WorldWideScience

Sample records for integrated organic gas

  1. Performance analysis of an integrated gas-, steam- and organic fluid-cycle thermal power plant

    International Nuclear Information System (INIS)

    Oko, C.O.C.; Njoku, I.H.

    2017-01-01

    This paper presents the performance analysis of an existing combined cycle power plant augmented with a waste heat fired organic Rankine cycle power plant for extra power generation. This was achieved by performing energy and exergy analysis of the integrated gas-, steam- and organic fluid-cycle thermal power plant (IPP). Heat source for the subcritical organic Rankine cycle (ORC) was the exhaust flue gases from the heat recovery steam generators of a 650 MW natural gas fired combined cycle power plant. The results showed that extra 12.4 MW of electricity was generated from the attached ORC unit using HFE7100 as working fluid. To select ORC working fluid, ten isentropic fluids were screened and HFE7100 produced the highest net power output and cycle efficiency. Exergy and energy efficiencies of the IPP improved by 1.95% and 1.93%, respectively. The rate of exergy destruction in the existing combined cycle plant was highest in the combustion chamber, 59%, whereas in the ORC, the highest rate of exergy destruction occurred in the evaporator, 62%. Simulations showed exergy efficiency of the IPP decreased with increasing ambient temperature. Exit stack flue gas temperature reduced from 126 °C in the combined cycle power plant to 100 °C in the integrated power plant. - Highlights: • Combined cycle plant retrofitted with ORC produced extra 12.4 MW electric power. • ORC is powered with low temperature flue gas from an existing combined cycle plant. • Exergy destruction rate in integrated plant(IPP) is less than in combined plant. • Exit stack temperature of the IPP has less environmental thermal pollution. • Exergy and energy efficiencies of the IPP improved by 1.95% and 1.93%, respectively.

  2. The Role of Integrated Gas Compounds in Regulation of Gas Homeostasis in the Norm

    OpenAIRE

    Alexander G. Kruglov; Valery N. Utkin; Alexander Yu. Vasilyev

    2017-01-01

    In practically healthy people on the background of self-breathing, we used catheterization to obtain blood samples from Ao, PT, SC, VJI, SS, VH and VR. We believe that the standard tests of blood gases by volume (pO2 and pCO2) and their A-V gradients, quantitatively determined, are insufficient to fully assess the hypoxic states both in the whole organism and in individual organs. To estimate gas homeokinesis, we performed integral gas tests, including an additive criterion of blood gases—pr...

  3. Natural gas development and integration for Asian markets

    International Nuclear Information System (INIS)

    Hovdestad, W. R.; Belgrave, J. D. M.

    1995-01-01

    Development schedule, and natural gas resources available to Southeast Asian countries were discussed in view of the area's rapidly growing market for natural gas. As evidence, the increased regional trade and cooperation are evident in the form of organizations like the Association of South East Asian Nations (ASEAN) and Asia Pacific Economic Cooperation (APEC) Forum were cited. Liquid natural gas pipeline grids were about 1/3 complete at the time of writing. Further development and completion of this system was expected to occur over the next 3 decades. Integration of new and existing facilities were seen to be inevitable future developments. The potential for international movement of natural gas from producing countries to consuming countries was assessed and was expected to remain favourable in the long term

  4. Comparative evaluation of a natural gas expansion plant integrated with an IC engine and an organic Rankine cycle

    International Nuclear Information System (INIS)

    Kostowski, Wojciech J.; Usón, Sergio

    2013-01-01

    Highlights: • Comparison of natural gas expansion systems integrated with gas boiler, ICE and ORC. • Expansion systems replace the throttling process in pressure regulating stations. • 5 System performance indicators based on the 1st and 2nd law are defined. • Exergy efficiency was calculated from the fuel-product approach. • ORC system yields highest exergy efficiency 52.6% and performance ratio of 0.771. - Abstract: The aim of the paper is to propose and evaluate an innovative exergy recovery system for natural gas expansion, based on the integration of an internal combustion engine (ICE) and an organic Rankine cycle (ORC), and to compare it with other alternatives. Natural gas expansion plants are a substantial improvement to the conventional gas pressure reduction stations, based on the throttling process, since the available physical exergy of pressurized gas is converted into mechanical energy by means of an expansion machine (turbine or piston expander) instead of being lost in the throttling process. However, due to the hydrate formation problem the gas has to be pre-heated prior to the expansion, which diminishes the system performance. An efficient method for performing this pre-heating is by the proposed system that comprises an ICE and an ORC: Pre-heating of natural gas is carried out partially directly by the co-generation module, via the engine cooling cycle, and partially indirectly, by means of the engine exhaust gases, which supply heat for the ORC, while the ORC condenser is connected with the lowest stage of natural gas pre-heating. Other alternatives are the use of an ICE without ORC, the use of a boiler, and even expansion in a throttling valve. The paper evaluates the performance of the aforementioned four configurations by means of both energy and exergy analysis. Several alternative performance indicators have been defined, calculated and discussed. Sources of irreversibilities have been identified by means of exergy analysis

  5. Gas Sensor

    KAUST Repository

    Luebke, Ryan

    2015-01-22

    A gas sensor using a metal organic framework material can be fully integrated with related circuitry on a single substrate. In an on-chip application, the gas sensor can result in an area-efficient fully integrated gas sensor solution. In one aspect, a gas sensor can include a first gas sensing region including a first pair of electrodes, and a first gas sensitive material proximate to the first pair of electrodes, wherein the first gas sensitive material includes a first metal organic framework material.

  6. Gas Sensor

    KAUST Repository

    Luebke, Ryan; Eddaoudi, Mohamed; Omran, Hesham; Belmabkhout, Youssef; Shekhah, Osama; Salama, Khaled N.

    2015-01-01

    A gas sensor using a metal organic framework material can be fully integrated with related circuitry on a single substrate. In an on-chip application, the gas sensor can result in an area-efficient fully integrated gas sensor solution. In one aspect, a gas sensor can include a first gas sensing region including a first pair of electrodes, and a first gas sensitive material proximate to the first pair of electrodes, wherein the first gas sensitive material includes a first metal organic framework material.

  7. International survey on gas technology organizations

    International Nuclear Information System (INIS)

    1994-11-01

    The International Survey on Gas Technology Organizations has been prepared by the IEA International Centre for Gas Technology Information. 172 companies and R and D Institutions from 41 countries have contributed to the survey. The objective of the Survey is to develop an overview of identified organizations active in the development of new gas technology. As a quick reference guide the survey offers you short descriptions of a number of the most important organizations within gas technology on a world wide basis. Many R and D institutions around the world are working with topics of relevance to the gas industry. New gas technology draws on many different scientific and technical disciplines. This first issue of the survey includes only a part of the numerous organizations and institutions active within the development of new technology of relevance to the gas industry. The preparation of this survey has been a first step in the development of the information activities of the Centre. The information regarding organizations with R and D activities of relevance to the gas industry will continuously be expanded and updated for internal use in the Centre and will also be available to external users. The Centre plans to establish on-line access to these update versions during 1995. (EG)

  8. Primer on gas integrated resource planning

    Energy Technology Data Exchange (ETDEWEB)

    Goldman, C.; Comnes, G.A.; Busch, J.; Wiel, S. [Lawrence Berkeley Lab., CA (United States)

    1993-12-01

    This report discusses the following topics: gas resource planning: need for IRP; gas integrated resource planning: methods and models; supply and capacity planning for gas utilities; methods for estimating gas avoided costs; economic analysis of gas utility DSM programs: benefit-cost tests; gas DSM technologies and programs; end-use fuel substitution; and financial aspects of gas demand-side management programs.

  9. Interim report on testing of off-gas treatment technologies for abatement of atmospheric emissions of chlorinated volatile organic compounds

    International Nuclear Information System (INIS)

    Haselow, J.S.; Jarosch, T.R.; Rossabi, J.; Burdick, S.; Lombard, K.

    1993-12-01

    The purpose of this report is to briefly summarize the results to date of the off-gas treatment program for atmospheric emissions of chlorinated volatile organic compounds (CVOCs), in particular trichloroethylene (TCE) and perchloroethylene (PCE). This program is part of the Department of Energy's Office of Technology Development's Integrated Demonstration for Treatment of Organics in Soil and Water at a Non-Arid Site. The off-gas treatment program was initiated after testing of in-situ air stripping with horizontal wells was completed. That successful test expectedly produced atmospheric emissions of CVOCs that were unabated. It was decided after that test that an off-gas treatment program would complement the Integrated Demonstration not only because off-gas treatment is an integral portion of remediation of CVOC contamination in groundwater and soil but also because several technologies were being developed across the US to mitigate CVOC emissions. A single platform for testing off-gas treatment technologies would facilitate systematic and unbiased evaluation of the emerging technologies

  10. Turbo-gas emissions and integrated pollution prevention and control (IPPC)

    International Nuclear Information System (INIS)

    Mariani, M.; Sera, B.

    2005-01-01

    The present paper considers the gas-turbine pollution and joints out that the NO, is the most important pollutant among others pollutants as well as the carbon oxide and the volatile organic compounds because the NO x , has a high mass production rate (in the combustion chamber), elevated toxicity to the ecosystem and because of being in the atmosphere a precursor of secondary ultrafine particles PM 2,5 . In with reference to the integrated pollution and control (IPPC) the job shows schemes of chain chemical reactions which are on the base of the formation of different types of NO x , thermal and organic, and it illustrates the influence of some operative parameters on the combustion's efficiency and then on the NO x , production rate. Also, the study gives the best absolvable techniques (BAT) to reduce the NO x , production rate and to demolish it before its introduction, as well as gas exhaust, in the atmosphere. At the end, the work shows that the gas-turbine are to consider thermal engines with a little environment impact index specially when they make use of the natural gas, as well as fuel [it

  11. The natural gas as integration element in Latin America

    International Nuclear Information System (INIS)

    Morales, Maria Elizabeth; Dutra, Luis Eduardo; Rosa, Luiz Pinguelli

    1999-01-01

    The article discusses the following global aspects of natural gas development: natural gas and worldwide energetic integration; natural gas consumption rates in the world; natural gas industry development in Latin America; and natural gas industry in Brazil. The article concludes that the natural gas can integrate Latin-american economies since the Governments adopt coherent energetic politicians articulated to each other

  12. Gas Separation Using Organic-Vapor-Resistent Membranes In Conjunctin With Organic-Vapor-Selective Membranes

    Science.gov (United States)

    Baker, Richard W.; Pinnau, Ingo; He, Zhenjie; Da Costa, Andre R.; Daniels, Ramin; Amo, Karl D.; Wijmans, Johannes G.

    2003-06-03

    A process for treating a gas mixture containing at least an organic compound gas or vapor and a second gas, such as natural gas, refinery off-gas or air. The process uses two sequential membrane separation steps, one using membrane selective for the organic compound over the second gas, the other selective for the second gas over the organic vapor. The second-gas-selective membranes use a selective layer made from a polymer having repeating units of a fluorinated polymer, and demonstrate good resistance to plasticization by the organic components in the gas mixture under treatment, and good recovery after exposure to liquid aromatic hydrocarbons. The membrane steps can be combined in either order.

  13. Integrated Microfluidic Gas Sensors for Water Monitoring

    Science.gov (United States)

    Zhu, L.; Sniadecki, N.; DeVoe, D. L.; Beamesderfer, M.; Semancik, S.; DeVoe, D. L.

    2003-01-01

    A silicon-based microhotplate tin oxide (SnO2) gas sensor integrated into a polymer-based microfluidic system for monitoring of contaminants in water systems is presented. This device is designed to sample a water source, control the sample vapor pressure within a microchannel using integrated resistive heaters, and direct the vapor past the integrated gas sensor for analysis. The sensor platform takes advantage of novel technology allowing direct integration of discrete silicon chips into a larger polymer microfluidic substrate, including seamless fluidic and electrical interconnects between the substrate and silicon chip.

  14. Toward a new, integrated interactive electric power and natural gas industry

    International Nuclear Information System (INIS)

    Anon.

    1995-01-01

    The movement toward a new, integrated interactive electric power and natural gas industry is discussed. This movement envisions more competition and fewer competitors. The key capabilities of the new market are described. It is concluded that what will make an energy business succeed is the ability to aggregate supply and markets, to optimize routing, to improve load factors, and to provide added levels of reliability through diversity. The strong organization that is able to deal in all forms of energy is a necessary part of this new paradigm of the integrated energy market

  15. Organic Rankine cycle saves energy and reduces gas emissions for cement production

    International Nuclear Information System (INIS)

    Wang, Huarong; Xu, Jinliang; Yang, Xufei; Miao, Zheng; Yu, Chao

    2015-01-01

    We investigated ORCs (organic Rankine cycles) integrated with typical China cement production line. The dry air at the kiln cooler outlet with the temperature of 220 °C was the waste heat. The fluids of hexane, isohexane, R601, R123 and R245fa were selected for ORCs based on the critical temperature criterion. The developed ORC verified the thermodynamics analysis. The NPV (net present value) and PBP (payback period) methods were applied to evaluate the economic performance. The LCA (life cycle assessment) was applied to evaluate the environment impacts. ORCs could generate 67,85,540–81,21,650 kWh electricity per year, equivalent to save 2035–2436 tons standard coal and reduce 7743–9268 tons CO 2 emission, for a 4000 t/d cement production line. ORCs reduced gas emissions of CO 2 by 0.62–0.74%, SO 2 by 3.83–4.59% and NO x by 1.36–1.63%. The PBP (payback period) was 2.74–3.42 years. The ORCs had the reduction ratios of EIL (environment impact load) by 1.49–1.83%, GWP (global warming potential) by 0.74–0.92%, AP (acidification potential) by 2.34–2.84%, EP (eutrophication potential) by 0.96–1.22% and HTP (human toxicity potential) by 2.38–2.89%. The ORC with R601 as the fluid had the best economic performance and significant gas emission reductions. ORCs had good economic performance and reduce the gas emissions. - Highlights: • Organic Rankine Cycles were integrated with the cement production line. • Five organic fluids were used as the working fluids for ORCs. • Thermal, economic and gas emission performances were analyzed. • R601 was the best fluid for ORC with the heat source temperature of 220 °C. • ORCs had good economic and gas emission reduction performances

  16. Metal-Organic Framework Thin Films as Stationary Phases in Microfabricated Gas-Chromatography Columns.

    Energy Technology Data Exchange (ETDEWEB)

    Read, Douglas [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Sillerud, Colin Halliday [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

    2016-01-01

    The overarching goal of this project is to integrate Sandia's microfabricated gas-chromatography ( GC) columns with a stationary phase material that is capable of retaining high-volatility chemicals and permanent gases. The successful integration of such a material with GCs would dramatically expand the repertoire of detectable compounds for Sandia's various microanalysis systems. One such promising class of candidate materials is metal-organic frameworks (MOFs). In this report we detail our methods for controlled deposition of HKUST-1 MOF stationary phases within GC columns. We demonstrate: the chromatographic separation of natural gas; a method for determining MOF film thickness from chromatography alone; and the first-reported GC x GC separation of natural gas -- in general -- let alone for two disparate MOF stationary phases. In addition we determine the fundamental thermodynamic constant for mass sorption, the partition coefficient, for HKUST-1 and several light hydrocarbons and select toxic industrial chemicals.

  17. European market integration for gas? Volume flexibility and political risk

    International Nuclear Information System (INIS)

    Asche, Frank; Tveteras, Ragnar; Osmundsen, Petter

    2002-01-01

    Long-term take-or-pay contracts regulating gas exports to the Continent are described and analyzed. We thereafter examine whether the German gas market is integrated. Time series of Norwegian, Dutch and Russian gas export prices to Germany in 1990-1998 are examined. Cointegration tests show that that the different border prices for gas to Germany move proportionally over time, indicating an integrated gas market. We find differences in mean prices, with Russian gas being sold at prices systematically lower than Dutch and Norwegian gas. Among the explanatory factors for price discrepancies are differences in volume flexibility (swing) and perceived political risk

  18. Performance analysis of solar energy integrated with natural-gas-to-methanol process

    International Nuclear Information System (INIS)

    Yang, Sheng; Liu, Zhiqiang; Tang, Zhiyong; Wang, Yifan; Chen, Qianqian; Sun, Yuhan

    2017-01-01

    Highlights: • Solar energy integrated with natural-gas-to-methanol process is proposed. • The two processes are modeled and simulated. • Performance analysis of the two processes are conducted. • The proposed process can cut down the greenhouse gas emission. • The proposed process can save natural gas consumption. - Abstract: Methanol is an important platform chemical. Methanol production using natural gas as raw material has short processing route and well developed equipment and technology. However, natural gas reserves are not large in China. Solar energy power generation system integrated with natural-gas-to-methanol (NGTM) process is developed, which may provide a technical routine for methanol production in the future. The solar energy power generation produces electricity for reforming unit and system consumption in solar energy integrated natural-gas-to-methanol system (SGTM). Performance analysis of conventional natural-gas-to-methanol process and solar energy integrated with natural-gas-to-methanol process are presented based on simulation results. Performance analysis was conducted considering carbon efficiency, production cost, solar energy price, natural gas price, and carbon tax. Results indicate that solar energy integrated with natural-gas-to-methanol process is able to cut down the greenhouse gas (GHG) emission. In addition, solar energy can replace natural gas as fuel. This can reduce the consumption of natural gas, which equals to 9.2% of the total consumed natural gas. However, it is not economical considering the current technology readiness level, compared with conventional natural-gas-to-methanol process.

  19. Natural gas integration in latin america: forward or backwards?

    International Nuclear Information System (INIS)

    Moutinho Dos Santos, E.; Oxilia Davalos, V.E.; Tadeu Werneck Faga, M.

    2006-01-01

    Throughout the 1990's to Year 2000, energy integration, and particularly natural gas integration, was seen as a major goal in the Southern Cone of South America, The regional perspective for energy was related to an even more challenging objective - Latin American economic integration, which was quickly moving forward by the constitution of MERCOSUR, the free trade zone built by Argentina, Brazil, Uruguay and Paraguay, and also having Bolivia and Chile as special partners. MERCOSUR was getting stronger and becoming a successful political project. Trade conflicts existed, but they were considered normal and nobody would disagree about the viability of MERCOSUR. By the beginning of the 21. Century, the economic integration process in South America was already advancing timidly as compared to the impetus from the beginning of 1990's. MERCOSUR started facing complex and almost insurmountable challenges after the numerous global financial crises (from 1998 to 2003) which had affected the economic balances in the region. Energy and gas integration in South America has equally lost perspective as fast as the importance of economic integration has declined. The economic crises in the region and poor energy policies have discouraged energy companies to invest. The paper presents this recent history of rising and falling in the concept of economic and energy integration in the Southern Cone of South America. Despite the abundance of energy resources, and particularly the plethora of recently discovered natural gas, the region has been experiencing systematic and important energy shortages, which may threaten its economic recovery. A stronger energy integration policy would help all the partner countries to reduce energy supply risks. Yet, energy (and gas) integration in the Southern Cone is still a complex long-term political project, which must involve all countries, but whose future perspective is unclear. It seems almost impossible to keep pushing forward this project

  20. Cogenerative Performance of a Wind − Gas Turbine − Organic Rankine Cycle Integrated System for Offshore Applications

    DEFF Research Database (Denmark)

    Bianchi, Michele; Branchini, Lisa; De Pascale, Andrea

    2016-01-01

    Gas Turbines (GT) are widely used for power generationin offshore oil and gas facilities, due to their high reliability,compactness and dynamic response capabilities. Small heavyduty and aeroderivative units in multiple arrangements aretypically used to offer larger load flexibility......, but limitedefficiency of such machines is the main drawback. A solutionto enhance the system performance, also in Combined Heat andPower (CHP) arrangement, is the implementation of OrganicRankine Cycle (ORC) systems at the bottom of the gas turbines.Moreover, the resulting GT-ORC combined cycle could befurther...... a 10MW offshorewind farm and three gas turbines rated for 16:5MW, eachone coupled with an 4:5MW ORC module. The ORC mainparameters are observed under different wind power fluctuations.Due to the non-programmable availability of wind and powerdemand, the part-load and dynamic characteristics...

  1. Gaining competitive advantage in the gas boilers market of Vojvodina through integrated marketing communications

    Directory of Open Access Journals (Sweden)

    Jovičić Dragoljub

    2015-01-01

    Full Text Available Since the appearance of marketing and implementation of marketing concept in practice, the importance of the marketing mix, through which organizations adapt their offer to targeted customer segments, was emphasized . Regardless of the fact that the product is commonly referred to as the basic (key instrument of the marketing mix, in the last ten years, due to the rapid and strong development of science, technology, especially information technology, business and society in general, integrated marketing communications (IMK are becoming increasingly important, without which organizations can not even begin, or end, any significant marketing activity. In this context, the aim of the authors of this study was to investigate the importance of integrated marketing communications on the placement of gas boilers, i.e. on the market share of individual producers in the market of Vojvodina, which also represents the basic hypothesis of the research. Research results confirmed the basic hypothesis as well as an extraordinary influence of IMK to the market share of producers in the placement of gas boilers. Supplementary hypothesis was not confirmed, advertising is not a key promotional instrument. Thanks to the specific characteristics, primarily the high technical complexity of gas boilers, a key promotional instrument are education and training of sales and installation staff in the marketing channels, which operate on the market of Vojvodina.

  2. Continuous organic waste digester and methane gas generator

    Energy Technology Data Exchange (ETDEWEB)

    Araneta, V.A.

    1979-01-01

    A patent on the construction of a utility model of an industrial product of a continuous organic-waste digester and methane-gas generator is described. It comprises an airtight chamber to receive slurry of organic waste; a gas-water scrubber to purge carbon dioxide, odor-omitting gases and froth or scrum from newly formed methane gas evolving from said slurry of organic wastes; and two dually functioning slurry-feed and -discharge pipes connected to a reversible pump. It has one pipe with an opening at the base of an airtight chamber and the other pipe with up-ended openings below the fluid level of the slurry to be accumulated in the airtight chamber.

  3. Integrating gas and electric markets and regulation

    International Nuclear Information System (INIS)

    Whitmore, C.S.

    1998-01-01

    The issues determining what energy companies must do to compete in an increasingly competitive energy market and what regulators must do to ensure fairness in competition were discussed. The similarities of gas and electric markets, and the factors driving their integration were highlighted. The importance of communications and customer service in the energy market and the nature of market power in the gas and electric industries was described. Three reasons were given why gas/electric mergers will be beneficial: (1) operating efficiency, (2) applying gas experience to electric markets, and (3) opportunity to exercise market power. Potential regulatory problems were also reviewed

  4. Well Integrity for Natural Gas Storage in Depleted Reservoirs and Aquifers

    Energy Technology Data Exchange (ETDEWEB)

    Freifeld, Barry [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Oldenburg, Curtis [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Jordan, Preston [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Pan, Lehua [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Perfect, Scott [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Morris, Joseph [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); White, Joshua [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Bauer, Stephen [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Blankenship, Douglas [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Roberts, Barry [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Bromhal, Grant [National Energy Technology Lab. (NETL), Morgantown, WV (United States); Glosser, Deborah [National Energy Technology Lab. (NETL), Morgantown, WV (United States); Wyatt, Douglas [National Energy Technology Lab. (NETL), Morgantown, WV (United States); Rose, Kelly [National Energy Technology Lab. (NETL), Morgantown, WV (United States)

    2016-09-01

    The 2015-2016 Aliso Canyon/Porter Ranch natural gas well blowout emitted approximately 100,000 tonnes of natural gas (mostly methane, CH4) over four months. The blowout impacted thousands of nearby residents, who were displaced from their homes. The high visibility of the event has led to increased scrutiny of the safety of natural gas storage at the Aliso Canyon facility, as well as broader concern for natural gas storage integrity throughout the country. This report presents the findings of the DOE National Laboratories Well Integrity Work Group efforts in the four tasks. In addition to documenting the work of the Work Group, this report presents high priority recommendations to improve well integrity and reduce the likelihood and consequences of subsurface natural gas leaks.

  5. Rapid estimation of the organic sulphur content of kerogens, coals and asphaltenes by pyrolysis-gas chromatography

    NARCIS (Netherlands)

    Sinninghe Damsté, J.S.; Eglinton, T.I.; Kohnen, M.E.L.; Leeuw, J.W. de

    1990-01-01

    A pyrolysis-gas Chromatographic (py-g.c.) method for estimation of the Sorg/C ratio in kerogens and other forms of sedimentary macromolecular organic matter is described. The method is based upon flash pyrolysis at 610 °C for 10s and areal integration of the FID peaks attributed to

  6. A Miniaturized Optical Sensor with Integrated Gas Cell

    NARCIS (Netherlands)

    Ayerden, N.P.; Ghaderi, M.; De Graaf, G.; Wolffenbuttel, R.F.

    2015-01-01

    The design, fabrication and characterization of a highly integrated optical gas sensor is presented. The gas cell takes up most of the space in a microspectrometer and is the only component that has so far not been miniaturized. Using the tapered resonator cavity of a linear variable optical filter

  7. Toward the integration of European natural gas markets:A time-varying approach

    International Nuclear Information System (INIS)

    Renou-Maissant, Patricia

    2012-01-01

    Over the past fifteen years, European gas markets have radically changed. In order to build a single European gas market, a new regulatory framework has been established through three European Gas Directives. The purpose of this article is to investigate the impact of the reforms in the natural gas industry on consumer prices, with a specific focus on gas prices for industrial use. The strength of the relationship between the industrial gas prices of six western European countries is studied by testing the Law of One Price for the period 1991–2009. Estimations were carried out using both cointegration analysis and time-varying parameter models. Results highlight an emerging and on-going process of convergence between the industrial gas prices in western Europe since 2001 for the six EU member states. The strength and the level of convergence differ widely between countries. Strong integration of gas markets in continental Europe, except for the Belgian market, has been established. It appears that the convergence process between continental countries and the UK is not completed. Thus, the integration of European gas markets remains an open issue and the question of how far integration will proceed will still be widely discussed in the coming years. - Highlights: ► We investigate the integration of European natural gas markets. ► We use both cointegration analysis and time-varying parameter models. ► We show the failure of cointegration techniques to take account of evolving processes. ► An emerging and on-going process of convergence between the industrial gas prices is at work. ► Strong integration of gas markets in continental Europe has been established.

  8. Natural gas integration in Latin America: end of a dream?

    International Nuclear Information System (INIS)

    Moutinho dos Santos, E.; Oxilia Davalos, V.E.; Tadeu Werneck Faga, M.

    2007-01-01

    Throughout the 1990's to year 2000, energy integration, and particularly natural gas integration, was seen as a major goal in the southern cone of South America. The regional perspective for energy was related to an even more challenging objective - Latin American economic integration, which was quickly moving forward by the constitution of Mercosur, the free trade zone built by Argentina, Brazil, Uruguay and Paraguay, and also having Bolivia and Chile as special partners. Mercosur was getting stronger and becoming a successful political project. Trade conflicts existed, but they were considered normal and nobody would disagree about the viability of Mercosur. By the beginning of the 21. century, the economic integration process in South America was already advancing timidly as compared to the impetus from the beginning of 1990's. Mercosur started facing complex and almost insurmountable challenges after the numerous global financial crises (from 1998 to 2003) had affected the economic balances in the region. Energy and gas integration in South America has equally lost perspective as fast as the importance of economic integration has declined. The economic crises in the region and poor energy policies have discourage energy companies to invest. The paper presents this recent history of rise and fall in the concept of economic and energy integration in the southern cone of South America. Despite the abundance of energy resources, and particularly the plethora of recently discovered natural gas, the region has been experiencing systematic and important energy shortages, which may threaten its economic recovery. A stronger energy integration policy would help all the partner countries to reduce energy supply risks. Yet, energy (and gas) integration in the southern cone is still a complex long-term political project, which must involve all countries, but whose future perspective is unclear. It seems almost impossible to keep pushing forward this project without

  9. Improvement of anaerobic bio-hydrogen gas production from organic sludge waste

    International Nuclear Information System (INIS)

    Lee, S.; Lee, Y. H.

    2009-01-01

    Microbial hydrogen gas production from organic matters stands out as one of the most promising alternatives for sustainable green energy production. Based on the literature review, investigation of anaerobic bio-hydrogen gas production from organic sludge waste using a mixed culture has been very limited. The objective of this study was to assess the anaerobic bio-hydrogen gas production from organic sludge waste under various conditions. (Author)

  10. Integrated biomass pyrolysis with organic Rankine cycle for power generation

    Science.gov (United States)

    Nur, T. B.; Syahputra, A. W.

    2018-02-01

    The growing interest on Organic Rankine Cycle (ORC) application to produce electricity by utilizing biomass energy sources are increasingly due to its successfully used to generate power from waste heat available in industrial processes. Biomass pyrolysis is one of the thermochemical technologies for converting biomass into energy and chemical products consisting of liquid bio-oil, solid biochar, and pyrolytic gas. In the application, biomass pyrolysis can be divided into three main categories; slow, fast and flash pyrolysis mainly aiming at maximizing the products of bio-oil or biochar. The temperature of synthesis gas generated during processes can be used for Organic Rankine Cycle to generate power. The heat from synthesis gas during pyrolysis processes was transfer by thermal oil heater to evaporate ORC working fluid in the evaporator unit. In this study, the potential of the palm oil empty fruit bunch, palm oil shell, and tree bark have been used as fuel from biomass to generate electricity by integrated with ORC. The Syltherm-XLT thermal oil was used as the heat carrier from combustion burner, while R245fa was used as the working fluid for ORC system. Through Aspen Plus, this study analyses the influences on performance of main thermodynamic parameters, showing the possibilities of reaching an optimum performance for different working conditions that are characteristics of different design parameters.

  11. Optimal integration of linear Fresnel reflector with gas turbine cogeneration power plant

    International Nuclear Information System (INIS)

    Dabwan, Yousef N.; Mokheimer, Esmail M.A.

    2017-01-01

    Highlights: • A LFR integrated solar gas turbine cogeneration plant (ISGCPP) has been simulated. • The optimally integrated LFR with gas turbine cogeneration plant can achieve an annual solar share of 23%. • Optimal integration of LFR with gas turbine cogeneration system can reduce CO 2 emission by 18%. • Compared to a fully-solar-powered LFR plant, the optimal ISGCPP reduces the LEC by 83%. • ISGCPP reduces the LEC by 50% compared to plants integrated with carbon capture technology. - Abstract: Solar energy is an abundant resource in many countries in the Sunbelt, especially in the middle east, countries, where recent expansion in the utilization of natural gas for electricity generation has created a significant base for introducing integrated solar‐natural gas power plants (ISGPP) as an optimal solution for electricity generation in these countries. ISGPP reduces the need for thermal energy storage in traditional concentrated solar thermal plants and results in dispatchable power on demand at lower cost than stand-alone concentrated thermal power and much cheaper than photovoltaic plants. Moreover, integrating concentrated solar power (CSP) with conventional fossil fuel based thermal power plants is quite suitable for large-scale central electric power generation plants and it can be implemented in the design of new installed plants or during retrofitting of existing plants. The main objective of the present work is to investigate the possible modifications of an existing gas turbine cogeneration plant, which has a gas turbine of 150 MWe electricity generation capacity and produces steam at a rate of 81.4 at 394 °C and 45.88 bars for an industrial process, via integrating it with concentrated solar power system. In this regard, many simulations have been carried out using Thermoflow software to explore the thermo-economic performance of the gas turbine cogeneration plant integrated with LFR concentrated solar power field. Different electricity

  12. An integration scheme for stiff solid-gas reactor models

    Directory of Open Access Journals (Sweden)

    Bjarne A. Foss

    2001-04-01

    Full Text Available Many dynamic models encounter numerical integration problems because of a large span in the dynamic modes. In this paper we develop a numerical integration scheme for systems that include a gas phase, and solid and liquid phases, such as a gas-solid reactor. The method is based on neglecting fast dynamic modes and exploiting the structure of the algebraic equations. The integration method is suitable for a large class of industrially relevant systems. The methodology has proven remarkably efficient. It has in practice performed excellent and been a key factor for the success of the industrial simulator for electrochemical furnaces for ferro-alloy production.

  13. Integrated hot fuel gas cleaning for advanced gasification combined cycle process

    Energy Technology Data Exchange (ETDEWEB)

    Nieminen, M.; Kangasmaa, K.; Laatikainen, J.; Staahlberg, P.; Kurkela, E. [VTT Energy, Espoo (Finland). Gasification and Advanced Combustion

    1996-12-01

    The fate of halogens in pressurised fluidized-bed gasification and hot gas filtration is determined. Potential halogen removal sorbents, suitable for integrated hot gas cleaning, are screened and some selected sorbents are tested in bench scale. Finally, halogen removal results are verified using the PDU-scale pressurised fluidized-bed gasification and integrated hot gas cleaning facilities of VTT. The project is part of the JOULE II Extension programme of the European Union. (author)

  14. Heterogeneous Monolithic Integration of Single-Crystal Organic Materials.

    Science.gov (United States)

    Park, Kyung Sun; Baek, Jangmi; Park, Yoonkyung; Lee, Lynn; Hyon, Jinho; Koo Lee, Yong-Eun; Shrestha, Nabeen K; Kang, Youngjong; Sung, Myung Mo

    2017-02-01

    Manufacturing high-performance organic electronic circuits requires the effective heterogeneous integration of different nanoscale organic materials with uniform morphology and high crystallinity in a desired arrangement. In particular, the development of high-performance organic electronic and optoelectronic devices relies on high-quality single crystals that show optimal intrinsic charge-transport properties and electrical performance. Moreover, the heterogeneous integration of organic materials on a single substrate in a monolithic way is highly demanded for the production of fundamental organic electronic components as well as complex integrated circuits. Many of the various methods that have been designed to pattern multiple heterogeneous organic materials on a substrate and the heterogeneous integration of organic single crystals with their crystal growth are described here. Critical issues that have been encountered in the development of high-performance organic integrated electronics are also addressed. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  15. Integrated failure probability estimation based on structural integrity analysis and failure data: Natural gas pipeline case

    International Nuclear Information System (INIS)

    Dundulis, Gintautas; Žutautaitė, Inga; Janulionis, Remigijus; Ušpuras, Eugenijus; Rimkevičius, Sigitas; Eid, Mohamed

    2016-01-01

    In this paper, the authors present an approach as an overall framework for the estimation of the failure probability of pipelines based on: the results of the deterministic-probabilistic structural integrity analysis (taking into account loads, material properties, geometry, boundary conditions, crack size, and defected zone thickness), the corrosion rate, the number of defects and failure data (involved into the model via application of Bayesian method). The proposed approach is applied to estimate the failure probability of a selected part of the Lithuanian natural gas transmission network. The presented approach for the estimation of integrated failure probability is a combination of several different analyses allowing us to obtain: the critical crack's length and depth, the failure probability of the defected zone thickness, dependency of the failure probability on the age of the natural gas transmission pipeline. A model's uncertainty analysis and uncertainty propagation analysis are performed, as well. - Highlights: • Degradation mechanisms of natural gas transmission pipelines. • Fracture mechanic analysis of the pipe with crack. • Stress evaluation of the pipe with critical crack. • Deterministic-probabilistic structural integrity analysis of gas pipeline. • Integrated estimation of pipeline failure probability by Bayesian method.

  16. Risk and integrity management system for PETRONAS Gas Berhad's gas and liquid hydrocarbon pipelines

    Energy Technology Data Exchange (ETDEWEB)

    Khalid, Tuan Hj. Ahmad Nadzri bin; Nasir, Osman; Napiah, Mohd Nazmi Mohd Ali [PETRONAS Gas Berhad, Johor (Malaysia); Choong, Evelyn

    2005-07-01

    PETRONAS Gas Berhad (PGB), Malaysia currently operates one of Southeast Asia's largest onshore pipeline systems comprising more than 2,500 km of large diameter high pressure gas and liquid transmission, supply and lateral pipelines. Recognizing the value of a risk based approach to pipeline integrity management program, in 2002 PGB implemented a customized and fully integrated Risk and Integrity Management System (RIMS) which included software modules for: data management; semi-quantitative risk assessment; risk control cost benefit analyses; defect assessment; corrosion growth modeling; and reporting. As part of this project, a benchmarking study performed jointly with the contractor, PGB's pipeline integrity programs were also compared with a broad group of international pipeline operators. This study compared the relative ranking position of PGB pre- and post implementation of RIMS. It demonstrated that implementation of RIMS places PGB in a select group of first quartile international pipeline operators, with respect to the implementation of pipeline integrity management best practice. This paper describes the functionalities of RIMS system and how it has benefited PGB, which have been realized to date from its implementation. (author)

  17. Part-Load Performance of aWet Indirectly Fired Gas Turbine Integrated with an Organic Rankine Cycle Turbogenerator

    Directory of Open Access Journals (Sweden)

    Leonardo Pierobon

    2014-12-01

    Full Text Available Over the last years, much attention has been paid to the development of efficient and low-cost power systems for biomass-to-electricity conversion. This paper aims at investigating the design- and part-load performance of an innovative plant based on a wet indirectly fired gas turbine (WIFGT fueled by woodchips and an organic Rankine cycle (ORC turbogenerator. An exergy analysis is performed to identify the sources of inefficiencies, the optimal design variables, and the most suitable working fluid for the organic Rankine process. This step enables to parametrize the part-load model of the plant and to estimate its performance at different power outputs. The novel plant has a nominal power of 250 kW and a thermal efficiency of 43%. The major irreversibilities take place in the burner, recuperator, compressor and in the condenser. Toluene is the optimal working fluid for the organic Rankine engine. The part-load investigation indicates that the plant can operate at high efficiencies over a wide range of power outputs (50%–100%, with a peak thermal efficiency of 45% at around 80% load. While the ORC turbogenerator is responsible for the efficiency drop at low capacities, the off-design performance is governed by the efficiency characteristics of the compressor and turbine serving the gas turbine unit.

  18. Integrating Student Organizations into Typewriting.

    Science.gov (United States)

    Munday, Sandy

    1978-01-01

    The author states that typewriting activities related to student organizations may be integrated into typewriting and other classes in which typewriting skills are needed. She cites advantages of typing in student organizations and suggests selected classroom typing activities to motivate students and also benefit student organizations. (MF)

  19. Conveyance of natural gas. Organization and regulation

    International Nuclear Information System (INIS)

    1995-01-01

    This International Energy Agency (IEA) study deals with the conveyance of natural gas. The socio-economic factors are given as well as the different organization and regulations modes of natural gas conveyance and storage in the IEA countries and in central and eastern Europe. The main questions forming the subject of discussions in the IEA countries are analyzed too. (O.L.). 50 refs., 55 figs., 16 tabs

  20. Small biogas plant with integrated gas and stirrer bellows. Kleinbiogasanlage mit integriertem Gas- und Ruehrbalg

    Energy Technology Data Exchange (ETDEWEB)

    Anon,

    1985-09-12

    The content of a flexible rectangular septic tank is stirred under the pressure produced by the gas generated by the rotting mass by means of integrated gas and stirring bellows. Their volume is indirectly connected via a gas pipe with the volume of the container, so that the gas formed in the septic tank can reach the bellows via this pipe and can expand this, which causes mixing and at the same time the rotting liquid exerts a pressure on the gas in the bellows. In this way, one can provide gas constantly under pressure. The formation of sinking and floating layers is prevented.

  1. Solid Organic Deposition During Gas Injection Studies

    DEFF Research Database (Denmark)

    Dandekar, Abhijit Y.; Andersen, Simon Ivar; Stenby, Erling Halfdan

    2000-01-01

    Recently a series of first contact miscibility (swelling) experiments have been performed on undersaturated light and heavy oils using LPG rich and methane rich injection gases, in which solid organic deposition was observed. A compositional gradient in the oils during the gas injection process....... The asphaltene content of the different oil samples were determined by the TP 143 method. The standard asphaltenes and the solid organic deposit recovered from the swelling tests were analyzed using FTIR, HPLC-SEC and H-1 NMR. The aim of these analyses is to reveal the molecular nature of the deposits formed...... during the gas injection process in comparison with the standard asphaltenes in order to understand the mechanisms involved in asphaltene deposition....

  2. Integrated marketing communications in sport organizations

    Directory of Open Access Journals (Sweden)

    Gašović Milan

    2011-01-01

    Full Text Available Integrated marketing communications represent the unification of organization's marketing and communication activities. Sports organizations have the emphasized need for effective communication with their environment (the public, the media, advertisers, sponsors, and other subjects interested in their offer. Elements of the integrated marketing communications are: advertising, personal selling, sales promotion, publicity, public relations, direct marketing, Internet communications etc. Each of these elements has some specifics which marketing specialists in sports organizations need to understand.

  3. Study on Gas-liquid Falling Film Flow in Internal Heat Integrated Distillation Column

    Science.gov (United States)

    Liu, Chong

    2017-10-01

    Gas-liquid internally heat integrated distillation column falling film flow with nonlinear characteristics, study on gas liquid falling film flow regulation control law, can reduce emissions of the distillation column, and it can improve the quality of products. According to the distribution of gas-liquid mass balance internally heat integrated distillation column independent region, distribution model of heat transfer coefficient of building internal heat integrated distillation tower is obtained liquid distillation falling film flow in the saturated vapour pressure of liquid water balance, using heat transfer equation and energy equation to balance the relationship between the circulating iterative gas-liquid falling film flow area, flow parameter information, at a given temperature, pressure conditions, gas-liquid flow falling film theory makes the optimal parameters to achieve the best fitting value with the measured values. The results show that the geometric gas-liquid internally heat integrated distillation column falling film flow heat exchange area and import column thermostat, the average temperature has significant. The positive correlation between the heat exchanger tube entrance due to temperature difference between inside and outside, the heat flux is larger, with the increase of internal heat integrated distillation column temperature, the slope decreases its temperature rise, which accurately describes the internal gas-liquid heat integrated distillation tower falling film flow regularity, take appropriate measures to promote the enhancement of heat transfer. It can enhance the overall efficiency of the heat exchanger.

  4. Integrated marketing communications in sport organizations

    OpenAIRE

    Gašović Milan

    2011-01-01

    Integrated marketing communications represent the unification of organization's marketing and communication activities. Sports organizations have the emphasized need for effective communication with their environment (the public, the media, advertisers, sponsors, and other subjects interested in their offer). Elements of the integrated marketing communications are: advertising, personal selling, sales promotion, publicity, public relations, direct marketing, Internet communications etc. Each ...

  5. Reliability modelling - PETROBRAS 2010 integrated gas supply chain

    Energy Technology Data Exchange (ETDEWEB)

    Faertes, Denise; Heil, Luciana; Saker, Leonardo; Vieira, Flavia; Risi, Francisco; Domingues, Joaquim; Alvarenga, Tobias; Carvalho, Eduardo; Mussel, Patricia

    2010-09-15

    The purpose of this paper is to present the innovative reliability modeling of Petrobras 2010 integrated gas supply chain. The model represents a challenge in terms of complexity and software robustness. It was jointly developed by PETROBRAS Gas and Power Department and Det Norske Veritas. It was carried out with the objective of evaluating security of supply of 2010 gas network design that was conceived to connect Brazilian Northeast and Southeast regions. To provide best in class analysis, state of the art software was used to quantify the availability and the efficiency of the overall network and its individual components.

  6. The gas-chromatographic and gas-chromatographic-mass-spectrometric identification of halogen-containing organic compounds

    Science.gov (United States)

    Gidaspov, B. V.; Zenkevich, I. G.; Rodin, A. A.

    1989-09-01

    The problem of identifying halogen-containing organic compounds in their gas-chromatographic and gas-chromatographic-mass-spectrometric (GC-MS) determination in different materials has been examined. Particular attention has been paid not to the complete characterisation of methods for carrying out this analysis but to the most important problem of increasing the selectivity at the stages of sampling, separation, and interpretation of the gas-chromatographic and GC-MS information. The bibliography contains 292 references.

  7. Hybrid gas turbine–organic Rankine cycle for seawater desalination by reverse osmosis in a hydrocarbon production facility

    International Nuclear Information System (INIS)

    Eveloy, Valérie; Rodgers, Peter; Qiu, Linyue

    2015-01-01

    Highlights: • Seawater reverse osmosis driven by hybrid gas turbine–organic Rankine power cycle. • High ambient air and seawater temperatures, and high seawater salinity. • Energy–exergy analysis of power and desalination systems for six organic fluids. • Economic viability of waste heat recovery in subsidized utility pricing context. - Abstract: Despite water scarcity, the use of industrial waste heat for seawater desalination has been limited in the Middle East to date. This study evaluates the technical and economic feasibility of integrating on-site gas turbine power generation and reverse osmosis equipment for the production of both electricity and fresh water in a coastal hydrocarbon production facility. Gas turbine exhaust gas waste heat is recovered using an intermediate heat transfer fluid and fed to an organic Rankine cycle evaporator, to generate mechanical power to drive the reverse osmosis high pressure pump. Six candidate organic working fluids are evaluated, namely toluene, benzene, cyclohexane, cyclopentane, n-pentane and R245fa. Thermodynamic and desalination performance are assessed in the harsh climatic and salinity conditions of the Arabian Gulf. The performance metrics considered incorporate electric power and permeate production, thermal and exergy efficiency, specific energy consumption, system size, and permeate quality. Using toluene in the bottoming power cycle, a gain in power generation efficiency of approximately 12% is achieved relative to the existing gas turbine cycle, with an annual average of 2260 m"3/h of fresh water produced. Depending upon the projected evolution of local water prices, the investment becomes profitable after two to four years, with an end-of-life net present value of 220–380 million USD, and internal rate of return of 26–48%.

  8. Volatile organic carbon/air separation test using gas membranes

    International Nuclear Information System (INIS)

    King, C.V.; Kaschemekat, J.

    1993-08-01

    An estimated 900 metric tons of carbon tetrachloride were discharged to soil columns during the Plutonium Finishing Plant Operations at the Hanford Site. The largest percentage of this volatile organic compound was found in the vadose region of the 200 West Area. Using a Vacuum Extraction System, the volatile organic compound was drawn from the soil in an air mixture at a concentration of about 1,000 parts per million. The volatile organic compounds were absorbed from the air stream using granulated activated carbon canisters. A gas membrane separation system, developed by Membrane Technology and Research, Inc., was tested at the Vacuum Extraction System site to determine if the volatile organic compound load on the granulated activated carbon could be reduced. The Vacuum Extraction System condensed most of the volatile organic compound into liquid carbon tetrachloride and vented the residual gas stream into the granulated activated carbon. This system reduced the cost of operation about $5/kilogram of volatile organic compound removed

  9. Organic Substances from Unconventional Oil and Gas Production in Shale

    Science.gov (United States)

    Orem, W. H.; Varonka, M.; Crosby, L.; Schell, T.; Bates, A.; Engle, M.

    2014-12-01

    Unconventional oil and gas (UOG) production has emerged as an important element in the US and world energy mix. Technological innovations in the oil and gas industry, especially horizontal drilling and hydraulic fracturing, allow for the enhanced release of oil and natural gas from shale compared to conventional oil and gas production. This has made commercial exploitation possible on a large scale. Although UOG is enormously successful, there is surprisingly little known about the effects of this technology on the targeted shale formation and on environmental impacts of oil and gas production at the surface. We examined water samples from both conventional and UOG shale wells to determine the composition, source and fate of organic substances present. Extraction of hydrocarbon from shale plays involves the creation and expansion of fractures through the hydraulic fracturing process. This process involves the injection of large volumes of a water-sand mix treated with organic and inorganic chemicals to assist the process and prop open the fractures created. Formation water from a well in the New Albany Shale that was not hydraulically fractured (no injected chemicals) had total organic carbon (TOC) levels that averaged 8 mg/L, and organic substances that included: long-chain fatty acids, alkanes, polycyclic aromatic hydrocarbons, heterocyclic compounds, alkyl benzenes, and alkyl phenols. In contrast, water from UOG production in the Marcellus Shale had TOC levels as high as 5,500 mg/L, and contained a range of organic chemicals including, solvents, biocides, scale inhibitors, and other organic chemicals at thousands of μg/L for individual compounds. These chemicals and TOC decreased rapidly over the first 20 days of water recovery as injected fluids were recovered, but residual organic compounds (some naturally-occurring) remained up to 250 days after the start of water recovery (TOC 10-30 mg/L). Results show how hydraulic fracturing changes the organic

  10. Microporous Organic Materials for Membrane-Based Gas Separation.

    Science.gov (United States)

    Zou, Xiaoqin; Zhu, Guangshan

    2018-01-01

    Membrane materials with excellent selectivity and high permeability are crucial to efficient membrane gas separation. Microporous organic materials have evolved as an alternative candidate for fabricating membranes due to their inherent attributes, such as permanent porosity, high surface area, and good processability. Herein, a unique pore-chemistry concept for the designed synthesis of microporous organic membranes, with an emphasis on the relationship between pore structures and membrane performances, is introduced. The latest advances in microporous organic materials for potential membrane application in gas separation of H 2 , CO 2 , O 2 , and other industrially relevant gases are summarized. Representative examples of the recent progress in highly selective and permeable membranes are highlighted with some fundamental analyses from pore characteristics, followed by a brief perspective on future research directions. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  11. Biodigestor for organic waste gas; Biodigestor para o gas do lixo organico

    Energy Technology Data Exchange (ETDEWEB)

    Ferreira, Carla Miranda; Fernandes, Carla Barbosa; Souza, Aline Vieira da Silva e; Melo, Cibelly Caroliny Santos; Sales, Jefferson Santos; Frade, Marcelo Lorenzo; Machado, Marcus Vinicius; Frade, Matheus Costa; Gomes, Natashua Lauar; Costa, Pedro Henrique de Andrade; Moraes, Rodrigo de Almeida; Estrella, Thales Goncalves; Lima, Miriam Cristina Pontello Barbosa [Centro Universitario de Belo Horizonte (UniBH), MG (Brazil)], e-mails: carlam.ferreira@yahoo.com.br, miriam.pontello@gmail.com

    2011-07-01

    This article to present an alternative reuse os the gas produced by garbage, through the construction of a digester, with a view to preserving the environment through renewable energy. The energy produced by this system is obtained from the decomposition of organic waste is biogas, made up of gases such as methane (CH{sub 4}) and carbon dioxide (CO{sub 2}). This experiment verifies the possibility of using methane gas as an alternative to the operation of a domestic stove. (author)

  12. Integration and test planning patterns in different organizations

    NARCIS (Netherlands)

    Jong, de I.S.M.; Boumen, R.; Mortel - Fronczak, van de J.M.; Rooda, J.E.; Tretmans, J.

    2007-01-01

    Planning an integration and test phase is often done by experts in the visited organizations. These experts have a thorough knowledge about the system, integration and testing and the business drivers of an organization. An integration and test plan developedfor an airplane is different than the

  13. Integrated approach to gas accumulation identification in Field M

    International Nuclear Information System (INIS)

    Malyshevskaya, K; Rukavishnikov, V; Belozerov, B; Podnebesnikh, A

    2015-01-01

    The given paper describes how the integration of different methods, such as core data, well logs, production logging, seismic data and well test analysis, was used to solve the problem of determining gas accumulation boundaries in sediment complex PK1-3 of Field M. This paper is devoted to the block with wells 2, 36, 49, 85, 127, 148 of the field, since it is characterized by high uncertainty, sc. recently drilled wells 1V, 2V and 120 have produced oil, although according to the present-day geological concept they were considered to be gas saturated in the intervals investigated with production logging. Besides, well 127 that was presumably oil saturated has produced gas. By accounting mismatching production data and the geological concept, the authors have supposed that PK1-3 gas accumulation is characterized by a more complex structure than it was supposed by the predecessors and it is represented by reservoir compartmentalization and high heterogeneity. Therefore, the main goal of the work was to revise the distribution of gas saturated reservoir within the PK1-3 sediment complex. To achieve this goal, the authors have set the following tasks: to revise the geological correlation and gas oil contact; to carry out fault interpretation by means of seismic and well test data; to determine areal facies distribution on the basis of integrated core, perform a log motifs and seismic facies analysis. Thus, the estimation of the gas saturated reservoir portion was implemented in two stages: defining the boundary of gas accumulation in depth on the basis of well logs, production data and fault interpretation; reservoir distribution determination on the basis of the seismic facies analysis within the derived gas accumulation boundary

  14. The generalized model of organization and planning of regional gas supply monitoring

    Directory of Open Access Journals (Sweden)

    Maria V. Shevchenko

    2015-12-01

    Full Text Available At the moment, gas is one of the most promising types of fuel in Ukraine. In this regard, the problems associated with its transportation in the regional system of gas supply are relevant. Now it is not completely solved and needs detailed study the problem of monitoring the regional gas supply system. Aim: The aim of the study is to improve the efficiency of the regional gas supply system at the expense of the organization and planning of gas transport monitoring and, in the future, the synthesis of the monitoring system of regional gas supply. Materials and Methods: The generalized model of organization and planning of monitoring regional gas suppliers were developed to achieve this goal. It allows making decisions on the organization of the monitoring system. In addition, this model makes it possible to plan under conditions of multicriteriality and uncertainty of the source data. Results: The basic criteria and constraints for solving the problem of organizing and planning the monitoring system of regional gas supply are proposed in this work. The corresponding computations were made to confirm the assumptions. The calculations were carried out in context of uncertainty of input data using a set of methods for the analysis of hierarchies, exhaustive search, as well as the methods of decision making in context of uncertainty.

  15. Vertical integration in the natural gas market. An industrial economic consideration; Vertikale Integration im Erdgasmarkt. Eine industrieoekonomische Betrachtung

    Energy Technology Data Exchange (ETDEWEB)

    Schumacher, Thomas

    2011-07-01

    The author of the book under consideration analyzes the effects of vertical integration in the German natural gas market. The impact of these effects on the current and future competition in the natural gas market is analysed. In particular, the corporate connections between natural gas producers and natural gas suppliers have to be considered energy-politically critical.

  16. [Is merging organizations the solution to service integration?].

    Science.gov (United States)

    Demers, Louis; Dupuis, Alain; Poirier, Mario

    2002-01-01

    Organizational models inherited from the time when institutionalizing patients was common practice are now obsolete. Service coordination, undergone earlier within a same institution, is now governed by professionnals linked to various organizations and different settings. One of the difficulties of integration of these services is that contributing organizations often continue to operate individually, consequently going against the pursued goal. The solution most often proposed to counter this compartimentalization consists in reinforcing integration of organizations, which will in time favor integration of various services. One of the ways to realize this organizational integration is to reduce the number of existing organizations, by merging for example, a certain number of them. It is this path of hierarchical organization that the Québec health care system has taken during the 1990. Other paths that of networking have also been experienced during the same period. To judge of the relevance of these options, the authors propose a reversal of the dominating perspective according to which service integration necessarily pass through installing mecanisms of organizational integration. Withought minimizing the importance of such mecanisms, the authors put forth that integration of services commands first and foremost collaboration between professional health workers. Through this angle, the relevance of an organizational integration model depends on the impact it will have on the capacity and willingness of health workers to work in a concerted way. The authors submit that the fact of giving to a sole authority the govern of existing organizations is not the panacea some would like to believe.

  17. How can natural gas markets be competitively organized

    International Nuclear Information System (INIS)

    Funk, C.

    1992-01-01

    In this paper it will be discussed how to most effectively give room to competitive forces in natural gas markets, given the traditional merchant pipeline as point of departure. Alternative models of organizing the market will be reviewed: we first consider decreasing barriers to entry and then analyze advantages and drawbacks of a third party access system. In this context different forms of implementing a competitive market for transportation capacity and coordinating it with gas trade are discussed, among them a simultaneous auction of gas and transmission capacity. Finally a hub system of point markets in conjunction with third party access will be suggested to allow for competitive markets for gas and transportation service. 33 refs

  18. Problems in the wellbore integrity of a shale gas horizontal well and corresponding countermeasures

    Directory of Open Access Journals (Sweden)

    Zhonglan Tian

    2015-12-01

    Full Text Available In the Changning–Weiyuan national shale gas demonstration area, SW Sichuan Basin, the wellbore integrity damage occurs in some shale gas wells and has direct effect on the gas production rate of single shale gas horizontal well. After statistics analysis was performed on the problems related with wellbore integrity, such as casing damage, casing running difficulty and cement sheath blow-by, the multi-factor coupling casing stress calculation and evaluation mode laws established. Then study was conducted on the influential mechanism of multi-factor coupling (temperature effect, casing bending and axial pressure on casing damage. The shale slip mechanism and its relationship with casing sheared formation were analyzed by using the Mohr–Coulomb criterion. Inversion analysis was performed on the main controlling factors of casing friction by using the developed casing hook load prediction and friction analysis software. And finally, based on the characteristics of shale gas horizontal wells, wellbore integrity control measures were proposed in terms of design and construction process, so as to improve the drilling quality (DQ. More specifically, shale gas well casing design calculation method and check standard were modified, well structure and full bore hole trajectory design were optimized, drilling quality was improved, cement properties were optimized and cement sealing integrity during fracturing process was checked. These research findings are significant in the design and management of future shale gas borehole integrity.

  19. Removal of organic compounds from shale gas flowback water

    NARCIS (Netherlands)

    Butkovskyi, Andrii; Faber, Ann-Hélène; Wang, Yue; Grolle, Katja; Hofman-Caris, Roberta; Bruning, Harry; Van Wezel, Annemarie P.; Rijnaarts, Huub H M

    2018-01-01

    Ozonation, sorption to granular activated carbon and aerobic degradation were compared as potential treatment methods for removal of dissolved organic carbon (DOC) fractions and selected organic compounds from shale gas flowback water after pre-treatment in dissolved air flotation unit. Flowback

  20. Integrated natural gas-electricity resource adequacy planning in Latin America

    International Nuclear Information System (INIS)

    Hammons, T.J.; Barroso, L.A.; Rudnick, H.

    2010-01-01

    Latin America is among the most dynamic regions for natural gas and electricity development. This paper discussed natural gas-electricity resource adequacy planning for Brazil, Chile, Mexico, and Colombia. The perspectives for creating an integrated market in the Southern Cone of Latin America were also presented. The continent has abundant natural gas reserves and high-growth energy markets. Many countries are promoting the use of natural gas for power generation in an effort to diversify away from heavy investments in hydropower and costly oil. These measures have created competition between hydro- and thermal generation, the breaking of cross-country natural gas agreements, as well as competition between natural gas and other resources for power generation and transmission.

  1. 49 CFR 571.303 - Standard No. 303; Fuel system integrity of compressed natural gas vehicles.

    Science.gov (United States)

    2010-10-01

    ... compressed natural gas vehicles. 571.303 Section 571.303 Transportation Other Regulations Relating to... system integrity of compressed natural gas vehicles. S1. Scope. This standard specifies requirements for the integrity of motor vehicle fuel systems using compressed natural gas (CNG), including the CNG fuel...

  2. Organic Pollutants in Shale Gas Flowback and Produced Waters

    NARCIS (Netherlands)

    Butkovskyi, Andrii; Bruning, Harry; Kools, Stefan A.E.; Rijnaarts, Huub H.M.; Wezel, van Annemarie P.

    2017-01-01

    Organic contaminants in shale gas flowback and produced water (FPW) are traditionally expressed as total organic carbon (TOC) or chemical oxygen demand (COD), though these parameters do not provide information on the toxicity and environmental fate of individual components. This review addresses

  3. Optical electronics self-organized integration and applications

    CERN Document Server

    Yoshimura, Tetsuzo

    2012-01-01

    IntroductionFrom Electronics to Optical ElectronicsAnalysis Tools for Optical CircuitsSelf-Organized Optical Waveguides: Theoretical AnalysisSelf-Organized Optical Waveguides: Experimental DemonstrationsOptical Waveguide Films with Vertical Mirrors 3-D Optical Circuits with Stacked Waveguide Films Heterogeneous Thin-Film Device IntegrationOptical Switches OE Hardware Built by Optical ElectronicsIntegrated Solar Energy Conversion SystemsFuture Challenges.

  4. Independents in European Gas Markets after liberalisation - downstream integration of upstream oil and gas companies

    International Nuclear Information System (INIS)

    Eikeland, Per Ove

    2005-01-01

    A central objective of gas market liberalisation in Europe in the 1990s was to increase competition by opening end-use markets for independent suppliers. Upstream oil and gas companies in Europe reacted to this opportunity by announcing strategies to integrate forward in European gas markets. By late 2004, however, upstream companies still recorded generally weak downstream strategy implementation in Europe. The article concludes that this general implementation gap should be explained by political failure in EU member states to abolish gas market barriers to entry for independents. Variation between companies in degree of implementation should be explained by variation in conditions in the companies' home markets / wider business spheres and internal company factors. (Author)

  5. How can natural gas markets be competitively organized

    International Nuclear Information System (INIS)

    Funk, C.

    1992-01-01

    In this paper it will be discussed how to most effectively give room to competitive forces in natural gas markets, given the traditional merchant pipeline as point of departure. Alternative models of organizing the market will be reviewed: we first consider decreasing barriers to entry and then analyse advantages and drawbacks of a third party access system. In this context different forms of implementing a competitive market for transportation capacity and coordinating it with gas trade are discussed, among them a simultaneous auction of gas and transmission capacity. Finally a hub system of point markets will be suggested to improve the currently implemented third party access system and to allow for competitive markets for gas and transportation service. 33 refs., 6 figs

  6. Dynamic Optimal Energy Flow in the Integrated Natural Gas and Electrical Power Systems

    DEFF Research Database (Denmark)

    Fang, Jiakun; Zeng, Qing; Ai, Xiaomeng

    2018-01-01

    . Simulation on the test case illustrates the success of the modelling and the beneficial roles of the power-to-gas are analyzed. The proposed model can be used in the decision support for both planning and operation of the coordinated natural gas and electrical power systems.......This work focuses on the optimal operation of the integrated gas and electrical power system with bi-directional energy conversion. Considering the different response times of the gas and power systems, the transient gas flow and steady- state power flow are combined to formulate the dynamic...... optimal energy flow in the integrated gas and power systems. With proper assumptions and simplifications, the problem is transformed into a single stage linear programming. And only a single stage linear programming is needed to obtain the optimal operation strategy for both gas and power systems...

  7. An integrated photosensor readout for gas proportional scintillation counters

    International Nuclear Information System (INIS)

    Lopes, J.A.M.; Santos, J.M.F. dos; Conde, C.A.N.

    1996-01-01

    A xenon gas proportional scintillation counter has been instrumented with a novel photosensor that replaces the photomultiplier tube normally used to detect the VUV secondary scintillation light. In this implementation, the collection grid of a planar gas proportional scintillation counter also functions as a multiwire proportional chamber to amplify and detect the photoelectrons emitted by a reflective CsI photocathode in direct contact with the xenon gas. This integrated concept combines greater simplicity, compactness, and ruggedness (no optical window is used) with low power consumption. An energy resolution of 12% was obtained for 59.6 keV x-rays

  8. The integration of gas and electricity: potential effects on competition in markets

    International Nuclear Information System (INIS)

    Lopez Milla, J.

    2007-01-01

    During the last years, an increasing number of gas and electricity companies have integrated their activities in both sectors. Following this trend, several Mergers and Acquisitions between gas and electricity companies have emerged, and some of them have been cross-borders operations that have given rise to multinational enterprises. This paper analyses the causes of the integration of gas and electricity activities, and examines its implications on regulation and competition policy, showing that these changes in the energy industry raise new challenges and compel to adopt new measures in that field of the economic policy. (Author) 25 refs

  9. Greenhouse gas emissions from integrated urban drainage systems

    DEFF Research Database (Denmark)

    Mannina, Giorgio; Butler, David; Benedetti, Lorenzo

    2018-01-01

    As sources of greenhouse gas (GHG) emissions, integrated urban drainage systems (IUDSs) (i.e., sewer systems, wastewater treatment plants and receiving water bodies) contribute to climate change. This paper, produced by the International Working Group on Data and Models, which works under the IWA...

  10. Risk and integrity management system for PETRONAS Gas Berhad's gas and liquid hydrocarbon pipelines

    Energy Technology Data Exchange (ETDEWEB)

    Khalid, Tuan Hj. Ahmad Nadzri bin; Nasir, Osman; Napiah, Mohd Nazmi Mohd Ali [PETRONAS Gas Berhad, Johor (Malaysia); Choong, Evelyn

    2005-07-01

    PETRONAS Gas Berhad (PGB), Malaysia currently operates one of Southeast Asia's largest onshore pipeline systems comprising more than 2,500 km of large diameter high pressure gas and liquid transmission, supply and lateral pipelines. Recognizing the value of a risk based approach to pipeline integrity management program, in 2002 PGB implemented a customized and fully integrated Risk and Integrity Management System (RIMS) which included software modules for: data management; semi-quantitative risk assessment; risk control cost benefit analyses; defect assessment; corrosion growth modeling; and reporting. As part of this project, a benchmarking study performed jointly with the contractor, PGB's pipeline integrity programs were also compared with a broad group of international pipeline operators. This study compared the relative ranking position of PGB pre- and post implementation of RIMS. It demonstrated that implementation of RIMS places PGB in a select group of first quartile international pipeline operators, with respect to the implementation of pipeline integrity management best practice. This paper describes the functionalities of RIMS system and how it has benefited PGB, which have been realized to date from its implementation. (author)

  11. Probabilistic Steady-State Operation and Interaction Analysis of Integrated Electricity, Gas and Heating Systems

    Directory of Open Access Journals (Sweden)

    Lun Yang

    2018-04-01

    Full Text Available The existing studies on probabilistic steady-state analysis of integrated energy systems (IES are limited to integrated electricity and gas networks or integrated electricity and heating networks. This paper proposes a probabilistic steady-state analysis of integrated electricity, gas and heating networks (EGH-IES. Four typical operation modes of an EGH-IES are presented at first. The probabilistic energy flow problem of the EGS-IES considering its operation modes and correlated uncertainties in wind/solar power and electricity/gas/heat loads is then formulated and solved by the Monte Carlo method based on Latin hypercube sampling and Nataf transformation. Numerical simulations are conducted on a sample EGH-IES working in the “electricity/gas following heat” mode to verify the probabilistic analysis proposed in this paper and to study the effects of uncertainties and correlations on the operation of the EGH-IES, especially uncertainty transmissions among the subnetworks.

  12. Organic richness and gas generation potential of Permian Barren

    Indian Academy of Sciences (India)

    The organic geochemistry of shales in terms of its organic richness, hydrocarbon source potential, thermal maturity, depositional environment, etc., are essential stipulations for shale gas resources assessment. In this study, a total of 32 core samples of Permian Barren Measures from four boreholes in Raniganj field of ...

  13. Optimization of the integrated gas balance planning with PLANGAS; Planejamento integrado e otimizado da movimentacao do gas utilizando o PLANGAS

    Energy Technology Data Exchange (ETDEWEB)

    Iamashita, Edson K.; Iachan, Roberto; Justiniano, Luiz R.S.; Silva, Nelson de M. da; Chaves, Jose R. da C. [PETROBRAS, Rio de Janeiro, RJ (Brazil)

    2004-07-01

    In this paper we propose to explain PLANGAS system, developed by PETROBRAS in order to subsidize the natural gas balance integrated planning of Campos Basin. This system performs the natural gas balance forecasting of a complex pipeline network, with a great deal of platforms, and wide operation possibilities correlated to the large number of variables. The production increasing, equipment process, compressors and pipeline capacity, and even gas price variation are examples considered in gas balance planning. The PLANGAS uses an optimizing mathematical model with linear programming and a database that optimizes the integrated gas balance forecasting, maximizing earnings, considering all the network restrictions. PLANGAS has been in use since 1999, and in 2003, was improved with new advances. This improvement reduced the simulation time providing opportunity to a better result analysis, as well as, higher quality plans. (author)

  14. Norwegian gas sale in an international perspective - future-directed organization

    International Nuclear Information System (INIS)

    Saga, B.P.

    1996-01-01

    This paper deals with future organization of the Norwegian gas sale. The author gives at first a brief review of the Norwegian gas sale, and then a discussion on which type of criteria being based on by evaluation of models for the Norwegian gas sale. A comparison on which type of criteria used in other gas supplying countries is discussed. The author discusses tendencies of development in the international market including Europe, and is questioning if the existing system of gas sale is prepared to meet future challenges. Several types of proposals are presented to solve these challenges. 5 figs

  15. Integrated approach to natural gas utilization in the Asia Pacific region

    International Nuclear Information System (INIS)

    Hovdestad, W.R.; Egbogah, E.O.

