WorldWideScience

Sample records for include extraneous particulates

  1. Global anthropogenic emissions of particulate matter including black carbon

    Science.gov (United States)

    Klimont, Zbigniew; Kupiainen, Kaarle; Heyes, Chris; Purohit, Pallav; Cofala, Janusz; Rafaj, Peter; Borken-Kleefeld, Jens; Schöpp, Wolfgang

    2017-07-01

    This paper presents a comprehensive assessment of historical (1990-2010) global anthropogenic particulate matter (PM) emissions including the consistent and harmonized calculation of mass-based size distribution (PM1, PM2. 5, PM10), as well as primary carbonaceous aerosols including black carbon (BC) and organic carbon (OC). The estimates were developed with the integrated assessment model GAINS, where source- and region-specific technology characteristics are explicitly included. This assessment includes a number of previously unaccounted or often misallocated emission sources, i.e. kerosene lamps, gas flaring, diesel generators, refuse burning; some of them were reported in the past for selected regions or in the context of a particular pollutant or sector but not included as part of a total estimate. Spatially, emissions were calculated for 172 source regions (as well as international shipping), presented for 25 global regions, and allocated to 0.5° × 0.5° longitude-latitude grids. No independent estimates of emissions from forest fires and savannah burning are provided and neither windblown dust nor unpaved roads emissions are included. We estimate that global emissions of PM have not changed significantly between 1990 and 2010, showing a strong decoupling from the global increase in energy consumption and, consequently, CO2 emissions, but there are significantly different regional trends, with a particularly strong increase in East Asia and Africa and a strong decline in Europe, North America, and the Pacific region. This in turn resulted in important changes in the spatial pattern of PM burden, e.g. European, North American, and Pacific contributions to global emissions dropped from nearly 30 % in 1990 to well below 15 % in 2010, while Asia's contribution grew from just over 50 % to nearly two-thirds of the global total in 2010. For all PM species considered, Asian sources represented over 60 % of the global anthropogenic total, and residential combustion

  2. Global anthropogenic emissions of particulate matter including black carbon

    Directory of Open Access Journals (Sweden)

    Z. Klimont

    2017-07-01

    Full Text Available This paper presents a comprehensive assessment of historical (1990–2010 global anthropogenic particulate matter (PM emissions including the consistent and harmonized calculation of mass-based size distribution (PM1, PM2. 5, PM10, as well as primary carbonaceous aerosols including black carbon (BC and organic carbon (OC. The estimates were developed with the integrated assessment model GAINS, where source- and region-specific technology characteristics are explicitly included. This assessment includes a number of previously unaccounted or often misallocated emission sources, i.e. kerosene lamps, gas flaring, diesel generators, refuse burning; some of them were reported in the past for selected regions or in the context of a particular pollutant or sector but not included as part of a total estimate. Spatially, emissions were calculated for 172 source regions (as well as international shipping, presented for 25 global regions, and allocated to 0.5°  ×  0.5° longitude–latitude grids. No independent estimates of emissions from forest fires and savannah burning are provided and neither windblown dust nor unpaved roads emissions are included. We estimate that global emissions of PM have not changed significantly between 1990 and 2010, showing a strong decoupling from the global increase in energy consumption and, consequently, CO2 emissions, but there are significantly different regional trends, with a particularly strong increase in East Asia and Africa and a strong decline in Europe, North America, and the Pacific region. This in turn resulted in important changes in the spatial pattern of PM burden, e.g. European, North American, and Pacific contributions to global emissions dropped from nearly 30 % in 1990 to well below 15 % in 2010, while Asia's contribution grew from just over 50 % to nearly two-thirds of the global total in 2010. For all PM species considered, Asian sources represented over 60 % of the global

  3. Significant events caused by extraneous acts

    International Nuclear Information System (INIS)

    Verlaeken, J.

    1987-01-01

    The operating experience feedback system of VINCOTTE, called ARIANE, consists, among others, of preparing synthesis reports on specific safety concerns. A recent report deals with significant events caused by extranous acts. Events attributable to human error are numerous. Confusion errors have already been analysed in several publications (NES IRS 664 etc.). However, are described here some ten incidents where extranous acts occurred: ZION 2 (September 76), OYSTER CREEK (May 79), PALISADES (January 81), CATAWBA (August 85), etc. The contributing factors for these unfortunate initiatives are explained; several resort to psychological influences. Corrective actions are discussed, and some general lessons are drawn. (author)

  4. HUMAL ALVEOLAR MACROPHAGE RESPONSES TO AIR POLLUTION PARTICULATES ARE ASSOCIATED WITH INSOLUBLE OCMPONENTS OF COARSE MATERIAL, INCLUDING PARTICULATE ENDOTOXIN

    Science.gov (United States)

    Inhalation of particulate matter in the ambient air has been shown to cause pulmonary morbidity and exacerbate asthma. Alveolar macrophage (AM) are essential for effective removal of inhaled particles and microbes in the lower airways. While some particles minimally effect AM...

  5. CATEGORIZATION OF EXTRANEOUS MATTER IN COTTON USING MACHINE VISION SYSTEMS

    Science.gov (United States)

    The Cotton Trash Identification System (CTIS) was developed at the Southwestern Cotton Ginning Research Laboratory to identify and categorize extraneous matter in cotton. The CTIS bark/grass categorization was evaluated with USDA-Agricultural Marketing Service (AMS) extraneous matter calls assigned ...

  6. Element Interactivity and Intrinsic, Extraneous, and Germane Cognitive Load

    Science.gov (United States)

    Sweller, John

    2010-01-01

    In cognitive load theory, element interactivity has been used as the basic, defining mechanism of intrinsic cognitive load for many years. In this article, it is suggested that element interactivity underlies extraneous cognitive load as well. By defining extraneous cognitive load in terms of element interactivity, a distinct relation between…

  7. Aerosol measurement: the use of optical light scattering for the determination of particulate size distribution, and particulate mass, including the semi-volatile fraction.

    Science.gov (United States)

    Grimm, Hans; Eatough, Delbert J

    2009-01-01

    The GRIMM model 1.107 monitor is designed to measure particle size distribution and particulate mass based on a light scattering measurement of individual particles in the sampled air. The design and operation of the instrument are described. Protocols used to convert the measured size number distribution to a mass concentration consistent with U.S. Environmental Protection Agency protocols for measuring particulate matter (PM) less than 10 microm (PM10) and less than 2.5 microm (PM2.5) in aerodynamic diameter are described. The performance of the resulting continuous monitor has been evaluated by comparing GRIMM monitor PM2.5 measurements with results obtained by the Rupprecht and Patashnick Co. (R&P) filter dynamic measurement system (FDMS). Data were obtained during month-long studies in Rubidoux, CA, in July 2003 and in Fresno, CA, in December 2003. The results indicate that the GRIMM monitor does respond to total PM2.5 mass, including the semi-volatile components, giving results comparable to the FDMS. The data also indicate that the monitor can be used to estimate water content of the fine particles. However, if the inlet to the monitor is heated, then the instrument measures only the nonvolatile material, more comparable to results obtained with a conventional heated filter tapered element oscillating microbalance (TEOM) monitor. A recent modification of the model 180, with a Nafion dryer at the inlet, measures total PM2.5 including the nonvolatile and semi-volatile components, but excluding fine particulate water. Model 180 was in agreement with FDMS data obtained in Lindon, UT, during January through February 2007.

  8. Including impacts of particulate emissions on marine ecosystems in life cycle assessment: the case of offshore oil and gas production.

    Science.gov (United States)

    Veltman, Karin; Huijbregts, Mark A J; Rye, Henrik; Hertwich, Edgar G

    2011-10-01

    Life cycle assessment is increasingly used to assess the environmental performance of fossil energy systems. Two of the dominant emissions of offshore oil and gas production to the marine environment are the discharge of produced water and drilling waste. Although environmental impacts of produced water are predominantly due to chemical stressors, a major concern regarding drilling waste discharge is the potential physical impact due to particles. At present, impact indicators for particulate emissions are not yet available in life cycle assessment. Here, we develop characterization factors for 2 distinct impacts of particulate emissions: an increased turbidity zone in the water column and physical burial of benthic communities. The characterization factor for turbidity is developed analogous to characterization factors for toxic impacts, and ranges from 1.4 PAF (potentially affected fraction) · m(3) /d/kg(p) (kilogram particulate) to 7.0 x 10³ [corrected] for drilling mud particles discharged from the rig. The characterization factor for burial describes the volume of sediment that is impacted by particle deposition on the seafloor and equals 2.0 × 10(-1) PAF · m(3) /d/kg(p) for cutting particles. This characterization factor is quantified on the basis of initial deposition layer characteristics, such as height and surface area, the initial benthic response, and the recovery rate. We assessed the relevance of including particulate emissions in an impact assessment of offshore oil and gas production. Accordingly, the total impact on the water column and on the sediment was quantified based on emission data of produced water and drilling waste for all oil and gas fields on the Norwegian continental shelf in 2008. Our results show that cutting particles contribute substantially to the total impact of offshore oil and gas production on marine sediments, with a relative contribution of 55% and 31% on the regional and global scale, respectively. In contrast, the

  9. Low levels of extraneous agents in vaccine starting materials.

    Science.gov (United States)

    Rouby, Jean-Claude

    2010-05-01

    There are different ways to define the concept of 'low levels' of extraneous agents in vaccines and vaccine starting materials, based on the amount of extraneous agents as such, the sensitivity of the detection method and the probability approach linked to the sampling method. None of these approaches, however, is entirely satisfactory--a general definition of a 'low level' cannot be provided. Since the main point is the safety of medicinal products, the risk analysis approach to 'low level' contaminations can be considered as a way to overcome the above mentioned deadlock. But as too many variables impact the risk analysis, it cannot be properly performed either. In practice, seeds are tested to show freedom from extraneous agents, the other raw materials are inactivated through a validated method. However, there are technical and regulatory limits in both cases, and neither testing nor inactivation entirely guarantees freedom from extraneous agents. Despite this unsatisfactory situation, it should be acknowledged that no truly significant disease outbreak linked to an extraneous agent has been identified until today. Regulatory actions are mainly undertaken when a sanitary problem occurs. In the end, companies remain responsible for their products. 2010 The International Association for Biologicals. Published by Elsevier Ltd. All rights reserved.

  10. Method for contamination control and barrier apparatus with filter for containing waste materials that include dangerous particulate matter

    Science.gov (United States)

    Pinson, Paul A.

    1998-01-01

    A container for hazardous waste materials that includes air or other gas carrying dangerous particulate matter has incorporated in barrier material, preferably in the form of a flexible sheet, one or more filters for the dangerous particulate matter sealably attached to such barrier material. The filter is preferably a HEPA type filter and is preferably chemically bonded to the barrier materials. The filter or filters are preferably flexibly bonded to the barrier material marginally and peripherally of the filter or marginally and peripherally of air or other gas outlet openings in the barrier material, which may be a plastic bag. The filter may be provided with a backing panel of barrier material having an opening or openings for the passage of air or other gas into the filter or filters. Such backing panel is bonded marginally and peripherally thereof to the barrier material or to both it and the filter or filters. A coupling or couplings for deflating and inflating the container may be incorporated. Confining a hazardous waste material in such a container, rapidly deflating the container and disposing of the container, constitutes one aspect of the method of the invention. The chemical bonding procedure for producing the container constitutes another aspect of the method of the invention.

  11. Method for contamination control and barrier apparatus with filter for containing waste materials that include dangerous particulate matter

    International Nuclear Information System (INIS)

    Pinson, P.A.

    1998-01-01

    A container for hazardous waste materials that includes air or other gas carrying dangerous particulate matter has incorporated barrier material, preferably in the form of a flexible sheet, and one or more filters for the dangerous particulate matter sealably attached to such barrier material. The filter is preferably a HEPA type filter and is preferably chemically bonded to the barrier materials. The filter or filters are preferably flexibly bonded to the barrier material marginally and peripherally of the filter or marginally and peripherally of air or other gas outlet openings in the barrier material, which may be a plastic bag. The filter may be provided with a backing panel of barrier material having an opening or openings for the passage of air or other gas into the filter or filters. Such backing panel is bonded marginally and peripherally thereof to the barrier material or to both it and the filter or filters. A coupling or couplings for deflating and inflating the container may be incorporated. Confining a hazardous waste material in such a container, rapidly deflating the container and disposing of the container, constitutes one aspect of the method of the invention. The chemical bonding procedure for producing the container constitutes another aspect of the method of the invention. 3 figs

  12. 27 CFR 19.322 - Distillates containing extraneous substances.

    Science.gov (United States)

    2010-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2010-04-01 2010-04-01 false Distillates containing... Distillates containing extraneous substances. (a) Use in production. Distillates containing substantial... produced. Distillates removed from the distilling system under the provisions of this paragraph shall be...

  13. Effects of Hot Streak and Phantom Cooling on Heat Transfer in a Cooled Turbine Stage Including Particulate Deposition

    Energy Technology Data Exchange (ETDEWEB)

    Bons, Jeffrey [The Ohio State Univ., Columbus, OH (United States); Ameri, Ali [The Ohio State Univ., Columbus, OH (United States)

    2016-01-08

    The objective of this research effort was to develop a validated computational modeling capability for the characterization of the effects of hot streaks and particulate deposition on the heat load of modern gas turbines. This was accomplished with a multi-faceted approach including analytical, experimental, and computational components. A 1-year no cost extension request was approved for this effort, so the total duration was 4 years. The research effort succeeded in its ultimate objective by leveraging extensive experimental deposition studies complemented by computational modeling. Experiments were conducted with hot streaks, vane cooling, and combinations of hot streaks with vane cooling. These studies contributed to a significant body of corporate knowledge of deposition, in combination with particle rebound and deposition studies funded by other agencies, to provide suitable conditions for the development of a new model. The model includes the following physical phenomena: elastic deformation, plastic deformation, adhesion, and shear removal. It also incorporates material property sensitivity to temperature and tangential-normal velocity rebound cross-dependencies observed in experiments. The model is well-suited for incorporation in CFD simulations of complex gas turbine flows due to its algebraic (explicit) formulation. This report contains model predictions compared to coefficient of restitution data available in the open literature as well as deposition results from two different high temperature turbine deposition facilities. While the model comparisons with experiments are in many cases promising, several key aspects of particle deposition remain elusive. The simple phenomenological nature of the model allows for parametric dependencies to be evaluated in a straightforward manner. This effort also included the first-ever full turbine stage deposition model published in the open literature. The simulations included hot streaks and simulated vane cooling

  14. 9 CFR 113.27 - Detection of extraneous viable bacteria and fungi in live vaccines.

    Science.gov (United States)

    2010-01-01

    ... bacteria and fungi in live vaccines. 113.27 Section 113.27 Animals and Animal Products ANIMAL AND PLANT... bacteria and fungi in live vaccines. Unless otherwise specified by the Administrator or elsewhere exempted... Seed Bacteria shall be tested for extraneous viable bacteria and fungi as prescribed in this section. A...

  15. 9 CFR 113.55 - Detection of extraneous agents in Master Seed Virus.

    Science.gov (United States)

    2010-01-01

    ... Master Seed Virus. 113.55 Section 113.55 Animals and Animal Products ANIMAL AND PLANT HEALTH INSPECTION SERVICE, DEPARTMENT OF AGRICULTURE VIRUSES, SERUMS, TOXINS, AND ANALOGOUS PRODUCTS; ORGANISMS AND VECTORS STANDARD REQUIREMENTS Ingredient Requirements § 113.55 Detection of extraneous agents in Master Seed Virus...

  16. Pre-service Teacher Extraneous Cognitive Load in the Pedagogical Content and Knowledge of Solar System Course

    Science.gov (United States)

    Permana, I.; Redjeki, S.; Hamidah, I.; Safitri, N.

    2017-09-01

    This study reported the student’s Extraneous Cognitive Load (ECL) in the Pedagogical Content and Knowledge of solar system Course. Participants in the study were 31 pre-service elementary school teachers from the university in Bogor Indonesia. The data collected from ECL were obtained using a Likert 4-scale questionnaire and interview. After taking lectures, we asked for some mental effort from pre-service elementary school teachers to attend courses in order to assess the ECL. The courses include 3 topics and they were non-experimental worksheet, developing experimental worksheet using Vee Diagram framework, and analysis for curriculum by grade IV, V and VI. Results of the data analysis showed that the course strategy resulted by ECL was relatively low. The ECL increased in the course of curriculum analysis due to material complexity.

  17. Pratique de l’extranéité dans l’écriture d’Abdelkébir Khatibi

    Directory of Open Access Journals (Sweden)

    Hassan Moustir

    2013-11-01

    Full Text Available Promoted to the rank of operational concept in writing, the notion of "foreign professional" means in both fictional and critical work of Abdelkébir Khatibi (1938-2009 this cosmopolitan otherness that reduces identity disparities and cultural differences. Late Khatibi’s fictions, including Un été à Stockholm (1990 and Féerie d’un mutant (2005 represent an ontological extraneous out with all cultural and identity anchors and discourse representations. Op-erating in a global space, and private of a fixed identity and separated cultural roots, the characters of these two fictions embody the thought of foreignness and border crossing practice, at the linguistic and the cultural levels. This fact grows to reflect on what would be writing and deterritorialized identity.

  18. Overestimation of Crop Root Biomass in Field Experiments Due to Extraneous Organic Matter.

    Science.gov (United States)

    Hirte, Juliane; Leifeld, Jens; Abiven, Samuel; Oberholzer, Hans-Rudolf; Hammelehle, Andreas; Mayer, Jochen

    2017-01-01

    Root biomass is one of the most relevant root parameters for studies of plant response to environmental change, soil carbon modeling or estimations of soil carbon sequestration. A major source of error in root biomass quantification of agricultural crops in the field is the presence of extraneous organic matter in soil: dead roots from previous crops, weed roots, incorporated above ground plant residues and organic soil amendments, or remnants of soil fauna. Using the isotopic difference between recent maize root biomass and predominantly C3-derived extraneous organic matter, we determined the proportions of maize root biomass carbon of total carbon in root samples from the Swiss long-term field trial "DOK." We additionally evaluated the effects of agricultural management (bio-organic and conventional), sampling depth (0-0.25, 0.25-0.5, 0.5-0.75 m) and position (within and between maize rows), and root size class (coarse and fine roots) as defined by sieve mesh size (2 and 0.5 mm) on those proportions, and quantified the success rate of manual exclusion of extraneous organic matter from root samples. Only 60% of the root mass that we retrieved from field soil cores was actual maize root biomass from the current season. While the proportions of maize root biomass carbon were not affected by agricultural management, they increased consistently with soil depth, were higher within than between maize rows, and were higher in coarse (>2 mm) than in fine (≤2 and >0.5) root samples. The success rate of manual exclusion of extraneous organic matter from root samples was related to agricultural management and, at best, about 60%. We assume that the composition of extraneous organic matter is strongly influenced by agricultural management and soil depth and governs the effect size of the investigated factors. Extraneous organic matter may result in severe overestimation of recovered root biomass and has, therefore, large implications for soil carbon modeling and estimations

  19. EXTRAN: A computer code for estimating concentrations of toxic substances at control room air intakes

    International Nuclear Information System (INIS)

    Ramsdell, J.V.

    1991-03-01

    This report presents the NRC staff with a tool for assessing the potential effects of accidental releases of radioactive materials and toxic substances on habitability of nuclear facility control rooms. The tool is a computer code that estimates concentrations at nuclear facility control room air intakes given information about the release and the environmental conditions. The name of the computer code is EXTRAN. EXTRAN combines procedures for estimating the amount of airborne material, a Gaussian puff dispersion model, and the most recent algorithms for estimating diffusion coefficients in building wakes. It is a modular computer code, written in FORTRAN-77, that runs on personal computers. It uses a math coprocessor, if present, but does not require one. Code output may be directed to a printer or disk files. 25 refs., 8 figs., 4 tabs

  20. Electrically heated particulate filter restart strategy

    Science.gov (United States)

    Gonze, Eugene V [Pinckney, MI; Ament, Frank [Troy, MI

    2011-07-12

    A control system that controls regeneration of a particulate filter is provided. The system generally includes a propagation module that estimates a propagation status of combustion of particulate matter in the particulate filter. A regeneration module controls current to the particulate filter to re-initiate regeneration based on the propagation status.

  1. Electrical diesel particulate filter (DPF) regeneration

    Science.gov (United States)

    Gonze, Eugene V; Ament, Frank

    2013-12-31

    An exhaust system that processes exhaust generated by an engine includes a diesel particulate filter (DPF) that is disposed downstream of the engine and that filters particulates from the exhaust. An electrical heater is disposed upstream of the DPF and selectively heats the exhaust to initiate combustion of the particulates within the exhaust as it passes therethrough. Heat generated by combustion of the particulates induces combustion of particulates within the DPF.

  2. The minimization of the extraneous electromagnetic fields of an inductive power transfer system

    International Nuclear Information System (INIS)

    McLean, James; Sutton, Robert

    2013-01-01

    The efficiency of inductive wireless power transfer (IPT) systems has been extensively studied. However, the electromagnetic compatibility of such systems is at least as important as the efficiency and has received much less attention. We consider the net magnetic dipole moment of the system as a figure of merit. That is, we seek to minimize the magnitude of the net dipole moment in order to minimize both the near magnetic fields and the radiated power. A 20 kHz, 3.3 kW, IPT system, representative of typical wireless vehicular battery charging systems, is considered and it is seen that one particular value of load impedance minimizes the net dipole moment while another, distinct, value maximizes efficiency. Thus, efficiency must be traded off, at least to some extent, in order to minimize extraneous electromagnetic fields.

  3. Development and Validation of Two Instruments Measuring Intrinsic, Extraneous, and Germane Cognitive Load

    Science.gov (United States)

    Klepsch, Melina; Schmitz, Florian; Seufert, Tina

    2017-01-01

    Cognitive Load Theory is one of the most powerful research frameworks in educational research. Beside theoretical discussions about the conceptual parts of cognitive load, the main challenge within this framework is that there is still no measurement instrument for the different aspects of cognitive load, namely intrinsic, extraneous, and germane cognitive load. Hence, the goal of this paper is to develop a differentiated measurement of cognitive load. In Study 1 (N = 97), we developed and analyzed two strategies to measure cognitive load in a differentiated way: (1) Informed rating: We trained learners in differentiating the concepts of cognitive load, so that they could rate them in an informed way. They were asked then to rate 24 different learning situations or learning materials related to either high or low intrinsic, extraneous, or germane load. (2) Naïve rating: For this type of rating of cognitive load we developed a questionnaire with two to three items for each type of load. With this questionnaire, the same learning situations had to be rated. In the second study (N = between 65 and 95 for each task), we improved the instrument for the naïve rating. For each study, we analyzed whether the instruments are reliable and valid, for Study 1, we also checked for comparability of the two measurement strategies. In Study 2, we conducted a simultaneous scenario based factor analysis. The informed rating seems to be a promising strategy to assess the different aspects of cognitive load, but it seems not economic and feasible for larger studies and a standardized training would be necessary. The improved version of the naïve rating turned out to be a useful, feasible, and reliable instrument. Ongoing studies analyze the conceptual validity of this measurement with up to now promising results. PMID:29201011

  4. Development and Validation of Two Instruments Measuring Intrinsic, Extraneous, and Germane Cognitive Load.

    Science.gov (United States)

    Klepsch, Melina; Schmitz, Florian; Seufert, Tina

    2017-01-01

    Cognitive Load Theory is one of the most powerful research frameworks in educational research. Beside theoretical discussions about the conceptual parts of cognitive load, the main challenge within this framework is that there is still no measurement instrument for the different aspects of cognitive load, namely intrinsic, extraneous, and germane cognitive load. Hence, the goal of this paper is to develop a differentiated measurement of cognitive load. In Study 1 ( N = 97), we developed and analyzed two strategies to measure cognitive load in a differentiated way: (1) Informed rating: We trained learners in differentiating the concepts of cognitive load, so that they could rate them in an informed way. They were asked then to rate 24 different learning situations or learning materials related to either high or low intrinsic, extraneous, or germane load. (2) Naïve rating: For this type of rating of cognitive load we developed a questionnaire with two to three items for each type of load. With this questionnaire, the same learning situations had to be rated. In the second study ( N = between 65 and 95 for each task), we improved the instrument for the naïve rating. For each study, we analyzed whether the instruments are reliable and valid, for Study 1, we also checked for comparability of the two measurement strategies. In Study 2, we conducted a simultaneous scenario based factor analysis. The informed rating seems to be a promising strategy to assess the different aspects of cognitive load, but it seems not economic and feasible for larger studies and a standardized training would be necessary. The improved version of the naïve rating turned out to be a useful, feasible, and reliable instrument. Ongoing studies analyze the conceptual validity of this measurement with up to now promising results.

  5. Development and Validation of Two Instruments Measuring Intrinsic, Extraneous, and Germane Cognitive Load

    Directory of Open Access Journals (Sweden)

    Melina Klepsch

    2017-11-01

    Full Text Available Cognitive Load Theory is one of the most powerful research frameworks in educational research. Beside theoretical discussions about the conceptual parts of cognitive load, the main challenge within this framework is that there is still no measurement instrument for the different aspects of cognitive load, namely intrinsic, extraneous, and germane cognitive load. Hence, the goal of this paper is to develop a differentiated measurement of cognitive load. In Study 1 (N = 97, we developed and analyzed two strategies to measure cognitive load in a differentiated way: (1 Informed rating: We trained learners in differentiating the concepts of cognitive load, so that they could rate them in an informed way. They were asked then to rate 24 different learning situations or learning materials related to either high or low intrinsic, extraneous, or germane load. (2 Naïve rating: For this type of rating of cognitive load we developed a questionnaire with two to three items for each type of load. With this questionnaire, the same learning situations had to be rated. In the second study (N = between 65 and 95 for each task, we improved the instrument for the naïve rating. For each study, we analyzed whether the instruments are reliable and valid, for Study 1, we also checked for comparability of the two measurement strategies. In Study 2, we conducted a simultaneous scenario based factor analysis. The informed rating seems to be a promising strategy to assess the different aspects of cognitive load, but it seems not economic and feasible for larger studies and a standardized training would be necessary. The improved version of the naïve rating turned out to be a useful, feasible, and reliable instrument. Ongoing studies analyze the conceptual validity of this measurement with up to now promising results.

  6. Microwave regenerated particulate trap

    Energy Technology Data Exchange (ETDEWEB)

    McDonald, A.C. Jr.; Yonushonis, T.M. [Cummins Engine Co., Inc., Columbus, IN (United States); Haberkamp, W.C.; Mako, F.; Len, L.K,; Silberglitt, R.; Ahmed, I. [FM Technologies, Inc., Fairfax, VA (United States)

    1997-12-31

    It has been demonstrated that a fibrous particulate filter can extract particulate matter from the diesel exhaust. However, additional engineering efforts remains to achieve the design target of 90%. It has also be shown that with minor modifications magnetrons produced for home ovens can endure a simulated diesel operating environment. Much work remains to develop a robust product ready to complete extensive engine testing and evaluation. These efforts include: (1) additional environmental testing of magnetrons; (2) vibration testing of the filter in the housing; (3) evaluating alternative methods/designs to seal the center bore; and (4) determining the optimum coating thickness that provides sufficient structural integrity while maintaining rapid heating rates.

  7. La extraña idea del desarrollo. Genealogía de un concepto

    Directory of Open Access Journals (Sweden)

    Carlos Eduardo Maldonado

    2017-01-01

    Full Text Available Este artículo elabora una genealogía del concepto de desarrollo. Formulado originalmente por R. Prebisch (1950, el con- cepto sufre varias traducciones, extensiones y modi caciones que terminan asimilándolo a una idea perfectamente distinta. El sentido y el contexto originarios terminan transformándose. Así, el desarrollo termina siendo una apología del capitalismo. Después de una introducción histórica y cientí ca, el artículo desarrolla cuatro argumentos, así: el modelo de desarrollo es una idea extraña; esta idea se ve ampliada y extendida en términos de sostenibilidad; varias críticas, sin embargo, emergen y se ha- cen necesarias; consiguientemente, se hace posible e imperativo un modelo alternativo al desarrollo. Cada una de las secciones mencionadas son justi cadas en cada paso. Al nal se extraen algunas conclusiones, y el artículo termina con una idea fuerte que vincula bancarización y control ciudadano. Palabras clave: Historia de la economía, filosofía de la economía, capitalismo, economía política Abstract This paper carries out a genealogy of the concept of development. Originally stated out by R. Prebisch (1950, the concept su ers a number of translations, extension, and changes that end up with a quite di erent idea than it was originally thought. Both the meaning and framework end up being radically changed. us, development ends as an apology to capitalism. A er a short historical and philosophical introduction, this paper develops four arguments, as follows: the model of economic de- velopment is a weird idea; such an idea is both extended and widened in terms of sustainability; a number of critiques merge, though, that are necessary and feasible; therea er, an alternative model of development becomes at the same time possible and compulsory. Each one of the mentioned paragraphs are justi ed in due time. At the end some conclusions are drawn, ad the paper ends with a string idea that

  8. Impact of extraneous mispositioned events on motion-corrected brain SPECT images of freely moving animals

    International Nuclear Information System (INIS)

    Angelis, Georgios I.; Ryder, William J.; Bashar, Rezaul; Meikle, Steven R.; Fulton, Roger R.

    2014-01-01

    Purpose: Single photon emission computed tomography (SPECT) brain imaging of freely moving small animals would allow a wide range of important neurological processes and behaviors to be studied, which are normally inhibited by anesthetic drugs or precluded due to the animal being restrained. While rigid body motion of the head can be tracked and accounted for in the reconstruction, activity in the torso may confound brain measurements, especially since motion of the torso is more complex (i.e., nonrigid) and not well correlated with that of the head. The authors investigated the impact of mispositioned events and attenuation due to the torso on the accuracy of motion corrected brain images of freely moving mice. Methods: Monte Carlo simulations of a realistic voxelized mouse phantom and a dual compartment phantom were performed. Each phantom comprised a target and an extraneous compartment which were able to move independently of each other. Motion correction was performed based on the known motion of the target compartment only. Two SPECT camera geometries were investigated: a rotating single head detector and a stationary full ring detector. The effects of motion, detector geometry, and energy of the emitted photons (hence, attenuation) on bias and noise in reconstructed brain regions were evaluated. Results: The authors observed two main sources of bias: (a) motion-related inconsistencies in the projection data and (b) the mismatch between attenuation and emission. Both effects are caused by the assumption that the orientation of the torso is difficult to track and model, and therefore cannot be conveniently corrected for. The motion induced bias in some regions was up to 12% when no attenuation effects were considered, while it reached 40% when also combined with attenuation related inconsistencies. The detector geometry (i.e., rotating vs full ring) has a big impact on the accuracy of the reconstructed images, with the full ring detector being more

  9. The use of nuclear and related techniques for the studies of airborne particulate matter in workplace including tissue analysis and possible impacts on human health in a metal industry

    International Nuclear Information System (INIS)

    Widjajakusuma, B.; Djojosubroto, H.; Kumolowati, E.

    1998-01-01

    Various processes in a metal industry may produce gases and fine airborne particulate matter that hazardous to human health. The present study deals with assessment of levels and health effects of airborne particulate matter in a metal industry. The objective is achieved by determination of elemental levels in blood, nail and hair of workers and airborne particulate matter that are collected from their workplace. The elemental levels in blood, nail and hair of the workers will be compared to those of control. Their health condition are examined by medical examination and biochemical analysis of their blood. The blood was drawn following an overnight fast before breakfast, by means of I.V. catheter into three polyethylene tubes. The blood samples in the first tubes were sent to clinical laboratory for biochemical examination. Those in the second and third tubes, which are considered free from metal contamination by the needle of the catheter, are used for trace element study. Sera in the polyethylene tubes were separated from erythrocyte by centrifugation, then cooled by liquid nitrogen and freeze dried. Approximately 1 g of toe nail and hair samples were taken respectively from every worker. To eliminate grease and surface contamination the hair samples were rinse with acetone. Airborne particulate samples were collected from the workplace using Gent sampler. These samples are ready for elemental analysis. Results of biochemical analysis and medical examinations of the workers are presented in this report. The correlation among various parameters will be determined by statistical analysis. (author)

  10. Airborne Particulate Threat Assessment

    Energy Technology Data Exchange (ETDEWEB)

    Patrick Treado; Oksana Klueva; Jeffrey Beckstead

    2008-12-31

    Aerosol threat detection requires the ability to discern between threat agents and ambient background particulate matter (PM) encountered in the environment. To date, Raman imaging technology has been demonstrated as an effective strategy for the assessment of threat agents in the presence of specific, complex backgrounds. Expanding our understanding of the composition of ambient particulate matter background will improve the overall performance of Raman Chemical Imaging (RCI) detection strategies for the autonomous detection of airborne chemical and biological hazards. Improving RCI detection performance is strategic due to its potential to become a widely exploited detection approach by several U.S. government agencies. To improve the understanding of the ambient PM background with subsequent improvement in Raman threat detection capability, ChemImage undertook the Airborne Particulate Threat Assessment (APTA) Project in 2005-2008 through a collaborative effort with the National Energy Technology Laboratory (NETL), under cooperative agreement number DE-FC26-05NT42594. During Phase 1 of the program, a novel PM classification based on molecular composition was developed based on a comprehensive review of the scientific literature. In addition, testing protocols were developed for ambient PM characterization. A signature database was developed based on a variety of microanalytical techniques, including scanning electron microscopy, FT-IR microspectroscopy, optical microscopy, fluorescence and Raman chemical imaging techniques. An automated particle integrated collector and detector (APICD) prototype was developed for automated collection, deposition and detection of biothreat agents in background PM. During Phase 2 of the program, ChemImage continued to refine the understanding of ambient background composition. Additionally, ChemImage enhanced the APICD to provide improved autonomy, sensitivity and specificity. Deliverables included a Final Report detailing our

  11. Screening for viral extraneous agents in live-attenuated avian vaccines by using a microbial microarray and sequencing

    DEFF Research Database (Denmark)

    Olesen, Majken Lindholm; Jørgensen, Lotte Leick; Blixenkrone-Møller, Merete

    2018-01-01

    The absence of extraneous agents (EA) in the raw material used for production and in finished products is one of the principal safety elements related to all medicinal products of biological origin, such as live-attenuated vaccines. The aim of this study was to investigate the applicability...... of the Lawrence Livermore Microbial detection array version 2 (LLMDAv2) combined with whole genome amplification and sequencing for screening for viral EAs in live-attenuated vaccines and specific pathogen-free (SPF) eggs.We detected positive microarray signals for avian endogenous retrovirus EAV-HP and several...... viruses belonging to the Alpharetrovirus genus in all analyzed vaccines and SPF eggs. We used a microarray probe mapping approach to evaluate the presence of intact retroviral genomes, which in addition to PCR analysis revealed that several of the positive microarray signals were most likely due to cross...

  12. Externality costs by emission. E. Particulates

    International Nuclear Information System (INIS)

    Anon.

    1991-01-01

    Fossil-fuel-fired electricity generating systems, particularly coal and oil-fired facilities, are significant emitters of particulate matter. The major components of particulate emissions from a power plant include ash, which is made up of heavy metals, radioactive isotopes and hydrocarbons, and sulfates (SO 4 ) and nitrates (NO 3 ), which are formed by reaction of sulfur dioxide (SO 2 ) and nitrogen oxides (NO x ) in the atmosphere. The smallest ash particulates (including sulfates and nitrates) cause human respiratory effects and impaired visibility. Other effects may include materials damage due to soiling and possibly corrosion, damage to domestic and wild flora through deposition of particulates on foliage, and possible health effects on domestic animals and wild fauna. Several studies focus on the direct effects of high ambient levels of small particulates. This chapter reviews the available literature on the effects of particulate emissions on humans and their environment, and attempts to assign a cost figure to the environmental effects and human health impairments associated with particulate matter emissions. Specifically, this report focuses on the effects of particulates related to human health, visibility, flora, fauna and materials

  13. RoLo: A Dictionary Interface that Minimizes Extraneous Cognitive Load of Lookup and Supports Incidental and Incremental Learning of Vocabulary

    Science.gov (United States)

    Dang, Thanh-Dung; Chen, Gwo-Dong; Dang, Giao; Li, Liang-Yi; Nurkhamid

    2013-01-01

    Dictionary use can improve reading comprehension and incidental vocabulary learning. Nevertheless, great extraneous cognitive load imposed by the search process may reduce or even prevent the improvement. With the help of technology, dictionary users can now instantly access the meaning list of a searched word using a mouse click. However, they…

  14. Transport phenomena in particulate systems

    CERN Document Server

    Freire, José Teixeira; Ferreira, Maria do Carmo

    2012-01-01

    This volume spans 10 chapters covering different aspects of transport phenomena including fixed and fluidized systems, spouted beds, electrochemical and wastewater treatment reactors. This e-book will be valuable for students, engineers and researchers aiming to keep updated on the latest developments on particulate systems.

  15. 40 CFR 230.21 - Suspended particulates/turbidity.

    Science.gov (United States)

    2010-07-01

    ... Impacts on Physical and Chemical Characteristics of the Aquatic Ecosystem § 230.21 Suspended particulates/turbidity. (a) Suspended particulates in the aquatic ecosystem consist of fine-grained mineral particles..., and man's activities including dredging and filling. Particulates may remain suspended in the water...

  16. Kuwaiti oil fires—Particulate monitoring

    Science.gov (United States)

    Husain, Tahir; Amin, Mohamed B.

    The total suspended particulate (TSP) matters using a high-volume sampler and inhalable particulate matters using PM-10 samplers were collected at various locations in the Eastern Province of Saudi Arabia during and after the Kuwaiti oil fires. The collected samples were analysed for toxic metals and oil hydrocarbon concentrations including some carcinogenic organic compounds in addition to gravimetric analysis. The concentration values of particulate matters were determined on a daily basis at Dhahran. Abqaiq, Rahima, Tanajib and Jubail locations. The analyses of the filters show a high concentration of the inhalable particulate at various locations, especially when north or northwest winds were blowing. It was found that the inhalable particulate concentration exceeded the Meteorology and Environmental Protection Administration (MEPA) permissible limit of 340 μg m- 3 at most of these locations during May-October 1991. A trend between the total suspended particulate and inhalable particulate measured concurrently at the same locations was observed and a regression equation was developed to correlate PM-10 data with the total suspended particulate data.

  17. Particulate Matter (Environmental Health Student Portal)

    Science.gov (United States)

    ... that includes curriculum standards, assessments, and lesson rubrics. Sources of Particulate Matter (U.S. Environmental Protection Agency) - Information and activity on interpreting ... U.S. National Library of Medicine National Institutes of Health U.S. Department ...

  18. Diesel Particulate Matter Polygons, California, 2005, NATA

    Data.gov (United States)

    U.S. Environmental Protection Agency — The national-scale assessment includes 177 air pollutants (a subset of the air toxics on the Clean Air Act's list of 187 air toxics plus diesel particulate matter...

  19. Diesel Particulate Matter Polygons, Hawaii, 2005, NATA

    Data.gov (United States)

    U.S. Environmental Protection Agency — The national-scale assessment includes 177 air pollutants (a subset of the air toxics on the Clean Air Act's list of 187 air toxics plus diesel particulate matter...

  20. Diesel Particulate Matter Polygons, Arizona, 2005, NATA

    Data.gov (United States)

    U.S. Environmental Protection Agency — The national-scale assessment includes 177 air pollutants (a subset of the air toxics on the Clean Air Act's list of 187 air toxics plus diesel particulate matter...

  1. Diesel Particulate Matter Polygons, Nevada, 2005, NATA

    Data.gov (United States)

    U.S. Environmental Protection Agency — The national-scale assessment includes 177 air pollutants (a subset of the air toxics on the Clean Air Act's list of 187 air toxics plus diesel particulate matter...

  2. Global Particulate Matter Source Apportionment

    Science.gov (United States)

    Lamancusa, C.; Wagstrom, K.

    2017-12-01

    As our global society develops and grows it is necessary to better understand the impacts and nuances of atmospheric chemistry, in particular those associated with atmospheric particulate matter. We have developed a source apportionment scheme for the GEOS-Chem global atmospheric chemical transport model. While these approaches have existed for several years in regional chemical transport models, the Global Particulate Matter Source Apportionment Technology (GPSAT) represents the first incorporation into a global chemical transport model. GPSAT runs in parallel to a standard GEOS-Chem run. GPSAT uses the fact that all molecules of a given species have the same probability of undergoing any given process as a core principle. This allows GPSAT to track many different species using only the flux information provided by GEOS-Chem's many processes. GPSAT accounts for the change in source specific concentrations as a result of aqueous and gas-phase chemistry, horizontal and vertical transport, condensation and evaporation on particulate matter, emissions, and wet and dry deposition. By using fluxes, GPSAT minimizes computational cost by circumventing the computationally costly chemistry and transport solvers. GPSAT will allow researchers to address many pertinent research questions about global particulate matter including the global impact of emissions from different source regions and the climate impacts from different source types and regions. For this first application of GPSAT, we investigate the contribution of the twenty largest urban areas worldwide to global particulate matter concentrations. The species investigated include: ammonium, nitrates, sulfates, and the secondary organic aerosols formed by the oxidation of benzene, isoprene, and terpenes. While GPSAT is not yet publically available, we will incorporate it into a future standard release of GEOS-Chem so that all GEOS-Chem users will have access to this new tool.

  3. Airborne particulate discriminator

    Science.gov (United States)

    Creek, Kathryn Louise [San Diego, CA; Castro, Alonso [Santa Fe, NM; Gray, Perry Clayton [Los Alamos, NM

    2009-08-11

    A method and apparatus for rapid and accurate detection and discrimination of biological, radiological, and chemical particles in air. A suspect aerosol of the target particulates is treated with a taggant aerosol of ultrafine particulates. Coagulation of the taggant and target particles causes a change in fluorescent properties of the cloud, providing an indication of the presence of the target.

  4. Heat and mass transfer in particulate suspensions

    CERN Document Server

    Michaelides, Efstathios E (Stathis)

    2013-01-01

    Heat and Mass Transfer in Particulate Suspensions is a critical review of the subject of heat and mass transfer related to particulate Suspensions, which include both fluid-particles and fluid-droplet Suspensions. Fundamentals, recent advances and industrial applications are examined. The subject of particulate heat and mass transfer is currently driven by two significant applications: energy transformations –primarily combustion – and heat transfer equipment. The first includes particle and droplet combustion processes in engineering Suspensions as diverse as the Fluidized Bed Reactors (FBR’s) and Internal Combustion Engines (ICE’s). On the heat transfer side, cooling with nanofluids, which include nanoparticles, has attracted a great deal of attention in the last decade both from the fundamental and the applied side and has produced several scientific publications. A monograph that combines the fundamentals of heat transfer with particulates as well as the modern applications of the subject would be...

  5. Electrically heated particulate filter enhanced ignition strategy

    Science.gov (United States)

    Gonze, Eugene V; Paratore, Jr., Michael J

    2012-10-23

    An exhaust system that processes exhaust generated by an engine is provided. The system generally includes a particulate filter (PF) that filters particulates from the exhaust wherein an upstream end of the PF receives exhaust from the engine. A grid of electrically resistive material is applied to an exterior upstream surface of the PF and selectively heats exhaust passing through the grid to initiate combustion of particulates within the PF. A catalyst coating applied to at least one of the PF and the grid. A control module estimates a temperature of the grid and controls the engine to produce a desired exhaust product to increase the temperature of the grid.

  6. Increased interestingness of extraneous details in a multimedia science presentation leads to decreased learning.

    Science.gov (United States)

    Mayer, Richard E; Griffith, Emily; Jurkowitz, Ilana T N; Rothman, Daniel

    2008-12-01

    In Experiment 1, students received an illustrated booklet, PowerPoint presentation, or narrated animation that explained 6 steps in how a cold virus infects the human body. The material included 6 high-interest details mainly about the role of viruses in sex or death (high group) or 6 low-interest details consisting of facts and health tips about viruses (low group). The low group outperformed the high group across all 3 media on a subsequent test of problem-solving transfer (d = .80) but not retention (d = .05). In Experiment 2, students who studied a PowerPoint lesson explaining the steps in how digestion works performed better on a problem-solving transfer test if the lesson contained 7 low-interest details rather than 7 high-interest details (d = .86), but the groups did not differ on retention (d = .26). In both experiments, as the interestingness of details was increased, student understanding decreased (as measured by transfer). Results are consistent with a cognitive theory of multimedia learning, in which highly interesting details sap processing capacity away from deeper cognitive processing of the core material during learning. PsycINFO Database Record (c) 2008 APA, all rights reserved.

  7. ADVANCED HYBRID PARTICULATE COLLECTOR

    Energy Technology Data Exchange (ETDEWEB)

    Ye Zhuang; Stanley J. Miller; Michelle R. Olderbak; Rich Gebert

    2001-12-01

    A new concept in particulate control, called an advanced hybrid particulate collector (AHPC), is being developed under funding from the U.S. Department of Energy. The AHPC combines the best features of electrostatic precipitators (ESPs) and baghouses in an entirely novel manner. The AHPC concept combines fabric filtration and electrostatic precipitation in the same housing, providing major synergism between the two methods, both in the particulate collection step and in transfer of dust to the hopper. The AHPC provides ultrahigh collection efficiency, overcoming the problem of excessive fine-particle emissions with conventional ESPs, and solves the problem of reentrainment and re-collection of dust in conventional baghouses. Phase I of the development effort consisted of design, construction, and testing of a 5.7-m{sup 3}/min (200-acfm) working AHPC model. Results from both 8-hr parametric tests and 100-hr proof-of-concept tests with two different coals demonstrated excellent operability and greater than 99.99% fine-particle collection efficiency. Since all of the developmental goals of Phase I were met, the approach was scaled up in Phase II to a size of 255 m{sup 3}/min (9000 acfm) (equivalent in size to 2.5 MW) and was installed on a slipstream at the Big Stone Power Plant. For Phase II, the AHPC at Big Stone Power Plant was operated continuously from late July 1999 until mid-December 1999. The Phase II results were highly successful in that ultrahigh particle collection efficiency was achieved, pressure drop was well controlled, and system operability was excellent. For Phase III, the AHPC was modified into a more compact configuration, and components were installed that were closer to what would be used in a full-scale commercial design. The modified AHPC was operated from April to July 2000. While operational results were acceptable during this time, inspection of bags in the summer of 2000 revealed some membrane damage to the fabric that appeared to be

  8. Particulate emissions from biodiesel fuelled CI engines

    International Nuclear Information System (INIS)

    Agarwal, Avinash Kumar; Gupta, Tarun; Shukla, Pravesh C.; Dhar, Atul

    2015-01-01

    hydrocarbons, crustal and anthropogenic trace metals, sulfates, and nitrates) in order to comprehensively assess the effects of biodiesel usage on the environment as well as on the human health. Control of particulate emissions using various engine control parameters such as intake air boosting using turbocharging, high pressure fuel injections, multiple injections, exhaust gas recirculation (EGR), and after-treatment devices in combination with the use of biodiesel has been critically assessed and included in this review article

  9. Shielded regeneration heating element for a particulate filter

    Science.gov (United States)

    Gonze, Eugene V [Pinckney, MI; Ament, Frank [Troy, MI

    2011-01-04

    An exhaust system includes a particulate filter (PF) that is disposed downstream from an engine. The PF filters particulates within an exhaust from the engine. A heating element heats particulate matter in the PF. A catalyst substrate or a flow converter is disposed upstream from said heating element. The catalyst substrate oxidizes the exhaust prior to reception by the heating element. The flow converter converts turbulent exhaust flow to laminar exhaust flow prior to reception by the heating element.

  10. Characterization of particulate amines

    International Nuclear Information System (INIS)

    Gundel, L.A.; Chang, S.G.; Clemenson, M.S.; Markowitz, S.S.; Novakov, T.

    1979-01-01

    The reduced nitrogen compounds associated with ambient particulate matter are chemically characterized by means of ESCA and proton activation analysis. Ambient particulate samples collected on silver filters in Berkeley, California were washed with water and organic solvents, and ESCA and proton activation analysis were performed in order to determine the composition of various nitrogen compounds and the total nitrogen content. It is found that 85% of the amines originally present in ambient particulate matter can be removed by water extraction, whereas the ammonium and nitrate are completely removed. An observed increase in ammonium ion in the extract, compared with its concentration in the original sample, coupled with the commensurate decrease in amine concentration, is attributed to the hydrolysis of amide groups, which may cause analytical methods based on extraction to yield erroneous results

  11. Mars on Earth: Analog basaltic soils and particulates from Lonar Crater, India, include Deccan soil, shocked soil, reworked lithic and glassy ejecta, and both shocked and unshocked baked zones

    Science.gov (United States)

    Wright, S. P.

    2017-12-01

    "There is no perfect analog for Mars on Earth" [first line of Hipkin et al. (2013) Icarus, 261-267]. However, fieldwork and corresponding sample analyses from laboratory instrumentation (to proxy field instruments) has resulted in the finding of unique analog materials that suggest that detailed investigations of Lonar Crater, India would be beneficial to the goals of the Mars Program. These are briefly described below as Analog Processes, Materials, and Fieldwork. Analog Processes: The geologic history of Lonar Crater emulates localities on Mars with 1.) flood basaltic volcanism with interlayer development of 2.) baked zones or "boles" and 3.) soil formation. Of six flows, the lower three are aqueously altered by groundwater to produce a range of 4.) alteration products described below. The impact event 570 ka produced a range of 5.) impactites including shocked baked zones, shocked soils, and altered basalt shocked to a range of shock pressures [Kieffer et al., 1976]. Analog Materials: 65 Ma Deccan basalt contains augite and labradorite. Baked zones are higher in hematite and other iron oxides. Soil consists of calcite and organic matter. Several basalts with secondary alteration are listed here and these mirror alteration on Mars: hematite, chlorite, serpentine, zeolite, and palagonite, with varying combinations of these with primary igneous minerals. All of these materials (#1 through 4 above) are shocked to a range of shocked pressures to produce maskelynite, flowing plagioclase glass, vesiculated plagioclase glass, and complete impact melts. Shocked soils contain schlieren calcite amidst comminuted grains of augite, labradorite, and these glasses. Shocked baked zones unsurprisingly have a petrographic texture similar to hornfels, another product of contact metamorphism. Analog Fieldwork: The ejecta consists of two layers: 8 m of lithic breccia with unshocked and fractured basalts under a 1 m suevite consisting of all ranges of shock pressure described above

  12. Radiant zone heated particulate filter

    Science.gov (United States)

    Gonze, Eugene V [Pinckney, MI

    2011-12-27

    A system includes a particulate matter (PM) filter including an upstream end for receiving exhaust gas and a downstream end. A radiant zoned heater includes N zones, where N is an integer greater than one, wherein each of the N zones includes M sub-zones, where M is an integer greater than or equal to one. A control module selectively activates at least a selected one of the N zones to initiate regeneration in downstream portions of the PM filter from the one of the N zones, restricts exhaust gas flow in a portion of the PM filter that corresponds to the selected one of the N zones, and deactivates non-selected ones of the N zones.

  13. Particulate matter sensor with a heater

    Science.gov (United States)

    Hall, Matthew [Austin, TX

    2011-08-16

    An apparatus to detect particulate matter. The apparatus includes a sensor electrode, a shroud, and a heater. The electrode measures a chemical composition within an exhaust stream. The shroud surrounds at least a portion of the sensor electrode, exclusive of a distal end of the sensor electrode exposed to the exhaust stream. The shroud defines an air gap between the sensor electrode and the shroud and an opening toward the distal end of the sensor electrode. The heater is mounted relative to the sensor electrode. The heater burns off particulate matter in the air gap between the sensor electrode and the shroud.

  14. Migration of particulates in permeable rock columns

    International Nuclear Information System (INIS)

    Cropper, R.L.

    1982-01-01

    The migration of radioactive material through soil and permeable rock formations have become a major topic of concern due to the interest in the licensing of new radioactive waste disposal sites. Previously, research has been conducted in relation to deep repositories; however, similar situations arise in the vadose zone, where there is a higher probability of naturally-occurring particulates of organic nature and for the incursion of water. Test data has provided information which suggests that particulates will travel through porous media subject to various delay mechnisms and must be included in any consideration of waste migration. Data concerning particulate migration must and should be considered in the future when radioactive waste disposal sites are licensed

  15. The mechanical behaviour of packed particulates

    International Nuclear Information System (INIS)

    Dutton, R.

    1998-01-01

    and temperature. The application of these maps to particulate compaction is reviewed and recommendations are made for their utilization to assess the long-term mechanical performance of the waste container. To obtain some empirical evidence over very long timescales (measured in millions of years), we have examined the geological literature. This includes specific information on the compaction of quartz sand, together with related data on creep deformation in monolithic quartzite rocks. Based on current understanding of creep mechanisms, availability of experimental measurements and long-term inference from geological phenomena, it would appear that time-dependent compaction of quartz-like particulates at 100 deg C occurs very slowly. Recommendations for quantifying the collective mechanical behaviour of the particulate, and relating this to the expected lifetime of the waste container, are presented. (author)

  16. The mechanical behaviour of packed particulates

    Energy Technology Data Exchange (ETDEWEB)

    Dutton, R

    1998-01-01

    range of stress and temperature. The application of these maps to particulate compaction is reviewed and recommendations are made for their utilization to assess the long-term mechanical performance of the waste container. To obtain some empirical evidence over very long timescales (measured in millions of years), we have examined the geological literature. This includes specific information on the compaction of quartz sand, together with related data on creep deformation in monolithic quartzite rocks. Based on current understanding of creep mechanisms, availability of experimental measurements and long-term inference from geological phenomena, it would appear that time-dependent compaction of quartz-like particulates at 100 deg C occurs very slowly. Recommendations for quantifying the collective mechanical behaviour of the particulate, and relating this to the expected lifetime of the waste container, are presented. (author)

  17. Controlling particulate matter under the Clean Air Act: a menu of options

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-07-01

    This document was prepared by STAPPA and ALAPCO to help US state and local air pollution control officials understand the effects of particulate matter (PM) on human health and air quality, the relative contribution of various sources to particulate emissions, and the effectiveness and costs of various approaches - including innovative ones - to minimizing these emissions. The document covers particulate matter with a nominal diameter of 10 microns ({mu}m) or less (PM{sub 10}), including `fine` PM of 2.5 microns or less in diameter (PM{sub 2.5}). Sections cover: the effects of particulate matter on human health; regulatory issues; characterization of particulate matter; emission control strategies for mobile sources (diesel engines, small nonroad engines, alternative fuels etc.), particulates from stationary sources (electric utilities, industry and commercial fuel combustion; mineral products industry, metallurgical industry etc.); particulates from area sources; and market-based strategies for controlling particulate matter. 2 apps.

  18. Airborne particulate matter in spacecraft

    Science.gov (United States)

    1988-01-01

    Acceptability limits and sampling and monitoring strategies for airborne particles in spacecraft were considered. Based on instances of eye and respiratory tract irritation reported by Shuttle flight crews, the following acceptability limits for airborne particles were recommended: for flights of 1 week or less duration (1 mg/cu m for particles less than 10 microns in aerodynamic diameter (AD) plus 1 mg/cu m for particles 10 to 100 microns in AD); and for flights greater than 1 week and up to 6 months in duration (0.2 mg/cu m for particles less than 10 microns in AD plus 0.2 mg/cu m for particles 10 to 100 microns in AD. These numerical limits were recommended to aid in spacecraft atmosphere design which should aim at particulate levels that are a low as reasonably achievable. Sampling of spacecraft atmospheres for particles should include size-fractionated samples of 0 to 10, 10 to 100, and greater than 100 micron particles for mass concentration measurement and elementary chemical analysis by nondestructive analysis techniques. Morphological and chemical analyses of single particles should also be made to aid in identifying airborne particulate sources. Air cleaning systems based on inertial collection principles and fine particle collection devices based on electrostatic precipitation and filtration should be considered for incorporation into spacecraft air circulation systems. It was also recommended that research be carried out in space in the areas of health effects and particle characterization.

  19. Electrically heated particulate filter regeneration methods and systems for hybrid vehicles

    Science.gov (United States)

    Gonze, Eugene V.; Paratore, Jr., Michael J.

    2010-10-12

    A control system for controlling regeneration of a particulate filter for a hybrid vehicle is provided. The system generally includes a regeneration module that controls current to the particulate filter to initiate regeneration. An engine control module controls operation of an engine of the hybrid vehicle based on the control of the current to the particulate filter.

  20. The evaluation of a ceramic diesel particulate filter in an underground mine laboratory

    International Nuclear Information System (INIS)

    Carlson, D.H.; Bucheger, D.; Patton, M.; Johnson, J.H.

    1986-01-01

    This paper details the collection of diesel exhaust particulate from the instrumented Wagner ST5A load-haul-dump vehicle during a simulated ore loading and hauling operation. An evaluation of the exhaust included measurements to determine the effect of the Corning diesel particulate filter (DPF) on air quality, and the effect of operating variables and fuel additives on DPF regeneration. The results demonstrate the important effects of other mine particulate sources on the particulate collection efficiency

  1. Advanced Fine Particulate Characterization Methods

    Energy Technology Data Exchange (ETDEWEB)

    Steven Benson; Lingbu Kong; Alexander Azenkeng; Jason Laumb; Robert Jensen; Edwin Olson; Jill MacKenzie; A.M. Rokanuzzaman

    2007-01-31

    The characterization and control of emissions from combustion sources are of significant importance in improving local and regional air quality. Such emissions include fine particulate matter, organic carbon compounds, and NO{sub x} and SO{sub 2} gases, along with mercury and other toxic metals. This project involved four activities including Further Development of Analytical Techniques for PM{sub 10} and PM{sub 2.5} Characterization and Source Apportionment and Management, Organic Carbonaceous Particulate and Metal Speciation for Source Apportionment Studies, Quantum Modeling, and High-Potassium Carbon Production with Biomass-Coal Blending. The key accomplishments included the development of improved automated methods to characterize the inorganic and organic components particulate matter. The methods involved the use of scanning electron microscopy and x-ray microanalysis for the inorganic fraction and a combination of extractive methods combined with near-edge x-ray absorption fine structure to characterize the organic fraction. These methods have direction application for source apportionment studies of PM because they provide detailed inorganic analysis along with total organic and elemental carbon (OC/EC) quantification. Quantum modeling using density functional theory (DFT) calculations was used to further elucidate a recently developed mechanistic model for mercury speciation in coal combustion systems and interactions on activated carbon. Reaction energies, enthalpies, free energies and binding energies of Hg species to the prototype molecules were derived from the data obtained in these calculations. Bimolecular rate constants for the various elementary steps in the mechanism have been estimated using the hard-sphere collision theory approximation, and the results seem to indicate that extremely fast kinetics could be involved in these surface reactions. Activated carbon was produced from a blend of lignite coal from the Center Mine in North Dakota and

  2. Characteristics of Airborne Particulates Containing Naturally Occurring Radioactive Materials in Monazite Industry

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Yong Geon; Choi, Cheol Kyu; Park, Il; Kim, Min Jun; Go, A Ra; Ji, Seung Woo; Kim, Kwang Pyo [Kyunghee University, Yongin (Korea, Republic of); Koo, Bon Cheol [KINS, Daejeon (Korea, Republic of)

    2016-05-15

    The objective of this study was to characterize physicochemical properties of airborne particulates at a monazite pulverization industry. The properties included particulate size distribution, concentration, shape, density, and radioactivity concentration. Monazite is one of the minerals containing naturally occurring radioactive material (NORM). Therefore, external and internal exposure can be occurred to the workers in monazite industry. The major exposure pathway of the workers is internal exposure due to inhalation of airborne particulates. According to International Commission on Radiological Protection (ICRP), radiation dose due to inhaled particulates containing NORM depends on particulate properties. Therefore, ICRP recommended the internal dose assessment using measured physicochemical properties of the airborne particulates. In the absence of specific information, ICRP provided default reference values. In this study, we characterized physicochemical properties of airborne particulates at a monazite pulverization industry. The databases of particulate information can be used for accurate internal dose assessment of worker.

  3. Ambient particulate matter as a risk factor for suicide.

    Science.gov (United States)

    Kim, Changsoo; Jung, Sang Hyuk; Kang, Dae Ryong; Kim, Hyeon Chang; Moon, Ki Tae; Hur, Nam Wook; Shin, Dong Chun; Suh, Il

    2010-09-01

    The authors assessed the relationship between exposure to ambient particulate matter and suicide in urban settings during a 1-year period. The association between particulate matter and suicide was determined using a time-stratified case-crossover approach in which subjects served as their own controls. All suicide cases (4,341) in 2004 that occurred in seven cities in the Republic of Korea were included. Hourly mean concentrations of particulate matter suicide risk associated with an interquartile range increase in particulate matter was determined by conditional logistic regression analysis after adjusting for national holidays and meteorological factors. Subgroup analysis was performed after stratification by underlying disease (cardiovascular disease, diabetes mellitus, chronic obstructive pulmonary disease, cancer, and psychiatric illness). The largest associations were a 9.0% increase (95% CI=2.4-16.1) and a 10.1% (95% CI=2.0-19.0) increase in suicide risk related to an interquartile range increase in particulate matter suicide) and particulate matter suicide), respectively. Among individuals with cardiovascular disease, a significant association between particulate matter suicide) and suicide was observed (18.9%; 95% CI=3.2-37.0). Conclusions: A transient increase in particulate matter was associated with increased suicide risk, especially for individuals with preexisting cardiovascular disease.

  4. Diesel Particulate Matter Polygons, US EPA Region 9, 2005, NATA

    Data.gov (United States)

    U.S. Environmental Protection Agency — The national-scale assessment includes 177 air pollutants (a subset of the air toxics on the Clean Air Act's list of 187 air toxics plus diesel particulate matter...

  5. AIRWAY EPITHELIAL EFFECTS OF PARTICULATE POLLUTANTS: ROLE OF METAL INTERACTIONS

    Science.gov (United States)

    Numerous epidemiologic studies have demonstrated positive associations with particulate matter (PM) air pollution and daily respiratory morbidity - including exacerbations of asthma. Data are needed to elucidate which PM subcomponents may be mediating disease exacerbation in ind...

  6. Zone heated inlet ignited diesel particulate filter regeneration

    Science.gov (United States)

    Gonze, Eugene V [Pinckney, MI; Ament, Frank [Troy, MI

    2012-06-26

    An exhaust system that processes exhaust generated by an engine is provided. The system includes: a particulate filter (PF) that is disposed downstream of the engine and that filters particulates from the exhaust; and a grid that includes electrically resistive material that is segmented by non-conductive material into a plurality of zones and wherein the grid is applied to an exterior upstream surface of the PF.

  7. DESIGN OF PARTICULATE MATERIAL COMPACTOR ROLLS DIAMETER

    Directory of Open Access Journals (Sweden)

    Peter Peciar

    2017-09-01

    Full Text Available At present, in a period of an industrial expansion great emphasis is placed on the environment. That means aiming for a reduced energy consumption, and also lessening dustiness from very fine powder material. This category also includes particulate material agglomeration processes. Because this process is very energy-intensive, it is necessary to correctly design these devices. The aim of this paper is to focus on a theoretical design of a production compactor with the rolls diameter for an experimental particulate material, based on Johanson’s theory and experimentally measured material properties. The material used for experimental measurements was an NPK-based industrial fertilizer consisting of several components. The results of this paper is the dependence of the ratio of the maximum compression pressure to the initial compression pressure from the rolls diameter of the proposed compactor.

  8. Dynamics of Charged Particulate Systems Modeling, Theory and Computation

    CERN Document Server

    Zohdi, Tarek I

    2012-01-01

    The objective of this monograph is to provide a concise introduction to the dynamics of systems comprised of charged small-scale particles. Flowing, small-scale, particles ("particulates'') are ubiquitous in industrial processes and in the natural sciences. Applications include electrostatic copiers, inkjet printers, powder coating machines, etc., and a variety of manufacturing processes. Due to their small-scale size, external electromagnetic fields can be utilized to manipulate and control charged particulates in industrial processes in order to achieve results that are not possible by purely mechanical means alone. A unique feature of small-scale particulate flows is that they exhibit a strong sensitivity to interparticle near-field forces, leading to nonstandard particulate dynamics, agglomeration and cluster formation, which can strongly affect manufactured product quality. This monograph also provides an introduction to the mathematically-related topic of the dynamics of swarms of interacting objects, ...

  9. Polarimetric Remote Sensing of Atmospheric Particulate Pollutants

    Science.gov (United States)

    Li, Z.; Zhang, Y.; Hong, J.

    2018-04-01

    Atmospheric particulate pollutants not only reduce atmospheric visibility, change the energy balance of the troposphere, but also affect human and vegetation health. For monitoring the particulate pollutants, we establish and develop a series of inversion algorithms based on polarimetric remote sensing technology which has unique advantages in dealing with atmospheric particulates. A solution is pointed out to estimate the near surface PM2.5 mass concentrations from full remote sensing measurements including polarimetric, active and infrared remote sensing technologies. It is found that the mean relative error of PM2.5 retrieved by full remote sensing measurements is 35.5 % in the case of October 5th 2013, improved to a certain degree compared to previous studies. A systematic comparison with the ground-based observations further indicates the effectiveness of the inversion algorithm and reliability of results. A new generation of polarized sensors (DPC and PCF), whose observation can support these algorithms, will be onboard GF series satellites and launched by China in the near future.

  10. POLARIMETRIC REMOTE SENSING OF ATMOSPHERIC PARTICULATE POLLUTANTS

    Directory of Open Access Journals (Sweden)

    Z. Li

    2018-04-01

    Full Text Available Atmospheric particulate pollutants not only reduce atmospheric visibility, change the energy balance of the troposphere, but also affect human and vegetation health. For monitoring the particulate pollutants, we establish and develop a series of inversion algorithms based on polarimetric remote sensing technology which has unique advantages in dealing with atmospheric particulates. A solution is pointed out to estimate the near surface PM2.5 mass concentrations from full remote sensing measurements including polarimetric, active and infrared remote sensing technologies. It is found that the mean relative error of PM2.5 retrieved by full remote sensing measurements is 35.5 % in the case of October 5th 2013, improved to a certain degree compared to previous studies. A systematic comparison with the ground-based observations further indicates the effectiveness of the inversion algorithm and reliability of results. A new generation of polarized sensors (DPC and PCF, whose observation can support these algorithms, will be onboard GF series satellites and launched by China in the near future.

  11. Making Sense of Extraneous Solutions

    Science.gov (United States)

    Zelkowski, Jeremy S.

    2013-01-01

    Principles and Standards for School Mathematics (NCTM 2000) states, "Technology is essential in teaching and learning mathematics; it influences the mathematics that is taught and enhances students' learning." The focus on reasoning and sense making with technology in the lesson presented in this article will enable students to do more…

  12. Particulate carbon in the atmosphere

    International Nuclear Information System (INIS)

    Surakka, J.

