The Influence of Basaltic Islands on the Oceanic REE Distribution: A Case Study From the Tropical South Pacific

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Mario Molina-Kescher

2018-03-01

Full Text Available The Rare Earth Elements (REEs have been widely used to investigate marine biogeochemical processes as well as the sources and mixing of water masses. However, there are still important uncertainties about the global aqueous REE cycle with respect to the contributions of highly reactive basaltic minerals originating from volcanic islands and the role of Submarine Groundwater Discharge (SGD. Here we present dissolved REE concentrations obtained from waters at the island-ocean interface (including SGD, river, lagoon and coastal waters from the island of Tahiti and from three detailed open ocean profiles on the Manihiki Plateau (including neodymium (Nd isotope compositions, which are located in ocean currents downstream of Tahiti. Tahitian fresh waters have highly variable REE concentrations that likely result from variable water–rock interaction and removal by secondary minerals. In contrast to studies on other islands, the SGD samples do not exhibit elevated REE concentrations but have distinctive REE distributions and Y/Ho ratios. The basaltic Tahitian rocks impart a REE pattern to the waters characterized by a middle REE enrichment, with a peak at europium similar to groundwaters and coastal waters of other volcanic islands in the Pacific. However, the basaltic island REE characteristics (with the exception of elevated Y/Ho ratios are lost during transport to the Manihiki Plateau within surface waters that also exhibit highly radiogenic Nd isotope signatures. Our new data demonstrate that REE concentrations are enriched in Tahitian coastal water, but without multidimensional sampling, basaltic island Nd flux estimates range over orders of magnitude from relatively small to globally significant. Antarctic Intermediate Water (AAIW loses its characteristic Nd isotopic signature (−6 to −9 around the Manihiki Plateau as a consequence of mixing with South Equatorial Pacific Intermediate Water (SEqPIW, which shows more positive values (−1 to �

Miocene isotope zones, paleotemperatures, and carbon maxima events at intermediate water-depth, Site 593, Southwest Pacific

International Nuclear Information System (INIS)

Cooke, P.J.; Nelson, C.S.; Crundwell, M.P.

2008-01-01

Oxygen and carbon isotopic stratigraphies are presented from both benthic and planktic foraminifera for the late early Miocene to earliest Pliocene interval (c. 19-5 Ma) of intermediate water-depth DSDP Site 593 in the southern Tasman Sea. The benthic values are interpreted as recording Miocene Southern Component Intermediate Water, while the planktic species record the Miocene mode and surface water signals. Comparisons are made between temperate Site 593 and the intermediate-depth polar Site 747 in the southern Indian Ocean. Glacial Mi zones Mi1b-Mi6, representing extreme glacial events, are evident in both the Site 593 intermediate and surface water records. Miocene Southern Component Intermediate Water δ 18 O values are generally lighter than the Holocene equivalent (Antarctic Intermediate Water), indicating slightly warmer intermediate waters and/ or less global ice volume. The benthic-planktic gradient is interpreted as indicating a less stratified Tasman Sea during the Miocene. The benthic δ 13 C record contains most of the global carbon maxima (CM) events, CM1-7 (CM1-6 = the Monterey Excursion). Like global deep-water records, the Tasman Sea intermediate water δ 13 C values indicate that most CM events correspond with Mi glacials, including Mi4 at Site 593, not reported previously. Intermediate waters play an important role in propagating climatic changes from the polar regions to the tropics, and the Site 593 dataset provides a full water column record of the structure of Miocene intermediate to surface watermasses prior to the modern situation. (author). 132 refs., 8 figs., 4 tabs

Nine years of mass transport data in the eastern boundary of the North Atlantic Subtropical Gyre

Science.gov (United States)

Fraile-Nuez, Eugenio; MachíN, Francisco; VéLez-Belchí, Pedro; López-Laatzen, Federico; Borges, Rafael; BeníTez-Barrios, Verónica; HernáNdez-Guerra, Alonso

2010-09-01

One of the longest current meter time series in the Lanzarote Passage in the eastern boundary of the North Atlantic Subtropical Gyre has been used to determine and quantify the 9-year mean transport, the inter-annual and seasonal mass transport variability for the three water masses present in the area. Results show North Atlantic Central Water (NACW) flowing southward in the upper levels with a mean mass transport of -0.81 ± 1.48 Sv, Antarctic Intermediate Water (AAIW) flowing northward at intermediate levels with a mean transport of +0.09 ± 0.57 Sv and Mediterranean Water (MW) flowing southward in the deep part of the passage with a mean transport of -0.05 ± 0.17 Sv. Harmonic and wavelet analysis show the presence of a seasonal pattern in the passage for the three water masses. A maximum southward transport in winter and spring has been observed for the NACW followed by a minimum in summer and fall. Near zero values during winter and spring are found for AAIW, with a maximum northward value in summer and a negative value in fall, when this water mass reverses its flow. MW has a similar seasonal pattern to NACW. The vertical structure in the Lanzarote Passage can be approximated by four significant oscillatory modes which cumulatively explain 86.4% of the variance. The strong transport fluctuation found at the seasonal and inter-annual timescales demonstrates that the Eastern Boundary Current transport has a strong impact on meridional overturning estimates, thus indicating that to understand Meridional Overturning Circulation variability, these transport estimates at the eastern Atlantic margin are necessary.

The path of the Levantine intermediate water to the Alboran sea

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Font, Jordi

1987-10-01

The Levantine Intermediate Water (LIW) traditionally has been assumed to reach the Alboran Sea as a counter-current along the North African coast. Here data are presented that confirm the LIW flow through the sill that separates the Balearic Islands from the mainland, after contouring cyclonically the western Mediterranean along the continental slope. This seems to be a seasonal phenomenon related to the process of deep water formation in the northwestern Mediterranean and to fluctuations in the Ligurian Current. In winter the LIW can circulate across the Catalan Sea without remarkable dilution, while in summer the intermediate outflow has almost lost the LIW water mass characteristics.

Interaction of the Faroe Bank Channel overflow with Iceland Basin intermediate waters

Science.gov (United States)

Ullgren, Jenny E.; Fer, Ilker; Darelius, Elin; Beaird, Nicholas

2014-01-01

The narrow and deep Faroe Bank Channel (FBC) is an important pathway for cold, dense waters from the Nordic Seas to flow across the Iceland-Scotland ridge into the North Atlantic. The swift, turbulent FBC overflow is associated with strong vertical mixing. Hydrographic profiles from a shipboard survey and two Slocum electric gliders deployed during a cruise in May-June 2012 show an intermediate water mass characterized by low salinity and low oxygen concentration between the upper waters of Atlantic origin and the dense overflow water. A weak low-salinity signal originating north-east of Iceland is discernible at the exit of the FBC, but smeared out by intense mixing. Further west (downstream) marked salinity and oxygen minima are found, which we hypothesize are indicators of a mixture of Labrador Sea Water and Intermediate Water from the Iceland Basin. Water mass characteristics vary strongly on short time scales. Low-salinity, low-oxygen water in the stratified interface above the overflow plume is shown to move along isopycnals toward the Iceland-Faroe Front as a result of eddy stirring and a secondary, transverse circulation in the plume interface. The interaction of low-salinity, low-oxygen intermediate waters with the overflow plume already at a short distance downstream of the sill, here reported for the first time, affects the final properties of the overflow waters through entrainment and mixing.

Mode and Intermediate Waters in Earth System Models

Energy Technology Data Exchange (ETDEWEB)

Gnanadesikan, Anand [Johns Hopkins Univ., Baltimore, MD (United States); Sarmiento, Jorge L. [Princeton Univ., NJ (United States)

2015-12-22

This report describes work done as part of a joint Princeton-Johns Hopkins project to look at the impact of mode and intermediate waters in Earth System Models. The Johns Hopkins portion of this work focussed on the role of lateral mixing in ventilating such waters, with important implications for hypoxia, the uptake of anthropogenic carbon, the dynamics of El Nino and carbon pumps. The Johns Hopkins group also collaborated with the Princeton Group to help develop a watermass diagnostics framework.

Physical and biogeochemical forcing of oxygen and nitrate changes during El Niño/El Viejo and La Niña/La Vieja upper-ocean phases in the tropical eastern South Pacific along 86° W

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P. J. Llanillo

2013-10-01

Full Text Available Temporal changes in the water mass distribution and biogeochemical signals in the tropical eastern South Pacific are investigated with the help of an extended optimum multi-parameter (OMP analysis, a technique for inverse modeling of mixing and biogeochemical processes through a multidimensional least-square fit. Two ship occupations of a meridional section along 85°50' W from 14° S to 1° N are analysed during relatively warm (El Niño/El Viejo, March 1993 and cold (La Niña/La Vieja, February 2009 upper-ocean phases. The largest El Niño–Southern Oscillation (ENSO impact was found in the water properties and water mass distribution in the upper 200 m north of 10° S. ENSO promotes the vertical motion of the oxygen minimum zone (OMZ associated with the hypoxic equatorial subsurface water (ESSW. During a cold phase the core of the ESSW is found at shallower layers, replacing shallow (top 200 m subtropical surface water (STW. The heave of isopycnals due to ENSO partially explains the intrusion of oxygen-rich and nutrient-poor antarctic intermediate water (AAIW into the depth range of 150–500 m. The other cause of the AAIW increase at shallower depths is that this water mass flowed along shallower isopycnals in 2009. The shift in the vertical location of AAIW reaching the OMZ induces changes in the amount of oxygen advected and respired inside the OMZ: the larger the oxygen supply, the greater the respiration and the lower the nitrate loss through denitrification. Variations in the intensity of the zonal currents in the equatorial current system, which ventilates the OMZ from the west, are used to explain the patchy latitudinal changes of seawater properties observed along the repeated section. Significant changes reach down to 800 m, suggesting that decadal variability (Pacific decadal oscillation is also a potential driver in the observed variability.

The hydrography of the Mozambique Channel from six years of continuous temperature, salinity, and velocity observations

Science.gov (United States)

Ullgren, J. E.; van Aken, H. M.; Ridderinkhof, H.; de Ruijter, W. P. M.

2012-11-01

has two cores: an intermediate one mainly containing diluted Antarctic Intermediate Water (AAIW), and a deep one consisting of North Atlantic Deep Water (NADW). In the intermediate core, T-S properties are strongly correlated with current velocity, probably because of the strong salinity gradient at the interface between Red Sea Water (RSW) and AAIW. In the deep core, velocity and hydrographic time series do not correlate on a daily basis, but they do at longer time scales.

South Atlantic circulation in a world ocean model

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M. H. England

1994-08-01

Full Text Available The circulation in the South Atlantic Ocean has been simulated within a global ocean general circulation model. Preliminary analysis of the modelled ocean circulation in the region indicates a rather close agreement of the simulated upper ocean flows with conventional notions of the large-scale geostrophic currents in the region. The modelled South Atlantic Ocean witnesses the return flow and export of North Atlantic Deep Water (NADW at its northern boundary, the inflow of a rather barotropic Antarctic Circumpolar Current (ACC through the Drake Passage, and the inflow of warm saline Agulhas water around the Cape of Good Hope. The Agulhas leakage amounts to 8.7 Sv, within recent estimates of the mass transport shed westward at the Agulhas retroflection. Topographic steering of the ACC dominates the structure of flow in the circumpolar ocean. The Benguela Current is seen to be fed by a mixture of saline Indian Ocean water (originating from the Agulhas Current and fresher Subantarctic surface water (originating in the ACC. The Benguela Current is seen to modify its flow and fate with depth; near the surface it flows north-westwards bifurcating most of its transport northward into the North Atlantic Ocean (for ultimate replacement of North Atlantic surface waters lost to the NADW conveyor. Deeper in the water column, more of the Benguela Current is destined to return with the Brazil Current, though northward flows are still generated where the Benguela Current extension encounters the coast of South America. At intermediate levels, these northward currents trace the flow of Antarctic Intermediate Water (AAIW equatorward, though even more AAIW is seen to recirculate poleward in the subtropical gyre. In spite of the model's rather coarse resolution, some subtle features of the Brazil-Malvinas Confluence are simulated rather well, including the latitude at which the two currents meet. Conceptual diagrams of the recirculation and interocean exchange of

South Atlantic circulation in a world ocean model

Directory of Open Access Journals (Sweden)

Matthew H. England

Full Text Available The circulation in the South Atlantic Ocean has been simulated within a global ocean general circulation model. Preliminary analysis of the modelled ocean circulation in the region indicates a rather close agreement of the simulated upper ocean flows with conventional notions of the large-scale geostrophic currents in the region. The modelled South Atlantic Ocean witnesses the return flow and export of North Atlantic Deep Water (NADW at its northern boundary, the inflow of a rather barotropic Antarctic Circumpolar Current (ACC through the Drake Passage, and the inflow of warm saline Agulhas water around the Cape of Good Hope. The Agulhas leakage amounts to 8.7 Sv, within recent estimates of the mass transport shed westward at the Agulhas retroflection. Topographic steering of the ACC dominates the structure of flow in the circumpolar ocean. The Benguela Current is seen to be fed by a mixture of saline Indian Ocean water (originating from the Agulhas Current and fresher Subantarctic surface water (originating in the ACC. The Benguela Current is seen to modify its flow and fate with depth; near the surface it flows north-westwards bifurcating most of its transport northward into the North Atlantic Ocean (for ultimate replacement of North Atlantic surface waters lost to the NADW conveyor. Deeper in the water column, more of the Benguela Current is destined to return with the Brazil Current, though northward flows are still generated where the Benguela Current extension encounters the coast of South America. At intermediate levels, these northward currents trace the flow of Antarctic Intermediate Water (AAIW equatorward, though even more AAIW is seen to recirculate poleward in the subtropical gyre. In spite of the model's rather coarse resolution, some subtle features of the Brazil-Malvinas Confluence are simulated rather well, including the latitude at which the two currents meet. Conceptual diagrams of the recirculation and interocean

Paleoproductivity and intermediate-water ventilation in the subarctic Northwest Pacific during the last deglaciation

Science.gov (United States)

Khim, B.; Ikehara, K.; Sagawa, T.; Shibahara, A.; Yamamoto, M.

2010-12-01

Laminated sediments during the last deglaciation in the subarctic North Pacific indicate significant depletion of dissolved oxygen concentration at intermediate water depths. Such a strong oxygen minimum zone results primarily from a combination of high surface water productivity and poor ventilation of intermediate waters. We investigated a variety of paleoclimatic proxies using about 8-m long piston core sediment (GH02-1030; 42o13.770N, 144o12.530E; water depth, 1212 m) obtained from the continental slope off Tokachi (eastern Hokkaido Island), which is the main path of the southwestward Oyashio Current in the subarctic Northwest Pacific. Laminated sediments were identified at the two horizons in the core GH02-1030; the upper one at 11.4-12.2 cal.kyr BP and the lower one at 14.1-14.7 cal.kyr BP, corresponding to Bølling-Allerød (B/A) and Preboreal (PB), respectively. Between these laminated layers, Younger Dryas occurred. Both laminated sediment layers are characterized by Bolivina tumida, B. pacifica, and Buliminella tenuata, indicating dysoxic bottom water conditions. Increased Mg/Ca-derived intermediate-water temperature and δ18OW values at B/A and PB periods suggest the poor ventilation of intermediate water because of the surface water freshening (i.e., decrease of surface-water salinity). UK'37-derived temperature record also supports the increase of surface-water temperature during B/A and PB intervals. During the last deglaciation, short-chain C14-C18 n-fatty acids, derived mainly from marine organisms, showed higher concentrations, indicating the increased surface-water production, and at the same time, abundant lignin reflected more contribution of terrigenous organic matter, supporting increased freshwater discharge. Variation of CaCO3 contents show remarkable double peaks, corresponding to B/A and PB periods, respectively, leading to the increase of TOC contents. Opal contents also follow similar pattern to CaCO3 contents, but are much less than the

Water activity reduction of intermediate moisture yellowstrip trevally (Selaroides leptolepis

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Phomajun, P.

2005-05-01

Full Text Available Water activity reduction of intermediate moisture yellowstrip trevally was studied. The optimal time (8, 12, 16, 20 hrs. for curing marinade was investigated. The effects of different humectants (glycerol, sorbitol, lactitol, glucose syrup at 50% w/w of curing ingredients were compared. Results showed that moisture content and water activity of cured yellowstrip trevally decreased as curing time increased (p0.05. However, the hardness of intermediate moisture Yellowstrip trevally, determined by texture analyzer, decreased. Hardness, shear force, L a b value of sample added with various humectants were lower than those of the control (p0.05. The glycerol-added samples had the highest overall acceptability score and were higher than control, whereas the glucose syrup-added samples had the lowest score. Moisture content of the samples with the addition of various humectants was higher than that of the control (18.28 %. The samples added with glycerol retained the highest moisture (24.94%. The adsorption isotherm studies showed that the equilibrium moisture of sample added with glycerol was higher than that added with lactitol.

A multi-proxy analysis of Late Quaternary ocean and climate variability for the Maldives, Inner Sea

Science.gov (United States)

Bunzel, Dorothea; Schmiedl, Gerhard; Lindhorst, Sebastian; Mackensen, Andreas; Reolid, Jesús; Romahn, Sarah; Betzler, Christian

2017-12-01

-monsoon-induced organic matter fluxes and oxygen consumption further controlled by the varying inflow intensity of the Antarctic Intermediate Water (AAIW). In addition, the bottom water oxygenation pattern of the Maldives Inner Sea reveals a long phase of reduced ventilation during the last glacial period. This process is likely linked to the combined effects of generally enhanced oxygen consumption rates during high-productivity phases, reduced AAIW production and the restriction of upper bathyal environments in the Inner Sea during sea-level lowstands. Thus, our multi-proxy record reflects a close linkage between the Indian monsoon oscillation, intermediate water circulation, productivity and sea-level changes on orbital timescale.

Modeling the dispersal of Levantine Intermediate Water and its role in Mediterranean deep water formation

Science.gov (United States)

Wu, Peili; Haines, Keith

1996-03-01

This paper demonstrates the importance of Levantine Intermediate Water (LIW) in the deep water formation process in the Mediterranean using the modular ocean general circulation model at 0.25° resolution, 19 vertical levels, over the entire Mediterranean with an open Gibraltar strait. LIW formation is strongly prescribed in the Rhodes Gyre region by Haney [1971] relaxation, while in other regions, surface salinity relaxation is much reduced by applying the `mixed' thermohaline surface boundary conditions. Isopycnal diagnostics are used to trace water mass movements, and volume fluxes are monitored at straits. Low viscosity and diffusion are used to permit baroclinic eddies to play a role in water mass dispersal. The overall water budget is measured by an average flux at Gibraltar of 0.8 Sv, of which 0.7 Sv is exchanged with the eastern basin at Sicily. LIW (density around 28.95) spreads rapidly after formation throughout the entire Levantine due to baroclinic eddies. Toward the west, LIW accumulates in the northern and central Ionian, with some entering the Adriatic through Otranto and some mixing southward in eddies and exiting to the western Mediterranean through Sicily. LIW is converted to deep water in the south Adriatic at an average rate of 0.4 Sv. Water exchange through the Otranto strait appears to be buoyancy driven, with a strong bias to the end of winter (March-April), while at Sicily the exchange has a strong symmetric seasonal cycle, with maximum transport of 1.1 Sv in December indicating the effects of wind driving. LIW pathways in the west are complex and variable. In the Tyrrhenian, intermediate water becomes uniform on isopycnal surfaces due to eddy stirring. West of Sardinia, two LIW boundary currents are formed in the Balearic basin; one flows northward up the west coast of Sardinia and Corsica, and one westward along the northern African coast. The northward current is consistent with observations, while the westward current is intermittent for

Abrupt changes of intermediate water properties on the northeastern slope of the Bering Sea during the last glacial and deglacial period

Science.gov (United States)

Rella, Stephan F.; Tada, Ryuji; Nagashima, Kana; Ikehara, Minoru; Itaki, Takuya; Ohkushi, Ken'ichi; Sakamoto, Tatsuhiko; Harada, Naomi; Uchida, Masao

2012-09-01

Millennial-scale variability in the behavior of North Pacific Intermediate Water during the last glacial and deglacial period, and its association with Dansgaard-Oeschger (D-O) cycles and Heinrich events, are examined based on benthic foraminiferal oxygen and carbon isotopes (δ18Obf and δ13Cbf) and %CaCO3 using a sediment core recovered from the northeastern slope of the Bering Sea. A suite of positive δ18Obf excursions at intermediate depths of the Bering Sea, which seem at least in part associated with increases in the δ18Obf gradients between the Bering and Okhotsk Seas, suggest the Bering Sea as a proximate source of intermediate water during several severe stadial episodes in the last glacial and deglacial period. Absence of such δ18Obf gradients during periods of high surface productivity in the Bering and Okhotsk Seas, which we correlate to D-O interstadials, suggests a reduction in intermediate water production in the Bering Sea and subsequent introduction of nutrient-rich deep waters from the North Pacific into intermediate depths of the Bering Sea. We argue that a reorganization of atmospheric circulation in the high-latitude North Pacific during severe cold episodes in the last glacial and deglacial period created favorable conditions for brine rejection in the northeastern Bering Sea. The resulting salinity increase in the cold surface waters could have initiated intermediate (and deep) water formation that spread out to the North Pacific.

Southwest Pacific deep water carbonate chemistry linked to high southern latitude climate and atmospheric CO2 during the Last Glacial Termination

Science.gov (United States)

Allen, Katherine A.; Sikes, Elisabeth L.; Hönisch, Bärbel; Elmore, Aurora C.; Guilderson, Thomas P.; Rosenthal, Yair; Anderson, Robert F.

2015-08-01

A greater amount of CO2 was stored in the deep sea during glacial periods, likely via greater efficiency of the biologic pump and increased uptake by a more alkaline ocean. Reconstructing past variations in seawater carbonate ion concentration (a major component of alkalinity) enables quantification of the relative roles of different oceanic CO2 storage mechanisms and also places constraints on the timing, magnitude, and location of subsequent deep ocean ventilation. Here, we present a record of deep-water inorganic carbon chemistry since the Last Glacial Maximum (LGM; ∼19-23 ka BP), derived from sediment core RR0503-83 raised from 1627 m in New Zealand's Bay of Plenty. The core site lies within the upper limit of southern-sourced Circumpolar Deep Water (CDW), just below the lower boundary of Antarctic Intermediate Water (AAIW). We reconstruct past changes in bottom water inorganic carbon chemistry from the trace element and stable isotopic composition of calcite shells of the epibenthic foraminifer Cibicidoides wuellerstorfi. A record of ΔCO32-(ΔCO32- = [COCO32-] in situ - [CO32-] saturation) derived from the foraminiferal boron to calcium ratio (B/Ca) provides evidence for greater ice-age storage of respired CO2 and reveals abrupt deglacial shifts in [CO32-] in situ of up to 30 μmol/kg (5 times larger than the difference between average LGM and Holocene values). The rapidity of these changes suggests the influence of changing water mass structure and atmospheric circulation in addition to a decrease in CO2 content of interior waters.

Critical masses of bare homogeneous spherical UO2-water mixtures at intermediate enrichments

International Nuclear Information System (INIS)

Rendon, G.L.; Stratton, W.

1999-01-01

Critical masses of bare homogeneous spherical UO 2 -water mixtures at various intermediate fissile enrichments determined by multigroup, transport theory is presented. This work was performed to provide support for particular issues encountered by the nuclear industry when operating in the intermediate enrichment regime, namely, the validation of codes used to set criticality safety limits. Validation is normally performed with a comparison of computational results and applicable experiments. However, this may be difficult in some cases because of the lack of sufficient applicable experiments in the intermediate enrichment range. If a large extension of the area of applicability from an experiment to the desired application exists, then an alternative means for validation must be employed. Ideal interpretations of standard ANSI/ANS 8.1 Section 4.3 (1983) implies that perhaps an independent code and data system may be employed for validation purposes

Development of Non-Platinum Catalysts for Intermediate Temperature Water Electrolysis

DEFF Research Database (Denmark)

Nikiforov, Aleksey Valerievich; Petrushina, Irina Michailovna; Bjerrum, Niels J.

2014-01-01

Water electrolysis is recognized as an efficient energy storage (in the form of hydrogen) supplement in renewable energy production. However, industrial alkaline water electrolyzers are rather ineffective and space requiring for a commercial use in connection with energy storage. The most effective...... modern water electrolyzers are based on polymeric proton-conducting membrane electrolytes (PEM), e.g. Nafion®, a perfluorocarbon-sulfonic acid polymer. These electrolyzers work at temperatures up to around 80 °C, and, in extreme cases, up to 130-140 °C. The most developed PEM electrolyzers...... as electrolytes for the intermediate temperature applications, such as CsHSO4, KHSO45. The most successful systems have been developed with CsH2PO4 (solid acid fuel cells (SAFCs) and Sn0.9In0.1P2O7 electrolytes6,7. While developing materials for the promising medium temperature electrolysis systems...

Red Sea Intermediate Water at the Agulhas Current termination

Science.gov (United States)

Roman, R. E.; Lutjeharms, J. R. E.

2007-08-01

The inter-ocean exchange of water masses at the Agulhas Current termination comes about through the shedding of rings, and this process plays an important role in the global thermohaline circulation. Using several hydrographic sections collected during the ARC (Agulhas Retroflection Cruise), MARE (Mixing of Agulhas Rings Experiment) and WOCE (World Ocean Circulation Experiment), this investigation aims to establish the degree to which Red Sea Intermediate Water (RSIW) is involved in this exchange and at what level of purity. To this end a wide range of hydrographic parameters were used. Upstream from the Agulhas Current retroflection water with clear RSIW origin is shown to move downstream on both the landward and seaward sides of the Agulhas Current with the highest water sample purity or water-mass content exceeding 15%. The least mixed water was found close to the continental shelf. At the retroflection the RSIW purity shows considerable variability that ranges between 5% and 20%. This suggests that RSIW moves down the current in patches of considerably varying degrees of previous mixing. This pattern was also observed in a ring sampled during the ARC experiment. The MARE sections in turn indicate that at times RSIW may be entirely absent in the Agulhas Current. RSIW is therefore shown to travel down the current as discontinuous filaments, and this intermittency is reflected in its presence in Agulhas Rings. From the sections investigated it is therefore clear that any calculation of RSIW fluxes involved in inter-ocean exchange can only be done on the basis of event scales. RSIW not trapped in Agulhas Rings flows east with the Agulhas Return Current.

Variation of the cold intermediate water in the Black Sea exit of the Strait of Istanbul (Bosphorus and its transfer through the strait

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Huseyin Yuce

2012-04-01

Full Text Available The cold intermediate water (CIW, T < 8°C entering the Strait of Istanbul and its variation along the strait have been studied by using monthly conductivity-temperature-depth (CTDdata sets collected during the period from 1996 to 2000. In the northern exit of the strait, CIW is located between the seasonal thermocline and Mediterranean water originating from the lowerlayer of the Sea of Marmara. The thickness of CIW decreases fromApril to October. In the Strait of Istanbul, CIW is observedas a layer of temperature < 14$^{circ}$C. The thickness of thismodified cold intermediate water flowing southwards with the upper layer decreases, while its temperature increases along thestrait due to mixing with adjacent water. In the southern exit of the strait, the modified cold intermediate water is observed during the period from May to October. If CIW exists in the Black Sea exit region of the strait, modified cold water is found inthe Marmara exit region during the same period. The distribution of CIW in the Strait of Istanbul contributes to our understanding of the dynamics of the strait, especially in the summer months.

87Sr/86Sr dating and preliminary interpretation of magnetic susceptibility logs of giant piston cores from the Rio Grande Rise in the South Atlantic

Science.gov (United States)

Lacasse, Christian Michel; Santos, Roberto Ventura; Dantas, Elton Luiz; Vigneron, Quentin; de Sousa, Isabela Moreno Cordeiro; Harlamov, Vadim; Lisniowski, Maria Aline; Pessanha, Ivo Bruno Machado; Frazão, Eugênio Pires; Cavalcanti, José Adilson Dias

2017-12-01

Giant piston cores recovered from shallow depths (optimized matching with an internationally recognized timescale of 87Sr/86Sr seawater variation through geological times. Depth-to-age conversion of the magnetic susceptibility logs was implemented based on the identification of correlative peaks between cores and the developed 87Sr/86Sr age model. The influence of Northern Hemisphere glaciation is reflected in these new stratigraphic logs by a gradual increase from ∼2.7 Ma in the lower signal of magnetic susceptibility (below background level), to values approaching the arithmetic means, likely reflecting an overall increase in terrigenous input. The Rio Grande Rise cores have very low Plio-Pleistocene sedimentation rates (∼0.4-0.8 cm/ka), similar to gravity cores from the oligotrophic subtropical South Atlantic (below ∼2000 mbsl), and for which an inverse correlation between carbonate content and magnetic susceptibility was established. The coring depths on the Rio Grande Rise encompass strong gradients in oxygen concentration and other seawater parameters that define today's AAIW/UCDW transition. Depth-dependent variation in sedimentation rates since the onset of Northern Hemisphere glaciation coincides with the incursion of intermediate waters (UCDW, AAIW) in response to the overall reduction of NADW export to the Southern Ocean. Background levels of magnetic susceptibility in the cores suggest that this variation is mainly attributed to terrigenous input. The source region of this material has yet to be traced by considering in particular the mineral composition and paramagnetic properties of the detrital clays.

Tropical teleconnections via the ocean and atmosphere induced by Southern Ocean deep convective events

Science.gov (United States)

Marinov, I.; Cabre, A.; Gunn, A.; Gnanadesikan, A.

2016-12-01

The current generation (CMIP5) of Earth System Models (ESMs) shows a huge variability in their ability to represent Southern Ocean (SO) deep-ocean convection and Antarctic Bottom Water, with a preference for open-sea convection in the Weddell and Ross gyres. A long control simulation in a coarse 3o resolution ESM (the GFDL CM2Mc model) shows a highly regular multi-decadal oscillation between periods of SO open sea convection and non-convective periods. This process also happens naturally, with different frequencies and durations of convection across most CMIP5 models under preindustrial forcing (deLavergne et al, 2014). Here we assess the impact of SO deep convection and resulting sea surface temperature (SST) anomalies on the tropical atmosphere and ocean via teleconnections, with a focus on interannual to multi-decadal timescales. We combine analysis of our low-resolution coupled model with inter-model analysis across historical CMIP5 simulations. SST cooling south of 60S during non-convective decades triggers a stronger, northward shifted SH Hadley cell, which results in intensified northward cross-equatorial moist heat transport and a poleward shift in the ITCZ. Resulting correlations between the cross-equatorial atmospheric heat transport and ITCZ location are in good agreement with recent theories (e.g. Frierson et al. 2013; Donohoe et al. 2014). Lagged correlations between a SO convective index and cross-equatorial heat transports (in the atmosphere and ocean), as well as various tropical (and ENSO) climate indices are analyzed. In the ocean realm, we find that non-convective decades result in weaker AABW formation and weaker ACC but stronger Antarctic Intermediate Water (AAIW) formation, likely as a result of stronger SO westerlies (more positive SAM). The signals of AABW and AAIW are seen in the tropics on short timescales of years to decades in the temperature, heat storage and heat transport anomalies and also in deep and intermediate ocean oxygen. Most

Mechanisms of deterioration of intermediate moisture food systems

Science.gov (United States)

Labuza, T. P.

1972-01-01

A study of shelf stability in intermediate moisture foods was made. Major efforts were made to control lipid oxidation and nonenzymatic browning. In order to determine means of preventing these reactions, model systems were developed having the same water activity content relationship of intermediate moisture foods. Models were based on a cellulose-lipid and protein-lipid system with glycerol added as the humectant. Experiments with both systems indicate that lipid oxidation is promoted significantly in the intermediate moisture range. The effect appeared to be related to increased mobility of either reactants or catalysts, since when the amount of water in the system reached a level where capillary condensation occurred and thus free water was present, the rates of oxidation increased. With added glycerol, which is water soluble and thus increases the amount of mobile phase, the increase in oxidation rate occurs at a lower relative humidity. The rates of oxidation were maximized at 61% RH and decreased again at 75% RH probably due to dilution. No significant non-enzymatic browning occurred in the protein-lipid systems. Prevention of oxidation by the use of metal chelating agents was enhanced in the cellulose system, whereas, with protein present, the lipid soluble chain terminating antioxidants (such as BHA) worked equally as well. Preliminary studies of foods adjusted to the intermediate moisture range bear out the results of oxidation in model systems. It can be concluded that for most fat containing intermediate moisture foods, rancidity will be the reaction most limiting stability.

The temperature dependence of intermediate range oxygen-oxygen correlations in liquid water

International Nuclear Information System (INIS)

Schlesinger, Daniel; Pettersson, Lars G. M.; Wikfeldt, K. Thor; Skinner, Lawrie B.; Benmore, Chris J.; Nilsson, Anders

2016-01-01

We analyze the recent temperature dependent oxygen-oxygen pair-distribution functions from experimental high-precision x-ray diffraction data of bulk water by Skinner et al. [J. Chem. Phys. 141, 214507 (2014)] with particular focus on the intermediate range where small, but significant, correlations are found out to 17 Å. The second peak in the pair-distribution function at 4.5 Å is connected to tetrahedral coordination and was shown by Skinner et al. to change behavior with temperature below the temperature of minimum isothermal compressibility. Here we show that this is associated also with a peak growing at 11 Å which strongly indicates a collective character of fluctuations leading to the enhanced compressibility at lower temperatures. We note that the peak at ∼13.2 Å exhibits a temperature dependence similar to that of the density with a maximum close to 277 K or 4 °C. We analyze simulations of the TIP4P/2005 water model in the same manner and find excellent agreement between simulations and experiment albeit with a temperature shift of ∼20 K.

The temperature dependence of intermediate range oxygen-oxygen correlations in liquid water

Energy Technology Data Exchange (ETDEWEB)

Schlesinger, Daniel; Pettersson, Lars G. M., E-mail: Lars.Pettersson@fysik.su.se [Department of Physics, AlbaNova University Center, Stockholm University, SE-106 91 Stockholm (Sweden); Wikfeldt, K. Thor [Department of Physics, AlbaNova University Center, Stockholm University, SE-106 91 Stockholm (Sweden); Science Institute, University of Iceland, VR-III, 107 Reykjavik (Iceland); Skinner, Lawrie B.; Benmore, Chris J. [X-ray Science Division, Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439 (United States); Nilsson, Anders [Department of Physics, AlbaNova University Center, Stockholm University, SE-106 91 Stockholm (Sweden); Stanford Synchrotron Radiation Lightsource, SLAC National Accelerator Laboratory, Menlo Park, California 94025 (United States)

2016-08-28

We analyze the recent temperature dependent oxygen-oxygen pair-distribution functions from experimental high-precision x-ray diffraction data of bulk water by Skinner et al. [J. Chem. Phys. 141, 214507 (2014)] with particular focus on the intermediate range where small, but significant, correlations are found out to 17 Å. The second peak in the pair-distribution function at 4.5 Å is connected to tetrahedral coordination and was shown by Skinner et al. to change behavior with temperature below the temperature of minimum isothermal compressibility. Here we show that this is associated also with a peak growing at 11 Å which strongly indicates a collective character of fluctuations leading to the enhanced compressibility at lower temperatures. We note that the peak at ∼13.2 Å exhibits a temperature dependence similar to that of the density with a maximum close to 277 K or 4 °C. We analyze simulations of the TIP4P/2005 water model in the same manner and find excellent agreement between simulations and experiment albeit with a temperature shift of ∼20 K.

Non-invasive detection of soil water content at intermediate field scale using natural neutrons from cosmic radiation

Energy Technology Data Exchange (ETDEWEB)

Oswald, Sascha; Rivera Villarreyes, Carlos; Baroni, Gabriele [Universitaet Potsdam, Institut fuer Erd und Umweltwissenschaften (Germany)

2011-07-01

The amount of water in the subsurface is a key factor influencing soil hydrology, run-off, evapotranspiration and plant development. A new measurement method is the so called cosmic ray method, recently introduced for soil moisture measurements by Zreda and coworkers. Secondary neutron fluxes, product of the interaction of primary cosmic-rays at the land surface, are strongly moderated by the presence of water in or above soil (soil moisture, snow and biomass water). Neutron counts at the ground/air interface represent a valuable observation at intermediate spatial scale which can be used to quantify stored water while distinguishing different water holding compartments at the land surface. We have performed such measurements in an agricultural field, in comparison with classical soil moisture measurement at a number of point locations. We discuss how to extract soil moisture values from the neutron counts, drawbacks of the method, but also that the results show a temporal development supported by the accompanying data.

A new perspective on origin of the East Sea Intermediate Water: Observations of Argo floats

Science.gov (United States)

Park, JongJin; Lim, Byunghwan

2018-01-01

The East Sea Intermediate Water (ESIW), defined as the salinity minimum in the East Sea (hereafter ES) (Sea of Japan), is examined with respect to its overall characteristics and its low salinity origin using historical Argo float data from 1999 to 2015. Our findings suggest that the ESIW is formed in the western Japan Basin (40-42°N, 130-133°E), especially west of the North Korean front in North Korean waters, where strong negative surface wind stress curl resides in wintertime. The core ESIW near the formation site has temperatures of 3-4 °C and less than 33.98 psu salinity, warmer and fresher than that in the southern part of the ES. In order to trace the origin of the warmer and fresher water at the sea surface in winter, we analyzed the data in three different ways: (1) spatial distribution of surface water properties using monthly climatology from the Argo float data, (2) seasonal variation of heat and salt contents at the formation site, and (3) backtracking of surface drifter trajectories. Based on these analyses, it is likely that the warmer and fresher surface water properties found in the ESIW formation site are attributed to the low-salinity surface water advected from the southern part of the ES in autumn.

Removal of Intermediate Aromatic Halogenated DBPs by Activated Carbon Adsorption: A New Approach to Controlling Halogenated DBPs in Chlorinated Drinking Water.

Science.gov (United States)

Jiang, Jingyi; Zhang, Xiangru; Zhu, Xiaohu; Li, Yu

2017-03-21

During chlorine disinfection of drinking water, chlorine may react with natural organic matter (NOM) and bromide ion in raw water to generate halogenated disinfection byproducts (DBPs). To mitigate adverse effects from DBP exposure, granular activated carbon (GAC) adsorption has been considered as one of the best available technologies for removing NOM (DBP precursor) in drinking water treatment. Recently, we have found that many aromatic halogenated DBPs form in chlorination, and they act as intermediate DBPs to decompose and form commonly known DBPs including trihalomethanes and haloacetic acids. In this work, we proposed a new approach to controlling drinking water halogenated DBPs by GAC adsorption of intermediate aromatic halogenated DBPs during chlorination, rather than by GAC adsorption of NOM prior to chlorination (i.e., traditional approach). Rapid small-scale column tests were used to simulate GAC adsorption in the new and traditional approaches. Significant reductions of aromatic halogenated DBPs were observed in the effluents with the new approach; the removals of total organic halogen, trihalomethanes, and haloacetic acids by the new approach always exceeded those by the traditional approach; and the effluents with the new approach were considerably less developmentally toxic than those with the traditional approach. Our findings indicate that the new approach is substantially more effective in controlling halogenated DBPs than the traditional approach.

The deterioration of intermediate moisture foods

Science.gov (United States)

Labruza, T. P.

1971-01-01

Deteriorative reactions are low and food quality high if intermediate moisture content of a food is held at a water activity of 0.6 to 0.75. Information is of interest to food processing and packaging industry.

The lower body muscle activation of intermediate to experienced kayakers when navigating white water.

Science.gov (United States)

Murtagh, Misha; Brooks, Darrell; Sinclair, Jonathan; Atkins, Stephen

2016-11-01

In white-water kayaking, the legs play a vital part in turning, stabilising and bracing actions. To date, there has been no reported information on neuromuscular activation of the legs in an authentic white-water environment. The aim of the current study was to identify lower body muscle activation, using 'in-boat' electromyography (EMG), whilst navigating a white-water run. Ten experienced male kayakers (age 31.5 ± 12.5 yr, intermediate to advanced experience) completed three successful runs of an international standard white-water course (grade 3 rapids), targeting right and left sides of the course, in a zigzag formation. Surface EMG (sEMG) outputs were generated, bilaterally, for the rectus femoris (RF), vastus lateralis, biceps femoris and gastrocnemius, expressed as a percentage of a dynamic maximal voluntary contraction (dMVC). Only RF showed significantly higher activation than any muscle on the left side of the body, and only on the left side of the course (P = .004; ETA(2) = 0.56). Other results showed no significant difference between muscle activation in the right and left legs during each run, nor when assessed at either the right or left side of the course (P > .05). These findings indicate that contralateral symmetry in lower limb muscle activation is evident during white-water kayaking. This symmetry may provide a stable base to allow more asymmetrical upper body and trunk movements to be fully optimised. Lower body symmetry development should be considered useful in targeted training programmes for white-water kayakers.

The MHD intermediate shock interaction with an intermediate wave: Are intermediate shocks physical?

International Nuclear Information System (INIS)

Wu, C.C.

1988-01-01

Contrary to the usual belief that MHD intermediate shocks are extraneous, the authors have recently shown by numerical solutions of dissipative MHD equations that intermediate shocks are admissible and can be formed through nonlinear steepening from a continuous wave. In this paper, he clarifies the differences between the conventional view and the results by studying the interaction of an MHD intermediate shock with an intermediate wave. The study reaffirms his results. In addition, the study shows that there exists a larger class of shocklike solutions in the time-dependent dissiaptive MHD equations than are given by the MHD Rankine-Hugoniot relations. it also suggests a mechanism for forming rotational discontinuities through the interaction of an intermediate shock with an intermediate wave. The results are of importance not only to the MHD shock theory but also to studies such as magnetic field reconnection models

Role of mesoscale eddies in the global ocean uptake of anthropogenic CO{sub 2}; Role des tourbillons de meso-echelle oceaniques dans la distribution et les flux air-mer de CO{sub 2} anthropique a l'echelle globale

Energy Technology Data Exchange (ETDEWEB)

Zouhair, Lachkar

2007-02-15

Mesoscale eddies play a fundamental role in ocean dynamics particularly in the Southern Ocean. Global-scale tracer simulations are typically made at coarse resolution without explicitly modeling eddies. Here we ask what role do eddies play in ocean uptake, storage, and meridional transport of anthropogenic CO{sub 2}, CFC-11 and bomb {delta}{sup 14}C. We made global anthropogenic transient tracer simulations in coarse-resolution, ORCA2, and eddy-permitting, ORCA05 and ORCA025, versions of the ocean modelling system NEMO. We focus on the Southern Ocean where tracer air-sea fluxes are largest. Eddies have little effect on bomb {delta}{sup 14}C uptake and storage. Yet for CFC-11 and anthropogenic CO{sub 2}, increased eddy activity reduces southern extra-tropical uptake by 28% and 25% respectively, thereby providing better agreement with observations. It is shown that the discrepancies in the equilibration times between the three tracers determine their respective sensitivities to the model horizontal resolution. Applying Gent and McWilliams (1990) (GM) parameterization of eddies in the non-eddying version of the model does improve results, but not enough. An in-depth investigation of the mechanisms by which eddies affect the uptake of the transient tracers shows that including mesoscale eddies leads to an overall reduction in the Antarctic Intermediate Water (AAIW) ventilation, and modifies substantially the spatial distribution of their source regions. This investigation reveals also that the GM parameterization still overestimates the ventilation and the subduction of AAIW in the Indian Ocean where the simulated mixed layer is particularly deep during the winter. This work suggests that most current coarse-resolution models may overestimate the ventilation of AAIW in the Indian sector of the Southern Ocean. This study shows also that the use of the GM parameterization may be of limited utility where mixed layer is relatively deep and confirms the general need for a

Role of mesoscale eddies in the global ocean uptake of anthropogenic CO2

International Nuclear Information System (INIS)

Zouhair, Lachkar

2007-02-01

Mesoscale eddies play a fundamental role in ocean dynamics particularly in the Southern Ocean. Global-scale tracer simulations are typically made at coarse resolution without explicitly modeling eddies. Here we ask what role do eddies play in ocean uptake, storage, and meridional transport of anthropogenic CO 2 , CFC-11 and bomb Δ 14 C. We made global anthropogenic transient tracer simulations in coarse-resolution, ORCA2, and eddy-permitting, ORCA05 and ORCA025, versions of the ocean modelling system NEMO. We focus on the Southern Ocean where tracer air-sea fluxes are largest. Eddies have little effect on bomb Δ 14 C uptake and storage. Yet for CFC-11 and anthropogenic CO 2 , increased eddy activity reduces southern extra-tropical uptake by 28% and 25% respectively, thereby providing better agreement with observations. It is shown that the discrepancies in the equilibration times between the three tracers determine their respective sensitivities to the model horizontal resolution. Applying Gent and McWilliams (1990) (GM) parameterization of eddies in the non-eddying version of the model does improve results, but not enough. An in-depth investigation of the mechanisms by which eddies affect the uptake of the transient tracers shows that including mesoscale eddies leads to an overall reduction in the Antarctic Intermediate Water (AAIW) ventilation, and modifies substantially the spatial distribution of their source regions. This investigation reveals also that the GM parameterization still overestimates the ventilation and the subduction of AAIW in the Indian Ocean where the simulated mixed layer is particularly deep during the winter. This work suggests that most current coarse-resolution models may overestimate the ventilation of AAIW in the Indian sector of the Southern Ocean. This study shows also that the use of the GM parameterization may be of limited utility where mixed layer is relatively deep and confirms the general need for a more adequate

Acid and base recovery from brine solution using PVP intermediate-based bipolar membrane through water splitting technology

Science.gov (United States)

Venugopal, Krishnaveni; Murugappan, Minnoli; Dharmalingam, Sangeetha

2017-07-01

Potable water has become a scarce resource in many countries. In fact, the world is not running out of water, but rather, the relatively fixed quantity is becoming too contaminated for many applications. Hence, the present work was designed to evaluate the desalination efficiency of resin and glass fiber-reinforced Polysulfone polymer-based monopolar and bipolar (BPM) ion exchange membranes (with polyvinyl pyrrolidone as the intermediate layer) on a real sample brine solution for 8 h duration. The prepared ion exchange membranes (IEMs) were characterized using FTIR, SEM, TGA, water absorption, and contact angle measurements. The BPM efficiency, electrical conductivity, salinity, sodium, and chloride ion concentration were evaluated for both prepared and commercial-based IEM systems. The current efficiency and energy consumption values obtained during BPMED process were found to be 45 % and 0.41 Wh for RPSu-PVP-based IEM system and 38 % and 1.60 Wh for PSDVB-based IEM system, respectively.

Comprehensive determination of macrolide antibiotics, their synthesis intermediates and transformation products in wastewater effluents and ambient waters by liquid chromatography-tandem mass spectrometry.

Science.gov (United States)

Senta, Ivan; Krizman-Matasic, Ivona; Terzic, Senka; Ahel, Marijan

2017-08-04

Macrolide antibiotics are a prominent group of emerging contaminants frequently found in wastewater effluents and wastewater-impacted aquatic environments. In this work, a novel analytical method for simultaneous determination of parent macrolide antibiotics (azithromycin, erythromycin, clarithromycin and roxithromycin), along with their synthesis intermediates, byproducts, metabolites and transformation products in wastewater and surface water was developed and validated. Samples were enriched using solid-phase extraction on Oasis HLB cartridges and analyzed by reversed-phase liquid chromatography coupled to electrospray ionization tandem mass spectrometry. The target macrolide compounds were separated on an ACE C18 PFP column and detected using multiple reaction monitoring in positive ionization polarity. The optimized method, which included an additional extract clean-up on strong anion-exchange cartridges (SAX), resulted in high recoveries and accuracies, low matrix effects and improved chromatographic separation of the target compounds, even in highly complex matrices, such as raw wastewater. The developed method was applied to the analysis of macrolide compounds in wastewater and river water samples from Croatia. In addition to parent antibiotics, several previously unreported macrolide transformation products and/or synthesis intermediates were detected in municipal wastewater, some of them reaching μg/L levels. Moreover, extremely high concentrations of macrolides up to mg/L level were found in pharmaceutical industry effluents, indicating possible importance of this source to the total loads into ambient waters. The results revealed a significant contribution of synthesis intermediates and transformation products to the overall mass balance of macrolides in the aquatic environment. Copyright © 2017. Published by Elsevier B.V.

Estimating carbonate parameters from hydrographic data for the intermediate and deep waters of the Southern Hemisphere oceans

Science.gov (United States)

Bostock, H. C.; Mikaloff Fletcher, S. E.; Williams, M. J. M.

2013-10-01

Using ocean carbon data from global datasets, we have developed several multiple linear regression (MLR) algorithms to estimate alkalinity and dissolved inorganic carbon (DIC) in the intermediate and deep waters of the Southern Hemisphere (south of 25° S) from only hydrographic data (temperature, salinity and dissolved oxygen). A Monte Carlo experiment was used to identify a potential density (σθ) of 27.5 as an optimal break point between the two regimes with different MLR algorithms. The algorithms provide a good estimate of DIC (R2=0.98) and alkalinity (R2=0.91), and excellent agreement for aragonite and calcite saturation states (R2=0.99). Combining the algorithms with the CSIRO Atlas of Regional Seas (CARS), we have mapped the calcite saturation horizon (CSH) and aragonite saturation horizon (ASH) for the Southern Ocean at a spatial resolution of 0.5°. These maps are more detailed and more consistent with the oceanography than the previously gridded GLODAP data. The high-resolution ASH map reveals a dramatic circumpolar shoaling at the polar front. North of 40° S the CSH is deepest in the Atlantic (~ 4000 m) and shallower in the Pacific Ocean (~ 2750 m), while the CSH sits between 3200 and 3400 m in the Indian Ocean. The uptake of anthropogenic carbon by the ocean will alter the relationships between DIC and hydrographic data in the intermediate and deep waters over time. Thus continued sampling will be required, and the MLR algorithms will need to be adjusted in the future to account for these changes.

Estimating carbonate parameters from hydrographic data for the intermediate and deep waters of the Southern Hemisphere oceans

Directory of Open Access Journals (Sweden)

H. C. Bostock

2013-10-01

Full Text Available Using ocean carbon data from global datasets, we have developed several multiple linear regression (MLR algorithms to estimate alkalinity and dissolved inorganic carbon (DIC in the intermediate and deep waters of the Southern Hemisphere (south of 25° S from only hydrographic data (temperature, salinity and dissolved oxygen. A Monte Carlo experiment was used to identify a potential density (σθ of 27.5 as an optimal break point between the two regimes with different MLR algorithms. The algorithms provide a good estimate of DIC (R2=0.98 and alkalinity (R2=0.91, and excellent agreement for aragonite and calcite saturation states (R2=0.99. Combining the algorithms with the CSIRO Atlas of Regional Seas (CARS, we have mapped the calcite saturation horizon (CSH and aragonite saturation horizon (ASH for the Southern Ocean at a spatial resolution of 0.5°. These maps are more detailed and more consistent with the oceanography than the previously gridded GLODAP data. The high-resolution ASH map reveals a dramatic circumpolar shoaling at the polar front. North of 40° S the CSH is deepest in the Atlantic (~ 4000 m and shallower in the Pacific Ocean (~ 2750 m, while the CSH sits between 3200 and 3400 m in the Indian Ocean. The uptake of anthropogenic carbon by the ocean will alter the relationships between DIC and hydrographic data in the intermediate and deep waters over time. Thus continued sampling will be required, and the MLR algorithms will need to be adjusted in the future to account for these changes.

Potentiometric surfaces of the intermediate aquifer system, west-central Florida, May, 1993

Science.gov (United States)

Mularoni, R.A.

1994-01-01

The intermediate aquifer system underlies a 5000-sq-mi area including De Soto, Sarasota, Hardee, Manatee, and parts of Charlotte, Hillsborough, Highlands, and Polk Counties, Florida. It is overlain by the surf@cial aquifer system and underlain by the Floridan aquifer system. The potentiometric surface of the intermediate aquifer system was mapped by determining the altitude of water levels in a network of wells and represented on a map by contours that connect points of equal altitude. This map represents water-level conditions near the end of the spring dry season when ground- water withdrawals for agricultural use were high. The cumulative rainfall for the study area was 4.84 inches above normal for the period from June 1992 to May 1993. Hydrographs for selected wells indicated that the annual and seasonal fluctuations of the water levels were generally large (greater than 15 feet) in the central interior region where water demand for irrigation is high during the fall and spring. Seasonal fluctuations were smaller in the northern recharge area where water use is predominantly for public supply. Water levels measured in May 1993 for the composite intermediate aquifer potentiometric surface were lower than those measured in May or September 1992. A cone of depression exists in the potentiometric surface for the composite aquifer system at Warm Mineral Springs, which is a natural discharge point from this system.

Kinetics of a Criegee intermediate that would survive high humidity and may oxidize atmospheric SO2.

Science.gov (United States)

Huang, Hao-Li; Chao, Wen; Lin, Jim Jr-Min

2015-09-01

Criegee intermediates are thought to play a role in atmospheric chemistry, in particular, the oxidation of SO2, which produces SO3 and subsequently H2SO4, an important constituent of aerosols and acid rain. However, the impact of such oxidation reactions is affected by the reactions of Criegee intermediates with water vapor, because of high water concentrations in the troposphere. In this work, the kinetics of the reactions of dimethyl substituted Criegee intermediate (CH3)2COO with water vapor and with SO2 were directly measured via UV absorption of (CH3)2COO under near-atmospheric conditions. The results indicate that (i) the water reaction with (CH3)2COO is not fast enough (kH2O SO2 at a near-gas-kinetic-limit rate (kSO2 = 1.3 × 10(-10) cm(3) s(-1)). These observations imply a significant fraction of atmospheric (CH3)2COO may survive under humid conditions and react with SO2, very different from the case of the simplest Criegee intermediate CH2OO, in which the reaction with water dimer predominates in the CH2OO decay under typical tropospheric conditions. In addition, a significant pressure dependence was observed for the reaction of (CH3)2COO with SO2, suggesting the use of low pressure rate may underestimate the impact of this reaction. This work demonstrates that the reactivity of a Criegee intermediate toward water vapor strongly depends on its structure, which will influence the main decay pathways and steady-state concentrations for various Criegee intermediates in the atmosphere.

Late Quaternary Palaeoceanographic Changes in Sea Surface Conditions in the Tropical Atlantic

Science.gov (United States)

Fischel, Andrea; Seidenkrantz, Marit-Solveig; Kuijpers, Antoon; Nürnberg, Dirk

2013-04-01

Palaeoceanographic changes and the variability in surface water mass hydrography are reconstructed in order to track tropical ocean and climate variability and inter-hemispheric heat exchange through the last 42,000 year BP. Our studies are based on the relative abundance of planktonic foraminifera combined with sea surface temperature approximation based Mg/Ca measurements, XRF scanning and stable oxygen isotope analyses in a 5 m long gravity core Ga307-Win-12GC (17°50.80N, 64°48.7290W), retrieved in the Virgin Island Basin in approx. 3,960 m water depth. The Virgin Island Basin is the deepest part of the Anegada-Jungfern Passage in the northeast Caribbean, one of the most important pathways for water mass exchange between the Central Atlantic and the Caribbean Sea. Due to its bathymetry surface waters as well as deep water mass strata from the northern and southern hemisphere enter the basin, comprising Caribbean Surface Water (CSW), Antarctic Intermediate Water (AAIW), Atlantic Intermediate Water (AIW) and North Atlantic Deep Water (NADW). The planktonic foraminiferal assemblage suggests rather stable sea-surface conditions during the Holocene in the NE Caribbean. However, major changes in the hydrographic setting could be identified within the glacial period. During the glacial period, clear millennial-scale variability in sea-surface temperature and productivity are present. Fluctuations in the relative abundance of Globigerinoides ruber in the sediment core may be correlated to Dansgaard-Oeschger events in the northern North Atlantic. Furthermore an increase in relative abundance of Globorotalia rubescens occurs synchronous with ice rafted debris layers described from the North Atlantic. The faunal changes in the tropical Atlantic may thus be correlated to major climate changes in the North Atlantic, mainly D-O cyclicity as well as Heinrich events. Thus, the synchronous change in water mass distribution and hydrographic cyclicity suggests a possible linkage

Intermediate-energy neutron beam for NCT at MURR

International Nuclear Information System (INIS)

Brugger, R.M.; Less, T.J.; Passmore, G.G.

1986-01-01

The University of Missouri Research Reactor (MURR) is one of the high-flux reactors in the USA and it can be used to produce an intense beam of intermediate-energy neutrons for neutron capture therapy. Two methods are being evaluated at MURR to produce such a beam. The first uses a moderator of Al 2 O 3 replacing part of the graphite and water on one side of the core of the reactor to produce a source of predominantly intermediate-energy neutrons. The second method is a filter of 238 U between the core and the patient position to pass only intermediate-energy neutrons. The results of these evaluations are presented in this paper along with an outline of the other resources at the University of Missouri-Columbia that are available to support an NCT program. 4 references, 7 figures, 1 table

Role of mesoscale eddies in the global ocean uptake of anthropogenic CO{sub 2}; Role des tourbillons de meso-echelle oceaniques dans la distribution et les flux air-mer de CO{sub 2} anthropique a l'echelle globale

Energy Technology Data Exchange (ETDEWEB)

Zouhair, Lachkar

2007-02-15

Mesoscale eddies play a fundamental role in ocean dynamics particularly in the Southern Ocean. Global-scale tracer simulations are typically made at coarse resolution without explicitly modeling eddies. Here we ask what role do eddies play in ocean uptake, storage, and meridional transport of anthropogenic CO{sub 2}, CFC-11 and bomb {delta}{sup 14}C. We made global anthropogenic transient tracer simulations in coarse-resolution, ORCA2, and eddy-permitting, ORCA05 and ORCA025, versions of the ocean modelling system NEMO. We focus on the Southern Ocean where tracer air-sea fluxes are largest. Eddies have little effect on bomb {delta}{sup 14}C uptake and storage. Yet for CFC-11 and anthropogenic CO{sub 2}, increased eddy activity reduces southern extra-tropical uptake by 28% and 25% respectively, thereby providing better agreement with observations. It is shown that the discrepancies in the equilibration times between the three tracers determine their respective sensitivities to the model horizontal resolution. Applying Gent and McWilliams (1990) (GM) parameterization of eddies in the non-eddying version of the model does improve results, but not enough. An in-depth investigation of the mechanisms by which eddies affect the uptake of the transient tracers shows that including mesoscale eddies leads to an overall reduction in the Antarctic Intermediate Water (AAIW) ventilation, and modifies substantially the spatial distribution of their source regions. This investigation reveals also that the GM parameterization still overestimates the ventilation and the subduction of AAIW in the Indian Ocean where the simulated mixed layer is particularly deep during the winter. This work suggests that most current coarse-resolution models may overestimate the ventilation of AAIW in the Indian sector of the Southern Ocean. This study shows also that the use of the GM parameterization may be of limited utility where mixed layer is relatively deep and confirms the general need for a

Intermediate tree cover can maximize groundwater recharge in the seasonally dry tropics

Science.gov (United States)

Ilstedt, U.; Bargués Tobella, A.; Bazié, H. R.; Bayala, J.; Verbeeten, E.; Nyberg, G.; Sanou, J.; Benegas, L.; Murdiyarso, D.; Laudon, H.; Sheil, D.; Malmer, A.

