WorldWideScience

Sample records for incident langmuir wavevectors

  1. Wavevector selective metasurfaces and tunnel vision filters

    OpenAIRE

    Fedotov, Vassili; Papasimakis, Nikitas; Zheludev, Nikolay I.; Wallauer, Jan; Walther, Markus; Perino, Mauro

    2015-01-01

    Metasurfaces offer unprecedented flexibility in the design and control of light propagation, replacing bulk optical components and exhibiting exotic optical effects. One of the basic properties of the metasurfaces, which renders them as frequency selective surfaces, is the ability to transmit or reflect radiation within a narrow spectral band that can be engineered on demand. Here we introduce and demonstrate experimentally in the THz domain the concept of wavevector selective surfaces -- met...

  2. Grazing incidence X-ray diffraction study of the tilted phases of Langmuir films: Determination of molecular conformations using simulated annealing

    International Nuclear Information System (INIS)

    Pignat, J.; Daillant, J.; Cantin, S.; Perrot, F.; Konovalov, O.

    2007-01-01

    We have analyzed grazing incidence X-ray diffraction (GIXD) data from condensed phases of Langmuir films of long-chain fatty acids at the air-water using a new method consisting in a careful extraction of the structure factors followed by fitting of molecular parameters using simulated annealing. We show that the information contained in GIXD spectra is enough to obtain near-atomic structural information. In particular, we directly determine the orientation of the chain backbone planes and of the carboxylic headgroups, and we evaluate chain conformation defects

  3. Grazing incidence X-ray diffraction study of the tilted phases of Langmuir films: Determination of molecular conformations using simulated annealing

    Energy Technology Data Exchange (ETDEWEB)

    Pignat, J. [LIONS/Service de Chimie Moleculaire, CEA-Saclay bat. 125, F-91191 Gif-sur-Yvette Cedex (France); LPPI, universite de Cergy-Pontoise, 5 mail Gay-Lussac Neuville/Oise, 95031 Cergy-Pontoise Cedex (France); Daillant, J. [LIONS/Service de Chimie Moleculaire, CEA-Saclay bat. 125, F-91191 Gif-sur-Yvette Cedex (France)]. E-mail: jean.daillant@cea.fr; Cantin, S. [LPPI, universite de Cergy-Pontoise, 5 mail Gay-Lussac Neuville/Oise, 95031 Cergy-Pontoise Cedex (France); Perrot, F. [LPPI, universite de Cergy-Pontoise, 5 mail Gay-Lussac Neuville/Oise, 95031 Cergy-Pontoise Cedex (France); Konovalov, O. [ESRF, 6 rue Jules Horowitz, BP220, 38043 Grenoble Cedex (France)

    2007-05-23

    We have analyzed grazing incidence X-ray diffraction (GIXD) data from condensed phases of Langmuir films of long-chain fatty acids at the air-water using a new method consisting in a careful extraction of the structure factors followed by fitting of molecular parameters using simulated annealing. We show that the information contained in GIXD spectra is enough to obtain near-atomic structural information. In particular, we directly determine the orientation of the chain backbone planes and of the carboxylic headgroups, and we evaluate chain conformation defects.

  4. Irving Langmuir

    Indian Academy of Sciences (India)

    Home; Journals; Resonance – Journal of Science Education; Volume 13; Issue 7. Irving Langmuir - A Pioneering Industrial Physical Chemist. Anil K Rajvanshi. General Article Volume 13 Issue 7 July 2008 pp 619-626. Fulltext. Click here to view fulltext PDF. Permanent link:

  5. Electron dynamics in solid state via time varying wavevectors

    Science.gov (United States)

    Khaneja, Navin

    2018-06-01

    In this paper, we study electron wavepacket dynamics in electric and magnetic fields. We rigorously derive the semiclassical equations of electron dynamics in electric and magnetic fields. We do it both for free electron and electron in a periodic potential. We do this by introducing time varying wavevectors k(t). In the presence of magnetic field, our wavepacket reproduces the classical cyclotron orbits once the origin of the Schröedinger equation is correctly chosen to be center of cyclotron orbit. In the presence of both electric and magnetic fields, our equations for wavepacket dynamics differ from classical Lorentz force equations. We show that in a periodic potential, on application of electric field, the electron wave function adiabatically follows the wavefunction of a time varying Bloch wavevector k(t), with its energies suitably shifted with time. We derive the effective mass equation and discuss conduction in conductors and insulators.

  6. Temperature-Dependent Change of Packing Structure of Condensed-Phase in a Micro-Phase Separated Langmuir Monolayer Studied by Grazing-Incidence X-ray Diffraction

    Energy Technology Data Exchange (ETDEWEB)

    Iimura, Ken-ichi [Department of Applied Chemisty, Faculty of Engineering, Utsunomiya University, 7-1-2 Yoto, Utsunomiya 321-8585, Utsunomiya (Japan); Kato, Teiji [Department of Applied Chemisty, Faculty of Engineering, Utsunomiya University, 7-1-2 Yoto, Utsunomiya 321-8585, Utsunomiya (Japan); Brezesinski, Gerald [Max-Planck Instutite of Colloids and Interfaces, Research Campus Golm, D-14476 Potsdam (Germany)

    2007-10-15

    Packing structure of condensed-phase in a binary mixed Langmuir monolayer of behenic acid (C22) and perfluoro-2,5,8-trimethyl-3,6,9-trioxadodecanoic acid (PFPE) on a cadmium acetate aqueous solution was studied by grazing incidence X-ray diffraction (GIXD) as a function of the subphase temperature. The measurements were made during temperature scan at a fixed molecular area to explain the morphological change of the condensed-phase domains due to a thermal treatment reported previously. Analysis of GIXD data implies that the condensed-phase domains are composed of only the C22 molecules perpendicularly oriented and very closely packed in a centered rectangular unit cell with orthorhombic distortion at low temperatures. As the temperature increases the area occupied by molecule increases, and above 25 deg. C the lattice becomes disordered, which would allow morphological transformation of the condensed-phase domains. The process of packing structure change is almost reversible except for non-equilibrium phases observed for the monolayer spread at a low temperature, 5.5 deg. C.

  7. Temperature-Dependent Change of Packing Structure of Condensed-Phase in a Micro-Phase Separated Langmuir Monolayer Studied by Grazing-Incidence X-ray Diffraction

    International Nuclear Information System (INIS)

    Iimura, Ken-ichi; Kato, Teiji; Brezesinski, Gerald

    2007-01-01

    Packing structure of condensed-phase in a binary mixed Langmuir monolayer of behenic acid (C22) and perfluoro-2,5,8-trimethyl-3,6,9-trioxadodecanoic acid (PFPE) on a cadmium acetate aqueous solution was studied by grazing incidence X-ray diffraction (GIXD) as a function of the subphase temperature. The measurements were made during temperature scan at a fixed molecular area to explain the morphological change of the condensed-phase domains due to a thermal treatment reported previously. Analysis of GIXD data implies that the condensed-phase domains are composed of only the C22 molecules perpendicularly oriented and very closely packed in a centered rectangular unit cell with orthorhombic distortion at low temperatures. As the temperature increases the area occupied by molecule increases, and above 25 deg. C the lattice becomes disordered, which would allow morphological transformation of the condensed-phase domains. The process of packing structure change is almost reversible except for non-equilibrium phases observed for the monolayer spread at a low temperature, 5.5 deg. C

  8. Wave-vector and polarization dependence of conical refraction.

    Science.gov (United States)

    Turpin, A; Loiko, Yu V; Kalkandjiev, T K; Tomizawa, H; Mompart, J

    2013-02-25

    We experimentally address the wave-vector and polarization dependence of the internal conical refraction phenomenon by demonstrating that an input light beam of elliptical transverse profile refracts into two beams after passing along one of the optic axes of a biaxial crystal, i.e. it exhibits double refraction instead of refracting conically. Such double refraction is investigated by the independent rotation of a linear polarizer and a cylindrical lens. Expressions to describe the position and the intensity pattern of the refracted beams are presented and applied to predict the intensity pattern for an axicon beam propagating along the optic axis of a biaxial crystal.

  9. Strong Langmuir turbulence

    International Nuclear Information System (INIS)

    Goldman, M.V.

    1984-01-01

    After a brief discussion of beam-excited Langmuir turbulence in the solar wind, we explain the criteria for wave-particle, three-wave and strong turbulence interactions. We then present the results of a numerical integration of the Zakharov equations, which describe the strong turbulence saturation of a weak (low-density) high energy, bump-on-tail beam instability. (author)

  10. Low wavevector in the 2-dimensional electron solid on liquid helium

    International Nuclear Information System (INIS)

    Williams, F.I.B.

    1983-08-01

    I try to summarize what the experiments have been able to say about the phonons. So, far, the principal motivation has been to learn about the phase diagramme and the nature of the phase transition (s), and the phonon properties have been investigated mostly as a manifestation of these. Only the small and very small wavevector regimes have been studied

  11. Wave-Vector Dependence of the Jahn-Teller Interactions in TmVO4

    DEFF Research Database (Denmark)

    Kjems, Jørgen; Hayes, W.; Smith, S. H.

    1975-01-01

    The resonant Jahn-Teller coupling of the B2g acoustic phonon and the Zeeman-split ground doublet in TmVO4 has been studied by inelastic neutron scattering. Tuning of the magnetic field provides a means for investigating the wave-vector dependence of the interactions. We find that the coupling...

  12. Mode Conversion of Langmuir to Electromagnetic Waves with Parallel Inhomogeneity in the Solar Wind and the Corona

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Eun-Hwa; Cairns, Iver H.; Robinson, Peter A.

    2008-06-09

    Linear mode conversion of Langmuir waves to radiation near the plasma frequency at density gradients is potentially relevant to multiple solar radio emissions, ionospheric radar experiments, laboratory plasma devices, and pulsars. Here we study mode conversion in warm magnetized plasmas using a numerical electron fluid simulation code with the density gradient parallel to the ambient magnetic field B0 for a range of incident Langmuir wavevectors. Our results include: (1) Both o- and x-mode waves are produced for Ω ∝ (ωL)1/3(ωc/ω) somewhat less than 1, contrary to previous ideas. Only o mode is produced for Ω and somewhat greater than 1.5. Here ωc is the (angular) electron cyclotron frequency, ω the angular wave frequency, and L the length scale of the (linear) density gradient. (2) In the unmagnetized limit, equal amounts of o- and x-mode radiation are produced. (3) The mode conversion window narrows as Ω increases. (4) As Ω increases the total electromagnetic field changes from linear to circular polarization, with the o- and x- mode signals remaining circularly polarized. (5) The conversion efficiency to the x mode decreases monotonically as Ω increases while the o-mode conversion efficiency oscillates due to an interference phenomenon between incoming and reflected Langmuir/z modes. (6) The total conversion efficiency for wave energy from the Langmuir/z mode to radiation is typically less than 10%, but the corresponding power efficiencies differ by the ratio of the group speeds for each mode and are of order 50 – 70%. (7) The interference effect and the disappearance of the x mode at Ω somewhat greater than 1 can be accounted for semiquantitatively using a WKB-like analysis. (8) Constraints on density turbulence are developed for the x mode to be generated and be able to propagate from the source. (9) Standard parameters for the corona and the solar wind near 1 AU suggest that linear mode conversion should produce both o- and x- mode radiation for

  13. Mode Conversion of Langmuir to Electromagnetic Waves with Parallel Inhomogeneity in the Solar Wind and the Corona

    International Nuclear Information System (INIS)

    Kim, Eun-Hwa; Cairns, Iver H.; Robinson, Peter A.

    2008-01-01

    Linear mode conversion of Langmuir waves to radiation near the plasma frequency at density gradients is potentially relevant to multiple solar radio emissions, ionospheric radar experiments, laboratory plasma devices, and pulsars. Here we study mode conversion in warm magnetized plasmas using a numerical electron fluid simulation code with the density gradient parallel to the ambient magnetic field B0 for a range of incident Langmuir wavevectors. Our results include: (1) Both o- and x-mode waves are produced for (Omega) ∝ (ωL) 1/3 (ω c /ω) ∼ 1.5. Here ω c is the (angular) electron cyclotron frequency, ω the angular wave frequency, and L the length scale of the (linear) density gradient. (2) In the unmagnetized limit, equal amounts of o- and x-mode radiation are produced. (3) The mode conversion window narrows as (Omega) increases. (4) As (Omega) increases the total electromagnetic field changes from linear to circular polarization, with the o- and x- mode signals remaining circularly polarized. (5) The conversion efficiency to the x mode decreases monotonically as (Omega) increases while the o-mode conversion efficiency oscillates due to an interference phenomenon between incoming and reflected Langmuir/z modes. (6) The total conversion efficiency for wave energy from the Langmuir/z mode to radiation is typically less than 10%, but the corresponding power efficiencies differ by the ratio of the group speeds for each mode and are of order 50-70%. (7) The interference effect and the disappearance of the x mode at (Omega) ∼> 1 can be accounted for semiquantitatively using a WKB-like analysis. (8) Constraints on density turbulence are developed for the x mode to be generated and be able to propagate from the source. (9) Standard parameters for the corona and the solar wind near 1 AU suggest that linear mode conversion should produce both o- and x- mode radiation for solar and interplanetary radio bursts. It is therefore possible that linear mode conversion

  14. Collapse of nonlinear Langmuir waves

    International Nuclear Information System (INIS)

    Malkin, V.M.

    1986-01-01

    The dispersion of sufficiently intensive Langmuir waves is determined by intrinsic (electron) nonlinearity. During Langmuir collapse the wave energy density required for the appearance of electron nonlinearity is attained, generally speaking, prior to the development of dissipative processes. Up to now, the effect of electron nonlinearity on the collapse dynamics and spectrum of strong Langmuir turbulence ( which may be very appreciable ) has not been studied extensively because of the difficulty of describing nonlinear Langmuir waves. In the present paper the positive determinacy of the electron nonlinear hamiltonian is proven, the increment of modulation instability of a nonlinear Langmuir wave cluster localized in a cavity is calculated, and the universal law of their collapse is found

  15. Existence conditions for bulk large-wavevector waves in metal-dielectric and graphene-dielectric multilayer hyperbolic metamaterials

    DEFF Research Database (Denmark)

    Zhukovsky, Sergei; Andryieuski, Andrei; Lavrinenko, Andrei

    2014-01-01

    We theoretically investigate general existence conditions for broadband bulk large-wavevector (high-k) propagating waves (such as volume plasmon polaritons in hyperbolic metamaterials) in arbitrary subwavelength periodic multilayers structures. Treating the elementary excitation in the unit cell...... of the structure as a generalized resonance pole of reflection coefficient and using Bloch's theorem, we derive analytical expressions for the band of large-wavevector propagating solutions. We apply our formalism to determine the high-k band existence in two important cases: the well-known metal-dielectric...

  16. Langmuir turbulence in space plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Goldman, M.V. [Colorado Univ., Boulder, CO (United States); Newman, D.L. [Colorado Univ., Boulder, CO (United States); Wang, J.G. [Colorado Univ., Boulder, CO (United States); Muschietti, L. [California Univ., Berkeley (United States). Space Sciences Lab.

    1996-11-01

    Recent developments in theoretical and numerical modeling of Langmuir turbulence in space and laboratory plasmas are addressed. Kinetic effects, which have been missing from (fluid) traditional Zakharov equation models are explored using Vlasov code simulations. These studies are motivated by beam-driven Langmuir waves and particle distributions measured in earth`s foreshock region, and by beam-driven Langmuir waves and beams that underlie type III solar radio emission in the solar wind. The nonlinear physical processes studied in these 1-D Vlasov simulations include both wave-wave interactions and acceleration of particles by waves-leading to electron-beam flattening. We study bump-on-tail instabilities as boundary value problems, and determine the interplay in space and time between beam plateau formation, stimulated wave-wave backscatter cascades, and strong turbulence wave-packet collapse. (orig.).

  17. Topics in strong Langmuir turbulence

    International Nuclear Information System (INIS)

    Skoric, M.M.

    1981-01-01

    This thesis discusses certain aspects of the turbulence of a fully ionised non-isothermal plasma dominated by the Langmuir mode. Some of the basic properties of strongly turbulent plasmas are reviewed. In particular, interest is focused on the state of Langmuir turbulence, that is the turbulence of a simple externally unmagnetized plasma. The problem of the existence and dynamics of Langmuir collapse is discussed, often met as a non-linear stage of the modulational instability in the framework of the Zakharov equations (i.e. simple time-averaged dynamical equations). Possible macroscopic consequences of such dynamical turbulent models are investigated. In order to study highly non-linear collapse dynamics in its advanced stage, a set of generalized Zakharov equations are derived. Going beyond the original approximation, the author includes the effects of higher electron non-linearities and a breakdown of slow-timescale quasi-neutrality. He investigates how these corrections may influence the collapse stabilisation. Recently, it has been realised that the modulational instability in a Langmuir plasma will be accompanied by the collisionless-generation of a slow-timescale magnetic field. Accordingly, a novel physical situation has emerged which is investigated in detail. The stability of monochromatic Langmuir waves in a self-magnetized Langmuir plasma, is discussed, and the existence of a novel magneto-modulational instability shown. The wave collapse dynamics is investigated and a physical interpretation of the basic results is given. A problem of the transient analysis of an interaction of time-dependent electromagnetic pulses with linear cold plasma media is investigated. (Auth.)

  18. Single-chain statistics and the upper wave-vector cutoff in polymer blends

    International Nuclear Information System (INIS)

    Holyst, R.; Vilgis, T.A.

    1994-01-01

    We derive the equation for the single-chain correlation function in polymer blends. The chains in the incompressible blend have a radius of gyration smaller than the radius of gyration for ideal chains. The chains shrink progressively as we approach the critical temperature T c . The correction responsible for shrinking is proportional to 1/ √N , where N is the polymerization index. At T=T c and for N=1000, the size of the chain has been estimated to be 10% smaller than the size of the ideal coil. The estimate relies on the appropriate cutoff. In the limit of N→∞ the chains approach the random walk limit. Additionally, we propose in this paper a self-consistent determination of the radius of gyration and the upper wave-vector cutoff. Our model is free from any divergences such as were encountered in the previous mean-field studies; we make an estimate of the chain size at the true critical temperature and not the mean-field one

  19. Interaction of langmuir and ion acoustic waves

    International Nuclear Information System (INIS)

    Lee, Hee Jae

    1991-01-01

    Interaction of Langmuir and ion acoustic waves in a plasma is described by Landau-Ginzburg type of equation when the group velocity of the Langmuir wave is equal to the wave velocity of ion acoustic wave. (Author)

  20. Vertical mixing by Langmuir circulations

    International Nuclear Information System (INIS)

    McWilliams, James C.; Sullivan, Peter P.

    2001-01-01

    Wind and surface wave frequently induce Langmuir circulations (LC) in the upper ocean, and the LC contribute to mixing materials down from the surface. In this paper we analyze large-eddy simulation (LES) cases based on surface-wave-averaged, dynamical equations and show that the effect of the LC is a great increase in the vertical mixing efficiency for both material properties and momentum. We provide new confirmation that the previously proposed K-profile parameterization (KPP) model accurately characterizes the turbulent transport in a weakly convective, wind-driven boundary layer with stable interior stratification. We also propose a modest generalization of KPP for the regime of weakly convective Langmuir turbulence. This makes the KPP turbulent flux profiles match those in the LES case with LC present fairly well, especially so for material properties being transported downwards from the ocean surface. However, some open issues remain about how well the present LES and KPP formulations represent Langmuir turbulence, in part because wave-breaking effects are not yet included. (Author)

  1. Phonon self-energy corrections to non-zero wavevector phonon modes in single-layer graphene

    Science.gov (United States)

    Araujo, Paulo; Mafra, Daniela; Sato, Kentaro; Saito, Richiiro; Kong, Jing; Dresselhaus, Mildred

    2012-02-01

    Phonon self-energy corrections have mostly been studied theoretically and experimentally for phonon modes with zone-center (q = 0) wave-vectors. Here, gate-modulated Raman scattering is used to study phonons of a single layer of graphene (1LG) in the frequency range from 2350 to 2750 cm-1, which shows the G* and the G'-band features originating from a double-resonant Raman process with q 0. The observed phonon renormalization effects are different from what is observed for the zone-center q = 0 case. To explain our experimental findings, we explored the phonon self-energy for the phonons with non-zero wave-vectors (q 0) in 1LG in which the frequencies and decay widths are expected to behave oppositely to the behavior observed in the corresponding zone-center q = 0 processes. Within this framework, we resolve the identification of the phonon modes contributing to the G* Raman feature at 2450 cm-1 to include the iTO+LA combination modes with q 0 and the 2iTO overtone modes with q = 0, showing both to be associated with wave-vectors near the high symmetry point K in the Brillouin zone.

  2. A computerized Langmuir probe system

    International Nuclear Information System (INIS)

    Pilling, L.S.; Bydder, E.L.; Carnegie, D.A.

    2003-01-01

    For low pressure plasmas it is important to record entire single or double Langmuir probe characteristics accurately. For plasmas with a depleted high energy tail, the accuracy of the recorded ion current plays a critical role in determining the electron temperature. Even for high density Maxwellian distributions, it is necessary to accurately model the ion current to obtain the correct electron density. Since the electron and ion current saturation values are, at best, orders of magnitude apart, a single current sensing resistor cannot provide the required resolution to accurately record these values. We present an automated, personal computer based data acquisition system for the determination of fundamental plasma properties in low pressure plasmas. The system is designed for single and double Langmuir probes, whose characteristics can be recorded over a bias voltage range of ±70 V with 12 bit resolution. The current flowing through the probes can be recorded within the range of 5 nA-100 mA. The use of a transimpedance amplifier for current sensing eliminates the requirement for traditional current sensing resistors and hence the need to correct the raw data. The large current recording range is realized through the use of a real time gain switching system in the negative feedback loop of the transimpedance amplifier

  3. A computerized Langmuir probe system

    Science.gov (United States)

    Pilling, L. S.; Bydder, E. L.; Carnegie, D. A.

    2003-07-01

    For low pressure plasmas it is important to record entire single or double Langmuir probe characteristics accurately. For plasmas with a depleted high energy tail, the accuracy of the recorded ion current plays a critical role in determining the electron temperature. Even for high density Maxwellian distributions, it is necessary to accurately model the ion current to obtain the correct electron density. Since the electron and ion current saturation values are, at best, orders of magnitude apart, a single current sensing resistor cannot provide the required resolution to accurately record these values. We present an automated, personal computer based data acquisition system for the determination of fundamental plasma properties in low pressure plasmas. The system is designed for single and double Langmuir probes, whose characteristics can be recorded over a bias voltage range of ±70 V with 12 bit resolution. The current flowing through the probes can be recorded within the range of 5 nA-100 mA. The use of a transimpedance amplifier for current sensing eliminates the requirement for traditional current sensing resistors and hence the need to correct the raw data. The large current recording range is realized through the use of a real time gain switching system in the negative feedback loop of the transimpedance amplifier.

  4. Collisionless dissipation of Langmuir turbulence

    International Nuclear Information System (INIS)

    Erofeev, V.I.

    2002-01-01

    An analysis of two experimental observations of Langmuir wave collapse is performed. The corresponding experimental data are shown to give evidence against the collapse. The physical reason for preventing the collapses is found to be the nonresonant electron diffusion in momentums. In this process, plasma thermal electrons are efficiently heated at the expense of wave energy, and intense collisionless wave dissipation takes place. The basic reason of underestimation of this phenomenon in traditional theory is shown to be the substitution of real plasma by a plasma probabilistic ensemble. A theory of nonresonant electron diffusion in a single collisionless plasma is developed. It is shown that corresponding collisionless wave dissipation may arrest spectral energy transfer towards small wave numbers

  5. Saturation of Langmuir waves in laser-produced plasmas

    International Nuclear Information System (INIS)

    Baker, K.L.

    1996-04-01

    This dissertation deals with the interaction of an intense laser with a plasma (a quasineutral collection of electrons and ions). During this interaction, the laser drives large-amplitude waves through a class of processes known as parametric instabilities. Several such instabilities drive one type of wave, the Langmuir wave, which involves oscillations of the electrons relative to the nearly-stationary ions. There are a number of mechanisms which limit the amplitude to which Langmuir waves grow. In this dissertation, these mechanisms are examined to identify qualitative features which might be observed in experiments and/or simulations. In addition, a number of experiments are proposed to specifically look for particular saturation mechanisms. In a plasma, a Langmuir wave can decay into an electromagnetic wave and an ion wave. This parametric instability is proposed as a source for electromagnetic emission near half of the incident laser frequency observed from laser-produced plasmas. This interpretation is shown to be consistent with existing experimental data and it is found that one of the previous mechanisms used to explain such emission is not. The scattering version of the electromagnetic decay instability is shown to provide an enhanced noise source of electromagnetic waves near the frequency of the incident laser

  6. Postcollaptical effects in strong Langmuir turbulence

    International Nuclear Information System (INIS)

    Malkin, V.M.

    1989-01-01

    The qualitative theory of Langmuir turbulence is constructed, which takes into account the postcollaptical effects. The spectra obtained for Langmuir waves and accelerated electrons differ substantially from those predicted earlier. An interesting feature of new spectra is their dependence on the collapse symmetry. 6 refs

  7. Langmuir and Langmuir-Blodgett films of amphiphilic hexa-peri-hexabenzocoronene: New phase transitions and electronic properties controlled by pressure

    DEFF Research Database (Denmark)

    Reitzel, N.; Hassenkam, T.; Balashev, K.

    2001-01-01

    from a solution at the air-water interface. Grazing-incidence X-ray diffraction (GIXD) and X-ray reflectivity studies of the Langmuir monolayer reveal two crystallographic phases at room temperature which depend on the surface pressure applied to the film. Scattering from very well-ordered (xi = 200...

  8. Langmuir-Blodgett nanotemplates for protein crystallography.

    Science.gov (United States)

    Pechkova, Eugenia; Nicolini, Claudio

    2017-12-01

    The new generation of synchrotrons and microfocused beamlines has enabled great progress in X-ray protein crystallography, resulting in new 3D atomic structures for proteins of high interest to the pharmaceutical industry and life sciences. It is, however, often still challenging to produce protein crystals of sufficient size and quality (order, intensity of diffraction, radiation stability). In this protocol, we provide instructions for performing the Langmuir-Blodgett (LB) nanotemplate method, a crystallization approach that can be used for any protein (including membrane proteins). We describe how to produce highly ordered 2D LB protein monolayers at the air-water interface and deposit them on glass slides. LB-film formation can be observed by surface-pressure measurements and Brewster angle microscopy (BAM), although its quality can be characterized by atomic force microscopy (AFM) and nanogravimetry. Such films are then used as a 2D template for triggering 3D protein crystal formation by hanging-drop vapor diffusion. The procedure for forming the 2D template takes a few minutes. Structural information about the protein reorganization in the LB film during the crystallization process on the nano level can be obtained using an in situ submicron GISAXS (grazing-incidence small-angle X-ray scattering) method. MicroGISAXS spectra, measured directly at the interface of the LB films and protein solution in real time, as described in this protocol, can be interpreted in terms of the buildup of layers, islands, or holes. In our experience, the obtained LB crystals take 1-10 d to prepare and they are more ordered and radiation stable as compared with those produced using other crystallization methods.

  9. Langmuir-Blodgett Films of Graphene Derivatives

    DEFF Research Database (Denmark)

    Petersen, Søren Vermehren

    The work presented in this PhD thesis can be divided into two main categories: 1) Syn-thesis and Langmuir-Blodgett assembly of graphene derivatives and 2) Application and characterization of graphene derivatives as an interface material in molecular electron-ics. While the first category could...... be divided further, the synthesis and Langmuir-Blodgett results are intertwined in such a way that it would be more confusing to pre-sent them separately. The Langmuir-Blodgett deposition also played a crucial, but more isolated, part in the investigation of graphene derivatives as interface material....... Solution processable graphene in the form of chemically derived graphene has been synthesized through the modified Hummers method with subsequent reduction into reduced graphene oxide with hydrazine. The completeness of oxidation, the effect of the refinement steps and the reduction of the graphene oxide...

  10. Statistical models of global Langmuir mixing

    Science.gov (United States)

    Li, Qing; Fox-Kemper, Baylor; Breivik, Øyvind; Webb, Adrean

    2017-05-01

    The effects of Langmuir mixing on the surface ocean mixing may be parameterized by applying an enhancement factor which depends on wave, wind, and ocean state to the turbulent velocity scale in the K-Profile Parameterization. Diagnosing the appropriate enhancement factor online in global climate simulations is readily achieved by coupling with a prognostic wave model, but with significant computational and code development expenses. In this paper, two alternatives that do not require a prognostic wave model, (i) a monthly mean enhancement factor climatology, and (ii) an approximation to the enhancement factor based on the empirical wave spectra, are explored and tested in a global climate model. Both appear to reproduce the Langmuir mixing effects as estimated using a prognostic wave model, with nearly identical and substantial improvements in the simulated mixed layer depth and intermediate water ventilation over control simulations, but significantly less computational cost. Simpler approaches, such as ignoring Langmuir mixing altogether or setting a globally constant Langmuir number, are found to be deficient. Thus, the consequences of Stokes depth and misaligned wind and waves are important.

  11. Langmuir Turbulence: Proposal for a Closure

    DEFF Research Database (Denmark)

    Dysthe, K. B.; Espedal, M. S.; Pécseli, Hans

    1986-01-01

    The Wigner formalism is applied to the standard equations for weakly nonlinear Langmuire waves. On the basis of this formulation, a closed set of equations is obtained to describe the statistical evolution of the average field intensity and the intensity correlation function. The analysis allows...

  12. Structure of binary mixed polymer Langmuir layers

    NARCIS (Netherlands)

    Bernardini, C.

    2012-01-01

    The possibility of preparing 2D stable emulsions through mixing of homopolymers in a Langmuir monolayer is the core topic of this thesis. While colloid science has achieved well established results in the study of bulk dispersed systems, accounts on properties of mixed monomolecular films are

  13. Second harmonic electromagnetic emission via Langmuir wave coalescence

    International Nuclear Information System (INIS)

    Willes, A.J.; Robinson, P.A.; Melrose, D.B.

    1996-01-01

    The coalescence of Langmuir waves to produce electromagnetic waves at twice the plasma frequency is considered. A simplified expression for the rate of production of second harmonic electromagnetic waves is obtained for a broad class of Langmuir spectra. In addition, two different analytic approximations are considered. The validity of the commonly used head-on approximation is explored, in which the two coalescing Langmuir waves are assumed to approach from opposite directions. This approximation breaks down at low Langmuir wavenumbers, and for narrow Langmuir wave spectra. A second, more general, approximation is introduced, called the narrow-spectrum approximation, which requires narrow spectral widths of the Langmuir spectra. The advantages of this approximation are that it does not break down at low Langmuir wavenumbers, and that it remains valid for relatively broad Langmuir wave spectra. Finally, the applicability of these approximations in treating harmonic radiation in type III solar radio bursts is discussed. copyright 1996 American Institute of Physics

  14. Caviton dynamics in strong Langmuir turbulence

    Science.gov (United States)

    DuBois, Don; Rose, Harvey A.; Russell, David

    1990-01-01

    Recent studies based on long time computer simulations of Langmuir turbulence as described by Zakharov's model will be reviewed. These show that for strong to moderate ion sound damping the turbulent energy is dominantly in non-linear "caviton" excitations which are localized in space and time. A local caviton model will be presented which accounts for the nucleation-collapse-burnout cycles of individual cavitons as well as their space-time correlations. This model is in detailed agreement with many features of the electron density fluctuation spectra in the ionosphere modified by powerful HF waves as measured by incoherent scatter radar. Recently such observations have verified a prediction of the theory that "free" Langmuir waves are emitted in the caviton collapse process. These observations and theoretical considerations also strongly imply that cavitons in the heated ionosphere, under certain conditions, evolve to states in which they are ordered in space and time. The sensitivity of the high frequency Langmuir field dynamics to the low frequency ion density fluctuations and the related caviton nucleation process will be discussed.

  15. Dynamics of cavitons in strong Langmuir turbulence

    Science.gov (United States)

    Dubois, D. F.; Rose, Harvey A.; Russell, David

    Recent studies of Langmuir turbulence as described by Zakharov's model will be reviewed. For parameters of interest in laser-plasma experiments and for ionospheric hf heating experiments a significant fraction of the turbulent energy is in nonlinear caviton excitations which are localized in space and time. A local caviton model will be presented which accounts for the nucleation-collapse-burnout cycles of individual cavitons as well as their space-time correlations. This model is in detailed agreement with many features of the electron density fluctuation spectra in the ionosphere modified by powerful hf waves as measured by incoherent scatter radar. Recently such observations have verified a prediction of the theory that free Langmuir waves are emitted in the caviton collapse process. Observations and theoretical considerations also imply that when the pump frequency is slightly lower than the ambient electron plasma frequency cavitons may evolve to states in which they are ordered in space and time. The sensitivity of the high frequency Langmuir field dynamics to the low frequency ion density fluctuations and the related caviton nucleation process will be discussed.

  16. Caviton dynamics in strong Langmuir turbulence

    International Nuclear Information System (INIS)

    DuBois, D.; Rose, H.A.; Russell, D.

    1990-01-01

    Recent studies based on long time computer simulations of Langmuir turbulence as described by Zakharov's model will be reviewed. These show that for strong to moderate ion sound damping the turbulent energy is dominantly in non-linear ''caviton'' excitations which are localized in space and time. A local caviton model will be presented which accounts for the nucleation-collapse-burnout cycles of individual cavitons as well as their space-time correlations. This model is in detailed agreement with many features of the electron density fluctuation spectra in the ionosphere modified by powerful HF waves as measured by incoherent scatter radar. Recently such observations have verified a prediction of the theory that ''free'' Langmuir waves are emitted in the caviton collapse process. These observations and theoretical considerations also strongly imply that cavitons in the heated ionosphere, under certain conditions, evolve to states in which they are ordered in space and time. The sensitivity of the high frequency Langmuir field dynamics to the low frequency ion density fluctuations and the related caviton nucleation process will be discussed. (orig.)

  17. Caviton dynamics in strong Langmuir turbulence

    International Nuclear Information System (INIS)

    DuBois, D.; Rose, H.A.; Russell, D.

    1989-01-01

    Recent studies based on long time computer simulations of Langmuir turbulence as described by Zakharov's model will be reviewed. These show that for strong to moderate ion sound samping the turbulent energy is dominantly in nonlinear ''caviton'' excitations which are localized in space and time. A local caviton model will be presented which accounts for the nucleation-collapse-burnout cycles of individual cavitons as well as their space-time correlations. This model is in detailed agreement with many features of the electron density fluctuation spectra in the ionosphere modified by powerful hf waves as measured by incoherent scatter radar. Recently such observations have verified a prediction of the theory that ''free'' Langmuir waves are emitted in the caviton collapse process. These observations and theoretical considerations also strongly imply that cavitons in the heated ionosphere, under certain conditions, evolve to states in which they are ordered in space and time. The sensitivity of the high frequency Langmuir field dynamics to the low frequency ion density fluctuations and the related caviton nucleation process will be discussed. 40 refs., 19 figs

  18. Modulated Langmuir waves and nonlinear Landau damping

    International Nuclear Information System (INIS)

    Yajima, Nobuo; Oikawa, Masayuki; Satsuma, Junkichi; Namba, Chusei.

    1975-01-01

    The nonlinear Schroedinger euqation with an integral term, iusub(t)+P/2.usub(xx)+Q/u/ 2 u+RP∫sub(-infinity)sup(infinity)[/u(x',t)/ 2 /(x-x')]dx'u=0, which describes modulated Langmuir waves with the nonlinear Landau damping effect, is solved by numerical calculations. Especially, the effects of nonlinear Landau damping on solitary wave solutions are studied. For both cases, PQ>0 and PQ<0, the results show that the solitary waves deform in an asymmetric way changing its velocity. (auth.)

  19. Interaction of Langmuir solitons with sound

    International Nuclear Information System (INIS)

    Kurin, V.V.; Fraiman, G.M.

    1981-01-01

    The adiabatic approximation is used to study the interaction of Langmuir solitons with long ion-acoustic waves. The finite acoustic velocity gives rise to an effective mass for the soliton which is quite different from that in the approximation of a local nonlinearity. The force acting on a soliton, averaged over the period of the acoustic wave, is derived. The system of kinetic equations is analyzed in the approximation of random phases of the acoustic waves. The interaction of acoustic waves with solitons causes the acoustic spectrum to become more nearly isotropic, and the solitons are effectively damped

  20. Contamination-free sounding rocket Langmuir probe

    Science.gov (United States)

    Amatucci, W. E.; Schuck, P. W.; Walker, D. N.; Kintner, P. M.; Powell, S.; Holback, B.; Leonhardt, D.

    2001-04-01

    A technique for removing surface contaminants from a sounding rocket spherical Langmuir probe is presented. Contamination layers present on probe surfaces can skew the collected data, resulting in the incorrect determination of plasma parameters. Despite following the usual probe cleaning techniques that are used prior to a launch, the probe surface can become coated with layers of adsorbed neutral gas in less than a second when exposed to atmosphere. The laboratory tests reported here show that by heating the probe from the interior using a small halogen lamp, adsorbed neutral particles can be removed from the probe surface, allowing accurate plasma parameter measurements to be made.

  1. ECR plasma diagnostics with Langmuir probe

    International Nuclear Information System (INIS)

    Kenez, L.; Biri, S.; Valek, A.

    2000-01-01

    Complete text of publication follows. An Electron Cyclotron Resonance (ECR) Ion Source is a tool to generate highly charged ions. The ion beam is extracted from the plasma chamber of the ECRIS. Higher charge states and beam intensities are the main objectives of ECR research. The heart of an ion source is the confined plasma which should be well known to reach those objectives. Information about the plasma can be obtained by plasma diagnostics methods. Langmuir probes were successfully used in case of other plasmas, e.g. TOKAMAK. Until last year plasma diagnostics at the ATOMKI ECRIS was performed by X-ray and visible light measurements. While X-ray measurements give global information, the Langmuir probe method can give information on the local plasma parameters. This is an advantage because the local parameters are not known in detail. By Langmuir probe measurements it is possible to get information on plasma density, plasma potential and partly on the electron temperature. From the experimental point of view a Langmuir probe is very simple. However, the precise positioning of the probe in the plasma chamber (HV platform, strong magnetic field, RF waves) is a difficult task. Also the theory of probes is complicated: the ECR plasma is a special one because the confining magnetic field is inhomogeneous, beside hot electrons it contains cold ions with different charge states and it is heated with high frequency EM waves. What can be measured with a probe is a voltage-current (U-I) characteristics. Figure 1 shows a typical U-I curve measured in our lab. As it can be seen in the figure the diagram has three main parts. An ion saturation current region (I.), an electron saturation current region (III.) and a transition region (II.) between them. These measurements were performed using two different power supplies to bias the probe to positive and negative voltage. To perform more precise U-I measurements we need a special power supply which is presently being built in

  2. On the theory of Langmuir solitons

    International Nuclear Information System (INIS)

    Gibbons, J.; Thornhill, S.G.; Wardrop, M.J.; Ter Haar, D.

    1977-01-01

    A Lagrangian density is found from which the equations of motion for the Langmuir solitons follow in the usual way. It is shown how this Lagrangian leads to the usual conservation laws. For the one-dimensional case a consideration of these conservation laws can help in understanding some of the results obtained in numerical experiments on the behaviour of a strongly turbulent plasma. It is shown that the situation in the three-dimensional case may be fundamentally different, and the near-sonic perturbations and Karpman's treatment of these is discussed. (U.K.)

  3. Validating experimental and theoretical Langmuir probe analyses

    Science.gov (United States)

    Pilling, L. S.; Carnegie, D. A.

    2007-08-01

    Analysis of Langmuir probe characteristics contains a paradox in that it is unknown a priori which theory is applicable before it is applied. Often theories are assumed to be correct when certain criteria are met although they may not validate the approach used. We have analysed the Langmuir probe data from cylindrical double and single probes acquired from a dc discharge plasma over a wide variety of conditions. This discharge contains a dual-temperature distribution and hence fitting a theoretically generated curve is impractical. To determine the densities, an examination of the current theories was necessary. For the conditions where the probe radius is the same order of magnitude as the Debye length, the gradient expected for orbital-motion limited (OML) is approximately the same as the radial-motion gradients. An analysis of the 'gradients' from the radial-motion theory was able to resolve the differences from the OML gradient value of two. The method was also able to determine whether radial or OML theories applied without knowledge of the electron temperature, or separation of the ion and electron contributions. Only the value of the space potential is necessary to determine the applicable theory.

  4. Simulation of weak and strong Langmuir collapse regimes

    International Nuclear Information System (INIS)

    Hadzievski, L.R.; Skoric, M.M.; Kono, M.; Sato, T.

    1998-01-01

    In order to check the validity of the self-similar solutions and the existence of weak and strong collapse regimes, direct two dimensional simulation of the time evolution of a Langmuir soliton instability is performed. Simulation is based on the Zakharov model of strong Langmuir turbulence in a weakly magnetized plasma accounting for the full ion dynamics. For parameters considered, agreement with self-similar dynamics of the weak collapse type is found with no evidence of the strong Langmuir collapse. (author)

  5. The child-Langmuir limit for semiconductors: a numerical validation

    International Nuclear Information System (INIS)

    Caceres, M.J.; Carrillo, J.A.; Degond, P.

    2002-01-01

    The Boltzmann-Poisson system modeling the electron flow in semiconductors is used to discuss the validity of the Child-Langmuir asymptotics. The scattering kernel is approximated by a simple relaxation time operator. The Child-Langmuir limit gives an approximation of the current-voltage characteristic curves by means of a scaling procedure in which the ballistic velocity is much larger that the thermal one. We discuss the validity of the Child-Langmuir regime by performing detailed numerical comparisons between the simulation of the Boltzmann-Poisson system and the Child-Langmuir equations in test problems. (authors)

  6. Electromagnetic radiation from strong Langmuir turbulence

    International Nuclear Information System (INIS)

    Akimoto, K.; Rowland, H.L.; Papadopoulos, K.

    1988-01-01

    A series of computer simulations is reported showing the generation of electromagnetic radiation by strong Langmuir turbulence. The simulations were carried out with a fully electromagnetic 2 1/2 -dimensional fluid code. The radiation process takes place in two stages that reflect the evolution of the electrostatic turbulence. During the first stage while the electrostatic turbulence is evolving from an initial linear wave packet into a planar soliton, the radiation is primarily at ω/sub e/. During the second stage when transverse instabilities lead to the collapse and dissipation of the solitons, 2ω/sub e/ and ω/sub e/ radiation are comparable, and 3ω/sub e/ is also present. The radiation power at ω = 2ω/sub e/ is in good agreement with theoretical predictions for electromagnetic emissions by collapsing solitons

  7. Asymmetric double Langmuir probe: Small signal application

    International Nuclear Information System (INIS)

    Uckan, T.

    1987-11-01

    We discuss the asymmetric double Langmuir probe (ADLP) and demonstrate the possibility of using it to measure plasma temperature T/sub e/ and density n when it is operated in the region of small signal response. The area of one of the ADLP collectors is considerably larger than the other. This probe can be operated at a relatively low applied voltage, eV/sub a/T/sub e/ < 1, and still provides sufficient information to determine the plasma T/sub e/ and n. There is no need for a direct measurement of the ion saturation current, which can be on the order of a few amperes in large fusion devices. This reduces the requirements on the probe power supply. 6 refs., 6 figs

  8. The Sheath-less Planar Langmuir Probe

    Science.gov (United States)

    Cooke, D. L.

    2017-12-01

    The Langmuir probe is one of the oldest plasma diagnostics, provided the plasma density and species temperature from analysis of a current-voltage curve as the voltage is swept over a practically chosen range. The analysis depends on a knowledge or theory of the many factors that influence the current-voltage curve including, probe shape, size, nearby perturbations, and the voltage reference. For applications in Low Earth Orbit, the Planar Langmuir Probe, PLP, is an attractive geometry because the ram ion current is very constant over many Volts of a sweep, allowing the ion density and electron temperature to be determined independently with the same instrument, at different points on the sweep. However, when the physical voltage reference is itself small and electrically floating as with a small spacecraft, the spacecraft and probe system become a double probe where the current collection theory depends on the interaction of the spacecraft with the plasma which is generally not as simple as the probe itself. The Sheath-less PLP, SPLP, interlaces on a single ram facing surface, two variably biased probe elements, broken into many small and intertwined segments on a scale smaller than the plasma Debye length. The SPLP is electrically isolated from the rest of the spacecraft. For relative bias potentials of a few volts, the ion current to all segments of each element will be constant, while the electron currents will vary as a function of the element potential and the electron temperature. Because the segments are small, intertwined, and floating, the assembly will always present the same floating potential to the plasma, with minimal growth as a function of voltage, thus sheath-less and still planar. This concept has been modelled with Nascap, and tested with a physical model inserted into a Low Earth Orbit-like chamber plasma. Results will be presented.

  9. Adsorption and enzyme activity of asparaginase at lipid Langmuir and Langmuir-Blodgett films

    International Nuclear Information System (INIS)

    Rocha Junior, Carlos da; Caseli, Luciano

    2017-01-01

    In this present work, the surface activity of the enzyme asparaginase was investigated at the air-water interface, presenting surface activity in high ionic strengths. Asparaginase was incorporated in Langmuir monolayers of the phospholipid dipalmitoylphosphatidylcholine (DPPC), forming a mixed film, which was characterized with surface pressure-area isotherms, surface potential-area isotherms, polarization-modulated infrared reflection-absorption spectroscopy (PM-IRRAS), and Brewster angle microscopy (BAM). The adsorption of the enzyme at the air-water interface condensed the lipid monolayer and increased the film compressibility at high surface pressures. Amide bands in the PM-IRRAS spectra were identified, with the C−N and C =O dipole moments lying parallel to monolayer plane, revealing the structuring of the enzyme into α-helices and β-sheets. The floating monolayers were transferred to solid supports as Langmuir-Blodgett (LB) films and characterized with fluorescence spectroscopy and atomic force microscopy. Catalytic activities of the films were measured and compared to the homogenous medium. The enzyme accommodated in the LB films preserved more than 78% of the enzyme activity after 30 days, in contrast for the homogeneous medium, which preserved less than 13%. The method presented in this work not only allows for an enhanced catalytic activity, but also can help explain why certain film architectures exhibit better performance. - Highlights: • Biomembranes are mimicked with Langmuir monolayers. • Asparaginase is incorporated into the lipid monolayer. • Enzyme adsorption is confirmed with tensiometry and infrared spectroscopy. • Langmuir-Blodgett films of the enzyme present enzyme activity.

  10. Adsorption and enzyme activity of asparaginase at lipid Langmuir and Langmuir-Blodgett films

    Energy Technology Data Exchange (ETDEWEB)

    Rocha Junior, Carlos da; Caseli, Luciano, E-mail: lcaseli@unifesp.br

    2017-04-01

    In this present work, the surface activity of the enzyme asparaginase was investigated at the air-water interface, presenting surface activity in high ionic strengths. Asparaginase was incorporated in Langmuir monolayers of the phospholipid dipalmitoylphosphatidylcholine (DPPC), forming a mixed film, which was characterized with surface pressure-area isotherms, surface potential-area isotherms, polarization-modulated infrared reflection-absorption spectroscopy (PM-IRRAS), and Brewster angle microscopy (BAM). The adsorption of the enzyme at the air-water interface condensed the lipid monolayer and increased the film compressibility at high surface pressures. Amide bands in the PM-IRRAS spectra were identified, with the C−N and C =O dipole moments lying parallel to monolayer plane, revealing the structuring of the enzyme into α-helices and β-sheets. The floating monolayers were transferred to solid supports as Langmuir-Blodgett (LB) films and characterized with fluorescence spectroscopy and atomic force microscopy. Catalytic activities of the films were measured and compared to the homogenous medium. The enzyme accommodated in the LB films preserved more than 78% of the enzyme activity after 30 days, in contrast for the homogeneous medium, which preserved less than 13%. The method presented in this work not only allows for an enhanced catalytic activity, but also can help explain why certain film architectures exhibit better performance. - Highlights: • Biomembranes are mimicked with Langmuir monolayers. • Asparaginase is incorporated into the lipid monolayer. • Enzyme adsorption is confirmed with tensiometry and infrared spectroscopy. • Langmuir-Blodgett films of the enzyme present enzyme activity.

  11. Upconversion of ion-sound to Langmuir turbulence

    International Nuclear Information System (INIS)

    Vlahos, L.; Papadopoulos, K.

    1979-01-01

    It is shown that upconversion of ion sound to Langmuir waves is impossible in a plasma with upsilon/sub d/< upsilon/sub e/. Previous conclusions to the opposite were in error, owing to neglect of the reverse process (i.e., reabsorbtion of Langmuir waves), which always dominates for upsilon/sub d/< upsilon/sub e/

  12. On the role of sound in the strong Langmuir turbulence

    International Nuclear Information System (INIS)

    Malkin, V.M.