    1995-01-01

    The rapidly expanding economies in the Pacific Rim have placed increasing demands upon indigenous natural gas supplies in South East Asia and Australia. Competing demands include exports of liquefied natural gas (LNG), domestic consumption, and potential use for enhanced oil recovery (EOR) to extend the useful life of maturing oil fields. An additional competing demand for gas exports may emerge as the interstate pipeline grid is expanded. An integrated approach incorporating the evolving nature of gas demands and discrete physical supplies would provide a means to mitigate against potential mismatching of supply and demand. The consideration of the evolving nature of gas demands could promote economically beneficial changes to gas field development. The development of high carbon dioxide (CO 2 ) content gas fields has been slowed by the lack of a market for CO 2 . Utilization of by-product CO 2 for EOR could improve development economics, thus facilitating earlier development of gas supplies to satisfy gas demands including domestic use and LNG exports. End users would also benefit from the assurance that gas supplies would become available as needed. The maturity and increasingly complex natural gas industry in the Asia Pacific Region has led to a qualitative change. The model of single projects to satisfy single markets is no longer valid. The current environment is more dynamic, creating the need to anticipate changes to market demands and to find value-added markets for by-products. The integrated approach to gas utilization discussed in this paper presents a new model more appropriate to the gas industry existing today in the Asia Pacific Region. This approach is particularly significant to widely discussed proposals for an Asia Pacific energy grid extending to Australia

  16. Printed organic thin-film transistor-based integrated circuits

    International Nuclear Information System (INIS)

    Mandal, Saumen; Noh, Yong-Young

    2015-01-01

    Organic electronics is moving ahead on its journey towards reality. However, this technology will only be possible when it is able to meet specific criteria including flexibility, transparency, disposability and low cost. Printing is one of the conventional techniques to deposit thin films from solution-based ink. It is used worldwide for visual modes of information, and it is now poised to enter into the manufacturing processes of various consumer electronics. The continuous progress made in the field of functional organic semiconductors has achieved high solubility in common solvents as well as high charge carrier mobility, which offers ample opportunity for organic-based printed integrated circuits. In this paper, we present a comprehensive review of all-printed organic thin-film transistor-based integrated circuits, mainly ring oscillators. First, the necessity of all-printed organic integrated circuits is discussed; we consider how the gap between printed electronics and real applications can be bridged. Next, various materials for printed organic integrated circuits are discussed. The features of these circuits and their suitability for electronics using different printing and coating techniques follow. Interconnection technology is equally important to make this product industrially viable; much attention in this review is placed here. For high-frequency operation, channel length should be sufficiently small; this could be achievable with a combination of surface treatment-assisted printing or laser writing. Registration is also an important issue related to printing; the printed gate should be perfectly aligned with the source and drain to minimize parasitic capacitances. All-printed organic inverters and ring oscillators are discussed here, along with their importance. Finally, future applications of all-printed organic integrated circuits are highlighted. (paper)

  17. Well Integrity for Natural Gas Storage in Depleted Reservoirs and Aquifers

    Energy Technology Data Exchange (ETDEWEB)

    Freifeld, Barry M. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Oldenburg, Curtis M. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Jordan, Preston [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Pan, Lehua [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Perfect, Scott [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Morris, Joseph [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); White, Joshua [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Bauer, Stephen [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Blankenship, Douglas [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Roberts, Barry [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Bromhal, Grant [National Energy Technology Lab. (NETL), Morgantown, WV (United States); Glosser, Deborah [National Energy Technology Lab. (NETL), Morgantown, WV (United States); Wyatt, Douglas [National Energy Technology Lab. (NETL), Morgantown, WV (United States); Rose, Kelly [National Energy Technology Lab. (NETL), Morgantown, WV (United States)

    2016-09-02

    Introduction Motivation The 2015-2016 Aliso Canyon/Porter Ranch natural gas well blowout emitted approximately 100,000 tonnes of natural gas (mostly methane, CH4) over four months. The blowout impacted thousands of nearby residents, who were displaced from their homes. The high visibility of the event has led to increased scrutiny of the safety of natural gas storage at the Aliso Canyon facility, as well as broader concern for natural gas storage integrity throughout the country. Federal Review of Well Integrity In April of 2016, the U.S. Department of Energy (DOE), in conjunction with the U.S. Department of Transportation (DOT) through the Pipeline and Hazardous Materials Safety Administration (PHMSA), announced the formation of a new Interagency Task Force on Natural Gas Storage Safety. The Task Force enlisted a group of scientists and engineers at the DOE National Laboratories to review the state of well integrity in natural gas storage in the U.S. The overarching objective of the review is to gather, analyze, catalogue, and disseminate information and findings that can lead to improved natural gas storage safety and security and thus reduce the risk of future events. The “Protecting our Infrastructure of Pipelines and Enhancing Safety Act of 2016’’ or the ‘‘PIPES Act of 2016,’’which was signed into law on June 22, 2016, created an Aliso Canyon Natural Gas Leak Task Force led by the Secretary of Energy and consisting of representatives from the DOT, Environmental Protection Agency (EPA), Department of Health and Human Services, Federal Energy Regulatory Commission (FERC), Department of Commerce and the Department of Interior. The Task Force was asked to perform an analysis of the Aliso Canyon event and make recommendations on preventing similar incidents in the future. The PIPES Act also required that DOT/PHMSA promulgate minimum safety standards for underground storage that would take effect within two years. Background on the DOE

  18. Organic Optical Sensor Based on Monolithic Integration of Organic Electronic Devices

    Directory of Open Access Journals (Sweden)

    Hoi Lam Tam

    2015-09-01

    Full Text Available A novel organic optical sensor that integrates a front organic light-emitting diode (OLED and an organic photodiode (OPD is demonstrated. The stripe-shaped cathode is used in the OLED components to create light signals, while the space between the stripe-shaped cathodes serves as the detection window for integrated OPD units. A MoO3 (5 nm/Ag (15 nm bi-layer inter-electrode is interposed between the vertically stacked OLED and OPD units, serving simultaneously as the cathode for the front OLED and an anode for the upper OPD units in the sensor. In the integrated sensor, the emission of the OLED units is confined by the area of the opaque stripe-shaped cathodes, optimized to maximize the reflected light passing through the window space for detection by the OPD components. This can ensure high OLED emission output, increasing the signal/noise ratio. The design and fabrication flexibility of an integrated OLED/OPD device also has low cost benefits, and is light weight and ultra-thin, making it possible for application in wearable units, finger print identification, image sensors, smart light sources, and compact information systems.

  19. China organic-rich shale geologic features and special shale gas production issues

    Directory of Open Access Journals (Sweden)

    Yiwen Ju

    2014-06-01

    Full Text Available The depositional environment of organic-rich shale and the related tectonic evolution in China are rather different from those in North America. In China, organic-rich shale is not only deposited in marine environment, but also in non-marine environment: marine-continental transitional environment and lacustrine environment. Through analyzing large amount of outcrops and well cores, the geologic features of organic-rich shale, including mineral composition, organic matter richness and type, and lithology stratigraphy, were analyzed, indicating very special characteristics. Meanwhile, the more complex and active tectonic movements in China lead to strong deformation and erosion of organic-rich shale, well-development of fractures and faults, and higher thermal maturity and serious heterogeneity. Co-existence of shale gas, tight sand gas, and coal bed methane (CBM proposes a new topic: whether it is possible to co-produce these gases to reduce cost. Based on the geologic features, the primary production issues of shale gas in China were discussed with suggestions.

  20. Critical Care Organizations: Building and Integrating Academic Programs.

    Science.gov (United States)

    Moore, Jason E; Oropello, John M; Stoltzfus, Daniel; Masur, Henry; Coopersmith, Craig M; Nates, Joseph; Doig, Christopher; Christman, John; Hite, R Duncan; Angus, Derek C; Pastores, Stephen M; Kvetan, Vladimir

    2018-04-01

    Academic medical centers in North America are expanding their missions from the traditional triad of patient care, research, and education to include the broader issue of healthcare delivery improvement. In recent years, integrated Critical Care Organizations have developed within academic centers to better meet the challenges of this broadening mission. The goal of this article was to provide interested administrators and intensivists with the proper resources, lines of communication, and organizational approach to accomplish integration and Critical Care Organization formation effectively. The Academic Critical Care Organization Building section workgroup of the taskforce established regular monthly conference calls to reach consensus on the development of a toolkit utilizing methods proven to advance the development of their own academic Critical Care Organizations. Relevant medical literature was reviewed by literature search. Materials from federal agencies and other national organizations were accessed through the Internet. The Society of Critical Care Medicine convened a taskforce entitled "Academic Leaders in Critical Care Medicine" on February 22, 2016 at the 45th Critical Care Congress using the expertise of successful leaders of advanced governance Critical Care Organizations in North America to develop a toolkit for advancing Critical Care Organizations. Key elements of an academic Critical Care Organization are outlined. The vital missions of multidisciplinary patient care, safety, and quality are linked to the research, education, and professional development missions that enhance the value of such organizations. Core features, benefits, barriers, and recommendations for integration of academic programs within Critical Care Organizations are described. Selected readings and resources to successfully implement the recommendations are provided. Communication with medical school and hospital leadership is discussed. We present the rationale for critical

  1. Process integration of organic Rankine cycle

    International Nuclear Information System (INIS)

    Desai, Nishith B.; Bandyopadhyay, Santanu

    2009-01-01

    An organic Rankine cycle (ORC) uses an organic fluid as a working medium within a Rankine cycle power plant. ORC offers advantages over conventional Rankine cycle with water as the working medium, as ORC generates shaft-work from low to medium temperature heat sources with higher thermodynamic efficiency. The dry and the isentropic fluids are most preferred working fluid for the ORC. The basic ORC can be modified by incorporating both regeneration and turbine bleeding to improve its thermal efficiency. In this paper, 16 different organic fluids have been analyzed as a working medium for the basic as well as modified ORCs. A methodology is also proposed for appropriate integration and optimization of an ORC as a cogeneration process with the background process to generate shaft-work. It has been illustrated that the choice of cycle configuration for appropriate integration with the background process depends on the heat rejection profile of the background process (i.e., the shape of the below pinch portion of the process grand composite curve). The benefits of integrating ORC with the background process and the applicability of the proposed methodology have been demonstrated through illustrative examples.

  2. Bio-testing integral toxicity of corrosion inhibitors, biocides and oil hydrocarbons in oil-and gas-processing industry

    Energy Technology Data Exchange (ETDEWEB)

    Chugunov, V.A.; Kholodenko, V.P.; Irkhina, I.A.; Fomchenkov, V.M.; Novikov, I.A. [State Research Center for Applied Microbiology, Obolensk, Moscow (Russian Federation)

    2004-07-01

    In recent years bioassays have been widely used for assessing levels of contamination of the environment. This is due to the fact that test-organisms provide a general response to toxicants present in samples. Based on microorganisms as test objects, it is possible to develop cheap, sensitive and rapid assays to identify environmental xenobiotics and toxicants. The objective of the research was to develop different microbiological assays for assessing integral toxicity of water environments polluted with corrosion inhibitors, biocides and hydrocarbons in oil- and gas-processing industry. Bio-luminescent, electro-orientational, osmo-optic and microorganism reducing activity assays were used for express evaluation of integral toxicity. They are found to determine promptly integral toxicity of water environments containing various pollutants (oil, oil products, corrosion inhibitors, biocides). Results conclude that the assays may be used for analyzing integral toxicity of water polluted with hydrocarbons, as well as for monitoring of water changes as a result of biodegradation of pollutants by microorganisms and their associations. Using a kit of different assays, it is also possible to evaluate ecological safety of biocides, corrosion inhibitors, and their compositions. Bioassays used as a kit are more effective than each assay individually, allowing one to get complete characterization of a reaction of bacterial test organisms to different environments. (authors)

  3. METHODS FOR ORGANIZATION OF WORKING PROCESS FOR GAS-DIESEL ENGINE

    Directory of Open Access Journals (Sweden)

    G. A. Vershina

    2017-01-01

    Full Text Available Over the past few decades reduction in pollutant emissions has become one of the main directions for further deve- lopment of engine technology. Solution of such problems has led to implementation of catalytic post-treatment systems, new technologies of fuel injection, technology for regulated phases of gas distribution, regulated turbocharger system and, lately, even system for variable compression ratio of engine. Usage of gaseous fuel, in particular gas-diesel process, may be one of the means to reduce air pollution caused by toxic substances and meet growing environmental standards and regulations. In this regard, an analysis of methods for organization of working process for a gas-diesel engine has been conducted in the paper. The paper describes parameters that influence on the nature of gas diesel process, it contains graphics of specific total heat consumption according to ignition portion of diesel fuel and dependence of gas-diesel indices on advance angle for igni-tion portion injection of the diesel fuel. A modern fuel system of gas-diesel engine ГД-243 has been demonstrated in the pa- per. The gas-diesel engine has better environmental characteristics than engines running on diesel fuel or gasoline. According to the European Natural & bio Gas Vehicle Association a significant reduction in emissions is reached at a 50%-substitution level of diesel fuel by gas fuel (methane and in such a case there is a tendency towards even significant emission decrease. In order to ensure widespread application of gaseous fuel as fuel for gas-diesel process it is necessary to develop a new wor- king process, to improve fuel equipment, to enhance injection strategy and fuel supply control. A method for organization of working process for multi-fuel engine has been proposed on the basis of the performed analysis. An application has been submitted for a patent.

  4. Characterization of microbial and chemical composition of shuttle wet waste with permanent gas and volatile organic compound analyses

    Science.gov (United States)

    Peterson, B. V.; Hummerick, M.; Roberts, M. S.; Krumins, V.; Kish, A. L.; Garland, J. L.; Maxwell, S.; Mills, A.

    2004-01-01

    Solid-waste treatment in space for Advanced Life Support, ALS, applications requires that the material can be safely processed and stored in a confined environment. Many solid-wastes are not stable because they are wet (40-90% moisture) and contain levels of soluble organic compounds that can contribute to the growth of undesirable microorganisms with concomitant production of noxious odors. In the absence of integrated Advanced Life Support systems on orbit, permanent gas, trace volatile organic and microbiological analyses were performed on crew refuse returned from the volume F "wet" trash of three consecutive Shuttle missions (STS-105, 109, and 110). These analyses were designed to characterize the short-term biological stability of the material and assess potential crew risks resulting from microbial decay processes during storage. Waste samples were collected post-orbiter landing and sorted into packaging material, food waste, toilet waste, and bulk liquid fractions deposited during flight in the volume F container. Aerobic and anaerobic microbial loads were determined in each fraction by cultivation on R2A and by acridine orange direct count (AODC). Dry and ash weights were performed to determine both water and organic content of the materials. Experiments to determine the aerobic and anaerobic biostability of refuse stored for varying periods of time were performed by on-line monitoring of CO2 and laboratory analysis for production of hydrogen sulfide and methane. Volatile organic compounds and permanent gases were analyzed using EPA Method TO15 by USEPA et al. [EPA Method TO15, The Determination of Volatile Organic Compounds (VOCs) in Ambient Air using SUMMA, Passivated Canister Sampling and Gas Chromatographic Analysis,1999] with gas chromatography/mass spectrometry and by gas chromatography with selective detectors. These baseline measures of waste stream content, labile organics, and microbial load in the volume F Shuttle trash provide data for waste

  5. Gas development plan - Estonia

    International Nuclear Information System (INIS)

    1994-06-01

    The total supply of natural gas to Estonia is provided by the Russian company ''Lentransgas'', a 10 year contract is under negotiation. The gas transmission system is physically a part of the transmission network in the Baltic region which previously operated as an integral part of the USSR gas transmission system. The potential market is too small to justify investment in an alternative pipeline from the North Sea. The general reduction in purchasing power in the former COMECON countries has resulted in a decreased industrial production in Estonia and lead to a steep decline in natural gas consumption in all sectors except households. The Danish firm ''Dansk Olie og Naturgas A/S'' has been requested to assist the Estonian company ''AS Eesti Gaas J.S.C.'' in preparing a gas development plan for Estonia. Phase 1 of this plan aims to provide a detailed description of the status of the existing situation under the headings of gas supply and demand, transmission and distribution, economy and organization. The most important problems related to the current transition of the Estonian gas sector towards operation under market conditions are addressed, focussing on gas supply and market conditions, flow control and metering. The general organization of the gas sector in Estonia is described and possible models for future organization are discussed. Some recommendations are given and areas in need of further investigation are identified. (AB)

  6. Organic positive ions in aircraft gas-turbine engine exhaust

    Science.gov (United States)

    Sorokin, Andrey; Arnold, Frank

    Volatile organic compounds (VOCs) represent a significant fraction of atmospheric aerosol. However the role of organic species emitted by aircraft (as a consequence of the incomplete combustion of fuel in the engine) in nucleation of new volatile particles still remains rather speculative and requires a much more detailed analysis of the underlying mechanisms. Measurements in aircraft exhaust plumes have shown the presence of both different non-methane VOCs (e.g. PartEmis project) and numerous organic cluster ions (MPIK-Heidelberg). However the link between detected organic gas-phase species and measured mass spectrum of cluster ions is uncertain. Unfortunately, up to now there are no models describing the thermodynamics of the formation of primary organic cluster ions in the exhaust of aircraft engines. The aim of this work is to present first results of such a model development. The model includes the block of thermodynamic data based on proton affinities and gas basicities of organic molecules and the block of non-equilibrium kinetics of the cluster ions evolution in the exhaust. The model predicts important features of the measured spectrum of positive ions in the exhaust behind aircraft. It is shown that positive ions emitted by aircraft engines into the atmosphere mostly consist of protonated and hydrated organic cluster ions. The developed model may be explored also in aerosol investigations of the background atmosphere as well as in the analysis of the emission of fine aerosol particles by automobiles.

  7. Towards a Novel Integrated Approach for Estimating Greenhouse Gas Emissions in Support of International Agreements

    Science.gov (United States)

    Reimann, S.; Vollmer, M. K.; Henne, S.; Brunner, D.; Emmenegger, L.; Manning, A.; Fraser, P. J.; Krummel, P. B.; Dunse, B. L.; DeCola, P.; Tarasova, O. A.

    2016-12-01

    In the recently adopted Paris Agreement the community of signatory states has agreed to limit the future global temperature increase between +1.5 °C and +2.0 °C, compared to pre-industrial times. To achieve this goal, emission reduction targets have been submitted by individual nations (called Intended Nationally Determined Contributions, INDCs). Inventories will be used for checking progress towards these envisaged goals. These inventories are calculated by combining information on specific activities (e.g. passenger cars, agriculture) with activity-related, typically IPCC-sanctioned, emission factors - the so-called bottom-up method. These calculated emissions are reported on an annual basis and are checked by external bodies by using the same method. A second independent method estimates emissions by translating greenhouse gas measurements made at regionally representative stations into regional/global emissions using meteorologically-based transport models. In recent years this so-called top-down approach has been substantially advanced into a powerful tool and emission estimates at the national/regional level have become possible. This method is already used in Switzerland, in the United Kingdom and in Australia to estimate greenhouse gas emissions and independently support the national bottom-up emission inventories within the UNFCCC framework. Examples of the comparison of the two independent methods will be presented and the added-value will be discussed. The World Meteorological Organization (WMO) and partner organizations are currently developing a plan to expand this top-down approach and to expand the globally representative GAW network of ground-based stations and remote-sensing platforms and integrate their information with atmospheric transport models. This Integrated Global Greenhouse Gas Information System (IG3IS) initiative will help nations to improve the accuracy of their country-based emissions inventories and their ability to evaluate the

  8. Management systems for high reliability organizations. Integration and effectiveness; Managementsysteme fuer Hochzuverlaessigkeitsorganisationen. Integration und Wirksamkeit

    Energy Technology Data Exchange (ETDEWEB)

    Mayer, Michael

    2015-03-09

    The scope of the thesis is the development of a method for improvement of efficient integrated management systems for high reliability organizations (HRO). A comprehensive analysis of severe accident prevention is performed. Severe accident management, mitigation measures and business continuity management are not included. High reliability organizations are complex and potentially dynamic organization forms that can be inherently dangerous like nuclear power plants, offshore platforms, chemical facilities, large ships or large aircrafts. A recursive generic management system model (RGM) was development based on the following factors: systemic and cybernetic Asepcts; integration of different management fields, high decision quality, integration of efficient methods of safety and risk analysis, integration of human reliability aspects, effectiveness evaluation and improvement.

  9. Visual observation of gas hydrates nucleation and growth at a water - organic liquid interface

    Science.gov (United States)

    Stoporev, Andrey S.; Semenov, Anton P.; Medvedev, Vladimir I.; Sizikov, Artem A.; Gushchin, Pavel A.; Vinokurov, Vladimir A.; Manakov, Andrey Yu.

    2018-03-01

    Visual observation of nucleation sites of methane and methane-ethane-propane hydrates and their further growth in water - organic liquid - gas systems with/without surfactants was carried out. Sapphire Rocking Cell RCS6 with transparent sapphire cells was used. The experiments were conducted at the supercooling ΔTsub = 20.2 °C. Decane, toluene and crude oils were used as organics. Gas hydrate nucleation occurred on water - metal - gas and water - sapphire - organic liquid three-phase contact lines. At the initial stage of growth hydrate crystals rapidly covered the water - gas or water - organics interfaces (depending on the nucleation site). Further hydrate phase accrete on cell walls (sapphire surface) and into the organics volume. At this stage, growth was accompanied by water «drawing out» from under initial hydrate film formed at water - organic interface. Apparently, it takes place due to water capillary inflow in the reaction zone. It was shown that the hydrate crystal morphology depends on the organic phase composition. In the case of water-in-decane emulsion relay hydrate crystallization was observed in the whole sample, originating most likely due to the hydrate crystal intergrowth through decane. Contacts of such crystals with adjacent water droplets result in rapid hydrate crystallization on this droplet.

  10. Framework of Quality Assurance of TEL Integration Into an Educational Organization

    Directory of Open Access Journals (Sweden)

    Airina Volungeviciene

    2014-12-01

    Full Text Available This research paper addresses the issues of integration of technology enhanced learning (TEL into an educational organization. Good practice experience cannot be directly transferred to new organisations due to different contextual conditions. The TEL integration depends significantly upon a very rapid development of services and information communication technologies (ICT. Some organizations have managed to go step by step with the developments and have become leaders in TEL provision, however others, though having successful examples, have not succeeded in reaching the service level they want. While many positive examples exist in research literature, it is rare that institutions have complete strategies or solutions for integrating TEL that meet their specific pre-conditions and satisfy quality assurance parameters at the same time. The research reported here aims at the development of a theoretical framework for quality assurance of TEL integration into educational organizations. During the research, the development of the TEL concept has been discussed, success indicators for TEL integration in an educational organization have been described, the quality parameters of TEL integration into an educational organization have been identified and the model for TEL integration into an organization has been developed.

  11. Electrochemical cell with integrated hydrocarbon gas sensor for automobile exhaust gas; Elektrochemische Zelle mit integriertem Kohlenwasserstoff-Gassensor fuer das Automobilabgas

    Energy Technology Data Exchange (ETDEWEB)

    Biskupski, D.; Moos, R. [Univ. Bayreuth (Germany). Bayreuth Engine Research Center, Lehrstuhl fuer Funktionsmaterialien; Wiesner, K.; Fleischer, M. [Siemens AG, Corporate Technology, CT PS 6, Muenchen (Germany)

    2007-07-01

    In the future sensors will be necessary to control the compliance with hydrocarbon limiting values, allowing a direct detection of the hydrocarbons. Appropriate sensor-active functional materials are metal oxides, which have a hydrocarbon sensitivity but are also dependent on the oxygen partial pressure. It is proposed that the gas-sensing layer should be integrated into an electrochemical cell. The authors show that the integration of a resistive oxygen sensor into a pump cell allows a defined oxygen concentration level at the sensor layer in any exhaust gas.

  12. 75 FR 5244 - Pipeline Safety: Integrity Management Program for Gas Distribution Pipelines; Correction

    Science.gov (United States)

    2010-02-02

    ... Management Program for Gas Distribution Pipelines; Correction AGENCY: Pipeline and Hazardous Materials Safety... DEPARTMENT OF TRANSPORTATION Pipeline and Hazardous Materials Safety Administration 49 CFR Part... Regulations to require operators of gas distribution pipelines to develop and implement integrity management...

  13. Final Report on Testing of Off-Gas Treatment Technologies for Abatement of Atmospheric Emissions of Chlorinated Volatile Organic Compounds

    International Nuclear Information System (INIS)

    Jarosch, T.R.; Haselow, J.S.; Rossabi, J.; Burdick, S.A.; Raymond, R.; Young, J.E.; Lombard, K.H.

    1995-01-01

    The purpose of this report is to summarize the results of the program for off-gas treatment of atmospheric emissions of chlorinated volatile organic compounds (CVOCs), in particular trichloroethylene (TCE) and perchloroethylene (PCE). This program was funded through the Department of Energy Office of Technology Development's VOC's in Non-Arid Soils Integrated Demonstration (VNID). The off-gas treatment program was initiated after testing of in-situ air stripping with horizontal wells was completed (Looney et al., 1991). That successful test expectedly produced atmospheric emissions of CVOCs that were unabated. It was decided after that test that an off-gas treatment is an integral portion of remediation of CVOC contamination in groundwater and soil but also because several technologies were being developed across the United States to mitigate CVOC emissions. A single platform for testing off-gas treatment technologies would facilitate cost effective evaluation of the emerging technologies. Another motivation for the program is that many CVOCs will be regulated under the Clean Air Act Amendments of 1990 and are already regulated by many state regulatory programs. Additionally, compounds such as TCE and PCE are pervasive subsurface environmental contaminants, and, as a result, a small improvement in terms of abatement efficiency or cost will significantly reduce CVOC discharges to the environment as well as costs to United States government and industry

  14. Integration of High-Temperature Gas-Cooled Reactors into Industrial Process Applications

    International Nuclear Information System (INIS)

    Nelson, Lee

    2009-01-01

    This report is a preliminary comparison of conventional and potential HTGR-integrated processes in several common industrial areas: (1) Producing electricity via a traditional power cycle; (2) Producing hydrogen; (3) Producing ammonia and ammonia-derived products, such as fertilizer; (4) Producing gasoline and diesel from natural gas or coal; (5) Producing substitute natural gas from coal; and (6) Steam-assisted gravity drainage (extracting oil from tar sands).

  15. Organic membrane photonic integrated circuits (OMPICs).

    Science.gov (United States)

    Amemiya, Tomohiro; Kanazawa, Toru; Hiratani, Takuo; Inoue, Daisuke; Gu, Zhichen; Yamasaki, Satoshi; Urakami, Tatsuhiro; Arai, Shigehisa

    2017-08-07

    We propose the concept of organic membrane photonic integrated circuits (OMPICs), which incorporate various functions needed for optical signal processing into a flexible organic membrane. We describe the structure of several devices used within the proposed OMPICs (e.g., transmission lines, I/O couplers, phase shifters, photodetectors, modulators), and theoretically investigate their characteristics. We then present a method of fabricating the photonic devices monolithically in an organic membrane and demonstrate the operation of transmission lines and I/O couplers, the most basic elements of OMPICs.

  16. In vitro organic matter digestibility and gas production of fish-meal ...

    African Journals Online (AJOL)

    In this study, an in vitro rumen gas production technique was utilized to evaluate fish-meal coated with different types and levels of fats for total gas production, Metabolizable energy (ME) and organic matter digestibility (OMD) contents. Approximately 200 mg of sample was weighed and inserted in glass syringes, then ...

  17. Periodic reviews of structural integrity of gas-cooled reactors

    International Nuclear Information System (INIS)

    Banks, P.J.; Stokoe, T.Y.; Thomas, D.L.

    1995-01-01

    Nuclear Electric operates 12 gas-cooled reactor power stations which have been in service for between 5 and 30 years. Periodically, comprehensive reviews of the safety cases are carried out for each station. The approach followed in these reviews in respect of structural integrity is outlined with the use of illustrative examples. (author)

  18. Integrating climate forecasts and natural gas supply information into a natural gas purchasing decision

    Science.gov (United States)

    Changnon, David; Ritsche, Michael; Elyea, Karen; Shelton, Steve; Schramm, Kevin

    2000-09-01

    This paper illustrates a key lesson related to most uses of long-range climate forecast information, namely that effective weather-related decision-making requires understanding and integration of weather information with other, often complex factors. Northern Illinois University's heating plant manager and staff meteorologist, along with a group of meteorology students, worked together to assess different types of available information that could be used in an autumn natural gas purchasing decision. Weather information assessed included the impact of ENSO events on winters in northern Illinois and the Climate Prediction Center's (CPC) long-range climate outlooks. Non-weather factors, such as the cost and available supplies of natural gas prior to the heating season, contribute to the complexity of the natural gas purchase decision. A decision tree was developed and it incorporated three parts: (a) natural gas supply levels, (b) the CPC long-lead climate outlooks for the region, and (c) an ENSO model developed for DeKalb. The results were used to decide in autumn whether to lock in a price or ride the market each winter. The decision tree was tested for the period 1995-99, and returned a cost-effective decision in three of the four winters.

  19. Concise Review: Organ Engineering: Design, Technology, and Integration.

    Science.gov (United States)

    Kaushik, Gaurav; Leijten, Jeroen; Khademhosseini, Ali

    2017-01-01

    Engineering complex tissues and whole organs has the potential to dramatically impact translational medicine in several avenues. Organ engineering is a discipline that integrates biological knowledge of embryological development, anatomy, physiology, and cellular interactions with enabling technologies including biocompatible biomaterials and biofabrication platforms such as three-dimensional bioprinting. When engineering complex tissues and organs, core design principles must be taken into account, such as the structure-function relationship, biochemical signaling, mechanics, gradients, and spatial constraints. Technological advances in biomaterials, biofabrication, and biomedical imaging allow for in vitro control of these factors to recreate in vivo phenomena. Finally, organ engineering emerges as an integration of biological design and technical rigor. An overall workflow for organ engineering and guiding technology to advance biology as well as a perspective on necessary future iterations in the field is discussed. Stem Cells 2017;35:51-60. © 2016 AlphaMed Press.

  20. Characteristics of electrostatic gas micro-pump with integrated polyimide passive valves

    International Nuclear Information System (INIS)

    Han, Jeahyeong; Yeom, Junghoon; Mensing, Glennys; Flachsbart, Bruce; Shannon, Mark A

    2012-01-01

    We report on the fabrication and characterization of electrostatic gas micro-pumps integrated with polyimide check valves. Touch-mode capacitance actuation, enabled by a fixed silicon electrode and a metal/polyimide diaphragm, creates the suction and push-out of the ambient gas; the gas flow is rectified by the check valves located at the inlet and outlet of the pump. The fabricated pumps were tested with various actuation voltages at different frequencies and duty cycles; an emphasis was placed on investigating the effect of valve flow conductance on the gas pumping characteristics. The pump with higher valve conductance could increase the operating frequency of the pump and affect the pumping characteristics from a pulsating flow to a continuous flow, leading to a higher gas flow rate. This electrostatic pump has a flow control resolution of 1 µL min −1 ; it could generate a gas flow up to 106 µL min −1 . (paper)

  1. Simulation, integration, and economic analysis of gas-to-liquid processes

    International Nuclear Information System (INIS)

    Bao, Buping; El-Halwagi, Mahmoud M.; Elbashir, Nimir O.

    2010-01-01

    Gas-to-liquid (GTL) involves the chemical conversion of natural gas into synthetic crude that can be upgraded and separated into different useful hydrocarbon fractions including liquid transportation fuels. Such technology can also be used to convert other abundant natural resources such as coal and biomass to fuels and value added chemicals (referred to as coal-to-liquid (CTL) and biomass-to-liquid (BTL)). A leading GTL technology is the Fischer-Tropsch (FT) process. The objective of this work is to provide a techno-economic analysis of the GTL process and to identify optimization and integration opportunities for cost saving and reduction of energy usage while accounting for the environmental impact. First, a base-case flowsheet is synthesized to include the key processing steps of the plant. Then, a computer-aided process simulation is carried out to determine the key mass and energy flows, performance criteria, and equipment specifications. Next, energy and mass integration studies are performed to address the following items: (a) heating and cooling utilities, (b) combined heat and power (process cogeneration), (c) management of process water, (c) optimization of tail gas allocation, and (d) recovery of catalyst-supporting hydrocarbon solvents. Finally, these integration studies are conducted and the results are documented in terms of conserving energy and mass resources as well as providing economic impact. Finally, an economic analysis is undertaken to determine the plant capacity needed to achieve the break-even point and to estimate the return on investment for the base-case study. (author)

  2. Pipelines integrity management in Transportadora de Gas del Sur; Gerenciamento de la integridad de gasoductos en Transportadora de Gas del Sur

    Energy Technology Data Exchange (ETDEWEB)

    Espineira, Eduardo [Transportadora de Gas del Sur (TGS) (Argentina). Gerencia de Integridad de Gasoductos

    2003-07-01

    To control the integrity of a buried gas pipeline system is not an easy task for a gas pipeline operator. As the threats that affect pipeline integrity are many, it is critical to obtain, visualize, and analyze a great quantity of data in order to ensure a safe and continuous gas supply. This task becomes even more complex in the case of pipelines installed long time ago, where time pays an important role in the formation and development of defects. It is essential to maintain a policy of permanent evaluation, monitoring and repair that allows to evaluate the integrity plan developed and to make the changes that might be necessary. The TGS pipeline system consists of 7400 Km of pipe with an average age of 30 years, going across a great variety of soils and zones with distinctive geographical features that demand the continuous investment of money. This study describes the integrity plan set up by TGS and its evolution in time, including the main tasks related to information gathering and analysis, as well as all rehabilitation tasks. The evaluation of the integrity plan implementation, and the evolution of failure rates in time with respect to the related investments are also described. Finally, the analysis includes the information management systems applied by TGS such as the Geographic Information System . (author)

  3. Concise Review: Organ Engineering: Design, Technology, and Integration

    NARCIS (Netherlands)

    Kaushik, G.; Leijten, Jeroen Christianus Hermanus; Khademhosseini, A.

    Engineering complex tissues and whole organs has the potential to dramatically impact translational medicine in several avenues. Organ engineering is a discipline that integrates biological knowledge of embryological development, anatomy, physiology, and cellular interactions with enabling

  4. Tholins - Organic chemistry of interstellar grains and gas

    Science.gov (United States)

    Sagan, C.; Khare, B. N.

    1979-01-01

    The paper discusses tholins, defined as complex organic solids formed by the interaction of energy - for example, UV light or spark discharge - with various mixtures of cosmically abundant gases - CH4, C2H6, NH3, H2O, HCHO, and H2S. It is suggested that tholins occur in the interstellar medium and are responsible for some of the properties of the interstellar grains and gas. Additional occurrences of tholins are considered. Tholins have been produced experimentally; 50 or so pyrolytic fragments of the brown, sometimes sticky substances have been identified by gas chromatography-mass spectrometry, and the incidence of these fragments in tholins produced by different procedures is reported.

  5. Radiation-induced transformations of isolated organic molecules in solid rare gas matrices

    International Nuclear Information System (INIS)

    Feldman, V.I.

    1998-01-01

    Complete text of publication follows. The studies of radiation-chemical behaviour of isolated organic molecules in rigid inert media are of considerable interest for radiation chemistry and general structural chemistry. Previous efforts were limited to the ESR studies of radicals resulting from some small hydrocarbon molecules in frozen rare gas solutions. Recently, we developed an approach to the radiation chemistry of isolated organic molecules using classic matrix isolation procedure for sample preparation and a combination of ESR and IR spectroscopy for characterization of paramagnetic and diamagnetic species resulting form electron irradiation or organic molecules in solid rare gas matrices at 10-15 K. The results obtained reveal high efficiency of energy transfer from rare gas matrix to organic molecules. The total radiation-chemical yields of degradation of organic molecules in argon and xenon matrices were measured directly by IR spectroscopy. The studies of the effect of electron scavengers on the radiolysis of organic molecules in solid rare gases show that the main primary process is positive hole transfer from matrix to additive molecule. ESR spectra of a number of radical cations (alkanes, ethers, arenes) were first characterized in a low-disturbing environment. It was found that the electronic characteristics (IP, polarizability) of the matrix used had crucial effect on trapping and degradation of primary organic radical cations. Using matrices with various IP provides an unique possibility to examine the chemical meaning of excess energy resulting from exothermic positive hole transfer, that is, to follow the fate of excited cations in condensed phase

  6. The Federal Trade Commission, clinical integration, and the organization of physician practice.

    Science.gov (United States)

    Casalino, Lawrence P

    2006-06-01

    This article examines Federal Trade Commission (FTC) policy--in particular, the agency's controversial 1996 statements on clinical integration--toward joint negotiations for nonrisk contracts with health plans by physicians organized into independent practice associations (IPAs) and (with hospitals) into physician-hospital organizations (PHOs). The article concludes that the policy is consistent with anti-trust principles, consistent with current thinking on the use of organized processes to improve medical care quality, specific enough to provide guidance to physicians wanting to integrate clinically, and general enough to encourage ongoing innovations in physician organization. The FTC should consider stronger sanctions for IPAs and PHOs whose clinical integration is nothing more than a sham intended to provide cover for joint negotiations, should give the benefit of the doubt to organizations whose clinical integration appears to be reasonably consonant with the statements, and should clarify several ambiguities in the statements. Health plans should facilitate IPA and PHO efforts to improve care by rewarding quality and efficiency and by providing clinically integrated organizations with claims information on individual patients. Though creating clinically integrated organizations is difficult and expensive, physicians should recognize that clinical integration can help them both to gain some negotiating leverage with health plans and to improve the quality of care for their patients.

  7. Organic printed photonics: From microring lasers to integrated circuits.

    Science.gov (United States)

    Zhang, Chuang; Zou, Chang-Ling; Zhao, Yan; Dong, Chun-Hua; Wei, Cong; Wang, Hanlin; Liu, Yunqi; Guo, Guang-Can; Yao, Jiannian; Zhao, Yong Sheng

    2015-09-01

    A photonic integrated circuit (PIC) is the optical analogy of an electronic loop in which photons are signal carriers with high transport speed and parallel processing capability. Besides the most frequently demonstrated silicon-based circuits, PICs require a variety of materials for light generation, processing, modulation, and detection. With their diversity and flexibility, organic molecular materials provide an alternative platform for photonics; however, the versatile fabrication of organic integrated circuits with the desired photonic performance remains a big challenge. The rapid development of flexible electronics has shown that a solution printing technique has considerable potential for the large-scale fabrication and integration of microsized/nanosized devices. We propose the idea of soft photonics and demonstrate the function-directed fabrication of high-quality organic photonic devices and circuits. We prepared size-tunable and reproducible polymer microring resonators on a wafer-scale transparent and flexible chip using a solution printing technique. The printed optical resonator showed a quality (Q) factor higher than 4 × 10(5), which is comparable to that of silicon-based resonators. The high material compatibility of this printed photonic chip enabled us to realize low-threshold microlasers by doping organic functional molecules into a typical photonic device. On an identical chip, this construction strategy allowed us to design a complex assembly of one-dimensional waveguide and resonator components for light signal filtering and optical storage toward the large-scale on-chip integration of microscopic photonic units. Thus, we have developed a scheme for soft photonic integration that may motivate further studies on organic photonic materials and devices.

  8. Integration of power to gas/power to liquid in the ongoing transformation processes; Integration von Power to Gas/Power to Liquid in den laufenden Transformationsprozess

    Energy Technology Data Exchange (ETDEWEB)

    Purr, Katja; Osiek, Dirk; Lange, Martin; and others

    2016-03-15

    The objective of this position paper is to assess from the current level of knowledge of the Federal Environment Agency the role and perspective of power to gas / power to Liquid (PtG / PtL) in a fully renewable energy system and in particular to appoint the challenges of integration and further development of this technique in the current transformation process in the next few years. Here also the comparison to other Power to X-options and their greenhouse gas reduction effect is shown. The geographic focus of the considerations is on Germany, knowing that a full renewable energy supply in Germany must be especially for economic reasons embedded in a long term international energy policy. [German] Ziel dieses Positionspapiers ist es, aus dem derzeitigen Kenntnisstand des Umweltbundesamts die Rolle und Perspektive von Power to Gas/Power to Liquid (PtG/PtL) in einem vollstaendig regenerativen Energiesystem einzuschaetzen und insbesondere die Herausforderungen bei der Integration und Weiterentwicklung dieser Technik im laufenden Transformationsprozess in den naechsten Jahren zu benennen. Dabei wird auch der Vergleich zu anderen Power to X-Optionen und deren Treibhausgasminderungswirkung dargestellt. Der geografische Fokus der Betrachtungen liegt dabei auf Deutschland, wohlwissend, dass eine vollstaendige regenerative Energieversorgung Deutschlands insbesondere aus oekonomischen Gruenden langfristig in eine internationale Energiepolitik eingebettet sein muss.

  9. Detection of Volatile Organic Compound Gas Using Localized Surface Plasmon Resonance of Gold Nanoparticles

    International Nuclear Information System (INIS)

    Sri Nengsih; Akrajas Ali Umar; Muhamad Mat Salleh; Muhammad Yahaya

    2011-01-01

    This paper reports on the detection of several organic vapors using the unique characteristic of localized surface plasmon resonance (LSPR) gold nanoparticles. Gold nanoparticles on quartz substrate were prepared using seed mediated growth method. In a typical process, gold nanoparticles with average size ca. 36 nm were obtained to densely grown on the substrate. Detection of gas was based on the change in the LSPR of the gold nanoparticles film upon the exposure to the gas sample. It was found that gold nanoparticles were sensitive to the presence of volatile organic compound (VOC) gas from the change in the surface plasmon resonance (SPR) intensity. The mechanism for the detection of VOCs gas will be discussed. (author)

  10. Research document no.31. Integration of European gas markets: nascent competition in a diversity of models

    International Nuclear Information System (INIS)

    Finon, D.

    2002-01-01

    The idea of building an integrated European gas market based on competitive trade, like a gas lake supplied indifferently by remote, intra-European and national sources with the help of active market places allowing arbitration and price convergence, is far from being reached. In fact it depends upon two conditions: the deregulation of each gas market at national level, and at the upper level of the market the change in contractual relations between remote gas producers and buyers, who currently make the relations rigid with long-term transactions and limit opportunities for exchange on a competitive basis. This document analyses at two levels, namely national and European, the changing shape of the European gas markets under the effects of the market reforms and their chance of integration. Firstly the former two-level European gas market, the legacy of which determines the constraints on competition development more strongly than in electricity, are characterized. Secondly, in order to characterize the potential for development of competition, the main traits of each national gas market are identified in terms of market attractiveness and market accessibility for the incumbents competitors. Thirdly, dynamics of market development towards market integration are inferred at European level from these characteristics and from the possibility for development of new forms of gas trade between foreign producers, suppliers and users at national level. (A.L.B.)

  11. Research document no.31. Integration of European gas markets: nascent competition in a diversity of models

    Energy Technology Data Exchange (ETDEWEB)

    Finon, D

    2002-07-01

    The idea of building an integrated European gas market based on competitive trade, like a gas lake supplied indifferently by remote, intra-European and national sources with the help of active market places allowing arbitration and price convergence, is far from being reached. In fact it depends upon two conditions: the deregulation of each gas market at national level, and at the upper level of the market the change in contractual relations between remote gas producers and buyers, who currently make the relations rigid with long-term transactions and limit opportunities for exchange on a competitive basis. This document analyses at two levels, namely national and European, the changing shape of the European gas markets under the effects of the market reforms and their chance of integration. Firstly the former two-level European gas market, the legacy of which determines the constraints on competition development more strongly than in electricity, are characterized. Secondly, in order to characterize the potential for development of competition, the main traits of each national gas market are identified in terms of market attractiveness and market accessibility for the incumbents competitors. Thirdly, dynamics of market development towards market integration are inferred at European level from these characteristics and from the possibility for development of new forms of gas trade between foreign producers, suppliers and users at national level. (A.L.B.)

  12. Interpretations of integration in early accountable care organizations.

    Science.gov (United States)

    Kreindler, Sara A; Larson, Bridget K; Wu, Frances M; Carluzzo, Kathleen L; Gbemudu, Josette N; Struthers, Ashley; VAN Citters, Aricca D; Shortell, Stephen M; Nelson, Eugene C; Fisher, Elliott S

    2012-09-01

    It is widely hoped that accountable care organizations (ACOs) will improve health care quality and reduce costs by fostering integration among diverse provider groups. But how do implementers actually envision integration, and what will integration mean in terms of managing the many social identities that ACOs bring together? Using the lens of the social identity approach, this qualitative study examined how four nascent ACOs engaged with the concept of integration. During multiday site visits, we conducted interviews (114 managers and physicians), observations, and document reviews. In no case was the ACO interpreted as a new, overarching entity uniting disparate groups; rather, each site offered a unique interpretation that flowed from its existing strategies for social-identity management: An independent practice association preserved members' cherished value of autonomy by emphasizing coordination, not "integration"; a medical group promoted integration within its employed core, but not with affiliates; a hospital, engaging community physicians who mistrusted integrated systems, reimagined integration as an equal partnership; an integrated delivery system advanced its careful journey towards intergroup consensus by presenting the ACO as a cultural, not structural, change. The ACO appears to be a model flexible enough to work in synchrony with whatever social strategies are most context appropriate, with the potential to promote alignment and functional integration without demanding common identification with a superordinate group. "Soft integration" may be a promising alternative to the vertically integrated model that, though widely assumed to be ideal, has remained unattainable for most organizations. © 2012 Milbank Memorial Fund.

  13. Integration Research on Gas Turbine and Tunnel Kiln Combined System

    Science.gov (United States)

    Shi, Hefei; Ma, Liangdong; Liu, Mingsheng

    2018-04-01

    Through the integrated modeling of gas turbine and tunnel kiln combined system, a thermodynamic calculation method of combined system is put forward, and the combined system operation parameters are obtained. By this method, the optimization of the combined system is analyzed and the optimal configuration of the gas turbine is calculated. At the same time, the thermal efficiency of the combined system is analyzed, and the heat distribution and thermal efficiency of the system before and after the improvement are explained. Taking the 1500 kg/h ceramic production as an example, pointed out that if the tunnel kiln has a gas turbine with a power of 342 kw. The amount of electricity of the combined system that produced per unit volume of the fuel which consumes more than it used to will be 7.19 kwh, the system thermal efficiency will reach 57.49%, which higher than the individual gas turbine’s cycle thermal efficiency 20% at least.

  14. Identification and measurement of chlorinated organic pesticides in water by electron-capture gas chromatography

    Science.gov (United States)

    Lamar, William L.; Goerlitz, Donald F.; Law, LeRoy M.

    1965-01-01

    Pesticides, in minute quantities, may affect the regimen of streams, and because they may concentrate in sediments, aquatic organisms, and edible aquatic foods, their detection and their measurement in the parts-per-trillion range are considered essential. In 1964 the U.S. Geological Survey at Menlo Park, Calif., began research on methods for monitoring pesticides in water. Two systems were selected--electron-capture gas chromatography and microcoulometric-titration gas chromatography. Studies on these systems are now in progress. This report provides current information on the development and application of an electron-capture gas chromatographic procedure. This method is a convenient and extremely sensitive procedure for the detection and measurement of organic pesticides having high electron affinities, notably the chlorinated organic pesticides. The electron-affinity detector is extremely sensitive to these substances but it is not as sensitive to many other compounds. By this method, the chlorinated organic pesticide may be determined on a sample of convenient size in concentrations as low as the parts-per-trillion range. To insure greater accuracy in the identifications, the pesticides reported were separated and identified by their retention times on two different types of gas chromatographic columns.

  15. A novel in situ gas stripping-pervaporation process integrated with acetone-butanol-ethanol fermentation for hyper n-butanol production.

    Science.gov (United States)

    Xue, Chuang; Liu, Fangfang; Xu, Mengmeng; Zhao, Jingbo; Chen, Lijie; Ren, Jiangang; Bai, Fengwu; Yang, Shang-Tian

    2016-01-01

    Butanol is considered as an advanced biofuel, the development of which is restricted by the intensive energy consumption of product recovery. A novel two-stage gas stripping-pervaporation process integrated with acetone-butanol-ethanol (ABE) fermentation was developed for butanol recovery, with gas stripping as the first-stage and pervaporation as the second-stage using the carbon nanotubes (CNTs) filled polydimethylsiloxane (PDMS) mixed matrix membrane (MMM). Compared to batch fermentation without butanol recovery, more ABE (27.5 g/L acetone, 75.5 g/L butanol, 7.0 g/L ethanol vs. 7.9 g/L acetone, 16.2 g/L butanol, 1.4 g/L ethanol) were produced in the fed-batch fermentation, with a higher butanol productivity (0.34 g/L · h vs. 0.30 g/L · h) due to reduced butanol inhibition by butanol recovery. The first-stage gas stripping produced a condensate containing 155.6 g/L butanol (199.9 g/L ABE), which after phase separation formed an organic phase containing 610.8 g/L butanol (656.1 g/L ABE) and an aqueous phase containing 85.6 g/L butanol (129.7 g/L ABE). Fed with the aqueous phase of the condensate from first-stage gas stripping, the second-stage pervaporation using the CNTs-PDMS MMM produced a condensate containing 441.7 g/L butanol (593.2 g/L ABE), which after mixing with the organic phase from gas stripping gave a highly concentrated product containing 521.3 g/L butanol (622.9 g/L ABE). The outstanding performance of CNTs-PDMS MMM can be attributed to the hydrophobic CNTs giving an alternative route for mass transport through the inner tubes or along the smooth surface of CNTs. This gas stripping-pervaporation process with less contaminated risk is thus effective in increasing butanol production and reducing energy consumption. © 2015 Wiley Periodicals, Inc.

  16. Numerical simulations of enhanced gas recovery at the Zalezcze gas field in Poland confirm high CO2 storage capacity and mechanical integrity

    International Nuclear Information System (INIS)

    Klimkowski, Lukasz; Nagy, Stanislaw; Papiernik, Bartosz; Orlic, Bogdan; Kempka, Thomas

    2015-01-01

    Natural gas from the Zalecze gas field located in the Fore-Sudetic Monocline of the Southern Permian Basin has been produced since November 1973, and continuous gas production led to a decrease in the initial reservoir pressure from 151 bar to about 22 bar until 2010. We investigated a prospective enhanced gas recovery operation at the Zalecze gas field by coupled numerical hydro-mechanical simulations to account for the CO 2 storage capacity, trapping efficiency and mechanical integrity of the reservoir, cap-rock and regional faults. Dynamic flow simulations carried out indicate a CO 2 storage capacity of 106.6 Mt with a trapping efficiency of about 43% (45.8 Mt CO 2 ) established after 500 years of simulation. Two independent strategies on the assessment of mechanical integrity were followed by two different modeling groups resulting in the implementation of field- to regional-scale hydro-mechanical simulation models. The simulation results based on application of different constitutive laws for the lithological units show deviations of 31% to 93% for the calculated maximum vertical displacements at the reservoir top. Nevertheless, results of both simulation strategies indicate that fault reactivation generating potential leakage pathways from the reservoir to shallower units is very unlikely due to the low fault slip tendency (close to zero) in the Zechstein cap-rocks. Consequently, our simulation results also emphasise that the supra- and sub-saliferous fault systems at the Zalecze gas field are independent and very likely not hydraulically connected. Based on our simulation results derived from two independent modeling strategies with similar simulation results on fault and cap-rock integrity, we conclude that the investigated enhanced gas recovery scheme is feasible, with a negligibly low risk of relevant fault reactivation or formation fluid leakage through the Zechstein cap-rocks. (authors)

  17. Enhancement of organic matter degradation and methane gas production of anaerobic granular sludge by degasification of dissolved hydrogen gas.

    Science.gov (United States)

    Satoh, Hisashi; Bandara, Wasala M K R T W; Sasakawa, Manabu; Nakahara, Yoshihito; Takahashi, Masahiro; Okabe, Satoshi

    2017-11-01

    A hollow fiber degassing membrane (DM) was applied to enhance organic matter degradation and methane gas production of anaerobic granular sludge process by reducing the dissolved hydrogen gas (D-H 2 ) concentration in the liquid phase. DM was installed in the bench-scale anaerobic granular sludge reactors and D-H 2 was removed through DM using a vacuum pump. Degasification improved the organic matter degradation efficiency to 79% while the efficiency was 62% without degasification at 12,000mgL -1 of the influent T-COD concentration. Measurement of D-H 2 concentrations in the liquid phase confirmed that D-H 2 was removed by degasification. Furthermore, the effect of acetate concentrations on the organic matter degradation efficiency was investigated. At acetate concentrations above 3gL -1 , organic matter degradation deteriorated. Degasification enhanced the propionate and acetate degradation. These results suggest that degasification reduced D-H 2 concentration and volatile fatty acids concentrations, prevented pH drop, and subsequent enhanced organic matter degradation. Copyright © 2017 Elsevier Ltd. All rights reserved.

  18. International market integration for natural gas? A cointegration analysis of prices in Europe, North America and Japan

    International Nuclear Information System (INIS)

    Siliverstovs, Boriss; L'Hegaret, Guillaume; Neumann, Anne; Hirschlausen, Christian von

    2005-01-01

    This paper investigates the degree of integration of natural gas markets in Europe, North America and Japan in the time period between the early 1990s and 2004. The relationship between international gas market prices and their relation to the oil price are explored through principal components analysis and Johansen likelihood-based cointegration procedure. Both of them show a high level of natural gas market integration within Europe, between the European and Japanese markets as well as within the North American market. At the same time the obtained results suggest that the European (respectively, Japanese) and the North American markets were not integrated. (Author)

  19. Integrating Community Health Workers (CHWs) into Health Care Organizations.

    Science.gov (United States)

    Payne, Julianne; Razi, Sima; Emery, Kyle; Quattrone, Westleigh; Tardif-Douglin, Miriam

    2017-10-01

    Health care organizations increasingly employ community health workers (CHWs) to help address growing provider shortages, improve patient outcomes, and increase access to culturally sensitive care among traditionally inaccessible or disenfranchised patient populations. Scholarly interest in CHWs has grown in recent decades, but researchers tend to focus on how CHWs affect patient outcomes rather than whether and how CHWs fit into the existing health care workforce. This paper focuses on the factors that facilitate and impede the integration of the CHWs into health care organizations, and strategies that organizations and their staff develop to overcome barriers to CHW integration. We use qualitative evaluation data from 13 awardees that received Health Care Innovation Awards from the Centers of Medicare and Medicaid Innovation to enhance the quality of health care, improve health outcomes, and reduce the cost of care using programs involving CHWs. We find that organizational capacity, support for CHWs, clarity about health care roles, and clinical workflow drive CHW integration. We conclude with practical recommendations for health care organizations interested in employing CHWs.

  20. Acetone-butanol-ethanol from sweet sorghum juice by an immobilized fermentation-gas stripping integration process.

    Science.gov (United States)

    Cai, Di; Wang, Yong; Chen, Changjing; Qin, Peiyong; Miao, Qi; Zhang, Changwei; Li, Ping; Tan, Tianwei

    2016-07-01

    In this study, sweet sorghum juice (SSJ) was used as the substrate in a simplified ABE fermentation-gas stripping integration process without nutrients supplementation. The sweet sorghum bagasse (SSB) after squeezing the fermentable juice was used as the immobilized carrier. The results indicated that the productivity of ABE fermentation process was improved by gas stripping integration. A total 24g/L of ABE solvents was obtained from 59.6g/L of initial sugar after 80h of fermentation with gas stripping. Then, long-term of fed-batch fermentation with continuous gas stripping was further performed. 112.9g/L of butanol, 44.1g/L of acetone, 9.5g/L of ethanol (total 166.5g/L of ABE) was produced in overall 312h of fermentation. At the same time, concentrated ABE product was obtained in the condensate of gas stripping. Copyright © 2016 Elsevier Ltd. All rights reserved.

  1. Steady-state analysis of the integrated natural gas and electric power system with bi-directional energy conversion

    DEFF Research Database (Denmark)

    Zeng, Qing; Fang, Jiakun; Li, Jinghua

    2016-01-01

    Nowadays, the electric power system and natural gas network are becoming increasingly coupled and interdependent. A harmonized integration of natural gas and electricity network with bi-directional energy conversion is expected to accommodate high penetration levels of renewables in terms of system...... flexibility. This work focuses on the steady-state analysis of the integrated natural gas and electric power system with bi-directional energy conversion. A unified energy flow formulation is developed to describe the nodal balance and branch flow in both systems and it is solved with the Newton......–Raphson method. Both the unification of units and the per-unit system are proposed to simplify the system description and to enhance the computation efficiency. The applicability of the proposed method is demonstrated by analyzing an IEEE-9 test system integrated with a 7-node natural gas network. Later, time...

  2. Automatic isotope gas analysis of tritium labelled organic materials Pt. 1

    International Nuclear Information System (INIS)

    Gacs, I.; Mlinko, S.

    1978-01-01

    A new automatic procedure developed to convert tritium in HTO hydrogen for subsequent on-line gas counting is described. The water containing tritium is introduced into a column prepared from molecular sieve-5A and heated to 550 deg C. The tritium is transferred by isotopic exchange into hydrogen flowing through the column. The radioactive gas is led into an internal detector for radioactivity measurement. The procedure is free of memory effects, provides quantitative recovery with analytical reproducibility better than 0.5% rel. at a preset number of counts. The experimental and analytical results indicate that isotopic exchange between HTO and hydrogen over a column prepared from alumina or molecular sieve-5A can be successfully applied for the quantitative transfer of tritium from HTO into hydrogen for on-line gas countinq. This provides an analytical procedure for the automatic determination of tritium in water with an analytical reproducibility better than 0.5% rel. The exchange process will also be suitable for rapid tritium transfer from water formed during the decomposition of tritium-labelled organic compounds or biological materials. The application of the procedure in automatic isotope gas analysis of organic materials labelled with tritium will be described in subsequent papers (Parts II and III). (T.G.)

  3. Emission of gaseous organic pollutants and flue gas treatment technology

    International Nuclear Information System (INIS)

    Chmielewski, A.G.; Sun, Y.

    2007-01-01

    Gaseous organic pollutants are emitted into atmosphere from various sources, creating a threat to the environment and man. New, economical technologies are needed for flue gas treatment. Emission sources of pollutants are reviewed and different treatment technologies are discussed in this report. (authors)

  4. Next Generation Offline Approaches to Trace Gas-Phase Organic Compound Speciation: Sample Collection and Analysis

    Science.gov (United States)

    Sheu, R.; Marcotte, A.; Khare, P.; Ditto, J.; Charan, S.; Gentner, D. R.

    2017-12-01

    Intermediate-volatility and semi-volatile organic compounds (I/SVOCs) are major precursors to secondary organic aerosol, and contribute to tropospheric ozone formation. Their wide volatility range, chemical complexity, behavior in analytical systems, and trace concentrations present numerous hurdles to characterization. We present an integrated sampling-to-analysis system for the collection and offline analysis of trace gas-phase organic compounds with the goal of preserving and recovering analytes throughout sample collection, transport, storage, and thermal desorption for accurate analysis. Custom multi-bed adsorbent tubes are used to collect samples for offline analysis by advanced analytical detectors. The analytical instrumentation comprises an automated thermal desorption system that introduces analytes from the adsorbent tubes into a gas chromatograph, which is coupled with an electron ionization mass spectrometer (GC-EIMS) and other detectors. In order to optimize the collection and recovery for a wide range of analyte volatility and functionalization, we evaluated a variety of commercially-available materials, including Res-Sil beads, quartz wool, glass beads, Tenax TA, and silica gel. Key properties for optimization include inertness, versatile chemical capture, minimal affinity for water, and minimal artifacts or degradation byproducts; these properties were assessed with a diverse mix of traditionally-measured and functionalized analytes. Along with a focus on material selection, we provide recommendations spanning the entire sampling-and-analysis process to improve the accuracy of future comprehensive I/SVOC measurements, including oxygenated and other functionalized I/SVOCs. We demonstrate the performance of our system by providing results on speciated VOCs-SVOCs from indoor, outdoor, and chamber studies that establish the utility of our protocols and pave the way for precise laboratory characterization via a mix of detection methods.

  5. Simultaneous integrated optimal energy flow of electricity, gas, and heat

    International Nuclear Information System (INIS)

    Shabanpour-Haghighi, Amin; Seifi, Ali Reza

    2015-01-01

    Highlights: • Integration of electrical, natural gas, and district heating networks is studied. • Part-load performances of units are considered in modeling. • A modified teaching–learning based optimization is used to solve the problem. • Results show the advantages of the integrated optimization approach. - Abstract: In this paper, an integrated approach to optimize electrical, natural gas, and district heating networks simultaneously is studied. Several interdependencies between these infrastructures are considered in details including a nonlinear part-load performance for boilers and CHPs besides the valve-point effect for generators. A novel approach based on selecting an appropriate set of state-variables for the problem is proposed that eliminates the addition of any new variable to convert irregular equations into a regular set while the optimization problem is still solvable. As a large optimization problem, the optimal solution cannot be achieved by conventional mathematical techniques. Hence, it is better to use evolutionary algorithms instead. In this paper, the well-known modified teaching–learning based optimization algorithm is utilized to solve the multi-period optimal power flow problem of multi-carrier energy networks. The proposed scheme is implemented and applied to a typical multi-carrier energy network. Results are compared with some other conventional heuristic algorithms and the applicability and superiority of the proposed methodology is verified

  6. Effects of gas-wall partitioning in Teflon tubing and instrumentation on time-resolved measurements of gas-phase organic compounds

    Science.gov (United States)

    Pagonis, Demetrios; Krechmer, Jordan E.; de Gouw, Joost; Jimenez, Jose L.; Ziemann, Paul J.

    2017-12-01

    Recent studies have demonstrated that organic compounds can partition from the gas phase to the walls in Teflon environmental chambers and that the process can be modeled as absorptive partitioning. Here these studies were extended to investigate gas-wall partitioning of organic compounds in Teflon tubing and inside a proton-transfer-reaction mass spectrometer (PTR-MS) used to monitor compound concentrations. Rapid partitioning of C8-C14 2-ketones and C11-C16 1-alkenes was observed for compounds with saturation concentrations (c∗) in the range of 3 × 104 to 1 × 107 µg m-3, causing delays in instrument response to step-function changes in the concentration of compounds being measured. These delays vary proportionally with tubing length and diameter and inversely with flow rate and c∗. The gas-wall partitioning process that occurs in tubing is similar to what occurs in a gas chromatography column, and the measured delay times (analogous to retention times) were accurately described using a linear chromatography model where the walls were treated as an equivalent absorbing mass that is consistent with values determined for Teflon environmental chambers. The effect of PTR-MS surfaces on delay times was also quantified and incorporated into the model. The model predicts delays of an hour or more for semivolatile compounds measured under commonly employed conditions. These results and the model can enable better quantitative design of sampling systems, in particular when fast response is needed, such as for rapid transients, aircraft, or eddy covariance measurements. They may also allow estimation of c∗ values for unidentified organic compounds detected by mass spectrometry and could be employed to introduce differences in time series of compounds for use with factor analysis methods. Best practices are suggested for sampling organic compounds through Teflon tubing.

  7. The Integration Aspects of Activities of the Companies in the Oil and Gas Industry Sector in the Context of Globalization

    Directory of Open Access Journals (Sweden)

    Panevnyk Tetiana M.

    2016-05-01

    Full Text Available The article considers both the dynamics and the structure of oil and gas production in Ukraine, situation of the oil and gas companies at the current stage of globalization of the world economy have been covered. The main problems impacting the functioning of the domestic industry sector have been identified, including the lack of effectiveness of the existing integration processes. The world trends and patterns of integration processes have been considered. It has been determined that the oil and gas industry sector leaders are the multinational companies that actively use integration in their practices. The current trends in creating integration linkages in different parts of the process chain in the oil and gas industry have been identified. Influence by large corporations of the innovative type on the creation of a favorable investment climate has been confirmed, as well as conducting their own policies of expansion in the overseas markets. On the basis of studying the foreign experience, expediency of development of the oil and gas sector enterprises by activating integration processes has been substantiated. Priorities and possibilities for further functioning of enterprises in the the oil and gas industry sector have been identified

  8. Natural gas as an integrating element for Latin America - An opportunity for Venezuela?

    Energy Technology Data Exchange (ETDEWEB)

    Gonzalez Cruz, Diego

    2010-09-15

    Summary This paper offers an analysis of the natural gas situation in Latin America, from Mexico to Argentina, including countries of the Caribbean; analyzes the attitude of potential buyers of this energy source and the possibilities of each country receiving natural gas from Venezuela based on its reserves and production, highlighting the most outstanding projects being undertaken in some of those countries; makes recommendations in the area of energy, with emphasis on natural gas; and, lastly, presents an epilog describing Venezuela's role in an integration process in Latin America.

  9. Gas phase precursors to anthropogenic secondary organic aerosol: detailed observations of 1,3,5-trimethylbenzene photooxidation

    Directory of Open Access Journals (Sweden)

    K. P. Wyche

    2009-01-01

    Full Text Available A series of photooxidation experiments were conducted in an atmospheric simulation chamber in order to investigate the oxidation mechanism and secondary organic aerosol (SOA formation potential of the model anthropogenic gas phase precursor, 1,3,5-trimethylbenzene. Alongside specific aerosol measurements, comprehensive gas phase measurements, primarily by Chemical Ionisation Reaction Time-of-Flight Mass Spectrometry (CIR-TOF-MS, were carried out to provide detailed insight into the composition and behaviour of the organic components of the gas phase matrix during SOA formation. An array of gas phase organic compounds was measured during the oxidation process, including several previously unmeasured primary bicyclic compounds possessing various functional groups. Analysis of results obtained during this study implies that these peroxide bicyclic species along with a series of ring opening products and organic acids contribute to SOA growth. The effect of varying the VOC/NOx ratio on SOA formation was explored, as was the effect of acid seeding. It was found that low NOx conditions favour more rapid aerosol formation and a higher aerosol yield, a result that implies a role for organic peroxides in the nucleation process and SOA growth.

  10. Experimental investigation of integrated refrigeration system (IRS) with gas engine, compression chiller and absorption chiller

    International Nuclear Information System (INIS)

    Sun, Z.G.

    2008-01-01

    An integrated refrigeration system (IRS) with a gas engine, a vapor-compression chiller and an absorption chiller is set up and tested. The vapor-compression refrigeration cycle is operated directly by the gas engine. The waste heat from the gas engine operates the absorption refrigeration cycle, which provides additional cooling. The performance of the IRS is described. The cooling capacity of the IRS is about 596 kW, and primary energy ratio (PER) reaches 1.84 at air-conditioning rated conditions. The refrigerating capacity of the prototype increased and PER of prototype decreased with the increase of the gas engine speed. The gas engine speed was preferably regulated at part load condition in order to operate the prototype at high-energy efficiency. The refrigerating capacity and PER of the prototype increased with the increase of the outlet temperature of chilled water or the decrease of the inlet temperature of cooling water. The integrated refrigeration chiller in this work saves running costs as compared to the conventional refrigeration system by using the waste heat

  11. An Integrated Approach to Water-Energy Nexus in Shale-Gas Production

    Directory of Open Access Journals (Sweden)

    Fadhil Y. Al-Aboosi

    2018-05-01

    Full Text Available Shale gas production is associated with significant usage of fresh water and discharge of wastewater. Consequently, there is a necessity to create proper management strategies for water resources in shale gas production and to integrate conventional energy sources (e.g., shale gas with renewables (e.g., solar energy. The objective of this study is to develop a design framework for integrating water and energy systems including multiple energy sources, the cogeneration process and desalination technologies in treating wastewater and providing fresh water for shale gas production. Solar energy is included to provide thermal power directly to a multi-effect distillation plant (MED exclusively (to be more feasible economically or indirect supply through a thermal energy storage system. Thus, MED is driven by direct or indirect solar energy and excess or direct cogeneration process heat. The proposed thermal energy storage along with the fossil fuel boiler will allow for the dual-purpose system to operate at steady-state by managing the dynamic variability of solar energy. Additionally, electric production is considered to supply a reverse osmosis plant (RO without connecting to the local electric grid. A multi-period mixed integer nonlinear program (MINLP is developed and applied to discretize the operation period to track the diurnal fluctuations of solar energy. The solution of the optimization program determines the optimal mix of solar energy, thermal storage and fossil fuel to attain the maximum annual profit of the entire system. A case study is solved for water treatment and energy management for Eagle Ford Basin in Texas.

  12. Conformal field theories, Coulomb gas picture and integrable models

    International Nuclear Information System (INIS)

    Zuber, J.B.

    1988-01-01

    The aim of the study is to present the links between some results of conformal field theory, the conventional Coulomb gas picture in statistical mechanics and the approach of integrable models. It is shown that families of conformal theories, related by the coset construction to the SU(2) Kac-Moody algebra, may be regarded as obtained from some free field, and modified by the coupling of its winding numbers to floating charges. This representation reflects the procedure of restriction of the corresponding integrable lattice models. The work may be generalized to models based on the coset construction with higher rank algebras. The corresponding integrable models are identified. In the conformal field description, generalized parafermions appear, and are coupled to free fields living on a higher-dimensional torus. The analysis is not as exhaustive as in the SU(2) case: all the various restrictions have not been identified, nor the modular invariants completely classified

  13. An integrated solar thermal power system using intercooled gas turbine and Kalina cycle

    International Nuclear Information System (INIS)

    Peng, Shuo; Hong, Hui; Jin, Hongguang; Wang, Zhifeng

    2012-01-01

    A new solar tower thermal power system integrating the intercooled gas turbine top cycle and the Kalina bottoming cycle is proposed in the present paper. The thermodynamic performance of the proposed system is investigated, and the irreversibility of energy conversion is disclosed using the energy–utilization diagram method. On the top cycle of the proposed system, the compressed air after being intercooled is heated at 1000 °C or higher at the solar tower receiver and is used to drive the gas turbine to generate power. The ammonia–water mixture as the working substance of the bottom cycle recovers the waste heat from the gas turbine to generate power. A concise analytical formula of solar-to-electric efficiency of the proposed system is developed. As a result, the peak solar-to-electric efficiency of the proposed system is 27.5% at a gas turbine inlet temperature of 1000 °C under the designed solar direct normal irradiance of 800 W/m 2 . Compared with a conventional solar power tower plant, the proposed integrated system conserves approximately 69% of consumed water. The results obtained in the current study provide an approach to improve solar-to-electric efficiency and offer a potential to conserve water for solar thermal power plants in arid area. -- Highlights: ► An Integrated Solar Thermal Power System is modeled. ► A formula forecasting the thermodynamic performance is proposed. ► The irreversibility of energy conversion is disclosed using an energy utilization method. ► The effect of key operational parameters on thermal performance is examined.