    1992-01-01

    Carbonaceous aerosols are emitted to the atmosphere in combustion processes. Carbon particles are very small and have a long residence time in the air. Black Carbon, a type of carbon aerosol, is a good label when transport of combustion emissions in the atmosphere is studied. It is also useful tool in air quality studies. Carbon particles absorb light 6.5 to 8 times stronger than any other particulate matter in the air. Their effect on decreasing visibility is about 50 %. Weather disturbances are also caused by carbon emissions e.g. in Kuwait. Carbon particles have big absorption surface and capacity to catalyze different heterogenous reactions in air. Due to their special chemical and physical properties particulate carbon is a significant air pollution specie, especially in urban air. Average particulate carbon concentration of 5.7 μg/m 2 have been measured in winter months in Helsinki

  13. Understanding particulate coating microstructure development

    Science.gov (United States)

    Roberts, Christine Cardinal

    How a dispersion of particulates suspended in a solvent dries into a solid coating often is more important to the final coating quality than even its composition. Essential properties like porosity, strength, gloss, particulate order, and concentration gradients are all determined by the way the particles come together as the coating dries. Cryogenic scanning electron microscopy (cryoSEM) is one of the most effective methods to directly visualize a drying coating during film formation. Using this method, the coating is frozen, arresting particulate motion and solidifying the sample so that it be imaged in an SEM. In this thesis, the microstructure development of particulate coatings was explored with several case studies. First, the effect of drying conditions was determined on the collapse of hollow latex particles, which are inexpensive whiteners for paint. Using cryoSEM, it was found that collapse occurs during the last stages of drying and is most likely to occur at high drying temperatures, humidity, and with low binder concentration. From these results, a theoretical model was proposed for the collapse of a hollow latex particle. CryoSEM was also used to verify a theoretical model for the particulate concentration gradients that may develop in a coating during drying for various evaporation, sedimentation and particulate diffusion rates. This work created a simple drying map that will allow others to predict the character of a drying coating based on easily calculable parameters. Finally, the effect of temperature on the coalescence and cracking of latex coatings was explored. A new drying regime for latex coatings was identified, where partial coalescence of particles does not prevent cracking. Silica was shown to be an environmentally friendly additive for preventing crack formation in this regime.

  14. The electromagnetic and acoustic properties of smoke particulates

    International Nuclear Information System (INIS)

    Churches, D.K.

    1999-10-01

    The research work explores the Electromagnetic and Acoustic Properties of Smoke Particulates from real fires, and the initial development of an alternative method of smoke detection based on the study work. The research was entirely self-funded including the purchase of the experimental apparatus, test equipment and calibration to international standards. The study includes the properties of solid and liquid post combustion particulates in air suspension forming smoke plumes, and the associated fluid flow dynamics. As part of the study the electromagnetic and acoustic properties of smoke particulates, a somewhat unique detection method described as the ''Double Matrix Board System'' was developed and used. It was initially developed to assist in the electromagnetic study work, and was later modified to examine the acoustic properties. The published results of the research on the ''Double Matrix Board System'' and the details of the patent application for the device are included in the Appendices to the Thesis document. (author)

  15. Effect of lubricant oil properties on the performance of gasoline particulate filter (GPF)

    Energy Technology Data Exchange (ETDEWEB)

    Shao, Huifang; Lam, William; Remias, Joseph; Roos, Joseph; Seong, HeeJe; Choi, Seungmok

    2016-10-17

    Mobile source emissions standards are becoming more stringent and particulate emissions from gasoline direct injection (GDI) engines represent a particular challenge. Gasoline particulate filter (GPF) is deemed as one possible technical solution for particulate emissions reduction. In this work, a study was conducted on eight formulations of lubricants to determine their effect on GDI engine particulate emissions and GPF performance. Accelerated ash loading tests were conducted on a 2.4L GDI engine with engine oil injection in gasoline fuel by 2%. The matrix of eight formulations was designed with changing levels of sulfated ash (SASH) level, Zinc dialkyldithiophosphates (ZDDP) level and detergent type. Comprehensive evaluations of particulates included mass, number, size distribution, composition, morphology and soot oxidation properties. GPF performance was assessed through filtration efficiency, back pressure and morphology. It was determined that oil formulation affects the particulate emission characteristics and subsequent GPF performance.

  16. CDC WONDER: Daily Fine Particulate Matter

    Data.gov (United States)

    U.S. Department of Health & Human Services — The Daily Fine Particulate Matter data available on CDC WONDER are geographically aggregated daily measures of fine particulate matter in the outdoor air, spanning...

  17. Particulate Matter: a closer look

    NARCIS (Netherlands)

    Buijsman E; Beck JP; Bree L van; Cassee FR; Koelemeijer RBA; Matthijsen J; Thomas R; Wieringa K; LED; MGO

    2005-01-01

    The summary in booklet form 'Fijn stof nader bekeken' (Particulate Matter: a closer look) , published in Dutch by the Netherlands Environmental Assessment Agency (MNP) and the Environment and Safety Division of the National Institute for Public Health and the Environment (RIVM), has been designed to

  18. Laser particulate spectrometer

    Science.gov (United States)

    Boyd, B. A.; Linford, R. M. F.; Schmitt, R. J.

    1977-01-01

    Hybrid laser scattering and extinction technique measures particle diameters from 0.8 to 2.75 micrometers and speeds from 0.2 to 20 m/s. Operating pressures range from ambient to ultra-high vacuum, and temperatures range from 77 to 300 K. Potential applications include air pollution, clean room, and particle size monitoring.

  19. Identification and Characterization of Particulate Matter Concentrations at Construction Jobsites

    Directory of Open Access Journals (Sweden)

    Ingrid P. S. Araújo

    2014-11-01

    Full Text Available The identification and characterization of particulate matter (PM concentrations from construction site activities pose major challenges due to the diverse characteristics related to different aspects, such as concentration, particle size and particle composition. Moreover, the characterization of particulate matter is influenced by meteorological conditions, including temperature, humidity, rainfall and wind speed. This paper is part of a broader investigation that aims to develop a methodology for assessing the environmental impacts caused by the PM emissions that arise from construction activities. The objective of this paper is to identify and characterize the PM emissions on a construction site with different aerodynamic diameters (PM2.5, PM10, total suspended particulates (TSP, based on an exploratory study. Initially, a protocol was developed to standardize the construction site selection criteria, laboratory procedures, field sample collection and laboratory analysis. This protocol was applied on a multifamily residential building construction site during three different construction phases (earthworks, superstructure and finishings aimed at measuring and monitoring PM concentrations arising from construction activities. The particulate matter was characterized in different particle sizes. Results showed that the higher TSP emissions arising from construction activities provoked environmental impacts. Some limitations to the results were identified, especially with regards the need for a detailed investigation about the influence of different construction phases on PM emissions. The findings provided significant knowledge about various situations, serving as a basis for improving the existing methodology for particulate material collection on construction sites and the development of future studies on the specific construction site phases.

  20. Evaluation of airborne particulates and fungi during hospital renovation.

    Science.gov (United States)

    Overberger, P A; Wadowsky, R M; Schaper, M M

    1995-07-01

    This study was conducted over 30 weeks on a hospital floor undergoing partial renovation. Some patients housed on the floor were immunosuppressed, including bone marrow transplant recipients. The construction zone was placed under negative pressure and was separated from patient rooms by existing hospital walls and via erection of a temporary barrier. Other control measures minimized patient exposure to airborne materials. Air sampling was done for 3 weeks prior to construction, 24 weeks during construction, and 3 weeks after renovation was completed. Airborne particulate concentrations, total spore counts, particle size, and fungal species were assessed. At the beginning of the renovation there were increases in airborne particulates (from 0.2 to 2.0 mg/m3) and fungal spores (from 3.5 to 350 colony forming units (CFU/m3), but only in the construction zone. Throughout the remainder of the renovation, particulate and fungal spore levels fluctuated inside the construction zone but remained close to baseline values in the patient area. When renovation was completed, particulates and spore counts inside the construction zone decreased to preconstruction levels. The primary fungus isolated from air samples was Penicillium. This study demonstrated that control measures were effective in reducing exposures of hospitalized patients to airborne particulates and spores and in reducing the increased risk of aspergillosis and other fungal infections associated with hospital construction projects. The data from this study may be useful in establishing exposure guidelines for other health care settings.

  1. Polycyclic aromatic hydrocarbon in fine particulate matter emitted from burning kerosene, liquid petroleum gas, and wood fuels in household cookstoves

    Data.gov (United States)

    U.S. Environmental Protection Agency — This dataset includes all data in figures in the manuscript and supporting information for the publication entitled "Particulate polycyclic aromatic hydrocarbon...

  2. Generalized Effective Medium Theory for Particulate Nanocomposite Materials

    Directory of Open Access Journals (Sweden)

    Muhammad Usama Siddiqui

    2016-08-01

    Full Text Available The thermal conductivity of particulate nanocomposites is strongly dependent on the size, shape, orientation and dispersion uniformity of the inclusions. To correctly estimate the effective thermal conductivity of the nanocomposite, all these factors should be included in the prediction model. In this paper, the formulation of a generalized effective medium theory for the determination of the effective thermal conductivity of particulate nanocomposites with multiple inclusions is presented. The formulated methodology takes into account all the factors mentioned above and can be used to model nanocomposites with multiple inclusions that are randomly oriented or aligned in a particular direction. The effect of inclusion dispersion non-uniformity is modeled using a two-scale approach. The applications of the formulated effective medium theory are demonstrated using previously published experimental and numerical results for several particulate nanocomposites.

  3. Electrification of particulates in industrial and natural multiphase flows

    CERN Document Server

    Gu, Zhaolin

    2017-01-01

    This book introduces comprehensive fundamentals, numerical simulations and experimental methods of electrification of particulates entrained multiphase flows. The electrifications of two particulate forms, liquid droplets and solid particles, are firstly described together. Liquid droplets can be charged under preset or associated electric fields, while solid particles can be charged through contact. Different charging ways in gas (liquid)-liquid or gas-solid multiphase flows are summarized, including ones that are beneficial to industrial processes, such as electrostatic precipitation, electrostatic spraying, and electrostatic separation, etc., ones harmful for shipping and powder industry, and ones occurring in natural phenomenon, such as wind-blown sand and thunderstorm. This book offers theoretical references to the control and utilization of the charging or charged particulates in multiphase flows as well.

  4. Protective coatings for commercial particulates

    DEFF Research Database (Denmark)

    Kindl, B.; Teng, Y.H.; Liu, Y.L.

    1994-01-01

    SiC/Al composites are in large-scale production with Al-Si alloy matrices. The same composites with pure Al or low Si matrices need diffusion barriers on the SiC reinforcement to control the interfacial reaction. The present paper describes various approaches taken to obtain protective coatings...... of alumina and zirconia on SiC particulates by sol-gel techniques. Aqueous and organic precursors have been used. The extent of the reaction, i.e., the Si and Al4C3 content in the matrix, was determined by differential thermal analysis and X-ray diffraction. The reaction rates of some coated particulates...... in liquid Al are decreased by as much as one order of magnitude during the first 15 min of immersion. Pretreatments of the SiC surface, the composition and thickness of the coating interphase and heat treatments of the coated materials have been studied, and are discussed in relation to their effect...

  5. Effect of Particulates Generated from Asphalt Production on the ...

    African Journals Online (AJOL)

    PROF HORSFALL

    in air, including dust, soot, dirt, smoke and liquid droplets. Particulate matter is of localized importance near roads, cement works, and other industrial areas. Apart from screening out sunlight, dust on leaf blocks stomata and lowers their conductants to Carbon iv oxide (Jitin and Manish, 2014). Asphalt, which is also referred ...

  6. Characterization of biological particulate loads in metropolitan air

    Science.gov (United States)

    J. A. Snow; R. D. Schein; W. J. Moroz

    1977-01-01

    The atmospheric particulate load includes a wide range of naturally occurring particles of biological origin that serve as a reservoir of allergenic agents in respiratory disease. Improved knowledge of potential aeroallergens is needed by medical clinicians. Aims are to better characterize air spora, qualitatively and quantitatively, and determine daily (by hour)...

  7. Particulate characterization by PIXE multivariate spectral analysis

    International Nuclear Information System (INIS)

    Antolak, Arlyn J.; Morse, Daniel H.; Grant, Patrick G.; Kotula, Paul G.; Doyle, Barney L.; Richardson, Charles B.

    2007-01-01

    Obtaining particulate compositional maps from scanned PIXE (proton-induced X-ray emission) measurements is extremely difficult due to the complexity of analyzing spectroscopic data collected with low signal-to-noise at each scan point (pixel). Multivariate spectral analysis has the potential to analyze such data sets by reducing the PIXE data to a limited number of physically realizable and easily interpretable components (that include both spectral and image information). We have adapted the AXSIA (automated expert spectral image analysis) program, originally developed by Sandia National Laboratories to quantify electron-excited X-ray spectroscopy data, for this purpose. Samples consisting of particulates with known compositions and sizes were loaded onto Mylar and paper filter substrates and analyzed by scanned micro-PIXE. The data sets were processed by AXSIA and the associated principal component spectral data were quantified by converting the weighting images into concentration maps. The results indicate automated, nonbiased, multivariate statistical analysis is useful for converting very large amounts of data into a smaller, more manageable number of compositional components needed for locating individual particles-of-interest on large area collection media

  8. Final report for measurement of primary particulate matter emissions from light-duty motor vehicles

    Energy Technology Data Exchange (ETDEWEB)

    Norbeck, J. M.; Durbin, T. D.; Truex, T. J.

    1998-12-31

    This report describes the results of a particulate emissions study conducted at the University of California, Riverside, College of Engineering-Center for Environmental Research and Technology (CE-CERT) from September of 1996 to August of 1997. The goal of this program was to expand the database of particulate emissions measurements from motor vehicles to include larger numbers of representative in-use vehicles. This work was co-sponsored by the Coordinating Research Council (CRC), the South Coast Air Quality Management District (SCAQMD), and the National Renewable Energy Laboratory (NREL) and was part of a larger study of particulate emissions being conducted in several states under sponsorship by CRC. For this work, FTP particulate mass emission rates were determined for gasoline and diesel vehicles, along with the fractions of particulates below 2.5 and 10 microns aerodynamic diameter. A total of 129 gasoline-fueled vehicles and 19 diesel-fueled vehicles were tested as part of the program.

  9. PIXE analysis of vehicle exhaust particulate

    International Nuclear Information System (INIS)

    Shi Xianfeng; Yao Huiying; Liu Bo; Sun Minde; Xu Huawei; Mi Yong; Shen Hao

    2001-01-01

    PIXE technique on the analysis of vehicle exhaust particulate is introduced. The clement composition and concentration of particulate are obtained. Some elements which are related to environmental pollution such as sulfur lead, silicon and manganese, were analyzed and discussed in detail by PIXE technique Nowadays although unleaded gasoline is widely used, the lead concentration is still very high in exhaust particulate. The concentrations of silicon and manganese in exhaust particulate from different model vehicles are also quite high from measurements. It shows that an evidence for exhaust pollution control could be provided from this work

  10. Production, handling and characterization of particulate materials

    CERN Document Server

    Meesters, Gabriel

    2016-01-01

    This edited volume presents most techniques and methods that have been developed by material scientists, chemists, chemical engineers and physicists for the commercial production of particulate materials, ranging from the millimeter to the nanometer scale.  The scope includes the physical and chemical background, experimental optimization of equipment and procedures, as well as an outlook on future methods. The books addresses  issues of industrial importance such as specifications, control parameter(s), control strategy, process models, energy consumption and discusses the various techniques in relation to potential applications. In addition to the production processes, all major unit operations and characterization methods are described in this book. It differs from other books which are devoted to a single technique or a single material. Contributors to this book are acknowledged experts in their field. The aim of the book is to facilitate comparison of the different unit operations leading to optimum...

  11. Dans le tourbillon des particules

    CERN Document Server

    Zito, Marco

    2015-01-01

    Accélérateurs géants, détecteurs complexes, particules énigmatiques... La physique subatomique peut sembler bien intimidante pour le novice. Et pourtant, qui n a jamais entendu parler du boson de Higgs et du CERN, le laboratoire européen où il a été découvert en 2012 ? Nul besoin d être un spécialiste pour comprendre de quoi il s agit. Aujourd hui, une théorie extraordinairement élégante, le Modèle Standard, décrit tous les résultats des expériences dans le domaine. Trente-sept particules élémentaires et quatre forces fondamentales : c est tout ce dont nous avons besoin pour expliquer la matière et l Univers ! Ce livre, destiné à un large public, raconte sans équations le long parcours qui a abouti au Modèle Standard. Ce parcours, parfois sinueux, a été entamé lorsque les Grecs anciens, et peut-être d autres avant eux, ont imaginé que la matière est composée de petites « billes ». Il faudra attendre plusieurs siècles pour qu on réalise que la matière, à l échelle micros...

  12. AGE AND STRAIN INFLUENCES ON LUNG RESPONSES TO CONCENTRATED AIR PARTICULATES (CAPS) IN RODENTS

    Science.gov (United States)

    Asthma, an inflammatory airways disease, is an urgent health problem. Recent epidemiologic studies have demonstrated positive associations between ambient air particulate matter concentrations and daily respiratory morbidity ? including exacerbations of asthma. Of note, elderly i...

  13. A possible link between particulate matter air pollution and type 2 diabetes

    NARCIS (Netherlands)

    Volders, Evelien

    2008-01-01

    Particulate matter (PM) air pollution is most commonly referred to as PM10 and can be subdivided into coarse particles, fine particles and ultrafine particles. Sources of PM air pollution include combustion from car engines and industrial processes. Expos

  14. DIII-D dust particulate characterization (June 1998 Vent)

    International Nuclear Information System (INIS)

    Carmack, W.J.

    1999-01-01

    Dust is a key component of fusion power device accident source term. Understanding the amount of dust expected in fusion power devices and its physical and chemical characteristics is needed to verify assumptions currently used in safety analyses. An important part of this safety research and development work is to characterize dust from existing experimental tokamaks. In this report, the authors present the collection, data analysis methods used, and the characterization of dust particulate collected from various locations inside the General Atomics DIII-D vacuum vessel following the June 1998 vent. The collected particulate was analyzed at the Idaho National Engineering and Environmental Laboratory (INEEL). Two methods were used to collect particulate with the goal of preserving the particle size distribution and physical characteristics of the particulate. Choice of collection technique is important because the sampling method used can bias the particle size distribution collected. Vacuum collection on substrates and adhesion removal with metallurgical replicating tape were chosen as non-intrusive sampling methods. Seventeen samples were collected including plasma facing surfaces in lower, upper, and horizontal locations, surfaces behind floor tiles, surfaces behind divert or tiles, and surfaces behind ceiling tiles. The results of the analysis are presented

  15. Comparison of high efficiency particulate filter testing methods

    International Nuclear Information System (INIS)

    1985-01-01

    High Efficiency Particulate Air (HEPA) filters are used for the removal of submicron size particulates from air streams. In nuclear industry they are used as an important engineering safeguard to prevent the release of air borne radioactive particulates to the environment. HEPA filters used in the nuclear industry should therefore be manufactured and operated under strict quality control. There are three levels of testing HEPA filters: i) testing of the filter media; ii) testing of the assembled filter including filter media and filter housing; and iii) on site testing of the complete filter installation before putting into operation and later for the purpose of periodic control. A co-ordinated research programme on particulate filter testing methods was taken up by the Agency and contracts were awarded to the Member Countries, Belgium, German Democratic Republic, India and Hungary. The investigations carried out by the participants of the present co-ordinated research programme include the results of the nowadays most frequently used HEPA filter testing methods both for filter medium test, rig test and in-situ test purposes. Most of the experiments were carried out at ambient temperature and humidity, but indications were given to extend the investigations to elevated temperature and humidity in the future for the purpose of testing the performance of HEPA filter under severe conditions. A major conclusion of the co-ordinated research programme was that it was not possible to recommend one method as a reference method for in situ testing of high efficiency particulate air filters. Most of the present conventional methods are adequate for current requirements. The reasons why no method is to be recommended were multiple, ranging from economical aspects, through incompatibility of materials to national regulations

  16. Air Quality Criteria for Particulate Matter.

    Science.gov (United States)

    National Air Pollution Control Administration (DHEW), Washington, DC.

    To assist states in developing air quality standards, this book offers a review of literature related to atmospheric particulates and the development of criteria for air quality. It not only summarizes the current scientific knowledge of particulate air pollution, but points up the major deficiencies in that knowledge and the need for further…

  17. Particulate carbohydrates in the Bay of Bengal

    Digital Repository Service at National Institute of Oceanography (India)

    Bhosle, N.B.; Nandakumar, K.; Venkat, K.

    Particulate matter collected from 77 water samples over a 3000 m water column was analyzed for particulate carbohydrates (PCHO). PCHO in the surface waters ranged from 43 to 143 mu g.l-1, and below 250 m it was 16.PCHO showed large variations at all...

  18. On-Board Particulate Filter Failure Prevention and Failure Diagnostics Using Radio Frequency Sensing

    Energy Technology Data Exchange (ETDEWEB)

    Sappok, Alex [Filter Sensing Technologies; Ragaller, Paul [Filter Sensing Technologies; Herman, Andrew [CTS Corporation; Bromberg, L. [Massachusetts Institute of Technology (MIT); Prikhodko, Vitaly Y [ORNL; Parks, II, James E [ORNL; Storey, John Morse [ORNL

    2017-01-01

    The increasing use of diesel and gasoline particulate filters requires advanced on-board diagnostics (OBD) to prevent and detect filter failures and malfunctions. Early detection of upstream (engine-out) malfunctions is paramount to preventing irreversible damage to downstream aftertreatment system components. Such early detection can mitigate the failure of the particulate filter resulting in the escape of emissions exceeding permissible limits and extend the component life. However, despite best efforts at early detection and filter failure prevention, the OBD system must also be able to detect filter failures when they occur. In this study, radio frequency (RF) sensors were used to directly monitor the particulate filter state of health for both gasoline particulate filter (GPF) and diesel particulate filter (DPF) applications. The testing included controlled engine dynamometer evaluations, which characterized soot slip from various filter failure modes, as well as on-road fleet vehicle tests. The results show a high sensitivity to detect conditions resulting in soot leakage from the particulate filter, as well as potential for direct detection of structural failures including internal cracks and melted regions within the filter media itself. Furthermore, the measurements demonstrate, for the first time, the capability to employ a direct and continuous monitor of particulate filter diagnostics to both prevent and detect potential failure conditions in the field.

  19. Particulate filtration in nuclear facilities

    International Nuclear Information System (INIS)

    1991-01-01

    The removal of particulate radioactive material from exhaust air or gases is an essential feature of virtually all nuclear facilities. Recent IAEA publications have covered the broad designs of off-gas and air cleaning systems for the range of nuclear power plants and other facilities. This report is a complementary guidebook that examines in detail the latest developments in the design, operation, maintenance and testing of fibrous air filters. The original draft of the report was prepared by three consultants, M.W. First, of the School of Public Health, Harvard University, United States of America, K.S. Robinson, from the UKAEA Harwell Laboratory, United Kingdom, and H.G. Dillmann, of the Kernforschungzentrum, Karlsruhe, Germany. The Technical Committee Meeting (TCM), at which the report was reviewed and much additional information contributed, was attended by 11 experts and was held in Vienna, from 30 May to 3 June 1988. 64 refs, 41 figs, 10 tabs

  20. Tile Effect of P reconsolidation on the Thermal Conductivity of Particulate Beds

    International Nuclear Information System (INIS)

    Weidenfeld, G.

    2001-09-01

    The thermal conductivity of particulate beds is an important property for many industrial handling processes as well as storage of particulate materials. This property can be affected by a few conditions, such as, temperature and external axial pressure. In the first part of this work, a background for the thermal conductivity of particulate bed is given. This includes a review of experimental and theoretical studies on the thermal conductivity of particulate beds. It is also a reviewed parameters that influence the thermal conductivity of particulate beds, such as, temperature. This study presents a new experimental apparatus that enables to measure the thermal conductivity in steady-state while the particulate bed is under axial consolidation stresses. The experimental apparatus was analyzed and characterized experimentally and by numerical simulations. An analytical model, that predicts the thermal conductivity of particulate beds under axial consolidation stress was developed. The model results were compared to the experimental results for 0.5 and 1 mm steel spheres and showed a good agreement. The experimental results showed a significant effect of the compression state on the bed and its pre-consolidation for 0.5 and 1 mm steel spheres. The effect of the compression state on the bed and its pre-consolidation was even more significant for limestone powder

  1. Evaluation of particulate filtration efficiency of retrofit particulate filters for light duty vehicles

    International Nuclear Information System (INIS)

    Van Asch, R.; Verbeek, R.

    2009-10-01

    In the light of the currently running subsidy programme for particulate filters in the Netherlands, the Dutch ministry of spatial planning and environment (VROM) asked TNO to execute a desk study to evaluate the particulates filtration efficiency of retrofit particulate filters for light duty vehicles (passenger cars and vans). The typical retrofit particulate filters for light duty vehicles are also called 'open' or 'half-open' filters, because a part of the exhaust gas can pass through the particulate filter unfiltered. From design point they are very different from the majority of the factory installed particulate filters, which are also called wall-flow or 'closed' particulate filters. Due to these differences there is a large difference in filtration efficiency. Whereas the 'dosed' particulate filters show a filtration efficiency of larger than 90%, the filtration efficiency of 'open' particulate filters is generally lower (type approval minimum 30%), and strongly dependent on the conditions of use. The objective of the current project was to assess the average filtration efficiency of retrofit (open) particulate fillters on light duty vehicles in real world day to day driving, based on available literature data. Also, the reasons of a possible deviation with the type approval test results (minimum filtration efficiency of 30%) was investigated.

  2. The UK market for dust and particulate removal equipment

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-08-01

    The report has a market overview of dust and particulate removal equipment, 1995-1999 and has specific market reports, by value, of fabric, ceramic and sintered filters, electrostatic precipitators, wet scrubbers (venturi, plate and others) and cyclones. It gives environmental expenditure by UK industry and discusses factors affecting supply, demand and success in the market. An overview is given of the industry structure and profiles are presented of 15 companies. Lists of contracts, trade associations and relevant journals are included. 33 tabs.

  3. Particulate contamination spectrometer. Volume 1: Technical report

    Science.gov (United States)

    Schmitt, R. J.; Boyd, B. A.; Linford, R. M. F.

    1975-01-01

    A laser particulate spectrometer (LPS) system was developed to measure the size and speed distributions of particulate (dusts, aerosols, ice particles, etc.) contaminants. Detection of the particulates was achieved by means of light scattering and extinction effects using a single laser beam to cover a size range of 0.8 to 275 microns diameter and a speed range of 0.2 to 20 meter/second. The LPS system was designed to operate in the high vacuum environment of a space simulation chamber with cold shroud temperatures ranging from 77 to 300 K.

  4. Removal of particulates from nuclear offgas

    International Nuclear Information System (INIS)

    Burchsted, C.A.

    1976-01-01

    Particulate removal from nuclear offgases can be broken down into three parts: pretreatment, prefiltration, and absolute filtration. Pretreatment, using conventional air cleaning devices in most cases, is sometimes required to temper the gases and remove heavy concentrations of particulate matter. Prefiltration, if required, serves primarily to protect the final filter stages from heavy dust loadings in order to extend their life. HEPA filters are the most commonly used ''absolute'' filtration devices and are always required for removal of submicrometer particulates that cannot be removed effectively by other devices

  5. Modelling airborne dispersion of coarse particulate material

    International Nuclear Information System (INIS)

    Apsley, D.D.

    1989-03-01

    Methods of modelling the airborne dispersion and deposition of coarse particulates are presented, with the emphasis on the heavy particles identified as possible constituents of releases from damaged AGR fuel. The first part of this report establishes the physical characteristics of the irradiated particulate in airborne emissions from AGR stations. The second part is less specific and describes procedures for extending current dispersion/deposition models to incorporate a coarse particulate component: the adjustment to plume spread parameters, dispersion from elevated sources and dispersion in conjunction with building effects and plume rise. (author)

  6. Particulate emissions from diesel engines: correlation between engine technology and emissions.

    Science.gov (United States)

    Fiebig, Michael; Wiartalla, Andreas; Holderbaum, Bastian; Kiesow, Sebastian

    2014-03-07

    In the last 30 years, diesel engines have made rapid progress to increased efficiency, environmental protection and comfort for both light- and heavy-duty applications. The technical developments include all issues from fuel to combustion process to exhaust gas aftertreatment. This paper provides a comprehensive summary of the available literature regarding technical developments and their impact on the reduction of pollutant emission. This includes emission legislation, fuel quality, diesel engine- and exhaust gas aftertreatment technologies, as well as particulate composition, with a focus on the mass-related particulate emission of on-road vehicle applications. Diesel engine technologies representative of real-world on-road applications will be highlighted.Internal engine modifications now make it possible to minimize particulate and nitrogen oxide emissions with nearly no reduction in power. Among these modifications are cooled exhaust gas recirculation, optimized injections systems, adapted charging systems and optimized combustion processes with high turbulence. With introduction and optimization of exhaust gas aftertreatment systems, such as the diesel oxidation catalyst and the diesel particulate trap, as well as NOx-reduction systems, pollutant emissions have been significantly decreased. Today, sulfur poisoning of diesel oxidation catalysts is no longer considered a problem due to the low-sulfur fuel used in Europe. In the future, there will be an increased use of bio-fuels, which generally have a positive impact on the particulate emissions and do not increase the particle number emissions.Since the introduction of the EU emissions legislation, all emission limits have been reduced by over 90%. Further steps can be expected in the future. Retrospectively, the particulate emissions of modern diesel engines with respect to quality and quantity cannot be compared with those of older engines. Internal engine modifications lead to a clear reduction of the

  7. Measurement and analysis of ambient atmospheric particulate matter in urban and remote environments

    Science.gov (United States)

    Hagler, Gayle S. W.

    Atmospheric particulate matter pollution is a challenging environmental concern in both urban and remote locations worldwide. It is intrinsically difficult to control, given numerous anthropogenic and natural sources (e.g. fossil fuel combustion, biomass burning, dust, and seaspray) and atmospheric transport up to thousands of kilometers after production. In urban regions, fine particulate matter (particles with diameters under 2.5 mum) is of special concern for its ability to penetrate the human respiratory system and threaten cardiopulmonary health. A second major impact area is climate, with particulate matter altering Earth's radiative balance through scattering and absorbing solar radiation, modifying cloud properties, and reducing surface reflectivity after deposition in snow-covered regions. While atmospheric particulate matter has been generally well-characterized in populated areas of developed countries, particulate pollution in developing nations and remote regions is relatively unexplored. This thesis characterizes atmospheric particulate matter in locations that represent the extreme ends of the spectrum in terms of air pollution-the rapidly-developing and heavily populated Pearl River Delta Region of China, the pristine and climate-sensitive Greenland Ice Sheet, and a remote site in the Colorado Rocky Mountains. In China, fine particles were studied through a year-long field campaign at seven sites surrounding the Pearl River Delta. Fine particulate matter was analyzed for chemical composition, regional variation, and meteorological impacts. On the Greenland Ice Sheet and in the Colorado Rocky Mountains, the carbonaceous fraction (organic and elemental carbon) of particulate matter was studied in the atmosphere and snow pack. Analyses included quantifying particulate chemical and optical properties, assessing atmospheric transport, and evaluating post-depositional processing of carbonaceous species in snow.

  8. Spacecraft Cabin Particulate Monitor, Phase II

    Data.gov (United States)

    National Aeronautics and Space Administration — We have built and tested an optical extinction monitor for the detection of spacecraft cabin particulates. This sensor sensitive to particle sizes ranging from a few...

  9. Johns Hopkins Particulate Matter Research Center

    Data.gov (United States)

    Federal Laboratory Consortium — The Johns Hopkins Particulate Matter Research Center will map health risks of PM across the US based on analyses of national databases on air pollution, mortality,...

  10. Spacecraft Cabin Particulate Monitor, Phase I

    Data.gov (United States)

    National Aeronautics and Space Administration — We propose to design, build and test an optical extinction monitor for the detection of spacecraft cabin particulates. This monitor will be sensitive to particle...

  11. Allegheny County Particulate Matter 2.5

    Data.gov (United States)

    Allegheny County / City of Pittsburgh / Western PA Regional Data Center — The U.S. Environmental Protection Agency provides information on the particulate matter concentration for Allegheny County that have a diameter greater or equal to...

  12. Analysis of airborne particulate matter

    International Nuclear Information System (INIS)

    Iwatsuki, Masaaki

    2002-01-01

    An airborne particulate matter (APM) consists of many kinds of solid and liquid particles in air. APM analysis methods and the application examples are explained on the basis of paper published after 1998. Books and general remarks, sampling and the measurement of concentration and particle distribution, elemental analysis methods and the present state of analysis of species are introduced. Tapered Element Oscillating Microbalance (TEOM) method can collect continuously the integrating mass, but indicates lower concentration. Cu, Ni, Zn, Co, Fe(2), Mn, Cd, Fe(3) and Pb, the water-soluble elements, are determined by ion-chromatography after ultrasonic extraction of the aqueous solution. The detection limit of them is from 10 to 15 ppb (30 ppb Cd and 60 ppb Pb). The elemental carbon (EC) and organic carbon (OC) are separated by the thermal mass measurement-differential scanning calorimeter by means of keeping at 430degC for 60 min. 11 research organizations compared the results of TC (Total Carbon) and EC by NIOSH method 5040 and the thermal method and obtained agreement of TC. ICP-MS has been developed in order to determine correctly and quickly the trace elements. The determination methods for distinction of chemical forms in the environment were developed. GC/MS, LC/MS and related technologies for determination of organic substances are advanced. Online real-time analysis of APN, an ideal method, is examined. (S.Y.)

  13. Contacting particulate solids with liquids

    International Nuclear Information System (INIS)

    Hodgson, T.D.

    1980-01-01

    Apparatus is described for contacting particulate solids with a fluid. The particular applications described are 1) an acid dissolver for dissolving plutonium from plutonium contaminated ash produced by the incineration of waste such as rubber gloves, tissue paper etc. and 2) apparatus for dissolving gel spheres of nuclear fuel material. The liquid, e.g. acid for use in a leaching process flows through a vertical conduit and past a series of baffles spaced along the axis of the conduit. Each baffle defines a mixing chamber and provides a small gap around its perimeter between the baffle and the wall of the conduit. The baffles are provided with sloping top surfaces for preventing solid particles from settling on the baffles and sloping undersurfaces to improve mixing of the liquid and the solid particles. The liquid flows upwards in the conduit but solid particles may be fed from the top or from the bottom of the conduit to mix with the liquid. Gas may be introduced to promote improved flow conditions. (U.K.)

  14. Particulate hot gas stream cleanup technical issues

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-09-01

    This is the eleventh in a series of quarterly reports describing the activities performed under Contract No. DE-AC21-94MC31160. Analyses of Hot Gas Stream Cleanup (HGCU) ashes and descriptions of filter performance address aspects of filter operation that are apparently linked to the characteristics of the collected ash or the performance of the ceramic bed filter elements. Task 1 is designed to generate a data base of the key characteristics of ashes collected from operating advanced particle filters (APFS) and to relate these ash properties to the operation and performance of these filters. Task 2 concerns testing and failure analysis of ceramic filter elements. Under Task 1 during the past quarter, analyses were completed on samples obtained during a site visit to the Power Systems Development Facility (PSDF). Analyses are in progress on ash samples from the Advanced Particulate Filter (APF) at the Pressurized Fluidized-Bed Combustor (PFBC) that was in operation at Tidd and ash samples from the Pressurized Circulating Fluid Bed (PCFB) system located at Karhula, Finland. An additional analysis was performed on a particulate sample from the Transport Reactor Demonstration Unit (TRDU) located at the University of North Dakota Energy and Environmental Research Center. A manuscript and poster were prepared for presentation at the Advanced Coal-Based Power and Environmental Systems `97 Conference scheduled for July 22 - 24, 1997. A summary of recent project work covering the mechanisms responsible for ash deposit consolidation and ash bridging in APF`s collecting PFB ash was prepared and presented at FETC-MGN in early July. The material presented at that meeting is included in the manuscript prepared for the Contractor`s Conference and also in this report. Task 2 work during the past quarter included mechanical testing and microstructural examination of Schumacher FT20 and Pall 326 as- manufactured, after 540 hr in service at Karhula, and after 1166 hr in service at

  15. Particulate matter and health - from air to human lungs

    International Nuclear Information System (INIS)

    Piniero, T.; Cerqueira Alves, L.; Reis, M.

    1998-01-01

    The aim of this project is to search for respiratory system particular aggressors to which workers are submitted in their labouring activity. The work plan under the current IAEA contract comprise a prospective study to identify particulate matter deposited in the human respiratory ducts and lung tissue and workers respiratory health status survey at a steel plant, Siderurgia Nacional (SN). So far, the selection of areas of interest at SN, workers exposed, airborne particulate monitoring sites according to the periodicity of labouring cycles, and the beginning of workers medical survey have been achieved and/or initiated. The SN selected area, where steel is processed and steel casting is achieved, involve approximately 80 workers, most of them working at that location for more than 15 years. Blood elemental content data determined by PIXE and INAA and a preliminary health status evaluation from 32 of the 80 workers included in this survey are presented and discussed. (author)

  16. Rechargeable particulate filter for radioactive contaminated gas streams

    International Nuclear Information System (INIS)

    Bonn, J.W.

    1976-01-01

    A system is disclosed which includes a closed housing having a plurality of rectangularly configured beds with perforated sidewalls longitudinally disposed in housing in laterally spaced disposition with each other. Alternate spaces at inlet end are closed and alternate spaces opposite the open ends are closed at exit end whereby contaminated gas is laterally squeezed through the beds filled with particulate adsorbent. The lower portions of the beds funnel into longitudinally extending discharge chutes enclosed within respective wells, the lower edges of the chutes rising at a constant angle above the well floor. An evacuation system coupled to the wells suctions the pile of particulate from the most remote portion of the chutes first. 3 claims, 7 drawing figures

  17. Particulate Emission Abatement for Krakow Boilerhouses

    International Nuclear Information System (INIS)

    Hucko, R.E.

    1997-01-01

    units in the U.S. and Europe. Ecolnstal, a leading supplier of environmental equipment in Poland, is licensed to sell the Core Separator, and will support LSR as a subcontractor. The Polish Foundation for Energy Efficiency (FEWE), located in Katowice, is a consulting organization with extensive expertise in the Polish economy and natural environment. FEWE is also be a subcontractor to LSR. This project will be divided into three major phases. Phase 1 is called 'Infrastructure Studies' and includes business planning, and site-selection of a full-scale Core Separator Demonstration Unit. Phase 2, called 'Commercial Development,' includes the first Demonstration Unit in a local boilerhouse, followed by several Core Separator installations collecting flyash from different Polish coals. Also, a manufacturing facility is to be equipped to accommodate the projected sales volume. If the goals of this project are met and the Core Separator can be successfully marketed, there is a potential to significantly reduce particulate emissions in Krakow

  18. Particulate Emission Abatement for Krakow Boilerhouses

    International Nuclear Information System (INIS)

    Hucko, R.E.

    1997-01-01

    units in the U.S. and Europe. Ecolnstal, a leading supplier of environmental equipment in Poland, is licensed to sell the Core Separator, and will support LSR as a subcontractor. The Polish Foundation for Energy Efficiency (FEWE), located in Katowice, is a consulting organization with extensive expertise in the Polish economy and natural environment. FEWE is also a subcontractor to LSR. This project will be divided into three major phases. Phase 1 is called 'Infrastructure Studies' and will includes business planning, and site-selection of a full- scale Core Separator Demonstration Unit. Phase 2, called 'Commercial Development,' includes the first Demonstration Unit in a local boilerhouse, followed by several Core Separator installations collecting flyash from different Polish coals. Also, a manufacturing facility is to be equipped to accommodate the projected sales volume. If the goals of this project are met and the Core Separator can be successfully marketed, there is a potential to significantly reduce particulate emissions in Krakow

  19. Homogenized thermal conduction model for particulate foods

    OpenAIRE

    Chinesta , Francisco; Torres , Rafael; Ramón , Antonio; Rodrigo , Mari Carmen; Rodrigo , Miguel

    2002-01-01

    International audience; This paper deals with the definition of an equivalent thermal conductivity for particulate foods. An homogenized thermal model is used to asses the effect of particulate spatial distribution and differences in thermal conductivities. We prove that the spatial average of the conductivity can be used in an homogenized heat transfer model if the conductivity differences among the food components are not very large, usually the highest conductivity ratio between the foods ...

  20. Complexity analysis in particulate matter measurements

    Directory of Open Access Journals (Sweden)

    Luciano Telesca

    2011-09-01

    Full Text Available We investigated the complex temporal fluctuations of particulate matter data recorded in London area by using the Fisher-Shannon (FS information plane. In the FS plane the PM10 and PM2.5 data are aggregated in two different clusters, characterized by different degrees of order and organization. This results could be related to different sources of the particulate matter.

  1. Assessment of inhalation dose sensitivity by physicochemical properties of airborne particulates containing naturally occurring radioactive materials

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Si Young; Choi, Cheol Kyu; Kim, Yong Geon; Choi, Won Chul; Kim, Kwang Pyo [Kyung Hee University, Seoul (Korea, Republic of)

    2015-12-15

    Facilities processing raw materials containing naturally occurring radioactive materials (NORM) may give rise to enhanced radiation dose to workers due to chronic inhalation of airborne particulates. Internal radiation dose due to particulate inhalation varies depending on particulate properties, including size, shape, density, and absorption type. The objective of the present study was to assess inhalation dose sensitivity to physicochemical properties of airborne particulates. Committed effective doses to workers resulting from inhalation of airborne particulates were calculated based on International Commission on Radiological Protection 66 human respiratory tract model. Inhalation dose generally increased with decreasing particulate size. Committed effective doses due to inhalation of 0.01μm sized particulates were higher than doses due to 100μm sized particulates by factors of about 100 and 50 for {sup 238}U and {sup 230}Th, respectively. Inhalation dose increased with decreasing shape factor. Shape factors of 1 and 2 resulted in dose difference by about 18 %. Inhalation dose increased with particulate mass density. Particulate mass densities of 11 g·cm{sup -3} and 0.7 g·cm{sup -3} resulted in dose difference by about 60 %. For {sup 238}U, inhalation doses were higher for absorption type of S, M, and F in that sequence. Committed effective dose for absorption type S of {sup 238}U was about 9 times higher than dose for absorption F. For {sup 230}Th, inhalation doses were higher for absorption type of F, M, and S in that sequence. Committed effective dose for absorption type F of {sup 230}Th was about 16 times higher than dose for absorption S. Consequently, use of default values for particulate properties without consideration of site specific physiochemical properties may potentially skew radiation dose estimates to unrealistic values up to 1-2 orders of magnitude. For this reason, it is highly recommended to consider site specific working materials and

  2. PARTICULATE EMISSION ABATEMENT FOR KRAKOW BOILERHOUSES

    Energy Technology Data Exchange (ETDEWEB)

    Bruce H. Easom; Leo A, Smolensky; S. Ronald Wysk; Jan Surowka; Miroslaw Litke; Jacek Ginter

    1998-09-30

    A U.S./Polish Bilateral Steering Committee (BSC) and the Department of Energy (DOE) selected LSR Technologies, Inc. as a contractor to participate in the Krakow Clean Fuels and Energy Efficiency Program. The objective of this program was the formation of business ventures between U.S. and Polish firms to provide equipment and services to reduce air emissions in the city of Krakow. A cooperative agreement was entered into by DOE and LSR to begin work in April 1994 involving implementation of particulate control technology called a Core Separator{trademark} for coal-fueled boilerhouses in the city. The major work tasks included: (1) conducting a market analysis, (2) completion of a formal marketing plan, (3) obtaining patent protection within Poland, (4) selecting a manufacturing partner, and (5) completing a demonstration unit and commercial installations. In addition to work performed by LSR Technologies, key contributors to this project were (1) the Polish Foundation for Energy Efficiency (FEWE), a non-profit consulting organization specializing in energy and environmental-related technologies, and (2) EcoInstal, a privately held Polish company serving the air pollution control market. As the project concluded in late 1998, five (5) Core Separator{trademark} installations had been implemented in the city of Krakow, while about 40 others were completed in other regions of Poland.

  3. Gene-particulate matter-health interactions

    International Nuclear Information System (INIS)

    Kleeberger, Steven R.; Ohtsuka, Yoshinori

    2005-01-01

    Inter-individual variation in human responses to air pollutants suggests that some subpopulations are at increased risk to the detrimental effects of pollutant exposure. Extrinsic factors such as previous exposure and nutritional status may influence individual susceptibility. Intrinsic (host) factors that determine susceptibility include age, gender, and pre-existing disease (e.g., asthma), and it is becoming clear that genetic background also contributes to individual susceptibility. Environmental exposures to particulates and genetic factors associated with disease risk likely interact in a complex fashion that varies from one population and one individual to another. The relationships between genetic background and disease risk and severity are often evaluated through traditional family-based linkage studies and positional cloning techniques. However, case-control studies based on association of disease or disease subphenotypes with candidate genes have advantages over family pedigree studies for complex disease phenotypes. This is based in part on continued development of quantitative analysis and the discovery and availability of simple sequence repeats and single nucleotide polymorphisms. Linkage analyses with genetically standardized animal models also provide a useful tool to identify genetic determinants of responses to environmental pollutants. These approaches have identified significant susceptibility quantitative trait loci on mouse chromosomes 1, 6, 11, and 17. Physical mapping and comparative mapping between human and mouse genomes will yield candidate susceptibility genes that may be tested by association studies in human subjects. Human studies and mouse modeling will provide important insight to understanding genetic factors that contribute to differential susceptibility to air pollutants

  4. Transport phenomena and drying of solids and particulate materials

    CERN Document Server

    Lima, AG

    2014-01-01

    The purpose of this book, Transport Phenomena and Drying of Solids and Particulate Materials, is to provide a collection of recent contributions in the field of heat and mass transfer, transport phenomena, drying and wetting of solids and particulate materials. The main benefit of the book is that it discusses some of the most important topics related to the heat and mass transfer in solids and particulate materials. It includes a set of new developments in the field of basic and applied research work on the physical and chemical aspects of heat and mass transfer phenomena, drying and wetting processes, namely, innovations and trends in drying science and technology, drying mechanism and theory, equipment, advanced modelling, complex simulation and experimentation. At the same time, these topics will be going to the encounter of a variety of scientific and engineering disciplines. The book is divided in several chapters that intend to be a resume of the current state of knowledge for benefit of professional c...

  5. Small-angle light scattering by airborne particulates: Environnement S.A. continuous particulate monitor

    International Nuclear Information System (INIS)

    Renard, Jean-Baptiste; Gaubicher, Bertrand; Thaury, Claire; Mineau, Jean-Luc

    2010-01-01

    Airborne particulate matter may have an effect on human health. It is therefore necessary to determine and control in real time the evolution of the concentration and mass of particulates in the ambient air. These parameters can be obtained using optical methods. We propose here a new instrument, 'CPM' (continuous particulate monitor), for the measurement of light scattered by ambient particulates at small angles. This geometry allows simultaneous and separate detections of PM10, PM2.5 and PM1 fractions of airborne particulate matter, with no influence of their chemical nature and without using theoretical calculations. The ambient air is collected through a standard sampling head (PM10 inlet according to EN 12341, PM2.5 inlet according to EN 14907; or PM1, TSP inlets, standard US EPA inlets). The analysis of the first measurements demonstrates that this new instrument can detect, for each of the seven defined size ranges, real-time variations of particulate content in the ambient air. The measured concentrations (expressed in number per liter) can be converted into total mass concentrations (expressed in micrograms per cubic meter) of all fractions of airborne particulate matters sampled by the system. Periodic comparison with a beta-attenuation mass monitor (MP101M Beta Gauge Analyzer from Environnement S.A. company) allows the calculation of a calibration factor as a function of the mean particulate density that is used for this conversion. It is then possible to provide real-time relative variations of aerosol mass concentration

  6. Temporal and spatial variations in particulate matter, particulate organic carbon and attenuation coefficient in Cochin Backwaters

    Digital Repository Service at National Institute of Oceanography (India)

    Devi, K.S.

    Nine stations over a stretch of 21 km of Periyar river estuary were sampled during January to December 1981. Particulate matter varied from 3-253 mg.1 super(1) at the surface and 24.8-257mg.1 super(1) at the bottom. Particulate organic carbon ranged...

  7. On the Impact of Particulate Matter Distribution on Pressure Drop of Wall-Flow Particulate Filters

    Directory of Open Access Journals (Sweden)

    Vicente Bermúdez

    2017-03-01

    Full Text Available Wall-flow particulate filters are a required exhaust aftertreatment system to abate particulate matter emissions and meet current and incoming regulations applying worldwide to new generations of diesel and gasoline internal combustion engines. Despite the high filtration efficiency covering the whole range of emitted particle sizes, the porous substrate constitutes a flow restriction especially relevant as particulate matter, both soot and ash, is collected. The dependence of the resulting pressure drop, and hence the fuel consumption penalty, on the particulate matter distribution along the inlet channels is discussed in this paper taking as reference experimental data obtained in water injection tests before the particulate filter. This technique is demonstrated to reduce the particulate filter pressure drop without negative effects on filtration performance. In order to justify these experimental data, the characteristics of the particulate layer are diagnosed applying modeling techniques. Different soot mass distributions along the inlet channels are analyzed combined with porosity change to assess the new properties after water injection. Their influence on the subsequent soot loading process and regeneration is assessed. The results evidence the main mechanisms of the water injection at the filter inlet to reduce pressure drop and boost the interest for control strategies able to force the re-entrainment of most of the particulate matter towards the inlet channels’ end.

  8. Mercury Control With The Advanced Hybrid Particulate Collector

    International Nuclear Information System (INIS)

    Stanley J. Miller; Ye Zhuang; Jay C. Almlie

    2004-01-01

    This project was awarded under U.S. Department of Energy (DOE) National Energy Technology Laboratory Program Solicitation DE-FC26-01NT41184 and specifically addresses Technical Topical Area 4 - Testing Novel and Less Mature Control Technologies on Actual Flue Gas at the Pilot Scale. The project team included the Energy and Environmental Research Center as the main contractor; W.L. Gore and Associates, Inc., as a technical and financial partner; and the Big Stone Plant operated by Otter Tail Power Company, host for the field-testing portion of the research. Since 1995, DOE has supported development of a new concept in particulate control called the advanced hybrid particulate collector (AHPC). The AHPC has been licensed to W.L. Gore and Associates, Inc., and is marketed as the Advanced Hybrid(trademark) filter by Gore. The AHPC combines the best features of electrostatic precipitators (ESPs) and baghouses in a unique configuration, providing major synergism between the two collection methods, both in the particulate collection step and in the transfer of dust to the hopper. The AHPC provides ultrahigh collection efficiency, overcoming the problem of excessive fine-particle emissions with conventional ESPs, and it solves the problem of reentrainment and re-collection of dust in conventional baghouses. The AHPC also appears to have unique advantages for mercury control over baghouses or ESPs as an excellent gas--solid contactor. The objective of the original five-task project was to demonstrate 90% total mercury control in the AHPC at a lower cost than current mercury control estimates. The approach included benchscale batch tests, larger-scale pilot testing with real flue gas on a coal-fired combustion system, and field demonstration at the 2.5-MW scale at a utility power plant to prove scale-up and demonstrate longer-term mercury control. The scope of work was modified to include an additional sixth task, initiated in April 2003. The objective of this task was to

  9. Advanced Hybrid Particulate Collector Project Management Plan

    Energy Technology Data Exchange (ETDEWEB)

    Miller, S.J.

    1995-11-01

    As the consumption of energy increases, its impact on ambient air quality has become a significant concern. Recent studies indicate that fine particles from coal combustion cause health problems as well as atmospheric visibility impairment. These problems are further compounded by the concentration of hazardous trace elements such as mercury, cadmium, selenium, and arsenic in fine particles. Therefore, a current need exists to develop superior, but economical, methods to control emissions of fine particles. Since most of the toxic metals present in coal will be in particulate form, a high level of fine- particle collection appears to be the best method of overall air toxics control. However, over 50% of mercury and a portion of selenium emissions are in vapor form and cannot be collected in particulate control devices. Therefore, this project will focus on developing technology not only to provide ultrahigh collection efficiency of particulate air toxic emissions, but also to capture vapor- phase trace metals such as mercury and selenium. Currently, the primary state-of-the-art technologies for particulate control are fabric filters (baghouses) and electrostatic precipitators (ESPs). However, they both have limitations that prevent them from achieving ultrahigh collection of fine particulate matter and vapor-phase trace metals. The objective of this project is to develop a highly reliable advanced hybrid particulate collector (AHPC) that can provide > 99.99 % particulate collection efficiency for all particle sizes between 0.01 and 50 14m, is applicable for use with all U.S. coals, and is cost-0443competitive with existing technologies. Phase I of the project is organized into three tasks: Task I - Project Management, Reporting, and Subcontract Consulting Task 2 - Modeling, Design, and Construction of 200-acfm AHPC Model Task 3 - Experimental Testing and Subcontract Consulting

  10. MERCURY CONTROL WITH THE ADVANCED HYBRID PARTICULATE COLLECTOR

    International Nuclear Information System (INIS)

    Ye Zhuang; Stanley J. Miller; Grant E. Dunham; Michelle R. Olderbak

    2002-01-01

    Since 1995, DOE has supported development of a new concept in particulate control, called the advanced hybrid particulate collector (AHPC). The AHPC combines the best features of electrostatic precipitators (ESPs) and baghouses in a unique configuration, providing major synergism between the two collection methods, both in the particulate collection step and in the transfer of dust to the hopper. The AHPC provides ultrahigh collection efficiency, overcoming the problem of excessive fine-particle emission with conventional ESPs, and it solves the problem of reentrainment and re-collection of dust in conventional baghouses. The AHPC appears to have unique advantages for mercury control over baghouses or ESPs as an excellent gas-solid contactor. The objective of the three-task project is to demonstrate 90% total mercury control in the AHPC at a lower cost than current mercury control estimates. The approach includes bench-scale batch testing that ties the new work to previous results and links results with larger-scale pilot testing with real flue gas on a coal-fired combustion system, pilot-scale testing on a coal-fired combustion system with both a pulse-jet baghouse and an AHPC to prove or disprove the research hypotheses, and field demonstration pilot-scale testing at a utility power plant to prove scaleup and demonstrate longer-term mercury control. This project, if successful, will demonstrate at the pilot-scale level a technology that would provide a cost-effective technique to accomplish control of mercury emissions and, at the same time, greatly enhance fine particulate collection efficiency. The technology can be used to retrofit systems currently employing inefficient ESP technology as well as for new construction, thereby providing a solution to a large segment of the U.S. utility industry as well as other industries requiring mercury control

  11. Source apportionment of airborne particulates through receptor modeling: Indian scenario

    Science.gov (United States)

    Banerjee, Tirthankar; Murari, Vishnu; Kumar, Manish; Raju, M. P.

    2015-10-01

    issues and specific recommendations have been included which need to be considered for a scientific apportionment of particulate sources in different geographical regions of India.

  12. Preliminary studies of airborne particulate emmisions from the Ampellum S.A. copper smelter, Zlatna, Romania

    Directory of Open Access Journals (Sweden)

    Ben J. Williamson

    2003-04-01

    Full Text Available Preliminary studies have been carried on the characterization of particulate emissions from the Ampellum S.A. copper smelter in the town of Zlatna, Romania. The particulates studied were collected on polycarbonate filters using air pump apparatus and on the surfaces of lichens. Mass of total suspended particulates (TSP and PM10 varied from 19 to 230 μg/m3 and 3 to 146 μg/m3, respectively (PM10/TSP = 0.14 to 1.0, depending on wind direction and proximity to the smelter. Particulates on collection filters from a site directly downwind from the smelter have a mean equivalent spherical diameter (ESD of 0.94 μm (s.d. 1.1 and are dominantly made up of material with the composition of anglesite (PbSO4. The remainder of the material is a heterogeneous mixture of silicates and Fe-, Pb- and Cu-bearing phases. Particulates > 5 μm ESD are rare on the TSP filters, mainly due to the restricted sampling durations possible with the equipment used (<3 hours. Particulates have therefore been studied in the lichen Acarospora smaragdula, which was growing on posts downwind from the smelter and which was found to contain high levels and a broader range of particulates compared with the filters (<5 to 100 μm in diameter. Larger particles include 20-30 μm diameter Fe-rich spherules, which occasionally have Pb- and S-rich encrustations on their surfaces. The nature and possible health effects of the particulates are discussed and recommendations made for future studies.

  13. Atmospheric particulate matter within the Sudbury footprint

    Energy Technology Data Exchange (ETDEWEB)

    Koski, P. [Laurentian Univ., Sudbury, ON (Canada); Spiers, G.A. [Laurentian Univ., Sudbury, ON (Canada). Centre for Environmental Monitoring

    2007-07-01

    In order to assess health and risks to ecosystems, measuring exposure to coarse, fine and ultrafine dust and their association with metals in the air is necessary. This paper presented the results of a study that investigated the concentration, particle size distribution and spatial dispersion of metals in total and fractioned airborne dust. The study involved collection of airborne dust samples at five different sites over a one year period in the Sudbury area, including one control site located downwind of the south-westerly most industrial emission source. The paper discussed the goals and objectives of the project which included analysis of total concentration of particulate matter (PM) within various size fractions; analysis of concentration of selected metals such as arsenic, zinc, copper, nickel, cobalt, iron, manganese, chromium and lead as well as the species of sulphur within those size fractions; delineation between particle chemistry of both short and long range transport origin; determining the effects of the different seasons on PM concentrations, and establish any seasonal/temperature trends that may occur. The paper also discussed the methodology for the study with reference to sampling sites, sampling equipment, sampling schedule, mass determination, and chemical analysis. X-ray Fluorescence (XRF) was used to determine the total metals concentration in airborne dust. The results of the study were also presented. It was concluded that PM analysis within the Sudbury footprint indicated that the finer fractions primarily contained the highest weight and metal concentration. In addition, sulphate seemed to be the only species of sulphur present in the different size fractions at each site. 22 refs., 4 tabs., 5 figs.

  14. Atmospheric particulate matter within the Sudbury footprint

    International Nuclear Information System (INIS)

    Koski, P.; Spiers, G.A.

    2007-01-01

    In order to assess health and risks to ecosystems, measuring exposure to coarse, fine and ultrafine dust and their association with metals in the air is necessary. This paper presented the results of a study that investigated the concentration, particle size distribution and spatial dispersion of metals in total and fractioned airborne dust. The study involved collection of airborne dust samples at five different sites over a one year period in the Sudbury area, including one control site located downwind of the south-westerly most industrial emission source. The paper discussed the goals and objectives of the project which included analysis of total concentration of particulate matter (PM) within various size fractions; analysis of concentration of selected metals such as arsenic, zinc, copper, nickel, cobalt, iron, manganese, chromium and lead as well as the species of sulphur within those size fractions; delineation between particle chemistry of both short and long range transport origin; determining the effects of the different seasons on PM concentrations, and establish any seasonal/temperature trends that may occur. The paper also discussed the methodology for the study with reference to sampling sites, sampling equipment, sampling schedule, mass determination, and chemical analysis. X-ray Fluorescence (XRF) was used to determine the total metals concentration in airborne dust. The results of the study were also presented. It was concluded that PM analysis within the Sudbury footprint indicated that the finer fractions primarily contained the highest weight and metal concentration. In addition, sulphate seemed to be the only species of sulphur present in the different size fractions at each site. 22 refs., 4 tabs., 5 figs

  15. Particulate Matter Emission Factors for Biomass Combustion

    Directory of Open Access Journals (Sweden)

    Simone Simões Amaral

    2016-10-01

    Full Text Available Emission factor is a relative measure and can be used to estimate emissions from multiple sources of air pollution. For this reason, data from literature on particulate matter emission factors from different types of biomass were evaluated in this paper. Initially, the main sources of particles were described, as well as relevant concepts associated with particle measurements. In addition, articles about particle emissions were classified and described in relation to the sampling environment (open or closed and type of burned biomass (agricultural, garden, forest, and dung. Based on this analysis, a set of emission factors was presented and discussed. Important observations were made about the main emission sources of particulate matter. Combustion of compacted biomass resulted in lower particulate emission factors. PM2.5 emissions were predominant in the burning of forest biomass. Emission factors were more elevated in laboratory burning, followed by burns in the field, residences and combustors.

  16. Differential electrocardiogram efffects in normal and hypertensive rats after inhalation exposure to transition metal rich particulate matter

    Science.gov (United States)

    Inhalation of particulate matter (PM) associated with air pollution causes adverse effects on cardiac function including heightened associations with ischemic heart disease, dysrhythmias, heart failure, and cardiac arrest. Some of these effects have been attributable to transitio...

  17. Polycyclic Aromatic Hydrocarbons in Fine Particulate Matter Emitted from Burning Kerosene, Liquid Petroleum Gas, and Wood Fuels in Household Cookstoves

    Science.gov (United States)

    This study measured polycyclic aromatic hydrocarbon (PAH) composition in particulate matter emissions from residential cookstoves. A variety of fuel and cookstove combinations were examined, including: (i) liquid petroleum gas (LPG), (ii) kerosene in a wick stove, (iii) wood (10%...

  18. Particulate hot gas stream cleanup technical issues

    Energy Technology Data Exchange (ETDEWEB)

    Pontius, D.H.; Snyder, T.R.

    1999-09-30

    The analyses of hot gas stream cleanup particulate samples and descriptions of filter performance studied under this contract were designed to address problems with filter operation that have been linked to characteristics of the collected particulate matter. One objective of this work was to generate an interactive, computerized data bank of the key physical and chemical characteristics of ash and char collected from operating advanced particle filters and to relate these characteristics to the operation and performance of these filters. The interactive data bank summarizes analyses of over 160 ash and char samples from fifteen pressurized fluidized-bed combustion and gasification facilities utilizing high-temperature, high pressure barrier filters.

  19. Gel nano-particulates against radioactivity

    International Nuclear Information System (INIS)

    Deroin, Ph.

    2004-01-01

    The Argonne research center (USA) has developed a 'super-gel' compound, a polymer close to those used in baby's diapers, which can reach a 90% efficiency in the radioactive decontamination of porous materials, like bricks or concrete. The contaminated materials are sprayed with a mixture of polymer gel and wetting agent with nano-particulates in suspension. Under the action of the wetting agent, radioactivity migrates from the pores to the gel and is trapped by the nano-particulates. The drying and recycling of the gel allows to reduce the volume of radioactive wastes. Short paper. (J.S.)

  20. Development of asthmatic inflammation in mice following early-life exposure to ambient environmental particulates and chronic allergen challenge

    Directory of Open Access Journals (Sweden)

    Cristan Herbert

    2013-03-01

    Childhood exposure to environmental particulates increases the risk of development of asthma. The underlying mechanisms might include oxidant injury to airway epithelial cells (AEC. We investigated the ability of ambient environmental particulates to contribute to sensitization via the airways, and thus to the pathogenesis of childhood asthma. To do so, we devised a novel model in which weanling BALB/c mice were exposed to both ambient particulate pollutants and ovalbumin for sensitization via the respiratory tract, followed by chronic inhalational challenge with a low mass concentration of the antigen. We also examined whether these particulates caused oxidant injury and activation of AEC in vitro. Furthermore, we assessed the potential benefit of minimizing oxidative stress to AEC through the period of sensitization and challenge by dietary intervention. We found that characteristic features of asthmatic inflammation developed only in animals that received particulates at the same time as respiratory sensitization, and were then chronically challenged with allergen. However, these animals did not develop airway hyper-responsiveness. Ambient particulates induced epithelial injury in vitro, with evidence of oxidative stress and production of both pro-inflammatory cytokines and Th2-promoting cytokines such as IL-33. Treatment of AEC with an antioxidant in vitro inhibited the pro-inflammatory cytokine response to these particulates. Ambient particulates also induced pro-inflammatory cytokine expression following administration to weanling mice. However, early-life dietary supplementation with antioxidants did not prevent the development of an asthmatic inflammatory response in animals that were exposed to particulates, sensitized and challenged. We conclude that injury to airway epithelium by ambient environmental particulates in early life is capable of promoting the development of an asthmatic inflammatory response in sensitized and antigen-challenged mice. These

  1. Polycyclic Aromatic Hydrocarbons in Fine Particulate Matter ...

    Science.gov (United States)

    This study measured polycyclic aromatic hydrocarbon (PAH) composition in particulate matter emissions from residential cookstoves. A variety of fuel and cookstove combinations were examined, including: (i) liquid petroleum gas (LPG), (ii) kerosene in a wick stove, (iii) wood (10% and 30% moisture content on a wet basis) in a forced-draft fan stove, and (iv) wood in a natural-draft rocket cookstove. LPG combustion had the highest thermal efficiency (~57%) and the lowest PAH emissions per unit fuel energy, resulting in the lowest PAH emissions per useful energy delivered (MJd). The average benzo[a]pyrene (B[a]P) emission factor for LPG was 0.842 µg/MJd; the emission rate was 0.043 µg/min. The highest PAH emissions were from wood burning in the natural-draft stove (209-700 µg B[a]P/MJd). PAH emissions from kerosene were significantly lower than those from the wood burning in the natural-draft cookstove, but higher than those from LPG. It is expected that in rural regions where LPG and kerosene are unavailable or unaffordable, the forced-draft fan stove may be an alternative because its emission factor (5.17-8.07 µg B[a]P/MJd) and emission rate (0.52-0.57 µg/min) are similar to kerosene (5.36 µg B[a]P/MJd and 0.45 µg/min). Compared with wood combustion emissions, LPG stoves emit less total PAH emissions and less fractions of high molecular weight PAHs. Relatively large variations in PAH emissions from LPG call for additional future tests to identify the major

  2. Diesel emission control: Catalytic filters for particulate removal

    Directory of Open Access Journals (Sweden)

    Debora Fino

    2007-01-01

    Full Text Available The European diesel engine industry represents a vital sector across the Continent, with more than 2 million direct work positions and a turnover of over 400 billion Euro. Diesel engines provide large paybacks to society since they are extensively used to transport goods, services and people. In recent years increasing attention has been paid to the emissions from diesel engines which, like gasoline engine emissions, include carbon monoxide (CO, hydrocarbons (HC and oxides of nitrogen (NOx. Diesel engines also produce significant levels of particulate matter (PM, which consists mostly of carbonaceous soot and a soluble organic fraction (SOF of hydrocarbons that have condensed on the soot.

  3. Elevated exhaust temperature, zoned, electrically-heated particulate matter filter

    Science.gov (United States)

    Gonze, Eugene V [Pinckney, MI; Bhatia, Garima [Bangalore, IN

    2012-04-17

    A system includes an electrical heater and a particulate matter (PM) filter that is arranged one of adjacent to and in contact with the electrical heater. A control module selectively increases an exhaust gas temperature of an engine to a first temperature and that initiates regeneration of the PM filter using the electrical heater while the exhaust gas temperature is above the first temperature. The first temperature is greater than a maximum exhaust gas temperature at the PM filter during non-regeneration operation and is less than an oxidation temperature of the PM.

