WorldWideScience

Sample records for influencing dewatering properties

  1. Investigation of Parameters Affecting Gypsum Dewatering Properties in a Wet Flue Gas Desulphurization Pilot Plant

    DEFF Research Database (Denmark)

    Hansen, Brian Brun; Kiil, Søren

    2012-01-01

    Wet flue gas desulphurization (FGD) plants with forced oxidation, installed at coal and oil fired power plants for removal of SO2(g), must produce gypsum of high quality. However, quality issues such as an excessive moisture content, due to poor gypsum dewatering properties, may occur from time...... to time. In this work, the particle size distribution, morphology, and filtration rate of wet FGD gypsum formed in a pilot-scale experimental setup, operated in forced oxidation mode, have been studied. The influence of holding tank residence time (10–408 h), solids content (30–169 g/L), and the presence...... of impurities (0.002 M Al2F6; 50 g quartz/L; 0.02 M Al3+, and 0.040 M Mg2+) were investigated. In addition, slurry from a full-scale wet FGD plant, experiencing formation of flat shaped crystals and poor gypsum dewatering properties, was transferred to the pilot plant to test if the plant would now start...

  2. Investigation of Parameters Affecting Gypsum Dewatering Properties in a Wet Flue Gas Desulphurization Pilot Plant

    OpenAIRE

    Hansen, Brian Brun; Kiil, Søren

    2012-01-01

    Wet flue gas desulphurization (FGD) plants with forced oxidation, installed at coal and oil fired power plants for removal of SO2(g), must produce gypsum of high quality. However, quality issues such as an excessive moisture content, due to poor gypsum dewatering properties, may occur from time to time. In this work, the particle size distribution, morphology, and filtration rate of wet FGD gypsum formed in a pilot-scale experimental setup, operated in forced oxidation mode, have been studied...

  3. Correlation of wood-based components and dewatering properties of waste activated sludge from pulp and paper industry.

    Science.gov (United States)

    Kyllönen, H; Lehto, J; Pirkonen, P; Grönroos, A; Pakkanen, H; Alén, R

    2010-01-01

    Large amounts of wet sludge are produced annually in municipal and industrial wastewater treatment. Already in pulp and paper industry, more than ten million tons of primary sludge, waste activated sludge, and de-inking sludge is generated. Waste activated sludge contains large quantities of bound water, which is difficult to dewater. Low water content would be a matter of high calorific value in incineration but it also has effects on the volume and the quality of the matter to be handled in sludge disposal. In this research waste activated sludges from different pulp and paper mills were chemically characterised and dewatered. Correlations of chemical composition and dewatering properties were determined using multivariate analysis. Chemical characterisation included basic sludge analysis, elementary analysis and analysis of wood-based components, such as hemicelluloses and lignin-derived material. Dewatering properties were determined using measurements of dry solids content, flux and flocculant dosage. The effects of different variables varied according to the response concerned. The variables which were significant regarding cake DS increase in filtration or centrifugation and flocculant dosage needed in filtration were different from those which were significant regarding flux.

  4. Operator assisted optimization of sludge dewatering

    DEFF Research Database (Denmark)

    Grüttner, Henrik

    1991-01-01

    On a municipal wastewater treatment plant using a decanter-centrifuge for dewatering of anaerobic digested sludge an operator assisting system for sludge dewatering was developed. The system is based on a database used to collect data on sludge properties and operational conditions which is added...... by the operator. By graphical presentation and an advisory service these data are used to support the operator in his dewatering operations and to secure a running optimization of the sludge dewatering. Evaluations show that this system is a useful tool for data collection and presentation and that the data...... collected seem to reflect the actual situation at the plant. In the future such systems are expected to be used as tools for education of operators, transfer of knowledge from one operator to another and for a continuous optimization of dewatering operations. (A)...

  5. Thermally assisted mechanical dewatering (TAMD) of suspensions of fine particles: analysis of the influence of the operating conditions using the response surface methodology.

    Science.gov (United States)

    Mahmoud, Akrama; Fernandez, Aurora; Chituchi, Toma-Mihai; Arlabosse, Patricia

    2008-08-01

    Thermally assisted mechanical dewatering (TAMD) is a new process for energy-efficient liquid/solids separation which enhances conventional-device efficiency. The main idea of this process is to supply a flow of heat in mechanical dewatering processes to favour the reduction of the liquid content. This is not a new idea but the proposed combination, especially the chosen operating conditions (temperature dewatering parameter and an excellent indicator of the extent of TAMD. In this study, a two-factor central composite rotatable design was used to establish the optimum conditions for the TAMD of suspensions of fine particles. Significant regression models, describing changes on final dry solids content with respect to independent variables, were established with regression coefficients (usually called determination coefficients), R(2), greater than 80%. Experiments were carried out on a laboratory filtration/compression cell, firstly on different compressible materials: synthetic mineral suspensions such as talc and synthetic organic suspensions such as cellulose, and then on industrial materials, such as bentonite sludge provided by Soletanche Bachy Company. Experiment showed that the extent of TAMD for a given material is particularly dependent on their physical and chemical properties but also on processing parameters.

  6. Salmonid redd dewatering: What do we know

    Energy Technology Data Exchange (ETDEWEB)

    Becker, C D; Neitzel, D A

    1983-11-01

    Dewatering of salmonid spawning areas causes abrupt changes in the intergravel environment that may lead to extensive losses of development phases while intergravel in redds. Information on tolerance to dewatering and the extent of physicochemical changes in the gravel during dewatering can be used to assess potential impacts and to design and implement effective mitigation methods. Studies with fall chinook salmon are summarized, and the comparisons are made with results from available literature. Potentially useful methods of mitigation are mentioned. We found that prehatch phases (cleavage eggs and embryos) can be dewatered for several successive days and survive, but posthatch phases (eleutheroembryos and alevins) usually die within 24 hours. Survival of prehatch phases during extended dewatering requires maintenance of favorable intergravel temperature and moisture levels. Elevated temperatures (up to 22/sup 0/C) can be tolerated for up to 8 hours without direct adverse effects, but freezing temperatures (/sup -/1.0/sup 0/C or below) are lethal. Dewatered gravels must remain sufficient moisture to provide near 100% humidity for egg and embryo survival. In field situations, physicochemical conditions that limit survival in dewatered gravels include residual flow, temperature, gravel size and composition, and dissolved oxygen. Biological variables such as alevin behavior and certain species characteristics also influence survival. 29 refs., 6 figs.

  7. 正渗透污泥脱水工艺的影响因素研究%Study on influencing factors of forward osmosis sludge dewatering process

    Institute of Scientific and Technical Information of China (English)

    邢珊珊; 朱洪涛

    2014-01-01

    将正渗透技术应用于污泥浓缩脱水,对孔径更大、机械强度更高的低压过滤膜应用于正渗透污泥脱水工艺的可行性及影响因素进行了探索。对比试验证明低压过滤膜由于膜厚度方面的劣势带来的严重浓差极化现象而无法获得良好的水通量,不能满足用于正渗透污泥脱水的要求。对正渗透污泥脱水过程中盐离子反向传质情况的监测分析发现,这一过程受污泥侧盐累积量与污泥含水率两个因素影响,污泥侧盐浓度最终根据试验条件不同而稳定在0.1~0.2 mol/L 内。污泥中混入盐对污泥极限脱水性能存在不利影响而应加以控制。试验用的3种常用污泥絮凝剂使正渗透污泥脱水效果有所提高。%The forward osmosis process was applied for sludge dewatering.The feasibility of low-pressure filter membranes with larger pores and higher mechanical strength used in the forward osmosis sludge dewatering process and its influencing factors were investigated.The results show that a low water flux was resulted by a more severe concentration polarization due to the dis-advantages of the film thickness of low-pressure filter membrane.Therefore,the low-pressure filtration membrane is not suitable for the forward osmosis sludge dewatering process.The reverse salt transfer in the forward osmosis sludge dewatering process is affected by two factors including the salt accumulation of sludge side and the sludge moisture content.The salt concentration of sludge side keeps finally between 0.1 and 0.2 mol/L no matter experimental conditions.Salt dissolved in sludge was proved to have negative effects on sludge dewatering.As a result,the reverse salt transfer in the forward osmosis sludge dewatering process should be minimized as possible.The performance of forward osmosis sludge dewatering process is improved by the three kinds of common sludge coagulants.

  8. Synthesis, characterization and application of a novel starch-based flocculant with high flocculation and dewatering properties.

    Science.gov (United States)

    Wang, Jian-Ping; Yuan, Shi-Jie; Wang, Yi; Yu, Han-Qing

    2013-05-15

    Flocculation process is one of the most widely used techniques for water and wastewater treatment, and also for sludge dewatering. Synthesis of natural biopolymers or modification of natural biopolymers as environmentally friendly flocculants is highly desired in the field of environmental protection. In this work, a water soluble copolymer flocculant, STC-g-PDMC (starch-graft-poly (2-methacryloyloxyethyl) trimethyl ammonium chloride) was synthesized through grafting a monomer, (2-methacryloyloxyethyl) trimethyl ammonium chloride (DMC), onto starch initiated by potassium persulphate. Acetone and ethanol were used for copolymer precipitation and purification in the synthesis, which diminished the toxicity during the synthesis process. The graft copolymer was characterized using Fourier-transform infrared spectroscopy, (1)H nuclear magnetic resonance, X-ray powder diffraction, thermogravimetric analysis and elemental analysis. The prepared STC-g-PDMC exhibited a highly effective flocculation capability for kaolin suspensions compared with starch and polyacrylamide as control. The charge neutralization effect played an important role in the flocculation process at low flocculant dosages. When it was used as dewatering agent for anaerobic sludge, the conditioned sludge could be easily filtered after the dosage reached 0.696% of the dry weight of sludge. Such a graft copolymer is a promising green agent for wastewater treatment and sludge dewatering applications.

  9. Advanced Dewatering Systems Development

    Energy Technology Data Exchange (ETDEWEB)

    R.H. Yoon; G.H. Luttrell

    2008-07-31

    A new fine coal dewatering technology has been developed and tested in the present work. The work was funded by the Solid Fuels and Feedstocks Grand Challenge PRDA. The objective of this program was to 'develop innovative technical approaches to ensure a continued supply of environmentally sound solid fuels for existing and future combustion systems with minimal incremental fuel cost.' Specifically, this solicitation is aimed at developing technologies that can (i) improve the efficiency or economics of the recovery of carbon when beneficiating fine coal from both current production and existing coal slurry impoundments and (ii) assist in the greater utilization of coal fines by improving the handling characteristics of fine coal via dewatering and/or reconstitution. The results of the test work conducted during Phase I of the current project demonstrated that the new dewatering technologies can substantially reduce the moisture from fine coal, while the test work conducted during Phase II successfully demonstrated the commercial viability of this technology. It is believed that availability of such efficient and affordable dewatering technology is essential to meeting the DOE's objectives.

  10. Ultrafine coal single stage dewatering and briquetting process

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, J.W. [Missouri Univ., Rolla, MO (United States). Dept. of Mining Engineering; Honaker, R.Q. [Southern Illinois Univ., Carbondale, IL (United States). Dept. of Mining Engineering

    1995-12-31

    It is well known that a large portion of the pyrite particles in the coal seams of the Illinois Basin are finely disseminated within the coal matrix. In order to liberate these micron size pyrite particles, one must use a fine grinding operation. The ultrafine coal particles are difficult to dewater and create problems in coal transportation, as well as in storage and handling at utility plants. The objective of this research project is to combine the ultrafine coal dewatering and briquetting processes into a single stage operation. This will be accomplished by the use of bitumen based emulsions for dewatering and a compaction device for briquetting. During this reporting period, several types of coal samples with various particle size distributions have been tested for use in the dewatering and briquetting processes. Furthermore, various bitumen emulsions have been tested to determine the optimum dewatering reagent. These dewatering and pelletizing tests were carried out using a lab-scale ram extruder. Discharge from the dewatering and briquetting processes was tested to determine compliance with current federal and state requirements. The influence of bitumen emulsion on the sulfur content of coal pellets made were also examined. In addition, a ram extruder which can be operated continuously to simulate a rotary press operation, has been built and is currently being tested for use in the fine coal dewatering and pelletizing process.

  11. Influence of the reactant carbon-hydrogen-oxygen composition on the key products of the direct gasification of dewatered sewage sludge in supercritical water.

    Science.gov (United States)

    Gong, Miao; Zhu, Wei; Fan, Yujie; Zhang, Huiwen; Su, Ying

    2016-05-01

    The supercritical water gasification of ten different types of dewatered sewage sludges was investigated to understand the relationship between sludge properties and gasification products. Experiments were performed in a high-pressure autoclave at 400°C for 60 min. Results showed that gasification of sewage sludge in supercritical water consists mainly of a gasification reaction, a carbonization reaction and a persistent organic pollutants synthesis reaction. Changes in the reactant C/H/O composition have significant effects on the key gasification products. Total gas production increased with increasing C/H2O of the reactant. The char/coke content increased with increasing C/H ratio of the reactant. A decrease in the C/O ratio of the reactant led to a reduction in polycyclic aromatic hydrocarbon formation. This means that we can adjust the reactant C/H/O composition by adding carbon-, hydrogen-, and oxygen-containing substances such as coal, algae and H2O2 to optimize hydrogen production and to inhibit an undesired by-product formation. Copyright © 2016 Elsevier Ltd. All rights reserved.

  12. Ultra-fine dewatering

    Energy Technology Data Exchange (ETDEWEB)

    Patwardhan, A.; Chugh, Y.P.; Arnold, B.J.; Terblanche, A.N. [Southern Illinois University, IL (US)

    2004-12-01

    The paper assesses the results from a filter press study. They demonstrate the success of a low-cost, high-efficiency filter press for dewatering column flotation clean coal products from two coal mines. A Tecnicas Hidraulicas Filter Press and a PrepTech Inc. turbo column were used for in-plant testing at a mine extracting Illinois No. 6 seam coal and another extracting Illinois No. 5 seam coal. Based on the results, an increase in profitability of US $ 900,000 per year is projected from full-scale implementation of the technology at No. 5 seam coal mine. 6 figs.

  13. Enhanced Brine Dewatering System Project

    Data.gov (United States)

    National Aeronautics and Space Administration — The purpose of the Enhanced Brine Dewatering System (EBDS) is to provide a scalable means of completely recovering usable water from byproducts created by reverse...

  14. Enhanced Brine Dewatering System Project

    Data.gov (United States)

    National Aeronautics and Space Administration — The purpose of the Enhanced Brine Dewatering System (EBDS) is to provide an easily scalable means of completely recovering usable water from byproducts created by...

  15. Osmotic Effects in Sludge Dewatering

    DEFF Research Database (Denmark)

    Keiding, Kristian; Rasmussen, Michael R.

    2003-01-01

    A model of filtration dewatering is presented. The model is based on the d’Arcy flow equation in which the resistance to filtration is described by the Corzeny–Carman equation and the driving force is the difference between the external pressure and the osmotic pressure of the filter cake. It has...... been found that this model reproduces all known features of filtration dewatering and is found to be consistent with experimental data....

  16. The effect of coal bed dewatering and partial oxidation on biogenic methane potential

    Science.gov (United States)

    Jones, Elizabeth J.P.; Harris, Steve H.; Barnhart, Elliott P.; Orem, William H.; Clark, Arthur C.; Corum, Margo D.; Kirshtein, Julie D.; Varonka, Matthew S.; Voytek, Mary A.

    2013-01-01

    Coal formation dewatering at a site in the Powder River Basin was associated with enhanced potential for secondary biogenic methane determined by using a bioassay. We hypothesized that dewatering can stimulate microbial activity and increase the bioavailability of coal. We analyzed one dewatered and two water-saturated coals to examine possible ways in which dewatering influences coal bed natural gas biogenesis by looking at differences with respect to the native coal microbial community, coal-methane organic intermediates, and residual coal oxidation potential. Microbial biomass did not increase in response to dewatering. Small Subunit rRNA sequences retrieved from all coals sampled represented members from genera known to be aerobic, anaerobic and facultatively anaerobic. A Bray Curtis similarity analysis indicated that the microbial communities in water-saturated coals were more similar to each other than to the dewatered coal, suggesting an effect of dewatering. There was a higher incidence of long chain and volatile fatty acid intermediates in incubations of the dewatered coal compared to the water-saturated coals, and this could either be due to differences in microbial enzymatic activities or to chemical oxidation of the coal associated with O2 exposure. Dilute H2O2 treatment of two fractions of structural coal (kerogen and bitumen + kerogen) was used as a proxy for chemical oxidation by O2. The dewatered coal had a low residual oxidation potential compared to the water-saturated coals. Oxidation with 5% H2O2 did increase the bioavailability of structural coal, and the increase in residual oxidation potential in the water saturated coals was approximately equivalent to the higher methanogenic potential measured in the dewatered coal. Evidence from this study supports the idea that coal bed dewatering could stimulate biogenic methanogenesis through partial oxidation of the structural organics in coal once anaerobic conditions are restored.

  17. Osmotic Effects in Sludge Dewatering

    DEFF Research Database (Denmark)

    Keiding, Kristian; Rasmussen, Michael R.

    2003-01-01

    A model of filtration dewatering is presented. The model is based on the d’Arcy flow equation in which the resistance to filtration is described by the Corzeny–Carman equation and the driving force is the difference between the external pressure and the osmotic pressure of the filter cake. It has...

  18. Improvement of dewatering characteristics by co-digestion of rice straw with sewage sludge.

    Science.gov (United States)

    Gu, Tingting; Yamamoto-Ikemoto, Ryoko; Tsuchiya-Nakakihara, Eri; Watanabe, Haruki; Suetsugu, Yasutaka; Yanai, Atsushi

    2016-12-01

    A continuous mesophilic co-digestion of sewage sludge and softened rice straw was conducted and the dewatering characteristics of digested sludge were evaluated by a dewatering experiment using a belt press. The digestion was operated with solid retention time (SRT) of 25 days, and the feeding ratio of sludge to rice straw was 1:0.5 (total solids base). After 129 days of stable operation, the properties of digested sludge were analysed; then five kinds of cationic coagulants were tested to select the optimal coagulants for dewatering, and two coagulants were selected and used in the dewatering experiment because of lower doses and lower moisture of sludge cakes. Sludge property analysis showed that by the addition of rice straw, the fibrous materials in the digested sludge increased remarkably and the normalized capillary suction time (CST) decreased significantly, indicating that the dewatering properties was improved. The results of dewatering experiment showed that by the addition of rice straw, specific filtration rate of digested sludge increased by 81.2% and 174.6%, respectively; water content of dewatered sludge cakes decreased by 8.2% and 13.4%, respectively. The dewaterability of digested sludge was suggested to be improved due to rice straw addition.

  19. Dewatering studies of fine clean coal

    Energy Technology Data Exchange (ETDEWEB)

    Parekh, B.K.

    1991-01-01

    The main objective of the present research program is to study and understand dewatering characteristics of ultrafine clean coal obtained using the advanced column flotation technique from the Kerr-McGee's Galatia preparation plant fine coal waste stream. It is also the objective of the research program to utilize the basic study results, i.e., surface chemical, particle shape particle size distribution, etc., in developing a cost-effective dewatering method. The ultimate objective is to develop process criteria to obtain a dewatered clean coal product containing less that 20 percent moisture, using the conventional vacuum dewatering equipment. (VC)

  20. Fine coal dewatering enhancement using mechanical thermal techniques

    Energy Technology Data Exchange (ETDEWEB)

    Patwardhan, A.; Mondal, K.; Chugh, Y.P.; Ping, H.; Singh, N. [Southern Illinois University-Carbondale, Carbondale, IL (USA). Department of Mining & Mineral Resources Engineering

    2002-07-01

    Studies were conducted in a laboratory pressure filter to evaluate and enhance the dewatering potential of thickener underflow samples from two operating coal mines in Illinois mining the No. 6 and No. 5 seams. Physical properties such as, size distribution, zeta potential variation with pH, microstructure and particle shape and ash content were characterized. In addition cake microstructure data was obtained through scanning electron microscopy. Experiments were conducted at a pressure of 42 psig. The initial solids content was varied from 8 to 30% to determine the impact of initial solids concentration on dewatering performance. A host of chemical treatments involving different surfactants and electrolytes were evaluated. In addition, mechanical agitation of cake and hot water treatment of the slurry was attempted. The introduction of copper ions into the slurry resulted in enhanced filtration rates due to reduced specific resistance to filtrate flow and increased porosity of the cake. Use of cationic and anionic surfactants reduced the total residual moisture by over 4%. The combined effect of a surfactant and copper ion resulted in further reduction in cake moisture along with significant improvement in dewatering rates. Elevating the temperature of the slurry to 55{degree}C showed only a slight improvement in filtration rate but produced the most compact cake with the lowest moisture content. Significant improvement in the dewatering kinetics from addition of electrolytes was also observed for the Illinois No. 5 seam sample. Statistical analysis of experimental data indicates dewatering enhancements as a result of electrolyte addition, hot water treatment and mechanical agitation. 20 refs., 5 figs., 7 tabs.

  1. Properties of water-soluble and insoluble particulate matter emitted from dewatered sewage sludge incineration in a pilot-scale ash melting furnace

    Energy Technology Data Exchange (ETDEWEB)

    Lian Zhang; Megumi Masui; Hiroharu Mizukoshi; Yoshihiko Ninomiya; Jugo Koketsu; Chikao Kanaoka [Chubu University, Aichi (Japan). Department of Applied Chemistry

    2008-05-15

    Emission of inorganic particulate matter (PM) from the incineration of dewatered sewage sludge has been investigated in a novel ash melting furnace. The sludge containing 79 wt% water was incinerated in an oxygen-enriched atmosphere at the primary temperature of 1400{sup o}C, and its unburned volatile was combusted at 1100{sup o}C in a secondary combustion chamber. A 13-stage low-pressure-impactor and the conventional impinger methods were employed for PM sampling at the outlet of the secondary combustion chamber. The results indicate that, PM is dominated by volatile and semi-volatile elements including Br, Cl, P, S, Na, K, Zn, As, Cu, Mn and Ni. Less refractory elements were found. PM has two major fractions: {lt}0.22 and {ge}0.22 {mu}m. Their chemical forms as well as water solubility are different between two fractions. The majority of Br, nearly half of Cl, and 40% of S and P are present in the small fraction. They are mostly water-soluble due to the association with alkali elements and heavy metals. The water-insoluble calcium sulfate and calcium/iron phosphate were, however, found in the large fraction of PM. Regarding the cations, the water solubilities of Na, K, Mn and Ni are close to their proportions partitioned into the small fraction of PM, since their water-soluble species were preferentially formed in this fraction. A relatively weak correlation for Al, Ca and As, while no such a correlation were found for Cu, Zn and Fe, due to the complex compounds formed for them. 31 refs., 11 figs., 5 tabs.

  2. Chemical Dewatering Technique of waste Polymer Drilling Fluid

    Institute of Scientific and Technical Information of China (English)

    Li Gang; Zhu Muo

    1997-01-01

    @@ On the basis of the compositional analysis of waste polymer drilling fluid, we adopt chemical dewatering technique and thoroughly break down the colloid system of the drilling fluid. Having changed the surface properties of the clay particles and made the waste mud flocculate, the floc lost mud making ability and the phemeonenon of the floc returning mud is completely dispelled when it is buried. The recovered water can be reused in the mud system.

  3. Soil vapor extraction with dewatering

    Energy Technology Data Exchange (ETDEWEB)

    Thomson, N.R. [Univ. of Waterloo, Ontario (Canada)

    1996-08-01

    The physical treatment technology of soil vapor extraction (SVE) is reliable, safe, robust, and able to remove significant amounts of mass at a relatively low cost. SVE combined with a pump-and-treat system to create a dewatered zone has the opportunity to remove more mass with the added cost of treating the extracted groundwater. Various limiting processes result in a significant reduction in the overall mass removal rates from a SVE system in porous media. Only pilot scale, limited duration SVE tests conducted in low permeability media have been reported in the literature. It is expected that the presence of a fracture network in low permeability media will add another complexity to the limiting conditions surrounding the SVE technology. 20 refs., 4 figs.

  4. Fibers of secondary ligno-cellulose materials and their influence on properties of insulating fiberboards

    Directory of Open Access Journals (Sweden)

    Marian Babiak

    2008-12-01

    Full Text Available This paper deals with the influence of addition of abraded fiber, as a partial substitute of softwood fibers, on the properties of insulating fiberboard. The fiber used was characterized by fractional composition of fiber length according to McNett (STN 50 0289 using the apparatus for the measurement of fiber length in aqueoussuspension (ADV and according to Brecht-Holl (STN 50 0289 by the determination of water retained by fiber, speed of dewatering and defibrator seconds. Insulating fiberboards were prepared with different content of abraded fiber. Mechanical properties (bending strength and tension strength perpendicular to the board plane as well as physical properties (swelling, water uptake, thermal conductivity, thermal diffusivity specific heat and volumetricspecific heat were measured for the boards.

  5. Ultrafine coal single stage dewatering and briquetting process. Technical report, December 1, 1994--February 28, 1995

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, J.W.

    1996-03-01

    It is well known that a large portion of the pyrite particles in the coal seams of the Illinois Basin, are finely disseminated within the coal matrix. In order to liberate these micron size pyrite particles, one must use a fine grinding operation. The ultrafine coal particles that are produced are difficult to dewater and they create problems in coal transportation as well as in its storage and handling at utility plants. The objective of this research project is to combine ultrafine coal dewatering and briquetting processes into a single stage operation. This will be accomplished by the use of bitumen based emulsions for dewatering and a compaction device for briquetting. During this reporting period, two types of coal samples have been tested for use in the dewatering and briquetting processes. These tests were carried out using Orimulsion as the dewatering reagent. A ram extruder that can be operated continuously is used to fabricate dewatered pellets. The influence of compaction pressure, curing time, binder concentration (2% to 5%), particle size, and compacting time on the performance of coal pellets have been evaluated in terms of their water resistance and wear vulnerability.

  6. Ultrafine coal single stage dewatering and briquetting process. Technical report, September 1--November 30, 1994

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, J.W. [Univ. of Missouri, Rolla, MO (United States). Dept. of Mining Engineering; Honaker, R.Q. [Southern Illinois Univ., Carbondale, IL (United States). Dept. of Mining Engineering

    1994-12-31

    It is well known that a large portion of the pyrite particles in the coal seams of the Illinois Basin, are finely disseminated within the coal matrix. In order to liberate these micron size pyrite particles, one must use a fine grinding operation. The ultrafine coal particles that are produced are difficult to dewater and they create problems in coal transportation as well as in its storage and handling at utility plants. The objective of this research project is to combine ultrafine coal dewatering and briquetting processes into a single stage operation. This will be accomplished by the use of bitumen based emulsions for dewatering and a compaction device for briquetting. During this reporting period, two types of coal samples have been tested for use in the dewatering and briquetting processes. These tests were carried out in conjunction with a selected hydrophobic binder as the dewatering reagent and an uniaxial hydraulic press. The influence of compaction pressure and binder concentration (2 to 5%) on the performance of coal pellets have been evaluated in terms of their water and wear resistance. A laboratory scale ultrafine coal dewatering and briquetting extruder that can be operated continuously for coal pellets fabrication, has been designed and built, and will be available for testing in the next quarter.

  7. Enhancement of dewatering performance of digested paper mill sludge by chemical pretreatment

    Science.gov (United States)

    Lin, Y. Q.; Zeng, C.; Wu, H. H.; Zeng, B. X.

    2016-08-01

    The wide application of anaerobic digestion (AD) for waste sludge results in a huge amount of digested sludge, while the appropriate reuse of digested sludge depends on effective solid-liquid separation. Thus, chemical (acid/alkali) pretreatment effects on dewaterability of digested paper mill sludge (DPMS) for better downstream reuse based on enhanced solid- liquid separation were investigated in this research. The dewatering properties of paper mill sludge (PMS) were also investigated to elucidate the impact of AD on sludge dewaterability. The results indicated that a higher DPMS dewaterability was noted with acid pretreatment (pH5). A 41.37% moisture content and 74.41% dewatering efficiency were determined for DPMS after acid (pH5) pretreatment within 25 min. In addition, a 7.13 mg•g-1 VSS of extracellular polymeric substances (EPS) and 101.50 μm of average particle size were observed. It was also observed that both EPS concentrations and particle sizes were key parameters influencing DPMS dewaterability. Lower EPS concentrations with larger average particle sizes contributed to enhanced sludge dewaterability. Moreover, dewaterability of PMS was higher than that of DPMS, which illustrated that AD would decrease the sludge dewaterability.

  8. Electroosmotically enhanced sludge dewatering-pilot-plant study

    CSIR Research Space (South Africa)

    Smollen, M

    1994-01-01

    Full Text Available Owing to the inherent inefficiency of dewatering equipment widely used today, the search for improved dewatering techniques has been pursued by the investigation of new innovative ideas. The main thrust of these investigations has been...

  9. Thermal conductivity characteristics of dewatered sewage sludge by thermal hydrolysis reaction.

    Science.gov (United States)

    Song, Hyoung Woon; Park, Keum Joo; Han, Seong Kuk; Jung, Hee Suk

    2014-12-01

    The purpose of this study is to quantify the thermal conductivity of sewage sludge related to reaction temperature for the optimal design of a thermal hydrolysis reactor. We continuously quantified the thermal conductivity of dewatered sludge related to the reaction temperature. As the reaction temperature increased, the dewatered sludge is thermally liquefied under high temperature and pressure by the thermal hydrolysis reaction. Therefore, the bound water in the sludge cells comes out as free water, which changes the dewatered sludge from a solid phase to slurry in a liquid phase. As a result, the thermal conductivity of the sludge was more than 2.64 times lower than that of the water at 20. However, above 200, it became 0.704 W/m* degrees C, which is about 4% higher than that of water. As a result, the change in physical properties due to thermal hydrolysis appears to be an important factor for heat transfer efficiency. Implications: The thermal conductivity of dewatered sludge is an important factor the optimal design of a thermal hydrolysis reactor. The dewatered sludge is thermally liquefied under high temperature and pressure by the thermal hydrolysis reaction. The liquid phase slurry has a higher thermal conductivity than pure water.

  10. Super-energy-saving dewatering method for high-specific-surface-area fuels by using dimethyl ether

    Energy Technology Data Exchange (ETDEWEB)

    Kanda, H. [Central Research Institute for Electric Power Industry, Kanagawa (Japan)

    2008-07-01

    There is a growing need for the economical dewatering of high-specific-surface-area fuels containing large amounts of water, such as coal and sewage sludge. The principle underlying conventional dewatering methods is evaporation of the water content by heating the fuels to a high temperature, but this approach consumes a considerable amount of energy. The Central Research Institute of the Electric Power Industry (CRIEPI) has developed a method for the extraction of this water through the use of dimethyl ether (DME), which liquefies at ordinary temperatures under the influence of a slight pressure. In this method, the water content in the fuel is extracted into the liquefied DME for separation from the fuel. After dewatering, the DME is depressurised, and subsequently vaporised, thereby leaving the separated water. Dewatering with an input energy of only 1109 kJ/kg water under ordinary conditions has been demonstrated theoretically.

  11. 水热及微波处理对我国典型褐煤气化特性的影响%Influence of the Hydrothermal Dewatering and microwave irradiation treatment on the Gasification Characteristics of Typical Chinese Lignite

    Institute of Scientific and Technical Information of China (English)

    王智化; 葛立超; 徐超群

    2016-01-01

    The influences of hydrothermal dewatering (HTD) and microwave irradiation performed at different temperatures on the gasification characteristics of typical lignites with different metamorphic grades in China were investigated in this paper. Results show that the upgrading process significantly decreases the inherent moisture at a maximum degree of 87.31% and oxygen content, and increases calorific value and fixed carbon content, According to the oxygen/carbon ratio parameter, the coal rank increases. The complex changes occurred on coal structure during the HTD process lead to pore size of coal char develop to the microporous region, and the surface area and volume increase at first but then decrease. Due to the development of coal structure and the increment of coal rank, the gasification process of upgraded coal is delayed towards high temperature region, the temperatures when carbon conversion rate reaches 50% increase. From the results of kinetic calculation, activation energy increases after treatment, and the reaction order of mechanistic model is changed. Besides, all the changes caused by HTD are more obvious when the upgraded temperature increased from 250 °C to 300 °C and when the rank of raw brown coal was lower. The upgrading process significantly decreased the inherent moisture content at a maximum degree of 87.31 % in a short time, and increased the calorific value and fixed carbon content. The moisture contents of all upgraded coals were less than 10 wt%. After upgrading, pore distribution extended to the micropore region, the surface area and volume increased, and the average pore size decreased. Based on thermo-gravimetric analysis, the temperature when carbon conversion rate reaches 50% decreased, and the gasification rate increased, indicating the increase of gasification activity. From the results of kinetic calculation,activation energy decreased after treatment, and the reaction order of mechanistic model changed. All the changes caused by

  12. Influences of influent carbon source on extracellular polymeric substances (EPS) and physicochemical properties of activated sludge.

    Science.gov (United States)

    Ye, Fenxia; Peng, Ge; Li, Ying

    2011-08-01

    It is necessary to understand the bioflocculation, settling and dewatering characteristics in the activated sludge process in order to establish more efficient operational strategies. The influences of carbon source on the extracellular polymeric substances (EPS) and flocculation, settling and dewatering properties of the activated sludge were investigated. Laboratory-scale completely mixed activated sludge processes were used to grow the activated sludge with different carbon sources of starch, glucose and sodium acetate. The sludge fed with acetate had highest loosely bound EPS (LB-EPS) and that fed with starch lowest. The amount of tightly bound EPS (TB-EPS), protein content in LB-EPS, polysaccharide content and protein contents in TB-EPS, were independent of the influent carbon source. The polysaccharide content in LB-EPS of the activated sludge fed with sodium acetate was lower slightly than those of starch and glucose. The sludge also had a nearly consistent flocs size and the sludge volume index (SVI) value. ESS content of the sludge fed with sodium acetate was higher initially, although it was similar to those fed with glucose and starch finally. However, the specific resistance to filtration and normalized capillary suction time fluctuated first, but finally were stable at around 5.0×10(8)mkg(-1) and 3.5 s Lg(-1) SS, respectively. Only the protein content in LB-EPS weakly correlated with the flocs size and SVI of the activated sludge. But there was no correlation between any other EPS contents or components and the physicochemical properties of the activated sludge.

  13. Improving the effectiveness of wells for lignite mine dewatering

    Energy Technology Data Exchange (ETDEWEB)

    Rude, T.R.; Banning, A. [Aachen Univ. (Germany). Inst. of Hydrogeology; Klauder, W.; Roger, S. [Aachen Univ. (Germany). Inst. of Hydraulic Engineering and Water Resources Management; Vinzelberg, G. [RWE Power AG, Bergheim (Germany). Dept. of Water Resources Management

    2010-07-01

    Mine dewatering is an important factor in determining the economic feasibility of lignite open cast mining projects. Ochre formation is accelerated in open pit dewatering, as the wells have long filter lengths that allow for high oxygen flux into well screens, gravel packs, and the surrounding aquifer. Ochre formation can reduce the productivity of wells by an estimated 20 percent. This experimental study investigated the formation of ochre in different environments using well screens from the Rhenish lignite mining district in Germany. The influence of oxygen, iron (Fe{sup 2+}), pH, flow velocity, water composition, and microorganisms were considered. Samples from the mine were passed through an apparatus that supplied Fe{sup 2+} and filtered the formed Fe{sup 3+} oxide colloids. The oxygen- and iron-free water was then conditioned and treated with ultraviolet (UV) radiation. Results of the study showed that Fe{sup 3+} hydroxides quickly formed in the screen due to high Fe{sup 2+} concentrations. Results indicated that pH must be kept high in the deoxygenation unit in order to facilitate rapid oxygen consumption. The experimental study will be used to investigate abiotic conditions created by variations in flow velocity, Fe{sup 2+} concentrations, sulfate content and alkalinity. 7 refs., 3 figs.

  14. Dewatering of alumino-humic sludge: impacts of hydroxide.

    Science.gov (United States)

    Bache, D H; Papavasilopoulos, E N

    2003-08-01

    The paper draws together information on factors which influence the conditioning and dewatering behaviour of an alum sludge gained from the coagulation of a low-turbidity coloured water. A principal focus is the potential impact of aluminium hydroxide on the sludge character. Background information is provided on the composition of the source floc for the domain pH 6.0-6.5 and Al>2.0mg/l. From this, there were many pointers to the presence of Al(OH)(3)(s) within the floc. A series of comparisons were made between an alum sludge and a hydroxide suspension at a concentration equivalent to the coagulant fraction within the sludge. The parameters studied included floc size, floc density, polymer adsorption and dewatering behaviour at different time-scales. In all cases, there were strong similarities in the behaviour of the two suspensions-indicating the potential impact of the hydroxide. There was also evidence of common features being displayed by both the organic fractions and the hydroxide. It was suggested that some of the behavioural features might emanate from a common fractal structure within the source floc, the fractal dimension (approximately 1) being insensitive to composition.

  15. [Study on dewatering of activated sludge under applied electric field].

    Science.gov (United States)

    Ji, Xue-Yuan; Wang, Yi-Li; Feng, Jing

    2012-12-01

    For an electro-dewatering process of activated sludge (AS), the effect of pH and conductivity of AS, flocculation conditioning and operation factors of horizontal electric field (voltage magnitude, method of applying electric field and distance between plates) were investigated, and the corresponding optimum electro-dewatering conditions were also obtained. The results showed that the best electro-dewatering effect was achieved for AS without change of its pH value (6.93) and conductivity (1.46 mS x cm(-1)). CPAM conditioning could lead to the increase of 30%-40% in the dewatering rate and accelerate the dewatering process, whereas a slight increase in the electro-dewatering rate. The electro-dewatering rate for conditioned AS reached 83.12% during an electric field applied period of 60 minutes, while this rate for original AS could be 75.31% even the electric field applied period extended to 120 minutes. The delay of applying the electric field had an inhibition effect on the AS electro-dewatering rate. Moreover, the optimum conditions for AS electro-dewatering were followed: CPAM dose of 9 g x kg(-1), electric field strength of 600 V x m(-1), distance between the two plates of 40 mm, dehydration time of 60 minutes. Under above optimum conditions the AS electro-dewatering rate could approach to 85.33% and the moisture content in AS decreased from 99.30% to 95.15% accordingly.

  16. Influence of the Hydrothermal Dewatering on the Gasification Characteristics of Typical Chinese Lignite%水热处理对我国典型褐煤气化特性的影响

    Institute of Scientific and Technical Information of China (English)

    葛立超; 张彦威; 应芝; 王智化; 周俊虎; 岑可法

    2013-01-01

    选取我国主要褐煤产区不同煤阶的3种典型褐煤,用水热处理对其进行脱水改性并研究改性前后褐煤 CO2气化特性的变化。结果表明,经过水热处理后,褐煤中的水分大幅度下降,最高降幅达87.31%,固定碳和热值上升,氧含量下降,煤阶参数(O/C原子比)下降,褐煤煤阶上升。水热处理过程中煤质结构的复杂重整导致煤焦孔径向微孔方向发展,先降低后增加,而比表面积和孔容呈现先上升后下降的趋势。煤质结构深度变化和煤阶的上升使得改性后褐煤的气化特性曲线向高温区移动,碳转化率达到50%时的气化温度上升。动力学计算结果表明,经过水热改性后气化反应活化能上升,反应级数发生变化。较高的水热处理终温和相对较低的原煤煤阶都使得水热脱水改性的效果更为显著。%The influences of hydrothermal dewatering (HTD) performed at different temperatures on the gasification characteristics of typical lignites with different metamorphic grades in China were investigated in this paper. Results show that the upgrading process significantly decreases the inherent moisture at a maximum degree of 87.31%and oxygen content, and increases calorific value and fixed carbon content. According to the oxygen/carbon ratio parameter, the coal rank increases. The complex changes occurred on coal structure during the HTD process lead to pore size of coal char develop to the microporous region, and the surface area and volume increase at first but then decrease. Due to the development of coal structure and the increment of coal rank, the gasification process of upgraded coal is delayed towards high temperature region, the temperature increases when carbon conversion rate reaches 50%. From the results of kinetic calculation, activation energy increases after the hydrothermal treatment, and the reaction order of mechanistic model is changed. Besides, all the changes

  17. Dewatering studies of fine clean coal

    Energy Technology Data Exchange (ETDEWEB)

    Parekh, B.K.

    1991-01-01

    Physical cleaning of ultra-fine coal using an advanced froth flotation technique provides a low ash product, however, the amount of water associated with clean coal is high. Economic removal of water from the froth will be important for commercial applicability of advanced froth flotation processes. The main objective of the present research program is to study and understand the dewatering characteristics of ultra-fine clean coal and to develop the process parameters to effectively reduce the moisture to less than 20 percent in the clean coal product. The research approach under investigation utilizes synergistic effects of metal ions and surfactant to lower the moisture of clean coal using a conventional vacuum dewatering technique. During the last year's effort, it was reported that a combination of metal ion and surfactant provided a 22 percent moisture filter cake.

  18. Optimisation of extraction and sludge dewatering efficiencies of bio-flocculants extracted from Abelmoschus esculentus (okra).

    Science.gov (United States)

    Lee, Chai Siah; Chong, Mei Fong; Robinson, John; Binner, Eleanor

    2015-07-01

    The production of natural biopolymers as flocculants for water treatment is highly desirable due to their inherent low toxicity and low environmental footprint. In this study, bio-flocculants were extracted from Hibiscus/Abelmoschus esculentus (okra) by using a water extraction method, and the extract yield and its performance in sludge dewatering were evaluated. Single factor experimental design was employed to obtain the optimum conditions for extraction temperature (25-90 °C), time (0.25-5 h), solvent loading (0.5-5 w/w) and agitation speed (0-225 rpm). Results showed that extraction yield was affected non-linearly by all experimental variables, whilst the sludge dewatering ability was only influenced by the temperature of the extraction process. The optimum extraction conditions were obtained at 70 °C, 2 h, solvent loading of 2.5 w/w and agitation at 200 rpm. Under the optimal conditions, the extract yield was 2.38%, which is comparable to the extraction of other polysaccharides (0.69-3.66%). The bio-flocculants displayed >98% removal of suspended solids and 68% water recovery during sludge dewatering, and were shown to be comparable with commercial polyacrylamide flocculants. This work shows that bio-flocculants could offer a feasible alternative to synthetic flocculants for water treatment and sludge dewatering applications, and can be extracted using only water as a solvent, minimising the environmental footprint of the extraction process.

  19. Parameter investigation for decentralised dewatering and solar thermic drying of sludge.

    Science.gov (United States)

    Wett, B; Demattio, M; Becker, W

    2005-01-01

    The purpose of this paper is an experimental and model assisted investigation of the capabilities of a dewatering system for sewage sludge for decentralised sites. Laboratory and field tests are performed with different initial conditions and the influences of filter medium, initial height, initial total suspended solids, temperature and relative humidity are discussed. The experimental work shows the feasibility of geotextile media for dewatering high water content sewage sludge and that the textile structure is of secondary importance. The specific filter resistance of the sludge cake is found to be the most significant factor in dewatering applications. The mathematical description of the dewatering process is based on the superposition of two models, the Conventional Filtration Theory for the filtration phase and the BT-model for the drying phase. Feasibility and limits of the theoretical approach are evaluated by means of a comparison between measurements and simulated data of cyclic reloading tests. It is found that a better filtration efficiency is achieved at higher TSS and at lower initial height of the slurry layer. Due to the viscosity decrease, a higher temperature enhances not only evaporation, but also filtration rate.

  20. High pressure dewatering of liquid manure; Hoejtryksafvanding af gylle

    Energy Technology Data Exchange (ETDEWEB)

    Koch, T.

    1999-08-01

    The purpose of this work is to develop a dewatering method that can dewater digested manure to a dry matter content that makes it possible to utilise the dry matter for energy production. Many tests of existing analysis methods for liquid manure. None of the mathods have shown any acceptable correlation's between the results and obtained dewatering characteristics. This project have not developed any analysis methods that can predict the mechanical behaviour of manure. But the dewatering device that has been developed works, and can dewater manure. It has been proved that it is possible to dewater digested manure up to 59-60% dry matter content in laboratory conditions. (dewatering time 10-20 minutes and a pressure of up to 61 MPa). The experiment has shown that the maximum obtainable pressure in the manure (before it escapes the dewatering chamber) is dependent of the speed of pressure increase. At more 'commercial' conditions (a total dewatering cycle time of 30-60 seconds) it is possible to obtain a dry matter content of 50-54%. Some times it is possible to obtain 58% dry matter content and 2 days later it is only possible to obtain 51% drymatter content. 2-10% of the ammonium and potassium and 20-40% of the phosphorous is found in the dry fraction. Fresh manure have been dewatered and the maximum obtainable dry matter content is approx. 25-35% at 5-15 MPa. In the second phase of the project it was decided to include an experiment of dewatering wet straw and straw coke. A technical note on this experiment is included as an appendix. (LN)

  1. Dewatering of fine coal using hyperbaric centrifugation

    Energy Technology Data Exchange (ETDEWEB)

    Ramazan Asmatulu; Gerald H. Luttrell; Roe-Hoan Yoon [Virginia Polytechnic Institute and State University, Blacksburg, VA (US). Center for Advanced Separation Technologies

    2005-09-01

    Many coal preparation plants are forced to discard their fine coal because of the inability of existing technologies to reduce the moisture content of this product to an acceptable level. In an effort to overcome this problem, a new mechanical dewatering method has been developed that combines centrifugation with pressure filtration. The process, which may be referred to as hyperbaric centrifugation, is capable of producing a drier product than can be achieved using either filtration or centrifugation alone. The test data obtained from batch experiments show that the new method can reduce cake moisture to 10% or below for many fine coal product streams.

  2. The utilization of forward osmosis for coal tailings dewatering

    Science.gov (United States)

    The feasibility of dewatering coal tailings slurry by forward osmosis (FO) membrane process was investigated in this research. A prototype cell was designed and used for the dewatering tests. A cellulosic FO membrane (Hydration Technology Innovations, LLC, Albany, OR) was used fo...

  3. The utilization of forward osmosis for coal tailings dewatering

    Science.gov (United States)

    The feasibility of dewatering coal tailings slurry by forward osmosis (FO) membrane process was investigated in this research. A prototype cell was designed and used for the dewatering tests. A cellulosic FO membrane (Hydration Technology Innovations, LLC, Albany, OR) was used fo...

  4. Groundwater Sustainability through a Novel Dewatering Technology

    Science.gov (United States)

    Jin, Y.; Holzbecher, E.; Ebneth, S.

    2012-12-01

    Groundwater plays a key role in the hydrologic cycle and ecosystem balances. Over the past decades, groundwater is intensively extracted in order to keep construction or mining sites dry. For the latter purpose the pumped water is usually discharged into a nearby surface water body or injected into an aquifer distant from the abstraction sites. As a result, aquifers are depleted and the local eco-system is disrupted as a consequence of falling groundwater tables. Given ongoing pressure on aquifer from abstraction sites, it is vital to bring up adequate attention on groundwater conservation. We demonstrate a novel technique, Düsensauginfiltration (DSI, translated as 'nozzel-suction-infiltration'), which avoids water conveyance but still lowers the groundwater table locally. The method combines abstraction of groundwater at the upper part of the aquifer with injection in the same borehole, but at a greater depth. Hence no water is withdrawn from the system. The method is already used practically in Germany, Netherlands, and China, however, it is not yet fully scientifically understood and evaluated. Currently, two tests sites in Germany, for single and multi well respectively, are selected, at which the DSI technology is currently examined. The project is cooperated with a leading dewatering company (Hoelscher Wasserbau GmbH) and funded by Deutsche Bundesstiftung Umwelt (DBU). To provide the basic principle of the method, we present numerical models solving the differential equation, which is derived from Darcy's Law and mass conservation, describing groundwater flow. We set up stationary numerical models in 2D (vertical cross section for single well case) and 3D (multi well case and/or when ambient groundwater flow is considered) using COMSOL Multiphysics. Since our model region only involves the saturated part of the unconfined aquifer, the numerical model solves a free boundary problem using hydraulic pressure as unknown variable. Two physical modes are included

  5. Thin lift dewatering of oil sand tailings: optimizing dewatering of fluid fine tailings by controlling polymer mixing

    Energy Technology Data Exchange (ETDEWEB)

    Demoz, A.; Munoz, V.; Mikula, R. [Natural Resources Canada, CanmetENERGY, Devon, Alberta (Canada)

    2011-07-01

    In the oil sands industry, dewatering of tailings is an important issue. Recent work has shown that the addition of polymer helps to enhance dewatering of fluid fine tailings. High molecular weight polymers are used to bind small solids which results in a higher floc strength with no significant effect on water chemistry. The problem of this technique is that polymers only achieve optimal performance within a narrow window. This paper aimed at assessing the effect of mixing on the dewatering performance of polymer treatment on mature fine tailings. Tests were performed with different impeller types, mixing speeds and durations. Results demonstrated that the flocculation process is critical in the dewatering process and that working at the optimal flocculation conditions presents considerable benefits. This paper investigated the importance of mixing on the dewatering process and highlighted that further work has to be undertaken to optimize this process.

  6. Dewatering coal gas by means of triethylene glycol

    Energy Technology Data Exchange (ETDEWEB)

    Kravets, P.D.; Zhila, N.P.; Govurun, A.A.; Skripchenko, N.P.; Kiseleva, O.I. (Yuzhniigiprogaz (USSR))

    1991-05-01

    Coal gas from the Avdeevka coking plant was dewatered using an absorption method (diethylene glycol process). Flowsheets of the dewatering system are shown. Dewatering efficiency was insufficient and resulted in increased corrosion of a pipeline used for coal gas transport. Increasing efficiency of coal gas dewatering by replacing diethylene glycol with triethylene glycol is analyzed. The dewatering system using the triethylene glycol was developed and tested on a commercial scale. Dewatering conditions were the following: coal gas pressure 1.2-1.3 MPa, temperature from 27 to 38 C, dewatering capacity 43,000-69,000 m{sup 3}/h. Moisture content in coal gas was reduced from 3.0 to 0.62-0.45 g/m{sup 3} (more than 5 times). Spraying intensity was 58-69 l/1,000 m{sup 3} gas, triethylene glycol dissolution with water was 1.5-5.0%. Content of triethylene glycol after regeneration ranged from 95 to 96%. Losses of triethylene glycol were 1.6 times lower than losses of diethylene glycol. Replacing diethylene glycol with triethylene glycol was not associated with extra investment or extra operating cost. 5 refs.

  7. Dewatering gas wells with pneumatic pumping equipment

    Energy Technology Data Exchange (ETDEWEB)

    Nickell, R.L.

    1973-01-01

    El Paso Natural Gas Co. has been operating pumping units on gas wells since 1964. At present, the company operates some 69 pumping units in the E. Panhandle field in Texas and the S. Erick field in Oklahoma. Of these 6 are pneumatic units and the remainder is conventional beam type units powered by gas-fueled engines or electric motors. A graphical representation of the data obtained from the El Paso wells in which various lift facilities are installed is included. These data show initial cost, maintenance cost, and lift cost per barrel of (1) gas engine beam unit; (2) electric beam unit; (3) pneumatic unit; (4) gas lift; and (5) intermitter. While not a panacea for all dewatering ills, pneumatic pumping represents an economical tool which may be applied to a wide range of conditions.

  8. Investigation into alternative sludge conditioning prior to dewatering

    CSIR Research Space (South Africa)

    Smollen, M

    1997-01-01

    Full Text Available The principal objective of this work is to provide a more effective alternative for sludge conditioning prior to mechanical dewatering. The common use of polyelectrolytes often results in the anal cake solids concentration not sufficiently high...

  9. Filtration and dewatering: review of literature. [117 references

    Energy Technology Data Exchange (ETDEWEB)

    Gala, H. B.; Chiang, S. H.

    1980-09-01

    Filtration and dewatering are important aspects of any chemical process involved in producing solid product from a slurry. However, these operations are not studied in as much detail as other industrial operations like distillation, absorption, etc. In the past, the design of filtration equipment was considered more of an art than science. Only in the last few years have attempts been made to understand the fundamental mechanism underlying these operations. In this review, the present status of filtration and dewatering is discussed, particularly concerning the models used for predicting the rate of filtration and dewatering. Effects of various parameters, size of particles in the slurry, their shape and method of cake formation, etc., on the characteristics of these operations are analyzed. A separate chapter on the use of these processes in coal cleaning is included. Dewatering of fine coal and refuse has attracted a great deal of attention in recent years. Special problems associated with dewatering of fine coal are discussed. Enhanced methods of dewatering are reviewed and finally areas requiring further research are highlighted.

  10. Bioelectricity generation and dewatered sludge degradation in microbial capacitive desalination cell.

    Science.gov (United States)

    Meng, Fanyu; Zhao, Qingliang; Na, Xiaolin; Zheng, Zhen; Jiang, Junqiu; Wei, Liangliang; Zhang, Jun

    2016-05-18

    Microbial desalination cell (MDC) is a new approach for the synergy in bioelectricity generation, desalination and organic waste treatment without additional power input. However, current MDC systems cause salt accumulation in anodic wastewater and sludge. A microbial capacitive desalination cell (MCDC) with dewatered sludge as anodic substrate was developed to address the salt migration problem and improve the sludge recycling value by special designed-membrane assemblies, which consisted of cation exchange membranes (CEMs), layers of activated carbon cloth (ACC), and nickel foam. Experimental results indicated that the maximum power output of 2.06 W/m(3) with open circuit voltage (OCV) of 0.942 V was produced in 42 days. When initial NaCl concentration was 2 g/L, the desalinization rate was about 15.5 mg/(L·h) in the first 24 h, indicating that the MCDC reactor was suitable to desalinize the low concentration salt solution rapidly. The conductivity of the anodic substrate decreased during the 42-day operation; the CEM/ACC/Ni assemblies could effectively restrict the salt accumulation in MCDC anode and promote dewatered sludge effective use by optimizing the dewatered sludge properties, such as organic matter, C/N, pH value, and electric conductivity (EC).

  11. DEVELOPMENT OF DEWATERING AIDS FOR MINERALS AND COAL FINES

    Energy Technology Data Exchange (ETDEWEB)

    Roe-Hoam Yoon; Ramazan Asmatulu; Ismail Yildirim; William Jansen; Jinmig Zhang; Brad Atkinson; Jeff Havens

    2004-07-01

    MCT has developed a suite of novel dewatering chemicals (or aids) that are designed to cause a decrease in the capillary pressures of the water trapped in a filter cake by (1) decreasing the surface tension of water, (2) increasing the contact angles of the particles to be dewatered, and (3) causing the particles to coagulate, all at the same time. The decrease in capillary pressure in turn causes an increase in the rate filtration, an increase in throughput, and a decrease in pressure drop requirement for filtration. The reagents are used frequently as blends of different chemicals in order to bring about the changes in all of the process variables noted above. The minerals and coal samples tested in the present work included copper sulfide, lead sulfide, zinc sulfide, kaolin clay, talc, and silica. The laboratory-scale test work included studies of reagent types, drying cycle times, cake thickness, slurry temperature, conditioning intensity and time, solid content, and reagent dosages. To better understand the mechanisms involved, fundamental studies were also conducted. These included the measurements of the contact angles of the particles to be dewatered (which are the measures of particle hydrophobicity) and the surface tensions of the filtrates produced from dewatering tests. The results of the laboratory-scale filtration experiments showed that the use of the novel dewatering aids can reduce the moistures of the filter cake by 30 to 50% over what can be achieved using no dewatering aids. In many cases, such high levels of moisture reductions are sufficient to obviate the needs for thermal drying, which is costly and energy intensive. Furthermore, the use of the novel dewatering aids cause a substantial increase in the kinetics of dewatering, which in turn results in increased throughput. As a result of these technological advantages, the novel dewatering aids have been licensed to Nalco, which is one of the largest mining chemicals companies of the world. At

  12. Electroosmotic dewatering of dredged sediments: bench-scale investigation.

    Science.gov (United States)

    Reddy, Krishna R; Urbanek, Adam; Khodadoust, Amid P

    2006-01-01

    The Indiana Harbor (Indiana, USA) has not been dredged since 1972 due to lack of a suitable disposal site for dredged sediment. As a result of this, over a million cubic yards of highly contaminated sediment has accumulated in the harbor. Recently, the United States Army Corps of Engineers (USACE) has selected a site for the confined disposal facility (CDF) and is in the process of designing it. Although dredging can be accomplished rapidly, the disposal in the CDF has to be done slowly to allow adequate time for consolidation to occur. The sediment possesses very high moisture content and very low hydraulic conductivity, which cause consolidation to occur slowly. Consolidation of the sediment is essential in order to achieve adequate shear strength of sediments and also to provide enough air space to accommodate the large amount of sediment that requires disposal. Currently, it has been estimated that if a one 3-foot (0.9-m) thick layer of sediment was disposed of at the CDF annually, it would take approximately 10 years to dispose of all the sediment that is to be dredged from the Indiana Harbor. This study investigated the feasibility of using an electroosmotic dewatering technology to accelerate dewatering and consolidation of sediment, thereby allowing more rapid disposal of sediment into the CDF. Electroosmotic dewatering essentially involves applying a small electric potential across the sediment layer, thereby inducing rapid flow as a result of physico-chemical and electrochemical processes. A series of bench-scale electrokinetic experiments were conducted on actual dredged sediment samples from the Indiana Harbor to investigate dewatering rates caused by gravity alone, dewatering rates caused by gravity and electric potential, and the effects of the addition of polymer flocculants on dewatering of the sediments. The results showed that electroosmotic dewatering under an applied electric potential of 1.0VDC/cm could increase the rate of dewatering and

  13. Electrokinetic dewatering of ultrafine coal and coal tailings

    Energy Technology Data Exchange (ETDEWEB)

    Andy Fourie [University of Western Australia, WA (Australia). CSIRO

    2008-03-15

    There are a number of established technologies for reducing the water content of coal slurries before impounding the slurry. This report deals with the process of electrokinetic dewatering, whereby water is extracted from a slurry through the application of direct current voltage using two or more electrodes. Water flows towards the negatively charged electrode, the cathode, where it can be collected. This project sought to verify that the findings of work carried out about two decades ago on coal tailings was valid when conductive polymer electrodes (commonly known as EKGs - ElectroKinetic Geosynthetics) are used. Verify the applicability of electrokinetic dewatering to a range of ultrafine coal products and coal tailings; and characterise the dewatering efficiency and effectiveness and consequent potential economic benefits for different electrokinetic treatment regimes for both in-situ and in-process dewatering methods using EKGs. The current project has again proved the technical viability of dewatering ultrafine coal tailings electrokinetically. Before the technology can be adopted at full scale, however, it would be important to conduct field trials.

  14. Restructuring of colloidal cakes during dewatering.

    Science.gov (United States)

    Madeline, J B; Meireles, M; Bourgerette, C; Botet, R; Schweins, R; Cabane, B

    2007-02-13

    Aqueous suspensions of aggregated silica particles have been dewatered to the point where the colloidal aggregates connect to each other and build a macroscopic network. These wet cakes have been compressed through the application of osmotic pressure. Some cakes offer a strong resistance to osmotic pressure and remain at a low volume fraction of solids; other cakes yield at low applied pressures, achieving nearly complete solid/liquid separation. We used small angle neutron scattering and transmission electron microscopy to determine the processes by which the particles move and reorganize during cake collapse. We found that these restructuring processes follow a general course composed of three stages: (1) at all scales, voids are compressed, with large voids compressed more extensively than smaller ones; the local order remains unchanged; (2) all voids with diameters in the range of 2-20 particle diameters collapse, and a few dense regions (lumps) are formed; and (3) the dense lumps build a rigid skeleton that resists further compression. Depending on the nature of interparticle bonds, some cakes jump spontaneously into stage 3 while others remain stuck in stage 1. To elucidate the relation between bond strength and compression resistance, we have constructed a numerical model of the colloidal network. In this model, particles interact through noncentral forces that are produced by springs attached to their surfaces. Networks made of bonds that break upon stretching evolve through a plastic deformation that reproduces the three stages of restructuring evidenced by the experiments. Networks made of bonds that are fragile jump into stage 3. Networks made of bonds that can be stretched without breaking evolve through elastic compression and restructure only according to stage 1.

  15. Monitoring and troubleshooting of non-filamentous settling and dewatering problems in an industrial activated sludge treatment plant

    DEFF Research Database (Denmark)

    Kjellerup, B. V.; Keiding, Kristian; Nielsen, Per Halkjær

    2001-01-01

    dewaterability. The monitoring program revealed that a deterioration of the floc strength and the settling properties in the process tanks was closely connected to downstream dewatering problems and poor effluent quality. Particularly severe problems were observed a few weeks after the production at the factory...... had started after summer closedown. Possible reasons for the changes in floc properties in the process tanks were found by a) analysing change in wastewater composition by evaluating the different production lines in the industrial plant, b) evaluating the operation of the plant, and c) performing...... to characterise the changes in floc properties that led to settling and dewatering problems and to find reasons for this taking place, a comprehensive monitoring program was conducted during more than one year. The monitoring program included various measurements of floc settleability, floc strength and sludge...

  16. Electric dewatering and drying of fine-grained products; Elektrisk afvanding og toerring af finkornede produkter

    Energy Technology Data Exchange (ETDEWEB)

    Hansen, H.K.; Villumsen, A.

    2001-07-01

    The aim of the project was to elucidate four aspects related to using electric direct current to find an energy saving alternative to existing methods within dewatering of fine-grained products. The four aspects were a) electrophoresis forced sedimentation of chalk slurry, b) electro osmotic dewatering of chalk slurry, c) electro osmotic dewatering of agricultural chalk and d) electro osmotic dewatering of liquid organic wastes. (EHS)

  17. Mechanical dewatering of silage; Mechanische Entwaesserung von Silage

    Energy Technology Data Exchange (ETDEWEB)

    Scholz, Volkhard; Daries, Werner [Leibniz-Institut fuer Agrartechnik Potsdam-Bornim e.V. (ATB), Potsdam (Germany). Abteilung Technik der Aufbereitung, Lagerung und Konservierung; Rinder, Ralf [Anhydro GmbH, Kassel (Germany)

    2009-07-01

    The use of screw presses for dewatering of silage is energetically more efficient than thermal drying. Tests with two types of screw presses show that on dry matter flow rates of more than 1.0 tDM/h the specific energy consumption is less than 30 kWh/tDM. The water content of the silage is decreased by 5 to 20 % and the share of undesired ingredients by 2 to 30 %. Besides press design and plant species, in particular moisture content, chip size and density of silage are essentially for the dewatering success. (orig.)

  18. Influence of Spinning Variable on the FR Properties of Yarns

    Institute of Scientific and Technical Information of China (English)

    Eric Oyondi Nganyi; YU Chong-wen(郁崇文)

    2003-01-01

    Broadly considered, spinning variables influences the properties of yarns. However there is scant information on the influence on the fire retardancy (FR) properties. The present work aims to establish the influence of the spinning method, twist, and fibre distribution in a blended yarn, on the FR properties of the yarn.

  19. Lake Michigan Bluff Dewatering and Stabilization Study - Allegan County, Michigan

    Science.gov (United States)

    2012-09-01

    inner bar. The smooth bed features have been interpreted to represent a sand veneer over a cohesive till. Sand probing with a jet pump has verified the...dewatering system than for conventional shore protection methods such as cement seawalls, steel sheet-pile bulkheads, and stone revetments

  20. The Development of Dewatering Predictions of the Velenje Coalmine

    Directory of Open Access Journals (Sweden)

    Željko Vukelić

    2016-08-01

    Full Text Available The complex hydro-geological situation, particularly in terms of groundwater, has been a constant threat to the mining carried out at the Velenje colliery since its inception. Of particular interest to the authors are the difficulties presented to the colliery by the adjacent sand aquifers, as the water pressure within these sands directly impacts mining safety, and the aquifers themselves are most directly affected by dewatering. In order to monitor water levels and estimate dewatering at the Velenje wells, multi-layered modelling using 3D Finite Difference Method (FDM has already been carried out. However, FDM is not optimal due to its greater dependence on cell size than on water flow. In 2017 in Velenje, a series of wells will be terminated as a result of mining and mining-induced subsidence, leading to dewatering and danger of flooding. As part of a plan to address this by replacing dewatering structures, a series of drive-in filters will be implemented around the entry and exit point tunnels of a longwall face. Because FDM seems to be inadequate for purposes of optimising this process, the Finite Elements Method (FEM was applied in this case. Based on such an application of FEM, a prediction of the optimisation of drive-in filters was carried out by the authors.

  1. Vibratory centrifuge for the dewatering of coal sludge

    Energy Technology Data Exchange (ETDEWEB)

    Schiele, H.; Schlebusch, L.

    1981-03-03

    A vibratory centrifuge for the dewatering of coal sludge, washed small coal or slack which comprises a revolvable conical screen which has a diameter that increases towards its discharge end. The conical screen is vibratable in an axial direction and includes radial steps each having a height of at least 20 mm to rearrangement or loosen the material in the zone of each step.

  2. Method of separating and de-watering fine particles

    Energy Technology Data Exchange (ETDEWEB)

    Yoon, Roe-Hoan

    2016-12-13

    A process for cleaning and dewatering hydrophobic particulate materials is presented. The process is performed in two steps: 1) agglomeration of the hydrophobic particles in a first hydrophobic liquid/aqueous mixture; followed by 2) dispersion of the agglomerates in a second hydrophobic liquid to release the water trapped within the agglomerates along with the entrained hydrophilic particles.

  3. The Practice and Explore of Dewatering Slag Tailings by Using Ceramic Filter%陶瓷过滤机应用于炉渣选矿尾矿脱水的实践与探索

    Institute of Scientific and Technical Information of China (English)

    谢杰; 马松勃

    2014-01-01

    陶瓷过滤机是一种应用较广的脱水设备。本文概述了铜炉渣选矿尾矿应用陶瓷过滤机脱水的生产状况,发现了影响系统生产的各类问题并提出了改进措施;探索研究了工艺、设备及物料性质对选矿尾矿过滤产能的影响,在最佳工艺条件下,陶瓷过滤机产能可达291 kg/(m2· h)。%Ceramic filter is widely used as a kind of dewatering equipment . This paper summarized the pro-duction situation of dewatering the slag beneficiation tailings of copper by using ceramic filter , some prob-lems that affected the system production were found and the corresponding improvement measures were put forward . And also found that the process , equipment and material properties influenced the filter ca-pacity , under the condition of optimum process , ceramic filter capacity can up to 291 kg/( m2.h) .

  4. Aircraft type influence on contrail properties

    Directory of Open Access Journals (Sweden)

    P. Jeßberger

    2013-05-01

    Full Text Available The investigation of the impact of aircraft parameters on contrail properties helps to better understand the climate impact from aviation. Yet, in observations, it is a challenge to separate aircraft and meteorological influences on contrail formation. During the CONCERT campaign in November 2008, contrails from 3 Airbus passenger aircraft of type A319-111, A340-311 and A380-841 were probed at cruise under similar meteorological conditions with in-situ instruments on board the DLR research aircraft Falcon. Within the 2 min old contrails detected near ice saturation, we find similar effective diameters Deff (5.2–5.9 μm, but differences in particle number densities nice (162–235 cm−3 and in vertical contrail extensions (120–290 m, resulting in large differences in contrail optical depths τ (0.25–0.94. Hence larger aircraft produce optically thicker contrails. Based on the observations, we apply the EULAG-LCM model with explicit ice microphysics and in addition the Contrail and Cirrus Prediction model CoCiP to calculate the aircraft type impact on young contrails under identical meteorological conditions. The observed increase in τ for heavier aircraft is confirmed by the models, yet for generally smaller τ. An aircraft dependence of climate relevant contrail properties persists during contrail lifetime, adding importance to aircraft dependent model initialization. We finally derive an analytical relationship between contrail, aircraft and meteorological parameters. Near ice saturation, contrail width × τ scales linearly with fuel flow rate as confirmed by observations. For higher saturation ratios approximations from theory suggest a non-linear increase in the form (RHI–12/3. Summarized our combined results could help to more accurately assess the climate impact from aviation using an aircraft dependent contrail parameterization.

  5. Occurrence and discharge of pharmaceuticals and personal care products in dewatered sludge from WWTPs in Beijing and Shenzhen

    Directory of Open Access Journals (Sweden)

    Rui Dong

    2016-03-01

    Full Text Available This study mainly focused on the occurrence of pharmaceutical and personal care products (PPCPs in sewage dewatered sludge and their discharges through sludge disposal from wastewater treatment plants (WWTPs. The data were obtained and calculated from seven PPCPs in dewatered sludge collected from 12 WWTPs in two typical cities, Beijing and Shenzhen in China. Four of seven PPCPs, diclofenac acid, carbamazepine, mefenamic acid and N,N-diethyl-m-toluamide were detectable in dewatered sludge from Beijing and Shenzhen with concentration up to 4240, 11,060, 92 and 219 μg/kg respectively. While, the other three compounds, trimethoprim, chloramphenicol and bezafibrate were not detected in collected samples from these two cities. The highest discharge of diclofenac acid and carbamazepine were 1023 g/d and 494 g/d respectively. In addition, the total discharge of these four detected PPCPs from each plant ranged from 5 to 1092 g/d in Beijing and 4–497 g/d in Shenzhen. Thus, PPCP discharge through sludge disposal cannot be neglected, and further research on transfer of PPCPs during sludge disposal onto agriculture land and influence of sludge application is required and essential.

