WorldWideScience

Sample records for industrial residues pt

  1. Industrial processes of olefin metathesis. Pt. 1

    Energy Technology Data Exchange (ETDEWEB)

    Warwel, S.

    1987-05-01

    Olefin metathesis opens new synthetic routes to typical petrochemicals (ethylene, propylene, n-butenes), special olefins (neohexene, higher molecular linear olefins, , -dienes) and unsaturated polymers (polynorbornene, -cyclooctene, -dicyclopentadiene) in an industrial scale. The 8 metathesis processes used in industry and further possible applications of olefin metathesis are reviewed.

  2. Heat pumps in industry. Pt. 2: Applications

    Energy Technology Data Exchange (ETDEWEB)

    Lazzarin, R.M. [Padova Univ., Vicenza (Italy). Ist. di Ingegneria Gestionale

    1995-04-01

    A selection of applications of heat pumps in industry is described, reporting plant lay-outs and performances. The selection includes compression heat pumps at different temperatures, vapour recompression systems, absorption heat pumps and heat transformers. (author)

  3. Handling of wet residues in industry

    DEFF Research Database (Denmark)

    Villanueva, Alejandro

    In countries with high prices of fresh water use and wastewater discharge, water recycling has become an alternative to traditional water consumption and discharge for industries with water-based processes. Industrial water recycling means in many cases that water has to be treated and cleaned......, to remove from it the substances which presence impedes reusing the water. These substances accumulate in a by-product called wet residue. An integral part of water recycling projects in the industry is the handling and disposal of the wet residues generated. The treatment, utilisation and disposal of wet...... residues depend totally on the industrial sector of origin and the composition of the water to be recycled. Treatment is more problematic in some cases than in others, but in all water recycling applications it is an issue of concern. The present study addresses this concern by providing a package...

  4. Heat pumps in industry: Pt. 1; Equipment

    Energy Technology Data Exchange (ETDEWEB)

    Lazzarin, R.M. (Padua Univ. (Italy). Ist. di Ingegneria Gestionale)

    1994-11-01

    Industrial heat pumps are reviewed, classifying them according to the way by which the working fluid is taken from the lower to the higher pressure: mechanical or thermal. Each group is further subdivided in closed and open cycle. The most recent technological developments are considered for each classification. (author)

  5. Management of industrial solid residues; Gerenciamento de residuos solidos industriais

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2002-07-01

    This chapter gives an overview on the management of industrial solid wastes, approaching the following subjects: classification of industrial solid residues; directives and methodologies for the management of industrial solid residues; instruments for the management of industrial solid residues; handling, packing, storage and transportation; treatment of industrial solid residues; final disposal - landfill for industrial residues; the problem of treatment and final disposer of domestic garbage in Brazil; recycling of the lubricant oils used in brazil; legislation.

  6. PERANCANGAN PROGRAM APLIKASI PEMBELIAN PADA PT INDO TAICHEN TEXTILE INDUSTRY

    Directory of Open Access Journals (Sweden)

    Yakub Yakub

    2010-05-01

    Full Text Available PT Indo Taichen Textile Industry is a company in the textile industry producing cloth. Activities and operations personnel administration, payroll systems, purchasing systems, and inventory systems are conducted manually. Problems begin to become fairly complex on the company’s purchasing system so that a software application is required. Purchasing system is made by Data Flow Diagram (DFD as a model of the process or system and Entity Relation Diagram (ERD as a data model. The purchasing application is programmed using the programming language Visual Basic 6.0 and SQL Server database.Keywords: data base, purchasing, system, information system

  7. Vocational High School Cooperation with PT Astra Honda Motor to Prepare Skilled Labor in Industries

    Science.gov (United States)

    Yoto; Widiyanti

    2017-01-01

    SMK Nasional as a secondary vocational education institution contribute in creating skilled labor to meet the needs of the industry. Motorcycle Engineering expertise program at the SMK Nasional in improving the graduate's quality carries out industrial class education with PT Astra Honda Motor (PT AHM); it is intended so that there is a link and…

  8. NATURAL RADIONUCLIDES IN RESIDUES FROM NON-NUCLEAR INDUSTRIES

    Directory of Open Access Journals (Sweden)

    E. P. Lisachenko

    2009-01-01

    Full Text Available In the present overview we analyze the available data concerning residues from non-nuclear industries which contain naturally occurring radioactive material (NORM. We consider their quantity, radiation properties, placement, utilization, regulatory and management.

  9. Production, composition, and application of coffee and its industrial residues

    OpenAIRE

    Mussatto, Solange I.; Machado, Ercília M. S.; Martins, Silvia; Teixeira, J.A.

    2012-01-01

    Coffee is one of the most consumed beverages in the world and is the second largest traded commodity after petroleum. Due to the great demand of this product, large amounts of residues are generated in the coffee industry, which are toxic and represent serious environmental problems. Coffee silverskin and spent coffee grounds are the main coffee industry residues, obtained during the beans roasting, and the process to prepare “instant coffee”, respectively. Recently, some attempts have been m...

  10. Biotechnology for agro-industrial residues utilisation: utilisation of agro-residues

    National Research Council Canada - National Science Library

    Nigam, Poonam Singh; Pandey, Ashok

    2009-01-01

    ..., are now largely wastes whose disposal presents a continuing problem for the farmer. The agro-industrial residues consist of many and varied wastes from agriculture and food industry, which in total account for over 250 million tonnes of waste per year in the UK alone. The prospects and application of biotechnical principles facilitates these prob...

  11. Biogas systems for sisal and other agro-industrial residues

    Energy Technology Data Exchange (ETDEWEB)

    Jungersen, G. [Danish Technological Inst., Section for Biotechnology, Taastrup (Denmark)

    1997-12-31

    Most of the East-African agro-industries are generating very large quantities of organic residues from production and processing of different crops. In the East-African Region the most important of these crops are: Sisal, Sugar, Coffee, Cashew nuts and Pineapple. In other 3. world countries, Palm oil and Cassava (Tapioca starch) processing are main producers of organic waste products. Moreover, large quantities of organic residues are generated from other food processing activities like breweries, consumption of bananas etc. The following pages give examples of setups and system designs of anaerobic treatment systems for some of the residues mentioned above. When considering anaerobic treatment of sisal residues, which constitutes the main agro-industrial biomass resource in Tanzania, two major issues should be considered: Optimal reactor set-up and performance; And optionally, potential methods for pre-treatment of fibre fraction in order to increase the methane yield. The sisal liquid residues are degraded very fast and efficiently in UASB systems. At COD loading rates less than 11 kg COD/m{sup 3} x day, the reduction in organic matter is more than 90% and methane yields obtained are between 373 and 377 ml CH{sub 4}/g COD reduced. The treatment of sisal solid residues in CSTR systems has been examined both at mesophilic (37 deg. C) and thermophilic temperatures (55 deg. C.). (EG)

  12. THE INDUSTRIAL UTILIZATION OF CHEMICAL MODIFIED AGRICULTURAL RESIDUES

    Institute of Scientific and Technical Information of China (English)

    Feng Xu; Runcang Sun; Huaiyu Zhan

    2004-01-01

    Various lignocellulosic materials such as wood,agricultural and forest residues has the potential to be valuable substitute for, or complement to,commercial sorbents for removing heavy metal ions or dyes from waste water or spilled oil from inland water or sea. More than 9 million tons of straw pulp are produced annually in china, which account for about 90% of the world′s total straw pulp. However,huge quantity of remain straw is not used as industrial raw material and is burnt in the fields or on the side of road. These resources can be chemical modified such as acetylation. Modified straws have the characteristics of low cost, high capacity, quick uptake, and easy to desorb. This paper reviews the current status of the technology for modified agricultural residues, which focus on hemicellulose and cellulose. The potential of these natural sorbents in main industry is also indicated.

  13. THE INDUSTRIAL UTILIZATION OF CHEMICAL MODIFIED AGRICULTURAL RESIDUES

    Institute of Scientific and Technical Information of China (English)

    FengXu; RuncangSun; HuaiyuZhan

    2004-01-01

    Various lignocellulosic materials such as wood, agricultural and forest residues has the potential to be valuable substitute for, or complement to, commercial sorbents for removing heavy metal ions or dyes from waste water or spilled oil from inland water or sea. More than 9 million tons of straw pulp are produced annually in china, which account for about 90% of the world's total straw pulp. However, huge quantity of remain straw is not used as industrial raw material and is burnt in the fields or on the side of road. These resources can be chemical modified such as acetylation. Modified straws have the characteristics of low cost, high capacity, quick uptake, and easy to desorb. This paper reviews the current status of the technology for modified agricultural residues, which focus on hemicellulose and cellulose. The potential of these natural sorbents in main industry is also indicated.

  14. Pyrolysis kinetics and residue characteristics of petrochemical industrial sludge.

    Science.gov (United States)

    Chiang, H L; Lo, J C; Tsai, J H; Chang, G M

    2000-02-01

    This study investigated the pyrolysis characteristics of sludge from wastewater treatment plants in the petrochemical industry and focused on the pyrolysis kinetics, elemental composition of residue, and volatile organic compounds (VOCs) of exhaust gas. As pyrolysis temperature increased to 773 K, the increasing rate of crude oil production tended to a stable condition. The result indicated that the optimal temperature of crude oil and water mixed production was 773 K. When pyrolysis temperature increased from 673 to 973 K, carbon, oxygen, nitrogen, and hydrogen concentrations of residue decreased and the sulfur concentration of residue increased. The concentrations of benzene, toluene,ethylbenzene, and styrene increased by the increasing pyrolysis temperature. We found that the reaction order of sludge pyrolysis was 2.5 and the activation energy of the reaction was 11.06 kJ/mol. We believe that our pyrolysis system is transitional between devolatilization and combustion.

  15. PERANCANGAN E-SCM PADA PT SUPERPOLY INDUSTRY

    Directory of Open Access Journals (Sweden)

    Rudy Rudy

    2009-05-01

    Full Text Available Manufacturing companies always strives to improve performance, namely in production of goods in time, management of material supply to prevent out of stock by exchanging information with suppliers, and on time delivery of goods to distributors to meet customer satisfaction on manufactured products. The purpose of this study is to analyse the supply chain management and to design the electronic supply chain management (e-SCM on Superpoly Industry Company so it able to give accurate and reliable information also support the better supply chain acitivity for the company. The used research methods are preliminary steps (energize the organization, enterprise vision, supply chain value assessment, opportunity identification, and strategy decision for the analysis and for the design consist of supply chain management strategic, customer and service management, manufacturing and supply chain planning, supplier relationship management, logistics resource management, and architecting. The conclusion is the e-SCM application will make it easier for the distributor to order merchandise from the company because information channel is open, which is website and information flow between supplier, company, and distribution is getting better.Keywords: supply chain management, electronic supply chain management, company

  16. 75 FR 50771 - Draft Revised Guidance for Industry on Residual Solvents in New Veterinary Medicinal Products...

    Science.gov (United States)

    2010-08-17

    ... Industry on Residual Solvents in New Veterinary Medicinal Products, Active Substances and Excipients... comments of a draft revised guidance for industry ( 100) entitled ``Residual Solvents in New Veterinary... veterinary use by the International Cooperation on Harmonisation of Technical Requirements for...

  17. ANALISIS SISTEM PENGEMBANGAN KAWASAN INDUSTRI TERPADU BERWAWASAN LINGKUNGAN: STUDI KASUS DI PT. KAWASAN INDUSTRI MEDAN (Analysis System of Integrated Industrial Estate Ecodevelopment Case Study: At PT. Medan Industrial Estate

    Directory of Open Access Journals (Sweden)

    Kimberly Febrina Kodrat

    2011-07-01

    Full Text Available ABSTRAK Tujuan utama penelitian adalah menganalisis kinerja pengembangan kawasan industri terpadu berwawasan lingkungan. Cakupan aspek penelitian disinkronkan dengan konsep pembangunan berkelanjutan sekaligus dijadikan sebagai batasan kajian, yakni mempersekutukan aspek ekonomi, ekologi dan sosial. Data diperoleh dengan menggunakan metode survei melalui observasi, wawancara mendalam, dan pendapat pakar. Metodologi penelitian menggunakan metode survei dengan menggunakan perpaduan antara hard system (analisis sistem dinamis dan soft system (analisis prospektif. Dari hasil uji statistik chi square (α = 0,01 diperoleh bahwa kelompok masyarakat yang bekerja di dalam PT. KIM mempunyai hubungan yang sangat signifikan dengan kelompok masyarakat yang bekerja di luat PT. KIM terhadap tingkat pendapatan, tingkat pendidikan dan faktor usia. Berdasarkan hasil analisis kualitas limbah cair unit IPAL PT. KIM terdapat 5 parameter yang masih berada diatas nilai baku mutu KepMenLHNo.51/1997, yaitu: BOD, COD, TSS, klorida dan amoniak. Tingkat efisiensi pengolahan limbah cair unit IPAL PT. KIM rata-rata 53,07%. Hasil analisis ketergantungan antar faktor dengan menggunakan Analisis Prospektif diperoleh sebanyak 5 faktor strategis masa depan yang mempengaruhi pengembangan kawasan industri terpadu berwawasan lingkungan, yaitu: jumlah industri, permintaan lahan, kebijakan pemerintah, model pengembangan, dan iklim investasi yang kondusif. Pengembangan kawasan industri terpadu berwawasan lingkungan dapat dilakukan dengan strategi moderat dengan kebijakan mencakup jumlah industri bertambah secara bertahap dengan meningkatnya permintaan lahan serta kebijakan pemerintah yang memfasilitasi peningkatan modal pengembangan dan didukung oleh iklim investasi yang kondusif. ABSTRACT The main purpose of the research is to study environmental aspect of industrial estate development. The scope of the research aspects is synchronized with sustainable development concepts, namely

  18. Kompetisi Industri Transportasi: Tinjauan Komunikasi Pemasaran Jasa PT Kereta Api Indonesia

    Directory of Open Access Journals (Sweden)

    Prima Mulyasari Agustini

    2008-06-01

    Full Text Available The development of transportation industry has removed the train business from its monopolistic business. Sooner or later, the government will open up opportunity for private parties to participate in the train business. In order to successfully anticipate this future, PT Kereta Api Indonesia (KAI needs to change its communication strategy. Integrated Service Marketing Communication (ISMC was recommended as a strategic approach covering management of service promise, management of customer expectation, customer education improvement, and management of internal marketing communication.

  19. Penentuan Konversi CO Yang Menjadi Metanol Pada Metanol Reaktor Di PT. Kaltim Metanol Industri

    OpenAIRE

    Marduansyah, Muhammad

    2015-01-01

    Telah dilakukan penelitian tentang penentuan konversi CO yang menjadi metanol pada reaktor metanol, di PT. Kaltim Metanol Industri dimana dalam penelitian ini digunakan data laju alir dan komposisi gas yang didapat dari control room. Dari perhitungan yang dilakukan maka didapat hasil konversi CO pada tanggal 25 februari 2013 yaitu 74,93%. Selain itu juga didapat hasil data perhitungan yang sebelumnya telah dilakukan yaitu 61,21% pada 12 november 2012; 68,53% pada 13 april 2012; 66,89% pada 14...

  20. Pemeriksaan Operasional Terhadap Proses Produksi Pada Unit Usaha PT. Mutifa-Industri Farmasi Medan

    OpenAIRE

    Rambe, Silvana

    2010-01-01

    Pursuant clarification make research that the aim of to know whether the income information system that is run by PT Mutifa-industri farmasi medan The research kind winch to execute write is descriptive research, data a kind wich use is primary data and secondary data, techniques of kind by data collecting is writers are observation and interview and method analyze data is descriptive method, that is method analyze where data method collected, to be compiled, interperetation, analyzed, so th...

  1. Penentuan Konversi CO Yang Menjadi Metanol Pada Metanol Reaktor Di PT. Kaltim Metanol Industri

    OpenAIRE

    Marduansyah, Muhammad

    2015-01-01

    Telah dilakukan penelitian tentang penentuan konversi CO yang menjadi metanol pada reaktor metanol, di PT. Kaltim Metanol Industri dimana dalam penelitian ini digunakan data laju alir dan komposisi gas yang didapat dari control room. Dari perhitungan yang dilakukan maka didapat hasil konversi CO pada tanggal 25 februari 2013 yaitu 74,93%. Selain itu juga didapat hasil data perhitungan yang sebelumnya telah dilakukan yaitu 61,21% pada 12 november 2012; 68,53% pada 13 april 2012; 66,89% pada 14...

  2. FAKTOR-FAKTOR YANG BERHUBUNGAN DENGAN DERMATITIS KONTAK PADA PEKERJA DI PT INTI PANTJA PRESS INDUSTRI

    Directory of Open Access Journals (Sweden)

    Hari Suryo Utomo

    2007-12-01

    Full Text Available Factors Related to Contact Dermatitis on Workers at PT Inti Pantja Press Industri. PT Inti Pantja Press Industri (IPPI is an automotive manufacturing industry for car pressing body and car chassis. In the manufacturing process, its uses a variety of chemicals which may cause contact dermatitis for workers. There are other factors which may cause the contact dermatitis to workers worsen including indirect causes. The objective of this research is to investigate factors related to contact dermatitis in workers at PT IPPI. Research is conducted using a cross sectional design with quantitative approach which describe factors affecting the development of workers contact dermatitis. Research subjects are all the worker who uses chemicals during the work process (80 workers consists from 4 (four different sections: production (handwork, maintenance (plant service and die shop, quality control, and inventory finish part. Methodology used for data collection was using a questionnaire in which respondents were asked to fullfill a self-completion questionnaire. Results suggested that workers at PT IPPI experienced contact dermatitis are 39 workers (48,8%. There are 4 (four factors were investigated using chi-square test (95% level of confidence which are significantly related to contact dermatitis, including: type of work {p value 0,02, odds ratio 3,4 (1,305-8,641}; age {p value 0,042, odds ratio 2,8 (1,136-7,019}; working period {p value 0,014, odds ratio 3,5 (1,383-9,008}; history of dermatitis at previous workplace {p value 0,042, odds ratio 5,9 (1,176-29,103}. Factors which are not related to contact dermatitis are history of allergy, personal hygiene, and the use of PPE (Personal Protective Equipment.

  3. Long term stability and hysteresis effects in Pt100 sensors used in industry

    Science.gov (United States)

    Ljungblad, S.; Holmsten, M.; Josefson, L.-E.; Klevedal, B.

    2013-09-01

    A Pt100 sensor is under normal conditions a very accurate and stable sensor for temperature measurements. Two important factors that can have influence on the results are its drift during time and the hysteresis effect at temperature changes. Different types of Pt100 sensors will show varying sensitivity for these effects. This study includes a number of partially supported wire type Pt100 sensors mainly used as reference sensors at different industries and laboratories. For most of the sensors, there is a history of calibration data for several years. By using a dry block calibrator, the hysteresis effects of the sensors are measured in the temperature range 0 °C up to 500 °C, depending on the calibration range of the sensor. The suitability of the method is evaluated by measurements of the stability of the dry-block and the repeatability of hysteresis tests. The evaluation shows that it is possible to measure hysteresis effects above a few mK. The tested Pt100 sensors exhibits hysteresis effects of 20 mK peak-to-peak as most, which is in the same magnitude as the uncertainty of the calibration and also more significant than the annual drift. The best sensors showed a hysteresis of just a few mK.

  4. Effect of industrial residue combinations on availability of elements

    Energy Technology Data Exchange (ETDEWEB)

    Brännvall, Evelina, E-mail: evelina.brannvall@ltu.se [Waste Science and Technology, Luleå University of Technology, 97187 Luleå (Sweden); Zamora, Carles Belmonte [Waste Science and Technology, Luleå University of Technology, 97187 Luleå (Sweden); Sjöblom, Rolf [Waste Science and Technology, Luleå University of Technology, 97187 Luleå (Sweden); Tekedo AB, Spinnarvägen 10, 611 37 Nyköping (Sweden); Kumpiene, Jurate [Waste Science and Technology, Luleå University of Technology, 97187 Luleå (Sweden)

    2014-07-15

    Highlights: • Beneficial combination of fly ash and biosolids. • Nutrient availability increase. • Potentially toxic element availability decrease. • Measured element availability was differed from the calculated leaching potential. - Abstract: Industrial residues, such as fly ashes and biosolids, contain elements (e.g., N, P, K, S, Ca and Zn) that make them a viable alternative for synthetic fertilizers in forestry and agriculture. However, the use of these materials is often limited due to the presence of potentially toxic substances. It is therefore necessary to assess and, when warranted, modify the chemical and physical form of these and similar waste materials before any advantages are taken of their beneficial properties. Biofuel fly ash, municipal solid waste incineration (MSWI) fly ash, biosolids, peat, peat residues and gypsum board waste were combined in various proportions, and this resulted in increased leaching of N, P, S, Cu and Mn, but decreased leaching of Ca, K, Mg, Cr, Fe, Ni, Zn, Al, As and Pb. Chemical fractionation revealed that elements Ca, K, Mg, S and Mn were predominantly exchangeable, while the rest of the elements were less mobile. Cadmium was mostly exchangeable in MSWI fly ash, but less mobile in biofuel fly ash mixtures. Recycling of MSWI fly ash in the mixtures with fertilizers is considerably less attractive, due to the high levels of salts and exchangeable Cd.

  5. Stabilization of APC residues from waste incineration with ferrous sulfate on a semi-industrial scale

    DEFF Research Database (Denmark)

    Lundtorp, Kasper; Jensen, Dorthe Lærke; Christensen, Thomas Højlund

    2002-01-01

    A stabilization method for air pollution control (APC) residues from municipal solid waste incineration (MSWI) involving mixing of the residue with water and FeSO4 has been demonstrated on a semi-industrial scale on three types of APC residues: a semidy (SD) APC residue, a fly ash (FA), and an FA...

  6. Study of mortars with industrial residual plastic scales

    Directory of Open Access Journals (Sweden)

    Magariños, O. E.

    1998-06-01

    Full Text Available This work proposes the utilization of industrial residues of PET (Polyethylene Terephtalate as a partial substitute of arids (sand in mortar making for construction components. Therefore, the environmental impact of large volumes of plastic of urban residues could be decreased. When PET scales were added to mortars in partial replacement of sand, lower unitary weight, acceptable absorption and resistances according to international specifications were achieved. Mortars with 66% of sand replacement by scales and without any additive, showed optimal characteristics to be used in concret block manufacturing.

    Este trabajo de investigación se desarrolla a partir de la hipótesis de utilizar los desechos post-industriales de PET (Tereftalato de Polietileno como sustituto de áridos (arena, ingrediente de morteros, en la fabricación de componentes constructivos. En dicho trabajo se estudian las propiedades físico-químicas de distintos morteros en los que se reemplazó el contenido de árido por escamas de plástico en distintas proporciones. Se compararon y evaluaron las propiedades físico-mecánicas de los morteros en estudio con los convencionales mediante ensayos de resistencia a la flexión, compresión, absorción, durabilidad y microfotografías por barrido electrónico. Estos estudios determinaron que el agregado de PET en morteros puede ser usado como un posible sustituto de áridos, ya que se obtuvieron morteros con 66% de reemplazo de arena por escamas que presentaron menor peso unitario, absorción aceptable y resistencias acordes a las exigidas por normas.

  7. Solid residues from combustion plants. Pt. 1; Feste Rueckstaende aus Verbrennungsanlagen. T. 1

    Energy Technology Data Exchange (ETDEWEB)

    Reichenberger, H.P.; Quicker, P.; Mocker, M.; Faulstich, M. [ATZ Entwicklungszentrum, Sulzbach-Rosenberg (Germany); Gleis, M. [Umweltbundesamt, Dessau-Rosslau (Germany)

    2008-08-15

    The following publication deals with solid combustion residues, which results in Germany from the thermal treatment of municipal waste, coal, sewage sludge and biomass. The intention is, to give an overview about the current situation. The first part of the article shows the annual quantities of combustible substances thermal treated and which kind of residues and which quantities of residues are resulting from the thermal treatment. Furthermore the properties of different residues are observed and together compared. The second part describes the quantities of residues feeded to the relevant ways of recycling or disposal. References to orders and legislations are given. (orig.)

  8. Solid residues from combustion plants. Pt. 2; Feste Rueckstaende aus Verbrennungsanlagen. T. 2

    Energy Technology Data Exchange (ETDEWEB)

    Reichenberger, H.P.; Quicker, P.; Mocker, M.; Faulstich, M. [ATZ Entwicklungszentrum, Sulzbach-Rosenberg (Germany); Gleis, M. [Umweltbundesamt, Dessau-Rosslau (Germany)

    2008-09-15

    The following publication deals with solid combustion residues, which results in Germany from the thermal treatment of municipal waste, coal, sewage sludge and biomass. The intention is, to give an overview about the current situation. The first part of the article shows the annual quantities of combustible substances thermal treated and which kind of residues and which quantities of residues are resulting from the thermal treatment. Furthermore the properties of different residues are observed and together compared. The second part describes the quantities of residues feeded to the relevant ways of recycling or disposal. References to orders and legislations are given. (orig.)

  9. BUSINESS MODEL IN ELECTRICITY INDUSTRY USING BUSINESS MODEL CANVAS APPROACH; THE CASE OF PT. XYZ

    Directory of Open Access Journals (Sweden)

    Achmad Arief Wicaksono

    2017-01-01

    Full Text Available The magnitude of opportunities and project values of electricity system in Indonesia encourages PT. XYZ to develop its business in electrical sector which requires business development strategies. This study aims to identify company's business model using Business Model Canvas approach, formulate business development strategy alternatives, and determine the prioritized business development strategy which is appropriate to the manufacturing business model for PT. XYZ. This study utilized a descriptive approach and the nine elements of the Business Model Canvas. Alternative formulation and priority determination of the strategies were obtained by using Strengths, Weaknesses, Opportunities, Threats (SWOT analysis and pairwise comparison. The results of this study are the improvement of Business Model Canvas on the elements of key resources, key activities, key partners and customer segment. In terms of SWOT analysis on the nine elements of the Business Model Canvas for the first business development, the results show an expansion on the power plant construction project as the main contractor, an increase in sales in its core business in supporting equipment industry of oil and gas,  a development in the second business i.e. an investment in the electricity sector as an independent renewable emery-based power producer. On its first business development, PT. XYZ selected three Business Model Canvas elements which become the priorities of the company i.e. key resources weighing 0.252, key activities weighing 0.240, and key partners weighing 0.231. On its second business development, the company selected three elements to become their the priorities i.e. key partners weighing 0.225, customer segments weighing 0.217, and key resources weighing 0.215.Keywords: business model canvas, SWOT, pairwise comparison, business model

  10. Residual Stress and Fatigue Strength of Hybrid Laser-MIG-Welded A7N01P-T4

    Science.gov (United States)

    Wang, Qiuying; Chen, Hui; Qiu, Peixian; Zhu, Zongtao

    2017-02-01

    A7N01P-T4 aluminum alloy is widely used in some important welded components of high-speed trains. The hybrid laser-metal inert gas (MIG) welding process was studied to solve problems associated with the MIG welding process, such as low welding efficiency, high residual stress and deformation, and serious loss of strength. A high-speed camera, a voltage and current collection system, and NI DAQ were used to acquire arc profiles, welding voltage, and welding current simultaneously. Thermal cycle tests were carried out. Residual stresses induced by the welding process and fatigue strength of the joint were investigated. Large-size fatigue specimens were used in fatigue tests. The results show that the energy of the hybrid welding process is focused, and the power density of hybrid welding process is intense. The heat input per unit of the hybrid welding process is only half of that of the MIG welding process. Compared with the MIG welded joint, the overall residual stress level of the hybrid-welded joint is lower. The peak longitudinal stress of the hybrid-welded joint is reduced by 20 pct. The fatigue strength of hybrid joints is 14 pct higher than that of MIG-welded joints. Narrow weld and HAZ, weak softening behavior, and low residual stress level are the causes of the improvement of fatigue strength.

  11. Residual Stress and Fatigue Strength of Hybrid Laser-MIG-Welded A7N01P-T4

    Science.gov (United States)

    Wang, Qiuying; Chen, Hui; Qiu, Peixian; Zhu, Zongtao

    2016-09-01

    A7N01P-T4 aluminum alloy is widely used in some important welded components of high-speed trains. The hybrid laser-metal inert gas (MIG) welding process was studied to solve problems associated with the MIG welding process, such as low welding efficiency, high residual stress and deformation, and serious loss of strength. A high-speed camera, a voltage and current collection system, and NI DAQ were used to acquire arc profiles, welding voltage, and welding current simultaneously. Thermal cycle tests were carried out. Residual stresses induced by the welding process and fatigue strength of the joint were investigated. Large-size fatigue specimens were used in fatigue tests. The results show that the energy of the hybrid welding process is focused, and the power density of hybrid welding process is intense. The heat input per unit of the hybrid welding process is only half of that of the MIG welding process. Compared with the MIG welded joint, the overall residual stress level of the hybrid-welded joint is lower. The peak longitudinal stress of the hybrid-welded joint is reduced by 20 pct. The fatigue strength of hybrid joints is 14 pct higher than that of MIG-welded joints. Narrow weld and HAZ, weak softening behavior, and low residual stress level are the causes of the improvement of fatigue strength.

  12. STRATEGI BISNIS PT. PARIWARA ADVERTISING DI INDUSTRI MEDIA LUAR RUANG DKI JAKARTA

    Directory of Open Access Journals (Sweden)

    Mila Kumala

    2017-01-01

    Full Text Available The objective of the research is to analyze the internal and external condition of PT Pariwara advertising to formulate an appropriate strategy due to the company’s declining condition. This condition is caused by the implementation of Pergub No.1 tahun 2015 on the banning of cigarette and tobacco product advertisement in outdoor Medias.  The data is analyzed using internal factor evaluation (IFE, External Factor Evaluation (EFE, grand strategy matrix, SWOT and Quantitative Strategic Planning Matrix (QSPM.  The result of the research shows that the strategy priority during a stagnant condition is applying the concentric diversification strategy which adding new product that has the similar technology, join facilities, or distribution network with the current product.   Keywords: IFE, EFE, SWOT, grand strategy, QSPMAbstrakPenelitian ini bertujuan menganalisis kondisi internal dan eksternal PT. Pariwara Advertising untuk merumuskan strategi yang tepat ditengah kondisi perusahaan yang sedang menurun dan kondisi industri media luar ruang DKI Jakarta yang melemah karena diterapkannya Pergub No. 1 Tahun 2015 tentang  Larangan Penyelenggaraan Reklame Rokok dan Produk Tembakau pada Media Luar Ruang. Teknik analisis data menggunakan analisis internal factor evaluation (IFE, External Factor Evaluation (EFE, matriks strategi besar, matriks SWOT dan Quantitative Strategic Planning Matrix (QSPM. Hasil penelitian ini menunjukan prioritas strategi yang harus dilakukan di tengah kondisi industri yang stagnan adalah dengan strategi diverisifikasi konsentris yaitu strategi penambahan produk baru yang masih ada kaitannya dalam hal kesamaan teknologi, fasilitas bersama, atau jaringan pemasaran yang sama dengan produk yang ada saat ini.Kata kunci:  EFI, EFE, SWOT, strategi besar, QSPM

  13. Use of OVH residue in the ceramics industry

    Directory of Open Access Journals (Sweden)

    Grellier, S.

    2010-10-01

    Full Text Available Hydrothermal oxidation (OVH: “Oxydation par Voie Humide” is an innovative technology used for waste water treatment, which is presented as an alternative to sewage sludge spreading and incineration. This process generates a fine-grain (D50 = 2 μm mineral by-product, which is very useful for the ceramics industry due to its high content in argillaceous elements, quartz, phosphate and calcium carbonate. Therefore, this work describes the recycling of this OVH residue in the ceramics industry, and more particularly in the manufacture of calcareous earthenware wall tiles. The residue can be combined with a white calcareous earthenware body up to a level of 7% without significant colorimetric deterioration, and if this is raised to 15%, it is possible to completely replace the crushed chalk, some of the quartz and reduce costly imported tight-burning clays by 6%. The developed body exceeds standardised requirements (modulus of rupture: + 40%; moisture swelling and glaze quality, which means that a 20°C reduction in firing temperature might be envisaged. An industrial pilot test of 1500 kg conducted by the DESVRES site managers with 100 m2 of tiles (format: 15 x 20 cm confirmed these laboratory results, in particular validating the absence of rheological disturbance of the slip and the harmlessness of the addition on the maturing glaze quality. Furthermore, the nature of the fumes emitted in the test complied with current regulations, and the finished product did not exceed the thresholds defined by European regulations for inert waste classification.

    La oxidación hidrotérmica (OVH: “Oxydation par Voie Humide” u oxidación por vía húmeda es una tecnología innovadora usada en la depuración de las aguas residuales, que se presenta como alternativa al esparcimiento y a la incineración de los lodos de aguas negras. Este proceso genera un producto derivado de mineral de grano fino (D50 = 2 μm que es muy útil para la

  14. Spore production of Beauveria bassiana from agro-industrial residues

    Directory of Open Access Journals (Sweden)

    Herta Stutz Dalla Santa

    2005-06-01

    Full Text Available The purpose of this work was to produce Beauveria bassiana by Solid-State Fermentation using agro-industrial residues and optimizing the cultivation conditions. Refused potatoes, coffee husks and sugar-cane bagasse were tested. The blend of refused potatoes and sugar-cane bagasse (60-40% with particle size in the range of 0.8-2 mm was used in the fermentation experiments. In Erlenmeyer flasks the best spore production was achieved with the following conditions: incubation temperature 26º C; initial pH 6.0; inoculum concentration 10(7 spores.g-1.dw and initial moisture 75%. In the column type reactor using forced aeration under the optimized conditions, the maximum production (1.07x10(10spores.g-1.dw was obtained at the 10th day of fermentation. The respirometric analyses of the fermentation showed a strong correlation between fungal growth and spore production.O objetivo deste trabalho foi produzir Beauveria bassiana por fermentação no estado sólido em resíduos agro-industriais e otimizar as condições de cultivo. Batata-refugo, polpa de café e bagaço de cana de açúcar foram testados. A mistura de batata-refugo e de bagaço de cana de açúcar (60:40%, com granulometria de 2 a 0,8 mm foi escolhida como melhor substrato/suporte. Em frascos de Erlenmeyer a produção de esporos foi maior com as seguintes condições: pH 6,0; temperatura de incubação de 26º C; taxa de inóculo de 10(7 esporos.g-1 de matéria seca; e umidade inicial de 75%. Em bioreator do tipo coluna com aeração forçada, as condições otimizadas possibilitaram uma produção máxima de esporos no 10º dia de fermentação, obtendo-se 1,07x10(10 esporos.g-1 de matéria seca. A análise respirométrica desta fermentação permitiu correlacionar o desenvolvimento do fungo com a produção de esporos.

  15. PENGARUH PENERAPAN BUDAYA PERUSAHAAN TERHADAP MOTIVASI KERJA DAN KINERJA KARYAWAN DI PT. REKAYASA INDUSTRI

    Directory of Open Access Journals (Sweden)

    Bambang Ernanto

    2015-08-01

    Full Text Available The purpose of this research was to analyze the corporate culture application effect on work motivation, and employee performance at PT. Rekayasa Industri. The sampling was collected using purposive sampling technique. Explanatory Factor Analysis (EFAwas  used in the research as culture corporate variables test and Confirmatory Factor Analysis (CFA  for each variable validation indicators. The test of hypotheses corporate culture that influence on work motivation and employee performance is done by using Structural Equation Modeling (SEM. The result of this research shows a significant effect on work motivation, performance and motivation on performance of corporate culture. There is still a difference between the important value in the field, corporate culture that should sipposed to be professional, innovation and team work and the most real implement is concern  for people, professional and focus on customer. Based on the average value of the score and a load factor of  SEM motivation variable, the   intrinsic motivation should be prioritized, but in fact extrinsic motivation and performance factors should prioritize conceptual abilities, but in reality the best  implementation is technical ability. This study is also to conduct explanatory to 6 core value of the company culture that has been formulated, in order to know whether the determination of the six core values are in accordance with the rules of statistics that can be used further for scientific research. Keywords: corporate culture, employee performance, motivation, CFA, SEMABSTRAKPenelitian ini bertujuan menganalisis pengaruh penerapan budaya perusahan terhadap motivasi kerja, dan kinerja karyawan di PT. Rekayasa Industri. Teknik pengambilan contoh yang digunakan adalah purposive sampling. Pengujian variabel budaya perusahan menggunakan Explanatory Factor Analysis (EFA, sedangkan untuk melihat validitas indikator dari masing-masing variabel menggunakan Confirmatory Factor

  16. 75 FR 75482 - Draft Guidance for Industry on Residual Solvents in Animal Drug Products; Questions and Answers...

    Science.gov (United States)

    2010-12-03

    ... HUMAN SERVICES Food and Drug Administration Draft Guidance for Industry on Residual Solvents in Animal... guidance for industry 211 entitled ``Residual Solvents in Animal Drug Products; Questions and Answers... availability of a draft guidance for industry 211 entitled ``Residual Solvents in Animal ] Drug...

  17. Emerging contaminants from industrial and municipal waste. Pt. 2. Removal technologies

    Energy Technology Data Exchange (ETDEWEB)

    Barcelo, Damia; Petrovic, Mira (eds.) [IIQAB - CSIC, Barcelona (Spain). Dept. of Environmental Chemistry

    2008-07-01

    The group of non-regulated contaminants termed 'emerging contaminants' mainly comprises products used in large quantities in everyday life, such as human and veterinary pharmaceuticals, personal care products, surfactants and surfactant residues, plasticizers and various industrial additives. The occurrence of 'emerging contaminants' in wastewaters, and their behavior during wastewater treatment and production of drinking water are key issues in the re-use of water resources. Emerging Contaminants from Industrial and Municipal Waste focuses on innovative treatment technologies for the elimination of emerging contaminants from wastewater and drinking water. The respective treatment processes, such as membrane bioreactors, photocatalysis, ozonation and advanced oxidation are dealt with in detail. The book also discusses sources and occurrence of emerging contaminants in municipal and industrial waste, giving a concise and critical overview of state-of-the-art analytical methods for their identification. Further important aspects covered by the book include the acute and chronic effects and overall impact of emerging contaminants on the environment. (orig.)

  18. Emerging contaminants from industrial and municipal waste. Pt. 1. Occurence, analysis and effects

    Energy Technology Data Exchange (ETDEWEB)

    Barcelo, Damia; Petrovic, Mira (eds.) [IIQAB - CSIC, Barcelona (Spain). Dept. of Environmental Chemistry

    2008-07-01

    The group of non-regulated contaminants termed 'emerging contaminants' mainly comprises products used in large quantities in everyday life, such as human and veterinary pharmaceuticals, personal care products, surfactants and surfactant residues, plasticizers and various industrial additives. The occurrence of 'emerging contaminants' in wastewaters, and their behavior during wastewater treatment and production of drinking water are key issues in the re-use of water resources. Emerging Contaminants from Industrial and Municipal Waste focuses on innovative treatment technologies for the elimination of emerging contaminants from wastewater and drinking water. The respective treatment processes, such as membrane bioreactors, photocatalysis, ozonation and advanced oxidation are dealt with in detail. The book also discusses sources and occurrence of emerging contaminants in municipal and industrial waste, giving a concise and critical overview of state-of-the-art analytical methods for their identification. Further important aspects covered by the book include the acute and chronic effects and overall impact of emerging contaminants on the environment. (orig.)

  19. Single-stranded oligonucleotide adducts formed by Pt complexes favoring left-handed base canting: steric effect of flanking residues and relevance to DNA adducts formed by Pt anticancer drugs.

    Science.gov (United States)

    Saad, Jamil S; Marzilli, Patricia A; Intini, Francesco P; Natile, Giovanni; Marzilli, Luigi G

    2011-09-01

    Platinum anticancer drug binding to DNA creates large distortions in the cross-link (G*G*) and the adjacent XG* base pair (bp) steps (G* = N7-platinated G). These distortions, which are responsible for anticancer activity, depend on features of the duplex (e.g., base pairing) and of the cross-link moiety (e.g., the position and canting of the G* bases). The duplex structure stabilizes the head-to-head (HH) over the head-to-tail (HT) orientation and right-handed (R) over left-handed (L) canting of the G* bases. To provide fundamental chemical information relevant to the assessment of such duplex effects, we examine (S,R,R,S)-BipPt(oligo) adducts (Bip = 2,2'-bipiperidine with S,R,R,S chiral centers at the N, C, C, and N chelate ring atoms, respectively; oligo = d(G*pG*) with 3'- and/or 5'-substituents). The moderately bulky (S,R,R,S)-Bip ligand favors L canting and slows rotation about the Pt-G* bonds, and the (S,R,R,S)-BipPt(oligo) models provide more useful data than do dynamic models derived from active Pt drugs. All 5'-substituents in (S,R,R,S)-BipPt(oligo) adducts favor the normal HH conformer (∼97%) by destabilizing the HT conformer through clashes with the 3'-G* residue rather than through favorable H-bonding interactions with the carrier ligand in the HH conformer. For all (S,R,R,S)-BipPt(oligo) adducts, the S pucker of the 5'-X residue is retained. For these adducts, a 5'-substituent had only modest effects on the degree of L canting for the (S,R,R,S)-BipPt(oligo) HH conformer. This small flanking 5'-substituent effect on an L-canted HH conformer contrasts with the significant decrease in the degree of R canting previously observed for flanking 5'-substituents in the R-canted (R,S,S,R)-BipPt(oligo) analogues. The present data support our earlier hypothesis that the distortion distinctive to the XG* bp step (S to N pucker change and movement of the X residue) is required for normal stacking and X·X' WC H bonding and to prevent XG* residue clashes.

  20. Pengendalian Kualitas Produk Lembaran Serat Semen Rata di Pt Bakrie Building Industries Dengan Metode DMAIC

    Directory of Open Access Journals (Sweden)

    Ho Hwi Chie

    2010-12-01

    Full Text Available Producing quality products to match customer expectations is an important thing that needs to be done by every company that produces any product, to gain public appreciation and sell their products on the market. Therefore companies need to have a strong commitment in improving and maintaining product quality. The study related to product quality of flat sheets of fiber cement or more commonly known as versaboard produced by PT. Bakrie Building Industries show that there are 9 (nine types of defects that can degrade the quality of production. Most dominant defects occured on 3 (three versaboard products, the crack (2.03%, broken end (0.80% and side trim (0.35% during observation. Sigma level of products is obtained at 4:16 at a cost saving of due to defects of Rp.14.645.600, 00. Defects that occur tend to be caused by methods, people, machines, and materials used. Efforts to reduce the level of defects are done by making the SOP of the break-up method, and manufacture of cutter flow diagram. REBA score calculation results (Rapid Entire Body Assessment in the removal and break-up reduction is obtained at 8 with a high level of risk should lead to improving the position of the operator using the Rapid Entire Body Assessment (Reba so that operators can work more carefully and responsibly.. 

  1. PERBANDINGAN KELAYAKAN PEMBELIAN DAN SEWA MOBIL UNTUK KENDARAAN OPERASIONAL DI PT PANARUB INDUSTRY

    Directory of Open Access Journals (Sweden)

    Heri Prastowo

    2014-02-01

    Full Text Available Semakin berkembang dan meningkatnya aktifitas bisnis mengakibatkan bertambahnya interaksi antara perusahaan dengan pihak eksternal baik itu instansi pemerintah maupun instansi swasta. Bertambahnya jumlah permintaan kendaraan operasional, menuntut perusahaan untuk menambah jumlah unit mobil operasional yang dimiliki. Keputusan untuk penambahan mobil operasional memerlukan pertimbangan yang tepat, terutama yang menyangkut masalah biaya, mulai dari pembelian, operasional, pemeliharaan, perawatan dan lain-lain. Pengambilan data dilakukan di PT Panarub Industry, pada periode Agustus - Desember 2012. Data yang berhasil dikumpulkan antara lain: data mobil, pengemudi, jam kerja, upah, permintaan mobil, biaya operasional, biaya perawatan, biaya pembelian dan penyewaan mobil. Selanjutnya data tersebut diolah dengan menggunakan beberapa metode analisis, diantaranya Payback Period, Net Present Value, Profitability Index, dan Internal Rate of Return.Dari hasil perbandingan kelayakan antara pembelian dan sewa, diperoleh hasil dan dipilih alternatif pembelian dengan nilai Payback Period  2,37 tahun; Net Present Value Rp 299.432.323; Profitability Index 1.73; dan Internal Rate of Return 31,58%. Berdasarkan  analisis hasil menunjukkan usul investasi layak untuk dijalankan.

  2. Anaerobic digestion from residue of industrial cassava industrialization with acidogenic and methanogenic physical separation phases.

    Science.gov (United States)

    Paixão, M A; Tavares, C R; Bergamasco, R; Bonifácio, A L; Costa, R T

    2000-01-01

    A trial was carried out in a continuous regimen, using a completely stirred tank reactor, at acidogenic phase, and a hybrid reactor (upflow anaerobic sludge blanket + fixed bed) at methanogenic phase at room temperature. The residue to be treated came from a flour and cassava meal industry, and the reactors operated for 300 d with affluent chemical oxygen demand (COD) concentrations of 7500, 9000, 11,000, and 14,000 mg/L. The final results showed a biogas production with a content of 80% methane and an average reduction of COD and free cyanide of nearly 96 and 98%, respectively. The separation of phases selected bacterial groups. At acidogenic phase, a predominance of propionic, n-butyric, and n-valeric acids, as well as a biomass composed of 95% fermentative bacilli, which were responsible for a 90% reduction in free cyanide concentration, was observed. At methanogenic phase, a predominance of methanogenic bacteria that came only from the Methanothrix genus was observed. The bacteria were responsible for high levels of organic matter removal and methane production.

  3. Stabilization of APC residues from waste incineration with ferrous sulfate on a semi-industrial scale

    DEFF Research Database (Denmark)

    Lundtorp, Kasper; Jensen, Dorthe Lærke; Christensen, Thomas Højlund

    2002-01-01

    A stabilization method for air pollution control (APC) residues from municipal solid waste incineration (MSWI) involving mixing of the residue with water and FeSO4 has been demonstrated on a semi-industrial scale on three types of APC residues: a semidy (SD) APC residue, a fly ash (FA), and an FA...... mixed with sludge (FAS) from a wet flue gas cleaning system. The process was performed in batches of 165-175 kg residue. It generates a wastewater that is highly saline but has a low content of heavy metals such as Cd, Cr, and Pb. The stabilized and raw residues have been subject to a range of leaching...... tests: the batch leacing test, the pH-static leaching test, the availability test, and the column test. These tests showed that the stabilized residues have remarkably improved leaching properties, especially with respect to Pb but also with respect to Cd, Cu, and Zn. The release of Pb was reduced...

  4. Pengaruh Temperatur Vulkanisasi Terhadap Kekuatan Tarik (Tensile Strength) Pada Packing Pintu Rebusan PT. Industri Karet Nusantara Medan

    OpenAIRE

    Ayutami, Rizki

    2012-01-01

    In this paper will discuss how is the influence of temperature vulcanization which in used at Rubber Articles Factory in PT. Rubbin Industry Nusantara Medan. The start with selection raw materials natural rubber and synthetic rubber in used until became rubber articles. The variety rubber which in used to produce rubber articles is rubber smoke sheet, there for variety synthetic rubber which used is SBR (Styrine Butadine Rubber). At the first process, main material rubber and chemical is mixe...

  5. Spore production in Paecilomyces lilacinus (Thom.) samson strains on agro-industrial residues

    OpenAIRE

    Robl, Diogo; Sung, Letizia B.; Novakovich,João Henrique; Marangoni, Paulo R.D.; Zawadneak, Maria Aparecida C.; Dalzoto,Patricia R.; Gabardo,Juarez; Pimentel,Ida Chapaval

    2009-01-01

    Paecilomyces lilacinus has potential for pests control. We aimed to analyze mycelial growth and spore production in P. lilacinus strains in several agro-industrial residues and commercial media. This study suggests alternative nutrient sources for fungi production and that the biotechnological potential of agro-industrial refuses could be employed in byproducts development.

  6. An alternative feedstock of corn meal for industrial fuel ethanol production: delignified corncob residue.

    Science.gov (United States)

    Lei, Cheng; Zhang, Jian; Xiao, Lin; Bao, Jie

    2014-09-01

    Delignified corncob residue is an industrial solid waste from xylose production using corncob as feedstock. In this study, delignified corncob residue was used as the feedstock of ethanol production by simultaneous saccharification and fermentation (SSF) and the optimal fermentation performance was investigated under various operation conditions. The ethanol titer and yield reached 75.07 g/L and 89.38%, respectively, using a regular industrial yeast strain at moderate cellulase dosage and high solids loading. A uniform SSF temperature of 37°C at both prehydrolysis and SSF stages was tested. The fermentation performance and cost of delignified corncob residue and corn meal was compared as feedstock of ethanol fermentation. The result shows that the delignified corncob residue is competitive to corn meal as ethanol production feedstock. The study gives a typical case to demonstrate the potential of intensively processed lignocellulose as the alternative feedstock of corn meal for industrial fuel ethanol production.

  7. Feed or bioenergy production from agri-industrial residues?

    DEFF Research Database (Denmark)

    Tonini, Davide; Hamelin, Lorie; Astrup, Thomas Fruergaard

    Second generation biofuels produced from “residual” biomasses are considered promising ways of producing bioenergy. However, many studies tend to forget that these biomasses are today used for specific purposes, (e.g. feeding). This means that their use for energy would induce cascading...... considered: combustion, fermentation to ethanol, and to biogas. The iLUC impacts were quantified and included in the assessment. The LCA results revealed that, for all scenarios, GHG emissions from indirect land-use changes were the major contributor to the total GHG impact (up to ca. 40-60% of the total...... induced GHG emissions). All in all, the use of biomasses that are today used as animal feed (e.g. beet molasses) induced significant GHG emissions through iLUC. These were quantified at between 1-3.5 t CO2/t dry residue depending upon the nutritional value. The recommendation is to avoid the use...

  8. Use of solid residue from the olive industry

    Directory of Open Access Journals (Sweden)

    Guinda, Ángeles

    2006-03-01

    Full Text Available Research into finding new uses for olive products, particularly by-products of olive oil production, is of great relevance not only to the economy, but also to the environment, in the towns where olives are grown. A large number of research articles has been published dealing with the chemical composition of olives and olive oil; however, only a few studies have centered on isolating and identifying compounds in the olive leaf. In this article an overview of the present body of knowledge on the chemical composition of the olive leaf will be presented. Also to be discussed is the use of solid residue, namely, the olive leaf and the olive stone. Both of these types of residue result from olive oil and table olive production, and can be used as a renewable energy source, as well as to obtain high added-value compounds. The latter, bioactive compounds are directed towards the cosmetic, pharmaceutical, and natural food supplements markets, all of which are currently highly receptive to products of natural origin.La investigación de nuevos aprovechamientos del olivar y en particular de lo subproductos del proceso de producción del aceite, tiene gran relevancia tanto en la economía como en el medio ambiente de los pueblos donde se desarrolla este cultivo. Son numerosos los trabajos publicados sobre la composición química de la aceituna y el aceite de oliva, en cambio sólo existen algunos estudios sobre el aislamiento e identificación de los compuestos de la hoja de olivo, en esta contribución se revisan los conocimientos sobre la composición química de la hoja de olivo, así como, las utilizaciones de los residuos sólidos -hoja de olivo y hueso de aceituna- que se originan en la producción del aceite de oliva y de aceitunas de mesa, como energía renovable y para la obtención de compuestos de alto valor añadido. Estos últimos, compuestos bioactivos dirigidos a los mercados de los aditivos alimentarios naturales, farmacéutico y cosm

  9. Utilization of residues from agro-forest industries in the production of high value bacterial cellulose.

    Science.gov (United States)

    Carreira, Pedro; Mendes, Joana A S; Trovatti, Eliane; Serafim, Luísa S; Freire, Carmen S R; Silvestre, Armando J D; Neto, Carlos Pascoal

    2011-08-01

    Bacterial cellulose (BC), a very peculiar form of cellulose, is gaining considerable importance due to its unique properties. In this study, several residues, from agro-forestry industries, namely grape skins aqueous extract, cheese whey, crude glycerol and sulfite pulping liquor were evaluated as economic carbon and nutrient sources for the production of BC. The most relevant BC amounts attained with the residues from the wine and pulp industries were 0.6 and 0.3 g/L, respectively, followed by biodiesel crude residue and cheese whey with productions of about, 0.1 g/L after 96 h of incubation. Preliminary results on the addition of other nutrient sources (yeast extract, nitrogen and phosphate) to the residues-based culture media indicated that, in general, these BC productions could be increased by ~200% and ~100% for the crude glycerol and grape skins, respectively, after the addition organic or inorganic nitrogen.

  10. Pozzolanic properties of residues of sugar industries (first part

    Directory of Open Access Journals (Sweden)

    Martirena-Hernández, J. F.

    2000-12-01

    Full Text Available Non altered straw and sugar cane bagasse ash (CPC, CBC collected directly from the boilers in the sugar industry and from non-controlled burning in the open fields turned up to be a reasonably good pozzolana, which can be utilized for the manufacture of lime-pozzolana binders. This paper presents a detailed survey of this material with the aim to use it as raw material in the manufacture of binders.

    Las cenizas de bagazo y paja de caña de azúcar (CPC, CBC, obtenidas en forma inalterada directamente de las calderas de la fábrica de azúcar, y de la quema incontrolada en el campo, representan una interesante fuente de puzolana reactiva, con potencialidad de ser usada en la preparación de aglomerantes del tipo cal/puzolana. El trabajo que se presenta realizó una evaluación integral de estas puzolanas, con el interés de utilizarlas como materia prima en la producción de aglomerantes.

  11. Mapping and quantification of organic agro-industrial residues in East Africa

    Energy Technology Data Exchange (ETDEWEB)

    Jungersen, G. [Dansk Teknologisk Inst. (Denmark); Kivaisi, A.; Rubindamayugi, M. [Univ. of Dar es Salaam (Tanzania, United Republic of)

    1998-05-01

    The East-African agro-industries generate very large quantities of organic residues from production and processing of different crops. These residues form a major contribution to the pollution of air, soil and water ways, but, at the same time they constitute a large potential for production of bioenergy through anaerobic digestion as well as potential substrate for other biological fermentation processes. The utilization of these resources for production of valuable products would contribute significantly to: Improvement of the local energy supply, through production of bio-energy; Improvement of the economy of the East African agro-industry; Reduction of the environmental impact from the agro-industrial sector. Except for production of cane sugar, most agro-industrial residues are generated from cash crops, which are produced and processed in the developing countries and where the final products mainly are used for export. In the East-African Region the most important of these crops are: Sisal, coffee, Cashew nuts and Pineapple. In addition significant quantities of organic residues are generated from other food processing activities like breweries, consumption of bananas etc. The total potential methane production of the residues available for use in biomethanization systems in East Africa is 189.61 million m{sup 3} of methane per year. Converted to diesel oil equivalents and including the residues only feasible for combustion systems, the total bioenergy potential of agro-industrial residues in Eastern Africa is 279,176 TOE. If this potential was fully utilized for production of electricity, it would correspond to installed effects of 37,68 and 31 MW in Tanzania, Kenya and Uganda, respectively, equivalent to 10%, 11% and 18% of the currently installed effect is these countries. Residues from sisal and coffee processing constitute the main part of the bioenergy potential, on average approximately 75%, while the remaining 25% of the potential are formed by the

  12. DEVELOPMENT OF INFORMATION TECHNOLOGY STRATEGIC PLANNING FOR MANUFACTURING INDUSTRY (CASE STUDY: PT MCM

    Directory of Open Access Journals (Sweden)

    Leonardus Hardjo

    2013-10-01

    Full Text Available IT Department in PT MCM has to carry out the duties and functions of developing solution to support the business unit in their operation and gain some benefits which should be obtained by using IT in manufacturing such as increasing efficiency, improving the effectivity in making decision and helping to promote the products. This study aims to design information technology strategic planning in accordance with the strategic plan. The research method is using the IT Strategic Planning framework of Alex Cullen and Marc Cecere. This study uses SWOT and IT Balanced Scorecard to analyze the needs of IT at PT MCM. The results of this study are recommended strategic steps to optimize the implementation of IT in the company to improve the performance from IT division to obtain the benefits by implementing IT in manufacturing and to form IT Blueprint, which is part of the information technology strategic plan in PT MCM.

  13. PENGARUH BIAYA OPERASIONAL TERHADAP PROFITABILITAS (ROA PT INDUSTRI TELEKOMUNIKASI INDONESIA (PERSERO

    Directory of Open Access Journals (Sweden)

    Widi Winarso

    2016-03-01

    Full Text Available Abstract - PT INTI (Persero is one of state company (BUMN in communication sector continuously try to becomeworld class communication facility provider. This research purposes to know the influence about operational costs against profitability (ROA on PT INTI (Persero. Thetendency of the operational costs increase while the profitability fluctuates every year. This research uses descriptive method with quantitative approach. To know the influence of operational cost to profitability (ROA used testing of statistics. Testing statistics that used is normality test, linear regression, correlation coefficient, coefficient determination, test t- and also use the application of Microsoft Excel 2007 and SPSS 20.0 for windows. The calculation result of linear regression and correlation coefficient is the relation between operational cost and profitability is not direction, and tending to direct so that the rate influences operational cost to profitability in PT INTI (Persero 13.26 % and the rest 86,4 %  are influenced by other factors that not explored. The test results obtained t0 ≥ ta, therefor the operational cost influence to profitability (ROA.   Keyword : Net-Operating Costs, Profitability (ROA   Abstrak - PT INTI (Persero yaitu salah satu perusahaan BUMN dibidang komunikasi yang senantiasa berupaya untuk menjadi penyedia sarana komunikasi kelas dunia. Tujuan penelitian ini untuk mengetahui pengaruh biaya operasional terhadap profitabilitas (ROA pada PT INTI (Persero. Dimana kecenderungan biaya operasional mengalami peningkatan sedangkan profitabilitas pada PT INTI (Persero mengalami fluktuatif setiap tahunnya. Metode yang digunakan dalam penelitian ini adalah metode deskriptif dengan pendekatan kuantitatif.  Untuk mengetahui pengaruh biaya operasional terhadap profitabilitas (ROA digunakan pengujian statistik. Pengujian statistik yang digunakan adalah uji normalitas, penggunaan regresi, koefisien korelasi, koefisien determinasi, uji t dan

  14. Quality Tools and TRIZ Based Quality Improvement Case Study at PT ‘X’ A Plastic Moulding Manufacturing Industry

    Science.gov (United States)

    Wirawan, Christina; Chandra, Fory

    2016-02-01

    Theory of Inventive Problem Solving (TRIZ) is a creative encouraging problem solving method. TRIZ is prepared by Altshuller for product design. Altshuller prepared contradiction matrix and suggestion to solve contradictions usually occur in product design. This paper try to combine TRIZ with quality tools such as Pareto and Fault Tree Analysis (FTA) to solve contradiction in quality improvement problem, neither than product design problem. Pareto used to identify defect priority, FTA used to analysis and identify root cause of defect. When there is contradiction in solving defect causes, TRIZ used to find creative problem solving. As a case study, PT ’X’, a plastic molding manufacturing industry was taken. PT ‘X’ using traditional press machine to produce plastic thread cone. There are 5 defect types that might occur in plastic thread cone production, incomplete form, dirty, mottle, excessive form, rugged. Research about quality improvement effort using DMAIC at PT ‘X’ have been done by Fory Candra. From this research, defect types, priority, root cause from FTA, recommendation from FMEA. In this research, from FTA reviewed, contradictions found among causes troublesome quality improvement efforts. TRIZ used to solve the contradictions and quality improvement effort can be made effectively.

  15. Physical characterization of particleboard panels made from Eucalyptus grandis with addition of industrial wood residues

    Directory of Open Access Journals (Sweden)

    Fernanda Cristina Pierre

    2014-06-01

    Full Text Available In Brazil, the wood from planted forests constitutes the main material source for the production of particleboards. The utilization of forest residues for production of these panels was not implemented in industrial level yet. This work had the objective of evaluating the physical properties of three layers particleboard, industrially manufactured, using wood of Eucalyptus grandis from plantation and industrial wood residues in different ratios (adittion from 10% to 35% in volume. The material (Eucalyptus grandis wood and industrial residues - recycled pallets and sawdust was supplied by Eucatex S. A. Ind. e Com. located in Botucatu - Sao Paulo State, Brazil, where the panels had been manufactured in Eucatex plant. Physical tests were carried out at the Process Laboratories of Eucatex and in the Materials Testing Laboratory, Rural Engineering Department of the College of Agronomic Sciences - Sao Paulo State University - UNESP. Results revealed that panels had very good physical performance, attending, in general, to all the technical specifications established by the product standards, even in the treatments with higher addition of residues. The final moisture content of the panel presented effect in the properties studied with general trend of reduction in water absorption and swelling in thickness when the moisture content increased from 9% for 12,5%.

  16. Fractional Precipitation of Amino Acids from Agro-industrial Residues Using Ethanol

    NARCIS (Netherlands)

    Widyarani, Rani; Bowden, Nathan A.; Kolfschoten, Ruben C.; Sanders, Johan P.M.; Bruins, Marieke E.

    2016-01-01

    Amino acids are important in human and animal diet, as well as being potential feedstocks for chemical production. Amino acids can be obtained from protein after hydrolysis. In addition, several agro-industrial residues already contain a mixture of free amino acids. The objective of this study wa

  17. Evaluation of holocellulase production by plant-degrading fungi grown on agro-industrial residues.

    Science.gov (United States)

    de Siqueira, Félix Gonçalves; de Siqueira, Aline Gonçalves; de Siqueira, Eliane Gonçalves; Carvalho, Marly Azevedo; Peretti, Beatriz Magalhães Pinto; Jaramillo, Paula Marcela Duque; Teixeira, Ricardo Sposina Sobral; Dias, Eustáquio Souza; Félix, Carlos Roberto; Filho, Edivaldo Ximenes Ferreira

    2010-09-01

    Agaricus brasiliensis CS1, Pleurotus ostreatus H1 and Aspergillus flavus produced holocellulases when grown in solid and submerged liquid cultures containing agro-industrial residues, including sugar cane bagasse and dirty cotton residue, as substrates. These isolates proved to be efficient producers of holocellulases under the conditions used in this screening. Bromatological analysis of agro-industrial residues showed differences in protein, fiber, hemicellulose, cellulose and lignin content. Maximal holocellulase activity (hemicellulase, cellulase and pectinase) was obtained using solid-state cultivation with 10% substrate concentration. In this case, remarkably high levels of xylanase and polygalacturonase activity (4,008 and 4,548 IU/l, respectively) were produced by A. flavus when grown in media containing corn residue, followed by P. ostreatus H1 with IU/l values of 1,900 and 3,965 when cultivated on 5% and 10% sugar cane bagasse, respectively. A. brasiliensis CS1 showed the highest reducing sugar yield (11.640 mg/ml) when grown on medium containing sugar cane bagasse. A. brasiliensis was also the most efficient producer of protein, except when cultivated on dirty cotton residue, which induced maximal production in A. flavus. Comparison of enzymatic hydrolysis of sugar cane bagasse and dirty cotton residue by crude extracts of A. brasiliensis CS1, P. ostreatus H1 and A. flavus showed that the best reducing sugar yield was achieved using sugar cane bagasse as a substrate.

  18. Residue Management of Biodiesel Industry: A Study of Value Creation in the Supply Chain

    Directory of Open Access Journals (Sweden)

    Stella Maris Lima Altoé

    2014-06-01

    Full Text Available Residues, whether solid or liquid, are inherent to many industrial processes, and require specialized treatments. The purpose of this research is to evaluate the process of creating value in the supply chain, from the sustainable management of residues in the biodiesel industry. The methodological approach was a multiple case study, with the use of bibliographic data, documents and discourse analysis. Data were collected through interviews with managers of the companies analyzed. The findings suggest that residue management enables the creation of value in the supply chain of biodiesel. It is also noted that from this management, environmental preservation occurs, the incidence of fines is reduced or even eliminated, and there are still economic cooperation between the companies that have different activities but are a part of the supply chain of biodiesel

  19. Metal-containing residues from industry and in the environment: geobiotechnological urban mining.

    Science.gov (United States)

    Glombitza, Franz; Reichel, Susan

    2014-01-01

    This chapter explains the manifold geobiotechnological possibilities to separate industrial valuable metals from various industrial residues and stored waste products of the past. In addition to an overview of the different microbially catalyzed chemical reactions applicable for a separation of metals and details of published studies, results of many individual investigations from various research projects are described. These concern the separation of rare earth elements from phosphorous production slags, the attempts of tin leaching from mining flotation residues, the separation of metals from spent catalysts, or the treatment of ashes as valuable metal-containing material. The residues of environmental technologies are integrated into this overview as well. The description of the different known microbial processes offers starting points for suitable and new technologies. In addition to the application of chemolithoautotrophic microorganisms the use of heterotrophic microorganisms is explained.

  20. Characterization of Industrial Pt-Sn/Al2O3 Catalyst and Transient Product Formations during Propane Dehydrogenation

    Directory of Open Access Journals (Sweden)

    Kah Sing Ho

    2013-06-01

    Full Text Available The major problem plaguing propane dehydrogenation process is the coke formation on the Pt-Sn/Al2O3 catalyst which leads to catalyst deactivation. Due to information paucity, the physicochemical characteristics of the commercially obtained regenerated Pt-Sn/Al2O3 catalyst (operated in moving bed reactor and coke formation at different temperatures of reaction were discussed. The physicochemical characterization of regenerated catalyst gave a BET surface area of 104.0 m2/g with graphitic carbon content of 8.0% indicative of incomplete carbon gasification during the industrial propylene production. Effect of temperatures on coke formation was identified by studying the product yield via temperature-programmed reaction carried out at 500oC, 600oC and 700oC. It was found that ethylene was precursor to carbon laydown while propylene tends to crack into methane. Post reaction, the spent catalyst possessed relatively lower surface area and pore radius whilst exhibited higher carbon content (31.80% at 700oC compared to the regenerated catalyst. Significantly, current studies also found that higher reaction temperatures favoured the coke formation. Consequently, the propylene yield has decreased with reaction temperature. © 2013 BCREC UNDIP. All rights reservedReceived: 10th March 2013; Revised: 28th April 2013; Accepted: 6th May 2013[How to Cite: Kah, S.H., Joanna Jo, E.C., Sim, Y.C., Chin, K.C. (2013. Characterization of Industrial Pt-Sn/Al2O3 Catalyst and Transient Product Formations during Propane Dehydrogenation. Bulletin of Chemical Reaction Engineering & Catalysis, 8 (1: 77-82. (doi:10.9767/bcrec.8.1.4569.77-82][Permalink/DOI: http://dx.doi.org/10.9767/bcrec.8.1.4569.77-82] | View in  |

  1. Economics of industrial cogeneration with a residual-oil-fired low-speed diesel

    Energy Technology Data Exchange (ETDEWEB)

    Santini, D.J.; Belak, F.J.; Bernard, M.J.; Stodolsky, F.; Suchy, K.W.

    1984-01-01

    The only residual-oil-fired low speed diesel cogeneration facility in the US has been in operation for a year at the Hoffman-LaRoche Vitamin C plant in Belvidere, NJ. Operating data for this grid-connected 23 MW facility are used to construct a generic evaluation of the economic desirability of such systems for industrial electric/thermal applications and industrial-thermal/commercial-electrical applications made possible by recent US legislation (PURPA). The post 1980 changes in relative electrical and residual oil prices are shown to have made oil fired on-site generation more attractive. The likely 1985-2005 movements of electricity and residual oil prices are discussed, along with risks of error in projections. The system is evaluated as a whole and on an incremental basis. Incremental analysis includes (1) the economics of steam and hot water use given the diesel and (2) the economics of system generation given industrial electric, steam and hot water loads. The sensitivity of the economics of the system to the full range of US electricity and residual oil prices is estimated. The effect of variation in system loads is examined. The economic desirability of the system is often great but is also highly variable geographically, largely as a function of local evaded electricity charges.

  2. Electrostatic painting residues as an alternative raw material for red clay industry.

    Science.gov (United States)

    Basegio, Tania; Machado, Andréa; Bernardes, Andréa Moura; Bergmann, Carlos Pérez

    2006-12-01

    In this study, the viability of using electrostatic painting residues--paint sludge--as a raw material to the red clay industry was investigated. Red clay-based ceramic masses containing electrostatic paint residues were formulated during the study. The clays were obtained from the Rio do Rastro deposit, in Gravataí, and were of the standard formulation used in industry. Different ceramic mass formulations with additions of 0.5, 1.0, 2.5 and 5.0 wt.% electrostatic painting residue in addition to a formulation with no residue addition (standard formulation), were evaluated. The samples were uniaxially pressed in a double-effect press and were fired in an electric oven at 900, 950 and 1000 degrees C. The firing at constant temperature lasted 8 h, and heating rate was 150 K h(-1). After processing the samples were characterized in terms of their physical and mechanical properties. Environmental compatibility was also considered by the evaluation of gaseous emissions and leaching and solubilization tests according to the Brazilian standards NBR 10.005 and NBR 10.006, respectively. The results showed that it was possible to produce ceramic materials containing electrostatic painting residues within their formulations.

  3. Bioenergy from agro-industrial residues in the East African region. Summary report

    Energy Technology Data Exchange (ETDEWEB)

    Jungersen, G. [Dansk Teknologisk Inst. (Denmark); Kivaisi, A.; Rubindamayugi, M. [Univ. of Dar es Salaam (Tanzania, United Republic of)

    1998-05-01

    Tanzania has recently developed a comprehensive environmental policy which has put high priority on several specific environmental issues. One of the issues is the quality of waste water. A special priority is given to the pollution from the sisal industry. The East-African agro-industries generate very large quantities of organic residues from production and processing of different crops. These residues form a major contribution to the pollution of air, soil and waterways, but, at the same time they constitute a large potential for production of bioenergy through anaerobic digestion as well as potential substrate for other biological fermentation processes. Generally, these residues are regarded as having no or very little value and the different disposal methods are mainly a matter of getting rid of the waste. The generation of residues are very often concentrated on few large units, which makes the exploitation of these resources feasible in large scale biogas systems. Typically the units will have a potential of a daily methane generation of 1,000-20,000 m{sup 3} CH{sub 4}, equivalent to a potential electricity production of 0.2-3.2 MW. The future utilization of these resources for production of valuable products is described in this report. This report consists of 3 volumes. This summary report including the main objectives and findings from the different project report: Mapping and Quantification of Organic Agro-Industrial Residues in East Africa; Biogas - Bioenergy Potential in East Africa, Seminar Proceedings, Siler Sands, Dar es Salaam 22-23 September 1997; Bioenergy from Sisal residues - Experimental results and Capacity Building Activities. (EG)

  4. PENGENDALIAN PERSEDIAAN BAHAN BAKU BASE MATERIAL PADA INDUSTRI KERAMIK DI PT. XYZ

    Directory of Open Access Journals (Sweden)

    Lidya Susanti

    2015-12-01

    Full Text Available Inventory of raw materials in the company is very important, so it has to be controlled. A good inventory control of raw materials should be supported with cost efficiency. This study was to analyze factors that cause the base material inventories excess at PT. XYZ and analyze the purpose of the base material inventories to be controlled. The reseacrh was using a fish bone method and continue with using pairwise comparison method assisted with the expert choice 2000 software. The classification result based on ABC analysis, the selected item that was going to be analyzed was the A category items.The items that are included in the A category are clay ex belitung jw, clay ja 1/ja b and sodium feldspar. The EOQ equations model was used to answer the purpose of the base material inventories control. Based from the EOQ model, the needed quantity, order quantity, order frequency, reorder point (ROP, total order cost (TOC, total carrying cost (TCC, and total inventory cost (TIC could be obtained. The comparison of the total cost of inventory among the EOQ model and company policies showed that the EOQ model in seven months can save up to Rp311.612.769. PT. XYZ could minimize the base material inventory costs by calculating the costs incurred. The EOQ model could be implemented if all of the departments involved are well cooperated. PT. XYZ should also be able to make inventory control standards which are quantity order, order frequency, and reorder point. Keywords: Cost, EOQ, frequency, inventory, ROPABSTRAKPersediaan bahan baku pada perusahaan sangatlah penting, sehingga harus dapat dikendalikan. Pengendalian persediaan bahan baku yang baik harus didukung dengan efisiensi biaya. Penelitian ini untuk menganalisis faktor-faktor yang menyebabkan kondisi persediaan bahan baku base material berlebih di PT. XYZ dan menganalisis persediaan bahan baku base material agar dapat dikendalikan. Penelitian ini menggunakan metode fish bone dilanjutkan dengan metode

  5. Research on the property improvement of PVC using red mud in industrial waste residue

    Science.gov (United States)

    Nie, Xiaopeng; Li, Xingang; Shuai, Songxian

    2015-07-01

    Red mud is a red solid power waste that is discharged in the aluminium refinery industry during production. It is a strong alkali and can be categorized as polluting industrial residue. How to make comprehensive use of red mud has become a worldwide issue. In this paper, we put red mud into PVC (polyvinyl chloride polymer), taking advantage of the complicated chemical properties of red mud derived from the Bayer process. The results are compared with silica fume, coal ash and calcium carbonate under the same experimental conditions, which shows that improvement of PVC plastication can be achieved by adding red mud.

  6. The hydrolysis of agro-industrial residues by holocellulose-degrading enzymes.

    Science.gov (United States)

    Moreira, Leonora Rios de Souza; Ferreira, Gaspar Virgilio; Santos, Sheila Sousa Thurler; Ribeiro, Ana Paula Souza; Siqueira, Félix Gonçalves; Filho, Edivaldo Ximenes Ferreira

    2012-04-01

    Holocellulose structures from agro-industrial residues rely on main and side chain attacking enzymes with different specificities for complete hydrolysis. Combinations of crude enzymatic extracts from different fungal species, including Aspergillus terreus, Aspergillus oryzae, Aspergillus niger and Trichoderma longibrachiatum, were applied to sugar cane bagasse, banana stem and dirty cotton residue to investigate the hydrolysis of holocellulose structures. A. terreus and A. oryzae were the best producers of FPase and xylanase activities. A combination of A. terreus and A. oryzae extracts in a 50% proportion provided optimal hydrolysis of dirty cotton residue and banana stem. For the hydrolysis of sugar cane bagasse, the best results were obtained with samples only containing A. terreus crude extract.