  4. Computation of radionuclide particulate finite area fugitive source strengths

    Energy Technology Data Exchange (ETDEWEB)

    Fields, D E

    1983-06-01

    Atmospheric source strengths quantifying particulate re-suspension from wind and non-wind disturbance-driven processes are computed for sites of small area. These values are useful in computing downwind air concentration values to evaluate risk to exposed populations. The net source strength for the site is the sum of the wind- and disturbance-driven components. A unified source strength approach includes both classes of re-suspension processes. More research is needed to satisfactorily express the time-dependence of re-suspension parameters, especially in non-arid climates where population densities are greater. (JMT)

  5. Aerotrace. Measurement of particulates from an engine combustor

    Energy Technology Data Exchange (ETDEWEB)

    Hurley, C D [DRA, Farnborough (United Kingdom)

    1998-12-31

    The effect of gas turbine operating conditions, inlet temperature, pressure and overall air fuel ratio, on particulate number density has been measured. Particulate number density was found to be proportional to combustor inlet pressure and decrease with increasing combustor inlet temperature. The relationship with air fuel ratio is more complex. The mechanism of particulate loss down sample lines has been elucidated and equations are presented to predict particulate losses for stainless steel and PTFE sample lines. (author) 3 refs.

  6. Aerotrace. Measurement of particulates from an engine combustor

    Energy Technology Data Exchange (ETDEWEB)

    Hurley, C.D. [DRA, Farnborough (United Kingdom)

    1997-12-31

    The effect of gas turbine operating conditions, inlet temperature, pressure and overall air fuel ratio, on particulate number density has been measured. Particulate number density was found to be proportional to combustor inlet pressure and decrease with increasing combustor inlet temperature. The relationship with air fuel ratio is more complex. The mechanism of particulate loss down sample lines has been elucidated and equations are presented to predict particulate losses for stainless steel and PTFE sample lines. (author) 3 refs.

  7. Atmospheric trace metal concentrations in Suspended Particulate ...

    African Journals Online (AJOL)

    The air particulate samples were collected from the kitchens, living rooms and outdoor environment of five households in the community. The quantification of the trace metals was done using Atomic Absorption spectrometry method, employing HNO based wet digestion. High baseline concentration of SPMwere obtained ...

  8. Effect of condensable species on particulate fouling

    NARCIS (Netherlands)

    Sathyanarayanarao Subbarao, K.K.; Rindt, C.C.M.; Steenhoven, van A.A.; Malayeri, M.R.; Muller-Steinhagen, H.; Watkinson, A.P.

    2011-01-01

    The flue gases emanating from the combustion of fuels or gasification process invariably comprises particulate matter and many chemical species in vapor form. The temperature of the flue gases gradually reduces when passing through different sections of heat exchanger like superheater, evaporator

  9. Effect of condensable species on particulate fouling

    NARCIS (Netherlands)

    Sathyanarayanarao Subbarao, K.K.; Rindt, C.C.M.; Steenhoven, van A.A.

    2013-01-01

    The flue gases emanating from the combustion of fuels or gasification process invariably comprise particulate matter and many chemical species in vapor form. The temperature of the flue gases gradually reduces when passing through different sections of heat exchanger, such as the superheater,

  10. Evaluation of diesel particulate matter sampling techniques

    CSIR Research Space (South Africa)

    Pretorius, CJ

    2011-09-01

    Full Text Available The study evaluated diesel particulate matter (DPM) sampling methods used in the South African mining industry. The three-piece cassette respirable, open face and stopper sampling methods were compared with the SKC DPM cassette method to find a...

  11. Casting of particulate Al-base composites

    International Nuclear Information System (INIS)

    Moustafa, S.F.

    1997-01-01

    A molten Al-4 wt.% Cu as well as a Al-13 wt.% Si alloy have been mixed mechanically with particulate of SiC, Al 2 O 3 , or graphite. After the completion of mixing, each mixture was poured into a permanent mould to solidify. To overcome the problem of non-wettability that exists between the investigated particulate and the molten aluminum alloys the particulate was chemically treated by impregnation in a solution containing Na + ions. The loading of SiC or Al 2 O 3 particulate in the produced composites can be as high as 40 wt.%, and for graphite particles it can be 20 wt.%. The mixing time required to introduce and distribute the investigated particles into the molten matrix was as low as five minutes to recluce chemical reactions at the interfaces between them. Processing details and parameters controlling this technique are described. Metallographic examinations as well as tensile tests were carried out to characterize the microstructure, the distribution of the particles and the strength of these composites. The results display that the composites made by this technique have good microstructure and tensile properties. (orig.)

  12. Glints from particulate media and wavy surfaces

    International Nuclear Information System (INIS)

    Borovoi, Anatoli; Konoshonkin, Alexander; Kolokolova, Ludmilla

    2012-01-01

    Glints are bright light spots created by particulate media like cirrus clouds, glaciers, and wavy water surfaces. They are seen around the specular reflection angle. In this paper, the glints from such scattering/reflecting media are described in a unified manner through the probability density for facet tilts. Various kinds of these probability densities for wavy surfaces are defined and classified. The concept of the differential scattering cross section (DSCS) for rough surfaces instead of the conventional bidirectional reflectance distribution function (BRDF) is introduced for characterization of the glints. The simple equations connecting the DSCS and the probability densities for facet tilts are derived. It is shown that the glints from particulate media and wavy surface are very similar at small incidence angles and they are significantly different at slant incidence. -- Highlights: ► Differential scattering cross section unifies particulate media and wavy surfaces. ► The glint pattern is a mapping of the probability density function for facet tilts. ► Shadowing is a crucial aspect of glint pattern formation. ► Glint patterns discriminate between the particulate media and wavy surfaces.

  13. Particulate absorption properties in the Red Sea from hyperspectral particulate absorption spectra

    KAUST Repository

    Tiwari, Surya Prakash; Zarokanellos, Nikolaos; Kheireddine, Malika; Shanmugam, Palanisamy; Jones, Burton

    2018-01-01

    This paper aims to describe the variability of particulate absorption properties using a unique hyperspectral dataset collected in the Red Sea as part of the TARA Oceans expedition. The absorption contributions by phytoplankton (aph) and non

  14. Air emission in France. Metropolitan area particulate matter; Emissions dans l'air en France. Metropole poussieres

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2002-04-01

    Substances and index currently in survey are: Particulate matter: Total suspended particulates (TSP), Fine particulates with an equivalent aerodynamic diameter less than 10 {mu}m (PM{sub 10}), 2.5 {mu}m (PM{sub 2.5}) and 1.0 {mu}m (PM{sub 1.0}). Density ratios relating to population, area, gross product, primary energy consumption, etc. Annual emissions are provided for each substance since 1990. Dates corresponding to the maximum and minimum values are also included. Results are provisional for 2001. (author)

  15. Chemical characterization of urban air particulate matter of Kuala Lumpur 2002-2004

    International Nuclear Information System (INIS)

    Wee Boon Siong; Ab. Khalik Bin Haji Wood

    2006-01-01

    Urban air particulate samples of Kuala Lumpur ambient air have been collected characterize according to fine and coarse airborne particulates. The air filters containing particulate matter were collected using GENT stack filter unit fitted with appropriate polycarbonate filters. The sampling location site (Lat: 03deg 10'30''; Long: 101deg 43'24.2'') is approximately 1 km from the Kuala Lumpur city center. All the sampling conducted from January 2002 until October 2004 was included in the analysis and results were reported. The mass loading for finest air particulate matter (PM 2.5) in Kuala Lumpur are 199±55 μg (2002), 171±53 μg (2003), and 171±61 μg (2004), respectively. The mass loading for coarse air particulate matter (PM 10) in Kuala Lumpur were 125±29 μg (2002), 134±48 μg (2003), and 137 ± 57 μg (2004), respectively. The elemental concentration of the air filters were determined using INAA technique utilizing both short and long irradiation facilities at MINT's TRIGA MKII reactor. Upon irradiation the air filters were counted at suitable counting time using HPGe gamma-ray detectors. The elements reported for this monitoring are Al, As, Br, Co, Cr, K, Lu, Mn, Na, Sb, Sc, Ti, V, and Zn. Certified reference materials were also included in the sample analysis function as quality control materials. (author)

  16. Dynamic Heterogeneous Multiscale Filtration Model: Probing Micro- and Macroscopic Filtration Characteristics of Gasoline Particulate Filters.

    Science.gov (United States)

    Gong, Jian; Viswanathan, Sandeep; Rothamer, David A; Foster, David E; Rutland, Christopher J

    2017-10-03

    Motivated by high filtration efficiency (mass- and number-based) and low pressure drop requirements for gasoline particulate filters (GPFs), a previously developed heterogeneous multiscale filtration (HMF) model is extended to simulate dynamic filtration characteristics of GPFs. This dynamic HMF model is based on a probability density function (PDF) description of the pore size distribution and classical filtration theory. The microstructure of the porous substrate in a GPF is resolved and included in the model. Fundamental particulate filtration experiments were conducted using an exhaust filtration analysis (EFA) system for model validation. The particulate in the filtration experiments was sampled from a spark-ignition direct-injection (SIDI) gasoline engine. With the dynamic HMF model, evolution of the microscopic characteristics of the substrate (pore size distribution, porosity, permeability, and deposited particulate inside the porous substrate) during filtration can be probed. Also, predicted macroscopic filtration characteristics including particle number concentration and normalized pressure drop show good agreement with the experimental data. The resulting dynamic HMF model can be used to study the dynamic particulate filtration process in GPFs with distinct microstructures, serving as a powerful tool for GPF design and optimization.

  17. Urban tree effects on fine particulate matter and human health

    Science.gov (United States)

    David J. Nowak

    2014-01-01

    Overall, city trees reduce particulate matter and provide substantial health benefits; but under certain conditions, they can locally increase particulate matter concentrations. Urban foresters need to understand how trees affect particulate matter so they can select proper species and create appropriate designs to improve air quality. This article details trees'...

  18. Cervical transforaminal epidural steroid injection for the management of cervical radiculopathy: a comparative study of particulate versus non-particulate steroids

    International Nuclear Information System (INIS)

    Lee, Joon Woo; Kang, Heung Sik; Park, Kun Woo; Yeom, Jin S.; Chung, Sang-Ki; Kim, Ki-Jeong; Kim, Hyun-Jib

    2009-01-01

    To determine if a particulate steroid which has a risk for embolic infarct would be more effective than a non-particulate steroid for transforaminal epidural steroid injection (TFESI). The purpose of this study was (1) to compare the effect of cervical TFESI using particulate (e.g., triamcinolone) and non-particulate (e.g., dexamethasone) steroids and (2) to evaluate the effectiveness of cervical TFESI in general. From January 2006 to August 2008, 159 consecutive patients [male:female (M:F) 89:70; mean age 53 years, range 33-75 years] who underwent cervical TFESI were included in this non-randomized study. For cervical TFESI, triamcinolone was injected into 97 patients and dexamethasone into 62 patients. Short-term follow-up was conducted within 1 month. The outcome was classified as effective or ineffective. Fisher's exact test was used to analyze the difference of outcome according to the injected steroid (triamcinolone vs dexamethasone). Other possible outcome predictors, such as age, gender, duration of radiculopathy, predominant symptom, attack of radiculopathy, cause of radiculopathy, number of nerve root compression levels, previous operation, and failure of previous interlaminar epidural injection, were also analyzed. Cervical TFESI using triamcinolone (78/97, 80.4%) was slightly more effective than that using dexamethasone (43/62, 69.4%), which was not significant (P = 0.129). In general, cervical TFESIs were effective in 121 of 159 patients (76.1%) at short-term follow-up. The only significant outcome predictor was whether the patient had had a previous operation (6/13, 46/2%) or not (115/146, 78.8%) (P = 0.015). There was no significant difference between particulate or non-particulate steroid for the effect of cervical TFESI. Cervical TFESI was effective in managing cervical radiculopathy in general. (orig.)

  19. Cervical transforaminal epidural steroid injection for the management of cervical radiculopathy: a comparative study of particulate versus non-particulate steroids

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Joon Woo; Kang, Heung Sik [Seoul National University Bundang Hospital, Department of Radiology, Gyeonggi-Do (Korea); Park, Kun Woo; Yeom, Jin S. [Seoul National University Bundang Hospital, Department of Orthopaedic Surgery, Gyeonggi-Do (Korea); Chung, Sang-Ki; Kim, Ki-Jeong; Kim, Hyun-Jib [Seoul National University Bundang Hospital, Department of Neurosurgery, Gyeonggi-do (Korea)

    2009-11-15

    To determine if a particulate steroid which has a risk for embolic infarct would be more effective than a non-particulate steroid for transforaminal epidural steroid injection (TFESI). The purpose of this study was (1) to compare the effect of cervical TFESI using particulate (e.g., triamcinolone) and non-particulate (e.g., dexamethasone) steroids and (2) to evaluate the effectiveness of cervical TFESI in general. From January 2006 to August 2008, 159 consecutive patients [male:female (M:F) 89:70; mean age 53 years, range 33-75 years] who underwent cervical TFESI were included in this non-randomized study. For cervical TFESI, triamcinolone was injected into 97 patients and dexamethasone into 62 patients. Short-term follow-up was conducted within 1 month. The outcome was classified as effective or ineffective. Fisher's exact test was used to analyze the difference of outcome according to the injected steroid (triamcinolone vs dexamethasone). Other possible outcome predictors, such as age, gender, duration of radiculopathy, predominant symptom, attack of radiculopathy, cause of radiculopathy, number of nerve root compression levels, previous operation, and failure of previous interlaminar epidural injection, were also analyzed. Cervical TFESI using triamcinolone (78/97, 80.4%) was slightly more effective than that using dexamethasone (43/62, 69.4%), which was not significant (P = 0.129). In general, cervical TFESIs were effective in 121 of 159 patients (76.1%) at short-term follow-up. The only significant outcome predictor was whether the patient had had a previous operation (6/13, 46/2%) or not (115/146, 78.8%) (P = 0.015). There was no significant difference between particulate or non-particulate steroid for the effect of cervical TFESI. Cervical TFESI was effective in managing cervical radiculopathy in general. (orig.)

  20. Characteristics and source appointment of atmospheric particulate mercury over East China Sea: Implication on the deposition of atmospheric particulate mercury in marine environment.

    Science.gov (United States)

    Duan, Lian; Cheng, Na; Xiu, Guangli; Wang, Fujiang; Chen, Ying

    2017-05-01

    Total Suspended Particulate (TSP) samples were collected at Huaniao Island in northern East China Sea (ECS) from March 2012 to January 2013. Chemical analysis were conducted to measure the concentration of total particulate mercury (TPM) and speciated particulate mercury including HCl-soluble particulate mercury (HPM), elemental particulate mercury (EPM) and residual particulate mercury (RPM). The bromine (Br) and iodine (I) on particles were also detected. The mean concentration of TPM during the study period was 0.23 ± 0.15 ng m -3 , while the obviously seasonal variation was found that the concentrations of TPM in spring, summer, fall and winter were 0.34 ± 0.20 ng m -3 , 0.15 ± 0.03 ng m -3 , 0.15 ± 0.05 ng m -3 and 0.27 ± 0.26 ng m -3 , respectively. The statistically strong correlation of bromine and iodine to HPM was only found in spring with r = 0.81 and 0.77 (p mercury due to the deposition of mercury over the sea. The cluster of air mass across the sea had low concentration of HPM in winter, which suggested that the oxidation of mercury in winter might be related to other oxidants. During the whole sampling period, the air mass from the north of China contributed to the higher concentration of TPM in Huaniao Island. Copyright © 2016 Elsevier Ltd. All rights reserved.

  1. Key sources and distribution patterns of particulate material in the South Atlantic: data from the UK GEOTRACES A10 cruise

    Science.gov (United States)

    Milne, A.; Palmer, M.; Lohan, M. C.

    2016-02-01

    Particles play a fundamental role in the biogeochemical cycling of both major- and micro-nutrients in marine systems, including trace elements and isotopes. However, knowledge of particulate distributions, and their potential to regulate dissolved elemental concentrations, remains limited and poorly understood. The paradox is, that the oceanic inventory of trace metals is dominated by particulate inputs (e.g. aerosol deposition, shelf sediment resuspension). Moreover the labile fraction of particulate trace elements could be an important regulator of dissolved concentrations. Here we present particulate data from the UK GEOTRACES South Atlantic transect (GA10) from South Africa to Uruguay. Data from a range of elements (e.g. Fe, Al, Mn) revealed a greater input of particulate metals from the Argentine shelf (up to 290 nM of pFe) in comparison to the South African shelf (basin and penetrated deeper up the water column (up to 1300 m), a result of intense benthic storms. The imprint of leakage from the Agulhas Current, identified through temperature and salinity, was observed in the upper water column profile of numerous particulate data (e.g. Pb, Ni, Cd). Measured elemental gradients, combined with measurements from a vertical mixing-profiler, will allow estimates of particulate fluxes to be calculated.

  2. Note on the sanitary impact of diesel particulates; Note sur l'impact sanitaire des particules diesel

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2003-10-15

    In the actual situation of scientific works, the epidemiology studies on environment do not allow to say the carcinogen contribution of diesel particulates at the concentration levels measured in the urban air. But according to the experimental data for the rat and the data observed for the personnel exposed to diesel particulates these particulates are classified as probably carcinogen. (N.C.)

  3. MERCURY CONTROL WITH THE ADVANCED HYBRID PARTICULATE COLLECTOR

    International Nuclear Information System (INIS)

    Stanley J. Miller; Grant E. Dunham; Michelle R. Olderbak

    2001-01-01

    This project was awarded under U.S. Department of Energy (DOE) Program Solicitation DE-PS26-00NT40769 and specifically addresses Technical Topical Area 4-Testing Novel and Less Mature Control Technologies on Actual Flue Gas at the Pilot-Scale. The project team will include the Energy and Environmental Research Center (EERC) as the main contractor, W.L. Gore and Associates, Inc., as a technical and financial partner, and the Big Stone Power Plant operated by Otter Tail Power Company, which will host the field testing portion of the research. Since 1995, DOE has supported development of a new concept in particulate control, called the advanced hybrid particulate collector (AHPC). The AHPC combines the best features of electrostatic precipitators (ESPs) and baghouses in a unique configuration, providing major synergism between the two collection methods, both in the particulate collection step and in the transfer of dust to the hopper. The AHPC provides ultrahigh collection efficiency, overcoming the problem of excessive fine-particle emission with conventional ESPs, and it solves the problem of reentrainment and re-collection of dust in conventional baghouses. The AHPC appears to have unique advantages for mercury control over baghouses or ESPs as an excellent gas-solid contactor. The objective of the three-task project is to demonstrate 90% total mercury control in the AHPC at a lower cost than current mercury control estimates. The approach includes bench-scale batch testing that ties the new work to previous results and links results with larger-scale pilot testing with real flue gas on a coal-fired combustion system, pilot-scale testing on a coal-fired combustion system with both a pulse-jet baghouse and an AHPC to prove or disprove the research hypotheses, and field demonstration pilot-scale testing at a utility power plant to prove scaleup and demonstrate longer-term mercury control. This project, if successful, will demonstrate at the pilot-scale level a

  4. Spatial and temporal variability in urban fine particulate matter concentrations

    International Nuclear Information System (INIS)

    Levy, Jonathan I.; Hanna, Steven R.

    2011-01-01

    Identification of hot spots for urban fine particulate matter (PM 2.5 ) concentrations is complicated by the significant contributions from regional atmospheric transport and the dependence of spatial and temporal variability on averaging time. We focus on PM 2.5 patterns in New York City, which includes significant local sources, street canyons, and upwind contributions to concentrations. A literature synthesis demonstrates that long-term (e.g., one-year) average PM 2.5 concentrations at a small number of widely-distributed monitoring sites would not show substantial variability, whereas short-term (e.g., 1-h) average measurements with high spatial density would show significant variability. Statistical analyses of ambient monitoring data as a function of wind speed and direction reinforce the significance of regional transport but show evidence of local contributions. We conclude that current monitor siting may not adequately capture PM 2.5 variability in an urban area, especially in a mega-city, reinforcing the necessity of dispersion modeling and methods for analyzing high-resolution monitoring observations. - Highlights: →Fine particulate matter (PM 2.5 ) hot spots are hard to identify in urban areas. → Literature conclusions about PM 2.5 hot spots depend on study design and methods. → Hot spots are more likely for short-term concentrations at high spatial density. → Statistical methods illustrate local source impacts beyond regional transport. → Dispersion models and high-resolution monitors are both needed to find hot spots. - Fine particulate matter can vary spatially within large urban areas, in spite of the significant contribution from regional atmospheric transport.

  5. Organic speciation of size-segregated atmospheric particulate matter

    Science.gov (United States)

    Tremblay, Raphael

    Particle size and composition are key factors controlling the impacts of particulate matter (PM) on human health and the environment. A comprehensive method to characterize size-segregated PM organic content was developed, and evaluated during two field campaigns. Size-segregated particles were collected using a cascade impactor (Micro-Orifice Uniform Deposit Impactor) and a PM2.5 large volume sampler. A series of alkanes and polycyclic aromatic hydrocarbons (PAHs) were solvent extracted and quantified using a gas chromatograph coupled with a mass spectrometer (GC/MS). Large volume injections were performed using a programmable temperature vaporization (PTV) inlet to lower detection limits. The developed analysis method was evaluated during the 2001 and 2002 Intercomparison Exercise Program on Organic Contaminants in PM2.5 Air Particulate Matter led by the US National Institute of Standards and Technology (NIST). Ambient samples were collected in May 2002 as part of the Tampa Bay Regional Atmospheric Chemistry Experiment (BRACE) in Florida, USA and in July and August 2004 as part of the New England Air Quality Study - Intercontinental Transport and Chemical Transformation (NEAQS - ITCT) in New Hampshire, USA. Morphology of the collected particles was studied using scanning electron microscopy (SEM). Smaller particles (one micrometer or less) appeared to consist of solid cores surrounded by a liquid layer which is consistent with combustion particles and also possibly with particles formed and/or coated by secondary material like sulfate, nitrate and secondary organic aerosols. Source apportionment studies demonstrated the importance of stationary sources on the organic particulate matter observed at these two rural sites. Coal burning and biomass burning were found to be responsible for a large part of the observed PAHs during the field campaigns. Most of the measured PAHs were concentrated in particles smaller than one micrometer and linked to combustion sources

  6. Quantifying the environmental impact of particulate deposition from dry unpaved roadways

    Energy Technology Data Exchange (ETDEWEB)

    Becker, D.L.

    1979-01-01

    Airborne dust is the air pollutant most frequently observed to exceed National Ambient Air Quality Standards in rural areas. This pollutant (also referred to as suspended particulates) may originate from point sources (e.g., large areas of bare soil or pollen-producing vegetation.) Most sources of atmospheric particulates, whether natural or anthropogenic, are difficult to quantify by means of a source strength (i.e., mass of particulates emitted per unit time). A numerical model was developed for calculating the source strength and quantifying the atmospheric transport and eposition of dust generated on unpaved roadways. This model satisfies the second-order differential equation for the diffusion process and also the equation of mass conservation. Input to the model includes meterological variables, surface roughness characteristics, and the size distribution and suspended particulate concentration of dust as sampled downwind of an unpaved roadway. By using predetermined tolerance levels of airborne concentrations or tolerance levels of deposition, maximum allowable vehicular traffic volume can be established. The model also may be used to estimate reduction in photosynthesis resulting from fugitive dust from point or line sources. The contribug ion to sedimentation in aquatic bodies, resulting from airborne particulates also may be assessed with this model.

  7. New seismograph includes filters

    Energy Technology Data Exchange (ETDEWEB)

    1979-11-02

    The new Nimbus ES-1210 multichannel signal enhancement seismograph from EG and G geometrics has recently been redesigned to include multimode signal fillers on each amplifier. The ES-1210F is a shallow exploration seismograph for near subsurface exploration such as in depth-to-bedrock, geological hazard location, mineral exploration, and landslide investigations.

  8. Particulate Study on NeoProfen, a Neonatal Injectable Product.

    Science.gov (United States)

    Krishna, Aravind; Rice, Michael; Kester, Tom; Waters, Michael; Wilson, Terry

    2016-01-01

    NeoProfen or sterile ibuprofen L-lysine at 10 mg/mL ibuprofen, in 2 mL single-use Type I glass vials is often a first choice medication used to close a patent ductus arteriosus in neonatal patients from 500 to 1500 g body weight. Visible particulate matter was found in vials that were placed on a commercial stability program prior to the approved expiration date of 2 years. A combination of instrumental techniques including inductively coupled plasma-mass spectrometry, x-ray photoelectron spectroscopy, scanning electron microscopy energy dispersive x-ray spectrometry, and Raman and Fourier transform infrared microspectroscopy was used to evaluate stability, pilot batch and packaging samples in a root cause investigation. The particulate matter was shown to consist largely of ibuprofen aluminum salts of various stoichiometries. It developed over time by a substitution mechanism, in which the ibuprofen anion in solution reacts with the aluminum oxide network of the borosilicate glass giving the ibuprofen aluminum salt with =Al-OH remaining in the network. For corrective action an alternate Type I borosilicate glass vial with interior coating, not found in the original vial, was chosen for the product to prevent this occurrence. NeoProfen (sterile preservative-free ibuprofin L-lysine at 17 mg/mL in a single-use glass vial) is used to close a clinically significant patent ductus arteriosus in premature infants no more than 32 weeks gestational age. The neonatal population is especially sensitive to outside chemical, physical and environmental conditions because of incompletely developed organ systems, low birth weight and other underlying conditions. Two batches of this product were voluntarily recalled by the manufacturer, Lundbeck, and investigated for the source of particulate matter observed during a commercial stability testing program. This was found to result from an interaction between the product and the Type I borosilicate glass vial where ibuprofen

  9. Efficiency of Respirator Filter Media against Diesel Particulate Matter: A Comparison Study Using Two Diesel Particulate Sources.

    Science.gov (United States)

    Burton, Kerrie A; Whitelaw, Jane L; Jones, Alison L; Davies, Brian

    2016-07-01

    Diesel engines have been a mainstay within many industries since the early 1900s. Exposure to diesel particulate matter (DPM) is a major issue in many industrial workplaces given the potential for serious health impacts to exposed workers; including the potential for lung cancer and adverse irritant and cardiovascular effects. Personal respiratory protective devices are an accepted safety measure to mitigate worker exposure against the potentially damaging health impacts of DPM. To be protective, they need to act as effective filters against carbon and other particulates. In Australia, the filtering efficiency of respiratory protective devices is determined by challenging test filter media with aerosolised sodium chloride to determine penetration at designated flow rates. The methodology outlined in AS/NZS1716 (Standards Australia International Ltd and Standards New Zealand 2012. Respiratory protective devices. Sydney/Wellington: SAI Global Limited/Standards New Zealand) does not account for the differences between characteristics of workplace contaminants like DPM and sodium chloride such as structure, composition, and particle size. This study examined filtering efficiency for three commonly used AS/NZS certified respirator filter models, challenging them with two types of diesel emissions; those from a diesel generator and a diesel engine. Penetration through the filter media of elemental carbon (EC), total carbon (TC), and total suspended particulate (TSP) was calculated. Results indicate that filtering efficiency assumed by P2 certification in Australia was achieved for two of the three respirator models for DPM generated using the small diesel generator, whilst when the larger diesel engine was used, filtering efficiency requirements were met for all three filter models. These results suggest that the testing methodology specified for certification of personal respiratory protective devices by Standards Australia may not ensure adequate protection for

  10. NICKEL SPECIATION OF URBAN PARTICULATE MATTER

    Energy Technology Data Exchange (ETDEWEB)

    Kevin C. Galbreath; Charlene R. Crocker; Carolyn M. Nyberg; Frank E. Huggins; Gerald P. Huffman

    2003-10-01

    A four-step sequential Ni extraction method, summarized in Table AB-1, was evaluated for identifying and quantifying the Ni species occurring in urban total suspended particulate (TSP) matter and fine particulate matter (<10 {micro}m [PM{sub 10}] and <2.5 {micro}m [PM{sub 2.5}] in aerodynamic diameter). The extraction method was originally developed for quantifying soluble, sulfidic, elemental, and oxidic forms of Ni that may occur in industrial atmospheres. X-ray diffraction (XRD) and x-ray absorption fine structure (XAFS) spectroscopy were used to evaluate the Ni species selectivity of the extraction method. Uncertainties in the chemical speciation of Ni in urban PM{sub 10} and PM{sub 2.5} greatly affect inhalation health risk estimates, primarily because of the large variability in acute, chronic, and cancer-causing effects for different Ni compounds.

  11. Particulate photocatalysts for overall water splitting

    Science.gov (United States)

    Chen, Shanshan; Takata, Tsuyoshi; Domen, Kazunari

    2017-10-01

    The conversion of solar energy to chemical energy is a promising way of generating renewable energy. Hydrogen production by means of water splitting over semiconductor photocatalysts is a simple, cost-effective approach to large-scale solar hydrogen synthesis. Since the discovery of the Honda-Fujishima effect, considerable progress has been made in this field, and numerous photocatalytic materials and water-splitting systems have been developed. In this Review, we summarize existing water-splitting systems based on particulate photocatalysts, focusing on the main components: light-harvesting semiconductors and co-catalysts. The essential design principles of the materials employed for overall water-splitting systems based on one-step and two-step photoexcitation are also discussed, concentrating on three elementary processes: photoabsorption, charge transfer and surface catalytic reactions. Finally, we outline challenges and potential advances associated with solar water splitting by particulate photocatalysts for future commercial applications.

  12. High exhaust temperature, zoned, electrically-heated particulate matter filter

    Science.gov (United States)

    Gonze, Eugene V.; Paratore, Jr., Michael J.; Bhatia, Garima

    2015-09-22

    A system includes a particulate matter (PM) filter, an electric heater, and a control circuit. The electric heater includes multiple zones, which each correspond to longitudinal zones along a length of the PM filter. A first zone includes multiple discontinuous sub-zones. The control circuit determines whether regeneration is needed based on an estimated level of loading of the PM filter and an exhaust flow rate. In response to a determination that regeneration is needed, the control circuit: controls an operating parameter of an engine to increase an exhaust temperature to a first temperature during a first period; after the first period, activates the first zone; deactivates the first zone in response to a minimum filter face temperature being reached; subsequent to deactivating the first zone, activates a second zone; and deactivates the second zone in response to the minimum filter face temperature being reached.

  13. Vertical hydraulic transport of particulate solids

    International Nuclear Information System (INIS)

    Restini, C.V.; Massarani, G.

    1977-01-01

    The problem of particulate solid vertical transport is formulated using the conservation equations of Continuum Mechanics. It is shown that the constitutive equation for solid-fluid interaction term in the equations of motion may be determined by rather simple experiments of homogeneous fluidization. The predicted fluid pressure drop and solid concentration are in satisfacting agreement with past experiments and with data obtained in this work. (Author) [pt

  14. Analytic device including nanostructures

    KAUST Repository

    Di Fabrizio, Enzo M.; Fratalocchi, Andrea; Totero Gongora, Juan Sebastian; Coluccio, Maria Laura; Candeloro, Patrizio; Cuda, Gianni

    2015-01-01

    A device for detecting an analyte in a sample comprising: an array including a plurality of pixels, each pixel including a nanochain comprising: a first nanostructure, a second nanostructure, and a third nanostructure, wherein size of the first nanostructure is larger than that of the second nanostructure, and size of the second nanostructure is larger than that of the third nanostructure, and wherein the first nanostructure, the second nanostructure, and the third nanostructure are positioned on a substrate such that when the nanochain is excited by an energy, an optical field between the second nanostructure and the third nanostructure is stronger than an optical field between the first nanostructure and the second nanostructure, wherein the array is configured to receive a sample; and a detector arranged to collect spectral data from a plurality of pixels of the array.

  15. Saskatchewan resources. [including uranium

    Energy Technology Data Exchange (ETDEWEB)

    1979-09-01

    The production of chemicals and minerals for the chemical industry in Saskatchewan are featured, with some discussion of resource taxation. The commodities mentioned include potash, fatty amines, uranium, heavy oil, sodium sulfate, chlorine, sodium hydroxide, sodium chlorate and bentonite. Following the successful outcome of the Cluff Lake inquiry, the uranium industry is booming. Some developments and production figures for Gulf Minerals, Amok, Cenex and Eldorado are mentioned.

  16. L'univers des particules une introduction

    CERN Document Server

    Diu, Bernard

    2017-01-01

    Au début du XXe siècle, les scientifiques imaginaient que l'ensemble du monde était construit à partir de trois "particules élémentaires" (électron, proton, photon). Depuis, nous avons appris que notre univers contient un nombre considérable de particules - soit des corps individualisés d'extension réduite - de natures et de caractéristiques très diverses, qu'il serait illusoire de chercher à énumérer de manière formelle et systématique. C'est pourquoi le propos de ce livre suit une stratégie fondamentalement différente. Il s'organise autour de certaines propriétés générales que laissent apparaître l'observation et l'étude des particules dans leur existence et leur conduite primaire. Aussi, chacune des parties de cet ouvrage rassemble plusieurs chapitres de thèmes voisins, mais un sujet donné peut également être traité en divers endroits et, de ce fait, être abordé sous différents angles de manière complémentaire. De telles compositions et décompositions d'éléments proche...

  17. Sampling/classification of gasifier particulates

    International Nuclear Information System (INIS)

    Wegrzyn, J.

    1984-01-01

    A high temperature and pressure real time extractive sampling probe for particulate monitoring was built at Brookhaven National Laboratory and tested on Morgantown Energy Technology Center's 42 inch fixed bed gasifier. The probe was specifically designed for the conditions of highly loaded particulate and condensable streams, that exist at the outlet of a fixed bed gasifier. Some of the salient features of the probe are: porous tube gas injection, aerodynamic particle classification in the presence of condensable vapors, β gauge particle detection, and micro processor control. Three of the key design problems were the separation of the particles from the vapor without promoting condensation, the prevention of plugging, and real time monitoring. Some plugging did occur over the seven day sampling period, but by over pressurizing and back purging the clog was blown back into the process stream. The tests validate the proof of concept of the sampling probe and indicated that the particulate output from the bed came in the form of bursts (several minutes in duration) rather than in the form of a steady stream

  18. Standard specification for high efficiency particulate air filters. Revision No. 2

    International Nuclear Information System (INIS)

    Porter, F.E.

    1976-01-01

    This specification covers the requirements for four types and four sizes of high efficiency particulate air filters, assembled with or without separators and gaskets. Types include Fire Resistant and Moisture Resistant; Hydrogen Fluoride Fume (HF) Resistant; Fire Resistant and Moisture Resistant and Chemical Resistant; and Fire Resistant and Moisture Resistant, High Temperature and High Humidity

  19. Ambient Air Pollution and Increases in Blood Pressure: Role for biological constituents of particulate matter

    Science.gov (United States)

    Particulate matter (PM) is a complex mixture of extremely small particles and liquid droplets made up of a number of components including elemental carbon, organic chemicals, metals, acids (such as nitrates and sulfates), and soil and dust particles. Epidemiological studies con...

  20. IDENTIFICATION OF POSSIBLE SOURCES OF PARTICULATE MATTER IN THE PERSONAL CLOUD USING SEM/EDX

    Science.gov (United States)

    The United States Environmental Protection Agency (U.S. EPA) conducted the Baltimore Particulate Matter (PM) Epidemiology-Exposure Study of the Elderly during the summer of 1998. The study design included PM2.5 samples obtained from elderly (65+ years of age) retirement facility ...

  1. Effects of Source-Apportioned Coarse Particulate Matter (PM) on Allergic Responses in Mice

    Science.gov (United States)

    The Cleveland Multiple Air Pollutant Study (CMAPS) is one of the first comprehensive studies conducted to evaluate particulate matter (PM) over local and regional scales. Cleveland and the nearby Ohio River Valley impart significant regional sources of air pollution including coa...

  2. Standard Practice for Sampling for Particulate Contamination by Tape Lift

    CERN Document Server

    American Society for Testing and Materials. Philadelphia

    2006-01-01

    1.1 This practice covers procedures for sampling surfaces to determine the presence of particulate contamination, 5 m and larger. The practice consists of the application of a pressure-sensitive tape to the surface followed by the removal of particulate contamination with the removal of the tape. The tape with the adhering particles is then mounted on counting slides. Counting and measuring of particles is done by standard techniques. 1.2 This practice describes the materials and equipment required to perform sampling of surfaces for particle counting and sizing. 1.3 The criteria for acceptance or rejection of a part for conformance to surface cleanliness level requirements shall be determined by the user and are not included in this practice. 1.4 This practice is for use on surfaces that are not damaged by the application of adhesive tape. The use of this practice on any surface of any material not previously tested or for which the susceptibility to damage is unknown is not recommended. In general, metal...

  3. Particulate matter analysis at elementary schools in Curitiba, Brazil.

    Science.gov (United States)

    Avigo, Devanir; Godoi, Ana F L; Janissek, Paulo R; Makarovska, Yaroslava; Krata, Agnieszka; Potgieter-Vermaak, Sanja; Alfoldy, Balint; Van Grieken, René; Godoi, Ricardo H M

    2008-06-01

    The particulate matter indoors and outdoors of the classrooms at two schools in Curitiba, Brazil, was characterised in order to assess the indoor air quality. Information concerning the bulk composition was provided by energy-dispersive x-ray fluorescence (EDXRF). From the calculated indoor/outdoor ratios and the enrichment factors it was observed that S-, Cl- and Zn-rich particles are of concern in the indoor environment. In the present research, the chemical compositions of individual particles were quantitatively elucidated, including low-Z components like C, N and O, as well as higher-Z elements, using automated electron probe microanalysis low Z EPMA. Samples were further analysed for chemical and morphological aspects, determining the particle size distribution and classifying them according to elemental composition associations. Five classes were identified based on major elemental concentrations: aluminosilicate, soot, organic, calcium carbonate and iron-rich particles. The majority of the respirable particulate matter found inside of the classroom was composed of soot, biogenic and aluminosilicate particles. In view of the chemical composition and size distribution of the aerosol particles, local deposition efficiencies in the human respiratory system were calculated revealing the deposition of soot at alveolar level. The results showed that on average 42% of coarse particles are deposited at the extrathoracic level, whereas 24% are deposited at the pulmonary region. The fine fraction showed a deposition rate of approximately 18% for both deposition levels.

  4. Composition and oxidation state of sulfur in atmospheric particulate matter

    Directory of Open Access Journals (Sweden)

    A. F. Longo

    2016-10-01

    Full Text Available The chemical and physical speciation of atmospheric sulfur was investigated in ambient aerosol samples using a combination of sulfur near-edge x-ray fluorescence spectroscopy (S-NEXFS and X-ray fluorescence (XRF microscopy. These techniques were used to determine the composition and oxidation state of sulfur in common primary emission sources and ambient particulate matter collected from the greater Atlanta area. Ambient particulate matter samples contained two oxidation states: S0 and S+VI. Ninety-five percent of the individual aerosol particles (> 1 µm analyzed contain S0. Linear combination fitting revealed that S+VI in ambient aerosol was dominated by ammonium sulfate as well as metal sulfates. The finding of metal sulfates provides further evidence for acidic reactions that solubilize metals, such as iron, during atmospheric transport. Emission sources, including biomass burning, coal fly ash, gasoline, diesel, volcanic ash, and aerosolized Atlanta soil, and the commercially available bacterium Bacillus subtilis, contained only S+VI. A commercially available Azotobacter vinelandii sample contained approximately equal proportions of S0 and S+VI. S0 in individual aerosol particles most likely originates from primary emission sources, such as aerosolized bacteria or incomplete combustion.

  5. Urban particulate matter pollution: a tale of five cities.

    Science.gov (United States)

    Pandis, Spyros N; Skyllakou, Ksakousti; Florou, Kalliopi; Kostenidou, Evangelia; Kaltsonoudis, Christos; Hasa, Erion; Presto, Albert A

    2016-07-18

    Five case studies (Athens and Paris in Europe, Pittsburgh and Los Angeles in the United States, and Mexico City in Central America) are used to gain insights into the changing levels, sources, and role of atmospheric chemical processes in air quality in large urban areas as they develop technologically. Fine particulate matter is the focus of our analysis. In all cases reductions of emissions by industrial and transportation sources have resulted in significant improvements in air quality during the last few decades. However, these changes have resulted in the increasing importance of secondary particulate matter (PM) which dominates over primary in most cases. At the same time, long range transport of secondary PM from sources located hundreds of kilometres from the cities is becoming a bigger contributor to the urban PM levels in all seasons. "Non-traditional" sources including cooking, and residential and agricultural biomass burning contribute an increasing fraction of the now reduced fine PM levels. Atmospheric chemistry is found to change the chemical signatures of a number of these sources relatively fast both during the day and night, complicating the corresponding source apportionment.

  6. Radio Frequency Sensing of Particulate Matter Accumulation on a Gasoline Particulate Filter

    Energy Technology Data Exchange (ETDEWEB)

    Parks, II, James E [ORNL; Prikhodko, Vitaly Y [ORNL; Sappok, Alex [Filter Sensing Technologies; Ragaller, Paul [Filter Sensing Technologies; Bromberg, L. [Massachusetts Institute of Technology (MIT)

    2016-10-30

    Filter Sensing Technology’s radio frequency (RF) sensor for particulate filter on-board diagnostics (OBD) was studied on a lean gasoline engine at the National Transportation Research Center (NTRC) at Oak Ridge National Laboratory (ORNL). The response of the RF sensor to particulate matter (PM) or “soot” accumulation on the gasoline particulate filter (GPF) installed in the engine exhaust was evaluated. In addition, end plugs of the GPF were purposely removed, and subsequent changes to the RF sensor measured soot loading on the GPF were characterized. Results from the study showed that the RF sensor can accurately measure soot accumulation on a GPF; furthermore, the predicted decreased soot accumulation due to plug removal was detected by the RF sensor. Overall, the studies were short and preliminary in nature; however, clearly, the RF sensor demonstrated the capability of measuring GPF soot loading at a level suitable for use in lean gasoline engine emission control OBD and control.

  7. Being Included and Excluded

    DEFF Research Database (Denmark)

    Korzenevica, Marina

    2016-01-01

    Following the civil war of 1996–2006, there was a dramatic increase in the labor mobility of young men and the inclusion of young women in formal education, which led to the transformation of the political landscape of rural Nepal. Mobility and schooling represent a level of prestige that rural...... politics. It analyzes how formal education and mobility either challenge or reinforce traditional gendered norms which dictate a lowly position for young married women in the household and their absence from community politics. The article concludes that women are simultaneously excluded and included from...... community politics. On the one hand, their mobility and decision-making powers decrease with the increase in the labor mobility of men and their newly gained education is politically devalued when compared to the informal education that men gain through mobility, but on the other hand, schooling strengthens...

  8. Flux dependency of particulate/colloidal fouling in seawater reverse osmosis systems

    KAUST Repository

    Salinas Rodríguez, S. G.

    2012-01-01

    Fouling is the main operational problem in seawater reverse osmosis systems (SWRO). Particulate fouling is traditionally measured through the silt density index (SDI) and through the modified fouling index (MFI). In recent years, ultrafiltration membranes were used successfully at constant flux-MFI-UF-to measure particulate/colloidal fouling potential and tested in sea water applications. Furthermore, constant flux operation allows predicting the rate of fouling in RO systems. The objectives of this study are: (1) to measure the flux effect in MFI-UF with different membranes (100, 30 and 10 kDa) for raw seawater and pre-treated water before reverse osmosis in three different locations; (2) to study the particulate and colloidal fouling potential of seawater in reverse osmosis systems; (3) to project the increase in pressure due to cake resistance in reverse osmosis systems. In this research, flat ultrafiltration membranes (100, 50, 30 and 10 kDa) are used in a con- stant flux filtration mode to test and compare real seawaters from various locations (North and Mediterranean Sea) and from various full scale facilities including different pre-treatments (i.e., ultrafiltration and coagulation + dual media filtration). The operated fluxes range from 350 down to values close to real RO operation, 15l(m2h)-1. After each filtration test, the MFI-UF is calculated to assess the particulate fouling potential. The obtained results showed that: (1) the particulate and colloidal fouling potential is directly proportional to the applied flux during filtration. This proportionality is related to the compression of the cake deposit occurring at high flux values; (2) the higher the flux, the higher the required pressure, the less porous the cake and therefore the higher the specific cake resistance; (3) particulate and colloidal fouling potential of seawater is site specific and is influenced by pre-treatment. © 2012 Desalination Publications. All rights reserved.

  9. Particulate versus non-particulate corticosteroids for transforaminal nerve root blocks. Comparison of outcomes in 494 patients with lumbar radiculopathy

    Energy Technology Data Exchange (ETDEWEB)

    Bensler, Susanne; Sutter, Reto; Pfirrmann, Christian W.A.; Peterson, Cynthia K. [Orthopaedic University Hospital Balgrist, Department of Radiology, Zurich (Switzerland); University of Zurich, Faculty of Medicine, Zurich (Switzerland)

    2018-03-15

    We set out to compare outcomes in CT-guided lumbar transforaminal nerve root block patients receiving either particulate or non-particulate corticosteroids. This was a retrospective comparative effectiveness outcomes study on two cohorts of lumbar radiculopathy patients. 321 received particulate and 173 non-particulate corticosteroids at CT-guided transforaminal lumbar nerve root injections. The particulate steroid was used from October 2009 until May 2014 and the non-particulate steroid was used from May 2014. Pain levels were collected at baseline using an 11-point numerical rating scale (NRS) and at 1 day, 1 week and 1 month. Overall 'improvement' was assessed using the Patients' Global Impression of Change (PGIC) at these same time points (primary outcome). The proportions of patients 'improved' were compared between the two groups using the Chi-square test. The NRS change scores were compared using the unpaired t-test. A significantly higher proportion of patients treated with particulate steroids were improved at 1 week (43.2 % vs. 27.7 %, p = 0.001) and at 1 month (44.3 % vs. 33.1 %, p = 0.019). Patients receiving particulate steroids also had significantly higher NRS change scores at 1 week (p = 0.02) and 1 month (p = 0.007). Particulate corticosteroids have significantly better outcomes than non-particulate corticosteroids. (orig.)

  10. Estimates of Particulate Mass in Multi-Canister Overpacks

    International Nuclear Information System (INIS)

    SLOUGHTER, J.P.

    2000-01-01

    High, best estimate, and low values are developed for particulate inventories within MCO baskets that have been loaded with freshly cleaned fuel assemblies and scrap. These per-basket estimates are then applied to all anticipated MCO payload configurations to identify which configurations are bounding for each type of particulate. Finally the resulting bounding and nominal values for residual particulates are combined with corresponding values [from other documents] for particulates that may be generated by corrosion of exposed uranium after the fuel has been cleaned. The resulting rounded nominal estimate for a typical MCO after 40 years of storage is 8 kg. The estimate for a bounding total particulate case MCO is that it may contain up to 64 kg of particulate after 40 years of storage

  11. Estimates of particulate mass in multi-canister overpacks

    International Nuclear Information System (INIS)

    SLOUGHTER, J.P.

    1999-01-01

    High, best estimate, and low values are developed for particulate inventories within MCO baskets that have been loaded with freshly cleaned fuel assemblies and scrap. These per-basket estimates are then applied to all anticipated MCO payload configurations to identify which configurations are bounding for each type of particulate. Finally the resulting bounding and nominal values for residual particulates are combined with corresponding values [from other documents] for particulate that may be generated by corrosion of exposed uranium after the fuel has been cleaned. The resulting rounded nominal estimate for a typical MCO after 40 years of storage is 8 kg. The estimate for a bounding total particulate case MCO is that it may contain up to 64 kg of particulate after 40 years of storage

  12. Estimates of particulate mass in multi-canister overpacks

    Energy Technology Data Exchange (ETDEWEB)

    SLOUGHTER, J.P.

    1999-02-25

    High, best estimate, and low values are developed for particulate inventories within MCO baskets that have been loaded with freshly cleaned fuel assemblies and scrap. These per-basket estimates are then applied to all anticipated MCO payload configurations to identify which configurations are bounding for each type of particulate. Finally the resulting bounding and nominal values for residual particulates are combined with corresponding values [from other documents] for particulate that may be generated by corrosion of exposed uranium after the fuel has been cleaned. The resulting rounded nominal estimate for a typical MCO after 40 years of storage is 8 kg. The estimate for a bounding total particulate case MCO is that it may contain up to 64 kg of particulate after 40 years of storage.

  13. Analysis of atmospheric particulate samples via instrumental neutron activation analysis

    International Nuclear Information System (INIS)

    Greenberg, R.R.

    1990-01-01

    Instrumental neutron activation analysis (INAA) is a powerful analytical technique for the elemental characterization of atmospheric particulate samples. It is a true multielement technique with adequate sensitivity to determine 30 to 40 elements in a sample of atmospheric particulate material. Its nondestructive nature allows sample reanalysis by the same or a different analytical technique. In this paper as an example of the applicability of INAA to the study of atmospheric particulate material, a study of the emissions from municipal incinerators is described

  14. In situ formation of ZrB2 particulates and their influence on microstructure and tensile behavior of AA7075 aluminum matrix composites

    Directory of Open Access Journals (Sweden)

    J. David Raja Selvam

    2017-02-01

    Full Text Available In situ synthesis of aluminum matrix composites (AMCs has become a popular method due to several advantages over conventional stir casting method. In the present study, AA7075/ZrB2 AMCs reinforced with various content of ZrB2 particulates (0, 3, 6, 9 and 12 wt.% were synthesized by the in situ reaction of molten aluminum with inorganic salts K2ZrF6 and KBF4. The composites were characterized using XRD, OM, SEM, EBSD and TEM. The XRD patterns revealed the formation of ZrB2 particulates without the presence of any other compounds. The formation of ZrB2 particulates refined the grains of aluminum matrix extensively. Most of the ZrB2 particulates were located near the grain boundaries. The ZrB2 particulates exhibited various morphologies including spherical, cylindrical and hexagonal shapes. The size of the ZrB2 particulates was in the order of nano, sub micron and micron level. A good interfacial bonding was observed between the aluminum matrix and the ZrB2 particulates. The in situ formed ZrB2 particulates enhanced the mechanical properties such as microhardness and the ultimate tensile strength. Various strengthening mechanisms were identified.

  15. Relationship between Particulate matter less than 10 microns exposures and health effects on humans in Ahvaz, Iran

    Directory of Open Access Journals (Sweden)

    Sahar Geravandi

    2015-06-01

    Full Text Available Background & Aims of the Study: Particulate matters less than 10 microns can absorb into your lungs and reacting with the moisture and enter the circulatory system directly through the airways. The aim of this study is to assess Behavior PM 10 data in different seasons and Determination effects on human health in Ahvaz city during 2013. Materials & Methods: Data Particulate matters less than 10 microns were taken from Ahvaz Department of Environment and Meteorological Organization. Sampling was performed for 24 hours in 4 stations. Method of sampling and analysis were performed according to EPA guideline. Processing data include the instruction set correction of averaging, coding and filtering. Finally, health-effects of Particulate matters less than 10 exposures were calculated with impact of meteorological parameters and converted as input file to the Air Q model. Results: PM 10 concentration in winter season was maximum amount in the year 2013. According to the research findings, highest and the lowest Particulate matters less than 10 microns concentrations during 2013 had the Bureau of Meteorology “Havashenasi” and Head office of ADoE “Mohitzist”. Sum of total numbers of cardiovascular death and hospitals admission to respiratory diseases attributed to Particulate matters less than 10 microns were 923 and 2342 cases in 2013. Conclusions: Particulate matter emissions are highly regulated in most industrialized countries. Due to environmental concerns, most industries and dust storm phenomena are required to decrease in source produce particle mater and kind of dust collection system to control particulate emissions. Pollution prevention and control measures that reduce Particulate matters less than 10 microns can very useful for expected to reduce people’s exposures to Sulfur dioxide.

  16. Particulate matter and neutron activation analysis

    International Nuclear Information System (INIS)

    Otoshi, Tsunehiko

    2003-01-01

    In these years, economy of East Asian region is rapidly growing, and countries in this region are facing serious environmental problems. Neutron activation analysis is known as one of high-sensitive analytical method for multi elements. And it is a useful tool for environmental research, particularly for the study on atmospheric particulate matter that consists of various constituents. Elemental concentration represents status of air, such as emission of heavy metals from industries and municipal incinerators, transportation of soil derived elements more than thousands of kilometers, and so on. These monitoring data obtained by neutron activation analysis can be a cue to evaluate environment problems. Japanese government launched National Air Surveillance Network (NASN) employing neutron activation analysis in 1974, and the data has been accumulated at about twenty sampling sites. As a result of mitigation measure of air pollution sources, concentrations of elements that have anthropogenic sources decreased particularly at the beginning of the monitoring period. However, even now, concentrations of these anthropogenic elements reflect the characteristics of each sampling site, e.g. industrial/urban, rural, and remote. Soil derived elements have a seasonal variation because of the contribution of continental dust transported by strong westerly winds prevailing in winter and spring season. The health effects associated with trace elements in particulate matter have not been well characterized. However, there is increasing evidence that particulate air pollution, especially fine portion of particles in many different cities is associated with acute mortality. Neutron activation analysis is also expected to provide useful information to this new study field related to human exposures and health risk. (author)

  17. Next Generation Non-particulate Dry Nonwoven Pad for Chemical Warfare Agent Decontamination

    Energy Technology Data Exchange (ETDEWEB)

    Ramkumar, S S; Love, A; Sata, U R; Koester, C J; Smith, W J; Keating, G A; Hobbs, L; Cox, S B; Lagna, W M; Kendall, R J

    2008-05-01

    New, non-particulate decontamination materials promise to reduce both military and civilian casualties by enabling individuals to decontaminate themselves and their equipment within minutes of exposure to chemical warfare agents or other toxic materials. One of the most promising new materials has been developed using a needlepunching nonwoven process to construct a novel and non-particulate composite fabric of multiple layers, including an inner layer of activated carbon fabric, which is well-suited for the decontamination of both personnel and equipment. This paper describes the development of a composite nonwoven pad and compares efficacy test results for this pad with results from testing other decontamination systems. The efficacy of the dry nonwoven fabric pad was demonstrated specifically for decontamination of the chemical warfare blister agent bis(2-chloroethyl)sulfide (H or sulfur mustard). GC/MS results indicate that the composite fabric was capable of significantly reducing the vapor hazard from mustard liquid absorbed into the nonwoven dry fabric pad. The mustard adsorption efficiency of the nonwoven pad was significantly higher than particulate activated carbon (p=0.041) and was similar to the currently fielded US military M291 kit (p=0.952). The nonwoven pad has several advantages over other materials, especially its non-particulate, yet flexible, construction. This composite fabric was also shown to be chemically compatible with potential toxic and hazardous liquids, which span a range of hydrophilic and hydrophobic chemicals, including a concentrated acid, an organic solvent and a mild oxidant, bleach.

  18. Activation analysis of air particulate matter

    International Nuclear Information System (INIS)

    Alian, A.; Sansoni, B.

    1988-11-01

    This review on activation analysis of air particulate matter is an extended and updated version of a review given by the same authors in 1985. The main part is aimed at the analytical scheme and refers to rules and techniques for sampling, sample and standard preparation, irradiation and counting procedures, as well as data processing, - evaluation, and - presentation. Additional chapters deal with relative and monostandard methods, the use of activation analysis for atmosphere samples in various localities, and level of toxic and other elements in the atmosphere. The review contains 190 references. (RB)

  19. Neutron Imaging of Diesel Particulate Filters

    International Nuclear Information System (INIS)

    Strzelec, Andrea; Bilheux, Hassina Z.; Finney, Charles E.A.; Daw, C. Stuart; Foster, Dave; Rutland, Christopher J.; Schillinger, Burkhard; Schulz, Michael

    2009-01-01

    This article presents nondestructive neutron computed tomography (nCT) measurements of Diesel Particulate Filters (DPFs) as a method to measure ash and soot loading in the filters. Uncatalyzed and unwashcoated 200cpsi cordierite DPFs exposed to 100% biodiesel (B100) exhaust and conventional ultra low sulfur 2007 certification diesel (ULSD) exhaust at one speed-load point (1500rpm, 2.6bar BMEP) are compared to a brand new (never exposed) filter. Precise structural information about the substrate as well as an attempt to quantify soot and ash loading in the channel of the DPF illustrates the potential strength of the neutron imaging technique

  20. Atmospheric particulate pollution in Kenitra (Morocco)

    International Nuclear Information System (INIS)

    Zghaid, Mustapha; Noack, Yves; Boukla, Moussa; Benyaich, Fouad

    2009-01-01

    Cities of Morocco are exposed to a high atmospheric particulate pollution due to automobile traffic, industrialization, but also to soil dusts (in relation with aridity and desert proximity). Monitoring networks and data about air pollution still rare. The present study is a preliminary work about particulate and heavy metals pollution in Kenitra city. Aerosols had been collected with a PM10 sampler (Partisol), a dichotomous sampler (P M2.5 and P M2.5-10 fractions) and stacked filter unit (Gent type) with a fine fraction (below 2.5 um) and a coarse fraction. In summer, the average PM10 concentration is near 80 u g/N m 3 , above the EEC rule and OMS recommendations, but similar to some other african towns. The ratio P M2.5/PM 10 is low (below 0.5), with seasonal variation in relation with meteorology. The lead and nickel concentrations are also very low, in relation with the use of leaded gasoline and the oldness of many vehicles. This preliminary work reveals high levels of pollution (especially PM10, Pb and Ni) in the town of Kenitra. The major sources are traffic, soil dusts and resuspension of deposited particles. It is necessary to develop monitoring network and sanitary and and environmental impact studies in these cities [fr

  1. Vale nails down reduction of diesel particulate

    Energy Technology Data Exchange (ETDEWEB)

    Larmour, A.

    2010-09-01

    This article discussed innovations for reducing emissions of diesel particulate matter (DPM) from light-duty underground vehicles. DPM is a byproduct of diesel-powered equipment. Controlling these emissions at the source of generation is necessary for a healthy work environment and more cost effective than fresh air ventilation to reduce contaminant concentrations. Previous diesel particulate filter (DPF) systems required extensive human intervention, but this was deemed too inefficient. A DPF system that does not require human intervention was developed and proved successful in filter regeneration, longevity, and reliability. This DPF system uses a sintered metal filter element, a base metal, fuel-borne catalyst with an on-board dosing system, an electric heater that uses on-board power, and a sensor-based control unit. Software in the control unit adjusts fuel dosing rates and heater timing to ensure filter regeneration for different engines and operating scenarios. The new filter system is robust, and it has a compact design and long service-intervals. The product is still being tested to determine the costs and service life of the filter. More testing on fuel additives was deemed to be warranted, as was designing filter elements for larger engines used in heavy-duty vehicles.

  2. Factors influencing particulate lipid production in the East Atlantic Ocean

    Science.gov (United States)

    Gašparović, B.; Frka, S.; Koch, B. P.; Zhu, Z. Y.; Bracher, A.; Lechtenfeld, O. J.; Neogi, S. B.; Lara, R. J.; Kattner, G.

    2014-07-01

    Extensive analyses of particulate lipids and lipid classes were conducted to gain insight into lipid production and related factors along the biogeochemical provinces of the Eastern Atlantic Ocean. Data are supported by particulate organic carbon (POC), chlorophyll a (Chl a), phaeopigments, Chl a concentrations and carbon content of eukaryotic micro-, nano- and picophytoplankton, including cell abundances for the latter two and for cyanobacteria and prokaryotic heterotrophs. We focused on the productive ocean surface (2 m depth and deep Chl a maximum (DCM). Samples from the deep ocean provided information about the relative reactivity and preservation potential of particular lipid classes. Surface and DCM particulate lipid concentrations (3.5-29.4 μg L-1) were higher than in samples from deep waters (3.2-9.3 μg L-1) where an increased contribution to the POC pool was observed. The highest lipid concentrations were measured in high latitude temperate waters and in the North Atlantic Tropical Gyral Province (13-25°N). Factors responsible for the enhanced lipid synthesis in the eastern Atlantic appeared to be phytoplankton size (micro, nano, pico) and the low nutrient status with microphytoplankton having the most expressed influence in the surface and eukaryotic nano- and picophytoplankton in the DCM layer. Higher lipid to Chl a ratios suggest enhanced lipid biosynthesis in the nutrient poorer regions. The various lipid classes pointed to possible mechanisms of phytoplankton adaptation to the nutritional conditions. Thus, it is likely that adaptation comprises the replacement of membrane phospholipids by non-phosphorus containing glycolipids under low phosphorus conditions. The qualitative and quantitative lipid compositions revealed that phospholipids were the most degradable lipids, and their occurrence decreased with increasing depth. In contrast, wax esters, possibly originating from zooplankton, survived downward transport probably due to the fast sinking

  3. Air Quality Standards for Particulate Matter (PM) at high altitude cities

    International Nuclear Information System (INIS)

    Bravo Alvarez, H.; Sosa Echeverria, R.; Sanchez Alvarez, P.; Krupa, S.

    2013-01-01

    The Air Quality Standards for Particulate Matter (PM) at high altitude urban areas in different countries, must consider the pressure and temperature due to the effect that these parameters have on the breath volume. This paper shows the importance to correct Air Quality Standards for PM considering pressure and temperature at different altitudes. Specific factors were suggested to convert the information concerning PM, from local to standard conditions, and adjust the Air Quality Standards for different high altitudes cities. The correction factors ranged from: 1.03 for Santiago de Chile to 1.47 for El Alto Bolivia. Other cities in this study include: Mexico City, México; La Paz, Bolivia; Bogota, Cali and Medellin, Colombia; Quito, Ecuador and Cuzco, Peru. If these corrections are not considered, the atmospheric concentrations will be underestimated. - Highlights: ► AQS for particulate matter concentrations adjusted by pressure and temperature. ► Particulate matter concentrations can be underestimated in high altitude Cities. ► Particulate matter concentrations must be compared under the same conditions. - In order to compare high altitude atmospheric PM concentrations with AQS, one must consider T and P of the sampling site.

  4. Characterization of airborne and bulk particulate from iron and steel manufacturing facilities.

    Science.gov (United States)

    Machemer, Steven D

    2004-01-15

    Characterization of airborne and bulk particulate material from iron and steel manufacturing facilities, commonly referred to as kish, indicated graphite flakes and graphite flakes associated with spherical iron oxide particles were unique particle characteristics useful in identifying particle emissions from iron and steel manufacturing. Characterization of airborne particulate material collected in receptor areas was consistent with multiple atmospheric release events of kish particles from the local iron and steel facilities into neighboring residential areas. Kish particles deposited in nearby residential areas included an abundance of graphite flakes, tens of micrometers to millimeters in size, and spherical iron oxide particles, submicrometer to tens of micrometers in size. Bulk kish from local iron and steel facilities contained an abundance of similar particles. Approximately 60% of blast furnace kish by volume consisted of spherical iron oxide particles in the respirable size range. Basic oxygen furnace kish contained percent levels of strongly alkaline components such as calcium hydroxide. In addition, concentrations of respirable Mn in airborne particulate in residential areas and at local iron and steel facilities were approximately 1.6 and 53 times the inhalation reference concentration of 0.05 microg/m3 for chronic inhalation exposure of Mn, respectively. Thus, airborne release of kish may pose potential respirable particulate, corrosive, or toxic hazards for human health and/or a corrosive hazard for property and the environment.

  5. Impact of maritime traffic on polycyclic aromatic hydrocarbons, metals and particulate matter in Venice air.

    Science.gov (United States)

    Gregoris, Elena; Barbaro, Elena; Morabito, Elisa; Toscano, Giuseppa; Donateo, Antonio; Cesari, Daniela; Contini, Daniele; Gambaro, Andrea

    2016-04-01

    Harbours are important hubs for economic growth in both tourism and commercial activities. They are also an environmental burden being a source of atmospheric pollution often localized near cities and industrial complexes. The aim of this study is to quantify the relative contribution of maritime traffic and harbour activities to atmospheric pollutant concentration in the Venice lagoon. The impact of ship traffic was quantified on various pollutants that are not directly included in the current European legislation for shipping emission reduction: (i) gaseous and particulate PAHs; (ii) metals in PM10; and (iii) PM10 and PM2.5. All contributions were correlated with the tonnage of ships during the sampling periods and results were used to evaluate the impact of the European Directive 2005/33/EC on air quality in Venice comparing measurements taken before and after the application of the Directive (year 2010). The outcomes suggest that legislation on ship traffic, which focused on the issue of the emissions of sulphur oxides, could be an efficient method also to reduce the impact of shipping on primary particulate matter concentration; on the other hand, we did not observe a significant reduction in the contribution of ship traffic and harbour activities to particulate PAHs and metals. Graphical abstract Impact of maritime traffic on polycyclic aromatic hydrocarbons, metals and particulate matter and evaluation of the effect of an European Directive on air quality in Venice.

  6. Effect of Particulate Matter Mineral Composition on Environmentally Persistent Free Radical (EPFR) Formation.

    Science.gov (United States)

    Feld-Cook, Elisabeth E; Bovenkamp-Langlois, Lisa; Lomnicki, Slawo M

    2017-09-19

    Environmentally Persistent Free Radicals (EPFRs) are newly discovered, long-lived surface bound radicals that form on particulate matter and combustion borne particulates, such as fly ash. Human exposure to such particulates lead to translocation into the lungs and heart resulting in cardio-vascular and respiratory disease through the production of reactive oxygen species. Analysis of some waste incinerator fly ashes revealed a significant difference between their EPFR contents. Although EPFR formation occurs on the metal domains, these differences were correlated with the altering concentration of calcium and sulfur. To analyze these phenomena, surrogate fly ashes were synthesized to mimic the presence of their major mineral components, including metal oxides, calcium, and sulfur. The results of this study led to the conclusion that the presence of sulfates limits formation of EPFRs due to inhibition or poisoning of the transition metal active sites necessary for their formation. These findings provide a pathway toward understanding differences in EPFR presence on particulate matter and uncover the possibility of remediating EPFRs from incineration and hazardous waste sites.

  7. Characterization and cytotoxic assessment of ballistic aerosol particulates for tungsten alloy penetrators into steel target plates.

    Science.gov (United States)

    Machado, Brenda I; Murr, Lawrence E; Suro, Raquel M; Gaytan, Sara M; Ramirez, Diana A; Garza, Kristine M; Schuster, Brian E

    2010-09-01

    The nature and constituents of ballistic aerosol created by kinetic energy penetrator rods of tungsten heavy alloys (W-Fe-Ni and W-Fe-Co) perforating steel target plates was characterized by scanning and transmission electron microscopy. These aerosol regimes, which can occur in closed, armored military vehicle penetration, are of concern for potential health effects, especially as a consequence of being inhaled. In a controlled volume containing 10 equispaced steel target plates, particulates were systematically collected onto special filters. Filter collections were examined by scanning and transmission electron microscopy (SEM and TEM) which included energy-dispersive (X-ray) spectrometry (EDS). Dark-field TEM identified a significant nanoparticle concentration while EDS in the SEM identified the propensity of mass fraction particulates to consist of Fe and FeO, representing target erosion and formation of an accumulating debris field. Direct exposure of human epithelial cells (A549), a model for lung tissue, to particulates (especially nanoparticulates) collected on individual filters demonstrated induction of rapid and global cell death to the extent that production of inflammatory cytokines was entirely inhibited. These observations along with comparisons of a wide range of other nanoparticulate species exhibiting cell death in A549 culture may suggest severe human toxicity potential for inhaled ballistic aerosol, but the complexity of the aerosol (particulate) mix has not yet allowed any particular chemical composition to be identified.