  6. Reducing water leakage into underground coal mines by aquifer dewatering

    Energy Technology Data Exchange (ETDEWEB)

    Schubert, J. P.

    1978-01-01

    Based on stratigraphic, structural, hydrogeologic, and mining data collected during a study in central Pennsylvania, a two-dimensional, finite-difference computer model was used to simulate groundwater flow in a sandstone unit (0.3 to 11 m thick) overlying an underground mine, and to evaluate the responses of the flow system and leakage rate into the mine when hypothetical dewatering wells are introduced into the system. Simulation of well dewatering, using 25 wells, showed that negligible reduction in leakage would occur if sandstone permeability was less than 0.30 m/day. When sandstone permeability equalled 3.0 m/day, 25 wells reduced leakage by 2.4 percent.

  7. Investigation of Activated Sludge Sewage Dewatering by Electro-Flotation: Optimization of Operating Parameters and Energy Consumption

    Directory of Open Access Journals (Sweden)

    K. Godini

    2015-01-01

    Full Text Available Introduction & Objective: Common methods for dewatering of wastewater sludge need chemi-cals and high energy consumption and have low efficiency and environmental acceptability because of colloidal and jelly property of bacteria cells of sludge. Furthermore, their operat-ing is completely complicated. In this study electro-flotation way, as a novel method, was performed to cover these limitations and also operating parameters and energy consumptions were optimized. Materials & Methods: In order to carry out the experiments, a batch reactor with the effective volume of 450 ml was used. In this experimental- laboratorial study, the effect of pH, current density, hydraulic retention time and surface/volume changes on the amount of dewatering and the amount of total solids in both the sludge cake (dewatered sludge and the water sepa-rated from the sludge as well as the content of TSS, TS and COD in the water were investi-gated. The amount of consumed electricity was calculated and lowered by optimizing the variables. Results: The finding showed that the best efficiency (81.6% of sludge dewatering was achieved at pH = 2, current density = 1.7mA/cm2, hydraulic retention time = 30 min and sur-face/volume amount = 178 cm2/L with electrical energy consumption of 0.33-0.726 kWh/m3. Conclusion: The electro-flotation process owing to high efficiency, convenient construction and operating and lower energy consumption and construction costs compared to common methods can effectively be applied. (Sci J Hamadan Univ Med Sci 2015; 21 (4:341-349

  8. Dynamics of heterogeneous separation on fine clean coal dewatering by filter press%浮选细精煤压滤脱水非均相分离动力学特性

    Institute of Scientific and Technical Information of China (English)

    巩冠群; 谢广元; 张英杰; 沙杰; 刘均章; 张秀峰; 陈宣辰; 董玉蛟

    2011-01-01

    Based on the dewatering theory and analysis of heterogeneous separation of fine clean coal dewatering, the heterogeneous separation process on fine clean coal dewatering of Yongcheng anthracite was investigated. A theoretical model on fine coal dewatering and its heterogeneous separation dynamic equations were proposed. The results show that the pressure filtration of flotation fine clean coal has the characteristic of heterogeneous separation of fluid dynamics. Fine coal dewatering rate is the function of driving force of operation, filter media,filter cake properties, coal slurry property and effective area coefficient of compaction. Pressure filtration process is comprised of filtration and pressure dewatering. The dewatering dynamic equation of flotation fine clean coal of Yongcheng anthracite was proposed. The compressibility index of cake s is 0. 855 9, the material properties constant k is 0. 237 1.%基于脱水理论及非均相分离特点分析,研究了永城无烟煤浮选细精煤脱水非均相分离过程,提出了细精煤脱水理论模型和动力学简化方程.结果表明:浮选细精煤压滤脱水具备非均相分离流体动力学作用特点,脱水速度是操作推动力、过滤介质、滤饼特性、煤浆属性及有效压密面积系数的函数,压滤过程分为过滤及压榨脱水,给出了永城无烟煤浮选细精煤过滤方程,滤饼压缩性指数s值为0.855 9,物料特性常数k为0.237 1.

  9. Evaluation of Dewatering Performance and Fractal Characteristics of Alum Sludge.

    Directory of Open Access Journals (Sweden)

    Yongjun Sun

    Full Text Available The dewatering performance and fractal characteristics of alum sludge from a drinking-water treatment plant were investigated in this study. Variations in residual turbidity of supernatant, dry solid content (DS, specific resistance to filtration (SRF, floc size, fractal dimension, and zeta potential were analyzed. Sludge dewatering efficiency was evaluated by measuring both DS and SRF. Results showed that the optimum sludge dewatering efficiency was achieved at 16 mg∙L(-1 flocculant dosage and pH 7. Under these conditions, the maximum DS was 54.6%, and the minimum SRF was 0.61 × 10(10 m∙kg(-1. Floc-size measurements demonstrated that high flocculant dosage significantly improved floc size. Correlation analysis further revealed a strong correlation between fractal dimension and floc size after flocculation. A strong correlation also existed between floc size and zeta potential, and flocculants with a higher cationic degree had a larger correlation coefficient between floc size and zeta potential. In the flocculation process, the main flocculation mechanisms involved adsorption bridging under an acidic condition, and a combination between charge neutralization and adsorption-bridging interaction under neutral and alkaline conditions.

  10. Evaluation of Dewatering Performance and Fractal Characteristics of Alum Sludge.

    Science.gov (United States)

    Sun, Yongjun; Fan, Wei; Zheng, Huaili; Zhang, Yuxin; Li, Fengting; Chen, Wei

    2015-01-01

    The dewatering performance and fractal characteristics of alum sludge from a drinking-water treatment plant were investigated in this study. Variations in residual turbidity of supernatant, dry solid content (DS), specific resistance to filtration (SRF), floc size, fractal dimension, and zeta potential were analyzed. Sludge dewatering efficiency was evaluated by measuring both DS and SRF. Results showed that the optimum sludge dewatering efficiency was achieved at 16 mg∙L(-1) flocculant dosage and pH 7. Under these conditions, the maximum DS was 54.6%, and the minimum SRF was 0.61 × 10(10) m∙kg(-1). Floc-size measurements demonstrated that high flocculant dosage significantly improved floc size. Correlation analysis further revealed a strong correlation between fractal dimension and floc size after flocculation. A strong correlation also existed between floc size and zeta potential, and flocculants with a higher cationic degree had a larger correlation coefficient between floc size and zeta potential. In the flocculation process, the main flocculation mechanisms involved adsorption bridging under an acidic condition, and a combination between charge neutralization and adsorption-bridging interaction under neutral and alkaline conditions.

  11. Evaluation of hyperbaric filtration for fine coal dewatering. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Parekh, B.K. [Univ. of Kentucky, Lexington, KY (United States); Hogg, R. [Pennsylvania State Univ., University Park, PA (United States); Fonseca, A. [CONSOL Inc. (United States)

    1996-08-15

    The main objectives of the project were to investigate the fundamental aspects of particle-liquid interaction in fine coal dewatering, to conduct laboratory and pilot plant studies on the applicability of hyperbaric filter systems and to develop process conditions for dewatering of fine clean coal to less than 20% moisture. The program consisted of three phases, namely Phase 1 -- Model Development, Phase 2 -- Laboratory Studies, Phase 3 -- Pilot Plant Testing. The Pennsylvania State University led efforts in Phase 1, the University of Kentucky in Phase 2, and CONSOL Inc. in Phase 3 of the program. All three organizations were involved in all the three phases of the program. The Pennsylvania State University developed a theoretical model for hyperbaric filtration systems, whereas the University of Kentucky conducted experimental studies to investigate fundamental aspects of particle-liquid interaction and application of high pressure filter in fine coal dewatering. The optimum filtration conditions identified in Phase 1 and 2 were tested in two of the CONSOL Inc. coal preparation plants using an Andritz Ruthner portable hyperbaric filtration unit.

  12. Low cloud properties influenced by cosmic rays

    DEFF Research Database (Denmark)

    Marsh, Nigel; Svensmark, Henrik

    2000-01-01

    The influence of solar variability on climate is currently uncertain. Recent observations have indicated a possible mechanism via the influence of solar modulated cosmic rays on global cloud cover. Surprisingly the influence of solar variability is strongest in low clouds (less than or equal to3 ......), which points to a microphysical mechanism involving aerosol formation that is enhanced by ionization due to cosmic rays. If confirmed it suggests that the average state of the heliosphere is important for climate on Earth.......The influence of solar variability on climate is currently uncertain. Recent observations have indicated a possible mechanism via the influence of solar modulated cosmic rays on global cloud cover. Surprisingly the influence of solar variability is strongest in low clouds (less than or equal to3 km...

  13. Dewatering studies of fine clean coal. Annual technical report, September 1, 1990--August 31, 1991

    Energy Technology Data Exchange (ETDEWEB)

    Parekh, B.K.

    1991-12-31

    The main objective of the present research program is to study and understand dewatering characteristics of ultrafine clean coal obtained using the advanced column flotation technique from the Kerr-McGee`s Galatia preparation plant fine coal waste stream. It is also the objective of the research program to utilize the basic study results, i.e., surface chemical, particle shape particle size distribution, etc., in developing a cost-effective dewatering method. The ultimate objective is to develop process criteria to obtain a dewatered clean coal product containing less that 20 percent moisture, using the conventional vacuum dewatering equipment. (VC)

  14. Variation properties of ionospheric eclipse factor and ionospheric influence factor

    Institute of Scientific and Technical Information of China (English)

    ZHAO Chunmei; YUAN Yunbin; OU Jikun; CHEN Jinping

    2005-01-01

    The concepts and calculation methods of ionospheric eclipse factor (IEF) and ionospheric influence factor (IFF) are further illustrated. The temporal and spacial variation properties of IEF and IFF are studied, which shows that the properties are influenced by the geographic position and season. The possibility of improving the precision of using GPS data to determine ionospheric delay based on the above variation properties is also analysed.

  15. Low cloud properties influenced by cosmic rays

    CERN Document Server

    Marsh, N D; Marsh, Nigel D; Svensmark, Henrik

    2000-01-01

    The influence of solar variability on climate is currently uncertain. Recent observations have indicated a possible mechanism via the influence of solar modulated cosmic rays on global cloud cover. Here we show that the influence of solar variability is strongest in low clouds (<= 3.2km). These are liquid water clouds which points to a microphysical mechanism involving enhanced aerosol formation. If confirmed it suggests that the average state of the Heliosphere is important for climate on Earth. The estimated response in low clouds due to a doubling of solar activity is a 1.4 W/m2 warming.

  16. Parallel studies on dewatering and conditioning of an alum sludge and an aluminium hydroxide suspension.

    Science.gov (United States)

    Papavasilopoulos, E N; Bache, D H

    2001-01-01

    The paper shows a comparison between properties of an alum sludge gained from the coagulation of a coloured water with those of a suspension of aluminium hydroxide at a concentration equivalent to the coagulant fraction within the sludge. Background information is provided on composition and aspects of the source floc. The comparisons embraced floc size, polymer adsorption, and dewatering parameters including specific resistance to filtration, capillary suction time and the equilibrium moisture content under pressure. In all cases, there were strong similarities in the behaviour of the two suspensions. It is suggested that such features emanate from a common fractal structure within the source floc, whose fractal index (approximately/= 1) has been found to be insensitive to the composition of the floc.

  17. Electrical field: a historical review of its application and contributions in wastewater sludge dewatering.

    Science.gov (United States)

    Mahmoud, Akrama; Olivier, Jérémy; Vaxelaire, Jean; Hoadley, Andrew F A

    2010-04-01

    Electric field-assisted dewatering, also called electro-dewatering, is a technology in which a conventional dewatering mechanism such a pressure dewatering is combined with electrokinetic effects to realize an improved liquid/solids separation, to increase the final dry solids content and to accelerate the dewatering process with low energy consumption compared to thermal drying. Electro-dewatering is not a new idea, but the practical industrial applications have been limited to niche areas in soil mechanics, civil engineering, and the ceramics industry. Recently, it has received great attention, specially, in the fields of fine-particle sludge, gelatinous sludge, sewage sludge, pharmaceutical industries, food waste and bull kelp, which could not be successfully dewatered with conventional mechanical methods. This review focuses on the scientific and practical aspects of the application of an electrical field in laboratory/industrial dewatering, and discusses this in relation to conventional dewatering techniques. A comprehensive bibliography of research in the electro-dewatering of wastewater sludges is included. As the fine-particle suspensions possess a surface charge, usually negative, they are surrounded by a layer with a higher density of positive charges, the electric double layer. When an electric field is applied, the usually negative charged particles move towards the electrode of the opposite charge. The water, commonly with cations, is driven towards the negative electrode. Electro-dewatering thus involves the well-known phenomena of electrophoresis, electro-osmosis, and electromigration. Following a detailed outline of the role of the electric double layer and electrokinetic phenomena, an analysis of the components of applied voltage and their significance is presented from an electrochemical viewpoint. The aim of this elementary analysis is to provide a fundamental understanding of the different process variables and configurations in order to

  18. Modeling of hyperbaric filtration and dewatering of coal

    Science.gov (United States)

    Ranjan, Sushil

    Generalized models have been developed for continuous hyperbaric filtration to evaluate cake formation, filter capacity/filter area, cake dewatering, air consumption and residual cake saturation/residual cake moisture. Emphasis has been placed on cake structure as being a major controlling factor in fine coal dewatering by filtration. The effects of cake structure, as defined by the distributions of pore size and shape, have been reviewed. A simple model relating cake structure to feed particle characteristics is presented and applied to a practical case of fine coal dewatering. A binary packing model has been proposed to explain the existence of compressibility in non-compressible cakes. This model proposes an inner open-structure in the main cake, with the inner layer being compressible. The variation in the inner cake porosity with applied pressure has been used to explain the change in specific cake resistance and filter capacity (solids cake throughput). Process simulations have been conducted for a single stage and a two stage process, wherein the original feed has been split into a coarse fraction and a fine fraction (and then each fraction processed separately). The process simulations for a two stage process show a lot of promise as this leads to a lowering of the required filter area and the residual cake moisture. The required filter area increases, while the residual cake moisture decreases as the cut size for the two stage process is increased. However, the advantages of a two stage process are adversely affected by an inefficient separation process, which leads to an increased filter area and a higher residual cake moisture and the two stage process approaches a single stage process.

  19. Locally produced natural conditioners for dewatering of faecal sludge

    Science.gov (United States)

    Gold, Moritz; Dayer, Pauline; Faye, Marie Christine Amie Sene; Clair, Guillaume; Seck, Alsane; Niang, Seydou; Morgenroth, Eberhard; Strande, Linda

    2016-01-01

    ABSTRACT In urban areas of low-income countries, treatment of faecal sludge (FS) is insufficient or non-existent. This results in large amounts of FS being dumped into the environment. Existing treatment technologies for FS, such as settling-thickening tanks and drying beds, are land intensive which is limiting in urban areas. Enhanced settling and dewatering by conditioning was evaluated in order to reduce the treatment footprint (or increase treatment capacity). Conventional wastewater conditioners, such as commercially available lime and polymers, are expensive, and commonly rely on complex supply chains for use in low-income countries. Therefore, the treatment performance of five conditioners which could be produced locally was evaluated: Moringa oleifera seeds and press cake, Jatropha curcas seeds, Jatropha Calotropis leaves and chitosan. M. oleifera seeds and press cake, and chitosan improved settling and dewatering and had a similar performance compared to lime and polymers. Optimal dosages were 400–500 kg M. oleifera/t TS, 300–800 kg lime/t TS and 25–50 kg polymer solution/t TS. In comparison, chitosan required 1.5–3.75 kg/t TS. These dosages are comparable to those recommended for wastewater (sludge). The results indicate that conditioning of FS can reduce total suspended solids (TSS) in the effluent of settling-thickening tanks by 22–81% and reduce dewatering time with drying beds by 59–97%. This means that the area of drying beds could be reduced by 59–97% with end-use as soil conditioner, or 9–26% as solid fuel. Least expensive options and availability will depend on the local context. In Dakar, Senegal, chitosan produced from shrimp waste appears to be most promising. PMID:26984372

  20. New coal dewatering technology turns sludge to powder

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2009-03-15

    Virginian Tech's College of Engineering's Roe-Hoan Yoon and his group have developed a hyperbaric centrifuge that can dewater coal as fine as talcum powder. Such coal fines presently must be discarded by even the most advanced coal cleaning plants because of their high moisture content. The new technology can be used with the Microcel technology to remove ash, to re-mine the fine coal discarded to impoundments and to help minimize waste generation. Virginia Tech has received $1 million in funding from the US Department of State to also help the Indian coal industry produce a cleaner product. 1 photo.

  1. 46 CFR 28.255 - Bilge pumps, bilge piping, and dewatering systems.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 1 2010-10-01 2010-10-01 false Bilge pumps, bilge piping, and dewatering systems. 28... the Aleutian Trade § 28.255 Bilge pumps, bilge piping, and dewatering systems. (a) Each vessel must be equipped with a bilge pump and bilge piping capable of draining any watertight compartment, other...

  2. Thermal properties of African yam bean seeds as influenced by ...

    African Journals Online (AJOL)

    Thermal properties of African yam bean seeds as influenced by moisture content and temperature. ... Nigerian Food Journal ... of the seeds determined using the American Society Agriculture Engineering Standard (ASAE) test was 9.6 % (d.b).

  3. STUDY OF THE DIGESTED SLUDGE DEWATERING EFFECTIVENESS USING POLYELECTROLYTE GEL BASED ON ORGANIC POLYMERS

    Directory of Open Access Journals (Sweden)

    Marcin Głodniok

    2016-02-01

    Full Text Available The paper addresses the problems connected with sewage sludge dewatering. The premise of the study was the analysis of whether there are opportunities to increase the efficiency of dewatering sludge, a relatively low-cost involving the use of innovative polymers. The authors analyzed the impact of the new type of polyelectrolyte gel on the effectiveness of dewatering sludge. Laboratory studies were carried out at polyelectrolyte dose selection and laboratory testing on the press chamber designed to simulate the actual operation of sludge dewatering system. Two different doses of polyelectrolyte were tested for dose I – 4 ml/m3 and dose II – 8 ml/m3. The conducted analysis on laboratory press showed an increase of sludge dewatering efficiency by about 2% for dose no. I and by about 13% for dose no. II, in comparison to the test without polyelectrolyte.

  4. Development of an Ultra-fine Coal Dewatering Technology and an Integrated Flotation-Dewatering System for Coal Preparation Plants

    Energy Technology Data Exchange (ETDEWEB)

    Wu Zhang; David Yang; Amar Amarnath; Iftikhar Huq; Scott O' Brien; Jim Williams

    2006-12-22

    The project proposal was approved for only the phase I period. The goal for this Phase I project was to develop an industrial model that can perform continuous and efficient dewatering of fine coal slurries of the previous flotation process to fine coal cake of {approx}15% water content from 50-70%. The feasibility of this model should be demonstrated experimentally using a lab scale setup. The Phase I project was originally for one year, from May 2005 to May 2006. With DOE approval, the project was extended to Dec. 2006 without additional cost from DOE to accomplish the work. Water has been used in mining for a number of purposes such as a carrier, washing liquid, dust-catching media, fire-retardation media, temperature-control media, and solvent. When coal is cleaned in wet-processing circuits, waste streams containing water, fine coal, and noncombustible particles (ash-forming minerals) are produced. In many coal preparation plants, the fine waste stream is fed into a series of selection processes where fine coal particles are recovered from the mixture to form diluted coal fine slurries. A dewatering process is then needed to reduce the water content to about 15%-20% so that the product is marketable. However, in the dewatering process currently used in coal preparation plants, coal fines smaller than 45 micrometers are lost, and in many other plants, coal fines up to 100 micrometers are also wasted. These not-recovered coal fines are mixed with water and mineral particles of the similar particle size range and discharged to impoundment. The wasted water from coal preparation plants containing unrecoverable coal fine and mineral particles are called tailings. With time the amount of wastewater accumulates occupying vast land space while it appears as threat to the environment. This project developed a special extruder and demonstrated its application in solid-liquid separation of coal slurry, tailings containing coal fines mostly less than 50 micron. The

  5. Influencing of pollution on power properties of hydrocarbonaceous fuel

    OpenAIRE

    О.Л. Матвєєва; І.А. Кравець

    2004-01-01

     The result investigation of influencing of a dispersion pollution of hydrocarbonaceous fuel on its power condition are reviewed. The intensity of change of a surface of a contact of a disperse phase is determined at splitting mechanical pollution in fuel. Is shown, that the process of pollution negatively influences power properties of fuel.

  6. Characteristics of dewatering induced drawdown curve under blocking effect of retaining wall in aquifer

    Science.gov (United States)

    Wu, Yong-Xia; Shen, Shui-Long; Yuan, Da-Jun

    2016-08-01

    For deep excavation pits that require the pumping of confined groundwater, a combination of a retaining wall and dewatering with large-diameter wells is usually adopted during excavation to improve safety. Since a retaining wall has a much lower hydraulic conductivity than the surrounding material in the aquifer, blocking of seepage to prolong the seepage path of the groundwater outside of the pit is effective. The retaining walls used during excavation dewatering cause hydraulic head drawdown inside the pit much faster than outside the pit. Thus, difference in hydraulic head between inside and outside of the pit increases. To investigate the mechanism of the blocking effect, numerical simulation using the finite difference method (FDM) was conducted to analyze the effects of pumping in the pit. The FDM results show that drawdown varies along the depth of the confined aquifer. The influence factors of drawdown inside and outside the pit include insertion depth of retaining walls, anisotropy of a confined aquifer and screen length of pumping wells. In addition, FDM results also show that the drawdown-time curve can be divided into four stages: in Stage I, drawdown inside the pit is very small and outside the pit it is almost zero; in Stage II, drawdown increases quickly with time; in Stage III, the drawdown curve is parallel to the Cooper-Jacob curve on semi-log axes; and in Stage IV, the drawdown becomes constant. These characteristics of the drawdown curve under the blocking effect of a retaining wall in an aquifer provide a way of estimating hydrogeological parameters according to pumping test results.

  7. Pervaporation applied for dewatering of reaction mixture during esterification

    Directory of Open Access Journals (Sweden)

    Krasiński Andrzej

    2016-03-01

    Full Text Available In this work the esterification of diethyl tartrate was studied. The research was focused on the enhancement of reversible reaction yield, which is accomplished by dewatering of the reaction mixture. The removal of water shifts the equilibrium towards the main product. Pervaporation was applied for this purpose, and results were compared to distillation. The advantages and limitations of both processes are discussed. The experimental part consists of dewatering of mixture after the reaction had reached the equilibrium, and was subsequently fed to the test rig equipped with a single zeolite membrane purchased from Pervatech B.V. Results show a significant conversion increase as a result of water removal by pervaporation. Compared to distillation no addition of organics is necessary to efficiently remove water above the azeotrope. Nevertheless, some limitations and issues which call for optimisation are pointed out. A simple numerical model is proposed to support design and sizing of the pervaporation system. Various modes of integrated system operation are also briefly discussed.

  8. Application of forward osmosis on dewatering of high nutrient sludge.

    Science.gov (United States)

    Nguyen, Nguyen Cong; Chen, Shiao-Shing; Yang, Hung-Yin; Hau, Nguyen Thi

    2013-03-01

    A novel approach was designed to simultaneously apply low energy sludge dewatering and nutrient removal for activated sludge using forward osmosis (FO). In this study, the municipal wastewater sludge was spiked with different nutrient concentrations to evaluate FO dewatering performance. The results showed that sludge concentration reached 21,511 and 28,500mg/L after 28h from initial sludge concentration of 3000 and 8000mg/L with flow rate of 150mL/min. Moreover, nutrient and organic compounds in sludge solution were also successfully removed (around 96% of NH4(+)-N, 98% of PO4(3-)-P and 99% of dissolved organic carbon (DOC)) due to steric effect of FO membrane and multi barrier layer of sludge forming on membrane surface. Furthermore, the analysis from Scanning Electron Microscopy & Energy Dispersive X-ray Spectroscopy (SEM-EDS) images recorded that FO membrane was fouled by cake layer of sludge in the active layer and NaCl in the support layer.

  9. Improvement Measures of Stope Filling Dewatering Process in Sanshandao Gold Mine%三山岛金矿采场充填脱水工艺改进措施

    Institute of Scientific and Technical Information of China (English)

    颜丙乾; 杨鹏; 吕文生

    2015-01-01

    采场充填脱水效果对充填体初凝时间及其短期和长期强度产生较大影响,三山岛金矿采用溢流管溢流脱水和充填挡墙的土工布渗透脱水,脱水效率不能满足现场工作要求。为此,在充填脱水理论研究的基础上,分析了影响充填脱水速度的主要因素,提出了多项充填脱水改进措施。增设竖直或倾斜的脱水管,更有效地排出充填采场中的重力水,同时避免充填料浆中细粒级颗粒堵塞脱水管。改进充填挡墙设计和滤水布的选取,避免细粒级颗粒短时间内聚集在滤水布附近,影响渗透脱水效果。设计充填管道滤水器,在充填料浆进入采空区前,过滤充填料浆中的部分自由水,提高了充填采场中料浆的浓度,减小了采场充填脱水工作量。改变矿山简单脱水方式,进一步提高采场充填脱水效率,避免影响下一步开采工作的顺利开展。%The dewatering of stope filling has a greater impact on the initial setting time of the filling body and its short-term and long-term strength. The overflow dewatering was used in Sanshandao Gold Mine by overflow tube,and penetration de-watering was used by filling retaining geotextile,but the dewatering efficiency can not meet the requirements of field work. The main influence factors of the filling dewatering rate was analyzed on the basis of theoretical research on the filling dewatering, and many improvement measures of filling dewatering are put forward. Additional vertical or inclined dewatering tubes can be used to discharge the filling gravity water more efficiently,meanwhile avoid dewatering tube clogged by the fine-sized particles in filling slurry. The improved design of filling retaining wall and selection of treatment cloth can avoid the fine-sized particles gathered near the water treatment cloth in short time which can affect penetration dewatering. The water filter of filling tube was designed to filter

  10. Feasibility study of green wastes composting with digested and dewatering sludge from municipal wastewater treatment plant in Iran

    Directory of Open Access Journals (Sweden)

    Neamat Jaafarzadeh Haghighi Fard

    2015-09-01

    Full Text Available Background: Composting as a waste management technology is becoming more widespread. The purpose of this study was to assess the feasibility and to find the most effective composting process for the ratio of green waste, digested and dewatered sludge from Chonibieh wastewater treatment plant in the west region of Ahvaz. Methods: The composting time was 23 days and the evaluated parameters in this period of the study were organic carbon, total nitrogen, phosphorus, carbon to nitrogen ratio (C/N, moisture content and pH. The C/N ratio was maintained at 30 with weight:weight ratio of 1:1, 1:2, 1:3 (digested and dewatered sludge to green waste. Results: It was observed that vessel R3 produced higher quality of compost with final total nitrogen (1.28%, final total phosphorus (0.71%, final total organic carbon (TOC (25.78% and C/N (20.65% within the 23 days of composting. While vessel R1 produced higher final total nitrogen and total phosphorus with lower amount of total coliform indicating suitable quality of composting. Therefore, the results showed that the characteristics of dewatered sludge mixed with green waste proportion of green waste significantly influenced the compost quality and process dynamics. The results also showed that the quality of final products in all the conditions was in agreement with Global Organic Textile Standard (GOTS and World Health Organization (WHO guidelines. However, the moisture content ratios were lower than the mentioned guidelines. With regards to microbial quality, all three ratios were in agreement with US Environmental Protection Agency (EPA and Iranian guidelines. Conclusion: It is suggested that the final product of composting can be safely used in farmland and green space.

  11. Intelligent Risk Assessment for Dewatering of Metro-Tunnel Deep Excavations

    Directory of Open Access Journals (Sweden)

    X. W. Ye

    2012-01-01

    Full Text Available In recent years, China has been undergoing a metro railway construction boom in order to alleviate the urban traffic congestion problem resulting from the rapid urbanization and population growth in many metropolises. In the construction of metro systems, deep excavations and continuous dewatering for construction of the metro tunnels and stations remain a challenging and high risk task in densely populated urban areas. Intelligent computational methods and techniques have exhibited the exceptional talent in dealing with the complicated problems inherent in the deep excavation and dewatering practice. In this paper, an intelligent risk assessment system for deep excavation dewatering is developed and has been applied in the project of Hangzhou Metro Line 1 which is the first metro line of the urban rapid rail transit system in Hangzhou, China. The specific characteristics and great challenges in deep excavation dewatering of the metro-tunnel airshaft of Hangzhou Metro Line 1 are addressed. A novel design method based on the coupled three-dimensional flow theory for dewatering of the deep excavation is introduced. The modularly designed system for excavation dewatering risk assessment is described, and the field observations in dewatering risk assessment of the airshaft excavation of Hangzhou Metro Line 1 are also presented.

  12. POC-scale testing of an advanced fine coal dewatering equipment/technique

    Energy Technology Data Exchange (ETDEWEB)

    Groppo, J.G.; Parekh, B.K. [Univ. of Kentucky, Lexington, KY (United States); Rawls, P. [Department of Energy, Pittsburgh, PA (United States)

    1995-11-01

    Froth flotation technique is an effective and efficient process for recovering of ultra-fine (minus 74 {mu}m) clean coal. Economical dewatering of an ultra-fine clean coal product to a 20 percent level moisture will be an important step in successful implementation of the advanced cleaning processes. This project is a step in the Department of Energy`s program to show that ultra-clean coal could be effectively dewatered to 20 percent or lower moisture using either conventional or advanced dewatering techniques. As the contract title suggests, the main focus of the program is on proof-of-concept testing of a dewatering technique for a fine clean coal product. The coal industry is reluctant to use the advanced fine coal recovery technology due to the non-availability of an economical dewatering process. in fact, in a recent survey conducted by U.S. DOE and Battelle, dewatering of fine clean coal was identified as the number one priority for the coal industry. This project will attempt to demonstrate an efficient and economic fine clean coal slurry dewatering process.

  13. Macroinvertebrate community responses to a dewatering disturbance gradient in a restored stream

    Directory of Open Access Journals (Sweden)

    J. D. Muehlbauer

    2010-12-01

    Full Text Available Dewatering disturbances are common in aquatic systems and represent a relatively untapped field of disturbance ecology, yet studying dewatering events along gradients in non-dichotomous (i.e., wet/dry terms is often difficult. Because many stream restorations can essentially be perceived as planned hydrologic manipulations, such systems can make ideal test-cases for understanding processes of hydrological disturbance. In this study we used an experimental drawdown in a 440 ha stream/wetland restoration site to assess aquatic macroinvertebrate community responses to dewatering and subsequent rewetting. The geomorphic nature of the site and the design of the restoration allowed dewatering to occur predictably along a gradient and decoupled the hydrologic response from any geomorphic (i.e., habitat heterogeneity effects. In the absence of such heterogeneous habitat refugia, reach-scale wetted perimeter and depth conditions exerted a strong control on community structure. The community exhibited an incremental response to dewatering severity over the course of this disturbance, which was made manifest not as a change in community means but as an increase in community variability, or dispersion, at each site. The dewatering also affected inter-species abundance and distributional patterns, as dewatering and rewetting promoted alternate species groups with divergent habitat tolerances. Finally, our results indicate that rapid rewetting – analogous to a hurricane breaking a summer drought – may represent a recovery process rather than an additional disturbance and that such processes, even in newly restored systems, may be rapid.

  14. Macroinvertebrate community responses to a dewatering disturbance gradient in a restored stream

    Directory of Open Access Journals (Sweden)

    J. D. Muehlbauer

    2011-06-01

    Full Text Available Dewatering disturbances are common in aquatic systems and represent a relatively untapped field of disturbance ecology, yet studying dewatering events along gradients in non-dichotomous (i.e. wet/dry terms is often difficult. Because many stream restorations can essentially be perceived as planned hydrologic manipulations, such systems can make ideal test-cases for understanding processes of hydrological disturbance. In this study we used an experimental drawdown in a 440 ha stream/wetland restoration site to assess aquatic macroinvertebrate community responses to dewatering and subsequent rewetting. The geomorphic nature of the site and the design of the restoration allowed dewatering to occur predictably along a gradient and decoupled the hydrologic response from any geomorphic (i.e. habitat heterogeneity effects. In the absence of such heterogeneous habitat refugia, reach-scale wetted perimeter and depth conditions exerted a strong control on community structure. The community exhibited an incremental response to dewatering severity over the course of this disturbance, which was made manifest not as a change in community means but as an increase in community variability, or dispersion, at each site. The dewatering also affected inter-species abundance and distributional patterns, as dewatering and rewetting promoted alternate species groups with divergent habitat tolerances. Finally, our results indicate that rapid rewetting – analogous to a hurricane breaking a summer drought – may represent a recovery process rather than an additional disturbance and that such processes, even in newly restored systems, may be rapid.

  15. The influence of the nanostructure geometry on the thermoelectric properties

    Science.gov (United States)

    AL-Badry, Lafy F.

    2016-09-01

    We discuss the influence of nanostructure geometry on the thermoelectric properties in quantum ring consists of one QD in each arm, each QD connects with side QD. The calculations are based on the time-dependent Hamiltonian model, the steady state is considered to obtain an analytical expression for the transmission probability as a function of system energies. We employed the transmission probability to calculate the thermoelectric properties. We investigate thermoelectric properties through three configurations of this nanostructure. Figure of merit enhanced in configuration (II) when side QD connected to upper arm of quantum ring. The magnetic flux threads quantum ring. The effect of magnetic flux on the thermoelectric properties is examined.

  16. IN718 Additive Manufacturing Properties and Influences

    Science.gov (United States)

    Lambert, Dennis M.

    2015-01-01

    The results of tensile, fracture, and fatigue testing of IN718 coupons produced using the selective laser melting (SLM) additive manufacturing technique are presented. The data have been "sanitized" to remove the numerical values, although certain references to material standards are provided. This document provides some knowledge of the effect of variation of controlled build parameters used in the SLM process, a snapshot of the capabilities of SLM in industry at present, and shares some of the lessons learned along the way. For the build parameter characterization, the parameters were varied over a range that was centered about the machine manufacturer's recommended value, and in each case they were varied individually, although some co-variance of those parameters would be expected. Tensile, fracture, and high-cycle fatigue properties equivalent to wrought IN718 are achievable with SLM-produced IN718. Build and post-build processes need to be determined and then controlled to established limits to accomplish this. It is recommended that a multi-variable evaluation, e.g., design-of experiment (DOE), of the build parameters be performed to better evaluate the co-variance of the parameters.

  17. Influence of alumina characteristics on glaze properties

    Directory of Open Access Journals (Sweden)

    Arrufat, S.

    2010-10-01

    Full Text Available Aluminium oxide is a synthetic raw material manufactured from bauxite by the Bayer process, whose Al2O3 content typically exceeds 99%. Four main types of alumina can be defined, depending on the processing used: hydrargillite Al(OH3, boehmite AlOOH, transition aluminas (calcined at low temperatures, 1000 °C, with an intermediary crystallographic structure between hydrates and alpha alumina, and α-Al2O3 (calcined at high temperatures, >1100 °C. In glaze manufacturing, α-Al2O3 is the main type of alumina used. This raw material acts as a matting agent: the matt effect depends on alumina particle size and content in the glaze. This study examines the effect of the degree of alumina calcination on glaze technical and aesthetic properties. For this purpose, aluminas with different degrees of calcination were added to a glaze formulated with a transparent frit and kaolin, in order to simplify the system to be studied. The results show that, depending on the degree of calcination, alumina particles can react with the glaze components (SiO2, CaO, and ZnO to form new crystalline phases (anorthite and gahnite. Both crystallisations extract CaO and ZnO from the glassy phase, increasing glassy phase viscosity. The variation in crystalline phases and glassy phase viscosity yields glazes with different technical and aesthetic properties.

    El óxido de aluminio es una materia prima sintética fabricada a partir de la bauxita por medio del proceso Bayer, cuyo contenido de Al2O3 supera, por regla general, el 99%. Se pueden definir cuatro tipos de alúmina, en función del tipo de proceso usado: hidrargilita Al(OH3, boehmita AlOOH, alúminas de transición (calcinadas a bajas temperaturas, 1000 °C, con una estructura cristalográfica intermedia entre los hidratos y la alfa alúmina, y la α-Al2O3 (calcinada a

  18. Influence of Superhydrophobic Properties on Deicing

    Science.gov (United States)

    Nazhipkyzy, M.; Mansurov, Z. A.; Amirfazli, A.; Esbosin, A.; Temirgaliyeva, T. S.; Lesbayev, B. T.; Aliyev, E. T.; Prikhodko, N. G.

    2016-11-01

    Nowadays the creation of anti-icing, or deicing, surfaces is one of the most important problems, as such surfaces are widely used in aeronautics, wind turbines, and telecommunication antennas. In this paper, we focus mainly on reducing the ice adhesion forces and easy ice removal, once ice has formed. Removal of a liquid from a surface can be provided by modification of the surface wettability by means of applying superhydrophobic coatings. Such coatings are water-resistant, i.e., are characterized by low water adhesion forces. To study the impact of superhydrophobic coatings, tests were performed on the surface of a wing in a wind tunnel. By spraying Teflon and polyphenylene sulfide (PPS) on the wing, we obtained a superhydrophobic film. This film has a structure that provides superhydrophobic properties, so that the wetting angle is above 140°. A comparison of the resulting surface with a clean Teflon one shows that adhesion of the Teflon + PPS mixture to an aluminum surface is five times higher. We also investigate the degree of ice formation on the surfaces of simple and superhydrophobic aircraft wings at a temperature of -18°C. It was shown that ice was formed on a simple wing within 40 s and on a superhydrophobic wing within 25 s. When the simple wing with a mass of 23 g was inserted into the wind tunnel, its mass reached 50 g, and for a superhydrophobic wing with a mass of 26 g the latter reached 42 g. The sample of the airfoil wing we prepared has a low adhesion, which helps in easy ice removal.

  19. Upgrading of brown coal by slurry-dewatering; Kattan no yuchu dassui ni yoru clean kotai nenryo no seizo

    Energy Technology Data Exchange (ETDEWEB)

    Okuma, O.; Shimizu, T.; Inoue, T.; Shigehisa, T.; Deguchi, T.; Katsushima, S. [Kobe Steel, Ltd., Kobe (Japan)

    1996-10-28

    This paper describes an outline of solid fuel production process from brown coal and the investigation results of its elemental techniques. Dried coal is produced by this process which consists of a dewatering of crushed brown coal in oil-based solvent, a solid and liquid separation of slurry, and a remained oil recovery by heating. This process is characterized by the higher thermal efficiency compared with usual drying and the restraint of spontaneous combustion of product coal. It was revealed that solid fuel with low moisture, low ash, low sulfur, and suppressed spontaneous combustion property can be produced from Australian brown coal through this process. From the comparison between kerosene and fuel oil A, it was confirmed that the oil content during dewatering was smaller and the oil recovery by heating was easier by using a solvent with lower boiling point. It was also confirmed that the spontaneous combustion property can be suppressed using small amount of asphalt by solving asphalt in the solvent and adsorbing asphalt on the surface of brown coal. From these results, low rank coals including brown coal, which are difficult to use, are expected to be used as clean coal with low ash and low sulfur through this process. 2 refs., 7 figs., 2 tabs.

  20. Using of Fine Particle to Improvement of Sludge Dewater Ability

    Directory of Open Access Journals (Sweden)

    Abdullah I. Ibrahem

    2013-04-01

    Full Text Available The main objective of this study is to compare the performance of three alternative materials used to improve dewatering of sludge produced from secondary settling tank of Mosul medical city wastewater treatment plant, those materials are Kaolin, Limestone and Clay stone.Six dry weight percentages for each alternative are used (2, 4, 6, 8, 10, 12 % from dry weight of sludge. The specific resistance to filtration (SRF was used as a criterion to compare the studied materials. Experimental results showed that SRF is 4.1×1012, 5.9×1012, 5.8×1012 m/kg when 8% additional dose were used for each of Kaolin, Limestone and Clay stone respectively, this study showed that the best alternative material studied is kaolin which achieve decreasing efficiency in SRF more than 70%.     

  1. Biosynthesised magnetic iron nanoparticles for sludge dewatering via Fenton process.

    Science.gov (United States)

    Ealias, Anu Mary; Jose, Jephin Varughese; Saravanakumar, M P

    2016-11-01

    The magnetic iron nanoparticles (MFeNp) were biosynthesised using the extract of Cinnamomum tamala (bay leaf) and examined for its efficacy on sludge dewatering. The characteristics of MFeNp were studied using scanning electron microscope (SEM), transmission electron microscopy (TEM), x-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and x-ray photoelectron spectrometer (XPS) techniques. The presence of polyphenolic compounds were confirmed by FTIR and XPS analysis. The reduction in capillary suction time (CST) (71.36 to 16.5 s) and specific resistance to filtration (SRF) (53.71 × 10(11) to 1.47 × 10(11) m/kg) values have indicated that the use of Fenton nanocatalyst enhanced the sludge dewaterability. The differential scanning calorimetry (DSC) analysis has shown that the mass of bound water in the treated sludge was decreased significantly from 1.45 to 0.92 kg H2O/kg DS. The breakdown of extracellular polymeric substances (EPS) by the MFeNp leads to the significant reduction in proteins, polysaccharides, water content and heavy metals. The optimisation using response surface modelling (RSM) have shown that the maximum removal efficiency of water from the sludge was 85.9 % when the optimum pH (3) MFeNp dosage (50 mg/g DS) and H2O2 dosage (500 mg/g DS) were maintained. The experimental results and the statistical optimisation have suggested that MFeNp can be used as a potential nanocatalyst for the sludge dewaterability and hence it can be used for the agricultural purpose. Graphical abstract Schematic representation of sludge dewatering process.

  2. The influence of the sterilisation process on certain thermal properties.

    Science.gov (United States)

    Issa, Manal; Abreu, Maria Jose; Schacher, Laurence; Adolphe, Dominique; Cabeco Silva, Maria Elisabete

    2004-09-01

    Surgical clothing and sheets have to meet all the requirements set in the health-care industry regarding body comfort, absorption capacity and general recognition of physiological safety and sterilisation capacity. The disposable surgical gown market is growing and the demand will increase in all product groups and market sectors, where the health care industry is the most dynamic growth area. The aim of this study was to analyse some of the thermal properties of disposable surgical gowns before and after different sterilisation methods, and therefore the influence of the sterilisation process on their thermal comfort. The apparatus used to measure heat transfer properties was the Thermo Labo device (KES FB7) which evaluates the cool/warm sensation, thermal conductivity and insulation properties of the test item. The results obtained highlight the influence of the sterilisation process on the thermal and comfort properties.

  3. Monitoring and troubleshooting of non-filamentous settling and dewatering problems in an industrial activated sludge treatment plant

    DEFF Research Database (Denmark)

    Kjellerup, B. V.; Keiding, Kristian; Nielsen, Per Halkjær

    2001-01-01

    A large industrial activated sludge wastewater treatment plant had temporary problems with settling and dewatering of the sludge. Microscopical investigations revealed that the poor settling properties were not due to presence of filamentous bacteria, but poor floc properties. In order...... at this industrial plant. The described strategy can be useful in general to find and solve many solid/liquid separation problems in activated sludge wastewater treatment plants....... had started after summer closedown. Possible reasons for the changes in floc properties in the process tanks were found by a) analysing change in wastewater composition by evaluating the different production lines in the industrial plant, b) evaluating the operation of the plant, and c) performing...

  4. Air Pressure-Assisted Centrifugal Dewatering of Concentrated Fine Sulfide Particles

    Directory of Open Access Journals (Sweden)

    R. Asmatulu

    2011-01-01

    Full Text Available An air pressure-assisted centrifugal dewatering method was developed and used for the dewatering of concentrated finesulfide particles, such as sphalerite, galena, and chalcopyrite. This filtration method was mainly designed to increase the filtration rate during the drainage cycle and, hence, produce drier filter cakes, which in turn could reduce the cost and emission problems/concerns of thermal dryers in the preparation plants. Several dewatering parameters, including applied pressure, centrifugal force (G-force, spin time, cake thickness, and surface hydrophobization, were tested to optimize the processing conditions. Test results showed that, at higher air pressure and centrifugal force, the cake moisture reduction was more than 70%, depending on the testing conditions. As a result, it can be-concluded that the novel filtration method effectively works on the dewatering of fine particles (–150 μm.

  5. Evaluation of geotextile filtration applying coagulant and flocculant amendments for aquaculture biosolids dewatering and phosphorus removal

    Science.gov (United States)

    Wastes contained in the microscreen backwash discharged from intensive recirculating aquaculture systems were removed and dewatered in simple geotextile bag filters. Three chemical coagulation aids, (aluminum sulfate (alum), ferric chloride, and calcium hydroxide (hydrated lime)), were tested in com...

  6. Study on Deep Well Dewatering Optimization Design in Deep Foundation Pit and Engineering Application

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    Based on analyses of the theories of groundwater unsteady flow in deep well dewatering in the deep foundation pit, Theis equations are chosen to calculate and analyze the relationship between water level drawdown of confined aquifer and dewatering duration. In order to reduce engineering cost and diminish detrimental effect on ambient surrounding, optimization design target function based on the control of confined water drawdown and four restriction requisitions based on the control of safe water level, resistance to throwing up from the bottom of foundation pit, avoiding excessively great subsidence and unequal surface subsidence are proposed. A deep well dewatering project in the deep foundation pit is optimally designed. The calculated results including confined water level drawdown and surface subsidence are in close agreement with the measured results, and the optimization design can effectively control both surface subsidence outside foundation pit and unequal subsidence as a result of dewatering.

  7. Management of dewatering areas for waterfowl: A situation assessment and long-range plan: Executive summary

    Data.gov (United States)

    US Fish and Wildlife Service, Department of the Interior — This document discusses strategic actions required to retain and secure increased wildlife benefits from dewatering units on Wheeler National Wildlife Refuge and...

  8. Integrated treatment of municipal sewage sludge by deep dewatering and anaerobic fermentation for biohydrogen production.

    Science.gov (United States)

    Yu, Li; Yu, Yang; Jiang, Wentian; Wei, Huangzhao; Sun, Chenglin

    2015-02-01

    The increasing sludge generated in wastewater treatment plants poses a threat to the environment. Based on the traditional processes, sludge dewatered by usual methods was further dewatered by hydraulic compression and the filtrate released was treated by anaerobic fermentation. The difficulties in sludge dewatering were associated with the existence of sludge flocs or colloidal materials. A suitable CaO dosage of 125 mg/g dry sludge (DS) could further decrease the moisture content of sludge from 82.4 to 50.9 %. The filtrate from the dewatering procedure was a potential substrate for biohydrogen production. Adding zero-valent iron (ZVI) into the anaerobic system improved the biohydrogen yield by 20 %, and the COD removal rate was lifted by 10 % as well. Meanwhile, the sludge morphology and microbial community were altered. The novel method could greatly reduce the sludge volume and successfully treated filtrate along with the conversion of organics into biohydrogen.

  9. Decolorization and biodegradation of the Congo red by Acinetobacter baumannii YNWH 226 and its polymer production's flocculation and dewatering potential.

    Science.gov (United States)

    Li, Ruijing; Ning, Xun-an; Sun, Jian; Wang, Yujie; Liang, Jieying; Lin, Meiqing; Zhang, Yaping

    2015-10-01

    The strain Acinetobacter baumannii YNWH 226 was utilized to degrade Congo red (CR) under aerobic conditions. CR was employed as the sole carbon source to produce extracellular polymeric substances (EPS) used as potent bioflocculants in this strain. A total of 98.62% CR was removed during the 48-h decoloration experiments using CR (100 mg/L). A total of 83% bioadsorption and 65% biodegradation were responsible for the decoloration and degradation of CR through the strain. The bioflocculant showed high flocculation activity and dewaterability on textile dyeing sludge. A maximum flocculation of 78.62% with a minimum SBF of 3.07×10(9) s(2)/g and a CST of 58.4 s were achieved. We investigated the internal relationship between the decolorization efficiency of YNWH 226 and the flocculation activity and dewatering capacity of its EPS. The components and structure of the EPS highly influenced the decolorization efficiency of CR and the flocculation activity and dewatering capacity on sludge.

  10. Influence of membrane properties on fouling in submerged membrane bioreactors

    NARCIS (Netherlands)

    Marel, van der P.; Zwijnenburg, A.; Kemperman, A.; Wessling, M.; Temmink, B.G.; Meer, van der W.

    2010-01-01

    Polymeric flat-sheet membranes with different properties were used in filtration experiments with activated sludge from a pilot-scale MBR to investigate the influence of membrane pore size, surface porosity, pore morphology, and hydrophobicity on membrane fouling. An improved flux-step method was us

  11. Mine dewatering and impact assessment in an arid area: Case of Gulf region.

    Science.gov (United States)

    Yihdego, Yohannes; Drury, Len

    2016-11-01

    Analytical and empirical solution coupled with water balance method were used to predict the ground water inflow to a mine pit excavated below the water table, final pit lake level/recovery and radius of influence, through long-term and time variant simulations. The solution considers the effect of decreased saturated thickness near the pit walls, distributed recharge to the water table and upward flow through the pit bottom. The approach is flexible to accommodate the anisotropy/heterogeneity of the real world. Final pit void water level was assessed through scenarios to know whether it will be consumed by evaporation and a shallow lake will form or not. The optimised radius of influence was estimated which is considered as crucial information in relation to the engineering aspects of mine planning and sustainable development of the mine area. Time-transient inflow over a period of time was estimated using solutions, including analytical element method (AEM). Their primary value is in providing estimates of pit inflow rates to be used in the mine dewatering. Inflow estimation and recovery helps whether there is water to supplement the demand and if there is any recovery issue to be dealt with in relation to surface and groundwater quality/eco-system, environmental evaluations and mitigation. Therefore, this method is good at informing decision makers in assessing the effects of mining operations and developing an appropriate water management strategy.

  12. Combined method for simultaneously dewatering and reconstituting finely divided carbonaceous material

    Science.gov (United States)

    Wen, Wu-Wey; Deurbrouck, Albert W.

    1990-01-01

    A finely-divided carbonaceous material is dewatered and reconstituted in a combined process by adding a binding agent directly into slurry of finely divided material and dewatering the material to form a cake or consolidated piece which can be hardened by drying at ambient or elevated temperatures. Alternatively, the binder often in the form of a crusting agent is sprayed onto the surface of a moist cake prior to curing.

  13. Prevention partition for land subsidence induced by engineering dewatering in Shanghai

    Science.gov (United States)

    Wang, J. X.; Liu, X. T.; Yang, T. L.

    2015-11-01

    Land subsidence in shanghai has been found for more than 70 years. In the early years, it was mainly caused by groundwater exploitation. In recent years, engineering dewatering in shallow ground (within 90 m) has become a major source for land subsidence in the rapid urbanization course. A management partition of land subsidence induced by foundation pit dewatering for the first confined aquifer was suggested.

  14. Development of a Two-Stage Microalgae Dewatering Process – A Life Cycle Assessment Approach

    Science.gov (United States)

    Soomro, Rizwan R.; Zeng, Xianhai; Lu, Yinghua; Lin, Lu; Danquah, Michael K.

    2016-01-01

    Even though microalgal biomass is leading the third generation biofuel research, significant effort is required to establish an economically viable commercial-scale microalgal biofuel production system. Whilst a significant amount of work has been reported on large-scale cultivation of microalgae using photo-bioreactors and pond systems, research focus on establishing high performance downstream dewatering operations for large-scale processing under optimal economy is limited. The enormous amount of energy and associated cost required for dewatering large-volume microalgal cultures has been the primary hindrance to the development of the needed biomass quantity for industrial-scale microalgal biofuels production. The extremely dilute nature of large-volume microalgal suspension and the small size of microalgae cells in suspension create a significant processing cost during dewatering and this has raised major concerns towards the economic success of commercial-scale microalgal biofuel production as an alternative to conventional petroleum fuels. This article reports an effective framework to assess the performance of different dewatering technologies as the basis to establish an effective two-stage dewatering system. Bioflocculation coupled with tangential flow filtration (TFF) emerged a promising technique with total energy input of 0.041 kWh, 0.05 kg CO2 emissions and a cost of $ 0.0043 for producing 1 kg of microalgae biomass. A streamlined process for operational analysis of two-stage microalgae dewatering technique, encompassing energy input, carbon dioxide emission, and process cost, is presented. PMID:26904075

  15. FINITE ELEMENT NUMERICAL SIMULATION OF THREE-DIMENSIONAL SEEPAGE CONTROL FOR DEEP FOUNDATION PIT DEWATERING

    Institute of Scientific and Technical Information of China (English)

    LUO Zu-jiang; ZHANG Ying-ying; WU Yong-xia

    2008-01-01

    For deep foundation pit dewatering in the Yangtze River Delta, it is easy to make a dramatic decrease of the underground water level surrounding the dewatering area and cause land subsidence and geologic disasters. In this work, a three-dimensional finite element simulation method was applied in the forth subway of Dongjiadu tunnel repair foundation pit dewatering in Shanghai. In order to control the decrease of the underground water level around the foundation pit, the foundation pit dewatering method was used to design the optimization project of dewatering ,which was simulated under these conditions that the aquifers deposited layer by layer, the bottom of the aquifers went deep to 144.45 m, the retaining wall of foundation pit shield went deep to 65 m, the filters of the extraction wells were located between 44 m to 59 m, the water level in the deep foundation pit was decreased by 34 m, and the maximum decrease of water level outside the foundation pit was 3 m. It is shown that the optimization project and the practical case are consistent with each other. Accordingly, the three-dimensional finite element numerical simulation is the basic theory of optimization design of engineering structures of dewatering in deep foundation pit in such areas.

  16. Influence of Rubber Size on Properties of Crumb Rubber Mortars

    Directory of Open Access Journals (Sweden)

    Yong Yu

    2016-06-01

    Full Text Available Studies on the properties and applications of rubber cement-based materials are well documented. The sizes of rubbers used in these materials varied. However, information about the effects of rubber size on the properties of rubber cement-based materials, especially pore structure, mechanical strengths, and drying shrinkage properties, remains limited. Three groups of rubber with major particle sizes of 2–4 mm, 1–3 mm, and 0–2 mm were selected in this study. This paper presents experimental studies on the effects of rubber size on the consistency, fresh density, pore structure, mechanical properties, and drying shrinkage properties of crumb rubber mortars (CRMs. Results demonstrated that the consistency and fresh density of CRMs decreased with the rubber size. As to the pore structure, the total pore volume increased with the decrease of the rubber size. By contrast, the influence of the rubber size on the mesopore (<50 nm volume is not as significant as that of the rubber content. The mechanical properties of CRMs decreased with the rubber size. Low rubber stiffness and large pore volumes, especially those of small sized rubbers, contribute to the reduction of CRMs strength. The drying shrinkage of CRM increases as the rubber size decreases. The influences of rubber size on capillary tension are not significant. Thus, the shrinkage increases with the decrease of rubber size mainly because of its function in the deformation modulus reduction of CRMs.

  17. Influence of trace elements on dental enamel properties: A review.

    Science.gov (United States)

    Qamar, Zeeshan; Haji Abdul Rahim, Zubaidah Binti; Chew, Hooi Pin; Fatima, Tayyaba

    2017-01-01

    Dental enamel, an avascular, irreparable, outermost and protective layer of the human clinical crown has a potential to withstand the physico-chemical effects and forces. These properties are being regulated by a unique association among elements occurring in the crystallites setup of human dental enamel. Calcium and phosphate are the major components (hydroxyapatite) in addition to some trace elements which have a profound effect on enamel. The current review was planned to determine the aptitude of various trace elements to substitute and their influence on human dental enamel in terms of physical and chemical properties.

  18. Influence of plywood grain direction on sandwich panel bending properties

    OpenAIRE

    Jaroslav Kljak; Mladen Brezović; Alan Antonović

    2009-01-01

    This paper investigates the influence of plywood grain direction on bending properties of a sandwich panel, as well as on stress distribution in each layer. Experimental sandwich panels (tnom= 29 mm) were made of two three-ply plywood panels and a rigid PVC core between them. Grain directions of plywood panels were between 0° and 90°, continuously raised by 15°. Seven models of sandwich panels were made. Bending properties of a sandwich panel was determined by three point bending method and s...

  19. The factors influencing microstructure and mechanical properties of ADI

    Directory of Open Access Journals (Sweden)

    A. Vaško

    2009-01-01

    Full Text Available The paper deals with the influence of different conditions of isothermal heat treatment on microstructure and mechanical properties of austempered ductile iron (ADI. Different temperature of isothermal transformation of austenite and different holding time at this temperature were used for heat treatment of specimens. The microstructure of specimens after casting and after heat treatment was evaluated by STN EN ISO 945 and by image analysis (using Lucia software. Mechanical properties were evaluated by the tensile test, the Rockwell hardness test and fatigue tests.

  20. Vibrating membrane filtration as improved technology for microalgae dewatering.

    Science.gov (United States)

    Nurra, Claudia; Clavero, Ester; Salvadó, Joan; Torras, Carles

    2014-04-01

    The effect of shear-enhanced filtration by vibratory process in microalgae dewatering is presented in this paper. The aim of this research was to investigate the technical performance and improvement of vibrating membrane filtration compared with conventional tangential cross-flow filtration in microalgae concentration. An industrial-scale available commercial set-up was used. Several membrane materials as polyethersulfone, polyacrylonitrile, etc., and mean pore sizes (from 7000Da to 0.2μm) were tested and compared in both filtration set-ups. Experiments were carried-out with Nannochloropsis gaditana and Phaeodactylum tricornutum microalgae. It has been demonstrated that, even if the choice of the membrane depends on its cut-off, its material and the type of microalgae filtrated, dynamic filtration is always the best technology over a conventional one. If with conventional filtration permeability values were in the vicinity of 10L/h/m(2)/bar in steady state phase, with dynamic filtration these values increased to 30L/h/m(2)/bar or more.

  1. Dewatering of Chlorella pyrenoidosa using diatomite dynamic membrane: filtration performance, membrane fouling and cake behavior.

    Science.gov (United States)

    Zhang, Yalei; Zhao, Yangying; Chu, Huaqiang; Zhou, Xuefei; Dong, Bingzhi

    2014-01-01

    The diatomite dynamic membrane (DDM) was utilized to dewater Chlorella pyrenoidosa of 2 g dry weight/L under continuous-flow mode, whose ultimate algae concentration ranged from 43 g to 22 g dry weight/L of different culture time. The stable flux of DDM could reach 30 L/m(2) h over a 24 h operation time without backwash. Influences of extracellular organic matters (EOM) on filtration behavior and membrane fouling were studied. The DDM was divided into three sub-layers, the slime layer, the algae layer and the diatomite layer from the outside to the inside of the cake layer based on components and morphologies. It was found that EOM caused membrane fouling by accumulating in the slime and algae layers. The DDM intercepted polysaccharides, protein-like substances, humic-like substances and some low-MW organics. Proteins were indicated the major membrane foulants with increased protein/polysaccharide ratio from the slime layer to the diatomite layer as culture time increased. This method could be applied to subsequent treatment of microalgae coupling technology of wastewater treatment or microalgae harvesting for producing biofuel. Copyright © 2013 Elsevier B.V. All rights reserved.

  2. Influence of Moisture on the Electrical Properties of XLPE Insulation

    OpenAIRE

    Mecheri, Yacine; Nedjar, Mohamed; Lamure, Alain; Aufray, Maëlenn; Drouet, Christophe

    2010-01-01

    International audience; During their operating service, insulated power cables can be exposed to wet environment. The presence of moisture in cables surroundings may affect the properties of the used insulation material for instance, XLPE widely employed in MV and HV power cables insulation and therefore the reliability of the insulated cables. In order to examine the influence of wet aging conditions on the performances of XLPE insulated cables,samples (plates moulded from granules HFDE 4201...

  3. Compressional rheology: A tool for understanding compressibility effects in sludge dewatering.

    Science.gov (United States)

    Stickland, Anthony D

    2015-10-01

    Water and wastewater treatment sludges exhibit compressible behaviour due to flocculation and aggregation. At a critical solids concentration called the gel point, which is as low as 1-2 v/v%, a continuous interconnected network of particles is formed that can resist an applied load. The applied load (mechanical filtration pressure or buoyancy in settling for example) must exceed the network strength in order to consolidate the network. The network strength increases with solids concentration such that the equilibrium extent of consolidation is a function of the applied load. Improved understanding of the nature of compressible suspensions can have a significant impact through optimising design and operation of sludge handling and dewatering processes. This work gives an overview of compressional rheology, which has proven to be a useful tool for describing the solid-liquid separation of compressible systems. This is followed by three examples where compressibility effects must be taken into account, namely the extraction of material properties for extremely compressible materials, consolidation and crust formation during constant rate evaporation, and the effect of bed height in thickening.

  4. Permanganate/bisulfite (PM/BS) conditioning-horizontal electro-dewatering (HED) of activated sludge: Effect of reactive Mn(III) species.

    Science.gov (United States)

    Guo, Xinxin; Wang, Yili; Wang, Dongsheng

    2017-11-01

    A novel activated sludge (AS) conditioning method through permanganate/bisulfate (PM/BS) process was proposed. The method involved a new conditioner of reactive Mn(III) intermediate. Moreover, a Mn(III) conditioning-horizontal electro-dewatering (Mn(III) C-HED) process was established to improve AS dewatering performance. Underlying mechanisms were unraveled by investigating changes in physicochemical characteristics, scanning electron microscope (SEM) morphology, and transformation of water and organic matters. The optimum dewatering conditions for Mn(III) C-HED process with the final water content of 86.94% were determined as the combination of KMnO4 0.01 mol/L AS and NaHSO3 0.05 mol/L AS at 20 V for 120 min. Results showed that Mn(III) C-HED process effectively reduced free water and bound water with the corresponding removal ratios of 51.68% and 87.62% at the anode-side as well as 36.55% and 85.08% at the cathode-side, respectively. During the PM/BS process, the produced Mn(III), Mn(2+), and MnO2 exerted chemical and physical effects on AS conditioning and dewatering. Mn(III) disintegrated extracellular polymeric substances (EPS) fractions and cells in AS, as well as induced partial bound water release. Additionally, flocculation effect induced by Mn(2+) and MnO2 skeleton building also benefited AS dewatering. AS cells were further disrupted under the effect of a horizontal electric field. Accordingly, EPS within the AS matrix was solubilized, tightly bound (TB)-EPS or loosely bound (LB)-EPS was converted to their corresponding outer EPS fractions, and AS dewaterability improved. Additionally, changes in pH and temperature at HED stage damaged the AS cells and changed the floc properties, thereby leading to easy separation of liquid and AS particles. Copyright © 2017 Elsevier Ltd. All rights reserved.

  5. Flotation: A promising microalgae harvesting and dewatering technology for biofuels production.

    Science.gov (United States)

    Ndikubwimana, Theoneste; Chang, Jingyu; Xiao, Zongyuan; Shao, Wenyao; Zeng, Xianhai; Ng, I-Son; Lu, Yinghua

    2016-03-01

    Microalgal biomass as renewable energy source is believed to be of great potential for reliable and sustainable biofuels production. However, microalgal biomass production is pinned by harvesting and dewatering stage thus hindering the developing and growing microalgae biotechnology industries. Flotation technology applied in mineral industry could be potentially applied in microalgae harvesting and dewatering, however substantial knowledge on different flotation units is essential. This paper presents an overview on different flotation units as promising cost-effective technologies for microalgae harvesting thus bestowing for further research in development and commercialization of microalgae based biofuels. Dispersed air flotation was found to be less energy consuming. Moreover, Jameson cell flotation and dispersed ozone flotation are believed to be energy efficient microalgae flotation approaches. Microalgae harvesting and dewatering by flotation is still at embryonic stage, therefore extended studies with the focus on life cycle assessment, sustainability of the flotation unit, optimization of the operating parameters using different algal species is imperative. Though there are a number of challenges in microalgae harvesting and dewatering, with well designed and developed cultivation, harvesting/dewatering, extraction and conversion technologies, progressively, microalgae technology will be of great potential for biological carbon sequestration, biofuels and biochemicals production.

  6. POC-SCALE TESTING OF AN ADVANCED FINE COAL DEWATERING EQUIPMENT/TECHNIQUE

    Energy Technology Data Exchange (ETDEWEB)

    X.H. Wang; J. Wiseman; D.J. Sung; D. McLean; William Peters; Jim Mullins; John Hugh; G. Evans; Vince Hamilton; Kenneth Robinette; Tim Krim; Michael Fleet

    1999-08-01

    Dewatering of ultra-fine (minus 150 {micro}m) coal slurry to less than 20% moisture is difficult using the conventional dewatering techniques. The main objective of the project was to evaluate a novel surface modification technique, which utilizes the synergistic effect of metal ions and surfactants in combination for the dewatering of ultra-fine clean-coal slurries using various dewatering techniques on a proof-of-concept (POC) scale of 0.5 to 2 tons per hour. The addition of conventional reagents and the application of coal surface modification technique were evaluated using vacuum filtration, hyperbaric (pressure) filtration, ceramic plate filtration and screen-bowl centrifuge techniques. The laboratory and pilot-scale dewatering studies were conducted using the fine-size, clean-coal slurry produced in the column flotation circuit at the Powell Mountain Coal Company, St. Charles, VA. The pilot-scale studies were conducted at the Mayflower preparation plant in St. Charles, VA. The program consisted of nine tasks, namely, Task 1--Project Work Planning, Task 2--Laboratory Testing, Task 3--Engineering Design, Task 4--Procurement and Fabrication, Task 5--Installation and Shakedown, Task 6--System Operation, Task 7--Process Evaluation, Task 8--Equipment Removal, and Task 9--Reporting.

  7. An investigation of aerosol optical properties: Atmospheric implications and influences

    Science.gov (United States)

    Penaloza-Murillo, Marcos A.

    An experimental, observational, and theoretical investigation of aerosol optical properties has been made in this work to study their implications and influences on the atmosphere. In the laboratory the scientific and instrumental methodology consisted of three parts, namely, aerosol generation, optical and mass concentration measurements, and computational calculations. In particular the optical properties of ammonium sulfate and caffeine aerosol were derived from measurements made with a transmissometer cell-reciprocal- integrating nephelometer (TCRIN), equipped with a laser beam at 632.8 nm, and by applying a Mie theory computer code The aerosol generators, optical equipment and calibration procedures were reviewed. The aerosol shape and size distribution were studied by means of scanning electron microscopy and the Gumprecht- Sliepcevich/Lipofsky-Green extinction-sedimentation method. In particular the spherical and cylindrical shape were considered. During this investigation, an alternative method for obtaining the optical properties of monodisperse spherical non-absorbing aerosol using a cell-transmissometer, which is based on a linearisation of the Lambert-Beer law, was found. In addition, adapting the TCRIN to electrooptical aerosol studies, the optical properties of a circular-cylindrical aerosol of caffeine were undertaken under the condition of random orientation in relation with the laser beam, and perpendicular orientation to it. A theoretical study was conducted to assess the sensitivity of aerosol to a change of shape under different polarisation modes. The aerosol optical properties, obtained previously in the laboratory, were then used to simulate the direct radiative forcing. The calculations and results were obtained by applying a one- dimensional energy-balance box model. The influence of atmospheric aerosol on the sky brightness due to a total solar eclipse was studied using the photometric and meteorological observations made during the

  8. Influence of Delhi Pollution on Aerosol Properties Over Greater Noida

    Science.gov (United States)

    Sharma, M.; Singh, R. P.; Kumar, R.

    2015-12-01

    Influence of Delhi Pollution on Aerosol Properties over Greater NoidaManish Sharma1, Ramesh P. Singh2 and Rajesh Kumar3 1Research and Technology Development Centre, Sharda University, Greater Noida, India. 2School of Earth and Environmental Sciences, Schmid College of Science, Chapman University, Orange 92866, USA 3School of Basic Sciences and Research, Sharda University, Greater Noida, India. Delhi capital of India is highly polluted during winter and summer seasons. Due to dominant westerly winds the air mass influence its neighboring city Greater Noida which is located 60 km south east of Delhi. Detailed analysis of multi satellite data and ground observations have been carried out during 2001-2015. The ground observation and satellite data show dynamic aerosol optical parameters over Greater Noida. During winter and summer seasons, dominant westerly wind outflow pollutants of Delhi that mix with the local anthropogenic emissions of Greater Noida influencing aerosol properties at different pressure levels. The characteristics of trace gases and aerosol parameters over Delhi and Greater Noida will be presented. The air quality is severely affected from the outflow of pollutants from Delhi which is threat to people living in the area. Due to dominant winds the air mass further transported towards eastern parts of Indo-Gangetic plains affecting weather conditions of the major cities.