  7. The hydrolysis of agro-industrial residues by holocellulose-degrading enzymes

    Directory of Open Access Journals (Sweden)

    Leonora Rios de Souza Moreira

    2012-06-01

    Full Text Available Holocellulose structures from agro-industrial residues rely on main and side chain attacking enzymes with different specificities for complete hydrolysis. Combinations of crude enzymatic extracts from different fungal species, including Aspergillus terreus, Aspergillus oryzae, Aspergillus niger and Trichoderma longibrachiatum, were applied to sugar cane bagasse, banana stem and dirty cotton residue to investigate the hydrolysis of holocellulose structures. A. terreus and A. oryzae were the best producers of FPase and xylanase activities. A combination of A. terreus and A. oryzae extracts in a 50% proportion provided optimal hydrolysis of dirty cotton residue and banana stem. For the hydrolysis of sugar cane bagasse, the best results were obtained with samples only containing A. terreus crude extract.

  8. Anaerobic Digestion of Laminaria japonica Waste from Industrial Production Residues in Laboratory- and Pilot-Scale

    Directory of Open Access Journals (Sweden)

    Yann Nicolas Barbot

    2015-09-01

    Full Text Available The cultivation of macroalgae to supply the biofuel, pharmaceutical or food industries generates a considerable amount of organic residue, which represents a potential substrate for biomethanation. Its use optimizes the total resource exploitation by the simultaneous disposal of waste biomaterials. In this study, we explored the biochemical methane potential (BMP and biomethane recovery of industrial Laminaria japonica waste (LJW in batch, continuous laboratory and pilot-scale trials. Thermo-acidic pretreatment with industry-grade HCl or industrial flue gas condensate (FGC, as well as a co-digestion approach with maize silage (MS did not improve the biomethane recovery. BMPs between 172 mL and 214 mL g−1 volatile solids (VS were recorded. We proved the feasibility of long-term continuous anaerobic digestion with LJW as sole feedstock showing a steady biomethane production rate of 173 mL g−1 VS. The quality of fermentation residue was sufficient to serve as biofertilizer, with enriched amounts of potassium, sulfur and iron. We further demonstrated the upscaling feasibility of the process in a pilot-scale system where a CH4 recovery of 189 L kg−1 VS was achieved and a biogas composition of 55% CH4 and 38% CO2 was recorded.

  9. The removal of dinitrochlorobenzene from industrial residuals by liquid-liquid extraction with chemical reaction

    Directory of Open Access Journals (Sweden)

    G. C. M. Ferreira

    2007-09-01

    Full Text Available Nitrochlorobenzenes (NCBs are very important in the chemical industry since they have been used as raw material for the manufacture of crop protection products, as active ingredients in the pharmaceutical industry, as pigments and as antioxidants as well as for other uses. In industrial processes, NCBs are produced by monochlorobenzene (MCB nitration reactions and one of the main residuals formed is dinitrochlorobenzene (DNCB, which is mainly composed of the isomer 2,4DNCB. This subproduct, although of commercial interest when in its pure state, is generally incinerated due to the high costs of recovery treatment and purification. The objective of this study is to present an alternative to the treatment of industrial residuals containing DNCB. The technique consists of converting DNCB into sodium dinitrophenolate, which is very soluble in water and is also easy to reuse. For this purpose, liquid-liquid extraction with chemical reaction (alkaline hydrolysis with a rotating disc contactor (RDC is used. Experimental data on MCB nitration reactions as well as alkaline hydrolysis using a rotating disc contactor are presented.

  10. An adsorbent with a high adsorption capacity obtained from the cellulose sludge of industrial residues.

    Science.gov (United States)

    Orlandi, Géssica; Cavasotto, Jéssica; Machado, Francisco R S; Colpani, Gustavo L; Magro, Jacir Dal; Dalcanton, Francieli; Mello, Josiane M M; Fiori, Márcio A

    2017-02-01

    One of the major problems in effluent treatment plants of the cellulose and paper industry is the large amount of residual sludge generated. Therefore, this industry is trying to develop new methods to treat such residues and to use them as new products, such as adsorbents. In this regard, the objective of this work was to develop an adsorbent using the raw activated sludge generated by the cellulose and paper industry. The activated cellulose sludge, after being dried, was chemically activated with 42.5% (v/v) phosphoric acid at 85 °C for 1 h and was charred at 500 °C, 600 °C and 700 °C for 2 h. The efficiency of the obtained adsorbent materials was evaluated using kinetic tests with methylene blue solutions. Using the adsorption kinetics, it was verified that the three adsorbents showed the capacity to adsorb dye, and the adsorbent obtained at a temperature of 600 °C showed the highest adsorption capacity of 107.1 mg g(-1). The kinetic model that best fit the experimental data was pseudo-second order. The Langmuir-Freudlich isotherm adequately described the experimental data. As a result, the cellulose sludge generated by the cellulose and paper industries could be used as an adsorbent.

  11. Anaerobic Digestion of Laminaria japonica Waste from Industrial Production Residues in Laboratory- and Pilot-Scale

    Science.gov (United States)

    Barbot, Yann Nicolas; Thomsen, Claudia; Thomsen, Laurenz; Benz, Roland

    2015-01-01

    The cultivation of macroalgae to supply the biofuel, pharmaceutical or food industries generates a considerable amount of organic residue, which represents a potential substrate for biomethanation. Its use optimizes the total resource exploitation by the simultaneous disposal of waste biomaterials. In this study, we explored the biochemical methane potential (BMP) and biomethane recovery of industrial Laminaria japonica waste (LJW) in batch, continuous laboratory and pilot-scale trials. Thermo-acidic pretreatment with industry-grade HCl or industrial flue gas condensate (FGC), as well as a co-digestion approach with maize silage (MS) did not improve the biomethane recovery. BMPs between 172 mL and 214 mL g−1 volatile solids (VS) were recorded. We proved the feasibility of long-term continuous anaerobic digestion with LJW as sole feedstock showing a steady biomethane production rate of 173 mL g−1 VS. The quality of fermentation residue was sufficient to serve as biofertilizer, with enriched amounts of potassium, sulfur and iron. We further demonstrated the upscaling feasibility of the process in a pilot-scale system where a CH4 recovery of 189 L kg−1 VS was achieved and a biogas composition of 55% CH4 and 38% CO2 was recorded. PMID:26393620

  12. The potential of agro-industrial residues for production of biogas and electricity in Tanzania

    Energy Technology Data Exchange (ETDEWEB)

    Kivaisi, A.K.; Rubindamayugi, M.S.T. [Applied Microbiology Unit, Dar es salaam (Tanzania, United Republic of). Botany Dept.

    1996-09-01

    This paper gives an overview of the energy demands in Tanzania, and highlights the current serious shortages of electricity. Government strategy to alleviate the problem include exploitation of the country`s big natural gas reserves for power generation, and utilization of the renewable energies such as solar, wind and biogas. Important agro-industrial residues with a large potential for anaerobic conversion into biogas and electricity are identified, and their production and locations are described. Tanzania generates a total of 468,100 tonnes organic matter from coffee, sisal, sugar and cereal residues annually. Laboratory scale determinations of methane yields from the residues gave 400m{sup 3} CH{sub 4}/ton VS of sisal pulp; 400 m{sup 3} CH{sub 4}/ton VS of sisal production wastewater; 650 m{sup 3} CH{sub 4}/ton VS of Robusta coffee solid waste; 730 m{sup 3} CH{sub 4}/tone of Arabica coffee solid waste; 230 m{sup 3} CH{sub 4}/ton VS of sugar filter mat and 450 m{sup 3} CH{sub 4}/ton VS maize bran. Based on these results the estimated total annual potential electricity production from these residues is 1,135 million kWh. The total oil substitution from these residues has been estimated at 0.32 million tonnes crude diesel oil per annum equivalent to 2% of the total energy consumption in Tanzania. Case studies of the coffee and sisal processing factories indicate that exploitation of the residues for the production of electricity on site of these factories is feasible. Utilization of agro-industrial residues for biogas production has a big potential for reduction of environmental pollution. The potential substitution of fossil fuel with biogas represents an annual reduction in the net CO{sub 2} emission to the atmosphere of approximately 1.05 million tonnes. By treating the residues in controlled anaerobic systems it is possible to reduce the methane emission by about 189 million m{sup 3}, and at the same time reduce contamination of surface and ground waters.

  13. Characterization of the Industrial Residues of Seven Fruits and Prospection of Their Potential Application as Food Supplements

    Directory of Open Access Journals (Sweden)

    Soraya de Oliveira Sancho

    2015-01-01

    Full Text Available Seven residues from tropical fruit (acerola, cashew apple, guava, mango, papaya, pineapple, and sapota processing were prospected for physicochemical parameters (pH, total soluble solids, water activity, reducing sugar, acidity, protein, moisture, ash, and lipids, functional compounds (total phenolic content, anthocyanins, ascorbic acid, and free radical scavenging activity—DPPH, fatty acid profile, and mineral content. Prospection of these industrial residues aimed its use as potential sources for food supplementation. Acerola residue was found to be a valuable source of anthocyanins, phenolics, and vitamin C; cashew apple residue could be a source of unsaturated fatty acids; pineapple and papaya residues could be used, respectively, as manganese and phosphorous source.

  14. STRATEGI PENINGKATAN DAYA SAING PT ‘ABCD’ TBK. DI INDUSTRI MAKANAN OLAHAN PADA TAHUN 2015

    Directory of Open Access Journals (Sweden)

    Kanya Lakshmi Sidarta

    2016-01-01

    Full Text Available The distribution of market share of Indonesia's processed food industry is dominated by only a few companies, i.e. one company representing 20% of market share, three companies representing 10% of market share, and 124 companies representing 35% of shares (2013, LEK insights. This condition is also shown by there are only 15 companies which are listed in Indonesian Stock Exchange (BEI as sub-sectors of food and beverages. CV 'ABCD', known as the 'ABCD', is one of the companies listed on the BEI on the sub-sectors of food and beverages. Thus, the purposes of this study were to examine the factors influencing the competition in the processed food industry in Indonesia, to analyze the competitiveness of 'ABCD' among other competing companies listed on BEI, and to propose alternative strategies to improve the competitiveness of 'ABCD' within the developing and challenging market. The analytical tools used in the study were Porter's Diamond Model, Firm Value Creation and AHP. The results showed that the factors affecting the competitiveness of the processed food industry in Indonesia, in reference to Porter's Diamond Model, is the availability of products (good quality & innovative, the number of requests, the decision-making process with a clear purpose, value creation, and good internal and external relations. The alternative strategy proposed in enhancing the competitiveness of 'ABCD' is improving quality standards in an integrated system by the CEO (owner and Director of Marketing as the main actors in the clear decision process.Keywords: AHP, competitiveness, diamond porter, processed food industry, BEI

  15. Optimization of the extraction process of polyphenols from cashew apple agro-industrial residues

    Directory of Open Access Journals (Sweden)

    Renata Araújo Milanez de Sena Andrade

    2015-06-01

    Full Text Available The goal of this study was to determine the chemical composition of cashew apples agro-industrial residue and optimize the process of polyphenols extraction in this residue. The extraction process conditions were defined using a 24-1 fractional factorial experimental design using acetone and methanol as solvents. The independent variables were: time (30 to 90 min, temperature (30 to 50 °C, solvent concentrations (50% to 90%, agitation speed (100 to 300 rpm; the dependent variables were: total phenolic content and DPPH scavenging capacity. The optimized process was carried out by applying the Central Composite Rotational Design (CCRD considering the results obtained with the 24-1 fractional factorial experimental design. The residue presented bioactive compounds in its composition, with emphasis on the content of total phenolic compounds (1975.64 mg/ 100 g. The extraction process was not affected by methanol; however, acetone affected the amounts of extracted phytochemicals. Extracts with high levels of polyphenols and strong DPPH scavenging capacity (> 80% were obtained using 55% acetone, 30 minutes, 30 °C, and 150 rpm. The results showed that cashew apple residue is a potential natural source of bioactive compounds with strong antioxidant capacity. These compounds could be used partially or totally to replace synthetic antioxidants.

  16. Thermal Analysis of a Thermal Energy Storage Unit to Enhance a Workshop Heating System Driven by Industrial Residual Water

    National Research Council Canada - National Science Library

    Wenqiang Sun; Zuquan Zhao; Yanhui Wang

    2017-01-01

    .... However, the majority of applicable waste heat resources are high-grade or stable thermal energy, while the low-grade or unstable waste heat resources, especially low-temperature industrial residual water (IRW...

  17. Agriculture-industrial residues x natural gas. An economic of energy analysis

    Energy Technology Data Exchange (ETDEWEB)

    Avellar, L.H.N. [Pos-Graduacao em Engenharia Mecanica, Guaratingueta, SP (Brazil); Carrocci, L.R.; Silveira, J.L.; Oliva, V.J. [Universidade Estadul Paulista, Guaratingueta, SP (Brazil). Faculdade de Engenharia de Guaratingueta

    1999-07-01

    In this paper are presented following, as it's main objective, an economic analysis between biogas coming from agriculture-industrial-residues and natural gas. Above all, also make part of this work, illustrating figures of the most used types of biodigestors in Brazil and all of world, and briefly descriptions of the most used control and reduction technologies of the pollutants emissions from the combustion process through in the atmosphere. Must emphasise, above technical-scientific importance of this work, it's social -economic part at the poignant of the residues seizing with considerable calorific power for the energy generation, thereby promoting the ambiental pollution retrenchment (also detach here), looking for, in a coming future, the sustainable development at all of it completeness.

  18. Polyhydroxybutyrate production using agro-industrial residue as substrate by Bacillus sphaericus NCIM 5149

    Directory of Open Access Journals (Sweden)

    Nisha V. Ramadas

    2009-02-01

    Full Text Available The aim of this work was to study the production of polyhydroxybutyrate (PHB using agro- industrial residues as the carbon source. Seven substrates, viz., wheat bran, potato starch, sesame oil cake, groundnut oil cake, cassava powder, jackfruit seed powder and corn flour were hydrolyzed using commercial enzymes and the hydrolyzates assessed for selecting the best substrate for PHB production. Jackfruit seed powder gave the maximum production of PHB under submerged fermentation using Bacillus sphaericus (19% at the initial pH of 7.5.

  19. Atomically flat surface of (0 0 1) textured FePt thin films by residual stress control

    Science.gov (United States)

    Liu, S. H.; Hsiao, S. N.; Chou, C. L.; Chen, S. K.; Lee, H. Y.

    2015-11-01

    Single-layered Fe52Pt48 films with thickness of 10 nm were sputter-deposited on glass substrates. Rapid thermal annealing with different heating rates (10-110 K/s) was applied to transform as-deposited fcc phase into L10 phase and meanwhile to align [0 0 1]-axis of L10 crystal along plane normal direction. Based on X-ray diffractometry using synchrotron radiation source, the texture coefficient of (0 0 1)-plane increases with increasing heating rate from 10 to 40 K/s, which is correlated with perpendicular magnetic anisotropy and in-plane tensile stress analyzed by asymmetric sin2 ψ method. Furthermore, it was revealed by atomic force microscopy that the dewetting process occurred as heating rate was raised up to 80 K/s and higher. The change in the microstructure due to stress relaxation leads to the degradation of (0 0 1) orientation and magnetic properties. Surface roughness is closely related to the in-plane tensile stress. Enhanced perpendicular magnetic anisotropy and atomically flat surface were achieved for the samples annealed at 40 K/s, which may be suitable for further practical applications. This work also suggests a feasible way for surface engineering by controlling internal stress of the FePt without introducing cap layer.

  20. Stability of the anthocyanins extracted from residues of the wine industry

    Directory of Open Access Journals (Sweden)

    Edmar Clemente

    2011-09-01

    Full Text Available Anthocyanins are highly important due to their antioxidant capacity. They are the most important among the phenolic compounds and one of the main natural dyes used in the food industry. In this research, residue of processed grapes was used to investigate the presence of anthocyanins, the possibility of their extraction from the residue, and their stability. The extraction solution consisted of 70 mL of ethanol 70% and 30 mL of HCl 0.1% at pH 2.0. The results found for the processed grapes residue was 26.20 mg.100 g-1. In order to evaluate stability, caffeic acid was added at 0.5:1 w/v; 0.8:1 w/v; and 1:1 w/v concentrations. Anthocyanins extract reached the greatest stability at 0.5:1 w/v concentration, with 82.47% color retention and a half-life period of 15 days. Therefore, the use of this organic acid as a stabilizer for anthocyanins is feasible.

  1. PERUMUSAN STRATEGI KEMITRAAN MENGGUNAKAN METODE AHP DAN SWOT (Studi Kasus pada Kemitraan PT. INKA dengan Industri Kecil Menengah di Wilayah Karesidenan Madiun

    Directory of Open Access Journals (Sweden)

    Eko Nurmianto

    2004-01-01

    Full Text Available Research on Partnership strategy between PT. INKA and SMI (Small Medium Industry conducted using Analytical Hierarchy Process (AHP and SWOT Analysis. Problem statement: (1 Type of criteria required to build Partnership Strategy (2 How to formulate Partnership Strategy between them. Results: (1 Performance of partnership model as follows : effectivity, profesionalism, supervisory, controlship, financial, development potency, and birocration procedure. (2 Weighted criteria effectivity 0.354, profesionalism 0.24, birocration procedure 0.159, supervisory 0.104, controlship 0.068, development potency 0.045, and financial 0.031. Model 2 (proposed is a partnership model on partnership development between PT. INKA and SMI with the management of Financial Management Council (Badan Pengelola Dana BUMN. Abstract in Bahasa Indonesia : Perumusan strategi kemitraan PT. INKA dan Industri Kecil Menengah diteliti menggunakan AHP dan SWOT. Permasalahan adalah kriteria-kriteria yang dibutuhkan dalam menyusun dan merumuskan strategi kemitraan antara PT. INKA dan industri kecil binaan. Hasil penelitian (1 Penilaian kinerja dari model kemitraan terdapat beberapa kriteria yang digunakan yaitu: efektivitas, profesionalitas, pembinaan, pengawasan, modal, potensi pengembangan, dan prosedur birokrasi. (2 Bobot kriteria: efektivitas 0.354, profesionalitas 0.24, prosedur birokrasi 0.159, pembinaan 0.104, pengawasan 0.068, potensi pengembangan 0.045, dan modal 0.031. Model 2 (usulan adalah model kemitraan yang memfokuskan pengembangan kemitraan antara PT. INKA dan IKM dengan pengelolaan yang lebih profesional dengan adanya Badan Pengelola Dana BUMN yang bersifat mandiri. Kata kunci: Perumusan strategi, AHP, SWOT, Model kemitraan BUMN-IKM.

  2. The use tracer radioactive in the station of treatment residual of in the oil industry

    Energy Technology Data Exchange (ETDEWEB)

    Damera, A.; Ramos, K. [Center of Attention to the Nuclear Activity, City of Camaguey (Cuba); Ferreira, A.; Magalhaes, A. [Centro of Development of Nuclear Technology, Mines Gerais (Brazil); Derivet, M. [Cuban Institute of Sugar Investigations, Havana (Cuba)

    2001-07-01

    The industry of the petroleum comes being in you finish them decades, an user of the Nuclear Techniques, overalls starting from the II World War, when sources radioactive and new techniques passed the investigators' disposition and technicians of the civil sector. Due to the amplification of activities in some of the technical and economic characteristics of this industry the possibilities of application of the nuclear techniques are proportionally bigger and more important than in many other sectors of the economy. This work was carried out in the Station of Treatment of Residual Industrial (ETDI) in PETROBRAS (Brazil). The ETDI has the function of receiving, to store and to try the you discard liquids and gassy coming from diverse points of the refinery avoiding this way the contamination of the environment. The work consisted on the determination of the time of residence inside the flocculators and the floats, for it was used it the nuclear technique of radioactive radiotracer, concretely the Technetium 99 m. This has a great economic and environmental importance, because when obtaining the time of real.. residence experimentally in the flocculators and the floats, you can compare with those obtained theoretically and to influence on the system, optimizing their operation. (authors)

  3. Electrochemical treatment of evaporated residue of soak liquor generated from leather industry

    Energy Technology Data Exchange (ETDEWEB)

    Boopathy, R.; Sekaran, G., E-mail: ganesansekaran@gmail.com

    2013-09-15

    Highlights: • Electrochemical treatment of evaporated residue of soak liquor (ERSL) generated in Tannery. • Copper coating on electrode surface and horizontal mounting of electrodes for ERSL treatment. • Electrochemical oxidation of organic pollutants under high saline condition. • The treated solution may be evaporated to dryness to get NaCl salt for hide/skin preservation. -- Abstract: The organic and suspended solids present in soak liquor, generated from leather industry, demands treatment. The soak liquor is being segregated and evaporated in solar evaporation pans/multiple effect evaporator due to non availability of viable technology for its treatment. The residue left behind in the pans/evaporator does not carry any reuse value and also faces disposal threat due to the presence of high concentration of sodium chloride, organic and bacterial impurities. In the present investigation, the aqueous evaporated residue of soak liquor (ERSL) was treated by electrochemical oxidation. Graphite/graphite and SS304/graphite systems were used in electrochemical oxidation of organics in ERSL. Among these, graphite/graphite system was found to be effective over SS304/graphite system. Hence, the optimised conditions for the electrochemical oxidation of organics in ERSL using graphite/graphite system was evaluated by response surface methodology (RSM). The mass transport coefficient (k{sub m}) was calculated based on pseudo-first order rate kinetics for both the electrode systems (graphite/graphite and SS304/graphite). The thermodynamic properties illustrated the electrochemical oxidation was exothermic and non-spontaneous in nature. The calculated specific energy consumption at the optimum current density of 50 mA cm{sup −2} was 0.41 kWh m{sup −3} for the removal of COD and 2.57 kWh m{sup −3} for the removal of TKN.

  4. Bio-syngas production from agro-industrial biomass residues by steam gasification.

    Science.gov (United States)

    Pacioni, Tatiana Ramos; Soares, Diniara; Domenico, Michele Di; Rosa, Maria Fernanda; Moreira, Regina de Fátima Peralta Muniz; José, Humberto Jorge

    2016-12-01

    This study evaluated the steam gasification potential of three residues from Brazilian agro-industry by assessing their reaction kinetics and syngas production at temperatures from 650 to 850°C and a steam partial pressure range of 0.05 to 0.3bar. The transition temperature between kinetic control and diffusion control regimes was identified. Prior to the gasification tests, the raw biomasses, namely apple pomace, spent coffee grounds and sawdust, were pyrolyzed in a fixed-bed quartz tubular reactor under controlled conditions. Gasification tests were performed isothermally in a magnetic suspension thermobalance and the reaction products were analyzed by a gas chromatograph with TCD/FID detectors. According to the characterization results, the samples presented higher carbon and lower volatile matter contents than the biomasses. Nevertheless, all of the materials had high calorific value. Syngas production was influenced by both temperature and steam partial pressure. Higher concentrations of H2 and CO were found in the conversion range of 50-80% and higher concentrations of CO2 in conversions around 10%, for all the gasified biochars. The H2/CO decreased with increasing temperature, mainly in kinetic control regime, in the lower temperature range. The results indicate the gasification potential of Brazilian biomass residues and are an initial and important step in the development of gasification processes in Brazil. Copyright © 2016 Elsevier Ltd. All rights reserved.

  5. Hydrothermal Synthesis of Xonotlite-type Calcium Silicate Insulation Material Using Industrial Zirconium Waste Residue

    Institute of Scientific and Technical Information of China (English)

    JIANG Jinguo; CUI Chong; LIU Jinqiang; LIAO Wenli

    2011-01-01

    Xonotlite-type insulation material was prepared by hydrothermal synthesis technology using industrial zirconium waste residue in this paper, and the phase analysis together with the observation of micro-morphology were also carried out by XRD, SEM and TEM. The density and thermal conductivity were measured finally. The results indicate, chlorine ion impurity contained in zirconium waste residue can be removed effectively via water washed process, and the reactive activity of silicon dioxide is almost not affected,which make it be a good substitution of silicon material for the preparation of calcium silicate insulation material by hydrothermal synthesis technique. The density and thermal conductivity of xonotlite-type calcium silicate insulation material obtained by hydrothermal synthesis technique can reach 159 kg/m3, 0.049 W/(m·°C), respectively, meeting with National Standard well, when synthesis conditions are selected as follows: Ca/Si molar ratio equal to 1, synthesis temperature at 210 ℃ and kept for 8 hrs. It provides a new approach to realize lightweight and low thermal conductivity of calcium silicate insulation material.

  6. Lactobacillus plantarum BL011 cultivation in industrial isolated soybean protein acid residue

    Directory of Open Access Journals (Sweden)

    Chaline Caren Coghetto

    Full Text Available Abstract In this study, physiological aspects of Lactobacillus plantarum BL011 growing in a new, all-animal free medium in bioreactors were evaluated aiming at the production of this important lactic acid bacterium. Cultivations were performed in submerged batch bioreactors using the Plackett-Burman methodology to evaluate the influence of temperature, aeration rate and stirring speed as well as the concentrations of liquid acid protein residue of soybean, soy peptone, corn steep liquor, and raw yeast extract. The results showed that all variables, except for corn steep liquor, significantly influenced biomass production. The best condition was applied to bioreactor cultures, which produced a maximal biomass of 17.87 g L-1, whereas lactic acid, the most important lactic acid bacteria metabolite, peaked at 37.59 g L-1, corresponding to a productivity of 1.46 g L-1 h-1. This is the first report on the use of liquid acid protein residue of soybean medium for L. plantarum growth. These results support the industrial use of this system as an alternative to produce probiotics without animal-derived ingredients to obtain high biomass concentrations in batch bioreactors.

  7. Lactobacillus plantarum BL011 cultivation in industrial isolated soybean protein acid residue.

    Science.gov (United States)

    Coghetto, Chaline Caren; Vasconcelos, Carolina Bettker; Brinques, Graziela Brusch; Ayub, Marco Antônio Záchia

    In this study, physiological aspects of Lactobacillus plantarum BL011 growing in a new, all-animal free medium in bioreactors were evaluated aiming at the production of this important lactic acid bacterium. Cultivations were performed in submerged batch bioreactors using the Plackett-Burman methodology to evaluate the influence of temperature, aeration rate and stirring speed as well as the concentrations of liquid acid protein residue of soybean, soy peptone, corn steep liquor, and raw yeast extract. The results showed that all variables, except for corn steep liquor, significantly influenced biomass production. The best condition was applied to bioreactor cultures, which produced a maximal biomass of 17.87gL(-1), whereas lactic acid, the most important lactic acid bacteria metabolite, peaked at 37.59gL(-1), corresponding to a productivity of 1.46gL(-1)h(-1). This is the first report on the use of liquid acid protein residue of soybean medium for L. plantarum growth. These results support the industrial use of this system as an alternative to produce probiotics without animal-derived ingredients to obtain high biomass concentrations in batch bioreactors.

  8. Industrial demonstration plant for the gasification of herb residue by fluidized bed two-stage process.

    Science.gov (United States)

    Zeng, Xi; Shao, Ruyi; Wang, Fang; Dong, Pengwei; Yu, Jian; Xu, Guangwen

    2016-04-01

    A fluidized bed two-stage gasification process, consisting of a fluidized-bed (FB) pyrolyzer and a transport fluidized bed (TFB) gasifier, has been proposed to gasify biomass for fuel gas production with low tar content. On the basis of our previous fundamental study, an autothermal two-stage gasifier has been designed and built for gasify a kind of Chinese herb residue with a treating capacity of 600 kg/h. The testing data in the operational stable stage of the industrial demonstration plant showed that when keeping the reaction temperatures of pyrolyzer and gasifier respectively at about 700 °C and 850 °C, the heating value of fuel gas can reach 1200 kcal/Nm(3), and the tar content in the produced fuel gas was about 0.4 g/Nm(3). The results from this pilot industrial demonstration plant fully verified the feasibility and technical features of the proposed FB two-stage gasification process.

  9. Analysis of hazardous organic residues from sodium hydrosulfite industry and utilization as raw materials in a novel solid lubricant production

    Energy Technology Data Exchange (ETDEWEB)

    Shang, Jiwu [State Key Laboratory of Geological Processes and Mineral Resources, National Laboratory of Mineral Materials, School of Materials Science and Technology, China University of Geosciences, Beijing 100083 (China); Zhang, Yihe, E-mail: zyh@cugb.edu.cn [State Key Laboratory of Geological Processes and Mineral Resources, National Laboratory of Mineral Materials, School of Materials Science and Technology, China University of Geosciences, Beijing 100083 (China); Department of Physics and Materials Science, City University of Hong Kong, Tat Chee Avenue, Kowloon, Hong Kong (China); Zhou, Fengshan; Lv, Fengzhu; Han, Feng; Lu, Jinbo; Meng, Xianghai [State Key Laboratory of Geological Processes and Mineral Resources, National Laboratory of Mineral Materials, School of Materials Science and Technology, China University of Geosciences, Beijing 100083 (China); Chu, Paul K. [Department of Physics and Materials Science, City University of Hong Kong, Tat Chee Avenue, Kowloon, Hong Kong (China); Ye, Zhengfang [Department of Environmental Engineering, Key Laboratory of Water and Sediment Sciences of the Ministry of Education, Peking University, Beijing 100871 (China); Xing, Jing [State Key Laboratory of Geological Processes and Mineral Resources, National Laboratory of Mineral Materials, School of Materials Science and Technology, China University of Geosciences, Beijing 100083 (China)

    2011-12-30

    Highlights: Black-Right-Pointing-Pointer The hazardous organic residual wastes produced by the sodium hydrosulfite industry are analyzed and the main compounds are found to be thiodiglycol and 2,2 Prime -dithiodiethanol. Black-Right-Pointing-Pointer The lubricity of the organic residues is subsequently studied and the homemade solid lubricant is observed to have good lubricity. Black-Right-Pointing-Pointer The clean process is expected to not only have commercial impact but also help to reduce environmental pollution. - Abstract: The hazardous organic residual wastes produced by the sodium hydrosulfite industry are demonstrated to be convertible into a novel solid lubricant. Identification and isolation of the organic residues are achieved by Fourier transform infrared (FTIR) spectroscopy, gas chromatography-mass spectrometry (GC-MS), and nuclear magnetic resonance (NMR). FTIR and GC-MS provide important information about the residues and the two main components obtained by column chromatography are further analyzed by NMR. The main organic residues are found to be thiodiglycol and 2,2 Prime -dithiodiethanol which have potential applications in petroleum drilling because of their S-S and/or C-S functional groups. The lubricity of the organic residues is subsequently studied and the influence of different adsorbents on the lubricity is investigated and discussed. This homemade lubricant is observed to have good lubricity and by increasing the concentration of the commercial solid lubricant M, the lubricity diminishes. The process is expected to not only have commercial impact but also help to reduce environmental pollution.

  10. Agro-industry sugarcane residues disposal: the trends of their conversion into energy carriers in Cuba.

    Science.gov (United States)

    Alonso Pippo, W; Garzone, P; Cornacchia, G

    2007-01-01

    The goal of the present work was to carry out a review of the disposal practices for the agro-industry's sugarcane residue and the trends of energy use in Cuba. The lack of an alternative energy carrier to electricity with storage capability for use in off-season has to date been an unsolvable question. The improvement of cogeneration capacity via implementation of CEST or BIG/GTCC and the barriers for their implementation, the introduction of a medium size (3 ton/h) fast pyrolysis module (FPM3) as a solution for off-season energy demand in the agro-industry, and an assessment of the energy required to do so, were also analyzed. Bio-oil production from bagasse and sugarcane agriculture residues (SCAR) and their particularities at the sugar mill are treated. The influence of sugar facility production process configuration is analyzed. The fast pyrolysis products and the trends of their end uses in Cuba are presented. The production cost of a ton of Bio-oil for FPM3 conditions was calculated at 155 USD/ton and the payback time as a function of selling price between 160 and 110 USD/ton was estimated to be from 1.5 to 4 years. The economic feasibility of the FPM3 was estimated, comparing the added values for three scenarios: 1st case, currently-used sugar production, 16.5 USD/ton of cane; 2nd case, factoring in the cogeneration improvement, 27 USD/ton of cane; and 3rd case, with cogeneration improvement and Bio-oil production, 40 USD/ton of cane. The energy use of SCAR and the introduction of FPM3 in the sugar mill are promising improvements that could result in a potential surplus of 80 kWh(e)/ton of cane in-season, or 6 x 10(6)ton of Bio-oil (LHV=15 MJ/kg) for use off-season in a milling season of 4 million tons of raw sugar.

  11. Combined incineration of industrial wastes with in-plant residues in fluidized-bed utility boilers--decision relevant factors.

    Science.gov (United States)

    Ragossnig, Arne M; Lorber, Karl E

    2005-10-01

    In Austria more than 50% of the high-calorific industrial residues and wastes generated are utilized for energy recovery in industrial utility boilers. This study investigated full-scale trials of combined incineration of in-plant residues with various industrial wastes. These trials were carried out in order to learn how the alternatively used fuel influences the incineration process itself as well as the quantity and quality of the various incineration products. The currently used fuel, which consisted of in-plant residues as well as externally acquired waste wood and the refuse-derived fuel (RDF) mixtures used during the full-scale trials are characterized in terms of material composition as well as chemical and physical parameters. An input-output mass balance for the incineration plant (two fluidized bed combustion units, 20 and 30 MW, respectively) has been established, based on the data collected during the full-scale incineration trials. Furthermore, pollutant concentrations in the off-gas as well as the solid incineration residue are reported. It is not only the pollutant content but also a variety of other internal as well as external factors that have to be considered if a company is to decide whether or not to thermally utilize specific waste types. Therefore a strengths and weaknesses profile for several types of waste and the specific industrial boiler is also presented.

  12. Study on vacuum pyrolysis of coffee industrial residue for bio-oil production

    Science.gov (United States)

    Chen, Nanwei; Ren, Jie; Ye, Ziwei; Xu, Qizhi; Liu, Jingyong; Sun, Shuiyu

    2017-03-01

    Coffee industrial residue (CIR) is a biomass with high volatile content (64.94 wt.%) and heating value (21.3 MJ·kg-1). This study was carried out to investigate the pyrolysis condition and products of CIR using thermogravimetric analyser (TGA) and vacuum tube furnace. The influence of pyrolysis temperature, time, pressure and heating rate on the yield of pyrolysis products were discussed. There was an optimal pyrolysis condition: CIR was heated from normal temperature to 400 °C for 60 min, with 10 °C·min-1 heating rate and a pressure of 30 kPaabs. In this condition, the yields of bio-oil, char and non-condensable gas were 42.29, 33.14 and 24.57 wt.%, respectively. The bio-oil contained palmitic acid (47.48 wt.%), oleic acid (17.45 wt.%), linoleic acid (11.34 wt.%), octadecanoic acid (7.62 wt.%) and caffeine (5.18 wt.%).

  13. Effects of various agro-industrial residues on soil fertility and yield and quality of potatoes.

    Science.gov (United States)

    Elmaci, O L; Seçer, M; Ceylan, S

    2012-07-01

    Nine combinations of production residues of agro-industries, urban wastes and mineral fertilizers were applied to potatoes (Solanum tuberosum var. Marabel) in a field experiment, and the effect of these combinations on soil characteristics, on yield and on various quality parameters of tubers were determined. The applications significantly affected soil pH, CaCO3 and organic matter content. Total N and available P and K levels of soils showed significant differences between the applications. The content of available Zn and Mn in the soil differed significantly between the applications. Sufficient levels of N, P and K were not attained in leaves in any application. Significant differences were observed between the P content of the leaves of the control and of the other applications. Potassium and Na content of the leaves showed significant variations between the applications. Manganese was at a statistically higher level in the leaves of some combinations. The nitrogen, P and Mn contents of tubers differed significantly between the applications. Phosphorus, K, Mg and Cu levels were found to be sufficient, but Fe, Zn and Mn were low in tubers. Tuber yield was statistically highest in the Wastes P + Mineral NK combination. Reduced sugar and protein content of the tubers was affected significantly by the applications. Significant correlations were found between soil, leaf and tubers.

  14. Studies on the utilization of agricultural residues in the manufacture of pulp and paper, and industrial chemicals

    Energy Technology Data Exchange (ETDEWEB)

    Joshi, V.S.; Kamath, G.P.; Basu, S.

    1980-03-15

    While demand for pulp and paper products in India is increasing at the annual rate of 7 to 8%, availability of cellulosic raw material to meet the ever increasing demand is becoming a serious problem. It has been estimated that bamboo, the traditional source of cellulosic raw material in India, even after ensuring the most scientific and best possible exploitation, could provide less than 50% of the requirement. In a big agricultural country like India, agri-residues like straws and bagasse, along with jute sticks, available in huge quantity, could provide substantial amount of cellulosic resources to the pulp and paper industry. Realizing the importance of agri-residue utilization in Indian economy, a series of research projects have been initiated and completed during the last 15 years to study the techno-economic feasibility of manufacturing pulp, paper, and industrial chemicals, based on rice and wheat straws, bagasse, and jute sticks. The economic advantages of the mechano-chemical pulping process, as compared to the conventional pressure, pulping process, for the conversion of agri-residues into pulp and paer is evaluated. For highlighting the importance of agri-residues in the field of useful chemical recovery possibilities, experimental data are given on the saccarification of agri-residues into reducing sugars by the simple acid hydrolysis method with the help of concentrated sulfuric acid.

  15. Thermoanalytical and starch content evaluation of cassava bagasse as agro-industrial residue

    Directory of Open Access Journals (Sweden)

    Luiz Gustavo Lacerda

    2009-11-01

    Full Text Available Starch nutritional fractions as well as thermal properties and other analysis are essential for food and industrial application. Cassava bagasse is an important agro-industrial residue and its starch content was evaluated using two alternative methods. Thermal characterization and microscopy analyses helped to understand how hydrolysis digests starchy fraction of cassava bagasse. The melting point of cassava starch occurred at 169.2ºC. Regarding TG analyses, after moisture content, there were observed two main mass losses for all samples. Results suggest hydrolysis carried out using enzyme is less effective in order to convert total starch content in cassava bagasse. However, using sulfuric acid, fibers are affected by analyses conditions.As frações nutricionais bem como as propriedades térmicas e outras análises são essenciais para a indústria de alimentos e suas aplicações O bagaço de mandioca é um importante resíduo agroindustrial e seu teor de amido foi avaliado por dois métodos alternativos. A caracterização por análise térmica e microscopia ajudou na compreensão de como a hidrólise digere a fração amilácea do bagaço de mandioca, O ponto de fusão foi de 170ºC, a análise termogravimétrica (TG mostrou após a perda de umidade do material, duas principais perdas de massa em todas as amostras analisadas. Os resultados sugerem que a hidrólise enzimática é menos eficiente na conversão total de amido no bagaço de mandioca. No entanto, o uso de ácido sulfúrico degradou até mesmo a parcela fibrosa do material, afetando as condições de análise.

  16. PENGENDALIAN LANTAI PABRIK DENGAN LOAD ORIENTED MANUFACTURING CONTROL PADA INDUSTRI MEBEL (STUDI KASUS PT “X”

    Directory of Open Access Journals (Sweden)

    Sri Hartini

    2012-02-01

    Full Text Available Load Oriented Manufacturing Control (LOMC is an input-output control system development thatconsidered work load in every work center. Production planning starts with determining production leadtime, then work load control (WLC. WLC consist of defining criteria and determining release procedure tothe shop floor for items that will be processed. This research tried to implement LOMC concept in afurniture company called PT.X. The result of the research showed that LOMC could improve throughputand minimize work in process (WIP.

  17. Optimization of manganese peroxidase production from Schizophyllum sp. F17 in solid-state fermentation of agro-industrial residues.

    Science.gov (United States)

    Zhou, Yue; Yang, Bing; Yang, Yang; Jia, Rong

    2014-03-01

    Manganese peroxidase (MnP), a crucial enzyme in lignin degradation, has wide potential applications in environmental protection. However, large-scale industrial application of this enzyme is limited due to several factors primarily related to cost and availability. Special attention has been paid to the production of MnP from inexpensive sources, such as lignocellulosic residues, using solid-state fermentation (SSF) systems. In the present study, a suitable SSF medium for the production of MnP by Schizophyllum sp. F17 from agro-industrial residues has been optimized. The mixed solid medium, comprising pine sawdust, rice straw, and soybean powder at a ratio of 0.52:0.15:0.33, conferred a maximum enzyme activity of 11.18 U/g on the sixth day of SSF. The results show that the use of wastes such as pine sawdust and rice straw makes the enzyme production more economical as well as helps solve environmental problems.

  18. Validated electrochemical and chromatographic quantifications of some antibiotic residues in pharmaceutical industrial waste water.

    Science.gov (United States)

    Ibrahim, Heba K; Abdel-Moety, Mona M; Abdel-Gawad, Sherif A; Al-Ghobashy, Medhat A; Kawy, Mohamed Abdel

    2017-03-01

    Realistic implementation of ion selective electrodes (ISEs) into environmental monitoring programs has always been a challenging task. This could be largely attributed to difficulties in validation of ISE assay results. In this study, the electrochemical response of amoxicillin trihydrate (AMX), ciprofloxacin hydrochloride (CPLX), trimethoprim (TMP), and norfloxacin (NFLX) was studied by the fabrication of sensitive membrane electrodes belonging to two types of ISEs, which are polyvinyl chloride (PVC) membrane electrodes and glassy carbon (GC) electrodes. Linear response for the membrane electrodes was in the concentration range of 10(-5)-10(-2) mol/L. For the PVC membrane electrodes, Nernstian slopes of 55.1, 56.5, 56.5, and 54.0 mV/decade were achieved over a pH 4-8 for AMX, CPLX, and NFLX, respectively, and pH 3-6 for TMP. On the other hand, for GC electrodes, Nernstian slopes of 59.1, 58.2, 57.0, and 58.2 mV/decade were achieved over pH 4-8 for AMX, CPLX, and NFLX, respectively, and pH 3-6 for TMP. In addition to assay validation to international industry standards, the fabricated electrodes were also cross-validated relative to conventional separation techniques; high performance liquid chromatography (HPLC), and thin layer chromatography (TLC)-densitometry. The HPLC assay was applied in concentration range of 0.5-10.0 μg/mL, for all target analytes. The TLC-densitometry was adopted over a concentration range of 0.3-1.0 μg/band, for AMX, and 0.1-0.9 μg/band, for CPLX, NFLX, and TMP. The proposed techniques were successfully applied for quantification of the selected drugs either in pure form or waste water samples obtained from pharmaceutical plants. The actual waste water samples were subjected to solid phase extraction (SPE) for pretreatment prior to the application of chromatographic techniques (HPLC and TLC-densitometry). On the other hand, the fabricated electrodes were successfully applied for quantification of the antibiotic residues in actual

  19. International Institute of Welding work on residual stress and its application to industry

    Energy Technology Data Exchange (ETDEWEB)

    Janosch, Jean-Jacques [Caterpillar France, 40 Avenue Leon-Blum, 38041 Grenoble (France)], E-mail: janosch_jean-jacques@cat.com

    2008-03-15

    This paper gives an overview of the International Institute of Welding (IIW) activity on residual stress and distortion prediction (RSDP) in welded structures. The overall goal of the activity is to define an IIW recommendation for prediction and determination of welding residual stress and distortion. The three main collaborative activities that were launched to support this goal (a modelling round robin, a measurement technique benchmark and definition of a compendium) are described. It is concluded that significant progress has been achieved by participants to improve the modelling approaches, and to optimize experimental technologies to calculate and measure accurately the residual stress distribution and distortion in welded assemblies.

  20. The potential of agro-industrial residues and municipal solid waste for production of biogas and electricity in Tanzania

    Energy Technology Data Exchange (ETDEWEB)

    Kivaisi, A.K. [Univ. of Dar es Salaam, Botany Dept., Applied Microbiology Unit (Tanzania, United Republic of)

    1997-12-31

    This paper gives an overview of the energy demands in Tanzania, and highlights the current serious shortage of electricity. Government strategy to alleviate the problem include exploitation of the country`s big natural gas reserves for power generation, and utilization of the renewable energies such as solar, wind and biogas. Important agro-industrial residues and municipal solid wastes with large potentials for anaerobic converstion into biogas and electricity have been identified and quantified. Tanzania is estimated to generate about 615,000 organic matter from coffee, sisal, sugar and cereal residues and households in main towns are estimated to generate about 600,000 tons of organic matter annually. Laboratory scale determinations of methane yields from the residues gave 400 m{sup 3} CH{sub 4}/ton VS of sisal pulp; 400 m{sup 3} CH{sub 4}/ton VS of sisal production wastewater; 400 m{sup 3} CH{sub 4}/ton VS of Robusta coffee solid waste, 350 m{sup 3} CH{sub 4}/ton VS of sugar processing wastewater; 250 m{sup 3} CH{sub 4}/ton VS of sugar filter mat, 450 m{sup 3} CH{sub 4}/ton VS maize bran and 300 m{sup 3} CH{sub 4}/ton VS of mixed household waste. Based on these results the estimated total annual potential electricity production from these residues is 1.4 million MW. The total oil substitution from these residues has been estimated at 0.35 million tonnes crude diesel oil per annum equivalent to 2% of the total energy consumption in Tanzania. Case studies onthe coffee and sisal processing factories indicate that exploitation of the residues for the production of electricity on site these factories is feasible. Utilization of agro-industrial residues and municipal waste for biogas production has enormous potential for reduction of environmental pollution. The potential substitution of fossil fuel with biogas represents an annual reduction in the net CO{sub 2} emission to the atmosphere of approximately 1.3 million tonnes. By treating the residues in controlled

  1. Distinguishing between chemical and physical promotion mechanisms by CeO{sub 2} in Pt, Rh three-way automotive catalysts under practical industrial conditions

    Energy Technology Data Exchange (ETDEWEB)

    Robota, H.J.; Nunan, J.G. [Allied-Signal Research and Technology, Des Plains, IL (United States)

    1993-12-31

    Under practical industrial conditions, aged, rather than fresh, catalyst performances is required to meet various regulatory emissions levels. While CeO{sub 2} is recognized as critical in allowing practically aged Pt, Rh catalysts to meet these performance targets, debate continues concerning the physicochemical mechanisms responsible for the performance enhancement. Suppressed precious metal sintering and stabilization of support {gamma}-Al{sub 2}O{sub 3} against surface area loss and structural phase changes are the principle physical mechanisms suggested. Chemical promotion by CeO2 has been attributed to oxygen storage, enhanced water gas shift activity, and enhanced CO oxidation activity through a precious metal-CeO2 coupling mechanisms. The authors have attempted to distinguish the relative contributions of these physical and chemical mechanisms to the performance of practical Pt, Rh catalysts. Two catalysts were aged in tandem using standard dynamometer methods. One was a fully formulated reference catalyst and the other was a CeO{sub 2}-free catalyst. Several potential chemical promotional mechanisms of CO oxidation via a more facile reaction pathway involving coupling between the precious metals and CeO{sub 2}.

  2. Contribution to the sustainable management of resources by novel combination of industrial solid residues into red ceramics.

    Science.gov (United States)

    Karayannis, V; Spiliotis, X; Papastergiadis, E; Ntampegliotis, K; Papapolymerou, G; Samaras, P

    2015-03-01

    Limited amounts of industrial residues are recycled while the remaining huge quantities are stockpiled or disposed of, thus frequently leading to soil contamination. The utilization of industrial residues as valuable secondary resources into ceramics can contribute to efficient waste management and substitution for massive amounts of natural resources (clayey minerals) demanded for ceramic production. The low cost of these residues and even possible energy savings during mixture firing may also be beneficial. In the present study, the innovative combination of lignite fly ash with steel-making dust into clay-based red ceramics is undertaken, to contribute both to sustainable use of resources and prevention of soil contamination. Brick specimens were shaped by extrusion and fired, their microstructure was examined and the effect of the mixture composition and firing temperature on physico-mechanical properties was determined. Ceramic microstructures were successfully obtained by a suitable combination of fly ash with steel dust (5 + 5 wt%) into clays. Properties can be predicted and tailored to meet the needs for specific applications by appropriately adjusting the mixture composition and sintering temperature.

  3. Utilization of steel, pulp and paper industry solid residues in forest soil amendment: relevant physicochemical properties and heavy metal availability.

    Science.gov (United States)

    Mäkelä, Mikko; Watkins, Gary; Pöykiö, Risto; Nurmesniemi, Hannu; Dahl, Olli

    2012-03-15

    Industrial residue application to soil was investigated by integrating granulated blast furnace or converter steel slag with residues from the pulp and paper industry in various formulations. Specimen analysis included relevant physicochemical properties, total element concentrations (HCl+HNO3 digestion, USEPA 3051) and chemical speciation of chosen heavy metals (CH3COOH, NH2OH·HCl and H2O2+H2O2+CH3COONH4, the BCR method). Produced matrices showed liming effects comparable to commercial ground limestone and included significant quantities of soluble vital nutrients. The use of converter steel slag, however, led to significant increases in the total concentrations of Cr and V. Subsequently, total Cr was attested to occur as Cr(III) by Na2CO3+NaOH digestion followed by IC UV/VIS-PCR (USEPA 3060A). Additionally, 80.6% of the total concentration of Cr (370 mg kg(-1), d.w.) occurred in the residual fraction. However, 46.0% of the total concentration of V (2470 mg kg(-1), d.w.) occurred in the easily reduced fraction indicating potential bioavailability.

  4. Characterization of natural fiber from agricultural-industrial residues; Caracterizacao de fibras naturais provenientes de residuos agroindustriais

    Energy Technology Data Exchange (ETDEWEB)

    Prado, Karen S.; Spinace, Marcia A.S., E-mail: marcia.spinace@ufabc.edu.br [Centro de Ciencias Naturais e Humanas, CCNH, Universidade Federal do ABC - UFABC, Campus de Santo Andre, SP (Brazil)

    2011-07-01

    Natural fibers show great potential for application in polymer composites. However, instead of the production of inputs for this purpose, an alternative that can also minimize solid waste generation is the use of agro-industrial waste for this purpose, such as waste-fiber textiles, rice husks residues and pineapple crowns. In this work the characterization of these three residues and evaluate their properties in order to direct the application of polymer composites. Was analyzed the moisture, density, scanning electron microscopy, X-ray diffraction and thermogravimetric analysis of the fibers. The results show that the use of these wastes is feasible both from an environmental standpoint and because its properties suitable for this application. (author)

  5. 76 FR 67746 - Revised Guidance for Industry on Impurities: Residual Solvents in New Veterinary Medicinal...

    Science.gov (United States)

    2011-11-02

    ... Solvents in New Veterinary Medicinal Products, Active Substances and Excipients (Revision), VICH GL18(R... ``Impurities: Residual Solvents in New Veterinary Medicinal Products, Active Substances and Excipients (Revision)'' VICH GL18(R). This revised guidance has been developed for veterinary use by the...

  6. Design of A District Heating System Including The Upgrading of Residual Industrial Waste Heat

    NARCIS (Netherlands)

    Falcao, P.W.; Mesbah, A.; Suherman, M.V.; Wennekes, S.

    2005-01-01

    This study was aimed to evaluate the feasibility of using a waste heat stream from DSM for a District Heating System. A conceptual design was carried out with emphasis on the unit for upgrading the residual waste heat. Having reviewed heat pump technology, mechanical heat pump was found to be the be

  7. Design of A District Heating System Including The Upgrading of Residual Industrial Waste Heat

    NARCIS (Netherlands)

    Falcao, P.W.; Mesbah, A.; Suherman, M.V.; Wennekes, S.

    2005-01-01

    This study was aimed to evaluate the feasibility of using a waste heat stream from DSM for a District Heating System. A conceptual design was carried out with emphasis on the unit for upgrading the residual waste heat. Having reviewed heat pump technology, mechanical heat pump was found to be the

  8. Design of A District Heating System Including The Upgrading of Residual Industrial Waste Heat

    NARCIS (Netherlands)

    Falcao, P.W.; Mesbah, A.; Suherman, M.V.; Wennekes, S.

    2005-01-01

    This study was aimed to evaluate the feasibility of using a waste heat stream from DSM for a District Heating System. A conceptual design was carried out with emphasis on the unit for upgrading the residual waste heat. Having reviewed heat pump technology, mechanical heat pump was found to be the be

  9. Profitability of an Co 60 semi-industrial irradiator type Gamma Beam 651 Pt; Rentabilidad de un irradiador de Cobalto 60 semi-industrial tipo Gamma beam 651 Pt

    Energy Technology Data Exchange (ETDEWEB)

    Cruz Z, E. [Instituto de Ciencias Nucleares, Universidad Nacional Autonoma de Mexico. Apdo. Postal 70-51, 04510 Mexico D.F. (Mexico)

    1997-12-31

    It is described the capacity in volume of processed material by irradiation interesting interesting for the industry and how many laboratory samples can be processed. It is showed the costs of the annual processing, that is, the relation between the volume of sterilized material and his cost, this give us an idea about the profits for this type of gamma irradiators designed for low capacity, where is necessary to define the effective area of sterilization using high dose dosimetry. Also have been compared the maintenance costs, operation and salaries including monetary devaluation in function of the real production of the irradiation processing. Finally, it is remarked the objectives and essential characteristics of this semi-industrial irradiator. (Author)

  10. DAMPAK HUBUNGAN INDUSTRIAL YANG BERSIFAT KAPITALISTIK TERHADAP HARMONISASI HUBUNGAN INDUSTRIAL PENGUSAHA DENGAN PEKERJA (Studi Kasus di PT Fiscous South Pacifik Kabupaten Purwakarta

    Directory of Open Access Journals (Sweden)

    H Gunarto

    2011-02-01

    Full Text Available The implementation of the concept on freedom of rights for association of trade union is facing the phenomenon of liberal capitalistic global economic trends characterized by conflicting industrial relations. The problems in this research, What are the impacts of the implementation of the concept on freedom for association in trade unions to industrial relations which is capitalistic to the workers’ welfare?. To answer these three problems, the writer used qualitative analysis with constructivism paradigm. This study draws some conclusions as follows, the implementation of the concept on freedom for association in trade unions, which is capitalistic, affects the following: (1 the high rates on labor strike, (2 the increasing number of disputes on industrial relations between the entrepreneurs and the workers.

  11. Initial Effects of Differently Treated Biogas Residues from Municipal and Industrial Wastes on Spring Barley Yield Formation.

    Science.gov (United States)

    Prays, Nadia; Kaupenjohann, Martin

    2016-01-01

    Soil application of biogas residues (BGRs) is important for closing nutrient cycles. This study examined the efficiency and impact on yields and yield formation of solid-liquid separated residues from biodegradable municipal and industrial wastes (bio-waste) in comparison to complete BGRs, nitrification inhibitor, agricultural BGRs, mineral fertilizer and unfertilized plots as control. The experiment was set up as a randomized block design on silt loam Cambisol. Biogas residues from four biogas plants were evaluated. Plants per m², ears per plant, grains per ear and thousand grain weight (TGW) were measured at harvest. Fertilization with BGRs resulted in similar biomass yields compared with mineral fertilizer. Mineral fertilizer (71 dt/ha) and plots fertilized with liquid fraction (59-62 dt/ha) indicated a trend to higher yields than solid fraction or complete BGR due to its high ammonia content. Liquid fractions and fraction with nitrification inhibitor induced fewer plants per m² than corresponding solid and complete variants due to a potential phytotoxicity of high NH4-N concentration during germination. However, barley on plots fertilized with liquid fraction compensated the disadvantages at the beginning during the vegetation period and induced higher grain yields than solid fraction. This was attributable to a higher number of ears per plant and grains per ear. In conclusion, BGRs from biodegradable municipal and industrial wastes can be used for soil fertilization and replace considerable amounts of mineral fertilizer. Our study showed that direct application of the liquid fraction of BGR is the most suitable strategy to achieve highest grain yields. Nevertheless potential phytotoxicity of the high NH4-N concentration in the liquid fraction should be considered.

  12. Initial Effects of Differently Treated Biogas Residues from Municipal and Industrial Wastes on Spring Barley Yield Formation.

    Directory of Open Access Journals (Sweden)

    Nadia Prays

    Full Text Available Soil application of biogas residues (BGRs is important for closing nutrient cycles. This study examined the efficiency and impact on yields and yield formation of solid-liquid separated residues from biodegradable municipal and industrial wastes (bio-waste in comparison to complete BGRs, nitrification inhibitor, agricultural BGRs, mineral fertilizer and unfertilized plots as control. The experiment was set up as a randomized block design on silt loam Cambisol. Biogas residues from four biogas plants were evaluated. Plants per m², ears per plant, grains per ear and thousand grain weight (TGW were measured at harvest. Fertilization with BGRs resulted in similar biomass yields compared with mineral fertilizer. Mineral fertilizer (71 dt/ha and plots fertilized with liquid fraction (59-62 dt/ha indicated a trend to higher yields than solid fraction or complete BGR due to its high ammonia content. Liquid fractions and fraction with nitrification inhibitor induced fewer plants per m² than corresponding solid and complete variants due to a potential phytotoxicity of high NH4-N concentration during germination. However, barley on plots fertilized with liquid fraction compensated the disadvantages at the beginning during the vegetation period and induced higher grain yields than solid fraction. This was attributable to a higher number of ears per plant and grains per ear. In conclusion, BGRs from biodegradable municipal and industrial wastes can be used for soil fertilization and replace considerable amounts of mineral fertilizer. Our study showed that direct application of the liquid fraction of BGR is the most suitable strategy to achieve highest grain yields. Nevertheless potential phytotoxicity of the high NH4-N concentration in the liquid fraction should be considered.

  13. Implementation of sustainable processes in regional industries: recycling of metallurgical residual as a project to chance masonry used in construction in Bogotá, Colombia.

    Directory of Open Access Journals (Sweden)

    Leonardo Quijano B.

    2014-03-01

    Full Text Available Rev.esc.adm.neg This paper shows the analysis of the possibilities to implement a new process, viable from the environmental and economic point of view, which includes two regional industries within the framework of the generation of sustainable solutions for the regional economy. In it, the description of how to use residuals from the steel industry as a source to transform the masonry industry, both located in the region of Bogota.

  14. Th Effct of Silver Nano-Particles on Removing Klebsiella pneumoniae from Industrial Residues

    Directory of Open Access Journals (Sweden)

    Habibipour R

    2017-03-01

    Full Text Available Introduction: Progress in nano-science and nanotechnology in the past decade has provided many opportunities to study the biological effcts of nanoparticles, in particular their anti-bacterial effcts. Th aim of this study was to evaluate the antimicrobial properties of silver nanoparticles for the removal of Klebsiella pneumoniae isolated from industrial efflnts. Methods: In this experimental study, aftr sampling polluted industries, coliform and total coliform measurements of fecal industrial wastewater microbiology were performed by standard methods. Th antimicrobial activity of silver nanoparticles on the bacteria (Klebsiella pneumoniae isolates and standard was evaluated with the agar dilution method and broth dilution. One milliliter suspension containing bacteria at 1.5 × 108 CFU/ mL was added to each sample followed by incubation at 37°C for 24 hours. Aftr the mentioned period, the optical density at a wavelength of 600 nm was used to measure the concentration of bacteria. Next, 100 mL of each dilution was transferred to solid medium followed by incubation. Th results were analyzed with SPSS 22 softare. Results: Fecal and total coliform bacteria pollution of textile wastewater was approved, and Klebsiella pneumoniae (textile industry pollution index were isolated. With increasing concentration, the antibacterial activity of silver nanoparticles increased while the number of colonies decreased. Although none of the concentrations were able to eliminate the bacteria, a non-signifiant decrease in the number of bacteria was observed. Conclusion: Th results of the study showed that the type of bacteria and concentrations of silver nanoparticles antimicrobial properties of silver nanoparticles are risk factors. Although the concentrations used were effctive against bacteria yet they did not lead to complete elimination of bacteria Threfore potential impact of nanoparticles for use requires further research and economic factors and other

  15. From Waste to Healing Biopolymers: Biomedical Applications of Bio-Collagenic Materials Extracted from Industrial Leather Residues in Wound Healing

    Directory of Open Access Journals (Sweden)

    Rafael Luque

    2013-04-01

    Full Text Available The biomedical properties of a porous bio-collagenic polymer extracted from leather industrial waste residues have been investigated in wound healing and tissue regeneration in induced wounds in rats. Application of the pure undiluted bio-collagen to induced wounds in rats dramatically improved its healing after 7 days in terms of collagen production and wound filling as well as in the migration and differentiation of keratinocytes. The formulation tested was found to be three times more effective than the commercial reference product Catrix® (Heal Progress (HP: 8 ± 1.55 vs. 2.33 ± 0.52, p < 0.001; Formation of Collagen (FC: 7.5 ± 1.05 vs. 2.17 ± 0.75, p < 0.001; Regeneration of Epidermis (RE: 13.33 ± 5.11 vs. 5 ± 5.48, p < 0.05.

  16. Solid-liquid extraction of alkali metals and organic compounds by leaching of food industry residues.

    Science.gov (United States)

    Yu, Chaowei; Zheng, Yi; Cheng, Yu-Shen; Jenkins, Bryan M; Zhang, Ruihong; VanderGheynst, Jean S

    2010-06-01

    Leaching was studied for its application in extracting inorganic and organic constituents from fresh fermented grape pomace, air-dried fermented grape pomace and air-dried sugar beet pulp. Samples of each feedstock were leached in water at ambient temperature for 30 or 120 min at dry solid-to-liquid ratios of 1/20 and 1/50 kg/L. Leaching removed 82% of sodium, 86% of potassium, and 76% of chlorine from sugar beet pulp, and reduced total ash concentration in air-dry fermented grape pomace from 8.2% to 2.9% of dry matter, 8.2% to 4.4% in fresh fermented grape pomace, and 12.5% to 5.4% in sugar beet pulp. Glycerol (7-11 mg/dry g), ethanol (131-158 mg/dry g), and acetic acid (24-31 mg/dry g) were also extracted from fermented grape pomace. These results indicate that leaching is a beneficial pretreatment step for improving the quality of food processing residues for thermochemical and biochemical conversion.

  17. Environmental implications of the use of agro-industrial residues for biorefineries: application of a deterministic model for indirect land-use changes

    DEFF Research Database (Denmark)

    Tonini, Davide; Hamelin, Lorie; Astrup, Thomas Fruergaard

    2016-01-01

    .1 t CO2-eq.ha-1demanded y-1 corresponding to 1.2-1.5 t CO2 t-1 dry biomass used for energy. Only bioenergy from straw and wild grass was shown to perform better than the alternative use, as no competition with the feed sector was involved. Biogas for heat-and-power production was the best performing......Biorefining agro-industrial biomass residues for bioenergy production represents an opportunity for both sustainable energy supply and greenhouse gas (GHG) emissions mitigation. Yet, is bioenergy the most sustainable use for these residues? To assess the importance of the alternative use...... of these residues, a consequential life-cycle assessment (LCA) of 32 energy-focused biorefinery scenarios was performed based on eight selected agro-industrial residues and four conversion pathways (two involving bioethanol and two biogas). To specifically address indirect land-use changes (iLUC) induced...

  18. Chemical composition of flours made of residues from the king palm (Archontophoenix alexandrae industry

    Directory of Open Access Journals (Sweden)

    Manoela Alano Vieira

    2009-08-01

    Full Text Available Residues from King palm (Archontophoenix alexandrae processing were used for the production of flours, which were then chemically characterized. The protein content in these flours ranged from 3.62 to 9.75 g/100g and was higher in sifted leaf flour (SLF. The dietary fiber contents varied from 64 to 72 g/100g. These values were high when compared to those of flours used in human nutrition. Analysis of anti-nutritional factors showed phytate contents to be below the levels that affected the bioavailability of minerals in human diet. Tannin contents were compatible with those found in legumes, between 0 and 2000 mg/100g. These flours showed high mineral content, which suggested a possibility for them to be used as food supplement. However, the bioavailability of these minerals could be affected by high total dietary fibre concentrations and anti-nutritional components contained in the samples.Resíduos do processamento de palmeira-real (Archontophoenix alexandrae foram utilizados para produção de farinha e caracterizados quimicamente. O conteúdo de proteína encontrado nas farinhas variam de 3,62 a 9,75, sendo maior na farinha da folha peneirada. Os teores de fibra dietética total variaram de 64.00 a 72 g/100g, valores altos quando comparados com farinhas tradicionalmente utilizadas na alimentação humana. A análise de fatores antinutricionais indicou teores de fitato abaixo dos níveis que afetam a biodisponibilidade de minerais na dieta. Os teores de tanino foram significativos, compatíveis aos encontrados nas leguminosas entre 0 e 2000 mg/100g. As farinhas de palmeirareal apresentaram elevados teores de minerais, podendo ser indicadas como suplementos em alimentos, porém, deve-se considerar que a biodisponibilidade destes minerais pode ser afetada pela alta concentração de fibras dietéticas totais e de outros componentes antinutricionais contidos na amostra.

  19. Laser sheet scattered light method for industrial measurement of thickness residual stress distribution in flat tempered glass

    Science.gov (United States)

    Castellini, P.; Stroppa, L.; Paone, N.

    2012-05-01

    The paper presents the laser sheet scattered light technique, a fast optical non contact method for measuring internal stress distribution over a cross section of flat glass specimens, designed for closed loop control of glass tempering furnaces. The technique is an evolution of the scattered light method for flat glass residual stress analysis and allows a full thickness stress profile to be measured with a single shot acquisition across a glass plate without any contact. A linearly polarized laser sheet, shaped into a thin plane of parallel light beams, enters orthogonally to the side of the flat glass illuminating its full thickness. Light sheet is orthogonal to the glass surface and travels parallel to it. Stress induced birefringence through the glass affects light polarization, thus scattered light intensity detected at 90° with respect to the polarization of the incident light appears spatially modulated in intensity. A camera aligned orthogonal to the laser light polarization collects an image of fringes whose shape is digitally analyzed to measure the thickness stress state. The paper describes the development of this technique by recalling the scattered light method, then describing its automation by scanning a collimated beam across the glass thickness and finally by showing that the scan method can be substituted by the light sheet method. Light sheet method provides a full field non contact stress measurement across the glass thickness, thus allowing for a fast inspection method, suitable for industrial use. Flat glass items for industrial use have bevelled edges; this does not allow measurements close to glass surface. To solve this limit, experimental data are extrapolated by a symmetrical polynomial fitting and imposing a zero integral to the stress profile. Results on surface stress measured by the laser sheet scattered method are in agreement with those of the automated light scattered method and show a fair agreement with measurement by an

  20. Quality and energetic evaluation of the charcoal made of babassu nut residues used in the steel industry

    Directory of Open Access Journals (Sweden)

    Thiago de Paula Protásio

    2014-10-01

    Full Text Available Brazil is the only country in the world that uses large scale charcoal in steel-making blast furnaces. Meantime, the monoculture plantations of Eucalyptus are not able to meet the demand for charcoal from the steel industries.Therefore, research is necessary, in order to use lignocellulosic residues for the production of charcoal with technological properties which are suitable for the reduction of iron ore. Given the above, the objective of this study was to evaluate the quality of charcoal which was made with babassu nut shell and designed for utilization in the steel industry in the function of the final carbonization temperature. All three layers of babassu nut shell (epicarp, mesocarp and endocarp were used together. The initial temperature of the test was 100ºC and the final temperatures were: 450ºC, 550ºC, 650ºC, 750ºC and 850ºC. For the charcoals produced, the following properties were determined: apparent relative density, energy density and fixed carbon stock, in addition to chemical compositions (immediate and elemental and heating values (higher and lower. Charcoal made of babassu nut shell showed high values of apparent density and energy density, and has a potential to replace coal and wood charcoal in the steel industry. The effect of the final carbonization temperature was expressed for all characteristics evaluated, except for the nitrogen content. Babassu nut shell must be carbonized at temperatures higher than 550ºC, so that the charcoal produced can be used in steel-making blast furnaces.

  1. Characterization and evaluation of residue 'grits' of the cellulose industry; Caracterizacao e avaliacao do resisduo 'grits' da industria de celulose

    Energy Technology Data Exchange (ETDEWEB)

    Destefani, A.Z.; Santos, M.M.; Holanda, J.N.F. [Universidade Estadual do Norte Fluminense Darcy Ribeiro (LAMAV/CCT/UENF), Campos dos Goytacazes, RJ (Brazil). Lab. de Materiais Avancados

    2010-07-01

    The cellulose industry generates huge amounts of solid waste residue called 'grits'. These wastes have been willing over time in landfills near the mills. However, this type of disposal is not environmentally friendly and can cause degradation and environmental pollution. In addition, environmental legislation increasingly severe and the high costs of landfill have led the search for new alternatives for final disposition of this abundant waste. In this context, this study is to characterize waste grits, generated by the cellulose industry in the region of Aracruz-ES. The residue samples were characterized in terms of chemical composition, X-ray diffraction, particle size distribution and thermal analysis (DTA and TGA). The characterization of the residual 'grits' demonstrated its potential as a feedstock for production of soil-cement bricks. (author)

  2. Analisis Intensitas Pencahayaan Dan Reflektan Di Lingkungan Kerja Terhadap Kelelahan Mata Pada Tenaga Kerja Industri Bulu Mata Palsu Di PT. Sung Shim International Purbalingga.

    Directory of Open Access Journals (Sweden)

    Feriyandi Feriyandi

    2015-12-01

    Full Text Available ABSTRACT Background : There are approximately 15,000 workers in several spurious eyelash industries in Purbalingga Regency. Since objects being observed are very fine and the tasks need high accuracy, good lighting is therefore highly required. Poor lighting can lead to visual and mental fatigue, stiffness around the eyes, eye damage and the increasing of work accidents. Sufficient intensity and good management of lighting will result a comfort environment in accordance  to achieve a safe  work environment. Method : This research was conducted as  observational study with a cross sectional approach  for 45 samples of workers. Sampling was carried out by using of systematic random sampling. Data of light intensity and reflectance were collected by measurement of light using Lux Meter and assessment of visual fatigue by using Retention Timer. Other data were collected by interviewing workers with age limitation up to 33 years old. Chi Square Test was used to analyze the data of light intensity and reflectance, work years, age, work period, distance of light to object, distance of eyes to object, relative humidity and temperature, and the correlation with the rise of visual fatigue. Result : Light intensity in the knitting section was between 301.5 – 576.7 lux with reflectance of 43.1%-89.6%. Thirty wokers (66.7% suffered from mild visual fatigue and fifteen wokers, suffered (33.3% from moderate visual fatigue. Light intensity had  an influence and significant relationship  to the occurring of visual fatigue among workers in the industry of spurious eyelash of  PT. Sung Shim International  (p < 0,05 with  Odd ratio = 10.246 (95% CI : 1.147 - 91.498.  Probability of light intensity factor to cause visual fatigue measured by a regression logistic model  was  82.9% . It was caused by  poor lighting (light intensities were measured  below 500 lux while 17.1%  was caused by  other factors. Conclusion : Most of the spurious eyelash

  3. Thermal Analysis of a Thermal Energy Storage Unit to Enhance a Workshop Heating System Driven by Industrial Residual Water

    Directory of Open Access Journals (Sweden)

    Wenqiang Sun

    2017-02-01

    Full Text Available Various energy sources can be used for room heating, among which waste heat utilization has significantly improved in recent years. However, the majority of applicable waste heat resources are high-grade or stable thermal energy, while the low-grade or unstable waste heat resources, especially low-temperature industrial residual water (IRW, are insufficiently used. A thermal energy storage (TES unit with paraffin wax as a phase change material (PCM is designed to solve this problem in a pharmaceutical plant. The mathematical models are developed to simulate the heat storage and release processes of the TES unit. The crucial parameters in the recurrence formulae are determined: the phase change temperature range of the paraffin wax used is 47 to 56 °C, and the latent heat is 171.4 kJ/kg. Several thermal behaviors, such as the changes of melting radius, solidification radius, and fluid temperature, are simulated. In addition, the amount of heat transferred, the heat transfer rate, and the heat storage efficiency are discussed. It is presented that the medicine production unit could save 10.25% of energy consumption in the investigated application.

  4. Influence of polymer bases on the synergistic effects obtained from mixtures of additives in the petroleum industry. Performance and residue formation

    Energy Technology Data Exchange (ETDEWEB)

    Spinelli, Luciana S.; Aquino, Aline S.; Pires, Renata V.; Barboza, Elaine M.; Lucas, Elizabete F. [Institute of Macromolecules/Federal University of Rio de Janeiro, IMA/UFRJ, Cidade Universitaria, Centro de Tecnologia, Bloco J, Ilha do Fundao 21945-970, Rio de Janeiro (Brazil); Louvisse, Ana Maria T. [Petrobras Research Center/CENPES - Q. 7 - Cidade Universitaria, Ilha do Fundao 21949-900, Rio de Janeiro (Brazil)

    2007-08-15

    Undesirable residue formation and lower performance can be observed during the use of polymer-based chemical additives in the petroleum industry when such compounds are mixed during a number of operations, such as oil production. In this work a demulsifier, a flocculant and a scale inhibitor and their respective polymeric bases were tested. These were evaluated through specific performance tests for each additive and a solubility test to assess residue formation. By correlating the performance of commercial additives and the respective polymeric bases, we can conclude that the polymeric base is responsible for the positive synergistic effects on demulsifier performance in the presence of other additives and for the negative synergistic effects on scale-inhibiting performance, also in the presence of other additives. Moreover, we found that the polymeric base can be responsible for the residue formation from the scale inhibitor and flocculant mixture, although it is not be responsible for the residue formation of the flocculant alone. (author)

  5. Use of life cycle assessment as decision-support tool for water reuse and handling of residues at a Danish industrial laundry

    DEFF Research Database (Denmark)

    Jørgensen, Kim; Villanueva, Alejandro; Wenzel, Henrik

    2004-01-01

    This analysis presents the results of a life cycle assessment (LCA) carried out on six alternative options for the recycling of water at a Danish industrial laundry for workwear. The study focuses on the handling and disposal of the wet residues generated when wastewater is treated for recycling...... treatment for production of vitrified sand, and mineralization in a sludge bed. It is concluded from the results that with the current Danish environmental policy priorities, the environmental impacts of highest priority are the toxicity effects derived from the presence of heavy metals in the residues....... The results of the study also confirm the potential of LCA as a decision-support tool for assisting water recycling initiatives and for residue handling management. The handling of residues has been identified as a stage of the water recycling strategy that bears important environmental impacts. This holistic...