    1989-01-01

    The main directions in the precision of the theory of strong Langmuir turbulence caused by the necessity of account of sound waves in plasma are preseted. In particular the effect of conversion of short-wave modulations in Langmuir waves induced by sound waves, are briefly described. 8 refs

  13. Non-Linear Langmuir Wave Modulation in Collisionless Plasmas

    DEFF Research Database (Denmark)

    Dysthe, K. B.; Pécseli, Hans

    1977-01-01

    in the expressions concerning the modulation instability of a plane Langmuir wave. When the Vlasov equation for the ions is applied, a Langmuir wave is modulationally unstable for arbitrary perturbations independent of the unperturbed wave amplitude, in contrast to what is found for fluid ions. A simple analogy...

  14. PMMA highlights the layering transition of PDMS in Langmuir films

    NARCIS (Netherlands)

    Bernardini, C.; Stoyanov, S.D.; Cohen Stuart, M.A.; Arnaudov, L.N.; Leermakers, F.A.M.

    2011-01-01

    We report a system consisting of a mixed Langmuir monolayer, made of water-insoluble, spreadable, fluid-like polymers polydimethylsiloxane (PDMS) and polymethylmethacrylate (PMMA) with a minority P(DMS-b-MMA) copolymer. We have performed both Langmuir trough pressure/area isotherm measurements and

  15. Langmuir field structures favored in wave collapse

    International Nuclear Information System (INIS)

    Robinson, P.A.; Wouters, M.J.; Broderick, N.G.

    1996-01-01

    Study of Langmuir collapse thresholds shows that they have little polarization dependence and that moving packets have the lowest thresholds in the undamped case. However, incorporation of damping into the density response inhibits collapse of packets moving at more than a small fraction of the sound speed. Investigation of energy transfer to packets localized in density wells emdash the nucleation process emdash shows that at most a few trapped states can exist and that energy transfer is most effective when there is a single barely-trapped state. Coupled with an argument that closely packed wave packets have lower collapse thresholds, this argument yields an estimate of the number density of localized nucleating states in a turbulent plasma. It also leads to a simple and direct semiquantitative estimate of the collapse threshold. All these results are in accord with previous numerical simulations incorporating ion-sound damping, which show a preponderance of slow-moving or stationary packets with little or no intrinsic polarization dependence of thresholds. Likewise, the number densities obtained are in good agreement with simulation values, and the simple estimate of the threshold is semiquantitatively correct. The extent of the agreement supports the nucleation scenario with close-packed nucleation sites in the turbulent state. copyright 1996 American Institute of Physics

  16. Langmuir wave dispersion relation in non-Maxwellian plasmas

    International Nuclear Information System (INIS)

    Ouazene, M.; Annou, R.

    2010-01-01

    The Langmuir wave dispersion relation is derived in partially ionized plasmas, where free electrons are confined to move in a nearest neighbor ions' potential well. The equilibrium velocity distribution function experiences then, a departure from Maxwell distribution function. The effect of the non-Maxwellian character of the distribution function on the Langmuir phase and group velocities as well as the phase matching conditions and the nonlinear growth rate of decay instability is investigated. The proposed Langmuir wave dispersion relation is relevant to dense and cryogenic plasmas.

  17. Theory of Langmuir probes in anisotropic plasmas

    International Nuclear Information System (INIS)

    Sudit, I.D.; Woods, R.C.

    1994-01-01

    A theory has been developed for electron retardation by Langmuir probes of several geometries in a general anisotropic plasma with arbitrary probe orientation and valid for any sheath thickness. Electron densities and electron velocity distribution functions (EVDFs) are obtained from the second derivative of probe I-V curves, as in Druyvesteyn's original method, which was developed for isotropic plasmas. Fedorov had extended the latter method in the context of a thin sheath approximation, to axisymmetric plasmas, in which the EVDF is expanded in a series of Legendary polynomials. In the present work an expansion in a series of spherical harmonics is employed, and the coordinate transformations are handled using the irreducible representation of the three dimensional rotation group. It is shown that the Volterra integral equations that must be solved to obtain the expansion coefficients of the EVDF from the second derivative data are no more complicated in the general case that hose for the axisymmetric plasma. Furthermore in the latter case the results can be shown to be equivalent to Fedrov's thin sheath expression. For the case of planar probes a formulation based on first derivatives of the I-V curves has been obtained. If data is obtained at enough different probe orientation of a one sided planar disc probe, any number of spherical harmonic coefficient functions may be obtained by inverting a set of linear equations and the complete EVDF deduced. For a cylindrical probe or a two-sided planar disc probe the integration of the second derivative of the probe current gives the exact electron density with any arbitrary probe orientation and any degree of plasma anisotropy

  18. Theory of emission spectra from metal films irradiated by low energy electrons near normal incidence

    International Nuclear Information System (INIS)

    Kretschmann, E.; Callcott, T.A.; Arakawa, E.T.

    1980-01-01

    The emission spectrum produced by low energy electrons incident on a rough metal surface has been calculated for a roughness auto-correlation function containing a prominent peak at a high wave vector. For low energy electrons near normal incidence, the high wavevector peak dominates the roughness coupled surface plasmon radiation (RCSPR) process. The calculation yields estimates of the ratio of RCSPR to transition radiation, the dependence of emission intensity on electron energy and the shape and position of the RCSPR peak. The most interesting result is that the high-wavevector roughness can split the RCSPR radiation into peaks lying above and below the asymptotic surface plasma frequency. The results are compared with data from Ag in the following paper. (orig.)

  19. Metallic Langmuir and Langmuir-Blodgett films based on TTF derivatives and fatty acid

    International Nuclear Information System (INIS)

    Ohnuki, H.; Ishizaki, Y.; Suzuki, M.; Desbat, B.; Delhaes, P.; Giffard, M.; Imakubo, T.; Mabon, G.; Izumi, M.

    2002-01-01

    Recent progress in the metallic conducting Langmuir-Blodgett (LB) films built from TTF derivative and fatty acids is reported. A simple LB method of transferring the mixed Langmuir (L) film of BEDO-TTF (BO) and stearic acid (SA) onto substrates provided metallic conducting LB films. A homogeneous L film formation on the water surface observed by Brewster angle microscope (BAM) is an essential factor for the well-ordered LB films. In the L film, the carboxylate group of fatty acid forms anion layer bringing about a spontaneous formation of mixed valence state (MVS) of BO layer. Similar spontaneous formation was also found in the molecular combination of nonoxygen-substituted donor of EDT-TTF and octadecanesulfonic acid (OS). This type of reaction would be useful for obtaining conducting LB films. For the LB films of BEDO-TTF and stearic acid, we found a negative transverse magnetoresistance at low temperature that was interpreted in the weak localization of a two-dimensional (2D) electronic system based on the well-defined conducting layer

  20. Synthesis of Novel Amphiphilic Azobenzenes and X-ray Scattering Studies of Their Langmuir Monolayers

    DEFF Research Database (Denmark)

    Sørensen, Thomas Just; Kjær, Kristian; Breiby, Dag Werner

    2008-01-01

    . At the air-water interface, the amphiphilic azobenzenes form noncrystalline but stable Langmuir films that display an unusual reversible monolayer collapse close to 35 mN/m. The structures and phase transitions were studied by X-ray reflectivity (XR) and grazing-incidence X-ray diffraction, both utilizing...... synchrotron radiation. Compression beyond the collapse point does not change the XR data, showing that the film is unchanged at the molecular level, even at areas less than half of that of the collapse. This leads to the conclusion that few macroscopic collapse sites are responsible for reversibly removing...

  1. Modification of ion-acoustic solitons on interaction with Langmuir waves

    International Nuclear Information System (INIS)

    Basovich, A.Ya.; Gromov, E.M.; Karpman, V.I.

    1981-01-01

    Variation of an ion-accoustic soliton under the effect of the Langmuir quasimonochromatic wave has been considered. Parameters of the soliton tail and variation of soliton velocity have been determined. It is shown that the soliton tail consists of two parts: averaged and oscillating. Density oscillations have a forced nature and are related to the modulation of striction force appearing during interference of waves incident and reflected from a soliton. Oscillations appear behind soliton when the wave runs after soliton and in front of soliton when soliton runs after wave [ru

  2. Macroscopic alignment of graphene stacks by Langmuir-Blodgett deposition of amphiphilic hexabenzocoronenes

    DEFF Research Database (Denmark)

    Laursen, B.W.; Nørgaard, K.; Reitzel, N.

    2004-01-01

    ). Grazing-incidence X-ray diffraction (GIXD) and X-ray reflectivity, both utilizing synchrotron radiation, show that these amphiphilic HBCs form well-defined Langmuir monolayers at the air-water interface, with pi-stacked columnar structure where the HBC cores are rotated around the surface normal...... and tilted relative to the water surface. The intercolumnar distance is 20 A. The HBCs are confined to a layer lying on top of the layer of polar groups that are in contact with the water subphase. Efficient transfer of the monolayer of the anthraquinone-substituted HBC derivative to hydrophobic quartz...

  3. Experimental signatures of localization in Langmuir wave turbulence

    Energy Technology Data Exchange (ETDEWEB)

    Rose, H.A.; DuBois, D.F.; Russell, D.; Bezzerides, B.

    1988-01-01

    Features in certain laser-plasma and ionospheric experiments are identified with the basic properties of Langmuir wave turbulence. Also, a model of caviton nucleation is presented which leads to certain novel scaling predictions. 12 refs., 19 figs.

  4. Langmuir and Langmuir–Blodgett films of capsules of haemoglobin ...

    Indian Academy of Sciences (India)

    Dynamic surface tension and the associated dilational and shear ... logy of the protein films spread in a Langmuir trough. In ..... ing effect of the lateral electrostatic repulsions, such ... formation did not alter the conformation of the protein.

  5. An Adaptive Langmuir Probe for CubeSats and Explorers

    Data.gov (United States)

    National Aeronautics and Space Administration — We propose to build an Adaptive Langmuir Probe (ALP) for CubeSats designed to mitigate spacecraft charging unique to small platforms. This project builds a new...

  6. Polycyclic aromatic hydrocarbons in model bacterial membranes - Langmuir monolayer studies.

    Science.gov (United States)

    Broniatowski, Marcin; Binczycka, Martyna; Wójcik, Aneta; Flasiński, Michał; Wydro, Paweł

    2017-12-01

    High molecular weight polycyclic aromatic hydrocarbons (HMW-PAHs) are persistent organic pollutants which due to their limited biodegradability accumulate in soils where their increased presence can lead to the impoverishment of the decomposer organisms. As very hydrophobic PAHs easily penetrate cellular membranes of soil bacteria and can be incorporated therein, changing the membrane fluidity and other functions which in consequence can lead to the death of the organism. The structure and size of PAH molecule can be crucial for its membrane activity; however the correlation between PAH structure and its interaction with phospholipids have not been investigated so far. In our studies we applied phospholipid Langmuir monolayers as model bacterial membranes and investigated how the incorporation of six structurally different PAH molecules change the membrane texture and physical properties. In our studies we registered surface pressure and surface potential isotherms upon the monolayer compression, visualized the monolayer texture with the application of Brewster angle microscopy and searched the ordering of the film-forming molecules with molecular resolution with the application of grazing incidence X-ray diffraction (GIXD) method. It turned out that the phospholipid-PAH interactions are strictly structure dependent. Four and five-ring PAHs of the angular or cluster geometry can be incorporated into the model membranes changing profoundly their textures and fluidity; whereas linear or large cluster PAHs cannot be incorporated and separate from the lipid matrix. The observed phenomena were explained based on structural similarities of the applied PAHs with membrane steroids and hopanoids. Copyright © 2017. Published by Elsevier B.V.

  7. Langmuir and Langmuir-Blodgett films of multifunctional, amphiphilic polyethers with cholesterol moieties.

    Science.gov (United States)

    Reuter, Sascha; Hofmann, Anna M; Busse, Karsten; Frey, Holger; Kressler, Jörg

    2011-03-01

    Langmuir films of multifunctional, hydrophilic polyethers containing a hydrophobic cholesterol group (Ch) were studied by surface pressure-mean molecular area (π-mmA) measurements and Brewster angle microscopy (BAM). The polyethers were either homopolymers or diblock copolymers of linear poly(glycerol) (lPG), linear poly(glyceryl glycidyl ether) (lPGG), linear poly(ethylene glycol) (lPEG), or hyperbranched poly(glycerol) (hbPG). Surface pressure measurements revealed that the homopolymers lPG and hbPG did not stay at the water surface after spreading and solvent evaporation, in contrast to lPEG. Because of the incorporation of the Ch group in the polymer structure, stable Langmuir films were formed by Ch-lPG(n), Ch-lPGG(n), and Ch-hbPG(n). The Ch-hbPG(n), Ch-lPEG(n), Ch-lPEG(n)-b-lPG(m), Ch-lPEG(n)-b-lPGG(m), and Ch-lPEG(n)-b-hbPG(m) systems showed an extended plateau region assigned to a phase transition involving the Ch groups. Typical hierarchically ordered morphologies of the LB films on hydrophilic substrates were observed for all Ch-initiated polymers. All LB films showed that Ch of the Ch-initiated homopolymers is able to crystallize. This strong tendency of self-aggregation then triggers further dewetting effects of the respective polyether entities. Fingerlike morphologies are observed for Ch-lPEG(69), since the lPEG(69) entity is able to undergo crystallization after transfer onto the silicon substrate.

  8. A theory for the Langmuir waves in the electron foreshock

    International Nuclear Information System (INIS)

    Cairns, I.H.

    1987-01-01

    A theory for the Langmuir (L) waves observed in the electron foreshock is suggested. Free energy for the Langmuir wave growth is contained in cutoff distributions of energetic electrons streaming from the bow shock. These cutoff distributions drive Langmuir wave growth primarily by the kinetic version of the beam instability, and wave growth is limited by quasi-linear relaxation. The observed bump-on-tail electron distributions are interpreted as the remnants of cutoff distributions after quasi-linear relaxation has limited the wave growth. Only plausibility arguments for this theory are given since suitable treatments of quasi-linear relaxation are not presently available. However, it is shown that the wave processes L ± S → L' and L ± S → T (where S and T denote ion sound and transverse waves, respectively), refraction in steady-state density structures, diffusion due to interactions with ion sound turbulence, and effects due to wave convection and spatial gradients in the beam velocity, are unable to suppress the beam instability. The theory leads to natural interpretations of the Langmuir electric field waveforms observed and of the decrease in the Langmuir wave electric fields with increasing distance from the foreshock boundary. The theory for the beam instability is reviewed, and previous analytic and numerical treatments of the beam instability are related

  9. LANGMUIR WAVE DECAY IN INHOMOGENEOUS SOLAR WIND PLASMAS: SIMULATION RESULTS

    Energy Technology Data Exchange (ETDEWEB)

    Krafft, C. [Laboratoire de Physique des Plasmas, Ecole Polytechnique, F-91128 Palaiseau Cedex (France); Volokitin, A. S. [IZMIRAN, Troitsk, 142190, Moscow (Russian Federation); Krasnoselskikh, V. V., E-mail: catherine.krafft@u-psud.fr [Laboratoire de Physique et Chimie de l’Environnement et de l’Espace, 3A Av. de la Recherche Scientifique, F-45071 Orléans Cedex 2 (France)

    2015-08-20

    Langmuir turbulence excited by electron flows in solar wind plasmas is studied on the basis of numerical simulations. In particular, nonlinear wave decay processes involving ion-sound (IS) waves are considered in order to understand their dependence on external long-wavelength plasma density fluctuations. In the presence of inhomogeneities, it is shown that the decay processes are localized in space and, due to the differences between the group velocities of Langmuir and IS waves, their duration is limited so that a full nonlinear saturation cannot be achieved. The reflection and the scattering of Langmuir wave packets on the ambient and randomly varying density fluctuations lead to crucial effects impacting the development of the IS wave spectrum. Notably, beatings between forward propagating Langmuir waves and reflected ones result in the parametric generation of waves of noticeable amplitudes and in the amplification of IS waves. These processes, repeated at different space locations, form a series of cascades of wave energy transfer, similar to those studied in the frame of weak turbulence theory. The dynamics of such a cascading mechanism and its influence on the acceleration of the most energetic part of the electron beam are studied. Finally, the role of the decay processes in the shaping of the profiles of the Langmuir wave packets is discussed, and the waveforms calculated are compared with those observed recently on board the spacecraft Solar TErrestrial RElations Observatory and WIND.

  10. A Robust Definition for the Turbulent Langmuir Number

    Science.gov (United States)

    Christensen, K. H.; Breivik, O.; Sutherland, G.; Belcher, S. E.; Gargett, A.

    2016-02-01

    The turbulent Langmuir number combines the water side friction velocity and the surface value of the Stokes drift, and is central to parameterizations of mixing by Langmuir turbulence. Making a direct comparison between such parameterizations and observations is difficult since the surface Stokes drift is sensitive to both the spectral tail and the directional spread of the waves. We propose a new definition for the turbulent Langmuir number based on low order moments of the one-dimensional frequency spectrum, hence eliminating most of the uncertainties associated with the diagnostic spectral tail. Comparison is made between the old and the new definitions using both observed and modeled wave spectra. The new definition has a higher variation around the mean and is better at resolving typical oceanic conditions. In addition, it is backwards compatible with the old definition for monochromatic waves, which means that scalings based on large eddy simulations with monochromatic wave forcing are still valid.

  11. Child-Langmuir flow with periodically varying anode voltage

    International Nuclear Information System (INIS)

    Rokhlenko, A.

    2015-01-01

    Using the Lagrangian technique, we study settled Child-Langmuir flows in a one dimensional planar diodes whose anode voltages periodically vary around given positive values. Our goal is to find analytically if the average currents in these systems can exceed the famous Child-Langmuir limit found for the stationary current a long time ago. The main result of our study is that in a periodic quasi-stationary regime the average current can be larger than the Child-Langmuir maximum even by 50% compared with its adiabatic average value. The cathode current in this case has the form of rectangular pulses which are formed by a very special triangular voltage modulation. This regime, i.e., periodicity, shape of pulses, and their amplitude, needs to be carefully chosen for the best performance

  12. Charged particle emission: the Child-Langmuir model

    International Nuclear Information System (INIS)

    Degond, P.; Raviart, P.A.

    1993-01-01

    The recent mathematical results concerning boundary emission modelling are reviewed with a synthetical view. The plane diode case is first studied; the Child-Langmuir model is then characterized as the limit to an absolutely non standard singular perturbation problem and is associated with approximate models (constrained and penalized models) which may be easily generalized in more realistic cases; an iterative solution method for the penalized problem is studied. The derived Child-Langmuir model is extended to the cylindrical diode case and to an arbitrary geometry case: constrained and penalized models related to the stationary Vlasov-Poisson equations are studied and extended to the Vlasov-Maxwell evolution equation general case

  13. Limitations on the upconversion of ion sound to Langmuir turbulence

    Science.gov (United States)

    Vlahos, L.; Papadopoulos, K.

    1982-01-01

    The weak turbulence theory of Tsytovich, Stenflo and Wilhelmsson (1981) for evaluation of the nonlinear transfer of ion acoustic waves to Langmuir waves is shown to be limited in its region of validity to the level of ion acoustic waves. It is also demonstrated that, in applying the upconversion of ion sound to Langmuir waves for electron acceleration, nonlinear scattering should be self-consistently included, with a suppression of the upconversion process resulting. The impossibility of accelerating electrons by such a process for any reasonable physical system is thereby reaffirmed.

  14. Calibration of langmuir probes by a microwave method; Etalonnage des sondes de langmuir par une methode hyperfrequence

    Energy Technology Data Exchange (ETDEWEB)

    Consoli, T [Commissariat a l' Energie Atomique, Saclay (France).Centre d' Etudes Nucleaires

    1960-07-01

    Measurements of the electronic density of a plasma between 10{sup 6} and 10{sup 8} e/cm{sup 3}, made by the Langmuir probe and by resonance frequency shift of a cavity are compared. (author) [French] On compare les mesures de la densite electronique d'un plasma peu dense 10{sup 6} < ne < 10{sup 8} e/cm{sup 3}, par sonde de Langmuir et par glissement de la frequence de resonance d'une cavite contenant le plasma. (auteur)

  15. Modeling of the Dynamics of Radio Wave Reflection and Absorption in a Smoothly Ionomogeneous Plasma with Electromagnetically Driven Strong Langmuir Turbulence

    Science.gov (United States)

    Kochetov, A. V.

    2018-05-01

    This work was initiated by experiments on studying the self-action of radio waves incident on the ionosphere from a ground-based transmitter at the stage of electromagnetic excitation of Langmuir turbulence (Langmuir effect). The emphasis is on the impact of "self-consistent" collisionless absorption of radio waves by the Langmuir turbulence, which develops when the incident-wave field swells in the resonant region of a smoothly inhomogeneous plasma, on the dynamics of the radio wave reflection. Electrodynamic characteristics of the nonlinear-plasma layer, which has a linear unperturbed profile of the plasma density, with different features of the absorption development are obtained for a high intensity of the incident radiation. Calculations of "soft" and "hard" regimes of the absorption occurrence, as well as hysteresis modes in which the damping switch-on and off thresholds differ several times, are carried out. The algorithms we devised and the results of the study can serve as the basis for a more adequate and more detailed numerical simulation for interpretation of the experimental data obtained at the stage of the Langmuir effect in the ionosphere.

  16. Simulation of the collapse and dissipation of Langmuir wave packets

    International Nuclear Information System (INIS)

    Newman, D.L.; Winglee, R.M.; Robinson, P.A.; Glanz, J.; Goldman, M.V.

    1990-01-01

    The collapse of isolated Langmuir wave packets is studied numerically in two dimensions using both particle-in-cell (PIC) simulations and by integrating the Zakharov partial differential equations (PDE's). The initial state consists of a localized Langmuir wave packet in an ion background that either is uniform or has a profile representative of the density wells in which wave packets form during strong plasma turbulence. Collapse thresholds are determined numerically and compared to analytical estimates. A model in which Langmuir damping is significantly stronger than Landau damping is constructed which, when included in the PDE simulations, yields good agreement with the collapse dynamics observed in PIC simulations for wave packets with initial wave energy densities small compared to the thermal level. For more intense initial Langmuir fields, collapse is arrested in PIC simulations at lower field strengths than in PDE simulations. Neither nonlinear saturation of the density perturbation nor fluid electron nonlinearities can account for the difference between simulation methods in this regime. However, at these wave levels inhomogeneous electron heating and coherent jets of transit-time accelerated electrons in phase space are observed, resulting in further enhancement of wave damping and the consequent reduction of fields in the PIC simulations

  17. Contamination effects on fixed-bias Langmuir probes

    Energy Technology Data Exchange (ETDEWEB)

    Steigies, C. T. [Institut fuer Experimentelle und Angewandte Physik, Christian-Albrechts-Universitaet zu Kiel, 24098 Kiel (Germany); Barjatya, A. [Department of Physical Sciences, Embry-Riddle Aeronautical University, Daytona Beach, Florida 32114 (United States)

    2012-11-15

    Langmuir probes are standard instruments for plasma density measurements on many sounding rockets. These probes can be operated in swept-bias as well as in fixed-bias modes. In swept-bias Langmuir probes, contamination effects are frequently visible as a hysteresis between consecutive up and down voltage ramps. This hysteresis, if not corrected, leads to poorly determined plasma densities and temperatures. With a properly chosen sweep function, the contamination parameters can be determined from the measurements and correct plasma parameters can then be determined. In this paper, we study the contamination effects on fixed-bias Langmuir probes, where no hysteresis type effect is seen in the data. Even though the contamination is not evident from the measurements, it does affect the plasma density fluctuation spectrum as measured by the fixed-bias Langmuir probe. We model the contamination as a simple resistor-capacitor circuit between the probe surface and the plasma. We find that measurements of small scale plasma fluctuations (meter to sub-meter scale) along a rocket trajectory are not affected, but the measured amplitude of large scale plasma density variation (tens of meters or larger) is attenuated. From the model calculations, we determine amplitude and cross-over frequency of the contamination effect on fixed-bias probes for different contamination parameters. The model results also show that a fixed bias probe operating in the ion-saturation region is affected less by contamination as compared to a fixed bias probe operating in the electron saturation region.

  18. Study of molecular orientations in Langmuir-Blodgett films

    International Nuclear Information System (INIS)

    Lesieur, Pierre

    1986-01-01

    This research thesis reports the characterization of Langmuir-Blodgett films by electric paramagnetic resonance and by resonant Raman diffusion in polarized light. Films are made of mixed or alternated multi-layers of amphiphilic porphyrins and docosenoic acid. The author more particularly studied the orientation of porphyrinic macro-cycles with respect to the layer substrate [fr

  19. Planktonic interactions and chaotic advection in Langmuir circulation

    DEFF Research Database (Denmark)

    Bees, Martin Alan; Mezic, I.; McGlade, J.

    1998-01-01

    The role of unsteady laminar flows for planktonic communities is investigated. Langmuir circulation is used, as a typical medium-scale structure, to illustrate mechanisms for the generation of plankton patches. Two behaviours are evident: chaotic regions that help to spread plankton and locally...

  20. Fluctuations measured by flush mounted versus proud divertor Langmuir probes - why are they different?

    Science.gov (United States)

    Garcia, O. E.; Kuang, A. Q.; Brunner, D.; Labombard, B.; Kube, R.

    2017-10-01

    A flush-mounted, toroidally-elongated, and field-aligned divertor `rail' Langmuir probe array was installed in Alcator C-Mod in 2015. This geometry is heat flux tolerant and effectively mitigates sheath expansion effects down to incident field line angles of 0.5 degree. Further complications have arisen that cannot be explained by sheath-expansion. In particular, the `rail' probe geometry measures significantly higher plasma fluctuation levels in the common flux region compared to traditional proud probes, whereas they are similar in the private flux zone. In some instances, the amplitudes of ion saturation current fluctuations normalized to the mean are a factor of 2 higher; probability distribution functions correspondingly record large amplitude events that are not seen by the proud probes. This discrepancy also appears to depend on divertor plasma regime. For example, fluctuations become similar near the strikepoint when the electron temperature is low. To ensure that these discrepancies were not due to perturbations caused by the voltage bias or currents collected by the probes, the two Langmuir probe systems were left to `float' and the fluctuation statistics analyzed. Yet, even in this non-perturbative situation, there exist clear differences in the fluctuation characteristics. The raises two questions: how does the probe geometry affect plasma fluctuations measurements and what are the true plasma fluctuations experienced by the divertor surface? Supported by USDoE awards DE-FC02-99ER54512.

  1. Transition from two-dimensional to three-dimensional melting in Langmuir-Blodgett films

    International Nuclear Information System (INIS)

    Mukhopadhyay, M.K.; Sanyal, M.K.; Datta, A.; Mukherjee, M.; Geue, Th.; Grenzer, J.; Pietsch, U.

    2004-01-01

    Results of energy-dispersive x-ray reflectivity and grazing incidence diffraction studies of Langmuir-Blodgett films exhibited evolution of conventional three-dimensional melting from continuous melting, characteristic of two-dimensional systems, as a function of deposited monolayers. Continuous expansion followed by a sharp phase transition of the in-plane lattice was observed before the melting point and found to be independent of number of deposited layers. Evolution of conventional melting with an increase in the number of monolayers could be quantified by measuring stiffness against tilting of the vertical stack of molecules, which are kept together by an internal field. The internal field as defined in this model reduces as the in-plane lattice expands and the sample temperature approaches melting point. The sharpness of the melting transition, which has been approximated by a Langevin function, increases with the number of deposited monolayers

  2. Self-consistent Langmuir waves in resonantly driven thermal plasmas

    Science.gov (United States)

    Lindberg, R. R.; Charman, A. E.; Wurtele, J. S.

    2007-12-01

    The longitudinal dynamics of a resonantly driven Langmuir wave are analyzed in the limit that the growth of the electrostatic wave is slow compared to the bounce frequency. Using simple physical arguments, the nonlinear distribution function is shown to be nearly invariant in the canonical particle action, provided both a spatially uniform term and higher-order spatial harmonics are included along with the fundamental in the longitudinal electric field. Requirements of self-consistency with the electrostatic potential yield the basic properties of the nonlinear distribution function, including a frequency shift that agrees closely with driven, electrostatic particle simulations over a range of temperatures. This extends earlier work on nonlinear Langmuir waves by Morales and O'Neil [G. J. Morales and T. M. O'Neil, Phys. Rev. Lett. 28, 417 (1972)] and Dewar [R. L. Dewar, Phys. Plasmas 15, 712 (1972)], and could form the basis of a reduced kinetic treatment of plasma dynamics for accelerator applications or Raman backscatter.

  3. Self-consistent Langmuir waves in resonantly driven thermal plasmas

    International Nuclear Information System (INIS)

    Lindberg, R. R.; Charman, A. E.; Wurtele, J. S.

    2007-01-01

    The longitudinal dynamics of a resonantly driven Langmuir wave are analyzed in the limit that the growth of the electrostatic wave is slow compared to the bounce frequency. Using simple physical arguments, the nonlinear distribution function is shown to be nearly invariant in the canonical particle action, provided both a spatially uniform term and higher-order spatial harmonics are included along with the fundamental in the longitudinal electric field. Requirements of self-consistency with the electrostatic potential yield the basic properties of the nonlinear distribution function, including a frequency shift that agrees closely with driven, electrostatic particle simulations over a range of temperatures. This extends earlier work on nonlinear Langmuir waves by Morales and O'Neil [G. J. Morales and T. M. O'Neil, Phys. Rev. Lett. 28, 417 (1972)] and Dewar [R. L. Dewar, Phys. Plasmas 15, 712 (1972)], and could form the basis of a reduced kinetic treatment of plasma dynamics for accelerator applications or Raman backscatter

  4. Operation of a Langmuir Probe in a Photoelectron Plasma

    International Nuclear Information System (INIS)

    Dove, Adrienne; Robertson, Scott; Horanyi, Mihaly; Poppe, Andrew; Wang Xu

    2011-01-01

    Dust transport on the lunar surface is likely facilitated by the variable electric fields that are generated by changing plasma conditions. We have developed an experimental apparatus to study lunar photoelectric phenomena and gain a better understanding of the conditions controlling dust transport. As an initial step, Langmuir probe measurements are used to characterize the photoelectron plasma produced above a Zr surface, and these techniques will be extended to CeO 2 and lunar simulant surfaces.

  5. Langmuir probe study of plasma expansion in pulsed laser ablation

    DEFF Research Database (Denmark)

    Hansen, T.N.; Schou, Jørgen; Lunney, J.G.

    1999-01-01

    Langmuir probes were used to monitor the asymptotic expansion of the plasma produced by the laser ablation of a silver target in a vacuum. The measured angular and temporal distributions of the ion flux and electron temperature were found to be in good agreement with the self-similar isentropic...... and adiabatic solution of the gas dynamics equations describing the expansion. The value of the adiabatic index gamma was about 1.25, consistent with the ablation plume being a low temperature plasma....

  6. Preliminary Langmuir probe results on the CTX gun experiment

    International Nuclear Information System (INIS)

    Tuszewski, M.

    1981-12-01

    Preliminary results obtained with a double Langmuir probe in the Compact Toroid experiment facility confirm the existence of a gun plasma of n approx. 5 x 10 14 cm -3 and T approx. 10 eV lasting for approx. 250 to 400 μs, which is consistent with interferometry and Thomson scattering data. The probe current characteristics as a function of voltage suggest non-Maxwellian features of the particles distribution functions

  7. Epidemic Intelligence. Langmuir and the Birth of Disease Surveillance

    OpenAIRE

    Lyle Fearnley

    2010-01-01

    In the wake of the SARS and influenza epidemics of the past decade, one public health solution has become a refrain: surveillance systems for detection of disease outbreaks. This paper is an effort to understand how disease surveillance for outbreak detection gained such paramount rationality in contemporary public health. The epidemiologist Alexander Langmuir is well known as the creator of modern disease surveillance. But less well known is how he imagined disease surveillance as one part o...

  8. The flush-mounted rail Langmuir probe array designed for the Alcator C-Mod vertical target plate divertor

    Science.gov (United States)

    Kuang, A. Q.; Brunner, D.; LaBombard, B.; Leccacorvi, R.; Vieira, R.

    2018-04-01

    An array of flush-mounted and toroidally elongated Langmuir probes (henceforth called rail probes) have been specifically designed for the Alcator C-Mod's vertical target plate divertor and operated over multiple campaigns. The "flush" geometry enables the tungsten electrodes to survive high heat flux conditions in which traditional "proud" tungsten electrodes suffer damage from melting. The toroidally elongated rail-like geometry reduces the influence of sheath expansion, which is an important effect to consider in the design and interpretation of flush-mounted Langmuir probes. The new rail probes successfully operated during C-Mod's FY2015 and FY2016 experimental campaigns with no evidence of damage, despite being regularly subjected to heat flux densities parallel to the magnetic field exceeding ˜1 GW m-2 for short periods of time. A comparison between rail and proud probe data indicates that sheath expansion effects were successfully mitigated by the rail design, extending the use of these Langmuir probes to incident magnetic field line angles as low as 0.5°.

  9. Solitary Langmuir waves in two-electron temperature plasma

    Science.gov (United States)

    Prudkikh, V. V.; Prudkikh

    2014-06-01

    Nonlinear interaction of Langmuir and ion-acoustic waves in two-electron temperature plasma is investigated. New integrable wave interaction regime was discovered, this regime corresponds to the Langmuir soliton with three-hump amplitude, propagating with a speed close to the ion-sound speed in the conditions of strong non-isothermality of electronic components. It was discovered that besides the known analytical solution in the form of one- and two-hump waves, there exists a range of solutions in the form of solitary waves, which in the form of envelope has multi-peak structure and differs from the standard profiles described by hyperbolic functions. In case of fixed plasma parameters, different group velocities correspond to the waves with different number of peaks. It is found that the Langmuir wave package contains both even and uneven numbers of oscillations. Low-frequency potential here has uneven number of peaks. Interrelation of obtained and known earlier results are also discussed.

  10. Langmuir-Blodgett films of molecular organic materials

    International Nuclear Information System (INIS)

    Talham, Daniel R; Yamamoto, Takashi; Meisel, Mark W

    2008-01-01

    Langmuir-Blodgett methods are perhaps the original approach for achieving controlled deposition of organic thin films. Molecules are first organized into a monolayer array on the surface of water before transfer as a monolayer onto solid supports. Molecular monolayers, multilayers, and multilayered heterostructures can be achieved. The capability of exercising such control over thin film assemblies has attracted materials chemists and physicists to develop Langmuir-Blodgett films for studies on organic conductors, magnets, non-linear optics, rectifiers, and intermolecular electron transfer. This article reviews objectives in each of these areas and selects some specific examples from the literature to highlight the state of the art, mostly from the point of view of the chemical systems that are studied. Mixed organic/inorganic hybrid films represent a new direction for Langmuir-Blodgett films in materials science, combining conventional inorganic solid-state phenomena with the properties of the organic networks, and recent examples, taken principally from the authors' work, are highlighted

  11. Epidemic Intelligence. Langmuir and the Birth of Disease Surveillance

    Directory of Open Access Journals (Sweden)

    Lyle Fearnley

    2010-12-01

    Full Text Available In the wake of the SARS and influenza epidemics of the past decade, one public health solution has become a refrain: surveillance systems for detection of disease outbreaks. This paper is an effort to understand how disease surveillance for outbreak detection gained such paramount rationality in contemporary public health. The epidemiologist Alexander Langmuir is well known as the creator of modern disease surveillance. But less well known is how he imagined disease surveillance as one part of what he called “epidemic intelligence.” Langmuir developed the practice of disease surveillance during an unprecedented moment in which the threat of biological warfare brought civil defense experts and epidemiologists together around a common problem. In this paper, I describe how Langmuir navigated this world, experimenting with new techniques and rationales of epidemic control. Ultimately, I argue, Langmuir′s experiments resulted in a set of techniques and infrastructures – a system of epidemic intelligence – that transformed the epidemic as an object of human art.

  12. Renormalization method and singularities in the theory of Langmuir turbulence

    International Nuclear Information System (INIS)

    Pelletier, G.

    1977-01-01

    The method of renormalization, using propagators and diagrams, is recalled with enough mathematical details to be read and used by a non-specialist. The Markovian models are discussed and applied to plasma turbulence. The physical meaning of the diagrams is exhibited. In addition to the usual resonance broadening, an improved renormalization is set out, including broadening of the nonlinear resonance with a beat wave by induced scattering. This improved renormalization is emphasized. In the case of Langmuir turbulence, it removes difficulties arising at the group velocity, and enhances large-scale induced-scattering diffusion. (author)

  13. Thermionic phenomena the collected works of Irving Langmuir

    CERN Document Server

    Suits, C Guy

    1961-01-01

    Thermionic Phenomena is the third volume of the series entitled The Collected Works of Irving Langmuir. This volume compiles articles written during the 1920's and early 1930's, the period when the science of thermionics is beginning to be of importance. This text is divided into two parts. The first part discusses vacuum pumps, specifically examining the effect of space charge and residual gases on thermionic currents in high vacuum. This part also explains fundamental phenomena in electron tubes having tungsten cathodes and the use of high-power vacuum tubes. The second part of this text loo

  14. Study of a Laser-Produced Plasma by Langmuir Probes

    DEFF Research Database (Denmark)

    Chang, C. T.; Hasimi, M.; Pant, H. C.

    1977-01-01

    -emission peak and the main plasma from the target. The flow velocity, density and electron temperature of the plasma were determined. The expansion of the plasma was found to be adiabatic, yielding gamma =5/3. The spatial distribution of the plasma was observed to be strongly anisotropic.......The structure, the parameters and the expansion of the plasma produced by focusing a 7 J, 20 ns Nd-glass laser on stainless-steel and glass targets suspended in a high-vacuum chamber were investigated by Langmuir probes. It was observed that the probe signals consisted of a photoelectric...

  15. Spreading dynamics of 2D dipolar Langmuir monolayer phases.

    Science.gov (United States)

    Heinig, P; Wurlitzer, S; Fischer, Th M

    2004-07-01

    We study the spreading of a liquid 2D dipolar droplet in a Langmuir monolayer. Interfacial tensions (line tensions) and microscopic contact angles depend on the scale on which they are probed and obey a scaling law. Assuming rapid equilibration of the microscopic contact angle and ideal slippage of the 2D solid/liquid and solid/gas boundary, the driving force of spreading is merely expressed by the shape-dependent long-range interaction integrals. We obtain good agreement between experiment and numerical simulations using this theory.

  16. Self-similar Langmuir collapse at critical dimension

    International Nuclear Information System (INIS)

    Berge, L.; Dousseau, Ph.; Pelletier, G.; Pesme, D.

    1991-01-01

    Two spherically symmetric versions of a self-similar collapse are investigated within the framework of the Zakharov equations, namely, one relative to a vectorial electric field and the other corresponding to a scalar modeling of the Langmuir field. Singular solutions of both of them depend on a linear time contraction rate ξ(t) = V(t * -t), where t * and V = -ξ denote, respectively, the collapse time and the constant collapse velocity. It is shown that under certain conditions, only the scalar model admits self-similar solutions, varying regularly as a function of the control parameter V from the subsonic (V >1) regime. (author)

  17. Designs of Langmuir probes for W7-X

    International Nuclear Information System (INIS)

    Laube, Ralph; Laux, Michael; Ye, Min You; Greuner, Henri; Lindig, Stefan

    2011-01-01

    Several designs of Langmuir probes for the stellarator Wendelstein 7-X (W7-X) are described. Different types of probes are proposed for the different divertors to be used during different operational phases of W7-X. Comb-like arrays of stiff probes, arrays of flexible probes, and fixed inlay probes are reviewed. For the initial phase of W7-X it was decided to install arrays of fixed inlay probes. Two mockups were manufactured and one of them was tested with success in the high heat flux test facility GLADIS. For long-pulse operation of W7-X different conceptual designs are proposed and are still developed further. This paper summarizes the different design constrains for the Langmuir probes in the different divertor surroundings, describes the design of the array of inlay probes for the initial phase and the result of the GLADIS test, and gives a preview of the conceptual designs of probes for the long-pulse operational phase of W7-X.

  18. Protonation of octadecylamine Langmuir monolayer by adsorption of halide counterions

    Science.gov (United States)

    Sung, Woongmo; Avazbaeva, Zaure; Lee, Jonggwan; Kim, Doseok

    Langmuir monolayer consisting of octadecylamine (C18H37NH2, ODA) was investigated by heterodyne vibrational sum-frequency generation (HD-VSFG) spectroscopy in conjunction with surface pressure-area (π- A) isotherm, and the result was compared with that from cationic-lipid (DPTAP) Langmuir monolayer. In case of ODA monolayer on pure water, both SF intensity of water OH band and the surface pressure were significantly smaller than those of the DPTAP monolayer implying that only small portion of the amine groups (-NH3+ is protonated in the monolayer. In the presence of sodium halides (NaCl and NaI) in the subphase water, it was found that the sign of Imχ (2) of water OH band remained the same as that of the ODA monolayer on pure water, but there was a substantial increase in the SF amplitude. From this, we propose that surface excess of the halide counterions (Cl- and I-) makes the solution condition near the ODA monolayer/water interface more acidic so that ODA molecules in the monolayer are more positively charged, which works to align the water dipoles at the interface.

  19. Photo-induced travelling waves in condensed Langmuir monolayers

    Energy Technology Data Exchange (ETDEWEB)

    Tabe, Y [Yokoyama Nano-Structured Liquid Crystal Project, ERATO, Japan Science and Technology Corporation, 5-9-9 Tokodai, Tsukuba, Ibaraki 300-2635, Japan (Japan); Yamamoto, T [Yokoyama Nano-Structured Liquid Crystal Project, ERATO, Japan Science and Technology Corporation, 5-9-9 Tokodai, Tsukuba, Ibaraki 300-2635, Japan (Japan); Yokoyama, H [Yokoyama Nano-Structured Liquid Crystal Project, ERATO, Japan Science and Technology Corporation, 5-9-9 Tokodai, Tsukuba, Ibaraki 300-2635, Japan (Japan)

    2003-06-01

    We report the detailed properties of photo-induced travelling waves in liquid crystalline Langmuir monolayers composed of azobenzene derivatives. When the monolayer, in which the constituent rodlike molecules are coherently tilted from the layer normal, is weakly illuminated to undergo the trans-cis photo-isomerization, spatio-temporal periodic oscillations of the molecular azimuth begin over the entire excited area and propagate as a two-dimensional orientational wave. The wave formation takes place only when the film is formed at an asymmetric interface with broken up-down symmetry and when the chromophores are continuously excited near the long-wavelength edge of absorption to induce repeated photo-isomerizations between the trans and cis forms. Under proper illumination conditions, Langmuir monolayers composed of a wide variety of azobenzene derivatives have been confirmed to exhibit similar travelling waves with velocity proportional to the excitation power irrespective of the degree of amphiphilicity. The dynamics can be qualitatively explained by the modified reaction-diffusion model proposed by Reigada, Sagues and Mikhailov.

  20. Dynamics of beam-driven Langmuir and ion-acoustic waves including electrostatic decay

    International Nuclear Information System (INIS)

    Li, B.; Willes, A.J.; Robinson, P.A.; Cairns, I.H.

    2003-01-01

    The evolution of Langmuir waves and ion-acoustic waves stimulated by a hot electron beam in an initially homogeneous plasma is investigated numerically in time, position, and wave number space. Quasilinear interactions between the beam particles and Langmuir waves, nonlinear interactions between the Langmuir and ion-acoustic waves through Langmuir decay processes, and spontaneous emission are taken into account in the kinetic theory employed. For illustrative parameters of those in the solar wind near 1 a.u., nonlinear Langmuir decays are observed to transfer the beam-driven Langmuir waves rapidly out of resonance. The scattered Langmuir waves then undergo further decays, moving sequentially toward small wave numbers, until decay is kinematically prohibited. The main features of the evolution of Langmuir and ion-acoustic waves are spatially inhomogeneous. The scattered Langmuir spectra increase and eventually reach or exceed the beam-driven Langmuir spectra at a given spatial location (except in regions where further decays proceed). The ion-acoustic waves are relatively weak and subject to damping at the later stages of their evolution. The development of fine structures in the product Langmuir and ion-acoustic waves are observed, due to depletion of their energy by decay and dominant damping effects, respectively. The propagation of the beam is essentially unaffected by the operation of the decay process. The decay process is thus slaved to the primary beam-plasma evolution, as assumed in previous studies. A variation of the ratio of electron temperature to ion temperature is found to affect not only the ion-acoustic wave levels through effects on the damping rate, but also the dynamics of decay via effects on the decay rate. The latter was not addressed in previous studies. Furthermore, spontaneous emission of ion-acoustic waves is found to affect the dynamics of decay, thus its inclusion is necessary to correctly model the Langmuir and ion-acoustic spectra

  1. Photo-switching of a non-ionic azobenzene amphiphile in Langmuir and Langmuir-Blodgett films.

    Science.gov (United States)

    Piosik, Emilia; Kotkowiak, Michał; Korbecka, Izabela; Galewski, Zbigniew; Martyński, Tomasz

    2017-08-30

    The concept of programmable and reconfigurable soft matter has emerged in science in the last few decades and can be realized by photoisomerization of azobenzene derivatives. This possibility results in great application potential of these compounds in optical storage devices, molecular junctions of electronic devices, command layers of liquid crystal displays or holographic gratings. In this paper, we present the results of a study on the organization and isomerization of the non-ionic and amphiphilic methyl 4-[(E)-2-[4-(nonyloxy)phenyl]diazen-1-yl]benzoate (LCA) in a 2D layer architecture of Langmuir and Langmuir-Blodgett (LB) films supported by spectroscopic studies on LCA chloroform solutions. Our investigation has shown a significantly different molecular organization of LCA depending on the ratio of trans and cis isomers in the monolayers. Taking advantage of a relatively low packing density and aggregation strength in the cis-LCA monolayer, we demonstrated the reversible isomerization in the LB film initially formed of LCA molecules in the cis form, while in the trans-LCA monolayer this effect was not observed. Our approach allows the formation of a switchable monolayer made of the amphiphilic LCA showing liquid crystalline properties without introducing an ionic group into the molecule structure, mixing with another compound or changing the subphase pH to provide free space for the molecules' isomerization.

  2. The Effect of Large Scale Salinity Gradient on Langmuir Turbulence

    Science.gov (United States)

    Fan, Y.; Jarosz, E.; Yu, Z.; Jensen, T.; Sullivan, P. P.; Liang, J.

    2017-12-01

    Langmuir circulation (LC) is believed to be one of the leading order causes of turbulent mixing in the upper ocean. It is important for momentum and heat exchange across the mixed layer (ML) and directly impact the dynamics and thermodynamics in the upper ocean and lower atmosphere including the vertical distributions of chemical, biological, optical, and acoustic properties. Based on Craik and Leibovich (1976) theory, large eddy simulation (LES) models have been developed to simulate LC in the upper ocean, yielding new insights that could not be obtained from field observations and turbulent closure models. Due its high computational cost, LES models are usually limited to small domain sizes and cannot resolve large-scale flows. Furthermore, most LES models used in the LC simulations use periodic boundary conditions in the horizontal direction, which assumes the physical properties (i.e. temperature and salinity) and expected flow patterns in the area of interest are of a periodically repeating nature so that the limited small LES domain is representative for the larger area. Using periodic boundary condition can significantly reduce computational effort in problems, and it is a good assumption for isotropic shear turbulence. However, LC is anisotropic (McWilliams et al 1997) and was observed to be modulated by crosswind tidal currents (Kukulka et al 2011). Using symmetrical domains, idealized LES studies also indicate LC could interact with oceanic fronts (Hamlington et al 2014) and standing internal waves (Chini and Leibovich, 2005). The present study expands our previous LES modeling investigations of Langmuir turbulence to the real ocean conditions with large scale environmental motion that features fresh water inflow into the study region. Large scale gradient forcing is introduced to the NCAR LES model through scale separation analysis. The model is applied to a field observation in the Gulf of Mexico in July, 2016 when the measurement site was impacted by

  3. Behavior of Triple Langmuir Probes in Non-Equilibrium Plasmas

    Science.gov (United States)

    Polzin, Kurt A.; Ratcliffe, Alicia C.