2016-01-01

Water scarcity contributes to the poverty of around one-third of the world’s people. Despite many benefits, tree planting in dry regions is often discouraged by concerns that trees reduce water availability. Yet relevant studies from the tropics are scarce, and the impacts of intermediate tree cover remain unexplored. We developed and tested an optimum tree cover theory in which groundwater recharge is maximized at an intermediate tree density. Below this optimal tree density the benefits from any additional trees on water percolation exceed their extra water use, leading to increased groundwater recharge, while above the optimum the opposite occurs. Our results, based on groundwater budgets calibrated with measurements of drainage and transpiration in a cultivated woodland in West Africa, demonstrate that groundwater recharge was maximised at intermediate tree densities. In contrast to the prevailing view, we therefore find that moderate tree cover can increase groundwater recharge, and that tree planting and various tree management options can improve groundwater resources. We evaluate the necessary conditions for these results to hold and suggest that they are likely to be common in the seasonally dry tropics, offering potential for widespread tree establishment and increased benefits for hundreds of millions of people. PMID:26908158

Photocatalytic oxidation of polycyclic aromatic hydrocarbons: Intermediates identification and toxicity testing

International Nuclear Information System (INIS)

Woo, O.T.; Chung, W.K.; Wong, K.H.; Chow, Alex T.; Wong, P.K.

2009-01-01

Polycyclic aromatic hydrocarbons (PAHs) are hydrophobic pollutants and their low water solubility limits their degradation in aqueous solution. The presence of water-miscible solvent such as acetone can increase the water solubility of PAHs, however acetone will also affect the degradation of PAH. In this study the effects of acetone on the photocatalytic degradation efficiency and pathways of 5 selected PAHs, namely naphthalene (2 rings), acenaphthylene (3 rings), phenanthrene (3 rings), anthracene (3 rings) and benzo[a]anthracene (4 rings) were investigated. The Microtox toxicity test was used to determine whether the PCO system can completely detoxify the parental PAHs and its intermediates. The addition of 16% acetone can greatly alter the degradation pathway of naphthalene and anthracene. Based on intermediates identified from degradation of the 5 PAHs, the location of parental PAHs attacked by reactive free radicals can be correlated with the localization energies of different positions of the compound. For toxicity analysis, irradiation by UV light was found to induce acute toxicity by generating intermediates/degradation products from PAHs and possibly acetone. Lastly, all PAHs (10 mg l -1 ) can be completely detoxified by titanium dioxide (100 mg l -1 ) within 24 h under UVA irradiation (3.9 mW cm -2 ).

Characterization of biodegradation intermediates of nonionic surfactants by MALDI-MS. 2. Oxidative biodegradation profiles of uniform octylphenol polyethoxylate in 18O-labeled water.

Science.gov (United States)

Sato, Hiroaki; Shibata, Atsushi; Wang, Yang; Yoshikawa, Hiromichi; Tamura, Hiroto

2003-01-01

This paper reports the characterization of the biodegradation intermediates of octylphenol octaethoxylate (OP(8)EO) by means of matrix-assisted laser desorption/ionization mass spectrometry (MALDI-MS). The biodegradation test study was carried out in a pure culture (Pseudomonas putida S-5) under aerobic conditions using OP(8)EO as the sole carbon source and (18)O-labeled water as an incubation medium. In the MALDI-MS spectra of biodegraded samples, a series of OP(n)EO molecules with n = 2-8 EO units and their corresponding carboxylic acid products (OP(n)EC) were observed. The use of purified OP(8)EO enabled one to distinguish the shortened OPEO molecules as biodegradation intermediates. Furthermore, the formation of OP(8)EC (the oxidized product of OP(8)EO) supported the notion that terminal oxidation is a step in the biodegradation process. When biodegradation study was carried out in (18)O-labeled water, incorporation of (18)O atoms into the carboxyl group was observed for OPEC, while no incorporation was observed for the shortened OPEO products. These results could provide some rationale to the biodegradation mechanism of alkylphenol polyethoxylates.

Intermediate treatments

Science.gov (United States)

John R. Jones; Wayne D. Shepperd

1985-01-01

Intermediate treatments are those applied after a new stand is successfully established and before the final harvest. These include not only intermediate cuttings - primarily thinning - but also fertilization, irrigation, and protection of the stand from damaging agents.

Photochemical transformation of phenylurea herbicides in surface waters: a model assessment of persistence, and implications for the possible generation of hazardous intermediates.

Science.gov (United States)

Fabbri, Debora; Minella, Marco; Maurino, Valter; Minero, Claudio; Vione, Davide

2015-01-01

This work models the phototransformation kinetics in surface waters of five phenylurea herbicides (diuron, fenuron, isoproturon, metoxuron and chlortoluron), for which important photochemical parameters are available in the literature (direct photolysis quantum yields and reaction rate constants with ·OH, CO3(-·) and the triplet states of chromophoric dissolved organic matter, (3)CDOM*). Model calculations suggest that isoproturon and metoxuron would be the least photochemically persistent and diuron the most persistent compound. Reactions with ·OH and (3)CDOM* would be the main phototransformation pathways for all compounds in the majority of environmental conditions. Reaction with CO3(-) could be important in waters with low dissolved organic carbon (DOC), while direct photolysis would be negligible for fenuron, quite important for chlortoluron, and somewhat significant for the other compounds. The direct photolysis of metoxuron and diuron is known to increase toxicity, and such a photoreaction pathway would be enhanced at intermediate DOC values (1-4 mg C L(1)). The reaction between phenylureas and ·OH is known to produce toxic intermediates, differently from (3)CDOM*. Therefore, the shift of reactivity from ·OH to (3)CDOM* with increasing DOC could reduce the environmental impact of photochemical transformation. Copyright © 2014 Elsevier Ltd. All rights reserved.

Perspective: Spectroscopy and kinetics of small gaseous Criegee intermediates

International Nuclear Information System (INIS)

Lee, Yuan-Pern

2015-01-01

The Criegee intermediates, carbonyl oxides proposed by Criegee in 1949 as key intermediates in the ozonolysis of alkenes, play important roles in many aspects of atmospheric chemistry. Because direct detection of these gaseous intermediates was unavailable until recently, previous understanding of their reactions, derived from indirect experimental evidence, had great uncertainties. Recent laboratory detection of the simplest Criegee intermediate CH 2 OO and some larger members, produced from ultraviolet irradiation of corresponding diiodoalkanes in O 2 , with various methods such as photoionization, ultraviolet absorption, infrared absorption, and microwave spectroscopy opens a new door to improved understanding of the roles of these Criegee intermediates. Their structures and spectral parameters have been characterized; their significant zwitterionic nature is hence confirmed. CH 2 OO, along with other products, has also been detected directly with microwave spectroscopy in gaseous ozonolysis reactions of ethene. The detailed kinetics of the source reaction, CH 2 I + O 2 , which is critical to laboratory studies of CH 2 OO, are now understood satisfactorily. The kinetic investigations using direct detection identified some important atmospheric reactions, including reactions with NO 2 , SO 2 , water dimer, carboxylic acids, and carbonyl compounds. Efforts toward the characterization of larger Criegee intermediates and the investigation of related reactions are in progress. Some reactions of CH 3 CHOO are found to depend on conformation. This perspective examines progress toward the direct spectral characterization of Criegee intermediates and investigations of the associated reaction kinetics, and indicates some unresolved problems and prospective challenges for this exciting field of research

Kinetics of formation of acrylamide and Schiff base intermediates from asparagine and glucose

DEFF Research Database (Denmark)

Hedegaard, Rikke Susanne Vingborg; Frandsen, Henrik; Skibsted, Leif H.

2008-01-01

From the concentration of glucose and asparagine as reactants and of acrylamide as product each determined by LC-MS during reaction in an acetonitrile/water (68:32) model system at pH 7.6 (0.04 M phosphate buffer) and from the relative concentration of the Schiff base intermediate, the decarboxyl......From the concentration of glucose and asparagine as reactants and of acrylamide as product each determined by LC-MS during reaction in an acetonitrile/water (68:32) model system at pH 7.6 (0.04 M phosphate buffer) and from the relative concentration of the Schiff base intermediate...

Photosynthetic water oxidation: binding and activation of substrate waters for O-O bond formation.

Science.gov (United States)

Vinyard, David J; Khan, Sahr; Brudvig, Gary W

2015-01-01

Photosynthetic water oxidation occurs at the oxygen-evolving complex (OEC) of Photosystem II (PSII). The OEC, which contains a Mn4CaO5 inorganic cluster ligated by oxides, waters and amino-acid residues, cycles through five redox intermediates known as S(i) states (i = 0-4). The electronic and structural properties of the transient S4 intermediate that forms the O-O bond are not well understood. In order to gain insight into how water is activated for O-O bond formation in the S4 intermediate, we have performed a detailed analysis of S-state dependent substrate water binding kinetics taking into consideration data from Mn coordination complexes. This analysis supports a model in which the substrate waters are both bound as terminal ligands and react via a water-nucleophile attack mechanism.

Rapid shift and millennial-scale variations in Holocene North Pacific Intermediate Water ventilation.

Science.gov (United States)

Lembke-Jene, Lester; Tiedemann, Ralf; Nürnberg, Dirk; Gong, Xun; Lohmann, Gerrit

2018-05-22

The Pacific hosts the largest oxygen minimum zones (OMZs) in the world ocean, which are thought to intensify and expand under future climate change, with significant consequences for marine ecosystems, biogeochemical cycles, and fisheries. At present, no deep ventilation occurs in the North Pacific due to a persistent halocline, but relatively better-oxygenated subsurface North Pacific Intermediate Water (NPIW) mitigates OMZ development in lower latitudes. Over the past decades, instrumental data show decreasing oxygenation in NPIW; however, long-term variations in middepth ventilation are potentially large, obscuring anthropogenic influences against millennial-scale natural background shifts. Here, we use paleoceanographic proxy evidence from the Okhotsk Sea, the foremost North Pacific ventilation region, to show that its modern oxygenated pattern is a relatively recent feature, with little to no ventilation before six thousand years ago, constituting an apparent Early-Middle Holocene (EMH) threshold or "tipping point." Complementary paleomodeling results likewise indicate a warmer, saltier EMH NPIW, different from its modern conditions. During the EMH, the Okhotsk Sea switched from a modern oxygenation source to a sink, through a combination of sea ice loss, higher water temperatures, and remineralization rates, inhibiting ventilation. We estimate a strongly decreased EMH NPIW oxygenation of ∼30 to 50%, and increased middepth Pacific nutrient concentrations and carbon storage. Our results ( i ) imply that under past or future warmer-than-present conditions, oceanic biogeochemical feedback mechanisms may change or even switch direction, and ( ii ) provide constraints on the high-latitude North Pacific's influence on mesopelagic ventilation dynamics, with consequences for large oceanic regions. Copyright © 2018 the Author(s). Published by PNAS.

Reactivity of Criegee Intermediates toward Carbon Dioxide.

Science.gov (United States)

Lin, Yen-Hsiu; Takahashi, Kaito; Lin, Jim Jr-Min

2018-01-04

Recent theoretical work by Kumar and Francisco suggested that the high reactivity of Criegee intermediates (CIs) could be utilized for designing efficient carbon capture technologies. Because the anti-CH 3 CHOO + CO 2 reaction has the lowest barrier in their study, we chose to investigate it experimentally. We probed anti-CH 3 CHOO with its strong UV absorption at 365 nm and measured the rate coefficient to be ≤2 × 10 -17 cm 3 molecule -1 s -1 at 298 K, which is consistent with our theoretical value of 2.1 × 10 -17 cm 3  molecule -1 s -1 at the QCISD(T)/CBS//B3LYP/6-311+G(2d,2p) level but inconsistent with their results obtained at the M06-2X/aug-cc-pVTZ level, which tends to underestimate the barrier heights. The experimental result indicates that the reaction of a Criegee intermediate with atmospheric CO 2 (400 ppmv) would be inefficient (k eff < 0.2 s -1 ) and cannot compete with other decay processes of Criegee intermediates like reactions with water vapor (∼10 3 s -1 ) or thermal decomposition (∼10 2 s -1 ).

An analysis of system pressure and temperature distribution in self-pressurizer of SMART considering thermal stratification at intermediate cavity

Energy Technology Data Exchange (ETDEWEB)

Kang, Yeon Moon; Lee, Doo Jeong; Yoon, Ju Hyun; Kim, Hwan Yeol [Korea Atomic Energy Research Institute, Taejon (Korea)

1999-03-01

Because the pressurizer is in reactor vessel, the heat transfer from primary water would increase the temperatures of fluids in pressurizer to same temperature of hotleg, if no cooling equipment were supplied. Thus, heat exchanger and thermal insulator are needed to minimize heat transferred from primary water and to remove heat in pressurizer. The temperatures in cavities of pressurizer for normal operation are 70 deg C and 74 deg C for intermediate and end cavity, respectively, which considers the solubility of nitrogen gas in water. Natural convection is the mechanism of heat balance in pressurizer of SMART. In SMART, the heat exchanger in pressurizer is placed in lower part of intermediate cavity, so the heat in upper part of intermediate cavity can't be removed adequately and it can cause thermal stratification. If thermal stratification occurred, it increases heat transfers to nitrogen gas and system pressure increases as the result. Thus, proper evaluation of those effects on system pressure and ways to mitigate thermal stratification should be established. This report estimates the system pressure and temperatures in cavities of pressurizer with considering thermal stratification in intermediate cavity. The system pressure and temperatures for each cavities considered size of wet thermal insulator, temperature of upper plate of reactor vessel, parameters of heat exchanger in intermediate cavity such as flow rate and temperature of cooling water, heat transfer area, effective tube height, and location of cooling tube. In addition to the consideration of thermal stratification thermal mixing of all water in intermediate cavity also considered and compared in this report. (author). 6 refs., 60 figs., 2 tabs.

Origin and pathways of Winter Intermediate Water in the Northwestern Mediterranean Sea using observations and numerical simulation

Science.gov (United States)

Juza, Mélanie; Renault, Lionel; Ruiz, Simon; Tintoré, Joaquin

2013-12-01

The study of water masses worldwide (their formation, spreading, mixing, and impact on general circulation) is essential for a better understanding of the ocean circulation and variability. In this paper, the formation and main pathways of Winter Intermediate Water (WIW) in the Northwestern Mediterranean Sea (NWMED) are investigated during the winter-spring 2011 using observations and numerical simulation. The main results show that the WIW, formed along the continental shelves of the Gulf of Lion and Balearic Sea, circulates southward following five preferential pathways depending on the WIW formation site location and the oceanic conditions. WIW joins the northeastern part of the Balearic Sea, or flows along the continental shelves until joining the Balearic Current (maximum of 0.33 Sv in early-April) or further south until the Ibiza Channel entrance. Two additional trajectories, contributing to water mass exchanges with the southern part of the Western Mediterranean Sea, bring the WIW through the Ibiza and Mallorca Channels (maxima of 0.26 Sv in late-March and 0.1 Sv in early-April, respectively). The circulation of WIW over the NWMED at 50-200 m depth, its mixing and spreading over the Western Mediterranean Sea (reaching the south of the Balearic Islands, the Algero-Provencal basin, the Ligurian and the Alboran Seas) suggest that the WIW may have an impact on the ocean circulation by eddy blocking effect, exchange of water masses between north and south subbasins of Western Mediterranean Sea through the Ibiza Channel or modification of the ocean stratification.

On the nature of the Madagascar dipoles: An analysis from Argo profiling floats and altimetry measurements

Science.gov (United States)

Aguiar-González, Borja; Ponsoni, Leandro; Ridderinkhof, Herman; de Ruijter, Will P. M.; Maas, Leo R. M.

2016-04-01

The South East Madagascar Current (SEMC) flows poleward along the eastern coast of Madagascar as a western boundary current which further south provides some of the source waters of the Agulhas Current, either directly or in the form of eddies. We investigate the region of dipole formation south of Madagascar combining vertical T/S profiles from Argo floats, altimetry measurements and an existing eddy detection algorithm. Results from our analysis show that the dipole consists of an anticyclonic intrathermocline eddy (ITE) formed on its southern flank and a cyclonic ITE formed on its northern flank. Both lobes of the dipole exhibit similar T/S properties throughout the water column, although vertically shifted within the thermocline depending on its nature: upward in a cyclonic ITE and downward in an anticyclonic ITE. A subsurface salinity maximum of about 35.5 psu characterizes the upper layers with Subtropical Surface Water (STSW). At intermediate levels, a well defined path of South Indian Central Water (SICW) extends throughout the water column up to reach a minimum in salinity of 34.5 psu, corresponding to Antarctic Intermediate Water (AAIW). Below, at deep layers, the North Atlantic Deep Water (NADW) is found. The intrathermocline nature of the Madagascar dipoles has not been previously reported and represents an important feature to be considered when assessing the heat and salt fluxes driven by eddy movement and contributing to the Agulhas Current. Unlike surface eddies, intrathermocline eddies strongly influence the intermediate/deeper layers in the oceans and, hence, may have a larger contribution in the spreading rates and pathways of water masses. Because the intrathermocline nature of eddies is invisible to altimetry measurements, these results stress the importance of combining altimetry with historical records of Argo profiles which uncover eddy dynamics below the sea surface. Lastly, we further investigate from altimetry the area of dipole formation

Corrosion behavior of construction materials for intermediate temperature steam electrolysers

DEFF Research Database (Denmark)

Nikiforov, Aleksey; Petrushina, Irina; Jensen, Jens Oluf

2013-01-01

Different corrosion resistant stainless steels, nickel-based alloys, pure nickel, Ta-coated stainless steel (AISI 316L), niobium, platinum and gold rods were evaluated as possible materials for use in the intermediate temperature (200-400 °C) acidic water electrolysers. The corrosion resistance w...

On contribution of horizontal and intra-layer convection to the formation of the Baltic Sea cold intermediate layer

Directory of Open Access Journals (Sweden)

I. Chubarenko

2010-02-01

Full Text Available Seasonal cascades down the coastal slopes and intra-layer convection are considered as the two additional mechanisms contributing to the Baltic Sea cold intermediate layer (CIL formation along with conventional seasonal vertical mixing. Field measurements are presented, reporting for the first time the possibility of denser water formation and cascading from the Baltic Sea underwater slopes, which take place under fall and winter cooling conditions and deliver waters into intermediate layer of salinity stratified deep-sea area. The presence in spring within the CIL of water with temperature below that of maximum density (Tmd and that at the local surface in winter time allows tracing its formation: it is argued that the source of the coldest waters of the Baltic CIL is early spring (March–April cascading, arising due to heating of water before reaching the Tmd. Fast increase of the open water heat content during further spring heating indicates that horizontal exchange rather than direct solar heating is responsible for that. When the surface is covered with water, heated above the Tmd, the conditions within the CIL become favorable for intralayer convection due to the presence of waters of Tmd in intermediate layer, which can explain its well-known features – the observed increase of its salinity and deepening with time.

Last Glacial to Holocene changes of deep and intermediate water carbonate ion concentrations in the Southern Ocean: constraints from foraminiferal Boron/Calcium ratios

OpenAIRE

Kersten, Franziska

2013-01-01

In this thesis, the first records of intermediate and deep water carbonate ion concentrations in the South Pacific were generated in order to study carbon cycle dynamics throughout the past 30,000 years. Benthic foraminiferal B/Ca, an indicator of past seawater carbonate ion saturation is the main paleoceanographic proxy that was used in this study. Down-core proxy studies carried out within the scope of this thesis were used to address currently unresolved questions about the origin, mechani...

Crystal structure of the covalent intermediate of amylosucrase from Neisseria polysaccharea

DEFF Research Database (Denmark)

Jensen, Malene H; Mirza, Osman Asghar; Albenne, Cecile

2004-01-01

The alpha-retaining amylosucrase from the glycoside hydrolase family 13 performs a transfer reaction of a glucosyl moiety from sucrose to an acceptor molecule. Amylosucrase has previously been shown to be able to use alpha-D-glucopyranosyl fluoride as a substrate, which suggested that it could also...... the first covalent intermediate of an alpha-retaining glycoside hydrolase where the glucosyl moiety is identical to the expected biologically relevant entity. Comparison to other enzymes with anticipated glucosylic covalent intermediates suggests that this structure is a representative model...... for such intermediates. Analysis of the active site shows how oligosaccharide binding disrupts the putative nucleophilic water binding site found in the hydrolases of the GH family 13. This reveals important parts of the structural background for the shift in function from hydrolase to transglycosidase seen...

Intermediate neutron spectrum problems and the intermediate neutron spectrum experiment

International Nuclear Information System (INIS)

Jaegers, P.J.; Sanchez, R.G.

1996-01-01

Criticality benchmark data for intermediate energy spectrum systems does not exist. These systems are dominated by scattering and fission events induced by neutrons with energies between 1 eV and 1 MeV. Nuclear data uncertainties have been reported for such systems which can not be resolved without benchmark critical experiments. Intermediate energy spectrum systems have been proposed for the geological disposition of surplus fissile materials. Without the proper benchmarking of the nuclear data in the intermediate energy spectrum, adequate criticality safety margins can not be guaranteed. The Zeus critical experiment now under construction will provide this necessary benchmark data

Gibbs Free Energy of Hydrolytic Water Molecule in Acyl-Enzyme Intermediates of a Serine Protease: A Potential Application for Computer-Aided Discovery of Mechanism-Based Reversible Covalent Inhibitors.

Science.gov (United States)

Masuda, Yosuke; Yamaotsu, Noriyuki; Hirono, Shuichi

2017-01-01

In order to predict the potencies of mechanism-based reversible covalent inhibitors, the relationships between calculated Gibbs free energy of hydrolytic water molecule in acyl-trypsin intermediates and experimentally measured catalytic rate constants (k cat ) were investigated. After obtaining representative solution structures by molecular dynamics (MD) simulations, hydration thermodynamics analyses using WaterMap™ were conducted. Consequently, we found for the first time that when Gibbs free energy of the hydrolytic water molecule was lower, logarithms of k cat were also lower. The hydrolytic water molecule with favorable Gibbs free energy may hydrolyze acylated serine slowly. Gibbs free energy of hydrolytic water molecule might be a useful descriptor for computer-aided discovery of mechanism-based reversible covalent inhibitors of hydrolytic enzymes.

Mediterranean intermediate circulation estimated from Argo data in 2003–2010

Directory of Open Access Journals (Sweden)

M. Menna

2010-03-01

Full Text Available Data from 38 Argo profiling floats are used to describe the intermediate Mediterranean currents for the period October 2003–January 2010. These floats were programmed to execute 5-day cycles, to drift at a neutral parking depth of 350 m and measure temperature and salinity profiles from either 700 or 2000 m up to the surface. At the end of each cycle the floats remained at the sea surface for about 6 h, enough time to be localised and transmit the data to the Argos satellite system. The Argos positions were used to determine the float surface and intermediate displacements. At the surface, the float motion was approximated by a linear displacement and inertial motion. Intermediate velocities estimates were used to investigate the Mediterranean circulation at 350 m, to compute the pseudo-Eulerian statistics and to study the influence of bathymetry on the intermediate currents. Maximum speeds, as large as 33 cm/s, were found northeast of the Balearic Islands (western basin and in the Ierapetra eddy (eastern basin. Typical speeds in the main along-slope currents (Liguro-Provençal-Catalan, Algerian and Libyo-Egyptian Currents were ~20 cm/s. In the central and western part of Mediterranean basin, the pseudo-Eulerian statistics show typical intermediate circulation pathways which can be related to the motion of Levantine Intermediate Water. In general our results agree with the qualitative intermediate circulation schemes proposed in the literature, except in the southern Ionian where we found westward-flowing intermediate currents. Fluctuating currents appeared to be usually larger than the mean flow. Intermediate currents were found to be essentially parallel to the isobaths over most of the areas characterized by strong bathymetry gradients, in particular, in the vicinity of the continental slopes.

La0.6Sr0.4Co0.2Fe0.8O3-δ nanofiber cathode for intermediate-temperature solid oxide fuel cells by water-based sol-gel electrospinning: Synthesis and electrochemical behaviour

DEFF Research Database (Denmark)

Enrico, Anna; Zhang, Wenjing (Angela); Traulsen, Marie Lund

2018-01-01

Water-based sol-gel electrospinning is employed to manufacture perovskite oxide La0.6Sr0.4Co0.2Fe0.8O3-δ (LSCF) nanofiber cathodes for intermediate-temperature solid oxide fuel cells. LSCF fibrous scaffolds are synthesized through electrospinning of a sol-gel solution employing water as the only...

The Indonesian Throughflow (ITF) and its impacts on the Indian Ocean during the global warming slowdown period

Science.gov (United States)

Makarim, S.; Liu, Z.; Yu, W.; Yan, X.; Sprintall, J.

2016-12-01

The global warming slowdown indicated by a slower warming rate at the surface layer accompanied by stronger heat transport into the deeper layers has been explored in the Indian Ocean. Although the mechanisms of the global warming slowdown are still under warm debate, some clues have been recognized that decadal La Nina like-pattern induced decadal cooling in the Pacific Ocean and generated an increase of the Indonesian Throughflow (ITF) transport in 2004-2010. However, how the ITF spreading to the interior of the Indian Ocean and the impact of ITF changes on the Indian Ocean, in particular its water mass transformation and current system are still unknown. To this end, we analyzed thermohaline structure and current system at different depths in the Indian Ocean both during and just before the global warming slowdown period using the ORAS4 and ARGO dataset. Here, we found the new edge of ITF at off Sumatra presumably as northward deflection of ITF Lombok Strait, and The Monsoon Onset Monitoring and Social Ecology Impact (MOMSEI) and Java Upwelling Variation Observation (JUVO) dataset confirmed this evident. An isopycnal mixing method initially proposed by Du et al. (2013) is adopted to quantify the spreading of ITF water in the Indian Ocean, and therefore the impacts of ITF changes on the variation of the Agulhas Current, Leuween Current, Bay of Bengal Water. This study also prevailed the fresher salinity in the Indian Ocean during the slowdown warming period were not only contributed by stronger transport of the ITF, but also by freshening Arabian Sea and infiltrating Antartic Intermediate Water (AAIW).

The South-to-North Water Diversion Project: effect of the water diversion pattern on transmission of Oncomelania hupensis, the intermediate host of Schistosoma japonicum in China.

Science.gov (United States)

Liang, You-Sheng; Wang, Wei; Li, Hong-Jun; Shen, Xue-Hui; Xu, Yong-Liang; Dai, Jian-Rong

2012-03-20

The South-to-North Water Diversion Project (SNWDP) is the largest national water conservancy project in China. However, the Eastern Route Project (ERP) of SNWDP will refer to the habitats of Oncomelania hupensis, the intermediate host of Schistosoma japonicum. The present study was aimed at investigating the effects of some factors relating to the water diversion pattern on the spread north of O. hupensis and transmission of S. japonicum. Marked snails were attached to the floating debris, and then placed on the water surface, the passage of snails through water pumps was observed. Some marked living adult snails were placed under water in the 5 spots, 15, 30, 60, 90 and 120 days later, their survival and transfer under water were investigated. 2, 4, 8, 16, 32, 64 and 128 juvenile snails, with a male: female ratio of about 1, were caged, 1 year later, their reproductions were calculated. The snails attached on the floating debris at 100-, 50- and 20-cm-distance from the inlet pipe of the big pump (with a diameter of 80 cm), could be absorbed into the pumps, with passing rates of 2.45%, 3.93% and 43.46%, respectively, compared with 72.07% and 91.00% for the snails at 20 cm and 10 cm-distance from the inlet pipe of the small pump (with a diameter of 20 cm). A total of 36,600 marked living snails were put into 5 ponds and ditches, with the water depths of 1-1.6 m, 15-120 days later, no marked ones were found along the ponds and ditches or in the straw packages. The juvenile snails did not reproduce until their density reached up to 8 snails (ratio of male: female of 1)/0.16 m2. During the construction of ERP of SNWDP, the risk of northward spread of schistosomiasis japonica will be decreased or eliminated as long as long-term reliable interventions for snail control are implemented.

Intermediality and media change

OpenAIRE

2012-01-01

This book is about intermediality as an approach to analysing and understanding media change. Intermediality and Media Change is critical of technological determinism that characterises 'new media discourse' about the ongoing digitalization, framed as a revolution and creating sharp contrasts between old and new media. Intermediality instead emphasises paying attention to continuities between media of all types and privileges a comparative perspective on technological changes in media over ti...

Tracer signals of the intermediate layer of the Arabian Sea

Science.gov (United States)

Rhein, Monika; Stramma, Lothar; Plähn, Olaf

In 1995, hydrographic and chlorofluorocarbon (CFCs, components F11, F12) measurements were carried out in the Gulf of Aden, in the Gulf of Oman, and in the Arabian Sea. In the Gulf of Oman, the F12 concentrations in the Persian Gulf outflow (PGW) at about 300m depth were significantly higher than in ambient surface water with saturations reaching 270%. These high values could not be caused by air-sea gas exchange. The outflow was probably contaminated with oil, and the lipophilic character of the CFCs could then lead to the observed supersaturations. The intermediate F12 maximum decreased rapidly further east and south. At the Strait of Bab el Mandeb in the Gulf of Aden, the Red Sea outflow (RSW) was saturated with F12 to about 65% at 400m depth, and decreased to 50% while descending to 800m depth. The low saturation is not surprising, because the outflow contains deep and intermediate water masses from the Red Sea which were isolated from the surface for some time. The tracer contributions to the Arabian Sea for Indian Central Water (ICW) and PGW are about equal, while below 500m depth the RSW contribution greatly exceeds ICW. Modeling the CFC budget of the Arabian Sea, the inflow of ICW north of 12°N is estimated to be 1-6 Sv, depending mainly on the strength of the flow of Red Sea Water into the Arabian Sea.

Intermediate Fragment

DEFF Research Database (Denmark)

Kruse Aagaard, Anders

2015-01-01

This text and its connected exhibition are aiming to reflect both on the thoughts, the processes and the outcome of the design and production of the artefact ‘Intermediate Fragment’ and making as a contemporary architectural tool in general. Intermediate Fragment was made for the exhibition ‘Enga...... of realising an exhibition object was conceived, but expanded, refined and concretised through this process. The context of the work shown here is an interest in a tighter, deeper connection between experimentally obtained material knowledge and architectural design....

Governance-Default Risk Relationship and the Demand for Intermediated and Non-Intermediated Debt

Directory of Open Access Journals (Sweden)

Husam Aldamen

2012-09-01

Full Text Available This paper explores the impact of corporate governance on the demand for intermediated debt (asset finance, bank debt, non-bank private debt and non-intermediated debt (public debt in the Australian debt market. Relative to other countries the Australian debt market is characterised by higher proportions of intermediated or private debt with a lower inherent level of information asymmetry in that private lenders have greater access to financial information (Gray, Koh & Tong 2009. Our firm level, cross-sectional evidence suggests that higher corporate governance impacts demand for debt via the mitigation of default risk. However, this relationship is not uniform across all debt types. Intermediated debt such as bank and asset finance debt are more responsive to changes in governance-default risk relationship than non-bank and non-intermediated debt. The implication is that a firm’s demand for different debt types will reflect its governance-default risk profile.

Ozone decomposition in water studied by pulse radiolysis. 2. OH and HO4 as chain intermediates

International Nuclear Information System (INIS)

Staehelin, J.; Buehler, R.E.; Hoigne, J.

1984-01-01

Ozone decomposition in pure water involves a chain mechanism, initiated by the reaction OH - +O 3 and propogated by O 2 - and OH. In the present studies this chain is initiated by pulse radiolysis of aqueous solutions of ozone. The chain propogation steps were studied in two parts. By computer simulation of the rate curves, it is shown that from OH + O 3 and intermediate HO 4 must be formed, most likely a charge-transfer complex (HO.O 3 ), which eventually decays into HO 2 . The derived rate constants for the formation of the various species are included. The spectrum of HO 4 is derived. It is similar to the one of ozone, but the absorption coefficients are about 50% larger. In the presence of high ozone concentration, the dominant chain termination reactions are HO 4 + HO 4 and HO 4 + HO 3 . The effect on chain length, dose, overall rate, and pH and of added scavengers is described. The implications for the natural ozone decay mechanism are discussed

Intermediate report on the problems of warm water drainage

International Nuclear Information System (INIS)

1976-01-01

The investigation into the solution of the problems of warm water drainage and its related matters was conducted, and the result was summarized by the warm water drainage sectional committee of the central public nuisance-prevention council entrusted by the Environment Agency. The first section of this report deals with the background of the warm water drainage problems. In December 1970, the environmental pollution prevention act was revised so as to include warm water drainage in the law. The second section deals with the progress of deliberation by the sectional committee. The third section deals with the actual conditions of warm water drainage. The temperature difference at the inlet and outlet of water was 5 to 11 0 C in power plants, 5 to 16 0 C in iron and steel works, 4 to 11 0 C in petroleum refineries, and 7 to 25 0 C in petrochemical plants. The amount of heat energy discharged from power plants was greater than that from the others. Other sections deal with its effects on the living things in water, the forecast of diffusion of warm drainage, the concept of the regulation of warm drainage, and the present countermeasure. Twelve points which require future investigation are listed. They are the change in the phases of living things affected by the change in temperature and flow of warm drainage, the effects on fishery resources, the estimation system for the environmental calorific capacity in the sea, the mechanism of diffusion and the forecasting method for the diffusion range. (Iwakiri, K.)

MHD intermediate shock discontinuities: Pt. 1

International Nuclear Information System (INIS)

Kennel, C.F.; Blandford, R.D.; Coppi, P.

1989-01-01

Recent numerical investigations have focused attention once more on the role of intermediate shocks in MHD. Four types of intermediate shock are identified using a graphical representation of the MHD Rankine-Hugoniot conditions. This same representation can be used to exhibit the close relationship of intermediate shocks to switch-on shocks and rotational discontinuities. The conditions under which intermediate discontinuities can be found are elucidated. The variations in velocity, pressure, entropy and magnetic-field jumps with upstream parameters in intermediate shocks are exhibited graphically. The evolutionary arguments traditionally advanced against intermediate shocks may fail because the equations of classical MHD are not strictly hyperbolic. (author)

Turbulence, aeration and bubble features of air-water flows in macro- and intermediate roughness conditions

Directory of Open Access Journals (Sweden)

Stefano Pagliara

2011-06-01

Full Text Available Free surface flows in macro- and intermediate roughness conditions have a high aeration potential causing the flow characteristics to vary with slopes and discharges. The underlying mechanism of two-phase flow characteristics in macro- and intermediate roughness conditions were analyzed in an experimental setup assembled at the Laboratory of Hydraulic Protection of the Territory (PITLAB of the University of Pisa, Italy. Crushed angular rocks and hemispherical boulders were used to intensify the roughness of the bed. Flow rates per unit width ranging between 0.03 m2/s and 0.09 m2/s and slopes between 0.26 and 0.46 were tested over different arrangements of a rough bed. Analyses were mainly carried out in the inner flow region, which consists of both bubbly and intermediate flow regions. The findings revealed that the two-phase flow properties over the rough bed were much affected by rough bed arrangements. Turbulence features of two-phase flows over the rough bed were compared with those of the stepped chute data under similar flow conditions. Overall, the results highlight the flow features in the inner layers of the two-phase flow, showing that the maximum turbulence intensity decreases with the relative submergence, while the bubble frequency distribution is affected by the rough bed elements.

Metal Phosphates as Intermediate Temperature Proton Conducting Electrolytes

DEFF Research Database (Denmark)

Huang, Yunjie; Li, Q.F.; Pan, Chao

2012-01-01

A series of metal phosphates were synthesized and screened as potential proton conductor electrolytes for fuel cells and electrolysers operational at intermediate temperatures. Among the selected, niobium and bismuth phosphates exhibited a proton conductivity of 10-2 and 10-7 S cm-1, respectively......, under the anhydrous atmosphere at 250 °C, showing close correlation with the presence of hydroxyl groups in the phosphate phases. At the water partial pressure of above 0.6 atm, both phosphates possessed a proton conductivity to a level of above 3 x 10-2 S cm-1. Reasonable stability of the proton...... conductivity was observed under either a constant low water partial pressure or under a humidity cycling test within a period of more than 80 hours....

Review of Global Ocean Intermediate Water Masses: 1.Part A,the Neutral Density Surface (the 'McDougall Surface') as a Study Frame for Water-Mass Analysis

Institute of Scientific and Technical Information of China (English)

Yuzhu You

2006-01-01

This review article commences with a comprehensive historical review of the evolution and application of various density surfaces in atmospheric and oceanic studies.The background provides a basis for the birth of the neutral density idea.Attention is paid to the development of the neutral density surface concept from the nonlinearity of the equation of state of seawater.The definition and properties of neutral density surface are described in detail as developed from the equations of state of seawater and the buoyancy frequency when the squared buoyancy frequency N2 is zero, a neutral state of stability.In order to apply the neutral density surface to intermediate water-mass analysis, this review also describes in detail its practical oceanographic application.The mapping technique is focused for the first time on applying regularly gridded data in this review.It is reviewed how a backbone and ribs framework was designed to flesh out from a reference cast and first mapped the global neutral surfaces in the world's oceans.Several mapped neutral density surfaces are presented as examples for each world ocean.The water-mass property is analyzed in each ocean at mid-depth.The characteristics of neutral density surfaces are compared with those of potential density surfaces.

Information acquisition and financial intermediation

OpenAIRE

Boyarchenko, Nina

2012-01-01

This paper considers the problem of information acquisition in an intermediated market, where the specialists have access to superior technology for acquiring information. These informational advantages of specialists relative to households lead to disagreement between the two groups, changing the shape of the intermediation-constrained region of the economy and increasing the frequency of periods when the intermediation constraint binds. Acquiring the additional information is, however, cost...

Stability and anti-glycation properties of intermediate moisture apple products fortified with green tea.

Science.gov (United States)

Lavelli, Vera; Corey, Mark; Kerr, William; Vantaggi, Claudia

2011-07-15

Intermediate moisture products made from blanched apple flesh and green tea extract (about 6mg of monomeric flavan 3-ols added per g of dry apple) or blanched apple flesh (control) were produced, and their quality attributes were investigated over storage for two months at water activity (a(w)) levels of 0.55 and 0.75, at 30°C. Products were evaluated for colour (L(∗), a(∗), and b(∗) Hunter's parameters), phytochemical contents (flavan 3-ols, chlorogenic acid, dihydrochalcones, ascorbic acid and total polyphenols), ferric reducing antioxidant potential, 2,2-diphenyl-1-(2,4,6-trinitrophenyl)hydrazyl radical-scavenging activity and ability to inhibit formation of fructose-induced advanced glycation end-products. During storage of the fortified and unfortified intermediate moisture apples, water availability was sufficient to support various chemical reactions involving phytochemicals, which degraded at different rates: ascorbic acid>flavan 3-ols>dihydrochalcones and chlorogenic acid. Colour variations occurred at slightly slower rates after green tea addition. In the intermediate moisture apple, antioxidant and anti-glycoxidative properties decreased at similar rates (half-life was about 80d at a(w) of 0.75, 30°C). In the green tea-fortified intermediate moisture apple, the antioxidant activity decreased at a slow rate (half-life was 165d at a(w) of 0.75, 30°C) and the anti-glycoxidative properties did not change, indicating that flavan 3-ol degradation involved the formation of derivatives that retained the properties of their parent compounds. Since these properties are linked to oxidative- and advanced glycation end-product-related diseases, these results suggest that green tea fortification of intermediate moisture apple products could be a valuable means of product innovation, to address consumers' nutritional needs. Copyright © 2011 Elsevier Ltd. All rights reserved.

Abandoning the ship: spontaneous mass exodus of Clinostomum complanatum (Rudolphi, 1814) progenetic metecercariae from the dying intermediate host Trichogaster fasciatus (Bloch & Schneider, 1801).

Science.gov (United States)

Rizvi, Asim; Alam, Md Maroof; Parveen, Saltanat; Saleemuddin, M; Abidi, S M A

2012-04-01

The dramatic and spontaneous exodus of live Clinostomum complanatum progenetic metacercaria from the gill slits of the dying intermediate host, Trichogaster fasciatus is reported. Basic water parameter tests for dissolved oxygen, pH and temperature revealed slightly lower level of dissolved oxygen in tank water used for water change. To the best of our knowledge, it is the first report of a digenean metacercariae, en mass leaving their intermediate host, upon its death in search of an alternative host to support their survival and help in continuing their life cycle.

Discourses and Models of Intermediality

OpenAIRE

Schröter, Jens

2011-01-01

In his article "Discourses and Models of Intermediality" Jens Schröter discusses the question as to what relations do different discourses pose between different "media." Schröter identifies four models of discourse: 1) synthetic intermediality: a "fusion" of different media to super-media, a model with roots in the Wagnerian concept of Gesamtkunstwerk with political connotations, 2) formal (or transmedial) intermediality: a concept based on formal structures not "specific" to one medium but ...

Intermediate-field transport of contaminants

International Nuclear Information System (INIS)

Ahn, J.; Kim, C.L.; Chambre, P.L.; Pigford, T.H.; Lee, W.W.L.

1989-06-01

This report is about ''intermediate-field'' transport or the migration of contaminants from arrays of discrete waste packages or sources. In constructing nuclear waste repositories in rock, it may be necessary to place a waste package across a rock fracture, or a rock fracture may develop some time after waste packages have been emplaced. To predict the spatial and temporal distribution of contaminant species from a line of waste packages facing a rock fracture may be important, because such fractures may now be considered a preferential pathway for released radionuclides to re-enter the biosphere. In land disposal of hazardous wastes, individual barrels may contain especially toxic material whose dispersion special attention. We have published analytic solutions for the multidimensional advective transport of contaminants from arrays of waste packages and multiple areal sources into a planar fracture. The results show a near region in which the concentrations vary greatly in the direction transverse to ground-water flow, an intermediate region in which the array can be treated as an infinite plane source of dissolving species, and a far-field region in which the array can be treated as a plane source of finite extent. The array equations have been developed for both porous and fractured media. In this paper we summarize and compare the work with multiple areal sources facing a planar fracture and an array of point sources in porous media. 5 refs., 5 figs

Time-resolved resonance Raman spectroscopy of intermediates of bacteriorhodopsin: The bK(590) intermediate.

Science.gov (United States)

Terner, J; Hsieh, C L; Burns, A R; El-Sayed, M A

1979-07-01

We have combined microbeam and flow techniques with computer subtraction methods to obtain the resonance Raman spectrum of the short lived batho-intermediate (bK(590)) of bacteriorhodopsin. Comparison of the spectra obtained in (1)H(2)O and (2)H(2)O, as well as the fact that the bK(590) intermediate shows large optical red shifts, suggests that the Schiff base linkage of this intermediate is protonated. The fingerprint region of the spectrum of bK(590), sensitive to the isomeric configuration of the retinal chromophore, does not resemble the corresponding region of the parent bR(570) form. The resonance Raman spectrum of bK(590) as well as the spectra of all of the other main intermediates in the photoreaction cycle of bacteriorhodopsin are discussed and compared with resonance Raman spectra of published model compounds.

Role of Intermediate Filaments in Vesicular Traffic

Directory of Open Access Journals (Sweden)

Azzurra Margiotta

2016-04-01

Full Text Available Intermediate filaments are an important component of the cellular cytoskeleton. The first established role attributed to intermediate filaments was the mechanical support to cells. However, it is now clear that intermediate filaments have many different roles affecting a variety of other biological functions, such as the organization of microtubules and microfilaments, the regulation of nuclear structure and activity, the control of cell cycle and the regulation of signal transduction pathways. Furthermore, a number of intermediate filament proteins have been involved in the acquisition of tumorigenic properties. Over the last years, a strong involvement of intermediate filament proteins in the regulation of several aspects of intracellular trafficking has strongly emerged. Here, we review the functions of intermediate filaments proteins focusing mainly on the recent knowledge gained from the discovery that intermediate filaments associate with key proteins of the vesicular membrane transport machinery. In particular, we analyze the current understanding of the contribution of intermediate filaments to the endocytic pathway.

Preparation of dispersible graphene through organic functionalization of graphene using a zwitterion intermediate cycloaddition approach

NARCIS (Netherlands)

Zhang, Xiaoyan; Browne, Wesley R.; Feringa, Ben L.

2012-01-01

Highly functionalized graphene were obtained through a zwitterion intermediate cycloaddition onto exfoliated graphene flakes under new reaction conditions. The functionalized graphene obtained formed stable dispersions in common solvents, including dimethylformamide (DMF), CHCl3 and water. Its

Intermediality: Bridge to Critical Media Literacy.

Science.gov (United States)

Pailliotet, Ann Watts; Semali, Ladislaus; Rodenberg, Rita K.; Giles, Jackie K.; Macaul, Sherry L.

2000-01-01

Defines "intermediality" as the ability to critically read and write with and across varied symbol systems. Relates it to critical media literacy. Offers rationales for teaching critical media literacy in general, and intermedial instruction in particular. Identifies seven guiding intermedial elements: theory, texts, processes, contexts,…

Effect of intermediate zone during gamma-gamma and X-ray spectrum logging of quarry wells with inversive probes

International Nuclear Information System (INIS)

Artsybashev, V.A.; Volkov, A.A.

1981-01-01

Experimental and calculated data on the effect of intermediate zone on results of gamma-gamma and X-ray spectrum logging of quarry wells at chalcopyrite deposits are presented. The measurements have been carried out using 57 Co and 109 Cd sources for intermediate zone represented by water, air and mud. Requirements for technical conditions of wells have been formulated. According to the requirements the application of gamma- gamma method is possible when the thickness of the intermediate zone does not exceed several millimetres and that of X-ray spectrum method - when the thickness does not exceed several hundredths of a millimetre [ru

Formation rate of water masses in the Japan Sea

International Nuclear Information System (INIS)

Kawamura, Hideyuki; Ito, Toshimichi; Yoon, Jong-Hwan

2007-01-01

Water masses in the subsurface and the intermediate layer are actively formed due to strong winter convection in the Japan Sea. It is probable that some fraction of pollution is carried into the layer below the sea surface together with these water masses, so it is important to estimate the formation rate and turnover time of water masses to study the fate of pollutants. The present study estimates the annual formation rate and the turnover time of water masses using a three-dimensional ocean circulation model and a particle chasing method. The total annual formation rate of water masses below the sea surface amounted to about 3.53±0.55 Sv in the Japan Sea. Regarding representative intermediate water masses, the annual formation rate of the Upper portion of the Japan Sea Proper Water (UJSPW) and the Japan Sea Intermediate Water (JSIW) were estimated to be about 0.38±0.11 and 1.43±0.16 Sv, respectively, although there was little evidence of the formation of deeper water masses below a depth of about 1500 m in a numerical experiment. An estimate of turnover time shows that the UJSPW and the JSIW circulate in the intermediate layer of the Japan Sea with timescales of about 22.1 and 2.2 years, respectively. (author)

Fabrication and Characterizations of Materials and Components for Intermediate Temperature Fuel Cells and Water Electrolysers

DEFF Research Database (Denmark)

Jensen, Annemette Hindhede; Prag, Carsten Brorson; Li, Qingfeng

The worldwide development of fuel cells and electrolysers has so far almost exclusively addressed either the low temperature window (20-200 °C) or the high temperature window (600-1000 °C). This work concerns the development of key materials and components of a new generation of fuel cells...... and electrolysers for operation in the intermediate temperature range from 200 to 400 °C. The intermediate temperature interval is of importance for the use of renewable fuels. Furthermore electrode kinetics is significantly enhanced compared to when operating at low temperature. Thus non-noble metal catalysts...... might be used. One of the key materials in the fuel cell and electrolyser systems is the electrolyte. Proton conducting materials such as cesium hydrogen phosphates, zirconium hydrogen phosphates and tin pyrophosphates have been investigated by others and have shown interesting potential....

Short, intermediate and long range order in amorphous ices

Science.gov (United States)

Martelli, Fausto; Torquato, Salvatore; Giovanbattista, Nicolas; Car, Roberto

Water exhibits polyamorphism, i.e., it exists in more than one amorphous state. The most common forms of glassy water are the low-density amorphous (LDA) and the high-density amorphous (HDA) ices. LDA, the most abundant form of ice in the Universe, transforms into HDA upon isothermal compression. We model the transformation of LDA into HDA under isothermal compression with classical molecular dynamics simulations. We analyze the molecular structures with a recently introduced scalar order metric to measure short and intermediate range order. In addition, we rank the structures by their degree of hyperuniformity, i.e.,the extent to which long range density fluctuations are suppressed. F.M. and R.C. acknowledge support from the Department of Energy (DOE) under Grant No. DE-SC0008626.

Electron-atom scattering at intermediate energies

International Nuclear Information System (INIS)

Kingston, A.E.; Walters, H.R.J.

1982-01-01

The problems of intermediate energy scattering are approached from the low and high energy ends. At low intermediate energies difficulties associated with the use of pseudostates and correlation terms are discussed, special consideration being given to nonphysical pseudoresonances. Perturbation methods appropriate to high intermediate energies are described and attempts to extend these high energy approximations down to low intermediate energies are studied. It is shown how the importance of electron exchange effects develops with decreasing energy. The problem of assessing the 'effective completeness' of pseudostate sets at intermediate energies is mentioned and an instructive analysis of a 2p pseudostate approximation to elastic e - -H scattering is given. It is suggested that at low energies the Pauli Exclusion Principle can act to hide short range defects in pseudostate approximations. (author)

The intermediate state in Patd

African Journals Online (AJOL)

) Jesus had assumed. (concerning the 'intermediate state') as existing, anything which does not exist. Three basic things about the intermediate state emerge from the parable: (a) Jesus recognizes that at the moment of death, in ipso articulo.

Higher order antibunching in intermediate states

International Nuclear Information System (INIS)

Verma, Amit; Sharma, Navneet K.; Pathak, Anirban

2008-01-01

Since the introduction of binomial state as an intermediate state, different intermediate states have been proposed. Different nonclassical effects have also been reported in these intermediate states. But till now higher order antibunching is predicted in only one type of intermediate state, which is known as shadowed negative binomial state. Recently we have shown that the higher order antibunching is not a rare phenomenon [P. Gupta, P. Pandey, A. Pathak, J. Phys. B 39 (2006) 1137]. To establish our earlier claim further, here we have shown that the higher order antibunching can be seen in different intermediate states, such as binomial state, reciprocal binomial state, hypergeometric state, generalized binomial state, negative binomial state and photon added coherent state. We have studied the possibility of observing the higher order subpoissonian photon statistics in different limits of intermediate states. The effects of different control parameters on the depth of non classicality have also been studied in this connection and it has been shown that the depth of nonclassicality can be tuned by controlling various physical parameters

α-chymotrypsin in water-acetone and water-dimethyl sulfoxide mixtures: Effect of preferential solvation and hydration.

Science.gov (United States)

Sirotkin, Vladimir A; Kuchierskaya, Alexandra A

2017-10-01

We investigated water/organic solvent sorption and residual enzyme activity to simultaneously monitor preferential solvation/hydration of protein macromolecules in the entire range of water content at 25°C. We applied this approach to estimate protein destabilization/stabilization due to the preferential interactions of bovine pancreatic α-chymotrypsin with water-acetone (moderate-strength H-bond acceptor) and water-DMSO (strong H-bond acceptor) mixtures. There are three concentration regimes for the dried α-chymotrypsin. α-Chymotrypsin is preferentially hydrated at high water content. The residual enzyme activity values are close to 100%. At intermediate water content, the dehydrated α-chymotrypsin has a higher affinity for acetone/DMSO than for water. Residual enzyme activity is minimal in this concentration range. The acetone/DMSO molecules are preferentially excluded from the protein surface at the lowest water content, resulting in preferential hydration. The residual catalytic activity in the water-poor acetone is ∼80%, compared with that observed after incubation in pure water. This effect is very small for the water-poor DMSO. Two different schemes are operative for the hydrated enzyme. At high and intermediate water content, α-chymotrypsin exhibits preferential hydration. However, at intermediate water content, in contrast to the dried enzyme, the initially hydrated α-chymotrypsin possesses increased preferential hydration parameters. At low water content, no residual enzyme activity was observed. Preferential binding of DMSO/acetone to α-chymotrypsin was detected. Our data clearly demonstrate that the hydrogen bond accepting ability of organic solvents and the protein hydration level constitute key factors in determining the stability of protein-water-organic solvent systems. © 2017 Wiley Periodicals, Inc.

Directional spread parameter at intermediate water depth

Digital Repository Service at National Institute of Oceanography (India)

SanilKumar, V.; Deo, M.C.; Anand, N.M.; AshokKumar, K.

’ involves only the significant wave height, zero crossing wave period and water depth, the spreading function based on ‘s 3 ’ can be used for practical appli- cation. In the model based on ‘s 3 ’ the mean wave direction is an input and this has...-linearity parameter can be recommended for practical use as it provides an averaged distribution. Acknowledgements The authors would like to thank the Department of Science and Technology, New Delhi, for funding the project titled “Directional wave modelling...

[Therapy of intermediate uveitis].

Science.gov (United States)

Doycheva, D; Deuter, C; Zierhut, M

2014-12-01

Intermediate uveitis is a form of intraocular inflammation in which the vitreous body is the major site of inflammation. Intermediate uveitis is primarily treated medicinally and systemic corticosteroids are the mainstay of therapy. When recurrence of uveitis or side effects occur during corticosteroid therapy an immunosuppressive treatment is required. Cyclosporine A is the only immunosuppressive agent that is approved for therapy of uveitis in Germany; however, other immunosuppressive drugs have also been shown to be effective and well-tolerated in patients with intermediate uveitis. In severe therapy-refractory cases when conventional immunosuppressive therapy has failed, biologics can be used. In patients with unilateral uveitis or when the systemic therapy is contraindicated because of side effects, an intravitreal steroid treatment can be carried out. In certain cases a vitrectomy may be used.

Effect of Intermediate Hosts on Emerging Zoonoses.

Science.gov (United States)

Cui, Jing-An; Chen, Fangyuan; Fan, Shengjie

2017-08-01

Most emerging zoonotic pathogens originate from animals. They can directly infect humans through natural reservoirs or indirectly through intermediate hosts. As a bridge, an intermediate host plays different roles in the transmission of zoonotic pathogens. In this study, we present three types of pathogen transmission to evaluate the effect of intermediate hosts on emerging zoonotic diseases in human epidemics. These types are identified as follows: TYPE 1, pathogen transmission without an intermediate host for comparison; TYPE 2, pathogen transmission with an intermediate host as an amplifier; and TYPE 3, pathogen transmission with an intermediate host as a vessel for genetic variation. In addition, we established three mathematical models to elucidate the mechanisms underlying zoonotic disease transmission according to these three types. Stability analysis indicated that the existence of intermediate hosts increased the difficulty of controlling zoonotic diseases because of more difficult conditions to satisfy for the disease to die out. The human epidemic would die out under the following conditions: TYPE 1: [Formula: see text] and [Formula: see text]; TYPE 2: [Formula: see text], [Formula: see text], and [Formula: see text]; and TYPE 3: [Formula: see text], [Formula: see text], [Formula: see text], and [Formula: see text] Simulation with similar parameters demonstrated that intermediate hosts could change the peak time and number of infected humans during a human epidemic; intermediate hosts also exerted different effects on controlling the prevalence of a human epidemic with natural reservoirs in different periods, which is important in addressing problems in public health. Monitoring and controlling the number of natural reservoirs and intermediate hosts at the right time would successfully manage and prevent the prevalence of emerging zoonoses in humans.

Evaluation of alternative fluids for SFR intermediate loops

International Nuclear Information System (INIS)

Brissonneau, L.; Simon, N.; Baque, F.

2009-01-01

Among the Generation IV systems, Sodium Fast Reactors (SFR) are promising and benefit of considerable technological experience, but improvements are researched on safety approach and capital cost reduction. One of the main drawback to be solved by the standard SFR design is the proper management of the risk of leakage between the intermediate circuit filled with sodium and the energy conversion system using a water Rankine cycle. The limitation of this risk requires notably an early detection of water leakage to prevent a water-sodium reaction. One innovative solution consists in the replacement of the sodium in the secondary loops by an alternative liquid fluid, not or less reactive with water. This alternative fluid might also allow innovative designs, e.g. intermediate heat exchanger and steam generator grouped in the same component. CEA, Areva NP and EdF have joined in a working group in order to evaluate different 'alternative fluids' that might replace sodium. A first selection retained seven fluids on the basis of 'required properties' as large operating range (low melting point, high boiling point ...), fluid cost and availability, acceptable corrosion at SFR working temperature. These are three bismuth alloys, two nitrate salts, one hydroxide melt and sodium with nanoparticles of nickel. Then, it was decided to evaluate these fluids through a multi-criteria analysis in order to quantify advantages and drawbacks of each fluid and to compare them with sodium. Lack of knowledge, impact on materials, design, working conditions and reactor availability should be emphasized by this analysis, in order to provide sound arguments for a research program on one or two promising fluids. A global note is given to each fluid by evaluating them with respect to 'grand criteria', weighted differently according to their importance. The grand criteria are : thermal properties, reactivity with structures, reactivity with other fluids (air, water, sodium), chemistry control

Intermediate structure and threshold phenomena

International Nuclear Information System (INIS)

Hategan, Cornel

2004-01-01

The Intermediate Structure, evidenced through microstructures of the neutron strength function, is reflected in open reaction channels as fluctuations in excitation function of nuclear threshold effects. The intermediate state supporting both neutron strength function and nuclear threshold effect is a micro-giant neutron threshold state. (author)

Intermediate algebra & analytic geometry

CERN Document Server

Gondin, William R

1967-01-01

Intermediate Algebra & Analytic Geometry Made Simple focuses on the principles, processes, calculations, and methodologies involved in intermediate algebra and analytic geometry. The publication first offers information on linear equations in two unknowns and variables, functions, and graphs. Discussions focus on graphic interpretations, explicit and implicit functions, first quadrant graphs, variables and functions, determinate and indeterminate systems, independent and dependent equations, and defective and redundant systems. The text then examines quadratic equations in one variable, system

Storage Stability and Improvement of Intermediate Moisture Foods, Phase 3

Science.gov (United States)

Labuza, T. P.

1975-01-01

Methods were determined for the improvement of shelf-life stability of intermediate moisture foods (IMF). Microbial challenge studies showed that protection against molds and Staphylococcus aureus could be achieved by a combination of antimicrobial agents, humectants and food acids. Potassium sorbate and propylene glycol gave the best results. It was also confirmed that the maximum in heat resistance shown by vegetative pathogens at intermediate water activities also occurred in a solid food. Glycols and sorbitol both achieve browning inhibition because of their action as a medium for reaction and effect on viscosity of the adsorbed phase. Chemical availability results showed rapid lysine loss before visual discoloration occurred. This is being confirmed with a biological test using Tetrahymena pyriformis W. Accelerated temperature tests show that effectiveness of food antioxidants against rancidity development can be predicted; however, the protection factor changes with temperature. BHA was found to be the best antioxidant for iron catalyzed oxidation.

The Canary Basin contribution to 26ºN AMOC Seasonality

Science.gov (United States)

Pérez-Hernández, M. D.; McCarthy, G.; Smeed, D.; Hernandez-Guerra, A.; Vélez-Belchí, P.

2014-12-01

Recent studies have shown that the seasonal transport of the Atlantic Meridional Overturning Circulation (AMOC) is linked with seasonal density changes in the eastern boundary of the Atlantic. As measured by the RAPID/MOCHA array, the AMOC has a seasonal peak-to-peak value of 6 Sv, with two relative maximums in July and October. The relative maximum in October coincides with the weakest transport of the upper mid-ocean transport (UMO), from the Bahamas to the eastern boundary, whose amplitude is 4 Sv. The seasonally averaged dynamic height indicates that the major source of seasonal variability in the UMO is due to the eastern boundary in fall. Data from the RAPID/MOCHA array at 26ºN is analyzed together with the data from a 15-year mooring between the African coast and the Canary Islands at 28ºN, in the Lanzarote Passage, the so-called Eastern Boundary Current Mooring (EBC4). The seasonal dynamics of the eastern boundary is analyzed: the recirculation of the Canary Current in fall through the Lanzarote Passage, the Rossby wave formation and the wind forcing. Significant correlations are found between the transport through the LP and the UMO. The transport of the North Atlantic Central Water (NACW) as measured by the EBC4 mooring has a correlation of 0.75 at zero lag with the UMO transport, and the transport of the Antarctic Intermediate Water (AAIW) and Mediterranean Water (MW) are correlated 0.77/0.85 respectively, with a lag of one moth with the UMO. The results stress the importance of the eastern boundary in determining the seasonal variability of the AMOC, as measured by the RAPID/MOCHA array.