  8. Characterization and Cytotoxic Assessment of Ballistic Aerosol Particulates for Tungsten Alloy Penetrators into Steel Target Plates

    Directory of Open Access Journals (Sweden)

    Brian E. Schuster

    2010-08-01

    Full Text Available The nature and constituents of ballistic aerosol created by kinetic energy penetrator rods of tungsten heavy alloys (W-Fe-Ni and W-Fe-Co perforating steel target plates was characterized by scanning and transmission electron microscopy. These aerosol regimes, which can occur in closed, armored military vehicle penetration, are of concern for potential health effects, especially as a consequence of being inhaled. In a controlled volume containing 10 equispaced steel target plates, particulates were systematically collected onto special filters. Filter collections were examined by scanning and transmission electron microscopy (SEM and TEM which included energy-dispersive (X-ray spectrometry (EDS. Dark-field TEM identified a significant nanoparticle concentration while EDS in the SEM identified the propensity of mass fraction particulates to consist of Fe and FeO, representing target erosion and formation of an accumulating debris field. Direct exposure of human epithelial cells (A549, a model for lung tissue, to particulates (especially nanoparticulates collected on individual filters demonstrated induction of rapid and global cell death to the extent that production of inflammatory cytokines was entirely inhibited. These observations along with comparisons of a wide range of other nanoparticulate species exhibiting cell death in A549 culture may suggest severe human toxicity potential for inhaled ballistic aerosol, but the complexity of the aerosol (particulate mix has not yet allowed any particular chemical composition to be identified.

  9. Composition of diesel exhaust with particular reference to particle bound organics including formation of artifacts.

    Science.gov (United States)

    Lies, K H; Hartung, A; Postulka, A; Gring, H; Schulze, J

    1986-01-01

    For particulate emissions, standards were established by the US EPA in February 1980. Regulations limiting particulates from new light duty diesel vehicles are valid by model year 1982. The corresponding standards on a pure mass basis do not take into account any chemical character of the diesel particulate matter. Our investigation of the material composition shows that diesel particulates consist mainly of soot (up to 80% by weight) and adsorptively bound organics including polycyclic aromatic hydrocarbons (PAH). The qualitative and quantitative nature of hydrocarbon compounds associated with the particulates is dependent not only on the combustion parameters of the engine but also to an important degree on the sampling conditions when the particulates are collected (dilution ratio, temperature, filter material, sampling time etc.). Various methods for the analyses of PAH and their oxy- and nitro-derivatives are described including sampling, extraction, fractionation and chemical analysis. Quantitative comparison of PAH, nitro-PAH and oxy-PAH from different engines are given. For assessing mutagenicity of particulate matter, short-term biological tests are widely used. These biological tests often need a great amount of particulate matter requiring prolonged filter sampling times. Since it is well known that facile PAH oxidation can take place under the conditions used for sampling and analysis, the question rises if these PAH-derivates found in particle extracts partly or totally are produced during sampling (artifacts). Various results concerning nitro- and oxy-PAH are presented characterizing artifact formation as a minor problem under the conditions of the Federal Test Procedure. But results show that under other sampling conditions, e.g. electrostatic precipitation, higher NO2-concentrations and longer sampling times, artifact formation can become a bigger problem. The more stringent particulate standard of 0.2 g/mi for model years 1986 and 1987 respectively

  10. 40 CFR 86.1343-88 - Calculations; particulate exhaust emissions.

    Science.gov (United States)

    2010-07-01

    ... determined from the following equation: er31au93.070 (1) Pmass = Mass of particulate emitted per test phase... (cubic meters) per revolution. This volume is dependent on the pressure differential across the positive... be applied before Vsf is determined. (4) Pf = Mass of particulate on the sample filter (or sample and...

  11. Process for off-gas particulate removal and apparatus therefor

    International Nuclear Information System (INIS)

    Carl, D.E.

    1997-01-01

    In the event of a breach in the off-gas line of a melter operation requiring closure of the line, a secondary vessel vent line is provided with a particulate collector utilizing atomization for removal of large particulates from the off-gas. The collector receives the gas containing particulates and directs a portion of the gas through outer and inner annular channels. The collector further receives a fluid, such as water, which is directed through the outer channel together with a second portion of the particulate-laden gas. The outer and inner channels have respective ring-like termination apertures concentrically disposed adjacent one another on the outer edge of the downstream side of the particulate collector. Each of the outer and inner channels curves outwardly away from the collector's centerline in proceeding toward the downstream side of the collector. Gas flow in the outer channel maintains the fluid on the channel's wall in the form of a ''wavy film,'' while the gas stream from the inner channel shears the fluid film as it exits the outer channel in reducing the fluid to small droplets. Droplets formed by the collector capture particulates in the gas stream by one of three mechanisms: impaction, interception or Brownian diffusion in removing the particulates. The particulate-laden droplets are removed from the fluid stream by a vessel vent condenser or mist eliminator. 4 figs

  12. Method for immobilizing particulate materials in a packed bed

    Science.gov (United States)

    Even, Jr., William R.; Guthrie, Stephen E.; Raber, Thomas N.; Wally, Karl; Whinnery, LeRoy L.; Zifer, Thomas

    1999-01-01

    The present invention pertains generally to immobilizing particulate matter contained in a "packed" bed reactor so as to prevent powder migration, compaction, coalescence, or the like. More specifically, this invention relates to a technique for immobilizing particulate materials using a microporous foam-like polymer such that a) the particulate retains its essential chemical nature, b) the local movement of the particulate particles is not unduly restricted, c) bulk powder migration and is prevented, d) physical and chemical access to the particulate is unchanged over time, and e) very high particulate densities are achieved. The immobilized bed of the present invention comprises a vessel for holding particulate matter, inlet and an outlet ports or fittings, a loosely packed bed of particulate material contained within the vessel, and a three dimensional porous matrix for surrounding and confining the particles thereby fixing the movement of individual particle to a limited local position. The established matrix is composed of a series of cells or chambers comprising walls surrounding void space, each wall forming the wall of an adjacent cell; each wall containing many holes penetrating through the wall yielding an overall porous structure and allowing useful levels of gas transport.

  13. The investigation of atmospheric particulate matter pollution in Suzhou

    International Nuclear Information System (INIS)

    Chen Yi'ou; Zhang Yuliang; Wang Ya; Wang Pei; Tian Hailin

    2012-01-01

    Objective: To investigate the pollution status, vertical distribution and concentration variation within 24 hours of total suspended particles (TSPs), particulate matter ≤10 μm (PM10), particulate matter ≤5 (PM5) and particulate matter ≤2.5 μm (PM2.5) in major functional areas of Suzhou and the protective effect of different type masks on particulate matter. Methods: (1) The concentration of atmospheric TSPs, PM10, PM5 and PM2.5 in seven functional areas in Suzhou was monitored for three consecutive days. (2) A residential building of 25 stories was chosen and the concentration of TSPs, PM10, PM5, PM2.5 was detected at the 1st, 5th, 10th, 15th, 20 th and the 25th floor respectively. (3) The concentrations of the four particulate matter were detected every two-hours for three consecutive days to investigate how concentration of particulate matter varies within 24 hours. (4) The concentration of the four kinds of particulate matter was analyzed with the sampling head of monitor wrapped with disposable non-woven medical mask, fashion-type mask, gauze mask or activated carbon anti-dust mask respectively, and the protective effect of the four masks on particulate matter was compared. Results: (1) The concentration of PM2.5 was higher than the national health limit in all seven functional areas in Suzhou. (2) No significant difference in vertical distribution of particulate matter was found among different floors in residential buildings (P>0.05). (3) Two small peaks of particulate matter appeared in the morning and evening respectively while the top appeared at dawn (P< 0.05). (4) Disposable non-woven medical mask showed the best protective effect on particulate matter among the four tested masks. Conclusion: PM2.5 is the main particulate matter in Suzhou area. In addition the 4 kinds of particulate matter: TSP, PM10, PM5 and PM2.5 are of higher concentration in the early morning. No significant difference was detected from an altitude of less than 75 meters

  14. Trace elemental analysis of the aerosol particulates in northern Punjab

    International Nuclear Information System (INIS)

    Iqbal, M.Z.

    2002-01-01

    Trace elemental analysis of the aerosol particulates was studied in the atmosphere of Lahore, Faisalabad, Islamabad, Sheikhupura, Wah Cantt. And Khanispur. The amount of the aerosol particulates in the above mentioned areas was compared to the U.S. EPA maximum permissible limits. Scavenging mechanism of the aerosol particulates through precipitation was studied in the atmosphere of Lahore and Sheikhupura by using HPLC and ICP-AES techniques. The site distribution and morphological structure of the aerosol particulates was studied by using Scanning Electron Microscope model JSM-35CF. Trace elemental composition of the aerosol particulates in the atmosphere of the selected areas of Pakistan was carried out by using NAA. The elements thus studied were Ce, Yb, Se, Cr, Hf, Cs, Sc, Fe, Co, Eu, Sb, Mo, Ba, Zn, Hg, Br, Na, Gd, Sm, Nd and In while Pb and Cd were estimated by using ASS technique. (author)

  15. Particulate hot gas stream cleanup technical issues

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-09-01

    This is the tenth in a series of quarterly reports describing the activities performed under Contract No. DE-AC21-94MC31160. Analyses of Hot Gas Stream Cleanup (HGCU) ashes and descriptions of filter performance address aspects of filter operation that are apparently linked to the characteristics of the collected ash or the performance of the ceramic bed filter elements. Task I is designed to generate a data base of the key characteristics of ashes collected from operating advanced particle filters (APFS) and to relate these ash properties to the operation and performance of these filters. Task 2 concerns testing and failure analysis of ceramic filter elements. Under Task I during the past quarter, analyses were performed on a particulate sample from the Transport Reactor Demonstration Unit (TRDU) located at the University of North Dakota Energy and Environmental Research Center. Analyses are in progress on ash samples from the Advanced Particulate Filter (APF) at the Pressurized Fluidized-Bed Combustor (PFBC) that was in operation at Tidd and ash samples from the Pressurized Circulating Fluid Bed (PCFB) system located at Karhula, Finland. A site visit was made to the Power Systems Development Facility (PSDF) to collect ash samples from the filter vessel and to document the condition of the filter vessel with still photographs and videotape. Particulate samples obtained during this visit are currently being analyzed for entry into the Hot Gas Cleanup (HGCU) data base. Preparations are being made for a review meeting on ash bridging to be held at Department of Energy Federal Energy Technology Center - Morgantown (DOE/FETC-MGN) in the near future. Most work on Task 2 was on hold pending receipt of additional funds; however, creep testing of Schumacher FT20 continued. The creep tests on Schumacher FT20 specimens just recently ended and data analysis and comparisons to other data are ongoing. A summary and analysis of these creep results will be sent out shortly. Creep

  16. Particulate matter emissions of different brands of mentholated cigarettes.

    Science.gov (United States)

    Gerharz, Julia; Bendels, Michael H K; Braun, Markus; Klingelhöfer, Doris; Groneberg, David A; Mueller, Ruth

    2018-01-09

    Inhaling particulate matter (PM) in environmental tobacco smoke (ETS) endangers the health of nonsmokers. Menthol, an additive in cigarettes, attenuates respiratory irritation of tobacco smoke. It reduces perceptibility of smoke and therefore passive smokers may inhale ETS unnoticed. To investigate a possible effect of menthol on PM concentrations (PM 10 , PM 2.5 , and PM 1 ), ETS of four mentholated cigarette brands (Elixyr Menthol, Winston Menthol, Reyno Classic, and Pall Mall Menthol Blast) with varying menthol content was analyzed. ETS was generated in a standardized way using an automatic environmental tobacco smoke emitter (AETSE), followed by laser aerosol spectrometry. This analysis shows that the tested cigarette brands, despite having different menthol concentrations, do not show differences with regard to PM emissions, with the exception of Reyno Classic, which shows an increased emission, although the menthol level ranged in the midfield. More than 90% of the emitted particles had a size smaller than or equal to 1 µm. Regardless of the menthol level, the count median diameter (CMD) and the mass median diameter (MMD) were found to be 0.3 µm and 0.5 µm, respectively. These results point out that there is no effect of menthol on PM emission and that other additives might influence the increased PM emission of Reyno Classic. Particulate matter (PM) in ETS endangers the health of nonsmokers and smokers. This study considers the effect of menthol, an additive in cigarettes, on PM emissions. Does menthol increase the amount of PM? Due to the exposure to secondhand smoke nearly 900,000 people die each year worldwide. The aim of the study is to measure the particle concentration (L -1 ), mass concentration (µg m -3 ), and dust mass fractions shown as PM 10 , PM 2.5 , and PM 1 of five different cigarette brands, including four with different menthol concentrations and one menthol-free reference cigarette, in a well-established standardized system.

  17. Establishing aeolian particulate 'fingerprints' in an airport environment using magnetic measurements and SEM/EDAX

    Science.gov (United States)

    Jones, Sue; Hoon, Stephen R.; Richardson, Nigel; Bennett, Michael

    2016-04-01

    The significant increase in global air travel which has occurred during the last fifty years has generated growing concern regarding the potential impacts associated with increasing emissions of particulate matter (PM) from aviation activity on health and the environment. PM within the airport environment, in particular, may be derived from a wide range of potential sources including aircraft; vehicles; ground support equipment and buildings. In order to investigate and remediate potential problem sources, it is important to be able to identify characteristic particulate 'fingerprints' which would allow source attribution, particularly respirable particulates. To date the identification of such 'fingerprints' has remained elusive but remains a key research priority for the aviation industry (Webb et al, 2008). In previous PM studies, environmental magnetism has been used as a successful technique for discriminating between different emission types and particulate sources in both urban and industrial environments (e.g. Hunt et al 1984; Lecoanet et al 2003, Jones et al 2015). Environmental magnetism is a non-destructive and relatively rapid technique involving the use of non-directional, rock magnetic measurements to characterise the mineral magnetic properties of natural and anthropogenic materials. In other studies scanning electron microscopy (SEM) has also been used as an effective characterisation technique for the investigation of grain size and morphology of PM derived from vehicle emissions (e.g. Bucko et al 2010) and fossil fuel combustion sources (Kim et al 2009). In this study, environmental magnetic measurements and SEM/EDAX have been used to characterise dusts from specific aircraft sources including engines, brakes and tyres. Furthermore, these methods have also been applied to runway (both hard and grass covered surfaces), taxiway and apron dusts collected during extensive environmental sampling at Manchester International Airport, UK in order to

  18. Exposure to particulate hexavalent chromium exacerbates allergic asthma pathology

    International Nuclear Information System (INIS)

    Schneider, Brent C.; Constant, Stephanie L.; Patierno, Steven R.; Jurjus, Rosalyn A.; Ceryak, Susan M.

    2012-01-01

    Airborne hexavalent chromate, Cr(VI), has been identified by the Environmental Protection Agency as a possible health threat in urban areas, due to the carcinogenic potential of some of its forms. Particulate chromates are produced in many different industrial settings, with high levels of aerosolized forms historically documented. Along with an increased risk of lung cancer, a high incidence of allergic asthma has been reported in workers exposed to certain inhaled particulate Cr(VI) compounds. However, a direct causal association between Cr(VI) and allergic asthma has not been established. We recently showed that inhaled particulate Cr(VI) induces an innate neutrophilic inflammatory response in BALB/c mice. In the current studies we investigated how the inflammation induced by inhaled particulate Cr(VI) might alter the pathology of an allergic asthmatic response. We used a well-established mouse model of allergic asthma. Groups of ovalbumin protein (OVA)-primed mice were challenged either with OVA alone, or with a combination of OVA and particulate zinc chromate, and various parameters associated with asthmatic responses were measured. Co-exposure to particulate Cr(VI) and OVA mediated a mixed form of asthma in which both eosinophils and neutrophils are present in airways, tissue pathology is markedly exacerbated, and airway hyperresponsiveness is significantly increased. Taken together these findings suggest that inhalation of particulate forms of Cr(VI) may augment the severity of ongoing allergic asthma, as well as alter its phenotype. Such findings may have implications for asthmatics in settings in which airborne particulate Cr(VI) compounds are present at high levels. -- Highlights: ► Allergic asthma correlated with exposure to certain inhaled particulate chromates. ► Direct causal association between Cr(VI) and allergic asthma not established. ► Cr exacerbated pathology and airway hyperresponsiveness in an OVA-challenged mouse. ► Particulate Cr

  19. Exposure to particulate hexavalent chromium exacerbates allergic asthma pathology

    Energy Technology Data Exchange (ETDEWEB)

    Schneider, Brent C. [Department of Microbiology, Immunology and Tropical Medicine, The George Washington University, Washington, DC 20037 (United States); Department of Pharmacology and Physiology, The George Washington University, Washington, DC 20037 (United States); Constant, Stephanie L. [Department of Microbiology, Immunology and Tropical Medicine, The George Washington University, Washington, DC 20037 (United States); Patierno, Steven R. [Department of Pharmacology and Physiology, The George Washington University, Washington, DC 20037 (United States); GW Cancer Institute, The George Washington University, Washington, DC 20037 (United States); Jurjus, Rosalyn A. [Department of Anatomy and Regenerative Biology, The George Washington University, Washington, DC 20037 (United States); Ceryak, Susan M., E-mail: phmsmc@gwumc.edu [Department of Pharmacology and Physiology, The George Washington University, Washington, DC 20037 (United States)

    2012-02-15

    Airborne hexavalent chromate, Cr(VI), has been identified by the Environmental Protection Agency as a possible health threat in urban areas, due to the carcinogenic potential of some of its forms. Particulate chromates are produced in many different industrial settings, with high levels of aerosolized forms historically documented. Along with an increased risk of lung cancer, a high incidence of allergic asthma has been reported in workers exposed to certain inhaled particulate Cr(VI) compounds. However, a direct causal association between Cr(VI) and allergic asthma has not been established. We recently showed that inhaled particulate Cr(VI) induces an innate neutrophilic inflammatory response in BALB/c mice. In the current studies we investigated how the inflammation induced by inhaled particulate Cr(VI) might alter the pathology of an allergic asthmatic response. We used a well-established mouse model of allergic asthma. Groups of ovalbumin protein (OVA)-primed mice were challenged either with OVA alone, or with a combination of OVA and particulate zinc chromate, and various parameters associated with asthmatic responses were measured. Co-exposure to particulate Cr(VI) and OVA mediated a mixed form of asthma in which both eosinophils and neutrophils are present in airways, tissue pathology is markedly exacerbated, and airway hyperresponsiveness is significantly increased. Taken together these findings suggest that inhalation of particulate forms of Cr(VI) may augment the severity of ongoing allergic asthma, as well as alter its phenotype. Such findings may have implications for asthmatics in settings in which airborne particulate Cr(VI) compounds are present at high levels. -- Highlights: ► Allergic asthma correlated with exposure to certain inhaled particulate chromates. ► Direct causal association between Cr(VI) and allergic asthma not established. ► Cr exacerbated pathology and airway hyperresponsiveness in an OVA-challenged mouse. ► Particulate Cr

  20. Is there a difference in treatment outcomes between epidural injections with particulate versus non-particulate steroids?

    Energy Technology Data Exchange (ETDEWEB)

    Bensler, Susanne; Sutter, Reto; Pfirrmann, Christian W.A.; Peterson, Cynthia K. [Orthopedic University Hospital Balgrist, Department of Radiology, Zurich (Switzerland); University of Zurich, Faculty of Medicine, Zurich (Switzerland)

    2017-04-15

    To compare the outcomes of patients after interlaminar computed tomography (CT)-guided epidural injections of the lumbar spine with particulate vs. non-particulate steroids. 531 consecutive patients were treated with CT-guided lumbar interlaminar epidural injections with steroids and local anaesthetics. 411 patients received a particulate steroid and 120 patients received a non-particulate steroid. Pain levels were assessed using the 11-point numerical rating scale (NRS) and overall reported 'improvement' was assessed using the Patients Global Impression of Change (PGIC) at 1 day, 1 week and 1 month post-injection. Descriptive and inferential statistics were applied. Patients receiving particulate steroids had statistically significantly higher NRS change scores (p = 0.0001 at 1 week; p = 0.0001 at 1 month). A significantly higher proportion of patients receiving particulate steroids reported relevant improvement (PGIC) at both 1 week and 1 month post injection (p = 0.0001) and they were significantly less likely to report worsening at 1 week (p = 0.0001) and 1 month (p = 0.017). Patients treated with particulate steroids had significantly greater pain relief and were much more likely to report clinically relevant overall 'improvement' at 1 week and 1 month compared to the patients treated with non-particulate steroids. (orig.)

  1. Is there a difference in treatment outcomes between epidural injections with particulate versus non-particulate steroids?

    International Nuclear Information System (INIS)

    Bensler, Susanne; Sutter, Reto; Pfirrmann, Christian W.A.; Peterson, Cynthia K.

    2017-01-01

    To compare the outcomes of patients after interlaminar computed tomography (CT)-guided epidural injections of the lumbar spine with particulate vs. non-particulate steroids. 531 consecutive patients were treated with CT-guided lumbar interlaminar epidural injections with steroids and local anaesthetics. 411 patients received a particulate steroid and 120 patients received a non-particulate steroid. Pain levels were assessed using the 11-point numerical rating scale (NRS) and overall reported 'improvement' was assessed using the Patients Global Impression of Change (PGIC) at 1 day, 1 week and 1 month post-injection. Descriptive and inferential statistics were applied. Patients receiving particulate steroids had statistically significantly higher NRS change scores (p = 0.0001 at 1 week; p = 0.0001 at 1 month). A significantly higher proportion of patients receiving particulate steroids reported relevant improvement (PGIC) at both 1 week and 1 month post injection (p = 0.0001) and they were significantly less likely to report worsening at 1 week (p = 0.0001) and 1 month (p = 0.017). Patients treated with particulate steroids had significantly greater pain relief and were much more likely to report clinically relevant overall 'improvement' at 1 week and 1 month compared to the patients treated with non-particulate steroids. (orig.)

  2. Ultra fine particulates. Small particulates with large consequences?; Ultrafijn stof. Kleine deeltjes met grote gevolgen?

    Energy Technology Data Exchange (ETDEWEB)

    Hensema, A.; Keuken, M.; Kooter, I.; Verbeek, R.; Van Vugt, M. [TNO Science and Industry, Delft (Netherlands)

    2009-02-15

    The concentrations of ultra fine particles (and elementary carbon) have increased significantly near traffic routes. The amount of ultra fine particles (and the chemical composition of particulate matter) are related to traffic emissions and are therefore relevant to the established health effects. Better insight in the effectiveness of particulate matter policy requires more attention for ultra fine particles than just maintaining the standards for PM2,5 and PM10. [mk]. [Dutch] De concentraties van ultrafijne deeltjes (en elementair koolstof) zijn fors verhoogd in de buurt van verkeerswegen. Het aantal ultrafijne deeltjes (en de chemische samenstelling van fijnstof) gerelateerd aan verkeersemissies lijkt daarom relevant voor de vastgestelde gezondheidseffecten. Voor een beter inzicht in de effectiviteit van het fijnstofbeleid is meer aandacht nodig voor ultrafijne deeltjes dan alleen handhaving van de normen voor PM2,5 en PM10.

  3. Particulate emissions from residential wood combustion

    DEFF Research Database (Denmark)

    Luis Teles de Carvalho, Ricardo; Jensen, Ole Michael; Tarelho, Luis A. C.

    Residential wood combustion (RWC) in fireplaces and conventional appliances is the main contributor to fine particulate matter (PM2.5) emissions in Denmark and Portugal representing more than 30% of the total emissions [1;2]. Such estimations are uncertain concerning the wood consumption...... and official emission factors, not taking into account actual burning conditions in dwellings [3]. There is limited knowledge on the real-life performance and spatial distribution of existing appliance types. Few studies have been targeting to understand the influence of fuel operation habits on PM2...... the available estimations for Denmark and Portugal, suggesting a methodology to increase the accuracy of activity data and emission factors. This work is based on new studies carried out to quantify the PM2.5 emissions in daily life through field experiments in Danish dwellings and by considering typical...

  4. Particulates in Europe; Fijn stof in Europa

    Energy Technology Data Exchange (ETDEWEB)

    Eeftens, M.; Brunekreef, B. [Institute for Risk Assessment Sciences IRAS, Utrecht University, Utrecht (Netherlands)

    2013-08-15

    Although the same air quality standards apply across Europe, there are large differences in concentration within, but also between countries. There are also differences between the methods that these countries use for regular monitoring networks, which makes a direct comparison of concentrations difficult. The ESCAPE project (European Study of Cohorts for Air Pollution Effects) mapped the differences in the European particulate concentrations using one unified measuring method [Dutch] Hoewel voor heel Europa dezelfde luchtkwaliteitsnormen gelden, bestaan er grote concentratieverschillen binnen, maar ook tussen landen. Ook zijn er verschillen tussen de meetmethoden die deze landen binnen reguliere meetnetten hanteren, wat een directe vergelijking van concentraties vaak moeilijk maakt. Het ESCAPE-project (European Study of Cohorts for Air Pollution Effects) bracht de Europese fijnstofcontrasten in kaart met behulp van 1 identieke meetmethode.

  5. Recent observations of particulates in Nitinol

    International Nuclear Information System (INIS)

    Shabalovskaya, S.; Anderegg, J.; Humbeeck, J. van

    2008-01-01

    In spite of 40 years of history of Nitinol, the issues regarding its inclusions have been poorly explored. In our brief studies, conducted within the projects on surface design using Auger, energy-dispersive X-ray spectroscopy and scanning electrons microscopy, we discovered that particulates in NiTi medical alloys were always based on Ti: either ∼Ti 2 NiO oxide, titanium dioxide, titanium carbide or oxidized titanium carbide. Nonmetallic particles were rather brittle, had various shapes and sizes, and revealed different solubility in chemical solutions. The matrix material surrounding inclusions showed a tendency to localized corrosion. It was hypothesized that release of inclusion debris in the human body due to corrosion might compromise biocompatibility of Nitinol

  6. Method for identifying particulate fluoride compounds

    Energy Technology Data Exchange (ETDEWEB)

    Tufts, B J

    1960-01-01

    A method is described for identifying particulates containing fluorides and other complex fluorine compounds such as fluorosilicate in samples collected on membrane filters. The filter is treated with lead chloride to precipitate lead chlorofluoride at each fluoride-containing spot. This microspot is identified by examination in a light microscope. Sulfate and phosphate, which also precipitate if present, can be distinguished and do not interfere. Calibrations are given for the fluorides and the more insoluble salts, relating the original particle size to the reaction site size. Thus, the mass of the particles can be calculated. Results of some field tests in an area of fluoride pollution are given, and compared with standard testing procedures.

  7. Lability of Secondary Organic Particulate Matter

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Pengfei; Li, Yong Jie; Wang, Yan; Giles, Mary K.; Zaveri, Rahul A.; Bertram, Allan K.; Martin, Scot T.

    2016-10-24

    Accurate simulations of the consenctrations of atmospheric organic particulate matter (PM) are needed for predicting energy flow in the Earth’s climate system. In the past, simulations of organic PM widely assume equilibrium partitioning of semivolatile organic compounds (SVOCs) between the PM and surrounding vapor. Herein, we test this assumption by measuring evaporation rates and associated vapor mass concentration of organic films representative of atmospheric PM. For films representing anthropogenic PM, evaporation rates and vapor mass concentrations increased above a threshold relative humidity (RH), indicating equilibrium partitioning above a transition RH but not below. In contrast for films representing biogenic PM, no threshold was observed, indicating equilibrium partitioning at all RHs. The results suggest that the mass lability of atmospheric organic PM can differ in consequential ways among Earth’s natural biomes, polluted regions, and regions of land-use change, and these differences need to be considered when simulating atmospheric organic PM.

  8. Mass spectroscopic analysis of atmospheric particulate matter

    International Nuclear Information System (INIS)

    Wippel, R.

    1997-02-01

    Particulate matter (PM) in the atmosphere vary greatly in origin, in their physical and chemical properties and their effects on climate, atmospheric chemistry and health. Aerosol particles with an aerodynamic diameter less than two μm can enter the respiratory tract of humans when inhaled. Bulk analysis of ambient dust particles was performed using an inductively coupled plasma mass spectrometer (ICP-MS). The size-fractionated collected samples were analyzed after a leaching procedure that simulates the solution reactions occurring in the lungs. A disadvantage of bulk analysis is that it gives no information about the distribution of a certain element within the particles under investigation. A Laser-Microprobe-Mass-Analyzer (LAMMA-500) was used to obtain this information. At sampling sites in Austria and in Zimbabwe, Africa, single particles were sampled using a self-made impactor. One of the final aims in environmental analysis is to successfully apply receptor models that relate the chemical and physical properties of a receptor site to a source. The knowledge of the sources of atmospheric particulate matter is essential for environmental policy makers as well as for epidemiological studies. Artificial neural networks (ANN) have a remarkable ability to handle LAMMA-data. Three ANNs were used as a pattern recognition tool for LAMMA mass spectral data: a back-propagation net, a Kohonen network,and a counter-propagation net. Standard source profiles from the United States Environmental Protection Agency were used as training and test data of the different nets. The elemental patterns of the sum of 100 mass spectra of fine dust particles were presented to the trained nets and satisfactory recognition (> 80 %) was obtained. (author)

  9. Comparison of testing methods for particulate filters

    International Nuclear Information System (INIS)

    Ullmann, W.; Przyborowski, S.

    1983-01-01

    Four testing methods for particulate filters were compared by using the test rigs of the National Board of Nuclear Safety and Radiation Protection: 1) Measurement of filter penetration P as a function of particle size d by using a polydisperse NaC1 test aerosol and a scintillation particle counter; 2) Modified sodium flame test for measurement of total filter penetration P for various polydisperse NaC1 test aerosols; 3) Measurement of total filter penetration P for a polydisperse NaC1 test aerosol labelled with short-lived radon daughter products; 4) Measurement of total filter penetration P for a special paraffin oil test aerosol (oil fog test used in FRG according DIN 24 184, test aerosol A). The investigations were carried out on sheets of glass fibre paper (five grades of paper). Detailed information about the four testing methods and the used particle size distributions is given. The different results of the various methods are the base for the discussion of the most important parameters which influence the filter penetration P. The course of the function P=f(d) shows the great influence of the particle size. As expected there was also found a great dependence both from the test aerosol as well as from the principle and the measuring range of the aerosol-measuring device. The differences between the results of the various test methods are greater the lower the penetration. The use of NaCl test aerosol with various particle size distributions gives great differences for the respective penetration values. On the basis of these results and the values given by Dorman conclusions are made about the investigation of particulate filters both for the determination of filter penetration P as well as for the leak test of installed filters

  10. Particulate absorption properties in the Red Sea from hyperspectral particulate absorption spectra

    KAUST Repository

    Tiwari, Surya Prakash

    2018-03-16

    This paper aims to describe the variability of particulate absorption properties using a unique hyperspectral dataset collected in the Red Sea as part of the TARA Oceans expedition. The absorption contributions by phytoplankton (aph) and non-algal particles (aNAP) to the total particulate absorption coefficients are determined using a numerical decomposition method (NDM). The NDM is validated by comparing the NDM derived values of aph and aNAP with simulated values of aph and aNAP are found to be in excellent agreement for the selected wavelengths (i.e., 443, 490, 555, and 676nm) with high correlation coefficient (R2), low root mean square error (RMSE), mean relative error (MRE), and with a slope close to unity. Further analyses showed that the total particulate absorption coefficients (i.e., ap(443)average = 0.01995m−1) were dominated by phytoplankton absorption (i.e., aph(443)average = 0.01743m−1) with a smaller contribution by non-algal particles absorption (i.e., aNAP(443)average = 0.002524m−1). The chlorophyll a is computed using the absorption based Line Height Method (LHM). The derived chlorophyll-specific absorption ((a⁎ph = aph(λ)/ChlLH)) showed more variability in the blue part of spectrum as compared to the red part of spectrum representative of the package effect and changes in pigment composition. A new parametrization proposed also enabled the reconstruction of a⁎ph(λ) for the Red Sea. Comparison of derived spectral constants with the spectral constants of existing models showed that our study A(λ) values are consistent with the existing values, despite there is a divergence with the B(λ) values. This study provides valuable information derived from the particulate absorption properties and its spectral variability and this would help us to determine the relationship between the phytoplankton absorption coefficients and chlorophyll a and its host of variables for the Red Sea.

  11. Elucidating the mechanisms of nickel compound uptake: A review of particulate and nano-nickel endocytosis and toxicity

    Energy Technology Data Exchange (ETDEWEB)

    Muñoz, Alexandra; Costa, Max, E-mail: Max.Costa@nyumc.org

    2012-04-01

    Nickel (Ni) is a worldwide pollutant and contaminant that humans are exposed to through various avenues resulting in multiple toxic responses — most alarming is its clear carcinogenic nature. A variety of particulate Ni compounds persist in the environment and can be distinguished by characteristics such as solubility, structure, and surface charge. These characteristics influence cellular uptake and toxicity. Some particulate forms of Ni are carcinogenic and are directly and rapidly endocytized by cells. A series of studies conducted in the 1980s observed this process, and we have reanalyzed the results of these studies to help elucidate the molecular mechanism of particulate Ni uptake. Originally the process of uptake observed was described as phagocytosis, however in the context of recent research we hypothesize that the process is macropinocytosis and/or clathrin mediated endocytosis. Primary considerations in determining the route of uptake here include calcium dependence, particle size, and inhibition through temperature and pharmacological approaches. Particle characteristics that influenced uptake include size, charge, surface characteristics, and structure. This discussion is relevant in the context of nanoparticle studies and the emerging interest in nano-nickel (nano-Ni), where toxicity assessments require a clear understanding of the parameters of particulate uptake and where establishment of such parameters is often obscured through inconsistencies across experimental systems. In this regard, this review aims to carefully document one system (particulate nickel compound uptake) and characterize its properties.

  12. MEASURING THE PARTICULATE BACKSCATTERING OF INLAND WATERS: A COMPARISON OF TECHNIQUES

    Directory of Open Access Journals (Sweden)

    G. Campbell

    2012-07-01

    Full Text Available The objective of this work was to examine whether the standard particulate backscattering IOP (Inherent Optical Properties measurement method could be simplified. IOP measurements are essential for parameterising several forms of algorithms used to estimate water quality parameters from airborne and satellite images. Field measurements of the backscattering IOPs are more difficult to make than absorption measurements as correction of the raw Hydroscat-6 backscattering sensor observations is required to allow for the systematic errors associated with the water and water quality parameter absorption. The standard approach involves making simultaneous measurement of the absorption and attenuation of the water with an absorption and attenuation meter (ac-9 or making assumptions about the particulate backscattering probability. Recently, a number of papers have been published that use an alternative method to retrieve the particulate backscattering spectrum by using laboratory measured absorption values and in situ spectroradiometric observations. The alternative method inverts a model of reflectance iteratively using non-linear least squares fitting to solve for the particulate backscattering at 532 nm (bbp0(532 and the particulate backscattering spectral slope (γ. In this paper, eleven observations made at Burdekin Falls Dam, Australia are used to compare the alternative reflectance method to the conventional corrected Hydroscat-6 observations. Assessment of the alternative reflectance method showed that the result of the inversions were highly dependent on the starting conditions. To overcome this limitation, Particle Swarm Optimisation, a stochastic search technique which includes a random element in the search approach, was used. It was found that when compared to the conventionally corrected Hydroscat-6 observations, the alternative reflectance method underestimated bbp0(532 by approximately 50% and overestimated γ by approximately 40

  13. Airborne soil particulates as vehicles for Salmonella contamination of tomatoes.

    Science.gov (United States)

    Kumar, Govindaraj Dev; Williams, Robert C; Al Qublan, Hamzeh M; Sriranganathan, Nammalwar; Boyer, Renee R; Eifert, Joseph D

    2017-02-21

    The presence of dust is ubiquitous in the produce growing environment and its deposition on edible crops could occur. The potential of wind-distributed soil particulate to serve as a vehicle for S. Newport transfer to tomato blossoms and consequently, to fruits, was explored. Blossoms were challenged with previously autoclaved soil containing S. Newport (9.39log CFU/g) by brushing and airborne transfer. One hundred percent of blossoms brushed with S. Newport-contaminated soil tested positive for presence of the pathogen one week after contact (PCompressed air was used to simulate wind currents and direct soil particulates towards blossoms. Airborne soil particulates resulted in contamination of 29% of the blossoms with S. Newport one week after contact. Biophotonic imaging of blossoms post-contact with bioluminescent S. Newport-contaminated airborne soil particulates revealed transfer of the pathogen on petal, stamen and pedicel structures. Both fruits and calyxes that developed from blossoms contaminated with airborne soil particulates were positive for presence of S. Newport in both fruit (66.6%) and calyx (77.7%). Presence of S. Newport in surface-sterilized fruit and calyx tissue tested indicated internalization of the pathogen. These results show that airborne soil particulates could serve as a vehicle for Salmonella. Hence, Salmonella contaminated dust and soil particulate dispersion could contribute to pathogen contamination of fruit, indicating an omnipresent yet relatively unexplored contamination route. Copyright © 2016 Elsevier B.V. All rights reserved.

  14. Particulate and soluble 210Pd activities in the deep sea

    International Nuclear Information System (INIS)

    Somayajulu, B.L.K.; Craig, H.

    1976-01-01

    Particulate and soluble, 210 Pb activities have been measured by filtration of large-volume water samples at two stations in the South Atlantic. Particulate phase 210 Pb (caught by a 0.4-μm filter) varies from 0.3% of total 210 Pb in equatorial surface water to 15% in the bottom water. The 'absolute activity' of 210 Pb per unit mass of particulate matter is about 10 7 times the activity of soluble 210 Pb per unit mass of water, but because the mass ratio of particulate matter to water is about 10 -8 , the particulate phase carries only about 10% of the total activity. In Antarctic surface water the particulate phase carries 40% of the total 210 Pb activity; the absolute activity of this material is about the same as in other water masses and the higher fraction is due to the much larger concentration of suspended matter in surface water in this region. In the equatorial Atlantic the particulate phase 210 Pb activity increases with depth, by a factor of 40 from surface to bottom, and by a factor of 4 from the Antarctic Intermediate water core to the Antarctic Bottom Water. (Auth.)

  15. Airborne Particulate Matter Induces Nonallergic Eosinophilic Sinonasal Inflammation in Mice.

    Science.gov (United States)

    Ramanathan, Murugappan; London, Nyall R; Tharakan, Anuj; Surya, Nitya; Sussan, Thomas E; Rao, Xiaoquan; Lin, Sandra Y; Toskala, Elina; Rajagopalan, Sanjay; Biswal, Shyam

    2017-07-01

    Exposure to airborne particulate matter (PM) has been linked to aggravation of respiratory symptoms, increased risk of cardiovascular disease, and all-cause mortality. Although the health effects of PM on the lower pulmonary airway have been extensively studied, little is known regarding the impact of chronic PM exposure on the upper sinonasal airway. We sought to test the impact of chronic airborne PM exposure on the upper respiratory system in vivo. Mice were subjected, by inhalation, to concentrated fine (2.5 μm) PM 6 h/d, 5 d/wk, for 16 weeks. Mean airborne fine PM concentration was 60.92 μm/m 3 , a concentration of fine PM lower than that reported in some major global cities. Mice were then killed and analyzed for evidence of inflammation and barrier breakdown compared with control mice. Evidence of the destructive effects of chronic airborne PM on sinonasal health in vivo, including proinflammatory cytokine release, and macrophage and neutrophil inflammatory cell accumulation was observed. A significant increase in epithelial barrier dysfunction was observed, as assessed by serum albumin accumulation in nasal airway lavage fluid, as well as decreased expression of adhesion molecules, including claudin-1 and epithelial cadherin. A significant increase in eosinophilic inflammation, including increased IL-13, eotaxin-1, and eosinophil accumulation, was also observed. Collectively, although largely observational, these studies demonstrate the destructive effects of chronic airborne PM exposure on the sinonasal airway barrier disruption and nonallergic eosinophilic inflammation in mice.

  16. A laser particulate spectrometer for a space simulation facility

    Science.gov (United States)

    Schmitt, R. J.; Boyd, B. A.; Linford, R. M. F.; Richmond, R. G.

    1975-01-01

    A laser particulate spectrometer (LPS) system was developed to measure the size and speed distributions of particulate contaminants. Detection of the particulates is achieved by means of light scattering and extinction effects using a single laser beam to cover a size range of 0.8 to 275 microns diameter and a speed range of 0.2 to 20 meters/second. The LPS system was designed to operate in the high-vacuum environment of a space simulation chamber with cold shroud temperatures ranging from 77 to 300 K.

  17. Review of the state-of-the-art of exhaust particulate filter technology in internal combustion engines.

    Science.gov (United States)

    Guan, Bin; Zhan, Reggie; Lin, He; Huang, Zhen

    2015-05-01

    The increasingly stringent emission regulations, such as US 2010, Tier 2 Bin 5 and beyond, off-road Tier 4 final, and Euro V/5 for particulate matter (PM) reduction applications, will mandate the use of the diesel particulate filters (DPFs) technology, which is proven to be the only way that can effectively control the particulate emissions. This paper covers a comprehensive overview of the state-of-the-art DPF technologies, including the advanced filter substrate materials, the novel catalyst formulations, the highly sophisticated regeneration control strategies, the DPF uncontrolled regenerations and their control methodologies, the DPF soot loading prediction, and the soot sensor for the PM on-board diagnostics (OBD) legislations. Furthermore, the progress of the highly optimized hybrid approaches, which involves the integration of diesel oxidation catalyst (DOC) + (DPF, NOx reduction catalyst), the selective catalytic reduction (SCR) catalyst coated on DPF, as well as DPF in the high-pressure exhaust gas recirculation (EGR) loop systems, is well discussed. Besides, the impacts of the quality of fuel and lubricant on the DPF performance and the maintenance and retrofit of DPF are fully elaborated. Meanwhile, the high efficiency gasoline particulate filter (GPF) technology is being required to effectively reduce the PM and particulate number (PN) emissions from the gasoline direct injection (GDI) engines to comply with the future increasingly stricter emissions regulations. Copyright © 2015 Elsevier Ltd. All rights reserved.

  18. Air pollution in Aleppo city, gases,suspended particulates

    International Nuclear Information System (INIS)

    Othman, I.; Sabra, Sh.; Al-Kharfan, K.

    1994-06-01

    Total suspended particulates measured by using High Volume Air Sampler. The Co and O 3 were measured during weekday and weekend. The concentration of all pollutants at city center are higher than other measured areas. (author). 10 figs., 10 tabs

  19. Observations on particulate organic nitrates and unidentified components of NOy

    DEFF Research Database (Denmark)

    Nielsen, T.; Egeløv, A.H.; Granby, K.

    1995-01-01

    A method to determine the total content of particulate organic nitrates (PON) has been developed and ambient air measurements of PON, NO, NO2, HNO3, peroxyacetyl nitrate (PAN), peroxypropionyl nitrate (PPN), gas NOy and particulate inorganic nitrate have been performed in the spring and early...... summer al an agricultural site in Denmark and compared with measurements of ozone, H2O2, SO2, formic acid, acetic acid and methane sulphonic acid. The gas NOy detector determines the sum NO + NO2 + HNO2 + HNO3 + PAN + PPN + gas phase organic nitrates + 2 x N2O5 + NO3. The content of residual gas NOy...... = gas NOy + particulate inorganic nitrate). Residual gas NOy was much higher than the particulate fraction of organic nitrates (PON). PON was only 0.25 +/- 0.11% of concentrations of photochemical oxidants in connection with high-pressure systems suggesting atmospheric processes being the major source...

  20. Life Support Systems: Trace Contaminant and Particulate Control

    Data.gov (United States)

    National Aeronautics and Space Administration — Advanced Exploration Systems (AES) Life Support Systems project Trace Contaminant and Particulate Control task: Work in the area of trace contamination and...

  1. Particulate Air Contamination in Puerto Rico: A Student Involvement Project.

    Science.gov (United States)

    Eckert, Richard R.

    1979-01-01

    Describes a research project undertaken by physics undergraduate students to monitor particulate air contamination in Ponce, Puerto Rico, and to determine the meteorological factors which contribute to it. (GA)

  2. Short term variations in particulate matter in Mahi river estuary

    Digital Repository Service at National Institute of Oceanography (India)

    Bhosle, N.B.; Rokade, M.A.; Zingde, M.D.

    The particulate matter (PM) collected from Mahi River Estuary was analysed for organic carbon (POC), nitrogen (PON), and chlorophyll a (Chl a). The concentration of PM, POC, PON and Chl a showed short term variations. Average surface concentration...

  3. Canada-United States Transboundary Particulate Matter Science Assessment 2013

    Science.gov (United States)

    This 2013 document summarizes the findings of the Canada-U.S. subcommittee on Scientific Cooperation concerning the transboundary transport of particulate matter (PM) and PM precursors between the two countries.

  4. Canada-United States Transboundary Particulate Matter Science Assessment

    Science.gov (United States)

    This 2004 document summarizes the findings of the Canada-U.S. subcommittee on Scientific Cooperation concerning the transboundary transport of particulate matter (PM) and PM precursors between the two countries.

  5. Ocean subsurface particulate backscatter estimation from CALIPSO spaceborne lidar measurements

    Science.gov (United States)

    Chen, Peng; Pan, Delu; Wang, Tianyu; Mao, Zhihua

    2017-10-01

    A method for ocean subsurface particulate backscatter estimation from the Cloud-Aerosol Lidar with Orthogonal Polarization (CALIOP) on the Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observation (CALIPSO) satellite was demonstrated. The effects of the CALIOP receiver's transient response on the attenuated backscatter profile were first removed. The two-way transmittance of the overlying atmosphere was then estimated as the ratio of the measured ocean surface attenuated backscatter to the theoretical value computed from wind driven wave slope variance. Finally, particulate backscatter was estimated from the depolarization ratio as the ratio of the column-integrated cross-polarized and co-polarized channels. Statistical results show that the derived particulate backscatter by the method based on CALIOP data agree reasonably well with chlorophyll-a concentration using MODIS data. It indicates a potential use of space-borne lidar to estimate global primary productivity and particulate carbon stock.

  6. Transportation conformity particulate matter hot-spot air quality modeling.

    Science.gov (United States)

    2013-07-01

    In light of the new development in particulate matter (PM) hot-spot regulations and Illinois Department : of Transportation (IDOT)s National Environmental Policy Act (NEPA) documentation requirements, : this project is intended to (1) perform and ...

  7. Automated particulate sampler field test model operations guide

    Energy Technology Data Exchange (ETDEWEB)

    Bowyer, S.M.; Miley, H.S.

    1996-10-01

    The Automated Particulate Sampler Field Test Model Operations Guide is a collection of documents which provides a complete picture of the Automated Particulate Sampler (APS) and the Field Test in which it was evaluated. The Pacific Northwest National Laboratory (PNNL) Automated Particulate Sampler was developed for the purpose of radionuclide particulate monitoring for use under the Comprehensive Test Ban Treaty (CTBT). Its design was directed by anticipated requirements of small size, low power consumption, low noise level, fully automatic operation, and most predominantly the sensitivity requirements of the Conference on Disarmament Working Paper 224 (CDWP224). This guide is intended to serve as both a reference document for the APS and to provide detailed instructions on how to operate the sampler. This document provides a complete description of the APS Field Test Model and all the activity related to its evaluation and progression.

  8. Atmospheric oxidative chemistry of organic particulate emissions from fuel combustion.

    Science.gov (United States)

    2011-03-25

    "Construction and characterization of the University of Vermont Environmental Chamber (UVMEC) : were completed in this last phase of the project. The primary function of the UVMEC is to enable : tropospheric particulate formation and aging studies to...

  9. Influence of particulates on crossflow filter performance with tetraphenylborate precipitate

    International Nuclear Information System (INIS)

    Peterson, R.A.; Nash, C.A.; McCabe, D.J.

    1995-01-01

    The pretreatment of High Level Waste at the Savannah River Site, prior to vitrification, includes tetraphenylborate precipitation of cesium. Also, strontium and actinides are removed from solution by sorption on monosodium titanate. The resulting slurry is concentrated and washed using 0.4 micron stainless steel Mott filters in a crossflow assembly. The rate of filtrate production is governed by a number of parameters including the concentration of both soluble and insoluble solids present in the process stream. The major insoluble constituents in the process stream are tetraphenylborate solids. However, the presence of small quantities of monosodium titanate as well as sludge particulates, typically less than 10% of the total solids concentration, produces up to a 50% decline in the rate of filtrate production. The cake that develops during filtration is the primary resistance to flow of filtrate. In addition, experimental data indicate the filter cake is enriched in the insoluble solids relative to the bulk of the solution. The presence of these insoluble solids in the filter cake influences not only the overall filtrate flow rate, but also the mechanisms by which the filter cake is formed

  10. Particulate emission abatement for Krakow boiler houses

    Energy Technology Data Exchange (ETDEWEB)

    Wysk, R.

    1995-12-31

    Among the many strategies for improving air quality in Krakow, one possible method is to adapt new and improved emission control technology. This project focuses on such a strategy. In order to reduce dust emissions from coal-fueled boilers, a new device called a Core Separator has been introduced in several boiler house applications. This advanced technology has been successfully demonstrated in Poland and several commercial units are now in operation. Particulate emissions from the Core Separator are typically 3 to 5 times lower than those from the best cyclone collectors. It can easily meet the new standard for dust emissions which will be in effect in Poland after 1997. The Core Separator is a completely inertial collector and is based on a unique recirculation method. It can effectively remove dust particles below 10 microns in diameter, the so-called PM-10 emissions. Its performance approaches that of fabric filters, but without the attendant cost and maintenance. It is well-suited to the industrial size boilers located in Krakow. Core Separators are now being marketed and sold by EcoInstal, one of the leading environmental firms in Poland, through a cooperative agreement with LSR Technologies.

  11. Evaluation of principal cannabinoids in airborne particulates

    Energy Technology Data Exchange (ETDEWEB)

    Balducci, C [Italian National Research Council, Institute for Atmospheric Pollution (CNR-IIA), Monterotondo Stazione (Italy); Nervegna, G; Cecinato, A [Italian National Research Council, Institute for Atmospheric Pollution (CNR-IIA), Monterotondo Stazione (Italy)

    2009-05-08

    The determination of delta(9)-tetrahydrocannabinol ({Delta}{sup 9}-THC), cannabidiol (CND) and cannabinol (CNB), primary active components in cannabis preparation, was carried out on airborne particulates by applying a specific procedure consisting of soot extraction by ultrasonic bath, purification by solvent partitioning, derivatization with N-(t-butyldimethylsilyl)-N-methyl-trifluoroacetamide, and separation/detection through gas chromatography coupled with tandem mass spectrometry. The optimized procedure was found suitable for measuring the three psychotropic substances at concentrations ranging from ca. 0.001 to ca. 5.0 ng cm{sup -3} of air, with recoveries always higher than 82%, accuracy >7.3% and precision >90%. Application of the procedure performed on field in Rome and Bari, Italy, demonstrated that all three compounds contaminate the air in Italian cities whereas in Algiers, Algeria, only cannabinol, the most stable in the atmosphere, exceeded the limit of quantification of the method. The relative percentages of the three cannabinoids in general reproduced those typical of the Cannabis sativa plant and were very different from those found in human blood, urine and sweat.

  12. Airborne particulate matter and spacecraft internal environments

    Science.gov (United States)

    Liu, Benjamin Y. H.; Rubow, Kenneth L.; Mcmurry, Peter H.; Kotz, Thomas J.; Russo, Dane

    1991-01-01

    Instrumentation, consisting of a Shuttle Particle Sampler (SPS) and a Shuttle Particle Monitor (SPM), has been developed to characterize the airborne particulate matter in the Space Shuttle cabin during orbital flight. The SPS size selectively collects particles in four size fractions (0-2.5, 2.5-10, 10-100, and greater than 100 microns) which are analyzed postflight for mass concentration and size distribution, elemental composition, and morphology. The SPM provides a continuous record of particle concentration through photometric light scattering. Measurements were performed onboard Columbia, OV-102, during the flight of STS-32 in January 1990. No significant changes were observed in the particle mass concentration, size distribution, or chemical composition in samples collected during flight-day 2 and flight-day 7. The total mass concentration was 56 microg/cu cm with approximately half of the particles larger than 100 microns. Elemental analysis showed that roughly 70 percent of the particles larger than 2.5 microns were carbonaceous with small amounts of other elements present. The SPM showed no temporal or spatial variation in particle mass concentration during the mission.

  13. Metal/nonmetal diesel particulate matter rule

    Energy Technology Data Exchange (ETDEWEB)

    Tomko, D.M. [United States Dept. of Labor, Mine Safety and Health Administration, Pittsburgh, PA (United States). Safety and Health Technology Center; Stackpole, R.P. [United States Dept. of Labor, Mine Safety and Health Administration, Triadelphia, WV (United States). Approval and Certification Center; Findlay, C.D. [United States Dept. of Labor, Mine Safety and Health Administration, Arlington, VA (United States). Metal/Nonmetal Safety and Health; Pomroy, W.H. [United States Dept. of Labor, Mine Safety and Health Administration, Duluth, MN (United States). Metal/Nonmetal North Central District

    2010-07-01

    The American Mine Safety and Health Administration (MSHA) issued a health standard in January 2001 designed to reduce exposure to diesel particulate matter (DPM) in underground metal and nonmetal mines. The rule established an interim concentration limit for DPM of 400 {mu}g/m{sup 3} of total carbon, to be followed in 2004 by a final limit of 160 {mu}g/m{sup 3} of total carbon. The 2001 rule was challenged in federal court by various mining trade associations and mining companies. The rule was subsequently amended. This paper highlighted the major provisions of the 2006 final rule and summarized MSHAs current compliance sampling procedures. The concentration limit was changed to a permissible exposure limit and the sampling surrogate was changed from total carbon to elemental carbon. The MSHA published a new rule in 2006 which based the final limit on a miner's personal exposure rather than a concentration limit. The final limit was phased in using 3 steps over 2 years. This paper also discussed engineering controls and a recent MSHA report on organic carbon, elemental carbon and total carbon emissions from a diesel engine fueled with various blends of standard diesel and biodiesel. In May 2008, about two-thirds of all underground metal/nonmetal mines achieved and maintained compliance with the rule. 20 refs.

  14. Evaluation of principal cannabinoids in airborne particulates

    International Nuclear Information System (INIS)

    Balducci, C.; Nervegna, G.; Cecinato, A.

    2009-01-01

    The determination of delta(9)-tetrahydrocannabinol (Δ 9 -THC), cannabidiol (CND) and cannabinol (CNB), primary active components in cannabis preparation, was carried out on airborne particulates by applying a specific procedure consisting of soot extraction by ultrasonic bath, purification by solvent partitioning, derivatization with N-(t-butyldimethylsilyl)-N-methyl-trifluoroacetamide, and separation/detection through gas chromatography coupled with tandem mass spectrometry. The optimized procedure was found suitable for measuring the three psychotropic substances at concentrations ranging from ca. 0.001 to ca. 5.0 ng cm -3 of air, with recoveries always higher than 82%, accuracy >7.3% and precision >90%. Application of the procedure performed on field in Rome and Bari, Italy, demonstrated that all three compounds contaminate the air in Italian cities whereas in Algiers, Algeria, only cannabinol, the most stable in the atmosphere, exceeded the limit of quantification of the method. The relative percentages of the three cannabinoids in general reproduced those typical of the Cannabis sativa plant and were very different from those found in human blood, urine and sweat.

  15. Particulate Emissions and Biodiesel: A review

    Directory of Open Access Journals (Sweden)

    Michal Angelovič

    2013-05-01

    Full Text Available Abstract The current mode of transport using fuel it cannot be characterized as harmless to human health or as sustainable. The whole process of extracting, processing and using of petroleum products can be seen as the raw material cycle in nature. This cycle also cause serious damage to the environment and human health. Many studies on air pollutant emissions with biodiesel have been carried out worldwide. Studies have shown that diesel-powered vehicles are the major contributors of PM emissions. PM particulates are especially important in regard to adverse health outcomes, such as increased cardiovascular, respiratory morbidity and mortality rates, due to their larger active surface and the higher likelihood of deposition in the alveolar region of the lungs. Hence, it is overwhelming argument that the use of biodiesel instead of diesel causes reduce of PM emissions. Of course, this reduction will become smaller with the reduction of biodiesel proportion in the blended fuel. The trend with which PM emissions of biodiesel will be reduced, is due to lower aromatic and sulfur compounds and higher cetane number for biodiesel, but the more important factor is the higher oxygen content.

  16. Fine particulate pollution and asthma exacerbations.

    Science.gov (United States)

    Bouazza, Naïm; Foissac, Frantz; Urien, Saik; Guedj, Romain; Carbajal, Ricardo; Tréluyer, Jean-Marc; Chappuy, Hélène

    2017-12-19

    As the results from epidemiological studies about the impact of outdoor air pollution on asthma in children are heterogeneous, our objective was to investigate the association between asthma exacerbation in children and exposure to air pollutants. A database of 1 264 585 paediatric visits during the 2010-2015 period to the emergency rooms from 20 emergency departments (EDs) of 'Assistance Publique Hôpitaux de Paris (APHP)', the largest hospital group in Europe, was used. A total of 47 107 visits were classified as asthma exacerbations. Concentration of air pollutants (nitrogen dioxide, ozone, fine particulate matter (PM) with an aerodynamic diameter smaller than 10  µm (PM 10 ) and 2.5 µm (PM 2.5 )), as well as meteorological data, evolution of respiratory syncytial virus infection and pollen exposition, were collected on an hourly or daily basis for the same period using institutional databases. To assess the association between air pollution and asthma, mixed-effects quasi-Poisson regression modelling was performed. The only compound independently associated with ED visits for asthma was PM 2.5 (Ppollutants. © Article author(s) (or their employer(s) unless otherwise stated in the text of the article) 2017. All rights reserved. No commercial use is permitted unless otherwise expressly granted.

  17. Particulate COD balance of particulate cod in eletrocuagulation/flotation reactor treating tannery effluent

    Directory of Open Access Journals (Sweden)

    Rodrigo Babora Borri

    2012-04-01

    Full Text Available Mass balance or particulate organic matter was studied in terms of COD, by means of electrocoagulation/flotation (ECF reactor treating tannery effluent. Reactor was operated in fill and draw (batch mode. Operating in hydraulic residence time of 65 minutes, ECF reactor reached 55 % COD removal. Although volatile solids were also removed from liquid phase (removal of 40%, fixed solids concentration, and hence total solids concentration, showed to be higher in withdrawn effluent than in ECF’s influent. This was assigned to NaCl added in order to enhance conductivity in wastewater.

  18. Inventory of primary particulates emissions; Inventaire des emissions de particules primaires

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-12-01

    CITEPA carried out a national inventory on particulate emissions. This report presents the results of this study for a great number of sectors and it covers a larger number of sources than the previous CITEPA inventories on particles and some other inventories carried out by International organisms (TNO, IIASA). In particular, at the present time, fugitive dust emissions for some sources are rarely taken into account in inventories because of poor knowledge and they are still the subject of researches in order to validate the emission results. (author)

  19. Method and apparatus for treating liquid contaminated with radioactive particulate solids

    International Nuclear Information System (INIS)

    Hirs, G.

    1976-01-01

    A method and apparatus reduces the amount of radioactive solids resulting from the filtration of particulate contaminants from liquid in a nuclear reactor plant. A filtration system includes a pre-filter comprising a sheet filter medium through which the reactor liquid passes to remove relatively large particulate contaminants for storage or disposal. The reactor liquid is then passed through a bed of granular filter medium to accumulate substantially all the previously non-filtered contaminants and thereby provide a clarified liquid suitable for reuse in the reactor. Backwash liquid is flowed through the granular filter bed to remove and entrain the accumulated contaminants into a slurry which is received by a reservoir where the slurry is maintained quiescently to settle the contaminants. Removal of liquid from the reservoir concentrates the contaminants for storage or further processing, without the necessity of large quantities of filter aids that would increase the quantity of storage-requiring contaminated solids

  20. Exposure to Particulate Hexavalent Chromium Exacerbates Allergic Asthma Pathology

    Science.gov (United States)

    Schneider, Brent C.; Constant, Stephanie L.; Patierno, Steven R.; Jurjus, Rosalyn A.; Ceryak, Susan M.

    2011-01-01

    Airborne hexavalent chromate, Cr(VI), has been identified by the Environmental Protection Agency as a possible health threat in urban areas, due to the carcinogenic potential of some of its forms. Particulate chromates are produced in many different industrial settings, with high levels of aerosolized forms historically documented. Along with an increased risk of lung cancer, a high incidence of allergic asthma has been reported in workers exposed to certain inhaled particulate Cr(VI) compounds. However, a direct causal association between Cr(VI) and allergic asthma has not been established. We recently showed that inhaled particulate Cr(VI) induces an innate neutrophilic inflammatory response in BALB/c mice. In the current studies we investigated how the inflammation induced by inhaled particulate Cr(VI) might alter the pathology of an allergic asthmatic response. We used a well-established mouse model of allergic asthma. Groups of ovalbumin protein (OVA)-primed mice were challenged either with OVA alone, or with a combination of OVA and particulate zinc chromate, and various parameters associated with asthmatic responses were measured. Co-exposure to particulate Cr(VI) and OVA mediated a mixed form of asthma in which both eosinophils and neutrophils are present in airways, tissue pathology is markedly exacerbated, and airway hyperresponsiveness is significantly increased. Taken together these findings suggest that inhalation of particulate forms of Cr(VI) may augment the severity of ongoing allergic asthma, as well as alter its phenotype. Such findings may have implications for asthmatics in settings in which airborne particulate Cr(VI) compounds are present at high levels. PMID:22178736

  1. Large impact of small particulates; Grote invloed van klein fijnstof

    Energy Technology Data Exchange (ETDEWEB)

    Hiemstra-Holtkamp, I.V.L. [Astma Fonds, Leusden (Netherlands)

    2006-06-15

    PM2.5 particulates are responsible for a large part of thousands of people that die of air pollution. The Asthma Fund in the Netherlands wants the Dutch government to take specific action and measures for those small particulates. [Dutch] PM2.5 is verantwoordelijk voor een groot deel van de 1000-en mensen die elk jaar sterven door luchtverontreiniging. Het Astma Fonds wil dat de overheid aparte maatregelen neemt voor PM2.5.

  2. K-Basins particulate water content, and behavior

    International Nuclear Information System (INIS)

    DUNCAN, D.R.

    1999-01-01

    This analysis summarizes the state of knowledge of K-basins spent nuclear fuel oxide (film, particulate or sludge) and its chemically bound water in order to estimate the associated multi-canister overpack (MCO) water inventory and to describe particulate dehydration behavior. This information can be used to evaluate the thermal and chemical history of an MCO and its contents during cold vacuum drying (CVD), shipping, and interim storage

  3. K-Basins particulate water content, and behavior

    Energy Technology Data Exchange (ETDEWEB)

    DUNCAN, D.R.

    1999-02-25

    This analysis summarizes the state of knowledge of K-basins spent nuclear fuel oxide (film, particulate or sludge) and its chemically bound water in order to estimate the associated multi-canister overpack (MCO) water inventory and to describe particulate dehydration behavior. This information can be used to evaluate the thermal and chemical history of an MCO and its contents during cold vacuum drying (CVD), shipping, and interim storage.

  4. Air particulate pollution studies in Asian countries using nuclear analytical techniques

    International Nuclear Information System (INIS)

    Hien, P.D.

    1998-01-01

    Air particulate pollution is regarded as critical in Asian cities. The levels of suspended particulate matter in major Asian cities far exceed the WHO's guideline. Nuclear analytical techniques have been widely used in the studies of air particulate pollution to provide aerosol elemental compositions for the purpose of deriving the structure of emission sources. This paper presents some preliminary observations and findings based on publications in scientific literatures. Data on PM-10 levels and socio-economic indicators are used for searching a relationship between air quality and the level of development across Asia. An inverse linear relationship between PM-10 levels and logarithm of per capita GDP appears to exist, although there are large fluctuations of data caused by the very different climatic and geographical conditions of cities studied. Soil dust is generally a major, or even predominant aerosol source in Asian cities. Other common sources include vehicular emissions, coal and oil combustion, burning of refuse (in open) and biomass (including forest fires). The relevance and the trends of these sources in Asian context are discussed. Multivariate receptor modelling techniques applied in source characterization are illustrated through the cases of Lahore and Hochiminh City. Although having limitations in dealing with mixing and overlapping sources, receptor modelling based on principal component factor analysis has been proven to be uncomplicated and sufficiently reliable for characterising aerosol sources in urban areas. (author)

  5. Co-exposure to inhaled ambient particulate matter and acrolein alters myocardial synchrony in mice: evidence for TRPA1 involvement

    Science.gov (United States)

    Because air pollution is a complex mixture of constituents, often including particulates and aldehydes, attributing health effects to air pollutants in a given ambient air shed can be difficult when pollutants are studied in isolation. The purpose of this study was to examine the...

  6. Temperature effects on particulate emissions from DPF-equipped diesel trucks operating on conventional and biodiesel fuels

    Science.gov (United States)

    Two diesel trucks equipped with a particulate filter (DPF) were tested at two ambient temperatures (70oF and 20oF), fuels (ultra low sulfur diesel (ULSD) and biodiesel (B20)) and operating loads (a heavy and light weight). The test procedure included three driving cycles, a cold ...

  7. Particulate matter mass concentrations produced from pavement surface abrasion

    Directory of Open Access Journals (Sweden)

    Fullova Dasa

    2017-01-01

    Full Text Available According to the latest findings particulate matter belong to the most significant pollutants in Europe together with ground-level ozone O3 and nitrogen dioxide NO2. Road traffic is one of the main sources of particulate matter. Traffic volume has unpleasant impact on longevity of the pavements and also on the environment. Vehicle motions cause mechanical wearing of the asphalt pavement surface - wearing course by vehicle tyres. The paper deals with abrasion of bituminous wearing courses of pavements. The asphalt mixtures are compared in terms of mechanically separated particulate matter. The samples of asphalt mixtures were rutted in wheel tracking machine. The particulate matter measurements were performed in laboratory conditions. The experimental laboratory measurements make it possible to sample particulates without contamination from exhaust emissions, abraded particles from vehicles, resuspension of road dust and climate affects. The paper offers partial results of measurements on six trial samples of asphalt mixtures with different composition. It presents particulate matter morphology and the comparison of rutted asphalt samples in terms of PM mass concentrations and chemical composition.