    2018-01-01

    The triple Langmuir probe is an electrostatic probe in which three probe tips collect current when inserted into a plasma. The triple probe differs from a simple single Langmuir probe in the nature of the voltage applied to the probe tips. In the single probe, a swept voltage is applied to the probe tip to acquire a waveform showing the collected current as a function of applied voltage (I-V curve). In a triple probe three probe tips are electrically coupled to each other with constant voltages applied between each of the tips. The voltages are selected such that they would represent three points on the single Langmuir probe I-V curve. Elimination of the voltage sweep makes it possible to measure time-varying plasma properties in transient plasmas. Under the assumption of a Maxwellian plasma, one can determine the time-varying plasma temperature T(sub e)(t) and number density n(sub e)(t) from the applied voltage levels and the time-histories of the collected currents. In the present paper we examine the theory of triple probe operation, specifically focusing on the assumption of a Maxwellian plasma. Triple probe measurements have been widely employed for a number of pulsed and timevarying plasmas, including pulsed plasma thrusters (PPTs), dense plasma focus devices, plasma flows, and fusion experiments. While the equilibrium assumption may be justified for some applications, it is unlikely that it is fully justifiable for all pulsed and time-varying plasmas or for all times during the pulse of a plasma device. To examine a simple non-equilibrium plasma case, we return to basic governing equations of probe current collection and compute the current to the probes for a distribution function consisting of two Maxwellian distributions with different temperatures (the two-temperature Maxwellian). A variation of this method is also employed, where one of the Maxwellians is offset from zero (in velocity space) to add a suprathermal beam of electrons to the tail of the

  4. Langmuir-like waves and radiation in planetary foreshocks

    Science.gov (United States)

    Cairns, Iver H.; Robinson, P. A.; Anderson, R. R.; Gurnett, D. A.; Kurth, W. S.

    1995-01-01

    The basic objectives of this NASA Grant are to develop theoretical understandings (tested with spacecraft data) of the generation and characteristics of electron plasma waves, commonly known as Langmuir-like waves, and associated radiation near f(sub p) and 2f(sub p) in planetary foreshocks. (Here f(sub p) is plasma frequency.) Related waves and radiation in the source regions of interplanetary type III solar radio bursts provide a simpler observational and theoretical context for developing and testing such understandings. Accordingly, applications to type III bursts constitute a significant fraction of the research effort. The testing of the new Stochastic Growth Theory (SGT) for type III bursts, and its extension and testing for foreshock waves and radiation, constitutes a major longterm strategic goal of the research effort.

  5. On bistable states retention in ferroelectric Langmuir-Blodgett films

    Science.gov (United States)

    Geivandov, A. R.; Palto, S. P.; Yudin, S. G.; Fridkin, V. M.; Blinov, L. M.; Ducharme, S.

    2003-08-01

    A new insight into the nature of ferroelectricity is emerging from the study of ultra-thin ferroelectric films prepared of poly(vinylidene fluoride with trifluoroethylene) copolymer using Langmuir-Blodgett (LB) technique. Unique properties of these films indicate the existence of two-dimensional ferroelectricity. The retention of two polarized states in ferroelectric polymer LB films is studied using nonlinear dielectric spectroscopy. The technique is based on phase sensitive measurements of nonlinear dielectric spectroscopy. The amplitude of the current response at the 2nd harmonic of the applied voltage is proportional to the magnitude of the remnant polarization, while its phase gives the sign. We have found that 10 - 20 mm thick LB films can show fast switching time and long retention of the two polarized states. Nevertheless, LB films show a pronounced asymmetry in switching to the opposite states. Possible mechanisms of such behavior are discussed.

  6. Langmuir probe characteristic in a current - carrying magnetized plasma

    International Nuclear Information System (INIS)

    Stanojevic, M.; Cercek, M.; Gyergyek, T.

    1995-01-01

    Experimental investigation of the Langmuir probe characteristic is a magnetized plasma with an electron current along the magnetic field direction shows that the standard procedure for determination of the electron temperature and plasma density, which is applicable in a current - free magnetized plasma, gives erroneous results for these plasma parameters. However, more precise values of the plasma parameters can be calculated from the ion saturation currents and electron temperatures obtained with that procedure for two opposite orientations of the one - sided planar probe collecting surface with respect to the direction of the electron drift. With the existing theoretical models only the order of magnitude of the electron drift velocity can be accurately determined from the measured electron saturation currents for the two probe orientations. (author)

  7. Studies of lipid interactions in mixed Langmuir monolayers

    Energy Technology Data Exchange (ETDEWEB)

    Gzyl-Malcher, Barbara [Department of Physical Chemistry and Electrochemistry, Faculty of Chemistry, Jagiellonian University, Ingardena 3, 30-060 Krakow (Poland)], E-mail: gzyl@chemia.uj.edu.pl; Paluch, Maria [Department of Physical Chemistry and Electrochemistry, Faculty of Chemistry, Jagiellonian University, Ingardena 3, 30-060 Krakow (Poland)

    2008-10-31

    The mixed monolayers of dipalmitoyl phosphatidylcholine (DPPC) with 3-monopalmitoyl glycerol (PG) and palmitic acid 4-methylumbelliferyl ester (4-MU) were compared. Relevant thermodynamic parameters such as excess area ({delta}A{sup E}) and excess free energy of mixing ({delta}G{sub mix}{sup E}) were derived from the surface pressure data obtained from compression measurements performed in a Langmuir trough. Generally, DPPC formed more condensed monolayers with PG and greater negative values of {delta}A{sup E} and {delta}G{sub mix}{sup E} were observed for DPPC/PG system than for DPPC/4-MU one. The positive values of the excess free entropy of mixing ({delta}S{sub mix}{sup E}) were calculated for DPPC/4-MU system at lower temperatures and for DPPC/PG system at higher temperatures.

  8. Langmuir waveforms at interplanetary shocks: STEREO statistical analysis

    Science.gov (United States)

    Briand, C.

    2016-12-01

    Wave-particle interactions and particle acceleration are the two main processes allowing energy dissipation at non collisional shocks. Ion acceleration has been deeply studied for many years, also for their central role in the shock front reformation. Electron dynamics is also important in the shock dynamics through the instabilities they can generate which may impact the ion dynamics.Particle measurements can be efficiently completed by wave measurements to determine the characteristics of the electron beams and study the turbulence of the medium. Electric waveforms obtained from the S/WAVES instrument of the STEREO mission between 2007 to 2014 are analyzed. Thus, clear signature of Langmuir waves are observed on 41 interplanetary shocks. These data enable a statistical analysis and to deduce some characteristics of the electron dynamics on different shocks sources (SIR or ICME) and types (quasi-perpendicular or quasi-parallel). The conversion process between electrostatic to electromagnetic waves has also been tested in several cases.

  9. Collisional damping of Langmuir waves in the collisionless limit

    International Nuclear Information System (INIS)

    Auerbach, S.P.

    1977-01-01

    Linear Langmuir wave damping by collisions is studied in the limit of collision frequency ν approaching zero. In this limit, collisions are negligible, except in a region in velocity space, the boundary layer, centered about the phase velocity. If kappa, the ratio of the collisional equilibration time in the boundary layer to the Landau damping time, is small, the boundary layer width scales as ν/sup 1/3/, and the perturbed distribution function scales as ν/sup -1/3/. The damping rate is thus independent of ν, although essentially all the damping occurs in the collision-dominated boundary layer. Solution of the Fokker--Planck equation shows that the damping rate is precisely the Landau (collisionless) rate. The damping rate is independent of kappa, although the boundary layer thickness is not

  10. Stability of the Tonks–Langmuir discharge pre-sheath

    Energy Technology Data Exchange (ETDEWEB)

    Tskhakaya, D. D. [Fusion@ÖAW, Institute of Applied Physics, TU Wien, Wiedner Hauptstraße 8-10, 1040 Vienna (Austria); Kos, L. [LECAD Laboratory, Faculty of Mechanical Engineering, University of Ljubljana, SI-1000 Ljubljana (Slovenia); Tskhakaya, D. [Fusion@ÖAW, Institute of Applied Physics, TU Wien, Wiedner Hauptstraße 8-10, 1040 Vienna (Austria); Institute for Theoretical Physics, University of Innsbruck, A-6020 Innsbruck (Austria)

    2016-03-15

    The article formulates the stability problem of the plasma sheath in the Tonks–Langmuir discharge. Using the kinetic description of the ion gas, i.e., the stability of the potential shape in the quasi-neutral pre-sheath regarding the high and low frequency, the perturbations are investigated. The electrons are assumed to be Maxwell–Boltzmann distributed. Regarding high-frequency perturbations, the pre-sheath is shown to be stable. The stability problem regarding low-frequency perturbations can be reduced to an analysis of the “diffusion like” equation, which results in the instability of the potential distribution in the pre-sheath. By means of the Particle in Cell simulations, also the nonlinear stage of low frequency oscillations is investigated. Comparing the figure obtained with the figure for linear stage, one can find obvious similarity in the spatial-temporal behavior of the potential.

  11. Two step formation of metal aggregates by surface X-ray radiolysis under Langmuir monolayers: 2D followed by 3D growth

    Directory of Open Access Journals (Sweden)

    Smita Mukherjee

    2015-12-01

    Full Text Available In order to form a nanostructured metallic layer below a Langmuir monolayer, radiolysis synthesis was carried out in an adapted geometry that we call surface X-ray radiolysis. In this procedure, an X-ray beam produced by a synchrotron beamline intercepts the surface of an aqueous metal-ion solution covered by a Langmuir monolayer at an angle of incidence below the critical angle for total internal reflection. Underneath the organic layer, the X-ray beam induces the radiolytic synthesis of a nanostructured metal–organic layer whose ultrathin thickness is defined by the vertical X-ray penetration depth. We have shown that increasing the X-ray flux on the surface, which considerably enhances the kinetics of the silver layer formation, results in a second growth regime of silver nanocrystals. Here the formation of the oriented thin layer is followed by the appearance of a 3D powder of silver clusters.

  12. Estudo de filmes de Langmuir e Langmuir-Blodgett de aminas anfifílicas utilizando a espectroscopia SFG

    OpenAIRE

    Thiers Massami Uehara

    2010-01-01

    O estudo da interação de moléculas orgânicas com a água é de grande importância para diversas áreas das ciências, como por exemplo, na compreensão de sistemas biológicos. Uma elevada diversidade de estudos nesta área já foram realizados, no entanto, alguns aspectos do estudo de filmes finos de aminas anfifílicas não foram satisfatoriamente esclarecidos. Este trabalho aborda filmes de Langmuir de octadecilamina em função do pH e da força iônica de subfases aquosas, investigando a estrutura d...

  13. Langmuir wave turbulence generated by electromagnetic waves in the laboratory and the ionosphere

    International Nuclear Information System (INIS)

    Lee, M.C.; Riddolls, R.J.; Moriarty, D.T.; Dalrymple, N.E.; Rowlands, M.J.

    1996-01-01

    The authors will present some recent results of the laboratory experiments at MIT, using a large plasma device known as the Versatile Toroidal Facility (VTF). These experiments are aimed at cross-checking the ionospheric plasma heating experiments at Arecibo, Puerto Rico using an HF heating facility (heater). The plasma phenomenon under investigation is the spectral characteristic of Langmuir wave turbulence produced by ordinary (o-mode) electromagnetic pump waves. The Langmuir waves excited by o-mode heaters waves at Arecibo have both a frequency-upshifted spectrum and a frequency-downshifted (viz., cascading) spectrum. While the cascading spectrum can be well explained in terms of the parametric decay instability (PDI), the authors have interpreted the frequency-upshifted Langmuir waves to be anti-Stokes Langmuir waves produced by a nonlinear scattering process as follows. Lower hybrid waves creates presumably by lightning-induced whistler waves can scatter nonlinearly the PDI-excited mother langmuir waves, yielding obliquely propagating langmuir waves with frequencies as the summation of the mother Langmuir wave frequencies and the lower hybrid wave frequencies. This suggested process has been confirmed in the laboratory experiments, that can reproduce the characteristic spectra of Langmuir wave turbulence observed in the Arecibo experiments

  14. Relativistic effects on large amplitude nonlinear Langmuir waves in a two-fluid plasma

    International Nuclear Information System (INIS)

    Nejoh, Yasunori

    1994-07-01

    Large amplitude relativistic nonlinear Langmuir waves are analyzed by the pseudo-potential method. The existence conditions for nonlinear Langmuir waves are confirmed by considering relativistic high-speed electrons in a two-fluid plasma. The significant feature of this investigation is that the propagation of nonlinear Langmuir waves depends on the ratio of the electron streaming velocity to the velocity of light, the normalized potential and the ion mass to electron mass ratio. The constant energy is determined by the specific range of the relativistic effect. In the non-relativistic limit, large amplitude relativistic Langmuir waves do not exist. The present investigation predicts new findings of large amplitude nonlinear Langmuir waves in space plasma phenomena in which relativistic electrons are important. (author)

  15. Three-dimensional Langmuir wave instabilities in type III solar radio bursts

    International Nuclear Information System (INIS)

    Bardwell, S.; Goldman, M.V.

    1976-01-01

    Assuming that type III solar radio bursts are associated with electron streams moving at about c/3, Langmuir waves should be strongly excited. We have studied all of the Langmuir-wave linear parametric instabilities excited in cylindrical symmetry by an electron-stream--driven Langmuir wave-pump propagating along the stream axis. Included in this unified homogeneous treatment are induced backscattering off ions, the oscillating two-stream instability, and a new ''stimulated modulational instability,'' previously unconsidered in this context. Near a few solar radii, the latter two deposit Langmuir wave energy into a forward-scattering cone about the stream axis. It is concluded that the linear stage of the forward-scattering instabilities involves transfer of energy to Langmuir waves which remain in resonance with the stream, and therefore probably do not prevent rapid depletion of the electron stream due to quasilinear plateau formation at these distances from the Sun

  16. Concerning the electromagnetic radiation spectrum of a hot plasma with Langmuir turbulence in a magnetic field

    International Nuclear Information System (INIS)

    Tirsky, V.V.; Ledenev, V.G.; Tomozov, V.M.

    2001-01-01

    We consider the process of generation of electromagnetic waves as a consequence of the merging of two Langmuir plasmons. The case of a hot plasma in a magnetic field is investigated. It is shown that under such conditions the frequency of Langmuir plasmons can vary over the range from 0.8 to 1.1 of the Langmuir frequency of electrons. The spectrum and polarization of electromagnetic radiation are analyzed. It is shown that allowance for the thermal motion of plasma particles under the conditions involved permits electromagnetic waves in the range from 1.6 to 2.2 of the Langmuir frequency of electrons to be generated. The degree of circular polarization of the radiation can reach 50% even in the case of an isotropic spectrum of Langmuir turbulence. (orig.)

  17. Numerical Simulations of a Multiscale Model of Stratified Langmuir Circulation

    Science.gov (United States)

    Malecha, Ziemowit; Chini, Gregory; Julien, Keith

    2012-11-01

    Langmuir circulation (LC), a prominent form of wind and surface-wave driven shear turbulence in the ocean surface boundary layer (BL), is commonly modeled using the Craik-Leibovich (CL) equations, a phase-averaged variant of the Navier-Stokes (NS) equations. Although surface-wave filtering renders the CL equations more amenable to simulation than are the instantaneous NS equations, simulations in wide domains, hundreds of times the BL depth, currently earn the ``grand challenge'' designation. To facilitate simulations of LC in such spatially-extended domains, we have derived multiscale CL equations by exploiting the scale separation between submesoscale and BL flows in the upper ocean. The numerical algorithm for simulating this multiscale model resembles super-parameterization schemes used in meteorology, but retains a firm mathematical basis. We have validated our algorithm and here use it to perform multiscale simulations of the interaction between LC and upper ocean density stratification. ZMM, GPC, KJ gratefully acknowledge funding from NSF CMG Award 0934827.

  18. Nonlinear dynamics of resonant electrons interacting with coherent Langmuir waves

    Science.gov (United States)

    Tobita, Miwa; Omura, Yoshiharu

    2018-03-01

    We study the nonlinear dynamics of resonant particles interacting with coherent waves in space plasmas. Magnetospheric plasma waves such as whistler-mode chorus, electromagnetic ion cyclotron waves, and hiss emissions contain coherent wave structures with various discrete frequencies. Although these waves are electromagnetic, their interaction with resonant particles can be approximated by equations of motion for a charged particle in a one-dimensional electrostatic wave. The equations are expressed in the form of nonlinear pendulum equations. We perform test particle simulations of electrons in an electrostatic model with Langmuir waves and a non-oscillatory electric field. We solve equations of motion and study the dynamics of particles with different values of inhomogeneity factor S defined as a ratio of the non-oscillatory electric field intensity to the wave amplitude. The simulation results demonstrate deceleration/acceleration, thermalization, and trapping of particles through resonance with a single wave, two waves, and multiple waves. For two-wave and multiple-wave cases, we describe the wave-particle interaction as either coherent or incoherent based on the probability of nonlinear trapping.

  19. The structure of organic langmuir films on liquid metal surfaces

    International Nuclear Information System (INIS)

    Kraack, H.; Deutsch, M.; Ocko, B.M.; Pershan, P.S.

    2003-01-01

    Langmuir films (LFs) on water have long been studied for their interest for basic science and their numerous applications in chemistry, physics, materials science and biology. We present here A-resolution synchrotron X-ray studies of the structure of stearic acid LFs on a liquid mercury surface. At low coverage, ≥110 A 2 /mol, a 2D gas phase of flat-lying molecules is observed. At high coverage, ≤23 A 2 /mol, two different hexatic phases of standing-up molecules are observed. At intermediate coverage, 52≤A≤110 A 2 /mol, novel single- and double-layered phases of flat-lying molecular dimers are found, exhibiting a 1D in-layer order. Such flat-lying phases were not hitherto observed in any LF. Measurements on LFs of fatty acids of other chain lengths indicate that this structure is generic to chain molecules on mercury, although the existence of some of the flat-lying phases, and the observed phase sequence, depend on the chain length. Organic LFs on Hg, and in particular the new flat-lying phases, should provide a broader nano-structural tunability range for molecular electronic device construction than most solid-supported self-assembled monolayers used at present

  20. Tonks-Langmuir problem for a bi-Maxwellian plasma

    International Nuclear Information System (INIS)

    Godyak, V.A.; Meytlis, V.P.; Strauss, H.R.

    1995-01-01

    An analytical solution of the Tonks-Langmuir (T-L) problem with a bi-Maxwellian electron energy distribution function (EEDF) is obtained for a plasma slab. The solution shows that the ambipolar potential, the plasma density distribution, and the ion flux to the wall are mainly governed by the cold electrons, while the ionization rate and voltage drop across the wall sheath are governed by the hot electrons. The ionization rate by direct electron impact is found to be spatially rather uniform, contrary to the T-L solution where it is proportional to the plasma density distribution. The temperature of hot electrons defined by the ionization balance is found to be close to that of the T-L solution for a mono-Maxwellian EEDF, and is in reasonable agreement with experiments carried out in a low pressure capacitance RF discharge. The energy balance for cold electrons in this discharge shows that their heating by hot electrons via Coulomb interaction is equalized by the cold electrons' escape to the RF electrodes during collapse of the RF sheath

  1. Photopatterning of heterostructured polymer Langmuir-Blodgett films

    International Nuclear Information System (INIS)

    Li Tiesheng; Mitsuishi, Masaya; Miyashita, Tokuji

    2008-01-01

    Heterostructured polymer Langmuir-Blodgett (LB) film prepared by using poly(N-dodecylacrylamide-co-t-butyl 4-vinylphenyl carbonate) (p(DDA-tBVPC53)) and poly(N-neopentyl methacrylamide-co-9-anthrylmethyl methacrylate) (p(nPMA-AMMA10)) polymer LB films which can act as photogenerator layers were investigated. Patterns with a resolution of 0.75 μm were obtained on heterostructured polymer LB films composed of 4 layers of p(nPMA-AMMA10) LB film (top layers) and 40 layers of p(DDA-tBVPC53) LB film (under layers) on a silicon wafer by deep UV irradiation followed by development with 1% tetramethylammonium hydroxide aqueous solution. The sensitivity of the heterostructured polymer LB films was improved without loss of the resolution compared with p(DDA-tBVPC53) LB film. The etch resistance of the heterostructured polymer LB films was sufficiently good to allow patterning of a copper film suitable for photomask fabrication

  2. Langmuir instability in partially spin polarized bounded degenerate plasma

    Science.gov (United States)

    Iqbal, Z.; Jamil, M.; Murtaza, G.

    2018-04-01

    Some new features of waves inside the cylindrical waveguide on employing the separated spin evolution quantum hydrodynamic model are evoked. Primarily, the instability of Langmuir wave due to the electron beam in a partially spin polarized degenerate plasma considering a nano-cylindrical geometry is discussed. Besides, the evolution of a new spin-dependent wave (spin electron acoustic wave) due to electron spin polarization effects in the real wave spectrum is elaborated. Analyzing the growth rate, it is found that in the absence of Bohm potential, the electron spin effects or exchange interaction reduce the growth rate as well as k-domain but the inclusion of Bohm potential increases both the growth rate and k-domain. Further, we investigate the geometry effects expressed by R and pon and find that they have opposite effects on the growth rate and k-domain of the instability. Additionally, how the other parameters like electron beam density or streaming speed of beam electrons influence the growth rate is also investigated. This study may find its applications for the signal analysis in solid state devices at nanoscales.

  3. Magnetic volcanos in gadolinium Langmuir-Blodgett films

    Energy Technology Data Exchange (ETDEWEB)

    Tishin, A.M. E-mail: amt@mailaps.org; Snigirev, O.V.; Khomutov, G.B.; Gudoshnikov, S.A.; Bohr, J

    2001-09-01

    Magnetic, structural and electronic properties of Langmuir-Blodgett films with incorporated Gd{sup 3+} ions has been detected using a scanning DC SQUID microscope, scanning electron microscope and X-ray diffraction. The magnetic images of 28 and 50 layer thick films at 77 K have been obtained after in-plane and out-of-plane pre-magnetization in a field of 1.4 T at 300 K. Randomly placed 'magnetic volcanos' with a remanent magnetic moment of the order of 10{sup -13} A m{sup 2} was observed. A decay of the remanent magnetization with a characteristic time of about 120 h was observed. It is suggested that the magnetic order is relatively long ranged, and that topological defects (vortices) lead to the observed out-of-plane field lines, and are responsible for the magnetic volcanos. Finally, it is hypothesized that a similar topology of field lines is responsible for superconductivity as observed in ceramic high-T{sub C} superconductors.

  4. Study of magnetic materials in Langmuir-Blodgett films

    International Nuclear Information System (INIS)

    Coronel, Philippe

    1990-01-01

    As one of the key issue in molecular electronics is the fabrication of organised systems with specific properties born by molecules, one of these properties being the possibility of information storage, this research thesis reports an exploratory study based on the development of a magnetic complex in a two-dimensional organisation in order to obtain a molecular magnetic memory. For this purpose, the chosen property for the complex was the molecular bi-stability which is a characteristic of magnetic materials which display a spin transition phenomenon. Two types of complex families have been studied: [(Phenanthroline)_2Fe'' (NCS)_2] and [Fe''' (8-quinolyl-salicyl-aldimine)_2](X''). The fabrication of a two-dimensional organised system is performed by using the Langmuir-Blodgett technique. With this technique, three synthesis ways are considered: an in-situ synthesis, a semi-amphiphilic way, and an amphiphilic way. Within this research, the author tried to see whether the existence of 3D (powder) spin transition phenomenon was transposable in 2D (case of a LB film) [fr

  5. Interaction between counter-streaming ion-acoustic solitons and the Langmuir waves

    International Nuclear Information System (INIS)

    Basovich, A.Ya.; Gromov, E.M.; Talanov, V.I.

    1984-01-01

    The interaction between strong counter-streaming ion-acoustic solitons and the Langmuir waves is considered. At first the Langmuir waves spectrum transformation by counter-streaming ion-acoustic solutions of a preset amplitude e has been found. An increase in the frequency and number of the Langmuir waves due to the Doppler effect in the course of multiple reflection from the f front soliton slope has been determined and the wave number range in which the confinement of the Langmuir waves by counter-streaning solitons is possible has s been found. It is shown that the time of the Langmuir wave transformation into the short-wave region under the effect of the counter-streaming soliton may y be short as compared with the time of the Langmuir wave diffusion into the Landau damping region under the effect of random fields of ion-acoustic waves. In the adiabatic fpproximation changes in the counter-streaming ion acoustic parameters of solitons owing to the Langmuir waves have been

  6. High frequency ion sound waves associated with Langmuir waves in type III radio burst source regions

    Directory of Open Access Journals (Sweden)

    G. Thejappa

    2004-01-01

    Full Text Available Short wavelength ion sound waves (2-4kHz are detected in association with the Langmuir waves (~15-30kHz in the source regions of several local type III radio bursts. They are most probably not due to any resonant wave-wave interactions such as the electrostatic decay instability because their wavelengths are much shorter than those of Langmuir waves. The Langmuir waves occur as coherent field structures with peak intensities exceeding the Langmuir collapse thresholds. Their scale sizes are of the order of the wavelength of an ion sound wave. These Langmuir wave field characteristics indicate that the observed short wavelength ion sound waves are most probably generated during the thermalization of the burnt-out cavitons left behind by the Langmuir collapse. Moreover, the peak intensities of the observed short wavelength ion sound waves are comparable to the expected intensities of those ion sound waves radiated by the burnt-out cavitons. However, the speeds of the electron beams derived from the frequency drift of type III radio bursts are too slow to satisfy the needed adiabatic ion approximation. Therefore, some non-linear process such as the induced scattering on thermal ions most probably pumps the beam excited Langmuir waves towards the lower wavenumbers, where the adiabatic ion approximation is justified.

  7. Surface chemistry of lipid raft and amyloid Aβ (1-40) Langmuir monolayer.

    Science.gov (United States)

    Thakur, Garima; Pao, Christine; Micic, Miodrag; Johnson, Sheba; Leblanc, Roger M

    2011-10-15

    Lipid rafts being rich in cholesterol and sphingolipids are considered to provide ordered lipid environment in the neuronal membranes, where it is hypothesized that the cleavage of amyloid precursor protein (APP) to Aβ (1-40) and Aβ (1-42) takes place. It is highly likely that the interaction of lipid raft components like cholesterol, sphingomylein or GM1 leads to nucleation of Aβ and results in aggregation or accumulation of amyloid plaques. One has investigated surface pressure-area isotherms of the lipid raft and Aβ (1-40) Langmuir monolayer. The compression-decompression cycles and the stability of the lipid raft Langmuir monolayer are crucial parameters for the investigation of interaction of Aβ (1-40) with the lipid raft Langmuir monolayer. It was revealed that GM1 provides instability to the lipid raft Langmuir monolayer. Adsorption of Aβ (1-40) onto the lipid raft Langmuir monolayer containing neutral (POPC) or negatively charged phospholipid (DPPG) was examined. The adsorption isotherms revealed that the concentration of cholesterol was important for adsorption of Aβ (1-40) onto the lipid raft Langmuir monolayer containing POPC whereas for the lipid raft Langmuir monolayer containing DPPG:cholesterol or GM1 did not play any role. In situ UV-vis absorption spectroscopy supported the interpretation of results for the adsorption isotherms. Copyright © 2011 Elsevier B.V. All rights reserved.

  8. Langmuir wave phase-mixing in warm electron-positron-dusty plasmas

    Science.gov (United States)

    Pramanik, Sourav; Maity, Chandan

    2018-04-01

    An analytical study on nonlinear evolution of Langmuir waves in warm electron-positron-dusty plasmas is presented. The massive dust grains of either positively or negatively charged are assumed to form a fixed charge neutralizing background. A perturbative analysis of the fluid-Maxwell's equations confirms that the excited Langmuir waves phase-mix and eventually break, even at arbitrarily low amplitudes. It is shown that the nature of the dust-charge as well as the amount of dust grains can significantly influence the Langmuir wave phase-mixing process. The phase-mixing time is also found to increase with the temperature.

  9. Calixarene Langmuir-Blodgett Thin Films For Volatile Organic Compounds

    International Nuclear Information System (INIS)

    Capan, R.

    2010-01-01

    Volatile Organic Compounds (VOC's) such as benzene, toluene, chloroform are chemicals that evaporate easily at room temperature and create many health effects on young children, elderly and a person with heightened sensitivity to chemicals. Concentrations of many VOC's are consistently higher indoors (up to ten times higher) than outdoors because many household products (for example paints, varnishes, many cleaning, disinfecting, cosmetic, degreasing, hobby products etc.) contains VOC's. Some effects of VOC's for human beings can be followed as the eye, nose, and throat irritations; headaches, loss of coordination, nausea; damage to liver, kidneys, and central nervous system. These are big incentives for the development of portable, user-friendly VOC's sensors and for the investigation of the sensing properties of new materials to be prepared as a thin film sensing element. Langmuir-Blodgett (LB) ultra-thin film technique allows us to produce monolayer or multilayer organic thin films that can be used as chemical sensing elements.In this work, materials known as the calix[n]arene are investigated for the production of sensing material against several VOC's such as the chloroform, benzene, ethylbenzene and toluene by using LB thin film techniques. UV-visible, Quartz Crystal Microbalance (QCM) system and Surface Plasmon Resonance (SPR) measurement techniques are used to check the quality of the deposition process onto a solid substrate. Surface morphology and sensing properties of the final sensing layers are then studied by Atomic Force Microscopy (AFM) and SPR techniques. Our results indicated that selected calixarene materials are sensitive enough and quite suitable to fabricate a highly ordered, reproducible and uniform LB film that can be used as a very thin sensing layer against VOC's.

  10. Non linear dynamic of Langmuir and electromagnetic waves in space plasmas; Dinamica nao linear de ondas de Langmuir e eletromagneticas em plasmas espaciais

    Energy Technology Data Exchange (ETDEWEB)

    Guede, Jose Ricardo Abalde

    1995-11-01

    The aim of this work is to study the nonlinear dynamics of Langmuir and electromagnetic waves in space plasmas. Firstly, the generalized Zakharov equations are derived which are used to study the hybrid parametric instability involving the generation of daughter Langmuir, electromagnetic and ion-acoustic waves induced by two counter-propagating Langmuir pump waves with different amplitudes based on a coupled dispersion relation. Secondly, starting from the generalized Zakharov equations the linear and nonlinear coupled mode theories of three-wave and four-wave parametric interactions are developed, respectively. In three-waves processes, a Langmuir wave decays into another Langmuir wave and an ion-acoustic wave (electrostatic parametric decay) or into an electromagnetic wave and an ion-acoustic wave (electromagnetic parametric decay). In four-wave (modulational) processes, the interaction involves two wave triplets: in the decay triplet a pump wave couples with a low-frequency wave to generate a Stokes wave, and in the fusion triplets: in the decay triplet a pump wave couples with a low-frequency wave to generate a Stokes wave, and in the fusion triplet the coupling of a pump wave with a low-frequency wave generate an anti-Stokes wave. These modulational processes are convective and resonant processes wherein the low-frequency modes are Eigenmodes of plasma and are known as the stimulated modulational processes. Four such processes are investigated in this thesis: two with Langmuir pump waves (electrostatic and hybrid stimulated modulation processes) and the other two with electromagnetic pump waves (stimulated modulation Brillouin scattering and electromagnetic stimulated modulation process). Applications of the theoretical results in space plasmas are discussed. In particular, it is shown that the electrostatic and electromagnetic parametric decay processes of Langmuir waves can model the generation and modulation of radio emissions and Langmuir waves in the

  11. The Child-Langmuir law and analytical theory of collisionless to collision-dominated sheaths

    International Nuclear Information System (INIS)

    Benilov, M S

    2009-01-01

    This paper is concerned with summarizing simple analytical models of space-charge sheaths and tracing their relation to the Child-Langmuir model of an ion sheath. The topics discussed include the Child-Langmuir law and model of a collisionless ion sheath, the Mott-Gurney law and model of a collision-dominated ion sheath, the Bohm model of a collisionless ion-electron sheath, the Su-Lam-Cohen model of a collision-dominated ion-electron sheath, ion sheaths with arbitrary collisionality, high-accuracy boundary conditions for the Child-Langmuir and Mott-Gurney models of an ion sheath and the mathematical sense of Child-Langmuir type models of an ion sheath from the point of view of modern theoretical physics.

  12. Electron nonlinearity in the field of powerful Langmuir wave in plasmas

    International Nuclear Information System (INIS)

    Chernousenko, V.M.; Kuklin, V.M.; Panchenko, I.P.; Romenskij, I.V.

    1988-01-01

    The system of equations that determines the dynamics of the development of parametric instability of intensive Langmuir plasma oscillation is obtained for two- and three-dimensional Cartessian geometries. 9 refs

  13. Chiral hierarchical self-assembly in Langmuir monolayers of diacetylenic lipids

    KAUST Repository

    Basnet, Prem B.; Mandal, Pritam; Malcolm, Dominic W.; Mann, Elizabeth; Chaieb, Saharoui

    2013-01-01

    When compressed in the intermediate temperature range below the chain-melting transition yet in the low-pressure liquid phase, Langmuir monolayers made of chiral lipid molecules form hierarchical structures. Using Brewster angle microscopy to reveal

  14. Wheelchair incidents

    NARCIS (Netherlands)

    Drongelen AW van; Roszek B; Hilbers-Modderman ESM; Kallewaard M; Wassenaar C; LGM

    2002-01-01

    This RIVM study was performed to gain insight into wheelchair-related incidents with powered and manual wheelchairs reported to the USA FDA, the British MDA and the Dutch Center for Quality and Usability Research of Technical Aids (KBOH). The data in the databases do not indicate that incidents with

  15. Non linear dynamic of Langmuir and electromagnetic waves in space plasmas

    International Nuclear Information System (INIS)

    Guede, Jose Ricardo Abalde

    1995-11-01

    The aim of this work is to study the nonlinear dynamics of Langmuir and electromagnetic waves in space plasmas. Firstly, the generalized Zakharov equations are derived which are used to study the hybrid parametric instability involving the generation of daughter Langmuir, electromagnetic and ion-acoustic waves induced by two counter-propagating Langmuir pump waves with different amplitudes based on a coupled dispersion relation. Secondly, starting from the generalized Zakharov equations the linear and nonlinear coupled mode theories of three-wave and four-wave parametric interactions are developed, respectively. In three-waves processes, a Langmuir wave decays into another Langmuir wave and an ion-acoustic wave (electrostatic parametric decay) or into an electromagnetic wave and an ion-acoustic wave (electromagnetic parametric decay). In four-wave (modulational) processes, the interaction involves two wave triplets: in the decay triplet a pump wave couples with a low-frequency wave to generate a Stokes wave, and in the fusion triplets: in the decay triplet a pump wave couples with a low-frequency wave to generate a Stokes wave, and in the fusion triplet the coupling of a pump wave with a low-frequency wave generate an anti-Stokes wave. These modulational processes are convective and resonant processes wherein the low-frequency modes are Eigenmodes of plasma and are known as the stimulated modulational processes. Four such processes are investigated in this thesis: two with Langmuir pump waves (electrostatic and hybrid stimulated modulation processes) and the other two with electromagnetic pump waves (stimulated modulation Brillouin scattering and electromagnetic stimulated modulation process). Applications of the theoretical results in space plasmas are discussed. In particular, it is shown that the electrostatic and electromagnetic parametric decay processes of Langmuir waves can model the generation and modulation of radio emissions and Langmuir waves in the

  16. Density determination of langmuir-blodgett monolayer films using x-ray reflectivity technique

    International Nuclear Information System (INIS)

    Damar Yoga Kusuma

    2015-01-01

    Monolayer deposition by Langmuir-Blodgett technique produces monolayer films that are uniform with controllable thickness down to nanometer scale. To evaluate the quality of the monolayer deposition, X-ray reflectivity technique are employed to monitor the monolayers density. Langmuir-Blodgett monolayer with good coverage and uniformity results in film density close to its macroscopic film counterpart whereas films with presence of air gaps shows lower density compared to its macroscopic film counterpart. (author)

  17. Validation of double Langmuir probe in-orbit performance onboard a nano-satellite

    Science.gov (United States)

    Tejumola, Taiwo Raphael; Zarate Segura, Guillermo Wenceslao; Kim, Sangkyun; Khan, Arifur; Cho, Mengu

    2018-03-01

    Many plasma measurement systems have been proposed and used onboard different satellites to characterize space plasma. Most of these systems employed the technique of Langmuir probes either using the single or double probes methods. Recent growth of lean satellites has positioned it on advantage to be used for space science missions using Langmuir probes because of its simplicity and convenience. However, single Langmuir probes are not appropriate to be used on lean satellites because of their limited conducting area which leads to spacecraft charging and drift of the instrument's electrical ground during measurement. Double Langmuir probes technique can overcome this limitation, as a measurement reference in relation to the spacecraft is not required. A double Langmuir probe measurement system was designed and developed at Kyushu Institute of Technology for HORYU-IV satellite, which is a 10 kg, 30 cm cubic class lean satellite launched into Low Earth Orbit on 17th February 2016. This paper presents the on-orbit performance and validation of the double Langmuir probe measurement using actual on-orbit measured data and computer simulations.

  18. Saturation of radiation-induced parametric instabilities by excitation of Langmuir turbulence

    International Nuclear Information System (INIS)

    DuBois, D.F.

    1996-01-01

    Progress made in the last few years in the calculation of the saturation spectra of parametric instabilities which involve Langmuir daughter waves will be reviewed. These instabilities include the ion acoustic decay instability, the two plasmon decay instability (TPDI), and stimulated Raman scattering (SRS). In particular we will emphasize spectral signatures which can be directly compared with experiment. The calculations are based on reduced models of driven Langmuir turbulence. Thomson scattering from hf-induced Langmuir turbulence in the unpreconditioned ionosphere has resulted in detailed agreement between theory and experiment at early times. Strong turbulence signatures dominate in this regime where the weak turbulence approximation fails completely. Recent experimental studies of the TPDI have measured the Fourier spectra of Langmuir waves as well as the angular and frequency spectra of light emitted near 3/2 of the pump frequency again permitting some detailed comparisons with theory. Thomson scattering measurements of the Langmuir wave spectra from SRS are consistent with the saturation by secondary and tertiary decay of the primary SRS Langmuir waves. Scaling laws derived from a local model of SRS saturation are compared with full simulations and recent Nova experiments. (orig.)

  19. Langmuir probe measurements in the TEXTOR tokamak during ALT-I pump limiter experiments

    International Nuclear Information System (INIS)

    Goebel, D.M.; Campbell, G.A.; Conn, R.W.; Leung, W.K.; Dippel, K.H.; Finken, K.H.; Thomas, G.J.; Pontau, A.E.

    1986-04-01

    Langmuir probes have been used to characterize the edge plasma of the TEXTOR tokamak and measure the parameters of the plasma incident on the ALT-I pump limiter during ohmic and ICRH heating. Probes mounted directly on the ALT limiter, and a scanning probe located 90 0 toroidally from the limiter, provide data for the evaluation of pump limiter performance and its effect on the edge plasma. The edge plasma is characterized by density and flux e-folding lengths of about 1.8cm when ALT is the main limiter. These scrape-off lengths do not vary significantly as ALT is moved between the normal 42-46cm minor radii, but increase to over 2.2cm when ALT is inserted to 40cm. The flux to probes at a fixed position in the limiter shadow varies by less than 25% for core density changes of a factor of five. This suggests that the global particle confinement time tau/sub p/, scales as the core density. Estimates from the probes indicate that tau/sub p/ is on the order of the energy confinement time, tau/sub E/. The edge electron temperature, T/sub e/, typically decreases by a factor of two when the core density is raised from 1 to 4 x 10 13 cm -3 . The T/sub e/ profile is essentially flat in the limiter shadow, with values of 10-25 eV depending on the core plasma density and ICRH power. ICRH heating increases the electron temperature and flux in proportion to the coupled power. With ALT as the primary limiter and no direct shadowing, the ion side receives 2 to 3 times the flux of the electron side during both ohmic and ICRH heating. The edge plasma is not directly modified by pump limiter operation, but changes with the core plasma density as particle removal lowers the recycling of neutrals in the boundary

  20. UV-Vis reflection spectroscopy under variable angle incidence at the air-liquid interface.

    Science.gov (United States)

    Roldán-Carmona, Cristina; Rubia-Payá, Carlos; Pérez-Morales, Marta; Martín-Romero, María T; Giner-Casares, Juan J; Camacho, Luis

    2014-03-07

    The UV-Vis reflection spectroscopy (UV-Vis-RS) in situ at the air-liquid interface provides information about tilt and aggregation of chromophores in Langmuir monolayers. This information is particularly important given in most cases the chromophore is located at the polar region of the Langmuir monolayer. This region of the Langmuir monolayers has been hardly accessible by other experimental techniques. In spite of its enormous potential, the application of UV-Vis-RS has been limited mainly to reflection measurements under light normal incidence or at lower incidence angles than the Brewster angle. Remarkably, this technique is quite sensitive to the tilt of the chromophores at values of incidence angles close to or larger than the Brewster angle. Therefore, a novel method to obtain the order parameter of the chromophores at the air-liquid interface by using s- and p-polarized radiation at different incidence angles is proposed. This method allowed for the first time the experimental observation of the two components with different polarization properties of a single UV-Vis band at the air-liquid interface. The method of UV-Vis spectroscopy under variable angle incidence is presented as a new tool for obtaining rich detailed information on Langmuir monolayers.

  1. Incidents analysis

    International Nuclear Information System (INIS)

    Francois, P.

    1996-01-01

    We undertook a study programme at the end of 1991. To start with, we performed some exploratory studies aimed at learning some preliminary lessons on this type of analysis: Assessment of the interest of probabilistic incident analysis; possibility of using PSA scenarios; skills and resources required. At the same time, EPN created a working group whose assignment was to define a new approach for analysis of incidents on NPPs. This working group gave thought to both aspects of Operating Feedback that EPN wished to improve: Analysis of significant incidents; analysis of potential consequences. We took part in the work of this group, and for the second aspects, we proposed a method based on an adaptation of the event-tree method in order to establish a link between existing PSA models and actual incidents. Since PSA provides an exhaustive database of accident scenarios applicable to the two most common types of units in France, they are obviously of interest for this sort of analysis. With this method we performed some incident analyses, and at the same time explores some methods employed abroad, particularly ASP (Accident Sequence Precursor, a method used by the NRC). Early in 1994 EDF began a systematic analysis programme. The first, transient phase will set up methods and an organizational structure. 7 figs

  2. Incidents analysis

    Energy Technology Data Exchange (ETDEWEB)

    Francois, P

    1997-12-31

    We undertook a study programme at the end of 1991. To start with, we performed some exploratory studies aimed at learning some preliminary lessons on this type of analysis: Assessment of the interest of probabilistic incident analysis; possibility of using PSA scenarios; skills and resources required. At the same time, EPN created a working group whose assignment was to define a new approach for analysis of incidents on NPPs. This working group gave thought to both aspects of Operating Feedback that EPN wished to improve: Analysis of significant incidents; analysis of potential consequences. We took part in the work of this group, and for the second aspects, we proposed a method based on an adaptation of the event-tree method in order to establish a link between existing PSA models and actual incidents. Since PSA provides an exhaustive database of accident scenarios applicable to the two most common types of units in France, they are obviously of interest for this sort of analysis. With this method we performed some incident analyses, and at the same time explores some methods employed abroad, particularly ASP (Accident Sequence Precursor, a method used by the NRC). Early in 1994 EDF began a systematic analysis programme. The first, transient phase will set up methods and an organizational structure. 7 figs.

  3. Immbolization of uricase enzyme in Langmuir and Langmuir-Blodgett films of fatty acids: possible use as a uric acid sensor.

    Science.gov (United States)

    Zanon, Nathaly C M; Oliveira, Osvaldo N; Caseli, Luciano

    2012-05-01

    Preserving the enzyme structure in solid films is key for producing various bioelectronic devices, including biosensors, which has normally been performed with nanostructured films that allow for control of molecular architectures. In this paper, we investigate the adsorption of uricase onto Langmuir monolayers of stearic acid (SA), and their transfer to solid supports as Langmuir-Blodgett (LB) films. Structuring of the enzyme in β-sheets was preserved in the form of 1-layer LB film, which was corroborated with a higher catalytic activity than for other uricase-containing LB film architectures where the β-sheets structuring was not preserved. The optimized architecture was also used to detect uric acid within a range covering typical concentrations in the human blood. The approach presented here not only allows for an optimized catalytic activity toward uric acid but also permits one to explain why some film architectures exhibit a superior performance. Copyright © 2011 Elsevier Inc. All rights reserved.

  4. Means to remove electrode contamination effect of Langmuir probe measurement in space

    Energy Technology Data Exchange (ETDEWEB)

    Oyama, K.-I.; Lee, C. H.; Fang, H. K.; Cheng, C. Z. [Plasma and Space Science Center, National Cheng Kung University, No.1 Ta-Hsueh Rd., Tainan 70101, Taiwan (China)

    2012-05-15

    Precaution to remove the serious effect of electrode contamination in Langmuir probe experiments has not been taken in many space measurements because the effect is either not understood or ignored. We stress here that one should pay extra attention to the electrode contamination effect to get accurate and reliable plasma measurements so that the long time effort for sounding rocket/satellite missions does not end in vain or becomes less fruitful. In this paper, we describe two main features of voltage-current characteristic curves associated with the contaminated Langmuir probe, which are predicted from the equivalent circuit model, which we proposed in 1970's. We then show that fast sweeping dc Langmuir probes can give reliable results in the steady state regime. The fast sweeping probe can also give reliable results in transient situations such as satellite moves through plasma bubble in the ionosphere where the electron density drastically changes. This fact was first confirmed in our laboratory experiment.

  5. Statistical Analysis of Langmuir Waves Associated with Type III Radio Bursts: I. Wind Observations

    Directory of Open Access Journals (Sweden)

    Vidojević S.

    2011-12-01

    Full Text Available Interplanetary electron beams are unstable in the solar wind and they generate Langmuir waves at the local plasma frequency or its harmonic. Radio observations of the waves in the range 4-256 kHz, observed in 1994-2010 with the WAVES experiment onboard the WIND spacecraft, are statistically analyzed. A subset of 36 events with Langmuir waves and type III bursts occurring at the same time was selected. After removal of the background, the remaining power spectral density is modeled by the Pearson system of probability distributions (types I, IV and VI. The Stochastic Growth Theory (SGT predicts log-normal distribution for the power spectrum density of the Langmuir waves. Our results indicate that SGT possibly requires further verification.

  6. Nonlinear Raman scattering behavior with Langmuir and sound waves coupling in a homogeneous plasma

    International Nuclear Information System (INIS)

    Bonnaud, G.; Pesme, D.; Pellat, R.

    1990-01-01

    By means of wave-coupling simulations, the typical nonlinear evolution of stimulated Raman scattering (SRS) is investigated in a homogeneous sub-quarter-critical plasma for present-day low laser irradiances and kilo-electron-volt electron temperatures. The decrease of the Langmuir energy observed after the SRS growth is found to be basically the result of the electrostatic decay instability (EDI) onset, which generates a high-amplitude ion-acoustic wave. The resulting strong modulation of the plasma density causes a conversion process that transforms the initial one-wave-vector Langmuir wave driven by SRS into a Bloch wave and induces SRS detuning and larger damping. The conditions involved herein have allowed isolation of these processes from the modulational instability; in addition, the Langmuir collapse is found not to occur owing to the high electron temperature

  7. Thermal and electrothermal sensitivity of polyglutamic acid with incorporated carbocyanine dyes in Langmuir-Blodgett films

    Energy Technology Data Exchange (ETDEWEB)

    Popova, G. [Mendeleyev University of Chemical Technology of Russia, Miusskaya sq., 9, Moscow 125047 (Russian Federation)], E-mail: galina@muctr.edu.ru; Spitsyn, A; Vantsyan, M [Mendeleyev University of Chemical Technology of Russia, Miusskaya sq., 9, Moscow 125047 (Russian Federation); Matveeva, N [Lukin Institute Phys. Problems, Zelenograd (Russian Federation); Yudin, S; Palto, S [Crystallography Institute Rus., Leninsky prosp., 57, 117336 Moscow (Russian Federation)

    2008-03-31

    Light-and electrosensitive carbocyanine dyes were incorporated into polyglutamic acid via covalent and non-covalent bonding. The reversible colour change on heating the Langmuir-Blodgett films of polyaminoacid has been studied by absorption spectroscopy and electroconductivity techniques. Characteristic shifts of the absorption spectrum are explained by formation of aggregates and hydrogen bonds. It was shown that H-aggregates and dimers are formed in Langmuir-Blodgett films; each type of assemblies contributes to the absorption spectrum. At elevated temperatures the ratio between concentrations of monomers, dimers and H-aggregates varies due to a breakdown of a part of aggregates into monomers. The change in molecular polarizability was also noticed. Electroconductivity of Langmuir-Blodgett films is observed in longitudinal and transverse directions. Electrochromic effect is noticed under weak electric current by change from red to colourless with iodine doping.

  8. Ion-sound emission by Langmuir soliton reflected at density barrier

    International Nuclear Information System (INIS)

    El-Ashry, M.Y.

    1989-07-01

    The emission of ion-sound waves by an accelerated Langmuir soliton is studied. The acceleration of the soliton is due to an inhomogeneous density barrier. On the assumption that the kinetic energy of the Langmuir soliton is smaller than the potential energy created by the barrier. The basic equations describing the dynamic behaviour of the soliton and the emission of the ion-sound waves are formulated. The qualitative spatial distributions of the perturbed concentration in the ion-sound waves are analyzed at different characteristic points of the soliton. The energy lost by the soliton, as a result of the emission, is estimated. (author). 6 refs, 4 figs

  9. Development of pop-up Langmuir probe system for the JET MkIIa divertor

    International Nuclear Information System (INIS)

    Davies, S.J.; Tellier, X.; Matthews, G.F.; Wilson, C.H.