An Intermediate in the evolution of superfast sonic muscles

Directory of Open Access Journals (Sweden)

Mok Hin-Kiu

2011-11-01

Full Text Available Abstract Background Intermediate forms in the evolution of new adaptations such as transitions from water to land and the evolution of flight are often poorly understood. Similarly, the evolution of superfast sonic muscles in fishes, often considered the fastest muscles in vertebrates, has been a mystery because slow bladder movement does not generate sound. Slow muscles that stretch the swimbladder and then produce sound during recoil have recently been discovered in ophidiiform fishes. Here we describe the disturbance call (produced when fish are held and sonic mechanism in an unrelated perciform pearl perch (Glaucosomatidae that represents an intermediate condition in the evolution of super-fast sonic muscles. Results The pearl perch disturbance call is a two-part sound produced by a fast sonic muscle that rapidly stretches the bladder and an antagonistic tendon-smooth muscle combination (part 1 causing the tendon and bladder to snap back (part 2 generating a higher-frequency and greater-amplitude pulse. The smooth muscle is confirmed by electron microscopy and protein analysis. To our knowledge smooth muscle attachment to a tendon is unknown in animals. Conclusion The pearl perch, an advanced perciform teleost unrelated to ophidiiform fishes, uses a slow type mechanism to produce the major portion of the sound pulse during recoil, but the swimbladder is stretched by a fast muscle. Similarities between the two unrelated lineages, suggest independent and convergent evolution of sonic muscles and indicate intermediate forms in the evolution of superfast muscles.

Sustainable thorium nuclear fuel cycles: A comparison of intermediate and fast neutron spectrum systems

International Nuclear Information System (INIS)

Brown, N.R.; Powers, J.J.; Feng, B.; Heidet, F.; Stauff, N.E.; Zhang, G.; Todosow, M.; Worrall, A.; Gehin, J.C.; Kim, T.K.; Taiwo, T.A.

2015-01-01

Highlights: • Comparison of intermediate and fast spectrum thorium-fueled reactors. • Variety of reactor technology options enables self-sustaining thorium fuel cycles. • Fuel cycle analyses indicate similar performance for fast and intermediate systems. • Reproduction factor plays a significant role in breeding and burn-up performance. - Abstract: This paper presents analyses of possible reactor representations of a nuclear fuel cycle with continuous recycling of thorium and produced uranium (mostly U-233) with thorium-only feed. The analysis was performed in the context of a U.S. Department of Energy effort to develop a compendium of informative nuclear fuel cycle performance data. The objective of this paper is to determine whether intermediate spectrum systems, having a majority of fission events occurring with incident neutron energies between 1 eV and 10 5 eV, perform as well as fast spectrum systems in this fuel cycle. The intermediate spectrum options analyzed include tight lattice heavy or light water-cooled reactors, continuously refueled molten salt reactors, and a sodium-cooled reactor with hydride fuel. All options were modeled in reactor physics codes to calculate their lattice physics, spectrum characteristics, and fuel compositions over time. Based on these results, detailed metrics were calculated to compare the fuel cycle performance. These metrics include waste management and resource utilization, and are binned to accommodate uncertainties. The performance of the intermediate systems for this self-sustaining thorium fuel cycle was similar to a representative fast spectrum system. However, the number of fission neutrons emitted per neutron absorbed limits performance in intermediate spectrum systems

Sustainable thorium nuclear fuel cycles: A comparison of intermediate and fast neutron spectrum systems

Energy Technology Data Exchange (ETDEWEB)

Brown, N.R., E-mail: nbrown@bnl.gov [Brookhaven National Laboratory, Upton, NY (United States); Powers, J.J. [Oak Ridge National Laboratory, Oak Ridge, TN (United States); Feng, B.; Heidet, F.; Stauff, N.E.; Zhang, G. [Argonne National Laboratory, Argonne, IL (United States); Todosow, M. [Brookhaven National Laboratory, Upton, NY (United States); Worrall, A.; Gehin, J.C. [Oak Ridge National Laboratory, Oak Ridge, TN (United States); Kim, T.K.; Taiwo, T.A. [Argonne National Laboratory, Argonne, IL (United States)

2015-08-15

Highlights: • Comparison of intermediate and fast spectrum thorium-fueled reactors. • Variety of reactor technology options enables self-sustaining thorium fuel cycles. • Fuel cycle analyses indicate similar performance for fast and intermediate systems. • Reproduction factor plays a significant role in breeding and burn-up performance. - Abstract: This paper presents analyses of possible reactor representations of a nuclear fuel cycle with continuous recycling of thorium and produced uranium (mostly U-233) with thorium-only feed. The analysis was performed in the context of a U.S. Department of Energy effort to develop a compendium of informative nuclear fuel cycle performance data. The objective of this paper is to determine whether intermediate spectrum systems, having a majority of fission events occurring with incident neutron energies between 1 eV and 10{sup 5} eV, perform as well as fast spectrum systems in this fuel cycle. The intermediate spectrum options analyzed include tight lattice heavy or light water-cooled reactors, continuously refueled molten salt reactors, and a sodium-cooled reactor with hydride fuel. All options were modeled in reactor physics codes to calculate their lattice physics, spectrum characteristics, and fuel compositions over time. Based on these results, detailed metrics were calculated to compare the fuel cycle performance. These metrics include waste management and resource utilization, and are binned to accommodate uncertainties. The performance of the intermediate systems for this self-sustaining thorium fuel cycle was similar to a representative fast spectrum system. However, the number of fission neutrons emitted per neutron absorbed limits performance in intermediate spectrum systems.

Features of Red Sea Water Masses

KAUST Repository

Kartadikaria, Aditya R.; Hoteit, Ibrahim

2015-01-01

by seasonal variability, fresh water intrusion of the Gulf of Aden Intermediate Water (GAIW), and eddies variability. Two types of mixing; isopycnal and diapycnal mixing are part of important physical phenomena that explain the change of water mass in the Red

Regularities of intermediate adsorption complex relaxation

International Nuclear Information System (INIS)

Manukova, L.A.

1982-01-01

The experimental data, characterizing the regularities of intermediate adsorption complex relaxation in the polycrystalline Mo-N 2 system at 77 K are given. The method of molecular beam has been used in the investigation. The analytical expressions of change regularity in the relaxation process of full and specific rates - of transition from intermediate state into ''non-reversible'', of desorption into the gas phase and accumUlation of the particles in the intermediate state are obtained

FINANCIAL INTERMEDIATION, ENTREPRENEURSHIP AND ECONOMIC GROWTH

OpenAIRE

Wenli Cheng

2007-01-01

This paper presents a simple general equilibrium model of financial intermediation, entrepreneurship and economic growth. In this model, the role of financial intermediation is to pool savings and to lend the pooled funds to an entrepreneur, who in turn invests the funds in a new production technology. The adoption of the new production technology improves individual real income. Thus financial intermediation promotes economic growth through affecting individuals’ saving behaviour and enabl...

Some Intermediate-Level Violin Concertos.

Science.gov (United States)

Abramson, Michael

1997-01-01

Contends that many violin students attempt difficult concertos before they are technically or musically prepared. Identifies a variety of concertos at the intermediate and advanced intermediate-level for students to study and master before attempting the advanced works by Bach and Mozart. Includes concertos by Vivaldi, Leclair, Viotti, Haydn,…

Mode coupling theory analysis of electrolyte solutions: Time dependent diffusion, intermediate scattering function, and ion solvation dynamics.

Science.gov (United States)

Roy, Susmita; Yashonath, Subramanian; Bagchi, Biman

2015-03-28

A self-consistent mode coupling theory (MCT) with microscopic inputs of equilibrium pair correlation functions is developed to analyze electrolyte dynamics. We apply the theory to calculate concentration dependence of (i) time dependent ion diffusion, (ii) intermediate scattering function of the constituent ions, and (iii) ion solvation dynamics in electrolyte solution. Brownian dynamics with implicit water molecules and molecular dynamics method with explicit water are used to check the theoretical predictions. The time dependence of ionic self-diffusion coefficient and the corresponding intermediate scattering function evaluated from our MCT approach show quantitative agreement with early experimental and present Brownian dynamic simulation results. With increasing concentration, the dispersion of electrolyte friction is found to occur at increasingly higher frequency, due to the faster relaxation of the ion atmosphere. The wave number dependence of intermediate scattering function, F(k, t), exhibits markedly different relaxation dynamics at different length scales. At small wave numbers, we find the emergence of a step-like relaxation, indicating the presence of both fast and slow time scales in the system. Such behavior allows an intriguing analogy with temperature dependent relaxation dynamics of supercooled liquids. We find that solvation dynamics of a tagged ion exhibits a power law decay at long times-the decay can also be fitted to a stretched exponential form. The emergence of the power law in solvation dynamics has been tested by carrying out long Brownian dynamics simulations with varying ionic concentrations. The solvation time correlation and ion-ion intermediate scattering function indeed exhibit highly interesting, non-trivial dynamical behavior at intermediate to longer times that require further experimental and theoretical studies.

Water oxidation by photosystem II: H(2)O-D(2)O exchange and the influence of pH support formation of an intermediate by removal of a proton before dioxygen creation.

Science.gov (United States)

Gerencsér, László; Dau, Holger

2010-11-30

Understanding the chemistry of photosynthetic water oxidation requires deeper insight into the interrelation between electron transfer (ET) and proton relocations. In photosystem II membrane particles, the redox transitions of the water-oxidizing Mn complex were initiated by nanosecond laser flashes and monitored by absorption spectroscopy at 360 nm (A(360)). In the oxygen evolution transition (S(3) + hν → S(0) + O(2)), an exponential decrease in A(360) (τ(O(2)) = 1.6 ms) can be assigned to Mn reduction and O(2) formation. The corresponding rate-determining step is the ET from the Mn complex to a tyrosine radical (Y(Z)(ox)). We find that this A(360) decrease is preceded by a lag phase with a duration of 170 ± 40 μs (τ(lag) at pH 6.2), indicating formation of an intermediate before ET and O-O bond formation and corroborating results obtained by time-resolved X-ray spectroscopy. Whereas τ(O(2)) exhibits a minor kinetic isotope effect and negligible pH dependence, formation of the intermediate is slowed significantly both in D(2)O (τ(lag) increase of ∼140% in D(2)O) and at low pH (τ(lag) of 30 ± 20 μs at pH 7.0 vs τ(lag) of 470 ± 80 μs at pH 5.5). These findings support the fact that in the oxygen evolution transition an intermediate is created by deprotonation and removal of a proton from the Mn complex, after Y(Z)(ox) formation but before the onset of electron transfer and O-O bond formation.

Water levels shape fishing participation in flood-control reservoirs

Science.gov (United States)

Miranda, Leandro E.; Meals, K. O.

2013-01-01

We examined the relationship between fishing effort (hours fished) and average March–May water level in 3 flood control reservoirs in Mississippi. Fishing effort increased as water level rose, peaked at intermediate water levels, and decreased at high water levels. We suggest that the observed arched-shaped relationship is driven by the shifting influence of fishability (adequacy of the fishing circumstances from an angler's perspective) and catch rate along a water level continuum. Fishability reduces fishing effort during low water, despite the potential for higher catch rates. Conversely, reduced catch rates and fishability at high water also curtail effort. Thus, both high and low water levels seem to discourage fishing effort, whereas anglers seem to favor intermediate water levels. Our results have implications for water level management in reservoirs with large water level fluctuations.

Welding. Performance Objectives. Intermediate Course.

Science.gov (United States)

Vincent, Kenneth

Several intermediate performance objectives and corresponding criterion measures are listed for each of nine terminal objectives for an intermediate welding course. The materials were developed for a 36-week (3 hours daily) course designed to prepare the student for employment in the field of welding. Electric welding and specialized (TIG & MIG)…

Effects of plasma polymerized para-xylene intermediate layers on characteristics of flexible organic light emitting diodes fabricated on polyethylene terephthalate substrates

International Nuclear Information System (INIS)

Sohn, Sunyoung; Kim, Kyuhyung; Kho, Samil; Jung, Donggeun; Boo, Jin-hyo

2008-01-01

Characteristics of flexible organic light emitting diodes (FOLEDs) with the plasma polymerized para-xylene (PPpX) intermediate layer were investigated. For the purpose of reducing moisture permeation through plastic substrates, a PPpX intermediate layer was inserted between FOLEDs and the plastic substrates. As the concentration of C-H bonding in the PPpX film deposited at 25 deg. C was increased, PPpX films showed increased transmittance. Surface morphologies of polyethylene terephthalate (PET) covered with the PPpX intermediate layer were improved compared to PET without PPpX on it. Due to the highly cross-linked network structure in the plasma polymer film, water vapor permeability of PET substrates with the PPpX intermediate layer of 75 nm was decreased compared to PET substrates without PPpX on it. FOLEDs with the PPpX intermediate layer showed improved optical and electrical characteristics as well as lifetimes than FOLEDs without the PPpX intermediate layer

Money distribution with intermediation

OpenAIRE

Teles, Caio Augusto Colnago

2013-01-01

This pap er analyzes the distribution of money holdings in a commo dity money search-based mo del with intermediation. Intro ducing heterogeneity of costs to the Kiyotaki e Wright ( 1989 ) mo del, Cavalcanti e Puzzello ( 2010) gives rise to a non-degenerated distribution of money. We extend further this mo del intro ducing intermediation in the trading pro cess. We show that the distribution of money matters for savings decisions. This gives rises to a xed p oint problem for the ...

Search for intermediate vector bosons

International Nuclear Information System (INIS)

Klajn, D.B.; Rubbia, K.; Meer, S.

1983-01-01

Problem of registration and search for intermediate vector bosons is discussed. According to weak-current theory there are three intermediate vector bosons with +1(W + )-1(W - ) and zero (Z 0 ) electric charges. It was suggested to conduct the investigation into particles in 1976 by cline, Rubbia and Makintair using proton-antiproton beams. Major difficulties of the experiment are related to the necessity of formation of sufficient amount of antiparticles and the method of antiproton beam ''cooling'' for the purpose of reduction of its random movements. The stochastic method was suggested by van der Meer in 1968 as one of possible cooling methods. Several large detectors were designed for searching intermediate vector bosons

Validation of intermediate end points in cancer research.

Science.gov (United States)

Schatzkin, A; Freedman, L S; Schiffman, M H; Dawsey, S M

1990-11-21

Investigations using intermediate end points as cancer surrogates are quicker, smaller, and less expensive than studies that use malignancy as the end point. We present a strategy for determining whether a given biomarker is a valid intermediate end point between an exposure and incidence of cancer. Candidate intermediate end points may be selected from case series, ecologic studies, and animal experiments. Prospective cohort and sometimes case-control studies may be used to quantify the intermediate end point-cancer association. The most appropriate measure of this association is the attributable proportion. The intermediate end point is a valid cancer surrogate if the attributable proportion is close to 1.0, but not if it is close to 0. Usually, the attributable proportion is close to neither 1.0 nor 0; in this case, valid surrogacy requires that the intermediate end point mediate an established exposure-cancer relation. This would in turn imply that the exposure effect would vanish if adjusted for the intermediate end point. We discuss the relative advantages of intervention and observational studies for the validation of intermediate end points. This validation strategy also may be applied to intermediate end points for adverse reproductive outcomes and chronic diseases other than cancer.

Biocatalytic Synthesis of Chiral Pharmaceutical Intermediates

Directory of Open Access Journals (Sweden)

Ramesh N. Patel

2004-01-01

Full Text Available The production of single enantiomers of drug intermediates has become increasingly important in the pharmaceutical industry. Chiral intermediates and fine chemicals are in high demand from both the pharmaceutical and agrochemical industries for the preparation of bulk drug substances and agricultural products. The enormous potential of microorganisms and enzymes for the transformation of synthetic chemicals with high chemo-, regio- and enantioselectivities has been demonstrated. In this article, biocatalytic processes are described for the synthesis of chiral pharmaceutical intermediates.

Simplifying biochemical models with intermediate species

DEFF Research Database (Denmark)

Feliu, Elisenda; Wiuf, Carsten

2013-01-01

techniques, we study systematically the effects of intermediate, or transient, species in biochemical systems and provide a simple, yet rigorous mathematical classification of all models obtained from a core model by including intermediates. Main examples include enzymatic and post-translational modification...... systems, where intermediates often are considered insignificant and neglected in a model, or they are not included because we are unaware of their existence. All possible models obtained from the core model are classified into a finite number of classes. Each class is defined by a mathematically simple...... canonical model that characterizes crucial dynamical properties, such as mono- and multistationarity and stability of steady states, of all models in the class. We show that if the core model does not have conservation laws, then the introduction of intermediates does not change the steady...

Reactions of stabilized Criegee Intermediates

Science.gov (United States)

Vereecken, Luc; Harder, Hartwig; Novelli, Anna

2014-05-01

Carbonyl oxides (Criegee intermediates) were proposed as key intermediates in the gas phase ozonolysis of alkenes in 1975 by Rudolf Criegee. Despite the importance of ozonolysis in atmospheric chemistry, direct observation of these intermediates remained elusive, with only indirect experimental evidence for their role in the oxidation of hydrocarbons, e.g. through scavenging experiments. Direct experimental observation of stabilized CI has only been achieved since 2008. Since then, a concerted effort using experimental and theoretical means is in motion to characterize the chemistry and kinetics of these reactive intermediates. We present the results of theoretical investigations of the chemistry of Criegee intermediates with a series of coreactants which may be of importance in the atmosphere, in experimental setups, or both. This includes the CI+CI cross-reaction, which proceeds with a rate coefficient near the collision limit and can be important in experimental conditions. The CI + alkene reactions show strong dependence of the rate coefficient depending on the coreactants, but is generally found to be rather slow. The CI + ozone reaction is sufficiently fast to occur both in experiment and the free troposphere, and acts as a sink for CI. The reaction of CI with hydroperoxides, ROOH, is complex, and leads both to the formation of oligomers, as to the formation of reactive etheroxides, with a moderately fast rate coefficient. The importance of these reactions is placed in the context of the reaction conditions in different atmospheric environments ranging from unpolluted to highly polluted.

The intermediate endpoint effect in logistic and probit regression

Science.gov (United States)

MacKinnon, DP; Lockwood, CM; Brown, CH; Wang, W; Hoffman, JM

2010-01-01

Background An intermediate endpoint is hypothesized to be in the middle of the causal sequence relating an independent variable to a dependent variable. The intermediate variable is also called a surrogate or mediating variable and the corresponding effect is called the mediated, surrogate endpoint, or intermediate endpoint effect. Clinical studies are often designed to change an intermediate or surrogate endpoint and through this intermediate change influence the ultimate endpoint. In many intermediate endpoint clinical studies the dependent variable is binary, and logistic or probit regression is used. Purpose The purpose of this study is to describe a limitation of a widely used approach to assessing intermediate endpoint effects and to propose an alternative method, based on products of coefficients, that yields more accurate results. Methods The intermediate endpoint model for a binary outcome is described for a true binary outcome and for a dichotomization of a latent continuous outcome. Plots of true values and a simulation study are used to evaluate the different methods. Results Distorted estimates of the intermediate endpoint effect and incorrect conclusions can result from the application of widely used methods to assess the intermediate endpoint effect. The same problem occurs for the proportion of an effect explained by an intermediate endpoint, which has been suggested as a useful measure for identifying intermediate endpoints. A solution to this problem is given based on the relationship between latent variable modeling and logistic or probit regression. Limitations More complicated intermediate variable models are not addressed in the study, although the methods described in the article can be extended to these more complicated models. Conclusions Researchers are encouraged to use an intermediate endpoint method based on the product of regression coefficients. A common method based on difference in coefficient methods can lead to distorted

Impact assessment of intermediate soil cover on landfill stabilization by characterizing landfilled municipal solid waste.

Science.gov (United States)

Qi, Guangxia; Yue, Dongbei; Liu, Jianguo; Li, Rui; Shi, Xiaochong; He, Liang; Guo, Jingting; Miao, Haomei; Nie, Yongfeng

2013-10-15

Waste samples at different depths of a covered municipal solid waste (MSW) landfill in Beijing, China, were excavated and characterized to investigate the impact of intermediate soil cover on waste stabilization. A comparatively high amount of unstable organic matter with 83.3 g kg(-1) dry weight (dw) total organic carbon was detected in the 6-year-old MSW, where toxic inorganic elements containing As, Cd, Cr, Cu, Mn, Ni, Pb, and Zn of 10.1, 0.98, 85.49, 259.7, 530.4, 30.5, 84.0, and 981.7 mg kg(-1) dw, respectively, largely accumulated because of the barrier effect of intermediate soil cover. This accumulation resulted in decreased microbial activities. The intermediate soil cover also caused significant reduction in moisture in MSW under the soil layer, which was as low as 25.9%, and led to inefficient biodegradation of 8- and 10-year-old MSW. Therefore, intermediate soil cover with low permeability seems to act as a barrier that divides a landfill into two landfill cells with different degradation processes by restraining water flow and hazardous matter. Copyright © 2013 Elsevier Ltd. All rights reserved.

Gravity with Intermediate Goods Trade

Directory of Open Access Journals (Sweden)

Sujin Jang

2017-12-01

Full Text Available This paper derives the gravity equation with intermediate goods trade. We extend a standard monopolistic competition model to incorporate intermediate goods trade, and show that the gravity equation with intermediates trade is identical to the one without it except in that gross output should be used as the output measure instead of value added. We also show that the output elasticity of trade is significantly underestimated when value added is used as the output measure. This implies that with the conventional gravity equation, the contribution of output growth can be substantially underestimated and the role of trade costs reduction can be exaggerated in explaining trade expansion, as we demonstrate for the case of Korea's trade growth between 1995 and 2007.

Mobile communication and intermediality

DEFF Research Database (Denmark)

Helles, Rasmus

2013-01-01

communicative affordances of mobile devices in order to understand how people choose between them for different purposes. It is argued that mobile communication makes intermediality especially central, as the choice of medium is detached from the location of stationary media and begins to follow the user across......The article argues the importance of intermediality as a concept for research in mobile communication and media. The constant availability of several, partially overlapping channels for communication (texting, calls, email, Facebook, etc.) requires that we adopt an integrated view of the various...

Niobium phosphates as an intermediate temperature proton conducting electrolyte for fuel cells

DEFF Research Database (Denmark)

Huang, Yunjie; Li, Qingfeng; Jensen, Annemette Hindhede

2012-01-01

A new proton conductor based on niobium phosphates was synthesized using niobium pentoxide and phosphoric acid as precursors. The existence of hydroxyl groups in the phosphates was confirmed and found to be preserved after heat treatment at 500 °C or higher, contributing to an anhydrous proton co...... are of high interest as potential proton conducting electrolytes for fuel cells operational in an intermediate temperature range....... conductivity of 1.6 × 10−2 S cm−1 at 250 °C. The conductivity increased with water content in the atmosphere and reached 5.8 × 10−2 S cm−1 under pure water vapour at the same temperature. The conductivity showed good stability in the low water partial pressure range of up to 0.05 atm. The metal phosphates...

Mechanical behaviour of PWR fuel rods during intermediate storage

International Nuclear Information System (INIS)

Bouffioux, P.; Dalmas, R.; Bernaudat, C.

2000-01-01

EDF, which owns the irradiated fuel coming from its NPPs, has initiated studies regarding the mechanical behaviour of a fuel rod and the integrity of its cladding, in the case where the spent fuel is stored for a significant duration. During the phases following in-reactor irradiation (ageing in a water-pool, transport and intermediate storage), many phenomena, which are strongly coupled, may influence the cladding integrity: - residual power and temperature decay; - helium production and release in the free volume of the rod (especially for MOX fuel); - fuel column swelling; - cladding creep-out under the inner gas pressure of the fuel rod; - metallurgical changes due to high temperatures during transportation. In parallel, the quantification of the radiological risk is based on the definition of a cladding integrity criterion. Up to now, this criterion requires that the clad hoop strain due to creep-out does not exceed 1%. A more accurate criterion is being investigated. The study and modelling of all the phenomena mentioned above are included in a R and D programme. This programme also aims at redefining the cladding integrity criterion, which is assumed to be too conservative. The R and D programme will be presented. In order to predict the overall behaviour of the rod during the intermediate storage phases, the AVACYC code has been developed. It includes the models developed in the R and D programme. The input data of the AVACYC code are provided by the results of in-reactor rod behaviour simulations, using the thermal-mechanical CYRANO3 code. Its main results are the evolution vs. time of hoop stresses in the cladding, rod internal pressure and cladding hoop strains. Chained CYRANO-AVACYC calculations have been used to simulate the behaviour of MOX fuel rods irradiated up to 40 GWd/t and stored under air during 100 years, or under water during 50 years. For such fuels, where the residual power remains high, we show that a large part of the cladding strain

Progress on the national low level radioactive waste repository and national intermediate level waste store

International Nuclear Information System (INIS)

Perkins, C.

2001-01-01

Over the last few years, significant progress has been made towards siting national, purpose-built facilities for Australian radioactive waste. In 2001, after an eight year search, a preferred site and two alternatives were identified in central-north South Australia for a near-surface repository for Australian low level (low level and short-lived intermediate level) radioactive waste. Site 52a at Everts Field West on the Woomera Prohibited Area was selected as the preferred site as it performs best against the selection criteria, particularly with respect to geology, ground water, transport and security. Two alternative sites, Site 45a and Site 40a, east of the Woomera-Roxby Downs Road, were also found to be highly suitable for the siting of the national repository. A project has commenced to site a national store for intermediate (long-lived intermediate level) radioactive waste on Commonwealth land for waste produced by Commonwealth agencies. Public input has been sought on relevant selection criteria

Classical model of intermediate statistics

International Nuclear Information System (INIS)

Kaniadakis, G.

1994-01-01

In this work we present a classical kinetic model of intermediate statistics. In the case of Brownian particles we show that the Fermi-Dirac (FD) and Bose-Einstein (BE) distributions can be obtained, just as the Maxwell-Boltzmann (MD) distribution, as steady states of a classical kinetic equation that intrinsically takes into account an exclusion-inclusion principle. In our model the intermediate statistics are obtained as steady states of a system of coupled nonlinear kinetic equations, where the coupling constants are the transmutational potentials η κκ' . We show that, besides the FD-BE intermediate statistics extensively studied from the quantum point of view, we can also study the MB-FD and MB-BE ones. Moreover, our model allows us to treat the three-state mixing FD-MB-BE intermediate statistics. For boson and fermion mixing in a D-dimensional space, we obtain a family of FD-BE intermediate statistics by varying the transmutational potential η BF . This family contains, as a particular case when η BF =0, the quantum statistics recently proposed by L. Wu, Z. Wu, and J. Sun [Phys. Lett. A 170, 280 (1992)]. When we consider the two-dimensional FD-BE statistics, we derive an analytic expression of the fraction of fermions. When the temperature T→∞, the system is composed by an equal number of bosons and fermions, regardless of the value of η BF . On the contrary, when T=0, η BF becomes important and, according to its value, the system can be completely bosonic or fermionic, or composed both by bosons and fermions

Water masses in the Humboldt Current System: Properties, distribution, and the nitrate deficit as a chemical water mass tracer for Equatorial Subsurface Water off Chile

Science.gov (United States)

Silva, Nelson; Rojas, Nora; Fedele, Aldo

2009-07-01

Three sections are used to analyze the physical and chemical characteristics of the water masses in the eastern South Pacific and their distributions. Oceanographic data were taken from the SCORPIO (May-June 1967), PIQUERO (May-June 1969), and KRILL (June 1974) cruises. Vertical sections of temperature, salinity, σ θ, dissolved oxygen, nitrate, nitrite, phosphate, and silicate were used to analyze the water column structure. Five water masses were identified in the zone through T- S diagrams: Subantarctic Water, Subtropical Water, Equatorial Subsurface Water, Antarctic Intermediate Water, and Pacific Deep Water. Their proportions in the sea water mixture are calculated using the mixing triangle method. Vertical sections were used to describe the geographical distributions of the water mass cores in the upper 1500 m. Several characteristic oceanographic features in the study area were analyzed: the shallow salinity minimum displacement towards the equator, the equatorial subsurface salinity maximum associated with a dissolved oxygen minimum zone and a high nutrient content displacement towards the south, and the equatorward intermediate Antarctic salinity minimum associated with a dissolved oxygen maximum. The nitrate deficit generated in the denitrification area off Peru and northern Chile is proposed as a conservative chemical tracer for the Equatorial Subsurface Waters off the coast of Chile, south of 25°S.

Using Peephole Optimization on Intermediate Code

NARCIS (Netherlands)

Tanenbaum, A.S.; van Staveren, H.; Stevenson, J.W.

1982-01-01

Many portable compilers generate an intermediate code that is subsequently translated into the target machine's assembly language. In this paper a stack-machine-based intermediate code suitable for algebraic languages (e.g., PASCAL, C, FORTRAN) and most byte-addressed mini- and microcomputers is

Pair production of intermediate vector bosons

International Nuclear Information System (INIS)

Mikaelian, K.O.

1979-01-01

The production of intermediate vector boson pairs W + W - , Z 0 Z 0 , W +- Z 0 and W +- γ in pp and p anti p collisions is discussed. The motivation is to detect the self-interactions among the four intermediate vector bosons

Effects of intermediate wettability on entry capillary pressure in angular pores.

Science.gov (United States)

Rabbani, Harris Sajjad; Joekar-Niasar, Vahid; Shokri, Nima

2016-07-01

Entry capillary pressure is one of the most important factors controlling drainage and remobilization of the capillary-trapped phases as it is the limiting factor against the two-phase displacement. It is known that the entry capillary pressure is rate dependent such that the inertia forces would enhance entry of the non-wetting phase into the pores. More importantly the entry capillary pressure is wettability dependent. However, while the movement of a meniscus into a strongly water-wet pore is well-defined, the invasion of a meniscus into a weak or intermediate water-wet pore especially in the case of angular pores is ambiguous. In this study using OpenFOAM software, high-resolution direct two-phase flow simulations of movement of a meniscus in a single capillary channel are performed. Interface dynamics in angular pores under drainage conditions have been simulated under constant flow rate boundary condition at different wettability conditions. Our results shows that the relation between the half corner angle of pores and contact angle controls the temporal evolution of capillary pressure during the invasion of a pore. By deviating from pure water-wet conditions, a dip in the temporal evolution of capillary pressure can be observed which will be pronounced in irregular angular cross sections. That enhances the pore invasion with a smaller differential pressure. The interplay between the contact angle and pore geometry can have significant implications for enhanced remobilization of ganglia in intermediate contact angles in real porous media morphologies, where pores are very heterogeneous with small shape factors. Copyright © 2016 The Authors. Published by Elsevier Inc. All rights reserved.

Language in use intermediate : classroom book

CERN Document Server

Doff, Adrian

1995-01-01

ach of the four levels comprises about 80 hours of class work, with additional time for the self-study work. The Teacher's Book contains all the pages from the Classroom Book, with interleaved teaching notes including optional activities to cater for different abilities. There is a video to accompany the Beginner, Pre-intermediate and Intermediate levels. Each video contains eight stimulating and entertaining short programmes, as well as a booklet of photocopiable activities. Free test material is available in booklet and web format for Beginner and Pre-intermediate levels. Visit www.cambridge.org/elt/liu or contact your local Cambridge University Press representative.

Language in use intermediate : teacher's book

CERN Document Server

Doff, Adrian

1998-01-01

Each of the four levels comprises about 80 hours of class work, with additional time for the self-study work. The Teacher's Book contains all the pages from the Classroom Book, with interleaved teaching notes including optional activities to cater for different abilities. There is a video to accompany the Beginner, Pre-intermediate and Intermediate levels. Each video contains eight stimulating and entertaining short programmes, as well as a booklet of photocopiable activities. Free test material is available in booklet and web format for Beginner and Pre-intermediate levels. Visit www.cambridge.org/elt/liu or contact your local Cambridge University Press representative.

Interpretation and code generation based on intermediate languages

DEFF Research Database (Denmark)

Kornerup, Peter; Kristensen, Bent Bruun; Madsen, Ole Lehrmann

1980-01-01

The possibility of supporting high level languages through intermediate languages to be used for direct interpretation and as intermediate forms in compilers is investigated. An accomplished project in the construction of an interpreter and a code generator using one common intermediate form...

Mapping intermediate degradation products of poly(lactic-co-glycolic acid) in vitro.

Science.gov (United States)

Li, Jian; Nemes, Peter; Guo, Ji

2018-04-01

There is widespread interest in using absorbable polymers, such as poly(lactic-co-glycolic acid) (PLGA), as components in the design and manufacture of new-generation drug eluting stents (DES). PLGA undergoes hydrolysis to progressively degrade through intermediate chemical entities to simple organic acids that are ultimately absorbed by the human body. Understanding the composition and structure of these intermediate degradation products is critical not only to elucidate polymer degradation pathways accurately, but also to assess the safety and performance of absorbable cardiovascular implants. However, analytical approaches to determining the intermediate degradation products have yet to be established and evaluated in a standard or regulatory setting. Hence, we developed a methodology using electrospray ionization mass spectrometry to qualitatively and quantitatively describe intermediate degradation products generated in vitro from two PLGA formulations commonly used in DES. Furthermore, we assessed the temporal evolution of these degradation products using time-lapse experiments. Our data demonstrated that PLGA degradation products via heterogeneous cleavage of ester bonds are modulated by multiple intrinsic and environmental factors, including polymer chemical composition, degradants solubility in water, and polymer synthesis process. We anticipate the methodologies and outcomes presented in this work will elevate the mechanistic understanding of comprehensive degradation profiles of absorbable polymeric devices, and facilitate the design and regulation of cardiovascular implants by supporting the assessments of the associated biological response to degradation products. © 2017 Wiley Periodicals, Inc. J Biomed Mater Res Part B: Appl Biomater, 106B: 1129-1137, 2018. © 2017 Wiley Periodicals, Inc.

Search for intermediate vector bosons

International Nuclear Information System (INIS)

Cline, D.B.; Rubbia, C.; van der Meer, S.

1982-01-01

Over the past 15 years a new class of unified theories has been developed to describe the forces acting between elementary particles. The most successful of the new theories establishes a link between electromagnetism and the weak force. A crucial prediction of this unified electroweak theory is the existence of three massive particles called intermediate vector bosons. If these intermediate vector bosons exist and if they have properties attributed to them by electroweak theory, they should soon be detected, as the world's first particle accelerator with enough energy to create such particles has recently been completed at the European Organization for Nuclear Research (CERN) in Geneva. The accelerator has been converted to a colliding beam machine in which protons and antiprotons collide head on. According to electroweak theory, intermediate vector bosons can be created in proton-antiproton collisions. (SC)

The impact of intermediate wet states on two-phase flow in porous media, studied by network modelling

Energy Technology Data Exchange (ETDEWEB)

Hoeiland, Linda Kaada

2006-04-15

Reservoir wettability is a measure of a rocks preference for the oil and/or the brine phase. Wettability has a dominant impact on fluid movements in porous media, hence oil displacement in reservoir rocks. Understanding the local wettability and the effect of wettability on the fluid movements are therefore of interest in relation to oil recovery processes. Contrary to the earlier believed homogenous wetted cases where the porous media was strongly oil-wet for carbonate reservoirs or strongly water-wet for clastic reservoirs, it is now believed that most reservoir rocks experience some kind of intermediate wet state. Since wettability affects oil recovery, different classes of intermediate wettability are expected to have different impacts on the fluid flow processes. The major subject treated in this thesis is how different intermediate wet states affect fluid flow parameters which are important for the oil recovery. This is done by use of a capillary dominated network model of two-phase flow, where the network is based on a model of reconstructed sandstone. The existence of different intermediate wet classes is argued in Paper I, while Paper II, III and IV analyse the effect different intermediate wet classes have on wettability indices, residual oil saturation, capillary pressure and relative permeability (author)

The effect of UV-C stimulation of potato tubers and soaking of potato strips in water on density differences of intermediates for French-fry production

Directory of Open Access Journals (Sweden)

Sobol Zygmunt

2018-01-01

Full Text Available The paper describes the effect of UV-C stimulation of potato tubers and immersing of potato strips in water on differences in density of intermediate products for French-fry production. The density difference used for description of the experiment was defined as a relationship between the post-treatment density and pre-treatment density. The study was conducted on tubers of the Innovator variety. The studies of density changes induced by absorption of water involved measurements of the mass of potato strips in air and in water. Potato strips measured 10 × 10 mm and 60 mm in length. The strips were cut lengthwise along the longest tuber axis set between the proximal and distal tuber end. Water absorption was investigated by immersing strips in water (1 at a temperature of 20°C for 15 min and (2 at 40°C for 20 min. In addition, the study included the group (3 where strips were blanched at a temperature of 90°C for 2 min and a control group (0 which was not immersed in water. Potato tubers were irradiated by UV-C in the following ways: (1 irradiation on one side for 30 min, (2 irradiation on both sides for 15 min each, (0 control group (no irradiation. The studies were conducted at two dates: (0 after harvest and (1 after 3-month storage. Laboratory and storage experiments were conducted in 2016-2017. The density difference was statistically significantly influenced by storage time, UV-C stimulation and immersion conditions of potato strips. The density difference increased with the increase in storage duration of tubers, immersion duration of strips, water temperature (up to starch gelification temperature and UV-C stimulation.

39 CFR 3001.39 - Intermediate decisions.

Science.gov (United States)

2010-07-01

... 39 Postal Service 1 2010-07-01 2010-07-01 false Intermediate decisions. 3001.39 Section 3001.39 Postal Service POSTAL REGULATORY COMMISSION PERSONNEL RULES OF PRACTICE AND PROCEDURE Rules of General Applicability § 3001.39 Intermediate decisions. (a) Initial decision by presiding officer. In any proceedings in...

42 CFR 54.12 - Treatment of intermediate organizations.

Science.gov (United States)

2010-10-01

... 42 Public Health 1 2010-10-01 2010-10-01 false Treatment of intermediate organizations. 54.12... intermediate organizations. If a nongovernmental organization (referred to here as an “intermediate organization”), acting under a contract or other agreement with the Federal Government or a State or local...

Formation, structure, and stability of MHD intermediate shocks

International Nuclear Information System (INIS)

Wu, C.C.

1990-01-01

Contrary to the usual belief that MHD intermediate shocks are extraneous, the author has recently shown by numerical solutions of dissipative MHD equations that intermediate shocks are admissible and can be formed through nonlinear wave steepening from continuous waves. In this paper, the formation, structure and stability of intermediate shocks in dissipative MHD are considered in detail. The differences between the conventional theory and his are pointed out and clarified. He shows that all four types of intermediate shocks can be formed from smooth waves. He also shows that there are free parameters in the structure of the intermediate shocks, and that these parameters are related to the shock stability. In addition, he shows that a rotational discontinuity can not exist with finite width, indicate how this is related to the existence of time-dependent intermediate shocks, and show why the conventional theory is not a good approximation to dissipative MHD solutions whenever there is rotation in magnetic field

Partially folded intermediates during trypsinogen denaturation

Directory of Open Access Journals (Sweden)

Martins N.F.

1999-01-01

Full Text Available The equilibrium unfolding of bovine trypsinogen was studied by circular dichroism, differential spectra and size exclusion HPLC. The change in free energy of denaturation was = 6.99 ± 1.40 kcal/mol for guanidine hydrochloride and = 6.37 ± 0.57 kcal/mol for urea. Satisfactory fits of equilibrium unfolding transitions required a three-state model involving an intermediate in addition to the native and unfolded forms. Size exclusion HPLC allowed the detection of an intermediate population of trypsinogen whose Stokes radii varied from 24.1 ± 0.4 Å to 26.0 ± 0.3 Å for 1.5 M and 2.5 M guanidine hydrochloride, respectively. During urea denaturation, the range of Stokes radii varied from 23.9 ± 0.3 Å to 25.7 ± 0.6 Å for 4.0 M and 6.0 M urea, respectively. Maximal intrinsic fluorescence was observed at about 3.8 M urea with 8-aniline-1-naphthalene sulfonate (ANS binding. These experimental data indicate that the unfolding of bovine trypsinogen is not a simple transition and suggest that the equilibrium intermediate population comprises one intermediate that may be characterized as a molten globule. To obtain further insight by studying intermediates representing different stages of unfolding, we hope to gain a better understanding of the complex interrelations between protein conformation and energetics.

Bacterial intermediate filaments

DEFF Research Database (Denmark)

Charbon, Godefroid; Cabeen, M.; Jacobs-Wagner, C.

2009-01-01

Crescentin, which is the founding member of a rapidly growing family of bacterial cytoskeletal proteins, was previously proposed to resemble eukaryotic intermediate filament (IF) proteins based on structural prediction and in vitro polymerization properties. Here, we demonstrate that crescentin...

Diverse patterns of stored water use among saplings in seasonally dry tropical forests.

Science.gov (United States)

Wolfe, Brett T; Kursar, Thomas A

2015-12-01

Tree species in seasonally dry tropical forests likely vary in their drought-survival mechanisms. Drought-deciduousness, which reduces water loss, and low wood density, which may permit dependence on stored water, are considered key traits. For saplings of six species at two distinct sites, we studied these and two associated traits: the seasonal amount of water released per stem volume ("water released") and the hydraulic capacitance of the stem (C). Two deciduous species with low stem density, Cavanillesia platanifolia and Bursera simaruba, had high C and high dry-season stem water potential (Ψ(stem)), but differed in dry-season water released. C. platanifolia did not use stored water during the dry season whereas B. simaruba, in a drier forest, released stored water. In both, water released was highest while flushing leaves, suggesting that stored water supports leaf flushing. In contrast, two deciduous species with intermediate stem density, Annona hayesii and Genipa americana, had intermediate C, low dry-season Ψ(stem), and high seasonal change in water released. Meanwhile, two evergreen species with intermediate stem density, Cojoba rufescens and Astronium graveolens, had relatively low C, low dry-season Ψ(stem), and intermediate seasonal change in water released. Thus, at least three, distinct stored-water-use strategies were observed. Additionally, bark relative water content (RWC) decreased along with Ψ(stem) during the dry season while xylem RWC did not change, suggesting that bark-stored water buffers Ψ(stem) seasonally. Together these results suggest that seasonal use of stored water and change in Ψ(stem) are associated with functional groups that are characterized by combinations of deciduousness and stem density.

Low and intermediate radioactive waste management at OPG's western waste management facility

International Nuclear Information System (INIS)

Ellsworth, M.

2006-01-01

'Full text:' This paper will discuss low and intermediate level radioactive waste operations at Ontario Power Generation's Western Waste Management Facility. The facility has been in operation since 1974 and receives about 5000 - 7000 m 3 of low and intermediate level radioactive waste per year from Ontario's nuclear power plants. Low-level radioactive waste is received at the Waste Volume Reduction Building for possible volume reduction before it is placed into storage. Waste may be volume reduced by one of two methods at the WWMF, through either compaction or incineration. The Compactor is capable of reducing the volume of waste by a factor up to 5:1 for most waste. The Radioactive Incinerator is capable of volume reducing incinerable material by a factor up to 70:1. After processing, low-level waste is stored in above ground concrete warehouse-like structures called Low Level Storage Buildings. Low-level waste that cannot be volume reduced is placed into steel containers and stored in the Low Level Storage Buildings. Intermediate level waste is stored mainly in steel lined concrete storage structures. WWMF has both above ground and in-ground storage structures for intermediate level waste. Intermediate level waste consists primarily of resin and filters used to keep reactor water systems clean, and some used reactor core components. All low and intermediate level waste storage at the WWMF is considered interim storage and the material can be retrieved for future disposal or permanent storage. Current improvement initiatives include the installation of a new radioactive incinerator and a shredder/bagger. The new incinerator is a continuous feed system that is expected to achieve volume reduction rates up to 70:1, while incinerating higher volumes of waste than its predecessor. The shredder will break down large/bulky items into a form, which can be processed for further volume reduction. A Refurbishment Waste Storage Project is underway in anticipation of the

Present status of intermediate band solar cell research

International Nuclear Information System (INIS)

Cuadra, L.; Marti, A.; Luque, A.

2004-01-01

The intermediate band solar cell is a theoretical concept with the potential for exceeding the performance of conventional single-gap solar cells. This novel photovoltaic converter bases its superior theoretical efficiency over single-gap solar cells by enhancing its photogenerated current, via the two-step absorption of sub-band gap photons, without reducing its output voltage. This is achieved through a material with an electrically isolated and partially filled intermediate band located within a higher forbidden gap. This material is commonly named intermediate band material. This paper centres on summarising the present status of intermediate band solar cell research. A number of attempts, which aim to implement the intermediate band concept, are being followed: the direct engineering of the intermediate band material, its implementation by means of quantum dots and the highly porous material approach. Among other sub-band gap absorbing proposals, there is a renewed interest on the impurity photovoltaic effect, the quantum well solar cells and the particularly promising proposal for the use of up- and down-converters

Study of thermal-hydraulic characteristics in an LMFBR intermediate plenum

International Nuclear Information System (INIS)

Uotani, M.; Naohara, N.; Kinoshita, I.

1985-01-01

Experimental studies using water and liquid metal were conducted in order to investigate the thermal-hydraulic characteristics of an LMFBR intermediate plenum. The present study is an attempt to evaluate the effect of natural convection on the temperature field and to validate the prediction method of temperature profile in a thermally stratified cavity. The experimental results indicated that the effect of the natural convection on flow velocity and heat transfer in the cavity is reduced with increasing the modified stratification parameter. The calculation by FEM code and a simple 1-D model are effective to predict the temperature profile in the cavity

Photo-induced bleaching of sensory rhodopsin II (phoborhodopsin) from Halobacterium salinarum by hydroxylamine: identification of the responsible intermediates.

Science.gov (United States)

Tamogami, Jun; Kikukawa, Takashi; Ikeda, Yoichi; Demura, Makoto; Nara, Toshifumi; Kamo, Naoki

2012-01-05

Sensory rhodopsin II from Halobacterium salinarum (HsSRII) is a retinal protein in which retinal binds to a specific lysine residue through a Schiff base. Here, we investigated the photobleaching of HsSRII in the presence of hydroxylamine. For identification of intermediate(s) attacked by hydroxylamine, we employed the flash-induced bleaching method. In order to change the concentration of intermediates, such as M- and O-intermediates, experiments were performed under varying flashlight intensities and concentrations of azide that accelerated only the M-decay. We found the proportional relationship between the bleaching rate and area under the concentration-time curve of M, indicating a preferential attack of hydroxylamine on M. Since hydroxylamine is a water-soluble reagent, we hypothesize that for M, hydrophilicity or water-accessibility increases specifically in the moiety of Schiff base. Thus, hydroxylamine bleaching rates may be an indication of conformational changes near the Schiff base. We also considered the possibility that azide may induce a small conformational change around the Schiff base. We compared the hydroxylamine susceptibility between HsSRII and NpSRII (SRII from Natronomonas pharaonis) and found that the M of HsSRII is about three times more susceptible than that of the stable NpSRII. In addition, long illumination to HsSRII easily produced M-like photoproduct, P370. We thus infer that the instability of HsSRII under illumination may be related to this increase of hydrophilicity at M and P370. Copyright © 2011 Elsevier B.V. All rights reserved.

Experimental study on intermediate level radioactive waste processing

International Nuclear Information System (INIS)

Nagakura, Tadashi; Abe, Hirotoshi; Okazawa, Takao; Hattori, Seiichi; Maki, Yasuro

1977-01-01

In the disposal of intermediate level radioactive wastes, multilayer package will be adopted. The multilayer package consists of cement-solidified waste and a container such as a drum - can with concrete liner or a concrete container. So, on the waste to be cement-solidified in such container, experimental study was carried out as follows. (1) Cement-solidification method. (2) Mechanical behaviour of cement-solidified waste. The mechanical behaviour of the containers was studied by the finite element method and experiment, and the function of pressure-balancing valves was also studied. The following data on processing intermediate level radioactive wastes were obtained. (1) In the case of cement-solidified waste, the data to select the suitable solidifying material and the standard mixing proportion were determined. (2) The basic data concerning the uniaxial compressive strength of cement-solidified waste, the mechanical behaviour of cement-solidified waste packed in a drum under high hydrostatic pressure, the shock response of cement-solidified waste at the time of falling and so on were obtained. (3) The pressure-balancing valves worked at about 0.5 Kg/cm 2 pressure difference inside and outside a container, and the deformation of a drum cover was 10 to 13 mm. In case of the pressure difference less than 0,5 Kg/cm 2 , the valves shut, and water flow did occur. (auth.)

Characterisation of long-lived low and intermediate-level radioactive wastes in the Nordic Countries

International Nuclear Information System (INIS)

Broden, K.; Carugati, S.; Brodersen, K.; Carlsson, T.; Viitanen, P.; Walderhaug, T.; Sneve, M.; Hornkjoel, S.; Backe, S.

1997-11-01

The present report is final report from a study on characterisation of radioactive waters in the Nordic countries. The study has mainly been focused on long-lived low and intermediate level radioactive waste. Methods to measure or estimate the activity content and the general composition are discussed. Recommendations are given regarding characterisation of waste under treatment and characterisation of already produced waste packages. (au)

Characterisation of long-lived low and intermediate-level radioactive wastes in the Nordic Countries

Energy Technology Data Exchange (ETDEWEB)

Broden, K. [Studsvik RadWaste AB, (El Salvador); Carugati, S.; Brodersen, K. [Forskningscenter Risoe, (Denmark); Carlsson, T.; Viitanen, P. [VVT, (Finland); Walderhaug, T. [Icelandic Radiation Protection Institute (Iceland); Sneve, M.; Hornkjoel, S. [Norwegian Radiation Protection Authority (Norway); Backe, S. [Institute for Energy Technology (Norway)

1997-11-01

The present report is final report from a study on characterisation of radioactive waters in the Nordic countries. The study has mainly been focused on long-lived low and intermediate level radioactive waste. Methods to measure or estimate the activity content and the general composition are discussed. Recommendations are given regarding characterisation of waste under treatment and characterisation of already produced waste packages. (au).

Associations of Systemic Diseases with Intermediate Uveitis.

Science.gov (United States)

Shoughy, Samir S; Kozak, Igor; Tabbara, Khalid F

2016-01-01

To determine the associations of systemic diseases with intermediate uveitis. The medical records of 50 consecutive cases with intermediate uveitis referred to The Eye Center in Riyadh, Saudi Arabia, were reviewed. Age- and sex-matched patients without uveitis served as controls. Patients had complete ophthalmic and medical examinations. There were 27 male and 23 female patients. Mean age was 29 years with a range of 5-62 years. Overall, 21 cases (42%) had systemic disorders associated with intermediate uveitis and 29 cases (58%) had no associated systemic disease. A total of 11 patients (22%) had asthma, 4 (8%) had multiple sclerosis, 3 (6%) had presumed ocular tuberculosis, 1 (2%) had inflammatory bowel disease, 1 (2%) had non-Hodgkin lymphoma and 1 (2%) had sarcoidosis. Evidence of systemic disease was found in 50 (5%) of the 1,000 control subjects. Bronchial asthma was found in 37 patients (3.7 %), multiple sclerosis in 9 patients (0.9%), inflammatory bowel disease in 3 patients (0.3%), and tuberculosis in 1 patient (0.1%). None of the control patients had sarcoidosis or lymphoma. There were statistically significant associations between intermediate uveitis and bronchial asthma (p = 0.0001), multiple sclerosis (p = 0.003) and tuberculosis (p = 0.0005). Bronchial asthma and multiple sclerosis were the most frequently encountered systemic diseases associated with intermediate uveitis in our patient population. Patients with intermediate uveitis should undergo careful history-taking and investigations to rule out associated systemic illness.

Intermediate-Size Inducer Pump design report. [LMFBR

Energy Technology Data Exchange (ETDEWEB)

Boardman, T.J.

1979-06-15

This report summarizes the mechanical, structural, and hydrodynamic design of the Intermediate-Size Inducer Pump (ISIP). The design was performed under Atomics International's DOE Base Technology Program by the Atomics International and Rocketdyne Divisions of Rockwell International. The pump was designed to utilize the FFTF prototype pump frame as a test vehicle to test the inducer, impeller, and diffuser plus necessary adapter hardware under simulated Large Scale Liquid Metal Fast Breeder Reactor service conditions. The report describes the design requirements including the purpose and objectives, and discusses those design efforts and considerations made to meet the requirements. Included in the report are appendices showing calculative methods and results. Also included are overall assembly and layout drawings plus some details used as illustrations for discussion of the design results and the results of water tests performed on a model of the inducer.

Intermediate Leg SBLOCA - Long Lasting Pressure Transient

International Nuclear Information System (INIS)

Konjarek, D.; Bajs, T.; Vukovic, J.

2010-01-01

The basic phenomenology of Small Break Loss of Coolant Accident (SBLOCA) for PWR plant is described with focus on analysis of scenario in which reactor coolant pressure decreases below secondary system pressure. Best estimate light water reactor transient analysis code RELAP5/mod3.3 was used in calculation. Rather detailed model of the plant was used. The break occurs in intermediate leg on lowest elevation near pump suction. The size of the break is chosen to be small enough to cause cycling of safety valves (SVs) on steam generators (SGs) for some time, but, afterwards, it is large enough to remove decay heat through the break, causing cooling the secondary side. In this case of SBLOCA, when primary pressure decreases below secondary pressure, long lasting pressure transients with significant amplitude occur. Reasons for such behavior are explained.(author).

Characterization of intermediate products of solar photocatalytic degradation of ranitidine at pilot-scale.

Science.gov (United States)

Radjenović, Jelena; Sirtori, Carla; Petrović, Mira; Barceló, Damià; Malato, Sixto

2010-04-01

In the present study the mechanisms of solar photodegradation of H(2)-receptor antagonist ranitidine (RNTD) were studied in a well-defined system of a pilot plant scale Compound Parabolic Collector (CPC) reactor. Two types of heterogeneous photocatalytic experiments were performed: catalysed by titanium-dioxide (TiO(2)) semiconductor and by Fenton reagent (Fe(2+)/H(2)O(2)), each one with distilled water and synthetic wastewater effluent matrix. Complete disappearance of the parent compounds and discreet mineralization were attained in all experiments. Furthermore, kinetic parameters, main intermediate products, release of heteroatoms and formation of carboxylic acids are discussed. The main intermediate products of photocatalytic degradation of RNTD have been structurally elucidated by tandem mass spectrometry (MS(2)) experiments performed at quadrupole-time of flight (QqToF) mass analyzer coupled to ultra-performance liquid chromatograph (UPLC). RNTD displayed high reactivity towards OH radicals, although a product of conduction band electrons reduction was also present in the experiment with TiO(2). In the absence of standards, quantification of intermediates was not possible and only qualitative profiles of their evolution could be determined. The proposed TiO(2) and photo-Fenton degradation routes of RNTD are reported for the first time. (c) 2010 Elsevier Ltd. All rights reserved.

A degradation approach to accelerate simulations to steady-state in a 3-D tracer transport model of the global ocean

Energy Technology Data Exchange (ETDEWEB)

Aumont, O.; Orr, J.C.; Marti, O. [CEA Saclay, Gif-sur-Yvette (France). Lab. de Modelisation du Climat et de l`Environnement; Jamous, D.; Monfray, P. [Centre des Faibles Radioactivites, Laboratoire mixte CNRS-CEA, L`Orme des Merisiers, Bt. 709/LMCE, CE Saclay, F-91191 Gif sur Yvette Cedex (France); Madec, G. [Laboratoire d`Oceanographie Dynamique et de Climatologie, (CNRS/ORSTOM/UPMC) Universite Paris VI, 4 place Jussieu, Paris (France)

1998-02-01

We have developed a new method to accelerate tracer simulations to steady-state in a 3D global ocean model, run off-line. Using this technique, our simulations for natural {sup 14}C ran 17 times faster when compared to those made with the standard nonaccelerated approach. For maximum acceleration we wish to initialize the model with tracer fields that are as close as possible to the final equilibrium solution. Our initial tracer fields were derived by judiciously constructing a much faster, lower-resolution (degraded), off-line model from advective and turbulent fields predicted from the parent on-line model, an ocean general circulation model (OGCM). No on-line version of the degraded model exists; it is based entirely on results from the parent OGCM. Degradation was made horizontally over sets of four adjacent grid-cell squares for each vertical layer of the parent model. However, final resolution did not suffer because as a second step, after allowing the degraded model to reach equilibrium, we used its tracer output to reinitialize the parent model (at the original resolution). After reinitialization, the parent model must then be integrated only to a few hundred years before reaching equilibrium. To validate our degradation-integration technique (DEGINT), we compared {sup 14}C results from runs with and without this approach. Differences are less than 10 permille throughout 98.5% of the ocean volume. Predicted natural {sup 14}C appears reasonable over most of the ocean. In the Atlantic, modeled {Delta}{sup 14}C indicates that as observed, the North Atlantic Deep Water (NADW) fills the deep North Atlantic, and Antartic Intermediate Water (AAIW) infiltrates northward. (orig.) With 12 figs., 1 tab., 42 refs.

The influence of organic materials on the near field of an intermediate level radioactive waste repository

International Nuclear Information System (INIS)

Wilkins, J.D.

1988-01-01

The influence of organic materials which are present in some intermediate level wastes on the chemistry of the near field of a radioactive waste repository is discussed. Particular attention is given to the possible formation of water soluble complexing agents as a result of the radiation field and chemical conditions. The present state of the research is reviewed. (author)

Isoporphyrin Intermediate in Heme Oxygenase Catalysis

Science.gov (United States)

Evans, John P.; Niemevz, Fernando; Buldain, Graciela; de Montellano, Paul Ortiz

2008-01-01

Human heme oxygenase-1 (hHO-1) catalyzes the O2- and NADPH-dependent oxidation of heme to biliverdin, CO, and free iron. The first step involves regiospecific insertion of an oxygen atom at the α-meso carbon by a ferric hydroperoxide and is predicted to proceed via an isoporphyrin π-cation intermediate. Here we report spectroscopic detection of a transient intermediate during oxidation by hHO-1 of α-meso-phenylheme-IX, α-meso-(p-methylphenyl)-mesoheme-III, and α-meso-(p-trifluoromethylphenyl)-mesoheme-III. In agreement with previous experiments (Wang, J., Niemevz, F., Lad, L., Huang, L., Alvarez, D. E., Buldain, G., Poulos, T. L., and Ortiz de Montellano, P. R. (2004) J. Biol. Chem. 279, 42593–42604), only the α-biliverdin isomer is produced with concomitant formation of the corresponding benzoic acid. The transient intermediate observed in the NADPH-P450 reductase-catalyzed reaction accumulated when the reaction was supported by H2O2 and exhibited the absorption maxima at 435 and 930 nm characteristic of an isoporphyrin. Product analysis by reversed phase high performance liquid chromatography and liquid chromatography electrospray ionization mass spectrometry of the product generated with H2O2 identified it as an isoporphyrin that, on quenching, decayed to benzoylbiliverdin. In the presence of H218O2, one labeled oxygen atom was incorporated into these products. The hHO-1-isoporphyrin complexes were found to have half-lives of 1.7 and 2.4 h for the p-trifluoromethyl- and p-methyl-substituted phenylhemes, respectively. The addition of NADPH-P450 reductase to the H2O2-generated hHO-1-isoporphyrin complex produced α-biliverdin, confirming its role as a reaction intermediate. Identification of an isoporphyrin intermediate in the catalytic sequence of hHO-1, the first such intermediate observed in hemoprotein catalysis, completes our understanding of the critical first step of heme oxidation. PMID:18487208

Intermediate obtained from photoionization, serving as precursor for the synthesis of Schiff’s base

Directory of Open Access Journals (Sweden)

R. Sanjeev

2014-05-01

Full Text Available In this article, we have introduced an intermediate benzyl carbocation (formed as a result of photoionization which serves as precursor for the synthesis of Schiff’s base. Lifetimes of many carbocations were determined from our laboratory. During the determination of the lifetimes, our endeavor was to obtain a carbocation with high selectivity, s = knu/kH2O. The selectivity is the ratio of the rate constant of the reaction of carbocation with an externally added nucleophile, (nu, aniline to that of the rate constant of the water. Our intention was to obtain a carbocation with high selectivity, so that one can pave a path for the synthesis of Schiff’s base by the reaction of the carbocation intermediate with aniline. DOI: http://dx.doi.org/10.4314/bcse.v28i2.13

Language in use intermediate : self-study workbook

CERN Document Server

Doff, Adrian

1994-01-01

Each of the four levels comprises about 80 hours of class work, with additional time for the self-study work. The Teacher's Book contains all the pages from the Classroom Book, with interleaved teaching notes including optional activities to cater for different abilities. There is a video to accompany the Beginner, Pre-intermediate and Intermediate levels. Each video contains eight stimulating and entertaining short programmes, as well as a booklet of photocopiable activities. Free test material is available in booklet and web format for Beginner and Pre-intermediate levels. Visit www.cambridge.org/elt/liu or contact your local Cambridge University Press representative.

an intermediate moisture meat

African Journals Online (AJOL)

STORAGESEVER

2008-07-04

Jul 4, 2008 ... traditional SM muscle without compromising quality. ... technique is intermediate moisture food processing. ... Traditionally, most tsire suya producers use ..... quality of Chinese purebred and European X Chinese crossbred ...