  6. Investigation of potential of agro-industrial residues for ethanol production by using Candida tropicalis and Zymomonas mobilis

    Science.gov (United States)

    Patle, Sonali

    India is becoming more susceptible regarding energy security with increasing world prices of crude oil and increasing dependence on imports. Based on experiments by the Indian Institute of Petroleum, a 10% ethanol blend with gasoline is being considered for use in vehicles in at least one state and it will be mandatory for all oil companies to blend petrol with 10% ethanol from October 2008. In view of the above, the Government has already started supply of 5% ethanol blended petrol from 2003 in nine states and four contiguous Union Territories. Currently, fuel ethanol is produced mainly from molasses, corn, wheat and sugar beets. The production cost of ethanol from these agro-feedstocks is more than twice the price of gasoline. The high feedstock cost poses a major obstacle to large scale implementation of ethanol as a transportation fuel. Molasses could be in short supply due to the implementation of 10% blending norm. A reduction in import duty for industrial alcohol from7.5% to 5% has been suggested. The use of lignocellulosic energy crops, and particularly low cost biomass residues, offers excellent perspectives for application of ethanol in transportation fuels (Ridder, 2000). These materials will increase the ethanol production capacity and reduce the production cost to a competitive level. There is a huge demand (500 million litres) of ethanol to meet the 5% blending in India. With the present infrastructure, only 90 million litres of ethanol was produced till November 2006 and could reach up to 140 million litres (around) till October 2007. Bioethanol from these materials provides a highly cost effective option for CO2 emission reduction in the transportation sector. The aim of the present investigation was to evaluate the potential of biomass as feedstock for ethanol production. The dedicated energy crops would require thorough support as well as planning efforts such as assessing resources, availability and utilization. Furthermore, applied research is

  7. PENGARUH GAYA KEPEMIMPINAN TRANSFORMASIONAL DAN KOMPENSASI TERHADAP KINERJA KARYAWAN DENGAN MOTIVASI SEBAGAI VARIABEL INTERVENING (STUDI PADA INDUSTRI ALAS KAKI PT. BO KYUNG PASURUAN

    Directory of Open Access Journals (Sweden)

    Wahyu Budi Priyanto

    2016-07-01

    Full Text Available Compensation is also self motivation factor for employees, where those things end in high-low level of work result or performance. This research purposes to test the effect of transformational leadership style, compensation, and motivation of employee’s performance, motivation as an effect mediator from transformational leadership style and compensation to employee’s performance in PT. Bo Kyung Pasuruan. This research is explanatory. In this research uses 96 samples from 2719 employees that work in PT. Bo Kyung Pasuruan. The result of Partial Least Square (PLS this research shows that transformational leadership style is positively effected but not significant to motivation and employee’s performance. Motivation affect transformational leadership style of employee’s performance, and motivation does not influence compensation of employee’s performance in PT. Bo Kyung Pasuruan.

  8. Chemical amendment and phytostabilization of an industrial residue contaminated with Zn and Cd Correção química e fitoestabilização de um resíduo industrial contaminado com Zn e Cd

    Directory of Open Access Journals (Sweden)

    Fabiana Soares dos Santos

    2007-10-01

    Full Text Available Phytostabilisation of a contaminated soil with heavy metals is considered a very appropriate technology to reduce erosion and dispersion of contaminants. A greenhouse study was conducted to evaluate the effects of both chemical amendments (calcium silicate and brewery sludge, and phytoremediation using the grass Brachiaria decumbens, on an industrial residue contaminated with Zn and Cd (industrial residue. Industrial residue samples placed into 30 L containers were amended with 20% brewery sludge, calcium silicate (2%, 3%, and 20% of brewery sludge + calcium silicate (2.5%, 4%, and were compared to the control treatment (non-amended residue. After pH stabilization, B. decumbens plants were grown on all treatments in order to evaluate the ability of the species to tolerate high Zn and Cd concentrations from the residue. Samples were collected twice, at planting and harvesting, for pH determination and simple extractions with water, sodium nitrate, acetic acid and DTPA. Differences in Zn and Cd concentrations in extracts allowed to estimate the concentrations of these elements in the most likely chemical forms they are found in the residue. Alkaline and organic industrial amendments reduced Zn and Cd percentages, both in the soluble and exchangeable fractions, as well as caused the predominance of Zn and Cd in the most stable chemical fractions, such as complexed and precipitated compounds. B. decumbens was tolerant to Zn and Cd from the industrial residue after addition of the amendments.A fitoestabilização de solos contaminados com metais pesados é considerada uma boa alternativa para reduzir a erosão e dispersão de contaminantes no ambiente. Foi conduzido um experimento em casa-de-vegetação com o objetivo de avaliar a contenção química (silicato de cálcio e lodo do biodigestor de uma cervejaria e a fitorremediação pela Brachiaria decumbens, de um resíduo industrial contaminado com Zn e Cd, utilizando vasos de 30 L. Os tratamentos

  9. Use of life cycle assessment as decision-support tool for water reuse and handling of residues at a Danish industrial laundry

    DEFF Research Database (Denmark)

    Jørgensen, Kim; Villanueva, Alejandro; Wenzel, Henrik

    2004-01-01

    This analysis presents the results of a life cycle assessment (LCA) carried out on six alternative options for the recycling of water at a Danish industrial laundry for workwear. The study focuses on the handling and disposal of the wet residues generated when wastewater is treated for recycling....... Heavy metals originate from the dirt in the workwear that is washed in the laundry. It is further concluded that the studied water treatment technologies satisfy both the need of clean water for recycling and simultaneously help controlling a safe disposal of pollutants by concentration of the residues......, and in accounting for long-term potential toxicity impacts. The analysed options are a combination of two water-upgrading technologies: biofilter and ultrafiltration, and three residue disposal alternatives: biogas followed by incineration of sludge at local wastewater treatment plant, thermal vitrification...

  10. Investigation of Filtration Membranes from the Dairy Protein Industry for Residual Fouling Using Infrared Spectroscopy and Chemometrics

    DEFF Research Database (Denmark)

    Jensen, Jannie Krog

    investigation (Paper I) describes the concentration development over the membrane leaves as a function of the distance from the feed inlet and the distance from the center permeate tube. A non-homogenous concentration distribution of residual fouling was observed with the highest concentration of residual...

  11. Interaction of biochar and organic residues from sugarcane industry in soil chemical attributes and greenhouse gases emissions.

    Science.gov (United States)

    Fernanda Abbruzzini, Thalita; Feola Conz, Rafaela; Pellegrino Cerri, Carlos Eduardo

    2014-05-01

    Researchers have highlighted the importance of providing soil quality in agricultural systems, besides mitigating greenhouse gases (GHG) emissions to the atmosphere and increasing soil carbon sequestration. Therefore, several studies have demonstrated the effectiveness of biochar as a soil conditioner, both in relation to increased C sequestration and improvements in soil chemical, physical and biological attributes, resulting in better conditions for plant growth. The aim of this study was to assess the impact of applying biochar produced from sugarcane straw to soils in relation to changes in soil chemical attributes and mitigation of greenhouse gases emissions into the atmosphere. To do so, we conducted a laboratory incubation under controlled environmental conditions (ie temperature and humidity) with and without the application of filter cake and vinasse (ie organic residues from sugarcane industry) and rates of biochar application (0, 10, 20 and 50 Mg ha-1). The fluxes of CO2, N2O and CH4 of each incubation unity were measured periodically (in days 1, 2, 5, 9, 13, 16, 20, 24, 28, 30, 47, 60, 91, 105, 123, 130, 138 and 150). Each treatment consisted of eight replicates with destructive samples evaluated at 30, 60, 90 and 150 days after incubation to characterize the chemical attributes of the incubated soil, besides GHG (CO2, N2O and CH4) emissions. In general, there was an increase in carbon dioxide (CO2) fluxes over time due to the application of filter cake and vinasse and increasing dose of biochar. Regarding nitrous oxide (N2O) emissions, there was an increase of 82.35% with the application of vinasse and filter cake compared to the control treatment. However, different doses of biochar (10, 20 and 50 Mg ha-1) reduced N2O emissions by 29, 38.7 and 70.9%, respectively. The methane (CH4) flux was negligible in all treatments. We observed improvements in soil chemical attributes, such as higher pH, a substantial increase in the soil CEC, reduced exchangeable

  12. Comparative study of residue pellets from cane sugar and palm-oil industries with commercial wood pellets, applied in downdraft gasification

    Energy Technology Data Exchange (ETDEWEB)

    Erlich, Catharina

    2009-10-15

    While biomass utilization for energy conversion in the industrialized nations is being largely developed, highly efficient and environmentally friendly, many tropical countries still use biomass at low efficiencies and high emission levels. The main reasons for these gaps are both political and technological: the energy markets are different, the Gross National Product (GDP) differs widely, and the feedstock differs in form and conversion behaviour. By implementing newer technologies adapted for tropical biomass feedstock, there would be a large potential in these countries for increased energy services since access to modern energy still is an essential step for improving the GDP for a country. Two dominant and tropically placed industries available for energy improvements are the cane sugar and palm-oil industries, which both produce an abundant amount of biomass residues. One step towards enhanced utilization of the residues, which would not require large investment costs in the power plant section nor in the processes of these industries, would be to install a pelletizing unit in the industry area to make fuel out of the excess residues for sale to the nearby villages. The pellets could be used both for cooking/heating and for small-scale power generation in a gasification-IC engine plant. The overall objective of this study is to experimentally evaluate the biomass residues in pellet form from the cane sugar and palm oil industries during conversion to useful energy in small-scale systems. The thesis is built upon five publications which include experimental analysis on flaming pyrolysis and rapid heating of pellets (paper I), pyrolysis in oxygen-free atmosphere and slow heating with subsequent steam gasification (paper II), global pelletizing data such as relative energy consumption, temperature levels, particle size and moisture content for successful pelletizing process (paper III), downdraft gasification evaluation including reactor temperature

  13. Investigation of Filtration Membranes from the Dairy Protein Industry for Residual Fouling Using Infrared Spectroscopy and Chemometrics

    DEFF Research Database (Denmark)

    Jensen, Jannie Krog

    the result showed that the MCR model needed three factors to describe the system, one describing the membrane material (polyethersulfone, PES), and two describing the residual fouling that is present on the membrane. The MCR method improved the interpretation of the models considerably compared to e.g. PCA...... or the univariate data analysis. However, it also became evident that the penetration depth of the infrared beam creates additional complexity when measuring semi-solid layered samples. In order to obtain an overview of the different analysis methods and data analysis methods that have been employed by other...... how the application of multivariate infrared spectroscopy combined with new data analysis methods has augmented the knowledge about residual fouling on real size production membranes. The information obtained can be used to investigate and monitor residual membrane fouling and help in the design...

  14. Bioprocessing of some agro-industrial residues for endoglucanase production by the new subsp.; Streptomyces albogriseolus subsp. cellulolyticus strain NEAE-J

    Science.gov (United States)

    El-Naggar, Noura El-Ahmady; Abdelwahed, Nayera A.M.; Saber, Wesam I.A.; Mohamed, Asem A.

    2014-01-01

    The use of low cost agro-industrial residues for the production of industrial enzymes is one of the ways to reduce significantly production costs. Cellulase producing actinomycetes were isolated from soil and decayed agricultural wastes. Among them, a potential culture, strain NEAE-J, was selected and identified on the basis of morphological, cultural, physiological and chemotaxonomic properties, together with 16S rDNA sequence. It is proposed that strain NEAE-J should be included in the species Streptomyces albogriseolus as a representative of a novel sub-species, Streptomyces albogriseolus subsp. cellulolyticus strain NEAE-J and sequencing product was deposited in the GenBank database under accession number JN229412. This organism was tested for its ability to produce endoglucanase and release reducing sugars from agro-industrial residues as substrates. Sugarcane bagasse was the most suitable substrate for endoglucanase production. Effects of process variables, namely incubation time, temperature, initial pH and nitrogen source on production of endoglucanase by submerged fermentation using Streptomyces albogriseolus subsp. cellulolyticus have been studied. Accordingly optimum conditions have been determined. Incubation temperature of 30 °C after 6 days, pH of 6.5, 1% sugarcane bagasse as carbon source and peptone as nitrogen source were found to be the optimum for endoglucanase production. Optimization of the process parameters resulted in about 2.6 fold increase in the endoglucanase activity. Therefore, Streptomyces albogriseolus subsp. cellulolyticus coud be potential microorganism for the intended application. PMID:25242966

  15. Bioprocessing of some agro-industrial residues for endoglucanase production by the new subsp.; Streptomyces albogriseolus subsp. cellulolyticus strain NEAE-J

    Directory of Open Access Journals (Sweden)

    Noura El-Ahmady El-Naggar

    2014-06-01

    Full Text Available The use of low cost agro-industrial residues for the production of industrial enzymes is one of the ways to reduce significantly production costs. Cellulase producing actinomycetes were isolated from soil and decayed agricultural wastes. Among them, a potential culture, strain NEAE-J, was selected and identified on the basis of morphological, cultural, physiological and chemotaxonomic properties, together with 16S rDNA sequence. It is proposed that strain NEAE-J should be included in the species Streptomyces albogriseolus as a representative of a novel sub-species, Streptomyces albogriseolus subsp. cellulolyticus strain NEAE-J and sequencing product was deposited in the GenBank database under accession number JN229412. This organism was tested for its ability to produce endoglucanase and release reducing sugars from agro-industrial residues as substrates. Sugarcane bagasse was the most suitable substrate for endoglucanase production. Effects of process variables, namely incubation time, temperature, initial pH and nitrogen source on production of endoglucanase by submerged fermentation using Streptomyces albogriseolus subsp. cellulolyticus have been studied. Accordingly optimum conditions have been determined. Incubation temperature of 30 ºC after 6 days, pH of 6.5, 1% sugarcane bagasse as carbon source and peptone as nitrogen source were found to be the optimum for endoglucanase production. Optimization of the process parameters resulted in about 2.6 fold increase in the endoglucanase activity. Therefore, Streptomyces albogriseolus subsp. cellulolyticus coud be potential microorganism for the intended application.

  16. Bioprocessing of some agro-industrial residues for endoglucanase production by the new subsp.; Streptomyces albogriseolus subsp. cellulolyticus strain NEAE-J.

    Science.gov (United States)

    El-Naggar, Noura El-Ahmady; Abdelwahed, Nayera A M; Saber, Wesam I A; Mohamed, Asem A

    2014-01-01

    The use of low cost agro-industrial residues for the production of industrial enzymes is one of the ways to reduce significantly production costs. Cellulase producing actinomycetes were isolated from soil and decayed agricultural wastes. Among them, a potential culture, strain NEAE-J, was selected and identified on the basis of morphological, cultural, physiological and chemotaxonomic properties, together with 16S rDNA sequence. It is proposed that strain NEAE-J should be included in the species Streptomyces albogriseolus as a representative of a novel sub-species, Streptomyces albogriseolus subsp. cellulolyticus strain NEAE-J and sequencing product was deposited in the GenBank database under accession number JN229412. This organism was tested for its ability to produce endoglucanase and release reducing sugars from agro-industrial residues as substrates. Sugarcane bagasse was the most suitable substrate for endoglucanase production. Effects of process variables, namely incubation time, temperature, initial pH and nitrogen source on production of endoglucanase by submerged fermentation using Streptomyces albogriseolus subsp. cellulolyticus have been studied. Accordingly optimum conditions have been determined. Incubation temperature of 30 °C after 6 days, pH of 6.5, 1% sugarcane bagasse as carbon source and peptone as nitrogen source were found to be the optimum for endoglucanase production. Optimization of the process parameters resulted in about 2.6 fold increase in the endoglucanase activity. Therefore, Streptomyces albogriseolus subsp. cellulolyticus coud be potential microorganism for the intended application.

  17. Controlled residual stresses introduction to improve fatigue resistance of rotary shouldered connections used in oil drilling industry

    Energy Technology Data Exchange (ETDEWEB)

    Korin, I., E-mail: ikorin@uncoma.edu.a [CONICET/San Antonio Internaciona. Instituto de Tecnologia Prof. J. A. Sabato (USAM/CNEA) - Grupo Mecanica de Fractura, UN Comahue. Buenos Aires 1200, Neuquen (CP8300) (Argentina); Perez Ipina, J. [CONICET/UNComa. Grupo Mecanica de Fractura, UN Comahue. Buenos Aires 1200, Neuquen (CP8300) (Argentina)

    2010-12-15

    An innovative technique is proposed with the aim of increasing the fatigue strength of rotary shouldered connections. The objective is to generate controlled compressive residual stresses at the most stressed zones (i.e., the threat root regions) to delay fatigue crack nucleation. The residual stresses are introduced through controlled application of an over-make-up torque of the joint and then returning to the nominal torque. The adequacy of the method was demonstrated through two experimental arrangements at laboratory scale, which employed specimens of reduced size. Results suggest that significant increases in the fatigue life of joints can be achieved applying this technique.

  18. Industry

    Energy Technology Data Exchange (ETDEWEB)

    Bernstein, Lenny; Roy, Joyashree; Delhotal, K. Casey; Harnisch, Jochen; Matsuhashi, Ryuji; Price, Lynn; Tanaka, Kanako; Worrell, Ernst; Yamba, Francis; Fengqi, Zhou; de la Rue du Can, Stephane; Gielen, Dolf; Joosen, Suzanne; Konar, Manaswita; Matysek, Anna; Miner, Reid; Okazaki, Teruo; Sanders, Johan; Sheinbaum Parado, Claudia

    2007-12-01

    This chapter addresses past, ongoing, and short (to 2010) and medium-term (to 2030) future actions that can be taken to mitigate GHG emissions from the manufacturing and process industries. Globally, and in most countries, CO{sub 2} accounts for more than 90% of CO{sub 2}-eq GHG emissions from the industrial sector (Price et al., 2006; US EPA, 2006b). These CO{sub 2} emissions arise from three sources: (1) the use of fossil fuels for energy, either directly by industry for heat and power generation or indirectly in the generation of purchased electricity and steam; (2) non-energy uses of fossil fuels in chemical processing and metal smelting; and (3) non-fossil fuel sources, for example cement and lime manufacture. Industrial processes also emit other GHGs, e.g.: (1) Nitrous oxide (N{sub 2}O) is emitted as a byproduct of adipic acid, nitric acid and caprolactam production; (2) HFC-23 is emitted as a byproduct of HCFC-22 production, a refrigerant, and also used in fluoroplastics manufacture; (3) Perfluorocarbons (PFCs) are emitted as byproducts of aluminium smelting and in semiconductor manufacture; (4) Sulphur hexafluoride (SF{sub 6}) is emitted in the manufacture, use and, decommissioning of gas insulated electrical switchgear, during the production of flat screen panels and semiconductors, from magnesium die casting and other industrial applications; (5) Methane (CH{sub 4}) is emitted as a byproduct of some chemical processes; and (6) CH{sub 4} and N{sub 2}O can be emitted by food industry waste streams. Many GHG emission mitigation options have been developed for the industrial sector. They fall into three categories: operating procedures, sector-wide technologies and process-specific technologies. A sampling of these options is discussed in Sections 7.2-7.4. The short- and medium-term potential for and cost of all classes of options are discussed in Section 7.5, barriers to the application of these options are addressed in Section 7.6 and the implication of

  19. An Approach Using Gas Monitoring to Find the Residual TCE Location in the Unsaturated Zone of Woosan Industrial Complex (WIC), Korea

    Science.gov (United States)

    Koh, Y.; Lee, S.; Yang, J.; Lee, K.

    2012-12-01

    An area accommodating various industrial facilities has fairly high probability of groundwater contamination with multiple chlorinated solvents such as trichloroethene (TCE), carbon tetrachloride (CT), and chloroform (CF). Source tracing of chlorinated solvents in the unsaturated zone is an essential procedure for the management and remediation of contaminated area. From the previous study on seasonal variations in hydrological stresses and spatial variations in geologic conditions on a TCE plume, the existence of residual DNAPLs at or above the water table has proved. Since TCE is one of the frequently detected VOCs (Volatile Organic Compounds) in groundwater, residual TCE can be detected by gas monitoring. Therefore, monitoring of temporal and spatial variations in the gas phase TCE contaminant at an industrial complex in Wonju, Korea, were used to find the residual TCE locations. As pilot tests, TCE gas samples collected in the unsaturated zone at 4 different wells were analyzed using SPME (Solid Phase MicroExtraction) fiber and Gas Chromatography (GC). The results indicated that detecting TCE in gas phase was successful from these wells and TCE analysis on gas samples, collected from the unsaturated zone, will be useful for source area characterization. However, some values were too high to doubt the accuracy of the current method, which needs a preliminary lab test with known concentrations. The modified experiment setups using packer at different depths are in process to find residual TCE locations in the unsaturated zone. Meanwhile, several PVD (polyethylene-membrane Passive Vapor Diffusion) samplers were placed under water table to detect VOCs by equilibrium between air in the vial and VOCs in pore water.

  20. Other solutions for the plastic residue from the automobile industry and used as additives in the asphaltic bitumens; Alternativas de los residuos plasticos de la automocion y su empleo como aditivos de los betunes asfalticos. Parte I

    Energy Technology Data Exchange (ETDEWEB)

    Lopez-Vidriero, E.; Castillo, F. [CEDEX. Ministerio de Fomento. Madrid (Spain)

    1999-08-01

    This article forms part of an investigation which aims to achieve two adjectives. The first is to cooperate in the improvement of the environment by decreasing the amount of plastic residue from the automobile industry. The second is to improve the characteristics of asphaltic bitumens used in roofing and waterproofing in civil engineering, through the addition of plastic residue from the automobile industry. (Author) 4 refs.

  1. 75 FR 45640 - Draft Guidance for Industry on Residual Drug in Transdermal and Related Drug Delivery Systems...

    Science.gov (United States)

    2010-08-03

    ... product lifecycle management--to ensure that the amount of residual drug substance at the end of the... development--as well as during manufacturing and product lifecycle management--to ensure that the amount of... systems (TDDS), transmucosal drug delivery systems (TMDS), and topical patch products regarding use of an...

  2. System implementation of electromobility, challenges to the energy industry law, current status. Pt. 1; Systemintegration von Elektromobilitaet, Herausforderung an das Energiewirtschaftsrecht, eine Standortbestimmung. T. 1

    Energy Technology Data Exchange (ETDEWEB)

    Keil, Eric [Verband kommunaler Unternehmen e.V., Berlin (Germany). Sachgebiet Netzzugang, Strom, Entflechtung; Schmelzer, Knut [Jena Univ. - Kompetenzzentrum fuer Technik, Wirtschaft, Recht e.V. (Germany). Inst. fuer Energiewirtschaftsrecht

    2010-11-15

    The authors of the first part of the contribution under consideration report on generic considerations on the implementation of electrical mobility in the valid energy industry law. Moreover, the authors report on the fundamental question whether and to what extent electrical mobility can be understood as an extended task of supply in the sense of the valid energy industry law.

  3. Technical problems of wastewater treatment plant in crude palm oil industry A case study in PT Socfin Indonesia-Kebun Sungai Liput, Nang groe Aceh Darussalam Province

    Science.gov (United States)

    Paramitadevi, Y. V.; Rahmatullah

    2017-05-01

    Crude palm oil produced in Indonesia has already been known as the largest in the world. Unfortunately many of palm oil factories (CPOF) spread out in Indonesia have not good wastewater treatments (WWTP) yet. PT Socfin Indonesia, as an example, which is located in Aceh Tamiang Regency, still has BOD contained in its final effluent of the waswater treatment plant more than 150 ppm. In fact, the capability and capacity of WWTP in PT Socfin are 192 m3per day. Because of improper operational and maintenance of the WWTP, the technical prob lem are accumulated, such as, increasing the deposition of sludge and decreasing the retention time. The following affect is the treatment process is not going well and the quality of effluent is getting worse. The objective of this paper is to solve the technical problems by means remov ing the deposition of sludge periodically and fixing floating aeration in the aerobic pond. Method using for this paper is survey and wastewater sampling. A recommendation of the was tewater treatment system has been proposed after average BOD from WWTP outlet is defined 158 mg/L. The recommendation has seven procesess including oil separation, neutralization, closed tank anaerobic digester equipped with gas holder, extended aeration, settling tank, sand drying bed and land application.

  4. Industrialization

    African Journals Online (AJOL)

    Lucy

    Second World era international system (1945-1990) may not have done any good to ... wedge between the capitalist and socialist blocs, not only blurred Third World .... Politics and the Stages of Economic Growth, Cambridge: Cambridge ... complex industries producing mainly for export, but also producing for local.

  5. Production of novel microbial flocculants by Klebsiella sp. TG-1 using waste residue from the food industry and its use in defecating the trona suspension.

    Science.gov (United States)

    Liu, Zhan-Ying; Hu, Zhi-Quan; Wang, Tao; Chen, Yan-Ying; Zhang, Jianbin; Yu, Jing-Ran; Zhang, Tong; Zhang, Yong-Feng; Li, Yong-Li

    2013-07-01

    A microbial-flocculants-producing (MBF-producing) bacterium, named TG-1, was isolated from waste water of a starch factory, and identified as Klebsiella sp. TG-1. The microbial flocculants (MBF) produced by TG-1, named as MBF-TG-1, was applied to defecating the strong basic trona suspension in the trona industry. After optimizing medium and culturing conditions with single-factor and orthogonal designs, the highest flocculation rate of 86.9% was achieved. Chemical analysis showed that the purified microbial flocculants (MBF-TG-1) was mainly composed of polysaccharides (84.6%), with a small amount of protein or amino acid (11.1%). Bridging mechanism was supposed as the main flocculation mechanism by analyzing the flocculation process and the biochemistry properties of MBF-TG-1. The high flocculation rate (84%) was also achieved with a low-cost medium (the solid residue of tofu production from food industry).

  6. Progress in biogas. Biogas production from agricultural biomass and organic residues. Pt. 1 and 2. Proceedings (oral presentations and poster presentations); Fortschritt beim Biogas. Biogas aus landwirtschaftlicher Biomasse and organischen Reststoffen. T. 1 und 2. Tagungsband. Vortraege and Poster

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2007-07-01

    Within the International Conference ''Progress in Biogas - Biogas production from agricultural biomass and organic residues'' at the University Hohenheim (Stuttgart, Federal Republic of Germany) from 18th to 21st September, 2007, the following lectures were held: (1) Global relevance and potential of bioenergy for regional development; (2) Biogas electricity for France feed-in tariff and some other things to know before entering French market; (3) Policy drivers and future prospects for on-farm anaerobic digestion in Northern Ireland; (4) Biogas in Belgium, a swot analysis; (5) Status and prospects of biogas energy use in Ukraine; (6) Recent developments in Chinese agricultural biogas production; (7) Opportunities for agricultural based biogas systems in the province of Ontario, Canada; (8) Pre-treatment and digestion of separated collected household waste in Sweden; (9) To the problem of monitoring measures and prophylaxis measures with the utilization of organic residual substances in biological gas facilities from hygienic view; (10) Fermenting residues from biological gas facilities - nutrients and pollutants, possibilities of application in the agriculture; (11) Treatment and utilization of fermentation residues; (12) Potential of residual gas of NaWaRo feeded biogas plants in Baden-Wuerttemberg; (13) Operating analytics of biogas plants to improve efficiency and to ensure process stability; (14) The potential of biogas and electric power production from subproducts in the sugar and alcohol industries by the application of anaerobic digestion; (15) Co-digestion plant in dairy cattle farm in Emilia Romagna region (Italy); (16) Facing operational problems in a biodigeser in Yuvientsa - Amazonian Region of Ecuador; (17) Biogas plant instead of milk cow - payment and occupation with the use of grassilage; (18) Biogas in ecologic agriculture - experiences from 3 years of fermentation of grass-clover ley; (19) Combined solar-biogas basis for the

  7. Cellulase and xylanase productions by isolated Amazon Bacillus strains using soybean industrial residue based solid-state cultivation

    Directory of Open Access Journals (Sweden)

    Heck Júlio X.

    2002-01-01

    Full Text Available In Brazil, a large amount of a fibrous residue is generated as result of soybean (Glycine max protein production. This material, which is rich in hemicellulose and cellulose, can be used in solid state cultivations for the production of valuable metabolites and enzymes. In this work, we studied the bioconversion of this residue by bacteria strains isolated from water and soil collected in the Amazon region. Five strains among 87 isolated bacteria selected for their ability to produce either celullases or xylanases were cultivated on the aforementioned residue. From strain BL62, identified as Bacillus subtilis, it was obtained a preparation showing the highest specific cellulase activity, 1.08 UI/mg protein within 24 hours of growth. Concerning xylanase, the isolate BL53, also identified as Bacillus subtilis, showed the highest specific activity for this enzyme, 5.19 UI/mg protein within 72 hours of cultivation. It has also been observed the production of proteases that were associated with the loss of cellulase and xylanase activities. These results indicated that the selected microorganisms, and the cultivation process, have great biotechnological potential.

  8. Avaliação do potencial fertilizante de dois resíduos da indústria florestal Assessement of two residues from forestry industry as fertilizers

    Directory of Open Access Journals (Sweden)

    Carmo Horta

    2010-12-01

    Full Text Available A indústria florestal produz resíduos com características e potenciais de utilização muito distintos. Por um lado, a queima de biomassa florestal para obtenção de energia conduz à produção de grandes quantidades de cinzas como produto final e, por outro lado, durante o processo de produção da pasta de papel e na sequência do tratamento por causticação é também produzido um resíduo em quantidades significativas. O objectivo deste trabalho foi avaliar o potencial fertilizante destes dois resíduos, ou seja, das cinzas provenientes da incineração de biomassa florestal e das cinzas provenientes da causticação da pasta de papel, resíduos provenientes da indústria florestal. Num ensaio em vasos estudou-se a resposta do azevém à aplicação de doses crescentes destes resíduos que corresponderiam à aplicação ao solo de 0, 0,5, 1, 3 e 5 toneladas por ha. Verificou-se que a cinza de biomassa florestal pode ser aplicada ao solo, não se observando efeitos negativos na produção ou propriedades do solo. Esta aplicação conduzirá ao fornecimento de alguns nutrientes, nomeadamente K e Ca. Em solos com relação Ca/Mg elevada aconselha-se a aplicação simultânea de Mg. O resíduo proveniente da causticação da pasta de papel, deve ser incorporado no solo com antecedência relativamente à sementeira devido à sua causticidade. Nas culturas plurianuais não deverá ser utilizado. Apresentou valor como correctivo alcalinizante, possuindo elevado teor em Na que conduziu a um aumento significativo da condutividade eléctrica e do Na de troca, não se aconselhando uma aplicação em quantidades superiores a 1 t/ha.Forestry industry originates residues with distinct properties which can have also differences in its management reutilization. This study aimed at evaluating the fertilizer potential of forestry biomass burning ashes and causticizing lime mud from pulp and paper industry process, which are both residues from forestry

  9. Partial Optimization of Endo-1, 4-Β-Xylanase Production by Aureobasidium pullulansUsing Agro-Industrial Residues

    Directory of Open Access Journals (Sweden)

    Shaghayegh Nasr

    2013-12-01

    This finding indicates the feasibility of growing of A. pullulans strain SN090 on wheat bran as an alternate economical substrate in order for reducing the costs of enzyme production and using this fortified agro-industrial byproduct in formulation of animal feed.

  10. Generation and energy utilization of methane form industrial wastewater; Produccion y aprovechamiento energetico de metano a partir de agua residual industrial

    Energy Technology Data Exchange (ETDEWEB)

    Lebek, M.

    2009-07-01

    At the production site of a natural ingredients manufacturer for the food industry was necessary the adjustment of the WWTP to the enlargement of the production and its complement with a pre-treatment. The core of the treatment plan tis an UASB (Upflow Anaerobic Sludge Blanket) reactor where the wastewater is removed under anaerobic conditions. The main advantages of this treatment ar the operation stability and the high methane production. The biogas generated is cleaned before it is used during the production process as an energy resource. (Author)

  11. Study of uranium leaching from industrial residues of Industrias Nucleares do Brazil S.A. (INB), Caetite, Bahia, Brazil

    Energy Technology Data Exchange (ETDEWEB)

    Formiga, Thiago S.; Morais, Carlos A., E-mail: cmorais@cdtn.b [Centro de Desenvolvimento da Tecnologia Nuclear (CDTN/CNEN-MG), Belo Horizonte, MG (Brazil); Gomiero, Luiz A., E-mail: gomiero@inb.gov.b [Industrias Nucleares do Brasil S/A (INB), Caetite, BA (Brazil)

    2011-07-01

    The uraniferous district of Lagoa Real, located in the south-central region of the state of Bahia, has reserves estimated at 100,000 tons of uranium, which is enough to supply Angra I, II and III for 100 more years. The process adopted for the beneficiation of the uranium ore from Lagoa Real is heap leaching, a static process in which the ore is crushed, disposed in heaps and irrigated with a sulfuric acid solution to remove the uranium. This technique has a relatively low cost of implementation, although the yield of uranium recovery is low, with an uranium content in the leached residue of 700 {mu}g/g U{sub 3}O{sub 8} for ores with an initial content of 2,700 {mu}g/g U{sub 3}O{sub 8}. With the deepening of the mine pit, an increase in the carbonate content in the ore was noted, which required a higher acid consumption in the leaching. In order to reduce the concentration of carbonates, a study of the ore concentration by flotation column was accomplished. The flotation reject had high carbonate content, with a uranium content of about 2,300 {mu}g/g U{sub 3}O{sub 8} for flotation in one column and 1,100 {mu}g/g U{sub 3}O{sub 8} for flotation in two columns. This paper presents the study of the leaching process for the recovery of the uranium present in the residue of the heap leaching and in the carbonated residue from the flotation of the anomaly 13 ore. The results indicate the feasibility of treating the waste of the heap leaching through dynamic leaching. The study of the uranium leaching from the flotation residue through acid leaching technique indicated a recovery of 96% of uranium, however with a high consumption of acid, around 450 kg/t, showing that for this case, the most suitable technique for the process is alkaline leaching. (author)

  12. Bioemulsifier production by Microbacterium sp. strains isolated from mangrove and their application to remove cadmiun and zinc from hazardous industrial residue

    Directory of Open Access Journals (Sweden)

    Erick Aniszewski

    2010-03-01

    Full Text Available The contamination of ecosystems with heavy metals is an important issue in current world and remediation technologies should be in according to environmental sustainability concept. Bioemulsifier are promising agents to be used in metal removal and could be effective to many applications in environmental industries. The aims of this work was screening the potential production of bioemulsifier by microorganisms isolated from an oil contaminated mangrove, and evaluate cadmium and zinc removal potential of those strains from a hazardous industrial residue. From that, bioemulsifier-producing bacteria were isolated from urban mangrove sediments. Four isolates were identified as Microbacterium sp by 16S rRNA analysis and were able to reduce up to 53.3% of culture medium surface tension (TS when using glucose as carbon and energy source and 20.2% when sucrose was used. Suspensions containing bioemulsifier produced by Microbacterium sp. strains show to be able to remove cadmium and zinc from contaminated industrial residue, and its ability varied according carbon source. Significant differences in metal removal were observed by all strains depending on the carbon source. When glucose was used, Cd and Zn removal varied from 17 to 41%, and 14 to 68%, respectively. However, when sucrose was used it was observed only 4 to a maximum of 15% of Cd removal, and 4 to 17% of Zn removal. When the same tests were performed after ethanol precipitation, the results were different: the percentages of removal of Zn (7-27% and Cd (14-32% were higher from sucrose cultures. This is the first report of heavy metals removal by bioemulsifier from Microbacterium sp.

  13. Composting of solid and sludge residues from agricultural and food industries. Bioindicators of monitoring and compost maturity.

    Science.gov (United States)

    Ranalli, G; Bottura, G; Taddei, P; Garavani, M; Marchetti, R; Sorlini, C

    2001-01-01

    A study to monitor the composting process, to evaluate the effectiveness of bioindicators for the quality and maturity of cured compost obtained by a mixture of winery residues, sludges from dairies and solid residues from food processing (grape-stalks, grape-dregs, rice husks), was conducted. Composting process lasting five months was monitored by chemico-physical, spectroscopic (FTIR, DTG and DSC), microbiological and enzymatic analyses. Biological activities (ATP, DHA contents and several enzymatic activities), impedance variations (DT) of mixed cultures during growth and potential pathogens (E. coli and Salmonella sp.), were determined. The phytotoxicity tests gave a germination index higher than 90% and no significant genotoxic differences between controls and the compost samples were evidenced. Pathogens were not found on the cured compost that can therefore be satisfactorily used as amendment for agricultural crops. However, no single measurement of a composting process factor, biological, chemical or physical, gave a comprehensive view of the quality of a specific composting. We proposed a tool of bioindicators of potential activity and markers in combination for integrated evaluation of monitoring of composting process and compost quality. The responses of several enzymatic activities were positive and indicative of their favorable use capable to reveal even very small changes within microbial population and activity in test and monitoring of compost programmes.

  14. REDUCCIÓN DE LA CONTAMINACIÓN EN AGUA RESIDUAL INDUSTRIAL LÁCTEA UTILIZANDO MICROORGANISMOS BENÉFICOS

    Directory of Open Access Journals (Sweden)

    OSCAR FERNANDO HERRERA A

    Full Text Available El agua residual generada en la industria láctea posee altas cargas contaminantes que evidencian impactos en los cuerpos receptores y por tanto hacen necesarios técnicas más potentes para alcanzar las reducciones impuestas por la normatividad ambiental vigente. Los resultados aquí expuestos muestran la capacidad de una mezcla de microorganismos benéficos (MB para reducir cargas contaminantes en agua residual generados en una planta de producción en la industria láctea, teniendo como indicadores, demanda biológica de oxigeno (DBO5, demanda química de oxigeno (DQO, sólidos suspendidos totales (SST y sólidos Totales (ST para dos tipos de residuos, aguas de lavado (mañana y aguas de proceso (tarde, se encontraron reducciones en la DQO de 71,65 % (tarde y 66,96 % (mañana, en la DBO de 68,58 % (tarde y 61,22 % (mañana, en los ST de 70,45 % (tarde y 70,34 % (mañana y para los SST se alcanzaron reducciones de 78,77 % (tarde y 71,48 % (mañana. Los resultados obtenidos experimentalmente fueron analizados mediante un Análisis de varianza (ANOVA permitiendo encontrar niveles de interacción entre las variables de respuesta seleccionadas. Finalmente se hacen recomendaciones necesarias para alcanzar el cumplimiento de la Legislación Ambiental vigente en cuanto a calidad y uso del recurso hídrico

  15. PENGARUH PROFITABILITAS, SOLVABILITAS, REPUTASI AUDITOR, UKURAN PERUSAHAAN, KANDUNGAN LABA, DAN JENIS INDUSTRI PADA KETIDAKTEPATWAKTUAN PUBLIKASI LAPORAN KEUANGAN DI PT BURSA EFEK INDONESIA PERIODE 2007 - 2009

    Directory of Open Access Journals (Sweden)

    MADE GEDE WIRAKUSUMA

    2011-07-01

    Full Text Available The usefulness of financial report would decrease if it is not timely reported. The purpose of this study is to examine the impact of profitability, solvency, auditor reputation, company size, earnings content, and industry type on late publication of financial report on Indonesia Stock Market during period of 2007-2009. The hypotheses are tested using multiple regression technique. The results show that auditor reputation and company size significantly affect the late publication of financial reports of companies listed on Indonesia Stock Market during 2007-2009. Other variables, i.e profitability, solvency, and earnings information content do not affect the late publication. The control variable, industry type, also does not have any impact on the late financial report publication of the listed companies.

  16. First Industrial Tests of a Drum Monitor Matrix Correction for the Fissile Mass Measurement in Large Volume Historic Metallic Residues with the Differential Die-away Technique

    Energy Technology Data Exchange (ETDEWEB)

    Antoni, R.; Passard, C.; Perot, B.; Batifol, M.; Vandamme, J.C. [CEA, DEN, Cadarache, Nuclear Measurement Laboratory, F-13108 St Paul-lez-Durance, (France); Grassi, G. [AREVA NC, 1 place Jean-Millier, 92084 Paris-La-Defense cedex (France)

    2015-07-01

    The fissile mass in radioactive waste drums filled with compacted metallic residues (spent fuel hulls and nozzles) produced at AREVA La Hague reprocessing plant is measured by neutron interrogation with the Differential Die-away measurement Technique (DDT. In the next years, old hulls and nozzles mixed with Ion-Exchange Resins will be measured. The ion-exchange resins increase neutron moderation in the matrix, compared to the waste measured in the current process. In this context, the Nuclear Measurement Laboratory (NML) of CEA Cadarache has studied a matrix effect correction method, based on a drum monitor ({sup 3}He proportional counter inside the measurement cavity). A previous study performed with the NML R and D measurement cell PROMETHEE 6 has shown the feasibility of method, and the capability of MCNP simulations to correctly reproduce experimental data and to assess the performances of the proposed correction. A next step of the study has focused on the performance assessment of the method on the industrial station using numerical simulation. A correlation between the prompt calibration coefficient of the {sup 239}Pu signal and the drum monitor signal was established using the MCNPX computer code and a fractional factorial experimental design composed of matrix parameters representative of the variation range of historical waste. Calculations have showed that the method allows the assay of the fissile mass with an uncertainty within a factor of 2, while the matrix effect without correction ranges on 2 decades. In this paper, we present and discuss the first experimental tests on the industrial ACC measurement system. A calculation vs. experiment benchmark has been achieved by performing dedicated calibration measurement with a representative drum and {sup 235}U samples. The preliminary comparison between calculation and experiment shows a satisfactory agreement for the drum monitor. The final objective of this work is to confirm the reliability of the

  17. Prothrombin time (PT)

    Science.gov (United States)

    PT; Pro-time; Anticoagulant-prothrombin time; Clotting time: protime; INR; International normalized ratio ... PT is measured in seconds. Most of the time, results are given as what is called INR ( ...

  18. Study on roasting pretreatment process of silver extraction from industrial residues%工业废渣焙烧预处理提取银工艺研究

    Institute of Scientific and Technical Information of China (English)

    赖子球; 曾斌; 余攀; 蓝金莲

    2014-01-01

    Roasting-sulfuric acid leaching-cyanide leaching process is used to extract silver from complex industri-al residues.The effects of roasting atmosphere ,additives and their dosage ,roasting temperature and time have on ex-traction rate of silver were investigated by experiments .The results show that the optimal roasting conditions include rich oxygen ,3 %of sodium carbonate dosage ,903 K of roasting temperature ,and 3 h of roasting time .With the calci-ning leached by sulfuric acid and cyanide ,the extraction rate of silver was 78.41%,and then the content of silver in residues can be reduced from 0.049 %to 0.014 5 %.%采用焙烧-硫酸浸出-氰化浸出工艺,从某复杂工业废渣中提取银。通过试验考察了焙烧气氛、添加剂种类和加入量、焙烧温度、焙烧时间等预处理因素对银浸出率的影响。试验结果表明:优化焙烧预处理条件为富氧气氛、温度903 K、焙烧时间3 h、添加剂硫酸钠加入量3%;焙砂经酸浸-氰化浸出后,银的提取率为78.41%;废渣中银质量分数由原来的0.049%降低至0.0145%。

  19. 2,3-Butanediol production by Enterobacter aerogenes: selection of the optimal conditions and application to food industry residues

    Energy Technology Data Exchange (ETDEWEB)

    Perego, P.; Converti, A.; Del Borghi, A. [Dept. of Chemical Engineering, Genoa Univ. (Italy); Canepa, P. [Dept. of Chemistry and Industrial Chemistry, Genoa Univ. (Italy)

    2000-12-01

    Optimum values of temperature, pH, and starting substrate concentration are experimentally determined for 2,3-butanediol production by Enterobacter aerogenes through three set of batch fermentations of synthetic glucose solutions. The results of tests carried out at variable temperature show an optimum of 39 C and are used to estimate, for both fermentation and thermal inactivation, the activation enthalpies (7.19 and 23.6 kJ mol{sup -1}) and the related entropies (-0.32 and -0.27 kJ mol{sup -1} K{sup -1}). An optimum pH value of 6.0 is evidenced from batch runs at variable pH, whose results are also used to make reasonable hypotheses on the reaction controlling the metabolic pathway which leads to butanediol. The fermentability of different food industry wastes, namely starch hydrolysate, both raw and decoloured molasses, and whey, is finally checked. (orig.)

  20. Residues from the thermal conversion of waste from the meat industry as a source of valuable macro- and micronutrients.

    Science.gov (United States)

    Staroń, Paweł; Kowalski, Zygmunt; Staroń, Anita; Seidlerová, Jana; Banach, Marcin

    2016-03-01

    The increased consumption of meat (including poultry) observed over the last decade has led to the intensification of its production. With the production increase, the amount of generated waste also increases. Appropriate disposal of waste from the meat industry will significantly reduce the amount of such waste and its negative impact on the environment. The paper presents a method for the thermal neutralisation of feathers, poultry litter and meat and bone meal (MBM). Waste incineration was carried out in a stationary electric furnace, at a temperature varying in the range of 600-900°C. The resulting ashes were characterised by a high percentage of phosphorus (30-170 g/kg ash), calcium (20-360 g/kg ash) and other valuable macro- and micronutrients like copper, iron, manganese and zinc. The ashes produced during the thermal treatment are safe in terms of sanitary and can be used as additives enriching the fertilisers and soil improvers.

  1. Progress in biogas. Biogas production from agricultural biomass and organic residues. Pt. 1 and 2. Proceedings (oral presentations and poster presentations); Fortschritt beim Biogas. Biogas aus landwirtschaftlicher Biomasse and organischen Reststoffen. T. 1 und 2. Tagungsband. Vortraege and Poster

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2007-07-01

    Within the International Conference ''Progress in Biogas - Biogas production from agricultural biomass and organic residues'' at the University Hohenheim (Stuttgart, Federal Republic of Germany) from 18th to 21st September, 2007, the following lectures were held: (1) Global relevance and potential of bioenergy for regional development; (2) Biogas electricity for France feed-in tariff and some other things to know before entering French market; (3) Policy drivers and future prospects for on-farm anaerobic digestion in Northern Ireland; (4) Biogas in Belgium, a swot analysis; (5) Status and prospects of biogas energy use in Ukraine; (6) Recent developments in Chinese agricultural biogas production; (7) Opportunities for agricultural based biogas systems in the province of Ontario, Canada; (8) Pre-treatment and digestion of separated collected household waste in Sweden; (9) To the problem of monitoring measures and prophylaxis measures with the utilization of organic residual substances in biological gas facilities from hygienic view; (10) Fermenting residues from biological gas facilities - nutrients and pollutants, possibilities of application in the agriculture; (11) Treatment and utilization of fermentation residues; (12) Potential of residual gas of NaWaRo feeded biogas plants in Baden-Wuerttemberg; (13) Operating analytics of biogas plants to improve efficiency and to ensure process stability; (14) The potential of biogas and electric power production from subproducts in the sugar and alcohol industries by the application of anaerobic digestion; (15) Co-digestion plant in dairy cattle farm in Emilia Romagna region (Italy); (16) Facing operational problems in a biodigeser in Yuvientsa - Amazonian Region of Ecuador; (17) Biogas plant instead of milk cow - payment and occupation with the use of grassilage; (18) Biogas in ecologic agriculture - experiences from 3 years of fermentation of grass-clover ley; (19) Combined solar-biogas basis for the

  2. Use of neutralized industrial residue to stabilize trace elements (Cu, Cd, Zn, As, Mo, and Cr) in marine dredged sediment from South-East of France.

    Science.gov (United States)

    Taneez, Mehwish; Marmier, Nicolas; Hurel, Charlotte

    2016-05-01

    Management of marine dredged sediments polluted with trace elements is prime issue in the French Mediterranean coast. The polluted sediments possess ecological threats to surrounding environment on land disposal. Therefore, stabilization of contaminants in multi-contaminated marine dredged sediment is a promising technique. Present study aimed to assess the effect of gypsum neutralized bauxaline(®) (bauxite residue) to decrease the availability of pollutants and inherent toxicity of marine dredged sediment. Bauxaline(®), (alumia industry waste) contains high content of iron oxide but its high alkalinity makes it not suitable for the stabilization of all trace elements from multi-contaminated dredged sediments. In this study, neutralized bauxaline(®) was prepared by mixing bauxaline(®) with 5% of plaster. Experiments were carried out for 3 months to study the effect of 5% and 20% amendment rate on the availability of Cu, Cd, Zn, As, Mo, and Cr. Trace elements concentration, pH, EC and dissolved organic carbon were measured in all leachates. Toxicity of leachates was assessed against marine rotifers Brachionus plicatilis. The Results showed that both treatments have immobilization capacity against different pollutants. Significant stabilization of contaminants (Cu, Cd, Zn) was achieved with 20% application rate whereas As, Mo, and Cr were slightly stabilized. Toxicity results revealed that leachates collected from treated sediment were less toxic than the control sediment. These results suggest that application of neutralized bauxaline(®) to dredged sediment is an effective approach to manage large quantities of dredged sediments as well as bauxite residue itself.

  3. Study on Biological Degradation of Industrial Organic Waste Residue with surface Soil%土壤有机废渣的生物降解研究

    Institute of Scientific and Technical Information of China (English)

    齐向阳; 周波

    2011-01-01

    [ Objective ] The study aimed to discuss the influencing factors and effective measures for the biological degradation of chemicalindustrial waste residue with the soil microbial. [ Method ] In testing area the soil samples were taken from the surface soil in 20cm with quartering method and the burning weightlessness of unit quality was detected resp., and then the different waste residue was applied in the each experimental plot and the their burning weightlessness were determined after taking the samples in the interval of 5 d, thus the degradation data of organic waste residue in each block of soil was acquired. [ Result ] The biological degradation of organic waste residue with the soil microbial was effected by the waste residue property and surface area, soil oxygenation content, soil pH, soil moisture content and soil temperatures. The aerobic degradation of organic matter was much faster and fuller than the anaerobic degradation. As the soil pH affected the microbial activities, it should be maintained at 7~9. Controlling the soil moisture content of 50%~60% was the best condition of microbial activity. When the soil temperature was below zero, the biological degradation stopped basically. [ Conclusion ] In the actual application of industrially processing the organic waste residue, the some soil texture and some kinds of wasted residue still needed for further research so as to control the biodegradation rate and degree and its management measures. texture.%[目的]探讨土壤微生物降解化工废渣的影响因素及有效措施.[方法]在试验区用四分法在地表20cm内取土壤样品,分别测出单位质量的燃烧失重,再向每块试验区施入不同的废渣,每隔5d取样后,测定其燃烧失重,获得各块土壤有机废渣随时间的降解数据.[结果]土壤有机废渣的生物降解受废渣性质、废渣表面积、土壤含氧量、土壤pH、含湿量和土壤温度的影响.有机物的

  4. Gasificación con aire en lecho fluidizado de los residuos sólidos del proceso industrial de la naranja//Air gasification in fluidized bed of solid residue the orange industrial process

    Directory of Open Access Journals (Sweden)

    Leonardo Aguiar-Trujillo

    2012-12-01

    Full Text Available La industria procesadora de la naranja genera elevados volúmenes de residuos sólidos. Este residuo se ha utilizado en la alimentación animal y en procesos bioquímicos; pero no se ha aprovechado a través de la gasificación. El objetivo del trabajo fue determinar el aporte energético por medio del proceso de gasificación, realizándose estudios de los residuos sólidos de naranja, utilizando aire en reactor de lecho fluidizado burbujeante (variando la temperatura de gasificación, relación estequiométrica y altura del lecho. En el proceso se utilizó un diseño de experimento factorial completo de 2k, valorando la influencia de las variables independientes y sus interacciones en las respuestas, con un grado de significación del 95 %. Se obtuvieron los parámetros para efectuar el proceso de gasificación de los residuos sólidos de naranja, obteniendo un gas de bajo poder calórico, próximo a 5046 kJ/m3N, demostrando sus cualidades para su aprovechamiento energético.Palabras claves: gasificación con aire, lecho fluidizado, residuo de naranja._______________________________________________________________________________AbstractThe orange industrial process generates high volumes of solid residue. This residue has been used as complement in the animal feeding and biochemical processes; but it has not taken advantage through of the gasification process. The objective of the work was to determine the energy contribution by means ofthe gasification process, were carried out studies of the orange solid residue, using air in reactor of bubbling fluidized bed (varying the gasification temperature, air ratio and bed height. In the process a design of complete factorial experiment of 2k, was used, valuing the influence of the independent variables and its interactions in the answers, using a confidence level of 95 %. Were obtained the parameters to make the process of gasification of the orange solid residue, obtaining a gas of lower heating

  5. Bacterial biodiversity from anthropogenic extreme environments: a hyper-alkaline and hyper-saline industrial residue contaminated by chromium and iron.

    Science.gov (United States)

    Brito, Elcia M S; Piñón-Castillo, Hilda A; Guyoneaud, Rémy; Caretta, César A; Gutiérrez-Corona, J Félix; Duran, Robert; Reyna-López, Georgina E; Nevárez-Moorillón, G Virginia; Fahy, Anne; Goñi-Urriza, Marisol

    2013-01-01

    Anthropogenic extreme environments are among the most interesting sites for the bioprospection of extremophiles since the selection pressures may favor the presence of microorganisms of great interest for taxonomical and astrobiological research as well as for bioremediation technologies and industrial applications. In this work, T-RFLP and 16S rRNA gene library analyses were carried out to describe the autochthonous bacterial populations from an industrial waste characterized as hyper-alkaline (pH between 9 and 14), hyper-saline (around 100 PSU) and highly contaminated with metals, mainly chromium (from 5 to 18 g kg(-1)) and iron (from 2 to 108 g kg(-1)). Due to matrix interference with DNA extraction, a protocol optimization step was required in order to carry out molecular analyses. The most abundant populations, as evaluated by both T-RFLP and 16S rRNA gene library analyses, were affiliated to Bacillus and Lysobacter genera. Lysobacter related sequences were present in the three samples: solid residue and lixiviate sediments from both dry and wet seasons. Sequences related to Thiobacillus were also found; although strains affiliated to this genus are known to have tolerance to metals, they have not previously been detected in alkaline environments. Together with Bacillus (already described as a metal reducer), such organisms could be of use in bioremediation technologies for reducing chromium, as well as for the prospection of enzymes of biotechnological interest.

  6. Bio-oil production of softwood and hardwood forest industry residues through fast and intermediate pyrolysis and its chromatographic characterization.

    Science.gov (United States)

    Torri, Isadora Dalla Vecchia; Paasikallio, Ville; Faccini, Candice Schmitt; Huff, Rafael; Caramão, Elina Bastos; Sacon, Vera; Oasmaa, Anja; Zini, Claudia Alcaraz

    2016-01-01

    Bio-oils were produced through intermediate (IP) and fast pyrolysis (FP), using Eucalyptus sp. (hardwood) and Picea abies (softwood), wood wastes produced in large scale in Pulp and Paper industries. Characterization of these bio-oils was made using GC/qMS and GC×GC/TOFMS. The use of GC×GC provided a broader characterization of bio-oils and it allowed tracing potential markers of hardwood bio-oil, such as dimethoxy-phenols, which might co-elute in 1D-GC. Catalytic FP increased the percentage of aromatic hydrocarbons in P. abies bio-oil, indicating its potential for fuel production. However, the presence of polyaromatic hydrocarbons (PAH) draws attention to the need of a proper management of pyrolysis process in order to avoid the production of toxic compounds and also to the importance of GC×GC/TOFMS use to avoid co-elutions and consequent inaccuracies related to identification and quantification associated with GC/qMS. Ketones and phenols were the major bio-oil compounds and they might be applied to polymer production.

  7. Anaerobic digestion of selected Italian agricultural and industrial residues (grape seeds and leather dust): combined methane production and digestate characterization.

    Science.gov (United States)

    Caramiello, C; Lancellotti, I; Righi, F; Tatàno, F; Taurino, R; Barbieri, L

    2013-01-01

    A combined experimental evaluation of methane production (obtained by anaerobic digestion) and detailed digestate characterization (with physical-chemical, thermo-gravimetric and mineralogical approaches) was conducted on two organic substrates, which are specific to Italy (at regional and national levels). One of the substrates was grape seeds, which have an agricultural origin, whereas the other substrate was vegetable-tanned leather dust, which has an industrial origin. Under the assumed experimental conditions of the performed lab-scale test series, the grape seed substrate exhibited a resulting net methane production of 175.0 NmL g volatile solids (VS)(-1); hence, it can be considered as a potential energy source via anaerobic digestion. Conversely, the net methane production obtained from the anaerobic digestion of the vegetable-tanned leather dust substrate was limited to 16.1 NmL gVS(-1). A detailed characterization of the obtained digestates showed that there were both nitrogen-containing compounds and complex organic compounds present in the digestate that was obtained from the mixture of leather dust and inoculum. As a general perspective of this experimental study, the application of diversified characterization analyzes could facilitate (1) a better understanding of the main properties of the obtained digestates to evaluate their potential valorization, and (2) a combination of the digestate characteristics with the corresponding methane productions to comprehensively evaluate the bioconversion process.

  8. Study on the benefits of using the date palm trees residuals in Saudi Arabia for development of the non-traditional wooden industry

    Science.gov (United States)

    Ghulman, H. A.; Metwally, M. Nabil; Alhazmi, M. W.

    2017-02-01

    The average world consumption of wood is about 22million tones/year (Faostat,2013), representing about 50% of the total world raw materials, which represents great challenge to find out alternative sources, and the agricultural residues can share strongly in this field. Important interest was paid to the palm trees residues, such as the "date palm leaves midrib" (DPLM), leaflets, coir and spadix stems, as DPLM after drying, which can be used as an industrial substitute of raw wooden materials particularly for the manufacture of particle boards. The Kingdom of Saudi-Arabia has the date palm trees as the third place in the world after Iran and Iraq, while Islamic and Arabic countries represent more than 92% of the world date palms. Local date palms increased from 17.5 million in 1995 to about 32 million in 2014, which may save about 15% of KSA wood imports (2.5 million tons costing about 5730 SR millions, saving about SR million 855/year according to 2014 prices), with 10 pruned &dried DPLMs /tree/year, if it is used only for particle board manufacture. The study includes a survey of the KSA wood imports; the dominant species of palms and their numbers, meteorological conditions, evaluation of DPLM drying rate in open air under the effect of solar radiation, achieving final moisture content of 8-12% in about 4 weeks. Also measurements of the mechanical properties of the dried Saudi DPLM samples approved the excellent mechanical properties as well as Beech and Spruce woods.

  9. Use of Residual Biomass from the Textile Industry as Carbon Source for Production of a Low-Molecular-Weight Xylanase from Aspergillus oryzae

    Directory of Open Access Journals (Sweden)

    Gilvan Caetano Duarte

    2012-10-01

    Full Text Available Pretreated dirty cotton residue (PDCR from the textile industry was used as an alternative carbon source for the submerged cultivation of Aspergillus oryzae and the production of xylanases. The filtered culture supernatant was fractionated by ultrafiltration followed by three chromatographic steps, which resulted in the isolation of a homogeneous low-molecular-weight xylanase (Xyl-O1 with a mass of 21.5 kDa as determined by sodium dodecyl sulfate-polyacrilamide gel electrophoresis (SDS-PAGE co-polymerized with 0.1% oat spelt xylan. Enzyme catalysis was the most efficient at 50 °C and pH 6.0. The Km values (mg·mL−1 for the soluble fraction of oat spelt and birchwood xylans were 10.05 and 3.34, respectively. Xyl-O1 was more stable in the presence of 5,5-dithio-bis-(2-nitrobenzoic acid (DTNB, 1,4-dithiothreitol (DTT, l-cysteine or β-mercaptoethanol, which increased the rate of catalysis by 40%, 14%, 40% or 37%, respectively. The enzyme stability was improved at pH 7.0 in the presence of 20 mM l-cysteine, with the retention of nearly 100% of the activity after 6 h at 50 °C. Xyl-O1 catalyzed the cleavage of internal β-1,4 linkages of the soluble substrates containing d-xylose residues, with a maximum efficiency of 33% for the hydrolysis of birchwood xylan after 12 h of incubation. Identification of the hydrolysis products by high-performance anion exchange chromatography coupled with pulsed amperometric detection (HPAEC-PAD indicated the predominance of the hydrolysis products X2-X6 during the first 12 h of incubation and the accumulation of higher xylooligomers after the elution of the last xylooligomer standard, xylohexaose.

  10. Boosting biogas production from sewage sludge by adding small amount of agro-industrial by-products and food waste residues.

    Science.gov (United States)

    Maragkaki, A E; Fountoulakis, M; Kyriakou, A; Lasaridi, K; Manios, T

    2017-04-17

    In Greece, in many cities, wastewater treatment plants (WWTPs) operate their own anaerobic digestion (AD) facility in order to treat sewage sludge rather than achieve optimum biogas production. Nowadays, there is a growing interest regarding the addition of other co-substrates in these existing facilities in order to increase gas yield from the biomass. This practice may be possible by adding small amount of co-substrates which will not affect significantly in the designed hydraulic retention time. Nonetheless, the lack of experimental data regarding this option is a serious obstacle. In this study, the effect of co-digestion sewage sludge, with small amount of agro-industrial by-products and food wastes is examined in lab-scale experiments. Specifically, co-digestion of SS and food waste (FW), grape residues (GR), crude glycerol (CG), cheese whey (CW) and sheep manure (SM), in a small ratio of 5-10% (v/v) was investigated. The effect of agro-industrial by-products and food waste residues on biogas production was investigated using one 1L and three 3L lab-scale reactors under mesophilic conditions at a 24-day hydraulic retention time. The biogas production rate reached 223, 259, 406, 572, 682 and 1751 mlbiogas/lreactor/d for 100% SS, 5% SM & 95% SS, 10% CW & 90% SS, 5% FW & 95% SS, 5% FW & 5% CG & 90% SS and 5% CG & 95% SS respectively. Depending on the co-digestion material, the average removal of total chemical oxygen demand (TCOD) ranged between 20% (5% SM & 95% SS) and 76% (5% FW & 5% CG & 90% SS). Reduction in the volatile solids ranged between 26% (5% SM & 95% SS) and 62% (5% FW & 5% CG & 90% SS) for organic loading rates between 0.8kgVSm(-3)d(-1) and 2.0kgVSm(-3)d(-1). Moreover, co-digestion improved biogas production from 14% (5% SM & 95% SS) to 674% (5% CG & 95% SS). This work suggests that WWTPs in Greece can increase biogas production by adding other wastes to the sewage sludge without affecting the operation of existing digesters and without requiring

  11. Polychlorobenzenes and polychlorinated biphenyls in ash and soil from several industrial areas in North Vietnam: residue concentrations, profiles and risk assessment.

    Science.gov (United States)

    Nguyen, Thi Hue; Nguyen, Thi Thu Thuy; Nguyen, Hoang Tung

    2016-04-01

    Polychlorinated benzenes (PCBzs) including penta- and hexachlorobenzene can be unintentionally formed from thermal processes in different industrial activities, and very little information is available on the contamination and emission characteristics of these new persistent organic pollutants from industries in Vietnam. In this study, contamination of PCBzs (including penta- and hexachlorobenzene, named PeCBz and HCB, respectively) and PCBs (including CB-28, 52, 101, 153, 138, 180) in fly ash, bottom ash and soil from combustion processes of waste incineration, metallurgy (steel making and zinc production) and cement production from several provinces in the Northern Vietnam, including Hai Duong, Hanoi, Bac Ninh, Hai Phong and Thai Nguyen, was preliminary investigated. The PCBzs concentrations in fly ash, bottom ash and soil ranged from 2.7 to 100 ng g(-1), from 2.7 to 159 ng g(-1) and from 0.28 to 33.9 ng g(-1), respectively. Relatively high residues of PeCBz in fly ash and bottom ash from municipal waste incinerators in some provinces from the Northern Vietnam were encountered. Total PCBs concentrations ranged from 18.0 to 8260 ng g(-1), from 1.0 to 10600 ng g(-1) and from 14.5 to 130 ng g(-1) for the fly ash, bottom ash and soil, respectively. Daily intakes of PeCBz, HCB and PCBs through soil ingestion and dermal exposure estimated for children ranged 0.33-9.93 (mean 3.14), 0.39-21.1 (mean 4.9) and 6.09-1530 ng/kg bw/day (mean 346), respectively; and these intakes were about 4.7-5.4 times higher than those estimated for adult. The intakes of PeCBz and HCB were relatively low, while those for PCBs exceeded WHO TDI for some samples.

  12. TENORM: Coal Combustion Residuals

    Science.gov (United States)

    Burning coal in boilers to create steam for power generation and industrial applications produces a number of combustion residuals. Naturally radioactive materials that were in the coal mostly end up in fly ash, bottom ash and boiler slag.

  13. Invisibility and PT symmetry

    OpenAIRE

    MOSTAFAZADEH, Ali

    2013-01-01

    PHYSICAL REVIEW A 87, 012103 (2013) Invisibility and PT symmetry Ali Mostafazadeh* Department of Mathematics, Koc¸ University, Sarıyer 34450, Istanbul, Turkey (Received 9 July 2012; published 3 January 2013) For a general complex scattering potential defined on a real line, we show that the equations governing invisibility of the potential are invariant under the combined action of parity and time-reversal (PT ) transformation. We determine the PT -symmetric as well as no...

  14. Ethanol production from residual wood chips of cellulose industry: acid pretreatment investigation, hemicellulosic hydrolysate fermentation, and remaining solid fraction fermentation by SSF process.

    Science.gov (United States)

    Silva, Neumara Luci Conceição; Betancur, Gabriel Jaime Vargas; Vasquez, Mariana Peñuela; Gomes, Edelvio de Barros; Pereira, Nei

    2011-04-01

    Current research indicates the ethanol fuel production from lignocellulosic materials, such as residual wood chips from the cellulose industry, as new emerging technology. This work aimed at evaluating the ethanol production from hemicellulose of eucalyptus chips by diluted acid pretreatment and the subsequent fermentation of the generated hydrolysate by a flocculating strain of Pichia stipitis. The remaining solid fraction generated after pretreatment was subjected to enzymatic hydrolysis, which was carried out simultaneously with glucose fermentation [saccharification and fermentation (SSF) process] using a strain of Saccharomyces cerevisiae. The acid pretreatment was evaluated using a central composite design for sulfuric acid concentration (1.0-4.0 v/v) and solid to liquid ratio (1:2-1:4, grams to milliliter) as independent variables. A maximum xylose concentration of 50 g/L was obtained in the hemicellulosic hydrolysate. The fermentation of hemicellulosic hydrolysate and the SSF process were performed in bioreactors and the final ethanol concentrations of 15.3 g/L and 28.7 g/L were obtained, respectively.

  15. Agro-industrial residues and starch for growth and co-production of polyhydroxyalkanoate copolymer and α-amylase by Bacillus sp. CFR-67

    Directory of Open Access Journals (Sweden)

    T. R. Shamala

    2012-09-01

    Full Text Available Polyhydroxyalkanoates (PHA and α-amylase (α-1,4 glucan-4-glucanohydrolase, E.C. 3.2.1.1 were co-produced by Bacillus sp. CFR-67 using unhydrolysed corn starch as a substrate. Bacterial growth and polymer production were enhanced with the supplementation of hydrolysates of wheat bran (WBH or rice bran (RBH individually or in combination (5-20 g L-1, based on weight of soluble substrates-SS. In batch cultivation, a mixture of WBH and RBH (1:1, 10 g L-1 of SS along with ammonium acetate (1.75 g L-1 and corn starch (30 g L-1 produced maximum quantity of biomass (10 g L-1 and PHA (5.9 g L-1. The polymer thus produced was a copolymer of polyhydroxybutyrate-co-hydroxyvalerate of 95:5 to 90:10 mol%. Presence of WBH and corn starch (10-50 g L-1 in the medium enhanced fermentative yield of α-amylase (2-40 U mL-1 min-1. The enzyme was active in a wide range of pH (4-9 and temperature (40-60ºC. This is the first report on simultaneous production of copolymer of bacterial PHA and α-amylase from unhydrolysed corn starch and agro-industrial residues as substrates.

  16. Co-composting of oil exhausted olive-cake, poultry manure and industrial residues of agro-food activity for soil amendment.

    Science.gov (United States)

    Sellami, F; Jarboui, R; Hachicha, S; Medhioub, K; Ammar, E

    2008-03-01

    The co-composting of exhausted olive-cake with poultry manure and sesame shells was investigated. These organic solid wastes were watered by the confectionary wastewater which is characterized by its high content of residual sugars raising its COD. Four aerated windrows were performed to establish the effects of confectionary by-products on the compost process. Different mixtures of the agro-industrial wastes were used. During the composting process, physico-chemical parameters (temperature, moisture, pH, electrical conductivity, total carbon and total nitrogen) were studied. The stability of the biological system was noticed after 70 days. The final products were characterized by their relatively high organic matter content, and low C/N ratio of 14-17. The humidification of the windrows with the wastewater seemed to have accelerated the composting process in comparison to a windrow humidified with water. In addition, the organic matter degradation was enhanced to reach 55-70%. The application of the obtained composts to soil appeared to significantly improve the soil fertility. Indeed, field experiments showed an increase in potato yield; the production was 30.5-37.5 tons ha(-1), compared to 30.5 tons ha(-1) with farm manure.

  17. Kinetics of coffee industrial residue pyrolysis using distributed activation energy model and components separation of bio-oil by sequencing temperature-raising pyrolysis.

    Science.gov (United States)

    Chen, Nanwei; Ren, Jie; Ye, Ziwei; Xu, Qizhi; Liu, Jingyong; Sun, Shuiyu

    2016-12-01

    This study was carried out to investigate the kinetics of coffee industrial residue (CIR) pyrolysis, the effect of pyrolysis factors on yield of bio-oil component and components separation of bio-oil. The kinetics of CIR pyrolysis was analyzed using distributed activation energy model (DAEM), based on the experiments in thermogravimetric analyzer (TGA), and it indicated that the average of activation energy (E) is 187.86kJ·mol(-1). The bio-oils were prepared from CIR pyrolysis in vacuum tube furnace, and its components were determined by gas chromatography/mass spectrometry (GC-MS). Among pyrolysis factors, pyrolysis temperature is the most influential factor on components yield of bio-oil, directly concerned with the volatilization and yield of components (palmitic acid, linoleic acid, oleic acid, octadecanoic acid and caffeine). Furthermore, a new method (sequencing temperature-raising pyrolysis) was put forward and applied to the components separation of bio-oil. Based on experiments, a solution of components separation of bio-oil was come out.

  18. Evaluation of laboratory and industrial meat and bone meal combustion residue as cadmium immobilizing material for remediation of polluted aqueous solutions: "chemical and ecotoxicological studies".

    Science.gov (United States)

    Coutand, M; Deydier, E; Cyr, M; Mouchet, F; Gauthier, L; Guilet, R; Savaete, L Bernues; Cren, S; Clastres, P

    2009-07-30

    Meat and Bone Meals (MBM) combustion residues (ashes) are calcium and phosphate-rich materials. The aim of this work is to evaluate ashes efficiency for remediation of cadmium-contaminated aqueous solutions, and to assess the bioavailability of cadmium on Xenopus laevis larvae. In this study both industrial (MBM-BA) and laboratory (MBM-LA) ashes are compared regarding their efficiency. Kinetic investigations reveal that cadmium ions are quickly immobilized, with a maximum cadmium uptake at 57 mg Cd(2+)/g of ashes for MBM-LA, two times higher than metal uptake quantity of MBM-BA, in our experimental conditions. Chemical and X-ray diffraction analysis (XRD) reveal that Cd(2+) is mainly immobilized as Ca(10-x)Cd(x)(PO(4))(6)(OH)(2) by both ashes, whereas otavite, Cd(CO(3)), is also involved for MBM-LA in cadmium uptake. Otavite formation could be explained by the presence of carbonates in MBM-LA, as observed by IR. Genotoxicity of cadmium solution on Xenopus larvae is observed at 0.02, 0.2 and 2mg Cd(2+)/L. However addition of only 0.1g/L MBM-LA inhibits these effects for the above concentration values whereas Cd(2+) bioaccumulation in larvae's liver is similar for both experiments, with and without ashes.

  19. Agro-industrial residues in biotechnological production of xylitol/ Resíduos agroindustriais para produção biotecnológica de xilitol

    Directory of Open Access Journals (Sweden)

    Maria Celia de Oliveira Hauly

    2004-05-01

    Full Text Available Lignocellulosic residues, such as sugarcane bagasse, rice and oat straw and forest cuttings, are abundant and inexpensive sources of carbohydrates (cellulose and hemicellulose with potential application in several conversion processes. Xylose, the predominant sugar in the hemicellulose fraction can be converted to xylitol. Xylitol is a polyol with some interesting properties that can make it an important product for the food and pharmaceutical industry. It is a compound with sweetness similar to that sucrose, is non-cariogenic, tolerated by diabetics and recommended for obese people. This polyol is currently produced by chemical catalysis of the xylose from lignocellulosic residues. However, this process needs expensive purification steps to obtain pure xylitol. Alternatively, it can be produced by biotechnological methods, using microorganisms, specially yeasts. These processes consist of hemicellulosic hydrolysate fermentation from agro-industrial residues, wich could compete with the traditional chemical method. The present work aims the accomplishment of a review about xylitol detaching the structural aspects, ways of attainment and applications; main hemicellulosic substrates used in its production; acid hydrolysis and treatment of the hemicellulosic hydrolysate for use as substrate to produce xylitol by microbial way.Resíduos lignocelulósicos tais como bagaço de cana-de-açúcar, palha de arroz, casca de aveia e resíduos florestais representam fontes abundantes e não dispendiosas de carboidratos (celulose e hemicelulose com potencial aplicação em processos de conversão química ou microbiana em produtos de interesse comercial. Xilose, o açúcar predominante na fração hemicelulósica pode ser convertido em xilitol. O xilitol é um poliol com propriedades físico-química importantes para as indústrias alimentícia e farmacêutica. É um composto com doçura semelhante à da sacarose, anticariogênico, tolerado por diabéticos e

  20. Structures, Mixed Types - Residual Waste Operations

    Data.gov (United States)

    NSGIC GIS Inventory (aka Ramona) — A Residual Waste Operation is a DEP primary facility type related to the Waste Management Residual Waste Program. Residual waste is waste generated at an industrial,...