  9. 电渗透/Fe-过硫酸盐氧化协同强化污泥深度脱水%Coordination of electro-osmotic and Fe-persulfate oxidation process on sewage sludge deep-dewatering

    Institute of Scientific and Technical Information of China (English)

    李亚林; 刘蕾; 张毅; 魏添; 史丹

    2016-01-01

    Dewatered sewage sludge of sewage treatment plant was studied by self-made experimental device dewatering based on electro-osmotic-advanced oxidation process which would be influenced by the dosage of persulfate, proportion of ferric salt and persulfate, voltage gradient and the thickness of dewatered sewage sludge. The results showed that the combination of electro-osmosis-advanced oxidation technology can improve the dewater ability. The water content can be reduced to below 60% with sludge amount of 140 g, persulfate dosage of 100 mg·(g DS)−1, Fe2+/persulfate of 1:1, mechanical pressure of 17.59 kPa and controlling initial voltage of 11 V·cm−1. Electro-osmotic-advanced oxidation process can ensure fully use of oxidation ability of4SO−i to improve the sludge dewater ability based on the mechanism of reduction of electric field and electronic metastasis reaction, making persulfate fully activated compared with sludge dewatering by activated persulfate. Better than the traditional electro-osmosis sludge dewatering, more amount sludge can be treated one time and sludge cake uniformity can be highly improved for the subsequent transportation and settlement.%利用电渗透和高级氧化技术,采用自制实验装置对城市污水处理厂的脱水污泥进行了脱水研究,系统研究了过硫酸盐投加量、铁盐与过硫酸盐比例、电压梯度、脱水时间和污泥厚度对污泥脱水的影响。结果表明,电渗透-高级氧化复合技术可以改善污泥的脱水性能,在污泥样品为140 g、过硫酸盐投加量为100(mg·g DS)−1、Fe2+与过硫酸盐比例为1:1、机械压力为17.59 kPa、控制初始电压为11 V·cm−1时,污泥的含水率可以降低至60%以下,与单独使用电渗透技术相比,泥饼具有更好的均匀性,便于后续的运输和安置。

  10. Electroosmotic dewatering of chalk sludge, iron hydroxide sludge, wet fly ash and biomass sludge

    DEFF Research Database (Denmark)

    Hansen, H.K.; Christensen, Iben Vernegren; Ottosen, Lisbeth M.

    2003-01-01

    Electroosmotic dewatering has been tested in laboratory cells on four different porous materials: chalk sludge, iron hydroxide sludge, wet fly ash and biomass sludge from enzyme production. In all cases it was possible to remove water when passing electric DC current through the material. Casagra......Electroosmotic dewatering has been tested in laboratory cells on four different porous materials: chalk sludge, iron hydroxide sludge, wet fly ash and biomass sludge from enzyme production. In all cases it was possible to remove water when passing electric DC current through the material....... Casagrande's coefficients were determined for the four materials at different water contents. The experiments in this work showed that chalk could be dewatered from 40% to 79% DM (dry matter), fly ash from 75 to 82% DM, iron hydroxide sludge from 2.7 to 19% DM and biomass from 3 to 33% DM by electroosmosis...

  11. Influence of Moisture on Mechanical Properties of Cellulose Insulation Paper

    Science.gov (United States)

    Wang, Y. Y.; Tian, M.; Xu, H. X.; Fan, P.

    2014-01-01

    This paper aims to investigate the impact of moisture on mechanical properties of insulation paper. According to the molecular modeling approach proposed by Theodorou, the amorphous cellulose models of insulation paper with different moisture contents were built up to calculate mechanical parameters and hydrogen bond networks. And relevant conclusions could be drawn through further analysis on these calculation results: water molecules can destroy hydrogen bond network between the neighboring cellulose molecules, which might be responsible for the significant decrease of Young's modulus and other mechanical parameters, while no appreciable effect of intramolecular hydrogen bonds on mechanical properties was detected. Thus tensile tests were also carried out to study the moisture influence on the Young's modulus, by which the result of the simulation was approved.

  12. Dewatering of lignin residues from enzymatic production of ethanol; Avvattning av ligninrester fraan enzymatisk framstaellning av etanol

    Energy Technology Data Exchange (ETDEWEB)

    Sedin, Peter; Theliander, Hans [Luleaa Univ. of Technology, Luleaa (Sweden); Gren, Urban [Chalmers Univ. of Technology, Goeteborg (Sweden)

    2000-05-01

    The aim of this report is to gather knowledge of dewatering of lignin residues from ethanol production through enzymatic fermentation. A combined filtering and pressing apparatus is used for the dewatering. From the experimental data it is possible to get materials data of lignin. These data may lay the foundation for a rational choice of filtering equipment and appropriate pressing conditions.

  13. Factors influencing gelation properties of corn germ proteins.

    Science.gov (United States)

    Sun, Xiang Dong; Shi, Dan; Lan, Yu; Yao, Xin Miao; Zhang, Rui Ying; Zhang, Ying Lei; Su, Ping; Shan, Hong

    2017-03-07

    As a by-product of the oil industry, corn germ meal is mainly applied as a high-protein ingredient in animal feeds, without any application of the specific functional properties of corn germ protein (CGP). Factors influencing the gelation properties of CGP in relation to its dynamic rheology are still unclear owing to limited information. CGP concentrate was recovered by the isoelectric precipitation method, and factors affecting its gelation properties were investigated using a rheometer. A weak gel formed at natural pH with 0.3 mol L(-1) NaCl, and the minimum gel-forming concentration was observed at 150 g kg(-1) . Higher CGP protein concentrations induced stiffer gels, and linear relationships were found between protein concentration and gel stiffness (G') as well as between protein concentration and gel viscosity (G″). Lower heating and cooling rate promoted the formation of stiffer gels. CGP gelation was both NaCl- and pH-dependent. Sodium tripolyphosphate significantly increased gel stiffness with increasing concentration. No difference in gel elasticity (tanδ) was observed with the inclusion of various concentrations of sodium tripolyphosphate or sodium polyphosphate. Heating and cooling rate, NaCl, protein concentration, pH and phosphates all impact the gel-forming ability of CGP concentrate. Desired gel properties can be obtained through adjustment of these factors. © 2017 Society of Chemical Industry. © 2017 Society of Chemical Industry.

  14. Influence of tempering temperature on mechanical properties of cast steels

    Directory of Open Access Journals (Sweden)

    G. Golański

    2008-12-01

    Full Text Available The paper presents results of research on the influence of tempering temperature on structure and mechanical properties of bainite hardened cast steel: G21CrMoV4 – 6 (L21HMF and G17CrMoV5 – 10 (L17HMF. Investigated cast steels were taken out from internal frames of steam turbines serviced for long time at elevated temperatures. Tempering of the investigated cast steel was carried out within the temperature range of 690 ÷ 730 C (G21CrMoV4 – 6 and 700 ÷ 740 C (G17CrMoV5 – 10. After tempering the cast steels were characterized by a structure of tempered lower bainite with numerous precipitations of carbides. Performed research of mechanical properties has shown that high temperatures of tempering of bainitic structure do not cause decrease of mechanical properties beneath the required minimum.oo It has also been proved that high-temperature tempering (>720 oC ensures high impact energy at the 20% decrease of mechanical properties.

  15. The influence of clay minerals on acoustic properties of sandstones

    Energy Technology Data Exchange (ETDEWEB)

    Hansen, Olav

    1997-12-31

    This thesis aims to provide better understanding of the relationship between the acoustic properties and the petrophysical/mineralogical properties in sand-prone rock. It emphasizes the influence of clay minerals. The author develops a method to deposit clay minerals/mineral aggregates in pore space of a rigid rock framework. Kaolinite aggregates were flushed into porous permeable Bentheimer sandstone to evaluate the effect of pore filling minerals on porosity, permeability and acoustic properties. The compressional velocity was hardly affected by the clay content and it was found that the effect of minor quantities of pore filling minerals may be acoustically modelled as an ideal suspension, where the pore fluid bulk modulus is modified by the bulk modulus of the clay minerals. The influence of clays on acoustic velocities in petroleum reservoir rocks was investigated through ultrasonic measurements of compressional- and shear-waves on core material from reservoir and non-reservoir units on the Norwegian Continental Shelf. The measured velocities decrease as the porosity increases, but are not strongly dependent on the clay content. The measured velocities are less dependent on the petrophysical and lithological properties than indicated by previous authors and published mathematical models, and stiffness reduction factors are introduced in two of the models to better match the data. Velocities are estimated along the wellbores based on non-sonic well logs and reflect well the actual sonic log well measurements. In some wells the compressional velocity cannot be modelled correctly by the models suggested. Very high compressional wave anisotropy was measured in the dry samples at atmospheric conditions. As the samples were saturated, the anisotropy was reduced to a maximum of about 30% and decreases further upon pressurization. Reservoir rocks retrieved from 2500 m are more stress dependent than those retrieved from less than 200 m depth. 168 refs., 117 figs., 24

  16. Compression dewatering of municipal activated sludge: effects of salt and pH.

    Science.gov (United States)

    Raynaud, Mickael; Vaxelaire, Jean; Olivier, Jérémy; Dieudé-Fauvel, Emilie; Baudez, Jean-Christophe

    2012-09-15

    Even after mechanical dewatering, activated sludge contains a large amount of water. Due to its composition and biological nature this material is usually highly compressible and known to be difficult to dewater. In the present work, two treatments (salt addition and pH modification) are proposed to highlight some aspects which could explain the poor dewaterability of activated sludge. Dewatering tests are carried out in a pressure-driven device in order to well examine both, filtration and compression stages. Physico-chemical parameters, such as surface charge, hydrophobicity, extracellular polymeric substances (EPS) content and filtrate turbidity are measured on the tested sludge, for a better analysis of dewatering results. The dewatering ability of the sludge is widely linked to the cohesion of the flocculated matrix and the presence of fine particles. Both treatments alter the flocculated matrix and release fine particles. The release of fine particles tends to clog both, the filter cake and the filter medium. Consequently, the filtration rate decreases due to higher resistances to the flow. On another hand, the polymeric matrix breakdown enables to release some water trapped within the floc to the bulk liquid phase and thus facilitates its removal, which tends to decrease the moisture content of the filter-cake. It also impacts the compression dewatering step. The more destroyed structures lead to less elastic cakes and thus a slower primary consolidation stage. At the opposite, the mobility of the broken aggregates within the filter-cake does not seem to be improved by size reduction (the kinetics of the secondary consolidation stage are not significantly modified).

  17. Stabilization and dewatering of wastewater treatment plants sludge using the Fenton process

    Directory of Open Access Journals (Sweden)

    Abolfazl Azhdarpoor

    2015-11-01

    Full Text Available Wastewater sludge typically contains large amounts of water and organic materials; therefore, its stabilization and dewatering is of particular importance. In this study, Fenton oxidation process is used for stabilization and dewatering of sludge in the output of a wastewater treatment plant. To evaluate the sludge stabilization and dewatering, specific resistance to filtration (SRF, volatile organic compounds (VSS, total suspended solids (TSS, soluble chemical oxygen demand (SCOD and heterotrophic bacteria were measured. During the experiment, the optimal values of various parameters such as pH (2-9, hydrogen peroxide (0.015- 0.18mol/L, Fe2+ (0.008- 0.1mol/L and time (5 - 60 minutes for optimum sludge dewatering and stabilization were investigated. The results showed that the highest percentages of SRF reduction and removal rates of SCOD, VSS and TSS were 99.48, 61, 42, and 41 percent respectively. These results were obtained in optimum pH 5, 0.05 mol/l Fe2+, 0.12 mol/l hydrogen peroxide, and the retention time of 15 minutes. The removal rate of heterotrophic bacteria increased with increasing dose of hydrogen peroxide, so that a removal rate of 84 percent was observed at a dose of 0.18 mol/l. In general, Fenton process can reduce volatile organic materials and chemical oxygen demand of the sludge resulting in its significant stabilization and dewatering. In general, Fenton process can reduce volatile organic materials and chemical oxygen demand of the sludge resulting in its significant stabilization and dewatering.

  18. A Study of the system control model of caisson dewatering of the north anchorage of Taizhou Bridge

    Institute of Scientific and Technical Information of China (English)

    Zhao Yanrong; Zhou Zhifang; Ruan Jing

    2011-01-01

    A caisson foundation is applied to the north anchorage of Taizhou Yangtze River Highway Bridge of which the initial caisson sinking requires dewatering. Since the caisson foundation is quite close to nearby buildings, a system control model is established with source (sink) distribution and intensity being the object function, minimum requirements of settlement and deformation of surroundings caused by dewatering and dynamic water levels during different working procedures being constraints, and the design parameter of pumping wells being the variable, so as to lower the jeopardizing of surrounding buildings, which provides a new method for active control over settlement during dewatering. Such a method of dewatering based on system control model should be of significance for similar projects involving dewatering.

  19. Influence of the soil genesis on physical and mechanical properties.

    Science.gov (United States)

    Marschalko, Marian; Yilmaz, Işık; Fojtová, Lucie; Kubečka, Karel; Bouchal, Tomáš; Bednárik, Martin

    2013-01-01

    The paper deals with the influence of soil genesis on the physical-mechanical properties. The presented case study was conducted in the region of the Ostrava Basin where there is a varied genetic composition of the Quaternary geological structure on the underlying Neogeneous sediments which are sediments of analogous granulometry but different genesis. In this study, 7827 soil samples of an eolian, fluvial, glacial, and deluvial origin and their laboratory analyses results were used. The study identified different values in certain cases, mostly in coarser-grained foundation soils, such as sandy loam S4 (MS) and clayey sand F4 (CS). The soils of the fluvial origin manifest different values than other genetic types. Next, based on regression analyses, dependence was proved neither on the deposition depth (depth of samples) nor from the point of view of the individual foundation soil classes or the genetic types. The contribution of the paper is to point at the influence of genesis on the foundation soil properties so that engineering geologists and geotechnicians pay more attention to the genesis during engineering-geological and geotechnical investigations.

  20. INFLUENCE OF WINE ACID ON RHEOLOGICAL PROPERTIES OF WELL BORE CEMENT SLURRIES AND HARDENED CEMENT PROPERTIES

    Directory of Open Access Journals (Sweden)

    Nediljka Gaurina-Međimurec

    1989-12-01

    Full Text Available Adaptation of commercial types of domestic cements for use in cementing the deep wells is a process by which Yugoslav oil industry tends to solve problems of completion of those wells independently. In order to design a domestic, cheep and effective retarder, tests of applicability of wine acid on cement slurries have been carried out. Besides examining the necessary wine acid content to achieve desirable Theological properties, the influence of this additive on properties of hardened cement samples has been tested too (the paper is published in Croatian.

  1. Observations of ebb flows on tidal flats: Evidence of dewatering?

    Science.gov (United States)

    Rinehimer, J. P.; Thomson, J. M.; Chickadel, C.

    2010-12-01

    Incised channels are a common morphological feature of tidal flats. When the flats are inundated, flows are generally forced by the tidally varying sea surface height. During low tide, however, these channels continue to drain throughout flat exposure even without an upstream source of water. While the role of porewater is generally overlooked due to the low permeability of marine muds, it remains the only potential source of flows through the channels during low tide. In situ and remotely sensed observations (Figure 1) at an incised channel on a tidal flat in Willapa Bay from Spring 2010 indicate that dewatering of the flats may be driving these low tide flows. High resolution Aquadopp ADCP velocity profiles are combined with observations from tower-based infrared (IR) video to produce a complete time series of surface velocity measurements throughout low tide. The IR video observations provide a measurement of surface currents even when the channel depth is below the blanking distance of the ADCP (10 cm). As the depth within the channel drops from 50 cm to 10 cm surface velocities increase from 10 cm/s to 60 cm/s even as the tide level drops below the channel flanks and the flats are dry. As the drainage continues, the temperature of the flow rises throughout low tide, mirroring temperatures within the sediment bed on the tidal flat. Drainage salinity falls despite the lack of any freshwater input to the flat indicating that less saline porewater may be the source. The likely source of the drainage water is from the channel flanks where time-lapse video shows slumping and compaction of channel sediments. Velocity profiles, in situ temperatures, and IR observations also are consistent with the presence of fluid muds and a hyperpycnal, density driven outflow at the channel mouth highlighting a possible pathway for sediment delivery from the flats to the main distributary channels of the bay. Figure 1: Time series of tidal flat channel velocities and temperatures

  2. Gamma irradiation influence on physical properties of milk proteins

    Energy Technology Data Exchange (ETDEWEB)

    Ciesla, K. E-mail: kciesla@orange.ichtj.waw.pl; Salmieri, S.; Lacroix, M.; Le Tien, C

    2004-10-01

    Gamma irradiation was found to be an effective method for the improvement of both barrier and mechanical properties of the edible films and coatings based on calcium and sodium caseinates alone or combined with some globular proteins. Our current studies concern gamma irradiation influence on the physical properties of calcium caseinate-whey protein isolate-glycerol (1:1:1) solutions and gels, used for films preparation. Irradiation of solutions was carried out with Co-60 gamma rays applying 0 and 32 kGy dose. The increase in viscosity of solutions was found after irradiation connected to induced crosslinking. Lower viscosity values were detected, however, after heating of the solutions irradiated with a 32 kGy dose than after heating of the non-irradiated ones regarding differences in the structure of gels and resulting in different temperature-viscosity curves that were recorded for the irradiated and the non-irradiated samples during heating and cooling. Creation of less stiff but better ordered gels after irradiation arises probably from reorganisation of aperiodic helical phase and {beta}-sheets, in particular from increase of {beta}-strands, detected by FTIR. Films obtained from these gels are characterised by improved barrier properties and mechanical resistance and are more rigid than those prepared from the non-irradiated gels. The route of gel creation was investigated for the control and the irradiated samples during heating and the subsequent cooling.

  3. Gamma irradiation influence on physical properties of milk proteins

    Science.gov (United States)

    Cieśla, K.; Salmieri, S.; Lacroix, M.; Tien, C. Le

    2004-09-01

    Gamma irradiation was found to be an effective method for the improvement of both barrier and mechanical properties of the edible films and coatings based on calcium and sodium caseinates alone or combined with some globular proteins. Our current studies concern gamma irradiation influence on the physical properties of calcium caseinate-whey protein isolate-glycerol (1:1:1) solutions and gels, used for films preparation. Irradiation of solutions was carried out with Co-60 gamma rays applying 0 and 32 kGy dose. The increase in viscosity of solutions was found after irradiation connected to induced crosslinking. Lower viscosity values were detected, however, after heating of the solutions irradiated with a 32 kGy dose than after heating of the non-irradiated ones regarding differences in the structure of gels and resulting in different temperature-viscosity curves that were recorded for the irradiated and the non-irradiated samples during heating and cooling. Creation of less stiff but better ordered gels after irradiation arises probably from reorganisation of aperiodic helical phase and β-sheets, in particular from increase of β-strands, detected by FTIR. Films obtained from these gels are characterised by improved barrier properties and mechanical resistance and are more rigid than those prepared from the non-irradiated gels. The route of gel creation was investigated for the control and the irradiated samples during heating and the subsequent cooling.

  4. Factors That Influence the Extensional Rheological Property of Saliva.

    Science.gov (United States)

    Vijay, Amrita; Inui, Taichi; Dodds, Michael; Proctor, Gordon; Carpenter, Guy

    2015-01-01

    The spinnbarkeit of saliva reflects the ability of saliva to adhere to surfaces within the mouth, thereby serving as a protective role and aiding in lubrication. Therefore, alterations in the extensional rheology of saliva may result in the loss in adhesiveness or the ability to bind onto surfaces. Mucin glycoproteins and their structures are known to be important factors for the extensional rheological properties of saliva. The conformation of mucin depends on factors such as pH and ionic strength. Chewing is one of the main stimuli for salivary secretion but creates significant sheer stress on the salivary film which could influence mouthfeel perceptions. The current study investigates the possible factors which affect the extensional rheological properties of saliva by comparing submandibular/sublingual saliva with different oral stimuli within the same group of subjects. Unstimulated and stimulated saliva (chew, smell and taste) salivas were collected primarily from submandibular/sublingual glands. The saliva samples were measured for Spinnbarkeit followed by the measuring mucin, total protein, total calcium and bicarbonate concentrations. The results indicated correlations between rheological properties and mucin/ion concentrations. However, chewing stimulated submandibular/sublingual saliva is shown to have significantly lower Spinnbarkeit, but factors such as mucin, protein and calcium concentrations did not account for this variation. Analysis of the concentration of bicarbonate and pH appears to suggest that it has a prominent effect on extensional rheology of saliva.

  5. Factors That Influence the Extensional Rheological Property of Saliva.

    Directory of Open Access Journals (Sweden)

    Amrita Vijay

    Full Text Available The spinnbarkeit of saliva reflects the ability of saliva to adhere to surfaces within the mouth, thereby serving as a protective role and aiding in lubrication. Therefore, alterations in the extensional rheology of saliva may result in the loss in adhesiveness or the ability to bind onto surfaces. Mucin glycoproteins and their structures are known to be important factors for the extensional rheological properties of saliva. The conformation of mucin depends on factors such as pH and ionic strength. Chewing is one of the main stimuli for salivary secretion but creates significant sheer stress on the salivary film which could influence mouthfeel perceptions. The current study investigates the possible factors which affect the extensional rheological properties of saliva by comparing submandibular/sublingual saliva with different oral stimuli within the same group of subjects. Unstimulated and stimulated saliva (chew, smell and taste salivas were collected primarily from submandibular/sublingual glands. The saliva samples were measured for Spinnbarkeit followed by the measuring mucin, total protein, total calcium and bicarbonate concentrations. The results indicated correlations between rheological properties and mucin/ion concentrations. However, chewing stimulated submandibular/sublingual saliva is shown to have significantly lower Spinnbarkeit, but factors such as mucin, protein and calcium concentrations did not account for this variation. Analysis of the concentration of bicarbonate and pH appears to suggest that it has a prominent effect on extensional rheology of saliva.

  6. Factors That Influence the Extensional Rheological Property of Saliva

    Science.gov (United States)

    Vijay, Amrita; Inui, Taichi; Dodds, Michael; Proctor, Gordon; Carpenter, Guy

    2015-01-01

    The spinnbarkeit of saliva reflects the ability of saliva to adhere to surfaces within the mouth, thereby serving as a protective role and aiding in lubrication. Therefore, alterations in the extensional rheology of saliva may result in the loss in adhesiveness or the ability to bind onto surfaces. Mucin glycoproteins and their structures are known to be important factors for the extensional rheological properties of saliva. The conformation of mucin depends on factors such as pH and ionic strength. Chewing is one of the main stimuli for salivary secretion but creates significant sheer stress on the salivary film which could influence mouthfeel perceptions. The current study investigates the possible factors which affect the extensional rheological properties of saliva by comparing submandibular/sublingual saliva with different oral stimuli within the same group of subjects. Unstimulated and stimulated saliva (chew, smell and taste) salivas were collected primarily from submandibular/sublingual glands. The saliva samples were measured for Spinnbarkeit followed by the measuring mucin, total protein, total calcium and bicarbonate concentrations. The results indicated correlations between rheological properties and mucin/ion concentrations. However, chewing stimulated submandibular/sublingual saliva is shown to have significantly lower Spinnbarkeit, but factors such as mucin, protein and calcium concentrations did not account for this variation. Analysis of the concentration of bicarbonate and pH appears to suggest that it has a prominent effect on extensional rheology of saliva. PMID:26305698

  7. Development of A Continuous Process for Displacement Dewatering

    Energy Technology Data Exchange (ETDEWEB)

    Dave Beck

    2006-10-30

    The subject of this contract was to investigate the viability of a new process for dewatering paper called displacement pressing. The term “displacement pressing” was coined in the 1980s by researchers to describe a paper dewatering process where air is blown through a sheet of paper while it is being pressed. It was shown at that time that the combination of air and low pressing force could dramatically increase both sheet bulk and sheet solids which in theory would translate into huge savings in energy and fiber consumption. But there was a catch. Although the research results were dramatic, no one could figure out a commercially viable process to carry out displacement pressing. All research work had been done with batch processes, and there was no obvious way to convert these processes into a continuous process. By the end of the early1990’s no one was researching in this area because no continuous process existed. Recently we proposed a new method to carry out displacement pressing. Our process uses special pressing fabrics and a special 4 roll press that we call a “Beck Cluster Press” or BCP. The BCP provides a pressurized atmosphere that acts on a moving web of paper and fabrics. The special fabrics designed for this process use this atmosphere to press the sheet and at the same time, these special fabrics force air through the sheet to carry out displacement pressing. 1 Because of the complexity and cost of building the first functioning BCP, a simple simulator was built to confirm and study the process. Although results from this simulator were extremely favorable, financial times were hard in the paper industry. We are grateful for the DOE contract that allowed us to continue research that showed the tremendous benefits of displacement pressing. Specifically, accomplishments from the DOE contract are as follows: 1. A narrow (5” wide sheet) lab Beck Cluster Press (BCP) was started up, and made operational. This press accepts hand sheets and

  8. 调理脱水污泥的热解特性及动力学分析%Pyrolysis characteristics and kinetics analysis of conditioned dewatered sewage sludge

    Institute of Scientific and Technical Information of China (English)

    徐新宇; 杨家宽; 宋健; 时亚飞; 虞文波; 郦超; 何姝; 吴旭; 梁莎

    2016-01-01

    利用TGA(Thermogravimetric analysis)热分析技术对污水处理厂原始污泥及调理脱水污泥进行了实验研究,获得了不同升温速率下污泥的TG (Thermogravimetric)和DTG失重曲线.实验发现,不同调理脱水污泥热解特性复杂,且热解动力学在不同转化率下对应的动力学反应也不同.并利用M-KAS(Kissinger-AkahiraSunose)模型和Discrete DAEM(Discrete distribute activation energy model)模型对不同调理污泥进行了动力学参数研究.结果表明,污泥的非等温热解过程包含3个失重阶段;升温速率影响污泥热解特征温度,随着升温速率的提高,失重曲线向高温区滑移.利用上述模型计算的动力学参数变化趋势表明所采用的Fenton及赤泥复合调理对污泥热解特性有很大影响,Fenton调理有助于污泥EPS(Extracellular polymeric substances)破坏,影响热解反应中的形核过程,进而影响热解动力学变化趋势;赤泥调理后,赤泥更容易与破坏的污泥细小颗粒结合,增加了污泥热解反应数量,影响整个污泥热解过程.从计算结果可以看出污泥热解由多步反应组成,整个热解过程动力学参数不断变化.%Raw and conditioned dewatered sewage sludges of sewage treatment plant were analysed by the TGA thermal analysis technique,and TG and DTG curves were obtained at different heating rates.Experimental results showed that the pyrolysis characteristics of different conditioned dewatered sludge were complex and pyrolysis kinetics with different conversion ratios corresponded to different kinetic reations.M-KAS model and Discrete DAEM model were also applied to analyze the kinetic parameters of different conditioned dewatered sewage sludge.The results showed that the nonisothermal decomposition process of dewatered sewage sludge contained three weight loss stages and the heating rate influenced the characteristic temperature zones of pyrolysis.With increasing heating rate,the weight loss curve slipped

  9. 46 CFR 28.815 - Bilge pumps, bilge piping, and dewatering systems.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 1 2010-10-01 2010-10-01 false Bilge pumps, bilge piping, and dewatering systems. 28... REQUIREMENTS FOR COMMERCIAL FISHING INDUSTRY VESSELS Aleutian Trade Act Vessels § 28.815 Bilge pumps, bilge... fixed, self priming, powered, bilge pump, having a minimum capacity rating of 50 gallons per...

  10. Numerical simulation of dewatering thick unconsolidated aquifers for safety of underground coal mining

    Institute of Scientific and Technical Information of China (English)

    HANG Yuan; ZHANG Gai-ling; YANG Guo-yong

    2009-01-01

    With an increase of mining the upper limits under unconsolidated aquifers, dewatering of the bottom aquifer of the Quaternary system has become a major method to avoid water and sand inrushes. In the 8th District of the Taiping Coal Mine in south-western Shandong province, the bottom aquifer of the Quaternary system is moderate to excellent in water-yielding capacity. The base rock above the coal seam is very thin in the concealed coal field of the Carboniferous and Permian systems. Therefore, a comprehensive dewatering plan from both the ground surface and the panel was proposed to lower the groundwater level in order to ensure mining safety. According to the hydrogeologic conditions of the 8th District, we established a numerical model so that we could simulate the groundwater flow in the dewatering process. We obtained the simulation parameters from previous data using backward modeling, such as the average coefficient of permeability of 12 m/d and the elastic storage coefficient of 0.002. From the same model, we predicted the movement of groundwater and water level variables and obtained the visible effect of the dewatering project. Despite the overburden failure during mining, no water and/or sand inrush occurred because the groundwater level in the bottom aquifer was lowered to a safe water level.

  11. Use of geotextile tubes with chemical amendments to dewater dairy lagoon solids.

    Science.gov (United States)

    Worley, J W; Bass, T M; Vendrell, P F

    2008-07-01

    Three geo-textile filtration tubes were used to dewater lagoon solids from a first stage dairy lagoon using chemical amendments (aluminum sulfate and a polymer) to enhance the separation process. This experiment had previously been done without chemical amendment. The chemical amendments speeded the dewatering process so that filling could be accomplished sooner, and also increased the removal rate of nutrients, especially phosphorus into the solid phase. Chemically amended slurry was pumped from the lagoon into the tube with the filtered liquid seeping from the tube and returning to the lagoon. Each tube was filled five to six times at 2-5-day intervals, and then allowed to dewater for 2 weeks before sampling the solid fraction in the tube. Separation efficiency improved from 79% to 99% for phosphorous and from 92% to 100% for organic nitrogen with chemical amendment. Time required for dewatering was significantly reduced by chemical amendment. Cost for the tube was approximately $10/m(3) of recovered solids with no chemical amendment and cost including the chemicals was approximately $14/m(3) of recovered solids.

  12. Geotextile filtration performance for lagoon sludges and liquid animal manures dewatering

    Science.gov (United States)

    Maintenance and control of liquid levels in anaerobic lagoons and storage ponds require liquid-solid separation as a pretreatment and periodic removal of accumulated sludges. Until local options become available, sludges can be contained, dewatered, and stored using geotextile filtration. We used a ...

  13. Dewatering ultrafine clean coal in a T.H. filter press

    Energy Technology Data Exchange (ETDEWEB)

    A. Patwardhan; Y.P. Chugh; B.J. Arnold; A.N. Terblanche [Southern Illinois University at Carbondale, IL (United States). Department of Mining and Mineral Resources Engineering

    2006-01-15

    This study demonstrates a low-cost, high-efficiency filter press technology for dewatering minus 150 {mu}m column flotation clean coal products from two coal mines. Pilot-scale in-plant demonstration of this technology at these two locations provided stable, trouble-free operation while achieving an excellent dewatering performance at a high throughput. At one location, filter cakes with residual total moisture contents in the 20-22% range were achieved. At the other location 25-27% residual total moisture contents were achieved. At the second location, lower cake moisture content in the range of 21-25% was achieved with the use of appropriate dewatering aids. For difficult to dewater coals with higher clay contents, the innovative use of hot water during the filtration process was found to reduce cake moisture content by two to three percentage points over the baseline conditions. Engineering economic evaluations indicated that a fine coal product can be produced using column flotation and the filter press at a cost of $5.95/t (dry basis) for one mine. With appropriate blending strategies, annual profitability can be shown to increase by $0.9 million ($US) for this 1.8 Mt/year mine. For the second 2.4 Mt/year mine, annual profitability was projected to increase by $2.5 million ($US).

  14. Feasibility of electro-osmotic belt filter dewatering technology at pilot scale

    CSIR Research Space (South Africa)

    Snyman, HG

    2000-01-01

    Full Text Available -effective dewatering technologies, electro-osmotic belt filtering was developed by Smollen and Kafaar in 1995. The mechanical equipment resembles a belt filter press but the belts are stainless steel, woven belts, which act as the electrodes. In this study...

  15. Influence of Biomass Chemical Properties on Torrefaction Characteristics

    DEFF Research Database (Denmark)

    Saleh, Suriyati Binti; Hansen, Brian Brun; Jensen, Peter Arendt

    2013-01-01

    Different biomass types may differ with respect to torrefaction characteristics, and an improved understanding and ability to predict the torrefaction performance is, therefore, desired. In this study, the influence of the chemical properties (lignocellulose composition and alkali content......) on the torrefaction behavior with respect to mass loss and grindability is investigated by simultaneous thermal analysis (STA) and by using a combined torrefaction and grinding reactor. The torrefaction behavior of six raw biomass samples and selected pretreated samples (washed and impregnated with KCl and K2CO3) has...... of the torrefied products was evaluated by determining the d50 value of the particle size distribution of the biomass before and after torrefaction in the combined torrefaction and mill reactor. A significant decrease in d50 value was observed when the alkali content increased from 0 to 0.2 wt % db, whereas...

  16. Influence of Stress History on Elastic and Frictional Properties of Core Material from IODP Expeditions 315 and 316, NanTroSEIZE Transect: Implications for the Nankai Trough Accretionary Prism

    Science.gov (United States)

    Knuth, M. W.; Tobin, H. J.; Marone, C.; Saffer, D. M.; Hashimoto, Y.

    2009-12-01

    We present results of ultrasonic P and S-wave velocity measurements on core material recovered during NanTroSEIZE Stage 1 Expeditions 315 and 316 to the Nankai Trough Accretionary Margin, focusing on how different stress paths during subduction and exhumation along regional thrust faults influence the elastic moduli and anisotropy of various components of the accretionary prism. The influence of changes in pore pressure and confining pressure on the elastic properties of prism material has important implications for its mechanical strength, and understanding how elastic properties change along various stress paths will help us use 3D seismic tomography to draw inferences about overpressurization and fluid flow within the accretionary prism. We compare the velocities measured during shipboard physical properties characterization and logging-while-drilling data from Expedition 314 with 3D seismic velocity data and the results of previous shore-based studies to establish in situ conditions for material at various locations within the prism. We test both intact core material and disaggregated gouge and unlithified sediments from the upper prism, subjecting both samples types to a progression of confining pressure, pore pressure, and axial loading conditions representing normal consolidation and overconsolidation stress paths due to compaction and dewatering during burial and subsequent uplift by thrust faulting. While making continuous ultrasonic velocity measurements to determine changes in dynamic and quasistatic elastic moduli during axial and isotropic loading, we also subject granular material to frictional shear in a biaxial double-direct shearing configuration to measure how its frictional properties vary as a function of stress history.

  17. Precision Dual-Aquifer Dewatering at a Low Level Radiological Cleanup in New Jersey

    Energy Technology Data Exchange (ETDEWEB)

    Gosnell, A. S.; Langman, J. W. Jr.; Zahl, H. A.; Miller, D. M.

    2002-02-27

    Cleanup of low-level radioactive wastes at the Wayne Interim Storage Site (WISS), Wayne, New Jersey during the period October, 2000 through November, 2001 required the design, installation and operation of a dual-aquifer dewatering system to support excavation of contaminated soils. Waste disposal pits from a former rare-earth processing facility at the WISS had been in contact with the water table aquifer, resulting in moderate levels of radionuclides being present in the upper aquifer groundwater. An uncontaminated artesian aquifer underlies the water table aquifer, and is a localized drinking water supply source. The lower aquifer, confined by a silty clay unit, is flowing artesian and exhibits potentiometric heads of up to 4.5 meters above grade. This high potentiometric head presented a strong possibility that unloading due to excavation would result in a ''blowout'', particularly in areas where the confining unit was < 1 meter thick. Excavation of contaminated materials w as required down to the surface of the confining unit, potentially resulting in an artesian aquifer head of greater than 8 meters above the excavation surface. Consequently, it was determined that a dual-aquifer dewatering system would be required to permit excavation of contaminated material, with the water table aquifer dewatered to facilitate excavation, and the deep aquifer depressurized to prevent a ''blowout''. An additional concern was the potential for vertical migration of contamination present in the water table aquifer that could result from a vertical gradient reversal caused by excessive pumping in the confined system. With these considerations in mind, a conceptual dewatering plan was developed with three major goals: (1) dewater the water table aquifer to control radionuclide migration and allow excavation to proceed; (2) depressurize the lower, artesian aquifer to reduce the potential for a ''blowout''; and (3

  18. Influence of snow-cover properties on avalanche dynamics

    Science.gov (United States)

    Steinkogler, W.; Sovilla, B.; Lehning, M.

    2012-04-01

    Snow avalanches with the potential of reaching traffic routes and settlements are a permanent winter threat for many mountain communities. Snow safety officers have to take the decision whether to close a road, a railway line or a ski slope. Those decisions are often very difficult as they demand the ability to interpret weather forecasts, to establish their implication for the stability and the structure of the snow cover and to evaluate the influence of the snow cover on avalanche run-out distances. In the operational programme 'Italy-Switzerland, project STRADA' we focus on the effects of snow cover on avalanche dynamics, and thus run-out distance, with the aim to provide a better understanding of this influence and to ultimately develop tools to support snow safety officers in their decision process. We selected five avalanches, measured at the Vallée de la Sionne field site, with similar initial mass and topography but different flow dynamics and run-out distances. Significant differences amongst the individual avalanches could be observed for front and internal velocities, impact pressures, flow regimes, deposition volumes and run-out distances. For each of these avalanches, the prevailing snow conditions at release were reconstructed using field data from local snowpits or were modeled with SNOWPACK. Combining flow dynamical data with snow cover properties shows that erodible snow depth, snow density and snow temperature in the snow pack along the avalanche track are among the decisive variables that appear to explain the observed differences. It is further discussed, how these influencing factors can be quantified and used for improved predictions of site and time specific avalanche hazard.

  19. Thermophysical properties of hydrophobised lime plasters - The influence of ageing

    Science.gov (United States)

    Pavlíková, Milena; Zemanová, Lucie; Pavlík, Zbyšek

    2017-07-01

    The building envelope is a principal responsible for buildings energy loses. Lime plasters as the most popular finishing materials of historical buildings and culture monuments influence the thermal behaviour as well as construction material of masonry. On this account, the effect of ageing on the thermophysical properties of a newly designed lime plasters containing hydrophobic admixture is analysed in the paper. For the comparative purposes, the reference lime plaster is tested. The ageing is accelerated with controlled carbonation process to simulate the final plasters properties. Basic characterization of the tested materials is done using bulk density, matrix density, and porosity measurements. Thermal conductivity and volumetric heat capacity are experimentally assessed using a transient impulse method. The obtained data revealed the significant changes of the both studied thermal parameters in the dependence on plasters composition and age. The assessed material parameters will be stored in a material database, where will find use as an input data for computational modelling of heat transport in this type of porous building materials and evaluation of energy-savings and sustainability issues.

  20. Influence of silybin on biophysical properties of phospholipid bilayers

    Institute of Scientific and Technical Information of China (English)

    Olga WESO(L)OWSKA; Krystyna MICHALAK; Barbara (L)ANIA-PIETRZAK; Micha(l) KU(Z)D(Z)A(L); Kamila STA(N)CZAK; Daniela MOSI(A)DZ; Piotr DOBRYSZYCKI; Andrzej O(Z)YHAR; Ma(l)gorzata KOMOROWSKA; Andrzej B HENDRICH

    2007-01-01

    Aim: Silybin (silibinin)is major biologically active flavonolignan extracted from milk thistle (Sylibum marianum). Its biological activities include hepato-protection, anticancer properties, and antioxidant- and membrane-stabilizing functions. Al-though membranes are postulated to be one of the cellular targets for silybin, little is known about its interaction with phospholipid bilayers. Methods: In the present work, the interactions of silybin with phosphatidylcholine bilayers were studied in detail using fluorescence spectroscopy, microcalorimetry and electron spin resonance techniques. Results: The results showed that silybin interacted with the surface of lipid bilayers. It affected the generalized polarization of the fluores-cent probe Prodan, while not influencing the more deeplylocated Laurdan. Silybin lowered the main phospholipid phase transition temperature as judged by microcalorimetry, and caused the immobilization of spin probe Tempo-palmitate located on the surface of membranes. The mobility of spin probes 5-and 16-doxylstearic acid was not affected by silybin. Silybin-induced quenching of 1,6-diphe-nyl-1,3,5-hexatriene fluorescence indicated that some flavonoid molecules parti-tioned into the hydrophobic region of membranes, which did not change signifi-cantly the biophysical properties of the deeper membrane regions. Conclusion: Such a behavior of silybin in membranes is in accordance with its postulated biological functions and neglectable side effects of therapies using silybin.

  1. Influence of Mullite Wool Waste on the Properties of Ceramics

    Directory of Open Access Journals (Sweden)

    Jurgita MALAIŠKIENĖ

    2011-03-01

    Full Text Available In the paper, the influence of mullite wool waste additive on the properties of building ceramics is analysed. For that purpose four formation masses were prepared, dried and fired at the analogous regimes (maximum firing temperature 1080 °C. The fired samples were used to determine the structural and physical-mechanical properties. The values of these parameters are analysed: water absorption, total and effective porosity, rate of capillary mass flow, reserve of porous volume, compressive strength, density and estimated exploitation frost resistance. It has been determined that mullite wool waste can be applied to the production of building ceramics and the optimum quantity of waste in a formation mass is 10 % according to weight. Water absorption of those ceramic samples was less than 4 %, compressive strength was 28.6 MPa, density - 2033 kg/m3, forecasted resistance to frost about 400 cycles.http://dx.doi.org/10.5755/j01.ms.17.1.255

  2. Substrate properties influence calcification in valvular interstitial cell culture.

    Science.gov (United States)

    Benton, Julie A; Kern, Hanna B; Anseth, Kristi S

    2008-11-01

    Valvular calcification is an active, cell-mediated process that results in significant morbidity and mortality. In standard culture, valvular interstitial cells (VICs) elicit significant calcification as a result of myofibroblast activation, and this limits their use in characterization studies. The study aim was to identify culturing substrates that would suppress atypical VIC calcification, and to investigate culture substrates representing a more physiological system. Several culture platforms were selected to compare and contrast the influence of biochemical and mechanical properties on VIC calcification. Substrates investigated included: tissue culture polystyrene (TCPS), TCPS coated with either fibronectin or fibrin, and an elastic poly(ethylene glycol) (PEG) hydrogel, also with fibronectin or fibrin coupled to the surface. Experiments were repeated with profibrotic growth factor transforming growth factor-beta 1 (TGF-beta1). VIC calcification was characterized by calcific nodule formation, alkaline phosphatase activity and calcium accumulation. Gene and protein expression of alpha smooth muscle actin (aSMA) and core binding factor-1 (CBFa-1) were analyzed with qRT-PCR and immunostaining. Unmodified TCPS substrates had an innate ability to promote the markers of calcification studied. The addition of TGF-beta1 enhanced levels of all osteoblastic markers studied. When TCPS surfaces were modified with fibronectin, all markers for calcification were repressed, but alphaSMA - a marker for myofibroblastic activity was unchanged. Meanwhile, fibrin-modified TCPS surfaces enhanced calcification over unmodified TCPS substrates. On soft PEG hydrogels, all markers for calcification were repressed, regardless of the surface chemistry, while alphaSMA expression remained unaffected. Collectively, VIC properties are highly linked to the culture microenvironment. Both, the biochemical and mechanical environment of tissue culture has an effect on the spontaneous calcification

  3. Synthesis, characterization, and secondary sludge dewatering performance of a novel combined silicon–aluminum–iron–starch flocculant

    Energy Technology Data Exchange (ETDEWEB)

    Lin, Qintie, E-mail: qintlin@163.com; Peng, Huanlong; Zhong, Songxiong; Xiang, Jiangxin

    2015-03-21

    Highlights: • Silicon, aluminum, and iron were grafted onto starch chains to synthesize CSiAFS. • The sludge dewatering performance of CSiAFS was superior to PAC, PAM, and FeCl{sub 3}. • CSiAFS exhibited a good dewatering efficiency over a wide range of pH (3.0–11.0). • CSiAFS had a discontinuous surface with channels which helped to sludge dewatering. - Abstract: Flocculation is one of the most widely used cost-effective pretreatment method for sludge dewatering, and a novel environmentally friendly and efficient flocculant is highly desired in the sludge dewatering field. In this study, a novel combined silicon–aluminum–ferric–starch was synthesized by grafting silicon, aluminum, and iron onto a starch backbone. The synthesized starch flocculant was characterized using Fourier-transform infrared spectroscopy (FTIR), scanning electron microscopy, X-ray powder diffraction, and thermogravimetric analysis. The dewatering performance of secondary sludge was evaluated according to the capillary suction time, settling volume percentage, and specific resistance to filtration. The results indicated that the copolymer exhibited: (1) a good dewatering efficiency over a wide pH range of 3.0–11.0, (2) superior sludge dewatering performance compared to those of polyaluminum chloride (PACl), polyacrylamide (PAM), ferric chloride, and (3) a discontinuous surface with many channels or voids that helps to mobilize the impermeable thin layer of secondary sludge during filter pressing. Such a novel copolymer is a promising green flocculant for secondary sludge dewatering applications.

  4. Lignite Drying and Dewatering Technologies%褐煤干燥脱水技术

    Institute of Scientific and Technical Information of China (English)

    孟顺; 孙绍增; 赵广播

    2013-01-01

    With a high water content, lignite has a low efficiency for direct combustion power generation. The lignite drying and dewatering technology can effectively lower the water content of lignite- and enhance its competitive power. On this basis, the authors studied and analyzed the principles of the following technologies, namely, flue gas drying technology , steam drying technology (tube type drying and fluidized bed steam drying) , hydrothermal dewatering technology, mechanical thermal dehydration (MTE) technology and upgraded brown coal (UBC) technology. Moreover,they also contrasted and analyzed the pressure, temperature, removing state, dewatering effectiveness, pore structure and re-absorption characteristics of various drying and dewatering technologies. The mechanical thermal dehydration technology can change the pore structure of brown coal and prevent from re-absorption, thus achieving a relatively high dewatering efficiency with a low energy consumption rate. It is of major significance for China to develop novel drying and dewatering technologies with due consideration of the brown coal distribution features of China to lower the water content of coal from its source, realize an economic transportation of coal and enhance the power generation efficiency of power plants.%褐煤含水量高,直接燃烧发电效率低.褐煤干燥脱水技术能有效降低褐煤含水量,提高其竞争力.研究介绍了烟气干燥技术、蒸汽干燥(管式干燥,流化床蒸汽干燥)、水热脱水技术、机械热力脱水技术(MTE)和热油干燥技术(UBC)5种褐煤干燥脱水技术的原理;对比分析了不同干燥脱水技术的压力、温度、脱除状态、脱水效率、孔隙结构和重吸收特性;机械热力脱水技术(MTE)可以改变褐煤孔隙结构、防止重吸收、脱水效率较高和能耗低.结合我国褐煤分布特点,开发新型干燥脱水技术,在源头降低煤的水分含量,实现煤的经济运输,提高电厂的发电效率.

  5. An Experimental Study on Axial Temperature Distribution of Combustion of Dewatered Poultry Sludge in Fluidized bed combustor

    Directory of Open Access Journals (Sweden)

    Abbas A.H.

    2016-01-01

    Full Text Available A laboratory scale bubbling fluidized bed combustor was designed and fabricated to study the combustion of dewatered poultry sludge at different operational parameters. This paper present a study on the influence of equivalent ratio, secondary to primary air ratio and the fuel feed rate on the temperature distribution along the combustor. The equivalent ratio has been changed between 0.8 to 1.4% under poultry sludge feed rate of 10 kg/h and from 0.8 to 1 under poultry sludge feed rate of 15 kg/h. The secondary to primary air ratio was varied from 0.1 to 0.5 at 0.65 m injection height and 1.25 equivalent ratio. The results showed that these factors had a significant influence on the combustion characteristics of poultry sludge. The temperature distribution along the combustor was found to be strongly dependent on the fuel feed rate and the equivalent ratio and it increased when these two factors increased. However, the secondary air ratio increased the temperature in the lower region of the combustor while no significant effect was observed at the upper region of the combustor. The results suggested that the poultry sludge can be used as a fuel with high thermal combustor efficiency.

  6. Sludge dewatering on filters aiming the utilization as fuel; Desaguamento de lodos em filtro visando aproveitamento como combustivel

    Energy Technology Data Exchange (ETDEWEB)

    Paschoalim, Luis Gustavo; Neves, Jose Mangolini

    1992-12-31

    This work presents modern methodologies for sludge dewatering and alternatives for environmental disposal of the so obtained cakes. Among the possible alternatives, special emphasis is given to the characterization and study of the variables which determine the behaviour of dewatering operation of sludges form pulp and paper industries. Results are presents for bench scale tests and pilot plant tests 28 refs., 9 figs., 7 tabs.

  7. Electroosmotically enhanced dewatering/deliquoring of fine-particle coal: Final report, January 1--December 31, 1988

    Energy Technology Data Exchange (ETDEWEB)

    Sami, Sedat [Department of Civil Engineering and Mechanics, Southern Illinois Univ., Carbondale, IL (United States); Davis, P.hilip K. [Department of Civil Engineering and Mechanics, Southern Illinois Univ., Carbondale, IL (United States); Smith, James G. [Department of Electrical Engineering, Southern Illinois Univ., Carbondale, IL (United States)

    1989-03-01

    This research is an investigation of the use of electroosmosis to dewater/deliquor ultrafine coal. Post-beneficiation dewatering/deliquoring methods for ultrafine coal are inadequate and generally require subsequent thermal drying. Thermal drying is not only expensive and time consuming, it also does not recover liquids for reuse in beneficiation processes. The degree of difficulty associated with dewatering increases as surface forces become more important than gravimetric forces. Electroosmotic flow has advantages for dewatering because it is much less sensitive to pore size than hydraulic gradient flow for the 1 to 75 ..mu..m ultrafine size range. The first year of this project focused upon preparation of ultrafine coal samples, development of test equipment and test cells, identification of variables affecting electroosmosis, and trial runs. Techniques and procedures not previously used by researchers of electroosmotic dewatering have revealed important information about the dynamics of the electroosmosis process. The identification of the first few millimeters of the cathode region of the cell as the sink for most of the energy input into the process provides the potential for improving efficiency by concentrating the second year effort on intervention in that region. Information gathered about differences in FTIR spectra as a function of location in the dewatering cell will be investigated. Changes in pH with temperature and by the application of electroosmotic current flow will receive attention, as well. 178 refs., 16 figs.

  8. Synthesis, characterization, and secondary sludge dewatering performance of a novel combined silicon-aluminum-iron-starch flocculant.

    Science.gov (United States)

    Lin, Qintie; Peng, Huanlong; Zhong, Songxiong; Xiang, Jiangxin

    2015-03-21

    Flocculation is one of the most widely used cost-effective pretreatment method for sludge dewatering, and a novel environmentally friendly and efficient flocculant is highly desired in the sludge dewatering field. In this study, a novel combined silicon-aluminum-ferric-starch was synthesized by grafting silicon, aluminum, and iron onto a starch backbone. The synthesized starch flocculant was characterized using Fourier-transform infrared spectroscopy (FTIR), scanning electron microscopy, X-ray powder diffraction, and thermogravimetric analysis. The dewatering performance of secondary sludge was evaluated according to the capillary suction time, settling volume percentage, and specific resistance to filtration. The results indicated that the copolymer exhibited: (1) a good dewatering efficiency over a wide pH range of 3.0-11.0, (2) superior sludge dewatering performance compared to those of polyaluminum chloride (PACl), polyacrylamide (PAM), ferric chloride, and (3) a discontinuous surface with many channels or voids that helps to mobilize the impermeable thin layer of secondary sludge during filter pressing. Such a novel copolymer is a promising green flocculant for secondary sludge dewatering applications.

  9. Experimental study on dewatering and consolidation of sludge from environment dredging by using geotextile tubes%土工管袋用于环保疏浚淤泥脱水固结的试验研究

    Institute of Scientific and Technical Information of China (English)

    王琦; 仰建国; 范文雪

    2014-01-01

    The dewatering and consolidation experiment of sludge from environmental is carried out by using small-sized geo-textile tubes. The influences of different structural characteristics of geotextile tubes such as weaving method,weaving structure and aperture,and dosages of dewatering agent on its dewatering and consolidation effects are studied. The results show that the dewatering and consolidation effect of the woven twill geotextile tube with 0.5 mm aperture is better. And the effect of cationic polyacrylamide (CPAM) in the dosage of 0.6~1.0 g/kg is also better. But the best dosage must be adjusted according to the different conditions in the practical projects.%利用小型土工管袋进行环保疏浚淤泥脱水固结试验,研究土工管袋的不同结构特征(织造方式、织造结构、等效孔径)和脱水药剂用量对环保疏浚淤泥脱水固结的影响。试验结果表明:脱水药剂阳离子聚丙烯酰胺(CPAM)在0.6~1.0 g/kg投加量下配合0.5 mm等效孔径机织斜纹土工管袋组合,在疏浚淤泥脱水固结方面表现较好,但脱水药剂具体最佳用量需在实际工程中根据不同工况做适当调整。

  10. A Case Study on Stratified Settlement and Rebound Characteristics due to Dewatering in Shanghai Subway Station

    Directory of Open Access Journals (Sweden)

    Jianxiu Wang

    2013-01-01

    Full Text Available Based on the Yishan Metro Station Project of Shanghai Metro Line number 9, a centrifugal model test was conducted to investigate the behavior of stratified settlement and rebound (SSR of Shanghai soft clay caused by dewatering in deep subway station pit. The soil model was composed of three layers, and the dewatering process was simulated by self-invention of decompressing devise. The results indicate that SSR occurs when the decompression was carried out, and only negative rebound was found in sandy clay, but both positive and negative rebound occurred in the silty clay, and the absolute value of rebound in sandy clay was larger than in silty clay, and the mechanism of SSR was discussed with mechanical sandwich model, and it was found that the load and cohesive force of different soils was the main source of different responses when decompressed.

  11. Dewatering studies of fine clean coal. Technical report, September 1, 1991--November 30, 1991

    Energy Technology Data Exchange (ETDEWEB)

    Parekh, B.K.

    1991-12-31

    Physical cleaning of ultra-fine coal using an advanced froth flotation technique provides a low ash product, however, the amount of water associated with clean coal is high. Economic removal of water from the froth will be important for commercial applicability of advanced froth flotation processes. The main objective of the present research program is to study and understand the dewatering characteristics of ultra-fine clean coal and to develop the process parameters to effectively reduce the moisture to less than 20 percent in the clean coal product. The research approach under investigation utilizes synergistic effects of metal ions and surfactant to lower the moisture of clean coal using a conventional vacuum dewatering technique. During the last year`s effort, it was reported that a combination of metal ion and surfactant provided a 22 percent moisture filter cake.

  12. Dewatering studies of fine clean coal. [Quarterly] technical report, December 1, 1991--February 29, 1992

    Energy Technology Data Exchange (ETDEWEB)

    Parekh, B.K. [Kentucky Univ., Lexington, KY (United States). Center for Applied Energy Research

    1992-08-01

    Physical cleaning of ultra-fine coal using an advanced froth flotation techniques provides a low ash product, however, due to high surface area of particles the amount of water associated with clean coal is high. Economic removal of water from the froth will be important for commercial applicability of advanced froth flotation processes. The main objective of the present research program is to study and understand the dewatering characteristics of ultra-fine clean coal and to develop process parameters to effectively reduce the moisture to less than 20 percent in the clean coal product. The research approach under investigation utilizes synergistic effects of metal ions and surfactant to lower the moisture of clean coal using a conventional vacuum dewatering technique. The studies have identified a combination of metal ion and surfactant found to be effective in providing a 22 percent moisture filter cake.

  13. Application of organic polymeric fiocculants in centrifugal dewatering of oil refinery sludge

    Institute of Scientific and Technical Information of China (English)

    2003-01-01

    In order to evaluate the applicability of the organic polymeric floeculants(OPF) in the treatment of oil refinery sludge, experimentswere conducted to show that OPF have better performance of flocculation than inorganic flocculants. Both the anionic and cationic OPF havesatisfactory flocculation efficiency in oil sludge treatment, but the latter are more cost-efficient. Among the over 20 types of flocculants tested,2OPF(CPAM-2 and HPAM-2) were selected as the treatment agents, based on their good treatment performances, oil-resistance and economicfeasibility. It was demonstrated in the industrial-scale centrifugal dewatering experiments that the application of either CPAM-2 or HPAM-2could achieve high treatment efficiency of the oil sludge dewatering and reduce the COD of centrifugal liquid to less than 1000 mg/L.

  14. Nitrogen removal from sludge dewatering effluent through anaerobic ammonia oxidation process

    Institute of Scientific and Technical Information of China (English)

    ZHANG Shao-hui; ZHENG Ping; HUA Yu-mei

    2005-01-01

    Anaerobic ammonia oxidation(Anammox) process is a novel and promising wastewater nitrogen removal process. The feasibility of transition of Anammox from denitrification and the performance of lab-scale Anammox biofilm reactor were investigated with sludge dewatering effluent. The results showed that Anammox process could be successfully started up after cultivation of denitrification biofilm and using it as inoculum. The transition of Anammox from denitrification was accomplished within 85 d. Anammox process was found suitable to remove ammonia from sludge dewatering effluent. The effluent ammonia concentration was detected to be 23.11 mgN/L at HRT of 28 h when influent ammonia concentration was fed 245 mgN/L, which was less than that for the national discharge standard Ⅱ (25 mgN/L) of 243.25 mg NH4+ -N/L and 288.31 mg NO2- -N/L.

  15. Harmless treatment of used foundry sands and dewatered municipal sludge by microwave

    Directory of Open Access Journals (Sweden)

    H. F. Wang

    2015-07-01

    Full Text Available A new method to treat four solid wastes of sodium silicate used sands, dewatered municipal sludge, clay sands sludge and waste polyethylene, was discussed. About wt/ 50 % sodium silicate used sands and wt/ 50 % dewatered sludge were mixed, and then cured by microwave with a certain thickness film of clay sands sludge and waste plastic of polyethylene in the surface. The results showed that the compression strength of granulation sample with the size of Ф 50 × 50 mm was over 0,45 MPa. The waste plastic was the key factor for the durability, and curing temperature must be over melting temperature, so the thicker film could be coated in the surface of used sands and sludge.

  16. Does pH influence soil hydro-mechanical properties?

    Science.gov (United States)

    Chaplain, V.; Défossez, P.; Delarue, G.; Dexter, A. R.; Richard, G.; Tessier, D.

    2009-04-01

    Does pH influence soil hydro-mechanical properties ? V. Chaplain1, P. Défossez2, G. Delarue1, A.R. Dexter3, G. Richard3 and D. Tessier1. 1 UR INRA PESSAC RD 10, F-78026 Versailles cedex 2 UMR INRA/URCA FARE, 2 Esplanade Roland Garros, BP 224 F-51686 Reims cedex 2 3 UR INRA Sols 2163 Avenue de la Pomme de Pin - CS 40001 ARDON F-45075 Orléans Cedex 2 Corresponding author : chaplain@versailles.inra.fr Structure of soils and its dynamic, physico-chemistry of the interface are of a great importance in the fate of organic pollutants because it governs the accessibility of pollutants to micro-organisms. The soil structure of soils is related to physical parameters (texture, density, water content) but the physico-chemical properties of the interface is not considered. In this study we performed hydro-mechanical measurements on soil samples taken from the 42-plot long-term experiment in Versailles. Indeed six plots were selected to cover a large range of pH values from acid (3.5) to alkaline (8.2) due to the repeated application of fertilizers. Soils were taken in the 0-20 cm and in the 30-35 cm layer out of the ploughed zone. All soils had similar texture and composition with low organic carbon. Therefore pH changes the surface charges and hydrophobicity that are implied in aggregation process. The two layers had the same pH values. The precompression stress Pc and the compression index Cc were derived from confined compression tests performed on remoulded soil samples (density 1.45 g/cm3) at saturation. Results shows that the precompression stress increased at pH lower than 4. In acid case, precompression stress was higher in subsoil. This increase of Pc was attributed to the hydrophobicity due in part to the condensation of charges probably sensitive to the humectation/dessication processes.

  17. Influence of substituent type on properties of starch derivates

    Directory of Open Access Journals (Sweden)

    Stojanović Željko P.

    2010-01-01

    Full Text Available The subject of the study was investigation of influence of substituent type on the properties of starch derivates in diluted solutions. Three samples were prepared: two anionic (carboxymethyl starch, CMS and one cationic starch (KS. Starch derivates were synthesized in two steps. The first step was preparation of alkali starch by the addition of sodium-hydroxide to the starch dispersed in ethanol or water. In the second step, the required amount of sodium monocloracetate or 3-chloro-2-hydroxypropyl-threemethylamonium chloride was added to the obtained alkali starch in order to prepare CMS or KS, respectively. The degree of substitution of carboxymethyl starch was determined by back titration method, and the degree of substitution of cationic starch was determined by potentiometric titration. The degrees of substitution of prepared samples were: 0.50 (assigned as CMS-0.50 and 0.70 (assigned as CMS-0.70 for carboxymethyl starch and 0.30 (assigned as KS-0.30 for cationic starch. The properties of starch derivatives in dilute solutions were investigated by the methods of static and dynamic light scattering. Aqueous solutions of sodium chloride of different concentrations were used as solvent. The values of the mass average molar mass, MW, radius of gyration, Rg, and second virial coefficient, A2, were determined for all samples together with hydrodynamic radius, Rh. Molar masses of the samples were: 5.06×106, 15.4×106 and 19.2×106 g/mol for CMS-0.50, CMS-0.70 and KS-0.30, respectively. The samples, CMS-0.70 and KS-0.30 had similar molar mass and hydrodynamic radius, but radius of gyration of KS-0.30 was smaller then radius of gyration of CMS-0.70 at all sodium chloride concentrations. Consequently, ρ value for KS-0.30 was smaller then for CMS-0.70, as a result of more compact architecture of KS-0.30 then of CMS-0.70. Kratky graph confirmed this result. For all samples, radius of gyration and hydrodynamic radius decreased with increasing of

  18. Influence of Particle Size on Properties of Expanded Graphite

    Directory of Open Access Journals (Sweden)

    Kurajica, S

    2010-02-01

    Full Text Available Expanded graphite has been applied widely in thermal insulation, adsorption, vibration damping, gasketing, electromagnetic interference shielding etc. It is made by intercalation of natural flake graphite followed by thermal expansion. Intercalation is a process whereby an intercalant material is inserted between the graphene layers of a graphite crystal. Exfoliation, a huge unidirectional expansion of the starting intercalated flakes, occurs when the graphene layers are forced apart by the sudden decomposition and vaporization of the intercalated species by thermal shock. Along with production methodologies, such as the intercalation process and heat treatment, the raw material characteristics, especially particle size, strongly influence the properties of the final product.This report evaluates the influence of the particle size of the raw material on the intercalation and expansion processes and consequently the properties of the exfoliated graphite. Natural crystalline flake graphite with wide particle diameter distribution (between dp = 80 and 425 µm was divided into four size-range portions by sieving. Graphite was intercalated via perchloric acid, glacial acetic acid and potassium dichromate oxidation and intercalation procedure. 5.0 g of graphite, 7.0 g of perchloric acid, 4.0 g of glacial acetic acid and 2.0 g of potassium dichromate were placed in glass reactor. The mixture was stirred with n = 200 min–1 at temperature of 45 °C during 60 min. Then it was filtered and washed with distilled water until pH~6 and dried at 60 °C during 24 h. Expansion was accomplished by thermal shock at 1000 °C for 1 min. The prepared samples were characterized by means of exfoliation volume measurements, simultaneous differential thermal analysis and thermo-gravimetry (DTA/TGA, X-ray diffraction (XRD, Fourier transform infrared spectroscopy (FTIR, BET measurements and scanning electron microscopy (SEM.X-ray diffraction indicated a change of distance

  19. Hydrophobic Dewatering of Fine Coal. Topical report, March 1, 1995-March 31, 1997

    Energy Technology Data Exchange (ETDEWEB)

    Yoon, R.; Sohn, S.; Luttrell, J.; Phillips, D.

    1997-12-31

    Many advanced fine coal cleaning technologies have been developed in recent years under the auspices of the U.S. Department of Energy. However, they are not as widely deployed in industry as originally anticipated. An important reason for this problem is that the cleaned coal product is difficult to dewater because of the large surface area associated with fine particles. Typically, mechanical dewatering, such as vacuum filtration and centrifugation, can reduce the moisture to 20-35% level, while thermal drying is costly. To address this important industrial problem, Virginia Tech has developed a novel dewatering process, in which water is displaced from the surface of fine particulate materials by liquid butane. Since the process is driven by the hydrophobic interaction between coal and liquid butane, it was referred to as hydrophobic dewatering (HD). A fine coal sample with 21.4 pm median size was subjected to a series of bench-scale HD tests. It was a mid-vol bituminous coal obtained from the Microcel flotation columns operating at the Middle Fork coal preparation plant, Virginia. All of the test results showed that the HD process can reduce the moisture to substantially less than 10%. The process is sensitive to the amount of liquid butane used in the process relative to the solids concentration in the feed stream. Neither the intensity nor the time of agitation is critical for the process. Also, the process does not require long time for phase separation. Under optimal operating conditions, the moisture of the fine coal can be reduced to 1% by weight of coal.

  20. An experimental investigation of microalgal dewatering efficiency of belt filter system

    Directory of Open Access Journals (Sweden)

    Anjali Sandip

    2015-11-01

    Full Text Available The objective of this study was to investigate the microalgal dewatering efficiency of a belt filter system for feed concentrations below 10 g dry wt./L. A prototype belt filtration system designed for 50 g dry wt./L microalgal feed concentration was used for this investigation. The highest concentration of microalgal suspension available for testing on the prototype belt filtration system was 6 g dry wt./L obtained from biomass settling tanks at the Lawrence, Kansas domestic wastewater treatment plant. For preparation of feed suspension with concentrations below 10 g dry wt./L, microalgal cultivation was followed by flocculation. A mixed laboratory culture of freshwater species dominated by three eukaryotic green microalgae (Chlorella vulgaris, Scenedesmus sp., and Kirchneriella sp. was cultivated in wastewater effluent. This was followed by flocculation which resulted in a microalgal feed suspension concentration of 4 g dry wt./L. Belt dewatering tests were conducted on microalgal suspensions with feed concentrations of 4 g dry wt./L and 6 g dry wt./L. The maximum microalgal recovery with the belt dewatering system was 46% from the 4 g dry wt./L, and 84% from the 6 g dry wt./L suspensions respectively. The results of this study indicate that microalgal suspension concentrations as low as 6 g dry wt./L can be recovered with a belt filter system improving the overall dewatering efficiency of the system.

  1. Dewatering and low-temperature pyrolysis of oily sludge in the presence of various agricultural biomasses.

    Science.gov (United States)

    Zhao, Song; Zhou, Xiehong; Wang, Chuanyi; Jia, Hanzhong

    2017-08-24

    Pyrolysis is potentially an effective treatment of waste oil residues for recovery of petroleum hydrocarbons, and the addition of biomass is expected to improve its dewatering and pyrolysis behavior. In this study, the dewatering and low-temperature co-pyrolysis of oil-containing sludge in the presence of various agricultural biomasses, such as rice husk, walnut shell, sawdust, and apricot shell, were explored. As a result, the water content gradually decreases with the increase of biomass addition within 0-1.0 wt % in original oily sludge. Comparatively, the dewatering efficiency of sludge in the presence of four types of biomasses follows the order of apricot shell > walnut shell > rice husk > sawdust. On the other hand, rice husk and sawdust are relatively more efficient in the recovery of petroleum hydrocarbons compared with walnut shell and apricot shell. The recovery efficiency generally increased with the increase in the biomass content in the range of 0-0.2 wt %, then exhibited a gradually decreasing trend with the increase in the biomass content from 0.2 to 1.0 wt %. The results suggest that optimum amount of biomass plays an important role in the recovery efficiency. In addition, the addition of biomass (such as rice husk) also promotes the formation of CxHy and CO, increasing the calorific value of pyrolysis residue, and controlled the pollution components of the exhaust gas discharged from residue incineration. The present work implies that biomass as addictive holds great potential in the industrial dewatering and pyrolysis of oil-containing sludge.

  2. Dewatering of ashes from mixed fuels. Experiences and results from Tekniska Verken in Linkoeping; Avvattning av aska fraan blandbraenslen. Erfarenheter och resultat fraan Tekniska Verken i Linkoeping

    Energy Technology Data Exchange (ETDEWEB)

    Carlson, Ulf; Fredriksson, Anders; Lindahl, Inge [Tekniska Verken i Linkoeping AB (Sweden); Arevius, Anna; Sjoeblom, Rolf [AaF-Energikonsult AB, Stockholm (Sweden)

    2003-12-01

    Unit 3 at Tekniska Verken i Linkoeping (TVL) has a grid type furnace. During the firing season 2000 - 2001, the fuel has been comprising 45 % recovered wood chip, 45 % bark and 10 % recovered plastic material. The outfeed has been wet, and flyash and bottom ash have been mixed in the process. During 1999, about 19,000 tonnes of ash with a water content of about 50 % have been generated. The procedure has implied drawbacks in the form of handling of sludge and disposal of material with a high water content. The purpose of the work carried out has been to provide a basis for design of a handling in which these drawbacks have been eliminated, and which supports other destinations for the bottom ash than disposal. The search for information showed that a number of reactions, in particular hydratisation and recrystallisation, take place when ash is in contact with water. The process is strongly dependent on the chemical composition of the ash. The result is influenced not only by the chemical reactions that occur but also by the order in which they take place. Fly ash is very reactive while bottom ash is relatively inert. The experiments in the laboratory scale showed that bottom ash drained well while fly ash as well as different mixtures of fly ash and bottom ash are relatively impermeable to water. The ageing experiments which were carried out did not indicate any particular alteration in the permeability. Tests on a reduced scale clearly showed that bottom ash drains rapidly without the aid of vacuum and that the field capacity (the relative amount of water which does not drain) is low. Mixtures of bottom ash and fly ash drained more when vacuum was applied. However, such mixtures cured within a few hours and this lead to a substantial decrease in permeability. Tests on a pilot scale were conducted using three different methods of dewatering. The tests on self-percolation showed that most of the drainage water appeared during the first few hours where after the

  3. Simple systems for treating pumped, turbid water with flocculants and a geotextile dewatering bag.

    Science.gov (United States)

    Kang, Jihoon; McLaughlin, Richard A

    2016-11-01

    Pumping sediment-laden water from excavations is often necessary on construction sites. This water is often treated by pumping it through geotextile dewatering bags. The bags are not designed to filter the fine sediments that create high turbidity, but dosing with a flocculant prior to the bag could result in greater turbidity control. This study compared two systems for introducing flocculant: passive dosing of commercial solid biopolymer (chitosan) and injection of dissolved polyacrylamide (PAM) in a length of corrugated pipe connected to the bag. The biopolymer system consisted of sequential porous socks containing a "charging agent" followed by chitosan in the corrugated pipe with two levels of dosing. The dissolved PAM was injected into turbid water at a flow-weighted concentration at 1 mg L(-1). For each treatment, sediment-laden turbid water in the range of 2000 to 3500 nephelometric turbidity units (NTU) was pumped into the upstream of corrugated pipe and samples were taken from pipe entrance, pipe exit, and dewatering bag exit. Without flocculant treatment, the dewatering bag reduced turbidity by 70% but the addition of flocculant increased the turbidity reduction up to 97% relative to influent. At the pipe exit, the low-dose biopolymer was less effective in reducing turbidity (37%) but it was equally effective as the high-dose biopolymer or PAM injection after the bag. Our results suggest that a relatively simple treatment with flocculants, either passively or actively, can be very effective in reducing turbidity for pumped water on construction sites.