  8. Domestic smoke exposure is associated with alveolar macrophage particulate load.

    Science.gov (United States)

    Fullerton, Duncan G; Jere, Khuzwayo; Jambo, Kondwani; Kulkarni, Neeta S; Zijlstra, Eduard E; Grigg, Jonathan; French, Neil; Molyneux, Malcolm E; Gordon, Stephen B

    2009-03-01

    Indoor air pollution is associated with impaired respiratory health. The pre-dominant indoor air pollutant to which two billion of the world's population is exposed is biomass fuel smoke. We tested the hypothesis that reported smoke exposure in men and women is associated with increased alveolar macrophage uptake of biomass smoke particulates. Healthy volunteers attending for research bronchoscopy in Malawi completed a questionnaire assessment of smoke exposure. Particulate matter visible in alveolar macrophages (AM) was quantified using digital image analysis. The geometric mean of the percentage area of the cytoplasm occupied by particulates in 50 cover-slip adherent AM was calculated and termed particulate load. In 57 subjects (40 men and 17 women) there was a significant difference between the particulate load in groups divided according to pre-dominant lighting form used at home (ANOVA P = 0.0009) and type of cooking fuel (P = 0.0078). Particulate load observed in macrophages is associated with the reported type of biomass fuel exposure. Macrophage function in relation to respiratory health should now be investigated in biomass smoke exposed subjects.

  9. Method and apparatus for removing volatile hydrocarbons from particulate soils

    International Nuclear Information System (INIS)

    Mendenhall, R.L.

    1992-01-01

    This patent describes an apparatus for heating solid particulate mineral compositions. It comprises: a counterflow ratable drum having a first end and an opposite second end, a first portion of the drum extending from the first end for a first length and having a first diameter along the first length, and a second portion of the drum secured to and extending from the first portion to the second end for a second length and having a second diameter along the second length, the second diameter being less than the first diameter, a burner adjacent the first end for introducing and directing hot gases of combustion into the first portion of the drum toward the second end, means for introducing particulate composition into the drum at the second end, means for directing the particulate composition along the drum from the second end toward the first end, and means for recovering composition at the first end, means for removing a gaseous mixture of organic volatiles, gases of combustion and fine particles of the particulate composition adjacent the second drum end, means for separating fine particles of the particulate composition from the gaseous mixture, and means for returning the separated fine particulate composition particles to the first portion of the drum

  10. An evaluation of fuels and retrofit diesel particulate filters to reduce diesel particulate matter emissions in an underground mine

    CSIR Research Space (South Africa)

    Wattrus, MC

    2016-09-01

    Full Text Available Through an industry wide collaborative project, this paper explores what potential exists for South African underground mines to reduce diesel particulate emissions, where the starting point is a mine using older engine technology (Tier 1 emission...

  11. Thorium-particulate matter interaction. Thorium complexing capacity of oceanic particulate matter: Theory

    International Nuclear Information System (INIS)

    Hirose, Katsumi; Tanque, Eiichiro

    1994-01-01

    The interaction between thorium and oceanic particulate matter was examined experimentally by using chemical equilibrium techniques. Thorium reacts quantitatively with the organic binding site of Particulate Matter (PM) in 0.1 mol/L HCl solution by complexation, which is equilibrated within 34 h. According to mass balance analysis, thorium forms a 1:1 complex with the organic binding site in PM, whose conditional stability constant is 10 6.6 L/mol. The Th adsorption ability is present even in 6.9 mol/L HCl solution although the amount of Th adsorption decreases with increasing acidity in the solution. Interferences to Th adsorption by Fe(III) suggests that other metals cannot react with PM in more than 0.1 mol/L HCl solutions when concentrations of other metals are the same level of Th. The competitive reaction between Th and Fe(III) occurs in higher Fe concentrations, which means that the organic binding site is nonspecific for Th. A vertical profile of Th complexing capacity of PM in the western North Pacific is characterized; that is, the Th complexing capacity shows a surface maximum and decreases rapidly with depth

  12. Transport of free and particulate-associated bacteria in karst

    Science.gov (United States)

    Mahler, B. J.; Personné, J.-C.; Lods, G. F.; Drogue, C.

    2000-12-01

    Karst aquifers, because of their unique hydrogeologic characteristics, are extremely susceptible to contamination by pathogens. Here we present the results of an investigation of contamination of a karst aquifer by fecal indicator bacteria. Two wells intercepting zones with contrasting effective hydraulic conductivities, as determined by pump test, were monitored both during the dry season and in response to a rain event. Samples were also collected from the adjacent ephemeral surface stream, which is known to be impacted by an upstream wastewater treatment plant after rainfall. Whole water and suspended sediment samples were analyzed for fecal coliforms and enterococci. During the dry season, pumping over a 2-day period resulted in increases in concentrations of fecal coliforms to greater than 10,000 CFU/100 ml in the high-conductivity well; enterococci and total suspended solids also increased, to a lesser degree. Toward the end of the pumping period, as much as 50% of the fecal coliforms were associated with suspended sediment. Irrigation of an up-gradient pine plantation with primary-treated wastewater is the probable source of the bacterial contamination. Sampling after a rain event revealed the strong influence of water quality of the adjacent Terrieu Creek on the ground water. Bacterial concentrations in the wells showed a rapid response to increased concentrations in the surface water, with fecal coliform concentrations in ground water ultimately reaching 60,000 CFU/100 ml. Up to 100% of the bacteria in the ground water was associated with suspended sediment at various times. The results of this investigation are evidence of the strong influence of surface water on ground water in karst terrain, including that of irrigation water. The large proportion of bacteria associated with particulates in the ground water has important implications for public health, as bacteria associated with particulates may be more persistent and more difficult to inactivate. The

  13. Nano indentation of particulate and polymer films

    International Nuclear Information System (INIS)

    Akram, Aisha

    2001-01-01

    A detailed knowledge of the formation and rupture mechanisms of agglomerates is essential when seeking to model equipment designed to produce and process such agglomerated particulate solids. In the work to be described the nano-indentation of two-dimensional agglomerate films was carried out in order to establish a means of identifying the generic breakage mechanisms of agglomerated systems. Data analysis techniques are developed that enable the individual inter-particle junction strengths to be calculated for a model system consisting of rather mono-dispersed colloidal silica particles (20-24 nm diameter) bound with a poly(methyl methacrylate). Applied load and penetration depth data in the range (10 mN and 500 nm respectively) are provided as a function of loading time during a continuous loading. It is argued that these data enable the sequence of the discrete binder bridge failures to be observed thus giving a quantitative indication of the breakage mechanism of this agglomerate system as well as reflect the agglomerate structure. The secondary objective of this work was to produce a range of agglomerates with different mechanical properties, without changing the type and amount of binder or prime particles used in the system. This was achieved by altering the mechanical properties of the binder, poly(methyl methacrylate), by the use of a variety of solvents. From data obtained using nano-indentation on thin films of the treated polymer, brittle and ductile forms of poly(methyl methacrylate) could be distinguished. These trends are reflected, to some degree, in the mechanical response of the agglomerated layers. (author)

  14. Source strengths for indoor human activities that resuspend particulate matter.

    Science.gov (United States)

    Ferro, Andrea R; Kopperud, Royal J; Hildemann, Lynn M

    2004-03-15

    A mathematical model was applied to continuous indoor and outdoor particulate matter (PM) measurements to estimate source strengths for a variety of prescribed human activities that resuspend house dust in the home. Activities included folding blankets, folding clothes, dry dusting, making a bed, dancing on a rug, dancing on a wood floor, vacuuming, and walking around and sitting on upholstered furniture. Although most of the resuspended particle mass from these activities was larger than 5 microm in diameter, the resuspension of PM2.5 and PM5 was substantial, with source strengths ranging from 0.03 to 0.5 mg min(-1) for PM2.5 and from 0.1 to 1.4 mg min(-1) for PM5. Source strengths for PM > 5 microm could not be quantified due to instrument limitations. The source strengths were found to be a function of the number of persons performing the activity, the vigor of the activity, the type of activity, and the type of flooring.

  15. On the removal of airborne particulate radioactivity under accident conditions

    International Nuclear Information System (INIS)

    Ruedinger, V.; Wilhelm, J.G.

    1985-03-01

    In the case of an accident, the filter elements in the ventilation systems of a nuclear facility may become a part of the remaining fission product barrier. Within the framework of the Project Nuclear Safety of the Karlsruhe Nuclear Research Center, contributions are made to an increase in reliability of the air cleaning systems under accident conditions. These include the development and verification of computer programs for the estimation of those conditions prevailing inside the air cleaning systems in the case of an accident. Experimental investigations into the response of HEPA filters to differential pressures involving both dry and moist air have demonstrated the occurence of structural failures with subsequent loss of efficiency at relatively low values of differential pressures. With regard to further investigations, a new test facility was put into operation for the realization of superimposed challenges. A new method for testing particulate removal efficiency under high temperature or high humidity was developed. Finally, first results of code development work and of the corresponding verification experiments are reported on. (orig.) [de

  16. Tackling the problem of fine particulate (HAP) collection

    Energy Technology Data Exchange (ETDEWEB)

    Parker, K.; Sanyal, A.

    2000-07-01

    With increasing concern over the emission of hazardous air pollutants (HAPs), measures are being considered to limit their discharge from many industrial sources. The main thrust o the proposed legislation is towards the power generators, because of their potentially large mass emissions, but also at specific targets, such as incinerators. Legislation already exists governing the emission of heavy metals, etc., from various types of incineration process and regulations controlling the emission of pM 2.5 material are proposed for the US. Provided the HAPs are in a solid particulate phase then their collection can be accomplished by correctly designed and operated control systems, such as electrostatic precipitators and bag filters. There are, however, other HAP species which are usually in a gaseous phase at normal back end temperatures, such as elemental mercury, dioxins, furans, etc. These need special consideration and equipment in order to satisfy the proposed regulations. one of the difficulties facing the designers and operators of processes giving rise to these species is the accurate measurement of these trace elements and predicting the uncontrolled emission level in order to size the collection system such as to remain in compliance. The options for the effective collection of these normally gaseous phase pollutants will be examined; these methods will include combined wet and dry collection, absorption and carbon injection systems. Finally, whichever system is finally considered and adopted, in order to satisfy and proposed regulations, will add significant capital and operating cost to the overall installation.

  17. Airborne particulate matter collection and analysis by XRF

    International Nuclear Information System (INIS)

    Santos, Flora L.; Esguerra, Luz V.; Pabroa, Preciosa B.; Almoneda, Rosalina

    2004-01-01

    The Philippine Nuclear Research Institute (PNRI) continues to pursue its air pollution research in support of the implementation of the 1999 Clean Air Act. The primary tool for analysis is X-Ray Fluorescence spectrometry (XRF) since the PPP-I is still on extended shut down. Following the workplan approved during the 1991 Workshop on Utilization of Research Reactors, the PNRI collected airborne particulate matter using the Gent sampler. The sampling site selected for the program was Poveda Learning Center, located beside a major highway, the Epifanio delos Santos Avenue (EDSA) where the principal source of pollution is vehicular emissions. Samples collected up to August were analyzed by XRF using three sets of analytical parameters to allow optimized analysis of a wider range of elements including Na and Pb. Although the PNRI has no operating reactor, it has personnel who have trained in NAA but are unable to apply the technique. As mentioned in the 2001 Workshop, the PNRI is considering several options to resume reactor-related activities. Thus, it is necessary to ensure continuing availability of expertise in NAA in the PNRI. It looks forward to collaborating with other Institutes through the FNCA program for the analysis of samples by NAA and using reactor parameters from collaborating Institute, to obtain experience in the use of Ko. This would also allow validation of XRF data obtained for these samples. In return it can analyze samples for collaborating institutions to generate data on Pb and S, which are important for pollutant source apportionment. (author)

  18. Atmospheric particulate emissions from dry abrasive blasting using coal slag

    Energy Technology Data Exchange (ETDEWEB)

    Bhaskar Kura; Kalpalatha Kambham; Sivaramakrishnan Sangameswaran; Sandhya Potana [University of New Orleans, New Orleans, LA (United States). Department of Civil and Environmental Engineering

    2006-08-15

    Coal slag is one of the widely used abrasives in dry abrasive blasting. Atmospheric emissions from this process include particulate matter (PM) and heavy metals, such as chromium, lead, manganese, nickel. Quantities and characteristics of PM emissions depend on abrasive characteristics and process parameters. Emission factors are key inputs to estimate emissions. Experiments were conducted to study the effect of blast pressure, abrasive feed rate, and initial surface contamination on total PM (TPM) emission factors for coal slag. Rusted and painted mild steel surfaces were used as base plates. Blasting was carried out in an enclosed chamber, and PM was collected from an exhaust duct using U.S. Environment Protection Agency source sampling methods for stationary sources. Results showed that there is significant effect of blast pressure, feed rate, and surface contamination on TPM emissions. Mathematical equations were developed to estimate emission factors in terms of mass of emissions per unit mass of abrasive used, as well as mass of emissions per unit of surface area cleaned. These equations will help industries in estimating PM emissions based on blast pressure and abrasive feed rate. In addition, emissions can be reduced by choosing optimum operating conditions. 40 refs., 5 figs., 2 tabs.

  19. Real-time diesel particulate monitor for underground mines.

    Science.gov (United States)

    Noll, James; Janisko, Samuel; Mischler, Steven E

    The standard method for determining diesel particulate matter (DPM) exposures in underground metal/ nonmetal mines provides the average exposure concentration for an entire working shift, and several weeks might pass before results are obtained. The main problem with this approach is that it only indicates that an overexposure has occurred rather than providing the ability to prevent an overexposure or detect its cause. Conversely, real-time measurement would provide miners with timely information to allow engineering controls to be deployed immediately and to identify the major factors contributing to any overexposures. Toward this purpose, the National Institute for Occupational Safety and Health (NIOSH) developed a laser extinction method to measure real-time elemental carbon (EC) concentrations (EC is a DPM surrogate). To employ this method, NIOSH developed a person-wearable instrument that was commercialized in 2011. This paper evaluates this commercial instrument, including the calibration curve, limit of detection, accuracy, and potential interferences. The instrument was found to meet the NIOSH accuracy criteria and to be capable of measuring DPM concentrations at levels observed in underground mines. In addition, it was found that a submicron size selector was necessary to avoid interference from mine dust and that cigarette smoke can be an interference when sampling in enclosed cabs.

  20. Chemical Composition of Fine Particulate Matter and Life Expectancy

    Science.gov (United States)

    Dominici, Francesca; Wang, Yun; Correia, Andrew W.; Ezzati, Majid; Pope, C. Arden; Dockery, Douglas W.

    2016-01-01

    Background In a previous study, we provided evidence that a decline in fine particulate matter (PM2.5) air pollution during the period between 2000 and 2007 was associated with increased life expectancy in 545 counties in the United States. In this article, we investigated which chemical constituents of PM2.5 were the main drivers of the observed association. Methods We estimated associations between temporal changes in seven major components of PM2.5 (ammonium, sulfate, nitrate, elemental carbon matter, organic carbon matter, sodium, and silicon) and temporal changes in life expectancy in 95 counties between 2002 and 2007. We included US counties that had adequate chemical components of PM2.5 mass data across all seasons. We fitted single pollutant and multiple pollutant linear models, controlling for available socioeconomic, demographic, and smoking variables and stratifying by urban and nonurban counties. Results In multiple pollutant models, we found that: (1) a reduction in sulfate was associated with an increase in life expectancy; and (2) reductions in ammonium and sodium ion were associated with increases in life expectancy in nonurban counties only. Conclusions Our findings suggest that recent reductions in long-term exposure to sulfate, ammonium, and sodium ion between 2002 and 2007 are associated with improved public health. PMID:25906366

  1. Herbaceous plants as filters: Immobilization of particulates along urban street corridors

    International Nuclear Information System (INIS)

    Weber, Frauke; Kowarik, Ingo; Säumel, Ina

    2014-01-01

    Among air pollutants, particulate matter (PM) is considered to be the most serious threat to human health. Plants provide ecosystem services in urban areas, including reducing levels of PM by providing a surface for deposition and immobilization. While previous studies have mostly addressed woody species, we focus on herbaceous roadside vegetation and assess the role of species traits such as leaf surface roughness or hairiness for the immobilization of PM. We found that PM deposition patterns on plant surfaces reflect site-specific traffic densities and that strong differences in particulate deposition are present among species. The amount of immobilized PM differed according to particle type and size and was related to specific plant species traits. Our study suggests that herbaceous vegetation immobilizes a significant amount of the air pollutants relevant to human health and that increasing biodiversity of roadside vegetation supports air filtration and thus healthier conditions along street corridors. -- Highlights: • We assessed PM immobilization by common urban herbaceous roadside species. • PM deposition was related to traffic density and plant species traits. • Amount of PM deposited differed according to particle type and size. • Increasing biodiversity of roadside vegetation supports air filtration. -- Herbaceous urban roadside vegetation immobilizes particulate matter relevant to human health, thus supporting healthier conditions next to busy roads

  2. Particulates in the city background of Rotterdam, Netherlands; Fijn stof in de stadsachtergrond van Rotterdam

    Energy Technology Data Exchange (ETDEWEB)

    Voogt, M.; Keuken, M. [TNO Bouw en Ondergrond, Utrecht (Netherlands); Weijers, E.; Kraai, A. [ECN Biomassa, Kolen en Milieuonderzoek, Petten (Netherlands)

    2009-04-15

    The Dutch research programme particulate matter (Policy oriented research programme Particulate matter or BOP) has examined the city background of PM10 and PM2,5 in the Dutch city of Rotterdam. Currently, little is known about the variation in background concentrations among districts. The new European Directive has included an obligation to improve the city background in 2020 compared to 2010. It is not sufficiently clear, though, where the border lies between regional and urban background. Moreover, little is known about the uncertainties in the city background. In order to gain more insight, a study has been conducted of the spatial variability of the city background and the gradient of the regional background into the city background. This article presents the results of the study. [mk]. [Dutch] In het Nederlands onderzoeksprogramma fijn stof (Beleidsgeorienteerd Onderzoeksprogramma Particulate matter of BOP) is de stadsachtergrond van PM10 en PM2,5 in Rotterdam onderzocht. Er is echter nog weinig bekend over de variatie in de achtergrondconcentratie van wijk tot wijk. In de nieuwe Europese Richtlijn is een verplichting opgenomen om de stadsachtergrond in 2020 te verbeteren ten opzichte van 2010. Onvoldoende duidelijk is waar de grens tussen de regionale en stedelijke achtergrond ligt. Er is ook weinig bekend over de onzekerheid in de stadsachtergrond. Om meer inzicht te krijgen is onderzoek uitgevoerd naar de ruimtelijke variabiliteit van de stadsachtergrond en de gradient van de regionale achtergrond naar de stadsachtergrond. In dit artikel worden de resultaten van het onderzoek gepresenteerd.

  3. Role of dissolved and particulate cadmium in the accumulation of cadmium in cultured oysters (Crassostrea gigas)

    Energy Technology Data Exchange (ETDEWEB)

    Lekhi, Priyanka [Department of Chemistry, University of British Columbia, Vancouver, BC V6T 1Z4 (Canada)], E-mail: anka.lekhi@ubc.ca; Cassis, D. [Department of Earth and Ocean Sciences, University of British Columbia, Vancouver, BC V6T 1Z4 (Canada); Pearce, C.M. [Pacific Biological Station, Fisheries and Oceans Canada, Nanaimo, BC V9T 6N7 (Canada); Ebell, N. [Odyssey Shellfish Ltd., Nanoose Bay, BC V0R 9G0 (Canada); Maldonado, M.T. [Department of Earth and Ocean Sciences, University of British Columbia, Vancouver, BC V6T 1Z4 (Canada); Orians, K.J. [Department of Chemistry, University of British Columbia, Vancouver, BC V6T 1Z4 (Canada); Department of Earth and Ocean Sciences, University of British Columbia, Vancouver, BC V6T 1Z4 (Canada)

    2008-04-15

    Pacific oysters (Crassostrea gigas) collected on the coast of British Columbia, Canada have occasionally shown cadmium (Cd) concentrations at or above 2 {mu}g g{sup -1} (wet weight), which has resulted in the loss of some international markets. This study investigated the source and transfer of Cd to oysters by focusing on the role of dissolved and particulate Cd in seawater. Parameters monitored for 1 year at two oyster farm sites on Vancouver Island included: oyster tissue mass and shell length, Cd in oysters, dissolved Cd, particulate Cd, temperature and salinity. Results show that dissolved Cd was the main source of Cd to the oysters and that Cd was mainly concentrated in the gut tissues. A seasonal trend was observed in Cd in oysters, in which levels were lowest during periods of higher temperatures. Results also indicate that the local oceanographic inputs and sediment diagenesis directly affect dissolved Cd and thereby influence the Cd levels in oysters. Particulate matter was not found to be a source of Cd in oysters, and was actually negatively correlated. This was likely due to the uptake of dissolved Cd by phytoplankton and the effect of phytoplankton on oyster tissue mass.

  4. The cytotoxicity and genotoxicity of particulate and soluble hexavalent chromium in leatherback sea turtle lung cells.

    Science.gov (United States)

    Speer, Rachel M; Wise, Catherine F; Young, Jamie L; Aboueissa, AbouEl-Makarim; Martin Bras, Mark; Barandiaran, Mike; Bermúdez, Erick; Márquez-D'Acunti, Lirio; Wise, John Pierce

    2018-05-01

    Hexavalent chromium [Cr(VI)] is a marine pollution of concern as recent studies show it has a global distribution, with some regions showing high Cr concentrations in marine animal tissue, and it is extensively used. Leatherback sea turtles (Dermochelys coriacea) are an endangered marine species that may experience prolonged exposures to environmental contaminants including Cr(VI). Human activities have led to global Cr(VI) contamination of the marine environment. While Cr(VI) has been identified as a known human carcinogen, the health effects in marine species are poorly understood. In this study, we assessed the cytotoxic and genotoxic effects of particulate and soluble Cr(VI) in leatherback sea turtle lung cells. Both particulate and soluble Cr(VI) induced a concentration-dependent increase in cytotoxicity. Next, using a chromosome aberration assay, we assessed the genotoxic effects of Cr(VI) in leatherback sea turtle lung cells. Particulate and soluble Cr(VI) induced a concentration-dependent increase in clastogenicity in leatherback sea turtle lung cells. These data indicate that Cr(VI) may be a health concern for leatherback sea turtles and other long-lived marine species. Additionally, these data provide foundational support to use leatherback sea turtles as a valuable model species for monitoring the health effects of Cr(VI) in the environment and possibly as an indicator species to assess environmental human exposures and effects. Copyright © 2018 Elsevier B.V. All rights reserved.

  5. Particulate Matter Emission from Dual Fuel Diesel Engine Fuelled with Natural Gas

    Directory of Open Access Journals (Sweden)

    Stelmasiak Zdzisław

    2017-06-01

    Full Text Available The paper presents the results of examination of particulate matter emission from the Diesel engine FPT 1.3 MJT simultaneously fuelled with diesel oil and natural gas CNG. The basic premise for engine adaptation was the addition of a small amount of CNG to reduce exhaust gas opacity and particulate matter emission. At this assumption, diesel oil remained the basic fuel, with contribution amounting to 0,70-0,85 of total energy delivered to the engine. The dual fuel engine was examined using an original controller installed in the Diesel engine FPT 1.3 MJT which controlled the diesel fuel dose. The dose of the injected natural gas was controlled by changing the opening time of gas injectors at constant pressure in the gas collector. The examined issues included the exhaust gas opacity, and the total number and fractional distribution of the emitted particles. The measurements were performed at twenty selected measuring points corresponding to the New European Driving Cycle (NEDC test. The performed tests have demonstrated a positive effect of gas addition on exhaust gas opacity and particulate matter emission. Depending on test conditions, the exhaust gas opacity was reduced by 10÷92%, and the total number of particles by 30÷40%. The performed tests have revealed that a small addition of gas can reduce the load of the DPF filter, extend its lifetime, and increase engine reliability. Longer time intervals between successive DPF filter regenerations improve ecological properties of the engine.

  6. Sampling and analytical methodologies for energy dispersive X-ray fluorescence analysis of airborne particulate matter

    International Nuclear Information System (INIS)

    1993-01-01

    The present document represents an attempt to summarize the most important features of the different forms of ED-XFR as applied to the analysis of airborne particulate matter. It is intended to serve as a set of guidelines for use by participants in the IAEA's own programmes, and other scientists, who are not yet fully experienced in the application of ED-XRF to airborne particulate samples, and who wish either to make a start on using this technique or to improve their existing procedures. The methodologies for sampling described in this document are of rather general applicability. Emphasis is also placed on the sources of errors affecting the sampling of airborne particulate matter. The analytical part of the document describes the different forms of ED-XRF and their potential applications. Spectrum evaluation, a key step in X-ray spectrometry, is covered in depth, including discussion on several calibration and peak fitting techniques and computer programs especially designed for this purpose. 148 refs, 25 figs, 13 tabs

  7. Role of dissolved and particulate cadmium in the accumulation of cadmium in cultured oysters (Crassostrea gigas)

    International Nuclear Information System (INIS)

    Lekhi, Priyanka; Cassis, D.; Pearce, C.M.; Ebell, N.; Maldonado, M.T.; Orians, K.J.

    2008-01-01

    Pacific oysters (Crassostrea gigas) collected on the coast of British Columbia, Canada have occasionally shown cadmium (Cd) concentrations at or above 2 μg g -1 (wet weight), which has resulted in the loss of some international markets. This study investigated the source and transfer of Cd to oysters by focusing on the role of dissolved and particulate Cd in seawater. Parameters monitored for 1 year at two oyster farm sites on Vancouver Island included: oyster tissue mass and shell length, Cd in oysters, dissolved Cd, particulate Cd, temperature and salinity. Results show that dissolved Cd was the main source of Cd to the oysters and that Cd was mainly concentrated in the gut tissues. A seasonal trend was observed in Cd in oysters, in which levels were lowest during periods of higher temperatures. Results also indicate that the local oceanographic inputs and sediment diagenesis directly affect dissolved Cd and thereby influence the Cd levels in oysters. Particulate matter was not found to be a source of Cd in oysters, and was actually negatively correlated. This was likely due to the uptake of dissolved Cd by phytoplankton and the effect of phytoplankton on oyster tissue mass

  8. Assessing the impacts of ethanol and isobutanol on gaseous and particulate emissions from flexible fuel vehicles.

    Science.gov (United States)

    Karavalakis, Georgios; Short, Daniel; Russell, Robert L; Jung, Heejung; Johnson, Kent C; Asa-Awuku, Akua; Durbin, Thomas D

    2014-12-02

    This study investigated the effects of higher ethanol blends and an isobutanol blend on the criteria emissions, fuel economy, gaseous toxic pollutants, and particulate emissions from two flexible-fuel vehicles equipped with spark ignition engines, with one wall-guided direct injection and one port fuel injection configuration. Both vehicles were tested over triplicate Federal Test Procedure (FTP) and Unified Cycles (UC) using a chassis dynamometer. Emissions of nonmethane hydrocarbons (NMHC) and carbon monoxide (CO) showed some statistically significant reductions with higher alcohol fuels, while total hydrocarbons (THC) and nitrogen oxides (NOx) did not show strong fuel effects. Acetaldehyde emissions exhibited sharp increases with higher ethanol blends for both vehicles, whereas butyraldehyde emissions showed higher emissions for the butanol blend relative to the ethanol blends at a statistically significant level. Particulate matter (PM) mass, number, and soot mass emissions showed strong reductions with increasing alcohol content in gasoline. Particulate emissions were found to be clearly influenced by certain fuel parameters including oxygen content, hydrogen content, and aromatics content.

  9. Particulate air pollution and mortality in a cohort of Chinese men

    International Nuclear Information System (INIS)

    Zhou, Maigeng; Liu, Yunning; Wang, Lijun; Kuang, Xingya; Xu, Xiaohui; Kan, Haidong

    2014-01-01

    Few prior cohort studies exist in developing countries examining the association of ambient particulate matter (PM) with mortality. We examined the association of particulate air pollution with mortality in a prospective cohort study of 71,431 middle-aged Chinese men. Baseline data were obtained during 1990–1991. The follow-up evaluation was completed in January, 2006. Annual average PM exposure between 1990 and 2005, including TSP and PM 10 , were estimated by linking fixed-site monitoring data with residential communities. We found significant associations between PM 10 and mortality from cardiopulmonary diseases; each 10 μg/m 3 PM 10 was associated with a 1.6% (95%CI: 0.7%, 2.6%), 1.8% (95%CI: 0.8%, 2.9%) and 1.7% (95%CI: 0.3%, 3.2%) increased risk of total, cardiovascular and respiratory mortality, respectively. For TSP, we observed significant associations only for cardiovascular morality. These data contribute to the scientific literature on long-term effects of particulate air pollution for high exposure settings typical in developing countries. -- Highlights: • There have been few air pollution cohort studies in developing countries. • PM 10 was associated with increased cardiorespiratory mortality in 71,431 Chinese men. • PM was not significantly associated with lung cancer mortality. -- PM 10 was associated with increased cardiorespiratory mortality in a cohort of 71,431 Chinese men

  10. Particulate air pollution and mortality in a cohort of Chinese men.

    Science.gov (United States)

    Zhou, Maigeng; Liu, Yunning; Wang, Lijun; Kuang, Xingya; Xu, Xiaohui; Kan, Haidong

    2014-03-01

    Few prior cohort studies exist in developing countries examining the association of ambient particulate matter (PM) with mortality. We examined the association of particulate air pollution with mortality in a prospective cohort study of 71,431 middle-aged Chinese men. Baseline data were obtained during 1990-1991. The follow-up evaluation was completed in January, 2006. Annual average PM exposure between 1990 and 2005, including TSP and PM10, were estimated by linking fixed-site monitoring data with residential communities. We found significant associations between PM10 and mortality from cardiopulmonary diseases; each 10 μg/m(3) PM10 was associated with a 1.6% (95%CI: 0.7%, 2.6%), 1.8% (95%CI: 0.8%, 2.9%) and 1.7% (95%CI: 0.3%, 3.2%) increased risk of total, cardiovascular and respiratory mortality, respectively. For TSP, we observed significant associations only for cardiovascular morality. These data contribute to the scientific literature on long-term effects of particulate air pollution for high exposure settings typical in developing countries. Copyright © 2013 Elsevier Ltd. All rights reserved.

  11. Exposure to airborne metals and particulate matter and risk for youth adjudicated for criminal activity

    Energy Technology Data Exchange (ETDEWEB)

    Haynes, Erin N., E-mail: Erin.Haynes@uc.edu [College of Medicine, Department of Environmental Health, University of Cincinnati, Cincinnati, OH 45267 (United States); Chen, Aimin, E-mail: Aimin.Chen@uc.edu [College of Medicine, Department of Environmental Health, University of Cincinnati, Cincinnati, OH 45267 (United States); Ryan, Patrick, E-mail: Patrick.Ryan@uc.edu [College of Medicine, Department of Environmental Health, University of Cincinnati, Cincinnati, OH 45267 (United States); Succop, Paul, E-mail: Paul.Succop@uc.edu [College of Medicine, Department of Environmental Health, University of Cincinnati, Cincinnati, OH 45267 (United States); Wright, John, E-mail: John.Wright@uc.edu [College of Education, Criminal Justice, and Human Services, University of Cincinnati, Cincinnati, OH 45221 (United States); Dietrich, Kim N., E-mail: Kim.Dietrich@uc.edu [College of Medicine, Department of Environmental Health, University of Cincinnati, Cincinnati, OH 45267 (United States)

    2011-11-15

    significance. In summary, airborne exposure to manganese, mercury, and particulate matter are associated with increased risk of adjudication. Causality cannot be proven in observational studies such as this one, but the association warrants further examination in other research studies. Comprehensive epidemiologic investigations of metal exposure in pediatric populations should include social health outcomes, including measures of delinquent or criminal activity. Furthermore, the influence of metals on the neurotoxic pathway leading to delinquent activity should be further explored. - Highlights: Black-Right-Pointing-Pointer We evaluate the relationship between air pollutants and adjudication. Black-Right-Pointing-Pointer Manganese, mercury, and particulate matter are associated with risk of adjudication. Black-Right-Pointing-Pointer Further research of metal exposure should include social health outcomes.

  12. Exposure to airborne metals and particulate matter and risk for youth adjudicated for criminal activity

    International Nuclear Information System (INIS)

    Haynes, Erin N.; Chen, Aimin; Ryan, Patrick; Succop, Paul; Wright, John; Dietrich, Kim N.

    2011-01-01

    significance. In summary, airborne exposure to manganese, mercury, and particulate matter are associated with increased risk of adjudication. Causality cannot be proven in observational studies such as this one, but the association warrants further examination in other research studies. Comprehensive epidemiologic investigations of metal exposure in pediatric populations should include social health outcomes, including measures of delinquent or criminal activity. Furthermore, the influence of metals on the neurotoxic pathway leading to delinquent activity should be further explored. - Highlights: ► We evaluate the relationship between air pollutants and adjudication. ► Manganese, mercury, and particulate matter are associated with risk of adjudication. ► Further research of metal exposure should include social health outcomes.

  13. Exposure assessment of particulates originating from diesel and CNG fuelled engines

    Energy Technology Data Exchange (ETDEWEB)

    Oravisjaervi, K.; Pietikaeinen, M.; Keiski, R. L. (Univ. of Oulu, Dept. of Process and Environmental Engineering (Finland)). email: kati.oravisjarvi@oulu.fi; Voutilainen, A. (Univ. of Kuopio, Dept. of Physics (Finland)); Haataja, M. (Oulu Univ. of Applied Sciences (Finland); Univ. of Oulu, Dept. of Mechanical Engineering (Finland)); Ruuskanen, J. (Univ. of Kuopio, Dept. of Environmental Sciences (Finland)); Rautio, A. (Univ. of Oulu, Thule Inst. (Finland))

    2009-07-01

    given mass, and the surface may be able to act as a catalyst for specific reactions with cells or as a carrier for co-pollutants. They also penetrate deeper into the lungs. Hydrocarbons, as lipid soluble compounds, can also penetrate the cell membranes of the lung cells, enter into the blood circulation and influence the whole organ system, even reach the brain. The aim of this study was to compare children's exposure to diesel and compressed natural gas (CNG) exhaust particulates, which have been formed and then distributed into the human lung. Particulate measurements were carried out in the Technical Research Centre of Finland for two Euro 2 diesel buses with an oxidation catalyst on one and a partial-DPF catalyst on the other vehicle (DI-OC and DI-pDPF, respectively), and one Euro 3 natural gas bus with an oxidation catalyst on the vehicle (CNG-OC). For the evaluation of particulate emissions in an urban bus route the Braunschweig City Driving Cycle, a transient chassis dynamometer test cycle was used. Particulate number size distributions were measured using an Electric Low Pressure Impactor (ELPI) instrument (Dekati Ltd, Finland) with the size range of 7 nm to 10 mum. The ELPI measurement system yields particulate number concentrations in 12 nonoverlapping size bins covering the whole measurement size range. Estimation of deposited particles into human lung system was computed with a lung deposition model based on a ICRP 66 lung deposition model published by the International Commission on Radiological Protection (ICRP). The model includes specific information related to the subjects (including age, ventilation rate, breathing pattern, gender). The respiratory tract is divided into five main deposition regions: the anterior nasal region (ET1), the main extra thoracic region (ET2, including the posterior nasal region, mouth, pharynx and larynx), the bronchial region (BB, consisting of the trachea and bronchi), the bronchiolar region (bb, consisting of the

  14. Identification of the mechanisms that drive the toxicity of TiO2 particulates: the contribution of physicochemical characteristics

    Directory of Open Access Journals (Sweden)

    Peters Sheona

    2009-12-01

    Full Text Available Abstract This review focuses on outlining the toxicity of titanium dioxide (TiO2 particulates in vitro and in vivo, in order to understand their ability to detrimentally impact on human health. Evaluating the hazards associated with TiO2 particles is vital as it enables risk assessments to be conducted, by combining this information with knowledge on the likely exposure levels of humans. This review has concentrated on the toxicity of TiO2, due to the fact that the greatest number of studies by far have evaluated the toxicity of TiO2, in comparison to other metal oxide particulates. This derives from historical reasons (whereby the size dependency of particulate toxicity was first realised for TiO2 and due to its widespread application within consumer products (such as sunscreens. The pulmonary and dermal hazards of TiO2 have been a particular focus of the available studies, due to the past use of TiO2 as a (negative control when assessing the pulmonary toxicity of particulates, and due to its incorporation within consumer products such as sunscreens. Mechanistic processes that are critical to TiO2 particulate toxicity will also be discussed and it is apparent that, in the main, the oxidant driven inflammatory, genotoxic and cytotoxic consequences associated with TiO2 exposure, are inherently linked, and are evident both in vivo and in vitro. The attributes of TiO2 that have been identified as being most likely to drive the observed toxicity include particle size (and therefore surface area, crystallinity (and photocatalytic activity, surface chemistry, and particle aggregation/agglomeration tendency. The experimental set up also influences toxicological outcomes, so that the species (or model used, route of exposure, experiment duration, particle concentration and light conditions are all able to influence the findings of investigations. In addition, the applicability of the observed findings for particular TiO2 forms, to TiO2 particulates in

  15. Workbook on reactor neutron activation analysis (NAA) of airborne particulate matter (APM)

    International Nuclear Information System (INIS)

    Tian Weizhi

    2000-01-01

    This publication presents general aspects of reactor neutron activation analysis (NAA) applied to measurement of elemental composition of airborne particulate matter. It presents an introduction to the NAA, its' basic principles and brief history of the method and discusses its' advantages and disadvantages. This publication also presents experimental procedures of NAA including sampling and sample preparation; preparation of calibration standard samples; reactor neutron irradiation; gamma-spectroscopy of the irradiated samples; quantification and presentation of analytical results. The publication pays attention to the quality assurance and quality control procedures including internal quality control, analysis of certified reference materials, and interlaboratory and multi-method comparison studies, control charts

  16. Electrically resistive coating for remediation (regeneration) of a diesel particulate filter and method

    Science.gov (United States)

    Phelps, Amanda C [Malibu, CA; Kirby, Kevin K [Calabasas Hills, CA; Gregoire, Daniel J [Thousand Oaks, CA

    2012-02-14

    A resistively heated diesel particulate filter (DPF). The resistively heated DPF includes a DPF having an inlet surface and at least one resistive coating on the inlet surface. The at least one resistive coating is configured to substantially maintain its resistance in an operating range of the DPF. The at least one resistive coating has a first terminal and a second terminal for applying electrical power to resistively heat up the at least one resistive coating in order to increase the temperature of the DPF to a regeneration temperature. The at least one resistive coating includes metal and semiconductor constituents.

  17. On-road particulate emission measurement

    Science.gov (United States)

    Mazzoleni, Claudio

    Particulate matter (PM) suspended in the atmosphere has harmful health effects, contributes to visibility impairment, and affects atmospheric radiative transfer, thereby contributing to global change. Vehicles contribute substantially to the ambient PM concentration in urban areas, yet the fraction of ambient PM originating from vehicle emissions is poorly characterized because suitable measurement methods have not been available. This dissertation describes the development and the use of a new vehicle emission remote sensing system (VERSS) for the on-road measurement of PM emission factors for vehicles. The PM VERSS measures PM by ultraviolet backscattering and transmission. PM backscattering and transmission mass efficiencies have been calculated from Mie theory based on an homogeneous spherical model for gasoline particles and on a two-layers, spherical model for diesel particles. The VERSS was used in a large-scale study in Las Vegas, NV. A commercial gaseous VERSS was used for the measurement of gaseous emission factors (i.e., carbon monoxide, hydrocarbons, and nitrogen oxide). Speed and acceleration were also measured for each vehicle. A video image of each vehicle's rear license plate was acquired and license plate numbers were matched with the Clark County department of motor vehicle database to retrieve vehicle information such as model year, vehicle weight category and engine ignition type. PM VERSS has precisely estimated PM fleet average emission factors and clearly shown the dependence of PM emission factors on vehicle model year. Under mostly hot-stabilized operation, diesel vehicle PM emission factors are about 25 times higher than those of gasoline vehicles. Furthermore, the fleet frequency distributions of PM emission factors are highly skewed, meaning that most of the fleet emission factor is accounted for by a small portion of the fleet. The PM VERSS can measure PM emission factors for these high emitting vehicles on an individual basis. PM

  18. Diesel engine exhaust particulate filter with intake throttling incineration control

    Energy Technology Data Exchange (ETDEWEB)

    Ludecke, O.; Rosebrock, T.

    1980-07-08

    A description is given of a diesel engine exhaust filter and particulate incineration system in combination with a diesel engine having a normally unthrottled air induction system for admitting combustion air to the engine and an exhaust system for carrying off spent combustion products exhausted from the engine, said filter and incineration system comprising: a combustion resistant filter disposed in the exhaust system and operative to collect and retain portions of the largely carbonaceous particulate matter contained in the engine exhaust products, said fiber being capable of withstanding without substantial damage internal temperatures sufficient to burn the collected particulate matter, a throttle in the indication system and operable to restrict air flow into the engine to reduce the admittance of excess combustion air and thereby increase engine exhaust gas temperature, and means to actuate said throttle periodically during engine operation to an air flow restricting burn mode capable of raising the particulates in said filter to their combustion temperature under certain engine operating conditions and to maintain said throttle mode for an interval adequate to burn retained particulates in the filter.

  19. Laboratory Measurements of Particulate Matter Concentrations from Asphalt Pavement Abrasion

    Directory of Open Access Journals (Sweden)

    Fullová Daša

    2016-12-01

    Full Text Available The issue of emissions from road traffic is compounded by the fact that the number of vehicles and driven kilometres increase each year. Road traffic is one of the main sources of particulate matter and traffic volume is still increasing and has unpleasant impact on longevity of the pavements and the environment. Vehicle motions cause mechanical wearing of the asphalt pavement surface - wearing course by vehicle tyres. The contribution deals with abrasion of bituminous wearing courses of pavements. The asphalt mixtures of wearing courses are compared in terms of mechanically separated particulate matter. The samples of asphalt mixtures were rutted in wheel tracking machine. The particulate matter measurements were performed in laboratory conditions. The experimental laboratory measurements make it possible to sample particulates without contamination from exhaust emissions, abraded particles from vehicles, resuspension of road dust and climate affects. The contribution offers partial results of measurements on six trial samples of asphalt mixtures with different composition. It presents particulate matter morphology and the comparison of rutted asphalt samples in terms of PM mass concentrations and chemical composition.

  20. Semivolatile Particulate Organic Material Southern Africa during SAFARI 2000

    Science.gov (United States)

    Eatough, D. J.; Eatough, N. L.; Pang, Y.; Sizemore, S.; Kirchstetter, T. W.; Novakov, T.

    2005-01-01

    During August and September 2000, the University of Washington's Cloud and Aerosol Research Group (CARG) with its Convair-580 research aircraft participated in the Southern African Fire-Atmosphere Research Initiative (SAFARI) 2000 field study in southern Africa. Aboard this aircraft was a Particle Concentrator-Brigham Young University Organic Sampling System (PC-BOSS), which was used to determine semivolatile particulate material with a diffusion denuder sampler. Denuded quartz filters and sorbent beds in series were used to measure nonvolatile and semivolatile materials, respectively. Results obtained with the PC-BOSS are compared to those obtained with conventional quartz-quartz and Teflon-quartz filter pack samplers. Various 10-120 min integrated samples were collected during flights through the h e troposphere, in the atmospheric boundary layer, and in plumes from savanna fires. Significant fine particulate semivolatile organic compounds (SVOC) were found in all samples. The SVOC was not collected by conventional filter pack samplers and therefore would not have been determined in previous studies that used only filter pack samplers. The SVOC averaged 24% of the fine particulate mass in emissions from the fires and 36% of the fine particulate mass in boundary layer samples heavily impacted by aged emissions from savanna fires. Concentrations of fine particulate material in the atmospheric mixed layer heavily impacted by aged savanna frre emissions averaged 130 micrograms per cubic meter. This aerosol was 85% carbonaceous mated.

  1. Magnetic Approaches to Measuring and Mitigating Airborne Particulate Pollution

    Science.gov (United States)

    Maher, B.

    2014-12-01

    Human exposure to airborne particulate matter (PM) generates adverse human health impacts at all life stages from the embryonic to the terminal, including damage to respiratory and cardiovascular health, and neurodevelopment and cognitive function. Detailed understanding of the causal links between PM exposure and specific health impacts, and possible means to reduce PM exposure require knowledge of PM concentrations, compositions and sources at the fine-scale; i.e. beyond the current resolution of spatially-sparse conventional PM monitoring, non-unique elemental analyses, or poorly-validated PM modelling. Magnetically-ordered iron oxide minerals appear to be a ubiquitous component of urban PM. These minerals derive partly from the presence of iron impurities in fuels, which form, upon combustion, a non-volatile residue, often dominated by magnetite, within glassy, spherical condensates. Iron-rich, magnetic PM also arises from abrasion from vehicle components, including disk brakes, and road dust. The ubiquity and diversity of these magnetic PM phases, and the speed and sensitivity of magnetic analyses (down to trace concentrations), makes possible rapid, cost-effective magnetic characterization and quantification of PM, a field of study which has developed rapidly across the globe over the last 2 decades. Magnetic studies of actively-sampled PM, on filters, and passively-sampled PM, on tree leaves and other depositional surfaces, can be used to: monitor and map at high spatial resolution ambient PM concentrations; address the controversial issue of the efficacy of PM capture by vegetation; and add a new, discriminatory dimension to PM source apportionment.

  2. Ambient particulate matter air pollution and cardiopulmonary diseases.

    Science.gov (United States)

    Thurston, George; Lippmann, Morton

    2015-06-01

    Population exposures to ambient outdoor particulate matter (PM) air pollution have been assessed to represent a major burden on global health. Ambient PM is a diverse class of air pollution, with characteristics and health implications that can vary depending on a host of factors, including a particle's original source of emission or formation. The penetration of inhaled particles into the thorax is dependent on their deposition in the upper respiratory tract during inspiration, which varies with particle size, flow rate and tidal volume, and in vivo airway dimensions. All of these factors can be quite variable from person to person, depending on age, transient illness, cigarette smoke and other short-term toxicant exposures that cause transient bronchoconstriction, and occupational history associated with loss of lung function or cumulative injury. The adverse effects of inhaled PM can result from both short-term (acute) and long-term (chronic) exposures to PM, and can range from relatively minor, such as increased symptoms, to very severe effects, including increased risk of premature mortality and decreased life expectancy from long-term exposure. Control of the most toxic PM components can therefore provide major health benefits, and can help guide the selection of the most human health optimal air quality control and climate change mitigation policy measures. As such, a continued improvement in our understanding of the nature and types of PM that are most dangerous to health, and the mechanism(s) of their respective health effects, is an important public health goal. Thieme Medical Publishers 333 Seventh Avenue, New York, NY 10001, USA.

  3. EDITORIAL: Global impacts of particulate matter air pollution

    Science.gov (United States)

    Bell, Michelle L.; Holloway, Tracey

    2007-10-01

    Even in well-studied, data-rich regions of the United States and Europe, understanding ambient particulate matter (PM, aka aerosols) remains a challenge. Atmospheric aerosols exhibit chemical heterogeneity, spatial and seasonal variability, and result in a wide range of health impacts (mortality, respiratory disease, cardiovascular disease, eye irritation, and others). In addition, aerosols play an important role in climate, exerting warming effects (black carbon), cooling effects (sulfate and organic carbon), and affecting precipitation and cloud cover. Characterizing the emission sources, concentrations, transport patterns, and impacts is particularly difficult in developing countries, where data are scarce, emissions are high, and health impacts are often severe. We are pleased to present this focus issue of Environmental Research Letters (ERL) devoted to the study of PM on an international scale. Our authors are leading researchers who each bring cross-cutting analysis to this critical health and environmental issue. Collectively, the research presented here contributes to our understanding of PM sources, processes, and impacts, while highlighting key steps forward. In this issue, Zhang et al examine the size distribution and composition of emitted anthropogenic PM in China, finding that the characteristics of primary aerosol emissions differ significantly between industrialized and developing regions in China. Concentration measurements of PM, like detailed emissions inventories, are rare in the developing world. van Vliet and Kinney analyze fine particles in Nairobi based on monitoring data for PM2.5 and black carbon. Using measurements from multiple locations of differing proximity to roadways, the authors evaluate traffic-source contributions to PM exposure. The impact of emission location and exposed population are also evaluated by Liu and Mauzerall, but on a continent-to-continent scale. The authors quantify the connection between SO2 emissions and

  4. Evaluation of airborne particulate matter pollution in Kenitra City, Morocco

    Directory of Open Access Journals (Sweden)

    Abdelfettah Benchrif

    2013-04-01

    Full Text Available Two size fractions of atmospheric particulate matter < 2.5 µm and 2.5-10 µm were collected in Kenitra City from February 2007 to February 2008. The sampling was done using a Gent Stacked sampler on nuclepore polycarbonate filters and the collected filters were analyzed using Total Reflection X-Ray Fluorescence (TXRF and Atomic Absorption Spectroscopy (AAS. The particulate matter trends show higher concentrations during the summer as compared to other seasons. The highest concentrations were obtained for Ca in coarse particles and Fe for fine particles. However, the lowest concentrations were observed for Cd in both particulate sizes. The principal component analysis (PCA based on multivariate study enabled the identification of soil, road dust and traffic emissions as common sources for coarse and fine particles.

  5. Gaseous and particulate air pollutants in the Northeastern Mediterranean Coast

    International Nuclear Information System (INIS)

    Soner Erduran, M.; Tuncel, Semra G.

    2001-01-01

    The concentrations of sulfur dioxide (SO 2 ), ammonia (NH 3 ) and particulate matter were measured for a 6-month period and the concentration of gas phase nitric acid (HNO 3 ) was measured for a 1-month period in the North-eastern Mediterranean atmosphere (Kuecuek Calticak, Antalya) using a 'filter pack' system that was developed and optimised in our laboratory. Among all the gas phase pollutants, HNO 3 had the lowest concentration (0.42 μg m -3 ) followed by ammonia. Most of the measured parameters showed variation in time depending on strengths of source regions and meteorological conditions. Nitric acid is found mostly in particulate form, but gas to particulate partitioning of SO 2 shows seasonal variation. Wind trajectory analyses indicate that the major contribution to the observed concentrations come mostly from Eastern Europe and Blacksea regions as well as the southern sector

  6. Characterization of the particulate air pollution in contrasted mega cities

    International Nuclear Information System (INIS)

    Favez, O.

    2008-02-01

    This work aims at characterizing the physics and the chemistry that govern particulate air pollution in two mega cities (Paris and Cairo) for which the size distribution and the chemical composition of airborne particles were poorly documented. Seasonal variations of the main aerosol sources and transformation processes are investigated in these two urban centres, with a particular attention to semi-volatile material and secondary organic aerosols. Short-term health effects of Paris size-segregated aerosols, as well as particulate pollution during the Cairo 'Black Cloud' season, are also emphasized here. Finally, the comparison of results obtained for the two mega cities and for another one (Beijing) allows investigating main factors responsible for particulate air pollution in urban centres with contrasted climatic conditions and development levels. Notably, this work also allows the build-up of an experimental dataset which is now available for the modelling of urban air quality and of environmental impacts of mega city air pollution. (author)

  7. Samplings of urban particulate matter for mutagenicity assays

    International Nuclear Information System (INIS)

    De Zaiacono, T.

    1996-07-01

    In the frame of a specific program relating to the evaluation of mutagenic activity of urban particulate matter, an experimental arrangement has been developed to sample aerosuspended particles from the external environment carried indoor by means of a fan. Instrumentation was placed directly in the air flow to minimize particle losses, and consisted of total filter, collecting particles without any size separation; cascade impactor, fractioning urban particulate to obtain separate samples for analyses; an optical device, for real time monitoring of aerosol concentration, temperature and relative humidity sensors. Some of the samples obtained were analysed to investigate: particle morphology, aerosol granulometric distributions, effect of relative humidity on collected particulate, amount of ponderal mass compared with real time optical determinations. The results obtained are reported here, together with some considerations about carbonaceous particles, in urban areas mainly originated from diesel exhausts, their degree of agglomeration and role to vehiculate substances into the human respiratory

  8. Particulate and carbon monoxide emissions from small scale firewood combustion

    International Nuclear Information System (INIS)

    Todd, J.J.

    1990-01-01

    One of the serious adverse effects of residential firewood use is the deterioration in air quality caused by wood-smoke. Low combustion zone temperatures, flame quenching, poor gas mixing, and lack of oxygen all contribute to relatively high emissions of particulates and CO. Average emission rates for particulates of 11 g/h for modern woodheaters can certainly be improved upon. More research effort is needed to reduce emissions from cooking stoves used in developing countries and more public information on correct heater use is needed in the developed countries. (author)

  9. Particulate air pollution, with emphasis on traffic generated aerosols

    DEFF Research Database (Denmark)

    Fauser, Patrik

    constitute each about 5 wt-% of the collected suspended particulate matter in inner city air. The particle size distribution shows that 92 % of the mass of airborne particulate tire debris have aerodynamic diameters smaller than 1 µm. The mean aerodynamic diameter is about 1 µm for the bitumen particles...... % of this concentration derives from adsorbed particles on both leaf sides. The remainder is either respired through stomata or incorporated in the epicuticular wax layer. The fact that a substantial amount of the airborne tire and bitumen particles occur in the submicron range permits long range transportation...

  10. Role of oxidative damage in toxicity of particulates

    DEFF Research Database (Denmark)

    Møller, Peter; Jacobsen, Nicklas R; Folkmann, Janne K

    2010-01-01

    composition play important roles in the oxidative potential of particulates. Studies in animal models indicate that particles from combustion processes (generated by combustion of wood or diesel oil), silicate, titanium dioxide and nanoparticles (C60 fullerenes and carbon nanotubes) produce elevated levels......Particulates are small particles of solid or liquid suspended in liquid or air. In vitro studies show that particles generate reactive oxygen species, deplete endogenous antioxidants, alter mitochondrial function and produce oxidative damage to lipids and DNA. Surface area, reactivity and chemical...

  11. Report on fine particulates and ozone in Quebec in connection with the Canada Wide Standard : 2009 report

    International Nuclear Information System (INIS)

    Busque, D.; Bisson, M.; Paradis, J.; Proulx, M.; Guay, M.

    2010-05-01

    In June 2000, the federal and provincial governments, with the exception of Quebec, adopted a Canada Wide Standard (CWS) for particulates and ozone and set out to reduce these pollutants by 2010. Although Quebec was not a signatory to the CWS, it acts in coherence with the other governments regarding these air quality standards. Ozone and particulates are the main precursors to smog and are known to cause health and environmental problems. Ozone forms when nitrogen oxides and volatile organic compounds (VOCs) chemically react, particularly during hot sunny days. The CWS is a strategy to reduce the risk of these pollutants to public health and the environment. In order to apply this standard, Quebec must verify conformity for regions with a population of more than 100,000, which includes 6 regions, notably Montreal, Quebec City, Gatineau, the Saguenay, Sherbrooke and Trois Rivieres. Results of a 2008 study showed that air quality in Gatineau and 3 subregions of Montreal exceeded the allow limit of 65 ppb for ozone. However, ozone concentrations in Quebec City, the Saguenay, Sherbrooke and Trois Rivieres were under the allowable limits. Results of the 2008 study showed that particulate concentration in all regions were blow the allowable limits. This document revealed that there has been an improvement in air quality in terms of ozone and particulates since 2005. Most regions in Quebec were under the allowable limits projected for 2010. 7 refs., 1 tab., 6 figs., 6 appendices.

  12. Distribution and seasonal variation of concentrations of particulate carbohydrates and uronic acids in the northern Indian Ocean

    Digital Repository Service at National Institute of Oceanography (India)

    Khodse, V.B.; Fernandes, L.; Gopalakrishna, V.V.; Bhosle, N.B.; Fernandes, V.; Matondkar, S.G.P.; Bhushan, R.

    particulate carbohydrate (TPCHO), total particulate uronic acid (TPURA) and total particulate neutral carbohydrate (TPNCHO) concentrations and composition. Strong spatial, temporal and depth related variations were evident in the distribution...

  13. New Approach to Monitor Transboundary Particulate Pollution over Northeast Asia

    Science.gov (United States)

    Park, M. E.; Song, C. H.; Park, R. S.; Lee, Jaehwa; Kim, J.; Lee, S.; Woo, J. H.; Carmichael, G. R.; Eck, Thomas F.; Holben, Brent N.; hide

    2014-01-01

    A new approach to more accurately monitor and evaluate transboundary particulate matter (PM) pollution is introduced based on aerosol optical products from Korea's Geostationary Ocean Color Imager (GOCI). The area studied is Northeast Asia (including eastern parts of China, the Korean peninsula and Japan), where GOCI has been monitoring since June 2010. The hourly multi-spectral aerosol optical data that were retrieved from GOCI sensor onboard geostationary satellite COMS (Communication, Ocean, and Meteorology Satellite) through the Yonsei aerosol retrieval algorithm were first presented and used in this study. The GOCI-retrieved aerosol optical data are integrated with estimated aerosol distributions from US EPA Models-3/CMAQ (Community Multi-scale Air Quality) v4.5.1 model simulations via data assimilation technique, thereby making the aerosol data spatially continuous and available even for cloud contamination cells. The assimilated aerosol optical data are utilized to provide quantitative estimates of transboundary PM pollution from China to the Korean peninsula and Japan. For the period of 1 April to 31 May, 2011 this analysis yields estimates that AOD as a proxy for PM2.5 or PM10 during long-range transport events increased by 117-265% compared to background average AOD (aerosol optical depth) at the four AERONET sites in Korea, and average AOD increases of 121% were found when averaged over the entire Korean peninsula. This paper demonstrates that the use of multi-spectral AOD retrievals from geostationary satellites can improve estimates of transboundary PM pollution. Such data will become more widely available later this decade when new sensors such as the GEMS (Geostationary Environment Monitoring Spectrometer) and GOCI-2 are scheduled to be launched.

  14. Impacts of Particulate Matter on Gulf of Mexico Tropical Cyclones

    Science.gov (United States)

    Cao, W.; Rohli, R. V.

    2017-12-01

    The purpose of this project is to analyze the relationship between tropical cyclones of the Gulf of Mexico-Atlantic basin and fine particulate matter (PM2.5). The daily mean PM2.5 concentration values were collected from United States Environmental Protection Agency (EPA). Tropical cyclone data were collected from Tropical Prediction Center Best Track Reanalysis in Unisys Weather®. The GRIdded Binary (GRIB-formatted) data were downloaded from the Data Support Section of the Computational and Information Systems Laboratory at the National Center for Atmospheric Research (NCAR). Through ArcGIS®, the tropical cyclone tracks were compared with the interpolated daily mean PM2.5 concentration value. Results suggest that the tracks tend to avoid areas with higher PM2.5 concentrations, and the intensity was weakened significantly after passing the PM2.5-rich area. Through simulation using the Weather Research and Forecasting (WRF) model, the pressure and vertical structure of Hurricane Lili were weakened after passing the most PM2.5-rich area in Louisiana. Also, little evidence is found for the possibility of precipitation generated by the approaching tropical cyclone to cleanse the atmosphere of PM2.5 before storm passage. These results have important implications for tropical cyclone prediction as storms approach polluted areas or other places where PM2.5 particles are abundant, not only including urban environments but also in coastal areas where proscribed burns take place during tropical cyclone season, such as during sugarcane harvesting in southern Louisiana.

  15. Sensitive determination of total particulate phosphorus and particulate inorganic phosphorus in seawater using liquid waveguide spectrophotometry.

    Science.gov (United States)

    Ehama, Makoto; Hashihama, Fuminori; Kinouchi, Shinko; Kanda, Jota; Saito, Hiroaki

    2016-06-01

    Determining the total particulate phosphorus (TPP) and particulate inorganic phosphorus (PIP) in oligotrophic oceanic water generally requires the filtration of a large amount of water sample. This paper describes methods that require small filtration volumes for determining the TPP and PIP concentrations. The methods were devised by validating or improving conventional sample processing and by applying highly sensitive liquid waveguide spectrophotometry to the measurements of oxidized or acid-extracted phosphate from TPP and PIP, respectively. The oxidation of TPP was performed by a chemical wet oxidation method using 3% potassium persulfate. The acid extraction of PIP was initially carried out based on the conventional extraction methodology, which requires 1M HCl, followed by the procedure for decreasing acidity. While the conventional procedure for acid removal requires a ten-fold dilution of the 1M HCl extract with purified water, the improved procedure proposed in this study uses 8M NaOH solution for neutralizing 1M HCl extract in order to reduce the dilution effect. An experiment for comparing the absorbances of the phosphate standard dissolved in 0.1M HCl and of that dissolved in a neutralized solution [1M HCl: 8M NaOH=8:1 (v:v)] exhibited a higher absorbance in the neutralized solution. This indicated that the improved procedure completely removed the acid effect, which reduces the sensitivity of the phosphate measurement. Application to an ultraoligotrophic water sample showed that the TPP concentration in a 1075mL-filtered sample was 8.4nM with a coefficient of variation (CV) of 4.3% and the PIP concentration in a 2300mL-filtered sample was 1.3nM with a CV of 6.1%. Based on the detection limit (3nM) of the sensitive phosphate measurement and the ambient TPP and PIP concentrations of the ultraoligotrophic water, the minimum filtration volumes required for the detection of TPP and PIP were estimated to be 15 and 52mL, respectively. Copyright © 2016

  16. Daily variability of suspended particulate concentrations and yields and their effect on river particulates chemistry

    Directory of Open Access Journals (Sweden)

    M. Meybeck

    2015-03-01

    Full Text Available Daily total suspended solids concentrations (TSS, mg L-1, yields (Y, kg day-1 km-2 and runoff (q, L s-1 km-2 in world rivers are described by the median (C50, the upper percentile (C99, the discharge-weighted average concentrations (C*, and by their corresponding yields (Y50, Y99, Y* and runoff (q*, q50, q99. These intra-station descriptors range over two to six orders of magnitude at a given station. Inter-station variability is considered through three sets of dimensionless metrics: (i q*/q50, C*/C50 and Y*/Y50, defining the general temporal variability indicators, and q99/q50, C99/C50 and Y99/Y50, defining the extreme variability indicators; (ii river flow duration (W2 and flux duration (M2 in 2% of time; and (iii the truncated rating curve exponent (b50sup of the C vs q relationship for the upper flows. The TSS and Y variability, measured on US, French and world rivers, are first explained by hydrological variability through the b50sup metric, the variability amplifier, then by basin size, erodibility, relief and lake occurrence. Yield variability is the product of runoff variability × TSS variability. All metrics are considerably modified after river damming. The control of river particulate matter (RPM composition by TSS or yields depends on the targeted component. For major elements (Al, Fe, Mn, Ti, Si, Ca, Mg, Na, K, the average RPM chemistry is not dependent on C* and Y* in most world hydroregions, except in the tropical hydrobelt where it is controlled by basin relief. By contrast, the particulate organic carbon content (POC, as a percentage of RPM is inversely correlated to TSS concentrations for (i intra-station measurements in any hydroregion, and (ii inter-station average POC and TSS figures in world rivers. TSS controls heavy metal content (ppm in highly contaminated basins (e.g. Cd in the Seine vs the Rhone, and total metal concentration (ng/L in all cases. Relations between RPM composition and TSS should be taken into account

  17. COPPER-DEPENDENT INFLAMMATION AND NUCLEAR FACTOR-KB ACTIVATION BY PARTICULATE AIR POLLUTION

    Science.gov (United States)

    Particulate air pollution causes increased cardiopulmonary morbidity and mortality, but the chemical determinants responsible for its biologic effects are not understood. We studied the effect of total suspended particulates collected in Provo, Utah, an area where an increase in ...

  18. Solid Phase Characterization of Tank 241-AY-102 Annulus Space Particulate

    International Nuclear Information System (INIS)

    Cooke, G. A.

    2013-01-01

    The Special Analytical Studies Group at the 222-S Laboratory (222-S) examined the particulate recovered from a series of samples from the annular space of tank 241-AY-102 (AY-102) using solid phase characterization (SPC) methods. These include scanning electron microscopy (SEM) using the ASPEX(R)1 scanning electron microscope, X-ray diffraction (XRD) using the Rigaku(R)2 MiniFlex X-ray diffractometer, and polarized light microscopy (PLM) using the Nikon(R)3 Eclipse Pol optical microscope. The SEM is equipped with an energy dispersive X-ray spectrometer (EDS) to provide chemical information

  19. Solid Phase Characterization of Tank 241-AY-102 Annulus Space Particulate

    Energy Technology Data Exchange (ETDEWEB)

    Cooke, G. A.

    2013-01-30

    The Special Analytical Studies Group at the 222-S Laboratory (222-S) examined the particulate recovered from a series of samples from the annular space of tank 241-AY-102 (AY-102) using solid phase characterization (SPC) methods. These include scanning electron microscopy (SEM) using the ASPEX®1 scanning electron microscope, X-ray diffraction (XRD) using the Rigaku®2 MiniFlex X-ray diffractometer, and polarized light microscopy (PLM) using the Nikon®3 Eclipse Pol optical microscope. The SEM is equipped with an energy dispersive X-ray spectrometer (EDS) to provide chemical information.

  20. INAA of airborne particulate matter collected in Bangkok 2002-2004

    International Nuclear Information System (INIS)

    Chueinta, W.; Bunprapob, S.; Tedthong, S.

    2006-01-01

    This paper presents the summary report of the monitoring study on ambient air quality in Bangkok metropolis and its boundary covering the period from 2002 to 2004. The work performed included sampling of fine and coarse fractions of particulate matter at the sites representing urban and suburban areas; measurement of particle mass concentration and elemental concentration; and data interpretation. Instrumental neutron activation by use of research reactor facilities at Office of Atoms for Peace was carried out for multielemental analysis of all filter samples collected. Twenty elements were determined. The database of the three consecutive years are summarized and reviewed in this paper. (author)

  1. INAA of Airborne Particulate Matter Collected in Bangkok and Pathumthani 2002-2004

    International Nuclear Information System (INIS)

    Chueinta, W.; Bunprapob, S.

    2005-01-01

    This paper presents the summary report of the monitoring study on ambient air quality in Bangkok metropolis and its boundary covering the period from 2002 to 2004. The work performed included sampling of fine and coarse fractions of particulate matter at the sites representing urban and suburban areas; measurement of particle mass concentration and elemental concentration; and data interpretation. Instrumental neutron activation by use of research reactor facilities at Office of Atoms for Peace was carried out for multielemental analysis of all filter samples collected. Twenty elements were determined. The database of the three consecutive years are summarized and reviewed in this paper

  2. Particulate Matter Filtration Design Considerations for Crewed Spacecraft Life Support Systems

    Science.gov (United States)

    Agui, Juan H.; Vijayakumar, R.; Perry, Jay L.