  14. Metal-Organic Frameworks for Sensing Applications in the Gas Phase

    Directory of Open Access Journals (Sweden)

    Sabine Achmann

    2009-03-01

    Full Text Available Several metal-organic framework (MOF materials were under investigated to test their applicability as sensor materials for impedimetric gas sensors. The materials were tested in a temperature range of 120 °C - 240 °C with varying concentrations of O2, CO2, C3H8, NO, H2, ethanol and methanol in the gas atmosphere and under different test gas humidity conditions. Different sensor configurations were studied in a frequency range of 1 Hz -1 MHz and time-continuous measurements were performed at 1 Hz. The materials did not show any impedance response to O2, CO2, C3H8, NO, or H2 in the gas atmospheres, although for some materials a significant impedance decrease was induced by a change of the ethanol or methanol concentration in the gas phase. Moreover, pronounced promising and reversible changes in the electric properties of a special MOF material were monitored under varying humidity, with a linear response curve at 120 °C. Further investigations were carried out with differently doped MOF materials of this class, to evaluate the influence of special dopants on the sensor effect.

  15. Biogas/fossil gas options. The future for integration of biogas in the natural gas sector in Denmark and in Europe

    Energy Technology Data Exchange (ETDEWEB)

    Biering Jensen, A [Naturgas Midt-Nord, Viborg (Denmark)

    1997-08-01

    Naturgas Midt-Nord is a company with the purpose of distributing and selling natural gas. The company is owned by 73 municipalities in the 4 counties in the northern part of Jutland. In this respect we cover almost 50% of the Danish farming areas. Since the company was established in 1983, almost 775 kilometres or 40 bar high-pressure pipes and 3,500 kilometres of 4 bar low-pressure pipes have been built. From time to time we have discussed the matter of biogas in the company. In relation to the distribution of natural gas, the integration of biogas could either be seen as a threat or a possibility to expand our business. It is still not quite clear for us, what part we should play with regards to biogas integration. (au)

  16. Reversed thermo-switchable molecular sieving membranes composed of two-dimensional metal-organic nanosheets for gas separation

    Science.gov (United States)

    Wang, Xuerui; Chi, Chenglong; Zhang, Kang; Qian, Yuhong; Gupta, Krishna M.; Kang, Zixi; Jiang, Jianwen; Zhao, Dan

    2017-02-01

    It is highly desirable to reduce the membrane thickness in order to maximize the throughput and break the trade-off limitation for membrane-based gas separation. Two-dimensional membranes composed of atomic-thick graphene or graphene oxide nanosheets have gas transport pathways that are at least three orders of magnitude higher than the membrane thickness, leading to reduced gas permeation flux and impaired separation throughput. Here we present nm-thick molecular sieving membranes composed of porous two-dimensional metal-organic nanosheets. These membranes possess pore openings parallel to gas concentration gradient allowing high gas permeation flux and high selectivity, which are proven by both experiment and molecular dynamics simulation. Furthermore, the gas transport pathways of these membranes exhibit a reversed thermo-switchable feature, which is attributed to the molecular flexibility of the building metal-organic nanosheets.

  17. Chlorinated pesticides in stream sediments from organic, integrated and conventional farms

    International Nuclear Information System (INIS)

    Shahpoury, Pourya; Hageman, Kimberly J.; Matthaei, Christoph D.; Magbanua, Francis S.

    2013-01-01

    To determine if current sheep/beef farming practices affect pesticide residues in streams, current-use and legacy chlorinated pesticides were quantified in 100 sediment samples from 15 streams on the South Island of New Zealand. The study involved five blocks of three neighboring farms, with each block containing farms managed by organic, integrated and conventional farming practices. Significantly higher concentrations of dieldrin, ∑ endosulfans, ∑ current-use pesticides, and ∑ chlorinated pesticides were measured in sediments from conventional farms compared to organic and integrated farms. However, streams in the latter two farming categories were not pesticide-free and sometimes contained relatively high concentrations of legacy pesticides. Comparison of measured pesticide concentrations with sediment quality guidelines showed that, regardless of farming practice, mean pesticide concentrations were below the recommended toxicity thresholds. However, up to 23% of individual samples contained chlorpyrifos, endosulfan sulfate, ∑ DDT, dieldrin, or ∑ chlordane concentrations above these thresholds. -- Highlights: •Pesticides were measured in streams in organic, integrated, and conventional farms. •Higher concentrations of some pesticides were found in conventional sites. •Streams in organic and integrated sites were not pesticide free. •Mean pesticide concentrations were below the recommended toxicity thresholds. -- Higher concentrations of several chlorinated pesticides were found in conventional farms; however, organic and integrated practices were not pesticide-free

  18. Integrated Wavelength-Tunable Light Source for Optical Gas Sensing Systems

    Directory of Open Access Journals (Sweden)

    Bin Li

    2015-01-01

    Full Text Available A compact instrument consisting of a distributed feedback laser (DFB at 1.65 μm was developed as a light source for gas sensing systems using tunable diode laser absorption spectroscopy (TDLAS technique. The wavelength of laser is tuned by adjusting the laser working temperature and injection current, which are performed by self-developed temperature controller and current modulator respectively. Stability test shows the fluctuation of the laser temperature is within the range of ±0.02°C. For gas detection experiments, the wavelength is tuned around the gas absorption line by adjusting laser temperature and is then shifted periodically to scan across the absorption line by the laser current modulator, which generates a 10 Hz saw wave signal. In addition, the current modulator is able to generate sine wave signal for gas sensing systems using wavelength modulation spectroscopy (WMS technique involving extraction of harmonic signals. The spectrum test proves good stability that the spectrum was measured 6 times every 10 minutes at the constant temperature and current condition. This standalone instrument can be applied as a light source for detection systems of different gases by integrating lasers at corresponding wavelength.

  19. Second Greenhouse Gas Information System Workshop

    Science.gov (United States)

    Boland, S. W.; Duren, R. M.; Mitchiner, J.; Rotman, D.; Sheffner, E.; Ebinger, M. H.; Miller, C. E.; Butler, J. H.; Dimotakis, P.; Jonietz, K.

    2009-12-01

    The second Greenhouse Gas Information System (GHGIS) workshop was held May 20-22, 2009 at the Sandia National Laboratories in Albuquerque, New Mexico. The workshop brought together 74 representatives from 28 organizations including U.S. government agencies, national laboratories, and members of the academic community to address issues related to the understanding, operational monitoring, and tracking of greenhouse gas emissions and carbon offsets. The workshop was organized by an interagency collaboration between NASA centers, DOE laboratories, and NOAA. It was motivated by the perceived need for an integrated interagency, community-wide initiative to provide information about greenhouse gas sources and sinks at policy-relevant temporal and spatial scales in order to significantly enhance the ability of national and regional governments, industry, and private citizens to implement and evaluate effective climate change mitigation policies. This talk provides an overview of the second Greenhouse Gas Information System workshop, presents its key findings, and discusses current status and next steps in this interagency collaborative effort.

  20. Quantitative characterization of urban sources of organic aerosol by high-resolution gas chromatography

    International Nuclear Information System (INIS)

    Hildemann, L.M.; Mazurek, M.A.; Cass, G.R.; Simoneit, B.R.T.

    1991-01-01

    Fine aerosol emissions have been collected from a variety of urban combustion sources, including an industrial boiler, a fireplace, automobiles, diesel trucks, gas-fired home appliances, and meat cooking operations, by use of a dilution sampling system. Other sampling techniques have been utilized to collect fine aerosol samples of paved road dust, brake wear, tire wear, cigarette smoke, tar pot emissions, and vegetative detritus. The organic matter contained in each of these samples has been analyzed via high-resolution gas chromatography. By use of a simple computational approach, a quantitative, 50-parameter characterization of the elutable fine organic aerosol emitted from each source type has been determined. The organic mass distribution fingerprints obtained by this approach are shown to differ significantly from each other for most of the source types tested, using hierarchical cluster analysis

  1. Integrating ALARA into work planning and organization

    International Nuclear Information System (INIS)

    Croft, J.R.; Robb, J.D.

    1993-01-01

    This paper presents various organizational structures and systematic approaches that can be of benefit in integrating ALARA into work planning and organization. It is possible to have elegant policy statements, procedures and organizations and yet fail to implement ALARA effectively. The real key to success in ALARA work management is to recognize that ALARA is primarily a way of thinking and to secure the commitment of individuals at all levels within the organization, from senior management to workers carrying out specific tasks. The authors explain that the recommendations of ICRP Publication 60 will have an impact and will maintain the downward pressure on individual doses. 6 figs

  2. Integration of organic based Schottky junctions for crossbar non-volatile memory applications

    DEFF Research Database (Denmark)

    Katsia, E.; Tallarida, G.; Ferrari, S.

    2008-01-01

    Small size Schottky junctions using two different synthesized organic semiconductors (oligophenylene-vinylenes) were integrated by standard UV lithography into crossbar arrays. The proposed integration scheme can be applied to a wide class of organics without affecting material properties. Current...

  3. Multiagency Initiative to Provide Greenhouse Gas Information

    Science.gov (United States)

    Boland, Stacey W.; Duren, Riley M.

    2009-11-01

    Global Greenhouse Gas Information System Workshop; Albuquerque, New Mexico, 20-22 May 2009; The second Greenhouse Gas Information System (GHGIS) workshop brought together 74 representatives from 28 organizations including U.S. government agencies, national laboratories, and members of the academic community to address issues related to the understanding, operational monitoring, and tracking of greenhouse gas emissions and carbon offsets. The workshop was held at Sandia National Laboratories and organized by an interagency collaboration among NASA centers, Department of Energy laboratories, and the U.S. National Oceanic and Atmospheric Administration. It was motivated by the perceived need for an integrated interagency, community-wide initiative to provide information about greenhouse gas sources and sinks at policy-relevant temporal and spatial scales. Such an initiative could significantly enhance the ability of national and regional governments, industry, and private citizens to implement and evaluate effective climate change mitigation policies.

  4. Dataset of statements on policy integration of selected intergovernmental organizations

    Directory of Open Access Journals (Sweden)

    Jale Tosun

    2018-04-01

    Full Text Available This article describes data for 78 intergovernmental organizations (IGOs working on topics related to energy governance, environmental protection, and the economy. The number of IGOs covered also includes organizations active in other sectors. The point of departure for data construction was the Correlates of War dataset, from which we selected this sample of IGOs. We updated and expanded the empirical information on the IGOs selected by manual coding. Most importantly, we collected the primary law texts of the individual IGOs in order to code whether they commit themselves to environmental policy integration (EPI, climate policy integration (CPI and/or energy policy integration (EnPI.

  5. Integrated gasification gas combined cycle plant with membrane reactors: Technological and economical analysis

    International Nuclear Information System (INIS)

    Amelio, Mario; Morrone, Pietropaolo; Gallucci, Fausto; Basile, Angelo

    2007-01-01

    In the present work, the capture and storage of carbon dioxide from the fossil fuel power plant have been considered. The main objective was to analyze the thermodynamic performances and the technological aspects of two integrated gasification gas combined cycle plants (IGCC), as well as to give a forecast of the investment costs for the plants and the resulting energy consumptions. The first plant considered is an IGCC* plant (integrated gasification gas combined cycle plant with traditional shift reactors) characterized by the traditional water gas shift reactors and a CO 2 physical adsorption system followed by the power section. The second one is an IGCC M plant (integrated gasification gas combined cycle plant with membrane reactor) where the coal thermal input is the same as the first one, but the traditional shift reactors and the physical adsorption unit are replaced by catalytic palladium membrane reactors (CMR). In the present work, a mono-dimensional computational model of the membrane reactor was proposed to simulate and evaluate the capability of the IGCC M plant to capture carbon dioxide. The energetic performances, efficiency and net power of the IGCC* and IGCC M plants were, thus, compared, assuming as standard a traditional IGCC plant without carbon dioxide capture. The economical aspects of the three plants were compared through an economical analysis. Since the IGCC* and IGCC M plants have additional costs related to the capture and disposal of the carbon dioxide, a Carbon Tax (adopted in some countries like Sweden) proportional to the number of kilograms of carbon dioxide released in the environment was assumed. According to the economical analysis, the IGCC M plant proved to be more convenient than the IGCC* one

  6. An integrated approach to better performance in the oil and gas business

    International Nuclear Information System (INIS)

    Fowlie, D.

    1995-01-01

    The oil and gas industry was characterized as an increasingly complex industry with low growth and high competition. A model of system thinking was developed to show the interrelationships of the oil and gas business. Examples illustrated possible scenarios that companies could use with respect to explorations. It was concluded that integrated strategies will be needed when making decisions in the future because of the competitive and risky nature of the business. A proactive attitude will have be supplemented with the use of innovations in business approaches and implementation of new technological solutions

  7. Effect of organic matter properties, clay mineral type and thermal maturity on gas adsorption in organic-rich shale systems

    Science.gov (United States)

    Zhang, Tongwei; Ellis, Geoffrey S.; Ruppel, Stephen C.; Milliken, Kitty; Lewan, Mike; Sun, Xun; Baez, Luis; Beeney, Ken; Sonnenberg, Steve

    2013-01-01

    A series of CH4 adsorption experiments on natural organic-rich shales, isolated kerogen, clay-rich rocks, and artificially matured Woodford Shale samples were conducted under dry conditions. Our results indicate that physisorption is a dominant process for CH4 sorption, both on organic-rich shales and clay minerals. The Brunauer–Emmett–Teller (BET) surface area of the investigated samples is linearly correlated with the CH4 sorption capacity in both organic-rich shales and clay-rich rocks. The presence of organic matter is a primary control on gas adsorption in shale-gas systems, and the gas-sorption capacity is determined by total organic carbon (TOC) content, organic-matter type, and thermal maturity. A large number of nanopores, in the 2–50 nm size range, were created during organic-matter thermal decomposition, and they significantly contributed to the surface area. Consequently, methane-sorption capacity increases with increasing thermal maturity due to the presence of nanopores produced during organic-matter decomposition. Furthermore, CH4 sorption on clay minerals is mainly controlled by the type of clay mineral present. In terms of relative CH4 sorption capacity: montmorillonite ≫ illite – smectite mixed layer > kaolinite > chlorite > illite. The effect of rock properties (organic matter content, type, maturity, and clay minerals) on CH4 adsorption can be quantified with the heat of adsorption and the standard entropy, which are determined from adsorption isotherms at different temperatures. For clay-mineral rich rocks, the heat of adsorption (q) ranges from 9.4 to 16.6 kJ/mol. These values are considerably smaller than those for CH4 adsorption on kerogen (21.9–28 kJ/mol) and organic-rich shales (15.1–18.4 kJ/mol). The standard entropy (Δs°) ranges from -64.8 to -79.5 J/mol/K for clay minerals, -68.1 to -111.3 J/mol/K for kerogen, and -76.0 to -84.6 J/mol/K for organic-rich shales. The affinity of CH4 molecules for sorption on organic matter

  8. Optimal integration of organic Rankine cycles with industrial processes

    International Nuclear Information System (INIS)

    Hipólito-Valencia, Brígido J.; Rubio-Castro, Eusiel; Ponce-Ortega, José M.; Serna-González, Medardo; Nápoles-Rivera, Fabricio; El-Halwagi, Mahmoud M.

    2013-01-01

    Highlights: • An optimization approach for heat integration is proposed. • A new general superstructure for heat integration is proposed. • Heat process streams are simultaneously integrated with an organic Rankine cycle. • Better results can be obtained respect to other previously reported methodologies. - Abstract: This paper presents a procedure for simultaneously handling the problem of optimal integration of regenerative organic Rankine cycles (ORCs) with overall processes. ORCs may allow the recovery of an important fraction of the low-temperature process excess heat (i.e., waste heat from industrial processes) in the form of mechanical energy. An integrated stagewise superstructure is proposed for representing the interconnections and interactions between the HEN and ORC for fixed data of process streams. Based on the integrated superstructure, the optimization problem is formulated as a mixed integer nonlinear programming problem to simultaneously account for the capital and operating costs including the revenue from the sale of the shaft power produced by the integrated system. The application of this method is illustrated with three example problems. Results show that the proposed procedure provides significantly better results than an earlier developed method for discovering optimal integrated systems using a sequential approach, due to the fact that it accounts simultaneously for the tradeoffs between the capital and operating costs as well as the sale of the produced energy. Also, the proposed method is an improvement over the previously reported methods for solving the synthesis problem of heat exchanger networks without the option of integration with an ORC (i.e., stand-alone heat exchanger networks)

  9. Trend of the gas market and relaxation of regulation in major countries. Activities in Europe and America and problems of the gas industry in Japan; Shuyokoku no gas shijo to kisei kanwa no doko. Obei no ugoki to Nippon gas jigyo no kadai

    Energy Technology Data Exchange (ETDEWEB)

    Saita, A; Okaya, Y [Institute of Energy Economics, Tokyo (Japan)

    1994-11-24

    Recently, relaxation of regulation has been promoted in the gas markets of Europe and America. In Japan as well, an amendment to gas industry law including relaxation of regulation has been conducted, and it is to be effectuated from March 1995. In this report, position of gas in the energy market, consolidation status of infrastructure, market structure, and trend of regulation relaxation and competition promotion plan are compared in major countries. The future direction of the gas industry in Japan is discussed. Although there is vertical integration composed of producer, carrier and distributor in the traditional gas industry organization of major countries, Japan`s gas industry organization composes only of distributors. For the regulation relaxation in the U.K. and U.S.A., a third party access (TPA) system has been introduced, in which transportation net is opened to the third party. In Germany and France as well, regulation relaxation and liberation are discussed. For the regulation relaxation of gas market in Japan, it is pointed out that the poor consolidation of infrastructure, such as transportation net should be taken into account. 48 figs., 6 tabs.

  10. Effects of syngas type on the operation and performance of a gas turbine in integrated gasification combined cycle

    International Nuclear Information System (INIS)

    Kim, Young Sik; Lee, Jong Jun; Kim, Tong Seop; Sohn, Jeong L.

    2011-01-01

    Research highlights: → The effect of firing syngas in a gas turbine designed for natural gas was investigated. → A full off-design analysis was performed for a wide syngas heating value range. → Restrictions on compressor surge margin and turbine metal temperature were considered. -- Abstract: We investigated the effects of firing syngas in a gas turbine designed for natural gas. Four different syngases were evaluated as fuels for a gas turbine in the integrated gasification combined cycle (IGCC). A full off-design analysis of the gas turbine was performed. Without any restrictions on gas turbine operation, as the heating value of the syngas decreases, a greater net system power output and efficiency is possible due to the increased turbine mass flow. However, the gas turbine is more vulnerable to compressor surge and the blade metal becomes more overheated. These two problems can be mitigated by reductions in two parameters: the firing temperature and the nitrogen flow to the combustor. With the restrictions on surge margin and metal temperature, the net system performance decreases compared to the cases without restrictions, especially in the surge margin control range. The net power outputs of all syngas cases converge to a similar level as the degree of integration approaches zero. The difference in net power output between unrestricted and restricted operation increases as the fuel heating value decreases. The optimal integration degree, which shows the greatest net system power output and efficiency, increases with decreasing syngas heating value.

  11. Effects of syngas type on the operation and performance of a gas turbine in integrated gasification combined cycle

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Young Sik; Lee, Jong Jun [Graduate School, Inha University, Incheon 402-751 (Korea, Republic of); Kim, Tong Seop, E-mail: kts@inha.ac.k [Dept. of Mechanical Engineering, Inha University, Incheon 402-751 (Korea, Republic of); Sohn, Jeong L. [Center for Next Generation Heat Exchangers, Busan 618-230 (Korea, Republic of)

    2011-05-15

    Research highlights: {yields} The effect of firing syngas in a gas turbine designed for natural gas was investigated. {yields} A full off-design analysis was performed for a wide syngas heating value range. {yields} Restrictions on compressor surge margin and turbine metal temperature were considered. -- Abstract: We investigated the effects of firing syngas in a gas turbine designed for natural gas. Four different syngases were evaluated as fuels for a gas turbine in the integrated gasification combined cycle (IGCC). A full off-design analysis of the gas turbine was performed. Without any restrictions on gas turbine operation, as the heating value of the syngas decreases, a greater net system power output and efficiency is possible due to the increased turbine mass flow. However, the gas turbine is more vulnerable to compressor surge and the blade metal becomes more overheated. These two problems can be mitigated by reductions in two parameters: the firing temperature and the nitrogen flow to the combustor. With the restrictions on surge margin and metal temperature, the net system performance decreases compared to the cases without restrictions, especially in the surge margin control range. The net power outputs of all syngas cases converge to a similar level as the degree of integration approaches zero. The difference in net power output between unrestricted and restricted operation increases as the fuel heating value decreases. The optimal integration degree, which shows the greatest net system power output and efficiency, increases with decreasing syngas heating value.

  12. The use of diffusive samplers for collecting organic gaseous constituents in waste gases. Diffusionssammler zur Probenahme von organischen gas- und dampffoermigen Substanzen in Abgasen

    Energy Technology Data Exchange (ETDEWEB)

    Canela, A.; Gruntz, U.; Muehleisen, H.; Tanner, S. (Sandoz AG, Basel (Switzerland). Umweltschutzlaboratorien)

    1990-01-01

    A relatively simple procedure for sample collection of multicomponent organic emissions is presented. A representative part of the waste gas is taken by means of a sampling probe and flows to the coupled sampling device. The gaseous constituents are collected in several diffusive samplers at the bottom of the device. Influencing parameters such as pressure, temperature, gas velocity etc., which may affect the collection rate and therefore the measured values, were investigated in the laboratory. Depending on the analytical detection limit, the sampling time and the diffusion parameters, the method can be applied for the determination of integrated emission concentrations between 0.1 mg/m{sup 3} and 1 g/m{sup 3}. (orig.).

  13. Municipal Solid Waste Gasification Plant Integrated With SOFC and Gas Turbine

    DEFF Research Database (Denmark)

    Bellomare, Filippo; Rokni, Masoud

    2012-01-01

    An interesting source of producing energy with low pollutants emission and reduced environmental impact are the biomasses; particularly using Municipal Solid Waste (MSW) as fuel, can be a competitive solution not only to produce energy with negligible costs but also to decrease the storage...... in landfills. A Municipal Solid Waste Gasification Plant Integrated with Solid Oxide Fuel Cell (SOFC) and Gas Turbine (GT) has been studied and the plant is called IGSG (Integrated Gasification SOFC and GT). Gasification plant is fed by MSW to produce syngas by which the anode side of a SOFC is fed wherein...

  14. Organic substances in produced and formation water from unconventional natural gas extraction in coal and shale

    Science.gov (United States)

    Orem, William H.; Tatu, Calin A.; Varonka, Matthew S.; Lerch, Harry E.; Bates, Anne L.; Engle, Mark A.; Crosby, Lynn M.; McIntosh, Jennifer

    2014-01-01

    Organic substances in produced and formation water from coalbed methane (CBM) and gas shale plays from across the USA were examined in this study. Disposal of produced waters from gas extraction in coal and shale is an important environmental issue because of the large volumes of water involved and the variable quality of this water. Organic substances in produced water may be environmentally relevant as pollutants, but have been little studied. Results from five CBM plays and two gas shale plays (including the Marcellus Shale) show a myriad of organic chemicals present in the produced and formation water. Organic compound classes present in produced and formation water in CBM plays include: polycyclic aromatic hydrocarbons (PAHs), heterocyclic compounds, alkyl phenols, aromatic amines, alkyl aromatics (alkyl benzenes, alkyl biphenyls), long-chain fatty acids, and aliphatic hydrocarbons. Concentrations of individual compounds range from gas shale unimpacted by production chemicals have a similar range of compound classes as CBM produced water, and TOC levels of about 8 mg/L. However, produced water from the Marcellus Shale using hydraulic fracturing has TOC levels as high as 5500 mg/L and a range of added organic chemicals including, solvents, biocides, scale inhibitors, and other organic chemicals at levels of 1000 s of μg/L for individual compounds. Levels of these hydraulic fracturing chemicals and TOC decrease rapidly over the first 20 days of water recovery and some level of residual organic contaminants remain up to 250 days after hydraulic fracturing. Although the environmental impacts of the organics in produced water are not well defined, results suggest that care should be exercised in the disposal and release of produced waters containing these organic substances into the environment because of the potential toxicity of many of these substances.

  15. Assessment of Integrated Information System (IIS) in organization ...

    African Journals Online (AJOL)

    Assessment of Integrated Information System (IIS) in organization. ... to enable the Information System (IS) managers, as well as top management to understand the ... since organisational and strategic aspects in IIS should also be considered.

  16. NOVEL GAS CLEANING/CONDITIONING FOR INTEGRATED GASIFICATION COMBINED CYCLE

    Energy Technology Data Exchange (ETDEWEB)

    Dennis A. Horazak; Richard A. Newby; Eugene E. Smeltzer; Rachid B. Slimane; P. Vann Bush; James L. Aderhold Jr; Bruce G. Bryan

    2005-12-01

    Development efforts have been underway for decades to replace dry-gas cleaning technology with humid-gas cleaning technology that would maintain the water vapor content in the raw gas by conducting cleaning at sufficiently high temperature to avoid water vapor condensation and would thus significantly simplify the plant and improve its thermal efficiency. Siemens Power Generation, Inc. conducted a program with the Gas Technology Institute (GTI) to develop a Novel Gas Cleaning process that uses a new type of gas-sorbent contactor, the ''filter-reactor''. The Filter-Reactor Novel Gas Cleaning process described and evaluated here is in its early stages of development and this evaluation is classified as conceptual. The commercial evaluations have been coupled with integrated Process Development Unit testing performed at a GTI coal gasifier test facility to demonstrate, at sub-scale the process performance capabilities. The commercial evaluations and Process Development Unit test results are presented in Volumes 1 and 2 of this report, respectively. Two gas cleaning applications with significantly differing gas cleaning requirements were considered in the evaluation: IGCC power generation, and Methanol Synthesis with electric power co-production. For the IGCC power generation application, two sets of gas cleaning requirements were applied, one representing the most stringent ''current'' gas cleaning requirements, and a second set representing possible, very stringent ''future'' gas cleaning requirements. Current gas cleaning requirements were used for Methanol Synthesis in the evaluation because these cleaning requirements represent the most stringent of cleaning requirements and the most challenging for the Filter-Reactor Novel Gas Cleaning process. The scope of the evaluation for each application was: (1) Select the configuration for the Filter-Reactor Novel Gas Cleaning Process, the arrangement of the

  17. WATER-GAS SHIFT WITH INTEGRATED HYDROGEN SEPARATION; A

    International Nuclear Information System (INIS)

    Maria Flytzani-Stephanopoulos; Jerry Meldon; Xiaomei Qi

    2001-01-01

    Optimization of the water-gas shift (WGS) reaction system for hydrogen production for fuel cells is of particular interest to the energy industry. To this end, it is desirable to couple the WGS reaction to hydrogen separation using a semi-permeable membrane, with both processes carried out at high temperature to improve reaction kinetics. Reduced equilibrium conversion of the WGS reaction at high temperatures is overcome by product H(sub 2) removal via the membrane. This project involves fundamental research and development of novel cerium oxide-based catalysts for the water-gas-shift reaction and the integration of these catalysts with Pd-alloy H(sub 2)-separation membranes supplying high purity hydrogen for fuel cell use. Conditions matching the requirements of coal gasifier-exit gas streams will be examined in the project. In the first year of the project, we prepared a series of nanostructured Cu- and Fe-containing ceria catalysts by a special gelation/precipitation technique followed by air calcination at 650 C. Each sample was characterized by ICP for elemental composition analysis, BET-N2 desorption for surface area measurement, and by temperature-programmed reduction in H(sub 2) to evaluate catalyst reducibility. Screening WGS tests with catalyst powders were conducted in a flow microreactor at temperatures in the range of 200-550 C. On the basis of both activity and stability of catalysts in simulated coal gas, and in CO(sub 2)-rich gases, a Cu-CeO(sub 2) catalyst formulation was selected for further study in this project. Details from the catalyst development and testing work are given in this report. Also in this report, we present H(sub 2) permeation data collected with unsupported flat membranes of pure Pd and Pd-alloys over a wide temperature window

  18. Techno-economic evaluation for the heat integration of vaporisation cold energy in natural gas processing

    International Nuclear Information System (INIS)

    Koku, Oludolapo; Perry, Simon; Kim, Jin-Kuk

    2014-01-01

    Highlights: • Development of thermal integration modelling framework for the utilisation of LNG cold energy. • Feasibility study for various design options for the integration of low-temperature cold energy. • Provision of a design approach for achieving efficient use of cold energy in LNG terminals. • Understanding of techno-economic impacts associated with the thermal integration of LNG cold energy. - Abstract: This paper addresses a conceptual study investigating the techno-economic feasibility for the thermal Integration of LNG cold vaporisation energy in power generation applications. In conventional regasification systems, this valuable LNG cold energy is often being wasted to ambient heat sources, representing a thermodynamic inefficient process with a significant thermal impact on the local environment. A combined facility consisting of a non-integrated Combined Cycle Power Plant (CCPP) and an LNG receiving terminal employing traditional Open Rack Vaporisers (ORV) technology, has been modelled, as a base case. Retrofit strategies for the integration of LNG cold energy have been investigated, and their impacts on power production and system efficiency are systematically compared. Retrofit design options considered in this work include the use of a propane Rankine cycle coupled with the direct expansion of natural gas, the integration of a closed-loop water cycle or open-loop water circuit with a steam Rankine cycle, and the facilitation of integrated air cooling for a gas turbine

  19. Optimal Energy Management for the Integrated Power and Gas Systems via Real-time Pricing

    DEFF Research Database (Denmark)

    Shu, KangAn; Ai, Xiaomeng; Wen, Jinyu

    2018-01-01

    This work proposed a bi-level formulation for energy management in the integrated power and natural gas system via real-time price signals. The upper-level problem minimizes the operational cost, in which dynamic electricity price and dynamic gas tariff are proposed. The lower level problem...... and P2Gs plants follow the system operator’s preferences such as wind power accommodation, mitigation of unsupplied load and relieving the network congestion....

  20. Economic integration and cross-border economic organizations: The case of San Diego-Tijuana

    Directory of Open Access Journals (Sweden)

    Jorge Eduardo Mendoza Cota

    2017-01-01

    Full Text Available The economic integration between the United States and Mexico has affected the economic, political and social relations in the border region. The paper seeks to relate the increasing economic integration and business cycles of the economies of San Diego and Tijuana to the development of both national and binational economic organizations in the border region. The methodology of analysis uses both statistical estimations of the economic integration of San Diego and Tijuana and semi-structured interviews of economic organizations to analyze the increasing economic integration and the role and achievements of the cross-border economic organizations. The results showed that cross-border cooperation is predominately controlled by federal and state governments on both sides of the border. However, the main achievements of cross-border economic cooperation have been accomplished by local private organizations. The perspective of further local economic development greatly depends on both the possibility of increased involvement of federal governments and the growing encouragement of regional organizations.

  1. A technique for rapid source apportionment applied to ambient organic aerosol measurements from a thermal desorption aerosol gas chromatograph (TAG

    Directory of Open Access Journals (Sweden)

    Y. Zhang

    2016-11-01

    Full Text Available We present a rapid method for apportioning the sources of atmospheric organic aerosol composition measured by gas chromatography–mass spectrometry methods. Here, we specifically apply this new analysis method to data acquired on a thermal desorption aerosol gas chromatograph (TAG system. Gas chromatograms are divided by retention time into evenly spaced bins, within which the mass spectra are summed. A previous chromatogram binning method was introduced for the purpose of chromatogram structure deconvolution (e.g., major compound classes (Zhang et al., 2014. Here we extend the method development for the specific purpose of determining aerosol samples' sources. Chromatogram bins are arranged into an input data matrix for positive matrix factorization (PMF, where the sample number is the row dimension and the mass-spectra-resolved eluting time intervals (bins are the column dimension. Then two-dimensional PMF can effectively do three-dimensional factorization on the three-dimensional TAG mass spectra data. The retention time shift of the chromatogram is corrected by applying the median values of the different peaks' shifts. Bin width affects chemical resolution but does not affect PMF retrieval of the sources' time variations for low-factor solutions. A bin width smaller than the maximum retention shift among all samples requires retention time shift correction. A six-factor PMF comparison among aerosol mass spectrometry (AMS, TAG binning, and conventional TAG compound integration methods shows that the TAG binning method performs similarly to the integration method. However, the new binning method incorporates the entirety of the data set and requires significantly less pre-processing of the data than conventional single compound identification and integration. In addition, while a fraction of the most oxygenated aerosol does not elute through an underivatized TAG analysis, the TAG binning method does have the ability to achieve molecular level

  2. Pipelines update : new tolls and new opportunities in gas gathering

    International Nuclear Information System (INIS)

    Shelton, E.

    1999-01-01

    An overview of the new TransCanada energy transmission system was given. TransCanada has ownership interests in seven other North American natural gas pipelines and the integration of former NOVA Gas Transmission, TransCanada Energy Transmission and ANG Pipeline organizations into a single organization is nearing completion. Integration efforts have been driven by TransCanada's commitment to provide customers with lower costs and improved service levels. The service enhancements will include one-stop shopping, customer advisory councils, harmonized design criteria, optimized operations/maintenance, and consistent billing processes. The new toll design which will replace the current postage-stamp pricing regime offered by NGTL was also reviewed, emphasizing key features such as pricing, term linked tolls, interruptible/short term tolls, renewal incentive, risk/reward collar, transition period and new services

  3. An Industrial Cloud: Integrated Operations in Oil and Gas in the Norwegian Continental Shelf

    Science.gov (United States)

    Rong, Chunming

    Cloud computing may provide the long waiting technologies and methodologies for large scale industrial collaboration across disciplines and enterprise boundaries. Industrial cloud is introduced as a new inter-enterprise integration concept in cloud computing. Motivations and advantages are given by a practical exploration of the concept from the perspective of the on-going effort by the Norwegian oil and gas industry to build industry wide information integration and collaboration. ISO15926 is recognized as a standard enabling cross boundaries data integration and processing.

  4. Integrated underground gas storage of CO2 and CH4 to decarbonize the "power-to-gas-to-gas-to-power" technology

    Science.gov (United States)

    Kühn, Michael; Streibel, Martin; Nakaten, Natalie; Kempka, Thomas

    2014-05-01

    Massive roll-out of renewable energy production units (wind turbines and solar panels) leads to date to excess energy which cannot be consumed at the time of production. So far, long-term storage is proposed via the so called 'power-to-gas' technology. Energy is transferred to methane gas and subsequently combusted for power production - 'power-to-gas-to-power' (PGP) - when needed. PGP profits from the existing infrastructure of the gas market and could be deployed immediately. However, major shortcoming is the production of carbon dioxide (CO2) from renewables and its emission into the atmosphere. We present an innovative idea which is a decarbonised extension of the PGP technology. The concept is based on a closed carbon cycle: (1) Hydrogen (H2) is generated from renewable energy by electrolysis and (2) transformed into methane (CH4) with CO2 taken from an underground geological storage. (3) CH4 produced is stored in a second storage underground until needed and (4) combusted in a combined-cycled power plant on site. (5) CO2 is separated during energy production and re-injected into the storage formation. We studied a show case for the cities Potsdam and Brandenburg/Havel in the Federal State of Brandenburg in Germany to determine the energy demand of the entire process chain and the costs of electricity (COE) using an integrated techno-economic modelling approach (Nakaten et al. 2014). Taking all of the individual process steps into account, the calculation shows an overall efficiency of 27.7 % (Streibel et al. 2013) with total COE of 20.43 euro-cents/kWh (Kühn et al. 2013). Although the level of efficiency is lower than for pump and compressed air storage, the resulting costs are similar in magnitude, and thus competitive on the energy storage market. The great advantage of the concept proposed here is that, in contrast to previous PGP approaches, this process is climate-neutral due to CO2 utilisation. For that purpose, process CO2 is temporally stored in an

  5. An integrated transient model for simulating the operation of natural gas transport systems

    NARCIS (Netherlands)

    Pambour, Kwabena Addo; Bolado-Lavin, Ricardo; Dijkema, Gerard P. J.

    This paper presents an integrated transient hydraulic model that describes the dynamic behavior of natural gas transport systems (GTS). The model includes sub models of the most important facilities comprising a GTS, such as pipelines, compressor stations, pressure reduction stations, underground

  6. Organic Iodine Adsorption by AgZ under Prototypical Vessel Off-Gas Conditions

    International Nuclear Information System (INIS)

    Bruffey, Stephanie H.; Jubin, Robert Thomas; Jordan, J. A.

    2016-01-01

    U.S. regulations will require the removal of 129 I from the off-gas streams of any used nuclear fuel (UNF) reprocessing plant prior to discharge of the off-gas to the environment. Multiple off-gas streams within a UNF reprocessing plant combine prior to release, and each of these streams contains some amount of iodine. For an aqueous UNF reprocessing plant, these streams include the dissolver off-gas, the cell off-gas, the vessel off-gas (VOG), the waste off-gas and the shear off-gas. To achieve regulatory compliance, treatment of multiple off-gas streams within the plant must be performed. Preliminary studies have been completed on the adsorption of I 2 onto silver mordenite (AgZ) from prototypical VOG streams. The study reported that AgZ did adsorb I 2 from a prototypical VOG stream, but process upsets resulted in an uneven feed stream concentration. The experiments described in this document both improve the characterization of I 2 adsorption by AgZ from dilute gas streams and further extend it to include characterization of the adsorption of organic iodides (in the form of CH 3 I) onto AgZ under prototypical VOG conditions. The design of this extended duration testing was such that information about the rate of adsorption, the penetration of the iodine species, and the effect of sorbent aging on iodine removal in VOG conditions could be inferred.

  7. Organic Iodine Adsorption by AgZ under Prototypical Vessel Off-Gas Conditions

    Energy Technology Data Exchange (ETDEWEB)

    Bruffey, Stephanie H. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Jubin, Robert Thomas [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Jordan, J. A. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

    2016-09-30

    U.S. regulations will require the removal of 129I from the off-gas streams of any used nuclear fuel (UNF) reprocessing plant prior to discharge of the off-gas to the environment. Multiple off-gas streams within a UNF reprocessing plant combine prior to release, and each of these streams contains some amount of iodine. For an aqueous UNF reprocessing plant, these streams include the dissolver off-gas, the cell off-gas, the vessel off-gas (VOG), the waste off-gas and the shear off-gas. To achieve regulatory compliance, treatment of multiple off-gas streams within the plant must be performed. Preliminary studies have been completed on the adsorption of I2 onto silver mordenite (AgZ) from prototypical VOG streams. The study reported that AgZ did adsorb I2 from a prototypical VOG stream, but process upsets resulted in an uneven feed stream concentration. The experiments described in this document both improve the characterization of I2 adsorption by AgZ from dilute gas streams and further extend it to include characterization of the adsorption of organic iodides (in the form of CH3I) onto AgZ under prototypical VOG conditions. The design of this extended duration testing was such that information about the rate of adsorption, the penetration of the iodine species, and the effect of sorbent aging on iodine removal in VOG conditions could be inferred.

  8. Integrated petrographic and geochemical study of coal and gas shales from the Sabinas and Chihuahua basins, North of Mexico: estimation of methane gas resources

    International Nuclear Information System (INIS)

    De La O Burrola, Francisco

    2013-01-01

    This comprehensive characterization study was performed using organic petrology and geochemistry conducted in the Sabinas basin and Chihuahua in northern Mexico. This information allowed a numerical modeling of gas formation, considering the thermal subsidence of coal and carbonaceous shales. The objectives of this thesis are: - Establish a characterization methodology for the studied rocks - Estimate potential gas generator and its regional distribution - Estimate the methane gas resources For the development of this project, we conducted an intensive campaign representative sampling of coal, carbonaceous shales and coal gas 'in situ'. For the Sabinas basin were studied 97 samples and 114 samples in the basin of Chihuahua. The analyses carried out that were used on the samples analyzed allowed to characterize the kerogen and gas. The methodology used to cross petrographic and geochemical information to analyze the petroleum system by numerical modeling. Analyses were: Petrographic, reflectance %Ro, elemental analysis and immediate, Rock Eval6 R (Bulk rock), isotopic analysis, δ 13 C, δD, (coal gas), scanning electron microscopy, image analysis and analysis of macerals fluid inclusions. The analyzes that were used on the samples allowed to characterize the sample, the kerogen and gas. The methodology used to cross petrographic and geochemical information for analyze the oil system by numerical modeling. Analyses were: Petrographic, reflectance %Ro, elemental analysis and immediate, Rock Eval6 R (Bulk rock), isotopic analysis, δ 13 C, δD, (coal gas), scanning electron microscopy, image analysis and analysis of macerals fluid inclusions A computer program was constructed to cross the information with the analysis of samples of artificial maturation experiments in the laboratory. This approach allowed estimation of methane gas resources generated by coal and carbonaceous shales. The main results obtained for Sabinas Basin were: - The kerogen of the

  9. Integrated field modelling[Oil and gas fields

    Energy Technology Data Exchange (ETDEWEB)

    Nazarian, Bamshad

    2002-07-01

    This research project studies the feasibility of developing and applying an integrated field simulator to simulate the production performance of an entire oil or gas field. It integrates the performance of the reservoir, the wells, the chokes, the gathering system, the surface processing facilities and whenever applicable, gas and water injection systems. The approach adopted for developing the integrated simulator is to couple existing commercial reservoir and process simulators using available linking technologies. The simulators are dynamically linked and customised into a single hybrid application that benefits from the concept of open software architecture. The integrated field simulator is linked to an optimisation routine developed based on the genetic algorithm search strategies. This enables optimisation of the system at field level, from the reservoir to the process. Modelling the wells and the gathering network is achieved by customising the process simulator. This study demonstrated that the integrated simulation improves current capabilities to simulate the performance of the entire field and optimise its design. This is achieved by evaluating design options including spread and layout of the wells and gathering system, processing alternatives, reservoir development schemes and production strategies. Effectiveness of the integrated simulator is demonstrated and tested through several field-level case studies that discuss and investigate technical problems relevant to offshore field development. The case studies cover topics such as process optimisation, optimum tie-in of satellite wells into existing process facilities, optimal well location and field layout assessment of a high pressure high temperature deepwater oil field. Case study results confirm the viability of the total field simulator by demonstrating that the field performance simulation and optimal design were obtained in an automated process with treasonable computation time. No significant

  10. Preliminary study or RSG-GAS reactor fuel element integrity

    International Nuclear Information System (INIS)

    Soejoedi, A.; Tarigan, A.; Sujalmo; Prayoga, S.; Suhadi

    1996-01-01

    After 8 years of operation, RSG-GAS was able to reach 15 cycles of reactor operation with 116 irradiated fuels, whereas 49 fuels were produced by NUKEM; and the other 67 were produced by PEBN-BATAN. At the 15 T h cycles, it have been used 40 standard fuels and 8 control fuels (Forty standard fuels and eight control fuels have been used in the 15 t h core cycles). Several activities have been performed in the reactor, to investigate the fuel integrity, among of them are: .fuel visual test with under water camera, which the results were recorder in the video cassette, primary water quality test during, reactor operation, fuel failure detector system examination and compared the PIE results in the Radiometallurgy Installation (RMI). The results showed that the fuel integrity, before and after irradiation, have still good performance and the fission products have not been released yet

  11. Self-organization of voids, gas bubbles and dislocation patterns under irradiation

    International Nuclear Information System (INIS)

    Dubinko, V.I.; Turkin, A.A.

    1993-01-01

    In the present paper three examples of self-organization in solids under irradiation are considered on the basis of original mechanisms, namely, the ordering of voids in void lattices under high temperature irradiation, the alignment of gas bubbles in bubble lattices under low-temperature gas atom implantation, and the formation of superdislocations (one-dimensional pile-ups of dislocation loops) and other dislocation patterns in the regimes of medium and high temperature irradiation. The ordering of cavities (i.e.voids or gas bubbles) is shown to arise due to a dissipative interaction between cavities induced by the interstitial dislocation loop absorption and punching, respectively, which represent anisotropic mechanisms of atomic transport. The dislocation patterning is shown to be driven by the dependence of dislocation bias for absorption of self-interstitial atoms on the dislocation arrangement. (author). 57 refs., 1 tab., 12 figs

  12. Development of a Simulation Framework for Analyzing Security of Supply in Integrated Gas and Electric Power Systems

    NARCIS (Netherlands)

    Pambour, Kwabena Addo; Erdener, Burcin Cakir; Bolado-Lavin, Ricardo; Dijkema, Gerhard

    2017-01-01

    Gas and power networks are tightly coupled and interact with each other due to physically interconnected facilities. In an integrated gas and power network, a contingency observed in one system may cause iterative cascading failures, resulting in network wide disruptions. Therefore, understanding

  13. Online Measurements of Highly Oxidized Organics in the Gas and Particle phase during SOAS and SENEX

    Science.gov (United States)

    Lopez-Hilfiker, F.; Lee, B. H.; Mohr, C.; Ehn, M.; Rubach, F.; Mentel, T. F.; Kleist, E.; Thornton, J. A.

    2014-12-01

    We present measurements of a large suite of gas and particle phase organic compounds made with a Filter Inlet for Gas and AEROsol (FIGAERO) coupled to a high resolution time of flight chemical ionization mass spectrometer (HR-ToF-CIMS) developed at the University of Washington and with airborne HR-ToF-CIMS measurements. The FIGAERO instrument was deployed on the Jülich Plant Atmosphere Chamber to study α-pinene oxidation, and subsequently at the SMEAR II forest station in Hyytiälä, Finland and the SOAS ground site, in Brent Alabama. During the Southern Atmosphere Study, a gas-phase only version of the HR-ToF-CIMS was deployed on the NOAA WP-3 aircraft as part of SENEX. We focus here on highly oxygenated organic compounds derived from monoterpene oxidation detected both aloft during SENEX and at the ground-based site during SOAS. In both chamber and the atmosphere, many highly oxidized, low volatility compounds were observed in the gas and particles and many of the same compositions detected in the gas-phase were detected in the particles upon temperature programmed thermal desorption. The fraction of a given compound measured in the particle phase follows expected trends with elemental composition such as O/C ratios, but many compounds would not be well described by an absorptive partitioning model assuming unity activity coefficients. The detailed structure in the thermograms reveals a significant contribution from large molecular weight organics and/or oligomers in both chamber and ambient aerosol samples. Approximately 50% of the measured organics in the particle phase are associated with compounds having effective vapour pressures 4 or more orders of magnitude lower than commonly measured monoterpene oxidation products. We discuss the implications of these findings for measurements of gas-particle partitioning and for evaluating the contribution of monoterpene oxidation to organic aerosol formation and growth. We also use the aircraft measurements and a

  14. Supply prospects and network integration in the European natural gas sector

    International Nuclear Information System (INIS)

    Bergmann, B.

    1998-01-01

    At least for the next 10-15 years, natural gas will be the fastest growing energy form in Europe, with a higher rate of growth in consumption (from a lower base) in central Europe than in western Europe. Although most of the prospective demand until 2010 is covered by signed import contracts and indigenous production, important additional gas supply capacity still has to be developed out of a plenitude of reserves within and (in the long run primarily) outside western and central Europe. The real problem is how to mobilise the reserves economically and direct them towards the European market, in competition with other markets. Europe has a sophisticated transmission system whose development has gone hand-in-hand with long-term import agreements. Among the missing links is the Interconnector, which, at the end of 1998, is due to integrate the UK and Ireland into mainland Europe. This is expected to enhance security of supply in both areas, to balance prices and maybe also to foster ideas of liberalisation. Overall, the European gas industry is in an excellent position to develop the supply of gas in an environmentally benign way. The future belongs all the more to natural gas, the fewer the mistakes that are made when it comes to matters of legal frameworks and taxation

  15. Synthesis of refractory organic matter in the ionized gas phase of the solar nebula.

    Science.gov (United States)

    Kuga, Maïa; Marty, Bernard; Marrocchi, Yves; Tissandier, Laurent

    2015-06-09

    In the nascent solar system, primitive organic matter was a major contributor of volatile elements to planetary bodies, and could have played a key role in the development of the biosphere. However, the origin of primitive organics is poorly understood. Most scenarios advocate cold synthesis in the interstellar medium or in the outer solar system. Here, we report the synthesis of solid organics under ionizing conditions in a plasma setup from gas mixtures (H2(O)-CO-N2-noble gases) reminiscent of the protosolar nebula composition. Ionization of the gas phase was achieved at temperatures up to 1,000 K. Synthesized solid compounds share chemical and structural features with chondritic organics, and noble gases trapped during the experiments reproduce the elemental and isotopic fractionations observed in primitive organics. These results strongly suggest that both the formation of chondritic refractory organics and the trapping of noble gases took place simultaneously in the ionized areas of the protoplanetary disk, via photon- and/or electron-driven reactions and processing. Thus, synthesis of primitive organics might not have required a cold environment and could have occurred anywhere the disk is ionized, including in its warm regions. This scenario also supports N2 photodissociation as the cause of the large nitrogen isotopic range in the solar system.

  16. Measuring resilience in integrated planning

    DEFF Research Database (Denmark)

    Apneseth, K.; Wahl, A. M.; Hollnagel, E.

    2013-01-01

    This chapter demonstrates how a Resilience Analysis Grid (RAG) can be used to profile the performance of a company in terms of the four abilities that characterize a resilient organization. It describes the development of a new, RAG-based tool founded on Resilience Engineering principles that can...... be used to assess an organization's resilience. The tool was tested in a case study involving a company in the offshore oil and gas industry. The company had decided to adopt an Integrated Operations (IO) approach to operations and maintenance planning and the tool was used to evaluate the impact...... of the Integrated Planning (IPL) process on its resilience....

  17. Integration of real-time operational data in geographical information for power and gas business; Integrando em tempo real os dados operacionais aos sistemas geo referenciados do negocio gas e energia

    Energy Technology Data Exchange (ETDEWEB)

    Salcedo, Fernando Jose de Carvalho; Carvalho, Ronaldo Jose Seixas de [PETROBRAS, Rio de Janeiro, RJ (Brazil)

    2005-07-01

    The Strategical Management of Data and Information of the Gas e Energia, has as its being reason, the provision of right information, in the right place and in the right time, based on the correct sources, adding strategic value to Business. The SCADA systems (Supervisory Control and Data Acquisition), give to the Thermoelectrical Plant Operators and Electrical Transporting Operators the integration with the operational stations, measurement and energy delivery. The Geographical Information Systems - GIS, give the maps visualization with geopolitics aspects, gas pipeline infrastructure and satellite images. The Historical Data systems, have as its requirements the interface between many SCADA systems by means of accompaniment of historical data, real time data of the common variables of the process (outflow, pressure, temperature, egg.) and KPI's visualization - typical performance indicators of energy systems (non-availability, generation efficiency and distribution, egg.). Based on the business systemic vision, the Real-Time Enterprise Architecture - Real Time data integration and Performance Indicators based on the GIS software platform was developed in the Gas e Energia enterprise scenario. The present action has, as its focus, the dynamic visualization in real-time of the integrated data to the GIS infrastructure of the Gas Pipelines and Thermoelectrical Plants, guaranteeing the integrity, the audit trail of the information and a pro active vision for the Management of the Gas e Energia Business. (author)

  18. Integration of real-time operational data in geographical information for power and gas business; Integrando em tempo real os dados operacionais aos sistemas geo referenciados do negocio gas e energia

    Energy Technology Data Exchange (ETDEWEB)

    Salcedo, Fernando Jose de Carvalho; Carvalho, Ronaldo Jose Seixas de [PETROBRAS, Rio de Janeiro, RJ (Brazil)

    2005-07-01

    The Strategical Management of Data and Information of the Gas e Energia, has as its being reason, the provision of right information, in the right place and in the right time, based on the correct sources, adding strategic value to Business. The SCADA systems (Supervisory Control and Data Acquisition), give to the Thermoelectrical Plant Operators and Electrical Transporting Operators the integration with the operational stations, measurement and energy delivery. The Geographical Information Systems - GIS, give the maps visualization with geopolitics aspects, gas pipeline infrastructure and satellite images. The Historical Data systems, have as its requirements the interface between many SCADA systems by means of accompaniment of historical data, real time data of the common variables of the process (outflow, pressure, temperature, egg.) and KPI's visualization - typical performance indicators of energy systems (non-availability, generation efficiency and distribution, egg.). Based on the business systemic vision, the Real-Time Enterprise Architecture - Real Time data integration and Performance Indicators based on the GIS software platform was developed in the Gas e Energia enterprise scenario. The present action has, as its focus, the dynamic visualization in real-time of the integrated data to the GIS infrastructure of the Gas Pipelines and Thermoelectrical Plants, guaranteeing the integrity, the audit trail of the information and a pro active vision for the Management of the Gas e Energia Business. (author)

  19. Technology Integration and Technology Leadership in Schools as Learning Organizations

    Science.gov (United States)

    Cakir, Recep

    2012-01-01

    The purpose of this study was to investigate technology integration in primary schools from the perspective of leadership in learning organizations. To that end, the study examines two groups: school administrators who play effective roles in technology integration in schools and computer teachers who are mainly responsible for schools' technology…

  20. Modeling the gas-particle partitioning of secondary organic aerosol: the importance of liquid-liquid phase separation

    Directory of Open Access Journals (Sweden)

    A. Zuend

    2012-05-01

    Full Text Available The partitioning of semivolatile organic compounds between the gas phase and aerosol particles is an important source of secondary organic aerosol (SOA. Gas-particle partitioning of organic and inorganic species is influenced by the physical state and water content of aerosols, and therefore ambient relative humidity (RH, as well as temperature and organic loading levels. We introduce a novel combination of the thermodynamic models AIOMFAC (for liquid mixture non-ideality and EVAPORATION (for pure compound vapor pressures with oxidation product information from the Master Chemical Mechanism (MCM for the computation of gas-particle partitioning of organic compounds and water. The presence and impact of a liquid-liquid phase separation in the condensed phase is calculated as a function of variations in relative humidity, organic loading levels, and associated changes in aerosol composition. We show that a complex system of water, ammonium sulfate, and SOA from the ozonolysis of α-pinene exhibits liquid-liquid phase separation over a wide range of relative humidities (simulated from 30% to 99% RH. Since fully coupled phase separation and gas-particle partitioning calculations are computationally expensive, several simplified model approaches are tested with regard to computational costs and accuracy of predictions compared to the benchmark calculation. It is shown that forcing a liquid one-phase aerosol with or without consideration of non-ideal mixing bears the potential for vastly incorrect partitioning predictions. Assuming an ideal mixture leads to substantial overestimation of the particulate organic mass, by more than 100% at RH values of 80% and by more than 200% at RH values of 95%. Moreover, the simplified one-phase cases stress two key points for accurate gas-particle partitioning calculations: (1 non-ideality in the condensed phase needs to be considered and (2 liquid-liquid phase separation is a consequence of considerable deviations

  1. Experimental systems of integrated and organic wheat production

    NARCIS (Netherlands)

    Vereijken, P.H.

    1989-01-01

    The objectives and significance of integrated and organic farming are briefly discussed. In wheat production, the cropping methods involved are then described and compared to those of a conventional system. Initial results from an experimental farm at Nagele, The Netherlands, indicate that by an

  2. Organic lining materials test in flue gas ducts

    International Nuclear Information System (INIS)

    Raveh, R.; Sfez, D.; Johannsson, L.

    1998-01-01

    Corrosion protection solutions are being widely used in electric power plants equipped with Flue Gas Desulfurization (FGD) systems. Organic lining materials are one of many solutions available on the market for corrosion protection. This market segment is found in a continuous development in order to fulfill the severe demands of these materials. The main goal of this test is to obtain information about the high temperature resistance of the materials as occurs when the FGD system is by-passed. Aster initial investigation of this market segment only a few lining materials were found compatible according to their manufacturer data. Seven of these materials were installed in the outlet flue gas duct of the Israeli power station M.D. B. This power station is not equipped with a FGD system, thus it gives a real simulation of the environmental conditions into which the lining material is subjected when the FGD system is by-passed. The materials installation was observed carefully and performed by representatives from the manufacturers in order to avoid material failure due to a non-adequate application. The power station was shut down and the lining materials were inspected three and a half months after the lining materials were applied. The inspection results were good and besides changes in the lining color, most materials did not show any damages. During that time the flue gas temperature at the duct was 134?C except some temperature fluctuations

  3. Performance of an electrothermal swing adsorption system with postdesorption liquefaction for organic gas capture and recovery.

    Science.gov (United States)

    Mallouk, Kaitlin E; Rood, Mark J

    2013-07-02

    The use of adsorption on activated carbon fiber cloth (ACFC) followed by electrothermal swing adsorption (ESA) and postdesorption pressure and temperature control allows organic gases with boiling points below 0 °C to be captured from air streams and recovered as liquids. This technology has the potential to be a more sustainable abatement technique when compared to thermal oxidation. In this paper, we determine the process performance and energy requirements of a gas recovery system (GRS) using ACFC-ESA for three adsorbates with relative pressures between 8.3 × 10(-5) and 3.4 × 10(-3) and boiling points as low as -26.3 °C. The GRS is able to capture > 99% of the organic gas from the feed air stream, which is comparable to destruction efficiencies for thermal oxidizers. The energy used per liquid mole recovered ranges from 920 to 52,000 kJ/mol and is a function of relative pressure of the adsorbate in the feed gas. Quantifying the performance of the bench-scale gas recovery system in terms of its ability to remove organic gases from the adsorption stream and the energy required to liquefy the recovered organic gases is a critical step in developing new technologies to allow manufacturing to occur in a more sustainable manner. To our knowledge, this is the first time an ACFC-ESA system has been used to capture, recover, and liquefy organic compounds with vapor pressures as low as 8.3 × 10(-5) and the first time such a system has been analyzed for process performance and energy consumption.

  4. Integration optimisation of elevated pressure air separation unit with gas turbine in an IGCC power plant

    International Nuclear Information System (INIS)

    Han, Long; Deng, Guangyi; Li, Zheng; Wang, Qinhui; Ileleji, Klein E.

    2017-01-01

    Highlights: • IGCC thermodynamic model was setup carefully. • Simulations focus on integration between an elevated pressure ASU with gas turbine. • Different recommended solutions from those of low pressure ASUs are figured out. • Full N 2 injection and 80% air extraction was suggested as the optimum integration. - Abstract: The integration optimisation between an elevated pressure air separation unit (EP-ASU) and gas turbine is beneficial to promote net efficiency of an integrated gasification combined cycle (IGCC) power plant. This study sets up the thermodynamic model for a 400 MW plant specially coupled with an EP-ASU, aiming to examine system performances under different integrations and acquire the optimum solution. Influences of air extraction rate at conditions of without, partial and full N 2 injection, as well as the effects of N 2 injection rate when adopting separate ASU, partial and full integrated ASU were both analysed. Special attention has been paid to performance differences between utilising an EP-ASU and a low pressure unit. Results indicated that integration solution with a separate EP-ASU or without N 2 injection would not be reasonable. Among various recommended solutions for different integration conditions, N 2 injection rate increased with the growth of air extraction rate. The integration with an air extraction rate of 80% and full N 2 injection was suggested as the optimum solution. It is concluded that the optimum integration solution when adopting an EP-ASU is different from that using a low pressure one.

  5. Business Case for Integrated Reporting in the Nigerian Oil and Gas Sector

    Directory of Open Access Journals (Sweden)

    Tajudeen J. AYOOLA

    2013-03-01

    were sourced from the annual reports and stand-alone sustainability reports of the six multinational companies operating in the Nigerian oil and gas sector. The results found that efforts to address environmental, social and governance reporting (ESG were adhoc, short term and unrelated to the core activities of the corporations and as such were not integrated into their business strategies and model. Information on ESG was also duplicated over many medium in a haphazard and distorted form. The study therefore concluded that the introduction of integrated reporting will streamline performance reporting that is in line with international best practice in the sector.

  6. Metal-organic frameworks in mixed-matrix membranes for gas separation.

    Science.gov (United States)

    Tanh Jeazet, Harold B; Staudt, Claudia; Janiak, Christoph

    2012-12-14

    Mixed-matrix membranes (MMMs) with metal-organic frameworks (MOFs) as additives (fillers) exhibit enhanced gas permeabilities and possibly also selectivities when compared to the pure polymer. Polyimides (Matrimid®) and polysulfones are popular polymer matrices for MOF fillers. Presently investigated MOFs for MMMs include [Cu(SiF(6))(4,4'-BIPY)(2)], [Cu(3)(BTC)(2)(H(2)O)(3)] (HKUST-1, Cu-BTC), [Cu(BDC)(DMF)], [Zn(4)O(BDC)(3)] (MOF-5), [Zn(2-methylimidazolate)(2)] (ZIF-8), [Zn(purinate)(2)] (ZIF-20), [Zn(2-carboxyaldehyde imidazolate)(2)] (ZIF-90), Mn(HCOO)(2), [Al(BDC)(μ-OH)] (MIL-53(Al)), [Al(NH(2)-BDC)(μ-OH)] (NH(2)-MIL-53(Al)) and [Cr(3)O(BDC)(3)(F,OH)(H(2)O)(2)] (MIL-101) (4,4'-BIPY = 4,4'-bipyridine, BTC = benzene-1,3,5-tricarboxylate, BDC = benzene-1,4-dicarboxylate, terephthalate). MOF particle adhesion to polyimide and polysulfone organic polymers does not represent a problem. MOF-polymer MMMs are investigated for the permeability of the single gases H(2), N(2), O(2), CH(4), CO(2) and of the gas mixtures O(2)/N(2), H(2)/CH(4), CO(2)/CH(4), H(2)/CO(2), CH(4)/N(2) and CO(2)/N(2) (preferentially permeating gas named first). Permeability increases can be traced to the MOF porosity. Since the porosity of MOFs can be tuned very precisely, which is not possible with polymeric material, MMMs offer the opportunity of significantly increasing the selectivity compared to the pure polymeric matrix. Additionally in most of the cases the permeability is increased for MMM membranes compared to the pure polymer. Addition of MOFs to polymers in MMMs easily yields performances similar to the best polymer membranes and gives higher selectivities than those reported to date for any pure MOF membrane for the same gas separation. MOF-polymer MMMs allow for easier synthesis and handability compared to pure MOF membranes.

  7. Integration of Organic Light Emitting Diodes and Organic Photodetectors for Lab-on-a-Chip Bio-Detection Systems

    Directory of Open Access Journals (Sweden)

    Graeme Williams

    2014-02-01

    Full Text Available The rapid development of microfluidics and lab-on-a-chip (LoC technologies have allowed for the efficient separation and manipulation of various biomaterials, including many diagnostically relevant species. Organic electronics have similarly enjoyed a great deal of research, resulting in tiny, highly efficient, wavelength-selective organic light-emitting diodes (OLEDs and organic photodetectors (OPDs. We consider the blend of these technologies for rapid detection and diagnosis of biological species. In the ideal system, optically active or fluorescently labelled biological species can be probed via light emission from OLEDs, and their subsequent light emission can be detected with OPDs. The relatively low cost and simple fabrication of the organic electronic devices suggests the possibility of disposable test arrays. Further, with full integration, the finalized system can be miniaturized and made simple to use. In this review, we consider the design constraints of OLEDs and OPDs required to achieve fully organic electronic optical bio-detection systems. Current approaches to integrated LoC optical sensing are first discussed. Fully realized OLED- and OPD-specific photoluminescence detection systems from literature are then examined, with a specific focus on their ultimate limits of detection. The review highlights the enormous potential in OLEDs and OPDs for integrated optical sensing, and notes the key avenues of research for cheap and powerful LoC bio-detection systems.

  8. On the integrability of a Hamiltonian reduction of a 2+1-dimensional non-isothermal rotating gas cloud system

    International Nuclear Information System (INIS)

    Rogers, C; Schief, W K

    2011-01-01

    A 2+1-dimensional version of a non-isothermal gas dynamic system with origins in the work of Ovsiannikov and Dyson on spinning gas clouds is shown to admit a Hamiltonian reduction which is completely integrable when the adiabatic index γ = 2. This nonlinear dynamical subsystem is obtained via an elliptic vortex ansatz which is intimately related to the construction of a Lax pair in the integrable case. The general solution of the gas dynamic system is derived in terms of Weierstrass (elliptic) functions. The latter derivation makes use of a connection with a stationary nonlinear Schrödinger equation and a Steen–Ermakov–Pinney equation, the superposition principle of which is based on the classical Lamé equation

  9. Applications of covalent organic frameworks (COFs): From gas storage and separation to drug delivery

    Institute of Scientific and Technical Information of China (English)

    Ming-Xue Wu; Ying-Wei Yang

    2017-01-01

    Covalent organic frameworks (COFs) are an emerging class of porous covalent organic structures whose backbones were composed of light elements (B,C,N,O,Si) and linked by robust covalent bonds to endow such material with desirable properties,i.e.,inherent porosity,well-defined pore aperture,ordered channel structure,large surface area,high stability,and multi-dimension.As expected,the abovementioned properties of COFs broaden the applications of this class of materials in various fields such as gas storage and separation,catalysis,optoelectronics,sensing,small molecules adsorption,and drug delivery.In this review,we outlined the synthesis of COFs and highlighted their applications ranging from the initial gas storage and separation to drug delivery.

  10. Organic and inorganic composition and microbiology of produced waters from Pennsylvania shale gas wells

    Science.gov (United States)

    Akob, Denise M.; Cozzarelli, Isabelle M.; Dunlap, Darren S.; Rowan, Elisabeth L.; Lorah, Michelle M.

    2015-01-01

    Hydraulically fractured shales are becoming an increasingly important source of natural gas production in the United States. This process has been known to create up to 420 gallons of produced water (PW) per day, but the volume varies depending on the formation, and the characteristics of individual hydraulic fracture. PW from hydraulic fracturing of shales are comprised of injected fracturing fluids and natural formation waters in proportions that change over time. Across the state of Pennsylvania, shale gas production is booming; therefore, it is important to assess the variability in PW chemistry and microbiology across this geographical span. We quantified the inorganic and organic chemical composition and microbial communities in PW samples from 13 shale gas wells in north central Pennsylvania. Microbial abundance was generally low (66–9400 cells/mL). Non-volatile dissolved organic carbon (NVDOC) was high (7–31 mg/L) relative to typical shallow groundwater, and the presence of organic acid anions (e.g., acetate, formate, and pyruvate) indicated microbial activity. Volatile organic compounds (VOCs) were detected in four samples (∼1 to 11.7 μg/L): benzene and toluene in the Burket sample, toluene in two Marcellus samples, and tetrachloroethylene (PCE) in one Marcellus sample. VOCs can be either naturally occurring or from industrial activity, making the source of VOCs unclear. Despite the addition of biocides during hydraulic fracturing, H2S-producing, fermenting, and methanogenic bacteria were cultured from PW samples. The presence of culturable bacteria was not associated with salinity or location; although organic compound concentrations and time in production were correlated with microbial activity. Interestingly, we found that unlike the inorganic chemistry, PW organic chemistry and microbial viability were highly variable across the 13 wells sampled, which can have important implications for the reuse and handling of these fluids

  11. 77 FR 34123 - Pipeline Safety: Public Meeting on Integrity Management of Gas Distribution Pipelines

    Science.gov (United States)

    2012-06-08

    ... DEPARTMENT OF TRANSPORTATION Pipeline and Hazardous Materials Safety Administration [Docket No. PHMSA-2012-0100] Pipeline Safety: Public Meeting on Integrity Management of Gas Distribution Pipelines AGENCY: Office of Pipeline Safety, Pipeline and Hazardous Materials Safety Administration, DOT. ACTION...

  12. Organic light emitting diodes (OLEDS) and OLED-based structurally integrated optical sensors

    Energy Technology Data Exchange (ETDEWEB)

    Cai, Yuankun [Iowa State Univ., Ames, IA (United States)

    2010-01-01

    General introduction to OLED basics and OLED-based structurally integrated sensors was provided in chapter 1 and chapter 2. As discussed in chapter 3, OLEDs were developed or improved using novel engineering methods for better charge injection (increased by over 1 order of magnitude) and efficiency. As the excitation sources, these OLEDs have preferred characteristics for sensor applications, including narrowed emission, emission at desired wavelength, and enhanced output for reduced EL background, higher absorption and improved device lifetime. In addition to OLEDs with desired performance, sensor integration requires oxidase immobilization with the sensor film for O2-based biological and chemical sensing. Nanoparticles such as ZnO have large surface area and high isoelectric point (~9.5), which favors enzyme immobilization via physical adsorption as well as Coulombic bonding. In chapter 4, it was demonstrated that ZnO could be used for this purpose, although future work is needed to further bond the ZnO to the sensor film. In chapter 5, single unit sensor was extended to multianalyte parallel sensing based on an OLED platform, which is compact and integrated with silicon photodiodes and electronics. Lactate and glucose were simultaneously monitored with a low limit of detection 0.02 mM, fast response time (~1 minute) and dynamic range from 0-8.6 ppm of dissolved oxygen. As discovered in previous work, the dynamic range covers 0-100% gas phase O2 or 0-40 ppm dissolved oxygen at room temperature. PL decay curve, which is used to extract the decay time, is usually not a simple exponential at high O2 concentration, which indicates that O2 is not equally accessible for different luminescent sites. This creates a challenge for data analysis, which however was successfully processed by stretched exponential as shown in chapter 6. This also provides an insight about the distribution of O2:dye collisional quenching

  13. Organic light emitting diodes (OLEDS) and OLED-based structurally integrated optical sensors

    International Nuclear Information System (INIS)

    Cai, Yuankun

    2010-01-01

    General introduction to OLED basics and OLED-based structurally integrated sensors was provided in chapter 1 and chapter 2. As discussed in chapter 3, OLEDs were developed or improved using novel engineering methods for better charge injection (increased by over 1 order of magnitude) and efficiency. As the excitation sources, these OLEDs have preferred characteristics for sensor applications, including narrowed emission, emission at desired wavelength, and enhanced output for reduced EL background, higher absorption and improved device lifetime. In addition to OLEDs with desired performance, sensor integration requires oxidase immobilization with the sensor film for O 2 -based biological and chemical sensing. Nanoparticles such as ZnO have large surface area and high isoelectric point (∼9.5), which favors enzyme immobilization via physical adsorption as well as Coulombic bonding. In chapter 4, it was demonstrated that ZnO could be used for this purpose, although future work is needed to further bond the ZnO to the sensor film. In chapter 5, single unit sensor was extended to multianalyte parallel sensing based on an OLED platform, which is compact and integrated with silicon photodiodes and electronics. Lactate and glucose were simultaneously monitored with a low limit of detection 0.02 mM, fast response time (∼ 1 minute) and dynamic range from 0-8.6 ppm of dissolved oxygen. As discovered in previous work, the dynamic range covers 0-100% gas phase O 2 or 0-40 ppm dissolved oxygen at room temperature. PL decay curve, which is used to extract the decay time, is usually not a simple exponential at high O 2 concentration, which indicates that O 2 is not equally accessible for different luminescent sites. This creates a challenge for data analysis, which however was successfully processed by stretched exponential as shown in chapter 6. This also provides an insight about the distribution of O 2 :dye collisional quenching rate due to microheterogeneity. Effect of Ti

  14. A purification process for an inert gas system

    International Nuclear Information System (INIS)

    Raj, S.S.; Samanta, S.K.; Jain, N.G.; Deshingkar, D.S.; Ramaswamy, M.