  4. Ecotoxicological assessment of dewatered drinking water treatment residue for environmental recycling.

    Science.gov (United States)

    Yuan, Nannan; Wang, Changhui; Wendling, Laura A; Pei, Yuansheng

    2016-11-18

    The beneficial recycle of drinking water treatment residue (DWTR) in environmental remediation has been demonstrated in many reports. However, the lack of information concerning the potential toxicity of dewatered DWTR hinders its widespread use. The present study examined the ecotoxicity of dewatered aluminum (Al) and iron (Fe) DWTR leachates to a green alga, Chlorella vulgaris. Data from the variations of cell density and chlorophyll a content suggested that algal growth in DWTR leachates was inhibited. The algal cellular oxidation stress was initially induced but completely eliminated within 72 h by antioxidant enzymes. The expression of three photosynthesis-related algae genes (psaB, psbC, and rbcL) also temporarily decreased (within 72 h). Moreover, the algal cells showed intact cytomembranes after exposure to DWTR leachates. Further investigation confirmed that inhibition of algal growth was due to DWTR-induced phosphorus (P) deficiency in growth medium, rather than potentially toxic contaminants (e.g. copper and Al) contained in DWTR. Interestingly, the leachates could potentially promote algal growth via increasing the supply of new components (e.g. calcium, kalium, magnesium, and ammonia nitrogen) from DWTR. In summary, based on the algae toxicity test, the dewatered Fe/Al DWTR was nontoxic and its environment recycling does not represent an ecotoxicological risk to algae.

  5. Influence of Weave on Fabric Wrinkle Recovery Property before and after Resin Treatment

    Institute of Scientific and Technical Information of China (English)

    马海青; 周翔

    2001-01-01

    Cotton fabrics with different weaves are designed and the influence of weave on wrinkle recovery property and tensile property is analyzed. Weave type plays a prominent part in determining fabric wrinkle recovery property and tensile property. Weave factor C is in direct relation to wrinkle recovery angle and in inverse relation to tensile property. This trend also exists after resin treatment. 3/1 left-twill fabric shows good wrinkle recovery angle and lest tensile loss after resin treatment.

  6. Influence of temperature on characteristics properties of flexible coupling

    OpenAIRE

    2012-01-01

    The presented article deals with issue of characteristics changes of flexible shaft couplings used in drive systems of transport devices (dynamic torsional stiffness and damping coefficient) which is caused by influence of increase or decrease of flexible elements temperature. The influence is presented on a unit and percentage change of dynamic characteristics of four selected flexible couplings with rubber, plastic and pneumatic flexible elements. Identification of influence of flexible ele...

  7. Sensory properties of marinated herring ( Clupea harengus ) - influence of fishing ground and season

    DEFF Research Database (Denmark)

    Nielsen, Durita; Hyldig, Grethe; Nielsen, Henrik Hauch

    2004-01-01

    fillets. Fishing ground did not influence the odor, flavor or texture, but there was an apparent effect of season on the sensory profile. The sensory properties were influenced by body weight, but not by age, sex and gonad maturity. The influence of varying lipid content, water content and liquid holding...

  8. CHOSEN FACTORS INFLUENCING MICROSTRUCTURE AND MECHANICAL PROPERTIES OF AUSTEMPERED DUCTILE IRON

    Directory of Open Access Journals (Sweden)

    Alan Vaško

    2009-10-01

    Full Text Available The paper deals with some factors influencing microstructure and mechanical properties of austempered ductile iron (ADI. Final structure and properties of ADI are obtained by exactly controlled process of heat treatment of nodular cast iron. The influence of conditions of isothermal heat treatment on microstructure and mechanical properties of austempered ductile iron, especially different temperature of isothermal transformation of austenite and different holding time at this temperature, is shown in the paper.

  9. CHOSEN FACTORS INFLUENCING MICROSTRUCTURE AND MECHANICAL PROPERTIES OF AUSTEMPERED DUCTILE IRON

    OpenAIRE

    Alan Vaško

    2009-01-01

    The paper deals with some factors influencing microstructure and mechanical properties of austempered ductile iron (ADI). Final structure and properties of ADI are obtained by exactly controlled process of heat treatment of nodular cast iron. The influence of conditions of isothermal heat treatment on microstructure and mechanical properties of austempered ductile iron, especially different temperature of isothermal transformation of austenite and different holding time at this temperature, i...

  10. Scale-down of continuous filtration for rapid bioprocess design: Recovery and dewatering of protein precipitate suspensions.

    Science.gov (United States)

    Reynolds, T; Boychyn, M; Sanderson, T; Bulmer, M; More, J; Hoare, M

    2003-08-20

    The early specification of bioprocesses often has to be achieved with small (tens of millilitres) quantities of process material. If extensive process discovery is to be avoided at pilot or industrial scale, it is necessary that scale-down methods be created that not only examine the conditions of process stages but also allows production of realistic output streams (i.e., streams truly representative of the large scale). These output streams can then be used in the development of subsequent purification operations. The traditional approach to predicting filtration operations is via a bench-scale pressure filter using constant pressure tests to examine the effect of pressure on the filtrate flux rate and filter cake dewatering. Interpretation of the results into cake resistance at unit applied pressure (alpha) and compressibility (n) is used to predict the pressure profile required to maintain the filtrate flux rate at a constant predetermined value. This article reports on the operation of a continuous mode laboratory filter in such a way as to prepare filter cakes and filtrate similar to what may be achieved at the industrial scale. Analysis of the filtration rate profile indicated the filter cake to have changing properties (compressibility) with time. Using the insight gained from the new scale-down methodology gave predictions of the flux profile in a pilot-scale candle filter superior to those obtained from the traditional batch filter used for laboratory development.

  11. On the Modelling of Mechanical Dewatering in Papermaking

    OpenAIRE

    Lobosco, Vinicius

    2004-01-01

    Most of the water fed into a paper machine is removedmechanically in the forming and press sections. One of thefactor which has an important influence on mechanicaldewatering, i.e. in both forming and pressing, is thestress-strain behaviour of the fibre network. The focus of this thesis is on the development of improvedmathematical descriptions of the stress-strain behaviourexhibited by fibre networks in the forming and press sections.The first part of the thesis presents a physically based m...

  12. 纤维素酶对废纸浆废水生化污泥脱水性能的影响%Effect of cellulase on sludge dewatering performance of recovered pulp wastewater

    Institute of Scientific and Technical Information of China (English)

    张安龙; 赵登; 景立明; 罗清

    2014-01-01

    采用纤维素酶处理废纸浆废水生化污泥,讨论了其影响因素.通过单因素实验和正交试验得到最佳工艺条件:酶用量为2.25U·g -1,温度为55℃,反应时间为75min,其处理后污泥的沉降性能得到很大程度的改善.红外光谱图和电镜扫描分析表明:经酶处理后污泥化学性质发生改变,细小颗粒污泥均匀分布,其污泥的结构紧密易实现固液分离,从而提高了污泥脱水性能.%The cellulase is applied in the treatment of biochemical sludge of recovered pulp wastewater and the influencing factors are discussed in this paper .Through the single factor experiment and orthogonal experiment to determine the optimal reaction conditions ,the re-sults show that :when dosage of enzyme is 2 .25 U · g -1 ,the temperature is 55 ℃ ,the reac-tion time is 75 min ,and the sludge settling properties has a large degree of improvement . Infrared spectrum and SEM analysis showed that cellulase treatment biochemical sludge can make sludge chemical properties change and fine granular sludge uniformly distribute ,then the compact sludge structure is easy to realize solid-liquid separation ,thereby improving the dewatering performance of sludge .

  13. Influence of Simulated Outside-Reactor Irradiation on Anticorrosion Property of Austenitic Stainless Steel

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    The influence of γ-ray irradiation on the properties of inside-reactor stainless steel structures was studied by simulating the working condition of pressurized water reactor (PWR) first circuit and the outside-reactor γ-ray irradiation. The result shows that the simulated outside-reactor irradiation (irradiation dose 4.4 × 104 Gy) has no influence on anticorrosion properties of solutionized SUS304 austenitic stainless steel, including intergranular corrosion (IC) and stress corrosion cracking (SCC). Anticorrosion properties (IC, SCC) of sensitized SUS304 austenitic stainless steel are reduced by simulated outside-reactor irradiation. The longer the sensitizedtime is, the more obvious the influence is.

  14. Influence of the gas shielding method upon the properties of the weld joints

    Science.gov (United States)

    Chinakhov, D. A.; Sapozhkov, A. S.

    2016-11-01

    The authors consider the influence of the gas shielding method under consumable electrode welding and double-jet gas shielding together with its influence upon the processes in the arc zone and the properties of weld joints from high-strength alloyed 30HGSA steel. The authors provide the results of recent experimental research on weld joints properties improvement through changing the gas dynamics of the active shielding gas. It was established that the jet of active shielding gas has a considerable gas-dynamic influence upon weld joints formation, chemical composition, structure and properties of the weld joints from high-strength alloyed steels.

  15. Effect of Soil Washing for Lead and Zinc Removal on Soil Hydraulic Properties

    Science.gov (United States)

    Kammerer, Gerhard; Zupanc, Vesna; Gluhar, Simon; Lestan, Domen

    2017-04-01

    Soil washing as a metal pollution remediation process, especially part with intensive mixing of the soil slurry and soil compression after de-watering, significantly deteriorates physical properties of soil compared to those of non-remediated soil. Furthermore, changed physical characteristics of remediated soil influence interaction of plant roots with soil system and affect soil water regime. Remediated soils showed significant differences to their original state in water retention properties and changed structure due to the influence of artificial structure created during remediation process. Disturbed and undisturbed soil samples of remediated and original soils were analyzed. We evaluated soil hydraulic properties as a possible constraint for re-establishing soil structure and soil fertility after the remediation procedure.

  16. INFLUENCE OF MULTIPLE LAUNDERING ON COTTON SHIRTS PROPERTIES

    OpenAIRE

    TOSHIKJ, Emilija; Igor JORDANOV; DEMBOSKI, Goran; MANGOVSKA, Biljana

    2016-01-01

    White and light colored cotton men's shirts were submitted to multiple laundering with two different detergents under the same washing conditions. Powder detergent contained bleaching agent and optical brightening agents while the liquid one did not. Changes after 25 washing cycles were analyzed through mechanical, comfort and aesthetic properties and ash content. Mechanical properties were studied by measuring tensile strength and tensile elongation, comfort b...

  17. Influence of delayed pouring on irreversible hydrocolloid properties

    OpenAIRE

    Stéfani Becker Rodrigues; Carolina Rocha Augusto; Vicente Castelo Branco Leitune; Susana Maria Werner Samuel; Fabrício Mezzomo Collares

    2012-01-01

    The aim of this study was to evaluate the physical properties of irreversible hydrocolloid materials poured immediately and after different storage periods. Four alginates were tested: Color Change (Cavex); Hydrogum (Zhermack); Hydrogum 5 (Zhermack); and Hydro Print Premium (Coltene). Their physical properties, including the recovery from deformation (n = 3), compressive strength (n = 3), and detail reproduction and gypsum compatibility (n = 3), were analyzed according to ANSI/ ADA specificat...

  18. The influence of propolis on rheological properties of lipstick.

    Science.gov (United States)

    Goik, U; Ptaszek, A; Goik, T

    2015-08-01

    The aim of this work was to study the effect of propolis on the rheological and textural properties of lipsticks. The studied lipsticks were based on raw materials and contained no synthetic compounds, preservatives, fragrances or dyes. The rheological and textural properties of the prepared lipsticks, both with and without propolis, were studied as a function of temperature and storage period. Measurements were taken using an RS6000 rheometer (Haake, Germany) with a cone-plate sensor. The cone parameters were as follows: diameter 35 mm and angle 2°. Textural tests were performed using the same cone-plate geometry. The research results of rheological and textural properties of lipsticks, with and without the addition of propolis, indicate the possibility of application of propolis as a beneficial additive to such type of cosmetics. The presence of propolis does not significantly alter the viscoelastic properties of the lipsticks. The courses of flow curves indicate shear thinning, which is very advantageous from an application point of view. From the rheological point of view, the properties of lipsticks tested in low deformation conditions show some structural changes, most likely due to consolidation of the structure. The analysis of textural properties indicates that lipsticks with added propolis are more brittle and prone to crushing. However, the temperature increase (30°C) does not cause significant changes to the textural characteristics of these lipsticks. © 2015 Society of Cosmetic Scientists and the Société Française de Cosmétologie.

  19. Factors influencing property selection for conservation revolving funds.

    Science.gov (United States)

    Hardy, Mathew J; Fitzsimons, James A; Bekessy, Sarah A; Gordon, Ascelin

    2017-07-20

    Finding sustainable ways to increase the amount of private land protected for biodiversity is a challenge for many conservation organizations. In a number of countries, organizations use 'revolving fund' programs, whereby land is purchased, and then on-sold to conservation-minded owners with a condition to enter into a conservation covenant or easement. The proceeds from sale are then used to purchase, protect and on-sell additional properties, incrementally increasing the amount of protected private land. As the effectiveness of this approach relies upon selecting the right properties, we sought to explore the factors currently considered by practitioners and how these are integrated into decision-making. We conducted exploratory, semi-structured interviews with managers from each of the five major revolving funds in Australia. Responses suggest that whilst conservation factors are important, financial and social factors are also highly influential, with a major determinant being whether the property can be on-sold within a reasonable timeframe, and at a price that replenishes the fund. To facilitate the on-sale process, often selected properties include the potential for the construction of a dwelling. Practitioners are faced with clear trade-offs between conservation, financial, amenity and other factors in selecting properties; and three main potential risks: difficulty recovering the costs of acquisition, protection, and resale; difficulty on-selling the property; and difficulty meeting conservation goals. Our findings suggest that the complexity of these decisions may be limiting revolving fund effectiveness. We draw from participant responses to identify potential strategies to mitigate the risks identified, and suggest that managers could benefit from a shared learning and adaptive approach to property selection given the commonalities between programs. Understanding how practitioners are dealing with complex decisions in the implementation of revolving

  20. Effects of cationic polyacrylamide characteristics on sewage sludge dewatering and moisture evaporation.

    Directory of Open Access Journals (Sweden)

    Jun Zhou

    Full Text Available The effects of the molecular weight (MW and charge density (CD of cationic polyacrylamide (CPAM on sludge dewatering and moisture evaporation were investigated in this study. Results indicated that in sludge conditioning, the optimum dosages were 10, 6, 6, 4, and 4 mg g(-1 CPAM with 5 million MW and 20% CD, 5 million MW and 40% CD, 3 million MW and 40% CD, 8 million MW and 40% CD, and 5 million MW and 60% CD, respectively. The optimum dosage of CPAM was negatively correlated with its CD or MW if the CD or MW of CPAM was above 20% or 5 million. In the centrifugal dewatering of sludge, the moisture content in the conditioned sludge gradually decreased with the extension of centrifugation time, and the economical centrifugal force was 400×g. The moisture evaporation rates of the conditioned sludge were closely related to sludge dewaterability, which was in turn significantly correlated either positively with the solid content of sludge particles that were >2 mm in size or negatively with that of particles measuring 1 mm to 2 mm in diameter. During treatment, sludge moisture content was reduced from 80% to 20% by evaporation, and the moisture evaporation rates were 1.35, 1.49, 1.62, and 2.24 times faster in the sludge conditioned using 4 mg g(-1 CPAM with 5 million MW and 60% CD than in the sludge conditioned using 4 mg g(-1 CPAM with 8 million MW and 40% CD, 6 mg g(-1 CPAM with 5 million MW and 40% CD, 6 mg g(-1 CPAM with 3 million MW and 40% CD, and 10 mg g(-1 CPAM with 5 million MW and 20% CD, respectively. Hence, the CPAM with 5 million MW and 60% CD was ideal for sludge dewatering.

  1. Dewatering studies of fine clean coal. Technical report, March 1, 1992--May 31, 1992

    Energy Technology Data Exchange (ETDEWEB)

    Parekh, B.K. [Kentucky Univ., Lexington, KY (United States). Center for Applied Energy Research

    1992-10-01

    Physical cleaning of ultra-fine coal using an advanced froth flotation technique provides a low ash product, however, due to high surface area of particles the amount of water associated with clean coal is high. Economic removal of water to 20 percent or lower moisture level from the clean coal froth will be important for commercial applicability of advanced froth flotation processes. The main objective of the present research program is to study and understand the dewatering characteristics of ultra-fine clean coal and to develop process parameters to effectively reduce the moisture to less than 20 percent in the clean coal product. The research approach under investigation utilizes synergistic effect of metal ions and surfactant to lower the moisture of clean coal using a conventional vacuum dewatering technique. The studies have identified a combination of metal ions and surfactant found to be effective in providing a 22 percent moisture filter cake. During the third quarter, efforts were made to understand reagent adsorption mechanism. Adsorption studies indicated that the presence of metal ions enhanced adsorption of surfactant. It appears that metal ions induced floc formation at pH {approximately}7.0, which are hydrophilic in nature, however addition of surfactant restores the hydrophobicity. Organic polymers along with metal ions were found to be effective in dewatering of fine coal. Continuous filtration tests conducted using a drum filter provided a filter cake containing 24 percent moisture. Additional studies on mechanism of adsorption and continuous filtration using AC Electro-Coagulation will be conducted in the next quarter.

  2. Dewatering studies of fine clean coal. Final technical report, September 1, 1991--August 31, 1992

    Energy Technology Data Exchange (ETDEWEB)

    Parekh, B.K. [Kentucky Univ., Lexington, KY (United States). Center for Applied Energy Research

    1992-12-31

    Physical cleaning of ultra-fine coal using advanced froth flotation technique provides a low ash product; however, the amount of water associated with clean coal is high. Economic removal of water from the froth will be important for commercial applicability of the advanced flotation processes. The main objective of the present research program is to study and understand dewatering characteristics of ultra-fine clean coal and to develop process parameters to effectively reduce the moisture to less than 20 percent in the clean coal product. The research approach utilized synergistic effect of metal ions and surfactant addition to lower the moisture of clean coal using the conventional vacuum dewatering technique. The studies have identified a combinations of metal ions and surfactants in providing a 22 percent moisture filter cake. Surface chemical study indicated a direct correlation between the point-of-zero charge (PZC) of metal ion/fine coal system and lowering of moisture in the filter cake. Adsorption of either metal ions or surfactants alone did not provide a significant reduction of moisture in the filter cake. However, a combination of the two provided a filter cake containing about 22 percent moisture. Filtration tests conducted using a laboratory vacuum drum filter indicated that the results obtained in batch filtration could be reproduced on a continuous filtration unit. FT-IR studies indicated that anionic surfactant and metal ions form complex species which adsorbs on the fine coal and results in improved moisture reduction during filtration. Recommendations are offered for testing this novel dewatering process on a pilot scale at a coal preparation plant in Illinois.

  3. Biodegradation and chemical precipitation of dissolved nutrients in anaerobically digested sludge dewatering centrate.

    Science.gov (United States)

    Galvagno, G; Eskicioglu, C; Abel-Denee, M

    2016-06-01

    The objective of this research was to assess specific side-stream treatment processes for biodegradation and precipitation of dissolved nutrients in dewatering centrate. In this study, characterization was made of a conventional suspended growth deammonification treatment process for transforming dissolved polyphosphate (poly-P), dissolved organic phosphorus (DOP) and dissolved organic nitrogen (DON) in two types of dewatering centrate. The deammonification process was configured as a sequencing batch reactor (SBR), combining partial nitrification and anaerobic ammonia oxidation (anammox) in a single tank. The first centrate feed studied was from the full-scale Annacis Island wastewater treatment plant (AIWWTP) located in Metro Vancouver, Canada. The second centrate feed was from a lab-scale anaerobic digester (AD) fed waste sludge from the existing City of Kelowna Wastewater Treatment Facility (KWTF), located in the Okanagan Valley, Canada. In addition, poly aluminum chloride (PACL) dosing was assessed for final polishing of dissolved nutrients. The deammonification SBR (DeSBR) process showed similar treatment characteristics for both the KWTF and AIWWTP centrates with excellent DON removal and poor non-reactive dissolved phosphorus (NRDP) removal. A statistical comparison of the DOP and poly-P through the DeSBR process suggests that DOP has a higher biodegradation potential. Future research focused on understanding the variables associated with degradation of DOP could lead to better NRDP removal through deammonification processes. Utilization of a post-anammox PACL chemical dosing stage can achieve the objective of precipitating any residual DON and NRDP and producing an effluent that has lower dissolved nutrients than the pre-digestion KWTF dewatering centrate scenario.

  4. The influence of roller compaction processing variables on the rheological properties of granules

    Directory of Open Access Journals (Sweden)

    Tim Freeman

    2016-08-01

    The results demonstrate several rheological properties of the granulate, which have been shown to be closely correlated with variance in die filling and tablet strength, and are predictably influenced by the processing parameters.

  5. Environmental and centrifugal factors influencing the visco-elastic properties of oral biofilms in vitro.

    Science.gov (United States)

    Peterson, Brandon W; Busscher, Henk J; Sharma, Prashant K; van der Mei, Henny C

    2012-01-01

    Centrifugal compaction causes changes in the surface properties of bacterial cells. It has been shown previously that the surface properties of planktonic cells change with increasing centrifugal compaction. This study aimed to analyze the influences of centrifugal compaction and environmental conditions on the visco-elastic properties of oral biofilms. Biofilms were grown out of a layer of initially adhering streptococci, actinomyces or a combination of these. Different uni-axial deformations were induced on the biofilms and the load relaxations were measured over time. Linear-Regression-Analysis demonstrated that both the centrifugation coefficient for streptococci and induced deformation influenced the percentage relaxation. Centrifugal compaction significantly influenced relaxation only upon compression of the outermost 20% of the biofilm (p centrifugal compaction of initially adhering, centrifuged bacteria extend to the visco-elastic properties of biofilms, indicating that the initial bacterial layer influences the structure of the entire biofilm.

  6. Xylanase from Fusarium heterosporum: Properties and influence of ...

    African Journals Online (AJOL)

    Unioeste

    2014-02-26

    Feb 26, 2014 ... influence of thiol compounds on xylanase activity. Paulo Ricardo .... (45 kDa), carbonic anhydrase (30 kDa), trypsin inhibitor (21.1 kDa) and α-lactalbumin (14.1 ..... effects on the activity of jack bean urease. Probing the modes ...

  7. Textural evidence for jamming and dewatering of a sub-surface, fluid-saturated granular flow

    Science.gov (United States)

    Sherry, T. J.; Rowe, C. D.; Kirkpatrick, J. D.; Brodsky, E. E.

    2011-12-01

    Sand injectites are spectacular examples of large-scale granular flows involving migration of hundreds of cubic meters of sand slurry over hundreds of meters to kilometers in the sub-surface. By studying the macro- and microstructural textures of a kilometer-scale sand injectite, we interpret the fluid flow regimes during emplacement and define the timing of formation of specific textures in the injected material. Fluidized sand sourced from the Santa Margarita Fm., was injected upward into the Santa Cruz Mudstone, Santa Cruz County, California. The sand injectite exposed at Yellow Bank Beach records emplacement of both hydrocarbon and aqueous sand slurries. Elongate, angular mudstone clasts were ripped from the wall rock during sand migration, providing evidence for high velocity, turbid flow. However, clast long axis orientations are consistently sub-horizontal suggesting the slurry transitioned to a laminar flow as the flow velocity decreased in the sill-like intrusion. Millimeter to centimeter scale laminations are ubiquitous throughout the sand body and are locally parallel to the mudstone clast long axes. The laminations are distinct in exposure because alternating layers are preferentially cemented with limonite sourced from later groundwater infiltration. Quantitative microstructural analyses show that the laminations are defined by subtle oscillations in grain alignment between limonite and non-limonite stained layers. Grain packing, size and shape distributions do not vary. The presence of limonite in alternating layers results from differential infiltration of groundwater, indicating permeability changes between the layers despite minimal grain scale differences. Convolute dewatering structures deform the laminations. Dolomite-cemented sand, a signature of hydrocarbon saturation, forms irregular bodies that cross-cut the laminations and dewatering structures. Laminations are not formed in the dolomite-cemented sand. The relative viscosity difference

  8. Influence of wheat kernel physical properties on the pulverizing process.

    Science.gov (United States)

    Dziki, Dariusz; Cacak-Pietrzak, Grażyna; Miś, Antoni; Jończyk, Krzysztof; Gawlik-Dziki, Urszula

    2014-10-01

    The physical properties of wheat kernel were determined and related to pulverizing performance by correlation analysis. Nineteen samples of wheat cultivars about similar level of protein content (11.2-12.8 % w.b.) and obtained from organic farming system were used for analysis. The kernel (moisture content 10 % w.b.) was pulverized by using the laboratory hammer mill equipped with round holes 1.0 mm screen. The specific grinding energy ranged from 120 kJkg(-1) to 159 kJkg(-1). On the basis of data obtained many of significant correlations (p kernel physical properties and pulverizing process of wheat kernel, especially wheat kernel hardness index (obtained on the basis of Single Kernel Characterization System) and vitreousness significantly and positively correlated with the grinding energy indices and the mass fraction of coarse particles (> 0.5 mm). Among the kernel mechanical properties determined on the basis of uniaxial compression test only the rapture force was correlated with the impact grinding results. The results showed also positive and significant relationships between kernel ash content and grinding energy requirements. On the basis of wheat physical properties the multiple linear regression was proposed for predicting the average particle size of pulverized kernel.

  9. The stability of piezoceramic materials properties at external influences

    Directory of Open Access Journals (Sweden)

    Kuzenko D. V.

    2010-02-01

    Full Text Available The impact of exciting electric fields (static and resonance frequency alternating, mechanical uniaxial loading and temperature on the stability of working parameters of piezoelectric ceramic elements had been investigated. It is shown that after the removal of excitation the long relaxation of properties under the law close to logarithmic is observed.

  10. THE INFLUENCE OF SOME SOIL CHEMICAL PROPERTIES ON THEIR ERODABILITY

    Directory of Open Access Journals (Sweden)

    I. C. Stanga

    2005-10-01

    Full Text Available Soils from de hills and tableland regions, as well as those from subcarpathian area are characterized through higher erodability. The soils from mountain area present the lowest erodability, especially districambosol, due to the upper horizons properties. The erodabilidydepends on the ratio of historical geological erosion and surface erosion.

  11. Size dependency and potential field influence on deriving mechanical properties of carbon nanotubes using molecular dynamics

    Directory of Open Access Journals (Sweden)

    K.G.S. Dilrukshi

    2015-07-01

    Full Text Available A thorough understanding on the mechanical properties of carbon nanotube (CNT is essential in extending the advanced applications of CNT based systems. However, conducting experiments to estimate mechanical properties at this scale is extremely challenging. Therefore, development of mechanistic models to estimate the mechanical properties of CNTs along with the integration of existing continuum mechanics concepts is critically important. This paper presents a comprehensive molecular dynamics simulation study on the size dependency and potential function influence of mechanical properties of CNT. Commonly used reactive bond order (REBO and adaptive intermolecular reactive bond order (AIREBO potential functions were considered in this regard. Young’s modulus and shear modulus of CNTs are derived by integrating classical continuum mechanics concepts with molecular dynamics simulations. The results indicate that the potential function has a significant influence on the estimated mechanical properties of CNTs, and the influence of potential field is much higher when studying the torsional behaviour of CNTs than the tensile behaviour.

  12. THE INFLUENCE OF GAS-DENSITY AND LIQUID PROPERTIES ON BUBBLE BREAKUP

    NARCIS (Netherlands)

    WILKINSON, PM; VANSCHAYK, A; SPRONKEN, JPM; VANDIERENDONCK, LL

    1993-01-01

    On the basis of a literature review of bubble breakup experiments, it is demonstrated that both liquid viscosity and surface tension have an influence on bubble stability and, thus, bubble breakup, for small as well as large bubbles. Possible influences of the gas properties on bubble breakup have u

  13. Influence of thickness on properties of plasticized oat starch films

    Directory of Open Access Journals (Sweden)

    Melicia Cintia Galdeano

    2013-08-01

    Full Text Available The aim of this study was to investigate the effect of thickness (between 80 and 120 µm on apparent opacity, water vapor permeability and mechanical properties (tensile and puncture of oat starch films plasticized with glycerol, sorbitol, glycerol:sorbitol mixture, urea and sucrose. Films were stored under 11, 57, 76 and 90% relative humidity (RH to study the mechanical properties. It was observed that the higher the thickness, the higher was the opacity values. Films without the plasticizer were more opaque in comparison with the plasticized ones. Glycerol:sorbitol films presented increased elongation with increasing thickness at all RH. Puncture force showed a strong dependence on the film thickness, except for the films plasticized with sucrose. In general, thickness did not affect the water permeability.

  14. Influence of Barium Hexaferrite on Magnetic Properties of Hydroxyapatite Ceramics.

    Science.gov (United States)

    Jarupoom, P; Jaita, P

    2015-11-01

    Hydroxyapatite (HA) powders was derived from natural bovine bone by sequence of thermal processes. The barium hexaferrite (BF) find magnetic powders were added into HA powders in ratio of 1-3 vol.%. The HA-BF ceramics were prepared by a solid state reaction method and sintered at 1250 degrees C for 2 h. Effects of BF additive on structural, physical and magnetic properties of HA ceramics were investigated. X-ray diffraction revealed that all HA-BF samples showed a main phase of high purity hydroxyapatite [Ca10(PO4)6(OH)2] with calcium and phosphate molar ratio of 1.67. The addition of BF into HA inhibited grain growth and caused an improvement of mechanical properties. The M-H hysteresis loops also showed an improvement in magnetic behavior for higher content of BF. Moreover, in vitro bioactivity test indicated that the 2-3 vol.% sample may be suitable for biological applications.

  15. Influence of impurity on electronic properties of carbon nanotube superlattices

    Directory of Open Access Journals (Sweden)

    AA Shokri

    2013-09-01

    Full Text Available   In this paper, electronic properties of single-wall armchair and zigzag carbon nanotubes (CNTs superlattices, n(12,0/m(6,6 and n(12,0/m(11,0 are investigated. For this reason, the topological defects of pentagon–heptagon pairs at interfaces of carbon hexagonal network appear. These defects break the symmetry of the system, and then change the electrical properties. The calculations include two parts: investigation of the structures in the absence and presence of the impurity effect, which are calculated by the nearest-neighbor tight binding model . Out numerical results can be useful in designing nanoelectronic devices based on carbon nanotubes.

  16. Influence of polyols on properties of bio-based polyurethanes

    Indian Academy of Sciences (India)

    S Gopalakrishnan; T Linda Fernando

    2012-04-01

    Polyurethane elastomers from cardanol-based polyol, polypropylene glycol (PPG-1200 and PPG-2000) and isophorone diisocyanate were prepared in the form of thin sheets. The sorption,mechanical and thermal properties were studied. The solubility parameter and molecular weight between crosslinks of polyurethane samples were calculated from swelling experiments. The swelling study of polyurethanes revealed that the sorption is found to decrease with an increase in chain length of PPG. The stress–strain data showed that the elastomers obtained using PPG-1200 gave the best mechanical properties. The thermal degradation of all the three elastomers starts almost at 270°C, regardless of the PPG chain length. The value of activation energy of degradation calculated using the Broido method was in the range of 40–70 kJ/mol.

  17. Influence of radiation on the properties of solar cells

    OpenAIRE

    Zdravković Miloš R.; Vasić Aleksandra I.; Radosavljević Radovan Lj.; Vujisić Miloš Lj.; Osmokrović Predrag V.

    2011-01-01

    The wide substitution of conventional types of energy by solar energy lies in the rate of developing solar cell technology. Silicon is still the mostly used element for solar cell production, so efforts are directed to the improvement of physical properties of silicon structures. There are several trends in the development of solar cells, but mainly two directions are indicated: the improvement of the conventional solar cell characteristics based on semiconductor materials, and explorin...

  18. Factors That Influence the Extensional Rheological Property of Saliva

    OpenAIRE

    Vijay, Amrita; Inui, Taichi; Dodds, Michael; Proctor, Gordon; Carpenter, Guy

    2015-01-01

    The spinnbarkeit of saliva reflects the ability of saliva to adhere to surfaces within the mouth, thereby serving as a protective role and aiding in lubrication. Therefore, alterations in the extensional rheology of saliva may result in the loss in adhesiveness or the ability to bind onto surfaces. Mucin glycoproteins and their structures are known to be important factors for the extensional rheological properties of saliva. The conformation of mucin depends on factors such as pH and ionic st...

  19. Influence of delayed pouring on irreversible hydrocolloid properties

    Directory of Open Access Journals (Sweden)

    Stéfani Becker Rodrigues

    2012-10-01

    Full Text Available The aim of this study was to evaluate the physical properties of irreversible hydrocolloid materials poured immediately and after different storage periods. Four alginates were tested: Color Change (Cavex; Hydrogum (Zhermack; Hydrogum 5 (Zhermack; and Hydro Print Premium (Coltene. Their physical properties, including the recovery from deformation (n = 3, compressive strength (n = 3, and detail reproduction and gypsum compatibility (n = 3, were analyzed according to ANSI/ADA specification no. 18. Specimens were stored at 23ºC and humidity and were then poured with gypsum immediately and after 1, 2, 3, 4, and 5 days. The data were analyzed by two-way analysis of variance (ANOVA and Tukey's test at p < 0.05. All of the alginate impression materials tested exhibited detail reproduction and gypsum compatibility at all times. Hydro Print Premium and Hydrogum 5 showed recovery from deformation, as established by ANSI/ADA specification no. 18, after 5 days of storage. As the storage time increased, the compressive strength values also increased. Considering the properties of compounds' recovery from deformation, compressive strength, and detail reproduction and gypsum compatibility, irreversible hydrocolloids should be poured immediately.

  20. Properties Influencing Plasma Discharges in Packed Bed Reactors

    Science.gov (United States)

    Kruszelnicki, Juliusz; Engeling, Kenneth W.; Foster, John E.; Kushner, Mark J.

    2016-09-01

    Atmospheric pressure dielectric barrier discharges (DBDs) sustained in packed bed reactors (PBRs) are being investigated for CO2 removal and conversion of waste gases into higher value compounds. We report on results of a computational investigation of PBR-DBD properties using the plasma hydrodynamics simulator nonPDPSIM with a comparison to experiments. Dielectric beads (rods in 2D) were inserted between two coplanar electrodes, 1 cm apart filled by humid air. A step-pulse of -30 kV was applied to the top electrode. Material properties of the beads (dielectric constant, secondary emission coefficient) and gas properties (photoionization and photo-absorption cross-sections, temperature) were varied. We found that photoionization plays a critical role in the propagation of the discharge through the PBR, as it serves to seed charges in regions of high electric field. Increasing rates of photo-ionization enable increases in the discharge propagation velocity, ionization rates and production of radicals. A transition between DBD-like and arc-like discharges occurs as the radiation mean free path decreases. Increasing the dielectric constant of the beads increased electric fields in the gas, which translated to increased discharge propagation velocity and charge density until ɛ/ɛ0 100. Secondary electron emission coefficient and gas temperature have minimal impacts on the discharge propagation though the latter did affect the production of reactive species. Work supported by US DOE Office of Fusion Energy Science and the National Science Foundation.

  1. Influence of delayed pouring on irreversible hydrocolloid properties.

    Science.gov (United States)

    Rodrigues, Stéfani Becker; Augusto, Carolina Rocha; Leitune, Vicente Castelo Branco; Samuel, Susana Maria Werner; Collares, Fabrício Mezzomo

    2012-01-01

    The aim of this study was to evaluate the physical properties of irreversible hydrocolloid materials poured immediately and after different storage periods. Four alginates were tested: Color Change (Cavex); Hydrogum (Zhermack); Hydrogum 5 (Zhermack); and Hydro Print Premium (Coltene). Their physical properties, including the recovery from deformation (n = 3), compressive strength (n = 3), and detail reproduction and gypsum compatibility (n = 3), were analyzed according to ANSI/ADA specification no. 18. Specimens were stored at 23ºC and humidity and were then poured with gypsum immediately and after 1, 2, 3, 4, and 5 days. The data were analyzed by two-way analysis of variance (ANOVA) and Tukey's test at p < 0.05. All of the alginate impression materials tested exhibited detail reproduction and gypsum compatibility at all times. Hydro Print Premium and Hydrogum 5 showed recovery from deformation, as established by ANSI/ADA specification no. 18, after 5 days of storage. As the storage time increased, the compressive strength values also increased. Considering the properties of compounds' recovery from deformation, compressive strength, and detail reproduction and gypsum compatibility, irreversible hydrocolloids should be poured immediately.

  2. The influence of the textural development on magnetic properties in Co-Cr thin films

    NARCIS (Netherlands)

    Li, Cheng-Zhang; Lodder, J.C.; Szpunar, J.A.

    1994-01-01

    Two series Co81Cr19 films (5-980 nm) were chosen to investigate the influence of textural development on magnetic properties. It was demonstrated that both the texture and the magnetic properties strongly depend on the film thickness. In the thickness range from 12 to 980 nm, the coercivity Hc and t

  3. Influence of carbon nanotubes on mechanical properties and structure of rigid polyurethane foam

    Science.gov (United States)

    Ciecierska, E.; Jurczyk-Kowalska, M.; Bazarnik, P.; Kulesza, M.; Lewandowska, M.; Kowalski, M.; Krauze, S.

    2014-08-01

    In this work, the influence of carbon nanotubes addition on foam structure and mechanical properties of rigid polyurethane foam/nanotube composites was investigated. Scanning electron microscopy was performed to reveal the foam porous structure and distribution of carbon nanotubes. To determine the mechanical properties, three point bending tests were carried out.

  4. Influence of double (w1/o/w2) emulsion composition on lubrication properties

    NARCIS (Netherlands)

    Oppermann, A.K.L.; Verkaaik, Lisa; Stieger, M.A.; Scholten, E.

    2017-01-01

    Double (w1/o/w2) emulsions are potential fat replacers in foods. Fats are known for their lubricating properties, which contribute to texture perception. It is therefore of interest to understand how the composition of double emulsions influences lubrication properties. This study focuses on the

  5. The influence of sensory product properties on affective and symbolic product experience

    NARCIS (Netherlands)

    Fenko, A.; Schifferstein, H.N.J.

    2012-01-01

    Creating pleasurable products requires understanding of the influence of sensory product properties on affective user experience and symbolic meaning of products. This paper gives an overview of a series of studies, in which we investigated the impact of sensory product properties (color, material,

  6. The Fabric of Thought: Priming Tactile Properties during Reading Influences Direct Tactile Perception

    Science.gov (United States)

    Brunye, Tad T.; Walters, Eliza K.; Ditman, Tali; Gagnon, Stephanie A.; Mahoney, Caroline R.; Taylor, Holly A.

    2012-01-01

    The present studies examined whether implied tactile properties during language comprehension influence subsequent direct tactile perception, and the specificity of any such effects. Participants read sentences that implicitly conveyed information regarding tactile properties (e.g., "Grace tried on a pair of thick corduroy pants while…

  7. The Fabric of Thought: Priming Tactile Properties during Reading Influences Direct Tactile Perception

    Science.gov (United States)

    Brunye, Tad T.; Walters, Eliza K.; Ditman, Tali; Gagnon, Stephanie A.; Mahoney, Caroline R.; Taylor, Holly A.

    2012-01-01

    The present studies examined whether implied tactile properties during language comprehension influence subsequent direct tactile perception, and the specificity of any such effects. Participants read sentences that implicitly conveyed information regarding tactile properties (e.g., "Grace tried on a pair of thick corduroy pants while…

  8. Effect of TiO2 nanoparticles on UASB biomass activity and dewatered sludge.

    Science.gov (United States)

    Yadav, Tushar; Mungray, Alka A; Mungray, Arvind K

    2017-02-01

    The accumulation of the nanowastes in the wastewater treatment plants has raised several concerns; therefore, it is an utmost priority to study the nanoparticle (NP) toxicity in such systems. In this work, the effect of TiO2 NPs on up-flow anaerobic sludge blanket (UASB) microflora and their photocatalytic effect on dewatered sludge were studied. We observed 99.98% removal of TiO2 NPs by sludge biomass within 24 h, though negligible toxicity was found up to 100 mg/L TiO2 concentration on extracellular polymeric substances (EPS), volatile fatty acid and biogas generation. The low toxicity corresponds to the agglomeration of TiO2 NPs in UASB sludge. Alterations in dewatered sludge biochemical composition and increase in cell damage were observed upon exposure to sunlight as evidenced by FTIR and fluorescent microscopy, respectively. Results suggest the negligible toxicity of TiO2 NPs on UASB biomass activity; however, once exposed to open environment and sunlight, they may exert detrimental effects.

  9. Chitosan use in chemical conditioning for dewatering municipal-activated sludge.

    Science.gov (United States)

    Zemmouri, H; Mameri, N; Lounici, H

    2015-01-01

    This work aims to evaluate the potential use of chitosan as an eco-friendly flocculant in chemical conditioning of municipal-activated sludge. Chitosan effectiveness was compared with synthetic cationic polyelectrolyte Sedipur CF802 (Sed CF802) and ferric chloride (FeCl₃). In this context, raw sludge samples from Beni-Messous wastewater treatment plant (WWTP) were tested. The classic jar test method was used to condition sludge samples. Capillary suction time (CST), specific resistance to filtration (SRF), cakes dry solid content and filtrate turbidity were analyzed to determine filterability, dewatering capacity of conditioned sludge and the optimum dose of each conditioner. Data exhibit that chitosan, FeCl₃and Sed CF802 improve sludge dewatering. Optimum dosages of chitosan, Sed CF802 and FeCl₃allowing CST values of 6, 5 and 9 s, were found, respectively, between 2-3, 1.5-3 and 6 kg/t ds. Both polymers have shown faster water removal with more permeable sludge. SRF values were 0.634 × 10¹², 0.932 × 10¹² and 2 × 10¹² m/kg for Sed CF802, chitosan and FeCl₃respectively. A reduction of 94.68 and 87.85% of the filtrate turbidity was obtained with optimal dosage of chitosan and Sed CF802, respectively. In contrast, 54.18% of turbidity abatement has been obtained using optimal dosage of FeCl₃.

  10. Bioelectrochemically-assisted anaerobic composting process enhancing compost maturity of dewatered sludge with synchronous electricity generation.

    Science.gov (United States)

    Yu, Hang; Jiang, Junqiu; Zhao, Qingliang; Wang, Kun; Zhang, Yunshu; Zheng, Zhen; Hao, Xiaodi

    2015-10-01

    Bioelectrochemically-assisted anaerobic composting process (AnCBE) with dewatered sludge as the anode fuel was constructed to accelerate composting of dewatered sludge, which could increase the quality of the compost and harvest electric energy in comparison with the traditional anaerobic composting (AnC). Results revealed that the AnCBE yielded a voltage of 0.60 ± 0.02 V, and total COD (TCOD) removal reached 19.8 ± 0.2% at the end of 35 d. The maximum power density was 5.6 W/m(3). At the end of composting, organic matter content (OM) reduction rate increased to 19.5 ± 0.2% in AnCBE and to 12.9 ± 0.1% in AnC. The fuzzy comprehensive assessment (FCA) result indicated that the membership degree of class I of AnCBE compost (0.64) was higher than that of AnC compost (0.44). It was demonstrated that electrogenesis in the AnCBE could improve the sludge stabilization degree, accelerate anaerobic composting process and enhance composting maturity with bioelectricity generation.

  11. Performance evaluation of existing wedgewater and vacuum-assisted bed dewatering systems. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Kim, B.J.; Cardenas, R.R.; Gee, C.S.; Bandy, J.T.

    1992-01-01

    Many Army wastewater treatment plants (WWTPs) use conventional sand drying beds to dewater sludge. However, sand-drying is slow, and requires a large land area commitment and manual sludge removal. Outdoor sand-drying beds are vulnerable to weather conditions and operational problems associated with sand-media and underdrain clogging. Successful new technologies for sludge treatment in small-scale WWTPs include wedgewater beds (WBs), vacuum-assisted beds (VABs) and reed-bed systems. As operator of over 100 small WWTPs, the Army has an interest in such cost effective and technically efficient sludge-dewatering systems. This study compiled operational data from commercial WWTPs with existing WBs and VABs to evaluate their potential for Army use. Generally. WBs were found to be easier to operate and maintain than VABs. WBs also showed fewer media-and underdrain-clogging problems when high-pressure hoses were used to clean the media, and when tiles were kept free from damage. VABs were preferred by smaller plants that required a lower target solids rate. Most problems with both systems were associated with poor media cleaning, front-end loader damage, and engineering errors.

  12. Bioelectrochemical desalination and electricity generation in microbial desalination cell with dewatered sludge as fuel.

    Science.gov (United States)

    Meng, Fanyu; Jiang, Junqiu; Zhao, Qingliang; Wang, Kun; Zhang, Guodong; Fan, Qingxin; Wei, Liangliang; Ding, Jing; Zheng, Zhen

    2014-04-01

    Microbial desalination cells (MDCs) with common liquid anodic substrate exhibit a slow startup and destructive pH drop, and abiotic cathodes have high cost and low sustainability. A biocathode MDC with dewatered sludge as fuel was developed for synergistic desalination, electricity generation and sludge stabilization. Experimental results indicated that the startup period was reduced to 3d, anodic pH was maintained between 6.6 and 7.6, and high stability was shown under long-term operation (300d). When initial NaCl concentrations were 5 and 10g/L, the desalinization rates during stable operation were 46.37±1.14% and 40.74±0.89%, respectively. The maximum power output of 3.178W/m(3) with open circuit voltage (OCV) of 1.118V was produced on 130d. After 300d, 25.71±0.15% of organic matter was removed. These results demonstrated that dewatered sludge was an appropriate anodic substrate to enhance MDC stability for desalination and electricity generation. Copyright © 2014 Elsevier Ltd. All rights reserved.

  13. Development of accelerated dewatering technology for managing oil sands fine fluid tailings

    Energy Technology Data Exchange (ETDEWEB)

    Lahaie, R. [Syncrude Canada Ltd., Fort McMurray, AB (Canada); Seto, J.T.C. [BGC Engineering Inc., Edmonton, AB (Canada); Chapman, D. [O' Kane Consultants Inc., Saskatoon, SK (Canada); Carrier, W.D. III [Argila Enterprises Inc., Lakeland, FL (United States)

    2010-07-01

    This article discussed an accelerated dewatering technique being applied and tested for managing fine fluid tailings produced from oil sands mining. The process involved rim ditching and a decant system to promote the drainage of surface waters and enhance the drying and densification of mature fine tailings (MFT). To field test the procedure, a deposit containing 60,000 cubic metres of in-line flocculated MFT was constructed and instrumented to monitor consolidation and dewatering response of the MFT deposit over time. Ten months after being filled, the deposit had settled about 1.2 metres, which corresponds to a 19 percent reduction in volume relative to initial filling. The field test will continue for several more years, during which time the deposit will continue to be monitored and sampled. The Florida phosphate industry has used rim ditching for over 20 years, but the process had never before been applied to oil sand tailings. The paper discussed the particular consolidation behaviour of MFT, the rim ditch concept, the layout of the containment pit and instrumentation, the pit filling procedure, and post-filling observations. 6 refs., 12 figs.

  14. Dewatering e bonifica dell’ area ˝ex Whitehead Motofides˝ (Pisa, Italia

    Directory of Open Access Journals (Sweden)

    Nicola Conti

    2014-12-01

    Full Text Available In 2007 the activities for the remediation of the “ex-Whitehead Motofides area” (in Marina di Pisa, Italy started. In order to allow the contaminated soil excavation in dry conditions a dewatering system was necessary. The water pumped through this system was then treated in an adequate plant. Acque Industriali realized and managed the whole system. The dewatering system was made of suction pins fixed to a depth of 5.5 m, connected by a junction manifold to the suction and booster vacuum assisted pump, which allowed the groundwater release toward the plant. The treatment plant, entirely designed by Acque Industriali and called ITAM (Impianto di Trattamento Acque di Falda Mobile, which means movable groundwater treatment, was realized and set up at the end of 2008. It consisted of a pre-treatment section, made of reinforced concrete, prefabricated nitrogen sweep elements, and a physical chemical treatment plant, in a continuous loop, completely made on skid. The plant, with 25 m3/h of maximum potential, was able to remove possible sedimentable or in suspension material particles from water, iron, manganese, residual organic substances such as hydrocarbons, solvents (chlorinated and not, PCBs, and partly heavy metals. Totally, 98,167 m3 of groundwater were managed in about 25 months of activity. The analytic input and output results confirmed extremely high and satisfactory pollutant removal efficiency. The concentration values of the pollutants, in fact, were always lower than the limits imposed by law.

  15. The effect of chemical, physical and enzymatic treatments on the dewatering of tar sands tailings

    Energy Technology Data Exchange (ETDEWEB)

    Theriault, Y.; Masliyah, J.H.; Fedorak, P.M.; Vazquez-Duhalt, R.; Gray, M.R. [University of Alberta, Edmonton, AB (Canada). Dept. of Chemical Engineering

    1995-09-01

    Fine tailings (with solids {lt} 106{mu}m) from hot-water extraction of the Athabasca tar sands were subjected to thermal, physical, chemical and enzymatic treatments in an attempt to modify the dewatering characteristics of the solid particles. A low-speed centrifuge at circa 1500 relative centrifugal force for 15 h was used to accelerate the sedimentation of the solids, and allowed comparison of the ultimate concentration of solids after the various treatments. Fine tailings were subjected to thermal treatment, sonication and modification of the water chemistry. Although the rate of sedimentation was affected by these treatments, the ultimate volume fraction of solids after centrifuging was about 0.3 (50-55 wt% solids). Extraction of the tailings to remove bitumen, humins and other organic components also failed to change the ultimate solids concentration. Oxidation of the organic material in the tailings by hydrogen peroxide in Fenton`s reagent, and enzymatic oxidation with lignin peroxidase, manganese peroxidase, cytochrome c, horseradish peroxidase and cowpea peroxidase gave no significant effect on the volume fraction of solids in the sediment after centrifugation. The observation that all of these treated samples gave an ultimate volume fraction of solids of about 0.3 indicated that bitumen, adsorbed organic matter and salts had little effect on the ultimate dewatering of tailings. 26 refs., 3 figs., 5 tabs.

  16. Isolation and Characterization of Polyacrylamide-Degrading Bacteria from Dewatered Sludge

    Directory of Open Access Journals (Sweden)

    Feng Yu

    2015-04-01

    Full Text Available Polyacrylamide (PAM is a water-soluble polymer that is widely used as a flocculant in sewage treatment. The accumulation of PAM affects the formation of dewatered sludge and potentially produces hazardous monomers. In the present study, the bacterial strain HI47 was isolated from dewatered sludge. This strain could metabolize PAM as its sole nutrient source and was subsequently identified as Pseudomonas putida. The efficiency of PAM degradation was 31.1% in 7 days and exceeded 45% under optimum culture condition (pH 7.2, 39 °C and 100 rpm. The addition of yeast extract and glucose improved the bacterial growth and PAM degradation. The degraded PAM samples were analyzed by gel-filtration chromatography, Fourier transform infrared and high-performance liquid chromatography. The results showed that high-molecular-weight PAM was partly cleaved to small molecular oligomer derivatives and part of the amide groups of PAM had been converted to carboxyl groups. The biodegradation did not accumulate acrylamide monomers. Based on the SDS-PAGE and N-terminal sequencing results, the PAM amide groups were converted into carboxyl groups by a PAM-induced extracellular enzyme from the aliphatic amidase family.

  17. Characterization of a bioflocculant from potato starch wastewater and its application in sludge dewatering.

    Science.gov (United States)

    Guo, Junyuan; Zhang, Yuzhe; Zhao, Jing; Zhang, Yu; Xiao, Xiao; Wang, Bin; Shu, Bi

    2015-07-01

    A bioflocculant was produced by using potato starch wastewater; its potential in sludge dewatering and potato starch wastewater treatment was investigated. Production of this bioflocculant was positively associated with cell growth, and a highest value of 0.81 g/L was obtained. When incubated with this bioflocculant, dry solids (DS) and specific resistance to filtration (SRF) of typical wastewater activated sludge reached 20.8% and 3.9 × 10(12) m/kg, respectively, which were much better than the ones obtained with conventional chemical flocculants. Sludge dewatering was further improved when both the bioflocculant and conventional polyacrylamide (PAM) were used simultaneously. With potato starch wastewater, chemical oxygen demand (COD) and turbidity removal rates could reach 52.4 and 81.7%, respectively, at pH value of 7.5 when the bioflocculant dose was adjusted to 30 mg/L; from a practical standpoint, the removal of COD and turbidity reached 48.3 and 72.5%, respectively, without pH value adjustment.

  18. Influence of finishing on the electrochemical properties of dental alloys.

    Science.gov (United States)

    Kaneko, T; Hattori, M; Hasegawa, K; Yoshinari, M; Kawada, E; Oda, Y

    2000-05-01

    Dental alloy surface finishing procedures of may influence their electrochemical behavior, which is used to evaluate their corrosion resistance. We examined the polarization resistance and potentiodynamic polarization profile of the precious-metal alloys, Type 4 gold alloy and silver-palladium alloy, and the base-metal alloys, nickel-chromium alloy, cobalt-chromium alloy, and CP-titanium. Three types of finishing procedure were examined: mirror-finishing using 0.05 micron alumina particles, polishing using #600 abrasive paper and sandblasting. Dissolution of the alloy elements in 0.9% NaCl solution was also measured and compared with the electrochemical evaluation. The corrosion resistance of the dental alloys was found to relate to finishing as follows: The polarization resistance and potentiodynamic polarization behavior revealed that the corrosion resistance improved in the order of sandblasting, #600-abrasive-paper polishing, and mirror-finishing. While the corrosion potential, critical current density and passive current density varied depending on the type of finishing, the transpassive potential remained unchanged. The influence of finishing on the corrosion resistance of precious-metal alloys was less significant than on that of base-metal alloys. A mirror-finishing specimen was recommended for use in evaluation of the corrosion resistance of various dental alloys.

  19. Influence of biofilms on transport properties in porous media

    Science.gov (United States)

    Davit, Y.

    2015-12-01

    Microbial activity and biofilm growth in porous media can drastically modify transport properties such as permeability, longitudinal and transverse dispersion or effective reaction rates. Understanding these effects has proven to be a considerable challenge. Advances in this field have been hindered by the difficulty of modeling and visualizing these multi-phase non-linear effects across a broad range of spatial and temporal scales. To address these issues, we are developing a strategy that combines imaging techniques based on x-ray micro-tomography with homogenization of pore-scale transport equations. Here, we review recent progress in x-ray imaging of biofilms in porous media, with a particular focus on the contrast agents that are used to differentiate between the fluid and biofilm phases. We further show how the 3D distribution of the different phases can be used to extract specific information about the biofilm and how effective properties can be calculated via the resolution of closure problems. These closure problems are obtained using the method of volume averaging and must be adapted to the problem of interest. In hydrological systems, we show that a generic formulation for reactive solute transport is based on a domain decomposition approach at the micro-scale yielding macro-scale models reminiscent of multi-rate mass transfer approaches.

  20. Properties that influence the specific surface areas of carbon nanotubes and nanofibers.

    Science.gov (United States)

    Birch, M Eileen; Ruda-Eberenz, Toni A; Chai, Ming; Andrews, Ronnee; Hatfield, Randal L

    2013-11-01

    Commercially available carbon nanotubes and nanofibers were analyzed to examine possible relationships between their Brunauer-Emmett-Teller specific surface areas (SSAs) and their physical and chemical properties. Properties found to influence surface area were number of walls/diameter, impurities, and surface functionalization with hydroxyl and carboxyl groups. Characterization by electron microscopy, energy-dispersive X-ray spectrometry, thermogravimetric analysis, and elemental analysis indicates that SSA can provide insight on carbon nanomaterials properties, which can differ vastly depending on synthesis parameters and post-production treatments. In this study, how different properties may influence surface area is discussed. The materials examined have a wide range of surface areas. The measured surface areas differed from product specifications, to varying degrees, and between similar products. Findings emphasize the multiple factors that influence surface area and mark its utility in carbon nanomaterial characterization, a prerequisite to understanding their potential applications and toxicities. Implications for occupational monitoring are discussed.

  1. Influence of Carbonation on Mechanical Properties of Concrete

    Institute of Scientific and Technical Information of China (English)

    梁发云; 陈龙珠; 李检保

    2003-01-01

    As one of the most important factors that determine the lifespan of a reinforced concrete structure, car-bonation not only corrodes the reinforcing steel, but also changes the mechanical properties of concrete. For betterunderstanding the performance of carbonated concrete structure, it is necessary to study the mechanical propertiesof carbonated concrete. The strees-strain relationship of carbonated concrete was analyzed on the basis of experi-ments. The specimens were made by means of accelerated carbonation and then compressed on the testing ma-chine. Some very important characteristics of carbonated concrete were revealed by the testing results. In addition,a useful constitutive model of carbonated concrete, which proved to be suitable for analyzing carbonated concretemembers, was established in this research.

  2. Biofuel Combustion Fly Ash Influence on the Properties of Concrete

    Directory of Open Access Journals (Sweden)

    Aurelijus Daugėla

    2016-02-01

    Full Text Available Cement as the binding agent in the production of concrete can be replaced with active mineral admixtures. Biofuel combustion fly ash is one of such admixtures. Materials used for the study: Portland cement CEM I 42.5 R, sand of 0/4 fraction, gravel of 4/16 fraction, biofuel fly ash, superplasticizer, water. Six compositions of concrete were designed by replacing 0%, 5%, 10%, 15% 20%, and 25% of cement with biofuel fly ash. The article analyses the effect of biofuel fly ash content on the properties of concrete. The tests revealed that the increase of biofuel fly ash content up to 20% increases concrete density and compressive strength after 7 and 28 days of curing and decreases water absorption, with corrected water content by using plasticizing admixture. It was found that concrete where 20% of cement is replaced by biofuel ash has higher frost resistance.

  3. Influence of sulfur physical properties in Claus unit operation

    Energy Technology Data Exchange (ETDEWEB)

    Larraz Mora, R.; Arvelo Alvarez, R. [Chemical Engineering Dept., Univ. of la Laguna, Tenerife (Spain)

    2002-09-01

    The Claus process is an efficient way of removing H{sub 2}S from acid gas streams and it has been widely practiced in industries such as natural gas processing, oil refining and metal smelting. Increasingly strict pollution control regulations require maximum sulfur recovery and high stream factor from the Claus units in order to minimize sulfur-containing effluents. As has been widely reported Claus unit's damages mainly occur during start up and shutdown. These operations involve scheduled warm-up and cool-down of the unit, usually burning refinery fuel-gas, which if not properly made can produce severe pipe and equipment plugging as well as catalyst deactivation. Sulfur products remaining in the unit during a shutdown period can produce dramatic unit corrosion episodes diminishing sulfur recovery unit stream factor. In the present paper some guidelines are given based on sulfur physical properties singularities which help to improve start-up/shut-down procedures. (orig.)

  4. INFLUENCE OF CYCLIC FREEZING AND THAWING UPON SPRUCE WOOD PROPERTIES

    Directory of Open Access Journals (Sweden)

    Maria Bernadett SZMUTKU

    2012-03-01

    Full Text Available The paper presents the results concerning the change of some physical and mechanical properties of spruce wood (Picea abies L., after repeated freezing and thawing, respectively after being subjected to temperature variation from positive valuea (+100C to negative values (-250C. Through this approach, the authors aimed at simulating normal temperature variations that occur in winter between night and daytime and which fresh cut timber has to stand if being stored in an open yard for one week before being kilndried. By comparing these results with the ones obtained after continuous freezing at -250C for one week, it was established that the temperature variation and the repeated changing phase of water inside wood increase dimensional instability and reduce the mechanical strengths much more than the simple exposure to theconstant negative temperature.

  5. Underlayer Roughness Influence on the Properties of ag Thin Film

    Science.gov (United States)

    Zhao, Pei; Wang, Reng; Liu, Dingquan; Zhang, Fengshan; Su, Weitao; Xu, Xiaofeng

    The effects of the roughness of ZnS underlayer on the microstructure, optical, and electrical properties of nanometer Ag thin film have been investigated in this paper. Nanometer Ag thin films in glass/ZnS/7.5 nm Ag/30 nm ZnS stacks have been deposited and analyzed. In the stacks, the underlayers of ZnS have been sputtered with various thicknesses to generate various surface roughnesses. The X-ray diffraction (XRD) has been used to study the crystal structure of Ag films. The surface topography and the roughness of ZnS underlayer have been analyzed by atomic force microscopy. The sheet resistant will become larger as the increasing of the roughness. The optical constants can be derived by fitting the transmission and reflectance spectrum. From optical constants comparison of Ag films, with the surface of the stack becoming rougher, it was found that the refractive index will increase but the extinction coefficient will decrease.

  6. Influence of porosity on thermophysical properties of a composite

    Energy Technology Data Exchange (ETDEWEB)

    Grishaeva, N. Yu., E-mail: anohina@mail2000.ru; Ljukshin, B. A., E-mail: lba2008@yandex.ru; Bochkareva, S. A., E-mail: svetlanab7@yandex.ru [Institute of Strength Physics and Materials Science SB RAS, Tomsk, 634055 (Russian Federation); Tomsk State University of Control Systems and Radioelectronics, Tomsk, 634050 (Russian Federation); Strukov, Yu. S., E-mail: regent@yandex.ru [Tomsk State University of Control Systems and Radioelectronics, Tomsk, 634050 (Russian Federation)

    2015-10-27

    In many modern information systems, the heat generated during the operation of electronic devices is usually dissipated by heat-conductive pads between the casing of the respective equipment and a massive base (platform). For newly developed pads, the promising materials are composites on the basis of various types of silicone rubber. At the same time, during the production of the pads without a vacuum setup, the material can contain air bubbles, which causes the porosity potentially negative for the thermal properties of the material. This work studies the thermal conductivity depending on the degree of silicone matrix filling by copper particles, introduced to improve thermal conductivity, and by air bubbles that are considered as reinforcing inclusions.

  7. INFLUENCE OF AUTOLYTIC TRANSFORMATIONS ON ELECTROPHYSICAL PROPERTIES OF GOAT MEAT

    Directory of Open Access Journals (Sweden)

    L. V. Antipova

    2014-01-01

    Full Text Available Functional foods represented an important element of a balanced, healthy diet. They play an important role in improving the structure of the diet of the population, are a means of prevention, correction and prevention of early transition premorbid conditions and various diseases. Meat and meat products based on it can be considered as a promising raw material for functional foods. Goat has certain dietary properties and can be used in manufacturing, but the production of high-grade products from goat meat, capable of long-term storage is not well developed. The chemical composition of the new raw meat - goat meat, on the example of the longissimus muscle of back is rich in protein, moisture, ash, and low-fat compared with other types of raw meat, which lets you create based on goat meat sector wide functional meat products. Therefore investigated the possibility of using goat meat in the production technology of functional foods. Showing the prospects for the development of goat in Russia. Investigated character of autolysis goat meat electro-physical methods and histological analysis. In the process of autolysis of goat meat are changing the electrical properties of raw meat, which are correlated with the morphological characteristics. Basic autolytic changes occurring in muscle tissue in the early stages of ripening, were reduced to a small extent the political process involving varying degrees of muscle structure in the early stages. In the later stages of maturation revealed changing widespread. Revealed that autolysis has characteristic periods and develops within 12 hours, further changes are irreversible. Shows the change in pH, carbohydrate fractions in the longissimus muscle of back goat. Results of the study of dynamics of change in pH, carbohydrate fractions in the longissimus muscle of back goat show compliance with the laws of classical autolysis noted in other sources, but differ in the time period. Defined stages of autolysis in

  8. Chemical modifications of graphene and their influence on properties of polyurethane composites: a review

    Science.gov (United States)

    Włodarczyk, D.; Urban, M.; Strankowski, M.

    2016-10-01

    Polyurethane composites are materials of great interest nowadays due to their wide range of available forms and applications in industry. Controlling and achieving unique properties via matrix modifications and addition of various specific nanofillers seems be one of the key elements to success. The purpose of this work is to briefly present some examples of graphene nanoderivatives, their syntheses, properties and influence on polyurethane matrix after application. Structural, mechanical and electrical properties of graphene nanofillers were analyzed before and after implementation into polymer matrices. Additionally properties of obtained composites were considered in the context of shape memory. The first chapter presents methods of synthesizing carbon nanofillers and some structure investigations via x-ray Diffraction (XRD), Fourier transform infrared (FTIR) and Raman spectroscopy. The second part discusses influence of graphene modifications on polymer structure and changes in thermomechanical properties via stress-strain tests and Thermogravimetry (TG).

  9. Influence of the processed sunflower oil on the cement properties

    Science.gov (United States)

    Fleysher, A. U.; Tokarchuk, V. V.; Sviderskiy, V. A.

    2015-01-01

    Used oils (vegetable oil, animal oil, engine oil, etc.), which are essentially industrial wastes, have found application as secondary raw materials in some braches of industry. In particular, the only well-known and commonly-used way of utilizing wastes of vegetable oils is to apply them as raw materials in the production of biodiesel. The goal of the present study is to develop a conceptually new way of vegetable oil wastes utilization in the building industry. The test admixture D-148 was obtained from the processing of wastes of sunflower oil and it mainly consists of fatty acid diethanolamide. The test admixture was added to the cement system for the purpose of studying its influence on water demand, flowability, setting times, compressive strength and moisture adsorption. The test admixture D-148 at the optimal content 0. 2 weight % causes 10% decrease in water demand, 1.7 time increase in flowability (namely spread diameter), 23% increase in grade strength and 34% decrease in moisture adsorption. The results of the present investigation make it possible to consider the final product of the waste sunflower oil processing as multifunctional plasticizing-waterproofing admixture.

  10. Interfacial Properties of Methylcelluloses: The Influence of Molar Mass

    Directory of Open Access Journals (Sweden)

    Pauline L. Nasatto

    2014-12-01

    Full Text Available The interfacial interactions of four methylcelluloses having the same average degree of substitution and distribution of methyl groups, but different molar masses, are studied at ambient temperature and at very low polymer concentrations. Firstly, the surface tension σ at the water/air interface is determined for the progressive addition of methylcellulose up to 100 mg/L; σ starts to decrease over 1 mg/L up to the critical aggregation concentration (CAC at 10 mg/L. The curves describing the influence of polymer concentration on σ are independent of the molar mass at equilibrium. Secondly, the adsorption of methylcellulose on silica particles is estimated from ζ-potential measurements. The data are interpreted in terms of an increase of the adsorbed layer thickness at the interface when the molar mass of methylcellulose increases. It is concluded that methylcellulose is adsorbed, forming trains and loops at the interface based on the equilibrium between surface free energy and solvent quality.

  11. Influence of radiation damage on BGO scintillation properties

    Energy Technology Data Exchange (ETDEWEB)

    Georgii, R.; Meissl, R.; Lichti, G.G.; Schoenfelder, V. [Max-Planck-Institut fuer Extraterrestrische Physik, Garching (Germany); Hajdas, W. [Paul-Scherrer Institut, CH-5232 Villigen (Switzerland); Henschel, H. [Fraunhofer-Institut fuer Naturwissenschaftlich-Technische Trendanalyse, D-53879 Euskirchen (Germany); Graef, H.-D.; Neumann-Cosel, P. von; Richter, A. [Institut fuer Kernphysik, Technische Universitaet Darmstadt, D-64289 Darmstadt (Germany)

    1998-08-11

    Aboard INTEGRAL, the next medium-size {gamma}-ray mission of the European Space Agency (ESA), a high-resolution Ge-spectrometer array with a BGO anticoincidence shield and imaging capability will be flown. The influence of the radiation damage on the photoelectron yield of the BGO scintillators due to the radiation environment in the orbit, i.e. {gamma}-rays, electrons and protons from the radiation, belts and the cosmic diffuse radiation, was investigated. Irradiation tests with doses equivalent to the orbit conditions were performed and the photoelectron yields of different BGO crystals were measured. It was found that for equal doses the reduction of the photoelectron yield varies strongly for the crystals of different manufacturers. Furthermore, electromagnetic radiation affects the photoelectron yield much stronger than particle radiation. A possible explanation is given by interpreting the effect due to {gamma}-rays primarily as damage of the electronic structure of the BGO, whereas the particle radiation damages mainly the crystal structure. (orig.) 19 refs.