  1. Progress in biogas II - Biogas production from agricultural biomass and organic residues. Pt. 1. Proceedings; Progress in Biogas II - Biogasproduktion aus landwirtschaftlicher Biomasse und organischen Reststoffen. T. 1. Tagungsband

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2011-08-12

    biogas production - Methabe yield and energy balance (R. Bolduan); (19) Evaluation of a pre-treatment process for improved methane production from grass silage (A. Orozco); (20) Anaerobic fungi and biogas production (J. Prochazka); (21) Preservation of sugar beets for biogas production (A. Wagner); (22) Fibre, biogas and compost from banana agro-residues (leaves, pseudostem and rachis) by anaerobic digestion in plug flow type digester (H. Chanakya); (23) Extraction of biogas from waste products of he sugarcane industry (J. Rietzler); (24) Practical experiences with the digestion of straw in 2-stage AD plants - Extension of the value chain (W. Danner); (25) Improving biogas production on wastewater treatment plants by co-digestion of grass (D. Klein); (26) Generation of algal biomass for biogas production: energetic and environmental from a Life Cycle Assessment (LCA) perspective (F. Romagnoli); (27) Risk reduction in spreading plant pathogens by anaerobic digestion? First results from laboratory experiments (M. Heiermann); (28) Demand-oriented biogas production for the generation of peak load (R. Wallmann); (29) Investigation of mesophilic and thermophilic bioleaching method in a two-phase anaerobic digestion process (M. Schoenberg): (30) Efficient hydrogen fermentation for 2-stage anaerobic digestion processes: Conversion of sucrose containing substrates (S. Noebauer); (31) Process development of two-phase pressure formation - Influence of gas solubilities (A.-M. Wonneberger); (32) Benefits and limitations when treating liquid pig manure in an anaerobic membrane bioreactor (P. Messerl); (33) Experiences with continuous high-rate thermophilic dry anaerobic digestion of energy crops (L. De Baere); (34) The Sauter-biogas-system: spraying instead of stirring (S. Sauter); (35) Biogas production from raw palm oil mill effluent using a pilot-scale anaerobic hybrid reactor (C. Wangnai); (36) Eta max - the biogas power plant with high biological efficiency (M. Niederbacher); (37

  2. EFEKTIVITAS IMPLEMENTASI CORPORATE SOCIAL RESPOSIBILITY PT. ABC

    Directory of Open Access Journals (Sweden)

    Rizkiaji Rikky Djunaedi

    2015-12-01

    Full Text Available The purposes of this study were 1 to analyze public perceptions on the effectiveness of the implementation of CSR of PT. A B C; 2 to analyze the implementation of CSR activities by PT. A B C; 3 to formulate strategies to improve the effectiveness of the implementation of CSR of PT. A B C. The method used in this research was descriptive analysis with a survey approach to measure expectations and performance assessment on the CSR implemented programs by the public, and there were respondents 104 respondents involved in this study. This study used the Importance-Performance Analysis (IPA aiming to determine the effectiveness of the programs that have been implemented and to map the relationship between the expectations and the performance of each variable. Furthermore, using a SWOT analysis of the data processing and of the objectives of the program made by CSR is expected to provide recommendations to develop strategies in order to increase the effectiveness of CSR program of ABC Company.Keywords: corporate social responsibility (CSR, mining industry, implementation analysis, IPA, SWOTAbstrakTujuan dari  penelitian ini adalah 1 menganalisis persepsi masyarakat teradap efektivitas implementasi CSR PT. ABC; 2 menganalisis pelaksanaan  kegiatan CSR oleh PT. ABC; 3 merumuskan strategi untuk meningkatkan efektivitas implementasi CSR PT. ABC. Metode yang digunakan dalam penelitian ini adalah analisis deskriptif dengan pendekatan survey untuk mengukur harapan dan penilaian kinerja oleh masyarakat atas program CSR yang diterapkan. Jumlah responden sebanyak 104 orang.  Dalam penelitian ini digunakan Analisis Importance-Performance Analysis (IPA bertujuan untuk mengetahui efektifitas dari program-program yang telah dijalankan serta  memetakan hubungan antara harapan dengan kinerja dari masing-masing variabel. Selanjutnya menggunakan analisis SWOT dari hasil pengolahan data dan dari tujuan program dibuat oleh CSR sehingga dapat memberikan rekomendasi

  3. 我国行业层面全要素生产率的实证分析%INVARIANCE PROPERTIES ANALYSIS OF SOLOW'S PRODUCTIVITY RESIDUAL BASED ON INDUSTRIAL LEVEL DATA OF CHINA

    Institute of Scientific and Technical Information of China (English)

    薛克明

    2011-01-01

    We judge the invariance property of both original and cost-based Solow residual using industrial level data of China. The result shows that the two types of Solow residual has the same invariance property in a large part of the industries we concerned, which means most of the industries have no significant long-term monopolistic profits. But mining, quarrying, transport, storage, post & telecommunications, banking and insurance rejected the invariance hypothesis in both two types of Solow residuals, this could be a sign of increasing returns to scale coupled with monopoly power in those industries.%采用我国9大行业的投入产出数据,选择国防支出和国际原油价格作为工具变量,对Solow提出的Solow余量与工具变量进行了无关性检验,结果显示对于多数行业两种检验的结果基本一致,表明我国多数行业不存在长期超额利润;但采矿业、交通运输业、邮电通信和金融业在两种检验下都拒绝了无关性原假设,表明这些行业存在规模收益递增和垄断结合的现象.

  4. Progress in biogas II - Biogas production from agricultural biomass and organic residues. Pt. 1. Proceedings; Progress in Biogas II - Biogasproduktion aus landwirtschaftlicher Biomasse und organischen Reststoffen. T. 1. Tagungsband

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2011-08-12

    biogas production - Methabe yield and energy balance (R. Bolduan); (19) Evaluation of a pre-treatment process for improved methane production from grass silage (A. Orozco); (20) Anaerobic fungi and biogas production (J. Prochazka); (21) Preservation of sugar beets for biogas production (A. Wagner); (22) Fibre, biogas and compost from banana agro-residues (leaves, pseudostem and rachis) by anaerobic digestion in plug flow type digester (H. Chanakya); (23) Extraction of biogas from waste products of he sugarcane industry (J. Rietzler); (24) Practical experiences with the digestion of straw in 2-stage AD plants - Extension of the value chain (W. Danner); (25) Improving biogas production on wastewater treatment plants by co-digestion of grass (D. Klein); (26) Generation of algal biomass for biogas production: energetic and environmental from a Life Cycle Assessment (LCA) perspective (F. Romagnoli); (27) Risk reduction in spreading plant pathogens by anaerobic digestion? First results from laboratory experiments (M. Heiermann); (28) Demand-oriented biogas production for the generation of peak load (R. Wallmann); (29) Investigation of mesophilic and thermophilic bioleaching method in a two-phase anaerobic digestion process (M. Schoenberg): (30) Efficient hydrogen fermentation for 2-stage anaerobic digestion processes: Conversion of sucrose containing substrates (S. Noebauer); (31) Process development of two-phase pressure formation - Influence of gas solubilities (A.-M. Wonneberger); (32) Benefits and limitations when treating liquid pig manure in an anaerobic membrane bioreactor (P. Messerl); (33) Experiences with continuous high-rate thermophilic dry anaerobic digestion of energy crops (L. De Baere); (34) The Sauter-biogas-system: spraying instead of stirring (S. Sauter); (35) Biogas production from raw palm oil mill effluent using a pilot-scale anaerobic hybrid reactor (C. Wangnai); (36) Eta max - the biogas power plant with high biological efficiency (M. Niederbacher); (37

  5. EVALUASI SISTEM PENGELOLAAN LIMBAH PADAT B3 PT. INDOFARMA, TBK BEKASI

    Directory of Open Access Journals (Sweden)

    Syafrudin Syafrudin

    2012-02-01

    Full Text Available Besides yielding product, production process also will yield discard product that we called as waste. Thetype of the waste are depended on the raw materials and other process that happened during theproduction process. As a pharmacy industry, PT. Indofarma Tbk also generate waste from their productionprocess which have potency to contaminate the environment because the most material that use for theproduction are chemicals that need to be handled seriously. The waste can be categorize as HazardousWaste and needed furthermore management to control, so it will be secure for the environment. Forpharmacy industry, the hazardous waste is in the form of the chemicals, Waste Water Treatment’s sludge,residu production process like dust from dust collector, incinerator’s fly ash, and other materials which iscame from hazardous materials.

  6. Evolution of mechanical properties of a residue from the secondary aluminium remelting industry stabilized with gypsum; Evolucion de las propiedades mecanicas de un residuo de la metalurgia secundaria del aluminio estabilizado con yeso

    Energy Technology Data Exchange (ETDEWEB)

    Tayibi, H.; Perez, C.; Lopez, F. A.; Lopez-Delgado, A.

    2005-07-01

    Aluminium dust from aluminium remelting industry is a hazardous residue because of its high reactivity in the presence of water (production of ammonia, methane, hydrogen sulphide...) potential aluminothermy and its content in leaching heavy metals. In order to apply the new European Directive about landfill of waste, a Stabilization/Solidification (S/S) process was developed in the CENIM with the aim of decreasing its reactivity and to assure an easy transport and storage of the residue. Gypsum was used as a binder material. This work summarizes the study of the mechanical properties of the stabilized residue en comparison with the gypsum ones. The reactivity of the dust, before and after the S/S process was investigated by analysing the ammonia and metallic aluminium. (Author) 16 refs.

  7. Integrated project: Microbiological and physiological studies on the presence of residual concentrations in mineral-oil-contaminated soils after rehabilitation. Final report. Pt. 2; Mikrobiologische und physiologische Untersuchungen zur Frage der Restkonzentration bei der Sanierung mineraloelkontaminierter Boeden. Abschlussbericht. T. 2

    Energy Technology Data Exchange (ETDEWEB)

    Miethe, D.; Riis, V.; Stimming, M.

    1996-01-04

    It has been known for a long time that microorganisms are able to utilise mineral oils. Today various methods are practised which exploit autochthonous microorganisms` ability to utilise mineral oils. The main problem of microbial decomposition of hydrocarbons is that mineral oil residues remain. The aim of the present research project was therefore to determine the limits of the metabolisability of the substrate and find out why residues remain. Mineral oils and residual fractions differ markedly in their decomposability. Intermediate distillates are easily decomposed to a degree of 95-97% by well-adapted consorts. For high-boiling mineral oils (bp>400 C) the degree of decomposition is approx. 60%. Extracts from contaminated sites range from 40 to 60% in their degree of decomposability. The incomplete microbial decomposition of mineral oils is mainly due to their structure. There remain chemically and thermally extremely, inert hydrocarbons (mainly aliphatic and aromatic fused-ring systems) which are either hardly metabolisable or not at all. An important factor in soils or at other contaminated sites is that some of the substrate is not available because it is bound to the matrix thus increasing the proportion of residue. The next task after examining and presenting the causes of incomplete decomposition is to minimise residual mineral oil concentrations remaining after microbial decomposition. Here the use of special surfactants or of auxiliary substrates could point a way. Project applications to this end have already been submitted to the Federal Ministry for Education and Research. (orig.) [Deutsch] Dass Mikroorganismen in der Lage sind, Mineraloele zu verwerten, ist seit langem bekannt. Verfahren, die das Potential autochthoner Mikroorganismen zur Verwertung von Mineraloelen nutzen sind Praxis. Hauptproblem beim mikrobiellen Abbau der Kohlenwasserstoffe ist das Verbleiben von Mineraloelresten. Das Ziel des Forschungsvorhabens war die Ermittlung der Grenzen

  8. PT-symmetric strings

    Energy Technology Data Exchange (ETDEWEB)

    Amore, Paolo, E-mail: paolo.amore@gmail.com [Facultad de Ciencias, CUICBAS, Universidad de Colima, Bernal Díaz del Castillo 340, Colima, Colima (Mexico); Fernández, Francisco M., E-mail: fernande@quimica.unlp.edu.ar [INIFTA (UNLP, CCT La Plata-CONICET), División Química Teórica, Diag. 113 y 64 (S/N), Sucursal 4, Casilla de Correo 16, 1900 La Plata (Argentina); Garcia, Javier [INIFTA (UNLP, CCT La Plata-CONICET), División Química Teórica, Diag. 113 y 64 (S/N), Sucursal 4, Casilla de Correo 16, 1900 La Plata (Argentina); Gutierrez, German [Facultad de Ciencias, CUICBAS, Universidad de Colima, Bernal Díaz del Castillo 340, Colima, Colima (Mexico)

    2014-04-15

    We study both analytically and numerically the spectrum of inhomogeneous strings with PT-symmetric density. We discuss an exactly solvable model of PT-symmetric string which is isospectral to the uniform string; for more general strings, we calculate exactly the sum rules Z(p)≡∑{sub n=1}{sup ∞}1/E{sub n}{sup p}, with p=1,2,… and find explicit expressions which can be used to obtain bounds on the lowest eigenvalue. A detailed numerical calculation is carried out for two non-solvable models depending on a parameter, obtaining precise estimates of the critical values where pair of real eigenvalues become complex. -- Highlights: •PT-symmetric Hamiltonians exhibit real eigenvalues when PT symmetry is unbroken. •We study PT-symmetric strings with complex density. •They exhibit regions of unbroken PT symmetry. •We calculate the critical parameters at the boundaries of those regions. •There are exact real sum rules for some particular complex densities.

  9. Evaluation of clayey masses compositions starting from the residue incorporation of the red ceramic industry to obtain tubular ceramic membranes; Avaliacao das composicoes de massas argilosas a partir da incorporacao de residuo da industria de ceramica vermelha na obtencao de membranas ceramicas tubulares

    Energy Technology Data Exchange (ETDEWEB)

    Silva, Adriano Lima da; Chaves, Alexsandra Cristina; Luna, Carlos Bruno Barreto; Neves, Gelmires de Araujo; Lira, Helio de Lucena, E-mail: adrianolimadasilva@hotmail.com, E-mail: alexsandra.chaves@ifap.edu.br, E-mail: brunobarretodemaufcg@hotmail.com, E-mail: gelmires@ufcg.edu.br, E-mail: helio@ufcg.edu.br [Universidade Federal de Campina Grande (UAEMa/CCT/UFCG), PB (Brazil). Unidade Academica de Engenharia de Materiais

    2017-01-15

    The inappropriate residue disposal of red ceramic industry is very high. Nowadays, one of the major challenges is the investigation of processes to obtain alternative materials, enabling the use of these residues to manufacture new materials. This work's objective is to study clayey masses' compositions starting from the residue incorporation of the red ceramic industry to be used in tubular ceramic membranes. Two compositions of ceramic masses were established, composition A (50% of residue) and composition B (70% of residue). Granulometric analysis of the ceramic masses presented an average size of particles, what indicates membranes in the microfiltration scale. Another observed factor is related to the increase of residue amount, what favored a decrease in the ceramic mass' plasticity. A rise in the apparent porosity was also observed, probably because of a possible growing in the bigger pores numbers, due to the sintering high temperature and the elevation of residue quantity itself. (author)

  10. PT quantum mechanics.

    Science.gov (United States)

    Bender, Carl M; DeKieviet, Maarten; Klevansky, S P

    2013-04-28

    PT-symmetric quantum mechanics (PTQM) has become a hot area of research and investigation. Since its beginnings in 1998, there have been over 1000 published papers and more than 15 international conferences entirely devoted to this research topic. Originally, PTQM was studied at a highly mathematical level and the techniques of complex variables, asymptotics, differential equations and perturbation theory were used to understand the subtleties associated with the analytic continuation of eigenvalue problems. However, as experiments on PT-symmetric physical systems have been performed, a simple and beautiful physical picture has emerged, and a PT-symmetric system can be understood as one that has a balanced loss and gain. Furthermore, the PT phase transition can now be understood intuitively without resorting to sophisticated mathematics. Research on PTQM is following two different paths: at a fundamental level, physicists are attempting to understand the underlying mathematical structure of these theories with the long-range objective of applying the techniques of PTQM to understanding some of the outstanding problems in physics today, such as the nature of the Higgs particle, the properties of dark matter, the matter-antimatter asymmetry in the universe, neutrino oscillations and the cosmological constant; at an applied level, new kinds of PT-synthetic materials are being developed, and the PT phase transition is being observed in many physical contexts, such as lasers, optical wave guides, microwave cavities, superconducting wires and electronic circuits. The purpose of this Theme Issue is to acquaint the reader with the latest developments in PTQM. The articles in this volume are written in the style of mini-reviews and address diverse areas of the emerging and exciting new area of PT-symmetric quantum mechanics.

  11. Alternative alloys for platinum jewelry? New structures in Pt-Hf and Pt-Mo

    Science.gov (United States)

    Gilmartin, Erin; Corbitt, Jacqueline; Hart, Gus

    2008-10-01

    The only known intermetallic structure with an 8:1 stoichiometry is that of Pt8Ti. It is intriguing that an ordered compound would occur at such low concentrations of the minority atom. But this structure occurs in about a dozen binary intermetallic systems. The formation of an ordered structure can significantly enhance the performance of the material, particularly the hardness. Pt- and Pd-rich ordered structures have been experimentally studied in the systems Pt/Pd-X where X is Ti, V, Cr, Zr, Nb, M, Hf, Ta, and W. We took a broader look at 80 Pt/Pd rich alloys to find new candidates for the 8:1 structure and have found about 20. In order to verify our predictions, we used the cluster expansion to find the stable structures. We first applied the cluster expansion to Pt-Hf and Pt-Mo because these two candidates are the most likely to form the 8:1 structure. These new candidates can have applications in the jewelry and catalysis industries.

  12. Micro thermoelectric power plant with residual biomass in a rice industry - efficiency increase due to a technological alteration; Micro central termeletrica com biomassa residual em uma industria de arroz - aumento de eficiencia por alteracao da tenologia

    Energy Technology Data Exchange (ETDEWEB)

    Hoffman, Ronaldo; Hoffmann, Rejane S.; Lagemann, Angela M.; Cremonese, Guilherme; Collazzo, Gabriela C. [Universidade Federal de Santa Maria (UFSM), RS (Brazil). Dept. de Engenharia Quimica; Machado, Luis A. [Universidade Federal de Santa Maria (UFSM), RS (Brazil). Dept. de Eletromecanica e Sistemas de Potencia; Mayer, Flavio D. [Universidade Federal de Santa Maria (UFSM), RS (Brazil). Curso de Pos-Graduacao em Engenharia de Producao]. E-mail: f.mayer@mail.ufsm.br

    2006-07-01

    A thermal electric system was implanted at Sao Pedro do Sul, Rio Grande do Sul, BR, for electric power self production. The initial analysis confirm the economic viability of the project and his contribution for the environment, through elimination of residue deposits and mitigation of the 4612 tCO{sub 2} equivalent greenhouse gases. Besides, an emphasis must be given to the contribution of the electric power decentralized generation for the regional development.

  13. PT symmetry and supersymmetry

    CERN Document Server

    Znojil, M

    2002-01-01

    A re-formulated, non-Hermitian version of the Witten's supersymmetric quantum mechanics is presented. Its use of pseudo-Hermitian (so called PT symmetric) Hamiltonians is reviewed and illustrated via several forms of an innovated supersymmetric partnership between strongly singular ("spiked") harmonic oscillators.

  14. Do wood-based panels made with agro-industrial residues provide environmentally benign alternatives? An LCA case study of sugarcane bagasse addition to particle board manufacturing

    DEFF Research Database (Denmark)

    Silva, Diogo Aparecido Lopes; Lahr, Francisco Antonio Rocco; Pavan, Ana Laura Raymundo

    2014-01-01

    environmental impacts? Could it substitute wood as raw material? Accordingly, this paper presents a life cycle assessment (LCA) study of particle board manufactured with sugarcane bagasse residues.The cradle-to-gate assessment of 1 m3 of particle board made with sugarcane bagasse (PSB) considered three main...

  15. PT-GC-CAFS联用技术测定污水处理厂外排水中烷基汞残留量%Determination of the Alkyl Mercury Residue in External Drainage of Partial of Sewage Treatment Plants by Purging Capture-Gas Chromatography-Cold Atomic Fluorescence Spectrometry

    Institute of Scientific and Technical Information of China (English)

    高兰兰; 徐浩; 杨琼; 戴刚

    2016-01-01

    建立了吹扫捕集-气相色谱-冷原子荧光( PT-GC-CAFS)联用技术、多功能自动进样器进样测定污水处理厂外排水中烷基汞残留量的方法. 用烷基化试剂直接衍生,吹扫捕集吸附/富集,以PEG20M填充柱为分离柱,用冷原子荧光作为检测器进行测定,整体分析工作在10 min内完成. 在所选实验条件下,方法对所测甲基汞、乙基汞的线性相关系数分别为0.999 9、1.000,最低检出限分别为0.002、0.003 ng/L,相对标准偏差为1.4% ~10.2%,2.3% ~9.7%;在不同质量浓度水平上进行加标回收率实验,甲基汞的回收率为93.7% ~101.7%,乙基汞为94.1% ~103.6%. 该方法用于污水处理厂外排水中烷基汞残留量的分析测定,结果令人满意.%A confirmative method was developed with purge and trap-GC separation-cold atomic fluorescence spectrophotometer ( PT-GC-CAFS) to detect the residues of alkyl mercury in external drainage of sewage treatment plants by multifunctional automatic sampler. Using direct derivative alkyl mercury by Alkylating reagent, adsorption/enrichment by PT, with PEG20M packed column for separation column, and with cold atomic fluorescence spectrophotometer as a detector to detect mercury in environmental water samples, the overall analysis of the work to be done within 10 min. The method showed that good linear correlation coefficient of methyl mercury′s and ethyl mercury′s was 0.999 9 and 1.000, the relative standard deviation was (RSD=1.4%-10.2%) and ( RSD=2.3%-9.7%) , respectively. With different quality levels to Standard addition recovery test sample, the recovery rate of methyl mercury was 93.7%-101.7%, ethyl mercury was 94.1%-103.6%. The method was applied to determine the alkyl mercury residue in external drainage samples of sewage treatment plants. The results were satisfactory.

  16. Nanospheres caped Pt(II and Pt (IV: synthesis and evaluation as antimicrobial and Antifungal Agent

    Directory of Open Access Journals (Sweden)

    Öğütçü Hatice

    2017-03-01

    Full Text Available Antimicrobial and antifungal polymers are gaining the attention of pharmaceutical makers and industrial design. Nanospheres-Polymers attached Platinum(II / (IV complexes have been synthesized to investigate antimicrobial activities. Firstly, nanospheres involving Schiff bases were synthesized from (aminomethyl polystyrene and four substitute salicylaldehyde (2-hydroxy benzaldehyde, 5-fluoro-2-hydroxy benzaldehyde, 5-kloro-2-hydroxy benzaldehyde, 5-bromo-2-hydroxy benzaldehyde. Secondly, polymers attached Platinum(II / (IV complexes have been prepared by means of template method. The IR spectra show that the ligands act in a monovalent bidentate fashion all nanospheres involving Schiff bases. Square-planar and octahedral structures are proposed for Pt(II and Pt(IV, respectively. All these substances have been examined for antibacterial activity against pathogenic strains, and antifungal activity. In particular, Pt(IV complexes were more potent bactericides than all of the synthesized substances.

  17. Spore production in Paecilomyces lilacinus (Thom. samson strains on agro-industrial residues Produção de esporos em linhagens de Paecilomyces lilacinus (Thom. samson em resíduos agro-industriais

    Directory of Open Access Journals (Sweden)

    Diogo Robl

    2009-06-01

    Full Text Available Paecilomyces lilacinus has potential for pests control. We aimed to analyze mycelial growth and spore production in P. lilacinus strains in several agro-industrial residues and commercial media. This study suggests alternative nutrient sources for fungi production and that the biotechnological potential of agro-industrial refuses could be employed in byproducts development.Paecilomyces lilacinus apresenta potencial para controle de pragas. O objetivo deste trabalho foi analisar o crescimento micelial e a produção de esporos de linhagens de P. lilacinus em resíduos agro-industriais e meios comerciais. Este estudo sugere fontes alternativas para produção de fungos com potencial biotecnológico para desenvolvimento de bioprodutos.

  18. Materials recovery from shredder residues

    Energy Technology Data Exchange (ETDEWEB)

    Daniels, E. J.; Jody, B. J.; Pomykala, J., Jr.

    2000-07-24

    Each year, about five (5) million ton of shredder residues are landfilled in the US. Similar quantities are landfilled in Europe and the Pacific Rim. Landfilling of these residues results in a cost to the existing recycling industry and also represents a loss of material resources that are otherwise recyclable. In this paper, the authors outline the resources recoverable from typical shredder residues and describe technology that they have developed to recover these resources.

  19. Management of residual materials from industries NORM in conventional LANDFILL; Gestion de materiales residuales procedentes de instrias NORM en vertederos de residuos convencionales

    Energy Technology Data Exchange (ETDEWEB)

    Robles Atienza, B.; Mora Canadas, J. C.

    2013-07-01

    An option that could be developed to manage waste with content radioactive exceeds the unconditional exemption/clearance levels established, would be its storage in the already these landfills of industrial waste, provided that will ensure compliance with the relevant criteria radiological established by the authorities. (Author)

  20. Residuation theory

    CERN Document Server

    Blyth, T S; Sneddon, I N; Stark, M

    1972-01-01

    Residuation Theory aims to contribute to literature in the field of ordered algebraic structures, especially on the subject of residual mappings. The book is divided into three chapters. Chapter 1 focuses on ordered sets; directed sets; semilattices; lattices; and complete lattices. Chapter 2 tackles Baer rings; Baer semigroups; Foulis semigroups; residual mappings; the notion of involution; and Boolean algebras. Chapter 3 covers residuated groupoids and semigroups; group homomorphic and isotone homomorphic Boolean images of ordered semigroups; Dubreil-Jacotin and Brouwer semigroups; and loli

  1. Chemical transformations of organic matter during the composting of wood industry wastes (residues); Transformacoes quimicas da materia organica durante a compostagem de residuos da industria madeireira

    Energy Technology Data Exchange (ETDEWEB)

    Budziak, Cristiane R.; Maia, Claudia M.B.F.; Mangrich, Antonio S. [Parana Univ., Curitiba, PR (Brazil). Dept. de Quimica]. E-mail: mangrich@quimica.ufpr.br

    2004-06-01

    Composting of sawdust and paper mill sludge, using a 'Kneer' process reactor, was studied in an attempt to elaborate upon organic matter transformation during the process and to define parameters to measure the compost maturity level. Temperature, electron paramagnetic resonance data, ash and C, H, N and S contents, and a spectroscopic method using ultraviolet-visible (UV-VIS) for alkaline (pH = 8.5) and solid samples was used to study the maturity of the compost samples. These parameters were measured in 6 humic acids extracted from the compost samples during 29 days. The results of this work show that the 'Kneer' process is efficient in transforming ligno-celulitic residues in a short time (29 days), into an organic fertilizer material with application perspectives (author)

  2. Purification process of Industrialization preparation of pesticide residue grade n-hexane%农残级正己烷的产业化制备纯化工艺研究

    Institute of Scientific and Technical Information of China (English)

    鄢雄伟; 全灿; 金君素; 黄挺; 李红梅

    2012-01-01

    以工业级正已烷为原料,通过脱色-连续精馏-过滤等一系列纯化工艺制备农残级正己烷,用紫外吸光度、纯度( GC-FID)和杂质峰高(GC-ECD)等检测值作为农残质量控制指标.产品质量与占当前国内垄断市场的进口试剂水平相当.通过试验确定了较为合适的工艺条件:二氧化硅为脱色剂,用量是原料质量的2%,然后用10%的蒸馏水水洗一次,连续精馏装置的导热油加热温度为98℃,脱轻塔和成品塔的回流比分别为10∶1和4∶1,重组分放料速率20 mL/min,产率可达70%左右.%Pesticide residue grade solvents have the characteristic of ultra high purity, low U V value, low pH value, low moisture content and low evaporation residue, which do not have those controlled impurity peak in pesticide chromato-graphic detection. This project funded by the China government, in which the industrialization process of pesticide residue grade n-hexane was studied, the industrial n-hexane as crude after purification approaches including decoloration,distillation and filtration. The optimized process parameters are: firstly utilizing 2% of silicon dioxide as decoloration agent then is rinsed with distilled water before distillation. The heating temperature of two distillation towers is 88 ℃ with reflux ratio of 10:1 and 4:1 for both respectively, the discharge rate of heavy component is 20 mLAnin.the yield is approximately 70%. This patented technique will meet pesticide residue grade n-hexane market in China or globally.

  3. Characterization of azo dyes on Pt and Pt/polyaniline/dispersed Pt electrodes

    Energy Technology Data Exchange (ETDEWEB)

    Molina, J.; Fernandez, J.; Rio, A.I. del; Bonastre, J. [Departamento de Ingenieria Textil y Papelera, EPS de Alcoy, Universitat Politecnica de Valencia, Plaza Ferrandiz y Carbonell s/n, 03801 Alcoy (Spain); Cases, F., E-mail: fjcases@txp.upv.es [Departamento de Ingenieria Textil y Papelera, EPS de Alcoy, Universitat Politecnica de Valencia, Plaza Ferrandiz y Carbonell s/n, 03801 Alcoy (Spain)

    2012-06-15

    The electrochemical characterization of two organic dyes (amaranth and procion orange MX-2R) has been performed on Pt electrodes and Pt electrodes coated with polyaniline and dispersed Pt. Electrodes with different Pt loads have been synthesized and characterized obtaining that a load of 300 {mu}g cm{sup -2} was the optimum one. Scanning electron microscopy (SEM) and atomic force microscopy (AFM) was employed to observe the distribution and morphology of the Pt nanoparticles. The electroactivity of the electrodes has also been characterized by means of scanning electrochemical microscopy (SECM). The chemical characterization of Pt dispersed Pani coated Pt electrodes (Pt-Pani-Pt) was performed by means of X-ray photoelectron spectroscopy (XPS). The electrochemical characterization of the dyes has been performed by means of cyclic voltammetry. Voltammograms have shown that the presence of the dyes diminishes characteristic Pt oxidation and reduction peaks. However, redox processes due to the dyes, appeared in the voltammograms. The different species responsible of these redox processes were generated in the vicinity of the electrode and were not adsorbed on the electrode surface since after stirring, the different redox processes disappeared. Characterization with different scan rates showed that redox processes of both dyes were controlled by diffusion.

  4. Regulatory Promotion of Waste Wood Reused as an Energy Source and the Environmental Concerns about Ash Residue in the Industrial Sector of Taiwan

    Directory of Open Access Journals (Sweden)

    Wen-Tien Tsai

    2012-11-01

    Full Text Available The objective of this paper was to provide a preliminary analysis of the utilization of energy derived from waste wood in Taiwan, a highly industrialized country with a high dependence (over 99% on imported energy. The discussion focuses on the status of waste wood generation and its management over the past decade. Findings show that the quantities of biomass waste collected for reuse purposes in the industrial sectors of Taiwan has exhibited an increasing trend, from about 4000 tons in 2001 to over 52,000 tons in 2010. Although waste wood can be reused as a fuel and raw material for a variety of applications based on regulatory promotion, the most commonly used end use is to directly utilize it as an auxiliary fuel in industrial utilities (e.g., boilers, heaters and furnaces for the purpose of co-firing with coal/fuel oil. The most progressive measure for promoting biomass-to-power is to introduce the feed-in tariff (FIT mechanism according to the Renewable Energy Development Act passed in June 2009. The financial support for biomass power generation has been increasing over the years from 0.070 US$/kWh in 2010 to 0.094 US$/kWh in 2012. On the other hand, the environmental regulations in Taiwan regarding the hazard identification of wood-combusted ash (especially in filter fly-ash and its options for disposal and utilization are further discussed in the paper, suggesting that waste wood impregnated with chromated copper arsenate (CCA and other copper-based preservatives should be excluded from the wood-to-energy system. Finally, some recommendations for promoting wood-to-energy in the near future of Taiwan are addressed.

  5. Problems of residues in cereals and bread. Pt. 2

    Energy Technology Data Exchange (ETDEWEB)

    Ocker, H.D.; Seibel, W.

    1980-01-01

    More than 1200 samples of cereals (wheat and rye) and more than 180 representative bread samples of the years 1975 to 1978 have been analyzed with regard to Pb and Cd concentrations (AAS tubular graphite cell). The findings are presented in 4 tables and 11 histograms and discussed. In wheat, the mean Pb concentration was a constant 0.05 ppm while the Cd concentration increased from 0.05 ppm to 0.06 ppm. In rye, the mean Pb concentration increased from 0.08 ppm to 0.11 ppm while the Cd concentration remained at 0.12 ppm. Variations between samples were considerable. Mean values for bread were between 0.021 and 0.059 ppm for Pb and between 0.011 and 0.037 ppm for Cd (referred to the fresh substance). The decontaminating effect of cereals processing was clearly proven.

  6. Aproveitamento de resíduos de painéis de madeira gerados pela indústria moveleira na produção de pequenos objetos Small objetcs manufactured with wood panel residues generated by rhe furniture industry

    Directory of Open Access Journals (Sweden)

    Luciana Barbosa de Abreu

    2009-02-01

    Full Text Available Os painéis reconstituídos à base de madeira ganharam espaço antes ocupado pela madeira maciça, o que tem gerado volume expressivo de resíduos. A indústria moveleira contribui para a geração desses resíduos, que se apresentam como alternativa viável para a exploração de sua aplicação na produção artesanal de pequenos objetos. Este trabalho teve por objetivo produzir pequenos objetos com painéis e com mistura de resíduos de painéis de madeira, a fim de comparar suas qualidades. A partir de 10 projetos gráficos, três artesãos confeccionaram 10 pequenos objetos, utilizando painéis de MDF (Medium Density Fiberboard, OSB (Oriented Strand Board e compensado. Cada artesão produziu nove exemplares de cada objeto. Um quarto artesão confeccionou os mesmos objetos com resíduos de três empresas do polo moveleiro da cidade de Ubá, MG, com três repetições, sendo comparados os atributos de qualidade dos objetos. Concluiu-se que todos os painéis são adequados para a confecção dos objetos e alguns se destacam em relação a outros, conforme o atributo avaliado. Os objetos confeccionados com a mistura de resíduos de painéis de madeira tiveram acabamento uniforme e não apresentaram diferenças significativas em relação aos produzidos com painéis com relação aos atributos funcionalidade, peso, proporção e simetria. A mistura de resíduos de diferentes painéis influenciou negativamente a avaliação dos atributos acabamento, beleza e cor. Um objeto produzido a partir de resíduos do mesmo painel pode ser mais harmonioso e atrativo. É tecnicamente viável a produção de pequenos objetos a partir de resíduos de painéis de madeira vindos de indústrias moveleiras.Wood residue panels have been used in substitution of solid wood. As a consequence, the volume of residues has been increasing day-by-day. The furniture industries are the major generators of these residues. Their use as raw material for the production of

  7. Application of Ceramic Filter in Tailings and Treatment of Other Industrial Waste Residue%陶瓷过滤机在选矿尾矿及其它工业废渣处理的应用

    Institute of Scientific and Technical Information of China (English)

    赵德平; 贾彪

    2009-01-01

    介绍了陶瓷过滤机与其他过滤机相比具有生产率高、节能降耗、清洁环保等方面的优点,列举了陶瓷过滤机在国内几大矿山的使用情况,指出陶瓷过滤机在矿山、冶金、化工、建材等行业中废渣、废水处理方面的广泛应用前景.%Ceramic filter has advantages over other filters in high productivity, energy saving and consumption reducing, and environmental protection. The service conditions of the ceramic filter in domestic large mines are cited. It considers that the ceramic filter has extensive use in treatment of waste residue and waste water of mine, metallurgy, chemical industry and building materials.

  8. Possibilities of using steelmaking industry residues in the removal of metals from liquid effluents; Posibilidades sobre el uso de residuos de la industria del acero en la elimiancion de metales de efluentes liquidos

    Energy Technology Data Exchange (ETDEWEB)

    Martin, M. I.; Lopez, F. A.; Lopez-Delgado, A.; Perez, C.; Alguacil, F. J.

    2004-07-01

    A study is made of the removal of metals present in aqueous effluents using a residue of the steelmaking industry deaminated rolling mill scale. Mill scale can be considered a cheap materials for the removal of toxic metals due to its high content in iron oxides and metallic iron. A study of the removal of Cd2+, Zn2+, Pb2+, Cu2+ ions from aqueous solutions was made, studying several variables that effect the process. The removal of cadmium, zinc and lead corresponding to a superficial adsorption process, was evaluated using the theories of Langmuir and Freundlich. The removal of copper occurs thorough a process of oxidation-reduction or cementation (Cu''2+/Fe''0). The possibilities of desorption were studied too. (Author) 18 refs.

  9. Selective laser extraction of the Pt group metals

    Energy Technology Data Exchange (ETDEWEB)

    Fadeeva, S.; Krynetsky, B.; Prokhorov, A.; Zhidkov, A. [General Physics Institute, Russian Academy of Science, Moscow (Russian Federation)

    1995-11-15

    The interest to the platinum-group metals extraction from solutions, especially industry waste, is stimulated by their extraordinary chemical inert. The traditional chemical methods of the extraction are uneffective. Have been investigated process of the extraction of metal Pt-group from acid solutions. Discussed processes reduction of noble metals by resonance laser action.

  10. Research on autoclaved reaction activities of Si/Al -based industrial residues%硅铝质工业废弃物蒸压反应活性研究

    Institute of Scientific and Technical Information of China (English)

    陆金驰

    2011-01-01

    Mass fractions of active SiO2 and A12O3 ,and infrared spectrum (IR) were used to analyze the autoclaved reaction activities of Si/Al - based industrial residues, such as fly ash and coal dust slag etc. Results showed that autoclaved reaction activities of Si/Al - based industrial residues had an evident relationship with the mass fractions of active SiO2 and A12O3 ,and Si - O stretching vibration frequency about 1 100 cm-1 in strong absorption region of IR,that is the more mass fractions of active SiO2 and Al2 O3, and the lower Si-O stretching vibration frequency about 1 100 cm -1 in strong absorption region of IR, the stronger autoclaved reaction activities and the higher compressive strength of autoclaved products.%通过测定活性二氧化硅、氧化铝含量及红外光谱分析等方法研究粉煤灰、煤粉炉渣等硅铝质工业废弃物的蒸压反应活性.结果表明,硅铝质工业废弃物的蒸压反应活性与其活性二氧化硅、氧化铝含量及红外光谱1 100 cm-1附近强吸收区的Si-O伸缩振动频率存在明显的对应关系,即活性二氧化硅、氧化铝含量越高,红外光谱1 100 cm-1附近强吸收区的Si-O伸缩振动频率越低,蒸压反应活性越强,蒸压制晶强度越高.

  11. Behaviour mechanisms and correlation between lead (Pb) and its isotope (210)Pb in industrial residue as an indicator for waste characterization.

    Science.gov (United States)

    Vaasma, Taavi; Bityukova, Liidia; Kiisk, Madis; Özden, Banu; Tkaczyk, Alan Henry

    2016-12-01

    Total lead and (210)Pb concentrations were determined in various ash fractions (collected from two of the world's largest oil shale-fired power plants) by inductively coupled plasma mass-spectrometry (ICP-MS) and gamma spectrometry. Results show a clear increase in total lead (values up to 193 ppm in filter ashes) and (210)Pb (values up to 148 Bq kg(-1) in filter ashes) concentrations in the ash fractions from the furnace towards the filter ashes. A strong positive linear correlation (Pearson's bivariate correlation remained between 0.86 and 0.99) was determined between total lead concentration (ppm) and (210)Pb activity concentration (Bq kg(-1)) within all the boilers under observation. The constant concentration ratio between total lead and (210)Pb remained around one (with minor exceptions), independent of the sampling location and the used combustion technology. The determined concentration ratio can be applicable as an indicative tool in waste material characterization. It also provides multiple additions to the general material characterization approach, by integrating radiological and elemental studies and providing an option to rapidly obtain initial indicative information about the residues. This in turn helps to generate the initial information to work out the next steps in waste material management.

  12. Obtenção de um compósito a partir da biomassa residual e industrial utilizando um reator de contracorrente

    Directory of Open Access Journals (Sweden)

    Felix Martin Carbajal Gamarra

    2012-01-01

    Full Text Available The major preoccupation and challenge for researchers is finding sustainable alternatives for the reuse of biomass. In view of this, the goal of this research was to produce a new compact material with minimum defects in its anatomic structure and excellent particle-resin interaction. The material obtained is a type of MDF panel composite made from industrial solid vegetable biomass. The MDF panel was produced using a vegetable biomass blend of Eucalyptus wood (Eucalyptus sp., asparagus (Asparagus officinalis, sugar-cane (Saccharum officinarum, and synthetic resin from urea-formaldehyde (UF. Physical-mechanical properties of the MDF, including modulus of rupture, strength, modulus of elasticity, density, thermal conductivity and perpendicular traction, were evaluated following EN and ASTM norms. The results obtained were consistent with and, in some cases, superior to those found in the literature. Thus, this research demonstrated the potential sustainable reuse of vegetal biomass to produce useful panels.

  13. Reuse of a residue from petrochemical industry with portland cement Reutilización de un residuo de la industria petroquímica como adición al cemento portland

    Directory of Open Access Journals (Sweden)

    Janneth Torres Agredo

    2012-06-01

    Full Text Available In this article the possibility of using waste from the petrochemical industry,as partial replacement of Portland cement is studied, evaluating the presenceof contaminants in the waste and the encapsulation, once it is confined on the cement. This has been done, in order to find a use to this residue without cause damage to the environment. This residue, called spent fluid catalytic cracking catalyst (FCC, is mainly formed by a type Y zeolite, which is dispersing in an inorganic oxides matrix. The toxicity characteristic leaching proceeding was applied, in mortars adding with 20% of FCC as Portland cement replacement. The results showed that the residue does not represent a problem from the point of view of the leaching of elements, such as As, Pb, Zn, Cr, and La, which were below to the permissible limits. Additionally, the pozzolanic activity of FCC was evaluated according to ASTM C311, where the efficiency of the residue as pozzolanic addition is demonstrated. With the results the importance of reusing a residue of the petrochemical industry is emphasized, that decreases the amount of cement to be used and improves the mechanical resistance of the materials containing it.En el presente artículo se estudia la posibilidad de utilizar un residuo de la industria petroquímica, como sustitución parcial del cemento Portland, evaluando la presencia de elementos contaminantes en el residuo y su encapsulación, una vez se haya confinado con el cemento. Lo anterior, con el fin de determinar si su uso como material de construcción, puede o no causar un efecto negativo al medio ambiente. El residuo, denominado catalizador usado de craqueo catalítico (FCC, es un material que está compuesto por una zeolita tipo Y, dispersa en una matriz de óxidos inorgánicos. Se aplicó la técnica de TCLP (del inglés Toxicity Characteristic Leaching Procedure, en morteros adicionados con un 20%, de FCC con respecto a la cantidad de cemento. Los resultados

  14. Preparation of Strotium Carbanate for Industrial Use with Strotium Residue as Material%以金属锶残渣为原料制备工业碳酸锶

    Institute of Scientific and Technical Information of China (English)

    王运朝; 段亚宏; 王玉凯

    2012-01-01

    Strotium carbanate for industrial use was prepared by leaching strotium residue with ammonium chloride and the leaching solution was carbonized by ammonium hydrogen carbonate.The optimum technological conditions of leaching strotium residue were that leaching temperature was 80 ℃, leaching time was 2 hours, ammonium chloride was added to make the pH value of the solution to 8-9,particle size of strontium residue was less 80 mesh, solid-liquid ratio was 1:4. In carbonation stage,the amout of ammonium hydrogen carbonate added was the 110% of the theoretical amount.In the technological conditions,strontium was leached strontium carbonate was prepared, leaching rate of the strontium could reach more than 92.5%, product quality could meet the type 11 of HG / T2969-2010 standard. The techonology is a new way for rycycling strotium residue.%对用氯化铵溶液浸锶,浸出液碳化得碳酸锶成品的工艺条件进行了研究。实验得到氯化铵浸锶的最佳工艺条件为:浸锶温度为80℃,浸锶时间为2 h,氯化铵加入量为使溶液pH值至8~9,锶渣粒度〈80目,固液比1∶4。碳化阶段碳酸氢铵加入量为其理论量的110%。按该条件浸锶,并制备碳酸锶,锶的浸出率可达92.5%以上,产品质量符合HG/T2969—2010Ⅱ型标准。该工艺实现了锶资源的二次利用,为锶渣的回收再利用开辟了一条新途径。

  15. Innovative applications of welding technology in the field of nuclear industry. Pt. 1. Along the nuclear fuel cycle; Innovative Anwendungsfelder der Schweisstechnik im Bereich der Nuklearindustrie. T. 1. Entlang des nuklearen Brennstoffkreislaufs

    Energy Technology Data Exchange (ETDEWEB)

    Krueger, Juergen [alfalang, Lippstatt (Germany)

    2013-07-01

    For the tungsten inert gas welding (TIG) in the nuclear industry special requirements apply. This part of the paper gives an overview and deals with the topics of welding technology in uranium enrichment and manufacturing of nuclear fuel. [German] Fuer das Wolfram-Inertgasschweissen (WIG) in der Nuklearindustrie gelten ganz besondere Anforderungen. Dieser Teil des Beitrags gibt einen Ueberblick und befasst sich mit den Themen Schweisstechnik bei der Urananreicherung und beim Herstellen von nuklearem Brennstoff.

  16. Electrochemical oxidation of methanol on Pt/(RuxSn1-xO2 nanocatalyst

    Directory of Open Access Journals (Sweden)

    Krstajić Mila N.

    2013-01-01

    Full Text Available The Ru-doped SnO2 powder, (RuxSn1-xO2, with the Sn:Ru atomic ratio of 9:1 was synthesized and used as a support for Pt nanoparticles (30 mass% loading. The (RuxSn1-xO2 support and Pt/(RuxSn1-xO2 catalyst were characterized by X-ray diffraction, energy dispersive X-ray spectroscopy and transmission electron microscopy (TEM. (RuxSn1-xO2 was found to be two-phase material consisting of probably solid solution of RuO2 in SnO2 and pure RuO2. The average Pt particle size determined by TEM was 5.3 nm. Cyclic voltammetry of Pt/(RuxSn1-xO2 indicated good conductivity of the sup-port and displayed usual features of Pt. The results of the electrochemical oxidation of COads and methanol on Pt/(RuxSn1-xO2 were compared with those on commercial Pt/C and PtRu/C catalysts. Oxidation of COads on Pt/(RuxSn1-xO2 starts at less positive potentials than on PtRu/C and Pt/C. Potentiodynamic polarization curves and chronoamperometric curves of methanol oxidation indicated higher initial activity of Pt/(RuxSn1-xO2 catalyst compared to PtRu/C, but also a greater loss in the current density over time. Potentiodynamic stability test of the catalysts revealed that deactivation of the Pt/(RuxSn1-xO2 and Pt/C was primarily caused by the poisoning of Pt surface by the methanol oxidation residues, which mostly occurred during the first potential cycle. In the case of PtRu/C the poisoning of the surface was minor and deactivation was caused by the PtRu surface area loss. [Projekat Ministarstva nauke Republike Srbije, br. ON-172054

  17. Identification of {sup 166}Pt and {sup 167}Pt

    Energy Technology Data Exchange (ETDEWEB)

    Bingham, C.R.; Toth, K.S.; Batchelder, J.C.; Blumenthal, D.J.; Brown, L.T.; Busse, B.C.; Conticchio, L.F.; Davids, C.N.; Davinson, T.; Henderson, D.J.; Irvine, R.J.; Seweryniak, D.; Walters, W.B.; Woods, P.J.; Zimmerman, B.E. [The University of Tennessee, Knoxville, Tennessee 37996 (United States)]|[Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States)]|[Louisiana State University, Baton Rouge, Louisiana 70803 (United States)]|[Argonne National Laboratory, Argonne, Illinois 60439 (United States)]|[Vanderbilt University, Nashville, Tennessee 37235 (United States)]|[Oregon State University, Corvallis, Oregon 97331 (United States)]|[University of Maryland, College Park, Maryland 20742 (United States)]|[Edinburgh University, Edinburgh, EH9 3JZ (United Kingdom)

    1996-07-01

    In a series of {sup 78}Kr bombardments of {sup 92}Mo the new isotopes {sup 166}Pt and {sup 167}Pt were identified via their {alpha}-decay properties. The {alpha}-decay energies and half-lives of these two nuclides are as follows. (1) {sup 166}Pt, {ital E}{sub {alpha}} = 7110(15) keV, {ital T}{sub 1/2} = 0.3(1) ms, and (2) {sup 167}Pt, {ital E}{sub {alpha}} = 6988(10) keV, {ital T}{sub 1/2} = 0.7(2) ms. Also, the half-life of {sup 168}Pt, which was previously unknown, was determined to be 2.0(4) ms. In a separate but concurrent experiment involving {sup 78}Kr + {sup 96}Ru reactions, {sup 170}Pt was made and a half-life of 14.7(5) ms was measured for it; the one published value is 6{sub {minus}2}{sup +5} ms. Results for {sup 162{minus}164}Os contained in the same data sets were also analyzed and by using mother-daughter correlations, the {alpha} branches of {sup 162,163,164}Os were established to be near 100{percent}. {copyright} {ital 1996 The American Physical Society.}

  18. Bioenergy from sisal residues

    Energy Technology Data Exchange (ETDEWEB)

    Jungersen, G. [Dansk Teknologisk Inst. (Denmark); Kivaisi, A.; Rubindamayugi, M. [Univ. of Dar es Salaam (Tanzania, United Republic of)

    1998-05-01

    The main objectives of this report are: To analyse the bioenergy potential of the Tanzanian agro-industries, with special emphasis on the Sisal industry, the largest producer of agro-industrial residues in Tanzania; and to upgrade the human capacity and research potential of the Applied Microbiology Unit at the University of Dar es Salaam, in order to ensure a scientific and technological support for future operation and implementation of biogas facilities and anaerobic water treatment systems. The experimental work on sisal residues contains the following issues: Optimal reactor set-up and performance; Pre-treatment methods for treatment of fibre fraction in order to increase the methane yield; Evaluation of the requirement for nutrient addition; Evaluation of the potential for bioethanol production from sisal bulbs. The processing of sisal leaves into dry fibres (decortication) has traditionally been done by the wet processing method, which consumes considerable quantities of water and produces large quantities of waste water. The Tanzania Sisal Authority (TSA) is now developing a dry decortication method, which consumes less water and produces a waste product with 12-15% TS, which is feasible for treatment in CSTR systems (Continously Stirred Tank Reactors). (EG)

  19. Pt/C Fuel Cell Catalyst Degradation

    DEFF Research Database (Denmark)

    Zana, Alessandro

    This thesis investigates the degradation behavior of Pt/C catalysts under simulated automotive conditions. By using the “tool box” synthesis method the Pt loading has been changed from low to high Pt loadings, therefore permitting to study the role of Pt on the degradation of high surface area (H...

  20. Pt/C Fuel Cell Catalyst Degradation

    DEFF Research Database (Denmark)

    Zana, Alessandro

    This thesis investigates the degradation behavior of Pt/C catalysts under simulated automotive conditions. By using the “tool box” synthesis method the Pt loading has been changed from low to high Pt loadings, therefore permitting to study the role of Pt on the degradation of high surface area (H...

  1. Study on the preparation of Pt nanocapsules

    Science.gov (United States)

    Zhang, Yi-fan; Ji, Zhen; Chen, Ke; Liu, Bo-wen; Jia, Cheng-chang; Yang, Shan-wu

    2017-01-01

    Ag@Pt core-shell nanoparticles (Ag@Pt NPs) were prepared by a co-reduction method. Pt nanocapsules with diameters of less than 10 nm were obtained by an electrochemical method. Cyclic voltammetry (CV) scanning was used to cavitate the Ag@Pt NPs, and the morphology, structure, and cavitation conditions were studied. The results indicate that the effective cavitation conditions to obtain Pt nanoparticles from Ag@Pt NPs are a scanning voltage of 0 to 0.8 V and continuous CV scanning over 2 h. This cavitation method is also applicable for the syntheses of Ir, Ru, and Ru-Pt nanocapsules.

  2. Evaluation of laboratory and industrial meat and bone meal combustion residue as cadmium immobilizing material for remediation of polluted aqueous solutions: 'Chemical and ecotoxicological studies'

    Energy Technology Data Exchange (ETDEWEB)

    Coutand, M., E-mail: marie.coutand@iut-tlse3.fr [Universite de Toulouse (France); UPS, INSA (France); LMDC - Laboratoire Materiaux et Durabilite des Constructions, 135, avenue de Rangueil, F-31 077 Toulouse Cedex 04 (France); Deydier, E., E-mail: eric.deydier@iut-tlse3.fr [Universite de Toulouse, Laboratoire de Chimie de Coordination du CNRS (UPR 8241), lie par convention a l' Universite Paul Sabatier - IUT A, Avenue Georges Pompidou, BP258, 81104 Castres (France); Cyr, M. [Universite de Toulouse (France); UPS, INSA (France); LMDC - Laboratoire Materiaux et Durabilite des Constructions, 135, avenue de Rangueil, F-31 077 Toulouse Cedex 04 (France); and others

    2009-07-30

    Meat and Bone Meals (MBM) combustion residues (ashes) are calcium and phosphate-rich materials. The aim of this work is to evaluate ashes efficiency for remediation of cadmium-contaminated aqueous solutions, and to assess the bioavailability of cadmium on Xenopuslaevis larvae. In this study both industrial (MBM-BA) and laboratory (MBM-LA) ashes are compared regarding their efficiency. Kinetic investigations reveal that cadmium ions are quickly immobilized, with a maximum cadmium uptake at 57 mg Cd{sup 2+}/g of ashes for MBM-LA, two times higher than metal uptake quantity of MBM-BA, in our experimental conditions. Chemical and X-ray diffraction analysis (XRD) reveal that Cd{sup 2+} is mainly immobilized as Ca{sub 10-x}Cd{sub x}(PO{sub 4}){sub 6}(OH){sub 2} by both ashes, whereas otavite, Cd(CO{sub 3}), is also involved for MBM-LA in cadmium uptake. Otavite formation could be explained by the presence of carbonates in MBM-LA, as observed by IR. Genotoxicity of cadmium solution on Xenopus larvae is observed at 0.02, 0.2 and 2 mg Cd{sup 2+}/L. However addition of only 0.1 g/L MBM-LA inhibits these effects for the above concentration values whereas Cd{sup 2+} bioaccumulation in larvae's liver is similar for both experiments, with and without ashes.

  3. Application of coal combustion residues to the stabilization/solidification of industrial wastes (IRIS); Desarrollo de un Proceso, a Escala Piloto de Inertizacion de Residuos Industriales con Cenizas Volantes

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-12-31

    Stabilization/solidification (S/S) processes, also called inertization processes, are a group of techniques which employ additives to reduce the mobility of the hazardous components from the waste and make possible for the residue to be accepted for its disposal in a safe way. These processes, mainly applied to wastes that contain heavy metals (such as lead, zinc, cadminum, mercury, copper, nickel, titanium, chromium-III, chromium-VI, arsenic,....) change the waste into a solid-like material in which the metals are trapped (nets and matrix) by physical or chemical links. The IRIS Project, carried out by AICIA through the ECSC Coal Programme with the participation of two industrial partners (Sevillana de Electricidad and EGMASA, a public-owned company for waste treatment), has developed, at pilot scale, a new S/S process for inorganic industrial wastes that uses great quantities of fly ash in the place of other more commonly used and expansive reagents. A pilot plant for 200 kg/h has been designed, built and operated. This facility has allowed to add improvements and scientific foundations to existing S/S technology. It has also allowed to obtain industrial scale parameters for fixed and portable plants. Experiencie have been mainly carried out using fly ash from high quality coals, but types of ash have been tested coming from coals with a greater calcium content, from fluidised bed combustion boilers and from desulphurisation processes, giving very suitable characteristics for their application to S/S processes. The addition of fly ash (up to 30%) in the IRIS process improves the results in comparison with the S/S processes that use only cement, because the final pH obtained (8-11) does not allow amphoteric metallic ions to escape in the leachate. The same as other S/S processes, IRIS can be applied also to wastes that contain certain metals (chromium-VI, arsenic, for example) with specific pre-treatments (redox, for example). The efficiency of the IRIS treatment

  4. Polybrominated dibenzo-p-dioxins/ dibenzofurans and polybrominated diphenyl ethers in soil, vegetation, workshop-floor dust, and electronic shredder residue from an electronic waste recycling facility and in soils from a chemical industrial complex in eastern China.

    Science.gov (United States)

    Ma, Jing; Addink, Rudolf; Yun, Sehun; Cheng, Jinping; Wang, Wenhua; Kannan, Kurunthachalam

    2009-10-01

    The formation and release of polybrominated dibenzo-p-dioxins and dibenzofurans (PBDD/Fs) from the incineration of electronic wastes (e-waste) that contain brominated flame retardants (BFRs) are a concern. However, studies on the determination of PBDD/Fs in environmental samples collected from e-waste recycling facilities are scarce. In this study, 11 2,3,7,8-substituted PBDD/Fs and 10 polybrominated diphenyl ether (PBDE) congeners were determined in electronic shredder waste, workshop-floor dust soil, and leaves (of plants on the grounds of the facility) from a large-scale e-waste recycling facility and in surface soil from a chemical-industrial complex (comprising a coke-oven plant, a coal-fired power plant, and a chlor-alkali plant) as well as agricultural areas in eastern China. Total PBDD/F concentrations in environmental samples were in the range of 113-818 pg/g dry wt (dw) for leaves, 392-18500 pg/g dw for electronic shredder residues, 716-800000 pg/g dw for soil samples, and 89600-pg/g dw for workshop-floor dust from the e-waste recycling facility and in a range from nondetect (ND) to 427 pg/g dw in soil from the chemical-industrial complex. The highest mean concentrations of total PBDD/Fs were found in soil samples and workshop-floor dust from the e-waste recycling facility. The dioxin-like toxic equivalent (measured as TEQ) concentrations of PBDD/Fs were greater than the TEQs of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) reported in our previous study for the same set of samples. The concentrations of PBDFs were several orders of magnitude higher than the concentrations of PBDDs in samples from the e-waste facility or from soil from the chemical-industrial complex. A significant correlation was found between the concentrations of sigmaPBDD/Fs and sigmaPBDEs (r = 0.769, p waste recycling facilities were higher than the intakes of TEQs contributed by PCDD/ Fs, calculated in our previous study.

  5. Pt···Pt vs Pt···S contacts between Pt-containing heterobimetallic lantern complexes.

    Science.gov (United States)

    Baddour, Frederick G; Fiedler, Stephanie R; Shores, Matthew P; Bacon, Jeffrey W; Golen, James A; Rheingold, Arnold L; Doerrer, Linda H

    2013-12-01

    A trio of Pt-based heterobimetallic lantern complexes of the form [(py)PtM(SAc)4(py)] (M = Co, 1; Ni, 2; Zn, 3) with unusual octahedral coordination of Pt(II) was prepared from a reaction of [PtM(SAc)4] with excess pyridine. These dipyridine lantern complexes could be converted to monopyridine derivatives with gentle heat to give the series [PtM(SAc)4(py)] (M = Co, 4; Ni, 5; Zn, 6). An additional family of the form [PtM(SAc)4(pyNH2)] (M = Co, 7; Ni, 8; Zn, 9) was synthesized from reaction of [PtM(SAc)4(OH2)] or [PtM(SAc)4] with 4-aminopyridine. Dimethylsulfoxide and N,N-dimethylformamide were also determined to react with [PtM(SAc)4] (M = Co, Ni), respectively, to give [PtCo(SAc)4(DMSO)](DMSO), 10, and [PtNi(SAc)4(DMF)](DMF), 11. Structural and magnetic data for these compounds and those for two other previously published families, [PtM(tba)4(OH2)] and [PtM(SAc)4(L)], L = OH2, pyNO2, are used to divide the structures among three distinct categories based on Pt···Pt and Pt···S distances. In general, the weaker donors H2O and pyNO2 seem to favor metallophilicity and antiferromagnetic coupling between 3d metal centers. When Pt···S interactions are favored over Pt···Pt ones, no coupling is observed and the pKa of the pyridine donor correlates with the interlantern S···S distance. UV-vis-NIR electronic and (1)H NMR spectra provide complementary characterization as well.

  6. Premature temporal theta (PT theta).

    Science.gov (United States)

    Hughes, J R; Fino, J J; Hart, L A

    1987-07-01

    A distinctive pattern called premature temporal theta (PT theta) was studied in 436 infants, ranging in age from 24 to 46 weeks. The pattern is seen in early prematurity, maximizes at 29-31 weeks and then diminishes and disappears near term. Usually the pattern is found independently on both temporal areas, but with a right-sided preference. Patients without PT theta or with a significantly low amount had either neurological or non-neurological (medical) conditions. With age there is a tendency for an increase in frequency and a decrease in amplitude. Five different peaks in the amount of this pattern are seen at approximately every month. Unilateral PT theta tends to be seen in older babies, more often on the right side and with an abnormal EEG. An abnormal EEG is usually associated with a delay in both the appearance and disappearance of this wave form. PT theta is also associated mainly with REM or active sleep. A polynomial rather than an exponential or power function best describes these data with changes of age. PT theta may arise from the inferior temporal gyrus and/or especially the transverse gyrus.

  7. Effect of Pt coverage in Pt-deposited Pd nanostructure electrodes on electrochemical properties

    Energy Technology Data Exchange (ETDEWEB)

    Park, Ah-Reum; Lee, Young-Woo; Kwak, Da-Hee; Park, Kyung-Won [Soongsil University, Seoul (Korea, Republic of)

    2015-06-15

    We have fabricated Pt-deposited Pd electrodes via a two-gun sputtering deposition system by separately operating Pd and Pt target as a function of sputtering time of Pt target. For Pt-deposited Pd electrodes (Pd/Pt-X), Pd were first deposited on the substrates at 20 W for 5min, followed by depositing Pt on the Pd-only electrodes as a function of sputtering time (X=1, 3, 5, 7, and 10min) at 20W on the Pt target. As the sputtering time of Pt target increased, the portion of Pt on the Pd electrodes increased, representing an increased coverage of Pt on the Pd electrodes. The Pd/Pt-7 electrode having an optimized Pt coverage exhibits an excellent electrocatalytic activity for methanol oxidation reaction.

  8. Electron transport in a Pt-CO-Pt nanocontact: Density functional theory calculations

    DEFF Research Database (Denmark)

    Strange, Mikkel; Thygesen, Kristian Sommer; Jacobsen, Karsten Wedel

    2006-01-01

    We have performed first-principles calculations for the mechanic and electric properties of pure Pt nanocontacts and a Pt contact with a single CO molecule adsorbed. For the pure Pt contacts we see a clear difference between point contacts and short chains in good agreement with experiments. We i...... of the transmission function for the Pt-CO-Pt contact, and show that the conductance is largely determined by the local d band at the Pt apex atoms....

  9. Electrodeposited CoPt and FePt alloys nanowires

    Energy Technology Data Exchange (ETDEWEB)

    Cagnon, L. [Laboratoire de Cristallographie, CNRS, BP 166, 38042 Grenoble cedex 9 (France)]. E-mail: laurent.cagnon@grenoble.cnrs.fr; Dahmane, Y. [Laboratoire Louis Neel, CNRS, BP 166, 38042 Grenoble cedex 9 (France); Laboratoire de Materiaux, Electrochimie et Corrosion, BP 17, 15000 Tizi-Ouzou (Algeria); Voiron, J. [Laboratoire Louis Neel, CNRS, BP 166, 38042 Grenoble cedex 9 (France); Pairis, S. [Laboratoire de Cristallographie, CNRS, BP 166, 38042 Grenoble cedex 9 (France); Bacia, M. [Laboratoire de Cristallographie, CNRS, BP 166, 38042 Grenoble cedex 9 (France); Ortega, L. [Laboratoire de Cristallographie, CNRS, BP 166, 38042 Grenoble cedex 9 (France); Benbrahim, N. [Laboratoire de Materiaux, Electrochimie et Corrosion, BP 17, 15000 Tizi-Ouzou (Algeria); Kadri, A. [Laboratoire de Materiaux, Electrochimie et Corrosion, BP 17, 15000 Tizi-Ouzou (Algeria)

    2007-03-15

    We have investigated CoPt and FePt alloys with the face centered tetragonal phase L10, which present very large magnetocrystalline anisotropy. Equiatomic CoPt nanowires exhibiting large coercive fields up to 1.1 T have been successfully prepared by electrodeposition into nanopores of commercial and home-made alumina membranes from a very simple electrolyte. The as-deposited material has the FCC structure with soft magnetic properties. An annealing treatment at 700 deg. C is crucial to transform this phase into the L1{sub 0} phase, which presents hard magnetic properties. Nanowires of annealed samples consist of small grains around 20 nm, with their c axes randomly distributed. The coercivity does not depend on the morphology and porosity of the two types of membranes but only on the deposited material elaborated with the appropriate thermal annealing process. Our preliminary results with FePt alloy indicate a more complicated system since the as-deposited material shows no magnetization. Magnetism appears only after annealing at 700-750 deg. C. Coercivity up to 0.85 T has been obtained at room temperature but with inhomogeneous phase composition. To achieve a single hard phase L1{sub 0}, it is essential to get for the as-deposited sample the equiatomic composition and then to employ the suitable annealing parameters (temperature and time) to change the whole FCC phase into the FCT ordered L1{sub 0} phase.

  10. Analysis of Business Process at PT XYZ by Using SCOR Thread Diagram

    Science.gov (United States)

    Sembiring, M. T.; Rambe, H. C.

    2017-03-01

    Supply Chain Operations Reference (SCOR) is a standard supply chain performance evaluation model which is proposed by Supply Chain Council (SCC). SCOR makes companies can analyse and evaluate their supply chain performance. SCOR has Thread Diagram which describes business process simply and systematically to help the analysis of company’s business process. This research takes place in PT XYZ that is involved in Crude Palm Oil (CPO) industry. PT XYZ used to be the market leader of CPO industry but nowadays they have a trouble to compete with new competitors. The purpose of this study is to provide the input for PT XYZ business process improvement to enhance the competitiveness of the company with the others. The result obtained shows that there are two performance metrics that are not reached. The analysis of business process shows the lack of control role of PT XYZ to supplier and customer side which is going to be the suggestion of improvement.

  11. Analisis Penilaian Kinerja Keuangan dengan Menggunakan Pendekatan Rasio (Studi Kasus Pada PT. Unilever Indonesia Tbk.

    Directory of Open Access Journals (Sweden)

    Sri Murwanti

    2012-06-01

    Full Text Available Tujuan penelitian ini adalah untuk mengetahui bagaimana penilaian kinerja keuangan PT. Unilever indonesia Tbk dilihat dari rasio keuanganya dan bagaimana penilaian kinerja keuangan PT. Unilever Indonesia Tbk bila dibandingkan antara rasio keuangan dengan rata-rata industri. Tehnik analisa yang digunakan dalam penelitian ini adalah Rasio Likuiditas(Current Ratio, Rasio Solvabilitas (Debt To Equity Ratio dan Leverage Ratio, Rasio Profitabilitas (Gross Profit Margin, Operating Profit Margin, Net Profit Margin, Return On Investment, Return On Equity dan Rasio Aktivitas (Inventory Turnover, Total Asset Turnover. Adapun laporan yang digunakan adalah laporan keuangan yang terdapat pada ICMD periode 2006 sampai dengan 2008. Berdasarkan penelitian yang dilakukan maka hasilnya dapat diketahui sebagai berikut, dilihat dari rasio keuangan secara keseluruhan (Rasio Likuiditas, Solvabilitas, Profitabilitas, Aktivitas penilaian kinerja keuangan PT. Unilever Indonesia Tbk masih kurang baik. Sedangkan dilihat dari perbandingan rasio keuangan dengan rata-rata industri kinerja keuangan PT. Unilever Indonesia Tbk dari tahun 2006-2008 dapat dikatakan baik

  12. A further insight into the biosorption mechanism of Pt(IV by infrared spectrometry

    Directory of Open Access Journals (Sweden)

    Xu Zhenling

    2009-07-01

    Full Text Available Abstract Background Platinum nanomaterial is one of the significant noble metal catalysts, and the interaction of platinum with microbe is one of the key factors in influencing the size and the distribution of the platinum nanoparticles on the microbial biomass. Some properties of Pt(IV adsorption and reduction by resting cells of Bacillus megatherium D01 biomass have once been investigated, still the mechanism active in the platinum biosorption remains to be seen and requires further elucidating. Result A further insight into the biosorption mechanism of Pt(IV onto resting cells of Bacillus megatherium D02 biomass on a molecular level has been obtained. The image of scanning electron microscopy (SEM of the D02 biomass challenged with Pt(IV displayed a clear distribution of bioreduced platinum particles with sizes of nanometer scale on the biomass. The state of Pt(IV bioreduced to elemental Pt(0 examined via X-ray photoelectron spectroscopy (XPS suggested that the biomass reduces the Pt(IV to Pt(II followed by a slower reduction to Pt(0. The analysis of glucose content in the hydrolysates of D02 biomass for different time intervals using ultraviolet-visible (UV-vis spectrophotometry indicated that certain reducing sugars occur in the hydrolyzed biomass and that the hydrolysis of polysaccharides of the biomass is a rapid process. The infrared (IR spectrometry on D02 biomass and that challenged with Pt(IV, and on glucose and that reacted with Pt(IV demonstrated that the interaction of the biomass with Pt(IV seems to be through oxygenous or nitrogenous chemical functional groups on the cell wall biopolymers; that the potential binding sites for Pt species include hydroxyl of saccharides, carboxylate anion and carboxyl of amino acid residues, peptide bond, etc.; and that the free monosaccharic group bearing hemiacetalic hydroxyl from the hydrolyzed biomass behaving as an electron donor, in situ reduces the Pt(IV to Pt(0. And moreover, the binding of

  13. Ab-initio study of the coadsorption of Li and H on Pt(001), Pt(110) and Pt(111) surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Saad, Farida [Laboratoire de Physique et Chimie Quantique, Faculte des Sciences, Universite Mouloud Mammeri, 15000 Tizi-Ouzou (Algeria); Zemirli, Mourad, E-mail: zemirlimourad@mail.ummto.dz [Laboratoire de Physique et Chimie Quantique, Faculte des Sciences, Universite Mouloud Mammeri, 15000 Tizi-Ouzou (Algeria); Benakki, Mouloud; Bouarab, Said [Laboratoire de Physique et Chimie Quantique, Faculte des Sciences, Universite Mouloud Mammeri, 15000 Tizi-Ouzou (Algeria)

    2012-02-15

    The coadsorption of Li and H atoms on Pt(001), Pt(110) and Pt(111) surfaces is studied using density functional theory with generalised gradient approximation. In all calculations Li, H and the two topmost layers of the metal were allowed to relax. At coverage of 0.25 mono-layer in a p(2 Multiplication-Sign 2) unit cell, lithium adsorption at the hollow site for the three surfaces is favoured over top and bridge sites. The most favoured adsorption sites for H atom on the Pt(001) and Pt(110) surfaces are the top and bridge sites, while on Pt(111) surface the fcc site appears to be slightly favoured over the hcp site. The coadsorption of Li and atomic hydrogen shows that the interaction between the two adsorbates is stabilising when they are far from each other. The analysis of Li, H and Pt local density of states shows that Li strongly interacts with the Pt surfaces.

  14. Caracterização dos óleos de algumas sementes de frutas como aproveitamento de resíduos industriais Characterization of some seed oils of fruits for utilization of industrial residues

    Directory of Open Access Journals (Sweden)

    Cíntia Nanci Kobori

    2005-10-01

    Full Text Available A finalidade deste estudo foi caracterizar os óleos extraídos das sementes de laranja, maracujá, tomate e goiaba, como aproveitamento de resíduos industriais. Os óleos foram extraídos das sementes em um extrator Soxhlet, utilizando como solvente o éter de petróleo e a caracterização dos mesmos foi realizada por meio de métodos analíticos padrões para óleos e gorduras (ácidos graxos livres, índices de peróxidos, refração, iodo, saponificação, matéria insaponificável e estabilidade oxidativa. As análises realizadas indicaram que esses óleos possuem características físico-químicas semelhantes a alguns óleos comestíveis, podendo ser uma nova fonte de óleos para o consumo humano.The purpose of this study was to characterize the extracted oils of the seeds of tomato, orange, passion fruit and guava with the objective of using industrial residues. The oils were extracted from the seeds with a Soxhlet extractor, using petroleum ether as solvent, and were characterized by standard methods for oil and fat analysis (free fatty acids, peroxide value, refractive index, iodine value, saponification value, unsaponifiable matter and oxidative stability. The analyses accomplished indicate that these oils possess similar physicochemical characteristics as some edible oils, them they can be a new source of oils for human consumption.

  15. Bimetallic Pt-Ni catalysts supported on usy zeolite for n-hexane isomerization

    OpenAIRE

    F. V. Barsi; Cardoso,D.

    2009-01-01

    Isomerization of linear alkanes has had considerable importance for the refining industry because the isomers formed in this reaction have high octane number. Most works reported in the literature studied the use of bifunctional catalysts, i.e., ones that have acid sites and metallic sites. In this study, bifunctional monometallic (Ni or Pt) and bimetallic catalysts (Pt-Ni), using HUSY zeolite as the support, were prepared in order to verify the role of the metal content and composition on th...

  16. PT-symmetric quantum theory

    Science.gov (United States)

    Bender, Carl M.

    2015-07-01

    The average quantum physicist on the street would say that a quantum-mechanical Hamiltonian must be Dirac Hermitian (invariant under combined matrix transposition and complex conjugation) in order to guarantee that the energy eigenvalues are real and that time evolution is unitary. However, the Hamiltonian H = p2 + ix3, which is obviously not Dirac Hermitian, has a positive real discrete spectrum and generates unitary time evolution, and thus it defines a fully consistent and physical quantum theory. Evidently, the axiom of Dirac Hermiticity is too restrictive. While H = p2 + ix3 is not Dirac Hermitian, it is PT symmetric; that is, invariant under combined parity P (space reflection) and time reversal T. The quantum mechanics defined by a PT-symmetric Hamiltonian is a complex generalization of ordinary quantum mechanics. When quantum mechanics is extended into the complex domain, new kinds of theories having strange and remarkable properties emerge. In the past few years, some of these properties have been verified in laboratory experiments. A particularly interesting PT-symmetric Hamiltonian is H = p2 - x4, which contains an upside-down potential. This potential is discussed in detail, and it is explained in intuitive as well as in rigorous terms why the energy levels of this potential are real, positive, and discrete. Applications of PT-symmetry in quantum field theory are also discussed.