    1984-01-01

    Special inert atmosphere is desired inside hot cells used for handling radioactive materials. In this report, details of experiments conducted to generate data required for the design of a system for maintaining very low levels of organic and acid vapours, oxygen and moisture in a nitrogen gas inert atmosphere, are described. Several grades of activated charcoals impregnated with 1% KOH were studied for the adsorption of acidic and organic vapours. A Pd/Al 2 O 3 catalyst was developed to remove oxygen with greater than 90% efficiency. For the removal of moisture, a regenerable molecular sieve 4A dual-bed was provided. Based on the performance data thus generated, an integrated purification system for nitrogen gas is proposed. (author)

  15. Effect of organic-matter type and thermal maturity on methane adsorption in shale-gas systems

    Science.gov (United States)

    Zhang, Tongwei; Ellis, Geoffrey S.; Ruppel, Stephen C.; Milliken, Kitty; Yang, Rongsheng

    2012-01-01

    A series of methane (CH4) adsorption experiments on bulk organic rich shales and their isolated kerogens were conducted at 35 °C, 50 °C and 65 °C and CH4 pressure of up to 15 MPa under dry conditions. Samples from the Eocene Green River Formation, Devonian–Mississippian Woodford Shale and Upper Cretaceous Cameo coal were studied to examine how differences in organic matter type affect natural gas adsorption. Vitrinite reflectance values of these samples ranged from 0.56–0.58 %Ro. In addition, thermal maturity effects were determined on three Mississippian Barnett Shale samples with measured vitrinite reflectance values of 0.58, 0.81 and 2.01 %Ro. For all bulk and isolated kerogen samples, the total amount of methane adsorbed was directly proportional to the total organic carbon (TOC) content of the sample and the average maximum amount of gas sorption was 1.36 mmol of methane per gram of TOC. These results indicate that sorption on organic matter plays a critical role in shale-gas storage. Under the experimental conditions, differences in thermal maturity showed no significant effect on the total amount of gas sorbed. Experimental sorption isotherms could be fitted with good accuracy by the Langmuir function by adjusting the Langmuir pressure (PL) and maximum sorption capacity (Γmax). The lowest maturity sample (%Ro = 0.56) displayed a Langmuir pressure (PL) of 5.15 MPa, significantly larger than the 2.33 MPa observed for the highest maturity (%Ro > 2.01) sample at 50 °C. The value of the Langmuir pressure (PL) changes with kerogen type in the following sequence: type I > type II > type III. The thermodynamic parameters of CH4 adsorption on organic rich shales were determined based on the experimental CH4 isotherms. For the adsorption of CH4 on organic rich shales and their isolated kerogen, the heat of adsorption (q) and the standard entropy (Δs0) range from 7.3–28.0 kJ/mol and from −36.2 to −92.2 J/mol/K, respectively.

  16. Integrated organic electronic based optochemical sensors using polarization filters

    International Nuclear Information System (INIS)

    Kraker, Elke; Haase, Anja; Lamprecht, Bernhard; Jakopic, Georg; Konrad, Christian; Koestler, Stefan

    2008-01-01

    A compact, integrated photoluminescence based oxygen and pH sensor, utilizing an organic light emitting device (OLED) as the light source and an organic photodiode (OPD) as the detection unit, is described. The main challenge in such an integrated sensor is the suppression of the excitation light at the detector, which is typically by many orders of magnitude higher in intensity than the emitted fluorescence. In our approach, we refrain from utilizing edge filters which require narrow band excitation sources and dyes with an adequate large Stokes shift. We rather developed an integrated sensor concept relying on two polarizers to separate the emission and excitation light. One polarizer is located right after the OLED, while the other one, oriented at 90 deg. to the first, is placed in front of the OPD. The main advantage of this solution is that any combination of excitation and emission light is acceptable, even if the two signals overlap spectrally. This is especially important for the use of OLEDs as the excitation sources, as these devices typically exhibit a broad spectral emission

  17. Natural gas potential in Canada

    International Nuclear Information System (INIS)

    1997-01-01

    An independent assessment of the undiscovered gas potential in Canada was conducted by a group of volunteer geoscientists. This report is the first of a series of assessments that are planned to be issued every three to four years. Separate assessments were made of conventional gas resources, unconventional gas resources and frontier gas resources. The assessment for conventional gas resources was organized into three categories: (1) gas producing areas where new discoveries can be integrated into existing producing and transportation infrastructure, (2) frontier basins where gas discoveries have been made, but no production is currently underway, and (3) frontier areas where gas-containing sedimentary rocks are known to exist, but where no gas discoveries have been made to date. The committee used year-end 1993 reserves data from discovered pools in each exploration play to predict the undiscovered potential. Information about discovered pools, geological setting, geographic limits and pool sizes of undiscovered pools in each exploration play was provided. Results of the investigation led to the conclusion that the natural gas potential in Canada is in fact larger than hitherto expected. It was estimated that in the Western Canada Sedimentary Basin 47 per cent of the total volume of conventional gas is yet to be discovered. 152 figs

  18. Integration of biohydrogen fermentation and gas separation processes to recover and enrich hydrogen

    Czech Academy of Sciences Publication Activity Database

    Bélafi-Bakó, K.; Búcsú, D.; Pientka, Zbyněk; Bálint, B.; Herbel, Z.; Kovács, K. L.; Wessling, M.

    2006-01-01

    Roč. 31, č. 11 (2006), s. 1490-1495 ISSN 0360-3199 R&D Projects: GA ČR GA203/06/1207 Institutional research plan: CEZ:AV0Z40500505 Keywords : integrated system * gas separation * polymer membranes Subject RIV: CD - Macromolecular Chemistry Impact factor: 2.612, year: 2006

  19. Integrated energy, air quality and greenhouse gas management plan

    International Nuclear Information System (INIS)

    2004-03-01

    This report outlines the measures that the Resort Municipality of Whistler has taken to become a sustainable community. In 2000, the Municipality adopted the Natural Step, a tool developed by international scientists to integrate ecological principles into the practices of communities, organizations and individuals. In 2001, the Municipality adopted a comprehensive sustainability plan. This report describes the efforts to manage energy, air quality, and greenhouse gases (GHG). More than 90 per cent of the common air contaminants that contribute to air quality problems in Whistler come from the combustion of fossil fuels. The community can reduce emissions of carbon monoxide, oxides of nitrogen, oxides of sulphur, volatile organic compounds, and particulate matter by managing energy and GHG emissions. This report is divided into several sections dealing with corporate and community energy use. It presents a community profile for Whistler, its energy and emissions inventory from 2000, and an integrated energy plan. An energy and emissions forecast for 2000 to 2020 was also included along with an implementation strategy for a sustainable energy future for Whistler. refs., tabs., figs

  20. Capture of elemental and organic iodine from dilute gas streams by silver-exchanged mordenite

    Energy Technology Data Exchange (ETDEWEB)

    Bruffey, S.H.; Jubin, R.T.; Jordan, J.A. [Oak Ridge National Laboratory, 1 Bethel Valley Road, Oak Ridge, TN 37831 (United States)

    2016-07-01

    The treatment of off-gas streams arising from reprocessing of used nuclear fuel (UNF) is an area of active study by the U.S. Department of Energy. Such off-gas streams contain volatile fission products, including long-lived {sup 129}I. Although {sup 129}I is released into the off-gas at multiple points within the chemical reprocessing flowsheet, previous research has focused on removal from the dissolver off-gas stream (DOG). The DOG is expected to contain up to 98% of iodine in UNF at ppm levels within the stream. Other off-gas streams will also contain iodine but at substantially lower concentrations. Recent work has shown that compliance with U.S. regulations will likely require capture of iodine from these dilute streams in addition to capture from DOG. In particular, the vessel off-gas (VOG) stream is expected to contain 1-3% of the total iodine inventory at ppb concentrations. A review of literature also indicates that the speciation of iodine in the VOG stream will differ from that of the DOG, with the DOG containing primarily I{sub 2} and the VOG containing a mixture of I{sub 2} and organic iodine species. Silver-exchanged mordenite (AgZ) has been identified for use in the removal of iodine from off-gas streams. It is an effective capture material for I{sub 2} at the concentrations expected in the DOG, but little is known about its performance in gas streams that may contain both I{sub 2} and organic iodides at very dilute concentrations. The experiments to be described were designed to separately characterize the adsorption of I{sub 2} and methyl iodide on AgZ through extended duration testing. Simulated vessel off-gases containing low levels of either I{sub 2} or methyl iodide were contacted with AgZ sorbent beds for up to four months. Through the use of sorbent beds in series and varied sampling times, key parameters such as adsorption rate, decontamination factor, and performance over time could be determined for the capture of each species by AgZ. This

  1. Metallurgy of gas turbine blades with integral shroud and its influence on blades performance

    International Nuclear Information System (INIS)

    Mazur, Z.; Marino, C.; Kubiak, J.

    1999-01-01

    The influence of the microstructure of the gas turbine blades with integral shroud on the blades performance is presented. The analysis of the solidification process of the gas turbine blades during conventionally casting process (equiaxed grains) with all elements which has influence on the mode of its solidification and variation of the microstructure is carried out. Also, the evaluation of the failure of the gas turbine blade is present. A detailed analysis of the blade tip shroud microstructure (presence of the equiaxed and columnar grains) and its influence on the failure initiation and propagation is carried out. Finally, conclusions and some necessary improvements of the blades casting process to prevent blades failures are presented. (Author) 2 refs

  2. Gas sorption properties of microporous metal organic frameworks

    International Nuclear Information System (INIS)

    Lee, JeongYong; Li Jing; Jagiello, Jacek

    2005-01-01

    A low-temperature gas sorption study has been carried out on four three-dimensional microporous metal organic framework (MMOF) structures and two two-dimensional layered structures. The pore characteristics are analyzed based on the argon adsorption-desorption isotherms at 87 K. The results from hydrogen sorption experiments conducted at 77 and 87 K show that all MMOFs have a relatively high hydrogen uptake, with adsorbed hydrogen densities falling in the range of liquid hydrogen. Isosteric heats of hydrogen adsorption data calculated based on the Clausius-Clapeyron equation are consistent with these observations, indicating strong sorbent-sorbate interactions. - Graphical abstract: Hydrogen adsorption isotherms measured at 77 and 87 K

  3. Transformative Learning Factors to Enhance Integral Healthy Organizations

    Science.gov (United States)

    Thavinpipatkul, Chanchai; Ratana-Ubol, Archanya; Charungkaittikul, Suwithida

    2016-01-01

    This article focuses on how organizations search for the key factors to develop integral changes and determine broader and higher transcendental learning skills in order to achieve healthy and sustainable organizational growth more effectively and efficiently. This study employed qualitative approaches. The research method used is an in-depth…

  4. Integrated transport code system for a multicomponent plasma in a gas dynamic trap

    International Nuclear Information System (INIS)

    Anikeev, A.V.; Karpushov, A.N.; Noak, K.; Strogalova, S.L.

    2000-01-01

    This report is focused on the development of the theoretical and numerical models of multicomponent high-β plasma confinement and transport in the gas-dynamic trap (GDT). In order to simulate the plasma behavior in the GDT as well as that in the GDT-based neutron source the Integrated Transport Code System is developed from existing stand-alone codes calculating the target plasma, the fast ions and the neutral gas in the GDT. The code system considers the full dependence of the transport phenomena on space, time, energy and angle variables as well as the interactions between the particle fields [ru

  5. Organochlorine pesticide residues in strawberries from integrated pest management and organic farming.

    Science.gov (United States)

    Fernandes, Virginia C; Domingues, Valentina F; Mateus, Nuno; Delerue-Matos, Cristina

    2011-07-27

    A rapid, specific, and sensitive method based on the Quick Easy Cheap Effective Rugged and Safe (QuEChERS) method and a cleanup using dispersive solid-phase extraction with MgSO(4), PSA, and C18 sorbents has been developed for the routine analysis of 14 pesticides in strawberries. The analyses were performed by three different analytical methodologies: gas chromatography (GC) with electron capture detection (ECD), mass spectrometry (MS), and tandem mass spectrometry (MS/MS). The recoveries for all the pesticides studied were from 46 to 128%, with relative standard deviation of residue limits (MRL) accepted in Portugal for organochlorine pesticides (OCP). A survey study of strawberries produced in Portugal in the years 2009-2010 obtained from organic farming (OF) and integrated pest management (IPM) was developed. Lindane and β-endosulfan were detected above the MRL in OF and IPM. Other OCP (aldrin, o,p'-DDT and their metabolites, and methoxychlor) were found below the MRL. The OCP residues detected decreased from 2009 to 2010. The QuEChERS method was successfully applied to the analysis of strawberry samples.

  6. THE IMPORTANCE OF THE IMPLEMENTATION OF INTEGRATED INFORMATION SYSTEMS IN THE RESTRUCTURING AND EUROPEAN INTEGRATION PROCESS OF ORGANIZATIONS

    Directory of Open Access Journals (Sweden)

    Steliac Nela

    2010-12-01

    Full Text Available Many of the organizations that are part of the public and private domain in Romania have reached the stage in which the existing information systems can no longer comply with the requests of users. Therefore, we are compelled by necessity to use integrated information systems which should be able to control all kinds of data and to allow access to them, to ensure the coherence and consistency of the stored information. Managers must be aware of the importance of the implementation of integrated information systems in the background restructuring of the organization, which can thus become consistent and competitive with the European Union one, so the integration process becomes a real and possible one.

  7. The Contribution of Network Organization and Integration to the Development of Cognitive Control.

    Science.gov (United States)

    Marek, Scott; Hwang, Kai; Foran, William; Hallquist, Michael N; Luna, Beatriz

    2015-12-01

    Cognitive control, which continues to mature throughout adolescence, is supported by the ability for well-defined organized brain networks to flexibly integrate information. However, the development of intrinsic brain network organization and its relationship to observed improvements in cognitive control are not well understood. In the present study, we used resting state functional magnetic resonance imaging (RS-fMRI), graph theory, the antisaccade task, and rigorous head motion control to characterize and relate developmental changes in network organization, connectivity strength, and integration to inhibitory control development. Subjects were 192 10-26-y-olds who were imaged during 5 min of rest. In contrast to initial studies, our results indicate that network organization is stable throughout adolescence. However, cross-network integration, predominantly of the cingulo-opercular/salience network, increased with age. Importantly, this increased integration of the cingulo-opercular/salience network significantly moderated the robust effect of age on the latency to initiate a correct inhibitory control response. These results provide compelling evidence that the transition to adult-level inhibitory control is dependent upon the refinement and strengthening of integration between specialized networks. Our findings support a novel, two-stage model of neural development, in which networks stabilize prior to adolescence and subsequently increase their integration to support the cross-domain incorporation of information processing critical for mature cognitive control.

  8. The Contribution of Network Organization and Integration to the Development of Cognitive Control

    Science.gov (United States)

    Marek, Scott; Hwang, Kai; Foran, William; Hallquist, Michael N.; Luna, Beatriz

    2015-01-01

    Abstract Cognitive control, which continues to mature throughout adolescence, is supported by the ability for well-defined organized brain networks to flexibly integrate information. However, the development of intrinsic brain network organization and its relationship to observed improvements in cognitive control are not well understood. In the present study, we used resting state functional magnetic resonance imaging (RS-fMRI), graph theory, the antisaccade task, and rigorous head motion control to characterize and relate developmental changes in network organization, connectivity strength, and integration to inhibitory control development. Subjects were 192 10–26-y-olds who were imaged during 5 min of rest. In contrast to initial studies, our results indicate that network organization is stable throughout adolescence. However, cross-network integration, predominantly of the cingulo-opercular/salience network, increased with age. Importantly, this increased integration of the cingulo-opercular/salience network significantly moderated the robust effect of age on the latency to initiate a correct inhibitory control response. These results provide compelling evidence that the transition to adult-level inhibitory control is dependent upon the refinement and strengthening of integration between specialized networks. Our findings support a novel, two-stage model of neural development, in which networks stabilize prior to adolescence and subsequently increase their integration to support the cross-domain incorporation of information processing critical for mature cognitive control. PMID:26713863

  9. The Contribution of Network Organization and Integration to the Development of Cognitive Control.

    Directory of Open Access Journals (Sweden)

    Scott Marek

    2015-12-01

    Full Text Available Cognitive control, which continues to mature throughout adolescence, is supported by the ability for well-defined organized brain networks to flexibly integrate information. However, the development of intrinsic brain network organization and its relationship to observed improvements in cognitive control are not well understood. In the present study, we used resting state functional magnetic resonance imaging (RS-fMRI, graph theory, the antisaccade task, and rigorous head motion control to characterize and relate developmental changes in network organization, connectivity strength, and integration to inhibitory control development. Subjects were 192 10-26-y-olds who were imaged during 5 min of rest. In contrast to initial studies, our results indicate that network organization is stable throughout adolescence. However, cross-network integration, predominantly of the cingulo-opercular/salience network, increased with age. Importantly, this increased integration of the cingulo-opercular/salience network significantly moderated the robust effect of age on the latency to initiate a correct inhibitory control response. These results provide compelling evidence that the transition to adult-level inhibitory control is dependent upon the refinement and strengthening of integration between specialized networks. Our findings support a novel, two-stage model of neural development, in which networks stabilize prior to adolescence and subsequently increase their integration to support the cross-domain incorporation of information processing critical for mature cognitive control.

  10. Microbial Electrolysis Cells for High Yield Hydrogen Gas Production from Organic Matter

    NARCIS (Netherlands)

    Logan, B.E.; Call, D.; Cheng, S.; Hamelers, H.V.M.; Sleutels, T.H.J.A.; Jeremiasse, A.W.; Rozendal, R.A.

    2008-01-01

    The use of electrochemically active bacteria to break down organic matter, combined with the addition of a small voltage (>0.2 V in practice) in specially designed microbial electrolysis cells (MECs), can result in a high yield of hydrogen gas. While microbial electrolysis was invented only a few

  11. Multi-objective optimization of a pressurized solid oxide fuel cell – gas turbine hybrid system integrated with seawater reverse osmosis

    International Nuclear Information System (INIS)

    Eveloy, Valerie; Rodgers, Peter; Al Alili, Ali

    2017-01-01

    To improve the capacity and efficiency of distributed power and fresh water generation in coastal industrial facilities affected by regional water scarcity, a natural gas-fueled, pressurized solid oxide fuel cell-gas turbine (SOFC-GT) hybrid is integrated with a bottoming organic Rankine cycle (ORC) and seawater reverse osmosis (RO) desalination plant. This power and water co-generation system is optimized in terms of two objectives, maximum exergy efficiency and minimum cost rate, using a genetic algorithm. The exergetic and economic performance of three solutions representing maximum exergy efficiency, minimum cost rate, and a compromise between efficiency and cost rate, are compared. When imposing a water production requirement (reference case), the selected compromise multi-objective optimization solution delivers a net power output of 2.4 MWe and 636 m"3/day of permeate, at a co-generation exergy efficiency and cost rate of 71.3% and 0.0256 USD/s, respectively. The system payback time is estimated to be less than six years for typical economic parameters, but would become unprofitable in the most unfavorable economic scenario considered. Overall, the results indicate the thermodynamic and economic benefits of reverse osmosis over thermal desalination processes for integration with high-efficiency power generation systems in coastal regions impacted by domestic gas shortages and water scarcity. - Highlights: • Integration of a pressurized SOFC-GT hybrid system with a reverse osmosis unit. • Multi-objective, exergetic and economic optimization using a genetic algorithm. • Optimum solution delivers 2.4 MWe and 636 m"3/day of desalinated water. • Overall exergy efficiency and cost rate of 71.3% and 0.0256 USD/s, respectively. • System payback time estimated at less than six years for typical economic conditions.

  12. Carbon Dioxide Removal from Flue Gas Using Microporous Metal Organic Frameworks

    Energy Technology Data Exchange (ETDEWEB)

    Lesch, David A

    2010-06-30

    UOP LLC, a Honeywell Company, in collaboration with Professor Douglas LeVan at Vanderbilt University (VU), Professor Adam Matzger at the University of Michigan (UM), Professor Randall Snurr at Northwestern University (NU), and Professor Stefano Brandani at the University of Edinburgh (UE), supported by Honeywell's Specialty Materials business unit and the Electric Power Research Institute (EPRI), have completed a three-year project to develop novel microporous metal organic frameworks (MOFs) and an associated vacuum-pressure swing adsorption (vPSA) process for the removal of CO{sub 2} from coal-fired power plant flue gas. The project leveraged the team's complementary capabilities: UOP's experience in materials development and manufacturing, adsorption process design and process commercialization; LeVan and Brandani's expertise in high-quality adsorption measurements; Matzger's experience in syntheis of MOFs and the organic components associated with MOFs; Snurr's expertise in molecular and other modeling; Honeywell's expertise in the manufacture of organic chemicals; and, EPRI's knowledge of power-generation technology and markets. The project was successful in that a selective CO{sub 2} adsorbent with good thermal stability and reasonable contaminant tolerance was discovered, and a low cost process for flue gas CO{sub 2} capture process ready to be evaluated further at the pilot scale was proposed. The team made significant progress toward the current DOE post-combustion research targets, as defined in a recent FOA issued by NETL: 90% CO{sub 2} removal with no more than a 35% increase in COE. The team discovered that favorable CO{sub 2} adsorption at more realistic flue gas conditions is dominated by one particular MOF structure type, M/DOBDC, where M designates Zn, Co, Ni, or Mg and DOBDC refers to the form of the organic linker in the resultant MOF structure, dioxybenzenedicarboxylate. The structure of the M/DOBDC MOFs

  13. Security management: a question of integration between people, systems and organizations

    International Nuclear Information System (INIS)

    Drukaroff, M. C.; Romano, A.

    2015-01-01

    Safety Management has always been the most important process of the Juzbado Factory since beginning of operations in 1985. this process has evolved, moving from focusing primary on preventive control of operation risks by means of adequate exploitation of Safety Systems, to integrating aspects related with Safety culture and Organization Factors, as key players in order to achieve sustainable safety improvements. This paper presents how Safety Management has evolved at the Factory, emphasizing especially on the integration process of the three main factors affecting safety: people, technology and organizations. (Author)

  14. The integration of gas and electricity: potential effects on competition in markets; La integracion vertical de los negocios de gas y electricidad: Posibles efectos sobre la competencia en los mercados afectados

    Energy Technology Data Exchange (ETDEWEB)

    Lopez Milla, J.

    2007-07-01

    During the last years, an increasing number of gas and electricity companies have integrated their activities in both sectors. Following this trend, several Mergers and Acquisitions between gas and electricity companies have emerged, and some of them have been cross-borders operations that have given rise to multinational enterprises. This paper analyses the causes of the integration of gas and electricity activities, and examines its implications on regulation and competition policy, showing that these changes in the energy industry raise new challenges and compel to adopt new measures in that field of the economic policy. (Author) 25 refs.

  15. Vertical integration of oil groups in gas downstream activities after the deregulation of gas and electricity industries: Determining factors and means of implementation of this strategy. Research report period: October 2000 - September 2003

    International Nuclear Information System (INIS)

    Benadjaoud, Nawel

    2003-12-01

    After a presentation of some characteristics of gas and electric power industries, and an overview of the process and consequences of the general trend of deregulation in these sectors, the author of this research proposes a contribution to the economic analysis of movements of vertical integration of large oil companies and groups in which downstream gas activities and power activities represent a small fraction of their activities. The objectives of this research were then to understand why oil companies are practising vertical integration on the gas sector, and how these oil companies proceed in terms of organisational means to perform this successful movement of vertical integration. The author addresses theoretical concepts as they are analysed in some theories of the firm. The studied questions are then addressed in the case of some major European oil companies through a detailed examination of all their operations related to the gas downstream activities and to electricity activities, and by examining the most used organisational modes for the implementation of such vertical integrations

  16. Concepts of intrinsic value and integrity of plants in organic plant breeding and propagation

    NARCIS (Netherlands)

    Lammerts Van Bueren, E.; Struik, P.C.; Tiemens-Hulscher, M.; Jacobsen, E.

    2003-01-01

    The natural approach taken by organic agriculture obviates the use of synthetic agrochemicals and emphasizes farming in accordance with agroecological principles. Also implicit in this approach is an appreciation for the integrity of living farm organisms, with the integrity being evaluated from a

  17. Monolithic photonic integration technology platform and devices at wavelengths beyond 2 μm for gas spectroscopy applications

    NARCIS (Netherlands)

    Latkowski, S.; van Veldhoven, P.J.; Hänsel, A.; D'Agostino, D.; Rabbani-Haghighi, H.; Docter, B.; Bhattacharya, N.; Thijs, P.J.A.; Ambrosius, H.P.M.M.; Smit, M.K.; Williams, K.A.; Bente, E.A.J.M.

    2017-01-01

    In this paper a generic monolithic photonic integration technology platform and tunable laser devices for gas sensing applications at 2 μm will be presented. The basic set of long wavelength optical functions which is fundamental for a generic photonic integration approach is realized using planar,

  18. Framework of Quality Assurance of TEL Integration into an Educational Organization

    Science.gov (United States)

    Volungeviciene, Airina; Tereseviciene, Margarita; Tait, Alan

    2014-01-01

    This research paper addresses the issues of integration of technology enhanced learning (TEL) into an educational organization. Good practice experience cannot be directly transferred to new organisations due to different contextual conditions. The TEL integration depends significantly upon a very rapid development of services and information…

  19. [Integrated health care organizations: guideline for analysis].

    Science.gov (United States)

    Vázquez Navarrete, M Luisa; Vargas Lorenzo, Ingrid; Farré Calpe, Joan; Terraza Núñez, Rebeca

    2005-01-01

    There has been a tendency recently to abandon competition and to introduce policies that promote collaboration between health providers as a means of improving the efficiency of the system and the continuity of care. A number of countries, most notably the United States, have experienced the integration of health care providers to cover the continuum of care of a defined population. Catalonia has witnessed the steady emergence of increasing numbers of integrated health organisations (IHO) but, unlike the United States, studies on health providers' integration are scarce. As part of a research project currently underway, a guide was developed to study Catalan IHOs, based on a classical literature review and the development of a theoretical framework. The guide proposes analysing the IHO's performance in relation to their final objectives of improving the efficiency and continuity of health care by an analysis of the integration type (based on key characteristics); external elements (existence of other suppliers, type of services' payment mechanisms); and internal elements (model of government, organization and management) that influence integration. Evaluation of the IHO's performance focuses on global strategies and results on coordination of care and efficiency. Two types of coordination are evaluated: information coordination and coordination of care management. Evaluation of the efficiency of the IHO refers to technical and allocative efficiency. This guide may have to be modified for use in the Catalan context.

  20. Weed species diversity in organic and integrated farming systems

    Directory of Open Access Journals (Sweden)

    Magdalena Jastrzębska

    2013-10-01

    Full Text Available Phytosociological data were collected in 1994–1996 in plots (relevés at the Research Station for Organic Farming and Conservation Breeding of the Polish Academy of Sciences in Popielno included in a large-area experiment conducted according to the concept and method proposed by Prof. S. Nawrocki. In a four-field crop rotation (root crops – spring barley undersown with red clover and grasses – red clover/grass mixture – winter triticale, each field was divided into two management units, organic and integrated. Data were collected in relevés by the Braun-Blanquet method, each year at the peak of the growing season. Weed abundance (% cover in cultivated fields and the number of weed species (species richness in crops were determined, which provided a basis for calculating the Shannon-Wiener indices of species diversity and evenness, and the Rényi profiles. The qualitative (species and quantitative structure of weed communities was compared using the Sørensen index. A total of 115 weed taxa (species, subspecies and varieties were identified in the examined agro-phytocenoses. Echinochloa crus-galli, Chenopodium album, Matricaria maritima subsp. inodora, Capsella bursa-pastoris, Thlaspi arvense and Stellaria media were the most abundant. Weed infestation was slightly higher in the organic farming system than in the integrated system. Organic farming contributed to higher weed species diversity in root crops, red clover/grass mixtures and winter triticale. Weed species richness was reduced in red clover/grass stands, while root crops and – to a lesser degree – spring barley undersown with red clover and grasses decreased weed species diversity. The species composition and in particular the quantitative structure of weeds were affected by crop species and cultivation regime rather than by the farming system. Weed communities of crops grown under organic and integrated farming systems were more similar with regard to species composition

  1. Subfornical organ neurons integrate cardiovascular and metabolic signals.

    Science.gov (United States)

    Cancelliere, Nicole M; Ferguson, Alastair V

    2017-02-01

    The subfornical organ (SFO) is a critical circumventricular organ involved in the control of cardiovascular and metabolic homeostasis. Despite the plethora of circulating signals continuously sensed by the SFO, studies investigating how these signals are integrated are lacking. In this study, we use patch-clamp techniques to investigate how the traditionally classified "cardiovascular" hormone ANG II, "metabolic" hormone CCK and "metabolic" signal glucose interact and are integrated in the SFO. Sequential bath application of CCK (10 nM) and ANG (10 nM) onto dissociated SFO neurons revealed that 63% of responsive SFO neurons depolarized to both CCK and ANG; 25% depolarized to ANG only; and 12% hyperpolarized to CCK only. We next investigated the effects of glucose by incubating and recording neurons in either hypoglycemic, normoglycemic, or hyperglycemic conditions and comparing the proportions of responses to ANG ( n = 55) or CCK ( n = 83) application in each condition. A hyperglycemic environment was associated with a larger proportion of depolarizing responses to ANG ( χ 2 , P neurons excited by CCK are also excited by ANG and that glucose environment affects the responsiveness of neurons to both of these hormones, highlighting the ability of SFO neurons to integrate multiple metabolic and cardiovascular signals. These findings have important implications for this structure's role in the control of various autonomic functions during hyperglycemia. Copyright © 2017 the American Physiological Society.

  2. When is vertical integration profitable? Focus on a large upstream company in the gas market

    International Nuclear Information System (INIS)

    Hatlebakk, Magnus

    2001-12-01

    This note discusses basic economic mechanisms that may affect the profitability of vertical integration in the European gas industry. It concentrates on reasonable strategies for a large upstream company which considers a stronger engagement downstream. The note warns against the effect of simplified conclusions with regard to the impact of vertical integration. It applies a simple model of successive oligopolies to discuss double mark-ups, exclusions, barriers to entry, etc

  3. Comparison of integration options for gasification-based biofuel production systems – Economic and greenhouse gas emission implications

    International Nuclear Information System (INIS)

    Holmgren, Kristina M.; Berntsson, Thore S.; Andersson, Eva; Rydberg, Tomas

    2016-01-01

    The impact of different integration options for gasification-based biofuel production systems producing synthetic natural gas, methanol and FT (Fischer-Tropsch) fuels on the NAP (net annual profit), FPC (fuel production cost) and the GHG (greenhouse gas) emission reduction potential are analysed. The considered integration options are heat deliveries to DH (district heating) systems or to nearby industries and integration with infrastructure for CO_2 storage. The comparison is made to stand-alone configurations in which the excess heat is used for power production. The analysis considers future energy market scenarios and case studies in southwestern Sweden. The results show that integration with DH systems has small impacts on the NAP and the FPC and diverging (positive or negative) impacts on the GHG emissions. Integration with industries has positive effects on the economic and GHG performances in all scenarios. The FPCs are reduced by 7–8% in the methanol case and by 12–13% in the FT production case. The GHG emission reductions are strongly dependent on the reference power production. The storage of separated CO_2 shows an increase in the GHG emission reduction potential of 70–100% for all systems, whereas the impacts on the economic performances are strongly dependent on the CO_2_e-charge. - Highlights: • Three gasification-based biofuel production systems at case study sites are analysed. • Greenhouse gas emissions reduction potential and economic performance are evaluated. • Impact of integration with adjacent industry or district heating systems is analysed. • The assessment comprises future energy market scenarios including CCS infrastructure. • Utilisation options for excess heat significantly impact the evaluated parameters.

  4. Shale-Gas Experience as an Analog for Potential Wellbore Integrity Issues in CO2 Sequestration

    Energy Technology Data Exchange (ETDEWEB)

    Carey, James W. [Los Alamos National Laboratory; Simpson, Wendy S. [Los Alamos National Laboratory; Ziock, Hans-Joachim [Los Alamos National Laboratory

    2011-01-01

    Shale-gas development in Pennsylvania since 2003 has resulted in about 19 documented cases of methane migration from the deep subsurface (7,0000) to drinking water aquifers, soils, domestic water wells, and buildings, including one explosion. In all documented cases, the methane leakage was due to inadequate wellbore integrity, possibly aggravated by hydrofracking. The leakage of methane is instructive on the potential for CO{sub 2} leakage from sequestration operations. Although there are important differences between the two systems, both involve migrating, buoyant gas with wells being a primary leakage pathway. The shale-gas experience demonstrates that gas migration from faulty wells can be rapid and can have significant impacts on water quality and human health and safety. Approximately 1.4% of the 2,200 wells drilled into Pennsylvania's Marcellus Formation for shale gas have been implicated in methane leakage. These have resulted in damage to over 30 domestic water supplies and have required significant remediation via well repair and homeowner compensation. The majority of the wellbore integrity problems are a result of over-pressurization of the wells, meaning that high-pressure gas has migrated into an improperly protected wellbore annulus. The pressurized gas leaks from the wellbore into the shallow subsurface, contaminating drinking water or entering structures. The effects are localized to a few thousands of feet to perhaps two-three miles. The degree of mixing between the drinking water and methane is sufficient that significant chemical impacts are created in terms of elevated Fe and Mn and the formation of black precipitates (metal sulfides) as well as effervescing in tap water. Thus it appears likely that leaking CO{sub 2} could also result in deteriorated water quality by a similar mixing process. The problems in Pennsylvania highlight the critical importance of obtaining background data on water quality as well as on problems associated with

  5. The quality management system in leading organization of the integrated structure

    Directory of Open Access Journals (Sweden)

    Kunitsyn A. M.

    2018-02-01

    Full Text Available the article has analyzed the problem of integrated structure management. The author has noted that the implementation of recommendations outlined in the article will allow building and improving the quality management system in leading organization of integrated structure on a regular basis that meets the requirements.

  6. The three-dimensional genome organization of Drosophila melanogaster through data integration.

    Science.gov (United States)

    Li, Qingjiao; Tjong, Harianto; Li, Xiao; Gong, Ke; Zhou, Xianghong Jasmine; Chiolo, Irene; Alber, Frank

    2017-07-31

    Genome structures are dynamic and non-randomly organized in the nucleus of higher eukaryotes. To maximize the accuracy and coverage of three-dimensional genome structural models, it is important to integrate all available sources of experimental information about a genome's organization. It remains a major challenge to integrate such data from various complementary experimental methods. Here, we present an approach for data integration to determine a population of complete three-dimensional genome structures that are statistically consistent with data from both genome-wide chromosome conformation capture (Hi-C) and lamina-DamID experiments. Our structures resolve the genome at the resolution of topological domains, and reproduce simultaneously both sets of experimental data. Importantly, this data deconvolution framework allows for structural heterogeneity between cells, and hence accounts for the expected plasticity of genome structures. As a case study we choose Drosophila melanogaster embryonic cells, for which both data types are available. Our three-dimensional genome structures have strong predictive power for structural features not directly visible in the initial data sets, and reproduce experimental hallmarks of the D. melanogaster genome organization from independent and our own imaging experiments. Also they reveal a number of new insights about genome organization and its functional relevance, including the preferred locations of heterochromatic satellites of different chromosomes, and observations about homologous pairing that cannot be directly observed in the original Hi-C or lamina-DamID data. Our approach allows systematic integration of Hi-C and lamina-DamID data for complete three-dimensional genome structure calculation, while also explicitly considering genome structural variability.

  7. Part-Load Performance of a Wet Indirectly Fired Gas Turbine Integrated with an Organic Rankine Cycle Turbogenerator

    DEFF Research Database (Denmark)

    Pierobon, Leonardo; Nguyen, Tuong-Van; Mazzucco, Andrea

    2014-01-01

    Over the last years, much attention has been paid to the development of efficient and low-cost power systems for biomass-to-electricity conversion. This paper aims at investigating the design- and part-load performance of an innovative plant based on a wet indirectly fired gas turbine (WIFGT......-design performance is governed by the efficiency characteristics of the compressor and turbine serving the gas turbine unit....

  8. Integrating Waste Heat from CO2 Removal and Coal-Fired Flue Gas to Increase Plant Efficiency

    Energy Technology Data Exchange (ETDEWEB)

    Irvin, Nick [Southern Company Services, Inc., Birmingham, AL (United States); Kowalczyk, Joseph [Southern Company Services, Inc., Birmingham, AL (United States)

    2017-04-01

    In project DE-FE0007525, Southern Company Services demonstrated heat integration methods for the capture and sequestration of carbon dioxide produced from pulverized coal combustion. A waste heat recovery technology (termed High Efficiency System) from Mitsubishi Heavy Industries America was integrated into an existing 25-MW amine-based CO2 capture process (Kansai Mitsubishi Carbon Dioxide Recovery Process®1) at Southern Company’s Plant Barry to evaluate improvements in the energy performance of the pulverized coal plant and CO2 capture process. The heat integration system consists of two primary pieces of equipment: (1) the CO2 Cooler which uses product CO2 gas from the capture process to heat boiler condensate, and (2) the Flue Gas Cooler which uses air heater outlet flue gas to further heat boiler condensate. Both pieces of equipment were included in the pilot system. The pilot CO2 Cooler used waste heat from the 25-MW CO2 capture plant (but not always from product CO2 gas, as intended). The pilot Flue Gas Cooler used heat from a slipstream of flue gas taken from downstream of Plant Barry’s air heater. The pilot also included a 0.25-MW electrostatic precipitator. The 25-MW High Efficiency System operated for approximately six weeks over a four month time period in conjunction with the 25-MW CO2 capture facility at Plant Barry. Results from the program were used to evaluate the technical and economic feasibility of full-scale implementation of this technology. The test program quantified energy efficiency improvements to a host power plant that could be realized due to the High Efficiency System. Through the execution of this project, the team verified the integrated operation of the High Efficiency System and Kansai Mitsubishi Carbon Dioxide Recovery Process®. The ancillary benefits of the High Efficiency System were also quantified, including reduced water consumption

  9. Snowflake-Shaped ZnO Nanostructures-Based Gas Sensor for Sensitive Detection of Volatile Organic Compounds

    Directory of Open Access Journals (Sweden)

    Tianli Han

    2017-01-01

    Full Text Available Volatile organic compounds (VOCs have been considered severe risks to human health. Gas sensors for the sensitive detection of VOCs are highly required. However, the preparation of gas-sensing materials with a high gas diffusion performance remains a great challenge. Here, through a simple hydrothermal method accompanied with a subsequent thermal treatment, a special porous snowflake-shaped ZnO nanostructure was presented for sensitive detection of VOCs including diethyl ether, methylbenzene, and ethanol. The fabricated gas sensors exhibit a good sensing performance including high responses to VOCs and a short response/recovery time. The responses of the ZnO-based gas sensor to 100 ppm ethanol, methylbenzene, and diethyl ether are about 27, 21, and 11, respectively, while the response times to diethyl ether and methylbenzene are less than 10 seconds. The gas adsorption-desorption kinetics is also investigated, which shows that the gas-sensing behaviors to different target gases are remarkably different, making it possible for target recognition in practical applications.

  10. Temperature dependence of the particle/gas partition coefficient: An application to predict indoor gas-phase concentrations of semi-volatile organic compounds

    Energy Technology Data Exchange (ETDEWEB)

    Wei, Wenjuan, E-mail: Wenjuan.Wei@cstb.fr [University of Paris-Est, Scientific and Technical Center for Building (CSTB), Health and Comfort Department, French Indoor Air Quality Observatory (OQAI), 84 Avenue Jean Jaurès, Champs sur Marne, 77447 Marne la Vallée Cedex 2 (France); Mandin, Corinne [University of Paris-Est, Scientific and Technical Center for Building (CSTB), Health and Comfort Department, French Indoor Air Quality Observatory (OQAI), 84 Avenue Jean Jaurès, Champs sur Marne, 77447 Marne la Vallée Cedex 2 (France); INSERM-U1085, Irset-Research Institute for Environmental and Occupational Health, Rennes (France); LERES-Environment and Health Research Laboratory (Irset and EHESP Technologic Platform), Rennes (France); Blanchard, Olivier [EHESP-School of Public Health, Sorbonne Paris Cité, Rennes (France); INSERM-U1085, Irset-Research Institute for Environmental and Occupational Health, Rennes (France); Mercier, Fabien [EHESP-School of Public Health, Sorbonne Paris Cité, Rennes (France); LERES-Environment and Health Research Laboratory (Irset and EHESP Technologic Platform), Rennes (France); INSERM-U1085, Irset-Research Institute for Environmental and Occupational Health, Rennes (France); Pelletier, Maud [EHESP-School of Public Health, Sorbonne Paris Cité, Rennes (France); INSERM-U1085, Irset-Research Institute for Environmental and Occupational Health, Rennes (France); Le Bot, Barbara [EHESP-School of Public Health, Sorbonne Paris Cité, Rennes (France); LERES-Environment and Health Research Laboratory (Irset and EHESP Technologic Platform), Rennes (France); INSERM-U1085, Irset-Research Institute for Environmental and Occupational Health, Rennes (France); and others

    2016-09-01

    The indoor gas-phase concentrations of semi-volatile organic compounds (SVOCs) can be predicted from their respective concentrations in airborne particles by applying the particle/gas partitioning equilibrium. The temperature used for partitioning is often set to 25 °C. However, indoor temperatures frequently differ from this reference value. This assumption may result in errors in the predicted equilibrium gas-phase SVOC concentrations. To improve the prediction model, the temperature dependence of the particle/gas partition coefficient must be addressed. In this paper, a theoretical relationship between the particle/gas partition coefficient and temperature was developed based on the SVOC absorptive mechanism. The SVOC particle/gas partition coefficients predicted by employing the derived theoretical relationship agree well with the experimental data retrieved from the literature (R > 0.93). The influence of temperature on the equilibrium gas-phase SVOC concentration was quantified by a dimensionless analysis of the derived relationship between the SVOC particle/gas partition coefficient and temperature. The predicted equilibrium gas-phase SVOC concentration decreased by between 31% and 53% when the temperature was lowered by 6 °C, while it increased by up to 750% when the indoor temperature increased from 15 °C to 30 °C. - Highlights: • A theoretical relationship between K{sub p} and temperature was developed. • The relationship was based on the SVOC absorptive mechanism. • The temperature impact was quantified by a dimensionless analysis.

  11. Characterization of Secondary Organic Aerosol Precursors Using Two-Dimensional Gas-Chromatography

    Science.gov (United States)

    Roskamp, M.; Lou, W.; Pankow, J. F.; Harley, P. C.; Turnipseed, A.; Barsanti, K. C.

    2012-12-01

    The oxidation of volatile organic compounds (VOCs) plays a role in both regional and global air quality. However, field and laboratory research indicate that the body of knowledge around the identities, quantities and oxidation processes of these compounds in the ambient atmosphere is still incomplete (e.g., Goldstein & Galbally, 2007; Robinson et al., 2009). VOCs emitted to the atmosphere largely are of biogenic origin (Guenther et al., 2006), and many studies of ambient secondary organic aerosol (SOA) suggest that SOA is largely of biogenic origin (albeit closely connected to anthropogenic activities, e.g., de Gouw and Jimenez, 2009). Accurate modeling of SOA levels and properties will require a more complete understanding of biogenic VOCs (BOCs) and their atmospheric oxidation products. For example, satellite measurements indicate that biogenic VOC emissions are two to three times greater than levels currently included in models (Heald et al., 2010). Two-dimensional gas chromatography (GC×GC) is a powerful analytical technique that shows much promise in advancing the state-of-knowledge regarding BVOCs and their role in SOA formation. In this work, samples were collected during BEACHON-RoMBAS (Bio-hydro-atmosphere Interactions of Energy, Aerosols, Carbon, H2O, Organics & Nitrogen - Rocky Mountain Biogenic Aerosol Study) in July and August of 2011. The field site was a Ponderosa Pine forest near Woodland, CO, inside the Manitou Experimental Forest, which is operated by the US Forest Service. The area is characteristic of the central Rocky Mountains and trace gas monitoring indicates that little anthropogenic pollution is transported from the nearby urban areas (Kim et al. 2010 and references therein). Ambient and enclosure samples were collected on ATD (adsorption/thermal desorption) cartridges and analyzed for BVOCs using two-dimensional gas chromatography (GC×GC) with time of flight mass spectrometry (TOFMS) and flame ionized detection (FID). Measurements of

  12. Managing the IT Integration of Acquisitions by Multi-Business Organizations

    DEFF Research Database (Denmark)

    Henningsson, Stefan; Yetton, Philip

    2011-01-01

    Acquisitions are standard components of the growth strategies of many organizations. Frequently, acquisitions raise important questions concerning how and to what extent the acquisition’s information technology (IT) needs to be integrated into the IT of the acquirer. We investigate how the initial...... of IT integration paths in two acquisitions made by the industry group Trelleborg AB. We identify four initial business and IT strategic alignment conditions where the IT integration process is a simple one-step process exploiting existing business and IT capabilities. Low compliance with these conditions leads...

  13. Self-Organization in Integrated Conservation and Development Initiatives

    Directory of Open Access Journals (Sweden)

    Cristiana Simão Seixas

    2007-11-01

    Full Text Available This paper uses a cooking metaphor to explore key elements (i.e., ingredients for a great meal that contribute to self-organization processes in the context of successful community-based conservation (CBC or integrated conservation and development projects (ICDP. We pose two major questions: (1 What are the key factors that drive peoples' and/or organizations' willingness to take responsibilities and to act? (2 What contributes to community self-organization? In other words, how conservation-development projects originate, evolve, survive or disappear? In order to address these questions we examine trigger events and catalytic elements in several cases among the Equator Prize finalists and short-listed nominees, from both the 2002 and 2004 awards. The Prize recognizes efforts in integrating biodiversity conservation and poverty reduction. We use secondary data in our analysis, including data from several technical reports and scientific papers written about the Equator Prize finalists and short-listed nominees. We observed common ingredients in most projects including: (1 involvement and commitment of key players (including communities, (2 funding, (3 strong leadership, (4 capacity building, (5 partnership with supportive organizations and government, and (6 economic incentives (including alternative livelihood options. We also observed that CBC and ICDP initiatives opportunistically evolve in a multi-level world, in which local communities establish linkages with people and organizations at different political levels, across different geographical scales and for different purposes. We conclude that there is no right 'recipe' to promote community self-organization but often a mix of some of these six ingredients need to come together for 'success' and that one or two ingredients are not sufficient to ensure success. Also the existence of these six ingredients does not guarantee a great meal - the 'chef's' creativity also is critical. That is

  14. Development of a Simulation Framework for Analyzing Security of Supply in Integrated Gas and Electric Power Systems

    Directory of Open Access Journals (Sweden)

    Kwabena Addo Pambour

    2017-01-01

    Full Text Available Gas and power networks are tightly coupled and interact with each other due to physically interconnected facilities. In an integrated gas and power network, a contingency observed in one system may cause iterative cascading failures, resulting in network wide disruptions. Therefore, understanding the impacts of the interactions in both systems is crucial for governments, system operators, regulators and operational planners, particularly, to ensure security of supply for the overall energy system. Although simulation has been widely used in the assessment of gas systems as well as power systems, there is a significant gap in simulation models that are able to address the coupling of both systems. In this paper, a simulation framework that models and simulates the gas and power network in an integrated manner is proposed. The framework consists of a transient model for the gas system and a steady state model for the power system based on AC-Optimal Power Flow. The gas and power system model are coupled through an interface which uses the coupling equations to establish the data exchange and coordination between the individual models. The bidirectional interlink between both systems considered in this studies are the fuel gas offtake of gas fired power plants for power generation and the power supply to liquefied natural gas (LNG terminals and electric drivers installed in gas compressor stations and underground gas storage facilities. The simulation framework is implemented into an innovative simulation tool named SAInt (Scenario Analysis Interface for Energy Systems and the capabilities of the tool are demonstrated by performing a contingency analysis for a real world example. Results indicate how a disruption triggered in one system propagates to the other system and affects the operation of critical facilities. In addition, the studies show the importance of using transient gas models for security of supply studies instead of successions of

  15. Integral Field Spectroscopy of Markarian 273: Mapping High-Velocity Gas Flows and an Off-Nucleus Seyfert 2 Nebula.

    Science.gov (United States)

    Colina; Arribas; Borne

    1999-12-10

    Integral field optical spectroscopy with the INTEGRAL fiber-based system is used to map the extended ionized regions and gas flows in Mrk 273, one of the closest ultraluminous infrared galaxies. The Hbeta and [O iii] lambda5007 maps show the presence of two distinct regions separated by 4&arcsec; (3.1 kpc) along position angle (P.A.) 240 degrees. The northeastern region coincides with the optical nucleus of the galaxy and shows the spectral characteristics of LINERs. The southwestern region is dominated by [O iii] emission and is classified as a Seyfert 2. Therefore, in the optical, Mrk 273 is an ultraluminous infrared galaxy with a LINER nucleus and an extended off-nucleus Seyfert 2 nebula. The kinematics of the [O iii] ionized gas shows (1) the presence of highly disturbed gas in the regions around the LINER nucleus, (2) a high-velocity gas flow with a peak-to-peak amplitude of 2.4x103 km s-1, and (3) quiescent gas in the outer regions (at 3 kpc). We hypothesize that the high-velocity flow is the starburst-driven superwind generated in an optically obscured nuclear starburst and that the quiescent gas is directly ionized by a nuclear source, similar to the ionization cones typically seen in Seyfert galaxies.

  16. Integrated modelling of two xenobiotic organic compounds

    DEFF Research Database (Denmark)

    Lindblom, Erik Ulfson; Gernaey, K.V.; Henze, Mogens

    2006-01-01

    This paper presents a dynamic mathematical model that describes the fate and transport of two selected xenobiotic organic compounds (XOCs) in a simplified representation. of an integrated urban wastewater system. A simulation study, where the xenobiotics bisphenol A and pyrene are used as reference...... compounds, is carried out. Sorption and specific biological degradation processes are integrated with standardised water process models to model the fate of both compounds. Simulated mass flows of the two compounds during one dry weather day and one wet weather day are compared for realistic influent flow...... rate and concentration profiles. The wet weather day induces resuspension of stored sediments, which increases the pollutant load on the downstream system. The potential of the model to elucidate important phenomena related to origin and fate of the model compounds is demonstrated....

  17. Microbial Electrolysis Cells for High Yield Hydrogen Gas Production from Organic Matter

    KAUST Repository

    Logan, Bruce E.

    2008-12-01

    The use of electrochemically active bacteria to break down organic matter, combined with the addition of a small voltage (>0.2 V in practice) in specially designed microbial electrolysis cells (MECs), can result in a high yield of hydrogen gas. While microbial electrolysis was invented only a few years ago, rapid developments have led to hydrogen yields approaching 100%, energy yields based on electrical energy input many times greater than that possible by water electrolysis, and increased gas production rates. MECs used to make hydrogen gas are similar in design to microbial fuel cells (MFCs) that produce electricity, but there are important differences in architecture and analytical methods used to evaluate performance. We review here the materials, architectures, performance, and energy efficiencies of these MEC systems that show promise as a method for renewable and sustainable energy production, and wastewater treatment. © 2008 American Chemical Society.

  18. Toho Gas accepts the challenge of operational reform creation of an integrated OA environment

    International Nuclear Information System (INIS)

    Kato, Hisaatsu; Ito, Mari; Goto, Akihito

    1997-01-01

    Toho Gas Co., Ltd. is Japan's third largest city gas supplier. In response to changes in the industrial environment, the company began the Integrated OA Project in 1994 promoting use of information technology while reforming its systems and culture. We made a proposal to distribute one personal computer connected to a company-wide network to each office worker. In addition, we attached importance to the creation of a database, which can integrate all information systems with a flexible structure and also play a central role in end user computing. A data model for the entire company has been already made and implemented into some operational systems and data-warehouses. Furthermore, to reform our business we are offering incremental goals, including the first step such as achieving a paper less working environment with a little effort. This methodology has achieved a great success. In the near future, we will expand the infrastructure with mobile computers and implementation of a database. (au)

  19. Rehabilitation of Mature Gas Fields in Romania: Success Through Integration of Management Processes and New Technology

    Directory of Open Access Journals (Sweden)

    Louboutin Michel

    2004-09-01

    Full Text Available Nature oil and gas fields are difficult to rehabilitate effectively because of the economics of declining production. Many fields are abandoned prematurely when their life could be prolonged significantly through application of new technology. Romgaz (a national exploration and production company and Schlumberger (an integrated oilfield services company developed a new business model to overcome these obstacles. The key to success of this model, which is being applied to gas fields in the Transylvanian basin of Romania, is the shared risk and shared reward for the two companies. Integrated management processes addressing the complete system from reservoir to wellbore to surface/transmission facilities and application of new technology (logging, perforation, etc. have resulted in multifold increases in production.

  20. Regulatory off-gas analysis from the evaporation of Hanford simulated waste spiked with organic compounds.

    Science.gov (United States)

    Saito, Hiroshi H; Calloway, T Bond; Ferrara, Daro M; Choi, Alexander S; White, Thomas L; Gibson, Luther V; Burdette, Mark A

    2004-10-01

    After strontium/transuranics removal by precipitation followed by cesium/technetium removal by ion exchange, the remaining low-activity waste in the Hanford River Protection Project Waste Treatment Plant is to be concentrated by evaporation before being mixed with glass formers and vitrified. To provide a technical basis to permit the waste treatment facility, a relatively organic-rich Hanford Tank 241-AN-107 waste simulant was spiked with 14 target volatile, semi-volatile, and pesticide compounds and evaporated under vacuum in a bench-scale natural circulation evaporator fitted with an industrial stack off-gas sampler at the Savannah River National Laboratory. An evaporator material balance for the target organics was calculated by combining liquid stream mass and analytical data with off-gas emissions estimates obtained using U.S. Environmental Protection Agency (EPA) SW-846 Methods. Volatile and light semi-volatile organic compounds (1 mm Hg vapor pressure) in the waste simulant were found to largely exit through the condenser vent, while heavier semi-volatiles and pesticides generally remain in the evaporator concentrate. An OLI Environmental Simulation Program (licensed by OLI Systems, Inc.) evaporator model successfully predicted operating conditions and the experimental distribution of the fed target organics exiting in the concentrate, condensate, and off-gas streams, with the exception of a few semi-volatile and pesticide compounds. Comparison with Henry's Law predictions suggests the OLI Environmental Simulation Program model is constrained by available literature data.

  1. Oil and gas platforms with steam bottoming cycles: System integration and thermoenvironomic evaluation

    DEFF Research Database (Denmark)

    Nguyen, Tuong-Van; Tock, Laurence; Breuhaus, Peter

    2014-01-01

    The integration of steam bottoming cycles on oil and gas platforms is currently regarded as the most promising option for improving the performance of these energy-intensive systems. In this paper, a North Sea platform is taken as case study, and a systematic analysis of its energy requirements...... cooling utility, and (iv) the weight limitations on the platform are quantitatively assessed. The results illustrate the benefits of converting the gas turbine process into a combined cycle, since the fuel gas consumption and the total CO2-emissions can be reduced by more than 15 %. Using the cooling...... water from the processing plant reveals to be more profitable than using seawater, as the additional pumping power outweighs the benefit of using a cooling medium at a temperature of about 8 °C lower. This study highlights thereby the importance of analysing energy savings and recovery options...

  2. Report of the experts group on the taxation of the access to gas transport and distribution network

    International Nuclear Information System (INIS)

    2001-04-01

    In the framework of a new french gas industry organization (directive of the 22 june 1998), a concerting mission has been realized on prices taxation for the transport and distribution facilities. The following topics have been debated: the integration and competition of the european gas market, the gas market liberalization consistency and the taxation of transport and distribution network access. (A.L.B.)

  3. Multiscale pore structure and its effect on gas transport in organic-rich shale

    Science.gov (United States)

    Wu, Tianhao; Li, Xiang; Zhao, Junliang; Zhang, Dongxiao

    2017-07-01

    A systematic investigation of multiscale pore structure in organic-rich shale by means of the combination of various imaging techniques is presented, including the state-of-the-art Helium-Ion-Microscope (HIM). The study achieves insight into the major features at each scale and suggests the affordable techniques for specific objectives from the aspects of resolution, dimension, and cost. The pores, which appear to be isolated, are connected by smaller pores resolved by higher-resolution imaging. This observation provides valuable information, from the microscopic perspective of pore structure, for understanding how gas accumulates and transports from where it is generated. A comprehensive workflow is proposed based on the characteristics acquired from the multiscale pore structure analysis to simulate the gas transport process. The simulations are completed with three levels: the microscopic mechanisms should be taken into consideration at level I; the spatial distribution features of organic matter, inorganic matter, and macropores constitute the major issue at level II; and the microfracture orientation and topological structure are dominant factors at level III. The results of apparent permeability from simulations agree well with the values acquired from experiments. By means of the workflow, the impact of various gas transport mechanisms at different scales can be investigated more individually and precisely than conventional experiments.

  4. Development of a Small, Inexpensive, and Field-deployable Gas Chromatograph for the Automated Collection, Separation, and Analysis of Gas-phase Organic Compounds

    Science.gov (United States)

    Skog, K.; Xiong, F.; Gentner, D. R.

    2017-12-01

    The identification and quantification of gas-phase organic compounds, like volatile organic compounds (VOCs), in the atmosphere relies on separation of complex mixtures and sensitive detection. Gas chromatography (GC) is widely applied, but relies on the need for high-purity compressed gases for separation and, often for detection. We have developed a low-cost, compact GC-based system for the collection and quantitative chemical speciation of complex mixtures of common atmospheric VOCs without the need for compressed high-purity gases or expensive detectors. We present results of lab and field testing against a commercially-available GC system. At optimized linear velocities challenging VOC pairs of similar volatility were resolved within 30 minutes, including n- and i-pentane; n-pentane and isoprene; and ethylbenzene and m/p-xylene. For 5-30 minute samples, we observe ppt-level detection limits for common VOCs such as benzene, toluene, ethylbenzene, xylenes, alpha-pinene, and limonene. We also present results of in-field use for VOC measurements. In all, this instrument is accurate, precise, small, and inexpensive (<$2500). Its lack of compressed gas cylinders make it ideal for field deployment and has been demonstrated to produce similar quality data to available GC technology.

  5. Incorporation of Gas Chromatography-Mass Spectrometry into the Undergraduate Organic Chemistry Laboratory Curriculum

    Science.gov (United States)

    Giarikos, Dimitrios G.; Patel, Sagir; Lister, Andrew; Razeghifard, Reza

    2013-01-01

    Gas chromatography-mass spectrometry (GC-MS) is a powerful analytical tool for detection, identification, and quantification of many volatile organic compounds. However, many colleges and universities have not fully incorporated this technique into undergraduate teaching laboratories despite its wide application and ease of use in organic…

  6. Organic High Electron Mobility Transistors Realized by 2D Electron Gas.

    Science.gov (United States)

    Zhang, Panlong; Wang, Haibo; Yan, Donghang

    2017-09-01

    A key breakthrough in inorganic modern electronics is the energy-band engineering that plays important role to improve device performance or develop novel functional devices. A typical application is high electron mobility transistors (HEMTs), which utilizes 2D electron gas (2DEG) as transport channel and exhibits very high electron mobility over traditional field-effect transistors (FETs). Recently, organic electronics have made very rapid progress and the band transport model is demonstrated to be more suitable for explaining carrier behavior in high-mobility crystalline organic materials. Therefore, there emerges a chance for applying energy-band engineering in organic semiconductors to tailor their optoelectronic properties. Here, the idea of energy-band engineering is introduced and a novel device configuration is constructed, i.e., using quantum well structures as active layers in organic FETs, to realize organic 2DEG. Under the control of gate voltage, electron carriers are accumulated and confined at quantized energy levels, and show efficient 2D transport. The electron mobility is up to 10 cm 2 V -1 s -1 , and the operation mechanisms of organic HEMTs are also argued. Our results demonstrate the validity of tailoring optoelectronic properties of organic semiconductors by energy-band engineering, offering a promising way for the step forward of organic electronics. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  7. Child welfare organizations: Do specialization and service integration impact placement decisions?

    Science.gov (United States)

    Smith, Carrie; Fluke, John; Fallon, Barbara; Mishna, Faye; Decker Pierce, Barbara

    2018-02-01

    The objective of this study was to contribute to the understanding of the child welfare organization by testing the hypothesis that the characteristics of organizations influence decisions made by child protection staff for vulnerable children. The influence of two aspects of organizational structure on the decision to place a child in out-of-home care were examined: service integration and worker specialization. A theoretical framework that integrated the Decision-Making Ecology Framework (Baumann et al., 2011) and Yoo et al. (2007) conceptual framework of organizational constructs as predictors of service effectiveness was tested. Secondary data analysis of the Ontario Incidence Study of Reported Child Abuse and Neglect - 2013 (OIS-2013) was conducted. A subsample of 4949 investigations from 16 agencies was included in this study. Given the nested structure of the data, multi-level modelling was used to test the relative contribution of case and organizational factors to the decision to place. Despite the reported differences among child welfare organizations and research that has demonstrated variance in the placement decision as a result of organizational factors, the structure of the organization (i.e., worker specialization and service integration) showed no predictive power in the final models. The lack of variance may be explained by the relatively low frequency of placements during the investigation phase of service, the hierarchical impact of the factors of the DME and the limited information available regarding the structure of child welfare organizations in Ontario. Suggestions for future research are provided. Copyright © 2017 Elsevier Ltd. All rights reserved.

  8. Facile Synthesis of a Pentiptycene-Based Highly Microporous Organic Polymer for Gas Storage and Water Treatment.

    Science.gov (United States)

    Luo, Shuangjiang; Zhang, Qinnan; Zhang, Yizhou; Weaver, Kevin P; Phillip, William A; Guo, Ruilan

    2018-05-02

    Rigid H-shaped pentiptycene units, with an intrinsic hierarchical structure, were employed to fabricate a highly microporous organic polymer sorbent via Friedel-Crafts reaction/polymerization. The obtained microporous polymer exhibits good thermal stability, a high Brunauer-Emmett-Teller surface area of 1604 m 2 g -1 , outstanding CO 2 , H 2 , and CH 4 storage capacities, as well as good adsorption selectivities for the separation of CO 2 /N 2 and CO 2 /CH 4 gas pairs. The CO 2 uptake values reached as high as 5.00 mmol g -1 (1.0 bar and 273 K), which, along with high adsorption selectivity values (e.g., 47.1 for CO 2 /N 2 ), make the pentiptycene-based microporous organic polymer (PMOP) a promising sorbent material for carbon capture from flue gas and natural gas purification. Moreover, the PMOP material displayed superior absorption capacities for organic solvents and dyes. For example, the maximum adsorption capacities for methylene blue and Congo red were 394 and 932 mg g -1 , respectively, promoting the potential of the PMOP as an excellent sorbent for environmental remediation and water treatment.

  9. Integration of power to gas/power to liquid in the ongoing transformation processes

    International Nuclear Information System (INIS)

    Purr, Katja; Osiek, Dirk; Lange, Martin

    2016-01-01

    The objective of this position paper is to assess from the current level of knowledge of the Federal Environment Agency the role and perspective of power to gas / power to Liquid (PtG / PtL) in a fully renewable energy system and in particular to appoint the challenges of integration and further development of this technique in the current transformation process in the next few years. Here also the comparison to other Power to X-options and their greenhouse gas reduction effect is shown. The geographic focus of the considerations is on Germany, knowing that a full renewable energy supply in Germany must be especially for economic reasons embedded in a long term international energy policy. [de

  10. Influence of oxygen gas on characteristics of self-organized luminous pattern formation observed in an atmospheric dc glow discharge using a liquid electrode

    International Nuclear Information System (INIS)

    Shirai, Naoki; Uchida, Satoshi; Tochikubo, Fumiyoshi

    2014-01-01

    Self-organized luminous pattern formation is observed in the liquid surface of an atmospheric dc glow discharge using a liquid electrode with a miniature helium flow. The factors affecting pattern formation are the gap length, discharge current, helium mass flow rate and polarity. The pattern shape depends on the conductivity and temperature of the liquid electrode. A variety of patterns were observed by changing the conductivity and temperature of the liquid. We clarified that the self-organized pattern formation depends on the amount of electronegative gas, such as oxygen, in the gas in the electrode gap. When an oxygen gas flow was fed to the liquid surface from the outside in an obliquely downward direction, namely, the amount of oxygen gas on the liquid surface was increased locally, self-organized pattern formation was observed in the region with the increased amount of oxygen gas. When the amount of oxygen in the gas in the gap was changed by using a sheath flow system, the appearance of the pattern changed. The presence of oxygen gas strongly affected the self-organized pattern formation of the atmospheric dc discharge using a liquid anode. (paper)

  11. Gas-phase advanced oxidation as an integrated air pollution control technique

    Directory of Open Access Journals (Sweden)

    Getachew A. Adnew

    2016-03-01

    Full Text Available Gas-phase advanced oxidation (GPAO is an emerging air cleaning technology based on the natural self-cleaning processes that occur in the Earth’s atmosphere. The technology uses ozone, UV-C lamps and water vapor to generate gas-phase hydroxyl radicals that initiate oxidation of a wide range of pollutants. In this study four types of GPAO systems are presented: a laboratory scale prototype, a shipping container prototype, a modular prototype, and commercial scale GPAO installations. The GPAO systems treat volatile organic compounds, reduced sulfur compounds, amines, ozone, nitrogen oxides, particles and odor. While the method covers a wide range of pollutants, effective treatment becomes difficult when temperature is outside the range of 0 to 80 °C, for anoxic gas streams and for pollution loads exceeding ca. 1000 ppm. Air residence time in the system and the rate of reaction of a given pollutant with hydroxyl radicals determine the removal efficiency of GPAO. For gas phase compounds and odors including VOCs (e.g. C6H6 and C3H8 and reduced sulfur compounds (e.g. H2S and CH3SH, removal efficiencies exceed 80%. The method is energy efficient relative to many established technologies and is applicable to pollutants emitted from diverse sources including food processing, foundries, water treatment, biofuel generation, and petrochemical industries.

  12. Development and validation of a portable gas phase standard generation and calibration system for volatile organic compounds

    Science.gov (United States)

    P. Veres; J. B. Gilman; J. M. Roberts; W. C. Kuster; C. Warneke; I. R. Burling; J. de Gouw

    2010-01-01

    We report on the development of an accurate, portable, dynamic calibration system for volatile organic compounds (VOCs). The Mobile Organic Carbon Calibration System (MOCCS) combines the production of gas-phase VOC standards using permeation or diffusion sources with quantitative total organic carbon (TOC) conversion on a palladium surface to CO2 in the presence of...