    2016-01-01

    Particulate matter filtration is a key component of crewed spacecraft cabin ventilation and life support system (LSS) architectures. The basic particulate matter filtration functional requirements as they relate to an exploration vehicle LSS architecture are presented. Particulate matter filtration concepts are reviewed and design considerations are discussed. A concept for a particulate matter filtration architecture suitable for exploration missions is presented. The conceptual architecture considers the results from developmental work and incorporates best practice design considerations.

  3. SOURCE SAMPLING FINE PARTICULATE MATTER: WOOD-FIRED INDUSTRIAL BOILER

    Science.gov (United States)

    The report provides a profile for a wood-fired industrial boiler equipped with a multistage electrostatic precipitator control device. Along with the profile of emissions of fine particulate matter of aerodynamic diameter of 2.5 micrometers or less (PM-2.5), data are also provide...

  4. Particulate matter characterization of Cauca River water in Colombia

    NARCIS (Netherlands)

    Gutierrez Marin, Juan Pablo; van Halem, D.; Rietveld, L.C.

    2016-01-01

    The particulate matter composition in the Upper Cauca River section was studied, considering the importance of this river for the water supply of Cali, Colombia, and the implications that the turbidity of this water source has had for the city's water treatment. Additionally, the upstream Palo River

  5. Diesel particulate emission in the South African mining industry.

    CSIR Research Space (South Africa)

    Van Niekerk, WCA

    2002-06-01

    Full Text Available measurements was confirmed by comparison of duplicate samples with analyses conducted by the Health and Safety Executive (HSE) in the UK. Furthermore, good agreement in readings was obtained between the Horiba instrument and the R&P direct-reading analyser... ......................................................................................................3 2.2 Characteristics and biological significance of particulates.................................................... 3 2.3 Animal studies...

  6. 40 CFR 86.145-82 - Calculations; particulate emissions.

    Science.gov (United States)

    2010-07-01

    ... = 0.43(Mp1 + Mp2)/(Dct + Ds) + 0.57(Mp3 + Mp2)/(Dht = Ds) where: (1) Mp1 = Mass of particulate... the cold start test, in miles. (6) Dht = The measured driving distance from the “transient” phase of...

  7. Deposition of Suspended Fine Particulate Matter in a Library

    Czech Academy of Sciences Publication Activity Database

    Smolík, Jiří; Mašková, Ludmila; Zíková, Naděžda; Ondráčková, Lucie; Ondráček, Jakub

    2013-01-01

    Roč. 1, 3 April (2013) ISSN 2050-7445 R&D Projects: GA MK DF11P01OVV020 Keywords : fine particulate matter * deposition * brownian diffusion Subject RIV: CF - Physical ; Theoretical Chemistry http://www.heritagesciencejournal.com/content/1/1/7

  8. Distribution spatiale intra-urbaine des particules fines : monitoring ...

    African Journals Online (AJOL)

    SARAH

    30 sept. 2014 ... En outre, l'accumulation des particules fines est faible pendant un mois pluvieux par rapport à un mois sec ..... benjamina, et la structure (tige, branches) des arborées ... par Zhang et al., (2006) sur des feuilles de Pinus pumila.

  9. Removal of residual particulate matter from filter media

    Science.gov (United States)

    Almlie, Jay C; Miller, Stanley J

    2014-11-11

    A method for removing residual filter cakes that remain adhered to a filter after typical particulate removal methodologies have been employed, such as pulse-jet filter element cleaning, for all cleanable filters used for air pollution control, dust control, or powder control.

  10. Nature of suspended particulate matter and concentrations of heavy ...

    African Journals Online (AJOL)

    The concentrations of metals in bottom sediment in the Tanzanian waters of Lake Victoria and the nature of suspended particulate matter (SPM) were analysed. The objective of the study was to compare levels of metals in sediment from different locations and to establish their sources. Metal concentrations were higher in ...

  11. Trace metals concentration assessment in urban particulate matter ...

    African Journals Online (AJOL)

    This study was conducted to investigate the distribution and correlation of selected trace elements (Ca, Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb, and Zn) in Yenagoa, Bayelsa State and its environs. Air particulate matter was collected gravimetrically at five stations (using a high volume portable SKC air check MTXSidekickair sampler ...

  12. Relationship between indoor and outdoor carbonaceous particulates in roadside households

    Energy Technology Data Exchange (ETDEWEB)

    Funasaka, K.; Miyazaki, T.; Tsuruho, K. [Osaka City Institute of Public Health and Environmental Sciences (Japan); Tamura, K. [The National Institute for Minamata Disease, Kumamoto (Japan); Mizuno, T. [Mie University (Japan). Dept. of Chemistry for Materials; Kuroda, K. [Osaka City University Medical School (Japan). Dept. of Preventive Medicine and Environmental Health

    2000-07-01

    Concentrations of particulate matter (PM) and carbonaceous particulates in indoor and outdoor air at roadside private households were measured in Osaka, Japan. The particulate samples were collected on filters using a portable AND sampler capable of separating particles into three different size ranges: over 10 {mu}m, 2-10 {mu}m (coarse) and below 2 {mu}m (fine) in aerodynamic diameter. The filters were weighed and then analyzed for elemental carbon (EC) and organic carbon (OC) by thermal oxidation using a CHN CORDER. The results showed that indoor fine PM concentration is considerably affected by fine EC and the fine EC in indoor air is significantly correlated to that in outdoor air, r = 0.86 (n = 30, p < 0.001). A simple estimation from EC content ratio in diesel exhaust particles indicated that about 30% of indoor particulates of less than 10 {mu}m (PM10) were contributed from diesel exhaust. Additionally, the size characteristics of outdoor PM at roadside and background sites were examined using Andersen Cascade Impactors. (author)

  13. Respiratory dose analysis for components of ambient particulate matter#

    Science.gov (United States)

    Particulate matter (PM) in the atmosphere is a complex mixture of particles with different sizes and chemical compositions. Although PM is known to cause health hazard, specific attributes of PM that may cause health effects are somewhat ambiguous. The dose of each specific compo...

  14. Characteristics, Causes, and Evaluation of Helicopter Particulate Visual Obstruction

    Science.gov (United States)

    2012-09-10

    future full-scale testing. The thrust sources examined were a 1 in. diameter nozzle , a 4 in. diameter nozzle , and a 16 in. ducted fan. The sources...Hiller also evaluated inclining the thrust vector , and determined there was little reduction in dynamic pressure at the point of ground interaction...CHARACTERISTICS, CAUSES, AND EVALUATION OF HELICOPTER PARTICULATE VISUAL OBSTRUCTION THESIS

  15. Membrane Characteristics for Removing Particulates in PFC Wastes

    International Nuclear Information System (INIS)

    Kim, Gye Nam; Lee, Sung Yeol; Won, Hui Jun; Jung, Chong Hun; Oh, Won Zin; Park, Jin Ho

    2005-01-01

    Pc (Per fluorocarbon) decontamination process is one of best methods to remove hot particulate adhered at inside surface of hot cell and surface of equipment in hot cell. It was necessary to develop a particulate filtration equipment to reuse Pc solution used on Pc decontamination due to its high cost and to minimize the volume of second wastewater. Contamination characteristics of hot particulate were investigated and then a filtration process was presented to remove hot particulate in Pc solution generated through Pc decontamination process. The removal efficiency of Pvdf (Poly vinylidene fluoride), Pp (Polypropylene), Ceramic (Al 2 O 3 ) filter showed more than 95%. The removal efficiency of Pvdf filter was a little lower than those of other kiters at same pressure (3 psi). A ceramic filter showed a higher removal efficiency with other filters, while a little lower flux rate than other filters. Due to inorganic composition, a ceramic filter was highly stable against radio nuclides in comparison with Pvdf and Pp membrane, which generate H 2 gas in α-radioactivity atmosphere. Therefore, the adoption of ceramic filter is estimated to be suitable for the real nitration process.

  16. Amino sugars in suspended particulate matter from the Bay

    Indian Academy of Sciences (India)

    particulate nitrogen (PN)and AS concentrations and composition.The AS varied between 0.4 and 17.5 nmol/l.Concentrations were high in the surface waters and generally decreased with increasing depth.AS concentration decreased from the south to ...

  17. Particulate matter urban air pollution from traffic car

    Science.gov (United States)

    Filip, G. M.; Brezoczki, V. M.

    2017-05-01

    The particulate matters (PM) are very important compounds of urban air pollution. There are a lot of air pollution sources who can generate PM and one of the most important of them it is urban traffic car. Air particulate matters have a major influence on human health so everywhere are looking for PM reducing solutions. It is knows that one of the solution for reduce the PM content from car traffic on ambient urban air is the fluidity of urban traffic car by introduction the roundabout intersections. This paper want to present some particulate matter determinations for PM10 and PM2.5 conducted on the two types of urban intersection respectively traffic light and roundabout intersections in Baia Mare town in the approximate the same work conditions. The determinations were carried out using a portable particulate matter monitor Haz - Dust model EPAM - 5000, who can provide a real time data for PM10, PM 2.5.Determinations put out that there are differences between the two locations regarding the PM content on ambient air. On roundabout intersection the PM content is less than traffic light intersection for both PM10 and PM 2.5 with more than 30%.

  18. Spatial Distribution of Suspended Particulate Matter in Mtwapa ...

    African Journals Online (AJOL)

    ... in the three sites; it accounts for a mean of 61% ±20 in Ramisi, 97% ±0.7 in Shirazi and 65% ±29 in Mtwapa. These high detritus levels are expected because of the allochthonous supply of particulate material by the river in Ramisi and the contribution from mangroves, which fringe the banks of the estuary and the creeks.

  19. Particulate Matter and Noise Impact Studies of Waste Rock Dump ...

    African Journals Online (AJOL)

    Adansi Gold Company Limited identified an economically viable gold deposit at Nkran in the Amansie West District of Ghana. Mining of this deposit requires the disposal of waste rock materials at a proposed waste rock dump near Nkran and Koninase communities. Since particulates and noise emissions from the ...

  20. Removal of residual particulate matter from filter media

    Energy Technology Data Exchange (ETDEWEB)

    Almlie, Jay C.; Miller, Stanley J.

    2018-01-09

    A method for removing residual filter cakes that remain adhered to a filter after typical particulate removal methodologies have been employed, such as pulse-jet filter element cleaning, for all cleanable filters used for air pollution control, dust control, or powder control.

  1. Ionization for reducing particulate matter emissions from poultry houses

    NARCIS (Netherlands)

    Cambra-López, M.; Winkel, A.; Harn, van J.; Ogink, N.W.M.; Aarnink, A.J.A.

    2009-01-01

    We evaluated the effect of ionization in reducing particulate and gaseous emissions in broiler houses and its effect on particle size distribution. Furthermore, we evaluated the performance of the tested ionization system and its influence on bird performance. The experiment was done during two

  2. An assessment of common atmospheric particulate matter sampling ...

    African Journals Online (AJOL)

    The method detection limit was also low (0.2 to 1 μg/L) for most metals, and 50% and less standard deviation to mean ratios were obtained for Ni and Pb. Key words: Toxic metals, inductively coupled plasma mass spectroscopy, scanning electron microscopy coupled with energy dispersive spectrometry, particulate matter, ...

  3. Determination of trace elements in urban airborne particulates (PM ...

    African Journals Online (AJOL)

    Assessment of the air quality in Newcastle upon Tyne, UK was performed by determining the trace element content in airborne particulates (PM10). Samples were collected over a 12 month period (March 2011 to April 2012) using two high volume air sampler provided with a PM10 size selective inlet. The concentrations of ...

  4. An Application Of Receptor Modeling To Identify Airborne Particulate ...

    African Journals Online (AJOL)

    An Application Of Receptor Modeling To Identify Airborne Particulate Sources In Lagos, Nigeria. FS Olise, OK Owoade, HB Olaniyi. Abstract. There have been no clear demarcations between industrial and residential areas of Lagos with focus on industry as the major source. There is need to identify potential source types in ...

  5. Monitoring Particulate Matter with Commodity Hardware

    Science.gov (United States)

    Holstius, David

    Health effects attributed to outdoor fine particulate matter (PM 2.5) rank it among the risk factors with the highest health burdens in the world, annually accounting for over 3.2 million premature deaths and over 76 million lost disability-adjusted life years. Existing PM2.5 monitoring infrastructure cannot, however, be used to resolve variations in ambient PM2.5 concentrations with adequate spatial and temporal density, or with adequate coverage of human time-activity patterns, such that the needs of modern exposure science and control can be met. Small, inexpensive, and portable devices, relying on newly available off-the-shelf sensors, may facilitate the creation of PM2.5 datasets with improved resolution and coverage, especially if many such devices can be deployed concurrently with low system cost. Datasets generated with such technology could be used to overcome many important problems associated with exposure misclassification in air pollution epidemiology. Chapter 2 presents an epidemiological study of PM2.5 that used data from ambient monitoring stations in the Los Angeles basin to observe a decrease of 6.1 g (95% CI: 3.5, 8.7) in population mean birthweight following in utero exposure to the Southern California wildfires of 2003, but was otherwise limited by the sparsity of the empirical basis for exposure assessment. Chapter 3 demonstrates technical potential for remedying PM2.5 monitoring deficiencies, beginning with the generation of low-cost yet useful estimates of hourly and daily PM2.5 concentrations at a regulatory monitoring site. The context (an urban neighborhood proximate to a major goods-movement corridor) and the method (an off-the-shelf sensor costing approximately USD $10, combined with other low-cost, open-source, readily available hardware) were selected to have special significance among researchers and practitioners affiliated with contemporary communities of practice in public health and citizen science. As operationalized by

  6. (including travel dates) Proposed itinerary

    Indian Academy of Sciences (India)

    Ashok

    31 July to 22 August 2012 (including travel dates). Proposed itinerary: Arrival in Bangalore on 1 August. 1-5 August: Bangalore, Karnataka. Suggested institutions: Indian Institute of Science, Bangalore. St Johns Medical College & Hospital, Bangalore. Jawaharlal Nehru Centre, Bangalore. 6-8 August: Chennai, TN.

  7. Particulate Air Pollution, Ambulatory Heart Rate Variability, and Cardiac Arrhythmia in Retirement Community Residents with Coronary Artery Disease

    Science.gov (United States)

    Longhurst, John; Tjoa, Thomas; Sioutas, Constantinos; Delfino, Ralph J.

    2013-01-01

    Background: Decreased heart rate variability (HRV) has been associated with future cardiac morbidity and mortality and is often used as a marker of altered cardiac autonomic balance in studies of health effects of airborne particulate matter. Fewer studies have evaluated associations between air pollutants and cardiac arrhythmia. Objectives: We examined relationships between cardiac arrhythmias, HRV, and exposures to airborne particulate matter. Methods: We measured HRV and arrhythmia with ambulatory electrocardiograms in a cohort panel study for up to 235 hr per participant among 50 nonsmokers with coronary artery disease who were ≥ 71 years of age and living in four retirement communities in the Los Angeles, California, Air Basin. Exposures included hourly outdoor gases, hourly traffic-related and secondary organic aerosol markers, and daily size-fractionated particle mass. We used repeated measures analyses, adjusting for actigraph-derived physical activity and heart rate, temperature, day of week, season, and community location. Results: Ventricular tachycardia was significantly increased in association with increases in markers of traffic-related particles, secondary organic carbon, and ozone. Few consistent associations were observed for supraventricular tachycardia. Particulates were significantly associated with decreased ambulatory HRV only in the 20 participants using ACE (angiotensin I–converting enzyme) inhibitors. Conclusions: Although these data support the hypothesis that particulate exposures may increase the risk of ventricular tachycardia for elderly people with coronary artery disease, HRV was not associated with exposure in most of our participants. These results are consistent with previous findings in this cohort for systemic inflammation, blood pressure, and ST segment depression. Citation: Bartell SM, Longhurst J, Tjoa T, Sioutas C, Delfino RJ. 2013. Particulate air pollution, ambulatory heart rate variability, and cardiac arrhythmia in

  8. Adverse effect of diesel engine produced particulate matter on various stone types and concrete: a laboratory exposure experiment

    Science.gov (United States)

    Farkas, Orsolya; Szabados, György; Antal, Ákos; Török, Ákos

    2015-04-01

    The effect of particulate matter on construction materials have been studied under laboratory conditions. For testing the adverse effects of diesel soot and particulate matter on stone and concrete a small scale laboratory exposure chamber was constructed. Blocks of 9 different stone types and concrete was placed in the chamber and an exhaust pipe of diesel engine was diverted into the system. Tested stones included: porous limestone, cemented non-porous limestone, travertine, marble, rhyolite tuff, andesite and granite. The engine was operated for 10 hours and the produced particulate matter was diverted directly to the surface of the material specimens of 3 cm in diameter each. Working parameters of the engine were controlled; the composition of the exhaust gas, smoke value and temperature were continuously measured during the test. Test specimens were documented and analysed prior to exposure and after the exposure test. Parameters such colorimetric values, weight, surface properties, mineralogical compositions of the test specimens were recorded. The working temperature was in the order of 300°C-320°C. The gas concentration was in ppm as follows: 157 CO; 5.98 CO2, 34.3 THC; 463 NOx; 408 NO; 12.88 O2. Our tests have demonstrated that significant amount of particulate matter was deposited on construction materials even at a short period of time; however the exposure was very intense. It also indicates that that the interaction of particulate matter and aerosol compounds with construction materials in urban areas causes rapid decay and has an adverse effect not only on human health but also on built structures.

  9. Health impact caused by exposure to particulate matter in the air of Tehran in the past decade

    Directory of Open Access Journals (Sweden)

    Majid Kermani

    2017-03-01

    Full Text Available Background: Air pollution, especially the phenomenon of dust and particulate matter can cause mortality of many civilians, and causes various diseases including cardiovascular and respiratory diseases. One of the major pollutants in the air is particulate matter that concentration has increased over recent years. So, present study with aim of Quantification Health Endpoints Attributed to particulate matter in Tehran, Capital of Iran during the past decade (2005-2014 by AirQ software, version 2.2.3 (WHO European Centre for Environment and Health was performed. Methods: This study is a descriptive-analytic investigation. The process of performance this study lasted 12 months. Subject of this the study and research was in Environmental Health Engineering Department of Iran University of Medical Sciences. Exact data of every hour pollutants were taken from Department of environmental (DOE Islamic Republic Iran and Air Quality Control Company of Tehran. Then validated according to the World Health Organization (WHO guidelines and Statistical parameters for quantifying health effects were calculated in excel software. Finally, assessment of cases total mortality, cardiovascular mortality, respiratory mortality and cardiovascular disease and respiratory disease, with AirQ software was performed. Results: The results of this study showed that the number of total mortality, cardiovascular mortality and respiratory mortality caused by exposure to Particulate matter smaller than 10 microns (PM10 in the past decade is 11776, 12121 and 33066 cases respectively. Also the total number of hospital admission due to cardiovascular disease and respiratory disease in the past decade is 20990 and 54352 cases in 2005-2014 years. Conclusion: According to the results of this study, during the last decade the level of air pollution and Concentration of pollutants in Tehran Increased. Effects and health consequences due to exposure to Particulate matter smaller than 10

  10. Cytotoxicity and genotoxicity properties of particulate matter fraction 2.5 μm

    Science.gov (United States)

    Bełcik, Maciej K.; Trusz-Zdybek, Agnieszka; Zaczyńska, Ewa; Czarny, Anna; Piekarska, Katarzyna

    2017-11-01

    In the ambient is more than 2,000 chemical substances, some of them are absorbed on the surface of the particulate matter and may causes many health problems. Air pollution is responsible for more than 3.2 million premature deaths which classifies it as a second place environmental risk factor. Especially dangerous for health are polycyclic aromatic hydrocarbons and their nitro- and amino derivatives which shows mutagenic and carcinogenic properties. Air pollutions were also classified by International Agency for Research on Cancer to group which carcinogenic properties on human were proved by available knowledge. Air pollutions, including particulate matter are one of the biggest problem in Polish cities. World Health Organization in report published in May 2016 set many of Polish cities on the top of the list most polluted in European Union. The article presents results of mutagenicity, genotoxicity and cytotoxicity researches conducted on a particulate matter fraction 2.5 μm collected during all year long in Wroclaw agglomeration. The material were collected on filters using high-flow air aspirator and extracted using dichloromethane. Additionally it was fractionated into 2 parts containing: all pollutants and only polycyclic aromatic hydrocarbons. Dry residue of this fractions were dissolving in DMSO and tested using biological methods. Biological methods include mutagenicity properties which are investigated by Salmonella assay (Ames assay). Other biological method was comet assay and 4 parameter cytotoxicity test PAN-I assay. Results of the conducted experiments shows differences in mutagenic, genotoxic and cytotoxic properties between seasons of collection and between volume of dust pollutions fractions. The worst properties shows particles collected in autumn and winter season and this containing only polycyclic aromatics hydrocarbons. Results showed also some correlations in results obtained during different methods and properties.

  11. Seasonal changes in suspended particulate component in Bombay High oil field (Arabian Sea)

    Digital Repository Service at National Institute of Oceanography (India)

    Bhat, K.L.; Verlecar, X.N.; Venkat, K.

    of phytoplankton biomass. Ratio of silicate and nitrate to phosphate was 16:16:1 for monsoon and postmonsoon periods. Annual values of particulate carbohydrates, particulate proteins and particulate lipids in surface waters ranged from 40 to 265 mu g l sup(-1), 21...

  12. A new technology for the reduction of particulate matter from diesel engines in ships

    NARCIS (Netherlands)

    Van Rens, G.L.M.A.

    2008-01-01

    In this thesis the focus is on the particulate matter reduction of ships, as ships contribute significantly to the particulate matter concentration in ambient air. Because the fuel of sea ships contains a lot of ash, the emitted particulate matter will also contain a lot of ash. In car and truck

  13. 30 CFR 7.89 - Test to determine the particulate index.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Test to determine the particulate index. 7.89... Use in Underground Coal Mines § 7.89 Test to determine the particulate index. The test shall be... measured and recorded at each test mode. (ii) The data required for use in the particulate index...

  14. The geocentric particulate distribution: Cometary, asteroidal, or space debris?

    Science.gov (United States)

    Mcdonnell, J. A. M.; Ratcliff, P. R.

    1992-01-01

    Definition of the Low Earth Orbit (LEO) particulate environment has been refined considerably with the analysis of data from NASA's Long Duration Exposure Facility (LDEF). Measurements of the impact rates from particulates ranging from sub-micron to millimetres in dimension and, especially, information on their directionality has permitted new scrunity of the sources of the particulates. Modelling of the dynamics of both bound (Earth orbital) and unbound (hyperbolic interplanetary) particulates intercepting LDEF's faces leads to the conclusion that the source is dominantly interplanetary for particle dimensions of greater than some 5 microns diameter; however the anisotropy below this dimension demands lower velocities and is compatible with an orbital component. Characteristics of the LDEF interplanetary component are compatible with familiar meteoroid sources and deep space measurements. Understanding of the orbital component which exceeds the interplanetary flux by a factor of 4 is less clear; although the very small particulates in orbit have been associated with space debris (Lawrance and Brownlee, 1986) this data conflicts with other measurements (McDonnell, Carey and Dixon, 1984) at the same epoch. By analysis of trajectories approaching the Earth and its atmosphere, we have shown that a significant contribution could be captured by aerocapture, i.e., atmospheric drag, from either asteroidal or cometary sources; such enhancement is unlikely however to provide the temporal and spatial fluctuations observed by the LDEF Interplanetary Dust Experiment (Mullholland et al. 1992). A further new mechanism is also examined, that of aerofragmentation capture, where an atmospheric grazing trajectory, which would not normally lead to capture, leads to fragmentation by thermal or mechanical shock; the microparticulates thus created can be injected in large numbers, but only into short-lifetime orbits. The concentration in one particular orbit plane, could explain the

  15. Partition of pollution between dissolved and particulate phases: what about emerging substances in urban stormwater catchments?

    Science.gov (United States)

    Zgheib, Sally; Moilleron, Régis; Saad, Mohamed; Chebbo, Ghassan

    2011-01-01

    This paper presents results about the occurrence, the concentrations of urban priority substances on both the dissolved and the particulate phases in stormwater. Samples were collected at the outlet of a dense urban catchment in Paris suburb (2.30 km(2)). 13 chemical groups were investigated including 88 individual substances. Results showed that stormwater discharges contained 45 substances among them some metals, organotins, PAHs, PCBs, alkylphenols, pesticides, phthalates, cholorophenols and one volatile organic compound, i.e. methylene chloride. With respect to the European Water Framework Directive, these substances included 47% of the priority hazardous substances (n = 8), 38% of the priority substances (n = 10). The remaining substances (n = 27) belong to a list of others specific urban substances not included in the Water Framework Directive but monitored during this work. Finally, stormwater quality was evaluated by comparing the substance concentrations to environmental quality standards (EQS) and the particulate content to Canadian sediment quality guidelines. This showed that stormwater was highly contaminated and should be treated before being discharged to receiving waters in order to avoid any adverse impact on the river quality. Copyright © 2010 Elsevier Ltd. All rights reserved.

  16. Theory including future not excluded

    DEFF Research Database (Denmark)

    Nagao, K.; Nielsen, H.B.

    2013-01-01

    We study a complex action theory (CAT) whose path runs over not only past but also future. We show that, if we regard a matrix element defined in terms of the future state at time T and the past state at time TA as an expectation value in the CAT, then we are allowed to have the Heisenberg equation......, Ehrenfest's theorem, and the conserved probability current density. In addition,we showthat the expectation value at the present time t of a future-included theory for large T - t and large t - T corresponds to that of a future-not-included theory with a proper inner product for large t - T. Hence, the CAT...

  17. Long-Term Exposure to Fine Particulate Matter and Breast Cancer Incidence in the Danish Nurse Cohort Study

    DEFF Research Database (Denmark)

    Andersen, Zorana J; Ravnskjaer, Line; Andersen, Klaus Kaae

    BACKGROUND: An association between air pollution and breast cancer risk has been suggested but evidence is sparse and inconclusive. METHODS: We included 22,877 female nurses from the Danish Nurse cohort who were recruited in 1993 or 1999, and followed them for incidence of breast cancer (N=1......,145) until 2013 in the Danish Cancer Register. We estimated annual mean concentrations of particulate matter with diameter nurses' residences since 1990 using an atmospheric chemistry transport model. We examined the association between...

  18. Long-Term Exposure to Fine Particulate Matter: Association with Nonaccidental and Cardiovascular Mortality in the Agricultural Health Study Cohort

    OpenAIRE

    Weichenthal, Scott; Villeneuve, Paul J.; Burnett, Richard T.; van Donkelaar, Aaron; Martin, Randall V.; Jones, Rena R.; DellaValle, Curt T.; Sandler, Dale P.; Ward, Mary H.; Hoppin, Jane A.

    2014-01-01

    Background: Few studies have examined the relationship between long-term exposure to ambient fine particulate matter (PM2.5) and nonaccidental mortality in rural populations. Objective: We examined the relationship between PM2.5 and nonaccidental and cardiovascular mortality in the U.S. Agricultural Health Study cohort. Methods: The cohort (n = 83,378) included farmers, their spouses, and commercial pesticide applicators residing primarily in Iowa and North Carolina. Deaths occurring between ...

  19. Characteristics of thin and coarse particulates of urban and natural brazilian aerosols

    International Nuclear Information System (INIS)

    Orsini, C.Q.; Tabacnics, M.H.; Artaxo, P.; Andrade, M.F.; Kerr, A.S.

    1994-01-01

    Thin and coarse particulate were sampled during the period 1982-1985 in a natural coastal forest (Jureia), and five urban-industrial regions (Vitoria, Salvador, Porto Alegre, Sao Paulo and Belo Horizonte). The time variation of the concentration in the air, and the relative elementary composition of the thin and coarse particulate, sampled by thin and Coarse Particulate Sampler (AFG), were determined by gravimetric method and PIXE analysis respectively. The results demonstrated that the ground dust and salt from the sea are unequivocally one of the largest sources of coarse particulate, and also the ground is a significant thin particulate source. 25 refs, 22 figs, 28 tabs. (L.C.J.A.)

  20. Device including a contact detector

    DEFF Research Database (Denmark)

    2011-01-01

    arms (12) may extend from the supporting body in co-planar relationship with the first surface. The plurality of cantilever arms (12) may extend substantially parallel to each other and each of the plurality of cantilever arms (12) may include an electrical conductive tip for contacting the area......The present invention relates to a probe for determining an electrical property of an area of a surface of a test sample, the probe is intended to be in a specific orientation relative to the test sample. The probe may comprise a supporting body defining a first surface. A plurality of cantilever...... of the test sample by movement of the probe relative to the surface of the test sample into the specific orientation.; The probe may further comprise a contact detector (14) extending from the supporting body arranged so as to contact the surface of the test sample prior to any one of the plurality...

  1. Neoclassical transport including collisional nonlinearity.

    Science.gov (United States)

    Candy, J; Belli, E A

    2011-06-10

    In the standard δf theory of neoclassical transport, the zeroth-order (Maxwellian) solution is obtained analytically via the solution of a nonlinear equation. The first-order correction δf is subsequently computed as the solution of a linear, inhomogeneous equation that includes the linearized Fokker-Planck collision operator. This equation admits analytic solutions only in extreme asymptotic limits (banana, plateau, Pfirsch-Schlüter), and so must be solved numerically for realistic plasma parameters. Recently, numerical codes have appeared which attempt to compute the total distribution f more accurately than in the standard ordering by retaining some nonlinear terms related to finite-orbit width, while simultaneously reusing some form of the linearized collision operator. In this work we show that higher-order corrections to the distribution function may be unphysical if collisional nonlinearities are ignored.

  2. Honey Bees (Apis mellifera, L.) as Active Samplers of Airborne Particulate Matter.

    Science.gov (United States)

    Negri, Ilaria; Mavris, Christian; Di Prisco, Gennaro; Caprio, Emilio; Pellecchia, Marco

    2015-01-01

    Honey bees (Apis mellifera L.) are bioindicators of environmental pollution levels. During their wide-ranging foraging activity, these hymenopterans are exposed to pollutants, thus becoming a useful tool to trace the environmental contaminants as heavy metals, pesticides, radionuclides and volatile organic compounds. In the present work we demonstrate that bees can also be used as active samplers of airborne particulate matter. Worker bees were collected from hives located in a polluted postmining area in South West Sardinia (Italy) that is also exposed to dust emissions from industrial plants. The area is included in an official list of sites of national interest for environmental remediation, and has been characterized for the effects of pollutants on the health of the resident population. The head, wings, hind legs and alimentary canal of the bees were investigated with Scanning Electron Microscopy coupled with X-ray spectroscopy (SEM-EDX). The analyses pointed to specific morphological and chemical features of the particulate, and resulted into the identification of three categories of particles: industry-, postmining-, and soil-derived. With the exception of the gut, all the analyzed body districts displayed inorganic particles, mostly concentrated in specific areas of the body (i.e. along the costal margin of the fore wings, the medial plane of the head, and the inner surface of the hind legs). The role of both past mining activities and the industrial activity close to the study area as sources of the particulate matter is also discussed. We conclude that honey bees are able to collect samples of the main airborne particles emitted from different sources, therefore could be an ideal tool for monitoring such a kind of pollutants.

  3. An analytical model for particulate deposition on vertical heat transfer surfaces in a boiling environment

    International Nuclear Information System (INIS)

    Keefer, R.H.; Rider, J.L.; Waldman, L.A.

    1993-01-01

    A frequent problem in heat exchange equipment is the deposition of particulates entrained in the working fluid onto heat transfer surfaces. These deposits increase the overall heat transfer resistance and can significantly degrade the performance of the heat exchanger. Accurate prediction of the deposition rate is necessary to ensure that the design and specified operating conditions of the heat exchanger adequately address the effects of this deposit layer. Although the deposition process has been studied in considerable detail, much of the work has focused on investigating individual aspects of the deposition process. This paper consolidates this previous research into a mechanistically based analytical prediction model for particulate deposition from a boiling liquid onto vertical heat transfer surfaces. Consistent with the well known Kern-Seaton approach, the model postulates net particulate accumulation to depend on the relative contributions of deposition and reentrainment processes. Mechanisms for deposition include boiling, momentum, and diffusion effects. Reentrainment is presumed to occur via an intermittent erosion process, with the energy for particle removal being supplied by turbulent flow instabilities. The contributions of these individual mechanisms are integrated to obtain a single equation for the deposit thickness versus time. The validity of the resulting model is demonstrated by comparison with data published in the open literature. Model estimates show good agreement with data obtained over a range of thermal-hydraulic conditions in both flow and pool boiling environments. The utility of the model in performing parametric studies (e.g. to determine the effect of flow velocity on net deposition) is also demonstrated. The initial success of the model suggests that it could prove useful in establishing a range of heat exchanger. operating conditions to minimize deposition

  4. Conduction and Narrow Escape in Dense, Disordered, Particulate-based Heterogeneous Materials

    Science.gov (United States)

    Lechman, Jeremy

    For optimal and reliable performance, many technological devices rely on complex, disordered heterogeneous or composite materials and their associated manufacturing processes. Examples include many powder and particulate-based materials found in phyrotechnic devices for car airbags, electrodes in energy storage devices, and various advanced composite materials. Due to their technological importance and complex structure, these materials have been the subject of much research in a number of fields. Moreover, the advent of new manufacturing techniques based on powder bed and particulate process routes, the potential of functional nano-structured materials, and the additional recognition of persistent shortcomings in predicting reliable performance of high consequence applications; leading to ballooning costs of fielding and maintaining advanced technologies, should motivate renewed efforts in understanding, predicting and controlling these materials' fabrication and behavior. Our particular effort seeks to understand the link between the top-down control presented in specific non-equilibrium processes routes (i.e., manufacturing processes) and the variability and uncertainty of the end product performance. Our ultimate aim is to quantify the variability inherent in these constrained dynamical or random processes and to use it to optimize and predict resulting material properties/performance and to inform component design with precise margins. In fact, this raises a set of deep and broad-ranging issues that have been recognized and as touching the core of a major research challenge at Sandia National Laboratories. In this talk, we will give an overview of recent efforts to address aspects of this vision. In particular the case of conductive properties of packed particulate materials will be highlighted. Combining a number of existing approaches we will discuss new insights and potential directions for further development toward the stated goal. Sandia National

  5. Particulate and colloidal silver in sewage effluent and sludge discharged from British wastewater treatment plants.

    Science.gov (United States)

    Johnson, Andrew C; Jürgens, Monika D; Lawlor, Alan J; Cisowska, Iwona; Williams, Richard J

    2014-10-01

    Differential filtration was used to measure silver (>2 nm) entering and leaving nine sewage treatment plants (STPs). The mean concentration of colloidal (2-450 nm) silver, which includes nanosilver, was found to be 12 ng L(-1) in the influent and 6 ng L(-1) in the effluent. For particulate silver (>450 nm) the mean values were 3.3 μg L(-1) for influent and 0.08 μg L(-1) for effluent. Thus, removal was around 50% and 98% for colloidal and particulate silver respectively. There was no significant difference in performance between the different types of STP investigated (three examples each of activated sludge, biological filter and biological filter with tertiary treatment located across England, UK). In addition, treated sewage sludge samples (biosolids) were taken from several STPs to measure the total silver likely to be discharged to soils. Total silver was 3-14 mg kg(-1) DW in the sludge (median 3.6), which if the sludge were added at the recommended rate to soil, would add 11 μg kg(-1) yr(-1) to the top 20 cm soil layer. Predicted concentrations using the LF2000-WQX model for all the rivers of England and Wales for nanosilver were typically in the 0-1 ng L(-1) range but levels up to 4 ng L(-1) are possible in a high discharge and low flow scenario. Predicted concentrations for the total particulate forms were mostly below 50 ng L(-1) except for a high discharge and low flow scenario where concentrations could reach 135 ng L(-1). Copyright © 2014 Elsevier Ltd. All rights reserved.

  6. Particulate filter behaviour of a Diesel engine fueled with biodiesel

    International Nuclear Information System (INIS)

    Buono, D.; Senatore, A.; Prati, M.V.

    2012-01-01

    Biodiesel is an alternative and renewable fuel made from plant and animal fat or cooked oil through a transesterification process to produce a short chain ester (generally methyl ester). Biodiesel fuels have been worldwide studied in Diesel engines and they were found to be compatible in blends with Diesel fuel to well operate in modern Common Rail engines. Also throughout the world the diffusion of biofuels is being promoted in order to reduce greenhouse gas emissions and the environmental impact of transport, and to increase security of supply. To meet the current exhaust emission regulations, after-treatment devices are necessary; in particular Diesel Particulate Filters (DPFs) are essential to reduce particulate emissions of Diesel engines. A critical requirement for the implementation of DPF on a modern Biodiesel powered engine is the determination of Break-even Temperature (BET) which is defined as the temperature at which particulate deposition on the filter is balanced by particulate oxidation on the filter. To fit within the exhaust temperature range of the exhaust line and to require a minimum of active regeneration during the engine running, the BET needs to occur at sufficiently low temperatures. In this paper, the results of an experimental campaign on a modern, electronic controlled fuel injection Diesel engine are shown. The engine was fuelled either with petroleum ultralow sulphur fuel or with Biodiesel: BET was evaluated for both fuels. Results show that on average, the BET is lower for biodiesel than for diesel fuel. The final goal was to characterize the regeneration process of the DPF device depending on the adopted fuel, taking into account the different combustion process and the different nature of the particulate matter. Overall the results suggest significant benefits for the use of biodiesel in engines equipped with DPFs. - Highlights: ► We compare Diesel Particulate Trap (DPF) performance with Biodiesel and Diesel fuel. ► The Break

  7. Exploration Mission Particulate Matter Filtration Technology Performance Testing in a Simulated Spacecraft Cabin Ventilation System

    Science.gov (United States)

    Agui, Juan H.; Vijayakumar, R.; Perry, Jay L.; Frederick, Kenneth R.; Mccormick, Robert M.

    2017-01-01

    Human deep space exploration missions will require advances in long-life, low maintenance airborne particulate matter filtration technology. As one of the National Aeronautics and Space Administrations (NASA) developments in this area, a prototype of a new regenerable, multi-stage particulate matter filtration technology was tested in an International Space Station (ISS) module simulation facility. As previously reported, the key features of the filter system include inertial and media filtration with regeneration and in-place media replacement techniques. The testing facility can simulate aspects of the cabin environment aboard the ISS and contains flight-like cabin ventilation system components. The filtration technology test article was installed at the inlet of the central ventilation system duct and instrumented to provide performance data under nominal flow conditions. In-place regeneration operations were also evaluated. The real-time data included pressure drop across the filter stages, process air flow rate, ambient pressure, humidity and temperature. In addition, two video cameras positioned at the filtration technology test articles inlet and outlet were used to capture the mechanical performance of the filter media indexing operation under varying air flow rates. Recent test results are presented and future design recommendations are discussed.

  8. Composition and Sources of Particulate Matter Measured near Houston, TX: Anthropogenic-Biogenic Interactions

    Directory of Open Access Journals (Sweden)

    Jeffrey K. Bean

    2016-05-01

    Full Text Available Particulate matter was measured in Conroe, Texas (~60 km north of downtown Houston, Texas during the September 2013 DISCOVER-AQ campaign to determine the sources of particulate matter in the region. The measurement site is influenced by high biogenic emission rates as well as transport of anthropogenic pollutants from the Houston metropolitan area and is therefore an ideal location to study anthropogenic-biogenic interactions. Data from an Aerosol Chemical Speciation Monitor (ACSM suggest that on average 64 percent of non-refractory PM1 was organic material, including a high fraction (27%–41% of organic nitrates. There was little diurnal variation in the concentrations of ammonium sulfate; however, concentrations of organic and organic nitrate aerosol were consistently higher at night than during the day. Potential explanations for the higher organic aerosol loadings at night include changing boundary layer height, increased partitioning to the particle phase at lower temperatures, and differences between daytime and nighttime chemical processes such as nitrate radical chemistry. Positive matrix factorization was applied to the organic aerosol mass spectra measured by the ACSM and three factors were resolved—two factors representing oxygenated organic aerosol and one factor representing hydrocarbon-like organic aerosol. The factors suggest that the measured aerosol was well mixed and highly processed, consistent with the distance from the site to major aerosol sources, as well as the high photochemical activity.

  9. Size, Composition, and Sources of Health Relevant Particulate Matter in the San Joaquin Valley

    Science.gov (United States)

    Ham, Walter Allan

    Particulate Matter (PM) is an environment contaminant that has been associated with adverse health effects in epidemiological and toxicological studies. Atmospheric PM is made up of a diverse array of chemical species that are emitted from multiple sources across a range of aerodynamic diameters spanning several orders of magnitude. The focus of the present work was the characterization of ambient PM with aerodynamic diameters below 1.8 mum (PM1.8) in 6 size sub-fractions including PM0.1. Chemical species measured included organic carbon, elemental carbon, water soluble ions, trace metals, and organic molecular markers in urban and rural environments in the San Joaquin Valley. These measurements were used to determine differences in relative diurnal size distributions during a severe winter stagnation event, seasonal changes in PM size and composition, and the source origin of carbonaceous PM. This size-resolved information was used to calculate lung deposition patterns of health relevant PM species to evaluate seasonal differences in PM dose. By accurately calculating PM dose, researchers are able to more directly link ambient PM characterization data with biological endpoints. All of these results are used to support ongoing toxicological health effects studies. These types of analyses are important as this type of information may assist regulators with developing control strategies to reduce health effects caused by particulate air pollution.

  10. Aromatic Radicals-Acetylene Particulate Matter Chemistry

    Science.gov (United States)

    2011-12-01

    solutions include deactivated fused silica-lined tubing provided by Sigma-Aldrich. The internal wall of these tubes is covered by a thin layer of fused... Ser 809 S. Marshfield, RM 520, Chicago, IL 60612 USACE HUMPHREYS ENGR CTR SPT ACTIVITY Attn: CECT-HC 7701 Telegraph Road Alexandria, VA 22315...Model, m-Xylene Oxidation, Phenyl + Acetylene, Phenyl Pyrolysis, Gas Chromatography , Potential Energy Surface, Ab-Initio Calculations. None 133

  11. Emission factors for CH{sub 4}, NO{sub x}, particulates and black carbon for domestic shipping in Norway, revision 1

    Energy Technology Data Exchange (ETDEWEB)

    Nielsen, Joergen Bremnes; Stenersen, Dag

    2010-11-15

    In this report new and updated emission factors for diesel, HFO and gas fuelled ships are presented and discussed as follows; NO{sub x} reduction factors from ships with NO{sub x} reduction measures; NO{sub x} emission factor from gas operated vessels; Methane emission factors for gas operated vessels; Updated emission factors for particulate emissions (PM) with a specific factor for the black carbon (BC) fraction of particulate emissions; A discussion on how low sulfur fuel will affect emissions of PM emissions and the BC fraction of PM is also included. (Author)

  12. A micromechanical study of the damage mechanics of acrylic particulate composites under thermomechanical loading

    Science.gov (United States)

    Nie, Shihua

    The main aim of this dissertation was to characterize the damage mechanism and fatigue behavior of the acrylic particulate composite. This dissertation also investigated how the failure mechanism is influenced by changes in certain parameters including the volume fraction of particle, the interfacial bonding strength, the stiffness and thickness of the interphase, and the CTE mismatch between the particle and the matrix. Monotonic uniaxial tensile and compressive testing under various temperatures and strain rates, isothermal low-cycle mechanical testing and thermal cycling of a plate with a cutout were performed. The influence of the interfacial bonding strength between the particle and the matrix on the failure mechanism of the ATH filled PMMA was investigated using in situ observations under uniaxial loading conditions. For composites with weak interfacial bonding, the debonding is the major damage mode. For composites with strong interfacial bonding, the breakage of the agglomerate of particles is the major damage mode. Experimental studies also demonstrated the significant influence of interfacial bonding strength on the fatigue life of the ATH filled PMMA. The damage was characterized in terms of the elastic modulus degradation, the load-drop parameter, the plastic strain range and the hysteresis dissipation. Identifying the internal state variables that quantify material degradation under thermomechanical loading is an active research field. In this dissertation, the entropy production, which is a measure of the irreversibility of the thermodynamic system, is used as the metric for damage. The close correlation between the damage measured in terms of elastic modulus degradation and that obtained from the finite element simulation results validates the entropy based damage evolution function. A micromechanical model for acrylic particulate composites with imperfect interfacial bonds was proposed. Acrylic particulate composites are treated as three

  13. Particulate Matter and Gaseous Pollutions in Three Metropolises along the Chinese Yangtze River: Situation and Implications.

    Science.gov (United States)

    Mao, Mao; Zhang, Xiaolin; Yin, Yan

    2018-05-28

    The situation of criteria atmospheric pollutants, including particulate matter and trace gases (SO₂, NO₂, CO and O₃), over three metropolises (Chongqing, Wuhan, and Nanjing), representing the upstream, midstream and downstream portions of the Yangtze River Basin from September 2015 to August 2016 were analyzed. The maximum annual mean PM 2.5 and PM 10 concentrations were 61.3 and 102.7 μg/m³ in Wuhan, while highest annual average gaseous pollutions occurred in Nanjing, with 49.6 and 22.9 ppb for 8 h O₃ and NO₂, respectively. Compared to a few years ago, SO₂ and CO mass concentrations have dropped to well below the qualification standards, and the O₃ and NO₂ concentrations basically meet the requirements though occasionally is still high. In contrary, about 13%, 25%, 22% for PM 2.5 , and 4%, 17%, 15% for PM 10 exceed the Chinese Ambient Air Quality Standard (CAAQS) Grade II. Particulate matter, especially PM 2.5 , is the most frequent major pollutant to poor air quality with 73%, 64% and 88% accounting for substandard days. Mean PM 2.5 concentrations on PM 2.5 episode days are 2⁻3 times greater than non-episode days. On the basis of calculation of PM 2.5 /PM 10 and PM 2.5 /CO ratios, the enhanced particulate matter pollution on episode days is closely related to secondary aerosol production. Except for O₃, the remaining five pollutants exhibit analogous seasonal patterns, with the highest magnitude in winter and lowest in summer. The results of back trajectories show that air pollution displays synergistic effects on local emissions and long range transport. O₃ commonly demonstrated negative correlations with other pollutants, especially during winter, while moderate to strong positive correlation between particulate matter and NO₂, SO₂, CO were seen. Compared to pollutant substandard ratios over three megacities in eastern China (Beijing, Shanghai, and Guangzhou), the situation in our studied second-tier cities are also severe. The

  14. Spatial and temporal variability of particulate polycyclic aromatic hydrocarbons in Mexico City

    Directory of Open Access Journals (Sweden)

    D. A. Thornhill

    2008-06-01

    Full Text Available As part of the Megacities Initiative: Local and Global Research Observations (MILAGRO study in the Mexico City Metropolitan Area in March 2006, we measured particulate polycyclic aromatic hydrocarbons (PAHs and other gaseous species and particulate properties, including light absorbing carbon or effective black carbon (BC, at six locations throughout the city. The measurements were intended to support the following objectives: to describe spatial and temporal patterns in PAH concentrations, to gain insight into sources and transformations of PAHs and BC, and to quantify the relationships between PAHs and other pollutants. Total particulate PAHs at the Instituto Mexicano del Petróleo (T0 supersite located near downtown averaged 50 ng m−3, and aerosol active surface area averaged 80 mm2 m−3. PAHs were also measured on board the Aerodyne Mobile Laboratory, which visited six sites encompassing a mixture of different land uses and a range of ages of air parcels transported from the city core. A combination of analyses of time series, back trajectories, concentration fields, pollutant ratios, and correlation coefficients supports the concept of T0 as an urban source site, T1 as a receptor site with strong local sources, Pedregal and PEMEX as intermediate sites, Pico Tres Padres as a vertical receptor site, and Santa Ana as a downwind receptor site. Weak intersite correlations suggest that local sources are important and variable and that exposure to PAHs and BC cannot be represented by a single regional-scale value. The relationships between PAHs and other pollutants suggest that a variety of sources and ages of particles are present. Among carbon monoxide, nitrogen oxides (NOx, and carbon dioxide, particulate PAHs are most strongly correlated with NOx. Mexico City's PAH/BC mass ratio of 0.01 is similar to that found on a freeway loop in the Los Angeles area and approximately 8–30

  15. Spatial and temporal variability of particulate polycyclic aromatic hydrocarbons in Mexico City

    Science.gov (United States)

    Thornhill, D. A.; de Foy, B.; Herndon, S. C.; Onasch, T. B.; Wood, E. C.; Zavala, M.; Molina, L. T.; Gaffney, J. S.; Marley, N. A.; Marr, L. C.

    2008-06-01

    As part of the Megacities Initiative: Local and Global Research Observations (MILAGRO) study in the Mexico City Metropolitan Area in March 2006, we measured particulate polycyclic aromatic hydrocarbons (PAHs) and other gaseous species and particulate properties, including light absorbing carbon or effective black carbon (BC), at six locations throughout the city. The measurements were intended to support the following objectives: to describe spatial and temporal patterns in PAH concentrations, to gain insight into sources and transformations of PAHs and BC, and to quantify the relationships between PAHs and other pollutants. Total particulate PAHs at the Instituto Mexicano del Petróleo (T0 supersite) located near downtown averaged 50 ng m-3, and aerosol active surface area averaged 80 mm2 m-3. PAHs were also measured on board the Aerodyne Mobile Laboratory, which visited six sites encompassing a mixture of different land uses and a range of ages of air parcels transported from the city core. A combination of analyses of time series, back trajectories, concentration fields, pollutant ratios, and correlation coefficients supports the concept of T0 as an urban source site, T1 as a receptor site with strong local sources, Pedregal and PEMEX as intermediate sites, Pico Tres Padres as a vertical receptor site, and Santa Ana as a downwind receptor site. Weak intersite correlations suggest that local sources are important and variable and that exposure to PAHs and BC cannot be represented by a single regional-scale value. The relationships between PAHs and other pollutants suggest that a variety of sources and ages of particles are present. Among carbon monoxide, nitrogen oxides (NOx), and carbon dioxide, particulate PAHs are most strongly correlated with NOx. Mexico City's PAH/BC mass ratio of 0.01 is similar to that found on a freeway loop in the Los Angeles area and approximately 8 30 times higher than that found in other cities. Evidence also suggests that primary

  16. Collection and Characterization of Particulate from the Tore Supra Tokamak (Dec. 1999 Vent)

    International Nuclear Information System (INIS)

    Sharpe, John Phillip

    2002-01-01

    Particulate generated during the operation of a fusion device contributes to the radiological source term associated with accident scenarios in the device. Understanding the mechanisms generating the particulate and correctly describing its physical and chemical behavior is essential for safety analyses of future fusion devices. Knowledge of these mechanisms is gained by collecting and characterizing particulate matter from operating fusion facilities. Tokamak dust, the particulate matter generated during the operation of a tokamak fusion device, was collected from Tore Supra in December 1999, during the initial phase of the scheduled shutdown for installation of advanced plasma facing components. Tore Supra, located at CEA Cadarache, France, is presently the third largest operating tokamak with the capability of long-pulse operation. Eighteen super-conducting coils produce the 4.5 T magnetic field inside a vessel 2.4 m in major radius and 1.2 m in minor radius. Limiter and divertor regimes of operation are possible. In the divertor regime, the circular magnetic configuration is ergodized by six outboard resonant divertor modules that are covered with 12 m2 of carbon fiber composite (CFC) tiles. In addition, some field lines are diverted to actively cooled neutralizing plates made of CuCrZr bars covered with B4C. In the limiter regime, the plasma leans on the actively cooled inboard first wall or on a set of inertially cooled pumped limiters. The first wall area of 12 m2 is covered with both polycrystalline graphite tiles (83%) and CFC tiles (17%). The single outboard limiter is constructed of pyrolitic graphite, and the four toroidally symmetric bottom limiters are constructed of CFC. Figure 1.1 displays the relative location of plasma facing components within the plasma chamber of Tore Supra. In this report, we present in Section 2 the methods used to collect and analyze this dust and describe the selection of sampling locations. Section 3 includes a discussion

  17. Recent developments in particulate control with low-rank fuels

    International Nuclear Information System (INIS)

    Miller, S.J.; Laudal, D.L.

    1991-01-01

    Regulations appear to be focusing on fine particle emissions rather than total mass particulate emissions. There is concern that electrostatic precipitators (ESPs) may not be able to meet potentially stricter finer particle emission standards. A new development in the area of fabric filtration is the use of flue gas-conditioning agents to reduce particulate emissions and pressure drop. Theoretical analysis of the factors that control the size of a baghouse indicates that pulse-jet baghouses can be designed to operate at much higher air-to-cloth ratios than is currently employed. To help optimize performance of both ESPs and baghouses, quantitative characterization of the cohesive properties of fly ash is necessary. Appropriate methods are determination of aerated and packed porosity and measurement of tensile strength as a function of porosity

  18. Les Particules élémentaires: Self–portrait

    Directory of Open Access Journals (Sweden)

    Gerald Prince

    2012-01-01

    Full Text Available Perhaps no French novel in the past fifteen years has received more critical attention than Michel Houellebecq’s Les Particules élémentaires and perhaps none has evoked stronger reactions with regard to the (literary values it espouses and represents. This (self-portrait, like any portrait, accents certain features more than others. It concentrates on refuting charges of nihilism, reactionaryism, sexism, and racism; it stresses Houellebecq’s novel’s attention to form and its thematic clarity as well as its determination to say something rather than nothing; and, through a consideration of its references to various media, arts, and texts, of its pet peeves and true delights, it specifies the nature and ambition of Les Particules élémentaires , the kind of text it is or aspires to be.

  19. Biological mechanisms and translocation kinetics of particulate plutonium

    International Nuclear Information System (INIS)

    Bruenger, F.W.; Stevens, W.; Atherton, D.R.; Roswell, R.L.; Smith, J.M.

    1981-01-01

    The dissolution and elimination of particulate 239 Pu from its initial sites of deposition in phagocytic organs (the liver, spleen, and lung), as well as its translocation and redeposition in soft tissue organs and skeleton have been investigated. Beagles were injected intravenously with particulate Pu and sacrificed sequentially at times ranging from 33 to 830 days after injection. Equations that describe the overall retention of Pu in liver, spleen, lung, and bone were calculated. Plutonium mobilized from these organs either re-entered the blood stream and redeposited in the skeleton and liver parenchyma or was excreted. The protracted translocation of Pu to bone surfaces potentially exposes all cells involved in osteogenesis to continuous α-radiation, a situation that could enhance the hazard of developing osteosarcoma. A kinetic model that describes the translocation of Pu from the phagocytic compartments to blood and its subsequent redistribution to bone, liver, and other organs was formulated

  20. High diversity of fungi in air particulate matter.

    Science.gov (United States)

    Fröhlich-Nowoisky, Janine; Pickersgill, Daniel A; Després, Viviane R; Pöschl, Ulrich

    2009-08-04

    Fungal spores can account for large proportions of air particulate matter, and they may potentially influence the hydrological cycle and climate as nuclei for water droplets and ice crystals in clouds, fog, and precipitation. Moreover, some fungi are major pathogens and allergens. The diversity of airborne fungi is, however, not well-known. By DNA analysis we found pronounced differences in the relative abundance and seasonal cycles of various groups of fungi in coarse and fine particulate matter, with more plant pathogens in the coarse fraction and more human pathogens and allergens in the respirable fine particle fraction (<3 microm). Moreover, the ratio of Basidiomycota to Ascomycota was found to be much higher than previously assumed, which might also apply to the biosphere.

  1. Bioengineering towards self-assembly of particulate vaccines.

    Science.gov (United States)

    Rehm, Bernd H A

    2017-12-01

    There is an unmet demand for safe and efficient vaccines for prevention of various infectious diseases. Subunit vaccines comprise selected pathogen specific antigens are a safe alternative to whole organism vaccines. However they often lack immunogenicity. Natural and synthetic self-assembling polymers and proteins will be reviewed in view their use to encapsulate and/or display antigens to serve as immunogenic antigen carriers for induction of protective immunity. Recent advances made in in vivo assembly of antigen-displaying polyester inclusions will be a focus. Particulate vaccines are inherently immunogenic due to enhanced uptake by antigen presenting cells which process antigens mediating adaptive immune responses. Bioengineering approaches enable the design of tailor-made particulate vaccines to fine tune immune responses towards protective immunity. Copyright © 2017 Elsevier Ltd. All rights reserved.

  2. High efficiency particulate removal with sintered metal filters

    International Nuclear Information System (INIS)

    Kirstein, B.E.; Paplawsky, W.J.; Pence, D.T.; Hedahl, T.G.

    1981-01-01

    Because of their particle removal efficiencies and durability, sintered metal filters have been chosen for high efficiency particulate air (HEPA) filter protection in the off-gas treatment system for the proposed Idaho National Engineering Laboratory Transuranic Waste Treatment Facility. Process evaluation of sintered metal filters indicated a lack of sufficient process design data to ensure trouble-free operation. Subsequence pilot scale testing was performed with flyash as the test particulate. The test results showed that the sintered metal filters can have an efficiency greater than 0.9999999 for the specific test conditions used. Stable pressure drop characteristics were observed in pulsed and reversed flow blowback modes of operation. Over 4900 hours of operation were obtained with operating conditions ranging up to approximately 90 0 C and 24 vol % water vapor in the gas stream

  3. Gaseous and particulate emissions from a DC arc melter.

    Science.gov (United States)

    Overcamp, Thomas J; Speer, Matthew P; Griner, Stewart J; Cash, Douglas M

    2003-01-01

    Tests treating soils contaminated with metal compounds and radionuclide surrogates were conducted in a DC arc melter. The soil melted, and glassy or ceramic waste forms with a separate metal phase were produced. Tests were run in the melter plenum with either air or N2 purge gases. In addition to nitrogen, the primary emissions of gases were CO2, CO, oxygen, methane, and oxides of nitrogen (NO(x)). Although the gas flow through the melter was low, the particulate concentrations ranged from 32 to 145 g/m3. Cerium, a nonradioactive surrogate for plutonium and uranium, was not enriched in the particulate matter (PM). The PM was enriched in cesium and highly enriched in lead.

  4. Development of a Low-Cost Particulate Matter Monitor

    Energy Technology Data Exchange (ETDEWEB)

    White, Richard M.; Apte, Michael G.; Gundel, Lara A.; Black, Justin

    2008-08-01

    We describe a small, inexpensive portable monitor for airborne particulates, composed of the following elements: a. A simple size-selective inlet (vertical elutriator) that permits only particles below a pre-set diameter to pass and enter the measurement section; b. A measurement section in which passing particles are deposited thermophoretically on a micro-fabricated resonant piezoelectric mass sensor; c. An optical characterization module co-located with the mass sensor module that directs infrared and ultraviolet beams through the deposit. The emergent optical beams are detected by a photodiode. The optical absorption of the deposit can be measured in order to characterize the deposit, and determine how much is due to diesel exhaust and/or environmental tobacco smoke; and d. A small pump that moves air through the device, which may also be operated in a passive mode. The component modules were designed by the project team, and fabricated at UCB andLBNL. Testing and validation were performed in a room-sized environmental chamber at LBNL in to which was added either environmental tobacco smoke (ETS, produced by a cigarette smoking machine) or diesel exhaust (from a conventional diesel engine). Two pilot field tests in a dwelling compared the monitor with existing aerosol instruments during exposure to infiltrated ambient air to which cigarette smoke, diesel exhaust, wood smoke and cooking fumes were added. The limit of detection (LOD) derived from statistical analysis of field data is 18 mu g m-3, at the 99percent confidence level. The monitor weighs less than 120 g and has a volume of roughly 250 cm3. Power consumption is approximately 100 milliwatts. During this study, the optical component of the device was not fully implemented and has been left for future efforts. Suggested improvements in the current prototype include use of integrated thermal correction, reconfiguration of the resonator for increased particle collection area, increased thermophoretic

  5. Experimental investigation of particulate debris spreading in a pool

    Energy Technology Data Exchange (ETDEWEB)

    Konovalenko, A., E-mail: kono@kth.se [Division of Nuclear Power Safety, Royal Institute of Technology (KTH) , Roslagstullsbacken 21, Stockholm 106 91 (Sweden); Basso, S., E-mail: simoneb@kth.se [Division of Nuclear Power Safety, Royal Institute of Technology (KTH) , Roslagstullsbacken 21, Stockholm 106 91 (Sweden); Kudinov, P., E-mail: pkudinov@kth.se [Division of Nuclear Power Safety, Royal Institute of Technology (KTH) , Roslagstullsbacken 21, Stockholm 106 91 (Sweden); Yakush, S.E., E-mail: yakush@ipmnet.ru [Institute for Problems in Mechanics of the Russian Academy of Sciences, Ave. Vernadskogo 101 Bldg 1, Moscow 119526 (Russian Federation)

    2016-02-15

    Termination of severe accident progression by core debris cooling in a deep pool of water under reactor vessel is considered in several designs of light water reactors. However, success of this accident mitigation strategy is contingent upon the effectiveness of heat removal by natural circulation from the debris bed. It is assumed that a porous bed will be formed in the pool in the process of core melt fragmentation and quenching. Debris bed coolability depends on its properties and system conditions. The properties of the bed, including its geometry are the outcomes of the debris bed formation process. Spreading of the debris particles in the pool by two-phase turbulent flows induced by the heat generated in the bed can affect the shape of the bed and thus influence its coolability. The goal of this work is to provide experimental data on spreading of solid particles in the pool by large-scale two-phase flow. The aim is to provide data necessary for understanding of separate effects and for development and validation of models and codes. Validated codes can be then used for prediction of debris bed formation under prototypic severe accident conditions. In PDS-P (Particulate Debris Spreading in the Pool) experiments, air injection at the bottom of the test section is employed as a means to create large-scale flow in the pool in isothermal conditions. The test section is a rectangular tank with a 2D slice geometry, it has fixed width (72 mm), adjustable length (up to 1.5 m) and allows water filling to the depth of up to 1 m. Variable pool length and depth allows studying two-phase circulating flows of different characteristic sizes and patterns. The average void fraction in the pool is determined by video recording and subsequent image processing. Particles are supplied from the top of the facility above the water surface. Results of several series of PDS-P experiments are reported in this paper. The influence of the gas flow rate, pool dimensions, particle density

  6. Fine particulate matter (PM) and organic speciation of fireplace emissions

    International Nuclear Information System (INIS)

    Purvis, C.R.; McCrillis, R.C.; Kariher, P.H.

    2000-01-01

    This paper presents a summary of fireplace particle size and organic speciation data gathered to date in an ongoing project. Tests are being conducted in a residential wood combustion (RWC) laboratory on three factory-built fireplaces. RWC wood smoke particles <10 microm (PM10) consist primarily of a mixture of organic compounds that have condensed into droplets; therefore, the size distribution and total mass are influenced by temperature of the sample during its collection. During the series 1 tests (15 tests), the dilution tunnel used to cool and dilute the stack gases gave an average mixed gas temperature of 47.3 C and an average dilution ration of 4.3. Averages for the PM2.5 (particles <2.5 microm) and PM10 fractions were 74 and 84%, respectively. For the series 2 tests, the dilution tunnel was modified, reducing the average mixed gas temperatures to 33.8 C and increasing the average dilution ratio to 11.0 in tests completed to date. PM2.5 and PM10 fractions were 83 and 91%, respectively. Since typical winter-time mixed gas temperatures would usually be less than 10 C, these size fraction results probably represent the lower bound; the PM10 and PM2.5 size fraction results might be higher at typical winter temperatures. The particles collected on the first stage were light gray and appeared to include inorganic ash. Particles collected on the remainder of the stages were black and appeared to be condensed organics because there was noticeable lateral bleeding of the collected materials into the filter substrate. Total particulate emission rates ranged from 10.3 to 58.4 g/h; corresponding emission factors ranged from 3.3 to 14.9 g/kg of dry wood burned. A wide range of Environmental Protection Agency (EPA) Method 8270 semivolatile organic compounds were found in the emissions; of the 17 target compounds quantified, major constituents are phenol, 2-methylphenol, 4-methylphenol, 2,4-dimethylphenol, and naphthalene

  7. Enhancement in secondary particulate matter production due to mountain trapping

    Science.gov (United States)

    Yao, Teng; Fung, J. C. H.; Ma, H.; Lau, A. K. H.; Chan, P. W.; Yu, J. Z.; Xue, J.

    2014-10-01

    As China's largest economic development zone, the Pearl River Delta (PRD) is subject to particulate matter (PM) and visibility deterioration problems. Due to high PM concentration, haze days impacting ambient visibility have occurred frequently in this region. Besides visibility impairment, PM pollution also causes a negative impact on public health. These negative impacts have heightened the need to improve our understanding of the PM pollution of the PRD region. One major cause of the PRD pollution problem is cold front passages in the winter; however, the mechanism of pollution formation stays unclear. In this study, the Comprehensive Air Quality Model (CAMx) is utilized to investigate the detailed PM production and transport mechanisms in the PRD. Simulated concentrations of PM2.5 species, which have a good correlation with observation, show that sulfate and nitrate are the dominant pollutants among different PM2.5 species. Before the cold front passage a large amount of gas-phase and particle-phase pollutants are transported to the mountainous regions in the north of the PRD, and become trapped by the terrain. Over the mountain regions, cloud driven by upwelling flow promotes aqueous-phase reactions including oxidations of PM precursors such as SO2 and NO2. By this process, production of secondary PM is enhanced. When the cold front continues to advance further south, PM is transported to the PRD cities, and suppressed into a thin layer near the ground by a low planetary boundary layer (PBL). Thus high PM concentration episodes take place in the PRD cities. After examining production and transportation pathways, this study presents that the complex terrain configuration would block pollutant dispersion, provide cloudy environment, and advance secondary PM production. Previous studies have pointed out that pollution emitted from outside this region largely influences the air quality in the PRD; however, this study shows that pollutants from the outside could be

  8. The mammalian response to lunar particulates.

    Science.gov (United States)

    Holland, J. M.; Simmonds, R. C.

    1973-01-01

    The response of germfree mice to subcutaneous and intraperitoneal injection of aqueous suspensions of lunar fine material (LFM) was evaluated. Both uninjected mice and mice injected with dry heat sterilized LFM were included as controls. After injection, the majority of mice were subjected to serial sacrifice to assess the time course of the tissue response. A smaller group of animals were held for lifespan studies. The observations suggest that LFM is relatively insoluble in tissue and that, while acting as a low grade irritant, it has little tendency to evoke reactive fibrosis.