  17. The stability and catalytic activity of W13@Pt42 core-shell structure

    Science.gov (United States)

    Huo, Jin-Rong; Wang, Xiao-Xu; Li, Lu; Cheng, Hai-Xia; Su, Yan-Jing; Qian, Ping

    2016-10-01

    This paper reports a study of the electronic properties, structural stability and catalytic activity of the W13@Pt42 core-shell structure using the First-principles calculations. The degree of corrosion of W13@Pt42 core-shell structure is simulated in acid solutions and through molecular absorption. The absorption energy of OH for this structure is lower than that for Pt55, which inhibits the poison effect of O containing intermediate. Furthermore we present the optimal path of oxygen reduction reaction catalyzed by W13@Pt42. Corresponding to the process of O molecular decomposition, the rate-limiting step of oxygen reduction reaction catalyzed by W13@Pt42 is 0.386 eV, which is lower than that for Pt55 of 0.5 eV. In addition by alloying with W, the core-shell structure reduces the consumption of Pt and enhances the catalytic efficiency, so W13@Pt42 has a promising perspective of industrial application.

  18. The stability and catalytic activity of W13@Pt42 core-shell structure

    Science.gov (United States)

    Huo, Jin-Rong; Wang, Xiao-Xu; Li, Lu; Cheng, Hai-Xia; Su, Yan-Jing; Qian, Ping

    2016-01-01

    This paper reports a study of the electronic properties, structural stability and catalytic activity of the W13@Pt42 core-shell structure using the First-principles calculations. The degree of corrosion of W13@Pt42 core-shell structure is simulated in acid solutions and through molecular absorption. The absorption energy of OH for this structure is lower than that for Pt55, which inhibits the poison effect of O containing intermediate. Furthermore we present the optimal path of oxygen reduction reaction catalyzed by W13@Pt42. Corresponding to the process of O molecular decomposition, the rate-limiting step of oxygen reduction reaction catalyzed by W13@Pt42 is 0.386 eV, which is lower than that for Pt55 of 0.5 eV. In addition by alloying with W, the core-shell structure reduces the consumption of Pt and enhances the catalytic efficiency, so W13@Pt42 has a promising perspective of industrial application. PMID:27759038

  19. The stability and catalytic activity of W13@Pt42 core-shell structure.

    Science.gov (United States)

    Huo, Jin-Rong; Wang, Xiao-Xu; Li, Lu; Cheng, Hai-Xia; Su, Yan-Jing; Qian, Ping

    2016-10-19

    This paper reports a study of the electronic properties, structural stability and catalytic activity of the W13@Pt42 core-shell structure using the First-principles calculations. The degree of corrosion of W13@Pt42 core-shell structure is simulated in acid solutions and through molecular absorption. The absorption energy of OH for this structure is lower than that for Pt55, which inhibits the poison effect of O containing intermediate. Furthermore we present the optimal path of oxygen reduction reaction catalyzed by W13@Pt42. Corresponding to the process of O molecular decomposition, the rate-limiting step of oxygen reduction reaction catalyzed by W13@Pt42 is 0.386 eV, which is lower than that for Pt55 of 0.5 eV. In addition by alloying with W, the core-shell structure reduces the consumption of Pt and enhances the catalytic efficiency, so W13@Pt42 has a promising perspective of industrial application.

  20. Oregon's forest products industry: 1976.

    Science.gov (United States)

    James O. Howard; Bruce A. Hiserote

    1976-01-01

    This report presents the findings of a 100-percent canvas of the primary forest products industry in Oregon for 1976. Tabular presentation includes characteristics of the industry log consumption and disposition of mill residues. Accompanying the tables is a descriptive analysis of conditions and trends in the industry.

  1. Information Technology (IT Improvement at PT Sumber Alfaria Trijaya

    Directory of Open Access Journals (Sweden)

    Marisa Karsen

    2013-05-01

    Full Text Available Retail industry is the second largest industry after agricultural industry in terms of employment absorption in Indonesia. The situation of the quite dynamic retail industry is marked by the development of modern retail trade and it impacts on traditional markets and suppliers. PT Sumber Alfaria Trijaya, known as Alfamart is one of the best retail company in Indonesia. It already uses Supply Chain Management and B2B to support their operations. Alfamart also has its own website which provides information about products, outlets, services, and promo. This research discusses about IT improvement. The purpose of this paper is to improve Alfamart IT performance and make innovation on the IT to increase customer satisfaction. The methodology used is defining the problem, measure, analyst problem, improvement required by Alfamart, and control to monitor the implementation. Problems are identified using SWOT analysis, problem clarification, and business model canvas. Analyzing the problems, solution hypotheses and IT improvement are recommended for Alfamart.

  2. Influência do tratamento térmico do resíduo sólido industrial (Grits na resistência mecânica de um latossolo para pavimentos de estradas florestais Influence of the thermal treatment of industrial solid residue (Grits on the mechanical resistance of a latosol for forest engineering roads

    Directory of Open Access Journals (Sweden)

    Carlos Cardoso Machado

    2003-08-01

    Full Text Available Em estudos que envolvem o tratamento de solos com aditivos químicos com fins rodoviários, merecem especial importância aquelas pesquisas orientadas no sentido de descobrir novos meios de torná-los mais econômicos e, ao mesmo tempo, mais resistentes. No presente trabalho, o resíduo sólido industrial Grits, oriundo do processo de fabricação de papel e celulose, foi aplicado a um latossolo denominado ETA, característico da microrregião de Viçosa, Minas Gerais, Brasil, com o intuito de melhorar suas características mecânicas para sua aplicação em pavimentos de estradas florestais. O Grits, após receber tratamento térmico a 200, 300, 400, 500 e 600 ºC, em mufla, foi misturado no teor de 10%, em peso, ao solo anteriormente citado. Parâmetros geotécnicos, característicos dos ensaios de compactação e resistência à compressão simples, foram utilizados para avaliar o efeito do tratamento térmico nas misturas solo+10% Grits. Os resultados indicaram que o Grits tem potencial para estabilização de solos de pavimentos de estradas florestais, sendo o melhor resultado alcançado para o Grits tratado a 600 ºC, pois houve ganhos de resistência mecânica.Road engineering studies involving chemical stabilization of soils deserve special recognition mainly those directed to lowering the costs of forest engineering roads. This work focuses on soil stabilization of a characteristic Latosol from Viçosa, Minas Gerais, Brazil, herein named ETA, using a residue from paper and cellulose industry production, herein called Grits. Grits content of 10% related to soil dry weight was used throughout the study after residue thermal treatment using a furnace at 200, 300, 400, 500 and 600 ºC. Geotechnical standard parameters from compaction and unconfined compression tests were used to evaluate the effect of thermal treatment on the mechanical response of soil-Grits mixtures. Unconfined compression testing data show that Grits is a promising soil

  3. Properties of CoPt ferromagnetic layers for application in spin light-emitting diodes

    Science.gov (United States)

    Zdoroveyshchev, A. V.; Dorokhin, M. V.; Vikhrova, O. V.; Demina, P. B.; Kudrin, A. V.; Temiryazev, A. G.; Temiryazeva, M. P.

    2016-11-01

    The magnetic properties of Co45Pt55 films deposited by electron-beam evaporation in vacuum have been studied. The measurements of the Faraday and Kerr magnetooptical effects confirm the presence of the easy-magnetization axis perpendicular to the Co45Pt55 surface. It is shown that the perpendicular magnetic anisotropy and the residual magnetization are retained at 300 K for a long time. The magnetic characteristics of the Co45Pt55 layer surface have been studied by magnetic force microscopy, and "circular" mobile magnetic structures have been detected. The spin light-emitting diodes based on In(Ga)As/GaAs heteronanostructures with Co45Pt55 contact layers were fabricated. These diodes emit circularly-polarized light in the absence of an external magnetic field.

  4. Results of the Proficiency Test, PT1 and PT2, 2012

    DEFF Research Database (Denmark)

    Vendramin, Niccolò; Nicolajsen, Nicole; Christophersen, Maj-Britt

    A comparative test of diagnostic procedures was provided by the European Union Reference Laboratory (EURL) for Fish Diseases. The test was divided into proficiency test 1 (PT1) and proficiency test 2 (PT2). The number of National Reference Laboratories (NRLs) participating in PT1 and PT2 was 43...

  5. Oxygen reduction activity of Pt and Pt-alloys in acid electrolyte

    Energy Technology Data Exchange (ETDEWEB)

    Paulus, Ursula A. [Paul Scherrer Inst., CH-5232 Villigen PSI (Switzerland); Schmidt, Thomas J.; Stamenkovic, Vojislav R.; Markovic, Nenad M.; Ross, Philip N. [Material Science Division, Lawrence Berkeley National Laboratory, University of California, Berkeley, CA 94720 (United States)

    2001-07-01

    The oxygen reduction reaction (ORR) has been studied on polycrystalline (pc) Pt, Pt{sub 3}Ni and Pt{sub 3}Co bulk alloy electrodes and on carbon supported Pt, PtNi and PtCo alloy catalysts. Base voltammetry measurements as well as complementary Auger Electron Spectroscopy (AES) and Low Energy Ion Scattering (LEIS) on bulk electrodes and High Resolution Transmission Electron Microscopy (HRTEM)-analysis on the supported catalysts allow an estimation of the surface composition. By using the rotating ring-disk electrode (RRDE) technique both the kinetic analysis of the ORR and in parallel the detection and quantification of the amount of peroxide produced during the ORR are possible. The activity for the ORR increases in the order Pt < Pt{sub 3}Ni < Pt{sub 3}Co for equally prepared bulk alloys and Pt < Pt{sub 3}Ni {approx} Pt{sub 3}CO < PtCo for the carbon supported catalysts, respectively. It was proposed that the mechanism for the ORR is the same on pure Pt and the PtNi and PtCo alloys. (author)

  6. Avaliação de resíduos de painéis de madeira gerados por indústrias moveleiras para aproveitamento na confecção de pequenos objetos: estudo de caso Evaluation of residues of wood boards generated by furniture industries for their utilization in the production of small objects: study of case

    Directory of Open Access Journals (Sweden)

    Luciana Barbosa de Abreu

    2009-01-01

    Full Text Available A indústria moveleira produz uma quantidade de resíduos que, normalmente, é descartada no meio ambiente ou utilizada como combustível em caldeiras e similares, ou apenas queimada. Alternativas para utilização desses resíduos têm sido alvo de pesquisas, destacando-se a confecção de pequenos objetos, na forma de artesanato. Neste trabalho, objetivou-se avaliar os resíduos de indústrias do pólo moveleiro de Ubá/MG. No levantamento quantitativo, constatou-se que as empresas geraram resíduos dos mesmos tipos de painéis de madeira. Os resíduos mais comuns foram de aglomerado e MDF (Medium Density Fiber. Observou-se grande variabilidade das dimensões desses resíduos, principalmente em sua largura. Concluiu-se que alguns resíduos não apresentaram dimensões adequadas para a confecção de determinados objetos e que se torna necessária uma seleção prévia desses resíduos para direcioná-los a trabalhos mais minuciosos, de forma a viabilizar a sua utilização.The furniture industry generates an amount of residues, which, normally, is discarded in the environment or destined to steam production in boilers. The handmade production of small wood board objects is an outstanding alternative to take advantage of these residues. The general aim of this study was to evaluate residues in furniture industries located at the pole of Ubá/MG. Through the survey and the analysis of the data, one established that the industries generate residues from the same kind of wood board. The most common residues were of particleboard and MDF (Medium Density Fiber. One observed a great diversity of residue dimensions, mainly in width. One concluded that some residues did not present adequate dimensions for the manufacturing of some objects and that there is a necessity of previous residues selection, in order to destine them to more detailed works and make possible their use.

  7. Hydrogen Adsorption on Pt, Rh and Pt-Rh Electrodes

    Institute of Scientific and Technical Information of China (English)

    贾梦秋; A.M.Meretskyi

    2005-01-01

    The hydrogen adsorption on Pt-Rh alloys in sulfuric acid aqueous solutions was studied by the method of cathode pulses. Hydrogen adsorption on the electrode with all ratio of alloy components (ωRh = 0-100%) is well described by the Temkin logarithmic isotherm. The surface coverage by adsorbed hydrogen at the same potential is decreased with increasing content of rhodium in the system. A linear dependence of adsorption peak potential on the alloy compositions in the case of weakly bonded adsorbed hydrogen is established. Hydrogen adsorption heat as a function of surface coverage for Pt-Rh-electrodes was obtained. The shape of the current-potential curve and position of the weakly bonded hydrogen adsorption on the potential scale are all related to alloy compositions, thus can serve as the basis for the determination surface composition of allovs.

  8. Synthesis, characterization and preliminary cytotoxicity assays of poly(ethylene glycol)-malonato-Pt-DACH conjugates.

    Science.gov (United States)

    Furin, Alessia; Guiotto, Andrea; Baccichetti, Franca; Pasut, Gianfranco; Deuschel, Christine; Bertani, Roberta; Veronese, Francesco M

    2003-01-01

    Oxalate 1,2-diaminocyclohexane platinum (oxaliplatin(R)), a successfully employed platinum compound belonging to the family of Pt-DACH complexes, has been conjugated to different molecular weight poly(ethylene glycols) (PEG) by means of peptide spacers and a malonic acid bidentate residue. Tri- and tetrapeptidic substrates of lysosomal enzymes were used in order to increase the release of Pt-DACH complex inside the cell following endocytosis and enzymatic degradation of the peptide spacer. Other aminoacids (e.g. norleucine) have been also employed. 1H-NMR of some conjugates was performed as characterisation of the product, while 195Pt-NMR analysis was carried out to detect the rearrangement of the platinum complex from the Pt(O,O) to the Pt(O,N) form. The compound PEG(5000)-Nle-malonato-Pt-DACH (4) has been tested against L1210-implanted mice and showed and appreciable increase in cytotoxicity as compared to the reference standard Cl(2)PtDACH.

  9. Surface termination of CePt5/Pt (111 ): The key to chemical inertness

    Science.gov (United States)

    Praetorius, C.; Zinner, M.; Held, G.; Fauth, K.

    2015-11-01

    The surface termination of CePt5/Pt (111 ) is determined experimentally by LEED-IV. In accordance with recent theoretical predictions, a dense Pt terminated surface is being found. Whereas the CePt5 volume lattice comprises Pt kagome layers, additional Pt atoms occupy the associated hole positions at the surface. This finding provides a natural explanation for the remarkable inertness of the CePt5 intermetallic. Implications of the structural relaxations determined by LEED-IV analysis are discussed with regard to observations by scanning tunneling microscopy and electron spectroscopies.

  10. Electron Induced Surface Reactions of cis-Pt(CO)2Cl2: A Route to Focused Electron Beam Induced Deposition of Pure Pt Nanostructures.

    Science.gov (United States)

    Spencer, Julie A; Wu, Yung-Chien; McElwee-White, Lisa; Fairbrother, D Howard

    2016-07-27

    Using mechanistic data from surface science studies on electron-induced reactions of organometallic precursors, cis-Pt(CO)2Cl2 (1) was designed specifically for use in focused electron beam induced deposition (FEBID) of Pt nanostructures. Electron induced decomposition of adsorbed 1 under ultrahigh vacuum (UHV) conditions proceeds through initial CO loss as determined by in situ X-ray photoelectron spectroscopy and mass spectrometry. Although the Pt-Cl bonds remain intact during the initial decomposition step, larger electron doses induce removal of the residual chloride through an electron-stimulated desorption process. FEBID structures created from cis-Pt(CO)2Cl2 under steady state deposition conditions in an Auger spectrometer were determined to be PtCl2, free of carbon and oxygen. Coupled with the electron stimulated removal of chlorine demonstrated in the UHV experiments, the Auger deposition data establish a route to FEBID of pure Pt. Results from this study demonstrate that structure-activity relationships can be used to design new precursors specifically for FEBID.

  11. Studies of surface processes of electrocatalytic reduction of CO2 on Pt(210), Pt(310) and Pt(510)

    Institute of Scientific and Technical Information of China (English)

    FAN; ChunJie; FAN; YouJun; ZHEN; ChunHua; ZHENG; QingWei; SUN; ShiGang

    2007-01-01

    Surface processes of CO2 reduction on Pt(210), Pt(310), and Pt(510) electrodes were studied by cyclic voltammetry. Different surface structures of these platinum single crystal electrodes were obtained by various treatment conditions. The experimental results illustrated that the electrocatalytic activity of Pt single crystal electrodes towards CO2 reduction is decreased in an order of Pt(210)>Pt(310)>Pt(510), i.e., with the decrease of (110) step density on well-defined surfaces. When the surfaces were reconstructed due to oxygen adsorption, the catalytic activity of all the three electrodes has been enhanced to a certain extent. Although the activity order remains unchanged, the electrocatalytic activity has been enhanced more significantly as the density of (110) step sites is more intensive on the Pt single crystal surface. It has revealed that the more open the surface structure is, the more active the Pt single crystal electrode will be, and the easier for the electrode to be transformed into a surface structure that exhibits higher activity under external inductions. However, the relatively ordered surfaces of Pt single crystal electrode are comparatively stable under the same external inductions. The present study has gained knowledge on the interaction between CO2 and Pt single crystal electrode surfaces at a microscopic level, and thrown new insight into understanding the surface processes of electrocatalytic reduction of CO2.

  12. Highly active Pt3Pb and core-shell Pt3Pb-Pt electrocatalysts for formic acid oxidation.

    Science.gov (United States)

    Kang, Yijin; Qi, Liang; Li, Meng; Diaz, Rosa E; Su, Dong; Adzic, Radoslav R; Stach, Eric; Li, Ju; Murray, Christopher B

    2012-03-27

    Formic acid is a promising chemical fuel for fuel cell applications. However, due to the dominance of the indirect reaction pathway and strong poisoning effects, the development of direct formic acid fuel cells has been impeded by the low activity of existing electrocatalysts at desirable operating voltage. We report the first synthesis of Pt(3)Pb nanocrystals through solution phase synthesis and show they are highly efficient formic acid oxidation electrocatalysts. The activity can be further improved by manipulating the Pt(3)Pb-Pt core-shell structure. Combined experimental and theoretical studies suggest that the high activity from Pt(3)Pb and the Pt-Pb core-shell nanocrystals results from the elimination of CO poisoning and decreased barriers for the dehydrogenation steps. Therefore, the Pt(3)Pb and Pt-Pb core-shell nanocrystals can improve the performance of direct formic acid fuel cells at desired operating voltage to enable their practical application. © 2012 American Chemical Society

  13. Caracterização da composição química e do rendimento dos resíduos industriais do limão Tahiti (Citrus latifolia Tanaka Chemical composition and Tahiti lime industrial residues output characterization

    Directory of Open Access Journals (Sweden)

    Luciana Maria Vieira Lopes Mendonça

    2006-12-01

    Full Text Available A indústria de sucos utiliza apenas de 40% a 50% dos frutos, sendo o restante considerado resíduo industrial. Estes resíduos apresentam-se ricos em alguns componentes como pectina, vitamina C e fibras dietárias que o tornam matéria-prima para a indústria alimentícia, farmacêutica e de rações. Visando o aproveitamento dos resíduos industriais do limão Tahiti para tais fins, caracterizou-se a composição centesimal, os teores de fibras, de pectina e de vitamina C presentes nas frações flavedo, albedo e bagaço do fruto. A partir da avaliação dos dados pelo teste de Scott Knott 5% de probabilidade, observou-se que os teores de cinzas, pectina, proteína, vitamina C e fibra bruta foram diferentes no flavedo, albedo e bagaço. O resíduo industrial do limão Tahiti tem um grande potencial para uso em formulação de rações para animais, dada a sua composição química, assim como poderá ser usado para a extração de fibras, pectina, vitamina C e óleos.The juice industry makes use of only 40 to 50% of the fruit and its remainder is considered industrial residue. This residue is very rich in some of its compounds such as pectin, ascorbic acid and dietary fibers making it into raw material for the food industry, pharmaceutics and animal food. With the purpose of using the industrial residue of Tahiti lime for such purposes, the centesimal composition, fiber contents, pectin and vitamin C contained in flavedo fractions, albedo and fruit pulp were characterized. From the evaluation for the Scott Knott's test to 5% of probability, it was observed that the ash content, pectin, protein, vitamin C and rude fiber were different for flavedo, albedo and pulp. Tahiti lime industrial residue has a great potential for animal food formulation, considering its chemical composition, as well as the fact that it can be used for fiber extraction, pectin, vitamin C and oils.

  14. PT Symmetry as a Generalization of Hermiticity

    CERN Document Server

    Wang, Qing-hai; Zhang, Jie-hong

    2010-01-01

    The Hilbert space in PT-symmetric quantum mechanics is formulated as a linear vector space with a dynamic weight function in the inner product. The most general PT-symmetric matrix Hamiltonians are constructed for 2*2 and 3*3 cases. In the former case, the PT-symmetric Hamiltonian represents the most general matrix Hamiltonian with a real spectrum. In both cases, the Hermitian matrix is shown to be a special case of PT-symmetric matrices. This finding confirms and strengthens the early belief that the PT-symmetric quantum mechanics is a generalization of the conventional Hermitian quantum mechanics.

  15. Marine Tar Residues: a Review.

    Science.gov (United States)

    Warnock, April M; Hagen, Scott C; Passeri, Davina L

    Marine tar residues originate from natural and anthropogenic oil releases into the ocean environment and are formed after liquid petroleum is transformed by weathering, sedimentation, and other processes. Tar balls, tar mats, and tar patties are common examples of marine tar residues and can range in size from millimeters in diameter (tar balls) to several meters in length and width (tar mats). These residues can remain in the ocean environment indefinitely, decomposing or becoming buried in the sea floor. However, in many cases, they are transported ashore via currents and waves where they pose a concern to coastal recreation activities, the seafood industry and may have negative effects on wildlife. This review summarizes the current state of knowledge on marine tar residue formation, transport, degradation, and distribution. Methods of detection and removal of marine tar residues and their possible ecological effects are discussed, in addition to topics of marine tar research that warrant further investigation. Emphasis is placed on benthic tar residues, with a focus on the remnants of the Deepwater Horizon oil spill in particular, which are still affecting the northern Gulf of Mexico shores years after the leaking submarine well was capped.

  16. Factors that predict residual tumors in re-TUR patients

    African Journals Online (AJOL)

    H. Türk

    2015-11-30

    Nov 30, 2015 ... a wide range in terms of recurrence, progression and survival rates. Stage pT1 tumors are usually high-grade ... Factors that predict residual tumors in re-TUR patients. 69. Table 1 .... Conflict of interest. No conflict of interest.

  17. Perpendicular magnetic anisotropy of Co85Cr15/Pt multilayers

    Institute of Scientific and Technical Information of China (English)

    Pol Hwang; Baohe Li; Tao Yang; Zhonghai Zhai; Fengwu Zhu

    2004-01-01

    The CoCr/Pt bilayers and (CoCr/Pt)20 multilayers with Pt underlayer were prepared by DC magnetron sputtering. The effects of prepared condition on perpendicular magnetic anisotropy were investigated. The results show that the thickness of Pt underlayer has a great effect on the microstructure and perpendicular magnetic anisotropy of CoCr/Pt bilayers and (CoCr/Pt)20 multilayers.When the thickness of Pt underlayer increases, Pt(111) and CoCr(002) peaks of both CoCr/Pt bilayers and (CoCr/Pt)20 multilayers increase and the bilayer periodicity of the multilayers is improved. The effective magnetic anisotropy of (CoCr/Pt)20 multilayers with Pt underlayer was much larger than that of CoCr/Pt bilayers. The (CoCr/Pt)20 multilayers has a stronger perpendicular magnetic anisotropy than that of CoCr/Pt bilayers. This is ascribed to the interface magnetic anisotropy of the multilayers.

  18. 40 CFR 266.112 - Regulation of residues.

    Science.gov (United States)

    2010-07-01

    ... (CONTINUED) STANDARDS FOR THE MANAGEMENT OF SPECIFIC HAZARDOUS WASTES AND SPECIFIC TYPES OF HAZARDOUS WASTE MANAGEMENT FACILITIES Hazardous Waste Burned in Boilers and Industrial Furnaces § 266.112 Regulation of residues. A residue derived from the burning or processing of hazardous waste in a boiler or industrial...

  19. Research Progress on Furfural Residues Recycling : A Literature Review

    NARCIS (Netherlands)

    Dai, Chun'ai; Liu, Bo; Girisuta, B.; Heeres, H.J.

    2010-01-01

    Millions of tons of furfural residues from the furfural industry are produced every year in China. Proper recycling of these residues is highly desirable as it may reduce associated environmental problems and increase the economic viability of the furfural industry. Research progress on furfural res

  20. PT AND PT/NI "NEEDLE" ELETROCATALYSTS ON CARBON NANOTUBES WITH HIGH ACTIVITY FOR THE ORR

    Energy Technology Data Exchange (ETDEWEB)

    Colon-Mercado, H.

    2011-11-10

    Platinum and platinum/nickel alloy electrocatalysts supported on graphitized (gCNT) or nitrogen doped carbon nanotubes (nCNT) are prepared and characterized. Pt deposition onto carbon nanotubes results in Pt 'needle' formations that are 3.5 nm in diameter and {approx}100 nm in length. Subsequent Ni deposition and heat treatment results in PtNi 'needles' with an increased diameter. All Pt and Pt/Ni materials were tested as electrocatalysts for the oxygen reduction reaction (ORR). The Pt and Pt/Ni catalysts showed excellent performance for the ORR, with the heat treated PtNi/gCNT (1.06 mA/cm{sup 2}) and PtNi/nCNT (0.664 mA/cm{sup 2}) showing the highest activity.

  1. Usulan Indikator Evaluasi Pemasok dalam Penetapan Bidder List: Studi Kasus Pengadaan Jasa PT. Semen Padang

    Directory of Open Access Journals (Sweden)

    Pri Gustari Akbar

    2016-04-01

    Full Text Available Each company will seek to improve performance in order to obtain the optimal results and customer satisfaction. One of the factors that affect the performance of the company is the supplier or vendor, which acts as a supplier of the operational needs of the company consisting of raw materials and spare parts manufacturing equipment. The existence of suppliers is crucial for the production process and the product to be produced. Therefore, it is necessary to a proper selection of suppliers so as to eliminate all risks that would result in losses for the company. PT. Semen Padang is one of the companies involved in the cement industry is one of the members of PT. Cement Indonesia as the Holding Company. Until now both PT. Semen Padang and PT. Cement Indonesia does not have yet a standard method in the selection of suppliers for the procurement process of goods and services. This study aims to design the proposed indicator in the evaluation of suppliers to determine the bidder's list on a tender for the procurement of services in PT. Semen Padang. Based on the literature study, it obtained six criteria i.e: quality, delivery, performance history, price, technical capability, and procedural compliance, which are divided into 13 indicators of performance evaluation. These indicators will be validated by the cement industry. Future studies will design a model of evaluation of suppliers using Analytic Hierarchy Process (AHP method to determine the bidder's list on a tender for the procurement of services in PT. Semen Padang.

  2. Impacts of Urban Economic Factors on Private Tutoring Industry

    Science.gov (United States)

    Kim, Kyung-Min; Park, Daekwon

    2012-01-01

    This paper investigates both supply (the number of employees in the PT industry and the number of PT institutions) and demand (the number of middle and high school students, grade 7-12). Panel data are used for this research, making it possible to analyze market growth over time since it contains both cross-sectional and time-series information.…

  3. Laser weldability of Pt and Ti alloys

    Energy Technology Data Exchange (ETDEWEB)

    Noolu, N.J. [Center for Advanced Materials Joining, University of Waterloo, Waterloo (Canada)]. E-mail: nnoolu@mecheng1.uwaterloo.ca; Kerr, H.W. [Center for Advanced Materials Joining, University of Waterloo, Waterloo (Canada); Zhou, Y. [Center for Advanced Materials Joining, University of Waterloo, Waterloo (Canada); Xie, J. [Cardiac Rhythm Management Division, Street Jude Medical Inc., Sylmar, CA (United States)

    2005-04-25

    Crack susceptibility of laser spot welds between Pt and Ti alloys was studied by characterizing the surface and the cross-sections of the welds produced at different pulse energies. Increase in laser pulse energy increased the dilution by the Ti alloy, giving rise to the evolution of microstructures with varying Ti contents across the entire fusion zone. Hardness results showed that regions with 66-75% Ti, i.e. consisting of primary Ti{sub 3}Pt and/or Ti{sub 3}Pt + TiPt eutectic, have a hardness higher than 700 Vickers hardness numbers (VHN), while regions with 42-66% Ti, i.e. consisting of primary TiPt, possessed hardness between 400 and 700 VHN. The extent of cracking increased with the increase in pulse energy and the cracked regions consisted of Ti contents between 50 and 75%. Brittle cracking in microstructures consisting of Ti{sub 3}Pt and TiPt phases suggested that one or both of the constituent phases are susceptible to cracking. However, crack arrest in microstructures predominantly consisting of TiPt showed that Ti{sub 3}Pt is the most susceptible phase to cracking in Pt-Ti alloy welds.

  4. Effect of Carbon Supported Pt Catalysts on Selective Hydrogenation of Cinnamaldehyde

    Directory of Open Access Journals (Sweden)

    Qing Han

    2016-01-01

    Full Text Available Selective hydrogenation of cinnamaldehyde (CAL to cinnamyl alcohol (COL is of both fundamental and industrial interest. It is of great significance to evaluate the possible differences between different supports arising from metal dispersion and electronic effects, in terms of activity and selectivity. Herein, Pt catalysts on different carbon supports including carbon nanotubes (CNTs and reduced graphene oxides (RGO were developed by a simple wet impregnation method. The resultant catalysts were well characterized by XRD, Raman, N2 physisorption, TEM, and XPS analysis. Applied in the hydrogenation of cinnamaldehyde, 3.5 wt% Pt/CNT shows much higher selectivity towards cinnamyl alcohol (62% than 3.5 wt% Pt/RGO@SiO2 (48%. The enhanced activity can be ascribed to the high graphitization degree of CNTs and high density of dispersed Pt electron cloud.

  5. Low Pt content direct methanol fuel cell anode catalyst: nanophase PtRuNiZr

    Science.gov (United States)

    Narayanan, Sekharipuram R. (Inventor); Whitacre, Jay F. (Inventor)

    2010-01-01

    A method for the preparation of a metallic material having catalytic activity that includes synthesizing a material composition comprising a metal content with a lower Pt content than a binary alloy containing Pt but that displays at least a comparable catalytic activity on a per mole Pt basis as the binary alloy containing Pt; and evaluating a representative sample of the material composition to ensure that the material composition displays a property of at least a comparable catalytic activity on a per mole Pt basis as a representative binary alloy containing Pt. Furthermore, metallic compositions are disclosed that possess substantial resistance to corrosive acids.

  6. Direct Determination of the Ionization Energies of PtC, PtO, and PtO2 with VUVRadiation

    Energy Technology Data Exchange (ETDEWEB)

    Citir, Murat; Metz, Ricardo B.; Belau, Leonid; Ahmed, Musahid

    2008-07-21

    Photoionization efficiency curves were measured for gas-phase PtC, PtO, and PtO2 using tunable vacuum ultraviolet (VUV) radiation at the Advanced Light Source. The molecules were prepared by laser ablation of a platinum tube, followed by reaction with CH4 or N2O and supersonic expansion. These measurements providethe first directly measured ionization energy for PtC, IE(PtC) = 9.45 +- 0.05 eV. The direct measurement also gives greatly improved ionization energies for the platinum oxides, IE(PtO) = 10.0 +- 0.1 eV and IE(PtO2) = 11.35 +- 0.05 eV. The ionization energy connects the dissociation energies of the neutral and cation, leading to greatly improved 0 K bond dissociation energies for the neutrals: D0(Pt-C) = 5.95 +- 0.07 eV, D0(Pt-O)= 4.30 +- 0.12 eV, and D0(OPt-O) = 4.41 +- 0.13 eV, as well as enthalpies of formation for the gas-phase molecules Delta H0 f,0(PtC(g)) = 701 +- 7 kJ/mol, Delta H0f,0(PtO(g)) = 396 +- 12 kJ/mol, and Delta H0f,0(PtO2(g)) = 218 +- 11 kJ/mol. Much of the error in previous Knudsen cell measurements of platinum oxide bond dissociation energies is due to the use of thermodynamic second law extrapolations. Third law values calculated using statistical mechanical thermodynamic functions are in much better agreement with values obtained from ionization energies and ion energetics. These experiments demonstrate that laser ablation production with direct VUV ionization measurements is a versatile tool to measure ionization energies and bond dissociation energies for catalytically interesting species such as metal oxides and carbides.

  7. Achieving Remarkable Activity and Durability toward Oxygen Reduction Reaction Based on Ultrathin Rh-Doped Pt Nanowires.

    Science.gov (United States)

    Huang, Hongwen; Li, Kan; Chen, Zhao; Luo, Laihao; Gu, Yuqian; Zhang, Dongyan; Ma, Chao; Si, Rui; Yang, Jinlong; Peng, Zhenmeng; Zeng, Jie

    2017-06-21

    The research of active and sustainable electrocatalysts toward oxygen reduction reaction (ORR) is of great importance for industrial application of fuel cells. Here, we report a remarkable ORR catalyst with both excellent mass activity and durability based on sub 2 nm thick Rh-doped Pt nanowires, which combine the merits of high utilization efficiency of Pt atoms, anisotropic one-dimensional nanostructure, and doping of Rh atoms. Compared with commercial Pt/C catalyst, the Rh-doped Pt nanowires/C catalyst shows a 7.8 and 5.4-fold enhancement in mass activity and specific activity, respectively. The combination of extended X-ray absorption fine structure analysis and density functional theory calculations reveals that the compressive strain and ligand effect in Rh-doped Pt nanowires optimize the adsorption energy of hydroxyl and in turn enhance the specific activity. Moreover, even after 10000 cycles of accelerated durability test in O2 condition, the Rh-doped Pt nanowires/C catalyst exhibits a drop of 9.2% in mass activity, against a big decrease of 72.3% for commercial Pt/C. The improved durability can be rationalized by the increased vacancy formation energy of Pt atoms for Rh-doped Pt nanowires.

  8. Comparative study of ethanol oxidation at Pt: Based nanoalloys and UPD modified Pt nanoparticles

    Directory of Open Access Journals (Sweden)

    Tripković Amalija V.

    2010-01-01

    Full Text Available The activity of two alloys, Pt3Sn/C and Pt3Ru2/C, was compared with the activity of Pt/C modified with corresponding amounts of SnUPD (≈25 % and RuUPD (≈40 % in oxidation of ethanol. Pt3Sn/C, Pt3Ru2/C and Pt/C catalysts were characterized by XRD. To establish the activity and stability of the catalysts, potentiodynamic, quasi steady-state and chronoamperometric measurements were performed. Both alloys are more active than SnUPD or RuUPD modified Pt/C catalysts. Electronic effect determining dominantly the activity of Pt3Sn/C is the main reason for its higher activity compared to Pt3Ru2/C. Since SnUPD and RuUPD do not provoke any significant modification of electronic environment, both modified Pt/C catalysts are less active than corresponding alloys. More pronounced difference in activity between Pt3Sn/C and SnUPD modified Pt/C than between Pt3Ru2/C and RuUPD modified Pt/C is caused by electronic effect in Pt3Sn/C. High activity of Pt3Sn/C modified with small amount of SnUPD (≈10% can be explained by combining the electronic effect, causing less strongly bonded adsorbate on Pt sites and easier mobility of SnUPD, with enhanced amount of oxygen-containing species on Sn sites resulting finally in reinforcement of bifunctional mechanism.

  9. Electrodeposited Pt and Pt-Sn nanoparticles on Ti as anodes for direct methanol fuel cells

    Institute of Scientific and Technical Information of China (English)

    Hanaa B HASSAN

    2009-01-01

    Electro-oxidation of methanol was studied on titanium supported nanocrystallite Pt and Ptx-Sny catalysts prepared by electrodeposition techniques. Their electro-catalytic activities were studied in 0.5mol/L H2SO4 and compared to those of a smooth Pt, Pt/Pt and Pt-Sn/Pt electrodes. Platinum was deposited on Ti by galvanostatic and potentiostatic techniques. X-ray diffractometer (XRD) and energy dispersive X-ray (EDX) techniques were applied in order to investigate the chemical composition and the phase structure of the modified electrodes. Scanning electron microscopy (SEM) was used to characterize the surface morphology and to correlate the results obtained from the two electrochemical deposition methods. Results show that modified Pt/Ti electrodes prepared by the two methods have comparable performance and enhanced catalytic activity towards methanol electro-oxidation compared to Pt/Pt and smooth Pt electrodes. Steady state Tafel plots experiments show a higher rate of methanol oxidation on a Pt/Ti catalyst than that on a smooth Pt. Introduction of a small amount of Sn deposited with Pt improves the catalytic activity and the stability of prepared electrode with time as indicated from the cyclic votlammetry and the chronoamperometric experiments. The effect of variations in the composition for binary catalysts of the type Ptx-Sny/Ti towards the methanol oxidation reaction is reported. Consequently, the Ptx-Sny/Ti (x∶y (8∶1), molar ratio) catalyst is a very promising one for methanol oxidation.

  10. Variáveis biométricas da cana-de-açúcar fertilizada com resíduos orgânico e industrial e irrigada com água servida e potável Biometric variable of sugar cane fertilized with organic and industrial residues irrigated with potable and wastewater

    Directory of Open Access Journals (Sweden)

    Fabio O. de Nobile

    2011-02-01

    Full Text Available O uso agrícola de resíduos orgânicos e industriais é uma alternativa de aproveitamento como fertilizante e fonte de matéria orgânica ao solo. Neste sentido, o objetivo deste trabalho foi avaliar o uso do composto de lixo e biofertilizante como fonte de nutrientes, e o resíduo do processamento da bauxita como corretivo da acidez do solo, para a cultura da cana-de-açúcar (cana-planta, irrigada com água potável e servida. Para tanto foi conduzido experimento em vaso, utilizando-se de solo Argissolo Vermelho-Amarelo distrófico, cultivado com a variedade RB855536. Foram avaliadas variáveis biométricas da planta, tais como: altura de plantas, diâmetro do colmo, perfilhamento, número de folhas, matéria seca de raiz e parte aérea. Os dados obtidos evidenciaram que a qualidade da água de irrigação, potável ou servida, não influenciou as variáveis avaliadas. A aplicação de composto de lixo e de biofertilizante constituiu-se numa fonte eficiente de nutrientes para as plantas de cana-de-açúcar, mas é necessária a aplicação adicional de fertilizantes para a obtenção de produção de colmos, similar ao do tratamento com adubação mineral convencional. Já o resíduo do processamento da bauxita mostrou-se eficiente na correção da acidez, apresentando as variáveis físicas semelhantes ao tratamento com adubação mineral, com exceção da matéria seca de raiz.The agricultural use of organic and industrial residues is an alternative of exploitation with fertilization and source of organic matter to the soil. In this direction, the objective of this research was to evaluate the use of the urban solid waste and biofertilizer as nutrient source, and residue of the bauxite processing as agricultural liming materials of the soil for sugar cane (cane plant and culture yields, irrigated with potable water and wastewater. For in such an experiment in vase was lead, under Alfisol soil, cultivated with the variety RB855536. It had

  11. Study of residual stresses in welded joints of dual phase HSLA steel used in automotive industry; Estudo das tensoes residuais em juntas soldadas de aco ARBL bifasico usado na industria automobilistica

    Energy Technology Data Exchange (ETDEWEB)

    Barbato, D.S.; Fonseca, M.P. Cindra; Marques Junior, A.S.; Chuvas, T.C.; Pardal, J.M., E-mail: mcindra@vm.uff.b [Universidade Federal Fluminense (PGMEC/UFF), Niteroi, RJ (Brazil). Programa de Pos-graduacao em Engenharia Mecanica; Berretta, J.R. [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil)

    2010-07-01

    One way of weight reduction in automotive vehicles is through the use of high strength and low alloy (HSLA) steels, which enables the use of small thickness plates. Whereas the appearance of residual stresses is intrinsic to the welding process, this study evaluates the residual stresses generated in welded joints obtained by TIG and LASER welding processes and comparing them. Residual stresses were measured by X-rays diffraction technique, using a portable device with Cr{kappa}{alpha} radiation applying the double exposure method. It also evaluates the influence of shot peening treatment applied after welding, in the bend tests conducted for both welding conditions and TIG welded joints showed higher stability of compressive stresses after welding. The metallographic analysis by optical microscopy complemented the welded joints characterization. (author)

  12. High-performance core-shell PdPt@Pt/C catalysts via decorating PdPt alloy cores with Pt

    Science.gov (United States)

    Wu, Yan-Ni; Liao, Shi-Jun; Liang, Zhen-Xing; Yang, Li-Jun; Wang, Rong-Fang

    A core-shell structured low-Pt catalyst, PdPt@Pt/C, with high performance towards both methanol anodic oxidation and oxygen cathodic reduction, as well as in a single hydrogen/air fuel cell, is prepared by a novel two-step colloidal approach. For the anodic oxidation of methanol, the catalyst shows three times higher activity than commercial Tanaka 50 wt% Pt/C catalyst; furthermore, the ratio of forward current I f to backward current I b is high up to 1.04, whereas for general platinum catalysts the ratio is only ca. 0.70, indicating that this PdPt@Pt/C catalyst has high activity towards methanol anodic oxidation and good tolerance to the intermediates of methanol oxidation. The catalyst is characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), and X-ray photoelectron spectroscopy (XPS). The core-shell structure of the catalyst is revealed by XRD and TEM, and is also supported by underpotential deposition of hydrogen (UPDH). The high performance of the PdPt@Pt/C catalyst may make it a promising and competitive low-Pt catalyst for hydrogen fueled polymer electrolyte membrane fuel cell (PEMFC) or direct methanol fuel cell (DMFC) applications.

  13. $\\mathcal{PT}$-symmetric mode-locking

    CERN Document Server

    Longhi, Stefano

    2016-01-01

    Parity-time ($\\mathcal{PT}$) symmetry is one of the most important accomplishments in optics over the past decade. Here the concept of $\\mathcal{PT}$ mode-locking of a laser is introduced, in which active phase locking of cavity axial modes is realized by asymmetric mode coupling in a complex time crystal. $\\mathcal{PT}$ mode-locking shows a transition from single to double pulse emission as the $\\mathcal{PT}$ symmetry breaking point is crossed. The transition can show a turbulent behavior, depending on a dimensionless modulation parameter that plays the same role as the Reynolds number in hydrodynamic flows.

  14. Remarks on the PT-pseudo-norm in PT-symmetric quantum mechanics

    Energy Technology Data Exchange (ETDEWEB)

    Duc Tai Trinh [Department of Mathematics, Teacher Training College of Dalat, 29 Yersin, Dalat (Viet Nam)]|[Abdus Salam International Centre for Theoretical Physics, Strada Costiera 11, Trieste 34014 (Italy)

    2005-04-22

    This paper presents an underlying analytical relationship between the PT-pseudo-norm associated with the PT-symmetric Hamiltonian H = p{sup 2} + V(q) and the Stokes multiplier of the differential equation corresponding to this Hamiltonian. We show that the sign alternation of the PT-pseudo-norm, which has been observed as a generic feature of the PT-inner product, is essentially controlled by the derivative of a Stokes multiplier with respect to the eigenparameter.

  15. Heterogeneous catalysts need not be so "heterogeneous": monodisperse Pt nanocrystals by combining shape-controlled synthesis and purification by colloidal recrystallization.

    Science.gov (United States)

    Kang, Yijin; Li, Meng; Cai, Yun; Cargnello, Matteo; Diaz, Rosa E; Gordon, Thomas R; Wieder, Noah L; Adzic, Radoslav R; Gorte, Raymond J; Stach, Eric A; Murray, Christopher B

    2013-02-20

    Well-defined surfaces of Pt have been extensively studied for various catalytic processes. However, industrial catalysts are mostly composed of fine particles (e.g., nanocrystals), due to the desire for a high surface to volume ratio. Therefore, it is very important to explore and understand the catalytic processes both at nanoscale and on extended surfaces. In this report, a general synthetic method is described to prepare Pt nanocrystals with various morphologies. The synthesized Pt nanocrystals are further purified by exploiting the "self-cleaning" effect which results from the "colloidal recrystallization" of Pt supercrystals. The resulting high-purity nanocrystals enable the direct comparison of the reactivity of the {111} and {100} facets for important catalytic reactions. With these high-purity Pt nanocrystals, we have made several observations: Pt octahedra show higher poisoning tolerance in the electrooxidation of formic acid than Pt cubes; the oxidation of CO on Pt nanocrystals is structure insensitive when the partial pressure ratio p(O2)/p(CO) is close to or less than 0.5, while it is structure sensitive in the O(2)-rich environment; Pt octahedra have a lower activation energy than Pt cubes when catalyzing the electron transfer reaction between hexacyanoferrate (III) and thiosulfate ions. Through electrocatalysis, gas-phase-catalysis of CO oxidation, and a liquid-phase-catalysis of electron transfer reaction, we demonstrate that high quality Pt nanocrystals which have {111} and {100} facets selectively expose are ideal model materials to study catalysis at nanoscale.

  16. Applications of bauxite residue: A mini-review.

    Science.gov (United States)

    Verma, Ajay S; Suri, Narendra M; Kant, Suman

    2017-09-01

    Bauxite residue is the waste generated during alumina production by Bayer's process. The amount of bauxite residue (40-50 wt%) generated depends on the quality of bauxite ore used for the processing. High alkalinity and high caustic content in bauxite residue causes environmental risk for fertile soil and ground water contamination. The caustic (NaOH) content in bauxite residue leads to human health risks, like dermal problems and irritation to eyes. Moreover, disposal of bauxite residue requires a large area; such problems can only be minimised by utilising bauxite residue effectively. For two decades, bauxite residue has been used as a binder in cement industries and filler/reinforcement for composite materials in the automobile industry. Valuable metals and oxides, like alumina (Al2O3), titanium oxide (TiO2) and iron oxide Fe2O3, were extracted from bauxite residue to reduce waste. Bauxite residue was utilised in construction and structure industries to make geopolymers. It was also used in the making of glass-ceramics and a coating material. Recently bauxite residue has been utilised to extract rare earth elements like scandium (Sc), yttrium (Y), lanthanum (La), cerium (Ce), neodymium (Nd) and dysprosium (Dy). In this review article, the mineralogical characteristics of bauxite residue are summarised and current progresses on utilisation of bauxite residue in different fields of science and engineering are presented in detail.

  17. Utilização de substrato composto por resíduos da agroindústria canavieira para produção de mudas de maracujazeiro-amarelo Use of substrate consisting of industrial sugarcane plant residues for production of yellow passion fruit seedlings

    Directory of Open Access Journals (Sweden)

    Luiz Augusto Lopes Serrano

    2006-12-01

    Full Text Available Um substrato composto por resíduos da agroindústria canavieira vem sendo utilizado com êxito para a produção de mudas de algumas espécies frutíferas e florestais. Assim, o objetivo deste trabalho foi avaliar o uso deste substrato comparando-o com outros recomendados para a produção de mudas de maracujazeiro-amarelo. Foram avaliados sete substratos: 1- Bagaço de cana + torta de filtro (3:2; v:v; 2- Bagaço de cana + torta de filtro (3:2; v:v + pulverização foliar semanal com NPK; 3- Bagaço de cana + torta de filtro (3:2; v:v + 7,3 kg m-3 de Osmocote® (14-14-14; 4- Plantmax®; 5- Plantmax® + pulverização foliar semanal com NPK; 6- Plantmax® + 7,3 kg m-3 Osmocote® (14-14-14, e 7- Areia + esterco bovino + vermiculita (1:1:1; v:v:v + NPK. De modo geral, as mudas cultivadas no substrato composto por resíduos da agroindústria canavieira e no substrato comercial, ambos fertilizados com adubo de liberação lenta, foram as que apresentaram melhor estado nutricional, comprovado pelos teores de nutrientes associados ao ótimo crescimento. Portanto, o substrato composto pela mistura bagaço de cana e torta de filtro (3:2; v:v fertilizado com 7,3 kg m-3 de Osmocote® (14-14-14 pode ser utilizado para a produção de mudas de maracujazeiro-amarelo.A substrate consisting of industrial sugarcane plant residues has been used with success to the production of some fruitful and forest species seedlings. Then, the objective of this research was to evaluate the use of that substrate, comparing it with other substrates recommended to the production of yellow passion fruit seedlings. It was evaluated seven substrates: 1- Sugarcane bagasse + industrial sugarcane plant residues (3:2; v:v; 2- Sugarcane bagasse + industrial sugarcane plant residues (3:2; v:v + NPK foliate spray weekly; 3- Sugarcane bagasse + industrial sugarcane plant residues (3:2; v:v + 7.3 kg m-3 of Osmocote® (14-14-14; 4- Plantmax®; 5- Plantmax® + NPK foliate spray weekly; 6

  18. Analisis Penggunaan Lean Manufacturing Untuk Meminimisasi Waste Pada PT. Bamindo Agrapersada

    OpenAIRE

    Sinaga, Antony

    2012-01-01

    PT. Bamindo Agrapersada adalah suatu industri yang bergerak di bidang pengolahan bambu. Produk yang dihasilkan adalah berbagai jenis kertas budaya cina atau dalam istilah kebudayaan cina disebut dengan uangdoa. Tahapan produksi yang dilalui dimulai dari chopping (pencacahan), extenuation (pelunakan/perendaman), mushing (pembuburan), rolling & drying (pembentukan lembaran kertas), printing (pencetakan kaligrafi), cutting (pemotongan), dan packing (pengepakan). Pemborosan yang adalah waktu menu...

  19. Analisis Sistem Pengukuran Kinerja dengan Metode Integrated Performance Measurement Systems (IPMS) Pada PT. PD. Paya Pinang

    OpenAIRE

    Alda, Tania

    2016-01-01

    Dalam era globalisasi saat ini, industri pengolahan kelapa sawit di Indonesia mengalami perkembangan yang cukup pesat. Pengukuran kinerja sangat penting bagi perusahaan, dapat membantu perusahaan untuk mengetahui tingkat performansi kerja yang baik. Saat ini, cara terbaik dalam mengukur kinerja adalah dengan mempertimbangkan stakeholder perusahaan dan mengidentifikasi kebutuhan stakeholder tersebut. PT. PD. Paya Pinang adalah salah satu perusahaan kelapa sawit swasta nasional yang melakukan p...

  20. Room-temperature formation of Pt$_3$Si/Pt$_2$Si films on poly-Si substrates

    CERN Document Server

    Dubkov, V P; Chizh, K V; Yuryev, V A

    2016-01-01

    We propose a way of formation of thin bilayer Pt$_3$Si/Pt$_2$Si films at room temperature on poly-Si substrates by Pt magnetron sputtering and wet etching, obtain such film, investigate its structure and phase composition and estimate the thickness of its layers. We verify by direct x-ray photoelectron-spectroscopic measurements our previous observation of the Pt$_2$Si layer formaton between Pt and poly-Si films as a result of Pt magnetron sputtering at room temperature. This layer likely appears due to high enough temperature of Pt ions in the magnetron plasma sufficient for chemical reaction of the silicide film formation on the Si surface. The Pt$_3$Si layer likely forms from the Pt--Pt$_3$Si layer (Pt$_{95}$Si$_5$), which arises under Pt film during the magnetron sputtering, as a result of Pt removal by wet etching.

  1. A comparative study of Pt and Pt-Pd core-shell nanocatalysts

    Energy Technology Data Exchange (ETDEWEB)

    Long, Nguyen Viet, E-mail: nguyenviet_long@yahoo.com [Department of Materials Science and Engineering, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya 466-8555 (Japan); Posts and Telecommunications Institute of Technology, km 10 Nguyen Trai, Thanh Xuan, Ha Dong, Hanoi (Viet Nam); Laboratory for Nanotechnology, Vietnam National University, Ho Chi Minh, Linh Trung, Thu Duc, Ho Chi Minh (Viet Nam); Department of Molecular and Material Sciences, Interdisciplinary Graduate School of Engineering Sciences, Kyushu University, 6-1 Kasugakouen, Kasuga, Fukuoka 816-8580 (Japan); Ohtaki, Michitaka [Department of Molecular and Material Sciences, Interdisciplinary Graduate School of Engineering Sciences, Kyushu University, 6-1 Kasugakouen, Kasuga, Fukuoka 816-8580 (Japan); Hien, Tong Duy [Laboratory for Nanotechnology, Vietnam National University, Ho Chi Minh, Linh Trung, Thu Duc, Ho Chi Minh (Viet Nam); Randy, Jalem [Department of Materials Science and Engineering, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya 466-8555 (Japan); Nogami, Masayuki, E-mail: nogami@nitech.ac.jp [Department of Materials Science and Engineering, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya 466-8555 (Japan)

    2011-10-30

    Highlights: > The syntheses of Pt (4-8 nm) and Pt-Pd core-shell nanoparticles (15-25 nm) are showed. > Pt-Pd core-shell catalysts possess catalytic property much better than Pt catalysts. > Pt-Pd core-shell catalysts exhibit fast and highly stable catalytic activity. > Fascinatingly, size effect is not as really important as nanostructuring effect. > Fast, stable, sensitive hydrogen adsorption is very crucial for fuel cells. - Abstract: This comparative study characterizes two types of metallic and core-shell bimetallic nanoparticles prepared with our modified polyol method. These nanoparticles consist of Pt and Pt-Pd core-shell nanocatalysts exhibiting polyhedral morphologies. The controlled syntheses of Pt metallic nanoparticles in the 10-nm regime (4-8 nm) and Pt-Pd bimetallic core-shell nanoparticles in the 30-nm regime (15-25 nm) are presented. To realize our ultimate research goals for proton exchange membrane fuel cells (PEMFCs) and direct methanol fuel cells (DMFCs), we thoroughly investigate the dependence of the electrocatalytic properties of the nanoparticles on the structure, size and morphology. Significant differences in the electrocatalysis are also explained in experimental evidences of both Pt and Pt-Pd nanocatalysts. We suggested that the core-shell controlled morphologies and nanostructures of the Pd nanoshell as the Pd atomic monolayers will not only play an important role in producing inexpensive, novel Pt- and Pd-based nanocatalysts but also in designing more efficient Pt- and Pd-based nanocatalysts for practical use in DMFC technology. Our comparative results show that Pt-Pd nanocatalysts with Pd nanoshells exhibited much better electrocatalytic activity and stabilization compared to Pt nanocatalysts. Interestingly, we found that the size effect is not as strong as the nanostructuring effect on the catalytic properties of the researched nanoparticles. A nanostructure effect of the core-shell bimetallic nanoparticles was identified.

  2. AN ANIMAL MODEL OF PLATINUM (PT) HYPERSENSITIVITY

    Science.gov (United States)

    Exposure to Pt salts has been associated with occupational asthma. Pt, the most active component and widely used metal in catalytic converters, is released in automobile exhaust and is a proposed diesel fuel additive. Thus, with the potential for widespread environmental distrib...

  3. Evaluasi Shift Kerja dan Penentuan Waktu Standar PT X Berdasarkan Beban Kerja

    Directory of Open Access Journals (Sweden)

    Trisna Mesra

    2016-04-01

    Full Text Available PT. X is one of the companies located in Dumai Industrial Region, produces fertilizer. This company has three production plants. The production capacity of the first plant is 450 tons/day, the second plant produces 750 tons/day and the third plant produces 700 tons/day.  PT. X is supported by 2 sub companies, they are PT. A and PT. B. PT. A operates 5 bagging lines and PT. B operates 3 bagging lines. The fertilizer bagging process has three steps where each step has its own work station: putting the labeled sack to the hook followed by filling the sack with fertilizer, installing the tie cable, and sewing the fertilizer filled sack. From the initial survey, it was found that the processing time is not optimal to reach production target. PT. A and B have to set 24 working hours per day to run the target resulting on frequent over time, excessive fatigue and the negative impact of physically and mentally for the workers. Author’s hypothesis is the current condition has been one of the reasons for a decline of the production output. Therefore, the purposes of the research are to find the impact of current working hours and shift work pattern on the physical and psychological response of the workers and to calculate the standard time required to complete one cycle of bagging process. This standard time is very crucial to determine production target thus determine the optimal working hours and shift rotation. Measuring of heart rate are collecting results of a questionnaire of NASA-TLX are the parameters used to evaluate the physical and psychological response of workers. Two workers from different group worker, different shift work, from PT. A and PT. B were selected as samples to evaluate their heart rate pattern. The questioner spread out to all workers. Time standard was determined by observing and taking data of   40 bagging cycles for each shift work. The results show that shift work affecting the physiological response of workers in PT. B

  4. Metrology with PT-Symmetric Cavities: Enhanced Sensitivity near the PT-Phase Transition.

    Science.gov (United States)

    Liu, Zhong-Peng; Zhang, Jing; Özdemir, Şahin Kaya; Peng, Bo; Jing, Hui; Lü, Xin-You; Li, Chun-Wen; Yang, Lan; Nori, Franco; Liu, Yu-Xi

    2016-09-09

    We propose and analyze a new approach based on parity-time (PT) symmetric microcavities with balanced gain and loss to enhance the performance of cavity-assisted metrology. We identify the conditions under which PT-symmetric microcavities allow us to improve sensitivity beyond what is achievable in loss-only systems. We discuss the application of PT-symmetric microcavities to the detection of mechanical motion, and show that the sensitivity is significantly enhanced near the transition point from unbroken- to broken-PT regimes. Our results open a new direction for PT-symmetric physical systems and it may find use in ultrahigh precision metrology and sensing.

  5. Characterization of Iron Grains near the P/T Boundary in the Meishan Section of China

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    The Meishan section of China has been confirmed as the "Global Stratotype Section and Point" of the P/T boundary. In the section, the authors found several types of iron grains, including pyrite, pure iron grains and goethite. From the research of macro minerals, it is easy to find that the grains rich in iron appear from the bottom of the event layer of the section. In other words, it is probably residue of the geochemical catastrophe of that time. Therefore, it is important to trace the source of these iron grains and their relationships, which probably provides evidence for volcanic eruption or impact-volcanoes and has directive significance to the crisis during the P/T transitional period. Through the study of the characterization and relationships of these iron grains, the authors make a preliminary discussion on the P/T mass extinction.

  6. The robust PT-symmetric chain

    CERN Document Server

    Joglekar, Yogesh N

    2010-01-01

    We study the properties of a parity- and time-reversal- (PT) symmetric tight-binding chain of size N with position-dependent hopping amplitude. In contrast to the fragile PT-symmetric phase of a chain with constant hopping and imaginary impurity potentials, we show that, under very general conditions, our model is {\\it always} in the PT-symmetric phase. We numerically obtain the energy spectrum and the density of states of such a chain, and show that they are widely tunable. By studying the size-dependence of inverse participation ratios, we show that although the chain is not translationally invariant, most of its eigenstates are extended. Our results indicate that tight-binding models with non-Hermitian PT-symmetric hopping have a robust PT-symmetric phase and rich dynamics.

  7. 75 FR 63060 - Airworthiness Directives; PIAGGIO AERO INDUSTRIES S.p.A. Model PIAGGIO P-180 Airplanes

    Science.gov (United States)

    2010-10-14

    ... INDUSTRIES S.p.A. Model PIAGGIO P-180 Airplanes AGENCY: Federal Aviation Administration (FAA), Department of..., installed on Pratt & Whitney Canada (P&WC) PT6A66 and PT6A66B engines, were detected on P.180 aeroplanes... & Whitney Canada (P&WC) PT6A66 and PT6A66B engines, were detected on P.180 aeroplanes; such failures, due...

  8. PENGARUH KUALITAS PELAYANAN DENGAN KEPUASAN KONSUMEN PADA PT. PUSRI PALEMBANG PPD LAMPUNG

    Directory of Open Access Journals (Sweden)

    Yudiana Sari

    2017-04-01

    Full Text Available Abstract-The research object of this research is PT. PUSRI PPD Lampung Palembang. PT Pusri arranged subsidized fertilizer marketing services in specific areas (rayonisasi and the Minister of Industry Decree 356 / MPP / Kep / 5/2004 for the smooth distribution of subsidized fertilizers which are the responsibility of manufacturers, authorized distributors and authorized retailers. The problem under study is to analyze the effect of service quality on customer satisfaction at PT. PUSRI Lampung Palembang PPD due to sales of PT. PUSRI PPD Lampung Palembang. The method used in this research is the research literature and field research conducted by examining directly on PT. PUSRI PPD Lampung Palembang. The results showed that the calculation formula product moment correlation that is equal to 0.804 with n = 55. The number is located on the interval coefficient of 0.75 to 1, which means the relationship between service quality and customer satisfaction in the volume of sales at PT. PUSRI Lampung Palembang PPD is very strong.

  9. Wireless Hydrogen Smart Sensor Based on Pt/Graphene-Immobilized Radio-Frequency Identification Tag.

    Science.gov (United States)

    Lee, Jun Seop; Oh, Jungkyun; Jun, Jaemoon; Jang, Jyongsik

    2015-08-25

    Hydrogen, a clean-burning fuel, is of key importance to various industrial applications, including fuel cells and the aerospace and automotive industries. However, hydrogen gas is odorless, colorless, and highly flammable; thus, appropriate safety protocol implementation and monitoring are essential. Highly sensitive hydrogen-gas leak detection and surveillance systems are needed; additionally, the ability to monitor large areas (e.g., cities) via wireless networks is becoming increasingly important. In this report, we introduce a radio frequency identification (RFID)-based wireless smart-sensor system, composed of a Pt-decorated reduced graphene oxide (Pt_rGO)-immobilized RFID sensor tag and an RFID-reader antenna-connected network analyzer to detect hydrogen gas. The Pt_rGOs, produced using a simple chemical reduction process, were immobilized on an antenna pattern in the sensor tag through spin coating. The resulting Pt_rGO-based RFID sensor tag exhibited a high sensitivity to hydrogen gas at unprecedentedly low concentrations (1 ppm), with wireless communication between the sensor tag and RFID-reader antenna. The wireless sensor tag demonstrated flexibility and a long lifetime due to the strong immobilization of Pt_rGOs on the substrate and battery-independent operation during hydrogen sensing, respectively.

  10. Electrochemical study of the Pt and Pt-Ni upon multiwalled carbon nanotubes

    Science.gov (United States)

    Mohammed, Norani Muti; Mumtaz, Asad; Ansari, Muhammad Shahid; Ahmad, Riaz

    2016-11-01

    Direct methanol fuel cells have attracted great interest in the recent development of portable devices. New routes are being developed for synthesizing the catalysts used in the methanol oxidation. In this work, the electrochemical behavior of the Pt and Pt-Ni upon multiwalled carbon nanotubes, synthesized via a new modified route, has been studied. The results showed that Pt-Ni 10% has the comparable current density to the Pt 20%-loading which is nearly 3 times greater than 10% Pt loading. The transfer of the polarization curve of Pt-Ni 10% towards lower polarization region following the catalyst with 20% Pt loading indicates the higher activity of the nano-electro-catalysts in the alkaline media. Also the long term efficiency and activity of the Pt-Ni with 10% loading is nearly reaching the 20% Pt-loading which is almost 10 folds greater than the 10% Pt loading. The study revealed that Ni in Pt-based nanoalloy impart not only an enhanced activity but also better durability of catalyst in direct methanol fuel cell applications.

  11. Industrial diamond

    Science.gov (United States)

    Olson, D.W.

    2001-01-01

    An overview of the industrial diamond industry is provided. More than 90 percent of the industrial diamond consumed in the U.S. and the rest of the world is manufactured diamond. Ireland, Japan, Russia, and the U.S. produce 75 percent of the global industrial diamond output. In 2000, the U.S. was the largest market for industrial diamond. Industrial diamond applications, prices for industrial diamonds, imports and exports of industrial diamonds, the National Defense Stockpile of industrial diamonds, and the outlook for the industrial diamond market are discussed.

  12. Magnetic moments in chemically ordered mass-selected CoPt and FePt clusters

    Energy Technology Data Exchange (ETDEWEB)

    Dupuis, V., E-mail: Veronique.Dupuis@univ-lyon1.fr [Institut Lumière Matière, UMR5306 Université Lyon 1-CNRS, Université de Lyon, 69622 Villeurbanne cedex (France); Khadra, G.; Linas, S.; Hillion, A. [Institut Lumière Matière, UMR5306 Université Lyon 1-CNRS, Université de Lyon, 69622 Villeurbanne cedex (France); Gragnaniello, L. [Institute of Condensed Matter Physics, EPFL, CH-1015 Lausanne (Switzerland); Tamion, A.; Tuaillon-Combes, J.; Bardotti, L.; Tournus, F. [Institut Lumière Matière, UMR5306 Université Lyon 1-CNRS, Université de Lyon, 69622 Villeurbanne cedex (France); Otero, E.; Ohresser, P. [Synchrotron SOLEIL, L’Orme des Merisiers, Saint-Aubin BP 48, F-91192 Gif-sur-Yvette Cedex (France); Rogalev, A.; Wilhelm, F. [European Synchrotron Radiation Facility, BP 220, F-38043 Grenoble Cedex (France)

    2015-06-01

    By combining high photon flux and chemical selectivity, X-ray absorption spectroscopy and X-ray magnetic circular dichroism (XMCD) have been used to study the magnetism of CoPt and FePt clusters before and after their transition to the chemically ordered L1{sub 0}-like phase. Compared to the bulk, we find larger magnetic spin and orbital moments of Fe, Co and Pt atoms in nanoalloys. - Highlights: • Study of magnetism on well-defined CoPt and FePt clusters embedded in carbon matrix • X-ray magnetic circular dichroism (XMCD) at each specific Fe, Co and Pt edges, before and after annealing to induce transition to the chemically L1{sub 0}-like phase. • Quantitative values of the spin and orbital magnetic moments of Co (resp. Fe) and Pt after the chemical ordering transition. • Specific nanoalloy effects.

  13. ELECTROCHEMICAL OXIDATION OF ETHYLENE AT PANI/Pt AND Ag/PANI/Pt MODIFIED ELECTRODES

    Directory of Open Access Journals (Sweden)

    Lenys Fernández

    Full Text Available The electrochemical behavior of ethylene on PANI/Pt and Ag/PANI/Pt modified electrodes was investigated in different media. Morphology of the deposits of PANI were observed by SEM analysis, complemented by the EDX techniques to obtain the Ag composition that shows that Ag is deposited in the polymeric matrix which covered the whole platinum surface. The electrodic system comprising Ag/PANI/ Pt electrode exhibited a more important electrocatalytic response for ethylene oxidation in neutral solutions than the PAN/Pt and Pt electrodes at 20 ºC.The results suggest that the oxidation of ethylene on Ag/PANI/Pt electrode is limited by adsorption-controlled reaction while the oxidation at PANI/Pt is mass transport-limited.

  14. Tafsir Kritis Privatisasi Berdasarkan Hermeneutika Gadamerian: Kasus Privatisasi PT Telkom dan PT Indosat

    Directory of Open Access Journals (Sweden)

    Ayudia Sokarina

    2011-08-01

    Full Text Available Privatization Under Critical Meaning by Using Gadamerian Hermeneutics: The Case for Privatization of PT. Telkom And PT. Indosat. The objectives of the study are to search critical meanings of privatisation in PT Telkom and PT Indosat. This research is using an interpretive approach and critical analysis by using Gadamerian hermeneutics. The study finds that there is other reality which shows that the Government views privatisation as a tool to achieve economic rents. Privatisation has failed to enable the distribution of ownership. At the same time, there is exploitation of consumers in the form of higher rates (as in the case of PT Telkomsel. As a result of privatisation of PT Telkom and PT Indosat has failed to provide justice and prosperity for the people and state.

  15. Platinum(0-1,3-divinyl-1,1,3,3-tetramethyldisiloxane Complex as a Pt Source for Pt/SnO2 Catalyst

    Directory of Open Access Journals (Sweden)

    Agnieszka Martyla

    2014-01-01

    Full Text Available This paper presents new preparation method of Pt/SnO2, an important catalytic system. Besides of its application as a heterogenic industrial catalyst, it is also used as a catalyst in electrochemical processes, especially in fuel cells. Platinum is commonly used as an anode catalyst in low temperature fuel cells, fuelled with alcohols of low molecular weight such as methanol. Platinum(0-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex was used as a precursor of metallic phase. The aim of the research was to obtain a highly active in electrochemical system Pt/SnO2 catalyst with low metal load. Considering small size of Pt crystallites, it should result in high activity of Pt/SnO2 system. The presented method of SnO2 synthesis allows for obtaining support consisting of nanoparticles. The effect of the thermal treatment on activity of Pt/SnO2 gel was demonstrated. The system properties were investigated using TEM, FTIR (ATR, and XRD techniques to describe its thermal structural evolution. The results showed two electrocatalytical activity peaks for drying at a temperature of 430 K and above 650 K.

  16. Reduction of Pt2+ species in model Pt-CeO2 fuel cell catalysts upon reaction with methanol

    Science.gov (United States)

    Neitzel, Armin; Johánek, Viktor; Lykhach, Yaroslava; Skála, Tomáš; Tsud, Nataliya; Vorokhta, Mykhailo; Matolín, Vladimír; Libuda, Jörg

    2016-11-01

    The stability of atomically dispersed Pt2+ species on the surface of nanostructured CeO2 films during the reaction with methanol has been investigated by means of synchrotron radiation photoelectron spectroscopy and resonant photoemission spectroscopy. The isolated Pt2+ species were prepared at low Pt concentration in Pt-CeO2 film. Additionally, Pt2+ species coexisting with metallic Pt particles were prepared at high Pt concentration. We found that adsorption of methanol yields similar decomposition products regardless of Pt concentration in Pt-CeO2 films. A small number of oxygen vacancies formed during the methanol decomposition can be replenished in the Pt-CeO2 film with low Pt concentration by diffusion of oxygen from the bulk. In the presence of supported Pt particles, a higher number of oxygen vacancies leads to a partial reduction of the Pt2+ species. The isolated Pt2+ species are reduced under rather strongly reducing conditions only, i.e. during annealing under continuous exposure to methanol. Reduction of isolated Pt2+ species results in the formation of ultra-small Pt particles containing around 25 atoms per particle or less. Such ultra-small Pt particles demonstrate excellent stability against sintering during annealing of Pt-CeO2 film with low Pt concentration under reducing conditions.

  17. Pt/MOx/SiO2, Pt/MOx/TiO2, and Pt/MOx/Al2O3 Catalysts for CO Oxidation

    OpenAIRE

    Hongmei Qin; Xiaoshuang Qian; Tao Meng; Yi Lin; Zhen Ma

    2015-01-01

    Conventional supported Pt catalysts have often been prepared by loading Pt onto commercial supports, such as SiO2, TiO2, Al2O3, and carbon. These catalysts usually have simple metal-support (i.e., Pt-SiO2) interfaces. To tune the catalytic performance of supported Pt catalysts, it is desirable to modify the metal-support interfaces by incorporating an oxide additive into the catalyst formula. Here we prepared three series of metal oxide-modified Pt catalysts (i.e., Pt/MOx/SiO2, Pt/MOx/TiO2, a...

  18. Bimetallic Pt-Ni catalysts supported on usy zeolite for n-hexane isomerization

    Directory of Open Access Journals (Sweden)

    F. V. Barsi

    2009-06-01

    Full Text Available Isomerization of linear alkanes has had considerable importance for the refining industry because the isomers formed in this reaction have high octane number. Most works reported in the literature studied the use of bifunctional catalysts, i.e., ones that have acid sites and metallic sites. In this study, bifunctional monometallic (Ni or Pt and bimetallic catalysts (Pt-Ni, using HUSY zeolite as the support, were prepared in order to verify the role of the metal content and composition on the catalytic properties for n-hexane isomerization. The method used for metal dispersion in the zeolite was competitive ion exchange using ammine complexes [Ni(NH36]Cl2 and [Pt(NH34]Cl2 as precursors. Four series of catalysts with constant atomic metal content had total metal amounts between 130 and 280 µmol M/g cat. Catalysts were characterized by temperature programmed reduction (TPR and subjected to catalytic evaluation for n-hexane isomerization at 250 ºC and 1 atm using H2/C6 = 9 molar ratio. TPR results show an easier reducibility of Ni+2 cations in the presence of Pt, which was evidenced by the displacement of the reduction peak of those cations towards lower temperatures in bimetallic catalysts. The bimetallic catalysts presented a higher activity in the isomerization of n-hexane when compared to the monometallic ones, as well better stability as the Pt content in the solid increases. The results of the activity as a function of the Pt content in the bimetallic catalysts show a maximum value around 50% of Pt. An addition of Pt above this critical value leads to a small decrease of the catalytic activity.

  19. Engineering the Activity and Stability of Pt-Alloy Cathode Fuel-Cell Electrocatalysts by Tuning the Pt-Pt Distance

    DEFF Research Database (Denmark)

    Escribano, Maria Escudero; Malacrida, Paolo; Vej-Hansen, Ulrik Grønbjerg

    2014-01-01

    with a thickness of few Pt layers is formed. Accordingly, the effect of alloying Pt is to impose strain onto the Pt overlayer [3,4]. It is likely that this strain would be relaxed by defects [6]. Moreover, the activity of the Pt5Ln catalysts vs. the Pt-Pt distance shows a volcano relationship (Fig. A) [5]. Pt5Ln......One of the main obstacles to the commercialisation of low-temperature fuel cells is the slow kinetics of the oxygen reduction reaction (ORR). In order to decrease the ORR overpotential and reduce the Pt loading we need to develop more active and stable electrocatalysts. A fruitful strategy...... for enhancing the cathode activity is to alloy Pt with transition metals [1-2]. However, alloys of Pt and late transition metals are typically unstable under fuel-cell conditions. Herein, we present experimental and theoretical studies showing the trends in activity and stability of novel cathode catalysts...

  20. Engineering the Activity and Stability of Pt-Alloy Cathode Fuel-Cell Electrocatalysts by Tuning the Pt-Pt Distance

    DEFF Research Database (Denmark)

    Escribano, Maria Escudero; Malacrida, Paolo; Vej-Hansen, Ulrik Grønbjerg

    2014-01-01

    based on alloys of Pt and lanthanides. Sputter-cleaned, polycrystalline Pt5Gd shows a five-fold increase in ORR activity [3], relative to Pt at 0.9 V in 0.1 M HClO4. The rest of the Pt5Ln (Ln = lanthanide) tested present at least a 3-fold enhancement in activity [4,5]. In all cases, a Pt overlayer...

  1. Dynamics of the YSZ-Pt Interface

    DEFF Research Database (Denmark)

    Bay, Lasse; Jacobsen, Torben

    1997-01-01

    Yttria stabilized zirconia (YSZ)-Pt point electrodes were examined by linear potential sweep, potential step and impedance measurements at 1000 degrees C in air. Inductive loops and hysteresis phenomena with long relaxation times were found. Atomic force microscopy showed changes of the interface...... between Pt and YSZ induced by the current passage. These changes involve transport of solid and are slow enough to explain the large time constants. The low frequency capacitance and inductive loop forming an entire circle indicate the presence of gas reservoirs at the YSZ-Pt interface....