Increasing water use efficiency along the C3 to C4 evolutionary pathway: a stomatal optimization perspective.

Science.gov (United States)

Way, Danielle A; Katul, Gabriel G; Manzoni, Stefano; Vico, Giulia

2014-07-01

C4 photosynthesis evolved independently numerous times, probably in response to declining atmospheric CO2 concentrations, but also to high temperatures and aridity, which enhance water losses through transpiration. Here, the environmental factors controlling stomatal behaviour of leaf-level carbon and water exchange were examined across the evolutionary continuum from C3 to C4 photosynthesis at current (400 μmol mol(-1)) and low (280 μmol mol(-1)) atmospheric CO2 conditions. To this aim, a stomatal optimization model was further developed to describe the evolutionary continuum from C3 to C4 species within a unified framework. Data on C3, three categories of C3-C4 intermediates, and C4 Flaveria species were used to parameterize the stomatal model, including parameters for the marginal water use efficiency and the efficiency of the CO2-concentrating mechanism (or C4 pump); these two parameters are interpreted as traits reflecting the stomatal and photosynthetic adjustments during the C3 to C4 transformation. Neither the marginal water use efficiency nor the C4 pump strength changed significantly from C3 to early C3-C4 intermediate stages, but both traits significantly increased between early C3-C4 intermediates and the C4-like intermediates with an operational C4 cycle. At low CO2, net photosynthetic rates showed continuous increases from a C3 state, across the intermediates and towards C4 photosynthesis, but only C4-like intermediates and C4 species (with an operational C4 cycle) had higher water use efficiencies than C3 Flaveria. The results demonstrate that both the marginal water use efficiency and the C4 pump strength increase in C4 Flaveria to improve their photosynthesis and water use efficiency compared with C3 species. These findings emphasize that the advantage of the early intermediate stages is predominantly carbon based, not water related. © The Author 2014. Published by Oxford University Press on behalf of the Society for Experimental Biology.

Taxation of Financial Intermediation Activities in Hong Kong

OpenAIRE

Jack M. Mintz; Stephen R. Richardson

2001-01-01

This paper discusses issues related to the taxation of financial intermediation in Hong Kong in the context of Hong Kong's position as a major regional financial centre. It first provides some background analysis as to the definition of financial intermediation and identification of the providers of financial services. This is then followed by a discussion of the principles of taxation applicable to financial intermediation, including a comparison of income taxes to consumption taxes. Some sp...

199 bacteriological quality of water used for ice making in some

African Journals Online (AJOL)

DR. AMINU

2010-06-01

Jun 1, 2010 ... from water related diseases like typhoid and para typhoid fevers, cholera bacillary dysentery and gastroenteritis. Water borne or related pathogens including bacteria are spread in water either through human ingestion of contaminated water or because water provides the habitat for intermediate host.

Collaborative Project. Mode and Intermediate Waters in Earth System Models

Energy Technology Data Exchange (ETDEWEB)

Sarmiento, Jorge L. [Princeton Univ., NJ (United States); Dufour, Carolina [Princeton Univ., NJ (United States); Rodgers, Keith B. [Princeton Univ., NJ (United States)

2015-12-16

The focus of this grant was on diagnosing the physical mechanisms controlling upper ocean water mass formation and carbon distribution in Earth System Models (ESMs), with the goal of improving the physics that controls their formation.

CFD modelling of axial mixing in the intermediate and final rinses of cleaning-in-place procedures of straight pipes

DEFF Research Database (Denmark)

Yang, Jifeng; Jensen, Bo Boye Busk; Nordkvist, Mikkel

2018-01-01

The intermediate and final rinses of straight pipes, in which water replaces a cleaning agent of similar density and viscosity, are modelled using Computational Fluid Dynamic (CFD) methods. It is anticipated that the displacement process is achieved by convective and diffusive transport. The simu...

Intermediate-energy nuclear chemistry workshop

International Nuclear Information System (INIS)

Butler, G.W.; Giesler, G.C.; Liu, L.C.; Dropesky, B.J.; Knight, J.D.; Lucero, F.; Orth, C.J.

1981-05-01

This report contains the proceedings of the LAMPF Intermediate-Energy Nuclear Chemistry Workshop held in Los Alamos, New Mexico, June 23-27, 1980. The first two days of the Workshop were devoted to invited review talks highlighting current experimental and theoretical research activities in intermediate-energy nuclear chemistry and physics. Working panels representing major topic areas carried out indepth appraisals of present research and formulated recommendations for future research directions. The major topic areas were Pion-Nucleus Reactions, Nucleon-Nucleus Reactions and Nuclei Far from Stability, Mesonic Atoms, Exotic Interactions, New Theoretical Approaches, and New Experimental Techniques and New Nuclear Chemistry Facilities

Intermediate-energy nuclear chemistry workshop

Energy Technology Data Exchange (ETDEWEB)

Butler, G.W.; Giesler, G.C.; Liu, L.C.; Dropesky, B.J.; Knight, J.D.; Lucero, F.; Orth, C.J.

1981-05-01

This report contains the proceedings of the LAMPF Intermediate-Energy Nuclear Chemistry Workshop held in Los Alamos, New Mexico, June 23-27, 1980. The first two days of the Workshop were devoted to invited review talks highlighting current experimental and theoretical research activities in intermediate-energy nuclear chemistry and physics. Working panels representing major topic areas carried out indepth appraisals of present research and formulated recommendations for future research directions. The major topic areas were Pion-Nucleus Reactions, Nucleon-Nucleus Reactions and Nuclei Far from Stability, Mesonic Atoms, Exotic Interactions, New Theoretical Approaches, and New Experimental Techniques and New Nuclear Chemistry Facilities.

The ARES High-level Intermediate Representation

Energy Technology Data Exchange (ETDEWEB)

Moss, Nicholas David [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

2017-03-03

The LLVM intermediate representation (IR) lacks semantic constructs for depicting common high-performance operations such as parallel and concurrent execution, communication and synchronization. Currently, representing such semantics in LLVM requires either extending the intermediate form (a signi cant undertaking) or the use of ad hoc indirect means such as encoding them as intrinsics and/or the use of metadata constructs. In this paper we discuss a work in progress to explore the design and implementation of a new compilation stage and associated high-level intermediate form that is placed between the abstract syntax tree and when it is lowered to LLVM's IR. This highlevel representation is a superset of LLVM IR and supports the direct representation of these common parallel computing constructs along with the infrastructure for supporting analysis and transformation passes on this representation.

Surface-Bound Intermediates in Low-Temperature Methanol Synthesis on Copper. Participants and Spectators

Energy Technology Data Exchange (ETDEWEB)

Yang, Yong; Mei, Donghai; Peden, Charles HF; Campbell, Charles T.; Mims, Charles A.

2015-11-03

The reactivity of surface adsorbed species present on copper catalysts during methanol synthesis at low temperatures was studied by simultaneous infrared spectroscopy (IR) and mass spectroscopy (MS) measurements during “titration” (transient surface reaction) experiments with isotopic tracing. The results show that adsorbed formate is a major bystander species present on the surface under steady-state methanol synthesis reaction conditions, but it cannot be converted to methanol by reaction with pure H₂, nor with H₂ plus added water. Formate-containing surface adlayers for these experiments were produced during steady state catalysis in (a) H₂:CO₂ (with substantial formate coverage) and (b) moist H₂:CO (with no IR visible formate species). Both these reaction conditions produce methanol at steady state with relatively high rates. Adlayers containing formate were also produced by (c) formic acid adsorption. Various "titration" gases were used to probe these adlayers at modest temperatures (T = 410-450K) and 6 bar total pressure. Methanol gas (up to ~1% monolayer equivalent) was produced in "titration" from the H₂:CO₂ catalytic adlayers by H₂ plus water, but not by dry hydrogen. The decay in the formate IR features accelerated in the presence of added water vapor. The H₂:CO:H₂O catalytic adlayer produced similar methanol titration yields in H₂ plus water but showed no surface formate features in IR (less than 0.2% monolayer coverage). Finally, formate from formic acid chemisorption produced no methanol under any titration conditions. Even under (H₂:CO₂) catalytic reaction conditions, isotope tracing showed that pre-adsorbed formate from formic acid did not contribute to the methanol produced. Although non-formate intermediates exist during low temperature methanol synthesis on copper which can be converted to methanol gas

Gasoline Engine Mechanics. Performance Objectives. Intermediate Course.

Science.gov (United States)

Jones, Marion

Several intermediate performance objectives and corresponding criterion measures are listed for each of six terminal objectives presented in this curriculum guide for an intermediate gasoline engine mechanics course at the secondary level. (For the beginning course guide see CE 010 947.) The materials were developed for a two-semester (2 hour…

Features of Red Sea Water Masses

Science.gov (United States)

Kartadikaria, Aditya; Hoteit, Ibrahim

2015-04-01

Features of Red Sea water mass can be divided into three types but best to be grouped into two different classes that are split at the potential density line σθ=27.4. The surface water (0-50 m) and the intermediate water (50-200 m) have nearly identical types of water mass. They appear as a maxima salinity layer for the water mass that has σθ > 26.0, and as a minimum salinity layer for water mass that has σθ water masses are strongly affected by mixing that is controlled by seasonal variability, fresh water intrusion of the Gulf of Aden Intermediate Water (GAIW), and eddies variability. Two types of mixing; isopycnal and diapycnal mixing are part of important physical phenomena that explain the change of water mass in the Red Sea. The isopycnal mixing occurs at the neutral potential density line, connecting the Red Sea with its adjacent channel, the Gulf of Aden. Diapycnal mixing is found as a dominant mixing mode in the surface of the Red Sea Water and mainly due to energetic eddy activity. Density gradients, across which diapycnal mixing occurs, in the Red Sea are mainly due to large variations in salinity. The isolation of an extreme haline water mass below the thermocline contributes to the generation of the latitudinal shift and low diapycnal mixing. This finding further explains the difference of spatial kinetic mixing between the RSW and the Indian Ocean basin.

Features of Red Sea Water Masses

KAUST Repository

Kartadikaria, Aditya R.

2015-04-01

Features of Red Sea water mass can be divided into three types but best to be grouped into two different classes that are split at the potential density line σθ=27.4. The surface water (0-50 m) and the intermediate water (50-200 m) have nearly identical types of water mass. They appear as a maxima salinity layer for the water mass that has σθ > 26.0, and as a minimum salinity layer for water mass that has σθ < 26.0. These types of water masses are strongly affected by mixing that is controlled by seasonal variability, fresh water intrusion of the Gulf of Aden Intermediate Water (GAIW), and eddies variability. Two types of mixing; isopycnal and diapycnal mixing are part of important physical phenomena that explain the change of water mass in the Red Sea. The isopycnal mixing occurs at the neutral potential density line, connecting the Red Sea with its adjacent channel, the Gulf of Aden. Diapycnal mixing is found as a dominant mixing mode in the surface of the Red Sea Water and mainly due to energetic eddy activity. Density gradients, across which diapycnal mixing occurs, in the Red Sea are mainly due to large variations in salinity. The isolation of an extreme haline water mass below the thermocline contributes to the generation of the latitudinal shift and low diapycnal mixing. This finding further explains the difference of spatial kinetic mixing between the RSW and the Indian Ocean basin.

Mapping Intermediality in Performance

NARCIS (Netherlands)

2010-01-01

Mapping Intermediality in Performance benadert het vraagstuk van intermedialiteit met betrekking tot performance (vooral theater) vanuit vijf verschillende invalshoeken: performativiteit en lichaam; tijd en ruimte; digitale cultuur en posthumanisme; netwerken; pedagogiek en praxis. In deze boeiende

Nickel and its alloys as perspective materials for intermediate temperature steam electrolysers operating on proton conducting solid acids as electrolyte

DEFF Research Database (Denmark)

Nikiforov, Aleksey; Petrushina, Irina; Jensen, Jens Oluf

2012-01-01

Several stainless steels, nickel-based alloys, Ta-coated stainless steel, niobium, nickel, platinum and gold were evaluated as possible materials for use in the intermediate temperature water electrolysers. The corrosion resistance was measured in molten KH2PO4 as simulated conditions corresponding...

Pectin Methyl Esterase Activity Change in Intermediate Moisture Sun-Dried Figs after Storage

Directory of Open Access Journals (Sweden)

Dilek Demirbüker Kavak

2015-12-01

Full Text Available Intermediate moisture fruits can be obtained by rehydrating dried fruits. Intermediate moisture fruits are suitable for direct consumption compared to dry fruits and can be directly used in the production of various products such as bakery products, dairy products and candies. Aim of this study is to compare the pectin methyl esterase (PME activity of intermediate moisture figs which causes softening of the texture and to compare their microbial stability after 3 months storage period. For this purpose, dried figs were rehydrated in 30 and 80° C water until they reach 30% moisture content. Rehydrated samples were stored for 3 months at +4°C. Results showed that there was no statistically significant difference between the control samples and the samples rehydrated at 80°C according to the total viable counts. At the end of the storage period, results of residual PME activity in control samples was 24.1 μmol COOH min-1g-1, while it was found 17.4 μmol COOH min-1g-1 in samples rehydrated at 80°C. As a result rehydration conducted at 80°C provided 28% reduction in PME activity compared to the control samples rehydrated at 30°C, although it did not affect the microbial load significantly after storage.

Passive Avoidance Training and Recall are Associated With Increased Glutamate Levels in the Intermediate Medial Hyperstriatum Ventrale of the Day-Old Chick

Directory of Open Access Journals (Sweden)

Jonathan N. Daisley

1998-01-01

glutamate levels in the intermediate medial hyperstriatum ventrale accompany pecking at either the water- or the methylanthranylate-bead. The taste of the aversant may be responsible for the greater increases found in methylanthranylate-trained birds.

The Intermediate Neutrino Program

CERN Document Server

Adams, C.; Ankowski, A.M.; Asaadi, J.A.; Ashenfelter, J.; Axani, S.N.; Babu, K.; Backhouse, C.; Band, H.R.; Barbeau, P.S.; Barros, N.; Bernstein, A.; Betancourt, M.; Bishai, M.; Blucher, E.; Bouffard, J.; Bowden, N.; Brice, S.; Bryan, C.; Camilleri, L.; Cao, J.; Carlson, J.; Carr, R.E.; Chatterjee, A.; Chen, M.; Chen, S.; Chiu, M.; Church, E.D.; Collar, J.I.; Collin, G.; Conrad, J.M.; Convery, M.R.; Cooper, R.L.; Cowen, D.; Davoudiasl, H.; de Gouvea, A.; Dean, D.J.; Deichert, G.; Descamps, F.; DeYoung, T.; Diwan, M.V.; Djurcic, Z.; Dolinski, M.J.; Dolph, J.; Donnelly, B.; Dwyer, D.A.; Dytman, S.; Efremenko, Y.; Everett, L.L.; Fava, A.; Figueroa-Feliciano, E.; Fleming, B.; Friedland, A.; Fujikawa, B.K.; Gaisser, T.K.; Galeazzi, M.; Galehouse, D.C.; Galindo-Uribarri, A.; Garvey, G.T.; Gautam, S.; Gilje, K.E.; Gonzalez-Garcia, M.; Goodman, M.C.; Gordon, H.; Gramellini, E.; Green, M.P.; Guglielmi, A.; Hackenburg, R.W.; Hackenburg, A.; Halzen, F.; Han, K.; Hans, S.; Harris, D.; Heeger, K.M.; Herman, M.; Hill, R.; Holin, A.; Huber, P.; Jaffe, D.E.; Johnson, R.A.; Joshi, J.; Karagiorgi, G.; Kaufman, L.J.; Kayser, B.; Kettell, S.H.; Kirby, B.J.; Klein, J.R.; Kolomensky, Yu. G.; Kriske, R.M.; Lane, C.E.; Langford, T.J.; Lankford, A.; Lau, K.; Learned, J.G.; Ling, J.; Link, J.M.; Lissauer, D.; Littenberg, L.; Littlejohn, B.R.; Lockwitz, S.; Lokajicek, M.; Louis, W.C.; Luk, K.; Lykken, J.; Marciano, W.J.; Maricic, J.; Markoff, D.M.; Martinez Caicedo, D.A.; Mauger, C.; Mavrokoridis, K.; McCluskey, E.; McKeen, D.; McKeown, R.; Mills, G.; Mocioiu, I.; Monreal, B.; Mooney, M.R.; Morfin, J.G.; Mumm, P.; Napolitano, J.; Neilson, R.; Nelson, J.K.; Nessi, M.; Norcini, D.; Nova, F.; Nygren, D.R.; Orebi Gann, G.D.; Palamara, O.; Parsa, Z.; Patterson, R.; Paul, P.; Pocar, A.; Qian, X.; Raaf, J.L.; Rameika, R.; Ranucci, G.; Ray, H.; Reyna, D.; Rich, G.C.; Rodrigues, P.; Romero, E.Romero; Rosero, R.; Rountree, S.D.; Rybolt, B.; Sanchez, M.C.; Santucci, G.; Schmitz, D.; Scholberg, K.; Seckel, D.; Shaevitz, M.; Shrock, R.; Smy, M.B.; Soderberg, M.; Sonzogni, A.; Sousa, A.B.; Spitz, J.; St. John, J.M.; Stewart, J.; Strait, J.B.; Sullivan, G.; Svoboda, R.; Szelc, A.M.; Tayloe, R.; Thomson, M.A.; Toups, M.; Vacheret, A.; Vagins, M.; Van de Water, R.G.; Vogelaar, R.B.; Weber, M.; Weng, W.; Wetstein, M.; White, C.; White, B.R.; Whitehead, L.; Whittington, D.W.; Wilking, M.J.; Wilson, R.J.; Wilson, P.; Winklehner, D.; Winn, D.R.; Worcester, E.; Yang, L.; Yeh, M.; Yokley, Z.W.; Yoo, J.; Yu, B.; Yu, J.; Zhang, C.

2015-01-01

The US neutrino community gathered at the Workshop on the Intermediate Neutrino Program (WINP) at Brookhaven National Laboratory February 4-6, 2015 to explore opportunities in neutrino physics over the next five to ten years. Scientists from particle, astroparticle and nuclear physics participated in the workshop. The workshop examined promising opportunities for neutrino physics in the intermediate term, including possible new small to mid-scale experiments, US contributions to large experiments, upgrades to existing experiments, R&D plans and theory. The workshop was organized into two sets of parallel working group sessions, divided by physics topics and technology. Physics working groups covered topics on Sterile Neutrinos, Neutrino Mixing, Neutrino Interactions, Neutrino Properties and Astrophysical Neutrinos. Technology sessions were organized into Theory, Short-Baseline Accelerator Neutrinos, Reactor Neutrinos, Detector R&D and Source, Cyclotron and Meson Decay at Rest sessions.This report summ...

Stable isotope fractionation during bacterial sulfate reduction is controlled by reoxidation of intermediates

Science.gov (United States)

Mangalo, Muna; Meckenstock, Rainer U.; Stichler, Willibald; Einsiedl, Florian

2007-09-01

Bacterial sulfate reduction is one of the most important respiration processes in anoxic habitats and is often assessed by analyzing the results of stable isotope fractionation. However, stable isotope fractionation is supposed to be influenced by the reduction rate and other parameters, such as temperature. We studied here the mechanistic basics of observed differences in stable isotope fractionation during bacterial sulfate reduction. Batch experiments with four sulfate-reducing strains ( Desulfovibrio desulfuricans, Desulfobacca acetoxidans, Desulfonatronovibrio hydrogenovorans, and strain TRM1) were performed. These microorganisms metabolize different carbon sources (lactate, acetate, formate, and toluene) and showed broad variations in their sulfur isotope enrichment factors. We performed a series of experiments on isotope exchange of 18O between residual sulfate and ambient water. Batch experiments were conducted with 18O-enriched (δ 18O water = +700‰) and depleted water (δ 18O water = -40‰), respectively, and the stable 18O isotope shift in the residual sulfate was followed. For Desulfovibrio desulfuricans and Desulfonatronovibrio hydrogenovorans, which are both characterized by low sulfur isotope fractionation ( ɛS > -13.2‰), δ 18O values in the remaining sulfate increased by only 50‰ during growth when 18O-enriched water was used for the growth medium. In contrast, with Desulfobacca acetoxidans and strain TRM1 ( ɛS factor ( ɛS exchange with water during sulfate reduction. However, this neither takes place in the sulfate itself nor during formation of APS (adenosine-5'-phosphosulfate), but rather in intermediates of the sulfate reduction pathway. These may in turn be partially reoxidized to form sulfate. This reoxidation leads to an incorporation of oxygen from water into the "recycled" sulfate changing the overall 18O isotopic composition of the remaining sulfate fraction. Our study shows that such incorporation of 18O is correlated with the

Physico-Chemical and microbial water quality assessment of Densu ...

African Journals Online (AJOL)

Water quality assessment conducted in the Densu basin of Ghana between July ... High nutrient loads observed in the basin were due to domestic, agricultural and ... a pattern which is an intermediate between fresh and sea water systems.

Intermediate Inflation or Late Time Acceleration?

International Nuclear Information System (INIS)

Sanyal, A.K.

2008-01-01

The expansion rate of intermediate inflation lies between the exponential and power law expansion but corresponding accelerated expansion does not start at the onset of cosmological evolution. Present study of intermediate inflation reveals that it admits scaling solution and has got a natural exit form it at a later epoch of cosmic evolution, leading to late time acceleration. The corresponding scalar field responsible for such feature is also found to behave as a tracker field for gravity with canonical kinetic term.

On financial equilibrium with intermediation costs

DEFF Research Database (Denmark)

Markeprand, Tobias Ejnar

2008-01-01

This paper studies the set of competitive equilibria in financial economies with intermediation costs. We consider an arbitrary dividend structure, which includes options and equity with limited liabilities.We show a general existence result and upper-hemi continuity of the equilibrium correspond......This paper studies the set of competitive equilibria in financial economies with intermediation costs. We consider an arbitrary dividend structure, which includes options and equity with limited liabilities.We show a general existence result and upper-hemi continuity of the equilibrium...

Intermediate product selection and blending in the food processing industry

DEFF Research Database (Denmark)

Kilic, Onur A.; Akkerman, Renzo; van Donk, Dirk Pieter

2013-01-01

This study addresses a capacitated intermediate product selection and blending problem typical for two-stage production systems in the food processing industry. The problem involves the selection of a set of intermediates and end-product recipes characterising how those selected intermediates...

Transfers of Colloidal Silica from Water into Organic Solvents of Intermediate Polarities

Science.gov (United States)

Kasseh; Keh

1998-01-15

Dispersions of discrete metal-oxide submicroparticles in organic solvents of medium polarities are uneasy to generate and weakly documented. We address this topic along two general methods focusing on silica. Successive transfers of colloidal particles from water into n-propanol and then into 1,2-dichloroethane by azeotropic distillation yield a stable organosol. The particles are found to be propanol-coated by surface esterification to the extent of 0.40 nm2 per molecule. Alternatively, centrifugation-redispersion cycles make it possible to obtain stable suspensions of unaltered silica in methanol and acetonitrile starting from an aqueous silicasol. Particles are characterized by various methods including nitrogen adsorption, transmission electron microscopy, dynamic light scattering, and electrophoresis. The stabilities of these suspensions in various organic solvents are investigated with special concern for the role of residual water. Stabilization of silica in methanol is inconspicuously related to solvent permittivity and prominently dependent on the presence of adsorbed water. In contrast, the acetonitrile silicasol, which is unaffected by residual water, displays electrophoretic behavior compatible with electrostatic stabilization. Copyright 1998 Academic Press. Copyright 1998Academic Press

Intermediate product selection and blending in the food processing industry

NARCIS (Netherlands)

Kilic, Onur A.; Akkerman, Renzo; van Donk, Dirk Pieter; Grunow, Martin

2013-01-01

This study addresses a capacitated intermediate product selection and blending problem typical for two-stage production systems in the food processing industry. The problem involves the selection of a set of intermediates and end-product recipes characterising how those selected intermediates are

Effect of an Intermediate Heat-treatment on a Change of the Corrosion Resistance and Hardness of a HANA-4 Outer Strip

International Nuclear Information System (INIS)

Lee, Myung Ho; Jung, Yang Il; Park, Sang Yoon; Choi, Byoung Kwon; Park, Jeong Yong; Jeong, Yong Hwan; Eom, Kyong Bo; Park, Nam Gyu; Lim, Yoon Soo

2008-01-01

KAERI (Korea Atomic Energy Research Institute) in collaboration with KNF (Korea Nuclear Fuel) undertook some researches on the applicability of HANA-4 and HANA-6 alloys for the spacer grid for a PWR (Pressurized Water Reactor) nuclear fuel. As a part of the research, KAERI studied the effect of the final heat-treatment on the mechanical and corrosion properties of a HANA-4 inner strip. The strip was manufactured with a sheet which had been intermediately heat-treated at about 580 .deg. C for 2.5-4 hours after each cold rolling before being processed into the final strip product. It was mentioned that the process with the intermediate heat treatment needed reviewing to establish an improved manufacturing process for the cold rolling. So, this work tried to check the effect of an intermediate heat-treatment on the properties of a HANA-4 strip using a specimen that was taken from a second hot rolled material before a cold-rolling. The manufacturing processes, with three different kinds of annealings, were introduced to investigate the applicable intermediate heat-treatment process. After all the cold-rolling processes, the Vickers hardness was measured for the final annealed specimens and 60 days of corrosion tests were carried out to check on the effect of the intermediate heat-treatment. Finally, an appropriate intermediate heat-treatment was proposed to improve the manufacturability of the HANA-4 strip

Future possibilities with intermediate-energy neutron beams

International Nuclear Information System (INIS)

Brady, F.P.

1987-01-01

Future possibilities for using neutrons of intermediate energies (50 - 200 MeV) as a probe of the nucleus are discussed. Some of the recent thinking concerning a systematic approach for studying elastic and inelastic scattering of electrons and hadrons and the important role of medium- and intermediate-energy neutrons in such a programme is reviewed. The advantages of neutrons in this energy range over neutrons with lower energies and over intermediate-energy pions for determining nuclear-transition and ground state densities, and for distinguishing proton from neutron density (isovector sensitivity), are noted. The important role of (n,p) charge exchange reactions in nuclear excitation studies is also reviewed. Experimental methods for utilizing neutrons as probes in elastic, inelastic, and charge exchange studies at these energies are discussed

The Intermediate Neutrino Program

Energy Technology Data Exchange (ETDEWEB)

Adams, C.; et al.

2015-03-23

The US neutrino community gathered at the Workshop on the Intermediate Neutrino Program (WINP) at Brookhaven National Laboratory February 4-6, 2015 to explore opportunities in neutrino physics over the next five to ten years. Scientists from particle, astroparticle and nuclear physics participated in the workshop. The workshop examined promising opportunities for neutrino physics in the intermediate term, including possible new small to mid-scale experiments, US contributions to large experiments, upgrades to existing experiments, R&D plans and theory. The workshop was organized into two sets of parallel working group sessions, divided by physics topics and technology. Physics working groups covered topics on Sterile Neutrinos, Neutrino Mixing, Neutrino Interactions, Neutrino Properties and Astrophysical Neutrinos. Technology sessions were organized into Theory, Short-Baseline Accelerator Neutrinos, Reactor Neutrinos, Detector R&D and Source, Cyclotron and Meson Decay at Rest sessions.This report summarizes discussion and conclusions from the workshop.

The Intermediate Neutrino Program

Energy Technology Data Exchange (ETDEWEB)

Adams, C. [Yale Univ., New Haven, CT (United States); Alonso, J. R. [Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States); Ankowski, A. M. [Virginia Polytechnic Inst. and State Univ. (Virginia Tech), Blacksburg, VA (United States); Asaadi, J. A. [Syracuse Univ., NY (United States); Ashenfelter, J. [Yale Univ., New Haven, CT (United States); Axani, S. N. [Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States); Babu, K [Oklahoma State Univ., Stillwater, OK (United States); Backhouse, C. [California Inst. of Technology (CalTech), Pasadena, CA (United States); Band, H. R. [Yale Univ., New Haven, CT (United States); Barbeau, P. S. [Duke Univ., Durham, NC (United States); Barros, N. [Univ. of Pennsylvania, Philadelphia, PA (United States); Bernstein, A. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Betancourt, M. [Illinois Inst. of Technology, Chicago, IL (United States); Bishai, M. [Brookhaven National Lab. (BNL), Upton, NY (United States); Blucher, E. [Univ. of Chicago, IL (United States); Bouffard, J. [State Univ. of New York (SUNY), Albany, NY (United States); Bowden, N. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Brice, S. [Illinois Inst. of Technology, Chicago, IL (United States); Bryan, C. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Camilleri, L. [Columbia Univ., New York, NY (United States); Cao, J. [Inst. of High Energy Physics, Beijing (China); Carlson, J. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Carr, R. E. [Columbia Univ., New York, NY (United States); Chatterjee, A. [Univ. of Texas, Arlington, TX (United States); Chen, M. [Univ. of California, Irvine, CA (United States); Chen, S. [Tsinghua Univ., Beijing (China); Chiu, M. [Brookhaven National Lab. (BNL), Upton, NY (United States); Church, E. D. [Illinois Inst. of Technology, Chicago, IL (United States); Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Collar, J. I. [Univ. of Chicago, IL (United States); Collin, G. [Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States); Conrad, J. M. [Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States); Convery, M. R. [SLAC National Accelerator Lab., Menlo Park, CA (United States); Cooper, R. L. [Indiana Univ., Bloomington, IN (United States); Cowen, D. [Pennsylvania State Univ., University Park, PA (United States); Davoudiasl, H. [Brookhaven National Lab. (BNL), Upton, NY (United States); Gouvea, A. D. [Northwestern Univ., Evanston, IL (United States); Dean, D. J. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Deichert, G. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Descamps, F. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); DeYoung, T. [Michigan State Univ., East Lansing, MI (United States); Diwan, M. V. [Brookhaven National Lab. (BNL), Upton, NY (United States); Djurcic, Z. [Argonne National Lab. (ANL), Argonne, IL (United States); Dolinski, M. J. [Drexel Univ., Philadelphia, PA (United States); Dolph, J. [Brookhaven National Lab. (BNL), Upton, NY (United States); Donnelly, B. [Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States); Dwyer, D. A. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Dytman, S. [Univ. of Pittsburgh, PA (United States); Efremenko, Y. [Univ. of Tennessee, Knoxville, TN (United States); Everett, L. L. [Univ. of Wisconsin, Madison, WI (United States); Fava, A. [University of Padua, Padova (Italy); Figueroa-Feliciano, E. [Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States); Fleming, B. [Yale Univ., New Haven, CT (United States); Friedland, A. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Fujikawa, B. K. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Gaisser, T. K. [Univ. of Delaware, Newark, DE (United States); Galeazzi, M. [Univ. of Miami, FL (United States); Galehouse, DC [Univ. of Akron, OH (United States); Galindo-Uribarri, A. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Garvey, G. T. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Gautam, S. [Tribhuvan Univ., Kirtipur (Nepal); Gilje, K. E. [Illinois Inst. of Technology, Chicago, IL (United States); Gonzalez-Garcia, M. [Stony Brook Univ., NY (United States); Goodman, M. C. [Argonne National Lab. (ANL), Argonne, IL (United States); Gordon, H. [Brookhaven National Lab. (BNL), Upton, NY (United States); Gramellini, E. [Yale Univ., New Haven, CT (United States); Green, M. P. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Guglielmi, A. [University of Padua, Padova (Italy); Hackenburg, R. W. [Brookhaven National Lab. (BNL), Upton, NY (United States); Hackenburg, A. [Yale Univ., New Haven, CT (United States); Halzen, F. [Univ. of Wisconsin, Madison, WI (United States); Han, K. [Yale Univ., New Haven, CT (United States); Hans, S. [Brookhaven National Lab. (BNL), Upton, NY (United States); Harris, D. [Illinois Inst. of Technology, Chicago, IL (United States); Heeger, K. M. [Yale Univ., New Haven, CT (United States); Herman, M. [Brookhaven National Lab. (BNL), Upton, NY (United States); Hill, R. [Univ. of Chicago, IL (United States); Holin, A. [Univ. College London, Bloomsbury (United Kingdom); Huber, P. [Virginia Polytechnic Inst. and State Univ. (Virginia Tech), Blacksburg, VA (United States); Jaffe, D. E. [Brookhaven National Lab. (BNL), Upton, NY (United States); Johnson, R. A. [Univ. of Cincinnati, OH (United States); Joshi, J. [Brookhaven National Lab. (BNL), Upton, NY (United States); Karagiorgi, G. [Univ. of Manchester (United Kingdom); Kaufman, L. J. [Indiana Univ., Bloomington, IN (United States); Kayser, B. [Illinois Inst. of Technology, Chicago, IL (United States); Kettell, S. H. [Brookhaven National Lab. (BNL), Upton, NY (United States); Kirby, B. J. [Brookhaven National Lab. (BNL), Upton, NY (United States); Klein, J. R. [Univ. of Texas, Arlington, TX (United States); Kolomensky, Y. G. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Univ. of California, Berkeley, CA (United States); Kriske, R. M. [Univ. of Minnesota, Minneapolis, MN (United States); Lane, C. E. [Drexel Univ., Philadelphia, PA (United States); Langford, T. J. [Yale Univ., New Haven, CT (United States); Lankford, A. [Univ. of California, Irvine, CA (United States); Lau, K. [Univ. of Houston, TX (United States); Learned, J. G. [Univ. of Hawaii, Honolulu, HI (United States); Ling, J. [Univ. of Illinois, Urbana-Champaign, IL (United States); Link, J. M. [Virginia Polytechnic Inst. and State Univ. (Virginia Tech), Blacksburg, VA (United States); Lissauer, D. [Brookhaven National Lab. (BNL), Upton, NY (United States); Littenberg, L. [Brookhaven National Lab. (BNL), Upton, NY (United States); Littlejohn, B. R. [Illinois Inst. of Technology, Chicago, IL (United States); Lockwitz, S. [Illinois Inst. of Technology, Chicago, IL (United States); Lokajicek, M. [Inst. of Physics of the Academy of Sciences of Czech Republic, Prague (Czech Republic); Louis, W. C. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Luk, K. [Univ. of California, Berkeley, CA (United States); Lykken, J. [Illinois Inst. of Technology, Chicago, IL (United States); Marciano, W. J. [Brookhaven National Lab. (BNL), Upton, NY (United States); Maricic, J. [Univ. of Hawaii, Honolulu, HI (United States); Markoff, D. M. [North Carolina Central Univ., Durham, NC (United States); Caicedo, D. A. M. [Illinois Inst. of Technology, Chicago, IL (United States); Mauger, C. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Mavrokoridis, K. [Univ. of Liverpool (United Kingdom); McCluskey, E. [Illinois Inst. of Technology, Chicago, IL (United States); McKeen, D. [Univ. of Washington, Seattle, WA (United States); McKeown, R. [Thomas Jefferson National Accelerator Facility (TJNAF), Newport News, VA (United States); Mills, G. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Mocioiu, I. [Pennsylvania State Univ., University Park, PA (United States); Monreal, B. [Univ. of California, Santa Barbara, CA (United States); Mooney, M. R. [Brookhaven National Lab. (BNL), Upton, NY (United States); Morfin, J. G. [Illinois Inst. of Technology, Chicago, IL (United States); Mumm, P. [National Inst. of Standards and Technology (NIST), Boulder, CO (United States); Napolitano, J. [Temple Univ., Philadelphia, PA (United States); Neilson, R. [Drexel Univ., Philadelphia, PA (United States); Nelson, J. K. [College of William and Mary, Williamsburg, VA (United States); Nessi, M. [European Organization for Nuclear Research (CERN), Geneva (Switzerland); Norcini, D. [Yale Univ., New Haven, CT (United States); Nova, F. [Univ. of Texas, Austin, TX (United States); Nygren, D. R. [Univ. of Texas, Arlington, TX (United States); Gann, GDO [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Univ. of California, Berkeley, CA (United States); Palamara, O. [Illinois Inst. of Technology, Chicago, IL (United States); Parsa, Z. [Brookhaven National Lab. (BNL), Upton, NY (United States); Patterson, R. [California Inst. of Technology (CalTech), Pasadena, CA (United States); Paul, P. [Stony Brook Univ., NY (United States); Pocar, A. [Univ. of Massachusetts, Amherst, MA (United States); Qian, X. [Brookhaven National Lab. (BNL), Upton, NY (United States); Raaf, J. L. [Illinois Inst. of Technology, Chicago, IL (United States); Rameika, R. [Illinois Inst. of Technology, Chicago, IL (United States); Ranucci, G. [National Inst. of Nuclear Physics, Milano (Italy); Ray, H. [Univ. of Florida, Gainesville, FL (United States); Reyna, D. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Rich, G. C. [Triangle Universities Nuclear Lab., Durham, NC (United States); Rodrigues, P. [Univ. of Rochester, NY (United States); Romero, E. R. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States); Rosero, R. [Brookhaven National Lab. (BNL), Upton, NY (United States); Rountree, S. D. [Virginia Polytechnic Inst. and State Univ. (Virginia Tech), Blacksburg, VA (United States); Rybolt, B. [Univ. of Tennessee, Knoxville, TN (United States); Sanchez, M. C. [Iowa State Univ., Ames, IA (United States); Santucci, G. [Stony Brook Univ., NY (United States); Schmitz, D. [Univ. of Chicago, IL (United States); Scholberg, K. [Duke Univ., Durham, NC (United States); Seckel, D. [Univ. of Delaware, Newark, DE (United States); Shaevitz, M. [Columbia Univ., New York, NY (United States); Shrock, R. [Stony Brook Univ., NY (United States); Smy, M. B. [Univ. of California, Irvine, CA (United States); Soderberg, M. [Syracuse Univ., NY (United States); Sonzogni, A. [Brookhaven National Lab. (BNL), Upton, NY (United States); Sousa, A. B. [Univ. of Cincinnati, OH (United States); Spitz, J. [Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States); John, J. M. S. [Univ. of Cincinnati, OH (United States); Stewart, J. [Brookhaven National Lab. (BNL), Upton, NY (United States); Strait, J. B. [Illinois Inst. of Technology, Chicago, IL (United States); Sullivan, G. [Univ. of Maryland, College Park, MD (United States); Svoboda, R. [Univ. of California, Davis, CA (United States); Szelc, A. M. [Yale Univ., New Haven, CT (United States); Tayloe, R. [Indiana Univ., Bloomington, IN (United States); Thomson, M. A. [Univ. of Cambridge (United Kingdom); Toups, M. [Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States); Vacheret, A. [Univ. of Oxford (United Kingdom); Vagins, M. [Univ. of California, Irvine, CA (United States); Water, R. G. V. D. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Vogelaar, R. B. [Virginia Polytechnic Inst. and State Univ. (Virginia Tech), Blacksburg, VA (United States); Weber, M. [Bern (Switzerland); Weng, W. [Brookhaven National Lab. (BNL), Upton, NY (United States); Wetstein, M. [Univ. of Chicago, IL (United States); White, C. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); White, B. R. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Whitehead, L. [Univ. of Houston, TX (United States); Whittington, D. W. [Indiana Univ., Bloomington, IN (United States); Wilking, M. J. [Stony Brook Univ., NY (United States); Wilson, R. J. [Colorado State Univ., Fort Collins, CO (United States); Wilson, P. [Illinois Inst. of Technology, Chicago, IL (United States); Winklehner, D. [Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States); Winn, D. R. [Fairfield Univ., CT (United States); Worcester, E. [Brookhaven National Lab. (BNL), Upton, NY (United States); Yang, L. [Univ. of Illinois, Urbana-Champaign, IL (United States); Yeh, M [Brookhaven National Lab. (BNL), Upton, NY (United States); Yokley, Z. W. [Virginia Polytechnic Inst. and State Univ. (Virginia Tech), Blacksburg, VA (United States); Yoo, J. [Illinois Inst. of Technology, Chicago, IL (United States); Yu, B. [Brookhaven National Lab. (BNL), Upton, NY (United States); Yu, J. [Univ. of Texas, Arlington, TX (United States); Zhang, C. [Brookhaven National Lab. (BNL), Upton, NY (United States)

2017-04-03

The US neutrino community gathered at the Workshop on the Intermediate Neutrino Program (WINP) at Brookhaven National Laboratory February 4-6, 2015 to explore opportunities in neutrino physics over the next five to ten years. Scientists from particle, astroparticle and nuclear physics participated in the workshop. The workshop examined promising opportunities for neutrino physics in the intermediate term, including possible new small to mid-scale experiments, US contributions to large experiments, upgrades to existing experiments, R&D plans and theory. The workshop was organized into two sets of parallel working group sessions, divided by physics topics and technology. Physics working groups covered topics on Sterile Neutrinos, Neutrino Mixing, Neutrino Interactions, Neutrino Properties and Astrophysical Neutrinos. Technology sessions were organized into Theory, Short-Baseline Accelerator Neutrinos, Reactor Neutrinos, Detector R&D and Source, Cyclotron and Meson Decay at Rest sessions.This report summarizes discussion and conclusions from the workshop.

The functional significance of C3-C4 intermediate traits in Heliotropium L. (Boraginaceae): gas exchange perspectives.

Science.gov (United States)

Vogan, Patrick J; Frohlich, Michael W; Sage, Rowan F

2007-10-01

We demonstrate for the first time the presence of species exhibiting C3-C4 intermediacy in Heliotropium (sensu lato), a genus with over 100 C3 and 150 C4 species. CO2 compensation points (Gamma) and photosynthetic water-use efficiencies (WUEs) were intermediate between C3 and C4 values in three species of Heliotropium: Heliotropium convolvulaceum (Gamma = 20 micromol CO2 mol(-1) air), Heliotropium racemosum (Gamma = 22 micromol mol(-1)) and Heliotropium greggii (Gamma = 17 micromol mol(-1)). Heliotropium procumbens may also be a weak C3-C4 intermediate based on a slight reduction in Gamma (48.5 micromol CO2 mol(-1)) compared to C3Heliotropium species (52-60 micromol mol(-1)). The intermediate species H. convolvulaceum, H. greggii and H. racemosum exhibited over 50% enhancement of net CO2 assimilation rates at low CO2 levels (200-300 micromol mol(-1)); however, no significant differences in stomatal conductance were observed between the C3 and C3-C4 species. We also assessed the response of Gamma to variation in O2 concentration for these species. Heliotropium convolvulaceum, H. greggii and H. racemosum exhibited similar responses of Gamma to O2 with response slopes that were intermediate between the responses of C3 and C4 species below 210 mmol O2 mol(-1) air. The presence of multiple species displaying C3-C4 intermediate traits indicates that Heliotropium could be a valuable new model for studying the evolutionary transition from C3 to C4 photosynthesis.

Comments on intermediate-scale models

International Nuclear Information System (INIS)

Ellis, J.; Enqvist, K.; Nanopoulos, D.V.; Olive, K.

1987-01-01

Some superstring-inspired models employ intermediate scales m I of gauge symmetry breaking. Such scales should exceed 10 16 GeV in order to avoid prima facie problems with baryon decay through heavy particles and non-perturbative behaviour of the gauge couplings above m I . However, the intermediate-scale phase transition does not occur until the temperature of the Universe falls below O(m W ), after which an enormous excess of entropy is generated. Moreover, gauge symmetry breaking by renormalization group-improved radiative corrections is inapplicable because the symmetry-breaking field has not renormalizable interactions at scales below m I . We also comment on the danger of baryon and lepton number violation in the effective low-energy theory. (orig.)

The influence of organic materials on the near field of an intermediate level waste radioactive waste repository

International Nuclear Information System (INIS)

Wilkins, J.D.

1988-02-01

The influence of organic materials, which are present in some intermediate level wastes, on the chemistry of the near field of a radioactive waste repository is discussed. Particular attention is given to the possible formation of water soluble complexing agents formed as a result of the radiation field and chemical conditions. The present state of the research is reviewed. (author)

Surface Intermediate Zone of Submerged Turbulent Buoyant Jet in Current

DEFF Research Database (Denmark)

Chen, H. B.; Larsen, Torben

1995-01-01

This paper deals with the intermediate zone between the jet and plume stages of a submerged buoyant discharge from sea outfall in current. The stability criteria, plume width and height after the intermediate zone and the dilution within the intermediate region have been studied theoretically and...

Computational uncertainties in silicon dioxide/plutonium intermediate neutron spectrum systems

International Nuclear Information System (INIS)

Jaegers, P.J.

1997-01-01

In the past several years, several proposals have been made for the long-term stabilization and storage of surplus fissile materials. Many of these proposed scenarios involve systems that have an intermediate neutron energy spectrum. Such intermediate-energy systems are dominated by scattering and fission events induced by neutrons ranging in energy from 1 eV to 100keV. To ensure adequate safety margins and cost effectiveness, it is necessary to have benchmark data for these intermediate-energy spectrum systems; however, a review of the nuclear criticality benchmarks indicates that no formal benchmarks are available. Nuclear data uncertainties have been reported for some types of intermediate-energy spectrum systems. Using a variety of Monte Carlo computer codes and cross-section sets, reported significant variations in the calculated k ∞ of intermediate-energy spectrum metal/ 235 U systems. We discuss the characteristics of intermediate neutron spectrum systems and some of the computational differences that can occur in calculating the k eff of these systems

On the stability of rotational discontinuities and intermediate shocks

International Nuclear Information System (INIS)

Lee, L.C.; Huang, L.; Chao, J.K.

1989-01-01

The stability of rotational discontinuities and intermediate shocks is studied based on a hybrid simulation code. The simulation results show that rotational discontinuities are stable and intermediate shocks are not stationary. Intermediate shocks tend to evolve to rotational discontinuities and waves. The authors employ several different initial profiles for the magnetic field in the transition region and find that the final structure of the discontinuities or shocks is not sensitive to the initial magnetic field profile. The present results are different from those obtained from the resistive MHD simulations. Furthermore, their study indicates that the kinetic effect of particles plays an important role in the structure and stability of rotational discontinuities and intermediate shocks

Gateways and Water Mass Mixing in the Late Cretaceous North Atlantic

Science.gov (United States)

Asgharian Rostami, M.; Martin, E. E.; MacLeod, K. G.; Poulsen, C. J.; Vande Guchte, A.; Haynes, S.

2017-12-01

Regions of intermediate/deep water formation and water-mass mixing in the North Atlantic are poorly defined for the Late Cretaceous, a time of gateway evolution and cooler conditions following the Mid Cretaceous greenhouse. Improved proxy data combined with modeling efforts are required to effectively evaluate the relationship between CO2, paleogeography, and circulation during this cooler interval. We analyzed and compiled latest Cretaceous (79 - 66 Ma) ɛNd and δ13C records from seven bathyal (paleodepths 0.2 - 2 km) and eight abyssal (paleodepths > 2 km) sites in the North Atlantic. Data suggest local downwelling of Northern Component Water (NCW; ɛNd -9.5 and δ13C 1.7 ‰) is the primary source of intermediate/deep water masses in the basin. As this water flows southward and ages, δ13C values decrease and ɛNd values increase; however, additional chemical changes at several sites require mixing with contributions from several additional water masses. Lower ɛNd ( -10) and higher δ13C ( 1.9 ‰) values in the deep NW part of the basin indicate proximal contributions from a region draining old continental crust, potentially representing deep convection following opening of the Labrador Sea. In the deep NE Iberian Basin, higher ɛNd ( -7) and lower δ13C ( 0.8 ‰) during the Campanian suggest mixing with a Tethyan source (ɛNd -7 and δ13C 0.1 ‰) whose importance decreased with restriction of that gateway in the Maastrichtian. Data from bathyal sites suggest additional mixing. In the SE Cape Verde region, observed ɛNd variations from -10 in the Campanian to -13 and -12 in the early and late Maastrichtian, respectively, may record variations in output rates of Tethyan and/or NCW sources and Demerara Bottom Water (ɛNd -16), a proposed warm saline intermediate water mass formed in shallow, equatorial seas. Pacific inflow through the Caribbean gateway impacts intermediate sites at Blake Nose (ɛNd values -8), particularly the shallowest site during the late

MNE Entrepreneurial Capabilities at Intermediate Levels

DEFF Research Database (Denmark)

Hoenen, Anne K.; Nell, Phillip Christopher; Ambos, Björn

2014-01-01

at intermediate geographical levels differ from local subsidiaries and global corporate headquarters, and why those differences are important. We illustrate our arguments using data on European regional headquarters (RHQs). We find that RHQs' entrepreneurial capabilities depend on their external embeddedness...... and on the heterogeneous information that is generated through dissimilar markets within the region. Our study opens up for an interesting discussion of the independence of these mechanisms. In sum, we contribute to the understanding of the entrepreneurial role of intermediate units in general and RHQs in particular....

Financial Intermediation and Economic Growth of Jordan 1964-1988

OpenAIRE

Magableh, Ali H.

1995-01-01

Until recently, the economics and financial literature placed little attention on the role that financial intermediation can play in accelerating the rate of economic development in less Developed Countries (LDCs). This has been changed now, however, where some instrumental role has been emphasised for financial intermediation in the process of economic development and growth. It is argued that an expansion of the financial system, size and intermediation in LDCs tends to increase the level o...

Surface intermediates on metal electrodes at high temperatures

DEFF Research Database (Denmark)

Zachau-Christiansen, Birgit; Jacobsen, Torben; Bay, Lasse

1998-01-01

The mechanisms widely conceived for the O(2)-reduction or H(2)-oxidation reactions in SOFC's involve intermediate O/H species adsorbed on the electrode surface. The presence of these intermediates is investigated by linear sweep voltammetry. In air at moderate temperatures (500 degrees C) Pt...

Intermediate-Mass Black Holes

Science.gov (United States)

Miller, M. Coleman; Colbert, E. J. M.

2004-01-01

The mathematical simplicity of black holes, combined with their links to some of the most energetic events in the universe, means that black holes are key objects for fundamental physics and astrophysics. Until recently, it was generally believed that black holes in nature appear in two broad mass ranges: stellar-mass (M~3 20 M⊙), which are produced by the core collapse of massive stars, and supermassive (M~106 1010 M⊙), which are found in the centers of galaxies and are produced by a still uncertain combination of processes. In the last few years, however, evidence has accumulated for an intermediate-mass class of black holes, with M~102 104 M⊙. If such objects exist they have important implications for the dynamics of stellar clusters, the formation of supermassive black holes, and the production and detection of gravitational waves. We review the evidence for intermediate-mass black holes and discuss future observational and theoretical work that will help clarify numerous outstanding questions about these objects.

Analysis of the need for intermediate and peaking technologies in the year 2000

Energy Technology Data Exchange (ETDEWEB)

Barrager, S.M.; Campbell, G.L.

1980-04-01

This analysis was conducted to assess the impact of load management on the future need for intermediate- and peak-generating technologies (IPTs) such as combustion turbines, pumped storage, and cycling coal plants. There will be a reduced need for IPTs if load-management activities such as time-of-use pricing, together with customer-owned energy-storage devices, hot-water-heater controls, and interruptible service, can economically remove most of the variation from electric-power demands. Therefore, the analysis assesses the need for IPTs in an uncertain future, which will probably include load management and time-differentiated electricity prices. Section 2 provides a condensed description of the models used in the analysis. (Details and data sets are contained in the appendixes.) Results of sensitivities on growth rates, model parameters, and appliance saturations are discussed in Section 3, which also contains the analysis of the potential impacts of customer energy storage, appliance control, and time-of-use pricing. The future need for intermediate and peaking technologies is analyzed in Section 4.

Intermediate Levels of Visual Processing

National Research Council Canada - National Science Library

Nakayama, Ken

1998-01-01

...) surface representation, here we have shown that there is an intermediate level of visual processing, between the analysis of the image and higher order representations related to specific objects; (2...

Intermediate energy proton and light-ion scattering

International Nuclear Information System (INIS)

Moss, J.M.

1981-01-01

A review is presented of recent (1979-81) developments in the field of intermediate-energy proton and light-ion scattering from nuclei. New theoretical and calculational techniques of particular interest to experimentalists are discussed. Emphasis is placed on topics in nuclear structure physics - giant resonances, pion-condensation precursor phenomena, and polarization transfer (spin-flip) experiments - where intermediate energy proton and light-ion scattering has made new and unique contributions

Comments on intermediate-scale models

Energy Technology Data Exchange (ETDEWEB)

Ellis, J.; Enqvist, K.; Nanopoulos, D.V.; Olive, K.

1987-04-23

Some superstring-inspired models employ intermediate scales m/sub I/ of gauge symmetry breaking. Such scales should exceed 10/sup 16/ GeV in order to avoid prima facie problems with baryon decay through heavy particles and non-perturbative behaviour of the gauge couplings above m/sub I/. However, the intermediate-scale phase transition does not occur until the temperature of the Universe falls below O(m/sub W/), after which an enormous excess of entropy is generated. Moreover, gauge symmetry breaking by renormalization group-improved radiative corrections is inapplicable because the symmetry-breaking field has not renormalizable interactions at scales below m/sub I/. We also comment on the danger of baryon and lepton number violation in the effective low-energy theory.

Proceedings of the Workshop on Program Options in Intermediate-Energy Physics. Keynote address: New directions in intermediate-energy nuclear physics

International Nuclear Information System (INIS)

Brown, G.E.

1980-05-01

This report presents the keynote address given by G.E. Brown at a LASL colloquium on August 21, 1979, for the Workshop on Program Options in Intermediate-Energy Physics. Professor Brown reviewed major topics of interest in intermediate-energy nuclear physics and suggested experimental approaches that might be most productive in the near future. 22 figures

Projecting non-diffracting waves with intermediate-plane holography.

Science.gov (United States)

Mondal, Argha; Yevick, Aaron; Blackburn, Lauren C; Kanellakopoulos, Nikitas; Grier, David G

2018-02-19

We introduce intermediate-plane holography, which substantially improves the ability of holographic trapping systems to project propagation-invariant modes of light using phase-only diffractive optical elements. Translating the mode-forming hologram to an intermediate plane in the optical train can reduce the need to encode amplitude variations in the field, and therefore complements well-established techniques for encoding complex-valued transfer functions into phase-only holograms. Compared to standard holographic trapping implementations, intermediate-plane holograms greatly improve diffraction efficiency and mode purity of propagation-invariant modes, and so increase their useful non-diffracting range. We demonstrate this technique through experimental realizations of accelerating modes and long-range tractor beams.

Surface Intermediates on Metal Electrodes at High Temperature

DEFF Research Database (Denmark)

Zachau-Christiansen, Birgit; Jacobsen, Torben; Bay, Lasse

1997-01-01

The mechanisms widely suggested for the O2-reduc-tion or H2-oxidation SOFC reactions involve inter-mediate O/H species adsorbed on the electrode surface. The presence of these intermediates is investigated by linear sweep voltammetry. In airat moderate temperatures (500øC) Pt in contact with YSZ...

Processing and validation of intermediate energy evaluated data files

International Nuclear Information System (INIS)

2000-01-01

Current accelerator-driven and other intermediate energy technologies require accurate nuclear data to model the performance of the target/blanket assembly, neutron production, activation, heating and damage. In a previous WPEC subgroup, SG13 on intermediate energy nuclear data, various aspects of intermediate energy data, such as nuclear data needs, experiments, model calculations and file formatting issues were investigated and categorized to come to a joint evaluation effort. The successor of SG13, SG14 on the processing and validation of intermediate energy evaluated data files, goes one step further. The nuclear data files that have been created with the aforementioned information need to be processed and validated in order to be applicable in realistic intermediate energy simulations. We emphasize that the work of SG14 excludes the 0-20 MeV data part of the neutron evaluations, which is supposed to be covered elsewhere. This final report contains the following sections: section 2: a survey of the data files above 20 MeV that have been considered for validation in SG14; section 3: a summary of the review of the 150 MeV intermediate energy data files for ENDF/B-VI and, more briefly, the other libraries; section 4: validation of the data library against an integral experiment with MCNPX; section 5: conclusions. (author)

An improved intermediate resonance method for heterogeneous media

International Nuclear Information System (INIS)

Chiovato, O.; Corno, S.; Pasquantonio, F.Di.

1977-01-01

A new formulation is described of the Intermediate Resonance method which incorporates the previous developments suitably modified and improved, together with some new contributions. The 'intermediate' character is directly introduced in the integral operator K, allowing a more rigorous deduction of the equations for evaluating the intermediate parameters related to the nuclides involved in the system. There is no limit to the number of internal (admixed in the fuel) and external moderators. The capability to take into account the interference scattering has been extended to heterogeneous systems. The Doppler broadening is described by means of new accurate rational approximations to the broadened line shape psi. Finally the use of energy mean values suitably defined refines the values of the resonance integrals and resonance absorption cross sections. The Intermediate Resonance method so extended and improved, has been coded in a group of FORTRAN routines, which have been inserted as a calculation option in the fast section of the GGC code for the evaluation of multigroup cross sections. A series of calculations has been carried out, using these routines, and comparisons have been made with Monte Carlo and Nordheim's methods. The results obtained show that the Intermediate Resonance method developed in the present work offers considerable advantages over Nordheim's method: better accuracy in evaluating resonance absorption cross sections, and much smaller computing times. (author)

Seismic Characterization of Oceanic Water Masses, Water Mass Boundaries, and Mesoscale Eddies SE of New Zealand

Science.gov (United States)

Gorman, Andrew R.; Smillie, Matthew W.; Cooper, Joanna K.; Bowman, M. Hamish; Vennell, Ross; Holbrook, W. Steven; Frew, Russell

2018-02-01

The Subtropical and Subantarctic Fronts, which separate Subtropical, Subantarctic, and Antarctic Intermediate Waters, are diverted to the south of New Zealand by the submerged continental landmass of Zealandia. In the upper ocean of this region, large volumes of dissolved or suspended material are intermittently transported across the Subtropical Front; however, the mechanisms of such transport processes are enigmatic. Understanding these oceanic boundaries in three dimensions generally depends on measurements collected from stationary vessels and moorings. The details of these data sets, which are critical for understanding how water masses interact and mix at the fine-scale (seismic reflection images of oceanic water masses have been produced using petroleum industry data. These seismic sections clearly show three main water masses, the boundary zones (fronts) between them, and associated thermohaline fine structure that may be related to the mixing of water masses in this region. Interpretations of the data suggest that the Subtropical Front in this region is a landward-dipping zone, with a width that can vary between 20 and 40 km. The boundary zone between Subantarctic Waters and the underlying Antarctic Intermediate Waters is also observed to dip landward. Several isolated lenses have been identified on the three data sets, ranging in size from 9 to 30 km in diameter. These lenses are interpreted to be mesoscale eddies that form at relatively shallow depths along the south side of the Subtropical Front.