    1999-01-01

    The successful operation of a pop-up Langmuir probe system, which was installed in the JET MkIIa divertor, is described. The system utilises the ambient magnetic field in tokamak plasmas to act on a current carrying coil and pop up a rail containing Langmuir probes. Measurements were made using pin-plate probes which, owing to their relatively large exposed area, are ideally suited for use with such a system. Details of the design, testing, measurements and potential applications of JET's pop-up system are given. (orig.)

  10. Development of 'popup' Langmuir probe system for the JET MkIIa divertor

    International Nuclear Information System (INIS)

    Davies, S.; Tellier, X.; Matthews, G.

    1999-01-01

    The successful operation of a 'popup' Langmuir probe system, which was installed in the JET MkIIa divertor, is described. The system utilises the ambient magnetic field in tokamak plasmas to act on a current carrying coil and pop up a rail containing Langmuir probes. Measurements were made using 'Pin-Plate' probes which, owing to their relatively large exposed area, are ideally suited for use with such a system. Details of the design, testing, measurements and potential applications of JET's 'popup' system are given. (author)

  11. Ion source plasma parameters measurement based on Langmuir probe with commercial frequency sweep

    International Nuclear Information System (INIS)

    Xie, Y.H.; Hu, C.D.; Liu, S.; Shong, S.H.; Jiang, C.C.; Liu, Z.M.

    2010-01-01

    Langmuir probe is one of the main diagnostic tools to measure the plasma parameters in the ion source. In this article, the commercial frequency power, which is sine wave of 50 Hz, was supplied on the Langmuir probe to measure the plasma parameters. The best feature of this probe sweep voltage is that it does not need extra design. The probe I-V characteristic curve can be got in less than 5 ms and the plasma parameters, the electron temperature and the electron density, varying with the time can be got in one plasma discharge of 400 ms.

  12. Linear mode conversion of Langmuir/z-mode waves to radiation: Scalings of conversion efficiencies and propagation angles with temperature and magnetic field orientation

    International Nuclear Information System (INIS)

    Schleyer, F.; Cairns, Iver H.; Kim, E.-H.

    2013-01-01

    Linear mode conversion (LMC) is the linear transfer of energy from one wave mode to another in an inhomogeneous plasma. It is relevant to laboratory plasmas and multiple solar system radio emissions, such as continuum radiation from planetary magnetospheres and type II and III radio bursts from the solar corona and solar wind. This paper simulates LMC of waves defined by warm, magnetized fluid theory, specifically the conversion of Langmuir/z-mode waves to electromagnetic (EM) radiation. The primary focus is the calculation of the energy and power conversion efficiencies for LMC as functions of the angle of incidence θ of the Langmuir/z-mode wave, temperature β=T e /m e c 2 , adiabatic index γ, and orientation angle φ between the ambient density gradient ∇N 0 and ambient magnetic field B 0 in a warm, unmagnetized plasma. The ratio of these efficiencies is found to agree well as a function of θ, γ, and β with an analytical relation that depends on the group speeds of the Langmuir/z and EM wave modes. The results demonstrate that the energy conversion efficiency ε is strongly dependent on γβ, φ and θ, with ε∝(γβ) 1/2 and θ∝(γβ) 1/2 . The power conversion efficiency ε p , on the other hand, is independent of γβ but does vary significantly with θ and φ. The efficiencies are shown to be maximum for approximately perpendicular density gradients (φ≈90°) and minimal for parallel orientation (φ=0°) and both the energy and power conversion efficiencies peak at the same θ.

  13. Statistical properties of small-amplitude Langmuir waves in the Earth’s electron foreshock

    Czech Academy of Sciences Publication Activity Database

    Musatenko, K.; Lobzin, V.; Souček, Jan; Krasnoselskikh, V. V.; Décréau, P.

    2007-01-01

    Roč. 55, č. 15 (2007), s. 2273-2280 ISSN 0032-0633 Institutional research plan: CEZ:AV0Z30420517 Keywords : Langmuir waves * Electron foreshock * Density inhomogeneities * Probability density functions * Beam-plasma instability * Plasma waves * Kinetic waves and instabilities Subject RIV: BL - Plasma and Gas Discharge Physics Impact factor: 1.842, year: 2007

  14. Generalization of the Child-Langmuir law for nonzero injection velocities in a planar diode

    International Nuclear Information System (INIS)

    Puri, R.R.; Biswas, Debabrata; Kumar, Raghwendra

    2004-01-01

    The Child-Langmuir law relates the voltage applied across a planar diode to the saturation value J CL of current density that can be transmitted through it in case the injection velocity of electrons is zero. The Child-Langmuir current density J CL is, at the same time: (i) the maximum current density that can be transmitted through a planar diode, (ii) the current density below which the flow is steady and unidirectional in the long time limit, and (iii) the average transmitted current density for any value of injected current density above J CL . Existing generalizations of Child-Langmuir law to nonzero velocities of injection are based on the characteristics (i) and (ii) of J CL . This paper generalizes the law to nonzero velocities of injection based on the characteristic (iii) by deriving an analytical expression for the saturation value of current density. The analytical expression for the saturation current density is found to be well supported by numerical computations. A reason behind preferring the saturation property of the Child-Langmuir current density as the basis for its generalization is the importance of that property in numerical simulations of high current diode devices

  15. Development of Langmuir probe diagnostic system for 13.56 MHz plasma sources

    International Nuclear Information System (INIS)

    Ranjini, K.; Nabhiraj, P.Y.; Mallik, C.; Bhandari, R.K.

    2006-01-01

    A work on development of high brightness ion source has been started recently. Plasma parameters are strongly linked to the brightness of the ion beams produced from the ion sources. A self compensated Langmuir probe and related automation system for the measurement of plasma parameters is developed. This paper describes design of the probe, software, hardware and the results. (author)

  16. Langmuir- Blodgett layers of amphiphilic molecules investigated by Atomic Force Microscopy

    NARCIS (Netherlands)

    Zdravkova, Aneliya Nikolova

    2007-01-01

    Langmuir - Blodgett technique and Atomic Force Microscopy were used to study the phase behaviour of organic molecules (fatty alcohols and monoacid saturated triglycerides) at air-water and air-solid interfaces. The structure of binary mixed LB monolayers of fatty alcohols was reported. The

  17. Saturation of radiation-induced parametric instabilities by excitation of Langmuir turbulence

    Energy Technology Data Exchange (ETDEWEB)

    Dubois, D.F.; Rose, H.A. [Los Alamos National Lab., NM (United States); Russell, D. [Lodestar Research Inc., Boulder, CO (United States)

    1995-12-01

    Progress made in the last few years in the calculation of the saturation spectra of parametric instabilities which involve Langmuir daughter waves will be reviewed. These instabilities include the ion acoustic decay instability, the two plasmon decay instability (TPDI), and stimulated Raman scattering (SRS). In particular I will emphasize spectral signatures which can be directly compared with experiment. The calculations are based on reduced models of driven Laugmuir turbulence. Thomson scattering from hf-induced Langmuir turbulence in the unpreconditioned ionosphere has resulted in detailed agreement between theory and experiment at early times. Strong turbulence signatures dominate in this regime where the weak turbulence approximation fails completely. Recent experimental studies of the TPDI have measured the Fourier spectra of Langmuir waves as well as the angular and frequency, spectra of light emitted near 3/2 of the pump frequency again permitting some detailed comparisons with theory. The experiments on SRS are less detailed but by Thomson scattering the secondary decay of the daughter Langmuir wave has been observed. Scaling laws derived from a local model of SRS saturation are compared with full simulations and recent Nova experiments.

  18. When Langmuir is too simple: H-2 dissociation on Pd(111) at high coverage

    DEFF Research Database (Denmark)

    Lopez, Nuria; Lodziana, Zbigniew; Illas, F.

    2004-01-01

    Recent experiments of H-2 adsorption on Pd(111) [T. Mitsui et al., Nature (London) 422, 705 (2003)] have questioned the classical Langmuir picture of second order adsorption kinetics at high surface coverage requiring pairs of empty sites for the dissociative chemisorption. Experiments find that ...

  19. The effect of gauche molecular conformations on the phase diagram of a Langmuir monolayer

    NARCIS (Netherlands)

    Zangi, R; Rice, SA

    2003-01-01

    Experimental and simulation studies have shown that the gauche conformational degrees of freedom of long-chain amphiphile molecules assembled in a dense Langmuir monolayer play an important role in determining the structures of the several phases that the monolayer supports. Nevertheless, for

  20. Oxidative coupling polymerization in a Langmuir monolayer of octadecyl 3,5-diaminobenzoate

    NARCIS (Netherlands)

    Kimkes, P.; Sohling, U.; Oostergetel, G.T.; Schouten, A.J.

    1996-01-01

    In a Langmuir monolayer of the surface active monomer octadecyl 3,5-diaminobenzoate (ODDB), stabilized at a surface pressure of 10 mN/m and a temperature of 23.7 degrees C at the air-water interface, oxidative coupling polymerization occurs when copper(II) chloride was added or already was present

  1. Langmuir probe measurement of the bismuth plasma plume formed by an extreme-ultraviolet pulsed laser

    Czech Academy of Sciences Publication Activity Database

    Pira, P.; Burian, T.; Kolpaková, A.; Tichý, M.; Kudrna, P.; Daniš, S.; Juha, Libor; Lančok, Ján; Vyšín, Luděk; Civiš, Svatopluk; Zelinger, Zdeněk; Kubát, Pavel; Wild, J.

    2014-01-01

    Roč. 47, č. 40 (2014), 1-6 ISSN 0022-3727 R&D Projects: GA ČR(CZ) GAP108/11/1312 Institutional support: RVO:68378271 ; RVO:61388955 Keywords : XUV laser * pulsed laser deposition * Langmuir probe * plasma plume Subject RIV: BL - Plasma and Gas Discharge Physics Impact factor: 2.721, year: 2014

  2. Molecular structure of dipalmitoylphospatidylcholine Langmuir-Blodgett monolayers studied by atomic force microscopy.

    NARCIS (Netherlands)

    Zhai, X.; Kleijn, J.M.

    1997-01-01

    Monolayers of dipalmitoylphosphatidylcholine (DPPC) on the air-water interface have been transferred at various surface pressures onto quartz substrates using the Langmuir-Blodgett (LB) technique. The topography of these layers, on a molecular scale, has been examined by atomic force microscopy

  3. Structure of Langmuir and electromagnetic collapsing wave packets in two-dimensional strong plasma turbulence

    International Nuclear Information System (INIS)

    Alinejad, H.; Robinson, P. A.; Cairns, I. H.; Skjaeraasen, O.; Sobhanian, S.

    2007-01-01

    Nucleating and collapsing wave packets relevant to electromagnetic strong plasma turbulence are studied theoretically in two dimensions. Model collapsing Langmuir and transverse potentials are constructed as superpositions of approximate eigenstates of a spherically symmetric density well. Electrostatic and electromagnetic potentials containing only components with azimuthal quantum numbers m=0, 1, 2 are found to give a good representation of the electric fields of nucleating collapsing wave packets in turbulence simulations. The length scales of these trapped states are related to the electron thermal speed v e and the length scale of the density well. It is shown analytically that the electromagnetic trapped states change with v e and that for v e e > or approx. 0.17c, the Langmuir and transverse modes remain coupled during collapse, with autocorrelation lengths in a constant ratio. An investigation of energy transfer to packets localized in density wells shows that the strongest power transfer to the nucleating state occurs for Langmuir waves. Energy transitions between different trapped and free states for collapsing wave packets are studied, and the transition rate from trapped Langmuir to free plane electromagnetic waves is calculated and related to the emission of electromagnetic waves at the plasma frequency

  4. Extracting surface diffusion coefficients from batch adsorption measurement data: application of the classic Langmuir kinetics model.

    Science.gov (United States)

    Chu, Khim Hoong

    2017-11-09

    Surface diffusion coefficients may be estimated by fitting solutions of a diffusion model to batch kinetic data. For non-linear systems, a numerical solution of the diffusion model's governing equations is generally required. We report here the application of the classic Langmuir kinetics model to extract surface diffusion coefficients from batch kinetic data. The use of the Langmuir kinetics model in lieu of the conventional surface diffusion model allows derivation of an analytical expression. The parameter estimation procedure requires determining the Langmuir rate coefficient from which the pertinent surface diffusion coefficient is calculated. Surface diffusion coefficients within the 10 -9 to 10 -6  cm 2 /s range obtained by fitting the Langmuir kinetics model to experimental kinetic data taken from the literature are found to be consistent with the corresponding values obtained from the traditional surface diffusion model. The virtue of this simplified parameter estimation method is that it reduces the computational complexity as the analytical expression involves only an algebraic equation in closed form which is easily evaluated by spreadsheet computation.

  5. The Langmuir isotherm and the standard model of ion-assisted etching

    International Nuclear Information System (INIS)

    Lieberman, M A

    2009-01-01

    Langmuir is lured to the General Electric Research Laboratory, where he creates a new science-surface chemistry-and christens another-plasma. His atomistic views of gas-surface interactions are extended 65 years later to describe ion-assisted plasma etching, an indispensable process in modern semiconductor device manufacturing.

  6. Properties of excited singular states of the anthraquinone dye in the Langmuir-Blodgett films

    International Nuclear Information System (INIS)

    Baratova, A.A.; Ibraev, N.Kh.

    2004-01-01

    The spectral luminescence properties of the anthraquinone dye solution and the Langmuir-Blodgett films have been investigated. The nature of the absorption centers is determined from the spectral characteristics. The conclusion about probable spatial configuration of the dye molecule in the dye molecule in monolayer on water surface is made. (author)

  7. Ion currents to cylindrical Langmuir probes for finite ion temperature values: Theory

    International Nuclear Information System (INIS)

    Ballesteros, J.; Palop, J.I.F.; Colomer, V.; Hernandez, M.A.

    1995-01-01

    As it is known, the experimental ion currents to a cylindrical Langmuir probe fit quite well to the radial motion theory, developed by Allen, Boyd and Reynolds (ABR Model) and generalized by Chen for the cylindrical probe case. In this paper, we are going to develop a generalization of the ABR theory, taking into account the influence of a finite ion temperature value

  8. Phase behaviour in binary mixed Langmuir-Blodgett monolayers of triglycerides

    NARCIS (Netherlands)

    Zdravkova, A.N.; van der Eerden, J.P.J.M.

    2007-01-01

    Binary mixed monolayers of the triglycerides (TAGs)-tripalmitin (PPP), tristearin (SSS) and triarachidin (AAA) at the air–water interface are investigated with the Langmuir method. Langmuir–Blodgett (LB) layers obtained by deposition on mica are investigated by Atomic Force Microscopy. Combining

  9. Comment on ''On the upconversion of ion sound to Langmuir turbulence,'' By L. Vlahos and K. Papadopoulos

    International Nuclear Information System (INIS)

    Kuijpers, J.

    1980-01-01

    It is shown that the production of Langmuir waves from ion sound by the turbulent Bremsstrahlung mechanism can be more effective than the destruction of the Langmuir waves by the Dawson-Oberman resistivity. Previous conclusions to the contrary are in error owing to the neglect of the wave-number dependence of the ion-sound waves

  10. Chain length dependence of the helix orientation in Langmuir-Blodgett monolayers of alpha-helical diblock copolypeptides

    NARCIS (Netherlands)

    Nguyen, Le-Thu T.; Ardana, Aditya; Vorenkamp, Eltjo J.; ten Brinke, Gerrit; Schouten, Arend J.

    2010-01-01

    The effect of chain length on the helix orientation of alpha-helical diblock copolypeptides in Langmuir and Langmuir-Blodgett monolayers is reported for the first time. Amphiphilic diblock copolypeptides (PLGA-b-PMLGSLGs) of poly(alpha-L-glutamic acid) (PLGA) and

  11. Accounting for Debye sheath expansion for proud Langmuir probes in magnetic confinement fusion plasmas.

    Science.gov (United States)

    Tsui, C K; Boedo, J A; Stangeby, P C

    2018-01-01

    A Child-Langmuir law-based method for accounting for Debye sheath expansion while fitting the current-voltage I-V characteristic of proud Langmuir probes (electrodes that extend into the volume of the plasma) is described. For Langmuir probes of a typical size used in tokamak plasmas, these new estimates of electron temperature and ion saturation current density values decreased by up to 60% compared to methods that did not account for sheath expansion. Changes to the collection area are modeled using the Child-Langmuir law and effective expansion perimeter l p , and the model is thus referred to as the "perimeter sheath expansion method." l p is determined solely from electrode geometry, so the method may be employed without prior measurement of the magnitude of the sheath expansion effects for a given Langmuir probe and can be used for electrodes of different geometries. This method correctly predicts the non-saturating ΔI/ΔV slope for cold, low-density plasmas where sheath-expansion effects are strong, as well as for hot plasmas where ΔI/ΔV ∼ 0, though it is shown that the sheath can still significantly affect the collection area in these hot conditions. The perimeter sheath expansion method has several advantages compared to methods where the non-saturating current is fitted: (1) It is more resilient to scatter in the I-V characteristics observed in turbulent plasmas. (2) It is able to separate the contributions to the ΔI/ΔV slope from sheath expansion to that of the high energy electron tail in high Te conditions. (3) It calculates the change in the collection area due to the Debye sheath for conditions where ΔI/ΔV ∼ 0 and for V = V f .

  12. Numerical test of a weak turbulence approximation for an electromagnetically driven Langmuir turbulence

    International Nuclear Information System (INIS)

    Hanssen, A.; Mjolhus, E.

    1993-01-01

    In ionospheric radio modification experiments, manifestations of excited Langmuir turbulence are observed by means of VHF or UHF radars. Such experiments are performed in Arecibo, Puerto Rico, and at Tromso, Northern Norway. A weak turbulence theory involving parametric cascade of Langmuir waves, has earlier dominated the theoretical understanding of these experiments. This has recently been challenged, both from a theoretical and an experimental point of view, and a theory of strong Langmuir turbulence, involving a large number of nucleation collapse burnout cycles has been advocated. A version of the Zakharov model including damping and parametric driving, contains both of these scenarios, the crucial parameter being ΔΩ = ω-ω pe where ω is the applied frequency and ω pe the plasma frequency. This model allows the construction of a weak turbulence wave kinetic equation. In the present work spectra obtained from full wave solutions of the one dimensional Zakharov model are compared with saturation spectra of the wave kinetic model. The results can be described as follows: (i) for large values of ΔΩ, cascades are formed, and the number of cascades increases with the strength of the driver E 0 ; (ii) the number of cascades found in the full wave solution is smaller than that obtained from the wave kinetic equation; (iii) when E 0 becomes sufficiently large, the narrowly peaked cascade structure of the full wave spectrum breaks down, and a broad spectrum comes instead; (iv) this breakdown comes far before the cascade sequence has reached the Langmuir condensate; thus the Langmuir condensate plays no role in this process. At smaller values of ΔΩ, the turbulence is characterized by caviton nucleation resulting in broad wave number spectra. Also a coexistence range is found at intermediate values of ΔΩ, in which a few cascade lines ride upon a broad cavitation type spectrum

  13. Statistical behavior of foreshock Langmuir waves observed by the Cluster wideband data plasma wave receiver

    Directory of Open Access Journals (Sweden)

    K. Sigsbee

    2004-07-01

    Full Text Available We present the statistics of Langmuir wave amplitudes in the Earth's foreshock using Cluster Wideband Data (WBD Plasma Wave Receiver electric field waveforms from spacecraft 2, 3 and 4 on 26 March 2002. The largest amplitude Langmuir waves were observed by Cluster near the boundary between the foreshock and solar wind, in agreement with earlier studies. The characteristics of the waves were similar for all three spacecraft, suggesting that variations in foreshock structure must occur on scales greater than the 50-100km spacecraft separations. The electric field amplitude probability distributions constructed using waveforms from the Cluster WBD Plasma Wave Receiver generally followed the log-normal statistics predicted by stochastic growth theory for the event studied. Comparison with WBD receiver data from 17 February 2002, when spacecraft 4 was set in a special manual gain mode, suggests non-optimal auto-ranging of the instrument may have had some influence on the statistics.

  14. Thermal and Driven Stochastic Growth of Langmuir Waves in the Solar Wind and Earth's Foreshock

    Science.gov (United States)

    Cairns, Iver H.; Robinson, P. A.; Anderson, R. R.

    2000-01-01

    Statistical distributions of Langmuir wave fields in the solar wind and the edge of Earth's foreshock are analyzed and compared with predictions for stochastic growth theory (SGT). SGT quantitatively explains the solar wind, edge, and deep foreshock data as pure thermal waves, driven thermal waves subject to net linear growth and stochastic effects, and as waves in a pure SGT state, respectively, plus radiation near the plasma frequency f(sub p). These changes are interpreted in terms of spatial variations in the beam instability's growth rate and evolution toward a pure SGT state. SGT analyses of field distributions are shown to provide a viable alternative to thermal noise spectroscopy for wave instruments with coarse frequency resolution, and to separate f(sub p) radiation from Langmuir waves.

  15. Determining the wavelength of Langmuir wave packets at the Earth's bow shock

    Directory of Open Access Journals (Sweden)

    V. V. Krasnoselskikh

    2011-03-01

    Full Text Available The propagation of Langmuir waves in plasmas is known to be sensitive to density fluctuations. Such fluctuations may lead to the coexistence of wave pairs that have almost opposite wave-numbers in the vicinity of their reflection points. Using high frequency electric field measurements from the WIND satellite, we determine for the first time the wavelength of intense Langmuir wave packets that are generated upstream of the Earth's electron foreshock by energetic electron beams. Surprisingly, the wavelength is found to be 2 to 3 times larger than the value expected from standard theory. These values are consistent with the presence of strong inhomogeneities in the solar wind plasma rather than with the effect of weak beam instabilities.

  16. Statistical behavior of foreshock Langmuir waves observed by the Cluster wideband data plasma wave receiver

    Directory of Open Access Journals (Sweden)

    K. Sigsbee

    2004-07-01

    Full Text Available We present the statistics of Langmuir wave amplitudes in the Earth's foreshock using Cluster Wideband Data (WBD Plasma Wave Receiver electric field waveforms from spacecraft 2, 3 and 4 on 26 March 2002. The largest amplitude Langmuir waves were observed by Cluster near the boundary between the foreshock and solar wind, in agreement with earlier studies. The characteristics of the waves were similar for all three spacecraft, suggesting that variations in foreshock structure must occur on scales greater than the 50-100km spacecraft separations. The electric field amplitude probability distributions constructed using waveforms from the Cluster WBD Plasma Wave Receiver generally followed the log-normal statistics predicted by stochastic growth theory for the event studied. Comparison with WBD receiver data from 17 February 2002, when spacecraft 4 was set in a special manual gain mode, suggests non-optimal auto-ranging of the instrument may have had some influence on the statistics.

  17. Langmuir wave-packet generation from an electron beam propagating in the inhomogeneous solar wind

    International Nuclear Information System (INIS)

    Zaslavsky, A.; Maksimovic, M.; Volokitin, A. S.; Krasnoselskikh, V. V.; Bale, S. D.

    2010-01-01

    Recent in-situ observations by the TDS instrument equipping the STEREO spacecraft revealed that large amplitude spatially localized Langmuir waves are frequent in the solar wind, and correlated with the presence of suprathermal electron beams during type III events or close to the electron foreshock. We briefly present the new theoretical model used to perform the study of these localized electrostatic waves, and show first results of simulations of the destabilization of Langmuir waves by a beam propagating in the inhomogeneous solar wind. The main results are that the destabilized waves are mainly focalized near the minima of the density profiles, and that the nonlinear interaction of the waves with the resonant particles enhances this focalization compared to a situation in which the only propagation effects are taken into account.

  18. A new Langmuir probe concept for rapid sampling of space plasma electron density

    International Nuclear Information System (INIS)

    Jacobsen, K S; Pedersen, A; Moen, J I; Bekkeng, T A

    2010-01-01

    In this paper we describe a new Langmuir probe concept that was invented for the in situ investigation of HF radar backscatter irregularities, with the capability to measure absolute electron density at a resolution sufficient to resolve the finest conceivable structure in an ionospheric plasma. The instrument consists of two or more fixed-bias cylindrical Langmuir probes whose radius is small compared to the Debye length. With this configuration, it is possible to acquire absolute electron density measurements independent of electron temperature and rocket/satellite potential. The system was flown on the ICI-2 sounding rocket to investigate the plasma irregularities which cause HF backscatter. It had a sampling rate of more than 5 kHz and successfully measured structures down to the scale of one electron gyro radius. The system can easily be adapted for any ionospheric rocket or satellite, and provides high-quality measurements of electron density at any desired resolution

  19. ANTENNA RADIATION NEAR THE LOCAL PLASMA FREQUENCY BY LANGMUIR WAVE EIGENMODES

    International Nuclear Information System (INIS)

    Malaspina, David M.; Cairns, Iver H.; Ergun, Robert E.

    2012-01-01

    Langmuir waves (LWs) in the solar wind are generated by electron beams associated with solar flares, interplanetary shock fronts, planetary bow shocks, and magnetic holes. In principle, LWs localized as eigenmodes of density fluctuations can emit electromagnetic (EM) radiation by an antenna mechanism near the local plasma frequency f p and twice the local plasma frequency. In this work, analytic expressions are derived for the radiated electric and magnetic fields and power generated near f p by LW eigenmodes. The EM wave power emitted near f p is predicted as a function of the eigenmode length scale L, maximum electric field, driving electron beam speed, and the ambient plasma density and temperature. The escape to a distant observer of f p radiation from a localized Langmuir eigenmode is also briefly explored as a function of the plasma conditions.

  20. Nanoparticle Langmuir-Blodgett Arrays for Sensing of CO and NO2 Gases

    Science.gov (United States)

    Luby, Stefan; Jergel, Matej; Majkova, Eva; Siffalovic, Peter; Chitu, Livia; Rella, Roberto; Manera, Maria Grazia; Caricato, Anna-Paola; Luches, Armando; Martino, Maurizio

    Metal oxide sensors with active Fe2O3 and CoFe2O4 nanoparticle arrays were studied. Sensing nanoparticle films from 1, 2, 4 or 7 monolayers were deposited by Langmuir-Blodgett technique. Sensors are formed on the alumina substrates equipped with heating meander. Langmuir-Blodgett layers were heated or UV irradiated to remove the insulating surfactant. Sensing properties were studied towards CO or NO2 gases in concentrations between 0.5 and 100 ppm in mixture with the dry air. Best response values Igas/Iair were obtained with CoFe2O4 device being 3 for 100 ppm of CO and with Fe2O3 device being (38)-1 for 0.5 ppm of NO2.

  1. Biasing, acquisition, and interpretation of a dense Langmuir probe array in NSTX

    Energy Technology Data Exchange (ETDEWEB)

    Jaworski, M. A.; Kallman, J.; Kaita, R.; Kugel, H.; LeBlanc, B.; Marsala, R. [Princeton Plasma Physics Laboratory, Princeton, New Jersey 08543 (United States); Ruzic, D. N. [Department of Nuclear, Plasma, and Radiological Engineering, University of Illinois at Urbana-Champaign, Urbana, Illinois 60181 (United States)

    2010-10-15

    A dense array of 99 Langmuir probes has been installed in the lower divertor region of the National Spherical Torus Experiment (NSTX). This array is instrumented with a system of electronics that allows flexibility in the choice of probes to bias as well as the type of measurement (including standard swept, single probe, triple probe, and operation as passive floating potential and scrape-off-layer SOL current monitors). The use of flush-mounted probes requires careful interpretation. The time dependent nature of the SOL makes swept-probe traces difficult to interpret. To overcome these challenges, the single- and triple-Langmuir probe signals are used in complementary fashion to determine the temperature and density at the probe location. A comparison to midplane measurements is made.

  2. Chiral hierarchical self-assembly in Langmuir monolayers of diacetylenic lipids

    KAUST Repository

    Basnet, Prem B.

    2013-01-01

    When compressed in the intermediate temperature range below the chain-melting transition yet in the low-pressure liquid phase, Langmuir monolayers made of chiral lipid molecules form hierarchical structures. Using Brewster angle microscopy to reveal this structure, we found that as the liquid monolayer is compressed, an optically anisotropic condensed phase nucleates in the form of long, thin claws. These claws pack closely to form stripes. This appears to be a new mechanism for forming stripes in Langmuir monolayers. In the lower temperature range, these stripes arrange into spirals within overall circular domains, while near the chain-melting transition, the stripes arrange into target patterns. We attributed this transition to a change in boundary conditions at the core of the largest-scale circular domains. © 2013 The Royal Society of Chemistry.

  3. Experimental investigation of the creation of a fire-rod by Langmuir and emissive probes

    International Nuclear Information System (INIS)

    Gyergyek, T.; Cercek, M.

    2000-01-01

    Positive voltage steps are applied to a plane electrode immersed in a weakly magnetized discharge plasma column with its surface perpendicular to the magnetic field lines. Steps of different amplitude are applied at various neutral gas pressures. If the amplitude of the voltage step and the gas pressure are high enough, additional discharge occurs in front of the anode and a fire-rod is created. In this work time development of the electron distribution function is measured using Langmuir and emissive probes. The formation of the anode plasma electron population is followed on the derivatives of the probe characteristics. Results obtained by Langmuir and emissive probes are compared and are found to be in good agreement. (author)

  4. Biasing, Acquisition and Interpretation of a Dense Langmuir Probe Array in NSTX

    International Nuclear Information System (INIS)

    Jaworski, M.A.; Kallman, J.; Kaita, R.; Kugel, H.; LeBlanc, B.; Marsala, R.; Ruzic, D.

    2010-01-01

    A dense array of 99 Langmuir probes has been installed in the lower divertor region of the National Spherical Torus Experiments (NSTX). This array is instrumented with a system of elec- tronics that allows flexibility in the choice of probes to bias as well as the type of measurement (including standard swept, single probe, triple probe and operation as passive floating potential and scrape-off-layer (SOL) current monitors). The use of flush-mounted probes requires careful inter- pretation. The time dependent nature of the SOL makes swept-probe traces difficult to interpret. To overcome these challenges, the single- and triple-Langmuir probe signals are used in comple- mentary fashion to determine the temperature and density at the probe location. A comparison to mid-plane measurements is made.

  5. Child-Langmuir law for cathode sheath of glow discharge in CO2

    International Nuclear Information System (INIS)

    Lisovskiy, V.A.; Krol, H.H.; Osmayev, R.O.; Yegorenkov, V.D.

    2016-01-01

    This work is devoted to the determination of the law that may be applicable to the description of the cathode sheath in CO 2 . To this end three versions of the Child-Langmuir law have been considered - a collision free one (for the ions moving through a cathode sheath without collisions with gas molecules) as well as two collision- related versions - one for a constant mean free path of positive ions and one for a constant mobility of positive ions. The current-voltage characteristics and the cathode sheath thickness of the glow discharge in CO 2 have been simultaneously measured in the pressure range from 0.05 to 1 Torr and with the discharge current values up to 80 mA. In the whole range of the discharge conditions we have studied the cathode sheath characteristics are found to obey correctly only to the Child-Langmuir law version with a constant ion mobility.

  6. Elaboration of Langmuir-Blodgett films of oligothiophenes derivatives for solid state polymerisation

    International Nuclear Information System (INIS)

    Isz, Sandrine

    1995-01-01

    Molecular electronics requires the elaboration of highly organised conductive architectures, and this research thesis addresses the fabrication of oriented conductive molecular wires. Precursors can be oriented by using the Langmuir-Blodgett technique. Synthesized molecules are oligothiophenes. After a UV-visible study in solution, these molecules have been tested under the form of Langmuir-Blodgett films. Their behaviour at the air-water interface has been characterized by using various techniques (compression isothermal, Brewster angle microscope, transmission electronic microscope, atomic force microscope) to check that higher oligothiophenes are forming a molecular film. Crystal structure reveals an almost vertical orientation of molecules at the water surface. A solid state coupling between these organised molecules has been attempted by electrochemical, thermal, and chemical ways [fr

  7. A compact, smart Langmuir Probe control module for MAST-Upgrade

    Science.gov (United States)

    Lovell, J.; Stephen, R.; Bray, S.; Naylor, G.; Elmore, S.; Willett, H.; Peterka, M.; Dimitrova, M.; Havranek, A.; Hron, M.; Sharples, R.

    2017-11-01

    A new control module for the MAST-Upgrade Langmuir Probe system has been developed. It is based on a Xilinx Zynq FPGA, which allows for excellent configurability and ease of retrieving data. The module is capable of arbitrary bias voltage waveform generation, and digitises current and voltage readings from 16 probes. The probes are biased and measured one at a time in a time multiplexed fashion, with the multiplexing sequence completely configurable. In addition, simultaneous digitisation of the floating potential of all unbiased probes is possible. A suite of these modules, each coupled with a high voltage amplifier, enables biasing and digitisation of 640 Langmuir Probes in the MAST-Upgrade Super-X divertor. The system has been successfully tested on the York Linear Plasma Device and on the COMPASS tokamak. It will be installed on MAST-Upgrade ready for operations in 2018.

  8. Crystallite structure formation at the collapse pressure of fatty acid Langmuir films

    International Nuclear Information System (INIS)

    Valdes-Covarrubias, M A; Cadena-Nava, R D; Vasquez-MartInez, E; Valdez-Perez, D; Ruiz-GarcIa, J

    2004-01-01

    We report isotherm and atomic force microscopy studies of collapsed Langmuir monolayers of fatty acids. The Langmuir monolayers were overcompressed in the range 7-40 deg. C and transferred onto mica after the sharp pressure drop when the collapse pressure was reached. Collapsed material was observed by AFM, which revealed that the multilayers are indeed three-dimensional crystallites. We found that the shape of the crystallites depends on the collapse temperature, the phase from which the collapse occurs and/or the chain length. However, at higher temperatures the collapsed films no longer show a well defined crystallite formation, but rather a more heterogeneous melt-like pattern. We associated the crystallite formation with known bulk crystal phases of the fatty acids

  9. DC Langmuir Probe for Measurement of Space Plasma: A Brief Review

    Directory of Open Access Journals (Sweden)

    Koichiro Oyama

    2015-09-01

    Full Text Available Herein, we discuss the in situ measurement of the electron temperature in the ionosphere/plasmasphere by means of DC Langmuir probes. Major instruments which have been reported are a conventional DC Langmuir probe, whose probe voltage is swept; a pulsed probe, which uses pulsed bias voltage; a rectification probe, which uses sinusoidal signal; and a resonance cone probe, which uses radio wave propagation. The content reviews past observations made with the instruments above. We also discuss technical factors that should be taken into account for reliable measurement, such as problems related to the contamination of electrodes and the satellite surface. Finally, we discuss research topics to be studied in the near future.

  10. Design and operation of a high-heat flux, flush-mounted ‘rail’ Langmuir probe array on Alcator C-Mod

    Directory of Open Access Journals (Sweden)

    A.Q. Kuang

    2017-08-01

    Full Text Available A poloidal array of toroidally-extended, flush-mounted ‘rail’ Langmuir probes was recently installed on Alcator C-Mod's vertical target plate divertor. The aim was to investigate if a Langmuir probe array could be designed to survive reactor-level heat fluxes and have the ability to make measurements that could be reliably interpreted under reactor-level plasma densities, neutral densities and magnetic fields. Langmuir probes are typically built to have incident field-line angles >10° to avoid interpretation issues associated with sheath expansion. However, at the high parallel heat fluxes experienced in reactor-relevant conditions such a probe would quickly overheat and melt. To mitigate both the issues of extreme heat flux and sheath expansion, each probe was designed to be flush with the divertor surface, toroidally-extended and field-aligned, giving it a ‘rail’ geometry. The flush mounted probes have proven to be exceptionally robust surviving the 2015–2016 campaign – a first for a C-Mod probe system. Examination of the probe current-voltage (I-V characteristics reveals that they are immune to sheath expansion at incident field angles down to ∼0.5°. Comparison of the flush probes to traditional proud probes shows that both measure the same electron pressure across the divertor plate. However, there are significant and systematic differences in the density, temperature and floating potential. This suggests that there is important physics, perhaps unique to conditions in a vertical-target plate divertor with small field-line attack angles, that affects the I-V characteristics and is not currently included in probe data analyses. Finally, the probe response is examined in the ‘death-ray’ regime, just near detachment. Previous work using proud probes has suggested that the ‘death-ray’ is an artefact of the probe bias. However, on flush mounted probes the ‘death-ray’ manifests itself under different conditions, which

  11. Maximum Langmuir Fields in Planetary Foreshocks Determined from the Electrostatic Decay Threshold

    Science.gov (United States)

    Robinson, P. A.; Cairns, Iver H.

    1995-01-01

    Maximum electric fields of Langmuir waves at planetary foreshocks are estimated from the threshold for electrostatic decay, assuming it saturates beam driven growth, and incorporating heliospheric variation of plasma density and temperature. Comparisons with spacecraft observations yields good quantitative agreement. Observations in type 3 radio sources are also in accord with this interpretation. A single mechanism can thus account for the highest fields of beam driven waves in both contexts.

  12. Spatial distribution of Langmuir waves observed upstream of Saturn's bow shock by Cassini

    Czech Academy of Sciences Publication Activity Database

    Píša, David; Santolík, Ondřej; Hospodarsky, G. B.; Kurth, W. S.; Gurnett, D. A.; Souček, Jan

    2016-01-01

    Roč. 121, č. 8 (2016), s. 7771-7784 ISSN 2169-9380 R&D Projects: GA ČR GJ16-16050Y; GA ČR(CZ) GAP209/12/2394 Institutional support: RVO:68378289 Keywords : Langmuir waves * Cassini * foreshock * Saturn Subject RIV: BL - Plasma and Gas Discharge Physics Impact factor: 2.733, year: 2016 http://onlinelibrary.wiley.com/doi/10.1002/2016JA022912/abstract

  13. Second derivative Langmuir probe diagnostics of gas discharge plasma at intermediate pressures (review article)

    International Nuclear Information System (INIS)

    Popov, Tsv K; Dimitrova, M; Dias, F M; Tsaneva, V N; Stelmashenko, N A; Blamire, M G; Barber, Z H

    2006-01-01

    The second-derivative Langmuir probe method for precise determination of the plasma potential, the electron energy distribution function (respectively the electron temperature,) and the electron density of gas discharge plasma at intermediate pressures (100-1000 Pa) is reviewed. Results of applying the procedure proposed to different kinds of gas discharges are presented. Factors affecting the accuracy of the plasma characteristics evaluated are discussed

  14. Asymmetric double Langmuir probe for fast and automatic measurements of plasma temperature

    International Nuclear Information System (INIS)

    Uckan, T.

    1987-11-01

    We present a fast technique for determining the plasma electron temperature T/sub e/ automatically from the small signal application of the asymmetric double Langmuir probe when it is operated in the region where -1 < eV/sub a/T/sub e/ < 1. The method described here is based on simple time and rms averages of the probe current that results from a sinusoidally varying applied voltage V/sub a/. 4 refs., 2 figs

  15. Stimulated Raman scattering and ion dynamics: the role of Langmuir wave non-linearities

    International Nuclear Information System (INIS)

    Bonnaud, G.; Pesme, D.

    1988-02-01

    The non-linear evolution of stimulated Raman scattering by coupling of the SRS-driven Langmuir waves to ion acoustic waves is studied numerically, in a homogeneous density laser-irradiated plasma. The coupled wave amplitude behaviour is represented either by envelope equations or by complete wave-like equations. The various physical phenomena which are involved are described. This preliminary work has been presented at the 17th Anomalous Absorption Conference, held in last May, in Lake Tahoe City (USA) [fr

  16. Fabrication of phytic acid sensor based on mixed phytase-lipid Langmuir-Blodgett films.

    Science.gov (United States)

    Caseli, Luciano; Moraes, Marli L; Zucolotto, Valtencir; Ferreira, Marystela; Nobre, Thatyane M; Zaniquelli, Maria Elisabete D; Rodrigues Filho, Ubirajara P; Oliveira, Osvaldo N

    2006-09-26

    This paper reports the surface activity of phytase at the air-water interface, its interaction with lipid monolayers, and the construction of a new phytic acid biosensor on the basis of the Langmuir-Blodgett (LB) technique. Phytase was inserted in the subphase solution of dipalmitoylphosphatidylglycerol (DPPG) Langmuir monolayers, and its incorporation to the air-water interface was monitored with surface pressure measurements. Phytase was able to incorporate into DPPG monolayers even at high surface pressures, ca. 30 mN/m, under controlled ionic strength, pH, and temperature. Mixed Langmuir monolayers of phytase and DPPG were characterized by surface pressure-area and surface potential-area isotherms, and the presence of the enzyme provided an expansion in the monolayers (when compared to the pure lipid at the interface). The enzyme incorporation also led to significant changes in the equilibrium surface compressibility (in-plane elasticity), especially in liquid-expanded and liquid-condensed regions. The dynamic surface elasticity for phytase-containing interfaces was investigated using harmonic oscillation and axisymmetric drop shape analysis. The insertion of the enzyme at DPPG monolayers caused an increase in the dynamic surface elasticity at 30 mN m(-)(1), indicating a strong interaction between the enzyme and lipid molecules at a high-surface packing. Langmuir-Blodgett (LB) films containing 35 layers of mixed phytase-DPPG were characterized by ultraviolet-visible and fluorescence spectroscopy and crystal quartz microbalance nanogravimetry. The ability in detecting phytic acid was studied with voltammetric measurements.

  17. Tests of Parameterized Langmuir Circulation Mixing in the Oceans Surface Mixed Layer II

    Science.gov (United States)

    2017-08-11

    inertial oscillations in the ocean are governed by three-dimensional processes that are not accounted for in a one-dimensional simulation , and it was...Unlimited 52 Paul Martin (228) 688-5447 Recent large-eddy simulations (LES) of Langmuir circulation (LC) within the surface mixed layer (SML) of...used in the Navy Coastal Ocean Model (NCOM) and tested for (a) a simple wind-mixing case, (b) simulations of the upper ocean thermal structure at Ocean

  18. Influence of unharmonic changes of plasma potential on the Langmuir probe characteristics for a grounded probe

    International Nuclear Information System (INIS)

    Surda, V.

    1990-01-01

    A theory is presented of the deformation of Langmuir probe characteristics by the presence of a.c. plasma potential oscillations at the space charge layer around the probe, making allowance for the fundamental frequency and the second harmonic. It is applicable particularly to the determination of the electron temperature in actual high-frequency discharges with a Maxwellian electron energy distribution. The effect of an a.c. signal on the ion current is also treated. (author). 8 figs., 14 refs

  19. New depositing method of Langmuir-Blodgett film of fatty acid soap as a radioactive source

    Energy Technology Data Exchange (ETDEWEB)

    Iwahashi, Makio; Watanabe, Norifumi; Seimiya, Tsutomu; Naito, Fujio

    1985-02-01

    A stable radioactive source in vacuo was obtained by a new depositing method of Langmuir-Blodgett (L/B) film. In spite of the slight consumption of the substrate solution (only 2-2.5 ml) for preparing a 15 mm x 25 mm sized L/B film containing four molecular layers of /sup 109/Cd-eicosanoate, the deposition of the film was complete. (author).

  20. Statistics of Langmuir wave amplitudes observed inside Saturn's foreshock by the Cassini spacecraft

    Czech Academy of Sciences Publication Activity Database

    Píša, David; Hospodarsky, G. B.; Kurth, W. S.; Santolík, Ondřej; Souček, Jan; Gurnett, D. A.; Masters, A.; Hill, M. E.

    2015-01-01

    Roč. 120, č. 4 (2015), s. 2531-2542 ISSN 2169-9380 R&D Projects: GA ČR GAP205/10/2279; GA ČR(CZ) GAP209/12/2394 Institutional support: RVO:68378289 Keywords : Langmuir waves * foreshock * Saturn * Cassini Subject RIV: BL - Plasma and Gas Discharge Physics Impact factor: 3.318, year: 2015 http://onlinelibrary.wiley.com/doi/10.1002/2014JA020560/abstract

  1. Electronegative plasma diagnostic by laser photo-detachment combined with negatively biased Langmuir probe

    Science.gov (United States)

    Oudini, N.; Sirse, N.; Taccogna, F.; Ellingboe, A. R.; Bendib, A.

    2018-05-01

    We propose a new technique for diagnosing negative ion properties using Langmuir probe assisted pulsed laser photo-detachment. While the classical technique uses a laser pulse to convert negative ions into electron-atom pairs and a positively biased Langmuir probe tracking the change of electron saturation current, the proposed method uses a negatively biased Langmuir probe to track the temporal evolution of positive ion current. The negative bias aims to avoid the parasitic electron current inherent to probe tip surface ablation. In this work, we show through analytical and numerical approaches that, by knowing electron temperature and performing photo-detachment at two different laser wavelengths, it is possible to deduce plasma electronegativity (ratio of negative ion to electron densities) α, and anisothermicity (ratio of electron to negative ion temperatures) γ-. We present an analytical model that links the change in the collected positive ion current to plasma electronegativity and anisothermicity. Particle-In-Cell simulation is used as a numerical experiment covering a wide range of α and γ- to test the new analysis technique. The new technique is sensitive to α in the range 0.5 1.

  2. ON QUIET-TIME SOLAR WIND ELECTRON DISTRIBUTIONS IN DYNAMICAL EQUILIBRIUM WITH LANGMUIR TURBULENCE

    International Nuclear Information System (INIS)

    Zaheer, S.; Yoon, P. H.

    2013-01-01

    A recent series of papers put forth a self-consistent theory of an asymptotically steady-state electron distribution function and Langmuir turbulence intensity. The theory was developed in terms of the κ distribution which features Maxwellian low-energy electrons and a non-Maxwellian energetic power-law tail component. The present paper discusses a generalized κ distribution that features a Davydov-Druyvesteyn type of core component and an energetic power-law tail component. The physical motivation for such a generalization is so that the model may reflect the influence of low-energy electrons interacting with low-frequency kinetic Alfvénic turbulence as well as with high-frequency Langmuir turbulence. It is shown that such a solution and the accompanying Langmuir wave spectrum rigorously satisfy the balance requirement between the spontaneous and induced emission processes in both the particle and wave kinetic equations, and approximately satisfy the similar balance requirement between the spontaneous and induced scattering processes, which are nonlinear. In spite of the low velocity modification of the electron distribution function, it is shown that the resulting asymptotic velocity power-law index α, where f e ∼ v –α is close to the average index observed during the quiet-time solar wind condition, i.e., α ∼ O(6.5) whereas α average ∼ 6.69, according to observation

  3. Payload charging events in the mesosphere and their impact on Langmuir type electric probes

    Directory of Open Access Journals (Sweden)

    T. A. Bekkeng

    2013-02-01

    Full Text Available Three sounding rockets were launched from Andøya Rocket Range in the ECOMA campaign in December 2010. The aim was to study the evolution of meteoric smoke particles during a major meteor shower. Of the various instruments onboard the rocket payload, this paper presents the data from a multi-Needle Langmuir Probe (m-NLP and a charged dust detector. The payload floating potential, as observed using the m-NLP instrument, shows charging events on two of the three flights. These charging events cannot be explained using a simple charging model, and have implications towards the use of fixed bias Langmuir probes on sounding rockets investigating mesospheric altitudes. We show that for a reliable use of a single fixed bias Langmuir probe as a high spatial resolution relative density measurement, each payload should also carry an additional instrument to measure payload floating potential, and an instrument that is immune to spacecraft charging and measures absolute plasma density.

  4. Langmuir and Freundlich Isotherm Adsorption Equations for Chromium (VI) Waste Adsorption by Zeolite

    International Nuclear Information System (INIS)

    Murni Handayani; Eko Sulistiyono

    2009-01-01

    The research of chromium (VI) waste adsorption by zeolite has done. Wastes which are produced by Industries, both radioactive waste and heavy metal waste need done more processing so that they are not endanger environment and human health. Zeolite has very well-ordered crystal form with cavity each other to way entirely so that cause surface wide of zeolite become very big and very good as adsorbents. This research intends to know appropriate isotherm adsorption method to determine maximum capacity of zeolite to chromium (VI) waste. The equations which used in adsorption process are Langmuir and Freundlich isotherm Adsorption equations. The instrument was used in adsorption process by using Atomic Adsorption Spectroscopy (AAS). The experiment result showed that the biggest mass of chromium (VI) metal ion which was absorb by zeolite in 20 ppm concentration was 7.71 mg/gram zeolite. Adsorption process of Chromium (VI) waste by zeolite followed Langmuir and Freundlich isotherm equations with R 2 >0,9 . Appropriate equation to determine maximum adsorption capacity of zeolite for chromium (VI) waste adsorption is Langmuir equation. The maximum adsorption capacity of zeolite is 52.25 mg/gram. (author)

  5. Impact of Langmuir Turbulence on Upper Ocean Response to Hurricane Edouard: Model and Observations

    Science.gov (United States)

    Blair, A.; Ginis, I.; Hara, T.; Ulhorn, E.