  2. Structure of the O-specific polysaccharide from the lipopolysaccharide of Aeromonas sobria strain Pt312.

    Science.gov (United States)

    Turska-Szewczuk, Anna; Pietras, Hubert; Duda, Katarzyna A; Kozińska, Alicja; Pękala, Agnieszka; Holst, Otto

    2015-02-11

    The O-specific polysaccharide (OPS) obtained by mild-acid degradation of the lipopolysaccharide from Aeromonas sobria strain Pt312 was studied by sugar and methylation analyses along with 1H and 13C NMR spectroscopy, including 2D 1H,1H COSY, TOCSY, NOESY, 1H-detected 1H,13C HSQC, and HMBC experiments. The sequence of the sugar residues was determined using 1H,1H NOESY and 1H,13C HMBC experiments. It was found that the OPS was built up of disaccharide repeating units composed of GlcpNAc and non-stoichiometrically O-acetylated Rhap residues, and had the structure.

  3. PT-Symmetric Quantum Electrodynamics

    CERN Document Server

    Bender, C M; Milton, K A; Shajesh, K V; Bender, Carl M.; Cavero-Pelaez, Ines; Milton, Kimball A.

    2005-01-01

    The Hamiltonian for quantum electrodynamics becomes non-Hermitian if the unrenormalized electric charge $e$ is taken to be imaginary. However, if one also specifies that the potential $A^\\mu$ in such a theory transforms as a pseudovector rather than a vector, then the Hamiltonian becomes PT symmetric. The resulting non-Hermitian theory of electrodynamics is the analog of a spinless quantum field theory in which a pseudoscalar field $\\phi$ has a cubic self-interaction of the form $i\\phi^3$. The Hamiltonian for this cubic scalar field theory has a positive spectrum, and it has recently been demonstrated that the time evolution of this theory is unitary. The proof of unitarity requires the construction of a new operator called C, which is then used to define an inner product with respect to which the Hamiltonian is self-adjoint. In this paper the corresponding C operator for non-Hermitian quantum electrodynamics is constructed perturbatively. This construction demonstrates the unitarity of the theory. Non-Hermit...

  4. Mesoporous Pt and Pt/Ru alloy electrocatalysts for methanol oxidation

    Energy Technology Data Exchange (ETDEWEB)

    Franceschini, Esteban A. [Grupo de Celdas de Combustible, Departamento de Fisica de la Materia Condensada, Centro Atomico Constituyentes, CNEA. Av. General Paz 1499 (1650), San Martin, Buenos Aires (Argentina); Planes, Gabriel A. [Departamento de Quimica, Facultad de Ciencias Exactas, Fisicoquimicas y Naturales, Universidad Nacional de Rio Cuarto, Agencia Postal No 3, 5800, Rio Cuarto (Argentina); Williams, Federico J. [Departamento de Quimica Inorganica, Analitica y Quimica-Fisica, INQUIMAE CONICET, Facultad Ciencias Exactas y Naturales, Pabellon 2, Ciudad Universitaria, Buenos Aires (Argentina); Soler-Illia, Galo J.A.A. [Gerencia de Quimica, Centro Atomico Constituyentes, CNEA. Av. General Paz 1499 (1650), San Martin, Buenos Aires (Argentina); Corti, Horacio R. [Grupo de Celdas de Combustible, Departamento de Fisica de la Materia Condensada, Centro Atomico Constituyentes, CNEA. Av. General Paz 1499 (1650), San Martin, Buenos Aires (Argentina); Departamento de Quimica Inorganica, Analitica y Quimica-Fisica, INQUIMAE CONICET, Facultad Ciencias Exactas y Naturales, Pabellon 2, Ciudad Universitaria, Buenos Aires (Argentina)

    2011-02-15

    Mesoporous Pt and Pt/Ru catalysts with 2D-hexagonal mesostructure were synthesized using a triblock poly(ethylene oxide)-b-poly(propylene oxide)-b-poly(ethylene oxide) copolymer (Pluronic F127 {sup registered}) template, on a gold support. Large electrochemical surface areas were observed for the catalysts prepared at high overpotentials. Compared to the Pt catalyst, the Pt/Ru alloy containing 3 at% of Ru exhibited lower onset potential and more than three times the limit mass activity for methanol oxidation. This behavior is assigned to the larger pore size of the mesoporous Pt and Pt/Ru catalysts obtained with this template that seems to improve the methanol accessibility to the active sites compared to those obtained using lyotropic liquid crystals. (author)

  5. The SHORT-ROOT-like gene PtSHR2B is involved in Populus phellogen activity.

    Science.gov (United States)

    Miguel, Andreia; Milhinhos, Ana; Novák, Ondřej; Jones, Brian; Miguel, Célia M

    2016-03-01

    SHORT-ROOT (SHR) is a GRAS transcription factor first characterized for its role in the specification of the stem cell niche and radial patterning in Arabidopsis thaliana (At) roots. Three SHR-like genes have been identified in Populus trichocarpa (Pt). PtSHR1 shares high similarity with AtSHR over the entire length of the coding sequence. The two other Populus SHR-like genes, PtSHR2A and PtSHR2B, are shorter in their 5' ends when compared with AtSHR. Unlike PtSHR1, that is expressed throughout the cambial zone of greenhouse-grown Populus trees, PtSHR2Bprom:uidA expression was detected in the phellogen. Additionally, PtSHR1 and PtSHR2B expression patterns markedly differ in the shoot apex and roots of in vitro plants. Transgenic hybrid aspen expressing PtSHR2B under the 35S constitutive promoter showed overall reduced tree growth while the proportion of bark increased relative to the wood. Reverse transcription-quantitative PCR (RT-qPCR) revealed increased transcript levels of cytokinin metabolism and response-related genes in the transgenic plants consistent with an increase of total cytokinin levels. This was confirmed by cytokinin quantification by LC-MS/MS. Our results indicate that PtSHR2B appears to function in the phellogen and therefore in the regulation of phellem and periderm formation, possibly acting through modulation of cytokinin homeostasis. Furthermore, this work points to a functional diversification of SHR after the divergence of the Populus and Arabidopsis lineages. This finding may contribute to selection and breeding strategies of cork oak in which, unlike Populus, the phellogen is active throughout the entire tree lifespan, being at the basis of a highly profitable cork industry.

  6. PT-Symmetry Quantum Electrodynamics--PTQED

    CERN Document Server

    Milton, Kimball A; Parashar, Prachi; Shajesh, K V; Wagner, Jef

    2007-01-01

    The construction of $\\mathcal{PT}$-symmetric quantum electrodynamics is reviewed. In particular, the massless version of the theory in 1+1 dimensions (the Schwinger model) is solved. Difficulties with unitarity of the $S$-matrix are discussed.

  7. PT-Symmetric Quantum Field Theory

    CERN Document Server

    Milton, K A

    2003-01-01

    In the context of the PT-symmetric version of quantum electrodynamics, it is argued that the C operator introduced in order to define a unitary inner product has nothing to do with charge conjugation.

  8. Golden Gate and Pt. Reyes Acoustic Detections

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This dataset contains detections of acoustic tagged fish from two general locations: Golden Gate (east and west line) and Pt. Reyes. Several Vemco 69khz acoustic...

  9. PT-Symmetric Optomechanically-Induced Transparency

    CERN Document Server

    Jing, H; Özdemir, S K; Zhang, J; Lü, X -Y; Peng, B; Yang, L; Nori, F

    2014-01-01

    Optomechanically-induced transparency (OMIT) and the associated slow-light propagation provide the basis for storing photons in nanofabricated phononic devices. Here we study OMIT in parity-time (PT)-symmetric microresonators with a tunable gain-to-loss ratio. This system features a reversed, non-amplifying transparency: inverted-OMIT. When the gain-to-loss ratio is steered, the system exhibits a transition from the PT-symmetric phase to the broken-PT-symmetric phase. We show that by tuning the pump power at fixed gain-to-loss ratio or the gain-to-loss ratio at fixed pump power, one can switch from slow to fast light and vice versa. Moreover, the presence of PT-phase transition results in the reversal of the pump and gain dependence of transmission rates. These features provide new tools for controlling light propagation using optomechanical devices.

  10. Calcium platinum aluminium, CaPtAl

    Directory of Open Access Journals (Sweden)

    Charles Fon Abi

    2011-10-01

    Full Text Available A preliminary X-ray study of CaPtAl has been reported previously by Hulliger [J. Alloys Compd (1993, 196, 225–228] based on X-ray powder diffraction data without structure refinement. With the present single-crystal X-ray study, we confirm the assignment of the TiNiSi type for CaPtAl, in a fully ordered inverse structure. All three atoms of the asymmetric unit have .m. site symmetry. The structure features a ∞3[AlPt] open framework with a fourfold coordination of Pt by Al atoms and vice versa. The Ca atoms are located in the large channels of the structure.

  11. Industrial Physics Careers: A Large Company Perspective

    Science.gov (United States)

    Zollner, Stefan

    2009-03-01

    Statistical data from the American Institute of Physics and the National Science Foundation show that only about a third of physics graduates get permanent jobs in academia. A few work in government labs and hospitals. The majority of physics Ph.D.s, however, find employment in the private sector (industry). This trend has been increasing, i.e., recent Ph.D.s are even more likely to start careers in industry. Industrial physicists work in small, medium or large companies in a broad range of fields, including aerospace, semiconductors, automotive, energy, information technology, contract research, medical, chemical, optics, etc. They are also represented in fields outside of physics, such as finance. Even the ``inventor'' of the Powerball lottery game is a Ph.D. physicist. In my talk, I will describe pathways to success for an industrial physicist, from the perspective of employment in three different large corporations. Based on the NIST Baldridge criteria of Performance Excellence, I will discuss how to achieve and measure organizational success through focus on products and customers. Individual performance is linked to the goals of the organization. Performance has two components: Goals and behaviors. Both are key to success as an individual contributor or manager.[4pt] References: [0pt] http://www.aip.org/statistics/trends/emptrends.html [0pt] http://www.aps.org/about/governance/committees/commemb/index.cfm [0pt] http://www.quality.nist.gov/

  12. Adsorption of formaldehyde and formyl intermediates on Pt, PtRu-, and PtRuMo-alloy surfaces: A density functional study

    Science.gov (United States)

    Cahyanto, Wahyu Tri; Shukri, Ganes; Agusta, Mohammad Kemal; Kasai, Hideaki

    2013-02-01

    Stable binding configuration for formaldehyde (H2CO) and formyl (HCO) adsorption on Pt, PtRu, and PtRuMo are studied within the frame of density functional theory (DFT). We address this study to investigate the role of Ru and Mo on the binding characteristic of formaldehyde and formyl adsorption with respect to interaction strength and charge analysis. Several binding conformation on all possible surface adsorption sites are considered in determining the most stable adsorption geometry on three surfaces. Our results show that the presence of Ru in PtRu and Mo in PtRuMo stabilize the formaldehyde and formyl, which are indicated by stronger bond strength. Further electronic structure analysis shows that the addition of Ru in PtRu and Mo in PtRuMo modifies the electronic structure of Pt's surface significantly. The presence of both impurities shifted the derived anti-bonding state - which is originally located below the fermi level in pure Pt surface - to be above the fermi level in PtRu and PtRuMo systems. This fact explains the stronger adsorption found on PtRu & PtRuMo as compared to pure Pt surface.

  13. PERSISTENCE AND TOXICITY OF TOXAPHENE RESIDUES IN SOIL

    OpenAIRE

    S.GH MIRSATTARI

    2003-01-01

    pt; font-family: Tahoma">Introduction: Toxaphene is a persistent chlorinated hydrocarbon insecticide which can bioaccumulate in foodweb and cause serious public health and environmental problems. The technical mixture of toxaphene contains over 800 different congeners with different toxicity and resistance to degradation.
    This study was carried out to determine the toxicity of toxaphene residues from soil on ho...

  14. Superior long-term activity for a Pt-Re alloy compared to Pt in methanol oxidation reactions

    Science.gov (United States)

    Duke, Audrey S.; Xie, Kangmin; Monnier, John R.; Chen, Donna A.

    2017-03-01

    Pt-Re bimetallic catalysts have shown enhanced activity compared to pure Pt for reactions involving oxidation, but the origins of this improved activity are not fully understood. Methanol oxidation on a Pt-Re alloy surface and pure Pt foil was studied in a microreactor coupled to an ultrahigh vacuum chamber. For reaction at 60 °C, the Pt-Re alloy surface exhibits superior long-term activity over a 24 h reaction period compared to pure Pt. The initial activity of Pt is 10-15% higher than on Pt-Re; however, the Pt surface gradually loses activity after 10 h online, whereas the activity of Pt-Re does not diminish. Post-reaction XPS shows that more carbon accumulates on the Pt than on Pt-Re, and the improved long-term activity is attributed to a greater ability of Pt-Re to oxidize the carbonaceous intermediates that eventually poison active sites. Both Pt and Pt-Re surfaces have almost no activity for methanol oxidation until a minimum coverage of oxygen is achieved from O2 dissociation. A comparison with methanol oxidation studies on Pt and Pt-Re in a pressure regime that is 150 times lower than in this work demonstrates that more carbon and less oxygen accumulate on the surfaces during reaction at the lower pressures.

  15. The CO/Pt(111) Puzzle

    Energy Technology Data Exchange (ETDEWEB)

    FEIBELMAN,PETER J.; HAMMER,B.; NORSHOV,J.K.; WAGNER,F.; SCHEFFLER,M.; STUMPF,R.; DUMESIC,J.; WATWE,R.

    2000-07-12

    Notwithstanding half a dozen theoretical publications, well-converged density-functional calculations, whether based on a local or generalized-gradient exchange-correlation potential, whether all-electron or employing pseudopotentials underestimate CO's preference for low-coordination binding sites on Pt(111) and vicinals to it. For example, they imply that CO should prefer hollow- to atop-site adsorption on Pt(111), in apparent contradiction to a host of low temperature experimental studies.

  16. Scattering properties of PT-symmetric objects

    CERN Document Server

    Miri, Mohammad-Ali; Facao, Margarida; Abouraddy, Ayman F; Bakry, Ahmed; Razvi, Mir A N; Alshahrie, Ahmed; Alù, Andrea; Christodoulides, Demetrios N

    2016-01-01

    We investigate the scattering response of parity-time (PT) symmetric structures. We show that, due to the local flow of energy between gain and loss regions, such systems can deflect light in unusual ways, as a function of the gain/loss contrast. Such structures are highly anisotropic and their scattering patterns can drastically change as a function of the angle of incidence. In addition, we derive a modified optical theorem for PT-symmetric scattering systems, and discuss its ramifications.

  17. Information Technology (IT Improvement At PT. Sumber Alfaria Trijaya

    Directory of Open Access Journals (Sweden)

    Marisa Karsen

    2013-06-01

    Full Text Available Retail industry is the second largest industry after agricultural industry in terms of employment absorption in Indonesia. The situation of the quite dynamic retail industry is marked by the development of modern retail trade and it impacts on traditional markets and suppliers. PT Sumber Alfaria Trijaya, known as Alfamart is one of the best retail company  in Indonesia. It already uses Supply Chain Management and B2B to support their operations. Alfamart also has its own website which provides information about products, outlets, services, and promo. This research discusses about IT improvement. The purpose of this paper is to improve Alfamart IT performance and make innovation on the IT to increase customer satisfaction.  The methodology used is defining the problem, measure, analyst problem, improvement required by Alfamart, and control to monitor the implementation. Problems are identified using SWOT analysis, problem clarification, and business model canvas. Analyzing the problems, solution hypotheses and IT improvement are recommended for Alfamart.  

  18. Measurement of residual solvents in a drug substance by a purge-and-trap method.

    Science.gov (United States)

    Lakatos, Miklós

    2008-08-05

    The purge-and-trap (P&T) gas extraction method combined with gas chromatography was studied for its suitability for quantitative residual solvents determination in a water-soluble active pharmaceutical ingredient (API). Some analytical method performance characteristics were investigated, namely, the repeatability, the accuracy and the detection limit of determination. The results show that the P&T technique is--as expected--more sensitive than the static headspace, thus it can be used for the determination of residual solvents pertaining to the ICH Class 1 group. It was found that it could be an alternative sample preparation method besides the static headspace (HS) method.

  19. Green supply chain management strategy selection using analytic network process: case study at PT XYZ

    Science.gov (United States)

    Adelina, W.; Kusumastuti, R. D.

    2017-01-01

    This study is about business strategy selection for green supply chain management (GSCM) for PT XYZ by using Analytic Network Process (ANP). GSCM is initiated as a response to reduce environmental impacts from industrial activities. The purposes of this study are identifying criteria and sub criteria in selecting GSCM Strategy, and analysing a suitable GSCM strategy for PT XYZ. This study proposes ANP network with 6 criteria and 29 sub criteria, which are obtained from the literature and experts’ judgements. One of the six criteria contains GSCM strategy options, namely risk-based strategy, efficiency-based strategy, innovation-based strategy, and closed loop strategy. ANP solves complex GSCM strategy-selection by using a more structured process and considering green perspectives from experts. The result indicates that innovation-based strategy is the most suitable green supply chain management strategy for PT XYZ.

  20. Analisis Perancangan Customer Relationship Management Berbasis Web pada PT ASP Jakarta

    Directory of Open Access Journals (Sweden)

    Idris Gautama So

    2011-05-01

    Full Text Available The purpose of this thesis is to identify the needs of web-based CRM in PT ASP and also to design the suitable CRM for the company. The research method is by analyzing competitions in the industry with Porter’s five forces analysis and formulating framework in input stage, matching stage, decision stage to choose the best strategy for the company. From the analysis of formulating strategy, it could be concluded that market penetration strategy is the best strategy for PT ASP. Market penetration strategy is an approach of web-based Customer Relationship Management (CRM to increase service quality for customers and company introduction to broaden community. Web-based CRM design is suitable for PT ASP based on interview conclusion using 5 features (5C from the 7 features (7C in web design elements. 

  1. Reduction of Pt Usage in Fuel Cell Electrocatalysts Using Carbon Nanotubes and Non-Pt Metals

    Institute of Scientific and Technical Information of China (English)

    J. Nakamura; Y. Nagashima; T. Yamazaki; T. Matsumoto; E. Yoo

    2005-01-01

    @@ 1Introduction The high-priced and limited Pt constitutes a high barrier to commercialization of fuel cells. Pt is essential for the electrode catalyst of polymer electrolyte fuel cells (PEFCs). A reduction in Pt usage is one of the key requirements for the commercialization of fuel cells for use in everyday life, because of its high price and limited availability, and the difficulty of finding suitable substitutes. Non-Pt fuel cell catalysts will decrease the demand for Pt by PEFCs, enabling more Pt to be available for use in other essential products, and make fuel cells more popular[1]. The cheaper Mo2C is known to possess similar catalytic activities and electronic structures to Pt[2]. Carbon black (CB) is widely used as the support for Pt nanoparticles. However, we found that when carbon nanotubes (CNTs) rather than CB are used as the support, the performance is improved, especially below 600 mA/cm2[3,4]. Here, we show that a combination of Mo2C catalyst and carbon nanotubes in the anode provides performance as high as half that of the current PEFCs with Pt catalysts below 600mA/cm2.

  2. Electrocatalysis of fuel cells reaction on Pt and Pt-bimetallic anode catalysts: A selective review

    Directory of Open Access Journals (Sweden)

    Stamenković Vojislav

    2002-01-01

    Full Text Available In this review we selectively summarize recent progress, primarily from our laboratory, in the development of interrelationships between the kinetics of the fuel cells reactions and the structure/composition of anode catalysts. The focus is placed on two types of metallic surfaces: platinum single crystals and bimetallic surfaces based on Pt. In the first part it was illustrated that the hydcogen reaction is structure sensitive process, with Pt(110 being an order of magnitude more active than either of the atomically "flatter" (100 and (111 surfaces. The hydrogen reaction on Pt(hkl modified by pseudomorphic Pd (submonolayers shows the "volcano-like" behavior, having the maximum rate on Pt(111 modified by 1 ML of Pd. The Pt(111-Pd system is used to demonstrate how the energetics of intermediates formed in the hydrogen reaction is affected by interfacial bonding and energetic constraints produced between pseudomorphic Pd films and the Pt(111 substrate. In the second part it was shown that the oxidation of Ha in the presence of CO occurs concurrently with CO oxidation on Pt and Pt bimetallic surfaces. The Pt-Ru system is used to demonstrate that both the bifunctional effect and the ligand effect contribute to the influence of Ru on the CO oxidation rate and for Hz oxidation process in the presence of CO. The knowledge is then used to create the real-life catalyst with the catalytic activities which are, to the greatest extend possible similar to the tailor-made surface.

  3. Dependence of Magnetic Properties of Co/Pt Multilayers on Deposition Temperature of Pt Buffer Layers

    Science.gov (United States)

    Shiomi, Shigeru; Nishimura, Tomotaka; Kobayashi, Tadashi; Masuda, Morio

    1993-04-01

    A 15-nm-thick Pt buffer layer was deposited on a glass slide at temperature Ts(Ptbuf) ranging from 30 to 300°C by e-gun evaporation. Following the cooling in vacuum to ambient temperature, Co and Pt layers have been alternately deposited on it. Very large perpendicular anisotropy and coercivity have been obtained at Ts(Ptbuf) higher than 200°C. The (111) preferred orientation of the Co/Pt multilayer as well as the Pt buffer layer became more pronounced with elevating Ts(Ptbuf), to which the enhancement of perpendicular anisotropy with elevating Ts(Ptbuf) might be ascribable.

  4. Nanoparticulate CoPt Thin Films

    Science.gov (United States)

    Barekatain, Yasaman; Hadjipanayis, George; Magnetics bLab Team

    Equiatomic FePt and CoPt alloys are very attractive for application in high density recording media because of the high magnetocrystalline anisotropy K of their fct(L10) structure with values exceeding 2MJ/m3.The aim of this study is to fabricate a nanoparticulate CoPt film consisting of CoPt nanoparticles embedded in a matrix. To obtain this we have used co-sputtering of CoPt with different materials M = BN,C, Cu and SiO2. Our first experiments were done on CoPt films with thickness of 200 nm. The as-sputtered films had the fcc structure and a coercivity of 150 Oe. Annealing at 700 oC for 30 min led to an increase in coercivity to 4 kOe. Optimization studies are under way to find the optimum sputtering conditions to obtain a fully ordered tetragonal structure with the highest value of coercivity which can then be used in the nanoparticulate composites. Work supported by DOE BES- FG02-04ERU4612 DOE DE-FG02-04ERU4612.

  5. PT -symmetric model of immune response

    Science.gov (United States)

    Bender, Carl M.; Ghatak, Ananya; Gianfreda, Mariagiovanna

    2017-01-01

    The study of PT -symmetric physical systems began in 1998 as a complex generalization of conventional quantum mechanics, but beginning in 2007 experiments began to be published in which the predicted PT phase transition was clearly observed in classical rather than in quantum-mechanical systems. This paper examines the classical PT phase transition in dynamical-system models that are moderately accurate representations of antigen-antibody systems. A surprising conclusion that can be drawn from these models is that it might be possible treat a serious disease in which the antigen concentration grows out of bounds (and the host dies) by injecting a small dose of a second (different) antigen. In this case a PT -symmetric analysis shows there are two possible favorable outcomes. In the unbroken-PT -symmetric phase the disease becomes chronic and is no longer lethal, while in the appropriate broken-PT -symmetric phase the concentration of lethal antigen goes to zero and the disease is completely cured.

  6. PT phase transition in multidimensional quantum systems

    CERN Document Server

    Bender, Carl M

    2012-01-01

    Non-Hermitian PT-symmetric quantum-mechanical Hamiltonians generally exhibit a phase transition that separates two parametric regions, (i) a region of unbroken PT symmetry in which the eigenvalues are all real, and (ii) a region of broken PT symmetry in which some of the eigenvalues are complex. This transition has recently been observed experimentally in a variety of physical systems. Until now, theoretical studies of the PT phase transition have generally been limited to one-dimensional models. Here, four nontrivial coupled PT-symmetric Hamiltonians, $H=p^2/2+x^2/2+q^2/2+y^2/2+igx^2y$, $H=p^2/2+x^2/2+q^2/2+y^2+igx^2y$, $H=p^2/2+x^2/2+q^2/2+y^2/2+r^2/2+z^2/2+igxyz$, and $H=p^2/2+x^2/2+q^2/2+y^2+r^2/2+3z^2/2+igxyz$ are examined. Based on extensive numerical studies, this paper conjectures that all four models exhibit a phase transition. The transitions are found to occur at $g\\approx 0.1$, $g\\approx 0.04$, $g\\approx 0.1$, and $g\\approx 0.05$. These results suggest that the PT phase transition is a robust phen...

  7. Utilização de resíduos da indústria de couro como fonte nitrogenada para o capim-elefante Use of leather industry residues as nitrogen sources for elephantgrass

    Directory of Open Access Journals (Sweden)

    Diana Quintão Lima de Oliveira

    2008-02-01

    Full Text Available Uma grande variedade de produtos tóxicos é emitida durante o processo de tratamento do couro nos curtumes que usam o cromo III para obter o couro wet blue. O resíduo sólido (raspas e aparas contém cerca de 3 % de Cr III, que representa um sério problema ambiental e não tem, atualmente, destino adequado. O resíduo de couro após extração de Cr (colágeno foi utilizado como fonte nitrogenada para o capim-elefante (Pennisetum purpureum Schum cv. Napier, em um Latossolo Vermelho-Amarelo, aplicando-se quatro doses do colágeno (4, 8, 16 e 32 t ha-1 e três tratamentos adicionais (testemunha; adubação com N mineral e resíduo de couro wet blue- sem a extração do Cr. O colágeno é uma boa fonte nitrogenada alternativa para crescimento do capim-elefante até a dose de 16 t ha-1. O resíduo de couro wet blue não disponibilizou N durante o cultivo de capim-elefante. Isso mostra que a extração do Cr utilizando-se o ácido fosfórico é fundamental para uso do rejeito de couro como fonte nitrogenada na agricultura. A aplicação do colágeno supriu a necessidade de N para plantas de capim-elefante, semelhantemente à adubação com N mineral.Large amounts of solid wastes are produced in tanneries, which use chromium (III to obtain wet blue leather hides. The solid residues (leather scraps and strips contain around 3 % chromium (III, which represent a serious environmental problem and, presently, have no adequate destination. The leather waste after chromium extraction (collagen was used as a nitrogen source for elephantgrass- Pennisetum purpureum Schum cv. Napier. Four doses of collagen (4, 8, 16, and 32 t ha-1 and three additional treatments (control; mineral fertilizer N; and wet blue leather residue without Cr extraction were used. Collagen as alternative nitrogen source has a positive effect on elephantgrass growth at rates up to 16 t ha-1. Little N became available to elephantgrass plants after application of wet blue leather residues

  8. Residual strength of damaged marine structures

    Science.gov (United States)

    Ghose, Dhruba J.; Nappi, Natale S.; Wiernicki, Christopher J.

    1994-09-01

    Traditionally assessment of ship's longitudinal strength has been made by comparing the elastic stresses at the deck or bottom shell to fractions of the material yield strength. This results in high reserve capacity due to inherent redundancies in ship structures. Residual strength, which is defined as the strength of the structure after damage, has rarely been considered either during design or at the time of repair. In this report, key elements required to undertake an engineering analysis to evaluate the residual strength have been identified. Emphasis has been placed on assessing the residual strength of marine structures damaged due to normal operating loads. Methods available to industry for evaluation of damage such as, fracture and ultimate strength have been summarized. An example problem, illustrating the application of an integrated approach to residual strength assessment on a particular ship type, is presented.

  9. High pressure CO hydrogenation over bimetallic Pt-Co catalysts

    DEFF Research Database (Denmark)

    Christensen, Jakob Munkholt; Medford, Andrew James; Studt, Felix

    2014-01-01

    The potential of bimetallic Pt-Co catalysts for production of higher alcohols in high pressure CO hydrogenation has been assessed. Two catalysts (Pt3Co/SiO2 and PtCo/SiO2) were tested, and the existing literature on CO hydrogenation over Pt-Co catalysts was reviewed. It is found that the catalyst...

  10. Modeling of PEM fuel cell Pt/C catalyst degradation

    Science.gov (United States)

    Bi, Wu; Fuller, Thomas F.

    Pt/C catalyst degradation remains as one of the primary limitations for practical applications of proton exchange membrane (PEM) fuel cells. Pt catalyst degradation mechanisms with the typically observed Pt nanoparticle growth behaviors have not been completely understood and predicted. In this work, a physics-based Pt/C catalyst degradation model is proposed with a simplified bi-modal particle size distribution. The following catalyst degradation processes were considered: (1) dissolution of Pt and subsequent electrochemical deposition on Pt nanoparticles in cathode; (2) diffusion of Pt ions in the membrane electrode assembly (MEA); and (3) Pt ion chemical reduction in membrane by hydrogen permeating through the membrane from the negative electrode. Catalyst coarsening with Pt nanoparticle growth was clearly demonstrated by Pt mass exchange between small and large particles through Pt dissolution and Pt ion deposition. However, the model is not adequate to predict well the catalyst degradation rates including Pt nanoparticle growth, catalyst surface area loss and cathode Pt mass loss. Additional catalyst degradation processes such as new Pt cluster formation on carbon support and neighboring Pt clusters coarsening was proposed for further simulative investigation.

  11. Amorphous Pt@PdCu/CNT Catalyst for Methanol Electrooxidation ...

    African Journals Online (AJOL)

    A multi-walled carbon nanotube-supported, Pt decorated nano-sized ... alloy cores (denoted as Pt@PdCu/CNT) catalyst with lower Pt loading is synthesized via a ... The electrochemical activity of the Pt@PdCu/CNT catalyst is tested by cyclic ...

  12. Surface Segregation in Supported Pd-Pt Nanoclusters and Alloys

    NARCIS (Netherlands)

    van den Oetelaar, L.C.A.; Nooij, O.W.; Oerlemans, S.; Denier van der Gon, A.W.; Brongersma, H.H.; Lefferts, Leonardus; Roosenbrand, A.G.; van Veen, J.A.R.

    1998-01-01

    Surface segregation processes in Pd-Pt alloys and bimetallic Pd-Pt nanoclusters on alumina and carbon supports (technical catalysts) have been investigated by determining the metal surface composition of these systems by low-energy ion scattering (LEIS). Both Pd-rich (Pd80Pt20) and Pt-rich

  13. Resistive switching in Pt/TiO{sub 2}/Pt

    Energy Technology Data Exchange (ETDEWEB)

    Jeong, Doo Seok

    2008-08-15

    Recently, the resistive switching behavior in TiO{sub 2} has drawn attention due to its application to resistive random access memory (RRAM) devices. TiO{sub 2} shows characteristic non-volatile resistive switching behavior, i.e. reversible switching between a high resistance state (HRS) and a low resistance state (LRS). Both unipolar resistive switching (URS) and bipolar resistive switching (BRS) are found to be observed in TiO{sub 2} depending on the compliance current for the electroforming. In this thesis the characteristic current-voltage (I-V) hysteresis in three different states of TiO{sub 2}, pristine, URS-activated, and BRS-activated states, was investigated and understood in terms of the migration of oxygen vacancies in TiO{sub 2}. The I-V hysteresis of pristine TiO{sub 2} was found to show volatile behavior. That is, the temporary variation of the resistance took place depending on the applied voltage. However, the I-V hysteresis of URS- and BRS-activated states showed non-volatile resistive switching behavior. Some evidences proving the evolution of oxygen gas during electroforming were obtained from time-of-flight secondary ion mass spectroscopy analysis and the variation of the morphology of switching cells induced by the electroforming. On the assumption that a large number of oxygen vacancies are introduced by the electroforming process, the I-V behavior in electroformed switching cells was simulated with varying the distribution of oxygen vacancies in electroformed TiO{sub x} (x Pt/TiO{sub x} interface. The oxygen-related reactions given as a function of the applied voltage affect the distribution of oxygen vacancies in TiO{sub x}, consequently, the Schottky barrier height at the cathode/TiO{sub x} interface is influenced by the oxygen vacancy distribution. Therefore, the BRS behavior including the

  14. Research on Raman-scattering and Fabrication of Multilayer Thin Film with Different Structures and Components Based on Pt/Ti/Si3N4/SiO2/Si Substrate

    Institute of Scientific and Technical Information of China (English)

    Qiu-lin Tan; Wen-dong Zhang; Chen-yang Xue; Jun Liu; Jun-hong Li; Ji-jun Xiong

    2009-01-01

    Using the same conditions and various starting materials, such as lead acetate trihydrate, tetrabulyl titanate, zirconium n-butoxide, and acetylacetone, two kinds of solid precursors, lead zirconate titanate (PZT, Zr/Ti=15/85) and lead titanate (PT), were fabricated. With three different combinations, namely, PZT, PT/PZT-PZT/PT, and PT/PZT/-/PZT/PT, three multilayer thin films were deposited on three Pt-Ti-Si3N4-SiO2-Si substrates by a modified sol-gel process. The fabrication process of the thin films is discussed in detail. We found that there is a large built-in stress in the thin film, which can be diminished by annealing at 600 ℃, when the gel is turned into solid material through drying and sintering. The Raman scattering spectra of the films with different compositions and structures were investigated. With the help of X-ray diffraction (XRD) analyzer and Raman scattering spectra analyzer, it was found that the thin films with the PT/PZT-PZT/PT structure have reasonable crystallinity and less residual stress. XRD testing shows that the diffraction pattern of the multilayer film results from the superimposition of the PZT and PT patterns. This leads to the conclusion that the PT/PZT-PZT/PT multilayer thin film has a promising future in pyroelectric infrared detectors with high performance.

  15. Evaluación del tratamiento biológico para remoción de color índigo de agua residual industrial textil por un consorcio microbiano en lecho fluidizado

    Directory of Open Access Journals (Sweden)

    Quintero1 Luz

    2012-05-01

    Full Text Available El recurso hídrico ha sido uno de los más afectados por la industrialización y el desarrollo del sector textil. Medellín es la capital de la moda en Colombia y en la ciudad, se utilizan diariamente tintorerías dedicadas al teñido de prendas índigo. Son grandes consumidores de agua potable y subterránea. El agua, utilizada con mínima conciencia, es su mayor materia prima y la que genera altos costos mensuales. Este estudio construyó un reactor de lecho fluidizado (RLF. La antracita se utilizó como material de soporte para investigar la eficiencia de remoción de la demanda química de oxígeno (DQO, demanda bioquímica de oxígeno (DBO y el color del agua residual textil simulada. Los siguientes estudios a escala de laboratorio fueron realizados inicialmente para preparar los ensayos de inmovilización de microorganismos en medio de soporte sólido y los períodos de puesta en marcha y operación de la planta piloto: bioaumentación y bioadaptación de inóculo tomado de efluente textil y remoción de color en reactor discontinuo. Los resultados indicaron que es posible lograr el tratamiento aeróbico de agua residual textil después de obtener un inóculo adaptado a las fuentes de carbono de tensoactivos e índigo.

  16. Industry Employment

    Science.gov (United States)

    Occupational Outlook Quarterly, 2012

    2012-01-01

    This article illustrates projected employment change by industry and industry sector over 2010-20 decade. Workers are grouped into an industry according to the type of good produced or service provided by the establishment for which they work. Industry employment projections are shown in terms of numeric change (growth or decline in the total…

  17. Synthesis of Supported NiPt Bimetallic Nanoparticles, Methods for Controlling the Surface Coverage of Ni Nanoparticles With Pt, Methods Of Making NiPt Multilayer Core-Shell Structures and Application of the Supported Catalysts for CO2 Reforming

    KAUST Repository

    Li, Lidong

    2015-06-25

    Embodiments of the present disclosure provide for supported Ni/Pt bimetallic nanoparticles, compositions including supported NiPt nanoparticles, methods of making supported NiPt nanoparticles, methods of using supported NiPt nanoparticles, and the like.

  18. Microwave sinthesys and characterization of Pt and Pt-Rh-Sn electrocatalysts for ethanol oxidation

    Directory of Open Access Journals (Sweden)

    Jovanović Vladislava M.

    2011-01-01

    Full Text Available Carbon supported Pt and Pt-Rh-Sn catalysts were synthesized by microwave-polyol method in ethylene glycol solution and investigated for the ethanol electro-oxidation reaction. The catalysts were characterized in terms of structure, morphology and composition by employing XRD, STM and EDX techniques. STM analysis indicated rather uniform particles and particle size of below 2 nm for both catalysts. XRD analysis of the Pt/C catalyst revealed two phases, one with the main characteristic peaks of face centered cubic crystal structure (fcc of platinum and another related to graphite like structure of carbon support Vulcan XC-72R. However, in XRD pattern of the Pt-Rh-Sn/C catalyst diffraction peaks for Pt, Rh or Sn cannot be resolved, indicating an extremely low crystallinity. The small particle sizes and homogeneous size distributions of both catalysts should be attributed to the advantages of microwave assisted modified polyol process in ethylene glycol solution. Pt-Rh- Sn/C catalyst is highly active for the ethanol oxidation with the onset potential shifted for more than 150 mV to negative values and with currents nearly 5 times higher in comparison to Pt/C catalyst. The stability tests of the catalysts, as studied by the chronoamperometric experiments, reveal that the Pt-Rh-Sn/C catalyst is evidently less poisoned then Pt/C catalyst. The increased activity of Pt-Rh-Sn/C in comparison to Pt/C catalyst is most probably promoted by bifunctional mechanism and the electronic effect of alloyed metals.

  19. Preparation of PtSn/C, PtRu/C, PtRh/C, PtRuRh/C and PtSnRh/C electrocatalysts using an alcohol-reduction process for methanol and ethanol oxidation; Preparacao e caracterizacao de eletrocatalisadores PtRu, PtSn, PtRh, PtRuRh e PtSnRh para oxidacao direta de alcoois em celulas a combustivel tipo PEM utilizando a metodologia da reducao por alcool

    Energy Technology Data Exchange (ETDEWEB)

    Dias, Ricardo Rodrigues

    2009-07-01

    In this work, Pt/C, PtRh (90:10), PtRh/C (50:50), PtSn/C (50:50), PtRu (50:50)/C, PtRuRh/C (50:40:10) and PtSnRh/C (50:40:10) were prepared by an alcohol-reduction process with metal loading of 20 wt.% using H{sub 2}PtCl{sub 6}.6H{sub 2}O (Aldrich), SnCl{sub 2}.2H{sub 2}O (Aldrich),and RhCl{sub 2}.XH{sub 2}O (Aldrich) as metals sources and Vulcan XC72 as support. The electrocatalysts were characterized by EDX, XRD and cyclic voltammetry (CV). The electro-oxidation of ethanol was studied by CV, chronoamperomety at room temperature in acid medium and tests at 100 deg C on a single cell of a direct methanol or ethanol fuel cell. The EDX analysis showed that the metal atomic ratios of the obtained electrocatalysts were similar to the nominal atomic ratios used in the preparation. The diffractograms of electrocatalysts prepared showed four peaks at approximately 2{theta} =40 deg, 47 deg, 67 deg and 82 deg, which are associated with the (111), (200), (220) and (311) planes, respectively, of a face cubic-centered (fcc) structure characteristic of platinum and platinum alloys. The average crystallite sizes using the Scherrer equation and the calculated values were in the range of 2-3 nm. For Pt Sn/C and PtSnRh/C two additional peaks were observed at 2 = 34 deg and 52 deg that were identified as a SnO{sub 2} phase. Pt Sn/C (50:50) and PtSnRh/C (50:40:10) electro catalyst showed the best performance for ethanol oxidation at room temperature. For methanol oxidation at room temperature Pt Ru/C, Pt Sn/C and PtRuRh/C electrocatalysts showed the best performance. Tests at 100 deg C on a single cell of a direct ethanol fuel cell PtSnRh/C showed the best performance, for methanol oxidation PtRuRh/C showed the best performance. (author)

  20. Pt skin coated hollow Ag-Pt bimetallic nanoparticles with high catalytic activity for oxygen reduction reaction

    Science.gov (United States)

    Fu, Tao; Huang, Jianxing; Lai, Shaobo; Zhang, Size; Fang, Jun; Zhao, Jinbao

    2017-10-01

    The catalytic activity and stability of electrocatalyst is critical for the commercialization of fuel cells, and recent reports reveal the great potential of the hollow structures with Pt skin coat for developing high-powered electrocatalysts due to their highly efficient utilization of the Pt atoms. Here, we provide a novel strategy to prepare the Pt skin coated hollow Ag-Pt structure (Ag-Pt@Pt) of ∼8 nm size at room temperature. As loaded on the graphene, the Ag-Pt@Pt exhibits a remarkable mass activity of 0.864 A/mgPt (at 0.9 V, vs. reversible hydrogen electrode (RHE)) towards oxygen reduction reaction (ORR), which is 5.30 times of the commercial Pt/C catalyst, and the Ag-Pt@Pt also shows a better stability during the ORR catalytic process. The mechanism of this significant enhancement can be attributed to the higher Pt utilization and the unique Pt on Ag-Pt surface structure, which is confirmed by the density functional theory (DFT) calculations and other characterization methods. In conclusion, this original work offers a low-cost and environment-friendly method to prepare a high active electrocatalyst with cheaper price, and this work also discloses the correlation between surface structures and ORR catalytic activity for the hollow structures with Pt skin coat, which can be instructive for designing novel advanced electrocatalysts for fuel cells.

  1. Pt and PtRu catalyst bilayers increase efficiencies for ethanol oxidation in proton exchange membrane electrolysis and fuel cells

    Science.gov (United States)

    Altarawneh, Rakan M.; Pickup, Peter G.

    2017-10-01

    Polarization curves, product distributions, and reaction stoichiometries have been measured for the oxidation of ethanol at anodes consisting of Pt and PtRu bilayers and a homogeneous mixture of the two catalysts. These anode structures all show synergies between the two catalysts that can be attributed to the oxidation of acetaldehyde produced at the PtRu catalyst by the Pt catalyst. The use of a PtRu layer over a Pt layer produces the strongest effect, with higher currents than a Pt on PtRu bilayer, mixed layer, or either catalyst alone, except for Pt at high potentials. Reaction stoichiometries (average number of electrons transferred per ethanol molecule) were closer to the values for Pt alone for both of the bilayer configurations but much lower for PtRu and mixed anodes. Although Pt alone would provide the highest overall fuel cell efficiency at low power densities, the PtRu on Pt bilayer would provide higher power densities without a significant loss of efficiency. The origin of the synergy between the Pt and PtRu catalysts was elucidated by separation of the total current into the individual components for generation of carbon dioxide and the acetaldehyde and acetic acid byproducts.

  2. Industrial Chain: Industrial Vertical Definition

    Institute of Scientific and Technical Information of China (English)

    YifeiDu; GuojunJiang; ShimingLi

    2004-01-01

    Like value chain and supply chain, “industrial chain” becomes the focus of attention. The implication of “industrial chain” has gained a large range of extension. It not only expresses the industrial “chain” structure and relationship of “back and forward”in order or “up and down” in direction, but also it represents a cluster of large scale of firms in an area or colony. It is a network, or a community. Consequently, we conclude that “industrial chain” is a synthesis of industrial chain, industrial cluster, or industrial network.In this article, firstly we will distinguish industry chain from industry. An industry is the collection of firms that have the same attribute, so an industry can be defined by firm collection of certain attribute. We indicate that industrial chain is a kind of vertical and orderly industrial link. It is defined according to a series of specific product or service created. Secondly we analyze the vertical orderly defiinition process from the aspects of social division of labor and requirement division, self-organization system, and value analysis.Non-symmetry and depending on system or community of large scale of industrial units lead to entire industry to “orderly” structure. On the other hand, the draught of diversity and complexity of requirement simultaneously lead to entire industry to be more “orderly”. Along with processes of self-organization, industrial will appi'oach the state of more orderly and steady, and constantly make industrial chain upgrade. Each firm or unit, who will gain the value, has to establish channels of value, which we called “industrial value chain”. Lastly,we discuss the consequence of vertical and orderly definition, which is exhibited by a certain relationship body. The typical forms of industrial chain include industrial cluster, strategy alliance and vertical integration etc.

  3. Establecimiento del límite aceptable para el residuo de limpieza en los equipos de producción de la industria farmacéutica Setting acceptable limit for cleaning residues in manufacturing equipment of the drug industry

    Directory of Open Access Journals (Sweden)

    Adaris María López Marzo

    2005-12-01

    Full Text Available Actualmente son crecientes las exigencias de los organismos reguladores de las Buenas Prácticas de Producción para asegurar la calidad y consistencia de los productos farmacéuticos. En uno de los aspectos básicos donde las autoridades realizan mucho más énfasis es en el programa de validación de limpieza, especialmente con la validación de los procedimientos de limpieza de los equipos de producción. No existe una guía clara para el establecimiento del límite de limpieza, solo existen pautas muy generales para la gran variedad de fármacos y situaciones de producción. Por ello, se recogen y analizan diferentes criterios para el cálculo y selección del límite aceptable de residuo. Se proponen soluciones para algunas situaciones que pudieran aparecer en la práctica y se destaca la importancia de un correcto establecimiento del límite. Se espera que resulte útil la identificación de situaciones donde sea apropiado cada enfoque del límite.At present, the demands of the governing bodies of Good Manufacturing Practice aimed at assuring the quality and consistency of pharmaceuticals are increasing. One of the basic aspects that the authorities make emphasis on is the cleaning validation program, particularly the validation of manufacturing equipment cleaning methods. There is no clear-cut guide to setting cleaning residues limit but very general guidelines for a great variety of drugs and manufacturing situations. To this end, the paper gathered and analyzed different criteria for estimation and selection of the acceptable residue limit. Some solutions for certain situations that may occur in practice were suggested and the importance of a right limit setting was underlined. It is expected that this paper be useful for the detection of situations where each limit approach may be convenient.

  4. Theoretical Study of CO Adsorption on Ni(111), Pt(111) and Pt/Ni(111) Surfaces

    Science.gov (United States)

    Cabeza, G. F.; Castellani, N. J.; Légaré, P.

    CO adsorption on a pseudomorphic Pt overlayer supported by Ni(111) has been studied with the use of extended Huckel calculations. Experimental information on the pure Pt(111) and Ni(111) single crystals was employed to select a consistent parameter set for our bimetallic system. This gives a good description of the chemisorption bond changes between the various systems considered in our study. The CO chemisorption energy on Pt/Ni(111) was found to be lowered in comparison with Pt(111) and Ni(111), in good agreement with experimental data on Pt-rich Pt-Ni surface alloys. This observation could be justified by the electronic changes of the Pt states (valence band broadening and decreasing density at the Fermi level). Indeed, they induce, in comparison with the pure substrates, a repulsion between Pt and CO although the 2π* population of the chemisorbed molecule increases. This points to the necessity of going beyond arguments based on an analysis of the 5σ donation and 2π* backdonation for a complete description of the chemisorption bond.

  5. Electrochemical promotion of catalytic reactions with Pt/C (or Pt/Ru/C)//PBI catalysts

    DEFF Research Database (Denmark)

    Petrushina, Irina; Bjerrum, Niels; Bandur, Viktor;

    2007-01-01

    The paper is an overview of the results of the investigation on electrochemical promotion of three catalytic reactions: methane oxidation with oxygen, NO reduction with hydrogen at 135 degrees C and Fischer-Tropsch synthesis (FTS) at 170 degrees C in the [CH4/O-2(or NO/H-2 or CO/H-2)/Ar//Pt(or Pt...

  6. Cyclic voltammograms for H on Pt(111) and Pt(100) from first principles

    DEFF Research Database (Denmark)

    Karlberg, Gustav; Jaramillo, Thomas; Skulason, Egill;

    2007-01-01

    Cyclic voltammetry is a fundamental experimental method for characterizing electrochemical surfaces. Despite its wide use, a way to quantitatively and directly relate cyclic voltammetry to ab initio calculations has been lacking. We derive the cyclic voltammogram for H on Pt(111) and Pt(100), based...

  7. Copper dusting effects on perpendicular magnetic anisotropy in Pt/Co/Pt tri-layers

    Directory of Open Access Journals (Sweden)

    Vineeth Mohanan Parakkat

    2016-05-01

    Full Text Available The effect of Cu dusting on perpendicular magnetic anisotropy of sputter grown Pt/Co/Pt stack in which the Cu layer is in proximity with that of Co is investigated in this work. We used magneto optic Kerr effect microscopy measurements to study the variation in the reversal mechanisms in films with Co thicknesses below 0.8nm by systematically varying their perpendicular magnetic anisotropy using controlled Cu dusting. Cu dusting was done separately above and below the cobalt layer in order to understand the role of bottom and top Pt layers in magnetization reversal mechanisms of sputtered Pt/Co/Pt stack. The introduction of even 0.3nm thick Cu layer below the cobalt layer drastically affected the perpendicular magnetic anisotropy as evident from the nucleation behavior. On the contrary, even a 4nm thick top Cu layer had little effect on the reversal mechanism. These observations along with magnetization data was used to estimate the role of top and bottom Pt in the origin of perpendicular magnetic anisotropy as well as magnetization switching mechanism in Pt/Co/Pt thin films. Also, with an increase in the bottom Cu dusting from 0.2 to 0.4nm there was an increase in the number of nucleation sites resulting in the transformation of domain wall patterns from a smooth interface type to a finger like one and finally to maze type.

  8. Copper dusting effects on perpendicular magnetic anisotropy in Pt/Co/Pt tri-layers

    Science.gov (United States)

    Parakkat, Vineeth Mohanan; Ganesh, K. R.; Anil Kumar, P. S.

    2016-05-01

    The effect of Cu dusting on perpendicular magnetic anisotropy of sputter grown Pt/Co/Pt stack in which the Cu layer is in proximity with that of Co is investigated in this work. We used magneto optic Kerr effect microscopy measurements to study the variation in the reversal mechanisms in films with Co thicknesses below 0.8nm by systematically varying their perpendicular magnetic anisotropy using controlled Cu dusting. Cu dusting was done separately above and below the cobalt layer in order to understand the role of bottom and top Pt layers in magnetization reversal mechanisms of sputtered Pt/Co/Pt stack. The introduction of even 0.3nm thick Cu layer below the cobalt layer drastically affected the perpendicular magnetic anisotropy as evident from the nucleation behavior. On the contrary, even a 4nm thick top Cu layer had little effect on the reversal mechanism. These observations along with magnetization data was used to estimate the role of top and bottom Pt in the origin of perpendicular magnetic anisotropy as well as magnetization switching mechanism in Pt/Co/Pt thin films. Also, with an increase in the bottom Cu dusting from 0.2 to 0.4nm there was an increase in the number of nucleation sites resulting in the transformation of domain wall patterns from a smooth interface type to a finger like one and finally to maze type.

  9. Magneto-optical properties for antiferromagnetically coupled CoPt stacked films with hexagonal anti-dot lattices

    Science.gov (United States)

    Yamane, Haruki; Kobayashi, Masanobu

    2014-01-01

    The influence of two-dimensional array structures (hexagonal anti-dot lattices) on magneto-optical (MO) properties was investigated in perpendicular antiferromagnetically coupled Co80Pt20 stacked films containing ZnO optical interference layers. Antiferromagnetic exchange coupling was generated in a [CoPt/Ru/CoPt] tri-layered structure, and anti-dot lattices were formed on both CoPt layers. The exchange coupling between the CoPt layers across a very thin 0.46-nm Ru interlayer was maintained even after nanofabrication. Characteristic MO hysteresis loops were measured by a 405-nm wavelength incident light on samples containing a 50-nm ZnO optical interference layer. The anti-dot lattice with a 200-nm diameter hole exhibited an increase in the residual Kerr rotation angle owing to the antiparallel magnetization alignment of the CoPt layers. Furthermore, compared with samples without the interference layer, the figure of merit for the anti-dot lattice with a 200-nm diameter hole was enhanced by inserting a 100-nm ZnO interference layer. These improvements are attributed to MO interference effects inside the stacked films.

  10. Properties of RF-Sputtered PZT Thin Films with Ti/Pt Electrodes

    Directory of Open Access Journals (Sweden)

    Cui Yan

    2014-01-01

    Full Text Available Effect of annealing temperature and thin film thickness on properties of Pb(Zr0.53Ti0.47O3 (PZT thin film deposited via radiofrequency magnetron sputtering technique onto Pt/Ti/SiO2/Si substrate was investigated. Average grain sizes of the PZT thin film were measured by atomic force microscope; their preferred orientation was studied through X-ray diffraction analysis. Average residual stress in the thin film was estimated according to the optimized Stoney formula, and impedance spectroscopy characterization was performed via an intelligent LCR measuring instrument. Average grain sizes of PZT thin films were 60 nm~90 nm and their average roughness was less than 2 nm. According to X-ray diffraction analysis, 600°C is the optimal annealing temperature to obtain the PZT thin film with better crystallization. Average residual stress showed that thermal mismatch was the decisive factor of residual stress in Pt/Ti/SiO2/Si substrate; the residual stress in PZT thin film decreased as their thickness increased and increased with annealing temperature. The dielectric constant and loss angle tangent were extremely increased with the thickness of PZT thin films. The capacitance of the device can be adjusted according to the thickness of PZT thin films.

  11. Comparative study on systems of residual water treatment in the process industry by evaporation, using fossils fuels or solar energy; Estudio comparativo sobre sistemas de tratamiento de aguas residuales de la industria de procesamiento por evaporacion, utilizando combustibles fosiles o energia solar

    Energy Technology Data Exchange (ETDEWEB)

    Landgrave Romero, Julio; Canseco Contreras, Jose [Facultad de Quimica, UNAM (Mexico)

    1996-07-01

    The residual water treatment of the process industry, nowadays is an imminent necessity in our country. In the present study two different forms are considered to concentrate residual waters: multiple effect evaporation and solar evaporation. The use of solar evaporation lagoons is a good possibility to conserving energy by means of the diminution of fossil fuel consumption. The design basis of the evaporation systems via multiple effect, as well as solar evaporation, the results of the respective sizing and the estimation of the corresponding costs are presented. A practical case is described on the cooking of cotton linters (flock) [Spanish] El tratamiento de aguas residuales de la industria de proceso, hoy en dia es una necesidad inminente en nuestro pais. En el presente trabajo se consideran dos formas distintas para concentrar las aguas residuales: evaporacion de multiple efecto y evaporacion solar. El empleo de lagunas de evaporacion solar es una buena posibilidad para conseguir el ahorro de energia mediante disminucion del consumo de combustibles fosiles. Se presentan las bases de diseno de los sistemas de evaporacion via multiple efecto, asi como solar, los resultados del dimensionamiento respectivo y la estimacion de los costos correspondientes. Se describe un caso practico sobre el cocido de linters de algodon (borra)

  12. In situ construction of Ir@Pt/C nanoparticles in the cathode layer of membrane electrode assemblies with ultra-low Pt loading and high Pt exposure

    Science.gov (United States)

    Dang, Dai; Zhang, Lei; Zeng, Xiaoyuan; Tian, Xinlong; Qu, Chong; Nan, Haoxiong; Shu, Ting; Hou, Sanying; Yang, Lijun; Zeng, Jianhuang; Liao, Shijun

    2017-07-01

    A novel membrane electrode assemblies (MEAs) with ultra-low Pt loadings and high Pt exposure in the cathode layer is prepared by spraying Ir/C catalyst ink on the membrane surface to form a substrate layer, followed by in situ pulse electrochemical deposition of a Pt shell layer on the Ir core nanoparticles in the substrate layer. It makes the Pt loadings on cathode lower to 0.044 mg/cm2. In our system, the MEA with our novel cathode exhibits excellent performance in a H2/air single fuel cell, which is comparable to that of the MEA prepared with commercial Pt/C catalyst (Johnson Matthey 40% Pt) with Pt loadings of 0.1 mg/cm2. The electrode with core-shell structured catalysts is characterized by X-ray diffraction, X-ray photoelectron spectroscopy, EDS line-scan, and scanning transmission electron microscopy. Based on the characterization results, it is found that the Pt is highly dispersed on the Ir NPs, and the electronic feature of Pt at shell layer can be tuned by the Ir core particle. Furthermore, the DFT calculation results also reveal the interaction between Pt at shell layer and Ir core. This work may provide a novel pathway to realize low Pt and high Pt utilization in low temperature fuel cells.

  13. Analisa Pengelolaan Modal Kerja pada Perusahaan Industri Semen

    Directory of Open Access Journals (Sweden)

    Engelwati Gani

    2011-04-01

    Full Text Available The purpose of this research is to identify financial ratios, to analyse the relation among the financial ratios, and to compare financial ratios of PT Indocement Tunggal Prakarsa, Tbk., PT Semen Gresik (Persero, Tbk., dan PT Holcim Indonesia, Tbk. The research method is qualitative, descriptive research, with the research time dimension using time series. The research depth is using the three industrial cement companies that listed in Indonesia Stock Exchange (BEJ. The gathering data method is by indirect contact like archive data.

  14. Analisa Pengelolaan Modal Kerja pada Perusahaan Industri Semen

    Directory of Open Access Journals (Sweden)

    Engelwati Gani

    2011-05-01

    Full Text Available The purpose of this research is to identify financial ratios, to analyse the relation among the financial ratios, and to compare financial ratios of PT Indocement Tunggal Prakarsa, Tbk., PT Semen Gresik (Persero, Tbk., dan PT Holcim Indonesia, Tbk. The research method is qualitative, descriptive research, with the research time dimention using time series. The research depth is using the three industrial cement companies that listed in Indonesia Stock Exchange (BEJ. The gathering data method is by indirect contact like archive data. 

  15. Experimental demonstration of PT-symmetric stripe lasers

    CERN Document Server

    Gu, Zhiyuan; Lyu, Quan; Li, Meng; Xiao, Shumin; Song, Qinghai

    2015-01-01

    Recently, the coexistence of parity-time (PT) symmetric laser and absorber has gained tremendous research attention. While the PT symmetric absorber has been observed in microwave metamaterials, the experimental demonstration of PT symmetric laser is still absent. Here we experimentally study PT-symmetric laser absorber in stripe waveguide. Using the concept of PT symmetry to exploit the light amplification and absorption, PT-symmetric laser absorbers have been successfully obtained. Different from the single-mode PT symmetric lasers, the PT-symmetric stripe lasers have been experimentally confirmed by comparing the relative wavelength positions and mode spacing under different pumping conditions. When the waveguide is half pumped, the mode spacing is doubled and the lasing wavelengths shift to the center of every two initial lasing modes. All these observations are consistent with the theoretical predictions and confirm the PT-symmetry breaking well.

  16. Evaluating the Training, Responsibilities, and Practices of P&T Committee Members and Nonmember Contributors.

    Science.gov (United States)

    Rodriguez, Ryan; Kelly, Brett J; Moody, Mary

    2017-08-01

    use any criteria for author selection. When authoring documents, primary literature was routinely consulted by 89.5% of the respondents. Most of the respondents (84.1%) used an organization-specific document template, while 5.8% of the respondents indicated that they prepared documents with no defined process. The most highly ranked factor that could have a perceived beneficial effect on P&T committee functions were guidelines on the authoring and reviewing of P&T committee documents. The survey of P&T committee members and nonmember contributors used in this study identified current training, responsibilities, and practices that can inform recommendations for standards in these domains. Findings suggest opportunities for improvement in achieving best practice recommendations to ensure evidence-based decision making by P&T committees. No outside funding supported this study. At the time of this study, Kelly was employed by Global Account Management Group (GAMG), which provides consulting services to the hospital and health services industry. As an employee of GAMG, Kelly has served on various advisory boards. All fees for consulting work were paid to GAMG and were primarily related to training or the federal market (e.g., Department of Defense or the Department of Veterans Affairs) and have no association with this study. Rodriguez and Moody report no conflicts of interest. All authors contributed to study concept and design. Rodriguez took the lead in data collection, assisted by the other authors. Data interpretation was performed by Rodriguez, along with Kelly and Moody. The manuscript was written and revised primarily by Rodriguez, along with the other authors.

  17. Electrodeposition and electrocatalytic activity of Pt and Pt-alloy nanoparticles and thin films on highly oriented pyrolytic graphite (HOPG)

    Science.gov (United States)

    Lu, Guojin

    Pt and Pt-based alloy catalysts were synthesized by electrodeposition on HOPG. The nucleation and growth, morphology, composition and crystal structure, and electrocatalytic activity (towards relevant reactions in the frame of PEMFCs and DMFCs) of these model electrodes were systematically investigated. The presence of chlorides inhibits the Pt reduction processes. There is a transition from progressive to instantaneous nucleation with increasing overpotential for the deposition from 1 mM H2PtCl6 electrolytes. The possibility of instantaneous nucleation at large overpotential by using electrolytes with large chloride concentration is advantageous for the growth of small, well dispersed nanoparticles. The electrochemical data were confirmed by AFM and SEM imaging studies. Relatively narrow size distributed nanoparticles can be obtained from the current system. While MOR activity decreases with decreasing particle size, the HER and HOR activity of deposited Pt particles increases with decreasing deposition period. The ORR activity first increases then decreases with increasing deposition time. Interactions between Pt and Ru, or Ni or Co are observed and they form solid solution as verified by XRD. Underpotential deposition occurs for Pt-Ni or Pt-Co co-electrodeposition. Pt-Ru deposition can be described as progressive nucleation at low overpotential and instantaneous nucleation at high overpotentials. Through direct morphological observations, the Pt-Ni or Pt-Co nucleation can be approximately described as progressive. Pt-Ru deposits are superior to Pt towards MOR. The optimum Ru content is about 50 at.%. Pt-Ni and Pt-Co deposits are more active than Pt for ORR. The optimum content is about 30 at.% Ni or 50 at.% Co. Dealloying of Pt-Ru and Pt-Ni or Pt-Co electrodeposit is observed after electrochemical characterization. The extent of dealloying increases with the content of the alloying element.

  18. Development and structural characterization of exchange-spring-like nanomagnets in (Fe,Co)-Pt bulk nanocrystalline alloys

    Science.gov (United States)

    Crisan, O.; Crisan, A. D.; Mercioniu, I.; Nicula, R.; Vasiliu, F.

    2016-03-01

    Curie temperature of about 820 K (close to 550 °C) is reported for the Fe35Co15Pt50 alloy which opens wide possibilities for the use of such magnets in high operating temperature industrial applications. The present results indicate that ternary FeCoPt alloys hold a great potential as a novel class of rare earth free exchange-spring coupled nanocomposite magnets.

  19. Surface Chemistry of Aromatic Reactants on Pt- and Mo-Modified Pt Catalysts

    Energy Technology Data Exchange (ETDEWEB)

    Robinson, Allison M.; Mark, Lesli; Rasmussen, Mathew J.; Hensley, Jesse E.; Medlin, J. Will

    2016-11-01

    Supported catalysts containing an oxophilic metal such as Mo and a noble metal such as Pt have shown promising activity and selectivity for deoxygenation of biomass-derived compounds. Here, we report that PtMo catalysts also promote hydrogenolysis of the model compound benzyl alcohol, while decarbonylation is most prevalent over unmodified Pt. A combination of single crystal surface science studies, density functional theory (DFT) calculations, and vapor phase upgrading experiments using supported catalysts was carried out to better understand the mechanism by which Mo promotes deoxygenation. Molybdenum was deposited in submonolayer quantities on a Pt(111) surface and reduced at high temperature. Temperature-programmed desorption (TPD) experiments using benzyl alcohol as a reactant showed greatly enhanced yields of the deoxygenation product toluene at moderate Mo coverages. To understand how the interaction of the aromatic group with the surface influenced this reactivity, we investigated the adsorption of toluene as a probe molecule. We found that the addition of Mo to Pt(111) resulted in a significant decrease in toluene decomposition. DFT calculations indicated that this decrease was consistent with decreased aromatic adsorption strengths that accompany incorporation of Mo into the Pt subsurface. The weaker aromatic-surface interaction on Pt/Mo surfaces led to a tilted adsorption geometry for benzyl alcohol, which presumably promotes hydrogenolysis to produce toluene instead of decarbonylation to produce benzene and CO. Alumina-supported Pt and PtMo catalysts were also tested for benzyl alcohol deoxygenation. PtMo catalysts had a higher rate of toluene production and lower rates of benzene and benzaldehyde production. Additionally, when benzaldehyde was used as the reactant to measure decarbonylation activity the mass-normalized rate of benzene production was 2.5 times higher on Pt than PtMo. Overall, the results of TPD, DFT, and supported catalyst experiments

  20. An anodic alumina supported Ni-Pt bimetallic plate-type catalysts for multi-reforming of methane, kerosene and ethanol

    KAUST Repository

    Zhou, Lu

    2014-05-01

    An anodic alumina supported Ni-Pt bimetallic plate-type catalyst was prepared by a two-step impregnation method. The trace amount 0.08 wt% of Pt doping efficiently suppressed the nickel particle sintering and improved the nickel oxides reducibility. The prepared Ni-Pt catalyst showed excellent performance during steam reforming of methane, kerosene and ethanol under both 3000 h stationary and 500-time daily start-up and shut-down operation modes. Self-activation ability of this catalyst was evidenced, which was considered to be resulted from the hydrogen spillover effect over Ni-Pt alloy. In addition, an integrated combustion-reforming reactor was proposed in this study. However, the sintering of the alumina support is still a critical issue for the industrialization of Ni-Pt catalyst. Copyright © 2014, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.

  1. Industrial Engineering

    DEFF Research Database (Denmark)

    Karlsson, Christer

    2015-01-01

    Industrial engineering is a discipline that is concerned with increasing the effectiveness of (primarily) manufacturing and (occasionally).......Industrial engineering is a discipline that is concerned with increasing the effectiveness of (primarily) manufacturing and (occasionally)....

  2. Preparation and characterization of Fe{sub 3}O{sub 4}-Pt nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Andrade, Ângela Leão, E-mail: angelala01@hotmail.com [Federal University of Ouro Preto (UFOP), Department of Chemistry, ICEB (Brazil); Cavalcante, Luis Carlos Duarte [Federal University of Piauí (UFPI), Center of Natural Sciences (Brazil); Fabris, José Domingos [Federal University of Minas Gerais (UFMG), Department of Chemistry, ICEx (Brazil); Pereira, Márcio César [Federal University of the Jequitinhonha and Mucuri Valleys (UFVJM), Institute of Science, Engineering and Technology (Brazil); Ardisson, José Domingos [Center for the Development of the Nuclear Technology (CDTN), Laboratory of Applied Physics (Brazil); Domingues, Rosana Zacarias [Federal University of Minas Gerais (UFMG), Department of Chemistry, ICEx (Brazil)

    2017-11-15

    Pt and Pt-based nanomaterials are active anticancer drugs for their ability to inhibit the division of living cells. Nanoparticles of magnetite containing variable proportions of platinum were prepared in the laboratory. The magnetite nanoparticles with platinum (Pt-Fe{sub 3}O{sub 4}) were obtained by reducing the Fe{sup 3+} of the maghemite (γ Fe{sub 2}O{sub 3}) mixed with platinum (II) acetylacetonate and sucrose in two inversely coupled ceramic crucibles and heated in a furnace at 400 °C for 20 min. The formed carbon during this preparation acts to chemically reduce the ferric iron in maghemite. Moreover, its residual layer on the particle surface prevents the forming magnetite from oxidizing in air and helps retain the platinum in the solid mixture. The produced Pt-magnetite samples were characterized by {sup 57}Fe-Mössbauer spectroscopy, powder X-ray diffraction, scanning electron microscopy, and magnetization measurements. Measurements of AC magnetic-field-induced heating properties of the obtained nanocomposites, in aqueous solution, showed that they are suitable as a hyperthermia agent for biological applications.

  3. Relaxor-PT Single Crystal Piezoelectric Sensors

    Directory of Open Access Journals (Sweden)

    Xiaoning Jiang

    2014-07-01

    Full Text Available Relaxor-PbTiO3 piezoelectric single crystals have been widely used in a broad range of electromechanical devices, including piezoelectric sensors, actuators, and transducers. This paper reviews the unique properties of these single crystals for piezoelectric sensors. Design, fabrication and characterization of various relaxor-PT single crystal piezoelectric sensors and their applications are presented and compared with their piezoelectric ceramic counterparts. Newly applicable fields and future trends of relaxor-PT sensors are also suggested in this review paper.

  4. MICRONUTRIENTS IN SOIL IRRIGATED OF WASTE WATER SERVED AND THE SUGAR CANE FERTILIZED WITH ORGANIC AND INDUSTRIAL RESIDUES = MICRONUTRIENTES NO SOLO IRRIGADO COM ÁGUA SERVIDA E NA PLANTA DE CANA-DE-AÇÚCAR FERTILIZADA COM RESÍDUOS ORGÂNICOS E INDUSTRIAIS

    Directory of Open Access Journals (Sweden)

    Fabio Olivieri de Nobile

    2013-01-01

    Full Text Available Population growth, with consequent demands for consumer goods and increased industrial development generate significant amounts of waste and increase the indiscriminate use of water. The environmental impact caused by the improper disposal of waste in the environment, causes great difficulty to control, implying high costs in its remediation. The agricultural use of organic and industrial residues is an alternative of exploitation with fertilization and source organic matter to the soil. In this direction, the objective of this research was to evaluate the use of the urban solid waste and biofertilizer as nutrient source, and residue of the bauxite processing as agricultural liming materials of the soil, irrigated with potable water and wastewater. The experiment was conducted in vase was lead, under soil Alfisol, being evaluated the micronutrient concentrations in the soil and leaves of sugar cane (Cu, Fe, Mn and Zn. The gotten data had evidenced the fertilization with biofertilizer increased texts of significantly Cu and Zn in the soil (409% e 520% mg.dm-3, respectively, the application of residue of the processing of the bauxite raised the manganese concentrations, had not been observed changes for Fe. Already in sugar cane leaves the use of residue of the processing the sugar cane raised texts of all the micronutrients, the application of biofertilizer and made up of urban solid waste raised texts of Cu in leaves (0.80 and 1.00 mg.dm-3 respectively however had a reduction of the text of Mn (124.66 and 84.66 mg.dm-3 respectively. The quality of irrigation water, drinking or served, did not influence the micronutrients concentrated in the soil as well as the contents of these elements in the plant. = O crescimento populacional, com as consequentes demandas por bens de consumo, e o aumento do desenvolvimento industrial geram quantidades expressivas de resíduos e aumento do uso indiscriminado de água. O impacto ambiental originado pela disposi

  5. Ion-irradiation induced chemical ordering of FePt and FePtAu nanoparticles

    Science.gov (United States)

    Seetala, Naidu V.; Harrell, J. W.; Lawson, Jeremy; Nikles, David E.; Williams, John R.; Isaacs-Smith, Tamara

    2005-12-01

    We have studied the effect of ion-beam irradiation on reducing the ordering temperature of FePt and FePtAu nanoparticles. FePt and FePt(Au14%) 4 nm particles dispersed on a Si-substrate were irradiated by 300 keV Al-ions with a dose of 1 × 1016 ions/cm2 at 43 °C using a water-cooled flange in order to minimize the vacancy migration and voids formation within the collision cascades. Partial chemical ordering has been observed in as-irradiated particles with coercivity of 60-130 Oe. Post-irradiation annealing at 220 °C enhanced chemical ordering in FePt nanoparticles with coercivity of 3500 Oe, magnetic anisotropy of 1.5 × 107 erg/cc, and thermal stability factor of 130. A much higher 375 °C post-irradiation annealing was required in FePtAu, presumably because Au atoms were trapped at Fe/Pt lattice sites at lower temperatures. As the annealing temperature increased, anomalous features in the magnetization reversal curves were observed that disappeared at higher annealing temperatures.

  6. Ion-irradiation induced chemical ordering of FePt and FePtAu nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Seetala, Naidu V. [Department of Physics, Grambling State University, RWE Jones Drive, Carver Hall 81, Grambling, LA 71245 (United States)]. E-mail: naidusv@gram.edu; Harrell, J.W. [MINT Center, University of Alabama, Tuscaloosa, AL 35487 (United States); Lawson, Jeremy [MINT Center, University of Alabama, Tuscaloosa, AL 35487 (United States); Nikles, David E. [MINT Center, University of Alabama, Tuscaloosa, AL 35487 (United States); Williams, John R. [Department of Physics, Auburn University, Auburn, AL 36849 (United States); Isaacs-Smith, Tamara [Department of Physics, Auburn University, Auburn, AL 36849 (United States)

    2005-12-15

    We have studied the effect of ion-beam irradiation on reducing the ordering temperature of FePt and FePtAu nanoparticles. FePt and FePt(Au14%) 4 nm particles dispersed on a Si-substrate were irradiated by 300 keV Al-ions with a dose of 1 x 10{sup 16} ions/cm{sup 2} at 43 {sup o}C using a water-cooled flange in order to minimize the vacancy migration and voids formation within the collision cascades. Partial chemical ordering has been observed in as-irradiated particles with coercivity of 60-130 Oe. Post-irradiation annealing at 220 {sup o}C enhanced chemical ordering in FePt nanoparticles with coercivity of 3500 Oe, magnetic anisotropy of 1.5 x 10{sup 7} erg/cc, and thermal stability factor of 130. A much higher 375 {sup o}C post-irradiation annealing was required in FePtAu, presumably because Au atoms were trapped at Fe/Pt lattice sites at lower temperatures. As the annealing temperature increased, anomalous features in the magnetization reversal curves were observed that disappeared at higher annealing temperatures.

  7. Discovery of the Pt-Based Superconductor LaPt5As.

    Science.gov (United States)

    Fujioka, Masaya; Ishimaru, Manabu; Shibuya, Taizo; Kamihara, Yoichi; Tabata, Chihiro; Amitsuka, Hiroshi; Miura, Akira; Tanaka, Masashi; Takano, Yoshihiko; Kaiju, Hideo; Nishii, Junji

    2016-08-10

    A novel superconductor, LaPt5As, which exhibits a new crystal structure was discovered by high-pressure synthesis using a Kawai-type apparatus. A superconducting transition temperature was observed at 2.6 K. Depending on the sintering pressure, LaPt5As has superconducting and non-superconducting phases with different crystal structures. A sintering pressure of around 10 GPa is effective to form single-phase superconducting LaPt5As. This material has a very unique crystal structure with an extremely long c lattice parameter of over 60 Å and corner-sharing tetrahedrons composed of network-like Pt layers. Density functional theory calculations have suggested that the superconducting current flows through these Pt layers. Also, this unique layered structure characteristic of LaPt5As is thought to play a key role in the emergence of superconductivity. Furthermore, due to a stacking structure which makes up layers, various structural modifications for the LaPt5As family are conceivable. Since such a high-pressure synthesis using a Kawai-type apparatus is not common in the field of materials science, there is large room for further exploration of unknown phases which are induced by high pressure in various materials.