Glutamate Induced Thermal Equilibrium Intermediate and Counteracting Effect on Chemical Denaturation of Proteins.

Science.gov (United States)

Anumalla, Bramhini; Prabhu, N Prakash

2018-01-25

When organisms are subjected to stress conditions, one of their adaptive responses is accumulation of small organic molecules called osmolytes. These osmolytes affect the structure and stability of the biological macromolecules including proteins. The present study examines the effect of a negatively charged amino acid osmolyte, glutamate (Glu), on two model proteins, ribonuclease A (RNase A) and α-lactalbumin (α-LA), which have positive and negative surface charges at pH 7, respectively. These proteins follow two-state unfolding transitions during both heat and chemical induced denaturation processes. The addition of Glu stabilizes the proteins against temperature and induces an early equilibrium intermediate during unfolding. The stability is found to be enthalpy-driven, and the free energy of stabilization is more for α-LA compared to RNase A. The decrease in the partial molar volume and compressibility of both of the proteins in the presence of Glu suggests that the proteins attain a more compact state through surface hydration which could provide a more stable conformation. This is also supported by molecule dynamic simulation studies which demonstrate that the water density around the proteins is increased upon the addition of Glu. Further, the intermediates could be completely destabilized by lower concentrations (∼0.5 M) of guanidinium chloride and salt. However, urea subverts the Glu-induced intermediate formed by α-LA, whereas it only slightly destabilizes in the case of RNase A which has a positive surface charge and could possess charge-charge interactions with Glu. This suggests that, apart from hydration, columbic interactions might also contribute to the stability of the intermediate. Gdm-induced denaturation of RNase A and α-LA in the absence and the presence of Glu at different temperatures was carried out. These results also show the Glu-induced stabilization of both of the proteins; however, all of the unfolding transitions followed two

Evidence to support horses as natural intermediate hosts for Sarcocystis neurona.

Science.gov (United States)

Mullaney, Thomas; Murphy, Alice J; Kiupel, Matti; Bell, Julia A; Rossano, Mary G; Mansfield, Linda S

2005-10-10

Opossums (Didelphis spp.) are the definitive host for the protozoan parasite Sarcocystis neurona, the causative agent of equine protozoal myeloencephalitis (EPM). Opossums shed sporocysts in feces that can be ingested by true intermediate hosts (cats, raccoons, skunks, armadillos and sea otters). Horses acquire the parasite by ingestion of feed or water contaminated by opossum feces. However, horses have been classified as aberrant intermediate hosts because the terminal asexual sarcocyst stage that is required for transmission to the definitive host has not been found in their tissues despite extensive efforts to search for them [Dubey, J.P., Lindsay, D.S., Saville, W.J., Reed, S.M., Granstrom, D.E., Speer, C.A., 2001b. A review of Sarcocystis neurona and equine protozoal myeloencephalitis (EPM). Vet. Parasitol. 95, 89-131]. In a 4-month-old filly with neurological disease consistent with EPM, we demonstrate schizonts in the brain and spinal cord and mature sarcocysts in the tongue and skeletal muscle, both with genetic and morphological characteristics of S. neurona. The histological and electron microscopic morphology of the schizonts and sarcocysts were identical to published features of S. neurona [Stanek, J.F., Dubey, J.P., Oglesbee, M.J., Reed, S.M., Lindsay, D.S., Capitini, L.A., Njoku, C.J., Vittitow, K.L., Saville, W.J., 2002. Life cycle of Sarcocystis neurona in its natural intermediate host, the raccoon, Procyon lotor. J. Parasitol. 88, 1151-1158]. DNA from schizonts and sarcocysts from this horse produced Sarcocystis specific 334bp PCR products [Tanhauser, S.M., Yowell, C.A., Cutler, T.J., Greiner, E.C., MacKay, R.J., Dame, J.B., 1999. Multiple DNA markers differentiate Sarcocystis neurona and Sarcocystis falcatula. J. Parasitol. 85, 221-228]. Restriction fragment length polymorphism (RFLP) analysis of these PCR products showed banding patterns characteristic of S. neurona. Sequencing, alignment and comparison of both schizont and sarcocyst DNA

Development of the North Pacific Ocean model for the assessment of the distribution of the radioactive materials. Improvement for formation of the North Pacific intermediate water

International Nuclear Information System (INIS)

Tsubono, Takaki; Misumi, Kazuhiro; Tsumune, Daisuke; Bryan, Frank

2014-01-01

The radioactive materials such as 137 Cs were released to the North Pacific Ocean (NP) through the major pathway; direct release from the accident site and atmospheric deposition, after the accidents at the Fukushima Dai-ichi Nuclear Power Plant following the earthquake and tsunami. The behavior of the materials in the NP has been paid great attention after the accident. The North Pacific Model for the calculation of the distribution of radionuclides has been developed using Regional Ocean Modeling System (ROMS). The model domain is NP with an eddy-resolving grid. A series of numerical experiments conducted by models suggests that the computational diffusivity caused by the advection scheme and the topography roughness are critical in representing the separation of Kuroshio, the Kuroshio Extension, the mixed-water region between Kuroshio Extension and Oyashio front and the formation of the North Pacific Intermediate Water (NPIW). The model requires the forth order scheme in the tracer advection and the smoothing of topography for these problems. Moreover the tidal mixing process around the straits in the North Pacific Ocean and the sea ice play important roles to reproduce the formation of lon salinity around the NPIW as well as the isopycnal mixing process represented by an eddy-resolving model. (author)

The management of intermediate level wastes in Sweden

International Nuclear Information System (INIS)

Hultgren, Aa.; Thegerstroem, C.

1980-01-01

A brief overview of current practices and research in Sweden on the management of intermediate level wastes is given. Intermediate level wastes include spent resins, filters and core components from the six power reactors in operation; radioactive wastes from nuclear fuel development at Studsvik and from non-nuclear applications are a minor contribution. (Auth.)

Continuous Hydrolysis and Liquid–Liquid Phase Separation of an Active Pharmaceutical Ingredient Intermediate Using a Miniscale Hydrophobic Membrane Separator

DEFF Research Database (Denmark)

Cervera Padrell, Albert Emili; Morthensen, Sofie Thage; Lewandowski, Daniel Jacob

2012-01-01

Continuous hydrolysis of an active pharmaceutical ingredient intermediate, and subsequent liquid–liquid (L-L) separation of the resulting organic and aqueous phases, have been achieved using a simple PTFE tube reactor connected to a miniscale hydrophobic membrane separator. An alkoxide product......, obtained in continuous mode by a Grignard reaction in THF, reacted with acidic water to produce partially miscible organic and aqueous phases containing Mg salts. Despite the partial THF–water miscibility, the two phases could be separated at total flow rates up to 40 mL/min at different flow ratios, using...

Preliminary thermal sizing of intermediate heat exchanger for NHDD system

International Nuclear Information System (INIS)

Kim, Chan Soo; Hong, Sung Deok; Kim, Yong Wan; Chang, Jongh Wa

2009-01-01

Nuclear Hydrogen Development and Demonstration (NHDD) system is a Very High Temperature gascooled Reactor (VHTR) coupled with hydrogen production systems. Intermediate heat exchanger transfers heat from the nuclear reactor to the hydrogen production system. This study presented the sensitivity analysis on a preliminary thermal sizing of the intermediate heat exchanger. Printed Circuit Heat Exchanger (PCHE) was selected for the thermal sizing because the printed circuit heat exchanger has the largest compactness among the heat exchanger types. The analysis was performed to estimate the effect of key parameters including the operating condition of the intermediate system, the geometrical factors of the PCHE, and the working fluid of the intermediate system.

Intermediate mass distribution of the dual resonance pomeron

International Nuclear Information System (INIS)

Chiu, C.B.; Matsuda, S.

1978-01-01

The intermediate mass distribution of the dual resonance pomeron is determined at the one-loop level and it is shown that the mass distribution obtained is remarkably similar to a suitably defined mass distribution in the dual multiperipheral model. Thus it is suggestive to identify the intermediate states of the dual resonance pomeron with multiperipheral processes. (Auth.)

CONDITIONING OF INTERMEDIATE-LEVEL WASTE AT FORSCHUNGSZENTRUM JUELICH GMBH

International Nuclear Information System (INIS)

Krumbach, H.

2003-01-01

This contribution to the group of low-level, intermediate, mixed and hazardous waste describes the conditioning of intermediate-level mixed waste (dose rate above 10 mSv/h at the surface) from Research Centre Juelich (FZJ). Conditioning of the waste by supercompaction is performed at Research Centre Karlsruhe (FZK). The waste described is radioactive waste arising from research at Juelich. This waste includes specimens and objects from irradiation experiments in the research reactors Merlin (FRJ-1) and Dido (FRJ-2) at FZJ. In principle, radioactive waste at Forschungszentrum Juelich GmbH is differentiated by the surface dose rate at the waste package. Up to a surface dose rate of 10 mSv/h, the waste is regarded as low-level. The radioactive waste described here has a surface dose rate above 10 mSv/h. Waste up to 10 mSv/h is conditioned at the Juelich site according to different conditioning methods. The intermediate-level waste can only be conditioned by supercompaction in the processing facility for intermediate-level waste from plant operation at Research Centre Karlsruhe. Research Centre Juelich also uses this waste cell to condition its intermediate-level waste from plant operation

Supersymmetry and intermediate symmetry breaking in SO(10) superunification

International Nuclear Information System (INIS)

Asatryan, H.M.; Ioannisyan, A.N.

1985-01-01

A scheme of simultaneous breakdown of intermediate symmetry SO(10) → SU(3)sub(c) x U(1) x SU(2)sub(L) x SU(2)sub(R) and supersymmetry by means of a single scale parameter is suggested. This intermediate symmetry, which is preferable physically, owing to the broken supersymmetry has a minimum lying lower than SU(4) x SU(2)sub(L) x SU(2)sub(R). The intermediate symmetry is broken by the vacuum expectation value of the Higgs superfields. Owing to the quantum corrections the potential minimum turns out to correspond to breakdown of the intermediate symmetry up to the standard group SU(3)sub(c) x SU(2)sub(L) x U(1)sub(y). The value of the Weinberg angle is less than that in the supersymmetric SU(5) model and agrees with the experiment

Latitudinal variations in intermediate depth ventilation and biological production over northeastern Pacific Oxygen Minimum Zones during the last 60 ka

Science.gov (United States)

Cartapanis, Olivier; Tachikawa, Kazuyo; Bard, Edouard

2012-10-01

Mechanisms affecting past variability in the Oxygen Minimum Zone (OMZ) in the Eastern Tropical North Pacific (ETNP) are poorly known. We analyzed core MD02-2524, obtained from the Nicaragua Margin in the present ETNP OMZ for major and minor elements (titanium (Ti), brome (Br), silicon (Si), potassium (K), and calcium (Ca)) using an X-ray Fluorescence (XRF) core scanner, and redox-sensitive trace elements (uranium (U), molybdenum (Mo), and nickel (Ni)) determined by ICP-MS. The U and Mo content was higher during the deglaciation than during the Holocene and the last glacial maximum, whereas enrichment was not observed for Ni, an element closely associated with organic matter. High-resolution XRF scanning indicated that the Ca-based carbonate content had millennial-scale variability inversely correlated with Br-based organic matter and Si/K-based opal content during the last glacial period. The available data suggest no clear regional trend in biological productivity during the last deglaciation, but significant local variability in the coastal eastern equatorial Pacific. The trace element enrichment and the lack of a concomitant increase in biogenic phases indicated that an enhanced ETNP OMZ, at least between 15°N and 12°N at a water depth of 500-900 m, was principally caused by a reduced oxygen supply driven by oceanic circulation to the Nicaragua Basin during the deglaciation. The observed patterns can be interpreted as the distinct changes in the oxygenation state of northern and southern water masses at intermediate depths. We also found evidence for a decoupling between local productivity and pore water oxygenation for several millennial-scale events during Marine Isotopic Stage 3, indicating that remote oxygen consumption and/or oceanic ventilation impacted OMZ intensity. Multi-millennial scale variations of the productivity at Papagayo upwelling cell displayed an opposite trend from productivity at the Costa Rica Dome, in relation with the latitudinal shift

Intermediate energy data

International Nuclear Information System (INIS)

Koning, A.J.; Fukahori, T.; Hasegawa, A.

1998-01-01

Subgroup 13 (SG13) on Intermediate Energy Nuclear data was formed by NEA Nuclear Science Committee to solve common problems of these types of data for nuclear applications. An overview is presented in this final report of the present activities of SG13, including data needs, high-priority nuclear data request list (nuclides), compilation of experimental data, specialists meetings and benchmarks, data formats and data libraries. Some important accomplishments are summarized, and recommendations are presented. (R.P.)

Has Banks’ Financial Intermediation Improved in Russia?

OpenAIRE

Fungachova, Z.; Solanko, L.

2010-01-01

The aim of this paper is to analyze the increasing importance of banks in the Russian economy over the period following the financial crisis of 1998. We use several measures to assess the role of banks in domestic financial intermediation in Russia. The traditional macro-level view is complemented by the analysis of sectoral financial flows as well as by insights from micro-level studies. All of these confirm that banks are becoming increasingly important in financial intermediation. We find ...

The carbonate mineralogy and distribution of habitat-forming deep-sea corals in the southwest pacific region

Science.gov (United States)

Bostock, Helen C.; Tracey, Dianne M.; Currie, Kim I.; Dunbar, Gavin B.; Handler, Monica R.; Mikaloff Fletcher, Sara E.; Smith, Abigail M.; Williams, Michael J. M.

2015-06-01

Habitat-forming deep-sea scleractinian and alcyonacean corals from around the southwest Pacific were analysed for their calcium carbonate mineralogy. Scleractinian coral species Solenosmilia variabilis, Enallopsammia rostrata, Goniocorella dumosa, Madrepora oculata and Oculina virgosa were all found to be 100% aragonitic, while some members of the alcyonacean taxa Keratoisis spp., Lepidisis spp., and Paragorgia spp. were determined to be high magnesium (Mg) calcite (with 8-11 mol% MgCO3) and Primnoa sp. is bimineralic with both aragonite and Mg calcite. The majority of these habitat-forming deep-sea corals are found at intermediate depths (800-1200 m) in the Antarctic Intermediate Waters (AAIW) with low salinities (~34.5), temperatures of 4-8 °C and high oxygen concentrations (>180 μmol/kg) and currently sitting above the aragonite saturation horizon (ASH). However, habitat-forming corals have been recorded from greater depths, in cooler waters (2-4 °C) that are undersaturated with respect to aragonite (Ωaragonite160 μmol/kg. To address the sampling depth bias the coral records were normalised by the number of benthic stations (sampling effort) in the same depth range. This shows that the highest number of corals per sampling effort is between 1000 and 1400 m with corals present in over 5% of the stations at these depths. The normalised records and Boot Strap analyses suggests that scleractinian corals, especially S. variabilis should be present in >1% of stations down to 1800 m water depth, with E. rostrata, M. oculata and G. dumosa slightly shallower. While alcyonacean corals are found in >1% down to 2600 m, with Keratoisis spp. the deepest down to 2600 m, while Lepidisis spp. and Paragorgia spp. found down to 1800 m. This suggests that most species can probably tolerate some undersaturation of aragonite (Ωaragonite=0.8-0.9), with several species/genera (S. variabilis; Keratoisis spp.) even more tolerant of lower carbonate concentrations ([CO3 2 -]), down

Efficient synthesis and physicochemical characterization of natural danshensu, its S isomer and intermediates thereof

Science.gov (United States)

Sidoryk, Katarzyna; Filip, Katarzyna; Cmoch, Piotr; Łaszcz, Marta; Cybulski, Marcin

2018-02-01

The synthesis and molecular structure details of R- 3,4-dihydroxyphenyl lactic acid (danshensu) and related compounds, i.e. S isomer and the key intermediates have been described. Danshensu is an important water soluble phenolic acid of Salvia miltiorrhiza herb (danshen or red sag) with numerous applications in traditional Chinese medicine (TCM). Our synthetic approach was based on the Knoevenagel condensation of the protected 3,4-dihydroxybenzaldehyd and Meldrum acid derivative, followed by asymmetric Sharples dihydroxylation, reductive mono dehydroxylation and final deprotection. All compounds were characterized by various spectroscopic techniques: 1H-, 13C- magnetic resonance (NMR); Fourier-transformed infrared (FTIR); Raman, HR mass spectroscopy. For the determination of compound optical purities original HPLC methods were developed which allowed for the efficient resolution of danshensu R and S enantiomers as well as its intermediate enantiomers, using commercially available chiral stationary phases. Furthermore, in order to better understand danshensu specificity as a potential API in drug formulation, the physicochemical properties of the compounds were studied by thermal analysis, including differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA).

Design Concept of Dialyzer Biomaterials: How to Find Biocompatible Polymers Based on the Biointerfacial Water Structure.

Science.gov (United States)

Tanaka, Masaru

2017-01-01

Although various types of materials have been used widely in dialyzers, most biomaterials lack the desired functional properties to interface with blood and have not been engineered for optimum performance. Therefore, there is increasing demand to develop novel materials to address such problems in the dialysis arena. Numerous parameters of polymeric biomaterials can affect biocompatibility in a controlled manner. The mechanisms responsible for the biocompatibility of polymers at the molecular level have not been clearly demonstrated, although many theoretical and experimental efforts have been made to try and understand them. Moreover, water interactions have been recognized as fundamental for the blood response to contact with polymers. We have proposed the 'intermediate water' concept and hypothesized that intermediate water, which prevents the proteins and blood cells from directly contacting the polymer surface, or nonfreezing water on the polymer surface, plays an important role in the biocompatibility of polymers. This chapter provides an overview of the recent experimental progress of biocompatible polymers measured by thermal, spectroscopic, and surface force techniques. Additionally, it highlights recent developments in the use of biocompatible polymeric biomaterials for dialyzers and provides an overview of the progress made in the design of multifunctional biomedical polymers by controlling the biointerfacial water structure through precision polymer synthesis. Key Messages: Intermediate water was found only in hydrated biopolymers (proteins, polysaccharides, and nucleic acids, DNA and RNA) and hydrated biocompatible synthetic polymers. Intermediate water could be one of the main screening factors for the design of appropriate dialyzer materials. © 2017 S. Karger AG, Basel.

An ecological study of Bithynia snails, the first intermediate host of Opisthorchis viverrini in northeast Thailand.

Science.gov (United States)

Wang, Yi-Chen; Ho, Richard Cheng Yong; Feng, Chen-Chieh; Namsanor, Jutamas; Sithithaworn, Paiboon

2015-01-01

Infection with the food-borne trematodiasis, liver fluke Opisthorchis viverrini, is a major public health concern in Southeast Asia. While epidemiology and parasitic incidence in humans are well studied, ecological information on the O. viverrini intermediate hosts remains limited. This study aimed to investigate the factors affecting the distribution and abundance of the first intermediate host, Bithynia siamensis goniomphalos snails. Water quality and snails were sampled in 31 sites in Muang District, Khon Kaen Province, Thailand from June 2012 to January 2013 to characterize the B.s. goniomphalos snail habitats. Species relative abundance and Shannon's diversity and evenness indices were employed to describe snail compositions and diversities across different habitat types. Statistical analyses were conducted to examine the extent to which the water quality variables and species interactions account for the relative abundance of B.s. goniomphalos snails. The results showed that the freshwater habitats of ponds, streams and rice paddies possessed significantly different abiotic water qualities, with water temperature and pH showing distinct statistical differences (P<0.05). Different habitats had different snail diversity and species evenness, with high B.s. goniomphalos snail abundance at rice paddy habitats. The differences in snail abundance might be due to the distinct sets of abiotic water qualities associated with each habitat types. The relative abundance of B.s. goniomphalos snails was found to be negatively correlated with that of Filopaludina martensi martensi snails (r=-0.46, P<0.05), underscoring the possible influence of species interaction on B.s. goniomphalos snail population. Field work observations revealed that rice planting seasons and irrigation could regulate snail population dynamics at rice paddy habitats. This study provides new ecological insights into the factors affecting Bithynia snail distribution and abundance. It bridges the

Heterophobia: Subverting Heterosexual Hegemony through Intermedial Applied Performance for Young People

Science.gov (United States)

Phillips, Hannah

2016-01-01

This article responds to intermediality through a case study of an intermedial applied performance for young people. "Heterophobia," a hybrid fusion of live performance, digital technology, social media and urban street art, aimed to challenge homophobia in schools and online. Intermediality was used as a tool to enhance young people's…

42 CFR 54a.12 - Treatment of intermediate organizations.

Science.gov (United States)

2010-10-01

... 42 Public Health 1 2010-10-01 2010-10-01 false Treatment of intermediate organizations. 54a.12... CHARITABLE CHOICE REGULATIONS APPLICABLE TO STATES, LOCAL GOVERNMENTS AND RELIGIOUS ORGANIZATIONS RECEIVING... ABUSE PREVENTION AND TREATMENT SERVICES § 54a.12 Treatment of intermediate organizations. If a...

Financial Intermediation and the Nigerian Economy: A Time Series ...

African Journals Online (AJOL)

... and cointegration analysis based on Engle Granger cointegration theory and error correction methodology, we tested both short and long run relationships between financial intermediation and economic growth in Nigeria. The result revealed that a long–run relationship exists between financial intermediation and growth ...

Borderline Personality Disorder in an Intermediate Psychological Therapies Service

Science.gov (United States)

Ryan, Seamus; Danquah, Adam N.; Berry, Katherine; Hopper, Mary

2017-01-01

The intermediate psychological therapies service is provided for individuals referred with common mental health problems within the primary care psychological therapies service, but whose difficulties are longstanding and/or complex. The prevalence of borderline personality disorder (BPD) in intermediate psychological therapy services has not been…

General educational disciplines practice-oriented training in intermediate vocational education

Directory of Open Access Journals (Sweden)

Liya G. Skorobogatova

2011-01-01

Full Text Available The article concerns crucial issues of practice-oriented training in Russia's intermediate vocational education, designates directions of general educational disciplines study in intermediate vocational education.

Intermediate inflation from a non-canonical scalar field

Energy Technology Data Exchange (ETDEWEB)

Rezazadeh, K.; Karami, K. [Department of Physics, University of Kurdistan, Pasdaran St., Sanandaj (Iran, Islamic Republic of); Karimi, P., E-mail: rezazadeh86@gmail.com, E-mail: KKarami@uok.ac.ir, E-mail: parvin.karimi67@yahoo.com [Center for Excellence in Astronomy and Astrophysics (CEAA-RIAAM), P.O. Box 55134-441, Maragha (Iran, Islamic Republic of)

2015-09-01

We study the intermediate inflation in a non-canonical scalar field framework with a power-like Lagrangian. We show that in contrast with the standard canonical intermediate inflation, our non-canonical model is compatible with the observational results of Planck 2015. Also, we estimate the equilateral non-Gaussianity parameter which is in well agreement with the prediction of Planck 2015. Then, we obtain an approximation for the energy scale at the initial time of inflation and show that it can be of order of the Planck energy scale, i.e. M{sub P} ∼ 10{sup 18}GeV. We will see that after a short period of time, inflation enters in the slow-roll regime that its energy scale is of order M{sub P}/100 ∼ 10{sup 16}GeV and the horizon exit takes place in this energy scale. We also examine an idea in our non-canonical model to overcome the central drawback of intermediate inflation which is the fact that inflation never ends. We solve this problem without disturbing significantly the nature of the intermediate inflation until the time of horizon exit.

Estimation of intermediate grade uranium resources. Final report

International Nuclear Information System (INIS)

Lambie, F.W.; Kendall, G.R.; Klahn, L.J.; Davis, J.C.; Harbaugh, J.W.

1980-12-01

The purpose of this project is to analyze the technique currently used by DOE to estimate intermediate grade uranium (0.01 to 0.05% U 3 O 8 ) and, if possible, suggest alternatives to improve the accuracy and precision of the estimate. There are three principal conclusions resulting from this study. They relate to the quantity, distribution and sampling of intermediate grade uranium. While the results of this study must be validated further, they indicate that DOE may be underestimating intermediate level reserves by 20 to 30%. Plots of grade of U 3 O 8 versus tonnage of ore and tonnage U 3 O 8 indicate grade-tonnage relationships that are essentially log-linear, at least down to 0.01% U 3 O 8 . Though this is not an unexpected finding, it may provide a technique for reducing the uncertainty of intermediate grade endowment. The results of this study indicate that a much lower drill hole density is necessary for DOE to estimate uranium resources than for a mining company to calculate ore resources. Though errors in local estimates will occur, they will tend to cancel over the entire deposit

Structure of replicating intermediates of human herpesvirus type 6

International Nuclear Information System (INIS)

Severini, Alberto; Sevenhuysen, Claire; Garbutt, Michael; Tipples, Graham A.

2003-01-01

We have studied the structure of the replicative intermediates of human herpesvirus 6 (HHV-6) using pulsed-field gel electrophoresis, partial digestion, two-dimensional gel electrophoresis, and sedimentation centrifugation. The results show that DNA replication of HHV-6 produces head-to-tail concatemeric intermediates as well as approximately equal amounts of circular monomers or oligomers. Unlike the situation in herpes simplex virus, the intermediates of human herpesvirus 6 replication are not highly branched, suggesting a difference in the mechanism of replication or a lower frequency of homologous recombination in human herpesvirus 6 compared to herpes simplex virus

Atmospheric fates of Criegee intermediates in the ozonolysis of isoprene.

Science.gov (United States)

Nguyen, Tran B; Tyndall, Geoffrey S; Crounse, John D; Teng, Alexander P; Bates, Kelvin H; Schwantes, Rebecca H; Coggon, Matthew M; Zhang, Li; Feiner, Philip; Milller, David O; Skog, Kate M; Rivera-Rios, Jean C; Dorris, Matthew; Olson, Kevin F; Koss, Abigail; Wild, Robert J; Brown, Steven S; Goldstein, Allen H; de Gouw, Joost A; Brune, William H; Keutsch, Frank N; Seinfeld, John H; Wennberg, Paul O

2016-04-21

We use a large laboratory, modeling, and field dataset to investigate the isoprene + O3 reaction, with the goal of better understanding the fates of the C1 and C4 Criegee intermediates in the atmosphere. Although ozonolysis can produce several distinct Criegee intermediates, the C1 stabilized Criegee (CH2OO, 61 ± 9%) is the only one observed to react bimolecularly. We suggest that the C4 Criegees have a low stabilization fraction and propose pathways for their decomposition. Both prompt and non-prompt reactions are important in the production of OH (28% ± 5%) and formaldehyde (81% ± 16%). The yields of unimolecular products (OH, formaldehyde, methacrolein (42 ± 6%) and methyl vinyl ketone (18 ± 6%)) are fairly insensitive to water, i.e., changes in yields in response to water vapor (≤4% absolute) are within the error of the analysis. We propose a comprehensive reaction mechanism that can be incorporated into atmospheric models, which reproduces laboratory data over a wide range of relative humidities. The mechanism proposes that CH2OO + H2O (k(H2O)∼ 1 × 10(-15) cm(3) molec(-1) s(-1)) yields 73% hydroxymethyl hydroperoxide (HMHP), 6% formaldehyde + H2O2, and 21% formic acid + H2O; and CH2OO + (H2O)2 (k(H2O)2∼ 1 × 10(-12) cm(3) molec(-1) s(-1)) yields 40% HMHP, 6% formaldehyde + H2O2, and 54% formic acid + H2O. Competitive rate determinations (kSO2/k(H2O)n=1,2∼ 2.2 (±0.3) × 10(4)) and field observations suggest that water vapor is a sink for greater than 98% of CH2OO in a Southeastern US forest, even during pollution episodes ([SO2] ∼ 10 ppb). The importance of the CH2OO + (H2O)n reaction is demonstrated by high HMHP mixing ratios observed over the forest canopy. We find that CH2OO does not substantially affect the lifetime of SO2 or HCOOH in the Southeast US, e.g., CH2OO + SO2 reaction is a minor contribution (production by stabilized Criegees is likely unimportant in regions dominated by the reactivity of ozone with isoprene. In contrast

Millennium scale radiocarbon variations in Eastern North Atlantic thermocline waters: 0-7000 years

Energy Technology Data Exchange (ETDEWEB)

Frank, N.; Tisnerat-Laborde, N.; Hatte, C. [LSCE, F-91190 Gif Sur Yvette, (France); Colin, C. [Univ Paris 11, IDES, Orsay, (France); Dottori, M.; Reverdin, G. [Univ Paris 06, LOCEAN, F-75252 Paris, (France)

2009-07-01

Complete text of publication follows: Deep water corals are exceptional archives of modern and past ocean circulation as combined U-series and radiocarbon dating allows to reconstruct seawater radiocarbon. Here we present thermocline water radiocarbon concentrations that have been reconstructed for the past {approx} 7000 years for the eastern north Atlantic, based on deep-water corals from Rockall Bank and Porcupine Seabight. We find that thermocline water radiocarbon values follow overall the mean atmospheric long term trend with an average offset of {Delta}{sup 14}C between intermediate water and atmosphere of -55{+-}5 per thousand until 1960 AD. Residual variations are strong ({+-}25 per thousand) over the past 7000 years and there is first evidence that those are synchronous to millennium scale climate variability. Over the past 60 years thermocline water radiocarbon values increase due to the penetration of bomb-radiocarbon into the upper intermediate ocean. Radiocarbon increases by {Delta}{sup 14}C of +95 per thousand compared to +210 per thousand for eastern North Atlantic surface waters. Moreover, bomb-radiocarbon penetration to thermocline depth occurs with a delay of {approx} 10-15 years. Based on high resolution ocean circulation models we suggest that radiocarbon changes at upper intermediate depth are today barely affected by vertical mixing and represent more likely variable advection and mixing of water masses from the Labrador Sea and the temperate Atlantic (including Mediterranean outflow water). Consequently, we assume that residual radiocarbon variations over the past 7000 years reflect millennium scale variability of the Atlantic sub-polar and sub-tropical gyres

Comparing Electrochemical and Biological Water Splitting

DEFF Research Database (Denmark)

Rossmeisl, Jan; Dimitrievski, Kristian; Siegbahn, P.

2007-01-01

On the basis of density functional theory calculations, we compare the free energies of key intermediates in the water splitting reaction over transition metal oxide surfaces to those of the Mn cluster in photo system II. In spite of the very different environments in the enzyme system and on the......On the basis of density functional theory calculations, we compare the free energies of key intermediates in the water splitting reaction over transition metal oxide surfaces to those of the Mn cluster in photo system II. In spite of the very different environments in the enzyme system...... and on the inorganic catalyst surface of an acidic electrolysis cell, the thermochemical features of the catalysts can be directly compared. We suggest a simple test for a thermochemically optimal catalyst. We show that, although both the RuO2 surface and the Mn cluster in photo system II are quite close to optimal...

Intermediate Collaborative Adaptive Management Strategies Build Stakeholder Capacity

Directory of Open Access Journals (Sweden)

Martha C. Monroe

2013-06-01

Full Text Available Efforts to implement collaborative adaptive management (CAM often suffer from challenges, such as an unwillingness of managers to share power, unresolved conflicts between stakeholders, and lack of capacity among stakeholders. Some aspects considered essential to CAM, e.g., trust and stakeholder capacity, may be more usefully viewed as goals for intermediate strategies rather than a set of initial conditions. From this perspective, intermediate steps that focus on social learning and building experience could overcome commonly cited barriers to CAM. An exploration of Springs Basin Working Groups, organized around major clusters of freshwater springs in north Florida, provides a case study of how these intermediate steps enable participants to become more reasonable and engaged. This strategy may be easily implemented by agencies beginning a CAM process.

Formation of intermediate shocks in both two-fluid and hybrid models

International Nuclear Information System (INIS)

Wu, C.C.; Hada, T.

1991-01-01

Intermediate shocks are shocks with shock frame fluid velocities greater than the Alfven speed ahead and less than the Alfven speed behind, or equivalently, across intermediate shocks the sign of the transverse component of the magnetic field changes. These shocks had been considered extraneous, or nonevolutionary, or unstable, and they had been thought not to correspond to physical reality [Germain, 1960; Jeffrey and Taniuti, 1964; Kantrowitz and Petschek, 1966]. However, it has been shown that intermediate shocks can be formed from continuous waves according to dissipative magnetohydrodynamics (MHD) [Wu, 1987, 1988a, b, 1990]. Thus according to the formation argument which requires that physical shocks be formed by the wave steepening process, the intermediate shocks should be considered physical. Here, intermediate shocks are studied in a two-fluid model that includes finite ion inertia dispersion and in a hybrid model in which the full ion dynamics is retained while the electrons are treated as a massless fluid. The authors show that in both models intermediate shocks can be formed through wave steepening, meaning that they are stable and possess shock structures

Quantum Chemical Investigation of the Transition States and Intermediates for the Reaction of the Nitrosonium Ion with the Pentaammineazidocobalt(III) Ion.

Science.gov (United States)

Rotzinger, François P

2016-12-19

The water exchange reaction on Co(NH 3 ) 5 OH 2 3+ was investigated with various density functionals and basis sets. A Gibbs activation energy (ΔG ⧧ ) agreeing with experiment was obtained with the long-range-corrected functionals ωB97X-D3 and LC-BOP-LRD, SMD hydration, and modified Karlsruhe def2-TZVP basis sets. This computational technique was then applied to the reaction of NO + with Co(NH 3 ) 5 N 3 2+ . All of the possible pathways were investigated, NO + attack at the terminal N of Co(NH 3 ) 5 N 3 2+ via the E and the Z isomers of the transition states, and NO + attack at the bound N of azide, also via both isomers. The most favorable pathway proceeds via the attack at the bound N via the Z isomer. This leads to the intermediate with an oxatetrazole ligand bound to Co(III) at the N in the 3-position, Co(NH 3 ) 5 (cycl-N 4 O) 3+ , which undergoes N 2 elimination to yield the Co(NH 3 ) 5 N 2 O 3+ intermediate. The subsequent substitution of N 2 O by water follows the I d mechanism with retention of the configuration. No evidence for the existence of the square-pyramidal pentacoordinated intermediate Co(NH 3 ) 5 3+ was found. All of the investigated intermediates, Co(NH 3 ) 5 N 2 3+ , Co(NH 3 ) 5 [E-N(N 2 )(NO)] 3+ , Co(NH 3 ) 5 (E-ON 4 ) 3+ , Co(NH 3 ) 5 ON 2 3+ , Co(NH 3 ) 5 (cycl-N 4 O) 3+ , and Co(NH 3 ) 5 N 2 O 3+ , exhibit short lifetimes of less than ∼60 μs and react via the I d mechanism.

A new intermediate for the production of flexible stable polymers

Science.gov (United States)

Webster, J. A.

1973-01-01

Method of incorporating ether linkages into perfluoroalkylene segment of a dianydride intermediate yields intermediate that may be used in synthesis of flexible, stable polyimides for use as high-temperature, solvent-resistant sealants.

Is light water reactor technology sustainable?

International Nuclear Information System (INIS)

Rothwell, G.; Van der Zwaan, B.

2001-01-01

This paper proposes criteria for determining ''intermediate sustainability'' over a 500-year horizon. We apply these criteria to Light Water Reactor (LWR) technology and the LWR industry. We conclude that LWR technology does not violate intermediate sustainability criteria for (1) environmental externalities, (2) worker and public health and safety, or (3) accidental radioactive release. However, it does not meet criteria to (1) efficiently use depleted uranium and (2) avoid uranium enrichment technologies that can lead to nuclear weapons proliferation. Finally, current and future global demand for LWR technology might be below the minimum needed to sustain the current global LWR industry. (author)

Late Holocene Radiocarbon Variability in Northwest Atlantic Slope Waters

Energy Technology Data Exchange (ETDEWEB)

Sherwood, O; Edinger, E; Guilderson, T P; Ghaleb, B; Risk, M J; Scott, D B

2008-08-15

Deep-sea gorgonian corals secrete a 2-part skeleton of calcite, derived from dissolved inorganic carbon at depth, and gorgonin, derived from recently fixed and exported particulate organic matter. Radiocarbon contents of the calcite and gorgonin provide direct measures of seawater radiocarbon at depth and in the overlying surface waters, respectively. Using specimens collected from Northwest Atlantic slope waters, we generated radiocarbon records for surface and upper intermediate water layers spanning the pre- and post bomb-{sup 14}C eras. In Labrador Slope Water (LSW), convective mixing homogenizes the pre-bomb {Delta}{sup 14}C signature (-67 {+-} 4{per_thousand}) to at least 1000 m depth. Surface water bomb-{sup 14}C signals were lagged and damped (peaking at {approx} +45{per_thousand} in the early 1980s) relative to other regions of the northwest Atlantic, and intermediate water signals were damped further. Off southwest Nova Scotia, the vertical gradient in {Delta}{sup 14}C is much stronger. In surface water, pre-bomb {Delta}{sup 14}C averaged -75 {+-} 5{per_thousand}. At 250-475 m depth, prebomb {Delta}{sup 14}C oscillated quasi-decadally between -80 and -100{per_thousand}, likely reflecting interannual variability in the presence of Labrador Slope Water vs. Warm Slope Water (WSW). Finally, subfossil corals reveal no systematic changes in vertical {Delta}{sup 14}C gradients over the last 1200 years.

Intermediate heat exchanger for HTR process heat application

International Nuclear Information System (INIS)

Crambes, M.

1980-01-01

In the French study on the nuclear gasification of coal, the following options were recommended: Coal hydrogenation, the hydrogen being derived from CH 4 reforming under the effects of HTR heat; the use of an intermediate helium circuit between the nuclear plant and the reforming plant. The purpose of the present paper is to describe the heat exchanger designed to transfer heat from the primary to the intermediate circuit

Shelf stable intermediate moisture fruit cubes using radiation technology

International Nuclear Information System (INIS)

Mishra, Bibhuti B.; Saxena, Sudhanshu; Gautam, Satyendra; Chander, Ramesh; Sharma, Arun

2009-01-01

A process has been developed to prepare shelf stable ready-to-eat (RTE) intermediate moisture pineapple slices and papaya cubes using radiation technology. The combination of hurdles including osmotic dehydration, blanching, infrared drying, and gamma radiation dose of 1 kGy successfully reduced the microbial load to below detectable limit. The shelf life of the intermediate moisture pineapple slices and papaya cubes was found to be 40 days at ambient temperature (28 ± 2 deg C). The control samples spoiled within 6 days. The RTE intermediate moisture fruit products were found to have good texture, colour and sensory acceptability during this 40 days storage. (author)

Material Voices: Intermediality and Autism

Science.gov (United States)

Trimingham, Melissa; Shaughnessy, Nicola

2016-01-01

Autism continues to be regarded enigmatically; a community that is difficult to access due to perceived disruptions of interpersonal connectedness. Through detailed observations of two children participating in the Arts and Humanities Research Council funded project "Imagining Autism: Drama, Performance and Intermediality as Interventions for…

Insignificant disease among men with intermediate-risk prostate cancer.

Science.gov (United States)

Hong, Sung Kyu; Vertosick, Emily; Sjoberg, Daniel D; Scardino, Peter T; Eastham, James A

2014-12-01

A paucity of data exists on the insignificant disease potentially suitable for active surveillance (AS) among men with intermediate-risk prostate cancer (PCa). We tried to identify pathologically insignificant disease and its preoperative predictors in men who underwent radical prostatectomy (RP) for intermediate-risk PCa. We analyzed data of 1,630 men who underwent RP for intermediate-risk disease. Total tumor volume (TTV) data were available in 332 men. We examined factors associated with classically defined pathologically insignificant cancer (organ-confined disease with TTV ≤0.5 ml with no Gleason pattern 4 or 5) and pathologically favorable cancer (organ-confined disease with no Gleason pattern 4 or 5) potentially suitable for AS. Decision curve analysis was used to assess clinical utility of a multivariable model including preoperative variables for predicting pathologically unfavorable cancer. In the entire cohort, 221 of 1,630 (13.6 %) total patients had pathologically favorable cancer. Among 332 patients with TTV data available, 26 (7.8 %) had classically defined pathologically insignificant cancer. Between threshold probabilities of 20 and 40 %, decision curve analysis demonstrated that using multivariable model to identify AS candidates would not provide any benefit over simply treating all men who have intermediate-risk disease with RP. Although a minority of patients with intermediate-risk disease may harbor pathologically favorable or insignificant cancer, currently available conventional tools are not sufficiently able to identify those patients.

Prediction and assessment of environmental impacts of Guangdong low-and-intermediate level radioactive waste disposal site

International Nuclear Information System (INIS)

Huang Yawen

1996-01-01

Guangdong Low-and Intermediate Level Radioactive Waste Disposal Site is located 5-7 km northeast to the Daya Bay Nuclear Power Plant. It is in a hilly area with strongly weathered light metamorphic quartz siltstone. The groundwater is 2 m below the repository bottom. The disposal unit is a U-shape concrete structure with drainage and water collecting system at the bottom. The designed cover is a multi-layer structure with functions of preventing from water infiltration, animal and plant intrusion. It is assumed that the engineered barriers would be effective to avoid waste immersion by surface water and groundwater within the first 100 years after closure. After 100 years, the engineered barriers would fail gradually. Radionuclides may release from the disposal unite. Some will enter the nearby stream, some will flow into the Daya Bay, and some will transport to groundwater through geologic media

Multifragmentation in intermediate energy heavy ion collisions

International Nuclear Information System (INIS)

Jacak, B.V.; Britt, H.C.; Claesson, G.

1986-01-01

There has been considerable recent interest in the production of intermediate mass fragments (A > 4) in intermediate and high energy nucleus-nucleus collisions. The mechanism for production of these fragments is not well understood and has been described by models employing a variety of assumptions. Some examples are: disassembly of a system in thermal equilibrium into nucleons and nuclear fragments, liquid-vapor phase transitions in nuclear matter, final state coalescence of nucleons and dynamical correlations between nucleons at breakup. Previous studies of fragment production, with one exception, have been single particle inclusive measurements; the observed fragment mass (or charge) distributions can be described by all of the models above. To gain insight into the fragment production mechanism, the authors used the GSI/LBL Plastic Ball detector system to get full azimuthal coverage for intermediate mass fragments in the forward hemisphere in the center of mass system while measuring all the light particles in each event. The authors studied the systems 200 MeV/nucleon Au + Au and Au + Fe

Thermogravimetric control of intermediate compounds in uranium metallurgy

International Nuclear Information System (INIS)

Gasco Sanchez, L.; Fernandez Cellini, R.

1959-01-01

The thermal decomposition of some intermediate compounds in the metallurgy of the uranium as uranium peroxide, ammonium uranate, uranium and ammonium penta-fluoride, uranium tetrafluoride and uranous oxide has been study by means of the Chevenard's thermo balance. Some data on pyrolysis of synthetic mixtures of intermediate compounds which may occasionally appear during the industrial process, are given. Thermogravimetric methods of control are suggested, usable in interesting products in the uranium metallurgy. (Author) 20 refs

Intermediate-energy neutron beams from reactors for NCT

International Nuclear Information System (INIS)

Brugger, R.M.; Less, T.J.; Passmore, G.G.

1986-01-01

This paper discusses ways that a beam of intermediate-energy neutrons might be extracted from a nuclear reactor. The challenge is to suppress the fast-neutron component and the gamma-ray component of the flux while leaving enough of the intermediate-energy neutrons in the beam to be able to perform neutron capture therapy in less than an hour exposure time. Moderators, filters, and reflectors are considered. 11 references, 7 figures, 3 tables

Larval helminths in intermediate hosts

DEFF Research Database (Denmark)

Fredensborg, Brian Lund; Poulin, R

2005-01-01

Density-dependent effects on parasite fitness have been documented from adult helminths in their definitive hosts. There have, however, been no studies on the cost of sharing an intermediate host with other parasites in terms of reduced adult parasite fecundity. Even if larval parasites suffer a ...

Intermediate/Advanced Research Design and Statistics

Science.gov (United States)

Ploutz-Snyder, Robert

2009-01-01

The purpose of this module is To provide Institutional Researchers (IRs) with an understanding of the principles of advanced research design and the intermediate/advanced statistical procedures consistent with such designs

Thin-film intermediate band chalcopyrite solar cells

International Nuclear Information System (INIS)

Fuertes Marron, D.; Marti, A.; Luque, A.

2009-01-01

Chalcopyrite-based solar cells currently lead the efficiency tables of thin-film photovoltaic technologies. Further improvements are foreseen upon implementation of an intermediate band in the absorber layers. We present a theoretical analysis of the efficiency limit for this type of device as a function of factors such as the gap of the host, the relative position of the intermediate band with respect to the band edge and the level of light concentration used as illumination. We have also considered the impact of non-idealities on the performance of the device, particularly the effect of electronic losses related to non-radiative recombination

Top predators induce the evolutionary diversification of intermediate predator species.

Science.gov (United States)

Zu, Jian; Yuan, Bo; Du, Jianqiang

2015-12-21

We analyze the evolutionary branching phenomenon of intermediate predator species in a tritrophic food chain model by using adaptive dynamics theory. Specifically, we consider the adaptive diversification of an intermediate predator species that feeds on a prey species and is fed upon by a top predator species. We assume that the intermediate predator׳s ability to forage on the prey can adaptively improve, but this comes at the cost of decreased defense ability against the top predator. First, we identify the general properties of trade-off relationships that lead to a continuously stable strategy or to evolutionary branching in the intermediate predator species. We find that if there is an accelerating cost near the singular strategy, then that strategy is continuously stable. In contrast, if there is a mildly decelerating cost near the singular strategy, then that strategy may be an evolutionary branching point. Second, we find that after branching has occurred, depending on the specific shape and strength of the trade-off relationship, the intermediate predator species may reach an evolutionarily stable dimorphism or one of the two resultant predator lineages goes extinct. Crown Copyright © 2015. Published by Elsevier Ltd. All rights reserved.

Conditioning of intermediate-level waste at Forschungszentrum Juelich GmbH

International Nuclear Information System (INIS)

Krumbach, H.

2003-01-01

This contribution to the group of low-level, intermediate, mixed and hazardous waste describes the conditioning of intermediate-level mixed waste (dose rate above 10 mSv/h at the surface) from Research Centre Juelich (FZJ). Conditioning of the waste by supercompaction is performed at Research Centre Karlsruhe (FZK). The waste described is radioactive waste arising from research at Juelich. This waste includes specimens and objects from irradiation experiments in the research reactors Merlin (FRJ-1) and Dido (FRJ-2) at FZJ. In principle, radioactive waste at Forschungszentrum Juelich GmbH is differentiated by the surface dose rate at the waste package. Up to a surface dose rate of 10 mSv/h, the waste is regarded as low-level. The radioactive waste described here has a surface dose rate above 10 mSv/h. Waste up to 10 mSv/h is conditioned at the Juelich site according to different conditioning methods. The intermediate-level waste can only be conditioned by supercompaction in the processing facility for intermediate-level waste from plant operation at Research Centre Karlsruhe. Research Centre Juelich also uses this waste cell to condition its intermediate-level waste from plant operation. (orig.)

Cryo-EM structures of two bovine adenovirus type 3 intermediates

International Nuclear Information System (INIS)

Cheng, Lingpeng; Huang, Xiaoxing; Li, Xiaomin; Xiong, Wei; Sun, Wei; Yang, Chongwen; Zhang, Kai; Wang, Ying; Liu, Hongrong; Huang, Xiaojun; Ji, Gang; Sun, Fei; Zheng, Congyi; Zhu, Ping

2014-01-01

Adenoviruses (Ads) infect hosts from all vertebrate species and have been investigated as vaccine vectors. We report here near-atomic structures of two bovine Ad type 3 (BAd3) intermediates obtained by cryo-electron microscopy. A comparison between the two intermediate structures reveals that the differences are localized in the fivefold vertex region, while their facet structures are identical. The overall facet structure of BAd3 exhibits a similar structure to human Ads; however, BAd3 protein IX has a unique conformation. Mass spectrometry and cryo-electron tomography analyses indicate that one intermediate structure represents the stage during DNA encapsidation, whilst the other intermediate structure represents a later stage. These results also suggest that cleavage of precursor protein VI occurs during, rather than after, the DNA encapsidation process. Overall, our results provide insights into the mechanism of Ad assembly, and allow the first structural comparison between human and nonhuman Ads at backbone level. - Highlights: • First structure of bovine adenovirus type 3. • Some channels are located at the vertex of intermediate during DNA encapsidation. • Protein IX exhibits a unique conformation of trimeric coiled–coiled structure. • Cleavage of precursor protein VI occurs during the DNA encapsidation process

Intermediate Filaments at the Junction of Mechanotransduction, Migration, and Development

Directory of Open Access Journals (Sweden)

Rucha Sanghvi-Shah

2017-09-01

Full Text Available Mechanically induced signal transduction has an essential role in development. Cells actively transduce and respond to mechanical signals and their internal architecture must manage the associated forces while also being dynamically responsive. With unique assembly-disassembly dynamics and physical properties, cytoplasmic intermediate filaments play an important role in regulating cell shape and mechanical integrity. While this function has been recognized and appreciated for more than 30 years, continually emerging data also demonstrate important roles of intermediate filaments in cell signal transduction. In this review, with a particular focus on keratins and vimentin, the relationship between the physical state of intermediate filaments and their role in mechanotransduction signaling is illustrated through a survey of current literature. Association with adhesion receptors such as cadherins and integrins provides a critical interface through which intermediate filaments are exposed to forces from a cell's environment. As a consequence, these cytoskeletal networks are posttranslationally modified, remodeled and reorganized with direct impacts on local signal transduction events and cell migratory behaviors important to development. We propose that intermediate filaments provide an opportune platform for cells to both cope with mechanical forces and modulate signal transduction.

Cryo-EM structures of two bovine adenovirus type 3 intermediates

Energy Technology Data Exchange (ETDEWEB)

Cheng, Lingpeng; Huang, Xiaoxing; Li, Xiaomin [National Laboratory of Biomacromolecules, Institute of Biophysics, Chinese Academy of Sciences, Beijing 100101 (China); Xiong, Wei [State Key Laboratory of Virology, College of Life Sciences, Wuhan University, Luo-jia-shan, Wuhan, Hubei 430072 (China); Sun, Wei; Yang, Chongwen; Zhang, Kai; Wang, Ying [National Laboratory of Biomacromolecules, Institute of Biophysics, Chinese Academy of Sciences, Beijing 100101 (China); Liu, Hongrong [College of Physics and Information Science, Hunan Normal University, Changsha, Hunan 410081 (China); Huang, Xiaojun; Ji, Gang; Sun, Fei [National Laboratory of Biomacromolecules, Institute of Biophysics, Chinese Academy of Sciences, Beijing 100101 (China); Zheng, Congyi, E-mail: cctcc202@whu.edu.cn [State Key Laboratory of Virology, College of Life Sciences, Wuhan University, Luo-jia-shan, Wuhan, Hubei 430072 (China); Zhu, Ping, E-mail: zhup@ibp.ac.cn [National Laboratory of Biomacromolecules, Institute of Biophysics, Chinese Academy of Sciences, Beijing 100101 (China)

2014-02-15

Adenoviruses (Ads) infect hosts from all vertebrate species and have been investigated as vaccine vectors. We report here near-atomic structures of two bovine Ad type 3 (BAd3) intermediates obtained by cryo-electron microscopy. A comparison between the two intermediate structures reveals that the differences are localized in the fivefold vertex region, while their facet structures are identical. The overall facet structure of BAd3 exhibits a similar structure to human Ads; however, BAd3 protein IX has a unique conformation. Mass spectrometry and cryo-electron tomography analyses indicate that one intermediate structure represents the stage during DNA encapsidation, whilst the other intermediate structure represents a later stage. These results also suggest that cleavage of precursor protein VI occurs during, rather than after, the DNA encapsidation process. Overall, our results provide insights into the mechanism of Ad assembly, and allow the first structural comparison between human and nonhuman Ads at backbone level. - Highlights: • First structure of bovine adenovirus type 3. • Some channels are located at the vertex of intermediate during DNA encapsidation. • Protein IX exhibits a unique conformation of trimeric coiled–coiled structure. • Cleavage of precursor protein VI occurs during the DNA encapsidation process.

A Phosphate Minimum in the Oxygen Minimum Zone (OMZ) off Peru

Science.gov (United States)

Paulmier, A.; Giraud, M.; Sudre, J.; Jonca, J.; Leon, V.; Moron, O.; Dewitte, B.; Lavik, G.; Grasse, P.; Frank, M.; Stramma, L.; Garcon, V.

2016-02-01

The Oxygen Minimum Zone (OMZ) off Peru is known to be associated with the advection of Equatorial SubSurface Waters (ESSW), rich in nutrients and poor in oxygen, through the Peru-Chile UnderCurrent (PCUC), but this circulation remains to be refined within the OMZ. During the Pelágico cruise in November-December 2010, measurements of phosphate revealed the presence of a phosphate minimum (Pmin) in various hydrographic stations, which could not be explained so far and could be associated with a specific water mass. This Pmin, localized at a relatively constant layer ( 20minimum with a mean vertical phosphate decrease of 0.6 µM but highly variable between 0.1 and 2.2 µM. In average, these Pmin are associated with a predominant mixing of SubTropical Under- and Surface Waters (STUW and STSW: 20 and 40%, respectively) within ESSW ( 25%), complemented evenly by overlying (ESW, TSW: 8%) and underlying waters (AAIW, SPDW: 7%). The hypotheses and mechanisms leading to the Pmin formation in the OMZ are further explored and discussed, considering the physical regional contribution associated with various circulation pathways ventilating the OMZ and the local biogeochemical contribution including the potential diazotrophic activity.

Immobilization of low and intermediate level radioactive liquid wastes using some industrial by-product materials

International Nuclear Information System (INIS)

Sami, N.M.; EI-Dessouky, M.I.; Abou EI-Nour, F.H.; Abdel-Khalik, M.

2006-01-01

Immobilization of low and intermediate level.radioactive liquid wastes in different matrices: ordinary Portland cement and cement mixed with some industrial byproduct: by-pass kiln cement dust, blast furnace slag and ceramic sludge was studied. The effect of these industrial by-product materials on the compressive strength, water immersion, radiation effect and teachability were investigated. The obtained results showed that, these industrial by-product improve the cement pastes where they increase the compressive strength, decrease the leaching rate for radioactive cesium-137 and cobalt-60 ions through the solidified waste forms and increase resistance for y-radiation. It is found that, solidified waste forms of intermediate level liquid waste (ILLW) had high compressive strength values more than those obtained from low level liquid waste (LLLW). The compressive strength increased after immersion in different leachant for one and three months for samples with LLLW higher than those obtained for ILLW. The cumulative fractions released of cesium-137 and cobalt-60 of solidified waste forms of LLLW was lower than those obtained for ILLW

Singlet channel coupling in deuteron elastic scattering at intermediate energies

International Nuclear Information System (INIS)

Al-Khalili, J.S.; Tostevin, J.A.; Johnson, R.C.

1990-01-01

Intermediate energy deuteron elastic scattering is investigated in a three-body model incorporating relativistic kinematics. The effects of deuteron breakup to singlet spin intermediate states, on the elastic scattering observables for the 58 Ni(d vector, d) 58 Ni reaction at 400 and 700 MeV, are studied quantitatively. The singlet-breakup contributions to the elastic amplitude are estimated within an approximate two-step calculation. The calculation makes an adiabatic approximation in the intermediate states propagator which allows the use of closure over the np intermediate states continuum. The singlet channel coupling is found to produce large effects on the calculated reaction tensor analysing power A yy , characteristic of a dynamically induced second-rank tensor interaction. By inspection of the calculated breakup amplitudes we show this induced interaction to be of the T L tensor type. (orig.)

"Affective Encounters": Live Intermedial Spaces in Sites of Trauma

Science.gov (United States)

Scott, Jo

2016-01-01

This article addresses live intermediality as a tool for creative learning in the context of workshops carried out with young people in the town of Terezin, in the Czech Republic, site of the Nazi concentration camp, Theresienstadt. Live intermediality, as a mode of live media practice, involves the real time mixing and merging of sound, image,…

Drinking-water monitoring systems

International Nuclear Information System (INIS)

1994-01-01

A new measuring system was developed by the Austrian Research Centre Seibersdorf for monitoring the quality of drinking-water. It is based on the experience made with the installation of UWEDAT (registered trademark) environmental monitoring networks in several Austrian provinces and regions. The standard version of the drinking-water monitoring system comprises sensors for measuring chemical parameters in water, radioactivity in water and air, and meteorological values of the environment. Further measuring gauges, e.g. for air pollutants, can be connected at any time, according to customers' requirements. For integration into regional and supraregional networks, station computers take over the following tasks: Collection of data and status signals transmitted by the subsystem, object protection, intermediate storage and communication of data to the host or several subcentres via Datex-P postal service, permanent lines or radiotransmission

Physiological response of selected eragrostis species to water ...

African Journals Online (AJOL)

Administrator

2011-09-07

Sep 7, 2011 ... Department of Molecular and Cell Biology, University of Cape Town, Private Bag, .... respiration measurements were taken at night (20:00 h). .... Cellular ultrastructure .... these in place, to be held at intermediate water contents.

Oxidative demethylation of lanosterol in cholesterol biosynthesis: accumulation of sterol intermediates

International Nuclear Information System (INIS)

Shafiee, A.; Trzaskos, J.M.; Paik, Y.K.; Gaylor, J.L.

1986-01-01

With [ 3 H-24,25]-dihydrolanosterol as substrate, large-scale metabolic formation of intermediates of lanosterol demethylation was carried out to identify all compounds in the metabolic process. Utilizing knowledge of electron transport of lanosterol demethylation, we interrupted the demethylation reaction allowing accumulation and confirmation of the structure of the oxygenated intermediates lanost-8-en-3 beta,32-diol and 3 beta-hydroxylanost-8-en-32-al, as well as the demethylation product 4,4-dimethyl-cholesta-8,14-dien-3 beta-ol. Further metabolism of the delta 8.14-diene intermediate to a single product 4,4-dimethyl-cholest-8-en-3 beta-ol occurs under interruption conditions in the presence of 0.5 mM CN-1. With authentic compounds, each intermediate has been rigorously characterized by high performance liquid chromatography and gas-liquid chromatography plus mass spectral analysis of isolated and derivatized sterols. Intermediates that accumulated in greater abundance were further characterized by ultraviolet, 1 H-NMR, and infrared spectroscopy of the isolated sterols

About the investigation of the ultrasonic absorption in intermediate states of superconductors

International Nuclear Information System (INIS)

Shepelev, A.G.

2003-01-01

Investigation of intermediate state in the bulk of superconductors are surveyed. Consideration is given to a previous attempt of eliminating edge effects in the ultrasonic investigation of intermediate states of pure gallium and molybdenum;it is demonstrated that those results are in strong contradiction with Landau's intermediate-state theory

Identification of combustion intermediates in low-pressure premixed pyridine/oxygen/argon flames.

Science.gov (United States)

Tian, Zhenyu; Li, Yuyang; Zhang, Taichang; Zhu, Aiguo; Qi, Fei

2008-12-25

Combustion intermediates of two low-pressure premixed pyridine/oxygen flames with respective equivalence ratios of 0.56 (C/O/N = 1:4.83:0.20) and 2.10 (C/O/N = 1:1.29:0.20) have been identified with tunable synchrotron vacuum ultraviolet (VUV) photoionization and molecular-beam mass spectrometry techniques. About 80 intermediates in the rich flame and 60 intermediates in the lean flame, including nitrogenous, oxygenated, and hydrocarbon intermediates, have been identified by measurements of photoionization mass spectra and photoionization efficiency spectra. Some radicals and new nitrogenous intermediates are identified in the present work. The experimental results are useful for studying the conversion of volatile nitrogen compounds and understanding the formation mechanism of NO(x) in flames of nitrogenous fuels.