    2017-12-01

    Tropical cyclone intensity is strongly affected by the air-sea heat flux beneath the storm. When strong storm winds enhance upper ocean turbulent mixing and entrainment of colder water from below the thermocline, the resulting sea surface temperature cooling may reduce the heat flux to the storm and weaken the storm. Recent studies suggest that this upper ocean turbulence is strongly affected by different sea states (Langmuir turbulence), which are highly complex and variable in tropical cyclone conditions. In this study, the upper ocean response under Hurricane Edouard (2014) is investigated using a coupled ocean-wave model with and without an explicit sea state dependent Langmuir turbulence parameterization. The results are compared with in situ observations of sea surface temperature and mixed layer depth from AXBTs, as well as satellite sea surface temperature observations. Overall, the model results of mixed layer deepening and sea surface temperature cooling under and behind the storm are consistent with observations. The model results show that the effects of sea state dependent Langmuir turbulence can be significant, particularly on the mixed layer depth evolution. Although available observations are not sufficient to confirm such effects, some observed trends suggest that the sea state dependent parameterization might be more accurate than the traditional (sea state independent) parameterization.

  6. Supramolecular architectures of iron phthalocyanine Langmuir-Blodgett films: The role played by the solution solvents

    Science.gov (United States)

    Rubira, Rafael Jesus Gonçalves; Aoki, Pedro Henrique Benites; Constantino, Carlos José Leopoldo; Alessio, Priscila

    2017-09-01

    The developing of organic-based devices has been widely explored using ultrathin films as the transducer element, whose supramolecular architecture plays a central role in the device performance. Here, Langmuir and Langmuir-Blodgett (LB) ultrathin films were fabricated from iron phthalocyanine (FePc) solutions in chloroform (CHCl3), dichloromethane (CH2Cl2), dimethylformamide (DMF), and tetrahydrofuran (THF) to determine the influence of different solvents on the supramolecular architecture of the ultrathin films. The UV-vis absorption spectroscopy shows a strong dependence of the FePc aggregation on these solvents. As a consequence, the surface pressure vs. mean molecular area (π-A) isotherms and Brewster angle microscopy (BAM) reveal a more homogeneous (surface morphology) Langmuir film at the air/water interface for FePc in DMF. The same morphological pattern observed for the Langmuir films is preserved upon LB deposition onto solid substrates. The Raman and FTIR analyses indicate the DMF-FePc interaction relies on coordination bonds between N atom (from DMF) and Fe atom (from FePc). Besides, the FePc molecular organization was also found to be affected by the DMF-FePc chemical interaction. It is interesting to note that, if the DMF-FePc leads to less aggregated FePc either in solution or ultrathin films (Langmuir and LB), with time (one week) the opposite trend is found. Taking into account the N-Fe interaction, the performance of the FePc ultrathin films with distinct supramolecular architectures composing sensing units was explored as proof-of-principle in the detection of trace amounts of atrazine herbicide in water using impedance spectroscopy. Further statistical and computational analysis reveal not only the role played by FePc supramolecular architecture but also the sensitivity of the system to detect atrazine solutions down to 10-10 mol/L, which is sufficient to monitor the quality of drinking water even according to the most stringent international

  7. Predicting heavy metals' adsorption edges and adsorption isotherms on MnO2 with the parameters determined from Langmuir kinetics.

    Science.gov (United States)

    Hu, Qinghai; Xiao, Zhongjin; Xiong, Xinmei; Zhou, Gongming; Guan, Xiaohong

    2015-01-01

    Although surface complexation models have been widely used to describe the adsorption of heavy metals, few studies have verified the feasibility of modeling the adsorption kinetics, edge, and isotherm data with one pH-independent parameter. A close inspection of the derivation process of Langmuir isotherm revealed that the equilibrium constant derived from the Langmuir kinetic model, KS-kinetic, is theoretically equivalent to the adsorption constant in Langmuir isotherm, KS-Langmuir. The modified Langmuir kinetic model (MLK model) and modified Langmuir isotherm model (MLI model) incorporating pH factor were developed. The MLK model was employed to simulate the adsorption kinetics of Cu(II), Co(II), Cd(II), Zn(II) and Ni(II) on MnO2 at pH3.2 or 3.3 to get the values of KS-kinetic. The adsorption edges of heavy metals could be modeled with the modified metal partitioning model (MMP model), and the values of KS-Langmuir were obtained. The values of KS-kinetic and KS-Langmuir are very close to each other, validating that the constants obtained by these two methods are basically the same. The MMP model with KS-kinetic constants could predict the adsorption edges of heavy metals on MnO2 very well at different adsorbent/adsorbate concentrations. Moreover, the adsorption isotherms of heavy metals on MnO2 at various pH levels could be predicted reasonably well by the MLI model with the KS-kinetic constants. Copyright © 2014. Published by Elsevier B.V.

  8. Magnetized Langmuir wave packets excited by a strong beam-plasma interaction

    International Nuclear Information System (INIS)

    Pelletier, G.; Sol, H.; Asseo, E.

    1988-01-01

    The physics of beam-plasma interaction, which has been investigated for a long time mostly in relation with solar bursts, is now more widely invoked in various astrophysical contexts such as pulsars, active galactic nuclei, close binaries, cataclysmic variables, γ bursters, and so on. In these situations the interaction is more likely in the spirit of strong Langmuir turbulence rather than in the spirit of quasilinear theory. Many investigations have been done for two opposite extremes, namely, in very weak and in very strong magnetic fields. Very few properties of the strong Langmuir turbulence are known in the most usual astrophysical situation where the magnetic field plays a significant role but is not strong enough to force the electrons into one-dimensional motion. For this case, we analyze the dynamics of Langmuir wave packets and provide new results about the stability of the solitons against transverse perturbations. It turns out that both the averaged Lagrangian method and the adiabatic perturbation method derived from the inverse scattering transform give exactly the same results (which is not obvious in soliton perturbation theory). In particular, they predict the stability of the solitons as long as the electron gyrofrequency is greater than the plasma frequency (strong magnetic field) and their instability against transverse self-modulation in the opposite case (weak magnetic field); moreover, they allow one to deduce the self-similar collapsing oblate cavitons in the latter case. The laws governing the collapse of the wave packets determine the relaxation of the beam in the surrounding medium and we derive a useful formula giving the power loss of the beam. We outline the astrophysical consequences of this investigation

  9. Strong Evidence for Stochastic Growth of Langmuir-Like Waves in Earth's Foreshock

    Science.gov (United States)

    Cairns, Iver H.; Robinson, P. A.

    1999-01-01

    Bursty Langmuir-like waves driven by electron beams in Earth's foreshock have properties which are inconsistent with the standard plasma physics paradigm of uniform exponential growth saturated by nonlinear processes. Here it is demonstrated for a specific period that stochastic growth theory (SGT) quantitatively describes these waves throughout a large fraction of the foreshock. The statistical wave properties are inconsistent with nonlinear processes or self-organized criticality being important. SGT's success in explaining the foreshock waves and type III solar bursts suggests that SGT is widely applicable to wave growth in space, astrophysical, and laboratory plasmas.

  10. Second harmonic generation in anisotropic Langmuir-Blodgett films of N-docosyl-4-nitroaniline

    DEFF Research Database (Denmark)

    Geisler, T.; Rosenkilde, S.; Ramanujam, P.S.

    1992-01-01

    Langmuir-Blodgett (LB) films of N-docosyl-4-nitroaniline have been made and their nonlinear optical properties studied by second harmonic generation (SHG) measurements. A significant enhancement of the intensity of the second harmonic of the 1.064-mu-m YAG was observed when a two layer Y-type film...... structure. Both of these observations are not common for Y-type LB films and the usual assumption of C(infinity nu) symmetry is therefore not valid. The results make us suggest that these LB films possess C(s) and C2-nu symmetry for mono- and multilayers, respectively. Theoretical expressions...

  11. Radicals as EPR probes of magnetization of gadolinium stearate Langmuir-Blodgett film

    DEFF Research Database (Denmark)

    Koksharov, Y.A.; Bykov, I.V.; Malakho, A.P.

    2002-01-01

    In the present work we have applied the method of the EPR spin probes which allows performing simultaneously EPR and magnetization measurements to the investigation of magnetism of the Cid stearate Langmuir-Blodgett (LB) films. For this purpose we have prepared and studied by the EPR technique...... the Gd and Y stearate LB films. Placing the small BDPA crystal on the film surface we have found that for the Gd LB sample the effective g-value of the radical's resonance depends on the film orientation in respect to the external magnetic field direction. The relative shift of the EPR signal...

  12. A maximally informative version of inelastic scattering of electromagnetic waves by Langmuir waves

    International Nuclear Information System (INIS)

    Erofeev, V. I.

    2015-01-01

    The concept of informativeness of nonlinear plasma physics scenarios is explained. Natural ideas of developing highly informative models of plasma kinetics are spelled out. A maximally informative version of inelastic scattering of electromagnetic waves by Langmuir waves in a weakly turbulent inhomogeneous plasma is developed with consideration of possible changes in wave polarization. In addition, a new formula for wave drift in spatial positions and wave vectors is derived. New scenarios of the respective wave drift and inelastic scattering are compared with the previous visions. The results indicate the need for further revision of the traditional understanding of nonlinear plasma phenomena

  13. Non-parametric correlative uncertainty quantification and sensitivity analysis: Application to a Langmuir bimolecular adsorption model

    Science.gov (United States)

    Feng, Jinchao; Lansford, Joshua; Mironenko, Alexander; Pourkargar, Davood Babaei; Vlachos, Dionisios G.; Katsoulakis, Markos A.

    2018-03-01

    We propose non-parametric methods for both local and global sensitivity analysis of chemical reaction models with correlated parameter dependencies. The developed mathematical and statistical tools are applied to a benchmark Langmuir competitive adsorption model on a close packed platinum surface, whose parameters, estimated from quantum-scale computations, are correlated and are limited in size (small data). The proposed mathematical methodology employs gradient-based methods to compute sensitivity indices. We observe that ranking influential parameters depends critically on whether or not correlations between parameters are taken into account. The impact of uncertainty in the correlation and the necessity of the proposed non-parametric perspective are demonstrated.

  14. Non-parametric correlative uncertainty quantification and sensitivity analysis: Application to a Langmuir bimolecular adsorption model

    Directory of Open Access Journals (Sweden)

    Jinchao Feng

    2018-03-01

    Full Text Available We propose non-parametric methods for both local and global sensitivity analysis of chemical reaction models with correlated parameter dependencies. The developed mathematical and statistical tools are applied to a benchmark Langmuir competitive adsorption model on a close packed platinum surface, whose parameters, estimated from quantum-scale computations, are correlated and are limited in size (small data. The proposed mathematical methodology employs gradient-based methods to compute sensitivity indices. We observe that ranking influential parameters depends critically on whether or not correlations between parameters are taken into account. The impact of uncertainty in the correlation and the necessity of the proposed non-parametric perspective are demonstrated.

  15. Quantitative study of the trapped particle bunching instability in Langmuir waves

    International Nuclear Information System (INIS)

    Hara, Kentaro; Boyd, Iain D.; Chapman, Thomas; Joseph, Ilon; Berger, Richard L.; Banks, Jeffrey W.; Brunner, Stephan

    2015-01-01

    The bunching instability of particles trapped in Langmuir waves is studied using Vlasov simulations. A measure of particle bunching is defined and used to extract the growth rate from numerical simulations, which are compared with theory [Dodin et al., Phys. Rev. Lett. 110, 215006 (2013)]. In addition, the general theory of trapped particle instability in 1D is revisited and a more accurate description of the dispersion relation is obtained. Excellent agreement between numerical and theoretical predictions of growth rates of the bunching instability is shown over a range of parameters

  16. Quantitative study of the trapped particle bunching instability in Langmuir waves

    Energy Technology Data Exchange (ETDEWEB)

    Hara, Kentaro, E-mail: kenhara@umich.edu; Boyd, Iain D. [Department of Aerospace Engineering, University of Michigan, Ann Arbor, Michigan 48109 (United States); Chapman, Thomas; Joseph, Ilon; Berger, Richard L. [Lawrence Livermore National Laboratory, Livermore, California 94550 (United States); Banks, Jeffrey W. [Department of Mathematical Sciences, Rensselaer Polytechnic Institute, Troy, New York 12180 (United States); Brunner, Stephan [Centre de Recherches en Physique des Plasmas, Association Euratom-Confederation Suisse, Ecole Polytechnique Fédérale de Lausanne, CRPP-PPB, CH-1015 Lausanne (Switzerland)

    2015-02-15

    The bunching instability of particles trapped in Langmuir waves is studied using Vlasov simulations. A measure of particle bunching is defined and used to extract the growth rate from numerical simulations, which are compared with theory [Dodin et al., Phys. Rev. Lett. 110, 215006 (2013)]. In addition, the general theory of trapped particle instability in 1D is revisited and a more accurate description of the dispersion relation is obtained. Excellent agreement between numerical and theoretical predictions of growth rates of the bunching instability is shown over a range of parameters.

  17. Langmuir-Blodgett films of polyaniline for low density lipoprotein detection

    Energy Technology Data Exchange (ETDEWEB)

    Matharu, Zimple [Department of Science and Technology Centre on Biomolecular Electronics, Biomedical Instrumentation Section, National Physical Laboratory (CSIR), Dr. K. S. Krishnan Marg, New Delhi-110012 (India); Department of Physics and Astrophysics, University of Delhi, Delhi-110007 (India); Sumana, G. [Department of Science and Technology Centre on Biomolecular Electronics, Biomedical Instrumentation Section, National Physical Laboratory (CSIR), Dr. K. S. Krishnan Marg, New Delhi-110012 (India); Gupta, Vinay [Department of Physics and Astrophysics, University of Delhi, Delhi-110007 (India); Malhotra, B.D., E-mail: bansi.malhotra@gmail.co [Department of Science and Technology Centre on Biomolecular Electronics, Biomedical Instrumentation Section, National Physical Laboratory (CSIR), Dr. K. S. Krishnan Marg, New Delhi-110012 (India)

    2010-11-30

    Langmuir-Blodgett (LB) films of polyaniline (PANI) were utilized for the fabrication of impedimetric immunosensor for detection of human plasma low density lipoprotein (LDL) by immobilizing anti-apolipoprotein B (AAB) via EDC-NHS coupling. The modified electrodes were characterized by electrochemical impedance spectroscopy (EIS) and scanning electron microscopy. AAB/PANI-SA LB immunoelectrodes studied by EIS spectroscopy revealed detection of LDL in the wide range of 0.018 {mu}M (6 mg/dl) to 0.39 {mu}M (130 mg/dl), covering the physiological range in blood, with a sensitivity of 11.25 k{Omega} {mu}M{sup -1}.

  18. Langmuir-Blodgett films of polyaniline for low density lipoprotein detection

    International Nuclear Information System (INIS)

    Matharu, Zimple; Sumana, G.; Gupta, Vinay; Malhotra, B.D.

    2010-01-01

    Langmuir-Blodgett (LB) films of polyaniline (PANI) were utilized for the fabrication of impedimetric immunosensor for detection of human plasma low density lipoprotein (LDL) by immobilizing anti-apolipoprotein B (AAB) via EDC-NHS coupling. The modified electrodes were characterized by electrochemical impedance spectroscopy (EIS) and scanning electron microscopy. AAB/PANI-SA LB immunoelectrodes studied by EIS spectroscopy revealed detection of LDL in the wide range of 0.018 μM (6 mg/dl) to 0.39 μM (130 mg/dl), covering the physiological range in blood, with a sensitivity of 11.25 kΩ μM -1 .

  19. Langmuir-Blodgett films of alkane chalcogenice (S, Se, Te) stabilized gold nanoparticles

    DEFF Research Database (Denmark)

    Brust, M.; Stuhr-Hansen, N.; Norgaard, K.

    2001-01-01

    Gold nanoparticles stabilized by alkanethiolates, alkaneselenides, and alkanetellurides have been prepared by analogous methods. Chloroform solutions of thiolate and selenide stabilized particles were spread and evaporated on the water/air interface where the particles formed well-defined Langmuir...... films. The films were transferred to solid supports of freshly cleaved mica and were studied by atomic force microscopy (AFM). The particles were found to have an average core diameter of 2 nm. The stability of the particles under ambient conditions increased in the order Te

  20. Child–Langmuir law applicability for a cathode sheath description of glow discharge in hydrogen

    International Nuclear Information System (INIS)

    Lisovskiy, V A; Artushenko, K P; Yegorenkov, V D

    2016-01-01

    The present paper reveals that the Child-Langmuir law version with the constant ion mobility has to be applied for the cathode sheath description of the glow discharge in hydrogen. Using the analytical model we demonstrate that even in a high electric field the constant mobility law version rather than that for the constant ion mean free path has to hold in the case of impeded charge exchange and the dominant effect of polarization forces on the ion motion through the cathode sheath. (paper)

  1. An introduction to ultrathin organic films from Langmuir-Blodgett to self-assembly

    CERN Document Server

    Ulman, Abraham

    1991-01-01

    The development of oriented organic monomolecular layers by the Langmuir-Blodgett (LB) and self-assembly (SA) techniques has led researchers toward their goal of assembling individual molecules into highly ordered architectures. Thus the continually growing contribution of LB and SA systems to the chemistry and physics of thin organic films is widely recognized. Equally well-known is the difficulty in keeping up to date with the burgeoning multidisciplinary research in this area. Dr. Ulman provides a massive survey of the available literature. The book begins with a section on analytical tools

  2. Plasma flow measurement using directional Langmuir probe under weakly ion-magnetized conditions

    Energy Technology Data Exchange (ETDEWEB)

    Nagaoka, Kenichi; Okamoto, Atsushi [Graduate School of Science, Nagoya Univ., Nagoya (Japan); Yoshimura, Shinji; Tanaka, Masayoshi Y. [National Inst. for Fusion Science, Toki, Gifu (Japan)

    2000-07-01

    It is both experimentally and theoretically demonstrated that ion flow velocity at an arbitrary angle with respect to the magnetic field can be measured with a directional Langmuir probe. Based on the symmetry argument, we show that the effect of magnetic field on directional probe current is exactly canceled in determining the ion flow velocity, and obtain the generalized relation between flow velocity and directional probe currents valid for any flowing direction. The absolute value of the flow velocity is determined by an in situ calibration method of the probe. The applicability limit of the present method to a strongly ion-magnetized plasma is experimentally examined. (author)

  3. First simultaneous measurements of Reynolds stress with ball-pen and Langmuir probes

    Czech Academy of Sciences Publication Activity Database

    Grover, Ondřej; Adámek, Jiří; Seidl, Jakub; Devitre, A.; Šos, Miroslav; Vondráček, Petr; Bílková, Petra; Hron, Martin

    2017-01-01

    Roč. 88, č. 6 (2017), č. článku 063501. ISSN 0034-6748 R&D Projects: GA ČR(CZ) GA15-10723S; GA ČR(CZ) GA16-25074S; GA MŠk(CZ) LM2015045 Institutional support: RVO:61389021 Keywords : COMPASS tokamak * Electric field effects * Electric fields * Langmuir probes * Magnetoplasma * Ball-pen probes Subject RIV: BL - Plasma and Gas Discharge Physics OBOR OECD: 2.11 Other engineering and technologies Impact factor: 1.515, year: 2016 http://aip.scitation.org/doi/full/10.1063/1.4984240

  4. Conceptual design of a Langmuir probe system for the tokamak ASDEX-UPGRADE

    International Nuclear Information System (INIS)

    Anastassiadis, A.; Tsingas, A.C.; Tsois, N.N.; Zoumbos, G.A.

    1985-05-01

    The conceptual design of a Langmuir probe system for the tokamak ASDEX-UPG is presented. This system is intended to carry out electrostatic measurements, in space and time, on the boundary layer plasma over the largest possible volume of the divertor plasma during discharges. Conducted by preset design requirements a fast probe system is proposed. During discharges signal measurements will be performed by means of a data-acquisition system and the motion will be controlled by a real-time computer. The desired information concerning plasma parameters and the motion of the probe system will be available to the diagnostician via a video display unit. (author)

  5. Electron non-linearities in Langmuir waves with application to beat-wave experiments

    International Nuclear Information System (INIS)

    Bell, A.R.; Gibbon, P.

    1988-01-01

    Non-linear Langmuir waves are examined in the context of the beat-wave accelerator. With a background of immobile ions the waves in one dimension are subject to the relativistic non-linearity of Rosenbluth, M.N. and Liu, C.S., Phys. Rev. Lett., 1972, 29, 701. In two or three dimensions, other electron non-linearities occur which involve electric and magnetic fields. The quasi-linear equations for these non-linearities are developed and solved numerically in a geometry representative of laser-driven beat waves. (author)

  6. Embedded calibration system for the DIII-D Langmuir probe analog fiber optic links

    International Nuclear Information System (INIS)

    Watkins, J. G.; Rajpal, R.; Mandaliya, H.; Watkins, M.; Boivin, R. L.

    2012-01-01

    This paper describes a generally applicable technique for simultaneously measuring offset and gain of 64 analog fiber optic data links used for the DIII-D fixed Langmuir probes by embedding a reference voltage waveform in the optical transmitted signal before every tokamak shot. The calibrated data channels allow calibration of the power supply control fiber optic links as well. The array of fiber optic links and the embedded calibration system described here makes possible the use of superior modern data acquisition electronics in the control room.

  7. RF plasma parameter determination by a Langmuir multipoint double probe array

    International Nuclear Information System (INIS)

    Rojas-Olmedo, I A; López-Callejas, R; De la Piedad-Beneitez, A; Valencia-Alvarado, R; Peña-Eguiluz, R; Mercado-Cabrera, A; Barocio, S R; Muñoz-Castro, A E; Rodríguez-Méndez, B G

    2012-01-01

    A multipoint double Langmuir (MDL) probe system, which is exempt from interference, has been designed and assembled to be applied to an RF plasma. The system provides the measurement of fundamental plasma parameters such as density, temperature, plasma potential, etc. on the basis of the Bohm Approximation Theory and the Orbital Movement Limit. Thus, one pair of the MDL system is selected so as to consider the right plasma parameters within the prevailing pressure-power intervals. Both the hardware and software of the system have been applied to the modification of material properties by means of the PIII process.

  8. RF compensation of single Langmuir probe in low density helicon plasma

    Energy Technology Data Exchange (ETDEWEB)

    Ghosh, Soumen, E-mail: soumen@ipr.res.in; Chattopadhyay, Prabal K.; Ghosh, Joydeep; Bora, Dhiraj

    2016-11-15

    Highlights: • Appropriate density and temperature measurement with Langmuir probe in RF Eenvironment. • Necessity of large auxiliary electrode for RF compensation at low densities (∼10{sup 16} m{sup −3}). • Measured two temperature electrons in low pressure helicon antenna produced RF plasma. • Tail electrons are localized only at off-axis in our cylindrical plasma system. - Abstract: Interpretations of Single Langmuir probe measurements in electrode-less radio frequency (RF) plasmas are noteworthy tricky and require adequate compensation of RF. Conventional RF compensation technique is limited only at high density (>10{sup 17} m{sup −3}) RF plasmas. RF compensation of single Langmuir probe at low density RF plasmas (∼10{sup 16} m{sup −3}) is presented in this paper. In RF driven plasmas, where the RF voltage is high (∼50 V) and density is in the range (∼10{sup 16} m{sup −3}), the primary RF compensation condition (Z{sub ck} > >Z{sub sh}) is very difficult to fulfill, because of high sheath impedance (Z{sub sh}) at 13.56 MHz and the construction limitation of a self-resonant tiny chock (Z{sub ck}) with very high impedance. Introducing a large auxiliary electrode (A{sub x}), (A{sub x} >>> A{sub p}), close to the small Langmuir probe (A{sub p}) tip, connected in parallel with probe via a coupling capacitor (C{sub cp}), significantly reduces the effective sheath impedance (Z{sub sh}) and allows probe bias to follow the RF oscillation. Dimensional requirements of the auxiliary electrode and the role of suitable coupling capacitor are discussed in this paper. Observations show proper compensation leads to estimation of more positive floating potentials and lower electron temperatures compared to uncompensated probe. The electron energy probability function (EEPF) is also obtained by double differentiating the collected current with respect to the applied bias voltage using an active analog circuit.

  9. Parametric decay of current-driven Langmuir waves in plateau plasmas: Relevance to solar wind and foreshock events

    Science.gov (United States)

    Sauer, Konrad; Malaspina, David M.; Pulupa, Marc; Salem, Chadi S.

    2017-07-01

    Langmuir amplitude modulation in association with type III radio bursts is a well-known phenomenon since the beginning of space observations. It is commonly attributed to the superposition of beam-excited Langmuir waves and their backscattered counterparts as a result of parametric decay. The dilemma, however, is the discrepancy between fast beam relaxation and long-lasting Langmuir wave activity. Instead of starting with an unstable electron beam, our focus in this paper is on the nonlinear response of Langmuir oscillations that are driven after beam stabilization by the still persisting current of the (stable) two-electron plasma. The velocity distribution function of the second population forms a plateau (index h) with a point at which ∂fh/∂v ˜0 associated with weak damping over a more or less extended wave number range k. As shown by particle-in-cell simulations, this so-called plateau plasma drives primarily Langmuir oscillations at the plasma frequency (ωe) with k = 0 over long times without remarkable change of the distribution function. These Langmuir oscillations act as a pump wave for parametric decay by which an electron-acoustic wave slightly below ωe and a counterstreaming ion-acoustic wave are generated. Both high-frequency waves have nearly the same amplitude, which is given by the product of plateau density and velocity. Beating of these two wave types leads to pronounced Langmuir amplitude modulation, in reasonable agreement with solar wind and terrestrial foreshock observations made by the Wind spacecraft.

  10. THE EFFECTS OF ELECTRON-BEAM-INDUCED ELECTRIC FIELD ON THE GENERATION OF LANGMUIR TURBULENCE IN FLARING ATMOSPHERES

    International Nuclear Information System (INIS)

    Zharkova, Valentina V.; Siversky, Taras V.

    2011-01-01

    The precipitation of an electron beam injected into the solar atmosphere is studied for the generation of Langmuir wave turbulence in the presence of collisional and Ohmic losses. The system of quasi-linear time-dependent kinetic equations describing the evolution of beams and Langmuir waves is solved by using the summary approximation method. It is found that at upper atmospheric levels the self-induced electric field suppresses the generation of Langmuir turbulence to very small regions below injection. With further precipitation into deeper atmosphere the initial single power-law distributions of beam electrons are transformed into energy distributions with maxima at lower energies formed by collisional and Ohmic energy depletion. The electrons with lower energies (<20 keV) generate on large spatial scales intense low-hybrid and high-hybrid Langmuir waves with well-defined patterns in the corona while higher energy electrons generate moderate low-hybrid waves in the chromosphere. The maximum wave density appears at the maximum of the ambient density. The self-induced electric field reduces the level and makes the regions with low-hybrid Langmuir turbulence narrower in the corona and upper chromosphere. The higher the beam energy flux or its self-induced electric field, the narrower the regions with Langmuir turbulence. High-hybrid Langmuir waves in the form of multiple patterns in space (in the corona) and energy (below 20 keV) are found to be generated only by a very intense electron beam. The number of patterns in both dimensions is also shown to be significantly reduced by the self-induced electric field.

  11. First Test of Stochastic Growth Theory for Langmuir Waves in Earth's Foreshock

    Science.gov (United States)

    Cairns, Iver H.; Robinson, P. A.

    1997-01-01

    This paper presents the first test of whether stochastic growth theory (SGT) can explain the detailed characteristics of Langmuir-like waves in Earth's foreshock. A period with unusually constant solar wind magnetic field is analyzed. The observed distributions P(logE) of wave fields E for two intervals with relatively constant spacecraft location (DIFF) are shown to agree well with the fundamental prediction of SGT, that P(logE) is Gaussian in log E. This stochastic growth can be accounted for semi-quantitatively in terms of standard foreshock beam parameters and a model developed for interplanetary type III bursts. Averaged over the entire period with large variations in DIFF, the P(logE) distribution is a power-law with index approximately -1; this is interpreted in terms of convolution of intrinsic, spatially varying P(logE) distributions with a probability function describing ISEE's residence time at a given DIFF. Wave data from this interval thus provide good observational evidence that SGT can sometimes explain the clumping, burstiness, persistence, and highly variable fields of the foreshock Langmuir-like waves.

  12. Studies on the Electrical Characteristics of a DC Glow Discharge by Using Langmuir Probe

    International Nuclear Information System (INIS)

    Safaai, S. S.; Yap, S. L.; Wong, C. S.; Muniandy, S. V.; Smith, P. W.

    2010-01-01

    Electrical characteristics of a DC glow discharge are studied with the aim of determining the suitable parameters for stable operation of the dusty plasma system. The presence of dust particles in plasma significantly alters the charged particle equilibrium in the plasma and leads to various phenomena. Argon plasma produced by DC glow discharge is investigated with a further goal of studying dusty plasma phenomena. The discharge system has two disc-shaped parallel plate electrodes. The electrodes are enclosed in a large cylindrical stainless steel chamber filled with argon gas. Two important physical parameters affecting the condition of the discharge are the gas pressure and the inter-electrode distance. A single Langmuir probe based on the Keithley source meter is used to determine the electron temperature of the positive column. A custom designed probe is employed to determine the potential distribution between the electrodes during the discharge. The I-V characteristic curve and the Langmuir probe measurement are then used to determine the electron energy distribution of the glow discharge plasma.

  13. Soliton solutions and chaotic motions of the Zakharov equations for the Langmuir wave in the plasma

    Energy Technology Data Exchange (ETDEWEB)

    Zhen, Hui-Ling; Tian, Bo, E-mail: tian-bupt@163.com; Wang, Yu-Feng; Liu, De-Yin [State Key Laboratory of Information Photonics and Optical Communications, and School of Science, Beijing University of Posts and Telecommunications, Beijing 100876 (China)

    2015-03-15

    For the interaction between the high-frequency Langmuir waves and low-frequency ion-acoustic waves in the plasma, the Zakharov equations are studied in this paper. Via the Hirota method, we obtain the soliton solutions, based on which the soliton propagation is presented. It is found that with λ increasing, the amplitude of u decreases, whereas that of v remains unchanged, where λ is the ion-acoustic speed, u is the slowly-varying envelope of the Langmuir wave, and v is the fluctuation of the equilibrium ion density. Both the head-on and bound-state interactions between the two solitons are displayed. We observe that with λ decreasing, the interaction period of u decreases, while that of v keeps unchanged. It is found that the Zakharov equations cannot admit any chaotic motions. With the external perturbations taken into consideration, the perturbed Zakharov equations are studied for us to see the associated chaotic motions. Both the weak and developed chaotic motions are investigated, and the difference between them roots in the relative magnitude of the nonlinearities and perturbations. The chaotic motions are weakened with λ increasing, or else, strengthened. Periodic motion appears when the nonlinear terms and external perturbations are balanced. With such a balance kept, one period increases with λ increasing.

  14. Luminescent Langmuir-Blodgett film of a new amphiphilic Eu3+ β-diketonate

    International Nuclear Information System (INIS)

    Gomes, Luciano F.; Oliveira, Kleber T. de; Neri, Claudio R.; Sousa Filho, Paulo C. de; Bianco, Marcos J. dal; Ramos, Ana P.; Zaniquelli, Maria E.D.; Serra, Osvaldo A.

    2008-01-01

    This work reports on the synthesis and characterization of the ligand 3-hexadecylpentane-2,4-dione (Hhdacac) and its Eu 3+ complexes Eu(hdacac) 6 .2H 2 O, Eu(hdacac) 6 .phen and Eu(hdacac) 6 .tta, where phen and tta denote 1,10-phenanthroline and thenoyltrifluoroacetone, respectively. These new compounds present long carbon chains and their expected miscibility into non-polar ambients is confirmed by the emission spectra of Eu(hdacac) 6 .tta in hexane. Moreover, the amphiphilic properties of Eu(hdacac) 6 complexes allow the obtainment of thin luminescent films by the Langmuir-Blodgett technique. In both cases (solids and films), the typical antenna effect of β-diketonates is observed. The alluring characteristics of these compounds raise great interest in many fields of Materials Science, like photo- and electro-luminescent materials (mainly thin 'organic' films), metal catalysts or probes in non-polar solutions, and Langmuir-Blodgett films of several compositions. For the characterization of these products, nuclear magnetic resonance spectroscopy ( 1 H NMR), thermogravimetric analysis, elementary analyses (C, H), scanning electron microscopy (energy dispersive X-ray spectroscopy), absorption (UV-vis/FT-IR) and photoluminescence spectroscopies were used

  15. The composite phthalocyanine-based Langmuir-Blodgett films: structural peculiarities and NO-sensitive properties

    Energy Technology Data Exchange (ETDEWEB)

    Emelianov, I.L.; Khatko, V.V. [Nat. Acad. of Sci., Minsk (Belarus). Phys. Tech. Inst.

    1999-10-08

    Surface pressure versus area per molecule isotherms of the Langmuir monolayers of copper tetra-tert-butyl phthalocyanine (abbreviated as CuTTBPc), arachidic acid (abbreviated as AA), and their mixtures were measured depending upon the film component ratio and ionic content of the subphase. Substantial deviations of the mixed monolayer behaviour from an ideal one, which is characteristic of fully immiscible compounds forming separate surface domains on the liquid subphase, were observed if the molar fraction of AA in mixed monolayers exceeded 50%. This abnormality in the monolayer behaviour correlated with the drastic changes in the kinetics responses to NO gas of the sensors based on the mixed Langmuir-Blodgett (LB) films. The comparison and analysis of the results obtained suggest that the gas-sensitive properties of the two-component LB films are determined by two features of their structure, namely, hole-like defects existing in the AA matrix and interlayer cavities. The corresponding structure model of the mixed films is proposed. The results obtained may be useful for understanding the gas-sensitive mechanism of the composite phthalocyanine-based LB films. (orig.)

  16. Description of two-metal biosorption equilibria by Langmuir-type models.

    Science.gov (United States)

    Chong, K H; Volesky, B

    1995-08-20

    A biosorbent prepared from Ascophyllum nodosum seaweed biomass, FCAN2, was examined for its sorption capacity. Equilibrium batch sorption studies were performed using two-matal systems containing either (Cu + Zn), (Cu + Cd), or (Zn + Cd). In the evaluation of the two-metal sorption system performance, simple isotherm curves had to be replaced by three-dimensional sorption isotherm surfaces. In order to describe the isotherm surfaces mathematically, three Langmuir-type models were evaluated. The apparent one-parameter Langmuir constant (b) was used to quantify FCAN2 "affinity" for one metal in the presence of another one. The uptake of Zn decreased drastically when Cu or Cd were present. The uptake of Cd wasmuch more sensitive to the presence of Cu than to that of Zn. The presence of Cd and Zn alter the "affinity" of FCAN2 for Cu the least at high Cu equilibrium concentrations. The mathematical model of the two-metal sorption system enabled quantitative estimation of one-metal (bio)sorption inhibition due to the influence of a second metal. (c) 1995 John Wiley & Sons Inc.

  17. Study of plasma-material surface interaction using Langmuir probe technique during plasma treatment

    International Nuclear Information System (INIS)

    Saloum, S.; Akel, M.

    2009-06-01

    In this study, we tried to understand the plasma-surface interactions by using Langmuir probes. Two different types of plasmas were studied, the first is the electropositive plasma in Argon and the second is the electronegative plasma in Sulfur Hexafluoride. In the first type, the effects of Argon gas pressure, the injection of Helium in the remote zone and the substrate bias on the measurements of the Electron Energy Probability Function (EEPF) and on the plasma parameters (electron density (n e ), effective electron temperature (T e ff), plasma potential (V p ) and floating potential (V f )) have been investigated. The obtained EEPFs and plasma parameters have been used to control two remote plasma processes. The first is the remote Plasma Enhanced Chemical Vapor Deposition (PE-CVD) of thin films, on silicon wafers, from Hexamethyldisoloxane (HMDSO) precursor diluted in the remote Ar-He plasma. The second is the pure Argon remote plasma treatment of polymethylmethacrylate (PMMA) polymer surface. In the second type, the plasma diagnostics were performed in the remote zone as a function of SF 6 flow rate, where relative concentrations of fluorine atoms were measured using actinometry optical emission spectroscopy; electron density, electron temperature and plasma potential were determined using single cylindrical Langmuir probe, positive ion flux and negative ion fraction were determined using an planar probe. The silicon etching process in SF 6 plasma was studied. (author)

  18. Study of plasma-material surface interaction using langmuir probe technique during plasma treatment

    International Nuclear Information System (INIS)

    Saloum, S.; Akel, M.

    2012-01-01

    In this study, we tried to understand the plasma-surface interactions by using Langmuir probes. Two different types of plasmas were studied, the first is the electropositive plasma in Argon and the second is the electronegative plasma in Sulfur Hexafluoride. In the first type, the effects of Argon gas pressure, the injection of Helium in the remote zone and the substrate bias on the measurements of the Electron Energy Probability Function (EEPF) and on the plasma parameters (electron density (n e ), effective electron temperature (T e ff), plasma potential (V p ) and floating potential (V f )) have been investigated. The obtained EEPFs and plasma parameters have been used to control two remote plasma processes. The first is the remote Plasma Enhanced Chemical Vapor Deposition (PE-CVD) of thin films, on silicon wafers, from Hexamethyldisiloxane (HMDSO) precursor diluted in the remote Ar-He plasma. The second is the pure Argon remote plasma treatment of polymethylmethacrylate (PMMA) polymer surface. In the second type, the plasma diagnostics were performed in the remote zone as a function of SF 6 flow rate, where relative concentrations of fluorine atoms were measured using actinometry optical emission spectroscopy; electron density, electron temperature and plasma potential were determined using single cylindrical Langmuir probe, positive ion flux and negative ion fraction were determined using an planar probe. The silicon etching process in SF 6 plasma was studied. (author)

  19. A theoretical model for the pyroelectric response in Langmuir-Blodgett films

    International Nuclear Information System (INIS)

    Capan, R.; Basaran, I.; Richardson, T.H.; Lacey, D.

    2002-01-01

    Understanding the structure of pyroelectric materials is important to elucidate the nature of the temperature-dependent microscopic and macroscopic electric polarisation. Pyroelectric materials must have a non-centrosymmetric structure. Previously, researchers [C.A. Jones, PhD thesis, University of Durham, (1987); J. Mater. Chem. 1 (1991) 819; Langmuir 11 (1995) 4623] have reported the pyroelectric effect of non-centrosymmetric ultrathin LB films prepared using the alternate layer Langmuir-Blodgett (LB) deposition technique. They have proposed three main mechanisms to explain the origin of the pyroelectric activity, namely, tilting, proton transfer, and ionic processes. Linear and cyclic polysiloxane materials with aliphatic and aromatic side groups have been studied in this work. These materials have been alternately deposited with eicosylamine to form the active pyroelectric material in metal-LB film-metal (MIM) devices, whose pyroelectric coefficients have been measured using a quasi-static measurement technique [W.H. Majid, Abd., PhD thesis, Univ. of Sheffield (1994); Mater. Sci. Eng., C, Biomim. Mater., Sens. Syst. 3 (1995) 197; Thin Solid Films 327-329 (1998) 369]. The relation between pyroelectric mechanism(s) and microscopic and macroscopic pyroelectric response for polysiloxane/eicosylamine alternate layer LB films will be explained in this work. Results indicate that the physical mechanism by which the pyroelectric activity arises in the LB films is critically dependent upon their structural quality, the ions within the multilayer arrangement and the molecular dipole moments of the molecules

  20. Langmuir probe measurement of the bismuth plasma plume formed by an extreme-ultraviolet pulsed laser

    International Nuclear Information System (INIS)

    Pira, P; Burian, T; Kolpaková, A; Tichý, M; Kudrna, P; Daniš, S; Wild, J; Juha, L; Lančok, J; Vyšín, L; Civiš, S; Zelinger, Z; Kubát, P

    2014-01-01

    Properties of the plasma plume produced on a bismuth (Bi) target irradiated by a focused extreme-ultraviolet (XUV) capillary-discharge laser beam were investigated. Langmuir probes were used in both single- and double-probe arrangements to determine the electron temperature and the electron density, providing values of 1–3 eV and ∼10 13 –10 14  m −3 , respectively. Although the temperatures seem to be comparable with values obtained in ablation plasmas produced by conventional, long-wavelength lasers, the density is significantly lower. This finding indicates that the desorption-like phenomena are responsible for the plume formation rather than the ablation processes. A very thin Bi film was prepared on an MgO substrate by pulsed XUV laser deposition. The non-uniform, sub-monolayer character of the deposited bismuth film confirms the Langmuir probe's observation of the desorption-like erosion induced by the XUV laser on the primary Bi target. (paper)

  1. Effect of temperature dependence of the Langmuir constant molecular pair potentials on gas hydrates formation mechanism

    Energy Technology Data Exchange (ETDEWEB)

    Mokhtari, B.; Enayati, M. [Iranian Offshore Oil Co., Tehran (Iran, Islamic Republic of); Heidaryan, E. [Islamic Azad Univ., Tehran (Iran, Islamic Republic of). Masjidosolayman Branch

    2008-07-01

    Theoretical methods show that crystalline hydrates can form from single-phase systems consisting of both vapor water with gaseous hydrate former and liquid water with dissolved hydrate former. Two phase systems consist of both liquid water with gaseous hydrate former and with liquid hydrate former on the surface. This paper presented a Langmuir constant related model for the prediction of equilibrium pressures and cage occupancies of pure component hydrates. Intermolecular potentials were fit to quantum mechanical energies to obtain the Langmuir constants, which differed from the procedure utilized with the vdWP model. The paper described the experimental method and model calculations. This included the Fugacity model and Van der Waals and Platteeuw model. The paper also discussed pair potential of non-spherical molecules, including the multicentre (site-site) potential; Gaussian overlap potential; Lennard-Jones potential; and Kihara generalized pair potential. It was concluded that fraction of occupied cavities is a function of pair potentials between hard core and empty hydrate lattice. These pair potentials could be calculated from some model as Kihara cell potential, Gaussian potential, Lennard-Jones potential and multicentre pair potential. 49 refs., 3 figs.

  2. Phase-mixing of Langmuir oscillations in cold electron-positron-ion plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Maity, Chandan [Saha Institute of Nuclear Physics, 1/AF Bidhannagar, Kolkata 700 064 (India)

    2014-07-15

    Space-time evolution of Langmuir oscillations in a cold homogeneous electron-positron-ion plasma has been analyzed by employing a straightforward perturbation expansion method, showing phase-mixing and, thus, wave-breaking of excited oscillations at arbitrary amplitudes. Within an assumption of infinitely massive ions, an approximate phase-mixing time is found to scale as ω{sub pe}t{sub mix}∼[(6/δ{sup 2})((2−α){sup 5/2}/(1−α))]{sup 1/3}, where “δ” and “α” (= n{sub 0i}/n{sub 0e}) are the amplitude of perturbation and the ratio of equilibrium ion density to equilibrium electron density, respectively, and ω{sub pe}∼√(4πn{sub 0e}e{sup 2}/m) is the electron plasma frequency. The results presented on phase-mixing of Langmuir modes in multispecies plasmas are expected to be relevant to laboratory and astrophysical environments.

  3. Immobilization of alcohol dehydrogenase in phospholipid Langmuir-Blodgett films to detect ethanol.

    Science.gov (United States)

    Caseli, Luciano; Perinotto, Angelo C; Viitala, Tapani; Zucolotto, Valtencir; Oliveira, Osvaldo N

    2009-03-03

    Enzyme immobilization in nanostructured films may be useful for a number of biomimetic systems, particularly if suitable matrixes are identified. Here we show that alcohol dehydrogenase (ADH) has high affinity toward a negatively charged phospholipid, dimyristoylphosphatidic acid (DMPA), which forms a Langmuir monolayer at an air-water interface. Incorporation of ADH into the DMPA monolayer was monitored with surface pressure measurements and polarization-modulation infrared reflection absorption spectroscopy, with the alpha-helices from ADH being mainly oriented parallel to the water surface. ADH remained at the interface even at high surface pressures, thus allowing deposition of Langmuir-Blodgett (LB) films from the DMPA-ADH film. Indeed, interaction with DMPA enhances the transfer of ADH, where the mass transferred onto a solid support increased from 134 ng for ADH on a Gibbs monolayer to 178 ng for an LB film with DMPA. With fluorescence spectroscopy it was possible to confirm that the ADH structure was preserved even after one month of the LB deposition. ADH-containing films deposited onto gold-interdigitated electrodes were employed in a sensor array capable of detecting ethanol at concentrations down to 10 ppb (in volume), using impedance spectroscopy as the method of detection.

  4. A seven harmonic actively compensated Langmuir probe for the GEC Cell

    Science.gov (United States)

    Goodyear, A.; Nolle, L.; Hopgood, A. A.; Picton, P. D.; Braithwaite, N.

    2001-10-01

    The uncertainty of Langmuir probe measurements in capacitively coupled discharges depends to a great extent on how well harmonic components in the plasma potential are accounted for. The extent to which individual harmonics distort a probe characteristic has been determined across power and pressure parameter-space in the GEC cell. Langmuir probe current-voltage measurements are distorted by RF components across the probe sheath. A seven harmonic waveform was applied to the probe tip to actively match that generated by the plasma. In some circumstances harmonics above the 3rd contributed RF components of the order of the electron temperature in magnitude. Measurement of the EEDF was found to be particularly sensitive to these components. Optimization of the applied waveform (seven amplitudes and seven phases) was achieved using artificially intelligent control. This is advantageous given the large number of (possibly interacting) parameters and permits tracking of changes in plasma conditions. An algorithm utilizing simulated annealing determines the optimum waveform in a far shorter time than a skilled human operator can.

  5. Numerical model of operation of the Langmuir probe under intermediate pressure

    International Nuclear Information System (INIS)

    Dudin, S.V.

    1996-01-01

    The technique of a Langmuir probe is known reasonably well. However, despite plenty of work devoted to calculation of currents on the probe inserted into plasma, a theory does not at present exist which would allow calculation of plasma parameters at any size of the probe and pressure of the working gas. While the theory of a probe in absence of collisions is developed rather in detail by Bernstain and Rabinovich, Laframboise, Allen, and others, there is no rigorous theory which describes a probe under high pressure of a gas. As for intermediate pressure, the theories are absent. Solution of the problem is in this case considerably complicated because of non-local dependence of density of charged particles on potential or electric field strength that means unusability of hydrodynamic approach and necessity of application of the kinetic theory. To fill in this gap the author has developed a numerical model of ion kinetics in a near-boundary layer of a Langmuir probe, inserted into a weakly-ionized gas-discharge plasma, in a range of intermediate pressure of a neutral gas as well as at any ratio between thickness of the layer of space charge and radius of the probe. On the base of results of modeling, practical technique of processing of pore characteristics at intermediate pressure is developed: (i) a technique of calculation of density of ions; (2) a technique of division of a probe current on electron and ion part

  6. A generalization of the child-langmuir relation for one-dimensional time-dependent diodes

    International Nuclear Information System (INIS)

    Kadish, A.; Jones, M.E.; Peter, W.

    1985-01-01

    The steady-state Child-Langmuir relation between current and applied voltage has been a basic principle upon which all modern diode physics has been based. With advances in pulsed power technology and diode design, new devices which operate in vastly different parameter regimes have recently become of interest. Many of these devices cannot be said to satisfy the strict requirements necessary for Child-Langmuir flow. For instance, in a recent pulsed electron device for use in high-current accelerators, the applied voltage is sinusoidal in time. In another case, development of sources for heavy ion fusion necessitates understanding of transient current oscillations when the voltage is applied abruptly. We derive the time-dependent relationship between the emitted current and time-dependent applied voltage in a nonrelativistic planar diode. The relationship is valid for arbitrary voltage shapes V(t) applied to the diode for times less than the beam-front transit time across the gap. Using this relationship, transient and time-dependent effects in the start-up phase of any nonrelativistic diode can be analyzed

  7. Optical storage in azobenzene-containing epoxy polymers processed as Langmuir Blodgett films

    International Nuclear Information System (INIS)

    Fernández, Raquel; Mondragon, Iñaki; Sanfelice, Rafaela C.; Pavinatto, Felippe J.; Oliveira, Osvaldo N.; Oyanguren, Patricia; Galante, María J.