  8. Tailoring Curie temperature and magnetic anisotropy in ultrathin Pt/Co/Pt films

    Directory of Open Access Journals (Sweden)

    Vineeth Mohanan Parakkat

    2016-05-01

    Full Text Available The dependence of perpendicular magnetization and Curie temperature (Tc of Pt/Co/Pt thin films on the thicknesses of Pt seed (Pts and presence of Ta buffer layer has been investigated in this work. Pt and Co thicknesses were varied between 2 to 8 nm and 0.35 to 1.31 nm (across the spin reorientation transition thickness respectively and the Tc was measured using SQUID magnetometer. We have observed a systematic dependence of Tc on the thickness of Pts. For 8nm thickness of Pts the Co layer of 0.35nm showed ferromagnetism with perpendicular anisotropy at room temperature. As the thickness of the Pts was decreased to 2nm, the Tc went down below 250K. XRD data indicated polycrystalline growth of Pts on SiO2. On the contrary Ta buffer layer promoted the growth of Pt(111. As a consequence Ta(5nm/Pt(3nm/Co(0.35nm/Pt(2nm had much higher Tc (above 300K with perpendicular anisotropy when compared to the same stack without the Ta layer. Thus we could tune the ferromagnetic Tc and anisotropy by varying the Pts thickness and also by introducing Ta buffer layer. We attribute these observations to the micro-structural evolution of Pts layer which hosts the Co layer.

  9. Electrochemical quartz crystal microbalance study of the electrodeposition of Co, Pt and Pt-Co alloy

    Energy Technology Data Exchange (ETDEWEB)

    Martin, A.J.; Chaparro, A.M. [CIEMAT, Avda. Complutense, 22, 28040 Madrid (Spain); Daza, L. [CIEMAT, Avda. Complutense, 22, 28040 Madrid (Spain); Instituto de Catalisis y Petroleoquimica (CSIC), C/Marie Curie 2, Campus Cantoblanco, 28049 Madrid (Spain)

    2007-06-10

    The electrochemical deposition of Co, Pt and Pt-Co alloy are studied with the electrochemical quartz crystal microbalance (EQCM) on a gold substrate. Co is deposited from acidic sulphate bath containing boric acid. Different processes are identified in this bath. Electrodeposition of Co on Au substrate is observed at potentials above redox potential, underpotential deposition, most probably due to formation of a Co-Au alloy. At more cathodic potentials, below -0.5 V, metallic Co is formed. The film is completely dissolved at positive potentials during the anodic scan, probably mediated by Co(OH){sub 2}. The electrodeposition of platinum from acidic PtCl{sub 6}{sup 2-} bath occurs below the thermodynamic potential (0.74 V) with almost 100% efficiency. At potentials negative from 0.0 V the efficiency decreases due to parallel water reduction. The codeposition of Co and Pt is also studied in acidic bath. Here, the decrease of pH due to water reduction on Pt deposits gives rise to precipitation of Co(OH){sub 2}, together with the deposition of metallic Pt and Co. The films contain as major component the Pt{sub 3}Co alloy. (author)

  10. Electrochemical quartz crystal microbalance study of the electrodeposition of Co, Pt and Pt-Co alloy

    Science.gov (United States)

    Martín, A. J.; Chaparro, A. M.; Daza, L.

    The electrochemical deposition of Co, Pt and Pt-Co alloy are studied with the electrochemical quartz crystal microbalance (EQCM) on a gold substrate. Co is deposited from acidic sulphate bath containing boric acid. Different processes are identified in this bath. Electrodeposition of Co on Au substrate is observed at potentials above redox potential, underpotential deposition, most probably due to formation of a Co-Au alloy. At more cathodic potentials, below -0.5 V, metallic Co is formed. The film is completely dissolved at positive potentials during the anodic scan, probably mediated by Co(OH) 2. The electrodeposition of platinum from acidic PtCl 6 2- bath occurs below the thermodynamic potential (0.74 V) with almost 100% efficiency. At potentials negative from 0.0 V the efficiency decreases due to parallel water reduction. The codeposition of Co and Pt is also studied in acidic bath. Here, the decrease of pH due to water reduction on Pt deposits gives rise to precipitation of Co(OH) 2, together with the deposition of metallic Pt and Co. The films contain as major component the Pt 3Co alloy.

  11. Mechanisms of current conduction in Pt/BaTiO{sub 3}/Pt resistive switching cell

    Energy Technology Data Exchange (ETDEWEB)

    Pan, R.K. [School of Materials Science and Engineering, Hubei University, Wuhan 430062 (China); Zhang, T.J., E-mail: tj65zhang@yahoo.com.cn [School of Materials Science and Engineering, Hubei University, Wuhan 430062 (China); Wang, J.Y.; Wang, J.Z. [School of Materials Science and Engineering, Hubei University, Wuhan 430062 (China); Wang, D.F. [School of Materials Science and Engineering, Hubei University, Wuhan 430062 (China); q-Psi and Department of Physics, Hanyang University, Seoul 133-791 (Korea, Republic of); Duan, M.G. [School of Materials Science and Engineering, Hubei University, Wuhan 430062 (China)

    2012-03-30

    The 80-nm-thickness BaTiO{sub 3} (BT) thin film was prepared on the Pt/Ti/SiO{sub 2}/Si substrate by the RF magnetron sputtering technique. The Pt/BT/Pt/Ti/SiO{sub 2}/Si structure was investigated using X-ray diffraction and scanning electron microscopy. The current-voltage characteristic measurements were performed. The bipolar resistive switching behavior was found in the Pt/BT/Pt cell. The current-voltage curves were well fitted in different voltage regions at the high resistance state (HRS) and the low resistance state (LRS), respectively. The conduction mechanisms are concluded to be Ohmic conduction and Schottky emission at the LRS, while space-charge-limited conduction and Poole-Frenkel emission at the HRS. The electroforming and switching processes were explained in terms of the valence change mechanism, in which oxygen vacancies play a key role in forming conducting paths. - Highlights: Black-Right-Pointing-Pointer Pt/BaTiO{sub 3}/Pt cell shows the bipolar resistive switching behavior. Black-Right-Pointing-Pointer The current-voltage curves were well fitted for different conduction mechanisms. Black-Right-Pointing-Pointer The electroforming and switching processes were explained.

  12. Carbon supported nanoparticles Pt Ru (Pt Ru/C electrocatalysts) prepared using electron beam irradiation; Preparacao de nanoparticulas de PtRu suportadas em carbono (eletrocatalisadores PtRu/C) utilizando feixe de eletrons

    Energy Technology Data Exchange (ETDEWEB)

    Silva, Dionisio F. da; Oliveira Neto, Almir; Pino, Eddy S.; Linardi, Marcelo; Spinace, Estevam V. [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil). Programa de Celulas a Combustivel], e-mail: espinace@ipen.br, e-mail: dfsilva@ipen.br

    2006-07-01

    Carbon-supported Pt Ru (electrocatalysts PtRu/C nanoparticles) were prepared submitting a water/ethylene glycol mixture containing Pt(IV) and Ru(III) ions and the carbon support to electron beam irradiation. The PtRu/C electrocatalysts were characterized by EDX, XRD and cyclic voltammetry and tested for methanol electro-oxidation aiming fuel cell application. The obtained PtRu/C electrocatalysts were more active for methanol electro-oxidation than the commercial PtRu/C ETEK electrocatalyst at ambient temperature. (author)

  13. Resistive random access memory utilizing ferritin protein with Pt nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Uenuma, Mutsunori; Kawano, Kentaro; Zheng Bin; Okamoto, Naofumi; Horita, Masahiro; Yoshii, Shigeo; Yamashita, Ichiro; Uraoka, Yukiharu, E-mail: uenuma@ms.naist.jp [Nara Institute of Science and Technology, 8916-5, Takayama, Ikoma, Nara 630-0192 (Japan)

    2011-05-27

    This study reports controlled single conductive paths found in resistive random access memory (ReRAM) formed by embedding Pt nanoparticles (Pt NPs) in NiO film. Homogeneous Pt NPs produced and placed by ferritin protein produce electric field convergence which leads to controlled conductive path formation. The ReRAM with Pt NPs shows stable switching behavior. A Pt NP density decrease results in an increase of OFF state resistance and decrease of forming voltage, whereas ON resistance was independent of the Pt NP density, which indicates that a single metal NP in a memory cell will achieve low power and stable operation.

  14. Carbon supported nanoparticles Pt Ru (Pt Ru/C electrocatalysts) prepared using electron beam irradiation; Preparacao de nanoparticulas de PtRu suportadas em carbono (eletrocatalisadores PtRu/C) utilizando feixe de eletrons

    Energy Technology Data Exchange (ETDEWEB)

    Silva, Dionisio F. da; Oliveira Neto, Almir; Pino, Eddy S.; Linardi, Marcelo; Spinace, Estevam V. [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil). Programa de Celulas a Combustivel], e-mail: espinace@ipen.br, e-mail: dfsilva@ipen.br

    2006-07-01

    Carbon-supported Pt Ru (electrocatalysts PtRu/C nanoparticles) were prepared submitting a water/ethylene glycol mixture containing Pt(IV) and Ru(III) ions and the carbon support to electron beam irradiation. The PtRu/C electrocatalysts were characterized by EDX, XRD and cyclic voltammetry and tested for methanol electro-oxidation aiming fuel cell application. The obtained PtRu/C electrocatalysts were more active for methanol electro-oxidation than the commercial PtRu/C ETEK electrocatalyst at ambient temperature. (author)

  15. Multifunctional Pt(II) Reagents: Covalent Modifications of Pt Complexes Enable Diverse Structural Variation and In-Cell Detection.

    Science.gov (United States)

    White, Jonathan D; Haley, Michael M; DeRose, Victoria J

    2016-01-19

    To enhance the functionality of Pt-based reagents, several strategies have been developed that utilize Pt compounds modified with small, reactive handles. This Account encapsulates work done by us and other groups regarding the use of Pt(II) compounds with reactive handles for subsequent elaboration with fluorophores or other functional moieties. Described strategies include the incorporation of substituents for well-known condensation or nucleophilic displacement-type reactions and their use, for example, to tether spectroscopic handles to Pt reagents for in vivo investigation. Other chief uses of displacement-type reactions have included tethering various small molecules exhibiting pharmacological activity directly to Pt, thus adding synergistic effects. Click chemistry-based ligation techniques have also been applied, primarily with azide- and alkyne-appended Pt complexes. Orthogonally reactive click chemistry reactions have proven invaluable when more traditional nucleophilic displacement reactions induce side-reactivity with the Pt center or when systematic functionalization of a larger number of Pt complexes is desired. Additionally, a diverse assortment of Pt-fluorophore conjugates have been tethered via click chemistry conjugation. In addition to providing a convenient synthetic path for diversifying Pt compounds, the use of click-capable Pt complexes has proved a powerful strategy for postbinding covalent modification and detection with fluorescent probes. This strategy bypasses undesirable influences of the fluorophore camouflaged as reactivity due to Pt that may be present when detecting preattached Pt-fluorophore conjugates. Using postbinding strategies, Pt reagent distributions in HeLa and lung carcinoma (NCI-H460) cell cultures were observed with two different azide-modified Pt compounds, a monofunctional Pt(II)-acridine type and a difunctional Pt(II)-neutral complex. In addition, cellular distribution was observed with an alkyne-appended difunctional

  16. Pt Skin Versus Pt Skeleton Structures of Pt3Sc as Electrocatalysts for Oxygen Reduction

    DEFF Research Database (Denmark)

    Johansson, Tobias Peter; Ulrikkeholm, Elisabeth Therese; Hernandez-Fernandez, Patricia

    2014-01-01

    In order for low temperature polymer electrolyte membrane fuel cells to become economically viable Pt catalyst loading must be significantly reduced. The cathode of the polymer electrolyte membrane fuel cell, where oxygen reduction takes place, is responsible for the main activity loss. The devel...

  17. Pt-Pd nanoelectrocatalyst of ultralow Pt content for the oxidation of formic acid: Towards tuning the reaction pathway

    Indian Academy of Sciences (India)

    Sourov Ghosh; C Retna Raj

    2015-05-01

    Synthesis of highly efficient functional electrocatalyst that favours the electrochemical oxidation of formic acid via CO-free dehydrogenation pathway is required for direct formic acid fuel cells. Traditional catalysts favour the dehydration pathway involving the generation of poisonous CO. Herein we demonstrate the superior electrocatalytic performance of Pt-Pd bimetallic nanoelectrocatalyst of ultralow Pt content and tuning the reaction pathway by controlling the Pt content. Bimetallic nanoparticles of Pt4Pd96, Pt7Pd93 and Pt47Pd53 compositions are synthesized by electrochemical co-deposition method in aqueous solution. The nanoparticles of ultralow Pt content, Pt4Pd96, favour the CO-free dehydrogenation pathway for formic acid oxidation with an onset potential of 0 V (SHE) whereas the Pt47Pd53 nanoparticles favour the dehydration pathway involving the formation of CO at high positive potential. The Pt content of the bimetallic nanoparticles actually controls the oxidation peak potential and catalytic activity. Significant negative shift (∼350 mV) in the oxidation peak potential and remarkable enhancement in the current density (2.6 times) are observed for Pt4Pd96 nanoparticles with respect to Pt47Pd53. The absence of three adjacent Pt and Pd atoms could be the reason for the suppression of CO pathway. The electrochemical impedance measurements indirectly support the CO-free pathway for the formic acid oxidation on Pt4Pd96 nanoparticles.

  18. Pt-Ni and Pt-Co Catalyst Synthesis Route for Fuel Cell Applications

    Science.gov (United States)

    Firdosy, Samad A.; Ravi, Vilupanur A.; Valdez, Thomas I.; Kisor, Adam; Narayan, Sri R.

    2013-01-01

    Oxygen reduction reactions (ORRs) at the cathode are the rate-limiting step in fuel cell performance. The ORR is 100 times slower than the corresponding hydrogen oxidation at the anode. Speeding up the reaction at the cathode will improve fuel cell efficiency. The cathode material is generally Pt powder painted onto a substrate (e.g., graphite paper). Recent efforts in the fuel cell area have focused on replacing Pt with Pt-X alloys (where X = Co, Ni, Zr, etc.) in order to (a) reduce cost, and (b) increase ORR rates. One of these strategies is to increase ORR rates by reducing the powder size, which would result in an increase in the surface area, thereby facilitating faster reaction rates. In this work, a process has been developed that creates Pt-Ni or Pt-Co alloys that are finely divided (on the nano scale) and provide equivalent performance at lower Pt loadings. Lower Pt loadings will translate to lower cost. Precursor salts of the metals are dissolved in water and mixed. Next, the salt mixtures are dried on a hot plate. Finally, the dried salt mixture is heattreated in a furnace under flowing reducing gas. The catalyst powder is then used to fabricate a membrane electrode assembly (MEA) for electrochemical performance testing. The Pt- Co catalyst-based MEA showed comparable performance to an MEA fabri cated using a standard Pt black fuel cell catalyst. The main objective of this program has been to increase the overall efficiencies of fuel cell systems to support power for manned lunar bases. This work may also have an impact on terrestrial programs, possibly to support the effort to develop a carbon-free energy source. This catalyst can be used to fabricate high-efficiency fuel cell units that can be used in space as regenerative fuel cell systems, and terrestrially as primary fuel cells. Terrestrially, this technology will become increasingly important when transition to a hydrogen economy occurs.

  19. Heterobimetallic lantern complexes that couple antiferromagnetically through noncovalent Pt···Pt interactions.

    Science.gov (United States)

    Baddour, Frederick G; Fiedler, Stephanie R; Shores, Matthew P; Golen, James A; Rheingold, Arnold L; Doerrer, Linda H

    2013-05-01

    A series of Pt-based heterobimetallic lantern complexes of the form [PtM(SAc)4(OH2)] (M = Co, 1; Ni, 2; Zn, 3) were prepared using a facile, single-step procedure. These hydrated species were reacted with 3-nitropyridine (3-NO2py) to prepare three additional lantern complexes, [PtM(SAc)4(3-NO2py)] (M = Co, 4; Ni, 5; Zn, 6), or alternatively dried in vacuo to the dehydrated species [PtM(SAc)4] (M = Co, 7; Ni, 8; Zn, 9). The Co- and Ni-containing species exhibit Pt-M bonding in solution and the solid state. In the structurally characterized compounds 1-6, the lantern units form dimers in the solid state via a short Pt···Pt metallophilic interaction. Antiferromagnetic coupling between 3d metal ions in the solid state through noncovalent metallophilic interactions was observed for all the paramagnetic lantern complexes prepared, with J-coupling values of -12.7 cm(-1) (1), -50.8 cm(-1) (2), -6.0 cm(-1) (4), and -12.6 cm(-1) (5). The Zn complexes 3 and 6 also form solid-state dimers, indicating that the formation of short Pt···Pt interactions in these complexes is not predicated on the presence of a paramagnetic 3d metal ion. These contacts and the resultant antiferromagnetic coupling are also not unique to heterobimetallic lantern complexes with axially coordinated H2O or the previously reported thiobenzoate supporting ligand.

  20. Disentangling interface and bulk contributions to the anisotropic magnetoresistance in Pt/Co/Pt sandwiches

    Science.gov (United States)

    Kobs, André; Oepen, Hans Peter

    2016-01-01

    We report on interfacial contributions to the anisotropic magnetoresistance (AMR) in Co layers sandwiched between Pt. Utilizing the Fuchs-Sondheimer formalism interface contributions can be separated from bulklike AMR. We demonstrate that for all-metal systems interfacial AMR is also present when varying the magnetization within the film plane. This interfacial in-plane AMR is two times smaller than the contribution that arises when the magnetization is varied within the plane perpendicular to the current direction. This finding is in contrast to the spin Hall MR found for ferromagnetic insulator/Pt bilayers revealing the existence of different MR effects at the interfaces of Pt with conducting and insulating ferromagnets.

  1. Pt/MOx/SiO2, Pt/MOx/TiO2, and Pt/MOx/Al2O3 Catalysts for CO Oxidation

    Directory of Open Access Journals (Sweden)

    Hongmei Qin

    2015-04-01

    Full Text Available Conventional supported Pt catalysts have often been prepared by loading Pt onto commercial supports, such as SiO2, TiO2, Al2O3, and carbon. These catalysts usually have simple metal-support (i.e., Pt-SiO2 interfaces. To tune the catalytic performance of supported Pt catalysts, it is desirable to modify the metal-support interfaces by incorporating an oxide additive into the catalyst formula. Here we prepared three series of metal oxide-modified Pt catalysts (i.e., Pt/MOx/SiO2, Pt/MOx/TiO2, and Pt/MOx/Al2O3, where M = Al, Fe, Co, Cu, Zn, Ba, La for CO oxidation. Among them, Pt/CoOx/SiO2, Pt/CoOx/TiO2, and Pt/CoOx/Al2O3 showed the highest catalytic activities. Relevant samples were characterized by N2 adsorption-desorption, X-ray diffraction (XRD, transmission electron microscopy (TEM, H2 temperature-programmed reduction (H2-TPR, X-ray photoelectron spectroscopy (XPS, CO temperature-programmed desorption (CO-TPD, O2 temperature-programmed desorption (O2-TPD, and CO2 temperature-programmed desorption (CO2-TPD.

  2. Optimized Combination of Residue Hydrodesulfurization and Residue Fluid Catalytic Cracking

    Institute of Scientific and Technical Information of China (English)

    Chen Junwu

    2003-01-01

    @@1 Introduction Combination of residue hydrodesulfurization (HDS) and resi-due fluid catalytic cracking (RFCC) is a unique technologyfor processing high-sulfur residue. This paper discusses theoptimized combination of these two processes.

  3. Robust Pt1000 temperature sensor for cryogenic applications in the process measurement technology; Robuste Pt1000-Temperaturfuehler fuer kryogene Anwendungen in der Prozessmesstechnik

    Energy Technology Data Exchange (ETDEWEB)

    Ramalingam, Rajini Kumar; Langhans, Oliver; Suesser, Manfred [Karlsruher Institut fuer Technologie (KIT), Eggenstein-Leopoldshafen (Germany). Inst. fuer Technische Physik (ITEP)

    2012-07-01

    The process measurement technology has a great demand for robust temperature sensors for temperatures between 20 and 500 K. The field of application is for example the hydrogen technology or the utilization of neon for the cooling of high temperature superconductors. Pt1000 temperature sensors with a shell conductor are investigated for this large range of temperatures in the calibration laboratory of the Institute for Technical Physics (Eggenstein-Leopoldshafen, Federal Republic of Germany). The Pt1000 temperature sensors were supplied by the manufacturer. The specific characteristic lines of 21 temperature sensors were determined. Furthermore, the thermal stability was investigated by means of multiple temperature cycles between 78 and 525 K. The contribution under consideration presents the investigations of this institute in detail and discusses the measurement results with regard to the industrial process measurement technology.

  4. PT L 3 near edge structure of halogen-bridged mixed-valence pt complexes and pd-pt mixed-metal complexes

    Science.gov (United States)

    Tanino, H.; Oyanagi, H.; Yamashita, M.; Kobayashi, K.

    1985-03-01

    X-ray absorption near edge structure (XANES) of halogen-bridged mixed-valence Pt complexes and halogen-bridged Pd-Pt mixed-metal complexes have been measured using synchrotron radiation with a high energy resolution. In Pd-Pt mixed metal complexes, we demonstrate that the degree of the valence is estimated from the intensity of the white line at the Pt L 3 edge. In the mixed-valence complexes, the electron system is proved to be the Peierls insulator with a charge density wave of renormalized d electrons of Pt, where the total valence of Pt IV- and Pt 11 is conserved without excess electrons from ligands or anions.

  5. PENGARUH STRES DALAM PEKERJAAN TERHADAP KINERJA KARYAWAN: STUDI KASUS DI PERUSAHAAN AGRIBISNIS PT NIC

    Directory of Open Access Journals (Sweden)

    Arif Imam Suroso

    2011-08-01

    Full Text Available Normal 0 false false false MicrosoftInternetExplorer4 /* Style Definitions */ table.MsoNormalTable {mso-style-name:"Table Normal"; mso-tstyle-rowband-size:0; mso-tstyle-colband-size:0; mso-style-noshow:yes; mso-style-parent:""; mso-padding-alt:0cm 5.4pt 0cm 5.4pt; mso-para-margin:0cm; mso-para-margin-bottom:.0001pt; mso-pagination:widow-orphan; font-size:10.0pt; font-family:"Times New Roman"; mso-ansi-language:#0400; mso-fareast-language:#0400; mso-bidi-language:#0400;} This study was aimed at finding out the existence of stress in work towards employees’ performance, and knowing the indicators of each shaper element of that influencing the employees’ performance of plant department of agribusiness industry at PT. NIC. The method of this study is case study involving 155 respondents. Using the Structural Equation Modelling (SEM, it is known that the influence of stress in work towards employees’ performance is significantly negative. It means that the advance of stress in work can take the employees’ performance down. The advance of stress in work was stimulated by stressor, in this case are job pressure and lack of support. The relationship between stressor and stress in work is positively significant. Lack of support is the most influence indicator of stressor variable instead of job pressure. This study concludes that stress in work significantly influence the employees’ performance. Generally, stress in work at plant department of PT. NIC is in low category (41.9% and the performance is in high/good category (60.6%. It means that the existence of stress in work at this time have positive characteristics because it has played the role as motivator to work.

  6. Industrial Waste

    DEFF Research Database (Denmark)

    Christensen, Thomas Højlund

    2011-01-01

    Industrial waste is waste from industrial production and manufacturing. Industry covers many industrial sectors and within each sector large variations are found in terms of which raw materials are used, which production technology is used and which products are produced. Available data on unit...... generation rates and material composition as well as determining factors are discussed in this chapter. Characterizing industrial waste is faced with the problem that often only a part of the waste is handled in the municipal waste system, where information is easily accessible. In addition part...... of the industrial waste may in periods, depending on market opportunities and prices, be traded as secondary rawmaterials. Production-specificwaste from primary production, for example steel slag, is not included in the current presentation. In some countries industries must be approved or licensed and as part...

  7. Industrial Waste

    DEFF Research Database (Denmark)

    Christensen, Thomas Højlund

    2011-01-01

    of the system industry has to inform at the planning stage and afterwards in yearly reports on their waste arising and how the waste is managed. If available such information is very helpful in obtaining information about that specific industry. However, in many countries there is very little information......Industrial waste is waste from industrial production and manufacturing. Industry covers many industrial sectors and within each sector large variations are found in terms of which raw materials are used, which production technology is used and which products are produced. Available data on unit...... generation rates and material composition as well as determining factors are discussed in this chapter. Characterizing industrial waste is faced with the problem that often only a part of the waste is handled in the municipal waste system, where information is easily accessible. In addition part...

  8. Pt-graphene electrodes for dye-sensitized solar cells

    Energy Technology Data Exchange (ETDEWEB)

    Hoshi, Hajime, E-mail: hoshi@ed.tus.ac.jp; Tanaka, Shumpei; Miyoshi, Takashi

    2014-12-15

    Highlights: • Graphene films with Pt nanoparticles were prepared from commercial graphene. • Pt consumption can be reduced by using Pt-graphene films. • The film showed improved catalytic activity for the reaction I{sub 3}{sup −}/I{sup −}. • The film can be used as the counter electrode of dye-sensitized solar cells (DSSCs). • The performance of DSSC was superior to that of the Pt electrode. - Abstract: A simple paste method for fabricating graphene films with Pt nanoparticles was developed. First, graphene pastes with Pt nanoparticles were prepared from commercially available graphene. The resulting films of graphene nanoplatelet aggregates with Pt nanoparticles (Pt-GNA) contained Pt nanoparticles distributed over the entire three-dimensional surface of the GNA. Then, the catalytic activity for the I{sub 3}{sup −}/I{sup −} redox reaction was evaluated by cyclic voltammetry. The GNA electrode exhibited higher activity than a graphene nanoplatelet electrode because of its higher effective surface area. Addition of Pt nanoparticles to the electrodes improved the catalytic activity. In particular, a large Faradaic current for the I{sub 3}{sup −}/I{sup −} reaction was observed for the Pt-GNA electrode. As the counter electrodes of dye-sensitized solar cells (DSSCs), their performance was consistent with the cyclic voltammetry results. In particular, the DSSC performance of the Pt-GNA electrode was superior to that of the Pt electrodes commonly used in DSSCs.

  9. Synthesis and composition evolution of bimetallic Pd Pt alloy nanoparticles

    Science.gov (United States)

    Ren, Guoqiang; Shi, Honglan; Xing, Yangchuan

    2007-09-01

    This paper reports a study on the synthesis of Pd-Pt alloy nanoparticles and composition evolution of the alloys. The synthesis involves Pd and Pt acetylacetonate as the metal precursors and trioctylphosphine (TOP) as the solvent. Thermal decomposition of the Pd-TOP complex resulted in Pd nanoparticles, while substitution of Pt in the Pt-TOP complex by Pd allowed formation of the Pd-Pt alloys. It was observed that the Pd-Pt nanoparticles formed at the very beginning in the synthesis process are Pd rich with various nanoparticle sizes ranging from 1.5 to 25 nm in diameter. These nanoparticles averaged out through a digestive ripening process and reached a final size of 3.5 nm in about 10 min. The alloy compositions evolved throughout the synthesis process and only reached the preset Pd to Pt ratio of the precursors in 120 min. It was found that Pt acetylacetonate alone in TOP cannot produce Pt nanoparticles, which was attributed to the formation of a Pt-TOP complex and a strong coordination of Pt to the phosphine. This observation led us to propose an atomic exchange process between the Pt-TOP complex and the Pd atoms at the nanoparticle surface. As a result, the alloy formation process is limited by a substitution and diffusion rate of the Pt atoms at the surface of the alloy nanoparticles.

  10. Development of Soda Residue Concrete Expansion Agent

    Institute of Scientific and Technical Information of China (English)

    WANG Bao-min; WANG Li-jiu; M F Mohd Zain; F C Lai

    2003-01-01

    A new type of concrete expansion agent has been successfully developed for the first time in the world by utilizing an industrial waste residue-soda residue and an industrial wasteliquor.Adding 3%-6% of the agent into Portland cement enables a shrinkage-compensating concrete to be prepared.Mortar and concrete containing this expansion agent have better shrinkage-compensating and mechanical properties.The raw materials component,production process,technical properties,micro-analysis of mortar made with this expansion agent,mechanism of expansion and research results are described in this article.The experimental results show that the new type of concrete expansion agent accords with the standard and its main mineral component is xCaO-ySO3-zAl2O3.

  11. Electrochemical Nucleation of Stable N2 Nanobubbles at Pt Nanoelectrodes.

    Science.gov (United States)

    Chen, Qianjin; Wiedenroth, Hilke S; German, Sean R; White, Henry S

    2015-09-23

    Exploring the nucleation of gas bubbles at interfaces is of fundamental interest. Herein, we report the nucleation of individual N2 nanobubbles at Pt nanodisk electrodes (6–90 nm) via the irreversible electrooxidation of hydrazine (N2H4 → N2 + 4H(+) + 4e(–)). The nucleation and growth of a stable N2 nanobubble at the Pt electrode is indicated by a sudden drop in voltammetric current, a consequence of restricted mass transport of N2H4 to the electrode surface following the liquid-to-gas phase transition. The critical surface concentration of dissolved N2 required for nanobubble nucleation, CN2,critical(s), obtained from the faradaic current at the moment just prior to bubble formation, is measured to be ∼0.11 M and is independent of the electrode radius and the bulk N2H4 concentration. Our results suggest that the size of stable gas bubble nuclei depends only on the local concentration of N2 near the electrode surface, consistent with previously reported studies of the electrogeneration of H2 nanobubbles. CN2,critical(s) is ∼160 times larger than the N2 saturation concentration at room temperature and atmospheric pressure. The residual current for N2H4 oxidation after formation of a stable N2 nanobubble at the electrode surface is proportional to the N2H4 concentration as well as the nanoelectrode radius, indicating that the dynamic equilibrium required for the existence of a stable N2 nanobubble is determined by N2H4 electrooxidation at the three phase contact line.

  12. Natural radioactivity in petroleum residues

    Energy Technology Data Exchange (ETDEWEB)

    Gazineu, M.H.P. [UNICAP, Dept. de Quimica, Recife (Brazil); Gazineu, M.H.P.; Hazin, C.A. [UFPE, Dept. de Energia Nuclear, Recife (Brazil); Hazin, C.A. [Centro Regional de Ciencias Nucleares/ CNEN, Recife (Brazil)

    2006-07-01

    The oil extraction and production industry generates several types of solid and liquid wastes. Scales, sludge and water are typical residues that can be found in such facilities and that can be contaminated with Naturally Occurring Radioactive Material (N.O.R.M.). As a result of oil processing, the natural radionuclides can be concentrated in such residues, forming the so called Technologically Enhanced Naturally Occurring Radioactive Material, or T.E.N.O.R.M.. Most of the radionuclides that appear in oil and gas streams belong to the {sup 238}U and {sup 232}Th natural series, besides 40 K. The present work was developed to determine the radionuclide content of scales and sludge generated during oil extraction and production operations. Emphasis was given to the quantification of {sup 226}Ra, {sup 228}Ra and 40 K since these radionuclides,are responsible for most of the external exposure in such facilities. Samples were taken from the P.E.T.R.O.B.R.A.S. unity in the State of Sergipe, in Northeastern Brazil. They were collected directly from the inner surface of water pipes and storage tanks, or from barrels stored in the waste storage area of the E and P unit. The activity concentrations for {sup 226}Ra, {sup 228}Ra and 40 K were determined by using an HP Ge gamma spectrometric system. The results showed concentrations ranging from 42.7 to 2,110.0 kBq/kg for {sup 226}Ra, 40.5 to 1,550.0 kBq/kg for {sup 228}Ra, and 20.6 to 186.6 kBq/kg for 40 K. The results highlight the importance of determining the activity concentration of those radionuclides in oil residues before deciding whether they should be stored or discarded to the environment. (authors)

  13. Modelling pesticides residues

    OpenAIRE

    2004-01-01

    This work is a contribution to the development of a specific method to assess the presence of residues in agricultural commodities. The following objectives are formulated: to identify and describe main processes in environment — plant exchanges, to build of a model to assess the residue concentration at harvest in agricultural commodities, to understand the functioning of the modelled system, to characterise pesticides used in field crops and identify optimisation potentials in phytosanitary...

  14. Sol-Gel Process for Making Pt-Ru Fuel-Cell Catalysts

    Science.gov (United States)

    Narayanan, Sekharipuram; Valdez, Thomas; Kumta, Prashant; Kim, Y.

    2005-01-01

    A sol-gel process has been developed as a superior alternative to a prior process for making platinum-ruthenium alloy catalysts for electro-oxidation of methanol in fuel cells. The starting materials in the prior process are chloride salts of platinum and ruthenium. The process involves multiple steps, is time-consuming, and yields a Pt-Ru product that has relatively low specific surface area and contains some chloride residue. Low specific surface area translates to incomplete utilization of the catalytic activity that might otherwise be available, while chloride residue further reduces catalytic activity ("poisons" the catalyst). In contrast, the sol-gel process involves fewer steps and less time, does not leave chloride residue, and yields a product of greater specific area and, hence, greater catalytic activity. In this sol-gel process (see figure), the starting materials are platinum(II) acetylacetonate [Pt(C5H7O2)2, also denoted Pt-acac] and ruthenium(III) acetylacetonate [Ru(C5H7O2)3, also denoted Ru-acac]. First, Pt-acac and Ru-acac are dissolved in acetone at the desired concentrations (typically, 0.00338 moles of each salt per 100 mL of acetone) at a temperature of 50 C. A solution of 25 percent tetramethylammonium hydroxide [(CH3)4NOH, also denoted TMAH] in methanol is added to the Pt-acac/Ruacac/ acetone solution to act as a high-molecular-weight hydrolyzing agent. The addition of the TMAH counteracts the undesired tendency of Pt-acac and Ru-acac to precipitate as separate phases during the subsequent evaporation of the solvent, thereby helping to yield a desired homogeneous amorphous gel. The solution is stirred for 10 minutes, then the solvent is evaporated until the solution becomes viscous, eventually transforming into a gel. The viscous gel is dried in air at a temperature of 170 C for about 10 hours. The dried gel is crushed to make a powder that is the immediate precursor of the final catalytic product. The precursor powder is converted to the

  15. PT-symmetric quantum electrodynamics and unitarity.

    Science.gov (United States)

    Milton, Kimball A; Abalo, E K; Parashar, Prachi; Pourtolami, Nima; Wagner, J

    2013-04-28

    More than 15 years ago, a new approach to quantum mechanics was suggested, in which Hermiticity of the Hamiltonian was to be replaced by invariance under a discrete symmetry, the product of parity and time-reversal symmetry, PT. It was shown that, if PT is unbroken, energies were, in fact, positive, and unitarity was satisfied. Since quantum mechanics is quantum field theory in one dimension--time--it was natural to extend this idea to higher-dimensional field theory, and in fact an apparently viable version of PT-invariant quantum electrodynamics (QED) was proposed. However, it has proved difficult to establish that the unitarity of the scattering matrix, for example, the Källén spectral representation for the photon propagator, can be maintained in this theory. This has led to questions of whether, in fact, even quantum mechanical systems are consistent with probability conservation when Green's functions are examined, since the latter have to possess physical requirements of analyticity. The status of PT QED will be reviewed in this paper, as well as the general issue of unitarity.

  16. SURFACE PROPERTIES AND CATALYTIC PERFORMANCE OF Pt ...

    African Journals Online (AJOL)

    salt (AO) layers, have been examined for their low cost, high catalytic activity and high thermal ... of each peak after subtraction of the S-shaped background and fitting to a curve mixed of ..... In addition, for the 0.3 % Pt/LaSrCoO4 and 0.5.

  17. Study on utilization of industrial waste residue for production of microporous cementitious materials%利用工业废渣生产多微孔胶凝材料的研究

    Institute of Scientific and Technical Information of China (English)

    周君生; 徐伟; 陈益兰; 潘荣伟

    2012-01-01

    A new inorganic cementitious material with microporous structure was prepared by single low-temperature sintering process with fly ash,carbide slag,and desulfurization gypsum as raw materials and with adding a small amount of mineralizer,adhesive agent,and pore-forming agent and the material's performances were also studied.Taking the optimized formula and under the conditions of pre-heat temperature 400 ℃, roasting temperature 1 220 ℃, and holding time 25 min, water absorption, apparent density, and 3 d compressive strength of the prepared microporous cementitious material were 2.10% ,1.32 g/cm3,and 8.56 MPa,respectively.XRD analysis showed the main phases of synthesized material were calcium silicate and gehlenite.Using industrial waste slag as raw material as well as the combination of porosity and cementitious character made the microporous cementitious material can partially replace cement and lightweight aggregates (haydite) to prepare insulating mortar so that the purpose of environmental protection and energy saving could be realized.%以粉煤灰、电石渣和脱硫石膏为主要原料,掺加少量矿化剂、黏结剂和造孔剂,采用一次低温烧成工艺,制备出具有多微孔结构的新型无机胶凝材料,并对产品性能进行了研究.采用优化配方,在预热温度为400℃、焙烧温度为1 220℃、保温时间为25 min条件下制备的多微孔胶凝材料,其吸水率为2.10%、表观密度为1.32 g/cm3,3d抗压强度为8.56 MPa.通过XRD分析可知,合成材料的主要矿物相为硅酸钙和钙铝黄长石.材料采用工业废渣制备,集多孔性和胶凝性,可部分代替水泥和陶粒制成保温砂浆,达到环保节能的目的.

  18. Consorcio microbiano nativo con actividad catalítica para remoción de índigo y surfactantes en agua residual industrial textil a través de una matriz de inmovilización

    Directory of Open Access Journals (Sweden)

    Lliana Guerrero Porras

    2014-06-01

    Full Text Available Título en ingles: Microbial consortium native catalytically active for removal of indigo and surfactants in textile industry wastewater through an immobilization matrixTítulo corto: Consorcio microbiano nativo con actividad catalítica para remoción de índigoResumen: El siguiente estudio tuvo como objetivo aislar seis diferentes cepas bacterianas  provenientes de las descargas de agua utilizadas en la tintura de hilo con colorante índigo, que tuviesen capacidad de degradación de compuestos orgánicos del tinte índigo y tres surfactantes de tipo no iónicos.  Igualmente, se evaluaron diferentes medios de soporte para inmovilizar las cepas seleccionadas. Las cepas con mejor capacidad de decoloración se combinaron para conformar cuatro consorcios (I, II, III, y IV con el fin de potenciar el proceso de decoloración, considerando que la sinergia y el complemento de actividades metabólicas de cultivos mixtos dentro de una comunidad microbiana incrementan la eficiencia de remoción de carga orgánica. Los porcentajes de remoción que se alcanzaron fueron 64, 73, 76 y 59 %, respectivamente. Los cultivos individuales no presentaron porcentajes de remoción superiores a los reportados por los consorcios, lo que permite pensar en su utilización para la remoción de tintes índigos en aguas residuales.Palabras claves: aislamiento, biodegradación, índigo, surfactantes no iónicos, consorcio bacteriano.Abstract: The aim of this study was isolate six different bacterial strains from water discharges used in dyeing yarn with indigo, capable of degradation of organic compounds with indigo dye and three nonionic type surfactants. Similarly, various supporting media were evaluated for immobilizing the selected strains. Strains with better capacity were combined to form four consortia (I, II, III, and IV in order to enhance the bleaching process, whereas synergy and complement metabolic activities of mixed cultures within a community increase

  19. Perumusan Strategi Bersaing pada Perusahaan Ban dengan Metode Analisis Portofolio Produk (Studi Kasus: PT Multistrada Arah Sarana, Tbk

    Directory of Open Access Journals (Sweden)

    Nathanael August Zefanya

    2017-01-01

    Full Text Available Industri ban di Indonesia mengalami perkembangan pesat dalam kurun waktu 10 tahun terakhir. Namun, terjadinya krisis ekonomi global menjadi penyebab menurunnya pendapatan, salah satunya adalah PT MASA dengan produk utamanya yaitu ban mobil Achilles dan ban motor Corsa yang digunakan sebagai objek penelitian ini. Telah diilakukan analisis PESTEL dan Porter’s Five Forces, identifikasi faktor lingkungan internal dan eksternal dengan analisis SWOT serta merumuskan alternatif strategi bersaing untuk direkomendasikan kepada PT MASA. Perumusan strategi alternatif didapat dari hasil analisis Matriks BCG dan Matriks IE sebagai analisis portofolio untuk mendapatkan tema strategi alternatif dalam pembuatan Matriks SWOT. Strategi alternatif kemudian diperingkatkan dengan QSPM dan dilanjutkan pembuatan rencana aksi bagi PT MASA dalam waktu 5 tahun ke depan. Setelah dilakukan analisis industri, diketahui bahwa ancaman terbesar datang dari pesaing produsen ban. Dari hasil analisis portofolio, PT MASA berada di kuadran I karena memiliki koordinat IFE serta EFE 3,32 dan 3,26. Dari hasil analisis Matriks IE, PT MASA direkomendasikan untuk melakukan strategi grow and build. Hasil Matriks BCG menunjukkan bahwa Achilles berada di dogs, sementara Corsa berada di question marks. Terdapat 13 strategi alternatif hasil dari formulasi strategi dengan menggunakan matriks TOWS. Dari hasil analisis QSPM, terdapat 7 alternatif strategi terbaik dan rencana aksi..

  20. A rational computational study of surface defect-mediated stabilization of low-dimensional Pt nanostructures on TiN(100).

    Science.gov (United States)

    Tak, Young Joo; Jang, Woosun; Richter, Norina A; Soon, Aloysius

    2015-04-21

    Platinum is known as a catalyst with exceptional reactivity for many important reactions, e.g. the oxygen reduction reaction. To reduce the high cost of pure platinum catalysts, platinum on a carbon support is widely used in industrial fuel cell applications. However, these Pt/C systems suffer from poor stability. As a cost-efficient and more durable alternative, Pt single-atom catalysts on a TiN support have recently been suggested, and it has been shown that the single-atom catalysts are stable when anchored at a nitrogen vacancy site on the TiN surface in a nitrogen-lean environment. To further explore the perspective of Pt/TiN catalytic systems, we provide insights into the stability and morphology of Pt nanostructures at the TiN(100) surface, using a density-functional theory approach in combination with ab initio atomistic thermodynamics. Our results show that the formation of two-dimensional Pt nano-layers is preferred over the formation of three-dimensional Pt nano-clusters on the TiN substrate. Similar to the single-atom catalysts, nano-layers of Pt can be stabilized on the TiN(100) surface by surface nitrogen vacancies under nitrogen-lean conditions. By analyzing the electronic metal-support interaction (EMSI) between the Pt nano-layer and the TiN surface with surface defects, we demonstrate that a strong EMSI between the surrounding Ti and Pt atoms is important for stabilizing the catalyst nano-layer at the TiN surface, and that N vacancies lead to stronger Pt-Ti interaction. This work provides a rational computational platform for the design of new generation high-performance Pt-based fuel cells.

  1. Adhesion and bonding of Pt/Ni and Pt/Co overlayers: Density functional calculations

    Science.gov (United States)

    Cabeza, Gabriela F.; Castellani, Norberto J.; Légaré, Pierre

    2006-04-01

    The electronic and energetic properties of bimetallic surfaces Pt/Ni(111) and Pt/Co(111) are examined using the FP-LAPW (Full-PotentialLinearized Augmented Plane Wave) method by means of spin-polarized and non-polarized calculations. We present both the results of the shifts in the d-band centers when one metal (Pt) is pseudomorfically deposited on another with smaller lattice constant (Ni, Co) and those corresponding to the surface and adhesion energies. The surface is modeled by a seven layer slab separated in z direction by a vacuum region of six substrate layers. The results obtained for pure Ni, Co and Pt surfaces are presented in order to compare with experimental and theoretical data reported in the literature

  2. Domain wall pinning on strain relaxation defects in FePt(001)/Pt thin films

    Energy Technology Data Exchange (ETDEWEB)

    Attane, J. P.; Samson, Y.; Marty, A.; Halley, D.; Beigne, C.

    2001-08-06

    Thin FePt (001) films, grown by molecular-beam epitaxy on Pt(001), exhibit a very large perpendicular magnetic anisotropy (K{sub u}=5 x 10{sup 6}Jm{sup -3}) and a 100% magnetic remanence in perpendicular field. The lattice misfit between FePt and Pt (1.5%) relaxes through the pileup of a/6 <112> partial dislocations along {l_brace}111{r_brace} planes, leading to the formation of microtwins. Atomic force microscopy images demonstrate that this process induces a spontaneous rectangular nanostructuration of the sample, while magnetic force microscopy shows that the microtwins act as pinning sites for the magnetic walls. This leads to square magnetic domains and explains the large coercivity associated with the domain wall propagation. {copyright} 2001 American Institute of Physics.

  3. Domain wall pinning on strain relaxation defects in FePt(001)/Pt thin films

    Science.gov (United States)

    Attané, J. P.; Samson, Y.; Marty, A.; Halley, D.; Beigné, C.

    2001-08-01

    Thin FePt (001) films, grown by molecular-beam epitaxy on Pt(001), exhibit a very large perpendicular magnetic anisotropy (Ku=5×106J m-3) and a 100% magnetic remanence in perpendicular field. The lattice misfit between FePt and Pt (1.5%) relaxes through the pileup of a/6 partial dislocations along {111} planes, leading to the formation of microtwins. Atomic force microscopy images demonstrate that this process induces a spontaneous rectangular nanostructuration of the sample, while magnetic force microscopy shows that the microtwins act as pinning sites for the magnetic walls. This leads to square magnetic domains and explains the large coercivity associated with the domain wall propagation.

  4. Selective oxidation of methylamine over zirconia supported Pt-Ru, Pt and Ru catalysts

    Institute of Scientific and Technical Information of China (English)

    Aiying Song; Gongxuan Lu

    2015-01-01

    Pt–Ru, Pt and Ru catalysts supported on zirconia were prepared by impregnation method and were tested in se-lective oxidation of methylamine (MA) in aqueous media. Among three catalysts, Ru/ZrO2 was more active than Pt/ZrO2 while Pt–Ru/ZrO2 demonstrated the best catalytic activity due to the fact that Pt addition efficiently pro-moted the dispersion of active species in bimetallic catalyst. Therefore, the~100%TOC conversion and N2 selec-tivity were achieved over Pt–Ru/ZrO2, Pt/ZrO2 and Ru/ZrO2 catalysts at 190, 220 and 250 °C, respectively.

  5. Ir0.5Pt0.5O2阳极的电催化活性及氧化电解水制备%Electrocatalytic performance of Ir0.5Pt0.5O2 anode and preparation of electrolyzed oxidizing water

    Institute of Scientific and Technical Information of China (English)

    高洁; 朱玉婵; 任占冬; 李文阳; 全姗姗; 刘晔; 王又容; 柴波

    2015-01-01

    Electrolyzed oxidizing water (EOW), as an innovative disinfectant characterized by its high efficiency, broad antimicrobial spectrum, and non-toxic residues, has been broadly used in health care industry, medicines, agriculture, and food processing. EOW is usually generated by electrolysis of a dilute NaCl solution in a chamber with two cells separated by membrane, and is obtained from the anode side. But low current efficiency and short service life of the anode in EOW generators restrict the application of EOW. Ir0.5Pt0.5O2 anode was prepared by the improved Adams fusion method. The properties of Ir0.5Pt0.5O2 anode was investigated with X-ray diffraction (XRD), scanning electron microscope (SEM) and electrochemistry cyclic voltammetry (CV). The crystal type is rutile with (101), (002) and (301) crystal planes. A large number of cellular structures were observed on the surface of the anode, which greatly increased specific surface area of the anode. With increasing specific surface area, electric charge was enhanced to 0.4 mC, which was 2.65 times of pure IrO2. Electrochemical characteristics of the anode surface, such as oxidation peaks at 1.0 V(Pt-OH) and 0.9 V(Ir3+/Ir4+) proved the formation of platinum iridium oxide. The activities of chlorine evolution and oxygen evolution were also studied through linear sweep voltammetry (LSV). Compared with IrO2, chlorine evolution activity in unit apparent surface area increased significantly, but oxygen evolution activity decreased obviously. The slope of Tafel was 56.3 mV·dec−1 for chlorine evolution reaction (CER), and the mechanism was Volmer-Heyrovsky in which the rate controlling step was electrochemical desorption. The slope of Tafel was 126.6 mV·dec−1 for oxygen evolution reaction (OER), and the rate controlling step was formation of surface hydroxide on the catalyst surface. Electrochemical surface structure and electrochemical performance of Ir0.5Pt0.5O2 oxide coatings in 1 g · L−1 NaCl solution were

  6. Ánodos de Pt-Ru y Pt-Ir para Celdas de Combustible Alimentadas con Metano y Propano Directo Pt-Ru and Pt-Ir Anodes for Direct Methane and Propane Proton Exchange Membrane Fuel Cells

    Directory of Open Access Journals (Sweden)

    Bibian A Hoyos

    2007-01-01

    Full Text Available En este trabajo se evalúa el efecto de la temperatura en el desempeño de celdas de combustible de membrana de intercambio protónico alimentadas con metano y propano, utilizando oxígeno como alimentación en el cátodo. Para la oxidación de los combustibles en los ánodos, se probaron cinco catalizadores soportados en carbón: Pt, Pt85Ru15, Pt50Ru50, Pt90Ir10 y Pt50Ir50. Como catalizador en el cátodo se usó platino puro soportado en carbón. El desempeño de las celdas de combustible fue evaluado mediante curvas de polarización obtenidas a partir de los datos corriente-potencial. Los resultados indican que la oxidación de metano se ve favorecida a altas temperaturas sobre los catalizadores Pt90/Ir10, Pt50/Ir50 y Pt50/Ru50. A bajas temperaturas los mejores catalizadores resultaron ser Pt y Pt85/Ru15. La mezcla bimetálica Pt85/Ru15 fue la que presentó mejor desempeño para llevar a cabo la oxidación de propano a 30 °C.In this paper, the effect of temperature in the performance of proton exchange membrane fuel cells feed with methane and propane, using oxygen as feed to the cathode, is presented. For the fuel oxidation in the anodes, five carbon supported catalysts were tested: Pt, Pt85/Ru15, Pt50/Ru50, Pt90/Ir10, and Pt50/Ir50. Carbon-supported pure platinum was used as catalysts in the cathode side. The performance of the fuel cells was evaluated by polarization curves obtained from the current-potential data. Results indicate that methane oxidation is favoured at high temperatures on the Pt90/Ir10, Pt50/Ir50 and Pt50/Ru50 catalysts. At low temperatures the best catalysts were Pt and Pt85/Ru15. The Pt85/Ru15 bimetallic mixture showed the best performance to carry out propane oxidation at 30 °C.

  7. Rapid thermal annealing of FePt and FePt/Cu thin films

    Energy Technology Data Exchange (ETDEWEB)

    Brombacher, Christoph

    2011-01-10

    Chemically ordered FePt is one of the most promising materials to reach the ultimate limitations in storage density of future magnetic recording devices due to its high uniaxial magnetocrystalline anisotropy and a corrosion resistance superior to rare-earth based magnets. In this study, FePt and FePt/Cu bilayers have been sputter deposited at room temperature onto thermally oxidized silicon wafers, glass substrates and self-assembled arrays of spherical SiO{sub 2} particles with diameters down to 10 nm. Millisecond flash lamp annealing, as well as conventional rapid thermal annealing was employed to induce the phase transformation from the chemically disordered A1 phase into the chemically ordered L1{sub 0} phase. The influence of the annealing temperature, annealing time and the film thickness on the ordering transformation and (001) texture evolution of FePt films with near equiatomic composition was studied. Whereas flash lamp annealed FePt films exhibit a polycrystalline morphology with high chemical L1{sub 0} order, rapid thermal annealing can lead to the formation of chemically ordered FePt films with (001) texture on amorphous SiO{sub 2}/Si substrates. The resultant high perpendicular magnetic anisotropy and large coercivities up to 40 kOe are demonstrated. Simultaneously to the ordering transformation, rapid thermal annealing to temperatures exceeding 600 C leads to a break up of the continuous FePt film into separated islands. This dewetting behavior was utilized to create regular arrays of FePt nanostructures on SiO{sub 2} particle templates with periods down to 50 nm. The addition of Cu improves the (001) texture formation and chemical ordering for annealing temperatures T{sub a} {<=}600 C. In addition, the magnetic anisotropy and the coercivity of the ternary FePtCu alloy can be effectively tailored by adjusting the Cu content. The prospects of FePtCu based exchange spring media, as well as the magnetic properties of FePtCu nanostructures fabricated

  8. Failure characteristics and mechanisms of EB-PVD TBCs with Pt-modified NiAl bond coats

    Energy Technology Data Exchange (ETDEWEB)

    Zhou, Le; Mukherjee, Sriparna; Huang, Ke; Park, Young Whan; Sohn, Yongho, E-mail: Yongho.Sohn@ucf.edu

    2015-06-18

    Microstructural evolution and failure characteristics/mechanisms were investigated for thermal barrier coatings that consist of electron beam physical vapor deposited ZrO{sub 2}−8 wt% Y{sub 2}O{sub 3} (YSZ) topcoat, Pt-modified nickel aluminide, (Ni,Pt)Al bond coat, and CMSX-4 superalloy substrate with furnace cycling at 1100 °C with 1-h dwell. Photo stimulated luminescence spectroscopy, scanning electron microscopy equipped with X-ray energy dispersive spectroscopy and transmission electron microscopy were employed to examine the residual stress of the thermally grown oxide (TGO) and microstructural changes. For comparison, (Ni,Pt)Al bond coat on CMSX-4 without the YSZ topcoat was also characterized. The TGO grew faster for the YSZ-coated (Ni,Pt)Al bond coat than the (Ni,Pt)Al coating without the YSZ topcoat. Correspondingly, the β-to-γ′/martensite formation in the (Ni,Pt)Al bond coat occurred faster on the YSZ-coated (Ni,Pt)Al bond coat. However the rumpling occurred much faster and with larger amplitude on the (Ni,Pt)Al coating without the YSZ topcoat. Still, the rumpling at the TGO/bond coat interface caused crack initiation as early as 10 thermal cycles, decohesion at the YSZ/TGO interface, and eventual spallation failure primarily through the TGO/bond coat interface. The magnitude of compressive residual stress in the TGO showed an initial increase up to 3−4 GPa followed by a gradual decrease. The rate of stress relaxation was much quicker for the TGO scale without the YSZ topcoat with distinctive relief corresponding to the cracking at the top of geometrical ridges associated with the (Ni,Pt)Al bond coat. The maximum elastic energy for the TGO scale was estimated at 90 J/m{sup 2} at 50% of its lifetime (N{sub f}=545 cycles). The YSZ presence/adhesion to the TGO scale is emphasized to minimize the undulation of the TGO/bond coat interface, i.e., decohesion at the YSZ/TGO scale accelerates the rumpling and crack-coalescence at the TGO/bond coat

  9. Cloning and Expression Patterns of PtSUS1 in Populus tomentosa%毛白杨蔗糖合酶基因PtSUS1的克隆及其表达模式分析

    Institute of Scientific and Technical Information of China (English)

    李英; 陈仲; 李昊; 郭斌; 王佳; 安新民

    2012-01-01

    蔗糖合酶(sucrose synthase)与植物库强调节、次生壁的形成和纤维素合成等有着密切的联系,其中在纤维素合成过程中的作用尤为显著.本研究根据我们已获得的毛白杨PtSUS1基因片段设计引物,采用RACE技术,获得了毛白杨PtSUS1的基因序列,测序结果显示该基因序列全长为2 669 bp,包括一个完整的阅读框,编码805个氨基酸.通过Blast检索分析表明,PtSUS1与拟南芥、巨桉、陆地棉、温州蜜柑、毛果杨SUS1的核酸和氨基酸序列的同源性分别达到76%~97%和82%~97%.运用生物信息软件对PtSUS1编码的蛋白进行了二级结构预测和功能位点分析,结果显示该蛋白氨基酸序列包括两个功能域,存在可能的磷酸化位点38个,无跨膜结构域存在.系统进化分析表明PtSUS1与PtSUS2关系最为接近.RT-PCR分析结果显示,PtSUS1在被检测的毛白杨根、茎、叶及雌雄花芽组织和器官中均有表达,呈现组成型表达模式.该研究为进一步深入探索毛白杨蔗糖合酶基因PtSUS1的功能奠定了基础.%Sucrose synthase (SUS) was closely associated with sink strength, secondary wall formationand cellulose synthesis in plant. Among these items, cellulose synthesis is considered to be the most important. According to the known gene fragment of PtSUSl and the principle of RACE amplification, we got the gene sequence of PtSUSl from Populous tomentosa. The full sequence of PtSUSl which contains an open reading frame (ORF) is 2 669 bp encoding a deduced amino acid sequence of 805 residues. Blast analysis results indicated that the homology was as high as 76% to 97% and 81% to 97%, respectively, when compared PtSUSl sequence of amino acid and nucle-otide with the ones of Arabidopsis thaliana, Eucalyptus grandis, Gossypium hirsutum, Citrus unshiu, and Populus trichocarpa. Furthermore, secondary structure and functional sites in amino acid sequences have been predicted by the bioinformatics

  10. Irreversible modification of magnetic properties of Pt/Co/Pt ultrathin films by femtosecond laser pulses

    Energy Technology Data Exchange (ETDEWEB)

    Kisielewski, J., E-mail: jankis@uwb.edu.pl [Institute for Molecules and Materials, Radboud University Nijmegen, Heyendaalseweg 135, 6525AJ Nijmegen (Netherlands); Laboratory of Magnetism, University of Białystok, Lipowa 41, 15-424 Białystok (Poland); Dobrogowski, W.; Kurant, Z.; Stupakiewicz, A.; Tekielak, M.; Maziewski, A. [Laboratory of Magnetism, University of Białystok, Lipowa 41, 15-424 Białystok (Poland); Kirilyuk, A.; Kimel, A.; Rasing, Th. [Institute for Molecules and Materials, Radboud University Nijmegen, Heyendaalseweg 135, 6525AJ Nijmegen (Netherlands); Baczewski, L. T.; Wawro, A. [Institute of Physics, Polish Academy of Sciences, al. Lotników 32/46, 02-668 Warsaw (Poland); Balin, K.; Szade, J. [A. Chełkowski Institute of Physics, University of Silesia, Uniwersytecka 4, 40-007 Katowice (Poland)

    2014-02-07

    Annealing ultrathin Pt/Co/Pt films with single femtosecond laser pulses leads to irreversible spin-reorientation transitions and an amplification of the magneto-optical Kerr rotation. The effect was studied as a function of the Co thickness and the pulse fluence, revealing two-dimensional diagrams of magnetic properties. While increasing the fluence, the creation of two branches of the out-of-plane magnetization state was found.

  11. Atomic Aggregation Processes in the Early Stages of Pt/Pt(111) Growth

    Institute of Scientific and Technical Information of China (English)

    ZHUANG Guo-Ce; ZHU Xiao-Bin; WANG Wei

    2000-01-01

    The atomic aggregation processes in the early stages of Pt/Pt(111) growth are studied by using kinetic Monte Carlo simulations. Our results show that the average neighbor coordination number of the atoms in a cluster is a function of temperature, agreeing well with the experiment observations of scanning tunneling microscopy. The influence of diffusion barriers of various atomic processes on the morphology of islands is also studied. Different morphologies of the islands (dendritic, fractal, or compact islands) are found.

  12. SELECTIVE HYDROGENATION OF CINNAMALDEHYDE WITH Pt AND Pt-Fe CATALYSTS: EFFECTS OF THE SUPPORT

    Directory of Open Access Journals (Sweden)

    A.B. da Silva

    1998-06-01

    Full Text Available Low-temperature reduced TiO2-supported Pt and Pt-Fe catalysts are much more active and selective for the liquid–phase hydrogenation of cinnamaldehyde to unsaturated cinnamyl alcohol than the corresponding carbon-supported catalysts. High-temperature reduced catalysts, where the SMSI effect should be present, are almost inactive for this reaction. There is at present no definitive explanation for this effect but an electronic metal-support interaction is most probably involved.

  13. Resistência mecânica de compósitos cimentícios leves utilizando resíduos industriais e fibras de sisal Mechanical resistence of lightweight cement composites utilizing industrial residues and fibers of sisal

    Directory of Open Access Journals (Sweden)

    Nivaldo T. de Arruda Filho

    2012-08-01

    Full Text Available A valorização de materiais alternativos incorporados com resíduos como opção ao convencional deve possibilitar a geração de um produto com qualidade, estética, produtividade e com potencial de reduzir impactos da poluição ambiental. Este trabalho foi realizado com o objetivo de desenvolver elementos construtivos para forro e divisórias, a partir de matrizes cimentícias com incorporação de resíduos industriais (resíduo cerâmico, etil vinil acetato - EVA e fibras de sisal. Desenvolveram-se técnicas de moldagem em matrizes cimentícias autoadensáveis e se avaliou a resistência mecânica dos novos compósitos. Uma placa com resíduos de EVA foi produzida e, através de trabalhos de reologia, encontrou-se a pasta matriz de revestimento desta placa, com teor adequado de adições pozolânicas e aditivo superplastificante. Avaliaram-se as resistências mecânicas das placas, da pasta matriz de revestimento encontrada, com e sem adição de fibras, e do novo compósito formado pela união desses dois elementos. Utilizou-se a técnica de alinhamento de fibras com o intuito de incrementar resistência ao novo compósito leve. A adição da matriz com fibras alinhadas melhorou a resistência a flexão do novo compósito.The appreciation of alternative materials incorporated in waste as an option to conventional material should enable to generate a product with quality, aesthetics, productivity and reduce the potential impacts of environmental pollution. This study aims to develop constructive elements for ceilings and walls from cementitious matrix incorporating industrial waste (ceramic waste, ethyl vinyl acetate - EVA and sisal fibers. Moulding techniques to produce self-compacting cementitious matrices were developed and the strength of the new composites were evaluated. A plate with EVA waste was produced and through rheology studies, a matrix plaster for coating of plate surface was found, with appropriate content of pozzolanic and

  14. Dry etching of single crystal PMN-PT piezoelectric material.

    OpenAIRE

    Agnus, Joël; Alexandru Ivan, Ioan; Queste, Samuel

    2011-01-01

    International audience; During the last decade, the applications of PMN-PT spread significantly. Unlike PZT, the appropriate microtechnologies for PMN-PT Piezo-MEMS aren't fully documented in the literature. This paper deals with the PMN-PT etching by inductively coupled plasma (ICP) technique, also known as DRIE. The paper quantitatively presents the etching parameters of PMN-PT by the Ar/C4F8 gas combination and reports some related useful experience.

  15. Nonlinear waves in $\\cal PT$-symmetric systems

    OpenAIRE

    Konotop, Vladimir V.; Yang, Jianke; Zezyulin, Dmitry A.

    2016-01-01

    Recent progress on nonlinear properties of parity-time ($\\cal PT$-) symmetric systems is comprehensively reviewed in this article. $\\cal PT$ symmetry started out in non-Hermitian quantum mechanics, where complex potentials obeying $\\cal PT$ symmetry could exhibit all-real spectra. This concept later spread out to optics, Bose-Einstein condensates, electronic circuits, and many other physical fields, where a judicious balancing of gain and loss constitutes a $\\cal PT$-symmetric system. The nat...

  16. Anthropogenic platinum group element (Pt, Pd, Rh) concentrations in PM10 and PM2.5 from Kolkata, India.

    Science.gov (United States)

    Diong, Huey Ting; Das, Reshmi; Khezri, Bahareh; Srivastava, Bijayen; Wang, Xianfeng; Sikdar, Pradip K; Webster, Richard D

    2016-01-01

    This study investigates platinum group elements (PGEs) in the breathable (PM10) and respirable (PM2.5) fractions of air particulates from a heavily polluted Indian metro city. The samples were collected from traffic junctions at the heart of the city and industrial sites in the suburbs during winter and monsoon seasons of 2013-2014. PGE concentrations were determined by inductively coupled plasma-mass spectrometry (ICP-MS). The PGE concentrations in the samples from traffic junctions are within the range of 2.7-111 ng/m(3) for Pd, 0.86-12.3 ng/m(3) for Pt and 0.09-3.13 ng/m(3) for Rh, and from industrial sites are within the range of 3.12-32.3 ng/m(3) for Pd, 0.73-7.39 ng/m(3) for Pt and 0.1-0.69 ng/m(3) for Rh. Pt concentrations were lower in the monsoon compared to winter while Pd concentrations increased during monsoon and Rh stayed relatively unaffected across seasons. For all seasons and locations, concentrations of Pd > Pt > Rh, indicating dominance of Pd-containing exhaust converters. Most of the PGEs were concentrated in the PM2.5 fraction. A strong correlation (R ≥ 0.62) between the PGEs from traffic junction indicates a common emission source viz. catalytic converters, whereas a moderate to weak correlation (R ≤ 0.5) from the industrial sites indicate mixing of different sources like coal, raw materials used in the factories and automobile. A wider range of Pt/Pd, Pt/Rh and Pd/Rh ratios measured in the traffic junction possibly hint towards varying proportions of PGEs used for catalyst productions in numerous rising and established car brands.

  17. Modification of Pt/Co/Pt film properties by ion irradiation

    Science.gov (United States)

    Avchaciov, K. A.; Ren, W.; Djurabekova, F.; Nordlund, K.; Sveklo, I.; Maziewski, A.

    2015-09-01

    We studied the structural modifications of a Pt/Co/Pt trilayer epitaxial film under Ga+ 30-keV ion irradiation by means of classical molecular dynamics and Monte Carlo simulations. The semiclassical tight-binding second-moment approximation potential was adjusted to reproduce the enthalpies of formation, the lattice constants, and the order-disorder transition temperatures for Co-Pt alloys. We found that during irradiation, the sandwich-type Pt(fcc)/Co(hcp)/Pt(fcc) film structure underwent a transition to the new solid solution α -Co /Pt (fcc ) phase. Our analysis of the short-range order indicates the formation, within a nanosecond time scale, of a homogeneous chemically disordered solution. The longer time-scale simulations employing a Monte Carlo algorithm demonstrated that the transition from the disordered phase to the ordered L 10 and L 12 phases was also possible but not significant for the changes in perpendicular magnetic anisotropy (PMA) observed experimentally. The strain analysis showed that the Co layer was under tensile strain in the lateral direction at the fluences of 1.5 ×1014-3.5 ×1014ionscm -2 ; this range of fluences corresponds to the appearance of PMA. This strain was induced in the initially relaxed hcp Co layer due to its partial transformation to the fcc phase and to the influence of atomic layers with larger lattice constants at upper/lower interfaces.

  18. The Mechanism of Direct Formic Acid Fuel Cell Using Pd, Pt and Pt-Ru

    Science.gov (United States)

    Kamiya, Nobuyuki; Liu, Yan; Mitsushima, Shigenori; Ota, Ken-Ichiro; Tsutsumi, Yasuyuki; Ogawa, Naoya; Kon, Norihiro; Eguchi, Mika

    The electro-oxidation of formic acid, 2-propanol and methanol on Pd black, Pd/C, Pt-Ru/C and Pt/C has been investigated to clear the reaction mechanism. It was suggested that the formic acid is dehydrogenated on Pd surface and the hydrogen is occluded in the Pd lattice. Thus obtained hydrogen acts like pure hydrogen supplied from the outside and the cell performance of the direct formic acid fuel cell showed as high as that of a hydrogen-oxygen fuel cell. 2-propanol did not show such dehydrogenation reaction on Pd catalyst. Platinum and Pt-Ru accelerated the oxidation of C-OH of 2-propanol and methanol. Slow scan voltammogram (SSV) and chronoamperometry measurements showed that the activity of formic acid oxidation increased in the following order: Pd black > Pd 30wt.%/C > Pt50wt.%/C > 27wt.%Pt-13wt.%Ru/C. A large oxidation current for formic acid was found at a low overpotential on the palladium electrocatalysts. These results indicate that formic acid is mainly oxidized through a dehydrogenation reaction. For the oxidation of 2-propanol and methanol, palladium was not effective, and 27wt.%Pt-13wt.%Ru/C showed the best oxidation activity.

  19. An evaluation of Pt sulfite acid (PSA) as precursor for supported Pt catalysts

    Energy Technology Data Exchange (ETDEWEB)

    Regalbuto, J.R.; Ansel, O.; Miller, J.T. (BP Res. Cntr.); (UIC)

    2010-11-12

    As a catalyst precursor, platinum sulfite acid (PSA) is easy to use and not relatively expensive, and is a potentially attractive precursor for many types of supported catalysts. The ultimate usefulness for many catalyst applications will depend on the extent that Pt can be dispersed and sulfur eliminated. To our knowledge, there exists no detailed characterization in the catalysis literature of PSA and the nanoparticulate Pt phases derived from it during catalyst pretreatment. To this end a series of supports including alumina, silica, magnesia, niobia, titania, magnesia and carbon were contacted with PSA solutions and subsequently analyzed with extended x-ray absorption fine structure (EXAFS) and x-ray absorption near edge structure (XANES) analysis, and x-ray photoelectron spectroscopy (XPS) to characterize the Pt species formed upon impregnation, calcination, and reduction. While all catalysts show retention of some S, reasonably small particle sizes with relatively little Pt-S can in some instances be produced using PSA. The amount of retained sulfur appears to decrease with decreasing surface acidity, although even the most acidic supports (niobia and silica) display some storage of S even while only Pt-O bands are observed after calcination or reoxidation. More sulfur was eliminated by high temperature calcinations followed by reduction in hydrogen, at the expense of increasing Pt particle size.

  20. 40 CFR Table 19 to Subpart G of... - Wastewater-Information on Residuals To Be Submitted With Notification of Compliance Status a,b

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 9 2010-07-01 2010-07-01 false Wastewater-Information on Residuals To... Vents, Storage Vessels, Transfer Operations, and Wastewater Pt. 63, Subpt. G, Table 19 Table 19 to Subpart G of Part 63—Wastewater—Information on Residuals To Be Submitted With Notification of...

  1. Lixiviação de íons após a aplicação de resíduos orgânicos de uma indústria farmoquímica Leaching of ions after the application of organic residues of a pharmochemical industry

    Directory of Open Access Journals (Sweden)

    Augusto V. Luchese

    2008-04-01

    Full Text Available Nas últimas décadas, quantidades crescentes de resíduo industrial têm sido depositadas sobre o solo, de forma planejada ou acidental, razão pela qual se objetiva avaliar neste trabalho, o impacto da aplicação de uma dose alta de resíduos orgânicos (Biossólido - Bs e Lodo - Lo, produzidos por indústria farmoquímica, na contaminação dos mananciais de água; para tanto, montou-se um experimento em coluna de PVC de 20 x 120 cm (diâmetro x altura em um fatorial 2 x 2 x 2+ 2, sendo 2 solos (NVdf e PVd, 2 resíduos (Bs e Lo, 2 formas de aplicação de 1 milhão de L ha-1 (incorporado e em superfície e 1 testemunha para cada solo; em cada coluna foram feitas 10 aplicações de água correspondentes a 120% da capacidade de retenção de água das colunas e coletados os efluentes para avaliação dos seus atributos químicos. A condutividade elétrica (CE do lixiviado apresentou grande diminuição da 1ª para a 2ª aplicação de água e o pH aumentou até a quarta aplicação de água. Os íons apresentaram comportamentos diferentes pois aqueles que formam complexos de esfera externa (N O3-, Cl-, Ca2+, Mg2+ e Na+ indicaram rápida lixiviação. Os nutrientes que formam complexos de esfera interna se comportaram de maneira diferente, sendo que PO4(3- apresentou baixa lixiviação, K+ lixiviou menos que nos tratamentos testemunhas e SO4(2- lixiviou mais a partir da 3ª coleta.In the last decades, increasing amounts of industrial residues have been deposited in the soil in either a planned way, or accidentally. The objective of this work is to evaluate the impact of the application of a high dose of organic residues (Biossolid - Bs and Sludge - Sd produced by a pharmochemical industry on the contamination of spring waters. Therefore, an experiment was set up in PVC columns of 20 x 120 cm (diameter x height in a factorial design 2 x 2 x 2+ 2 with, 2 soils (NVdf and PVd, 2 residues (Bs and Sd, 2 forms of application of 1 million L ha-1

  2. Longshoring Industry

    Science.gov (United States)

    2001-01-01

    a)(1). (5) ANSI Z-89.1-1986, Personnel Protection-Protective Headwear for Industrial Workers-Requirements; IBR approved for 1917.93(b). (6) ANSI Z-41... Headwear for Industrial Workers-Requirements.” (c) Protective hats previously worn shall be cleaned and disinfected before issuance by the employer to... Headwear for Industrial Workers-Requirements; IBR approved for §1918.103(b). (6) ANSI Z-41-1991, American National Standard for Personal Protection

  3. Biotechnology Industry

    Science.gov (United States)

    2007-01-01

    Countries Growing GMO , 2007). Herbicide and insect resistance traits will continue to be pursued since 25% of food crops are lost each year to insect...daily lives from the clothing we wear, the fuel we use, the food we eat, and the medicines we take. From the earliest days, humans have used the...industry is very broad and includes health care, food , agriculture, industrial, and environmental industries. It is one of the fastest growing sciences

  4. Biomass energy conversion workshop for industrial executives

    Energy Technology Data Exchange (ETDEWEB)

    None

    1979-01-01

    The rising costs of energy and the risks of uncertain energy supplies are increasingly familiar problems in industry. Bottom line profits and even the simple ability to operate can be affected by spiralling energy costs. An often overlooked alternative is the potential to turn industrial waste or residue into an energy source. On April 9 and 10, 1979, in Claremont, California, the Solar Energy Research Institute (SERI), the California Energy Commission (CEC), and the Western Solar Utilization Network (WSUN) held a workshop which provided industrial managers with current information on using residues and wastes as industrial energy sources. Successful industrial experiences were described by managers from the food processing and forest product industries, and direct combustion and low-Btu gasification equipment was described in detail. These speakers' presentations are contained in this document. Some major conclusions of the conference were: numerous current industrial applications of wastes and residues as fuels are economic and reliable; off-the-shelf technologies exist for converting biomass wastes and residues to energy; a variety of financial (tax credits) and institutional (PUC rate structures) incentives can help make these waste-to-energy projects more attractive to industry. However, many of these incentives are still being developed and their precise impact must be evaluated on a case-by-case basis.

