been made via melting or solid state reactions at temperatures above 100 deg C. The sol-gel process offers new approaches to the synthesis of glasses and ceramics, combining control of composition and structure at the molecular level with the ability to shape materials in bulk, powder, fiber and thin-film forms. The growth of sol-gel technology research is due to the many unique features of that class of materials. Major applications include optical elements and integrated optical devices, ceramic filters, membranes, supercondutors, magnetic, catalytic and manostructured materials to antioxidant, anticorrosion coatings and composite and biomedical materials. In this work a variety of techniques like spectroscopy, Raman spectroscopy, ultraviolet-visible spectroscopy, light scattering nuclear magnetic resonance, X ray diffraction and nitrogen adsorption have been employed to investigate the initial phase of the sol-gel transition of gamma ray irradiated tetramethoxysilane (TMOS) solutions and non-irradiated TMOS solution and to get information about the structure of the silica gels obtained under different gelation conditions. Typically the tetramethoxysilane solutions were prepared using a molar ratio of TMOS to demineralized water of 1 to 16. Some experiments were made under catalysed conditions. The mixing was carried out at room temperature. The turbidity and light scattering experiments on the polycondensation of tetramethoxysilane show that exists no drastic difference in the gelling time of a gamma ray irradiated and a non-irradiated TMOS+H 2 O (1+16 M) solution. In the absence of a catalyst, the gelling time for both reactions occurs in about 3.30 h. When HNO 3 (o.03 M) was used, the gelling time observed was 3 days. Raman and ultraviolet-visible spectroscopy show no drastic difference during the initial phase at the sol-gel transition under ambient temperature/pressure and under gamma radiation. The gels heated

  12. Internal Decoupling in Nonlinear Process Control

    Directory of Open Access Journals (Sweden)

    Jens G. Balchen

    1988-07-01

    Full Text Available A simple method has been investigated for the total or partial removal of the effect of non-linear process phenomena in multi-variable feedback control systems. The method is based upon computing the control variables which will drive the process at desired rates. It is shown that the effect of model errors in the linearization of the process can be partly removed through the use of large feedback gains. In practice there will be limits on how large gains can he used. The sensitivity to parameter errors is less pronounced and the transient behaviour is superior to that of ordinary PI controllers.

  13. Research on Business Process Outsourcing | IDRC - International ...

    International Development Research Centre (IDRC) Digital Library (Canada)

    The business process outsourcing (BPO) sector, worth over $130 billion ... Call for new OWSD Fellowships for Early Career Women Scientists now open ... Addressing Africa's unmet need for family planning by intensifying sexual and ...

  14. Process Coordination and Policy Officer | IDRC - International ...

    International Development Research Centre (IDRC) Digital Library (Canada)

    Such liaison aims to ensure that the operational aspects and requirements are taken into account. ... Business Process Coordination and Change Management ... Liaises with the Resources Planning and Development Officer of the Office of ...

  15. Process Coordination & Policy Officer | IDRC - International ...

    International Development Research Centre (IDRC) Digital Library (Canada)

    Such liaison aims to ensure that the operational aspects and requirements are taken into account. ... Business Process Coordination and Change Management ... plan and coordinating the update of the Division's work plan by all managers; ...

  16. 8 CFR 287.10 - Expedited internal review process.

    Science.gov (United States)

    2010-01-01

    ... jurisdiction regarding criminal violations of law. [68 FR 35281, June 13, 2003] ... 8 Aliens and Nationality 1 2010-01-01 2010-01-01 false Expedited internal review process. 287.10... OFFICERS; POWERS AND DUTIES § 287.10 Expedited internal review process. (a) Violations of standards for...

  17. Comparison of the sickling and gelation properties of acidic ...

    African Journals Online (AJOL)

    The effects of acidic metabolites of A. vera and C. cajan extracts on the sickling and gelation times of human HbSS erythrocytes were investigated to obtain a better understanding of the anti-sickling compounds contained in them for use in the management of sickle cell disease. The results obtained showed that the acidic ...

  18. Use of different additives to improve low quality surimi gelation.

    Directory of Open Access Journals (Sweden)

    Deysi Cando

    2014-06-01

    In conclusion, in general, the physicochemical and viscoelastic properties of gels were improved by the addition of both ingredients, giving stronger gels even at very low level of salt. These results indicate that both ingredients, which do not add calories to the final gels, can be used as a good alternative for the better gelation of the low quality surimis.

  19. Conductive Screen Printing Inks by Gelation of Graphene Dispersions

    NARCIS (Netherlands)

    Arapov, K.; Rubingh, E.; Abbel, R.J.; Laven, J.; With, G. de; Friedrich, H.

    2016-01-01

    This paper describes the gelation of highly concentrated graphene/polymer dispersions triggered by mild heating. The gel formation is only dependent on the concentration of graphene with 3.25 mg mL-1 as the minimum value for graphene network formation. The graphene gel is then utilized for the

  20. Internal control in the management system of meat processing enterprises

    Directory of Open Access Journals (Sweden)

    Volodymyr Kushnir

    2018-03-01

    Full Text Available The article is described the theoretical basis of internal control and its practical aspects in the work of meat processing enterprises (a case in the meat processing industry in Ukraine. The purpose of the research is to establish the theoretical foundations of the internal control and its improvement in the activity of meat processing plants of various forms of management. It is proposed to use precisely internal control among other names of domestic control. Definition of internal control, its subject and purpose are improved. The subjects and objects of internal control are determined; the principles of its implementation are supplemented. Specific control tasks in meat processing plants according to the needs of this industry are outlined. Specific examples of control subjects are presented and the role of the revision commission is emphasized. The state of internal control in meat processing plants in Ukraine is investigated and it is established that it has a bad condition and unfounded approach to its implementation by managers of meat processing enterprises. To improve the situation we recommend that each meat processing enterprise have in its staff a revision commission or an apposer (auditor. It is established that internal control is more effective in joint-stock companies than in limited liability companies. The necessity of internal control as an important element in the enterprise management system is accented.

  1. Summary of the International Conference on Software and System Processes

    DEFF Research Database (Denmark)

    Kuhrmann, Marco; O'Connor, Rory V.; Perry, Dewayne E.

    2016-01-01

    The International Conference on Software and Systems Process (ICSSP), continuing the success of Software Process Workshop (SPW), the Software Process Modeling and Simulation Workshop (ProSim) and the International Conference on Software Process (ICSP) conference series, has become the established...... premier event in the field of software and systems engineering processes. It provides a leading forum for the exchange of research outcomes and industrial best-practices in process development from software and systems disciplines. ICSSP 2016 was held in Austin, Texas, from 14-15 May 2016, co......-located with the 38th International Conference on Software Engineering (ICSE). The theme of mICSSP 2016 was studying "Process(es) in Action" by recognizing that the AS-Planned and AS-Practiced processes can be quite different in many ways including their ows, their complexity and the evolving needs of stakeholders...

  2. International Student Mobility and the Bologna Process

    Science.gov (United States)

    Teichler, Ulrich

    2012-01-01

    The Bologna Process is the newest of a chain of activities stimulated by supra-national actors since the 1950s to challenge national borders in higher education in Europe. Now, the ministers in charge of higher education of the individual European countries have agreed to promote a similar cycle-structure of study programmes and programmes based…

  3. Galaxy formation: internal mechanisms and cosmological processes

    International Nuclear Information System (INIS)

    Martig, Marie

    2010-01-01

    This thesis is devoted to galaxy formation and evolution in a cosmological context. Cosmological simulations have unveiled two main modes of galaxy growth: hierarchical growth by mergers and accretion of cold gas from cosmic filaments. However, these simulations rarely take into account small scale mechanisms, that govern internal evolution and that are a key ingredient to understand galaxy formation and evolution. Thanks to a new simulation technique that I have developed, I first studied the colors of galaxies, and in particular the reddening of elliptical galaxies. I showed that the gas disk in an elliptical galaxy could be stabilized against star formation because of the galaxy's stellar component being within a spheroid instead of a disk. This mechanism can explain the red colors of some elliptical galaxies that contain a gas disk. I also studied the formation of spiral galaxies: most cosmological simulations cannot explain the formation of Milky Way-like galaxies, i.e. with a large disk and a small bulge. I showed that this issue could be partly solved by taking into account in the simulations the mass loss from evolved stars through stellar winds, planetary nebulae and supernovae explosions. (author) [fr

  4. Towards a fully synthetic substitute of alginate: optimization of a thermal gelation/chemical cross-linking scheme ("tandem" gelation) for the production of beads and liquid-core capsules.

    Science.gov (United States)

    Cellesi, F; Weber, W; Fussenegger, M; Hubbell, J A; Tirelli, N

    2004-12-20

    Fully synthetic polymers were used for the preparation of hydrogel beads and capsules, in a processing scheme that, originally designed for calcium alginate, was adapted to a "tandem" process, that is the combination a physical gelation with a chemical cross-linking. The polymers feature a Tetronic backbone (tetra armed Pluronics), which exhibits a reverse thermal gelation in water solutions within a physiological range of temperatures and pHs. The polymers bear terminal reactive groups that allow for a mild, but effective chemical cross-linking. Given an appropriate temperature jump, the thermal gelation provides a hardening kinetics similar to that of alginate. With slower kinetics, the chemical cross-linking then develops an irreversible and elastic gel structure, and determines its transport properties. In the present article this process has been optimized for the production of monodisperse, high elastic, hydrogel microbeads, and liquid-core microcapsules. We also show the feasibility of the use of liquid-core microcapsules in cell encapsulation. In preliminary experiments, CHO cells have been successfully encapsulated preserving their viability during the process and after incubation. The advantages of this process are mainly in the use of synthetic polymers, which provide great flexibility in the molecular design. This, in principle, allows for a precise tailoring of mechanical and transport properties and of bioactivity of the hydrogels, and also for a precise control in material purification.

  5. Inhibition and Promotion of Heat-Induced Gelation of Whey Proteins in the Presence of Calcium by Addition of Sodium Caseinate.

    Science.gov (United States)

    Nguyen, Bach T; Balakrishnan, Gireeshkumar; Jacquette, Boris; Nicolai, Taco; Chassenieux, Christophe; Schmitt, Christophe; Bovetto, Lionel

    2016-11-14

    Heat-induced aggregation and gelation of aqueous solutions of whey protein isolate (WPI) in the presence of sodium caseinate (SC) and CaCl 2 was studied at pH 6.6. The effect of adding SC (0-100 g/L) on the structure of the aggregates and the gels was investigated by light scattering and confocal laser scanning microscopy at different CaCl 2 concentration ([CaCl 2 ] = 0-30 mM). The gelation process was studied by oscillatory shear rheology. At the whey protein concentrations studied here (34 and 60 g/L), no gels were formed in the absence of CaCl 2 and SC. However, WPI solutions gelled above a critical CaCl 2 concentration that increased with increasing SC concentration. In the absence of CaCl 2 , WPI gels were formed only above a critical SC concentration. The critical SC concentration needed to induce WPI gelation decreased weakly when CaCl 2 was added. In an intermediate range of CaCl 2 concentrations, gels were formed both at low and high SC concentrations, but not at intermediate SC concentrations. Finally, at high CaCl 2 concentrations gels were formed at all SC concentrations. The gelation rate and the gel structure of the gels formed at low and high casein concentrations were very different. The effect of SC on the thermal gelation of WPI was interpreted by competition for Ca 2+ , a chaperon effect, and microphase separation.

  6. Effect of food additives on egg yolk gelation induced by freezing.

    Science.gov (United States)

    Primacella, Monica; Fei, Tao; Acevedo, Nuria; Wang, Tong

    2018-10-15

    This study demonstrates technological advances in preventing yolk gelation during freezing and thawing. Gelation negatively affects yolk functionality in food formulation. Preventing gelation using 10% salt or sugar limits the application of the yolk. Novel food additives were tested to prevent gelation induced by freezing. Significant reduction (p freezing at -20 °C) indicates that hydrolyzed carboxymethyl cellulose (HCMC), proline, and hydrolyzed egg white and yolk (HEW and HEY) are effective gelation inhibitors. The mechanisms in which these additives prevented gelation were further studied through measuring the changes in the amount of freezable water, lipoprotein particle size, and protein surface hydrophobicity. Overall, this study provides several alternatives of gelation inhibitor that have great potentials in replacing the use of salt or sugar in commercial operation of freezing egg yolk for shelf-life extension. Copyright © 2018 Elsevier Ltd. All rights reserved.

  7. The International Criminal Court and Peace Processes in Africa

    DEFF Research Database (Denmark)

    Gissel, Line Engbo

    justice, while also tracing how and why international decision-making processes interfered with the negotiations, narrated the conflicts and insisted on a narrow scope of justice. Building on this interpretive analysis, a comparative analysis of peace processes in Uganda, Kenya and Colombia explores a set......The book investigates how involvement by the International Criminal Court (ICC) affects efforts to negotiate peace. It offers an interpretive account of how peace negotiators and mediators in two peace processes in Uganda and Kenya sought to navigate and understand the new terrain of international...... of general features pertaining to the judicialisation of peace....

  8. The Influence of Geopolitical Processes on Functioning of International Enterprises

    OpenAIRE

    Gawlik, Remigiusz

    2012-01-01

    The paper presents the influence of geopolitical processes on management of international enterprises. Basic geopolitical and managerial notions have been defined. The paper contains also a brief historical overview of development of geopolitics as a science. Key subjects of international law have been described. The author aims at attiring attention to the meaning of geopolitical issues for enterprise’s strategic planning phase and in consecutive managerial phases in international companies.

  9. IEEE International Workshop on Machine Learning for Signal Processing: Preface

    DEFF Research Database (Denmark)

    Tao, Jianhua

    The 21st IEEE International Workshop on Machine Learning for Signal Processing will be held in Beijing, China, on September 18–21, 2011. The workshop series is the major annual technical event of the IEEE Signal Processing Society's Technical Committee on Machine Learning for Signal Processing...

  10. CM Process Improvement and the International Space Station Program (ISSP)

    Science.gov (United States)

    Stephenson, Ginny

    2007-01-01

    This viewgraph presentation reviews the Configuration Management (CM) process improvements planned and undertaken for the International Space Station Program (ISSP). It reviews the 2004 findings and recommendations and the progress towards their implementation.

  11. LABORATORY-SCALE PRODUCTION OF ADU GELS BY EXTERNAL GELATION FOR AN INTERMEDIATE HTGR NUCLEAR

    Directory of Open Access Journals (Sweden)

    S Simbolon

    2015-03-01

    Full Text Available LABORATORY-SCALE PRODUCTION OF ADU GELS BY EXTERNAL GELATION FOR AN INTERMEDIATE HTGR NUCLEAR. The The aim of this research is to produce thousands of microsphere ADU (Ammonium Diuranate gels by using external gelation for an intermediate HTGR (High Temperature Gas-cooled Reactor nuclear fuel in laboratory-scale. Microsphere ADU gels were based on sol-solution which was made from a homogeneous mixture of ADUN (Acid Deficient Uranyl Nitrate which was containing uranyl ion in high concentration, a water soluble organic compound PVA (Polyvinyl Alcohol and THFA (Tetrahydrofurfuryl Alcohol. The simple unified home made laboratory experimental machine was developed to replace test tube experiment method which was once used due to a tiny amount of microsphere ADU gels produced. It consists of four main parts: tank filled sol-solution connecting to peristaltic pump and vibrating nozzle, preliminary gelation and gelation column. The machine has successfully converted 150 mL sol-solution into thousands of drops which produced 120 - 130 drops in each minute in steady state in ammonia gas free sector. Preliminary gelation reaction was carried out in ammonia gas sector where drops react with ammonia gas in a bat an eye followed by gelation reaction in column containing ammonia solution 7 M. In ageing process, ADU gels were collected and submerged into a vessel containing ammonia solution which was shaken for 1 hour in a shaker device. Isopropyl alcohol (90% solution was used to wash ADU gels and a digital camera was used to measured spherical form of ADU gels. Diameters in spherical spheroid form were found between 1.8 mm until 2.2 mm. The spherical purity of ADU gels were 10% - 20% others were oblate, prolate spheroid and microsphere which have hugetiny of dimples on the surface.   PRODUKSI GEL ADU SKALA LABORATORIUM DENGAN MENGGUNAKAN GELASI EKSTERNAL UNTUK BAHAN BAKAR ANTARA HTGR. Penelitian ini bertujuan untuk membuat ribuan gel bulat ADU (Ammonium

  12. Gelation of mucin: Protecting the stomach from autodigestion

    Science.gov (United States)

    Bansil, Rama

    2011-03-01

    In this talk I will describe the molecular mechanisms involved in the remarkable ability of the mucus lining of the stomach for protecting the stomach from being digested by the acidic gastric juices that it secretes. These physical properties can be attributed to the presence of a high molecular weight glycoprotein found in mucus, called mucin. Rheology and other measurements show that gastric mucin forms a gel under acidic pH. A model of gelation based on the interplay of hydrophobic and electrostatic interactions will be discussed. Molecular Dynamics simulation studies of folding and aggregation of mucin domains provide further support for this model. The relevance of gelation to the motion of the ulcer causing bacterium H. pylori will be discussed.

  13. Gelation mechanism of poly(N-isopropylacrylamide)-clay nanocomposite hydrogels synthesized by photopolymerization.

    Science.gov (United States)

    Ferse, Bernhard; Richter, Sven; Eckert, Franziska; Kulkarni, Amit; Papadakis, Christine M; Arndt, Karl-Friedrich

    2008-11-04

    The gelation process of poly-(N-isopropylacrylamide)-clay nanocomposite hydrogels (PNIPAAm-clay NC gels) was investigated by dynamic and static light scattering (DLS and SLS), as well as by fluorescence correlation spectroscopy (FCS). The photopolymerization method chosen for the radical polymerizing system ensured that, when the irradiation is removed, the reaction stopped immediately. Experiments showed that shortly before the gelation threshold is reached, no changes in the DLS autocorrelation functions appear, while the monomer conversion can be observed by 1H NMR spectroscopy. These results correspond to the formation of microparticles, in which the PNIPAAm chains are closely attached to the clay platelets. During the further polymerization process, clay clusters are developed before the sol-gel threshold is reached. FCS measurements were performed to obtain information on the motion of the clay platelets inside the NC gel. The DLS method gives only an average of the motions in the gel. In a time window between 10 micros and 1 s, the clay sheets labeled with Rhodamine B show no characteristic motions.

  14. Transforming Internal Activities of Business Process Models to Services Compositions

    NARCIS (Netherlands)

    Dirgahayu, Teduh; Quartel, Dick; van Sinderen, Marten J.; Mostefaoui, S.K.; Maamar, Z.; Ferreira Pires, L.; Hammoudi, S.; Rinderle-Ma, S.; Sadiq, S.; Schulz, K.

    As a service composition language, BPEL imposes as constraint that a business process model should consist only of activities for interacting with other business processes. BPEL provides limited support for implementing internal activities, i.e. activities that are performed by a single business

  15. Process of international kaizen transfer in the Netherlands

    NARCIS (Netherlands)

    Yokozawa, Kodo; Steenhuis, H.J.; de Bruijn, E.J.

    2011-01-01

    This study sheds light on the international kaizen transfer process. Two research questions were explored: what are the major stages in the kaizen transfer process? And what are the activities, positive and negative factors influencing each stage? Case studies with 15 Japanese manufacturers in the

  16. Information Architecture without Internal Theory: An Inductive Design Process.

    Science.gov (United States)

    Haverty, Marsha

    2002-01-01

    Suggests that information architecture design is primarily an inductive process, partly because it lacks internal theory and partly because it is an activity that supports emergent phenomena (user experiences) from basic design components. Suggests a resemblance to Constructive Induction, a design process that locates the best representational…

  17. Using Reporting in the Internal Communication Process of the Company

    Directory of Open Access Journals (Sweden)

    Cornel Marian Iosif

    2013-07-01

    Full Text Available Internal communication can be regarded either as a subsistent process of the organization, or as a process helping to decode and more easily understand them. Organizations are based on the internal communication process, because without it, information, ideas could not be sent, the organization’s goals and values could not be built, and its organizational culture would simply not exist. The internal communication process is centered on sending ideas, information in the organization. This is directly proportional with the efficiency of the organization. Internal communication allows for the best decision to be taken, for information to be sent towards the interior of the company, towards the employees, but also has the purpose of strengthening the relations between persons. Internal communication has at its basis the verbal and non-verbal communication, but they have great disadvantages, because: verbal communication has losses of information, depends on the moment of transmission, but also on the receiver.Keywords: report, internal communication, neuro linguistic programming, company

  18. Synthesis and Properties of Gelators Derived from Tetraphenylethylene and Gallic Acid with Aggregation-Induced Emission

    Science.gov (United States)

    Luo, Miao; Zhou, Xie; Chi, Zhenguo; Ma, Chunping; Zhang, Yi; Liu, Siwei; Xu, Jiarui

    2013-09-01

    Two novel organogelators (TEG and TAG) based on tetraphenylethylene and 3,4,5-tris(dodecyloxy) benzoic acid were synthesized through ester bond and amido bond linkages, respectively. Compounds TEG and TAG were able to induce gelation in ethanol. Aggregation-induced enhanced emission was observed in these organogelator molecules, with increased fluorescence intensity from the solutions to the gels. The completely thermoreversible gelation occurred due to the aggregation of the organogelators. In the process, a fibrous network was formed by a combination of intermolecular hydrogen bonding, π-π stacking and van der Waals interactions. These phenomena were observed in the xerogels by field-emission scanning electron microscopy and Fourier-transform infrared spectroscopy. The results of differential scanning calorimetry and polarized optical microscopy indicated that compound TAG exhibited stable liquid crystalline phases over a wide temperature range. The linking groups have severe influence on the properties of the organogelators, which was mainly attributed to the hydrogen bonding interaction in compound TAG.

  19. In Situ Gelation-Induced Death of Cancer Cells Based on Proteinosomes.

    Science.gov (United States)

    Zhou, Yuting; Song, Jianmin; Wang, Lei; Xue, Xuting; Liu, Xiaoman; Xie, Hui; Huang, Xin

    2017-08-14

    Hydrogels are an excellent type of material that can be utilized as a platform for cell culture. However, when a bulky hydrogel forms on the inside of cancer cells, the result would be different. In this study, we demonstrate a method for in situ gelation inside cancer cells that can efficiently induce cell death. Glutathione-responsive proteinosomes with good biocompatibility were prepared as carriers for sodium alginate to be endocytosed by cancer cells, where the chelation between sodium alginate and free calcium ions in the culture medium occurs during the diffusion process. The uptake of the hydrogel-loaded proteinosomes into the cancer cells, and then the triggered release of hydrogel with concomitant aggregation, was well-confirmed by monitoring the change of the Young's modulus of the cells based on AFM force measurements. Accordingly, when a large amount of hydrogel formed in cells, the cell viability would be inhibited by ∼90% by MTT assay at a concentration of 5.0 μM of hydrogel-loaded proteinosomes after 48 h incubation, which clearly proves the feasibility of the demonstrated method for killing cancer cells. Although more details regarding the mechanism of cell death should be conducted in the near future, such a demonstrated method of in situ gelation inside cells provides another choice for killing cancer cells.

  20. Chiral bis(amino acid)- and bis(amino alcohol)-oxalamide gelators. Gelation properties, self-assembly motifs and chirality effects.

    Science.gov (United States)

    Frkanec, Leo; Zinić, Mladen

    2010-01-28

    Bis(amino acid)- and bis(amino alcohol)oxalamide gelators represent the class of versatile gelators whose gelation ability is a consequence of strong and directional intermolecular hydrogen bonding provided by oxalamide units and lack of molecular symmetry due to the presence of two chiral centres. Bis(amino acid)oxalamides exhibit ambidextrous gelation properties, being capable to form gels with apolar and also highly polar solvent systems and tend to organise into bilayers or inverse bilayers in hydrogel or organic solvent gel assemblies, respectively. (1)H NMR and FTIR studies of gels revealed the importance of the equilibrium between the assembled network and smaller dissolved gelator assemblies. The organisation in gel assemblies deduced from spectroscopic structural studies are in certain cases closely related to organisations found in the crystal structures of selected gelators, confirming similar organisations in gel assemblies and in the solid state. The pure enantiomer/racemate gelation controversy is addressed and the evidence provided that rac-16 forms a stable toluene gel due to resolution into enantiomeric bilayers, which then interact giving gel fibres and a network of different morphology compared to its (S,S)-enantiomer gel. The TEM investigation of both gels confirmed distinctly different gel morphologies, which allowed the relationship between the stereochemical form of the gelator, the fibre and the network morphology and the network solvent immobilisation capacity to be proposed. Mixing of the constitutionally different bis(amino acid) and bis(amino alcohol)oxalamide gelators resulted in some cases in highly improved gelation efficiency denoted as synergic gelation effect (SGE), being highly dependent also on the stereochemistry of the component gelators. Examples of photo-induced gelation based on closely related bis(amino acid)-maleic acid amide and -fumaramide and stilbene derived oxalamides where gels form by irradiation of the solution of

  1. External and internal limitations in amplitude-modulation processing

    DEFF Research Database (Denmark)

    Ewert, Stephan; Dau, Torsten

    2004-01-01

    Three experiments are presented to explore the relative role of "external" signal variability and "internal" resolution limitations of the auditory system in the detection and discrimination of amplitude modulations (AM). In the first experiment, AM-depth discrimination performance was determined......-filterbank models. The predictions revealed that AM-depth discrimination and AM detection are limited by a combination of the external signal variability and an internal "Weber-fraction" noise process....

  2. Gelation Behavior Study of a Resorcinol–Hexamethyleneteramine Crosslinked Polymer Gel for Water Shut-Off Treatment in Low Temperature and High Salinity Reservoirs

    Directory of Open Access Journals (Sweden)

    Yongpeng Sun

    2017-07-01

    Full Text Available Mature oilfields usually encounter the problem of high watercut. It is practical to use chemical methods for water-shutoff in production wells, however conventional water-shutoff agents have problems of long gelation time, low gel strength, and poor stability under low temperature and high salinity conditions. In this work a novel polymer gel for low temperature and high salinity reservoirs was developed. This water-shutoff agent had controllable gelation time, adjustable gel strength and good stability performance. The crosslinking process of this polymer gel was studied by rheological experiments. The process could be divided into an induction period, a fast crosslinking period, and a stable period. Its gelation behaviors were investigated in detail. According to the Gel Strength Code (GSC and vacuum breakthrough method, the gel strength was displayed in contour maps. The composition of the polymer gel was optimized to 0.25~0.3% YG100 + 0.6~0.9% resorcinol + 0.2~0.4% hexamethylenetetramine (HMTA + 0.08~0.27% conditioner (oxalic acid. With the concentration increase of the polymer gel and temperature, the decrease of pH, the induction period became shorter and the crosslinking was more efficient, resulting in better stability performance. Various factors of the gelation behavior which have an impact on the crosslinking reaction process were examined. The relationships between each impact factor and the initial crosslinking time were described with mathematical equations.

  3. Process gas generator feeding internal combustion piston engines

    Energy Technology Data Exchange (ETDEWEB)

    Iwantscheff, G; Kostka, H; Henkel, H J

    1978-10-26

    The invention relates to a process gas generator feeding gaseous fuel to internal combustion piston engines. The cylinder linings of the internal combustion engine are enclosed by the catalytic reaction chamber of the process gas generator which contains perforated sintered nozzle bricks as carriers of the catalysts needed for the conversion. The reaction chamber is surrounded by the exhaust gas chamber around which a tube coil is ound which feeds the fuel charge to the reaction chamber after evaporation and mixing with exhaust gas and air. The fuel which may be used for this purpose, e.g., is low-octane gasoline or diesel fuel. In the reaction chamber the fuel is catalytically converted at temperatures above 200/sup 0/C, e.g., into low-molecular paraffins, carbon monoxide and hydrogen. Operation of the internal combustion engine with a process gas generator greatly reduces the pollutant content of the exhaust gases.

  4. Effect of co-solute and gelation temperature on milk protein and gum tragacanth interaction in acidified gels.

    Science.gov (United States)

    Hatami, Masoud; Nejatian, Mohammad; Mohammadifar, Mohammad Amin

    2012-05-01

    The aim of this study was to investigate the role of process conditions and system composition on the acid-induced gelation of a mixture of milk protein and gum tragacanth. This was studied by determining the effects of co-solute (lactose) addition (3, 5 and 7%) and gelation temperature (25, 37 and 45°C) on the mixture's rheological properties and microstructure using a combination of techniques including small-deformation rheology and scanning electron microscopy. The presence of lactose played an important role in the microstructure formation of gels but did not change most rheological properties. The microstructure of gels formed in the presence of lactose was coarser and more particulate, but less interconnected; this can be explained by lactose's role in improving protein aggregation. Gels prepared at a lower temperature had a high structure strength, as indicated by their high storage modulus, τ(f) and G(f) values. Low gelation temperature also caused a more branched and homogenous microstructure. Copyright © 2012 Elsevier B.V. All rights reserved.

  5. International Outsourcing: a process approach to the apparel industry

    Directory of Open Access Journals (Sweden)

    Maria Rosario Alves Moreira

    2015-12-01

    Full Text Available Objective – The purpose of this paper is to build a framework for an international outsourcing process in the apparel industry that can serve to support managerial decisions and actions regarding outsourcing choices and implementation. Design/methodology/approach – We developed of a straightforward and flexible framework describing the main stages of the international outsourcing process and its main activities with application in the context of the apparel industry. A case study approach was adopted with primary data collected through in-depth interviews and secondary data aggregated from company reports and documents. Theoretical foundation – Some research gaps in the outsourcing literature and most specifically on the matter of international outsourcing were identified by Hatonen and Eriksson (2009 and Kakabadse and Kakabadse (2000, among others. Specifically, these authors claim that there is not enough research on developing and offering decision models, tools or guidelines to support managerial decisions with the appropriate empirical evidence. This study aims to address this gap. Findings – We found that the international outsourcing process can be described using the proposed framework. Apparel companies can use this framework to support and supervise international outsourcing processes. Practical implications – This study provides a simple model that can help companies in the apparel industry to enhance their outsourcing activities and operations, and also contributes to a broader academic understanding of the matter.

  6. 78 FR 18321 - International Code Council: The Update Process for the International Codes and Standards

    Science.gov (United States)

    2013-03-26

    ... Energy Conservation Code. International Existing Building Code. International Fire Code. International... Code. International Property Maintenance Code. International Residential Code. International Swimming Pool and Spa Code International Wildland-Urban Interface Code. International Zoning Code. ICC Standards...

  7. Uranium 2000 : International symposium on the process metallurgy of uranium

    International Nuclear Information System (INIS)

    Ozberk, E.; Oliver, A.J.

    2000-01-01

    The International Symposium on the Process Metallurgy of Uranium has been organized as the thirtieth annual meeting of the Hydrometallurgy Section of the Metallurgical Society of the Canadian Institute of Mining, Metallurgy and Petroleum (CIM). This meeting is jointly organized with the Canadian Mineral Processors Division of CIM. The proceedings are a collection of papers from fifteen countries covering the latest research, development, industrial practices and regulatory issues in uranium processing, providing a concise description of the state of this industry. Topics include: uranium industry overview; current milling operations; in-situ uranium mines and processing plants; uranium recovery and further processing; uranium leaching; uranium operations effluent water treatment; tailings disposal, water treatment and decommissioning; mine decommissioning; and international regulations and decommissioning. (author)

  8. Growth and gelation of inorganic polymers

    International Nuclear Information System (INIS)

    Kallala, Mohamed

    1992-01-01

    This research thesis reports a study during which gels, sols and precipitates are obtained by hydrolysis and condensation of titanium tetra-n-butoxide diluted in n-butanol. The condensation of the non-modified precursor always results in a precipitate. Small angle X-ray scattering shows that these precipitates are made of dense polymers with rough surfaces. Due to the condensation selective inhibition by protons or by organic complexes, polymers must grow in an anisotropic way. When these accumulations reach a macroscopic size, a gel is formed. The inner structure of these accumulations is continuously varying with the inhibition rate. For high inhibitions, the final state is a sol or a transparent gel with a fractal dimension equal to 2. For intermediate inhibition rates, the gel becomes turbid. Precipitation occurs when fractal dimension reaches 3. The author shows that the final state of the aggregation results from a difference of reactivity of monomers with respect to their environment. Depending on this reactivity, the reaction bath changes its regime during aggregation, and passes from a recombination of branch polymers to the precipitation of dense objects. This explains the role of some chemical modifiers in the control of aggregation processes, notably in the sol-gel process [fr

  9. 4th International Conference on Communications, Signal Processing, and Systems

    CERN Document Server

    Mu, Jiasong; Wang, Wei; Zhang, Baoju

    2016-01-01

    This book brings together papers presented at the 4th International Conference on Communications, Signal Processing, and Systems, which provides a venue to disseminate the latest developments and to discuss the interactions and links between these multidisciplinary fields. Spanning topics ranging from Communications, Signal Processing and Systems, this book is aimed at undergraduate and graduate students in Electrical Engineering, Computer Science and Mathematics, researchers and engineers from academia and industry as well as government employees (such as NSF, DOD, DOE, etc).

  10. Relativistic Processes and the Internal Structure of Neutron Stars

    International Nuclear Information System (INIS)

    Alvarez-Castillo, D. E.; Kubis, S.

    2011-01-01

    Models for the internal composition of Dense Compact Stars are reviewed as well as macroscopic properties derived by observations of relativistic processes. Modeling of pure neutron matter Neutron Stars is presented and crust properties are studied by means of a two fluid model.

  11. Preparation of curcumin nanoparticle by using reinforcement ionic gelation technique

    Science.gov (United States)

    Suryani, Halid, Nur Hatidjah Awaliyah; Akib, Nur Illiyyin; Rahmanpiu, Mutmainnah, Nina

    2017-05-01

    Curcumin, a polyphenolic compound present in curcuma longa has a wide range of activities including anti-inflammatory properties. The potency of curcumin is limited by its poor oral bioavailability because of its poor solubility in aqueous. Various methods have been tried to solve the problem including its encapsulation into nanoparticle. The aim of this study is to develop curcumin nanoparticle by using reinforcement ionic gelation technique and to evaluate the stability of curcumin nanoparticles in gastrointestinal fluid. Curcumin nanoparticles were prepared by using reinforcement ionic gelation technique with different concentrations of chitosan, trypolyphosphate, natrium alginate and calcium chloride. Curcumin nanoparticles were then characterized including particle size and zeta potential by using particle size analyzer and morphology using a transmission electron microscope, entrapment efficiency using UV-Vis Spectrophotometer and chemical structure analysis by Infra Red Spectrophotometer (FTIR). Furthermore, the stability of curcumin nanoparticles were evaluated on artificial gastric fluid and artificial intestinal fluids by measuring the amount of curcumin released in the medium at a time interval. The result revealed that curcumin nanoparticles can be prepared by reinforcement ionic gelation technique, the entrapment efficiency of curcumin nanoparticles were from 86.08 to 91.41%. The average of particle size was 272.9 nm and zeta potential was 12.05 mV. The morphology examination showed that the curcumin nanoparticles have spherical shape. The stability evaluation of curcumin nanoparticles showed that the nanoparticles were stable on artificial gastric fluid and artificial intestinal fluid. This result indicates that curcumin nanoparticles have the potential to be developed for oral delivery.

  12. International Patients' Travel Decision Making Process- A Conceptual Framework.

    Science.gov (United States)

    Khan, Mohammad Jamal; Chelliah, Shankar; Haron, Mahmod Sabri

    2016-02-01

    Role of information source, perceived benefits and risks, and destination image has significantly been examined in travel and tourism literature; however, in medical tourism it is yet to be examined thoroughly. The concept discussed in this article is drawn form well established models in tourism literature. The purpose of this research was to identify the source of information, travel benefits and perceived risks related to movement of international patients and develop a conceptual model based on well-established theory. Thorough database search (Science Direct, utmj.org, nih.gov, nchu.edu.tw, palgrave-journals, medretreat, Biomedcentral) was performed to fulfill the objectives of the study. International patients always concern about benefits and risks related to travel. These benefits and risks form images of destination in the minds of international patients. Different sources of information make international patients acquaint about the associated benefits and risks, which later leads to development of intention to visit. This conceptual paper helps in establishing model for decision-making process of international patients in developing visit intention. Ample amount of literature is available detailing different factors involved in travel decision making of international patients; however literature explaining relationship between these factors is scarce.

  13. International Patients’ Travel Decision Making Process- A Conceptual Framework

    Science.gov (United States)

    KHAN, Mohammad Jamal; CHELLIAH, Shankar; HARON, Mahmod Sabri

    2016-01-01

    Background: Role of information source, perceived benefits and risks, and destination image has significantly been examined in travel and tourism literature; however, in medical tourism it is yet to be examined thoroughly. The concept discussed in this article is drawn form well established models in tourism literature. Methods: The purpose of this research was to identify the source of information, travel benefits and perceived risks related to movement of international patients and develop a conceptual model based on well-established theory. Thorough database search (Science Direct, utmj.org, nih.gov, nchu.edu.tw, palgrave-journals, medretreat, Biomedcentral) was performed to fulfill the objectives of the study. Results: International patients always concern about benefits and risks related to travel. These benefits and risks form images of destination in the minds of international patients. Different sources of information make international patients acquaint about the associated benefits and risks, which later leads to development of intention to visit. This conceptual paper helps in establishing model for decision-making process of international patients in developing visit intention. Conclusion: Ample amount of literature is available detailing different factors involved in travel decision making of international patients; however literature explaining relationship between these factors is scarce. PMID:27114978

  14. Gelation of covalently edge-modified laponites in aqueous media. 1. rheology and nuclear magnetic resonance.

    Science.gov (United States)

    Patil, Suhas P; Mathew, Renny; Ajithkumar, T G; Rajamohanan, P R; Mahesh, T S; Kumaraswamy, Guruswamy

    2008-04-17

    We describe the covalent modification of the edges of laponite with organic groups and the influence of this modification on gelation behavior. We compare three materials: an unmodified laponite, a laponite edge modified with a trimethyl moiety (MLap), and an octyldimethyl moiety (OLap). Gelation is investigated using rheology and NMR T1 relaxation measurements and nuclear Overhauser enhancement spectroscopy (NOESY). MLap and OLap show qualitatively different gelation. Gelation of MLap is very similar to laponite: MLap gels over the same time scale as laponite and has about the same solid modulus, and the MLap gel is almost as transparent as laponite. In contrast, OLap gels rapidly relative to laponite and forms a weak, turbid gel. We believe that gelation in laponite and MLap results from the formation of a network of well-dispersed platelets (or a few platelets), while in OLap, gelation results from a network of stacks of several platelets. NMR relaxation measurements indicate that gelation does not affect the average relaxation of water protons. However, T1 increases marginally for the protons in the organic moieties in MLap and decreases for protons in the organic moieties in OLap. Relaxation measurements, analyses of line width, and NOESY taken together suggest that, in OLap, gelation is a consequence of association of the organic moieties on the laponite edges, and that this association strengthens with time. Thus, the time-dependent changes in NMR suggest a structural origin for the time-dependent changes in the rheological behavior.

  15. Towards a fragment-based approach in gelator design: halogen effects leading to thixotropic, mouldable and self-healing systems in aryl-triazolyl amino acid-based gelators!

    Science.gov (United States)

    Srivastava, Bhartendu K; Manheri, Muraleedharan K

    2017-04-18

    A simple replacement of a H atom by Br transformed non-gelating aryl triazolyl amino acid benzyl ester into a versatile gelator, which formed shape-persistent, self-healing and mouldable gels. The 'bromo-aryl benzyl ester' fragment was then transplanted into another framework, which resulted in similar solvent preference and gelation efficiency.

  16. Stabilization of oil-in-water emulsions by enzyme catalyzed oxidative gelation of sugar beet pectin

    DEFF Research Database (Denmark)

    Abang Zaidel, Dayang Norulfairuz; Chronakis, Ioannis S.; Meyer, Anne S.

    2013-01-01

    Enzyme catalyzed oxidative cross-linking of feruloyl groups can promote gelation of sugar beet pectin (SBP). It is uncertain how the enzyme kinetics of this cross-linking reaction are affected in emulsion systems and whether the gelation affects emulsion stability. In this study, SBP (2.5% w...... larger average particle sizes than the emulsions in which the SBP was homogenized into the emulsion system during emulsion preparation (referred as Mix B). Mix B type emulsions were stable. Enzyme catalyzed oxidative gelation of SBP helped stabilize the emulsions in Mix A. The kinetics of the enzyme...... catalyzed oxidative gelation of SBP was evaluated by small angle oscillatory measurements for horseradish peroxidase (HRP) (EC 1.11.1.7) and laccase (EC 1.10.3.2) catalysis, respectively. HRP catalyzed gelation rates, determined from the slopes of the increase of elastic modulus (G0) with time, were higher...

  17. Effects of irradiation on the gelation properties of muscle protein

    International Nuclear Information System (INIS)

    Lin Xianping; Yang Wenge

    2014-01-01

    Gel properties of muscle protein are the important functional characteristics in meat and its products. which determine the meat products' unique quality. such as texture. Juiciness. fat content and sensory characteristics As a novel food preservation technique, irradiation may lead to changes in the composition and structure of protein molecule. and impact the gel forming ability and gelation properties of muscle protein. Based on the introduction of gel forming mechanism of muscle protein, effects of irradiation on the water holding capacity, mechanical properties and structure of muscle protein gel were reviewed in detail. High-dose irradiation could weaken the water holding capacity of muscle protein and result in the loss of meat juice. With different irradiation conditions or raw materials, influences of irradiation on the texture and theological properties of muscle protein gels are varied, and effects on the structure of muscle protein and its gel are more complex. Finally, the research trend of irradiation effects on the gelation properties of muscle protein is put forward. (authors)

  18. Solubility and dissolution improvement of ketoprofen by emulsification ionic gelation

    Science.gov (United States)

    Rachmaniar, Revika; Tristiyanti, Deby; Hamdani, Syarif; Afifah

    2018-02-01

    Ketoprofen or [2-(3-benzoylphenyl) propionic acid] is non-steroidal anti-inflammatory (NSAID) and an analgesic which has high permeability and low solubility. The purpose of this work was to improve the solubility and dissolution of poorly water-soluble ketoprofen prepared by emulsification ionic gelation method and utilizing polymer (chitosan) and cross linker (tripolyphosphate, TPP) for particles formulation. The results show that increasing pH value of TPP, higher solubility and dissolution of as-prepared ketoprofen-chitosan was obtained. The solubility in water of ketoprofen-chitosan with pH 6 for TPP increased 2.71-fold compared to untreated ketoprofen. While the dissolution of ketoprofen-chitosan with pH 6 of TPP in simulated gastric fluid without enzyme (0.1 N HCl), pH 4.5 buffer and simulated intestinal fluid without enzyme (phosphate buffer pH 6.8) was increased 1.9-fold, 1.6-fold and 1.2-fold compared to untreated ketoprofen for dissolution time of 30 minutes, respectively. It could be concluded that chitosan and TPP in the emulsification ionic gelation method for ketoprofen preparation effectively increases solubility and dissolution of poorly water-soluble ketoprofen.

  19. 1st International Conference on Cognitive Systems and Information Processing

    CERN Document Server

    Hu, Dewen; Liu, Huaping

    2014-01-01

    "Foundations and Practical Applications of Cognitive Systems and Information Processing" presents selected papers from the First International Conference on Cognitive Systems and Information Processing, held in Beijing, China on December 15-17, 2012 (CSIP2012). The aim of this conference is to bring together experts from different fields of expertise to discuss the state-of-the-art in artificial cognitive systems and advanced information processing, and to present new findings and perspectives on future development. This book introduces multidisciplinary perspectives on the subject areas of Cognitive Systems and Information Processing, including cognitive sciences and technology, autonomous vehicles, cognitive psychology, cognitive metrics, information fusion, image/video understanding, brain-computer interfaces, visual cognitive processing, neural computation, bioinformatics, etc. The book will be beneficial for both researchers and practitioners in the fields of Cognitive Science, Computer Science and Cogni...

  20. First International Conference Multimedia Processing, Communication and Computing Applications

    CERN Document Server

    Guru, Devanur

    2013-01-01

    ICMCCA 2012 is the first International Conference on Multimedia Processing, Communication and Computing Applications and the theme of the Conference is chosen as ‘Multimedia Processing and its Applications’. Multimedia processing has been an active research area contributing in many frontiers of today’s science and technology. This book presents peer-reviewed quality papers on multimedia processing, which covers a very broad area of science and technology. The prime objective of the book is to familiarize readers with the latest scientific developments that are taking place in various fields of multimedia processing and is widely used in many disciplines such as Medical Diagnosis, Digital Forensic, Object Recognition, Image and Video Analysis, Robotics, Military, Automotive Industries, Surveillance and Security, Quality Inspection, etc. The book will assist the research community to get the insight of the overlapping works which are being carried out across the globe at many medical hospitals and instit...

  1. The crucial effect of early-stage gelation on the mechanical properties of cement hydrates

    Science.gov (United States)

    Ioannidou, Katerina; Kanduč, Matej; Li, Lunna; Frenkel, Daan; Dobnikar, Jure; Del Gado, Emanuela

    2016-07-01

    Gelation and densification of calcium-silicate-hydrate take place during cement hydration. Both processes are crucial for the development of cement strength, and for the long-term evolution of concrete structures. However, the physicochemical environment evolves during cement formation, making it difficult to disentangle what factors are crucial for the mechanical properties. Here we use Monte Carlo and Molecular Dynamics simulations to study a coarse-grained model of cement formation, and investigate the equilibrium and arrested states. We can correlate the various structures with the time evolution of the interactions between the nano-hydrates during the preparation of cement. The novel emerging picture is that the changes of the physicochemical environment, which dictate the evolution of the effective interactions, specifically favour the early gel formation and its continuous densification. Our observations help us understand how cement attains its unique strength and may help in the rational design of the properties of cement and related materials.

  2. 9th International Symposium on Ultrafast Processes in Spectroscopy

    CERN Document Server

    Silvestri, S; Denardo, G

    1996-01-01

    This volume is a collection of papers presented at the Ninth International Symposium on "Ultrafast Processes in Spectroscopy" (UPS '95) held at the International Centre for Theo­ retical Physics (ICTP), Trieste (Italy), October 30 -November 3, 1995. These meetings have become recognized as the major forum in Europe for discussion of new work in this rapidly moving field. The UPS'95 Conference in Trieste brought together a multidisciplinary group of researchers sharing common interests in the generation of ultrashort optical pulses and their application to studies of ultrafast phenomena in physics, chemistry, material science, electronics, and biology. It was attended by approximately 250 participants from 20 countries and the five-day program comprises more than 200 papers. The progress of both technology and applications in the field of ultrafast processes during these last years is truly remarkable. The advent of all solid state femtosecond lasers and the extension of laser wavelengths by frequency convers...

  3. 75 FR 19944 - International Code Council: The Update Process for the International Codes and Standards

    Science.gov (United States)

    2010-04-16

    ... documents from ICC's Chicago District Office: International Code Council, 4051 W Flossmoor Road, Country... Energy Conservation Code. International Existing Building Code. International Fire Code. International...

  4. 4th International Conference on Software Process Improvement

    CERN Document Server

    Muñoz, Mirna; Rocha, Álvaro; Calvo-Manzano, Jose

    2016-01-01

    This book contains a selection of papers from The 2015 International Conference on Software Process Improvement (CIMPS’15), held between the 28th and 30th of October in Mazatlán, Sinaloa, México. The CIMPS’15 is a global forum for researchers and practitioners that present and discuss the most recent innovations, trends, results, experiences and concerns in the several perspectives of Software Engineering with clear relationship but not limited to software processes, Security in Information and Communication Technology and Big Data Field. The main topics covered are: Organizational Models, Standards and Methodologies, Knowledge Management, Software Systems, Applications and Tools, Information and Communication Technologies and Processes in non-software domains (Mining, automotive, aerospace, business, health care, manufacturing, etc.) with a demonstrated relationship to software process challenges.

  5. 2015 International Conference on Machine Learning and Signal Processing

    CERN Document Server

    Woo, Wai; Sulaiman, Hamzah; Othman, Mohd; Saat, Mohd

    2016-01-01

    This book presents important research findings and recent innovations in the field of machine learning and signal processing. A wide range of topics relating to machine learning and signal processing techniques and their applications are addressed in order to provide both researchers and practitioners with a valuable resource documenting the latest advances and trends. The book comprises a careful selection of the papers submitted to the 2015 International Conference on Machine Learning and Signal Processing (MALSIP 2015), which was held on 15–17 December 2015 in Ho Chi Minh City, Vietnam with the aim of offering researchers, academicians, and practitioners an ideal opportunity to disseminate their findings and achievements. All of the included contributions were chosen by expert peer reviewers from across the world on the basis of their interest to the community. In addition to presenting the latest in design, development, and research, the book provides access to numerous new algorithms for machine learni...

  6. Gelation or molecular recognition; is the bis-(α,β-dihydroxy esters motif an omnigelator?

    Directory of Open Access Journals (Sweden)

    Peter C. Griffiths

    2010-11-01

    Full Text Available Understanding the gelation of liquids by low molecular weight solutes at low concentrations gives an insight into many molecular recognition phenomena and also offers a simple route to modifying the physical properties of the liquid. Bis-(α,β-dihydroxy esters are shown here to gel thermoreversibly a wide range of solvents, raising interesting questions as to the mechanism of gelation. At gelator concentrations of 5–50 mg ml−1, gels were successfully formed in acetone, ethanol/water mixtures, toluene, cyclohexane and chloroform (the latter, albeit at a higher gelator concentration. A range of neutron techniques – in particular small-angle neutron scattering (SANS – have been employed to probe the structure of a selection of these gels. The universality of gelation in a range of solvent types suggests the gelation mechanism is a feature of the bis-(α,β-dihydroxy ester motif, with SANS demonstrating the presence of regular structures in the 30–40 Å range. A correlation between the apparent rodlike character of the structures formed and the polarity of the solvent is evident. Preliminary spin-echo neutron scattering studies (SESANS indicated the absence of any larger scale structures. Inelastic neutron spectroscopy (INS studies demonstrated that the solvent is largely unaffected by gelation, but does reveal insights into the thermal history of the samples. Further neutron studies of this kind (particularly SESANS and INS are warranted, and it is hoped that this work will stimulate others to pursue this line of research.

  7. Enzymatic gelation of sugar beet pectin in food products

    DEFF Research Database (Denmark)

    Bergsøe, Merete Norsker; Jensen, Mette; Adler-Nissen, Jens

    2000-01-01

    Sugar beet pectin is a food ingredient with specific functional properties. It may form gels by an oxidative cross-linking of ferulic acid. In the present study, the gel forming properties of three oxidative enzymes were examined in different food relevant conditions. The enzymes chosen were two...... laccases and one peroxidase. The textural properties of the produced gels were measured on a texture analyser. The influence of sugar, salt and protein were analysed. Finally, the enzymatic gelation was studied in three food products with added sugar beet pectin. These were black currant juice, milk...... and chopped heat-treated meat emulsion. The addition of salt resulted in softer, less stiff and chewy, and less adhesive gels. Generally speaking, sugar addition increased the hardness but at high concentration the gels were very brittle. However, Young's modulus was lower in gels containing sugar than...

  8. STRATEGIC PRIORITIES FOR THE INTERNAL MIGRATION PROCESSES REGULATION IN UKRAINE

    Directory of Open Access Journals (Sweden)

    Olga Balueva

    2018-01-01

    implementation ought to be approved by the strategic migration model for Ukraine’s internal migration aimed at promoting the implementation of the basic IDPs and internally displaced businesses rights; ensuring the social and economic integration of the IDPs into the host society; promotion of country territories’ social and economic development; reducing the level of social and psychological tension in host communities; creating new jobs; improvement of the investment climate; increasing the efficiency of using the country intellectual potential and its human resources. Value / originality. Solving the urgent issues associated with forced displacement processes, including integration and adaptation to host communities.

  9. Advancements in internationally accepted standards for radiation processing

    International Nuclear Information System (INIS)

    Farrar, H. IV; Derr, D.D.; Vehar, D.W.

    1993-01-01

    Subcommittees of the American Society for Testing and Materials (ASTM) are developing standards on various aspects of radiation processing. Nine standards on how to select and calibrate dosimeters, where to put them, how many to use, and how to use individual types of dosimeter systems have been published. The group is also developing standards on how to use gamma, electron beam, and X-ray facilities for radiation processing, and a standard on how to treat dose uncertainties. Efforts are underway to promote inclusion of these standards into procedures now being developed by government agencies and by international groups such as the United Nations' International Consultative Group on Food Irradiation (ICGFI) in order to harmonize regulations and help avoid trade barriers. Standards on good irradiation practices for meat and poultry and for fresh fruits, and for the irradiation of seafood and spices have been developed. These food-related standards are based on practices previously published by ICGFI. Standards for determining doses for radiation hardness testing of electronics have been developed. Standards on the Fricke and TLD dosimetry systems are equally useful in other radiation processing applications. (Author)

  10. Proceedings of the international seminar on atomic processes in plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Kato, Takako; Murakami, Izumi [eds.