Ab initio results for intermediate-mass, open-shell nuclei

Science.gov (United States)

Baker, Robert B.; Dytrych, Tomas; Launey, Kristina D.; Draayer, Jerry P.

2017-01-01

A theoretical understanding of nuclei in the intermediate-mass region is vital to astrophysical models, especially for nucleosynthesis. Here, we employ the ab initio symmetry-adapted no-core shell model (SA-NCSM) in an effort to push first-principle calculations across the sd-shell region. The ab initio SA-NCSM's advantages come from its ability to control the growth of model spaces by including only physically relevant subspaces, which allows us to explore ultra-large model spaces beyond the reach of other methods. We report on calculations for 19Ne and 20Ne up through 13 harmonic oscillator shells using realistic interactions and discuss the underlying structure as well as implications for various astrophysical reactions. This work was supported by the U.S. NSF (OCI-0904874 and ACI -1516338) and the U.S. DOE (DE-SC0005248), and also benefitted from the Blue Waters sustained-petascale computing project and high performance computing resources provided by LSU.

Disposal of high level and intermediate level radioactive wastes

International Nuclear Information System (INIS)

Flowers, R.H.

1991-01-01

The waste products from the nuclear industry are relatively small in volume. Apart from a few minor gaseous and liquid waste streams, containing readily dispersible elements of low radiotoxicity, all these products are processed into stable solid packages for disposal in underground repositories. Because the volumes are small, and because radioactive wastes are latecomers on the industrial scene, a whole new industry with a world-wide technological infrastructure has grown up alongside the nuclear power industry to carry out the waste processing and disposal to very high standards. Some of the technical approaches used, and the Regulatory controls which have been developed, will undoubtedly find application in the future to the management of non-radioactive toxic wastes. The repository site outlined would contain even high-level radioactive wastes and spent fuels being contained without significant radiation dose rates to the public. Water pathway dose rates are likely to be lowest for vitrified high-level wastes with spent PWR fuel and intermediate level wastes being somewhat higher. (author)

Seasonal and Spatial Environmental Influence on Opisthorchis viverrini Intermediate Hosts, Abundance, and Distribution: Insights on Transmission Dynamics and Sustainable Control.

Directory of Open Access Journals (Sweden)

Christina Sunyoung Kim

2016-11-01

Full Text Available Opisthorchis viverrini (Ov is a complex-life-cycle trematode affecting 10 million people in SEA (Southeast Asia. Human infection occurs when infected cyprinid fish are consumed raw or undercooked. Ov requires three hosts and presents two free-living parasitic stages. As a consequence Ov transmission and infection in intermediate and human hosts are strongly mediated by environmental factors and understanding how environmental variability influences intermediate host abundance is critical. The objectives of this study were 1 to document water parameters, intermediate hosts abundance and infection spatio-temporal variation, 2 to assess their causal relationships and identify windows of transmission risk.Fish and snails were collected monthly for one year at 12 sites in Lawa Lake, an Ov-endemic region of Khon Kaen Province in Northeast Thailand. Physicochemical water parameters [pH, temperature (Tp, dissolved oxygen (DO, Salinity, electrical conductivity (EC, total dissolved solid (TDS, nitrite nitrogen (NO2-N, lead (Pb, total coliform bacteria (TCB and fecal coliform bacteria (FCB] were measured. Multivariate analyses, linear models and kriging were used to characterize water parameter variation and its influence on host abundance and infection prevalence. We found that sampling sites could be grouped in three clusters and discriminated along a nitrogen-salinity gradient where higher levels in the lake's southern region predicted higher Bithynia relative abundance (P<0.05 and lower snail and fish species diversity (P<0.05. Highest Bithynia abundance occurred during rainy season (P<0.001, independently of site influence. Cyprinids were the most abundant fish family and higher cyprinid relative abundance was found in areas with higher Bithynia relative abundance (P<0.05. Ov infection in snails was anecdotal while Ov infection in fish was higher in the southern region (P<0.001 at sites showing high FCB.Our results indicate that water contamination

Ground-water hydrology and simulation of ground-water flow at Operable Unit 3 and surrounding region, U.S. Naval Air Station, Jacksonville, Florida

Science.gov (United States)

Davis, J.H.

1998-01-01

The Naval Air Station, Jacksonville (herein referred to as the Station), occupies 3,800 acres adjacent to the St. Johns River in Duval County, Florida. Operable Unit 3 (OU3) occupies 134 acres on the eastern side of the Station and has been used for industrial and commercial purposes since World War II. Ground water contaminated by chlorinated organic compounds has been detected in the surficial aquifer at OU3. The U.S. Navy and U.S. Geological Survey (USGS) conducted a cooperative hydrologic study to evaluate the potential for ground water discharge to the neighboring St. Johns River. A ground-water flow model, previously developed for the area, was recalibrated for use in this study. At the Station, the surficial aquifer is exposed at land surface and forms the uppermost permeable unit. The aquifer ranges in thickness from 30 to 100 feet and consists of unconsolidated silty sands interbedded with local beds of clay. The low-permeability clays of the Hawthorn Group form the base of the aquifer. The USGS previously conducted a ground-water investigation at the Station that included the development and calibration of a 1-layer regional ground-water flow model. For this investigation, the regional model was recalibrated using additional data collected after the original calibration. The recalibrated model was then used to establish the boundaries for a smaller subregional model roughly centered on OU3. Within the subregional model, the surficial aquifer is composed of distinct upper and intermediate layers. The upper layer extends from land surface to a depth of approximately 15 feet below sea level; the intermediate layer extends from the upper layer down to the top of the Hawthorn Group. In the northern and central parts of OU3, the upper and intermediate layers are separated by a low-permeability clay layer. Horizontal hydraulic conductivities in the upper layer, determined from aquifer tests, range from 0.19 to 3.8 feet per day. The horizontal hydraulic

Hγ Line Spectrum of Intermediate Polars

Directory of Open Access Journals (Sweden)

Yonggi Kim

1998-06-01

Full Text Available Kim & Beuermann (1995, 1996 have developed a model for the propagation of X-rays from the accreting white dwarf through the infalling material and the re-emission of the energy deposited by photo-absorption in the optical (and UV spectral range. By using this model, we calculate the profiles of the Hγ emission-line spectrum of intermediate polars. Photoabsorption of X-rays by the infalling material is the dominant process in forming the observed energy-dependent rotational modulation of the X-ray flux. X-ray and optical modulations are sensitive to model parameters in different ways. In principle, these dependencies allow us to obtain improved insight into the accretion geometry of the intermediate polars. We present results of our calculations and compare them with the Hβ line spectrum (Kim & Beuermann 1996.

Is light water reactor technology sustainable?

Energy Technology Data Exchange (ETDEWEB)

Rothwell, G. [Stanford Univ., Dept. of Economics, CA (United States); Van der Zwaan, B. [Vrije Univ., Amsterdam, Inst. for Environmental Studies (Netherlands)

2001-07-01

This paper proposes criteria for determining ''intermediate sustainability'' over a 500-year horizon. We apply these criteria to Light Water Reactor (LWR) technology and the LWR industry. We conclude that LWR technology does not violate intermediate sustainability criteria for (1) environmental externalities, (2) worker and public health and safety, or (3) accidental radioactive release. However, it does not meet criteria to (1) efficiently use depleted uranium and (2) avoid uranium enrichment technologies that can lead to nuclear weapons proliferation. Finally, current and future global demand for LWR technology might be below the minimum needed to sustain the current global LWR industry. (author)

Nuclear spin-orbit splitting from an intermediate Δ excitation

International Nuclear Information System (INIS)

Ohta, K.; Terasawa, T.; Tohyama, M.

1980-01-01

The strength of the single particle spin-orbit potential is calculated from the two pion exchange box diagrams involving an intermediate Δ(1232) resonance excitation by taking account of the exclusion principle for the intermediate nucleon states. The effect of the rho meson is also considered. The predicted strength is found to account for a substantial part of the empirical spin-orbit splittings

42 CFR 422.750 - Types of intermediate sanctions and civil money penalties.

Science.gov (United States)

2010-10-01

... 42 Public Health 3 2010-10-01 2010-10-01 false Types of intermediate sanctions and civil money... § 422.750 Types of intermediate sanctions and civil money penalties. (a) The following intermediate... organization. (b) CMS may impose civil money penalties as specified in 422.760. [72 FR 68725, Dec. 5, 2007, as...

Microdosimetry of intermediate energy neutrons in fast neutron fields

International Nuclear Information System (INIS)

Saion, E.B.; Watt, D.E.

1988-01-01

A coaxial double cylindrical proportional counter has been constructed for microdosimetry of intermediate energy neutrons in mixed fields. Details are given of the measured gas gain and resolution characteristics of the counter for a wide range of anode voltages. Event spectra due to intermediate neutrons in any desired energy band is achieved by an appropriate choice of thickness of the common dividing wall in the counter and by appropriate use of the coincidence, anticoincidence pulse counting arrangements. Calculated estimates indicate that the dose contribution by fast neutrons to the energy deposition events in the intermediate neutron range may be as large as 25%. Empirical procedures being investigated aim to determine the necessary corrections to be applied to the microdose distributions, with a precision of 10%. (author)

About the structure of quantum intermediate state of superconductors

International Nuclear Information System (INIS)

Ledenev, O.P.

2008-01-01

The calculation of spatial structure of a quantum intermediate state in Type I superconductors is completed. Theoretical model of thermodynamics of considered state was proposed by Andreev. It is shown, that in a quantum case, the period of structure appears significantly smaller and has different dependence on both the magnetic field and temperature than in the classical intermediate Landau state. The decrease of thickness of normal layers results in increase of characteristic distance between the quantum Andreev levels of electronic excitations, and the transition to the quantum intermediate from classical state is realized at higher temperatures ∼1 K, than it was supposed in previous works. The comparison of calculation data with experimental results, for example using the sample of mono-crystal gallium, is conducted

Negotiating comfort in low energy housing: The politics of intermediation

International Nuclear Information System (INIS)

Grandclément, Catherine; Karvonen, Andrew; Guy, Simon

2015-01-01

Optimising the energy performance of buildings is technically and economically challenging but it also has significant social implications. Maintaining comfortable indoor conditions while reducing energy consumption involves careful design, construction, and management of the built environment and its inhabitants. In this paper, we present findings from the study of a new low energy building for older people in Grenoble, France where conflicts emerged over the simultaneous pursuit of energy efficiency and comfort. The findings contribute to the contemporary literature on the sociotechnical study of buildings and energy use by focusing on intermediation, those activities that associate a technology to end users. Intermediation activities take many forms, and in some cases, can result in the harmonisation or alignment of energy efficiency goals and comfort goals. In other cases, intermediation is unsuccessful, leading to the conventional dichotomy between optimising technical performance and meeting occupant preferences. By highlighting the multiple ways that comfort and energy efficiency is negotiated, we conclude that buildings are provisional achievements that are constantly being intermediated. This suggests that building energy efficiency policies and programmes need to provide opportunities for intermediaries to negotiate the desires and preferences of the multiple stakeholders that are implicated in low energy buildings. -- Highlights: •Energy efficiency and comfort are two possibly contradictory aims of buildings. •We study the pursuit of these aims at the occupation stage of a new building. •Aligning these aims involve negotiating them with occupants. •Intermediation processes are key to such negotiations. •Intermediation processes involve both actors and technical devices

The Implications of Intermediate Stop Operations on Aviation Emissions and Climate

Directory of Open Access Journals (Sweden)

Florian Linke

2017-12-01

Full Text Available Among the various transport modes aviation's impact on climate change deserves special attention. Due to typical flight altitudes in the upper troposphere and above, the effect of aircraft engine emissions like e.g. water vapour, nitrogen oxides and aerosols on radiative forcing agents is substantial. The projected doubling of aircraft movements in the next 15 years will lead to an increase of aviation's impact on climate and requires immediate mitigation options. Besides technological measures also new operational strategies are widely discussed; one of these concepts which has been subject of several studies in the past is Intermediate Stop Operations (ISO. It is based on the idea to reduce the stage length of flights by performing one or more intermediate landings during a mission. Here, we analyse the ISO concept by combining different models, which include a realistic traffic simulation taking into account operational constraints and ambient conditions, like e.g. wind, the calculation of engine emissions and the integration of a climate response model. We analyse the ISO concept for today's worldwide aircraft fleet, including its influence on global emissions distributions as well as the impact on climate change by taking into account CO2 and non-CO2 effects, arising from contrail-cirrus, water vapour and nitrogen oxide emissions. We show in agreement with earlier findings that due to shorter flight distances the amount of fuel burnt over the mission can be reduced by roughly 5 % on average globally. For the first time, we quantify the climate impact of ISO, where the flight trajectory is optimised for fuel use and the aircraft is not redesigned for the ISO procedure. We find an increased warming effect, which arises from nitrogen oxide and water vapour emissions, which are released at higher cruise altitudes and which over-compensate reduced warming effects from CO2 and contrail-cirrus. However, we expect a climate impact reduction for

A hybrid intermediate language between SSA and CPS

DEFF Research Database (Denmark)

Torrens, Paulo; Vasconcellos, Cristiano; Gonçalves, Ju

2017-01-01

passing style (CPS) lambda calculus has been used as intermediate language for functional language compilers, they are (almost) equivalent and it is possible to draw syntactic translations between them. This short paper aims to present an untyped intermediate language which may be interpreted as both SSA...... and CPS, in order to provide a common language for both imperative and functional compilers, as well to take advantage of optimizations designed for either one of the approaches. Finally, potential variants and research opportunities are discussed....

Intermediate states in quantum cryptography and Bell inequalities

International Nuclear Information System (INIS)

Bechmann-Pasquinucci, H.; Gisin, N.

2003-01-01

Intermediate states are known from intercept/resend eavesdropping in the Bennett-Brassard 1984 (BB84) quantum cryptographic protocol. But they also play fundamental roles in the optimal eavesdropping strategy on the BB84 protocol and in the CHSH (Clauser-Horne-Shimony-Holt) inequality. We generalize the intermediate states to an arbitrary dimension and consider intercept/resend eavesdropping, optimal eavesdropping on the generalized BB84 protocol and present a generalized Clauser-Horne-Shimony-Holt inequality for two entangled qudits based on these states

Distribution and habitats of Lymnaea natalensis, snail intermediate host of the liver fluke Fasciola gigantica, in South Africa

Directory of Open Access Journals (Sweden)

Editorial Office

2001-09-01

Full Text Available This paper focuses on the geographical distribution and the habitats of Lymnaea natalensis, the snail intermediate host of the liver fluke, Fasciola gigantica, as reflected by the collection sites of its 4 552 samples currently on record in the National Freshwater Snail Collection (NFSC of South Africa. Although this species was represented in a variety of waterbodies, the majority of samples(±70%came from rivers, brooks and dams and in 70.8% of the cases the water was described as permanent and in 71.8% as slow flowing or standing. The results of life-table studies conducted by various authors indicated that temperature should be a relatively unimportant factor in determining its geographical distribution, but that the availability of permanent water should be decisive for its presence in a given habitat. These results are in agreement with the finding that only 7.5% of the samples of this species in the NFSC were collected in habitats which were described as seasonal. Furthermore, it gives a logical explanation for the sporadic occurrence, or total absence of this species in the more arid regions of South Africa. Water impoundments and irrigation networks contribute to a large extent towards creating perennial habitats which would be suitable for L. natalensis. As intermediate host for one of the liver fluke species which already is an economic factor in South Africa, this certainly is an aspect which ought to be reckoned within the planning and construction of new irrigation schemes.

Puget Sound Dissolved Oxygen Modeling Study: Development of an Intermediate Scale Water Quality Model

Energy Technology Data Exchange (ETDEWEB)

Khangaonkar, Tarang; Sackmann, Brandon S.; Long, Wen; Mohamedali, Teizeen; Roberts, Mindy

2012-10-01

The Salish Sea, including Puget Sound, is a large estuarine system bounded by over seven thousand miles of complex shorelines, consists of several subbasins and many large inlets with distinct properties of their own. Pacific Ocean water enters Puget Sound through the Strait of Juan de Fuca at depth over the Admiralty Inlet sill. Ocean water mixed with freshwater discharges from runoff, rivers, and wastewater outfalls exits Puget Sound through the brackish surface outflow layer. Nutrient pollution is considered one of the largest threats to Puget Sound. There is considerable interest in understanding the effect of nutrient loads on the water quality and ecological health of Puget Sound in particular and the Salish Sea as a whole. The Washington State Department of Ecology (Ecology) contracted with Pacific Northwest National Laboratory (PNNL) to develop a coupled hydrodynamic and water quality model. The water quality model simulates algae growth, dissolved oxygen, (DO) and nutrient dynamics in Puget Sound to inform potential Puget Sound-wide nutrient management strategies. Specifically, the project is expected to help determine 1) if current and potential future nitrogen loadings from point and non-point sources are significantly impairing water quality at a large scale and 2) what level of nutrient reductions are necessary to reduce or control human impacts to DO levels in the sensitive areas. The project did not include any additional data collection but instead relied on currently available information. This report describes model development effort conducted during the period 2009 to 2012 under a U.S. Environmental Protection Agency (EPA) cooperative agreement with PNNL, Ecology, and the University of Washington awarded under the National Estuary Program

Intermediate-range order in lead metasilicate glass

Energy Technology Data Exchange (ETDEWEB)

Suzuya, Kentaro [Japan Atomic Energy Research Inst., Ako, Hyogo (Japan)]|[Argonne National Lab., IL (United States). Materials Science Div.; Price, D.L.; Saboungi, M.L. [Argonne National Lab., IL (United States). Materials Science Div.; Ohno, Hideo [Japan Atomic Energy Research Inst., Ako, Hyogo (Japan)

1997-03-01

The complementarity of anomalous X-ray scattering (AXS) and neutron diffraction (ND) techniques is used here to investigate the nature and origin of intermediate-range order in lead metasilicate glass. Both X-ray and neutron source factors reveal small peaks at low wave vector which are shown to be associated with intermediate-range order of the Pb-O network. The combination of AXS and ND is shown to be a powerful tool to correlate contributions from the different atom pairs to such a peak. The information thus derived is compared with results from alkali germanate glasses and with structural data on corresponding crystalline compounds.

Low polarity water, a novel transition species at the polyethylene-water interface.

Science.gov (United States)

Kosower, Edward M; Borz, Galina

2015-10-14

The bridge between water repelling and water-attracting regions is recognized here as low polarity water, a novel "neutral" form of water; its identity as a dipole-dipole water dimer is supported by spectroscopic evidence of its presence in thin films of water on a polyethylene surface. High resolution (0.5 cm(-1)), low signal energies (Sg 100) and short scans (0.1 s) are used to ensure that all peaks are detected. Thin films may be trapped between two polyethylene windows, affirming the low polarity of such water; the spectra of the trapped films ("sandwich") are similar to those from a subtraction procedure. Use of the "sandwich" is a new and useful technique in surface studies. In general, intermediate forms might bridge incompatibility between different regimes, from sets of molecules (chemistry and physics) to sets of organisms (biology and sociology). Thin films of water on polyethylene also display strong and transient peaks of water oligomers, cyclic pentamers and cyclic hexamers (chair and boat), bicyclic hexamers (books 1 and 2) and tricyclic hexamers (prism) that have been previously identified in thin films of water on a silver halide surface.

Low temperature intermediate band metallic behavior in Ti implanted Si

Energy Technology Data Exchange (ETDEWEB)

Olea, Javier, E-mail: oleaariza@fis.ucm.es; Pastor, David; Garcia-Hemme, Eric; Garcia-Hernansanz, Rodrigo; Prado, Alvaro del; Martil, Ignacio; Gonzalez-Diaz, German

2012-08-31

Si samples implanted with very high Ti doses and subjected to Pulsed-Laser Melting (PLM) have been electrically analyzed in the scope of a two-layer model previously reported based on the Intermediate Band (IB) theory. Conductivity and Hall effect measurements using the van der Pauw technique suggest that the insulator-metal transition takes place for implantation doses in the 10{sup 14}-10{sup 16} cm{sup -2} range. Results of the sample implanted with the 10{sup 16} cm{sup -2} dose show a metallic behavior at low temperature that is explained by the formation of a p-type IB out of the Ti deep levels. This suggests that the IB would be semi-filled, which is essential for IB photovoltaic devices. - Highlights: Black-Right-Pointing-Pointer We fabricated high dose Ti implanted Si samples for intermediate band research. Black-Right-Pointing-Pointer We measured the electronic transport properties in the 7-300 K range. Black-Right-Pointing-Pointer We show an insulator to metallic transition when the intermediate band is formed. Black-Right-Pointing-Pointer The intermediate band is semi-filled and populated by holes. Black-Right-Pointing-Pointer We satisfactorily explain the electrical behavior by an intermediate band model.

Wetting of alkanes on water

Energy Technology Data Exchange (ETDEWEB)

Bertrand, E.; Bonn, D.; Meunier, J.; Shahidzadeh, N. [Ecole Normale Superieure, Laboratoire de Physique Statistique, 24 rue Lhomond, 75231, Cedex 05 Paris (France); Broseta, D.; Ragil, K. [Institut Francais du Petrole, 1-4 avenue de Bois Preau, 92852 Rueil-Malmaison Cedex (France); Dobbs, H.; Indekeu, J.O. [Katholieke Universiteit Leuven, Laboratorium voor Vaste-Stoffysica en Magnetisme, B-3001 Leuven (Belgium)

2002-04-01

The wetting behavior of oil on water (or brine) has important consequences for the transport properties of oil in water-containing porous reservoirs, and consequently for oil recovery. The equilibrium wetting behavior of model oils composed of pure alkanes or alkane mixtures on brine is reviewed in this paper. Intermediate between the partial wetting state, in which oil lenses coexist on water with a thin film of adsorbed alkane molecules, and the complete wetting state, in which a macroscopically thick oil layer covers the water, these systems display a third, novel wetting state, in which oil lenses coexist with a mesoscopic (a few-nanometers-thick) oil film. The nature and location of the transitions between these wetting regimes depend on oil and brine compositions, temperature and pressure.

Intermediate organizations in the innovation process in Mexico

Directory of Open Access Journals (Sweden)

Maria del Pilar Monserrat Pérez Hernández

2016-07-01

Full Text Available The innovation activity depends strongly on the interaction between generating actors and end-users of new knowledge and technologies. There are several intermediate organizations (IO that facilitate translating the needs of the users with the new technologies that are beingdeveloped, in order to satisfy more effectively their demands. This paper analyzes the mediation process involved in the IO in innovative activity in Mexico, to identify structural holes in the innovation process. The relevant results in the Mexican intermediation process points that threeimportant structural holes of the process are missing: one between the negotiation process and sponsorship, the second in marketing and commercial profit of the obtained results and the last one in the regulation and referring activities. It is very important that the detected missinglinks in the intermediation process are filled, because they can hinder considerably the overall profit and benefits that society could obtained of the innovation process.

Low and intermediate radioactive waste characterization using MICROSHIELD 5 code

International Nuclear Information System (INIS)

Mateescu, Silvia; Pantazi, Doina; Stanciu, Marcela

2002-01-01

Low and intermediate radioactive gaseous, liquid and solid waste produced at Cernavoda Nuclear Power Plant must be known from the point of view of contained radionuclide activity, during all steps of their processing, storage and transport, to ensure the nuclear safety of radioactive waste management. As the waste activity changes by radioactive decay and nuclear transmutation, the evolution in time of these sources is necessary to be assess, for the purpose of biological shielding determination at any time. On the other hand, during the transport of waste package at the repository, the external dose rates must meet the national and international requirements concerning radioactive materials transportation on public roads. In this paper, a calculation methodology for waste characterization based on external exposure rate measurement and on sample analysis results is presented. The time evolution of waste activity, as well as the corresponding shielding at different moments of management process, has been performed using MICROSHIELD-5 code. The spent resins proceeded from systems for clean-up and purification of cooling water and moderator, water from spent fuel storage bays, etc. have been analyzed. In this paper an example of spent ionic resins characterization, using the MICROSHIELD 5 code, is presented. (authors)

Aspartate aminotransferase: the kinetic barriers facing the covalent intermediates on the reaction pathway

International Nuclear Information System (INIS)

Kirsch, J.F.; Julin, D.A.; McLeish, M.; Wiesinger, H.

1986-01-01

The intermediates, aldimine (A), quinonoid (Q) and ketimine (K), along the transaminase reaction coordinate were probed by isotope transfer and solvent exchange kinetics. Less than 0.003% of 3 H is transferred from C/sub α/[ 3 H]-aspartate to pyridoxamine phosphate in the cytoplasmic aspartate aminotransferase (cAATase) reaction implying either that Q does not exist as a kinetically competent intermediate or that there is a rapid exchange of isotope with solvent. The ratio of the rate constants for C/sub α/ hydrogen exchange vs keto acid product formation (k/sub exge//k/sub prod/) are 2.5 and 0.5 for the reactions of cAATase with C/sub α/ [ 2 H]-aspartate and mitochondrial (m) AATase with C/sub α/[ 2 H]-glutamate respectively. The latter reaction was also probed from the α-keto-glutarate side with carbonyl 0-18 enriched keto acid. This experiment gave k/sub exge//k/sub prod/ = 1.0 for oxygen-18 exchange in α-ketoglutarate versus amino acid formation. The two exchange experiments with mAATase are interpreted in terms of a model in which the rate constant for diffusion of water from the active site is comparable with those for product forming steps

Production of intermediate-mass dileptons in relativistic heavy ion collisions

International Nuclear Information System (INIS)

Kvasnikova, Ioulia; Gale, Charles; Kumar Srivastava, Dinesh

2002-01-01

The production of intermediate-mass dileptons in ultrarelativistic nuclear collisions at SPS energies is studied. The acceptance and detector resolution inherent to measurements by the NA50 experimental collaboration are accurately modeled. The measured centrality dependence of the intermediate mass lepton pair excess is also addressed

Intermediate uveitis

Directory of Open Access Journals (Sweden)

Babu B

2010-01-01

Full Text Available Intermediate uveitis (IU is described as inflammation in the anterior vitreous, ciliary body and the peripheral retina. In the Standardization of Uveitis Nomenclature (SUN working group′s international workshop for reporting clinical data the consensus reached was that the term IU should be used for that subset of uveitis where the vitreous is the major site of the inflammation and if there is an associated infection (for example, Lyme disease or systemic disease (for example, sarcoidosis. The diagnostic term pars planitis should be used only for that subset of IU where there is snow bank or snowball formation occurring in the absence of an associated infection or systemic disease (that is, "idiopathic". This article discusses the clinical features, etiology, pathogenesis, investigations and treatment of IU.

File list: Unc.PSC.50.AllAg.iPSC_intermediates [Chip-atlas[Archive

Lifescience Database Archive (English)

Full Text Available Unc.PSC.50.AllAg.iPSC_intermediates mm9 Unclassified Pluripotent stem cell iPSC intermediates... http://dbarchive.biosciencedbc.jp/kyushu-u/mm9/assembled/Unc.PSC.50.AllAg.iPSC_intermediates.bed ...

File list: Pol.PSC.10.AllAg.iPSC_intermediates [Chip-atlas[Archive

Lifescience Database Archive (English)

Full Text Available Pol.PSC.10.AllAg.iPSC_intermediates mm9 RNA polymerase Pluripotent stem cell iPSC intermediates...e.biosciencedbc.jp/kyushu-u/mm9/assembled/Pol.PSC.10.AllAg.iPSC_intermediates.bed ...

File list: Unc.PSC.20.AllAg.iPSC_intermediates [Chip-atlas[Archive

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Full Text Available Unc.PSC.20.AllAg.iPSC_intermediates mm9 Unclassified Pluripotent stem cell iPSC intermediates... http://dbarchive.biosciencedbc.jp/kyushu-u/mm9/assembled/Unc.PSC.20.AllAg.iPSC_intermediates.bed ...

File list: Pol.PSC.05.AllAg.iPSC_intermediates [Chip-atlas[Archive

Lifescience Database Archive (English)

Full Text Available Pol.PSC.05.AllAg.iPSC_intermediates mm9 RNA polymerase Pluripotent stem cell iPSC intermediates...e.biosciencedbc.jp/kyushu-u/mm9/assembled/Pol.PSC.05.AllAg.iPSC_intermediates.bed ...

File list: Pol.PSC.20.AllAg.iPSC_intermediates [Chip-atlas[Archive

Lifescience Database Archive (English)

Full Text Available Pol.PSC.20.AllAg.iPSC_intermediates mm9 RNA polymerase Pluripotent stem cell iPSC intermediates...e.biosciencedbc.jp/kyushu-u/mm9/assembled/Pol.PSC.20.AllAg.iPSC_intermediates.bed ...

File list: Unc.PSC.10.AllAg.iPSC_intermediates [Chip-atlas[Archive

Lifescience Database Archive (English)

Full Text Available Unc.PSC.10.AllAg.iPSC_intermediates mm9 Unclassified Pluripotent stem cell iPSC intermediates... http://dbarchive.biosciencedbc.jp/kyushu-u/mm9/assembled/Unc.PSC.10.AllAg.iPSC_intermediates.bed ...

File list: Pol.PSC.50.AllAg.iPSC_intermediates [Chip-atlas[Archive

Lifescience Database Archive (English)

Full Text Available Pol.PSC.50.AllAg.iPSC_intermediates mm9 RNA polymerase Pluripotent stem cell iPSC intermediates...e.biosciencedbc.jp/kyushu-u/mm9/assembled/Pol.PSC.50.AllAg.iPSC_intermediates.bed ...

File list: Unc.PSC.05.AllAg.iPSC_intermediates [Chip-atlas[Archive

Lifescience Database Archive (English)

Full Text Available Unc.PSC.05.AllAg.iPSC_intermediates mm9 Unclassified Pluripotent stem cell iPSC intermediates... http://dbarchive.biosciencedbc.jp/kyushu-u/mm9/assembled/Unc.PSC.05.AllAg.iPSC_intermediates.bed ...

Visual dictionaries as intermediate features in the human brain

Directory of Open Access Journals (Sweden)

Kandan eRamakrishnan

2015-01-01

Full Text Available The human visual system is assumed to transform low level visual features to object and scene representations via features of intermediate complexity. How the brain computationally represents intermediate features is still unclear. To further elucidate this, we compared the biologically plausible HMAX model and Bag of Words (BoW model from computer vision. Both these computational models use visual dictionaries, candidate features of intermediate complexity, to represent visual scenes, and the models have been proven effective in automatic object and scene recognition. These models however differ in the computation of visual dictionaries and pooling techniques. We investigated where in the brain and to what extent human fMRI responses to short video can be accounted for by multiple hierarchical levels of the HMAX and BoW models. Brain activity of 20 subjects obtained while viewing a short video clip was analyzed voxel-wise using a distance-based variation partitioning method. Results revealed that both HMAX and BoW explain a significant amount of brain activity in early visual regions V1, V2 and V3. However BoW exhibits more consistency across subjects in accounting for brain activity compared to HMAX. Furthermore, visual dictionary representations by HMAX and BoW explain significantly some brain activity in higher areas which are believed to process intermediate features. Overall our results indicate that, although both HMAX and BoW account for activity in the human visual system, the BoW seems to more faithfully represent neural responses in low and intermediate level visual areas of the brain.

Reactor-moderated intermediate-energy neutron beams for neutron-capture therapy

International Nuclear Information System (INIS)

Less, T.J.

1987-01-01

One approach to producing an intermediate energy beam is moderating fission neutrons escaping from a reactor core. The objective of this research is to evaluate materials that might produce an intermediate beam for NCT via moderation of fission neutrons. A second objective is to use the more promising moderator material in a preliminary design of an NCT facility at a research reactor. The evaluations showed that several materials or combinations of materials could produce a moderator source for an intermediate beam for NCT. The best neutron spectrum for use in NCT is produced by Al 2 O 3 , but mixtures of Al metal and D 2 O are also attractive. Using the best moderator materials, results were applied to the design of an NCT moderator at the Georgia Institute of Technology Research Reactor's bio-medical facility. The amount of photon shielding and thermal neutron absorber were optimized with respect to the desired photon dose rate and intermediate neutron flux at the patient position

Carbonate compensation depth: relation to carbonate solubility in ocean waters.

Science.gov (United States)

Ben-Yaakov, S; Ruth, E; Kaplan, I R

1974-05-31

In situ calcium carbonate saturometry measurements suggest that the intermediate water masses of the central Pacific Ocean are close to saturation with resppect to both calcite and local carbonate sediment. The carbonate compensation depth, located at about 3700 meters in this area, appears to represent a depth above which waters are essentially saturated with respect to calcite and below which waters deviate toward undersaturation with respect to calcite.

File list: DNS.PSC.20.AllAg.iPSC_intermediates [Chip-atlas[Archive

Lifescience Database Archive (English)

Full Text Available DNS.PSC.20.AllAg.iPSC_intermediates mm9 DNase-seq Pluripotent stem cell iPSC intermediates... http://dbarchive.biosciencedbc.jp/kyushu-u/mm9/assembled/DNS.PSC.20.AllAg.iPSC_intermediates.bed ...

File list: DNS.PSC.10.AllAg.iPSC_intermediates [Chip-atlas[Archive

Lifescience Database Archive (English)

Full Text Available DNS.PSC.10.AllAg.iPSC_intermediates mm9 DNase-seq Pluripotent stem cell iPSC intermediates... http://dbarchive.biosciencedbc.jp/kyushu-u/mm9/assembled/DNS.PSC.10.AllAg.iPSC_intermediates.bed ...

File list: DNS.PSC.05.AllAg.iPSC_intermediates [Chip-atlas[Archive

Lifescience Database Archive (English)

Full Text Available DNS.PSC.05.AllAg.iPSC_intermediates mm9 DNase-seq Pluripotent stem cell iPSC intermediates... http://dbarchive.biosciencedbc.jp/kyushu-u/mm9/assembled/DNS.PSC.05.AllAg.iPSC_intermediates.bed ...

Intermediality and the Child Performer

Science.gov (United States)

Budd, Natasha

2016-01-01

This report details examples of praxis in the creation and presentation of "Joy Fear and Poetry": an intermedial theatre performance in which children aged 7-12 years generated aesthetic gestures using a range of new media forms. The impetus for the work's development was a desire to make an intervention into habituated patterns of…

Thorium Fuel Performance in a Tight-Pitch Light Water Reactor Lattice

International Nuclear Information System (INIS)

Kim, Taek Kyum; Downar, Thomas J.

2002-01-01

Research on the utilization of thorium-based fuels in the intermediate neutron spectrum of a tight-pitch light water reactor (LWR) lattice is reported. The analysis was performed using the Studsvik/Scandpower lattice physics code HELIOS. The results show that thorium-based fuels in the intermediate spectrum of tight-pitch LWRs have considerable advantages in terms of conversion ratio, reactivity control, nonproliferation characteristics, and a reduced production of long-lived radiotoxic wastes. Because of the high conversion ratio of thorium-based fuels in intermediate spectrum reactors, the total fissile inventory required to achieve a given fuel burnup is only 11 to 17% higher than that of 238 U fertile fuels. However, unlike 238 U fertile fuels, the void reactivity coefficient with thorium-based fuels is negative in an intermediate spectrum reactor. This provides motivation for replacing 238 U with 232 Th in advanced high-conversion intermediate spectrum LWRs, such as the reduced-moderator reactor or the supercritical reactor

Bioorthogonal Cycloadditions with Sub-Millisecond Intermediates.

Science.gov (United States)

Qing, Yujia; Pulcu, Gökçe Su; Bell, Nicholas A W; Bayley, Hagan

2018-01-26

Tetrazine- and sydnone-based click reactions have emerged as important bioconjugation strategies with fast kinetics and N 2 or CO 2 as the only byproduct. Mechanistic studies of these reactions have focused on the initial rate-determining cycloaddition steps. The subsequent N 2 or CO 2 release from the bicyclic intermediates has been approached mainly through computational studies, which have predicted lifetimes of femtoseconds. In the present study, bioorthogonal cycloadditions involving N 2 or CO 2 extrusion have been examined experimentally at the single-molecule level by using a protein nanoreactor. At the resolution of this approach, the reactions appeared to occur in a single step, which places an upper limit on the lifetimes of the intermediates of about 80 μs, which is consistent with the computational work. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Intermediate L-K molecular orbital radiation from heavy ion collisions

International Nuclear Information System (INIS)

Heinig, K.H.; Jaeger, H.U.; Richter, H.; Woittennek, H.

1975-09-01

The structure of x-ray continua observed recently in violent collisions between intermediate mass atoms can be explained by a superposition of K molecular orbital (KMO) radiation and of an intermediate L-K molecular orbital (ILKMO) radiation of high intensity which is due to 2psigma vacancies. (author)

Degradation and intermediates of diclofenac as instructive example for decomposition of recalcitrant pharmaceuticals by hydroxyl radicals generated with pulsed corona plasma in water.

Science.gov (United States)

Banaschik, Robert; Jablonowski, Helena; Bednarski, Patrick J; Kolb, Juergen F

2018-01-15

Seven recalcitrant pharmaceutical residues (diclofenac, 17α-ethinylestradiol, carbamazepine, ibuprofen, trimethoprim, diazepam, diatrizoate) were decomposed by pulsed corona plasma generated directly in water. The detailed degradation pathway was investigated for diclofenac and 21 intermediates could be identified in the degradation cascade. Hydroxyl radicals have been found primarily responsible for decomposition steps. By spin trap enhanced electron paramagnetic resonance spectroscopy (EPR), OH-adducts and superoxide anion radical adducts were detected and could be distinguished applying BMPO as a spin trap. The increase of concentrations of adducts follows qualitatively the increase of hydrogen peroxide concentrations. Hydrogen peroxide is eventually consumed in Fenton-like processes but the concentration is continuously increasing to about 2mM for a plasma treatment of 70min. Degradation of diclofenac is inversely following hydrogen peroxide concentrations. No qualitative differences between byproducts formed during plasma treatment or due to degradation via Fenton-induced processes were observed. Findings on degradation kinetics of diclofenac provide an instructive understanding of decomposition rates for recalcitrant pharmaceuticals with respect to their chemical structure. Accordingly, conclusions can be drawn for further development and a first risk assessment of the method which can also be applied towards other AOPs that rely on the generation of hydroxyl radicals. Copyright © 2017 Elsevier B.V. All rights reserved.

Hoxd11 specifies a program of metanephric kidney development within the intermediate mesoderm of the mouse embryo.

Science.gov (United States)

Mugford, Joshua W; Sipilä, Petra; Kobayashi, Akio; Behringer, Richard R; McMahon, Andrew P

2008-07-15

The mammalian kidney consists of an array of tubules connected to a ductal system that collectively function to control water/salt balance and to remove waste from the organisms' circulatory system. During mammalian embryogenesis, three kidney structures form within the intermediate mesoderm. The two most anterior structures, the pronephros and the mesonephros, are transitory and largely non-functional, while the most posterior, the metanephros, persists as the adult kidney. We have explored the mechanisms underlying regional specific differentiation of the kidney forming mesoderm. Previous studies have shown a requirement for Hox11 paralogs (Hoxa11, Hoxc11 and Hoxd11) in metanephric development. Mice lacking all Hox11 activity fail to form metanephric kidney structures. We demonstrate that the Hox11 paralog expression is restricted in the intermediate mesoderm to the posterior, metanephric level. When Hoxd11 is ectopically activated in the anterior mesonephros, we observe a partial transformation to a metanephric program of development. Anterior Hoxd11(+) cells activate Six2, a transcription factor required for the maintenance of metanephric tubule progenitors. Additionally, Hoxd11(+) mesonephric tubules exhibit an altered morphology and activate several metanephric specific markers normally confined to distal portions of the functional nephron. Collectively, our data support a model where Hox11 paralogs specify a metanephric developmental program in responsive intermediate mesoderm. This program maintains tubule forming progenitors and instructs a metanephric specific pattern of nephron differentiation.

Is Adjuvant Chemoradiotherapy Overtreatment in Cervical Cancer Patients With Intermediate Risk Factors?

International Nuclear Information System (INIS)

Ryu, Sang-Young; Park, Sang-Il; Nam, Byung-Ho; Cho, Chul-Koo; Kim, Kidong; Kim, Beob-Jong; Kim, Moon-Hong; Choi, Seok-Cheol; Lee, Eui-Don; Lee, Kyoung-Hee

2011-01-01

Purpose: To determine whether adjuvant chemoradiotherapy (CRT) improves the outcome of cervical cancer patients with intermediate risk factors. Methods and Materials: Between January 2000 and June 2006, the medical records of 735 patients who had undergone radical surgery for Stage IB-IIA cervical cancer were reviewed retrospectively. Of the 735 patients, 172 with two or more intermediate risk factors (i.e., lymphovascular space involvement, deep stromal invasion, and tumor size ≥2 cm) were grouped as follows according to the adjuvant treatment received: 34 patients, no further treatment; 49 patients, RT; and 89 patients, CRT. The significance of the clinical parameters and recurrence-free survival of each group were analyzed. Results: Of the 172 patients with any of the intermediate risk factors, 137 (79.6%) had two or more intermediate risk factors. Of the 172 patients, 12 developed recurrences (6.4%)->(7.0%), with 6 in the pelvis and 6 in distant sites. All 12 recurrences occurred in those who had two or more intermediate risk factors (sensitivity, 100%); however, only six recurrences were detected in patients who met the Gynecologic Oncology Group criteria for the intermediate-risk group (sensitivity, 50%; Z test, p .05). Conclusion: Postoperative adjuvant CRT can improve the outcome of cervical cancer patients with intermediate risk factors, with low increase in toxicity.

Heavy Section Steel Technology Program. Part II. Intermediate vessel testing

International Nuclear Information System (INIS)

Whitman, G.D.

1975-01-01

The testing of the intermediate pressure vessels is a major activity under the Heavy Section Steel Technology Program. A primary objective of these tests is to develop or verify methods of fracture prediction, through the testing of selected structures and materials, in order that a valid basis can be established for evaluating the serviceability and safety of light-water reactor pressure vessels. These vessel tests were planned with sufficiently specific objectives that substantial quantitative weight could be given to the results. Each set of testing conditions was chosen so as to provide specific data by which analytical methods of predicting flaw growth, and in some cases crack arrest, could be evaluated. Every practical effort was made to assure that results would be relevant to some aspect of real reactor pressure vessel performance through careful control of material properties, selection of test temperatures, and design of prepared flaws. 5 references

Optimal design of the cable metro with unified intermediate supports

Directory of Open Access Journals (Sweden)

Lagerev A.V.

2017-12-01

Full Text Available In article was formulated and solved the problem of conditional nonlinear technical and economic optimization of the distance between intermediate supports, uniform in height, during the design of the cable metro lines in highly urban-ized city environment. The optimization problem involves a single-criterion objective function that expresses the cost of construction of the cable metro line (total cost of intermediate supports and their foundations, traction and carrying steel cables and technical equipment. The specified objective function subject to minimization by finding the optimal combination of the distance between intermediate supports and tension carrying ropes with accounting constructive, modal, structural and planning constraints in the form of nonlinear inequalities. The optimization algorithm was based on the direct method of optimization type, Hooke-Jeeves, which was modified taking into account the need of varying the height of intermediate supports with a constant step equal to the step of unification. When constructing the objective function were considered three possible forms sagging of carrying ropes, which can be implemented for various values of the efforts of their tension. Analysis was done of the influence of the step unification and minimum size of interme-diate supports on their optimum step, the cost of intermediate supports, the cost of 1 km cable metro line for different values of the angle of the longitudinal slope of the surface relief along the cable metro line. The graph of height of uni-fied supports from the angle of the longitudinal slope of the surface relief has discrete-step type. With the increase of the step unify the discreteness increases: the width of the range of angles of the longitudinal slope of the surface relief within which the height of the supports remains constant, increases. The graph of step installation of unified supports along the cable metro line from the angle of the longitudinal

Carbon emission, energy consumption and intermediate goods trade: A regional study of East Asia

International Nuclear Information System (INIS)

Zhang, Jingjing

2015-01-01

Using country level panel data from East Asia over the period 1998–2011, this paper examines the implications of international production fragmentation-induced intermediate goods trade on the link between energy consumption and carbon pollution. The paper focuses on the interaction effect between energy consumption and trade in intermediate goods on carbon emission. The empirical results presented suggest that international trade in intermediate goods decreases the positive impact on carbon emission of energy consumption. When compared with the trade in final goods, intermediate goods trade contributes to a greater decrease in carbon pollution resulting from energy consumption. These results confirm that the link between energy consumption and carbon pollution in East Asia is significantly affected by international production fragmentation-induced trade in intermediate goods. The results presented in this paper have some important policy implications. - Highlights: • This paper tests the role of intermediates trade in energy-development nexus. • Empirical study is based on data of East Asia. • International trade can reduce the carbon pollution caused by energy use. • Intermediates trade has higher moderating effect than non-intermediate trade.

Intermediate coupling collision strengths from LS coupled R-matrix elements

International Nuclear Information System (INIS)

Clark, R.E.H.

1978-01-01

Fine structure collision strength for transitions between two groups of states in intermediate coupling and with inclusion of configuration mixing are obtained from LS coupled reactance matrix elements (R-matrix elements) and a set of mixing coefficients. The LS coupled R-matrix elements are transformed to pair coupling using Wigner 6-j coefficients. From these pair coupled R-matrix elements together with a set of mixing coefficients, R-matrix elements are obtained which include the intermediate coupling and configuration mixing effects. Finally, from the latter R-matrix elements, collision strengths for fine structure transitions are computed (with inclusion of both intermediate coupling and configuration mixing). (Auth.)

Intermediate statistics in quantum maps

Energy Technology Data Exchange (ETDEWEB)

Giraud, Olivier [H H Wills Physics Laboratory, University of Bristol, Tyndall Avenue, Bristol BS8 1TL (United Kingdom); Marklof, Jens [School of Mathematics, University of Bristol, University Walk, Bristol BS8 1TW (United Kingdom); O' Keefe, Stephen [School of Mathematics, University of Bristol, University Walk, Bristol BS8 1TW (United Kingdom)

2004-07-16

We present a one-parameter family of quantum maps whose spectral statistics are of the same intermediate type as observed in polygonal quantum billiards. Our central result is the evaluation of the spectral two-point correlation form factor at small argument, which in turn yields the asymptotic level compressibility for macroscopic correlation lengths. (letter to the editor)

Influence of an Intermediate Option on the Description-Experience Gap and Information Search.

Science.gov (United States)

Sharma, Neha; Debnath, Shoubhik; Dutt, Varun

2018-01-01

Research shows that people tend to overweight small probabilities in description and underweight them in experience, thereby leading to a different pattern of choices between description and experience; a phenomenon known as the Description-Experience (DE) gap. However, little is known on how the addition of an intermediate option and contextual framing influences the DE gap and people's search strategies. This paper tests the effects of an intermediate option and contextual framing on the DE gap and people's search strategies, where problems require search for information before a consequential choice. In the first experiment, 120 participants made choice decisions across investment problems that differed in the absence or presence of an intermediate option. Results showed that adding an intermediate option did not reduce the DE gap on the maximizing option across a majority of problems. There were a large majority of choices for the intermediate option. Furthermore, there was an increase in switching between options due to the presence of the intermediate option. In the second experiment, 160 participants made choice decisions in problems like those presented in experiment 1; however, problems lacked the investment framing. Results replicated findings from the first experiment and showed a similar DE gap on the maximizing option in a majority of problems in both the absence and presence of the intermediate option. Again, there were a large majority of choices for the intermediate option. Also, there was an increase in switching between options due to the presence of the intermediate option. Meta-analyses revealed that the absence or presence of the intermediate option created certain differences in the strength of frequency and recency processes. Also, a single natural-mean heuristic model was able to account for the experimental results across both experiments. We discuss implications of our findings to consequential decisions made after information search.

Influence of an Intermediate Option on the Description-Experience Gap and Information Search

Directory of Open Access Journals (Sweden)

Neha Sharma

2018-03-01

Full Text Available Research shows that people tend to overweight small probabilities in description and underweight them in experience, thereby leading to a different pattern of choices between description and experience; a phenomenon known as the Description-Experience (DE gap. However, little is known on how the addition of an intermediate option and contextual framing influences the DE gap and people’s search strategies. This paper tests the effects of an intermediate option and contextual framing on the DE gap and people’s search strategies, where problems require search for information before a consequential choice. In the first experiment, 120 participants made choice decisions across investment problems that differed in the absence or presence of an intermediate option. Results showed that adding an intermediate option did not reduce the DE gap on the maximizing option across a majority of problems. There were a large majority of choices for the intermediate option. Furthermore, there was an increase in switching between options due to the presence of the intermediate option. In the second experiment, 160 participants made choice decisions in problems like those presented in experiment 1; however, problems lacked the investment framing. Results replicated findings from the first experiment and showed a similar DE gap on the maximizing option in a majority of problems in both the absence and presence of the intermediate option. Again, there were a large majority of choices for the intermediate option. Also, there was an increase in switching between options due to the presence of the intermediate option. Meta-analyses revealed that the absence or presence of the intermediate option created certain differences in the strength of frequency and recency processes. Also, a single natural-mean heuristic model was able to account for the experimental results across both experiments. We discuss implications of our findings to consequential decisions made after

Determination Bounds for Intermediate Products in a Two-Stage Network DEA

Directory of Open Access Journals (Sweden)

Hadi Bagherzadeh Valami

2016-03-01

Full Text Available The internal structure of decision making unit (DMU is the key element at extension of network DEA. In general considering internal performance evaluation of system is a better criterion than the conventional DEA-models, essentially based on the initial inputs and final outputs of the system. The internal performance of a system is dependent on the relation between sub-DMUs and intermediate products. Since the intermediate measures are consumed by some sub-DMUs produced by the others, it is possible to produce systems; the role of intermediate production is twice output and input. That's why they can be analyzed based on conventional mathematical modeling. In this paper we introduce a new method for determining bounds for intermediate product in a two stage network DEA structure.

Unification of favourable intermediate-, unfavourable intermediate-, and very high-risk stratification criteria for prostate cancer.

Science.gov (United States)

Zumsteg, Zachary S; Zelefsky, Michael J; Woo, Kaitlin M; Spratt, Daniel E; Kollmeier, Marisa A; McBride, Sean; Pei, Xin; Sandler, Howard M; Zhang, Zhigang

2017-11-01

To improve on the existing risk-stratification systems for prostate cancer. This was a retrospective investigation including 2 248 patients undergoing dose-escalated external beam radiotherapy (EBRT) at a single institution. We separated National Comprehensive Cancer Network (NCCN) intermediate-risk prostate cancer into 'favourable' and 'unfavourable' groups based on primary Gleason pattern, percentage of positive biopsy cores (PPBC), and number of NCCN intermediate-risk factors. Similarly, NCCN high-risk prostate cancer was stratified into 'standard' and 'very high-risk' groups based on primary Gleason pattern, PPBC, number of NCCN high-risk factors, and stage T3b-T4 disease. Patients with unfavourable-intermediate-risk (UIR) prostate cancer had significantly inferior prostate-specific antigen relapse-free survival (PSA-RFS, P prostate cancer-specific mortality (PCSM, P prostate cancer. Similarly, patients with very high-risk (VHR) prostate cancer had significantly worse PSA-RFS (P prostate cancer. Moreover, patients with FIR and low-risk prostate cancer had similar outcomes, as did patients with UIR and SHR prostate cancer. Consequently, we propose the following risk-stratification system: Group 1, low risk and FIR; Group 2, UIR and SHR; and Group 3, VHR. These groups have markedly different outcomes, with 8-year distant metastasis rates of 3%, 9%, and 29% (P < 0.001) for Groups 1, 2, and 3, respectively, and 8-year PCSM of 1%, 4%, and 13% (P < 0.001) after EBRT. This modified stratification system was significantly more accurate than the three-tiered NCCN system currently in clinical use for all outcomes. Modifying the NCCN risk-stratification system to group FIR with low-risk patients and UIR with SHR patients, results in modestly improved prediction of outcomes, potentially allowing better personalisation of therapeutic recommendations. © 2017 The Authors BJU International © 2017 BJU International Published by John Wiley & Sons Ltd.

Isomerization Intermediates In Solution Phase Photochemistry Of Stilbenes

Science.gov (United States)

Doany, F. E.; Hochstrasser, R. M.; Greene, B. I.

1985-04-01

Picosecond and subpicosecond spectroscopic studies have revealed evidence for an isomerization intermediate between cis and trans in the photoinduced isomerism of both stilbene and biindanyledene ("stiff" stilbene). In stiff stilbene, a transient absorption at 351 nm displays time evolution and viscosity dependence consistent with absorption by a twisted intermediate ("phantom" state) with a lOps lifetime. An analagous bottleneck state with a life-time of 4ps is also consistent with the ground state recovery dynamics of t-stilbene following excitation of c-stilbene when monitored with 0.1ps resolution.

Post-crisis financial intermediation

Directory of Open Access Journals (Sweden)

Ilie MIHAI

2015-09-01

Full Text Available The recent financial crisis that begun in 2007 in the US, which then swept around the world, has left deep scars on the already wrinkled face of the global economy. Some national and regional economies, which had money for expensive makeup, or created money[1], managed to blur or hide the scars left by the crisis, others are still facing difficulties in overcoming the effects of this. The rapacity of banks, their greed and risk ignorance, were the origin of the outbreak of the last major economic and financial crisis but unfortunately those who were responsible or, rather, irresponsible, paid little or nothing at all for the burden of their bad loan portfolio. This cost has been supported by the population, either directly by paying high interest and fees [Mihai I., 2007], or indirectly, through the use of public budgets to cover the losses of banks, most of which had private capital. In this context, we intend to examine the state of financial intermediation in Romania in the post-crisis period, and to primarily follow: (i The structure and evolution of the banking system; (ii Non-government credit situation; (iii The level of savings; (iiii Loan-deposit ratio; (v The degree of financial intermediation and disintegration phenomenon etc., and to articulate some conclusions and suggestions on the matters that have been explored.

Determination of the vildagliptin intermediate enantiomer by chiralce-columns

Directory of Open Access Journals (Sweden)

Weina LI

2017-06-01

Full Text Available In order to establish a NP-HPLC method for the determination of enantiomer in vildagliptin intermediate, the determination is carried out on the column of ChiralpakAD-H(250 mm×4.6 mm, 5 μm, with the mobile phase of n-hexane, ethanol and methanol（volume ratio of 65∶25∶10）at flow rate of 0.8 mL/min. The sample volume is 10 μL, the wavelength is 210 nm and the column temperature is 35 ℃. The result shows that the vildagliptin intermediate and its enantiomer could be well separated and detected effectively; blank solvent doesn't interfere with the enantiomer assaying; the detection limit is 27 ng/mL and the quantification limit is 81 ng/mL; in repetitive test, the RSD of enantiomer assaying of samples are no more than 2.0%; in stability test, the RSD are no more than 2.0% in 12 h; the vildagliptin intermediate and its enantiomer could be well separated in the test of durability with all RSDs below 2.0%. The method is simple, reliable, accurate and durable, and can be used for determination of enantiomer in vildagliptin intermediate.

Continuous Flow-Resonance Raman Spectroscopy of an Intermediate Redox State of Cytochrome-C

DEFF Research Database (Denmark)

Forster, M.; Hester, R. E.; Cartling, B.

1982-01-01

An intermediate redox state of cytochrome c at alkaline pH, generated upon rapid reduction by sodium dithionite, has been observed by resonance Raman (RR) spectroscopy in combination with the continuous flow technique. The RR spectrum of the intermediate state is reported for excitation both...... in the (alpha, beta) and the Soret optical absorption band. The spectra of the intermediate state are more like those of the stable reduced form than those of the stable oxidized form. For excitation of 514.5 nm, the most prominent indication of an intermediate state is the wave-number shift of one RR band from...... 1,562 cm-1 in the stable oxidized state through 1,535 cm-1 in the intermediate state to 1,544 cm-1 in the stable reduced state. For excitation at 413.1 nm, a band, present at 1,542 cm-1 in the stable reduced state but not present in the stable oxidized state, is absent in the intermediate state. We...

Synchrotron photoionization mass spectrometry study of intermediates in fuel-rich 1,2-dimethoxyethane flame

International Nuclear Information System (INIS)

Lin, Z. K.; Han, D. L.; Li, S. F.; Li, Y. Y.; Yuan, T.

2009-01-01

Intermediates in a fuel-rich premixed laminar 1,2-dimethoxyethane (DME) flame are studied by molecular beam mass spectrometry combined with tunable synchrotron vacuum ultraviolet photoionization. About 30 intermediate species are identified in the present work, and their mole fraction profiles are evaluated. The experimental results show that the formations of intermediates, both hydrocarbons and oxygenated hydrocarbons, are closely linked to the structure of fuel, which is consistent with the previous reports. Species produced from H atom abstraction and beta scission of DME usually have much higher concentrations than others. The oxygen atoms in DME are considered to act as partitions of the primary intermediates; therefore farther reactions among these primary intermediates are difficult to occur, resulting in absence of most large intermediate species.

A pump/intermediate heat exchanger assembly for a liquid metal reactor

International Nuclear Information System (INIS)

Nathenson, R.D.; Alexion, C.C.; Sumpman, W.C.

1987-01-01

A heat exchanger and electromagnetic pump assembly is disclosed comprising a heat exchanger housing defining an annularly shaped cavity and supporting therein a plurality of heat transfer tubes. An electromagnetic pump disposed beneath the heat exchanger comprises a circular array of flow couplers. Each flow coupler comprises a pump duct receiving primary liquid metal and a generator duct receiving a pumped intermediate liquid metal. A first plenum chamber is in communication with the generator ducts of all the flow couplers and receives intermediate liquid metal from inlet duct. The generator ducts exit their flows of intermediate liquid metal to a second plenum chamber in communication with the heat exchanger annularly shaped cavity to permit the flow of the intermediate liquid metal therethrough. A third plenum chamber receives collectively the flows of the primary liquid metal from the tubes and directs the primary liquid metal to the pump ducts of the flow couplers. The annular magnetic field of the electromagnetic pump is produced by a circular array of electromagnets having hollow windings cooled by a flow of intermediate liquid metal via tubes and manifolds. The leads to the electromagnets pass through an annular space around the inlet duct. (author)

Carbon monosulfide: a useful synthetic intermediate

International Nuclear Information System (INIS)

Kramer, M.P.

1986-01-01

The physical properties of carbon monosulfide, CS, are well documented. The molecule has been observed in interstellar space and is found to be a common intermediate in the thermal decomposition of carbon disulfide and other sulfur compounds. Interestingly enough, the chemistry of carbon monosulfide, a molecule that is isovalent with carbon monoxide, has received little attention. The explosive nature of the carbon monosulfide monomer, which hindered previous workers, was overcome by the development of special handling techniques. The ability to produce carbon monosulfide in gram quantities had lead to synthesis of novel compounds and to a more direct synthetic route for certain known compounds. Specifically, the following general reaction demonstrates the capabilities of carbon monosulfide on the synthetic scale. CS + RXY → RXC(S)Y;(X = N,S), (Y = H, Cl). Note: The initial product formed in the reaction can be an unstable intermediate

Intermediate care: for better or worse? Process evaluation of an intermediate care model between a university hospital and a residential home

Directory of Open Access Journals (Sweden)

Janmaat Tonnie ACM

2005-05-01

Full Text Available Abstract Background Intermediate care was developed in order to bridge acute, primary and social care, primarily for elderly persons with complex care needs. Such bridging initiatives are intended to reduce hospital stays and improve continuity of care. Although many models assume positive effects, it is often ambiguous what the benefits are and whether they can be transferred to other settings. This is due to the heterogeneity of intermediate care models and the variety of collaborating partners that set up such models. Quantitative evaluation captures only a limited series of generic structure, process and outcome parameters. More detailed information is needed to assess the dynamics of intermediate care delivery, and to find ways to improve the quality of care. Against this background, the functioning of a low intensity early discharge model of intermediate care set up in a residential home for patients released from an Amsterdam university hospital has been evaluated. The aim of this study was to produce knowledge for management to improve quality of care, and to provide more generalisable insights into the accumulated impact of such a model. Methods A process evaluation was carried out using quantitative and qualitative methods. Registration forms and patient questionnaires were used to quantify the patient population in the model. Statistical analysis encompassed T-tests and chi-squared test to assess significance. Semi-structured interviews were conducted with 21 staff members representing all disciplines working with the model. Interviews were transcribed and analysed using both 'open' and 'framework' approaches. Results Despite high expectations, there were significant problems. A heterogeneous patient population, a relatively unqualified staff and cultural differences between both collaborating partners impeded implementation and had an impact on the functioning of the model. Conclusion We concluded that setting up a low intensity

Heavy section steel technology program technical report No. 38. Fracture toughness characterization of HSST intermediate pressure vessel material

International Nuclear Information System (INIS)

Mager, T.R.; Yanichko, S.E.; Singer, L.R.