  5. Germanene termination of Ge2Pt crystals on Ge(110)

    NARCIS (Netherlands)

    Bampoulis, Pantelis; Zhang, Lijie; Safaei, A.; van Gastel, Raoul; Poelsema, Bene; Zandvliet, Henricus J.W.

    2014-01-01

    We have investigated the growth of Pt on Ge(1 1 0) using scanning tunneling microscopy and spectroscopy. The deposition of several monolayers of Pt on Ge(1 1 0) followed by annealing at 1100 K results in the formation of 3D metallic Pt-Ge nanocrystals. The outermost layer of these crystals exhibits

  6. Synthesis and characterization of Au@Pt nanoparticles

    Institute of Scientific and Technical Information of China (English)

    ZHAO Dan; WU Gang; XU Boqing

    2005-01-01

    Aucore-Ptshell (Au@Pt) nanoparticles were synthesized at room temperature by reducing K2PtCl6 with hydrogen in the solution containing Au colloids and polyvinylpyrrolidone (PVP). The particles obtained were characterized with UV-Vis, TEM and XPS techniques. UV-Vis spectra show that the surface plasmon absorption feature of Au colloids is significantly reduced with increasing the amount of reduced Pt. TEM images that the metals are found always appear as spherical nanoparticles and their sizes grow apparently due to the reduction of PtCl62- ions, indicating that Pt is deposited from solution onto Au particle surface and forms a Pt-layer with uniform thickness. In the XPS spectra, the signals of Au metal decrease due to the reductive deposition of Pt on the surface of the Au colloids. UV-Vis and XPS data are consistent in showing that when the amount of Pt in the AuPt colloids is increased to reach an overall atomic ratio of Pt/Au=2, the Pt deposits form a shell covering completely the surface of Au particles, demonstrating the core-shell structure of the synthesized AuPt particles.

  7. Structure dependence of Pt surface activated ammonia oxidation

    Energy Technology Data Exchange (ETDEWEB)

    Santen, R A van; Offermans, W K [Schuit Institute of Catalysis, Laboratory of Inorganic Chemistry and Catalysis, Department of Chemical Engineering and Chemistry, Eindhoven University of Technology, PO Box 513, 5600 MB Eindhoven (Netherlands); Ricart, J M; Novell-Leruth, G [Department of Chemical Physics and Inorganic Chemistry, University Rovira I Virgili, C/ Marcel.lI Domingo s/n, 43007 Tarragona (Spain); Perez-RamIrez, J [Institute of Chemical Research of Catalonia (ICIQ) and Catalan, Institution for Research and Advanced Studies (ICREA), Avinguda Paisos Catalans 16, 43007, Tarragona (Spain)], E-mail: r.a.v.santen@tue.nl

    2008-06-01

    Computational advances that enable the prediction of the structures and the energies of surface reaction intermediates are providing essential information to the formulation of theories of surface chemical reactivity. In this contribution this is illustrated for the activation of ammonia by coadsorbed oxygen and hydroxyl on the Pt(111), Pt(100), and Pt(211) surfaces.

  8. Magnetic Properties and Nanostructures of FePtCu:C Thin Films with FePt Underlayers

    Institute of Scientific and Technical Information of China (English)

    JIN Ling-Fang; YAN Ming-Lang

    2007-01-01

    Magnetic properties and nanostructures of FePtCu:C thin films with FePt underlayers (ULs) are studied. The effect of FePt ULs on the orientation and magnetic properties of the thin films are investigated by adjusting FePt UL thicknesses from 2nm to 14nm. X-ray diffraction (XRD) scans reveal that the orientation of the films is dependent on FePt UL thickness. For a 5-nm FePtCu:C nanocomposite thin film with a 2-nm FePt UL, the coercivity is 6.5 KOe, the correlation length is 59nm, the desired face-centred-tetragonal (fct) ordered structure [L10 phase] is formed and the c axis normal to the film plane [(001) texture] is obtained. These results indicate that the better orientation and magnetic properties of the films can be tuned by decreasing the thickness of the FePt UL.

  9. Analisis Postur Kerja Aktivitas Pengangkatan Karung di PT. Indofood CBP Sukses Makmur Tbk. Cabang Makassar

    Directory of Open Access Journals (Sweden)

    Arminas Arminas

    2017-05-01

    Full Text Available PT. Indofood CBP Sukses Makmur Tbk is a company that works in the field of food processing industry which produces instant noodles, Indomie. At this company, human resource management gives a significant effect on the production sustainability and development. The observation that conducted in PT. Indofood CBP indicates that loading and delivering process are still using the manual procedure which uses human power with loading capacity around 25 kg. The observation focus on two working movement elements used by the screw machine workers consists of bending over when lifting and pouring the wheat flour sack resulted in worker’s frequent complaints related to the waist and backbone problems. The objective of this research is to discover the risk arising from lifting and delivering techniques used by the screw machine workers in PT. Indofood Sukses Makmur Tbk., then analyze the worker’s workload based on the observation result. Rapid Entire Body Assessment (REBA method was used to analyze the data and concluded that lifting and pouring procedures used by the screw machinery workers in PT. Indofood CBP have a high risk of injury since the REBA scores of both activities is 5 or on the third level. This score means that immediate improvement on the working system is needed.

  10. A label-free colorimetric aptasensor for simple, sensitive and selective detection of Pt (II) based on platinum (II)-oligonucleotide coordination induced gold nanoparticles aggregation.

    Science.gov (United States)

    Fan, Daoqing; Zhai, Qingfeng; Zhou, Weijun; Zhu, Xiaoqing; Wang, Erkang; Dong, Shaojun

    2016-11-15

    Herein, a gold nanoparticles (AuNPs) based label-free colorimetric aptasensor for simple, sensitive and selective detection of Pt (II) was constructed for the first time. Four bases (G-G mismatch) mismatched streptavidin aptamer (MSAA) was used to protect AuNPs from salt-induced aggregation and recognize Pt (II) specifically. Only in the presence of Pt (II), coordination occurs between G-G bases and Pt (II), leading to the activation of streptavidin aptamer. Streptavidin coated magnetic beads (MBs) were used as separation agent to separate Pt (II)-coordinated MSAA. The residual less amount of MSAA could not efficiently protect AuNPs anymore and aggregation of AuNPs will produce a colorimetric product. With the addition of Pt (II), a pale purple-to-blue color variation could be observed by the naked eye. A detection limit of 150nM and a linear range from 0.6μM to 12.5μM for Pt (II) could be achieved without any amplification.

  11. Catalyst Architecture for Stable Single Atom Dispersion Enables Site-Specific Spectroscopic and Reactivity Measurements of CO Adsorbed to Pt Atoms, Oxidized Pt Clusters, and Metallic Pt Clusters on TiO2.

    Science.gov (United States)

    DeRita, Leo; Dai, Sheng; Lopez-Zepeda, Kimberly; Pham, Nicholas; Graham, George W; Pan, Xiaoqing; Christopher, Phillip

    2017-10-11

    Oxide-supported precious metal nanoparticles are widely used industrial catalysts. Due to expense and rarity, developing synthetic protocols that reduce precious metal nanoparticle size and stabilize dispersed species is essential. Supported atomically dispersed, single precious metal atoms represent the most efficient metal utilization geometry, although debate regarding the catalytic activity of supported single precious atom species has arisen from difficulty in synthesizing homogeneous and stable single atom dispersions, and a lack of site-specific characterization approaches. We propose a catalyst architecture and characterization approach to overcome these limitations, by depositing ∼1 precious metal atom per support particle and characterizing structures by correlating scanning transmission electron microscopy imaging and CO probe molecule infrared spectroscopy. This is demonstrated for Pt supported on anatase TiO2. In these structures, isolated Pt atoms, Ptiso, remain stable through various conditions, and spectroscopic evidence suggests Ptiso species exist in homogeneous local environments. Comparing Ptiso to ∼1 nm preoxidized (Ptox) and prereduced (Ptmetal) Pt clusters on TiO2, we identify unique spectroscopic signatures of CO bound to each site and find CO adsorption energy is ordered: Ptiso ≪ Ptmetal atoms bonded to TiO2 and that Ptiso exhibits optimal reactivity because every atom is exposed for catalysis and forms an interfacial site with TiO2. This approach should be generally useful for studying the behavior of supported precious metal atoms.

  12. Concave Pd-Pt Core-Shell Nanocrystals with Ultrathin Pt Shell Feature and Enhanced Catalytic Performance.

    Science.gov (United States)

    Zhang, Ying; Bu, Lingzheng; Jiang, Kezhu; Guo, Shaojun; Huang, Xiaoqing

    2016-02-10

    One-pot creation of unique concave Pd-Pt core-shell polyhedra has been developed for the first time using an efficient approach. Due to the concave feature and ultrathin Pt shell, the created Pd-Pt core-shell polyhedra exhibit enhanced catalytic performance in both the electrooxidation of methanol and hydrogenation of nitrobenzene, as compared with commercial Pt black and Pd black catalysts. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  13. Insights on the SO2 Poisoning of Pt3Co/VC and Pt/VC Fuel Cell Catalysts

    Science.gov (United States)

    2010-01-01

    stripping voltammetry and underpotential deposition (upd) of copper adatoms. Then the performance of PEMFC cathodes employing 30wt.% Pt3Co/VC and 50wt.% Pt/VC...atoms (Pt and Cu atomic radii are 0.139 and 0.128nm, respectively [15]) makes copper underpotential deposition a perfect tool for evaluating the plat...the surface area of Pt3Co/VC catalyst is rigorously characterized by hydrogen adsorption,CO stripping voltammetry and under potential deposition (upd

  14. Emerging pesticide residue issues and analytical approaches.

    Science.gov (United States)

    Fintschenko, Yolanda; Krynitsky, Alexander J; Wong, Jon W

    2010-05-26

    The 46th Annual Florida Pesticide Residue Workshop of 2009 (FPRW 2009) held in St. Pete Beach, FL, is the latest in an annual tradition drawing scientists from U.S. federal and state government laboratories, industry, and other laboratories worldwide. In 2009, selected FPRW presenters were invited to contribute to this special issue of the Journal of Agricultural and Food Chemistry with a section devoted to emerging pesticide residue issues and analytical approaches. What follows is the written record of what should become a scientific conversation launched at FPRW 2009. There are two distinct approaches to organic residue analysis: instrumental methods and assays. In much of the world, scientists primarily rely on laboratories equipped with instrumentation for analysis, usually gas chromatography and liquid chromatography with some type of selective detector. In the discussion of instrumental approaches, the focus is on chromatography with mass spectrometry as a detection method. Approaches such as biomonitoring and assays fall outside the traditional instrumental method approach to residue analysis. Assays that do not require laboratory equipment are of greater interest for screening and are well-suited to field use. Regardless of the analytical method, the success of multiresidue analysis relies on the appropriate choice of sample preparation and cleanup methodologies. Many new sample preparation and cleanup approaches used for pesticide and other small molecule contaminant residue analyses in a variety of complex sample matrices are discussed in this special issue. The goal of these approaches is to reduce overall analysis time and solvent consumption without compromising the analytical results.

  15. Optimización del Proceso de Remoción de Metales Pesados de Agua Residual de la Industria Galvánica por Precipitación Química Optimization of the Removal Processs of Heavy Metals from Raw Water of Galvanic Industry by Chemical Precipitation

    Directory of Open Access Journals (Sweden)

    Eduardo Soto

    2006-01-01

    Full Text Available Se han estudiado las condiciones óptimas requeridas para remover metales pesados del agua residual de una industria galvánica, que contiene cromo (435 mg/L, zinc (720 mg/L, hierro (168 mg/L y níquel (24 mg/L. Se usó agua preparada en el laboratorio (agua sintética y agua de la industria misma (agua cruda. El tratamiento se hizo mediante precipitación química, usando sosa para ajustar el pH y cloruro férrico como aditivo coagulante en un equipo de prueba de jarras. Las condiciones óptimas encontradas usando el agua sintética fueron: 7 minutos para el tiempo de floculación, 18 rpm para la velocidad de agitación y 11.8 mL para la dosis de coagulante. Para el agua cruda fueron: 9.5 minutos para el tiempo de floculación, 30 rpm para la velocidad de agitación y 5.2 mL para la dosis de coagulante. Las condiciones de tratamiento fueron diferentes para el agua residual cruda, ya que el agua residual cruda contiene otros contaminantes, los cuales sobrecargan la superficie coloidal, esto afecta el proceso de floculaciónThe aim of this research was to obtain the optimum conditions to remove heavy metals from wastewaters of the galvanic industry, which contain chromium (435 mg/L, zinc (720 mg/L, iron (168 mg/L and nickel (24 mg/L. The treatment was made by chemical precipitation using caustic soda to set pH and ferric chloride like coagulant aid in jar test. The responses to optimize are: flocculation time, stirring speed and coagulant dose. The optimum conditions to remove heavy metals from synthetic wastewater was, flocculation time: 7 minutes, stirring speed: 18 rpm, coagulant dose: 11.8 mL and flocculation time: 9.5 minutes,stirring speed: 30 rpm, coagulant dose: 5.2 mL for raw wastewater. The treatment conditions were different for the raw wastewater because the raw wastewater contains other pollutants which over charge the colloidal surface and affects the flocculation processes

  16. Kansas timber industry: an assessment of timber product output and use, 2009

    Science.gov (United States)

    David E. Haugen

    2013-01-01

    Presents recent Kansas forest industry trends; production and receipts of industrial roundwood; and production of saw logs and other products in 2009. Logging residue generated from timber harvest operations is reported, as well as wood and bark residue generated at primary wood-using mills and disposition of mill residues.

  17. Kansas timber industry--an assessment of timber product output and use, 2003

    Science.gov (United States)

    William H., IV Reading; David L. Bruton

    2007-01-01

    Discusses recent forest industry trends in Kansas; reports production and receipts of industrial roundwood by product, species, and county in 2003. Also reports on logging residue, on wood and bark residue generated at primary wood-using mills, and on disposition of mill residues.

  18. North Dakota timber industry: an assessment of timber product output and use, 2009

    Science.gov (United States)

    David E. Haugen; Robert A. Harsel

    2013-01-01

    Presents recent North Dakota forest industry trends; production and receipts of industrial roundwood; and production of saw logs and other products in 2009. Logging residue generated from timber harvest operations is reported, as well as wood and bark residue generated at primary wood-using mills and disposition of mill residues.

  19. Maryland timber industry: an assessment of timber product output and use, 2008

    Science.gov (United States)

    Brian F. Walters; Daniel R. Rider; Ronald J. Piva

    2012-01-01

    Presents recent Maryland forest industry trends; production and receipts of industrial roundwood; and production of saw logs, veneer logs, pulpwood, and other products in 2008. Logging residue generated from timber harvest operations is reported, as well as wood and bark residue generated at primary wood-using mills and disposition of mill residues.

  20. Minnesota timber industry: an assessment of timber product output and use, 2007

    Science.gov (United States)

    David E. Haugen; Keith. Jacobson

    2012-01-01

    Presents recent Minnesota forest industry trends; production and receipts of industrial roundwood; and production of saw logs, veneer logs, pulpwood, and other products in 2007. Logging residue generated from timber harvest operations is reported, as well as wood and bark residue generated at primary wood-using mills and disposition of mill residues.

  1. South Dakota timber industry: an assessment of timber product output and use, 2009

    Science.gov (United States)

    Ronald J. Piva; Gregory J. Josten

    2013-01-01

    Presents recent South Dakota forest industry trends; production and receipts of industrial roundwood; and production of saw logs, veneer logs, pulpwood, and other products in 2009. Logging residue generated from timber harvest operations is reported, as well as wood and bark residue generated at primary wood-using mills and disposition of mill residues.

  2. Wisconsin timber industry: an assessment of timber product output and use, 2008

    Science.gov (United States)

    David E. Haugen

    2013-01-01

    Presents recent Wisconsin forest industry trends; production and receipts of industrial roundwood; and production of saw logs, and other products in 2008. Logging residue generated from timber harvest operations is reported, as well as wood and bark residue generated at primary wood-using mills and disposition of mill residues.

  3. Missouri timber industry: an assessment of timber product output and use, 2009

    Science.gov (United States)

    Ronald J. Piva; Thomas B. Treiman

    2012-01-01

    Presents recent Missouri forest industry trends; production and receipts of industrial roundwood; and production of saw logs, veneer logs, pulpwood, and other products in 2009. Logging residue generated from timber harvest operations is reported, as well as wood and bark residue generated at primary wood-using mills and disposition of mill residues.

  4. Nebraska timber Industry--an assessment of timber product output and use, 2006

    Science.gov (United States)

    Ronald J. Piva; Dennis M. Adams

    2008-01-01

    Presents recent Nebraska forest industry trends; production and receipts of industrial roundwood; and production of saw logs, veneer logs, excelsior/shavings, and other products in 2006. Logging residue generated from timber harvest operations is reported, as well as wood and bark residue generated at primary wood-using mills and disposition of mill residues.

  5. Minnesota timber industry--an assessment of timber product output and use, 2004

    Science.gov (United States)

    William H., IV. Reading; Keith Jacobson

    2008-01-01

    Discusses recent forest industry trends in Minnesota; reports production and receipts of industrial roundwood by product, species, and county in 2004. Also reports on logging residue, on wood and bark residue generated at primary wood-using mills, and on disposition of mills residue.

  6. Indiana timber industry: an assessment of timber product output and use, 2008

    Science.gov (United States)

    Brian F. Walters; Jeff Settle; Ronald J. Piva

    2012-01-01

    Presents recent Indiana forest industry trends; production and receipts of industrial roundwood; and production of saw logs, veneer logs, pulpwood, and other products in 2008. Logging residue generated from timber harvest operations is reported, as well as wood and bark residue generated at primary wood-using mills and disposition of mill residues.

  7. Michigan timber industry: an assessment of timber product output and use, 2006

    Science.gov (United States)

    Ronald J. Piva; Anthony K. Weatherspoon

    2010-01-01

    Presents recent Michigan forest industry trends; production and receipts of industrial roundwood; and production of saw logs, veneer logs, pulpwood, and other products in 2006. Logging residue generated from timber harvest operations is reported, as well as wood and bark residue generated at primary wood-using mills and disposition of mill residues.

  8. Utilização de Resíduos Gerados por Indústria do Setor Sucroalcoleiro, Pela RAUDI Indústria e Comércio LTDA, na Produção de Bicarbonato de Sódio. = Use of Residues Generated for the Sugar-Alcohol Industry Sector, by The RAUDI Industry and Commerce Limited, in the Sodium Bicarbonate Production.

    Directory of Open Access Journals (Sweden)

    Frederico F. da Silva

    2008-07-01

    Full Text Available A consciência ecológica está intimamente ligada à preservação do meio ambiente. A importância da preservação dos recursos naturais passou a ser preocupação mundial e nenhum país pode eximir-se de sua responsabilidade. Essa necessidade de proteção do ambiente é antiga e surgiu quando o homem passou a valorizar a natureza, mas não de maneira tão acentuada como nos dias de hoje. Esse trabalho tem como objetivo, passar ao leitor como é possível a utilização de resíduos na obtenção de novos produtos ecologicamente corretos, como o uso de resíduos poluentes de uma usina de álcool transformando-os em matéria prima no processo de fabricação do bicarbonato de sódio. = The ecological conscience is intimately linked to the preservation of the environment. The importance of the preservation of the natural resources became a world-wide concern and no country can be exempted of its responsibility. This necessity of protection of the environment is not a new thing and appeared when man started to value nature, but not in an accentuated way as nowadays. This work has as objective, to inform the reader as to the use of residues in the attainment of new ecologically correct products possible, as the use of pollutant residues of an alcohol plant transforming them into substance in the process of manufacturing sodium bicarbonate.

  9. The inclusion of weld residual stress in fracture margin assessments of embrittled nuclear reactor pressure vessels

    Energy Technology Data Exchange (ETDEWEB)

    Dickson, T.L.; Bass, B.R.; McAfee, W.J.

    1998-01-01

    Analyses were performed to determine the impact of weld residual stresses in a reactor pressure vessel (RPV) on (1) the generation of pressure temperature (P-T) curves required for maintaining specified fracture prevention margins during nuclear plant startup and shutdown, and (2) the conditional probability of vessel failure due to pressurized thermal shock (PTS) loading. The through wall residual stress distribution in an axially oriented weld was derived using measurements taken from a shell segment of a canceled RPV and finite element thermal stress analyses. The P-T curve derived from the best estimate load analysis and a t / 8 deep flaw, based on K{sub Ic}, was less limiting than the one derived from the current methodology prescribed in the ASME Boiler and Pressure Vessel Code. The inclusion of the weld residual stresses increased the conditional probability of cleavage fracture due to PTS loading by a factor ranging from 2 to 4.

  10. One-Step Synthesis of Pt/Graphene Composites from Pt Acid Dissolved Ethanol via Microwave Plasma Spray Pyrolysis

    Science.gov (United States)

    Jo, Eun Hee; Chang, Hankwon; Kim, Sun Kyung; Choi, Ji-Hyuk; Park, Su-Ryeon; Lee, Chong Min; Jang, Hee Dong

    2016-09-01

    Pt nanoparticles-laden graphene (Pt/GR) composites were synthesized in the gas phase from a mixture of ethanol and Pt precursor by microwave plasma spray pyrolysis. The morphology of Pt/GR composites has the shape of wrinkled sheets of paper, while Pt nanoparticles (Pt NPs) that are less than 2.6 nm in the mean diameter are uniformly well deposited on the surface of GR sheets stacked in only three layers. The Pt/GR composite prepared with 20 wt% of Pt had the highest specific surface area and electrochemical surface area of up to 402 m2 g-1 and 77 m2 g-1 (Pt), respectively. In addition, the composite showed superior electrocatalytic activity compared with commercial Pt-carbon black. The excellent electrocatalytic activity was attributed to the high specific surface area and electrochemical surface area of the Pt/GR composite directly produced by microwave plasma spray pyrolysis. Thus, it is clearly expected that the Pt/GR composite is a promising material for DMFC catalysts.

  11. Surface enrichment of Pt in Ga2O3 films grown on liquid Pt/Ga alloys

    Science.gov (United States)

    Grabau, Mathias; Krick Calderón, Sandra; Rietzler, Florian; Niedermaier, Inga; Taccardi, Nicola; Wasserscheid, Peter; Maier, Florian; Steinrück, Hans-Peter; Papp, Christian

    2016-09-01

    The formation of surface Ga2O3 films on liquid samples of Ga, and Pt-Ga alloys with 0.7 and 1.8 at.% Pt was examined using near-ambient pressure (NAP) X-ray photoelectron spectroscopy (XPS). Thickness, composition and growth of the oxide films were deduced as a function of temperature and Pt content of the alloys, in ultra-high vacuum and at oxygen pressures of 3 × 10- 7, 3 × 10- 3 and 1 mbar. We examined oxide layers up to a thickness of 37 Å. Different growth modes were found for oxidation at low and high pressures. The formed Ga2O3 oxide films showed an increased Pt content, while the pristine GaPt alloy showed a surface depletion of Pt at the examined temperatures. Upon growth of Ga2O3 on Pt/Ga alloys a linear increase of Pt content was observed, due to the incorporation of 3.6 at.% Pt in the Ga2O3. The Pt content in Ga2O3, at the examined temperatures and bulk Pt concentrations is found to be independent of pressure, temperature and the nominal Pt content of the metallic alloy.

  12. Asymmetric magnetic bubble expansion under in-plane field in Pt/Co/Pt : Effect of interface engineering

    NARCIS (Netherlands)

    Lavrijsen, R.; Hartmann, D. M. F.; van den Brink, Ton; Yin, Y.; Barcones, B.; Duine, R. A.|info:eu-repo/dai/nl/304830127; Verheijen, M. A.; Swagten, H. J. M.; Koopmans, B.

    2015-01-01

    We analyze the impact of growth conditions on the asymmetric magnetic bubble expansion under an in-plane field in ultrathin Pt/Co/Pt films. Specifically, using sputter deposition, we vary the Ar pressure during the growth of the top Pt layer. This induces a large change in the interfacial structure

  13. Asymmetric magnetic bubble expansion under in-plane field in Pt/Co/Pt : Effect of interface engineering

    NARCIS (Netherlands)

    Lavrijsen, R.; Hartmann, D. M. F.; van den Brink, Ton; Yin, Y.; Barcones, B.; Duine, R. A.; Verheijen, M. A.; Swagten, H. J. M.; Koopmans, B.

    2015-01-01

    We analyze the impact of growth conditions on the asymmetric magnetic bubble expansion under an in-plane field in ultrathin Pt/Co/Pt films. Specifically, using sputter deposition, we vary the Ar pressure during the growth of the top Pt layer. This induces a large change in the interfacial structure

  14. Covariant Residual Entropy

    CERN Document Server

    Hubeny, Veronika E

    2014-01-01

    A recently explored interesting quantity in AdS/CFT, dubbed 'residual entropy', characterizes the amount of collective ignorance associated with either boundary observers restricted to finite time duration, or bulk observers who lack access to a certain spacetime region. However, the previously-proposed expression for this quantity involving variation of boundary entanglement entropy (subsequently renamed to 'differential entropy') works only in a severely restrictive context. We explain the key limitations, arguing that in general, differential entropy does not correspond to residual entropy. Given that the concept of residual entropy as collective ignorance transcends these limitations, we identify two correspondingly robust, covariantly-defined constructs: a 'strip wedge' associated with boundary observers and a 'rim wedge' associated with bulk observers. These causal sets are well-defined in arbitrary time-dependent asymptotically AdS spacetimes in any number of dimensions. We discuss their relation, spec...

  15. Industrial Communications.

    Science.gov (United States)

    Lindsay, Dan

    Intended for seniors planning a career in industry as skilled laborers, this specialized course in Industrial Communications offers the student basic communications skills which he will need in his work and in his daily life. Since class activities center around short, factual oral reports, class size will be limited to 20, providing a maximum of…

  16. Pt Ru/C electrocatalysts prepared using electron beam irradiation

    Energy Technology Data Exchange (ETDEWEB)

    Silva, Dionisio Furtunato da; Oliveira Neto, Almir; Pino, Eddy Segura; Brandalise, Michele; Linardi, Marcelo; Spinace, Estevam Vitorio [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil)]. E-mail: espinace@ipen.br

    2007-10-15

    Pt Ru/C electrocatalysts (carbon-supported Pt Ru nanoparticles) were prepared submitting water/ethylene glycol mixtures containing Pt(IV) and Ru(III) ions and the carbon support to electron beam irradiation. The electrocatalysts were characterized by energy dispersive X ray analysis (EDX), X ray diffraction (XRD) and cyclic voltammetry and tested for methanol electro-oxidation aiming fuel cell application. The obtained Pt Ru/C electrocatalysts showed superior performance for methanol electro-oxidation at room temperature compared to commercial Pt Ru/C electrocatalyst. (author)

  17. Residual-stress measurements

    Energy Technology Data Exchange (ETDEWEB)

    Ezeilo, A.N.; Webster, G.A. [Imperial College, London (United Kingdom); Webster, P.J. [Salford Univ. (United Kingdom)

    1997-04-01

    Because neutrons can penetrate distances of up to 50 mm in most engineering materials, this makes them unique for establishing residual-stress distributions non-destructively. D1A is particularly suited for through-surface measurements as it does not suffer from instrumental surface aberrations commonly found on multidetector instruments, while D20 is best for fast internal-strain scanning. Two examples for residual-stress measurements in a shot-peened material, and in a weld are presented to demonstrate the attractive features of both instruments. (author).

  18. Decomposition of residue currents

    OpenAIRE

    Andersson, Mats; Wulcan, Elizabeth

    2007-01-01

    Given a submodule $J\\subset \\mathcal O_0^{\\oplus r}$ and a free resolution of $J$ one can define a certain vector valued residue current whose annihilator is $J$. We make a decomposition of the current with respect to Ass$(J)$ that correspond to a primary decomposition of $J$. As a tool we introduce a class of currents that includes usual residue and principal value currents; in particular these currents admit a certain type of restriction to analytic varieties and more generally to construct...

  19. Sharing Residual Liability

    DEFF Research Database (Denmark)

    Carbonara, Emanuela; Guerra, Alice; Parisi, Francesco

    2016-01-01

    Economic models of tort law evaluate the efficiency of liability rules in terms of care and activity levels. A liability regime is optimal when it creates incentives to maximize the value of risky activities net of accident and precaution costs. The allocation of primary and residual liability...... allows policy makers to induce parties to undertake socially desirable care and activity levels. Traditionally, tort law systems have assigned residual liability either entirely on the tortfeasor or entirely on the victim. In this paper, we unpack the cheapest-cost-avoider principle to consider...

  20. Industry honoured

    CERN Multimedia

    2008-01-01

    CERN has organised a day to thank industry for its exceptional contributions to the LHC project. Lucio Rossi addresses CERN’s industrial partners in the Main Auditorium.The LHC inauguration provided an opportunity for CERN to thank all those who have contributed to transforming this technological dream into reality. Industry has been a major player in this adventure. Over the last decade it has lent its support to CERN’s teams and participating institutes in developing, building and assembling the machine, its experiments and the computing infrastructure. CERN involved its industrial partners in the LHC inauguration by organising a special industry prize-giving day on 20 October. Over 70 firms accepted the invitation. The firms not only made fundamental contributions to the project, but some have also supported LHC events in 2008 and the inauguration ceremony through generous donations, which have been coordinated by Carmen Dell’Erba, who is responsible for secu...

  1. Half-Lantern Pt(II and Pt(III Complexes. New Cyclometalated Platinum Derivatives

    Directory of Open Access Journals (Sweden)

    Violeta Sicilia

    2014-08-01

    Full Text Available The divalent complex [{Pt(bzq(μ-L}2] (1 [Hbzq = benzo[h]quinolone, HL = CF3C4H2N2SH: 4-(trifluoromethylpyrimidine-2-thiol] was obtained from equimolar amounts of [Pt(bzq(NCMe2]ClO4 and 4-(trifluoromethylpyrimidine-2-thiol with an excess of NEt3. The presence of a low intensity absorption band at 486 nm (CH2Cl2, assignable to a metal-metal-to-ligand charge transfer transition (1MMLCT [dσ*(Pt2→π*(bzq], is indicative of the existence of two platinum centers located in close proximity because the rigidity of the half-lantern structure allows the preservation of these interactions in solution. Compound 1 undergoes two-electron oxidation upon treatment with halogens X2 (X2: Cl2, Br2 or I2 to give the corresponding dihalodiplatinum (III complexes [{Pt(bzq(μ-LX}2] (L = CF3C4H2N2S-κN,S; X: Cl 2, Br 3, I 4. Complexes 2–4 were also obtained by reaction of 1 with HX (molar ratio 1:2, 10% excess of HX in THF with yields of about 80% and compound 2 was also obtained by reaction of [{Pt(bzq(μ-Cl}2] with HL (4-(trifluoromethylpyrimidine-2-thiol in molar ratio 1:2 in THF, although in small yield. The X-ray structures of 2 and 3 confirmed the half-lantern structure and the anti configuration of the molecules. Both of them show Pt–Pt distances (2.61188(15 Å 2, 2.61767(16 Å 3 in the low range of those observed in Pt2(III,IIIX2 half-lantern complexes.

  2. KINERJA INDUSTRI KAYU LAPIS DI KALIMANTAN SELATAN MENUJU EKOEFISIENSI Performance of Plywood Industry in South Kalimantan Towards Ecoefficiency

    Directory of Open Access Journals (Sweden)

    Darni Subari

    2016-09-01

    Full Text Available Penelitian ini bertuiuan untuk mendapatkan gambaran umum kineria industri lapis di Kalimantan Selatan saat ini.  Penelitian dilaksanakan dengan mengamati data industri kayu lapis di Kalsel saat ini dan detail pengamatan pada 3 (tiga industri, yaitu PT. SST, PT. WTU dan PT. BIC. Hasil penelitian menunjukkan bahwa industri kayu lapis umumnva memiliki kesamaan dalam proses dan mesin produksinya. Dari ke 3 industri kayu lapis yang diteliti vang membedakan adalah macam produk dan bahan baku kayunva. Efektifitas mesin dan proses masih cukup tinggi dengan rata-rata efisiensi mesin > 90% dan rendemen rata-rata ± 64%. Dalam penanganan aspek lingkungan, industri kavu lapis mempunyai kesamaan dalam hal penanganan limbahnva.  Penanganan limbah kayu dengan memanfaatkan kembali sebagian limbah kayu sebagai produk blockboard dan sisanva sebagai bahan bakar boiler. Untuk penanganan limbah cair. yaitu menggunakan kolam treatment dengan pencapaian mutu mengacu SK Gubernur Kalsel Nomor 036 tahun 2008 tentang Baku Mutu Limbah Cair bagi Kegiatan Industri dan penanganan limbah debu dengan teknologi penyedot debu dan filter pada cerobong, sehingga emisi memenuhi baku mutu (SK Gubernur Kalsel Nomor 70 tahun 2008 tentang Baku Mutu Emisi. Kata kunci: industri plywood, proses produksi, hasil dan kualitas, limbah cair

  3. Direct determination of the ionization energies of PtC, PtO, and PtO2 with VUV radiation.

    Science.gov (United States)

    Citir, Murat; Metz, Ricardo B; Belau, Leonid; Ahmed, Musahid

    2008-10-02

    Photoionization efficiency curves were measured for gas-phase PtC, PtO, and PtO2 using tunable vacuum ultraviolet (VUV) radiation at the Advanced Light Source. The molecules were prepared by laser ablation of a platinum tube, followed by reaction with CH4 or N2O and supersonic expansion. These measurements provide the first directly measured ionization energy for PtC, IE(PtC) = 9.45 +/- 0.05 eV. The direct measurement also gives greatly improved ionization energies for the platinum oxides, IE(PtO) = 10.0 +/- 0.1 eV and IE(PtO2) = 11.35 +/- 0.05 eV. The ionization energy connects the dissociation energies of the neutral and cation, leading to greatly improved 0 K bond dissociation energies for the neutrals: D0(Pt-C) = 5.95 +/- 0.07 eV, D0(Pt-O) = 4.30 +/- 0.12 eV, and D0(OPt-O) = 4.41 +/- 0.13 eV, as well as enthalpies of formation for the gas-phase molecules DeltaH(0)(f,0)(PtC(g)) = 701 +/- 7 kJ/mol, DeltaH(0)(f,0)(PtO(g)) = 396 +/- 12 kJ/mol, and DeltaH(0)(f,0)(PtO2(g)) = 218 +/- 11 kJ/mol. Much of the error in previous Knudsen cell measurements of platinum oxide bond dissociation energies is due to the use of thermodynamic second law extrapolations. Third law values calculated using statistical mechanical thermodynamic functions are in much better agreement with values obtained from ionization energies and ion energetics. These experiments demonstrate that laser ablation production with direct VUV ionization measurements is a versatile tool to measure ionization energies and bond dissociation energies for catalytically interesting species such as metal oxides and carbides.

  4. Evaluasi Sistem Informasi Penjualan PT SPNS

    Directory of Open Access Journals (Sweden)

    Anderes Gui

    2010-06-01

    Full Text Available The purpose of this paper is to identify and analyze problems that occur in information systems sales PT SPNS. It also serves to control the management and control of applications running well so it can produce accurate information for decision making. The method used is book study method and field study. Study was done by reading library books, scientific papers and other sources, while the field study was done by observation, interviews, and questionnaires. The result of the evaluation is derived from the respective strengths and weaknesses - each control. Weaknesses are found, the findings presented in the form of a matrix that contains the findings and recommendations as a matter of risk remedial action. Conclusions obtained from the audit for security control, operations, limitations, input and output is good enough because it can satisfy and support the sales activities of PT SPNS.

  5. Revisiting the Optical PT-Symmetric Dimer

    Directory of Open Access Journals (Sweden)

    José Delfino Huerta Morales

    2016-08-01

    Full Text Available Optics has proved a fertile ground for the experimental simulation of quantum mechanics. Most recently, optical realizations of PT -symmetric quantum mechanics have been shown, both theoretically and experimentally, opening the door to international efforts aiming at the design of practical optical devices exploiting this symmetry. Here, we focus on the optical PT -symmetric dimer, a two-waveguide coupler where the materials show symmetric effective gain and loss, and provide a review of the linear and nonlinear optical realizations from a symmetry-based point of view. We go beyond a simple review of the literature and show that the dimer is just the smallest of a class of planar N-waveguide couplers that are the optical realization of the Lorentz group in 2 + 1 dimensions. Furthermore, we provide a formulation to describe light propagation through waveguide couplers described by non-Hermitian mode coupling matrices based on a non-Hermitian generalization of the Ehrenfest theorem.

  6. Revisiting the optical $PT$-symmetric dimer

    CERN Document Server

    Morales, J D Huerta; López-Aguayo, S; Rodríguez-Lara, B M

    2016-01-01

    Optics has proved a fertile ground for the experimental simulation of quantum mechanics. Most recently, optical realizations of $\\mathcal{PT}$-symmetric quantum mechanics have been shown, both theoretically and experimentally, opening the door to international efforts aiming at the design of practical optical devices exploiting this symmetry. Here, we focus on the optical $\\mathcal{PT}$-symmetric dimer, a two-waveguide coupler were the materials show symmetric effective gain and loss, and provide a review of the linear and nonlinear optical realizations from a symmetry based point of view. We go beyond a simple review of the literature and show that the dimer is just the smallest of a class of planar $N$-waveguide couplers that are the optical realization of Lorentz group in 2+1 dimensions. Furthermore, we provide a formulation to describe light propagation through waveguide couplers described by non-Hermitian mode coupling matrices based on a non-Hermitian generalization of Ehrenfest theorem.

  7. MANFAAT DATA WAREHOUSE PADA PT ABC

    Directory of Open Access Journals (Sweden)

    Evaristus Didik Madyatmadja

    2013-11-01

    Full Text Available The purpose of this paper is to analyze the current system to find out problems faced by the company and propose alternative solutions and generate information needed by management by designing a data warehouse according to the information needs of PT ABC. This research implements analysis and design of data warehouse by Ralph Kimball and Ross cited by Connolly and Begg, known as Nine-Step Methodology. The result obtained is a data warehouse application that may present a multidimensional historical data that can assist the management in decisions. Designing data warehouse at PT ABC makes concise the enterprise data and can be viewed from several dimensions. It helps users analyze data for strategic decision quickly and accurately.

  8. High Activity of Hexagonal Ag/Pt Nanoshell Catalyst for Oxygen Electroreduction

    Directory of Open Access Journals (Sweden)

    Lee Chien-Liang

    2008-01-01

    Full Text Available Abstract Hexagonal Ag/Pt nanoshells were prepared by using a hexagonal Ag nanoplate as the displacement template and by introducing Pt ions. The prepared Ag/Pt nanoshells played the role of an electrocatalyst in an oxygen reduction process. Compared to spherical Pt and Ag/Pt nanoparticles, the hexagonal Ag/Pt nanoshells showed higher activity for oxygen electroreduction.

  9. Ethanol and chemicals from wood residues

    Energy Technology Data Exchange (ETDEWEB)

    Pye, K. [Lignol Innovations Corp., Media, PA (United States)

    2003-07-01

    Climate change mitigation issues have created new business opportunities for the forest products industry in terms of energy and chemicals production from renewable energy sources. Wood residues are currently used as low value solid fuel and for low efficiency liquefaction and gasification. However, wood in general is a poor choice for fuel. It is a much better source for industrial oxychemicals than coal, oil or natural gas. The market for oxychemicals is huge. Typical oxychemicals, which are made from starch and sugar, include acetic acid, ethanol, propanediol, ethylene glycol, acetone, acrylic acid, and glycerol. Wood contains the same glucose found in starch. Biorefining technology makes it possible to extract the glucose from the wood and convert it to oxychemicals. Biorefining separates the major components of woody biomass into cellulose, hemicellulose, lignin and extractives. As a solid fuel, wood residues amount to $35 to $50 of electrical power per dry tonne. However, the value of wood as a purified chemical component is more than $750 per tonne. There is very strong government support in the United States, Canada, the United Kingdom, Europe and Japan to develop biorefining and associated technologies. Canada is considering to invest C$575 million of its Kyoto funding to support fuel ethanol production. This paper described the Organosolv delignification process which uses aqueous ethanol at high temperature to separate wood residues into high value product streams. The characteristics of a Lignol Biorefinery demonstration plant in Miramichi, New Brunswick were described. This new technology offers the lumber industry with new opportunities to increase revenues from under-utilized wood residues. 1 tab., 4 figs.

  10. Relaxor-PT Single Crystal Piezoelectric Sensors

    OpenAIRE

    Xiaoning Jiang; Jinwook Kim; Kyugrim Kim

    2014-01-01

    Relaxor-PbTiO3 piezoelectric single crystals have been widely used in a broad range of electromechanical devices, including piezoelectric sensors, actuators, and transducers. This paper reviews the unique properties of these single crystals for piezoelectric sensors. Design, fabrication and characterization of various relaxor-PT single crystal piezoelectric sensors and their applications are presented and compared with their piezoelectric ceramic counterparts. Newly applicable fields and futu...

  11. Adhesion of metal on metal. The Pt on Co case

    Science.gov (United States)

    Légaré, P.; Castellani, N. J.; Cabeza, G. F.

    2002-01-01

    The adhesion of Pt overlayers in pseudomorphic epitaxy on hcp Co(0 0 0 1) and fcc Co(1 0 0) was investigated with first-principles calculations. This was compared to the adhesion of the Pt surface layers on Pt(1 1 1) and Pt(1 0 0). We show that adhesion can be analyzed by taking into account the interplay between the chemical and structural properties at the interface. The free Pt planes with the bulk Pt-Pt distance are submitted to tensile stress which can be relaxed by 6.6% and 9.1% contraction for the (1 1 1) and (1 0 0) symmetries respectively. This results in equilibrium interatomic distances which are not far from that of the Co substrate. Consequently the stress energy in a pseudomorphic Pt monolayer on a Co substrate is lower than the stress energy of pure Pt(1 1 1) or Pt(1 0 0) surfaces. However, this is at the expense of the Pt chemical reactivity towards the Co substrate. This is in agreement with the general dependence between chemical reactivity and stress of a metal surface.

  12. Spin Hall effects in mesoscopic Pt films with high resistivity

    Science.gov (United States)

    Qin, Chuan; Luo, Yongming; Zhou, Chao; Cai, Yunjiao; Jia, Mengwen; Chen, Shuhan; Wu, Yizheng; Ji, Yi

    2016-10-01

    The energy efficiency of the spin Hall effects (SHE) can be enhanced if the electrical conductivity is decreased without sacrificing the spin Hall conductivity. The resistivity of Pt films can be increased to 150-300 µΩ · cm by mesoscopic lateral confinement, thereby decreasing the conductivity. The SHE and inverse spin Hall effects (ISHE) in these mesoscopic Pt films are explored at 10 K by using the nonlocal spin injection/detection method. All relevant physical quantities are determined in situ on the same substrate, and a quantitative approach is developed to characterize all processes effectively. Extensive measurements with various Pt thickness values reveal an upper limit for the Pt spin diffusion length: {λ\\text{pt}}   ⩽  0.8 nm. The average product of {λ\\text{pt}} and the Pt spin Hall angle {α\\text{H}} is substantial: {α\\text{H}}{λ\\text{pt}}   =  (0.142  ±  0.040) nm for 4 nm thick Pt, though a gradual decrease is observed at larger Pt thickness. The results suggest enhanced spin Hall effects in resistive mesoscopic Pt films.

  13. Srategi The Boston Consulting Group Untuk Memastikan Kesinambungan Produk PT Gudang Garam Tbk Kediri

    Directory of Open Access Journals (Sweden)

    Poniran Poniran

    2013-09-01

    Full Text Available Lingkungan bisnis saat ini meningkat secara kompetitif, setiap perusahaan dituntut untuk memiliki kekuatan untuk bersaing di perdagangan global. PT Gudang Garam sebagai pasar dalam industri tembakau, untuk mempertahankan kondisi ini harus pandai dalam menentukan kebijakan manajemen . Alternatifnya adalah dengan menggunakan Strategi Analisis The Boston Consulting Group, sebuah analisis untuk mengukur pertumbuhan dan  pasar untuk produk SBU. Dengan analisis ini akan diketahui strategi apa yang harus dilakukan untuk mencapai keunggulan biaya serta bagaimana menentukan investasi yang tepat. Hal ini dapat dilihat dari analisis posisi kekuatan dan daya tarik perusahaan. Penelitian ini menggunakan metode deskriptif. Penelitian ini fokus untuk mempelajari (a Produksi (b penjualan (c daya tarik industri (d posisi kompetitif (e atribut produk perusahaan (fpajak/cukai. Penelitian ini dilakukan di perusahaan rokok PT Gudang Garam Tbk . Kediri alamat dengan : Jl . Semampir II / I Semampir Kediri - Indonesia Tel : 0354-682091-7 , fax: 0354-681555. Hasil penelitian menunjukkan bahwa PT. Gudang Garam adalah pimpinan pasar di posisi pangsa pasar tinggi BCG, GE - Mc. Kinsey, menang / kuat pada SKM dan SKT, SKL pada Mean Business, posisi PLC yang menurun untuk SKM, SKT dan SKL sekarang ini. Dengan kondisi seperti ini, penulis memberikan saran untuk perlunya perusahaan melakukan kegiatan yang spesifik, meliputi: (1 memastikan kesetimbangan portofolio melalui peluncuran produk baru yang menarik dan diharapkan mempunyai prospek bagus dalam jangka panjang, mengingat pada umumnya mengalami pengurangan produksi, dan peningkatan pajak, (2 berdasar portofolio produk PT Gudang Garam Tbk sebagian besar mempunyai posisi yang kuat, hal ini menunjukkan keberhasilan iklan produk dalam pandangan konsumen. Meskipun demikian PT Gudang Garam Tbk harus melakukan riset pasar untuk menentukan perubahan yang terjadi di pasar, (3 memaksimalkan pangsa pasar secara keseluruhan produk

  14. Incorporation of metals (Pt-Ni-Ru) in the zeolite ZSM-5 through ion exchange competitive: synthesis and characterization; Incorporacao de metais (Pt-Ni-Ru) na zeolita ZSM-5 atraves da troca ionica competitiva: sintese e caracterizacao

    Energy Technology Data Exchange (ETDEWEB)

    Barbosa, A.S.; Rodrigues, M.G.F., E-mail: antusiasb@hotmail.com [Universidade Federal de Campina Grande (UFCG), PB (Brazil). Departamento de Engenharia Quimica; Grau, J.M. [Instituto de Investigaciones en Catalisis y Petroquimica (INCAPE/FIQ/UNL-CONICET), Santa Fe (Argentina)

    2012-07-01

    Zeolites are very important materials due to their high specific surface area. Moreover, they are suitable for use as catalyst support. Noble metals supported on zeolites have been widely used as catalysts in the petrochemical industry. This paper was prepared and characterized, a powder aiming its use in heterogeneous catalysis. Support was used as ZSM-5 and the method of incorporation of the metals (Ru-PtNi) was competitive ion exchange. The materials (ZSM-5 and Pt-Ni-Ru/ZSM-5) were characterized by spectrophotometry Energy Dispersive X-ray (EDX), X-Ray Diffraction (XRD) and nitrogen physisorption (BET method). Based on the results of X-ray diffraction, it is possible to demonstrate the preservation of the structure of zeolite ZSM-5 after the competitive ion Exchange with metals (Ru-Pt-Ni) and calcination. The dispersion of metals on ZSM-5 did not change the textural characteristics of the zeolite. (author)

  15. Fabrication of monometallic (Co, Pd, Pt, Au) and bimetallic (Pt/Au, Au/Pt) thin films with hierarchical architectures as electrocatalysts

    Science.gov (United States)

    Qiu, Cuicui; Zhang, Jintao; Ma, Houyi

    2010-05-01

    Co thin films with novel hierarchical structures were controllably fabricated by simple electrochemical deposition in the absence of hard and soft templates, which were used as sacrificial templates to further prepare noble metal (Pd, Pt, Au) hierarchical micro/nanostructures via metal exchange reactions. SEM characterization demonstrated that the resulting noble metal thin films displayed hierarchical architectures. The as-prepared noble metal thin films could be directly used as the anode catalysts for the electro-oxidation of formic acid. Moreover, bimetallic catalysts (Pt/Au, Au/Pt) fabricated based on the monometallic Au, Pt micro/nanostructures exhibited the higher catalytic activity compared to the previous monometallic catalysts.

  16. XAS and XMCD studies of magnetic properties modifications of Pt/Co/Au and Pt/Co/Pt trilayers induced by Ga⁺ ions irradiation.

    Science.gov (United States)

    Mazalski, Piotr; Sveklo, Iosif; Kurant, Zbigniew; Ollefs, Katharina; Rogalev, Andrei; Wilhelm, Fabrice; Fassbender, Juergen; Baczewski, Lech Tomasz; Wawro, Andrzej; Maziewski, Andrzej

    2015-05-01

    Magnetic and magneto-optical properties of Pt/Co/Au and Pt/Co/Pt trilayers subjected to 30 keV Ga(+) ion irradiation are compared. In two-dimensional maps of these properties as a function of cobalt thickness and ion fluence, two branches with perpendicular magnetic anisotropy (PMA) for Pt/Co/Pt trilayers are well distinguished. The replacement of the Pt capping layer with Au results in the two branches still being visible but the in-plane anisotropy for the low-fluence branch is suppressed whereas the high-fluence branch displays PMA. The X-ray absorption spectra and X-ray magnetic circular dichroism (XMCD) spectra are discussed and compared with non-irradiated reference samples. The changes of their shapes and peak amplitude, particularly for the high-fluence branch, are related to the modifications of the local environment of Co(Pt) atoms and the etching effects induced by ion irradiation. Additionally, in irradiated trilayers the XMCD measurements at the Pt L2,3-edge reveal an increase of the magnetic moment induced in Pt atoms.

  17. Nonlinear waves in $\\cal PT$-symmetric systems

    CERN Document Server

    Konotop, Vladimir V; Zezyulin, Dmitry A

    2016-01-01

    Recent progress on nonlinear properties of parity-time ($\\cal PT$-) symmetric systems is comprehensively reviewed in this article. $\\cal PT$ symmetry started out in non-Hermitian quantum mechanics, where complex potentials obeying $\\cal PT$ symmetry could exhibit all-real spectra. This concept later spread out to optics, Bose-Einstein condensates, electronic circuits, and many other physical fields, where a judicious balancing of gain and loss constitutes a $\\cal PT$-symmetric system. The natural inclusion of nonlinearity into these $\\cal PT$ systems then gave rise to a wide array of new phenomena which have no counterparts in traditional dissipative systems. Examples include the existence of continuous families of nonlinear modes and integrals of motion, stabilization of nonlinear modes above $\\cal PT$-symmetry phase transition, symmetry breaking of nonlinear modes, distinctive soliton dynamics, and many others. In this article, nonlinear $\\cal PT$-symmetric systems arising from various physical disciplines ...

  18. Tunable Architecture of Rhombic Dodecahedral Pt-Ni Nanoframe Electrocatalysts.

    Energy Technology Data Exchange (ETDEWEB)

    Becknell, Nigel; Son, Yoonkook; Kim, Dohyung; Li, Dongguo; Yu, Yi; Niu, Zhiqiang; Lei, Teng; Sneed, Brian T.; More, Karren L.; Markovic, Nenad M.; Stamenkovic, Vojislav R.; Yang, Peidong

    2017-08-30

    Platinum-based alloys are known to demonstrate advanced properties in electrochemical reactions that are relevant for proton exchange membrane fuel cells and electrolyzers. Further development of Pt alloy electrocatalysts relies on the design of architectures with highly active surfaces and optimized utilization of the expensive elpment, Pt. Here, we show that the three-dimensional Pt anisotropy of Pt-Ni rhombic dodecahedra can be tuned by controlling the ratio between Pt and Ni precursors such that either a completely hollow nanoframe or a new architecture, the excavated nanoframe, can be obtained. The excavated nanoframe showed similar to 10 times higher specific and similar to 6 times higher mass activity for the oxygen reduction reaction than Pt/C, and twice the mass activity of the hollow nanoframe. The high activity is attributed to enhanced Ni content in the near-surface region and the extended two-dimensional sheet structure within the nanoframe that minimizes the number of buried Pt sites.

  19. Highly durable graphene nanoplatelets supported Pt nanocatalysts for oxygen reduction

    Energy Technology Data Exchange (ETDEWEB)

    Shao, Yuyan; Zhang, Sheng; Wang, Chongmin; Nie, Zimin; Liu, Jun; Lin, Yuehe [Pacific Northwest National Laboratory, Richland, WA 99352 (United States); Wang, Yong [Pacific Northwest National Laboratory, Richland, WA 99352 (United States); The Gene and Linda Voiland School of Chemical Engineering and Bioengineering, Washington State University, Pullman, WA 99164 (United States)

    2010-08-01

    We report graphene nanoplatelets (GNPs), which exhibit the advantages of both single-layer graphene and highly graphitic carbon, as a durable alternative support material for Pt nanoparticles for oxygen reduction in fuel cells. Pt nanoparticles are deposited on poly(diallyldimethylammonium chloride) (PDDA)-coated GNP, and characterized with transmission electron microscopy, X-ray diffraction, Raman spectra, and electrochemical tests. Pt/GNP exhibits greatly enhanced electrochemical durability (2-3 times that of Pt/CNT and commercial Etek Pt/C). These are attributed to the intrinsic high graphitization degree of GNP and the enhanced Pt-carbon interaction in Pt/GNP. If considering that GNP can be easily mass produced from graphite, GNP is a promising, low-cost, and durable electrocatalyst support for oxygen reduction in fuel cells. (author)

  20. PT-Symmetric Quantum Electrodynamics and Unitarity

    CERN Document Server

    Milton, Kimball A; Parashar, Prachi; Pourtolami, Nima; Wagner, J

    2012-01-01

    More than 15 years ago, a new approach to quantum mechanics was suggested, in which Hermiticity of the Hamiltonian was to be replaced by invariance under a discrete symmetry, the product of parity and time-reversal symmetry, $\\mathcal{PT}$. It was shown that if $\\mathcal{PT}$ is unbroken, energies were, in fact, positive, and unitarity was satisifed. Since quantum mechanics is quantum field theory in 1 dimension, time, it was natural to extend this idea to higher-dimensional field theory, and in fact an apparently viable version of $\\mathcal{PT}$-invariant quantum electrodynamics was proposed. However, it has proved difficult to establish that the unitarity of the scattering matrix, for example, the K\\"all\\'en spectral representation for the photon propagator, can be maintained in this theory. This has led to questions of whether, in fact, even quantum mechanical systems are consistent with probability conservation when Green's functions are examined, since the latter have to possess physical requirements of ...

  1. Density functional theory studies of the adsorption of ethylene and oxygen on Pt(111) and Pt3Sn(111)

    DEFF Research Database (Denmark)

    Watwe, R.M.; Cortright, R.D.; Mavrikakis, Manos

    2001-01-01

    of pi -bonded ethylene, di-sigma -bonded ethylene, and ethylidyne species are weaker on Pt3Sn(111) than on Pt(111) by 21, 31, and 50 kJ/mol, respectively. Hence, the electronic effect of Sn on the adsorption of ethylene depends on the type of adsorption site, with adsorption on three-fold site weakened......Density functional theory, employing periodic slab calculations, was used to investigate the interactions of ethylene and oxygen with Pt(111) and Pt3Sn(111). The predicted energetics and structures of adsorbed species on Pt(111) are in good agreement with experimental data. The binding energies...

  2. Pt skin on AuCu intermetallic substrate: a strategy to maximize Pt utilization for fuel cells.

    Science.gov (United States)

    Wang, Gongwei; Huang, Bing; Xiao, Li; Ren, Zhandong; Chen, Hao; Wang, Deli; Abruña, Héctor D; Lu, Juntao; Zhuang, Lin

    2014-07-09

    The dependence on Pt catalysts has been a major issue of proton-exchange membrane (PEM) fuel cells. Strategies to maximize the Pt utilization in catalysts include two main approaches: to put Pt atoms only at the catalyst surface and to further enhance the surface-specific catalytic activity (SA) of Pt. Thus far there has been no practical design that combines these two features into one single catalyst. Here we report a combined computational and experimental study on the design and implementation of Pt-skin catalysts with significantly improved SA toward the oxygen reduction reaction (ORR). Through screening, using density functional theory (DFT) calculations, a Pt-skin structure on AuCu(111) substrate, consisting of 1.5 monolayers of Pt, is found to have an appropriately weakened oxygen affinity, in comparison to that on Pt(111), which would be ideal for ORR catalysis. Such a structure is then realized by substituting the Cu atoms in three surface layers of AuCu intermetallic nanoparticles (AuCu iNPs) with Pt. The resulting Pt-skinned catalyst (denoted as Pt(S)AuCu iNPs) has been characterized in depth using synchrotron XRD, XPS, HRTEM, and HAADF-STEM/EDX, such that the Pt-skin structure is unambiguously identified. The thickness of the Pt skin was determined to be less than two atomic layers. Finally the catalytic activity of Pt(S)AuCu iNPs toward the ORR was measured via rotating disk electrode (RDE) voltammetry through which it was established that the SA was more than 2 times that of a commercial Pt/C catalyst. Taking into account the ultralow Pt loading in Pt(S)AuCu iNPs, the mass-specific catalytic activity (MA) was determined to be 0.56 A/mg(Pt)@0.9 V, a value that is well beyond the DOE 2017 target for ORR catalysts (0.44 A/mg(Pt)@0.9 V). These findings provide a strategic design and a realizable approach to high-performance and Pt-efficient catalysts for fuel cells.

  3. 75 FR 43095 - Airworthiness Directives; PIAGGIO AERO INDUSTRIES S.p.A. Model PIAGGIO P-180 Airplanes

    Science.gov (United States)

    2010-07-23

    ... INDUSTRIES S.p.A. Model PIAGGIO P-180 Airplanes AGENCY: Federal Aviation Administration (FAA), Department of... failure of engine oil dipsticks, installed on Pratt & Whitney Canada (P&WC) PT6A66 and PT6A66B engines, were detected on P.180 aeroplanes; such failures, due to moisture penetration into the dipstick...

  4. Designing with residual materials

    NARCIS (Netherlands)

    Walhout, W.; Wever, R.; Blom, E.; Addink-Dölle, L.; Tempelman, E.

    2013-01-01

    Many entrepreneurial businesses have attempted to create value based on the residual material streams of third parties. Based on ‘waste’ materials they designed products, around which they built their company. Such activities have the potential to yield sustainable products. Many of such companies

  5. Sharing Residual Liability

    DEFF Research Database (Denmark)

    Carbonara, Emanuela; Guerra, Alice; Parisi, Francesco

    2016-01-01

    allows policy makers to induce parties to undertake socially desirable care and activity levels. Traditionally, tort law systems have assigned residual liability either entirely on the tortfeasor or entirely on the victim. In this paper, we unpack the cheapest-cost-avoider principle to consider...

  6. Residual stresses within sprayed coatings

    Institute of Scientific and Technical Information of China (English)

    JIANG Yi; XU Bin-shi; WANG Hai-dou

    2005-01-01

    Some important developments of residual stress researches for coating-based systems were studied. The following topics were included the sources of residual stresses in coatings: error analysis of Stoney's equation in the curvature method used for the measurement of coating residual stress, the modeling of residual stress and some analytical models for predicting the residual stresses in coatings. These topics should provide some important insights for the fail-safe design of the coating-based systems.

  7. Characterization of FePt nanoparticles in FePt/C multilayers

    Energy Technology Data Exchange (ETDEWEB)

    Barradas, N.P. E-mail: nunoni@itn.mces.pt; Alves, E.; Babonneau, D

    2004-06-01

    The areal density growth of recording media is expected to reach 100 Gbit/in.{sup 2} within a few years. Such high densities require magnetic grain sizes of 10 nm or less, which is close to the superparamagnetic limit of current media. Therefore, in order to retain thermal stability, it is essential to use a magnetic material with high anisotropy energy. Ordered metallic phases such as FePt and CoPt, which have very large magnetocrystalline anisotropy, are regarded as attractive candidates. We have deposited at different temperatures by ion beam sputtering C/(FePt/C){sub x20} multilayers, with nominal thickness t{sub C}=4 nm and t{sub FePt}=1 nm. The FePt consists of nanoparticles embedded in the C matrix. Using Rutherford backscattering at grazing angles of incidence, we determined the stoichiometry of the nanoparticles, the multilayer periodicity and the nanoparticle height. We compare the results with X-ray reflectivity, grazing incidence small-angle X-ray scattering, and transmission electron microscopy results.

  8. LEAD AND ZINC LEACHING IN SOIL TREATED WITH IRON SMELTING RESIDUES LIXIVIAÇÃO DE CHUMBO E ZINCO EM SOLO TRATADO COM RESÍDUOS DE SIDERURGIA

    Directory of Open Access Journals (Sweden)

    Leônidas Paixão Passos

    2010-10-01

    Full Text Available

    pt-BR" align="JUSTIFY">In order to evaluate the dynamics of Zn and Pb in the soil, a greenhouse experiment was set up in pots filled with soil samples (Typic Hapludox treated with increasing doses of iron smelting residues. It was set under a completely randomized design, in a 3×5 factorial scheme, with three replications, combining three iron smelting residues (mill scale, filter press mud, and phosphate mud, with five doses for each residue (0 t ha-1, 1 t ha-1, 2 t ha-1, 4 t ha-1, and 8 t ha-1. Elephant grass was cultivated during 120 days, followed by common beans, for 75 days. In that period, contents of Zn and Pb were determined in the leachate. No Pb was found in the leachate, but Zn proved to be quite mobile in this soil. In soils treated with mill scale and filter press mud, no risk of groundwater contamination was observed, however, the 8 t ha-1 phosphate mud rate increased Zn contents in the leachate above the maximum allowed by environmental regulations. This fact limits the use of such residue for agricultural purposes. The other two residues should be evaluated in field-scale tests aiming their agricultural use.

    KEY-WORDS: Industrial residue; heavy metal; mill scale; filter press mud; phosphate mud.

    pt-BR" align="JUSTIFY">

  9. Soil carbon storage and stratiifcation under different tillage/residue-management practices in double rice cropping system

    Institute of Scientific and Technical Information of China (English)

    CHEN Zhong-du; ZHANG Hai-lin; S Batsile Dikgwatlhe; XUE Jian-fu; QIU Kang-cheng; TANG Hai-ming; CHEN fu

    2015-01-01

    The importance of soil organic carbon (SOC) sequestration in agricultural soils as climate-change-mitigating strategy has become an area of focus by the scientiifc community in relation to soil management. This study was conducted to determine the temporal effect of different til age systems and residue management on distribution, storage and stratiifcation of SOC, and the yield of rice under double rice (Oryza sativa L.) cropping system in the southern China. A til age experiment was conducted in the southern China during 2005–2011, including plow til age with residue removed (PT0), plow til age with residue retention (PT), rotary til age with residue retention (RT), and no-til with residue retention on the surface (NT). The soil samples were obtained at the harvesting of late rice in October of 2005, 2007 and 2011. Multiple-year residue return application signiifcantly increased rice yields for the two rice-cropping systems;yields of early and late rice were higher under RT than those under other til age systems in both years in 2011. Compared with PT0, SOC stocks were increased in soil under NT at 0–5, 5–10, 10–20, and 20–30 cm depths by 33.8, 4.1, 6.6, and 53.3%, respectively, in 2011. SOC stocks under RT were higher than these under other til age treatments at 0–30 cm depth. SOC stocks in soil under PT were higher than those under PT0 in the 0–5 and 20–30 cm soil layers. Therefore, crop residues played an important role in SOC management, and improvement of soil quality. In the 0–20 cm layer, the stratiifcation ratio (SR) of SOC fol owed the order NT>RT>PT>PT0;when the 0–30 cm layer was considered, NT also had the highest SR of SOC, but the SR of SOC under PT was higher than that under RT with a multiple-year til age practice. Therefore, the notion that conservation til age lead to higher SOC stocks and soil quality than plowed systems requires cautious scrutiny. Nevertheless, some beneifts associated with RT system present a greater

  10. EXPOSURE TO RADIATION WELDING WORKERS IN PT.PUTRA SULTRA SAMUDERA KENDARI AGAINST DISEASE DISORDERS CATARACT

    Directory of Open Access Journals (Sweden)

    Abdul Rahim Sya’ban

    2015-12-01

    Full Text Available Background: In the industrial sector, the number of workers employed quite a lot, with the type and intensity of the various aspects of the environment including physical, chemical, biological and psychosocial. Various kinds of environments can cause a variety of occupational diseases. Aim: To determine the relationship between distance and time exposure PT. Putra Sultra Samudera Kendari against cataracts Methods: This research was a survey research with cross sectional analytic study, the data collection were accomplsihed in a certain time to describe the condition of the population Results: The results showed a strong relationship between the suitability of distance, time of exposure to diseases cataracts Conclusions: There was a positive correlation and significant influence between the suitability of the distance and time of exposure with cataract disorder, the use of Personal Protective Equipment showed a positive relationship and did not have a significant effect on cataract disorders in workers in the welding parts firm PT. Putra Sultra Samudera Kendari.

  11. Carbon nanocages: a new support material for Pt catalyst with remarkably high durability.

    Science.gov (United States)

    Wang, Xiao Xia; Tan, Zhe Hua; Zeng, Min; Wang, Jian Nong

    2014-03-24

    Low durability is the major challenge hindering the large-scale implementation of proton exchange membrane fuel cell (PEMFC) technology, and corrosion of carbon support materials of current catalysts is the main cause. Here, we describe the finding of remarkably high durability with the use of a novel support material. This material is based on hollow carbon nanocages developed with a high degree of graphitization and concurrent nitrogen doping for oxidation resistance enhancement, uniform deposition of fine Pt particles, and strong Pt-support interaction. Accelerated degradation testing shows that such designed catalyst possesses a superior electrochemical activity and long-term stability for both hydrogen oxidation and oxygen reduction relative to industry benchmarks of current catalysts. Further testing under conditions of practical fuel cell operation reveals almost no degradation over long-term cycling. Such a catalyst of high activity, particularly, high durability, opens the door for the next-generation PEMFC for "real world" application.

  12. Pt/Mesoporous Carbon Counter Electrode with a Low Pt Loading for High-Efficient Dye-Sensitized Solar Cells

    Directory of Open Access Journals (Sweden)

    Guiqiang Wang

    2010-01-01

    Full Text Available Pt/Mesoporous carbon counter electrodes with a low Pt loading for dye-sensitized solar cells were fabricated by coating Pt/mesoporous carbon on fluorine-doped tin oxide glass. Pt/mesoporous carbon samples were prepared by reducing H2PtCl6 with NaBH4 in mesoporous carbon and characterized by N2 adsorption analysis, X-ray diffraction, X-ray photoelectron spectroscopy, and transmission electron microscopy. The Pt particles deposited on mesoporous carbon support were found to be in uniform shape and narrow range of particle size. Low-Pt-loading Pt/mesoporous carbon counter electrode showed a high electrocatalytic activity for triiodide reduction. Electrochemical impedance spectroscopy measurement displayed a low charge-transfer resistance of 1.2 Ωcm2 for 1-Pt/mesoporous carbon counter electrode. Dye-sensitized solar cells based on the 1-Pt/mesoporous carbon counter electrode achieved an overall conversion efficiency of 6.62% under one sun illumination, which is higher than that of the cell with the conventional Pt counter electrode.

  13. Michigan timber industry: An assessment of timber product output and use, 2004

    Science.gov (United States)

    David E. Haugen; Anthony K. Weatherspoon

    2010-01-01

    Reports forest-industry trends, production and receipts of industrial roundwood, and production of saw logs, veneer logs, excelsior/shavings, and other products for Michigan's timber industry in 2004. Also reports logging residue generated from timber harvest operations in Michigan as well as the generation and disposition of wood and bark residue generated by...

  14. Property comparison of a CoSiB/Pt multilayer to Co/Pt and CoFe/Pt with perpendicular magnetic anisotropy

    Energy Technology Data Exchange (ETDEWEB)

    Jeong, S.; Yim, H. I. [Sookmyung Women' s University, Seoul (Korea, Republic of)

    2011-07-15

    We have investigated the perpendicular magnetic anisotropy of a [CoSiB t{sub CoSiB}/Pt 14 A]{sub 5} multilayer as a function of the CoSiB thickness. We have studied the perpendicular magnetic anisotropy of [Co t{sub Co}/Pt 15 A]{sub 5} and [CoFe t{sub CoFe}/Pt 10 A]{sub 5} multilayers for various thicknesses of Co and CoFe. Furthermore, we have measured and compared the coercivities and the saturation magnetizations of all samples. In this study, samples were [Co t{sub Co} /Pt 15 A]{sub 5}, [CoFe t{sub CoFe}/Pt 10 A]{sub 5} and [CoSiB t{sub CoSiB} /Pt 14 A]{sub 5} with t = 2, 3, 4, and 5 A. The coercivities and the saturation magnetizations were obtained 223.76 Oe and 341.25 emu/cm{sup 3}, 395.86 Oe and 286.79 emu/cm{sup 3} and 155.13 Oe and 429.98 emu/cm{sup 3} in CoSiB/Pt, Co/Pt and CoFe/Pt mutilayers, respectively. The maximum coercivity was obtained 395.86 Oe in the [Co 3 A /Pt 15 A]{sub 5} multilayer, and the minimum saturation magnetization was 286.79 emu/cm{sup 3} in the [Co 2 A /Pt 15 A]{sub 5} multilayer.

  15. Role of rotational energy component in the dynamics of 16O+198Pt reaction

    Directory of Open Access Journals (Sweden)

    Sharma Manoj K.

    2017-01-01

    Full Text Available The role of rotational energy is investigated in reference to the dynamics of 16O+198Pt →214Rn∗ reaction using the sticking (IS and the non-sticking (INS limits of moment of inertia within the framework of dynamical cluster decay model. The decay barrier height and barrier position get significantly modified for the use of sticking or non-sticking choice, which in turn reproduce the evaporation residue and the fusion-fission cross-sections nicely by the IS approach, while the INS approach provides feasible addressal of data only for evaporation residue channel. Moreover, the fragmentation path of decaying fragments of 214Rn∗ compound nucleus gets influenced for different choices of moment of inertia. Beside this, the role of nuclear deformations i.e. static, dynamic quadurpole (β2 and higher order static deformation up to β4 are duly investigated for both choices of the moment of inertia.

  16. Pt- and FePt- nanoparticles on the basis of emulsion techniques

    Energy Technology Data Exchange (ETDEWEB)

    Manzke, Achim; Wiedemann, Stefan; Enderle, Fabian; Plettl, Alfred; Ziemann, Paul [Institut fuer Festkoerperphysik, Universitaet Ulm (Germany); Schreiber, Eyk; Ziener, Ulrich [Institut fuer Organische Chemie III, Universitaet Ulm (Germany); Vogel, Nicolas; Landfester, Katharina [MPI fuer Polymerforschung, Mainz (Germany); Biskupek, Johannes; Kaiser, Ute [Materialwissenschaftliche Elektronenmikroskopie, Universitaet Ulm (Germany)

    2010-07-01

    Metal-precursor loaded colloidal polystyrene (PS) particles in aqueous solution are produced by an emulsion and miniemulsion technique, respectively. We report on colloids loaded with Pt- as well as with Fe- and Pt-complexes. After deposition of a hexagonally ordered monolayer of PS spheres on top of a silicon substrate, optimized plasma and temper sequences are applied to obtain metallic nanoparticles which still exhibit the original lateral order. The metal content within a colloid defines the size of the final particle, which could be varied between 6 and 14 nm, so far. The interparticle distance is determined by the diameter of the starting PS-particles and was varied between 80 and 250 nm. Different process steps are investigated by HRSEM, HRTEM and XPS giving insight in the plasma- and annealing process and demonstrating e.g. the crystalline structure of the Pt- nanoparticles.

  17. Selective formation of tetrahedral Pt nanocrystals from K2PtCl6/PVP

    Institute of Scientific and Technical Information of China (English)

    YU Yingtao; XU Boqing

    2003-01-01

    Tetrahedral platinum (Pt) nanocrystals (3-8 nm) are synthesized in high selectivity (ca. 80%) from hydrogen reduction of aqueous K2PtCl6 by using polyvinylpyrrolidone (PVP: Mw≈360000) as a protector. Morphology (TEM) measurements of the metal colloids and UV-Vis absorption of the colloidal solution are employed to monitor the tetrahedron formation during the syntheses with varying K2PtCl6/PVP ratios. The results clearly show a two-stage process for the selective formation of tetrahedral nanocrystals. Rapid nucleation and crystal formation at the early stage result in round-like crystallites and the external facet evolution in thereafter slow crystal growth leads selectively to the formation of the tetrahedrons.

  18. Effects of anisotropic diffusion and finite island sizes in homoepitaxial growth Pt on Pt(100)-hex

    DEFF Research Database (Denmark)

    Mortensen, Jens Jørgen; Linderoth, T.R.; Jacobsen, Karsten Wedel

    1998-01-01

    size is i=1 and that the mobility of dimers is negligible. Furthermore, an early onset of island coalescence is revealed. From the scaling of the measured saturation island density, N-x similar to(R/h)(chi), where h = v exp(-E-d/k(B)T) is the adatom hopping rate, an effective barrier for diffusion of E......The diffusion, nucleation, and growth of Pt on the hexagonally reconstructed Pt(100)-hex surface are investigated. By means of Scanning Tunneling Microscopy (STM), the positions, sizes, and number densities of monoatomically high, rectangular. reconstructed Pt islands, formed in the submonolayer...... of the determined island positions, it is revealed that the islands are distributed with long/short correlation lengths along, perpendicular to the reconstruction channels. The autocorrelation analysis allows us to quantify the degree of anisotropy in adatom diffusion. Island size distributions obtained...

  19. Industrial pioneers

    NARCIS (Netherlands)

    Wassink, J.

    2014-01-01

    With their knowledge of metallurgy, mechanics and thermodynamics, mechanical engineers had to give shape to the industrial revolution in the Netherlands 150 years ago. This revolution only slowly gathered momentum, however, especially in comparison with England.

  20. Industrial Chemistry.

    Science.gov (United States)

    Gumprecht, Donald L.; Thrasher, Joseph S.

    1990-01-01

    Described is a course designed to better prepare students for employment in chemical industries. A course schedule for this interim course and a list of sources of speakers and speaker credentials is provided. (CW)