    2013-01-01

    In this study, azocopolymers containing different main-chain segments have been synthesized with diglycidyl ether of bisphenol A (DGEBA, DER 332, n = 0.03) and the azochromophore Disperse Orange 3 (DO3) cured with two monoamines, viz. benzylamine (BA) and m-toluidine (MT). The photoinduced birefringence was investigated in films produced with these azopolymers using the spin coating (SC) and Langmuir Blodgett (LB) techniques. In the LB films, birefringence increased with the content of azochromophore and the film thickness, as expected. The nanostructured nature of the LB films led to an enhanced birefringence and faster dynamics in the writing process, compared to the SC films. In summary, the combination of azocopolymers and the LB method may allow materials with tuned properties for various optical applications, including in biological systems were photoisomerization may be used to trigger actions such as drug delivery. Highlights: ► Langmuir Blodgett (LB) films of epoxy-based azopolymers were obtained and analyzed. ► Optical properties of LB and spin coated (SC) films were compared. ► Azo content, structure, laser power and number of layers were main factors studied. ► LB films had larger free volume for the azobenzenes isomerization than SC. ► LB films led to higher birefringence and faster dynamics compared to SC

  8. Optical storage in azobenzene-containing epoxy polymers processed as Langmuir Blodgett films

    Energy Technology Data Exchange (ETDEWEB)

    Fernández, Raquel; Mondragon, Iñaki [‘Materials - Technologies’ Group, Department of Chemical and Environmental Engineering, Polytechnic School, Universidad País Vasco/Euskal Herriko Unibertsitatea, Pza Europa 1, 20018 Donostia-San Sebastián (Spain); Sanfelice, Rafaela C.; Pavinatto, Felippe J.; Oliveira, Osvaldo N. [Instituto de Física de São Carlos, Universidade de São Paulo, Av. Trabalhador São Carlense, 400, Centro, CEP 13560-970, São Carlos (Brazil); Oyanguren, Patricia [Institute of Materials Science and Technology (INTEMA), University of Mar del Plata and National Research Council (CONICET), J. B. Justo 4302, 7600 Mar del Plata (Argentina); Galante, María J., E-mail: galant@fi.mdp.edu.ar [Institute of Materials Science and Technology (INTEMA), University of Mar del Plata and National Research Council (CONICET), J. B. Justo 4302, 7600 Mar del Plata (Argentina)

    2013-04-01

    In this study, azocopolymers containing different main-chain segments have been synthesized with diglycidyl ether of bisphenol A (DGEBA, DER 332, n = 0.03) and the azochromophore Disperse Orange 3 (DO3) cured with two monoamines, viz. benzylamine (BA) and m-toluidine (MT). The photoinduced birefringence was investigated in films produced with these azopolymers using the spin coating (SC) and Langmuir Blodgett (LB) techniques. In the LB films, birefringence increased with the content of azochromophore and the film thickness, as expected. The nanostructured nature of the LB films led to an enhanced birefringence and faster dynamics in the writing process, compared to the SC films. In summary, the combination of azocopolymers and the LB method may allow materials with tuned properties for various optical applications, including in biological systems were photoisomerization may be used to trigger actions such as drug delivery. Highlights: ► Langmuir Blodgett (LB) films of epoxy-based azopolymers were obtained and analyzed. ► Optical properties of LB and spin coated (SC) films were compared. ► Azo content, structure, laser power and number of layers were main factors studied. ► LB films had larger free volume for the azobenzenes isomerization than SC. ► LB films led to higher birefringence and faster dynamics compared to SC.

  9. Cellulase and alcohol dehydrogenase immobilized in Langmuir and Langmuir-Blodgett films and their molecular-level effects upon contact with cellulose and ethanol.

    Science.gov (United States)

    Rodrigues, Dilmer; Camilo, Fernanda Ferraz; Caseli, Luciano

    2014-02-25

    The key challenges for producing devices based on nanostructured films with control over the molecular architecture are to preserve the catalytic activity of the immobilized biomolecules and to provide a reliable method for determining the intermolecular interactions and the accommodation of molecules at very small scales. In this work, the enzymes cellulase and alcohol dehydrogenase (ADH) were coimmobilized with dipalmitoylphosphatidylcholine (DPPC) as Langmuir-Blodgett (LB) films, and their biological activities were assayed by accommodating the structure formed in contact with cellulose. For this purpose, the polysaccharide was dissolved in an ionic liquid, 1-buthyl-3-methylimidazolium chloride (BMImCl), and dropped on the top of the hybrid cellulase-ADH-DPPC LB film. The interactions between cellulose and ethanol, which are the catalytic substrates of the enzymes as well as important elements in the production of second-generation fuels, were then investigated using polarization-modulation infrared reflection-absorption spectroscopy (PM-IRRAS). Investigation of the secondary structures of the enzymes was performed using PM-IRRAS, through which the presence of ethanol and cellulose was observed to highly affect the structures of ADH and cellulase, respectively. The detection of products formed from the catalyzed reactions as well as the changes of secondary structure of the enzymes immobilization could be carried out, which opens the possibility to produce a means for producing second-generation ethanol using nanoscale arrangements.

  10. Nonlinear generation of the fundamental radiation in plasmas: the influence of induced ion-acoustic and Langmuir waves

    International Nuclear Information System (INIS)

    Rizzato, F.B.

    1992-01-01

    A nonlinear emission mechanism of electromagnetic waves at the fundamental plasma frequency has been examined. This mechanism is based on the electromagnetic oscillating two-stream instability driven by two oppositely propagating Langmuir waves. The excitation of the electromagnetic oscillating two-stream instability is due to nonlinear wave-wave coupling involving Langmuir waves, low-frequency density waves and electromagnetic waves. The Chian and Alves model is improved using the generalized Zakharov equations. Attention is directed toward the influence of induced low-frequency and Langmuir waves on the properties of the electromagnetic oscillating two-stream instability. Presumably, the properties derived in the present context may be relevant to both space and laboratory plasmas. (author)

  11. PEMILIHAN ADSORBEN UNTUK PENJERAPAN KARBON MONOKSIDA MENGGUNAKAN MODEL ADSORPSI ISOTERMIS LANGMUIR

    Directory of Open Access Journals (Sweden)

    Yuliusman Yuliusman

    2013-11-01

    Full Text Available ADSORBENT SELECTION FOR CO ADSORPTION USING LANGMUIR ISOTHERMIC ADSORPTION MODEL. The objective of this research is to choose the adsorbent that can be applied to decrease toxicity level and to purify fire smoke. In case of fire, toxicity level is high due to carbon monoxide. Adsorbent is chosen based on its ability to adsorb carbon monoxide using volumetric method in constant temperature. Materials to be tested are natural zeolite, active carbon, TiO2, CuO, MgO. Due to existence of organic and mineral polluters, natural zeolite needs to be activated prior to adsorption test using fluoride acid (HF, chloride acid (HCl, ammonium chloride (NH4Cl and followed by calcination process. Result shows that activation of natural zeolite can increase Si/Al ratio and surface area. According to Langmuir adsorption model obtained, adsorption capacity of active carbon and natural zeolite are the highest. At 1 atmospheric pressure, adsorption capacity are 0.0682 mmol/g for active carbon, 0.0464 for activated natural zeolite with particle size of 400 nm, and 0.0265 mmol/g for activated natural zeolite with particle size of (37-50 μm. Penelitian ini bertujuan untuk memilih adsorben yang dapat diaplikasikan untuk menurunkan tingkat racun dan menjernihkan asap kebakaran. Pada kasus kebakaran tingkat racun asap disebabkan tingginya kandungan karbon monoksida. Proses pemilihan adsorben dilihat pada kemampuan adsorben mengadsorpsi karbon monoksida, yang dilakukan dengan metode volumetrik pada temperatur konstan. Material yang diuji adalah zeolit alam, karbon aktif, TiO2, CuO, MgO. Zeolit alam banyak terdapat pengotor baik organik maupun mineral, oleh karena itu sebelum dilakukan uji adsorpsi, zeolit alam terlebih dahulu diaktifasi menggunakan larutan asam florida (HF, asam khlorida (HCl dan larutan amonium khlorida (NH4Cl, dilanjutkan dengan proses kalsinasi. Hasil penelitian menunjukkan bahwa aktifasi zeolit alam dapat meningkatkan rasio Si/Al dan luas permukaan

  12. Characterization of Langmuir and Langmuir–Blodgett films of an octasubstituted zinc phthalocyanine

    International Nuclear Information System (INIS)

    Torrent-Burgués, J.; Cea, P.; Giner, I.; Guaus, E.

    2014-01-01

    In this work we report the fabrication of Langmuir and Langmuir–Blodgett (LB) films of a substituted ZnPc (octakis(oxyoctyl)phthalocyanine of zinc), and their characterization by means of several techniques. These characterization techniques include surface pressure (π-A) and surface potential (ΔV-A) isotherms as well as UV–vis Reflection spectroscopy and Brewster Angle Microscopy (BAM) for the films at the air–water interface together with UV–vis absorption and IR spectroscopies and Atomic Force Microscopy (AFM) for the LB films. The π-A and ΔV-A isotherms and BAM images indicate a phase transition at a surface pressure of ca. 9 mN/m and a multilayer formation at surface pressures around 19–20 mN/m; at a surface pressure around 27 mN/m a disordered collapse of the film occurs. In addition, AFM images of LB films at π = 10 mN/m and π = 20 mN/m show a monomolecular and a multilayered film, respectively. The comparison of the UV–vis spectrum of ZnPc in solution, the reflection spectra of the Langmuir films and UV–vis spectra of LB films reveals a significant reduction in the Q band intensity for the films, indicative of an organization of ZnPc in the Langmuir and LB films versus the random distribution in solution. The UV–vis Reflection spectra are also consistent with multilayer formation at surface pressures around 19–20 mN/m. The relative intensities of the IR spectrum bands change from the KBr pellet to the LB film which is also attributable to orientation effects in the film. Cyclic voltammetric experiments of LB films incorporating the ZnPc derivative show peaks that can be correlated with redox processes occurring in the phthalocyanine ring. A small but significant influence of the surface pressure and the number of deposited layers in the electrochemical behaviour is observed. The electrochemical response of cast films exhibits some differences with respect to that of LB films which have been attributed to their different molecular

  13. Characterization of Langmuir and Langmuir–Blodgett films of an octasubstituted zinc phthalocyanine

    Energy Technology Data Exchange (ETDEWEB)

    Torrent-Burgués, J. [Department of Chemical Engineering, Universitat Politècnica de Catalunya (UPC), C/Colom 1, 08222 Terrassa, Barcelona (Spain); Institut de Bioenginyeria de Catalunya (IBEC), 08028 Barcelona (Spain); Cea, P. [Departamento de Química Orgánica y Química Física, Facultad de Ciencias, Universidad de Zaragoza, 50009 Zaragoza (Spain); Instituto de Nanociencia de Aragón (INA) y Laboratorio de Microscopias Avanzadas (LMA), Edificio i+d, Campus Rio Ebro, Universidad de Zaragoza, C/Mariano Esquillor, s/n, 50017 Zaragoza (Spain); Giner, I. [Departamento de Química Orgánica y Química Física, Facultad de Ciencias, Universidad de Zaragoza, 50009 Zaragoza (Spain); Guaus, E. [Department of Chemical Engineering, Universitat Politècnica de Catalunya (UPC), C/Colom 1, 08222 Terrassa, Barcelona (Spain)

    2014-04-01

    In this work we report the fabrication of Langmuir and Langmuir–Blodgett (LB) films of a substituted ZnPc (octakis(oxyoctyl)phthalocyanine of zinc), and their characterization by means of several techniques. These characterization techniques include surface pressure (π-A) and surface potential (ΔV-A) isotherms as well as UV–vis Reflection spectroscopy and Brewster Angle Microscopy (BAM) for the films at the air–water interface together with UV–vis absorption and IR spectroscopies and Atomic Force Microscopy (AFM) for the LB films. The π-A and ΔV-A isotherms and BAM images indicate a phase transition at a surface pressure of ca. 9 mN/m and a multilayer formation at surface pressures around 19–20 mN/m; at a surface pressure around 27 mN/m a disordered collapse of the film occurs. In addition, AFM images of LB films at π = 10 mN/m and π = 20 mN/m show a monomolecular and a multilayered film, respectively. The comparison of the UV–vis spectrum of ZnPc in solution, the reflection spectra of the Langmuir films and UV–vis spectra of LB films reveals a significant reduction in the Q band intensity for the films, indicative of an organization of ZnPc in the Langmuir and LB films versus the random distribution in solution. The UV–vis Reflection spectra are also consistent with multilayer formation at surface pressures around 19–20 mN/m. The relative intensities of the IR spectrum bands change from the KBr pellet to the LB film which is also attributable to orientation effects in the film. Cyclic voltammetric experiments of LB films incorporating the ZnPc derivative show peaks that can be correlated with redox processes occurring in the phthalocyanine ring. A small but significant influence of the surface pressure and the number of deposited layers in the electrochemical behaviour is observed. The electrochemical response of cast films exhibits some differences with respect to that of LB films which have been attributed to their different molecular

  14. Comment on 'Extrinsic versus intrinsic ferroelectric switching: experimental investigations using ultra-thin PVDF Langmuir-Blodgett films'

    International Nuclear Information System (INIS)

    Naber, R C G; Blom, P W M; Leeuw, D M de

    2006-01-01

    Previous work on ultra-thin P(VDF-TrFE) Langmuir-Blodgett films has indicated a transition from extrinsic to intrinsic ferroelectric switching. The lack of several key features of intrinsic switching in the experimental work reported by Kliem et al argues against intrinsic switching. In this Comment we discuss two published papers and new experimental results that support a lack of intrinsic switching and point to the conclusion that the thickness dependence of the Langmuir-Blodgett films is due to the influence of the electrode interfaces. (comment)

  15. Behaviour of a planar Langmuir probe in a laser ablation plasma

    International Nuclear Information System (INIS)

    Doggett, B.; Budtz-Joergensen, C.; Lunney, J.G.; Sheerin, P.; Turner, M.M.

    2005-01-01

    We have investigated some aspects of the behaviour of planar Langmuir probes in the supersonic plasma flow produced by laser ablation of solid materials in vacuum. The ablation was done using a 26 ns, 248 nm excimer laser, irradiating a silver target at 1 J cm -2 . We have compared the behaviour of the probe when it is orientated perpendicular and parallel to the plasma flow. In particular, we have shown that it is possible to adapt an analytical model, developed for plasma immersion ion implantation, to quantitatively describe the variation of the ion current with probe bias for the case when the plasma flow is along the probe surface. The electron temperature was also measured

  16. Damping kinetics of annihilation slowed fluorescence of aromatic molecules in Langmuir films

    International Nuclear Information System (INIS)

    Ibraev, N.Kh.; Latonin, V.A.; Satybaldina, D.Zh.

    1996-01-01

    The paper is devoted to study of decay mechanism of phosphors molecules triplet states in the Langmuir-Blogett (L-B) films. The L-B-films have being prepared on the base of anthracene, pyrene, 3,4-benzopyrene and 1,2-benzanthracene molecules. Spectral and kinetic investigations were carried out in photons counting regime. Long-lived luminescence was observed under excitation of the LB-film by nitrogen laser radiation (λ=337 nm) .Spectrum of the long-lived luminescence coincides with spectrum of fast fluorescence of same film. Received spectral data indicate on similarity of LB-films structure of aromatic molecules and its crystals. It was defined, that deactivation of triplet states of aromatic molecules in LB-films has being carried out mainly in the result of annihilation of triplet excitation. 14 refs., 2 tabs., 5 figs

  17. Stochastic Growth Theory of Spatially-Averaged Distributions of Langmuir Fields in Earth's Foreshock

    Science.gov (United States)

    Boshuizen, Christopher R.; Cairns, Iver H.; Robinson, P. A.

    2001-01-01

    Langmuir-like waves in the foreshock of Earth are characteristically bursty and irregular, and are the subject of a number of recent studies. Averaged over the foreshock, it is observed that the probability distribution is power-law P(bar)(log E) in the wave field E with the bar denoting this averaging over position, In this paper it is shown that stochastic growth theory (SGT) can explain a power-law spatially-averaged distributions P(bar)(log E), when the observed power-law variations of the mean and standard deviation of log E with position are combined with the log normal statistics predicted by SGT at each location.

  18. Novel luminescent Langmuir-Blodgett films of europium complex embedded in titania matrix

    International Nuclear Information System (INIS)

    Zhang Li; Liu, H.-G.; Kang, S.-Z.; Mu, Y.-D.; Qian, D.-J.; Lee, Yong-Ill; Feng Xusheng

    2005-01-01

    A stable Eu(DBM) 3 (DB-bpy)/AA/TiO 2 monolayer was formed on the surface of a composite subphase by spreading an Eu(DBM) 3 (DB-bpy)/AA/TBT chloroform solution. DBM, DB-bpy, AA and TBT refer to dibenzoylmethanate, 4,4'-Di-tert-butyl-2,2'-bipyridine, arachidic acid and tetrabutyloxyltitanium, respectively. Eu(DBM) 3 (DB-bpy)/AA/TiO 2 Langmuir-Blodgett films were deposited on solid substrates and were characterized by low-angle X-ray diffractometry, UV-visible (UV refers to ultra-violet) spectroscopy, photoluminescent spectroscopy and electron probe microanalysis. The results show that a luminescent composite film with layered structure was fabricated, which shows characteristic emission of Eu(III)

  19. Study of an edge transport barrier by Langmuir probes in the compact helical system

    Energy Technology Data Exchange (ETDEWEB)

    Takeuchi, M [Department of Energy Engineering and Science, Nagoya University, Nagoya 464-8603 (Japan); Toi, K [National Institute of Fusion Science, Toki 509-5292 (Japan); Nagaoka, K [National Institute of Fusion Science, Toki 509-5292 (Japan); Suzuki, C [National Institute of Fusion Science, Toki 509-5292 (Japan); Minami, T [National Institute of Fusion Science, Toki 509-5292 (Japan); Akiyama, T [National Institute of Fusion Science, Toki 509-5292 (Japan); Isobe, M [National Institute of Fusion Science, Toki 509-5292 (Japan); Yoshimura, Y [National Institute of Fusion Science, Toki 509-5292 (Japan); Nishimura, S [National Institute of Fusion Science, Toki 509-5292 (Japan); Shimizu, A [National Institute of Fusion Science, Toki 509-5292 (Japan); Takahashi, C [National Institute of Fusion Science, Toki 509-5292 (Japan); Matsuoka, K [National Institute of Fusion Science, Toki 509-5292 (Japan); Okamura, S [National Institute of Fusion Science, Toki 509-5292 (Japan)

    2006-05-15

    The edge transport barrier (ETB) produced by the L-H transition was measured by a triple Langmuir probe (LP) at two toroidal sections of the compact helical system (CHS), of which diagnostic method has good time and spatial resolutions. The radial profiles of electron density (n{sub e}), electron temperature (T{sub e}) and space potential (V{sub s}) in the ETB region have different shapes at two different toroidal sections. These profiles are deformed inside the ETB region at one location and are formed with rather smooth variations at the other. These deformations gradually disappear in the deep H-phase (after {approx}15 ms from the transition) and the profiles inside the ETB become similar at both sections. The deformation seems linked to the presence of a non-rotating magnetic island at the rational surface of the rotational transform {iota}/2{pi} = 1.

  20. Extrinsic versus intrinsic ferroelectric switching: experimental investigations using ultra-thin PVDF Langmuir-Blodgett films

    International Nuclear Information System (INIS)

    Kliem, H; Tadros-Morgane, R

    2005-01-01

    Mechanisms of extrinsic and intrinsic switching phenomena in ferroelectrics are explained and existing models are summarized. Then, criteria for an experimental distinction between both models are elaborated. Samples with thicknesses ranging from 2.7 to 63.8 nm prepared by a Langmuir-Blodgett technique were investigated with respect to these criteria. Measurements of their polarization switching behaviour, their polarization hysteresis loops, and their coercive fields were carried out. It is found that the coercive fields increase with decreasing sample thickness. Also, the switching time increases with decreasing sample thickness and it increases with decreasing field strength. The switching process turns out to be thermally activated. We find that neither intrinsic nor extrinsic models are sufficient to describe the experimental situation

  1. Measurements of Ozone, Lightning, and Electric Fields within Thunderstorms over Langmuir Laboratory, New Mexico

    Science.gov (United States)

    Eack, K. B.; Winn, W. P.; Rust, W. D.; Minschwaner, K.; Fredrickson, S.; Kennedy, D.; Edens, H. E.; Kalnajs, L. E.; Rabin, R. M.; Lu, G. P.; Bonin, D.

    2008-12-01

    A field project was conducted at the Langmuir Laboratory for Atmospheric Research during the summer of 2008 in an effort to better understand the direct production of ozone within electrically active storms. Five balloon flights were successfully launched into thunderstorms during this project. In situ measurements from the balloon instrument package included ozone mixing ratio, electric field strength, meteorological variables, and GPS location and timing. Lightning discharges were identified within each storm using a ground based lightning mapping array. The data show that the instruments ascended through regions of high electric fields within the sampled storms, and in some cases the balloon was in very close proximity to lightning. Relationships between electric field, lightning, and ozone observed during these flights will be discussed.

  2. Moessbauer study of C18N/Fe Langmuir-Blodgett layers

    Energy Technology Data Exchange (ETDEWEB)

    Kuzmann, Erno [Institute of Chemistry, Eoetvoes Lorand University (Hungary); Telegdi, Judit [Institute of Nanochemistry and Catalysis, Chemical Research Center, HAS (Hungary); Nemeth, Zoltan, E-mail: hentes@chem.elte.hu; Vertes, Attila [Institute of Chemistry, Eoetvoes Lorand University (Hungary); Nyikos, Lajos [Institute of Nanochemistry and Catalysis, Chemical Research Center, HAS (Hungary)

    2012-03-15

    Langmuir-Blodgett (LB) films of octadecanoyl hydroxamic acid (C18N) complexed with Fe{sup 3 + } ions have been prepared at various subphase pH values. The LB films consisting of different number of layers were investigated by {sup 57}Fe conversion electron Moessbauer spectroscopy (CEM) at room temperature. The CEM detector contained a piece of {alpha}-iron, enriched with {sup 57}Fe, using as an internal standard. The Moessbauer pattern of the C18N/Fe LB films is a doublet with parameters {delta} = 0.35 mm/s and {Delta} = 0.74 mm/s. A gradual increase of the relative occurrence of the doublet compared to the sextet of the internal standard was observed with the increasing number of layers, indicating the nearly uniform distribution of Fe among the LB layers.

  3. Inorganic insertion compounds under the form of Langmuir-Blodgett films

    International Nuclear Information System (INIS)

    Zylberajch, Claire

    1989-01-01

    As the study of organic or mineral compounds under the form of thin layers showed that they are displaying very original properties with respect to massive compounds, this research thesis reports a work which aimed at obtaining mineral conductive materials under the form of extremely thin layers, notably metallic sulfides of mercury and cadmium. Synthesis is performed in soft conditions within an organic matrix produced by using the Langmuir-Blodgett technique with successive diffusions of mineral reactants. Salt formation is monitored by infrared spectroscopy. Physical properties of these compounds have been studied by various techniques (UV, visible, and IR spectroscopy, linear dichroism, X ray diffraction, X ray photoelectron spectrometry, conduction, and so on). Structural and electronic properties of these extremely thin films confirm that metallic sulfides adopt a lamellar geometry with molecular thickness. Conductivity and photo-conductivity are interpreted by means of a conventional band diagram [fr

  4. Langmuir Isotherm application to the competitive adsorption of Cadmium, Nickel and Zinc on a Bentonite

    International Nuclear Information System (INIS)

    Silva Giraldo, German Dario; Pinzon Bello, Jorge Alejo

    1999-01-01

    In the present work, it was studied the simultaneous adsorption of binary and ternary mixtures of cadmium, nickel and zinc ions in aqueous solution at 25oC over a bentonite from the Cauca Valley, in its native state as well as in its sodium homo ionic form. The Langmuir isotherm, initially introduced by Murali and Aylmore for the competitive adsorption of various adsorbents, adequately describes the simultaneous adsorption of the three ions over the studied bentonite. The lineal correlation coefficient is greater than 0.900 in the major part of the systems. The competitive effect was interpreted by means of the thermodynamic distribution coefficient, Kdm. The degree of adsorption in the binary mixtures is nickel > zinc, cadmium over the natural bentonite, and nickel > cadmium > zinc over the sodium homo ionic form, whereas in the ternary mixture the order Nickel > Cadmium > Zinc is found over both adsorbents

  5. Rocket-borne Langmuir probe response to an applied periodic potential

    International Nuclear Information System (INIS)

    Muralikrishna, P.; Abdu, M.A.; Kantor, I.J.

    1988-01-01

    A Langmuir Probe (LP) payload designed and developed at Instituto de Pesquisas Espaciais (INPE/MCT) was flown on-board a SONDA III rocket at 2259 hrs. (LST) on October 31, 1986 from the Centro de Lancamento da Barreira do Inferno in Natal, RN, Brazil, under a collaborative programme between INPE and Instituto de Atividades Espaciais (IAE/CTA). A sweep voltage varying between - IV and +4V in a period of about 2.6 seconds was applied to the LP sensor. As the applied voltage increased from -IV to +4V, the LP sensor current first showed an increase, reached a saturation level, and then, though the sensor potential increased towards a steady value, the current showed a systematic decrease. This sensor current characteristic also showed a clear dependence on altitude and hence on the ambient plasma parameters. Possible physical mechanisms responsible for these LP response characteristics are analysed and discussed here. (author) [pt

  6. Fractional-dimensional Child-Langmuir law for a rough cathode

    International Nuclear Information System (INIS)

    Zubair, M.; Ang, L. K.

    2016-01-01

    This work presents a self-consistent model of space charge limited current transport in a gap combined of free-space and fractional-dimensional space (F α ), where α is the fractional dimension in the range 0 < α ≤ 1. In this approach, a closed-form fractional-dimensional generalization of Child-Langmuir (CL) law is derived in classical regime which is then used to model the effect of cathode surface roughness in a vacuum diode by replacing the rough cathode with a smooth cathode placed in a layer of effective fractional-dimensional space. Smooth transition of CL law from the fractional-dimensional to integer-dimensional space is also demonstrated. The model has been validated by comparing results with an experiment.

  7. Structure and frictional properties of Langmuir-Blodgett films of Cu nanoparticles modified by dialkyldithiophosphate

    International Nuclear Information System (INIS)

    Xu Jun; Dai Shuxi; Cheng Gang; Jiang Xiaohong; Tao Xiaojun; Zhang Pingyu; Du Zuliang

    2006-01-01

    Langmuir-Blodgett (LB) films of dialkyldithiophosphate (DDP) modified Cu nanoparticles were prepared. The structure, microfrictional behaviors and adhesion of the LB films were investigated by transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS) and atomic/friction force microscopy (AFM/FFM). Our results showed that the modified Cu nanoparticles have a typical core-shell structure and fine film-forming ability. The images of AFM/FFM showed that LB films of modified Cu nanoparticles were composed of many nanoparticles arranged closely and orderly and the nanoparticles had favorable behaviors of lower friction. The friction loop of the films indicated that the friction force was affected prominently by the surface slope of the Cu nanoparticles and the microfrictional behaviors showed obvious 'ratchet effect'. The adhesion experiment showed that the modified Cu nanoparticle had a very small adhesive force

  8. Langmuir hydrogen dissociation approach in radiolabeling carbon nanotubes and graphene oxide

    International Nuclear Information System (INIS)

    Badun, Gennadii A.; Chernysheva, Maria G.; Eremina, Elena A.; Egorov, Alexander V.; Grigorieva, Anastasia V.

    2016-01-01

    Carbon-based nanomaterials have piqued the interest of several researchers. At the same time, radioactive labeling is a powerful tool for studying processes in different systems, including biological and organic; however, the introduction of radioactive isotopes into carbon-based nanomaterial remains a great challenge. We have used the Langmuir hydrogen dissociation method to introduce tritium in single-walled carbon nanotubes and graphene oxide. The technique allows us to achieve a specific radioactivity of 107 and 27 Ci/g for single-layer graphene oxide and single-walled carbon nanotubes, respectively. Based on the analysis of characteristic Raman modes at 1350 and 1580 cm -1 , a minimal amount of structural changes to the nanomaterials due to radiolabeling was observed. The availability of a simple, nondestructive, and economic technique for the introduction of radiolabels to single-walled carbon nanotubes and graphene oxide will ultimately expand the applicability of these materials.

  9. Langmuir-Blodgett films prepared from pre-formed cholestanic liquid-crystalline polymers

    Energy Technology Data Exchange (ETDEWEB)

    Tundo, P.; Hodge, P.; Valli, L.; Davis, F. (Venice Univ. (Italy). Dip. di Scienze Ambientali Lecce Univ. (Italy). Dip. di Scienza dei Materiali Manchester Univ. (United Kingdom). Dep. of Chemistry)

    1992-01-01

    A series of alternating copolymers of maleic anhydride and a-olefins functionalized through different alkyl chains with cholestanic groups were synthetised and derivatives prepared by reactions of the anhydride residues with methanol, water, dimethylamine and morpholine, respectively. The same starting functionalized a-olefins were used to prepare other suitable compounds in order to correlate the features of the liquid-crystalline behaviour of the mesogenic cholestanic group with the stability of the forthcoming polymeric or not polymeric Langmuir-Blodgett (LB) films. For some copolymers surface pressure against area per molecule isotherms are reported. In some multilayer (LB) films, the spacings between the layers were determined by the detection of BRAGG peaks by X-ray diffraction. The (LB) films of these polymers are closed packed, owing to either the polymeric skeleton or liquid-crystalline interaction.

  10. Structural studies of Langmuir-Blodgett films containing rare-earth metal cations

    DEFF Research Database (Denmark)

    Khomutov, G.B.; Antipina, M.N.; Bykov, I.V.

    2002-01-01

    Comparative structural study of gadolinium stearate Langmuir-Blodgett (LB) films formed by monolayer deposition from either aqueous gadolinium acetate or gadolinium chloride solutions have been carried out. Structure of the films was characterized by X-ray diffraction, Fourier transform infrared...... spectroscopy, high-energy electron diffraction, atomic force microscopy and scanning electron microscopy. It was found that when subphase pH had a value at which all monolayer stearic acid molecules were ionized and bound with Gd3+ cations (pH > 5), the LB films deposited from gadolinium acetate and gadolinium....... The data obtained indicate that the control of multivalent metal cations complexes formation in the subphase and at the monolayer surface can be an instrument for optimization, the conditions to form metal-containing LB film with regulated structure and properties....

  11. Circular patterns of calcium oxalate monohydrate induced by defective Langmuir-Blodgett film on quartz substrates

    Energy Technology Data Exchange (ETDEWEB)

    He Jieyu [Institute of Biomineralization and Lithiasis Research, Jinan University, Guangzhou 510632 (China); Institute of Biomineralization and Lithiasis Research, Jinan University, Guangzhou 510632 (China); Ouyang Jianming [Institute of Biomineralization and Lithiasis Research, Jinan University, Guangzhou 510632 (China); Institute of Biomineralization and Lithiasis Research, Jinan University, Guangzhou 510632 (China)], E-mail: toyjm@jnu.edu.cn

    2009-01-01

    The defective Langmuir-Blodgett (LB) film of dipalmitoylphosphatidylcholine (DPPC) on quartz injured by potassium oxalate (K{sub 2}C{sub 2}O{sub 4}) was used as a model system to induce growth of calcium oxalate crystals. Atomic force microscopy (AFM) indicated that circular defective domains with a diameter of 1-200 {mu}m existed in the LB film. Scanning electron microscopy (SEM) showed circular patterns of aggregated calcium oxalate monohydrate (COM) crystallites were induced by these defective domains. It was ascribed to that the interaction between the negatively-charged oxalate ions and the phosphatidyl groups in DPPC headgroups makes the phospholipid molecules rearranged and exist in an out-of-order state in the LB film, especially at the boundaries of liquid-condensed (LC)/liquid-expanded (LE) phases, which provide much more nucleating sites for COM crystals.

  12. Dispersion relation and growth rate of a relativistic electron beam propagating through a Langmuir wave wiggler

    Science.gov (United States)

    Zirak, H.; Jafari, S.

    2015-06-01

    In this study, a theory of free-electron laser (FEL) with a Langmuir wave wiggler in the presence of an axial magnetic field has been presented. The small wavelength of the plasma wave (in the sub-mm range) allows obtaining higher frequency than conventional wiggler FELs. Electron trajectories have been obtained by solving the equations of motion for a single electron. In addition, a fourth-order Runge-Kutta method has been used to simulate the electron trajectories. Employing a perturbation analysis, the dispersion relation for an electromagnetic and space-charge waves has been derived by solving the momentum transfer, continuity, and wave equations. Numerical calculations show that the growth rate increases with increasing the e-beam energy and e-beam density, while it decreases with increasing the strength of the axial guide magnetic field.

  13. Langmuir hydrogen dissociation approach in radiolabeling carbon nanotubes and graphene oxide

    Energy Technology Data Exchange (ETDEWEB)

    Badun, Gennadii A.; Chernysheva, Maria G.; Eremina, Elena A.; Egorov, Alexander V. [Lomonosov Moscow State Univ. (Russian Federation). Dept. of Chemistry; Grigorieva, Anastasia V. [Lomonosov Moscow State Univ., Moscow (Russian Federation). Dept. of Materials Science

    2016-11-01

    Carbon-based nanomaterials have piqued the interest of several researchers. At the same time, radioactive labeling is a powerful tool for studying processes in different systems, including biological and organic; however, the introduction of radioactive isotopes into carbon-based nanomaterial remains a great challenge. We have used the Langmuir hydrogen dissociation method to introduce tritium in single-walled carbon nanotubes and graphene oxide. The technique allows us to achieve a specific radioactivity of 107 and 27 Ci/g for single-layer graphene oxide and single-walled carbon nanotubes, respectively. Based on the analysis of characteristic Raman modes at 1350 and 1580 cm{sup -1}, a minimal amount of structural changes to the nanomaterials due to radiolabeling was observed. The availability of a simple, nondestructive, and economic technique for the introduction of radiolabels to single-walled carbon nanotubes and graphene oxide will ultimately expand the applicability of these materials.

  14. Self-organized dendritic patterns in the polymer Langmuir-Blodgett film

    Energy Technology Data Exchange (ETDEWEB)

    Matsui, Jun, E-mail: jun_m@tagen.tohoku.ac.j [Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, 2-1-1, Katahira, Aoba-ku Sendai, 980-8577 (Japan); Precursory Research for Embryonic Science and Technology (PRESTO), Japan Science and Technology Agency, 4-1-8, Honcho, Kawaguchi 332-0012 (Japan); Suzuki, Toshio; Mikayama, Takeshi [Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, 2-1-1, Katahira, Aoba-ku Sendai, 980-8577 (Japan); Aoki, Atsushi [Materials Science and Engineering, Graduate School of Engineering, Nagoya Institute of Technology Gokiso, Shouwa-ku, Nagoya 466-8555 (Japan); Miyashita, Tokuji [Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, 2-1-1, Katahira, Aoba-ku Sendai, 980-8577 (Japan)

    2011-01-03

    We report the formation of a self-organized dendritic pattern of nanometer thickness in polymer Langmuir-Blodgett (LB) films. Poly(N-dodecylacrylamide) (pDDA)/chloroform solution was spread on a water surface to form a stable polymer monolayer. A pDDA monolayer was deposited onto a hydrophilic silicon substrate by upward deposition from a water subphase, and a second layer was then deposited by downward deposition. The substrate with the two layers was withdrawn from a clean water surface at a high speed to form the dendritic pattern, which was imaged by atomic force microscopy. The height of the pattern, 3.5 nm, corresponds to the height of a bilayer pDDA LB film, suggesting that the pattern forms when the deposited outermost layer overturns by meniscus oscillation. A similar dendritic structure of narrower width and lower height was fabricated on a hydrophobic silicon substrate.

  15. Methods for the numerical calculation of the plasma potential from measured Langmuir probe characteristics

    International Nuclear Information System (INIS)

    Seifert, W.; Johanning, D.; Bankov, N.

    1986-01-01

    In a previous paper the results of the Langmuir probe experiment carried out on board of two INTERKOSMOS satellites have been described. The experiences have shown that the usage of high quality algorithms for analyzing the current-voltage-characteristics is necessary to yield real physical parameters. The key problem is the determination of the plasma potential. This paper reviews the different methods to determine the plasma potential especially under the circumstances of computer application. The test of the well developed methods shows, that for the evaluation of the applied methods a number of different factors, discussed in the following sections of this paper, has to be taken into account. The used test data are model values or real measurements obtained by the satellite missions IK-10, IK-18 and BULGARIA-1300. The computer procedures have been realized as FORTRAN-subroutines for the BESM 6 and ES 1040. (author)

  16. Langmuir probe measurements of the scrape-off plasma in ISX-A

    International Nuclear Information System (INIS)

    Namkung, W.; England, A.C.; Eldridge, O.C.

    1978-11-01

    A fixed double Langmuir probe was used to investigate the temporal behavior of the scrape-off plasma in the ISX-A tokamak. During gas puffing, the ion saturation current dropped rapidly to a very low level while the line average density showed a steady increase. This sudden transition was due mainly to a density change of more than a factor of five while the electron temperature remained relatively constant at approximately 10 eV. This behavior was easily observed at points away from the limiter with mild and moderate gas puffing rates, and near the inner edge of the limiter with strong gas puffing. In order to explain the phenomenon, it is suggested that there may be two distinct layers in the scrape-off plasma and that the boundary between the layers moves inward toward the limiter. The existence of the boundary has been confirmed indirectly by sudden shifts of the plasma during feedback control experiments

  17. Molecular recognition applied to gas detection: the contribution of Langmuir-Blodgett films

    International Nuclear Information System (INIS)

    Clemendot, Sylvain

    1992-01-01

    In the first part of this research thesis, the author presents the Langmuir-Blodgett technique and outlines how it can face the challenge of molecular electronics. Then, he proposes an overview of the state-of-the-art of chemical sensors based on LB films, and an assessment of the state of the art of conductive LB films based on TCNQ (tetracyanoquinodimethane) and on tetrathiafulvalene for which the author proposes a modelling. He describes how phosphine sensors with varying conductivity based on TCNQ-based conductive LB films have been developed and reports the study of electric performance of these sensors. He describes and compares mechanisms of interaction of phosphine with conductive LB films for films based on TCNQ and those based on tetrathiafulvalene [fr

  18. Stirring competes with chemical induction in chiral selection of Langmuir monolayer domains

    Directory of Open Access Journals (Sweden)

    Petit-Garrido Nuria

    2013-08-01

    Full Text Available Chirality, the absence of mirror symmetry, can be equally invoked in relation to physical forces and chemical induction processes, yet a competition between these two types of influences is rarely reported. Here, we employ Langmuir monolayers of azobenzene surfactants as a prototypical self-assembled two-dimensional system in which chiral selection is controlled by the combined independent action of a chiral dopant and vortical stirring. The two effects can be arbitrarily coupled, either constructively or destructively, leading to a situation of perfect compensation. The induced enantiomorphic excess is measured in terms of the statistical imbalance of an ensemble of sub-millimeter monolayer domains, where achiral molecules self-assemble with a well-defined orientational chirality, which is unambiguously resolved using Brewster angle microscopy.

  19. Child-Langmuir flow in a planar diode filled with charged dust impurities

    International Nuclear Information System (INIS)

    Tang Xiaoyan; Shukla, Padma Kant

    2008-01-01

    The Child-Langmuir (CL) flow in a planar diode in the presence of stationary charged dust particles is studied. The limiting electron current density and other diode properties, such as the electrostatic potential, the electron flow speed, and the electron number density, are calculated analytically. A comparison of the results with the case without dust impurities reveals that the diode parameters mentioned above decrease with the increase of the dust charge density. Furthermore, it is found that the classical scaling of D -2 (the gap spacing D) for the CL current density remains exactly valid, while the scaling of V 3/2 (the applied gap voltage V) can be a good approximation for low applied gap voltage and for low dust charge density

  20. Design and fabrication of an actively cooled Langmuir probe for long pulse applications

    International Nuclear Information System (INIS)

    Paterson, J.A.; Biagi, L.A.; Ehlers, K.W.; Koehler, G.W.

    1985-11-01

    The details of the mechanical design and fabrication for a Langmuir Probe for the continuous monitoring of plasma density are given. The probe was designed for use as a diagnostic tool in the development of long pulse positive ion plasma sources for use on neutral beam systems. The essential design feature of this probe is the incorporation of two electrically isolated cooling water circuits which actively cool the probe tip and probe jacket. The electrical isolation is required to prevent drain currents from the probe body disturbing the measurement of the probe tip current and thereby the plasma density measurement. The successful realization of the design requires precision components and vacuum tight ceramic to refractory metal brazes. To date this design has successfully operated in steady-state in plasma densities up to 250 mA/cm 2 and surface heat fluxes of 25 W/cm 2

  1. Fractional-dimensional Child-Langmuir law for a rough cathode

    Energy Technology Data Exchange (ETDEWEB)

    Zubair, M., E-mail: muhammad-zubair@sutd.edu.sg; Ang, L. K., E-mail: ricky-ang@sutd.edu.sg [SUTD-MIT International Design Centre, Singapore University of Technology and Design, Singapore 487372 and Engineering Product Development, Singapore University of Technology and Design, Singapore 487372 (Singapore)

    2016-07-15

    This work presents a self-consistent model of space charge limited current transport in a gap combined of free-space and fractional-dimensional space (F{sup α}), where α is the fractional dimension in the range 0 < α ≤ 1. In this approach, a closed-form fractional-dimensional generalization of Child-Langmuir (CL) law is derived in classical regime which is then used to model the effect of cathode surface roughness in a vacuum diode by replacing the rough cathode with a smooth cathode placed in a layer of effective fractional-dimensional space. Smooth transition of CL law from the fractional-dimensional to integer-dimensional space is also demonstrated. The model has been validated by comparing results with an experiment.

  2. Large-sized and highly radioactive 3H and 109Cd Langmuir-Blodgett films

    International Nuclear Information System (INIS)

    Shibata, S.; Kawakami, H.; Kato, S.

    1994-02-01

    A device for the deposition of a radioactive Langmuir-Blodgett (LB) film was developed with the use of: (1) a modified horizontal lifting method, (2) an extremely shallow trough, and (3) a surface pressure-generating system without piston oil. It made a precious radioactive subphase solution repeatedly usable while keeping its radioactivity concentration as high as possible. Any large-size thin films can be prepared by just changing the trough size. Two monomolecular-layers of Y-type films of cadmium [ 3 H] icosanoate and 109 Cd icosanoate were built up as 3 H and 109 Cd β-sources for electron spectroscopy with intensities of 1.5 GBq (40 mCi) and 7.4 MBq (200 μCi), respectively, and a size of 65x200 mm 2 . Excellent uniformity of the distribution of deposited radioactivity was confirmed by autoradiography and photometry. (author)

  3. Numerical Simulation of the Interaction between Phosphorus and Sediment Based on the Modified Langmuir Equation

    Directory of Open Access Journals (Sweden)

    Pengjie Hu

    2018-06-01

    Full Text Available Phosphorus is the primary factor that limits eutrophication of surface waters in aquatic environments. Sediment particles have a strong affinity to phosphorus due to the high specific surface areas and surface active sites. In this paper, a numerical model containing hydrodynamics, sediment, and phosphorus module based on improved Langmuir equation is established, where the processes of adsorption and desorption are considered. Through the statistical analysis of the physical experiment data, the fitting formulas of two important parameters in the Langmuir equation are obtained, which are the adsorption coefficient, ka, and the ratio k between the adsorption coefficient and the desorption coefficient. In order to simulate the experimental flume and get a constant and uniform water flow, a periodical numerical flume is built by adding a streamwise body force, Fx. The adsorbed phosphorus by sediment and the dissolved phosphorus in the water are separately added into the Advection Diffusion equation as a source term to simulate the interaction between them. The result of the numerical model turns out to be well matched with that of the physical experiment and can thus provide the basis for further analysis. With the application of the numerical model to some new and relative cases, the conclusion will be drawn through an afterwards analysis. The concentration of dissolved phosphorus proves to be unevenly distributed along the depth and the maximum value approximately appears in the 3/4 water depth because both the high velocity in the top layer and the high turbulence intensity in the bottom layer can promote sediment adsorption on phosphorus.

  4. Assessment of the effect of parallel temperature gradients in the JET SOL on Te measured by divertor target Langmuir probes

    NARCIS (Netherlands)

    Ďuran, I.; Ješko, K.; Fuchs, V.; Groth, M.; Guillemaut, C.; Gunn, J.P.; Horáček, J.; Pitts, R.A.; Tskhakaya, D.

    2015-01-01

    Abstract Higher than expected electron temperatures (Te) are often measured by divertor Langmuir probes (LP) in high recycling and detached regimes in JET and other tokamaks. As a possible mechanism to explain this discrepancy, we investigate the effect of penetration of fast, almost collisionless

  5. Comment on 'extrinsic versus intrinsic ferroelectric switching : experimental investigations using ultra-thin PVDF Langmuir-Blodgett films'

    NARCIS (Netherlands)

    Naber, R.C.G.; Blom, P.W.M.; de Leeuw, DM

    2006-01-01

    Previous work on ultra-thin P(VDF-TrFE) Langmuir-Blodgett films has indicated a transition from extrinsic to intrinsic ferroelectric switching. The lack of several key features of intrinsic switching in the experimental work reported by Kliem et al argues against intrinsic switching. In this Comment

  6. Antibacterial and Antibiofouling Properties of Light Triggered Fluorescent Hydrophobic Carbon Quantum Dots Langmuir-Blodgett Thin Films

    Czech Academy of Sciences Publication Activity Database

    Stanković, N. K.; Bodik, M.; Šiffalovič, P.; Kotlár, M.; Mičušik, M.; Špitalsky, Z.; Danko, M.; Milivojević, D. D.; Kleinová, A.; Kubát, Pavel; Capáková, Z.; Humpolíček, P.; Lehocký, M.; Todorović Marković, B. M.; Marković, Z. M.

    2018-01-01

    Roč. 6, č. 3 (2018), s. 4154-4163 ISSN 2168-0485 R&D Projects: GA ČR(CZ) GA17-05095S Institutional support: RVO:61388955 Keywords : Hydrophobic carbon quantum dots * Langmuir-Blodgett thin films * Photodynamic therapy * Singlet oxygen Subject RIV: CF - Physical ; Theoretical Chemistry OBOR OECD: Physical chemistry Impact factor: 5.951, year: 2016

  7. A quasi-time-resolved CryoTEM study of the nucleation of CaCO3 under Langmuir monolayers

    NARCIS (Netherlands)

    Pichon, B.P.R.; Bomans, P.H.H.; Frederik, P.M.; Sommerdijk, N.A.J.M.

    2008-01-01

    Calcium carbonate biomineralization uses complex assemblies of macromolecules that control the nucleation, growth, and positioning of the mineral with great detail. To investigate the mechanisms involved in these processes, for many years Langmuir monolayers have been used as model systems. Here, we

  8. Incident Information Management Tool

    CERN Document Server

    Pejovic, Vladimir

    2015-01-01

    Flaws of\tcurrent incident information management at CMS and CERN\tare discussed. A new data\tmodel for future incident database is\tproposed and briefly described. Recently developed draft version of GIS-­‐based tool for incident tracking is presented.

  9. A Statistical Analysis of Langmuir Wave-Electron Correlations Observed by the CHARM II Auroral Sounding Rocket

    Science.gov (United States)

    Dombrowski, M. P.; Labelle, J. W.; Kletzing, C.; Bounds, S. R.; Kaeppler, S. R.

    2014-12-01

    Langmuir-mode electron plasma waves are frequently observed by spacecraft in active plasma environments such as the ionosphere. Ionospheric Langmuir waves may be excited by the bump-on-tail instability generated by impinging beams of electrons traveling parallel to the background magnetic field (B). The Correlation of High-frequencies and Auroral Roar Measurement (CHARM II) sounding rocket was launched into a substorm at 9:49 UT on 17 February 2010, from the Poker Flat Research Range in Alaska. The primary instruments included the University of Iowa Wave-Particle Correlator (WPC), the Dartmouth High-Frequency Experiment (HFE), several charged particle detectors, low-frequency wave instruments, and a magnetometer. The HFE is a receiver system which effectively yields continuous (100% duty cycle) electric-field waveform measurements from 100 kHz to 5 MHz, and which had its detection axis aligned nominally parallel to B. The HFE output was fed on-payload to the WPC, which uses a phase-locked loop to track the incoming wave frequency with the most power, then sorting incoming electrons at eight energy levels into sixteen wave-phase bins. CHARM II encountered several regions of strong Langmuir wave activity throughout its 15-minute flight, and the WPC showed wave-lock and statistically significant particle correlation distributions during several time periods. We show results of an in-depth analysis of the CHARM II WPC data for the entire flight, including statistical analysis of correlations which show evidence of direct interaction with the Langmuir waves, indicating (at various times) trapping of particles and both driving and damping of Langmuir waves by particles. In particular, the sign of the gradient in particle flux appears to correlate with the phase relation between the electrons and the wave field, with possible implications for the wave physics.

  10. Synthesis and spectral properties of preorganized BODIPYs in solutions and Langmuir-Schaefer films

    Science.gov (United States)

    Marfin, Yuriy S.; Usoltsev, Sergey D.; Kazak, Alexandr V.; Smirnova, Antonina I.; Rumyantsev, Evgeniy V.; Molchanov, Evgeniy E.; Kuznetsov, Vladimir V.; Chumakov, Alexey S.; Glukhovskoy, Evgeny G.