    2000-01-01

    The International Seminar on Atomic Processes in Plasmas (ISAPP), a satellite meeting to the ICPEAC was held July 28-29 at the National Institute for Fusion Science in Toki, Gifu, Japan. About 110 scientists attended the ISAPP meeting and discussed atomic processes and atomic data required for fusion research. This Proceedings book includes the papers of the talks, posters and panel discussion given at the meeting. The invited talks described the super configuration array method for complex spectra, near-LTE atomic kinetics, R-matrix calculations, the binary-encounter dipole model for electron-impact ionization of molecules, other calculations of molecular processes, the ADAS project and the NIFS atomic data-base, and a survey of the role of molecular processes in divertor plasmas. On the experimental side crossed-beam ion-ion collision-experiments for charge transfer, and storage-ring and EBIT measurements of ionization, excitation and dielectronic recombination cross-sections were presented, and atomic processes important for x-ray laser experiments and x-ray spectroscopy of astrophysical plasmas were described. The new method of plasma polarization spectroscopy was outlined. There was also a spectroscopic study of particle transport in JT-60U, new results for detached plasmas, and a sketch of the first hot plasma experiments with the Large Helical Device recently completed at NIFS. The 63 of the presented papers are indexed individually. (J.P.N.)

  11. 1st International Conference on Computer Vision and Image Processing

    CERN Document Server

    Kumar, Sanjeev; Roy, Partha; Sen, Debashis

    2017-01-01

    This edited volume contains technical contributions in the field of computer vision and image processing presented at the First International Conference on Computer Vision and Image Processing (CVIP 2016). The contributions are thematically divided based on their relation to operations at the lower, middle and higher levels of vision systems, and their applications. The technical contributions in the areas of sensors, acquisition, visualization and enhancement are classified as related to low-level operations. They discuss various modern topics – reconfigurable image system architecture, Scheimpflug camera calibration, real-time autofocusing, climate visualization, tone mapping, super-resolution and image resizing. The technical contributions in the areas of segmentation and retrieval are classified as related to mid-level operations. They discuss some state-of-the-art techniques – non-rigid image registration, iterative image partitioning, egocentric object detection and video shot boundary detection. Th...

  12. The role of internal and external constructive processes in evolution.

    Science.gov (United States)

    Laland, Kevin; Odling-Smee, John; Turner, Scott

    2014-06-01

    The architects of the Modern Synthesis viewed development as an unfolding of a form already latent in the genes. However, developing organisms play a far more active, constructive role in both their own development and their evolution than the Modern Synthesis proclaims. Here we outline what is meant by constructive processes in development and evolution, emphasizing how constructive development is a shared feature of many of the research developments central to the developing Extended Evolutionary Synthesis. Our article draws out the parallels between constructive physiological processes expressed internally and in the external environment (niche construction), showing how in each case they play important and not fully recognized evolutionary roles by modifying and biasing natural selection. © 2014 The Authors. The Journal of Physiology © 2014 The Physiological Society.

  13. The role of internal and external constructive processes in evolution

    Science.gov (United States)

    Laland, Kevin; Odling-Smee, John; Turner, Scott

    2014-01-01

    The architects of the Modern Synthesis viewed development as an unfolding of a form already latent in the genes. However, developing organisms play a far more active, constructive role in both their own development and their evolution than the Modern Synthesis proclaims. Here we outline what is meant by constructive processes in development and evolution, emphasizing how constructive development is a shared feature of many of the research developments central to the developing Extended Evolutionary Synthesis. Our article draws out the parallels between constructive physiological processes expressed internally and in the external environment (niche construction), showing how in each case they play important and not fully recognized evolutionary roles by modifying and biasing natural selection. PMID:24591574

  14. An International Perspective on Pharmacy Student Selection Policies and Processes.

    Science.gov (United States)

    Shaw, John; Kennedy, Julia; Jensen, Maree; Sheridan, Janie

    2015-10-25

    Objective. To reflect on selection policies and procedures for programs at pharmacy schools that are members of an international alliance of universities (Universitas 21). Methods. A questionnaire on selection policies and procedures was distributed to admissions directors at participating schools. Results. Completed questionnaires were received from 7 schools in 6 countries. Although marked differences were noted in the programs in different countries, there were commonalities in the selection processes. There was an emphasis on previous academic performance, especially in science subjects. With one exception, all schools had some form of interview, with several having moved to multiple mini-interviews in recent years. Conclusion. The majority of pharmacy schools in this survey relied on traditional selection processes. While there was increasing use of multiple mini-interviews, the authors suggest that additional new approaches may be required in light of the changing nature of the profession.

  15. Acceleration of gelation and promotion of mineralization of chitosan hydrogels by alkaline phosphatase

    NARCIS (Netherlands)

    Douglas, T.E.L.; Skwarczynska, A.; Modrzejewska, Z.; Balcaen, L.; Schaubroeck, D.; Lycke, S.; Vanhaecke, F.; Vandenabeele, P.; Dubruel, P.; Jansen, J.A.; Leeuwenburgh, S.C.G.

    2013-01-01

    Thermosensitive chitosan hydrogels containing sodium beta-glycerophosphate (beta-GP), whose gelation is induced by increasing temperature to body temperature, were functionalized by incorporation of alkaline phosphatase (ALP), an enzyme involved in mineralization of bone. ALP incorporation led to

  16. Solvent-mediated pathways to gelation and phase separation in suspensions of grafted nanoparticles

    KAUST Repository

    Anyfantakis, Manos; Bourlinos, Athanasios; Vlassopoulos, Dimitris; Fytas, George; Giannelis, Emmanuel; Kumar, Sanat K.

    2009-01-01

    , rheology and visual observations, and different routes to gelation, depending on the solvent used. In agreement with earlier works, the solvent quality for the grafted chains at a given temperature controls the balance between attractions and repulsions

  17. Organic Gelators as Growth Control Agents for Stable and Reproducible Hybrid Perovskite-Based Solar Cells

    KAUST Repository

    Masi, Sofia; Rizzo, Aurora; Munir, Rahim; Listorti, Andrea; Giuri, Antonella; Esposito Corcione, Carola; Treat, Neil D.; Gigli, Giuseppe; Amassian, Aram; Stingelin, Natalie; Colella, Silvia

    2017-01-01

    Low-molecular-weight organic gelators are widely used to influence the solidification of polymers, with applications ranging from packaging items, food containers to organic electronic devices, including organic photovoltaics. Here, this concept

  18. Dynamic covalent gels assembled from small molecules:from discrete gelators to dynamic covalent polymers

    Institute of Scientific and Technical Information of China (English)

    Jian-Yong Zhang; Li-Hua Zeng; Juan Feng

    2017-01-01

    Dynamic covalent chemistry has emerged recently to be a powerful tool to construct functional materials.This article reviews the progress in the research and development of dynamic covalent chemistry in gels assembled from small molecules.First dynamic covalent reactions used in gels are reviewed to understand the dynamic covalent bonding.Afterwards the catalogues of dynamic covalent gels are reviewed according to the nature of gelators and the interactions between gelators.Dynamic covalent bonding can be involved to form low molecular weight gelators.Low molecular weight molecules with multiple functional groups react to form dynamic covalent cross-linked polymers and act as gelators.Two catalogues of gels show different properties arising from their different structures.This review aims to illustrate the structure-property relationships of these dynamic covalent gels.

  19. Structural and solubility parameter correlations of gelation abilities for dihydroxylated derivatives of long-chain, naturally occurring fatty acids.

    Science.gov (United States)

    Zhang, Mohan; Selvakumar, Sermadurai; Zhang, Xinran; Sibi, Mukund P; Weiss, Richard G

    2015-06-01

    Creating structure-property correlations at different distance scales is one of the important challenges to the rational design of molecular gelators. Here, a series of dihydroxylated derivatives of long-chain fatty acids, derived from three naturally occurring molecules-oleic, erucic and ricinoleic acids-are investigated as gelators of a wide variety of liquids. Conclusions about what constitutes a more (or less!) efficient gelator are based upon analyses of a variety of thermal, structural, molecular modeling, and rheological results. Correlations between the manner of molecular packing in the neat solid or gel states of the gelators and Hansen solubility data from the liquids leads to the conclusion that diol stereochemistry, the number of carbon atoms separating the two hydroxyl groups, and the length of the alkanoic chains are the most important structural parameters controlling efficiency of gel formation for these gelators. Some of the diol gelators are as efficient or even more efficient than the well-known, excellent gelator, (R)-12-hydroxystearic acid; others are much worse. The ability to form extensive intermolecular H-bonding networks along the alkyl chains appears to play a key role in promoting fiber growth and, thus, gelation. In toto, the results demonstrate how the efficiency of gelation can be modulated by very small structural changes and also suggest how other structural modifications may be exploited to create efficient gelators. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  20. Internal model of gravity influences configural body processing.

    Science.gov (United States)

    Barra, Julien; Senot, Patrice; Auclair, Laurent

    2017-01-01

    Human bodies are processed by a configural processing mechanism. Evidence supporting this claim is the body inversion effect, in which inversion impairs recognition of bodies more than other objects. Biomechanical configuration, as well as both visual and embodied expertise, has been demonstrated to play an important role in this effect. Nevertheless, the important factor of body inversion effect may also be linked to gravity orientation since gravity is one of the most fundamental constraints of our biology, behavior, and perception on Earth. The visual presentation of an inverted body in a typical body inversion paradigm turns the observed body upside down but also inverts the implicit direction of visual gravity in the scene. The orientation of visual gravity is then in conflict with the direction of actual gravity and may influence configural processing. To test this hypothesis, we dissociated the orientations of the body and of visual gravity by manipulating body posture. In a pretest we showed that it was possible to turn an avatar upside down (inversion relative to retinal coordinates) without inverting the orientation of visual gravity when the avatar stands on his/her hands. We compared the inversion effect in typical conditions (with gravity conflict when the avatar is upside down) to the inversion effect in conditions with no conflict between visual and physical gravity. The results of our experiment revealed that the inversion effect, as measured by both error rate and reaction time, was strongly reduced when there was no gravity conflict. Our results suggest that when an observed body is upside down (inversion relative to participants' retinal coordinates) but the orientation of visual gravity is not, configural processing of bodies might still be possible. In this paper, we discuss the implications of an internal model of gravity in the configural processing of observed bodies. Copyright © 2016 Elsevier B.V. All rights reserved.

  1. Resonance internal conversion as a way of accelerating nuclear processes

    International Nuclear Information System (INIS)

    Karpeshin, F.F.

    2006-01-01

    Theory of resonance conversion is presented. Being a natural extension of the traditional internal conversion into the subthreshold area, resonance conversion in a number of cases strongly affects the nuclear processes. Moreover, concentrating the transition strength on the narrow bands corresponding to the spectral atomic lines, it offers a unique tool capable of accelerating nuclear decay rates. Furthermore, along with the conventional nonradiative process of nuclear excitation through NEET and its reverse, TEEN, resonance conversion offers an appropriate mathematics for consideration of a number of cross-invariant processes involving both nuclei and electrons: excitation and deexcitation of the nuclei by hyperfine magnetic field, nuclear spin mixing, hyperfine interaction and magnetic anomalies in the atomic spectra, collisional nuclear excitation via ionization of the shells in the muon decay in the orbit, etc. The mechanisms of the optical pumping of the isomers are also considered, as well as triggering their energy in the resonance field of a laser. The effect is especially high in the hydrogen-like heavy ions due to practical absence of any damping of the resonance. The theory is also generalized to the case of the discrete Auger transitions [ru

  2. Alginate gelation-induced cell death during laser-assisted cell printing

    International Nuclear Information System (INIS)

    Gudapati, Hemanth; Yan, Jingyuan; Huang, Yong; Chrisey, Douglas B

    2014-01-01

    Modified laser-induced forward transfer has emerged as a promising bioprinting technique. Depending on the operating conditions and cell properties, laser cell printing may cause cell injury and even death, which should be carefully elucidated for it to be a viable technology. This study has investigated the effects of alginate gelation, gelation time, alginate concentration, and laser fluence on the post-transfer cell viability of NIH 3T3 fibroblasts. Sodium alginate and calcium chloride are used as the gel precursor and gel reactant solution to form cell-laden alginate microspheres. It is found that the effects of gelation depend on the duration of gelation. Two-minute gelation is observed to increase the cell viability after 24 h incubation, mainly due to the protective cushion effect of the forming gel membrane during droplet landing. Despite the cushion effect from 10 min gelation, it is observed that the cell viability decreases after 24 h incubation because of the forming thick gel membrane that reduces nutrient and oxygen diffusion from the culture medium. In addition, the cell viability after 24 h incubation decreases as the laser fluence or alginate concentration increases. (paper)

  3. PREFACE: International Workshop on Multi-Rate Processes and Hysteresis

    Science.gov (United States)

    Mortell, Michael P.; O'Malley, Robert E.; Pokrovskii, Alexei; Rachinskii, Dmitrii; Sobolev, Vladimir A.

    2008-07-01

    We are interested in singular perturbation problems and hysteresis as common strongly nonlinear phenomena that occur in many industrial, physical and economic systems. The wording `strongly nonlinear' means that linearization will not encapsulate the observed phenomena. Often these two types of phenomena are manifested for different stages of the same or similar processes. A number of fundamental hysteresis models can be considered as limit cases of time relaxation processes, or admit an approximation by a differential equation which is singular with respect to a particular parameter. However, the amount of interaction between practitioners of theories of systems with time relaxation and systems with hysteresis (and between the `relaxation' and `hysteresis' research communities) is still low, and cross-fertilization is small. In recent years Ireland has become a home for a series of prestigious International Workshops in Singular Perturbations and Hysteresis: International Workshop on Multi-rate Processes and Hysteresis (University College Cork, Ireland, 3-8 April 2006). Proceedings are published in Journal of Physics: Conference Series, volume 55. See further information at http://euclid.ucc.ie/murphys2008.htm International Workshop on Hysteresis and Multi-scale Asymptotics (University College Cork, Ireland, 17-21 March 2004). Proceedings are published in Journal of Physics: Conference Series, volume 22. See further information at http://euclid.ucc.ie/murphys2006.htm International Workshop on Relaxation Oscillations and Hysteresis (University College Cork, Ireland, 1-6 April 2002). The related collection of invited lectures, was published as a volume Singular Perturbations and Hysteresis, SIAM, Philadelphia, 2005. See further information at http://euclid.ucc.ie/hamsa2004.htm International Workshop on Geometrical Methods of Nonlinear Analysis and Semiconductor Laser Dynamics (University College Cork, Ireland, 5-5 April 2001). A collection of invited papers has been

  4. THE PARTICIPATION OF INTERNATIONAL ENTITIES ON THE PUBLIC CONSULTATION PROCESS OF PUBLIC INTERNATIONAL ACCOUNTING STANDARD ABOUT INTANGIBLE ASSETS

    OpenAIRE

    Salaroli, Abner Ribeiro; de Almeida, José Elias Feres; Gama, Janyluce Rezende

    2015-01-01

    The public accounting follows the same direction of financial accounting on the search for convergence to international standards, where IFAC is the body responsible for issuing international standards of public accounting. In this context, this study aims to analyze the process of development of the international public accounting standard about public intangible assets. The analysis was performed based on the suggestions available in comment letters sent to the consultation process. As a th...

  5. The preparation of UO2 ceramic microspheres with an advanced process (TGU)

    International Nuclear Information System (INIS)

    Xu Zhichang; Tang Yaping; Zhang Fuhong

    1994-04-01

    The UO 2 ceramic microspheres are the most important materials in the spherical fuel elements for high temperature reactor (HTR). An advanced process for preparation of UO 2 ceramic microspheres has been developed at Institute of Nuclear Energy Technology, Tsinghua University. This process known as total gelation process of uranium (TGU), is based on the traditional sol-gel process, external gelation process and internal gelation process of uranium (EGU and IGU), and has been selected as the production process. The result of batch test is described. Accordance with the requirements of quality control (QC) and quality assurance (QA), the stabilization of operating parameters and product quality is tested., The results on batch test have shown that as well as all of the operated parameters are fixed, then the product quality can be stable as well as the product specification can be met. When the colloidal flow rate and the vibration frequency of nozzle are fixed, the kernel's size is also fixed. When the sintering temperature and time are fixed, the product density is also fixed. When the hydrogen atmosphere is used, the O/U ratio is very near to stoichiometry. The performance and structure of UO 2 ceramic microspheres are also given

  6. International Symposium on Dynamics of Ordering Processes in Condensed Matter

    CERN Document Server

    Furukawa, H

    1988-01-01

    The International Symposium on Dynamics of Ordering Processes in Condensed Matter was held at the Kansai Seminar House, Kyoto, for four days, from 27 to 30 August 1987, under the auspices of the Physical Soci­ ety of Japan. The symposium was financially supported by the four orga­ nizations and 45 companies listed on other pages in this volume. We are very grateful to all of them and particularly to the greatest sponsor, the Commemorative Association for the Japan World Exposition 1970. A total Df 22 invited lectures and 48 poster presentations were given and 110 participants attended from seven nations. An objective of the Symposium was to review and extend our present understanding of the dynamics of ordering processes in condensed matters, (for example, alloys, polymers and fluids), that are brought to an un­ stable state by sudden change of such external parameters as temperature and pressure. A second objective, no less important, was to identify new fields of science that might be investigated by sim...

  7. Self-Healing Phase Change Salogels with Tunable Gelation Temperature.

    Science.gov (United States)

    Karimineghlani, Parvin; Palanisamy, Anbazhagan; Sukhishvili, Svetlana A

    2018-04-19

    Chemically cross-linked polymer matrices have demonstrated strong potential for shape stabilization of molten phase change materials (PCM). However, they are not designed to be fillable and removable from a heat exchange module for an easy replacement with new PCM matrices and lack self-healing capability. Here, a new category of shapeable, self-healing gels, "salogels", is introduced. The salogels reversibly disassemble in a high-salinity environment of a fluid inorganic PCM [lithium nitrate trihydrate (LNH)], at a preprogrammed temperature. LNH was employed as a high latent heat PCM and simultaneously as a solvent, which supported the formation of a network of polyvinyl alcohol (PVA) chains via physical cross-linking through poly(amidoamine) dendrimers of various generations. The existence of hydrogen bonding and the importance of low-hydration state of PVA for the efficient gelation were experimentally confirmed. The thermal behavior of PCM salogels was highly reversible and repeatable during multiple heating/cooling cycles. Importantly, the gel-sol transition temperature could be precisely controlled within a range of temperature above LNH's melting point by the choice of dendrimer generation and their concentration. Shape stabilization and self-healing properties of the salogels, taken together with tunability of their temperature-induced fluidization make these materials attractive for thermal energy storage applications that require on-demand removal and replacement of used inorganic PCM salt hydrates.

  8. Supra-dendron Gelator Based on Azobenzene-Cyclodextrin Host-Guest Interactions: Photoswitched Optical and Chiroptical Reversibility.

    Science.gov (United States)

    Xie, Fan; Ouyang, Guanghui; Qin, Long; Liu, Minghua

    2016-12-12

    A novel amphiphilic dendron (AZOC 8 GAc) with three l-glutamic acid units and an azobenzene moiety covalently linked by an alkyl spacer has been designed. The compound formed hydrogels with water at very low concentration and self-assembled into chiral-twist structures. The gel showed a reversible macroscopic volume phase transition in response to pH variations and photo-irradiation. During the photo-triggered changes, although the gel showed complete reversibility in its optical absorptions, only an incomplete chiroptical property change was achieved. On the other hand, the dendron could form a 1:1 inclusion complex through a host-guest interaction with α-cyclodextrin (α-CD), designated as supra-dendron gelator AZOC 8 GAc/α-CD. The supra-dendron showed similar gelation behavior to that of AZOC 8 GAc, but with enhanced photoisomerization-transition efficiency and chiroptical switching capacity, which was completely reversible in terms of both optical and chiroptical performances. The self-assembly of the supra-dendron is a hierarchical or multi-supramolecular self-assembling process. This work has clearly illustrated that the hierarchical and multi-supramolecular self-assembling system endows the supramolecular nanostructures or materials with superior reversible optical and chiroptical switching. © 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  9. Effect of gum tragacanth exuded by three Iranian Astragalus on mixed milk protein system during acid gelation.

    Science.gov (United States)

    Nejatian, Mohammad; Hatami, Masoud; Mohammadifar, Mohammad Amin

    2013-02-01

    The effects of various concentrations of three species of gum tragacanth on the gelation process, microstructure and viscoelastic properties of milk protein mixed gels acidified at 37°C by glucono-δ-lactone (GDL) were investigated using dynamic rheometry and microscopy. According to rheological measurements, the addition of gum tragacanth in the range of 0.05-0.2% (w/w) into milk protein dispersions led to a weaker structure for the milk protein network, compared to the control sample. This weakening effect could be eliminated by adding 0.3% (w/w) gum tragacanth exudates from A. gossypinus; the compositional features of gum tragacanth may have been responsible for the improved protein-protein interactions, greater structural strength and reduced gelation time onset. It was determined by scanning electron microscopy that the addition of gum tragacanth at a low concentration caused the density of the matrix to increase, while an open structure was observed in the presence of a higher gum concentration. Copyright © 2012 Elsevier B.V. All rights reserved.

  10. Synthesis and Characterization of New Thiolated Chitosan Nanoparticles Obtained by Ionic Gelation Method

    Directory of Open Access Journals (Sweden)

    Reynaldo Esquivel

    2015-01-01

    Full Text Available We derivatized low molecular weight chitosan (LMWC with 3-mercaptopropanoic acid (3-MPA by a coupling reaction. The chemical modification of LMWC was characterized by Fourier transform infrared spectroscopy (FT-IR and nuclear magnetic resonance, 1HNMR. We researched the influence of 3-MPA on the nanoparticles formation by ionic gelation method using sodium tripolyphosphate (TPP as cross-linker reagent. In order to optimize the nanoparticles formation, we studied the effect of the pH solution and molar ratio on nanoparticles stability. Analyses of particle size, morphology, and surface charge were determined by dynamic light scattering, Atomic Force Microscopy, and zeta potential, respectively. It was found that formation of semispherical and stable nanoparticles was improved due to the chemical modification of chitosan. Optimized semispherical nanoparticles of thiolated chitosan were synthesized with the parameters (pH 4.7, molar ratios 1 : 106. Additionally, we reported the thermodynamic profile of the nanoparticles formation determined by isothermal titration calorimetry (ITC. The aggregation process achieved to form nanoparticles of thiolated and nonmodified chitosan consisted of two stages, considering one binding site model. Gibbs free energy (ΔG and binding constant (Ka describe the aggregation process of thiolated chitosan/TPP, which is an initial reaction and followed by an endothermic stage. These results are promising for the possible application of these nanoparticles as nanocarriers and delivery systems.

  11. Links between galaxy evolution, morphology and internal physical processes

    International Nuclear Information System (INIS)

    Kraljic, Katarina

    2014-01-01

    This thesis aims at making the link between galaxy evolution, morphology and internal physical processes, namely star formation as the outcome of the turbulent multiphase interstellar medium, using the cosmological zoom-in simulations, simulations of isolated and merging galaxies, and the analytic model of star formation. In Chapter 1, I explain the motivation for this thesis and briefly review the necessary background related to galaxy formation and modeling with the use of numerical simulations. I first explore the evolution of the morphology of Milky-Way-mass galaxies in a suite of zoom-in cosmological simulations through the analysis of bars. I analyze the evolution of the fraction of bars with redshift, its dependence on the stellar mass and accretion history of individual galaxies. I show in particular, that the fraction of bars declines with increasing redshift, in agreement with the observations. This work also shows that the obtained results suggest that the bar formation epoch corresponds to the transition between an early 'violent' phase of spiral galaxies formation at z > 1, during which they are often disturbed by major mergers or multiple minor mergers as well as violent disk instabilities, and a late 'secular' phase at z [fr

  12. A regional process under the international initiative for IFM

    Directory of Open Access Journals (Sweden)

    Murase Masahiko

    2016-01-01

    Full Text Available Climate change is likely to result in increases in the frequency or intensity of extreme weather events including floods. The International Flood Initiative (IFI, initiated in January 2005 by UNESCO and WMO and voluntary partner organizations has promoted an integrated flood management (IFM to take advantage of floods and use of floodplains while reducing the social, environmental and economic risks. Its secretariat is located in ICHARM. The initiative objective is to support national platforms to practice evidence-based disaster risk reduction through mobilizing scientific and research networks. After its initial decade, the initiative is providing a stepping-stone for the implementation of Sendai Framework by revitalizing its activities aimed at building on the sucess of the past, while addressing existing gaps in integrated flood managemnet strategies comprising of optimal structural and nonstructural measures thereby mainstreaming disaster risk reduction and targeting sustainable development. In this context, a new mechanism try to facilitate monitoring, assessment and capacity building in the Asia Pacific region. The primary outcomes of the mechanism are demand-driven networking and related documentations of best practices for 1 hazard assessment, 2 exposure assessment, 3 vulnerability assessment and coping capacity to identify the gaps, and 4 follow-ups and monitoring of the IFM process.

  13. Gelation of photopolymerized hyaluronic acid grafted with glycidyl methacrylate

    International Nuclear Information System (INIS)

    Prado, S.S.; Weaver, J.M.; Love, B.J.

    2011-01-01

    Experiments have tracked the ambient gelation of a series of hydrophilic hyaluronic acid (HA) resins grafted with glycidyl methacrylate (GM) and photopolymerized as a function of dose. The resin mixtures range in GMHA concentration between 0.5 and 1.5% w/w in phosphate buffered saline (PBS). Illuminated at 20 mW/cm 2 , the dynamic viscosity (η(t)) has been tracked and characterized using the Boltzmann log-sigmoidal model. A gelled viscosity of ∼ 10 Pa s was determined at 0.5% w/w which rose to ∼ 50 Pa s at or above 1% w/w. More curing agent marginally increased the gel viscosity at each concentration. Time constants associated with viscosity advancement were shortest at [GMHA] = 1.0%; higher concentrations are attributed with lower quantum efficiency when illuminated. Subsequent frequency sweeps replicated already published work using similar GHMA concentrations in PBS. G' values ranged from 100 to 500 Pa over the formulation range with expected sensitivity to GMHA and curing agent concentration. Overall, the sigmoidal model represented this advancing viscosity data well, and further analysis of the physical significance of these model parameters may help in understanding photopolymerization of this complicated formulation more broadly. Highlights: → The ambient dynamic viscosity of photopolymerized GMHA gels has been measured. → 2 physical parameters and two time constants were extracted from the sigmoidal model. → Higher crosslinker content for a fixed GMHA concentration led to higher gel viscosity. → The time to toggle between the initial and final viscosity ranged between 5 and 10 s. → Dynamic frequency sweep tests on cured gels also revealed G' values between 100 and 500 Pa.

  14. Thermal gelation and tissue adhesion of biomimetic hydrogels

    International Nuclear Information System (INIS)

    Burke, Sean A; Ritter-Jones, Marsha; Lee, Bruce P; Messersmith, Phillip B

    2007-01-01

    Marine and freshwater mussels are notorious foulers of natural and manmade surfaces, secreting specialized protein adhesives for rapid and durable attachment to wet substrates. Given the strong and water-resistant nature of mussel adhesive proteins, significant potential exists for mimicking their adhesive characteristics in bioinspired synthetic polymer materials. An important component of these proteins is L-3,4-dihydroxylphenylalanine (DOPA), an amino acid believed to contribute to mussel glue solidification through oxidation and crosslinking reactions. Synthetic polymers containing DOPA residues have previously been shown to crosslink into hydrogels upon the introduction of oxidizing reagents. Here we introduce a strategy for stimuli responsive gel formation of mussel adhesive protein mimetic polymers. Lipid vesicles with a bilayer melting transition of 37 0 C were designed from a mixture of dipalmitoyl and dimyristoyl phosphatidylcholines and exploited for the release of a sequestered oxidizing reagent upon heating from ambient to physiologic temperature. Colorimetric studies indicated that sodium-periodate-loaded liposomes released their cargo at the phase transition temperature, and when used in conjunction with a DOPA-functionalized poly(ethylene glycol) polymer gave rise to rapid solidification of a crosslinked polymer hydrogel. The tissue adhesive properties of this biomimetic system were determined by in situ thermal gelation of liposome/polymer hydrogel between two porcine dermal tissue surfaces. Bond strength measurements showed that the bond formed by the adhesive hydrogel (mean = 35.1 kPa, SD = 12.5 kPa, n = 11) was several times stronger than a fibrin glue control tested under the same conditions. The results suggest a possible use of this biomimetic strategy for repair of soft tissues

  15. Synergistic enhancement in the co-gelation of salt-soluble pea proteins and whey proteins.

    Science.gov (United States)

    Wong, Douglas; Vasanthan, Thava; Ozimek, Lech

    2013-12-15

    This paper investigated the enhancement of thermal gelation properties when salt-soluble pea proteins were co-gelated with whey proteins in NaCl solutions, using different blend ratios, total protein concentrations, pH, and salt concentrations. Results showed that the thermal co-gelation of pea/whey proteins blended in ratio of 2:8 in NaCl solutions showed synergistic enhancement in storage modulus, gel hardness, paste viscosity and minimum gelation concentrations. The highest synergistic enhancement was observed at pH 6.0 as compared with pH 4.0 and 8.0, and at the lower total protein concentration of 10% as compared with 16% and 22% (w/v), as well as in lower NaCl concentrations of 0.5% and 1.0% as compared with 1.5%, 2.0%, 2.5%, and 3.0% (w/v). The least gelation concentrations were also lower in the different pea/whey protein blend ratios than in pure pea or whey proteins, when dissolved in 1.0% or 2.5% (w/v) NaCl aqueous solutions. Copyright © 2013 Elsevier Ltd. All rights reserved.

  16. Insight on the formation of chitosan nanoparticles through ionotropic gelation with tripolyphosphate.

    Science.gov (United States)

    Koukaras, Emmanuel N; Papadimitriou, Sofia A; Bikiaris, Dimitrios N; Froudakis, George E

    2012-10-01

    This work reports details pertaining to the formation of chitosan nanoparticles that we prepare by the ionic gelation method. The molecular interactions of the ionic cross-linking of chitosan with tripolyphosphate have been investigated and elucidated by means of all-electron density functional theory. Solvent effects have been taken into account using implicit models. We have identified primary-interaction ionic cross-linking configurations that we define as H-link, T-link, and M-link, and we have quantified the corresponding interaction energies. H-links, which display high interaction energies and are also spatially broadly accessible, are the most probable cross-linking configurations. At close range, proton transfer has been identified, with maximum interaction energies ranging from 12.3 up to 68.3 kcal/mol depending on the protonation of the tripolyphosphate polyanion and the relative coordination of chitosan with tripolyphosphate. On the basis of our results for the linking types (interaction energies and torsion bias), we propose a simple mechanism for their impact on the chitosan/TPP nanoparticle formation process. We introduce the β ratio, which is derived from the commonly used α ratio but is more fundamental since it additionally takes into account structural details of the oligomers.

  17. Production and characterization of alginate-starch-chitosan microparticles containing stigmasterol through the external ionic gelation technique

    Directory of Open Access Journals (Sweden)

    Gislene Mari Fujiwara

    2013-09-01

    Full Text Available Stigmasterol - a plant sterol with several pharmacological activities - is susceptible to oxidation when exposed to air, a process enhanced by heat and humidity. In this context, microencapsulation is a way of preventing oxidation, allowing stigmasterol to be incorporated into various pharmaceutical forms while increasing its absorption. Microparticles were obtained using a blend of polymers of sodium alginate, starch and chitosan as the coating material through a one-stage process using the external gelation technique. Resultant microparticles were spherical, averaging 1.4 mm in size. Encapsulation efficiency was 90.42% and method yield 94.87%. The amount of stigmasterol in the oil recovered from microparticles was 9.97 mg/g. This technique proved feasible for the microencapsulation of stigmasterol.

  18. SANS study of understanding mechanism of cold gelation of globular proteins

    International Nuclear Information System (INIS)

    Chinchalikar, A. J.; Kumar, Sugam; Aswal, V. K.; Wagh, A. G.; Kohlbrecher, J.

    2014-01-01

    Small-angle neutron scattering (SANS) has been used to probe the evolution of interaction and the resultant structures in the cold gelation of globular proteins. The cold gelation involves two steps consisting of irreversible protein deformation by heating followed by some means (e.g. increasing ionic strength) to bring them together at room temperature. We have examined the role of different salts in cold gelation of preheated aqueous Bovine Serum Albumin (BSA) protein solutions. The interactions have been modeled by two Yukawa potential combining short-range attraction and long-range repulsion. We show that in step 1 (preheated temperature effect) the deformation of protein increases the magnitude of attractive interaction but not sufficient to induce gel. The attractive interaction is further enhanced in step 2 (salt effect) to result in gel formation. The salt effect is found to be strongly depending on the valency of the counterions. The gel structure has been characterized by the mass fractals

  19. [The balanced scorecard used as a management tool in a clinical laboratory: internal business processes indicators].

    Science.gov (United States)

    Salinas La Casta, Maria; Flores Pardo, Emilio; Uris Selles, Joaquín

    2009-01-01

    to propose a set of indicators as a management tool for a clinical laboratory, by using the balanced scorecard internal business processes perspective. indicators proposed are obtained from different sources; external proficiency testing of the Valencia Community Government, by means of internal surveys and laboratory information system registers. One year testing process proportion indicators results are showed. internal management indicators are proposed (process, appropriateness and proficiency testing). The process indicators results show gradual improvement since its establishment. after one years of using a conceptually solid Balanced Scorecard Internal business processes perspective indicators, the obtained results validate the usefulness as a laboratory management tool.

  20. Silica-gel structural characterization during the initial phases of gelation and drying; Caracterizacao estrutural de geis de silica durante as etapas iniciais de gelacao e secagem

    Energy Technology Data Exchange (ETDEWEB)

    Ferreira, Max Passos

    1997-12-31

    For centuries, glasses and ceramics have been made via melting or solid state reactions at temperatures above 100 deg C. The sol-gel process offers new approaches to the synthesis of glasses and ceramics, combining control of composition and structure at the molecular level with the ability to shape materials in bulk, powder, fiber and thin-film forms. The growth of sol-gel technology research is due to the many unique features of that class of materials. Major applications include optical elements and integrated optical devices, ceramic filters, membranes, supercondutors, magnetic, catalytic and manostructured materials to antioxidant, anticorrosion coatings and composite and biomedical materials. In this work a variety of techniques like spectroscopy, Raman spectroscopy, ultraviolet-visible spectroscopy, light scattering nuclear magnetic resonance, X ray diffraction and nitrogen adsorption have been employed to investigate the initial phase of the sol-gel transition of gamma ray irradiated tetramethoxysilane (TMOS) solutions and non-irradiated TMOS solution and to get information about the structure of the silica gels obtained under different gelation conditions. Typically the tetramethoxysilane solutions were prepared using a molar ratio of TMOS to demineralized water of 1 to 16. Some experiments were made under catalysed conditions. The mixing was carried out at room temperature. The turbidity and light scattering experiments on the polycondensation of tetramethoxysilane show that exists no drastic difference in the gelling time of a gamma ray irradiated and a non-irradiated TMOS+H{sub 2}O (1+16 M) solution. In the absence of a catalyst, the gelling time for both reactions occurs in about 3.30 h. When HNO{sub 3} (o.03 M) was used, the gelling time observed was 3 days. Raman and ultraviolet-visible spectroscopy show no drastic difference during the initial phase at the sol-gel transition under ambient temperature/pressure and under gamma radiation. The gels

  1. Silica-gel structural characterization during the initial phases of gelation and drying; Caracterizacao estrutural de geis de silica durante as etapas iniciais de gelacao e secagem

    Energy Technology Data Exchange (ETDEWEB)

    Ferreira, Max Passos

    1996-12-31

    For centuries, glasses and ceramics have been made via melting or solid state reactions at temperatures above 100 deg C. The sol-gel process offers new approaches to the synthesis of glasses and ceramics, combining control of composition and structure at the molecular level with the ability to shape materials in bulk, powder, fiber and thin-film forms. The growth of sol-gel technology research is due to the many unique features of that class of materials. Major applications include optical elements and integrated optical devices, ceramic filters, membranes, supercondutors, magnetic, catalytic and manostructured materials to antioxidant, anticorrosion coatings and composite and biomedical materials. In this work a variety of techniques like spectroscopy, Raman spectroscopy, ultraviolet-visible spectroscopy, light scattering nuclear magnetic resonance, X ray diffraction and nitrogen adsorption have been employed to investigate the initial phase of the sol-gel transition of gamma ray irradiated tetramethoxysilane (TMOS) solutions and non-irradiated TMOS solution and to get information about the structure of the silica gels obtained under different gelation conditions. Typically the tetramethoxysilane solutions were prepared using a molar ratio of TMOS to demineralized water of 1 to 16. Some experiments were made under catalysed conditions. The mixing was carried out at room temperature. The turbidity and light scattering experiments on the polycondensation of tetramethoxysilane show that exists no drastic difference in the gelling time of a gamma ray irradiated and a non-irradiated TMOS+H{sub 2}O (1+16 M) solution. In the absence of a catalyst, the gelling time for both reactions occurs in about 3.30 h. When HNO{sub 3} (o.03 M) was used, the gelling time observed was 3 days. Raman and ultraviolet-visible spectroscopy show no drastic difference during the initial phase at the sol-gel transition under ambient temperature/pressure and under gamma radiation. The gels

  2. Heat processing of gels into sintered uranium dioxide modelled by thermal analysis. I

    International Nuclear Information System (INIS)

    Landspersky, H.; Urbanek, V.

    1979-01-01

    Thermoanalytical methods were used for investigating the processes of air drying and calcination of gels prepared by internal gelation of uranyl nitrate, urea and urotropine solutions at 90 degC. The gels were dried in air at room temperature, at 220 degC in a controlled atmosphere or by azeotropic distillation with CCl 4 . The course of thermal decomposition of the gel depends not only on the drying method used but also on the medium in which the drying process takes place. If the drying is carried out so as to produce a macroporous structure after the elimination of most of the water, ammonia and possibly other gelation by-products and non-reacted gelating agents, the resulting gels can be further processed by calcination, reduction and sintering, thus obtaining compact undamaged spheres of sintered uranium dioxide. Dilatometric analysis generated of uranium trioxide gels showed that the transformation of UO 3 to U 3 O 8 generated another intermediate thermal decomposition product showing a change in dimensions at temperatures of about 520 degC and a change in colour. This phenomenon is analogous to the decomposition of UO 3 prepared by thermal decomposition of α-UO 3 .2H 2 O involving a change in weight producing the UOsub(3-x) compound or a phase transformation with a change in colour; the structural conversion cannot be identified by X-ray structural analysis. (author)

  3. Isothermal martensitic transformation as an internal-stress-increasing process

    International Nuclear Information System (INIS)

    Liu, Y.; Xie, Z.L.; Haenninen, H.; Humbeeck, J. van; Pietikaeinen, J.

    1995-01-01

    Based on the results that the magnitude of the stabilization of retained austenite increases with increasing the amount of martensite transformed, it has been assumed that the martensitic transformation is accompanied with an increase in internal resisting stress which subsequently results in the stabilization of retained austenite. By simplifying this internal resisting stress to be a type of hydrostatic compressive stress acting on retained austenite due to surrounding martensite plates, a thermodynamical analysis for an isothermal martensitic transformation under applied hydrostatic pressure has been performed. The calculated results, to some extent, show a good agreement with the experimental data. (orig.)

  4. Study of Hygrothermal Processes in External Walls with Internal Insulation

    Directory of Open Access Journals (Sweden)

    Biseniece Edite

    2018-03-01

    Full Text Available Being an important contributor to the final energy consumption, historic buildings built before 1945 have high specific heating energy consumption compared to current energy standards and norms. However, they often cannot be insulated from the outside due to their heritage and culture value. Internal insulation is an alternative. However internal insulation faces challenges related to hygrothermal behaviour leading to mold growth, freezing, deterioration and other risks. The goal of this research is to link hygrothermal simulation results with experimental results for internally insulated historic brick masonry to assess correlation between simulated and measured data as well as the most influential parameters. The study is carried out by both a mathematical simulation tool and laboratory tests of historic masonry with internal insulation with four insulation materials (mineral wool, EPS, wood fiber and granulated aerogel in a cold climate (average 4000 heating degree days. We found disparity between measured and simulated hygrothermal performance of studied constructions due to differences in material parameters and initial conditions of materials. The latter plays a more important role than material parameters. Under a steady state of conditions, the condensate tolerating system varies between 72.7 % and 80.5 % relative humidity, but in condensate limiting systems relative humidity variates between 73.3 % and 82.3 %. The temperature between the masonry wall and all insulation materials has stabilized on average at +10 °C. Mold corresponding to Mold index 3 was discovered on wood fiber mat.

  5. Study of Hygrothermal Processes in External Walls with Internal Insulation

    Science.gov (United States)

    Biseniece, Edite; Freimanis, Ritvars; Purvins, Reinis; Gravelsins, Armands; Pumpurs, Aivars; Blumberga, Andra

    2018-03-01

    Being an important contributor to the final energy consumption, historic buildings built before 1945 have high specific heating energy consumption compared to current energy standards and norms. However, they often cannot be insulated from the outside due to their heritage and culture value. Internal insulation is an alternative. However internal insulation faces challenges related to hygrothermal behaviour leading to mold growth, freezing, deterioration and other risks. The goal of this research is to link hygrothermal simulation results with experimental results for internally insulated historic brick masonry to assess correlation between simulated and measured data as well as the most influential parameters. The study is carried out by both a mathematical simulation tool and laboratory tests of historic masonry with internal insulation with four insulation materials (mineral wool, EPS, wood fiber and granulated aerogel) in a cold climate (average 4000 heating degree days). We found disparity between measured and simulated hygrothermal performance of studied constructions due to differences in material parameters and initial conditions of materials. The latter plays a more important role than material parameters. Under a steady state of conditions, the condensate tolerating system varies between 72.7 % and 80.5 % relative humidity, but in condensate limiting systems relative humidity variates between 73.3 % and 82.3 %. The temperature between the masonry wall and all insulation materials has stabilized on average at +10 °C. Mold corresponding to Mold index 3 was discovered on wood fiber mat.

  6. The 4th international colloquium on process simulation. Proceedings

    Energy Technology Data Exchange (ETDEWEB)

    Jokilaakso, A [Helsinki Univ. of Technology, Otaniemi (Finland). Dept. of Materials Science and Metallurgy

    1998-12-31

    The papers collected in this volume were presented at the 4th Colloquium on Process Simulation held at Helsinki University of Technology, Espoo, Finland, June 11-13, 1997. In the more developed industrial nations, the processes for producing chemicals, energy, and materials encounter environmental concern and laws which challenge engineers to develop the processes towards more efficient, economical and safe operation. This necessitates more thorough understanding of the processes and phenomena involved. Formerly, the development of the processes was largely based on trial and error, whereas today, the development of computer performance together with the diversification of modelling software enables simulation of the processes. The increased capacity and possibilities for modelling the processes brought by the improved hardware and software, have generated a strong demand for more accurate mathematical descriptions of the processes. Especially, the coupling of computational fluid dynamics and chemical kinetics, combustion, and thermodynamics is of current interest in process oriented technology. This colloquium attempts to give examples of modelling efforts in operation in different universities, research institutes and companies. Furthermore, the aim of this colloquium is to offer an annual opportunity to the researchers to come together and discuss their common problems and the state of their investigations

  7. The 4th international colloquium on process simulation. Proceedings

    Energy Technology Data Exchange (ETDEWEB)

    Jokilaakso, A. [Helsinki Univ. of Technology, Otaniemi (Finland). Dept. of Materials Science and Metallurgy

    1997-12-31

    The papers collected in this volume were presented at the 4th Colloquium on Process Simulation held at Helsinki University of Technology, Espoo, Finland, June 11-13, 1997. In the more developed industrial nations, the processes for producing chemicals, energy, and materials encounter environmental concern and laws which challenge engineers to develop the processes towards more efficient, economical and safe operation. This necessitates more thorough understanding of the processes and phenomena involved. Formerly, the development of the processes was largely based on trial and error, whereas today, the development of computer performance together with the diversification of modelling software enables simulation of the processes. The increased capacity and possibilities for modelling the processes brought by the improved hardware and software, have generated a strong demand for more accurate mathematical descriptions of the processes. Especially, the coupling of computational fluid dynamics and chemical kinetics, combustion, and thermodynamics is of current interest in process oriented technology. This colloquium attempts to give examples of modelling efforts in operation in different universities, research institutes and companies. Furthermore, the aim of this colloquium is to offer an annual opportunity to the researchers to come together and discuss their common problems and the state of their investigations

  8. Solvent-mediated pathways to gelation and phase separation in suspensions of grafted nanoparticles

    KAUST Repository

    Anyfantakis, Manos

    2009-01-01

    We explore the role of the solvent medium on the interplay between gelation and phase separation in suspensions of organosilicate planar hybrids grafted with hydrocarbon chains. We establish their phase diagram by means of dynamic light scattering, rheology and visual observations, and different routes to gelation, depending on the solvent used. In agreement with earlier works, the solvent quality for the grafted chains at a given temperature controls the balance between attractions and repulsions, and hence the phase diagram of the nanoparticles and their tendency to gel. Here we show how to tune the suspension state and hence its rheology. For decane, a good solvent for the hydrocarbon chains, gelation occurs at rather low volume fractions in the presence of phase separation. This is due to the interdigitation of solvent molecules with the grafted chains, resulting in their crystalline packing that promotes the attraction between particles. For toluene, a solvent of reduced quality for the hydrocarbon chains, no interdigitation takes place, and hence gelation is triggered by clustering at higher volume fractions before phase separation. Our results support the generic picture of complex kinetic arrest/phase separation interplay in soft matter, where phase separation can proceed, be interrupted or be completely inhibited. A number of interesting possibilities for tailoring the rheology of grafted colloidal systems emerge. © 2009 The Royal Society of Chemistry.

  9. A saponification-triggered gelation of ester-based Zn(II) complex through conformational transformations.

    Science.gov (United States)

    Kumar, Ashish; Dubey, Mrigendra; Kumar, Amit; Pandey, Daya Shankar

    2014-09-11

    Novel saponification-triggered gelation in an ester-based bis-salen Zn(II) complex (1) is described. Strategic structural modifications induced by NaOH in 1 tune the dipolar-/π-interactions leading to J-aggregation and the creation of an inorganic gel material (IGM), which has been established by photophysical, DFT and rheological studies.

  10. KINETICS OF A SILICATE COMPOSITION GELATION IN PRESENCE OF REACTION RATE REGULATING COMPOUNDS

    Directory of Open Access Journals (Sweden)

    Olga Titova

    2013-12-01

    Full Text Available The influence of organic and inorganic additions on the formation rate of the silicate gels standard systems – sodium silicate solution in model fresh water was studied. As a result of the experiments were selected optimum concentrations of additives - gelation time regulators

  11. Controlling the aggregation and gelation of ß-lactoglobulin by the addition of its peptides

    NARCIS (Netherlands)

    Kosters, H.A.

    2012-01-01

    In this thesis the effects of peptides, or protein hydrolysates on the heat-induced aggregation and gelation of (concentrated) protein systems were studied. First, it was investigated if specific peptides could influence the heat-induced denaturation and aggregation of intact proteins solutions,

  12. The Internationalization Process of International New Ventures: The Case of Skype

    OpenAIRE

    Chan, Cheuk-Hay

    2007-01-01

    Past literature has emphasized on large, long-established multinational enterprises (MNEs) in international business. However, the emerging phenomenon of international new ventures has attracted much attention due to their distinctive internationalization processes. Skype Technologies S.A. is one of these international new ventures with comparable characteristics, albeit it has shown differences compared with the typical international new ventures. This research aims to compare and contrast t...

  13. Gelation of high-methoxy pectin by enzymic de-esterification in the presence of calcium ions: a preliminary evaluation.

    Science.gov (United States)

    O'Brien, Aileen B; Philp, Kevin; Morris, Edwin R

    2009-09-28

    Cohesive gels have been obtained by de-esterification of 1.0wt% high-methoxy citrus pectin (degree of esterification approximately 68%) in the presence of Ca(2+) cations, using a commercial preparation (NovoShape) of fungal methyl esterase cloned from Aspergillus aculeatus. A convenient rate of network formation (gelation within approximately 30min) was achieved at an enzyme concentration of 0.2 PEU/g pectin. At a Ca(2+)-concentration of 40mM and incubation temperature of 20 degrees C, severe syneresis (>7% of sample mass) was observed, but release of fluid decreased with decreasing concentration of Ca(2+) and increasing temperature of incubation, becoming undetectable for 10mM Ca(2+) at 30 degrees C. Under these conditions, progressive development of solid-like character (storage modulus, G') was observed during 160min of enzymic de-esterification, and the mechanical spectrum recorded at the end of the incubation period had the form typical of a biopolymer gel. On subsequent heating to 70 degrees C, dissociation of the gel network (sigmoidal reduction in G' and G'') was observed. At or above the midpoint temperature of this melting process ( approximately 50 degrees C), there was no indication of gel formation on enzymic de-esterification (at 50 or 60 degrees C). At lower temperatures (20, 30 and 40 degrees C), the rate of gelation (assessed visually) showed no systematic increase as the incubation temperature was increased towards the temperature-optimum of the enzyme ( approximately 50 degrees C). This unexpected behaviour is attributed to competition between faster de-esterification and slower formation of Ca(2+)-induced 'egg-box' junctions.

  14. Benchmarking processes for managing large international space programs

    Science.gov (United States)

    Mandell, Humboldt C., Jr.; Duke, Michael B.

    1993-01-01

    The relationship between management style and program costs is analyzed to determine the feasibility of financing large international space missions. The incorporation of management systems is considered to be essential to realizing low cost spacecraft and planetary surface systems. Several companies ranging from large Lockheed 'Skunk Works' to small companies including Space Industries, Inc., Rocket Research Corp., and Orbital Sciences Corp. were studied. It is concluded that to lower the prices, the ways in which spacecraft and hardware are developed must be changed. Benchmarking of successful low cost space programs has revealed a number of prescriptive rules for low cost managements, including major changes in the relationships between the public and private sectors.

  15. The Role of International Juridical Process in International Security and Civil-Military Relations

    Science.gov (United States)

    2002-12-01

    judged, although under domestic criminal law provisions, certainly in the light of the Nuremberg principles, e.g. the Eichmann case by the District...Court of Jerusalem in 1961, and the case of Klaus Barbie in France. Until today the application of international rules of war remains generally

  16. International cooperative effort to establish dosimetry standardization for radiation processing

    International Nuclear Information System (INIS)

    Farrar, Harry IV

    1990-01-01

    Radiation processing is a rapidly developing technology with numerous applications in food treatment, sterilization, and polymer modification. The effectiveness of the process depends, however, on the proper application of dose and its measurement. These aspects are being considered by a wide group of experts from around the world who have joined together to write a comprehensive set of standards for dosimetry for radiation processing. Originally formed in 1984 to develop standards for food processing dosimetry, the group has now expanded into a full subcommittee of the American Society for Testing and Materials (ASTM), with 97 members from 19 countries. The scope of the standards now includes dosimetry for all forms and applications of radiation processing. To date, the group has completed and published four standards, and is working on an additional seven. Three are specifically for food applications and the others are for all radiation applications, including food processing. Together, this set of standards will specify acceptable guidelines and methods for accomplishing the required irradiation treatment. This set will be available for adoption by national regulatory agencies or other standards-setting organizations for their procedures and protocols. (author)

  17. International cooperative effort to establish dosimetry standardization for radiation processing

    International Nuclear Information System (INIS)

    Farrar, H. IV.

    1989-01-01

    Radiation processing is a rapidly developing technology with numerous applications in food treatment, sterilization, and polymer modification. The effectiveness of the process depends, however, on the proper application of dose and its measurement. These aspects are being considered by a wide group of experts from around the world who have joined together to write a comprehensive set of standards for dosimetry for radiation processing. Originally formed in 1984 to develop standards for food processing dosimetry, the group has now expanded into a full subcommittee of the American Society for Testing and Materials (ASTM), with 97 members from 19 countries. The scope of the standards now includes dosimetry for all forms of radiation processing. The group has now completed and published four standards, and is working on an additional seven. Three are specifically for food applications and the others are for all radiation applications, including food processing. Together, this set of standards will specify acceptable guidelines and methods for accomplishing the required irradiation treatment, and will be available for adoption by national regulatory agencies in their procedures and protocols. 1 tab

  18. Working memory as internal attention: toward an integrative account of internal and external selection processes.

    Science.gov (United States)

    Kiyonaga, Anastasia; Egner, Tobias

    2013-04-01

    Working memory (WM) and attention have been studied as separate cognitive constructs, although it has long been acknowledged that attention plays an important role in controlling the activation, maintenance, and manipulation of representations in WM. WM has, conversely, been thought of as a means of maintaining representations to voluntarily guide perceptual selective attention. It has more recently been observed, however, that the contents of WM can capture visual attention, even when such internally maintained representations are irrelevant, and often disruptive, to the immediate external task. Thus, the precise relationship between WM and attention remains unclear, but it appears that they may bidirectionally impact one another, whether or not internal representations are consistent with the external perceptual goals. This reciprocal relationship seems, further, to be constrained by limited cognitive resources to handle demands in either maintenance or selection. We propose here that the close relationship between WM and attention may be best described as a give-and-take interdependence between attention directed toward either actively maintained internal representations (traditionally considered WM) or external perceptual stimuli (traditionally considered selective attention), underpinned by their shared reliance on a common cognitive resource. Put simply, we argue that WM and attention should no longer be considered as separate systems or concepts, but as competing and influencing one another because they rely on the same limited resource. This framework can offer an explanation for the capture of visual attention by irrelevant WM contents, as well as a straightforward account of the underspecified relationship between WM and attention.