  9. Scavenging of particulate elemental carbon into stratus cloud

    Energy Technology Data Exchange (ETDEWEB)

    Kaneyasu, Naoki; Maeda, Takahisa [National Inst. for Resources and Environment, Tsukuba (Japan)

    1995-12-31

    The role of atmospheric aerosols on the alternation of cloud radiative properties has widely been recognized since 1977 when Tomey and his coworkers have numerically demonstrated the effect of increased cloud condensation nuclei (CCN). At the same time, cloud processes are one of the most important factor in controlling the residence time of atmospheric aerosols through the wet removal process. The redistribution of the size and the composition of pre-cloud aerosols is also the important role of cloud process on the nature of atmospheric aerosols. In order to study these cloud-aerosol interaction phenomena, the incorporation of aerosols into cloud droplets is the first mechanism to be investigated. Among the several mechanisms for the incorporation of aerosols into cloud droplets, nucleation scavenging, is the potentially important process in the view of cloud-aerosol interactions. This critical supersaturation for a given radius of a particle can be theoretically calculated only for pure species, e.g., NaCl. However, a significant portion of the atmospheric aerosols is in the form of internal mixture of multiple components, such as SO{sub 4}{sup 2-}, NO{sub 3}{sup -}, NH{sub 4}{sup +} and particulate elemental carbon. The knowledge acquired by field measurements is therefore essential on this subject. The present study focuses on the scavenging of major components of urban atmospheric aerosols, in particular the incorporation of particulate elemental carbon into stratus cloud. Particulate elemental carbon is the strongest light absorbing species in visible region, and has potential to change the optical property of cloud. On the basis of the measurements conducted at a mountain located in the suburb of Tokyo Metropolitan area, Japan, some insights on the scavenging of particulate elemental carbon into cloud droplet will be presented

  10. Ultrastructural immunocytochemistry of particulate fractions using polyvinyl chloride microculture wells.

    Science.gov (United States)

    Wray, B E; Sealock, R

    1984-10-01

    A method is described for immunoelectron microscopy of particulate subcellular fractions using polyvinyl chloride (soft) microculture wells as mechanical supports and reaction vessels. Appropriate quantities of particles are centrifuged onto the well bottoms, fixed and permeabilized if necessary, then labeled by standard procedures, fixed in glutaraldehyde and tannic acid, and prepared for thin section electron microscopy. The centrifugation, the fixations, and the embedment in Epon are discussed in detail.

  11. Removal of both dissolved and particulate iron from groundwater

    OpenAIRE

    H. van Dijk; H. Leijssen; L. Rietveld; A. Abrahamse; K. Teunissen

    2008-01-01

    Iron is the primary source for discolouration problems in the drinking water distribution system. The removal of iron from groundwater is a common treatment step in the production of drinking water. Even when clear water meets the drinking water standards, the water quality in the distribution system can deteriorate due to settling of iron (hydroxide) particles or post-treatment flocculation of dissolved iron. Therefore it is important to remove dissolved and particulate iron to a large exten...

  12. Characterization of Urban Runoff Pollution between Dissolved and Particulate Phases

    OpenAIRE

    Wei, Zhang; Simin, Li; Fengbing, Tang

    2013-01-01

    To develop urban stormwater management effectively, characterization of urban runoff pollution between dissolved and particulate phases was studied by 12 rainfall events monitored for five typical urban catchments. The average event mean concentration (AEMC) of runoff pollutants in different phases was evaluated. The AEMC values of runoff pollutants in different phases from urban roads were higher than the ones from urban roofs. The proportions of total dissolved solids, total dissolved nitr...

  13. Chemical and biological characterization of urban particulate matter

    International Nuclear Information System (INIS)

    Agurell, E.; Alsberg, T.; Assefaz-Redda, Y.

    1990-11-01

    Airborne particulate matter has been collected on glass fiber filter by high volume sampling in the Goeteborg urban area. The samples were, after extraction with respect to organic components, tested for biological effect in the Salmonella mutagenicity assay, affinity to the cytosol TCDD receptor and toxicity towards a mammalian cell system and analysed chemically for selected polycyclic aromatic compounds. A series of samples collected simultaneously at a street level location and a rooftop site showed that most parameters associated with the organic compounds adsorbed to airborne particulate matter has similar concentrations at the two levels. The differences observed for the mutagenic effect in different strains and conditions showed that the rooftop samples had a different composition compared to the street samples indicating that atmospheric transformations have occurred. Chemical fractionation of representative samples showed that the distribution of mutagenic activity among different fractions is dissimilar to the distribution obtained in the fractionation of both gasoline and diesel engine exhaust particles. Partial least squares regression analysis showed qualitatively that diesel exhaust is a major source of airborne particulate mutagenic activity and source apportionment with chemical mass balance and multilinear regression corroborated this quantitatively. The multilinear regression analysis gave the result that the airborne activity in Salmonella TA90-S9 originated to 54±4% from diesel exhaust and to 26±3% from gasoline exhaust. The contribution is more equal for the activity measured with TA98+S9. The usefulness of short-term bioassays as an addition to chemical analysis of airborne particulate matter depends on whether only polycylic aromatic hydrocarbons (PAH) are major carcinogens, as has been suggested in the literature, or whether also other polycyclic aromatic compound (PAC) are of importance. (au)

  14. Scavenging of particulate elemental carbon into stratus cloud

    Energy Technology Data Exchange (ETDEWEB)

    Kaneyasu, Naoki; Maeda, Takahisa [National Inst. for Resources and Environment, Tsukuba (Japan)

    1996-12-31

    The role of atmospheric aerosols on the alternation of cloud radiative properties has widely been recognized since 1977 when Tomey and his coworkers have numerically demonstrated the effect of increased cloud condensation nuclei (CCN). At the same time, cloud processes are one of the most important factor in controlling the residence time of atmospheric aerosols through the wet removal process. The redistribution of the size and the composition of pre-cloud aerosols is also the important role of cloud process on the nature of atmospheric aerosols. In order to study these cloud-aerosol interaction phenomena, the incorporation of aerosols into cloud droplets is the first mechanism to be investigated. Among the several mechanisms for the incorporation of aerosols into cloud droplets, nucleation scavenging, is the potentially important process in the view of cloud-aerosol interactions. This critical supersaturation for a given radius of a particle can be theoretically calculated only for pure species, e.g., NaCl. However, a significant portion of the atmospheric aerosols is in the form of internal mixture of multiple components, such as SO{sub 4}{sup 2-}, NO{sub 3}{sup -}, NH{sub 4}{sup +} and particulate elemental carbon. The knowledge acquired by field measurements is therefore essential on this subject. The present study focuses on the scavenging of major components of urban atmospheric aerosols, in particular the incorporation of particulate elemental carbon into stratus cloud. Particulate elemental carbon is the strongest light absorbing species in visible region, and has potential to change the optical property of cloud. On the basis of the measurements conducted at a mountain located in the suburb of Tokyo Metropolitan area, Japan, some insights on the scavenging of particulate elemental carbon into cloud droplet will be presented

  15. Stabilization void-fill encapsulation high-efficiency particulate filters

    International Nuclear Information System (INIS)

    Alexander, R.G.; Stewart, W.E.; Phillips, S.J.; Serkowski, M.M.; England, J.L.; Boynton, H.C.

    1994-05-01

    This report discusses high-efficiency particulate air (HEPA) filter systems that which are contaminated with radionuclides are part of the nuclear fuel processing systems conducted by the US Department of Energy (DOE) and require replacement and safe and efficient disposal for plant safety. Two K-3 HEPA filters were removed from service, placed burial boxes, buried, and safely and efficiently stabilized remotely which reduced radiation exposure to personnel and the environment

  16. Validation of NAA Method for Urban Particulate Matter

    International Nuclear Information System (INIS)

    Woro Yatu Niken Syahfitri; Muhayatun; Diah Dwiana Lestiani; Natalia Adventini

    2009-01-01

    Nuclear analytical techniques have been applied in many countries for determination of environmental pollutant. Method of NAA (neutron activation analysis) representing one of nuclear analytical technique of that has low detection limits, high specificity, high precision, and accuracy for large majority of naturally occurring elements, and ability of non-destructive and simultaneous determination of multi-elemental, and can handle small sample size (< 1 mg). To ensure quality and reliability of the method, validation are needed to be done. A standard reference material, SRM NIST 1648 Urban Particulate Matter, has been used to validate NAA method. Accuracy and precision test were used as validation parameters. Particulate matter were validated for 18 elements: Ti, I, V, Br, Mn, Na, K, Cl, Cu, Al, As, Fe, Co, Zn, Ag, La, Cr, and Sm,. The result showed that the percent relative standard deviation of the measured elemental concentrations are found to be within ranged from 2 to 14,8% for most of the elements analyzed whereas Hor rat value in range 0,3-1,3. Accuracy test results showed that relative bias ranged from -11,1 to 3,6%. Based on validation results, it can be stated that NAA method is reliable for characterization particulate matter and other similar matrix samples to support air quality monitoring. (author)

  17. Controlling exposure to DPM : diesel particulate filters vs. biodiesel

    International Nuclear Information System (INIS)

    Bugarski, A.D.; Shi, X.C.

    2009-01-01

    In order to comply with Mine Safety and Health Administration regulations, mining companies are required to reduce miners exposures to diesel particulate matter (DPM) to 160 μg/m 3 of total carbon. Diesel particulate filter (DPF) systems, disposable filter elements (DFEs), and diesel oxidation catalysts (DOCs) are among the most effective strategies and technologies for curtailing DPM at its source. Substituting diesel fuel with biodiesel blends is also considered to be a plausible solution by many underground mine operators. Studies were conducted at the National Institute for Occupational Safety and Health Diesel Laboratory at Lake Lynn Experimental Mine to evaluate various control technologies and strategies available to the underground mining industry to reduce exposure to DPM. The physical, chemical and toxicological properties of diesel aerosols (DPM) emitted by engines in an underground mine were also evaluated. The DPF and DFE systems were found to be highly effective in reducing total particulate and elemental carbon mass concentrations, total aerosol surface concentrations and, in most cases, concentrations of diesel aerosols in occupational settings such as underground mines. Soy methyl ester (SME) biodiesel fuels had the potential to reduce the mine air concentrations of total DPM, although the rate of reduction varied depending on engine operating conditions. The disadvantage of using biodiesel fuels was an increase in the fraction of particle-bound volatile organics and concentration of aerosols for light-load engine operating conditions.

  18. Particulate air pollution and daily mortality in Detroit.

    Science.gov (United States)

    Schwartz, J

    1991-12-01

    Particulate air pollution has been associated with increased mortality during episodes of high pollution concentrations. The relationship at lower concentrations has been more controversial, as has the relative role of particles and sulfur dioxide. Replication has been difficult because suspended particle concentrations are usually measured only every sixth day in the U.S. This study used concurrent measurements of total suspended particulates (TSP) and airport visibility from every sixth day sampling for 10 years to fit a predictive model for TSP. Predicted daily TSP concentrations were then correlated with daily mortality counts in Poisson regression models controlling for season, weather, time trends, overdispersion, and serial correlation. A significant correlation (P less than 0.0001) was found between predicted TSP and daily mortality. This correlation was independent of sulfur dioxide, but not vice versa. The magnitude of the effect was very similar to results recently reported from Steubenville, Ohio (using actual TSP measurements), with each 100 micrograms/m3 increase in TSP resulting in a 6% increase in mortality. Graphical analysis indicated a dose-response relationship with no evidence of a threshold down to concentrations below half of the National Ambient Air Quality Standards for particulate matter.

  19. Subsurface migration of radioactive waste materials by particulate transport

    International Nuclear Information System (INIS)

    Eichholz, G.G.; Craft, T.F.; Powell, G.F.; Wahlig, B.G.

    1982-01-01

    The role of suspended particles as carriers of dissolved nuclides from high-level radioactive waste repositories has been investigated. Depending on the concentrations of suspended particles and the nature of the invading water, it has been found that cationic nuclides may be competitively adsorbed on suspended clay particles, the partitioning being largely determined by pH, temperature, and comparative surface areas of particulates and surrounding rocks. Column tests with activated particles have been conducted and showed that the clay particles pass readily through porous mineral columns and are increasingly retained if salinity is increased. Retention in basalt columns is stronger in the presence of high concentrations of sodium and calcium ions and has been explained in terms of van der Waals forces. The range of particulate migration then depends on the condition of the rock surfaces, the persistence of a clay coating, and the total dissolved ion concentration. For adsorbable waste ions, this may represent a pathway comparable in significance to ion-exchange-controlled migration. For some bed materials, the particulate movement displayed a prompt and a delayed component; the nature of the delay mechanism is not fully understood at present

  20. Filtration of Carbon Particulate Emissions from a Plasma Pyrolysis Assembly

    Science.gov (United States)

    Agui, Juan H.; Green, Robert; Vijayakumar, R.; Berger, Gordon; Greenwood, Zach; Abney, Morgan; Peterson, Elspeth

    2016-01-01

    NASA is investigating plasma pyrolysis as a candidate technology that will enable the recovery of hydrogen from the methane produced by the ISS Sabatier Reactor. The Plasma Pyrolysis Assembly (PPA) is the current prototype of this technology which converts the methane product from the Carbon Dioxide Reduction Assembly (CRA) to acetylene and hydrogen with 90% or greater conversion efficiency. A small amount of solid carbon particulates are generated as a side product and must be filtered before the acetylene is removed and the hydrogen-rich gas stream is recycled back to the CRA. We discuss developmental work on several options for filtering out the carbon particulate emissions from the PPA exit gas stream. The filtration technologies and concepts investigated range from fibrous media to monolithic ceramic and sintered metal media. This paper describes the different developed filter prototypes and characterizes their performance from integrated testing at the Environmental Chamber (E-Chamber) at MSFC. In addition, characterization data on the generated carbon particulates, that help to define filter requirements, are also presented.

  1. An overview of particulate emissions from residential biomass combustion

    Science.gov (United States)

    Vicente, E. D.; Alves, C. A.

    2018-01-01

    Residential biomass burning has been pointed out as one of the largest sources of fine particles in the global troposphere with serious impacts on air quality, climate and human health. Quantitative estimations of the contribution of this source to the atmospheric particulate matter levels are hard to obtain, because emission factors vary greatly with wood type, combustion equipment and operating conditions. Updated information should improve not only regional and global biomass burning emission inventories, but also the input for atmospheric models. In this work, an extensive tabulation of particulate matter emission factors obtained worldwide is presented and critically evaluated. Existing quantifications and the suitability of specific organic markers to assign the input of residential biomass combustion to the ambient carbonaceous aerosol are also discussed. Based on these organic markers or other tracers, estimates of the contribution of this sector to observed particulate levels by receptor models for different regions around the world are compiled. Key areas requiring future research are highlighted and briefly discussed.

  2. Modelisation des emissions de particules microniques et nanometriques en usinage

    Science.gov (United States)

    Khettabi, Riad

    La mise en forme des pieces par usinage emet des particules, de tailles microscopiques et nanometriques, qui peuvent etre dangereuses pour la sante. Le but de ce travail est d'etudier les emissions de ces particules pour fins de prevention et reduction a la source. L'approche retenue est experimentale et theorique, aux deux echelles microscopique et macroscopique. Le travail commence par des essais permettant de determiner les influences du materiau, de l'outil et des parametres d'usinage sur les emissions de particules. E nsuite un nouveau parametre caracterisant les emissions, nomme Dust unit , est developpe et un modele predictif est propose. Ce modele est base sur une nouvelle theorie hybride qui integre les approches energetiques, tribologiques et deformation plastique, et inclut la geometrie de l'outil, les proprietes du materiau, les conditions de coupe et la segmentation des copeaux. Il ete valide au tournage sur quatre materiaux: A16061-T6, AISI1018, AISI4140 et fonte grise.

  3. Hyperspectral imaging applied to complex particulate solids systems

    Science.gov (United States)

    Bonifazi, Giuseppe; Serranti, Silvia

    2008-04-01

    HyperSpectral Imaging (HSI) is based on the utilization of an integrated hardware and software (HW&SW) platform embedding conventional imaging and spectroscopy to attain both spatial and spectral information from an object. Although HSI was originally developed for remote sensing, it has recently emerged as a powerful process analytical tool, for non-destructive analysis, in many research and industrial sectors. The possibility to apply on-line HSI based techniques in order to identify and quantify specific particulate solid systems characteristics is presented and critically evaluated. The originally developed HSI based logics can be profitably applied in order to develop fast, reliable and lowcost strategies for: i) quality control of particulate products that must comply with specific chemical, physical and biological constraints, ii) performance evaluation of manufacturing strategies related to processing chains and/or realtime tuning of operative variables and iii) classification-sorting actions addressed to recognize and separate different particulate solid products. Case studies, related to recent advances in the application of HSI to different industrial sectors, as agriculture, food, pharmaceuticals, solid waste handling and recycling, etc. and addressed to specific goals as contaminant detection, defect identification, constituent analysis and quality evaluation are described, according to authors' originally developed application.

  4. High Efficiency Particulate Air (HEPA) Filter Generation, Characterization, and Disposal Experiences at the Oak Ridge National Laboratory

    International Nuclear Information System (INIS)

    Coffey, D. E.

    2002-01-01

    High Efficiency Particulate Air filtration is an essential component of the containment and ventilation systems supporting the research and development activities at the Oak Ridge National Laboratory. High Efficiency Particulate Air filters range in size from 7.6cm (3 inch) by 10.2 cm (4 inch) cylindrical shape filters to filter array assemblies up to 2.1 m (7 feet) high by 1.5 m (5 feet) wide. Spent filters are grouped by contaminates trapped in the filter media and become one of the components in the respective waste stream. Waste minimization and pollution prevention efforts are applied for both radiological and non-radiological applications. Radiological applications include laboratory hoods, glove boxes, and hot cells. High Efficiency Particulate Air filters also are generated from intake or pre-filtering applications, decontamination activities, and asbestos abatement applications. The disposal avenues include sanitary/industrial waste, Resource Conservation and Recovery Act and Toxic Substance Control Act, regulated waste, solid low-level waste, contact handled transuranic, and remote handled transuranic waste. This paper discusses characterization and operational experiences associated with the disposal of the spent filters across multiple applications

  5. Historical performance of particulate settleable in a municipality located in the ceramic cluster of Castellón (Spain)

    Science.gov (United States)

    Pardo, P.; Sanfeliu, Teófilo; Soriano, A.; Pallarés, S.; Vicente, A. B.

    2010-05-01

    Air pollution can be defined as: "the introduction into the atmosphere by man, directly or indirectly, of substances or energy with have effects deleterious of such a nature that endangers human health, causing damage to biological resources and to ecosystems, which impair material goods and to harm or interfere with amenities and other legitimate uses of the environment". One of the main pollutants in air is the particulate matter. This material particulate includes settleable, particles larger than 10 μm that remain airborne for relatively short periods of time. For what its effects are most pronounced in the vicinity of the emitting sources. The study area is located in the city of Alcora. This population is located in the region eastern of the province of Castellon (Spain). The municipality of Alcora has a high industrial density, highlighting framed companies in chemical industry and non-metallic mineral products. The area has a high traffic density due to the proximity of population to various roads. These two factors point peaks rise high concentration of atmospheric particulate pollutants. The purpose of this paper is conducting a retrospective view of the evolution of settleable particulate concentrations. Settleable particulate samples were collected with a sensor BRITISH STANDARD PS particles during the period between January 2000 and December 2005. REFERENCES Gómez E.T.; Sanfeliu T.; Rius J.; Jordán M.M. (2005) "Evolution, sources and distribution of mineral particles and amorphous phase of atmospheric aerosol in an industrial and Mediterranean coastal area" Water, air and Soil Pollution 167:311-330. Sanfeliu T.; Gómez E.T.; Hernánde D.;Martín J.D.; Ovejero M.; Jordán M.M. (2002). "Avaluation of the particulate atmospheric aerosol in the urban area on Castellón, Spain". Protecction and conservation of the cultural heritage of the Mediterranean cities. Eds. Galán and Zezza Ed. Swets&Zeitlinger, Lisse pp:61-64. Sanfeliu T.; Jordán M.M.; Gómez E

  6. Measured and modelled concentrations and vertical profiles of airborne particulate matter within the boundary layer of a street canyon

    International Nuclear Information System (INIS)

    Colls, J.J.; Micallef, A.

    1999-01-01

    Concentrations and vertical profiles of various fractions of airborne particulate matter (suspended particulate matter (SPM), PM 10 and PM 2.5 ) have been measured over the first three metres from ground in a street canyon. Measurements were carried out using automated near real-time apparatus called the Kinetic Sequential Sampling (KSS) system. KSS system is essentially an electronically-controlled lift carrying a real-time particle monitor for sampling air sequentially, at different heights within the breathing zone, which includes all heights within the surface layer of a street canyon at which people may breathe. Data is automatically logged at the different receptor levels, for the determination of the average vertical concentration profile of airborne particulate matter. For measuring the airborne particle concentration, a Grimm Dust Monitor 1.104/5 was used. The recorded data also allows for time series analysis of airborne particulate matter concentration at different heights. Time series data and hourly-average vertical concentration profiles in the boundary layer of the confines of a street are thought to be mainly determined by traffic emissions and traffic associated processes. Hence the measured data were compared with results of a street canyon emission-dispersion model in time and space. This Street Level Air Quality (SLAQ) model employs the plume-box technique and includes modules for simulating vehicle-generated effects such as thermally- and mechanically-generated turbulence and resuspension of road dust. Environmental processes, such as turbulence resulting from surface sensible heat and the formation of sulphate aerosol from sulphur dioxide exhaust emissions, are taken into account. The paper presents an outline description of the measuring technique and model used, and a comparison of the measured and modelled data

  7. Heat transfer phenomena during thermal processing of liquid particulate mixtures-A review.

    Science.gov (United States)

    Singh, Anubhav Pratap; Singh, Anika; Ramaswamy, Hosahalli S

    2017-05-03

    During the past few decades, food industry has explored various novel thermal and non-thermal processing technologies to minimize the associated high-quality loss involved in conventional thermal processing. Among these are the novel agitation systems that permit forced convention in canned particulate fluids to improve heat transfer, reduce process time, and minimize heat damage to processed products. These include traditional rotary agitation systems involving end-over-end, axial, or biaxial rotation of cans and the more recent reciprocating (lateral) agitation. The invention of thermal processing systems with induced container agitation has made heat transfer studies more difficult due to problems in tracking the particle temperatures due to their dynamic motion during processing and complexities resulting from the effects of forced convection currents within the container. This has prompted active research on modeling and characterization of heat transfer phenomena in such systems. This review brings to perspective, the current status on thermal processing of particulate foods, within the constraints of lethality requirements from safety view point, and discusses available techniques of data collection, heat transfer coefficient evaluation, and the critical processing parameters that affect these heat transfer coefficients, especially under agitation processing conditions.

  8. Microstructural and mechanical properties of titanium particulate reinforced magnesium composite materials

    Energy Technology Data Exchange (ETDEWEB)

    Umeda, Junko; Kawakami, Masashi [Joining and Welding Research Institute, Osaka University, 11-1 Mihogaoka, Ibaragi, Osaka 567-0047 (Japan); Kondoh, Katsuyoshi, E-mail: kondoh@jwri.osaka-u.ac.jp [Joining and Welding Research Institute, Osaka University, 11-1 Mihogaoka, Ibaragi, Osaka 567-0047 (Japan); Ayman, El-Sayed; Imai, Hisashi [Joining and Welding Research Institute, Osaka University, 11-1 Mihogaoka, Ibaragi, Osaka 567-0047 (Japan)

    2010-10-01

    Pure titanium (Ti) particulate reinforced pure magnesium (Mg) composite materials were fabricated via powder metallurgy route, and their microstructural and mechanical properties were evaluated. When using the elemental mixture of pure Mg and pure Ti powders and consolidating them by solid-state sintering process, no significant increase in tensile strength of the composites was obtained, because of poor bonding strength at the interface between {alpha}-Mg matrix and Ti particles. In particular, coarse magnesium oxide (MgO) particles of about 100 nm were formed via thermite reaction between TiO{sub 2} surface films of Ti particles and Mg raw powders and resulted in preventing the improvement of the mechanical properties of the composite material. On the other hand, when using the atomized pure Mg composite powders reinforced with Ti particulates, their extruded composite material showed obviously improved tensile strength and good elongation, compared to the extruded pure Mg powder material including no Ti particle. The obvious improvement in the tensile strength was due to the restriction of dislocation movement by Ti reinforcements under applied tensile load.

  9. Estimating Anthropogenic Emissions of Hydrogen Chloride and Fine Particulate Chloride in China

    Science.gov (United States)

    Fu, X.; Wang, T.; Wang, S.; Zhang, L.

    2017-12-01

    Nitryl chloride (ClNO2) can significantly impact the atmospheric photochemistry via photolysis and subsequent reactions of chlorine radical with other gases. The formation of ClNO2 in the atmosphere is sensitive to the emissions of chlorine-containing particulates from oceanic and anthropogenic sources. For China, the only available anthropogenic chlorine emission inventory was compiled for the year 1990 with a coarse resolution of 1 degree. In this study, we developed an up-to-date anthropogenic inventory of hydrogen chloride (HCl) and fine particulate chloride (Cl-) emissions in China for the year 2014, including coal burning, industrial processes, biomass burning and waste burning. Bottom-up and top-down methodologies were combined. Detailed local data (e.g. Cl content in coal, control technologies, etc.) were collected and applied. In order to improve the spatial resolution of emissions, detailed point source information were collected for coal-fired power plants, cement factories, iron & steel factories and waste incineration factories. Uncertainties of this emission inventory and their major causes were analyzed using the Monte Carlo method. This work enables better quantification of the ClNO2 production and impact over China.

  10. Temperature modifies the health effects of particulate matter in Brisbane, Australia

    Science.gov (United States)

    Ren, Cizao; Tong, Shilu

    2006-11-01

    A few epidemiological studies have examined whether there was an interactive effect between temperature and ambient particulate matter on cardiorespiratory morbidity and mortality, but the results were inconsistent. The present study used three time-series approaches to explore whether maximum temperature modified the impact of ambient particulate matter less than 10 μm in diameter (PM10) on daily respiratory hospital admissions, cardiovascular hospital admissions, respiratory emergency visits, cardiovascular emergency visits, non-external cause mortality and cardiovascular mortality in Brisbane between 1996 and 2001. The analytical approaches included a bivariate response surface model, a non-stratification parametric model and a stratification parametric model. Results show that there existed a statistically significant interaction between PM10 and temperature on most health outcomes at various lags. PM10 exhibited more adverse health effects on warm days than cold days. The choice of the degree of freedom for smoothers to adjust for confounders and the selection of arbitrary cut-offs for temperature affected the interaction estimates to a certain extent, but did not change the overall conclusion. The results imply that it is important to control and reduce the emission of air particles in Brisbane, particularly when temperature increases.

  11. In-line digital holographic sensor for monitoring and characterizing marine particulates

    International Nuclear Information System (INIS)

    Owen, Robert B.; Zozulya, Alex A.

    2000-01-01

    We report an in-line digital holographic sensor (DHS) for monitoring and characterizing marine particulates. This system images individual particles over a deep depth of field (>25 cm) with a resolution of 5 μm. The DHS projects a collimated beam through the water column and onto a lensless CCD array. Some light is diffracted by particulates and forms an object beam; the undeflected remainder constitutes the reference beam. The two beams combine at the CCD array and create an in-line hologram, which is then numerically reconstructed. The DHS eliminates many problems traditionally associated with holography. The CCD recording material considerably lowers the exposure time and eliminates most vibration problems. The laser power needs are low; the DHS uses a small 10-mW diode laser. Rapid numerical reconstruction eliminates photographic processing and optical reconstruction. We successfully operated the DHS underwater on a remotely operated vehicle; our test results include tracing a single particle from one hologram to the next, thus deriving a velocity vector for marine mass transport. We outline our digital holographic reconstruction procedure, and present our graphical user interface and user software tools. The DHS is particularly useful for providing in situ ground-truth measurements for environmental remote sensing. (c) 2000 Society of Photo-Optical Instrumentation Engineers

  12. Study of particulate matter in Limeira (Brazil) using SR-TXRF

    International Nuclear Information System (INIS)

    Canteras, Felippe B.; Moreira, Silvana

    2011-01-01

    Air pollution is a growing problem mainly in metropolitan areas in the world. The atmospheric pollutants are responsible for various environmental problems including the human health. Among the pollutants, the particulate matter is important, since it has a heterogeneous composition. The goal of this work was to analyze quantitatively the particulate matter in Limeira city, Sao Paulo State, Brazil. The sampling was made using a sequential filtering system, containing two filters putted in series, to collect fine and coarse fractions. After a removal in an acid medium, with ultrasound bath, the samples were analyzed by Synchrotron Radiation Total Reflection X-Ray Fluorescence (SR-TXRF). The results obtained for PM10 were in agreement with the standards defined by the Brazilian legislation and also with the standards established by USEPA. In all analyzed samples S, K, Ca, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, Br, Rb, Sr, Ba and Pb were quantified. Employing multivariate statistical analysis (principal component and cluster analysis) was possible to identify the emission sources. For coarse fraction the main emission source was soil dusty responsible for 57% of the total in the coarse fraction, followed by vehicular emission with 30% and industrial 13%. In the fine fraction soil dusty was the mainly emission source contributing with 79% of the total, followed by vehicular emission with 13% and finally the industrial emission responsible just for 8%. (author)

  13. Characterisation of air particulate matter in Klang Valley by neutron activation analysis technique

    International Nuclear Information System (INIS)

    Mohd Suhaimi Hamzah; Shamsiah Abd Rahman; Mohd Khalid Matori; Abd Khalik Wood

    2000-01-01

    Air particulate matter is known to affect human health, impairs visibility and can cause climate change. Study on air particulate matter in term of particle size and chemical contents is very important to indicate the quality of air in a sampling area. Information on concentration of important constituents in air particles can be used to identify some of emission sources which contribute to the pollution problem. The data collected may also be, used as a basis to design a strategy in order to overcome the air pollution problem in the area. The study involved sampling of air dust at two stations, one in Bangi and the other in Kuala Lumpur using Gent Stack Sampler units. Each sampler capable of collecting air particle sizes smaller than 2.5 micron (PM 2.5) and between 2.5 - O micron on two different filters simultaneously. The filters were measured for their mass, elemental carbon and elemental concentrations using analytical equipment or techniques including reflectometer and Neutron Activation Analysis. The results of analysis on samples collected in 1997-1998 are discussed. (author)

  14. Control of fine particulate (PM2.5) emissions from restaurant operations.

    Science.gov (United States)

    Whynot, J; Quinn, G; Perryman, P; Votlucka, P

    1999-09-01

    This paper describes efforts to reduce particulate matter (PM) emissions from restaurant operations, including application of an existing control method to a new equipment type. Commercial charbroiling in the South Coast Air Basin results in emissions of approximately 10 tons/day of fine particulate matter (PM2.5) and 1.3 tons/day of volatile organic compounds (VOCs). Over a seven-year period, the South Coast Air Quality Management District worked with industry to develop test methods for measuring emissions from various cooking operations, evaluate control technologies, and develop a rule to reduce these emissions. Of the two basic types of charbroilers--chain-driven and underfired--underfired produce four times the emissions when equivalent amounts of product are cooked. Cost-effective control technology is currently available only for chain-driven charbroilers. The application of flameless catalytic oxidizers to chain-driven charbroilers was found to effectively reduce emissions by at least 83% and is cost-effective. The catalysts have been used worldwide at restaurants for several years. Research efforts are underway to identify control options for underfired charbroilers. Implementation of Rule 1138, Control of Emissions from Restaurant Operations, adopted November 14, 1997, will result in reductions of 0.5 tons/day of PM2.5 and 0.2 tons/day of VOCs. Future rules will result in reductions from underfired charbroilers and possibly other restaurant equipment when cost-effective solutions are available.

  15. Artificial neural network forecast application for fine particulate matter concentration using meteorological data

    Directory of Open Access Journals (Sweden)

    M. Memarianfard

    2017-09-01

    Full Text Available Most parts of the urban areas are faced with the problem of floating fine particulate matter. Therefore, it is crucial to estimate the amounts of fine particulate matter concentrations through the urban atmosphere. In this research, an artificial neural network technique was utilized to model the PM2.5 dispersion in Tehran City. Factors which are influencing the predicted value consist of weather-related and air pollution-related data, i.e. wind speed, humidity, temperature, SO2, CO, NO2, and PM2.5 as target values. These factors have been considered in 19 measuring stations (zones over urban area across Tehran City during four years, from March 2011 to March 2015. The results indicate that the network with hidden layer including six neurons at training epoch 113, has the best performance with the lowest error value (MSE=0.049438 on considering PM2.5 concentrations across metropolitan areas in Tehran. Furthermore, the “R” value for regression analysis of training, validation, test, and all data are 0.65898, 0.6419, 0.54027, and 0.62331, respectively. This study also represents the artificial neural networks have satisfactory implemented for resolving complex patterns in the field of air pollution.

  16. Characterization of particulate drug delivery systems for oral delivery of Peptide and protein drugs.

    Science.gov (United States)

    Christophersen, Philip Carsten; Fano, Mathias; Saaby, Lasse; Yang, Mingshi; Nielsen, Hanne Mørck; Mu, Huiling

    2015-01-01

    Oral drug delivery is a preferred route because of good patient compliance. However, most peptide/ protein drugs are delivered via parenteral routes because of the absorption barriers in the gastrointestinal (GI) tract such as enzymatic degradation by proteases and low permeability acrossthe biological membranes. To overcome these barriers, different formulation strategies for oral delivery of biomacromolecules have been proposed, including lipid based formulations and polymer-based particulate drug delivery systems (DDS). The aim of this review is to summarize the existing knowledge about oral delivery of peptide/protein drugs and to provide an overview of formulationand characterization strategies. For a better understanding of the challenges in oral delivery of peptide/protein drugs, the composition of GI fluids and the digestion processes of different kinds of excipients in the GI tract are summarized. Additionally, the paper provides an overview of recent studies on characterization of solid drug carriers for peptide/protein drugs, drug distribution in particles, drug release and stability in simulated GI fluids, as well as the absorption of peptide/protein drugs in cell-based models. The use of biorelevant media when applicable can increase the knowledge about the quality of DDS for oral protein delivery. Hopefully, the knowledge provided in this review will aid the establishment of improved biorelevant models capable of forecasting the performance of particulate DDS for oral peptide/protein delivery.

  17. Study of particulate matter in Limeira (Brazil) using SR-TXRF

    Energy Technology Data Exchange (ETDEWEB)

    Canteras, Felippe B.; Moreira, Silvana, E-mail: silvana@fec.unicamp.b [Universidade Estadual de Campinas (FEC/UNICAMP), SP (Brazil) Faculdade de Engenharia Civil, Arquitetura e Urbanismo

    2011-07-01

    Air pollution is a growing problem mainly in metropolitan areas in the world. The atmospheric pollutants are responsible for various environmental problems including the human health. Among the pollutants, the particulate matter is important, since it has a heterogeneous composition. The goal of this work was to analyze quantitatively the particulate matter in Limeira city, Sao Paulo State, Brazil. The sampling was made using a sequential filtering system, containing two filters putted in series, to collect fine and coarse fractions. After a removal in an acid medium, with ultrasound bath, the samples were analyzed by Synchrotron Radiation Total Reflection X-Ray Fluorescence (SR-TXRF). The results obtained for PM10 were in agreement with the standards defined by the Brazilian legislation and also with the standards established by USEPA. In all analyzed samples S, K, Ca, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, Br, Rb, Sr, Ba and Pb were quantified. Employing multivariate statistical analysis (principal component and cluster analysis) was possible to identify the emission sources. For coarse fraction the main emission source was soil dusty responsible for 57% of the total in the coarse fraction, followed by vehicular emission with 30% and industrial 13%. In the fine fraction soil dusty was the mainly emission source contributing with 79% of the total, followed by vehicular emission with 13% and finally the industrial emission responsible just for 8%. (author)

  18. Work place air particulate monitoring of automobile workshops for public health and safety

    International Nuclear Information System (INIS)

    Siddique, N.; Waheed, S.

    2013-01-01

    Twenty-eight pairs of coarse and fine air particulate samples were collected in front of an automotive workshop located at Tasmasipabad on Chaklala Road in Rawalpindi using a Gent sampler and polycarbonate filters. These samples were collected during the period; 7th to 27th of April 2009. The gravimetric data (PM 2.5 and PM 10 ) were obtained for these samples and were found to exceed the Pakistani standards. Black carbon (BC) was also determined using reflectance measurements and it was found that BC contributed significantly more to the fine mass than to the coarse fraction; i.e. ∼10 to ∼3 %, respectively. This is not surprising as soot is emitted by combustion processes and is usually found in the fine particulate mass. Using instrumental neutron activation analysis technique all 28 pairs of filters were analyzed for >30 elements. Major elements, in the coarse mass fraction, include Al, K, Fe, Sr, Na, and Zn implying soil as the major source while BC was found to be a higher contributor of PM 2.5 . An episode of high PM 2.5 was observed on the 18th of April 2009. Back trajectory analysis showed that the air mass originated from the Middle East where a dust storm was in progress over Iraq. (author)

  19. Long-term particulate matter exposure and mortality: a review of European epidemiological studies

    Directory of Open Access Journals (Sweden)

    Boffetta Paolo

    2009-12-01

    Full Text Available Abstract Background Several studies considered the relation between long-term exposure to particulate matter (PM and total mortality, as well as mortality from cardiovascular and respiratory diseases. Our aim was to provide a comprehensive review of European epidemiological studies on the issue. Methods We searched the Medline database for epidemiological studies on air pollution and health outcomes published between January 2002 and December 2007. We also examined the reference lists of individual papers and reviews. Two independent reviewers classified the studies according to type of air pollutant, duration of exposure and health outcome considered. Among European investigations that examined long-term PM exposure we found 4 cohort studies (considering total and cardiopulmonary mortality, 1 case-control study (considering mortality from myocardial infarction, and 4 ecologic studies (2 studies considering total and cardiopulmonary mortality and 2 studies focused on cardiovascular mortality. Results Measurement indicators of PM exposure used in European studies, including PM10, PM2.5, total suspended particulate and black smoke, were heterogeneous. This notwithstanding, in all analytic studies total mortality was directly associated with long-term exposure to PM. The excesses in mortality were mainly due to cardiovascular and respiratory causes. Three out of 4 ecologic studies found significant direct associations between PM indexes and mortality. Conclusion European studies on long-term exposure to PM indicate a direct association with mortality, particularly from cardiovascular and respiratory diseases.

  20. Source apportionment studies on particulate matter in Beijing/China

    Science.gov (United States)

    Suppan, P.; Shen, R.; Shao, L.; Schrader, S.; Schäfer, K.; Norra, S.; Vogel, B.; Cen, K.; Wang, Y.

    2013-05-01

    More than 15 million people in the greater area of Beijing are still suffering from severe air pollution levels caused by sources within the city itself but also from external impacts like severe dust storms and long range advection from the southern and central part of China. Within this context particulate matter (PM) is the major air pollutant in the greater area of Beijing (Garland et al., 2009). PM did not serve only as lead substance for air quality levels and therefore for adverse health impact effects but also for a strong influence on the climate system by changing e.g. the radiative balance. Investigations on emission reductions during the Olympic Summer Games in 2008 have caused a strong reduction on coarser particles (PM10) but not on smaller particles (PM2.5). In order to discriminate the composition of the particulate matter levels, the different behavior of coarser and smaller particles investigations on source attribution, particle characteristics and external impacts on the PM levels of the city of Beijing by measurements and modeling are performed: a) Examples of long term measurements of PM2.5 filter sampling in 2010/2011 with the objectives of detailed chemical (source attribution, carbon fraction, organic speciation and inorganic composition) and isotopic analyses as well as toxicological assessment in cooperation with several institutions (Karlsruhe Institute of Technology (IfGG/IMG), Helmholtz Zentrum München (HMGU), University Rostock (UR), Chinese University of Mining and Technology Beijing, CUMTB) will be discussed. b) The impact of dust storm events on the overall pollution level of particulate matter in the greater area of Beijing is being assessed by the online coupled comprehensive model system COSMO-ART. First results of the dust storm modeling in northern China (2011, April 30th) demonstrates very well the general behavior of the meteorological parameters temperature and humidity as well as a good agreement between modeled and

  1. Monitoring of PM10 and PM2.5 around primary particulate anthropogenic emission sources

    Science.gov (United States)

    Querol, Xavier; Alastuey, Andrés; Rodriguez, Sergio; Plana, Felicià; Mantilla, Enrique; Ruiz, Carmen R.

    Investigations on the monitoring of ambient air levels of atmospheric particulates were developed around a large source of primary anthropogenic particulate emissions: the industrial ceramic area in the province of Castelló (Eastern Spain). Although these primary particulate emissions have a coarse grain-size distribution, the atmospheric transport dominated by the breeze circulation accounts for a grain-size segregation, which results in ambient air particles occurring mainly in the 2.5-10 μm range. The chemical composition of the ceramic particulate emissions is very similar to the crustal end-member but the use of high Al, Ti and Fe as tracer elements as well as a peculiar grain-size distribution in the insoluble major phases allow us to identify the ceramic input in the bulk particulate matter. PM2.5 instead of PM10 monitoring may avoid the interference of crustal particles without a major reduction in the secondary anthropogenic load, with the exception of nitrate. However, a methodology based in PM2.5 measurement alone is not adequate for monitoring the impact of primary particulate emissions (such as ceramic emissions) on air quality, since the major ambient air particles derived from these emissions are mainly in the range of 2.5-10 μm. Consequently, in areas characterised by major secondary particulate emissions, PM2.5 monitoring should detect anthropogenic particulate pollutants without crustal particulate interference, whereas PM10 measurements should be used in areas with major primary anthropogenic particulate emissions.

  2. Application of Cyclone to Removal of Hot Particulate in Hot Cell

    International Nuclear Information System (INIS)

    Kim, Gye Nam; Lee, Sung Yeol; Won, Hui Jun; Jung, Chong Hun; Oh, Won Zin

    2005-01-01

    The size and main ingredient of hot particulate generated during the nuclide experiment in hot cells of nuclear facilities were 0.5300 μm and UO 2 . A cyclone filter equipment which consists of a cyclone and Bag/HEPA filter was devised to remove hot particulate generated during the nuclide experiment in hot cells of nuclear facilities. The experimental conditions to maximize the collection efficiency of hot particulate were suggested through experiments done with the cyclone filter equipment. With the large size of simulated particulate, the collection efficiency of the particulate was high. When the size of simulated particulate was more than 5 μm, the collection efficiency of the particulate was more than 80% and when the size of simulated particulate was less than 1.0 μm, the collection efficiency decreased by less than. If the inflow velocity of simulated particulate was increased, the collection efficiency of the particulate was also increased. When the inflow velocity of simulated particulate was more than 12 m/sec, the collection efficiency was higher than , but after 17 m/sec inflow velocity, no change observed. The collection efficiency of the simulated particulate can be enhanced with the length of vortex finder inside the chamber. With the length of vortex finder, 7.2 cm, the observed collection efficiency of the particulate was the maximum. Moreover, when the sub-cone was attached under the cyclone, the collection efficiency of cyclone increased 2%. It was found that effect by attachment of sub-cone was not serious.

  3. Continuous and semicontinuous monitoring techniques for particulate matter mass and chemical components: a synthesis of findings from EPA's Particulate Matter Supersites Program and related studies.

    Science.gov (United States)

    Solomon, Paul A; Sioutas, Constantinos

    2008-02-01

    The U.S. Environmental Protection Agency (EPA) established the Particulate Matter (PM) Supersites Program to provide key stakeholders (government and private sector) with significantly improved information needed to develop effective and efficient strategies for reducing PM on urban and regional scales. All Supersites projects developed and evaluated methods and instruments, and significant advances have been made and applied within these programs to yield new insights to our understanding of PM accumulation in air as well as improved source-receptor relationships. The tested methods include a variety of continuous and semicontinuous instruments typically with a time resolution of an hour or less. These methods often overcome many of the limitations associated with measuring atmospheric PM mass concentrations by daily filter-based methods (e.g., potential positive or negative sampling artifacts). Semicontinuous coarse and ultrafine mass measurement methods also were developed and evaluated. Other semicontinuous monitors tested measured the major components of PM such as nitrate, sulfate, ammonium, organic and elemental carbon, trace elements, and water content of the aerosol as well as methods for other physical properties of PM, such as number concentration, size distribution, and particle density. Particle mass spectrometers, although unlikely to be used in national routine monitoring networks in the foreseeable future because of their complex technical requirements and cost, are mentioned here because of the wealth of new information they provide on the size-resolved chemical composition of atmospheric particles on a near continuous basis. Particle mass spectrometers likely represent the greatest advancement in PM measurement technology during the last decade. The improvements in time resolution achieved by the reported semicontinuous methods have proven to be especially useful in characterizing ambient PM, and are becoming essential in allowing scientists to

  4. Performance of particulate containment at nanotechnology workplaces

    International Nuclear Information System (INIS)

    Lo, Li-Ming; Tsai, Candace S.-J.; Dunn, Kevin H.; Hammond, Duane; Marlow, David; Topmiller, Jennifer; Ellenbecker, Michael

    2015-01-01

    The evaluation of engineering controls for the production or use of carbon nanotubes (CNTs) was investigated at two facilities. These control assessments are necessary to evaluate the current status of control performance and to develop proper control strategies for these workplaces. The control systems evaluated in these studies included ventilated enclosures, exterior hoods, and exhaust filtration systems. Activity-based monitoring with direct-reading instruments and filter sampling for microscopy analysis were used to evaluate the effectiveness of control measures at study sites. Our study results showed that weighing CNTs inside the biological safety cabinet can have a 37 % reduction on the particle concentration in the worker’s breathing zone, and produce a 42 % lower area concentration outside the enclosure. The ventilated enclosures used to reduce fugitive emissions from the production furnaces exhibited good containment characteristics when closed, but they failed to contain emissions effectively when opened during product removal/harvesting. The exhaust filtration systems employed for exhausting these ventilated enclosures did not provide promised collection efficiencies for removing engineered nanomaterials from furnace exhaust. The exterior hoods were found to be a challenge for controlling emissions from machining nanocomposites: the downdraft hood effectively contained and removed particles released from the manual cutting process, but using the canopy hood for powered cutting of nanocomposites created 15–20 % higher ultrafine (<500 nm) particle concentrations at the source and at the worker’s breathing zone. The microscopy analysis showed that CNTs can only be found at production sources but not at the worker breathing zones during the tasks monitored

  5. Performance of particulate containment at nanotechnology workplaces

    Energy Technology Data Exchange (ETDEWEB)

    Lo, Li-Ming, E-mail: LLo@cdc.gov [National Institute for Occupational Safety and Health, Centers for Disease Control and Prevention (United States); Tsai, Candace S.-J. [Purdue University (United States); Dunn, Kevin H.; Hammond, Duane; Marlow, David; Topmiller, Jennifer [National Institute for Occupational Safety and Health, Centers for Disease Control and Prevention (United States); Ellenbecker, Michael [University of Massachusetts Lowell (United States)

    2015-11-15

    The evaluation of engineering controls for the production or use of carbon nanotubes (CNTs) was investigated at two facilities. These control assessments are necessary to evaluate the current status of control performance and to develop proper control strategies for these workplaces. The control systems evaluated in these studies included ventilated enclosures, exterior hoods, and exhaust filtration systems. Activity-based monitoring with direct-reading instruments and filter sampling for microscopy analysis were used to evaluate the effectiveness of control measures at study sites. Our study results showed that weighing CNTs inside the biological safety cabinet can have a 37 % reduction on the particle concentration in the worker’s breathing zone, and produce a 42 % lower area concentration outside the enclosure. The ventilated enclosures used to reduce fugitive emissions from the production furnaces exhibited good containment characteristics when closed, but they failed to contain emissions effectively when opened during product removal/harvesting. The exhaust filtration systems employed for exhausting these ventilated enclosures did not provide promised collection efficiencies for removing engineered nanomaterials from furnace exhaust. The exterior hoods were found to be a challenge for controlling emissions from machining nanocomposites: the downdraft hood effectively contained and removed particles released from the manual cutting process, but using the canopy hood for powered cutting of nanocomposites created 15–20 % higher ultrafine (<500 nm) particle concentrations at the source and at the worker’s breathing zone. The microscopy analysis showed that CNTs can only be found at production sources but not at the worker breathing zones during the tasks monitored.

  6. Emission factors of carbonaceous particulate matter and polycyclic aromatic hydrocarbons from residential solid fuel combustions

    Energy Technology Data Exchange (ETDEWEB)

    Shen, Guofeng [Jiangsu Academy of Environmental Science, Nanjing (China). Inst. of Atmospheric Sciences

    2014-07-01

    Emission inventory is basic for the understanding of environmental behaviors and potential effects of compounds, however, current inventories are often associated with relatively high uncertainties. One important reason is the lack of emission factors, especially for the residential solid fuel combustion in developing countries. In the present study, emission factors of a group of pollutants including particulate matter, organic carbon, elemental carbon (sometimes known as black carbon) and polycyclic aromatic hydrocarbons were measured for a variety of residential solid fuels including coal, crop straw, wood, and biomass pellets in rural China. The study provided a large number of emission factors that can be further used in emission estimation. Composition profiles and isomer ratios were investigated and compared so as to be used in source apportionment. In addition, the present study identified and quantified the influence of factors like fuel moisture, volatile matter on emission performance.

  7. Phase I aging assessment of nuclear air-treatment system high efficiency particulate air and adsorbers

    International Nuclear Information System (INIS)

    Winegardner, W.K.

    1996-01-01

    A phase I aging assessment of high efficiency particulate air filters and activated carbon gas adsorption units was performed by the Pacific Northwest Laboratory as part of the US Nuclear Regulatory Commission's Nuclear Plant Aging Research Program. Information was compiled concerning design features, failure experience, aging mechanisms, effects, and stressors, and monitoring methods. Over 1100 failures, or 12% of the filter installations, were reported as part of a US Department of energy survey. Investigators from other laboratories have suggested that aging could have contributed to over 80% of these failures. Several instances of impaired performance as the result of the premature aging of carbon were reported. Filter aging mechanisms range from those associated with particle loading to reactions that alter the properties of gaskets. Mechanisms that can lead to impaired adsorber performance include the loss of potentially available active sites as a result of the adsorption of moisture or pollutants. Stressors include heat, moisture, radiation, and airborne particles and contaminants. (orig.)

  8. Risk of human health by particulate matter as a source of air pollution--comparison with tobacco smoking.

    Science.gov (United States)

    Enomoto, Makoto; Tierney, William J; Nozaki, Kohsuke

    2008-08-01

    Increased air pollution, containing carcinogenic particulate matter smaller than 2.5 microm (PM(2.5)), has gained particular attention in recent years as a causative factor in the increased incidence of respiratory diseases, including lung cancer. Extensive carcinogenicity studies conducted recently under Good Laboratory Practice conditions by National Toxicology Program in the USA, Ramazzini Foundation in Italy or Contract Research Organizations on numerous chemical compounds have demonstrated the importance of considering dose levels, times and duration of exposure in the safety evaluation of carcinogenic as well as classical toxic agents. Data on exposure levels to chemical carcinogens that produce tumor development have contributed to the evaluation of human carcinogens from extrapolation of animal data. A popular held misconception is that the risk from smoking is the result of inhaling assorted particulate matter and by products from burning tobacco rather than the very low ng levels of carcinogens present in smoke. Consider the fact that a piece of toasted bread contains ng levels of the carcinogen urethane (ethyl carbamate). Yet, no one has considered toast to be a human carcinogen. Future human carcinogenic risk assessment should emphasize consideration of inhalation exposure to higher levels of benzo (a) pyrene and other possible carcinogens and particulate matter present in polluted air derived from automobile exhaust, pitch and coal tar on paved roads and asbestos, in addition to other environmental contaminant exposure via the food and drinking water.

  9. The effects of biodiesels on semivolatile and nonvolatile particulate matter emissions from a light-duty diesel engine.

    Science.gov (United States)

    Cheng, Yuan; Li, Shao-Meng; Liggio, John; Hayden, Katherine; Han, Yuemei; Stroud, Craig; Chan, Tak; Poitras, Marie-Josée

    2017-11-01

    Semivolatile organic compounds (SVOCs) represent a dominant category of secondary organic aerosol precursors that are increasingly included in air quality models. In the present study, an experimental system was developed and applied to a light-duty diesel engine to determine the emission factors of particulate SVOCs (pSVOCs) and nonvolatile particulate matter (PM) components at dilution ratios representative of ambient conditions. The engine was tested under three steady-state operation modes, using ultra-low-sulfur diesel (ULSD), three types of pure biodiesels and their blends with ULSD. For ULSD, the contribution of pSVOCs to total particulate organic matter (POM) mass in the engine exhaust ranged between 21 and 85%. Evaporation of pSVOCs from the diesel particles during dilution led to decreases in the hydrogen to carbon ratio of POM and the PM number emission factor of the particles. Substituting biodiesels for ULSD could increase pSVOCs emissions but brought on large reductions in black carbon (BC) emissions. Among the biodiesels tested, tallow/used cooking oil (UCO) biodiesel showed advantages over soybean and canola biodiesels in terms of both pSVOCs and nonvolatile PM emissions. It is noteworthy that PM properties, such as particle size and BC mass fraction, differed substantially between emissions from conventional diesel and biodiesels. Copyright © 2017 Elsevier Ltd. All rights reserved.

  10. Source apportionment of the particulate PAHs at Seoul, Korea: impact of long range transport to a megacity

    Directory of Open Access Journals (Sweden)

    J. Y. Lee

    2007-07-01

    Full Text Available Northeast Asia including China, Korea, and Japan is one of the world's largest fossil fuel consumption regions. Seoul, Korea, is a megacity in Northeast Asia. Its emissions of air pollutants can affect the region, and in turn it is also affected by regional emissions. To understand the extent of these influences, major sources of ambient particulate PAHs in Seoul were identified and quantified based on measurements made between August 2002 and December 2003. The chemical mass balance (CMB model was applied. Seven major emission sources were identified based on the emission data in Seoul and Northeast Asia: Gasoline and diesel vehicles, residential coal use, coke ovens, coal power plants, biomass burning, and natural gas (NG combustion. The major sources of particulate PAHs in Seoul during the whole measurement period were gasoline and diesel vehicles, together accounted for 31% of the measured particulate PAHs levels. However, the source contributions showed distinct daily and seasonal variations. High contributions of biomass burning and coal (residential and coke oven were observed in fall and winter, accounting for 63% and 82% of the total concentration of PAHs, respectively. Since these sources were not strong in and around Seoul, they are likely to be related to transport from outside of Seoul, from China and/or North Korea. This implies that the air quality in a mega-city such as Seoul can be influenced by the long range transport of air pollutants such as PAHs.

  11. Cognitive Load of Learner Control: Extraneous or Germane Load?

    Directory of Open Access Journals (Sweden)

    Mieke Vandewaetere

    2013-01-01

    Full Text Available Computer-based learning environments become more tailored when learners can exert control over one or more parts of the learning process. Learner control (LC demands additional efforts of learners because, in addition to learning, they also have to monitor that learning. As a consequence, LC may cause additional cognitive load and even cognitive overload. The central question in this study is what type of cognitive load is induced by LC and whether the experienced load is related to learning outcomes. For this study, half of the students had control over task selection, while the other half had not. Within each condition, students were assigned to a single treatment, with the primary task to solely focus on the learning content, and a dual treatment, comprising a primary task and a secondary task. The results indicate that LC did not impose higher cognitive load as measured by secondary task scores and mental effort ratings.

  12. Extraneous Information and Graph Comprehension: Implications for Effective Design Choices

    Science.gov (United States)

    Stewart, Brandie M.; Cipolla, Jessica M.; Best, Lisa A.

    2009-01-01

    Purpose: The purpose of this paper is to examine if university students could accurately extract information from graphs presented in 2D or 3D formats with different colour hue variations or solid black and white. Design/methodology/approach: Participants are presented with 2D and 3D bar and pie charts in a PowerPoint presentation and are asked to…

  13. Effects of extraneous variables on performance of choking ...

    African Journals Online (AJOL)

    Furthermore, Competitive State Anxiety ... and sport composition [F (1, 56) = 1.635, p>.05]. ... and sufficient training before competitions in different situations could help to control and managed choking effect among susceptible athletes.

  14. Bio-derived fuels may ease the regeneration of diesel particulate traps

    Energy Technology Data Exchange (ETDEWEB)

    E. Coda Zabetta; M. Hupa; S. Niemi [Aabo Akademi Process Chemistry Centre, Turku (Finland)

    2006-12-15

    Particulate is the most problematic emission from diesel engines. To comply with environmental regulations, these engines are often equipped with particulate traps, which must be regenerated frequently for the sake of efficiency. The regeneration is commonly achieved by rising the temperature in the trap till the particulate self-ignites. However, this method implies energy losses and thermal shocks in the trap. Alternatively, catalysts and additives have been recently considered for reducing the ignition temperature of particulate, but these techniques suffer from poisoning and undesirable byproducts. The present experimental study shows that the ignition temperature of particulate from seed-derived oils (SO) and from blends of SO with diesel fuel oil (DO) can be lower than that of particulate from neat DO. If substantiated by more extensive studies, such finding could have noteworthy implications on the future of fuels and traps. Short communication. 8 refs., 3 figs., 2 tabs.

  15. Octanol-solubility of dissolved and particulate trace metals in contaminated rivers: implications for metal reactivity and availability.

    Science.gov (United States)

    Turner, Andrew; Mawji, Edward

    2005-05-01

    The lipid-like, amphiphilic solvent, n-octanol, has been used to determine a hydrophobic fraction of dissolved and particulate trace metals (Al, Cd, Co, Cu, Mn, Ni, Pb, Zn) in contaminated rivers. In a sample from the River Clyde, southwest Scotland, octanol-solubility was detected for all dissolved metals except Co, with conditional octanol-water partition coefficients, D(ow), ranging from about 0.2 (Al and Cu) to 1.25 (Pb). In a sample taken from the River Mersey, northwest England, octanol-solubility was detected for dissolved Al and Pb, but only after sample aliquots had been spiked with individual ionic metal standards and equilibrated. Spiking of the River Clyde sample revealed competition among different metals for hydrophobic ligands. Metal displacement from hydrophobic complexes was generally most significant following the addition of ionic Al or Pb, although the addition of either of these metals had little effect on the octanol-solubility of the other. In both river water samples hydrophobic metals were detected on the suspended particles retained by filtration following their extraction in n-octanol. In general, particulate Cu and Zn (up to 40%) were most available, and Al, Co and Pb most resistant (octanol extraction. Distribution coefficients defining the concentration ratio of octanol-soluble particle-bound metal to octanol-soluble dissolved metal were in the range 10(3.3)-10(5.3)mlg(-1). The presence of hydrophobic dissolved and particulate metal species has implications for our understanding of the biogeochemical behaviour of metals in aquatic environments. Specifically, such species are predicted to exhibit characteristics of non-polar organic contaminants, including the potential to penetrate the lipid bilayer. Current strategies for assessing the bioavailability and toxicity of dissolved and particulate trace metals in natural waters may, therefore, require revision.

  16. Octanol-solubility of dissolved and particulate trace metals in contaminated rivers: implications for metal reactivity and availability

    International Nuclear Information System (INIS)

    Turner, Andrew; Mawji, Edward

    2005-01-01

    The lipid-like, amphiphilic solvent, n-octanol, has been used to determine a hydrophobic fraction of dissolved and particulate trace metals (Al, Cd, Co, Cu, Mn, Ni, Pb, Zn) in contaminated rivers. In a sample from the River Clyde, southwest Scotland, octanol-solubility was detected for all dissolved metals except Co, with conditional octanol-water partition coefficients, D ow , ranging from about 0.2 (Al and Cu) to 1.25 (Pb). In a sample taken from the River Mersey, northwest England, octanol-solubility was detected for dissolved Al and Pb, but only after sample aliquots had been spiked with individual ionic metal standards and equilibrated. Spiking of the River Clyde sample revealed competition among different metals for hydrophobic ligands. Metal displacement from hydrophobic complexes was generally most significant following the addition of ionic Al or Pb, although the addition of either of these metals had little effect on the octanol-solubility of the other. In both river water samples hydrophobic metals were detected on the suspended particles retained by filtration following their extraction in n-octanol. In general, particulate Cu and Zn (up to 40%) were most available, and Al, Co and Pb most resistant ( 3.3 -10 5.3 ml g -1 . The presence of hydrophobic dissolved and particulate metal species has implications for our understanding of the biogeochemical behaviour of metals in aquatic environments. Specifically, such species are predicted to exhibit characteristics of non-polar organic contaminants, including the potential to penetrate the lipid bilayer. Current strategies for assessing the bioavailability and toxicity of dissolved and particulate trace metals in natural waters may, therefore, require revision. - New approaches are presented for fractionating trace metals in natural waters

  17. Octanol-solubility of dissolved and particulate trace metals in contaminated rivers: implications for metal reactivity and availability

    Energy Technology Data Exchange (ETDEWEB)

    Turner, Andrew [School of Earth, Ocean and Environmental Sciences, University of Plymouth, Drake Circus, Plymouth PL4 8AA (United Kingdom)]. E-mail: aturner@plymouth.ac.uk; Mawji, Edward [School of Earth, Ocean and Environmental Sciences, University of Plymouth, Drake Circus, Plymouth PL4 8AA (United Kingdom)

    2005-05-01

    The lipid-like, amphiphilic solvent, n-octanol, has been used to determine a hydrophobic fraction of dissolved and particulate trace metals (Al, Cd, Co, Cu, Mn, Ni, Pb, Zn) in contaminated rivers. In a sample from the River Clyde, southwest Scotland, octanol-solubility was detected for all dissolved metals except Co, with conditional octanol-water partition coefficients, D{sub ow}, ranging from about 0.2 (Al and Cu) to 1.25 (Pb). In a sample taken from the River Mersey, northwest England, octanol-solubility was detected for dissolved Al and Pb, but only after sample aliquots had been spiked with individual ionic metal standards and equilibrated. Spiking of the River Clyde sample revealed competition among different metals for hydrophobic ligands. Metal displacement from hydrophobic complexes was generally most significant following the addition of ionic Al or Pb, although the addition of either of these metals had little effect on the octanol-solubility of the other. In both river water samples hydrophobic metals were detected on the suspended particles retained by filtration following their extraction in n-octanol. In general, particulate Cu and Zn (up to 40%) were most available, and Al, Co and Pb most resistant (<1%) to octanol extraction. Distribution coefficients defining the concentration ratio of octanol-soluble particle-bound metal to octanol-soluble dissolved metal were in the range 10{sup 3.3}-10{sup 5.3} ml g{sup -1}. The presence of hydrophobic dissolved and particulate metal species has implications for our understanding of the biogeochemical behaviour of metals in aquatic environments. Specifically, such species are predicted to exhibit characteristics of non-polar organic contaminants, including the potential to penetrate the lipid bilayer. Current strategies for assessing the bioavailability and toxicity of dissolved and particulate trace metals in natural waters may, therefore, require revision. - New approaches are presented for fractionating

  18. Human and Environmental Dangers Posed by Ongoing Global Tropospheric Aerosolized Particulates for Weather Modification.

    Science.gov (United States)

    Herndon, J Marvin

    2016-01-01

    U.S. military perception of nuclear warfare led to countless unethical nuclear experiments performed on unsuspecting individuals without their informed consent. As evidenced here, subsequent perception of weather warfare has led to exposing millions of unsuspecting individuals to toxic coal fly ash with no public disclosure, no informed consent, and no health warnings. Three methods were used: (1) comparison of eight elements analyzed in rainwater samples, thought to have leached from aerosolized coal fly ash, with corresponding coal fly ash laboratory leachate; (2) comparison of 14 elements analyzed in air filter dust with corresponding elements in coal fly ash; and (3) comparison of 23 elements analyzed in fibrous mesh found after snow melted with corresponding elements in coal fly ash. The rainwater element ratios show that the aerial particulate matter has essentially the same water-leach characteristics as coal fly ash. The air filter dust element ratios occur in the same range of compositions as coal fly ash, as do element ratios in fibrous mesh found on grass after snow melted. The fibrous mesh provides an inferred direct connection with the aerosolizing jet aircraft via coal fly ash association with the jet combustion environment. Strong evidence for the correctness of the hypothesis: coal fly ash is likely the aerosolized particulate emplaced in the troposphere for geoengineering, weather modification, and/or climate alteration purposes. The documented public health associations for ≤2.5 μm particulate pollution are also applicable to aerosolized coal fly ash. The ability of coal fly ash to release aluminum in a chemically mobile form upon exposure to water or body moisture has potentially grave human and environmental consequences over a broad spectrum, including implications for neurological diseases and biota debilitation. The ability of coal fly ash to release heavy metals and radioactive elements upon exposure to body moisture has potentially

  19. Estimating particulate matter health impact related to the combustion of different fossil fuels

    OpenAIRE

    Kuenen , Jeroen; Gschwind , Benoît; Drebszok , Kamila M.; Stetter , Daniel; Kranenburg , Richard; Hendriks , Carlijn; Lefèvre , Mireille; Blanc , Isabelle; Wyrwa , Artur; Schaap , Martijn

    2013-01-01

    International audience; Exposure to particulate matter (PM) in ambient air leads to adverse health effects. To design cost effective mitigation strategies, a thorough understanding of the sources of particulate matter is crucial. We have successfully generated a web map service that allows to access information on fuel dependent health effects due to particulate matter. For this purpose, the LOTOS-EUROS air pollution model was equipped with a source apportionment module that tracks the origin...

  20. Report Task 2.3: Particulate waste and turbidity in (marine) RAS

    OpenAIRE

    Kals, J.; Schram, E.; Brummelhuis, E.B.M.; Bakel, van, B.

    2006-01-01

    Particulate waste management and removal is one of the most problematic parts of recirculation aquaculture systems (RAS). Particulate waste and thereby turbidity originates from three major sources: fish (faeces), feed and biofilm (heterotrophic bacteria and fungi). Based on size and density there are roughly four categories of particulate waste: settable, suspended, floatable and fine or dissolved solids. Specific problems related to high turbidity are a decreasing feed intake by fish, causi...

  1. Debonding of short fibres among particulates in a metal matrix composite

    DEFF Research Database (Denmark)

    Tvergaard, Viggo

    2003-01-01

    of differently shaped fibres or particulates in each unit cell. thus representing debonding of a relatively long discontinuous fibre among particulates that do not debond. Interfacial failure is modelled in terms of a cohesive zone model that accounts for decohesion by normal separation as well as by tangential...... separation. It is found that the evolution of failure can depend rather strongly on the distribution of particulates around a fibre subject to debonding. (C) 2003 Elsevier Ltd. All rights reserved....