  13. Integrity management of Brazil-Bolivia gas pipeline to reduce risks due third party damage

    Energy Technology Data Exchange (ETDEWEB)

    Vasconcellos, Carlos Renato Aragonez de; Monte, Oswaldo [PETROBRAS, Rio de Janeiro, RJ (Brazil); Colen, Eustaquio; Cunha, Roberto de Souza; Oliveira, Hudson Regis de [Transportadora Brasileira Gasoduto Bolivia-Brasil, S.A., Rio de Janeiro, RJ (Brazil); Lima, Rogerio de Souza [RSL Consultoria Geoprojetos (Brazil); Schultz Neto, Walter [Milton Braga Assessoria Tecnica (Brazil)

    2005-07-01

    The Bolivia-Brazil Natural Gas Pipeline has 2.600 kilometers from Rio Grande City in Bolivia to Canoas City, in the south of Brazil. The right-of-way crosses a lot of types of topography and areas subjected to various kinds of anthropological actions, like areas in class locations 3, locals under agricultural activities, forests and minerals explorations, and near constructions of highway and railway, industrial constructions, new pipelines in the same right-of -way, channels, dams, that requires special projects to avoid that the gas pipeline could be subject to strengths that were not consider in the original design. The aim of this paper is to present the jobs developed by TBG during seven years of gas pipeline operations, as public awareness program, procedures to design, construct and inspect specials constructions along and near the right-of -way, control of mineral and forest explorations, monitoring and controlling of excavations on the right-of-way to install new pipelines and optical cables, to reduce risks of gas pipeline damage due third party, as a component of TBG' Managing Integrity Gas Pipeline Program. (author)

  14. Design of bone-integrating organic-inorganic composite suitable for bone repair.

    Science.gov (United States)

    Miyazaki, Toshiki

    2013-01-01

    Several ceramics exhibit specific biological affinity, i.e. direct bone integration, when implanted in bony defects. They are called bioactive ceramics and utilized as important bone substitutes. However, there is limitation on clinical application, because of their inappropriate mechanical properties such as high Young's modulus and low fracture toughness. Novel bioactive materials exhibiting high machinability and flexibility have been desired in medical fields. Mixing bioactive ceramic powders and organic polymers have developed various organic-inorganic composites. Their mechanical property and bioactivity are mainly governed by the ceramics content. It is known that bioactive ceramics integrate with the bone through bone-like hydroxyapatite layer formed on their surfaces by chemical reaction with body fluid. This is triggered by a catalytic effect of various functional groups. On the basis of these facts, novel bioactive organic-inorganic nanocomposites have been developed. In these composites, inorganic components effective for triggering the hydroxyapatite nucleation are dispersed in polymer matrix at molecular level. Concept of the organic-inorganic composite is also applicable for providing polymethyl methacrylate (PMMA) bone cement with the bioactivity.

  15. Integrating recycling, renewable energy and agriculture for commercial waste to wealth businesses

    International Nuclear Information System (INIS)

    Gan Khai Chung; Angeline Pang

    2010-01-01

    Recycling organic material to produce renewable energy and organic fertilizer is an attractive business model in waste to wealth business proposition. Azed Bina Sdn Bhd has developed an integrated recycling facility to recycle solid organic materials into energy and organic fertilizer, a project partially funded by MOSTI TechnoFund in 2008. The novel and innovative aspect is the water disassociation technology which separates the water into hydrogen gas and oxygen gas economically using thermal heat from the burning of biomass which is a waste material. This system is modular, scalable, economical and environmental friendly. It has many applications in the field of, Environment and Solid Waste Management - recycling organic waste into energy and organic fertilizer rather than disposal at the landfill, hence preserving our environment. Green technology - economical biogas production consists of 50% hydrogen gas which is a clean and renewable energy source. The biogas has many applications in the food industry, manufacturing industry and agriculture sector. Agro-based industry - production of clean heat energy is useful for the drying of agriculture crops. Agriculture Sector - production of ash can be used to produce organic fertilizer by incorporating effective microbes. Reduce the dependence on chemical fertilizer which is bad for the environment Rural Development - developing rural area by integrating small scale industries, agro based industry, agriculture and rural area. The company commercial applications of recycling organic materials to produce energy for companies such as laundry business, agro based food drying and waste management recycling. The next project is to provide chilled water using organic waste. (author)

  16. Chemical composition of gas-phase organic carbon emissions from motor vehicles and implications for ozone production.

    Science.gov (United States)

    Gentner, Drew R; Worton, David R; Isaacman, Gabriel; Davis, Laura C; Dallmann, Timothy R; Wood, Ezra C; Herndon, Scott C; Goldstein, Allen H; Harley, Robert A

    2013-10-15

    Motor vehicles are major sources of gas-phase organic carbon, which includes volatile organic compounds (VOCs) and other compounds with lower vapor pressures. These emissions react in the atmosphere, leading to the formation of ozone and secondary organic aerosol (SOA). With more chemical detail than previous studies, we report emission factors for over 230 compounds from gasoline and diesel vehicles via two methods. First we use speciated measurements of exhaust emissions from on-road vehicles in summer 2010. Second, we use a fuel composition-based approach to quantify uncombusted fuel components in exhaust using the emission factor for total uncombusted fuel in exhaust together with detailed chemical characterization of liquid fuel samples. There is good agreement between the two methods except for products of incomplete combustion, which are not present in uncombusted fuels and comprise 32 ± 2% of gasoline exhaust and 26 ± 1% of diesel exhaust by mass. We calculate and compare ozone production potentials of diesel exhaust, gasoline exhaust, and nontailpipe gasoline emissions. Per mass emitted, the gas-phase organic compounds in gasoline exhaust have the largest potential impact on ozone production with over half of the ozone formation due to products of incomplete combustion (e.g., alkenes and oxygenated VOCs). When combined with data on gasoline and diesel fuel sales in the U.S., these results indicate that gasoline sources are responsible for 69-96% of emissions and 79-97% of the ozone formation potential from gas-phase organic carbon emitted by motor vehicles.

  17. Economics, organization, and planning of drilling and petroleum-gas production enterprises. Ekonomika, organizatsiya, i planirovanie burovykh i neftegazo-dobyvayushchikh predpriyatii

    Energy Technology Data Exchange (ETDEWEB)

    Shmatov, V F; Tishchenko, V E; Malyshev, Yu M; Strizhenova, N F; Samigullin, A S

    1978-01-01

    An examination is made of problems in the economics, organization, planning, and management of production at drilling and petroleum-gas producing enterprises. A discussion is made of the development and distribution of the petroleum and gas industry, the essence and characteristics of technical progress in the petroleum industry, concentration, specialization, cooperation, and combination production. Considerable attention is given to fixed and working capital, productivity, principles of cost accounting, production costs, and economic reform. A discussion is made of the principles of organizing and managing a petroleum enterprise, labor management, technical labor standards, wage organization, planning of drilling and petroleum-gas production, principles of cost-accounting, inventory, and accountability. A discussion is made of the essence of methods of determining the economic effectiveness of production, and an examination is made of advanced methods of managing production, and basic problems in the economic analysis of production-management activities of enterprises. The book is intended as a textbook for students at secondary specialized teaching institutions dealing with the drilling and operation of petroleum and gas wells, the operation of oil and gas wells, and equipment of petroleum and gas industries. It may also be used by students in other fields of specialization as well as by workers in the petroleum and gas industry. 50 references, 5 figures, 55 tables.

  18. The importance of civilian nursing organizations: integrative literature review.

    Science.gov (United States)

    Santos, James Farley Estevam Dos; Santos, Regina Maria Dos; Costa, Laís de Miranda Crispim; Almeida, Lenira Maria Wanderley Santos de; Macêdo, Amanda Cavalcante de; Santos, Tânia Cristina Franco

    2016-06-01

    to identify and analyze evidence from studies about the importance of civilian nursing organizations. an integrative literature review, for which searches were conducted in the databases LILACS, PubMed/MEDLINE, SciELO, BDENF, and Scopus. sixteen articles published between the years 2004-2013 were selected, 68.75% of which were sourced from Brazilian journals and 31.25% from American journals. civilian nursing organizations are important and necessary, because they have collaborated decisively in nursing struggles in favor of the working class and society in general, and these contributions influence different axes of professional performance.

  19. Fully integrated microfluidic measurement system for real-time determination of gas and liquid mixtures composition

    NARCIS (Netherlands)

    Lötters, Joost Conrad; Groenesteijn, Jarno; van der Wouden, E.J.; Sparreboom, Wouter; Lammerink, Theodorus S.J.; Wiegerink, Remco J.

    2015-01-01

    We have designed and realised a fully integrated microfluidic measurement system for real-time determination of both flow rate and composition of gas- and liquid mixtures. The system comprises relative permittivity sensors, pressure sensors, a Coriolis flow and density sensor, a thermal flow sensor

  20. Future distributed generation: An operational multi-objective optimization model for integrated small scale urban electrical, thermal and gas grids

    International Nuclear Information System (INIS)

    Lo Cascio, Ermanno; Borelli, Davide; Devia, Francesco; Schenone, Corrado

    2017-01-01

    Highlights: • Multi-objective optimization model for retrofitted and integrated natural gas pressure regulation stations. • Comparison of different incentive mechanisms for recovered energy based on the characteristics of preheating process. • Control strategies comparison: performances achieved with optimal control vs. ones obtained by thermal load tracking. - Abstract: A multi-objective optimization model for urban integrated electrical, thermal and gas grids is presented. The main system consists of a retrofitted natural gas pressure regulation station where a turbo-expander allows to recover energy from the process. Here, the natural gas must be preheated in order to avoid methane hydrates. The preheating phase could be based on fossil fuels, renewable or on a thermal mix. Depending on the system configuration, the proposed optimization model enables a proper differentiation based on how the natural gas preheating process is expected to be accomplished. This differentiation is addressed by weighting the electricity produced by the turbo-expander and linking it to proper remuneration tariffs. The effectiveness of the model has been tested on an existing plant located in the city of Genoa. Here, the thermal energy is provided by means of two redundant gas-fired boilers and a cogeneration unit. Furthermore, the whole system is thermally integrated with a district heating network. Numerical simulation results, obtained with the commercial proprietary software Honeywell UniSim Design Suite, have been compared with the optimal solutions achieved. The effectiveness of the model, in terms of economic and environmental performances, is finally quantified. For specific conditions, the model allows achieving an operational costs reduction of about 17% with the respect to thermal-load-tracking control logic.

  1. Integrated Farm System Model Version 4.3 and Dairy Gas Emissions Model Version 3.3 Software development and distribution

    Science.gov (United States)

    Modeling routines of the Integrated Farm System Model (IFSM version 4.2) and Dairy Gas Emission Model (DairyGEM version 3.2), two whole-farm simulation models developed and maintained by USDA-ARS, were revised with new components for: (1) simulation of ammonia (NH3) and greenhouse gas emissions gene...

  2. Turbo-gas emissions and integrated pollution prevention and control (IPPC); Emissioni da turbogas e prevenzione e limitazione integrata dell'inquinamento

    Energy Technology Data Exchange (ETDEWEB)

    Mariani, M. [ISPESL/DIPIA, Roma (Italy); Sera, B. [Roccadarce (Italy)

    2005-10-15

    The present paper considers the gas-turbine pollution and joints out that the NO, is the most important pollutant among others pollutants as well as the carbon oxide and the volatile organic compounds because the NO{sub x}, has a high mass production rate (in the combustion chamber), elevated toxicity to the ecosystem and because of being in the atmosphere a precursor of secondary ultrafine particles PM{sub 2,5}. In with reference to the integrated pollution and control (IPPC) the job shows schemes of chain chemical reactions which are on the base of the formation of different types of NO{sub x}, thermal and organic, and it illustrates the influence of some operative parameters on the combustion's efficiency and then on the NO{sub x}, production rate. Also, the study gives the best absolvable techniques (BAT) to reduce the NO{sub x}, production rate and to demolish it before its introduction, as well as gas exhaust, in the atmosphere. At the end, the work shows that the gas-turbine are to consider thermal engines with a little environment impact index specially when they make use of the natural gas, as well as fuel. [Italian] Lo studio considera gli inquinanti emessi dalle turbine a gas ed evidenzia che l'ossido di azoto NO, e quell'inquinante che e degno di attenzione a causa del suo alto tasso di produzione in camera di combustione (notevolmente piu alto di quello dell'ossido di carbonio e dei composti organici volatili), della sua elevata tossicita nei confronti dell'ecosistema e per il fatto di essere in atmosfera un precursore del particolato secondario ultrafino PM{sub 2},{sub 5}. In riferimento. alla prevenzione e limitazione integrata dell'inquinamento lo studio espone gli schemi di reazioni chimiche che sono alla base della formazione dei vari tipi di NO{sub x}, quello termico e quello organico, che si generano in camera di combustione ed inoltre illustra l'influenza di alcuni parametri operativi sull'efficienza del

  3. Air ionization as a control technology for off-gas emissions of volatile organic compounds.

    Science.gov (United States)

    Kim, Ki-Hyun; Szulejko, Jan E; Kumar, Pawan; Kwon, Eilhann E; Adelodun, Adedeji A; Reddy, Police Anil Kumar

    2017-06-01

    High energy electron-impact ionizers have found applications mainly in industry to reduce off-gas emissions from waste gas streams at low cost and high efficiency because of their ability to oxidize many airborne organic pollutants (e.g., volatile organic compounds (VOCs)) to CO 2 and H 2 O. Applications of air ionizers in indoor air quality management are limited due to poor removal efficiency and production of noxious side products, e.g., ozone (O 3 ). In this paper, we provide a critical evaluation of the pollutant removal performance of air ionizing system through comprehensive review of the literature. In particular, we focus on removal of VOCs and odorants. We also discuss the generation of unwanted air ionization byproducts such as O 3 , NOx, and VOC oxidation intermediates that limit the use of air-ionizers in indoor air quality management. Copyright © 2017. Published by Elsevier Ltd.

  4. Integration of systems biology with organs-on-chips to humanize therapeutic development

    Science.gov (United States)

    Edington, Collin D.; Cirit, Murat; Chen, Wen Li Kelly; Clark, Amanda M.; Wells, Alan; Trumper, David L.; Griffith, Linda G.

    2017-02-01

    "Mice are not little people" - a refrain becoming louder as the gaps between animal models and human disease become more apparent. At the same time, three emerging approaches are headed toward integration: powerful systems biology analysis of cell-cell and intracellular signaling networks in patient-derived samples; 3D tissue engineered models of human organ systems, often made from stem cells; and micro-fluidic and meso-fluidic devices that enable living systems to be sustained, perturbed and analyzed for weeks in culture. Integration of these rapidly moving fields has the potential to revolutionize development of therapeutics for complex, chronic diseases, including those that have weak genetic bases and substantial contributions from gene-environment interactions. Technical challenges in modeling complex diseases with "organs on chips" approaches include the need for relatively large tissue masses and organ-organ cross talk to capture systemic effects, such that current microfluidic formats often fail to capture the required scale and complexity for interconnected systems. These constraints drive development of new strategies for designing in vitro models, including perfusing organ models, as well as "mesofluidic" pumping and circulation in platforms connecting several organ systems, to achieve the appropriate physiological relevance.

  5. Crop-Cattle Integrated Farming System: An Alternative of Climatic Change Mitigation

    Directory of Open Access Journals (Sweden)

    Munandar

    2015-08-01

    Full Text Available An integrated farming system is one of the alternatives for climatic change mitigation. This paper reports the application of corn-cattle based integrated farming system in Agrotechno Park Center of Palembang, and discusses its impact on CO2 fixation and the reduction of methane emissions. The study was based on the data of the first 6 yr from 2003 until 2009. The CO2 fixed in the soil and plants was determined based on the content of organic C which was multiplied by the index of 3.67. The methane gas produced by Balinese cattle and its dung was observed and modified into feed rations. The results showed that soil organic C increased from 40.80 tons C/ha in the 1st yr to 66.40 tons C/ha in the 6th yr. In addition, there was organic C fixation equivalent to 93.95 tons of CO2e. Corn biomass increased from 6.67 tons/ha to 18.66 tons/ha, equivalent to an increase in the fixation of atmospheric CO2e as much as 19.80 tons CO2e/ha. The supplementation of 60%-80% grass fodder with concentrate lowered the concentration of methane gas in cattle breathing by 28.7%, from 617 ppm to 440 ppm, while the methane emissions from cattle manure decreased by 31%, from 1367 mL/head/d to 943 mL/head/d. Installing a bio digester that generates biogas served to accommodate methane gas emissions from cattle dung and used it for bioenergy. Composting reduced the formation of methane gas from cattle manure through a regular process of turning over that gives aeration and forms aerobic condition in the heap of cattle dung. Recycling produces a variety of organic products that store carbon for a longer period of time and slowed the conversion of organic C into CO2. This study showed that the diverse activities of an integrated crop-cattle farming could be an alternative solution to climatic change mitigation.

  6. Integrated diagnostics of northern gas pipelines; Diagnostic integre des gazoducs septentrionaux

    Energy Technology Data Exchange (ETDEWEB)

    Volsky, E.; Dedikov, E.; Ananenkov, A.; Salchov, Z.; Yakupov, Z. [Joint-Stock Company, Gazprom (Russian Federation)

    2000-07-01

    The main part of gas joint - stock company 'Gazprom' extracts from the northern deposits, which are situated in the permafrost zone. Ensuring of gas transporting pipeline's safety operation is a very complex and priority problem. On the basis of usage of this complex of methods the problem to ensure the safety operation is solved systematically: gas-mine - plant IV - derivation pipelines (condensate pipeline Yamburg Novy Urengoy, gas pipeline IV - GCS with negative temperature of transported products) taking into account 'co-ordination' dynamics of changes in pipeline GTS and technological modes of equipment operation. All researches was executed on the high professional level. (authors)

  7. Effect of ranking criteria on development goals in capital and manpower-limited oil and gas organizations

    International Nuclear Information System (INIS)

    Starzer, M.R.

    1991-01-01

    This paper summarizes a study to determine the effect of financial ranking criteria on development goals of oil and gas organizations. Economic analysis and ranking was applied to one hundred projects representing oil and gas investment opportunities available to an organization. Each project's after tax cash flows were subjected to four financial analysis methods for ranking. The four analysis methods used were net present value to investment ratio (NPVI), internal rate of return (IRR), payback period and profit to investment ratio (P/I). After ranking, the projects were totaled according to a particular organizational objective. Totaling of projects by ranking would continue until a limiting resource to the organization was exhausted. This study demonstrates the insensitivity of financial analysis methods for ranking whether the organization is limited by capital or manpower. It concludes that the only requirement for a ranking criterion to properly allocate resources is that the criterion quantifies the organizational goal to some degree. Decision makers charged with selecting the most attractive growth portfolio of investment opportunities will do well with any profit measuring criterion for ranking

  8. Effects of cyclic mean pressure of helium gas on performance of integral crank driven stirling cryocooler

    Energy Technology Data Exchange (ETDEWEB)

    Hong, Yong Ju; Ko, Jun Seok; Kim, Hyo Bong; Park, Seong Je [Korea Institute of Machinery and Materials, Changwon (Korea, Republic of)

    2016-09-15

    An integral crank driven Stirling cryocooler is solidly based on concepts of direct IR detector mounting on the cryocooler's cold finger, and the integral construction of the cryocooler and Dewar envelope. Performance factors of the cryocooler depend on operating conditions of the cryocooler such as a cyclic mean pressure of the working fluid, a rotational speed of driving mechanism, a thermal environment, a targeted operation temperature and etc.. At given charging condition of helium gas, the cyclic mean pressure of helium gas in the cryocooler changes with temperatures of the cold end and the environment. In this study, effects of the cyclic mean pressure of helium gas on performances of the Stirling cryocooler were investigated by numerical analyses using the Sage software. The simulation model takes into account thermodynamic losses due to an inefficiency of regenerator, a pressure drop, a shuttle heat transfer and solid conductions. Simulations are performed for the performance variation according to the cyclic mean pressure induced by the temperature of the cold end and the environment. This paper presents P-V works in the compression and expansion space, cooling capacity, contribution of losses in the expansion space.

  9. Effects of cyclic mean pressure of helium gas on performance of integral crank driven stirling cryocooler

    International Nuclear Information System (INIS)

    Hong, Yong Ju; Ko, Jun Seok; Kim, Hyo Bong; Park, Seong Je

    2016-01-01

    An integral crank driven Stirling cryocooler is solidly based on concepts of direct IR detector mounting on the cryocooler's cold finger, and the integral construction of the cryocooler and Dewar envelope. Performance factors of the cryocooler depend on operating conditions of the cryocooler such as a cyclic mean pressure of the working fluid, a rotational speed of driving mechanism, a thermal environment, a targeted operation temperature and etc.. At given charging condition of helium gas, the cyclic mean pressure of helium gas in the cryocooler changes with temperatures of the cold end and the environment. In this study, effects of the cyclic mean pressure of helium gas on performances of the Stirling cryocooler were investigated by numerical analyses using the Sage software. The simulation model takes into account thermodynamic losses due to an inefficiency of regenerator, a pressure drop, a shuttle heat transfer and solid conductions. Simulations are performed for the performance variation according to the cyclic mean pressure induced by the temperature of the cold end and the environment. This paper presents P-V works in the compression and expansion space, cooling capacity, contribution of losses in the expansion space

  10. Authentication of organically and conventionally grown basils by gas chromatograpy/mass spectrometry chemical profiles

    Science.gov (United States)

    Basil plants cultivated by organic and conventional farming practices were differentiated using gas chromatography/mass spectrometry (GC/MS) and chemometric methods. The two-way GC/MS data sets were baseline-corrected and retention time-aligned prior to data processing. Two self-devised fuzzy clas...

  11. Bottoming organic Rankine cycle for a small scale gas turbine: A comparison of different solutions

    International Nuclear Information System (INIS)

    Clemente, Stefano; Micheli, Diego; Reini, Mauro; Taccani, Rodolfo

    2013-01-01

    Highlights: ► The ORC bottoming section for a commercial micro gas turbine has been studied. ► Six different organic working fluids have been considered and compared. ► The preliminary designs of both axial and radial turbines have been developed. ► Also scroll and reciprocating expanders have been analyzed for comparison. ► The best suited machine has to be selected after a detailed analysis in each case. - Abstract: Recently, several efforts have been devoted to the improvement of the thermal efficiency of small gas turbines, in order to approach the typical values of the internal combustion engines in the same range of power. One possibility is represented by a combined cycle, obtained coupling the gas turbine to a bottoming organic Rankine cycle (ORC). This paper deals with the definition of the main features of an ORC system aimed to recover heat from a 100 kWe commercial gas turbine with internal recuperator. After the optimization of the thermodynamic cycles, involving a comparison between six working fluids, different expanders are analyzed, with the aim of detecting, if possible, the best suited machine. First, single stage turbines, in both radial and axial flow configuration, are designed specifically for each considered fluid, in particular investigating the opportunity of mounting the ORC expander directly on the high-speed shaft of the gas turbine. Then, the performances of these dynamic machines are compared with those of positive displacement expanders, such as scroll devices, obtainable from commercial HVAC compressor with minor revisions, and reciprocating ones, here newly designed

  12. [Treatment of organic waste gas by adsorption rotor].

    Science.gov (United States)

    Zhu, Run-Ye; Zheng, Liang-Wei; Mao, Yu-Bo; Wang, Jia-De

    2013-12-01

    The adsorption rotor is applicable to treating organic waste gases with low concentration and high air volume. The performance of adsorption rotor for purifying organic waste gases was investigated in this paper. Toluene was selected as the simulative gaseous pollutant and the adsorption rotor was packed with honeycomb modified 13X molecular sieves (M-13X). Experimental results of the fixed adsorption and the rotor adsorption were analyzed and compared. The results indicated that some information on the fixed adsorption was useful for the rotor adsorption. Integrating the characteristics of the adsorbents, waste gases and the structures of the rotor adsorption, the formulas on optimal rotor speed and cycle removal efficiency of the adsorption rotor were deduced, based on the mass and heat balances of the adsorbing process. The numerical results were in good agreement with the experimental data, which meant that the formulas on optimal rotor speed and cycle removal efficiency could be effectively applied in design and operation of the adsorption rotor.

  13. Organizing integrated care in a university hospital: application of a conceptual framework.

    Science.gov (United States)

    Axelsson, Runo; Axelsson, Susanna Bihari; Gustafsson, Jeppe; Seemann, Janne

    2014-04-01

    As a result of New Public Management, a number of industrial models of quality management have been implemented in health care, mainly in hospitals. At the same time, the concept of integrated care has been developed within other parts of the health sector. The aim of the article is to discuss the relevance of integrated care for hospitals. The discussion is based on application of a conceptual framework outlining a number of organizational models of integrated care. These models are illustrated in a case study of a Danish university hospital implementing a new organization for improving the patient flows of the hospital. The study of the reorganization is based mainly on qualitative data from individual and focus group interviews. The new organization of the university hospital can be regarded as a matrix structure combining a vertical integration of clinical departments with a horizontal integration of patient flows. This structure has elements of both interprofessional and interorganizational integration. A strong focus on teamwork, meetings and information exchange is combined with elements of case management and co-location. It seems that integrated care can be a relevant concept for a hospital. Although the organizational models may challenge established professional boundaries and financial control systems, this concept can be a more promising way to improve the quality of care than the industrial models that have been imported into health care. This application of the concept may also contribute to widen the field of integrated care.

  14. The welfare effects of unbundling gas storage and distribution

    International Nuclear Information System (INIS)

    Breton, Michele; Kharbach, Mohammed

    2008-01-01

    We use a stylized gas system to study the use of access-to-gas storage in a seasonal model. In a duopoly setting, we find that welfare is higher under vertical integration and open access organization than under separate management of storage and distribution. This raises questions about recent regulatory reforms in the gas sectors in the US and Europe, supporting the separation of storage and merchant activities. In the absence of other justifying reasons such as encouraging competition by creating a level playing field, separating the management and accounting functions of storage activities from those of distribution may be a better option than real divestiture, on the basis of welfare arguments. (author)

  15. Passive sampling of selected endocrine disrupting compounds using polar organic chemical integrative samplers

    International Nuclear Information System (INIS)

    Arditsoglou, Anastasia; Voutsa, Dimitra

    2008-01-01

    Two types of polar organic chemical integrative samplers (pharmaceutical POCIS and pesticide POCIS) were examined for their sampling efficiency of selected endocrine disrupting compounds (EDCs). Laboratory-based calibration of POCISs was conducted by exposing them at high and low concentrations of 14 EDCs (4-alkyl-phenols, their ethoxylate oligomers, bisphenol A, selected estrogens and synthetic steroids) for different time periods. The kinetic studies showed an integrative uptake up to 28 days. The sampling rates for the individual compounds were obtained. The use of POCISs could result in an integrative approach to the quality status of the aquatic systems especially in the case of high variation of water concentrations of EDCs. The sampling efficiency of POCISs under various field conditions was assessed after their deployment in different aquatic environments. - Calibration and field performance of polar organic integrative samplers for monitoring EDCs in aquatic environments

  16. Organic contamination of ground water at Gas Works Park, Seattle, Washington

    International Nuclear Information System (INIS)

    Turney, G.L.; Goerlitz, D.F.

    1990-01-01

    Gas Works Park, in Seattle, Washington, is located on the site of a coal and oil gasification plant that ceased operation in 1956. During operation, many types of wastes, including coal, tar, and oil, accumulated on-site. The park soil is currently (1986) contaminated with compounds such as polynuclear aromatic hydrocarbons, volatile organic compounds, trace metals, and cyanide. Analyses of water samples from a network of observation wells in the park indicate that these compounds are also present in the ground water. Polynuclear aromatic hydrocarbons and volatile organic compounds were identified in ground water samples in concentrations as large as 200 mg/L. Concentrations of organic compounds were largest where ground water was in contact with a non-aqueous phase liquid in the soil. Where no non-aqueous phase liquid was present, concentrations were much smaller, even if the ground water was in contact with contaminated soils. This condition is attributed to weathering processes in which soluble, low-molecular-weight organic compounds are preferentially dissolved from the non-aqueous phase liquid into the ground water. Where no non-aqueous phase liquid is present, only stained soils containing relatively insoluble, high-molecular-weight compounds remain. Concentrations of organic contaminants in the soils may still remain large

  17. Organic contamination of ground water at Gas Works Park, Seattle, Washington

    Science.gov (United States)

    Turney, G.L.; Goerlitz, D.F.

    1990-01-01

    Gas Works Park, in Seattle, Washington, is located on the site of a coal and oil gasification plant that ceased operation in 1956. During operation, many types of wastes, including coal, tar, and oil, accumulated on-site. The park soil is currently (1986) contaminated with compounds such as polynuclear aromatic hydrocarbons, volatile organic compounds, trace metals, and cyanide. Analyses of water samples from a network of observation wells in the park indicate that these compounds are also present in the ground water. Polynuclear aromatic hydrocarbons and volatile organic compounds were identified in ground water samples in concentrations as large as 200 mg/L. Concentrations of organic compounds were largest where ground water was in contact with a non-aqueous phase liquid in the soil. Where no non-aqueous phase liquid was present, concentrations were much smaller, even if the ground water was in contact with contaminated soils. This condition is attributed to weathering processes in which soluble, low-molecular-weight organic compounds are preferentially dissolved from the non-aqueous phase liquid into the ground water. Where no non-aqueous phase liquid is present, only stained soils containing relatively insoluble, high-molecular-weight compounds remain. Concentrations of organic contaminants in the soils may still remain large.

  18. Characterization of Crew Refuse Returned from Shuttle Missions with Permanent Gas, Volatile Organic Compound, and Microbial Analyses

    Science.gov (United States)

    Peterson, B.; Hummerick, M.; Roberts, M.; Krummins, V.; Kish, A.; Garland, J.; Maxwell, S.; Mills, A.

    In addition to the mass and energy costs associated with bioregenerative systems for advanced life support, the storage and processing of waste on spacecraft requires both atmospheric and biological management. Risks to crew health may arise from the presence of potential human pathogens in waste or from decay processes during waste storage and/or processing. This study reports on the permanent gas, trace volatile organic and microbiological analyses of crew refuse returned from shuttle missions STS-105, 109 and 110. The research objective is to characterize the biological stability of the waste stream, to assess the risks associated with its storage, and to provide baseline measures for the evaluation of waste processing technologies. Microbiological samples were collected from packaging material, food waste, bathroom waste, and bulk liquid collected from the volume F waste container. The number of culturable bacteria and total bacteria were determined by plating on R2A media and by Acridine Orange direct count, respectively. Samples of the trash were analyzed for the presence of fecal and total coliforms and other human-associated bacteria. Dry and ash weights were determined to estimate both water and organic content of the materials. The aerobic and anaerobic bio-stability of stored waste was determined by on-line monitoring of CO2 and by laboratory analysis of off-gas samples for hydrogen sulfide and methane. Volatile organic compounds and permanent gases were analyzed using EPA method TO15 with gas chromatography/mass spectrometry and by gas chromatography with selective detectors . This study establishes a baseline measure of waste composition, labile organics, and microbial load for this material.

  19. The Oil and Gas Discourse from the Perspective of the Canadian and Albertan Governments, Non-Governmental Organizations and the Oil and Gas Industry

    Directory of Open Access Journals (Sweden)

    Jacqueline Noga

    2014-01-01

    Full Text Available Three of the major players in the discussion of the production of oil and gas are: (1 government; (2 the oil and gas industry and (3 non-governmental organizations (NGOs. A comparison of contributions from these three sources using a list of positive and negative words from the General Inquirer Category Listings showed that industry provided a very positive message about the production and consumption of oil and gas that is generally reinforced by government whereas NGOs advocated for a reduction in the use of oil and gas. Messages delivered by each player are focused on the same topics in either a positive or negative way and are often contradictory. The authors submit to be properly informed the public must consider all the sources in order to avoid bias. A mind map is presented in a supplementary file which summarizes information from each source in a comprehensive way. This approach can be used by consumers when considering the choice of using oil and gas and can be extended to the discourse beyond Canada.

  20. Organic unity theory: an integrative mind-body theory for psychiatry.

    Science.gov (United States)

    Goodman, A

    1997-12-01

    The potential of psychiatry as an integrative science has been impeded by an internal schism that derives from the duality of mental and physical. Organic unity theory is proposed as a conceptual framework that brings together the terms of the mind-body duality in one coherent perspective. Organic unity theory is braided of three strands: identity, which describes the relationship between mentally described events and corresponding physically described events; continuity, which describes the linguistic-conceptual system that contains both mental and physical terms; and dialectic, which describes the relationship between the empirical way of knowing that is associated with the physical domain of the linguistic-conceptual system and the hermeneutic way of knowing that is associated with the mental domain. Each strand represents an integrative formulation that resolves an aspect of mental-physical dualism into an underlying unity. After the theory is presented, its implications for psychiatry are briefly considered.

  1. Organic waste processing using molten salt oxidation

    Energy Technology Data Exchange (ETDEWEB)

    Adamson, M. G., LLNL

    1998-03-01

    Molten Salt Oxidation (MSO) is a thermal means of oxidizing (destroying) the organic constituents of mixed wastes, hazardous wastes, and energetic materials while retaining inorganic and radioactive constituents in the salt. For this reason, MSO is considered a promising alternative to incineration for the treatment of a variety of organic wastes. The U. S. Department of Energy`s Office of Environmental Management (DOE/EM) is currently funding research that will identify alternatives to incineration for the treatment of organic-based mixed wastes. (Mixed wastes are defined as waste streams which have both hazardous and radioactive properties.) One such project is Lawrence Livermore National Laboratory`s Expedited Technology Demonstration of Molten Salt Oxidation (MSO). The goal of this project is to conduct an integrated demonstration of MSO, including off-gas and spent salt treatment, and the preparation of robust solid final forms. Livermore National Laboratory (LLNL) has constructed an integrated pilot-scale MSO treatment system in which tests and demonstrations are presently being performed under carefully controlled (experimental) conditions. The system consists of a MSO process vessel with dedicated off-gas treatment, a salt recycle system, feed preparation equipment, and equipment for preparing ceramic final waste forms. In this paper we describe the integrated system and discuss its capabilities as well as preliminary process demonstration data. A primary purpose of these demonstrations is to identify the most suitable waste streams and waste types for MSO treatment.

  2. Cochlear condition and olivocochlear system of gas station attendants exposed to organic solvents

    Directory of Open Access Journals (Sweden)

    Tochetto, Tania Maria

    2012-01-01

    Full Text Available Introduction: Organic solvents have been increasingly studied due to its ototoxic action. Objective: Evaluate the conditions of outer hair cells and olivocochlear system in individuals exposed to organic solvents. Method: This is a prospective study. 78 gas station attendants exposed to organic solvents had been evaluated from three gas stations from Santa Maria city, Rio Grande do Sul (RS. After applying the inclusion criteria, the sample was constituted by 24 individuals. The procedures used on the evaluation were audiological anamnesis, Transient otoacoustic emissions (TEOAES and research for the suppressive effect of TEOAES. A group control (GC compounded by 23 individuals was compared to individuals exposed and non-exposed individuals. The data collection has been done in the room of Speech Therapy of Workers Health Reference Center of Santa Maria. Results: The TEOAES presence was major in the left ear in both groups; the average relation of TEOAES signal/noise in both ears was greater in GE; the TEOAES suppressive effect in the right ear was higher in the individual of GE (62,5% and in the left ear was superior in GC (86,96%, with statistically significant difference. The median sign/noise ratio of TEOAES, according to the frequency range, it was higher in GC in three frequencies ranges in the right ear and one in the left ear. Conclusion: It was not found signs of alteration on the outer hair cells neither on the olivocochlear medial system in the individuals exposed to organic solvents.

  3. Recovery of flue gas energy in heat integrated IGCC power plants using the contact economizer system

    CSIR Research Space (South Africa)

    Madzivhandila, V

    2010-10-01

    Full Text Available Asia Pacific Confederation of APCChE 2010 Chemical Engineering Congress October 5-8, 2010, Taipei � �� Recovery of flue gas energy in heat integrated IGCC power plants using the contact economizer system Vhutshilo Madzivhandilaa, Thokozani... temperature and the thermal efficiency of the plant. The 13th Asia Pacific Confederation of APCChE 2010 Chemical Engineering Congress October 5-8, 2010, Taipei � �� 1. Introduction The IGCC (Integrated Gasification Combined Cycle) is one...

  4. Automatic isotope gas analysis of tritium labelled organic materials Pt. 3

    International Nuclear Information System (INIS)

    Gacs, I.; Mlinko, S.; Payer, K.; Otvos, L.; Banfi, D.; Palagyi, T.

    1978-01-01

    An isotope analytical procedure and an automatic instrument developed for the determination of tritium in organic compounds and biological materials by internal gas counting are described. The sample is burnt in a stream of oxygen and the combustion products including water vapour carrying the tritium are led onto a column of molecular sieve-5A heated to 550 deg C. Tritium is retained temporarily on the column, then transferred into a stream of hydrogen by isotope exchange. After addition of butane, the tritiated hydrogen is led into an internal detector and enclosed there for radioactivity measurement. The procedure, providing quantitative recovery, is completed in five minutes. It is free of memory effect and suitable for the determination of tritium in a wide range of organic compounds and samples of biological origin. (author)

  5. A new model for calculating the reduction in greenhouse gas emissions through anaerobic co-digestion of manure and organic waste

    International Nuclear Information System (INIS)

    Sommer, S.G.; Moeller, H.B.; Petersen, S.O.

    2002-01-01

    Biogenic emissions of methane (CH 4 ) and nitrous oxide (N 2 0) occur during handling, storage and after field application of animal manure. The emissions are linked to decomposition of volatile solids (VS), which provide energy for microorganisms. During anaerobic storage, turnover of VS drives the microbial processes which lead to CH 4 , production. Also, turnover of VS in slurry applied to fields will consume oxygen and can thereby stimulate N 2 0 production. Anaerobic digestion of manure and organic wastes for biogas production removes VS prior to storage and field application, and therefore this treatment also reduces the potential for CH 4 , and N 2 0 emissions. A model has been developed to evaluate the effect of anaerobic co-digestion of animal manure and organic waste on CH, and N 2 0 emissions. The model estimates the reduction in VS during storage and digestion, and an algorithm for prediction of CH 4 , emissions from manure during storage relates the emission to VS, temperature and storage time. Nitrous oxide emissions from field-applied slurry are calculated using VS, slurry N, soil water potential and application method as input variables, thus linking C and N turnover. The amount of fossil fuel that is substituted by CH 4 , produced during digestion is also calculated in order to estimate the total effect of anaerobic digestion on greenhouse gas emissions from slurry. Model calculations show the potential of manure digestion to modify the emission of greenhouse gases from agriculture. The experience from application of the model to different scenarios is that the emission of greenhouse gases and their reduction must be calculated with dynamic and integrated models. Specifically, the results indicate that digestion of slurry and organic wastes could reduce Danish greenhouse gas emissions by as much as 3%. (au)

  6. An innovative process for simultaneous removal of CO2 and SO2 from flue gas of a power plant by energy integration

    International Nuclear Information System (INIS)

    Yu, Y.S.; Li, Y.; Li, Q.; Jiang, J.; Zhang, Z.X.

    2009-01-01

    With the fast development of the society, the amount of carbon dioxide has been increased enormously in the atmosphere all over the world, which has already endangered the survival of human being. More and more people or organizations are studying new technologies to reduce the cost of capturing CO 2 . The recovery and sequestration of CO 2 from flue gas of the power plant is regarded as a feasible way to mitigate the greenhouse gas emissions. Therefore, the process of recovering carbon dioxide by chemical absorption with monoethanolamine (MEA) in industry was emphatically described in this paper. Based on energy integration, a coupled process was proposed which included MEA absorption of CO 2 and SO 2 , and the heat recovery from the flue gas's waste heat recovery unit and compressor inter-stage cooling unit. Compared the innovative process with an original process, 9% of thermal energy could be reduced in the new flowsheet. Meanwhile decarbonization and desulphurization could be carried on in the absorber simultaneously without the usual wet flue gas desulphurization (FGD) system. An exergy analysis model was established and validated by the literature data with a deviation less than 5.40%. The exergy results indicated that the exergy loss of the improved process was 15.48-20.75% less than that of the original one, which proved that the innovative process was reasonable and effective from the perspective of energy utilization.

  7. Integrated strategy for N-methylformanilide production from carbon dioxide of flue gas in coal-fired power plant

    International Nuclear Information System (INIS)

    Han, Jeehoon

    2017-01-01

    Highlights: • A ‘green’ N-methylformanilide production process based new carbon dioxide conversion technologies is developed. • Monoethanolamine-based system for capturing carbon dioxide from the flue gas of a coal-fired power plant is deployed. • Gamma-valerolactone is used a solvent and catalyst for converting carbon dioxide to N-methylformanilide. • New separations for recovery of N-methylformanilide and gamma-valerolactone are developed. • Economic evaluation of the proposed process is performed. - Abstract: In this work, an integrated strategy is developed for producing N-methylformanilide from the carbon dioxide of flue gas in a coal-fired power plant. Based on lab-scale experimental studies presenting maximum yields (96%) with low reaction concentrations (below 25 wt% reactants) using large volumes of gamma-valerolactone as a solvent and catalyst, the integrated strategy focuses on the development of commercial-scale processes that consist of a monoethanolamine-based carbon dioxide separation subsystem and a catalytic conversion subsystem of N-Methylaniline with carbon dioxide to N-methylformanilide. Moreover, a heat exchanger network is designed to minimize the total energy requirements by transferring the heat between subsystems. In the proposed integrated strategy, the energy efficiency after heat integration (77.5%) is higher than that before heat integration (74.5%). Economic analysis results show that the minimum selling price of N-methylformanilide ($1592.1 Mt"−"1 using the best possible parameters) for use in this integrated strategy is cost-competitive with the current market price ($2984 Mt"−"1).

  8. An Image-based Micro-continuum Pore-scale Model for Gas Transport in Organic-rich Shale

    Science.gov (United States)

    Guo, B.; Tchelepi, H.

    2017-12-01

    Gas production from unconventional source rocks, such as ultra-tight shales, has increased significantly over the past decade. However, due to the extremely small pores ( 1-100 nm) and the strong material heterogeneity, gas flow in shale is still not well understood and poses challenges for predictive field-scale simulations. In recent years, digital rock analysis has been applied to understand shale gas transport at the pore-scale. An issue with rock images (e.g. FIB-SEM, nano-/micro-CT images) is the so-called "cutoff length", i.e., pores and heterogeneities below the resolution cannot be resolved, which leads to two length scales (resolved features and unresolved sub-resolution features) that are challenging for flow simulations. Here we develop a micro-continuum model, modified from the classic Darcy-Brinkman-Stokes framework, that can naturally couple the resolved pores and the unresolved nano-porous regions. In the resolved pores, gas flow is modeled with Stokes equation. In the unresolved regions where the pore sizes are below the image resolution, we develop an apparent permeability model considering non-Darcy flow at the nanoscale including slip flow, Knudsen diffusion, adsorption/desorption, surface diffusion, and real gas effect. The end result is a micro-continuum pore-scale model that can simulate gas transport in 3D reconstructed shale images. The model has been implemented in the open-source simulation platform OpenFOAM. In this paper, we present case studies to demonstrate the applicability of the model, where we use 3D segmented FIB-SEM and nano-CT shale images that include four material constituents: organic matter, clay, granular mineral, and pore. In addition to the pore structure and the distribution of the material constituents, we populate the model with experimental measurements (e.g. size distribution of the sub-resolution pores from nitrogen adsorption) and parameters from the literature and identify the relative importance of different

  9. Organic pollutants in shale gas flowback and produced waters : identification, potential ecological impact and implications for treatment strategies

    NARCIS (Netherlands)

    Butkovskyi, Andrii; Bruning, Harry; Kools, Stefan A E; Rijnaarts, Huub H M; van Wezel, Annemarie P

    2017-01-01

    Organic contaminants in shale gas flowback and produced water (FPW) are traditionally expressed as total organic carbon (TOC) or chemical oxygen demand (COD), though these parameters do not provide information on the toxicity and environmental fate of individual components. This review addresses

  10. The Russian strategy of gas export: Europe against Asia?

    International Nuclear Information System (INIS)

    Locatelli, C.

    2005-01-01

    Can we say that today's gas strategy of Russia is the continuation of the one implemented by the former USSR? Three factors have to be taken into consideration: the liberalization of the European gas market is a major stake with lot of constraints but also lot of opportunities. This deregulation may lead to sensible evolutions of the organization of Russia's gas industry since the question of gas supply costs has to face the competition that should develop in the European market. Also, the possible integration of some Central and Eastern Europe countries to the European Union, which are important transit ways for the Russian gas exports towards Western Europe, but which are also markets where Gazprom has been the quasi-exclusive gas supplier so far. Finally, Europe is no longer the only goal of Russian gas exports: Gazprom clearly shows its will of defining a global export strategy. With about 40% of the world gas reserves, Russia definitely has a master card to play on the international energy markets. (J.S.)

  11. Organizing integrated care in a university hospital: application of a conceptual framework

    Directory of Open Access Journals (Sweden)

    Runo Axelsson

    2014-06-01

    Full Text Available Background and aim: As a result of New Public Management, a number of industrial models of quality management have been implemented in health care, mainly in hospitals. At the same time, the concept of integrated care has been developed within other parts of the health sector. The aim of the article is to discuss the relevance of integrated care for hospitals.Theory and methods: The discussion is based on application of a conceptual framework outlining a number of organizational models of integrated care. These models are illustrated in a case study of a Danish university hospital implementing a new organization for improving the patient flows of the hospital. The study of the reorganization is based mainly on qualitative data from individual and focus group interviews.Results: The new organization of the university hospital can be regarded as a matrix structure combining a vertical integration of clinical departments with a horizontal integration of patient flows. This structure has elements of both interprofessional and interorganizational integration. A strong focus on teamwork, meetings and information exchange is combined with elements of case management and co-location.Conclusions: It seems that integrated care can be a relevant concept for a hospital. Although the organizational models may challenge established professional boundaries and financial control systems, this concept can be a more promising way to improve the quality of care than the industrial models that have been imported into health care. This application of the concept may also contribute to widen the field of integrated care.

  12. Organizing integrated care in a university hospital: application of a conceptual framework

    Directory of Open Access Journals (Sweden)

    Runo Axelsson

    2014-06-01

    Full Text Available Background and aim: As a result of New Public Management, a number of industrial models of quality management have been implemented in health care, mainly in hospitals. At the same time, the concept of integrated care has been developed within other parts of the health sector. The aim of the article is to discuss the relevance of integrated care for hospitals. Theory and methods: The discussion is based on application of a conceptual framework outlining a number of organizational models of integrated care. These models are illustrated in a case study of a Danish university hospital implementing a new organization for improving the patient flows of the hospital. The study of the reorganization is based mainly on qualitative data from individual and focus group interviews. Results: The new organization of the university hospital can be regarded as a matrix structure combining a vertical integration of clinical departments with a horizontal integration of patient flows. This structure has elements of both interprofessional and interorganizational integration. A strong focus on teamwork, meetings and information exchange is combined with elements of case management and co-location. Conclusions: It seems that integrated care can be a relevant concept for a hospital. Although the organizational models may challenge established professional boundaries and financial control systems, this concept can be a more promising way to improve the quality of care than the industrial models that have been imported into health care. This application of the concept may also contribute to widen the field of integrated care.

  13. Organizing integrated care in a university hospital: application of a conceptual framework

    Science.gov (United States)

    Axelsson, Runo; Axelsson, Susanna Bihari; Gustafsson, Jeppe; Seemann, Janne

    2014-01-01

    Background and aim As a result of New Public Management, a number of industrial models of quality management have been implemented in health care, mainly in hospitals. At the same time, the concept of integrated care has been developed within other parts of the health sector. The aim of the article is to discuss the relevance of integrated care for hospitals. Theory and methods The discussion is based on application of a conceptual framework outlining a number of organizational models of integrated care. These models are illustrated in a case study of a Danish university hospital implementing a new organization for improving the patient flows of the hospital. The study of the reorganization is based mainly on qualitative data from individual and focus group interviews. Results The new organization of the university hospital can be regarded as a matrix structure combining a vertical integration of clinical departments with a horizontal integration of patient flows. This structure has elements of both interprofessional and interorganizational integration. A strong focus on teamwork, meetings and information exchange is combined with elements of case management and co-location. Conclusions It seems that integrated care can be a relevant concept for a hospital. Although the organizational models may challenge established professional boundaries and financial control systems, this concept can be a more promising way to improve the quality of care than the industrial models that have been imported into health care. This application of the concept may also contribute to widen the field of integrated care. PMID:24966806

  14. INTEGRATION OF MANAGEMENT SYSTEM QMS/EMS/OHSAS/FMS/LMS IN WATER SUPPLY ORGANIZATION

    Directory of Open Access Journals (Sweden)

    Slavko Arsovski

    2007-12-01

    Full Text Available Level of difficulties arises when goes up number of integrated management systems (IMS. In this paper are given model and empirical research which provide the details of an integrated management system with five component subsystems in area of water supply. Presented model addresses the issues of scope and carracterisctics based on process approach and is tested in water supply organization in Kragujevac, Serbia. Testing in the proposed model is accomplish through realization project of design and implementation of IMS in regional water supply organization in Kragujevac.

  15. Analysis of a gas-liquid film plasma reactor for organic compound oxidation

    Energy Technology Data Exchange (ETDEWEB)

    Hsieh, Kevin [Department of Chemical and Biomedical Engineering, Florida State University, Tallahassee, FL 32310 (United States); Wang, Huijuan [School of Environmental and Safety Engineering, Jiangsu University, Zhenjiang 212013 (China); Locke, Bruce R., E-mail: blocke@fsu.edu [Department of Chemical and Biomedical Engineering, Florida State University, Tallahassee, FL 32310 (United States)

    2016-11-05

    Highlights: • Non-homogeneous filamentary plasma discharge formed along gas-liquid interface. • Hydrogen peroxide formed near interface favored over organic oxidation from liquid. • Post-plasma Fenton reactions lead to complete utilization of hydrogen peroxide. - Abstract: A pulsed electrical discharge plasma formed in a tubular reactor with flowing argon carrier gas and a liquid water film was analyzed using methylene blue as a liquid phase hydroxyl radical scavenger and simultaneous measurements of hydrogen peroxide formation. The effects of liquid flow rate, liquid conductivity, concentration of dye, and the addition of ferrous ion on dye decoloration and degradation were determined. Higher liquid flow rates and concentrations of dye resulted in less decoloration percentages and hydrogen peroxide formation due to initial liquid conductivity effects and lower residence times in the reactor. The highest decoloration energy yield of dye found in these studies was 5.2 g/kWh when using the higher liquid flow rate and adding the catalyst. The non-homogeneous nature of the plasma discharge favors the production of hydrogen peroxide in the plasma-liquid interface over the chemical oxidation of the organic in the bulk liquid phase and post-plasma reactions with the Fenton catalyst lead to complete utilization of the plasma-formed hydrogen peroxide.

  16. Improving the organization of the outfitting of gas and oil fields in a unitized design

    Energy Technology Data Exchange (ETDEWEB)

    Berezin, V.L.; Kurepin, B.N.; Sivergin, M.Yu.; Telegin, L.G.

    1985-01-01

    The basic tenets of the organization of outfitting gas and oil fields in a unitized design are examined. An economic and mathematical model for selecting a variant for transporting unitized devices is proposed in which the transport expenditures are minimal.

  17. Integrated materials design of organic semiconductors for field-effect transistors.

    Science.gov (United States)

    Mei, Jianguo; Diao, Ying; Appleton, Anthony L; Fang, Lei; Bao, Zhenan

    2013-05-08

    The past couple of years have witnessed a remarkable burst in the development of organic field-effect transistors (OFETs), with a number of organic semiconductors surpassing the benchmark mobility of 10 cm(2)/(V s). In this perspective, we highlight some of the major milestones along the way to provide a historical view of OFET development, introduce the integrated molecular design concepts and process engineering approaches that lead to the current success, and identify the challenges ahead to make OFETs applicable in real applications.

  18. Catalyst-Free Vapor-Phase Method for Direct Integration of Gas Sensing Nanostructures with Polymeric Transducing Platforms

    Directory of Open Access Journals (Sweden)

    Stella Vallejos

    2014-01-01

    Full Text Available Tungsten oxide nanoneedles (NNs are grown and integrated directly with polymeric transducing platforms for gas sensors via aerosol-assisted chemical vapor deposition (AACVD method. Material analysis shows the feasibility to grow highly crystalline nanomaterials in the form of NNs with aspect ratios between 80 and 200 and with high concentration of oxygen vacancies at the surface, whereas gas testing demonstrates moderate sensing responses to hydrogen at concentrations between 10 ppm and 50 ppm, which are comparable with results for tungsten oxide NNs grown on silicon transducing platforms. This method is demonstrated to be an attractive route to fabricate next generation of gas sensors devices, provided with flexibility and functionality, with great potential in a cost effective production for large-scale applications.

  19. Thermodynamic modeling and evaluation of high efficiency heat pipe integrated biomass Gasifier–Solid Oxide Fuel Cells–Gas Turbine systems

    International Nuclear Information System (INIS)

    Santhanam, S.; Schilt, C.; Turker, B.; Woudstra, T.; Aravind, P.V.

    2016-01-01

    This study deals with the thermodynamic modeling of biomass Gasifier–SOFC (Solid Oxide Fuel Cell)–GT (Gas Turbine) systems on a small scale (100 kW_e). Evaluation of an existing biomass Gasifier–SOFC–GT system shows highest exergy losses in the gasifier, gas turbine and as waste heat. In order to reduce the exergy losses and increase the system's efficiency, improvements are suggested and the effects are analyzed. Changing the gasifying agent for air to anode gas gave the largest increase in the electrical efficiency. However, heat is required for an allothermal gasification to take place. A new and simple strategy for heat pipe integration is proposed, with heat pipes placed in between stacks in series, rather than the widely considered approach of integrating the heat pipes within the SOFC stacks. The developed system based on a Gasifier–SOFC–GT combination improved with heat pipes and anode gas recirculation, increases the electrical efficiency from approximately 55%–72%, mainly due to reduced exergy losses in the gasifier. Analysis of the improved system shows that operating the system at possibly higher operating pressures, yield higher efficiencies within the range of the operating pressures studied. Further the system was scaled up with an additional bottoming cycle achieved electrical efficiency of 73.61%. - Highlights: • A new and simple strategy for heat pipe integration between SOFC and Gasifier is proposed. • Anode exhaust gas is used as a gasifying agent. • The new proposed Gasifier–SOFC–GT system achieves electrical efficiency of 72%. • Addition of steam rankine bottoming cycle to proposed system increases electrical efficiency to 73.61%.

  20. A monolithically fabricated gas chromatography separation column with an integrated high sensitivity thermal conductivity detector

    International Nuclear Information System (INIS)

    Kaanta, Bradley C; Zhang, Xin; Chen, Hua

    2010-01-01

    The monolithic integration of a high sensitivity detector with a gas chromatography (GC) separation column creates many potential advantages over the discrete components of a traditional chromatography system. In miniaturized high-speed GC systems, component interconnections can cause crucial errors and loss of fidelity during detection and analysis. A monolithically integrated device would eliminate the need to create helium-tight interconnections, which are bulky and labor intensive. Additionally, batch fabrication of integrated devices that no longer require expensive and fragile detectors can decrease the cost of micro GC systems through economies of scale. We present the design, fabrication and operation of a monolithic GC separation column and detector. Our device is able to separate nitrogen, methane and carbon dioxide within 30 s. This method of device integration could be applied to the existing wealth of column geometries and chemistries designed for specialized applications.

  1. Using dissolved gas analysis to investigate the performance of an organic carbon permeable reactive barrier for the treatment of mine drainage

    Science.gov (United States)

    Williams, R.L.; Mayer, K.U.; Amos, R.T.; Blowes, D.W.; Ptacek, C.J.; Bain, J.G.

    2007-01-01

    The strongly reducing nature of permeable reactive barrier (PRB) treatment materials can lead to gas production, potentially resulting in the formation of gas bubbles and ebullition. Degassing in organic C based PRB systems due to the production of gases (primarily CO2 and CH4) is investigated using the depletion of naturally occurring non-reactive gases Ar and N2, to identify, confirm, and quantify chemical and physical processes. Sampling and analysis of dissolved gases were performed at the Nickel Rim Mine Organic Carbon PRB, which was designed for the treatment of groundwater contaminated by low quality mine drainage characterized by slightly acidic pH, and elevated Fe(II) and SO4 concentrations. A simple 4-gas degassing model was used to analyze the dissolved gas data, and the results indicate that SO4 reduction is by far the dominant process of organic C consumption within the barrier. The data provided additional information to delineate rates of microbially mediated SO4 reduction and confirm the presence of slow and fast flow zones within the barrier. Degassing was incorporated into multicomponent reactive transport simulations for the barrier and the simulations were successful in reproducing observed dissolved gas trends.

  2. Integration of Substance Abuse Treatment Organizations into Accountable Care Organizations: Results from a National Survey

    Science.gov (United States)

    D’Aunno, Thomas; Friedmann, Peter D.; Chen, Qixuan; Wilson, Donna M.

    2016-01-01

    To meet their aims of managing population health to improve the quality and cost of health care in the United States, accountable care organizations (ACOs) will need to focus on coordinating care for individuals with substance abuse disorders. The prevalence of these disorders is high, and these individuals often suffer from comorbid chronic medical and social conditions. This article examines the extent to which the nation’s fourteen thousand specialty substance abuse treatment (SAT) organizations, which have a daily census of more than 1 million patients, are contracting with ACOs across the country; we also examine factors associated with SAT organization involvement with ACOs. We draw on data from a recent (2014) nationally representative survey of executive directors and clinical supervisors from 635 SAT organizations. Results show that only 15 percent of these organizations had signed contracts with ACOs. Results from multivariate analyses show that directors’ perceptions of market competition, organizational ownership, and geographic location are significantly related to SATinvolvement with ACOs. We discuss implications for integrating the SAT specialty system with the mainstream health care system. PMID:26124307

  3. Segmentation of Natural Gas Customers in Industrial Sector Using Self-Organizing Map (SOM) Method

    Science.gov (United States)

    Masbar Rus, A. M.; Pramudita, R.; Surjandari, I.

    2018-03-01

    The usage of the natural gas which is non-renewable energy, needs to be more efficient. Therefore, customer segmentation becomes necessary to set up a marketing strategy to be right on target or to determine an appropriate fee. This research was conducted at PT PGN using one of data mining method, i.e. Self-Organizing Map (SOM). The clustering process is based on the characteristic of its customers as a reference to create the customer segmentation of natural gas customers. The input variables of this research are variable of area, type of customer, the industrial sector, the average usage, standard deviation of the usage, and the total deviation. As a result, 37 cluster and 9 segment from 838 customer data are formed. These 9 segments then employed to illustrate the general characteristic of the natural gas customer of PT PGN.

  4. Direct Structural Identification of Gas Induced Gate-Opening Coupled with Commensurate Adsorption in a Microporous Metal-Organic Framework.

    Science.gov (United States)

    Banerjee, Debasis; Wang, Hao; Plonka, Anna M; Emge, Thomas J; Parise, John B; Li, Jing

    2016-08-08

    Gate-opening is a unique and interesting phenomenon commonly observed in flexible porous frameworks, where the pore characteristics and/or crystal structures change in response to external stimuli such as adding or removing guest molecules. For gate-opening that is induced by gas adsorption, the pore-opening pressure often varies for different adsorbate molecules and, thus, can be applied to selectively separate a gas mixture. The detailed understanding of this phenomenon is of fundamental importance to the design of industrially applicable gas-selective sorbents, which remains under investigated due to the lack of direct structural evidence for such systems. We report a mechanistic study of gas-induced gate-opening process of a microporous metal-organic framework, [Mn(ina)2 ] (ina=isonicotinate) associated with commensurate adsorption, by a combination of several analytical techniques including single crystal X-ray diffraction, in situ powder X-ray diffraction coupled with differential scanning calorimetry (XRD-DSC), and gas adsorption-desorption methods. Our study reveals that the pronounced and reversible gate opening/closing phenomena observed in [Mn(ina)2 ] are coupled with a structural transition that involves rotation of the organic linker molecules as a result of interaction of the framework with adsorbed gas molecules including carbon dioxide and propane. The onset pressure to open the gate correlates with the extent of such interaction. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  5. Thermo-economic comparative analysis of gas turbine GT10 integrated with air and steam bottoming cycle

    Science.gov (United States)

    Czaja, Daniel; Chmielnak, Tadeusz; Lepszy, Sebastian

    2014-12-01

    A thermodynamic and economic analysis of a GT10 gas turbine integrated with the air bottoming cycle is presented. The results are compared to commercially available combined cycle power plants based on the same gas turbine. The systems under analysis have a better chance of competing with steam bottoming cycle configurations in a small range of the power output capacity. The aim of the calculations is to determine the final cost of electricity generated by the gas turbine air bottoming cycle based on a 25 MW GT10 gas turbine with the exhaust gas mass flow rate of about 80 kg/s. The article shows the results of thermodynamic optimization of the selection of the technological structure of gas turbine air bottoming cycle and of a comparative economic analysis. Quantities are determined that have a decisive impact on the considered units profitability and competitiveness compared to the popular technology based on the steam bottoming cycle. The ultimate quantity that can be compared in the calculations is the cost of 1 MWh of electricity. It should be noted that the systems analyzed herein are power plants where electricity is the only generated product. The performed calculations do not take account of any other (potential) revenues from the sale of energy origin certificates. Keywords: Gas turbine air bottoming cycle, Air bottoming cycle, Gas turbine, GT10

  6. Complex organic molecules in strongly UV-irradiated gas

    Science.gov (United States)

    Cuadrado, S.; Goicoechea, J. R.; Cernicharo, J.; Fuente, A.; Pety, J.; Tercero, B.

    2017-07-01

    We investigate the presence of complex organic molecules (COMs) in strongly UV-irradiated interstellar molecular gas. We have carried out a complete millimetre (mm) line survey using the IRAM 30 m telescope towards the edge of the Orion Bar photodissociation region (PDR), close to the H2 dissociation front, a position irradiated by a very intense far-UV (FUV) radiation field. These observations have been complemented with 8.5'' resolution maps of the H2CO JKa,Kc = 51,5 → 41,4 and C18O J = 3 → 2 emission at 0.9 mm. Despite being a harsh environment, we detect more than 250 lines from COMs and related precursors: H2CO, CH3OH, HCO, H2CCO, CH3CHO, H2CS, HCOOH, CH3CN, CH2NH, HNCO, H213CO, and HC3N (in decreasing order of abundance). For each species, the large number of detected lines allowed us to accurately constrain their rotational temperatures (Trot) and column densities (N). Owing to subthermal excitation and intricate spectroscopy of some COMs (symmetric- and asymmetric-top molecules such as CH3CN and H2CO, respectively), a correct determination of N and Trot requires building rotational population diagrams of their rotational ladders separately. The inferred column densities are in the 1011-1013 cm-2 range. We also provide accurate upper limit abundances for chemically related molecules that might have been expected, but are not conclusively detected at the edge of the PDR (HDCO, CH3O, CH3NC, CH3CCH, CH3OCH3, HCOOCH3, CH3CH2OH, CH3CH2CN, and CH2CHCN). A non-thermodynamic equilibrium excitation analysis for molecules with known collisional rate coefficients suggests that some COMs arise from different PDR layers but we cannot resolve them spatially. In particular, H2CO and CH3CN survive in the extended gas directly exposed to the strong FUV flux (Tk = 150-250 K and Td≳ 60 K), whereas CH3OH only arises from denser and cooler gas clumps in the more shielded PDR interior (Tk = 40-50 K). The non-detection of HDCO towards the PDR edge is consistent with the

  7. A highly selective and self-powered gas sensor via organic surface functionalization of p-Si/n-ZnO diodes.

    Science.gov (United States)

    Hoffmann, Martin W G; Mayrhofer, Leonhard; Casals, Olga; Caccamo, Lorenzo; Hernandez-Ramirez, Francisco; Lilienkamp, Gerhard; Daum, Winfried; Moseler, Michael; Waag, Andreas; Shen, Hao; Prades, J Daniel

    2014-12-17

    Selectivity and low power consumption are major challenges in the development of sophisticated gas sensor devices. A sensor system is presented that unifies selective sensor-gas interactions and energy-harvesting properties, using defined organic-inorganic hybrid materials. Simulations of chemical-binding interactions and the consequent electronic surface modulation give more insight into the complex sensing mechanism of selective gas detection. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  8. Optimal integration strategies for a syngas fuelled SOFC and gas turbine hybrid

    Science.gov (United States)

    Zhao, Yingru; Sadhukhan, Jhuma; Lanzini, Andrea; Brandon, Nigel; Shah, Nilay

    This article aims to develop a thermodynamic modelling and optimization framework for a thorough understanding of the optimal integration of fuel cell, gas turbine and other components in an ambient pressure SOFC-GT hybrid power plant. This method is based on the coupling of a syngas-fed SOFC model and an associated irreversible GT model, with an optimization algorithm developed using MATLAB to efficiently explore the range of possible operating conditions. Energy and entropy balance analysis has been carried out for the entire system to observe the irreversibility distribution within the plant and the contribution of different components. Based on the methodology developed, a comprehensive parametric analysis has been performed to explore the optimum system behavior, and predict the sensitivity of system performance to the variations in major design and operating parameters. The current density, operating temperature, fuel utilization and temperature gradient of the fuel cell, as well as the isentropic efficiencies and temperature ratio of the gas turbine cycle, together with three parameters related to the heat transfer between subsystems are all set to be controllable variables. Other factors affecting the hybrid efficiency have been further simulated and analysed. The model developed is able to predict the performance characteristics of a wide range of hybrid systems potentially sizing from 2000 to 2500 W m -2 with efficiencies varying between 50% and 60%. The analysis enables us to identify the system design tradeoffs, and therefore to determine better integration strategies for advanced SOFC-GT systems.

  9. Profiling of volatile organic compounds produced by clinical Aspergillus isolates using gas chromatography-mass spectrometry

    NARCIS (Netherlands)

    Gerritsen, M G; Brinkman, P; Escobar Salazar, Natalia; Bos, L D; de Heer, K; Meijer, M; Janssen, H-G; de Cock, H; Wösten, H A B; Visser, C.E.; van Oers, M H J; Sterk, P J

    Volatile organic compounds (VOCs) in exhaled breath may identify the presence of invasive pulmonary aspergillosis. We aimed to detect VOC profiles emitted by in vitro cultured, clinical Aspergillus isolates using gas chromatography-mass spectrometry (GC-MS). Three clinical Aspergillus isolates and a

  10. Profiling of volatile organic compounds produced by clinical Aspergillus isolates using gas chromatography-mass spectrometry

    NARCIS (Netherlands)

    Gerritsen, M. G.; Brinkman, P.; Escobar, N.; Bos, L. D.; de Heer, K.; Meijer, M.; Janssen, H.-G.; de Cock, H.; Wösten, H. A. B.; Visser, C. E.; van Oers, M. H. J.; Sterk, P. J.

    2018-01-01

    Volatile organic compounds (VOCs) in exhaled breath may identify the presence of invasive pulmonary aspergillosis. We aimed to detect VOC profiles emitted by in vitro cultured, clinical Aspergillus isolates using gas chromatography-mass spectrometry (GC-MS). Three clinical Aspergillus isolates and a

  11. Integration of A Solid Oxide Fuel Cell into A 10 MW Gas Turbine Power Plant

    Directory of Open Access Journals (Sweden)

    Denver F. Cheddie

    2010-04-01

    Full Text Available Power generation using gas turbine power plants operating on the Brayton cycle suffers from low efficiencies. In this work, a solid oxide fuel cell (SOFC is proposed for integration into a 10 MW gas turbine power plant, operating at 30% efficiency. The SOFC system utilizes four heat exchangers for heat recovery from both the turbine outlet and the fuel cell outlet to ensure a sufficiently high SOFC temperature. The power output of the hybrid plant is 37 MW at 66.2% efficiency. A thermo-economic model predicts a payback period of less than four years, based on future projected SOFC cost estimates.

  12. Integration and the hold-up problem in the design organization for engineering projects

    NARCIS (Netherlands)

    Zerjav, Vedran; Hartmann, Timo; Javernick-Will, A.; Chinowsky, P.

    2012-01-01

    The paper presents a perspective of the design organization in engineering projects based on the economic concept of the hold-up problem. By integrating the economic theories on the boundaries of organizations into the existing knowledge on design in engineering projects, the paper hypothesizes a

  13. Experience in developing control integrated multilevel systems for gas transport; Developpement de systemes integres de gestion multi-niveaux pour le transport du gaz

    Energy Technology Data Exchange (ETDEWEB)

    Kostyukov, V.Y. [NIIIS, (Russian Federation); Bityukov, V.S. [Gasprom, (Russian Federation)

    2000-07-01

    This report describes the experience of the integrated control multilevel system (IACS) development and implementation for gas transport at the regional enterprises of JSC 'Gasprom', specificity of IACS creation by the Russian enterprises on the basis of the technical and licensed basic software SCADA Geamatics purchased from AEG company under the contract. (authors)

  14. Integrated Materials Design of Organic Semiconductors for Field-Effect Transistors

    KAUST Repository

    Mei, Jianguo

    2013-05-08

    The past couple of years have witnessed a remarkable burst in the development of organic field-effect transistors (OFETs), with a number of organic semiconductors surpassing the benchmark mobility of 10 cm2/(V s). In this perspective, we highlight some of the major milestones along the way to provide a historical view of OFET development, introduce the integrated molecular design concepts and process engineering approaches that lead to the current success, and identify the challenges ahead to make OFETs applicable in real applications. © 2013 American Chemical Society.