  12. INFLUENCE OF COMPLEX COMPOSTS ON PHYSICOCHEMICAL PROPERTIES OF ORDINARY CHERNOZEM

    Directory of Open Access Journals (Sweden)

    Antonenko D. A.

    2016-09-01

    Full Text Available During the last century, in the biosphere occur expressed processes of soil degradation due to anthropogenic influence, which seriously change of top layer of soil. The agricultural landscape is allocated of noticeable accumulation of various wastes at expense of growing of food crops and grazing of farm animals, as well as due to mineral wastes generated in process production of building materials and fertilizers from natural raw. According to physical and chemical characteristics of wastes of plant origin and natural-raw wastes constitute a non-toxic highly dispersed connection with an admixture of different undecomposed organic and mineral substances. Specificity of physical state is determined there of high dispersion, which is represented by system particles of colloidal substances distributed in various environments. Colloids of natural-raw wastes are characterized by a low rate of diffusion; do not penetrate finely porous membrane of cell structures, different very nonequilibrium insolubility and specific chemical composition. For example, phosphogypsum is characterized by high concentration of sulfur and calcium, and trace amounts of entire table of D.I. Mendeleev. Organic wastes are made by variety of chemical compounds and high concentration of carbohydrates, proteins, fats and other organic substances

  13. Study on the Comparison between Prediction and Field Measurement of Surface Settlement Caused by Dewatering of Confined Water%降承压水引起地表沉降的预估与实测对比研究

    Institute of Scientific and Technical Information of China (English)

    张刚

    2013-01-01

    随着基坑工程不断向大深度、大面积方向发展,承压水降水引起的环境影响日益明显.本文采用以现场抽水试验参数为依据的数值模拟法对承压水降水引起的地表沉降进行了预测,并与基坑开挖和降水期间引起的地表总沉降进行了对比研究.实例分析结果表明,在基坑开挖和降水期间,承压水降水引起的沉降量占总沉降的比重比较大(约占30%);以现场抽水试验参数为依据的数值模拟法能较好地还原降水过程中地下水渗流场的分布形式、降深影响范围和沉降影响范围,为承压水降水引起的地表沉降研究提供了重要的工程资料和分析依据.%With the increase of depth and area of large-scale deep excavation,the environmental impact caused by dewatering of confined water has become increasingly clear.The numerical simulation method based on in-situ test was used to predict the surface settlement caused by dewatering of confined water,and then to compare the predicted value with the total settlement during the construction period.The results of engineering example showed that the setdement caused by dewatering of confined water accounted for a larger proportion of the total settlement (about 30%) ;this method could simulate the field distribution of groundwater,the influence scope of drop depth and the influence range of settlement very well,which provided engineering experience and theoretical basis for study of the settlement caused by dewatering of confined water.

  14. Influence of Nano-TiO2 on Property of Dacrotized Coating

    Institute of Scientific and Technical Information of China (English)

    GAO Fu-quan; WU Zhi-yong; YANG Qiang

    2004-01-01

    The influence of nano-TiO2 to the property of Dacrotized coating was studied in this paper. The complex film obtained by Dacrotized coating modified by TiO2with particle size 30 ~50 nm has no obvious change in appearance and antirust property, but obvious improvement on hardness and anti-abrasion and anti-aged property. It can meet the requirement on both size precision and anti-rust property in manufacturing high tech-products. Therefore it has important meaning in practice.

  15. Influence of Rare Earth on Property of Low Chromium Semi-Steel

    Institute of Scientific and Technical Information of China (English)

    LIU Jian-hua; XIE Dan-yang; LI Chang-sheng; SHAO Li; ZHANG Rui-jun

    2003-01-01

    The influence of rare earth (RE) content on mechanical properties and abrasion resistance of low chromium semi-steel was studied by means of metallographic examination, scanning electron microscopic examination and mechanical property test. The experiment results show that RE can improve the comprehensive properties, especially in combination with proper heat treatment. The optimum properties of low chromium semi-steel modified by RE of 0.25 % could be obtained by normalization at 950 ℃ for 3 h. The main reason is the change in morphology and distribution of eutectic carbide and the precipitation of granular carbides.

  16. Influence of nanometric silicon carbide on phenolic resin composites properties

    Indian Academy of Sciences (India)

    GEORGE PELIN; CRISTINA-ELISABETA PELIN; ADRIANA STEFAN; ION DINC\\u{A}; ANTON FICAI; ECATERINA ANDRONESCU; ROXANA TRUSC\\u{A}

    2016-06-01

    This paper presents a preliminary study on obtaining and characterization of phenolic resin-based composites modified with nanometric silicon carbide. The nanocomposites were prepared by incorporating nanometric silicon carbide (nSiC) into phenolic resin at 0.5, 1 and 2 wt% contents using ultrasonication to ensure uniform dispersion of the nanopowder, followed by heat curing of the phenolic-based materials at controlled temperature profile up to 120$^{\\circ}$C. The obtained nanocomposites were characterized by FTIR spectroscopy and scanning electron microscopy analysis and evaluated in terms of mechanical, tribological and thermal stability under load. The results highlight the positive effect of the nanometric silicon carbide addition in phenolic resin on mechanical, thermo-mechanical and tribological performance, improving their strength, stiffness and abrasive properties. The best results were obtained for 1 wt% nSiC, proving that this value is the optimum nanometric silicon carbide content. The results indicate that these materials could be effectively used to obtain ablative or carbon–carbon composites in future studies.

  17. Influence of the structural properties on the pseudocritical magnetic behavior of single-wall ferromagnetic nanotubes

    Energy Technology Data Exchange (ETDEWEB)

    Salazar-Enriquez, C.D. [PCM Computational Applications, Universidad Nacional de Colombia - Sede Manizales, A.A. 127 Manizales (Colombia); Restrepo-Parra, E., E-mail: erestrepopa@unal.edu.co [PCM Computational Applications, Universidad Nacional de Colombia - Sede Manizales, A.A. 127 Manizales (Colombia); Restrepo, J. [Grupo de Magnetismo y Simulacion Gplus, Instituto de Fisica, Universidad de Antioquia, A.A. 1226 Medellin (Colombia)

    2012-04-15

    In this work we address the influence of the crystalline structure, concretely when the system under study is formed by square or hexagonal unit cells, upon the magnetic properties and pseudocritical behavior of single-wall ferromagnetic nanotubes. We focus not only on the effect of the geometrical shape of the unit cell but also on their dimensions. The model employed is based on the Monte Carlo method, the Metropolis dynamics and a nearest neighbors classical Heisenberg Hamiltonian. Magnetization per magnetic site, magnetic susceptibility, specific heat and magnetic energy were computed. These properties were computed varying the system size, unit cell dimension and temperature. The dependence of the nearest neighbor exchange integral on the nanotubes geometrical characteristics is also discussed. Results revealed a strong influence of the system topology on the magnetic properties caused by the difference in the coordination number between square and hexagonal unit cell. Moreover, the nanotubes diameter influence on magnetic properties is only observed at very low values, when the distance between atoms is less than it, presented by the 2D sheet. On the other hand, it was concluded that the surface-related finite-size effects do not influence the magnetic nanotubes properties, contrary to the case of other nano-systems as thin films and nanoparticles among others. - Highlights: Black-Right-Pointing-Pointer Unit cell geometry has strong influence on the magnetic properties in ferromagnetic nanotubes. Black-Right-Pointing-Pointer The nanotube diameter increase produces a decrease of interaction between nearest neighbor. Black-Right-Pointing-Pointer Surface-related finite-size effects do not influence the magnetic nanotubes properties.

  18. Prediction and verification of centrifugal dewatering of P. pastoris fermentation cultures using an ultra scale-down approach.

    Science.gov (United States)

    Lopes, A G; Keshavarz-Moore, E

    2012-08-01

    Recent years have seen a dramatic rise in fermentation broth cell densities and a shift to extracellular product expression in microbial cells. As a result, dewatering characteristics during cell separation is of importance, as any liquor trapped in the sediment results in loss of product, and thus a decrease in product recovery. In this study, an ultra scale-down (USD) approach was developed to enable the rapid assessment of dewatering performance of pilot-scale centrifuges with intermittent solids discharge. The results were then verified at scale for two types of pilot-scale centrifuges: a tubular bowl equipment and a disk-stack centrifuge. Initial experiments showed that employing a laboratory-scale centrifugal mimic based on using a comparable feed concentration to that of the pilot-scale centrifuge, does not successfully predict the dewatering performance at scale (P-value fermentation cultures. This work presents a simple and novel USD approach to predict dewatering levels in two types of pilot-scale centrifuges using small quantities of feedstock (<50 mL). It is a useful tool to determine optimal conditions under which the pilot-scale centrifuge needs to be operated, reducing the need for repeated pilot-scale runs during early stages of process development. Copyright © 2012 Wiley Periodicals, Inc.

  19. Organic Carbon Influences on Soil Particle Density and Rheological Properties

    Energy Technology Data Exchange (ETDEWEB)

    Blanco-Canqui, H; Lal, Rattan; Post, W M.; Izaurralde, R Cesar C.; Shipitalo, M. J.

    2006-07-01

    Soil particle density (rs) is not routinely measured and is assumed to range between 2.60 and 2.70 Mgm23 or to be a constant (2.65 Mgm23) when estimating essential properties such as porosity, and volumetric water and air relations. Values of rs for the same soil may, however, differ significantly from the standard range due to management induced changes in soil organic carbon (SOC) concentrations. We quantified the rs and Atterberg limits of a Rayne silt loam for five long-term (.22 yr) moldboard-plowed continuous corn (Zea mays L.; MP), no-till continuous corn (NT), no-till continuous corn with beef cattle manure (NTm), pasture, and forest systems.We also assessed the relationships of SOC concentration with rs and the Atterberg limits and the impact of rs on soil porosity. Mean rs across NT, NTm, and pasture (2.35 Mg m23) was |7% lower than that for MP in the 0- to 10-cm soil depth (2.52 Mg m23, P , 0.01). Forest had the lowest rs of all soils (1.79 Mg m23). The NTm caused a greater reduction in rs and a greater increase in SOC concentration, liquid limit (LL), plastic limit (PL), and plasticity index (PI) than NT. Surface soils under MP had the highest rs and rb and the lowest SOC concentration, LL, PL, and PI. The SOC concentration was correlated negatively with rs (r 2 5 0.75) and positively with Atterberg limits (r 2 . 0.64) at .20-cm depth. Estimates of soil porosity for NT, NTm, and pasture using the constant rs overestimated the ''true'' porosity by 12% relative to that using the measured rs.

  20. Quality and safety aspects of reusable plastic food packaging materials: influence of reuse on intrinsic properties.

    Science.gov (United States)

    Jetten, J; de, Kruijf N

    2002-01-01

    The aim of the project was to develop a comprehensive package of quality assurance criteria for use by the industry and by regulatory authorities to ensure the quality and safety-in-use (sensory, microbiological and chemical safety) of reused plastics for food packaging. The paper describes the investigations into potential adulteration effects by reuse on the intrinsic properties of plastics in more detail. The plastic articles investigated were bottles of polyethylene terephthalate (PET) or polycarbonate (PC) and vending cups of polypropylene (PP). The influence of repeated use on the migration of plastic constituents, degradation products of plastic additives, barrier properties and surface characteristics were investigated. The overall conclusion was that the investigated intrinsic properties of the refillable articles were not significantly influenced by repeated use. Only the hydrophobicity of the refillable PC and PP articles seemed to be influenced by repeated washing. PC bottles washed 15 times were significantly less hydrophobic than unwashed bottles.

  1. The Influence of Nanopore Dimensions on the Electrochemical Properties of Nanopore Arrays Studied by Impedance Spectroscopy

    Directory of Open Access Journals (Sweden)

    Krishna Kant

    2014-11-01

    Full Text Available The understanding of the electrochemical properties of nanopores is the key factor for better understanding their performance and applications for nanopore-based sensing devices. In this study, the influence of pore dimensions of nanoporous alumina (NPA membranes prepared by an anodization process and their electrochemical properties as a sensing platform using impedance spectroscopy was explored. NPA with four different pore diameters (25 nm, 45 nm and 65 nm and lengths (5 μm to 20 μm was used and their electrochemical properties were explored using different concentration of electrolyte solution (NaCl ranging from 1 to 100 μM. Our results show that the impedance and resistance of nanopores are influenced by the concentration and ion species of electrolytes, while the capacitance is independent of them. It was found that nanopore diameters also have a significant influence on impedance due to changes in the thickness of the double layer inside the pores.

  2. The Influence of Nanopore Dimensions on the Electrochemical Properties of Nanopore Arrays Studied by Impedance Spectroscopy

    Science.gov (United States)

    Kant, Krishna; Priest, Craig; Shapter, Joe G.; Losic, Dusan

    2014-01-01

    The understanding of the electrochemical properties of nanopores is the key factor for better understanding their performance and applications for nanopore-based sensing devices. In this study, the influence of pore dimensions of nanoporous alumina (NPA) membranes prepared by an anodization process and their electrochemical properties as a sensing platform using impedance spectroscopy was explored. NPA with four different pore diameters (25 nm, 45 nm and 65 nm) and lengths (5 μm to 20 μm) was used and their electrochemical properties were explored using different concentration of electrolyte solution (NaCl) ranging from 1 to 100 μM. Our results show that the impedance and resistance of nanopores are influenced by the concentration and ion species of electrolytes, while the capacitance is independent of them. It was found that nanopore diameters also have a significant influence on impedance due to changes in the thickness of the double layer inside the pores. PMID:25393785

  3. Influence of Compacting Rate on the Properties of Compressed Earth Blocks

    Directory of Open Access Journals (Sweden)

    Humphrey Danso

    2016-01-01

    Full Text Available Compaction of blocks contributes significantly to the strength properties of compressed earth blocks. This paper investigates the influence of compacting rates on the properties of compressed earth blocks. Experiments were conducted to determine the density, compressive strength, splitting tensile strength, and erosion properties of compressed earth blocks produced with different rates of compacting speed. The study concludes that although the low rate of compaction achieved slightly better performance characteristics, there is no statistically significant difference between the soil blocks produced with low compacting rate and high compacting rate. The study demonstrates that there is not much influence on the properties of compressed earth blocks produced with low and high compacting rates. It was further found that there are strong linear correlations between the compressive strength test and density, and density and the erosion. However, a weak linear correlation was found between tensile strength and compressive strength, and tensile strength and density.

  4. PROPERTIES OF BACTERIAL CELLULOSE AND ITS INFLUENCE ON THE PHYSICAL PROPERTIES OF PAPER

    Directory of Open Access Journals (Sweden)

    Wen-Hua Gao

    2011-02-01

    Full Text Available Bacterial cellulose is a promising source of biodegradable polymers having high purity. The time required to disperse bacterial cellulose wet membranes was studied, along with evaluation by infrared spectroscopy and thermal analysis of the dispersed bacterial fiber and tests of the physical properties of the sheet. The results showed that bacterial cellulose wet membrane can be dispersed well, forming fibers when the dispersing time was 3 minutes at a suitable concentration. FT-IR results showed that the composition of bacterial fiber is similar to that of bleached softwood fibers. Thus, the morphology, thermal performance, and the length of bacterial fibers are significantly different. The sheets’ physical properties show that with the increasing dosage of bacterial fibers (relative to softwood fiber, the properties of tensile index, tear index, burst index, and stiffness greatly improve, while the porosity and the relative water absorption decrease.

  5. Influence of Raw Material and Mat-forming on Physical-mechanical Properties of Panels

    Institute of Scientific and Technical Information of China (English)

    YUWenji; RENDinghua; MAHongxia; ZHOUYue

    2005-01-01

    This paper mainly discussed the heat transmission rate and physical-mechanical properties of particleboard (PB) and middle density fiberboard (MDF) with different forming methods. In this experiment,both poplar and wheat-straw with different ratios and different shape forms were used as furnishes; UF and MDI were added to the poplar furnish and wheat-straw one, respectively. The experiment results showed that the layer-forming boards were superior to the mixture-forming boards. Under the given experimental conditions, the poplar to wheat straw ratio has no obvious influence on the mechanical properties, but has significant influence on the thickness swell (TS) of PB and MDF.

  6. Influence of Mineral Additives on the Technological Properties of Sealing Slurries for Geoengineering Works

    Directory of Open Access Journals (Sweden)

    Andrzej Gonet

    2006-10-01

    Full Text Available One of the most important factors influencing the efficiency of sealing and reinforcing the ground and rock mass with geoengineering methods is a proper selection of respective technological parameters in view of existing hydrogeological and geotechnical conditions.Selected mineral additives increase the sealing properties of fresh and set slurries. They also decrease the cost of the slurry, provide a method for utilizing the stored materials (additives, and consequently, lessen the risk of environmental pollution.The results of laboratory tests on the influence of selected mineral additives on technological properties of sealing slurries are presented in the paper.

  7. Influence of Storage Conditions on Geotechnical Properties of Ariake Clay and on its Chemical Stabilization

    OpenAIRE

    シナ, コスラナント; SINAT, KOSLANANT

    2006-01-01

    Influence of storage conditions on geotechnical properties of Ariake clay and on its chemical stabilization is investigated to make use of the surplus clay as construction materials. The influence factors in lime and cement stabilization including salts, diatom and clay minerals were studied. The experiments were set up by mixing clays with various proportions of studied factors. As a result, for Bangkok clay, Kaolin and Bentonite, the factors improving the unconfined compressive strength of...

  8. The influence of ventilated façade on sound insulation properties of envelope walls

    OpenAIRE

    2017-01-01

    Presented article deals with sound insulation properties of timber structures’ envelope walls. Particularly, the influence of heavy board ventilated façade on laboratory airborne sound insulation R and Rw in dB was studied. The installation method and gaps between façade boards can cause building defects originating in overrating the influence of ventilated cladding on envelope wall acoustic parameters. Real constructions were built for the experimental purposes and measurements, one with gap...

  9. The influence of surface reflectance anisotropy on estimation of soil properties

    Science.gov (United States)

    Bartholomeus, Harm; Roosjen, Peter; Clevers, Jan

    2014-05-01

    The spatial variation in soil properties is an important factor for agricultural management. Unmanned airborne vehicles (UAV's) equipped with a hyperspectral mapping system may provide these data, but anisotropic reflectance effects may have an influence on the derived soil properties. Besides influencing the reflectance, angular observations may deliver added information about soil properties. We investigated the anisotropic behavior of 59 soil samples with a large variation in soil composition, by measuring their reflectance (350-2500 nm) over 92 different angles using a robot-based laboratory goniometer system. The results show that the anisotropic behavior of the soils influences the measured reflectance significantly, which limits the accurate prediction of soil properties (OM and clay especially). However, prediction accuracies of OM increase when spectra are measured under specific angles. Prediction accuracies further increase when a combination of observation angles is being used. Apart from that, using UAV's the wavelength range is limited to about 1000 nm. In general, this will decrease the model performance, but our results show that this effect can largely be compensated by combining multiple observation angles. Altogether, we demonstrate that surface anisotropy influences the prediction of soil properties negatively. This effect can be reduced by combining spectra acquired under different angles. Moreover, predictions can be improved if combinations of different observation angles are used.

  10. Influence of nonmartensitic transformation products on mechanical properties of tempered martensite

    Science.gov (United States)

    Hodge, J M; Lankford, W T

    1952-01-01

    The influence of nonmartensitic transformations products on the mechanical properties of tempered martensite is presented for samples of a SAE 4340 steel, partially isothermally transformed to specific high-temperature transformation products and quenched and tempered to hardness values of from 25 to 40 Rockwell c. The effects of upper bainite in amounts of 1,5, 10, 20 and 50 percent, of 5 percent ferrite, and of 5 percent pearlite on the tensile, impact, and fatigue properties are evaluated. (author)

  11. The influence of the production process on mechanical properties of rubber testing samples

    OpenAIRE

    Škrobák, Adam; STANĚK, Michal; Maňas, David; Ovsík, Martin; Šenkeřík, Vojtěch; Řezníček, Martin

    2014-01-01

    The article deals with the influence of production technology on mechanical properties of rubber testing samples. In practice, rubber testing samples are cut out from a compression molded sheet, also in case of testing of rubber compounds appointed for injection molding. However, the different way of the preparation of testing samples and the production itself may have a negative effect on the mechanical properties of the final product. Thus the article judges, to what extent the mechanical p...

  12. STABILIZATION OF DEWATERED SEWAGE SLUDGE BY AEROBIC COMPOSTING METHOD: USING SAWDUST AS BULKING AGENTS

    Directory of Open Access Journals (Sweden)

    A PARVARESH

    2002-12-01

    Full Text Available Introduction. Sludge production from municipal wastewater treatment plants should have quality standards before disposal in to the environment. Environmental specialists classified sewage sludge as a hazardous waste because of high organic compounds and pathogenic microorganisms. They belive that sewage should be stabilized before disposal and so composting of sewage sludge is an effective and economical method to stabilize. Sewage sludge compost could be used to improve soil structure and enrich the soil with nutrients. Methods. To evaluate the optimum conditions of aerobic compost, the mixture of dewatered sewage sludge from Isfahan municipal waste water treatment plant and sawdust as bulking agent were used. Pilot scale study were performed in Isfahan municipal waste water treatment plant. To perform this research project, the dewatered sewage sludge with humidity between 78 to 82 percent were mixed with sawdust. Turning over method of the piles with one week interval were applied to aerate the mixture. Temperature of the piles were monitored at different depths daily. Other parameters such as N, G, organic matters and pH were determined weekly. Total and fecal coli form, and salmonella were determined at the beginning and end of the composting process, also heavy metals were measured at the same time. Results. The results of this study showed that after days, temperature of the mixture reached up to 55 G, and were stabled for 15 days. Humidity, organic matter, organic carbon and GIN ratio of the mixture decreased over the period of the study, due to increasing the temperature. Also organic matter and humidity mainly decreased in thermofilic phase. The number of total and fecal coliform and also salmonella decreased to A class standards of US.EPA at the end of the operation. Discussion. The results of the study also showed that, this type of composting method is reliable, and simple to schedule, with high flexibility and low odor

  13. The Influence Of The Temperature Of Liquid Nitrogen On The Physical Properties Of Powder Magnetic Composites

    Directory of Open Access Journals (Sweden)

    Kapelski D.

    2015-06-01

    Full Text Available The paper presents the physical properties of soft magnetic iron composites and Nd-Fe-B bonded permanent magnets measured at room temperature and at liquid nitrogen. The objective of research was a determination of influence of liquid nitrogen temperature on the magnetic properties, resistivity and mechanical properties of different powder magnetic materials. Research was carried out for three powder materials: soft magnetic, i.e. Somaloy 700, AncorLam and hard magnetic powder MQP-B used for production of bonded magnets. Composite specimens were prepared by compression moulding technology.

  14. Influence of isothermal transformation dwell on tensile and fatigue properties of austempered ductile iron

    Energy Technology Data Exchange (ETDEWEB)

    Vechet, S.; Hanzlikova, K. [Brno Univ. of Technology, Brno (Czech Republic); Kohout, J. [Military Academy in Brno, Brno (Czech Republic)

    2005-07-01

    Two ADI heats transformed at temperatures of 400 and 380 C during temporal range from 2 minutes to 9 hours were studied in details, with emphasis on structure composition and mechanical properties (tensile and fatigue properties were determined). In the case of the shortest dwells the level of mechanical properties is influenced by martensite, which occurs in the structure as a result of subsequent cooling. UTS and yield stress increase slightly with the dwell of isothermal transformation while the values of elongation to fracture as well as of fatigue limit are very closely dependent on the amount of the retained austenite in the microstructure. (orig.)

  15. Influence of Al content on textural properties and catalytic activity of hierarchical porous aluminosilicate materials

    Indian Academy of Sciences (India)

    Ling Xu; Limei Duan; Zongrui Liu; Jingqi Guan; Qiubin Kan

    2013-12-01

    A series of hierarchical porous aluminosilicate materials were prepared using hydrothermal treatment of the composite formed by polystyrene colloidal spheres and aluminosilicate gel. Influence of Al content on the textural properties, acidic properties and catalytic activity of the hierarchical porous aluminosilicate materials was studied. The results showed that textural and acidic properties of the hierarchical porous aluminosilicate materials were strongly related to Al content. As Al content is increased (Si/Al = 25), the hierarchical porous catalysts exhibited higher catalytic activity and major product selectivity for alkylation of phenol with tert-butanol than the catalysts with a lower Al content (Si/Al = 50).

  16. Influence of cooling rate on optical properties and electrical properties of nanorod ZnO films

    Energy Technology Data Exchange (ETDEWEB)

    Gao, Meizhen, E-mail: gaomz@lzu.edu.c [Key Lab for Magnetism and Magnetic Materials of MOE, Lanzhou University, Lanzhou 730000 (China); Liu, Jing; Sun, Huina; Wu, Xiaonan; Xue, Desheng [Key Lab for Magnetism and Magnetic Materials of MOE, Lanzhou University, Lanzhou 730000 (China)

    2010-06-25

    ZnO films are prepared on Ag-coated glass substrates by wet chemical method at low temperature using Zn(NO{sub 3}).6H{sub 2}O and dimethylamine borane complex (DMAB). The structural, electrical and optical properties of ZnO films are investigated by X-ray diffraction, scanning electron microscope, four-point probe method and photoluminescence, respectively. The ZnO film deposited at 90 {sup o}C is the most compact films with a c-axis preferred orientation. The cooling rate affects the optical and electrical properties of ZnO films dramatically. The ZnO films cooled at -15 {sup o}C exhibit the lowest electrical resistivity of 0.525 {Omega} cm and the strongest photoluminescence in visible light. The increase of the conductivity and the enhancement of the photoluminescence are attributed to the increase of oxygen vacancies in the films.

  17. Influence of supplementary cementitious materials on water transport kinetics and mechanical properties of hydrated lime and cement mortars

    Directory of Open Access Journals (Sweden)

    Ince, C.

    2015-06-01

    Full Text Available The purpose of this paper is an investigation of the possible role of supplementary cementitious materials (SCMs on water transport kinetics and mechanical properties of hydrated lime (CL90 and Portland cement (PC mortars. The properties of hydrated lime are significantly different from those of cement and therefore modifying fresh and hardened properties of these mortars are vital for mortar/substrate optimisation in masonry construction. The parameters investigated in this paper often are the main barriers to the use of hydrated lime in construction practice. The results show that transfer sorptivity and time to dewater freshly-mixed hydrated lime mortars can be modified when binder is partially replaced with SCMs. Compressive strength of CL90 mortars is increased systematically with the increased replacement levels of SCMs and the results are supported with the microstructural images. The ability to modify the water transport kinetics and mechanical properties allows compatibility between the mortar and the substrate unit in masonry construction.El objetivo de este artículo es investigar el papel de los materiales cementantes suplementarios (SCMs en la cinética de transporte del agua y en las propiedades mecánicas de los morteros de cal hidratada (CL90 y cemento Portland. Las propiedades de la cal hidratada son significativamente diferentes a las del cemento y por lo tanto el control de las propiedades de los morteros frescos y endurecidos es fundamental en la optimización mortero/substrato en albañilería. Los parámetros estudiados en este trabajo son a menudo las principales barreras para el uso de la cal hidratada en la práctica de la construcción. Los resultados indican que la absortividad y el tiempo necesario para deshidratar morteros de cal hidratada recién mezclados pueden ser controlados cuando el conglomerante es parcialmente remplazado por SCMs. La resistencia a compresión de los morteros CL90 aumenta sistem

  18. The influence of surface functionalisation on the electrical properties and thermal stability of nanodiamonds

    Energy Technology Data Exchange (ETDEWEB)

    Welch, Joseph O; Li, Pei; Chaudhary, Aysha; Edgington, Robert; Jackman, Richard B., E-mail: r.jackman@ucl.ac.uk [London Centre for Nanotechnology and the Department of Electronic and Electrical Engineering, University College London, 17-19 Gordon Street, London WC1H 0AH (United Kingdom)

    2014-10-07

    Detonation nanodiamond (ND) has recently emerged as a useful new class of diamond material. However, to date there has been little investigation of the electrical properties of this material. Due to the nanoscale dimensions, the surface functionalisation of the individual ND is of particular importance to the characteristics of ND films. Here, hydrogen and oxygen termination of ND, verified using Fourier transform infrared spectroscopy, are shown to strongly influence the electronic properties of NDs. Hydrogen terminated ND exhibiting a far greater resilience to thermal decomposition when compared to the oxygen terminated NDs. Moreover, H-NDs also displayed so-called “surface conductivity,” a property displayed by hydrogen-terminated bulk diamond films, whilst O-NDs display properties high resistivity. These results indicate that under the correct conditions ND layers can display similar electrical properties to “bulk” diamond thin films.

  19. The influence of surface functionalisation on the electrical properties and thermal stability of nanodiamonds

    Science.gov (United States)

    Welch, Joseph O.; Li, Pei; Chaudhary, Aysha; Edgington, Robert; Jackman, Richard B.

    2014-10-01

    Detonation nanodiamond (ND) has recently emerged as a useful new class of diamond material. However, to date there has been little investigation of the electrical properties of this material. Due to the nanoscale dimensions, the surface functionalisation of the individual ND is of particular importance to the characteristics of ND films. Here, hydrogen and oxygen termination of ND, verified using Fourier transform infrared spectroscopy, are shown to strongly influence the electronic properties of NDs. Hydrogen terminated ND exhibiting a far greater resilience to thermal decomposition when compared to the oxygen terminated NDs. Moreover, H-NDs also displayed so-called "surface conductivity," a property displayed by hydrogen-terminated bulk diamond films, whilst O-NDs display properties high resistivity. These results indicate that under the correct conditions ND layers can display similar electrical properties to "bulk" diamond thin films.

  20. Influence of Specific Features of Twin Arc Welding on Properties of Weld Joints

    Science.gov (United States)

    Sholokhov, M. A.; Melnikov, A. U.; Fiveyskiy, A. M.

    2016-04-01

    The present article covers the influence of standard and narrow gap twin arc welding on properties of weld joints from high-strength steels. While analyzing microsections we established that distribution of micro structure and phase terms, as well the distribution of micro-hardness, were more homogeneous under narrow gap twin arc welding.

  1. Rheological properties of wheat starch influenced by amylose-lysophosphatidylcholine complexation at different gelation phases

    NARCIS (Netherlands)

    Ahmadiabhari, Salomeh; Woortman, Albert; Hamer, Rob; Loos, Katja

    2015-01-01

    Amylose is able to form helical inclusion complexes with lysophosphatidylcholine (LPC). This complexation influences the functional and rheological properties of wheat starch; however it is well known that the formation of these complexes lead the starchy systems to a slower enzymatic hydrolysis. Ba

  2. Influence of Processing Parameters on Properties of Needle punched Composite Geotextiles

    Institute of Scientific and Technical Information of China (English)

    李婕; 储才元; 杨金魁; 张键

    2001-01-01

    The influence of the processing parameters on the properties of needle-punched composite geotextiles,compounded by polypropylene filament woven-fabrics and nonwoven fabrics is studied by using orthogonal design method. The relationship between tensile strength and peeling strength is discussed. The experimental results are offered as reference.

  3. Molecular characterization of biochars and their influence on microbiological properties of soil

    Science.gov (United States)

    The composition and surface chemistry of carbon rich biochar materials is highly uncertain and believed to change with feedstock and biomass conversion process. The tentative connection between the biochar surface chemical properties and their influence on microbially mediated mineralization of C, N...

  4. Amide, urea and thiourea-containing triphenylene derivatives: influence of H-bonding on mesomorphic properties

    NARCIS (Netherlands)

    Paraschiv, I.; Tomkinson, A.; Giesbers, M.; Sudhölter, E.J.R.; Zuilhof, H.; Marcelis, A.T.M.

    2007-01-01

    The synthesis and thermotropic properties are reported for a series of hexaalkoxytriphenylenes that contain an amide, urea or thiourea group in one of their alkoxy tails. The intermolecular hydrogen bonding abilities of these molecules have a disturbing influence on the formation and stability of th

  5. Influence of layer eccentricity on the resonant properties of cylindrical active coated nano-particles

    DEFF Research Database (Denmark)

    Thorsen, R. O.; Arslanagic, Samel

    2015-01-01

    We report on the influence of the layer eccentricity on the resonant properties of active coated nano-particles made of a silver core and gain impregnated silica shell illuminated by a near-by magnetic line source. For a fixed over-all size of the particle, designs with small and large cores...

  6. Influence of Textile Structure and Silica Based Finishing on Thermal Insulation Properties of Cotton Fabrics

    Directory of Open Access Journals (Sweden)

    G. Rosace

    2016-01-01

    Full Text Available The aim of this work is to investigate the influence of weave structures and silica coatings obtained via sol-gel process on the thermal insulation properties of cotton samples. For this reason three main weave structures (plain, satin, and piqué of cotton fabric were selected with different yarn count, threads per cm, and mass per square meter values. Thereafter, only for the plain weave, the samples were padded using silica sol formed by hydrolysis and subsequent condensation of 3-glycidoxypropyltrimethoxysilane under acidic conditions. The silanized plain weave samples were characterized by TGA and FT-IR techniques. The thermal properties were measured with a home-made apparatus in order to calculate thermal conductivity, resistance, and absorption of all the treated fabric samples. The relationship between the thermal insulation properties of the plain weave fabrics and the concentration of sol solutions has been investigated. Fabrics weave and density were found to strongly influence the thermal properties: piqué always shows the lowest values and satin shows the highest values while plain weave lies in between. The thermal properties of treated high-density cotton plain weave fabric were proved to be strongly influenced by finishing agent concentration.

  7. Antibacterial Properties of Copper Nanoparticle Dispersions: Influence of Synthesis Conditions and Physicochemical Characteristics

    Science.gov (United States)

    Godymchuk, A.; Frolov, G.; Gusev, A.; Zakharova, O.; Yunda, E.; Kuznetsov, D.; Kolesnikov, E.

    2015-11-01

    The production of bactericidal plasters, bandages and medicines with the inclusion of copper nanoparticles and copper ions may have a great potential in terms of their biomedical application. The work considers the influence of the synthesis conditions, size, aggregation status, and charge of nanoparticles in aqueous solutions as well as the type of microorganisms to the antibacterial properties of water suspensions of electroexplosive copper nanoparticles in the conditions in vitro in relation to strains Escherichia coli, Pseudomonas aeruginosa, Staphylococcus aureus, and Bacillus cereus. Water dispersions of copper nanoparticles were shown to inhibit the growth of test cells for both G+ and G- microbacteria but the degree of such an influence strongly depended on the type of a test strain. The authors have demonstrated that use of deeply purified water and alcohol-containing stabilizers at the synthesis of nanoparticles via metals electric erosion in the liquid prevents the copper nanoparticles coagulation and significantly influences on their physicochemical characteristics and, consequently, antibacterial properties.

  8. Research on various factors influencing the moisture absorption property of sodium polyacrylate

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    Sodium polyacrylate was synthesized with acrylic acid as the monomer, and sodium bisulfate and ammonium persulfate as the initiator, by means of aqueous solution polymerization. The factors influencing the properties of moisture absorption, such as monomer concentration, dosage of initiator, and reaction temperature were systematically investigated. The experimental results indicate that the moisture-absorbing property of this polymer was better than other traditional material, such as silica gel, and molecular sieve. The best reaction condition and formula are based on the orthogonal experiment design. The optimum moisture absorbency of sodium polyacrylate reaches 1.01 g/g. The mathematical correlation of this polymer with various factors and moisture absorbency is obtained based on the multiple regression analysis. The moisture content intuitive analysis table shows that neutralization degree has the most significant influence on moisture absorbency, followed by monomer concentration and reaction temperature, while other factors have less influence.

  9. Influence of structural parameters of the masonry on effective elastic properties and strength

    Directory of Open Access Journals (Sweden)

    А.I. Grishchenko

    2014-08-01

    Full Text Available Two phase masonry model, which contains elastic mortar and elastic bricks, is analyzed numerically in order to evaluate sensitivity of effective elastic moduli and strength properties to a deviation in the masonry structural parameters. Different methods of masonry homogenization are studied. Effective elastic moduli of the masonry representative volume element are obtained by means of direct finite element simulation and homogenization procedure. Influence of variation in the heterogeneous material microstructure characteristics (influence of brick aspect ratio and orientation angle on the local stress-strain state and mechanical properties of the representative volume element of the composite considered is analyzed. Mechanical properties obtained by direct finite element modeling and other methods in various literary sources are compared. These studies are relevant for the design of composite materials with a structure similar to masonry.

  10. Influence of solution annealing on microstructure and mechanical properties of Maraging 300 steel

    Energy Technology Data Exchange (ETDEWEB)

    Lima Filho, Venceslau Xavier; Barros, Isabel Ferreira; Abreu, Hamilton Ferreira Gomes de, E-mail: venceslau@ifce.edu.br [Universidade Federal do Ceara (UFC), Fortaleza, CE (Brazil). Departamento de Engenharia Metalurgica e Materiais. Laboratorio de Caracterizacao de Materiais, Metalurgia Fisica e Grupo de Pesquisa de Transformacao de Fase

    2017-01-15

    Maraging 300 belongs to a family of metallic materials with extremely high mechanical strength and good toughness. Some works have been published about aging temperatures that improve ultimate strength resistance with acceptable toughness levels in this steel family, where the prior austenite grain size obtained by different solution annealing temperature influence in the final mechanical properties. Solution annealing temperatures ranging from 860 °C to 1150 deg C and were kept constant until the aging temperature. These treatments were used in order to investigate their influence on the microstructure and mechanical properties of maraging steel 300, especially with regard to toughness. The characterization of the microstructure was performed by optical microscopy, scanning electron microscope (SEM) and X-ray diffraction (XRD). Mechanical properties were evaluated by Rockwell C hardness and Charpy impact tests. The results showed that there is a temperature range where one can get some improvement in toughness without a large loss of mechanical strength. (author)

  11. Comparison and analysis of the main technological factors of influencing mechanical properties of scrimber and PSL

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    The main mechanical properties of scrimber and Parallel Strand Lumber (PSL) were researched through technological test. Experimental materials of scrimber are small log of Aspen, Dahurian larch and Birch. Experimental materials of PSL come from fishtail veneer strips at plywood plant of Aspen and Birch. In the laboratory conditions low quality small log and wood residues can yield scrimber and PSL with high strength. After the technological conditions of scrimber were compared with that of PSL, the main factors of influencing their properties were separately pointed out and the reasons influencing properties have been analyzed in this paper. The results showed that the hot-pressing pressure is an important technological factor for scrimber. The ratio of veneer-strand length to thickness is a key technological factor for PSL.

  12. Transport phenomena in the crystallization of lysozyme by osmotic dewatering and liquid-liquid diffusion in low gravity

    Science.gov (United States)

    Todd, Paul; Sportiello, Michael G.; Gregory, Derek; Cassanto, John M.; Alvarado, Ulises A.; Ostroff, Robert; Korszun, Z. R.

    1993-01-01

    Two methods of protein crystallization, osmotic dewatering and liquid-liquid diffusion, like the vapor diffusion (hanging-drop and sessile-drop) methods allow a gradual approach to supersaturation conditions. The crystallization of hen egg-white lysozyme, an extensively characterized protein crystal, in the presence of sodium chloride was used as an experimental model with which to compare these two methods in low gravity and in the laboratory. Comparisons of crystal growth rates by the two methods under the two conditions have, to date, indicated that the rate of crystal growth by osmotic dewatering is nearly the same in low gravity and on the ground, while much faster crystal growth rates can be achieved by the liquid-liquid diffusion method in low gravity.

  13. The influence of Reynolds numbers on resistance properties of jet pumps

    Science.gov (United States)

    Geng, Q.; Zhou, G.; Li, Q.

    2014-01-01

    Jet pumps are widely used in thermoacoustic Stirling heat engines and pulse tube cryocoolers to eliminate the effect of Gedeon streaming. The resistance properties of jet pumps are principally influenced by their structures and flow regimes which are always characterized by Reynolds numbers. In this paper, the jet pump of which cross section contracts abruptly is selected as our research subject. Based on linear thermoacoustic theory, a CFD model is built and the oscillating flow of the working gas is simulated and analyzed with different Reynolds numbers in the jet pump. According to the calculations, the influence of different structures and Reynolds numbers on the resistance properties of the jet pump are analyzed and presented. The results show that Reynolds numbers have a great influence on the resistance properties of jet pumps and some empirical formulas which are widely used are unsuitable for oscillating flow with small Reynolds numbers. This paper provides a more comprehensive understanding on resistance properties of jet pumps with oscillating flow and is significant for the design of jet pumps in practical thermoacoustic engines and refrigerators.

  14. Influence of x-ray radiation on the properties of magnetorheological elastomers

    Science.gov (United States)

    Yu, M.; Fu, J.; Ju, B. X.; Zheng, X.; Choi, S. B.

    2013-12-01

    In this work, the influence of x-ray radiation on the properties of magnetorheological elastomers (MREs) was experimentally investigated. Five MRE samples with the same composition were prepared, and then were irradiated by an x-ray detection machine, with different radiation doses. The microstructures of samples before and after x-ray irradiation were observed by using scanning electron microscopy. The dynamic mechanical properties of all samples were investigated under different magnetic flux densities. The experimental results indicated that the x-rays had a great impact on the properties of MRE. Due to the x-ray radiation, two kinds of radiation-induced effects were generated in the MRE, which were radiation-induced crosslinking and radiation-induced degradation. Based on the influence of the radiation-induced effects on MRE, the initial modulus of the MRE was increased by the radiation-induced crosslinking effect, but the MR effect of the MRE decreased. While the MRE began to degrade, the MR effect of the MRE exhibited a large increasing trend with the increase of the x-ray radiation dose. In addition, the damping property of the MRE was also influenced greatly by the x-ray radiation, and the loss factor of the MRE was increased dramatically first and then decreased under x-ray irradiation. On the basis of these results, this study may provide a good guideline for developing various applications of MREs.

  15. Observations of Three-Dimensional Radiative Effects that Influence Satellite Retrievals of Cloud Properties

    Science.gov (United States)

    Varnai, Tamas; Marshak, Alexander; Lau, William K. M. (Technical Monitor)

    2001-01-01

    This paper examines three-dimensional (3D) radiative effects, which arise from horizontal radiative interactions between areas that have different cloud properties. Earlier studies have argued that these effects can cause significant uncertainties in current satellite retrievals of cloud properties, because the retrievals rely on one-dimensional (1D) theory and do not consider the effects of horizontal changes in cloud properties. This study addresses two questions: which retrieved cloud properties are influenced by 3D radiative effects, and where 3D effects tend to occur? The influence of 3D effects is detected from the wayside illumination and shadowing make clouds appear asymmetric: Areas appear brighter if the cloud top surface is tilted toward, rather than away from, the Sun. The analysis of 30 images by the Moderate Resolution Imaging Spectroradiometer (MODIS) reveals that retrievals of cloud optical thickness and cloud water content are most influenced by 3D effects, whereas retrievals of cloud particle size are much less affected. The results also indicate that while 3D effects are strongest at cloud edges, cloud top variability in cloud interiors, even in overcast regions, also produces considerable 3D effects. Finally, significant 3D effects are found in a wide variety of situations, ranging from thin clouds to thick ones and from low clouds to high ones.

  16. Influence of ionic strength on the rheological properties of hydroxypropylmethyl cellulose-sodium dodecylsulfate mixtures

    Directory of Open Access Journals (Sweden)

    Katona Jaroslav M.

    2015-01-01

    Full Text Available Mixtures of polymers and surfactants are commonly found in a range of products of pharmaceutical, cosmetic, and food industry. Interaction between polymers and surfactants influences different properties of these products, e.g. stability, flow properties, phase behavior, etc. It is known from previous work that an interaction in binary mixtures of hydroxypropylmethyl cellulose (HPMC and sodium dodecylsulfate (SDS takes place when SDS concentration (CSDS. is higher than the critical association concentration (CAC and lower than the polymer saturation point (PSP. The interaction results in the formation of an HPMC-SDS complex. The objective of this work was to study the effect of the ionic strength on the HPMC-SDS complex formation by rheological investigation. The HPMC/SDS mixtures composed of 0.70 % wt. HPMC, and 0.00 % to 2.50 % wt. SDS were prepared in deionized water, 0.01M and 0.05M NaCl solution. It was found that an increase in the ionic strength influences the HPMC-SDS complex formation by increasing the zero shear viscosity of the mixtures in the interaction region (CACPSP. The HPMC/SDS mixtures showed a shear thinning or a shear thickening flow properties depending on CSDS. The flow properties were influenced by the ionic strength of the mixtures.[Projekat Ministarstva nauke Republike Srbije, br. III46010

  17. Polarization properties of real aluminum mirrors; I. Influence of the aluminum oxide layer

    CERN Document Server

    van Harten, G; Keller, C U

    2009-01-01

    In polarimetry it is important to characterize the polarization properties of the instrument itself to disentangle real astrophysical signals from instrumental effects. This article deals with the accurate measurement and modeling of the polarization properties of real aluminum mirrors, as used in astronomical telescopes. Main goals are the characterization of the aluminum oxide layer thickness at different times after evaporation and its influence on the polarization properties of the mirror. The full polarization properties of an aluminum mirror are measured with Mueller matrix ellipsometry at different incidence angles and wavelengths. The best fit of theoretical Mueller matrices to all measurements simultaneously is obtained by taking into account a model of bulk aluminum with a thin aluminum oxide film on top of it. Full Mueller matrix measurements of a mirror are obtained with an absolute accuracy of ~1% after calibration. The determined layer thicknesses indicate logarithmic growth in the first few hou...

  18. Wide – Ranging Influence of Mischmetal on Properties of GP240GH Cast Steel

    Directory of Open Access Journals (Sweden)

    J. Kasińska

    2012-12-01

    Full Text Available This paper presents influence of rare earth metals (REM on the properties of GP240GH cast carbon steel. The research has beenperformed on successive industrial melts. Each time ca 2000 kg of liquid metal was modified. The rare earth metals were put into the ladle during tapping of heat melt from the furnace. Because of this the amount of sulphur in the cast steel was decreased and the non-metallic inclusion morphology was significantly changed. It was found that non metallic inclusions the cracking mechanism of Charpy specimens and the impact strength were all changed. The following properties were tested: mechanical properties (y, UTS, plastic properties (necking, elongation and impact strength (SCI. In the three-point bend test the KJC stress intensity factor was evaluated.

  19. Wide – Ranging Influence of Mischmetal on Properties of GP240GH Cast Steel

    Directory of Open Access Journals (Sweden)

    Kasińska J.

    2012-12-01

    Full Text Available This paper presents influence of rare earth metals (REM on the properties of GP240GH cast carbon steel. The research has been performed on successive industrial melts. Each time ca 2000 kg of liquid metal was modified. The rare earth metals were put into the ladle during tapping of heat melt from the furnace. Because of this the amount of sulphur in the cast steel was decreased and the non-metallic inclusion morphology was significantly changed. It was found that non metallic inclusions the cracking mechanism of Charpy specimens and the impact strength were all changed. The following properties were tested: mechanical properties (σy, σUTS, plastic properties (necking, elongation and impact strength (SCI. In the three-point bend test the KJC stress intensity factor was evaluated.

  20. Influence of hot extrusion on microstructure and mechanical properties of AZ31 magnesium alloy

    Institute of Scientific and Technical Information of China (English)

    WANG Ling; TIAN Su-gui; MENG Fan-lai; DU Hong-qiang

    2006-01-01

    Extrusion treatment is a common method to refine the grain size and improve the mechanical properties of metal material. The influence of hot extrusion on microstructure and mechanical properties of AZ31 magnesium alloy was investigated. The results show that the mechanical properties of AZ31 alloy are obviously improved by extrusion treatment. The ultimate tensile strength (UTS) of AZ31 alloy at room temperature is measured to be 222 MPa, and is enhanced to 265.8 MPa after extrusion at 420℃. The yield tensile strength (YTS) of AZ31 alloy at room temperature is measured to be 84 MPa, and is enhanced to 201 MPa after extrusion at 420℃. The effective improvements on mechanical properties result from the formation of the finer grains during extrusion and the finer particles precipitated by age treatment. The features of the microstructure evolution during hot extruded of AZ31 alloy are dislocation slipping on the matrix and occurrence of the dynamic recrystallization.

  1. Influence of a matrix on properties of mottled cast iron applied for mill rolls

    Directory of Open Access Journals (Sweden)

    J. Krawczyk

    2010-07-01

    Full Text Available Mill rolls are ones of the most expensive tools applied in plastic working processes and have to satisfy several criteria, which allow them to be used. Cast iron mill rolls, due to their fracture toughness and tribological properties, are the most often applied at hot-rolling in the last rolling stands. This results from the smallest dynamic loads of such rolling stands and the decisive influence of the surface quality of these tools on the surface quality of the rolled product. An improper microstructure of rolls can lead to their premature wearing, e.g. broken flanges, pivots twisting off etc. By means of the heat treatment the matrix microstructure and morphology of carbide precipitationscan be modified and this in-turn can influence cast iron properties.Determination of the influence of microstructure changes, caused by the heat treatment, on the properties of EN-GJN-HV300 low-alloycast iron, after its modification and spheroidization – is the aim of the present paper. Those changes are based on the formation pearlitic or bainitic matrices at the similar morphology of graphite and ledeburitic cementite precipitations. The performed investigations should enable designing the heat treatment of cast iron metallurgical rolls in such a way as to obtain the optimal microstructures for functional parameters of these type of tools. The influence of changing the pearlitic matrix into the bainitic one on such properties as: hardness, impact strength, tensile strength, creep limit, bending strength and a stress intensity factor KIc was investigated in this study. Samples for testing, the listed above mechanical properties, were taken from an industrial casting with care to have pieces of very similar crystallization conditions.

  2. Feasibility study of green wastes composting with digested and dewatering sludge from municipal wastewater treatment plant in Iran

    OpenAIRE

    Neamat Jaafarzadeh Haghighi Fard; Behnam Moradi; Mokhtar Abbasi; Rahman Alivar Babadi; Hossein Bahrani; Azadeh Mirzaie; Ahmad Zare Javid; Maryam Ravanbakhsh

    2015-01-01

    Background: Composting as a waste management technology is becoming more widespread. The purpose of this study was to assess the feasibility and to find the most effective composting process for the ratio of green waste, digested and dewatered sludge from Chonibieh wastewater treatment plant in the west region of Ahvaz. Methods: The composting time was 23 days and the evaluated parameters in this period of the study were organic carbon, total nitrogen, phosphorus, carbon to nitrogen ratio ...

  3. Effect of Long-Term Freezing and Freeze–Thaw Cycles on Indigenous and Inoculated Microorganisms in Dewatered Blackwater

    DEFF Research Database (Denmark)

    Gunnarsdottir, Ragnhildur; Müller, Karoline; Jensen, Pernille Erland

    2012-01-01

    coliforms, fecal streptococci, and antibiotic-resistant (AR) bacteria, and inoculated Salmonella Enteriditis and E. coli bacteriophage ΦX174 in dewatered blackwater. At the end of the long-term freezing experiment (10 months), an MPN recovery study was done, including the microbial groups that had shown....... Bacteriophages showed limited reduction during the long-term freezing. Repeated freezing and thawing increased the reduction of all tested microbial groups markedly....

  4. Properties of Chemically Combusted Calcium Carbide Residue and Its Influence on Cement Properties

    Directory of Open Access Journals (Sweden)

    Hongfang Sun

    2015-02-01

    Full Text Available Calcium carbide residue (CCR is a waste by-product from acetylene gas production. The main component of CCR is Ca(OH2, which can react with siliceous materials through pozzolanic reactions, resulting in a product similar to those obtained from the cement hydration process. Thus, it is possible to use CCR as a substitute for Portland cement in concrete. In this research, we synthesized CCR and silica fume through a chemical combustion technique to produce a new reactive cementitious powder (RCP. The properties of paste and mortar in fresh and hardened states (setting time, shrinkage, and compressive strength with 5% cement replacement by RCP were evaluated. The hydration of RCP and OPC (Ordinary Portland Cement pastes was also examined through SEM (scanning electron microscope. Test results showed that in comparison to control OPC mix, the hydration products for the RCP mix took longer to formulate. The initial and final setting times were prolonged, while the drying shrinkage was significantly reduced. The compressive strength at the age of 45 days for RCP mortar mix was found to be higher than that of OPC mortar and OPC mortar with silica fume mix by 10% and 8%, respectively. Therefore, the synthesized RCP was proved to be a sustainable active cementitious powder for the strength enhanced of building materials, which will result in the diversion of significant quantities of this by-product from landfills.

  5. Properties of Chemically Combusted Calcium Carbide Residue and Its Influence on Cement Properties.

    Science.gov (United States)

    Sun, Hongfang; Li, Zishanshan; Bai, Jing; Memon, Shazim Ali; Dong, Biqin; Fang, Yuan; Xu, Weiting; Xing, Feng

    2015-02-13

    Calcium carbide residue (CCR) is a waste by-product from acetylene gas production. The main component of CCR is Ca(OH)₂, which can react with siliceous materials through pozzolanic reactions, resulting in a product similar to those obtained from the cement hydration process. Thus, it is possible to use CCR as a substitute for Portland cement in concrete. In this research, we synthesized CCR and silica fume through a chemical combustion technique to produce a new reactive cementitious powder (RCP). The properties of paste and mortar in fresh and hardened states (setting time, shrinkage, and compressive strength) with 5% cement replacement by RCP were evaluated. The hydration of RCP and OPC (Ordinary Portland Cement) pastes was also examined through SEM (scanning electron microscope). Test results showed that in comparison to control OPC mix, the hydration products for the RCP mix took longer to formulate. The initial and final setting times were prolonged, while the drying shrinkage was significantly reduced. The compressive strength at the age of 45 days for RCP mortar mix was found to be higher than that of OPC mortar and OPC mortar with silica fume mix by 10% and 8%, respectively. Therefore, the synthesized RCP was proved to be a sustainable active cementitious powder for the strength enhanced of building materials, which will result in the diversion of significant quantities of this by-product from landfills.

  6. Evaluation of hyperbaric filtration for fine coal dewatering. Fourth quarterly technical progress report: June 1, 1993--September 30, 1993

    Energy Technology Data Exchange (ETDEWEB)

    Parekh, B.K. [Univ. of Kentucky, Lexington, KY (United States); Hogg, R. [Pennsylvania State Univ., University Park, PA (United States); Fonseca, A. [CONSOL Inc., Library, PA (United States)

    1993-12-31

    The main objectives of the project are to investigate the fundamental aspects of particle-liquid interaction in fine coal dewatering, to conduct laboratory and pilot plant studies on the applicability of hyperbaric filter systems and to develop process conditions for dewatering of fine clean coal to less than 20 percent moisture. The program consist of three phases, Model Development, Laboratory Studies, and Field Testing. The Pennsylvania State University is leading efforts in Phase 1, the University of Kentucky in Phase 2, and Consol Inc. in Phase 3 of the program. All three organizations are involved in all the three phases of the program. The Pennsylvania State University is developing a theoretical model for hyperbaric filtration systems, whereas the University of Kentucky is conducting experimental studies to investigate fundamental aspects of particle-liquid interaction and application of high pressure filter in fine coal dewatering. The optimum filtration conditions identified in phase 1 and 2 will be tested in a Consol Inc. coal preparation plant using an Andritz Ruthner portable hyperbaric filtration unit.

  7. Membrane-based energy efficient dewatering of microalgae in biofuels production and recovery of value added co-products.

    Science.gov (United States)

    Bhave, Ramesh; Kuritz, Tanya; Powell, Lawrence; Adcock, Dale

    2012-05-15

    The objective of this paper is to describe the use of membranes for energy efficient biomass harvesting and dewatering. The dewatering of Nannochloropsis sp. was evaluated with polymeric hollow fiber and tubular inorganic membranes to demonstrate the capabilities of a membrane-based system to achieve microalgal biomass of >150 g/L (dry wt.) and ∼99% volume reduction through dewatering. The particle free filtrate containing the growth media is suitable for recycle and reuse. For cost-effective processing, hollow fiber membranes can be utilized to recover 90-95% media for recycle. Tubular membranes can provide additional media and water recovery to achieve target final concentrations. Based on the operating conditions used in this study and taking into scale-up considerations, an integrated hollow fiber-tubular membrane system can process microalgal biomass with at least 80% lower energy requirement compared to traditional processes. Backpulsing was found to be an effective flux maintenance strategy to minimize flux decline at high biomass concentration. An effective chemical cleaning protocol was developed for regeneration of fouled membranes.

  8. The influence of non-magnetocaloric properties on the AMR performance

    DEFF Research Database (Denmark)

    Nielsen, Kaspar Kirstein; Bahl, Christian; Smith, Anders;

    2012-01-01

    properties (conductivity, specific heat and mass density) and operating parameters (utilization, frequency, number of transfer units etc.). In this paper we focus on the influence of three parameters on regenerator performance: 1) Solid thermal conductivity, 2) magnetostatic demagnetization and 3) flow...... maldistribution due to geometrically non-uniform regenerators. It is shown that the AMR performance is optimal at an intermediate value of the solid thermal conductivity for many operating conditions. The magnetostatic demagnetization is shown to have a significant influence on the AMR performance, giving...

  9. The influence of non-magnetocaloric properties on the performance in parallel-plate AMRs

    DEFF Research Database (Denmark)

    Nielsen, Kaspar Kirstein; Bahl, Christian R.H.; Smith, Anders;

    2014-01-01

    properties (conductivity, specific heat and mass density) and operating parameters (utilization, frequency, number of transfer units etc.). In this paper we focus on the influence of three parameters on regenerator performance: 1) Solid thermal conductivity, 2) magnetostatic demagnetization and 3) flow...... maldistribution due to geometrically non-uniform regenerators. It is shown that the AMR performance is optimal at an intermediate value of the solid thermal conductivity for many operating conditions. The magnetostatic demagnetization is shown to have a significant influence on the AMR performance, giving...

  10. The influence of chemical composition on the properties and structure Al-Si-Cu(Mg alloys

    Directory of Open Access Journals (Sweden)

    M. Kaczorowski

    2007-04-01

    Full Text Available The mechanical properties of different chemical composition AlSiCuMg type cast alloys after precipitation hardening are presented. The aim of the study was to find out how much the changes in chemistry of aluminum cast alloys permissible by EN-PN standards may influence the mechanical properties of these alloys. Eight AlSi5Cu3(Mg type cast alloys of different content alloying elements were selected for the study. The specimens cut form test castings were subjected to precipitation hardening heat treatment. The age hardened specimens were evaluated using tensile test, hardness measurements and impact test. Moreover, the structure investigation were carried out using either conventional light Metallography and scanning (SEM and transmission (TEM electron microscopy. The two last methods were used for fractography observations and precipitation process observations respectively. It was concluded that the changes in chemical composition which can reach even 2,5wt.% cause essential differences of the structure and mechanical properties of the alloys. As followed from quantitative evaluation and as could be predicted theoretically, copper and silicon mostly influenced the mechanical properties of AlSi5Cu3(Mg type cast alloys. Moreover it was showed that the total concentration of alloying elements accelerated and intensifies the process of decomposition of supersaturated solid solution. The increase of Cu and Mg concentration increased the density of precipitates. It increases of strength properties of the alloys which are accompanied with decreasing in ductility.

  11. Influence of sputtering power on the optical properties of ITO thin films

    Energy Technology Data Exchange (ETDEWEB)

    K, Aijo John; M, Deepak, E-mail: manju.thankamoni@gmail.com; T, Manju, E-mail: manju.thankamoni@gmail.com [Department of Physics, Sree Sankara College, Kalady P. O., Ernakulam Dist., Kerala (India); Kumar, Vineetha V. [Dept. of Physics, K. E. College, Mannanam, Kottayam Dist., Kerala (India)

    2014-10-15

    Tin doped indium oxide films are widely used in transparent conducting coatings such as flat panel displays, crystal displays and in optical devices such as solar cells and organic light emitting diodes due to the high electrical resistivity and optical transparency in the visible region of solar spectrum. The deposition parameters have a commendable influence on the optical and electrical properties of the thin films. In this study, ITO thin films were prepared by RF magnetron sputtering. The properties of the films prepared under varying sputtering power were compared using UV- visible spectrophotometry. Effect of sputtering power on the energy band gap, absorption coefficient and refractive index are investigated.

  12. Influence of Alumina Addition on the Optical Property of Zirconia/Alumina Composite Dental Ceramics

    Institute of Scientific and Technical Information of China (English)

    JIANG Li; LIAO Yunmao; LI Wei; WAN Qianbing; ZHAO Yongqi

    2011-01-01

    The influence of various alumina additions on the optical property of zirconia/alumina composite ceramics was investigated.The relative sintered densities,transmittances,color and the microstructure of the composite ceramics were studied.The experimental results showed that the relative sintered densities and transmittances decreased with alumina addition.The lightness increased obviously but the chroma change was small.Pure zirconia nanopowders sintered densely could obtain the relatively high transmittance,while the transmittance and the lightness of slight addition changed significantly.The zirconia/alumina composite ceramics with alumina addition less than 7.5wt% could achieve the relatively stable and reliable optical properties.

  13. How Far Does a Receptor Influence Vibrational Properties of an Odorant?

    DEFF Research Database (Denmark)

    Reese, Anna; List, Nanna Holmgaard; Kongsted, Jacob

    2016-01-01

    -assisted electron transfer reaction. We consider this controversy by studying the influence of a receptor on the vibrational properties of an odorant in atomistic details as the coupling between electronic degrees of freedom of the receptor and the vibrations of the odorant is the key parameter of the vibrationally......-assisted electron transfer. Through molecular dynamics simulations we elucidate the binding specificity of a receptor towards acetophenone odorant. The vibrational properties of acetophenone inside the receptor are then studied by the polarizable embedding density functional theory approach, allowing to quantify...

  14. The influence of assist gas on magnetic properties of electrotechnical steel sheets cut with laser

    Science.gov (United States)

    Gaworska-Koniarek, Dominika; Szubzda, Bronisław; Wilczyński, Wiesław; Drosik, Jerzy; Karaś, Kazimierz

    2011-07-01

    The paper presents the influence of assist gas (air and nitrogen) during laser cutting on magnetization, magnetic permeability and loss characteristics of non-oriented electrical steels. The research was made on an non-oriented M330-50A grade electrical steels by means of single sheet tester. In order to enhance the effect of cutting and the same degradation zone on magnetic properties, strips with different width were achieved. Measurements results indicate that application of air as assist gas has more destructive effect on magnetic properties of electrical steels than nitrogen one.

  15. Influence of Hot Deformation and Subsequent Austempering on the Mechanical Properties of Hot Rolled Multiphase Steel

    Institute of Scientific and Technical Information of China (English)

    Zhuang LI; Di WU

    2006-01-01

    Influence of hot deformation and subsequent austempering on the mechanical properties of hot rolled multiphase steel was investigated. Thermo-mechanical control processing (TMCP) was conducted by using a laboratory hot rolling mill, where three different kinds of finishing rolling reduction, and austemperings with various isothermal holding duration were applied. The results have shown that a multiphase microstructure consisting of polygonal ferrite, granular bainite and larger amount of stabilized retained austenite can be obtained by controlled rolling processes. Mechanical properties increase with increasing the amount of deformation because of the stabilization of retained austenite. Ultimate tensile strength (σb), total elongation (δ)36% and 28476 MPa%, respectively) at optimal processes.

  16. Influence of alloy ingredients on mechanical properties of ternary boride hard alloy clad materials

    Institute of Scientific and Technical Information of China (English)

    LIU Fu-tian; SONG Shi-xue; YANG Jun-ru; HUANG Wei-ling; HUANG Chuan-zhen; CHENG Xin; LI Zhao-qian

    2004-01-01

    Using Mo, B-Fe alloy and Fe powders as raw materials, and adding C, Cr and Ni ingredients, respectively, or C, Cr and Ni mixed powders, ternary boride hard alloy clad materials was prepared on Q235 steel substrate by means of in-situ reaction and vacuum liquid phase sintering technology. The influence of alloy ingredients on the mechanical properties of ternary boride hard alloy clad materials was investigated. The results indicate that a mixture of 0.8% C, 5% Cr and 2% Ni ingredients gives a ternary boride hard alloy clad material with optimal mechanical properties, such as high transverse rupture strength, high hardness and good wear resistance.

  17. Influence of Planting Spacing on Mechanical Properties of Eucalyptus grandis × E. urophylla Planted in China

    Institute of Scientific and Technical Information of China (English)

    HENSON; Michael

    2008-01-01

    The objective of this study was to understand influence of planting spacing on mechanical properties of Eucalyptus grandis × E. urophylla planted as a potential species for solid wood products in China. Four trees at age of 13 were selected from each of 6 groups of planting spacing and a total of 24 sampling trees were selected from the Dongmen Forestry Center of Guangxi Province in China. Furthermore, a one-meter-long log from each tree was cut into small blocks for wood properties testing. MOE, MOR and co...

  18. Influence of Doppler-broadening on absorption-dispersion properties in a resonant coherent medium

    Institute of Scientific and Technical Information of China (English)

    Xu Wei-Hua; Gao Jin-Yue

    2005-01-01

    We investigate the influence of Doppler broadening on absorption-dispersion properties in a four-level atomic system that can evolve from a normal dispersion to an anomalous dispersion. Our results show that the absorption-dispersion properties become strongly dependent on the propagation directions of the applied fields if Doppler broadening is taken into account. Especially, the switchover in the sign of the dispersion is still achievable even in the presence of Doppler broadening if properly arranging the propagation directions of the applied fields, which is in contrast with the otherwise behaviours in some other configurations.

  19. Investigation of influence of micro-structure on magnetic properties of amorphous powder core

    Institute of Scientific and Technical Information of China (English)

    GUO Feng; BA Shan; LI Deren; LU Zhichao; LU Caowei; WANG Jun

    2006-01-01

    The influence of micro-structure on magnetic properties of amorphous powder core was investigated. The results show that the amorphous powders of the powder core become crystallized with the increase of annealing temperature, and the permeability decreases from 60 to 12, the core loss increases from 0.2 to 0.3 W·cm-3 , DC-bias characteristic was improved with further increase of annealing temperature, and the magnetic properties become deteriorated due to decrease of permeability and enhancement of coercive force resulting from the crystallization of amorphous powder.

  20. The Analysis of the Influence of the Polystyrene Patterns Shaping Parameters on the Resistance Properties

    Directory of Open Access Journals (Sweden)

    T. Pacyniak

    2012-04-01

    Full Text Available This work presents the technology of making foam plastics patterns used in casting as well as the final shaping stand. The analysis of the sintering process was carried out aiming at determining the influence of the pressure and the time of sintering on the flexural strength properties. The analysis of the research results confirmed that when the sintering pressure grows to the value of Pa =1,7 bar the flexural strength also increases, when the pressure value is higher than that, the degradation of the material takes place and the strength properties decrease.

  1. Influence of Kind of Weft Yarn on Properties of the Seersucker Woven Fabrics

    Directory of Open Access Journals (Sweden)

    Matusiak Małgorzata

    2016-12-01

    Full Text Available Seersucker woven fabrics create a unique 3D woven structure. Such 3D structure is usually received on loom by an application of two warps of different tension. However, a kind of the weft yarn also significantly influences the structure and properties of the seersucker woven fabric. The paper presents an investigation of the seersucker fabrics made of the same set of warps and different weft yarns. The mechanical properties of the investigated fabrics were measured by means of the standardized testing methods. The structure of the fabric was assessed using the 3D laser scanning.

  2. Influence of sputtering power on the optical properties of ITO thin films

    Science.gov (United States)

    K, Aijo John; Kumar, Vineetha V.; M, Deepak; T, Manju

    2014-10-01

    Tin doped indium oxide films are widely used in transparent conducting coatings such as flat panel displays, crystal displays and in optical devices such as solar cells and organic light emitting diodes due to the high electrical resistivity and optical transparency in the visible region of solar spectrum. The deposition parameters have a commendable influence on the optical and electrical properties of the thin films. In this study, ITO thin films were prepared by RF magnetron sputtering. The properties of the films prepared under varying sputtering power were compared using UV- visible spectrophotometry. Effect of sputtering power on the energy band gap, absorption coefficient and refractive index are investigated.

  3. The Influence of Consumers Behavior on the Variables Determining Residential Property Values in Lagos, Nigeria

    Directory of Open Access Journals (Sweden)

    M. O. Bello

    2007-01-01

    Full Text Available The objective of this study was to assess the influence of consumer behaviour on the variables determining residential property values in Lagos metropolis and how Nigerian valuers are incorporating these in their valuation exercise. The survey which was carried out within a period of three months (January, February and March 2006 involved buyers and valuers which participated in the sales of some properties within Lagos Metropolis. These buyers and valuers were asked to rank on a 4-point likert scale; the relative importance of each of the property attributes which affect the price of the property as perceived by them. The significance of each attribute was then assessed using Relative Importance Index (RII. The significant difference between the ranking of the buyers and valuers was assessed at each variable level and when all the variables were combined using the Kendall test of concordance and tested at .05 level of significant using chi- square approximation. Regressing the attributes of each property against the actual property paid, the significance of each attribute was determined; which was then compared with the ratings of both the valuers and the buyers. The study revealed that the methods of valuation used by the Nigerian estate surveyors and valuers do not take into consideration the buyers preferences in the assessments of residential property value.