    2017-12-01

    In order to investigate the influence of molecular structure peculiarities of boron-dipyrrine dyes (BODIPYs) on their properties in solutions and supramolecular organization in Langmuir-Schaefer (LS) films, four new BODIPY dyes with various aliphatic, aromatic or mixed nature meso-subtituents were synthesized and investigated. Spectral characteristics (electronic absorption and fluorescence) of the synthesized compounds in organic solvents and LS-films were studied. Floating monolayers of the BODIPYs were formed from chloroform solutions placed onto water subphase in Langmuir-Blodgett through. Thin films were prepared using the Langmuir-Schaefer technique by the transfer of floating monolayers onto standard polished glass, ITO covered glass or pure silicon substrate. The variation of the dye structure we consider as a preorganization aiming to influence the structure of LS-films. The morphology and structure of the LS-films was examined by fluorescent microscopy, scanning electron microscopy, atomic force microscopy and small angle X-ray diffraction analysis. It was found that the introduced substituents have no substantial influence on the position of the absorption and fluorescence bands in dilute solutions. In contrast, the fluorescent characteristics of the LS-films significantly depend on the substituent nature. Therefore, this strategy could be used for the direct tuning of compounds fluorescent properties in LS-films. Concerning the LS-film surface characteristics it was proved that the films are homogeneous, without disruptions and only some widely-spaced microcrystals could be observed. With respect to the LS-film structure, the change of the substituents introduced to the BODIPY molecule did not influence the average given periodicity of layers (d = 0.3-0.4 nm). This value corresponds to a single-layer arrangement of BODIPY molecules located parallel to the substrate surface. Nevertheless, the diffraction peak intensities depended on the molecular

  11. The spherical segmented Langmuir probe in a flowing thermal plasma: numerical model of the current collection

    Directory of Open Access Journals (Sweden)

    E. Séran

    2005-07-01

    Full Text Available The segmented Langmuir probe (SLP has been recently proposed by one of the authors (Lebreton, 2002 as an instrument to derive the bulk velocity of terrestrial or planetary plasmas, in addition to the electron density and temperature that are routinely measured by Langmuir probes. It is part of the scientific payload on the DEMETER micro-satellite developed by CNES. The basic concept of this probe is to measure the current distribution over the surface using independent collectors under the form of small spherical caps and to use the angular anisotropy of these currents to obtain the plasma bulk velocity in the probe reference frame. In order to determine the SLP capabilities, we have developed a numerical PIC (Particles In Cell model which provides a tool to compute the distribution of the current collected by a spherical probe. Our model is based on the simultaneous determination of the charge densities in the probe sheath and on the probe surface, from which the potential distribution in the sheath region can be obtained. This method is well adapted to the SLP problem and has some advantages since it provides a natural control of the charge neutrality inside the simulation box, allows independent mesh sizes in the sheath and on the probe surface, and can be applied to complex surfaces. We present in this paper initial results obtained for plasma conditions corresponding to a Debye length equal to the probe radius. These plasma conditions are observed along the Demeter orbit. The model results are found to be in very good agreement with those published by Laframboise (1966 for a spherical probe in a thermal non-flowing plasma. This demonstrates the adequacy of the computation method and of the adjustable numerical parameters (size of the numerical box and mesh, time step, number of macro-particles, etc. for the considered plasma-probe configuration. We also present the results obtained in the case of plasma flowing with mesothermal conditions

  12. The spherical segmented Langmuir probe in a flowing thermal plasma: numerical model of the current collection

    Directory of Open Access Journals (Sweden)

    E. Séran

    2005-07-01

    Full Text Available The segmented Langmuir probe (SLP has been recently proposed by one of the authors (Lebreton, 2002 as an instrument to derive the bulk velocity of terrestrial or planetary plasmas, in addition to the electron density and temperature that are routinely measured by Langmuir probes. It is part of the scientific payload on the DEMETER micro-satellite developed by CNES. The basic concept of this probe is to measure the current distribution over the surface using independent collectors under the form of small spherical caps and to use the angular anisotropy of these currents to obtain the plasma bulk velocity in the probe reference frame. In order to determine the SLP capabilities, we have developed a numerical PIC (Particles In Cell model which provides a tool to compute the distribution of the current collected by a spherical probe. Our model is based on the simultaneous determination of the charge densities in the probe sheath and on the probe surface, from which the potential distribution in the sheath region can be obtained. This method is well adapted to the SLP problem and has some advantages since it provides a natural control of the charge neutrality inside the simulation box, allows independent mesh sizes in the sheath and on the probe surface, and can be applied to complex surfaces. We present in this paper initial results obtained for plasma conditions corresponding to a Debye length equal to the probe radius. These plasma conditions are observed along the Demeter orbit. The model results are found to be in very good agreement with those published by Laframboise (1966 for a spherical probe in a thermal non-flowing plasma. This demonstrates the adequacy of the computation method and of the adjustable numerical parameters (size of the numerical box and mesh, time step, number of macro-particles, etc. for the considered plasma-probe configuration. We also present the results obtained in the case of plasma flowing with mesothermal conditions

  13. Some simple ideas on x-ray reflection and grazing-incidence diffraction from thin surfactant films

    DEFF Research Database (Denmark)

    Kjær, K.

    1994-01-01

    For Langmuir films of long linear amphiphilic molecules at the air-water interface, grazing-incidence diffraction data resolved in terms of both the horizontal and vertical components of the scattering angle can be evaluated to a fair level of detail by means of a slide rule. Specular reflection ...... data require more sophisticated means although some rules of thumb can be formulated.......For Langmuir films of long linear amphiphilic molecules at the air-water interface, grazing-incidence diffraction data resolved in terms of both the horizontal and vertical components of the scattering angle can be evaluated to a fair level of detail by means of a slide rule. Specular reflection...

  14. Bovine insulin-phosphatidylcholine mixed Langmuir monolayers: behavior at the air-water interface.

    Science.gov (United States)

    Pérez-López, S; Blanco-Vila, N M; Vila-Romeu, N

    2011-08-04

    The behavior of the binary mixed Langmuir monolayers of bovine insulin (INS) and phosphatidylcholine (PC) spread at the air-water interface was investigated under various subphase conditions. Pure and mixed monolayers were spread on water, on NaOH and phosphate-buffered solutions of pH 7.4, and on Zn(2+)-containing solutions. Miscibility and interactions between the components were studied on the basis of the analysis of the surface pressure (π)-mean molecular area (A) isotherms, surface compression modulus (C(s)(-1))-π curves, and plots of A versus mole fraction of INS (X(INS)). Our results indicate that intermolecular interactions between INS and PC depend on both the monolayer state and the structural characteristics of INS at the interface, which are strongly influenced by the subphase pH and salt content. Brewster angle microscopy (BAM) was applied to investigate the peptide aggregation pattern at the air-water interface in the presence of the studied lipid under any experimental condition investigated. The influence of the lipid on the INS behavior at the interface strongly depends on the subphase conditions.

  15. Characterisation of target plasma required for REB-plasma interaction studies using cylindrical Langmuir probes

    International Nuclear Information System (INIS)

    Roychowdhury, P.; Paithankar, A.S.; Iyyengar, S.K.; Rohatgi, V.K.

    1987-01-01

    The target plasma required for relativistic electron beam (REB)-plasma interaction studies has been generated by coaxial plasma gun. The measurement of electron density and temperature has been carried out using cylindrical Langmuir probes. Probes both oriented parallel and transverse to the flow have been used. The spatial as well as temporal variation of electron density and temperature have been studied. The typical electron density and temperature measured by probe were in the range of 9.0-3.5 x 10 13 cm -3 and 5-7 eV respectively. The typical e-folding decay time of density was 6.2 μs, while no appreciable change in electron temperature was observed until 10 μs after the peak density. The density decays by about 50% at distance of 30 cm from the gun. The plasma flow velocity has been measured by the time of flight technique and was found to be 2.5 x 10 6 cm s -1 . The plasma radius measured by dosimeter film, at distance of 30 cm from the gun was 3 cm. (author)

  16. Solving the Capacitive Effect in the High-Frequency sweep for Langmuir Probe in SYMPLE

    International Nuclear Information System (INIS)

    Pramila; Patel, J J; Rajpal, R; Hansalia, C J; Anitha, V P; Sathyanarayana, K

    2017-01-01

    Langmuir Probe based measurements need to be routinely carried out to measure various plasma parameters such as the electron density (n e ), the electron temperature (T e ), the floating potential (V f ), and the plasma potential (V p ). For this, the diagnostic electronics along with the biasing power supplies is installed in standard industrial racks with a 2KV isolation transformer. The Signal Conditioning Electronics (SCE) system is populated inside the 4U-chassis based system with the front-end electronics, designed using high common mode differential amplifiers which can measure small differential signal in presence of high common mode dc- bias or ac ramp voltage used for biasing the probes. DC-biasing of the probe is most common method for getting its I-V characteristic but method of biasing the probe with a sweep at high frequency encounters the problem of corruption of signal due to capacitive effect specially when the sweep period and the discharge time is very fast and die down in the order of μs or lesser. This paper presents and summarises the method of removing such effects encountered while measuring the probe current. (paper)

  17. Improvement of density control by feedback on Langmuir probe signals in Tore Supra

    International Nuclear Information System (INIS)

    Gunn, J.; Bucalossi, J.; Costanzo, L.; Grisolia, C.; Ghendrih, Ph.; Grosman, A.; Loarer, T.; Martin, G.; Monier-Garbet, P.; Moulin, D.; Pascal, J.Y.; Saint-Laurent, F.

    1999-12-01

    Real time control of deuterium or helium gas injection by feedback on Langmuir probe signals is implemented in Tore Supra ergodic divertor discharges. The feedback schemes are based on the robust experimental observation that the density limit coincides with edge temperature T e ∼ 10 eV. Three control algorithms are used: (1) proportional feedback on the central line-averaged density with real-time attenuation of the system gain and security cut-off of the gas injection if the edge temperature becomes too low; (2) proportional feedback on the central line-averaged density with security cut-off controlled by the degree of detachment (DoD); (3) proportional feedback on edge temperature with security cut-off on the DoD. The DoD is defined for deuterium discharges, but not for helium since those do not detach. All three feedback modes permit operation close to the density limit and have been successfully applied for plasma currents 0.4 p p =1.4 MA with up to 4 MW of ICRH power. (author)

  18. NOAA-MMS joint Langmuir circulation and oil spill trajectory models workshop

    International Nuclear Information System (INIS)

    Simecek-Beatty, D.; Lehr, W.

    2000-01-01

    An NOAA/HAZMAT workshop was held in October 1999 which provided an opportunity for 14 spill response officials to discuss the scientific theory of Langmuir Circulation (LC) and to determine ways that it affects oil spreading, dispersion and transport. The workshop helped identify potential modifications to existing oil spill trajectory models. LC is a result of the interaction between wind-driven surface currents and waves. This interaction causes vortices in the surface mixed layer of the water body. The vortices are aligned in the general direction of the wind. The surface water between the vortices either diverges or converges. For cleanup purposes and remote sensing it is necessary to incorporate LC into most oil and spill trajectory and behavior models. It was determined it should be possible to build simple models to predict the intensity of LC since current knowledge suggests that LC is forced by wind and waves. A prediction equation would be of tremendous use to oil spill response personnel. 39 refs., 1 tab., 1 fig

  19. High-resolution disruption halo current measurements using Langmuir probes in Alcator C-Mod

    Science.gov (United States)

    Tinguely, R. A.; Granetz, R. S.; Berg, A.; Kuang, A. Q.; Brunner, D.; LaBombard, B.

    2018-01-01

    Halo currents generated during disruptions on Alcator C-Mod have been measured with Langmuir ‘rail’ probes. These rail probes are embedded in a lower outboard divertor module in a closely-spaced vertical (poloidal) array. The dense array provides detailed resolution of the spatial dependence (~1 cm spacing) of the halo current distribution in the plasma scrape-off region with high time resolution (400 kHz digitization rate). As the plasma limits on the outboard divertor plate, the contact point is clearly discernible in the halo current data (as an inversion of current) and moves vertically down the divertor plate on many disruptions. These data are consistent with filament reconstructions of the plasma boundary, from which the edge safety factor of the disrupting plasma can be calculated. Additionally, the halo current ‘footprint’ on the divertor plate is obtained and related to the halo flux width. The voltage driving halo current and the effective resistance of the plasma region through which the halo current flows to reach the probes are also investigated. Estimations of the sheath resistance and halo region resistivity and temperature are given. This information could prove useful for modeling halo current dynamics.

  20. Ionic channels in Langmuir-Blodgett films imaged by a scanning tunneling microscope.

    Science.gov (United States)

    Kolomytkin, O V; Golubok, A O; Davydov, D N; Timofeev, V A; Vinogradova, S A; Tipisev SYa

    1991-01-01

    The molecular structure of channels formed by gramicidin A in a lipid membrane was imaged by a scanning tunneling microscope operating in air. The mono- and bimolecular films of lipid with gramicidin A were deposited onto a highly oriented pyrolitic graphite substrate by the Langmuir-Blodgett technique. It has been shown that under high concentration gramicidin A molecules can form in lipid films a quasi-regular, densely packed structure. Single gramicidin A molecules were imaged for the first time as well. The cavity of 0.4 +/- 0.05 nm in halfwidth was found on the scanning tunneling microscopy image of the gramicidin A molecule. The results of direct observation obtained by means of scanning tunneling microscope are in good agreement with the known molecular model of gramicidin A. It was shown that gramicidin A molecules can exist in a lipid monolayer as individual molecules or combined into clusters. The results demonstrate that scanning tunneling microscope can be used for high spatial resolution study of ionic channel structure. Images FIGURE 1 FIGURE 2 FIGURE 4 FIGURE 5 PMID:1712239

  1. Saponin Interactions with Model Membrane Systems - Langmuir Monolayer Studies, Hemolysis and Formation of ISCOMs.

    Science.gov (United States)

    de Groot, Carolin; Müller-Goymann, Christel C

    2016-12-01

    Saponins are used in medicine due to their pharmacological and immunological effects. To better understand interactions of saponins with model membranes and natural membranes of, for example, erythrocytes, Langmuir film balance experiments are well established. For most saponins, a strong interaction with cholesterol was demonstrated in dependence of both the aglycone part and the sugar moieties and is suggested to be correlated with a strong hemolytic activity, high toxicity, and high surface activity, as was demonstrated for the steroid saponin digitonin. In general, changes in the sugar chain or in substituents of the aglycone result in a modification of the saponin properties. A promising saponin with regard to fairly low hemolytic activity and high adjuvant effect is α -tomatine, which still shows a high affinity for cholesterol. An interaction with cholesterol and lipids has also been proven for the Quillaja saponin from the bark of Quillaja saponaria Molina. This triterpene saponin was approved in marketed vaccines as an adjuvant due to the formation of immunostimulating complexes. Immunostimulating complexes consist of a Quillaja saponin, cholesterol, phospholipids, and a corresponding antigen. Recently, another saponin from Quillaja brasiliensis was successfully tested in immunostimulating complexes, too. Based on the results of interaction studies, the formation of drug delivery systems such as immunostimulating complexes or similar self-assembled colloids is postulated for a variety of saponins. Georg Thieme Verlag KG Stuttgart · New York.

  2. Study of immunoglobulin G thin layers obtained by the Langmuir-Blodgett method: application to immunosensors.

    Science.gov (United States)

    Barraud, A; Perrot, H; Billard, V; Martelet, C; Therasse, J

    1993-01-01

    Nowadays, immunosensors play a leading part in the field of bioanalytical chemistry research. As with any biosensor, they need appropriate transducers and a suitable technique to immobilize the active biocomponents. In this study, two transduction modes were chosen: mass effects (quartz microbalance measurements) and geometric and dielectric effects (capacitance measurements). The Langmuir-Blodgett (LB) method appears to be quite suitable for generating biospecific surfaces. This work has focused on the detection of staphylococcal enterotoxin B, the corresponding antibody being immobilized at the surface of fatty acids by a variant of the LB method. The composition of the film and the nature of antibody-fatty acid interactions were studied by means of the two transducers mentioned above. FTIR (Fourier transform infra-red) spectroscopy and protein diagnostic assay. Influence of several parameters (pH, ionic strength, transfer pressure, antibody concentration in the subphase) was investigated. The immobilization rate reached its maximum when experimental conditions allowed optimal electrostatic interactions. In this case, the quartz crystal microbalance response, in air, reached 55 Hz per monolayer of immobilized immunoglobulin G and the equivalent capacitance variation, measured in liquid media, was around 300 pF cm-2. Activity of the biospecific LB films, when binding enterotoxin, was checked by the classical ELISA (enzyme immuno-linked assay) technique.

  3. Electrochemical properties of carbon nanotubes-hydrogenase conjugates Langmuir-Blodgett films

    International Nuclear Information System (INIS)

    Liu, Ai-Rong; Wakayama, Tatsuki; Nakamura, Chikashi; Miyake, Jun; Zorin, Nikolay A.; Qian, Dong-Jin

    2007-01-01

    We report the preparation of Langmuir-Blodgett (LB) films composed of oxidized carbon nanotubes (CNTs) and hydrogenase (H 2 ase) conjugates and their electrochemical properties. Both single-walled (SWNTs) and multi-walled CNTs (MWNTs) were used to form mixed monolayers with H 2 ase on the Tris-HCl subphase surfaces. By using the LB method, the CNTs-H 2 ase monolayers were transferred onto CaF 2 and indium tin oxide (ITO) electrode surfaces. The LB film modified electrodes showed a couple of waves centered at around -500 mV (versus Ag/AgCl), which corresponding to the redox reaction of [4Fe-4S] 2+/1+ clusters in the H 2 ase. The current intensity was enhanced after co-assembly with CNTs. Because of the different diameters of CNTs, this current intensity was proportional to the scan rate (υ) for the electrodes modified with the LB films of pure H 2 ase and SWNTs-H 2 ase, but to the root of scan rate (υ 1/2 ) for those modified with the MWNTs-H 2 ase LB film. The products of diffusion coefficient and concentration (D 1/2 C) increased in the order of pure H 2 ase, SWNTs-H 2 ase, and MWNTs-H 2 ase LB films

  4. Adsorption behaviour of aromatic in different activated carbon: (Frendlich and Langmuir models)

    International Nuclear Information System (INIS)

    Nouri, S.; Haghseresht, F.; Lu, Max

    2001-01-01

    Adsorption behavior of p-Cresol, Benzoic acid and nitrobenzene on the two different activated carbons was carried out at 301 K and at controlled ph conditions. In acidic conditions, well below the pK a of all solutes, it was observed that the adsorbate solubility and the electron density of its aromatic ring were the influencing factors on the extent of the adsorption by affecting the extent of London dispersion forces. In higher solution ph conditions, on the other hand, it was found that the electrostatic forces played a significant role on the extent on adsorption. The Effect of ph must be considered from its combined effects on the carbon surface and on the solute molecules. It was found that the uptake of the molecular form of the aromatic solute was dependent on the substituents of the aromatic ring. Adsorption of the solutes in higher ph values was found to be dependent on the concentration of anionic form of the solutes. All isotherms on the F 100 and S E I were fitted into Langmuir and Freundlich isotherm Equations, respectively to find the relative factors

  5. Plasma monitoring of the RLVIP-process with a Langmuir probe

    Science.gov (United States)

    Huber, D.; Hallbauer, A.; Pulker, H. K.

    2005-09-01

    The aim of this investigation was to study the characteristics of a reactive-low-voltage-high-current-ion-plating plasma and to correlate the observed plasma data with the properties of films deposited under such conditions. A Langmuir probe system (Smart Probe - Scientific Systems) was inserted into a Balzers BAP 800 ion plating plant above the e-gun evaporation source close to the insulated substrate holder. In this position during RLVIP deposition, plasma potential, floating potential, self-bias voltage, electron temperature, ion current density, and particle number density were measured and calculated, respectively. All measurements were performed in dependence of arc current (20-80A) and oxygen partial pressure (1 - 36 x 10-4mbar). With rising arc current the number of charged particles, the self-bias voltage between plasma and substrates as well as the energy of the condensing and bombarding species were increased. These data explain the increase of density, refractive index and mechanical stress of RLVIP-metal-oxide-layers, like Ta2O5 and Nb2O5, deposited with higher arc currents. An increase of gas pressure decreased the energy of the particles and therefore reduced slightly film density and refractive index. However, it improved chemistry and eliminated unwanted residual optical absorption and also decreased compressive mechanical film stress.

  6. Density, temperature, and potential fluctuation measurements by the swept Langmuir probe technique in Wendelstein 7-AS

    International Nuclear Information System (INIS)

    Giannone, L.; Balbin, R.; Niedermeyer, H.; Endler, M.; Herre, G.; Hidalgo, C.; Rudyj, A.; Theimer, G.; Verplanke, P.

    1994-01-01

    In the Wendelstein 7-AS stellarator (W7-AS) [Plasma Phys. Controlled Fusion 33, 1591 (1991)], current-voltage characteristics of the Langmuir probe at sweep frequencies in the range 400 kHz to 1 MHz were measured and it was found that the mean and fluctuation values of the ion saturation current, floating potential, and electron temperature were independent of the sweep frequency. A radial scan in the vicinity of the velocity shear layer was performed. The simultaneous sweeping of 3 probe tips showed a statistically significant spatial coherence of the fluctuations in the poloidal direction and a decrease in spatial coherence of the fluctuations with increasing tip separation could be demonstrated. The observation of a change in the propagation direction of fluctuations as the shear layer was crossed and a calculation of the transport spectrum show that the swept probe method is capable of reproducing known results. Apparent temperature fluctuations, due to variations of density and potential during a sweep, are shown by simulations to be only of importance at frequencies above half the Nyquist frequency

  7. Temperature, density and potential fluctuations by a swept Langmuir probe in Wendelstein 7-AS

    Energy Technology Data Exchange (ETDEWEB)

    Giannone, L.; Niedermeyer, H; Endler, M; Theimer, G; Rudyj, A; Verplancke, Ph [Max-Planck-Institut fuer Plasmaphysik, Garching (Germany); Balbin, R; Hidalgo, C [Centro de Investigaciones Energeticas, Medioambientales y Tecnologicas (CIEMAT), Madrid (Spain)

    1994-12-31

    Numerous experiments using a Langmuir probe to investigate the magnitude of temperature fluctuations and their contribution to heat transport in the edge region of tokamak plasmas have been carried out. Sweeping the voltage applied to a tip fast enough to ensure that the ion saturation current, floating potential and electron temperature may be assumed to be constant during the sweep is experimentally more difficult than alternative schemes but this disadvantage is compensated by the ability to measure all three of these quantities at one spatial location. Sweep frequencies up to 600 kHz have been employed to obtain the current-voltage characteristic. A radial scan in the vicinity of the velocity shear layer on W7-AS stellarator was performed. Inside and outside the shear layer the normalised magnitude of the temperature fluctuations was found to be approximately 30% larger than the magnitude of the electron density fluctuations, approaching a value of 0.12 and 0.09 respectively at a radial position 1 cm inside the shear layer. An increase in the coherency of the temperature, floating potential and density fluctuations between tips with a poloidal separation of 2 mm was also measured as the shear layer was crossed. Heat conduction produced by correlated temperature and poloidal electric field fluctuations is therefore possible. An increasing coherence of temperature and floating potential fluctuations leads to an increase in the coherence of temperature and plasma potential fluctuations as the shear layer was crossed. (author) 7 refs., 3 figs.

  8. A deterministic mathematical model for bidirectional excluded flow with Langmuir kinetics.

    Science.gov (United States)

    Zarai, Yoram; Margaliot, Michael; Tuller, Tamir

    2017-01-01

    In many important cellular processes, including mRNA translation, gene transcription, phosphotransfer, and intracellular transport, biological "particles" move along some kind of "tracks". The motion of these particles can be modeled as a one-dimensional movement along an ordered sequence of sites. The biological particles (e.g., ribosomes or RNAPs) have volume and cannot surpass one another. In some cases, there is a preferred direction of movement along the track, but in general the movement may be bidirectional, and furthermore the particles may attach or detach from various regions along the tracks. We derive a new deterministic mathematical model for such transport phenomena that may be interpreted as a dynamic mean-field approximation of an important model from mechanical statistics called the asymmetric simple exclusion process (ASEP) with Langmuir kinetics. Using tools from the theory of monotone dynamical systems and contraction theory we show that the model admits a unique steady-state, and that every solution converges to this steady-state. Furthermore, we show that the model entrains (or phase locks) to periodic excitations in any of its forward, backward, attachment, or detachment rates. We demonstrate an application of this phenomenological transport model for analyzing ribosome drop off in mRNA translation.

  9. A Langmuir probe system for high power RF-driven negative ion sources on high potential

    International Nuclear Information System (INIS)

    McNeely, P; Christ-Koch, S; Fantz, U; Dudin, S V

    2009-01-01

    A fully automated Langmuir probe system capable of operating simultaneously with beam extraction has been developed and commissioned for the negative hydrogen ion source testbeds at IPP Garching. It allows the measurement of temporal and spatial distributions of the plasma parameters within a single plasma pulse ( 10 18 m -3 ) and hot (T e > 10 eV) plasma with bi-Maxwellian electron energy distribution at low pressures. The plasma found near the plasma grid is very different being of low density (≤10 17 m -3 ) and very cold (T e < 2 eV). This plasma is also strongly influenced by the presence of caesium, the potential of the plasma grid, and if an ion beam is extracted from the source. Caesium strongly reduces the plasma potential of the source and enhances the negative ion density near the plasma grid. Extracting an ion beam is observed to reduce the electron density and increase the potential near the plasma grid. Applying a potential greater than the plasma potential to the plasma grid is found to significantly decrease the electron density near the plasma grid.

  10. Characteristics of the Plasma Source for Ground Ionosphere Simulation Surveyed by Disk-Type Langmuir Probe

    Science.gov (United States)

    Ryu, Kwangsun; Lee, Junchan; Kim, Songoo; Chung, Taejin; Shin, Goo-Hwan; Cha, Wonho; Min, Kyoungwook; Kim, Vitaly P.

    2017-12-01

    A space plasma facility has been operated with a back-diffusion-type plasma source installed in a mid-sized vacuum chamber with a diameter of 1.5 m located in Satellite Technology Research Center (SaTReC), Korea Advanced Institute of Science and Technology (KAIST). To generate plasma with a temperature and density similar to the ionospheric plasma, nickel wires coated with carbonate solution were used as filaments that emit thermal electrons, and the accelerated thermal electrons emitted from the heated wires collide with the neutral gas to form plasma inside the chamber. By using a disk-type Langmuir probe installed inside the vacuum chamber, the generation of plasma similar to the space environment was validated. The characteristics of the plasma according to the grid and plate anode voltages were investigated. The grid voltage of the plasma source is realized as a suitable parameter for manipulating the electron density, while the plate voltage is suitable for adjusting the electron temperature. A simple physical model based on the collision cross-section of electron impact on nitrogen molecule was established to explain the plasma generation mechanism.

  11. Langmuir-Blodgett film based on MEH-PPV for cholesterol biosensor

    International Nuclear Information System (INIS)

    Matharu, Zimple; Arya, Sunil K.; Singh, S.P.; Gupta, Vinay; Malhotra, B.D.

    2009-01-01

    Cholesterol oxidase (ChOx) has been immobilized onto conducting poly[2-methoxy,5-(2'-ethyl-hexyloxy)-1,4-phenylene vinylene] (MEH-PPV)/stearic acid (SA) Langmuir-Blodgett film transferred onto octadecanethiol (ODT) modified gold plate. The ChOx/MEH-PPV/SA LB film bioelectrode exhibits has been characterized by FT-IR, contact angle, and atomic force microscopy. The response of the ChOx/MEH-PPV/SA LB film bioelectrode carried out using differential pulse voltammetry (DPV) studies reveal linearity from 1.29 to 12.91 mM of cholesterol concentration and response time as 30 s. This ChOx/MEH-PPV/SA bioelectrode exhibits values of correlation coefficient as 0.9939, standard deviation as 0.0029 μA and limit of detection as 1.66 mM. UV-visible spectrophotometer studies reveal that 5.2 x 10 -3 U of ChOx are actively working per cm 2 area of ChOx/MEH-PPV/SA LB film bioelectrode and this bioelectrode is thermally stable upto 55 deg. C with reusability of about 60 times

  12. Langmuir-Blodgett film based on MEH-PPV for cholesterol biosensor

    Energy Technology Data Exchange (ETDEWEB)

    Matharu, Zimple [Biomolecular Electronics and Conducting Polymer Research Group, National Physical Laboratory, Dr. K.S. Krishnan Marg, New Delhi 110012 (India); Department of Physics and Astrophysics, University of Delhi, Delhi 110007 (India); Arya, Sunil K.; Singh, S.P. [Biomolecular Electronics and Conducting Polymer Research Group, National Physical Laboratory, Dr. K.S. Krishnan Marg, New Delhi 110012 (India); Gupta, Vinay [Department of Physics and Astrophysics, University of Delhi, Delhi 110007 (India); Malhotra, B.D. [Biomolecular Electronics and Conducting Polymer Research Group, National Physical Laboratory, Dr. K.S. Krishnan Marg, New Delhi 110012 (India)], E-mail: bansi.malhotra@gmail.com

    2009-02-23

    Cholesterol oxidase (ChOx) has been immobilized onto conducting poly[2-methoxy,5-(2'-ethyl-hexyloxy)-1,4-phenylene vinylene] (MEH-PPV)/stearic acid (SA) Langmuir-Blodgett film transferred onto octadecanethiol (ODT) modified gold plate. The ChOx/MEH-PPV/SA LB film bioelectrode exhibits has been characterized by FT-IR, contact angle, and atomic force microscopy. The response of the ChOx/MEH-PPV/SA LB film bioelectrode carried out using differential pulse voltammetry (DPV) studies reveal linearity from 1.29 to 12.91 mM of cholesterol concentration and response time as 30 s. This ChOx/MEH-PPV/SA bioelectrode exhibits values of correlation coefficient as 0.9939, standard deviation as 0.0029 {mu}A and limit of detection as 1.66 mM. UV-visible spectrophotometer studies reveal that 5.2 x 10{sup -3} U of ChOx are actively working per cm{sup 2} area of ChOx/MEH-PPV/SA LB film bioelectrode and this bioelectrode is thermally stable upto 55 deg. C with reusability of about 60 times.

  13. Spatial survey of a magnetron plasma sputtering system using a Langmuir probe

    International Nuclear Information System (INIS)

    Field, D.J.; Dew, S.K.; Burrell, R.E.

    2002-01-01

    A two-dimensional spatial survey is conducted for a magnetron sputtering plasma at two pressures (40 and 5 mTorr) using a Langmuir probe. The plasma density is found to be highest (up to 6.0x10 10 cm -3 ) above the etch region of the cathode, near the magnetic trap. The density drops between the etch regions, near the edges of the cathode and also at distances farther away from the cathode. The floating potential was found to be most negative (down to -12 V) in regions where the highest electron temperatures were observed (up to almost 4 eV) and became less negative (near 0 V) in regions where the electron temperature was lowest (less than 0.5 eV). This complementary trend was consistent in all spatial locations and at both pressures. The plasma potential was found to have very weak dependence, if any, on spatial location and pressure. The relationship between electron transport processes, collision processes and electron temperatures is discussed. Electron energy distribution functions were found to be either Maxwellian or bi-Maxwellian in nature, depending on pressure and spatial location. Maxwellian distributions were found near the magnetic trap or source of the plasma. Bi-Maxwellian distributions were found further away from the source, and it appears they result from Maxwellian distributions bifurcating as they diffuse away from the source. The suitability of the popular models for this bifurcation is discussed

  14. Combined Langmuir-magnetic probe measurements of type-I ELMy filaments in the EAST tokamak

    Science.gov (United States)

    Qingquan, YANG; Fangchuan, ZHONG; Guosheng, XU; Ning, YAN; Liang, CHEN; Xiang, LIU; Yong, LIU; Liang, WANG; Zhendong, YANG; Yifeng, WANG; Yang, YE; Heng, ZHANG; Xiaoliang, Li

    2018-06-01

    Detailed investigations on the filamentary structures associated with the type-I edge-localized modes (ELMs) should be helpful for protecting the materials of a plasma-facing wall on a future large device. Related experiments have been carefully conducted in the Experimental Advanced Superconducting Tokamak (EAST) using combined Langmuir-magnetic probes. The experimental results indicate that the radially outward velocity of type-I ELMy filaments can be up to 1.7 km s‑1 in the far scrape-off layer (SOL) region. It is remarkable that the electron temperature of these filaments is detected to be ∼50 eV, corresponding to a fraction of 1/6 to the temperature near the pedestal top, while the density (∼ 3× {10}19 {{{m}}}-3) of these filaments could be approximate to the line-averaged density. In addition, associated magnetic fluctuations have been clearly observed at the same time, which show good agreement with the density perturbations. A localized current on the order of ∼100 kA could be estimated within the filaments.

  15. ATF [Advanced Toroidal Facility] edge plasma turbulence studies using a fast reciprocating Langmuir probe

    International Nuclear Information System (INIS)

    Uckan, T.; Hidalgo, C.; Bell, J.D.; Harris, J.H.; Dunlap, J.L.; Dyer, G.R.; Mioduszewski, P.K.; Wilgen, J.B.; Ritz, C.P.; Wootton, A.J.; Rhodes, T.L.; Carter, K.

    1990-01-01

    Electrostatic turbulence on the edge of the Advanced Torodial Facility (ATF) torsatron is investigated experimentally with a fast reciprocating Langmuir probe (FRLP) array. Initial measurements of plasma electron density n e and temperature T e and fluctuations in density (n e ) and plasma floating potential (φ f ) are made in ECH plasmas at 1 T. At the last closed flux surface (LCFS, r/bar a ∼1), T e ∼ 20--40 eV and n e ∼ 10 12 cm -3 for a line-averaged electron density bar n e = (3--6) x 10 12 cm -3 . Relative fluctuation levels, as the FRLP is moved into core plasma where T e > 20 eV, are n e /n e ∼ 5%, and e φ f /T e ∼ 2n e /n e about 2 cm inside the LCFS. The observed fluctuation spectra are broadband (40--300 kHz) with bar kρ s ≤ 0.1, where bar k is the wavenumber of the fluctuations and ρ s is the ion Larmor radius at the sound speed. The propagation direction of the fluctuations reverses to the electron diamagnetic direction around r/bar a ph ∼ v de ). The fluctuation-induced particle flux is comparable to fluxes estimated from the particle balance using the H α spectroscopic measurements. Many of the features seen in these experiments resemble the features of ohmically heated plasmas in the Texas Experimental Tokamak (TEXT). 17 refs., 10 figs

  16. Solving the Capacitive Effect in the High-Frequency sweep for Langmuir Probe in SYMPLE

    Science.gov (United States)

    Pramila; Patel, J. J.; Rajpal, R.; Hansalia, C. J.; Anitha, V. P.; Sathyanarayana, K.

    2017-04-01

    Langmuir Probe based measurements need to be routinely carried out to measure various plasma parameters such as the electron density (ne), the electron temperature (Te), the floating potential (Vf), and the plasma potential (Vp). For this, the diagnostic electronics along with the biasing power supplies is installed in standard industrial racks with a 2KV isolation transformer. The Signal Conditioning Electronics (SCE) system is populated inside the 4U-chassis based system with the front-end electronics, designed using high common mode differential amplifiers which can measure small differential signal in presence of high common mode dc- bias or ac ramp voltage used for biasing the probes. DC-biasing of the probe is most common method for getting its I-V characteristic but method of biasing the probe with a sweep at high frequency encounters the problem of corruption of signal due to capacitive effect specially when the sweep period and the discharge time is very fast and die down in the order of μs or lesser. This paper presents and summarises the method of removing such effects encountered while measuring the probe current.

  17. Large Area Fabrication of Semiconducting Phosphorene by Langmuir-Blodgett Assembly

    Science.gov (United States)

    Kaur, Harneet; Yadav, Sandeep; Srivastava, Avanish. K.; Singh, Nidhi; Schneider, Jörg J.; Sinha, Om. P.; Agrawal, Ved V.; Srivastava, Ritu

    2016-01-01

    Phosphorene is a recently new member of the family of two dimensional (2D) inorganic materials. Besides its synthesis it is of utmost importance to deposit this material as thin film in a way that represents a general applicability for 2D materials. Although a considerable number of solvent based methodologies have been developed for exfoliating black phosphorus, so far there are no reports on controlled organization of these exfoliated nanosheets on substrates. Here, for the first time to the best of our knowledge, a mixture of N-methyl-2-pyrrolidone and deoxygenated water is employed as a subphase in Langmuir-Blodgett trough for assembling the nanosheets followed by their deposition on substrates and studied its field-effect transistor characteristics. Electron microscopy reveals the presence of densely aligned, crystalline, ultra-thin sheets of pristine phosphorene having lateral dimensions larger than hundred of microns. Furthermore, these assembled nanosheets retain their electronic properties and show a high current modulation of 104 at room temperature in field-effect transistor devices. The proposed technique provides semiconducting phosphorene thin films that are amenable for large area applications. PMID:27671093

  18. Studying the influence of substrate conductivity on the optoelectronic properties of quantum dots langmuir monolayer

    Science.gov (United States)

    Al-Alwani, Ammar J.; Chumakov, A. S.; Begletsova, N. N.; Shinkarenko, O. A.; Markin, A. V.; Gorbachev, I. A.; Bratashov, D. N.; Gavrikov, M. V.; Venig, S. B.; Glukhovskoy, E. G.

    2018-04-01

    The formation of CdSe quantum dots (QDs) monolayers was studied by Langmuir Blodgett method. The fluorescence (PL) spectra of QD monolayers were investigated at different substrate type (glass, silicon and ITO glass) and the influence of graphene sheets layer (as a conductive surface) on the QDs properties has also been studied. The optoelectronic properties of QDs can be tuned by deposition of insulating nano-size layers of the liquid crystal between QDs and conductive substrate. The monolayer of QDs transferred on conductive surface (glass with ITO) has lowest intensity of PL spectra due to quenching effect. The PL intensity of QDs could be tuned by using various type of substrates or/and by transformed high conductive layer. Also the photooxidation processes of CdSe QDs monolayer on the solid surface can be controlled by selection of suitable substrate. The current-voltage (I–V) characteristics of QDs thin film on ITO surface was studied using scanning tunneling microscope (STM).

  19. Conductive Langmuir-Blodgett films. Doping with iodine or self-doping?

    International Nuclear Information System (INIS)

    Bourgoin, Jean-Philippe

    1991-01-01

    In this research thesis dealing with molecular architecture, the author reports the testing of two strategies aiming at reducing the importance of defects in conductive Langmuir-Blodgett films, and at enabling the production of conductive mono-molecular layer. According to the first strategy, conductive films are obtained after doping based on the use of iodine vapours of an insulating precursor film of molecules derived from BEDT-TTF. The so-produced films display a high conductivity and can be used as sensitive elements in gas sensors, but remain macroscopically insulating, probably because molecular reorganisation, as shown by a study based on different techniques (IR and UV linear dichroism, Raman spectroscopy, X ray diffraction), generates too many defects. The second strategy, self-doping, is based on a mixing of two derivatives of the same electro-active nucleus (the TCNQ, tetracyanoquinodimethane), an amphiphilic one and a semi-amphiphilic one. This strategy opens new perspectives in molecular engineering as it is a general way to produce conductive LB films from TCNQ [fr

  20. Plasma-treated Langmuir-Blodgett reduced graphene oxide thin film for applications in biophotovoltaics

    Science.gov (United States)

    Ibrahim, Siti Aisyah; Jaafar, Muhammad Musoddiq; Ng, Fong-Lee; Phang, Siew-Moi; Kumar, G. Ghana; Majid, Wan Haliza Abd; Periasamy, Vengadesh

    2018-01-01

    The surface optimization and structural characteristics of Langmuir-Blodgett (LB) reduced graphene oxide thin (rGO) film treated by argon plasma treatment were studied. In this work, six times deposition of rGO was deposited on a clean glass substrate using the LB method. Plasma technique involving a variation of plasma power, i.e., 20, 60, 100 and 140 W was exposed to the LB-rGO thin films under argon ambience. The plasma treatment generally improves the wettability or hydrophilicity of the film surface compared to without treatment. Maximum wettability was observed at a plasma power of 20 W, while also increasing the adhesion of the rGO film with the glass substrate. The multilayer films fabricated were characterized by means of spectroscopic, structural and electrical studies. The treatment of rGO with argon plasma was found to have improved its biocompatibility, and thus its performance as an electrode for biophotovoltaic devices has been shown to be enhanced considerably.

  1. Estimation of plasma ion saturation current and reduced tip arcing using Langmuir probe harmonics.

    Science.gov (United States)

    Boedo, J A; Rudakov, D L

    2017-03-01

    We present a method to calculate the ion saturation current, I sat , for Langmuir probes at high frequency (>100 kHz) using the harmonics technique and we compare that to a direct measurement of I sat . It is noted that the I sat estimation can be made directly by the ratio of harmonic amplitudes, without explicitly calculating T e . We also demonstrate that since the probe tips using the harmonic method are oscillating near the floating potential, drawing little power, this method reduces tip heating and arcing and allows plasma density measurements at a plasma power flux that would cause continuously biased tips to arc. A multi-probe array is used, with two spatially separated tips employing the harmonics technique and measuring the amplitude of at least two harmonics per tip. A third tip, located between the other two, measures the ion saturation current directly. We compare the measured and calculated ion saturation currents for a variety of plasma conditions and demonstrate the validity of the technique and its use in reducing arcs.

  2. Generation of Langmuir wave supercontinuum by phase-preserving equilibration of plasmons with irreversible wave-particle interaction

    Science.gov (United States)

    Eiichirou, Kawamori

    2018-04-01

    We report the observation of supercontinuum of Langmuir plasma waves, that exhibits broad power spectrum having significant spatio-temporal coherence grown from a monochromatic seed-wave, in one-dimensional particle-in-cell simulations. The Langmuir wave supercontinuum (LWSC) is formed when the seed wave excites side-band fields efficiently by the modulational instabilities. Its identification is achieved by the use of the tricoherence analysis, which detects four wave mixings (FWMs) of plasmons (plasma wave quanta), and evaluation of the first order coherence, which is a measure of temporal coherence, of the wave electric fields. The irreversible evolution to the coherent LWSC from the seed wave is realized by the wave-particle interactions causing stochastic electron motions in the phase space and the coherence of LWSC is maintained by the phase-preserving FWMs of plasmons. The LWSC corresponds to a quasi Bernstein-Greene-Kruskal mode.

  3. Network structure control of binary mixed langmuir monolayers of homo-PS and PS-b-P2VP.

    Science.gov (United States)

    Wen, Gangyao

    2010-03-25

    Our recent work showed there existed a composition window for mixed Langmuir monolayers of homopolystyrene (h-PS) and a symmetric diblock copolymer polystyrene-block-poly(2-vinylpyridine) (PS-b-P2VP) to form necklace-network structures at the air/water interface. In order to study further the possible mechanism and control the network structure (i.e., surface coverage and nanoaggregate diameter), effects of spreading solution concentration and volume, subphase temperature, and transfer pressure on the network structure were studied by the Langmuir monolayer technique and tapping mode atomic force microscopy. With the increase of transfer pressure, there existed a novel nonlinear behavior for the nanoaggregate diameter first to increase, then to decrease, and finally to increase again, while the surface coverage tended to increase step by step. Moreover, with the elevation of temperature, chain motion between the adjoining nanoaggregates tended to be improved and thus the nanoaggregate diameter tended to be more uniform.

  4. Dependence of the electron Langmuir wave damping on the angle of propagation in weakly ionized neon plasma

    International Nuclear Information System (INIS)

    Zigman, V.J.; Milic, B.S.

    1995-01-01

    The dependence of the attenuation of the longitudinal electron Langmuir waves (ω ∼ ω pe ), in collisional weakly ionized, non-magnetized, uniform and steady-state plasmas placed in external d.c. electric field, on the angle θ between the wave vector and the electron drift rvec u is studied on the ground of the kinetic theory and the linear perturbation technique. The collisionless and collisional contributions to the overall attenuation were evaluated separately, as it was shown previously that in certain instances the elastic e - n encounters (with collision frequency ν en , ν en much-lt ω pe ) may attenuate the Langmuir waves more efficiently than the Landau mechanism. More precisely, it was found that, for any fixed value of E 0 /n n , there exists a critical value of the ratio n n /X above which the collisional attenuation prevails

  5. Comparison of fluctuations properties measured by Langmuir and ball-pen probes in the ISTTOK boundary plasma

    Czech Academy of Sciences Publication Activity Database

    Silva, C.; Adámek, Jiří; Fernandes, H.; Figueiredo, H.

    2015-01-01

    Roč. 57, č. 2 (2015), č. článku 025003. ISSN 0741-3335 R&D Projects: GA ČR(CZ) GAP205/12/2327; GA MŠk(CZ) LM2011021 Institutional support: RVO:61389021 Keywords : langmuir probes * turbulence * tokamak Subject RIV: BL - Plasma and Gas Discharge Physics OBOR OECD: Fluids and plasma physics (including surface physics) Impact factor: 2.404, year: 2015 http://iopscience.iop.org/0741-3335/57/2/025003

  6. Structural studies on Langmuir-Blodgett ultra-thin films on tin (IV) stearate using X-ray diffraction technique

    International Nuclear Information System (INIS)

    Mohamad Deraman; Muhamad Mat Salleh; Mohd Ali Sulaiman; Mohd Ali Sufi

    1991-01-01

    X-ray diffraction measurements were carried out on Langmuir-Blodgett (LB) ultra-thin films of tin (IV) stearate for different numbers of layers. The structural information such as interplanar spacing, unit cells spacing, molecular length and orientation of molecular chains were obtained from the diffraction data. This information is discussed and compared with that previously published for LB ultra-thin films of manganese stearate and cadmium stearate

  7. Numerical evaluation of Cs adsorption in PB column by extended Langmuir formula and one-dimensional adsorption model

    International Nuclear Information System (INIS)

    Hiroshi Ogawa; Akiko Kitajima; Hisashi Tanaka; Tohru Kawamoto

    2015-01-01

    Adsorption property of granulated Prussian blue adsorbent on radioactive cesium was evaluated for efficient decontamination in Fukushima area. The adsorbent was found to show an inflective adsorption isotherm, which was expressed by extended Langmuir formula with three adsorption sites. Adsorption speeds of each site were evaluated by time-dependent batch experiment. The simulation using derived parameters and one-dimensional adsorption model successfully reproduced the experimental data of cesium decontamination by small and large columns. (author)

  8. High-spatial-resolution electron density measurement by Langmuir probe for multi-point observations using tiny spacecraft

    Science.gov (United States)

    Hoang, H.; Røed, K.; Bekkeng, T. A.; Trondsen, E.; Clausen, L. B. N.; Miloch, W. J.; Moen, J. I.

    2017-11-01

    A method for evaluating electron density using a single fixed-bias Langmuir probe is presented. The technique allows for high-spatio-temporal resolution electron density measurements, which can be effectively carried out by tiny spacecraft for multi-point observations in the ionosphere. The results are compared with the multi-needle Langmuir probe system, which is a scientific instrument developed at the University of Oslo comprising four fixed-bias cylindrical probes that allow small-scale plasma density structures to be characterized in the ionosphere. The technique proposed in this paper can comply with the requirements of future small-sized spacecraft, where the cost-effectiveness, limited space available on the craft, low power consumption and capacity for data-links need to be addressed. The first experimental results in both the plasma laboratory and space confirm the efficiency of the new approach. Moreover, detailed analyses on two challenging issues when deploying the DC Langmuir probe on a tiny spacecraft, which are the limited conductive area of the spacecraft and probe surface contamination, are presented in the paper. It is demonstrated that the limited conductive area, depending on applications, can either be of no concern for the experiment or can be resolved by mitigation methods. Surface contamination has a small impact on the performance of the developed probe.

  9. Lightning mapping and dual-polarization radar observations of electrified storms at Langmuir Laboratory

    Science.gov (United States)

    Krehbiel, P. R.; Hyland, P. T.; Edens, H. E.; Rison, W.