  15. Assessment of parameters of gas centrifuge and separation cascade basing on integral characteristics of separation plant

    Energy Technology Data Exchange (ETDEWEB)

    Borisevich, Valentin, E-mail: VDBorisevich@mephi.ru [National Research Nuclear University MEPhI, Kashirskoe Shosse 31, Moscow 115409 (Russian Federation); National Research Center “Kurchatov Institute”, Kurchatov Square 1, Moscow 123182 (Russian Federation); Borshchevskiy, Michael, E-mail: Michael_mephi@mail.ru [National Research Nuclear University MEPhI, Kashirskoe Shosse 31, Moscow 115409 (Russian Federation); Andronov, Igor, E-mail: andronov@imp.kiae.ru [National Research Center “Kurchatov Institute”, Kurchatov Square 1, Moscow 123182 (Russian Federation); Senchenkov, Sergey, E-mail: senchenkov@imp.kiae.ru [National Research Center “Kurchatov Institute”, Kurchatov Square 1, Moscow 123182 (Russian Federation)

    2013-12-15

    Highlights: • We developed the calculation method to assess a feed flow rate into a gas centrifuge. • It is based on the knowledge of the integral characteristics of a separation plant. • Our method is verified by comparison with the results of the independent one. • The method also allows to specify other features of the separation cascade work. - Abstract: A calculation technique to assess a feed flow rate into a single GC, a total number of centrifuges in a separation cascade and to determine its likely configurations basing on the known integral characteristics of a centrifugal plant is developed. Evaluation of characteristics of the industrial gas centrifuge TC-12 and separation cascades of the NEF plant performed by two independent calculation techniques demonstrates their satisfactory agreement. This methodology would help to some extent the nuclear inspectors in evaluating and assessing the capability of an enrichment facility, and discovering any use for undeclared purposes.

  16. Transportation fuel production from gasified biomass integrated with a pulp and paper mill - Part B: Analysis of economic performance and greenhouse gas emissions

    International Nuclear Information System (INIS)

    Isaksson, Johan; Jansson, Mikael; Åsblad, Anders; Berntsson, Thore

    2016-01-01

    This paper presents a comparison between four gasification-based biorefineries integrated with a pulp and paper mill. It is a continuation of 'Transportation fuel production from gasified biomass integrated with a pulp and paper mill - Part A: Heat integration and system performance'. Synthesis into methanol, Fischer-Tropsch crude or synthetic natural gas, or electricity generation in a gas turbine combined cycle, were evaluated. The concepts were assessed in terms of GHG (greenhouse gas) emissions and economic performance. Net annual profits were positive for all biofuel cases for an annuity factor of 0.1 in the year 2030; however, the results are sensitive to biofuel selling prices and CO_2_,_e_q charge. Additionally, GHG emissions from grid electricity are highly influential on the results since all biofuel processes require external power. Credits for stored CO_2 might be necessary for processes to be competitive, i.e. storage of separated CO_2 from the syngas conditioning has an important role to play. Without CO_2 storage, the gas turbine case is better than, or equal to, biofuels regarding GHG emissions. Efficiency measures at the host mill prior to heat integration of a gasification process are beneficial from the perspective of GHG emissions, while having a negative impact on the economy. - Highlights: • Biomass gasification integrated with a pulp and paper mill was evaluated. • Greenhouse gas emission consequences and economic performance were assessed. • CCS has an important role to play, both in terms of emissions and economy. • Green electricity production is competitive compared to biofuel production in terms of GHG. • All biofuel cases are profitable in 2030 with assumed level of future policy instruments.

  17. Primary and secondary organic aerosol origin by combined gas-particle phase source apportionment

    Directory of Open Access Journals (Sweden)

    M. Crippa

    2013-08-01

    Full Text Available Secondary organic aerosol (SOA, a prominent fraction of particulate organic mass (OA, remains poorly constrained. Its formation involves several unknown precursors, formation and evolution pathways and multiple natural and anthropogenic sources. Here a combined gas-particle phase source apportionment is applied to wintertime and summertime data collected in the megacity of Paris in order to investigate SOA origin during both seasons. This was possible by combining the information provided by an aerosol mass spectrometer (AMS and a proton transfer reaction mass spectrometer (PTR-MS. A better constrained apportionment of primary OA (POA sources is also achieved using this methodology, making use of gas-phase tracers. These tracers made possible the discrimination between biogenic and continental/anthropogenic sources of SOA. We found that continental SOA was dominant during both seasons (24–50% of total OA, while contributions from photochemistry-driven SOA (9% of total OA and marine emissions (13% of total OA were also observed during summertime. A semi-volatile nighttime component was also identified (up to 18% of total OA during wintertime. This approach was successfully applied here and implemented in a new source apportionment toolkit.

  18. Grid integration policies of gas-fired cogeneration in Peninsular Malaysia: Fallacies and counterexamples

    Energy Technology Data Exchange (ETDEWEB)

    Shaaban, M., E-mail: m.shaaban@fke.utm.my [Centre of Electrical Energy Systems, Faculty of Electrical Engineering, Universiti Teknologi Malaysia, 81310 Johor Bahru (Malaysia); Azit, A.H. [Tenaga Nasional Berhad, Wisma TNB, Jalan Timur, 46200 Petaling Jaya, Selangor (Malaysia); Nor, K.M. [Centre of Electrical Energy Systems, Faculty of Electrical Engineering, Universiti Teknologi Malaysia, 81310 Johor Bahru (Malaysia)

    2011-09-15

    Despite the abundance of natural gas reserves in Malaysia coupled with serious government thrusts to promote cogeneration, its (cogeneration) development pace lags far off expectations. There are widespread fallacies among potential cogeneration developers and concerned professionals that cogeneration is uncompetitive in Malaysia due to existing policies of subsidized gas prices and grid-connection charges. This paper exposes these fallacies through counterexamples of practical cogeneration system design and evaluation of some segments of the industrial and service sectors in Peninsular Malaysia. The electrical and thermal characteristics of the cogeneration were modeled based on heat rate characteristics at partial loading patterns. A hierarchical mathematical programming approach that uses mixed-integer nonlinear optimization and dynamic programming principle, if necessary, is employed to determine the optimal size of cogeneration and its related auxiliary equipment as well as the optimal operation schedule. Financial assessment is integrated at a later stage to assess the economic viability of the system. Analyses of the cogeneration potential for several facilities of miscellaneous activities were carried out using various gas and electricity prices. Results obtained consistently rebuff the perpetuated fallacies and confirm that there is no real barrier to cogeneration development in Malaysia under current policies of gas prices and electricity tariffs. - Highlights: > Mixed-integer nonlinear programming and dynamic programming are used in the design. > Various loading levels are modeled and hourly operation schedule is determined. > Standby electricity charge has a minimal impact on cogeneration feasibility. > Gas and electricity prices are interrelated and affect cogeneration investment. > Under existing policies, there is no barrier to cogeneration adoption in Malaysia.

  19. Grid integration policies of gas-fired cogeneration in Peninsular Malaysia: Fallacies and counterexamples

    International Nuclear Information System (INIS)

    Shaaban, M.; Azit, A.H.; Nor, K.M.

    2011-01-01

    Despite the abundance of natural gas reserves in Malaysia coupled with serious government thrusts to promote cogeneration, its (cogeneration) development pace lags far off expectations. There are widespread fallacies among potential cogeneration developers and concerned professionals that cogeneration is uncompetitive in Malaysia due to existing policies of subsidized gas prices and grid-connection charges. This paper exposes these fallacies through counterexamples of practical cogeneration system design and evaluation of some segments of the industrial and service sectors in Peninsular Malaysia. The electrical and thermal characteristics of the cogeneration were modeled based on heat rate characteristics at partial loading patterns. A hierarchical mathematical programming approach that uses mixed-integer nonlinear optimization and dynamic programming principle, if necessary, is employed to determine the optimal size of cogeneration and its related auxiliary equipment as well as the optimal operation schedule. Financial assessment is integrated at a later stage to assess the economic viability of the system. Analyses of the cogeneration potential for several facilities of miscellaneous activities were carried out using various gas and electricity prices. Results obtained consistently rebuff the perpetuated fallacies and confirm that there is no real barrier to cogeneration development in Malaysia under current policies of gas prices and electricity tariffs. - Highlights: → Mixed-integer nonlinear programming and dynamic programming are used in the design. → Various loading levels are modeled and hourly operation schedule is determined. → Standby electricity charge has a minimal impact on cogeneration feasibility. → Gas and electricity prices are interrelated and affect cogeneration investment. → Under existing policies, there is no barrier to cogeneration adoption in Malaysia.

  20. Integral Transport Analysis Results for Ions Flowing Through Neutral Gas

    Science.gov (United States)

    Emmert, Gilbert; Santarius, John

    2017-10-01

    Results of a computational model for the flow of energetic ions and neutrals through a background neutral gas will be presented. The method models reactions as creating a new source of ions or neutrals if the energy or charge state of the resulting particle is changed. For a given source boundary condition, the creation and annihilation of the various species is formulated as a 1-D Volterra integral equation that can quickly be solved numerically by finite differences. The present work focuses on multiple-pass, 1-D ion flow through neutral gas and a nearly transparent, concentric anode and cathode pair in spherical, cylindrical, or linear geometry. This has been implemented as a computer code for atomic (3He, 3He +, 3He + +) and molecular (D, D2, D-, D +, D2 +, D3 +) ion and neutral species, and applied to modeling inertial-electrostatic connement (IEC) devices. The code yields detailed energy spectra of the various ions and energetic neutral species. Calculations for several University of Wisconsin IEC and ion implantation devices will be presented. Research supported by US Dept. of Homeland Security Grant 2015-DN-077-ARI095, Dept. of Energy Grant DE-FG02-04ER54745, and the Grainger Foundation.

  1. Integrating Metal-Oxide-Decorated CNT Networks with a CMOS Readout in a Gas Sensor

    Directory of Open Access Journals (Sweden)

    Suhwan Kim

    2012-02-01

    Full Text Available We have implemented a tin-oxide-decorated carbon nanotube (CNT network gas sensor system on a single die. We have also demonstrated the deposition of metallic tin on the CNT network, its subsequent oxidation in air, and the improvement of the lifetime of the sensors. The fabricated array of CNT sensors contains 128 sensor cells for added redundancy and increased accuracy. The read-out integrated circuit (ROIC was combined with coarse and fine time-to-digital converters to extend its resolution in a power-efficient way. The ROIC is fabricated using a 0.35 µm CMOS process, and the whole sensor system consumes 30 mA at 5 V. The sensor system was successfully tested in the detection of ammonia gas at elevated temperatures.

  2. A Worldwide Assessment of Greenhouse Gas Emissions from Drained Organic Soils

    Directory of Open Access Journals (Sweden)

    Francesco Nicola Tubiello

    2016-04-01

    Full Text Available Despite the importance of organic soils, including peatlands, in the global carbon cycle, detailed information on regional and global emissions is scarce. This is due to the difficulty to map, measure, and assess the complex dynamics of land, soil, and water interactions needed to assess the human-driven degradation of organic soils. We produced a new methodology for the comprehensive assessment of drained organic soils in agriculture and the estimation of the associated greenhouse gas emissions. Results indicated that over 25 million hectares of organic soils were drained worldwide for agriculture use, of which about 60% were in boreal and temperate cool areas, 34% in tropical areas, and 5% in warm temperate areas. Total emissions from the drainage were globally significant, totaling nearly one billion tonnes CO2eq annually. Of this, the CO2 component, about 780 million tonnes, represented more than one-fourth of total net CO2 emissions from agriculture, forestry, and land use. The bulk of these emissions came from a few tropical countries in Southeast Asia, and was linked to land clearing and drainage for crop cultivation. Geospatial data relative to this work were disseminated via the FAO geospatial server GeoNetwork, while the national aggregated statistics were disseminated via the FAOSTAT database.

  3. An Integrated Model for Effective Knowledge Management in Chinese Organizations

    Science.gov (United States)

    An, Xiaomi; Deng, Hepu; Wang, Yiwen; Chao, Lemen

    2013-01-01

    Purpose: The purpose of this paper is to provide organizations in the Chinese cultural context with a conceptual model for an integrated adoption of existing knowledge management (KM) methods and to improve the effectiveness of their KM activities. Design/methodology/approaches: A comparative analysis is conducted between China and the western…

  4. A tunable lighting system integrated by inorganic and transparent organic light-emitting diodes

    Science.gov (United States)

    Zhang, Jing-jing; Zhang, Tao; Jin, Ya-fang; Liu, Shi-shen; Yuan, Shi-dong; Cui, Zhao; Zhang, Li; Wang, Wei-hui

    2014-05-01

    A tunable surface-emitting integrated lighting system is constructed using a combination of inorganic light-emitting diodes (LEDs) and transparent organic LEDs (OLEDs). An RB two-color LED is used to supply red and blue light emission, and a green organic LED is used to supply green light emission. Currents of the LED and OLED are tuned to produce a white color, showing different Commission Internationale d'Eclairage (CIE) chromaticity coordinates and correlated color temperatures with a wide adjustable range. Such an integration can compensate for the lack of the LED's luminance uniformity and the transparent OLED's luminance intensity.

  5. Self-organizing path integration using a linked continuous attractor and competitive network: path integration of head direction.

    Science.gov (United States)

    Stringer, Simon M; Rolls, Edmund T

    2006-12-01

    A key issue is how networks in the brain learn to perform path integration, that is update a represented position using a velocity signal. Using head direction cells as an example, we show that a competitive network could self-organize to learn to respond to combinations of head direction and angular head rotation velocity. These combination cells can then be used to drive a continuous attractor network to the next head direction based on the incoming rotation signal. An associative synaptic modification rule with a short term memory trace enables preceding combination cell activity during training to be associated with the next position in the continuous attractor network. The network accounts for the presence of neurons found in the brain that respond to combinations of head direction and angular head rotation velocity. Analogous networks in the hippocampal system could self-organize to perform path integration of place and spatial view representations.

  6. Greenhouse Gas Emissions from Solid and Liquid Organic Fertilizers Applied to Lettuce.

    Science.gov (United States)

    Toonsiri, Phasita; Del Grosso, Stephen J; Sukor, Arina; Davis, Jessica G

    2016-11-01

    Improper application of nitrogen (N) fertilizer and environmental factors can cause the loss of nitrous oxide (NO) to the environment. Different types of fertilizers with different C/N ratios may have different effects on the environment. The focus of this study was to evaluate the effects of environmental factors and four organic fertilizers (feather meal, blood meal, fish emulsion, and cyano-fertilizer) applied at different rates (0, 28, 56, and 112 kg N ha) on NO emissions and to track CO emissions from a lettuce field ( L.). The study was conducted in 2013 and 2014 and compared preplant-applied solid fertilizers (feather meal and blood meal) and multiple applications of liquid fertilizers (fish emulsion and cyano-fertilizer). Three days a week, NO and CO emissions were measured twice per day in 2013 and once per day in 2014 using a closed-static chamber, and gas samples were analyzed by gas chromatography. Preplant-applied solid fertilizers significantly increased cumulative NO emissions as compared with control, but multiple applications of liquid fertilizers did not. Emission factors for NO ranged from 0 to 0.1% for multiple applications of liquid fertilizers and 0.6 to 11% for preplant-applied solid fertilizers, which could be overestimated due to chamber placement over fertilizer bands. In 2014, solid fertilizers with higher C/N ratios (3.3-3.5) resulted in higher CO emissions than liquid fertilizers (C/N ratio, 0.9-1.5). Therefore, organic farmers should consider the use of multiple applications of liquid fertilizers as a means to reduce soil greenhouse gas emissions while maintaining high yields. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

  7. Computation of liquid-liquid equilibria and phase stabilities: implications for RH-dependent gas/particle partitioning of organic-inorganic aerosols

    Directory of Open Access Journals (Sweden)

    A. Zuend

    2010-08-01

    Full Text Available Semivolatile organic and inorganic aerosol species partition between the gas and aerosol particle phases to maintain thermodynamic equilibrium. Liquid-liquid phase separation into an organic-rich and an aqueous electrolyte phase can occur in the aerosol as a result of the salting-out effect. Such liquid-liquid equilibria (LLE affect the gas/particle partitioning of the different semivolatile compounds and might significantly alter both particle mass and composition as compared to a one-phase particle. We present a new liquid-liquid equilibrium and gas/particle partitioning model, using as a basis the group-contribution model AIOMFAC (Zuend et al., 2008. This model allows the reliable computation of the liquid-liquid coexistence curve (binodal, corresponding tie-lines, the limit of stability/metastability (spinodal, and further thermodynamic properties of multicomponent systems. Calculations for ternary and multicomponent alcohol/polyol-water-salt mixtures suggest that LLE are a prevalent feature of organic-inorganic aerosol systems. A six-component polyol-water-ammonium sulphate system is used to simulate effects of relative humidity (RH and the presence of liquid-liquid phase separation on the gas/particle partitioning. RH, salt concentration, and hydrophilicity (water-solubility are identified as key features in defining the region of a miscibility gap and govern the extent to which compound partitioning is affected by changes in RH. The model predicts that liquid-liquid phase separation can lead to either an increase or decrease in total particulate mass, depending on the overall composition of a system and the particle water content, which is related to the hydrophilicity of the different organic and inorganic compounds. Neglecting non-ideality and liquid-liquid phase separations by assuming an ideal mixture leads to an overestimation of the total particulate mass by up to 30% for the composition and RH range considered in the six

  8. The Skogaryd Research Site - Integration of terrestrial and freshwater greenhouse gas sources and sinks

    Science.gov (United States)

    Klemedtsson, L.

    2012-04-01

    Forests play an important role in the global carbon (C) cycle, and management as well as climate can cause major effects on the balance of C between the atmosphere and the plant/soil system. With regard to our commitments to the Kyoto and post-Kyoto actions on climate change, we need reliable predictions on how this balance is affected by management and climate. In 2006 the Skogaryd Research Forest was established in the southwest of Sweden (58°23'N, 12°09'E). The overall goal is to quantify net greenhouse gas (GHG) fluxes from drained spruce forest soils, by determining the individual fluxes and pools of C and nitrogen and elucidating their connection to site fertility, drainage status and abiotic parameters. The generated data will be used in GHG models, for model validations and ultimately emissions predictions. During 2006-2009 the research has focused on two sites, mineral and organic soils, both dominated by Norway spruce (Picea abies). Both sites are drained fertile soils but with different land-use history that have affected their physical properties. Measurements include: net ecosystem exchange of CO2, shoot photosynthesis and respiration at different locations within the canopy, stem respiration, emissions of N2O and CH4 using manual chambers, soil respiration with automatic chambers including a trenching experiment where root, ectomycorrhizal, and heterotrophic respiration are separated, fine root production using minirhizotrons, and ectomycorrhizal mycelia production. The organic site also includes a wood ash fertilization experiment. From 2010 the research has been expanded by the project Landscape Greenhouse Gas Exchange (LAGGE) to the whole watershed, from the pristine mire system via streams, riparian zones, forests, to lakes and the subsequent exchange between the atmosphere and surface waters. The current accounting of forests as carbon sinks has relied on measurements of vertical carbon dioxide (CO2) exchange between vegetation and the

  9. Remarkably enhanced gas separation by partial self-conversion of a laminated membrane to metal-organic frameworks.

    Science.gov (United States)

    Liu, Yi; Pan, Jia Hong; Wang, Nanyi; Steinbach, Frank; Liu, Xinlei; Caro, Jürgen

    2015-03-02

    Separation methods based on 2D interlayer galleries are currently gaining widespread attention. The potential of such galleries as high-performance gas-separation membranes is however still rarely explored. Besides, it is well recognized that gas permeance and separation factor are often inversely correlated in membrane-based gas separation. Therefore, breaking this trade-off becomes highly desirable. Here, the gas-separation performance of a 2D laminated membrane was improved by its partial self-conversion to metal-organic frameworks. A ZIF-8-ZnAl-NO3 layered double hydroxide (LDH) composite membrane was thus successfully prepared in one step by partial conversion of the ZnAl-NO3 LDH membrane, ultimately leading to a remarkably enhanced H2 /CH4 separation factor and H2 permeance. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  10. An integrated simulation tool for analyzing the Operation and Interdependency of Natural Gas and Electric Power Systems

    OpenAIRE

    PAMBOUR Kwabena A.; CAKIR BURCIN; BOLADO LAVIN Ricardo; DIJKEMA Gerard

    2016-01-01

    In this paper, we present an integrated simulation tool for analyzing the interdependency of natural gas and electric power systems in terms of security of energy supply. In the first part, we develop mathematical models for the individual systems. In part two, we identify the interconnections between both systems and propose a method for coupling the combined simulation model. Next, we develop the algorithm for solving the combined system and integrate this algorithm into a simulation softwa...

  11. Performance analysis of different organic Rankine cycle configurations on board liquefied natural gas-fuelled vessels

    DEFF Research Database (Denmark)

    Baldasso, Enrico; Andreasen, Jesper Graa; Meroni, Andrea

    2017-01-01

    Gas-fuelled shipping is expected to increase significantly in the coming years. Similarly, much effort is devoted to the study of waste heat recovery systems to be implemented on board ships. In this context, the organic Rankine cycle (ORC) technology is considered one of the most promising...

  12. Plastic lab-on-a-chip for fluorescence excitation with integrated organic semiconductor lasers.

    Science.gov (United States)

    Vannahme, Christoph; Klinkhammer, Sönke; Lemmer, Uli; Mappes, Timo

    2011-04-25

    Laser light excitation of fluorescent markers offers highly sensitive and specific analysis for bio-medical or chemical analysis. To profit from these advantages for applications in the field or at the point-of-care, a plastic lab-on-a-chip with integrated organic semiconductor lasers is presented here. First order distributed feedback lasers based on the organic semiconductor tris(8-hydroxyquinoline) aluminum (Alq3) doped with the laser dye 4-dicyanomethylene-2-methyl-6-(p-dimethylaminostyril)-4H-pyrane (DCM), deep ultraviolet induced waveguides, and a nanostructured microfluidic channel are integrated into a poly(methyl methacrylate) (PMMA) substrate. A simple and parallel fabrication process is used comprising thermal imprint, DUV exposure, evaporation of the laser material, and sealing by thermal bonding. The excitation of two fluorescent marker model systems including labeled antibodies with light emitted by integrated lasers is demonstrated.

  13. Perspective: Fabrication of integrated organ-on-a-chip via bioprinting.

    Science.gov (United States)

    Yang, Qingzhen; Lian, Qin; Xu, Feng

    2017-05-01

    Organ-on-a-chip has emerged as a powerful platform with widespread applications in biomedical engineering, such as pathology studies and drug screening. However, the fabrication of organ-on-a-chip is still a challenging task due to its complexity. For an integrated organ-on-a-chip, it may contain four key elements, i.e., a microfluidic chip, live cells/microtissues that are cultured in this chip, components for stimulus loading to mature the microtissues, and sensors for results readout. Recently, bioprinting has been used for fabricating organ-on-a-chip as it enables the printing of multiple materials, including biocompatible materials and even live cells in a programmable manner with a high spatial resolution. Besides, all four elements for organ-on-a-chip could be printed in a single continuous procedure on one printer; in other words, the fabrication process is assembly free. In this paper, we discuss the recent advances of organ-on-a-chip fabrication by bioprinting. Light is shed on the printing strategies, materials, and biocompatibility. In addition, some specific bioprinted organs-on-chips are analyzed in detail. Because the bioprinted organ-on-a-chip is still in its early stage, significant efforts are still needed. Thus, the challenges presented together with possible solutions and future trends are also discussed.

  14. Metal organic framework absorbent platforms for removal of co2 and h2s from natural gas

    KAUST Repository

    Belmabkhout, Youssef; Eddaoudi, Mohamed; Adil, Karim; Cadiau, Amandine; Bhatt, Prashant M.

    2016-01-01

    Provided herein are metal organic frameworks comprising metal nodes and N-donor organic ligands which have high selectivity and stability in the present of gases and vapors including H2S, H2O, and CO2. Methods include capturing one or more of H2S, H2O, and CO2 from fluid compositions, such as natural gas.

  15. Metal organic framework absorbent platforms for removal of co2 and h2s from natural gas

    KAUST Repository

    Belmabkhout, Youssef

    2016-10-13

    Provided herein are metal organic frameworks comprising metal nodes and N-donor organic ligands which have high selectivity and stability in the present of gases and vapors including H2S, H2O, and CO2. Methods include capturing one or more of H2S, H2O, and CO2 from fluid compositions, such as natural gas.

  16. Structural integrity evaluation of X52 gas pipes subjected to external corrosion defects using the SINTAP procedure

    Energy Technology Data Exchange (ETDEWEB)

    Adib-Ramezani, H. [Ecole Polytechnique de l' Universite d' Orleans, CNRS-CRMD, 8 rue Leonard de Vinci, 45072 Orleans Cedex 2 (France)]. E-mail: hradib_2000@yahoo.com; Jeong, J. [Ecole Polytechnique de l' Universite d' Orleans, CNRS-CRMD, 8 rue Leonard de Vinci, 45072 Orleans Cedex 2 (France); Pluvinage, G. [Laboratoire de Fiabilite Mecanique (LFM), Universite de Metz-ENIM, 57045 Metz (France)

    2006-06-15

    In the present study, the SINTAP procedure has been proposed as a general structural integrity tool for semi-spherical, semi-elliptical and long blunt notch defects. The notch stress intensity factor concept and SINTAP structural integrity procedure are employed to assess gas pipelines integrity. The external longitudinal defects have been investigated via elastic-plastic finite element method results. The notch stress intensity concept is implemented into SINTAP procedure. The safety factor is calculated via SINTAP procedure levels 0B and 1B. The extracted evaluations are compared with the limit load analysis based on ASME B31G, modified ASME B31G, DNV RP-F101 and recent proposed formulation [Choi JB, Goo BK, Kim JC, Kim YJ, Kim WS. Development of limit load solutions for corroded gas pipelines. Int J Pressure Vessel Piping 2003;80(2):121-128]. The comparison among extracted safety factors exhibits that SINTAP predictions are located between lower and upper safety factor bounds. The SINTAP procedure including notch-based assessment diagram or so-called 'NFAD' involves wide range of defect geometries with low, moderate and high stress concentrations and relative stress gradients. Finally, some inspired and advanced viewpoints have been investigated.

  17. Structural integrity evaluation of X52 gas pipes subjected to external corrosion defects using the SINTAP procedure

    International Nuclear Information System (INIS)

    Adib-Ramezani, H.; Jeong, J.; Pluvinage, G.

    2006-01-01

    In the present study, the SINTAP procedure has been proposed as a general structural integrity tool for semi-spherical, semi-elliptical and long blunt notch defects. The notch stress intensity factor concept and SINTAP structural integrity procedure are employed to assess gas pipelines integrity. The external longitudinal defects have been investigated via elastic-plastic finite element method results. The notch stress intensity concept is implemented into SINTAP procedure. The safety factor is calculated via SINTAP procedure levels 0B and 1B. The extracted evaluations are compared with the limit load analysis based on ASME B31G, modified ASME B31G, DNV RP-F101 and recent proposed formulation [Choi JB, Goo BK, Kim JC, Kim YJ, Kim WS. Development of limit load solutions for corroded gas pipelines. Int J Pressure Vessel Piping 2003;80(2):121-128]. The comparison among extracted safety factors exhibits that SINTAP predictions are located between lower and upper safety factor bounds. The SINTAP procedure including notch-based assessment diagram or so-called 'NFAD' involves wide range of defect geometries with low, moderate and high stress concentrations and relative stress gradients. Finally, some inspired and advanced viewpoints have been investigated

  18. Analysis of Discharged Gas from Incinerator using Simulated Organic Solution

    International Nuclear Information System (INIS)

    Kim, Seungil; Kim, Hyunki; Heo, Jun; Kang, Dukwon; Kim, Yunbok; Kwon, Youngbock

    2014-01-01

    is controlled from 800 .deg. c to 930 .deg. C using temperature controller. The concentration of gaseous pollutants released by incinerating simulated organic waste is satisfied with Clean Air Conservation Act, Notification of Nuclear Safety Commission, Persistent Organic Pollutants Control Act and related statute. The incinerator used in this experiment is not object of regulation but the concentration of dioxin released from incinerator, 0.007ng-TEQ/Sm 3 , could be ignored because it is just 7%, in comparison with the limit of exhaust standard, 0.1ng-TEQ/Sm 3 . This is due to the rapid cooling of exhaust gas using heat-exchanger

  19. Analysis of Discharged Gas from Incinerator using Simulated Organic Solution

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Seungil; Kim, Hyunki; Heo, Jun; Kang, Dukwon [HaJI Co., Ltd., Radiation Eng. Center, Siheung (Korea, Republic of); Kim, Yunbok; Kwon, Youngbock [KORAD, Daejeon (Korea, Republic of)

    2014-05-15

    is controlled from 800 .deg. c to 930 .deg. C using temperature controller. The concentration of gaseous pollutants released by incinerating simulated organic waste is satisfied with Clean Air Conservation Act, Notification of Nuclear Safety Commission, Persistent Organic Pollutants Control Act and related statute. The incinerator used in this experiment is not object of regulation but the concentration of dioxin released from incinerator, 0.007ng-TEQ/Sm{sup 3}, could be ignored because it is just 7%, in comparison with the limit of exhaust standard, 0.1ng-TEQ/Sm{sup 3}. This is due to the rapid cooling of exhaust gas using heat-exchanger.

  20. MODERN TENDENCIES OF USING INTEGRATIVE APPROACH TO ORGANIZING ART TEACHERS’ INSTRUMENTAL AND PERFORMING TRAINING

    Directory of Open Access Journals (Sweden)

    Zhanna Kartashova

    2016-04-01

    Full Text Available In the article the modern tendencies of using integrative approach to organizing art teachers’ instrumental and performing training. The concept “integration” is singled out; it is defined as the process of recovery, replenishment, combining previously isolated parts; moving of the system to a great organic integrity. It is disclosed that the integration means considering multidimensionality of element features which are being integrated while accumulating quantitative features and emerging a new quality and individual features of integral elements are saved. It is proved that integrating is interrelation of art varieties in the process of their aesthetic and educational impact on pupils that is the whole perception of a work (its content and its emotional, rational, ethical and aesthetic form in the unity of tasks of developing artistic and aesthetic senses, thoughts, tastes and pupils’ ideals. It is thought that integration in art pedagogy is held at three levels: internal artistic and aesthetic synthesis of various arts organically combined with students creative activity; interdisciplinary humanistic synthesis of the arts, the native language, literature, and folklore; looking for semantic blocks, images, concepts that have universal meaning, which, entering all spheres of human consciousness, such as science and mathematics, seamlessly combining them into a coherent system. It is noted that the most efficient approach is appeal to the learning subjects of Humanities cycle – music, literature and art. It is concluded that designing of training should be started with the analyzing prospective art teacher’s activity. It should be understood what the teacher has to do, not in general formulation, but at the level of actions and operations.

  1. Highly integrated CO2 capture and conversion: Direct synthesis of cyclic carbonates from industrial flue gas

    KAUST Repository

    Barthel, Alexander; Saih, Youssef; Gimenez, Michel; Pelletier, Jeremie; Kü hn, Fritz Elmar; D´ Elia, Valerio; Basset, Jean-Marie

    2016-01-01

    Robust and selective catalytic systems based on early transition metal halides (Y, Sc, Zr) and organic nucleophiles were found able to quantitatively capture CO2 from diluted streams via formation of hemicarbonate species and to convert it to cyclic organic carbonates under ambient conditions. This observation was exploited in the direct and selective chemical fixation of flue gas CO2 collected from an industrial exhaust, affording high degrees of CO2 capture and conversion.

  2. Highly integrated CO2 capture and conversion: Direct synthesis of cyclic carbonates from industrial flue gas

    KAUST Repository

    Barthel, Alexander

    2016-02-08

    Robust and selective catalytic systems based on early transition metal halides (Y, Sc, Zr) and organic nucleophiles were found able to quantitatively capture CO2 from diluted streams via formation of hemicarbonate species and to convert it to cyclic organic carbonates under ambient conditions. This observation was exploited in the direct and selective chemical fixation of flue gas CO2 collected from an industrial exhaust, affording high degrees of CO2 capture and conversion.

  3. Natural gas markets integration in the Southern Cone: analysis of interests and stakeholders; Perspectivas para a integracao gasifera no Cone Sul: uma analise dos principais interesses e interessados

    Energy Technology Data Exchange (ETDEWEB)

    Villas Boas, Marina Vieira [PETROBRAS, Rio de Janeiro, RJ (Brazil)

    2004-07-01

    Natural gas has been recently gaining importance in the world energy mix especially because of its economical and environmental advantages but also because of technological and geopolitical issues. In the Southern Cone, natural gas demand shall maintain its upward trend in the next years mainly due to its use in power generation. This region owns significant natural gas reserves and, at the same time, a growing and with high potential market. In this scenario, natural gas markets integration is seen simultaneously as an opportunity and a necessity as it can contribute to demand and production interconnection, price competitiveness and security of supply. Nevertheless, there are important barriers to the consolidation of natural gas market integration in the Southern Cone region that have to be overcome. For the natural gas markets integration to be a sustainable project it is necessary to identify the major stakeholders and their interests and pursue a balance between them. (author)

  4. A charge-polarized porous metal-organic framework for gas chromatographic separation of alcohols from water.

    Science.gov (United States)

    Sun, Jian-Ke; Ji, Min; Chen, Cheng; Wang, Wu-Gen; Wang, Peng; Chen, Rui-Ping; Zhang, Jie

    2013-02-25

    A bipyridinium ligand with a charge separated skeleton has been introduced into a metal-organic framework to yield a porous material with charge-polarized pore space, which exhibits selective adsorption for polar guest molecules and can be further used in gas chromatography for the separation of alcohol-water mixtures.

  5. Hazardous gas production by alpha particles in solid organic transuranic waste matrices. 1998 annual progress report

    International Nuclear Information System (INIS)

    LaVerne, J.A.

    1998-01-01

    'This project uses fundamental radiation chemical techniques to elucidate the basic processes occurring in the heavy-ion radiolysis of solid hydrocarbon matrices such as polymers and organic resins that are associated with many of the transuranic waste deposits or the transportation of these radionuclides. The environmental management of mixed waste containing transuranic radionuclides is difficult because these nuclides are alpha particle emitters and the energy deposited by the alpha particles causes chemical transformations in the matrices accompanying the waste. Most radiolysis programs focus on conventional radiation such as gamma rays, but the chemical changes induced by alpha particles and other heavy ions are typically very different and product yields can vary by more than an order of magnitude. The objective of this research is to measure the production of gases, especially molecular hydrogen, produced in the proton, helium ion, and carbon ion radiolysis of selected solid organic matrices in order to obtain fundamental mechanistic information on the radiolytic decomposition of these materials. This knowledge can also be used to directly give reasonable estimates of explosive or flammability hazards in the storage or transport of transuranic wastes in order to enhance the safety of DOE sites. This report summarizes the work after eight months of a three-year project on determining the production of hazardous gases in transuranic waste. The first stage of the project was to design and build an assembly to irradiate solid organic matrices using accelerated ion beams. It is necessary to measure absolute radiolytic yields, and simulate some of the conditions found in the field. A window assembly was constructed allowing the beam to pass consecutively through a collimator, a vacuum exit window and into the solid sample. The beam is stopped in the sample and the entire end of the assembly is a Faraday cup. Integration of the collected current, in conjunction

  6. Thermal maturity and organic composition of Pennsylvanian coals and carbonaceous shales, north-central Texas: Implications for coalbed gas potential

    Energy Technology Data Exchange (ETDEWEB)

    Hackley, Paul C. [U.S. Geological Survey, 956 National Center, Reston, VA 20192 (United States); Guevara, Edgar H.; Hentz, Tucker F. [Bureau of Economic Geology, The University of Texas at Austin, Austin, TX 78713 (United States); Hook, Robert W. [1301 Constant Springs Drive, Austin, TX 78746 (United States)

    2009-01-31

    Thermal maturity was determined for about 120 core, cuttings, and outcrop samples to investigate the potential for coalbed gas resources in Pennsylvanian strata of north-central Texas. Shallow (< 600 m; 2000 ft) coal and carbonaceous shale cuttings samples from the Middle-Upper Pennsylvanian Strawn, Canyon, and Cisco Groups in Archer and Young Counties on the Eastern Shelf of the Midland basin (northwest and downdip from the outcrop) yielded mean random vitrinite reflectance (R{sub o}) values between about 0.4 and 0.8%. This range of R{sub o} values indicates rank from subbituminous C to high volatile A bituminous in the shallow subsurface, which may be sufficient for early thermogenic gas generation. Near-surface (< 100 m; 300 ft) core and outcrop samples of coal from areas of historical underground coal mining in the region yielded similar R{sub o} values of 0.5 to 0.8%. Carbonaceous shale core samples of Lower Pennsylvanian strata (lower Atoka Group) from two deeper wells (samples from {proportional_to} 1650 m; 5400 ft) in Jack and western Wise Counties in the western part of the Fort Worth basin yielded higher R{sub o} values of about 1.0%. Pyrolysis and petrographic data for the lower Atoka samples indicate mixed Type II/Type III organic matter, suggesting generated hydrocarbons may be both gas- and oil-prone. In all other samples, organic material is dominated by Type III organic matter (vitrinite), indicating that generated hydrocarbons should be gas-prone. Individual coal beds are thin at outcrop (< 1 m; 3.3 ft), laterally discontinuous, and moderately high in ash yield and sulfur content. A possible analog for coalbed gas potential in the Pennsylvanian section of north-central Texas occurs on the northeast Oklahoma shelf and in the Cherokee basin of southeastern Kansas, where contemporaneous gas-producing coal beds are similar in thickness, quality, and rank. (author)

  7. Prediction of total organic carbon content in shale reservoir based on a new integrated hybrid neural network and conventional well logging curves

    Science.gov (United States)

    Zhu, Linqi; Zhang, Chong; Zhang, Chaomo; Wei, Yang; Zhou, Xueqing; Cheng, Yuan; Huang, Yuyang; Zhang, Le

    2018-06-01

    There is increasing interest in shale gas reservoirs due to their abundant reserves. As a key evaluation criterion, the total organic carbon content (TOC) of the reservoirs can reflect its hydrocarbon generation potential. The existing TOC calculation model is not very accurate and there is still the possibility for improvement. In this paper, an integrated hybrid neural network (IHNN) model is proposed for predicting the TOC. This is based on the fact that the TOC information on the low TOC reservoir, where the TOC is easy to evaluate, comes from a prediction problem, which is the inherent problem of the existing algorithm. By comparing the prediction models established in 132 rock samples in the shale gas reservoir within the Jiaoshiba area, it can be seen that the accuracy of the proposed IHNN model is much higher than that of the other prediction models. The mean square error of the samples, which were not joined to the established models, was reduced from 0.586 to 0.442. The results show that TOC prediction is easier after logging prediction has been improved. Furthermore, this paper puts forward the next research direction of the prediction model. The IHNN algorithm can help evaluate the TOC of a shale gas reservoir.

  8. Verification of the integrity of barriers using gas diffusion

    International Nuclear Information System (INIS)

    Ward, D.B.; Williams, C.V.

    1997-06-01

    In-situ barrier materials and designs are being developed for containment of high risk contamination as an alternative to immediate removal or remediation. The intent of these designs is to prevent the movement of contaminants in either the liquid or vapor phase by long-term containment, essentially buying time until the contaminant depletes naturally or a remediation can be implemented. The integrity of the resultant soil-binder mixture is typically assessed by a number of destructive laboratory tests (leaching, compressive strength, mechanical stability with respect to wetting and freeze-thaw cycles) which as a group are used to infer the likelihood of favorable long-term performance of the barrier. The need exists for a minimally intrusive yet quantifiable methods for assessment of a barrier's integrity after emplacement, and monitoring of the barrier's performance over its lifetime. Here, the authors evaluate non-destructive measurements of inert-gas diffusion (specifically, SF 6 ) as an indicator of waste-form integrity. The goals of this project are to show that diffusivity can be measured in core samples of soil jet-grouted with Portland cement, validate the experimental method through measurements on samples, and to calculate aqueous diffusivities from a series of diffusion measurements. This study shows that it is practical to measure SF 6 diffusion rates in the laboratory on samples of grout (Portland cement and soil) typical of what might be used in a barrier. Diffusion of SF 6 through grout (Portland cement and soil) is at least an order of magnitude slower than through air. The use of this tracer should be sensitive to the presence of fractures, voids, or other discontinuities in the grout/soil structure. Field-scale measurements should be practical on time-scales of a few days

  9. Information security architecture an integrated approach to security in the organization

    CERN Document Server

    Killmeyer, Jan

    2000-01-01

    An information security architecture is made up of several components. Each component in the architecture focuses on establishing acceptable levels of control. These controls are then applied to the operating environment of an organization. Functionally, information security architecture combines technical, practical, and cost-effective solutions to provide an adequate and appropriate level of security.Information Security Architecture: An Integrated Approach to Security in the Organization details the five key components of an information security architecture. It provides C-level executives

  10. Hybrid Approximate Dynamic Programming Approach for Dynamic Optimal Energy Flow in the Integrated Gas and Power Systems

    DEFF Research Database (Denmark)

    Shuai, Hang; Ai, Xiaomeng; Wen, Jinyu

    2017-01-01

    This paper proposes a hybrid approximate dynamic programming (ADP) approach for the multiple time-period optimal power flow in integrated gas and power systems. ADP successively solves Bellman's equation to make decisions according to the current state of the system. So, the updated near future...

  11. Chlorination of some eliphatic organic compounds in liquid and gas phase

    International Nuclear Information System (INIS)

    Hassan, A.A.

    1990-01-01

    The photochlorination of different organic compounds and the relative slectivities of different positions have been investigated in both gaseous and liquid phases at different temperatures. The results have shown that the relative selectivity generally decreased with increasing temperature and in the gas phase has a higher value. Polar solvents increase the selectivity relative to the chlorination of pure liquid phases. The differences in activation energy between two positions were much higher in the gas phases chlorination, relative to that in the liquid phase. It was also found that the functional groups have great influence on the rate of chlorine free radical attack on different positions, for example the electron withdrawing groups decreasing the selectivity on the first position, but the electron donating groups increase the selectivity on the first position, but the electron donating groups increase the selectivity on the first position. Furthermore it was found that the polar solvents, which stabilize the resonance between oxygen and carbon atoms, increases the selectivity on that position. 23 tabs.; 16 figs.; 50 refs

  12. Analysis of Gas Vent System in Overseas LILW Disposal Facilities

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Ju Yub; Kim, Ju Youl [FNC Technology Co., Yongin (Korea, Republic of); Jung, Hae Ryong; Ha, Jae Chul [Korea Radioactive Waste Management Corporation, Daejeon (Korea, Republic of)

    2012-05-15

    A Low- and Intermediate-Level Radioactive Waste (LILW) disposal facility is currently under construction in Korea. It is located in the aquifer, 80{approx}130 m below the ground surface. Thus, it is expected that disposal facility will be saturated after closure and various gases will be generated from metal corrosion, microbial degradation of organic materials and radiolysis. Generated gases will move up to the upper part of the silo, and it will increase the pressure of the silo. Since the integrity of the engineered barrier could be damaged, development of effective gas vent system which can prevent the gas accumulation in the silo is essential. In order to obtain basic data needed to develop site-specific gas vent system, gas vent systems of Sweden, Finland and Switzerland, which have the disposal concept of underground facility, were analyzed

  13. Fungal pathogens and antagonists in root-soil zone in organic and integrated systems of potato production

    Directory of Open Access Journals (Sweden)

    Lenc Leszek

    2016-04-01

    Full Text Available Occurrence of culturable Fungi and Oomycota in root-soil habitat of potato cv. Owacja in organic and integrated production systems at Osiny (northern Poland was compared in 2008-2010. The densities of both pathogens were significantly greater in the organic system. The eudominant fungal taxa (with frequency > 10% in at least one habitat included species of Fusarium + Gibberella + Haematonectria, Penicillium, Phoma and Trichoderma. The dominant taxa (with frequency 5-10% included species from 13 genera. In the rhizoplane, rhizosphere and non-rhizosphere soil, the total density of potential pathogens was greater in the integrated system, and of potential antagonists in the organic system. Among eudominant and dominant pathogens, Fusarium oxysporum and Gibellulopsis nigrescens occurred at greater density in the integrated system and Haematonectria haematococca and Phoma spp. in the organic system. Among eudominant antagonists, Trichoderma species occurred at greater density in the organic system. The organic system provided more disease suppressive habitat than the integrated system. The occurrence of brown leaf spot and potato blight was however similar in both systems. The mean yield of organic potatoes (24.9 t · ha-1 was higher than the mean organic potato yield in Poland (21.0 t · ha-1 and similar to the mean in other European countries (Germany 25.1 t · ha-1, Great Britain 25.0 t · ha-1. The organic system, based on a 5-year rotation, with narrow-leafed lupin, white mustard and buckwheat as a cover crop, inorganic fertilization based on ground rock phosphate + potassium sulphate, and biological and chemical control of insects and diseases (Bacillus thuringiensis ssp. tenebrionis + copper hydroxide + copper oxychloride, may be recommended for use in central Europe.

  14. Process development of coke oven gas to methanol integrated with CO2 recycle for satisfactory techno-economic performance

    International Nuclear Information System (INIS)

    Yi, Qun; Gong, Min-Hui; Huang, Yi; Feng, Jie; Hao, Yan-Hong; Zhang, Ji-Long; Li, Wen-Ying

    2016-01-01

    A novel process designed for producing methanol from coke oven gas (COG) integrated with CO 2 recycle is proposed. In the new system, oxygen replacing air is blown to combustor for assisting combustion of COG and unreacted syngas from methanol synthesis process. The combustion process provides to the heat required in the coking process. The rest COG reacts with the recycled CO 2 separated from the exhaust gas to produce syngas for methanol synthesis. The unreacted syngas from methanol synthesis process with low grade energy level is recycled to the combustor. In the whole methanol production process, there is no additional process with respect to supplementary carbon, and the carbon resource only comes from the internal CO 2 recycle in the plant. With the aid of techno-economic analysis, the new system presents the energy or exergy saving by 5–10%, the CO 2 emission reduction by about 70% and the internal rate of return increase by 5–8%, respectively, in comparison with the traditional COG to methanol process. - Highlights: • A process for producing methanol from COG integrated with CO 2 recycle is first proposed. • CO 2 from the exhaust gas is recycled to supply carbon for producing syngas. • New integrated plant simplifies the production process with 5–8% IRR increase. • New system presents about 5–10% energy saving, about 70% CO 2 emission reduction.

  15. Flexible Electronics: Integration Processes for Organic and Inorganic Semiconductor-Based Thin-Film Transistors

    Directory of Open Access Journals (Sweden)

    Fábio F. Vidor

    2015-07-01

    Full Text Available Flexible and transparent electronics have been studied intensively during the last few decades. The technique establishes the possibility of fabricating innovative products, from flexible displays to radio-frequency identification tags. Typically, large-area polymeric substrates such as polypropylene (PP or polyethylene terephthalate (PET are used, which produces new requirements for the integration processes. A key element for flexible and transparent electronics is the thin-film transistor (TFT, as it is responsible for the driving current in memory cells, digital circuits or organic light-emitting devices (OLEDs. In this paper, we discuss some fundamental concepts of TFT technology. Additionally, we present a comparison between the use of the semiconducting organic small-molecule pentacene and inorganic nanoparticle semiconductors in order to integrate TFTs suitable for flexible electronics. Moreover, a technique for integration with a submicron resolution suitable for glass and foil substrates is presented.

  16. Determination of Organic Pollutants in Small Samples of Groundwaters by Liquid-Liquid Extraction and Capillary Gas Chromatography

    DEFF Research Database (Denmark)

    Harrison, I.; Leader, R.U.; Higgo, J.J.W.

    1994-01-01

    A method is presented for the determination of 22 organic compounds in polluted groundwaters. The method includes liquid-liquid extraction of the base/neutral organics from small, alkaline groundwater samples, followed by derivatisation and liquid-liquid extraction of phenolic compounds after neu...... neutralisation. The extracts were analysed by capillary gas chromatography. Dual detection by flame Ionisation and electron capture was used to reduce analysis time....

  17. Photovoltaic and Hydrogen Plant Integrated with a Gas Heat Pump for Greenhouse Heating: A Mathematical Study

    Directory of Open Access Journals (Sweden)

    Alexandros Sotirios Anifantis

    2018-02-01

    Full Text Available Nowadays, the traditional energy sources used for greenhouse heating are fossil fuels such as LPG, diesel and natural gas. The global energy demand will continue to grow and alternative technologies need to be developed in order to improve the sustainability of crop production in protected environments. Innovative solutions are represented by renewable energy plants such as photovoltaic, wind and geothermal integrated systems, however, these technologies need to be connected to the power grid in order to store the energy produced. On agricultural land, power grids are not widespread and stand-alone renewable energy systems should be investigated especially for greenhouse applications. The aim of this research is to analyze, by means of a mathematical model, the energy efficiency of a photovoltaic (8.2 kW, hydrogen (2.5 kW and ground source gas heat pump (2.2 kW integrated in a stand-alone system used for heating an experimental greenhouse tunnel (48 m2 during the winter season. A yearlong energy performance analysis was conducted for three different types of greenhouse cover materials, a single layer polyethylene film, an air inflated-double layer polyethylene film, and a double acrylic or polycarbonate. The results of one year showed that the integrated system had a total energy efficiency of 14.6%. Starting from the electric energy supplied by the photovoltaic array, the total efficiency of the hydrogen and ground source gas heat pump system was 112% if the coefficient of the performance of the heat pump is equal to 5. The heating system increased the greenhouse air temperatures by 3–9 °C with respect to the external air temperatures, depending on the greenhouse cover material used.

  18. Behavior of radioactive organic iodide in an atmosphere of High Temperature Gas-cooled Reactor

    International Nuclear Information System (INIS)

    Saeki, Masakatsu; Nakashima, Mikio; Sagawa, Chiaki; Masaki, Nobuyuki; Hirabayashi, Takakuni; Aratono, Yasuyuki

    1990-06-01

    Formation and decomposition behavior of radioactive organic iodide have been studied in an atmosphere of High Temperature Gas-cooled Reactor (High Temperature Engineering Test Reactor, HTTR). Na 125 I was chosen for radioactive iodine source instead of CsI diffusing from coated fuel particles. Na 125 I adsorbed on graphite was heated in pure He and He containing O 2 or H 2 O atmosphere. The results obtained are as follows. It was proved that organic iodide was formed with organic radicals released from graphite even in He atmosphere. Thus, the interchange rate of inorganic iodide with organic iodide was remarkably decreased with prolonged preheat-treatment period at 1000degC. Organic iodide formed was easily decomposed by its recirculation into hot reaction tube kept at 900degC. When organic iodide was passed through powdered graphite bed, more than 70% was decomposed at 90degC. Oxygen and water vapour intermixed in He suppressed the interchange rate of inorganic iodide with organic iodide. These results suggest that organic iodide rarely exists in the pressure vessel under normal operating condition of HTTR, and, under hypothetical accident condition of HTTR, organic iodide fraction never exceeds the value used for a safety assessment of light water reactor. (author)

  19. Characterization and Health Risk Assessment of Volatile Organic Compounds in Gas Service Station Workers

    Directory of Open Access Journals (Sweden)

    Duangduan Yimrungruang

    2008-07-01

    Full Text Available Gas service station workers who work near volatile organic compounds (VOCs sources, such as gasoline vapor emissions, and motor vehicle exhausts, may be exposed to highly elevated VOCs levels. This study investigates air samples from gas service stations in Thailand to evaluate the health risks following inhalation exposure. Personal air samplings were obtained at nine gas service stations in Chonburi, Thailand from October to December 2007. The concentrations of benzene, toluene, ethylbenzene, xylenes, and hexane in the air from the workplaces were significantly higher than in a control group of office workers (p<0.05. However, all VOCs in these air samples were lower than TWA limit of Thailand and the OSHA standard. Samples of urine, collected after 8-h work periods which were analyzed for VOCs metabolites, including t,t muconic acid, hippuric acid, mandelic acid and m-hippuric acid, demonstrate that the average levels of metabolites in gas service station workers and in controls were close, except for t,t muconic acid of gas service station workers which displayed higher levels than the in the controls. The lifetime cancer and noncancer risks for the workers exposed to VOCs were also assessed. Results show that all nine gas service stations in this study had a elevated lifetime cancer risk ranging from 53 to 630 per million, thus exceeding the normal risk of 1 per million. For noncancer risks, the levels in all gas stations ranged between 0.03 and 0.4, which is well below the reference hazard level of 1.0. Benzene may the most important cause of both cancer and noncancer risk followed by 1,3 butadiene.

  20. Thermodynamic and design considerations of organic Rankine cycles in combined application with a solar thermal gas turbine

    Science.gov (United States)

    Braun, R.; Kusterer, K.; Sugimoto, T.; Tanimura, K.; Bohn, D.

    2013-12-01

    Concentrated Solar Power (CSP) technologies are considered to provide a significant contribution for the electric power production in the future. Different kinds of technologies are presently in operation or under development, e.g. parabolic troughs, central receivers, solar dish systems and Fresnel reflectors. This paper takes the focus on central receiver technologies, where the solar radiation is concentrated by a field of heliostats in a receiver on the top of a tall tower. To get this CSP technology ready for the future, the system costs have to reduce significantly. The main cost driver in such kind of CSP technologies are the huge amount of heliostats. To reduce the amount of heliostats, and so the investment costs, the efficiency of the energy conversion cycle becomes an important issue. An increase in the cycle efficiency results in a decrease of the solar heliostat field and thus, in a significant cost reduction. The paper presents the results of a thermodynamic model of an Organic Rankine Cycle (ORC) for combined cycle application together with a solar thermal gas turbine. The gas turbine cycle is modeled with an additional intercooler and recuperator and is based on a typical industrial gas turbine in the 2 MW class. The gas turbine has a two stage radial compressor and a three stage axial turbine. The compressed air is preheated within a solar receiver to 950°C before entering the combustor. A hybrid operation of the gas turbine is considered. In order to achieve a further increase of the overall efficiency, the combined operation of the gas turbine and an Organic Rankine Cycle is considered. Therefore an ORC has been set up, which is thermally connected to the gas turbine cycle at two positions. The ORC can be coupled to the solar-thermal gas turbine cycle at the intercooler and after the recuperator. Thus, waste heat from different cycle positions can be transferred to the ORC for additional production of electricity. Within this investigation

  1. Integration of Computational and Preparative Techniques to Demonstrate Physical Organic Concepts in Synthetic Organic Chemistry: An Example Using Diels-Alder Reaction

    Science.gov (United States)

    Palmer, David R. J.

    2004-01-01

    The Diels-Alder reaction is used as an example for showing the integration of computational and preparative techniques, which help in demonstrating the physical organic concepts in synthetic organic chemistry. These experiments show that the students should not accept the computational results without questioning them and in many Diels-Alder…

  2. Gas in Andean countries

    International Nuclear Information System (INIS)

    Campos Pinzon, Rafael

    2000-01-01

    The paper explores aspects of gas integration among Colombia, Venezuela, Ecuador and Peru. A comparison of the GDP is made, gas reserves are provided and the existent nets of gas-pipe are included in Colombia and Venezuela

  3. The importance of grid integration for achievable greenhouse gas emissions reductions from alternative vehicle technologies

    International Nuclear Information System (INIS)

    Tarroja, Brian; Shaffer, Brendan; Samuelsen, Scott

    2015-01-01

    Alternative vehicles must appropriately interface with the electric grid and renewable generation to contribute to decarbonization. This study investigates the impact of infrastructure configurations and management strategies on the vehicle–grid interface and vehicle greenhouse gas reduction potential with regard to California's Executive Order S-21-09 goal. Considered are battery electric vehicles, gasoline-fueled plug-in hybrid electric vehicles, hydrogen-fueled fuel cell vehicles, and plug-in hybrid fuel cell vehicles. Temporally resolved models of the electric grid, electric vehicle charging, hydrogen infrastructure, and vehicle powertrain simulations are integrated. For plug-in vehicles, consumer travel patterns can limit the greenhouse gas reductions without smart charging or energy storage. For fuel cell vehicles, the fuel production mix must be optimized for minimal greenhouse gas emissions. The plug-in hybrid fuel cell vehicle has the largest potential for emissions reduction due to smaller battery and fuel cells keeping efficiencies higher and meeting 86% of miles on electric travel keeping the hydrogen demand low. Energy storage is required to meet Executive Order S-21-09 goals in all cases. Meeting the goal requires renewable capacities of 205 GW for plug-in hybrid fuel cell vehicles and battery electric vehicle 100s, 255 GW for battery electric vehicle 200s, and 325 GW for fuel cell vehicles. - Highlights: • Consumer travel patterns limit greenhouse gas reductions with immediate charging. • Smart charging or energy storage are required for large greenhouse gas reductions. • Fuel cells as a plug-in vehicle range extender provided the most greenhouse gas reductions. • Energy storage is required to meet greenhouse gas goals regardless of vehicle type. • Smart charging reduces the required energy storage size for a given greenhouse gas goal

  4. Observations of gas- and aerosol-phase organic nitrates at BEACHON-RoMBAS 2011

    Directory of Open Access Journals (Sweden)

    J. L. Fry

    2013-09-01

    Full Text Available At the Rocky Mountain Biogenic Aerosol Study (BEACHON-RoMBAS field campaign in the Colorado front range, July–August 2011, measurements of gas- and aerosol-phase organic nitrates enabled a study of the role of NOx (NOx = NO + NO2 in oxidation of forest-emitted volatile organic compounds (VOCs and subsequent aerosol formation. Substantial formation of peroxy- and alkyl-nitrates is observed every morning, with an apparent 2.9% yield of alkyl nitrates from daytime RO2 + NO reactions. Aerosol-phase organic nitrates, however, peak in concentration during the night, with concentrations up to 140 ppt as measured by both optical spectroscopic and mass spectrometric instruments. The diurnal cycle in aerosol fraction of organic nitrates shows an equilibrium-like response to the diurnal temperature cycle, suggesting some reversible absorptive partitioning, but the full dynamic range cannot be reproduced by thermodynamic repartitioning alone. Nighttime aerosol organic nitrate is observed to be positively correlated with [NO2] × [O3] but not with [O3]. These observations support the role of nighttime NO3-initiated oxidation of monoterpenes as a significant source of nighttime aerosol. Nighttime production of organic nitrates is comparable in magnitude to daytime photochemical production at this site, which we postulate to be representative of the Colorado front range forests.

  5. On a non-local gas dynamics like integrable hierarchy

    International Nuclear Information System (INIS)

    Brunelli, Jose Carlos; Das, Ashok

    2004-01-01

    We study a new hierarchy of equations derived from the system of isentropic gas dynamics equations where the pressure is a non-local function of the density. We show that the hierarchy of equations is integrable. We construct the two compatible Hamiltonian structures and show that the first structure has three distinct Casimirs while the second has one. The existence of Casimirs allows us to extend the flows to local ones. We construct an infinite series of commuting local Hamiltonians as well as three infinite series (related to the three Casimirs) of non-local charges. We discuss the zero curvature formulation of the system where we obtain a simple expression for the non-local conserved charges, which also clarifies the existence of the three series from a Lie algebraic point of view. We point out that the non-local hierarchy of Hunter-Zheng equations can be obtained from our non-local flows when the dynamical variables are properly constrained. (author)

  6. Evaluasi Program Corporate Social Responsibility “Organic Integrated System” PT. Pembangkitan Jawa-Bali Unit Pembangkitan Paiton

    OpenAIRE

    Harianto, Ruth Carissa

    2016-01-01

    Penelitian ini dilakukan untuk mengevaluasi program Corporate Social Responsibility “Organic Integrated System” yang dijalankan oleh divisi umum dan CSR PT. Pembangkitan Jawa – Bali Unit Pembangkitan Paiton. Di dalam melaksanakan program Corporate Social Responsibility “Organic Integrated System” ini, PT. Pembangkitan Jawa – Bali Unit Pembangkitan Paiton bekerja sama dengan Lembaga Swadaya Masyarakat Sekola Konang dan Kelompok Suko Tani sebagai publik sasarannya. Penelitian ini menggunakan pe...

  7. Sensitive resonant gas sensor operating in air with metal organic frameworks coating

    KAUST Repository

    Jaber, Nizar; Ilyas, Saad; Shekhah, Osama; Eddaoudi, Mohamed; Younis, Mohammad I.

    2017-01-01

    We report a practical resonant gas sensor that is uniformly coated with metal organic frameworks (MOFs) and excited near the higher order modes for a higher attained sensitivity. The resonator is based on an electrostatically excited clamped-clamped microbeam. The microbeam is fabricated from a polyimide layer coated from the top with Cr/Au and from the bottom with Cr/Au/Cr layer. The geometry of the resonator is optimized to reduce the effect of the squeeze film damping, thereby allowing operation under atmospheric pressure. The electrostatic force electrode is designed to enhance the excitation of the second mode of vibration with the minimum power required. Significant frequency shift (kHz) is demonstrated for the first time upon water vapor, acetone, and ethanol exposure due to the MOFs functionalization and the higher order modes excitation. Also, the adsorption dynamics and MOF selectivity is investigated by studying the decaying time constants of the response upon gas exposure.

  8. Sensitive resonant gas sensor operating in air with metal organic frameworks coating

    KAUST Repository

    Jaber, Nizar

    2017-08-09

    We report a practical resonant gas sensor that is uniformly coated with metal organic frameworks (MOFs) and excited near the higher order modes for a higher attained sensitivity. The resonator is based on an electrostatically excited clamped-clamped microbeam. The microbeam is fabricated from a polyimide layer coated from the top with Cr/Au and from the bottom with Cr/Au/Cr layer. The geometry of the resonator is optimized to reduce the effect of the squeeze film damping, thereby allowing operation under atmospheric pressure. The electrostatic force electrode is designed to enhance the excitation of the second mode of vibration with the minimum power required. Significant frequency shift (kHz) is demonstrated for the first time upon water vapor, acetone, and ethanol exposure due to the MOFs functionalization and the higher order modes excitation. Also, the adsorption dynamics and MOF selectivity is investigated by studying the decaying time constants of the response upon gas exposure.

  9. Propagation of uncertainty and sensitivity analysis in an integral oil-gas plume model

    KAUST Repository

    Wang, Shitao

    2016-05-27

    Polynomial Chaos expansions are used to analyze uncertainties in an integral oil-gas plume model simulating the Deepwater Horizon oil spill. The study focuses on six uncertain input parameters—two entrainment parameters, the gas to oil ratio, two parameters associated with the droplet-size distribution, and the flow rate—that impact the model\\'s estimates of the plume\\'s trap and peel heights, and of its various gas fluxes. The ranges of the uncertain inputs were determined by experimental data. Ensemble calculations were performed to construct polynomial chaos-based surrogates that describe the variations in the outputs due to variations in the uncertain inputs. The surrogates were then used to estimate reliably the statistics of the model outputs, and to perform an analysis of variance. Two experiments were performed to study the impacts of high and low flow rate uncertainties. The analysis shows that in the former case the flow rate is the largest contributor to output uncertainties, whereas in the latter case, with the uncertainty range constrained by aposteriori analyses, the flow rate\\'s contribution becomes negligible. The trap and peel heights uncertainties are then mainly due to uncertainties in the 95% percentile of the droplet size and in the entrainment parameters.

  10. Propagation of uncertainty and sensitivity analysis in an integral oil-gas plume model

    KAUST Repository

    Wang, Shitao; Iskandarani, Mohamed; Srinivasan, Ashwanth; Thacker, W. Carlisle; Winokur, Justin; Knio, Omar

    2016-01-01

    Polynomial Chaos expansions are used to analyze uncertainties in an integral oil-gas plume model simulating the Deepwater Horizon oil spill. The study focuses on six uncertain input parameters—two entrainment parameters, the gas to oil ratio, two parameters associated with the droplet-size distribution, and the flow rate—that impact the model's estimates of the plume's trap and peel heights, and of its various gas fluxes. The ranges of the uncertain inputs were determined by experimental data. Ensemble calculations were performed to construct polynomial chaos-based surrogates that describe the variations in the outputs due to variations in the uncertain inputs. The surrogates were then used to estimate reliably the statistics of the model outputs, and to perform an analysis of variance. Two experiments were performed to study the impacts of high and low flow rate uncertainties. The analysis shows that in the former case the flow rate is the largest contributor to output uncertainties, whereas in the latter case, with the uncertainty range constrained by aposteriori analyses, the flow rate's contribution becomes negligible. The trap and peel heights uncertainties are then mainly due to uncertainties in the 95% percentile of the droplet size and in the entrainment parameters.

  11. 2D Time-lapse Resistivity Monitoring of an Organic Produced Gas Plume in a Landfill using ERT.

    Science.gov (United States)

    Amaral, N. D.; Mendonça, C. A.; Doherty, R.

    2014-12-01

    This project has the objective to study a landfill located on the margins of Tietê River, in São Paulo, Brazil, using the electroresistivity tomography method (ERT). Due to huge organic matter concentrations in the São Paulo Basin quaternary sediments, there is subsurface depth related biogas accumulation (CH4 and CO2), induced by anaerobic degradation of the organic matter. 2D resistivity sections were obtained from a test area since March 2012, a total of 7 databases, being the last one dated from October 2013. The studied line has the length of 56m, the electrode interval is of 2m. In addition, there are two boreholes along the line (one with 3 electrodes and the other one with 2) in order to improve data quality and precision. The boreholes also have a multi-level sampling system that indicates the fluid (gas or water) presence in relation to depth. With our results it was possible to map the gas plume position and its area of extension in the sections as it is a positive resistivity anomaly, with the gas level having approximately 5m depth. With the time-lapse analysis (Matlab script) between the obtained 2D resistivity sections from the site, it was possible to map how the biogas volume and position change in the landfill in relation to time. Our preliminary results show a preferential gas pathway through the subsurface studied area. A consistent relation between the gas depth and obtained microbiological data from archea and bacteria population was also observed.

  12. Integration of organic based Schottly junctions into crossbar arrays by standard UV lithography

    DEFF Research Database (Denmark)

    Katsia, E.; Tallarida, G.; Kutrzeba-Kotowska, B.

    2008-01-01

    organic based Schottky diodes in a crossbar architecture, by standard UV lithography. The proposed integration route features a limited number of process steps and prevents the exposure of the active materials to UV. This approach was developed using poly(3-hexylthiophene) as a model compound...... and was successfully applied to different organic semiconductors. The electrical characteristics of the as prepared junctions reveal the successful patterning and demonstrate the compatibility of the process sequence steps with the organic materials....

  13. Determination of Diffusion Coefficients and Activation Energy of Selected Organic Liquids using Reversed-Flow Gas Chromatographic Technique

    International Nuclear Information System (INIS)

    Khalisanni Khalid; Rashid Atta Khan; Sharifuddin Mohd Zain

    2012-01-01

    Evaporation of vaporize organic liquid has ecological consequences when the compounds are introduced into both freshwater and marine environments through industrial effluents, or introduced directly into the air from industrial unit processes such as bioreactors and cooling towers. In such cases, a rapid and simple method are needed to measure physicochemical properties of the organic liquids. The Reversed-Flow Gas Chromatography (RF-GC) sampling technique is an easy, fast and accurate procedure. It was used to measure the diffusion coefficients of vapors from liquid into a carrier gas and at the same time to determine the rate coefficients for the evaporation of the respective liquid. The mathematical expression describing the elution curves of the samples peaks was derived and used to calculate the respective parameters for the selected liquid pollutants selected such as methanol, ethanol, 1-propanol, 1-butanol, n-pentane, n-hexane, n-heptane and n-hexadecane, evaporating into the carrier gas of nitrogen. The values of diffusion coefficients found were compared with those calculated theoretically or reported in the literature. The values of evaporation rate were used to determine the activation energy of respective samples using Arrhenius equation. An interesting finding of this work is by using an alternative mathematical analysis based on equilibrium at the liquid-gas interphase, the comparison leads to profound agreement between theoretical values of diffusion coefficients and experimental evidence. (author)

  14. Greenhouse gas fluxes from agricultural soils under organic and non-organic management — A global meta-analysis

    International Nuclear Information System (INIS)

    Skinner, Colin; Gattinger, Andreas; Muller, Adrian; Mäder, Paul; Fließbach, Andreas; Stolze, Matthias; Ruser, Reiner; Niggli, Urs

    2014-01-01

    It is anticipated that organic farming systems provide benefits concerning soil conservation and climate protection. A literature search on measured soil-derived greenhouse gas (GHG) (nitrous oxide and methane) fluxes under organic and non-organic management from farming system comparisons was conducted and followed by a meta-analysis. Up to date only 19 studies based on field measurements could be retrieved. Based on 12 studies that cover annual measurements, it appeared with a high significance that area-scaled nitrous oxide emissions from organically managed soils are 492 ± 160 kg CO 2 eq. ha −1 a −1 lower than from non-organically managed soils. For arable soils the difference amounts to 497 ± 162 kg CO 2 eq. ha −1 a −1 . However, yield-scaled nitrous oxide emissions are higher by 41 ± 34 kg CO 2 eq. t −1 DM under organic management (arable and use). To equalize this mean difference in yield-scaled nitrous oxide emissions between both farming systems, the yield gap has to be less than 17%. Emissions from conventionally managed soils seemed to be influenced mainly by total N inputs, whereas for organically managed soils other variables such as soil characteristics seemed to be more important. This can be explained by the higher bioavailability of the synthetic N fertilisers in non-organic farming systems while the necessary mineralisation of the N sources under organic management leads to lower and retarded availability. Furthermore, a higher methane uptake of 3.2 ± 2.5 kg CO 2 eq. ha −1 a −1 for arable soils under organic management can be observed. Only one comparative study on rice paddies has been published up to date. All 19 retrieved studies were conducted in the Northern hemisphere under temperate climate. Further GHG flux measurements in farming system comparisons are required to confirm the results and close the existing knowledge gaps. - Highlights: • Lower area-scaled nitrous oxide emissions from soils managed organically compared

  15. Natural gas market assessment: Price convergence in North American natural gas markets

    International Nuclear Information System (INIS)

    1995-12-01

    The extent to which Canadian and U.S. natural gas markets have become integrated in the post-deregulation era was assessed. This assessment was accomplished through a statistical analysis of the price movements in Canadian and U.S. gas markets. The analysis pointed to three broad conclusions: (1) on the whole, there has been an increasing degree of integration among North American natural gas markets since price deregulation and the introduction of open access, (2) there is somewhat of a split between eastern and western markets, (3) Alberta's links are stronger with the western U.S. natural gas market than with the market in the eastern U.S. Several factors were cited as contributing to the general increase in market integration, including: (1) increased pipeline capacity and additional pipeline interconnections, coupled with the development of market hubs, (2) improved flexibility of access to pipeline transportation services, (3) improved access to market information and greater trading flexibility which has been facilitated by growing use of electronic bulletin boards and electronic trading systems. The increased market integration was claimed to have benefited both consumers and producers, and to have increased competition in both countries.. 28 refs., 14 figs

  16. Integration of a municipal solid waste gasification plant with solid oxide fuel cell and gas turbine

    DEFF Research Database (Denmark)

    Bellomare, Filippo; Rokni, Masoud

    2013-01-01

    An interesting source of producing energy with low pollutants emission and reduced environmental impact are the biomasses; particularly using Municipal Solid Waste (MSW) as fuel, can be a competitive solution not only to produce energy with negligible costs but also to decrease the storage...... in landfills. A Municipal Solid Waste Gasification Plant Integrated with Solid Oxide Fuel Cell (SOFC) and Gas Turbine (GT) has been studied and the plant is called IGSG (Integrated Gasification SOFC and GT). Gasification plant is fed by MSW to produce syngas by which the anode side of an SOFC is fed wherein...