  19. Working Memory as Internal Attention: Toward an Integrative Account of Internal and External Selection Processes

    Science.gov (United States)

    Kiyonaga, Anastasia; Egner, Tobias

    2012-01-01

    Working memory (WM) and attention have been studied as separate cognitive constructs, although it has long been acknowledged that attention plays an important role in controlling the activation, maintenance, and manipulation of representations in WM. WM has, conversely, been thought of as a means of maintaining representations to voluntarily guide perceptual selective attention. It has more recently been observed, however, that the contents of WM can capture visual attention, even when such internally maintained representations are irrelevant, and often disruptive, to the immediate external task. Thus the precise relationship between WM and attention remains unclear, but it appears that they may bi-directionally impact one another, whether or not internal representations are consistent with external perceptual goals. This reciprocal relationship seems, further, to be constrained by limited cognitive resources to handle demands in either maintenance or selection. We propose here that the close relationship between WM and attention may be best described as a give-and-take interdependence between attention directed toward actively maintained internal representations (traditionally considered WM) versus external perceptual stimuli (traditionally considered selective attention), underpinned by their shared reliance on a common cognitive resource. Put simply, we argue that WM and attention should no longer be considered as separate systems or concepts, but as competing and impacting one another because they rely on the same limited resource. This framework can offer an explanation for the capture of visual attention by irrelevant WM contents, as well as a straightforward account of the underspecified relationship between WM and attention. PMID:23233157

  20. External Influences on an Internal Process: Supporting Preservice Teacher Research

    Science.gov (United States)

    Schulte, Ann; Klipfel, Lyndsay Halpin

    2016-01-01

    In an effort to better understand how participating in teacher research as a student teacher compares to conducting it as a practicing teacher, a teacher educator and her former teacher education student engaged in a collaborative dialogue. They focus their reflections in this article on the impact of external forces on the process of teacher…

  1. Anatomical characteristics of the styloid process in internal carotid artery dissection: Case-control study.

    Science.gov (United States)

    Amorim, José M; Pereira, Daniela; Rodrigues, Marta G; Beato-Coelho, José; Lopes, Margarida; Cunha, André; Figueiredo, Sofia; Mendes-Pinto, Mafalda; Ferreira, Carla; Sargento-Freitas, João; Castro, Sérgio; Pinho, João

    2018-06-01

    Introduction Pathophysiology of cervical artery dissection is complex and poorly understood. In addition to well-known causative and predisposing factors, including major trauma and monogenic connective tissue disorders, morphological characteristics of the styloid process have been recently recognized as a possible risk factor for cervical internal carotid artery dissection. Aims To study the association of the anatomical characteristics of styloid process with internal carotid artery dissection. Methods Retrospective, multicenter, case-control study of patients with internal carotid artery dissection and age- and sex-matched controls. Consecutive patients with internal carotid artery dissection and controls with ischemic stroke or transient ischemic attack of any etiology excluding internal carotid artery dissection, who had performed computed tomography angiography, diagnosed between January 2010 and September 2016. Two independent observers measured styloid process length and styloid process distance to internal carotid artery. Results Sixty-two patients with internal carotid artery dissection and 70 controls were included. Interobserver agreement was good for styloid process length and styloid process-internal carotid artery distance (interclass correlation coefficient = 0.89 and 0.76, respectively). Styloid process ipsilateral to dissection was longer than left and right styloid process in controls (35.8 ± 14.4 mm versus 30.4 ± 8.9 mm and 30.3 ± 8.2 mm, p = 0.011 and p = 0.008, respectively). Styloid process-internal carotid artery distance ipsilateral to dissection was shorter than left and right distance in controls (6.3 ± 1.9 mm versus 7.2 ± 2.1 mm and 7.0 ± 2.3 mm, p = 0.003 and p = 0.026, respectively). Internal carotid artery dissection was associated with styloid process length (odds ratio = 1.04 mm -1 , 95% confidence interval = 1.01-1.08, p = 0.015) and styloid process-internal

  2. Understanding national and international safeguards: an evolutionary process

    International Nuclear Information System (INIS)

    Higinbotham, W.A.

    1983-01-01

    Domestic and international safeguards have been evolving and will continue to evolve. in the case of the United States, the concern was to protect the classified materials, at first. Then attention focussed on material accounting, then on measures to promptly detect theft by individuals with access, and later on physical protection to ward-off armed terrorists. The objective of the IAEA has always been to provide assurance that nuclear materials are not being diverted from the peaceful facilities that are under safeguards. The evolution has taken place in deciding how to provide this assurance, and in the definition of specific safeguards goals. In both cases the technology needed to meet the goals has improved due to R and D and to experience. A plea is made for more cooperation betwen those who develop and manage the policies, those who develop safeguards techniques, and those who are subject to national and IAEA safeguards. Some illustrations of the evolution of policies, inadequate coordination and general progress are given

  3. International seminar on safeguards information reporting and processing. Extended synopses

    International Nuclear Information System (INIS)

    1998-01-01

    Review of the safeguards of information technology, its current developments and status of safeguards in Member States are described concerning especially the role of domestic safeguards in cooperation with IAEA Safeguards. A Number of reports is dealing with declarations provided to the IAEA pursuant to Protocols Additional to Safeguard agreements. The Information Section of the IAEA Safeguards Information Technology Division is responsible for the data entry, loading and quality control od State supplied declarations. A software system is used to process information which should be readily accessible and usable in implementation of the strengthened safeguards system. Experiences in combating illegal trafficking of nuclear materials in a number of countries are included

  4. AN INVESTIGATION INTO FACTORS INFLUENCING INTERNATIONAL STRATEGIC ALLIANCE PROCESS

    Directory of Open Access Journals (Sweden)

    Sari Wahyuni

    2003-02-01

    Full Text Available Empirical research indicates that strategic alliances, like other organizational forms, emerge as an adaptive mechanism to market uncertainty, and their developments over time reflect the co-evolution of distinctive firm capabilities and of industry and market activities. Interestingly, most strategic alliances go through similar revolutionary cycles in terms of their motives and capabilities toward the cooperative relationship. Studies in this areas how that alliance failure is an outcome of the co-evolutionary adjustment to changes in the market, the competitive dynamics between partners, and assessment of efficiency of the alliance as an alternative governance structure. It is thus critical to adopt a dynamics perspective and historical observations of cooperative process. This paper attempts to distil, derive and integrate theories across different perspectives into a unified framework that offers a better understanding of alliance process development. Our analysis shows that we can divide strategic alliance development into three phases of development: formation, operation and evaluation. We further endeavor to seek the important factors that should be taken into account in each stage of their life.

  5. Biomass Gasification for Power Generation Internal Combustion Engines. Process Efficiency

    International Nuclear Information System (INIS)

    Lesme-Jaén, René; Garcia-Faure, Luis; Oliva-Ruiz, Luis; Pajarín-Rodríguez, Juan; Revilla-Suarez, Dennis

    2016-01-01

    Biomass is a renewable energy sources worldwide greater prospects for its potential and its lower environmental impact compared to fossil fuels. By different processes and energy conversion technologies is possible to obtain solid, liquid and gaseous fuels from any biomass.In this paper the evaluation of thermal and overall efficiency of the gasification of Integral Forestry Company Santiago de Cuba is presented, designed to electricity generation from waste forest industry. The gasifier is a downdraft reactor, COMBO-80 model of Indian manufacturing and motor (diesel) model Leyland modified to work with producer gas. The evaluation was conducted at different loads (electric power generated) of the motor from experimental measurements of flow and composition of gas supplied to the engine. The results show that the motor operates with a thermal efficiency in the range of 20-32% with an overall efficiency between 12-25 %. (author)

  6. International seminar on safeguards information reporting and processing. Extended synopses

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-12-31

    Review of the safeguards of information technology, its current developments and status of safeguards in Member States are described concerning especially the role of domestic safeguards in cooperation with IAEA Safeguards. A Number of reports is dealing with declarations provided to the IAEA pursuant to Protocols Additional to Safeguard agreements. The Information Section of the IAEA Safeguards Information Technology Division is responsible for the data entry, loading and quality control od State supplied declarations. A software system is used to process information which should be readily accessible and usable in implementation of the strengthened safeguards system. Experiences in combating illegal trafficking of nuclear materials in a number of countries are included Refs, figs, 1 tab

  7. Combination Processes in Food Irradiation. Proceedings of an International Symposium on Combination Processes in Food Irradiation

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1981-09-15

    Processes in Food Irradiation was held by the IAEA and FAO at the Bandaranaike Memorial International Conference Hall in Colombo on 24-28 November 1980, and the present volume contains the proceedings. One of the most effective means demonstrated of increasing the efficacy of irradiation in the control of food spoilage is the combination of a low irradiation dose with a mild heat treatment. Promising results were reported for the shelf-life extension of mangoes and papayas, and the disinfestation of dried dates. Commercial application of the heat-irradiation treatment for some fruits is expected to follow soon. The Symposium covered other topics, such as the mechanisms of sensitization of microorganisms by physical and chemical agents, improvement of the microbiological quality of foods by combination processes, and the aspects of the wholesomeness and legislation of the food irradiation process. A key issue in the general discussion was the recommendation on the acceptability of food irradiated up to an overall average dose of 10 kGy. This important recommendation had been achieved at a recently convened Joint FAO/IAEA/WHO Expert Committee on the Wholesomeness of Irradiated Foods (27 October - 3 November 1980, Geneva). The breakthrough on the toxicological acceptability constitutes a firm basis for going ahead speedily with the development of practical applications of food irradiation, which should take its rightful place among other food preservation methods in helping to provide more and better food to a world in need. The sponsoring organizations hope that the publication of these proceedings will encourage further research and development of food irradiation to the benefit of mankind.

  8. Combination Processes in Food Irradiation. Proceedings of an International Symposium on Combination Processes in Food Irradiation

    International Nuclear Information System (INIS)

    1981-01-01

    Processes in Food Irradiation was held by the IAEA and FAO at the Bandaranaike Memorial International Conference Hall in Colombo on 24-28 November 1980, and the present volume contains the proceedings. One of the most effective means demonstrated of increasing the efficacy of irradiation in the control of food spoilage is the combination of a low irradiation dose with a mild heat treatment. Promising results were reported for the shelf-life extension of mangoes and papayas, and the disinfestation of dried dates. Commercial application of the heat-irradiation treatment for some fruits is expected to follow soon. The Symposium covered other topics, such as the mechanisms of sensitization of microorganisms by physical and chemical agents, improvement of the microbiological quality of foods by combination processes, and the aspects of the wholesomeness and legislation of the food irradiation process. A key issue in the general discussion was the recommendation on the acceptability of food irradiated up to an overall average dose of 10 kGy. This important recommendation had been achieved at a recently convened Joint FAO/IAEA/WHO Expert Committee on the Wholesomeness of Irradiated Foods (27 October — 3 November 1980, Geneva). The breakthrough on the toxicological acceptability constitutes a firm basis for going ahead speedily with the development of practical applications of food irradiation, which should take its rightful place among other food preservation methods in helping to provide more and better food to a world in need. The sponsoring organizations hope that the publication of these proceedings will encourage further research and development of food irradiation to the benefit of mankind

  9. THE MEASUREMENT AND EVALUATION OF THE INTERNAL COMMUNICATION PROCESS IN PROJECT MANAGEMENT

    Directory of Open Access Journals (Sweden)

    Pop Alexandra Mihaela

    2013-07-01

    The model is a useful tool for improving the internal communication process of a project and help the project raise its efficiency. It has been created based on the characteristics of the information flow within a project. Also the Internal Communication Analysis Model – ICAM – helps improve the projects‘ deliverables by making sure that everyone in the project understood their roles correctly.

  10. Peptide Drug Release Behavior from Biodegradable Temperature-Responsive Injectable Hydrogels Exhibiting Irreversible Gelation

    Directory of Open Access Journals (Sweden)

    Kazuyuki Takata

    2017-10-01

    Full Text Available We investigated the release behavior of glucagon-like peptide-1 (GLP-1 from a biodegradable injectable polymer (IP hydrogel. This hydrogel shows temperature-responsive irreversible gelation due to the covalent bond formation through a thiol-ene reaction. In vitro sustained release of GLP-1 from an irreversible IP formulation (F(P1/D+PA40 was observed compared with a reversible (physical gelation IP formulation (F(P1. Moreover, pharmaceutically active levels of GLP-1 were maintained in blood after subcutaneous injection of the irreversible IP formulation into rats. This system should be useful for the minimally invasive sustained drug release of peptide drugs and other water-soluble bioactive reagents.

  11. Effects of nano-scaled fish bone on the gelation properties of Alaska pollock surimi.

    Science.gov (United States)

    Yin, Tao; Park, Jae W

    2014-05-01

    Gelation properties of Alaska pollock surimi as affected by addition of nano-scaled fish bone (NFB) at different levels (0%, 0.1%, 0.25%, 0.5%, 1% and 2%) were investigated. Breaking force and penetration distance of surimi gels after setting increased significantly as NFB concentration increased up to 1%. The first peak temperature and value of storage modulus (G'), which is known to relate to the unfolding and aggregation of light meromyosin, increased as NFB concentration increased. In addition, 1% NFB treatment demonstrated the highest G' after gelation was completed. The activity of endogenous transglutaminase (TGase) in Alaska pollock surimi increased as NFB calcium concentration increased. The intensity of myosin heavy chain cross-links also increased as NFB concentration increased indicating the formation of more ε-(γ-glutamyl) lysine covalent bond by endogenous TGase and calcium ions from NFB. Copyright © 2013 Elsevier Ltd. All rights reserved.

  12. Enhanced gelation of chitosan/β-sodium glycerophosphate thermosensitive hydrogel with sodium bicarbonate and biocompatibility evaluated.

    Science.gov (United States)

    Deng, Aipeng; Kang, Xi; Zhang, Jing; Yang, Yang; Yang, Shulin

    2017-09-01

    The application of chitosan/β-sodium glycerophosphate (β-GP) thermosensitive hydrogel has been limited by the relatively slow gelation, weak mechanical resistance and poor cytocompatibility. In this study, sodium hydrogen carbonate (NaHCO 3 ) was applied with β-GP as gel agents to produce high-strength hydrogel. The hydrogels prepared with high NaHCO 3 concentration or more gel agents showed shorter gelation time, better thermostability, drastically enhanced resistance in compression. Meanwhile, the hydrogels presented obvious porous structures and excellent biocompatibility to HUVEC and NIH 3T3 cultured in vitro with higher NaHCO 3 concentration and moderate concentration of β-GP. Overall, appropriate concentration of β-GP combined with NaHCO 3 can be a good gel regent to improve properties of chitosan thermosensitive hydrogels. Copyright © 2017 Elsevier B.V. All rights reserved.

  13. Proceedings of the International Symposium on quantitative description of metal extraction processes

    International Nuclear Information System (INIS)

    Themelis, N.J.

    1991-01-01

    This book contains the proceedings of the H.H. Kellogg International Symposium. Topics include: Extractive metallurgy; Thermochemical phenomena in metallurgy; Thermodynamic modeling of metallurgical processes; and Transport and rate phenomena in metallurgical extraction

  14. Succeeding in process standardization: Explaining the fit with international management strategy

    DEFF Research Database (Denmark)

    Rahimi, Fatemeh; Møller, Charles; Hvam, Lars

    2016-01-01

    Purpose: The purpose of this paper is to explore the fit between process standardization and international management strategy of multinational corporations (MNCs) by assessing the compatibility between process standardization and corporate structural characteristics in terms of asset configuration...... and headquarters-subsidiary relationships. Design/methodology/approach: First, after a literature review on MNCs’ strategy and process standardization, the study suggests two propositions on the fit between corporate international management strategy and process standardization. Second, to empirically examine....../value: The study provides in-depth understanding of how the international management strategy and consequent structural characteristics of MNCs affects process standardization in the course of a global enterprise resource planning implementation. The study proposes conditions of fit for aligning process...

  15. Proceedings of the 5th International Workshop on Constraints and Language Processing (CSLP 2008)

    DEFF Research Database (Denmark)

    This research report constitutes the proceedings of the 5th International Workshop on Constraints and Language Processing (CSLP 2008) which is part of the European Summer School in Logic, Language, and Information (ESSLLI 2008), Hamburg, Germany, August 2008.......This research report constitutes the proceedings of the 5th International Workshop on Constraints and Language Processing (CSLP 2008) which is part of the European Summer School in Logic, Language, and Information (ESSLLI 2008), Hamburg, Germany, August 2008....

  16. PerPos: a Translucent Positioning Middleware Supporting Adaptation of Internal Positioning Processes

    DEFF Research Database (Denmark)

    Jensen, Jakob Langdal; Schougaard, Kari Rye; Kjærgaard, Mikkel Baun

    2010-01-01

    of application specific features that can be applied to the internal position processing of the middleware. To evaluate these capabilities we extend the internal position processing of the middleware with functionality supporting probabilistic position tracking and strategies for minimization of the energy......A positioning middleware benefits the development of location aware applications. Traditionally, positioning middleware provides position transparency in the sense that it hides low-level details. However, many applications require access to specific details of the usually hidden positioning...

  17. Permanganate gel (PG) for groundwater remediation: compatibility, gelation, and release characteristics.

    Science.gov (United States)

    Lee, Eung Seok; Olson, Pamela R; Gupta, Neha; Solpuker, Utku; Schwartz, Franklin W; Kim, Yongje

    2014-02-01

    Permanganate (MnO4(-)) is a strong oxidant that is widely used for treating chlorinated ethylenes in groundwater. This study aims to develop hyper-saline MnO4(-) solution (MnO4(-) gel; PG) that can be injected into aquifers via wells, slowly gelates over time, and slowly release MnO4(-) to flowing water. In this study, compatibility and miscibility of gels, such as chitosan, aluminosilicate, silicate, and colloidal silica gels, with MnO4(-) were tested. Of these gels, chitosan was reactive with MnO4(-). Aluminosilicates were compatible but not readily miscible with MnO4(-). Silicates and colloidal silica were both compatible and miscible with MnO4(-), and gelated with addition of KMnO4 granules. Colloidal silica has low initial viscosity (<15cP), exhibited delayed gelation characteristics with the lag times ranging from 0 to 200min. Release of MnO4(-) from the colloidal silica-based PG gel occurred in a delayed fashion, with maximum duration of 24h. These results suggested that colloidal silica can be used to create PG or delayed-gelling forms containing other oxidants which can be used for groundwater remediation. Copyright © 2013 Elsevier Ltd. All rights reserved.

  18. Factors influencing the gelation and rennetability of camel milk using camel chymosin

    DEFF Research Database (Denmark)

    Hailu, Yonas; Hansen, Egon Bech; Seifu, Eyassu

    2016-01-01

    The effects of temperature, pH, concentration of camel chymosin and addition of CaCl2 on the hydrolysis of κ-casein (κ-CN) and the coagulation kinetics of camel milk were investigated. The rate of κ-CN hydrolysis was higher at 40 °C than at 30 °C and with increasing addition of chymosin...... and decreasing pH. For all samples gelation was initiated at levels of camel milk κ-CN hydrolysis >95%. The gelation time (Tg) of camel milk was significantly reduced (from 717 to 526 s) at 30 °C when the concentration of chymosin was increased, but was independent of chymosin concentration at 40 °C. Reducing p......H also reduced Tg. The gel firmness increased at 40 °C (58 Pa) compared with 30 °C (44 Pa) and effect of CaCl2 addition on the gelation properties of camel milk was found to be dependent on pH; a significant improvement was only found at pH 6.3....

  19. Modeling and simulation of cement clinkering process with compact internal burning of carbon

    International Nuclear Information System (INIS)

    Chen, Hanmin

    2014-01-01

    This article describes a mathematical model of the thermodynamic process for Cement Clinkering Process with Compact Internal Burning of Carbon. Using simplifying assumptions, results of calculations are presented based on relevant computerized numerical simulation for a set of typical process parameters obtained from the existing cement shaft kiln operation and the electrical furnace test on the mechanical and chemical performance of the compact coal containing cement raw meal pellets. It is revealed that, the carbon internal burning mode, combining fuel combustion and gas solid heat transfer together as well as preheating, calcining, clinkering and cooling of the raw pellets together, is the origin of the process superiority in respect of equipment simplicity, process enhancement, high energy efficiency and low pollution. Important process details are determined, e.g. the features and lengths of the process zones, the material residence time and the burning mode of carbon in each zone, the clinkering reaction course and the maximum burning temperature. It is concluded that numerical simulations could be useful tool for understanding the new process ideas, as well as conducting the technical development and optimizing the process design. - Highlights: • Twin subsystem model is used to simulate a new type of cement shaft kiln process. • Grain-particle structural model is used to describe the pellet solid gas reactions. • The process superiority resulted from the carbon internal burning mode is revealed. • A series of important process details are determined. • An unprecedented comprehensive picture for cement clinkering process is depicted

  20. Internalization and cellular processing of cholecystokinin in rat pancreatic acinar cells

    International Nuclear Information System (INIS)

    Izzo, R.S.; Pellecchia, C.; Praissman, M.

    1988-01-01

    To evaluate the internalization of cholecystokinin, monoiodinated imidoester of cholecystokinin octapeptide [ 125 I-(IE)-CCK-8] was bound to dispersed pancreatic acinar cells, and surface-bound and internalized radioligand were differentiated by treating with an acidified glycine buffer. The amount of internalized radioligand was four- and sevenfold greater at 24 and 37 degree C than at 4 degree C between 5 and 60 min of association. Specific binding of radioligand to cell surface receptors was not significantly different at these temperatures. Chloroquine, a lysosomotropic agent that blocks intracellular proteolysis, significantly increased the amount of CCK-8 internalized by 18 and 16% at 30 and 60 min of binding, respectively, compared with control. Dithiothreitol (DTT), a sulfhydryl reducing agent, also augmented the amount of CCK-8 radioligand internalized by 25 and 29% at 30 and 60 min, respectively. The effect of chloroquine and DTT on the processing of internalized radioligand was also considered after an initial 60 min of binding of radioligand to acinar cells. After 180 min of processing, the amount of radioligand internalized was significantly greater in the presence of chloroquine compared with controls, whereas the amount of radioligand declined in acinar cells treated with DTT. Internalized and released radioactivity from acinar cells was rebound to pancreatic membrane homogenates to determine the amount of intact radioligand during intracellular processing. Chloroquine significantly increased the amount of intact 125 I-(IE)-CCK-8 radioligand in released and internalized radioactivity while DTT increased the amount of intact radioligand only in internalized samples. This study shows that pancreatic acinar cells rapidly internalize large amounts of CCK-8 and that chloroquine and DTT inhibit intracellular degradation

  1. Universal sol state behavior and gelation kinetics in mixed clay dispersions.

    Science.gov (United States)

    Pujala, Ravi Kumar; Pawar, Nisha; Bohidar, H B

    2011-05-03

    Sol and gel state behavior, in aqueous salt free dispersions, of clays Laponite (L) and Na montmorillonite (MMT) was studied at various mixing ratios (L:MMT = r = 1:0.5, 1:1, and 1:2). In the sol state, the zeta potential and gelation concentration of L-MMT obeyed the universal relation, X(L-MMT) = (rX(L) + X(MMT))/(1 + r), where X is zeta potential or gelation concentration (c(g)), implying that these properties are linear combinations of the same of their individual components. The low frequency storage modulus (G(0)'), relative viscosity (η(r)), and apparent cluster size (R) could be universally described by the power-law, G(0)' ∼ ((c/c(g)) - 1)(t) (c > c(g)), and η(r), R ∼ (1 - (c/c(g)))(-k,ν) (c < c(g)), with t = 1.5, k = 1.1, and υ = 0.8 close to the gelation concentration, for r = 1:1 cogel, consistent with the percolation model description of gelation. Interestingly, the hyperscaling relation δ = t/(k + t) yielded δ = 0.56 not too different from the predicted value ∼0.7, while the experimental value of δ obtained from G''(ω) ∼ ω(δ) close to c ≈ c(g) yielded δ = 1.5, which was at variance with the hyperscaling result. The experimental data, on hand, mostly supported percolation type gelation mechanism. As the cogels were slowly heated, at a characteristic temperature, T(g), a sharp increase in G' value was noticed, implying a transition to gel hardening (a new phase state). The temperature-dependent behavior followed the power-law description, G' ∼ (T(g) - T)(-γ) (T < T(g)), with γ = 0.40 ± 0.05 invariant of composition of the cogel, whereas for MMT and Laponite, γ = 0.25 and 0.55, respectively. It has been shown that the cogel has significantly enhanced mechanical (G(0) increased by 10 times for r = 1:1 cogel) and thermal properties (T(g) increased by 13 °C for 1:1 cogel) that can be exploited to design customized soft materials.

  2. Insights into gelation kinetics and gel front migration in cation-induced polysaccharide hydrogels by viscoelastic and turbidity measurements: Effect of the nature of divalent cations.

    Science.gov (United States)

    Huynh, Uyen T D; Chambin, Odile; du Poset, Aline Maire; Assifaoui, Ali

    2018-06-15

    Polysaccharide-based hydrogels were prepared by the diffusion of various divalent cations (X 2+ ) into the polygalacturonate (polyGal) solution through a dialysis membrane. The diffusion of various divalent cations (Mg 2+ , Ca 2+ , Zn 2+ and Ba 2+ ) was investigated. The polyGal gel growth was studied as a function of the initial cation concentration by both viscoelastic and turbidity measurements. We have demonstrated for the first time that the determination of the spatiotemporal variation of turbidity during the gelation process allowed to study the gel front migration. For Ca-polyGal, Zn-polyGal and Ba-polyGal, the gel front migration was characterized by the presence of a peak at the sol/gel interface. This peak was not observed in the case of Mg-polyGal where the gel was not formed. The apparent diffusion coefficient of the gel front (D app ) which was calculated from the evolution of this peak increased when the initial cation concentration was increased. Moreover, we have suggested a gelation mechanism based on the presence of a threshold molar ratio R* (=[X 2+ ]/[Galacturonic unit]) in which some point-like crosslinks are precursors of the formation of dimers and multimers inducing the contraction of the gel and thus the formation of the gel front. Copyright © 2018 Elsevier Ltd. All rights reserved.

  3. 3rd International Conference on Modelling and Management of Engineering Processes

    CERN Document Server

    Gericke, Kilian; Szélig, Nikoletta; Vajna, Sándor

    2015-01-01

    Innovative processes for the development of products and services are more and more considered as an organisational capability, which is recognised to be increasingly important for business success in today’s competitive environment. However, management and academia need a more profound understanding of these processes in order to develop improved management approaches to exploit business potentials. This book contains the proceedings of the 3rd International Conference on Modelling and Management of Engineering Processes (MMEP2013) held in Magdeburg, Germany, in November 2013. It includes contributions from international leading researchers in the fields of process modelling and process management. The conference topics were recent trends in modelling and management of engineering processes, potential synergies between different modelling approaches, future challenges for the management of engineering processes as well as future research in these areas.

  4. Ethnic Differences in Relations between Family Process and Child Internalizing Problems

    Science.gov (United States)

    Vendlinski, Matthew; Silk, Jennifer S.; Shaw, Daniel S.; Lane, Tonya J.

    2006-01-01

    Background: Family process variables have been linked to child problem behavior, but recent research suggests that child ethnicity may moderate relations between family process and child outcomes. The current study examined how ethnicity moderates relations between parent conflict, parent-child relationship quality, and internalizing problems.…

  5. Helping International Students Succeed Academically through Research Process and Plagiarism Workshops

    Science.gov (United States)

    Chen, Yu-Hui; Van Ullen, Mary K.

    2011-01-01

    Workshops on the research process and plagiarism were designed to meet the needs of international students at the University at Albany. The research process workshop covered formulating research questions, as well as locating and evaluating sources. The plagiarism workshop focused on acknowledging sources, quoting, paraphrasing, and summarizing…

  6. An Investigation of the Internal Structure of the Biggs Study Process Questionnaire.

    Science.gov (United States)

    Watkins, David; Hattie, John

    1980-01-01

    Results of an Australian study of the Biggs Study Process Questionnaire (SPQ) are presented. The purposes of the research were to: (1) re-examine the SPQ's internal consistency; (2) explore dimensionality of the SPQ scales; and (3) investigate validity of Bigg's model of the study process complex through factor analysis. (Author/GK)

  7. 2012 Proceedings of the International Conference on Communications, Signal Processing, and Systems

    CERN Document Server

    Wang, Wei; Mu, Jiasong; Liang, Jing; Zhang, Baoju; Pi, Yiming; Zhao, Chenglin

    2012-01-01

    Communications, Signal Processing, and Systems is a collection of contributions coming out of the International Conference on Communications, Signal Processing, and Systems (CSPS) held October 2012. This book provides the state-of-art developments of Communications, Signal Processing, and Systems, and their interactions in multidisciplinary fields, such as Smart Grid. The book also examines Radar Systems, Sensor Networks, Radar Signal Processing, Design and Implementation of Signal Processing Systems and Applications. Written by experts and students in the fields of Communications, Signal Processing, and Systems.

  8. Evaluation of polyacrylamide gels with accelerator ammonium salts for water shutoff in ultralow temperature reservoirs: Gelation performance and application recommendations

    Directory of Open Access Journals (Sweden)

    Hu Jia

    2016-03-01

    Full Text Available Water shutoff in ultralow temperature reservoirs has received great attention in recent years. In previous study, we reported a phenol-formaldehyde-based gel formula with ammonium salt which can provide a gelation time between 2 hrs and 2 days at 25 °C. However, systematic evaluation and field recommendations of this gel formula when encountering complex reservoirs environment are not addressed. In this paper, how and why such practical considerations as water composition, temperature, pH, weight ratio of formaldehyde to resorcinol and contaminant Fe3+ to affect the gelation performance are examined. Brookfield DV-III and scanning electron microscopy (SEM are employed respectively for viscosity measurement and microstructure analysis. SEM results further illustrate the mechanism of the effect of salinity on gelation performance. It reveals that crosslinking done by covalent bond has great advantage for gel stability under high salinity environment. The target gel formula can provide desirable gelation time below 60 °C, perfect for 15–45 °C, while it is unfeasible to use high salinity to delay gelation at 60 °C. We summarized the effect of salinity on gelation performance of different gel formulas from the present study and published literature. The summarized data can provide important guideline for gel formula design before conducting any kinds of experiments. The variation of gelation performance at different salinity may be dominated by the interaction between crosslinker-salt-polymer, not only limited to “charge-screening effect” and “ion association” proposed by several authors. We hope the analysis encouraging further investigations. Some recommendations for field application of this gel are given in the end of this paper.

  9. A novel method for the production of core-shell microparticles by inverse gelation optimized with artificial intelligent tools.

    Science.gov (United States)

    Rodríguez-Dorado, Rosalia; Landín, Mariana; Altai, Ayça; Russo, Paola; Aquino, Rita P; Del Gaudio, Pasquale

    2018-03-01

    Numerous studies have been focused on hydrophobic compounds encapsulation as oils. In fact, oils can provide numerous health benefits as synergic ingredient combined with other hydrophobic active ingredients. However, stable microparticles for pharmaceutical purposes are difficult to achieve when commonly techniques are used. In this work, sunflower oil was encapsulated in calcium-alginate capsules by prilling technique in co-axial configuration. Core-shell beads were produced by inverse gelation directly at the nozzle using a w/o emulsion containing aqueous calcium chloride solution in sunflower oil pumped through the inner nozzle while an aqueous alginate solution, coming out from the annular nozzle, produced the beads shell. To optimize process parameters artificial intelligence tools were proposed to optimize the numerous prilling process variables. Homogeneous and spherical microcapsules with narrow size distribution and a thin alginate shell were obtained when the parameters as w/o constituents, polymer concentrations, flow rates and frequency of vibration were optimized by two commercial software, FormRules® and INForm®, which implement neurofuzzy logic and Artificial Neural Networks together with genetic algorithms, respectively. This technique constitutes an innovative approach for hydrophobic compounds microencapsulation. Copyright © 2018 Elsevier B.V. All rights reserved.

  10. The Making of discussion groups in a combined process of internal evaluation of safety culture

    International Nuclear Information System (INIS)

    German, S.; Buedo, J. L.; La Salabarnada, E.; Navajas, J.; Silla, I.

    2012-01-01

    The purpose of this paper is to show the design and evaluation of safety culture conducted in the Cofrentes nuclear plant. The process has combined the use of different methodologies and techniques and has allowed the participation of different internal and external stake holders. For internal assessment discussion groups were conducted. These groups, which were designed and analyzed by the CIEMAT, were led by employees from different levels of Cofrentes.

  11. Quasilinear Extreme Learning Machine Model Based Internal Model Control for Nonlinear Process

    Directory of Open Access Journals (Sweden)

    Dazi Li

    2015-01-01

    Full Text Available A new strategy for internal model control (IMC is proposed using a regression algorithm of quasilinear model with extreme learning machine (QL-ELM. Aimed at the chemical process with nonlinearity, the learning process of the internal model and inverse model is derived. The proposed QL-ELM is constructed as a linear ARX model with a complicated nonlinear coefficient. It shows some good approximation ability and fast convergence. The complicated coefficients are separated into two parts. The linear part is determined by recursive least square (RLS, while the nonlinear part is identified through extreme learning machine. The parameters of linear part and the output weights of ELM are estimated iteratively. The proposed internal model control is applied to CSTR process. The effectiveness and accuracy of the proposed method are extensively verified through numerical results.

  12. Discrimination against international medical graduates in the United States residency program selection process.

    Science.gov (United States)

    Desbiens, Norman A; Vidaillet, Humberto J

    2010-01-25

    Available evidence suggests that international medical graduates have improved the availability of U.S. health care while maintaining academic standards. We wondered whether studies had been conducted to address how international graduates were treated in the post-graduate selection process compared to U.S. graduates. We conducted a Medline search for research on the selection process. Two studies provide strong evidence that psychiatry and family practice programs respond to identical requests for applications at least 80% more often for U.S. medical graduates than for international graduates. In a third study, a survey of surgical program directors, over 70% perceived that there was discrimination against international graduates in the selection process. There is sufficient evidence to support action against discrimination in the selection process. Medical organizations should publish explicit proscriptions of discrimination against international medical graduates (as the American Psychiatric Association has done) and promote them in diversity statements. They should develop uniform and transparent policies for program directors to use to select applicants that minimize the possibility of non-academic discrimination, and the accreditation organization should monitor whether it is occurring. Whether there should be protectionism for U.S. graduates or whether post-graduate medical education should be an unfettered meritocracy needs to be openly discussed by medicine and society.

  13. Influence of pre-cooking protein paste gelation conditions and post-cooking gel storage conditions on gel texture.

    Science.gov (United States)

    Paker, Ilgin; Matak, Kristen E

    2016-01-15

    Gelation conditions affect the setting of myofibrillar fish protein gels. Therefore the impact of widely applied pre-cooking gelation time/temperature strategies and post-cooking period on the texture and color of final protein gels was determined. Four pre-cooking gelation strategies (no setting time, 30 min at 25 °C, 1 h at 40 °C or 24 h at 4 °C) were applied to protein pastes (fish protein concentrate and standard functional additives). After cooking, texture and color were analyzed either directly or after 24 h at 4 °C on gels adjusted to 25 °C. No-set gels were harder, gummier and chewier (P cooking. Gel-setting conditions had a greater (P cooking stored gels in texture and color, depending on the pre-cooking gelation strategy. Pre-cooking gelation conditions will affect final protein gel texture and color, with gel stability benefiting from a gel-setting period. However, post-cooking storage may have a greater impact on final gels, with textural attributes becoming more consistent between all samples. © 2015 Society of Chemical Industry.

  14. Technical benefit and risk analysis on cement clinkering process with compact internal burning of carbon

    International Nuclear Information System (INIS)

    Chen, Hanmin

    2015-01-01

    This article demonstrates the potential technical benefit and risk for cement clinkering process with compact internal burning of carbon, a laboratory-phase developing technique, from 9 aspects, including the heat consumption of clinkering and exhaust heat utilization, clinker quality, adaptability to alternative fuels, the disposal ability of industrial offal and civil garbage, adaptability to the raw materials and fuels with high content of chlorine, sulphur and alkali, the feasibility of process scale up, the briquetting process of the coal-containing cement raw meal pellet, NO x emission and the capital cost and benefit of conversion project. It is concluded that it will be able to replace the modern precalciner rotary kiln process and to become the main stream technique of cement clinkering process in low carbon economy times. - Highlights: • Compact internal burning of carbon enables cement shaft kiln to run stably. • Compact internal burning of carbon enables cement shaft kiln to scale up. • New process triples energy efficiency with excellent environmental performance. • It will be able to compete with and replace the existing precalciner kiln process. • It will become the mainstream clinkering process in low carbon economy

  15. Internationally Standardized Reporting (Checklist) on the Sustainable Development Performance of Uranium Mining and Processing Sites

    International Nuclear Information System (INIS)

    Harris, Frank

    2014-01-01

    The Internationally Standardized Reporting Checklist on the Sustainable Development Performance of Uranium Mining and Processing Sites: • A mutual and beneficial work between a core group of uranium miners and nuclear utilities; • An approach based on an long term experience, international policies and sustainable development principles; • A process to optimize the reporting mechanism, tools and efforts; • 11 sections focused on the main sustainable development subject matters known at an operational and headquarter level. The WNA will make available the sustainable development checklist for member utilities and uranium suppliers. Utilities and suppliers are encouraged to use the checklist for sustainable development verification.

  16. Transient internal characteristic study of a centrifugal pump during startup process

    International Nuclear Information System (INIS)

    Hu, F F; Ma, X D; Wu, D Z; Wang, L Q

    2012-01-01

    The transient process of a centrifugal pump existed in a variety of occasions. There were a lot of researches in the external characteristic in startup process and stopping process, but internal characteristics were less observed and studied. Study of the internal flow field had significant meanings. The performance of a pump could be evaluated and improved by revealing the flow field. In the other hand, the prediction of external characteristic was based on the correct analysis of the internal flow. In this paper, theoretical method and numerical simulation were used to study the internal characteristic of a centrifugal pump. The theoretical study showed that the relative flow in an impeller was composed of homogeneous flow and axial vortex flow. The vortex intensity was mainly determined by angular velocity of impeller, flow channel width and blade curvature. In order to get the internal flow field and observe the evolution of transient internal flow in the impeller, Computational Fluid Dynamics(CFD) were used to study the three-dimensional unsteady incompressible viscous flows in a centrifugal pump during starting period. The Dynamic Mesh (DM) method with non-conformal grid boundaries was applied to get the external characteristic and internal flow field. The simulate model included three pumps with different blade numbers and the same blade curvature. The relative velocity vector showed that there was a big axial vortex in impeller channel. At the beginning, the vortex was raised in the pressure side of the impeller outlet and with time went on, it shifted to the middle flow channel of the impeller and the vortex intensity increased. When the speed and flow rate reached a definite value, the influence of the axial vortex began to get smaller. The vortex developed faster when the flow channel got narrower. Due to the evolution of axial vortex, the slip factor during starting period was smaller than that in quasi-steady condition. As a result, transient head was

  17. Effect of protease inhibitors on thermal gelation of squid (Illex argentinus. mantle paste

    Directory of Open Access Journals (Sweden)

    Maria Elida Paredi

    2014-04-01

    Full Text Available The characteristics of the thermal gelation of squid mantle paste and the effect of protease inhibitors on them were investigated. Pastes in the absence and presence the protease inhibitors, ethylendiaminetetracetic acid (EDTA and phenylmethylsulfonyl fluoride (PMSF, were formulated. Pastes were made by the respective one or two step thermal treatments: direct heating at 85°C for 20 min and preincubation at 27 or 40 °C for 3 or 2 hours, followed by heating at 85 °C for 20 min. The gel strength, water holding capacity (WHC and whiteness of gelled pastes were analyzed. The tricloroacetic acid (TCA soluble peptides in homogenate of the muscle were determined. Gel strength decreased when heating was made in two steps. EDTA and PMSF were effective in avoiding that decrease when pre-incubation was made at 40 °C. Maximum gel strength was observed for the gels in presence of EDTA, giving values of 255 and 219 g x cm for the samples made by direct heating and pre-incubated at 40 °C  respectively. TCA soluble peptides increased between 20 and 60 °C, with maximum values reached at 30 and 60 °C. No significant differences (p>0.05 were observed in gel whiteness, neither with the thermal treatment nor with the inhibitors. The WHC was higher (p<0.05 in the gelated paste formulated with EDTA. These results show a good gelation capacity of I argentinus pastes and improvements with protease inhibitors. 

  18. Developing and enforcing internal information systems standards: InduMaker’s Standards Management Process

    Directory of Open Access Journals (Sweden)

    Claudia Loebbecke

    2016-01-01

    Full Text Available It is widely agreed that standards provide numerous benefits when available and enforced. Company-internal Information Systems (IS management procedures and solutions, in the following coined IS ‘standards’, allow for harmonizing operations between company units, locations and even different service providers. However, many companies lack an organized process for defining and managing internal IS standards, which causes uncertainties and delays in decision making, planning, and design processes. In this case study of the globally operating InduMaker (anonymized company name, an established manufacturing supplier, we look into the company-internal management of IS standards. Theoretically grounded in the organizational and IS-focused literature on business process modelling and business process commoditization, we describe and investigate InduMaker’s newly developed Standard Management Process (SMP for defining and managing company-internal business and IS standards, with which the multinational pursues offering clear answers to business and IT departments about existing IS standards, their degree of obligation, applicability, and scope at any time.

  19. Synthesis and characterization of sugar based low molecular weight gelators and the preparation of chiral sulfinamides

    Science.gov (United States)

    Mangunuru, Hari Prasad Reddy

    Low molecular weight gelators (LMWGs) have received considerable attention in the field of chemistry from last few decades. These compounds form self-assembled fibrous networks like micelles, cylindrical, sheets, fibers, layers and so on. The fibrous network entraps the solvent and forms gel, because of the self-assembly phenomenon and their demonstrated potential uses in a variety of areas, ranging from environmental to medicinal applications. Sugars are good starting materials to synthesize the new class of LMWG's, because these are different from some expensive materials, these are natural products. We have synthesized and characterized the LMGS's based on D-glucose and D-glucosamine. D-glucosamine is the versatile starting material to make different peptoids and triazoles. Several series of compounds were synthesized using compounds 1-3 as starting material and studied the gelation behavior all the compounds. We have studied the self-assembling properties of a new class of tripeptoids, synthesized by one-pot Ugi reaction from simple starting materials. Among the focused library of tripeptoids synthesized, we found that several efficient low molecular weight organogelators were obtained for aqueous DMSO and ethanol mixtures. We have also synthesized and characterized a series of monosaccharide triazole derivatives. These compounds were synthesized from N-acetyl glucosamine and D-glucose via a Cu(I) catalyzed azide/alkyne cycloaddition reaction (CuAAc). The compounds have been screened for their gelation properties and several efficient low molecular weight organo/hydro gelators were obtained, among these compounds, five per-acetyl glucosamine derivatives and one peracetyl glucose derivative were able to form gels in water. These new molecules are expected to be useful in drug delivery and tissue engineering.*. Asymmetric synthesis of chiral amines is a challenging in synthetic organic chemistry. The development of new catalysts for asymmetric organic

  20. Pinning of phase separation of aqueous solution of hydroxypropylmethylcellulose by gelation

    Science.gov (United States)

    Kita, Rio; Kaku, Takeshi; Kubota, Kenji; Dobashi, Toshiaki

    1999-08-01

    Opalescence of the aqueous solution of hydroxypropylmethylcellulose (HPMC) induced by heating has been studied in terms of the phase diagram and the phase separation dynamics. The cloud point curve and the sol-to-gel transition curve intersected with each other at about 55 °C. Just above the cloud-point curve at which the spinodal curve has its minimum, a ring-like scattering pattern appeared corresponding to the spinodal decomposition. Temporal growth of the scattering function in the course of phase separation was studied by a time-resolved light scattering technique. The gelation pinned the phase separation (spinodal decomposition) of the aqueous HPMC solution.

  1. Rheological and gelation properties of rice starch modified with 4-alpha-glucanotransferase.

    Science.gov (United States)

    Lee, Kwang Yeon; Kim, Yong-Ro; Park, Kwan Hwa; Lee, Hyeon Gyu

    2008-04-01

    Rheological measurements were performed to characterize rice starch modified with 4-alpha-glucanotransferase (4alphaGTase) isolated from Thermus scotoductus, in terms of effects of the enzyme and starch concentration on flow behavior, gel strength, and melting and gelling kinetics of the modified rice starch. Consistency index decreased and flow behavior index increased with the level of enzyme treatment, and at high level of enzyme treatment, it demonstrated Bingham plastic behavior. As the level of enzyme decreased and the starch concentration increased, gelation time decreased and the final gel strength increased significantly. Regardless of treatment variables, all the modified starch gels melted at similar temperature.

  2. Generalized role for the cerebellum in encoding internal models: evidence from semantic processing.

    Science.gov (United States)

    Moberget, Torgeir; Gullesen, Eva Hilland; Andersson, Stein; Ivry, Richard B; Endestad, Tor

    2014-02-19

    The striking homogeneity of cerebellar microanatomy is strongly suggestive of a corresponding uniformity of function. Consequently, theoretical models of the cerebellum's role in motor control should offer important clues regarding cerebellar contributions to cognition. One such influential theory holds that the cerebellum encodes internal models, neural representations of the context-specific dynamic properties of an object, to facilitate predictive control when manipulating the object. The present study examined whether this theoretical construct can shed light on the contribution of the cerebellum to language processing. We reasoned that the cerebellum might perform a similar coordinative function when the context provided by the initial part of a sentence can be highly predictive of the end of the sentence. Using functional MRI in humans we tested two predictions derived from this hypothesis, building on previous neuroimaging studies of internal models in motor control. First, focal cerebellar activation-reflecting the operation of acquired internal models-should be enhanced when the linguistic context leads terminal words to be predictable. Second, more widespread activation should be observed when such predictions are violated, reflecting the processing of error signals that can be used to update internal models. Both predictions were confirmed, with predictability and prediction violations associated with increased blood oxygenation level-dependent signal in the posterior cerebellum (Crus I/II). Our results provide further evidence for cerebellar involvement in predictive language processing and suggest that the notion of cerebellar internal models may be extended to the language domain.

  3. 2nd International Symposium on Signal Processing and Intelligent Recognition Systems

    CERN Document Server

    Bandyopadhyay, Sanghamitra; Krishnan, Sri; Li, Kuan-Ching; Mosin, Sergey; Ma, Maode

    2016-01-01

    This Edited Volume contains a selection of refereed and revised papers originally presented at the second International Symposium on Signal Processing and Intelligent Recognition Systems (SIRS-2015), December 16-19, 2015, Trivandrum, India. The program committee received 175 submissions. Each paper was peer reviewed by at least three or more independent referees of the program committee and the 59 papers were finally selected. The papers offer stimulating insights into biometrics, digital watermarking, recognition systems, image and video processing, signal and speech processing, pattern recognition, machine learning and knowledge-based systems. The book is directed to the researchers and scientists engaged in various field of signal processing and related areas. .

  4. Fundamental limitations of non-thermal plasma processing for internal combustion engine NOx control

    International Nuclear Information System (INIS)

    Penetrante, B.M.

    1993-01-01

    This paper discusses the physics and chemistry of non-thermal plasma processing for post-combustion NO x control in internal combustion engines. A comparison of electron beam and electrical discharge processing is made regarding their power consumption, radical production, NO x removal mechanisms, and by product formation. Can non-thermal deNO x operate efficiently without additives or catalysts? How much electrical power does it cost to operate? What are the by-products of the process? This paper addresses these fundamental issues based on an analysis of the electron-molecule processes and chemical kinetics

  5. Development of international labor migration in the dynamics of globalization processes

    Directory of Open Access Journals (Sweden)

    Rubinskaya Eteri, D.

    2015-03-01

    Full Text Available The current characteristics of international migration caused by the qualitative changes that occur in the global economy under influence of increasing globalization. The paper attempts to suggest periodization of the global economy development and to identify features of international labor migration occurred under the influence of deep changes in the world economy. During this period, the author identifies three stages in the formation of globalization, the transition criterion from one to other is the degree of world economy changes under the influence of the productive forces development and the major social and political transformations resulted in qualitative changes in the processes of international labor migration. At the same time in the context of globalization the place and role of international labor migration changes in the global economy system: migration becomes a means of promoting the globalization of countries and regions, the most important factor of demographic development and economic growth.

  6. Board members’ contribution to strategy: The mediating role of board internal processes

    Directory of Open Access Journals (Sweden)

    Carmen Barroso-Castro

    2017-05-01

    Full Text Available This study aims to explore what directors do on the board, to what extent the processes occurring in the board allow the sharing and integrating of the existing knowledge, thus facilitating the board members’ contributions to strategy. We adopt the view that the internal board processes increase the impact of the cognitive resources on board performance. Using survey data from 200 large Spanish companies we demonstrate that directors’ level of knowledge of the firm and board job-related diversity positively influence the degree of the board's strategic involvement. Additionally, the internal processes that take place within the board – particularly Cognitive Conflict, the Critical and Independent Approach and the Comprehensive Discussion Process – influence the board's strategic involvement and play a partial mediating role on the aforementioned relationships. However, our results show no evidence for a positive relationship between Board Meeting Dynamics and the board's strategic involvement.

  7. Preparation of ThO2 sols suitable for gelation into microspheres in CCl4-ammonia media

    International Nuclear Information System (INIS)

    Yamagishi, Shigeru; Takahashi, Yoshihisa

    1985-01-01

    Production conditions of ThO 2 sols are studied for satisfactorily gelling them into microspheres in CCl 4 -ammonia media, which result gel-spheres with good sphericities but need high-quality source-sols for crackfree gelation. Two-stage pH-setting techniques were added to the previously reported method, which had been developed to produce ThO 2 sols suitable for gelation in hexone-ammonia media and was characterized by preneutralization followed by neutralization under pH-control. As a result, colloid fractions of Th in sols were increased without decreasing colloid size. This enabled one to obtain crackfree, large, spherical ThO 2 particles by gelation in the CCl 4 -ammonia media. (author)

  8. Solubilization of bovine gelatin using power ultrasound: gelation without heating.

    Science.gov (United States)

    Farahnaky, Asgar; Zendeboodi, Fatemeh; Azizi, Rezvan; Mesbahi, Gholamreza; Majzoobi, Mahsa

    2017-04-01

    The aim of this study was to investigate the efficacy of power ultrasound without using any heating stage in solubilizeing gelatin dispersions, and to characterize the mechanical and microstructural properties of the resulting gels using texture analysis and scanning electron microscopy, respectively. Usually to prepare a gel from gelatin, a primary heating stage of at about 40C or above is required to solubilize gelatin macromolecules. In this study solubilizing gelatin dispersions using power ultrasound without any heating was successfully performed. For solubilising gelatin, an ultrasound equipment with a frequency of 20 kHz, amplitude of 100% and power range of 50-150 W was used. Aqueous gelatin dispersions (4% w/v) were subjected to ultrasound for different times (40-240 s) at a constant temperature of 13C. Applying ultrasound to gelatin dispersions caused increases in water absorption and water solubility of the hydrocolloid. The textural parameters of the resulting gelatin gels, increased with increasing time and power of ultrasound. Moreover, a generalized Maxwell model with three elements was used for calculating relaxation times of the gels. The microstructural observations by SEM showed that the structural cohesiveness of the gels increased by increasing ultrasonication time. Ultrasound-assisted solubilization of gelatin can have emerging implications for industrial uses in pharmaceuticals, food and non-food systems. Usually to prepare a gel from gelatin, a primary heating stage of at about 40C or above is required to solubilize gelatin macromolecules. Therefore, the use of gelatin as a hydrocolloid in food processings or pharmaceutical formulations which lack a heating step has been a technological and practical challenge. In this study solubilizing gelatin dispersions using power ultrasound without any heating was successfully performed. Ultrasound-assisted solubilisation of gelatin can have emerging implications for industrial uses in pharmaceuticals

  9. Styles of International Mediation in Peace Processes Between States and Terrorist Organizations

    Science.gov (United States)

    2016-06-01

    NAVAL POSTGRADUATE SCHOOL MONTEREY, CALIFORNIA THESIS Approved for public release; distribution is unlimited STYLES OF...Office of Management and Budget, Paperwork Reduction Project (0704-0188) Washington, DC 20503. 1. AGENCY USE ONLY (Leave blank) 2. REPORT DATE...June 2016 3. REPORT TYPE AND DATES COVERED Master’s thesis 4. TITLE AND SUBTITLE STYLES OF INTERNATIONAL MEDIATION IN PEACE PROCESSES BETWEEN

  10. Managing organizational change in an international scientific network: A study of ICES reform processes

    NARCIS (Netherlands)

    Stange, K.; Olssen, P.; Österblom, H.

    2012-01-01

    Organizations involved in the governance of natural resources are challenged to adjust to the call for more holistic management approaches. This often necessitates organizational change. Here change processes in the International Council for the Exploration of the Sea (ICES) during the years

  11. ECO LOGIC INTERNATIONAL GAS-PHASE CHEMICAL REDUCTION PROCESS - THE REACTOR SYSTEM - APPLICATIONS ANALYSIS REPORT

    Science.gov (United States)

    The ELI Eco Logic International Inc. (Eco Logic) process thermally separates organics, then chemically reduces them in a hydrogen atmosphere, converting them to a reformed gas that consists of light hydrocarbons and water. A scrubber treats the reformed gas to remove hydrogen chl...

  12. ECO LOGIC INTERNATIONAL GAS-PHASE CHEMICAL REDUCTION PROCESS - THE THERMAL DESORPTION UNIT - APPLICATIONS ANALYSIS REPORT

    Science.gov (United States)

    ELI ECO Logic International, Inc.'s Thermal Desorption Unit (TDU) is specifically designed for use with Eco Logic's Gas Phase Chemical Reduction Process. The technology uses an externally heated bath of molten tin in a hydrogen atmosphere to desorb hazardous organic compounds fro...