  4. Influence of cure via network structure on mechanical properties of a free-radical polymerizing thermoset

    Science.gov (United States)

    Ganglani, Manisha Sachin

    The matrix of a composite material exerts influence over composite properties. The hypothesis is that control of molecular architecture of the matrix allows for the control of resin properties and therefore impacts composite properties. The objective of this research is to define the relationship between cure chemistry, network structure, and final physical properties of vinyl ester-styrene (VE/S) resin, a free-radical polymerizing thermoset polymer often used as the matrix of fiber reinforced polymers. Tensile and fracture properties of the polymer are found to depend on both cure schedule and cure formulation. The possibilities of phase separation and microgel formation being the cause for the differences in mechanical properties are examined. This research shows that the VE/S system does not phase separate under the conditions studied. This proven, the research examines changes in network architecture under different cure conditions. It is found that though bulk properties of the resin are unaffected by the details of the cure, the microscopic morphology, in particular the type of crosslink formed (intermolecular bond or intramolecular bond), is sensitive to both cure temperature and initiation mechanism as determined by cure formulation. Thus, the molecular architecture of the network is responsible for the bulk mechanical properties of the resin. A kinetic analysis shows that both temperature and initiation mechanism affect the apparent "reaction order" of the VE/S system as determined by the autoacceleration equation. This apparent reaction order is interpreted as being an indication of the degree of heterogeneity in the resin. By controlling cure temperature and cure formulation, it is possible to minimize the apparent reaction order and thereby optimize physical properties. Finally, a theory is adapted from other non-network polymer systems to describe qualitatively how cure temperature and initiation mechanism may alter the heterogeneity in network

  5. The Influence of Free Water Content on Dielectric Properties of Alkali Active Slag Cement Paste

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    The dielectric performance of alkali activated slag (AAS) cement paste was investigated in the frequency range of 1 to 1000 MHz. The experimental results showed the unstable dielectric properties of harden paste were mostly influenced by the fraction of free water in paste or absorbed water from ambient, but not including hydration water and microstructure. The free water was completely eliminated by heat treatment at 105 ℃ about 4 hours, and then its dielectric loss was depressed; but with the exposure time in air increasing,the free water adsorption in ambient air made the dielectric property of harden cement paste to be bad. The temperature and relative humidity of environment was the key factors of free water adsorption; hence, if the influence of free water on dielectric constant was measured or eliminated, the cement-based materials may be applied in humidity sensitive materials or dielectric materials domains.

  6. Influence of Conditions of Pd/SnO2 Nanomaterial Formation on Properties of Hydrogen Sensors

    Science.gov (United States)

    Sokovykh, E. V.; Oleksenko, L. P.; Maksymovych, N. P.; Matushko, I. P.

    2017-06-01

    Metal oxide sensors were created using nanosized tin dioxide obtained by a sol-gel method. Gas-sensitive layers of the sensors were impregnated with PdCl2 solutions of different concentrations to increase sensitivities of the proposed sensors. Influence of different temperature conditions of the sensor formation on the sensor properties was studied. It was found that decreasing duration of high-temperature sensor treatment prevents enlargement of particles of the gas-sensitive materials. It was shown that the sensors based on materials with smaller particle sizes showed higher sensor responses to 40 ppm H2. Obtained results were explained in terms of substantial influence of length of the common boundaries between the material particles of tin dioxide and palladium on the gas-sensitive properties of the sensors. The obtained sensors had possessed a fast response and recovery time and demonstrated stable characteristics during their long-term operation.

  7. Influence of perennial plants on chemical properties of arid calcareous soils in Iran

    Energy Technology Data Exchange (ETDEWEB)

    Karimian, N.; Razmi, K. (Shiraz Univ. (Iran))

    1990-10-01

    The authors conducted a study in Bajgah to determine the influence of perennial plants on some selected properties of soils formed on the highly calcareous parent material. The major plant genera were determined to be Agropyron, Artemisia, Astragalus, Dianthus, Eryngium, Peganum, Polygonum, Stipa, and Thymus. Tops of plants genera were found to be significantly different in ash, N, P, K, Ca, Mg, Na, Mn, Zn, and Cu; the concentration of Fe was not significantly different. The authors found the plants to differ significantly in their influence on soil properties. Peganum caused an accumulation of organic matter (OM) as high as 7% in the soil, in an environment where the soils typically contain less than 1% OM. Soil concentrations of P, K, Mn, Zn, and Cu were also found to vary significantly beneath different plant genera. They suggest these differences in OM accumulation were caused by plant litter. Concentration of Fe in the soils formed beneath different plant genera was statistically unchanged.

  8. The influence of high and low temperatures on the impact properties of glass–epoxy composites

    Directory of Open Access Journals (Sweden)

    SLAVISA PUTIC

    2007-07-01

    Full Text Available The aim of this paper is to present the influence of high and low temperatures on the impact properties glass–epoxy composites. The impact strength an is presented for four different glass–epoxy composite structures at three different temperatures, i.e., at room temperature t = 20 °C, at an elevated temperature t = +50 °C and at a low temperature t = –50 °C. Standard mechanical testing was carried out on the composite materials with specific masses of reinforcement of 210 g m-2 and 550 g m-2 and orientations 0°/90° and ±45°. Micromechanical analysis of the failure was performed in order to determine real models and mechanisms of crack and temperature influence on the impact properties.

  9. The Influence of Three-Layer Knitted Fabrics’ Structure on Electrostatic and Comfort Properties

    Directory of Open Access Journals (Sweden)

    Sandra VARNAITĖ ŽURAVLIOVA

    2013-12-01

    Full Text Available In our times, when electricity and electrical devices are around us every day, it is very important to be protected from electrostatic discharge. The best protection from electric charge dissipation provides conductive textile materials. For the last few decades fine and flexible conductive yarns were developed, which ensure very good electrostatic properties. Unfortunately, due to their chemical nature, these yarns do not distinguish good comfort properties. The main purpose of development of such textiles is to determine the influence of conductive yarns and hollow fiber yarns arrangements in the middle layer of the three layer weft-knitted fabrics to electrostatic and comfort properties. So, in order to have flexible textile materials with good electrostatic and comfort properties, multifunctional three layer weft-knitted fabrics of combined pattern were designed and manufactured for this research work. Two groups of polyester based three layer knitted fabrics with different arrangement of conductive yarns (such as carbon core yarn and polyester silver coated yarn and polyester yarn of special design (Coolmax®, Thermolite® were investigated. The parameters of electrostatic characteristics, such as surface and vertical resistances as well as charge decay properties were measured. The results have showed that all tested fabrics have excellent shielding properties. The main influence on the electrostatic properties of tested fabrics has the arrangement of conductive carbon core yarns inserted in the knits. In order to evaluate the comfort of knitted fabrics the air permeability, hygroscopicity, time of absorption and drying degree of fabrics were evaluated. It was determined, that the values of comfort parameters depend on the quantity and distribution of Coolmax® and Thermolite® yarns in the fabrics.DOI: http://dx.doi.org/10.5755/j01.ms.19.4.2235

  10. Influence of amount of graphite and modifying agent on the properties of periclase-carbon refractories

    OpenAIRE

    Борисенко, Оксана Миколаївна

    2016-01-01

    One of the main components of periclase-carbon materials is graphite, which provides high thermal conductivity and slag resistance of refractories. However, at temperatures of 600 °C it begins to oxidize. To prevent oxidation it is proposed to modify the sol-gel graphite by composition based on nickel salts for further formation of NiO coating on its surface, which will provide additional protection. An influence of graphite amount and its modifier agent on physical and mechanical properties ...

  11. The influence of nano-ceramic modifier on the structure and properties of polyolefin composites

    Science.gov (United States)

    Sudnik, L.; Dubkova, V.; Galinovsky, A.; Osipkov, A.

    2016-10-01

    It has been shown, that the nano-ceramic modifier boehmite, with specific surface area of up to 400 m2/g and dispersion degree of less than100 nm, is a structurally active filler of an ultra-high-molecular-weight polyethylene. The boehmite influences the polymer crystalline and supra-molecular structure, during crystallization of the polymer from the melt under uniaxial plastic deformation conditions. It results in the production of nano-composites with an improved complex of properties.

  12. Influence of Microstructure and Sintering Routes on Transport Properties of Apatite Materials for Fuel Cells

    Institute of Scientific and Technical Information of China (English)

    A.Chesnaud; C.Estournes; G.Dezannau

    2007-01-01

    1 Results Oxy-apatite materials are thought as zirconia-substitutes in Solid Oxide Fuel Cells due to their fast ionic conduction. However, the well known difficulties related to their densification prevent them from being used as such. This study presents strategies to obtain oxy-apatite dense materials and the influence of elaboration route on transport properties. Particular emphasis is put on the microstructure effect on ion conduction. By the combined use of freeze-drying and conventional or spark p...

  13. Influence of Zwitterions on Thermomechanical Properties and Morphology of Acrylic Copolymers: Implications for Electroactive Applications

    Science.gov (United States)

    2011-09-30

    properties of ethyl acrylate and n-butyl acrylate ( nBA )-based sulfobetaine-containing copolymers.10,11 They found that the incorporation of...ammonio]-1-propanesulfonate (SBMA), a zwitterionic mono- mer. Copolymerization of both charge-containing monomers with nBA elucidates the influence of...3-[[2-(methacryloyloxy)ethyl]- (dimethyl)ammonio]-1-propanesulfonate (SBMA), was generously provided by Raschig GmbH. n-Butyl acrylate ( nBA , Alfa

  14. Influence of the morphology on mechanical properties of toughened epoxies with CTBN

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    Presents a toughened-epoxy risen based on diglycidylether of bisphenol A (DGEBA) cured with ethylene-diamine (EDA) and modified with a carboxyl-terminated acrylonitrile-butadiene (CTBN), studies morphologies with different rubber content and analyses the influence of rubber-phase morphology corresponding to different rubber contents on mechanical properties (elastic modulus, uniaxial compression yield stress, shearing strength, uneven tensile strength, critical stress intensity factor Kic and strain energy release rate Gic) of toughened epoxies.

  15. Influence of Synthetic Fibers Angle Orientation on Bending Properties of Composite Plywood

    OpenAIRE

    Mladen Brezović; Jaroslav Kljak; Stjepan Pervan; Alan Antonović

    2010-01-01

    This paper presents the results of research on carbon fiber angle orientation and quantity of carbon fi bers in yarn on bending properties of plywood. For that purpose the specimens have been defined as multilayer composites made from carbon fibers and veneer. Carbon fibers were inserted in the second and third glue line of the composite with angle variation of 15°. Stresses and strain were analyzed in significant layers together with displacement of the whole composite plate. The influence o...

  16. Influence of Composition on Properties of BNT-BT Lead-Free Piezoceramics

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    Lead-free piezoelectric ceramics of (Bi1/2Na1/2)TiO3-BaTiO3(BNT-BT) were prepared by the conventional piezoelectric ceramic preparation technique (free air atmosphere sintering). The influence of BaTiO3 additive amount and La2O3 additive amount on the properties of BNT-BT lead-free piezoceramics were investigated. The results show that the dielectric constant(ε) and piezoelectric strain constant(d33) of materials start increasing and then decreasing while BaTiO3 additive amount increasing, the ε and d33 of materials have maximum value (ε=1650, d33=120 PC·N-1) while x(BaTiO3)=0.06 mol. The ε and d33 of materials start increasing and then decreasing while La2O3 additive amount increasing, the ε and d33 of materials have maximum value (ε=1684, d33=153 PC·N-1) while w(La2O3)=0.3%. The influence of La2O3 additive amount on the microstructure of BNT-BT piezoelectric ceramics was analysed by SEM(scanning electron microscope). The influence mechanism of La2O3 additive amount on the properties of BNT-BT piezoelectric ceramics was discussed. The BNT-BT ceramics with optimum comprehensive properties were obtained.

  17. Mining nutrients (N, K, P) from urban source-separated urine by forward osmosis dewatering.

    Science.gov (United States)

    Zhang, Jiefeng; She, Qianhong; Chang, Victor W C; Tang, Chuyang Y; Webster, Richard D

    2014-03-18

    Separating urine from domestic wastewater promotes a more sustainable municipal wastewater treatment system. This study investigated the feasibility of applying a forward osmosis (FO) dewatering process for nutrient recovery from source-separated urine under different conditions, using seawater or desalination brine as a low-cost draw solution. The filtration process with the active layer facing feed solution exhibited relatively high water fluxes up to 20 L/m(2)-h. The process also revealed relatively low rejection to neutral organic nitrogen (urea-N) in fresh urine but improved rejection of ammonium (50-80%) in hydrolyzed urine and high rejection (>90%) of phosphate, potassium in most cases. Compared to simulation based on the solution-diffusion mechanism, higher water flux and solute flux were obtained using fresh or hydrolyzed urine as the feed, which was attributed to the intensive forward nutrient permeation (i.e., of urea, ammonium, and potassium). Membrane fouling could be avoided by prior removal of the spontaneously precipitated crystals in urine. Compared to other urine treatment options, the current process was cost-effective and environmentally friendly for nutrient recovery from urban wastewater at source, yet a comprehensive life-cycle impact assessment might be needed to evaluate and optimize the overall system performance at pilot and full scale operation.

  18. Syneresis cracks: subaqueous shrinkage in argillaceous sediments caused by earthquake-induced dewatering

    Science.gov (United States)

    Pratt, Brian R.

    1998-04-01

    Syneresis cracks, often confused with subaerial desiccation phenomena, are traditionally ascribed to subaqueous shrinkage whereby salinity changes caused deflocculation of clay. This and other previously proposed mechanisms fail to account for their occurrence in low-energy, typically non-evaporitic facies, stratigraphically sporadic distribution, intrastratal formation under shallow burial depths, variation in morphology, degree of contraction, generation of sedimentary dikelets as crack fills, and deformation of dikelets and enclosing layers. Instead, it is suggested that ground motion from strong synsedimentary earthquakes caused argillaceous sediments to dewater, interbedded sands and silts to be almost simultaneously liquefied and injected into the resulting fissures, and then these dikelets to be distorted. Comparative rarity of syneresis cracks in Phanerozoic versus Precambrian marine strata is considered to be primarily an evolutionary consequence of theological changes caused by increased organic binding of clay flocs in the water column, greater input of organic matter into the sediment, and the diversification of sediment-dwelling bacteria and meiofauna in Phanerozoic deposits.

  19. Cr and Ni recovery during bioleaching of dewatered metal-plating sludge using Acidithiobacillus ferrooxidans.

    Science.gov (United States)

    Rastegar, S O; Mousavi, S M; Shojaosadati, S A

    2014-09-01

    This study determined the optimal conditions required to attain maximum metal recovery in the bioleaching process of dewatered metal-plating sludge using Acidithiobacillus ferrooxidans (A. ferrooxidans). Adaptation of this strain was carried up to 1% (w/v) of the sample. Three factors including initial pH, initial Fe(3+) concentration and pulp density were selected as the effective factors and were optimized using a central composite design of response surface methodology. An initial pH of 1, pulp density of 9 g/l and initial Fe(3+) concentration of 1g/l were determined to be optimum values by the statistical models. The highest extractions for Cr and Ni under optimal conditions were 55.6% and 58.2%, respectively. Bioleaching kinetics was investigated using a modified shrinking core model to better understand the mechanism of the leaching reaction. The model predictions indicate that the diffusion step controlled the overall dissolution kinetics and is the rate controlling step.

  20. Brown Coal Dewatering Using Poly (Acrylamide-Co-Potassium Acrylic Based Super Absorbent Polymers

    Directory of Open Access Journals (Sweden)

    Sheila Devasahayam

    2015-09-01

    Full Text Available With the rising cost of energy and fuel oils, clean coal technologies will continue to play an important role during the transition to a clean energy future. Victorian brown coals have high oxygen and moisture contents and hence low calorific value. This paper presents an alternative non evaporative drying technology for high moisture brown coals based on osmotic dewatering. This involves contacting and mixing brown coal with anionic super absorbent polymers (SAP which are highly crossed linked synthetic co-polymers based on a cross-linked copolymer of acryl amide and potassium acrylate. The paper focuses on evaluating the water absorption potential of SAP in contact with 61% moisture Loy Yang brown coal, under varying SAP dosages for different contact times and conditions. The amount of water present in Loy Yang coal was reduced by approximately 57% during four hours of SAP contact. The extent of SAP brown coal drying is directly proportional to the SAP/coal weight ratio. It is observed that moisture content of fine brown coal can readily be reduced from about 59% to 38% in four hours at a 20% SAP/coal ratio.

  1. Strategies for Treating and Dewatering Contaminated Soils and Sediments Simultaneously - 13389

    Energy Technology Data Exchange (ETDEWEB)

    Bickford, Jody; Foote, Martin [MSE Technology Applications, Inc., 200 Technology Way, Butte, MT 59701 (United States)

    2013-07-01

    MSE Technology Applications, Inc. (MSE) was asked to perform a series of treatability studies by Global Technologies, Inc. (Global) and M{sup 2} Polymer Technologies, Inc. (M{sup 2} Polymer) using Global's metal treatment agent, Molecular Bonding System (MBS) and M{sup 2} Polymer's super-absorbent polymer, Waste Lock 770 (WL-770). The primary objective of the study was to determine if the two products could be used as a one-step treatment process to reduce the leachability of metals and de-water soils and/or sediments simultaneously. Three phases of work were performed during the treatability study. The first phase consisted of generating four bench-scale samples: two treated using only MBS and two treated using only WL- 770, each at variable concentrations. The second phase consisted of generating nine bench-scale samples that were treated using MBS and WL-770 in combination with three different addition techniques. The third phase consisted of generating four intermediate-scale samples that were treated using MBS and WL-770 simultaneously. The soils used in the treatability study were collected at the Mike Mansfield Advanced Technology Center in Butte, Montana. The collected soils were screened at 4 mesh (4.75 millimeters (mm)) to remove the coarse fraction of the soil and spiked with metallic contaminants of lead, cadmium, nickel, mercury, uranium, chromium, and zinc. (authors)

  2. THE ROLE OF PRESS FABRIC PRESSURE UNIFORMITY AND PORE SIZE ON DEWATERING AND REWET DURING PRESSING

    Institute of Scientific and Technical Information of China (English)

    Xiaolin Fan; Mary Toney; Jorgen Gullbrand; Fawaad Qamar

    2004-01-01

    New procedures for measuring the pressure uniformity and pore size of press fabrics have been developed to study their role in the dewatering efficiency of a wet paper sheet and fabric system during pressing. The press nip profile of a single nip can be simulated in the laboratory using a custom built Servo-hydraulic Press Nip Simulator (SPNS) and is used to evaluate the final dryness and rewet of a handsheet with press fabric(s). Pressure uniformity can be measured with a flexible high-resolution transducer and pore size; both tests measured using water as the fluid are performed on compressed press fabric samples. A strong correlation is found between pressure uniformity parameters, mean flow pore size and final dryness for different sheets. Rewet is measured "directly" using a tracer fluid in the press fabric in our SPNS tester. Preliminary results indicate a significant reduction in rewet for some sheets with the use of an anti-rewet layer in combination withcertain press fabric designs.

  3. Influence of reduction conditions of NiO on its mechanical and electrical properties

    Directory of Open Access Journals (Sweden)

    Yehor Brodnikovskyi

    2016-04-01

    Full Text Available Yttria stabilized zirconia with a nickel catalyst (Ni-YSZ is the most developed, widely used cermet anode for manufacturing Solid Oxide Fuel Cells (SOFCs. Its electro-catalytic properties, mechanical durability and performance stability in hydrogen-rich environ­ments makes it the state of the art fuel electrode for SOFCs. During the reduction stage in initial SOFC operation, the virgin anode material, a NiO-YSZ mixture, is reduced to Ni-YSZ. The volume decrease associated with the change from NiO-YSZ to Ni-YSZ creates voids and causes structural changes, which can influence the physical properties of the anode. In this work, the structural, mechanical and electrical properties of NiO samples before and after reduction in pure H2 and a mixture of 5 vol. % H2-Ar were studied. The NiO to Ni phase transformations that occur in the anode under reducing and Reduction-Oxidation (RedOx cycling conditions and the impact on cell microstruc­ture, strength and electrical conductivity have been examined. Results show that the RedOx treatment of the NiO samples influence on their properties controversially, due to structural transfor­mation (formation of large amount of fine pores of the reduced Ni. It strengthened the treated samples yielding the highest mechanical strength values of 25.7 MPa, but from another side it is resulting in lowest electrical conductivity value of 1.9×105 S m-1 among all reduced samples. The results of this investigation shows that reduction conditions of NiO is a powerful tool for influence on properties of the anode substrate.

  4. Influence of carbonisation on selected engineering properties of carbon resin electrodes for electrochemical treatment of wastewater

    Energy Technology Data Exchange (ETDEWEB)

    Oke, I.A. [Obafemi Awolowo Univ., Ile-Ife (Nigeria). Dept. of Civil Engineering

    2009-10-15

    Carbon resin electrodes (CRE) developed using a non-heat treatment process were investigated in an effort to determine the influence of several properties on electrode performance. These included density; electrical resistance; microstructure; hydroscopy; stability moisture content; and compressive and flexural strength. The influences of carbonization temperature, carbon particle size, and compaction pressure were also analyzed. Results of the study showed that the electrical resistance and density of the CRE decreased with increases in carbonization temperatures. Particle size, compacting pressure, and the percentage of resin used in the electrodes also influenced electrical resistance. The carbonization of the CREs from 30 to 220 degrees C reduced specific electrical resistance and density. The carbonization temperature did not have a significant effect on wetness, compressive and flexural strength, or on the stability and moisture content of the electrodes. It was concluded that the cost of producing the CREs is significantly cheaper than the cost of heat-treated electrodes. 78 refs., 9 tabs., 8 figs.

  5. Characterization of morphology and component of struvite pellets crystallized from sludge dewatering liquor: Effects of total suspended solid and phosphate concentrations.

    Science.gov (United States)

    Ping, Qian; Li, Yongmei; Wu, Xinghai; Yang, Lu; Wang, Lin

    2016-06-05

    A lab-scale struvite pellet crystallization system was used to study phosphorus (P) removal and recovery from sludge dewatering liquor (SDL). Influences of total suspended solids (TSS) and phosphate concentrations on P removal as well as the size, morphology, purity, and components of struvite pellets were investigated. The increase in TSS concentration resulted in not only the decreases in phosphate removal efficiency and struvite purity but also the irregular pellet morphology and broken struvite crystals. Increasing inlet PO4-P concentration enhanced PO4-P removal, average struvite pellet diameter, purity and crystal volume growth rate. Amorphous calcium phosphate (ACP), calcite, brucite and magnesium phosphate were formed as co-precipitates with struvite. However, species and quantity of co-precipitates could be variable. More calcium precipitates were easily formed at lower PO4-P concentration (48mg/L), while brucite was the main co-precipitate at higher PO4-P concentration (151mg/L). Organic compounds were involved in struvite pellets along with suspended solids during the formation of struvite. Higher TSS concentration resulted in both more species and higher contents of organic compounds in struvite pellets. Therefore, it is essential to remove suspended solids in advance so as to obtain high P-removal and harvest high-quality struvite pellets. Copyright © 2016 Elsevier B.V. All rights reserved.

  6. Influence of flocculation and settling properties of activated sludge in relation to secondary settler performance.

    Science.gov (United States)

    Wilén, B M; Onuki, M; Hermansson, M; Lumley, D; Mino, T

    2006-01-01

    Floc characteristics were studied at a full scale activated sludge treatment plant with a unique process solution incorporating pre-denitrification with post-nitrification in nitrifying trickling filters. Since greater nitrogen removal is achieved when more secondary settled wastewater is recirculated to the trickling filters, the secondary settlers are always operated close to their maximal capacity. The flocculation and settling properties are therefore crucial and have an effect on the overall plant performance. Since the plant is operated at a short sludge age, these properties change quickly, resulting in variable maximal secondary settler capacity. The dynamics in floc structure and microbial community composition were studied and correlated to the secondary settler performance. Fluorescence in situ hybridisation was used to investigate the microbial community structure and their spatial distribution. The floc structure could to some extent be related to the flocculation and settling properties of the sludge. Even small differences had an influence suggesting that colloidal properties also play a significant role in determining the floc properties. No correlation between microbial community composition and settling properties could be established with the group-specific probes investigated.

  7. Influence Parameters on Properties of Dolomite Bricks Containing Different Bonding Systems

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    Pitch and tar bonded dolomite bricks are extensively used in ladles and converters for long time because of their superior properties such as: steel melt refining, easy production as well as low production cost. Recently,resin bonded dolomite bricks are presented for using in steel plants. Generally, quality and final cost of steels are affected by properties of refractories especially dolomite bricks. Therefore, recognition of influence parameters on dolomite refractory properties is very important.In this study, the effects of tar and resin as bonding systems, and addition of graphite ( 2wt% ) on the properties of dolomite refractory bricks have been investigated.Properties such as: density and porosity, cold crushing strength, hydration time and depth of slag penetration have been studied. Results show that the bonding systems and graphite have a great effect on the mentioned properties especially cold crushing strength and hydration time. In addition to their low rate of pollution, resin bonded dolomite bricks show higher performance with proper technical specifications.

  8. Treatment of petroleum contaminated soils by hot alkaline water combined with mechanical dewatering process%热碱水洗-机械脱水工艺处理石油污染土壤

    Institute of Scientific and Technical Information of China (English)

    谭蔚; 邢帅; 贡皓霜; 刘丽艳

    2016-01-01

    The treatment of petroleum contaminated soils by hot alkaline water combined with mechanical dewatering process is conducted in an oil field in China.The effect of NaOH concentration,alkaline water-oily sludge ratio and temperature on the oil-removal effect is studied.The factors affecting the filtration and dewatering performance of the petroleum contaminated soils treated by hot alkaline water,such as the types and contents flocculating agents,are also investigated.The results show that residual oil is firstly decreased and then increased with increasing the concentration of NaOH and alkaline water-oily sludge ratio.But,the increase in temperature leds to th drastical decrease in residual oil.The proper parameters for hot alkaline water treatment are 0.2% of NaOH,4:1 of alkaline water-oily sludge ratio and 80℃ of temperature.In the experiments of dewatering,the flocculation capability of AlCl3,Fe2 (SO4) 3 and PAC are strongly influenced by pH.The Ca2+ ions effectively incresase the flocculation of tiny particles by forming Ca(OH) + and Ca(OH) 2,thus greatly improving the filtration and dewatering performance.When the concentration of CaCl2 is 0.8%,the best filtration and dewatering performance can be achieved based on the filtration rate,moisture content and residual oil ratio in the petroleum contaminated soils.%采用热碱水洗-机械脱水工艺对国内某油田区的石油污染土壤进行处理.考察了热碱水洗条件(包括NaOH质量分数、液固比、洗涤温度)对含油土壤脱油效果的影响,及絮凝剂种类、质量分数对热碱水洗法处理后的含油污泥过滤脱水性能的影响.结果表明,残余油质量分数随NaOH质量分数及液固比的升高呈现先下降后上升的趋势,而随温度的升高呈现持续下降的趋势.在探究含油污泥脱水性能实验中发现铝盐及铁盐类絮凝剂对于高碱性污泥的适应性较差,而钙盐可以很好地破坏油水细砂混合层,有效地改善含油

  9. Influence of Cryogenic Temperatures on the Microstructure and Mechanical Properties of Magnesium Alloys: A Review

    Directory of Open Access Journals (Sweden)

    Hajo Dieringa

    2017-01-01

    Full Text Available Magnesium alloys have been used in the automotive industry and 3C (computer, communication, and consumer electronics for many years. Their room temperature properties combined with their low density offer a wide range of applications, especially when processed by High Pressure Die Casting (HPDC. The use of magnesium alloys at higher temperatures is well-studied; special creep resistant alloys containing the rare earth elements silver or yttrium are needed. However, when it comes to very low temperatures, only a few studies have been performed to determine the property-microstructure relationship. The possible fields of application at low temperatures are aerospace and satellite parts and tanks for liquefied gases. This review shall not only examine mechanical properties at low temperatures, but also the permanent effects of cyclic or long-lasting cryogenic treatment on the microstructure and mechanical properties. It was found that cryogenic treatment is able to influence the precipitate concentration and grain orientation in some magnesium alloys. Reduction in the number of brittle phases is improving ductility in some cases. It is well-known that high speed tool steels, in particular, can be influenced by cryogenic treatment. Whether this is possible with magnesium alloys and what the mechanisms are shall be reviewed.

  10. Rheological properties of wheat starch influenced by amylose-lysophosphatidylcholine complexation at different gelation phases.

    Science.gov (United States)

    Ahmadi-Abhari, S; Woortman, A J J; Hamer, R J; Loos, K

    2015-05-20

    Amylose is able to form helical inclusion complexes with lysophosphatidylcholine (LPC). This complexation influences the functional and rheological properties of wheat starch; however it is well known that the formation of these complexes lead the starchy systems to a slower enzymatic hydrolysis. Based on this, to benefit from both the structuring properties of starch and also lower digestibility of the inclusion complexes, the objective of this study is the formation of amylose-LPC inclusion complexes while developing a firm network providing the desired functional properties in a starchy system. To investigate the influence of amylose-LPC complex formation at different stages of starch gelation on the viscosity behavior of wheat starch, 3% (w/w) LPC was added at three different points of the viscosity profile, obtained by rapid visco analyzer (RVA). LPC addition at all points affected the gelation behavior of wheat starch as compared with the reference. LPC addition at half-peak and peak of the viscosity profile resulted in a viscosity increase during cooling. Measuring the dynamic rheological properties of the freshly prepared gelatinized samples showed a decrease of storage modulus (G') and loss modulus (G") in the presence of LPC. During storage, in the presence of LPC, a lower elasticity was observed which indicates a lower rate of amylose retrogradation due to complexation with LPC.

  11. An influence of a Glass Braze Composition on the Properties of Li-Ti Ferrite Joints

    Science.gov (United States)

    Lin, Panpan; Lin, Tiesong; He, Peng; Sekulic, Dusan P.; Zhao, Mengyuan; Wang, Shulei

    2017-04-01

    The influence of the chemical composition of Bi2O3-B2O3-SiO2-ZnO glass brazes on (i) the microstructure, (ii) the mechanical and (iii) the dielectric properties of Li-Ti ferrite joints was systematically investigated. The Bi5(Ti3Fe)O15 whisker and a white block phase consisting of Bi12SiO2 and Bi24B2O39 were observed in the joints of Li-Ti ferrite/Bi25-Ba and Li-Ti ferrite/glass brazes, respectively, containing a higher content of Bi2O3. No crystalline phase was detected in the Li-Ti ferrite/Bi25 and Li-Ti ferrite/Bi20 joints. The joint strength reached the maximum of 48 MPa in the Li-Ti ferrite/Bi25-Ba couples. It is assumed that this is mainly due to the strengthening effect of Bi5(Ti3Fe)O15 whiskers. The bonding temperature (700°C) had little effect on the dielectric properties of Li-Ti ferrite. Moreover, compared to the Bi25-Ba glass brazes, the Bi25 and Bi20 glass brazes had a less pronounced influence on the dielectric properties of joints. Different glass brazes can be tailored to different requirements depending on specific application and joint property requirements.

  12. The Influence of Fiber Type and Conformation on the Damping Property of FRP Composite

    Institute of Scientific and Technical Information of China (English)

    WANG Xiang; CHEN Wei; WANG Jun; LIU Hanxing

    2012-01-01

    In order to get a fiber reinforced plastic(FRP) composite with good damping property as well as good mechanical properties,different types of reinforcing materials were used to reinforcing a damping resin.The influence of fiber types and conformation on the damping property of the composite are tested.Compared to the glass fiber(GF),carbon fiber(CF) can improve the damping factor of the composites; the highest tanδ value is 0.827 while the Tg is 22.5 ℃.The style of the fibers also influences the damping factors of the composite.The composite reinforced with mat has higher loss factors than that composite reinforced with clothe for the reason that the former has the ability to deform and the composite has higher resin content.The loss factor of GF mat reinforced composite is 0.704 while the T is 27 ℃.Both composite has good damping properties and can be used as the damping layer of the structural damping composite.

  13. Influence of laser power on tensile properties and material characteristics of laser-sintered UHMWPE

    Directory of Open Access Journals (Sweden)

    Khalil Yas

    2016-01-01

    Full Text Available Ultra High Molecular Weight Polyethylene (UHMWPE has excellent properties, such as high mechanical performance, low friction, high wear and chemical resistance but so far there has been limited use in additive manufacturing (AM. Laser sintering of polymers is one of the most promising AM technologies due to its ability to produce complex geometries with accurate dimensions and good mechanical properties. Consequently, this study investigates the influence of laser power on physical and mechanical properties of UHMWPE parts produced by laser sintering. In particular mechanical properties, such as Ultimate Tensile Strength (UTS, Young’s Modulus and elongation at break were evaluated alongside relative density, dilation and shrinkage. Finally, the fracture surface of the tensile test specimens was examined by electron microscopy. Results show that within a laser power range of 6–12 W there appears to be an optimum where tensile strength and relative density reach a maximum, dilation is minimised and where elongation increases with laser power. UTS up to 2.42 MPa, modulus up to 72.6 MPa and elongation at break up to 51.4% were observed. Relative density and part dimensions are also influenced by laser power.

  14. Influence of increasing amount of recycled concrete powder on mechanical properties of cement paste

    Science.gov (United States)

    Topič, Jaroslav; Prošek, Zdeněk; Plachý, Tomáš

    2017-09-01

    This paper deals with using fine recycled concrete powder in cement composites as micro-filler and partial cement replacement. Binder properties of recycled concrete powder are given by exposed non-hydrated cement grains, which can hydrate again and in small amount replace cement or improve some mechanical properties. Concrete powder used in the experiments was obtained from old railway sleepers. Infrastructure offer more sources of old concrete and they can be recycled directly on building site and used again. Experimental part of this paper focuses on influence of increasing amount of concrete powder on mechanical properties of cement paste. Bulk density, shrinkage, dynamic Young’s modulus, compression and flexural strength are observed during research. This will help to determine limiting amount of concrete powder when decrease of mechanical properties outweighs the benefits of cement replacement. The shrinkage, dynamic Young’s modulus and flexural strength of samples with 20 to 30 wt. % of concrete powder are comparable with reference cement paste or even better. Negative effect of concrete powder mainly influenced the compression strength. Only a 10 % cement replacement reduced compression strength by about 25 % and further decrease was almost linear.

  15. INFLUENCE OF COLD ROLLING REDUCTION ON MICROSTRUCTURE AND MECHANICAL PROPERTIES OF TWIP STEEL

    Institute of Scientific and Technical Information of China (English)

    Z.L. Mi; D. Tang; Y.J. Dai; H.Q. Wang; S.S. Li

    2007-01-01

    The influence of cold rolling reduction on microstructure and mechanical properties of the TWIP (ttwinning induced plasticity) steel was investigated. The results indicated that the steel had better comprehensive mechanical properties when cold rolling reduction was about 65.0% and the annealing temperature was 1000℃. The tensile strength of the steel is about 640MPa and the yield strength is higher than 255MPa, while the elongation is above 82%. The microstructure is composed of austenitic matrix and annealing twins at room temperature, at the same time, a significant amount of annealing twins and stacking faults are observed by transmission electron microscopy (TEM). Mechanical twins play a dominant role during deformation, and result in excellent mechanical properties.

  16. Influence of structural defects on the optical properties of strongly coupled Au nanoshell arrays

    Science.gov (United States)

    Zhou, Xin; Fang, JianShu; Liao, XiangPing; Zhu, QianQuan; Liu, ZhiMin; Tang, Bin

    2013-09-01

    The effects of different defects on optical properties and plasmon resonances properties of Au nanoshell arrays were investigated by using the finite-difference time-domain (FDTD) theory. It is found that the optical properties of the nanoshell arrays are strongly influenced by different defects. We show that when the hollow Au nanoshell arrays are placed in air, there is a wide photonic band gap (PBG) in the infrared region, but the band gap becomes narrower as we introduced different defects. Based on the distributions of electric field component E z and the total energy distribution of the electric and the magnetic field, we show that there exhibit dipoles field distributions for the plasmon mode at the long-wavelength edge of the band gap, but composite higher order modes are excited at the short-wavelength edge of the band gap. The plasmon resonant modes also can be controlled by introducing defects.

  17. Influence of hydroxypropylmethylcellulose addition and homogenization conditions on properties and ageing of corn starch based films.

    Science.gov (United States)

    Jiménez, Alberto; Fabra, María José; Talens, Pau; Chiralt, Amparo

    2012-06-20

    Edible films based on corn starch, hydroxypropyl methylcellulose (HPMC) and their mixtures were prepared by using two different procedures to homogenize the film forming dispersions (rotor-stator and rotor-stator plus microfluidizer). The influence of both HPMC-starch ratio and the homogenization method on the structural, optical, tensile and barrier properties of the films was analysed. The ageing of the films was also studied by characterizing them after 5 weeks' storage. Starch re-crystallization in newly prepared and stored films was analysed by means of X-ray diffraction. HPMC-corn starch films showed phase separation of polymers, which was enhanced when microfluidization was applied to the film forming dispersion. Nevertheless, HPMC addition inhibited starch re-crystallization during storage, giving rise to more flexible films at the end of the period. Water barrier properties of starch films were hardly affected by the addition of HPMC, although oxygen permeability increased due to its poorer oxygen barrier properties.

  18. Influence of metallic vapours on the properties of air thermal plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Cressault, Y; Hannachi, R; Teulet, Ph; Gleizes, A [LAPLACE - UMR CNRS 5213, Universite de Toulouse 3, 118 route de Narbonne, 31062 Toulouse Cedex 9 (France); Gonnet, J-P; Battandier, J-Y [Schneider Electric, Innovation Division, 38TEC/T3 Plant, 37 Quai Paul-Louis Merlin F38000 Grenoble (France)], E-mail: yann.cressault@laplace.univ-tlse.fr

    2008-08-01

    This paper deals with properties of air thermal plasmas containing vapours of iron, silver or copper. The plasma is supposed to be in local thermodynamic equilibrium, for temperatures ranging from 2000 to 30 000 K. First, the equilibrium composition and thermodynamic properties are presented. Then, the radiative properties are calculated using the method of the net emission coefficient. Finally, the viscosity, electrical and thermal conductivities are calculated using the method of Chapman-Enskog. For all mixtures, mole fractions have been used. The results are computed for various values of pressure, plasma size and proportions of vapours. The influence of metallic vapour is important on the electrical conductivity and on the radiation, even at low concentration. All the metallic vapours present a similar behaviour except iron, which has a stronger radiation emission than the other components.

  19. Influence of bias on properties of carbon films deposited by MCECR plasma sputtering method

    Institute of Scientific and Technical Information of China (English)

    CAI Chang-long; DIAO Dong-feng; S.Miyake; T.Matsumoto

    2004-01-01

    The mirror-confinement-type electron cyclotron resonance(MCECR) plasma source has high plasma density and high electron temperature. It is quite useful in many plasma processing, and has been used for etching and thin-film deposition. The carbon films with 40 nm thickness were deposited by MCECR plasma sputtering method on Si, and the influence of substrate bias on the properties of carbon films was studied. The bonding structure of the film was analyzed by the X-ray photoelectron spectroscopy(XPS), the tribological properties were measured by the pin-on-disk(POD) tribometer, the nanohardness of the films was measured by the nanoindenter, and the deposition speed and the refractive index were measured by the ellipse meter. The better substrate bias was obtained, and the better properties of carbon films were obtained.

  20. Influence of molybdenum on the creep properties of nickel-base superalloy single crystals

    Science.gov (United States)

    Mackay, R. A.; Nathal, M. V.; Pearson, D. D.

    1990-01-01

    The Mo content of an alloy series based on Ni-6 wt pct Al-6 wt pct Ta was systematically varied from 9.8 to 14.6 wt pct, in order to ascertain the influence of Mo on the creep properties of single crystals. The optimum initial gamma-gamma prime microstructure for raft development and creep strength was established in each alloy before testing. It was found that, as the Mo content increased from 9.8 to 14.0 percent, the magnitude of the lattice mismatch increased; upon reaching 14.6 percent, a degradation of mechanical properties occurred due to the precipitation of a third phase. These results suggest that small refractory metal content and initial gamma-prime variations can profoundly affect mechanical properties.

  1. Influence of Hot Rolling Conditions on the Mechanical Properties of Hot Rolled TRIP Steel

    Institute of Scientific and Technical Information of China (English)

    LI Zhuang; WU Di

    2008-01-01

    Influence of hot rolling conditions on the mechanical properties of hot rolled TRIP steel was investigated.Thermomechanical control processing(TMCP)was conducted by using a laboratory hot rolling mill,in which three different kinds of finish rolling temperatures were applied.The results show that polygonal ferrite,granular bainite and larger amount of stabilized retained anstenite can be obtained by controlled rolling processes.The finer ferrite grain size is produced through the deformation induced transformation during deformation rather than after deformation,which affects the mechanical properties of hot rolled TRIP steel.Mechanical properties increase with decreasing finish rolling temperature due to the stabilization of retained austenite.Ultimate tensile strength(UTS),total elongation(TEL)and the product of ultimate tensile strength and total elongation(UTS×TEL)reaches optimal values(791 MPa,36% and 28 476 MPa%,respectively)whenthe specimen was hot rolled for 50% reduction at finish rolling temperature of 700℃.

  2. Influence of carbon nanofiber properties as electrocatalyst support on the electrochemical performance for PEM fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Sebastian, D.; Suelves, I.; Moliner, R.; Lazaro, M.J. [Instituto de Carboquimica (CSIC), Energy and Environment, C/Miguel Luesma Castan 4, 50018 Zaragoza (Spain); Calderon, J.C.; Gonzalez-Exposito, J.A.; Pastor, E. [Universidad de La Laguna, Dpto de Quimica-Fisica, Avda. Astrofisico Francisco Sanchez s/n, 38071 La Laguna, Tenerife (Spain); Martinez-Huerta, M.V. [Instituto de Catalisis y Petroleoquimica (CSIC), C/Marie Curie 2, 28049 Madrid (Spain)

    2010-09-15

    Novel carbonaceous supports for electrocatalysts are being investigated to improve the performance of polymer electrolyte fuel cells. Within several supports, carbon nanofibers blend two properties that rarely coexist in a material: a high mesoporosity and a high electrical conductivity, due to their particular structure. Carbon nanofibers have been obtained by catalytic decomposition of methane, optimizing growth conditions to obtain carbon supports with different properties. Subsequently, the surface chemistry has been modified by an oxidation treatment, in order to create oxygen surface groups of different nature that have been observed to be necessary to obtain a higher performance of the electrocatalyst. Platinum has then been supported on the as-prepared carbon nanofibers by different deposition methods and the obtained catalysts have been studied by different electrochemical techniques. The influence of carbon nanofibers properties and functionalization on the electrochemical behavior of the electrocatalysts has been studied and discussed, obtaining higher performances than commercial electrocatalysts with the highest electrical conductive carbon nanofibers as support. (author)

  3. Influence of calcium compounds on the mechanical properties of fly ash geopolymer pastes.

    Science.gov (United States)

    Temuujin, J; van Riessen, A; Williams, R

    2009-08-15

    The influence of calcium compounds (CaO and Ca(OH)(2)) on the mechanical properties of fly ash based geopolymers has been studied. Calcium compounds were substituted in fly ash at 1, 2 and 3 wt%, respectively. Curing of the geopolymers was performed at ambient temperature (20 degrees C) and 70 degrees C. Addition of calcium compounds as a fly ash substitute improved mechanical properties for the ambient temperature cured samples while decreasing properties for the 70 degrees C cured samples. Seven days compressive strength of the ambient temperature cured samples increased from 11.8 (2.9) to 22.8 (3.8)MPa and 29.2 (1.1)MPa for 3% CaO and 3% Ca(OH)(2) additions, respectively.

  4. The influence of tilt grain boundaries on the mechanical properties of bicrystalline graphene nanoribbons

    Science.gov (United States)

    Xu, Na; Guo, Jian-Gang; Cui, Zhen

    2016-10-01

    The mechanical properties of bicrystalline graphene nanoribbons with various tilt grain boundaries (GBs) which typically consist of repeating pentagon-heptagon ring defects are investigated based on the method of molecular structural mechanics. The GB models are constructed via the theory of disclinations in crystals, and the elastic properties and ultimate strength of bicrystalline graphene nanoribbons are calculated under uniaxial tensile loads in perpendicular and parallel directions to grain boundaries. The dependence of mechanical properties is analyzed on the chirality and misorientation angles of graphene nanoribbons, and the experimental phenomena that Young's modulus and ultimate strength of bicrystalline graphene nanoribbons can either increase or decrease with the grain boundary angles are further verified and discussed. In addition, the influence of GB on the size effects of graphene Young's modulus is also analyzed.

  5. 电渗与真空排水法降低填料含水率的比较研究%Comparative Research on Decreasing Water Content of Filler by Electro-Osmosis and Vacuum Dewatering

    Institute of Scientific and Technical Information of China (English)

    王甦达; 费维水; 唐正光; 吴培关

    2011-01-01

    Based on contrast experiments, this paper researches the efficiency of electro-osmosis and vacuum de-watering, two methods for water content decreasing of filler. Analysis of experiments indicates that the efficiency of dewatering by electro-osmosis is higher than that by vacuum dewatering in fine grained soil, and it's almost the same in coarse grained soil, but the electricity consumption by electro-osmosis is much less than that by vacuum dewatering. The conclusion given in this article may be helpful to choose proper scheme for decreasing water content.

  6. Ground-water conditions and effects of mine dewatering in Desert Valley, Humboldt and Pershing Counties, northwestern Nevada, 1962-91

    Science.gov (United States)

    Berger, D.L.

    1995-01-01

    Desert Valley is a 1,200-square-mile, north- trending, structural basin, about 30 miles northwest of Winnemucca, Nevada. Unconsolidated basin-fill deposits exceeding 7,000 feet in thickness constitute the primary ground-water reservoir. Dewatering operations at an open-pit mine began in the Spring of 1985 in the northeast part of Desert Valley. Ground-water withdrawal for mine dewatering in 1991 was greater than three times the estimated average annual recharge from precipitation. The mine discharge water has been allowed to flow to areas west of the mine where it has created an artificial wetlands. This report documents the 1991 hydrologic conditions in Desert Valley and the change in conditions since predevelopment (pre-1962). It also summarizes the results of analyzing the simulated effects of open-pit mine dewatering on a basin-wide scale over time. Water-level declines associated with the dewatering have propagated north and south of the mine, but have been attenuated to the west due to the infiltration beneath the artificial wetlands. Maximum water-level declines beneath the open pits at the mine, as of Spring 1991, are about 300 feet. Changes in the hydrologic conditions since predevelopment are observed predominantly near the dewatering operations and the associated discharge lakes. General ground-water chemistry is essentially unchanged since pre- development. On the basis of a ground-water flow model used to simulate mine dewatering, a new equilibrium may slowly be approached only after 100 years of recovery from the time mine dewatering ceases.

  7. Continuous melt granulation: Influence of process and formulation parameters upon granule and tablet properties.

    Science.gov (United States)

    Monteyne, Tinne; Vancoillie, Jochem; Remon, Jean-Paul; Vervaet, Chris; De Beer, Thomas

    2016-10-01

    The pharmaceutical industry has a growing interest in alternative manufacturing models allowing automation and continuous production in order to improve process efficiency and reduce costs. Implementing a switch from batch to continuous processing requires fundamental process understanding and the implementation of quality-by-design (QbD) principles. The aim of this study was to examine the relationship between formulation-parameters (type binder, binder concentration, drug-binder miscibility), process-parameters (screw speed, powder feed rate and granulation temperature), granule properties (size, size distribution, shape, friability, true density, flowability) and tablet properties (tensile strength, friability, dissolution rate) of four different drug-binder formulations using Design of experiments (DOE). Two binders (polyethylene glycol (PEG) and Soluplus®) with a different solid state, semi-crystalline vs amorphous respectively, were combined with two model-drugs, metoprolol tartrate (MPT) and caffeine anhydrous (CAF), both having a contrasting miscibility with the binders. This research revealed that the granule properties of miscible drug-binder systems depended on the powder feed rate and barrel filling degree of the granulator whereas the granule properties of immiscible systems were mainly influenced by binder concentration. Using an amorphous binder, the tablet tensile strength depended on the granule size. In contrast, granule friability was more important for tablet quality using a brittle binder. However, this was not the case for caffeine-containing blends, since these phenomena were dominated by the enhanced compression properties of caffeine Form I, which was formed during granulation. Hence, it is important to gain knowledge about formulation behavior during processing since this influences the effect of process parameters onto the granule and tablet properties.

  8. Research on vacuum membrane distillation technique disposing of high concentration inorganic salt reverse osmosis dense dewatering%减压膜蒸馏技术处理无机高盐 RO 浓排水研究

    Institute of Scientific and Technical Information of China (English)

    郭建中; 路全忠; 杨才伟

    2012-01-01

      针对无机高盐 RO 浓排水具有含盐量高难处理的特点,本文研究了减压膜蒸馏技术处理无机高盐RO 浓排水试验阶段中不同料液温度、真空度、流速对膜通量的影响.结果表明:料液温度、真空度、流速与膜通量存在相关性.随着料液温度和真空度的提高,膜通量会相应增加;随着料液流速的增加膜通量也有增加,但流速小于0.2 m/s 时对膜通量的影响明显,当流速大于0.2m/s 时对膜通量影响小%  Aimed at the characteristic of high salinity and difficult dispose of high concentration inorganic salt reverse osmosis dewatering, this paper studies the vacuum membrane distillation technique dispose of high concentration inorganic salt reverse osmosis dewatering, and analyse the influence of different vacuum, material fluid temperature, flow velocity to membrane flux. The result shows that there is a correlation between membrane flux and vacuum, material fluid temperature and flow velocity. With increasing of vacuum and material fluid temperature, membrane flux increased accordingly; and when the velocity increased and membrane flux increased at the same time. With the velocity was less than 0.2 m/s, the influence to membrane flux came to be obvious, when the velocity was above 0.2 m/s, the influence to membrane flux went light.

  9. Investigating the influence of infill percentage on the mechanical properties of fused deposition modelled ABS parts

    Directory of Open Access Journals (Sweden)

    Kenny Álvarez

    2016-09-01

    Full Text Available 3D printing is a manufacturing process that is usually used for modeling and prototyping. One of the most popular printing techniques is fused deposition modeling (FDM, which is based on adding melted material layer by layer. Although FDM has several advantages with respect to other manufacturing materials, there are several problems that have to be faced. When setting the printing options, several parameters have to be taken into account, such as temperature, speed, infill percentage, etc. Selecting these parameters is often a great challenge for the user, and is generally solved by experience without considering the influence of variations in the parameters on the mechanical properties of the printed parts.This article analyzes the influence of the infill percentage on the mechanical properties of ABS (Acrylonitrile Butadiene Styrene printed parts. In order to characterize this influence, test specimens for tensile strength and Charpy tests were printed with a Makerbot Replicator 2X printer, in which the infill percentage was varied but the rest of the printing parameters were kept constant. Three different results were analyzed for these tests: tensile strength, impact resistance, and effective printing time. Results showed that the maximum tensile force (1438N and tensile stress (34,57MPa were obtained by using 100% infill. The maximum impact resistance, 1,55J, was also obtained with 100% infill. In terms of effective printing time, results showed that printing with an infill range between 50% and 98% is not recommended, since the effective printing time is higher than with a 100% infill and the tensile strength and impact resistance are smaller. In addition, in comparing the results of our analysis with results from other authors, it can be concluded that the printer type and plastic roll significantly influence the mechanical properties of ABS parts.

  10. Stressful Presentations: Mild Chronic Cold Stress in Mice Influences Baseline Properties of Dendritic Cells

    Directory of Open Access Journals (Sweden)

    Kathleen Marie Kokolus

    2014-02-01

    Full Text Available The ability of dendritic cells to stimulate and regulate T cells is critical to effective anti-tumor immunity. Therefore, it is important to fully recognize any inherent factors which may influence DC function under experimental conditions, especially in laboratory mice since they are used so heavily to study immune responses. Physiological stress is well recognized to impair several arms of immune protection. The goals of this report are to briefly summarize previous work revealing how DCs respond to various forms of physiologically relevant stress and to present new data highlighting the potential for chronic mild cold stress inherent in mice housed at standard ambient temperatures required for laboratory mice to influence baseline DCs properties. Since recent data from our group shows that CD8+ T cell function is altered by mild chronic cold stress and since DC function is crucial for CD8+ T cell activation, we wondered whether mild cold stress may also be influencing DC properties. We found increased numbers of splenic DCs (CD11c+ in cold stressed mice compared to mice housed at a thermoneutral temperature, which significantly reduces cold stress. However, many of the DCs which are expanded in cold stressed mice express an immature phenotype. We also found that antigen presentation and ability of splenocytes to activate T cells were impaired compared to that seen in DCs isolated from mice at thermoneutrality. The new data presented here strongly suggest that the housing temperature of mice can affect fundamental properties of DC function which in turn could be influencing the response of DCs to added experimental stressors or other treatments.

  11. Influence of ceramic thickness and type on micromechanical properties of light-cured adhesive bonding agents.

    Science.gov (United States)

    Öztürk, Elif; Bolay, Sükran; Hickel, Reinhard; Ilie, Nicoleta

    2014-10-01

    The aim of this study was to evaluate the micromechanical properties of different adhesive bonding agents when polymerized through ceramics. Sixty sound extracted human third molars were selected and the crowns were sectioned perpendicular to the long axis in order to obtain dentin slices to be bonded with one of the following adhesives: Syntac/Heliobond (Ivoclar-Vivadent) or Adper-Scotchbond-1XT (3M-ESPE). The adhesives were cured by using a LED-unit (Bluephase®, Ivoclar Vivadent) with three different curing times (10 s, 20 s and 30 s) under two ceramics (IPS-e.max-Press, Ivoclar-Vivadent; IPS-Empress®CAD, Ivoclar-Vivadent) of different thicknesses (0 mm, 0.75 mm, 2 mm). Thirty groups were included, each containing 60 measurements. Micromechanical properties (Hardness, HV; indentation modulus, E; and creep, Cr) of the adhesives were measured with an automatic microhardness indenter (Fisherscope H100C, Germany). Data were statistically analyzed by using one-way ANOVA and Tukey's post-hoc test, as well as a multivariate analysis to test the influence of the study parameters (SPSS 18.0). Significant differences were observed between the micromechanical properties of the adhesives (p ceramic type showed the highest effect on HV (Partial-eta squared (η(2)) = 0.109) of the tested adhesives, while E (η(2) = 0.275) and Cr (η(2) = 0.194) were stronger influenced by the adhesive type. Ceramic thickness showed no effect on the E and Cr of the adhesives. The adhesive bonding agents used in this study performed well by curing through different thicknesses of ceramics. The micromechanical properties of the adhesives were determined by the adhesive type and were less influenced by ceramic type and curing time.

  12. Influence of Halide Solutions on Collagen Networks: Measurements of Physical Properties by Atomic Force Microscopy

    Science.gov (United States)

    Kempe, André; Lackner, Maximilian

    2016-01-01

    The influence of aqueous halide solutions on collagen coatings was tested. The effects on resistance against indentation/penetration on adhesion forces were measured by atomic force microscopy (AFM) and the change of Young's modulus of the coating was derived. Comparative measurements over time were conducted with halide solutions of various concentrations. Physical properties of the mesh-like coating generally showed large variability. Starting with a compact set of physical properties, data disperse after minutes. A trend of increase in elasticity and permeability was found for all halide solutions. These changes were largest in NaI, displaying a logical trend with ion size. However a correlation with concentration was not measured. Adhesion properties were found to be independent of mechanical properties. The paper also presents practical experience for AFM measurements of soft tissue under liquids, particularly related to data evaluation. The weakening in physical strength found after exposure to halide solutions may be interpreted as widening of the network structure or change in the chemical properties in part of the collagen fibres (swelling). In order to design customized surface coatings at optimized conditions also for medical applications, halide solutions might be used as agents with little impact on the safety of patients.

  13. Using 137 Cs measurements to investigate the influence of erosion and soil redistribution on soil properties.

    Science.gov (United States)

    Du, P; Walling, D E

    2011-05-01

    Information on the interaction between soil erosion and soil properties is an important requirement for sustainable management of the soil resource. The relationship between soil properties and the soil redistribution rate, reflecting both erosion and deposition, is an important indicator of this interaction. This relationship is difficult to investigate using traditional approaches to documenting soil redistribution rates involving erosion plots and predictive models. However, the use of the fallout radionuclide (137)Cs to document medium-term soil redistribution rates offers a means of overcoming many of the limitations associated with traditional approaches. The study reported sought to demonstrate the potential for using (137)Cs measurements to assess the influence of soil erosion and redistribution on soil properties (particle size composition, total C, macronutrients N, P, K and Mg, micronutrients Mn, Mo, Fe, Cu and Zn and other elements, including Ti and As). (137)Cs measurements undertaken on 52 soil cores collected within a 7 ha cultivated field located near Colebrooke in Devon, UK were used to establish the magnitude and spatial pattern of medium-term soil redistribution rates within the field. The soil redistribution rates documented for the individual sampling points within the field ranged from an erosion rate of -12.9 t ha(-1) yr(-1) to a deposition rate of 19.2 t ha(-1) yr(-1). Composite samples of surface soil (0-5 cm) were collected immediately adjacent to each coring point and these samples were analysed for a range of soil properties. Individual soil properties associated with these samples showed significant variability, with CV values generally lying in the range 10-30%. The relationships between the surface soil properties and the soil redistribution rate were analysed. This analysis demonstrated statistically significant relationships between some soil properties (total phosphorus, % clay, Ti and As) and the soil redistribution rate, but for

  14. Influence of color on dielectric properties of marinated poultry breast meat.

    Science.gov (United States)

    Samuel, D; Trabelsi, S

    2012-08-01

    The dielectric behavior of foods when exposed to radio-frequency and microwave electric fields is highly influenced by moisture content and the degree of water binding with constituents of the food materials. The ability to correlate specific food quality characteristics with the dielectric properties can lead to the development of rapid, nondestructive techniques for such quality measurements. Water-holding capacity is a critical attribute in meat quality. Up to 50% of raw poultry meat in the United States is marinated with mixtures of water, salts, and phosphates. The objective of this study was to determine if variations in breast meat color would affect the dielectric properties of marinated poultry meat over a broad frequency range from 500 MHz to 50 GHz. Poultry meat was obtained from a local commercial plant in Georgia (USA). Color and pH measurements were taken on the breast filets. Groups of breast filets were sorted into classes of pale and normal before adding marination pickup percentages of 0, 5, 10, and 15. Breast filets were vacuum-tumbled and weighed for pickup percentages. Dielectric properties of the filets were measured with a coaxial open-ended probe on samples equilibrated to 25°C. Samples from pale meat exhibited higher dielectric properties than samples from normal meat. No differences could be observed between samples from pale and normal meat after marination of the samples. Overall, dielectric properties increased as the marination pickup increased (α=0.05). Marination pickup strongly influenced the dielectric loss factor. Differences between samples marinated at different pickup levels were more pronounced at lower frequencies for the dielectric loss factor. As frequency increased, the differences between samples decreased. Differences in dielectric constant between samples were not as consistent as those seen with the dielectric loss factor.

  15. Influence of internal temperature development during manufacturing on thick laminates compression fatigue properties

    Science.gov (United States)

    Lahuerta, F.; Nijssen, RPL

    2016-07-01

    Thick laminates (above 6 mm) are increasingly present in large composite structures such as wind turbine blades. Blade designs are based on static and fatigue coupon tests on 14mm thick laminates. However, a thickness effect has been observed, showing significantly shorter fatigue life in thick laminates. Different factors are suspected to be involved in the decreased static and dynamic performance of thick laminates. These include the effect of selfheating during fatigue testing, scaling effects, and the influence of residual stresses due to temperature gradients during manufacturing. This work studies the influence of the temperature gradients during resin infusion on the through-thickness fatigue properties in thick laminates. Coupons from thick laminates cured at different curing rates have been tested in fatigue. The work reports the compression fatigue properties of a thick laminate and relates the results with the curing rate. Safety factors between 1.23 and 1.60 regarding the influence of the curing cycles in thick laminates are reported.

  16. Research on various factors influencing the moisture absorption property of sodium polyacrylate

    Institute of Scientific and Technical Information of China (English)

    ZHANG ChunXiao; ZHANG WanXi; PAN ZhenYuan; ZHANG XiYao; LIU Jian; YUE ChongWang

    2009-01-01

    Sodium polyacrylate was synthesized with acrylic acid as the monomer,and sodium bisulfate and ammonium persulfate as the initiator,by means of aqueous solution polymerization.The factors influencing the properties of moisture absorption,such as monomer concentration,dosage of initiator,and reaction temperature were systematically investigated.The experimental results indicate that the moisture-absorbing property of this polymer was better than other traditional material,such as silica gel,and molecular sieve.The best reaction condition and formula are based on the orthogonal experiment design.The optimum moisture absorbency of sodium polyacrylate reaches 1.01 g/g.The mathematical correlation of this polymer with various factors and moisture absorbency is obtained based on the multiple regression analysis.The moisture content intuitive analysis table shows that neutralization degree has the most significant influence on moisture absorbency,followed by monomer concentration and reaction temperature,while other factors have less influence.

  17. Influences of interphase on dynamic effective properties of composites reinforced by dispersed spherical particles

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    The influences of interphase on dynamic effective properties of composites reinforced by randomly dispersed spherical particles were studied. A thin homogeneous elastic interphase with different shear and bulk moduli, located between the reinforced particle and the host matrix, was introduced to model the interfacial bonding state. The effects of such an interphase on the coherent plane waves were studied numerically. Numerical simulations were carried out for SiC-Al composites with four typical cases of interphase. It was found that the property of interphase has significant influences on the effective propagation constants of coherent waves and the dynamic effective elastic moduli of the composites. The influences on the coherent longitudinal wave and the coherent shear waves were different and dependent upon the frequency range. Moreover, several imperfect interface models, i.e., the spring model, mass model, and spring-mass model, were studied numerically and compared with the interphase model. It was found that the spring model is a more suitable model than the mass model for the light and weak interphase whereas the mass model is a more suitable model than the spring model for the heavy and strong interphase.

  18. Short term preservation of hide using vacuum: influence on properties of hide and of processed leather.

    Science.gov (United States)

    Gudro, Ilze; Valeika, Virgilijus; Sirvaitytė, Justa

    2014-01-01

    The objective of this work was to investigate vacuum influence on hide preservation time and how it affects hide structure. It was established that vacuum prolongs the storage time without hide tissue putrefaction up to 21 days when the storage temperature is 4°C. The microorganisms act for all storage times, but the action is weak and has no observable influence on the quality of hide during the time period mentioned. The hide shrinkage temperature decrease is negligible, which shows that breaking of intermolecular bonds does not occur. Optical microscopy, infrared spectroscopy and differential scanning calorimetry also did not show any structural changes which can influence the quality of leather produced from such hide. The qualitative indexes of wet blue processed under laboratory conditions and of leather produced during industrial trials are presented. Indexes such as chromium compounds exhaustion, content of chromium in leather, content of soluble matter in dichloromethane, strength properties, and shrinkage temperature were determined. Properties of the leather produced from vacuumed hide under industrial conditions conformed to the requirements of shoe upper leather.

  19. Copper dynamics under alternating redox conditions is influenced by soil properties and contamination source.

    Science.gov (United States)

    Balint, Ramona; Said-Pullicino, Daniel; Ajmone-Marsan, Franco

    2015-02-01

    Understanding the effect of soil redox conditions on contaminant dynamics is of significant importance for evaluating their lability, mobility and potential transfer to other environmental compartments. Under changing redox conditions, soil properties and constituents such as Fe and Mn (hydr)oxides and organic matter (OM) may influence the behavior of associated metallic elements (MEs). In this work, the redox-driven release and redistribution of Cu between different soil pools was studied in three soils having different contamination sources. This was achieved by subjecting soil columns to a series of alternating reducing and oxidizing cycles under non-limiting C conditions, and assessing their influence on soil pore water, leachate and solid phase composition. Results showed that, in all soils, alternating redox conditions led to an increase in the distribution of Cu in the more labile fractions, consequently enhancing its susceptibility to loss. This was generally linked to the redox-driven cycling of Fe, Mn and dissolved organic matter (DOM). In fact, results suggested that the reductive dissolution of Fe and Mn (hydr)oxides and subsequent reprecipitation as poorly-ordered phases under oxic conditions contributed to the release and mobilization of Cu and/or Cu-containing organometallic complexes. However, the behavior of Cu, as well as the mechanisms controlling Cu release and loss with redox cycling, was influenced by both soil properties (e.g. pH, contents of easily reducible Fe and Mn (hydr)oxides) and source of Cu contamination.

  20. Influence of spray drying operating conditions on microencapsulated rosemary essential oil properties

    Directory of Open Access Journals (Sweden)

    Regiane Victória de Barros Fernandes

    2013-02-01

    Full Text Available Spray drying is an important method used by the food industry in the production of microencapsulated flavors to improve handling and dispersion properties. The objective of this study was to evaluate the influence of the process conditions on the properties of rosemary essential oil microencapsulated by spray drying using gum Arabic as encapsulant. The effects of the wall material concentration (10-30%, inlet air temperature (135-195 ºC, and feed flow rate (0.5-1.0 L.h-1 on the moisture content, hygroscopicity, wettability, solubility, bulk and tapped densities, particle density, flowability, and cohesiveness were evaluated using a 2³ central composite rotational experimental design. Moisture content, hygroscopicity and wettability were significantly affected by the three factors analyzed. Bulk density was positively influenced by the wall material concentration and negatively by the inlet air temperature. Particle density was influenced by the wall material concentration and the inlet air temperature variables, both in a negative manner. As for the solubility, tapped density, flowability, and cohesiveness, the models did not fit the data well. The results indicated that moderate wall material concentration (24%, low inlet air temperature (135 ºC, and moderate feed flow rate (0.7 L.h-1 are the best spray drying conditions.

  1. Influences of the steam sterilization on the properties of calcium phosphate porous bioceramics.

    Science.gov (United States)

    Li, Xiangfeng; Guo, Bo; Xiao, Yumei; Yuan, Tun; Fan, Yujiang; Zhang, Xingdong

    2016-01-01

    The influences of steam sterilization on the physicochemical properties of calcium phosphate (Ca-P) porous bioceramics, including β-tricalcium phosphate (β-TCP), biphasic calcium phosphate (BCP) and hydroxyapatite (HA) are investigated. After being steam sterilized in an autoclave (121 °C for 40 min), the porous bioceramics are dried and characterized. The steam sterilization has no obvious effects on the phase composition, thermal stability, pH value and dissolubility of β-TCP porous bioceramic, but changes its morphology and mechanical strength. Meanwhile, the steam sterilization leads to the significant changes of the morphology, phase composition, pH value and dissolubility of BCP porous bioceramic. The increase of dissolubility and mechanical strength, the decrease of pH value of the immersed solution and partial oriented growth of crystals are also observed in HA porous bioceramic after steam sterilization. These results indicate that the steam sterilization can result in different influences on the physicochemical properties of β-TCP, BCP and HA porous bioceramics, thus the application of the steam sterilization on the three kinds of Ca-P porous bioceramics should be considered carefully based on the above changed properties.

  2. Influence of physicochemical properties of rice flour on oil uptake of tempura frying batter.

    Science.gov (United States)

    Nakamura, Sumiko; Ohtsubo, Ken'ichi

    2010-01-01

    The physicochemical properties of rice flour and wheat flour influenced the oil uptake of tempura frying batter. Rice flour was better than wheat flour in the overall quality and crispness of the fried tempura batter. Rice flour resisted oil absorption more than wheat flour, and a higher level of apparent starch amylose and higher consistency/breakdown ratio of the pasting properties led to a lower oil uptake of the batter. Super hard EM10 rice showed the highest apparent amylose content and higher consistency/breakdown ratio than the other flour samples, the batter from EM10 revealing the lowest oil content after frying among all the batters examined. The apparent amylose content, consistency/breakdown ratio and oil absorption index are proposed as useful guides for oil absorption when frying from among the physicochemical properties that influence the oil content of fried batter. Our proposal for the "oil absorption index" could be a simple, although not perfect method for estimating the oil content of batter flour.

  3. THE INFLUENCE OF THE NUMBER OF RIPPLE OF POLYACRYLONITRILIC FIBERS COTTON TYPE ON YARN PROPERTIES

    Directory of Open Access Journals (Sweden)

    HRISTIAN Liliana

    2016-05-01

    Full Text Available In this study we aimed the influence of the number of undulations of polyacrylonitrile fibers, cotton type, on the properties of yarns with Nm50/1 fineness, made on BD 200 the rotor spinning machine. Rotor spinning of the synthetic fibers is largely influenced by some characteristics of the fibers as being: the quality and quantity of the avivage, frequency of undulations and the number of defects fiber. Tensile properties and structural characteristics aspect of the yarns carried on BD 200 rotor spinning machine are determined, at the fiber content, the structural model and the technological parameters of processing, by the result of the transfer of fibers proprieties, into the meaning fiber-yarn. The yarns structural compactness, determined by the degree of twisting and tensional properties are defining for the quality of yarns and warrants the corresponding to their destination. Structural characteristics of the yarns which are characterized by complexity and diversity of their actions were studied by determining the linear irregularity (U% , standard deviation (CV% and the imperfections in the form of thinning (S, thickening (G, neppines (N, relative to 1000 m yarn.