  17. Integrated biomass gasification using the waste heat from hot slags: Control of syngas and polluting gas releases

    International Nuclear Information System (INIS)

    Sun, Yongqi; Seetharaman, Seshadri; Liu, Qianyi; Zhang, Zuotai; Liu, Lili; Wang, Xidong

    2016-01-01

    In this study, the thermodynamics of a novel strategy, i.e., biomass/CO 2 gasification integrated with heat recovery from hot slags in the steel industry, were systemically investigated. Both the target syngas yield and the polluting gas release were considered where the effect of gasifying conditions including temperature, pressure and CO 2 reacted was analyzed and then the roles of hot slags were further clarified. The results indicated that there existed an optimum temperature for the maximization of H 2 production. Compared to blast furnace slags, steel slags remarkably increased the CO yield at 600–1400 °C due to the existence of iron oxides and decreased the S-containing gas releases at 400–700 °C, indicating potential desulfurizing ability. The identification of biomass/CO 2 gasification thermodynamics in presence of slags could thus provide important clues not only for the deep understanding of biomass gasification but also for the industrial application of this emerging strategy from the viewpoint of syngas optimization and pollution control. - Highlights: • Biomass/CO 2 gasification was integrated with the heat recovery from hot slags. • Both syngas yield and polluting gas release during gasification were determined. • There existed an optimum temperature for the maximization of H 2 production. • Steel slags increased CO yield at 600–1400 °C due to the existence of iron oxides. • Steel slags remarkably decreased the releases of S-containing gas at 400–700 °C.

  18. Orientation and Integration of New Employees in an Organization Hotel

    Directory of Open Access Journals (Sweden)

    Daniel Dăneci-Pătrău

    2016-01-01

    The aim of this study is to highlight the role and importance of the integration process,orientation and training of new employees within an organization hotel. To achieve was analyzedprofessional orientation program for new employees in the department reception at Hotel DaliConstanta, offering a guide to best practices be reflected in the behavior of employees to hotelguests in the future.

  19. Tissue engineering and cell-based therapy toward integrated strategy with artificial organs.

    Science.gov (United States)

    Gojo, Satoshi; Toyoda, Masashi; Umezawa, Akihiro

    2011-09-01

    Research in order that artificial organs can supplement or completely replace the functions of impaired or damaged tissues and internal organs has been underway for many years. The recent clinical development of implantable left ventricular assist devices has revolutionized the treatment of patients with heart failure. The emerging field of regenerative medicine, which uses human cells and tissues to regenerate internal organs, is now advancing from basic and clinical research to clinical application. In this review, we focus on the novel biomaterials, i.e., fusion protein, and approaches such as three-dimensional and whole-organ tissue engineering. We also compare induced pluripotent stem cells, directly reprogrammed cardiomyocytes, and somatic stem cells for cell source of future cell-based therapy. Integrated strategy of artificial organ and tissue engineering/regenerative medicine should give rise to a new era of medical treatment to organ failure.

  20. Fabricating an organic complementary inverter by integrating two transistors on a single substrate

    International Nuclear Information System (INIS)

    Wang Jun; Wei Bin; Zhang Jianhua

    2008-01-01

    Organic complementary inverters were fabricated by integrating two transistors of different electric type on a single substrate. One is a p-type organic heterojunction transistor with a depletion–accumulation mode that acts as a load element. The other is an n-type transistor with an accumulation mode that acts as a drive element. Typical inverter characteristics with a voltage gain of 12 were obtained. Compared with conventional devices, our organic complementary inverter used only one-step patterning of an organic semiconductor, and simultaneously suppressed the leakage current between supply voltage and ground. Therefore, current studies provide a simpler path to fabrication of organic complementary circuits

  1. INTEGRAL-FIELD STELLAR AND IONIZED GAS KINEMATICS OF PECULIAR VIRGO CLUSTER SPIRAL GALAXIES

    International Nuclear Information System (INIS)

    Cortés, Juan R.; Hardy, Eduardo; Kenney, Jeffrey D. P.

    2015-01-01

    We present the stellar and ionized gas kinematics of 13 bright peculiar Virgo cluster galaxies observed with the DensePak Integral Field Unit at the WIYN 3.5 m telescope in order to look for kinematic evidence that these galaxies have experienced gravitational interactions or gas stripping. Two-dimensional maps of the stellar velocity V, stellar velocity dispersion σ, and the ionized gas velocity (Hβ and/or [O III]) are presented for the galaxies in the sample. The stellar rotation curves and velocity dispersion profiles are determined for 13 galaxies, and the ionized gas rotation curves are determined for 6 galaxies. Misalignments between the optical and kinematical major axes are found in several galaxies. While in some cases this is due to a bar, in other cases it seems to be associated with gravitational interaction or ongoing ram pressure stripping. Non-circular gas motions are found in nine galaxies, with various causes including bars, nuclear outflows, or gravitational disturbances. Several galaxies have signatures of kinematically distinct stellar components, which are likely signatures of accretion or mergers. For all of our galaxies, we compute the angular momentum parameter λ R . An evaluation of the galaxies in the λ R ellipticity plane shows that all but two of the galaxies have significant support from random stellar motions, and have likely experienced gravitational interactions. This includes some galaxies with very small bulges and truncated/compact Hα morphologies, indicating that such galaxies cannot be fully explained by simple ram pressure stripping, but must have had significant gravitational encounters. Most of the sample galaxies show evidence for ICM-ISM stripping as well as gravitational interactions, indicating that the evolution of a significant fraction of cluster galaxies is likely strongly impacted by both effects

  2. Application of Homochiral Alkylated Organic Cages as Chiral Stationary Phases for Molecular Separations by Capillary Gas Chromatography.

    Science.gov (United States)

    Xie, Shengming; Zhang, Junhui; Fu, Nan; Wang, Bangjin; Hu, Cong; Yuan, Liming

    2016-11-08

    Molecular organic cage compounds have attracted considerable attention due to their potential applications in gas storage, catalysis, chemical sensing, molecular separations, etc. In this study, a homochiral pentyl cage compound was synthesized from a condensation reaction of ( S , S )-1,2-pentyl-1,2-diaminoethane and 1,3,5-triformylbenzene. The imine-linked pentyl cage diluted with a polysiloxane (OV-1701) was explored as a novel stationary phase for high-resolution gas chromatographic separation of organic compounds. Some positional isomers were baseline separated on the pentyl cage-coated capillary column. In particular, various types of enantiomers including chiral alcohols, esters, ethers and epoxides can be resolved without derivatization on the pentyl cage-coated capillary column. The reproducibility of the pentyl cage-coated capillary column for separation was investigated using nitrochlorobenzene and styrene oxide as analytes. The results indicate that the column has good stability and separation reproducibility after being repeatedly used. This work demonstrates that molecular organic cage compounds could become a novel class of chiral separation media in the near future.

  3. Application of Homochiral Alkylated Organic Cages as Chiral Stationary Phases for Molecular Separations by Capillary Gas Chromatography

    Directory of Open Access Journals (Sweden)

    Shengming Xie

    2016-11-01

    Full Text Available Molecular organic cage compounds have attracted considerable attention due to their potential applications in gas storage, catalysis, chemical sensing, molecular separations, etc. In this study, a homochiral pentyl cage compound was synthesized from a condensation reaction of (S,S-1,2-pentyl-1,2-diaminoethane and 1,3,5-triformylbenzene. The imine-linked pentyl cage diluted with a polysiloxane (OV-1701 was explored as a novel stationary phase for high-resolution gas chromatographic separation of organic compounds. Some positional isomers were baseline separated on the pentyl cage-coated capillary column. In particular, various types of enantiomers including chiral alcohols, esters, ethers and epoxides can be resolved without derivatization on the pentyl cage-coated capillary column. The reproducibility of the pentyl cage-coated capillary column for separation was investigated using nitrochlorobenzene and styrene oxide as analytes. The results indicate that the column has good stability and separation reproducibility after being repeatedly used. This work demonstrates that molecular organic cage compounds could become a novel class of chiral separation media in the near future.

  4. Strategical integration and prior evaluation of science and innovation projects in Ecuadorians sports organizations.

    Directory of Open Access Journals (Sweden)

    Gloria Barroso Rodríguez

    2015-09-01

    Full Text Available This work shows the design of a procedure for evaluating the strategical integration of science and innovation projects level in the physical and sport sphere, and its validation through expert criteria for application to Ecuadorian sports organizations. As a result, it was possible to demonstrate the validity of the procedure designed, so it will be possible to be used to facilitate decision-making in relation to the execution of such projects considering, as a value judgment, the level of their essential components integration for the achievement of objectives aligned to the strategic priorities of the Ecuadorians sports organizations.  

  5. Integrating Corporate Social Responsability Programs into the Ethical Dimension of the Organization

    OpenAIRE

    Ibrian CARAMIDARU; Sabina IRIMIE

    2011-01-01

    The purpose of this paper is to indicate the need to integrate corporate social responsibility programs into the global ethical vision of organizations. Such an approach requires the definition of the corporation in relation to the moral values it assumes and the ways in which moral values occur within the organization. On this foundation, the authors examined the various implications that moral values have on the initiation and conduct of corporate social responsibility programs.

  6. Introducing Knowledge Management into the Integrated Management System of Nuclear Organizations

    International Nuclear Information System (INIS)

    Yanev, Y.; Brandner, A.; Kosilov, A.

    2016-01-01

    Full text: The analysis for introducing knowledge management into an integrated management system in nuclear organizations, conducted by NKMI, and discussed in a number of meetings in IAEA and other organizations has shown that currently there is no full and comprehensive implementation of KM in IMS. NKMI has suggested and developed a common, systematic approach for introducing Knowledge Management in the IMS of a nuclear regulatory organization, based on the concept of competence, graded approach and continuous improvement. The approach is based on the concept of integrating an initial review of all knowledge and competence needed for effective and efficient process implementation including a gap analysis and provision of compensatory measures. Knowledge resources are represented as a knowledge resource matrix, which are necessary to complete a given process successfully. The “performance” of the available knowledge resources contribute to an efficient regulatory process is also reviewed at the end of process implementation where relevant decision for enhancement of knowledge and competence are taken, including capturing, preserving, sharing and reuse of new knowledge, gained through the process implementation. The “knowledge resource matrix” approach is fully based on IAEA recommendation and has already been applied in a number of regulatory processes. (author

  7. The Research of Micro-structure and Gas Sensitivity of SnO2

    Directory of Open Access Journals (Sweden)

    Mingxin Song

    2014-07-01

    Full Text Available This paper adopts Sol-gel method and solid state reaction to make SnO2 matrix material and Sb2O3 is used as zuji to make SnO2 gas sensor under different sintering temperature. XRD analysis, SEM analysis and response time restoration test of working voltage sensitivity are choose to research SnO2 gas sensor constituents and influence factor on sensing properties by processing. Experiment results show that when the SnO2 make by sol-get method and Sb2O3 take up 2 %, Polyvinyl alcohol as an organic binder, platinum as catalyst, SnO2 gas sensor can get optimal integral sensing properties.

  8. Status and integration of the gas generation studies performed for the Hydrogen Safety Program

    International Nuclear Information System (INIS)

    Pederson, L.R.; Strachan, D.M.

    1993-02-01

    Waste in Tank 241-SY-101 on the Hanford Site generates and periodically releases hydrogen, nitrous oxide, and nitrogen gases. Studies have been conducted at several laboratories to determine the chemical mechanisms for the gas generation and release. Results from these studies are presented and integrated in an attempt to describe current understanding of the physical properties of the waste and the mechanisms of gas generation and retention. Existing tank data are consistent with the interpretation that gases are uniformly generated in the tank, released continuously from the convecting layer, and stored in the nonconvecting layer. Tank temperature measurements suggest that the waste consists of ''gobs'' of material that reach neutral buoyancy at different times. The activation energy of the rate limiting step of the gas generating process was calculated to be about 7 kJ/mol but measured in the laboratory at 80 to 100 kJ/mol. Based on observed temperature changes in the tank the activation energy is probably not higher than about 20 kJ/mol. Several simulated waste compositions have been devised for use in laboratory studies in the place of actual waste from Tank 241-SY-101. Data from these studies can be used to predict how the actual waste might behave when heated or diluted. Density evaluations do not confirm that heating waste at the bottom of the tank would induce circulation within the waste; however, heating may release gas bubbles by dissolving the solids to which the bubbles adhere. Gas generation studies on simulated wastes indicated that nitrous oxide and hydrogen yields are not particularly coupled. Solubility studies of nitrous oxide, the most soluble of the principal gaseous products, indicate it is unlikely that dissolved gases contribute substantially to the quantity of gas released during periodic events

  9. Integration of air quality-related planning processes : report

    International Nuclear Information System (INIS)

    2004-05-01

    Several communities in British Columbia have conducted air quality, greenhouse gas, or community energy management plans. This report explored the possibility of integrating 3 community-based air quality-related planning processes into a single process and evaluated the use of these 3 processes by local governments and First Nations in identifying and addressing air quality-related objectives, and determined to what extent they could be integrated to achieve planning objectives for air quality, greenhouse gas emissions, and energy supply and conservation. The lessons learned from 9 case studies in British Columbia were presented. The purpose of the case studies was to examine how communities handled emissions and energy related inventory and planning work, as well as their experiences with, or considerations for, an integrated process. The lessons were grouped under several key themes including organization and stakeholder involvement; messaging and focus; leadership/champions; and resources and capacity. The report also outlined a framework for an integrated planning process and provided recommendations regarding how an integrated or complementary process could be performed. A number of next steps were also offered for the provincial government to move the concept of an integrated process forward with the assistance of other partners. These included identifying the resources required to support communities engaging in an integrated process as well as discussing the series of options for provincial support with key stakeholders. refs., tabs., figs

  10. Physician organization-practice team integration for the advancement of patient-centered care.

    Science.gov (United States)

    Wise, Christopher G; Alexander, Jeffrey A; Green, Lee A; Cohen, Genna R

    2012-01-01

    The patient-centered medical home is being promoted as a cornerstone for transforming primary care. Physician organizations (POs) are playing a more prominent role by facilitating practices' transformation to the patient-centered medical home. Using a framework of organizational integration, we investigated the changing relationship between POs and practices through qualitative interviews. Through increased integration, POs can support both the big picture and day-to-day activities of practice transformation. Most PO-practice unit connections we identified reflected new areas of engagement-competencies that POs were not developing in the past-that are proving integral to the broad-scale practice change of patient-centered medical home implementation.

  11. Expert System for support of natural gas network management; Sistema especialista para gerenciamento de redes de gas natural: SEGRED

    Energy Technology Data Exchange (ETDEWEB)

    Silva, Jonny Carlos da [Universidade Federal de Santa Catarina (UFSC), Florianopolis, SC (Brazil); Hirano, Eduardo Wulff [Universidade Federal de Santa Catarina (UFSC), Florianopolis, SC (Brazil). Lab. de Hidraulica e Pneumatica (LASHIP); Moura, Newton Reis de [PETROBRAS, Rio de Janeiro, RJ (Brazil); Freire, Luiz Gustavo de Melo [PETROBRAS S.A., Pojuca, BA (Brazil). Unidade de Negocios de Gas Natural (UNGN)

    2004-07-01

    This work reports on the SEGRED project, which aims to develop an expert system for management of natural gas transportation networks. The system is currently being developed by LASHIP-UFSC in partnership with PETROBRAS/CENPES and TBG. The SEGRED system consists of an environment designed to support natural gas pipeline management by means of remote supervision of process parameters and analysis of the mutual interactions of those parameters by an expert system integrated to a dynamic simulator. The system is deployed through a process that contributes to making available for use the knowledge about functions such as line packing analysis and line break detection, thus enhancing the quality of execution of these tasks, which are related to the management of natural gas transportation network. The main benefits consist of promoting efforts to acquire and organize expert knowledge. This process contributes to the generation of a knowledge base with corporate technical memory, which can be made available in a permanent, expansible and useful way for decision-making. (author)

  12. Nonlinear-Based MEMS Sensors and Active Switches for Gas Detection

    KAUST Repository

    Bouchaala, Adam M.; Jaber, Nizar; Yassine, Omar; Shekhah, Osama; Chernikova, Valeriya; Eddaoudi, Mohamed; Younis, Mohammad I.

    2016-01-01

    The objective of this paper is to demonstrate the integration of a MOF thin film on electrostatically actuated microstructures to realize a switch triggered by gas and a sensing algorithm based on amplitude tracking. The devices are based on the nonlinear response of micromachined clamped-clamped beams. The microbeams are coated with a metal-organic framework (MOF), namely HKUST-1, to achieve high sensitivity. The softening and hardening nonlinear behaviors of the microbeams are exploited to demonstrate the ideas. For gas sensing, an amplitude-based tracking algorithm is developed to quantify the captured quantity of gas. Then, a MEMS switch triggered by gas using the nonlinear response of the microbeam is demonstrated. Noise analysis is conducted, which shows that the switch has high stability against thermal noise. The proposed switch is promising for delivering binary sensing information, and also can be used directly to activate useful functionalities, such as alarming.

  13. Nonlinear-Based MEMS Sensors and Active Switches for Gas Detection

    KAUST Repository

    Bouchaala, Adam M.

    2016-05-25

    The objective of this paper is to demonstrate the integration of a MOF thin film on electrostatically actuated microstructures to realize a switch triggered by gas and a sensing algorithm based on amplitude tracking. The devices are based on the nonlinear response of micromachined clamped-clamped beams. The microbeams are coated with a metal-organic framework (MOF), namely HKUST-1, to achieve high sensitivity. The softening and hardening nonlinear behaviors of the microbeams are exploited to demonstrate the ideas. For gas sensing, an amplitude-based tracking algorithm is developed to quantify the captured quantity of gas. Then, a MEMS switch triggered by gas using the nonlinear response of the microbeam is demonstrated. Noise analysis is conducted, which shows that the switch has high stability against thermal noise. The proposed switch is promising for delivering binary sensing information, and also can be used directly to activate useful functionalities, such as alarming.

  14. Nonlinear-Based MEMS Sensors and Active Switches for Gas Detection.

    Science.gov (United States)

    Bouchaala, Adam; Jaber, Nizar; Yassine, Omar; Shekhah, Osama; Chernikova, Valeriya; Eddaoudi, Mohamed; Younis, Mohammad I

    2016-05-25

    The objective of this paper is to demonstrate the integration of a MOF thin film on electrostatically actuated microstructures to realize a switch triggered by gas and a sensing algorithm based on amplitude tracking. The devices are based on the nonlinear response of micromachined clamped-clamped beams. The microbeams are coated with a metal-organic framework (MOF), namely HKUST-1, to achieve high sensitivity. The softening and hardening nonlinear behaviors of the microbeams are exploited to demonstrate the ideas. For gas sensing, an amplitude-based tracking algorithm is developed to quantify the captured quantity of gas. Then, a MEMS switch triggered by gas using the nonlinear response of the microbeam is demonstrated. Noise analysis is conducted, which shows that the switch has high stability against thermal noise. The proposed switch is promising for delivering binary sensing information, and also can be used directly to activate useful functionalities, such as alarming.

  15. Reducing life cycle greenhouse gas emissions of corn ethanol by integrating biomass to produce heat and power at ethanol plants

    International Nuclear Information System (INIS)

    Kaliyan, Nalladurai; Morey, R. Vance; Tiffany, Douglas G.

    2011-01-01

    A life-cycle assessment (LCA) of corn ethanol was conducted to determine the reduction in the life-cycle greenhouse gas (GHG) emissions for corn ethanol compared to gasoline by integrating biomass fuels to replace fossil fuels (natural gas and grid electricity) in a U.S. Midwest dry-grind corn ethanol plant producing 0.19 hm 3 y -1 of denatured ethanol. The biomass fuels studied are corn stover and ethanol co-products [dried distillers grains with solubles (DDGS), and syrup (solubles portion of DDGS)]. The biomass conversion technologies/systems considered are process heat (PH) only systems, combined heat and power (CHP) systems, and biomass integrated gasification combined cycle (BIGCC) systems. The life-cycle GHG emission reduction for corn ethanol compared to gasoline is 38.9% for PH with natural gas, 57.7% for PH with corn stover, 79.1% for CHP with corn stover, 78.2% for IGCC with natural gas, 119.0% for BIGCC with corn stover, and 111.4% for BIGCC with syrup and stover. These GHG emission estimates do not include indirect land use change effects. GHG emission reductions for CHP, IGCC, and BIGCC include power sent to the grid which replaces electricity from coal. BIGCC results in greater reductions in GHG emissions than IGCC with natural gas because biomass is substituted for fossil fuels. In addition, underground sequestration of CO 2 gas from the ethanol plant's fermentation tank could further reduce the life-cycle GHG emission for corn ethanol by 32% compared to gasoline.

  16. Highly Reliable Organizations in the Onshore Natural Gas Sector: An Assessment of Current Practices, Regulatory Frameworks, and Select Case Studies

    Energy Technology Data Exchange (ETDEWEB)

    Logan, Jeffrey S. [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Paranhos, Elizabeth [Energy Innovation Partners, Seattle, WA (United States); Kozak, Tracy G. [Energy Innovation Partners, Seattle, WA (United States); Boyd, William [Univ. of Colorado, Boulder, CO (United States)

    2017-07-31

    This study focuses on onshore natural gas operations and examines the extent to which oil and gas firms have embraced certain organizational characteristics that lead to 'high reliability' - understood here as strong safety and reliability records over extended periods of operation. The key questions that motivated this study include whether onshore oil and gas firms engaged in exploration and production (E&P) and midstream (i.e., natural gas transmission and storage) are implementing practices characteristic of high reliability organizations (HROs) and the extent to which any such practices are being driven by industry innovations and standards and/or regulatory requirements.

  17. Loose and Tight Coupling in Educational Organizations--An Integrative Literature Review

    Science.gov (United States)

    Hautala, Tanja; Helander, Jaakko; Korhonen, Vesa

    2018-01-01

    Purpose: The purpose of this paper is to review and synthesize the attributes of loose and tight coupling in educational organizations. In addition, it is aimed to determine whether this phenomenon has value and strategies to offer for the current educational administration and research. Design/methodology/approach: Integrative literature review…

  18. Greenhouse gas emissions from integrated urban drainage systems: Where do we stand?

    Science.gov (United States)

    Mannina, Giorgio; Butler, David; Benedetti, Lorenzo; Deletic, Ana; Fowdar, Harsha; Fu, Guangtao; Kleidorfer, Manfred; McCarthy, David; Steen Mikkelsen, Peter; Rauch, Wolfgang; Sweetapple, Chris; Vezzaro, Luca; Yuan, Zhiguo; Willems, Patrick

    2018-04-01

    As sources of greenhouse gas (GHG) emissions, integrated urban drainage systems (IUDSs) (i.e., sewer systems, wastewater treatment plants and receiving water bodies) contribute to climate change. This paper, produced by the International Working Group on Data and Models, which works under the IWA/IAHR Joint Committee on Urban Drainage, reviews the state-of-the-art and modelling tools developed recently to understand and manage GHG emissions from IUDS. Further, open problems and research gaps are discussed and a framework for handling GHG emissions from IUDSs is presented. The literature review reveals that there is a need to strengthen already available mathematical models for IUDS to take GHG into account.

  19. Intelligent Integration between Human Simulated Intelligence and Expert Control Technology for the Combustion Process of Gas Heating Furnace

    Directory of Open Access Journals (Sweden)

    Yucheng Liu

    2014-01-01

    Full Text Available Due to being poor in control quality of the combustion process of gas heating furnace, this paper explored a sort of strong robust control algorithm in order to improve the control quality of the combustion process of gas heating furnace. The paper analyzed the control puzzle in the complex combustion process of gas heating furnace, summarized the cybernetics characteristic of the complex combustion process, researched into control strategy of the uncertainty complex control process, discussed the control model of the complex process, presented a sort of intelligent integration between human-simulated intelligence and expert control technology, and constructed the control algorithm for the combustion process controlling of gas heating furnace. The simulation results showed that the control algorithm proposed in the paper is not only better in dynamic and steady quality of the combustion process, but also obvious in energy saving effect, feasible, and effective in control strategy.

  20. The Integration and Applications of Organic Thin Film Transistors and Ferroelectric Polymers

    Science.gov (United States)

    Hsu, Yu-Jen

    Organic thin film transistors and ferroelectric polymer (polyvinylidene difluoride) sheet material are integrated to form various sensors for stress/strain, acoustic wave, and Infrared (heat) sensing applications. Different from silicon-based transistors, organic thin film transistors can be fabricated and processed in room-temperature and integrated with a variety of substrates. On the other hand, polyvinylidene difluoride (PVDF) exhibits ferroelectric properties that are highly useful for sensor applications. The wide frequency bandwidth (0.001 Hz to 10 GHz), vast dynamic range (100n to 10M psi), and high elastic compliance (up to 3 percent) make PVDF a more suitable candidate over ceramic piezoelectric materials for thin and flexible sensor applications. However, the low Curie temperature may have impeded its integration with silicon technology. Organic thin film transistors, however, do not have the limitation of processing temperature, hence can serve as transimpedance amplifiers to convert the charge signal generated by PVDF into current signal that are more measurable and less affected by any downstream parasitics. Piezoelectric sensors are useful for a range of applications, but passive arrays suffer from crosstalk and signal attenuation which have complicated the development of array-based PVDF sensors. We have used organic field effect transistors, which are compatible with the low Curie temperature of a flexible piezoelectric polymer,PVDF, to monolithically fabricate transimpedance amplifiers directly on the sensor surface and convert the piezoelectric charge signal into a current signal which can be detected even in the presence of parasitic capacitances. The device couples the voltage generated by the PVDF film under strain into the gate of the organic thin film transistors (OFET) using an arrangement that allows the full piezoelectric voltage to couple to the channel, while also increasing the charge retention time. A bipolar detector is created by

  1. Calcium and organic matter removal by carbonation process with waste incineration flue gas towards improvement of leachate biotreatment performance.

    Science.gov (United States)

    Zhang, Cheng; Zhu, Xuedong; Wu, Liang; Li, Qingtao; Liu, Jianyong; Qian, Guangren

    2017-09-01

    Municipal solid wastes incineration (MSWI) flue gas was employed as the carbon source for in-situ calcium removal from MSWI leachate. Calcium removal efficiency was 95-97% with pH of 10.0-11.0 over 100min of flue gas aeration, with both bound Ca and free Ca being removed effectively. The fluorescence intensity of tryptophan, protein-like and humic acid-like compounds increased after carbonation process. The decrease of bound Ca with the increase of precipitate indicated that calcium was mainly converted to calcium carbonate precipitate. It suggested that the interaction between dissolved organic matter and Ca 2+ was weakened. Moreover, 10-16% of chemical oxygen demand removal and the decrease of ultraviolet absorption at 254nm indicated that some organics, especially aromatic compound decreased via adsorption onto the surface of calcium carbonate. The results indicate that introduce of waste incineration flue gas could be a feasible way for calcium removal from leachate. Copyright © 2017 Elsevier Ltd. All rights reserved.

  2. Energy resources' utilization in organic and conventional vineyards: Energy flow, greenhouse gas emissions and biofuel production

    International Nuclear Information System (INIS)

    Kavargiris, Stefanos E.; Mamolos, Andreas P.; Tsatsarelis, Constantinos A.; Nikolaidou, Anna E.; Kalburtji, Kiriaki L.

    2009-01-01

    An energy analysis, in conventional and organic vineyards, combined with ethanol production and greenhouse gas emissions, is useful in evaluating present situation and deciding best management strategies. The objective of this study was to evaluate the differences in the energy flow between organic and conventional vineyards in three locations, to calculate CO 2 , CH 4 and N 2 O-emissions based on the used fossil energy and to explore if wine industry wastes can be used to extract bioethanol. The data were collected through personal interviews with farmers during 2004-2005. Eighteen farmers, who owned vineyards about 1 ha each, were randomly selected to participate in this study [(3 conventional and 3 organic) x 3 locations]. The means averaged over all locations for fertilizer application, plant protection products application, transportation, harvesting, labor, machinery, fuels, plant protections products and tools energy inputs, total energy inputs, outputs (grapes), outputs (grapes + shoots), grape yield, man hour, pomace and ethanol from pomace were significantly higher in conventional than in organic vineyards, while the opposite occurred for the pruning. Means averaged over two farming systems for harvesting, tools energy inputs, energy outputs (grapes), grape yield, pomace and ethanol from pomace were significantly higher at location A, followed by location C and location B. Finally, for irrigation, the means averaged over the two farming systems were significantly lower at location C. Greenhouse gas emissions were significant lower in organic than in conventional vineyards. The results show a clear response of energy inputs to energy outputs that resulted from the farming system and location.

  3. The use of radon (Rn-222) and volatile organic compounds in monitoring soil gas to localize NAPL contamination at a gas station in Rio Claro, São Paulo State, Brazil

    International Nuclear Information System (INIS)

    Barbosa, E.Q.; Galhardi, J.A.; Bonotto, D.M.

    2014-01-01

    This study focuses on the presence of radon ( 222 Rn) and volatile organic compounds (VOCs) in soil gases at a gas station located in the city of Rio Claro, São Paulo, Brazil, where a fossil fuel leak occurred. The spatial distribution results show a correlation between 222 Rn and VOCs, consistent with the fact that radon gas has a greater chemical affinity with organic phases than with water. This finding demonstrates that the presence of a residual hydrocarbon phase in an aquifer can retain radon, leading to a reduced radon content in the soil gas. The data in this study confirm the results of previous investigations, in which the method used in this study provided a preliminary fingerprint of a contaminated area. Furthermore, the data analysis time is brief, and only simple equipment is required. - Highlights: • 222 Rn in soil gases. • Correlation between 222 Rn and VOCs. • Useful method as a preliminary fingerprint of a contaminated area

  4. Gas-liquid partitioning of halogenated volatile organic compounds in aqueous cyclodextrin solutions

    Energy Technology Data Exchange (ETDEWEB)

    Ondo, Daniel; Barankova, Eva [Department of Physical Chemistry, Institute of Chemical Technology, Technicka 5, 166 28 Prague 6 (Czech Republic); Dohnal, Vladimir, E-mail: dohnalv@vscht.cz [Department of Physical Chemistry, Institute of Chemical Technology, Technicka 5, 166 28 Prague 6 (Czech Republic)

    2011-08-15

    Highlights: > Binding of halogenated VOCs with cyclodextrins examined through g-l partitioning. > Complex stabilities reflect host-guest size matching and hydrophobic interaction. > Presence of halogens in the guest molecule stabilizes the binding. > Thermodynamic origin of the binding varies greatly among the systems studied. > Results obey the guest-CD global enthalpy-entropy compensation relationship. - Abstract: Gas-liquid partitioning coefficients (K{sub GL}) were measured for halogenated volatile organic compounds (VOCs), namely 1-chlorobutane, methoxyflurane, pentafluoropropan-1-ol, heptafluorobutan-1-ol, {alpha},{alpha},{alpha}-trifluorotoluene, and toluene in aqueous solutions of natural {alpha}-, {beta}-, and {gamma}-cyclodextrins (CDs) at temperatures from (273.35 to 326.35) K employing the techniques of headspace gas chromatography and inert gas stripping. The binding constants of the 1:1 inclusion complex formation between the VOCs and CDs were evaluated from the depression of the VOCs volatility as a function of CD concentration. The host-guest size matching and the hydrophobic interaction concept were used to rationalize the observed widely different affinity of the VOC-CD pairs to form the inclusion complex. The enthalpic and entropic component of the standard Gibbs free energy of complex formation as derived from the temperature dependence of the binding constant indicate the thermodynamic origin of the binding to vary greatly among the systems studied, but follow the global enthalpy-entropy compensation relationships reported previously in the literature.

  5. Characteristics of the volatile organic compounds -- Arid Integrated Demonstration Site

    International Nuclear Information System (INIS)

    Last, G.V.; Lenhard, R.J.; Bjornstad, B.N.; Evans, J.C.; Roberson, K.R.; Spane, F.A.; Amonette, J.E.; Rockhold, M.L.

    1991-10-01

    The Volatile Organic Compounds -- Arid Integrated Demonstration Program (VOC-Arid ID) is targeted at demonstration and testing of technologies for the evaluation and cleanup of volatile organic compounds and associated contaminants at arid DOE sites. The initial demonstration site is an area of carbon tetrachloride (CCl 4 ) contamination located near the center of the Hanford Site. The movement of CCl 4 and other volatile organic contaminants in the subsurface is very complex. The problem at the Hanford Site is further complicated by the concurrent discharge of other waste constituents including acids, lard oil, organic phosphates, and transuranic radionuclides. In addition, the subsurface environment is very complex, with large spatial variabilities in hydraulic properties. A thorough understanding of the problem is essential to the selection of appropriate containment, retrieval, and/or in situ remedial technologies. The effectiveness of remedial technologies depends on knowing where the contaminants are, how they are held up in a given physical and chemical subsurface environment; and knowing the physical, chemical, and microbiological changes that are induced by the various remedial technologies

  6. A new integrated planning model for gas compression and transmission through a complex pipeline network; Um novo modelo de planejamento integrado de compressao e escoamento de gas para uma rede complexa

    Energy Technology Data Exchange (ETDEWEB)

    Iamashita, Edson K. [PETROBRAS, Rio de Janeiro, RJ (Brazil); Galaxe, Frederico; Arica, Jose [Universidade Estadual do Norte Fluminense (UENF), Campos dos Goytacases, RJ (Brazil)

    2005-07-01

    The aim of this paper is to show a new approach to solve integrated gas balance planning problems that defines the best compression and transmission strategy for a system with a large number of platforms or compression units that are interlinked with the delivery points through a complex gas pipeline network. For solving the proposed optimization problem is used a genetic meta-heuristic technique, where the fitness function of the algorithm is the Profit function of the gas balance, being considered the incomes and costs besides the pipeline network constraints, representing the compression system and transmission network near to the real operational condition. Newton Raphson's method is used to solve the nonlinear system that represents the calculation of the pressure drop in the gas pipeline network that can contain various cycles. This model could be used for design and optimization of gas pipeline networks, as well as for the gas balance planning of an existent network looking for the profit maximization. (author)

  7. Real-Time Measurements of Gas/Particle Partitioning of Semivolatile Organic Compounds into Different Probe Particles in a Teflon Chamber

    Science.gov (United States)

    Liu, X.; Day, D. A.; Ziemann, P. J.; Krechmer, J. E.; Jimenez, J. L.

    2017-12-01

    The partitioning of semivolatile organic compounds (SVOCs) into and out of particles plays an essential role in secondary organic aerosol (SOA) formation and evolution. Most atmospheric models treat the gas/particle partitioning as an equilibrium between bulk gas and particle phases, despite potential kinetic limitations and differences in thermodynamics as a function of SOA and pre-existing OA composition. This study directly measures the partitioning of oxidized compounds in a Teflon chamber in the presence of single component seeds of different phases and polarities, including oleic acid, squalane, dioctyl sebacate, pentaethylene glycol, dry/wet ammonium sulfate, and dry/wet sucrose. The oxidized compounds are generated by a fast OH oxidation of a series of alkanols under high nitric oxide conditions. The observed SOA mass enhancements are highest with oleic acid, and lowest with wet ammonium sulfate and sucrose. A chemical ionization mass spectrometer (CIMS) was used to measure the decay of gas-phase organic nitrates, which reflects uptake by particles and chamber walls. We observed clear changes in equilibrium timescales with varying seed concentrations and in equilibrium gas-phase concentrations across different seeds. In general, the gas evolution can be reproduced by a kinetic box model that considers partitioning and evaporation with particles and chamber walls, except for the wet sucrose system. The accommodation coefficient and saturation mass concentration of each species in the presence of each seed are derived using the model. The changes in particle size distributions and composition monitored by a scanning mobility particle sizer (SMPS) and a high-resolution time-of-flight aerosol mass spectrometer (HR-ToF-AMS) are investigated to probe the SOA formation mechanism. Based on these results, the applicability of partitioning theory to these systems and the relevant quantitative parameters, including the dependencies on seed particle composition, will

  8. Modeling and optimization of integrated exhaust gas recirculation and multi-stage waste heat recovery in marine engines

    DEFF Research Database (Denmark)

    Kyriakidis, Fotis; Sørensen, Kim; Singh, Shobhana

    2017-01-01

    Waste heat recovery combined with exhaust gas recirculation is a promising technology that can address both the issue of NOx (nitrogen oxides) reduction and fuel savings by including a pressurized boiler. In the present study, a theoretical optimization of the performance of two different...... configurations of steam Rankine cycles, with integrated exhaust gas recirculation for a marine diesel engine, is presented. The first configuration employs two pressure levels and the second is configured with three-pressure levels. The models are developed in MATLAB based on the typical data of a large two......-stroke marine diesel engine. A turbocharger model together with a blower, a pre-scrubber and a cooler for the exhaust gas recirculation line, are included. The steam turbine, depending on the configuration, is modeled as either a dual or triple pressure level turbine. The condensation and pre-heating process...

  9. Greenhouse gas fluxes from agricultural soils under organic and non-organic management — A global meta-analysis

    Energy Technology Data Exchange (ETDEWEB)

    Skinner, Colin, E-mail: colin.skinner@fibl.org [Research Institute of Organic Agriculture (FiBL), Ackerstrasse 21, 5070 Frick (Switzerland); Gattinger, Andreas, E-mail: andreas.gattinger@fibl.org [Research Institute of Organic Agriculture (FiBL), Ackerstrasse 21, 5070 Frick (Switzerland); Muller, Adrian, E-mail: adrian.mueller@fibl.org [Research Institute of Organic Agriculture (FiBL), Ackerstrasse 21, 5070 Frick (Switzerland); Mäder, Paul, E-mail: paul.maeder@fibl.org [Research Institute of Organic Agriculture (FiBL), Ackerstrasse 21, 5070 Frick (Switzerland); Fließbach, Andreas, E-mail: andreas.fliessbach@fibl.org [Research Institute of Organic Agriculture (FiBL), Ackerstrasse 21, 5070 Frick (Switzerland); Stolze, Matthias, E-mail: matthias.stolze@fibl.org [Research Institute of Organic Agriculture (FiBL), Ackerstrasse 21, 5070 Frick (Switzerland); Ruser, Reiner, E-mail: reiner.ruser@uni-hohenheim.de [Fertilisation and Soil Matter Dynamics (340i), Institute of Crop Science, University of Hohenheim, Fruwirthstraße 20, 70599 Stuttgart (Germany); Niggli, Urs, E-mail: urs.niggli@fibl.org [Research Institute of Organic Agriculture (FiBL), Ackerstrasse 21, 5070 Frick (Switzerland)

    2014-01-01

    It is anticipated that organic farming systems provide benefits concerning soil conservation and climate protection. A literature search on measured soil-derived greenhouse gas (GHG) (nitrous oxide and methane) fluxes under organic and non-organic management from farming system comparisons was conducted and followed by a meta-analysis. Up to date only 19 studies based on field measurements could be retrieved. Based on 12 studies that cover annual measurements, it appeared with a high significance that area-scaled nitrous oxide emissions from organically managed soils are 492 ± 160 kg CO{sub 2} eq. ha{sup −1} a{sup −1} lower than from non-organically managed soils. For arable soils the difference amounts to 497 ± 162 kg CO{sub 2} eq. ha{sup −1} a{sup −1}. However, yield-scaled nitrous oxide emissions are higher by 41 ± 34 kg CO{sub 2} eq. t{sup −1} DM under organic management (arable and use). To equalize this mean difference in yield-scaled nitrous oxide emissions between both farming systems, the yield gap has to be less than 17%. Emissions from conventionally managed soils seemed to be influenced mainly by total N inputs, whereas for organically managed soils other variables such as soil characteristics seemed to be more important. This can be explained by the higher bioavailability of the synthetic N fertilisers in non-organic farming systems while the necessary mineralisation of the N sources under organic management leads to lower and retarded availability. Furthermore, a higher methane uptake of 3.2 ± 2.5 kg CO{sub 2} eq. ha{sup −1} a{sup −1} for arable soils under organic management can be observed. Only one comparative study on rice paddies has been published up to date. All 19 retrieved studies were conducted in the Northern hemisphere under temperate climate. Further GHG flux measurements in farming system comparisons are required to confirm the results and close the existing knowledge gaps. - Highlights: • Lower area-scaled nitrous

  10. Microfluidics and thin-film processes: a recipe for organic integrated photonics based on 3D microresonators

    Science.gov (United States)

    Huby, N.; Pluchon, D.; Belloul, M.; Moreac, A.; Coulon, N.; Gaviot, E.; Panizza, P.; B"che, B.

    2010-02-01

    We report on the design and realization of photonic integrated devices based on 3D organic microresonators. This has been achieved by combining microfluidics techniques and thin-film processes. The microfluidic device and the control of the flow rates of the continuous and dispersed phases allow the fabrication of organic microresonators with diameter ranging from 30 to 200 μm. The resonance of the sphere in air has been first investigated by using the Raman spectroscopy set-up demonstrating the appropriate photonic properties. Then the microresonators have been integrated on an organic chip made of the photosensitive resin SU-8 and positioned at the extremity of a taper and alongside a rib waveguide. The realization of these structures by thin-film processes needs one step UV-lithography leading to 6μm width and 30μm height. Both devices have proved the efficient evanescent coupling leading to the excitation of the whispering gallery modes confined at the surface of the organic 3D microresonators. Finally, a band-stop filter has been used to detect the resonance spectra of the resonators once integrated.

  11. Soil greenhouse gas emissions from afforested organic soil croplands and cutaway peatlands

    International Nuclear Information System (INIS)

    Maekiranta, P.; Hytoenen, J.; Aro, L.

    2007-01-01

    The effects of land-use and land-use change on soil greenhouse gas (GHG) fluxes are of concern due to Kyoto Protocol requirements. To quantify the soil GHG-fluxes of afforested organic soils in Finland, chamber measurements of soil CO 2 , CH 4 and N 2 O fluxes were made during the years 2002 to 2005 on twelve organic soil cropland and six cutaway peatland sites afforested 9 to 35 years ago. The annual soil CO 2 effluxes were statistically modelled using soil temperature as the driving variable and the annual CH 4 and N 2 O fluxes were estimated using the average fluxes during the measurement period. Soil CO 2 effluxes on afforested organic soil croplands varied from 207 to 539 g CO 2 -C m -2 a -1 and on cutaway peatlands from 276 to 479 g CO 2 -C m -2 a -1 . Both the afforested organic soil cropland and cutaway peatland sites acted mainly as small sinks for CH 4 ; the annual flux ranged from -0.32 to 0.61 g CH 4 -C m -2 . Afforested organic croplands emitted more N 2 O (from 0.1 to over 3.0 g N 2 O-N m -2 a -1 ) than cutaway peatland sites (from 0.01 to 0.48 g N 2 O-N m -2 a -1 ). Due to the decrease in soil CO 2 efflux, and no change in CH 4 and N 2 O fluxes, afforestation of organic croplands appears to decrease the greenhouse impact of these lands. (orig.)

  12. Integral anomalous effect of an oil and gas deposit in a seismic wave field

    Energy Technology Data Exchange (ETDEWEB)

    Korostyshevskiy, M.B.; Nabokov, G.N.

    1981-01-01

    The basic precepts of an elaborated version of a procedure for forecasting (direct exploration) of oil and gas deposits according to seismic prospecting data MOV are examined. This procedure was previously called the procedure of analysis of the integral affect of an oil and gas deposit in a seismic wave field (MIIEZ-VP). The procedure is implemented in the form of an automated system ASOM-VP for the BESM-4 computer in a standard configuration equipped with standard input-output devices for seismic information (''Potok'', MVU, ''Atlas''). The entire procedure of processing from input of data into the computer to output of resulting maps and graphs on graph plotter ''Atlas'' is automated. Results of testing of procedure MIIEZ-VP and system ASOM-VP on drilled areas of Kazakhstan, Azerbaydzhan and Uzbekistan are cited.

  13. Effort Optimization in Minimizing Food Related Greenhouse Gas Emissions, a look at "Organic" and "Local"

    Science.gov (United States)

    Bowen, E.; Martin, P. A.; Eshel, G.

    2008-12-01

    The adverse environmental effects, especially energy use and resultant GHG emissions, of food production and consumption are becoming more widely appreciated and increasingly well documented. Our insights into the thorny problem of how to mitigate some of those effects, however, are far less evolved. Two of the most commonly advocated strategies are "organic" and "local", referring, respectively, to growing food without major inputs of fossil fuel based synthetic fertilizers and pesticides and to food consumption near its agricultural origin. Indeed, both agrochemical manufacture and transportation of produce to market make up a significant percentage of energy use in agriculture. While there can be unique environmental benefits to each strategy, "organic" and "local" each may potentially result in energy and emissions savings relative to conventionally grown produce. Here, we quantify the potential energy and greenhouse gas emissions savings associated with "organic" and "local". We take note of energy use and actual GHG costs of the major synthetic fertilizers and transportation by various modes routinely employed in agricultural distribution chains, and compare them for ~35 frequently consumed nutritional mainstays. We present new, current, lower-bound energy and greenhouse gas efficiency estimates for these items and compare energy consumption and GHG emissions incurred during producing those food items to consumption and emissions resulting from transporting them, considering travel distances ranging from local to continental and transportation modes ranging from (most efficient) rail to (least efficient) air. In performing those calculations, we demonstrate the environmental superiority of either local or organic over conventional foods, and illuminate the complexities involved in entertaining the timely yet currently unanswered, and previously unanswerable, question of "Which is Environmentally Superior, Organic or Local?". More broadly, we put forth a

  14. A comparative analysis of vehicle-related greenhouse gas emissions between organic and conventional dairy production.

    Science.gov (United States)

    Aggestam, Vivianne; Buick, Jon

    2017-08-01

    Agricultural industrialisation and globalisation have steadily increased the transportation of food across the world. In efforts to promote sustainability and self-sufficiency, organic milk producers in Sweden are required to produce a higher level of cattle feed on-farm in the hope that increased self-sufficiency will reduce reliance on external inputs and reduce transport-related greenhouse gas emissions. Using data collected from 20 conventional and 20 organic milk producers in Sweden this paper aims to assess the global warming impact of farmyard vehicles and the transportation of feed produced 'off-farm' in order to compare the impact of vehicle-related emissions from the different production methods. The findings show organic and conventional production methods have different vehicle-related emission outputs that vary according to a reliance on either road transportation or increased farmyard machinery use. Mechanical weeding is more fuel demanding than conventional agrichemical sprayers. However, artificial fertilising is one of the highest farmyard vehicle-related emitters. The general findings show organic milk production emits higher levels of farm vehicle-related emissions that fail to be offset by reduced emissions occurring from international transport emissions. This paper does not propose to cover a comprehensive supply chain carbon footprint for milk production or attempt to determine which method of production has the largest climatic impact. However, it does demonstrate that Sweden's legal requirements for organic producers to produce more feed on-farm to reduce transport emissions have brought emissions back within Sweden's greenhouse gas inventory and raises questions around the effectiveness of policies to reduce vehicle-related emissions. Further research is needed into the effectiveness of climate change mitigation on food production policies, in particular looking at various trade-offs that affects the entire food supply chain.

  15. Origin of natural gas; Tennen gas no kigen

    Energy Technology Data Exchange (ETDEWEB)

    Katayama, Y. [The Institute of Applied Energy, Tokyo (Japan)

    1996-03-20

    Natural gas, which is a general term of flammable hydrocarbon gases such as methane, is classified by origin into the following categories : (1) oil field gas (oil gas), (2) aquifers (bacteria-fermented methane), (3) coal gas (coal field gas), and (4) abiogenetic gas. The natural gas which has (1-4) origins and is now used as resource in a large quantity is (1) oil field gas. This gas is a hydrocarbon gas recovered in the production process of petroleum and contains components such as ethane, propane and butane. To the contrary, (2) aquifers and (3) coal gas have methane as main component. As (4) abiogenetic methane, there are gas formed in inorganic reaction in activities of submarine volcanos and deep gas (earth origin gas). Oil field gas has kerogen origin. Aquifers were formed by fermentation of organic matters. Coal gas was formed by coalification of vitrinite. As abiogenetic methane, there are inorganic reaction formation gas and deep gas, the latter of which exists little as resource. 7 refs., 11 figs., 1 tab.

  16. Surface acoustic wave sensors/gas chromatography; and Low quality natural gas sulfur removal and recovery CNG Claus sulfur recovery process

    Energy Technology Data Exchange (ETDEWEB)

    Klint, B.W.; Dale, P.R.; Stephenson, C.

    1997-12-01

    This topical report consists of the two titled projects. Surface Acoustic Wave/Gas Chromatography (SAW/GC) provides a cost-effective system for collecting real-time field screening data for characterization of vapor streams contaminated with volatile organic compounds (VOCs). The Model 4100 can be used in a field screening mode to produce chromatograms in 10 seconds. This capability will allow a project manager to make immediate decisions and to avoid the long delays and high costs associated with analysis by off-site analytical laboratories. The Model 4100 is currently under evaluation by the California Environmental Protection Agency Technology Certification Program. Initial certification focuses upon the following organics: cis-dichloroethylene, chloroform, carbon tetrachloride, trichlorethylene, tetrachloroethylene, tetrachloroethane, benzene, ethylbenzene, toluene, and o-xylene. In the second study the CNG Claus process is being evaluated for conversion and recovery of elemental sulfur from hydrogen sulfide, especially found in low quality natural gas. This report describes the design, construction and operation of a pilot scale plant built to demonstrate the technical feasibility of the integrated CNG Claus process.

  17. Process integration and optimization of a solid oxide fuel cell – Gas turbine hybrid cycle fueled with hydrothermally gasified waste biomass

    International Nuclear Information System (INIS)

    Facchinetti, Emanuele; Gassner, Martin; D’Amelio, Matilde; Marechal, François; Favrat, Daniel

    2012-01-01

    Due to its suitability for using wet biomass, hydrothermal gasification is a promising process for the valorization of otherwise unused waste biomass to synthesis gas and biofuels. Solid oxide fuel cell (SOFC) based hybrid cycles are considered as the best candidate for a more efficient and clean conversion of (bio) fuels. A significant potential for the integration of the two technologies is expected since hydrothermal gasification requires heat at 673–773 K, whereas SOFC is characterized by heat excess at high temperature due to the limited electrochemical fuel conversion. This work presents a systematic process integration and optimization of a SOFC-gas turbine (GT) hybrid cycle fueled with hydrothermally gasified waste biomass. Several design options are systematically developed and compared through a thermodynamic optimization approach based on First Law and exergy analysis. The work demonstrates the considerable potential of the system that allows for converting wet waste biomass into electricity at a First Law efficiency of up to 63%, while simultaneously enabling the separation of biogenic carbon dioxide for further use or sequestration. -- Highlights: ► Hydrothermal gasification is a promising process for the valorization of waste wet biomass. ► Solid Oxide Fuel Cell – Gas Turbine hybrid cycle emerges as the best candidates for conversion of biofuels. ► A systematic process integration and optimization of a SOFC-GT hybrid cycle fuelled with hydrothermally gasified biomass is presented. ► The system may convert wet waste biomass to electricity at a First Law efficiency of 63% while separating the biogenic carbon dioxide. ► The process integration enables to improve the First Law efficiency of around 4% with respect to a non-integrated system.

  18. On the ability of the Viking gas chromatograph-mass spectrometer to detect organic matter.

    Science.gov (United States)

    Biemann, Klaus

    2007-06-19

    A recent paper by Navarro-Gonzalez et al. [Navarro-Gonzalez R, Navarro KF, de la Rosa J, Iniguez E, Molina P, Miranda LD, Morales P, Cienfuegos E, Coll P, Raulin F, et al. (2006) Proc Natl Acad Sci USA 103:16089-16094] claims to show that the Viking GCMS (gas chromatograph-mass spectrometer) experiment, which carried out a search for organic matter at the surface of Mars in 1976, "may have been blind to low levels of organics." To rebut this assertion, the Viking experiment, test data, and results on Mars are reviewed, and the fallacies in the design, execution, and interpretation of the new experiments presented by Navarro-Gonzalez et al. are critically examined.

  19. Integrated gasification combined cycle and steam injection gas turbine powered by biomass joint-venture evaluation

    International Nuclear Information System (INIS)

    Sterzinger, G.J.

    1994-05-01

    This report analyzes the economic and environmental potential of biomass integrated gasifier/gas turbine technology including its market applications. The mature technology promises to produce electricity at $55--60/MWh and to be competitive for market applications conservatively estimated at 2000 MW. The report reviews the competitiveness of the technology of a stand-alone, mature basis and finds it to be substantial and recognized by DOE, EPRI, and the World Bank Global Environmental Facility

  20. Gas development plan - Lithuania

    International Nuclear Information System (INIS)

    1993-10-01

    A detailed description of the plan for the development of gas utilization in Lithuania is presented. The plan is subdivided under the headings of gas supply, gas demand, gas transmission and distribution, economy and the organization of the gas sector in the country. The first phase of the project has been undertaken by a Danish firm in cooperation with the Lithuanian firm Lietuvos Dujos. The first aim was to clarify the problems that will arise in connection with this joint venture on developing the use of gas in Lithuania, focusing on existing gas supply and market conditions, the current flow control and metering and economic constraints. The organization of the gas sector in the country as it stands today is described and possible models for its future organization are discussed in addition to a strategy of implementation. Possible development trends are outlined and maximum/minimum demand scenarios are suggested. Subjects and areas related to the gas sector in Lithuania are identified for further investigation in the next phase. It is stated that Lithuania is at present undergoing a fast transformation towards a market economy and that the transfer of foreign currency has been liberalized. Only the pipeline from Minsk to Vilnius is open at present and provides the total supply of natural gas to Lithuania and Kalingrad, controlled by the Russian gas company, Lentransgas, on the basis of a gas purchase agreement regulated on a yearly basis. Other possible supply sources are the Danish part of the North Sea and the Norwegian offshore fields. (AB)

  1. Gas-sensing properties of SnO2-TiO2-based sensor for volatile organic compound gas and its sensing mechanism

    International Nuclear Information System (INIS)

    Zeng Wen; Liu Tianmo

    2010-01-01

    We report the microstructure and gas-sensing properties of the SnO 2 -TiO 2 composite oxide dope with Ag ion prepared by the sol-gel method. Of all various volatile organic compounds (VOCs) such as ethanol, methanol, acetone and formaldehyde were examined, the sensor exhibits remarkable selectivity to each VOCs at different operating temperature. Further investigations based on quantum chemistry calculation show that difference orbital energy of VOCs molecule may be a qualitative factor to affect the selectivity of the sensor.

  2. GAS TURBINE ENGINES CONSUMING BIOGAS

    Directory of Open Access Journals (Sweden)

    Е. Ясиніцький

    2011-04-01

    Full Text Available A problem of implementation of biofuel for power plants of big capacity was considered in thisarticle. Up to date in the world practice a wide implementation of biogas plants of low and medialcapacity are integrated. It is explained by the big amount of enterprises in which relatively smallvolumes of organic sediment excrete in the process of its activity. An emphasis of article is on thatenterprises, which have big volumes of sediments for utilizing of which module system of medialcapacity biogas plants are non-effective. The possibility of using biogas and biomethane as a fuelfor gas turbine engine is described. The basic problems of this technology and ways of its solutionsare indicated. Approximate profitability of biogas due to example of compressor station locatednearby poultry factory was determined also. Such factors as process characteristics of engine withcapacity of 5 MW, approximate commercial price for natural gas and equipment costs due toofficial sources of “Zorg Ukraine” company was taken into consideration. The necessity forproviding researches on influence of biogas on the process characteristics of gas turbine engine andits reliability, constructing modern domestic purification system for biogas was shown.

  3. Development of Solid Ceramic Dosimeters for the Time-Integrative Passive Sampling of Volatile Organic Compounds in Waters.

    Science.gov (United States)

    Bonifacio, Riza Gabriela; Nam, Go-Un; Eom, In-Yong; Hong, Yong-Seok

    2017-11-07

    Time-integrative passive sampling of volatile organic compounds (VOCs) in water can now be accomplished using a solid ceramic dosimeter. A nonporous ceramic, which excludes the permeation of water, allowing only gas-phase diffusion of VOCs into the resin inside the dosimeter, effectively captured the VOCs. The mass accumulation of 11 VOCs linearly increased with time over a wide range of aqueous-phase concentrations (16.9 to 1100 μg L -1 ), and the linearity was dependent upon the Henry's constant (H). The average diffusivity of the VOCs in the solid ceramic was 1.46 × 10 -10 m 2 s -1 at 25 °C, which was 4 orders of magnitude lower than that in air (8.09 × 10 -6 m 2 s -1 ). This value was 60% greater than that in the water-permeable porous ceramic (0.92 × 10 -10 m 2 s -1 ), suggesting that its mass accumulation could be more effective than that of porous ceramic dosimeters. The mass accumulation of the VOCs in the solid ceramic dosimeter increased in the presence of salt (≥0.1 M) and with increasing temperature (4 to 40 °C) but varied only slightly with dissolved organic matter concentration. The solid ceramic dosimeter was suitable for the field testing and measurement of time-weighted average concentrations of VOC-contaminated waters.

  4. The high integrity design and manufacture of the Heysham II/Torness gas baffle

    International Nuclear Information System (INIS)

    Armor, J.; Day, B.V.; White, C.M.

    1985-01-01

    The AGR design used on the Heysham II and Torness power stations requires a gas baffle which is essentially a steel pressure vessel for which one can demonstrate a high degree of integrity. The design, analytical, manufacturing, erection and testing processes which were undertaken to achieve the standard required of the completed assembly are discussed. To this end the vessels were manufactured in purpose-made shops and transported to site, leaving a minimum amount of work to be undertaken at site. Subsequent evaluation has shown a very low probability of failure compared with conventional steel pressure vessels. (author)

  5. Integrated sulphur management : gas, oil sands, reclamation and the challenges of fluctuating demand

    International Nuclear Information System (INIS)

    Pineau, R.

    2009-01-01

    International Commodities Export Corporation is a privately held company that provides fully integrated service offerings to add maximum value in designing, building, owning, and operating sulphur assets. The company also offers in-house, engineering, procurement and project management, as well as supply management, transportation and distribution services. It also has expertise in marine transportation. This presentation discussed integrated sulphur management, with particular focus on gas, oil sands, reclamation and the challenges of fluctuating demand. The presentation provided an overview of the sulphur market and oil sands sulphur. Key considerations for oil sands producers were also presented. The challenges of fluctuating demand include price and volume considerations; logistics; geography and distance to market; export/offshore versus domestic/United States; seasonal considerations; and an inelastic sulphur market. The presentation concluded with a status update of ICEC's initiative and the advantages of Prince Rupert, an economically viable export infrastructure to producers without onsite forming facilities. figs

  6. Integrated systems of weed management in organic transplated vidalia sweet onion production

    Science.gov (United States)

    Field experiments were conducted from 2008 through 2010 near Lyons, GA to develop integrated weed management systems for organic Vidalia® sweet onion production. Treatments were a factorial arrangement of summer solarization, cultivation with a tine weeder, and a clove oil herbicide. Plots were so...

  7. NF ISO 14064-1 Greenhouse gases. Part 1: specifications and guidance at the organization level for quantification and reporting of greenhouse gas emissions and removals

    International Nuclear Information System (INIS)

    2005-01-01

    This document describes methodology for quantification, monitoring of greenhouse gas as well as for drafting of inventory report for organisms. Thus it suggests a method for inventory declarations for organism greenhouse gas and provides support for the monitoring and the management of their emission. It provides the terms and definitions, the principles, the greenhouse gases inventory design, development and components, the greenhouse inventory quality management, the reporting of greenhouse gases and the organization role in verification activities. (A.L.B.)

  8. Conceptual design of sustainable integrated microalgae biorefineries: Parametric analysis of energy use, greenhouse gas emissions and techno-economics

    NARCIS (Netherlands)

    Posada, John; Brentner, Laura; Ramirez, Andrea; Patel, Martin

    2016-01-01

    This study covers four main aspects of the conceptual design of sustainable integrated microalgae-based biorefineries using flue gas from CO2-intensive industries (i.e. 100% CO2): i) screening of technologies (4 options for cultivation, 3 for culture dewatering, 3 for cell disruption, 4 for lipids

  9. Conceptual design of sustainable integrated microalgae biorefineries : Parametric analysis of energy use, greenhouse gas emissions and techno-economics

    NARCIS (Netherlands)

    Posada Duque, J.A.; Brentner, L.B.; Ramirez, A; Patel, MK

    2016-01-01

    This study covers four main aspects of the conceptual design of sustainable integrated microalgae-based biorefineries using flue gas from CO2-intensive industries (i.e. 100% CO2): i) screening of technologies (4 options for cultivation, 3 for culture dewatering, 3 for cell disruption, 4 for lipids

  10. Conceptual design of sustainable integrated microalgae biorefineries: Parametric analysis of energy use, greenhouse gas emissions and techno-economics

    NARCIS (Netherlands)

    Posada, John A.; Brentner, Laura B.; Ramirez, Andrea; Patel, Martin K.

    This study covers four main aspects of the conceptual design of sustainable integrated microalgae-based biorefineries using flue gas from CO2-intensive industries (i.e. 100% CO2): i) screening of technologies (4 options for cultivation, 3 for culture dewatering, 3 for cell disruption, 4 for lipids

  11. Evaluation of supercritical fluid extraction/gas chromatography/matrix isolation-infrared spectrometry for analysis of organic compounds

    International Nuclear Information System (INIS)

    Bopari, A.S.; Bierma, D.R.; Applegate, D.V.

    1991-01-01

    Analysis of soil samples for organic compounds typically first requires Soxhlet extraction or sonication. These processes are time consuming and generate large amounts of waste solvent. Supercritical fluid extraction (SFE), which uses a supercritical fluid such as carbon dioxide, has recently been shown to extract organic compounds from soil samples in good yields. Moreover, SFE does not generate waste solvent and can be performed rapidly. Gas Chromatography/Matrix Isolation-Infrared Spectrometry (GC/MI-IR) has been used in our laboratories for determining organic compounds present in extracts from various matrices. The authors have interfaced an SFE extraction apparatus to GC/MI-IR instruments. In this paper the utility of SPE/GC/MI-IR instrumentation is discussed

  12. Nonlinear-Based MEMS Sensors and Active Switches for Gas Detection

    Directory of Open Access Journals (Sweden)

    Adam Bouchaala

    2016-05-01

    Full Text Available The objective of this paper is to demonstrate the integration of a MOF thin film on electrostatically actuated microstructures to realize a switch triggered by gas and a sensing algorithm based on amplitude tracking. The devices are based on the nonlinear response of micromachined clamped-clamped beams. The microbeams are coated with a metal-organic framework (MOF, namely HKUST-1, to achieve high sensitivity. The softening and hardening nonlinear behaviors of the microbeams are exploited to demonstrate the ideas. For gas sensing, an amplitude-based tracking algorithm is developed to quantify the captured quantity of gas. Then, a MEMS switch triggered by gas using the nonlinear response of the microbeam is demonstrated. Noise analysis is conducted, which shows that the switch has high stability against thermal noise. The proposed switch is promising for delivering binary sensing information, and also can be used directly to activate useful functionalities, such as alarming.

  13. Nonlinear-Based MEMS Sensors and Active Switches for Gas Detection

    Science.gov (United States)

    Bouchaala, Adam; Jaber, Nizar; Yassine, Omar; Shekhah, Osama; Chernikova, Valeriya; Eddaoudi, Mohamed; Younis, Mohammad I.

    2016-01-01

    The objective of this paper is to demonstrate the integration of a MOF thin film on electrostatically actuated microstructures to realize a switch triggered by gas and a sensing algorithm based on amplitude tracking. The devices are based on the nonlinear response of micromachined clamped-clamped beams. The microbeams are coated with a metal-organic framework (MOF), namely HKUST-1, to achieve high sensitivity. The softening and hardening nonlinear behaviors of the microbeams are exploited to demonstrate the ideas. For gas sensing, an amplitude-based tracking algorithm is developed to quantify the captured quantity of gas. Then, a MEMS switch triggered by gas using the nonlinear response of the microbeam is demonstrated. Noise analysis is conducted, which shows that the switch has high stability against thermal noise. The proposed switch is promising for delivering binary sensing information, and also can be used directly to activate useful functionalities, such as alarming. PMID:27231914

  14. A study of a high temperature nuclear power plant incorporating a non-integrated indirect cycle gas turbine

    International Nuclear Information System (INIS)

    Sarlos, G.; Helbling, W.; Zollinger, E.; Gregory, N.; Luchsinger, H.

    1982-04-01

    In connection with the HHT-project, the Swiss Federal Institute for Reactor Research has performed a study of a 1640-MWth HTR-plant incorporating a non-integrated indirect cycle gas turbine with two-stage intercooling, as a possibility of simplifying and reducing the cost of the HHT-demonstration plant. In this paper, the plant design is described and compared with the HHT-demonstration plant (a CCGT integrated plant with single stage intercooling). Also included is an evaluation of the various advantages and disadvantages of this design together with the presentation of some of the sensitivity results. (Auth.)

  15. Integration between environmental management and strategic planning in the oil and gas sector

    International Nuclear Information System (INIS)

    Magrini, Alessandra; Lins, Luiz dos Santos

    2007-01-01

    For activities that have a high possibility of causing environmental accidents, like in the oil and gas sector, it is reasonable to expect the environmental management to be an important variable within the company's strategic planning. However, this is not always true. In some cases, a change in the companies' attitude, abandoning a reactive position and assuming a proactive one, only happens upon the occurrence of serious environmental accidents with strong repercussion in the media. For the company that was the object of study, these accidents gave rise to deep changes in its environmental management, culminating in investments of approximately US$ 2.6 billion in environment, health and security, from 2000 to 2004. This was the highest amount to date invested on these areas by an oil company. This case study seeks to discuss the integration between environmental management and strategic planning in the oil and gas sector over a period of 10 years (from 1995 to 2004) in order to make a contextual analysis of the period before and after the environmental accidents possible

  16. Natural gas monthly

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-01-01

    The Natural Gas Monthly highlights activities, events, and analyses of interest to public and private sector organizations associated with the natural gas industry. Volume and price data are presented each month for natural gas production, distribution, consumption, and interstate pipeline activities. Producer-related activities and underground storage data are also reported. From time to time, the Natural Gas Monthly features articles designed to assist readers in using and interpreting natural gas information.

  17. Interdisciplinary Investigation of CO2 Sequestration in Depleted Shale Gas Formations

    Energy Technology Data Exchange (ETDEWEB)

    Zoback, Mark D. [Stanford Univ., CA (United States); Kovscek, Anthony R. [Stanford Univ., CA (United States); Wilcox, Jennifer [Stanford Univ., CA (United States)

    2013-09-30

    This project investigates the feasibility of geologic sequestration of CO2 in depleted shale gas reservoirs from an interdisciplinary viewpoint. It is anticipated that over the next two decades, tens of thousands of wells will be drilled in the 23 states in which organic-rich shale gas deposits are found. This research investigates the feasibility of using these formations for sequestration. If feasible, the number of sites where CO2 can be sequestered increases dramatically. The research embraces a broad array of length scales ranging from the ~10 nanometer scale of the pores in the shale formations to reservoir scale through a series of integrated laboratory and theoretical studies.

  18. Recent Developments in 2D Nanomaterials for Chemiresistive-Type Gas Sensors

    Science.gov (United States)

    Choi, Seon-Jin; Kim, Il-Doo

    2018-03-01

    Two-dimensional (2D) nanostructures are gaining tremendous interests due to the fascinating physical, chemical, electrical, and optical properties. Recent advances in 2D nanomaterials synthesis have contributed to optimization of various parameters such as physical dimension and chemical structure for specific applications. In particular, development of high performance gas sensors is gaining vast importance for real-time and on-site environmental monitoring by detection of hazardous chemical species. In this review, we comprehensively report recent achievements of 2D nanostructured materials for chemiresistive-type gas sensors. Firstly, the basic sensing mechanism is described based on charge transfer behavior between gas species and 2D nanomaterials. Secondly, diverse synthesis strategies and characteristic gas sensing properties of 2D nanostructures such as graphene, metal oxides, transition metal dichalcogenides (TMDs), metal organic frameworks (MOFs), phosphorus, and MXenes are presented. In addition, recent trends in synthesis of 2D heterostructures by integrating two different types of 2D nanomaterials and their gas sensing properties are discussed. Finally, this review provides perspectives and future research directions for gas sensor technology using various 2D nanomaterials.