  13. Strengthening Internal Quality Assurance Processes: Facilitating Student Evaluation Committees to Contribute

    Science.gov (United States)

    Stalmeijer, Renée; Whittingham, Jill; de Grave, Willem; Dolmans, Diana

    2016-01-01

    Student evaluation committees play a crucial role in internal quality assurance processes as representatives of the student body. However, the students on these committees sometimes experience difficulty in providing constructive and structured feedback to faculty in an environment characterised by a strong power differential between student and…

  14. Reducing Post-Decision Dissonance in International Decisions: The Analytic Hierarchy Process Approach.

    Science.gov (United States)

    DuBois, Frank L.

    1999-01-01

    Describes use of the analytic hierarchy process (AHP) as a teaching tool to illustrate the complexities of decision making in an international environment. The AHP approach uses managerial input to develop pairwise comparisons of relevant decision criteria to efficiently generate an appropriate solution. (DB)

  15. Non-traditional Process of Hydrogen Containing Fuel Mixtures Production for Internal-combustion Engines

    Directory of Open Access Journals (Sweden)

    Gennady G. Kuvshinov

    2012-12-01

    Full Text Available The article justifies the perspectives of development of the environmentally sound technology of hydrogen containing fuel mixtures for internal-combustion engines based on the catalytic process of low-temperature decomposition of hydrocarbons into hydrogen and nanofibrous carbon.

  16. Researching International Processes of Education Policy Formation: Conceptual and Methodological Considerations

    Science.gov (United States)

    Edwards, D. Brent, Jr.

    2012-01-01

    This article elaborates one approach to conceptualizing and investigating international processes of education policy formation (IPEPF), which are dynamic, multi-level and processual in nature. This contribution is important because, although research is increasingly conducted on phenomena with such characteristics, extended discussions of how…

  17. The doctrinal illusion of heterogeneity of international law-making processes

    NARCIS (Netherlands)

    d' Aspremont, J.; Ruiz Fabri, H.; Wofrum, R.; Gogolin, J.

    2010-01-01

    Contemporary practice shows that the image of international lawmaking as a diverse and heterogeneous process, understood in terms of the multiplicity of the actors involved, is mostly an illusion. Despite strong empirical evidence, many scholars have been lured by this idea or have tried to promote

  18. Supporting the Thesis Writing Process of International Research Students through an Ongoing Writing Group

    Science.gov (United States)

    Li, Linda Y.; Vandermensbrugghe, Joelle

    2011-01-01

    Evidence from research suggests writing support is particularly needed for international research students who have to tackle the challenges of thesis writing in English as their second language in Western academic settings. This article reports the development of an ongoing writing group to support the thesis writing process of international…

  19. Combination of high-performance refractometry and infrared spectroscopy as a probe for chemically induced gelation and vitrification of epoxies

    International Nuclear Information System (INIS)

    Mueller, U; Philipp, M; Gervais, P-C; Sanctuary, R; Krueger, J K; Possart, W; Wehlack, C; Kieffer, J

    2010-01-01

    A combination of infrared spectroscopy and high-performance refractometry was used to investigate the chemically induced sol-gel and glass transition during the polymerization of epoxies. Representations of the refractive index versus chemical conversion reveal an interesting insight into the optical properties accompanying gelation and vitrification. Whereas the electronic polarizability of the liquid state of small average molecular mass and the glassy state is dominated by the mass density, an unexpected excess polarizability observed during the gelation is attributed to cooperative dipole-dipole interactions.

  20. Combination of high-performance refractometry and infrared spectroscopy as a probe for chemically induced gelation and vitrification of epoxies

    Energy Technology Data Exchange (ETDEWEB)

    Mueller, U; Philipp, M; Gervais, P-C; Sanctuary, R; Krueger, J K [Laboratoire de Physique des Materiaux, Universite du Luxembourg, 162A avenue de la faiencerie, L-1511 Luxembourg (Luxembourg); Possart, W; Wehlack, C [Fachbereich Werkstoffwissenschaften, Universitaet des Saarlandes, D-66123 Saarbruecken (Germany); Kieffer, J, E-mail: ulrich.mueller@uni.l [Department of Materials Science and Engineering, University of Michigan, Ann Arbor, MI (United States)

    2010-08-15

    A combination of infrared spectroscopy and high-performance refractometry was used to investigate the chemically induced sol-gel and glass transition during the polymerization of epoxies. Representations of the refractive index versus chemical conversion reveal an interesting insight into the optical properties accompanying gelation and vitrification. Whereas the electronic polarizability of the liquid state of small average molecular mass and the glassy state is dominated by the mass density, an unexpected excess polarizability observed during the gelation is attributed to cooperative dipole-dipole interactions.

  1. Influence of gamma-irradiation on thermally-induced mesoscopic gelation of degalactosylated xyloglucans

    International Nuclear Information System (INIS)

    Todaro, S.; Sabatino, M.A.; Walo, M.; Mangione, M.R.; Bulone, D.; Dispenza, C.

    2014-01-01

    Thermoresponsive degalactosylated xyloglucans have been already proposed as in situ gelling scaffolds for tissue engineering, due to their reversible macroscopic thermal gelation at body temperature and biodegradability. The highly branched, hydroxyl group-rich molecular structure renders xyloglucans interesting raw materials also in the form of micro/nanoparticles for application as nanoscalar drug delivery devices in cosmetic and pharmaceutical formulations. Owing to their natural source, xyloglucans show high average molecular weight, broad molecular weight distribution and poor water solubility, as large and compact aggregates usually form via inter-molecular hydrogen bonding. 60 Co γ-irradiation has been here applied to reduce the molecular weight. The aqueous solutions of irradiated xyloglucan were characterized by dynamic light scattering measurements and gel filtration chromatography. The aggregation kinetics at 37 °C were studied by dynamic light scattering measurements to confirm the temperature-responsive behavior of this polymer even when dispersed in water at low concentration after γ-irradiation. Irradiation dose–molecular properties relationship has been sought. - Highlights: • Influence of γ-irradiation on a partially degalactosylated xyloglucan is investigated. • Molecular weight reduction is observed in the investigated dose range. • Modification of the temperature-induced mesoscopic gelation kinetics is evidenced

  2. The impact of the improvement in internal medicine consultation process on ED length of stay.

    Science.gov (United States)

    Shin, Sangheon; Lee, Soo Hoon; Kim, Dong Hoon; Kim, Seong Chun; Kim, Tae Yun; Kang, Changwoo; Jeong, Jin Hee; Lim, Daesung; Park, Yong Joo; Lee, Sang Bong

    2018-04-01

    Although consultations are essential for delivering safe, high-quality care to patients in emergency departments, they contribute to emergency department patient flow problems and overcrowding which is associated with several adverse outcomes, such as increases in patient mortality and poor quality care. This study aimed to investigate how time flow metrics including emergency department length of stay is influenced by changes to the internal medicine consultation policy. This study is a pre- and post-controlled interventional study. We attempted to improve the internal medicine consultation process to be more concise. After the intervention, only attending emergency physicians consult internal medicine chief residents, clinical fellows, or junior staff of each internal medicine subspecialty who were on duty when patients required special care or an admission to internal medicine. Emergency department length of stay of patients admitted to the department of internal medicine prior to and after the intervention decreased from 996.94min to 706.62min. The times from consultation order to admission order and admission order to emergency department departure prior to and after the intervention were decreased from 359.59min to 180.38min and from 481.89min to 362.37min, respectively. The inpatient mortality rates and Inpatient bed occupancy rates prior to and after the intervention were similar. The improvements in the internal medicine consultation process affected the flow time metrics. Therefore, more comprehensive and cooperative strategies need to be developed to reduce the time cycle metrics and overcrowding of all patients in the emergency department. Copyright © 2017 Elsevier Inc. All rights reserved.

  3. Entrepreneurial Orientation and Business Internationalisation Process: The Theoretical Foundations of International Entrepreneurship

    Directory of Open Access Journals (Sweden)

    Krzysztof Wach

    2015-06-01

    Full Text Available The main goal of the article is to discuss and elaborate on the basics of international entrepreneurial orientation (IEO, its fundamentals and principles. The paper reviews these three important terms by trying to link them and suggests a holistic framework. The article is of descriptive character, thus it is based on literature review and its constructive critics. The article is an attempted synthesis of the concept of international entrepreneurial orientation. It focuses on IEO as the implementation of one of the most important research theme in the theory of entrepreneurship, which is entrepreneurial orientation (EO into the studies of international entrepreneurship (IE. Findings: Firstly, international entrepreneurial process was discussed from the international entrepreneurship perspective. Secondly, the paper introduces the conceptualisation of entrepreneurial orientation from both three- and multidimensional perspectives. Thirdly, IEO is conceptualised and operationalised from the perspective of entrepreneurial internationalisation of firms. Implications & Recommendations: IEO is a multi-dimensional concept. IEO can be considered both an individual and firm-level construct. IEO enables business to identify and exploit internationalisation opportunities. IEO reflects the firms overall proactiveness and aggressiveness in its pursuit of international markets.

  4. 12th International Conference on Intelligent Information Hiding and Multimedia Signal Processing

    CERN Document Server

    Tsai, Pei-Wei; Huang, Hsiang-Cheh

    2017-01-01

    This volume of Smart Innovation, Systems and Technologies contains accepted papers presented in IIH-MSP-2016, the 12th International Conference on Intelligent Information Hiding and Multimedia Signal Processing. The conference this year was technically co-sponsored by Tainan Chapter of IEEE Signal Processing Society, Fujian University of Technology, Chaoyang University of Technology, Taiwan Association for Web Intelligence Consortium, Fujian Provincial Key Laboratory of Big Data Mining and Applications (Fujian University of Technology), and Harbin Institute of Technology Shenzhen Graduate School. IIH-MSP 2016 is held in 21-23, November, 2016 in Kaohsiung, Taiwan. The conference is an international forum for the researchers and professionals in all areas of information hiding and multimedia signal processing. .

  5. Family process and youth internalizing problems: A triadic model of etiology and intervention.

    Science.gov (United States)

    Schleider, Jessica L; Weisz, John R

    2017-02-01

    Despite major advances in the development of interventions for youth anxiety and depression, approximately 30% of youths with anxiety do not respond to cognitive behavioral treatment, and youth depression treatments yield modest symptom decreases overall. Identifying networks of modifiable risk and maintenance factors that contribute to both youth anxiety and depression (i.e., internalizing problems) may enhance and broaden treatment benefits by informing the development of mechanism-targeted interventions. A particularly powerful network is the rich array of family processes linked to internalizing problems (e.g., parenting styles, parental mental health problems, and sibling relationships). Here, we propose a new theoretical model, the triadic model of family process, to organize theory and evidence around modifiable, transdiagnostic family factors that may contribute to youth internalizing problems. We describe the model's implications for intervention, and we propose strategies for testing the model in future research. The model provides a framework for studying associations among family processes, their relation to youth internalizing problems, and family-based strategies for strengthening prevention and treatment.

  6. 1st International Conference on Recent Cognizance in Wireless Communication & Image Processing

    CERN Document Server

    Srivastava, Vishnu; Singh, Ghanshyam; Bhatnagar, Deepak

    2016-01-01

    This volume comprises the proceedings of the International Conference on Recent Cognizance in Wireless Communication & Image Processing. It brings together content from academicians, researchers, and industry experts in areas of Wireless Communication and Image Processing. The volume provides a snapshot of current progress in computational creativity and a glimpse of future possibilities. The proceedings include two kinds of paper submissions: (i) regular papers addressing foundation issues, describing original research on creative systems development and modeling; and (ii) position papers describing work-in-progress or research directions for computational creativity. This work will be useful to professionals and researchers working in the core areas of wireless communications and image processing.

  7. VII International scientific conference Radiation-thermal effects and processes in inorganic materials. Proceedings

    International Nuclear Information System (INIS)

    2010-01-01

    In the collection there are the reports of the VII International scientific conference and the VII All-Russian school-conference Radiation-thermal effects and processes in inorganic materials which were conducted on October 2-10, 2010, in Tomsk. The reports deal with new developments of charged particles high-intensity beam sources, high-temperature metrology of high-current beams and work materials, radiation-thermal stimulated effects and processes in inorganic materials, physical basics of technological processes, radiation-thermal technologies and equipment for their realization, allied branches of science and technology, specifically, nanotechnologies [ru

  8. International laser safety standardization. From the European perspective with an emphasis on materials processing

    Energy Technology Data Exchange (ETDEWEB)

    Schulmeister, K [Div. of Life Sciences, Dept. of Radiation Protection, Oesterreichisches Forschungszentrum Seibersdorf, 2444 Seibersdorf (Austria)

    1997-08-01

    This report reviews international standards relevant to the safety of laser products and laser installations, with an emphasis on the safety of laser materials processing from the European perspective. In the first paragraphs an overview of the international standards organisations, their relative roles and ways of developing new standards is given. In the second part of the report, work currently underway in the respective standards committees is summarised and specific standards dealing with different aspects of laser safety are discussed. An appendix contains a list of standards organised in standards organisations (IEC, ISO and EN). (author)

  9. International laser safety standardization. From the European perspective with an emphasis on materials processing

    International Nuclear Information System (INIS)

    Schulmeister, K.

    1997-08-01

    This report reviews international standards relevant to the safety of laser products and laser installations, with an emphasis on the safety of laser materials processing from the European perspective. In the first paragraphs an overview of the international standards organisations, their relative roles and ways of developing new standards is given. In the second part of the report, work currently underway in the respective standards committees is summarised and specific standards dealing with different aspects of laser safety are discussed. An appendix contains a list of standards organised in standards organisations IEC, ISO and EN). (author)

  10. Business Process Risk Management, Compliance and Internal Control: A Research Agenda

    DEFF Research Database (Denmark)

    Rikhardsson, Pall M.; Best, Peter; Green, Peter

    (COSO). Based on an inductive methodological approach using literature review and interviews with managers engaged in risk management and internal control projects, this paper identifies three main areas that currently have management attention. These are business process risk management, compliance......Integration of risk management and management control is emerging as an important area in the wake of the Sarbanes-Oxley Act and with ongoing development of frameworks such as the Enterprise Risk Management (ERM) framework from the Committee of Sponsoring Organizations of the Treadway Commission...... management and internal control development. This paper discusses these areas and identifies a series of research questions regarding these critical issues....

  11. Effect of uranyl nitrate and free acid concentration in feed solution of gelation on UO2 kernel quality

    International Nuclear Information System (INIS)

    Masduki, B.; Wardaya; Widarmoko, A.

    1996-01-01

    An investigation on the effect of uranium and free nitric acid concentration of uranyl nitrate as feed of gelation process on quality of UO 2 kernel was done.The investigation is to look for some concentration of uranyl nitrate solutions those are optimum as feed for preparation of gelled UO 3 . Uranyl nitrate solution of various concentration of uranium (450; 500; 550; 600; 650; 700 g/l) and free nitric acid of (0.9; 1.0; 1.1 N) was made into feed solutions by adding urea and HMTA with mole ratio of urea/uranium and HMTA/uranium 2.1 and 2.0. The feed solutions were changed into spherical gelled UO 3 by dropping was done to get the optimum concentrations of uranyl nitrate solutions. The gelled UO 3 was soaked and washed with 2.5% ammonia solution for 17 hours, dried at 70 o C, calcined at 350 o C for 3 hours then reduced at 850 o C for 3 hours. At every step of the steps process the colour and percentage of well product of gelled UO 3 were noticed. The density and O/U ratio of end product (UO 2 kernel) was determined, the percentage of well product of all steps process was also determined. The three factor were used to chose the optimum concentration of uranyl nitrate solution. From this investigation it was concluded that the optimum concentration of uranyl nitrate was 600 g/l uranium with free nitric acid 0,9 - 1,0 N, the percentage of well product was 97% density of 6.12 - 4.8 g/cc and O/U ratio of 2.15 - 2.06. (author)

  12. Supply chain process collaboration and Internet utilization: an international perspective of business to business relationships

    Directory of Open Access Journals (Sweden)

    Marcos Paulo Valadares de Oliveira

    2015-01-01

    Full Text Available This paper compiles the findings of an international study which primary objective was to investigate the relationships between Internet utilization in business-to-business relationships, collaborative efforts and their impact over supplier and customer-oriented processes performance. It highlights the Internet as an important enhancer of collaboration in supply chains and addresses the effects of such efforts on companies’ overall performance. As a conclusive-descriptive and quantitative study, data from a survey of 788 companies from the USA, China, Canada, United Kingdom, and Brazil were analyzed with the use of descriptive statistics, reliability evaluation of the research model’s internal scales, path analysis and structural equation modeling to evaluate supply chain processes collaboration, both up- and down-stream. Internet utilization in supplier and customer-oriented processes was found positively related to collaborative practices in business-to-business relationships. Collaborative practices in supplier and customer-oriented processes, in turn, showed potential effects on performance. Also, supplier-oriented processes performance was found positively associated with customer-oriented process performance. Both internet use and collaborative practices are even more important in a high-context country like Brazil. The paper helps clarify the impact of internet use on business-to-business collaborative relationships. In this sense, practitioners can take this impact to redraw the organizational landscape and business processes amongst supply chain participants.

  13. Trans individuals' facilitative coping: An analysis of internal and external processes.

    Science.gov (United States)

    Budge, Stephanie L; Chin, Mun Yuk; Minero, Laura P

    2017-01-01

    Existing research on trans individuals has primarily focused on their negative experiences and has disproportionately examined coming-out processes and identity development stages. Using a grounded theory approach, this qualitative study sought to examine facilitative coping processes among trans-identified individuals. Facilitative coping was operationalized as processes whereby individuals seek social support, learn new skills, change behaviors to positively adapt, and find alternative means to seek personal growth and acceptance. The sample included 15 participants who self-identified with a gender identity that was different from their assigned sex at birth. Results yielded a total of nine overarching themes: Accepting Support from Others, Actions to Increase Protection, Active Engagement Throughout the Transition Process, Actively Seeking Social Interactions, Engaging in Exploration, Internal Processes Leading to Self-Acceptance, Self-Efficacy, Shifts Leading to Embracing Change and Flexibility, and Utilization of Agency. Based on the analysis, a theoretical model emerged that highlighted the importance of internal and external coping processes in facilitating gender identity development and navigating stressors among trans individuals. Clinical implications focusing on how to implement facilitative coping processes are discussed. (PsycINFO Database Record (c) 2017 APA, all rights reserved).

  14. The importance of establishing an international network of tissue banks and regional tissue processing centers.

    Science.gov (United States)

    Morales Pedraza, Jorge

    2014-03-01

    During the past four decades, many tissue banks have been established across the world with the aim of supplying sterilized tissues for clinical use and research purposes. Between 1972 and 2005, the International Atomic Energy Agency supported the establishment of more than sixty of these tissue banks in Latin America and the Caribbean, Asia and the Pacific, Africa and Eastern Europe; promoted the use of the ionizing radiation technique for the sterilization of the processed tissues; and encouraged cooperation between the established tissue banks during the implementation of its program on radiation and tissue banking at national, regional and international levels. Taking into account that several of the established tissue banks have gained a rich experience in the procurement, processing, sterilization, storage, and medical use of sterilized tissues, it is time now to strengthen further international and regional cooperation among interested tissue banks located in different countries. The purpose of this cooperation is to share the experience gained by these banks in the procurement, processing, sterilization, storage, and used of different types of tissues in certain medical treatments and research activities. This could be done through the establishment of a network of tissue banks and a limited number of regional tissue processing centers in different regions of the world.

  15. Levels-of-processing effect on internal source monitoring in schizophrenia.

    Science.gov (United States)

    Ragland, J Daniel; McCarthy, Erin; Bilker, Warren B; Brensinger, Colleen M; Valdez, Jeffrey; Kohler, Christian; Gur, Raquel E; Gur, Ruben C

    2006-05-01

    Recognition can be normalized in schizophrenia by providing patients with semantic organizational strategies through a levels-of-processing (LOP) framework. However, patients may rely primarily on familiarity effects, making recognition less sensitive than source monitoring to the strength of the episodic memory trace. The current study investigates whether providing semantic organizational strategies can also normalize patients' internal source-monitoring performance. Sixteen clinically stable medicated patients with schizophrenia and 15 demographically matched healthy controls were asked to identify the source of remembered words following an LOP-encoding paradigm in which they alternated between processing words on a 'shallow' perceptual versus a 'deep' semantic level. A multinomial analysis provided orthogonal measures of item recognition and source discrimination, and bootstrapping generated variance to allow for parametric analyses. LOP and group effects were tested by contrasting recognition and source-monitoring parameters for words that had been encoded during deep versus shallow processing conditions. As in a previous study there were no group differences in LOP effects on recognition performance, with patients and controls benefiting equally from deep versus shallow processing. Although there were no group differences in internal source monitoring, only controls had significantly better performance for words processed during the deep encoding condition. Patient performance did not correlate with clinical symptoms or medication dose. Providing a deep processing semantic encoding strategy significantly improved patients' recognition performance only. The lack of a significant LOP effect on internal source monitoring in patients may reflect subtle problems in the relational binding of semantic information that are independent of strategic memory processes.

  16. International Best Practices for Pre-Processing and Co-Processing Municipal Solid Waste and Sewage Sludge in the Cement Industry

    Energy Technology Data Exchange (ETDEWEB)

    Hasanbeigi, Ali [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Lu, Hongyou [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Williams, Christopher [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Price, Lynn [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

    2012-07-01

    The purpose of this report is to describe international best practices for pre-processing and coprocessing of MSW and sewage sludge in cement plants, for the benefit of countries that wish to develop co-processing capacity. The report is divided into three main sections. Section 2 describes the fundamentals of co-processing, Section 3 describes exemplary international regulatory and institutional frameworks for co-processing, and Section 4 describes international best practices related to the technological aspects of co-processing.

  17. Dimensional accuracy of internal cooling channel made by selective laser melting (SLM And direct metal laser sintering (DMLS processes in fabrication of internally cooled cutting tools

    Directory of Open Access Journals (Sweden)

    Ghani S. A. C.

    2017-01-01

    Full Text Available Selective laser melting(SLM and direct metal laser sintering(DMLS are preferred additive manufacturing processes in producing complex physical products directly from CAD computer data, nowadays. The advancement of additive manufacturing promotes the design of internally cooled cutting tool for effectively used in removing generated heat in metal machining. Despite the utilisation of SLM and DMLS in a fabrication of internally cooled cutting tool, the level of accuracy of the parts produced remains uncertain. This paper aims at comparing the dimensional accuracy of SLM and DMLS in machining internally cooled cutting tool with a special focus on geometrical dimensions such as hole diameter. The surface roughness produced by the two processes are measured with contact perthometer. To achieve the objectives, geometrical dimensions of identical tool holders for internally cooled cutting tools fabricated by SLM and DMLS have been determined by using digital vernier calliper and various magnification of a portable microscope. In the current study, comparing internally cooled cutting tools made of SLM and DMLS showed that generally the higher degree of accuracy could be obtained with DMLS process. However, the observed differences in surface roughness between SLM and DMLS in this study were not significant. The most obvious finding to emerge from this study is that the additive manufacturing processes selected for fabricating the tool holders for internally cooled cutting tool in this research are capable of producing the desired internal channel shape of internally cooled cutting tool.

  18. Ayahuasca and the process of regulation in Brazil and internationally: implications and challenges.

    Science.gov (United States)

    Labate, Beatriz Caiuby; Feeney, Kevin

    2012-03-01

    This paper provides a summary and analysis of the regulation of ayahuasca in Brazil, from its prohibition in the mid-eighties to the recent adoption of CONAD's (Conselho Nacional de Políticas sobre Drogas) 2010 Resolution, which established a set of rules, norms and ethical principles to be applied to religious and ritual uses of ayahuasca. Brazil's regulatory process is used as a starting point to explore emerging international regulatory themes as various nations respond to the global expansion of the Santo Daime and UDV (União do Vegetal) ayahuasca religions. The text reviews the primary legislative and court documents, academic literature, as well as solicited expert opinions. Three prominent themes have emerged internationally. The first concerns the scope of international treaties regarding plant-based psychoactive substances, as well as the responsibilities of individual nations to adhere to said treaties. The second concerns the scope of religious liberty and how to determine religious legitimacy. The final theme addresses the potential dangers of ayahuasca to health and public safety. Over the past 20 years the Brazilian ayahuasca religions have established a global presence, with congregations in the USA, Canada, Japan, South Africa, Australia, and throughout Europe and Latin America. As a result, many nations are faced with the predicament of balancing the interests of these religious minorities with the international "war on drugs." The regulatory process applied in Brazil exemplifies a progressive approach, one which considered issues of anthropology and involved representatives of ayahuasca religions, and which provided a degree of deference to the principle of religious liberty. The Brazilian process has influenced judicial and administrative decisions internationally, and stands as a model worthy of further consideration. Copyright © 2011 Elsevier B.V. All rights reserved.

  19. Processes in the development of international specialist competencies and standards: the Sports Physiotherapy for All Project.

    Science.gov (United States)

    Bulley, Catherine; Donaghy, Marie

    2008-01-01

    In a world of rapidly developing knowledge it is important that professions describe their roles and capabilities. The need for a thorough description of sports physiotherapy was addressed through collaboration between the International Federation of Sports Physiotherapy (IFSP) and five European higher education institutions. This resulted in the Sports Physiotherapy for All Project, which has been successful in developing internationally accepted competencies and standards for sports physiotherapists. This article describes and reflects on the process to communicate useful lessons. A competency model was chosen to facilitate differentiation and communication of aspects of sports physiotherapy practice. Documentation relating to sports physiotherapy practice was collected from 16 countries and analysed thematically. A cut and paste method was used by a panel of experts to allocate themes to areas of practice within the competency model. Theme groups were used to select areas of practice for description in competency form. Standards were derived from competencies following in depth discussion with the expert panel, and triangulation with themes derived from international documentation. A rigorous process of international review and revision led to the final list of 11 competencies and related standards, both accepted by the IFSP. This work provides a foundation for the development of an audit toolkit to guide demonstration and evaluation of competencies and standards. This provides a foundation for targeted career development activities, appropriate provision of training opportunities, and quality enhancement. The experiences gained during this project can inform other health professions and their specialisms when embarking on a similar journey.

  20. PREFACE: I International Scientific School Methods of Digital Image Processing in Optics and Photonics

    Science.gov (United States)

    Gurov, I. P.; Kozlov, S. A.

    2014-09-01

    The first international scientific school "Methods of Digital Image Processing in Optics and Photonics" was held with a view to develop cooperation between world-class experts, young scientists, students and post-graduate students, and to exchange information on the current status and directions of research in the field of digital image processing in optics and photonics. The International Scientific School was managed by: Saint Petersburg National Research University of Information Technologies, Mechanics and Optics (ITMO University) - Saint Petersburg (Russia) Chernyshevsky Saratov State University - Saratov (Russia) National research nuclear University "MEPHI" (NRNU MEPhI) - Moscow (Russia) The school was held with the participation of the local chapters of Optical Society of America (OSA), the Society of Photo-Optical Instrumentation Engineers (SPIE) and IEEE Photonics Society. Further details, including topics, committees and conference photos are available in the PDF

  1. Proton triggered circularly polarized luminescence in orthogonal- and co-assemblies of chiral gelators with achiral perylene bisimide.

    Science.gov (United States)

    Han, Dongxue; Han, Jianlei; Huo, Shengwei; Qu, Zuoming; Jiao, Tifeng; Liu, Minghua; Duan, Pengfei

    2018-05-29

    The orthogonal- or co-assembly of achiral perylene bisimide (PBI) with chiral gelators can be regulated by solvents. While the coassembly leads to the formation of chiroptical nanofibers through chirality transfer, the orthogonal assemblies could not. Moreover, protonation on the coassembled nanofibers could light up the circularly polarized luminescence (CPL).

  2. Gels with exceptional thermal stability formed by bis(amino acid) oxalamide gelators and solvents of low polarity.

    Science.gov (United States)

    Makarević, Janja; Jokić, Milan; Frkanec, Leo; Katalenić, Darinka; Zinić, Mladen

    2002-10-07

    Some bis (amino acid) oxalamide gelators form common thermo-reversible gels with various organic solvents but also gels of exceptional thermal stability with some solvents of medium and low polarity; the latter gels can be heated up to 50 degrees C higher temperatures than the bp of the solvent without apparent gel-to-sol transition.

  3. Effect of gelation of inner dispersed phase on stability of (w1/o/w2) multiple emulsions

    NARCIS (Netherlands)

    Oppermann, A.K.L.; Renssen, M.; Schuch, A.; Stieger, M.A.; Scholten, E.

    2015-01-01

    The use of water-in-oil-in-water (w1/o/w2) multiple emulsions offers a method for the reduction of oil in foods. In this study we investigated the influence of osmotic pressure tailoring and gelation of the inner dispersed w1 water droplets on the stability and yield of multiple emulsions. Yield is

  4. 2nd International Conference on Mechanical, Manufacturing and Process Plant Engineering

    CERN Document Server

    2017-01-01

    This volume presents selected papers from the 2nd International Conference on Mechanical, Manufacturing and Process Plant Engineering (ICMMPE 2016) which was held from 23rd to 24th November, 2016 in Kuala Lumpur, Malaysia. The proceedings discuss genuine problems of joining technologies that are heart of manufacturing sectors. It discusses the findings of experimental and numerical works from soldering, arc welding to solid state joining technology that faced by current industry. .

  5. Amnesty, Reconciliation and Reintegration: The International Community and the Rwandan Process

    Science.gov (United States)

    2008-05-22

    N., Harvey M. Weinstein , and Timothy Longman. "Trauma and PTSD Symptoms in Rwanda: Implications for Attitudes Toward Justice and Reconciliation...repairing the social fabric of the nation had to take place. The case shows how Rwanda overcame the negative impacts of the international community and...reintegration policies. Throughout the case there are four issues that prove integral to the AR2 process; the anthropology of Rwanda, its colonial

  6. Critical Internal Factors Influencing The Centralization Of Stock Procurement Processes In A South African Municipality

    OpenAIRE

    Zwelihle Wiseman Nzuza; Lawrence Mpele Lekhanya

    2014-01-01

    The purpose of this paper was threefold: 1) to examine the internal factors influencing centralization of stock procurement processes, 2) to assess the relationship between demographic factors and staff understanding of Information Communication Technology (ICT) with performance improvement, and 3) to examine the relationship between prevention of corruption with management commitment. A structured questionnaire was used to collect data from 82 members of staff from procurement division in a ...

  7. A review of internal combustion engine combustion chamber process studies at NASA Lewis Research Center

    Science.gov (United States)

    Schock, H. J.

    1984-01-01

    The performance of internal combustion stratified-charge engines is highly dependent on the in-cylinder fuel-air mixing processes occurring in these engines. Current research concerning the in-cylinder airflow characteristics of rotary and piston engines is presented. Results showing the output of multidimensional models, laser velocimetry measurements and the application of a holographic optical element are described. Models which simulate the four-stroke cycle and seal dynamics of rotary engines are also discussed.

  8. An analysis of viable financial negotiations processes and related internal controls for procurement in Pakistan

    OpenAIRE

    Rafique, Abdul B.; Malik, Muhammad W.; Salman, Muhammad

    2016-01-01

    MBA Professional Report Approved for public release; distribution is unlimited In Pakistan, the process of public procurement procedure standardization started in 2002 with the establishment of the Pakistan Public Procurement Regulatory Authority (PPRA), based on the 1994 United Nations Commission on International Trade Law (UNCITRAL) Model Law. PPRA rules allow four types of procurement procedures but limit the ability to conduct financial negotiations. PPRA rules are aimed at implemen...

  9. Strategies for Enhancing Nonlinear Internal Model Control of pH Processes

    Energy Technology Data Exchange (ETDEWEB)

    Hu, Qiuping.; Rangaiah, G.P. [The National University of Singapore, Singapore (Singapore). Dept. of Chemical and Environmental Engineering

    1999-02-01

    Control of neutralization processes is very difficult due to nonlinear dynamics, different types of disturbances and modeling errors. The objective of the paper is to evaluate two strategies (augmented internal model control, AuIMC and adaptive internal model control, AdIMC) for enhancing pH control by nonlinear internal model control (NIMC). A NIMC controller is derived directly form input output linearization. The AuIMC is composed of NIMC and an additional loop through which the difference between the process and model outputs is fed back and added to the input of the controller. For the AdIMC, and adaptive law with two tuning parameters is proposed for estimating the unknown parameter. Both AuIMC and AdIMC are extensively tested via simulation for pH neutralization. The theoretical and simulation results show that both the proposed strategies can reduce the effect of modeling errors and disturbances, and thereby enhance the performance of NIMC for pH processes. (author)

  10. [Internal audit in medical laboratory: what means of control for an effective audit process?].

    Science.gov (United States)

    Garcia-Hejl, Carine; Chianéa, Denis; Dedome, Emmanuel; Sanmartin, Nancy; Bugier, Sarah; Linard, Cyril; Foissaud, Vincent; Vest, Philippe

    2013-01-01

    To prepare the French Accreditation Committee (COFRAC) visit for initial certification of our medical laboratory, our direction evaluated its quality management system (QMS) and all its technical activities. This evaluation was performed owing an internal audit. This audit was outsourced. Auditors had an expertise in audit, a whole knowledge of biological standards and were independent. Several nonconformities were identified at that time, including a lack of control of several steps of the internal audit process. Hence, necessary corrective actions were taken in order to meet the requirements of standards, in particular, the formalization of all stages, from the audit program, to the implementation, review and follow-up of the corrective actions taken, and also the implementation of the resources needed to carry out audits in a pre-established timing. To ensure an optimum control of each step, the main concepts of risk management were applied: process approach, root cause analysis, effects and criticality analysis (FMECA). After a critical analysis of our practices, this methodology allowed us to define our "internal audit" process, then to formalize it and to follow it up, with a whole documentary system.

  11. Marital Processes, Neuroticism, and Stress as Risk Factors for Internalizing Symptoms.

    Science.gov (United States)

    Brock, Rebecca L; Lawrence, Erika

    2014-03-01

    Marital discord has a robust association with depression, yet it is rarely considered within broader etiological frameworks of psychopathology. Further, little is known about the particular aspects of relationships that have the greatest impact on psychopathology. The purpose of the present study was to test a novel conceptual framework including neuroticism, specific relationship processes (conflict management, partner support, emotional intimacy, and distribution of power and control), and stress as predictors of internalizing symptoms (depression and anxiety). Questionnaire and interview data were collected from 103 husbands and wives 5 times over the first 7 years of marriage. Results suggest that neuroticism (an expression of the underlying vulnerability for internalizing disorders) contributes to symptoms primarily through high levels of non-marital stress, an imbalance of power/control in one's marriage, and poor partner support for husbands, and through greater emotional disengagement for wives. Marital processes, neuroticism, and stress work together to significantly predict internalizing symptoms, demonstrating the need to routinely consider dyadic processes in etiological models of individual psychopathology. Specific recommendations for adapting and implementing couple interventions to prevent and treat individual psychopathology are discussed.

  12. 9th International Conference on Robotics, Vision, Signal Processing & Power Applications

    CERN Document Server

    Iqbal, Shahid; Teoh, Soo; Mustaffa, Mohd

    2017-01-01

     The proceeding is a collection of research papers presented, at the 9th International Conference on Robotics, Vision, Signal Processing & Power Applications (ROVISP 2016), by researchers, scientists, engineers, academicians as well as industrial professionals from all around the globe to present their research results and development activities for oral or poster presentations. The topics of interest are as follows but are not limited to:   • Robotics, Control, Mechatronics and Automation • Vision, Image, and Signal Processing • Artificial Intelligence and Computer Applications • Electronic Design and Applications • Telecommunication Systems and Applications • Power System and Industrial Applications • Engineering Education.

  13. 8th International Conference on Robotic, Vision, Signal Processing & Power Applications

    CERN Document Server

    Mustaffa, Mohd

    2014-01-01

    The proceeding is a collection of research papers presented, at the 8th International Conference on Robotics, Vision, Signal Processing and Power Applications (ROVISP 2013), by researchers, scientists, engineers, academicians as well as industrial professionals from all around the globe. The topics of interest are as follows but are not limited to: • Robotics, Control, Mechatronics and Automation • Vision, Image, and Signal Processing • Artificial Intelligence and Computer Applications • Electronic Design and Applications • Telecommunication Systems and Applications • Power System and Industrial Applications  

  14. Information Processing and Firm-Internal Environment Contingencies: Performance Impact on Global New Product Development

    DEFF Research Database (Denmark)

    Kleinschmidt, Elko; de Brentani, Ulrike; Salomo, Søren

    2010-01-01

    , functionally, geographically and culturally. To this end, an IT-communication strength is essential, one that is nested in an internal organizational environment that ensures its effective functioning. Using organizational information processing (OIP) theory as a framework, superior global NPD program......Innovation in its essence is an information processing activity. Thus, a major factor impacting the success of new product development (NPD) programs, especially those responding to global markets, is the firm's ability to access, share and apply NPD information, which is often widely dispersed...

  15. International Conference on Materials, Processing and Product Engineering 2015 (MPPE2015)

    International Nuclear Information System (INIS)

    Eck, S; Ebner, R; Ludwig, A

    2016-01-01

    The Materials Center Leoben Forschung GmbH (MCL) and the Austrian Society for Metallurgy and Materials (ASMET) have jointly organized the 'First International Conference on Materials, Processing and Product Engineering - MPPE' held in the Congress Center of Leoben from Nov. 3 rd to 5 th , 2015. The main topic of the conference was to present the state of the art in fundamental knowledge and technological expertise enabling and stimulating the development of knowledge based innovations across the entire product value chain starting from the material synthesis, proceeding with the processing of products and concluding with their in-service behaviour until the end of the product life time. Hence, the International Conference on Materials, Processing and Product Engineering MPPE 2015 focused on the core regions of industrial production chains, covering topics such as • Development and characterization of materials; • Materials synthesis and processing; • Dimensioning of components including integrated materials and process modelling; • Behaviour of materials and components during service. The scientific and technological goal was to present the state of the art of theoretical, experimental and numerical techniques and their combinations that are capable of improving the competitiveness of modern production facilities. (paper)

  16. Acid skim milk gels: The gelation process as affected by preheated pH

    NARCIS (Netherlands)

    Lakemond, C.M.M.; Vliet, van T.

    2008-01-01

    The effect of preheating milk (10 min 80 [degree sign]C) at pH values from 6.20 to 6.90 on formation of acid skim milk gels was studied by dynamic oscillation measurements. Up to pH 6.65 a higher pH of heating (pHheating) resulted in a higher G'. Since below pH 4.9 the development of

  17. The continuous improvement of the Internal Audits Process assurance the effective compliance of ISO 17025:2005 requirements

    Directory of Open Access Journals (Sweden)

    Carina Di Candia

    2011-04-01

    Full Text Available Continuous Improvement Process started in LATU in 1996. The Impact was so important that covered all the organization. Nowadays LATU has almost all its processes certificated and most than 200 tests accredited. The Internal Audits process began in 1996 with an annual planning for all the laboratory's areas. For the UKAS accreditation in 1998, LATU improves the internal audits planning auditing not only the system but also the tests. In 1999 LATU was certified by SQS and accredited the calibrations by DKD. Since 2004 internal audits was managed as a process; in order to that was defined objectives, indicators, achievements and the necessary resources of the internal audit programme and process. The internal audit programme has a pre defined tri annual planning that includes all the laboratory areas. The results of the measures obtained till now demonstrate the improvement in the internal audit and all the laboratory processes. Auditors final staff increase their technical competence. As a consequence of managing the internal audits as a process, the internal communication has an important relevance to feedback the continuous improvement of the laboratory. This was evidence in a decrease of the documentaries non conformities, improvement of the calibrations and maintenance programme, optimization trainings and qualifications of the staff, common internal trainings, creation of a quality assurance team to improvement the tests control, improvement in the relationship with the support areas. Most of this requirements are included in ISO 17025:2005; that assurance the effective compliance of this standard.

  18. Concepts in context: Processing mental state concepts with internal or external focus involves different neural systems

    Science.gov (United States)

    Oosterwijk, Suzanne; Mackey, Scott; Wilson-Mendenhall, Christine; Winkielman, Piotr; Paulus, Martin P.

    2015-01-01

    According to embodied cognition theories concepts are contextually-situated and grounded in neural systems that produce experiential states. This view predicts that processing mental state concepts recruits neural regions associated with different aspects of experience depending on the context in which people understand a concept. This neuroimaging study tested this prediction using a set of sentences that described emotional (e.g., fear, joy) and non-emotional (e.g., thinking, hunger) mental states with internal focus (i.e. focusing on bodily sensations and introspection) or external focus (i.e. focusing on expression and action). Consistent with our predictions, data suggested that the inferior frontal gyrus, a region associated with action representation, was engaged more by external than internal sentences. By contrast, the ventromedial prefrontal cortex, a region associated with the generation of internal states, was engaged more by internal emotion sentences than external sentence categories. Similar patterns emerged when we examined the relationship between neural activity and independent ratings of sentence focus. Furthermore, ratings of emotion were associated with activation in the medial prefrontal cortex, whereas ratings of activity were associated with activation in the inferior frontal gyrus. These results suggest that mental state concepts are represented in a dynamic way, using context-relevant interoceptive and sensorimotor resources. PMID:25748274

  19. Transdermal gelation of methacrylated macromers with near-infrared light and gold nanorods

    International Nuclear Information System (INIS)

    Gramlich, William M; Holloway, Julianne L; Rai, Reena; Burdick, Jason A

    2014-01-01

    Injectable hydrogels provide locally controlled tissue bulking and a means to deliver drugs and cells to the body. The formation of hydrogels in vivo may involve the delivery of two solutions that spontaneously crosslink when mixed, with pH or temperature changes, or with light (e.g., visible or ultraviolet). With these approaches, control over the kinetics of gelation, introduction of the initiation trigger (e.g., limited penetration of ultraviolet light through tissues), or alteration of the material physical properties (e.g., mechanics) may be difficult to achieve. To overcome these limitations, we used the interaction of near-infrared (NIR) light with gold nanorods (AuNRs) to generate heat through the photothermal effect. NIR light penetrates tissues to a greater extent than other wavelengths and provides a means to indirectly initiate radical polymerization. Specifically, this heating coupled with a thermal initiator (VA-044) produced radicals that polymerized methacrylated hyaluronic acid (MeHA) and generated hydrogels. A range of VA-044 concentrations changed the gelation time, yielding a system stable at 37 ° C for 22 min that gels quickly (∼3 min) when heated to 55 ° C. With a constant irradiation time (10 min) and laser power (0.3 W), different VA-044 and AuNR concentrations tuned the compressive modulus of the hydrogel. By changing the NIR irradiation time we attained a wide range of moduli at a set solution composition. In vivo mouse studies confirmed that NIR laser irradiation through tissue could gel an injected precursor solution transdermally. (paper)

  20. Transdermal gelation of methacrylated macromers with near-infrared light and gold nanorods

    Science.gov (United States)

    Gramlich, William M.; Holloway, Julianne L.; Rai, Reena; Burdick, Jason A.

    2014-01-01

    Injectable hydrogels provide locally controlled tissue bulking and a means to deliver drugs and cells to the body. The formation of hydrogels in vivo may involve the delivery of two solutions that spontaneously crosslink when mixed, with pH or temperature changes, or with light (e.g., visible or ultraviolet). With these approaches, control over the kinetics of gelation, introduction of the initiation trigger (e.g., limited penetration of ultraviolet light through tissues), or alteration of the material physical properties (e.g., mechanics) may be difficult to achieve. To overcome these limitations, we used the interaction of near-infrared (NIR) light with gold nanorods (AuNRs) to generate heat through the photothermal effect. NIR light penetrates tissues to a greater extent than other wavelengths and provides a means to indirectly initiate radical polymerization. Specifically, this heating coupled with a thermal initiator (VA-044) produced radicals that polymerized methacrylated hyaluronic acid (MeHA) and generated hydrogels. A range of VA-044 concentrations changed the gelation time, yielding a system stable at 37 ° C for 22 min that gels quickly (˜3 min) when heated to 55 ° C. With a constant irradiation time (10 min) and laser power (0.3 W), different VA-044 and AuNR concentrations tuned the compressive modulus of the hydrogel. By changing the NIR irradiation time we attained a wide range of moduli at a set solution composition. In vivo mouse studies confirmed that NIR laser irradiation through tissue could gel an injected precursor solution transdermally.

  1. Exergetic analysis of cogeneration plants through integration of internal combustion engine and process simulators

    Energy Technology Data Exchange (ETDEWEB)

    Carvalho, Leonardo de Oliveira [Petroleo Brasileiro S.A. (PETROBRAS), Rio de Janeiro, RJ (Brazil)], E-mail: leonardo.carvalho@petrobras.com.br; Leiroz, Albino Kalab; Cruz, Manuel Ernani [Coordenacao dos Programas de Pos-Graduacao de Engenharia (COPPE/UFRJ), RJ (Brazil). Programa de Engenharia Mecanica], Emails: leiroz@mecanica.ufrj.br, manuel@mecanica.ufrj.br

    2010-07-01

    Internal combustion engines (ICEs) have been used in industry and power generation much before they were massively employed for transportation. Their high reliability, excellent power-to-weight ratio, and thermal efficiency have made them a competitive choice as main energy converters in small to medium sized power plants. Process simulators can model ICE powered energy plants with limited depth, due to the highly simplified ICE models used. Usually a better understanding of the global effects of different engine parameters is desirable, since the combustion process within the ICE is typically the main cause of exergy destruction in systems which utilize them. Dedicated commercial ICE simulators have reached such a degree of maturity, that they can adequately model a wide spectrum of phenomena that occur in ICEs. However, ICE simulators are unable to incorporate the remaining of power plant equipment and processes in their models. This paper presents and exploits the integration of an internal combustion engine simulator with a process simulator, so as to evaluate the construction of a fully coupled simulation platform to analyze the performance of ICE-based power plants. A simulation model of an actual cogeneration plant is used as a vehicle for application of the proposed computational methodology. The results show that by manipulating the engine mapping parameters, the overall efficiency of the plant can be improved. (author)

  2. MCWASP XIV: International Conference on Modelling of Casting, Welding and Advanced Solidification Processes

    International Nuclear Information System (INIS)

    Yasuda, H

    2015-01-01

    The current volume represents contributed papers of the proceedings of the 14th international conference on ''Modeling of Casting, Welding and Advanced Solidification Processes (MCWASP XIV)'', Yumebutai International Conference Center, Awaji island, Hyogo, Japan on 21 – 26 June, 2016. The first conference of the series 'Modeling of Casting, Welding and Advanced Solidification Processes (MCWASP)' was started up in 1980, and this is the 14th conference. The participants are more than 100 scientists from industry and academia, coming from 19 countries. In the conference, we have 5 invited, 70 oral and 31 poster presentations on different aspects of the modeling. The conference deals with various casting processes (Ingot / shape casting, continuous casting, direct chill casting and welding), fundamental phenomena (nucleation and growth, dendritic growth, eutectic growth, micro-, meso- and macrostructure formation and defect formation), coupling problems (electromagnetic interactions, application of ultrasonic wave), development of experimental / computational methods and so on. This volume presents the cutting-edge research in the modeling of casting, welding and solidification processes. I would like to thank MAGMA Giessereitechnologie GmbH, Germany and SCSK Corporation, Japan for supporting the publication of contributed papers. Hideyuki Yasuda Conference Chairman Department of Materials Science and Engineering, Kyoto University Japan (preface)

  3. Determination of hexamethylene tetramine in the process solution of sol-gel method for nuclear fuel fabrication

    International Nuclear Information System (INIS)

    Ganatra, V.R.; Sawant, R.M.; Chaudhuri, N.K.; Vaidya, V.N.

    1998-01-01

    Hexamethylene tetramine (HMTA) was determined in the presence of large quantities of urea, formaldehyde and ammonium hydroxide by potentiometric titration with perchloric acid solution using an autotitrator coupled to a personal computer. This analysis is required for the process control of the sol-gel method in the production of ceramic metal oxide (e.g., oxides and mixed oxides of Th, U and Pu) microspheres using the internal gelation route. Feed solution used for preparation of microspheres contains large quantities of urea. The washings of gel microspheres produced after the internal gelation process contain urea, formaldehyde, urea-formaldehyde complex and ammonium hydroxide. The presence of these constituents in the feed solution and washings seriously interfere in the commonly used methods for the determination of HMTA. Using this method the relative standard deviation was found to be 0.27% in eleven determinations of a typical feed solution (3.0M HMTA) when the aliquots contained 75 to 125 mg of HMTA. Time required for each titration was 5-7 minutes. Feed and effluent solutions of sol-gel process were analysed. (author)

  4. A novel mini-DNA barcoding assay to identify processed fins from internationally protected shark species.

    Science.gov (United States)

    Fields, Andrew T; Abercrombie, Debra L; Eng, Rowena; Feldheim, Kevin; Chapman, Demian D

    2015-01-01

    There is a growing need to identify shark products in trade, in part due to the recent listing of five commercially important species on the Appendices of the Convention on International Trade in Endangered Species (CITES; porbeagle, Lamna nasus, oceanic whitetip, Carcharhinus longimanus scalloped hammerhead, Sphyrna lewini, smooth hammerhead, S. zygaena and great hammerhead S. mokarran) in addition to three species listed in the early part of this century (whale, Rhincodon typus, basking, Cetorhinus maximus, and white, Carcharodon carcharias). Shark fins are traded internationally to supply the Asian dried seafood market, in which they are used to make the luxury dish shark fin soup. Shark fins usually enter international trade with their skin still intact and can be identified using morphological characters or standard DNA-barcoding approaches. Once they reach Asia and are traded in this region the skin is removed and they are treated with chemicals that eliminate many key diagnostic characters and degrade their DNA ("processed fins"). Here, we present a validated mini-barcode assay based on partial sequences of the cytochrome oxidase I gene that can reliably identify the processed fins of seven of the eight CITES listed shark species. We also demonstrate that the assay can even frequently identify the species or genus of origin of shark fin soup (31 out of 50 samples).

  5. A novel mini-DNA barcoding assay to identify processed fins from internationally protected shark species.

    Directory of Open Access Journals (Sweden)

    Andrew T Fields

    Full Text Available There is a growing need to identify shark products in trade, in part due to the recent listing of five commercially important species on the Appendices of the Convention on International Trade in Endangered Species (CITES; porbeagle, Lamna nasus, oceanic whitetip, Carcharhinus longimanus scalloped hammerhead, Sphyrna lewini, smooth hammerhead, S. zygaena and great hammerhead S. mokarran in addition to three species listed in the early part of this century (whale, Rhincodon typus, basking, Cetorhinus maximus, and white, Carcharodon carcharias. Shark fins are traded internationally to supply the Asian dried seafood market, in which they are used to make the luxury dish shark fin soup. Shark fins usually enter international trade with their skin still intact and can be identified using morphological characters or standard DNA-barcoding approaches. Once they reach Asia and are traded in this region the skin is removed and they are treated with chemicals that eliminate many key diagnostic characters and degrade their DNA ("processed fins". Here, we present a validated mini-barcode assay based on partial sequences of the cytochrome oxidase I gene that can reliably identify the processed fins of seven of the eight CITES listed shark species. We also demonstrate that the assay can even frequently identify the species or genus of origin of shark fin soup (31 out of 50 samples.

  6. Averaging, not internal noise, limits the development of coherent motion processing

    Directory of Open Access Journals (Sweden)

    Catherine Manning

    2014-10-01

    Full Text Available The development of motion processing is a critical part of visual development, allowing children to interact with moving objects and navigate within a dynamic environment. However, global motion processing, which requires pooling motion information across space, develops late, reaching adult-like levels only by mid-to-late childhood. The reasons underlying this protracted development are not yet fully understood. In this study, we sought to determine whether the development of motion coherence sensitivity is limited by internal noise (i.e., imprecision in estimating the directions of individual elements and/or global pooling across local estimates. To this end, we presented equivalent noise direction discrimination tasks and motion coherence tasks at both slow (1.5°/s and fast (6°/s speeds to children aged 5, 7, 9 and 11 years, and adults. We show that, as children get older, their levels of internal noise reduce, and they are able to average across more local motion estimates. Regression analyses indicated, however, that age-related improvements in coherent motion perception are driven solely by improvements in averaging and not by reductions in internal noise. Our results suggest that the development of coherent motion sensitivity is primarily limited by developmental changes within brain regions involved in integrating motion signals (e.g., MT/V5.

  7. Analysis and prediction of dimensions and cost of laser micro-machining internal channel fabrication process

    Directory of Open Access Journals (Sweden)

    Brabazon D.

    2010-06-01

    Full Text Available This paper presents the utilisation of Response Surface Methodology (RSM as the prediction tool for the laser micro-machining process. Laser internal microchannels machined using pulsed Nd:YVO4 laser in polycarbonate were investigated. The experiments were carried out according to 33 factorial Design of Experiment (DoE. In this work the three input process set as control parameters were laser power, P; pulse repetition frequency, PRF; and sample translation speed, U. Measured responses were the channel width and the micro-machining operating cost per metre of produced microchannels. The responses were sufficiently predicted within the set micro-machining parameters limits. Two factorial interaction (2FI and quadratic polynomial regression equations for both responses were constructed. It is proposed that the developed prediction equations can be used to find locally optimal micro-machining process parameters under experimental and operational conditions.