  2. Regions of pollution with particulate matter in Poland

    Directory of Open Access Journals (Sweden)

    Rawicki Kacper

    2018-01-01

    Full Text Available The study presents the temporal and spatial variability of particulate matter concentration in Poland in the calendar winter season (December-February. The basis for the study were the hourly and daily values of particulate matter PM10 concentration from the period 2005/06 – 2014/15, obtained from 33 air pollution monitoring stations. In Poland, the obligation to monitor the concentration of the finer fraction of particles smaller than 2.5µm in aerodynamic diameter was introduced only in 2010. Consequently, data on PM2.5 concentration refer to a shorter period, i.e. 2009/10 – 2014/15, and were obtained from 23 stations. Using the cluster analysis (k-means method, three regions of comparable variability of particulate matter concentration were delineated. The largest region, i.e. Region I, comprises the northern and eastern central area of Poland, and its southern boundary is along the line Gorzów Wlkp-Bydgoszcz-Konin-Łódź-Kielce-Lublin. Markedly smaller Region II is located to the south of Region I. By far the smallest area was designated to Region III which covers the south west area of Poland. The delineated regions show a marked variability in terms of mean concentration of both PM fractions in winter (PM10: region I - 33 µg·m-3, region II - 55 µg·m-3, region III - 83 µg·m-3; PM2,5: region I - 35 µg·m-3, region II - 50 µg·m-3, region III - 60 µg·m-3 and, in the case of PM10, the frequency of excessive daily limit value.

  3. Dynamics of particulate phosphorus in a shallow eutrophic lake

    Energy Technology Data Exchange (ETDEWEB)

    Shinohara, Ryuichiro, E-mail: r-shino@nies.go.jp [National Institute for Environmental Studies, 16-2 Onogawa, Tsukuba, Ibaraki 305-8506 (Japan); Imai, Akio; Kohzu, Ayato; Tomioka, Noriko [National Institute for Environmental Studies, 16-2 Onogawa, Tsukuba, Ibaraki 305-8506 (Japan); Furusato, Eiichi [Graduate School of Science and Engineering, Saitama University, 255 Shimo-okubo, Sakura-ku, Saitama 338-8570 (Japan); Satou, Takayuki; Sano, Tomoharu; Komatsu, Kazuhiro; Miura, Shingo; Shimotori, Koichi [National Institute for Environmental Studies, 16-2 Onogawa, Tsukuba, Ibaraki 305-8506 (Japan)

    2016-09-01

    We tested the hypothesis that in shallow, eutrophic Lake Kasumigaura, the concentration of particulate phosphorus (PP) is controlled by biogenic P (P in living or dead phytoplankton and bacterial cells), rather than by resuspension of inorganic P in sediment. Increases in wind velocity and turbidity were associated with bottom shear stress exceeding the critical value for the lake (τ{sub c} = 0.15 N m{sup −2}); this increased turbidity was due to sediment resuspension. However, concentrations of PP; HCl-extractable, reactive P in PP (P-rP); and HCl-extractable, non-reactive P in PP (P-nrP) were not correlated with wind velocity (PP vs. wind velocity: r = 0.40, p > 0.05). Rather, the P-nrP concentration accounted for approximately 79% of PP, and the concentrations of PP, P-rP, and P-nrP were correlated with the particulate organic carbon (POC) concentration (POC vs. PP: r = 0.90, p < 0.01; POC vs. P-rP: r = 0.82, p < 0.01; POC vs. P-nrP: r = 0.86, p < 0.01). In our {sup 31}P nuclear magnetic resonance spectroscopy results, mononucleotides accounted for the largest proportion among the detected P compound classes. In addition, concentrations of mononucleotides, orthophosphate, and pyrophosphate were significantly higher in samples with high POC concentrations, whereas the DNA-P concentration was not. These results suggest that biogenic P affects PP concentrations more strongly than does sediment resuspension, and the production of biogenic P creates a pool of mononucleotides, a class of easily degradable P, even in shallow, eutrophic Lake Kasumigaura. - Highlights: • Biogenic P affected the PP concentration more than did sediment resuspension. • PP correlated with particulate organic carbon concentration but not wind velocity. • Mononucleotides accounted for the largest P compound class of organic P in PP.

  4. Large scale air monitoring: Biological indicators versus air particulate matter

    International Nuclear Information System (INIS)

    Rossbach, M.; Jayasekera, R.; Kniewald, G.

    2000-01-01

    Biological indicator organisms are widely used for monitoring and banking purposes since many years. Although the complexity of the interactions between bioorganisms and their environment is generally not easily comprehensible, environmental quality assessment using the bioindicator approach offers some convincing advantages compared to direct analysis of soil, water, or air. Direct measurement of air particulates is restricted to experienced laboratories with access to expensive sampling equipment. Additionally, the amount of material collected generally is just enough for one determination per sampling and no multidimensional characterization might be possible. Further, fluctuations in air masses have a pronounced effect on the results from air filter sampling. Combining the integrating property of bioindicators with the world wide availability and uniform matrix characteristics of air particulates as a prerequisite for global monitoring of air pollution will be discussed. A new approach for sampling urban dust using large volume filtering devices installed in air conditioners of large hotel buildings is assessed. A first experiment was initiated to collect air particulates (300 to 500 g each) from a number of hotels during a period of three to four months by successive vacuum cleaning of used inlet filters from high volume air conditioning installations reflecting average concentrations per three months in different large cities. This approach is expected to be upgraded and applied for global monitoring. Highly positive correlated elements were found in lichen such as K/S, Zn/P, the rare earth elements (REE) and a significant negative correlation between Fig and Cu was observed in these samples. The ratio of concentrations of elements in dust and Usnea spp. is highest for Cr, Zn, and Fe (400-200) and lowest for elements such as Ca, Rb, and Sr (20-10). (author)

  5. Particulate Matter Concentrations in East Oakland's High Street Corridor

    Science.gov (United States)

    Lei, P.; Jackson, J.; Lewis, R.; Marigny, A.; Mitchell, J. D.; Nguyen, R.; Philips, B.; Randle, D.; Romero, D.; Spears, D.; Telles, C.; Weissman, D.

    2012-12-01

    Particulate matter (PM) is a complex mixture of small solid pieces and/or liquid droplets in the air. High concentrations of PM can pose a serious health hazard because inhalation can result in breathing problems and/or aggravate asthma. Long term exposure can increase the likelihood of respiratory problems like asthma and emphysema as well as cancer. The smaller the particles, the deeper they can get into the respiratory system. For this reason, the smallest particles, those smaller than 2.5 micrometers in diameter (PM2.5), are the most dangerous. PM2.5 is largely emitted from motor vehicles burning fuels that don't break down fully. Our research team investigated the levels of PM2.5 as well as particles smaller than 10 micrometers (PM10) and total suspended particulate (TSP) along the northeast-southwest trending High Street Corridor, near Fremont High School in East Oakland, California. Using the Aerocet 531 mass particle counter, team members walked through neighborhoods and along major roads within a 1 mile radius of Fremont High School. The Aerocet 531 recorded two minute average measurements of all the relevant PM sizes, which are reported in mg/m3. Measurements were consistently taken in the morning, between 8:30 and 11:30 am. Preliminary results indicate maximum readings of all PM sizes at sites that are in close proximity to a major freeway (Interstate-880). These results support our initial hypothesis that proximity to major roads and freeways, especially those with high diesel-fuel burning truck traffic, would be the primary factor affecting PM concentration levels. Preliminary median and maximum readings all suggest particulate matter levels below what the EPA would consider unhealthy or risky.

  6. Regions of pollution with particulate matter in Poland

    Science.gov (United States)

    Rawicki, Kacper; Czarnecka, Małgorzata; Nidzgorska-Lencewicz, Jadwiga

    2018-01-01

    The study presents the temporal and spatial variability of particulate matter concentration in Poland in the calendar winter season (December-February). The basis for the study were the hourly and daily values of particulate matter PM10 concentration from the period 2005/06 - 2014/15, obtained from 33 air pollution monitoring stations. In Poland, the obligation to monitor the concentration of the finer fraction of particles smaller than 2.5µm in aerodynamic diameter was introduced only in 2010. Consequently, data on PM2.5 concentration refer to a shorter period, i.e. 2009/10 - 2014/15, and were obtained from 23 stations. Using the cluster analysis (k-means method), three regions of comparable variability of particulate matter concentration were delineated. The largest region, i.e. Region I, comprises the northern and eastern central area of Poland, and its southern boundary is along the line Gorzów Wlkp-Bydgoszcz-Konin-Łódź-Kielce-Lublin. Markedly smaller Region II is located to the south of Region I. By far the smallest area was designated to Region III which covers the south west area of Poland. The delineated regions show a marked variability in terms of mean concentration of both PM fractions in winter (PM10: region I - 33 µg·m-3, region II - 55 µg·m-3, region III - 83 µg·m-3; PM2,5: region I - 35 µg·m-3, region II - 50 µg·m-3, region III - 60 µg·m-3) and, in the case of PM10, the frequency of excessive daily limit value.

  7. Gaseous and particulate emissions from prescribed burning in Georgia.

    Science.gov (United States)

    Lee, Sangil; Baumann, Karsten; Schauer, James J; Sheesley, Rebecca J; Naeher, Luke P; Meinardi, Simone; Blake, Donald R; Edgerton, Eric S; Russell, Armistead G; Clements, Mark

    2005-12-01

    Prescribed burning is a significant source of fine particulate matter (PM2.5) in the southeastern United States. However, limited data exist on the emission characteristics from this source. Various organic and inorganic compounds both in the gas and particle phase were measured in the emissions of prescribed burnings conducted at two pine-dominated forest areas in Georgia. The measurements of volatile organic compounds (VOCs) and PM2.5 allowed the determination of emission factors for the flaming and smoldering stages of prescribed burnings. The VOC emission factors from smoldering were distinctly higher than those from flaming except for ethene, ethyne, and organic nitrate compounds. VOC emission factors show that emissions of certain aromatic compounds and terpenes such as alpha and beta-pinenes, which are important precursors for secondary organic aerosol (SOA), are much higher from active prescribed burnings than from fireplace wood and laboratory open burning studies. Levoglucosan is the major particulate organic compound (POC) emitted for all these studies, though its emission relative to total organic carbon (mg/g OC) differs significantly. Furthermore, cholesterol, an important fingerprint for meat cooking, was observed only in our in situ study indicating a significant release from the soil and soil organisms during open burning. Source apportionment of ambient primary fine particulate OC measured at two urban receptor locations 20-25 km downwind yields 74 +/- 11% during and immediately after the burns using our new in situ profile. In comparison with the previous source profile from laboratory simulations, however, this OC contribution is on average 27 +/- 5% lower.

  8. Interactions between particulate air pollution and temperature in air pollution mortality time series studies

    International Nuclear Information System (INIS)

    Roberts, Steven

    2004-01-01

    In many community time series studies on the effect of particulate air pollution on mortality, particulate air pollution is modeled additively. In this study, we investigated the interaction between daily particulate air pollution and daily mean temperature in Cook County, Illinois and Allegheny County, Pennsylvania, using data for the period 1987-1994. This was done through the use of joint particulate air pollution-temperature response surfaces and by stratifying the effect of particulate air pollution on mortality by temperature. Evidence that the effect of particulate air pollution on mortality may depend on temperature is found. However, the results were sensitive to the number of degrees of freedom used in the confounder adjustments, the particulate air pollution exposure measure, and how the effects of temperature on mortality are modeled. The results were less sensitive to the estimation method used--generalized linear models and natural cubic splines or generalized additive models and smoothing splines. The results of this study suggest that in community particulate air pollution mortality time series studies the possibility of an interaction between daily particulate air pollution and daily mean temperature should be considered

  9. Size distribution of airbone particulates in monazite dust

    International Nuclear Information System (INIS)

    Cunha, K.M.A.D. da; Carvalho, S.M.M.; Leite, C.V.B.; Baptista, G.B.; Paschoa, A.S.

    1988-01-01

    A six-stage cascade impactor was used to collect airborne dust particulates in the grinding area of a Monazite sepation plant. The samples were analysis using particle-induced X-ray emission (PIXE) to determine the elemental concentrations, with special attention to thorium and uranium concentrations. The particle size distribution of the samples containing thorium and uranium were determined. The mass median aerodynamic diameter (MMAD) obtained was 1.15 μm for both elements. The activity median aerodynamic diameter (AMAD) was estimated based on the MMAD. The results are compared with ICRP recommendations for derived air concentrations (DAC) for thorium and uranium in restricted areas [pt

  10. New Results on the Simulation of Particulate Flows

    Energy Technology Data Exchange (ETDEWEB)

    Uhlmann, M.

    2004-07-01

    We propose a new immersed boundary method for the simulation of particulate flows. The fluid solid interaction force is formulate din a direct manner, without resorting to a feed-back mechanisms and thereby avoiding the introduction of additional free parameters. The regularized delta function of Peskin (Acta Numerica, 2002) is used to pass variables between Lagrangian and Eulerian representations, providing for a smooth variation of the hydrodynamic forces while particles are in motion relative to the fixed grid. The application of this scheme to several benchmark problems in two space dimensions demonstrates its feasibility and efficiency. (Author) 9 refs.

  11. New Results on the Simulation of Particulate Flows

    International Nuclear Information System (INIS)

    Uhlmann, M.

    2004-01-01

    We propose a new immersed boundary method for the simulation of particulate flows. The fluid solid interaction force is formulated in a direct manner, without resorting to a feed-back mechanism and thereby avoiding the introduction of additional free parameters. The regularized delta function of Pekin (Acta Numerical, 2002) is used to pass variables between Lagrangian and Eulerian representations, providing for a smooth variation of the hydrodynamic forces while particles are in motion relative to the fixed grid. The application of this schemer to several benchmark problems in two space dimensions demonstrates its feasibility and efficiency. (Author) 9 refs

  12. Ash reduction system using electrically heated particulate matter filter

    Science.gov (United States)

    Gonze, Eugene V [Pinckney, MI; Paratore, Jr., Michael J; He, Yongsheng [Sterling Heights, MI

    2011-08-16

    A control system for reducing ash comprises a temperature estimator module that estimates a temperature of an electrically heated particulate matter (PM) filter. A temperature and position estimator module estimates a position and temperature of an oxidation wave within the electrically heated PM filter. An ash reduction control module adjusts at least one of exhaust flow, fuel and oxygen levels in the electrically heated PM filter to adjust a position of the oxidation wave within the electrically heated PM filter based on the oxidation wave temperature and position.

  13. Mechanics/heat-transfer relation for particulate materials

    Energy Technology Data Exchange (ETDEWEB)

    Campbell, C.S.; Wang, D.G.; Rahman, K.

    1991-11-01

    The original goal of this study was to try and understand the relationship between the thermal and mechanical properties of particulate flows. Two situations were examined. The first is a study of the effects of simple shear flows, as a embryonic flow type on the apparent thermal conductivity and apparent viscosity of a dry granular flow. The second study involved fluidized beds. The original idea was to try and relate the heat transfer behavior of a fluidized bed to the particle pressure,'' the forces by only the particle phase of the two-phase mixture. (VC)

  14. Mechanics/heat-transfer relation for particulate materials. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Campbell, C.S.; Wang, D.G.; Rahman, K.

    1991-11-01

    The original goal of this study was to try and understand the relationship between the thermal and mechanical properties of particulate flows. Two situations were examined. The first is a study of the effects of simple shear flows, as a embryonic flow type on the apparent thermal conductivity and apparent viscosity of a dry granular flow. The second study involved fluidized beds. The original idea was to try and relate the heat transfer behavior of a fluidized bed to the ``particle pressure,`` the forces by only the particle phase of the two-phase mixture. (VC)

  15. A study to reduce DPM(Diesel Particulate Matter) emission

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Bok Youn; Kang, Chang Hee; Jo, Young Do; Lim, Sang Taek [Korea Institute of Geology Mining and Materials, Taejon (Korea, Republic of)

    1997-12-01

    This research commenced in 1994 for the purpose of providing safety and environmental measures of underground mines where the mobile diesel equipment are operating. In this last research year, research on filtering of DPM(diesel particulate matter) has been carried out. Through the research, it was known that water scrubber is only one practical way to reduce DPM emission as of now. There are several kinds of the sophisticated DPM filters, but it is not practical yet to be used in underground equipment due to the many adverse effects of the devices such as tremendous increase of SOx, NOx and back pressure etc. (author). 1 tab., 3 figs.

  16. Infiltration processing of metal matrix composites using coated ceramic particulates

    Science.gov (United States)

    Leon-Patino, Carlos Alberto

    2001-07-01

    A new process was developed to fabricate particulate metal matrix composites (MMCs). The process involves three steps: (1) modifying the particulate surface by metal coating, (2) forming a particulate porous compact; and (3) introducing metal into the channel network by vacuum infiltration. MMCs with different reinforcements, volume fractions, and sizes can be produced by this technique. Powders of alumina and silicon carbide were successfully coated with nickel and copper in preparation for infiltration with molten aluminum. Electroless Ni and Cu deposition was used since it enhances the wettability of the reinforcements for composite fabrication. While Cu deposits were polycrystalline, traces of phosphorous co-deposited from the electroless bath gave an amorphous Ni-P coating. The effect of metal coating on wetting behavior was evaluated at 800°C on plain and metal-coated ceramic plates using a sessile drop technique. The metallic films eliminated the non-wetting behavior of the uncoated ceramics, leading to equilibrium contact angles in the order of 12° and below 58° for Ni and Cu coated ceramics, respectively. The spreading data indicated that local diffusion at the triple junction was the governing mechanism of the wetting process. Precipitation of intermetallic phases in the drop/ceramic interface delayed the formation of Al4C3. Infiltration with molten Al showed that the coated-particulates are suitable as reinforcing materials for fabricating MMCs, giving porosity-free components with a homogeneously distributed reinforcing phase. The coating promoted easy metal flow through the preform, compared to the non-infiltration behavior of the uncoated counterparts. Liquid state diffusion kinetics due to temperature dependent viscosity forces controlled the infiltration process. Microstructural analysis indicated the formation of intermetallic phases such as CuAl 2, in the case of Cu coating, and Ni2Al3 and NiAl 3 when Ni-coated powders were infiltrated. The

  17. PIXE analysis of atmospheric particulate matter in glas fibre filters

    International Nuclear Information System (INIS)

    Tabacniks, M.H.; Orsini, C.Q.; Maenhaut, W.

    1993-01-01

    A 3-step extraction procedure was developed to allow particle-induced X-ray emission (PIXE) analysis of particulate matter in normal glass fibre filter samples. The detection limits, expressed in ng/m 3 of air, for the filter extracts were 5 to 30 times lower than those achieved by PIXE analysis or ordinary Nuclepore polycarbonate filter samples. The concentration results were compared with those obtained from routine atomic absorption spectrometry measurements and with the PIXE data from Nuclepore stacked filter unit samples taken in parallel. (orig.)

  18. Comparison of Particulate Mercury Measured with Manual and Automated Methods

    Directory of Open Access Journals (Sweden)

    Rachel Russo

    2011-01-01

    Full Text Available A study was conducted to compare measuring particulate mercury (HgP with the manual filter method and the automated Tekran system. Simultaneous measurements were conducted with the Tekran and Teflon filter methodologies in the marine and coastal continental atmospheres. Overall, the filter HgP values were on the average 21% higher than the Tekran HgP, and >85% of the data were outside of ±25% region surrounding the 1:1 line. In some cases the filter values were as much as 3-fold greater, with

  19. Aged riverine particulate organic carbon in four UK catchments

    International Nuclear Information System (INIS)

    Adams, Jessica L.; Tipping, Edward; Bryant, Charlotte L.; Helliwell, Rachel C.; Toberman, Hannah; Quinton, John

    2015-01-01

    The riverine transport of particulate organic matter (POM) is a significant flux in the carbon cycle, and affects macronutrients and contaminants. We used radiocarbon to characterise POM at 9 riverine sites of four UK catchments (Avon, Conwy, Dee, Ribble) over a one-year period. High-discharge samples were collected on three or four occasions at each site. Suspended particulate matter (SPM) was obtained by centrifugation, and the samples were analysed for carbon isotopes. Concentrations of SPM and SPM organic carbon (OC) contents were also determined, and were found to have a significant negative correlation. For the 7 rivers draining predominantly rural catchments, PO 14 C values, expressed as percent modern carbon absolute (pMC), varied little among samplings at each site, and there was no significant difference in the average values among the sites. The overall average PO 14 C value for the 7 sites of 91.2 pMC corresponded to an average age of 680 14 C years, but this value arises from the mixing of differently-aged components, and therefore significant amounts of organic matter older than the average value are present in the samples. Although topsoil erosion is probably the major source of the riverine POM, the average PO 14 C value is appreciably lower than topsoil values (which are typically 100 pMC). This is most likely explained by inputs of older subsoil OC from bank erosion, or the preferential loss of high- 14 C topsoil organic matter by mineralisation during riverine transport. The significantly lower average PO 14 C of samples from the River Calder (76.6 pMC), can be ascribed to components containing little or no radiocarbon, derived either from industrial sources or historical coal mining, and this effect is also seen in the River Ribble, downstream of its confluence with the Calder. At the global scale, the results significantly expand available information for PO 14 C in rivers draining catchments with low erosion rates. - Highlights:

  20. Residual stress of particulate polymer composites with reduced thermal expansion

    International Nuclear Information System (INIS)

    Nishino, T; Kotera, M; Sugiura, Y

    2009-01-01

    Thermal expansion behavior was investigated for tangusten zirconium phosphate (Zr 2 (WO 4 )(PO 4 ) 2 (ZWP)) particulate filled poly(ether ether ketone) (PEEK) composite. ZWP is known as ceramic filler with a negative thermal expansion. By incorporating ZWP with 40 volume %, the linear thermal expansion coefficient of the PEEK composite was reduced to almost same value (2.53 X 10 -5 K -1 ) with that of aluminum. This decrease was found to be quite effective for the decrease of the residual stress at the interface between aluminum plate and the composite.

  1. Aged riverine particulate organic carbon in four UK catchments

    Energy Technology Data Exchange (ETDEWEB)

    Adams, Jessica L., E-mail: jesams@ceh.ac.uk [Centre for Ecology and Hydrology, Lancaster Environment Centre, Lancaster, LA1 4AP (United Kingdom); Tipping, Edward, E-mail: et@ceh.ac.uk [Centre for Ecology and Hydrology, Lancaster Environment Centre, Lancaster, LA1 4AP (United Kingdom); Bryant, Charlotte L., E-mail: charlotte.bryant@glasgow.ac.uk [NERC Radiocarbon Facility, East Kilbride G75 0QF, Scotland (United Kingdom); Helliwell, Rachel C., E-mail: rachel.helliwell@hutton.ac.uk [The James Hutton Institute, Craigiebuckler, Aberdeen AB15 8QH Scotland (United Kingdom); Toberman, Hannah, E-mail: hannahtoberman@hotmail.com [Centre for Ecology and Hydrology, Lancaster Environment Centre, Lancaster, LA1 4AP (United Kingdom); School of Environmental Sciences, University of Liverpool, Liverpool L69 3GP (United Kingdom); Quinton, John, E-mail: j.quinton@lancaster.ac.uk [Lancaster Environment Centre, Lancaster University, Lancaster LA1 4YQ (United Kingdom)

    2015-12-01

    The riverine transport of particulate organic matter (POM) is a significant flux in the carbon cycle, and affects macronutrients and contaminants. We used radiocarbon to characterise POM at 9 riverine sites of four UK catchments (Avon, Conwy, Dee, Ribble) over a one-year period. High-discharge samples were collected on three or four occasions at each site. Suspended particulate matter (SPM) was obtained by centrifugation, and the samples were analysed for carbon isotopes. Concentrations of SPM and SPM organic carbon (OC) contents were also determined, and were found to have a significant negative correlation. For the 7 rivers draining predominantly rural catchments, PO{sup 14}C values, expressed as percent modern carbon absolute (pMC), varied little among samplings at each site, and there was no significant difference in the average values among the sites. The overall average PO{sup 14}C value for the 7 sites of 91.2 pMC corresponded to an average age of 680 {sup 14}C years, but this value arises from the mixing of differently-aged components, and therefore significant amounts of organic matter older than the average value are present in the samples. Although topsoil erosion is probably the major source of the riverine POM, the average PO{sup 14}C value is appreciably lower than topsoil values (which are typically 100 pMC). This is most likely explained by inputs of older subsoil OC from bank erosion, or the preferential loss of high-{sup 14}C topsoil organic matter by mineralisation during riverine transport. The significantly lower average PO{sup 14}C of samples from the River Calder (76.6 pMC), can be ascribed to components containing little or no radiocarbon, derived either from industrial sources or historical coal mining, and this effect is also seen in the River Ribble, downstream of its confluence with the Calder. At the global scale, the results significantly expand available information for PO{sup 14}C in rivers draining catchments with low erosion rates

  2. Surface water, particulate matter, and sediments of inland waters

    International Nuclear Information System (INIS)

    Mundschenk, H.

    1985-01-01

    The Bundesanstalt fuer Gewaesserkunde (BfG) since 1958 runs a system for monitoring the surface water and sediments of Federal German waterways in its capacity as a directing water monitoring centre. The data recorded over the years show that the radioactivity released by the various emission sources leads to radionuclide concentrations in water, particulate matter, or sediments that generally are below the detection limits defined in the relevant legal provisions governing monitoring and surveillance of nuclear facilities effluents. Representative examples of measuring methods and results (as for e.g. for H-3) are given. (DG) [de

  3. Particulate organic nitrates: Sampling and night/day variation

    DEFF Research Database (Denmark)

    Nielsen, T.; Platz, J.; Granby, K.

    1998-01-01

    Atmospheric day and night concentrations of particulate organic nitrates (PON) and several other air pollutants were measured in the summer 1995 over an open-land area in Denmark. The sampling of PON was evaluated comparing 24 h samples with two sets of 12 h samples. These results indicate...... that the observed low contribution of PON to NO, is real and not the result of an extensive loss during the sampling. Empirical relationships between the vapour pressure and chemical formula of organic compounds were established in order to evaluate the gas/particle distribution of organic nitrates. A positive...

  4. The filtering effect of buildings on airborne particulate matter

    International Nuclear Information System (INIS)

    Christensen, G.C.; Mustonen, R.

    1987-06-01

    Within the radioecological programme of the Nordic Liaison Committee for Atomic Energy (NKA), the possible consequences of a major reactor accident are one of its main research branches. This study of the filtering effect of buildings on airborne particulate matter has been one part of this branch. The absorbed dose to a person from a passing radioactive cloud will be lower if he has been indoors and not ourdoors during the cloud passage. The aim of this study has been to find filtering factors for typical Finnish and Norwegian houses to use in model work

  5. Characterization of coarse particulate matter in school gyms.

    Science.gov (United States)

    Braniš, Martin; Šafránek, Jiří

    2011-05-01

    We investigated the mass concentration, mineral composition and morphology of particles resuspended by children during scheduled physical education in urban, suburban and rural elementary school gyms in Prague (Czech Republic). Cascade impactors were deployed to sample the particulate matter. Two fractions of coarse particulate matter (PM(10-2.5) and PM(2.5-1.0)) were characterized by gravimetry, energy dispersive X-ray spectrometry and scanning electron microscopy. Two indicators of human activity, the number of exercising children and the number of physical education hours, were also recorded. Lower mass concentrations of coarse particulate matter were recorded outdoors (average PM(10-2.5) 4.1-7.4 μg m(-3) and PM(2.5-1.0) 2.0-3.3 μg m(-3)) than indoors (average PM(10-2.5) 13.6-26.7 μg m(-3) and PM(2.5-1.0) 3.7-7.4 μg m(-3)). The indoor concentrations of coarse aerosol were elevated during days with scheduled physical education with an average indoor-outdoor (I/O) ratio of 2.5-16.3 for the PM(10-2.5) and 1.4-4.8 for the PM(2.5-1.0) values. Under extreme conditions, the I/O ratios reached 180 (PM(10-2.5)) and 19.1 (PM(2.5-1.0)). The multiple regression analysis based on the number of students and outdoor coarse PM as independent variables showed that the main predictor of the indoor coarse PM concentrations is the number of students in the gym. The effect of outdoor coarse PM was weak and inconsistent. The regression models for the three schools explained 60-70% of the particular dataset variability. X-ray spectrometry revealed 6 main groups of minerals contributing to resuspended indoor dust. The most abundant particles were those of crustal origin composed of Si, Al, O and Ca. Scanning electron microscopy showed that, in addition to numerous inorganic particles, various types of fibers and particularly skin scales make up the main part of the resuspended dust in the gyms. In conclusion, school gyms were found to be indoor microenvironments with high

  6. A Li-particulate blanket concept for ITER

    International Nuclear Information System (INIS)

    Wong, C.P.C.; Cheng, E.T.; Creedon, R.L.

    1989-01-01

    The Li-particulate blanket design concept the authors proposed for the International Thermonuclear Experimental Reactor (ITER) uses a dilute suspension of fine solid breeder particles in a carrier gas as the combined coolant and lithium breeder stream. This blanket concept has a simple mechanical and hydraulic configuration, low inventory of bred tritium, and simple tritium extraction system. Existing technology can be used to implement the design for ITER. The concept has the potential to be a highly reliable shield and blanket design for ITER with relatively low development and capital costs

  7. Silkworm cocoons inspire models for random fiber and particulate composites

    Energy Technology Data Exchange (ETDEWEB)

    Fujia, Chen; Porter, David; Vollrath, Fritz [Department of Zoology, University of Oxford, Oxford OX1 3PS (United Kingdom)

    2010-10-15

    The bioengineering design principles evolved in silkworm cocoons make them ideal natural prototypes and models for structural composites. Cocoons depend for their stiffness and strength on the connectivity of bonding between their constituent materials of silk fibers and sericin binder. Strain-activated mechanisms for loss of bonding connectivity in cocoons can be translated directly into a surprisingly simple yet universal set of physically realistic as well as predictive quantitative structure-property relations for a wide range of technologically important fiber and particulate composite materials.

  8. Monitoring diesel particulate matter and calculating diesel particulate densities using Grimm model 1.109 real-time aerosol monitors in underground mines.

    Science.gov (United States)

    Kimbal, Kyle C; Pahler, Leon; Larson, Rodney; VanDerslice, Jim

    2012-01-01

    Currently, there is no Mine Safety and Health Administration (MSHA)-approved sampling method that provides real-time results for ambient concentrations of diesel particulates. This study investigated whether a commercially available aerosol spectrometer, the Grimm Portable Aerosol Spectrometer Model 1.109, could be used during underground mine operations to provide accurate real-time diesel particulate data relative to MSHA-approved cassette-based sampling methods. A subset was to estimate size-specific diesel particle densities to potentially improve the diesel particulate concentration estimates using the aerosol monitor. Concurrent sampling was conducted during underground metal mine operations using six duplicate diesel particulate cassettes, according to the MSHA-approved method, and two identical Grimm Model 1.109 instruments. Linear regression was used to develop adjustment factors relating the Grimm results to the average of the cassette results. Statistical models using the Grimm data produced predicted diesel particulate concentrations that highly correlated with the time-weighted average cassette results (R(2) = 0.86, 0.88). Size-specific diesel particulate densities were not constant over the range of particle diameters observed. The variance of the calculated diesel particulate densities by particle diameter size supports the current understanding that diesel emissions are a mixture of particulate aerosols and a complex host of gases and vapors not limited to elemental and organic carbon. Finally, diesel particulate concentrations measured by the Grimm Model 1.109 can be adjusted to provide sufficiently accurate real-time air monitoring data for an underground mining environment.

  9. Fine particulate matter in the indoor air of barbeque restaurants: Elemental compositions, sources and health risks

    International Nuclear Information System (INIS)

    Taner, Simge; Pekey, Beyhan; Pekey, Hakan

    2013-01-01

    Cooking is a significant source of indoor particulate matter that can cause adverse health effects. In this study, a 5-stage cascade impactor was used to collect particulate matter from 14 restaurants that cooked with charcoal in Kocaeli, the second largest city in Turkey. A total of 24 elements were quantified using ICP-MS. All of the element contents except for Mn were higher for fine particles (PM 2.5 ) than coarse particles (PM >2.5 ), and the major trace elements identified in the PM 2.5 included V, Se, Zn, Cr, As, Cu, Ni, and Pb. Principle component analysis (PCA) and enrichment factor (EF) calculations were used to determine the sources of PM 2.5 . Four factors that explained over 77% of the total variance were identified by the PCA. These factors included charcoal combustion, indoor activities, crustal components, and road dust. The Se, As, Cd, and V contents in the PM 2.5 were highly enriched (EF > 100). The health risks posed by the individual metals were calculated to assess the potential health risks associated with inhaling the fine particles released during charcoal cooking. The total hazard quotient (total HQ) for a PM 2.5 of 4.09 was four times greater than the acceptable limit (i.e., 1.0). In addition, the excess lifetime cancer risk (total ELCR) for PM 2.5 was 1.57 × 10 −4 , which is higher than the acceptable limit of 1.0 × 10 −6 . Among all of the carcinogenic elements present in the PM 2.5 , the cancer risks resulting from Cr(VI) and As exposure were the highest (i.e., 1.16 × 10 −4 and 3.89 × 10 −5 , respectively). Overall, these results indicate that the lifetime cancer risk associated with As and Cr(VI) exposure is significant at selected restaurants, which is of concern for restaurant workers. - Highlights: • Particulate emissions from charcoal combustion in the BBQ restaurants were studied. • Vanadium, Se, Zn, Cr and As were found as high concentrations in PM 2.5 . • Charcoal combustion and indoor activities were the

  10. Biomass Burning: The Cycling of Gases and Particulates from the Biosphere to the Atmosphere

    Science.gov (United States)

    Levine, J. S.

    2003-12-01

    Biomass burning is both a process of geochemical cycling of gases and particulates from the biosphere to the atmosphere and a process of global change. In the preface to the book, One Earth, One Future: Our Changing Global Environment (National Academy of Sciences, 1990), Dr. Frank Press, the President of the National Academy of Sciences, writes: "Human activities are transforming the global environment, and these global changes have many faces: ozone depletion, tropical deforestation, acid deposition, and increased atmospheric concentrations of gases that trap heat and may warm the global climate."It is interesting to note that all four global change "faces" identified by Dr. Press have a common thread - they are all caused by biomass burning.Biomass burning or vegetation burning is the burning of living and dead vegetation and includes human-initiated burning and natural lightning-induced burning. The bulk of the world's biomass burning occurs in the tropics - in the tropical forests of South America and Southeast Asia and in the savannasof Africa and South America. The majority of the biomass burning, primarily in the tropics (perhaps as much as 90%), is believed to be human initiated for land clearing and land-use change. Natural fires triggered by atmospheric lightning only accounts for ˜10% of all fires (Andreae, 1991). As will be discussed, a significant amount of biomass burning occurs in the boreal forests of Russia, Canada, and Alaska.Biomass burning is a significant source of gases and particulates to the regional and global atmosphere (Crutzen et al., 1979; Seiler and Crutzen, 1980; Crutzen and Andreae, 1990; Levine et al., 1995). Its burning is truly a multidiscipline subject, encompassing the following areas: fire ecology, fire measurements, fire modeling, fire combustion, remote sensing, fire combustion gaseous and particulate emissions, the atmospheric transport of these emissions, and the chemical and climatic impacts of these emissions. Recently

  11. Fine particulate matter in the indoor air of barbeque restaurants: Elemental compositions, sources and health risks

    Energy Technology Data Exchange (ETDEWEB)

    Taner, Simge; Pekey, Beyhan, E-mail: bpekey@kocaeli.edu.tr; Pekey, Hakan

    2013-06-01

    Cooking is a significant source of indoor particulate matter that can cause adverse health effects. In this study, a 5-stage cascade impactor was used to collect particulate matter from 14 restaurants that cooked with charcoal in Kocaeli, the second largest city in Turkey. A total of 24 elements were quantified using ICP-MS. All of the element contents except for Mn were higher for fine particles (PM{sub 2.5}) than coarse particles (PM{sub >2.5}), and the major trace elements identified in the PM{sub 2.5} included V, Se, Zn, Cr, As, Cu, Ni, and Pb. Principle component analysis (PCA) and enrichment factor (EF) calculations were used to determine the sources of PM{sub 2.5}. Four factors that explained over 77% of the total variance were identified by the PCA. These factors included charcoal combustion, indoor activities, crustal components, and road dust. The Se, As, Cd, and V contents in the PM{sub 2.5} were highly enriched (EF > 100). The health risks posed by the individual metals were calculated to assess the potential health risks associated with inhaling the fine particles released during charcoal cooking. The total hazard quotient (total HQ) for a PM{sub 2.5} of 4.09 was four times greater than the acceptable limit (i.e., 1.0). In addition, the excess lifetime cancer risk (total ELCR) for PM{sub 2.5} was 1.57 × 10{sup −4}, which is higher than the acceptable limit of 1.0 × 10{sup −6}. Among all of the carcinogenic elements present in the PM{sub 2.5}, the cancer risks resulting from Cr(VI) and As exposure were the highest (i.e., 1.16 × 10{sup −4} and 3.89 × 10{sup −5}, respectively). Overall, these results indicate that the lifetime cancer risk associated with As and Cr(VI) exposure is significant at selected restaurants, which is of concern for restaurant workers. - Highlights: • Particulate emissions from charcoal combustion in the BBQ restaurants were studied. • Vanadium, Se, Zn, Cr and As were found as high concentrations in PM{sub 2.5}.

  12. Radiation dose estimates due to air particulate emissions from selected phosphate industry operations

    International Nuclear Information System (INIS)

    Partridge, J.E.; Horton, T.R.; Sensintaffar, E.L.; Boysen, G.A.

    1978-06-01

    The EPA Office of Radiation Programs has conducted a series of studies to determine the radiological impact of the phosphate mining and milling industry. This report describes the efforts to estimate the radiation doses due to airborne emissions of particulates from selected phosphate milling operations in Florida. Two wet process phosphoric acid plants and one ore drying facility were selected for this study. The 1976 Annual Operations/Emissions Report, submitted by each facility to the Florida Department of Environmental Regulation, and a field survey trip by EPA personnel to each facility were used to develop data for dose calculations. The field survey trip included sampling for stack emissions and ambient air samples collected in the general vicinity of each plant. Population and individual radiation dose estimates are made based on these sources of data

  13. Microphysical Characteristics of Atmospheric Particulate Matter from NASA’s MODIS, MISR, and AERONET Observations

    International Nuclear Information System (INIS)

    Gad, N; Ibrahim, Alaa; Shokr, M

    2017-01-01

    We present a comparative study of atmospheric particulate matter (also known as aerosols) observed by satellite remote sensing and ground-based observations. We compare satellite measurements obtained by NASA’s Moderate Resolution Imaging Spectro-Radiometer (MODIS) and Multi-angle Imaging Spectro-Radiometer (MISR) instruments against the ground-based aerosol sun-photometer data from the Aerosol Robotic Network (AERONET) station in Cairo, Egypt from 2003 to 2014 to build a long-term database for climatological studies and to improve upon the accuracy and coverage achievable from the satellite data. We deduce microphysical and geometrical properties about the dominant aerosols based on key optical properties including aerosol optical depth (AOD), single scattering albedo (SSA), and Ångström exponent (AE). This has allowed us to place important constraints on the type of aerosols (natural, anthropogenic, and biogenic). (paper)

  14. Proceedings: Joint DOE/NSF Workshop on flow of particulates and fluids

    Energy Technology Data Exchange (ETDEWEB)

    1993-12-31

    These proceedings are the result of the Fifth DOR-NSF Workshop on fundamental research in the area of particulate two-phase flow and granular flow. The present collection of twenty contributions from universities and national laboratories is based on research projects sponsored by either the Department of Energy or the National Science Foundation. These papers illustrate some of the latest advances in theory, simulations, and experiments. The papers from the Workshop held September 29--October 1, 1993 have been separated into three basic areas: experiments, theory, and numerical simulations. A list of attendees at the workshop is included at the end of the proceedings. Selected papers have been indexed separately for inclusion in the Energy Science and Technology Database.

  15. Trace element composition of airborne particulate matter in urban and rural areas of Bangladesh

    International Nuclear Information System (INIS)

    Khaliquzzaman, M.; Biswas, S. K.; Tarafdar, S.A.; Isalam, A.; Khan, A.H.

    1995-11-01

    Size fractionated aerosol samples were collected at an urban site (Dhaka) in Bangladesh for a period of 17 months and at a rural site for six months. The samples were collected using a 'Gent' stacked filter unit in two fractions of 0-2 μm and 2-10 μm sizes. Proton induced x-ray emission (PIXE) spectroscopy has been used to determine the concentrations of 18 elements in the range of ng/m 3 . The elements range from Si to Sr and include Pb. The results of analysis of 292 air particulate samples of course and fine types from the urban site are presented. The results are discussed in the context of air pollution specially that of Pb. 6 refs., 7 tables., 2 figs

  16. Measurement and instrumentation techniques for monitoring plutonium and uranium particulates released from nuclear facilities

    International Nuclear Information System (INIS)

    Nero, A.V. Jr.

    1976-08-01

    The purpose of this work has been an analysis and evaluation of the state-of-the-art of measurement and instrumentation techniques for monitoring plutonium and uranium particulates released from nuclear facilities. The occurrence of plutonium and uranium in the nuclear fuel cycle, the corresponding potential for releases, associated radiological protection standards and monitoring objectives are discussed. Techniques for monitoring via decay radiation from plutonium and uranium isotopes are presented in detail, emphasizing air monitoring, but also including soil sampling and survey methods. Additionally, activation and mass measurement techniques are discussed. The availability and prevalence of these various techniques are summarized. Finally, possible improvements in monitoring capabilities due to alterations in instrumentation, data analysis, or programs are presented

  17. Cooling of particulate debris beds: analysis of the initial D-series experiments

    International Nuclear Information System (INIS)

    Rivard, J.B.

    1978-01-01

    In an effort to provide basic data on the cooling of fast reactor debris, three in-pile experiments employing oxide fuel particulate in liquid sodium were completed in late 1977. Preliminary results from these experiments were reported shortly after their completion at the Third Post-Accident Heat Removal Information Exchange, at Argonne National Laboratory. In these experiments, a distribution of 100 μm to 1000 μm-sized particles of enriched UO 2 was fission-heated to simulate decay-heated debris. In each experiment, the UO 2 particles were contained in a closed, flat-bottomed vessel 012 mm in diameter which was insulated on the diameter and bottom. Sufficient sodium was included to saturate the bed of particles and to provide a volume of bulk sodium above the bed at a controlled temperature. Parameters of interest in the experiments are given

  18. Surface roughness prediction of particulate composites using artificial neural networks in turning operation

    Directory of Open Access Journals (Sweden)

    Mohammad Ramezani

    2015-07-01

    Full Text Available A number of factors, e.g. cutting speed and feed rate, affect the surface roughness in machining process. In this paper, an Artificial Neural Network model was used to forecast surface roughness with related inputs, including cutting speed and feed rate. The output of the ANN model input parameters related to the machined surface roughness parameters. In this research, twelve samples of experimental data were used to train the network. Moreover, four other experimental tests were implemented to test the network. The study concludes that ANN was a reliable and accurate method for predicting machining parameters in CNC turning operation of Particulate Reinforced Aluminum Matrix Composites (PAMCs specimens with 0%, 5%, 10% and 15% filler. The aim of this work is to decrease the production cost and consequently increase the production rate of these materials for industry without any trial and error method procedure.

  19. Can particulate organic matter reveal emerging changes in soil organic carbon?

    DEFF Research Database (Denmark)

    Simonsson, Magnus; Kirchmann, Holger; Magid, Jakob

    2014-01-01

    different cropping systems, N fertilizer applications, and organic amendments, we found that C and N in the fine to medium sand fraction (0.063-0.600 mm, "Fraction B") showed considerably larger relative errors according to ANOVA (RMSE was 11-20% of the mean), slightly lower values of the F statistic......This study assessed whether particulate organic matter (POM) in sand fractions, isolated by wet sieving after treatment with Na hexametaphosphate, can be a sensitive indicator of incipient changes in the content and composition of soil organic matter. In five long-term field experiments including......, and slightly less contrast between treatments than total organic C and N (RMSE 3-9% of the mean). Imprecision in laboratory procedures only explained part of the increase in RMSE for C and N in Fraction B compared with total C and N; within-field spatial variability most likely had a greater influence...

  20. Bayesian spatio-temporal modeling of particulate matter concentrations in Peninsular Malaysia

    Science.gov (United States)

    Manga, Edna; Awang, Norhashidah

    2016-06-01

    This article presents an application of a Bayesian spatio-temporal Gaussian process (GP) model on particulate matter concentrations from Peninsular Malaysia. We analyze daily PM10 concentration levels from 35 monitoring sites in June and July 2011. The spatiotemporal model set in a Bayesian hierarchical framework allows for inclusion of informative covariates, meteorological variables and spatiotemporal interactions. Posterior density estimates of the model parameters are obtained by Markov chain Monte Carlo methods. Preliminary data analysis indicate information on PM10 levels at sites classified as industrial locations could explain part of the space time variations. We include the site-type indicator in our modeling efforts. Results of the parameter estimates for the fitted GP model show significant spatio-temporal structure and positive effect of the location-type explanatory variable. We also compute some validation criteria for the out of sample sites that show the adequacy of the model for predicting PM10 at unmonitored sites.

  1. New Leakage Current Particulate Matter Sensor for On-Board Diagnostics

    Directory of Open Access Journals (Sweden)

    Jiawei Wang

    2016-01-01

    Full Text Available Structure and principle of the new leakage current particulate matter (PM sensor are introduced and further study is performed on the PM sensor with the combination of numerical simulation and bench test. High voltage electrode, conductive shell, and heaters are all built-in. Based on the principle of Venturi tube and maze structure design, this sensor can detect transient PM concentrations. Internal flow field of the sensor and distribution condition of PM inside the sensor are analyzed through gas-solid two-phase flow numerical simulation. The experiment was also carried out on the whole sensor system (including mechanical and electronic circuit part and the output signals were analyzed. The results of simulation and experiment reveal the possibility of PM concentration (mass detection by the sensor.

  2. Control of polysilicon on-film particulates with on-product measurements

    Science.gov (United States)

    Barker, Judith B.; Chain, Elizabeth E.; Plachecki, Vincent E.

    1997-08-01

    Historically, a number of in-line particle measurements have been performed on separate test wafers included with product wafers during polysilicon processes. By performing film thickness and particulate measurements directly on product wafers, instead, a number of benefits accrue: (1) reduced test wafer usage, (2) reduced test wafer storage requirements, (3) reduced need for equipment to reclaim test wafers, (4) reduced need for direct labor to reclaim test wafers, and (5) reduced engineering 'false alarms' due to incorrectly processed test wafers. Implementation of on-product measurements for the polysilicon diffusion process required a number of changes in both philosophy and methodology. We show the necessary steps to implementation of on-product particle measurements with concern for overall manufacturing efficiency and the need to maintain appropriate control. Particle results from the Tencor 7600 Surfscan are presented.

  3. Arsenic in solution, colloidal and particulate phases of East-Hainan estuaries

    Science.gov (United States)

    Balzer, Wolfgang; Boehler, Esther; Tang, Xiaoliang; Ren, Jingling; Zhang, Jing; Wang, Daoru

    2013-04-01

    During two nominal dry seasons (December 2006, March 2009) and two wet seasons (July 2007, July/August 2008) the estuarine distribution and size speciation of arsenic was studied in the Wanquan river and the Wenchang/Wenjiao river estuaries, located in tropical East-Hainan (China). Arsenic in solution and in colloidal fractions was analyzed by anodic stripping voltammetry after oxidative UV digestion thereby including inorganic As(III) and As(V) as well as organic As forms. Particulate As was determined by high-resolution ICP-MS after a microwave assisted total decomposition protocol. Taking the two relatively similar estuaries and the two expeditions for each season together, the average concentrations of total dissolved As (aquaculture ponds and piles of excavated soil. The separation of colloidal fractions revealed that on average 82% of td-As remains in solution (aquaculture ponds, the two estuaries might be considered uncontaminated with respect to As.

  4. Characterization of particulate drug delivery systems for oral delivery of Peptide and protein drugs

    DEFF Research Database (Denmark)

    Christophersen, Philip Carsten; Fano, Mathias; Saaby, Lasse

    2015-01-01

    Oral drug delivery is a preferred route because of good patient compliance. However, most peptide/ protein drugs are delivered via parenteral routes because of the absorption barriers in the gastrointestinal (GI) tract such as enzymatic degradation by proteases and low permeability acrossthe...... delivery of peptide/protein drugs and to provide an overview of formulationand characterization strategies. For a better understanding of the challenges in oral delivery of peptide/protein drugs, the composition of GI fluids and the digestion processes of different kinds of excipients in the GI tract...... biological membranes. To overcome these barriers, different formulation strategies for oral delivery of biomacromolecules have been proposed, including lipid based formulations and polymer-based particulate drug delivery systems (DDS). The aim of this review is to summarize the existing knowledge about oral...

  5. Distribution in rat tissues of modulator-binding protein of particulate nature

    International Nuclear Information System (INIS)

    Sobue, K.; Muramoto, Y.; Kakiuchi, S.; Yamazaki, R.

    1979-01-01

    Studies on Ca 2+ -activatable cyclic nucleotide phosphodiesterase led to the discovery of a protein modulator that is required for the activation of this enzyme by Ca 2+ . Later, this protein has been shown to cause the Ca 2+ -dependent activation of several enzymes that include phosphodiesterase, adenylate cyclase, a protein kinase from muscles, phosphorylase b kinase, actomyosin ATPase, membranous ATPase from erythrocytes and nerve synapses. Thus, modulator protein appears to be an intracellular mediator of actions of Ca 2+ . The present work shows the distribution of this particulate modulator-binding component in rat tissues. This paper also describes the labeling of modulator protein with tritium without deteriorating its biological activities and application of this 3 H-modulator protein to the determination of the Ca ++ dependent binding of modulator protein with membranous protein. This technique proves to be useful in studying enzymes or proteins whose functions are regulated by Ca ++ /modulator protein system. (Auth.)

  6. Miniaturized inertial impactor for personal airborne particulate monitoring: Prototyping

    Science.gov (United States)

    Pasini, Silvia; Bianchi, Elena; Dubini, Gabriele; Cortelezzi, Luca

    2017-11-01

    Computational fluid dynamic (CFD) simulations allowed us to conceive and design a miniaturized inertial impactor able to collect fine airborne particulate matter (PM10, PM2.5 and PM1). We created, by 3D printing, a prototype of the impactor. We first performed a set of experiments by applying a suction pump to the outlets and sampling the airborne particulate of our laboratory. The analysis of the slide showed a collection of a large number of particles, spanning a wide range of sizes, organized in a narrow band located below the exit of the nozzle. In order to show that our miniaturized inertial impactor can be truly used as a personal air-quality monitor, we performed a second set of experiments where the suction needed to produce the airflow through the impactor is generated by a human being inhaling through the outlets of the prototype. To guarantee a number of particles sufficient to perform a quantitative characterization, we collected particles performing ten consecutive deep inhalations. Finally, the potentiality for realistic applications of our miniaturized inertial impactor used in combination with a miniaturized single-particle detector will be discussed. CARIPLO Fundation - project MINUTE (Grant No. 2011-2118).

  7. Microfluidic paper-based analytical device for particulate metals.

    Science.gov (United States)

    Mentele, Mallory M; Cunningham, Josephine; Koehler, Kirsten; Volckens, John; Henry, Charles S

    2012-05-15

    A microfluidic paper-based analytical device (μPAD) fabricated by wax printing was designed to assess occupational exposure to metal-containing aerosols. This method employs rapid digestion of particulate metals using microliters of acid added directly to a punch taken from an air sampling filter. Punches were then placed on a μPAD, and digested metals were transported to detection reservoirs upon addition of water. These reservoirs contained reagents for colorimetric detection of Fe, Cu, and Ni. Dried buffer components were used to set the optimal pH in each detection reservoir, while precomplexation agents were deposited in the channels between the sample and detection zones to minimize interferences from competing metals. Metal concentrations were quantified from color intensity images using a scanner in conjunction with image processing software. Reproducible, log-linear calibration curves were generated for each metal, with method detection limits ranging from 1.0 to 1.5 μg for each metal (i.e., total mass present on the μPAD). Finally, a standard incineration ash sample was aerosolized, collected on filters, and analyzed for the three metals of interest. Analysis of this collected aerosol sample using a μPAD showed good correlation with known amounts of the metals present in the sample. This technology can provide rapid assessment of particulate metal concentrations at or below current regulatory limits and at dramatically reduced cost.

  8. Collaboration in air particulate analysis through sharing of regional resources

    International Nuclear Information System (INIS)

    Santos, Flora L.

    2003-01-01

    The air pollution research program of the Philippine Nuclear Research Institute is being pursued in support of the 1999 Clean Air Act. This is being undertaken as part of the RCA/IAEA subproject, 'Air Pollution and Its Trends'. Since the PNRI research reactor (PRR-I) has been on extended shut down for the past 18 years, the PNRI depends solely on X-ray Fluorescence (XRF) spectrometry for elemental characterization of air particulate samples. NAA is a powerful and efficient tool in air particulate characterization and is used in many national programs in the region. Collaboration in air pollution studies through exchange of samples between XRF and NAA groups will widen the range of elements that could be detected by one group. In the RCA/IAEA RAS/4/020, 'Improvement of Research Reactor Operation and Utilization' sharing of research reactor facilities is encouraged. Working out of mechanisms for such sharing will be advantageous to research groups without operational research reactors. This could take the form of exchange of samples or fellowship at a regional host institution. This will allow training of technical staff from countries without research reactors, thus ensuring continuing expertise in NAA even after long periods of reactor shutdown. (author)

  9. Toward Distinguishing Woodsmoke and Diesel Exhaust in Ambient Particulate Matter

    International Nuclear Information System (INIS)

    Braun, A.; Huggins, F.; Kubatova, A.; Wirick, S.; Maricq, M.; Mun, B.; McDonald, J.; Kelly, K.; Shah, N.; Huffman, G.

    2008-01-01

    Particulate matter (PM) from biomass burning and diesel exhaust has distinct X-ray spectroscopic, carbon specific signatures, which can be employed for source apportionment. Characterization of the functional groups of a wide selection of PM samples (woodsmoke, diesel soot, urban air PM) was carried out using the soft X-ray spectroscopy capabilities at the synchrotron radiation sources in Berkeley (ALS) and Brookhaven (NSLS). The spectra reveal that diesel exhaust particulate (DEP) matter is made up from a semigraphitic solid core and soluble organic matter, predominantly with carboxylic functional groups. Woodsmoke PM has no or a less prevalent, graphitic signature, instead it contains carbon-hydroxyl groups. Using these features to apportion the carbonaceous PM in ambient samples we estimate that the relative contribution of DEP to ambient PM in an urban area such as Lexington, KY and St. Louis, MO is 7% and 13.5%, respectively. These values are comparable to dispersion modeling data from nonurban and urban areas in California, and with elemental carbon measurements in urban locations such as Boston, MA, Rochester, NY, and Washington, DC.

  10. Characterization of Urban Runoff Pollution between Dissolved and Particulate Phases

    Science.gov (United States)

    Wei, Zhang; Simin, Li; Fengbing, Tang

    2013-01-01

    To develop urban stormwater management effectively, characterization of urban runoff pollution between dissolved and particulate phases was studied by 12 rainfall events monitored for five typical urban catchments. The average event mean concentration (AEMC) of runoff pollutants in different phases was evaluated. The AEMC values of runoff pollutants in different phases from urban roads were higher than the ones from urban roofs. The proportions of total dissolved solids, total dissolved nitrogen, and total dissolved phosphorus in total ones for all the catchments were 26.19%–30.91%, 83.29%–90.51%, and 61.54–68.09%, respectively. During rainfall events, the pollutant concentration at the initial stage of rainfall was high and then sharply decreased to a low value. Affected by catchments characterization and rainfall distribution, the highest concentration of road pollutants might appear in the later period of rainfall. Strong correlations were also found among runoffs pollutants in different phases. Total suspended solid could be considered as a surrogate for particulate matters in both road and roof runoff, while dissolved chemical oxygen demand could be regarded as a surrogate for dissolved matters in roof runoff. PMID:23935444

  11. Characterization of urban runoff pollution between dissolved and particulate phases.

    Science.gov (United States)

    Wei, Zhang; Simin, Li; Fengbing, Tang

    2013-01-01

    To develop urban stormwater management effectively, characterization of urban runoff pollution between dissolved and particulate phases was studied by 12 rainfall events monitored for five typical urban catchments. The average event mean concentration (AEMC) of runoff pollutants in different phases was evaluated. The AEMC values of runoff pollutants in different phases from urban roads were higher than the ones from urban roofs. The proportions of total dissolved solids, total dissolved nitrogen, and total dissolved phosphorus in total ones for all the catchments were 26.19%-30.91%, 83.29%-90.51%, and 61.54-68.09%, respectively. During rainfall events, the pollutant concentration at the initial stage of rainfall was high and then sharply decreased to a low value. Affected by catchments characterization and rainfall distribution, the highest concentration of road pollutants might appear in the later period of rainfall. Strong correlations were also found among runoffs pollutants in different phases. Total suspended solid could be considered as a surrogate for particulate matters in both road and roof runoff, while dissolved chemical oxygen demand could be regarded as a surrogate for dissolved matters in roof runoff.

  12. Effective moduli of high volume fraction particulate composites

    International Nuclear Information System (INIS)

    Kwon, P.; Dharan, C.K.H.

    1995-01-01

    Predictions using current micromechanics theories for the effective moduli of particulate-reinforced composites tend to break down at high volume fractions of the reinforcing phase. The predictions are usually well below experimentally measured values of the Young's modulus for volume fractions exceeding about 0.6. In this paper, the concept of contiguity, which is a measure of phase continuity, is applied to Mori-Tanaka micromechanics theory. It is shown that contiguity of the second phase increases with volume fraction, leading eventually to a reversal in the roles of the inclusion and matrix. In powder metallurgy practice, it is well known that at high volume fractions, sintering and consolidation of the reinforcement make it increasingly continuous and more like the matrix phase, while the former matrix tends to become more like the inclusion phase. The concept of contiguity applied to micromechanics theory results in very good agreement between the predicted Young's modulus and experimental data on tungsten carbide particulate-reinforced cobalt

  13. Les particules et leurs symétries

    CERN Document Server

    Chanfray, Guy

    1997-01-01

    Les particules élémentaires, initialement au nombre de trois (proton, neutron, électron) se sont rapidement révélées plus nombreuses, notamment grâce aux expériences menées dans des accélérateurs de plus en plus puissants. L'interprétation théorique des données a permis de fonder une classification qui permet aujourd'hui de parler des " vrais " constituants fondamentaux : les quards et les leptons. Ce livre expose la manière dont les lois de symétrie, externes et internes, déterminent les propriétés des particules élémentaires. Il montre comment ces symétries mènent aux lois de conservation, comment le formalisme canonique de la théorie des champs permet de retrouver les diagrammes de Feynman et comment la compréhension des symétries SU(2) et SU (3)F détermine la classification des hadrons en multiples. La deuxième partie de l'ouvrage est consacrée aux grandes théories de jauge, la chromodynamique quantique et la théorie électrofaible. La QCD permet aujourd'hui de comprendre la...

  14. Multiscale Modeling of Dewetting Damage in Highly Filled Particulate Composites

    Science.gov (United States)

    Geubelle, P. H.; Inglis, H. M.; Kramer, J. D.; Patel, J. J.; Kumar, N. C.; Tan, H.

    2008-02-01

    Particle debonding or dewetting constitutes one of the key damage processes in highly filled particulate composites such as solid propellant and other energetic materials. To analyze this failure process, we have developed a multiscale finite element framework that combines, at the microscale, a nonlinear description of the binder response with a cohesive model of the damage process taking place in a representative periodic unit cell (PUC). To relate micro-scale damage to the macroscopic constitutive response of the material, we employ the mathematical theory of homogenization (MTH). After a description of the numerical scheme, we present the results of the damage response of a highly filled particulate composite subjected to a uniaxial macroscopic strain, and show the direct correlation between the complex damage processes taking place in the PUC and the nonlinear macroscopic constitutive response. We also present a detailed study of the PUC size and a comparison between the finite element MTH-based study and a micromechanics model of the dewetting process.

  15. Modifying Char Dustcake Pressure Drop Using Particulate Additives

    Energy Technology Data Exchange (ETDEWEB)

    Landham, C.; Dahlin, R.S.; Martin, R.A.; Guan, X.

    2002-09-19

    Coal gasification produces residual particles of coal char, coal ash, and sorbent that are suspended in the fuel gas stream exiting the gasifier. In most cases, these particles (referred to, hereafter, simply as char) must be removed from the stream prior to sending the gas to a turbine, fuel cell, or other downstream device. Currently, the most common approach to cleaning the gas stream at high temperature and pressure is by filtering the particulate with a porous ceramic or metal filter. However, because these dusts frequently have small size distributions, irregular morphology, and high specific surface areas, they can have very high gas flow resistance resulting in hot-gas filter system operating problems. Typical of gasification chars, the hot-gas filter dustcakes produced at the Power Systems Development Facility (PSDF) during recent coal gasification tests have had very high flow resistance (Martin et al, 2002). The filter system has been able to successfully operate, but pressure drops have been high and filter cleaning must occur very frequently. In anticipation of this problem, a study was conducted to investigate ways of reducing dustcake pressure drop. This paper will discuss the efficacy of adding low-flow-resistance particulate matter to the high-flow-resistance char dustcake to reduce dustcake pressure drop. The study had two parts: a laboratory screening study and confirming field measurements at the PSDF.

  16. Characterisation of particulate matter on airborne pollen grains

    International Nuclear Information System (INIS)

    Ribeiro, Helena; Guimarães, Fernanda; Duque, Laura; Noronha, Fernando; Abreu, Ilda

    2015-01-01

    A characterization of the physical–chemical composition of the atmospheric PM adsorbed to airborne pollen was performed. Airborne pollen was sampled using a Hirst-type volumetric spore sampler and observed using a Field Emission Electron Probe Microanalyser for PM analysis. A secondary electron image was taken of each pollen grain and EDS spectra were obtained for individually adsorbed particles. All images were analysed and the size parameters of the particles adsorbed to pollen was determined. The measured particles’ equivalent diameter varied between 0.1 and 25.8 μm, mostly in the fine fraction. The dominant particulates identified were Si-rich, Organic-rich, SO-rich, Metals & Oxides and Cl-rich. Significant daily differences were observed in the physical–chemical characteristics of particles adsorbed to the airborne pollen wall. These differences were correlated with weather parameters and atmospheric PM concentration. Airborne pollen has the ability to adsorb fine particles that may enhance its allergenicity. - Highlights: • Airborne pollen sorbs other PM found in suspension. • 84% of the particles sorbed belonged to the fine aerosol fraction. • Adsorbed PM presented daily physical–chemical variations. • Particles sorbed dominated by Si-rich, Organic-rich, SO-rich, Fe-rich and Cl-rich. - Airborne pollen is able to transport finer particulate matter, which presents daily physical–chemical variations.

  17. Fabrication of particulate metal fuel for fast burner reactors

    International Nuclear Information System (INIS)

    Ryu, Ho Jin; Lee, Sun Yong; Kim, Jong Hwan; Woo, Yoon Myung; Ko, Young Mo; Kim, Ki Hwan; Park, Jong Man; Lee, Chan Bok

    2012-01-01

    U Zr metallic fuel for sodium cooled fast reactors is now being developed by KAERI as a national R and D program of Korea. In order to recycle transuranic elements (TRU) retained in spent nuclear fuel, remote fabrication capability in a shielded hot cell should be prepared. Moreover, generation of long lived radioactive wastes and loss of volatile species should be minimized during the recycled fuel fabrication step. Therefore, innovative fuel concepts should be developed to address the fabrication challenges pertaining to TRU while maintaining good performances of metallic fuel. Particulate fuel concepts have already been proposed and tested at several experimental fast reactor systems and vipac ceramic fuel of RIAR, Russia is one of the examples. However, much less work has been reported for particulate metallic fuel development. Spherical uranium alloy particles with various diameters can be easily produced by the centrifugal atomization technique developed by KAERI. Using the atomized uranium and uranium zirconium alloy particles, we fabricated various kinds of powder pack, powder compacts and sintered pellets. The microstructures and properties of the powder pack and pellets are presented

  18. Particulate air pollution and vascular reactivity: the bus stop study.

    Science.gov (United States)

    Dales, Robert; Liu, Ling; Szyszkowicz, Mietek; Dalipaj, Mary; Willey, Jeff; Kulka, Ryan; Ruddy, Terrence D

    2007-11-01

    Particulate air pollution is associated with cardiovascular morbidity but mechanisms are not well understood. We tested the effects on vascular reactivity of exposure to fine particulates matter mass (PM(2.5)), number of particles bus stops. Flow-mediated vasodilation (FMD) of the brachial artery was then measured by ultrasound and expressed as: (maximum artery diameter after release of a blood pressure cuff inflated above systolic pressure-baseline resting diameter)/baseline resting diameter. A 30 microg/m(3) increase in PM(2.5) exposure corresponded to a 0.48% reduction in FMD, P=0.05 representing a 5% relative change in the maximum ability to dilate. Results were consistent between the two bus stops and not sensitive to type of analysis. No significant association was found between FMD and NO(2), PM(1.0) or traffic density. PM(2.5) may reduce the capacity to vasodilate, a potential explanation for the documented association with cardiovascular morbidity.

  19. Impacts modeling using the SPH particulate method. Case study

    International Nuclear Information System (INIS)

    Debord, R.

    1999-01-01

    The aim of this study is the modeling of the impact of melted metal on the reactor vessel head in the case of a core-meltdown accident. Modeling using the classical finite-element method alone is not sufficient but requires a coupling with particulate methods in order to take into account the behaviour of the corium. After a general introduction about particulate methods, the Nabor and SPH (smoothed particle hydrodynamics) methods are described. Then, the theoretical and numerical reliability of the SPH method is determined using simple cases. In particular, the number of neighbours significantly influences the preciseness of calculations. Also, the mesh of the structure must be adapted to the mesh of the fluid in order to reduce the edge effects. Finally, this study has shown that the values of artificial velocity coefficients used in the simulation of the BERDA test performed by the FZK Karlsruhe (Germany) are not correct. The domain of use of these coefficients was precised during a low speed impact. (J.S.)

  20. Collaboration in air particulate analysis through sharing of regional resources

    Energy Technology Data Exchange (ETDEWEB)

    Santos, Flora L. [Philippine Nuclear Research Institute, Diliman, Quezon (Philippines)

    2003-03-01

    The air pollution research program of the Philippine Nuclear Research Institute is being pursued in support of the 1999 Clean Air Act. This is being undertaken as part of the RCA/IAEA subproject, 'Air Pollution and Its Trends'. Since the PNRI research reactor (PRR-I) has been on extended shut down for the past 18 years, the PNRI depends solely on X-ray Fluorescence (XRF) spectrometry for elemental characterization of air particulate samples. NAA is a powerful and efficient tool in air particulate characterization and is used in many national programs in the region. Collaboration in air pollution studies through exchange of samples between XRF and NAA groups will widen the range of elements that could be detected by one group. In the RCA/IAEA RAS/4/020, 'Improvement of Research Reactor Operation and Utilization' sharing of research reactor facilities is encouraged. Working out of mechanisms for such sharing will be advantageous to research groups without operational research reactors. This could take the form of exchange of samples or fellowship at a regional host institution. This will allow training of technical staff from countries without research reactors, thus ensuring continuing expertise in NAA even after long periods of reactor shutdown. (author)