  19. Recent Developments in 2D Nanomaterials for Chemiresistive-Type Gas Sensors

    Science.gov (United States)

    Choi, Seon-Jin; Kim, Il-Doo

    2018-05-01

    Two-dimensional (2D) nanostructures are gaining tremendous interests due to the fascinating physical, chemical, electrical, and optical properties. Recent advances in 2D nanomaterials synthesis have contributed to optimization of various parameters such as physical dimension and chemical structure for specific applications. In particular, development of high performance gas sensors is gaining vast importance for real-time and on-site environmental monitoring by detection of hazardous chemical species. In this review, we comprehensively report recent achievements of 2D nanostructured materials for chemiresistive-type gas sensors. Firstly, the basic sensing mechanism is described based on charge transfer behavior between gas species and 2D nanomaterials. Secondly, diverse synthesis strategies and characteristic gas sensing properties of 2D nanostructures such as graphene, metal oxides, transition metal dichalcogenides (TMDs), metal organic frameworks (MOFs), phosphorus, and MXenes are presented. In addition, recent trends in synthesis of 2D heterostructures by integrating two different types of 2D nanomaterials and their gas sensing properties are discussed. Finally, this review provides perspectives and future research directions for gas sensor technology using various 2D nanomaterials.

  20. Energy flow and greenhouse gas emissions in organic and conventional sweet cherry orchards located in or close to Natura 2000 sites

    International Nuclear Information System (INIS)

    Litskas, Vassilios D.; Mamolos, Andreas P.; Kalburtji, Kiriaki L.; Tsatsarelis, Constantinos A.; Kiose-Kampasakali, Eleni

    2011-01-01

    An energy analysis in orchards is useful to deciding best management strategies. The objective of this study was to evaluate, by selecting organic and conventional sweet cherry orchards located in/or close to Natura 2000 sites (a) the energy flow between the two farming systems and (b) the effect of farming system to gas emissions (CO 2 , CH 4 and N 2 O). Twenty farms [(2-conventional and 2-organic) x 5-locations] were selected during 2003-2004. Means averaged over all locations for insecticides and fungicides application, fuel, insecticides, fungicides, non-renewable energy inputs, energy shoot outputs, energy fruit outputs, energy shoot + fruit outputs, fruit production, shoot efficiency, fruit efficiency, shoot + fruit efficiency, non-renewable energy efficiency, gas emissions were higher in conventional than in organic orchards, while fertilizer application, harvesting, fertilizers, labor, total energy inputs, renewable energy inputs, intensity and non-renewable energy consumption were higher in organic orchards. Means averaged over two farming systems for fertilizer, insecticide and fungicide application were higher in GRL2 and GRL5. The means averaged over two systems for transportation had the highest value in GRL4 and the lowest in GRL5. Finally, means averaged over two farming systems for labor had the highest value in GRL2. Non-renewable energy inputs as percent of total inputs were 82.63 and 52.42% in conventional and organic sweet cherry orchards respectively. The results show that organic farming systems could reduce non-renewable energy inputs and gas emissions in an efficient way in areas related to Natura 2000 sites.

  1. Methods for calculation of engineering parameters for gas separation. [vapor pressure and solubility of gases in organic liquids

    Science.gov (United States)

    Lawson, D. D.

    1979-01-01

    A group additivity method is generated which allows estimation, from the structural formulas alone, of the energy of vaporization and the molar volume at 25 C of many nonpolar organic liquids. Using these two parameters and appropriate thermodynamic relations, the vapor pressure of the liquid phase and the solubility of various gases in nonpolar organic liquids are predicted. It is also possible to use the data to evaluate organic and some inorganic liquids for use in gas separation stages or liquids as heat exchange fluids in prospective thermochemical cycles for hydrogen production.

  2. Recovery of flue gas energy in heat-integrated gasification combined cycle (IGCC) power plants using the contact economizer system

    CSIR Research Space (South Africa)

    Madzivhandila, VA

    2011-03-01

    Full Text Available (flue gas) stream of a heat-integrated gasification combined cycle (IGCC) design of the Elcogas plant adopted from previous studies. The underlying support for this idea was the direct relationship between efficiency of the IGCC and the boiler feedwater...

  3. Integration, de-integration and liberal controlled finance

    International Nuclear Information System (INIS)

    Deyirmendjian, J.

    2008-01-01

    With the forthcoming adoption of the 3. directive of the European Commission project, the European Union will make a new step towards integration. The stake for gas or electric utilities is of prime importance: each will have to de-integrate and positioned itself as an infrastructure company or as a production and commercialization company. In other words, they will have to chose between 'regulation and recurrent incomes' or 'fortunes and risks of production and trade'. Such changes, added to the globalization of gas trades linked with the development of LNG, require more investments than in the past. However, these over-investments combined to technical progresses allow to expect that this mutation will not significantly weaken the security of gas supplies in the European Union. The end-user, on the other hand, will certainly not make any profit of this integration considering the enhanced volatility of markets more and more dominated by the speculative strategies of financial operators. (J.S.)

  4. Integrated biomass gasification combined cycle distributed generation plant with reciprocating gas engine and ORC

    International Nuclear Information System (INIS)

    Kalina, Jacek

    2011-01-01

    The paper theoretically investigates the performance of a distributed generation plant made up of gasifier, Internal Combustion Engine (ICE) and Organic Rankine Cycle (ORC) machine as a bottoming unit. The system can be used for maximization of electricity production from biomass in the case where there is no heat demand for cogeneration plant. To analyze the performance of the gasifier a model based on the thermodynamic equilibrium approach is used. Performance of the gas engine is estimated on the basis of the analysis of its theoretical thermodynamic cycle. Three different setups of the plant are being examined. In the first one the ORC module is driven only by the heat recovered from engine exhaust gas and cooling water. Waste heat from a gasifier is used for gasification air preheating. In the second configuration a thermal oil circuit is applied. The oil transfers heat from engine and raw gas cooler into the ORC. In the third configuration it is proposed to apply a double cascade arrangement of the ORC unit with a two-stage low temperature evaporation of working fluid. This novel approach allows utilization of the total waste heat from the low temperature engine cooling circuit. Two gas engines of different characteristics are taken into account. The results obtained were compared in terms of electric energy generation efficiency of the system. The lowest obtained value of the efficiency was 23.6% while the highest one was 28.3%. These are very favorable values in comparison with other existing small and medium scale biomass-fuelled power generation plants. - Highlights: →The study presents performance analysis of a biomass-fuelled local power plant. →Downdraft wood gasifier, gas engine and ORC module are modelled theoretically. →Method for estimation of the producer gas fired engine performance is proposed. →Two gas engines of different characteristics are taken into account. →Different arrangements of the bottoming ORC cycle ere examined.

  5. Integrated resource planning for local gas distribution companies: A critical review of regulatory policy issues

    International Nuclear Information System (INIS)

    Harunuzzaman, M.; Islam, M.

    1994-08-01

    According to the report, public utility commissions (PUCs) are increasingly adopting, or considering the adoption of integrated resource planning (IRP) for local gas distribution companies (LDCs). The Energy Policy Act of 1992 (EPAct) requires PUCs to consider IRP for gas LDCs. This study has two major objectives: (1) to help PUCs develop appropriate regulatory approaches with regard to IRP for gas LDCs; and (2) to help PUCs respond to the EPAct directive. The study finds that it is appropriate for PUCs to pursue energy efficiency within the traditional regulatory framework of minimizing private costs of energy production and delivery; and PUCs should play a limited role in addressing environmental externalities. The study also finds that in promoting energy efficiency, PUCs should pursue policies that are incentive-based, procompetitive, and sensitive to rate impacts. The study evaluates a number of traditional and nontraditional ratemaking mechanisms on the basis of cost minimization, energy efficiency, competitiveness, and other criteria. The mechanisms evaluated include direct recovery of DSM expenses, lost revenue adjustments for DSM options, revenue decoupling mechanisms, sharing of DSM cost savings, performance-based rate of return for DSM, provision of DSM as a separate service, deregulation of DSM service, price caps, and deregulation of the noncore gas market. The study concludes with general recommendations for regulatory approaches and ratemaking mechanisms that PUCs may wish to consider in advancing IRP objectives

  6. New set-up for high-quality soft-X-ray absorption spectroscopy of large organic molecules in the gas phase

    Energy Technology Data Exchange (ETDEWEB)

    Holch, Florian; Huebner, Dominique [Universitaet Wuerzburg, Experimentelle Physik VII, Am and Roentgen Reasearch Center for Complex Materials (RCCM) Hubland, 97074 Wuerzburg (Germany); Fink, Rainer [Universitaet Erlangen-Nuernberg, ICMM and CENEM, Egerlandstrasse 3, 91058 Erlangen (Germany); Schoell, Achim, E-mail: achim.schoell@physik.uni-wuerzburg.de [Universitaet Wuerzburg, Experimentelle Physik VII, Am and Roentgen Reasearch Center for Complex Materials (RCCM) Hubland, 97074 Wuerzburg (Germany); Umbach, Eberhard [Karlsruhe Institute of Technology, 76021 Karlsruhe (Germany)

    2011-11-15

    Highlights: {yields} We present a new set-up for x-ray absorption (NEXAFS) on large molecules in the gas-phase. {yields} The cell has a confined volume and can be heated. {yields} The spectra can be acquired fast, are of very high quality with respect tosignal-to-noise ratio and energy resolution. {yields} This allowsthe analysis of spectroscopic details (e.g. solid state effects by comparing gas- and condensed phase data). - Abstract: We present a new experimental set-up for the investigation of large (>128 amu) organic molecules in the gas-phase by means of near-edge X-ray absorption fine structure spectroscopy in the soft X-ray range. Our approach uses a gas cell, which is sealed off against the surrounding vacuum and which can be heated above the sublimation temperature of the respective molecular compound. Using a confined volume rather than a molecular beam yields short acquisition times and intense signals due to the high molecular density, which can be tuned by the container temperature. In turn, the resulting spectra are of very high quality with respect to signal-to-noise ratio and energy resolution, which are the essential aspects for the analysis of fine spectroscopic details. Using the examples of ANQ, NTCDA, and PTCDA, specific challenges of gas phase measurements on large organic molecules with high sublimation temperatures are addressed in detail with respect to the presented set-up and possible ways to tackle them are outlined.

  7. Application of gas chromatography-surface ionization organic mass spectrometry to forensic toxicology.

    Science.gov (United States)

    Ishii, Akira; Watanabe-Suzuki, Kanako; Seno, Hiroshi; Suzuki, Osamu; Katsumata, Yoshinao

    2002-08-25

    Surface ionization (SI), which consists in the formation of positive and negative ions along the course of thermal desorption of particles from a solid surface, was first applied as a detector for gas chromatography (GC), GC-surface ionization detection (SID); we developed many new sensitive methods for the determination of abused and other drugs by GC-SID. Recently, Fujii has devised a combination of SI and a quadrupole mass spectrometer and named this system a surface ionization organic mass spectrometer (SIOMS), which is highly selective and sensitive for organic compounds containing tertiary amino groups. We have tried to apply this mass spectrometer to forensic toxicological study; so far we have succeeded in determining important drugs-of-abuse and toxic compounds, such as phencyclidine (PCP), pethidine, pentazocine, MPTP and its derivatives from human body fluids with high sensitivity and selectivity. In this review, we describe our recent studies on the application of GC-SIOMS to forensic toxicology. Copyright 2002 Elsevier Science B.V.

  8. Towards Breath Gas Analysis Based on Millimeter-Wave Molecular Spectroscopy

    Science.gov (United States)

    Rothbart, Nick; Hübers, Heinz-Wilhelm; Schmalz, Klaus; Borngräber, Johannes; Kissinger, Dietmar

    2018-03-01

    Breath gas analysis is a promising non-invasive tool for medical diagnosis as there are thousands of Volatile Organic Compounds (VOCs) in human breath that can be used as health monitoring markers. Millimeter-wave/terahertz molecular spectroscopy is highly suitable for breath gas analysis due to unique fingerprint spectra of many VOCs in that frequency range. We present our recent work on sensor systems for gas spectroscopy based on integrated transmitters (TX) and receivers (RX) fabricated in IHP's 0.13 μm SiGe BiCMOS technology. For a single-band system, spectroscopic measurements and beam profiles are presented. The frequency is tuned by direct voltage-frequency tuning and by a fractional-n PLL, respectively. The spectroscopic system includes a folded gas absorption cell with gas pre-concentration abilities demonstrating the detection of a 50 ppm mixture of ethanol in ambient air corresponding to a minimum detectable concentration of 260 ppb. Finally, the design of a 3-band system covering frequencies from 225 to 273 GHz is introduced.

  9. Integration of gas phase condensed nanoparticles in YBa_2Cu_3O_7_-_δ multilayers

    International Nuclear Information System (INIS)

    Sparing, Maria

    2012-01-01

    The control and targeted variation of nanoparticles properties is a central challenge in research on particle induced defects in YBa_2Cu_3O_7_-_δ. Using a combined Sputter-PLD system with inert gas condensation particle size and density integrated into the YBCO multilayers were varied independently. The cooling process influences the electrical properties of the multilayers. The effect of HfO2 and FePt nanoparticles on the structural and electrical properties was studied.

  10. Monoterpene oxidation in an oxidative flow reactor: SOA yields and the relationship between bulk gas-phase properties and organic aerosol growth

    Science.gov (United States)

    Friedman, B.; Link, M.; Farmer, D.

    2016-12-01

    We use an oxidative flow reactor (OFR) to determine the secondary organic aerosol (SOA) yields of five monoterpenes (alpha-pinene, beta-pinene, limonene, sabinene, and terpinolene) at a range of OH exposures. These OH exposures correspond to aging timescales of a few hours to seven days. We further determine how SOA yields of beta-pinene and alpha-pinene vary as a function of seed particle type (organic vs. inorganic) and seed particle mass concentration. We hypothesize that the monoterpene structure largely accounts for the observed variance in SOA yields for the different monoterpenes. We also use high-resolution time-of-flight chemical ionization mass spectrometry to calculate the bulk gas-phase properties (O:C and H:C) of the monoterpene oxidation systems as a function of oxidant concentrations. Bulk gas-phase properties can be compared to the SOA yields to assess the capability of the precursor gas-phase species to inform the SOA yields of each monoterpene oxidation system. We find that the extent of oxygenated precursor gas-phase species corresponds to SOA yield.

  11. Orientation and Integration of New Employees in an Organization Hotel

    OpenAIRE

    Daniel Dăneci-Pătrău

    2016-01-01

    The tourism industry is an industry of "labor" because the employees who work in direct contactwith customers depends on the success of the organization. Hotel staff is the image of anorganization, thus requiring a certain prestige from its standard defining the policy andorganizational culture of the company. Hence the role of integration employees in the hotel as afactor determining the quality work of the new employee, its performance and hence organizationalperformance. The aim of this...

  12. Misperceived climate friendliness of organic food and consumer willingness to pay for actual greenhouse gas emission reduction

    DEFF Research Database (Denmark)

    Olsen, Søren Bøye; Christensen, Tove; Denver, Sigrid

    2015-01-01

    Organic farming practices are generally associated with lower environmental impacts than conventional farming but this does not generally hold true in a climate context. A recent meta-analysis shows that organic milk production often has higher greenhouse gas (GHG) emissions per kilo milk produce...... in consumers’ preferences. Hence, if reduced GHG emissions are to be pursued by increased consumption of climate friendlier food then marketing efforts and information strategies need to be targeted specifically to different segments of the population....

  13. Natural gas developments in Latin America

    International Nuclear Information System (INIS)

    Faith, P.L.

    1996-01-01

    Natural gas opportunities in Latin America are discussed with reference to the Bolivia to Brazil Gas Pipeline Project. This fully integrated natural gas project extends from reserves development to market consumption and involves cooperation between countries and between the public and private sector. The project's success will depend, it is argued on the thorough integration and cooperation of all stages from reserve exploration, through pipeline construction, and distribution to power generation. (UK)

  14. Towards the future organization of the French gas industry

    International Nuclear Information System (INIS)

    Batail, J.

    1999-01-01

    This article recapitulates the content of the directive on the 'internal gas market', recalls the spirit of co-operation established with a view to developing the future gas system in France, and puts forward some to the questions raised within the framework of this co-operation. These include: public utilities, third party access to networks, the definition of future 'eligible consumers', the regulation necessary for the correct operation of the gas market on a competitive basis, and the development of French gas operators throughout the world. (author)

  15. Hydrogen production with fully integrated fuel cycle gas and vapour core reactors

    International Nuclear Information System (INIS)

    Anghaie, S.; Smith, B.

    2004-01-01

    This paper presents results of a conceptual design study involving gas and vapour core reactors (G/VCR) with a combined scheme to generate hydrogen and power. The hydrogen production schemes include high temperature electrolysis as well as two dominant thermochemical hydrogen production processes. Thermochemical hydrogen production processes considered in this study included the calcium-bromine process and the sulphur-iodine processes. G/VCR systems are externally reflected and moderated nuclear energy systems fuelled by stable uranium compounds in gaseous or vapour phase that are usually operated at temperatures above 1500 K. A gas core reactor with a condensable fuel such as uranium tetrafluoride (UF 4 ) or a mixture of UF 4 and other metallic fluorides (BeF 2 , LiF, KF, etc.) is commonly known as a vapour core reactor (VCR). The single most relevant and unique feature of gas/vapour core reactors is that the functions of fuel and coolant are combined into one. The reactor outlet temperature is not constrained by solid fuel-cladding temperature limits. The maximum fuel/working fluid temperature in G/VCR is only constrained by the reactor vessel material limits, which is far less restrictive than the fuel clad. Therefore, G/VCRs can potentially provide the highest reactor and cycle temperature among all existing or proposed fission reactor designs. Gas and vapour fuel reactors feature very low fuel inventory and fully integrated fuel cycle that provide for exceptional sustainability and safety characteristics. With respect to fuel utilisation, there is no fuel burn-up limit for gas core reactors due to continuous recycling of the fuel. Owing to the flexibility in nuclear design characteristics of cavity reactors, a wide range of conversion ratio from completely burner to breeder is achievable. The continuous recycling of fuel in G/VCR systems allow for complete burning of actinides without removing and reprocessing of the fuel. The only waste products at the back

  16. Investigation of DNA Integration into Reproductive Organs Following Intramuscular Injection of DNA in Mice

    Directory of Open Access Journals (Sweden)

    Fatemeh Vahedi

    2012-10-01

    Full Text Available Background: DNA immunization with plasmid DNA encoding bacterial, viral, parasitic, and tumor antigens has been reported to trigger protective immunity. The use of plasmid DNA vaccinations against many diseases has produced promising results in animal and human clinical trials; however, safety concerns about the use of DNA vaccines exist, such as the possibility of integration into the host genome, and elicitation of adverse immune responses. Methods: In this study, we examined the potential integration and bio-distribution of pcDNA3.1+PA, a new vaccine candidate with GenBank accession # EF550208, encoding the PA63 gene, in reproductive organs of mice; ovaries and uterus in female, and testis in male. Animals of both sexes were injected intramuscularly with pcDNA3.1+PA. Host genome integration and tissue distribution were examined using PCR and RT-PCR two times monthly for six months. Results: RT-PCR confirmed that pcDNA3.1+PA was not integrated into the host genome and did not enter reproductive organs. Conclusions: This finding has important implications for the use of pcDNA3.1+PA plasmid as a vaccine and opens new perspectives in the DNA vaccine area.

  17. A Monolithically-Integrated μGC Chemical Sensor System

    Directory of Open Access Journals (Sweden)

    Davor Copic

    2011-06-01

    Full Text Available Gas chromatography (GC is used for organic and inorganic gas detection with a range of applications including screening for chemical warfare agents (CWA, breath analysis for diagnostics or law enforcement purposes, and air pollutants/indoor air quality monitoring of homes and commercial buildings. A field-portable, light weight, low power, rapid response, micro-gas chromatography (μGC system is essential for such applications. We describe the design, fabrication and packaging of mGC on monolithically-integrated Si dies, comprised of a preconcentrator (PC, μGC column, detector and coatings for each of these components. An important feature of our system is that the same mechanical micro resonator design is used for the PC and detector. We demonstrate system performance by detecting four different CWA simulants within 2 min. We present theoretical analyses for cost/power comparisons of monolithic versus hybrid μGC systems. We discuss thermal isolation in monolithic systems to improve overall performance. Our monolithically-integrated μGC, relative to its hybrid cousin, will afford equal or slightly lower cost, a footprint that is 1/2 to 1/3 the size and an improved resolution of 4 to 25%.

  18. An integrated platform for gas-diffusion separation and electrochemical determination of ethanol on fermentation broths

    Energy Technology Data Exchange (ETDEWEB)

    Giordano, Gabriela Furlan [Microfabrication Laboratory, Brazilian Nanotechnology National Laboratory (LNNano), Brazilian Center for Research in Energy and Materials (CNPEM), Campinas, SP 13083-970 (Brazil); Department of Analytical Chemistry, Institute of Chemistry – UNICAMP, Campinas, SP 13083-970 (Brazil); National Institute of Science and Technology of Bioanalytics, Institute of Chemistry – UNICAMP, Campinas, SP 13083-970 (Brazil); Vieira, Luis Carlos Silveira; Gobbi, Angelo Luiz [Microfabrication Laboratory, Brazilian Nanotechnology National Laboratory (LNNano), Brazilian Center for Research in Energy and Materials (CNPEM), Campinas, SP 13083-970 (Brazil); Lima, Renato Sousa [Microfabrication Laboratory, Brazilian Nanotechnology National Laboratory (LNNano), Brazilian Center for Research in Energy and Materials (CNPEM), Campinas, SP 13083-970 (Brazil); Department of Analytical Chemistry, Institute of Chemistry – UNICAMP, Campinas, SP 13083-970 (Brazil); National Institute of Science and Technology of Bioanalytics, Institute of Chemistry – UNICAMP, Campinas, SP 13083-970 (Brazil); Kubota, Lauro Tatsuo, E-mail: kubota@iqm.unicamp.br [Department of Analytical Chemistry, Institute of Chemistry – UNICAMP, Campinas, SP 13083-970 (Brazil); National Institute of Science and Technology of Bioanalytics, Institute of Chemistry – UNICAMP, Campinas, SP 13083-970 (Brazil)

    2015-05-22

    Highlights: • Integrated platform was developed to determine ethanol in fermentation broths. • The designed system integrates gas diffusion separation with voltammetric detection. • Detector relied on Ni(OH){sub 2}-modified electrode stabilized by Co{sup 2+} and Cd{sup 2+} insertion. • Separation was made by PTFE membrane separating sample from electrolyte (receptor). • Despite the sample complexity, accurate tests were achieved by direct interpolation. - Abstract: An integrated platform was developed for point-of-use determination of ethanol in sugar cane fermentation broths. Such analysis is important because ethanol reduces its fuel production efficiency by altering the alcoholic fermentation step when in excess. The custom-designed platform integrates gas diffusion separation with voltammetric detection in a single analysis module. The detector relied on a Ni(OH){sub 2}-modified electrode. It was stabilized by uniformly depositing cobalt and cadmium hydroxides as shown by XPS measurements. Such tests were in accordance with the hypothesis related to stabilization of the Ni(OH){sub 2} structure by insertion of Co{sup 2+} and Cd{sup 2+} ions in this structure. The separation step, in turn, was based on a hydrophobic PTFE membrane, which separates the sample from receptor solution (electrolyte) where the electrodes were placed. Parameters of limit of detection and analytical sensitivity were estimated to be 0.2% v/v and 2.90 μA % (v/v){sup −1}, respectively. Samples of fermentation broth were analyzed by both standard addition method and direct interpolation in saline medium based-analytical curve. In this case, the saline solution exhibited ionic strength similar to those of the samples intended to surpass the tonometry colligative effect of the samples over analyte concentration data by attributing the reduction in quantity of diffused ethanol vapor majorly to the electrolyte. The approach of analytical curve provided rapid, simple and accurate

  19. Towards the future french organization of the natural gas industry

    International Nuclear Information System (INIS)

    2001-01-01

    In the framework of the new directive on the internal gas market of 1998, the government proposed a discussion by the presentation of this white book, providing information and questions. This book proposes seven main chapters: the gas industry activity and the directive on the internal gas market; the gas actors, the key numbers and the juridical context in France; define and strengthen the natural gas public utility; useful actions for each gas facilities (transport, distribution, storage and retailers); the realization of progresses for the consumer; the operating of an efficiency control; actions to develop the gas operators in the world. The text of the 98/30/CE directive is also provided. (A.L.B.)

  20. Heat Integration of the Water-Gas Shift Reaction System for Carbon Sequestration Ready IGCC Process with Chemical Looping

    Energy Technology Data Exchange (ETDEWEB)

    Juan M. Salazara; Stephen E. Zitney; Urmila M. Diwekara

    2010-01-01

    Integrated gasification combined cycle (IGCC) technology has been considered as an important alternative for efficient power systems that can reduce fuel consumption and CO2 emissions. One of the technological schemes combines water-gas shift reaction and chemical-looping combustion as post gasification techniques in order to produce sequestration-ready CO2 and potentially reduce the size of the gas turbine. However, these schemes have not been energetically integrated and process synthesis techniques can be applied to obtain an optimal flowsheet. This work studies the heat exchange network synthesis (HENS) for the water-gas shift reaction train employing a set of alternative designs provided by Aspen energy analyzer (AEA) and combined in a process superstructure that was simulated in Aspen Plus (AP). This approach allows a rigorous evaluation of the alternative designs and their combinations avoiding all the AEA simplifications (linearized models of heat exchangers). A CAPE-OPEN compliant capability which makes use of a MINLP algorithm for sequential modular simulators was employed to obtain a heat exchange network that provided a cost of energy that was 27% lower than the base case. Highly influential parameters for the pos gasification technologies (i.e. CO/steam ratio, gasifier temperature and pressure) were calculated to obtain the minimum cost of energy while chemical looping parameters (oxidation and reduction temperature) were ensured to be satisfied.

  1. Generalized Energy Flow Analysis Considering Electricity Gas and Heat Subsystems in Local-Area Energy Systems Integration

    Directory of Open Access Journals (Sweden)

    Jiaqi Shi

    2017-04-01

    Full Text Available To alleviate environmental pollution and improve the efficient use of energy, energy systems integration (ESI—covering electric power systems, heat systems and natural gas systems—has become an important trend in energy utilization. The traditional power flow calculation method, with the object as the power system, will prove difficult in meeting the requirements of the coupled energy flow analysis. This paper proposes a generalized energy flow (GEF analysis method which is suitable for an ESI containing electricity, heat and gas subsystems. First, the models of electricity, heat, and natural gas networks in the ESI are established. In view of the complexity of the conventional method to solve the gas network including the compressor, an improved practical equivalent method was adopted based on different control modes. On this basis, a hybrid method combining homotopy and the Newton-Raphson algorithm was executed to compute the nonlinear equations of GEF, and the Jacobi matrix reflecting the coupling relationship of multi-energy was derived considering the grid connected mode and island modes of the power system in the ESI. Finally, the validity of the proposed method in multi-energy flow calculation and the analysis of interacting characteristics was verified using practical cases.

  2. How would the gas exporting countries forum influence gas trade?

    International Nuclear Information System (INIS)

    Wagbara, O.N.

    2007-01-01

    The cleanest burning fossil fuel, today, is natural gas. While many businesses have gone global, it has remained an exception. An impending challenge facing the industry, however, is the evolution of a cartel from the 5-year-old Gas Exporting Countries Forum. How would this new organization influence the trade of gas globally? Does its existence imply a threat to the development of gas trade? The paper reviews this fairly new organization within the context of the above questions. It is mainly a comparative study of the body in relation to OPEC's historical, political and economic development. Subsequently, the author proposes probable influence options available to the Forum and the impending consequence of such actions on the market. The outcome of this study calls for further analysis and research on new issues and questions of interest. (author)

  3. How would the gas exporting countries forum influence gas trade?

    International Nuclear Information System (INIS)

    Wagbara, Obindah N.

    2007-01-01

    The cleanest burning fossil fuel, today, is natural gas. While many businesses have gone global, it has remained an exception. An impending challenge facing the industry, however, is the evolution of a cartel from the 5-year-old Gas Exporting Countries Forum. How would this new organization influence the trade of gas globally? Does its existence imply a threat to the development of gas trade? The paper reviews this fairly new organization within the context of the above questions. It is mainly a comparative study of the body in relation to OPEC's historical, political and economic development. Subsequently, the author proposes probable influence options available to the Forum and the impending consequence of such actions on the market. The outcome of this study calls for further analysis and research on new issues and questions of interest

  4. Greenhouse gas (GHG) emission in organic farming. Approximate quantification of its generation at the organic garden of the School of Agricultural, Food and Biosystems Engineering (ETSIAAB) in the Technical University of Madrid (UPM)

    Science.gov (United States)

    Campos, Jorge; Barbado, Elena; Maldonado, Mariano; Andreu, Gemma; López de Fuentes, Pilar

    2016-04-01

    As it well-known, agricultural soil fertilization increases the rate of greenhouse gas (GHG) emission production such as CO2, CH4 and N2O. Participation share of this activity on the climate change is currently under study, as well as the mitigation possibilities. In this context, we considered that it would be interesting to know how this share is in the case of organic farming. In relation to this, a field experiment was carried out at the organic garden of the School of Agricultural, Food and Biosystems Engineering (ETSIAAB) in the Technical University of Madrid (UPM). The orchard included different management growing areas, corresponding to different schools of organic farming. Soil and gas samples were taken from these different sites. Gas samples were collected throughout the growing season from an accumulated atmosphere inside static chambers inserted into the soil. Then, these samples were carried to the laboratory and there analyzed. The results obtained allow knowing approximately how ecological fertilization contributes to air pollution due to greenhouse gases.

  5. Simple, stable and reliable modeling of gas properties of organic working fluids in aerodynamic designs of turbomachinery for ORC and VCC

    Science.gov (United States)

    Kawakubo, T.

    2016-05-01

    A simple, stable and reliable modeling of the real gas nature of the working fluid is required for the aerodesigns of the turbine in the Organic Rankine Cycle and of the compressor in the Vapor Compression Cycle. Although many modern Computational Fluid Dynamics tools are capable of incorporating real gas models, simulations with such a gas model tend to be more time-consuming than those with a perfect gas model and even can be unstable due to the simulation near the saturation boundary. Thus a perfect gas approximation is still an attractive option to stably and swiftly conduct a design simulation. In this paper, an effective method of the CFD simulation with a perfect gas approximation is discussed. A method of representing the performance of the centrifugal compressor or the radial-inflow turbine by means of each set of non-dimensional performance parameters and translating the fictitious perfect gas result to the actual real gas performance is presented.

  6. DEVELOPMENT OF NOVEL CERAMIC NANOFILM-FIBER INTEGRATED OPTICAL SENSORS FOR RAPID DETECTION OF COAL DERIVED SYNTHESIS GAS

    Energy Technology Data Exchange (ETDEWEB)

    Junhang Dong; Hai Xiao; Xiling Tang; Hongmin Jiang; Kurtis Remmel; Amardeep Kaur

    2012-09-30

    The overall goal of this project is to conduct fundamental studies on advanced ceramic materials and fiber optic devices for developing new types of high temperature (>500{degree}C) fiber optic chemical sensors (FOCS) for monitoring fossil (mainly coal) and biomass derived gases in power plants. The primary technical objective is to investigate and demonstrate the nanocrystalline doped-ceramic thin film enabled FOCS that possess desired stability, sensitivity and selectivity for in-situ, rapid gas detection in the syngas streams from gasification and combustion flue gases. This report summarizes research works of two integrated parts: (1) development of metal oxide solid thin films as sensing materials for detection and measurement of important gas components relevant to the coal- and biomass-derived syngas and combustion gas streams at high temperatures; and (2) development of fiber optic devices that are potentially useful for constructing FOCS in combination with the solid oxide thin films identified in this program.

  7. Array of organic thin film transistors integrated with organic light emitting diodes on a plastic substrate

    International Nuclear Information System (INIS)

    Ryu, Gi-Seong; Choe, Ki-Beom; Song, Chung-Kun

    2006-01-01

    In order to demonstrate the possible application of an organic thin film transistor (OTFT) to a flexible active matrix organic light emitting diode (OLED) an array of 64 x 64 pixels was fabricated on a 4-in. size poly-ethylene-terephehalate substrate. Each pixel was composed of one OTFT integrated with one OLED. OTFTs successfully drove OLEDs by varying current in a wide range and some images were displayed on the array by emitting green light. The OTFTs used poly(4-vinylphenol) for the gate and pentacene for the semiconductor taking account compatibility with the PET substrate. The average mobility in the array was 0.2 cm 2 /V.s, which was reduced from 1.0 cm 2 /V.s in a single OTFT, and its variation over the entire substrate was 10%

  8. Organization and Integration of Learning Experiences in a Curriculum: A Case Study.

    Science.gov (United States)

    Everwijn, S. E. M.

    1983-01-01

    The literature on "organizers" by Ausubel, Earl, and Tyler provides clues to help teachers and students relate what has been learned in one subject to what is being learned in another. Problems of integration in a curriculum for student nurses are examined, and a solution to these problems is described. (RM)

  9. Shale gas. Shale gas formation and extraction

    International Nuclear Information System (INIS)

    Renard, Francois; Artru, Philippe

    2015-10-01

    A first article recalls the origin of shale gases and technological breakthroughs which allowed their exploitation, describes the development of shale gas exploitation in the USA during the 2000's and the consequences for the gas and electricity markets, and discusses the various environmental impacts (risks of pollution of aquifers, risks of induced seismicity, use and processing of drilling and production waters). The second article describes the formation of shale gas: presence of organic matter in sediments, early evolution with the biogenic gas, burrowing, diagenesis and oil formation, thermal generation of gas (condensates and methane). The author indicates the location of gas within the rock, and the main sites of shale oils and shale gases in the World. In the next part, the author describes the various phases of shale gas extraction: exploration, oriented drillings, well preparation for hydraulic fracturing, fracturing, processing of fracturing fluids, flow-back, gas production and transport, aquifer protection. He finally gives a brief overview of technical evolution and of shale gas economy

  10. Conversion of Low Quality Waste Heat to Electric Power with Small-Scale Organic Rankine Cycle (ORC) Engine/Generator Technology

    Science.gov (United States)

    2016-08-01

    efficiency by reducing energy consumption associated with electrical generation and reduces greenhouse gas emissions by increasing electrical generating...integrated system fuel economy test conditions This computation requires prediction of fuel consumption over baseline and integrated system load...EW-201251) Conversion of Low Quality Waste Heat to Electric Power with Small-Scale Organic Rankine Cycle (ORC) Engine/Generator Technology

  11. Waste Energy Recovery from Natural Gas Distribution Network: CELSIUS Project Demonstrator in Genoa

    Directory of Open Access Journals (Sweden)

    Davide Borelli

    2015-12-01

    Full Text Available Increasing energy efficiency by the smart recovery of waste energy is the scope of the CELSIUS Project (Combined Efficient Large Scale Integrated Urban Systems. The CELSIUS consortium includes a world-leading partnership of outstanding research, innovation and implementation organizations, and gather competence and excellence from five European cities with complementary baseline positions regarding the sustainable use of energy: Cologne, Genoa, Gothenburg, London, and Rotterdam. Lasting four-years and coordinated by the City of Gothenburg, the project faces with an holistic approach technical, economic, administrative, social, legal and political issues concerning smart district heating and cooling, aiming to establish best practice solutions. This will be done through the implementation of twelve new high-reaching demonstration projects, which cover the most major aspects of innovative urban heating and cooling for a smart city. The Genoa demonstrator was designed in order to recover energy from the pressure drop between the main supply line and the city natural gas network. The potential mechanical energy is converted to electricity by a turboexpander/generator system, which has been integrated in a combined heat and power plant to supply a district heating network. The performed energy analysis assessed natural gas saving and greenhouse gas reduction achieved through the smart systems integration.

  12. INTEGRATED PYROLYSIS COMBINED CYCLE BIOMASS POWER SYSTEM CONCEPT DEFINITION

    International Nuclear Information System (INIS)

    Sandvig, Eric; Walling, Gary; Brown, Robert C.; Pletka, Ryan; Radlein, Desmond; Johnson, Warren

    2003-01-01

    Advanced power systems based on integrated gasification/combined cycles (IGCC) are often presented as a solution to the present shortcomings of biomass as fuel. Although IGCC has been technically demonstrated at full scale, it has not been adopted for commercial power generation. Part of the reason for this situation is the continuing low price for coal. However, another significant barrier to IGCC is the high level of integration of this technology: the gas output from the gasifier must be perfectly matched to the energy demand of the gas turbine cycle. We are developing an alternative to IGCC for biomass power: the integrated (fast) pyrolysis/ combined cycle (IPCC). In this system solid biomass is converted into liquid rather than gaseous fuel. This liquid fuel, called bio-oil, is a mixture of oxygenated organic compounds and water that serves as fuel for a gas turbine topping cycle. Waste heat from the gas turbine provides thermal energy to the steam turbine bottoming cycle. Advantages of the biomass-fueled IPCC system include: combined cycle efficiency exceeding 37 percent efficiency for a system as small as 7.6 MW e ; absence of high pressure thermal reactors; decoupling of fuel processing and power generation; and opportunities for recovering value-added products from the bio-oil. This report provides a technical overview of the system including pyrolyzer design, fuel clean-up strategies, pyrolysate condenser design, opportunities for recovering pyrolysis byproducts, gas turbine cycle design, and Rankine steam cycle. The report also reviews the potential biomass fuel supply in Iowa, provide and economic analysis, and present a summery of benefits from the proposed system

  13. INTEGRATED PYROLYSIS COMBINED CYCLE BIOMASS POWER SYSTEM CONCEPT DEFINITION

    Energy Technology Data Exchange (ETDEWEB)

    Eric Sandvig; Gary Walling; Robert C. Brown; Ryan Pletka; Desmond Radlein; Warren Johnson

    2003-03-01

    Advanced power systems based on integrated gasification/combined cycles (IGCC) are often presented as a solution to the present shortcomings of biomass as fuel. Although IGCC has been technically demonstrated at full scale, it has not been adopted for commercial power generation. Part of the reason for this situation is the continuing low price for coal. However, another significant barrier to IGCC is the high level of integration of this technology: the gas output from the gasifier must be perfectly matched to the energy demand of the gas turbine cycle. We are developing an alternative to IGCC for biomass power: the integrated (fast) pyrolysis/ combined cycle (IPCC). In this system solid biomass is converted into liquid rather than gaseous fuel. This liquid fuel, called bio-oil, is a mixture of oxygenated organic compounds and water that serves as fuel for a gas turbine topping cycle. Waste heat from the gas turbine provides thermal energy to the steam turbine bottoming cycle. Advantages of the biomass-fueled IPCC system include: combined cycle efficiency exceeding 37 percent efficiency for a system as small as 7.6 MW{sub e}; absence of high pressure thermal reactors; decoupling of fuel processing and power generation; and opportunities for recovering value-added products from the bio-oil. This report provides a technical overview of the system including pyrolyzer design, fuel clean-up strategies, pyrolysate condenser design, opportunities for recovering pyrolysis byproducts, gas turbine cycle design, and Rankine steam cycle. The report also reviews the potential biomass fuel supply in Iowa, provide and economic analysis, and present a summery of benefits from the proposed system.

  14. Electro-scrubbing volatile organic carbons in the air stream with a gas diffusion electrode

    Energy Technology Data Exchange (ETDEWEB)

    Yang Ji, E-mail: yangji@ecust.edu.cn [School of Resources and Environmental Engineering, State Environmental Protection Key Laboratory of Environmental Risk Assessment and Control on Chemical Process, East China University of Science and Technology, Shanghai 200237 (China); School of Environmental Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240 (China); Liu Kaichen; Jia Jinping; Cao Limei [School of Environmental Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240 (China)

    2011-04-15

    It is demonstrated that exposing the VOC air streams to the electro-scrubbing reactor with a gas diffusion electrode leads to an efficient removal of organics. The importance order of the influence factors on the electro-scrubbing reactor performance is: conductivity, voltage and air stream flow-rate. The effective conductivity and high voltages generally are beneficial to the removal process and the air flow-rate is not a significant factor compared with the other two, indicating that the reactor might have a consistently satisfying performance within a wide range of gas volumetric load. The mass transfer of both organics and oxygen in the reactor is estimated by mathematical model, and the calculation determines the concentration boundary conditions for the 2-ethoxyethyl acetate removal: if the 2-ethoxyethyl acetate concentration in the inflow air stream holds C{sub G,i} {<=} 0.7198 % , the removal in the electro-scrubbing reactor is electrochemical reaction controlled; if C{sub G,i} > 0.7198 % , the controlling step will be the oxygen mass transfer from the air to the liquid in the electro-scrubbing reactor. The Apparent Current Efficiency of the electro-scrubbing reactor was also determined using COD data, which is significantly higher than some commercial metal oxide electrodes, showing that the reactor is energy efficient and has the promise for the future scale-up.

  15. Development of multicomponent parts-per-billion-level gas standards of volatile toxic organic compounds

    International Nuclear Information System (INIS)

    Rhoderick, G.C.; Zielinski, W.L. Jr.

    1990-01-01

    This paper reports that the demand for stable, low-concentration multicomponent standards of volatile toxic organic compounds for quantifying national and state measurement of ambient air quality and hazardous waste incineration emissions has markedly increased in recent years. In response to this demand, a microgravimetric technique was developed and validated for preparing such standards; these standards ranged in concentration from several parts per million (ppm) down to one part per billion (ppb) and in complexity from one organic up to 17. Studies using the gravimetric procedure to prepare mixtures of different groups of organics. including multi-components mixtures in the 5 to 20 ppb range, revealed a very low imprecision. This procedure is based on the separate gravimetric introduction of individual organics into an evacuated gas cylinder, followed by the pressurized addition of a precalculated amount of pure nitrogen. Additional studies confirmed the long-term stability of these mixtures. The uncertainty of the concentrations of the individual organics at the 95% confidence level ranged from less than 1% relative at 1 ppm to less than 10% relative at 1 ppb. Over 100 primary gravimetric standards have been developed, validated, and used for certifying the concentrations of a variety of mixtures for monitoring studies

  16. [Target and non-target screening of volatile organic compounds in industrial exhaust gas using thermal desorption-gas chromatography-mass spectrometry].

    Science.gov (United States)

    Ma, Huilian; Jin, Jing; Li, Yun; Chen, Jiping

    2017-10-08

    A method of comprehensive screening of the target and non-target volatile organic compounds (VOCs) in industrial exhaust gas using thermal desorption-gas chromatography-mass spectrometry (TD-GC-MS) has been developed. In this paper, two types of solid phase adsorption column were compared, and the Tenex SS TD Tube was selected. The analytes were enriched into the adsorption tube by constant flow sampling, and detected by TD-GC-MS in full scan mode. Target compounds were quantified by internal standard method, and the quantities of non-target compounds were calculated by response coefficient of toluene. The method detection limits (MDLs) for the 24 VOCs were 1.06 to 5.44 ng, and MDLs could also be expressed as 0.004 to 0.018 mg/m 3 assuming that the sampling volume was 300 mL. The average recoveries were in the range of 78.4% to 89.4% with the relative standard deviations (RSDs) of 3.9% to 14.4% ( n =7). The established analytical method was applied for the comprehensive screening of VOCs in a waste incineration power plant in Dalian city. Twenty-nine VOCs were identified. In these compounds, only five VOCs were the target compounds set in advance, which accounted for 26.7% of the total VOCs identified. Therefore, this study further proved the importance of screening non-target compounds in the analysis of VOCs in industrial exhaust gas, and has certain reference significance for the complete determination of VOCs distribution.

  17. Integration of Gas Enhanced Oil Recovery in Multiphase Fermentations for the Microbial Production of Fuels and Chemicals.

    Science.gov (United States)

    Pedraza-de la Cuesta, Susana; Keijzers, Lore; van der Wielen, Luuk A M; Cuellar, Maria C

    2018-04-01

    In multiphase fermentations where the product forms a second liquid phase or where solvents are added for product extraction, turbulent conditions disperse the oil phase as droplets. Surface-active components (SACs) present in the fermentation broth can stabilize the product droplets thus forming an emulsion. Breaking this emulsion increases process complexity and consequently the production cost. In previous works, it has been proposed to promote demulsification of oil/supernatant emulsions in an off-line batch bubble column operating at low gas flow rate. The aim of this study is to test the performance of this recovery method integrated to a fermentation, allowing for continuous removal of the oil phase. A 500 mL bubble column is successfully integrated with a 2 L reactor during 24 h without affecting cell growth or cell viability. However, higher levels of surfactants and emulsion stability are measured in the integrated system compared to a base case, reducing its capacity for oil recovery. This is related to release of SACs due to cellular stress when circulating through the recovery column. Therefore, it is concluded that the gas bubble-induced oil recovery method allows for oil separation and cell recycling without compromising fermentation performance; however, tuning of the column parameters considering increased levels of SACs due to cellular stress is required for improving oil recovery. © 2018 The Authors. Biotechnology Journal Published by Wiley-VCHVerlag GmbH & Co. KGaA, Weinheim.

  18. Density functional theory for adsorption of gas mixtures in metal-organic frameworks.

    Science.gov (United States)

    Liu, Yu; Liu, Honglai; Hu, Ying; Jiang, Jianwen

    2010-03-04

    In this work, a recently developed density functional theory in three-dimensional space was extended to the adsorption of gas mixtures. Weighted density approximations to the excess free energy with different weighting functions were adopted for both repulsive and attractive contributions. An equation of state for hard-sphere mixtures and a modified Benedict-Webb-Rubin equation for Lennard-Jones mixtures were used to estimate the excess free energy of a uniform fluid. The theory was applied to the adsorption of CO(2)/CH(4) and CO(2)/N(2) mixtures in two metal-organic frameworks: ZIF-8 and Zn(2)(BDC)(2)(ted). To validate the theoretical predictions, grand canonical Monte Carlo simulations were also conducted. The predicted adsorption and selectivity from DFT were found to agree well with the simulation results. CO(2) has stronger adsorption than CH(4) and N(2), particularly in Zn(2)(BDC)(2)(ted). The selectivity of CO(2) over CH(4) or N(2) increases with increasing pressure as attributed to the cooperative interactions of adsorbed CO(2) molecules. The composition of the gas mixture exhibits a significant effect on adsorption but not on selectivity.

  19. Structural change in Europe's gas markets: three scenarios for the development of the European gas market to 2020

    International Nuclear Information System (INIS)

    Ellis, A.; Bowitz, E.; Roland, K.

    2000-01-01

    Against the background of the European Union's Gas Directive, and the emergence of new players and markets in Europe's gas sector, this paper explores how company actions could shape the future for the gas industry. Starting with an examination of company strategies this paper develops three scenarios for the future: a 'Gradual Transformation' scenario where a single European gas market develops that is essentially oligopolistic in nature; a 'Vertical Integration' scenario, where upstream and downstream gas companies merge to form a vertically integrated gas supplier; and a 'Pull the Plug' scenario, where the current market structure decomposes into a competitive market. These scenarios are examined in terms of their impact on gas prices, demand and the distribution of gas rent along the supply chain. The paper highlights the fact that the EU's gas Directive is not sufficient for the introduction of competition into Europe's gas markets, but that company actions will be the key determinant, and they may favour alternative market structures. (Author)

  20. Controllable Organic Resistive Switching Achieved by One-Step Integration of Cone-Shaped Contact.

    Science.gov (United States)

    Ling, Haifeng; Yi, Mingdong; Nagai, Masaru; Xie, Linghai; Wang, Laiyuan; Hu, Bo; Huang, Wei

    2017-09-01

    Conductive filaments (CFs)-based resistive random access memory possesses the ability of scaling down to sub-nanoscale with high-density integration architecture, making it the most promising nanoelectronic technology for reclaiming Moore's law. Compared with the extensive study in inorganic switching medium, the scientific challenge now is to understand the growth kinetics of nanoscale CFs in organic polymers, aiming to achieve controllable switching characteristics toward flexible and reliable nonvolatile organic memory. Here, this paper systematically investigates the resistive switching (RS) behaviors based on a widely adopted vertical architecture of Al/organic/indium-tin-oxide (ITO), with poly(9-vinylcarbazole) as the case study. A nanoscale Al filament with a dynamic-gap zone (DGZ) is directly observed using in situ scanning transmission electron microscopy (STEM) , which demonstrates that the RS behaviors are related to the random formation of spliced filaments consisting of Al and oxygen vacancy dual conductive channels growing through carbazole groups. The randomicity of the filament formation can be depressed by introducing a cone-shaped contact via a one-step integration method. The conical electrode can effectively shorten the DGZ and enhance the localized electric field, thus reducing the switching voltage and improving the RS uniformity. This study provides a deeper insight of the multiple filamentary mechanisms for organic RS effect. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  1. Capillary gas-solid chromatography

    International Nuclear Information System (INIS)

    Berezkin, V.G.

    1996-01-01

    Modern state of gas adsorption chromatography in open capillary columns has been analyzed. The history of the method development and its role in gas chromatography, ways to construct open adsorptional capillary columns, foundations of the theory of retention and washing of chromatographic regions in gas adsorption capillary columns have been considered. The fields is extensively and for analyzing volatile compounds of different isotopic composition, inorganic and organic gases, volatile organic polar compounds, aqueous solutions of organic compounds. Separation of nuclear-spin isomers and isotopes of hydrogen is the first illustrative example of practical application of the adsorption capillary chromatography. It is shown that duration of protium and deuterium nuclear isomers may be reduced if the column temperature is brought to 47 K

  2. Positioning for capitation in long-term care: a profile of vertical integration strategies in health and social service organizations.

    Science.gov (United States)

    Walsh, A M

    1998-01-01

    During the next decade, the population over age 65 is expected to increase by 11% while the population over age 85 is expected to increase by 42%. These projections suggest that many organizations which currently provide services to the aged will be required to design a range of new products and services for this diverse population. Vertically integrated services provide a viable opportunity to competitively position an organization to respond to the diverse needs of an aged market. Since vertical integration will be essential in negotiating capitate contracts for the aged in the future, this study examined the extent of vertical integration in 116 health and social service organizations in an urban market with an expanding geriatric population.

  3. Study on Integrating Accounting in the Information System of the Organization

    Directory of Open Access Journals (Sweden)

    Ciuhureanu Alina-Teodora

    2017-12-01

    Full Text Available In order to gain power in an ever-changing economy, in diversified markets, the organization must have an up-to-date information system that enables managers to get a detailed understanding of the organization’s status and to obtain what is needed to manage – the information. Starting from these premises, the empirical research presents the components of the information system. One of the main contributions, however, is to customize the opinions of the specialists and to create a logical scheme on the accounting information system. Moreover, through selective research, the article analyzed the managers’ interest in accounting information and its integration into the information system of the organization.

  4. Gas transport in metal organic framework–polyetherimide mixed matrix membranes: The role of the polyetherimide backbone structure

    NARCIS (Netherlands)

    Hegde, Maruti; Shahid, S.; Norder, Ben; Dingemans, Theo J.; Nijmeijer, Dorothea C.

    2015-01-01

    We report on how the morphology of the polymer matrix, i.e. amorphous vs. semi-crystalline, affects the gas transport properties in a series of mixed matrix membranes (MMMs) using Cu3(BTC)2 as the metal organic framework (MOF) filler. The aim of our work is to demonstrate how incorporation of

  5. Gas transport in metal organic framework-polyetherimide mixed matrix membranes: The role of the polyetherimide backbone structure

    NARCIS (Netherlands)

    Hegde, Maruti; Shahid, Salman; Norder, Ben; Dingemans, T.J.; Nijmeijer, Kitty

    2015-01-01

    We report on how the morphology of the polymer matrix, i.e. amorphous vs. semi-crystalline, affects the gas transport properties in a series of mixed matrix membranes (MMMs) using Cu3(BTC)2 as the metal organic framework (MOF) filler. The aim of our work is to demonstrate how incorporation of

  6. Organic Pollutants in Shale Gas Flowback and Produced Waters: Identification, Potential Ecological Impact, and Implications for Treatment Strategies

    Science.gov (United States)

    2017-01-01

    Organic contaminants in shale gas flowback and produced water (FPW) are traditionally expressed as total organic carbon (TOC) or chemical oxygen demand (COD), though these parameters do not provide information on the toxicity and environmental fate of individual components. This review addresses identification of individual organic contaminants in FPW, and stresses the gaps in the knowledge on FPW composition that exist so far. Furthermore, the risk quotient approach was applied to predict the toxicity of the quantified organic compounds for fresh water organisms in recipient surface waters. This resulted in an identification of a number of FPW related organic compounds that are potentially harmful namely those compounds originating from shale formations (e.g., polycyclic aromatic hydrocarbons, phthalates), fracturing fluids (e.g., quaternary ammonium biocides, 2-butoxyethanol) and downhole transformations of organic compounds (e.g., carbon disulfide, halogenated organic compounds). Removal of these compounds by FPW treatment processes is reviewed and potential and efficient abatement strategies are defined. PMID:28376616

  7. Identification of novel synthetic organic compounds with supersonic gas chromatography-mass spectrometry.

    Science.gov (United States)

    Fialkov, Alexander B; Amirav, Aviv

    2004-11-26

    Several novel synthetic organic compounds were successfully analyzed with a unique type of GC-MS titled Supersonic GC-MS following a failure in their analysis with standard GC-MS. Supersonic GC-MS is based on interfacing GC and MS with a supersonic molecular beam (SMB) and on electron ionization of sample compounds as vibrationally cold molecules while in the SMB, or by cluster chemical ionization. The analyses of novel synthetic organic compounds significantly benefited from the extended range of compounds amenable to analyses with the Supersonic GC-MS. The Supersonic GC-MS enabled the analysis of thermally labile compounds that usually degrade in the GC injector, column and/or ion source. Due to the high carrier gas flow rate at the injector liner and column these compounds eluted without degradation at significantly lower elution temperatures and the use of fly-through EI ion source eliminated any sample degradation at the ion source. The cold EI feature of providing trustworthy enhanced molecular ion (M+), complemented by its optional further confirmation with cluster CI was highly valued by the synthetic organic chemists that were served by the Supersonic GC-MS. Furthermore, the provision of extended mass spectral structural, isomer and isotope information combined with short (a few minutes) GC-MS analysis times also proved beneficial for the analysis of unknown synthetic organic compounds. As a result, the synthetic organic chemists were provided with both qualitative and quantitative data on the composition of their synthetic mixture, and could better follow the path of their synthetic chemistry. Ten cases of such analyses are demonstrated in figures and discussed.

  8. Unraveling the High Open Circuit Voltage and High Performance of Integrated Perovskite/Organic Bulk-Heterojunction Solar Cells.

    Science.gov (United States)

    Dong, Shiqi; Liu, Yongsheng; Hong, Ziruo; Yao, Enping; Sun, Pengyu; Meng, Lei; Lin, Yuze; Huang, Jinsong; Li, Gang; Yang, Yang

    2017-08-09

    We have demonstrated high-performance integrated perovskite/bulk-heterojunction (BHJ) solar cells due to the low carrier recombination velocity, high open circuit voltage (V OC ), and increased light absorption ability in near-infrared (NIR) region of integrated devices. In particular, we find that the V OC of the integrated devices is dominated by (or pinned to) the perovskite cells, not the organic photovoltaic cells. A Quasi-Fermi Level Pinning Model was proposed to understand the working mechanism and the origin of the V OC of the integrated perovskite/BHJ solar cell, which following that of the perovskite solar cell and is much higher than that of the low bandgap polymer based organic BHJ solar cell. Evidence for the model was enhanced by examining the charge carrier behavior and photovoltaic behavior of the integrated devices under illumination of monochromatic light-emitting diodes at different characteristic wavelength. This finding shall pave an interesting possibility for integrated photovoltaic devices to harvest low energy photons in NIR region and further improve the current density without sacrificing V OC , thus providing new opportunities and significant implications for future industry applications of this kind of integrated solar cells.

  9. Integral or integrated marketing

    Directory of Open Access Journals (Sweden)

    Davčik Nebojša

    2006-01-01

    Full Text Available Marketing theorists and experts try to develop business efficient organization and to get marketing performance at higher, business integrated level since its earliest beginnings. The core issue in this paperwork is the dialectic and practical approach dilemma should we develop integrated or integral marketing approach in the organization. The presented company cases as well as dialectic and functional explanations of this dilemma clearly shows that integrated marketing is narrower approach than integral marketing if we take as focal point new, unique and completed entity. In the integration the essence is in getting different parts together, which do not have to make necessary the new entity. The key elements in the definition of the integral marketing are necessity and holistic, e.g. necessity to develop new, holistic entity.

  10. Fracture mapping in clays: the design and application of a mobile gas geochemistry laboratory for the analysis of soil gases

    International Nuclear Information System (INIS)

    Gregory, R.G.

    1988-02-01

    Integrated soil gas analyses for helium, radon, carbon dioxide, oxygen and organic gases allow the accurate interpretation of soil gas signatures as indicators of underlying structure. The most important features observed in the patterns of soil gas behaviour are large variations over faults and fractures. Structures such as these provide channelways for fluid movement in the upper crust. The construction of a mobile gas geochemistry laboratory for the analysis of soil gases at field investigation sites, and the subsequent trials carried out to evaluate the laboratory, clearly show that the soil gas investigation technique is accurate and viable as an independent site investigation method for the study of fracturing and groundwater movement around potential waste repository sites. (author)

  11. Assessing Emissions of Volatile Organic Componds from Landfills Gas

    Directory of Open Access Journals (Sweden)

    Fahime Khademi

    2016-01-01

    Full Text Available Background: Biogas is obtained by anaerobic decomposition of organic wastes buried materials used to produce electricity, heat and biofuels. Biogas is at the second place for power generation after hydropower and in 2000 about 6% of the world power generation was allocated to biogas. Biogas is composed of 40–45 vol% CO2, 55–65 vol% CH4, and about 1% non-methaneVOCs, and non-methane volatile organic compounds. Emission rates are used to evaluate the compliance with landfill gas emission regulations by the United States Environmental Protection Agency (USEPA. BTEX comounds affect the air quality and may be harmful to human health. Benzene, toluene, ethylbenzene and xylene isomers that are generally called BTEX compounds are the most abundant VOCs in biogas. Methods: Sampling of VOCs in biogas vents was operated passively or with Tedlar bags. 20 samples were collected from 40 wells of old and new biogas sites of Shiraz’ landfill. Immediately after sampling, the samples were transferred to the laboratory. Analysis of the samples was performed with GC-MS. Results: The results showed that in the collection of the old and new biogas sites, the highest concentration of VOCs was observed in toluene (0.85ppm followed by benzene (0.81ppm, ethylbenzene (0.13ppm and xylene (0.08ppm. Conclusion: The results of the study showed that in all samples, most available compounds in biogas vents were aromatic hydrocarbon compounds.These compounds’ constituents originate from household hazardous waste materials deposited in the landfill or from biological/chemical decomposition processes within the landfill.

  12. Gas production, composition and emission at a modern disposal site receiving waste with a low-organic content

    DEFF Research Database (Denmark)

    Scheutz, Charlotte; Fredenslund, Anders Michael; Nedenskov, Jonas

    2011-01-01

    AV Miljø is a modern waste disposal site receiving non-combustible waste with a low-organic content. The objective of the current project was to determine the gas generation, composition, emission, and oxidation in top covers on selected waste cells as well as the total methane (CH4) emission from....... The results indicated that the gas composition in the shredder waste was governed by chemical reactions as well as microbial reactions. CH4 mass balances from three individual waste cells showed that a significant part (between 15% and 67%) of the CH4 generated in cell 1.3 and 2.2.2 was emitted through...

  13. Comparative Evaluation of Integrated Waste Heat Utilization Systems for Coal-Fired Power Plants Based on In-Depth Boiler-Turbine Integration and Organic Rankine Cycle

    Directory of Open Access Journals (Sweden)

    Shengwei Huang

    2018-01-01

    Full Text Available To maximize the system-level heat integration, three retrofit concepts of waste heat recovery via organic Rankine cycle (ORC, in-depth boiler-turbine integration, and coupling of both are proposed, analyzed and comprehensively compared in terms of thermodynamic and economic performances. For thermodynamic analysis, exergy analysis is employed with grand composite curves illustrated to identify how the systems are fundamentally and quantitatively improved, and to highlight key processes for system improvement. For economic analysis, annual revenue and investment payback period are calculated based on the estimation of capital investment of each component to identify the economic feasibility and competitiveness of each retrofit concept proposed. The results show that the in-depth boiler-turbine integration achieves a better temperature match of heat flows involved for different fluids and multi-stage air preheating, thus a significant improvement of power output (23.99 MW, which is much larger than that of the system with only ORC (6.49 MW. This is mainly due to the limitation of the ultra-low temperature (from 135 to 75 °C heat available from the flue gas for ORC. The thermodynamic improvement is mostly contributed by the reduction of exergy destruction within the boiler subsystem, which is eventually converted to mechanical power; while the exergy destruction within the turbine system is almost not changed for the three concepts. The selection of ORC working fluids is performed to maximize the power output. Due to the low-grade heat source, the cycle with R11 offers the largest additional net power generation but is not significantly better than the other preselected working fluids. Economically, the in-depth boiler-turbine integration is the most economic completive solution with a payback period of only 0.78 year. The ORC concept is less attractive for a sole application due to a long payback time (2.26 years. However, by coupling both

  14. CO{sub 2} storage in the geological ground: Integrity of drilling acceptable for CSEGR (Carbon Sequestration with Enhanced Gas Recovery); CO{sub 2} Lagerung im Geogrund: Bohrungsintegritaet akzeptabel fuer CSEGR (Carbon Sequestration with Enhanced Gas Recovery)

    Energy Technology Data Exchange (ETDEWEB)

    Reinicke, K.M.; Franz, O. [Technische Univ. Clausthal (Germany). Inst. fuer Erdoel- und Erdgastechnik

    2008-10-23

    With respect to the handling of carbon dioxide, there exist long-standing experiences in the industry (a) for the injection of carbon dioxide in petroleum deposits in the context of EOR measures (EOR = Enhanced Oil Recovery); (b) for the production of high pressure sour gas from petroleum deposits and (c) for the injection of hydrogen sulfide and carbon dioxide from the production of sour gas. Extensive information about arising failure processes and consequences was compiled and used for the development of the sour gas technology. With employment of this technology, no fundamental problems are to be expected in order to guarantee a safe injection and production during the operation phase. The authors of the contribution under consideration report on the state of the art so far it is relevant for the guarantee of the drilling integrity under influence of carbon dioxide. Recommendations for the guarantee and the proof are given to the mechanical integrity for new drillings, old drillings, filled drillings and monitoring.

  15. Universal model for water costs of gas exchange by animals and plants.

    Science.gov (United States)

    Woods, H Arthur; Smith, Jennifer N

    2010-05-04

    For terrestrial animals and plants, a fundamental cost of living is water vapor lost to the atmosphere during exchange of metabolic gases. Here, by bringing together previously developed models for specific taxa, we integrate properties common to all terrestrial gas exchangers into a universal model of water loss. The model predicts that water loss scales to gas exchange with an exponent of 1 and that the amount of water lost per unit of gas exchanged depends on several factors: the surface temperature of the respiratory system near the outside of the organism, the gas consumed (oxygen or carbon dioxide), the steepness of the gradients for gas and vapor, and the transport mode (convective or diffusive). Model predictions were largely confirmed by data on 202 species in five taxa--insects, birds, bird eggs, mammals, and plants--spanning nine orders of magnitude in rate of gas exchange. Discrepancies between model predictions and data seemed to arise from biologically interesting violations of model assumptions, which emphasizes how poorly we understand gas exchange in some taxa. The universal model provides a unified conceptual framework for analyzing exchange-associated water losses across taxa with radically different metabolic and exchange systems.

  16. Natural gas usage as a heat source for integrated SMR and thermochemical hydrogen production technologies

    International Nuclear Information System (INIS)

    Jaber, O.; Naterer, G.F.; Dincer, I.

    2010-01-01

    This paper investigates various usages of natural gas (NG) as an energy source for different hydrogen production technologies. A comparison is made between the different methods of hydrogen production, based on the total amount of natural gas needed to produce a specific quantity of hydrogen, carbon dioxide emissions per mole of hydrogen produced, water requirements per mole of hydrogen produced, and a cost sensitivity analysis that takes into account the fuel cost, carbon dioxide capture cost and a carbon tax. The methods examined are the copper-chlorine (Cu-Cl) thermochemical cycle, steam methane reforming (SMR) and a modified sulfur-iodine (S-I) thermochemical cycle. Also, an integrated Cu-Cl/SMR plant is examined to show the unique advantages of modifying existing SMR plants with new hydrogen production technology. The analysis shows that the thermochemical Cu-Cl cycle out-performs the other conventional methods with respect to fuel requirements, carbon dioxide emissions and total cost of production. (author)

  17. Integral diagnostic in the failure causes of external corrosion of a natural gas transport pipeline

    Energy Technology Data Exchange (ETDEWEB)

    Mora-Mendoza, J.L.; Saucedo-Robles, L.C.; Rodriguez-Clemente, H. [PEMEX Gas y Petroquimica Basica, Subdireccion de Ductos; Marina Nacional 329, Edificio B-1, Piso 8, Col. Huasteca, D.F., CP 11311 (Mexico); Gonzalez-Nunez, M.A. [Instituto de Investigaciones Electricas, Reforma 113, Col. Palmira, Cuernavaca, Morelos, CP 62490 (Mexico); Zavala-Olivares, G.; Hernandez-Gayosso, M.J. [Instituto Mexicano del Petroleo, Direccion de Exploracion y Produccion, Eje Central Lazaro Cardenas Norte 152, Col. San Bartolo Atepehuacan, D.F., CP 07730 (Mexico)

    2011-08-15

    The objective of this study consisted in investigating the possible causes which give rise to the presence of low wall pipe thicknesses on a 16'' natural gas transport pipeline, even though during the last 12-year period cathodic protection (CP) potentials were kept in the protection range at which external corrosion should not occur. Results from in-line inspection from a 16'' natural gas transport pipeline showed 46 indications with more than 80% wall thickness lost due to external corrosion in the second segment of the pipeline. Direct inspection at the indication locations, review of the CP system performance, pipeline maintenance programs and studies, allowed to make an integral diagnostic where it was found out that the main cause of external corrosion was an inappropriate coating application since the pipeline construction, this situation has originated the increase of CP shielding effects through time. (Copyright copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  18. Integrated operations plan for the MFTF-B Mirror Fusion Test Facility. Volume I. Organization plan

    International Nuclear Information System (INIS)

    1981-12-01

    This plan and the accompanying MFTF-B Integrated Operations Plan are submitted in response to UC/LLNL Purchase Order 3883801, dated July 1981. The organization plan also addresses the specific tasks and trade studies directed by the scope of work. The Integrated Operations Plan, which includes a reliability, quality assurance, and safety plan and an integrated logistics plan, comprises the burden of the report. In the first section of this volume, certain underlying assumptions and observations are discussed setting the requirements and limits for organization. Section B presents the recommended structure itself. Section C Device Availability vs Maintenance and Support Efforts and Section D Staffing Levels and Skills provide backup detail and justification. Section E is a trade study on maintenance and support by LLNL staff vs subcontract and Section F is a plan for transitioning from the construction phase into operation. A brief summary of schedules and estimated costs concludes the volume

  19. Navigating the multilayered organization of eukaryotic signaling: a new trend in data integration.

    Directory of Open Access Journals (Sweden)

    Tapesh Santra

    2014-02-01

    Full Text Available The ever-increasing capacity of biological molecular data acquisition outpaces our ability to understand the meaningful relationships between molecules in a cell. Multiple databases were developed to store and organize these molecular data. However, emerging fundamental questions about concerted functions of these molecules in hierarchical cellular networks are poorly addressed. Here we review recent advances in the development of publically available databases that help us analyze the signal integration and processing by multilayered networks that specify biological responses in model organisms and human cells.

  20. Integration of seismic data and a triple porosity model for interpretation of tight gas formations in the Western Canada sedimentary basin

    Energy Technology Data Exchange (ETDEWEB)

    Castillo, Fernando; Aguilera, Roberto; Lawton, Don [University of Calgary (Canada)

    2011-07-01

    Due to the increased global demand for oil and gas, companies are looking to unconventional methods for exploring, drilling and refining these products. Unconventional reservoirs are found in the form of shale gas, coal bed methane and tight gas. This paper presents a model for evaluating various tight gas reservoirs in the Western Canada sedimentary basin (WCSB) by developing an equation. The proposed method integrates a triple porosity model with sonic, density and resistivity logs. The model uses petrographic data from work in the WCSB to determine the types of pores that are present in the tight rocks. The process also provides information on inter-well formation resistivity, porosity and water saturation to allow estimation of the amount of original gas in place. The results calculated from this study agreed with the actual deep resistivities of the WCSB Nikanassin group. This model can also be applied to other regions of the world that have similar characteristics to those of the WCSB.