  4. The influence of microwave curing time and water glass kind on the properties of molding sands

    Directory of Open Access Journals (Sweden)

    K. Granat

    2007-12-01

    Full Text Available This work presents results of research on the influence of microwave heating time on the process of hardening of water glass molding sands. Essential influence of this drying process on basic properties such as: compression, bending and tensile strength as well as permeability and wear resistance, has been found. It has been proved, that all the investigated sorts of sodium water glass could be used as binding material of molding sands intended for curing with the microwave process heating. It has been found, while analyzing the results of property studies of microwave heated molding sands with 2.5% addition of water glass, that all available on the market kinds of this binding agent (including the most frequently used in foundry 145 and 149 kinds after microwave heating guarantee very good compression, bending and tensile strength as well as permeability and wear resistance. Moreover, it has been determined that the optimal curing time of molding sands containing various kinds of water glass is 240 seconds. After this time, all basic properties of molding sands are stable. The use of microwave curing of water glass molding sands results in a significant decrease of hardening process time, full stabilization of molding sands as well as much lower energy consumption.

  5. The Influence of Textile Materials Mechanical Properties upon Virtual Garment Fit

    Directory of Open Access Journals (Sweden)

    Kristina ANCUTIENĖ

    2011-07-01

    Full Text Available 3D virtual representation of garment provides high potential for design, product development and marketing processes, especially in mass customization strategies implementation. Clothing industry rapidly turns to virtual simulation which not only presents realistic 3D view of garment but also simulates mechanical behaviour of materials. 3D CAD systems can be used to define strain distribution in virtual garment which describes garment fit without actually producing the garment. Strain and distance ease between body and garment depends not only upon body measurements and garment construction, but also on mechanical and structural properties of selected material. The aim of this research was to investigate virtual garment fit using "Modaris 3D Fit" (Lectra software subjected to fabrics mechanical (tensile, bending, shear and structural (composition, thickness, area density properties investigating strain distribution in garment and distance ease between garment and human body. It was defined that for diagonal cut garments the highest influence upon garment fit has fabric tensile properties in weft direction. The highest influence is obtained at high distance ease and small strain values zones and at negative distance ease and high strain values zones. Therefore, presented method could be used for tight-fitted garments also for garments with draperies on purpose to investigate garment fit upon fabrics used.http://dx.doi.org/10.5755/j01.ms.17.2.486

  6. Hydrothermal carbonization of biomass from landscape management - Influence of process parameters on soil properties of hydrochars.

    Science.gov (United States)

    Röhrdanz, Michael; Rebling, Tammo; Ohlert, Jan; Jasper, Jan; Greve, Thomas; Buchwald, Rainer; von Frieling, Petra; Wark, Michael

    2016-05-15

    Besides pyrolysis the technology of hydrothermal carbonization (HTC) is tested to produce hydrochars for soil improvement. The chemical and physical properties of the hydrochars mainly depend on the feedstock and the process parameters reaction time and process temperature. Systematic investigations on the influences of these process parameters on soil properties of hydrochars like water holding capacity (WHC) and cation exchange capacity (CEC) are missing. In this study, a rush-rich biomass was carbonized within defined HTC process conditions under variation of reaction time and process temperature to produce hydrochars. Analysis of WHC, CEC, the elemental composition and Fourier-transform infrared spectroscopy (FT-IR) were performed to evaluate the influence of HTC process conditions on the pedological hydrochar properties. The results indicated that at increasing reaction severity (reaction time and process temperature) WHC and CEC decreased as well as the elemental O/C ratio. The decrease of WHC and CEC is based on the decrease of the hydrochar surface polarity. However, even the lowest WHC and CEC of investigated hydrochars still exceeded those of pure quartz sand by factors of 5-10. An application of hydrochars produced at severe HTC conditions could improve WHC and CEC of sandy soils. This has to be investigated in further studies.

  7. Influence of Amino-Ffunctional Macro and Micro Silicone Softeners on the Properties of Cotton Fabric

    Directory of Open Access Journals (Sweden)

    Abdul Wahab Jatoi

    2015-01-01

    Full Text Available Amino-functional silicone softeners are most widely used type of soft finishes owing to their outstanding permanent softness, smoothness and handle characteristics. These soft finishes are prepared in different emulsion droplet sizes such as macro and micro emulsions providing varying characteristics on the textile on which they are applied. The macroemulsions due to their larger droplet sizes lubricate fabric and yarn surfaces, while the micro-emulsion, thanks to their smaller sizes penetrate inside fiber pores. In this research amino-functional macro and micro emulsions have been applied on dyed cotton fabric in 1:1 combination and compared against their influence on physical properties such as bending length, abrasion resistance, tensile strength, crease resistance and water repellency. These emulsions have also been compared for their influence on colorimetric properties; color difference and color strength (K/S values. The results reveal that the softener`s application in combination improves the properties deteriorated by each softener when applied separately

  8. Influence of Morphology on Electrical Properties of Syndiotactic Polypropylene Compared with Those of Isotactic Polypropylene

    Science.gov (United States)

    Kim, Dong; Yoshino, Katsumi; Inoue, Takeo; Abe, Masaru; Uchikawa, Nobutaka

    1999-06-01

    The influence of morphology on the electrical properties of syndiotactic polypropylene (sPP) has been investigated in comparison with those of conventional isotactic polypropylene (iPP). The evolution of spherulite in sPP occurred at a lower temperature than in iPP, and the size of spherulites in sPP is much smaller than those of iPP, though the number of spherulites increases drastically. The influence of heat treatment on the electrical properties of sPP, such as conductivity and current density-electric field characteristics, is negligible in contrast to iPP, in which the conductivity increased drastically and breakdown strength decreased markedly due to growth of large spherulites upon heat treatment. These results are discussed in terms of morphological change upon heat treatment. As a result, sPP is confirmed to be an excellent candidate for a new insulating polymer for cables which can be used at a much higher operating temperature than that of widely used cables with cross-linked polyethylene (XLPE) (90°C), because of its thermal stability, stable electrical properties even following heating treatment and mechanical flexibility due to the small spherulite size and low crystallinity under any preparation and treatment conditions.

  9. Analysis of the Magnetic Field Influence on the Rheological Properties of Healthy Persons Blood

    Directory of Open Access Journals (Sweden)

    Anna Marcinkowska-Gapinska

    2013-01-01

    Full Text Available The influence of magnetic field on whole blood rheological properties remains a weakly known phenomenon. An in vitro analysis of the magnetic field influence on the rheological properties of healthy persons blood is presented in this work. The study was performed on blood samples taken from 25 healthy nonsmoking persons and included comparative analysis of the results of both the standard rotary method (flow curve measurement and the oscillatory method known also as the mechanical dynamic analysis, performed before and after exposition of blood samples to magnetic field. The principle of the oscillatory technique lies in determining the amplitude and phase of the oscillations of the studied sample subjected to action of a harmonic force of controlled amplitude and frequency. The flow curve measurement involved determining the shear rate dependence of blood viscosity. The viscoelastic properties of the blood samples were analyzed in terms of complex blood viscosity. All the measurements have been performed by means of the Contraves LS40 rheometer. The data obtained from the flow curve measurements complemented by hematocrit and plasma viscosity measurements have been analyzed using the rheological model of Quemada. No significant changes of the studied rheological parameters have been found.

  10. Analysis of the magnetic field influence on the rheological properties of healthy persons blood.

    Science.gov (United States)

    Marcinkowska-Gapinska, Anna; Nawrocka-Bogusz, Honorata

    2013-01-01

    The influence of magnetic field on whole blood rheological properties remains a weakly known phenomenon. An in vitro analysis of the magnetic field influence on the rheological properties of healthy persons blood is presented in this work. The study was performed on blood samples taken from 25 healthy nonsmoking persons and included comparative analysis of the results of both the standard rotary method (flow curve measurement) and the oscillatory method known also as the mechanical dynamic analysis, performed before and after exposition of blood samples to magnetic field. The principle of the oscillatory technique lies in determining the amplitude and phase of the oscillations of the studied sample subjected to action of a harmonic force of controlled amplitude and frequency. The flow curve measurement involved determining the shear rate dependence of blood viscosity. The viscoelastic properties of the blood samples were analyzed in terms of complex blood viscosity. All the measurements have been performed by means of the Contraves LS40 rheometer. The data obtained from the flow curve measurements complemented by hematocrit and plasma viscosity measurements have been analyzed using the rheological model of Quemada. No significant changes of the studied rheological parameters have been found.

  11. Influence of dopant distribution on the plasmonic properties of indium tin oxide nanocrystals.

    Science.gov (United States)

    Lounis, Sebastien D; Runnerstrom, Evan L; Bergerud, Amy; Nordlund, Dennis; Milliron, Delia J

    2014-05-14

    Doped metal oxide nanocrystals represent an exciting frontier for colloidal synthesis of plasmonic materials, displaying unique optoelectronic properties and showing promise for a variety of applications. However, fundamental questions about the nature of doping in these materials remain. In this article, the strong influence of radial dopant distribution on the optoelectronic properties of colloidal indium tin oxide nanocrystals is reported. Comparing elemental depth-profiling by X-ray photoelectron spectroscopy (XPS) with detailed modeling and simulation of the optical extinction of these nanocrystals using the Drude model for free electrons, a correlation between surface segregation of tin ions and the average activation of dopants is observed. A strong influence of surface segregation of tin on the line shape of the localized surface plasmon resonance (LSPR) is also reported. Samples with tin segregated near the surface show a symmetric line shape that suggests weak or no damping of the plasmon by ionized impurities. It is suggested that segregation of tin near the surface facilitates compensation of the dopant ions by electronic defects and oxygen interstitials, thus reducing activation. A core-shell model is proposed to explain the observed differences in line shape. These results demonstrate the nuanced role of dopant distribution in determining the optoelectronic properties of semiconductor nanocrystals and suggest that more detailed study of the distribution and structure of defects in plasmonic colloidal nanocrystals is warranted.

  12. Influence of some crosslinking agents on thermal and mechanical properties of electron beam irradiated polylactide

    Energy Technology Data Exchange (ETDEWEB)

    Rytlewski, Piotr, E-mail: prytlewski@ukw.edu.p [Department of Materials Engineering, Kazimierz Wielki University, ul. Chodkiewicza 30, 85-064 Bydgoszcz (Poland); Malinowski, RafaL [Institute for Engineering of Polymer Materials and Dyes, ul. M. SkLodowskiej-Curie 55, 87-100 Torun (Poland); Moraczewski, Krzysztof [Department of Materials Engineering, Kazimierz Wielki University, ul. Chodkiewicza 30, 85-064 Bydgoszcz (Poland); Zenkiewicz, Marian [Institute for Engineering of Polymer Materials and Dyes, ul. M. SkLodowskiej-Curie 55, 87-100 Torun (Poland)

    2010-10-15

    The aim of this article was to determine and compare the influence of trimethylopropane trimethacylate (TMPTA) and trially isocyanurate (TAIC) crosslinking agents on thermal and mechanical properties of electron beam irradiated polylactide (PLA). The blends were made of PLA mixed with 3 wt% of TMPTA (PLA/TMPTA), and PLA mixed with 3 wt% of TAIC (PLA/TAIC). Injection moulded samples were irradiated with the use of high energy (10 MeV) electron beam at various radiation doses to crosslinking PLA macromolecules. Thermal and mechanical properties were investigated by means of differential scanning calorimetry (DSC), dynamic mechanical analysis (DMA), tensile strength, and impact strength measurements. The samples were also characterized by Fourier transform infrared spectroscopy (FTIR). It was found that under the influence of electron irradiation PLA/TMPTA samples underwent degradation while PLA/TAIC samples became crosslinked. Tensile and impact strengths of PLA/TMPTA samples decreased with increasing radiation dose while an enhancement of these properties for PLA/TAIC samples was observed.

  13. Feasibility of vermicomposting dewatered sludge from paper mills using Perionyx excavatus

    Directory of Open Access Journals (Sweden)

    Puspanjali Sonowal

    2013-06-01

    Full Text Available India has a large network of pulp and paper mills of varying capacity. On an industrial scale the sludge from paper and pulp mills is disposed of either as landfill or incinerated. Both methods result in the loss of a valuable resource and have obvious environmental and economic disadvantages. The solid waste from pulp and paper mills is a source of organic matter and its proper disposal and management is the responsibility of the industry. As composting/vermicomposting could be used to transform this waste trials were carried out to determine the feasibility of converting dewatered sludge (DS into a value added end product using an earthworm, Perionyx excavatus. The vermicomposting of the waste resulted in an increase in its electrical conductivity (EC, ash content, total nitrogen (TN, total phosphorous (TP and available phosphorous (AP, respectively, and a decrease in total organic carbon (TOC, biochemical oxygen demand (BOD, chemical oxygen demand (COD, oxygen uptake rate (OUR and evolution of carbon dioxide (CO2. Overall, the best treatment was T5 in which there was a 76.1% increase in TP, 58.7% in TN, 74.5% decrease in TOC , and a reduction of 6.7 fold in the production of CO2 and 10.7 fold in BOD, respectively. Our trials demonstrate that vermicomposting using an epigeic earthworm, Perionyx excavatus, is an alternate and environmentally safe way of recycling paper mill sludge if it is mixed with an appropriate amount of cow dung and food processing waste. Overall T5 was the best combination of paper mill sludge and waste for vermicomposting followed by T3, T2, T4 and T1, respectively.

  14. Coontail fluorite rhythmites of southern Illinois: evidence for episodic basin dewatering

    Energy Technology Data Exchange (ETDEWEB)

    Cowan, C.A.; Kelly, W.C.; Wilkinson, B.H.

    1985-01-01

    Stratiform coontail ore of the Cave-in-Rock fluorite district, southern Illinois, display conspicuous, rhythmic banded textures similar to those reported in many MVT deposits throughout the world (e.g., east Tennessee, USA; Silesian-Cracow Region, Poland; and northern Baffin Island, Canada). Banding is expressed by the rhythmic alteration of two types of layers: detrital layers of fluorite mottled with particulate gangue dolomite and quartz, and layers of clear, crystalline fluorspar. Both are now composed principally of fluorite but differ in color, fabric and outline. In the past, this rhythmic banding has generally been attributed to fine-scale replacement of a primary host rock stratification or to cyclic replacement of host carbonates by a fluid of oscillating chemistry. Detailed megascopic and microscopic studies of these ores and their carbonate host real that ore bands were not derived by fine-scale in situ limestone replacement. Detrital bands contain hydraulically transported, sorted and graded, allochthonous debris derived by dissolution and disaggregation of host limestone and overlying shale. The banded fabric thus represents a cyclic interplay of chemical and hydraulic processes active during hydrothermal ore mineralization. Coontail ore bodies evidently formed in a hydrothermal spelean system, whose laterally sinuous trace reflects localization of hydrothermal activity where feeder faults intersected relatively impermeable roof-rock shales. The banded nature of these ores testifies to the ability of Mississippi Valley-type hydrothermal solutions to both create and fill their own open spaces. Moreover, the rhythmic nature of coontail ores suggests a prolonged and pulsating mineralization best explained by episodic dewatering of the Illinois Basin.

  15. Irradiating of Bulk Soybeans: Influence on Their Functional and Sensory Properties for Soyfood Processing

    Science.gov (United States)

    Chia, Chiew-Ling; Wilson, Lester A.; Boylston, Terri; Perchonok, Michele; French, Stephen

    2006-01-01

    Soybeans were chosen for lunar and planetary missions, where soybeans will be supplied in bulk or grown locally, due to their nutritive value and ability to produce oil and protein for further food applications. However, soybeans must be processed into foods prior to consumption. Radiation that soybeans would be exposed to during bulk storage prior to and during a Mars mission may influence their germination and functional properties. The influence of radiation includes the affect of surface pasteurization to ensure the astronauts safety from food-borne illnesses (HACCP, CCP), and the affect of the amount of radiation the soybeans receive during a Mars mission. Decreases in the amount of natural antioxidants free radical formation, and oxidation-induced changes in the soybean will influence the nutritional value, texture, color, and aroma of soyfoods. The objective of this study was to determine the influence of pasteurization and sterilization surface radiation on whole soybeans using gamma and electron beam radiation. The influence of 0, 1, 5, 10, and 30kGy on microbial load, germination rate, ease of processing, and quality of soymilk and tofu were determined. Surface radiation of whole dry soybeans using electron beam or gamma rays from 1-30kGy did provide microbial safety for the astronauts. However, the lower dose levels had surviving yeasts and molds. These doses caused oxidative changes that resulted in soymilk and tofu with rancid aromas. GC-MS of the aroma compounds using SPME Headspace confirmed the presence of lipid oxidation compounds. Soybean germination ability was reduced as radiation dosage increased. While lower doses may reduce these problems, the ability to insure microbial safety of bulk soybeans will be lost. Counter measures could include vacuum packaging, nitrogen flushing, added antioxidants, and radiating under freezing conditions. Doses below 1kGy need to be investigated further to determine the influence of the radiation encountered

  16. Probabilistic assessment of the influence of lake properties in long-term radiation doses to humans.

    Science.gov (United States)

    Pohjola, Jari; Turunen, Jari; Lipping, Tarmo; Ikonen, Ari T K

    2016-11-01

    The assessment processes concerning the safety of nuclear waste repositories include the modelling of radionuclide transport in biosphere and the evaluation of the doses to the most affected humans. In this paper, a scenario, in which a contaminated lake is the water source for drinking water, irrigation water and watering of livestock, is presented. The objective of the paper is to probabilistically study the influence of lake properties as parameters in the assessment scenario. The properties of the lake are a result of previously conducted probabilistic studies, where the land uplift of the terrain surrounding the repositories and the formation of water bodies were studied in a 10,000-year time span using Monte Carlo simulation. The lake is formed at 3000 years from present day and the changing properties of the lake have been used in the study. The studied radionuclides (36)Cl, (135)Cs, (129)I, (237)Np, (90)Sr, (99)Tc and (238)U enter the lake with a rate of 1 Bq/year. The transport process from the lake water to humans is described and the doses (dose conversion factors) to adult humans are evaluated based on a study on average food consumption. Sensitivity analysis is used for identifying the parameters having the most influence on the outcome of the dose. Based on the results from the sensitivity analysis, the volumetric outflow rate of the lake and the volume of the lake were taken into closer consideration. The results show the influence of probabilistically derived geomorphic lake input parameters on the dose. Copyright © 2016 Elsevier Ltd. All rights reserved.

  17. Structural and dynamical properties of ionic liquids: the influence of ion size disparity.

    Science.gov (United States)

    Spohr, H V; Patey, G N

    2008-08-14

    The influence of ion size disparity on structural and dynamical properties of ionic liquids is systematically investigated employing molecular dynamics simulations. Ion size ratios are varied over a realistic range (from 1:1 to 5:1) while holding other important molecular and system parameters fixed. In this way we isolate and identify effects that stem from size disparity alone. In strongly size disparate systems the larger species (cations in our model) tend to dominate the structure; the anion-anion distribution is largely determined by anion-cation correlations. The diffusion coefficients of both species increase, and the shear viscosity decreases with increasing size disparity. The influence of size disparity is strongest up to a size ratio of 3:1, then decreases, and by 5:1 both the diffusion coefficients and viscosity appear to be approaching limiting values. The conventional Stokes-Einstein expression for diffusion coefficients holds reasonably well for the cations but fails for the smaller anions as size disparity increases likely due to the neglect of strong anion-cation correlations. The electrical conductivity is not a simple monotonic function of size disparity; it first increases up to size ratios of 2:1, remains nearly constant until 3:1, then decreases such that the conductivities of the 1:1 and 5:1 systems are similar. This behavior is traced to the competing influences of ion diffusion (enhancing) and ion densities (reducing) on conductivities at constant packing fraction. The temperature dependence of the transport properties is examined for the 1:1 and 3:1 systems. In accord with experiment, the temperature dependence of all transport properties is well represented by the Vogel-Fulcher-Tammann equation. The dependence of the diffusion coefficients on the temperature/viscosity ratio is well described by the fractional Stokes-Einstein relation D proportional to (T/eta)(beta) with beta approximately = 0.8, consistent with the exponent observed for

  18. [Does garlic influence rheologic properties and blood flow in progressive systemic sclerosis?].

    Science.gov (United States)

    Rapp, Alexander; Grohmann, Gerald; Oelzner, Peter; Uehleke, Bernhard; Uhlemann, Christine

    2006-06-01

    According to traditional European naturopathy garlic is an agent that increases perfusion. In studies with healthy subjects and in-vitro research garlic has shown influences on erythrocyte and thrombocyte aggregation as well as on vasoregulation. However, data on its effects in clinical populations are still lacking. Garlic may be useful for systemic sclerosis which is characterised by impaired perfusion that often cannot sufficiently be influenced by standard treatment. We investigated if dried garlic powder can influence rheologic properties and vasomotor function in systemic sclerosis. During a randomised, double blind pilot study, 20 female inpatients with systemic sclerosis received a 7 day add-on therapy with either 900 mg dried garlic powder or placebo. Rheologic properties (erythrocyte aggregation, ADP-induced thromboycyte aggregation, plasma viscosity, fibrinogenous plasma level, blood sedimentation rate) were assessed initially as well as after 1 and 7 days of treatment. Vasomotor function was evaluated using near-infrared red photoplethysmography, a new diagnostic tool to assess microcirculation. Furthermore, acral skin temperature was measured. After 7 days, only the verum treatment had induced a significant reduction of ADP-induced thrombocyte aggregation and a decrease in erythrocyte aggregation. Results showed no significant effects on vasomotor function, but an immediate effect of garlic on acral skin temperature. According to the 'Qualitatenlehre' of traditional European naturopathy, garlic is classified as a 'heating agent'. Our results suggest that the improvement of rheologic properties could be a possible biological correlate for this. Although further research is required, we conclude garlic could be a rational add-on therapy in the 'Kaltekrankheit' ('cold disease') of systemic sclerosis.

  19. Influence of grinding on service properties of VT-22 powder applied in additive technologies

    Science.gov (United States)

    Zakharov, M. N.; Rybalko, O. F.; Romanova, O. V.; Gelchinskiy, B. R.; Il’inykh, S. A.; Krashaninin, V. A.

    2017-01-01

    Powder of titanium alloy (VT-22) produced by plasma-spraying was subjected to grinding to obtain powder with size less 100 microns. These powders were sprayed by plasma unit using two types of gases, namely, air and air with methane (spraying in water and sputtering of coating on steel support). Influence of grinding time on yield of powder of required fraction was studied. Morphology and phase composition of the grinded powder and plasma sprayed one were under investigation. In the result of experiments, it appears that the grinding time genuinely influences the chemical and phase compositions, but there is no effect on physical-processing properties. For powders after plasma spraying some changes of non-metal elements content were detected by chemical analysis. Using gaseous mixture of air and methane in plasma spraying unit leads to formation of a new phase in the powder according X-ray diffraction data.

  20. Influence of Combined Hard and Fine Machining on the Surface Properties of Cemented Carbides

    Directory of Open Access Journals (Sweden)

    U. Engel

    2012-09-01

    Full Text Available As a result of recent developments in cold forging cemented carbides are increasingly used as tool materials. Due to their high hardness only electrical discharge machining (EDM and grinding are suitable for tool machining. The structure of tool surface has significant influence on dominating failure mechanisms wear and fatigue. For improvement of tribological conditions the surface is polished in a finale processing step. The result of hard and fine machining is a specific combination of coarse and fine structure which is determined by processing parameters. The different surface structures lead to a particular tool behavior in forming process. This paper aims to show the influence of combined hard and fine machining on the surface properties of cemented carbides.

  1. Influence of heat treatment on properties of ti-nb alloys

    Directory of Open Access Journals (Sweden)

    L. Kunčicka

    2014-04-01

    Full Text Available Ti-Nb alloys are of a large potential for industrial, as well as biomedical utilisation. Oxygen content in the alloy is a parameter influencing its properties and cannot be neglected. The main focus of this paper is on observation of influence of annealing time on oxygen content in the structure of Ti – 20,7 (at.% Nb alloy. Four groups of the samples were annealed at the temperature of 800 °C from 15 to 60 minutes with 15 min. step. As it was proven by the analysis, the oxygen content increased with increasing annealing time. Moreover, microhardness measurements showed increasing trend of HV microhardness value with increasing oxygen content.

  2. Influence of pore fluid and frequency on elastic properties of greensand as interpreted using NMR data

    DEFF Research Database (Denmark)

    Hossain, Zakir; Mukerj, Tapan; Fabricius, Ida Lykke

    2011-01-01

    The objective of this study was to discuss the influence of pore fluid on elastic properties of greensand. Gassmann’s equations generally work at low frequency and do not take into consideration the fluid related dispersion. In some cases Biot’s theory is used to describe the fluid related...... dispersion. However, Biot’s theory does not fully explain the frequency dispersion of sedimentary rocks. Greensands are composed of a mixture of quartz and micro-porous glauconite grains. In greensand, it is possible that the contrast between flow in macro-pores and micro-pores within glauconites gives rise...... to a local stiffening pressure gradient in the fluid. Then fluid flow in greensand could then be described as a kind of squirt flow. Greensand data from the North Nini filed was included in this study. Gassmann’s, Biot’s and squirt models were used to discuss the influence of pore fluid on elastic moduli...

  3. Influence of carbon nanoparticles on the properties of screen printed polymer composites

    Science.gov (United States)

    Jakubowska, Małgorzata; Janeczek, Kamil; MłoŻniak, Anna; Kozioł, GraŻyna; Araźna, Aneta

    2013-07-01

    Further development of printed electronics requires investigations of new polymer composites which can be coated on flexible substrates with printing techniques. These composites should exhibit low sheet resistance and high durability to thermal stresses. In this article, the properties of polymer composites prepared by mixing a commercial solution of poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) in aliphatic hydrocarbons with multi-wall carbon nanotubes or graphite platelet nanofibers were described. These composites were coated on flexible and low-cost substrates with screen printing techniques. The microstructure of fabricated layers were observed in a top and cross-sectional view and their thickness was measured with a contact profilometer. Their resistance was measured with a four-point-probe method depending on a printing multiplicity and after exposure the tested samples to the influence of temperature variation. Temperature distribution under influence of current flow in the produced layers was also examined.

  4. The influence of ventilated façade on sound insulation properties of envelope walls

    Directory of Open Access Journals (Sweden)

    Fišarová Zuzana

    2017-01-01

    Full Text Available Presented article deals with sound insulation properties of timber structures’ envelope walls. Particularly, the influence of heavy board ventilated façade on laboratory airborne sound insulation R and Rw in dB was studied. The installation method and gaps between façade boards can cause building defects originating in overrating the influence of ventilated cladding on envelope wall acoustic parameters. Real constructions were built for the experimental purposes and measurements, one with gaps between boards and one with simply eliminated gaps for mutual comparison. The results obtained were processed to make tables and graphs and to derive recommendations for the design of this type of constructions involving the general installation method of façade boards. Detailed results are depicted in conclusions.

  5. Influence of selective atomic measurement on the entanglement properties of a two-atom outside cavity

    Institute of Scientific and Technical Information of China (English)

    Lu Dao-Ming

    2011-01-01

    Considering three two-level atoms initially in the W or Greenberger-Horne-Zeilinger (GHZ) state, one of the three atoms is put into an initially coherent light cavity and made to resonantly interact with the cavity. The two-atom entanglement evolution outside the cavity is investigated. The influences of state-selective measurement of the atom inside the cavity and strength of the light field on the two-atom entanglement evolution outside the cavity are discussed. The results obtained from the numerical method show that the two-atom entanglement outside the cavity is strengthened through state-selective measurement of the atom inside the cavity. In addition, the strength of the light field also influences the two-atom entanglement properties.

  6. Influence of surface properties of mix-monolayers on lipolytic hydrolysis

    DEFF Research Database (Denmark)

    Peters, Günther H. J.; Dahmen, U.; Brezesinski, G.

    2000-01-01

    Fluorescence microscopy, surface potential, and activity measurements were used to investigate the influence of fatty acids and fatty alcohols on the lipolytic activity of several lipases. We have determined the lateral lipid distribution and interfacial properties of Langmuir mixed monolayers...... correlates with the isoelectric point (pI) of the enzymes. A simpler mechanism is observed by the addition of fatty alcohol. Within the concentration range studied, 1-octadecanol is immiscible in the diacylglyceride matrix, forming liquid-condensed domains. The inhibitory effect is related to the reduction...... composed of 1,2-didecanoylglycerol/eicosanoic acid or 1,2-didecanoylglycerol/1-octadecanol molecules and have measured lipase activities toward these films. Enzymatic activities are remarkably influenced by the addition of fatty acid. Activity decreases continuously up to a mole fraction of ≈ 0.1 fatty...

  7. Influence of boehmite nanoparticle loading on the mechanical, thermal, and rheological properties of biodegradable polylactide/ poly(e-caprolactone) blends

    CSIR Research Space (South Africa)

    Agwuncha, SC

    2015-01-01

    Full Text Available -1 Macromolecular Materials and Engineering Vol. 300(1), 31-47 Influence of Boehmite Nanoparticle Loading on the Mechanical, Thermal, and Rheological Properties of Biodegradable Polylactide/Poly(e-caprolactone) Blendsa Stephen C. Agwuncha, Suprakas Sinha...

  8. Laboratory assessment of the influence of the proportion of waste foundry sand on the geotechnical engineering properties of clayey soils

    CSIR Research Space (South Africa)

    Mgangira, Martin B

    2006-01-01

    Full Text Available Soil improvement can be achieved through mechanical stabilisation using industrial byproducts. Clayey soils were blended with waste foundry sand to examine its influence on the geotechnical engineering properties of the soils. The waste foundry sand...

  9. Influence of Sputtering Gas on Morphological and Optical Properties of Magnesium Films

    Institute of Scientific and Technical Information of China (English)

    Yogendra K. Gautam; Amit K. Chawla; Vipin Chawla; R.D. Agrawal; Ramesh Chandra

    2011-01-01

    The influence of sputtering gas (He & Ar) on the structural properties of Mg thin films has been investigated. The optical property (reflectance) that results from the growth of films at varying substrate temperatures (Tsub) was also studied. The deposited films were characterized by using X-ray diffraction (XRD), field emission scaning electron microscopy (FE-SEM), atomic force microscopy (AFM) and UV-Vis-NIR spectrophotometer. The smaller crystallite size and lower deposition rate were observed in the presence of Helium atmosphere compared to Argon. Morphology of the films shows 2D hexagonal geometry of grains in the deposition temperature range (Tsub≈50-150℃) in both the sputtering gases. The surface roughness of the polycrystalline films were found to increase with increase in the deposition temperature of both ambient gases. Optical reflectance of Mg films was measured in near infrared region and larger reflectance was observed from Mg films sputtered in He atmosphere compared to that in argon.

  10. Influence of the Lubricant Thermo-Piezo-Viscous Property on Hydrostatic Bearings in Oil Hydraulics

    DEFF Research Database (Denmark)

    Johansen, Per; Roemer, Daniel Beck; Andersen, Torben O.

    2016-01-01

    In fluid power machinery hydrostatic bearings are frequently used, and a first approximation approach to design is determination of a balance ratio by analytical calculations of the hydrostatic presure force. Usually this is performed assuming that the thermo-piezo-viscous property can be neglected....... However, in applications as piston machines, where pressure in many cases exceeds 200 Bar, such assumption leads to considerable error in the valance ratio prediction, due to the piezo-viscous property of the lubricant. Furthermore, the thermo-viscosity relation also has a significant influence, which...... adds to the discrepancy of such simple design approach. In this paper the hydrostatic pressure force calculation is reviewed in terms of thermohydrodynamic (THD) lubrication theory, and simple analytical approximations of the hydrostatic pressure force, incorporating the piezo-viscous and thermo...

  11. Influence analysis of structural parameters on electromagnetic properties of HTS linear induction motor

    Science.gov (United States)

    Zhao, J.; Zheng, T. Q.; Zhang, W.; Fang, J.; Liu, Y. M.

    2011-11-01

    A new type high temperature superconductor linear induction motor is designed and analyzed as a prototype to ensure applicability aimed at industrial motors. Made of Bi-2223/Ag, primary windings are distributed with the double-layer concentrated structure. The motor is analyzed by 2D electromagnetic Finite Element Method to get magnetic field distribution, thrust force, vertical force and so on. The critical current of motor and the electromagnetic force are mostly decided by the leakage flux density of primary slot and by the main magnetic flux and eddy current respectively. The structural parameters of motor have a great influence on the distribution of magnetic field. Under constant currents, the properties of motor are analyzed with different slot widths, slot heights and winding turns. The properties of motor, such as the maximum slot leakage flux density, motor thrust and motor vertical force, are analyzed with different structural parameters.

  12. Influence of Rare Earth Doping on the Structural and Catalytic Properties of Nanostructured Tin Oxide

    Directory of Open Access Journals (Sweden)

    Maciel Adeilton

    2008-01-01

    Full Text Available AbstractNanoparticles of tin oxide, doped with Ce and Y, were prepared using the polymeric precursor method. The structural variations of the tin oxide nanoparticles were characterized by means of nitrogen physisorption, carbon dioxide chemisorption, X-ray diffraction, and X-ray photoelectron spectroscopy. The synthesized samples, undoped and doped with the rare earths, were used to promote the ethanol steam reforming reaction. The SnO2-based nanoparticles were shown to be active catalysts for the ethanol steam reforming. The surface properties, such as surface area, basicity/base strength distribution, and catalytic activity/selectivity, were influenced by the rare earth doping of SnO2and also by the annealing temperatures. Doping led to chemical and micro-structural variations at the surface of the SnO2particles. Changes in the catalytic properties of the samples, such as selectivity toward ethylene, may be ascribed to different dopings and annealing temperatures.

  13. Influence of hydroxyl content on selected properties of 45S5 bioactive glass.

    Science.gov (United States)

    Hall, Matthew M

    2007-12-01

    Numerous material properties may be influenced by the concentration of chemically dissolved hydroxyl species within a glass. A tube furnace connected to a steam generator was used to create hydroxyl-saturated 45S5 glass under 1 atm of water at 1100 degrees C. Selected properties of as-melted and hydroxyl-saturated samples were compared to assess the sensitivity of 45S5 to excess hydroxylation. The glass transition temperature and the peak crystallization temperature of the treated 45S5 glass were reduced in comparison to the as-melted 45S5 glass. In addition, the treated glass exhibited a broad endothermic signal that may be indicative of enhanced viscous flow. A simple dissolution experiment indicated that the treated 45S5 glass was also less durable than the as-melted 45S5 glass.

  14. The influence of physical properties on propagation velocity of seismic waves of the rocks

    Directory of Open Access Journals (Sweden)

    Radoslav Schügerl

    2010-01-01

    Full Text Available Dynamic load are very important for determination physical properties of the rocks. Dynamic load propagates in the rocks by seismic waves (subsurface waves – longitudinal and transverse, and surface – Rayleigh´s waves. Laboratory (ultrasound machine and hydraulic jack and field methods (cross – hole, down – hole and up – hole on the determination to propagation velocity of seismic waves of the rocks can be used. This article presents selected problems of the research of the influence of physical properties (bulk density, porosity, change of temperature, stage of saturation on propagation velocity of seismic waves of the rocks and compares the values of dynamic modulus of elasticity Edyn obtain by means of ultrasound machine and by hydraulic jack. These parameters were obtained by laboratory testing of sandstone samples from locality of Jánovce – Jablonov (Šibenik tunnel.

  15. Influence of carbonyl iron particle coating with silica on the properties of magnetorheological elastomers

    Science.gov (United States)

    Małecki, P.; Królewicz, M.; Hiptmair, F.; Krzak, J.; Kaleta, J.; Major, Z.; Pigłowski, J.

    2016-10-01

    In this paper, the influence of encapsulating carbonyl iron particles with various silica coatings on the properties of magnetorheological elastomers (MREs) was investigated. A soft styrene-ethylene-butylene-styrene thermoplastic elastomer was used as the composite’s polymer matrix. Spherical carbonyl iron powder (CIP) acted as the ferromagnetic filler. In order to improve the metal-polymer interaction, carbonyl iron particles were coated with two types of single and six types of double silica layers. The first layer was created through a TMOS or TEOS hydrolysis whereas the second one was composed of organosilanes. The mechanical properties of MREs containing 38.5 vol% of CIP were analysed under dynamic loading conditions. To investigate the magnetorheological effect in these composites, a 430 mT magnetic field, generated by an array of permanent magnets, was applied during testing. The results revealed that the magnetomechanical response of the MREs differs substantially, depending on the kind of particle coating.

  16. Influence of Rare Earth Elements on Microstructure and Mechanical Properties of Mg-Li Alloys

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    A series of α-based Mg-Li-Al-Zn-xRE alloys were prepared. These alloys have low density ranging from 1.5 to 1.7 g·cm-3 and high strength properties. The influence of RE element on the microstructure and the mechanical properties of these alloys were studied. The results indicate that the addition of RE (La, Pr, Ce) leads to the formation of rod-shaped intermetallic compound Al2Zn2La distributed in the matrix. Al2Zn2La induces reduction of the laminar spacing and causes refinement of the microstructure. Therefore, this compound improves the strength of alloys at a high temperature.

  17. Influence of tragacanth gum in egg white based bioplastics: Thermomechanical and water uptake properties.

    Science.gov (United States)

    López-Castejón, María Luisa; Bengoechea, Carlos; García-Morales, Moisés; Martínez, Inmaculada

    2016-11-05

    This study aims to extend the range of applications of tragacanth gum by studying its incorporation into bioplastics formulation, exploring the influence that different gum contents (0-20wt.%) exert over the thermomechanical and water uptake properties of bioplastics based on egg white albumen protein (EW). The effect of plasticizer nature was also evaluated through the modification of the water/glycerol ratio within the plasticizer fraction (fixed at 40wt.%). The addition of tragacanth gum generally yielded an enhancement of the water uptake capacity, being doubled at the highest content. Conversely, presence of tragacanth gum resulted in a considerable decrease in the bioplastic mechanical properties: both tensile strength and maximum elongation were reduced up to 75% approximately when compared to the gum-free system. Ageing of selected samples was also studied, revealing an important effect of storage time when tragacanth gum is present, possibly due to its hydrophilic character.

  18. How Far Does a Receptor Influence Vibrational Properties of an Odorant?

    Directory of Open Access Journals (Sweden)

    Anna Reese

    Full Text Available The biophysical mechanism of the sense of smell, or olfaction, is still highly debated. The mainstream explanation argues for a shape-based recognition of odorant molecules by olfactory receptors, while recent investigations suggest the primary olfactory event to be triggered by a vibrationally-assisted electron transfer reaction. We consider this controversy by studying the influence of a receptor on the vibrational properties of an odorant in atomistic details as the coupling between electronic degrees of freedom of the receptor and the vibrations of the odorant is the key parameter of the vibrationally-assisted electron transfer. Through molecular dynamics simulations we elucidate the binding specificity of a receptor towards acetophenone odorant. The vibrational properties of acetophenone inside the receptor are then studied by the polarizable embedding density functional theory approach, allowing to quantify protein-odorant interactions. Finally, we judge whether the effects of the protein provide any indications towards the existing theories of olfaction.

  19. The influence of processing on microstructure and properties of iron aluminides

    Energy Technology Data Exchange (ETDEWEB)

    Wright, R.N.; Wright, J.K. [Idaho National Engineering Lab., Idaho Falls, ID (United States)

    1995-08-01

    An Fe-28%Al alloy containing 5% Cr has been synthesized by reaction of elemental powders, followed by consolidation using hot isostatic pressing or hot extrusion. The resulting materials are fully dense, homogeneous, and have a grain size of less than 5{mu}m. Processing strongly influences the propensity toward secondary recrystallization. While HIPped material is extremely resistant to grain growth, under some circumstances hot extruded material undergoes secondary recrystallization, resulting in grain sizes as large as 25 millimeters. Elevated temperature tensile properties and strain rate sensitivities are reported for fine and very coarse grained materials. Grain boundary sliding is not a significant deformation mode for any of the materials. The properties are compared to those of Fe{sub 3}Al processed from conventional hot extruded prealloyed. powder. It has been found that the reaction synthesized materials generally have superior elevated temperature tensile strength.

  20. Influence of oxygen impurity on electronic properties of carbon and boron nitride nanotubes: A comparative study

    Directory of Open Access Journals (Sweden)

    Ram Sevak Singh

    2015-11-01

    Full Text Available Influence of oxygen impurity on electronic properties of carbon and boron nitride nanotubes (CNTs and BNNTs is systematically studied using first principle calculations based on density functional theory. Energy band structures and density of states of optimized zigzag (5, 0, armchair (3, 3, and chiral (4, 2 structures of CNT and BNNT are calculated. Oxygen doping in zigzag CNT exhibits a reduction in metallicity with opening of band gap in near-infrared region while metallicity is enhanced in armchair and chiral CNTs. Unlike oxygen-doped CNTs, energy bands are drastically modulated in oxygen-doped zigzag and armchair BNNTs, showing the nanotubes to have metallic behaviour. Furthermore, oxygen impurity in chiral BNNT induces narrowing of band gap, indicating a gradual modification of electronic band structure. This study underscores the understanding of different electronic properties induced in CNTs and BNNTs under oxygen doping, and has potential in fabrication of various nanoelectronic devices.

  1. Influence of the flexibility of beams and slabs in static response and dynamic properties

    Directory of Open Access Journals (Sweden)

    J. R. BUENO

    Full Text Available Abstract This article examines numerically the flexibility influence of support beams in static response and dynamic properties of a symmetric plate formed by massive slabs of reinforced concrete in elastic linear regime, using the Finite Element Method. In the static response the variation of bending mo-ments and displacements are evaluated, which depend on the relationship between the flexibility of the slab and the beam. The evaluation of dynamic properties is held in undamped free vibration, through which the vibration modes and the values of the natural frequencies is obtained, which are compared with the limits of the Brazilian standard code for design of concrete structures. Results show that the response may show great variation due to the change in the relationship between bending stiffness of the slabs and the beams.

  2. The influence of high pressure on the properties of natural alumino-silicates

    Directory of Open Access Journals (Sweden)

    Šušić N.

    2002-01-01

    Full Text Available The effect of the application of high-pressure (up to 12 GPa on natural alumino-silicates has been studied. Chemical and mineral compositions and thermal behaviour have been analyzed of two samples of alumino-silicates. Results obtained indicate that the application of high pressure causes notable changes. A particularly significant one is the formation of amorphous phases on account of crystalline phases. An amorphous layer formed on particle surfaces with its diverse physical, mechanical, chemical, and other properties, especially over a long period of time, can influence the processes provoking or activating land slides or soil settlements. This enables derivation of many new materials with entirely new properties important for use in the ceramic and brick industries.

  3. Mesomeric Effects of Graphene Modified with Diazonium Salts: Substituent Type and Position Influence its Properties.

    Science.gov (United States)

    Bouša, Daniel; Jankovský, Ondřej; Sedmidubský, David; Luxa, Jan; Šturala, Jiří; Pumera, Martin; Sofer, Zdeněk

    2015-12-01

    In the last decade, graphene and graphene derivatives have become some of the most intensively studied materials. Tuning of the electronic and electrochemical properties of graphene is of paramount importance. In this study, six diazonium-modified graphenes containing different functional groups according to the diazonium salt precursor were investigated. These diazonium moieties have a strong mesomeric (resonance) effect and act as either electron-donating or -withdrawing species. Different graphene precursors, such as thermally and chemically reduced graphenes were studied. All the products were characterized in detail by elemental combustion analysis, FTIR spectroscopy, Raman spectroscopy, high-resolution X-ray photoelectron spectroscopy (XPS), and cyclic voltammetry. Resistivity and zeta potential measurements were consistent with theoretical (DFT) calculations. The results show that chemical modification of graphene by diazotation strongly influences its properties, creating a huge application potential in microelectronics, energy storage and conversion devices, and electrocatalysis.

  4. Influence of oxygen impurity on electronic properties of carbon and boron nitride nanotubes: A comparative study

    Energy Technology Data Exchange (ETDEWEB)

    Singh, Ram Sevak, E-mail: singh915@gmail.com [Department of Physics, National Institute of TechnologyKurukshetra 136119 (Haryana) (India)

    2015-11-15

    Influence of oxygen impurity on electronic properties of carbon and boron nitride nanotubes (CNTs and BNNTs) is systematically studied using first principle calculations based on density functional theory. Energy band structures and density of states of optimized zigzag (5, 0), armchair (3, 3), and chiral (4, 2) structures of CNT and BNNT are calculated. Oxygen doping in zigzag CNT exhibits a reduction in metallicity with opening of band gap in near-infrared region while metallicity is enhanced in armchair and chiral CNTs. Unlike oxygen-doped CNTs, energy bands are drastically modulated in oxygen-doped zigzag and armchair BNNTs, showing the nanotubes to have metallic behaviour. Furthermore, oxygen impurity in chiral BNNT induces narrowing of band gap, indicating a gradual modification of electronic band structure. This study underscores the understanding of different electronic properties induced in CNTs and BNNTs under oxygen doping, and has potential in fabrication of various nanoelectronic devices.

  5. INFLUENCE OF MIXING SEQUENCE ON THE PROPERTIES OF BLENDS OF PS/SBRr COMPATIBILIZED WITH SBS

    Directory of Open Access Journals (Sweden)

    Carlos Bruno Barreto Luna

    2015-03-01

    Full Text Available Blends of polystyrene (PS containing styrene-butadiene rubber (SBRr wastes were prepared using 5% the styrenebutadiene-styrene compatibilizer agent (SBS. The blends were initially processed in a corrotational twin screw extruder and subsequently, the extruded pellets were molded by injection. The blends were mechanically characterized (Impact and Bending and morphologically (SEM. The main objective was to analyze the influence of mixing sequence on the morphology and mechanical properties of these blends. The results showed that the impact strength increased significantly, while losses in the resistance to flexure property occurred in comparison to the polymer matrix. When the SBS and PS were mixed together in a first extrusion step, prior to incorporation of SBRr in a second extrusion step, an optimization of the impact strength increased by 302% in relation to polystyrene matrix. These results show a good perspective of application of these industrial wastes (SBRr, since they can add value to a material that would otherwise be discarded.

  6. Influence of the virtual photon field on the squeezing properties of an atom laser

    Institute of Scientific and Technical Information of China (English)

    Zhao Jian-Gang; Sun Chang-Yong; Wen Ling-Hua; Liang Bao-Long

    2009-01-01

    This paper investigates the squeezing properties of an atom laser without rotating-wave approximation in the system of a binomial states field interacting with a two-level atomic Bose-Einstein condensate. It discusses the influences of atomic eigenfrequency, the interaction intensity between the optical field and atoms, parameter of the binomial states field and virtual photon field on the squeezing properties. The results show that two quadrature components of an atom laser can be squeezed periodically. The duration and the degree of squeezing an atom laser have something to do with the atomic eigenfrequency and the parameter of the binomial states field, respectively. The collapse and revival frequency of atom laser fluctuation depends on the interaction intensity between the optical field and atoms. The effect of the virtual photon field deepens the depth of squeezing an atom laser.

  7. Influence of the Scrap Tyre Processing Techniques on the Physical Properties of the Crumb Rubber

    Directory of Open Access Journals (Sweden)

    Naeem Aziz Memon

    2012-10-01

    Full Text Available The processing mechanism of scrap tyres to produce CR (Crumb Rubber has a great influence on the properties of the CRMB (Crumb Rubber Modified Bitumen. A fair amount of research was observed in the literature on the bitumen modified by CR processed cryogenically and ambiently. However, little or no work has been done on the CR processed by the other methods such as the Aquablast processing technique, which is a relatively a new waste tyre rubber processing technique within the CR industry. In this study, CR obtained from the two sources; ambient and Aquablast grinding techniques were primarily assessed with a helium pycnometer and SEM (Scanning Electron Microscopy for their physical properties and appearance respectively. Observations from this laboratory study indicated: (1 the density of the ambient CR was slightly higher than the CR obtained from Aquablast technique; (2 difference in physical appearance was found insignificant.

  8. The Influenced of Compression on Properties of Binderless Compressed Veneer Made from Oil Palm Trunk

    Directory of Open Access Journals (Sweden)

    Norhafizah Saari

    2015-01-01

    Full Text Available Binderless compressed veneer panels from oil palm trunk consisted of 5 layers of oil palm trunk veneers were made with 3 different thickness, 7 mm, 10 mm and 15 mm. The panels were pressed at temperature of 180 °C with pressure 5 MPa at duration time of 20 minutes. The veneers were pressed without using any synthetic adhesive in the manufacturing process. Mechanical and physical properties such as flexural test, thickness swelling and water absorption, density and compression ratio were observed and evaluated based on Japanese Agricultural Standard 2003 (JAS. The findings showed that binderless compressed veneer panels that undergo pressing process with thickness bar 7 mm showed the highest value of flexural strength compared to other type of panels. Dimensional stability such as thickness swelling and water absorption showed relationship with compression ratio. Based on the results, the compression ratio did influenced the properties of binderless compressed veneer panel made from oil palm trunk.

  9. Influence of deposition time on the properties of chemical bath deposited manganese sulfide thin films

    Directory of Open Access Journals (Sweden)

    Anuar Kassim

    2010-12-01

    Full Text Available Manganese sulfide thin films were chemically deposited from an aqueous solution containing manganese sulfate, sodium thiosulfate and sodium tartrate. The influence of deposition time (2, 3, 6 and 8 days on the properties of thin films was investigated. The structure and surface morphology of the thin films were studied by X-ray diffraction and atomic force microscopy, respectively. In addition, in order to investigate the optical properties of the thin films, the UV-visible spectrophotometry was used. The XRD results indicated that the deposited MnS2 thin films exhibited a polycrystalline cubic structure. The number of MnS2 peaks on the XRD patterns initially increased from three to six peaks and then decreased to five peaks, as the deposition time was increased from 2 to 8 days. From the AFM measurements, the film thickness and surface roughness were found to be dependent on the deposition time.

  10. Influence of sintering temperature on structure, microstructure and piezoelectric properties of doped BZT-BCT ceramics

    Science.gov (United States)

    Dang, Anh Tuan; Vo, Thanh Tung; Truong, Van Chuong; Le, Van Hong

    2017-01-01

    This work reports the influence of sintering temperature on structure, microstructure and piezoelectric properties of 0.48 Ba(Zr0.2Ti0.8)O3-0.52 (Ba0.7Ca0.3)TiO3(BZT-BCT) doped with ZnO nanoparticle ceramics manufactured by a conventional solid state reaction method. By increasing sintering temperature, the piezoelectric behaviors were improved and rose up to the best parameters at a sintering temperature of 1450∘C (d33 = 576 pC/N and kp = 0.55). The corresponding properties of undoped BZT-BCT ceramics were investigated as a comparison. The received results show that the sintering behavior and piezo-parameters of doped BZT-BCT samples are better than the undoped BZT-BCT samples at each sintering temperature.

  11. Influence of Oxygen Vacancy on Transport Property in Perovskite Oxide Heterostructures

    Institute of Scientific and Technical Information of China (English)

    HAN Peng; JIN Kui-Juan; Lü Hui-Bin; JIA Jin-Feng; QIU Jie; HU Chun-Lian; YANG Guo-Zhen

    2009-01-01

    Effect of oxygen vacancy on transport property of perovskite microstructures is studied theoretically. Compared with calculated and measured I-V curves, it is revealed that electron conduction plays an important role in the oxygen nonstoichiometry perovskite heterostructures even with hole-doped or un-doped material due to the oxygen vacancies. In addition, a detailed understanding of the influence of oxygen vacancy concentration and temperature on the conduction characteristics of oxide heterojunction with both forward and reverse biases is obtained by calculation.

  12. Influence of electrostatic charging on the magnetic and other physical properties of thin metallic films

    Energy Technology Data Exchange (ETDEWEB)

    Steinbeck, K.

    1971-01-01

    Electrical, superconducting and optical properties of thin metal films can be influenced by electrostatic charging. In the same way attempts have been made to change the saturation magnetization of ferromagnetic films, which was measured, e.g., with the torque method. Using the film as one plate of a capacitor torque changes are measured for different voltages. The torque changes are assumed to be caused by magnetization changes due to an altered electron concentration of the metal. The contribution of one unit charge to the magnetic moment was estimated to ca. /sup 1///sub 2/ mu/sub B/.

  13. Catalytic activity of metallic nanoisland coatings. The influence of size effects on the recombination properties

    Science.gov (United States)

    Tomilina, O. A.; Berzhansky, V. N.; Tomilin, S. V.; Shaposhnikov, A. N.

    2016-08-01

    The results of investigations of the quantum-size effects influence on selective properties of heterogeneous nanocatalysts are presents. As etalon exothermic reaction was used the reaction of atomic hydrogen recombination. The nanostructured Pd and Pt films on Teflon substrate were used as a samples of heterogeneous nanocatalysts. It was shown that for nanoparticles with various sizes the catalytic activity has the periodic dependence. It has been found that for certain sizes of nanoparticles their catalytic activity is less than that of Teflon substrate.

  14. AMINOSILICA NANO- AND SUBMICROSPHERES: ANALYSIS OF FACTORS INFLUENCING MORPHOLOGY, STRUCTURE AND PROPERTIES

    Directory of Open Access Journals (Sweden)

    Inna Melnyk

    2014-06-01

    Full Text Available Current paper focuses on the analysis of influence of main factors (stages of the synthesis, the ratio of the reacting components, the order of their introduction, the concentration of water and ammonia, the synthesis temperature on the morphology, size and content of functional groups of aminosilicanano- and submicrospheres. The recommendations for the synthesis of particles with predetermined properties were done. It is shown, that the ratio of the reacting components mainly affects the content of 3-aminopropyl functional groups and the temperature of the hydrolytic polycondensation reaction - the size of the particles.

  15. Influence of the Surfactants on Microstructure and the Properties of Wet Coagulation Polyurethane Film

    Institute of Scientific and Technical Information of China (English)

    ZENG Yue-min; YAN Hao-jing; HU Jin-lian

    2002-01-01

    Polyurethane asymmetric membranes were prepared bywet coagulation process from the PU/DMF/Span-80/OT-70 solutions, and the morphological features of the cross section of the membranes obtained by scanning electron microscopy were presented. The influences of the non-ionic hydrophobic surfactant Span- 80 and the anionic surfactant hydrophilic OT-70 on the morphology of the membranes, the mechanical properties and the water vapor permeability were studied. The formation mechanism of the membrane microstructure from the different PU/DMF/Surfactants systems was discussed.

  16. The influence of yarn treatment on the tensile properties of biocomposites

    Science.gov (United States)

    Širvaitienė, Anne; Jankauskaitė, Virginija; Bekampienė, Paulė; Sankauskaitė, Audronė

    2012-07-01

    The aim of this work was to investigate the influence of cotton and linen yarns treatments at different hierarchical levels on the biocomposite tensile properties. The biodegradable poly(lactic acid) (PLA) resin was used as the matrix polymer. The water based mercerization and low pressure plasma treatment were applied for chemical modification of yarns macro- and microfibrils. To improve fiber orientation of fibre bundles and single fibers the pretension of yarn was used. It was obtained that the most efficient is the complex yarns treatment, plasma treatment with subsequent pre-tension, where especially notable was the positive effect of low-pressure plasma.

  17. Influence of cooling rate on interlaminar fracture properties of unidirectional commingled CF/PEEK composites

    Science.gov (United States)

    Beehag, Andrew; Ye, Lin

    1995-05-01

    The influence of cooling rates on the mechanical property profile (transverse flexure properties and modes-I and -II interlaminar fracture toughness) has been investigated for unidirectional commingled CF/PEEK composites. A laboratory hot press with a steel mould was used to process the composites at 400°C for 60 min, at an applied pressure of 1 MPa. Cooling rates from fast (quenching in oil) to slow (hot press cooling) were achieved at ambient pressure. The results indicate that different matrix morphology was found at different cooling conditions, although deconsolidation occurred in the CF/PEEK composites during cooling. When the cooling rate was shifted from slow to fast, consolidation quality of the CF/PEEK composites was improved. The resulting effect of the consolidation quality and cooling rates on the mechanical property profile of commingled CF/PEEK composites is presented. It was found that the effect of the cooling rate on the mechanical property profile of the commingled CF/PEEK composites could not be isolated from the consolidation quality.

  18. TEXTURE AND CRYSTALLINITY EVOLUTION IN ISOTACTIC POLYPROPYLENE INDUCED BY ROLLING AND THEIR INFLUENCE ON MECHANICAL PROPERTIES

    Institute of Scientific and Technical Information of China (English)

    Juan Jia; Dierk Raabe; Wei-min Mao

    2006-01-01

    The orientation and crystallinity evolution of isotactic polypropylene (iPP) induced by rolling were studied using wide angle X-ray scattering with an area detector. The tensile mechanical properties of rolled isotactic polypropylene sheets were also measured in this work. The texture component method was used to analyze the rolling texture. The rolling texture consists mainly of (010)[001], (130)[001] and [001]//RD fiber components in the sample with a rolling true strain of 1.5.The results reveal that crystallinity drastically decreases during rolling. It is suggested that amorphization is a deformation mechanism which takes place as an alternative to crystallographic intralamellar slip depending on the orientation of the lamellae. Both the orientation and crystallinity affect the tensile mechanical properties of rolled polypropylene. Crystallinity influences the elastic modulus on both directions and yield strength on transverse direction at the first stage of deformation.Orientation is the main reason for the changes of mechanical properties, especially at the latter part of deformation. The changes of both tensile strength and elongation percentage on rolling direction are larger than those on transverse direction,which results from the orientation. At last, the anisotropic mechanical properties occur on the rolling and transverse direction: high tensile strength with low elongation percentage on rolling direction and low tensile strength with high elongation percentage on transverse direction.

  19. Gum Tragacanth Fibers from Astragalus gummifer Species: Effects of Influencing Factors on Mechanical Properties of Fibers

    Science.gov (United States)

    Khajavi, Ramin; Mossavi Pourgharbi, Seyed Hossein; Kiumarsi, Amir; Rashidi, Abosayeed

    Gum Tragacanth (GT) is one of the most widely used natural gum across the globe and it is shown that GT from Asteragalus gummifer can be processed into fiber via alkaline treatment. In this study a complementary description of GT fibers is provided and the effects of influencing factors on properties of GT fibers investigated. Spinning Dope (SD) prepared by adding ribbon type GT of Astragalus gummifer species to alkaline solutions and fibers produced by solution spinning method. The effects of some processing factors including: draft ratio, residence time in coagulation bath, GT concentration in SD, ripening time of SD, kind of coagulant agent and the pH of washing bath on some mechanical properties of GT fibers studied. It was concluded that with increasing the coagulant concentration the mechanical properties of fibers improved, but it caused formation of sheet core structure. ZnCl2 as coagulant agent improved mechanical properties and applying glycerol caused more flexibility in GT fibers, even though their tenacity reduced.

  20. The Influence of Alkoxy Substitutions on the Properties of Diketopyrrolopyrrole-Phenyl Copolymers for Solar Cells

    Directory of Open Access Journals (Sweden)

    Paul Heremans

    2013-07-01

    Full Text Available A previously reported diketopyrrolopyrrole (DPP-phenyl copolymer is modified by adding methoxy or octyloxy side chains on the phenyl spacer. The influence of these alkoxy substitutions on the physical, opto-electronic properties, and photovoltaic performance were investigated. It was found that the altered physical properties correlated with an increase in chain flexibility. Well-defined oligomers were synthesized to verify the observed structure-property relationship. Surprisingly, methoxy substitution on the benzene spacer resulted in higher melting and crystallization temperatures in the synthesized oligomers. This trend is not observed in the polymers, where the improved interactions are most likely counteracted by the larger conformational possibilities in the polymer chain upon alkoxy substitution. The best photovoltaic performance was obtained for the parent polymer: fullerene blends whereas the modifications on the other two polymers result in reduced open-circuit voltage and varying current densities under similar processing conditions. The current densities could be related to different polymer: fullerene blend morphologies. These results show that supposed small structural alterations such as methoxy substitution already significantly altered the physical properties of the parent polymer and also that oligomers and polymers respond divergent to structural alterations made on a parent structure.

  1. Analyzing the Heat Transfer Property of Heat Pipe Influenced by Integrated Cooling Apparatus

    Directory of Open Access Journals (Sweden)

    Chen-Ching Ting

    2014-01-01

    Full Text Available Heat pipe with discrete heat transfer property is often called thermal superconductor because it has extremely large thermal conductivity. This special heat transfer property is destroyed by integrating cooling apparatus and further reducing the cooling power of a heat pipe cooler. This paper experimentally studied the heat transfer property of heat pipe influenced by integrated cooling apparatus. To simplify the investigating process, a home-made square heat pipe with the dimensions of L×W×H=10×10×100 mm3 was built with two pieces of copper plates and two pieces of glass plates face to face, respectively. The two pieces of copper plates were constructed with inside walls of capillary structure and the two pieces of glasses were with antifog inside walls for observing the inner phenomenon. Moreover, isothermal circulating cooling water was applied outside the heat pipe instead of cooling fin. The results show that heat vapor in the heat pipe is condensed earlier and cannot reach the remote section of condenser. In other words, the heat transfer property of heat pipe is destroyed by integrating cooling water. This phenomenon causes the unfavorable cooling power of the heat pipe cooler.

  2. Evaluation of Beeswax Influence on Physical Properties of Lipstick Using Instrumental and Sensory Methods.

    Science.gov (United States)

    Kasparaviciene, Giedre; Savickas, Arunas; Kalveniene, Zenona; Velziene, Saule; Kubiliene, Loreta; Bernatoniene, Jurga

    2016-01-01

    The aim of this study was to optimize the lipsticks formulation according to the physical properties and sensory attributes and investigate the relationship between instrumental and sensory analyses and evaluate the influence of the main ingredients, beeswax and oil, with analysis of lipsticks properties. Central composite design was used to optimize the mixture of oils and beeswax and cocoa butter for formulation of lipsticks. Antioxidant activity was evaluated by DPPH free radical scavenging method spectrophotometrically. Physical properties of lipsticks melting point were determined in a glass tube; the hardness was investigated with texture analyzer. Sensory analysis was performed with untrained volunteers. The optimized mixture of sea buckthorn oil and grapeseed oil mixture ratio 13.96 : 6.18 showed the highest antioxidative activity (70 ± 0.84%) and was chosen for lipstick formulation. According to the sensory and instrumental analysis results, optimal ingredients amounts for the lipstick were calculated: 57.67% mixture of oils, 19.58% beeswax, and 22.75% cocoa butter. Experimentally designed and optimized lipstick formulation had good physical properties and high scored sensory evaluation. Correlation analysis showed a significant relationship between sensory and instrumental evaluations.

  3. Evaluation of Beeswax Influence on Physical Properties of Lipstick Using Instrumental and Sensory Methods

    Directory of Open Access Journals (Sweden)

    Giedre Kasparaviciene

    2016-01-01

    Full Text Available The aim of this study was to optimize the lipsticks formulation according to the physical properties and sensory attributes and investigate the relationship between instrumental and sensory analyses and evaluate the influence of the main ingredients, beeswax and oil, with analysis of lipsticks properties. Central composite design was used to optimize the mixture of oils and beeswax and cocoa butter for formulation of lipsticks. Antioxidant activity was evaluated by DPPH free radical scavenging method spectrophotometrically. Physical properties of lipsticks melting point were determined in a glass tube; the hardness was investigated with texture analyzer. Sensory analysis was performed with untrained volunteers. The optimized mixture of sea buckthorn oil and grapeseed oil mixture ratio 13.96 : 6.18 showed the highest antioxidative activity (70±0.84% and was chosen for lipstick formulation. According to the sensory and instrumental analysis results, optimal ingredients amounts for the lipstick were calculated: 57.67% mixture of oils, 19.58% beeswax, and 22.75% cocoa butter. Experimentally designed and optimized lipstick formulation had good physical properties and high scored sensory evaluation. Correlation analysis showed a significant relationship between sensory and instrumental evaluations.

  4. Indexical properties influence time-varying amplitude and fundamental frequency contributions of vowels to sentence intelligibility

    Science.gov (United States)

    Fogerty, Daniel

    2015-01-01

    The present study investigated how non-linguistic, indexical information about talker identity interacts with contributions to sentence intelligibility by the time-varying amplitude (temporal envelope) and fundamental frequency (F0). Young normal-hearing adults listened to sentences that preserved the original consonants but replaced the vowels with a single vowel production. This replacement vowel selectively preserved amplitude or F0 cues of the original vowel, but replaced cues to phonetic identity. Original vowel duration was always preserved. Three experiments investigated indexical contributions by replacing vowels with productions from the same or different talker, or by acoustically morphing the original vowel. These stimulus conditions investigated how vowel suprasegmental and indexical properties interact and contribute to intelligibility independently from phonetic information. Results demonstrated that indexical properties influence the relative contribution of suprasegmental properties to sentence intelligibility. F0 variations are particularly important in the presence of conflicting indexical information. Temporal envelope modulations significantly improve sentence intelligibility, but are enhanced when either indexical or F0 cues are available. These findings suggest that F0 and other indexical cues may facilitate perceptually grouping suprasegmental properties of vowels with the remainder of the sentence. Temporal envelope modulations of vowels may contribute to intelligibility once they are successfully integrated with the preserved signal. PMID:26543276

  5. Compound microstructures and wax layer of beetle elytral surfaces and their influence on wetting properties.

    Directory of Open Access Journals (Sweden)

    Mingxia Sun

    Full Text Available A beetles' first line of defense against environmental hazards is their mesothoracic elytra--rigid, protective forewings. In order to study the interaction of these wings with water, the surface microstructures of various beetles' elytra were observed by Environment Scanning Electron Microscopy (ESEM and Atomic Force Microscopy (AFM. Chemistry components were ascertained using X-ray photoelectron spectroscopy (XPS. All the beetles of various habitats (including desert, plant, dung, land and water exhibited compound microstructures on their elytra. The wetting properties of these elytra were identified using an optical contact angle meter. In general the native elytra exhibited hydrophilic or weak hydrophobic properties with contact angles (CAs ranging from 47.5° to 109.1°. After treatment with chloroform, the CAs all increased on the rougher elytral surfaces. The presence of wax is not the only determinant of hydrophobic properties, but rather a combination with microscopic structures found on the surfaces. Irregularities and the presence or absence of tiny cracks, hairs (or setae, pores and protrusions are important factors which influence the wetting properties. Rougher elytral surfaces tended to present a stronger hydrophobicity. Effects on hydrophobicity, such as surface microstructures, chemistry, environment and aging (referring to the time after emergence, are also included and discussed. Our results also provide insights into the motion of water droplets when in contact with beetle elytra.

  6. Influence of static and cyclic climate condition on bending properties of wood plastic composites (WPC

    Directory of Open Access Journals (Sweden)

    2010-06-01

    Full Text Available Wood and natural fiber reinforced plastic composites are established for several fields like decking, transportation and automotive applications. In the last decade, extensive researches were conducted to improve the mechanical properties, such as incorporating additives like maleic anhydride grafted polypropylene (MAH-PP. The major challenge is to keep the properties in face of the environmental influence the parts are exposed to. Therefore it’s necessary to find the hardest impact factor concerning the mechanical properties. Water absorption (static and cyclic of the composites was examined at two different temperatures (23, 50°C. A correlation between duration, kind of conditioning, temperature and modification was established. The results indicate that the coupling agent MAH-PP improved significantly the water resistance of the wood plastic composites under climatic conditions and higher temperature accelerated the rate of water absorption of the composites. The decrease of mechanical properties related to cyclic conditions is partially reversible and therefore the cyclic exposition shows less effects compared to static conditions.

  7. Influence of soil properties on the bioaccumulation and effects of arsenic in the earthworm Eisenia andrei.

    Science.gov (United States)

    Romero-Freire, A; Peinado, F J Martín; Ortiz, M Díez; van Gestel, C A M

    2015-10-01

    This study aimed at assessing the influence of soil properties on the uptake and toxicity effects of arsenic in the earthworm Eisenia andrei exposed for 4 weeks to seven natural soils spiked with different arsenic concentrations. Water-soluble soil concentrations (AsW) and internal As concentrations in the earthworms (AsE) were greatly different between soils. These two variables were highly correlated and were key factors in earthworm toxicity response. AsW was explained by some soil properties, such as the pH, calcium carbonate content, ionic strength, texture or oxide forms. Toxicity showed a clear variation between soils, in some cases without achieving 50 % adverse effect at the highest As concentration added (600 mg kg(-1)). Nevertheless, soil properties did not show, in general, a high relation with studied toxicity endpoints, although the high correlation with AsW could greatly reduce indirectly As bioavailability and toxicity risk for earthworms. Obtained results suggest that soil properties should be part of the criteria to establishing thresholds for contaminated soils because they will be key in controlling As availability and thus result in different degrees of toxicity.

  8. Influence of autoclave sterilization on the surface parameters and mechanical properties of six orthodontic wires.

    Science.gov (United States)

    Pernier, C; Grosgogeat, B; Ponsonnet, L; Benay, G; Lissac, M

    2005-02-01

    Orthodontic wires are frequently packaged in individual sealed bags in order to avoid cross-contamination. The instructions on the wrapper generally advise autoclave sterilization of the package and its contents if additional protection is desired. However, sterilization can modify the surface parameters and the mechanical properties of many types of material. The aim of this research was to determine the influence of one of the most widely used sterilization processes, autoclaving (18 minutes at 134 degrees C, as recommended by the French Ministry of Health), on the surface parameters and mechanical properties of six wires currently used in orthodontics (one stainless steel alloy: Tru-Chrome RMO; two nickel-titanium shape memory alloys: Neo Sentalloy and Neo Sentalloy with Ionguard GAC; and three titanium-molybdenum alloys: TMA(R) and Low Friction TMA Ormco and Resolve GAC). The alloys were analysed on receipt and after sterilization, using surface structure observation techniques, including optical, scanning electron and atomic force microscopy and profilometry. The mechanical properties were assessed by three-point bending tests. The results showed that autoclave sterilization had no adverse effects on the surface parameters or on the selected mechanical properties. This supports the possibility for practitioners to systematically sterilize wires before placing them in the oral environment.