  8. Microsoft excel's automatic data processing and diagram drawing of RIA internal quality control parameters

    International Nuclear Information System (INIS)

    Zeng Pingfan; Liu Guoqiang

    2006-01-01

    We did automatic data processing and diagram drawing of various parameters of RIA' s internal quality control (IQC)by the use of Microsoft Excel (ME). By use of AVERAGE and STDEV of ME, we got x-bar, s and CV%. With pearson, we got the serum quality control coefficients (r). Inputing the original data to diagram's self-definition item, the diagram was drawn automatically. By the use of logic judging, we got the quality control judging results with the status, timing and data of various quality control parameters. For the past four years, the ME data processing and diagram drawing as well as quality control judging have been showed to be accurate, convenient and correct. It was quick and easy to manage and the automatic computer processing of RIA's IQC was realized. Conclusion: the method is applicable to all types of RIA' s IQC. (authors)

  9. Study of the spheronization process of glass particles by the gravitational falling process for internal selective radiotherapy

    International Nuclear Information System (INIS)

    Barros Filho, E.C.; Martinelli, J.R.; Sene, F.F.

    2011-01-01

    The internal selective radiotherapy is an alternative to treat hepatocellular carcinoma. Glass microspheres containing β - emitter radionuclide are introduced in the liver, and they are housed preferentially in the region where the cancer cells are located. The microspheres are trapped in the arterioles which feed the tumors, and the β - particles annihilate the cancer cells. The glass particles must be spherical to avoid unnecessary bleeding, and the particle size must be restricted to a range which optimizes the blocking effect and avoid the migration to other parts of the human body. The particle size distribution of microspheres is not easily predicted since the variation of the aspect ratio and the presence of agglomerates can influence the resulting particle size distribution. In the present work, the spheronization process to obtain microspheres from irregular shape glass particles with suitable diameter and shape for radiotherapy treatment is studied. (author)

  10. The Process for the Formulation of the International Telehealth Position Statement for Occupational Therapy

    Science.gov (United States)

    JACOBS, KAREN; CASON, JANA; MCCULLOUGH, ANN

    2015-01-01

    The World Federation of Occupational Therapists (WFOT) consists of 84 member organizations representing over 420,000 occupational therapists internationally (WFOT, 2014). In 2014, WFOT published the WFOT Telehealth Position Statement on the use of telehealth in occupational therapy. The process for the formulation of the official document involved reviewing WFOT member organizations’ telehealth position statements and data collected from a survey sent to member organizations’ delegates in April 2014. Qualitative data from 39 countries yielded factors to consider in five key areas: licensure/registration requirements, the cost of technology, privacy and security, reimbursement/payment models, and other issues (e.g., need for collaboration/transfer of knowledge, client selection, provider competencies, standard of care). The WFOT Telehealth Position Statement addressed each of these areas. The collaborative effort resulting in the development of the WFOT Telehealth Position Statement serves as a model for other international organizations. PMID:27563380

  11. Application of uti possidetis juris principle in the process of determination of international borders

    Directory of Open Access Journals (Sweden)

    Tubić Bojan

    2011-01-01

    Full Text Available Uti possidetis juris principle was basic rule in determining international borders in the period of decolonization. It was applied in Latin America and Africa, but also at the end of 20th century in the processes of dissolution of USSR, SFRY and Czechoslovakia. Uti possidetis juris principle is based on the presumption that former colonial administrative borders kept stability and territorial integrity. It was undoubtedly connected with the right of self-determination. It keeps the existing borders by preventing secession, but in that way it does not solve the problem of badly determined and disputed borders. The unclear foundations on which the borders were determined can be a source of chaos and indisputes, which was shown n some cases before the International Court of Justice. The dominant theory is that uti possidetis juris principle should be applied with certain limitations, in the period after decolonization as a basis for preserving the territorial integrity of postcolonial states.

  12. Processing covariance data for the resonance region - International Evaluation Co-operation, V. 20

    International Nuclear Information System (INIS)

    Dunn, M.; Leal, L.C.; Wiarda, D.; Jacqmin, R.; Kodeli, I.; ); Chiba, G.; Shibata, K.; Ishikawa, M.; Oh, S.; Nikolaev, M.; Kahler, A.C. Jr.; Kawano, T.; Arcilla, R.

    2014-01-01

    A Working Party on International Evaluation Co-operation (WPEC) was established under the sponsorship of the OECD/NEA Nuclear Science Committee (NSC) to promote the exchange of information on nuclear data evaluations, validation, and related topics. Its aim is also to provide a framework for co-operative activities between members of the major nuclear data evaluation projects. Requirements for experimental data resulting from this activity are compiled. The working party determines common criteria for evaluated nuclear data files with a view to assessing and improving the quality and completeness of evaluated data. The parties to the project are ENDF (United States), JEF/EFF (NEA Data Bank member countries), and JENDL (Japan). Cooperation with evaluation projects of non- OECD countries is organized through the Nuclear Data Section of the International Atomic Energy Agency (IAEA). This report summarizes the work performed by WPEC Subgroup 28 (SG28) on issues pertinent to the methodology used to process covariance data in the resonance region. Specifically, SG28 has developed the requisite processing methods needed to process resonance parameter covariance data, generate cross-section covariance data files and demonstrate the use of covariance data in radiation transport analyses. The work performed by SG28 and documented in this report addresses the following tasks: - Produce resonance parameter covariance evaluation for 235 U; - Develop resonance parameter covariance processing methods in widely used processing systems (e.g., NJOY, AMPX, etc.); - Use the updated cross-section processing systems to generate covariance data files for use in radiation transport analyses. In addition, use sensitivity/uncertainty (S/U) analyses to demonstrate the propagation of the covariance data in specific radiation transport applications

  13. Development of Metal Plate with Internal Structure Utilizing the Metal Injection Molding (MIM Process

    Directory of Open Access Journals (Sweden)

    Kwangho Shin

    2013-12-01

    Full Text Available In this study, we focus on making a double-sided metal plate with an internal structure, such as honeycomb. The stainless steel powder was used in the metal injection molding (MIM process. The preliminary studies were carried out for the measurement of the viscosity of the stainless steel feedstock and for the prediction of the filling behavior through Computer Aided Engineering (CAE simulation. PE (high density polyethylene (HDPE and low density polyethylene (LDPE and polypropylene (PP resins were used to make the sacrificed insert with a honeycomb structure using a plastic injection molding process. Additionally, these sacrificed insert parts were inserted in the metal injection mold, and the metal injection molding process was carried out to build a green part with rectangular shape. Subsequently, debinding and sintering processes were adopted to remove the sacrificed polymer insert. The insert had a suitable rigidity that was able to endure the filling pressure. The core shift analysis was conducted to predict the deformation of the insert part. The 17-4PH feedstock with a low melting temperature was applied. The glass transition temperature of the sacrificed polymer insert would be of a high grade, and this insert should be maintained during the MIM process. Through these processes, a square metal plate with a honeycomb structure was made.

  14. Sustaining a Mature Risk Management Process: Ensuring the International Space Station for a Vibrant Future

    Science.gov (United States)

    Raftery, Michael; Carter-Journet, Katrina

    2013-01-01

    The International Space Station (ISS) risk management methodology is an example of a mature and sustainable process. Risk management is a systematic approach used to proactively identify, analyze, plan, track, control, communicate, and document risks to help management make risk-informed decisions that increase the likelihood of achieving program objectives. The ISS has been operating in space for over 14 years and permanently crewed for over 12 years. It is the longest surviving habitable vehicle in low Earth orbit history. Without a mature and proven risk management plan, it would be increasingly difficult to achieve mission success throughout the life of the ISS Program. A successful risk management process must be able to adapt to a dynamic program. As ISS program-level decision processes have evolved, so too has the ISS risk management process continued to innovate, improve, and adapt. Constant adaptation of risk management tools and an ever-improving process is essential to the continued success of the ISS Program. Above all, sustained support from program management is vital to risk management continued effectiveness. Risk management is valued and stressed as an important process by the ISS Program.

  15. National cultural values and the evolution of process and outcome discrepancies in international strategic alliances

    DEFF Research Database (Denmark)

    Kumar, Rajesh; Nti, Kofi O

    2004-01-01

    The article assesses the role played by national cultural values in shaping the evolution of international strategic alliances. The authors build on a systems dynamic model of alliance evolution in which the developmental path of an alliance depends on how the partners manage process and outcome...... discrepancies that may emerge during the course of an alliance. They argue that national culture affects alliance evolution by influencing partners sensitivity to discrepancy detection , shaping the nature of attributions they make, and by affecting the partners reactions to discrepancies. They focus...

  16. Journal of Environmental Radioactivity special issue: II International Conference on Radioecological Concentration Processes. (50 years later).

    Science.gov (United States)

    Garcia-Tenorio, Rafael; Holm, Elis

    2018-06-01

    An international conference on Radioecological Concentration Processes was held in Seville, Spain, 6-9 November 2016 at the Centro Nacional de Aceleradores. It was attended by 160 participants from 35 different countries. This was the 2nd conference on this item since 1966, 50 years ago. The conference covered aspects of radiological important radionuclides on terrestrial, marine and freshwater environments and has allowed obtaining a clear picture of the status of the Radioecology as a consolidated discipline in the 21st century. Copyright © 2017 Elsevier Ltd. All rights reserved.

  17. Relationship marketing and disadvantaged health care segments: using internal marketing to improve the vocational rehabilitation process.

    Science.gov (United States)

    Peltier, James W; Scovotti, Carol

    2004-01-01

    The purpose of vocational rehabilitation (VR) is to provide disabled individuals with the training and support services needed to assimilate into the workforce. This study incorporates concepts developed in the relationship marketing and internal marketing literature to determine the factors that influence overall satisfaction of vocational training services. Results underscore the importance of social and structural bonds that develop among the multiple stakeholders involved in the VR process. Satisfaction is also influenced by the design and equipment used in the facilities and the efficiency of initiating VR services. A highly reliable instrument to measure VR participant satisfaction is presented.

  18. A review of internal combustion engine combustion chamber process studies at NASA Lewis Research Center

    Science.gov (United States)

    Schock, H. J.

    1984-01-01

    The performance of internal combustion stratified-charge engines is highly dependent on the in-cylinder fuel-air mixing processes occurring in these engines. Current research concerning the in-cylinder airflow characteristics of rotary and piston engines is presented. Results showing the output of multidimensional models, laser velocimetry measurements and the application of a holographic optical element are described. Models which simulate the four-stroke cycle and seal dynamics of rotary engines are also discussed. Previously announced in STAR as N84-24999

  19. International technology exchange in support of the Defense Waste Processing Facility wasteform production

    International Nuclear Information System (INIS)

    Kitchen, B.G.

    1989-01-01

    The nearly completed Defense Waste Processing Facility (DWPF) is a Department of Energy (DOE) facility at the Savannah River Site that is designed to immobilize defense high level radioactive waste (HLW) by vitrification in borosilicate glass and containment in stainless steel canisters suitable for storage in the future DOE HLW repository. The DWPF is expected to start cold operation later this year (1990), and will be the first full scale vitrification facility operating in the United States, and the largest in the world. The DOE has been coordinating technology transfer and exchange on issues relating to HLW treatment and disposal through bi-lateral agreements with several nations. For the nearly fifteen years of the vitrification program at Savannah River Laboratory, over two hundred exchanges have been conducted with a dozen international agencies involving about five-hundred foreign national specialists. These international exchanges have been beneficial to the DOE's waste management efforts through confirmation of the choice of the waste form, enhanced understanding of melter operating phenomena, support for paths forward in political/regulatory arenas, confirmation of costs for waste form compliance programs, and establishing the need for enhancements of melter facility designs. This paper will compare designs and schedules of the international vitrification programs, and will discuss technical areas where the exchanges have provided data that have confirmed and aided US research and development efforts, impacted the design of the DWPF and guided the planning for regulatory interaction and product acceptance

  20. Effect of Weekend Admissions on the Treatment Process and Outcomes of Internal Medicine Patients

    Science.gov (United States)

    Huang, Chun-Che; Huang, Yu-Tung; Hsu, Nin-Chieh; Chen, Jin-Shing; Yu, Chong-Jen

    2016-01-01

    Abstract Many studies address the effect of weekend admission on patient outcomes. This population-based study aimed to evaluate the relationship between weekend admission and the treatment process and outcomes of general internal medicine patients in Taiwan. A total of 82,340 patients (16,657 weekend and 65,683 weekday admissions) aged ≥20 years and admitted to the internal medicine departments of 17 medical centers between 2007 and 2009 were identified from the Taiwan National Health Insurance Research Database. A generalized estimating equation (GEE) analysis was used to compare patients admitted on weekends and those admitted on weekdays. Patients who were admitted on weekends were more likely to undergo intubation (odds ratio [OR]: 1.27; 95% confidence interval [CI]: 1.16–1.39; P internal medicine patients who were admitted on weekends experienced more intensive care procedures and higher ICU admission, in-hospital mortality, and treatment cost. Intensive care utilization may serve as early indicator of poorer outcomes and a potential entry point to offer preventive intervention before proceeding to intensive treatment. PMID:26871788

  1. Proposal of a Modelling of the Innovation Process in an International Manufacturing Company

    Directory of Open Access Journals (Sweden)

    Pauline Lacom

    2017-07-01

    Full Text Available Nowadays, to cope with the competition, and to ensure the durability of their activities, companies have to be able to innovate. Manufacturing companies operating in a B2B market often perceive innovation as a technological result. However, innovation is often more characterized as a process. The needs of the users, and not only the technology, can achieve innovation. In this context, our paper intends to determine how to involve better the users in the innovation process of an international manufacturing company, which is, according to us, representative of the current manufacturing companies. The aim of our research paper is to help manufacturing companies to manage innovation led by users, and to implement their innovation process so that they will be able to set up specific tools for each action of the process. The study proposes a diagram-based language Structured Analysis and Design Technique (SADT that is based on the normative guide FD X50-271 of the French national organization for standardization (AFNOR. The SADT model we propose usefully complements this guide, to make the innovation process more understandable, practical and operational, for manufacturing companies, which are often helpless when faced with the subject. A critical analysis of the model we propose completed in a manufacturing company through semi-structured interviews of the innovation team and questionnaire for all the employees shows the application of the model in the company.

  2. AUTOMATED PROCESS MONITORING: APPLYING PROVEN AUTOMATION TECHNIQUES TO INTERNATIONAL SAFEGUARDS NEEDS

    International Nuclear Information System (INIS)

    O'Hara, Matthew J.; Durst, Philip C.; Grate, Jay W.; Devol, Timothy A.; Egorov, Oleg; Clements, John P.

    2008-01-01

    Identification and quantification of specific alpha- and beta-emitting radionuclides in complex liquid matrices is highly challenging, and is typically accomplished through laborious wet chemical sample preparation and separations followed by analysis using a variety of detection methodologies (e.g., liquid scintillation, gas proportional counting, alpha energy analysis, mass spectrometry). Analytical results may take days or weeks to report. Chains of custody and sample security measures may also complicate or slow the analytical process. When an industrial process-scale plant requires the monitoring of specific radionuclides as an indication of the composition of its feed stream or of plant performance, radiochemical measurements must be fast, accurate, and reliable. Scientists at Pacific Northwest National Laboratory have assembled a fully automated prototype Process Monitor instrument capable of a variety of tasks: automated sampling directly from a feed stream, sample digestion/analyte redox adjustment, chemical separations, radiochemical detection and data analysis/reporting. The system is compact, its components are fluidically inter-linked, and analytical results could be immediately transmitted to on- or off-site locations. The development of a rapid radiochemical Process Monitor for 99Tc in Hanford tank waste processing streams, capable of performing several measurements per hour, will be discussed in detail. More recently, the automated platform was modified to perform measurements of 90Sr in Hanford tank waste stimulant. The system exemplifies how automation could be integrated into reprocessing facilities to support international nuclear safeguards needs

  3. Bis(PheOH) maleic acid amide-fumaric acid amide photoizomerization induces microsphere-to-gel fiber morphological transition: the photoinduced gelation system.

    Science.gov (United States)

    Frkanec, Leo; Jokić, Milan; Makarević, Janja; Wolsperger, Kristina; Zinić, Mladen

    2002-08-21

    The photoinduced gelation system based on 1 (non-gelling) to 2 (gelling) molecular photoisomerization in water results by microspheres (1) to gel fibers (2) transformation at the supramolecular level.

  4. Cultural differences and process adaptation in international R&D project management

    DEFF Research Database (Denmark)

    Li, Xing; Li, J. Z.

    2009-01-01

    In the era of globalization, Western companies have started to explore China as a source of technology. Yet, Western R&D project management processes in China are frequently facing many problems. Some of the problems can be conceptualized by analyzing a number of known cultural contrasts between ...... project success. At the same time, lessons and recommendations on the adaptability to Chinese style business and management interactions will be drawn from the case study for international companies that locate R&D projects in China.......In the era of globalization, Western companies have started to explore China as a source of technology. Yet, Western R&D project management processes in China are frequently facing many problems. Some of the problems can be conceptualized by analyzing a number of known cultural contrasts between...

  5. International

    International Nuclear Information System (INIS)

    Anon.

    1997-01-01

    This rubric reports on 10 short notes about international economical facts about nuclear power: Electricite de France (EdF) and its assistance and management contracts with Eastern Europe countries (Poland, Hungary, Bulgaria); Transnuclear Inc. company (a 100% Cogema daughter company) acquired the US Vectra Technologies company; the construction of the Khumo nuclear power plant in Northern Korea plays in favour of the reconciliation between Northern and Southern Korea; the delivery of two VVER 1000 Russian reactors to China; the enforcement of the cooperation agreement between Euratom and Argentina; Japan requested for the financing of a Russian fast breeder reactor; Russia has planned to sell a floating barge-type nuclear power plant to Indonesia; the control of the Swedish reactor vessels of Sydkraft AB company committed to Tractebel (Belgium); the renewal of the nuclear cooperation agreement between Swiss and USA; the call for bids from the Turkish TEAS electric power company for the building of the Akkuyu nuclear power plant answered by three candidates: Atomic Energy of Canada Limited (AECL), Westinghouse (US) and the French-German NPI company. (J.S.)

  6. Processing of angular motion and gravity information through an internal model.

    Science.gov (United States)

    Laurens, Jean; Straumann, Dominik; Hess, Bernhard J M

    2010-09-01

    The vestibular organs in the base of the skull provide important information about head orientation and motion in space. Previous studies have suggested that both angular velocity information from the semicircular canals and information about head orientation and translation from the otolith organs are centrally processed in an internal model of head motion, using the principles of optimal estimation. This concept has been successfully applied to model behavioral responses to classical vestibular motion paradigms. This study measured the dynamic of the vestibuloocular reflex during postrotatory tilt, tilt during the optokinetic afternystagmus, and off-vertical axis rotation. The influence of otolith signal on the VOR was systematically varied by using a series of tilt angles. We found that the time constants of responses varied almost identically as a function of gravity in these paradigms. We show that Bayesian modeling could predict the experimental results in an accurate and consistent manner. In contrast to other approaches, the Bayesian model also provides a plausible explanation of why these vestibulooculo motor responses occur as a consequence of an internal process of optimal motion estimation.

  7. Process for dissolving the radioactive corrosion products from internal surfaces in nuclear reactors

    International Nuclear Information System (INIS)

    Brown, W.W.

    1976-01-01

    This invention concerns a process for dissolving in the coolant flowing in a reactor the radioactive substances from the corrosion of the internal surfaces of the reactor to which they cling. When a reactor is operating, the fission occurring in the fuel generates gases and fission substances, such as iodine 131 and 133, cesium 134 and 137, molybdenum 99, xenon 133 and activates the structural materials of the reactor such as nickel by giving off cobalt 58 and similar substances. Under this invention an oxygen rich solution is injected in the reactor coolant after the temperature and pressure reduction stage, during the preparation prior to refuelling and repairs. The oxygen in the solution speeds up the release of cobalt 58 and other radioactive substances from the internal surfaces of the reactor and their dissolving in the oxygenated cold coolant at the start of the cooling procedures of the installation. This allows them to be removed by an ion exchanger before the reactor is emptied. By utilising this process, about half a day may be gained in refuelling time when this has to be done once a week [fr

  8. Effect of internal flow and evaporation on hydrogel assembly process at droplet interface

    Science.gov (United States)

    Kang, Giho; Seong, Baekhoon; Gim, Yeonghyeon; Ko, Han Seo; Byun, Doyoung

    2017-11-01

    Recently, controlling the behavior of nanoparticles inside liquid droplet has been widely studied. There have been many reports about the mechanism of the nanoparticles assembly and fabrication of a thin film on a substrate. However, the assembly mechanism at a liquid-air interface has not been clearly understood to form polymer chains into films. Herein, we investigated the role of internal flow on the thin film assembly process at the interface of the hydrogel droplet. The internal fluid flow during the formation of the hydrogel film was visualized systematically using micro-PIV (Particle image velocimetry) technique at various temperatures. We show that the buoyancy effect and convection flow induced by heat can affect the film morphology and its mechanical characteristics. Due to the accelerated fluid flow inside the droplet and evaporation flux, densely assembled hydrogel film was able to be formed. Film strength was increased 24% with temperature increase from 40 to 80 degrees Celsius. We expect our investigations could be applied to many applications such as self-assembly of planar structures at the interface in coating and printing process. The support from the Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education, Science and Technology (NRF-2015R1A2A1A05001829) is acknowledged.

  9. Non-Steroidal Biphenyl Gelators: Correlation of Xerogel Structure with Solid-State Structure and Circular Dichroism Spectroscopy

    Directory of Open Access Journals (Sweden)

    H. Cristina Geiger

    2018-04-01

    Full Text Available Because the factors favoring the formation of well-formed single crystals are dissimilar to those conducive to gel formation, few examples of single-crystal structural characterizations of organogelators are found in the literature. A series of biphenyl methyl and ethyl diester derivatives of varying chain length were synthesized and their gelation abilities explored. X-ray diffraction of single crystals of one of the gelators reveals a columnar extended structure. Based on XRD results for xerogels obtained from the reported organogelators, the members of the series are isostructural and so also adopt a columnar superstructure. Scanning electron microscopy (SEM was used for the investigation of the morphology of the xerogels, which display either platelet-like morphologies or more typical entangled twisted ribbon-like aggregates. The gels exhibit chirality, which depends on the sol-gel transition history, as observed by induced circular dichroism (ICD spectroscopy.

  10. Efficient Synthesis of MCu (M = Pd, Pt, and Au) Aerogels with Accelerated Gelation Kinetics and their High Electrocatalytic Activity.

    Science.gov (United States)

    Zhu, Chengzhou; Shi, Qiurong; Fu, Shaofang; Song, Junhua; Xia, Haibing; Du, Dan; Lin, Yuehe

    2016-10-01

    To accelerate hydrogel formation and further simplify the synthetic procedure, a series of MCu (M = Pd, Pt, and Au) bimetallic aerogels is synthesized from the in situ reduction of metal precursors through enhancement of the gelation kinetics at elevated temperature. Moreover, the resultant PdCu aerogel with ultrathin nanowire networks exhibits excellent electrocatalytic performance toward ethanol oxidation, holding promise in fuel-cell applications. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  11. Determination of heat-set gelation capacity of a quinoa protein isolate (Chenopodium quinoa) by dynamic oscillatory rheological analysis.

    Science.gov (United States)

    Kaspchak, Elaine; Oliveira, Marco Aurelio Schüler de; Simas, Fernanda Fogagnoli; Franco, Célia Regina Cavicchiolo; Silveira, Joana Léa Meira; Mafra, Marcos Rogério; Igarashi-Mafra, Luciana

    2017-10-01

    This work aimed to study the influence of pH (3.5 and 7.0) and CaCl 2 and MgCl 2 addition on heat-set gelation of a quinoa protein isolate at 10% and 15% (w/w). The protein isolate obtained was composed mainly of 11S globulin as was observed by electrophoresis and mass spectrometry analysis. Heat-set gelation occurred at both pH values studied. Nevertheless, the gels formed at pH 3.5 were more viscoelastic and denser than those formed at pH 7.0, that was coarser and presented syneresis. The CaCl 2 and MgCl 2 addition increased the gel strength during rheological analysis at pH 3.5, possibly due to the formation of fiber-like connections in the gel network. At pH 7.0, the divalent salts resulted in weaker gels formed by agglomerates, suggesting a neutralization of the protein surface charges. The differences in quinoa protein gelation were attributed to solubility, and the flexibility of proteins secondary structure at the pH studied. Copyright © 2017 Elsevier Ltd. All rights reserved.

  12. ic-cmtp3: 3rd International Conference on Competitive Materials and Technology Processes

    Science.gov (United States)

    2016-04-01

    Competitiveness is one of the most important factors in our lives and it plays a key role in the efficiency both of organizations and societies. The more scientifically advanced and prepared organizations develop more competitive materials with better physical, chemical, and biological properties, and the leading companies apply more competitive equipment and technological processes. The aims of the 3rd International Conference on Competitive Materials and Technology Processes (ic-cmtp3), and the 1st International Symposium on Innovative Carbons and Carbon Based Materials (is-icbm1) and the 1st International Symposium on Innovative Construction Materials (is-icm1) organized alongside are the following: —Promote new methods and results of scientific research in the fields of material, biological, environmental and technological sciences; —Exchange information between the theoretical and applied sciences as well as technical and technological implementations; —Promote communication and collaboration between the scientists, researchers and engineers of different nations, countries and continents. Among the major fields of interest are advanced and innovative materials with competitive characteristics, including mechanical, physical, chemical, biological, medical and thermal, properties and extreme dynamic strength. Their crystalline, nano - and micro-structures, phase transformations as well as details of their technological processes, tests and measurements are also in the focus of the ic-cmtp3 conference and the is-scbm1 and is-icm1 symposia. Multidisciplinary applications of material science and the technological problems encountered in sectors like ceramics, glasses, thin films, aerospace, automotive and marine industries, electronics, energy, construction materials, medicine, biosciences and environmental sciences are of particular interest. In accordance with the program of the ic-cmtp3 conference and is-icbm1 and is-icm1 symposia we have received more

  13. Evolution of International Space Station Program Safety Review Processes and Tools

    Science.gov (United States)

    Ratterman, Christian D.; Green, Collin; Guibert, Matt R.; McCracken, Kristle I.; Sang, Anthony C.; Sharpe, Matthew D.; Tollinger, Irene V.

    2013-01-01

    The International Space Station Program at NASA is constantly seeking to improve the processes and systems that support safe space operations. To that end, the ISS Program decided to upgrade their Safety and Hazard data systems with 3 goals: make safety and hazard data more accessible; better support the interconnection of different types of safety data; and increase the efficiency (and compliance) of safety-related processes. These goals are accomplished by moving data into a web-based structured data system that includes strong process support and supports integration with other information systems. Along with the data systems, ISS is evolving its submission requirements and safety process requirements to support the improved model. In contrast to existing operations (where paper processes and electronic file repositories are used for safety data management) the web-based solution provides the program with dramatically faster access to records, the ability to search for and reference specific data within records, reduced workload for hazard updates and approval, and process support including digital signatures and controlled record workflow. In addition, integration with other key data systems provides assistance with assessments of flight readiness, more efficient review and approval of operational controls and better tracking of international safety certifications. This approach will also provide new opportunities to streamline the sharing of data with ISS international partners while maintaining compliance with applicable laws and respecting restrictions on proprietary data. One goal of this paper is to outline the approach taken by the ISS Progrm to determine requirements for the new system and to devise a practical and efficient implementation strategy. From conception through implementation, ISS and NASA partners utilized a user-centered software development approach focused on user research and iterative design methods. The user-centered approach used on

  14. Investigation of the internal behavior in segmented PEMFCs of different flow fields during cold start process

    International Nuclear Information System (INIS)

    Lin, R.; Ren, Y.S.; Lin, X.W.; Jiang, Z.H.; Yang, Z.; Chang, Y.T.

    2017-01-01

    In this study, we have researched the internal behavior in segmented proton exchange membrane fuel cells (PEMFCs) with three different flow fields during cold start process. The change of internal current density and temperature in fuel cells with different flow fields could be obviously shown by the printed circuit board (PCB) technology, and the study shows that the flow field is significant for enhancing the cold start ability and durability. Single serpentine flow field has the best cold start performance, while triple channel serpentine flow field has the best uniformity. It is found that without a robust temperature rising tendency, the cell temperature reaching 0 °C does not definitely mean a successful cold start because the cell temperature might drop down 0 °C again. Polarization curves show that there is almost no performance degradation after successful cold start, but the cell degrades quickly after the failed cold start at −7 °C and −10 °C. Based on these characteristics, we optimized the rapid cold start strategy by using electric heating and make it possible to start up the PEMFC at temperatures down to −20 °C within about 11 min. - Highlights: • Segmented fuel cell were used to record the internal current density and temperature distributions during the cold start. • The effects of flow fields on the PEMFC cold start capacity were evaluated. • The effect of cold start on the performance of fuel cell was evaluated. • An optimized strategy was adopted to improve the cold start capacity.

  15. $Nb_{3}Sn macrostructure, microstructure, and property comparisons for bronze and internal Sn process strands

    CERN Document Server

    Lee, P J; Larbalestier, D C

    2000-01-01

    The variation in irreversibility field, B*(T), with temperature has been measured for Nb/sub 3/Sn superconducting strands manufactured for ITER using vibrating sample and SQUID magnetometers. The high performance strands were developed for both high transport critical current density, J/sub c/, and low hysteresis loss. Despite a wide variety of designs and components, the strands could be split into two distinctive groups, based on the extrapolated irreversibility fields, which lie about 10% lower than the upper critical field. "Bronze-process" strands exhibited consistently higher B*(T) (28 T to 31 T) compared with "internal Sn" process (24 T to 26 T) conductors. The intrinsic critical current density of the superconductor, J/sub c (sc)/, and the specific pinning force of the grain boundaries, Q/sub gb/, were evaluated using the measured J/sub c/, and image analysis of the macro- and micro-structures. A bronze-processed Nb(-Ta)/sub 3 /Sn was found to have a higher J/sub c(sc)/ but lower Q/sub gb/ than Nb/sub...

  16. International Heart Valve Bank Survey: A Review of Processing Practices and Activity Outcomes

    Science.gov (United States)

    Albrecht, Helmi; Lim, Yeong Phang; Manning, Linda

    2013-01-01

    A survey of 24 international heart valve banks was conducted to acquire information on heart valve processing techniques used and outcomes achieved. The objective was to provide an overview of heart valve banking activities for tissue bankers, tissue banking associations, and regulatory bodies worldwide. Despite similarities found for basic manufacturing processes, distinct differences in procedural details were also identified. The similarities included (1) use of sterile culture media for procedures, (2) antibiotic decontamination, (3) use of dimethyl sulfoxide (DMSO) as a cryoprotectant, (4) controlled rate freezing for cryopreservation, and (5) storage at ultralow temperatures of below −135°C. Differences in procedures included (1) type of sterile media used, (2) antibiotics combination, (3) temperature and duration used for bioburden reduction, (4) concentration of DMSO used for cryopreservation, and (5) storage duration for released allografts. For most banks, the primary reasons why allografts failed to meet release criteria were positive microbiological culture and abnormal morphology. On average, 85% of allografts meeting release criteria were implanted, with valve size and type being the main reasons why released allografts were not used clinically. The wide variation in percentage of allografts meeting release requirements, despite undergoing validated manufacturing procedures, justifies the need for regular review of important outcomes as cited in this paper, in order to encourage comparison and improvements in the HVBs' processes. PMID:24163756

  17. Degassing of primordial hydrogen and helium as the major energy source for internal terrestrial processes

    Directory of Open Access Journals (Sweden)

    Arie Lev Gilat

    2012-11-01

    Full Text Available Examples of the mightiest energy releases by great earthquakes and volcanic eruptions and hypotheses providing explanations for them are analyzed along with the results of some recently published researches and visualizations. The emerging conclusions are that the mechanism of the strong earthquake is a chemical explosion; that volcanic eruption is a special type of earthquake wherein the hypocenter rises to the earth-surface; and that there is an association between the seismic-volcanic processes and mantle “fluids” and the lack of energy for mantle plumes. A conceptual system of hypotheses is put forward to explain the conservation of energy during Earth’s accretion, its quasi-stable release by primordial H- and He-degassing and of the crucial role of the energy of degassing-comprising-reactions in endogenic processes. Specific mechanisms and chemical processes are proposed for the gas-liquid mantle plumes melting through the solid mantle using heat-energy released in reactions of their metamorphic and chemical transformation under gradual decrease of pressure and temperature; volcanic gases are put forward as energy carriers. 3He performance as a unique measuring transformer correlative to the internal heat flow was used for calculation of energy release by degassing; it equals to 5.12 × 1020 J/yr, an amount of energy five-fold greater than the entire energy loss involved in earthquake and volcanic activity. The hypotheses proposed are objectively testable.

  18. Is Sustainable Remediation Now a Self-Sustaining Process? an International Progress Report

    Science.gov (United States)

    Smith, J. W. N.

    2014-12-01

    Sustainable remediation - the consideration of environmental, social and economic factors associated with soil and groundwater risk-management options, to help select the best overall solution - has been a rapidly evolving topic in recent years. The first published reference[1] to 'sustainable remediation' was in the title of a 1999 conference paper by Kearney et al., (1999), but activity really accelerated in the middle-late 2000's, with establishment of a number of collaborative sustainable remediation groups and fora, and increased publication rates in the peer reviewed literature (Fig 1). Figure 1. Journal paper publications with search term 'sustainable remediation' (SCOPUS survey, 17 July 2014) This presentation will review the international progress of sustainable remediation concept development and application in regulatory and corporate decision-making processes. It will look back at what has already been achieved, provide an update on the latest initiatives and developments, and look forward to what the future of sustainable remediation might look like. Specifically it will describe: Sustainable remediation frameworks: synergies and international collaboration; Latest guidance and tools developed by the various sustainable remediation organisations (SuRFs), including the SuRF-UK Best Management Practices and Tier 1 Briefcase; Best practice standard development by ASTM and ISO; Regulatory acceptance of sustainable remediation, including incorporation into legislation, and the NICOLE - Common Forum Joint statement on 'risk-informed and sustainable remediation' in Europe; Examples of corporate adoption of sustainable remediation principles. The presentation will conclude with a look forward to a vision of sustainable remediation in 2020.

  19. External and internal facial features modulate processing of vertical but not horizontal spatial relations.

    Science.gov (United States)

    Meinhardt, Günter; Kurbel, David; Meinhardt-Injac, Bozana; Persike, Malte

    2018-03-22

    Some years ago an asymmetry was reported for the inversion effect for horizontal (H) and vertical (V) relational face manipulations (Goffaux & Rossion, 2007). Subsequent research examined whether a specific disruption of long-range relations underlies the H/V inversion asymmetry (Sekunova & Barton, 2008). Here, we tested how detection of changes in interocular distance (H) and eye height (V) depends on cardinal internal features and external feature surround. Results replicated the H/V inversion asymmetry. Moreover, we found very different face cue dependencies for both change types. Performance and inversion effects did not depend on the presence of other face cues for detecting H changes. In contrast, accuracy for detecting V changes strongly depended on internal and external features, showing cumulative improvement when more cues were added. Inversion effects were generally large, and larger with external feature surround. The cue independence in detecting H relational changes indicates specialized local processing tightly tuned to the eyes region, while the strong cue dependency in detecting V relational changes indicates a global mechanism of cue integration across different face regions. These findings suggest that the H/V asymmetry of the inversion effect rests on an H/V anisotropy of face cue dependency, since only the global V mechanism suffers from disruption of cue integration as the major effect of face inversion. Copyright © 2018. Published by Elsevier Ltd.

  20. Performance optimization of internal tin process multifilamentary Nb{sub 3}Sn strands

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Ke, E-mail: zhangke@c-wst.com [State Key Laboratory of Solidification Processing, Northwestern Polytechnical University, Xi’an, Shaanxi 710072 (China); Western Superconducting Technologies Co. Ltd, Xi’an, Shaanxi 710018 (China); State Engineering Lab. of Superconducting Material Preparation, Xi’an, Shaanxi 710018 (China); Zhang, Pingxiang [State Key Laboratory of Solidification Processing, Northwestern Polytechnical University, Xi’an, Shaanxi 710072 (China); Western Superconducting Technologies Co. Ltd, Xi’an, Shaanxi 710018 (China); State Engineering Lab. of Superconducting Material Preparation, Xi’an, Shaanxi 710018 (China); Northwest Institute for Non-ferrous Metal Research, Xi’an, Shaanxi 710016 (China); Shi, Yigong; Liu, Jianwei; Gao, Huixian; Li, Jianfeng; Liu, Xianghong; Feng, Yong [Western Superconducting Technologies Co. Ltd, Xi’an, Shaanxi 710018 (China); State Engineering Lab. of Superconducting Material Preparation, Xi’an, Shaanxi 710018 (China)

    2016-11-01

    Highlights: • J{sub c} increases by adding Sn cores in the interspaces, hysteresis loss increases at the same time. • Enlarger the number of filaments with the same Sn proportion will increase J{sub c} and hysteresis loss. • Cu split adopted in each sub-element leads to a low hysteresis loss. - Abstract: In this study, internal tin process Nb{sub 3}Sn strands for the International Thermo-nuclear Experimental Reactor are developed in Western Superconducting Technologies. Short cable-in-conduit conductors manufactured with these strands have been qualified. Mass production is accomplished, and all the performances of the strands meet the requirement of ITER project. Besides, more researches on the effect of strand design on critical current density and hysteresis loss for Nb{sub 3}Sn strands are carried out. It is found that critical current density can be enhanced by reducing filament diameter and increasing Sn content, and hysteresis loss of the strands can be significantly reduced through Cu split adopted in sub-element.

  1. An Assessment of the International Space Station's Trace Contaminant Control Subassembly Process Economics

    Science.gov (United States)

    Perry J. L.; Cole, H. E.; El-Lessy, H. N.

    2005-01-01

    The International Space Station (ISS) Environmental Control and Life Support System includes equipment speci.cally designed to actively remove trace chemical contamination from the cabin atmosphere. In the U.S. on-orbit segment, this function is provided by the trace contaminant control subassembly (TCCS) located in the atmosphere revitalization subsystem rack housed in the laboratory module, Destiny. The TCCS employs expendable adsorbent beds to accomplish its function leading to a potentially signi.cant life cycle cost over the life of the ISS. Because maintaining the TCCSs proper can be logistically intensive, its performance in .ight has been studied in detail to determine where savings may be achieved. Details of these studies and recommendations for improving the TCCS s process economics without compromising its performance or crew health and safety are presented and discussed.

  2. Competence evaluation process for nursing students abroad: Findings from an international Case study

    DEFF Research Database (Denmark)

    Jansen, Mette Bro

    2017-01-01

    , with between five and 88 items included. Through content analysis, 196 items emerged, classified into 12 different core competence categories, the majority were categorised as ‘Technical skills’ (=60), ‘Self-learning and critical thinking’ (=27) and ‘Nursing care process’ (=25) competences. Little emphasiswas......) were approached. Methods: Tools as instruments for evaluating competences developed in clinical training by international nursing students, and written procedures aimed at guiding the evaluation process, were scrutinised through a content analysis method. Findings: All clinical competence evaluation...... procedures and instruments used in the nursing programmes involvedwere provided in English. A final evaluation of the competenceswas expected by all nursing programmes at the end of the clinical placement, while only four provided an intermediate evaluation. Great variability emerged in the tools...

  3. THE ROLE OF THE INTERNAL AUDIT IN THE TOURISM UNIT’S RISK MANAGEMENT PROCESS

    Directory of Open Access Journals (Sweden)

    BOGDAN RĂVAŞ

    2011-01-01

    Full Text Available Management plans, organizes, and directs the performance of sufficient actions to provide reasonable assurance that objectives and goals will be achieved. Management periodically reviews its objectives and goals and modifies its processes to accommodate changes in internal and external conditions. Management also establishes and maintains an tourism unital culture, including an ethical climate that fosters control. Control is any action taken by management to enhance the likelihood that established objectives and goals will be achieved. Controls may be preventive (to determine undesirable events from occurring, detective (to detect and correct undesirable events which have occurred, or directive (to cause or encourage a desirable event to occur. The concept of a system of control is the integrated collection of control components and activities that are used by an tourism unit to achieve its objectives and goals.

  4. Simulation and Development of Internal Model Control Applications in the Bayer Process

    Science.gov (United States)

    Colombé, Ph.; Dablainville, R.; Vacarisas, J.

    Traditional PID feedback control system is limited in its use in the Bayer cycle due to the important and omnipresent time delays which can lead to stability problems and sluggish response. Advanced modern control techniques are available, but suffer in an industrial environment from a lack of simplicity and robustness. In this respect the Internal Model Control (IMC) method may be considered as an exception. After a brief review of the basic theoretical principles behind IMC, an IMC scheme is developed to work with single-input, single-output, discrete-time, nonlinear systems. Two applications of IMC in the Bayer process, both in simulations and on industrial plants, are then described: control of the caustic soda concentration of the aluminate liquor and control of the A12O3/Na20 caust. ratio of the digested slurry, Finally, the results obtained make this technique quite attractive for the alumina industry.

  5. Influence of adding Sea Spaghetti seaweed and replacing the animal fat with olive oil or a konjac gel on pork meat batter gelation. Potential protein/alginate association.

    Science.gov (United States)

    Fernández-Martín, F; López-López, I; Cofrades, S; Colmenero, F Jiménez

    2009-10-01

    Standard and modulated differential scanning calorimetry (DSC, MDSC) and dynamic rheological thermal analysis (DRTA) were used to in situ simulate the batter gelation process. Texture profile analysis (TPA) and conventional quality evaluations were applied to processed products. Sea Spaghetti seaweed addition was highly effective at reinforcing water/oil retention capacity, hardness and elastic modulus in all formulations. Olive oil substituting half pork fat yielded a presumably healthier product with slightly better characteristics than control. A konjac-starch mixed gel replacing 70% of pork fat produced a similar product to control but with nearly 10% more water. DSC revealed the currently unknown phenomenon that Sea Spaghetti alginates apparently prevented thermal denaturation of a considerable protein fraction. MDSC confirmed that this mainly concerned non-reversing effects, and displayed glass transition temperatures in the range of 55-65°C. DRTA and TPA indicated however much stronger alginate-type gels. It is tentatively postulated that salt-soluble proteins associate athermally with seaweed alginates on heating to constitute a separate phase in a thermal composite-gelling process.

  6. Coupling the Alkaline-Surfactant-Polymer Technology and The Gelation Technology to Maximize Oil Production

    Energy Technology Data Exchange (ETDEWEB)

    Malcolm Pitts; Jie Qi; Dan Wilson; Phil Dowling; David Stewart; Bill Jones

    2005-12-01

    Performance and produced polymer evaluation of four alkaline-surfactant-polymer projects concluded that only one of the projects could have benefited from combining the alkaline-surfactant-polymer and gelation technologies. Cambridge, the 1993 Daqing, Mellott Ranch, and the Wardlaw alkaline-surfacant-polymer floods were studied. An initial gel treatment followed by an alkaline-surfactant-polymer flood in the Wardlaw field would have been a benefit due to reduction of fracture flow. Numerical simulation demonstrated that reducing the permeability of a high permeability zone of a reservoir with gel improved both waterflood and alkaline-surfactant-polymer flood oil recovery. A Minnelusa reservoir with both A and B sand production was simulated. A and B sands are separated by a shale layer. A sand and B sand waterflood oil recovery was improved by 196,000 bbls or 3.3% OOIP when a gel was placed in the B sand. Alkaline-surfactant-polymer flood oil recovery improvement over a waterflood was 392,000 bbls or 6.5% OOIP. Placing a gel into the B sand prior to an alkaline-surfactant-polymer flood resulted in 989,000 bbl or 16.4% OOIP more oil than only water injection. A sand and B sand alkaline-surfactant-polymer flood oil recovery was improved by 596,000 bbls or 9.9% OOIP when a gel was placed in the B sand.

  7. Encapsulating anthocyanins from Hibiscus sabdariffa L. calyces by ionic gelation: Pigment stability during storage of microparticles.

    Science.gov (United States)

    de Moura, Sílvia C S R; Berling, Carolina L; Germer, Sílvia P M; Alvim, Izabela D; Hubinger, Míriam D

    2018-02-15

    Hibiscus extract (HE) has a strong antioxidant activity and high anthocyanin content; it can be used as a natural pigment, also adding potential health benefits. The objective of this work was the microencapsulation of HE anthocyanin by ionic gelation (IG) using two techniques: dripping-extrusion and atomization, both by means of a double emulsion (HE/rapseed oil/pectin) and a cross-linked solution (CaCl 2 ). Particles (77-83% moisture content) were conditioned in acidified solution at 5, 15 and 25°C, absence of light, and evaluated for anthocyanins and color for 50-days. The median diameter (D 50 ) of the particles ranged from 78 to 1100μm and encapsulation efficiency ranged from 67.9 to 93.9%. The encapsulation caused higher temperature stability compared with the free extract. The half-life (t 1/2 ) values of the particles ranged from 7 (25°C) to 180days (5°C) for anthocyanins and from 25 (25°C) to 462days (5°C) for Chroma value. The IG increased the stability of HE anthocyanin. Both the dripping-extrusion and the atomization have shown to be feasible techniques. Copyright © 2017 Elsevier Ltd. All rights reserved.

  8. Nanoparticle and gelation stabilized functional composites of an ionic salt in a hydrophobic polymer matrix.

    Directory of Open Access Journals (Sweden)

    Selin Kanyas

    Full Text Available Polymer composites consisted of small hydrophilic pockets homogeneously dispersed in a hydrophobic polymer matrix are important in many applications where controlled release of the functional agent from the hydrophilic phase is needed. As an example, a release of biomolecules or drugs from therapeutic formulations or release of salt in anti-icing application can be mentioned. Here, we report a method for preparation of such a composite material consisted of small KCOOH salt pockets distributed in the styrene-butadiene-styrene (SBS polymer matrix and demonstrate its effectiveness in anti-icing coatings. The mixtures of the aqueous KCOOH and SBS-cyclohexane solutions were firstly stabilized by adding silica nanoparticles to the emulsions and, even more, by gelation of the aqueous phase by agarose. The emulsions were observed in optical microscope to check its stability in time and characterized by rheological measurements. The dry composite materials were obtained via casting the emulsions onto the glass substrates and evaporations of the organic solvent. Composite polymer films were characterized by water contact angle (WCA measurements. The release of KCOOH salt into water and the freezing delay experiments of water droplets on dry composite films demonstrated their anti-icing properties. It has been concluded that hydrophobic and thermoplastic SBS polymer allows incorporation of the hydrophilic pockets/phases through our technique that opens the possibility for controlled delivering of anti-icing agents from the composite.

  9. Production and characterization of nanocapsules encapsulated linalool by ionic gelation method using chitosan as wall material

    Directory of Open Access Journals (Sweden)

    Zuobing XIAO

    Full Text Available Abstract Linalool has been extensively applied in various fields, such as flavoring agent, perfumes, cosmetics and medical science. However, linalool is unstable, volatile and readily oxidizable. A sensitive substance can be encapsulated in a capsule, so encapsulation technology can solve these problems. In this paper, linalool-loaded nanocapsules (Lin-nanocapsules were prepared via the ionic gelation method and Lin-nanocapsules were characterized. The results of Fourier transformation infrared spectroscopy (FTIR showed that linalool was successfully encapsulated in the wall materials. Scanning electron microscopy (SEM results demonstrated that the shapes of Lin-nanocapsules, with smooth surfaces, were nearly spherical. Lin-nanocapsule average particle size was 352 nm and its polydispersity index (PDI was proved to be 0.214 by the results of dynamic light scattering (DLC. Thermogravimetric results indicated that linalool loading capacity (LC was 15.17%, and encapsulation could decrease linalool release and increase linalool retaining time under the high temperature. Oscillatory shear and steady-state shear measurements of Lin-nanocapsule emulsions were systematically investigated. The results of steady-state shear showed that Lin-nanocapsule emulsion, which was Newtonian only for high shear rate, was non-Newtonian. It was proved by oscillatory shear that when oscillation frequency changed from low to high, Lin-nanocapsules emulsion changed from viscous into elastic.

  10. Combined effects of presalted prerigor and postrigor batter mixtures on chicken breast gelation.

    Science.gov (United States)

    Choi, Yun-Sang; Kim, Hyun-Wook; Hwang, Ko-Eun; Song, Dong-Hun; Jeong, Tae-Jun; Jeon, Ki-Hong; Kim, Young-Boong; Kim, Cheon-Jei

    2015-04-01

    We examined the combined effects of prerigor and postrigor batter mixtures on protein gelation. The postrigor batter was prepared with 2% salt, whereas the prerigor meat at 5 min postmortem was used to prepare postrigor batters at different salt levels. For 5 treatments, prerigor batters were mixed with postrigor batter that had 2% salt (control) as follows: T1: ground presalted (1%) hot-boned breast with 1% salt for 50% total batch; T2: ground presalted (2%) hot-boned breast for 50% total batch; T3: ground presalted (3%) hot-boned breast for 30% total batch that was mixed with cold-boned batter for 50% total batch; T4: ground presalted (4%) hot-boned breast for 25% total batch that was mixed with cold-boned batter for 50% total batch; and T5: ground presalted (5%) hot-boned breast for 20% total batch that was mixed with cold-boned batter for 50% total batch. Treatments with both presalted prerigor and postrigor muscle showed less cooking loss and lower emulsion stability than the control, except T5. The protein solubility and apparent viscosity of the control was the lowest. Thus, presalted hot-boned muscle combined with cold-boned muscle positively affected physicochemical properties. © 2015 Poultry Science Association Inc.

  11. DSC and TMA studies on freezing and thawing gelation of galactomannan polysaccharide

    International Nuclear Information System (INIS)

    Iijima, Mika; Hatakeyama, Tatsuko; Hatakeyama, Hyoe

    2012-01-01

    Research highlights: ► Locust bean gum forms hydrogels by freezing and thawing. ► Syneresis was observed when freezing and thawing cycle (n) increased. ► Dynamic Young's modulus increased with increasing n. ► Non-freezing water content restrained by hydrogels decreased with increasing n. ► Strong gel with densely packed network structure formed with increasing n. - Abstract: Among various kinds of polysaccharides known to form hydrogels, locust bean gum (LBG) consisting of a mannose backbone and galactose side chains has unique characteristics, since LBG forms hydrogels by freezing and thawing. In this study, effect of thermal history on gelation was investigated by differential scanning calorimetry (DSC) and thermomechanical analysis (TMA). Gel/sol ratio calculated by weighing method was found to be affected by sol concentration, freezing rate and the number of freezing and thawing cycle (n). Once LBG hydrogels are formed, they are thermally stable, although syneresis was observed when n increased. Dynamic Young's modulus (E′) of hydrogels measured by TMA in water increased with increasing n and decreasing freezing rate. Non-freezing water calculated from DSC melting peak of ice in the gel decreased with increasing n and decreasing freezing rate. Morphological observation of freeze-dried gels was carried out by scanning electron microscopy (SEM). The above results indicate that weak hydrogel having large molecular network structure transformed into strong gel with densely packed network structure by increasing n and decreasing freezing rate.

  12. Gelation in a model 1-component system with adhesive hard-sphere interactions

    Science.gov (United States)

    Kim, Jung Min; Eberle, Aaron; Fang, Jun; Wagner, Norman

    2012-02-01

    Colloidal dispersions can undergo a dynamical arrest of the disperse phase leading to a system with solid-like properties when either the volume fraction or the interparticle potential is varied. Systems that contain low to moderate particulate concentrations form gels whereas higher concentrations lead to glassy states in which caging by nearest neighbors can be a significant contributor to the arrested long-time dynamics. Colloid polymer mixtures have been the prevalent model system for studying the effect of attraction, where attractions are entropically driven by depletion effects, in which gelation has been shown to be a result of phase separation [1]. Using the model 1-component octadecyl coated silica nanoparticle system, Eberle et al. [2] found the gel-line to intersect the spinodal to the left of the critical point, and at higher concentrations extended toward the mode coupling theory attractive driven glass line. . We continue this study by varying the particle diameter and find quantitative differences which we explain by gravity. 1. Lu, P.J., et al., Nature, 2008. 453(7194): p. 499-504.2. Eberle, A.P.R., N.J. Wagner, and R. Castaneda-Priego, Physical Review Letters, 2011. 106(10).

  13. PREFACE: 6th International Workshop on Multi-Rate Processes and Hysteresis (MURPHYS2012)

    Science.gov (United States)

    Dimian, Mihai; Rachinskii, Dmitrii

    2015-02-01

    The International Workshop on Multi-Rate Processes and Hysteresis (MURPHYS) conference series focuses on multiple scale systems, singular perturbation problems, phase transitions and hysteresis phenomena occurring in physical, biological, chemical, economical, engineering and information systems. The 6th edition was hosted by Stefan cel Mare University in the city of Suceava located in the beautiful multicultural land of Bukovina, Romania, from May 21 to 24, 2012. This continued the series of biennial multidisciplinary conferences organized in Cork, Ireland from 2002 to 2008 and in Pécs, Hungary in 2010. The MURPHYS 2012 Workshop brought together more than 50 researchers in hysteresis and multi-scale phenomena from the United State of America, the United Kingdom, France, Germany, Italy, Ireland, Czech Republic, Hungary, Greece, Ukraine, and Romania. Participants shared and discussed new developments of analytical techniques and numerical methods along with a variety of their applications in various areas, including material sciences, electrical and electronics engineering, mechanical engineering and civil structures, biological and eco-systems, economics and finance. The Workshop was sponsored by the European Social Fund through Sectoral Operational Program Human Resources 2007-2013 (PRO-DOCT) and Stefan cel Mare University, Suceava. The Organizing Committee was co-chaired by Mihai Dimian from Stefan cel Mare University, Suceava (Romania), Amalia Ivanyi from the University of Pecs (Hungary), and Dmitrii Rachinskii from the University College Cork (Ireland). All papers published in this volume of Journal of Physics: Conference Series have been peer reviewed through processes administered by the Editors. Reviews were conducted by expert referees to the professional and scientific standards expected of a proceedings journal published by IOP Publishing. The Guest Editors wish to place on record their sincere gratitude to Miss Sarah Toms for the assistance she provided

  14. Investigation of gas-phase decontamination of internally radioactively contaminated gaseous diffusion process equipment and piping

    International Nuclear Information System (INIS)

    Bundy, R.D.; Munday, E.B.