1974-12-01

The primary objective of the Heavy Section Steel Technology (HSST) Program is to develop pertinent fracture technology to demonstrate the structural reliability of present and contemplated water-cooled nuclear reactor pressure vessels. In order to demonstrate the ability to predict failure of large, heavy-walled pressure vessels under service type loading conditions, the fracture toughness properties of the vessel's materials must be characterized. The sampling procedure and test results are presented for vessel material supplied by the Oak Ridge National Laboratory that were used to characterize the fracture toughness of the HSST Intermediate Test Vessels. The metallurgical condition and heat treatment of the test material was representative of the vessel simulated service test condition. Test specimen locations and orientations were selected by the Oak Ridge National Laboratory and are representative of flaw orientations incorporated in the test vessels. The fracture toughness is documented for the materials from each of the eight HSST Intermediate Pressure Vessels tested to date. 7 references. (U.S.)

Low-energy consequences of superstring-inspired models with intermediate-mass scales

International Nuclear Information System (INIS)

Gabbiani, F.

1987-01-01

The phenomenological consequences of implementing intermediate-mass scales in E 6 superstring-inspired models are discussed. Starting from a suitable Calabi-Yau compactification with b 1,1 >1, one gets, after Hosotani breaking, the rank r=5 gauge group SU(3) C x SU(2) L x U(1) Y x U(1) E , that is broken at an intermediate-mass scale down to the standard-model group. The analysis of both the intermediate and the electroweak breaking is performed in the two cases Λ c = M x and Λ c x , where Λ c is the scale at which the hidden sector gauginos condensate. It is performed quantitatively the minimization of the low-energy effective potential and the renormalization group analysis, yielding a viable set of mass spectra and confirming the reliability of the intermediate-breaking scheme

ESL intermediate/advanced writing

CERN Document Server

Munoz Page, Mary Ellen; Jaskiewicz, Mary

2011-01-01

Master ESL (English as a Second Language) Writing with the study guide designed for non-native speakers of English. Skill-building lessons relevant to today's topics help ESL students write complete sentences, paragraphs, and even multi-paragraph essays. It's perfect for classroom use or self-guided writing preparation.DETAILS- Intermediate drills for improving skills with parallel structure, mood, correct shifting errors & dangling participles- Advanced essay drills focusing on narrative, descriptive, process, reaction, comparison and contrast- Superb preparation for students taking the TOEFL

Role of Glycolytic Intermediates in Global Regulation and Signal Transduction. Final Report

Energy Technology Data Exchange (ETDEWEB)

Liao, J.C.

2000-05-08

The goal of this project is to determine the role of glycolytic intermediates in regulation of cell physiology. It is known that many glycolytic intermediates are involved in regulation of enzyme activities at the kinetic level. However, little is known regarding the role of these metabolites in global regulation and signal transduction. This project aims to investigate the role of glycolytic intermediates in the regulation of gene expression.

Rising Billing for Intermediate Intensive Care among Hospitalized Medicare Beneficiaries between 1996 and 2010.

Science.gov (United States)

Sjoding, Michael W; Valley, Thomas S; Prescott, Hallie C; Wunsch, Hannah; Iwashyna, Theodore J; Cooke, Colin R

2016-01-15

Intermediate care (i.e., step-down or progressive care) is an alternative to the intensive care unit (ICU) for patients with moderate severity of illness. The adoption and current use of intermediate care is unknown. To characterize trends in intermediate care use among U.S. hospitals. We examined 135 million acute care hospitalizations among elderly individuals (≥65 yr) enrolled in fee-for-service Medicare (U.S. federal health insurance program) from 1996 to 2010. We identified patients receiving intermediate care as those with intensive care or coronary care room and board charges labeled intermediate ICU. In 1996, a total of 960 of the 3,425 hospitals providing critical care billed for intermediate care (28%), and this increased to 1,643 of 2,783 hospitals (59%) in 2010 (P billed for intermediate care, but billing steadily increased to 22.8% by 2010 (P billed for ICU care and ward-only care declined. Patients billed for intermediate care had more acute organ failures diagnoses codes compared with general ward patients (22.4% vs. 15.8%). When compared with patients billed for ICU care, those billed for intermediate care had fewer organ failures (22.4% vs. 43.4%), less mechanical ventilation (0.9% vs. 16.7%), lower mean Medicare spending ($8,514 vs. $18,150), and lower 30-day mortality (5.6% vs. 16.5%) (P billing increased markedly between 1996 and 2010. These findings highlight the need to better define the value, specific practices, and effective use of intermediate care for patients and hospitals.

File list: Oth.PSC.20.AllAg.iPSC_intermediates [Chip-atlas[Archive

Lifescience Database Archive (English)

Full Text Available Oth.PSC.20.AllAg.iPSC_intermediates mm9 TFs and others Pluripotent stem cell iPSC intermediates...7379,SRX977371,SRX977370,SRX897943,SRX1184107,SRX897941 http://dbarchive.biosciencedbc.jp/kyushu-u/mm9/assembled/Oth.PSC.20.AllAg.iPSC_intermediates.bed ...

File list: Oth.PSC.05.AllAg.iPSC_intermediates [Chip-atlas[Archive

Lifescience Database Archive (English)

Full Text Available Oth.PSC.05.AllAg.iPSC_intermediates mm9 TFs and others Pluripotent stem cell iPSC intermediates...7367,SRX977374,SRX897943,SRX977378,SRX1184107,SRX897941 http://dbarchive.biosciencedbc.jp/kyushu-u/mm9/assembled/Oth.PSC.05.AllAg.iPSC_intermediates.bed ...

File list: Oth.PSC.10.AllAg.iPSC_intermediates [Chip-atlas[Archive

Lifescience Database Archive (English)

Full Text Available Oth.PSC.10.AllAg.iPSC_intermediates mm9 TFs and others Pluripotent stem cell iPSC intermediates...7378,SRX897943,SRX977370,SRX977371,SRX1184107,SRX897941 http://dbarchive.biosciencedbc.jp/kyushu-u/mm9/assembled/Oth.PSC.10.AllAg.iPSC_intermediates.bed ...

File list: Oth.PSC.50.AllAg.iPSC_intermediates [Chip-atlas[Archive

Lifescience Database Archive (English)

Full Text Available Oth.PSC.50.AllAg.iPSC_intermediates mm9 TFs and others Pluripotent stem cell iPSC intermediates...7379,SRX977371,SRX977370,SRX897943,SRX897941,SRX1184107 http://dbarchive.biosciencedbc.jp/kyushu-u/mm9/assembled/Oth.PSC.50.AllAg.iPSC_intermediates.bed ...

Gulf-Wide Information System, Environmental Sensitivity Index Intermediate Marsh, Geographic NAD83, LDWF (2001) [esi_intermediate_marsh_LDWF_2001

Data.gov (United States)

Louisiana Geographic Information Center — This data set contains Environmental Sensitivity Index (ESI) intermediate marshes data of coastal Louisiana. The ESI is a classification and ranking system, which...

Intermediates and Generic Convergence to Equilibria

DEFF Research Database (Denmark)

Marcondes de Freitas, Michael; Wiuf, Carsten; Feliu, Elisenda

2017-01-01

Known graphical conditions for the generic and global convergence to equilibria of the dynamical system arising from a reaction network are shown to be invariant under the so-called successive removal of intermediates, a systematic procedure to simplify the network, making the graphical conditions...

Opening the Black Box of Intermediation

DEFF Research Database (Denmark)

Nowinska, Agnieszka

This paper attempts to answer how external environmental factors affect intermediating firms within the maritime industry - the middlemen that plays a very important role in the sector. The category encompasses firms such as liner and port agencies, freight forwarders and shipbrokers, who link sh...

Intermediate Filaments as Organizers of Cellular Space: How They Affect Mitochondrial Structure and Function.

Science.gov (United States)

Schwarz, Nicole; Leube, Rudolf E

2016-07-05

Intermediate filaments together with actin filaments and microtubules form the cytoskeleton, which is a complex and highly dynamic 3D network. Intermediate filaments are the major mechanical stress protectors but also affect cell growth, differentiation, signal transduction, and migration. Using intermediate filament-mitochondrial crosstalk as a prominent example, this review emphasizes the importance of intermediate filaments as crucial organizers of cytoplasmic space to support these functions. We summarize observations in different mammalian cell types which demonstrate how intermediate filaments influence mitochondrial morphology, subcellular localization, and function through direct and indirect interactions and how perturbations of these interactions may lead to human diseases.

Water infiltration into homogeneous soils: a new concept

International Nuclear Information System (INIS)

Manfredni, S.

1977-10-01

A new concept for the analytical description of the process of water infiltration into homogeneous soils is presented. The concept uses a new definition of a 'gravitational diffusivity' which permits the generalization of both cases, horizontal and vertical infiltration. The efficiency of the new concept in describing the infiltration process, for short and intermediate times, is proved through experimental data obtained during water infiltration into air-dry soil columns. Its advantages are discussed comparing soil water contents predicted by the numerical solution proposed by PHILLIP (1955, 1957) [pt

Current issues in the management of low- and intermediate-level radioactive wastes from Ontario Hydro's CANDU reactors

International Nuclear Information System (INIS)

Krasznai, J.P.; Vaughan, B.R.; Williamson, A.S.

1990-01-01

Nuclear generating stations (NGSs) in Canada are operated by utilities in Ontario, Quebec, and New Brunswick. Ontario Hydro, with a committed nuclear program of 13,600 MW(electric) is the major producer of CANDU pressurized heavy-water reactor (PHWR) low- and intermediate-level radioactive wastes. All radioactive wastes with the exception of irradiated fuel are processed and retrievably stored at a centralized facility at the Bruce Nuclear Power Development site. Solid-waste classifications and annual production levels are given. Solid-waste management practices at the site as well as the physical, chemical, and radiochemical characteristics of the wastes are well documented. The paper summarizes types, current inventory, and estimated annual production rate of liquid waste. Operation of the tritium recovery facility at Darlington NGS, which removes tritium from heavy water and produces tritium gas in the process, gives rise to secondary streams of tritiated solid and liquid wastes, which will receive special treatment and packaging. In addition to the treatment of radioactive liquid wastes, there are a number of other important issues in low- and intermediate-level radioactive waste management that Ontario Hydro will be addressing over the next few years. The most pressing of these is the reduction of radioactive wastes through in-station material control, employee awareness, and improved waste characterization and segregation programs. Since Ontario Hydro intends to store retrievable wastes for > 50 yr, it is necessary to determine the behavior of wastes under long-term storage conditions

Fission cross sections in the intermediate energy region

International Nuclear Information System (INIS)

Lisowski, P.W.; Gavron, A.; Parker, W.E.; Ullmann, J.L.; Balestrini, S.J.; Carlson, A.D.; Wasson, O.A.; Hill, N.W.

1991-01-01

Until recently there has been very little cross section data for neutron-induced fission in the intermediate energy region, primarily because no suitable neutron source has existed. At Los Alamos, the WNR target-4 facility provides a high-intensity source of neutrons nearly ideal for fission measurements extending from a fraction of a MeV to several hundred MeV. This paper summarizes the status of fission cross section data in the intermediate energy range (En > 30 MeV) and presents our fission cross section data for 235 U and 238 U compared to intranuclear cascade and statistical model predictions

Fission cross sections in the intermediate energy region

Energy Technology Data Exchange (ETDEWEB)

Lisowski, P.W.; Gavron, A.; Parker, W.E.; Ullmann, J.L.; Balestrini, S.J. (Los Alamos National Lab., NM (USA)); Carlson, A.D.; Wasson, O.A. (National Inst. of Standards and Technology, Gaithersburg, MD (USA)); Hill, N.W. (Oak Ridge National Lab., TN (USA))

1991-01-01

Until recently there has been very little cross section data for neutron-induced fission in the intermediate energy region, primarily because no suitable neutron source has existed. At Los Alamos, the WNR target-4 facility provides a high-intensity source of neutrons nearly ideal for fission measurements extending from a fraction of a MeV to several hundred MeV. This paper summarizes the status of fission cross section data in the intermediate energy range (En > 30 MeV) and presents our fission cross section data for {sup 235}U and {sup 238}U compared to intranuclear cascade and statistical model predictions.

Positron scattering by atomic hydrogen at intermediate energies

International Nuclear Information System (INIS)

Higgins, K.; Burke, P.G.; Walters, H.R.J.

1990-01-01

Results of an accurate calculation based upon the intermediate energy R-matrix theory are reported for elastic scattering of positrons by atomic hydrogen. T-matrix elements for both low and intermediate energy scattering are evaluated for the S e , P o , D e and F o partial wave symmetries. The low-energy elastic phaseshifts are found to be in good agreement with previous accurate variational calculations. Using an optical potential approach to include the effect of the higher partial waves, elastic and total cross sections are presented for energies ranging from near threshold to 3.7 Rydbergs. (author)

File list: ALL.PSC.10.AllAg.iPSC_intermediates [Chip-atlas[Archive

Lifescience Database Archive (English)

Full Text Available ALL.PSC.10.AllAg.iPSC_intermediates mm9 All antigens Pluripotent stem cell iPSC intermediates...,SRX1178446,SRX1178449,SRX1178447,SRX897944,SRX1090865,SRX684777,SRX1090866 http://dbarchive.biosciencedbc.jp/kyushu-u/mm9/assembled/ALL.PSC.10.AllAg.iPSC_intermediates.bed ...

Assessment of Southern Ocean water mass circulation and characteristics in CMIP5 models: Historical bias and forcing response

Science.gov (United States)

Sallée, J.-B.; Shuckburgh, E.; Bruneau, N.; Meijers, A. J. S.; Bracegirdle, T. J.; Wang, Z.; Roy, T.

2013-04-01

The ability of the models contributing to the fifth Coupled Models Intercomparison Project (CMIP5) to represent the Southern Ocean hydrological properties and its overturning is investigated in a water mass framework. Models have a consistent warm and light bias spread over the entire water column. The greatest bias occurs in the ventilated layers, which are volumetrically dominated by mode and intermediate layers. The ventilated layers have been observed to have a strong fingerprint of climate change and to impact climate by sequestrating a significant amount of heat and carbon dioxide. The mode water layer is poorly represented in the models and both mode and intermediate water have a significant fresh bias. Under increased radiative forcing, models simulate a warming and lightening of the entire water column, which is again greatest in the ventilated layers, highlighting the importance of these layers for propagating the climate signal into the deep ocean. While the intensity of the water mass overturning is relatively consistent between models, when compared to observation-based reconstructions, they exhibit a slightly larger rate of overturning at shallow to intermediate depths, and a slower rate of overturning deeper in the water column. Under increased radiative forcing, atmospheric fluxes increase the rate of simulated upper cell overturning, but this increase is counterbalanced by diapycnal fluxes, including mixed-layer horizontal mixing, and mostly vanishes.

Deep geologic repository for low and intermediate radioactive level waste in Canada

International Nuclear Information System (INIS)

Liu Jianqin; Li Honghui; Sun Qinghong; Yang Zhongtian

2012-01-01

Ontario Power Generation (OPG) is undergoing a project for the long-term management of low and intermediate level waste (LILW)-a deep geologic repository (DGR) project for low and intermediate level waste. The waste source term disposed, geologic setting, repository layout and operation, and safety assessment are discussed. It is expected to provide reference for disposal of low and intermediate level waste that contain the higher concentration of long-lived radionuclides in China. (authors)

Synchronization Experiments With A Global Coupled Model of Intermediate Complexity

Science.gov (United States)

Selten, Frank; Hiemstra, Paul; Shen, Mao-Lin

2013-04-01

In the super modeling approach an ensemble of imperfect models are connected through nudging terms that nudge the solution of each model to the solution of all other models in the ensemble. The goal is to obtain a synchronized state through a proper choice of connection strengths that closely tracks the trajectory of the true system. For the super modeling approach to be successful, the connections should be dense and strong enough for synchronization to occur. In this study we analyze the behavior of an ensemble of connected global atmosphere-ocean models of intermediate complexity. All atmosphere models are connected to the same ocean model through the surface fluxes of heat, water and momentum, the ocean is integrated using weighted averaged surface fluxes. In particular we analyze the degree of synchronization between the atmosphere models and the characteristics of the ensemble mean solution. The results are interpreted using a low order atmosphere-ocean toy model.

Proceedings of the Topical Meeting on the safety of nuclear fuel cycle intermediate storage facilities

International Nuclear Information System (INIS)

1998-01-01

The CSNI Working Group on Fuel Cycle Safety held an International Topical Meeting on safety aspects of Intermediate Storage Facilities in Newby Bridge, England, from 28 to 30 October 1997. The main purpose of the meeting was to provide a forum for the exchange of information on the technical issues on the safety of nuclear fuel cycle facilities (intermediate storage). Titles of the papers are: An international view on the safety challenges to interim storage of spent fuel. Interim storage of intermediate and high-level waste in Belgium: a description and safety aspects. Encapsulated intermediate level waste product stores at Sellafield. Safety of interim storage facilities of spent fuel: the international dimension and the IAEA's activities. Reprocessing of irradiated fuel and radwaste conditioning at Belgoprocess site: an overview. Retrieval of wastes from interim storage silos at Sellafield. Outline of the fire and explosion of the bituminization facility and the activities of the investigation committee (STAIJAERI). The fire and explosion incident of the bituminization facility and the lessons learned from the incident. Study on the scenario of the fire incident and related analysis. Study on the scenario of the explosion incident and related analysis. Accident investigation board report on the May 14, 1997 chemical explosion at the plutonium reclamation facility, Hanford site, Richland, Washington. Dry interim storage of spent nuclear fuel elements in Germany. Safe and effective system for the bulk receipt and storage of light water reactor fuel prior to reprocessing. Receiving and storage of glass canisters at vitrified waste storage center of Japan Nuclear Fuel Ltd. Design and operational experience of dry cask storage systems. Sellafield MOX plant; Plant safety design (BNFL). The assessment of fault studies for intermediate term waste storage facilities within the UK nuclear regulatory regime. Non-active and active commissioning of the thermal oxide

File list: ALL.PSC.50.AllAg.iPSC_intermediates [Chip-atlas[Archive

Lifescience Database Archive (English)

Full Text Available ALL.PSC.50.AllAg.iPSC_intermediates mm9 All antigens Pluripotent stem cell iPSC intermediates...44,SRX897944,SRX1178447,SRX684776,SRX684778,SRX684777,SRX1090865,SRX1090866 http://dbarchive.biosciencedbc.jp/kyushu-u/mm9/assembled/ALL.PSC.50.AllAg.iPSC_intermediates.bed ...

File list: ALL.PSC.05.AllAg.iPSC_intermediates [Chip-atlas[Archive

Lifescience Database Archive (English)

Full Text Available ALL.PSC.05.AllAg.iPSC_intermediates mm9 All antigens Pluripotent stem cell iPSC intermediates...6,SRX1184108,SRX897944,SRX1178447,SRX684778,SRX684777,SRX1090865,SRX1090866 http://dbarchive.biosciencedbc.jp/kyushu-u/mm9/assembled/ALL.PSC.05.AllAg.iPSC_intermediates.bed ...

File list: ALL.PSC.20.AllAg.iPSC_intermediates [Chip-atlas[Archive

Lifescience Database Archive (English)

Full Text Available ALL.PSC.20.AllAg.iPSC_intermediates mm9 All antigens Pluripotent stem cell iPSC intermediates...4,SRX1184108,SRX897944,SRX1178447,SRX684778,SRX1090865,SRX684777,SRX1090866 http://dbarchive.biosciencedbc.jp/kyushu-u/mm9/assembled/ALL.PSC.20.AllAg.iPSC_intermediates.bed ...

Financial intermediation with credit constrained agents

Czech Academy of Sciences Publication Activity Database

Boháček, Radim

2007-01-01

Roč. 29, č. 4 (2007), s. 741-759 ISSN 0164-0704 R&D Projects: GA AV ČR IAA700850602 Institutional research plan: CEZ:AV0Z70850503 Keywords : financial intermediation * occupational choice * general equilibrium Subject RIV: AH - Economics Impact factor: 0.360, year: 2007

Being back home after intermediate care

DEFF Research Database (Denmark)

Martinsen, Bente; Harder, Ingegerd; Norlyk, Annelise

2015-01-01

Older people may face many challenges and experience insecurity after discharge from hospital to home. To bridge the potential gap between general hospital and home, the concept ‘Intermediate Care’ (IC) was developed at the beginning of 2000. IC aims to safeguard older people from being discharge...

CONSIDERATIONS REGARDING THE DEFINITION AND CLASSIFICATION OF COMMERCIAL INTERMEDIATION

Directory of Open Access Journals (Sweden)

DAN-ALEXANDRU SITARU

2011-04-01

Full Text Available The commercial intermediation is a complex juridical operation which includes a different number of juridical relationships that takes place between contractual partners either on a national or international level. These partners bare different naming due to their different set of rights and obligations set forth by the law or by the parties, and it is from this that the classification of the intermediation can be set forth. The commercial intermediation represents the activity that one person executes either in the name and on behalf of another person, or using its own name but on behalf of another person, or, finally, using its own name but on behalf of acting towards a common goal with the person who mandated her (the principal, in relation with who it is either a proxy or an independent intermediary, only negotiating or both negotiating and binding the principal. The purpose of the paper is to strictly define and set in order the various variations of the juridical operation that is the commercial intermediation, presented both in the light of the actual legal framework and also by reference to the New Civil Code. Also, the purpose is to highlight and systematize the contractual relationships from which the parties involved in a commercial intermediary operation may choose and the rights and obligations specific to each contract.

File list: NoD.PSC.05.AllAg.iPSC_intermediates [Chip-atlas[Archive

Lifescience Database Archive (English)

Full Text Available NoD.PSC.05.AllAg.iPSC_intermediates mm9 No description Pluripotent stem cell iPSC intermediates... http://dbarchive.biosciencedbc.jp/kyushu-u/mm9/assembled/NoD.PSC.05.AllAg.iPSC_intermediates.bed ...

File list: NoD.PSC.10.AllAg.iPSC_intermediates [Chip-atlas[Archive

Lifescience Database Archive (English)

Full Text Available NoD.PSC.10.AllAg.iPSC_intermediates mm9 No description Pluripotent stem cell iPSC intermediates... http://dbarchive.biosciencedbc.jp/kyushu-u/mm9/assembled/NoD.PSC.10.AllAg.iPSC_intermediates.bed ...

File list: NoD.PSC.20.AllAg.iPSC_intermediates [Chip-atlas[Archive

Lifescience Database Archive (English)

Full Text Available NoD.PSC.20.AllAg.iPSC_intermediates mm9 No description Pluripotent stem cell iPSC intermediates... http://dbarchive.biosciencedbc.jp/kyushu-u/mm9/assembled/NoD.PSC.20.AllAg.iPSC_intermediates.bed ...

File list: NoD.PSC.50.AllAg.iPSC_intermediates [Chip-atlas[Archive

Lifescience Database Archive (English)

Full Text Available NoD.PSC.50.AllAg.iPSC_intermediates mm9 No description Pluripotent stem cell iPSC intermediates... http://dbarchive.biosciencedbc.jp/kyushu-u/mm9/assembled/NoD.PSC.50.AllAg.iPSC_intermediates.bed ...

Intermediate phase evolution in YBCO thin films grown by the TFA process

International Nuclear Information System (INIS)

Zalamova, K; Pomar, A; Palau, A; Puig, T; Obradors, X

2010-01-01

The YBCO thin film growth process from TFA precursors involves a complex reaction path which includes several oxide, fluoride and oxyfluoride intermediate phases, and the final microstructure and properties of the films are strongly influenced by the morphological and chemical evolution of these intermediate phases. In this work we present a study of the evolution of the intermediate phases involved in the TFA YBCO growth process under normal pressure conditions and we show that the oxygen partial pressure during pyrolysis of the TFA precursors is an important parameter. The Cu phase after the TFA pyrolysis can be either CuO, Cu 2 O or a mixture of both as the oxygen partial pressure is modified. The kinetics evolution of the intermediate phases has been determined for films pyrolysed in oxygen and nitrogen atmospheres and it is concluded that non-equilibrium phase transformations influence the reaction path towards epitaxial YBCO films and its microstructure. The intermediate phase evolution in these two series of films is summarized in kinetic phase diagrams.

Mediterranean Outflow Water dynamics during the past ~570 kyr : Regional and global implications

NARCIS (Netherlands)

Kaboth, Stefanie; de Boer, Bas; Bahr, André; Zeeden, Christiaan; Lourens, Lucas J.

The Gulf of Cadiz constitutes a prime area to study teleconnections between the North Atlantic Ocean and climate change in the Mediterranean realm. In particular, the highly saline Mediterranean Outflow Water (MOW) is an important modulator of the North Atlantic salt budget on intermediate water

Determination of Intermediate Resonance Parameter with RMET21 for nTRACER

International Nuclear Information System (INIS)

Sohail, Muhammad; Kim, Myung Hyun

2012-01-01

Ray Tracing based code nTRACER is being developed in Seoul National University that has the capability of 3-dimensional whole core neutron transport calculation. As a part of development of multi-group neutron cross section library for nTRACER, the current work is intended to accurately determine intermediate resonance parameters. Beside the systematic calculation of subgroup parameters for resonance self shielding calculation, intermediate resonance parameters itself can be as important as the multi-group neutron cross section in the library and its overall accuracy. In this paper lambda factors were computed using RMET21 from ENDF/B-VII.1 for nTRACER to investigate its dependence on temperature and background cross section and replaced with lambda factors from HELIOS multi-group library. The procedure used for determining the intermediate resonance parameter for the isotope under study is introduced in the next section. Oxygen being one of the primary nuclide in PWR fuel has been selected for intermediate resonance parameters calculation

Role of interference of states of intermediate nuclei in exchange processes

International Nuclear Information System (INIS)

Belyaeva, T.L.; Zelenskaya, N.S.; Teplov, I.B.

1982-01-01

Role of interference of intermediate nucleus states for exchange processes in reactions with alpha particles on 11 B, 7 Li and 6 Li light nuclei was investigated when considering exactly the process dynamics in the method of distorted waves with a finite interaction radius. The process dynamics, in particular, the overlapping degree of wave functions of bound states and interaction potentials, affects considerably the reaction cross section in the rections with alpha particles on nuclei of 1p shell. If in the reaction selection rules permit the excitation of components of intermediate system states with maximum values of #betta# 1 and #betta# 2 orbital moments at the given N 1 and N 2 , the contribution of such components to the cross section will be determining. When components of intermediate system states with maximum #betta# 1 (or #betta# 2 ) are forbidden with selection rules, several intermediate states can have approximately similar overlapping integrals

Characteristics of bank financial intermediation in Croatian counties

Directory of Open Access Journals (Sweden)

Jakša Krišto

2015-03-01

Full Text Available Research on bank financial intermediation in a country’s narrower territorial units is scarce, in both domestic and international literature. Banks are almost the only financial intermediaries in narrower territorial units and their role is substantial, ranging from participating in regional development to the successful running of their own business. Hence, the main objective of this paper is to examine the characteristics of the financial intermediation of banks in the counties of the Republic of Croatia, both through a comparison between their economic development levels and the general presence of financial intermediation, and a more specific analysis of their deposit and credit policies. The article uses hierarchical and non-hierarchical (k-means cluster analyses to identify relatively homogeneous groups of counties based on sets of indicators of: economic environment, financial development and infrastructure and, at a more detailed level, the deposit and credit policies of banks. The research results suggest heterogeneity and diversity of bank policies across the counties and sets of indicators. Differences have been observed between developed and developing counties, as well as in approaches to banks’ deposit and credit policies. The paper’s findings encourage further research into these issues.

Examining moral thinking of adolescents through intermediate concepts

Directory of Open Access Journals (Sweden)

Frichand Ana

2011-01-01

Full Text Available This study examines moral thinking of adolescents through intermediate concepts. Intermediate concepts describe a level of analysis that falls between the general default schemas defined in Kohlberg's theory and specific ethical codes. They are related to the ability to identify good and bad actions and justifications in solving specific moral dilemmas. Participants were adolescent males and females in early, middle and late adolescence. The type of education, expressed antisocial behaviour and the primary group of socialization (family were analyzed as well. The results indicate that the ability to identify good and bad actions and justifications is increasing with age. Female adolescents have higher scores on this ability than male adolescents. Individuals in late adolescence, who are concentrating more on moral values and principles during education, show higher ability in identifying bad actions and justifications. In middle adolescence those who exhibit antisocial behaviour have lower ability in identifying intermediate concepts, compared to their peers who do not show this type of behaviour. Similar results are true for those living in institutions for children without parents and parental care when compared to adolescents who are living with their parents. .

The impact of intermediate care services on job satisfaction, skills and career development opportunities.

Science.gov (United States)

Nancarrow, Susan

2007-07-01

The purpose of this study was to examine, in depth, the impact of intermediate care services on staff job satisfaction, skills development and career development opportunities. Recruitment and retention difficulties present a major barrier to the effective delivery of intermediate care services in the UK. The limited existing literature is contradictory, but points to the possibility of staff deskilling and suggests that intermediate care is poorly understood and may be seen by other practitioners as being of lower status than hospital work. These factors have the potential to reduce staff morale and limit the possibilities of recruiting staff. The research is based on interviews with 26 staff from case studies of two intermediate care services in South Yorkshire. Participants reported high levels of job satisfaction, which was because of the enabling philosophy of care, increased autonomy, the setting of care and the actual teams within which the workers were employed. For most disciplines, intermediate care facilitated the application of existing skills in a different way; enhancing some skills, while restricting the use of others. Barriers to career development opportunities were attributed to the relative recency of intermediate care services, small size of the services and lack of clear career structures. Career development opportunities in intermediate care could be improved through staff rotations through acute, community and intermediate care to increase their awareness of the roles of intermediate care staff. The non-hierarchical management structures limits management career development opportunities, instead, there is a need to enhance professional growth opportunities through the use of consultant posts and specialization within intermediate care. This study provides insight into the impact of an increasingly popular model of care on the roles and job satisfaction of workers and highlights the importance of this learning for recruitment and retention of

[Intermediate energy nuclear physics

International Nuclear Information System (INIS)

1989-01-01

This report summarizes work in experimental Intermediate Energy Nuclear Physics carried out between October 1, 1988 and October 1, 1989 at the Nuclear Physics Laboratory of the University of Colorado, Boulder, under grant DE-FG02-86ER-40269 with the United States Department of Energy. The experimental program is very broadly based, including pion-nucleon studies at TRIUMF, inelastic pion scattering and charge exchange reactions at LAMPF, and nucleon charge exchange at LAMPF/WNR. In addition, a number of other topics related to accelerator physics are described in this report

PNGMDR - Characterisation of intermediate-level long-lived wastes

International Nuclear Information System (INIS)

2014-12-01

This document presents the status of the characterization of intermediate-level long-lived wastes which are warehoused on exploited EDF sites or which will be produced during the deconstruction of first-generation reactors. It addresses aspects related to characterisation and packaging of wastes produced before 2015. More specifically, it addresses aspects related to contamination and to activation. Contamination is assessed by measurements whereas activation assessment is based on numerical simulations associated with measurements performed during parcel production. After having mentioned the concerned reactors, the document presents the methodology adopted for these assessments, and reports the progress status of the characterization process for these intermediate-level long-lived wastes

Spacing Sensitivity Analysis of HLW Intermediate Storage Facility

International Nuclear Information System (INIS)

Youn, Bum Soo; Lee, Kwang Ho

2010-01-01

Currently, South Korea's spent fuels are stored in its temporary storage within the plant. But the temporary storage is expected to be reaching saturation soon. For the effective management of spent fuel wastes, the need for intermediate storage facility is a desperate position. However, the research for the intermediate storage facility for waste has not made active so far. In addition, in case of foreign countries it is mostly treated confidentially and the information isn't easy to collect. Therefore, the purpose of this study is creating the basic thermal analysis data for the waste storage facility that will be valuable in the future

How Do Transfer Students Perform in Economics? Evidence from Intermediate Macroeconomics

Science.gov (United States)

Asarta, Carlos J.; Fuess, Scott M., Jr.; Perumal, Andrew

2013-01-01

For students taking intermediate-level economics, does it matter where they studied principles of economics? Does transferring college credit influence subsequent academic performance in economics? With a sample covering 1999-2008, the authors analyze in this article a group of nearly 1,000 students taking intermediate macroeconomics at a…

Visible-Light-Driven Valorization of Biomass Intermediates Integrated with H2 Production Catalyzed by Ultrathin Ni/CdS Nanosheets.

Science.gov (United States)

Han, Guanqun; Jin, Yan-Huan; Burgess, R Alan; Dickenson, Nicholas E; Cao, Xiao-Ming; Sun, Yujie

2017-11-08

Photocatalytic upgrading of crucial biomass-derived intermediate chemicals (i.e., furfural alcohol, 5-hydroxymethylfurfural (HMF)) to value-added products (aldehydes and acids) was carried out on ultrathin CdS nanosheets (thickness ∼1 nm) decorated with nickel (Ni/CdS). More importantly, simultaneous H 2 production was realized upon visible light irradiation under ambient conditions utilizing these biomass intermediates as proton sources. The remarkable difference in the rates of transformation of furfural alcohol and HMF to their corresponding aldehydes in neutral water was observed and investigated. Aided by theoretical computation, it was rationalized that the slightly stronger binding affinity of the aldehyde group in HMF to Ni/CdS resulted in the lower transformation of HMF to 2,5-diformylfuran compared to that of furfural alcohol to furfural. Nevertheless, photocatalytic oxidation of furfural alcohol and HMF under alkaline conditions led to complete transformation to the respective carboxylates with concomitant production of H 2 .

Electrochemical and Spectroscopic Study of Mononuclear Ruthenium Water Oxidation Catalysts: A Combined Experimental and Theoretical Investigation

KAUST Repository

de Ruiter, J. M.

2016-09-20

One of the key challenges in designing light-driven artificial photosynthesis devices is the optimization of the catalytic water oxidation process. For this optimization it is crucial to establish the catalytic mechanism and the intermediates of the catalytic cycle, yet a full description is often difficult to obtain using only experimental data. Here we consider a series of mononuclear ruthenium water oxidation catalysts of the form [Ru(cy)(L)(H2O)](2+) (cy = p-cymene, L = 2,2\\'-bipyridine and its derivatives). The proposed catalytic cycle and intermediates are examined using density functional theory (DFT), radiation chemistry, spectroscopic techniques, and electrochemistry to establish the water oxidation mechanism. The stability of the catalyst is investigated using online electrochemical mass spectrometry (OLEMS). The comparison between the calculated absorption spectra of the proposed intermediates with experimental spectra, as well as free energy calculations with electrochemical data, provides strong evidence for the proposed pathway: a water oxidation catalytic cycle involving four proton-coupled electron transfer (PCET) steps. The thermodynamic bottleneck is identified as the third PCET step, which involves O-O bond formation. The good agreement between the optical and thermodynamic data and DFT predictions further confirms the general applicability of this methodology as a powerful tool in the characterization of water oxidation catalysts and for the interpretation of experimental observables.

C and C* among intermediate rings

NARCIS (Netherlands)

Sack, J.; Watson, S.

2014-01-01

Given a completely regular Hausdorff space X, an intermediate ring A(X) is a ring of real valued continuous functions between C*(X) and C(X). We discuss two correspondences between ideals in A(X) and z-filters on X, both reviewing old results and introducing new results. One correspondence, ZA,

Intermediate Temperature Fuel Cell Using Gypsum Based Electrolyte And Electrodes

International Nuclear Information System (INIS)

Suzuki, Satoshi; Nagai, Masayuki; Katagiri, Yuji

2011-01-01

The proton conductive electrolyte membrane and the electrodes for intermediate temperature fuel cell were made from the phosphoric acid treated gypsum as a proton conductor. The membrane and the electrodes were built into single cell and tested at intermediate temperature region. The power density of the fuel cell was 0.56 mW/cm -2 at 150 deg. C without any humidification and 1.38 mW/cm -2 at 150 deg. C, 5% relative humidity. The open circuit voltage of the cell was increased higher than 0.7 V when the electrodes were annealed at 150 deg. C, 5%R.H., however the reasons for this are still to be further investigated. The results show that the potential of the phosphoric acid treated gypsum for the intermediate temperature proton conductor.

On intermediate structures in heavy ion reactions

International Nuclear Information System (INIS)

Rotter, I.

1977-01-01

The conceptions of the nuclear reaction theory are reinvestigated on the basis of the continuum shell model. The correlation of the resonance states via the continuum can lead to intermediate structures in the cross section. (Auth.)

Alternatives generation and analysis for phase I intermediate waste feed staging system design requirements

Energy Technology Data Exchange (ETDEWEB)

Britton, M.D.

1996-10-02

This document provides; a decision analysis summary; problem statement; constraints, requirements, and assumptions; decision criteria; intermediate waste feed staging system options and alternatives generation and screening; intermediate waste feed staging system design concepts; intermediate waste feed staging system alternative evaluation and analysis; and open issues and actions.

The deep Canary poleward undercurrent

Science.gov (United States)

Velez-Belchi, P. J.; Hernandez-Guerra, A.; González-Pola, C.; Fraile, E.; Collins, C. A.; Machín, F.

2012-12-01

Poleward undercurrents are well known features in Eastern Boundary systems. In the California upwelling system (CalCEBS), the deep poleward flow has been observed along the entire outer continental shelf and upper-slope, using indirect methods based on geostrophic estimates and also using direct current measurements. The importance of the poleward undercurrents in the CalCEBS, among others, is to maintain its high productivity by means of the transport of equatorial Pacific waters all the way northward to Vancouver Island and the subpolar gyre but there is also concern about the low oxygen concentration of these waters. However, in the case of the Canary Current Eastern Boundary upwelling system (CanCEBS), there are very few observations of the poleward undercurrent. Most of these observations are short-term mooring records, or drifter trajectories of the upper-slope flow. Hence, the importance of the subsurface poleward flow in the CanCEBS has been only hypothesized. Moreover, due to the large differences between the shape of the coastline and topography between the California and the Canary Current system, the results obtained for the CalCEBS are not completely applicable to the CanCEBS. In this study we report the first direct observations of the continuity of the deep poleward flow of the Canary Deep Poleward undercurrent (CdPU) in the North-Africa sector of the CanCEBS, and one of the few direct observations in the North-Africa sector of the Canary Current eastern boundary. The results indicate that the Canary Island archipelago disrupts the deep poleward undercurrent even at depths where the flow is not blocked by the bathymetry. The deep poleward undercurrent flows west around the eastern-most islands and north east of the Conception Bank to rejoin the intermittent branch that follows the African slope in the Lanzarote Passage. This hypothesis is consistent with the AAIW found west of Lanzarote, as far as 17 W. But also, this hypothesis would be coherent

Feasibility study on vitrification of low- and intermediate-level radioactive waste from pressurized water reactors

International Nuclear Information System (INIS)

Park, J.K.; Song, M.J.

1998-01-01

In order to obtain annual generation volume and composition data for low- and intermediate-level radioactive waste (LILW), characteristics and generation trends for each waste which was produced at nuclear power plants (NPPs) in Korea were investigated. Of the three different types of melters, the platinum crucible was found to be most suitable for the performance of vitrification experiments and hence, was used to help better understand the optimal waste contents in borosilicate glass waste forms with respect to waste types. After the performance of vitrification experiments, compressive strength tests showed that the final waste glass product, containing up to 40 vol% of ashy pyrolyzed/oxidized at 400--800 C, showed good mechanical stability and homogeneity in the glass matrix. Economical assessment was performed with some considerations given for equipment having already been adopted for LILW treatment in Korea for four treatment strategies with melters selected from a technical assessment. For each strategy, the capital and the operation cost were estimated, and the disposal volume was calculated with reasonably estimated volume reduction factors with regard to waste type and treatment concept

Software Testing An ISEB Intermediate Certificate

CERN Document Server

Hambling, Brian

2009-01-01

Covering testing fundamentals, reviews, testing and risk, test management and test analysis, this book helps newly qualified software testers to learn the skills and techniques to take them to the next level. Written by leading authors in the field, this is the only official textbook of the ISEB Intermediate Certificate in Software Testing.

Heavy-Section Steel Technology Program intermediate-scale pressure vessel tests

International Nuclear Information System (INIS)

Bryan, R.H.; Merkle, J.G.; Smith, G.C.; Whitman, G.D.

1977-01-01

The tests of intermediate-size vessels with sharp flaws permitted the comparison of experimentally observed behavior with analytical predictions of the behavior of flawed pressure vessels. Fracture strains estimated by linear elastic fracture mechanics (LEFM) were accurate in the cases in which the flaws resided in regions of high transverse restraint and the fracture toughness was sufficiently low for unstable fracture to occur prior to yielding through the vessel wall. When both of these conditions were not present, unstable fracture did occur, always preceded by stable crack growth; and the cylinders with flaws initially less than halfway through the wall attained gross yield prior to burst. Predictions of failure pressure of the vessels with flawed nozzles, based upon LEFM estimates of failure strain, were very conservative. LEFM calculations of critical load were based upon small-specimen fracture toughness test data. Whenever gross yielding preceded failure, the actual strains achieved were considerably greater than the estimated strains at failure based on LEFM. In such cases the strength of the vessel may be no longer dependent upon plane-strain fracture toughness but upon the capacity of the cracked section to carry the imposed load stably in the plastic range. Stable crack growth, which has not been predictable quantitatively, is an important factor in elastic-plastic analysis of strength. The ability of the flawed vessels to attain gross yield in unflawed sections has important qualitative implications on pressure vessel safety margins. The gross yield condition occurs in light-water-reactor pressure vessels at about 2 x design pressure. The intermediate vessel tests that demonstrated a capacity for exceeding this load confirm that the presumed margin of safety is not diminished by the presence of flaws of substantial size, provided that material properties are adequate

Millennial-scale variations of late Pleistocene radiolarian assemblages in the Bering Sea related to environments in shallow and deep waters

Science.gov (United States)

Itaki, Takuya; Kim, Sunghan; Rella, Stephan F.; Uchida, Masao; Tada, Ryuji; Khim, Boo-Keun

2012-02-01

A high-resolution record of the radiolarian assemblage from 60 to 10 ka was investigated using a piston core (PC-23A) obtained from the northern slope of the Bering Sea. Faunal changes based on the 29 major radiolarian taxa demonstrated that the surface and deep water conditions in the Bering Sea were related to the orbital and millennial-scale climatic variations known as glacial-interglacial and Dansgaard-Oeschger (D-O) cycles, respectively. During interstadial periods of the D-O cycles, the assemblage was characterized by increases in the high-latitude coastal species Rhizoplegma boreale and the upper-intermediate water species Cycladophora davisiana, while the sea-ice related species Actinomma boreale and A. leptodermum and many deep-water species such as Dictyophimus crisiae and D. hirundo tended to be reduced. This trend was more apparent in two laminated intervals at 15-13.5 and 11.5-11 ka, which were correlated with well-known ice-sheet collapse events that occurred during the last deglaciation: melt-water pulse (MWP)-1A and MWP-1B, respectively. The radiolarian faunal composition in these periods suggests that oceanic conditions were different from today: (1) surface water was affected by increased melt-water discharge from continental ice-sheet, occurring at the same time as an abrupt increase in atmospheric temperature, (2) upper-intermediate water (ca. 200-500 m) was well-ventilated and organic-rich, and (3) lower-intermediate water (ca. 500-1000 m) was oxygen-poor. Conversely, the sea-ice season might have been longer during stadial periods of the D-O cycles and the last glacial maximum (LGM) compared to the interstadial periods and the earliest Holocene. In these colder periods, deep-water species were very abundant, and this corresponded to increases in the oxygen isotope value of benthic foraminifera. Our findings suggest that the oxygen-rich water was present in the lower-intermediate layer resulting from intensified ventilation.

Femtochemistry of confined water

Science.gov (United States)

Douhal, A.; Carranza, M. A.; Sanz, M.; Organero, J. A.; Santos, L.

In this contribution, we applied ultrafast spectroscopy to study the H-bond network of water confined in nanostructures (Cyclodextrins and Micelles). We examine the effect of caging on ultrafast reaction dynamics and discuss the related processes under different experimental conditions. The results show an ultrafast dynamic giving birth to intermediates of the probe, which show femtosecond and picosecond dynamics leading to the final structure at the excited state. The results show the high sensitivity of the used technique in detecting small of water. This work was supported by the Ministry of Science and Technology (MCYT, Spain) and ``Conserjería de Ciencia y Tecnologia de la JCCM, Spain'' through projects MAT2002-01829 and PAI-02-004.

Reactive intermediates in the gas phase generation and monitoring

CERN Document Server

Setser, D W

2013-01-01

Reactive Intermediates in the Gas Phase: Generation and Monitoring covers methods for reactive intermediates in the gas phase. The book discusses the generation and measurement of atom and radical concentrations in flow systems; the high temperature flow tubes, generation and measurement of refractory species; and the electronically excited long-lived states of atoms and diatomic molecules in flow systems. The text also describes the production and detection of reactive species with lasers in static systems; the production of small positive ions in a mass spectrometer; and the discharge-excite

Stingray-inspired robot with simply actuated intermediate motion

Science.gov (United States)

Neely, Lincoln; Gaiennie, Jack; Noble, Nick; Erickson, Jonathan C.

2016-04-01

Batoids, or rays, utilize unique forms of locomotion that may offer more efficient techniques of motorized propulsion in various marine environments. We present a novel biomimetic engineering design and assembly of a stingray-inspired robot swimmer. The robots locomotion mimics the Dasyatis americana, or southern stingray, whose distinction among rays is its intermediate motion, characterized by sweeping strokes that propagate between 1/2-1 wavelength of the fin profile in the posterior direction. Though oscillatory ( wavelengths) ray-based robots have been created, this project demonstrates new engineering possibilities in what is, to the best of our knowledge, the first intermediately propelled batoid-based robot. The robots fins were made of silicone rubber, cast in a 3-D printed mold, with wingspan of 42 cm (1/2 - 1/5 scale for males and females, respectively, scale of model organism). Two anteriorly placed servomotors per fin were used, all controlled by one wirelessly enabled Arduino microcontroller. Each servomotor oscillated a flexible rod with cylindrical joint, whose frequency, speed, and front-back phase delay were user-programmed over wireless connection. During free-swimming tests, the fin profile developed about 0.8 wavelength, qualifying for successful mimicry of its biological inspiration. The robot satisfactorily maintained straight-line motion, reaching average peak velocity of 9.4+/-1.0 cm/s (0.27-0.03 body lengths/second) at its optimum flapping frequency of 1.4 Hz. This is in the same order of magnitude of speed normalized to body length achieved by others in two recent batoid-based projects. In summary, our robot performed intermediate stingray locomotion with relatively fewer components, which reveals robust potential for innovation of the simple intermediate batoid-based robot swimmer.

Analysis and solution of spike current of intermediate range for nuclear instrumentation system

International Nuclear Information System (INIS)

Li Xingqiang; Xiao Yu; Xue Bin; Wang Yinli

2015-01-01

During the initial start-up of HYH NPP unit 1, spike currents occurred in intermediate range channel of RPN system and reactor trip was triggered. After analyzing the operation principle of intermediate range channel and site inspection, and doing simulating test, the root cause was fixed on the bug of range switching of intermediate range channel. Then a solution based on parameters optimizing was made and executed on site. (authors)

Connecting demand and supply: The role of intermediation in public procurement of innovation

OpenAIRE

Yeow, Jillian; Edler, Jakob

2015-01-01

open access article Intermediation in innovation serves to establish or improve the link between different actors with complementary skill sets or interests in order to support the generation and diffusion of innovation. This article conceptualises and analyses intermediation between supply and demand using the example of public procurement of innovation. It defines specific intermediation needs and functions in different procurement situations and outlines the pre-condition for effective ...

Correlated Default and Financial Intermediation

OpenAIRE

Gregory Phelan

2015-01-01

Financial intermediation naturally arises when knowledge about the aggregate state is valuable for managing investments and lenders cannot easily observe the aggregate state. I show this using a costly enforcement model in which lenders need ex-post incentives to enforce payments from defaulted loans and borrowers' payoffs are correlated. When projects have correlated outcomes, learning the state of one project (via enforcement) provides information about the states of other projects. A large...

Lifetime enhancement for multiphoton absorption in intermediate band solar cells

International Nuclear Information System (INIS)

Bezerra, Anibal T; Studart, Nelson

2017-01-01

A semiconductor structure consisting of two coupled quantum wells embedded into the intrinsic region of a p – i–n junction is proposed as an intermediate band solar cell with a photon ratchet state, which would lead to increasing the cell efficiency. The conduction subband of the right-hand side quantum well works as the intermediated band, whereas the excited conduction subband of the left-hand side quantum well operates as the ratchet state. The photoelectrons in the intermediate band are scattered through the thin wells barrier and accumulated into the ratchet subband. A rate equation model for describing the charge transport properties is presented. The efficiency of the current generation is analyzed by studying the occupation of the wells subbands, taking into account the charge dynamic behavior provided by the electrical contacts connected to the cell. The current generation efficiency depends essentially from the relations between the generation, recombination rates and the scattering rate to the ratchet state. The inclusion of the ratchet states led to both an increase and a decrease in the cell current depending on the transition rates. This suggests that the coupling between the intermediate band and the ratchet state is a key point in developing an efficient solar cell. (paper)

Lifetime enhancement for multiphoton absorption in intermediate band solar cells

Science.gov (United States)

Bezerra, Anibal T.; Studart, Nelson

2017-08-01

A semiconductor structure consisting of two coupled quantum wells embedded into the intrinsic region of a p-i-n junction is proposed as an intermediate band solar cell with a photon ratchet state, which would lead to increasing the cell efficiency. The conduction subband of the right-hand side quantum well works as the intermediated band, whereas the excited conduction subband of the left-hand side quantum well operates as the ratchet state. The photoelectrons in the intermediate band are scattered through the thin wells barrier and accumulated into the ratchet subband. A rate equation model for describing the charge transport properties is presented. The efficiency of the current generation is analyzed by studying the occupation of the wells subbands, taking into account the charge dynamic behavior provided by the electrical contacts connected to the cell. The current generation efficiency depends essentially from the relations between the generation, recombination rates and the scattering rate to the ratchet state. The inclusion of the ratchet states led to both an increase and a decrease in the cell current depending on the transition rates. This suggests that the coupling between the intermediate band and the ratchet state is a key point in developing an efficient solar cell.

Management applicability of the intermediate disturbance hypothesis across Mongolian rangeland ecosystems.

Science.gov (United States)

Sasaki, Takehiro; Okubo, Satoru; Okayasu, Tomoo; Jamsran, Undarmaa; Ohkuro, Toshiya; Takeuchi, Kazuhiko

2009-03-01

The current growing body of evidence for diversity-disturbance relationships suggests that the peaked pattern predicted by the intermediate disturbance hypothesis (IDH) may not be the rule. Even if ecologists could quantify the diversity-disturbance relationship consistent with the IDH, the applicability of the IDH to land management has rarely been addressed. We examined two hypotheses related to the generality and management applicability of the IDH to Mongolian rangeland ecosystems: that the diversity-disturbance relationship varies as a function of landscape condition and that some intermediate scales of grazing can play an important role in terms of sustainable rangeland management through a grazing gradient approach. We quantified the landscape condition of each ecological site using an ordination technique and determined two types of landscape conditions: relatively benign and harsh environmental conditions. At the ecological sites characterized by relatively benign environmental conditions, diversity-disturbance relationships were generally consistent with the IDH, and maximum diversity was observed at some intermediate distance from the source of the grazing gradient. In contrast, the IDH was not supported at most (but not all) sites characterized by relatively harsh environmental conditions. The intermediate levels of grazing were generally located below the ecological threshold representing the points or zones at which disturbance should be limited to prevent drastic changes in ecological conditions, suggesting that there is little "conundrum" with regard to intermediate disturbance in the studied systems in terms of land management. We suggest that the landscape condition is one of the primary factors that cause inconsistencies in diversity-disturbance relationships. The ecological threshold can extend its utility in rangeland management because it also has the compatibility with the maintenance of species diversity. This study thus suggests that some

Transarterial chemoembolization versus resection for intermediate-stage (BCLC B hepatocellular carcinoma

Directory of Open Access Journals (Sweden)

Jun Young Kim

2016-06-01

Full Text Available Background/Aims: Several studies have suggested that surgical resection (SR can provide a survival benefit over transarterial chemoembolization (TACE for hepatocellular carcinoma (HCC at the intermediate stage according to the Barcelona Clinic Liver Cancer (BCLC staging system. However, the criteria for SR remain to be determined. This study compared the long-term outcome of intermediate-stage HCC patients treated by either TACE or SR as a primary treatment modality, with the aim of identifying the patient subgroup that gained a survival benefit by either modality. Methods: In total, 277 BCLC intermediate-stage HCC patients treated by either TACE (N=225 or SR (N=52 were analyzed. Results: The overall median survival time was significantly better for SR than TACE (61 vs. 30 months, P=0.002. Decision-tree analysis divided patients into seven nodes based on tumor size and number, serum alpha-fetoprotein (AFP level, and Child-Pugh score, and these were then simplified into four subgroups (B1–B4 based on similarities in the overall hazard rate. SR provided a significant survival benefit in subgroup B2, characterized by ‘oligo’ (2–4 nodules of intermediate size (5–10 cm when the AFP levels was <400 ng/ml, or ‘oligo’ (2–4 nodules of small to intermediate size (<10 cm plus a Child-Pugh score of 5 when the AFP level was ≥400 ng/mL (median survival 73 vs. 28 months for SR vs. TACE respectively; P=0.014. The survival rate did not differ significantly between SR and TACE in the other subgroups (B1 and B3. Conclusion: SR provided a survival benefit over TACE in intermediate-stage HCC, especially for patients meeting certain criteria. Re-establishing the criteria for optimal treatment modalities in this stage of HCC is needed to improve survival rates.

Memory Monitoring and Control in Young and Intermediate-Age Adults

Directory of Open Access Journals (Sweden)

Maxciel Zortea

2015-08-01

Full Text Available The way adults perceive and regulate learning (metamemory is an important indicator of how they perform on memory tasks. This study assessed memory monitoring, control and performance in young and intermediate-age adults according to item type (with or without semantic relation, type of judgment of learning (JOL - immediate or delayed, and age. Twenty-six young adults (M = 22 years old and 18 intermediate-age adults (M = 47 years old participated, who responded to an experimental paradigm to evaluate metamemory. Results showed that related word-pairs received higher magnitude for the JOLs and better cued-recall scores. JOLs’ accuracy was similar between the age groups, delayed JOLs being more accurate only for young adults. Intermediate-age adults apparently based their allocation of study time less on JOLs or cued-recall than young adults.

File list: InP.PSC.20.AllAg.iPSC_intermediates [Chip-atlas[Archive

Lifescience Database Archive (English)

Full Text Available InP.PSC.20.AllAg.iPSC_intermediates mm9 Input control Pluripotent stem cell iPSC intermediates...178446,SRX1178444,SRX1178449,SRX1184108,SRX897944,SRX1178447 http://dbarchive.biosciencedbc.jp/kyushu-u/mm9/assembled/InP.PSC.20.AllAg.iPSC_intermediates.bed ...

File list: InP.PSC.50.AllAg.iPSC_intermediates [Chip-atlas[Archive

Lifescience Database Archive (English)

Full Text Available InP.PSC.50.AllAg.iPSC_intermediates mm9 Input control Pluripotent stem cell iPSC intermediates...178448,SRX1178449,SRX1184108,SRX1178444,SRX897944,SRX1178447 http://dbarchive.biosciencedbc.jp/kyushu-u/mm9/assembled/InP.PSC.50.AllAg.iPSC_intermediates.bed ...

File list: InP.PSC.05.AllAg.iPSC_intermediates [Chip-atlas[Archive

Lifescience Database Archive (English)

Full Text Available InP.PSC.05.AllAg.iPSC_intermediates mm9 Input control Pluripotent stem cell iPSC intermediates...178445,SRX1178449,SRX1178446,SRX1184108,SRX897944,SRX1178447 http://dbarchive.biosciencedbc.jp/kyushu-u/mm9/assembled/InP.PSC.05.AllAg.iPSC_intermediates.bed ...

File list: InP.PSC.10.AllAg.iPSC_intermediates [Chip-atlas[Archive

Lifescience Database Archive (English)

Full Text Available InP.PSC.10.AllAg.iPSC_intermediates mm9 Input control Pluripotent stem cell iPSC intermediates...184108,SRX1178445,SRX1178446,SRX1178449,SRX1178447,SRX897944 http://dbarchive.biosciencedbc.jp/kyushu-u/mm9/assembled/InP.PSC.10.AllAg.iPSC_intermediates.bed ...

Effects Disposal Condition and Ground Water to Leaching Rate of Radionuclides from Solidification Products

International Nuclear Information System (INIS)

Herlan Martono; Wati

2008-01-01

Effects disposal condition and ground water to leaching rate of radionuclides from solidification products have been studied. The aims of leaching test at laboratory to get the best composition of solidified products for continuous process or handling. The leaching rate of radionuclides from the many kinds of matrix from smallest to bigger are glass, thermosetting plastic, urea formaldehyde, asphalt, and cement. Glass for solidification of high level waste, thermosetting plastic and urea formaldehyde for solidification of low and intermediate waste, asphalt and cement for solidification of low and intermediate level waste. In shallow land burial, ground water rate is fast, debit is high, and high permeability, so the probability contact between solidification products and ground water is occur. The pH of ground water increasing leaching rate, but cation in the ground water retard leaching rate. Effects temperature radiation and radiolysis to solidification products is not occur. In the deep repository, ground water rate is slow, debit is small, and low permeability, so the probability contact between solidification products and ground water is very small. There are effect cooling time and distance between pits to rock temperature. Alfa radiation effects can be occur, but there is no contact between solidification products and ground water, so that there is not radiolysis. (author)

Improved enzymatic production of phenolated glycerides through alkyl phenolate intermediate

DEFF Research Database (Denmark)

Yang, Zhiyong; Feddern, Vivian; Glasius, Marianne

2011-01-01

This work reported a novel approach for synthesis of dihydrocaffoylated glycerides, consisting of 2 steps: enzymatic synthesis of octyl dihydrocaffeate (as a synthetic intermediate) from octanol and dihydrocaffeic acid (DHCA), and enzymatic interesterification of triglycerides with octyl dihydroc......This work reported a novel approach for synthesis of dihydrocaffoylated glycerides, consisting of 2 steps: enzymatic synthesis of octyl dihydrocaffeate (as a synthetic intermediate) from octanol and dihydrocaffeic acid (DHCA), and enzymatic interesterification of triglycerides with octyl...

Electron microscopic analysis of rotavirus assembly-replication intermediates

International Nuclear Information System (INIS)

Boudreaux, Crystal E.; Kelly, Deborah F.; McDonald, Sarah M.