  9. Properties of BGO thin films under the influence of gamma radiation

    Energy Technology Data Exchange (ETDEWEB)

    Arshak, K. [Electronic and Computer Engineering Department, University of Limerick, Limerick (Ireland)], E-mail: khalil.arshak@ul.ie; Korostynska, O.; Harris, J. [Electronic and Computer Engineering Department, University of Limerick, Limerick (Ireland); Morris, D.; Arshak, A. [Physics Department, University of Limerick, Limerick (Ireland); Jafer, E. [Electronic and Computer Engineering Department, University of Limerick, Limerick (Ireland)

    2008-02-15

    It is important to know the behaviour of materials under the influence of radiation for the effective design of novel sensor systems. Optical properties of bismuth germinate (Bi{sub 4}Ge{sub 3}O{sub 12}-BGO) thin films were investigated in terms of their perception to gamma radiation exposure. An Edwards E306A vacuum thermal coating system was used for thin films deposition. BGO films with a thickness of 200 nm were exposed to a disk-type {sup 137}Cs gamma radiation source with an activity of 370 kBq. Optical properties of the films were investigated using CARY IE UV-Visible Spectrophotometer. Calculated optical band gap for as-deposited BGO thin film was 1.95 eV. Gamma radiation induced changes in the optical properties of thin films, which could be explained by the variation in the degree of disorder. From the density-of-state model, it is known that optical band gap decreases with an increasing degree of disorder of the amorphous phase. Electrical properties of BGO thin films were recorded in real time using a low power capacitive interface system with a high resolution, which is based on Delta-sigma modulator. At doses from 0 to 1.5 mGy little if any changes in the capacitance were measured. This could be explained by co-existence of two processes, namely creation and annihilation of defects under the influence of radiation. After a threshold dose of 1.5 mGy creation of defects becomes more prevailing and the BGO film capacitance has gradually increased in value from 2.97 pF to 7.09 pF after irradiation with a 2.44 mGy dose.

  10. The Influence of the RF PACVD MS Process Parameters on the Physicochemical Properties of Hydroxyapatite Coatings

    Directory of Open Access Journals (Sweden)

    Niedzielska A.

    2015-12-01

    Full Text Available Hydroksyapatite (HAp as the coating, is produced using different methods of deposition, among others: laser ablation method, sol-gel, electrophoresis, thermal sputtering or magnetron spraying with the usage of high frequency. Attempts to benefit from such a wide spectrum of existing methods are related to the fact that this material possesses many advantages. We have to distinguish, among others, proper biological properties, i.e. both - high bio-tolerance and high osteo-inductivity [1,2]. However, it is worth mentioning that the material also presents disadvantages, i.e. it indicates too quick resorption within the biological environment, depending on its obtained form. In case when HAp is in the amorphous form, it undergoes a very rapid process of dissolving in the tissue environment. [3] In order to prevent the above, it is important to produce the coatings with a regulative level of cristallinity. In the presented research the hydroxyapatite coating produced using RF PACVD MS plasma method (Radio Frequency Plasma Assisted Chemical Vapor Deposition Magnetron Sputtering possesses the above mentioned amorphous form. Nevertheless, due to the usage of ‘bubbler’, allowing for delivery of hydroxyl groups into the operating chamber, it was possible to receive the Hap coatings in a crystalline form. Changing the operating pressure (the amount of bonds - OH, during sputtering, it was checked what is the influence of that parameter on the physicochemical properties of obtained coatings. Scanning electron microscopy (SEM was used for the founding research as well as the Roentgen Apparatus Analyser (EDS. The Phase composition of a created coating was researched using the Roentgen diffract-meter (XRD. The measures of thickness were conducted using contact-profilometry. Nano-indentation technique was used to assess the mechanical properties. Obtained results of research encourage for further researches related to the influence of hydroxyl groups on the

  11. Influence of nanomechanical crystal properties on the comminution process of particulate solids in spiral jet mills.

    Science.gov (United States)

    Zügner, Sascha; Marquardt, Karin; Zimmermann, Ingfried

    2006-02-01

    Elastic-plastic properties of single crystals are supposed to influence the size reduction process of bulk materials during jet milling. According to Pahl [M.H. Pahl, Zerkleinerungstechnik 2. Auflage. Fachbuchverlag, Leipzig (1993)] and H. Rumpf: [Prinzipien der Prallzerkleinerung und ihre Anwendung bei der Strahlmahlung. Chem. Ing. Tech., 3(1960) 129-135.] fracture toughness, maximum strain or work of fracture for example are strongly dependent on mechanical parameters like hardness (H) and young's modulus of elasticity (E). In addition the dwell time of particles in a spiral jet mill proved to correlate with the hardness of the feed material [F. Rief: Ph. D. Thesis, University of Würzburg (2001)]. Therefore 'near-surface' properties have a direct influence on the effectiveness of the comminution process. The mean particle diameter as well as the size distribution of the ground product may vary significantly with the nanomechanical response of the material. Thus accurate measurement of crystals' hardness and modulus is essential to determine the ideal operational micronisation conditions of the spiral jet mill. The recently developed nanoindentation technique is applied to examine subsurface properties of pharmaceutical bulk materials, namely calcite, sodium ascorbate, lactose and sodium chloride. Pressing a small sized tip into the material while continuously recording load and displacement, characteristic diagrams are derived. The mathematical evaluation of the force-displacement-data allows for calculation of the hardness and the elastic modulus of the investigated material at penetration depths between 50-300 nm. Grinding experiments performed with a modified spiral jet mill (Type Fryma JMRS 80) indicate the strong impact of the elastic-plastic properties of a given substance on its breaking behaviour. The fineness of milled products produced at constant grinding conditions but with different crystalline powders varies significantly as it is dependent on the

  12. From "fills" to filter : insights into the reuse of dewatered alum sludge as a filter media in a constructed wetland

    OpenAIRE

    Babatunde, A.O.; Y. Q. ZHAO; Yang, Y.; Kearney, P

    2007-01-01

    Dewatered alum sludge, a by-product of drinking water treatment plants, hitherto consigned to landfills was used to develop a novel bio-filter in form of a constructed wetland. Performance results have demonstrated the benefits of the alum sludge cakes in a lab-scale system in enhancing phosphorus (P) removal from an animal farm wastewater. Although P and organic matter were concurrently removed in the system, there was a probable “one off” release of organics from the system, and this coinci...

  13. POC-scale testing of an advanced fine coal dewatering equipment/technique. Quarterly technical progress report 2, January 1995--March 1995

    Energy Technology Data Exchange (ETDEWEB)

    Groppo, J.G.; Parekh, B.K.

    1995-05-05

    Froth flotation technique is an effective and efficient process for recovering of ultra-fine (minus 74 {mu}m) clean coal. Economical dewatering of an ultra-fine clean coal product to a 20 percent level moisture will be an important step in successful implementation of the advanced cleaning processes. This project is a step in the Department of Energy`s program to show that ultra-clean coal could be effectively dewatered to 20 percent or lower moisture using either conventional or advanced dewatering techniques. The cost-sharing contract effort is for 36 months beginning September 30, 1994. This report discusses technical progress made during the quarter from January 1 to March 31, 1995.

  14. On construction points deep well dewatering project of foundation pit%基坑深井降水工程施工要点

    Institute of Scientific and Technical Information of China (English)

    李冬

    2015-01-01

    介绍了深井降水的概念,对深井降水设计及施工前应注意的问题进行了详细说明,并对施工时降水井施工、抽水施工、土方开挖等技术作了简要阐述,提出了一些深井降水关键控制点,以确保工程的顺利进行。%The paper introduces the concept of deep well dewatering project,indicates some precautions for deep well dewatering project,illus-trates some techniques including dewatering well project,pumping construction,and earthwork excavation,and points out its key controlling points,so as to ensure its smooth construction.

  15. How contamination sources and soil properties can influence the Cd and Pb bioavailability to snails.

    Science.gov (United States)

    Pauget, Benjamin; Gimbert, Frédéric; Coeurdassier, Mickael; Druart, Coline; Crini, Nadia; de Vaufleury, Annette

    2016-02-01

    To better understand the fate of metals in the environment, numerous parameters must be studied, such as the soil properties and the different sources of contamination for the organisms. Among bioindicators of soil quality, the garden snail (Cantareus aspersus) integrates multiple sources (e.g. soil, plant) and routes (e.g. digestive, cutaneous) of contamination. However, the contribution of each source on metal bioavailability and how soil properties influence these contributions have never been studied when considering the dynamic process of bioavailability. Using accumulation kinetics, this study showed that the main assimilation source of Cd was lettuce (68%), whereas the main source of Pb was the soil (90%). The plant contribution increased in response to a 2-unit soil pH decrease. Unexpectedly, an increase in the soil contribution to metal assimilation accompanied an increase in the organic matter (OM) content of the soil. For both metals, no significant excretion and influence of source on excretion have been modelled either during exposure or depuration. This study highlights how the contribution of different sources to metal bioavailability changes based on changes in soil parameters, such as pH and OM, and the complexity of the processes that modulate metal bioavailability.

  16. Aberration influence and active compensation on laser mode properties for asymmetric folded resonators

    Science.gov (United States)

    Zhang, Xiang; Hu, Zhiqiu; Yang, Wentao; Su, Likun

    2017-09-01

    We demonstrate the influence on mode features with introducing typical intracavity perturbation and results of aberrated wavefront compensation in a folded-type unstable resonator used in high energy lasers. The mode properties and aberration coefficient with intracavity misalignment are achieved by iterative calculation and Zernike polynomial fitting. Experimental results for the relation of intracavity maladjustment and mode characteristics are further obtained in terms of S-H detection and model wavefront reconstruction. It indicates that intracavity phase perturbation has significant influence on out coupling beam properties, and the uniform and symmetry of the mode is rapidly disrupted even by a slight misalignment of the resonator mirrors. Meanwhile, the far-field beam patterns will obviously degrade with increasing the distance between the convex mirror and the phase perturbation position even if the equivalent disturbation is inputted into such the resonator. The closed-loop device for compensating intracavity low order aberration is successfully fabricated. Moreover, Zernike defocus aberration is also effectively controlled by precisely adjusting resonator length, and the beam quality is noticeably improved.

  17. Influence of different ions doping on the antibacterial properties of MgO nanopowders

    Energy Technology Data Exchange (ETDEWEB)

    Rao, Yuanyuan; Wang, Wei, E-mail: weiwang@hust.edu.cn; Tan, Fatang; Cai, Yuncheng; Lu, Junwen; Qiao, Xueliang

    2013-11-01

    Compared with other inorganic antibacterial agents, magnesium oxide (MgO) nanopowders exhibit a unique antibacterial mechanism and various advantages in applications, having attracted extensive attention. In this study, MgO nanopowders doped with different ions (Li{sup +}, Zn{sup 2+} and Ti{sup 4+}) were synthesized by a sol–gel method, respectively. The structures and morphologies of the as-obtained precursors and nanopowders were characterized and confirmed by X-ray diffraction (XRD), transmission electron microscope (TEM) and X-ray photoelectron spectroscopy (XPS) analysis. The influence of three metal ions doping on the antibacterial properties of MgO nanopowders was also investigated by their bactericidal activity against Escherichia coli (E. coli, ATCC 25922) using the broth microdilution method and the agar method. The results show that Li-doped MgO exhibits better antibacterial activity, Zn-doped and Ti-doped MgO display poorer antibacterial activity than pure MgO. It can be concluded that the influence of different ions doping on the antibacterial properties of MgO mainly lies on oxygen vacancies and basicity of nanopowders.

  18. Influence of annealing atmosphere on optical properties of Al-doped ZnO powders

    Energy Technology Data Exchange (ETDEWEB)

    Li, Chundong; Lv, Jinpeng; Zhou, Bo; Liang, Zhiqiang [Key Laboratory on Materials Behaviour and Evaluation Technology in Space Environment, School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150001 (China)

    2012-08-15

    We systematically studied the influences of annealing atmosphere on the structural and optical properties of Al-doped ZnO (AZO) powders by performing anneals in N{sub 2}, Ar{sub 2}, H{sub 2} and O{sub 2} atmospheres. The results indicated that the optical properties were highly influenced by the annealing atmosphere, which were more pronounced for the AZO powders annealed in forming gas and an oxygen atmosphere. The E{sub 1} (LO) vibration mode in the Raman spectra exhibits a good correlation with the green emission and is demonstrated to be originated from V{sub O} defects. We conclude that both V{sub O} and O{sub i} defects give rise to the green photoluminescence in ZnO, and each will play a dominant role in oxygen-deficient and oxygen-rich environments, respectively. (Copyright copyright 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  19. The influence of surface properties on uptake of oil into complex coacervate microcapsules.

    Science.gov (United States)

    Rabiskova, M; Song, J; Opawale, F O; Burgess, D J

    1994-08-01

    A range of surfactants with different hydrophile-lipophile balance (HLB) values was selected to investigate the influence of interfacial properties on the uptake of oil droplets into complex coacervate microcapsules. The well characterized gelatin/acacia complex coacervate system was used in this study and the encapsulation of squalane, and oleic acid was investigated. The surfactants investigated were Span 85, Span 80, Span 40, egg yolk lecithin, and Tween 80. Combinations of surfactants were utilized to obtain intermediate HLB values. The percentage oil encapsulated was determined gravimetrically, based on the initial concentration and the amount extracted from the microcapsules. The aqueous interfacial tension values of the oils and oil/surfactant systems were measured using the Wilhelmy plate method. The interfacial properties were correlated to the percentage oil uptake by the coacervate phase. The relative hydrophobicity/lipophilicity of the oil influenced its uptake by complex coacervate droplets. The presence of surfactant affected oil uptake, depending on the HLB value of the surfactant or surfactant mixture. Uptake of squalane by the gelatin/acacia coacervates was found to be optimized by the addition of surfactants with HLB values in the range 2.5-6. The percentage uptake of oil decreased rapidly for systems prepared containing surfactants with HLB values outside this range. No correlation was observed between oil uptake by the coacervate phase and the interfacial tension of the oil and oil/surfactant systems with double-distilled deionized water.

  20. Influence of different ions doping on the antibacterial properties of MgO nanopowders

    Science.gov (United States)

    Rao, Yuanyuan; Wang, Wei; Tan, Fatang; Cai, Yuncheng; Lu, Junwen; Qiao, Xueliang

    2013-11-01

    Compared with other inorganic antibacterial agents, magnesium oxide (MgO) nanopowders exhibit a unique antibacterial mechanism and various advantages in applications, having attracted extensive attention. In this study, MgO nanopowders doped with different ions (Li+, Zn2+ and Ti4+) were synthesized by a sol-gel method, respectively. The structures and morphologies of the as-obtained precursors and nanopowders were characterized and confirmed by X-ray diffraction (XRD), transmission electron microscope (TEM) and X-ray photoelectron spectroscopy (XPS) analysis. The influence of three metal ions doping on the antibacterial properties of MgO nanopowders was also investigated by their bactericidal activity against Escherichia coli (E. coli, ATCC 25922) using the broth microdilution method and the agar method. The results show that Li-doped MgO exhibits better antibacterial activity, Zn-doped and Ti-doped MgO display poorer antibacterial activity than pure MgO. It can be concluded that the influence of different ions doping on the antibacterial properties of MgO mainly lies on oxygen vacancies and basicity of nanopowders.

  1. The Influence of Nanofillers on the Mechanical Properties of Carbon Fibre Reinforced Methyl Methacrylate Composite

    Directory of Open Access Journals (Sweden)

    Tomas ŽUKAS

    2012-09-01

    Full Text Available The influence of different types of nanofillers – carbon nanotubes (CNT and organically modified nanoclay – on the flexural properties and nail penetration resistance of carbon fiber reinforced methyl methacrylate (MMA composite have been investigated. An ultrasonic mixing was used to distribute various content of nanofillers (0.7 wt.% – 3.0 wt.% in MMA resin. Scanning electron microscopy and X-ray diffraction analyses confirmed formation of intercalated MMA clay nanocomposites. Two different stacking sequences, [0/90]3 or [0/90/45]2, and two types of carbon fibre, with or without epoxy binder, were used for composites preparation. The composites with stacking sequence of [0/90]3 show higher resistance to the mechanical loading. Epoxy binder increases fibre adhesion interaction with MMA resin, however, almost does not influences on the fibre reinforced composite strength properties. The results demonstrated that only low content (up to 1 wt.% of organically modified nanoclay Cloisite 10A increases the carbon fibre reinforced composites resistance to flexure and nail penetration. The low content of CNT also increases flexural stress and modulus, but decreases resistance to the nail penetration.DOI: http://dx.doi.org/10.5755/j01.ms.18.3.2434

  2. Does the contact time of alginate with plaster cast influence its properties?

    Directory of Open Access Journals (Sweden)

    Mariana Marquezan

    2012-06-01

    Full Text Available The aim of this study was to verify the influence of the time of contact between alginate and gypsum after the modeling procedure on the properties of the plaster cast, such as surface detail, dimensional stability and microhardness. Thirty cylindrical specimens of orthodontic gypsum Type III were made by means of impressions of a stainless steel master model which had five reference lines in the upper surface. The samples were divided into two groups: Group 1 (G1 - with time of contact of 1 hour; and Group 2 (G2 - 12 hours of contact. All the specimens were stored up to 48 hours until they underwent laboratory testing. Surface detail and dimensional stability were tested by one calibrated examiner using a visual analysis and a profilometer (Profile Projector Nikon model 6C, Nikon Corporation, Tokyo, Japan, respectively, to evaluate the quality of reproduction of the lines and the distances between them. The microhardness was determined for each sample by making six indentations with a Vickers diamond pyramid indenter (Buehler, Lake Bluff, USA under a load of 100 gF for 15 s. The results showed significant difference (P £ 0.05 between groups in two of the three properties examined: surface detail and microhardness, which decreased as the time of contact rose. The 12-hour time of contact between alginate and the plaster cast is not recommended because it influences the quality of the plaster cast.

  3. Does the contact time of alginate with plaster cast influence its properties?

    Directory of Open Access Journals (Sweden)

    Mariana Marquezan

    Full Text Available The aim of this study was to verify the influence of the time of contact between alginate and gypsum after the modeling procedure on the properties of the plaster cast, such as surface detail, dimensional stability and microhardness. Thirty cylindrical specimens of orthodontic gypsum Type III were made by means of impressions of a stainless steel master model which had five reference lines in the upper surface. The samples were divided into two groups: Group 1 (G1 - with time of contact of 1 hour; and Group 2 (G2 - 12 hours of contact. All the specimens were stored up to 48 hours until they underwent laboratory testing. Surface detail and dimensional stability were tested by one calibrated examiner using a visual analysis and a profilometer (Profile Projector Nikon model 6C, Nikon Corporation, Tokyo, Japan, respectively, to evaluate the quality of reproduction of the lines and the distances between them. The microhardness was determined for each sample by making six indentations with a Vickers diamond pyramid indenter (Buehler, Lake Bluff, USA under a load of 100 gF for 15 s. The results showed significant difference (P £ 0.05 between groups in two of the three properties examined: surface detail and microhardness, which decreased as the time of contact rose. The 12-hour time of contact between alginate and the plaster cast is not recommended because it influences the quality of the plaster cast.

  4. Dynamic Properties of Footbridges: Influence of Asphalt Pavement and Support Conditions

    Directory of Open Access Journals (Sweden)

    Weber Benedikt

    2015-01-01

    Full Text Available Natural frequencies and damping ratios are important parameters in the design of footbridges against vibrations. Although not normally considered in calculations, non-structural elements such as the asphalt pavement and the supports can have a significant influence on the dynamic properties. In this article we present results from vibration tests conducted on four footbridges over the last few years covering a wide range of asphalt temperatures. The experiments show that both the natural frequencies and the damping ratios can change significantly with temperature. In one particular case, a variation in natural frequency of 25% has been observed between high and low asphalt temperatures. An additional damping of around 1% due to the asphalt pavement has been detected. To more clearly understand the experimental results, the bridges were also analysed numerically using a visco-elastic material for the asphalt. The analysis of the experimental results also revealed that other non-structural elements can have a large influence on dynamic properties of bridges. In two cases, the supports did not perform as expected and lead to surprising results.

  5. The influence of substrate temperature on the tribo- mechanical properties of chromium nitride thin films

    Science.gov (United States)

    Merie, V. V.; Negrea, G.; Modi, E.

    2016-08-01

    Different nitrides such as titanium nitride, chromium nitride and so on are used in a widespread range of applications such as cutting tools, medical implants, and microelectromechanical devices and all that due to their mechanical, physical and chemical properties. The aim of this study is to obtain chromium nitride thin films and to characterize them by atomic force microscopy investigations. The chromium nitride thin films were deposited by reactive magnetron sputtering on silicon substrates. During the deposition process, the discharge current, the argon and nitrogen flows, the pressure inside the chamber and the deposition time were kept constant. A chromium target with a purity of 99.95 % was used. Some of the films were deposited after a chromium buffer layer was previously deposited on the silicon substrate. The deposition was carried out when substrate temperature was at room temperature, at 300 and 500°C respectively. Once the films were deposited, atomic force microscopy investigations were performed in order to emphasize the influence of the substrate temperature on the topographical, mechanical and tribological characteristics. The results pointed out an important influence of the substrate temperature on topographical, mechanical and tribological properties of the investigated chromium nitride thin films.

  6. Orientation of the magnetization easy axes of interacting nanoparticles: Influence on the hyperthermia properties

    Energy Technology Data Exchange (ETDEWEB)

    Conde-Leborán, Iván, E-mail: ivan.conde@usc.es [Departamento de Física Aplicada, Universidade de Santiago de Compostela, E-15782 Campus Sur s/n, Santiago de Compostela (Spain); Instituto de Investigacións Tecnolóxicas, Universidade de Santiago de Compostela, E-15782 Campus Sur s/n, Santiago de Compostela (Spain); Serantes, David [Instituto de Ciencia de Materiales de Madrid, CSIC, E-28049 Cantoblanco, Madrid (Spain); Baldomir, Daniel [Departamento de Física Aplicada, Universidade de Santiago de Compostela, E-15782 Campus Sur s/n, Santiago de Compostela (Spain); Instituto de Investigacións Tecnolóxicas, Universidade de Santiago de Compostela, E-15782 Campus Sur s/n, Santiago de Compostela (Spain)

    2015-04-15

    The relative orientation between anisotropy easy axes of magnetization of magnetic nanoparticles (MNPs) and the applied magnetic field direction determines their heating properties and thus needs to be considered for accurate heating applications. In this work we systematically study the heating properties of a system of interacting MNPs with ferromagnetic-like behavior (i.e. in the blocked state), randomly distributed in space, as a function of the degree of collinearity of their easy anisotropy axes along the magnetic field direction. The easy-axes of the particles were distributed at random within cones of different aperture angles (0, 10, 22.5 and 45 degrees with respect to the field direction), under different conditions of magnetic field amplitude and interparticle interactions. Our results show that easy-axes collinearity marks a clear threshold for heat dissipation at low interacting conditions, but increasing interactions tends to attenuate this effect. - Highlights: • Heating is strongly influenced by easy-axes collinearity and field direction. • Easy-axes collinearity marks a threshold for heat dissipation at low interaction. • Increasing interactions attenuates this influence.

  7. Influence of Synthetic Fibers Angle Orientation on Bending Properties of Composite Plywood

    Directory of Open Access Journals (Sweden)

    Mladen Brezović

    2010-12-01

    Full Text Available This paper presents the results of research on carbon fiber angle orientation and quantity of carbon fi bers in yarn on bending properties of plywood. For that purpose the specimens have been defined as multilayer composites made from carbon fibers and veneer. Carbon fibers were inserted in the second and third glue line of the composite with angle variation of 15°. Stresses and strain were analyzed in significant layers together with displacement of the whole composite plate. The influence of carbon fiber angle orientation on properties of the composite (amount of stresses and related strains was significant. The best results have been achieved with carbon fiber angle of 0°, and bidirectional carbon fiber type (BCF with the orientation angle of 90°. The lowest values have been achieved with carbon fiber angle of 65° (unidirectional carbon fibers-UCF, and bidirectional carbon fiber type (BCF with the orientation angle of 45°. Greater quantity of carbon fibers per one yarn has positive influence on decrease of stresses and strains in veneer layers and provides better stiffness of plywood.

  8. The Influence of Normal Load and Sliding Speed on Frictional Properties of Skin

    Institute of Scientific and Technical Information of China (English)

    Wei Tang; Shi-rong Ge; Hua Zhu; Xi-chuan Cao; Ning Li

    2008-01-01

    The study of frictional properties of human skin is important for medical research, skin care products and textile exploitation. In order to investigate the influence of normal load and sliding speed on the frictional properties of skin and its possible mechanism, tests were carried out on a multi-specimen friction tester. When the normal load increases from 0.1 N to 0.9 N,normal displacement and the friction coefficient of skin increase. The friction coefficient is dependent on the load, indicating that both adhesion and deformation contribute to the friction behaviour. The deformation friction was interpreted using the plough model of fiiction. When sliding speed increases from 0.5 mm·s-1 to 4 mm·s-1,the friction coefficient increases and "stick-slip" phenomena increase, indicating that hysteretic friction contributes to the friction. The hysteretic friction was interpreted using schematic of energy translation during the rigid spherical probe sliding on the soft skin surface, which provides an explanation for the influence of the sliding speed on the frictional characteristics of the skin.

  9. Influence of Fluorination on the Conformational Properties and Hydrogen-Bond Acidity of Benzyl Alcohol Derivatives

    Science.gov (United States)

    Bogdan, Elena; Compain, Guillaume; Mtashobya, Lewis; Le Questel, Jean-Yves; Besseau, François; Galland, Nicolas; Linclau, Bruno; Graton, Jérôme

    2015-01-01

    The effect of fluorination on the conformational and hydrogen-bond (HB)-donating properties of a series of benzyl alcohols has been investigated experimentally by IR spectroscopy and theoretically with quantum chemical methods (ab initio (MP2) and DFT (MPWB1K)). It was found that o-fluorination generally resulted in an increase in the HB acidity of the hydroxyl group, whereas a decrease was observed upon o,o′-difluorination. Computational analysis showed that the conformational landscapes of the title compounds are strongly influenced by the presence of o-fluorine atoms. Intramolecular interaction descriptors based on AIM, NCI and NBO analyses reveal that, in addition to an intramolecular OH⋅⋅⋅F interaction, secondary CH⋅⋅⋅F and/or CH⋅⋅⋅O interactions also occur, contributing to the stabilisation of the various conformations, and influencing the overall HB properties of the alcohol group. The benzyl alcohol HB-donating capacity trends are properly described by an electrostatic potential based descriptor calculated at the MPWB1K/6-31+G(d,p) level of theory, provided solvation effects are taken into account for these flexible HB donors. PMID:26130594

  10. Influence of Rare Earth Elements on Luminescent Properties of Y2SiO5:Tb

    Institute of Scientific and Technical Information of China (English)

    Jiao Huan; Liao Fuhui; Zhou Jingjing; Jing Xiping

    2005-01-01

    Photoluminescent(PL) and cathodoluminescent(CL) properties of rare earths (Sc3+, La3+, Gd3+ and Lu3+) doped (Y0.97Tb0.03)2SiO5 were studied. Rare earth doping clearly influences PL and CL properties of Y2SiO5:Tb. For La3+ doped system, PL intensity increases nearly 10% at x=0.05 whereas for Lu3+ doped system, the intensity increases about 20% at x=0.20. Gd3+ doping and Sc3+ doping reduce the intensity; at x=0.3, it is reduced about 30% for Gd3+ doped system and about 15% for Sc3+ doped system, respectively. Quenching concentration of activator became higher in rare earth doped samples, which may be understood by that the rare earth dopants might dilute the concentration of the activator. Additionally, doping also influences the color saturation of Y2SiO5:Tb. Sc3+, La3+, and Gd3+ doping improve the color saturation, whereas Lu3+ doping decreases the color saturation. CL measurements show that CL intensity increases for all rare earths doped systems. The energy transfer from Gd3+ to Tb3+ was discussed.

  11. Preparation of thiomer microparticles and in vitro evaluation of parameters influencing their mucoadhesive properties.

    Science.gov (United States)

    Albrecht, K; Zirm, E J; Palmberger, T F; Schlocker, W; Bernkop-Schnürch, A

    2006-01-01

    It was the aim of this study to develop mucoadhesive microparticulate delivery systems based on thiomers and to investigate parameters influencing their mucoadhesive properties. Microparticles were prepared via coazervation of thiolated or unmodified polycarbophil with fluorescein-diacetate as marker. The protective effect of the polymers toward enzymatic hydrolysis by intestinal enzymes was investigated. Mucoadhesion studies with microparticles, applied in dry and prehydrated form, were performed by ascertaining their residence time on intestinal mucosa. Furthermore, the influence of the amount of thiol groups on mucoadhesion was studied in vitro. Results showed that in comparison to unmodified polycarbophil, thiolated polycarbophil provided a more than 3-fold higher protective effect for the incorporated marker fluorescein-diacetate toward hydrolysis. When being applied in dry form 23.4 +/- 4.8% of the fluorescence marker being embedded in thiomer microparticles remained adhering to the intestinal mucosa within 3 h. In contrast, only 11.6 +/- 2.0% of the marker remained on the mucosa, when the thiomer microparticles were applied in prehydrated form. In addition, tests performed to assess the impact of the amount of thiol groups pointed out that a high amount of thiol groups is advantageous in order to further improve mucoadhesive properties. This knowledge should contribute to the design of highly efficient drug delivery systems being based on thiomer microparticles.

  12. Influence of temperature-dependent material properties on heat transfer in the turbulent flow over a flat plate

    Science.gov (United States)

    Wehle, F.; Brandt, F.

    The influence of temperature dependence of material properties on heat transfer in a turbulent plate boundary layer is investigated using differential equations for the velocity and temperature fields of even, steady, and compressible boundary layer flows. The results are compared with the well-known material property correction factors of Zhukauskas (1966), Sieder and Tate (1936), and Hufschmidt and Bruck (1968).

  13. Influence of Mn on the tensile properties of SSM-HPDC Al-Cu-Mg-Ag alloy A201

    CSIR Research Space (South Africa)

    Müller, H

    2011-03-01

    Full Text Available be obtained through the addition of transition elements, but care must be taken as other elements might have adverse effects on the mechanical properties. The objective of this study is to determine the influence of Mn on the tensile properties of rheo...

  14. Influence of Water Absorption on Volume Resistivity and the Dielectric Properties of Neat Epoxy Material

    KAUST Repository

    Sulaimani, Anwar Ali

    2014-07-15

    Influence of Water Absorption on the Dielectric Properties and Volume Resistivity of Neat Epoxy Material Anwar Ali Sulaimani Epoxy resins are widely used materials in the industry as electrical insulators, adhesives and in aircrafts structural components because of their high mechanical sti ness, strength and high temperature and chemical resistance properties. But still, the in uence of water uptake due to moisture adsorption is not fully understood as it detrimentally modi es the electrical and chemical properties of the material. Here, we investigate the in uence of water moisture uptake on the neat epoxy material by monitoring the change in the volume resistivity and dielectric properties of epoxy material at three di erent thickness con gurations: 0.250 mm, 0.50 mm and 1 mm thicknesses. Gravimetric analysis was done to monitor the mass uptake behaviour, Volume Resistivity was measured to monitor the change in conductivity of the material, and the dielectric properties were mapped to characterise the type of water mechanism available within the material during two ageing processes of sorption and desorption. Two-stage behaviours of di usion and reaction have been identi ed by the mass uptake analysis. Moreover, the plot of volume resistivity versus mass uptake has indi- cated a non-uniform relationship between the two quantities. However, the analysis of the dielectric spectrum at medium range of frequency and time has showed a change 5 in the dipolar activities and also showed the extent to which the water molecules can be segregated between bounding to the resin or existing as free water.

  15. Influence of semi-volatile aerosol on physical and optical properties of aerosol in Kathmandu valley

    Science.gov (United States)

    Shrestha, Sujan; Praveen, Ps; Adhikary, Bhupesh; Shrestha, Kundan; Panday, Arnico

    2016-04-01

    A field study was conducted in the urban atmosphere of Kathmandu valley to study the influence of the semi-volatile aerosol fraction on physical and optical properties of aerosols. The study was carried out during the 2015 pre-monsoon period. Experimental setup consisted of air from an ambient air inlet being split to two sets of identical sampling instruments. The first instrument received the ambient sample directly, while the second instrument received the air sample through a thermodenuder (TDD). Four sets of experiments were conducted to understand aerosol number, size distribution, scattering and absorption properties using Condensation Particle Counter (CPC), Scanning Mobility Particle Sizer (SMPS), Aethalometer (AE33) and Nephelometer. The influence of semi-volatile aerosols was calculated from the fraction of particles evaporated in the TDD at set temparetures: room temperature, 50°C, 100°C, 150°C, 200°C, 250°C and 300°C. Results show that, with increasing temperature, the evaporated fraction of semi-volatile aerosol also increased. At room temperature the fraction of semi-volatile aerosols was 12% while at 300°C it was as high as to 49%. Aerosol size distribution analysis shows that with an increase in TDD temperature from 50°C to 300°C, peak mobility diameter of particles shifted from around 60nm to 40nm. However we found little change in effective diameter of aerosol size distribution with increase in set TDD temperature. The change in size of aerosols due to loss of semi-volatile component has a stronger influence (~70%) in higher size bins when compared to at lower size bins (~20%). Studies using the AE33 showed that absorption by black carbon (BC) is amplified due to influence of semi-volatile aerosols by upto 37% at 880nm wavelength. Similarly nephelometer measurements showed that upto 71% of total scattering was found to be contributed by semi-volatile aerosol fraction. The scattering Angstrom Exponent (SAE) of semi-volatile aerosol

  16. Influence of the ytterbium doping technique on the luminescent properties of ZnSe single crystals

    Energy Technology Data Exchange (ETDEWEB)

    Radevici, Ivan, E-mail: ivarad@utu.fi [Wihuri Physical Laboratory, Department of Physics and Astronomy, University of Turku, FI-20014 Turku (Finland); Faculty of Physics and Engineering, Moldova State University, 60 A. Mateevici str., MD-2009 Chisinau, Republic of Moldova (Moldova, Republic of); Sushkevich, Konstantin [Faculty of Physics and Engineering, Moldova State University, 60 A. Mateevici str., MD-2009 Chisinau, Republic of Moldova (Moldova, Republic of); Huhtinen, Hannu [Wihuri Physical Laboratory, Department of Physics and Astronomy, University of Turku, FI-20014 Turku (Finland); Nedeoglo, Dmitrii [Faculty of Physics and Engineering, Moldova State University, 60 A. Mateevici str., MD-2009 Chisinau, Republic of Moldova (Moldova, Republic of); Paturi, Petriina [Wihuri Physical Laboratory, Department of Physics and Astronomy, University of Turku, FI-20014 Turku (Finland)

    2015-02-15

    Luminescent properties of the ytterbium doped zinc selenide crystals with 0.00–8.00 at % concentrations of the Yb impurity within the temperature interval from 6 K to 300 K were studied. Ytterbium doping was performed within three technological processes: during the growth by chemical vapor transport method and by thermal diffusion from the Bi+Yb or Zn+Yb melt. The influence of ytterbium impurity concentration on spectral position and intensity of the various photoluminescent bands in ZnSe emission spectra in visible and infrared range is analyzed. A tendency of ytterbium ions to form associates with background defects was demonstrated. A strong dependence between ytterbium influence on the zinc selenide emission spectra and concentration of selenium vacancies was shown. - Highlights: • Co-doping of ZnSe crystals with Yb and Bi or I impurities was studied. • Influence of Yb concentration on ZnSe emission spectra in visible and infrared range was analyzed. • Tendency of Yb to form associates with background defects was discussed. • Impact of V{sub Se} on formation of Yb-based emission centers was demonstrated.

  17. The influence of the addition of polymers on the physico-chemical properties of bentonite suspensions

    Directory of Open Access Journals (Sweden)

    Stojiljkovic S.

    2014-01-01

    Full Text Available Bentonite clays have many applications in industries ranging from construction to cosmetics. Addition of polymers can profoundly influence the properties of bentonite suspensions and we now describe the influence of a range of different polymers. Whereas polyvinyl pyrolidone and soy isolate only slightly influenced the pH and the electrical conductivity of bentonite polymers in suspension, Carbopol solution caused decreases in both pH and electrical conductivity. As expected, strong electrolytes like sodium chloride caused big changes in the electrical conductivity of the suspensions. When the temperature of the bentonite suspensions was increased, the pH was almost unchanged, but the electrical conductivity increased. Bentonite treated with polymer suspensions can be used in purifying polluted water; for example, our results suggest that high pH caused by phosphorous salts can be addressed using bentonite modified with Carbopol. [Projekat Ministarstva nauke Republike Srbije: Stanisa Stojiljkovic, Vojkan Miljkovic, Goran Nikolic, Ivana Savic and Ivan Savic, TR 34020, Danijela Kostic 172047 and Biljana Arsic 174007

  18. Retention and Mobility of Copper and Lead in Soils as Influenced by Soil Horizon Properties

    Institute of Scientific and Technical Information of China (English)

    B. CERQUEIRA; E. F. COVELO; M. L. ANDRADE; F. A. VEGA

    2011-01-01

    The mobility and bioavailability of heavy metals in soils is largely governed by sorption and desorption phenomena.Cu2+ and Pb2+ are among the most potentially toxic heavy metals and they are present,often concomitantly,in many polluting spills and in agrochemicals.The objective was to assess and compare the competitive sorption and desorption capacities and sorption hysteresis of Cu2+ and Pb2+,as well as their migration through the profiles of four natural soils:a Humic Umbrisol,an Umbric Cambisol,an Endoleptic Luvisol and a Humic Cambisol.In all horizons Pb2+ was invariably sorbed and retained to a greater extent than Cu2+.The sorption and retention of Cu2+ were most influenced by pH,effective cation exchange capacity (CECe) and Mn oxide content.On the other hand,the fixation capacity of Pb2+ was most influenced by pH,CECe,and Mn oxide and organic matter contents.pH and CECe were the individual soil properties most markedly influencing Cu2+ and Pb2+ sorption and retention.In all the horizons Pb2+ exhibited greater hysteresis than Cu2+.In each soil the hysteresis in the A horizon was greater than that in the B horizon,except in the Bt horizon of the Endoleptic Luvisol,due to its high pH and vermiculite content.Based on migration indices,Pb2+ was less mobile than Cu2+ in the studied soils.

  19. The influence of orientation on the stress rupture properties of nickel-base superalloy single crystals

    Science.gov (United States)

    Mackay, Rebecca A.; Maier, Ralph D.

    1982-10-01

    The influence of orientation on the stress rapture properties of MAR-M247 single crystals was studied. Stress rupture tests were performed at 724 MPa and 774 °C where the effect of anisotropy is prominent. The mechanical behavior of the single crystals was rationalized on the basis of the Schmid factors for the operative slip systems and the lattice rotations which the crystals underwent during deformation. The stress rupture lives at 774 °C were found to be greatly influenced by the lattice rotations required to produce intersecting slip, because second-stage creep does not begin until after the onset of intersecting slip. Crystals which required large rotations to become oriented for intersecting slip exhibited a large primary creep strain, a large effective stress level at the onset of steady-state creep, and consequently, a short stress rupture life. Those crystals having orientations within about 25° of the [001] exhibited significantly longer lives when their orientations were closer to the [001]-[011] boundary of the stereographic triangle than to the [001]-[1l 1] boundary, because they required smaller rotations to produce intersecting slip and the onset of second-stage creep. Thus, the direction off the [001], as well as the number of degrees off the [001], has a major influence on the stress rapture lives of single crystals in this temperature regime.

  20. Influence of manufacturing processes on cell surface properties of probiotic strain Lactobacillus rhamnosus Lcr35®.

    Science.gov (United States)

    Nivoliez, Adrien; Veisseire, Philippe; Alaterre, Elina; Dausset, Caroline; Baptiste, Fabrice; Camarès, Olivier; Paquet-Gachinat, Marylise; Bonnet, Muriel; Forestier, Christiane; Bornes, Stéphanie

    2015-01-01

    The influence of the industrial process on the properties of probiotics, administered as complex manufactured products, has been poorly investigated. In the present study, we comparatively assessed the cell wall characteristics of the probiotic strain Lactobacillus rhamnosus Lcr35® together with three of its commercial formulations with intestinal applications. Putative secreted and transmembrane-protein-encoding genes were initially searched in silico in the genome of L. rhamnosus Lcr35®. A total of 369 candidate genes were identified which expressions were followed using a custom Lactobacillus DNA chip. Among them, 60 or 67 genes had their expression either upregulated or downregulated in the Lcr Restituo® packet or capsule formulations, compared to the native Lcr35® strain. Moreover, our data showed that the probiotic formulations (Lcr Lenio®, Lcr restituo® capsule and packet) showed a better capacity to adhere to intestinal epithelial Caco-2 cells than the native Lcr35® strain. Microbial (MATS) tests showed that the probiotic was an electron donor and that they were more hydrophilic than the native strain. The enhanced adhesion capacity of the active pharmaceutical ingredients (APIs) to epithelial Caco-2 cells and their antipathogen effect could be due to this greater surface hydrophilic character. These findings suggest that the manufacturing process influences the protein composition and the chemical properties of the cell wall. It is therefore likely that the antipathogen effect of the formulation is modulated by the industrial process. Screening of the manufactured products' properties would therefore represent an essential step in evaluating the effects of probiotic strains.

  1. THE INFLUENCE OF THE COMPLEX CHEMICAL ADDITIVE CONTAINING THE STRUCTURED CARBON NANOMATERIAL ON PROPERTIES OF CEMENT

    Directory of Open Access Journals (Sweden)

    O. Yu. Sheyda

    2015-01-01

    Full Text Available The paper presents results of investigations on influence of domestic complex chemical additive containing structured carbon nanomaterial and characterized by a combination effect (curing acceleration and plasticizing on cement and cement stone properties. The purpose of the investigations, on the one hand, has been to confirm efficacy of УКД-1additive from the perspective for increasing the rate of gain, strength growth of cement concrete and additive influence on setting time with the purpose to preserve molding properties of concrete mixes in time, and on the other hand, that is to assess “mechanism” of the УКД-1 additive action in the cement concrete. The research results have revealed regularities in changes due to the additive of water requirements and time period of the cement setting. The reqularities are considered as a pre-requisite for relevant changes in molding properties of the concrete mixes. The paper also experimentally substantiates the possibility to decrease temperature of cement concrete heating with the УДК-1 additive. It has been done with the purpose to save energy resources under production conditions. In addition to this the paper proves the efficiency of the additive which is expressed in strength increase of cement stone up to 20–40 % in the rated age (28 days that is considered as a basis for strength growth of cement concrete. The paper confirms a hypothesis on physical nature of this phenomenon because the X-ray phase analysis method has shown that there are no changes in morphology of portland cement hydration products under the action of the additive agent containing a structured carbon nanomaterial. Results of theoretical and experimental investigations on УКД-1 additive efficiency have been proved by industrial approbation while fabricating precast concrete products and construction of monolithic structures under plant industrial conditions (Minsk, SS “Stroyprogress” JSC MAPID and on

  2. Influence of fermentation conditions on the surface properties and adhesion of Lactobacillus rhamnosus GG

    Directory of Open Access Journals (Sweden)

    Deepika Gurjot

    2012-08-01

    Full Text Available Abstract Background The surface properties of probiotic bacteria influence to a large extent their interactions within the gut ecosystem. There is limited amount of information on the effect of the production process on the surface properties of probiotic lactobacilli in relation to the mechanisms of their adhesion to the gastrointestinal mucosa. The aim of this work was to investigate the effect of the fermentation pH and temperature on the surface properties and adhesion ability to Caco-2 cells of the probiotic strain Lactobacillus rhamnosus GG. Results The cells were grown at pH 5, 5.5, 6 (temperature 37°C and at pH 6.5 (temperature 25°C, 30°C and 37°C, and their surfaces analysed by X-ray photoelectron spectrometry (XPS, Fourier transform infrared spectroscopy (FT-IR and gel-based proteomics. The results indicated that for all the fermentation conditions, with the exception of pH 5, a higher nitrogen to carbon ratio and a lower phosphate content was observed at the surface of the bacteria, which resulted in a lower surface hydrophobicity and reduced adhesion levels to Caco-2 cells as compared to the control fermentation (pH 6.5, 37°C. A number of adhesive proteins, which have been suggested in previous published works to take part in the adhesion of bacteria to the human gastrointestinal tract, were identified by proteomic analysis, with no significant differences between samples however. Conclusions The temperature and the pH of the fermentation influenced the surface composition, hydrophobicity and the levels of adhesion of L. rhamnosus GG to Caco-2 cells. It was deduced from the data that a protein rich surface reduced the adhesion ability of the cells.

  3. Influence of metallic vapours on thermodynamic and transport properties of two-temperature air plasma

    Science.gov (United States)

    Zhong, Linlin; Wang, Xiaohua; Cressault, Yann; Teulet, Philippe; Rong, Mingzhe

    2016-09-01

    The metallic vapours (i.e., copper, iron, and silver in this paper) resulting from walls and/or electrode surfaces can significantly affect the characteristics of air plasma. Different from the previous works assuming local thermodynamic equilibrium, this paper investigates the influence of metallic vapours on two-temperature (2 T) air plasma. The 2 T compositions of air contaminated by Cu, Fe, and Ag are first determined based on Saha's and Guldberg-Waage's laws. The thermodynamic properties (including mass density, specific enthalpy, and specific heat) are then calculated according to their definitions. After determining the collision integrals for each pair of species in air-metal mixtures using the newly published methods and source data, the transport coefficients (including electrical conductivity, viscosity, and thermal conductivity) are calculated for air-Cu, air-Fe, and air-Ag plasmas with different non-equilibrium degree θ (Te/Th). The influences of metallic contamination as well as non-equilibrium degree are discussed. It is found that copper, iron, and silver exist mainly in the form of Cu2, FeO, and AgO at low temperatures. Generally, the metallic vapours increase mass density at most temperatures, reduce the specific enthalpy and specific heat in the whole temperature range, and affect the transport properties remarkably from 5000 K to 20 000 K. The effect arising from the type of metals is little except for silver at certain temperatures. Besides, the departure from thermal equilibrium results in the delay of dissociation and ionization reactions, leading to the shift of thermodynamic and transport properties towards a higher temperature.

  4. Influences of different cobalt sources on the properties of synthesized LiCoO2

    Institute of Scientific and Technical Information of China (English)

    LIU Xing-Quan; HE Ze-Zhen; LI Shu-Hua

    2004-01-01

    Since 1991, LiCoO2 used as cathode material of lithium-ion rechargeable batteries has attracted much attention in the industry of portable power apparatus such as mobiles, laptops and camcorders, etc. However, the production technologies of LiCoO2 have always been possessed by the foreign corporations. Although a plenty of research work has been performed in domestics, it is almost impossible to surpass the technological rampart, which renders our state to subject to much foreign exchange consumption.Many preparation methods such as solid state reaction, sol-gel process and hydrothermal synthesis et al have been reported in the literature. Via our studies, it is found that in the process of LiCoO2 synthesis not only lithium sources but also cobalt sources can play an important part in the physical and electrochemical properties, and also have a remarkable influence on the properties of LiCoO2.But as for the different synthesis methods, the necessary cobalt source is different, and as for the same synthesis method, the LiCoO2 prepared with different cobalt sources has different electrochemical performance.So far, the detailed findings on the LiCoO2 cathode material synthesized with various cobalt sources have not been reported yet in the literature. In this paper, the following work has been carried out.The LiCoO2 cathode material was synthesized by liquid-phase soft-chemistry process and solid state reaction at higher temperature with different cobalt sources respectively, and characterized by XRD, BET, SEM, TEM, laser particle size distribution and electrochemical testing. Its properties were compared. The effects of different cobalt sources, aqueous ammonia and ethanol additives on the physical and electrochemical properties of LiCoO2 cathode materials were investigated. The results have demonstrated that the different cobalt sources, aqueous ammonia and ethanol additives have remarkable influences on the physical and electrochemical properties of LiCoO2 cathode

  5. Influence of yarn folding on UV protection properties of hemp knitted fabrics

    Directory of Open Access Journals (Sweden)

    Kocić Ana A.

    2016-01-01

    Full Text Available In the last years the media have highlighted the damage of the ozone layer and the resulting increase of ultraviolet radiation (UVR reaching the earth’s surface. Prolonged and repeated, both occupational and recreational, sun exposure of the population causes some detrimental effects. Clothing is considered to be one of the most important tools for UV protection. It is generally accepted that synthetic fibres provide a high UV protection capability of textiles, while cellulose fibres (cotton, linen, hemp, viscose have a low UV absorption capacity. However, natural pigments, pectin and waxes in natural cellulose fibers, and lignin in hemp fibers, act as UV absorbers having a favorable effect on UPF of grey-state fabrics. Bearing in mind the trend of reintroduction of hemp fibers as a source of eco-friendly textiles, there is a serious lack of study about the potential of hemp materials in terms of UV protection. Folded yarn is a complex yarn composed of two or more component yarns arranged parallel and twisted together to make a “new quality” yarn. Folding of yarns is an operation undertaken in order to modify single-yarn properties to an appreciable degree. There are very few investigations concerning the relationship between the yarn properties and UV protection effectiveness of the fabric made there from. In addition, there is no any result in the scientific literature about the influence of yarn folding on UV protection properties of textile materials. Having this in mind, for our research the idea was to evaluate the effect of yarn folding in this regard. The plain knitted fabrics composed of single or two-folded hemp yarn were compared in terms of UV protection properties. The Ultraviolet Protection Factor (UPF, as the quantitative measurement of the material effectiveness to protect the human skin against UVR, was determined for the textile materials by in vitro test method according to the European standard EN 13758. The knitted

  6. Influence of skin tissue properties on the radial reference point for glucose measurement

    Science.gov (United States)

    Yang, Yue; Xu, Kexin; Ding, Lijun; Shi, Zhenzhi; Chen, Wenliang

    2009-02-01

    A reference position where the diffuse reflectance light intensity is insensitive to the variation of glucose concentration exists in the radial detection space for glucose measurement in the scattering medium such as skin. The signal measured in this position could be used as an inside reference to evaluate the influence on spectrum caused by other interferential factors. The relationship between the position of radial reference point and the skin tissue property is studied in this paper. Three-layer skin models with different optical parameters are designed to get sample sets at 1200~1700nm. In these sets, μa, μs and g of dermis varies respectively, so does the depth of epidermis or dermis. The distribution rule of dispersion of diffuse reflectance light intensity in the radial space is confirmed with the glucose concentration changes. And the distribution property of the radial reference position in every sample set is obtained through Monte Carlo simulation. The result shows that the distance of radial reference position from light source is insensitive to the variation of absorption coefficient or the depth of dermis, but an increased scattering coefficient will shorten the distance; an increased anisotropy coefficient or depth of epidermis will lengthen it. On the basis of that, the optical probes with different structures are designed according to the skin tissue properties. So they could be used for the measurement of corresponding patients, which enhances the practicability of floating reference method greatly.

  7. Influence of bress laminate volume fraction on electromechanical properties of externally laminated coated conductor tapes

    Energy Technology Data Exchange (ETDEWEB)

    Bautista, Zhierwinjay M.; Shin, Hyung Seop [Dept. of Mechanical Design Engineering, Andong National University, Andong (Korea, Republic of); Lee, Jae Hun; Lee, Hun Ju; Moon, Seung Hyun [SuNAM Co Ltd., Anseong (Korea, Republic of)

    2016-09-15

    The enhancement of mechanical properties of coated conductor (CC) tapes in practical application are usually achieved by reinforcing through lamination or electroplating metal layers on either sides of the CC tape. Mechanical or electromechanical properties of the CC tapes have been largely affected by the lamination structure under various loading modes such as tension, bending or even cyclic. In this study, the influence of brass laminate volume fraction on electromechanical properties of RCE-DR processed Gadolinium-barium-copper-oxide (GdBCO) CC tapes was investigated. The samples used were composed of single-side and both-side laminate of brass layer to the Cu-stabilized CC tape and their Ic behaviors were compared to those of the Cu-stabilized CC tape without external lamination. The stress/strain dependences of Ic in laminated CC tapes under uniaxial tension were analyzed and the irreversible stress/strain limits were determined. As a result, the increase of brass laminate volume fraction initially increased the irreversible strain limit and became gradual. The corresponding irreversible stress limit, however, showed no difference even though the brass laminate volume fraction increased to 3.4. But the irreversible load limit linearly increased with the brass laminate volume fraction.

  8. Influence of the Substrate Properties on the Offset Printing ink Colour Matching

    Directory of Open Access Journals (Sweden)

    Anne Blayo

    2003-07-01

    Full Text Available The printing industry has been using computerised ink colour matching for a long time. The problem of ink formulation is to match a given standard colour with only three or four inks from a basis of about twelve inks.This is generally achieved by calculations based on the well-known Kubelka-Munk turbid media theory, which gives excellent results in many industrial situations. However, some hypotheses are necessary to apply the Kubelka-Munk model and corrections to the measured reflectance are often required (Saunderson’s correction coefficients, for example.One limitation in the resolution of this method of formulation may arise from the fact that the characterisation of the basic inks is made on one standard substrate, which may differ a lot from the real printing substrate.The aim of this work is precisely to study the contribution of the substrate to the colour matching procedure. The properties of the substrate which intervene in the process are physical properties (thickness, absorbency… and optical properties (brightness and gloss. Five different papers were chosen to make the characterisations of the basic offset inks. The reflectance measurements were performed with spectrophotometer X-Rite with the D/0° geometry, specular excluded or included, coupled with a coloured matching software (X-Rite Inkmaster. A special emphasis was put on the influence on the calculation of the ink film thickness, estimated for the different substrates, and on the choice of the correction coefficients for the Kubelka-Munk theory.

  9. Influence of organic modification on the structure and properties of polyurethane/sepiolite nanocomposites

    Energy Technology Data Exchange (ETDEWEB)

    Chen Hongxiang, E-mail: chenhx_916@hotmail.com [Hubei Key Laboratory of Coal Conversion and New Carbon Material, College of Chemical Engineering and Technology, Wuhan University of Science and Technology, 947 Heping Road, 430081 Wuhan, Hubei (China); Zeng Danlin [Hubei Key Laboratory of Coal Conversion and New Carbon Material, College of Chemical Engineering and Technology, Wuhan University of Science and Technology, 947 Heping Road, 430081 Wuhan, Hubei (China); Xiao Xiaoqin [College of Machinery and Automation, Wuhan University of Science and Technology, 430081 Wuhan (China); Zheng Maosheng [Institute of Condensed Physics and Materials, Northwest University, 710069 Xi' an (China); Ke Changmei; Li Yanjun [Hubei Key Laboratory of Coal Conversion and New Carbon Material, College of Chemical Engineering and Technology, Wuhan University of Science and Technology, 947 Heping Road, 430081 Wuhan, Hubei (China)

    2011-01-25

    Research highlights: {yields} KH550 was the best among the three organic modifiers by comparing tensile properties, water resistance and swelling rate. {yields} FTIR revealed the strong interaction between KH550-Sp and the PU matrix. {yields} TEM revealed the compatibility of KH550-Sp and PU was improved. {yields} SEM confirmed the good dispersion of KH550-Sp in PU matrix. - Abstract: The polyurethane (PU) nanocomposites were prepared using organomodified sepiolite (organo-Sp) by in situ polymerization method. The clay was modified with three different organic modifiers such as {gamma}-aminopropyltriethoxylsilane (KH550), hexadecyltrimethylammonium bromide (CTAB) and lauric acid (LA). The morphology and the dispersion of organo-Sp in polyurethane were characterized by scanning electron microscope, transmission electron microscope and Fourier transform infrared spectroscopy. The influence of organo-Sp on the tensile properties, water resistance and swelling rate of polyurethane composites was studied. The results showed the properties and structure of polyurethane nanocomposites were related to the kind of organic modifier.

  10. The Influence of Dimensional Effects on the Composition and Properties of Polydicarbonfluoride.

    Science.gov (United States)

    Makotchenko, Victor G; Pinakov, Dmitry V; Logvinenko, Vladimir A

    2015-08-01

    The influence of dimensional effects on the compositions and properties of polydicarbonfluoride (C2 F)n prepared from multilayered graphenes was investigated. Multilayered graphenes were produced by destructive thermal decomposition of intercalation compounds of "idealized" (C2 F)n that were obtained by reaction of gaseous ClF3 with natural graphite at a room temperature. The precursors of multilayered graphenes have a common formula (C2 F⋅xR)n where R is an organic or inorganic component. It was shown that polydicarbonfluoride prepared from multilayered graphene does not form stable intercalation compound with ClF3 , in contrast to polydicarbonfluoride prepared from graphite, that forms its intercalation compound with ClF3 during fluorination of initial graphite in the ClF3 excess. Investigations of polydicarbonfluoride prepared from multilayered graphene showed that it cannot form intercalation compounds with different classes of organic and inorganic compounds as polydicarbonfluoride prepared from graphite can do. The absence of such intercalation activity for polydicarbonfluoride prepared from multilayered graphene can be explained by high exfoliation degree of multilayered graphene (3-4 nm) along the c-axis that results in the presence of two-dimensional (2D) structure properties in multilayered graphene. Dimensional effects transformed the chemical properties of polydicarbonfluoride prepared from multilayered graphene and lowered its decomposition temperature by 150 K in comparison with polydicarbonfluoride prepared from graphite.

  11. Influence of sulfur in fuel on the properties of diffusion flame soot

    Science.gov (United States)

    Zhao, Yan; Ma, Qingxin; Liu, Yongchun; He, Hong

    2016-10-01

    Previous studies indicate that sulfur in fuel affects the hygroscopicity of soot. However, the issue of the effect of sulfur in fuel on soot properties is not fully understood. Here, the properties of soot prepared from fuel with a variable sulfur content were investigated under lean and rich flame conditions. Lean flame soot was influenced more by sulfur in fuel than rich flame soot. The majority of sulfur in fuel in lean flame was converted to gaseous SO2, while a small fraction appeared as sulfate and bisulfate (referred to as sulfate species) in soot. As the sulfur content in fuel increased, sulfate species in lean flame soot increased nonlinearly, while sulfate species on the surface of lean flame soot increased linearly. The hygroscopicity of lean flame soot from sulfur-containing fuel was enhanced mainly due to sulfate species. Meanwhile, more alkynes were formed in lean flame. The diameter of primary lean flame soot particles increased and accumulation mode particle number concentrations of lean flame soot from sulfur-containing fuel increased as a result of more alkynes. Because the potential effects of soot particles on air pollution development greatly depend on the soot properties, which are related to both chemical aging and combustion conditions, this work will aid in understanding the impacts of soot on air quality and climate.

  12. Influence of defects on electrical properties of electrodeposited co-doped ZnO nanocoatings

    Science.gov (United States)

    Simimol, A.; Anappara, Aji A.; Barshilia, Harish C.

    2017-01-01

    We present a systematic investigation of the electrical properties of undoped and Co-doped ZnO nanostructures at room temperature as an extensive study of the role of defects in ZnO. The ZnO nanostructures were fabricated by the electrodeposition method at low bath temperature (80 °C) and the Co concentration was varied from 0.01 to 0.2 mM. Electrical properties of the undoped and Co-doped ZnO nanostructures were studied in detail. The carrier concentration increases while the mobility reduces with increase in Co-concentration. The resistivity increases with an increase in Co-concentration and the reason is correlated with the defects in ZnO. In order to understand more details of the role of defects in the present I-V characteristic behavior of the Co-doped ZnO, high temperature vacuum annealing of ZnO sample was carried out. Electrical, optical and magnetic properties of the high temperature vacuum annealed ZnO were studied in detail. Photoluminescence spectroscopy (PL) results revealed more information of the defect levels which act as scattering centers for the carriers. Co-doping as well as annealing at high temperature in vacuum environment tunes the defects in ZnO and which influence the optical, magnetic and electrical behavior of the ZnO nanostructures.

  13. Influence of the Viscoelastic Properties of the Polyimide Dielectric Coating on the Wafer Warpage

    Science.gov (United States)

    Zhu, Chunsheng; Ning, Wenguo; Xu, Gaowei; Luo, Le

    2014-09-01

    Polyimide is widely used as the dielectric material in wafer level packaging. One potential problem with its application is the warpage and stress generated in the curing process. This paper investigated the material properties of polyimide and its influence on the wafer warpage. The viscoelastic properties of polyimide film were measured and a mathematical model of the properties was developed. Finite element analysis of the wafer warpage was performed and this indicates that the viscoelastic material model gave the best prediction. To better understand the causation of the warpage, curvature evolution of the polyimide-coated silicon wafer during its curing process was measured by a multi-beam optical sensor system. It was found that the warpage was mainly induced by the coefficient of thermal expansion mismatch and that the cure shrinkage of polyimide had little effect. Additionally, the effect of the cooling rate on the wafer warpage was also studied. Both simulation and experiment results showed that a slower cooling rate in the temperature range around the glass transition temperature ( T g) of polyimide will help to reduce the final wafer warpage.

  14. Influence of Surface Transition Layers on Phase Transformation and Pyroelectric Properties of Ferroelectric Thin Film

    Institute of Scientific and Technical Information of China (English)

    SUN Pu-Nan; L(U) Tian-Quan; CHEN Hui; CAO Wen-Wu

    2008-01-01

    Taking into account surface transition layers (STLs), we study the phase transformation and pyroelectric properties of ferroelectric thin films by employing the transverse Ising model (TIM) in the framework of the mean field approximation. The distribution functions representing the intra-layer and inter-layer couplings between the two nearest neighbour pseudo-spins are introduced to characterize STLs. Compared with the results obtained by the traditional treatments for the thin films using only the single surface transition layer (SSL), it is shown that the STL model reflects a more realistic and comprehensive situation of films. The effects of various parameters on the phase transformation properties have shown that STL can make the Curie temperature of the film higher or lower than that of the corresponding bulk material, and the thickness of STL is a key factor influencing the film properties. For a film with definite thickness, there exists a critical STL thickness at which ferroelectricity will disappear when the intra-layer and inter-layer interactions are weak.

  15. Influence of Parameters of Screen Printing on Photoluminescence Properties of Nanophotonic Labels for Smart Packaging

    Directory of Open Access Journals (Sweden)

    Olha Hrytsenko

    2017-01-01

    Full Text Available Smart packaging is becoming more popular on world market as a new type of packaging able to react to changes in a packaged product during storage and informs a customer about the safety of consumption of packaged food. This article investigates the main technological issues of the use of nanophotonic printing inks based on ZnO/SiO2 nanoparticles and polyvinylpyrrolidone (PVP for printing active elements of smart packaging on paper substrates, concerning material properties and parameters of screen printing. It is determined that the use of ink compositions with medium content of ZnO/SiO2 nanoparticles allows obtaining blue-green and blue shades of luminescence color of screen printed images by changing ink layer thickness on papers with different contents of optical brightness agents (OBAs. The minimum content of ZnO/SiO2 nanoparticles in the developed fluorescent inks leads to blue luminescence colors regardless the contents of OBAs of the papers and ink layer thickness. The luminescence intensity is directly proportional to ink layer thickness and partly depends on the content of OBAs in the selected paper. In order to fabricate nanophotonic elements of smart packaging with predetermined photoluminescence properties, the influence of investigated factors on photoluminescence properties of printed nanophotonic labels should be taken into account.

  16. The influence of modification on structural, textural and adsorption properties of bentonite

    Directory of Open Access Journals (Sweden)

    Jović-Jovičić Nataša R.

    2008-01-01

    Full Text Available Natural bentonite clay from the Bogovina locality in Serbia was Na-exchanged and modified using hexadecyll-trimethylammonium bromide as surfactant and organobentonite was obtained. The influence of modifications on the structural, textural and sorption properties of bentonite was investigated. It was estimated that modifications solely replace exchangeable cations in smectite layers, whereas other admixture minerals (quartz, calcite, feldspar in bentonite remain unaffected. According to X-ray results the modification lead to changes in the smectite structure by either decreasing, for Na-bentonite, or increasing, for organobentonite, the interplanar spacing, JQOI- The appearance of three new bands in IR spectra of HDTMA-bentonite comparing to those of raw and Na-bentonite assigned to the methylene vibrations confirmed the embedding of aliphatic cations into smectite structure. In organobentonite a significant change in textural properties was observed. In particular, specific surface area dramatically decreased while originally meso and microporous material became almost completely non-porous. Despite almost insignificant specific surface area the synthesized organobentonite due to gained organophyllity of its surface exhibits exquisite adsorption properties toward investigated textile dyes having adsorption capacity approx. 2 times higher than activated carbon.

  17. Research Update: Mechanical properties of metal-organic frameworks – Influence of structure and chemical bonding

    Directory of Open Access Journals (Sweden)

    Wei Li

    2014-12-01

    Full Text Available Metal-organic frameworks (MOFs, a young family of functional materials, have been attracting considerable attention from the chemistry, materials science, and physics communities. In the light of their potential applications in industry and technology, the fundamental mechanical properties of MOFs, which are of critical importance for manufacturing, processing, and performance, need to be addressed and understood. It has been widely accepted that the framework topology, which describes the overall connectivity pattern of the MOF building units, is of vital importance for the mechanical properties. However, recent advances in the area of MOF mechanics reveal that chemistry plays a major role as well. From the viewpoint of materials science, a deep understanding of the influence of chemical effects on MOF mechanics is not only highly desirable for the development of novel functional materials with targeted mechanical response, but also for a better understanding of important properties such as structural flexibility and framework breathing. The present work discusses the intrinsic connection between chemical effects and the mechanical behavior of MOFs through a number of prototypical examples.

  18. Influence of Doping Concentration on Dielectric, Optical, and Morphological Properties of PMMA Thin Films

    Directory of Open Access Journals (Sweden)

    Lyly Nyl Ismail

    2012-01-01

    Full Text Available PMMA thin films were deposited by sol gel spin coating method on ITO substrates. Toluene was used as the solvent to dissolve the PMMA powder. The PMMA concentration was varied from 30 ~ 120 mg. The dielectric properties were measured at frequency of 0 ~ 100 kHz. The dielectric permittivity was in the range of 7.3 to 7.5 which decreased as the PMMA concentration increased. The dielectric loss is in the range of 0.01 ~ –0.01. All samples show dielectric characteristics which have dielectric loss is less than 0.05. The optical properties for thin films were measured at room temperature across 200 ~ 1000 nm wavelength region. All samples are highly transparent. The energy band gaps are in the range of 3.6 eV to 3.9 eV when the PMMA concentration increased. The morphologies of the samples show that all samples are uniform and the surface roughness increased as the concentration increased. From this study, it is known that, the dielectric, optical, and morphology properties were influenced by the amount of PMMA concentration in the solution.

  19. INFLUENCE OF TORREFACTION ON SOME CHEMICAL AND ENERGY PROPERTIES OF MARITIME PINE AND PEDUNCULATE OAK

    Directory of Open Access Journals (Sweden)

    Floran Pierre

    2011-04-01

    Full Text Available This study investigated the influence of heat treatment on the chemical composition and energy properties of maritime pine (Pinus pinaster and pedunculate oak (Quercus robur. Samples were treated in a new experimental device at 220, 250, or 280 °C for 1 or 5 hours. Chemical and energy analyses were performed using standard methods. Our results clearly demonstrated an increased degradation of the material due to the combined effects of temperature and treatment duration. This mass loss was basically due to degradation of acid-soluble materials. The energy analysis showed that the fixed carbon content and higher heating value increased, for both species, whereas the volatile matter content decreased with increased extent of treatment (cumulated effects of temperature and time. In the range of temperature and duration studied here, the dimensionless energy properties for both species obeyed the same functions of overall mass loss. The relationships obtained allow quantification of the increase in wood energy concentration due to torrefaction. Mass loss is an excellent indicator of treatment extent. Analytical expressions allowing the prediction of energy and chemical properties as a function of overall mass loss, within the range of treatment extents studied here, are provided.

  20. Statistical analysis of the factors that influenced the mechanical properties improvement of cassava starch films

    Science.gov (United States)

    Monteiro, Mayra; Oliveira, Victor; Santos, Francisco; Barros Neto, Eduardo; Silva, Karyn; Silva, Rayane; Henrique, João; Chibério, Abimaelle

    2017-08-01

    In order to obtain cassava starch films with improved mechanical properties in relation to the synthetic polymer in the packaging production, a complete factorial design 23 was carried out in order to investigate which factor significantly influences the tensile strength of the biofilm. The factors to be investigated were cassava starch, glycerol and modified clay contents. Modified bentonite clay was used as a filling material of the biofilm. Glycerol was the plasticizer used to thermoplastify cassava starch. The factorial analysis suggested a regression model capable of predicting the optimal mechanical property of the cassava starch film from the maximization of the tensile strength. The reliability of the regression model was tested by the correlation established with the experimental data through the following statistical analyse: Pareto graph. The modified clay was the factor of greater statistical significance on the observed response variable, being the factor that contributed most to the improvement of the mechanical property of the starch film. The factorial experiments showed that the interaction of glycerol with both modified clay and cassava starch was significant for the reduction of biofilm ductility. Modified clay and cassava starch contributed to the maximization of biofilm ductility, while glycerol contributed to the minimization.