    1991-01-01

    Construction of the gaseous diffusion plants (GDPs) was begun during World War 2 to produce enriched uranium for defense purposes. These plants, which utilized UF 6 gas, were used primarily for this purpose through 1964. From 1959 through 1968, production shifted primarily to uranium enrichment to supply the nuclear power industry. Additional UF 6 -handling facilities were built in feed and fuel-processing plants associated with the uranium enrichment process. Two of the five process buildings at Oak ridge were shut down in 1964. Uranium enrichment activities at Oak Ridge were discontinued altogether in 1985. In 1987, the Department of Energy (DOE) decided to proceed with a permanent shutdown of the Oak Ridge Gaseous Diffusion Plant (ORGDP). DOE intends to begin decommissioning and decontamination (D ampersand D) of ORGDP early in the next century. The remaining two GDPs are expected to be shut down during the next 10 to 40 years and will also require D ampersand D, as will the other UF 6 -handling facilities. This paper presents an investigation of gas- phase decontamination of internally radioactively contaminated gaseous diffusion process equipment and piping using powerful fluorinating reagents that convert nonvolatile uranium compounds to volatile UF 6 . These reagents include ClF 3 , F 2 , and other compounds. The scope of D ampersand D at the GDPs, previous work of gas-phase decontamination, four concepts for using gas-phase decontamination, plans for further study of gas-phase decontamination, and the current status of this work are discussed. 13 refs., 15 figs

  15. Students' perceptions of the admissions process for a program for internationally-trained dentists

    Science.gov (United States)

    King, Patricia Ann

    This study is designed to analyze the students' perceptions of the application process for a foreign-trained dental program. The goal was to add to the knowledge base the views of students who have experienced the application process of this type of program. Using a quantitative approach, the method of data collection was through a link to an online Likert survey which was emailed to graduates, first-year and second-year current students of the International Dental Studies (IDS) program at the University of the Pacific Arthur A. Dugoni School of Dentistry. Respondents were students who had experienced the IDS application process and had been accepted into the program. The study identified three topics: background, motivation and perception of fairness. The background information identified whether the participant was male/female and whether they were a current first-/second-year student or a graduate of the program. Motivation for applying was identified through questions about knowing someone who was in or had completed the program, and/or applied because of the program's reputation. Perception of fairness was determined by asking how the student felt about each required element of the process. By using structure based upon construct, which provides the researcher with a methodical review and configuration of the information, the study found that students had some views about application elements that, at times, conflicted with school's requirements. However, in general, the students felt the school was requiring the right elements for their application and were, therefore, basing their acceptance decisions on the correct requisites.

  16. International workshop on site investigation and evaluation based on the siting process in Sweden

    International Nuclear Information System (INIS)

    Andersson, Johan; Stroem, A.

    2001-06-01

    SKB's goal is to commence surface based site investigations in 2002. Extensive preparations are now being made for this transition to the next phase in the siting process for the deep repository for spent nuclear fuel. The purpose of the international workshop on site characterisation held at Aespoe April 2001 was to: present the SKB site investigation and evaluation programme to a group of international experts; discuss whether the available toolbox of investigation methods for surface based site investigations is appropriate and state-of-the-art in an international perspective; and by working group sessions discuss the level of ambition in the programme for site investigation for each discipline. This report summarises the conclusions of the workshop in general terms. Many of the detailed comments and ideas obtained at the workshop have already inspired and will also directly inspire the on-going planning work for site characterisation. The core activity at the workshop was the work performed by working groups. They addressed what should be considered for a site characterisation programme, based on the generic planning made so far by SKB. The working groups also outlined site specific characterisation programmes for the sites suggested by SKB. The tasks were strictly confined to technical and scientific modelling issues. The working group chairmen presented the working group results at the workshop and have also submitted short memos to SKB. The present document is a compilation of these memos. The SKB generic programme as presented in the existing top level documents, 'Requirements and Criteria and Overall Programme', received general endorsement and was appreciated for being comprehensive and systematic. For example, it contains comprehensive lists of parameters to be measured. However, there is need for prioritisation and sequencing. This is actually included in the current planning process at SKB where the generic programme later this year will be adapted to

  17. International Scientific Conference on 'Radiation-Thermal Effects and Processes in Inorganic Materials'

    International Nuclear Information System (INIS)

    2015-01-01

    The International Scientific Conference on 'Radiation-Thermal Effects and Processes in Inorganic Materials' is a traditional representative forum devoted to the discussion of fundamental problems of radiation physics and its technical applications. The first nine conferences were held four times in Tomsk, then in Ulan-Ude (Russia), Bishkek (Kyrgyzstan), Tashkent (Uzbekistan), Sharm El Sheikh (Egypt), and the island of Cyprus. The tenth conference was held in Tomsk, Russia. The program of the Conference covers a wide range of technical areas and modern aspects of radiation physics, its applications and related matters. Topics of interest include, but are not limited to: • Physical and chemical phenomena in inorganic materials in radiation, electrical and thermal fields; • Research methods and equipment modification states and properties of materials; • Technologies and equipment for their implementation; • The use of radiation-thermal processes in nanotechnology; • Adjacent to the main theme of the conference issues The conference was attended by leading scientists from countries near and far abroad who work in the field of radiation physics of solid state and of radiation material science. The School-Conference of Young Scientists was held during the conference. The event was held with the financial support of the Russian Foundation for Basic Research, projects № 14-38-10210 and № 14-02-20376. (introduction)

  18. Improving Knowledge and Process for International Emergency Medicine Fellowship Applicants: A Call for a Uniform Application

    Directory of Open Access Journals (Sweden)

    Gabrielle A. Jacquet

    2013-01-01

    Full Text Available Background. There are currently 34 International Emergency Medicine (IEM fellowship programs. Applicants and programs are increasing in number and diversity. Without a standardized application, applicants have a difficulty approaching programs in an informed and an organized method; a streamlined application system is necessary. Objectives. To measure fellows’ knowledge of their programs’ curricula prior to starting fellowship and to determine what percent of fellows and program directors would support a universal application system. Methods. A focus group of program directors, recent, and current fellows convened to determine the most important features of an IEM fellowship application process. A survey was administered electronically to a convenience sample of 78 participants from 34 programs. Respondents included fellowship directors, fellows, and recent graduates. Results. Most fellows (70% did not know their program’s curriculum prior to starting fellowship. The majority of program directors and fellows support a uniform application service (81% and 67%, resp. and deadline (85% for both. A minority of program directors (35% and fellows (30% support a formal match. Conclusions. Program directors and fellows support a uniform application service and deadline, but not a formalized match. Forums for disseminating IEM fellowship information and for administering a uniform application service and deadline are currently in development to improve the process.

  19. The internal and external customer focused process improvement and the performance analysis studies in healthcare systems

    Directory of Open Access Journals (Sweden)

    Piril Tekin

    2017-07-01

    Full Text Available Purpose: The main contribution of this paper is to generate an optimum solution for capacity planning and appointment scheduling issues, which are frequently encountered in clinical flows with various route and treatment periods at dental hospitals. Design/methodology/approach: It is essential to define the system well in order to ensure that the working staff and patients use their time very efficiently and that the process flows continuously. By having examined a sample healthcare system through the help of a study addressed in such context, studies on process improvement in line with the dissatisfactions of the working staff and patients have been carried out. Within the scope of the study, the operation of 7 Departments in a dental hospital undergoing a treatment process have been reviewed and examined. The problems encountered as result of the observations made are discussed in detail, and formerly and recently designed system performance analyses are conducted by having performed the respective process improvement studies. The relevant samplings of this study are modeled via the Arena Simulation Program. The data of the previous four months is used in the parameters, which are used through the modellings. The system data are entered by taking into account seasonal characteristics of the data. Findings: The analyses are made as a consequence of such study that has been addressed, it is established that the efficiency of the internal customers of the hospital increases substantially, and that the waiting durations of the dental patients decrease and in turn, the external customer satisfaction increases drastically. Research limitations/implications: Under the scope of the present study, 7 different treatment processes are analysed in a dental hospital in Cukurova Region with a significant patient potential. The treatment clinics present in the hospital are radiology, periodontology, surgery, treatment, orthodontics and prosthesis. These

  20. PREFACE: 3rd International Workshop on Materials Analysis and Processing in Magnetic Fields (MAP3)

    Science.gov (United States)

    Sakka, Yoshio; Hirota, Noriyuki; Horii, Shigeru; Ando, Tsutomu

    2009-07-01

    The 3rd International Workshop on Materials Analysis and Processing in Materials Fields (MAP3) was held on 14-16 May 2008 at the University of Tokyo, Japan. The first was held in March 2004 at the National High Magnetic Field Laboratory in Tallahassee, USA. Two years later the second took place in Grenoble, France. MAP3 was held at The University of Tokyo International Symposium, and jointly with MANA Workshop on Materials Processing by External Stimulation, and JSPS CORE Program of Construction of the World Center on Electromagnetic Processing of Materials. At the end of MAP3 it was decided that the next MAP4 will be held in Atlanta, USA in 2010. Processing in magnetic fields is a rapidly expanding research area with a wide range of promising applications in materials science. MAP3 focused on the magnetic field interactions involved in the study and processing of materials in all disciplines ranging from physics to chemistry and biology: Magnetic field effects on chemical, physical, and biological phenomena Magnetic field effects on electrochemical phenomena Magnetic field effects on thermodynamic phenomena Magnetic field effects on hydrodynamic phenomena Magnetic field effects on crystal growth Magnetic processing of materials Diamagnetic levitation Magneto-Archimedes effect Spin chemistry Application of magnetic fields to analytical chemistry Magnetic orientation Control of structure by magnetic fields Magnetic separation and purification Magnetic field-induced phase transitions Materials properties in high magnetic fields Development of NMR and MRI Medical application of magnetic fields Novel magnetic phenomena Physical property measurement by Magnetic fields High magnetic field generation> MAP3 consisted of 84 presentations including 16 invited talks. This volume of Journal of Physics: Conference Series contains the proceeding of MAP3 with 34 papers that provide a scientific record of the topics covered by the conference with the special topics (13 papers) in

  1. Introduction to the First International Workshop on Process-Oriented Information Systems in Healthcare (ProHealth 2007)

    NARCIS (Netherlands)

    Reichert, Manfred; Peleg, Mor; Lenz, Richard

    2007-01-01

    The proHealth’07 workshop is held in Brisbane in conjunction with the fifth international conference on business process management. ProHealth’07 elaborates both the potential and the limitations of IT support for healthcare processes. It further provides a forum wherein challenges, paradigms, and

  2. PREFACE: 2nd International Conference on Competitive Materials and Technological Processes (IC-CMTP2)

    Science.gov (United States)

    László, Gömze A.

    2013-12-01

    Competitiveness is one of the most important factors in our life and it plays a key role in the efficiency both of organizations and societies. The more scientifically supported and prepared organizations develop more competitive materials with better physical, chemical and biological properties and the leading companies apply more competitive equipment and technology processes. The aims of the 2nd International Conference on Competitive Materials and Technology Processes (ic-cmtp2) are the following: Promote new methods and results of scientific research in the fields of material, biological, environmental and technology sciences; Change information between the theoretical and applied sciences as well as technical and technological implantations. Promote the communication between the scientist of different nations, countries and continents. Among the major fields of interest are materials with extreme physical, chemical, biological, medical, thermal, mechanical properties and dynamic strength; including their crystalline and nano-structures, phase transformations as well as methods of their technological processes, tests and measurements. Multidisciplinary applications of materials science and technological problems encountered in sectors like ceramics, glasses, thin films, aerospace, automotive and marine industry, electronics, energy, construction materials, medicine, biosciences and environmental sciences are of particular interest. In accordance to the program of the conference ic-cmtp2, more than 250 inquiries and registrations from different organizations were received. Researchers from 36 countries in Asia, Europe, Africa, North and South America arrived at the venue of conference. Including co-authors, the research work of more than 500 scientists are presented in this volume. Professor Dr Gömze A László Chair, ic-cmtp2 The PDF also contains lists of the boards, session chairs and sponsors.

  3. Poleward propagation of boreal summer intraseasonal oscillations in a coupled model: role of internal processes

    Energy Technology Data Exchange (ETDEWEB)

    Ajayamohan, R.S. [University of Victoria, Canadian Centre for Climate Modelling and Analysis, P.O. Box 3065, Victoria, BC (Canada); Annamalai, H.; Hafner, Jan [University of Hawaii, International Pacific Research Center, Honolulu (United States); Luo, Jing-Jia [Japan Agency for Marine-Earth Science and Technology, Frontier Research Centre for Global Change, Yokohama (Japan); Yamagata, Toshio [Japan Agency for Marine-Earth Science and Technology, Frontier Research Centre for Global Change, Yokohama (Japan); The University of Tokyo, Department of Earth and Planetary Science, Tokyo (Japan)

    2011-09-15

    The study compares the simulated poleward migration characteristics of boreal summer intraseasonal oscillations (BSISO) in a suite of coupled ocean-atmospheric model sensitivity integrations. The sensitivity experiments are designed in such a manner to allow full coupling in specific ocean basins but forced by temporally varying monthly climatological sea surface temperature (SST) adopted from the fully coupled model control runs (ES10). While the local air-sea interaction is suppressed in the tropical Indian Ocean and allowed in the other oceans in the ESdI run, it is suppressed in the tropical Pacific and allowed in the other oceans in the ESdP run. Our diagnostics show that the basic mean state in precipitation and easterly vertical shear as well as the BSISO properties remain unchanged due to either inclusion or exclusion of local air-sea interaction. In the presence of realistic easterly vertical shear, the continuous emanation of Rossby waves from the equatorial convection is trapped over the monsoon region that enables the poleward propagation of BSISO anomalies in all the model sensitivity experiments. To explore the internal processes that maintain the tropospheric moisture anomalies ahead of BSISO precipitation anomalies, moisture and moist static energy budgets are performed. In all model experiments, advection of anomalous moisture by climatological winds anchors the moisture anomalies that in turn promote the northward migration of BSISO precipitation. While the results indicate the need for realistic simulation of all aspects of the basic state, our model results need to be taken with caution because in the ECHAM family of coupled models the internal variance at intraseasonal timescales is indeed very high, and therefore local air-sea interactions may not play a pivotal role. (orig.)

  4. Developing expertise in gynecologic surgery: reflective perspectives of international experts on learning environments and processes

    Directory of Open Access Journals (Sweden)

    Hardre PL

    2017-01-01

    Full Text Available Patricia L Hardré,1 Mikio Nihira,2 Edgar L LeClaire3 1Department of Educational Psychology, University of Oklahoma College of Education, Norman, 2Department of Obstetrics and Gynecology, University of Oklahoma College of Medicine, Oklahoma City, OK, 3Department of Obstetrics and Gynecology, University of Kansas College of Medicine, Kansas City, KS, USA Abstract: Research in medical education does not provide a clear understanding of how professional expertise develops among surgeons and what experiential factors contribute to that development. To address this gap, the researchers interviewed 16 international experts in female pelvic medicine and reconstructive surgery to assess their reflective perceptions of what specific opportunities and experiences initiated and supported their development toward expertise in their field. Characteristics and influences explaining the speed and quality of expertise development were sorted into the following themes: the dynamic process of expertise development, internal and personal characteristics, general aptitudes and preparatory skills, role modeling and interpersonal influences, opportunities to learn and practice, and roles and reference points. Across the narratives and perspectives of these expert surgeons, both individual characteristics and choices, and contextual activities and opportunities were necessary and important. Experiences with greatest impact on quality of expertise development included those provided by the environment and mentors, as well as those sought out by learners themselves, to elaborate and supplement existing opportunities. The ideal combination across experts was interaction and integration of individual characteristics with experiential opportunities. Grounded in theory and research in expertise development, these findings can support improvement of medical education, both for individual mentors and strategic program development. As surgery evolves at a continuously

  5. Intragastric Gelation of Heated Soy Protein Isolate-Alginate Mixtures and Its Effect on Sucrose Release.

    Science.gov (United States)

    Huang, Zhaozhi; Gruen, Ingolf; Vardhanabhuti, Bongkosh

    2018-06-15

    The goal of our study was to investigate the effect of alginate on in vitro gastric digestion and sucrose release of soy protein isolate (SPI) in model beverages. Model beverages containing 5% w/w SPI, 0% to 0.20% w/w alginate, and 10% w/w sucrose were prepared by heating the mixtures at 85 °C for 30 min at pH 6.0 or 7.0. Characterizations of beverages included determination of zeta potential, particle size and rheological properties. Digestion patterns and sucrose release profiles were determined during 2 hr in vitro gastric digestion using SDS-PAGE and HPLC analysis, respectively. Increasing alginate concentration led to increased negative surface charge, particle size, as well as viscosity and pseudoplastic behavior; however, no phase separation was observed. SPI beverages formed intragastric gel during in vitro gastric digestion when the formulations contained alginate or at pH 6.0 without alginate. Formation of the intragastric gel led to delayed protein digestion and release of sucrose. Higher resistance to digestion and a slower sucrose release rate were exhibited at increased alginate concentration, and to a lesser extent, at pH 6.0. This suggests that electrostatic interaction between SPI and alginate that occurred when the beverages were under gastric condition could be responsible for the intragastric gelation. These results could potentially lead to the formulation of SPI beverages with functionality to lower postprandial glycemic response. The results could be used to design beverages or semi solid food products with altered digestion properties and lowered or slower glucose release. © 2018 Institute of Food Technologists®.

  6. COUPLING THE ALKALINE-SURFACTANT-POLYMER TECHNOLOGY AND THE GELATION TECHNOLOGY TO MAXIMIZE OIL PRODUCTION

    Energy Technology Data Exchange (ETDEWEB)

    Malcolm Pitts; Jie Qui; Dan Wilson; Phil Dowling

    2004-05-01

    Gelation technologies have been developed to provide more efficient vertical sweep efficiencies for flooding naturally fractured oil reservoirs or more efficient areal sweep efficiency those with high permeability contrast ''thief zones''. The field proven alkaline-surfactant-polymer technology economically recovers 15% to 25% OOIP more oil than waterflooding in the swept pore space of an oil reservoir. However, alkaline-surfactant-polymer technology is not amenable to the naturally fractured reservoirs or those with thief zones because much of the injected solution bypasses the target pore space containing oil. The objective of this work is to investigate whether combining these two technologies could broaden the applicability of alkaline-surfactant-polymer flooding into these reservoirs. Fluid-fluid interaction with different gel chemical compositions and alkaline-surfactant-polymer solution with pH values ranging from 9.2 to 12.9 have been tested. Aluminum-polyacrylamide gels are not stable to alkaline-surfactant-polymer solutions at any pH. Chromium--polyacrylamide gels with polymer to chromium ion ratios of 25 or greater were stable to alkaline-surfactant-polymer solutions if solution pH was 10.6 or less. When the polymer to chromium ion was 15 or less, chromium-polyacrylamide gels were stable to alkaline-surfactant-polymer solutions with pH values up to 12.9. Chromium-xanthan gum gels were stable to alkaline-surfactant-polymer solutions with pH values of 12.9 at the polymer to chromium ion ratios tested. Silicate-polyacrylamide, resorcinol-formaldehyde, and sulfomethylated resorcinol-formaldehyde gels were also stable to alkaline-surfactant-polymer solutions with pH values ranging from 9.2 to 12.9. Iron-polyacrylamide gels were immediately destroyed when contacted with any of the alkaline-surfactant-polymer solutions with pH values of 9.2 to 12.9.

  7. COUPLING THE ALKALINE-SURFACTANT-POLYMER TECHNOLOGY AND THE GELATION TECHNOLOGY TO MAXIMIZE OIL PRODUCTION

    Energy Technology Data Exchange (ETDEWEB)

    Malcolm Pitts; Jie Qi; Dan Wilson

    2004-10-01

    Gelation technologies have been developed to provide more efficient vertical sweep efficiencies for flooding naturally fractured oil reservoirs or more efficient areal sweep efficiency for those with high permeability contrast ''thief zones''. The field proven alkaline-surfactant-polymer technology economically recovers 15% to 25% OOIP more oil than waterflooding from swept pore space of an oil reservoir. However, alkaline-surfactant-polymer technology is not amenable to naturally fractured reservoirs or those with thief zones because much of injected solution bypasses target pore space containing oil. This work investigates whether combining these two technologies could broaden applicability of alkaline-surfactant-polymer flooding into these reservoirs. A prior fluid-fluid report discussed interaction of different gel chemical compositions and alkaline-surfactant-polymer solutions. Gel solutions under dynamic conditions of linear corefloods showed similar stability to alkaline-surfactant-polymer solutions as in the fluid-fluid analyses. Aluminum-polyacrylamide, flowing gels are not stable to alkaline-surfactant-polymer solutions of either pH 10.5 or 12.9. Chromium acetate-polyacrylamide flowing and rigid flowing gels are stable to subsequent alkaline-surfactant-polymer solution injection. Rigid flowing chromium acetate-polyacrylamide gels maintained permeability reduction better than flowing chromium acetate-polyacrylamide gels. Silicate-polyacrylamide gels are not stable with subsequent injection of either a pH 10.5 or a 12.9 alkaline-surfactant-polymer solution. Neither aluminum citrate-polyacrylamide nor silicate-polyacrylamide gel systems produced significant incremental oil in linear corefloods. Both flowing and rigid flowing chromium acetate-polyacrylamide gels produced incremental oil with the rigid flowing gel producing the greatest amount. Higher oil recovery could have been due to higher differential pressures across cores. None of

  8. Comparing and correlating solubility parameters governing the self-assembly of molecular gels using 1,3:2,4-dibenzylidene sorbitol as the gelator.

    Science.gov (United States)

    Lan, Yaqi; Corradini, Maria G; Liu, Xia; May, Tim E; Borondics, Ferenc; Weiss, Richard G; Rogers, Michael A

    2014-12-02

    Solvent properties play a central role in mediating the aggregation and self-assembly of molecular gelators and their growth into fibers. Numerous attempts have been made to correlate the solubility parameters of solvents and gelation abilities of molecular gelators, but a comprehensive comparison of the most important parameters has yet to appear. Here, the degree to which partition coefficients (log P), Henry's law constants (HLC), dipole moments, static relative permittivities (ε(r)), solvatochromic E(T)(30) parameters, Kamlet-Taft parameters (β, α, and π), Catalan's solvatochromic parameters (SPP, SB, and SA), Hildebrand solubility parameters (δ(i)), and Hansen solubility parameters (δ(p), δ(d), δ(h)) and the associated Hansen distance (R(ij)) of 62 solvents (covering a wide range of properties) can be correlated with the self-assembly and gelation of 1,3:2,4-dibenzylidene sorbitol (DBS) gelation, a classic molecular gelator, is assessed systematically. The approach presented describes the basis for each of the parameters and how it can be applied. As such, it is an instructional blueprint for how to assess the appropriate type of solvent parameter for use with other molecular gelators as well as with molecules forming other types of self-assembled materials. The results also reveal several important insights into the factors favoring the gelation of solvents by DBS. The ability of a solvent to accept or donate a hydrogen bond is much more important than solvent polarity in determining whether mixtures with DBS become solutions, clear gels, or opaque gels. Thermodynamically derived parameters could not be correlated to the physical properties of the molecular gels unless they were dissected into their individual HSPs. The DBS solvent phases tend to cluster in regions of Hansen space and are highly influenced by the hydrogen-bonding HSP, δ(h). It is also found that the fate of this molecular gelator, unlike that of polymers, is influenced not only by

  9. Process for Upgrading Cognitive Assessment Capabilities Onboard the International Space Station

    Science.gov (United States)

    Picano, J. J.; Seaton, K. A.; Holland, A. W.

    2016-01-01

    MOTIVATION: Spaceflight poses varied and unique risks to the brain and cognitive functioning including radiation exposure, sleep disturbance, fatigue, fluid shifts (increased intracranial pressure), toxin exposure, elevated carbon dioxide, and traumatic brain injury, among others. These potential threats to cognitive functioning are capable of degrading performance and compromising mission success. Furthermore, the threats may increase in severity, and new types of threats may emerge for longer duration exploration missions. This presentation will describe the process used to identify gaps in our current approach, evaluate best practices in cognitive assessment, and transition new cognitive assessment tools to operational use. OVERVIEW: Risks to brain health and performance posed by spaceflight missions require sensitive tools to assess cognitive functioning of astronauts in flight. The Spaceflight Cognitive Assessment Tool for Windows (WinSCAT) is the automated cognitive assessment tool currently deployed onboard the International Space Station (ISS). WinSCAT provides astronauts and flight surgeons with objective data to monitor neurocognitive functioning. WinSCAT assesses 5 discrete cognitive domains, is sensitive to changes in cognitive functioning, and was designed to be completed in less than 15 minutes. However, WinSCAT does not probe other areas of cognitive functioning that might be important to mission success. Researchers recently have developed batteries that may expand current capabilities, such as increased sensitivity to subtle fluctuations in cognitive functioning. Therefore, we engaged in a systematic process review in order to improve upon our current capabilities and incorporate new advances in cognitive assessment. This process included a literature review on newer measures of neurocognitive assessment, surveys of operational flight surgeons at NASA regarding needs and gaps in our capabilities, and expert panel review of candidate cognitive

  10. The peer review process for awarding funds to international science research consortia: a qualitative developmental evaluation.

    Science.gov (United States)

    Gregorius, Stefanie; Dean, Laura; Cole, Donald C; Bates, Imelda

    2017-01-01

    Background:  Evaluating applications for multi-national, multi-disciplinary, dual-purpose research consortia is highly complex. There has been little research on the peer review process for evaluating grant applications and almost none on how applications for multi-national consortia are reviewed. Overseas development investments are increasingly being channelled into international science consortia to generate high-quality research while simultaneously strengthening multi-disciplinary research capacity. We need a better understanding of how such decisions are made and their effectiveness. Methods:  An award-making institution planned to fund 10 UK-Africa research consortia. Over two annual rounds, 34 out of 78 eligible applications were shortlisted and reviewed by at least five external reviewers before final selections were made by a face-to-face panel. We used an innovative approach involving structured, overt observations of award-making panel meetings and semi-structured interviews with panel members to explore how assessment criteria concerning research quality and capacity strengthening were applied during the peer review process. Data were coded and analysed using pre-designed matrices which incorporated categories relating to the assessment criteria. Results:  In general the process was rigorous and well-managed. However, lack of clarity about differential weighting of criteria and variations in the panel's understanding of research capacity strengthening resulted in some inconsistencies in use of the assessment criteria. Using the same panel for both rounds had advantages, in that during the second round consensus was achieved more quickly and the panel had increased focus on development aspects. Conclusion:  Grant assessment panels for such complex research applications need to have topic- and context-specific expertise. They must also understand research capacity issues and have a flexible but equitable and transparent approach. This study has

  11. International magazines and journals (National Geographic and Reader'sDigest) launched at the Czech market: transfer strategies and processes

    OpenAIRE

    Gallóová, Markéta

    2011-01-01

    This study has aimed at describing the strategies and processes that apply during the introduction of international magazines to the Czech market. We have chosen the well-known and widely read, truly international magazines National Geographic and Reader's Digest as our material. We have focused on the role of these magazines in the interaction of cultures (Czech and American). We have realized that this area of translatological knowledge has not yet been analysed thoroughly enough. There are...

  12. PREFACE: Third International Conference on Advances in Solidification Processes (ICASP - 3)

    Science.gov (United States)

    Zimmermann, Gerhard; Ratke, Lorenz

    2012-01-01

    The 3rd International Conference on Advances in Solidification Processes was held in the Rolduc Abbey in the Netherlands a few kilometres away from Aachen. Around 200 scientists from 24 countries come in for the four day meeting. They found a stimulating but also relaxing environment and atmosphere, with beautiful weather and the medieval abbey inviting for walks, discussions, sitting outside and drinking a beer or wine. The contributions given at the conference reflected recent advances in various topics of solidification processes, ranging from fundamental aspects to applied casting technologies. In 20 oral sessions and a large poster session innovative results of segregation phenomena, microstructure evolution, nucleation and growth, phase formation, polyphase solidification, rapid solidification and welding, casting technology, thermophysics of molten alloys, solidification with forced melt flow and growth of single crystals and superalloys together with innovative diagnostic techniques were presented. Thereby, findings from experiments as well as from numerical modeling on different lengths scales were jointly discussed and contribute to new insight in solidification behaviour. The papers presented in this open access proceedings cover about half the oral and poster presentations given. They were carefully reviewed as in classical peer reviewed journals by two independent referees and most of them were revised and thus improved according to the reviewers comments. We think that this collection of papers presented at ICASP-3 gives an impression of the excellent contributions made. The papers embrace both the basic and applied aspects of solidification. We especially wish to express our appreciation for the team around Georg Schmitz and Margret Nienhaus organising this event and giving us their valued advice and support at every stage in preparing the conference. We also thank Lokasenna Lektorat for taking the task of checking all language-associated issues and

  13. An educational international partnership responding to local needs: process evaluation of the Brazil FAIMER Regional Institute.

    Science.gov (United States)

    Amaral, E; Campos, H H; Friedman, S; Morahan, P S; Araujo, M N T; Carvalho, P M; Bollela, V; Ribeiro, M G F; Mennin, S; Haddad, A E; Campos, F

    2012-11-01

    The Brazilian public health system requires competent professionals sensitive to the needs of the population. The Foundation for Advancement of International Medical Education and Research (FAIMER) provides a two-year faculty development programme for health professions educators, aiming to build leadership in education to improve health. A partnership with governmental initiatives and FAIMER was established for meeting these needs. This paper describes the initial process evaluation results of the Brazilian FAIMER Institute Fellowship (FAIMER BR). Data were analysed for the classes 2007-2010 regarding: application processes; innovation project themes; retrospective post-pre self-ratings of knowledge acquisition; and professional development portfolios. Seventeen of 26 Brazilian states were represented among 98 Fellows, predominantly from public medical schools (75.5%) and schools awarded Ministry of Health grants to align education with public health services (89.8%). One-third (n = 32) of Fellows' innovation projects were related to these grants. Significant increases occurred in all topic subscales on self-report of knowledge acquisition (effect sizes, 1.21-2.77). In the follow up questionnaire, 63% of Fellows reported that their projects were incorporated into the curriculum or institutional policies. The majority reported that the programme deepened their knowledge (98%), provided new ideas about medical education (90%) and provided skills for conflict management (63%). One-half of the Fellows reported sustained benefits from the programme listserv and other communications, including breadth of expertise, establishment of research collaboration and receiving emotional support. Contributors to initial programme success included alignment of curriculum with governmental initiatives, curriculum design merging educational technology, leadership and management skills and central role of an innovation educational project responding to local needs.

  14. Gravity Changes and Internal Processes: Some Results Obtained from Observations at Three Volcanoes

    Science.gov (United States)

    Jentzsch, Gerhard; Weise, Adelheid; Rey, Carlos; Gerstenecker, Carl

    Temporal gravity changes provide information about mass and/or density variations within and below the volcano edifice. Three active volcanoes have been under investigation; each of them related to a plate boundary: Mayon/Luzon/Philippines, Merapi/Java/Indonesia, and Galeras/Colombia. The observed gravity changes are smaller than previously expected but significant. For the three volcanoes under investigation, and within the observation period, mainly the increase of gravity is observed, ranging from 1,000 nm-2 to 1,600 nms-2. Unexpectedly, the gravity increase is confined to a rather small area with radii of 5 to 8 km around the summit. At Mayon and Merapi the parallel GPS measurements yield no significant elevation changes. This is crucial for the interpretation, as the internal pressure variations do not lead to significant deformation at the surface. Thus the classical Mogi-model for a shallow extending magma reservoir cannot apply. To confine the possible models, the attraction due to changes of groundwater level or soil moisture is estimated along the slope of Merapi exemplarily by 2-D modelling. Mass redistribution or density changes were evaluated within the vent as well as deeper fluid processes to explain the gravity variations; the results are compared to the model incorporating the additional effect of elastic deformation.

  15. Strata-1: An International Space Station Experiment into Fundamental Regolith Processes in Microgravity

    Science.gov (United States)

    Fries, M.; Abell, P.; Brisset, J.; Britt, D.; Colwell, J.; Durda, D.; Dove, A.; Graham, L.; Hartzell, C.; John, K.; hide

    2016-01-01

    The Strata-1 experiment will study the evolution of asteroidal regolith through long-duration exposure of simulant materials to the microgravity environment on the International Space Station (ISS). Many asteroids feature low bulk densities, which implies high values of porosity and a mechanical structure composed of loosely bound particles, (i.e. the "rubble pile" model), a prime example of a granular medium. Even the higher-density, mechanically coherent asteroids feature a significant surface layer of loose regolith. These bodies are subjected to a variety of forces and will evolve in response to very small perturbations such as micrometeoroid impacts, planetary flybys, and the YORP effect. Our understanding of this dynamical evolution and the inter-particle forces involved would benefit from long-term observations of granular materials exposed to small vibrations in microgravity. A detailed understanding of asteroid mechanical evolution is needed in order to predict the surface characteristics of as-of-yet unvisited bodies, to understand the larger context of samples collected by missions such as OSIRIS-REx and Hayabusa 1 and 2, and to mitigate risks for both manned and unmanned missions to asteroidal bodies. Understanding regolith dynamics will inform designs of how to land and set anchors, safely sample/move material on asteroidal surfaces, process large volumes of material for in situ resource utilization (ISRU) purposes, and, in general, predict behavior of large and small particles on disturbed asteroid surfaces.

  16. Aspects of Spatial Economic Processes of Disadvantaged Areas in Hungarian and International Perspective

    Directory of Open Access Journals (Sweden)

    KITTI NÉMEDI-KOLLÁR

    2015-12-01

    Full Text Available The examination of disadvantaged regions goes back to a long history, greatly influenced by the ever-changing natural, economic and human resources. Consequently, while examining the disadvantaged areas, we face new systems of coherences. Today’s regional policy also needs to answer the question whether the spatial development funds of the past have been efficient or not and whether the land use distribution influences the spatial competitiveness or not. As we move towards 2015, we must consider the actual state of delivery of the Millennium Development Goals (MDGs in the Least Developed Countries (LDCs and address the above-mentioned issues in order to realise the international political commitment to leave no one behind. In this paper, we have shown some aspects of spatial economic processes through the example of the Hungarian disadvantaged areas. These issues are timely because the usefulness of the research is important, ranging from rural development to spatial planning and the elaboration of local and regional development strategies. Spatial discrepancies in Hungary cause the disadvantage of rural areas, contributing to their lagging behind compared to the urban areas (Kollár, 2012.

  17. Biomass gasification for electricity generation with internal combustion engines. Process efficiency

    International Nuclear Information System (INIS)

    Lesme-Jaén, René; Garcia Faure, Luis; Recio Recio, Angel; Oliva Ruiz, Luis; Pajarín Rodríguez, Juan; Revilla Suarez, Dennis

    2015-01-01

    Biomass is a renewable source of energy worldwide increased prospects for its potential and its lower environmental impact compared to fossil fuels. By processes and energy conversion technologies it is possible to obtain fuels in solid, liquid and gaseous form from any biomass. The biomass gasification is the thermal conversion thereof into a gas, which can be used for electricity production with the use of internal combustion engines with a certain level of efficiency, which depends on the characteristics of biomass and engines used. In this work the evaluation of thermal and overall efficiency of the gasification in Integrated Forestry Enterprise of Santiago de Cuba, designed to generate electricity from waste from the forest industry is presented. Is a downdraft gasifier reactor, COMBO-80 model and engine manufacturing Hindu (diesel) model Leyland modified to work with producer gas. The evaluation was carried out for different loads (electric power generated) engine from experimental measurements of flow and composition of the gas supplied to the engine. The results show that the motor operates with a thermal efficiency in the range of 20-32% with an overall efficiency between 12-25%. (full text)

  18. Facile synthesis of radial-like macroporous superparamagnetic chitosan spheres with in-situ co-precipitation and gelation of ferro-gels.

    Directory of Open Access Journals (Sweden)

    Chih-Hui Yang

    Full Text Available Macroporous chitosan spheres encapsulating superparamagnetic iron oxide nanoparticles were synthesized by a facile and effective one-step fabrication process. Ferro-gels containing ferrous cations, ferric cations and chitosan were dropped into a sodium hydroxide solution through a syringe pump. In addition, a sodium hydroxide solution was employed for both gelation (chitosan and co-precipitation (ferrous cations and ferric cations of the ferro-gels. The results showed that the in-situ co-precipitation of ferro-ions gave rise to a radial morphology with non-spheroid macro pores (large cavities inside the chitosan spheres. The particle size of iron oxide can be adjusted from 2.5 nm to 5.4 nm by tuning the concentration of the sodium hydroxide solution. Using Fourier Transform Infrared Spectroscopy and X-ray diffraction spectra, the synthesized nanoparticles were illustrated as Fe(3O(4 nanoparticles. In addition, the prepared macroporous chitosan spheres presented a super-paramagnetic behaviour at room temperature with a saturation magnetization value as high as ca. 18 emu/g. The cytotoxicity was estimated using cell viability by incubating doses (0∼1000 µg/mL of the macroporous chitosan spheres. The result showed good viability (above 80% with alginate chitosan particles below 1000 µg/mL, indicating that macroporous chitosan spheres were potentially useful for biomedical applications in the future.

  19. Two-Phase Diffusion Technique for the Preparation of Ultramacroporous/Mesoporous Silica Microspheres via Interface Hydrolysis, Diffusion, and Gelation of TEOS.

    Science.gov (United States)

    Ju, Minhua; Li, Yupeng; Yu, Liang; Wang, Chongqing; Zhang, Lixiong

    2018-02-06

    Honeycombed hierarchical ultramacroporous/mesoporous silica microspheres were prepared via the hydrolysis of TEOS in the oil-water interface, with subsequent diffusion and gelation in the acidic water-phase microdroplets with the assistance of a simple homemade microdevice. The diffusion of furfuryl alcohol (FA) also happened at a relatively high rate during the hydrolysis and diffusion of TEOS. Therefore, plenty of FA will be inside of the water microdroplets and form a decent number of polyfurfuryl alcohol (PFA) microparticles, thereby obtaining honeycombed hierarchical porosity silica microspheres with abundant ultramacroporous cavities and mesopores after calcination. It was found that the concentration of FA, residence time, and reaction temperature have significant effects on the porosity and pore size due to the influence on the diffusion rate and amount of FA in water-phase microdroplets. The honeycombed silica microspheres have obvious microscopic visible ultramacroporous cavities with the submicrometer cavity diameter as high as 85% porosity based on the rough overall volume of microsphere. N 2 adsorption-desorption isotherms show that the honeycombed hierarchical porosity silica microspheres have a high surface area of 602 m 2 g -1 , a mesopore volume of 0.77 cm 3 /g, and a mesopore porosity of 99.6% based on the total pore volume of N 2 adsorption-desorption. On the basis of the experiment results, a rational formation process of the honeycombed hierarchical porosity silica microspheres was deduced.

  20. Formation of Globular Clusters with Internal Abundance Spreads in r -Process Elements: Strong Evidence for Prolonged Star Formation

    Energy Technology Data Exchange (ETDEWEB)

    Bekki, Kenji [ICRAR, M468, University of Western Australia, 35 Stirling Highway, Crawley, Western Australia, 6009 (Australia); Tsujimoto, Takuji [National Astronomical Observatory of Japan, Mitaka-shi, Tokyo 181-8588 (Japan)

    2017-07-20

    Several globular clusters (GCs) in the Galaxy are observed to show internal abundance spreads in r -process elements (e.g., Eu). We propose a new scenario that explains the origin of these GCs (e.g., M5 and M15). In this scenario, stars with no/little abundance variations first form from a massive molecular cloud (MC). After all of the remaining gas of the MC is expelled by numerous supernovae, gas ejected from asymptotic giant branch stars can be accumulated in the central region of the GC to form a high-density intracluster medium (ICM). Merging of neutron stars then occurs to eject r -process elements, which can be efficiently trapped in and subsequently mixed with the ICM. New stars formed from the ICM can have r -process abundances that are quite different from those of earlier generations of stars within the GC. This scenario can explain both (i) why r -process elements can be trapped within GCs and (ii) why GCs with internal abundance spreads in r -process elements do not show [Fe/H] spreads. Our model shows (i) that a large fraction of Eu-rich stars can be seen in Na-enhanced stellar populations of GCs, as observed in M15, and (ii) why most of the Galactic GCs do not exhibit such internal abundance spreads. Our model demonstrates that the observed internal spreads of r -process elements in GCs provide strong evidence for prolonged star formation (∼10{sup 8} yr).

  1. On anisotropy and internal pressure errors in numerical ocean models and processes near the shelf edge

    Energy Technology Data Exchange (ETDEWEB)

    Thiem, Oeyvind A.

    2004-12-01

    In this thesis the focus has been on anisotropy, internal pressure errors and shelf edge/slope processes. Anisotropy is a common problem in ocean models. Especially where a rectangular grid is used to discretize the horizontal. Selecting a horizontal grid, which reduces the anisotropy, will therefore probably be important when new ocean models are being developed. Hexagonal grid discretization in the horizontal has the desired property of reducing anisotropy, and therefore this grid should be considered as a reasonable choice for new ocean models. In sigma coordinate models internal pressure errors occur in areas with steep topography. In the second paper in this thesis, it is shown that the internal pressure errors depend on the grid orientation. It is further shown that the erroneous velocities in the sea mount test case of Beckmann and Haidvogel (1993) can be reduced significantly by first computing the internal pressure gradients in both the original and a coordinate system where the axis are rotated 45 degrees to the original. Then a normalized weighted linear combination of the two estimates is used as the internal pressure gradients in the simulation. A following up paper where this method is used on a real ocean should be performed to investigate how well this method performs in domains with irregular topography. In such an experiment the boundary should be closed and the initial velocities set to zero. The occurring currents should then be compared with a corresponding experiment, where the initial pressure gradients are computed in the original grid only. In the third and fourth paper the focus is on the use of BOM in along shelf barotropic flow. First the generation of eddies is investigated. This is done in the third paper and two simulations are performed. The first simulation is a barotropic simulation, and the second is a two layer simulation. The results from both simulations show development of eddies, but the strength of the eddies depend on the

  2. Economic analysis of solar industrial process heat systems: A methodology to determine annual required revenue and internal rate of return

    Science.gov (United States)

    Dickinson, W. C.; Brown, K. C.

    1981-08-01

    An economic evaluation of solar industrial process heat systems, is developed to determine the annual required revenue and the internal rate of return. First, a format is provided to estimate the solar system's installed cost, annual operating and maintenance expenses, and net annual solar energy delivered to the industrial process. The annual required revenue and the price of solar is calculated. The economic attractiveness of the potential solar investment can be determined by comparing the price of solar energy with the price of fossilfuel, both expressed in levelized terms. This requires calcuation of the internal rate of return on the solar investment or, in certain cases, the growth rate of return.

  3. Evaluation of some physico-chemical properties of restructured trout and hake mince during cold gelation and chilled storage

    DEFF Research Database (Denmark)

    Moreno, H.M.; Javier Borderias, A.; Baron, Caroline

    2010-01-01

    Cold gelation was carried out on trout (Oncorhynchus mykiss) or on hake (Merluccius mertuccius) mince with or without addition of fish oil and using microbial transglutaminase (MTGase). Products were stored at 4 QC for 6 days and lipid oxidation, protein oxidation, texture, water binding capacity......, and colour were followed. Results indicated that MTGase was able to generate gels with good properties for both trout and hake. Gels prepared with trout were oxidised whilst gels prepared with hake were stable toward oxidation even in the presence of 5% fish oil. However, in the presence of oil...

  4. Developing an Undergraduate International Business Program: Context, Rationale, Process and Focus

    Science.gov (United States)

    Bell, Jim; Gray, Brendan; McNaughton, Rod

    2003-01-01

    This paper discusses the recent development of a new undergraduate international business program at the University of Otago in New Zealand. Firstly, it describes the context of the initiative in terms of the New Zealand business environment, the university sector in New Zealand and recent global trends in international business education.…

  5. Towards an integration of affiliated companies energy audit process system at P.T Astra International

    Science.gov (United States)

    Telaga, Abdi Suryadinata; Hartanto, Indra Dwi; Audina, Debby Rizky; Prabowo, Fransiscus Dimas

    2017-06-01

    Environmental awareness, stringent regulation and soaring energy costs, together make energy efficiency as an important pillar for every company. Particularly, in 2020, the ministry of energy and mineral resources of Indonesia has set a target to reduce carbon emission by 26%. For that reason, companies in Indonesia have to comply with the emission target. However, there is trade-off between company's productivity and carbon emission. Therefore, the companies' productivity must be weighed against the environmental effect such as carbon emission. Nowadays, distinguish excessive energy in a company is still challenging. The company rarely has skilled person that capable to audit energy consumed in the company. Auditing energy consumption in a company is a lengthy and time consuming process. As PT Astra International (AI) have 220 affiliated companies (AFFCOs). Occasionally, direct visit to audit energy consumption in AFFCOs is inevitable. However, capability to conduct on-site energy audit was limited by the availability of PT AI energy auditors. For that reason, PT AI has developed a set of audit energy tools or Astra green energy (AGEn) tools to aid the AFFCOs auditor to be able to audit energy in their own company. Fishbone chart was developed as an analysis tool to gather root cause of audit energy problem. Following the analysis results, PT AI made an improvement by developing an AGEn web-based system. The system has capability to help AFFCOs to conduct energy audit on-site. The system was developed using prototyping methodology, object-oriented system analysis and design (OOSAD), and three-tier architecture. The implementation of system used ASP.NET, Microsoft SQL Server 2012 database, and web server IIS 8.

  6. Study of the spheroidization process of glass particles for selective internal radiotherapy

    International Nuclear Information System (INIS)

    Barros Filho, Eraldo Cordeiro

    2012-01-01

    The selective internal radiotherapy is an alternative method to treat hepatocellular carcinoma. Glass microspheres containing radionuclides are introduced in the liver through the hepatic artery, and they are housed preferentially in the region where the cancer cells are located. The microspheres are trapped in the arterioles which feed the tumors, and the β - particles annihilate the cancer cells. When these particles simultaneously emit γ rays, they can also be used to provide images of the tumor. The glass particles must be spherical to avoid unnecessary bleeding, and the particle size must be restricted to a range which is appropriated to trap them and avoid the migration to other parts of the body. Furthermore, they must have a good chemical durability and be nontoxic. The particle size distribution of microspheres is not easily predicted based on the original irregular particles since the variation of the aspect ratio and the presence of agglomerates can influence the final result. In the present work, the spheroidization process to obtain microspheres for radiotherapy treatment was studied. The glass microspheres were characterized by X-rays diffraction, Energy Dispersive X-rays Fluorescence Spectroscopy, Differential Scanning Calorimetry, Specific Superficial Area and cytotoxicity test. The dissolution rate in distilled water at 90 degree C (DR∼10 -8 g.cm - 2.min -1 ), density (2.79g.cm -3 ), viscosity, and size particle distribution were determined. The surface morphological aspect was evaluated by Scanning Electron Microscopy before and after the chemical durability tests in SBF and after the neutron irradiation. It is proposed that the produced material should be sieved to select the most suitable microspheres

  7. On the Internal Structure of Mobile Barchan Sand Dunes due to Granular Processes

    Science.gov (United States)

    Vriend, N. M.; Arran, M.; Louge, M. Y.; Hay, A. G.; Valance, A.

    2017-12-01

    In this work, we visualize the internal structure of mobile barchan desert dunes at the avalanche scale. We reveal an intriguing history of dune building using a novel combination of local sand sampling and advanced geophysical techniques resulting in high resolution measurements of individual avalanche events. Due to progressive rebuilding, granular avalanching, erosional and depositional processes, these marching barchan dunes are reworked every few years and a characteristic zebra-pattern (figure 1a), orientated parallel to the slipface at the angle of repose, appears at regular intervals. We present scientific data on the structure obtained from several mobile barchan dunes of different sizes during recent desert field campaigns (2014, 2015, 2017) in a mobile barchan dune field in Qatar (25.01°N, 51.34°E in the AlWakrah municipality). The site has been equipped with a weather station and has been regularly visited by a multidisciplinary research team in recent years (e.g. [1]). By applying high-frequency (1200 MHz) ground penetrating radar (GPR) transects across the midline (figure 1b) we map the continuous evolution of this cross-bedding at high resolution deep within the dune. The GPR reveals a slope reduction of the slipface near the base of the dune; evidence of irregular wind reversals; and the presence of a harder aeolian cap around the crest and extending to the brink. The data is supplemented with granulometry from layers stabilized by dyed water injection and uncovered by excavating vertical walls perpendicular to old buried avalanches. We attribute visible differences in water penetration between adjacent layers to fine particle segregation processes in granular avalanches. This work was made possible by the support of NPRP grant 6-059-2-023 from the Qatar National Research Fund to MYL and AGH, and a Royal Society Dorothy Hodgkin Research Fellowship to NMV. We thank Jean-Luc Métayer for performing detailed particle size distribution measurements

  8. Clathrin-dependent internalization, signaling, and metabolic processing of guanylyl cyclase/natriuretic peptide receptor-A.

    Science.gov (United States)

    Somanna, Naveen K; Mani, Indra; Tripathi, Satyabha; Pandey, Kailash N

    2018-04-01

    Cardiac hormones, atrial and brain natriuretic peptides (ANP and BNP), have pivotal roles in renal hemodynamics, neuroendocrine signaling, blood pressure regulation, and cardiovascular homeostasis. Binding of ANP and BNP to the guanylyl cyclase/natriuretic peptide receptor-A (GC-A/NPRA) induces rapid internalization and trafficking of the receptor via endolysosomal compartments, with concurrent generation of cGMP. However, the mechanisms of the endocytotic processes of NPRA are not well understood. The present study, using 125 I-ANP binding assay and confocal microscopy, examined the function of dynamin in the internalization of NPRA in stably transfected human embryonic kidney-293 (HEK-293) cells. Treatment of recombinant HEK-293 cells with ANP time-dependently accelerated the internalization of receptor from the cell surface to the cell interior. However, the internalization of ligand-receptor complexes of NPRA was drastically decreased by the specific inhibitors of clathrin- and dynamin-dependent receptor internalization, almost 85% by monodansylcadaverine, 80% by chlorpromazine, and 90% by mutant dynamin, which are specific blockers of endocytic vesicle formation. Visualizing the internalization of NPRA and enhanced GFP-tagged NPRA in HEK-293 cells by confocal microscopy demonstrated the formation of endocytic vesicles after 5 min of ANP treatment; this effect was blocked by the inhibitors of clathrin and by mutant dynamin construct. Our results suggest that NPRA undergoes internalization via clathrin-mediated endocytosis as part of its normal itinerary, including trafficking, signaling, and metabolic degradation.

  9. Evaluation of Internal Cracks and Collapse in Poplar Wood (Populus nigra during a Conventional Drying Process with Ultrasonic Inspection

    Directory of Open Access Journals (Sweden)

    Saeid ESHAGHI

    2012-05-01

    Full Text Available In this research, internal cracks and collapse of wood, formed during drying process, were measured using ultrasonic inspection. For this purpose, seven poplar (Populus nigra small blocks were dried, according to a time-based schedule. Ultrasonic waves� propagation velocity was measured at both parallel and perpendicular to grain directions, using Sylvatest ultrasound device, during kiln drying process. Results showed that in all dried blocks, waves� propagation velocity in the parallel direction was higher than in the perpendicular direction to grain. Ultrasonic waves� propagation test for non-destructive identification of internal cracks, which occurs in wood during drying process in the parallel direction, was more successful compared to the perpendicular direction. Using ultrasonic waves� propagation test for detection of collapse that occurs in wood during drying process was not useful.

  10. Evaluation of Internal Cracks and Collapse in Poplar Wood (Populus nigra during a Conventional Drying Process with Ultrasonic Inspection

    Directory of Open Access Journals (Sweden)

    Saeid ESHAGHI

    2012-05-01

    Full Text Available In this research, internal cracks and collapse of wood, formed during drying process, were measured using ultrasonic inspection. For this purpose, seven poplar (Populus nigra small blocks were dried, according to a time-based schedule. Ultrasonic waves propagation velocity was measured at both parallel and perpendicular to grain directions, using Sylvatest ultrasound device, during kiln drying process. Results showed that in all dried blocks, waves propagation velocity in the parallel direction was higher than in the perpendicular direction to grain. Ultrasonic waves propagation test for non-destructive identification of internal cracks, which occurs in wood during drying process in the parallel direction, was more successful compared to the perpendicular direction. Using ultrasonic waves propagation test for detection of collapse that occurs in wood during drying process was not useful.