2015-01-01

Rotaviruses (RVs) replicate their segmented, double-stranded RNA genomes in tandem with early virion assembly. In this study, we sought to gain insight into the ultrastructure of RV assembly-replication intermediates (RIs) using transmission electron microscopy (EM). Specifically, we examined a replicase-competent, subcellular fraction that contains all known RV RIs. Three never-before-seen complexes were visualized in this fraction. Using in vitro reconstitution, we showed that ~15-nm doughnut-shaped proteins in strings were nonstructural protein 2 (NSP2) bound to viral RNA transcripts. Moreover, using immunoaffinity-capture EM, we revealed that ~20-nm pebble-shaped complexes contain the viral RNA polymerase (VP1) and RNA capping enzyme (VP3). Finally, using a gel purification method, we demonstrated that ~30–70-nm electron-dense, particle-shaped complexes represent replicase-competent core RIs, containing VP1, VP3, and NSP2 as well as capsid proteins VP2 and VP6. The results of this study raise new questions about the interactions among viral proteins and RNA during the concerted assembly–replicase process. - Highlights: • Rotaviruses replicate their genomes in tandem with early virion assembly. • Little is known about rotavirus assembly-replication intermediates. • Assembly-replication intermediates were imaged using electron microscopy

Electron microscopic analysis of rotavirus assembly-replication intermediates

Energy Technology Data Exchange (ETDEWEB)

Boudreaux, Crystal E.; Kelly, Deborah F. [Virginia Tech Carilion School of Medicine and Research Institute, Roanoke, VA (United States); McDonald, Sarah M., E-mail: mcdonaldsa@vtc.vt.edu [Virginia Tech Carilion School of Medicine and Research Institute, Roanoke, VA (United States); Department of Biomedical Sciences and Pathobiology, Virginia—Maryland Regional College of Veterinary Medicine, Blacksburg, VA (United States)

2015-03-15

Rotaviruses (RVs) replicate their segmented, double-stranded RNA genomes in tandem with early virion assembly. In this study, we sought to gain insight into the ultrastructure of RV assembly-replication intermediates (RIs) using transmission electron microscopy (EM). Specifically, we examined a replicase-competent, subcellular fraction that contains all known RV RIs. Three never-before-seen complexes were visualized in this fraction. Using in vitro reconstitution, we showed that ~15-nm doughnut-shaped proteins in strings were nonstructural protein 2 (NSP2) bound to viral RNA transcripts. Moreover, using immunoaffinity-capture EM, we revealed that ~20-nm pebble-shaped complexes contain the viral RNA polymerase (VP1) and RNA capping enzyme (VP3). Finally, using a gel purification method, we demonstrated that ~30–70-nm electron-dense, particle-shaped complexes represent replicase-competent core RIs, containing VP1, VP3, and NSP2 as well as capsid proteins VP2 and VP6. The results of this study raise new questions about the interactions among viral proteins and RNA during the concerted assembly–replicase process. - Highlights: • Rotaviruses replicate their genomes in tandem with early virion assembly. • Little is known about rotavirus assembly-replication intermediates. • Assembly-replication intermediates were imaged using electron microscopy.

Studies on corrosion of mild steel by water using Moessbauer spectroscopy

International Nuclear Information System (INIS)

Nigam, A.N.; Tripathi, R.P.; Jangid, M.L.

1987-01-01

The corrosion of mild steel as a result of interaction with various types of local natural water samples and distilled water is studied with the help of Moessbauer spectroscopy. The data are supplemented with the studies on IR and magnetic properties as and when required. Distilled water and potable water behave in almost similar fashion wherein ferrihydrite and FeOOH are observed to be the precursors of magnetite, the end corrosion product. In case of brakish water, the additional species, viz., FeCl 2 , βFeOOH and an intermediate possibly FeOCl are accounted, and possible mechanisms are suggested. (author)

Understanding the interface between silicon-based materials and water: Molecular-dynamics exploration of infrared spectra

Directory of Open Access Journals (Sweden)

José A. Martinez-Gonzalez

2017-11-01

Full Text Available Molecular-dynamics simulations for silicon, hydrogen- and hydroxyl-terminated silicon in contact with liquid water, at 220 and 300 K, display water-density ‘ordering’ along the laboratory z-axis, emphasising the hydrophobicity of the different systems and the position of this first adsorbed layer. Density of states (DOS of the oxygen and proton velocity correlation functions (VACFs and infrared (IR spectra of the first monolayer of adsorbed water, calculated via Fourier transformation, indicate similarities to more confined, ice-like dynamical behaviour (redolent of ice. It was observed that good qualitative agreement is obtained between the DOS for this first layer in all systems. The DOS for the lower-frequency zone indicates that for the interface studied (i.e., the first layer near the surface, the water molecules try to organise in a similar form, and that this form is intermediate between liquid water and ice. For IR spectra, scrutiny of the position of the highest-intensity peaks for the stretching and bending bands indicate that such water molecules in the first solvating layer are organised in an intermediate fashion between ice and liquid water.

Intermediates and the folding of proteins L and G

Energy Technology Data Exchange (ETDEWEB)

Brown, Scott; Head-Gordon, Teresa

2003-07-01

We use a minimalist protein model, in combination with a sequence design strategy, to determine differences in primary structure for proteins L and G that are responsible for the two proteins folding through distinctly different folding mechanisms. We find that the folding of proteins L and G are consistent with a nucleation-condensation mechanism, each of which is described as helix-assisted {beta}-1 and {beta}-2 hairpin formation, respectively. We determine that the model for protein G exhibits an early intermediate that precedes the rate-limiting barrier of folding and which draws together misaligned secondary structure elements that are stabilized by hydrophobic core contacts involving the third {beta}-strand, and presages the later transition state in which the correct strand alignment of these same secondary structure elements is restored. Finally the validity of the targeted intermediate ensemble for protein G was analyzed by fitting the kinetic data to a two-step first order reversible reaction, proving that protein G folding involves an on-pathway early intermediate, and should be populated and therefore observable by experiment.

Bridge: Intelligent Tutoring with Intermediate Representations

Science.gov (United States)

1988-05-01

Research and Development Center and Psychology Department University of Pittsburgh Pittsburgh, PA. 15260 The Artificial Intelligence and Psychology...problem never introduces more than one unfamiliar plan. Inteligent Tutoring With Intermediate Representations - Bonar and Cunniigbam 4 You must have a... Inteligent Tutoring With ntermediate Representations - Bonar and Cunningham 7 The requirements are specified at four differcnt levels, corresponding to

Simulation experiments for a large leak sodium-water reaction analysis. Volume 4. IHTS/relief system simulation tests

International Nuclear Information System (INIS)

Ploeger, D.W.

1978-09-01

Tests were performed in which a simplified 1/8-scale model of the intermediate heat transfer system and relief system of a LMFBR was subjected to a simulated sodium-water reaction in a steam generator. Pressures in the intermediate heat exchanger (IHX) and in the pipe were measured. The flow of water through the relief system was photographed and its velocity was measured. The forces on the relief system elbows resulting from the fluid flow were also measured. The tests were performed primarily to validate pulse propagation codes used for design and for direct use as design data

Present municipal water treatment and potential removal methods

International Nuclear Information System (INIS)

Lee, S.Y.; White, S.K.; Bondietti, E.A.

1982-01-01

Uranium analyses of raw water, intermediate stage, and treated water samples from 20 municipal water treatment plants indicated that the present treatment practices were not effective in removing uranium from raw waters when the influent concentration was in the range of 0.1 to 16 μg/L uranium. Laboratory batch tests revealed that the water softening and coagulant chemicals commonly used were able to remove more than 90% of the dissolved uranium ( < 100 μg/L) in waters if an optimum pH and dosage were provided. Absorbents, titanium oxide and activated charcoal, were also effective in uranium removal under specific conditions. Strong base anion exchange resin was the most efficient uranium adsorbent, and an anion exchange column is a recommended option for the treatment of private well waters containing uranium at higher than desirable levels

Anaerobic manganese- or iron-mediated pharmaceutical degradation in water

NARCIS (Netherlands)

Liu, Wenbo

2018-01-01

Pharmaceutical compounds, originating mainly from industrial production and public consumption, are detected at extremely low levels (ng·L-1 –µg·L-1) in groundwater, surface water, and wastewater. So far, the adverse effects of pharmaceuticals and their intermediates have been widely reported,

Two different strategies of host manipulation allow parasites to persist in intermediate-definitive host systems

NARCIS (Netherlands)

Vries, de L.J.; Langevelde, van F.

2018-01-01

Trophically transmitted parasites start their development in an intermediate host, before they finish the development in their definitive host when the definitive host preys on the intermediate host. In intermediate-definitive host systems, two strategies of host manipulation have been evolved:

Distribution of intermediate host snails of schistosomiasis and fascioliasis in relation to environmental factors during the dry season in the Tchologo region, Côte d'Ivoire

Science.gov (United States)

Krauth, Stefanie J.; Wandel, Nathalie; Traoré, Seïdinan I.; Vounatsou, Penelope; Hattendorf, Jan; Achi, Louise Y.; McNeill, Kristopher; N'Goran, Eliézer K.; Utzinger, Jürg

2017-10-01

Snail-borne trematodiases, such as fascioliasis and schistosomiasis, belong to the neglected tropical diseases; yet, millions of people and livestock are affected. The spatial and temporal distribution of intermediate host snails plays an important role in the epidemiology and control of trematodiases. Snail distribution is influenced by numerous environmental and anthropomorphic factors. The aim of this study was to assess the distribution and constitution of the snail fauna during the dry season in constructed and natural water bodies in the Tchologo region, northern Côte d'Ivoire, and to relate these findings to environmental factors and human infections. Snails were collected using standard procedures and environmental parameters were assessed from a total of 50 water bodies in and around 30 randomly selected villages. A canonical correspondence analysis was performed to establish the relationship between snail occurrence and environmental factors. Furthermore, a total of 743 people from the same 30 villages and nearby settlements were invited for stool and urine examination for the diagnosis of Fasciola spp., Schistosoma haematobium and Schistosoma mansoni. Snails of medical importance of the genera Biomphalaria, Bulinus, Lymnaea and Physa were found. Differences in snail occurrence from sites sampled in December 2014 and snails sampled in February 2015, as well as between the northern and southern part of the study area, were revealed. Various environmental factors, such as temperature and human activities, were related to the occurrence of intermediate host snail species in the region. Only 2.3% of human participants tested positive for schistosomiasis, while no Fasciola eggs were found in stool samples. We conclude that intermediate host snails of Fasciola and Schistosoma co-occur in water bodies in the Tchologo region and that the distribution of these snails correlates not only with environmental factors, but also with the presence of humans and animals

PIC-container for containment and disposal of low and intermediate level radioactive wastes

International Nuclear Information System (INIS)

Araki, Kunio; Shinji, Yoshimasa; Maki, Yasuro; Ishizaki, Kanjiro; Minegishi, Keiichi; Sudoh, Giichi.

1981-03-01

Steel fiber reinforced polymer-impregnated concrete (SFPIC) has been investigated for low and intermediate level radioactive waste containers. The present study has been carried out by the following stages. A) Preliminary evaluation: 60 L size container for cold and hot tests. B) Evaluation of size effect: 200 L size container for cold tests. The 60 L and 200 L containers were designed as pressure-container (without equalizer) for 500 kg/cm 2 and 700 kg/cm 2 . Polymerization of impregnated methylmethacrylate monomer for stage-A and B were performed by 60 Co-γ ray radiation and thermal catalytic polymerization, respectively. Under the loading of 500 kg/cm 2 and 700 kg/cm 2 -outside hydraulic pressure, these containers were kept in their good condition. The observed maximum strains were about 1380 x 10 -6 and 3950 x 10 -6 at the outside central position of container body for circumferential direction of the 60 L and 200 L container, respectively. An accelerated leaching test was performed by charging the concentrate of the liquid radioactive waste from JMTR in JAERI into the container. Although they were immersed in deionized water for 400 days, nuclides were not leached from the container. From results of various tests, it was evaluated that the SFPIC-container was suitable for containment and disposal of low and intermediate level radioactive wastes. There was not any great difference between the two size containers for the physical and chemical properties except in their preparation process. (author)

Radiotherapy and hormone therapy in intermediate risk prostate cancer: a critical review

International Nuclear Information System (INIS)

Franco, Rejane Carolina; Souhami, Luis

2015-01-01

Introduction: The standard treatment for patients with high risk prostate cancer is the combined use of radiation therapy (RT ) and hormone therapy (HT). In regards to patients stratified as intermediate risk, the use of HT associated with RT remains controversial, and its use should be carefully planned and based on available evidence. Objective: To critically assess results of randomized studies published in the literature that associated the use of HT of short duration with an average period of 6 months with RT in the treatment of patients with localized prostate cancer classified as intermediate risk. Method: Only randomized studies comparing these treatments were eligible for this review. A structured search through 'PubMed' was carried out using the terms 'androgen suppression therapy', 'radiotherapy', 'randomized trials', 'phase 3 trials', 'prostate cancer' and 'intermediate risk'. Results: Four randomized studies comparing RT alone to RT plus short course HT were found and selected. The majority of the trials had a mixed population of intermediate and high risk disease and did not include patients with only intermediate risk. Despite that, there appears to be a significant benefit for the combined approach regarding disease-free survival, biochemical free survival and overall survival. Conclusion: The randomized studies published so far suggest improved outcomes for the group of patients receiving RT and short course HT. Data from randomized trials comparing RT alone to RT and short course HT in patients with intermediate risk only are forthcoming. (author)

Lithological and hydrological influences on ground-water composition in a heterogeneous carbonate-clay aquifer system

Science.gov (United States)

Kauffman, S.J.; Herman, J.S.; Jones, B.F.

1998-01-01

The influence of clay units on ground-water composition was investigated in a heterogeneous carbonate aquifer system of Miocene age in southwest Florida, known as the Intermediate aquifer system. Regionally, the ground water is recharged inland, flows laterally and to greater depths in the aquifer systems, and is discharged vertically upward at the saltwater interface along the coast. A depth profile of water composition was obtained by sampling ground water from discrete intervals within the permeable carbonate units during coring and by squeezing pore water from a core of the less-permeable clay layers. A normative salt analysis of solute compositions in the water indicated a marine origin for both types of water and an evolutionary pathway for the clay water that involves clay diagenesis. The chemical composition of the ground water in the carbonate bedrock is significantly different from that of the pore water in the clay layers. Dissolution of clays and opaline silica results in high silica concentrations relative to water in other parts of the Intermediate aquifer system. Water enriched in chloride relative to the overlying and underlying ground water recharges the aquifer inland where the confining clay layer is absent, and it dissolves carbonate and silicate minerals and reacts with clays along its flow path, eventually reaching this coastal site and resulting in the high chloride and silica concentrations observed in the middle part of the Intermediate aquifer system. Reaction-path modeling suggests that the recharging surficial water mixes with sulfate-rich water upwelling from the Upper Floridan aquifer, and carbonate mineral dissolution and precipitation, weathering and exchange reactions, clay mineral diagenesis, clay and silica dissolution, organic carbon oxidation, and iron and sulfate reduction result in the observed water compositions.A study was conducted to clarify the influence of clay units on ground-water composition in a heterogeneous

On spallation and fragmentation of heavy ions at intermediate energies

International Nuclear Information System (INIS)

Musulmanbekov, G.; Al-Haidary, A.

2002-01-01

A new code for simulation of spallation and (multi)fragmentation of nuclei in proton and nucleus induced collisions at intermediate and high energies is developed. The code is a combination of modified intranuclear cascade model with traditional fission - evaporation part and multifragmentation part based on lattice representation of nuclear structure and percolation approach. The production of s-wave resonances and formation time concept included into standard intranuclear cascade code provides correct calculation of excitation energy of residues. This modified cascade code served as a bridge between low and high energy model descriptions of nucleus-nucleus collisions. A good agreement with experiments has been obtained for multiparticle production at intermediate and relatively high energies. Nuclear structure of colliding nuclei is represented as face centered cubic lattice. This representation, being isomorphic to the shell model of nuclear structure, allows to apply percolation approach for nuclear fragmentation. The offered percolation model includes both site and bond percolation. Broken sites represent holes left by nucleons knocked out at cascade state. Therefore, in the first cascade stage mutual rescattering of the colliding nuclei results in knocking some nucleons out of them. After this fast stage paltrily destruct and excited residues remain. On the second stage residual nuclei either evaporate nucleons and light nuclei up to alpha-particles or fragment into pieces with intermediate masses. The choice depends on residue's destruction degree. At low excitation energy and small destruction of the residue the evaporation and fission mechanisms are preferable. The more excitation energy and destruction the more probability of (multi)fragmentation process. Moreover, the more destruction degree of the residual the more the site percolation probability. It is concluded, that at low and intermediate excitation energies the fragmentation of nuclei is slow

Analysis of an AP600 intermediate-size loss-of-coolant accident

Energy Technology Data Exchange (ETDEWEB)

Boyack, B.E.; Lime, J.F. [Los Alamos National Lab., NM (United States)

1995-09-01

A postulated double-ended guillotine break of an AP600 direct-vessel-injection line has been analyzed. This event is characterized as an intermediate-break loss-of-coolant accident. Most of the insights regarding the response of the AP600 safety systems to the postulated accident are derived from calculations preformed with the TRAC-PF1/MOD2 code. However, complementary insights derived from a scaled experiment conducted in the ROSA facility, as well as insights based upon calculations by other codes, are also presented. Based upon the calculated and experimental results, the AP600 will not experience a core heat up and will reach a safe shutdown state using only safety-class equipment. Only the early part of the long-term cooling period initiated by In-containment Refueling Water Storage Tank injection was evaluated. Thus, the observation that the core is continuously cooled should be verified for the later phase of the long-term cooling period when sump injection and containment cooling processes are important.

Trusted intermediating agents in electronic trade networks

NARCIS (Netherlands)

T.B. Klos (Tomas); F. Alkemade (Floortje)

2005-01-01

htmlabstract Electronic commerce and trading of information goods significantly impact the role of intermediaries: consumers can bypass intermediating agents by forming direct links to producers. One reason that traditional intermediaries can still make a profit, is that they have more knowledge of

Essays in financial intermediation and political economy

NARCIS (Netherlands)

Luo, Mancy

2017-01-01

This thesis consists of three chapters in financial intermediation and political economy. The first chapter studies how investors’ preference for local stocks affects global mutual funds’ investment behaviors, and shows that mutual funds overweight stocks from their client countries (i.e., where

Intermediality and politics in theatre and performance

NARCIS (Netherlands)

Dapp, G.S.

2013-01-01

This dissertation applies the concepts of intermediality and politics to five performances by Rimini Protokoll, Christoph Schlingensief, and Igneous, and analyzes the implications that emerge on both a significational and a theoretical level. Based on the specific mediality involved, it argues that

Intermediates, Catalysts, Persistence, and Boundary Steady States

DEFF Research Database (Denmark)

Marcondes de Freitas, Michael; Feliu, Elisenda; Wiuf, Carsten

2017-01-01

networks without breaking known necessary or sufficient conditions for persistence, by iteratively removing socalled intermediates and catalysts from the network. The procedures are easy to apply and, in many cases, lead to highly simplified network structures, such as monomolecular networks. For specific...

Silicon pool dynamics and biogenic silica export in the Southern Ocean inferred from Si-isotopes

Directory of Open Access Journals (Sweden)

F. Fripiat

2011-09-01

Full Text Available Silicon isotopic signatures (δ³⁰Si of water column silicic acid (Si(OH₄ were measured in the Southern Ocean, along a meridional transect from South Africa (Subtropical Zone down to 57° S (northern Weddell Gyre. This provides the first reported data of a summer transect across the whole Antarctic Circumpolar Current (ACC. δ³⁰Si variations are large in the upper 1000 m, reflecting the effect of the silica pump superimposed upon meridional water transfer across the ACC: the transport of Antarctic surface waters northward by a net Ekman drift and their convergence and mixing with warmer upper-ocean Si-depleted waters to the north. Using Si isotopic signatures, we determine different mixing interfaces: the Antarctic Surface Water (AASW, the Antarctic Intermediate Water (AAIW, and thermoclines in the low latitude areas. The residual silicic acid concentrations of end-members control the δ³⁰Si alteration of the mixing products and with the exception of AASW, all mixing interfaces have a highly Si-depleted mixed layer end-member. These processes deplete the silicic acid AASW concentration northward, across the different interfaces, without significantly changing the AASW δ³⁰Si composition. By comparing our new results with a previous study in the Australian sector we show that during the circumpolar transport of the ACC eastward, the δ³⁰Si composition of the silicic acid pools is getting slightly, but significantly lighter from the Atlantic to the Australian sectors. This results either from the dissolution of biogenic silica in the deeper layers and/or from an isopycnal mixing with the deep water masses in the different oceanic basins: North Atlantic Deep Water in the Atlantic, and Indian Ocean deep water in the Indo-Australian sector. This isotopic trend is further transmitted to the subsurface waters, representing mixing interfaces between the surface and deeper layers.

Supercritical water oxidation of ion exchange resins: Degradation mechanisms

Energy Technology Data Exchange (ETDEWEB)

Leybros, A.; Roubaud, A. [CEA Marcoule, DEN DTCD SPDE LFSM, F-30207 Bagnols Sur Ceze (France); Guichardon, P. [Ecole Cent Marseille, F-13451 Marseille 20 (France); Boutin, O. [Aix Marseille Univ, UMR CNRS 6181, F-13545 Aix En Provence 4 (France)

2010-07-01

Spent ion exchange resins are radioactive process wastes for which there is no satisfactory industrial treatment. Supercritical water oxidation could offer a viable treatment alternative to destroy the organic structure of resins and contain radioactivity. IER degradation experiments were carried out in a continuous supercritical water reactor. Total organic carbon degradation rates in the range of 95-98% were obtained depending on operating conditions. GC-MS chromatography analyses were carried out to determine intermediate products formed during the reaction. Around 50 species were identified for cationic and anionic resins. Degradation of poly-styrenic structure leads to the formation of low molecular weight compounds. Benzoic acid, phenol and acetic acid are the main compounds. However, other products are detected in appreciable yields such as phenolic species or heterocycles, for anionic IERs degradation. Intermediates produced by intramolecular rearrangements are also obtained. A radical degradation mechanism is proposed for each resin. In this overall mechanism, several hypotheses are foreseen, according to HOO center dot radical attack sites. (authors)

Hydrogen-water deuterium exchange over metal oxide promoted nickel catalysts

Energy Technology Data Exchange (ETDEWEB)

Sagert, N H; Shaw-Wood, P E; Pouteau, R M.L. [Atomic Energy of Canada Ltd., Pinawa, Manitoba. Whiteshell Nuclear Research Establishment

1975-11-01

Specific rates have been measured for hydrogen-water deuterium isotope exchange over unsupported nickel promoted with about 20% of various metal oxides. The oxides used were Cr/sub 2/O/sub 3/, MoO/sub 2/, MnO, WO/sub 2/-WO/sub 3/, and UO/sub 2/. Nickel surface areas, which are required to measure the specific rates, were determined by hydrogen chemisorption. Specific rates were measured as a function of temperature in the range 353 to 573 K and as a function of the partial pressure of hydrogen and water over a 10-fold range of partial pressure. The molybdenum and tungsten oxides gave the highest specific rates, and manganese and uranium oxides the lowest. Chromium oxide was intermediate, although it gave the highest rate per gram of catalyst. The orders with respect to hydrogen and water over molybdenum oxide and tungsten oxide promoted nickel were consistent with a mechanism in which nickel oxide is formed from the reaction of water with the catalyst, and then is reduced by hydrogen. Over manganese and uranium oxide promoted catalysts, these orders are consistent with a mechanism in which adsorbed water exchanges with chemisorbed hydrogen atoms on the nickel surface. Chromium oxide is intermediate. It was noted that those oxides which favored the nickel oxide route had electronic work functions closest to those of metallic nickel and nickel oxide.

Oxidation of Refractory Benzothiazoles with PMS/CuFe2O4: Kinetics and Transformation Intermediates

KAUST Repository

Zhang, Tao; Chen, Yin; Leiknes, TorOve

2016-01-01

Benzothiazole (BTH) and its derivatives, 2-(methylthio)bezothiazole (MTBT), 2-benzothiazolsulfonate (BTSA) and 2-hydroxybenzothiazole (OHBT), are refractory pollutants ubiquitously existing in urban runoff at relatively high concentrations. Here, we report their oxidation by CuFe2O4-activated peroxomonosulfate (PMS/CuFe2O4), focusing on kinetics and transformation intermediates. These benzothiazoles can be efficiently degraded by this oxidation process which is confirmed to generate mainly sulfate radicals (with negligible hydroxyl-radical formation) under slightly acidic to neutral pH conditions. The molar exposure ratio of sulfate radical to residual PMS (i.e. Rct) of this process is a constant which is related to reaction condition and can be easily determined. Reaction rate constants of these benzothiazoles towards sulfate radical are (3.3 ± 0.3) × 109, (1.4 ± 0.3) × 109, (1.5 ± 0.1) × 109 and (4.7 ± 0.5) × 109 M-1s-1, respectively (pH 7 and 20 oC). Based on Rct and these rate constants, their degradation in the presence of organic matter can be well predicted. A number of transformation products were detected and tentatively identified using triple-quadruple/linear ion trap MS/MS and high-resolution MS. It appears that sulfate radicals attack BTH, MTBT and BTSA on their benzo ring via electron transfer, generating multiple hydroxylated intermediates which are reactive towards common oxidants. For OHBT oxidation, it prefers to break down the thiazole ring. Due to competitions of the transformation intermediates, a minimum PMS/pollutant molar ratio of 10-20 is required for effective degradation. The flexible PMS/CuFe2O4 could be a useful process to remove the benzothiazoles from low DOC waters like urban runoff or polluted groundwater.

Oxidation of Refractory Benzothiazoles with PMS/CuFe2O4: Kinetics and Transformation Intermediates

KAUST Repository

Zhang, Tao

2016-05-04

Benzothiazole (BTH) and its derivatives, 2-(methylthio)bezothiazole (MTBT), 2-benzothiazolsulfonate (BTSA) and 2-hydroxybenzothiazole (OHBT), are refractory pollutants ubiquitously existing in urban runoff at relatively high concentrations. Here, we report their oxidation by CuFe2O4-activated peroxomonosulfate (PMS/CuFe2O4), focusing on kinetics and transformation intermediates. These benzothiazoles can be efficiently degraded by this oxidation process which is confirmed to generate mainly sulfate radicals (with negligible hydroxyl-radical formation) under slightly acidic to neutral pH conditions. The molar exposure ratio of sulfate radical to residual PMS (i.e. Rct) of this process is a constant which is related to reaction condition and can be easily determined. Reaction rate constants of these benzothiazoles towards sulfate radical are (3.3 ± 0.3) × 109, (1.4 ± 0.3) × 109, (1.5 ± 0.1) × 109 and (4.7 ± 0.5) × 109 M-1s-1, respectively (pH 7 and 20 oC). Based on Rct and these rate constants, their degradation in the presence of organic matter can be well predicted. A number of transformation products were detected and tentatively identified using triple-quadruple/linear ion trap MS/MS and high-resolution MS. It appears that sulfate radicals attack BTH, MTBT and BTSA on their benzo ring via electron transfer, generating multiple hydroxylated intermediates which are reactive towards common oxidants. For OHBT oxidation, it prefers to break down the thiazole ring. Due to competitions of the transformation intermediates, a minimum PMS/pollutant molar ratio of 10-20 is required for effective degradation. The flexible PMS/CuFe2O4 could be a useful process to remove the benzothiazoles from low DOC waters like urban runoff or polluted groundwater.

On FEL integral equation and electron energy loss in intermediate gain regime

International Nuclear Information System (INIS)

Takao, Masaru

1994-03-01

The FEL pendulum equation in a intermediate gain small signal regime is investigated. By calculating the energy loss of the electron beam in terms of the solution of the pendulum equation, we confirm the consistency of the FEL equation in intermediate gain regime. (author)

Defining and treating the spectrum of intermediate risk nonmuscle invasive bladder cancer

NARCIS (Netherlands)

Kamat, A.M.; Witjes, J.A.; Brausi, M.; Soloway, M.; Lamm, D.; Persad, R.; Buckley, R.; Bohle, A.; Colombel, M.; Palou, J.

2014-01-01

PURPOSE: Low, intermediate and high risk categories have been defined to help guide the treatment of patients with nonmuscle invasive bladder cancer (Ta, T1, CIS). However, while low and high risk disease has been well classified, the intermediate risk category has traditionally comprised a

Marine Microorganisms as Source of Stereoselective Esterases and Ketoreductases: Kinetic Resolution of a Prostaglandin Intermediate

KAUST Repository

De Vitis, Valerio; Guidi, Benedetta; Contente, Martina Letizia; Granato, Tiziana Mariarita; Conti, Paola; Molinari, Francesco; Crotti, Elena; Mapelli, Francesca; Borin, Sara S.; Daffonchio, Daniele; Romano, Diego

2014-01-01

A screening among bacterial strains isolated from water-brine interface of the deep hypersaline anoxic basins (DHABs) of the Eastern Mediterranean was carried out for the biocatalytical resolution of racemic propyl ester of anti-2-oxotricyclo[2.2.1.0]heptan-7-carboxylic acid (R,S)-1, a key intermediate for the synthesis of d-cloprostenol. Bacillus horneckiae 15A gave highly stereoselective reduction of (R,S)-1, whereas Halomonas aquamarina 9B enantioselectively hydrolysed (R,S)-1; in both cases, enantiomerically pure unreacted (R)-1 could be easily recovered and purified at molar conversion below 57–58 %, showing the potential of DHAB extremophile microbiome and marine-derived enzymes in stereoselective biocatalysis.

Marine Microorganisms as Source of Stereoselective Esterases and Ketoreductases: Kinetic Resolution of a Prostaglandin Intermediate

KAUST Repository

De Vitis, Valerio

2014-09-30

A screening among bacterial strains isolated from water-brine interface of the deep hypersaline anoxic basins (DHABs) of the Eastern Mediterranean was carried out for the biocatalytical resolution of racemic propyl ester of anti-2-oxotricyclo[2.2.1.0]heptan-7-carboxylic acid (R,S)-1, a key intermediate for the synthesis of d-cloprostenol. Bacillus horneckiae 15A gave highly stereoselective reduction of (R,S)-1, whereas Halomonas aquamarina 9B enantioselectively hydrolysed (R,S)-1; in both cases, enantiomerically pure unreacted (R)-1 could be easily recovered and purified at molar conversion below 57–58 %, showing the potential of DHAB extremophile microbiome and marine-derived enzymes in stereoselective biocatalysis.

Intermediate-Valence Tautomerism in Decamethylytterbocene Complexes of Methyl-Substituted Bipyridines

Energy Technology Data Exchange (ETDEWEB)

Booth, Corwin H.; Kazhdan, Daniel; Werkema, Evan L.; Walter, Marc D.; Lukens, Wayne W.; Bauer, Eric D.; Hu, Yung-Jin; Maron, Laurent; Eisenstein, Odile; Head-Gordon, Martin; Andersen, Richard A.

2011-01-25

Multiconfigurational, intermediate valent ground states are established in several methyl-substituted bipyridine complexes of bispentamethylcyclopentadienylytterbium, Cp*{sub 2} Yb(Me{sub x}-bipy). In contrast to Cp*{sub 2} Yb(bipy) and other substituted-bipy complexes, the nature of both the ground state and the first excited state are altered by changing the position of the methyl or dimethyl substitutions on the bipyridine rings. In particular, certain substitutions result in multiconfigurational, intermediate valent open-shell singlet states in both the ground state and the first excited state. These conclusions are reached after consideration of single-crystal x-ray diffraction (XRD), the temperature dependence of x-ray absorption near-edge structure (XANES), extended x-ray absorption fine-structure (EXAFS), and magnetic susceptibility data, and are supported by CASSCF-MP2 calculations. These results place the various Cp*{sub 2}Yb(bipy) complexes in a new tautomeric class, that is, intermediate-valence tautomers.

Seasonal water mass distribution in the Indonesian throughflow entering the Indian Ocean

Science.gov (United States)

Coatanoan, C.; Metzl, N.; Fieux, M.; Coste, B.

1999-09-01

A multiparametric approach is used to analyze the seasonal properties of water masses in the eastern Indian Ocean. The data were measured during two cruises of the Java Australia Dynamic Experiment (JADE) program carried out during two opposite seasons: August 1989 (SE monsoon) and February-March 1992 (NW monsoon). These cruises took place at the end of a La Niña event and during an El Niño episode, respectively. Seven sources have been identified in the studied region for the 200-800 m layer: the Subtropical Indian Water, the Indian Central Water, the modified Antarctic Intermediate Water, the Indonesian Subsurface Water, the Indonesian Intermediate Water, the Arabian Sea-Persian Gulf Water (AS-PGW), and the Arabian Sea-Red Sea Water (AS-RSW). The selected tracers are potential temperature, salinity and oxygen with mass conservation and positive mixing coefficients as constraints. The analysis indicates the proportion of each water source along the Australia-Bali section and into the Indonesian channels. Although no large changes are observed for Indonesian waters, significant seasonal variations are found for the southern and northern Indian Ocean water. During the NW monsoon, the contribution of the AS-RSW increases at the entrance of the Indonesian archipelago whereas the contribution of the south Indian waters decreases in the northwest Australia basin. In a complementary study, nutrients are introduced into the multiparametric analysis in order to more clearly separate the signature of the north Indian waters (AS-PGW, AS-RSW) and to provide supplementary information on the biological history of the water masses, which is compared to large-scale primary production estimates.

Early photolysis intermediates of gecko and bovine artificial visual pigments.

Science.gov (United States)

Lewis, J W; Liang, J; Ebrey, T G; Sheves, M; Livnah, N; Kuwata, O; Jäger, S; Kliger, D S

1997-11-25

Nanosecond laser photolysis measurements were conducted on digitonin extracts of artificial pigments prepared from the cone-type visual pigment, P521, of the Tokay gecko (Gekko gekko) retina. Artificial pigments were prepared by regeneration of bleached gecko photoreceptor membranes with 9-cis-retinal, 9-cis-14-methylretinal, or 9-cis-alpha-retinal. Absorbance difference spectra were recorded at a sequence of time delays from 30 ns to 60 microseconds following excitation with a pulse of 477-nm actinic light. Global analysis showed the kinetic data for all three artificial gecko pigments to be best fit by two-exponential processes. These two-exponential decays correspond to similar decays observed after photolysis of P521 itself, with the first process being the decay of the equilibrated P521 BathoP521 BSI mixture to P521 Lumi and the second process being the decay of P521 Lumi to P521 Meta I. In spite of its large blue shift relative to P521, iso-P521 displays a normal chloride depletion induced blue shift. Iso-P521's early intermediates up to Lumi were also blue-shifted, with the P521 BathoP521 BSI equilibrated mixture being 15 nm blue-shifted and P521 Lumi being 8 nm blue-shifted relative to the intermediates formed after P521 photolysis. The blue shift associated with the iso-pigment is reduced or disappears entirely by P521 Meta I. Similar blue shifts were observed for the early intermediates observed after photolysis of bovine isorhodopsin, with the Lumi intermediate blue-shifted 5 nm compared to the Lumi intermediate formed after photolysis of bovine rhodopsin. These shifts indicate that a difference exists between the binding sites of 9- and 11-cis pigments which persists for microseconds at 20 degrees C.

Brillouin spectroscopy with surface acoustic waves on intermediate valent, doped SmS

International Nuclear Information System (INIS)

Schaerer, U.; Jung, A.; Wachter, P.

1998-01-01

Brillouin scattering on surface acoustic waves is a very powerful tool to determine the elastic constants of intermediate valent crystals, since the method is non-destructive and no mechanical contact is needed. A strong evidence for intermediate valence is a negative value of Poisson's ratio, which describes the behavior of the volume under uniaxial pressure. SmS by itself makes a semiconductor-metal transition at a pressure of more than 6.5 kbar. When substituting the divalent Sm by a trivalent cation, like Y, La or Tm, SmS can become - depending on the doping concentration - intermediate valent without any applied, external pressure. In this work, we will present measurements of the velocities of the surface acoustic waves and the calculation of the elastic constants of La- and Tm-doped SmS compounds. We found a clear dependence of Poisson's ratio on the doping concentration and on the valence of the materials. Furthermore, we will discuss the mechanism leading to intermediate valence when substituting Sm. Besides the internal, chemical pressure, which is produced by the built in trivalent cations with their smaller ionic radii, we have clear evidence, that the free electrons in the 5d band, induced by the substituting atoms, also play an important role in making doped SmS intermediate valent. (orig.)

Bituminization of low- and intermediate-level radioactive concentrates

International Nuclear Information System (INIS)

Breza, M.; Krejci, F.; Timulak, J.; Tibensky, L.

1985-01-01

The results and experiences are summed up from the research and development of the technology of bituminization of low- and intermediate-level radioactive concentrates generated in the operation of nuclear power plants with WWER-440 reactors. The experiments took place on a pilot plant bituminization line with various model solutions at an evaporator capacity of 70, 100 and 140 litres per hour. The composition of the solutions changed in dependence on the knowledge of the composition of actual concentrates in the V-1 nuclear power plant at Jaslovske Bohunice. The following factors were studied in the concentrate: the effect of its pH, its borate content and content of metal carbonates, the content of organic acid salts, the content of detergents, etc., on the process of bituminization. Physico-chemical conditions are described under which the operation of the evaporator was fail-safe and filling of the bituminization product with salts homogeneous. A low water content of up to 1% was achieved. The properties of the bituminization product were negatively affected by a high level of heavy metal oxides, surfactants, oxalates and citrates. In order to improve the properties of the product it will be necessary to replace bitumen emulsion Silembit-60 used as reinforcement matrix, by a different type of bitumen. (Z.M.)

Design of the US-CRBRP sodium/water reaction pressure relief system

International Nuclear Information System (INIS)

Kruger, G.B.; Murdock, T.B.; Rodwell, E.; Sane, J.O.

1976-01-01

Protection against intermediate sodium system overpressure from the sodium/water reaction associated with large leaks within the CRBRP Steam Generators is provided by the sodium/water reaction pressure relief system (SWRPRS). This system consists of rupture disks connected to the intermediate sodium piping adjacent to the inlet to the superheater and outlet from the evaporator modules. The rupture discs relieve into piping that leads to reaction produce separator tanks, which in turn are vented to a centrifugal separator and flare stack arranged to burn hydrogen gas exhausting into the atmosphere. Analyses have been conducted using the TRANSWRAP Computer Code to predict the system pressures and flow rates during the large leak event. Experimental tests to be conducted in the large leak test rig (LLTR) will be used to confirm the analysis techniques used in the design

Cervicovaginal cytokines, sialidase activity and bacterial load in reproductive-aged women with intermediate vaginal flora.

Science.gov (United States)

Santos-Greatti, Mariana Morena de Vieira; da Silva, Márcia Guimarães; Ferreira, Carolina Sanitá Tafner; Marconi, Camila

2016-11-01

Studies have shown that not only bacterial vaginosis, but also intermediate vaginal flora has deleterious effects for women's reproductive health. However, literature still lacks information about microbiological and immunological aspects of intermediate flora. To characterize intermediate flora regarding levels of Interleukin (IL)-1beta, IL-6, IL-8, tumor necrosis factor-alpha, interleukin 1 receptor antagonist (IL-1ra), IL-10, sialidase; loads of Gardnerella vaginalis, total bacteria and to verify whether it is closer related to normal flora or bacterial vaginosis. This cross-sectional study enrolled 526 non-pregnant reproductive-aged women distributed in 3 groups according to pattern of vaginal flora using Nugent's system in normal, intermediate and bacterial vaginosis. Cervicovaginal levels of cytokines, sialidases, loads of G. vaginalis and total bacteria were assessed by ELISA, conversion of MUAN and quantitative real-time PCR, respectively. A principal component analysis(PCA) using all measured parameters was performed to compare the three different types of flora. Results showed that intermediate flora is associated with increased cervicovaginal IL-1beta in relation to normal flora(Pbacterial vaginosis, intermediate flora has higher IL-8 and IL-10 levels(Pbacterial vaginosis(Pbacterial differed among all groups(Pbacterial vaginosis. PCA showed that normal and intermediate flora were closely scattered, while bacterial vaginosis were grouped separately. Although intermediate flora shows some differences in cytokines, sialidases and bacterial loads in relation to normal flora and bacterial vaginosis, when taken together, general microbiological and immunological pattern pattern of intermediate flora resembles the normal flora. Copyright © 2016 Elsevier Ireland Ltd. All rights reserved.

Essays in corporate finance and financial intermediation

NARCIS (Netherlands)

Kempf, Elisabeth

2016-01-01

This thesis consists of three chapters in corporate finance and financial intermediation. The first two chapters explore sources of incentives and learning for finance professionals. Specifically, the first chapter studies how the option to go work for an investment bank affects the incentives of

N-Acyliminium Intermediates in Solid-Phase Synthesis

DEFF Research Database (Denmark)

Quement, Sebastian Thordal le; Petersen, Rico; Meldal, M.

2010-01-01

N-Acyliminium ions are powerful intermediates in synthetic organic chemistry. Examples of their use are numerous in solution-phase synthesis, but there are unmerited few reports on these highly reactive electrophiles in solid-phase synthesis. The present review covers the literature to date and i...

137Cs inventories in the water column collected from the South and South China Seas

International Nuclear Information System (INIS)

Yamada, M.; Wang, Z.-L.; Zheng, J.

2006-01-01

Seawater samples were collected in the Sulu and South China Seas and their 137 Cs activities were determined by γ spectrometry. A significant difference in intermediate water 137 Cs activities in the 750-1500 m depth was observed between the Sulu and South China Seas. The 137 Cs inventories in the Sulu Sea was 5.7 times higher than that of the integrated deposition density of atmospheric global fallout at the same latitude of 0-10degN. A possible mechanism controlling this extremely high 137 Cs inventories may be inflows of 137 Cs rich North Pacific Tropical Water and upper North Pacific Intermediate Water through the Luzon Straight from the West Philippine Sea, and lateral transport across the Mindoro Strait into the Sulu Sea, then conveyance into the deep layer in the Sulu Sea basin. (author)

International express student's book : pre-intermediate

CERN Document Server

Taylor, Liz

1996-01-01

The New Edition of International Express Pre-Intermediate retains all the keys features of this popular and successel four-level course. It combines engaging, up-to-date topics with a time-efficient and student-centred approach to language work, and clearly focused activities that reflect learner's real communicative needs - the ideal course for professional adults who use English for work, travel, and socializing.

Inventories of organic materials and complexing agents in intermediate-level long-lived parcels (Report PNGMDR 2013-2015)

International Nuclear Information System (INIS)

2014-01-01

This report presents an inventory of organic materials and of complexing agents they may produce within parcels of alpha wastes which are to be produced or are being currently produced. The report proposes the results of campaigns of measurements of degassing, and comparison with results of modelling studies. The assessment of degassing rates of parcels of alpha wastes is completed by an assessment of hydrogen produced by radiolysis of interstitial water within the concrete container. Thus, after a presentation of the main parcels used by the CEA for intermediate-level long-lived wastes, and of an inventory of wastes containing organic materials, this report describes the consequences of radiolysis on polymers, and describes the objectives of R and D studies. It reports measurements and presents simulation tools for heterogeneous wastes, homogeneous wastes, production of water-soluble degradation products, and transfer and adsorption of these products in the storage site argillite

Intermediality in early cinema studies: An interrogation of a widely used concept for research practice

NARCIS (Netherlands)

Dellmann, S.; Ruppin, D.; de Zwaan, K.

2012-01-01

The authors discuss the concept of intermediality for research in early cinema. After a general introduction to intermediality as research problem in media studies, the question is raised whether the concept of intermediality can be used in diachronic research designs and for media studies that deal

Microplastics in the Baltic Sea water: fibers everywhere.

Science.gov (United States)

Khatmullina, Lilia; Bagaev, Andrey; Chubarenko, Irina

2017-04-01

Presence of thin synthetic fibres (microfibres, tens of micrometres in diameter) in the surface waters and sediments is documented in different studies; however, the data on their exact abundances in the marine environment are commonly not presented owing to the shortcomings of the sampling procedure and general absence of well-established methodology for microplastics data collection. Nevertheless, we made an attempt to qualitatively analyse the amounts of microplastic fibres in the water column of the Baltic Sea. Water samples acquired during 6 cruises over the Baltic Sea Proper in 2015-2016 were filtered using 174 μm filters, which were subsequently analysed by microscope. From the total of 95 examined filters, 63% contained fibres. They were identified by colour and the reaction to the mechanical action of a thin needle: justification of anthropogenic origin was considered to be enough; any questionable objects were discarded. Fibres comprise more than 90% of the whole microplastic particles found in the near-bottom layers in the coastal zone and around 24% of microplastics in the surface and intermediate waters, with mean concentrations of 0.71 and 0.07 fibres per litre, respectively. Although the methodology still requires a lot of enhancement, even the preliminary results indicate ubiquitous distribution of the microfibres in the water column of the Baltic Sea with surface and bottom layers revealing higher abundances of microfibres in comparison with intermediate layers, and open-sea waters being less contaminated than the coastal ones. Apart from enhancing the sampling technics, we consider that it is crucial to understand principal physical features of fibers behavior in the marine environment (e.g., settling, entrainment by currents), as it would provide an opportunity to parameterize their transport and further on to model distribution of fibers in the water column. The research is supported by the Russian Science Foundation grant number 15-17-10020.

Design of intermediate die shape of multistage profile drawing for linear motion guide

International Nuclear Information System (INIS)

Lee, Sang Kon; Lee, Jae Eun; Kim, Sung Min; Kim, Byung Min

2010-01-01

The design of an intermediate die shape is very important in multistage profile drawing. In this study, two design methods for the intermediate die shape of a multistage profile drawing for producing a linear motion guide (LM) guide is proposed. One is the electric field analysis method using the equipotential lines generated by electric field analysis, and the other is the virtual die method using a virtual drawing die constructed from the initial material and the final product shape. In order to design the intermediate die shapes of a multistage profile drawing for producing LM guide, the proposed design methods are applied, and then FE analysis and profile drawing experiment are performed. As a result, based on the measurement of dimensional accuracy, it can be known that the intermediate die shape can be designed effectively

Detecting Elusive Intermediates in Carbohydrate Conversion: A Dynamic Ensemble of Acyclic Glucose-Catalyst Complexes

DEFF Research Database (Denmark)

Meier, Sebastian; Karlsson, Magnus; Jensen, Pernille Rose

2017-01-01

within few seconds prior to reaching a steady state. Exchange between the acyclic intermediates increases at conditions that favor epimerization. Species accounting for less than 0.05% of total glucose can be monitored with sub-second time resolution to allow kinetic analysis of intermediate formation...... and catalytic conversion. Epimerization occurs 2-3 orders of magnitude-fold faster than the binding of acyclic glucose to the catalyst at near-optimum reaction conditions. The current study brings insight in to the nature of acyclic intermediate-catalyst complexes of very low population and into experimental...... strategies for characterizing very minor intermediates in carbohydrate conversion to value-added compounds....

Critical Intermediate Structure That Directs the Crystalline Texture and Surface Morphology of Organo-Lead Trihalide Perovskite.

Science.gov (United States)

Chia, Hao-Chung; Sheu, Hwo-Shuenn; Hsiao, Yu-Yun; Li, Shao-Sian; Lan, Yi-Kang; Lin, Chung-Yao; Chang, Je-Wei; Kuo, Yen-Chien; Chen, Chia-Hao; Weng, Shih-Chang; Su, Chun-Jen; Su, An-Chung; Chen, Chun-Wei; Jeng, U-Ser

2017-10-25

We have identified an often observed yet unresolved intermediate structure in a popular processing with dimethylformamide solutions of lead chloride and methylammonium iodide for perovskite solar cells. With subsecond time-resolved grazing-incidence X-ray scattering and X-ray photoemission spectroscopy, supplemental with ab initio calculation, the resolved intermediate structure (CH 3 NH 3 ) 2 PbI 2 Cl 2 ·CH 3 NH 3 I features two-dimensional (2D) perovskite bilayers of zigzagged lead-halide octahedra and sandwiched CH 3 NH 3 I layers. Such intermediate structure reveals a hidden correlation between the intermediate phase and the composition of the processing solution. Most importantly, the 2D perovskite lattice of the intermediate phase is largely crystallographically aligned with the [110] planes of the three-dimensional perovskite cubic phase; consequently, with sublimation of Cl ions from the organo-lead octahedral terminal corners in prolonged annealing, the zigzagged octahedral layers of the intermediate phase can merge with the intercalated methylammonium iodide layers for templated growth of perovskite crystals. Regulated by annealing temperature and the activation energies of the intermediate and perovskite, deduced from analysis of temperature-dependent structural kinetics, the intermediate phase is found to selectively mature first and then melt along the layering direction for epitaxial conversion into perovskite crystals. The unveiled epitaxial conversion under growth kinetics controls might be general for solution-processed and intermediate-templated perovskite formation.

Stepwise expansion of the bacteriophage ϕ6 procapsid: possible packaging intermediates.

Science.gov (United States)

Nemecek, Daniel; Cheng, Naiqian; Qiao, Jian; Mindich, Leonard; Steven, Alasdair C; Heymann, J Bernard

2011-11-25

The initial assembly product of bacteriophage ϕ6, the procapsid, undergoes major structural transformation during the sequential packaging of its three segments of single-stranded RNA. The procapsid, a compact icosahedrally symmetric particle with deeply recessed vertices, expands to the spherical mature capsid, increasing the volume available to accommodate the genome by 2.5-fold. It has been proposed that expansion and packaging are linked, with each stage in expansion presenting a binding site for a particular RNA segment. To investigate procapsid transformability, we induced expansion by acidification, heating, and elevated salt concentration. Cryo-electron microscopy reconstructions after all three treatments yielded the same partially expanded particle. Analysis by cryo-electron tomography showed that all vertices of a given capsid were either in a compact or an expanded state, indicating a highly cooperative transition. To benchmark the mature capsid, we analyzed filled (in vivo packaged) capsids. When these particles were induced to release their RNA, they reverted to the same intermediate state as expanded procapsids (intermediate 1) or to a second, further expanded state (intermediate 2). This partial reversibility of expansion suggests that the mature spherical capsid conformation is obtained only when sufficient outward pressure is exerted by packaged RNA. The observation of two intermediates is consistent with the proposed three-step packaging process. The model is further supported by the observation that a mutant capable of packaging the second RNA segment without previously packaging the first segment has enhanced susceptibility for switching spontaneously from the procapsid to the first intermediate state. Published by Elsevier Ltd.

Restrictions on the masses and coupling constants of excited intermediate bosons

International Nuclear Information System (INIS)

Kaidalov, A.B.; Nogteva, A.V.

1985-01-01

The properties of the intermediate bosons are discussed in the framework of composite models which include not only the W +- and Z 0 bosons but also their excited states with large masses. The influence of the excited states on the values of the masses of the W +- and Z 0 bosons is investigated. Restrictions on the masses and coupling constants of the excited intermediate bosons are obtained

Introductory Overview of Intermediate-luminosity X-ray Objects

Science.gov (United States)

Colbert, E. J. M.

2001-05-01

Intermediate-luminosity X-ray Objects (IXOs) are defined as compact objects having X-ray luminosities between those of X-ray binaries and low-luminosity AGNs (i.e., 1039.0 erg s-1 < ~ LX [IXOs] < ~ 1041.0 erg s-1). It is not currently known if these objects are intermediate-mass (M ~ 102-104 Msun) black holes accreting near the Eddington limit, near-solar-mass black holes in a super-Eddington state, or are, in some cases, just supermassive black holes accreting at very low rates. However, the first idea has been popularized by recent press coverage. IXOs are quite common (present in about half of spiral galaxies) and are typically found displaced from the optical nucleus, reducing the likelihood that they are low-luminosity AGN. Nearly all of our knowledge of these objects comes from X-ray observations, as observations of optical, NIR and radio counterparts are not widely known. In this session, we will address (1) the phenomenology of the objects, (2) possible geometry and accretion mechanisms for these objects (i.e., are they more similar to black hole X-ray binaries or AGNs), (3) the central black hole masses, and (4) the formation mechanism for these black holes, if they are of intermediate mass. In this talk, I will focus primarily on giving background information of these fascinating objects.

Water concentration controlled hydrolysis and crystallization in n-octanol to TiO{sub 2} nanocrystals with size below 10 nm

Energy Technology Data Exchange (ETDEWEB)

Wang Meilan [School of Chemical and Biological Science and Engineering, Yantai University, Yantai 264005 (China); He Tao, E-mail: htzy79@yahoo.com.cn [School of Chemical and Biological Science and Engineering, Yantai University, Yantai 264005 (China); Pan Yanfei; Liao Weiping [School of Chemical and Biological Science and Engineering, Yantai University, Yantai 264005 (China); Zhang Shangzhou; Du Wei [School of Environment and Materials Engineering, Yantai University, Yantai 264005 (China)

2011-11-01

Highlights: {yields} Controlled hydrolysis of alkoxide was realized by adjusting water concentration. {yields} Carrying out hydrolysis under different water concentration gave hydrolyzed intermediate with different composition. {yields} A precise size control below 10 nm for anatase TiO{sub 2} nanocrystals was realized. - Abstract: Hydrolysis of tetrabutyl titanate (TBT) and crystallization from hydrolyzed intermediates were carried out in a simple ternary system including n-octanol, TBT and water. Anatase TiO{sub 2} nanocrystals (NCS) were prepared with precise size control below 10 nm. The hydrolysis rate at different water concentration (C{sub water}) was evaluated by measuring the induction time before turbidity changing of the synthetic solution. Fourier transform infrared spectrum (FT-IR) and thermogravimetric/differential thermal analysis (TG/DTA) techniques were applied to make clear the composition of hydrolyzed intermediates obtained at different C{sub water}. Powder X-ray diffraction (XRD) technique was used to track the crystallization process of TiO{sub 2} NCS. Transmission electron microscopy (TEM), XRD, FT-IR and TG/DTA techniques were used to characterize the particular properties of NCS. The C{sub water} controlled mechanism responsible for the slow hydrolysis and crystallization were discussed. Since no other organic capping ligands or rapid injecting techniques were used to limit NCS' growth and the solvent n-octanol can be easily separated and reused, this simple synthetic process is of green chemistry and has application potential in large-scale preparation of inorganic NCS.

Isoporphyrin intermediate in heme oxygenase catalysis. Oxidation of alpha-meso-phenylheme.

Science.gov (United States)

Evans, John P; Niemevz, Fernando; Buldain, Graciela; de Montellano, Paul Ortiz

2008-07-11

Human heme oxygenase-1 (hHO-1) catalyzes the O2- and NADPH-dependent oxidation of heme to biliverdin, CO, and free iron. The first step involves regiospecific insertion of an oxygen atom at the alpha-meso carbon by a ferric hydroperoxide and is predicted to proceed via an isoporphyrin pi-cation intermediate. Here we report spectroscopic detection of a transient intermediate during oxidation by hHO-1 of alpha-meso-phenylheme-IX, alpha-meso-(p-methylphenyl)-mesoheme-III, and alpha-meso-(p-trifluoromethylphenyl)-mesoheme-III. In agreement with previous experiments (Wang, J., Niemevz, F., Lad, L., Huang, L., Alvarez, D. E., Buldain, G., Poulos, T. L., and Ortiz de Montellano, P. R. (2004) J. Biol. Chem. 279, 42593-42604), only the alpha-biliverdin isomer is produced with concomitant formation of the corresponding benzoic acid. The transient intermediate observed in the NADPH-P450 reductase-catalyzed reaction accumulated when the reaction was supported by H2O2 and exhibited the absorption maxima at 435 and 930 nm characteristic of an isoporphyrin. Product analysis by reversed phase high performance liquid chromatography and liquid chromatography electrospray ionization mass spectrometry of the product generated with H2O2 identified it as an isoporphyrin that, on quenching, decayed to benzoylbiliverdin. In the presence of H218O2, one labeled oxygen atom was incorporated into these products. The hHO-1-isoporphyrin complexes were found to have half-lives of 1.7 and 2.4 h for the p-trifluoromethyl- and p-methyl-substituted phenylhemes, respectively. The addition of NADPH-P450 reductase to the H2O2-generated hHO-1-isoporphyrin complex produced alpha-biliverdin, confirming its role as a reaction intermediate. Identification of an isoporphyrin intermediate in the catalytic sequence of hHO-1, the first such intermediate observed in hemoprotein catalysis, completes our understanding of the critical first step of heme oxidation.

Fission in intermediate energy heavy ion reactions

International Nuclear Information System (INIS)

Wilhelmy, J.B.; Begemann-Blaich, M.; Blaich, T.; Boissevain, J.; Fowler, M.M.; Gavron, A.; Jacak, B.V.; Lysaght, P.S.; Britt, H.C.; Fields, D.J.; Hansen, L.F.; Lanier, R.G.; Massoletti, D.J.; Namboodiri, M.M.; Remington, B.A.; Sangster, T.C.; Struble, G.L.; Webb, M.L.; Chan, Y.D.; Dacai, A.; Harmon, A.; Leyba, J.; Pouliot, J.; Stokstad, R.G.; Hansen, O.; Levine, M.J.; Thorn, C.E.; Trautmann, W.; Dichter, B.; Kaufman, S.; Videbaek, F.; Fraenkel, Z.; Mamane, G.; Cebra, D.; Westfall, G.D.

1989-01-01

A systematic study of reaction mechanisms at intermediate energies (50-100 MeV/A) has been performed at the Lawrence Berkeley Laboratory's BeValac using medium weight projectiles on medium and heavy element targets. A gas and plastic phoswich detector system was employed which gave large geometric coverage and a wide dynamic response. The particles identified with the gas detectors could be characterized into three components - intermediate mass fragments (IMF), fission fragments (FF) and heavy residues (HR). Major observed features are: The reaction yields are similar in the 50 to 100 MeV/A range, central collisions have high multiplicty of IMF's with broad angular correlations consistent with a large participant region, effects of final state Coulomb interactions are observed and give information on the size and temporal behavior of the source, true fission yields are dependent on target fissility and correlated with relatively peripheral collisions. Analysis of fission and evaporation yields implies limiting conditions for which fission decay remains a viable deexcitation channel. (orig.)

BANKING INTERMEDIATION AND CONSEQUENCES OF FINANCIAL CRISIS

Directory of Open Access Journals (Sweden)

Medar Lucian-Ion

2012-12-01

Full Text Available The financial intermediation of bank institutions, has an essential role in mobilising of the available funds and their distribution in various products and services, for economic growth. The extent that banking system is in distress or passing through a period of crisis, then, everything turns into a general crisis, especially that, in some states, natural and legal persons have been learned ,,to live’’ on the credits.The effectiveness of banking intermediation activity in Romania depends on how fast the market is enabled under the influence of the new European regulations. The Romanian market in all its forms is the second largest in the EU, and the banking system is almost entirely made up of banks with foreign capital. The romanian banking market has not suffered so much because of the financial crisis. To the extent that banking institutions provide the necessary funds, Romania has important resources for the transition to a new economic cycle based on sustainable development.

Intermediate-Level Knowledge in Child-Computer Interaction

DEFF Research Database (Denmark)

Barendregt, Wolmet; Torgersson, Olof; Eriksson, Eva

2017-01-01

Based on an analysis of all papers at IDC from 2003 to 2016 this paper urges the Child-Computer Interaction (CCI) field to start formulating intermediate-level knowledge, in the form of e.g. strong concepts. Our analysis showed that 40% of all papers at the Interaction Design and Children...... conference presents the design of an artefact accompanied by an evaluation (to which we will refer as 'artefact-centered' papers). While exploring the design space in the form of artefacts is important and valuable, it can be argued that those artefact-centered papers generally make a smaller contribution...... to the field as a whole, which is also visible in the number of citations to such papers in comparison to the number of citations to other kinds of papers. As a first step towards more intermediate-level knowledge, we have thus attempted to formulate and ground three suggestions for strong concepts in CCI...