  11. Elastin Based Cell-laden Injectable Hydrogels with Tunable Gelation, Mechanical and Biodegradation Properties

    Science.gov (United States)

    Fathi, Ali; Mithieux, Suzanne M.; Wei, Hua; Chrzanowski, Wojciech; Valtchev, Peter; Weiss, Anthony S.; Dehghani, Fariba

    2015-01-01

    Injectable hydrogels made from extracellular matrix proteins such as elastin show great promise for various biomedical applications. Use of cytotoxic reagents, fixed gelling behavior, and lack of mechanical strength in these hydrogels are the main associated drawbacks. The aim of this study was to develop highly cytocompatible and injectable elastin-based hydrogels with alterable gelation characteristics, favorable mechanical properties and structural stability for load bearing applications. A thermoresponsive copolymer, poly(N-isopropylacrylamide-co-polylactide-2-hydroxyethyl methacrylate-co-oligo(ethylene glycol)monomethyl ether methacrylate, was functionalized with succinimide ester groups by incorporating N-acryloxysuccinimide monomer. These ester groups were exploited to covalently bond this polymer, denoted as PNPHO, to different proteins with primary amine groups such as α-elastin in aqueous media. The incorporation of elastin through covalent bond formation with PNPHO promotes the structural stability, mechanical properties and live cell proliferation within the structure of hydrogels. Our results demonstrated that elastin-co-PNPHO solutions were injectable through fine gauge needles and converted to hydrogels in situ at 37 °C in the absence of any crosslinking reagent. By altering PNPHO content, the gelling time of these hydrogels can be finely tuned within the range of 2 to 15 min to ensure compatibility with surgical requirements. In addition, these hydrogels exhibited compression moduli in the range of 40 to 145 kPa, which are substantially higher than those of previously developed elastin-based hydrogels. These hydrogels were highly stable in the physiological environment with the evidence of 10 wt% mass loss in 30 days of incubation in a simulated environment. This class of hydrogels is in vivo bioabsorbable due to the gradual increase of the lower critical solution temperature of the copolymer to above 37 °C due to the cleavage of polylactide from

  12. Insights into the mechanical properties of a silicone oil gel with a ‘latent’ gelator, 1-octadecylamine, and CO2 as an ‘activator’

    Directory of Open Access Journals (Sweden)

    Emiliano Carretti

    2010-10-01

    Full Text Available A detailed study of the rheological properties of silicone oil gels, made from a low-molecular-mass organic gelator, a combination of 1-octadecylamine (a latent gelator and carbon dioxide (an ‘activating’ molecule, is reported. Information gleaned from the mechanical measurements is used to characterize the gel networks and how they respond to temperature and strain. It is shown, for example, that very precise measurements of the gel-to-sol transitions can be obtained from plots of viscosity versus temperature.

  13. Identifying the Research Process to Analyse the Adoption of the International Baccalaureate's Diploma Programme in England

    Science.gov (United States)

    Outhwaite, Deborah

    2018-01-01

    This article analyses the flow-line around the methodology used inside an educational research process that was originally established to examine the expansion of the International Baccalaureate's Diploma Programme (IBDP) in England. This article analyses the research question, then assesses the research focus, aims and objectives. The article…

  14. SITE PROGRAM DEMONSTRATION ECO LOGIC INTERNATIONAL GAS-PHASE CHEMICAL REDUCTION PROCESS, BAY CITY, MICHIGAN TECHNOLOGY EVALUATION REPORT

    Science.gov (United States)

    The SITE Program funded a field demonstration to evaluate the Eco Logic Gas-Phase Chemical Reduction Process developed by ELI Eco Logic International Inc. (ELI), Ontario, Canada. The Demonstration took place at the Middleground Landfill in Bay City, Michigan using landfill wa...

  15. International Processes of Education Policy Formation: An Analytic Framework and the Case of Plan 2021 in El Salvador

    Science.gov (United States)

    Edwards, D. Brent, Jr.

    2013-01-01

    This article uses multiple perspectives to frame international processes of education policy formation and then applies the framework to El Salvador's Plan 2021 between 2003 and 2005. These perspectives are policy attraction, policy negotiation, policy imposition, and policy hybridization. Research reveals that the formation of Plan 2021 was the…

  16. Internal Quality Assurance Reviews: Challenges and Processes--Walter Sisulu University's Business, Management Sciences and Law Faculty

    Science.gov (United States)

    Moodly, A.; Saunderson, I.

    2008-01-01

    The Council for Higher Educations' (CHE) Higher Education Quality Committee (HEQC) requires internal quality evaluations to be performed on the various programmes offered by the Faculty before visitation by the HEQC. This article examines some of the challenges and processes followed by six of the departments of Walter Sisulu University's Faculty…

  17. Business process management : 3rd international conference, BPM 2005, Nancy, France, September 5-8, 2005 : proceedings

    NARCIS (Netherlands)

    Aalst, van der W.M.P.; Benatallah, B.; Casati, F.; Curbera, F.

    2005-01-01

    This volume contains the proceedings of the 3rd International Conference on Business Process Management (BPM 2005), organized by LORIA in Nancy, France, September 5–8, 2005. This year, BPM included several innovations with respect to previous editions, most notably the addition of an industrial

  18. The 54th International Meeting of Physical Chemistry; Fast Elementary Processes in Chemical and Biological Systems Proceedings

    International Nuclear Information System (INIS)

    Tramer, A.

    1996-01-01

    These proceedings represent papers presented at the 54th International Meeting of Physical Chemistry held in Villeneuve d'Ascq in France. Topics discussed include ultrafast studies in biophysics surface phenomena, photochemical processes, electron and proton transfer, crystalline and microdisperse media and isolated molecules. There were 80 papers presented at the meeting and 14 have been abstracted for the Energy Science and Technology database

  19. Engaging China in the International Export Control Process: Options for U.S. Policy

    National Research Council Canada - National Science Library

    Goldman, Charles

    1995-01-01

    This documented briefing is intended to provide options for U.S. policy that will enhance China's participation in the control of international transfers of destabilizing military or dual use technology...

  20. Passive autocatalytic recombiner process features and new status of international qualification

    International Nuclear Information System (INIS)

    Eckardt, Bernd A.; Losch, Norbert

    2010-01-01

    New results of International PAR-Severe Accidents Qualification in frame of EC/IRSN Core Melt Program PHEBUS (with real molten core) are presented. Example Results: AREVA PAR Design: Best performance very fast start-up • highest efficiency absolutely constant hydrogen depletion rates. Others: Some industrial competitors failed. This enveloping real severe accident tests represents the new international PAR qualification standard and finalized the PAR qualification successfully. The design features supports PAR Dual function

  1. An Analysis of Viable Financial Negotiations Processes and Related Internal Controls for Procurement in Pakistan

    Science.gov (United States)

    2016-06-01

    regulations are in accordance with UNCITRAL Model Law and are based on principles of “ accountability , transparency, fairness, efficiency and value for... account certain factors about the firm(s) for pre-qualification. These factors include past performance and experience; financial health; managerial...internal control components, along with associated principles , were discussed in detail to develop a suitable internal control system for the financial

  2. Corporate internal control system in the process of transformations: formation, development, problems

    OpenAIRE

    Kanapickienė, Rasa

    2009-01-01

    In the market environment every company is seeking to obtain and maintain the best market share. One of the mechanisms in achieving this goal is an effective internal control of the company. With growing competition, fast development and introduction of new technologies, progressing complexity of business projects, and enlarging business diversity, company management is becoming increasingly more complicated. Consequently, company internal control is becoming a more and more complicated task....

  3. Preparation and characterization of monodisperse microcapsules with alginate and bentonite via external gelation technique encapsulating Pseudomonas putida Rs-198.

    Science.gov (United States)

    Li, Xuan; Wu, Zhansheng; He, Yanhui; Ye, Bang-Ce; Wang, Jun

    2017-10-01

    This paper evaluated the external gelation technique for preparing microcapsules. The microcapsules were consisted of Pseudomonas putida Rs-198 (Rs-198) core and sodium alginate (NaAlg)-bentonite (Bent) shell. Different emulsification rotation speeds and core/shell ratios were used to prepare the microcapsules of each formulation. The near-spherical microcapsules were monodisperse with a mean diameter of 25-100 μm and wrinkled surfaces. Fourier transform infrared spectrophotometry (FTIR) and thermogravimetric analysis (TGA) revealed the physical mixture of the wall material and the superior thermal stability of the microcapsules. Percentage yield, water content, and encapsulation efficiency were evaluated and correlated with the changes in emulsification rotation speed and core/shell ratio. In vitro release experiments demonstrated that 60% of the bacteria were released from the NaAlg-Bent microcapsules within three days. Considerably better survival was observed for encapsulated cells compared to free cells, especially in pH 4.0 and 10.0. In summary, the desired properties of microcapsules can be obtained by external gelation technique and the microcapsules on the bacteria had a good protective effect.

  4. Coupling the Alkaline-Surfactant-Polymer Technology and The Gelation Technology to Maximize Oil Production

    Energy Technology Data Exchange (ETDEWEB)

    Malcolm Pitts; Jie Qi; Dan Wilson; Phil Dowling; David Stewart; Bill Jones

    2005-12-01

    Gelation technologies have been developed to provide more efficient vertical sweep efficiencies for flooding naturally fractured oil reservoirs or reservoirs with different sand lenses with high permeability contrast. The field proven alkaline-surfactant-polymer technology economically recovers 15% to 25% OOIP more crude oil than waterflooding from swept pore space of an oil reservoir. However, alkaline-surfactant-polymer technology is not amenable to naturally fractured reservoirs or reservoirs with high permeability contrast zones because much of injected solution bypasses target pore space containing oil. This work investigates whether combining these two technologies could broaden applicability of alkaline-surfactant-polymer flooding into these reservoirs. Fluid-fluid interaction with different gel chemical compositions and alkaline-surfactant-polymer solution with pH values ranging from 9.2 to 12.9 have been tested. Aluminum-polyacrylamide gels are not stable to alkaline-surfactant-polymer solutions at any pH. Chromium-polyacrylamide gels with polymer to chromium ion ratios of 25 or greater were stable to alkaline-surfactant-polymer solutions if solution pH was 10.6 or less. When the polymer to chromium ion was 15 or less, chromium-polyacrylamide gels were stable to alkaline-surfactant-polymer solutions with pH values up to 12.9. Chromium-xanthan gum gels were stable to alkaline-surfactant-polymer solutions with pH values of 12.9 at the polymer to chromium ion ratios tested. Silicate-polyacrylamide, resorcinol-formaldehyde, and sulfomethylated resorcinol-formaldehyde gels were also stable to alkaline-surfactant-polymer solutions with pH values ranging from 9.2 to 12.9. Iron-polyacrylamide gels were immediately destroyed when contacted with any of the alkaline-surfactant-polymer solutions with pH values ranging from 9.2 to 12.9. Gel solutions under dynamic conditions of linear corefloods showed similar stability to alkaline-surfactant-polymer solutions as in

  5. Age Stereotypes and Self-Views Revisited: Patterns of Internalization and Projection Processes Across the Life Span.

    Science.gov (United States)

    Kornadt, Anna E; Voss, Peggy; Rothermund, Klaus

    2017-07-01

    We investigated processes of age stereotype internalization into the self and projection of self-views onto age stereotypes from a life-span perspective, taking age-related differences in the relevance of life domains into account. Age stereotypes and self-views in eight life domains were assessed in a sample of N = 593 persons aged 30-80 years (T1) at two time points that were separated by a 4-year time interval. We estimated cross-lagged projection and internalization effects in multigroup structural equation models. Internalization and projection effects were contingent on age group and life domain: Internalization effects were strongest in the young and middle-aged groups and emerged in the domains family, personality, work, and leisure. Projection effects in different domains were most pronounced for older participants. Our findings suggest that the internalization of age stereotypes is triggered by domain-specific expectations of impending age-related changes and transitions during certain phases of the life span. Projection processes, however, seem to occur in response to changes that have already been experienced by the individual. Our study demonstrates the dynamic interrelation of age stereotypes and self-views across the life course and highlights the importance of a differentiated, life-span perspective for the understanding of these mechanisms. © The Author 2015. Published by Oxford University Press on behalf of The Gerontological Society of America. All rights reserved. For permissions, please e-mail: journals.permissions@oup.com.

  6. Chemical Changes in Proteins Produced by Thermal Processing.

    Science.gov (United States)

    Dutson, T. R.; Orcutt, M. W.

    1984-01-01

    Discusses effects of thermal processing on proteins, focusing on (1) the Maillard reaction; (2) heat denaturation of proteins; (3) aggregation, precipitation, gelation, and degradation; and (4) other thermally induced protein reactions. Also discusses effects of thermal processing on muscle foods, egg proteins, fruits and vegetables, and cereal…

  7. Japan's Siting Process for the Geological Disposal of High-level Radioactive Waste - An International Peer Review

    International Nuclear Information System (INIS)

    Brassinnes, Stephane; Fabbri, Olivier; Rubenstone, James; Seppaelae, Timo; Siemann, Michael; ); Kwong, Gloria; )

    2016-01-01

    The Nuclear Energy Agency carried out an independent peer review of Japan's siting process and criteria for the geological disposal of high-level radioactive waste in May 2016. The review concluded that Japan's site screening process is generally in accordance with international practices. As the goal of the siting process is to locate a site - that is both appropriate and accepted by the community - to host a geological disposal facility for high-level radioactive waste, the international review team emphasises in this report the importance of maintaining an open dialogue and interaction between the regulator, the implementer and the public. Dialogue should begin in the early phases and continue throughout the siting process. The international review team also underlines the importance of taking into account feasibility aspects when selecting a site for preliminary investigations, but suggests that it would be inappropriate to set detailed scientific criteria for nationwide screening at this stage. The team has provided extensive advisory remarks in the report as opportunities for improvement, including the recommendation to use clear and consistent terminology in defining the site screening criteria as it is a critical factor in a successful siting process. (authors)

  8. Editorial - Special Issue on the Ninth International Conference on Aeolian Research - ICAR IX (Coastal Dune Processes and Aeolian Transport)

    Science.gov (United States)

    da Silva, Graziela Miot

    2018-04-01

    This special issue combines some of the papers related to coastal dune processes and aeolian sediment transport that were presented at the Ninth International Conference on Aeolian Research - ICAR IX. The conference was held between 4 and 8 of July 2016 in Mildura, Australia, organized by the International Society for Aeolian Research (ISAR) and convened by Adrian Chappell (Cardiff University), Craig Strong (Australian National University), Stephen Cattle (University of Sydney), Patrick Hesp (Flinders University), John Leys (New South Wales Office of Environment and Heritage), Lynda Petherick (University of Wellington) and Nick Webb (USDA-ARS Jornada Experimental Range).

  9. PREFACE: International Symposium on Ultrasound in the Control of Industrial Processes (UCIP 2012)

    Science.gov (United States)

    Segura, Luis Elvira; Resa López, Pablo; Salazar, Jordi; Benedito Fort, José Javier; Martínez Graullera, Óscar

    2012-12-01

    The following describes most of the presentations (both oral and poster) given at the International Symposium of Ultrasound in the Control of Industrial Processes (UCIP 2012) celebrated in Madrid between 18 and 20 April 2012. This event was intended to be a meeting point for scientists, engineers and professionals from all over the world in the field of ultrasonics applied to the characterization and control of materials and processes in the industry. More precisely, the topics included were: 1. Novel applications of ultrasound in the industry (including high-power ultrasound) Food science Biotechnology and microbiology Pharmaceutics and cosmetics Petrochemistry and civil engineering 2. New insights in the ultrasonic characterization of media: Fluids and emulsions Nano- and micro-particle dispersions Soft materials Porous bodies and inhomogeneous materials 3. New developments in ultrasonic measuring techniques: Acoustic microscopy Piezoelectric sensors Ultrasonic imaging Signal processing The symposium was organized by the Centro de Acústica Aplicada y Evaluación No Destructiva (CAEND, UPM-CSIC) in collaboration with the Universidad Politécnica de Cataluña, the Universidad Politécnica de Valencia and the University of Leeds. During the conference, 32 posters and 33 oral communications were presented. In addition, 4 invited lectures were imparted: 'Acoustic microscopy, spectroscopy and nanoparticle detection' by Dr Malcolm Povey; 'Acoustic and electroacoustic spectroscopy' by Dr Andrei Dukhin; 'High-Resolution Ultrasonic Spectroscopy and its application for material analysis by Dr Vitaly Buckin; 'Ultrasonic sensors for process applications - state of the art' by Dr Bern Henning; and three tutorials were given: 'PZFlex - Finite Element Analysis for Virtual Prototyping' by Weidlinger Associates; 'SITAU - A flexible architecture controlled by MATLAB for the development of ultrasonic applications' by DASEL; 'Ultra-SCATTERERTM (Acoustics Suite) - The R&D Tool for

  10. Study contribution to the new international philosophy of the radiological safety system on chemical processing of the natural uranium

    International Nuclear Information System (INIS)

    Silva, T.M. da.

    1988-01-01

    The objective of the work is to adapt the radiological Safety System in the facilities concerned to the chemical treatment of the uranium concentrated (yellow-cake) until conversion in uranium hexafluoride in the pilot plant of IPEN-CNEN/SP, to the new international philosophy adopted by the International Commission Radiological on Protection ICPR publication 22(1973), 26(1977), 30(1978) and the International Atomic Energy Agency IAEA publication 9(1982). The new philosophy changes fully the Radiological Protection concepts of preceding philosophy, changes, also, the concept of the work place and individual monitoring as well as the classification of the working areas. These new concepts are applied in each phase of the natural uranium treatment chemical process in conversion facility. (author)

  11. Linguistic Diversity in the International Workplace: Language Ideologies and Processes of Exclusion

    Science.gov (United States)

    Lønsmann, Dorte

    2014-01-01

    This article draws on a study of language choice and language ideologies in an international company in Denmark. It focuses on the linguistic and social challenges that are related to the diversity of language competences among employees in the modern workplace. Research on multilingualism at work has shown that employees may be excluded from…

  12. External and internal sources which inhibit the nitrification process in wastewater treatment plants

    DEFF Research Database (Denmark)

    Sinkjær, O.; Bøgebjerg, P.; Grüttner, H.

    1996-01-01

    the nitrification capacity monitored at the pilot plants has been in agreement with the design basis. The recycling of the scrubber water from the cleaning of sludge incineration flue gas was found to be an important internal source of inhibition at the Lynetten WWTP. Investigations show that it is possible...

  13. Affective Experiences of International and Home Students during the Information Search Process

    Science.gov (United States)

    Haley, Adele Nicole; Clough, Paul

    2017-01-01

    An increasing number of students are studying abroad requiring that they interact with information in languages other than their mother tongue. The UK in particular has seen a large growth in international students within Higher Education. These nonnative English speaking students present a distinct user group for university information services,…

  14. Processes and experiences of Portugal's international recruitment scheme of Colombian physicians: Did it work?

    Science.gov (United States)

    Masanet, Erika

    2017-08-01

    The Portuguese Ministry of Health performed five international recruitment rounds of Latin American physicians due to the need for physicians in certain geographic areas of the country and in some specialties, as a temporary solution to shortages. Among these recruitments is that of Colombian physicians in 2011 that was the largest of the five groups. This paper presents an evaluation of the international recruitment procedure of Colombian physicians based on the criteria of procedural outcomes and health system outcomes. The methodology used is qualitative, based on semi-structured interviews with key informants and Colombian physicians recruited in Portugal and also on documentary analysis of secondary sources. International recruitment of Colombian physicians coincided with a period of political change and severe economic crisis in Portugal that caused some problems in the course of this recruitment, mainly family reunification in the later group of Colombian physicians and non-compliance of the salary originally agreed upon. Furthermore, due to the continuous resignations of Colombian physicians throughout the 3-year contract, procedural outcomes and health system outcomes of this international recruitment were not fulfilled and therefore the expected results to meet the temporary needs for medical personnel in some areas of the country were not accomplished. Copyright © 2017 Elsevier B.V. All rights reserved.

  15. Theoretical foundations of international migration process studies: analysis of key migration theories development

    Directory of Open Access Journals (Sweden)

    Shymanska K.V.

    2017-03-01

    Full Text Available The need for transformation of Ukraine's migration policy based on globalized world development trends and in response to the challenges of European integration transformations causes the need of researching the theoretical and methodological basis of migration studies, and the regulations of existing theories of international migration. The bibliometric analysis of scientific publications on international migration in cites indexes found that the recent researches on these problems acquire interdisciplinary character. It necessitates the transformation of migration study approaches basing on economic, social, institutional theories and concepts synthesis. The article is devoted to the study of theoretical regulations of existing international migration theories in the context of the evolution of scientists’ views on this phenomenon. The author found that the existing theories of international migration should be divided into three categories (microeconomic, macroeconomic, globalizational that contributes to their understanding in the context of implementation possibilities in migrational public administration practice. It allows to determine the theories which should be used for Ukrainian state migration policy constructing and eliminating or reducing the external migration negative effects.

  16. Automatic Generation of Object Models for Process Planning and Control Purposes using an International standard for Information Exchange

    Directory of Open Access Journals (Sweden)

    Petter Falkman

    2003-10-01

    Full Text Available In this paper a formal mapping between static information models and dynamic models is presented. The static information models are given according to an international standard for product, process and resource information exchange, (ISO 10303-214. The dynamic models are described as Discrete Event Systems. The product, process and resource information is automatically converted into product routes and used for simulation, controller synthesis and verification. A high level language, combining Petri nets and process algebra, is presented and used for speci- fication of desired routes. A main implication of the presented method is that it enables the reuse of process information when creating dynamic models for process control. This method also enables simulation and verification to be conducted early in the development chain.

  17. New models of radical polymerization with branching and scission predicting molecular weight distribution in tubular and series of continuous stirred tank reactors allowing for multiradicals and gelation

    NARCIS (Netherlands)

    Yaghini, N.; Iedema, P.D.

    2015-01-01

    Modeling of the mol. wt. distribution (MWD) of low-​d. Polyethylene (ldPE) has been carried out for a tubular reactor under realistic non-​isothermal conditions and for a series of CSTR's. The model allows for the existence of multiradicals and the occurrence of gelation. The deterministic model is

  18. Gelation of Oil upon Contact with Water: A Bioinspired Scheme for the Self-Repair of Oil Leaks from Underwater Tubes.

    Science.gov (United States)

    Oh, Hyuntaek; Yaraghi, Nicholas; Raghavan, Srinivasa R

    2015-05-19

    Molecular organogelators convert oils into gels by forming self-assembled fibrous networks. Here, we demonstrate that such gelation can be activated by contacting the oil with an immiscible solvent (water). Our gelator is dibenzylidene sorbitol (DBS), which forms a low-viscosity sol when added to toluene containing a small amount of dimethyl sulfoxide (DMSO). Upon contact with water, DMSO partitions into the water, activating gelation of DBS in the toluene. The gel grows from the oil/water interface and slowly envelops the oil phase. We have exploited this effect for the self-repair of oil leaks from underwater tubes. When a DBS/toluene/DMSO solution flows through the tube, it forms a gel selectively at the leak point, thereby plugging the leak and restoring flow. Our approach is reminiscent of wound-sealing via blood-clotting: there also, inactive gelators in blood are activated at the wound site into a fibrous network, thereby plugging the wound and restoring blood flow.

  19. Effect of extraction pH on heat-induced aggregation, gelation and microstructure of protein isolate from quinoa (Chenopodium quinoa Willd)

    NARCIS (Netherlands)

    Ruiz, Geraldine Avila; Xiao, Wukai; Boekel, van Tiny; Minor, Marcel; Stieger, Markus

    2016-01-01

    The aim of this study was to determine the influence of extraction pH on heat-induced aggregation, gelation and microstructure of suspensions of protein isolates extracted from quinoa (Chenopodium quinoa Willd). Quinoa seed protein was extracted by alkaline treatment at various pH values (pH 8

  20. Advanced Nursing Process quality: Comparing the International Classification for Nursing Practice (ICNP) with the NANDA-International (NANDA-I) and Nursing Interventions Classification (NIC).

    Science.gov (United States)

    Rabelo-Silva, Eneida Rejane; Dantas Cavalcanti, Ana Carla; Ramos Goulart Caldas, Maria Cristina; Lucena, Amália de Fátima; Almeida, Miriam de Abreu; Linch, Graciele Fernanda da Costa; da Silva, Marcos Barragan; Müller-Staub, Maria

    2017-02-01

    To assess the quality of the advanced nursing process in nursing documentation in two hospitals. Various standardised terminologies are employed by nurses worldwide, whether for teaching, research or patient care. These systems can improve the quality of nursing records, enable care continuity, consistency in written communication and enhance safety for patients and providers alike. Cross-sectional study. A total of 138 records from two facilities (69 records from each facility) were analysed, one using the NANDA-International and Nursing Interventions Classification terminology (Centre 1) and one the International Classification for Nursing Practice (Centre 2), by means of the Quality of Diagnoses, Interventions, and Outcomes instrument. Quality of Diagnoses, Interventions, and Outcomes scores range from 0-58 points. Nursing records were dated 2012-2013 for Centre 1 and 2010-2011 for Centre 2. Centre 1 had a Quality of Diagnoses, Interventions, and Outcomes score of 35·46 (±6·45), whereas Centre 2 had a Quality of Diagnoses, Interventions, and Outcomes score of 31·72 (±4·62) (p Nursing Diagnoses as Process' dimension, whereas in the 'Nursing Diagnoses as Product', 'Nursing Interventions' and 'Nursing Outcomes' dimensions, Centre 1 exhibited superior performance; acceptable reliability values were obtained for both centres, except for the 'Nursing Interventions' domain in Centre 1 and the 'Nursing Diagnoses as Process' and 'Nursing Diagnoses as Product' domains in Centre 2. The quality of nursing documentation was superior at Centre 1, although both facilities demonstrated moderate scores considering the maximum potential score of 58 points. Reliability analyses showed satisfactory results for both standardised terminologies. Nursing leaders should use a validated instrument to investigate the quality of nursing records after implementation of standardised terminologies. © 2016 John Wiley & Sons Ltd.

  1. Proceedings of the international symposium on control and optimization in minerals, metals and materials processing

    International Nuclear Information System (INIS)

    Hodouin, D.; Bazin, C.; Desbiens, A.

    1999-01-01

    This is the first symposium on Process optimization and Control in Ore Processing, Extractive Metallurgy and Material Science ever sponsored by Metsoc. Sure enough, papers dealing with these topics are regularly presented at the Annual Conference of Metallurgists, but they have always been, so far, scattered through different symposia dealing with specific mineral or metallurgical processes. The novelty, at this symposium, is that our central theme reflects the methods rather than the processes, a change of focus that should foster interdisciplinary exchanges in Metallurgical Engineering. The various methods reviewed in the symposium proceedings are presented in four chapters covering the following topics: data acquisition and filtering, process monitoring; process modelling; process control; and process optimization. We hope that the 41 papers collected in this volume can sensitize the reader to the importance of modern data processing techniques for the valorization of available process data to improve the metallurgical and economic efficiency of industrial processes. They should also incite production managers, research directors and educational leaders to expand their efforts in the field

  2. Internal State Dependent Odor Processing and Perception—The Role of Neuromodulation in the Fly Olfactory System

    Directory of Open Access Journals (Sweden)

    Sercan Sayin

    2018-01-01

    Full Text Available Animals rely heavily on their sense of olfaction to perform various vital interactions with an ever-in-flux environment. The turbulent and combinatorial nature of air-borne odorant cues demands the employment of various coding strategies, which allow the animal to attune to its internal needs and past or present experiences. Furthermore, these internal needs can be dependent on internal states such as hunger, reproductive state and sickness. Neuromodulation is a key component providing flexibility under such conditions. Understanding the contributions of neuromodulation, such as sensory neuron sensitization and choice bias requires manipulation of neuronal activity on a local and global scale. With Drosophila's genetic toolset, these manipulations are feasible and even allow a detailed look on the functional role of classical neuromodulators such as dopamine, octopamine and neuropeptides. The past years unraveled various mechanisms adapting chemosensory processing and perception to internal states such as hunger and reproductive state. However, future research should also investigate the mechanisms underlying other internal states including the modulatory influence of endogenous microbiota on Drosophila behavior. Furthermore, sickness induced by pathogenic infection could lead to novel insights as to the neuromodulators of circuits that integrate such a negative postingestive signal within the circuits governing olfactory behavior and learning. The enriched emporium of tools Drosophila provides will help to build a concrete picture of the influence of neuromodulation on olfaction and metabolism, adaptive behavior and our overall understanding of how a brain works.

  3. Process Modelling of Curing Process-Induced Internal Stress and Deformation of Composite Laminate Structure with Elastic and Viscoelastic Models

    Science.gov (United States)

    Li, Dongna; Li, Xudong; Dai, Jianfeng

    2018-06-01

    In this paper, two kinds of transient models, the viscoelastic model and the linear elastic model, are established to analyze the curing deformation of the thermosetting resin composites, and are calculated by COMSOL Multiphysics software. The two models consider the complicated coupling between physical and chemical changes during curing process of the composites and the time-variant characteristic of material performance parameters. Subsequently, the two proposed models are implemented respectively in a three-dimensional composite laminate structure, and a simple and convenient method of local coordinate system is used to calculate the development of residual stresses, curing shrinkage and curing deformation for the composite laminate. Researches show that the temperature, degree of curing (DOC) and residual stresses during curing process are consistent with the study in literature, so the curing shrinkage and curing deformation obtained on these basis have a certain referential value. Compared the differences between the two numerical results, it indicates that the residual stress and deformation calculated by the viscoelastic model are more close to the reference value than the linear elastic model.

  4. Internal mechanisms underlying anticipatory language processing: Evidence from event-related-potentials and neural oscillations.

    Science.gov (United States)

    Li, Xiaoqing; Zhang, Yuping; Xia, Jinyan; Swaab, Tamara Y

    2017-07-28

    Although numerous studies have demonstrated that the language processing system can predict upcoming content during comprehension, there is still no clear picture of the anticipatory stage of predictive processing. This electroencephalograph study examined the cognitive and neural oscillatory mechanisms underlying anticipatory processing during language comprehension, and the consequences of this prediction for bottom-up processing of predicted/unpredicted content. Participants read Mandarin Chinese sentences that were either strongly or weakly constraining and that contained critical nouns that were congruent or incongruent with the sentence contexts. We examined the effects of semantic predictability on anticipatory processing prior to the onset of the critical nouns and on integration of the critical nouns. The results revealed that, at the integration stage, the strong-constraint condition (compared to the weak-constraint condition) elicited a reduced N400 and reduced theta activity (4-7Hz) for the congruent nouns, but induced beta (13-18Hz) and theta (4-7Hz) power decreases for the incongruent nouns, indicating benefits of confirmed predictions and potential costs of disconfirmed predictions. More importantly, at the anticipatory stage, the strongly constraining context elicited an enhanced sustained anterior negativity and beta power decrease (19-25Hz), which indicates that strong prediction places a higher processing load on the anticipatory stage of processing. The differences (in the ease of processing and the underlying neural oscillatory activities) between anticipatory and integration stages of lexical processing were discussed with regard to predictive processing models. Copyright © 2017 Elsevier Ltd. All rights reserved.

  5. Modeling of secondary emission processes in the negative ion based electrostatic accelerator of the International Thermonuclear Experimental Reactor

    OpenAIRE

    G. Fubiani; H. P. L. de Esch; A. Simonin; R. S. Hemsworth

    2008-01-01

    The negative ion electrostatic accelerator for the neutral beam injector of the International Thermonuclear Experimental Reactor (ITER) is designed to deliver a negative deuterium current of 40 A at 1 MeV. Inside the accelerator there are several types of interactions that may create secondary particles. The dominating process originates from the single and double stripping of the accelerated negative ion by collision with the residual molecular deuterium gas (≃29% losses). The resulting seco...

  6. Business Process Risk Management, Compliance and Internal Control: A Research Agenda

    OpenAIRE

    Rikhardsson, Pall; Best, Peter; Green, Peter; Rosemann, Michael

    2006-01-01

    Integration of risk management and management control is emerging as an important area in the wake of the Sarbanes-Oxley Act and with ongoing development of frameworks such as the Enterprise Risk Management (ERM) framework from the Committee of Sponsoring Organizations of the Treadway Commission (COSO). Based on an inductive methodological approach using literature review and interviews with managers engaged in risk management and internal control projects, this paper identifies three main ar...

  7. Democratising the learning process: the use of Twitter in the teaching of Politics and International Relations

    OpenAIRE

    Blair, Alasdair

    2013-01-01

    The version attached to this record is the authors final peer reviewed version. The publishers final version of record can be found by following the DOI link. Twitter has become an established feature of the contemporary landscape. It has been used by, among others, politicians, political parties, governments, international organisations, charities, think-tanks and individuals from academics to celebrities. Twitter has also been subject to a great deal of debate and analysis. This includes...

  8. Comparing internal and alliance-based new product development processes: case studies in the food industry

    OpenAIRE

    Olsen, Nina Veflen; Gripsrud, Geir

    2011-01-01

    This is the authors’ final, accepted and refereed manuscript to the article Companies may simultaneously pursue different new product development (NPD) strategies. This article reports a comparative two case design study of in-house NPD projects as well as alliance based NPD projects in a food company. Two contradicting proposition’s of the efficiency of NPD in an alliance compared to NPD performed internally are stated, and the findings indicate that the alliance based NPD solution create...

  9. Comparing internal and alliance-based new product development processes: case studies in the food industry

    OpenAIRE

    Olsen, Nina Veflen; Gripsrud, Geir

    2011-01-01

    Companies may simultaneously pursue different new product development (NPD) strategies. This article reports a comparative two case design study of in-house NPD projects as well as alliance based NPD projects in a food company. Two contradicting proposition’s of the efficiency of NPD in an alliance compared to NPD performed internally are stated, and the findings indicate that the alliance based NPD solution creates a better context for NPD than the in-house solution. Less forwarding of unsol...

  10. The process of learning from emergency preparedness cooperation in international schools

    OpenAIRE

    Pham, Hanh

    2014-01-01

    Master's thesis in Risk management and societal safety The cooperation between schools and organizations can encourage schools to learn about safety procedures and preparation for emergencies to improve the school emergency preparedness. In the international schools in Stavanger, learning from emergency preparedness cooperation can be optimized when knowledge creation contributes to improve the school capability and update or change the school emergency preparedness activities. However, de...

  11. The macrodynamics of international migration as a sociocultural diffusion process. Part A: theory.

    Science.gov (United States)

    Diamantides, N D

    1992-11-01

    "This study formulates a model of the macrodynamics of international migration using a differential equation to capture the push-pull forces that propel it. The model's architecture rests on the functioning of information feedback between settled friends and family at the destination and potential emigrants at the origin." The author tests the model using data on Greek emigration to the United States since 1820 and on total emigration from Cyprus since 1946. excerpt

  12. EFFECT OF DEXTRAN-graft-POLYACRYLAMIDE INTERNAL STRUCTURE ON FLOCCULATION PROCESS PARAMETERS

    International Nuclear Information System (INIS)

    Bezugla, T.; Kutsevol, N.; Shyichuk, A.; Ziolkowska, D.

    2008-01-01

    Dextran-graft-Polyacrylamide copolymers (D-g-PAA) of brush-like architecture were tested as flocculation aids in the model kaolin suspensions. Due to expanded conformation the D-g-PAA copolymers are more effective flocculants than individual PAA with close molecular mass. The internal structure of D-g-PAA copolymers which is determined by number and length of grafted PAA chains, the distance between grafts, etc., has the significant influence on flocculation behavior of such polymers

  13. Analysis of International Monetary Fund under conditions of globalization of economic processes

    Directory of Open Access Journals (Sweden)

    V.V. Ksendzuk

    2016-06-01

    Full Text Available Globalization in the economy requires proper management of countries' financial resources as the regulation of international financial market is one of the most important tasks of the successful development of the world economy and individual national economies. The International Monetary Fund since the beginning of its creation was intended to regulate the financial situation in the post-war period in world space. In present conditions of information development of the world economic system the role and importance of international financial institutions are changing. Thus, the policies and activities of the IMF are increasingly criticized, that is substantiated and requires some restructuring and reforming areas of the Fund activity. During the research the basic aspects of IMF activities in 2015 have been analyzed and the suggestions for its further effective development have been presented. In particular, it is advisable to use the specific individual approach to the problems of particular economies and to view the sizes of quotas and their functional purposes that will allow to develop new funding mechanisms that are based on social and ecological needs of society. This, in turn, will reduce the impact of developed countries on the activities of the financial institution

  14. Proceedings of the First International Research Workshop for Process Improvement in Small Settings, 2005

    National Research Council Canada - National Science Library

    Garcia, Suzanne; Graettinger, Caroline; Kost, Keith

    2006-01-01

    ... enterprises, small organizations within large companies, and small projects. The presentations addressed starting and sustaining process improvement, qualitative and quantitative studies, and using Capability Maturity Model Integration (CMMI...

  15. Proceedings of the First International Research Workshop for Process Improvement in Small Settings, 2005

    National Research Council Canada - National Science Library

    Garcia, Suzanne; Graettinger, Caroline; Kost, Keith

    2006-01-01

    .... Attendees from Australia, Canada, Chile, China, Germany, Ireland, India, Japan, Malaysia, Mexico, Spain, and the United States discussed the challenges of process improvement in small and medium size...

  16. IMPACT OF THE CONVERGENCE PROCESS TO INTERNATIONAL FINANCIAL REPORTING STANDARDS ON THE VALUE RELEVANCE OF FINANCIAL INFORMATION

    Directory of Open Access Journals (Sweden)

    Marcelo Alvaro da Silva Macedo

    2012-11-01

    Full Text Available Law 11.638/07 marked the start of a series of changes in the laws that regulate Brazilian accounting practices. The main reason for these changes is the convergence process of local with international accounting standards. As a result of Law 11.638/07, the legal precedent was established to achieve convergence. In that context, the aim of this study is to analyze the impact of the convergence process with international accounting standards on the relevance of financial information, based on data for 2007, without and with the alterations Law 11.638/07 introduced and according to the CPC Pronouncements, applicable as from 2008 onwards. Therefore, a value relevance study is used, applying regression analysis to annual stock price information (dependent variable and net profit per share (NPPS and net equity per share (NEPS as independent variables. The main results show that financial information on NPPS and NEPS for 2007, with and without the legal alterations, are relevant for the capital market. A comparison between both regressions used in the analysis, however, shows an information gain for financial information that includes the changes introduced in the first phase of the accounting convergence process with the international standards.

  17. Selective removals of heavy metals (Pb(2+), Cu(2+), and Cd(2+)) from wastewater by gelation with alginate for effective metal recovery.

    Science.gov (United States)

    Wang, Fei; Lu, Xingwen; Li, Xiao-yan

    2016-05-05

    A novel method that uses the aqueous sodium alginate solution for direct gelation with metal ions is developed for effective removal and recovery of heavy metals from industrial wastewater. The experimental study was conducted on Pb(2+), Cu(2+), and Cd(2+) as the model heavy metals. The results show that gels can be formed rapidly between the metals and alginate in less than 10 min and the gelation rates fit well with the pseudo second-order kinetic model. The optimum dosing ratio of alginate to the metal ions was found to be between 2:1 and 3:1 for removing Pb(2+) and around 4:1 for removing Cu(2+) and Cd(2+) from wastewater, and the metal removal efficiency by gelation increased as the solution pH increased. Alginate exhibited a higher gelation affinity toward Pb(2+) than Cu(2+) and Cd(2+), which allowed a selective removal of Pb(2+) from the wastewater in the presence of Cu(2+) and Cd(2+) ions. Chemical analysis of the gels suggests that the gelation mainly occurred between the metal ions and the -COO(-) and -OH groups on alginate. By simple calcination of the metal-laden gels at 700 °C for 1 h, the heavy metals can be well recovered as valuable resources. The metals obtained after the thermal treatment are in the form of PbO, CuO, and CdO nanopowders with crystal sizes of around 150, 50, and 100 nm, respectively. Copyright © 2016 Elsevier B.V. All rights reserved.

  18. A study of internal structure in components made by additive manufacturing process using 3 D X-ray tomography

    International Nuclear Information System (INIS)

    Raguvarun, K.; Balasubramaniam, Krishnan; Rajagopal, Prabhu; Palanisamy, Suresh; Nagarajah, Romesh; Kapoor, Ajay; Hoye, Nicholas; Curiri, Dominic

    2015-01-01

    Additive manufacturing methods are gaining increasing popularity for rapidly and efficiently manufacturing parts and components in the industrial context, as well as for domestic applications. However, except when used for prototyping or rapid visualization of components, industries are concerned with the load carrying capacity and strength achievable by additive manufactured parts. In this paper, the wire-arc additive manufacturing (AM) process based on gas tungsten arc welding (GTAW) has been examined for the internal structure and constitution of components generated by the process. High-resolution 3D X-ray tomography is used to gain cut-views through wedge-shaped parts created using this GTAW additive manufacturing process with titanium alloy materials. In this work, two different control conditions for the GTAW process are considered. The studies reveal clusters of porosities, located in periodic spatial intervals along the sample cross-section. Such internal defects can have a detrimental effect on the strength of the resulting AM components, as shown in destructive testing studies. Closer examination of this phenomenon shows that defect clusters are preferentially located at GTAW traversal path intervals. These results highlight the strong need for enhanced control of process parameters in ensuring components with minimal defects and higher strength

  19. A study of internal structure in components made by additive manufacturing process using 3 D X-ray tomography

    Energy Technology Data Exchange (ETDEWEB)

    Raguvarun, K., E-mail: prajagopal@iitm.ac.in; Balasubramaniam, Krishnan, E-mail: prajagopal@iitm.ac.in; Rajagopal, Prabhu, E-mail: prajagopal@iitm.ac.in [Centre for NDE, Indian Institute of Technology Madras, Chennai 600036, Tamilnadu (India); Palanisamy, Suresh [Swinburne University of Technology, Faculty of Engineering, Science and Technology, Hawthorn, Victoria 3122 Australia and Defence Materials Technology Centre, Hawthorn, Victoria 3122 (Australia); Nagarajah, Romesh; Kapoor, Ajay [Swinburne University of Technology, Faculty of Engineering, Science and Technology, Hawthorn, Victoria 3122 (Australia); Hoye, Nicholas; Curiri, Dominic [University of Wollongong, Faculty of Engineering, New South Wales 2522, Australia and Defence Materials Technology Centre, Hawthorn, Victoria 3122 (Australia)

    2015-03-31

    Additive manufacturing methods are gaining increasing popularity for rapidly and efficiently manufacturing parts and components in the industrial context, as well as for domestic applications. However, except when used for prototyping or rapid visualization of components, industries are concerned with the load carrying capacity and strength achievable by additive manufactured parts. In this paper, the wire-arc additive manufacturing (AM) process based on gas tungsten arc welding (GTAW) has been examined for the internal structure and constitution of components generated by the process. High-resolution 3D X-ray tomography is used to gain cut-views through wedge-shaped parts created using this GTAW additive manufacturing process with titanium alloy materials. In this work, two different control conditions for the GTAW process are considered. The studies reveal clusters of porosities, located in periodic spatial intervals along the sample cross-section. Such internal defects can have a detrimental effect on the strength of the resulting AM components, as shown in destructive testing studies. Closer examination of this phenomenon shows that defect clusters are preferentially located at GTAW traversal path intervals. These results highlight the strong need for enhanced control of process parameters in ensuring components with minimal defects and higher strength.

  20. Proceedings of the 48. conference of metallurgists : international symposium on process control applications in mining and metallurgical plants

    Energy Technology Data Exchange (ETDEWEB)

    Shang, H. [Laurentian Univ., Sudbury, ON (Canada). School of Engineering; Ryan, L. [Barrick Gold Corp., Toronto, ON (Canada); Kennedy, S. [Barrick Gold Corp., Dar Es Salaam (Tanzania, United Republic of)] (eds.)

    2009-07-01

    This international symposium on process control applications in mining and metallurgical plants was held to promote economic and sustainable production practices in Canadian industry applications. Topics related to process control in mining and metallurgical plants included expert systems, model-based control technology, as well as recent advances in simulation, monitoring, and optimization techniques. Methods of improving the process and energy efficiency of mining and metallurgical plants were discussed along with technologies designed to improve monitoring accuracy. The symposium was divided into the following 5 sessions: (1) expert system, control, and performance monitoring, (2) flotation, (3) metallurgical processes, modelling, (4) mining applications, and (5) monitoring, analysis. The symposium featured 23 presentations, of which 2 have been catalogued separately for inclusion in this database. refs., tabs., figs.

  1. 45 CFR 147.136 - Internal claims and appeals and external review processes.

    Science.gov (United States)

    2010-10-01

    ..., appropriateness, health care setting, level of care, or effectiveness of a covered benefit. (ii) The State process... pay the cost of the IRO for conducting the external review. Notwithstanding this requirement, the... not impose, for example, a $500 minimum claims threshold. (vi) The State process must allow at least...

  2. Editorial : Facilitating multi-stakeholder processes : balancing internal dynamics and institutional politics

    NARCIS (Netherlands)

    Brouwers, J.H.A.M.; Buchanan, K.S.; Brouwer, J.H.; Klerkx, L.W.A.; Schaap, M.; Borgne, Le E.

    2013-01-01

    This issue of the Knowledge Management for Development Journal focuses on the connection between the knowledge function in knowledge management for development (KM4D) and the facilitation function within multi stakeholder processes (MSPs). Both functions are key functions in innovation processes.

  3. Micellizationa and Gelation of Water Soluable Thermo-and Light-sensitive Block Copolymer Investigated by SANS

    Science.gov (United States)

    He, Lilin; Hu, Bin; Zhao, Bin

    2015-03-01

    Here we present an extensive small-angle neutron scattering (SANS) characterization of micellization and gelation of PEO-b-P(TEGEA-co-NBA) in deuterated water in a wide range of temperatures and concentrations before and after the removal of o-nitrobenzyl group by UV irradiation. Scattering data analysis indicated that unimers predominated in the solutions at low temperatures and concentrations. The polymer self-assembled into micelles with the P(TEGEA-co-NBA) block packed into the core and PEO forming the corona layer. A core-shell model was used to fit SANS data and obtain sizes and scattering length densities. Structural parameters such as the aggregation numbers, the radius of gyration of the chains in the shell region, the number of water molecules in the both regions were determined. The structural information combined with the rheological data were used to describe the phase behaviors of the diblock copolymer in aqueous solution.

  4. PREFACE: First International Workshop on Nonequilibrium Processes in Plasma Physics and Studies of Environment

    Science.gov (United States)

    Petrović, Z. Lj; Malović, G.; Tasić, M.; Nikitović, Ž.

    2007-06-01

    This volume is a collection of papers associated with a series of invited lectures presented at the First Workshop on Nonequilibrium processes in Plasma Physics and studies of Environment that was held at Mt Kopaonik in August 2006. The workshop originated as a part of the FP6 COE 026328 which had the basic aim of promoting centers of excellence in Western Balkan countries, to facilitate dissemination of their results and to help them establish themselves in the broader arena of European and international science. So the best way to achieve all those goals was to prepare a workshop associated with the local conference SPIG (Symposium on Physics of Ionized Gases) where the participants could attend sessions in which the host Laboratory presented progress reports and papers and thereby gain a full perspective of our results. At the same time this allowed participants in the COE the opportunity to compare their results with the results of external speakers and to gain new perspectives and knowledge. The program of the workshop was augmented by inviting some of our colleagues who visited the COE in recent years or have an active collaboration with a participating member. In that respect this volume is not only a proceedings of the workshop but a collection of papers related to the topic of the workshop: Non-equilibrium phenomena in plasmas and in the science of our environment. The idea is to offer review articles either summarizing a broader area of published or about to be published work or to give overviews showing preliminary results of the works in progress. The refereeing of the papers consisted of two parts, first in selection of the invitees and second in checking the submitted manuscripts. The papers were refereed to the standard of the Journal. As the program of the COE covers a wide area of topics from application of plasmas in nano- electronics to monitoring and removal of pollutants in the atmosphere, so the program of the workshop covered an even broader

  5. Biological Effects of Drug-Free Alginate Beads Cross-Linked by Copper Ions Prepared Using External Ionotropic Gelation.

    Science.gov (United States)

    Pavelková, M; Kubová, K; Vysloužil, J; Kejdušová, M; Vetchý, D; Celer, V; Molinková, D; Lobová, D; Pechová, A; Vysloužil, J; Kulich, P

    2017-05-01

    External ionotropic gelation offers a unique possibility to entrap multivalent ions in a polymer structure. The aim of this experimental study was to prepare new drug-free sodium alginate (ALG) particles cross-linked by Cu 2+ ions and to investigate their technological parameters (particle size, sphericity, surface topology, swelling capacity, copper content, release of Cu 2+ ions, mucoadhesivity) and biological activity (cytotoxicity and efficiency against the most common vaginal pathogens-Herpes simplex, Escherichia coli, Candida albicans) with respect to potential vaginal administration. Beads prepared from NaALG dispersions (3 or 4%) were cross-linked by Cu 2+ ions (0.5 or 1.0 M CuCl 2 ) using external ionotropic gelation. Prepared mucoadhesive beads with particle size over 1000 μm exhibited sufficient sphericity (all ˃0.89) and copper content (214.8-249.07 g/kg), which increased with concentration of polymer and hardening solution. Dissolution behaviour was characterized by extended burst effect, followed by 2 h of copper release. The efficiency of all samples against the most common vaginal pathogens was observed at cytotoxic Cu 2+ concentrations. Anti-HSV activity was demonstrated at a Cu 2+ concentration of 546 mg/L. Antibacterial activity of beads (expressed as minimum inhibition concentration, MIC) was influenced mainly by the rate of Cu 2+ release which was controlled by the extent of swelling capacity. Lower MIC values were found for E. coli in comparison with C. albicans. Sample ALG-3_1.0 exhibited the fastest copper release and was proved to be the most effective against both bacteria. This could be a result of its lower polymer concentration in combination with smaller particle size and thus larger surface area.

  6. Internal acid buffering in San Joaquin Valley fog drops and its influence on aerosol processing

    Science.gov (United States)

    Collett, Jeffrey L.; Hoag, Katherine J.; Rao, Xin; Pandis, Spyros N.

    Although several chemical pathways exist for S(IV) oxidation in fogs and clouds, many are self-limiting: as sulfuric acid is produced and the drop pH declines, the rates of these pathways also decline. Some of the acid that is produced can be buffered by uptake of gaseous ammonia. Additional internal buffering can result from protonation of weak and strong bases present in solution. Acid titrations of high pH fog samples (median pH=6.49) collected in California's San Joaquin Valley reveal the presence of considerable internal acid buffering. In samples collected at a rural location, the observed internal buffering could be nearly accounted for based on concentrations of ammonia and bicarbonate present in solution. In samples collected in the cities of Fresno and Bakersfield, however, significant additional, unexplained buffering was present over a pH range extending from approximately four to seven. The additional buffering was found to be associated with dissolved compounds in the fogwater. It could not be accounted for by measured concentrations of low molecular weight ( C1- C3) carboxylic acids, S(IV), phosphate, or nitrophenols. The amount of unexplained buffering in individual fog samples was found to correlate strongly with the sum of sample acetate and formate concentrations, suggesting that unmeasured organic species may be important contributors. Simulation of a Bakersfield fog episode with and without the additional, unexplained buffering revealed a significant impact on the fog chemistry. When the additional buffering was included, the simulated fog pH remained 0.3-0.7 pH units higher and the amount of sulfate present after the fog evaporated was increased by 50%. Including the additional buffering in the model simulation did not affect fogwater nitrate concentrations and was found to slightly decrease ammonium concentrations. The magnitude of the buffering effect on aqueous sulfate production is sensitive to the amount of ozone present to oxidize S

  7. Internalization, Trafficking, Intracellular Processing and Actions of Antibody-Drug Conjugates.

    Science.gov (United States)

    Xu, Shi

    2015-11-01

    This review discusses the molecular mechanism involved in the targeting and delivery of antibody-drug conjugates (ADCs), the new class of biopharmaceuticals mainly designed for targeted cancer therapy. this review goes over major progress in preclinical and clinical studies of ADCs, in the past 5 years. The pharmacokinetics and pharmacodynamics of ADCs involve multiple mechanisms, including internalization of ADCs by target cells, intracellular trafficking, release of conjugated drugs, and payload. These mechanisms actually jointly determine the efficacy of ADCs. Therefore, the optimization of ADCs should take them as necessary rationales.

  8. The macrodynamics of international migration as a socio-cultural diffusion process. Part B: applications.

    Science.gov (United States)

    Diamantides, N D

    1992-12-01

    "This study formulates a model of the macrodynamics of international migration using a differential equation to capture the push-pull forces that propel it. The model's architecture rests on the functioning of information feedback between settled friends and family at the destination and potential emigrants at the origin.... Two specific paradigms of diverse nature serve to demonstrate the model's tenets and pertinence, one being Greek emigration to the United States since 1820, and the other total out-migration from Cyprus since statehood (1946)." excerpt

  9. Proceedings of the international society for optical engineering biomedical image processing 2

    International Nuclear Information System (INIS)

    Bovik, A.G.; Howard, V.

    1991-01-01

    This book contains the proceedings of biomedical image processing. Topics covered include: Filtering and reconstruction of biomedical images; analysis, classification and recognition of biomedical images; and 3-D microscopy

  10. Process of forming a sol-gel/metal hydride composite

    Science.gov (United States)

    Congdon, James W [Aiken, SC

    2009-03-17

    An external gelation process is described which produces granules of metal hydride particles contained within a sol-gel matrix. The resulting granules are dimensionally stable and are useful for applications such as hydrogen separation and hydrogen purification. An additional coating technique for strengthening the granules is also provided.

  11. Microstructure and Macrosegregation Study of Directionally Solidified Al-7Si Samples Processed Terrestrially and Aboard the International Space Station

    Science.gov (United States)

    Angart, Samuel; Erdman, R. G.; Poirier, David R.; Tewari, S.N.; Grugel, R. N.

    2014-01-01

    This talk reports research that has been carried out under the aegis of NASA as part of a collaboration between ESA and NASA for solidification experiments on the International Space Station (ISS). The focus has been on the effect of convection on the microstructural evolution and macrosegregation in hypoeutectic Al-Si alloys during directional solidification (DS). The DS-experiments have been carried out under 1-g at Cleveland State University (CSU) and under low-g on the International Space Station (ISS). The thermal processing-history of the experiments is well defined for both the terrestrially-processed samples and the ISS-processed samples. We have observed that the primary dendrite arm spacings of two samples grown in the low-g environment of the ISS show good agreement with a dendrite-growth model based on diffusion controlled growth. The gravity-driven convection (i.e., thermosolutal convection) in terrestrially grown samples has the effect of decreasing the primary dendrite arm spacings and causes macrosgregation. In order to process DS-samples aboard the ISS, dendritic-seed crystals have to partially remelted in a stationary thermal gradient before the DS is carried out. Microstructural changes and macrosegregation effects during this period are described.

  12. The internal processes and behavioral dynamics of hospital boards: an exploration of differences between high- and low-performing hospitals.

    Science.gov (United States)

    Kane, Nancy M; Clark, Jonathan R; Rivenson, Howard L

    2009-01-01

    Nonprofit hospital boards are under increasing pressure to improve financial, clinical, and charitable and community benefit performance. Most research on board effectiveness focuses on variables measuring board structure and attributes associated with competing ideal models of board roles. However, the results do not provide clear evidence that one role is superior to another and suggest that in practice boards pursue hybrid roles. Board dynamics and processes have received less attention from researchers, but emerging theoretical frameworks highlight them as key to effective corporate governance. We explored differences in board processes and behavioral dynamics between financially high- and low-performing hospitals, with the goal of developing a better understanding of the best board practices in nonprofit hospitals. A comparative case study approach allowed for in-depth, qualitative assessments of how the internal workings of boards differ between low- and high-performing facilities. Boards of hospitals with strong financial performance exhibited behavioral dynamics and internal processes that differed in important ways from those of hospitals with poor financial performance. Boards need to actively attend to key processes and foster positive group dynamics in decision making to be more effective in governing hospitals.

  13. A High Current Density Low Cost Niobium 3 Tin Titanium Doped Conductor Utilizing A Novel Internal Tin Process

    International Nuclear Information System (INIS)

    Bruce A Zeitlin

    2005-01-01

    An internal tin conductor has been developed using a Mono Element Internal Tin (MEIT) with an integral Nb barrier surrounding the Nb filaments. High current densities of 3000 A/mm2+ at 12 T and 1800 A/mm2 at 15 T have been achieved in conductors as small as 0.152 mm with the use of Nb7.5Ta filaments and Ti in the Sn core. In contrast, conductors with pure Nb and Ti in the Sn achieved 2700 A/mm2 at 12 T. Two internal fins, developed and patented on the project, were introduced into the filament array and reduced the effective filament diameter (Deff) by 38%. Additional fins will further reduce Deff The conductor was produced from 152.4 mm diameter billets to produce wire as small as 0.152 mm. The process promises be scaleable to 304 mm diameter billets yielding wire of 0.304 mm diameter. The MEIT process wire was easy to draw with relatively few breaks. The cost of this conductor in large production quantities based on the cost model presented could meet the 1.5 $/kilo amp meter(KAM) target of the HEP community

  14. Investigating steam penetration using thermometric methods in dental handpieces with narrow internal lumens during sterilizing processes with non-vacuum or vacuum processes.

    Science.gov (United States)

    Winter, S; Smith, A; Lappin, D; McDonagh, G; Kirk, B

    2017-12-01

    Dental handpieces are required to be sterilized between patient use. Vacuum steam sterilization processes with fractionated pre/post-vacuum phases or unique cycles for specified medical devices are required for hollow instruments with internal lumens to assure successful air removal. Entrapped air will compromise achievement of required sterilization conditions. Many countries and professional organizations still advocate non-vacuum sterilization processes for these devices. To investigate non-vacuum downward/gravity displacement, type-N steam sterilization of dental handpieces, using thermometric methods to measure time to achieve sterilization temperature at different handpiece locations. Measurements at different positions within air turbines were undertaken with thermocouples and data loggers. Two examples of widely used UK benchtop steam sterilizers were tested: a non-vacuum benchtop sterilizer (Little Sister 3; Eschmann, Lancing, UK) and a vacuum benchtop sterilizer (Lisa; W&H, Bürmoos, Austria). Each sterilizer cycle was completed with three handpieces and each cycle in triplicate. A total of 140 measurements inside dental handpiece lumens were recorded. The non-vacuum process failed (time range: 0-150 s) to reliably achieve sterilization temperatures within the time limit specified by the international standard (15 s equilibration time). The measurement point at the base of the handpiece failed in all test runs (N = 9) to meet the standard. No failures were detected with the vacuum steam sterilization type B process with fractionated pre-vacuum and post-vacuum phases. Non-vacuum downward/gravity displacement, type-N steam sterilization processes are unreliable in achieving sterilization conditions inside dental handpieces, and the base of the handpiece is the site most likely to fail. Copyright © 2017 The Healthcare Infection Society. Published by Elsevier Ltd. All rights reserved.

  15. Coupling the Alkaline-Surfactant-Polymer Technology and the Gelation Technology to Maximize Oil Production

    Energy Technology Data Exchange (ETDEWEB)

    Malcolm Pitts; Jie Qi; Dan Wilson; Phil Dowling; David Stewart; Bill Jones

    2005-12-01

    Gelation technologies have been developed to provide more efficient vertical sweep efficiencies for flooding naturally fractured oil reservoirs or reservoirs with different sand lenses with high permeability contrast. The field proven alkaline-surfactant-polymer technology economically recovers 15% to 25% OOIP more crude oil than waterflooding froin swept pore space of an oil reservoir. However, alkaline-surfactant-polymer technology is not amenable to naturally fractured reservoirs or reservoirs with high permeability contrast zones because much of injected solution bypasses target pore space containing oil. This work investigates whether combining these two technologies could broaden applicability of alkaline-surfactant-polymer flooding into these reservoirs. Fluid-fluid interaction with different gel chemical compositions and alkaline-surfactant-polymer solution with pH values ranging from 9.2 to 12.9 have been tested. Aluminum-polyacrylamide gels are not stable to alkaline-surfactant-polymer solutions at any pH. Chromium-polyacrylamide gels with polymer to chromium ion ratios of 25 or greater were stable to alkaline-surfactant-polymer solutions if solution pH was 10.6 or less. When the polymer to chromium ion was 15 or less, chromium-polyacrylamide gels were stable to alkaline-surfactant-polymer solutions with pH values up to 12.9. Chromium-xanthan gum gels were stable to alkaline-surfactant-polymer solutions with pH values of 12.9 at the polymer to chromium ion ratios tested. Silicate-polyacrylamide, resorcinol-formaldehyde, and sulfomethylated resorcinol-formaldehyde gels were also stable to alkaline-surfactant-polymer solutions with pH values ranging from 9.2 to 12.9. Iron-polyacrylamide gels were immediately destroyed when contacted with any of the alkaline-surfactant-polymer solutions with pH values ranging from 9.2 to 12.9. Gel solutions under dynamic conditions of linear corefloods showed similar stability to alkaline-surfactant-polymer solutions as in

  16. Exploring challenges in the patient's discharge process from the internal medicine service: A qualitative study of patients' and providers' perceptions.

    Science.gov (United States)

    Pinelli, Vincent; Stuckey, Heather L; Gonzalo, Jed D

    2017-09-01

    In hospital-based medicine units, patients have a wide range of complex medical conditions, requiring timely and accurate communication between multiple interprofessional providers at the time of discharge. Limited work has investigated the challenges in interprofessional collaboration and communication during the patient discharge process. In this study, authors qualitatively assessed the experiences of internal medicine providers and patients about roles, challenges, and potential solutions in the discharge process, with a phenomenological focus on the process of collaboration. Authors conducted interviews with 87 providers and patients-41 providers in eight focus-groups, 39 providers in individual interviews, and seven individual patient interviews. Provider roles included physicians, nurses, therapists, pharmacists, care coordinators, and social workers. Interviews were audio-recorded and transcribed verbatim, followed by iterative review of transcripts using qualitative coding and content analysis. Participants identified several barriers related to interprofessional collaboration during the discharge process, including systems insufficiencies (e.g., medication reconciliation process, staffing challenges); lack of understanding others' roles (e.g., unclear which provider should be completing the discharge summary); information-communication breakdowns (e.g., inaccurate information communicated to the primary medical team); patient issues (e.g., patient preferences misaligned with recommendations); and poor collaboration processes (e.g., lack of structured interprofessional rounds). These results provide context for targeting improvement in interprofessional collaboration in medicine units during patient discharges. Implementing changes in care delivery processes may increase potential for accurate and timely coordination, thereby improving the quality of care transitions.

  17. Low-impedance internal linear inductive antenna for large-area flat panel display plasma processing

    International Nuclear Information System (INIS)

    Kim, K.N.; Jung, S.J.; Lee, Y.J.; Yeom, G.Y.; Lee, S.H.; Lee, J.K.

    2005-01-01

    An internal-type linear inductive antenna, that is, a double-comb-type antenna, was developed for a large-area plasma source having the size of 1020 mmx830 mm, and high density plasmas on the order of 2.3x10 11 cm -3 were obtained with 15 mTorr Ar at 5000 W of inductive power with good plasma stability. This is higher than that for the conventional serpentine-type antenna, possibly due to the low impedance, resulting in high efficiency of power transfer for the double-comb antenna type. In addition, due to the remarkable reduction of the antenna length, a plasma uniformity of less than 8% was obtained within the substrate area of 880 mmx660 mm at 5000 W without having a standing-wave effect

  18. The Role of Technology Spillovers in the Process of Water Pollution Abatement for Large International Firms

    Directory of Open Access Journals (Sweden)

    Luigi Aldieri

    2017-05-01

    Full Text Available The objective of this paper is to analyze the effects of technology externalities stemming from different technological sectors for international firms engaged both in water pollution abatement and in dirty activities. We present a theoretical framework and an empirical analysis based upon a dataset composed of worldwide R&D-intensive firms. In order to identify the technological proximity between the firms, we construct an original Mahalanobis environmental industry weight matrix, based on the construction of technological vectors for each firm, with European ecological patents distributed across more technology classes. Opportune econometric techniques that deal with the firms’ unobserved heterogeneity and the weak exogeneity of the explanatory variables are implemented. The findings show significant spillover effects on the productivity and environmental performance of the firms.

  19. OVERVIEW OF INTERNATIONAL PUBLICATIONS ON THE INNOVATION PROCESS: A BIBLIOMETRIC STUDY

    Directory of Open Access Journals (Sweden)

    Rodrigo Marques de Almeida Guerra

    2015-03-01

    Full Text Available Bibliometric Studies concepts. There were five stages for the configuration of this article: identification of the keyword, Innovation Process, and selection of the search criteria; selection of articles and listing them according to the number of citations under the search criteria; selection of the ten articles with the highest number of citations; analysis of the selected articles; and discussion about the conclusions. The study makes it possible to identify which are the main published articles on Innovation Process based on the number of citations, length of time and date, countries, areas of knowledge, journals, authors and universities of publication. According to the findings, it seems advisable for developing countries’ scholars to foster further research on Innovation Process, as well as more productions on Bibliometric Research as a whole.

  20. Innovation indicators: a survey of innovative activities in the international food processed industry

    Directory of Open Access Journals (Sweden)

    Vinicius Cardoso de Barros Fornari

    2015-02-01

    Full Text Available This paper seeks to combine traditional methods of measuring intensity with other alternative indicators to examine the dispersion of innovation activities in different industries and countries. The hypothesis that underlies the study lies in the fact that in the Food Processed Industry (IAP the traditional methods are insufficient to detect the core of the innovation process. As method, we analyzed patent data extracted from the twenty-five largest food processed companies in the world and suggested different indicators developed from the Pesquisa de Inovação Tecnológica (PINTEC, 2010 – for Brazilian companies – and the Community Innovation Survey (CIS, 2009 – for European Union companies. The results allowed us to establish relationships in three dimensions: (i the complexity of the innovative effort of the IAP; (ii the efforts to innovation in different countries are distinct and; (iii there is heterogeneity in country performance.

  1. International recommendations for national patient safety incident reporting systems: an expert Delphi consensus-building process.

    Science.gov (United States)

    Howell, Ann-Marie; Burns, Elaine M; Hull, Louise; Mayer, Erik; Sevdalis, Nick; Darzi, Ara

    2017-02-01

    Patient safety incident reporting systems (PSRS) have been established for over a decade, but uncertainty remains regarding the role that they can and ought to play in quantifying healthcare-related harm and improving care. To establish international, expert consensus on the purpose of PSRS regarding monitoring and learning from incidents and developing recommendations for their future role. After a scoping review of the literature, semi-structured interviews with experts in PSRS were conducted. Based on these findings, a survey-based questionnaire was developed and subsequently completed by a larger expert panel. Using a Delphi approach, consensus was reached regarding the ideal role of PSRSs. Recommendations for best practice were devised. Forty recommendations emerged from the Delphi procedure on the role and use of PSRS. Experts agreed reporting system should not be used as an epidemiological tool to monitor the rate of harm over time or to appraise the relative safety of hospitals. They agreed reporting is a valuable mechanism for identifying organisational safety needs. The benefit of a national system was clear with respect to medication error, device failures, hospital-acquired infections and never events as these problems often require solutions at a national level. Experts recommended training for senior healthcare professionals in incident investigation. Consensus recommendation was for hospitals to take responsibility for creating safety solutions locally that could be shared nationally. We obtained reasonable consensus among experts on aims and specifications of PSRS. This information can be used to reflect on existing and future PSRS, and their role within the wider patient safety landscape. The role of PSRS as instruments for learning needs to be elaborated and developed further internationally. Published by the BMJ Publishing Group Limited. For permission to use (where not already granted under a licence) please go to http://www.bmj.com/company/products-services/rights-and-licensing/.

  2. CFD analysis of a solid oxide fuel cell with internal reforming: Coupled interactions of transport, heterogeneous catalysis and electrochemical processes

    Science.gov (United States)

    Janardhanan, Vinod M.; Deutschmann, Olaf

    Direct internal reforming in solid oxide fuel cell (SOFC) results in increased overall efficiency of the system. Present study focus on the chemical and electrochemical process in an internally reforming anode supported SOFC button cell running on humidified CH 4 (3% H 2 O). The computational approach employs a detailed multi-step model for heterogeneous chemistry in the anode, modified Butler-Volmer formalism for the electrochemistry and Dusty Gas Model (DGM) for the porous media transport. Two-dimensional elliptic model equations are solved for a button cell configuration. The electrochemical model assumes hydrogen as the only electrochemically active species. The predicted cell performances are compared with experimental reports. The results show that model predictions are in good agreement with experimental observation except the open circuit potentials. Furthermore, the steam content in the anode feed stream is found to have remarkable effect on the resulting overpotential losses and surface coverages of various species at the three-phase boundary.

  3. Making sense of intercultural interaction processes in international joint venture settings

    DEFF Research Database (Denmark)

    Dao, Li

    , i.e. competence building interaction, decision making interaction, and socializing interaction, which is consistent with the three major processes of learning, power bargaining, and relationship building as suggested by IJV literature. Second, interaction processes appear to be shaped by individual...... approach toward decision making, a mutual learning attitude, the appreciation and strategic utilization of emergent ties between individual members put together in work settings, the proper implementation of consensus-facilitating mechanisms like ISO standards, and a holistic view of knowledge transfer...... in terms of core skills as well as non-core yet critically supporting skills like decision making and project/ time management....

  4. 1991 Second international symposium on the biological processing of coal: Proceedings

    International Nuclear Information System (INIS)

    1991-09-01

    This symposium was held to aid in the advancement of science and technology in the area of coal bioprocessing by facilitating the exchange of technical information and offering a forum for open discussion and review. The symposium was complemented by four workshops which introduced the attendees to the fundamentals of genetic, mass ampersand energy balances, process ampersand economic analysis, and advanced analytical techniques as they pertain to bioprocessing of coal. Eleven countries were represented, as were numerous universities, national laboratories, federal agencies and corporations. Topics discussed include desulfurization, coal dissolution, gene cloning, and enzyme activity. Individual projects are processed separately on the databases

  5. Bridging the Operational Divide: An Information-Processing Model of Internal Supply Chain Integration

    Science.gov (United States)

    Rosado Feger, Ana L.

    2009-01-01

    Supply Chain Management, the coordination of upstream and downstream flows of product, services, finances, and information from a source to a customer, has risen in prominence over the past fifteen years. The delivery of a product to the consumer is a complex process requiring action from several independent entities. An individual firm consists…

  6. An alternative internal control to improve the educational process in elementary school

    Directory of Open Access Journals (Sweden)

    Mercedes Piñera Montesino

    2003-03-01

    Full Text Available The article suggests how to achieve and maintain high indicators efficiency more than 600 centers studied tes, applying different alternativas, which convert to control democratic and participatory style of all the factors that have to do with the educational process at school.

  7. Does ownership affect the variability of the production process? Evidence from international courier services

    NARCIS (Netherlands)

    Hsieh, C.; Lazzarini, S.G.; Nickerson, J.A.; Laurini, M.

    2010-01-01

    A firm often must ensure that products or services it produces match customer expectations. We define variability as any deviation in a production process yielding products or services whose attributes differ from the firm's stated target specifications. Firms pursuing products marked by low

  8. International Student Mobility in Europe in the Context of the Bologna Process

    Science.gov (United States)

    Teichler, Ulrich

    2012-01-01

    The Bologna Process is the newest of a chain of activities stimulated by supra-national actors since the 1950s to challenge national borders in higher education in Europe. Now, the ministers in charge of higher education of the individual European countries agreed to promote a similar cycle-structure of study programmes and programmes based on the…

  9. Proceedings of INC 02. International Nuclear Conference 2002: Global Trends and Perspectives, Seminar V: Radiation Processing

    International Nuclear Information System (INIS)

    2002-01-01

    The papers discuss the folowing areas: radiation processing using low, medium and high energy electron beam, gamma and ultraviolet radiation; polymers blend; electron beam uses in wire, cables and polymers industry; studies of mechanical and tensile properties of elastomers / polymers blend

  10. Proceedings of the First International Research Workshop for Process Improvement in Small Settings, 2005

    Science.gov (United States)

    2006-01-01

    NeedsCONTINOUS IMPROVEMENT CYCLE Banco de Datos Organizaci ón Data Bank of the Organization ’s Projects Project Data Established Improvements Te m pl at es Te...25 From Bedini G, Alejandro. Calidad y conocimiento , Cartagena de Indias Colombia. CMU/SEI-2006-SR...135 4.3 A Pattern- Based Approach to Deploy Process Improvements in Small Settings

  11. Establishing an international reference image database for research and development in medical image processing

    NARCIS (Netherlands)

    Horsch, A.D.; Prinz, M.; Schneider, S.; Sipilä, O; Spinnler, K.; Vallée, J-P; Verdonck-de Leeuw, I; Vogl, R.; Wittenberg, T.; Zahlmann, G.

    2004-01-01

    INTRODUCTION: The lack of comparability of evaluation results is one of the major obstacles of research and development in Medical Image Processing (MIP). The main reason for that is the usage of different image datasets with different quality, size and Gold standard. OBJECTIVES: Therefore, one of

  12. Leadership Development as a Dialogic Process: The Rationale and Concept of an International Leadership Institute

    Science.gov (United States)

    Kedian, Jeremy; Giles, David; Morrison, Michele; Fletcher, Murray

    2016-01-01

    Rapidly changing educational contexts demand deft leadership responses. In this fluid environment, it is imperative that leadership learning models sound educational praxis. Such praxis necessitates the inclusion of participant voices within relational and dialogic processes that enable authentic, creative and collaborative thinking. This paper…

  13. Proposal to support the 4th international conference on nitrification and related processes (ICoN4)

    International Nuclear Information System (INIS)

    Klotz, Martin Gunter

    2016-01-01

    The 4th International Conference on Nitrification and Related Processes (ICoN4) commencing between June 27 and July 1, 2015, at the University of Alberta in Edmonton, Alberta, Canada brings together an international collection of academic, government, and private sector researchers of the global biogeochemical nitrogen cycle to share their scientific discoveries, innovations and pertinent societal impacts. The classical understanding of “nitrification” describes the two-step transformation of ammonium to nitrite and nitrite to nitrate; however, we now know from the analysis genome sequences, the application of ‘omics technologies, microbial ecology, biogeochemistry, and microbial physiology that the transformation of ammonium is not performed by a few particular groups of microorganisms nor is it confined to oxic environments. Past ICoN meetings have explored the interconnections between ammonium- and nitrite-consuming processes in all ecosystems, the emission of greenhouse gases by these processes and their control, and the intersection between intermediates of the nitrification process and other elemental cycles; this has generated tremendous progress in our understanding of the global nitrogen cycle and it has generated excitement in the next generation of N cycle researchers. Nitrification research has a long-standing connection to the Community Science Program of the DOE. Between 1999 and 2001, the JGI generated the first genome sequence of an ammonia-oxidizing bacterium, Nitrosomonas europaea ATCC 19718, and it has subsequently sequenced, or is in the process of sequencing over 50 additional genomes from ammonia-oxidizing bacteria, nitrite-oxidizing bacteria, and ammonia-oxidizing archaea. Autotrophic ammonia- and nitrite-transforming microorganisms play also a critical role in carbon cycling and sequestration in nearly all ecosystems. Not only do they control the concentration and speciation of biologically available N to plants and other

  14. Proposal to support the 4th international conference on nitrification and related processes (ICoN4)

    Energy Technology Data Exchange (ETDEWEB)

    Klotz, Martin Gunter [Univ. of North Carolina, Charlotte, NC (United States)

    2016-11-04

    The 4th International Conference on Nitrification and Related Processes (ICoN4) commencing between June 27 and July 1, 2015, at the University of Alberta in Edmonton, Alberta, Canada brings together an international collection of academic, government, and private sector researchers of the global biogeochemical nitrogen cycle to share their scientific discoveries, innovations and pertinent societal impacts. The classical understanding of “nitrification” describes the two-step transformation of ammonium to nitrite and nitrite to nitrate; however, we now know from the analysis genome sequences, the application of ‘omics technologies, microbial ecology, biogeochemistry, and microbial physiology that the transformation of ammonium is not performed by a few particular groups of microorganisms nor is it confined to oxic environments. Past ICoN meetings have explored the interconnections between ammonium- and nitrite-consuming processes in all ecosystems, the emission of greenhouse gases by these processes and their control, and the intersection between intermediates of the nitrification process and other elemental cycles; this has generated tremendous progress in our understanding of the global nitrogen cycle and it has generated excitement in the next generation of N cycle researchers. Nitrification research has a long-standing connection to the Community Science Program of the DOE. Between 1999 and 2001, the JGI generated the first genome sequence of an ammonia-oxidizing bacterium, Nitrosomonas europaea ATCC 19718, and it has subsequently sequenced, or is in the process of sequencing over 50 additional genomes from ammonia-oxidizing bacteria, nitrite-oxidizing bacteria, and ammonia-oxidizing archaea. Autotrophic ammonia- and nitrite-transforming microorganisms play also a critical role in carbon cycling and sequestration in nearly all ecosystems. Not only do they control the concentration and speciation of biologically available N to plants and other

  15. Proceedings of the third international conference on recent advances in material processing technology: book of abstracts

    International Nuclear Information System (INIS)

    Mannan, S.L.; Manisekar, K.; Lenin, N.; Ramanan, P.

    2013-01-01

    The objective of the conference was to disseminate information on the latest trends and global research in manufacturing and material processing techniques. This conference provided a forum to share information on technologies, concepts, and techniques to improve the quality of the products and productivity. The deliberations at the conference provided discussion on Casting Technology, Forming processes, Manufacturing Techniques, Simulation and Modeling Techniques, Tools and Precision Engineering, Condition Monitoring, Composites, Optimization Techniques, Surface Engineering, Welding Technology, Nano Technology, Recycle Technology, Fuel Cell Technology, Sensors and Robotics, Materials for Energy Engineering, Rapid Protyping, Eco-Manufacturing Systems, Functionally Graded Materials, Non-Destructive Evaluation, Materials Development and Evaluation etc. Articles relevant to INIS are indexed separately

  16. International perspectives on the influence of structure and process of weaning from mechanical ventilation

    DEFF Research Database (Denmark)

    Rose, Louise; Blackwood, Bronagh; Burns, Suzanne M

    2011-01-01

    , roles, and responsibilities for weaning in intensive care units of selected countries. Results Australia, New Zealand, Denmark, Norway, Sweden, and the United Kingdom showed similarities in critical care provision, structure, skill mix, and staffing ratios in intensive care units. Weaning...... in these countries is generally a collaborative process between nurses and physicians. Notable differences in intensive care units in the United States were the frequent use of an open structure and inclusion of respiratory therapists on the intensive care unit’s health care team. Nurses may be excluded from direct...... management of ventilator weaning in some institutions, as this role is primarily assumed by respiratory therapists guided by medical directives. Availability of critical care beds was highest in the United States and lowest in the United Kingdom. Conclusion Context and processes of care that could influence...

  17. Summary of research on microbiological processes. International Energy Agency Subtask D, final report

    Energy Technology Data Exchange (ETDEWEB)

    Winters, A.L.

    1992-09-01

    Storage of thermal energy in aquifers has obvious benefits of saving energy and decreasing the consumption of fossil fuels. However, aquifer thermal energy storage (ATES), which involves groundwater aquifers as the storage medium for heat or chill, impinges on the environment. A literature review of pertinent microbiology publications (Hicks and Stewart, 1988) identified the potential for the interaction of ATES systems and microbiological processes to create a source of infectious diseases and the potential for damage to the environment. In addition, the review identified a potential for microbiological processes to develop conditions that would interfere with the operation of an ATES system. As a result of this research effort, investigators from Finland, Germany, Switzerland, and the United States have examined several ATES systems in operation and have observed that the ATES systems studied do not contribute to infectious disease transmission, do not adversely affect the environment, and do not contribute significantly to biofouling or biocorrosion.

  18. The accounting cooperative society in a process of countable international harmonization. The case of Spain

    OpenAIRE

    Polo Garrido, Fernando

    2006-01-01

    Cooperatives meet differentiated purposes since their origins. In the same way as other economic units, they need to make use of accounting. So the study of cooperative accounting arouse interest from distant time, as it is shown by the fact that in Spain a monograph book about cooperative accounting came out in 1925. The present work studies the cooperative accounting in Spain from the beginnings until nowadays. Currently we are living a process of accounting reform, for this reason we analy...

  19. On the integration developmental characteristics as a form of international policy in the context of modern globalization processes

    Directory of Open Access Journals (Sweden)

    Bostan Sergii Ivanovich

    2014-12-01

    Full Text Available Under globalization of the world community, there are new opportunities and potential threats to the current system of international relations, collective security and geopolitical development of different regions. Integration and regionalization, consolidation and separatism entered upon the agenda of the political present. The integration process becomes one of the variations of peaceful and mutually beneficial solution to the question of the globalization influence of uneven development of the world regions, the fight against global problems of humanity, discrimination and intolerance, spread the values of democracy, rights, freedom and equality.

  20. World Nuclear Association (WNA) internationally standardized reporting (checklist) on the sustainable development performance of uranium mining and processing sites

    International Nuclear Information System (INIS)

    Harris, F.

    2014-01-01

    The World Nuclear Association (WNA) has developed internationally standardized reporting (‘Checklist’) for uranium mining and processing sites. This reporting is to achieve widespread utilities/miners agreement on a list of topics/indicators for common use in demonstrating miners’ adherence to strong sustainable development performance. Nuclear utilities are often required to evaluate the sustainable development performance of their suppliers as part of a utility operational management system. In the present case, nuclear utilities are buyers of uranium supplies from uranium miners and such purchases are often achieved through the utility uranium or fuel supply management function. This Checklist is an evaluation tool which has been created to collect information from uranium miners’ available annual reports, data series, and measurable indicators on a wide range of sustainable development topics to verify that best practices in this field are implemented throughout uranium mining and processing sites. The Checklist has been developed to align with the WNA’s policy document Sustaining Global Best Practices in Uranium Mining and Processing: Principles for Managing Radiation, Health and Safety, and Waste and the Environment which encompasses all applicable aspects of sustainable development to uranium mining and processing. The eleven sections of the Checklist are: 1. Adherence to Sustainable Development; 2. Health, Safety and Environmental Protection; 3. Compliance; 4. Social Responsibility and Stakeholder Engagement; 5. Management of Hazardous Materials; 6. Quality Management Systems; 7. Accidents and Emergencies; 8. Transport of Hazardous Materials; 9. Systematic Approach to Training; 10. Security of Sealed Radioactive Sources and Nuclear Substances; 11. Decommissioning and Site Closure. The Checklist benefits from many years of nuclear utility experience in verifying the sustainable development performance of uranium mining and processing sites. This

  1. Effect of Weekend Admissions on the Treatment Process and Outcomes of Internal Medicine Patients: A Nationwide Cross-Sectional Study.

    Science.gov (United States)

    Huang, Chun-Che; Huang, Yu-Tung; Hsu, Nin-Chieh; Chen, Jin-Shing; Yu, Chong-Jen

    2016-02-01

    Many studies address the effect of weekend admission on patient outcomes. This population-based study aimed to evaluate the relationship between weekend admission and the treatment process and outcomes of general internal medicine patients in Taiwan.A total of 82,340 patients (16,657 weekend and 65,683 weekday admissions) aged ≥20 years and admitted to the internal medicine departments of 17 medical centers between 2007 and 2009 were identified from the Taiwan National Health Insurance Research Database. A generalized estimating equation (GEE) analysis was used to compare patients admitted on weekends and those admitted on weekdays.Patients who were admitted on weekends were more likely to undergo intubation (odds ratio [OR]: 1.27; 95% confidence interval [CI]: 1.16-1.39; P internal medicine patients who were admitted on weekends experienced more intensive care procedures and higher ICU admission, in-hospital mortality, and treatment cost. Intensive care utilization may serve as early indicator of poorer outcomes and a potential entry point to offer preventive intervention before proceeding to intensive treatment.

  2. Using X-ray microbeam diffraction to study the long-range internal stresses in aluminum processed by ECAP

    International Nuclear Information System (INIS)

    Lee, I-Fang; Phan, Thien Q.; Levine, Lyle E.; Tischler, Jonathan Z.; Geantil, Peter T.; Huang, Yi; Langdon, Terence G.; Kassner, Michael E.

    2013-01-01

    Aluminum alloy 1050 was processed by equal-channel angular pressing (ECAP) using a single pass (equivalent uniaxial strain of about 0.88). Long-range internal stresses (LRISs) were assessed in the grain/subgrain interiors using X-ray microbeam diffraction to measure the spacing of {5 3 1} planes, with normals oriented approximately +27.3°, +4.9° and −17.5° off the pressing (axial) direction. The results are consistent with mechanical analysis that suggests the maximum tensile plastic-strain after one pass is expected for +22.5°, roughly zero along the pressing axis, and maximum compressive strain for the −67.5° direction. The magnitude of the measured maximum compressive long-range internal stress is about 0.13σ a (applied stress) in low-dislocation regions within the grain/subgrain interiors. This work is placed in the context of earlier work where convergent beam electron diffraction was used to analyze LRISs in close proximity to the deformation-induced boundaries. The results are complementary and the measured stresses are consistent with a composite model for long-range internal stresses

  3. The internal strength of rivers: autogenic processes in control of the sediment load (Tana River, Kenya)

    Science.gov (United States)

    Geeraert, Naomi; Ochieng Omengo, Fred; Tamooh, Fredrick; Paron, Paolo; Bouillon, Steven; Govers, Gerard

    2014-05-01

    The construction of sediment rating curves for monitoring stations is a widely used technique to budget sediment fluxes. Changes in the relationship between discharge and sediment concentrations over time are often attributed to human-induced changes in catchment characteristics, such as land use change, dam construction or soil conservation measures and many models have been developed to quantitatively link catchment characteristics and river sediment load. Conversely, changes in river sediment fluxes are often interpreted as indications of major changes in the catchment. By doing so, autogenic processes, taking place within the river channel, are overlooked despite the increasing awareness of their importance. We assessed the role of autogenic processes on the sediment load of Tana River (Kenya). The Tana river was impacted by major dam construction between 1968 and 1988, effectively blocking at least 80% of the sediment transfer from the highlands to the lower river reaches. However, a comparison of pre-dam sediment fluxes at Garissa (located 250 km downstream of the dams) with recent measurements shows that sediment fluxes have not changed significantly. This suggests that most of the sediment in the post-dam period has to originate from inside the alluvial plain of the river, as tributaries downstream of the dams are scarce and intermittent. Several observations are consistent with this hypothesis. We observed that, during the wet season, sediment concentrations rapidly increased below the dams and are not controlled by inputs from tributaries. Also, sediment concentrations were high at the beginning of the wet season, which can be attributed to channel adjustment to the higher discharges. The river sediment does not contain significant amounts of 137Cs or 210Pbxs, suggesting that sediments are not derived from topsoil erosion. Furthermore, we observed a counter clockwise hysteresis during individual events which can be explained by the fact that sediment

  4. Directionally Solidified Aluminum - 7 wt% Silicon Alloys: Comparison of Earth and International Space Station Processed Samples

    Science.gov (United States)

    Grugel, Richard N,; Tewari, Surendra; Rajamure, R. S.; Erdman, Robert; Poirier, David

    2012-01-01

    Primary dendrite arm spacings of Al-7 wt% Si alloy directionally solidified in low gravity environment of space (MICAST-6 and MICAST-7: Thermal gradient approx. 19 to 26 K/cm, Growth speeds varying from 5 to 50 microns/s show good agreement with the Hunt-Lu model. Primary dendrite trunk diameters of the ISS processed samples show a good fit with a simple analytical model based on Kirkwood s approach, proposed here. Natural convection, a) decreases primary dendrite arm spacing. b) appears to increase primary dendrite trunk diameter.

  5. The Relationship of the Facial Nerve to the Condylar Process: A Cadaveric Study with Implications for Open Reduction Internal Fixation

    Directory of Open Access Journals (Sweden)

    H. P. Barham

    2015-01-01

    Full Text Available Introduction. The mandibular condyle is the most common site of mandibular fracture. Surgical treatment of condylar fractures by open reduction and internal fixation (ORIF demands direct visualization of the fracture. This project aimed to investigate the anatomic relationship of the tragus to the facial nerve and condylar process. Materials and Methods. Twelve fresh hemicadavers heads were used. An extended retromandibular/preauricular approach was utilized, with the incision being based parallel to the posterior edge of the ramus. Measurements were obtained from the tragus to the facial nerve and condylar process. Results. The temporozygomatic division of the facial nerve was encountered during each approach, crossing the mandible at the condylar neck. The mean tissue depth separating the facial nerve from the condylar neck was 5.5 mm (range: 3.5 mm–7 mm, SD 1.2 mm. The upper division of the facial nerve crossed the posterior border of the condylar process on average 2.31 cm (SD 0.10 cm anterior to the tragus. Conclusions. This study suggests that the temporozygomatic division of the facial nerve will be encountered in most approaches to the condylar process. As visualization of the relationship of the facial nerve to condyle is often limited, recognition that, on average, 5.5 mm of tissue separates condylar process from nerve should help reduce the incidence of facial nerve injury during this procedure.

  6. [Effects of an implicit internal working model on attachment in information processing assessed using Go/No-Go Association Task].

    Science.gov (United States)

    Fujii, Tsutomu; Uebuchi, Hisashi; Yamada, Kotono; Saito, Masahiro; Ito, Eriko; Tonegawa, Akiko; Uebuchi, Marie

    2015-06-01

    The purposes of the present study were (a) to use both a relational-anxiety Go/No-Go Association Task (GNAT) and an avoidance-of-intimacy GNAT in order to assess an implicit Internal Working Model (IWM) of attachment; (b) to verify the effects of both measured implicit relational anxiety and implicit avoidance of intimacy on information processing. The implicit IWM measured by GNAT differed from the explicit IWM measured by questionnaires in terms of the effects on information processing. In particular, in subliminal priming tasks involving with others, implicit avoidance of intimacy predicted accelerated response times with negative stimulus words about attachment. Moreover, after subliminally priming stimulus words about self, implicit relational anxiety predicted delayed response times with negative stimulus words about attachment.

  7. Metallic materials for heat exchanger components and highly stressed internal of HTR reactors for nuclear process heat generation

    International Nuclear Information System (INIS)

    1982-01-01

    The programme was aimed at the development and improvement of materials for the high-temperature heat exchanger components of a process steam HTR. The materials must have high resistance to corrosion, i.e. carburisation and internal oxidation, and high long-term toughness over a wide range of temperatures. They must also meet the requirements set in the nuclear licensing procedure, i.e. resistance to cyclic stress and irradiation, non-destructive testing, etc. Initially, it was only intended to improve and qualify commercial alloys. Later on an alloy development programme was initiated in which new, non-commercial alloys were produced and modified for use in a nuclear process heat facility. Separate abstracts were prepared for 19 pays of this volume. (orig./IHOE) [de

  8. The influence of Uranium-Thorium ratio and heating time during gelation using as a CCl4(NH3) on the Gel quality

    International Nuclear Information System (INIS)

    Indra-Suryawan; Sukarsono, R; Setyo-Sulardi

    1996-01-01

    Gel has been prepared from a uranium-thorium sol using CCI 4 (NH 3 ) as a gelling medium. The uranium-thorium ratio and the heating time during gelation have been chosen as variables. The sol was prepared by mixing Th(NO 3 ) 4 and UO 2 (NO 3 ) 2 solutions, heating the solution at 95 o C and adding NH 4 OH solution drop by drop until colloidal particles were formed. Sol was then fed into a gelation column containing CCI 4 (NH 3 ), where the sol was transformed into gel. A good gel has properties such as sphere in shape and elastic which it will not crack when it is dropped from 2 metres height. The experimental work resulted a good gel when the percentage of uranium was about 15 - 25 % at heating time of 40 - 50 minutes

  9. Solid triphenylmethanol: A molecular material that undergoes multiple internal reorientational processes on different timescales

    International Nuclear Information System (INIS)

    Kitchin, Simon J.; Xu Mingcan; Serrano-Gonzalez, Heliodoro; Coates, Laura J.; Zaka Ahmed, S.; Glidewell, Christopher; Harris, Kenneth D.M.

    2006-01-01

    In solid triphenylmethanol, the molecules are arranged in hydrogen-bonded tetramers, and it is already well established that the hydrogen bonding in this material undergoes a dynamic switching process between different hydrogen bonding arrangements. In addition to this motion, we show here, from solid-state 2 H NMR studies of the deuterated material (C 6 D 5 ) 3 COH, that each phenyl ring in this material undergoes a 180 deg.-jump reorientation about the C 6 D 5 -C(OH) bond, with an activation energy of ca. 50 kJ mol -1 . The timescale for the phenyl ring dynamics is several orders of magnitude longer than the timescale for the hydrogen bond dynamics in this material, and is uncorrelated with the dynamics of the hydrogen bonding arrangement

  10. Proceedings of the 4th International Workshop on Constraints and Language Processing, CSLP 2007

    DEFF Research Database (Denmark)

    , and the Programming, Logic and Intelligent Systems Research Group & the Department of Communication, Business and Information Technologies, Roskilde University, Denmark. Finally we dedicate this volume to Peter Rossen Skadhauge, who sadly and unexpectedly passed away last year. He has been a member of the program...... our invited speaker, Annelies Braffort, who will talk on the modelling of spatio-temporal constraints in sign language processing. We will also express a special thanks to Barbara Hemforth who accepted to send us a late paper which emphasizes the importance of the psycholinguistic dimension...... in this research. This volume contains papers accepted for the workshop based on an open call, and each paper has been reviewed by three or four members of the program committee. As editors, we would also like to thank the other members of the organization committee, Philippe Blache and Veronica Dahl, whose...

  11. Evidence for ligand and/or receptor-specific mechanisms of internalization and processing in cultured H35 hepatoma cells

    International Nuclear Information System (INIS)

    Goldberg, R.I.; Smith, R.M.; Jarett, L.

    1987-01-01

    Total cell associated (TC) and intracellularly accumulated (IC) 125 I-labeled insulin (INS) or α-2-macroglobulin (α2M) were assessed in cultured H35 hepatoma cells which were preincubated with various agents. Cytochalasin D or sodium azide, which affect microfilament- or energy-dependent receptor internalization, had no significant effects on INS TC or IC but each decreased α2M TC and IC to 50-75% of control. Monensin and chloroquine, acidotrophic agents, each increased INS TC and IC to 150-300% of control yet decreased TC and IC of α2M to 20-50% of control. Only leupeptin, a lysosomal protease inhibitor, caused an increase in both INS and α2M TC and IC. These data suggest significant differences exist in the biochemical regulation or structural routes of INS and α2M receptors and/or receptor-ligand complexes in their (1) internalization, (2) processing in acidic organelles, (3) recycling to the cell surface or in combinations of the above. Biochemical and ultrastructural studies are being performed on the H35 hepatoma cell which will characterize the processing of INS and α2M receptors and provide an explanation for the differences observed

  12. Multi response optimization of internal grinding process parameters for outer ring using Taguchi method and PCR-TOPSIS

    Science.gov (United States)

    Wisnuadi, Alief Regyan; Damayanti, Retno Wulan; Pujiyanto, Eko

    2018-02-01

    Bearing is one of the most widely used parts in automotive industry. One of the leading bearing manufacturing companies in the world is SKF Indonesia. This company must produce bearing with international standard. SKF Indonesia must do continuous improvement in order to face competition. During this time, SKF Indonesia is only performing quality control at its Quality Assurance department. In other words, quality improvement at SKF Indonesia has not been done thoroughly. The purpose of this research is to improve quality of outer ring product at SKF Indonesia by conducting an internal grinding process experiment about setting speed ratio, fine position, and spark out grinding time. The specific purpose of this experiment is to optimize some quality responses such as roughness, roundness, and cycle time. All of the response in this experiment were smaller the better. Taguchi method and PCR-TOPSIS are used for the optimization process. The result of this research shows that by using Taguchi method and PCR-TOPSIS, the optimum condition occurs on speed ratio 36, fine position 18 µm/s and spark out 0.5 s. The optimum conditions result were roughness 0.398 µm, roundness 1.78 µm and cycle time 8.1 s. This results have been better than the previous results and meet the standards. The roughness of 0.523 µm decrease to 0.398 µm and the average cycle time of 8.5 s decrease to 8.1 s.

  13. Internal states of model isotropic granular packings. I. Assembling process, geometry, and contact networks.

    Science.gov (United States)

    Agnolin, Ivana; Roux, Jean-Noël

    2007-12-01

    This is the first paper of a series of three, in which we report on numerical simulation studies of geometric and mechanical properties of static assemblies of spherical beads under an isotropic pressure. The influence of various assembling processes on packing microstructures is investigated. It is accurately checked that frictionless systems assemble in the unique random close packing (RCP) state in the low pressure limit if the compression process is fast enough, higher solid fractions corresponding to more ordered configurations with traces of crystallization. Specific properties directly related to isostaticity of the force-carrying structure in the rigid limit are discussed. With frictional grains, different preparation procedures result in quite different inner structures that cannot be classified by the sole density. If partly or completely lubricated they will assemble like frictionless ones, approaching the RCP solid fraction Phi_{RCP} approximately 0.639 with a high coordination number: z* approximately =6 on the force-carrying backbone. If compressed with a realistic coefficient of friction mu=0.3 packings stabilize in a loose state with Phi approximately 0.593 and z* approximately =4.5 . And, more surprisingly, an idealized "vibration" procedure, which maintains an agitated, collisional regime up to high densities results in equally small values of z* while Phi is close to the maximum value Phi_{RCP}. Low coordination packings have a large proportion (>10%) of rattlers--grains carrying no force--the effect of which should be accounted for on studying position correlations, and also contain a small proportion of localized "floppy modes" associated with divalent grains. Low-pressure states of frictional packings retain a finite level of force indeterminacy even when assembled with the slowest compression rates simulated, except in the case when the friction coefficient tends to infinity. Different microstructures are characterized in terms of near

  14. Decomplexation efficiency and mechanism of Cu(II)-EDTA by H2O2 coupled internal micro-electrolysis process.

    Science.gov (United States)

    Zhou, Dongfang; Hu, Yongyou; Guo, Qian; Yuan, Weiguang; Deng, Jiefan; Dang, Yapan

    2016-12-29

    Internal micro-electrolysis (IE) coupled with Fenton oxidation (IEF) was a very effective technology for copper (Cu)-ethylenediaminetetraacetic acid (EDTA) wastewater treatment. However, the mechanisms of Cu 2+ removal and EDTA degradation were scarce and lack persuasion in the IEF process. In this paper, the decomplexation and removal efficiency of Cu-EDTA and the corresponding mechanisms during the IEF process were investigated by batch test. An empirical equation and the oxidation reduction potential (ORP) index were proposed to flexibly control IE and the Fenton process, respectively. The results showed that Cu 2+ , total organic carbon (TOC), and EDTA removal efficiencies were 99.6, 80.3, and 83.4%, respectively, under the proper operation conditions of iron dosage of 30 g/L, Fe/C of 3/1, initial pH of 3.0, Fe 2+ /H 2 O 2 molar ratio of 1/4, and reaction time of 20 min, respectively for IE and the Fenton process. The contributions of IE and Fenton to Cu 2+ removal were 91.2 and 8.4%, respectively, and those to TOC and EDTA removal were 23.3, 25.1, and 57, 58.3%, respectively. It was found that Fe 2+ -based replacement-precipitation and hydroxyl radical (•OH) were the most important effects during the IEF process. •OH played an important role in the degradation of EDTA, whose yield and productive rate were 3.13 mg/L and 0.157 mg/(L min -1 ), respectively. Based on the intermediates detected by GC-MS, including acetic acid, propionic acid, pentanoic acid, amino acetic acid, 3-(diethylamino)-1,2-propanediol, and nitrilotriacetic acid (NTA), a possible degradation pathway of Cu-EDTA in the IEF process was proposed. Graphical abstract The mechanism diagram of IEF process.

  15. 1H, 15N and 13C assignments of domain 5 of Dictyostelium discoideum gelation factor (ABP-120) in its native and 8M urea-denatured states.

    Science.gov (United States)

    Hsu, Shang-Te Danny; Cabrita, Lisa D; Christodoulou, John; Dobson, Christopher M

    2009-06-01

    The gelation factor from Dictyostelium discoideum (ABP-120) is an actin binding protein consisting of six immunoglobulin (Ig) domains in the C-terminal rod domain. We have recently used the pair of domains 5 and 6 of ABP-120 as a model system for studying multi-domain nascent chain folding on the ribosome. Here we present the NMR assignments of domain 5 in its native and 8M urea-denatured states.

  16. Lessons Learned from GOSAT; Instrument Design, Calibration, Operation, Data Processing, and International Collaboration

    Science.gov (United States)

    Kuze, A.; Suto, H.; Shiomi, K.; Nakajima, M.

    2012-12-01

    we target sun glint (specular reflection) points, where the surface reflectance is not uniform or randomly distributed. Over the desert area, where surface reflectance is high and dust layers extend to high altitude, we have to use lower gain to avoid saturation and multiple scattering is complicated. For both ocean high albedo targets, validation data of XCO2 and XCH4 are limited. Validation by airplane become accurate but extrapolation is needed above flight attitude. Comparison of surface pressure between retrieved data and a priori model forecast fields is useful. For such kind of consistency, measurement must be very linear within wide dynamic range. After launch, we are re-evaluating the linearity of the detector, analog circuit and AD converters using a lab-model on the ground. Since launch, we have received feedback about the radiance spectra data from many data users of diverse institutes. We have gathered many calibration and validation data from international collaboration. We have modified the Level 1 algorithm and instrument calibrations several times. We are currently measuring the grid point of the Earth's surface, but the sampling for source and sink retrieval has not been optimized yet. We will present how we have solved problems, which portions of the instrument design we should modify, and items that we have not understood well yet.

  17. Internal cholinergic regulation of learning and recall in a model of olfactory processing

    Directory of Open Access Journals (Sweden)

    Licurgo Benemann Almeida

    2016-11-01

    Full Text Available In the olfactory system, cholinergic modulation has been associated with contrast modulation and changes in receptive fields in the olfactory bulb, as well the learning of odor associations in olfactory cortex. Computational modeling and behavioral studies suggest that cholinergic modulation could improve sensory processing and learning while preventing pro-active interference when task demands are high. However, how sensory inputs and/or learning regulate incoming modulation has not yet been elucidated. We here use a computational model of the olfactory bulb, piriform cortex (PC and horizontal limb of the diagonal band of Broca (HDB to explore how olfactory learning could regulate cholinergic inputs to the system in a closed feedback loop. In our model, the novelty of an odor is reflected in firing rates and sparseness of cortical neurons in response to that odor and these firing rates can directly regulate learning in the system by modifying cholinergic inputs to the system. In the model, cholinergic neurons reduce their firing in response to familiar odors – reducing plasticity in the PC, but increase their firing in response to novel odor – increasing PC plasticity. Recordings from HDB neurons in awake behaving rats reflect predictions from the model by showing that a subset of neurons decrease their firing as an odor becomes familiar.

  18. Gelation of Photonic Microdomain Structures Formed in Semi-Dilute Solutions of Ultra-High-Molecular-Weight Polystyrene-b-Polybutadiene with Various Polybutadiene Contents

    International Nuclear Information System (INIS)

    Okamoto, S; Ito, S; Ando, K; Mouri, M; Ikeda, A; Hasegawa, H; Koshikawa, N

    2010-01-01

    Well-ordered microdomain structures were obtained in semi-dilute solutions and successfully stabilized by gelation. We used polystyrene-b-polybutadiene (PS-b-PB) diblock copolymer with the weight-averaged molecular weight varying from several hundred thousands to millions g/mol. The solutions had iridescent colors because the domain spacing is on the order of the wavelength of visible light. As the structures are susceptible to distortion by flow or vibration, structural fixation was carried out by gelation. The polybutadiene used has the microstructure of 1,2-linkage and hence the chains can be cross-linkable. The Small-Angle X-ray Scattering and the UV-vis spectroscopic measurements showed that in the case of PS-b-PBs with the PB volume fraction, φ PB , greater than about 50 vol % the microdomain structures were successfully fixed by gelation, while largely distorted in the case of those with φ PB < ca. 50 vol %. The SAXS scattering intensities were quantitatively analyzed by the scattering functions numerically calculated based on the one- and two-dimensional paracrystal theories and on the concentration fluctuation between the polymers and the solvent molecules.

  19. Slow-release Permanganate Gel (SRP-G) for Groundwater Remediation: Spreading, Gelation, and Release in Porous and Low-Permeability Media

    Science.gov (United States)

    Lee, E. S.; Hastings, J.; Kim, Y.

    2015-12-01

    Dense nonaqueous phase liquids (DNAPLs) like trichloroethylene (TCE) serve as the most common form of groundwater pollution in the world. Pore-plugging by the solid oxidation product MnO2 and limited lateral dispersion of the oxidant are two common problems with existing in-situ chemical oxidation (ISCO) schemes that could be alleviated through the development of a delayed gelation method for oxidant delivery. The objective of the current study was to further develop and optimize slow-release permanganate gel (SRP-G), a solution comprising colloidal silica and KMnO4, as a novel low-cost treatment option for large and dilute TCE plumes in groundwater. Batch tests showed that gelation could be delayed through manipulation of KMnO4 concentration, pH, and silica particle size of the SRP-G solution. In flow-through columns and flow-tanks filled with saturated sands, silica concentration had little effect on the gelation lag stage and release rate, but increasing silica concentration was associated with increasing release duration. When compared to a pure KMnO4 solution, visual observations and [MnO4-] measurements from flow tank tests demonstrated that the SRP-G prolonged the release duration and enhanced lateral spreading of the oxidant.

  20. Process evaluation to explore internal and external validity of the "Act in Case of Depression" care program in nursing homes.

    Science.gov (United States)

    Leontjevas, Ruslan; Gerritsen, Debby L; Koopmans, Raymond T C M; Smalbrugge, Martin; Vernooij-Dassen, Myrra J F J

    2012-06-01

    A multidisciplinary, evidence-based care program to improve the management of depression in nursing home residents was implemented and tested using a stepped-wedge design in 23 nursing homes (NHs): "Act in case of Depression" (AiD). Before effect analyses, to evaluate AiD process data on sampling quality (recruitment and randomization, reach) and intervention quality (relevance and feasibility, extent to which AiD was performed), which can be used for understanding internal and external validity. In this article, a model is presented that divides process evaluation data into first- and second-order process data. Qualitative and quantitative data based on personal files of residents, interviews of nursing home professionals, and a research database were analyzed according to the following process evaluation components: sampling quality and intervention quality. Nursing home. The pattern of residents' informed consent rates differed for dementia special care units and somatic units during the study. The nursing home staff was satisfied with the AiD program and reported that the program was feasible and relevant. With the exception of the first screening step (nursing staff members using a short observer-based depression scale), AiD components were not performed fully by NH staff as prescribed in the AiD protocol. Although NH staff found the program relevant and feasible and was satisfied with the program content, individual AiD components may have different feasibility. The results on sampling quality implied that statistical analyses of AiD effectiveness should account for the type of unit, whereas the findings on intervention quality implied that, next to the type of unit, analyses should account for the extent to which individual AiD program components were performed. In general, our first-order process data evaluation confirmed internal and external validity of the AiD trial, and this evaluation enabled further statistical fine tuning. The importance of