    2013-12-01

    Observations being made at Langmuir Laboratory with the NM Tech Lightning Mapping Array (LMA) and the University of Oklahoma ARRC PX-1000 dual polarization X-band radar strongly confirm and expand upon the normal polarity tripolar electrical structure of central New Mexico storms. This is in sharp contrast with the anomalously electrified storm structures observed in northern Colorado during and subsequent to the 2012 DC3 field campaign, as seen with North Colorado LMA and CSU CHILL dual-polarization radar observations. In this presentation we focus on the New Mexico observations, and several modes in which the tripolar structure appears initially to develop and evolve with time. Central New Mexico storms are often prolific producers of negative cloud-to-ground (CG) flashes, but rarely produce positive CGs. By contrast, many or most north Colorado storms are CG-deficient, with the relatively few CG discharges being of predominantly positive polarity. In addition, NM storms commonly produce bolt-from-the-blue (BFB) negative CGs, whereas anomalously electrified Colorado storms produce none. The occurrence of BFBs is indicative of a relatively weak lower positive charge region, while the occurrence of normal downward -CGs is indicative of a somewhat stronger lower positive charge. The lack of -CGs in Colorado storms results from lower positive charge being a dominant storm charge that is elevated in altitude. These and other basic features of the electrically activity of storms, coupled with dual polarization and Doppler radar observations of hydrometeor types and motions, are leading to a better understanding of the storm electrification processes.

  10. A Quantitative Study of Tethered Chains in Various Solution Conditions Using Langmuir Diblock Copolymer Monolayers

    Energy Technology Data Exchange (ETDEWEB)

    Kent, Michael S.

    1999-08-13

    This article summarizes our investigations of tethered chain systems using Langmuir monolayer of polydimethysiloxane-poly styrene (PDMS-PS) diblock copolymers on organic liquids. In this system, the PDMS block adsorbs to the air surface while the PS block dangles into the subphase liquid. The air surface can be made either repulsive or attractive for the tethered PS chain segments by choosing a subphase liquid which has a surface tension lower or greater than that of PS, respectively. The segment profile of the PS block is determined by neutron reflection as a function of the surface density, the molecular weights of the PS and PDMS blocks, and the solution conditions. We cover the range of reduced surface density (SIGMA) characteristic of the large body of data in the literature for systems of chains tethered onto solid surfaces from dilute solution in good or theta solvent conditions (SIGMA < 12). We emphasize quantitative comparisons with analytical profile forms and scaling predictions. We find that the strong-stretching limit invoked in analytical SCF and scaling theories is not valid over this Z range. On the other hand, over a large portion of this range (SIGMA < 5) tethered layers are well described by a renormalization group theory addressing weakly interacting or noninteracting chains. Simultaneous with the study of the profile form, the free energy of the chains is examined through the surface tension. A strong increase in the surface pressure is observed with increasing surface density which determines the maximum surface density which can be achieved. This apparently nonequilibrium effect is attributed to steric interactions and limited lateral interpenetration. This effect may explain several outstanding discrepancies regarding the adsorption of end-functionalized chains and diblock copolymers onto solid surfaces.

  11. Weak turbulence theory of Langmuir waves: A reconsideration of validity of quasilinear theory

    International Nuclear Information System (INIS)

    Liang, Y.M.; Diamond, P.H.

    1991-01-01

    The weak turbulence theory of Langmuir waves in a one-dimensional, one-species plasma is discussed. Analytical calculations using the theory of two-point correlation functions show that in the weak turbulence regime τ ac much-lt min[τ tr , γ k -1 ], the nonlinear enhancement of the mode growth rate relative to the linear Landau mode growth rate γ k L is rather weak, and quasilinear theory is reproduced at the lowest order. Hence this work also proves the validity of the quasilinear theory. Here τ ac ∼ (kΔv ph ) -1 is the phase-mixing time or the auto-correlation time, and τ tr ∼ (k 2 D ql ) -1/3 is the particle decorrelation time or the turbulence trapping time. In particular, the lowest order nonlinear correction to γ k L in the regime τ ac much-lt τ tr much-lt γ k -1 is proportional to (1/ω k τ tr )γ k L . Both corrections are additive, not multiplicative, and are of higher order in the weak turbulence expansion. The smallness of the corrections is due to the fact that the only mechanism for the relaxation of the plasma distribution function in a one-dimensional, one-species plasma is momentum exchange between waves and particles, which is exactly the interaction considered in the quasilinear theory. No like-like particle momentum exchange is allowed due to momentum conservation constraints. Similar calculations are also done for the traveling wave tube, which can be used to test this theory experimentally, especially for the case of bump-on-tail instability. A comparison of theoretical predictions with experimental results is presented. 3 refs

  12. ATF edge plasma turbulence studies using a fast reciprocating Langmuir probe

    International Nuclear Information System (INIS)

    Uckan, T.; Hidalgo, C.; Bell, J.D.; Harris, J.H.; Dunlap, J.L.; Dyer, G.R.; Mioduszewski, P.K.; Wilgen, J.B.; Ritz, C.P.; Wootton, A.J.; Rhodes, T.L.; Carter, K.

    1991-01-01

    Electrostatic turbulence on the edge of the Advanced Toroidal Facility (ATF) torsatron is investigated experimentally with a fast reciprocating Langmuir probe (FRLP) array. Initial measurements of plasma electron density n e and temperature T e and fluctuations in density (n e ) and plasma floating potential (φ f ) are made in electron cyclotron heated plasmas at 1 T. At the last closed flux surface (LCFS, r√a ∼ 1), T e ∼ 20--40 eV and n e ∼ 10 12 cm -3 for a line-averaged electron density bar n e = (3--6) x 10 12 cm -3 . Relative fluctuation levels, as the FRLP is moved into core plasma where T e > 20 eV, are n e /n e ∼ 5% and eφ f /T e ∼ 2n e /n e about 2 cm inside the LCFS. The observed fluctuation spectra are broadband (40--300 kHz) with bar kρ s ≤ 0.1, where bar k is the wavenumber of the fluctuations and ρ s is the ion Larmor radius at the sound speed. The propagation direction of the fluctuations reverses to the electron diamagnetic direction around r√a ph ∼ v de ). The fluctuation-induced particle flux is comparable to fluxes estimated from the particle balance using the H α spectroscopic measurements. Many of the features seen in these experiments resemble the features of ohmically heated plasmas in the Texas Experimental Tokamak (TEXT). 18 refs., 10 figs

  13. Multi-channel Langmuir-probe and H[alpha]-measurements of edge fluctuations on ASDEX

    Energy Technology Data Exchange (ETDEWEB)

    Niedermeyer, H; Carlson, A; Endler, M; Giannone, L.; Rudyj, A; Theimer, G [Max-Planck-Institut fuer Plasmaphysik, Garching (Germany)

    1991-01-01

    The anomalous transport observed in tokamaks is caused by turbulent fluctuations, the nature of which is still poorly understood. Diagnostic difficulties are one major reason for this lack of understanding, at least with respect to the bulk plasma. The plasma edge, however, is accessible by several diagnostics permitting localized measurements of different parameters with good spatial and temporal resolution. For this reason one can hope to obtain enough information about edge fluctuations to permit the development of theoretical models. Different ranges of plasma parameters and the lack of closed magnetic surfaces distinguish this plasma zone from the bulk plasma. Edge turbulence might well involve other mechanisms than the turbulence in the bulk. Although transport in the bulk plasma receives more attention transport in the edge plasma and edge physics are very relevant for reactor design. The realistic hope to find a solution and the importance of the problem for the next step in fusion research are reasons for the strong effort in this field on many tokamaks. Like in many limiter tokamaks Langmuir probes were used in the ASDEX divertor device for measurements of the floating potential and of the ion saturation current. Under certain assumptions the electron density and the plasma potential can be derived from these data. Observation of the H[alpha]-light emitted from the edge in the vicinity of a neutral gas source yields information about the electron density. While probe measurements are more suitable for quantitative evaluations including the calculation of the local particle flux the H[alpha]-method is not calibrated and integrates radially over the edge. It is however applicable in situations where probes fail because of excessive heat load. With 16-channel arrays both methods permit spatial correlations and wavenumber spectra to be determined without any further assumptions. (author) 4 refs., 2 figs.

  14. Interactions between an anticancer drug - edelfosine - and cholesterol in Langmuir monolayers

    International Nuclear Information System (INIS)

    Wiecek, Agata; Dynarowicz-Latka, Patrycja; Minones, J.; Conde, Olga; Casas, Matilde

    2008-01-01

    Edelfosine (1-O-octadecyl-2-O-methyl-rac-glycero-3-phosphocholine, abbr. Et-18-OCH 3 ) is a new generation anticancer drug based on a phospholipids-like structure. Since its mechanism of action is believed to be related to the lipids of cellular membrane, we have investigated the interactions between edelfosine and main mammalian sterol: cholesterol, using the Langmuir monolayer technique. The interactions have been analyzed by comparing the experimental curves with theoretical ones, obtained basing on the additivity rule. The observed contraction together with negative deviations from ideality observed on the mean molecular area (A 12 ) vs film composition plots proves the existence of strong attractive forces between edelfosine and cholesterol, which have been quantified with the excess free energy of mixing (ΔG exc ) values, calculated from the surface pressure-area isotherms datapoints. The most negative values of ΔG exc have been found for the mixture of equimolar composition, proving its highest thermodynamic stability and the existence of the strongest interactions between film components. Thus, it has been postulated that at the surface edelfosine and cholesterol form stable complexes of 1:1 stoichiometry. The analysis of the collapse pressure values for the investigated mixed monolayers proves that films of edelfosine mole fraction ≤ 0.5 are miscible within the whole range of surface pressures, while monolayers richer in edelfosine mix in the pressure region below ca. 37.6 mN/m, which corresponds to the collapse of pure edelfosine monolayer. At this very surface pressure, edelfosine is expelled from the mixed monolayer and the remaining film is composed by surface complexes of high stability. The hypothesis of complex formation explains the results performed in vitro on cell cultures, indicating that the increase of cholesterol content significantly reduces the uptake of edelfosine

  15. Instability and damping of one-dimensional high-amplitude Langmuir waves

    International Nuclear Information System (INIS)

    Buchel'nikova, N.S.; Matochkin, E.P.

    1981-01-01

    Numerical experiments (methods ''of particles in cells'') on investigation of instability and damping of one-dimensional Langmuir waves in the region Esub(0)sup(2)/8πnT>m/M>(ksub(0)rsub(d))sup(2) ksub(0) is wave vector, M- ion mass, m-electron mass, v=√T/M, vsub(ph)=Wsub(0)/ksub(0), Wsub(0)-proper plasma frequency) are performed. Numerical experiments have been conducted in a wide range of initial parameters of the wave: E 0 2 /8πnT approximately 4x10 2 -10 -2 , vsub(ph)/vsub(T) approximately 3-160, M/m=10 2 , in some cases M/m=10 3 . It is shown that the basic processes are modulation instability with a modulation length less than the wave length, wave conversion at density inhomogeneity and electron capture by the wave or its harmonics. Depending on initial wave parameters the predominant role is played by this or that process. In the range of linear waves Esub(0)sup(2)/8πnT ksub(0)rsub(d) - to the collapse. In the range of 4x10sup(-2)/(ksub(0)rsub(d)sup(2)>Esub(0)sup(2)/8πnT>10sup(-3)/(ksub(0)rsub(d))sup(2) all the three processes play a comparable role. In the range of strong damping Esub(0)sup(2)/8πnT>4x10sup(-2)/(h ksub(0)rsub(d))sup(2) the main part is played by the wave electron capture resulting in damping considerably exceeding the Lamdau damping [ru

  16. Langmuir probe diagnostics of an atmospheric pressure, vortex-stabilized nitrogen plasma jet

    Energy Technology Data Exchange (ETDEWEB)

    Prevosto, L.; Mancinelli, B. R. [Grupo de Descargas Electricas, Departamento Ingenieria Electromecanica, Facultad Regional Venado Tuerto (UTN), Laprida 651, (2600) Venado Tuerto, Santa Fe (Argentina); Kelly, H. [Grupo de Descargas Electricas, Departamento Ingenieria Electromecanica, Facultad Regional Venado Tuerto (UTN), Laprida 651, (2600) Venado Tuerto, Santa Fe (Argentina) and Instituto de Fisica del Plasma (CONICET), Departamento de Fisica, Facultad de Ciencias Exactas y Naturales UBA Ciudad Universitaria Pab. I, (1428) Buenos Aires (Argentina)

    2012-09-15

    Langmuir probe measurements in an atmospheric pressure direct current (dc) plasma jet are reported. Sweeping probes were used. The experiment was carried out using a dc non-transferred arc torch with a rod-type cathode and an anode of 5 mm diameter. The torch was operated at a nominal power level of 15 kW with a nitrogen flow rate of 25 Nl min{sup -1}. A flat ion saturation region was found in the current-voltage curve of the probe. The ion saturation current to a cylindrical probe in a high-pressure non local thermal equilibrium (LTE) plasma was modeled. Thermal effects and ionization/recombination processes inside the probe perturbed region were taken into account. Averaged radial profiles of the electron and heavy particle temperatures as well as the electron density were obtained. An electron temperature around 11 000 K, a heavy particle temperature around 9500 K and an electron density of about 4 Multiplication-Sign 10{sup 22} m{sup -3}, were found at the jet centre at 3.5 mm downstream from the torch exit. Large deviations from kinetic equilibrium were found throughout the plasma jet. The electron and heavy particle temperature profiles showed good agreement with those reported in the literature by using spectroscopic techniques. It was also found that the temperature radial profile based on LTE was very close to that of the electrons. The calculations have shown that this method is particularly useful for studying spraying-type plasma jets characterized by electron temperatures in the range 9000-14 000 K.

  17. Characterisation of the incident beam and current diffraction capabilities on the VESUVIO spectrometer

    Science.gov (United States)

    Romanelli, G.; Krzystyniak, M.; Senesi, R.; Raspino, D.; Boxall, J.; Pooley, D.; Moorby, S.; Schooneveld, E.; Rhodes, N. J.; Andreani, C.; Fernandez-Alonso, F.

    2017-09-01

    The VESUVIO spectrometer at the ISIS pulsed neutron and muon source is a unique instrument amongst those available at neutron facilities. This is the only inverted-geometry neutron spectrometer accessing values of energy and wavevector transfer above tens of eV and {\\mathringA}-1 , respectively, and where deep inelastic neutron scattering experiments are routinely performed. As such, the procedure at the base of the technique has been previously described in an article published by this journal (Mayers and Reiter 2012 Meas. Sci. Technol. 23 045902). The instrument has recently witnessed an upsurge of interest due to a new trend to accommodate, within a single experiment, neutron diffraction and transmission measurements in addition to deep inelastic neutron scattering. This work presents a broader description of the instrument following these recent developments. In particular, we assess the absolute intensity and two-dimensional profile of the incident neutron beam and the capabilities of the backscattering diffraction banks. All results are discussed in the light of recent changes to the moderator viewed by the instrument. We find that VESUVIO has to be considered a high-resolution diffractometer as much as other diffractometers at ISIS, with a resolution as high as 2× 10-3 in backscattering. Also, we describe the extension of the wavelength range of the instrument to include lower neutron energies for diffraction measurements, an upgrade that could be readily applied to other neutron instruments as well.

  18. Cancer incidence among waiters

    DEFF Research Database (Denmark)

    Reijula, Jere; Kjaerheim, Kristina; Lynge, Elsebeth

    2015-01-01

    AIMS: To study cancer risk patterns among waiters in the Nordic countries. METHODS: We identified a cohort of 16,134 male and 81,838 female waiters from Denmark, Finland, Iceland, Norway and Sweden. During the follow-up period from 1961 to 2005, we found that 19,388 incident cancer cases were...... diagnosed. Standardised incidence ratio (SIR) was defined as the observed number of cancer cases divided by the expected number, based on national age, time period and gender-specific cancer incidence rates in the general population. RESULTS: The SIR of all cancers in waiters, in the five countries combined...... INCIDENCE IN SOME CANCER SITES CAN LIKELY BE EXPLAINED BY HIGHER ALCOHOL CONSUMPTION, THE PREVALENCE OF SMOKING AND OCCUPATIONAL EXPOSURE TO TOBACCO SMOKE HOPEFULLY, THE INCIDENCE OF CANCER AMONG WAITERS WILL DECREASE IN THE FUTURE, DUE TO THE BANNING OF TOBACCO SMOKING IN RESTAURANTS AND BARS IN THE NORDIC...

  19. Radiological incidents in radiotherapy

    International Nuclear Information System (INIS)

    Hobzova, L.; Novotny, J.

    2008-01-01

    In many countries a reporting system of radiological incidents to national regulatory body exists and providers of radiotherapy treatment are obliged to report all major and/or in some countries all incidents occurring in institution. State Office for Nuclear Safety (SONS) is providing a systematic guidance for radiotherapy departments from 1997 by requiring inclusion of radiation safety problems into Quality assurance manual, which is the basic document for obtaining a license of SONS for handling with sources of ionizing radiation. For that purpose SONS also issued the recommendation 'Introduction of QA system for important sources in radiotherapy-radiological incidents' in which the radiological incidents are defined and the basic guidance for their classification (category A, B, C, D), investigation and reporting are given. At regular periods the SONS in co-operation with radiotherapy centers is making a survey of all radiological incidents occurring in institutions and it is presenting obtained information in synoptic communication (2003 Motolske dny, 2005 Novy Jicin). This presentation is another summary report of radiological incidents that occurred in our radiotherapy institutions during last 3 years. Emphasis is given not only to survey and statistics, but also to analysis of reasons of the radiological incidents and to their detection and prevention. Analyses of incidents in radiotherapy have led to a much broader understanding of incident causation. Information about the error should be shared as early as possible during or after investigation by all radiotherapy centers. Learning from incidents, errors and near misses should be a part of improvement of the QA system in institutions. Generally, it is recommended that all radiotherapy facilities should participate in the reporting, analyzing and learning system to facilitate the dissemination of knowledge throughout the whole country to prevent errors in radiotherapy.(authors)

  20. Arguments for fundamental emission by the parametric process L yields T + S in interplanetary type III bursts. [langmuir, electromagnetic, ion acoustic waves (L, T, S)

    Science.gov (United States)

    Cairns, I. H.

    1984-01-01

    Observations of low frequency ion acoustic-like waves associated with Langmuir waves present during interplanetary Type 3 bursts are used to study plasma emission mechanisms and wave processes involving ion acoustic waves. It is shown that the observed wave frequency characteristics are consistent with the processes L yields T + S (where L = Langmuir waves, T = electromagnetic waves, S = ion acoustic waves) and L yields L' + S proceeding. The usual incoherent (random phase) version of the process L yields T + S cannot explain the observed wave production time scale. The clumpy nature of the observed Langmuir waves is vital to the theory of IP Type 3 bursts. The incoherent process L yields T + S may encounter difficulties explaining the observed Type 3 brightness temperatures when Langmuir wave clumps are incorporated into the theory. The parametric process L yields T + S may be the important emission process for the fundamental radiation of interplanetary Type 3 bursts.

  1. The Adsorption Langmuir Model of Transfer Metal Ti, V and Mn on System Water-Sediment in Along Side Code River, Yogyakarta

    International Nuclear Information System (INIS)

    Rini Jati Wardani; Muzakky; Agus Taftazani

    2007-01-01

    The adsorption langmuir model of transfer metal Ti, V and Mn on system water-sediment in along side Code river, Yogyakarta has been studied. For that purpose, the study is to make prediction about adsorption langmuir model of identified metal Ti, V and Mn from upstream until downstream samples water and sediment in along side Code river. The factor influenced of langmuir adsorption on transfer metal Ti, V and Mn in system water-sediment is Total Suspended Solid (TSS). The analysis showed that between TSS with metal concentration in sediment have linear correlation. The result of calculation from curve of langmuir isotherm, showed for Ti has R 2 = 0.8006 with capacities of adsorption = 0.5 mol/l and energy of adsorption = 13.286 J/mol, V has R 2 = 0.9883 with capacities of adsorption = 0.0137 mol/l and energy of adsorption = 16.64 J/mol, Mn has R 2 = 0.9624 with capacities of adsorption 0.152 mol/l and energy of adsorption = 10.51 J/mol. The conclusion from this topic about adsorption langmuir for metal Ti, V and Mn according to energy of langmuir adsorption by chemisorption process above 10 J/mo. (author)

  2. Police Incident Blotter (Archive)

    Data.gov (United States)

    Allegheny County / City of Pittsburgh / Western PA Regional Data Center — The Police Blotter Archive contains crime incident data after it has been validated and processed to meet Uniform Crime Reporting (UCR) standards, published on a...

  3. 2011 Japanese Nuclear Incident

    Science.gov (United States)

    EPA’s RadNet system monitored the environmental radiation levels in the United States and parts of the Pacific following the Japanese Nuclear Incident. Learn about EPA’s response and view historical laboratory data and news releases.

  4. Prediction of Safety Incidents

    Data.gov (United States)

    National Aeronautics and Space Administration — Safety incidents, including injuries, property damage and mission failures, cost NASA and contractors thousands of dollars in direct and indirect costs. This project...

  5. Marine Animal Incident Database

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — Large whale stranding, death, ship strike and entanglement incidents are all recorded to monitor the health of each population and track anthropogenic factors that...

  6. Acute incidents during anaesthesia

    African Journals Online (AJOL)

    management of acute incidents and the prevention of ... High or total (complete) spinal blocks in obstetric .... Pain and opioid analgesics lead to delayed ... Step up postoperative care and use ... recognise suprasternal and supraclavicular.

  7. Diffusion barrier characteristics of co monolayer prepared by Langmuir Blodgett technique

    Energy Technology Data Exchange (ETDEWEB)

    Sharma, Sumit, E-mail: sumitelsd2007@gmail.com [Electronic Science Department, Kurukshetra University, Kurukshetra, Haryana 136119 (India); Kumar, Mukesh, E-mail: kumarmukesh@gmail.com [Department of Electrical Engineering, College of Engineering at Wadi Aldawasir, Prince Sattam Bin Abdulaziz University, Wadi Aldawasir 11991 (Saudi Arabia); Rani, Sumita [Electronic Science Department, Kurukshetra University, Kurukshetra, Haryana 136119 (India); Kumar, Dinesh, E-mail: dineshelsd@gmail.com [Electronic Science Department, Kurukshetra University, Kurukshetra, Haryana 136119 (India)

    2016-04-30

    Graphical abstract: Thermal stability of structures (a) Cu/SiO{sub 2}/Si and (b) Cu/Co/SiO{sub 2}/Si, indicating that presence of thin cobalt layer improves the thermal stability of the structure up to 600 °C. - Highlights: • Monolayers of cobalt were deposited on SiO{sub 2}/Si substrates using LB technique. • Copper layers were deposited on this structures using thermal evaporation method. • Thermal stability was determined by annealing the structures at various temperatures. • The structure was found to be stable up to 650 °C. - Abstract: Monolayers of Co over SiO{sub 2}/Si substrate were deposited using Langmuir Blodgett (LB) technique. The diffusion barrier capability of Co layer was evaluated against copper diffusion. The structure of the deposited Co layer was analyzed using X-ray photoelectron spectroscopy (XPS), Energy Dispersive X-ray Spectroscopy (EDS) and Atomic force microscopy (AFM) techniques. Thermal stability of Cu/SiO{sub 2}/Si and Cu/Co/SiO{sub 2}/Si test structures was studied and compared using X-ray diffraction (XRD), scanning electron microscope (SEM) and four probe techniques. The samples were annealed at different temperatures starting from 200 °C up to 700 °C in vacuum for 30 min. XRD results indicated that combination of Co/SiO{sub 2} worked as diffusion barrier up to 550 °C whereas SiO{sub 2} alone could work as barrier only up to 300 °C. Sheet resistance of these samples was measured as a function of annealing temperature which also supports XRD results. C–V curves of these structures under the influence of Biased Thermal Stress (BTS) were analyzed. BTS was applied at 2.5 MV cm{sup −1} at 150 °C. Results showed that in the presence of Co barrier layer there was no shift in the C–V curve even after 90 min of BTS while in the absence of barrier there was a significant shift in the C–V curve even after 30 min of BTS. Further these test structures were examined for leakage current density (j{sub L}) at same BTS

  8. Electron acoustic-Langmuir solitons in a two-component electron plasma

    Science.gov (United States)

    McKenzie, J. F.

    2003-04-01

    We investigate the conditions under which ‘high-frequency’ electron acoustic Langmuir solitons can be constructed in a plasma consisting of protons and two electron populations: one ‘cold’ and the other ‘hot’. Conservation of total momentum can be cast as a structure equation either for the ‘cold’ or ‘hot’ electron flow speed in a stationary wave using the Bernoulli energy equations for each species. The linearized version of the governing equations gives the dispersion equation for the stationary waves of the system, from which follows the necessary but not sufficient conditions for the existence of soliton structures; namely that the wave speed must be less than the acoustic speed of the ‘hot’ electron component and greater than the low-frequency compound acoustic speed of the two electron populations. In this wave speed regime linear waves are ‘evanescent’, giving rise to the exponential growth or decay, which readily can give rise to non-linear effects that may balance dispersion and allow soliton formation. In general the ‘hot’ component must be more abundant than the ‘cold’ one and the wave is characterized by a compression of the ‘cold’ component and an expansion in the ‘hot’ component necessitating a potential dip. Both components are driven towards their sonic points; the ‘cold’ from above and the ‘hot’ from below. It is this transonic feature which limits the amplitude of the soliton. If the ‘hot’ component is not sufficiently abundant the window for soliton formation shrinks to a narrow speed regime which is quasi-transonic relative to the ‘hot’ electron acoustic speed, and it is shown that smooth solitons cannot be constructed. In the special case of a very cold electron population (i.e. ‘highly supersonic’) and the other population being very hot (i.e. ‘highly subsonic’) with adiabatic index 2, the structure equation simplifies and can be integrated in terms of elementary

  9. Theoretical and experimental study of a non-linear disintegration process for a langmuir wave; Etude theorique et experimental d'un processus non lineaire de desintegration d'une onde de langmuir

    Energy Technology Data Exchange (ETDEWEB)

    Perulli, M [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1968-07-01

    Using the Vlasov equation we calculate and discuss non-linear coupling equations between three electronic plasma waves (Langmuir waves) which propagate in a cylindrical plasma column confined by a strong magnetic field. We study, in the experimental device EOS, along the magnetic field, the disintegration of a Langmuir wave excited in the plasma column by means of an antenna. Space structure measurements for various waves show that the resonance conditions (selection rules) are satisfied. The measured disintegration threshold is in agreement with the theoretical value within 30 per cent and shows that this non linear mechanism appears when the oscillating density to the mean density ratio is about 10{sup -3} to 10{sup -2}. The variation of the spatial growth rate as a function of the amplitude of the disintegrated wave shows that the resulting waves are correlated in groups of three along the magnetic field even though the disintegrating spectrum appears in a wide frequency band. (author) [French] A partir de l'equation de Vlasov nous calculons et discutons les equations de couplage non lineaire entre trois ondes plasma electroniques (ou ondes de Langmuir) qui se propagent dans une colonne de plasma cylindrique confinee par un champ magnetique de forte intensite. Nous etudions, dans le dispositif experimental EOS, le long du champ magnetique, la desintegration d'une onde de Langmuir excitee dans la colonne de plasma a l'aide d'une antenne. La mesure de la structure spatiale des differentes ondes montre que l'ensemble des conditions de resonance (ou regles de selection) sont satisfaites. Le seuil de desintegration mesure est en accord avec la valeur theorique a 30 pour cent pres et montre que ce mecanisme non lineaire apparait lorsque le rapport de la densite oscillante a la densite moyenne est de l'ordre de 10{sup -3} a 10{sup -2}. La variation du taux de croissance spatiale en fonction de l'amplitude de l'onde qui se desintegre montre que les ondes restent trois

  10. Theoretical and experimental study of a non-linear disintegration process for a langmuir wave; Etude theorique et experimental d'un processus non lineaire de desintegration d'une onde de langmuir

    Energy Technology Data Exchange (ETDEWEB)

    Perulli, M. [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

    1968-07-01

    Using the Vlasov equation we calculate and discuss non-linear coupling equations between three electronic plasma waves (Langmuir waves) which propagate in a cylindrical plasma column confined by a strong magnetic field. We study, in the experimental device EOS, along the magnetic field, the disintegration of a Langmuir wave excited in the plasma column by means of an antenna. Space structure measurements for various waves show that the resonance conditions (selection rules) are satisfied. The measured disintegration threshold is in agreement with the theoretical value within 30 per cent and shows that this non linear mechanism appears when the oscillating density to the mean density ratio is about 10{sup -3} to 10{sup -2}. The variation of the spatial growth rate as a function of the amplitude of the disintegrated wave shows that the resulting waves are correlated in groups of three along the magnetic field even though the disintegrating spectrum appears in a wide frequency band. (author) [French] A partir de l'equation de Vlasov nous calculons et discutons les equations de couplage non lineaire entre trois ondes plasma electroniques (ou ondes de Langmuir) qui se propagent dans une colonne de plasma cylindrique confinee par un champ magnetique de forte intensite. Nous etudions, dans le dispositif experimental EOS, le long du champ magnetique, la desintegration d'une onde de Langmuir excitee dans la colonne de plasma a l'aide d'une antenne. La mesure de la structure spatiale des differentes ondes montre que l'ensemble des conditions de resonance (ou regles de selection) sont satisfaites. Le seuil de desintegration mesure est en accord avec la valeur theorique a 30 pour cent pres et montre que ce mecanisme non lineaire apparait lorsque le rapport de la densite oscillante a la densite moyenne est de l'ordre de 10{sup -3} a 10{sup -2}. La variation du taux de croissance spatiale en fonction de l'amplitude de l'onde qui se

  11. Plasma potential and electron temperature evaluated by ball-pen and Langmuir probes in the COMPASS tokamak

    Science.gov (United States)

    Dimitrova, M.; Popov, Tsv K.; Adamek, J.; Kovačič, J.; Ivanova, P.; Hasan, E.; López-Bruna, D.; Seidl, J.; Vondráček, P.; Dejarnac, R.; Stöckel, J.; Imríšek, M.; Panek, R.; the COMPASS Team

    2017-12-01

    The radial distributions of the main plasma parameters in the scrape-off-layer of the COMPASS tokamak are measured during L-mode and H-mode regimes by using both Langmuir and ball-pen probes mounted on a horizontal reciprocating manipulator. The radial profile of the plasma potential derived previously from Langmuir probes data by using the first derivative probe technique is compared with data derived using ball-pen probes. A good agreement can be seen between the data acquired by the two techniques during the L-mode discharge and during the H-mode regime within the inter-ELM periods. In contrast with the first derivative probe technique, the ball-pen probe technique does not require a swept voltage and, therefore, the temporal resolution is only limited by the data acquisition system. In the electron temperature evaluation, in the far scrape-off layer and in the limiter shadow, where the electron energy distribution is Maxwellian, the results from both techniques match well. In the vicinity of the last closed flux surface, where the electron energy distribution function is bi-Maxwellian, the ball-pen probe technique results are in agreement with the high-temperature components of the electron distribution only. We also discuss the application of relatively large Langmuir probes placed in parallel and perpendicularly to the magnetic field lines to studying the main plasma parameters. The results obtained by the two types of the large probes agree well. They are compared with Thomson scattering data for electron temperatures and densities. The results for the electron densities are compared also with the results from ASTRA code calculation of the electron source due to the ionization of the neutrals by fast electrons and the origin of the bi-Maxwellian electron energy distribution function is briefly discussed.

  12. Plasma potential and electron temperature evaluated by ball-pen and Langmuir probes in the COMPASS tokamak.

    Czech Academy of Sciences Publication Activity Database

    Dimitrova, Miglena; Popov, Tsv.K.; Adámek, Jiří; Kovačič, J.; Ivanova, P.; Hasan, E.; López-Bruna, D.; Seidl, Jakub; Vondráček, Petr; Dejarnac, Renaud; Stöckel, Jan; Imríšek, Martin; Pánek, Radomír

    2017-01-01

    Roč. 59, č. 12 (2017), č. článku 125001. ISSN 0741-3335 R&D Projects: GA ČR(CZ) GA15-10723S; GA MŠk(CZ) LM2015045 Institutional support: RVO:61389021 Keywords : Plasma potential * electron temperature * bi-Maxwellian EEDF * ball-pen probe * Langmuir probe * COMPASS tokamak * last closed flux surface Subject RIV: BL - Plasma and Gas Discharge Physics OBOR OECD: Fluids and plasma physics (including surface physics) Impact factor: 2.392, year: 2016

  13. Interaction of the modulated electron beam with inhomogeneous plasma: plasma density profile deformation and langmuir waves excitation

    International Nuclear Information System (INIS)

    Anisimov, I.O.; Kelnyk, O.I.; Soroka, S.V.; Siversky, T.V.

    2005-01-01

    Nonlinear deformation of the initially linear plasma density profile due to the modulated electron beam is studied via computer simulation. In the initial time period the field slaves to the instantaneous profile of the plasma density. Langmuir waves excitation is suppressed by the density profile deformation. The character of the plasma density profile deformation for the late time period depends significantly on the plasma properties. Particularly, for plasma with hot electrons quasi-periodic generation of ion-acoustic pulses takes place in the vicinity of the initial point of plasma resonance

  14. Towards Fast Measurement of the Electron Temperature in the SOL of ASDEX Upgrade Using Swept Langmuir Probes

    Czech Academy of Sciences Publication Activity Database

    Müller, H. W.; Adámek, Jiří; Horáček, Jan; Ionita, C.; Mehlmann, F.; Rohde, V.; Schrittwieser, R.

    2010-01-01

    Roč. 50, č. 9 (2010), s. 847-853 ISSN 0863-1042. [International Workshop on Electric Probes in Magnetized Plasmas/8th./. Innsbruck, 21.09.2009-24.09.2009] R&D Projects: GA AV ČR KJB100430901; GA ČR GA202/09/1467 Institutional research plan: CEZ:AV0Z20430508 Keywords : Tokamak * Langmuir probe * swept probe * ball-pen probe * fast temperature measurement * ELM Subject RIV: BL - Plasma and Gas Discharge Physics Impact factor: 1.006, year: 2010 http://onlinelibrary.wiley.com/doi/10.1002/ctpp.201010144/pdf

  15. Validating the collision-dominated Child-Langmuir law for a dc discharge cathode sheath in an undergraduate laboratory

    International Nuclear Information System (INIS)

    Lisovskiy, V; Yegorenkov, V

    2009-01-01

    In this paper, we propose a simple method of observing the collision-dominated Child-Langmuir law in the course of an undergraduate laboratory work devoted to studying the properties of gas discharges. To this end we employ the dc gas discharge whose properties are studied in sufficient detail. The undergraduate laboratory work itself is reduced to registering the voltage drop across the electrodes, the discharge current as well as the cathode sheath thickness. We can easily perform the measurements of all three quantities with sufficient accuracy in a laboratory equipped with vacuum pumps.

  16. Hazmat Yearly Incident Summary Reports

    Data.gov (United States)

    Department of Transportation — Series of Incident data and summary statistics reports produced which provide statistical information on incidents by type, year, geographical location, and others....

  17. Pattern Formation in Langmuir Monolayers Due to Long-Range Electrostatic Interactions

    Science.gov (United States)

    Fischer, Thomas M.; Lösche, Mathias

    A distinctive characteristic of Langmuir monolayers that bears important consequences for the physics of structure formation within membranes is the uniaxial orientation of the constituent dipolar molecules, brought about by the symmetry break which is induced by the surface of the aqueous substrate. The association of oriented molecular dipoles with the interface leads to the formation of image dipoles within the polarizeable medium - the subphase - such that the effective dipole orientation of every of the individual molecules is strictly normal to the surface, even within molecularly disordered phases. As a result, dipole-dipole repulsions play an eminently important role for the molecular interactions within the system - independent of the state of phase (while the dipole area density does of course depend on the state of phase) - and control the morphogenesis of the phase boundaries in their interplay with the one-dimensional (1D) line tension between coexisting phases. The physics of these phenomena is only now being explored and is particularly exciting for systems within a three-phase coexistence region where complete or partial wetting, as well as dewetting between the coexisting phases may be experimentally observed by applying fluorescence microscopy to the monolayer films. It is revealed that the wetting behavior depends sensitively on the details of the electrostatic interactions, in that the apparent contact angles observed at three-phase contact points depends on the sizes of the coexisting phases. This is in sharp contrast to the physics of wetting in conventional 3D systems where the contact angle is a materials property, independent of the local details. In 3D systems, this leads to Youngs equation - which has been established more than two centuries ago. We report recent progress in the understanding of this unusual and rather unexpected behavior of a quasi-2D system by reviewing recent experimental results from optical microscopy on equilibrium

  18. Radiation incidents in dentistry

    International Nuclear Information System (INIS)

    Lovelock, D.J.

    1996-01-01

    Most dental practitioners act as their own radiographer and radiologist, unlike their medical colleagues. Virtually all dental surgeons have a dental X-ray machine for intraoral radiography available to them and 40% of dental practices have equipment for dental panoramic tomography. Because of the low energy of X-ray equipment used in dentistry, radiation incidents tend to be less serious than those associated with other aspects of patient care. Details of 47 known incidents are given. The advent of the 1985 and 1988 Ionising Radiation Regulations has made dental surgeons more aware of the hazards of radiation. These regulations, and general health and safety legislation, have led to a few dental surgeons facing legal action. Because of the publicity associated with these court cases, it is expected that there will be a decrease in radiation incidents arising from the practice of dentistry. (author)

  19. Preparation of porous monolayer film by immersing the stearic acid Langmuir-Blodgett monolayer on mica in salt solution

    Energy Technology Data Exchange (ETDEWEB)

    Wang, S. [Institute of Near-Field Optics and Nano Technology, School of Physics and Optoelectronic Technology, Dalian University of Technology, Street No. 2 Linggong Road, Dalian 116024 (China); Li, Y.L.; Zhao, H.L.; Liang, H. [Institute of Photo-Biophysics, School of Physics and Electronic, Henan University, Jinming, Kaifeng 475004, Henan (China); Liu, B., E-mail: boliu@henu.edu.cn [Institute of Photo-Biophysics, School of Physics and Electronic, Henan University, Jinming, Kaifeng 475004, Henan (China); Pan, S., E-mail: span@dlut.edu.cn [Institute of Near-Field Optics and Nano Technology, School of Physics and Optoelectronic Technology, Dalian University of Technology, Street No. 2 Linggong Road, Dalian 116024 (China)

    2012-11-15

    Highlights: Black-Right-Pointing-Pointer Porous film has been prepared by immersing the stearic acid Langmuir-Blodgett monolayer on mica in salt solution. Black-Right-Pointing-Pointer The mechanism relies on the electrostatic screening effect of the cations in salt solution. Black-Right-Pointing-Pointer The factors influencing the size and area of the pores were investigated. - Abstract: Porous materials have drawn attention from scientists in many fields such as life sciences, catalysis and photonics since they can be used to induce some materials growth as expected. Especially, porous Langmuir-Blodgett (LB) film is an ideal material with controlled thickness and flat surface. In this paper, stearic acid (SA), which has been extensively explored in LB film technique, is chosen as the template material with known parameters to prepare the LB film, and then the porous SA monolayer film is obtained by means of etching in salt solution. The main etching mechanism is suggested that the cations in the solution block the electrostatic interaction between the polar carboxyl group of SA and the electronegative mica surface. The influencing factors (such as concentration of salt solution, valence of cation and surface pressure) of the porous SA film are systematically studied in this work. The novel method proposed in this paper makes it convenient to prepare porous monolayer film for designed material growth or cell culture.

  20. Analysis of wall-embedded Langmuir probe signals in different conditions on the Tokamak à Configuration Variable

    Science.gov (United States)

    Février, O.; Theiler, C.; De Oliveira, H.; Labit, B.; Fedorczak, N.; Baillod, A.

    2018-05-01

    This paper presents the current wall-embedded Langmuir probe system installed on the Tokamak à Configuration Variable (TCV), as well as the analysis tool chain used to interpret the current-voltage characteristic obtained when the probes are operated in swept-bias conditions. The analysis is based on a four-parameter fit combined with a minimum temperature approach. In order to reduce the effect of plasma fluctuations and measurement noise, several current-voltage characteristics are usually averaged before proceeding to the fitting. The impact of this procedure on the results is investigated, as well as the possible role of finite resistances in the circuitry, which could lead to an overestimation of the temperature. We study the application of the procedure in a specific regime, the plasma detachment, where results from other diagnostics indicate that the electron temperature derived from the Langmuir probes might be overestimated. To address this issue, we explore other fitting models and, in particular, an extension of the asymmetric double probe fit, which features effects of sheath expansion. We show that these models yield lower temperatures (up to approximately 60%) than the standard analysis in detached conditions, particularly for a temperature peak observed near the plasma strike point, but a discrepancy with other measurements remains. We explore a possible explanation for this observation, the presence of a fast electron population, and assess how robust the different methods are in such conditions.

  1. Carbon Nanotubes and Algal Polysaccharides To Enhance the Enzymatic Properties of Urease in Lipid Langmuir-Blodgett Films.

    Science.gov (United States)

    Rodrigues, Raul T; Morais, Paulo V; Nordi, Cristina S F; Schöning, Michael J; Siqueira, José R; Caseli, Luciano

    2018-03-06

    Algal polysaccharides (extracellular polysaccharides) and carbon nanotubes (CNTs) were adsorbed on dioctadecyldimethylammonium bromide Langmuir monolayers to serve as a matrix for the incorporation of urease. The physicochemical properties of the supramolecular system as a monolayer at the air-water interface were investigated by surface pressure-area isotherms, surface potential-area isotherms, interfacial shear rheology, vibrational spectroscopy, and Brewster angle microscopy. The floating monolayers were transferred to hydrophilic solid supports, quartz, mica, or capacitive electrolyte-insulator-semiconductor (EIS) devices, through the Langmuir-Blodgett (LB) technique, forming mixed films, which were investigated by quartz crystal microbalance, fluorescence spectroscopy, and field emission gun scanning electron microscopy. The enzyme activity was studied with UV-vis spectroscopy, and the feasibility of the thin film as a urea sensor was essayed in an EIS sensor device. The presence of CNT in the enzyme-lipid LB film not only tuned the catalytic activity of urease but also helped to conserve its enzyme activity. Viability as a urease sensor was demonstrated with capacitance-voltage and constant capacitance measurements, exhibiting regular and distinctive output signals over all concentrations used in this work. These results are related to the synergism between the compounds on the active layer, leading to a surface morphology that allowed fast analyte diffusion owing to an adequate molecular accommodation, which also preserved the urease activity. This work demonstrates the feasibility of employing LB films composed of lipids, CNT, algal polysaccharides, and enzymes as EIS devices for biosensing applications.

  2. Surface correlation behaviors of metal-organic Langmuir-Blodgett films on differently passivated Si(001) surfaces

    Science.gov (United States)

    Bal, J. K.; Kundu, Sarathi

    2013-03-01

    Langmuir-Blodgett films of standard amphiphilic molecules like nickel arachidate and cadmium arachidate are grown on wet chemically passivated hydrophilic (OH-Si), hydrophobic (H-Si), and hydrophilic plus hydrophobic (Br-Si) Si(001) surfaces. Top surface morphologies and height-difference correlation functions g(r) with in-plane separation (r) are obtained from the atomic force microscopy studies. Our studies show that deposited bilayer and trilayer films have self-affine correlation behavior irrespective of different passivations and different types of amphiphilic molecules, however, liquid like correlation coexists only for a small part of r, which is located near the cutoff length (1/κ) or little below the correlation length ξ obtained from the liquid like and self-affine fitting, respectively. Thus, length scale dependent surface correlation behavior is observed for both types of Langmuir-Blodgett films. Metal ion specific interactions (ionic, covalent, etc.,) in the headgroup and the nature of the terminated bond (polar, nonpolar, etc.,) of Si surface are mainly responsible for having different correlation parameters.

  3. Physicochemical and structural characterization of a two-dimensional polymer performed by using the Langmuir-Blodgett technique

    International Nuclear Information System (INIS)

    Lefevre, Didier

    1995-01-01

    This research thesis addresses the physicochemical and structural characterization of two-dimensional polymer made of polymerizable macro-cycles pre-organised in-plane by using the Langmuir-Blodgett technique. Macro-cycles are porphyrins with four acetylenic functions which bind in both plane directions by formation of diacetylenic covalent bonds. These porphyrins are adsorbed under a single layer of dihexadecyl-phosphoric acid to build up a monomer amphiphilic film. The author reports the characterization of the Langmuir film by the study of compression isotherms and by Brewster angle microscopy. Other techniques are used (UV, visible and infrared spectroscopy, Raman spectroscopy) to highlight the polymerization in LB film. X photo-electronic spectroscopy and secondary ion mass spectroscopy are also used. The author reports the study of the orientation of macro-cycles before and after polymerization by using linear dichroism, electronic paramagnetic resonance and X ray diffraction. The in-plane LB film structure is studied by transmission X ray diffraction, atomic force microscopy in correlation with molecular simulation. The two-dimensional feature of the polymer formed at the water surface is highlighted. The membrane is visualized by electronic and optic microscopy, and characterized by EDXS and electronic diffraction [fr

  4. Applicability of the Child-Langmuir laws versions for describing the glow discharge cathode sheath in CO2

    Science.gov (United States)

    Lisovskiy, Valeriy; Krol, Hennadii; Osmayev, Ruslan; Yegorenkov, Vladimir

    2016-09-01

    This work is devoted to the determination of the law that may be applicable to the description of the cathode sheath in CO2. To this end three versions of the Child-Langmuir law have been considered - a collision free one (for the ions moving through a cathode sheath without collisions with gas molecules) as well as two collision- related versions- one for a constant mean free path of positive ions and one for a constant mobility of positive ions. The current-voltage characteristics and the cathode sheath thickness of the glow discharge in carbon oxide have been simultaneously measured in the pressure range from 0.05 to 1 Torr and with the discharge current values up to 80 mA. The inter-electrode distance has been chosen such that the discharge consists only of the cathode sheath and a small portion of the negative glow, i.e. the experiments have been performed in short tubes. In this case the voltage drop across the cathode sheath is equal approximately to the voltage drop across the electrodes. In the whole range of the discharge conditions we have studied the cathode sheath characteristics are found to obey correctly only to the Child-Langmuir law version with a constant ion mobility. The reason for this phenomenon may be related with a significant conversion of carbon dioxide molecules.

  5. Examination of fluorination effect on physical properties of saturated long-chain alcohols by DSC and Langmuir monolayer.

    Science.gov (United States)

    Nakahara, Hiromichi; Nakamura, Shohei; Okahashi, Yoshinori; Kitaguchi, Daisuke; Kawabata, Noritake; Sakamoto, Seiichi; Shibata, Osamu

    2013-02-01

    Partially fluorinated long-chain alcohols have been newly synthesized from a radical reaction, which is followed by a reductive reaction. The fluorinated alcohols have been investigated by differential scanning calorimetry (DSC) and compression isotherms in a Langmuir monolayer state. Their melting points increase with an increase in chain length due to elongation of methylene groups. However, the melting points for the alcohols containing shorter fluorinated moieties are lower than those for the typical hydrogenated fatty alcohols. Using the Langmuir monolayer technique, surface pressure (π)-molecular area (A) and surface potential (ΔV)-A isotherms of monolayers of the fluorinated alcohols have been measured in the temperature range from 281.2 to 303.2K. In addition, a compressibility modulus (Cs(-1)) is calculated from the π-A isotherms. Four kinds of the alcohol monolayers show a phase transition (π(eq)) from a disordered to an ordered state upon lateral compression. The π(eq) values increase linearly with increasing temperatures. A slope of π(eq) against temperature for the alcohols with shorter fluorocarbons is unexpectedly larger than that for the corresponding fatty alcohols. Generally, fluorinated amphiphiles have a greater thermal stability (or resistance), which is a characteristic of highly fluorinated or perfluorinated compounds. Herein, however, the alcohols containing perfluorobutylated and perfluorohexylated chains show the irregular thermal behavior in both the solid and monolayer states. Copyright © 2012 Elsevier B.V. All rights reserved.

  6. Beyond the Child-Langmuir law: A review of recent results on multidimensional space-charge-limited flow

    International Nuclear Information System (INIS)

    Luginsland, J.W.; Lau, Y.Y.; Umstattd, R.J.; Watrous, J.J.

    2002-01-01

    Space-charge-limited (SCL) flows in diodes have been an area of active research since the pioneering work of Child and Langmuir in the early part of the last century. Indeed, the scaling of current density with the voltage to the 3/2's power is one of the best-known limits in the fields of non-neutral plasma physics, accelerator physics, sheath physics, vacuum electronics, and high power microwaves. In the past five years, there has been renewed interest in the physics and characteristics of SCL emission in physically realizable configurations. This research has focused on characterizing the current and current density enhancement possible from two- and three-dimensional geometries, such as field-emitting arrays. In 1996, computational efforts led to the development of a scaling law that described the increased current drawn due to two-dimensional effects. Recently, this scaling has been analytically derived from first principles. In parallel efforts, computational work has characterized the edge enhancement of the current density, leading to a better understanding of the physics of explosive emission cathodes. In this paper, the analytic and computational extensions to the one-dimensional Child-Langmuir law will be reviewed, the accuracy of SCL emission algorithms will be assessed, and the experimental implications of multidimensional SCL flows will be discussed

  7. Lightning incidents in Mongolia

    Directory of Open Access Journals (Sweden)

    Myagmar Doljinsuren

    2015-11-01

    Full Text Available This is one of the first studies that has been conducted in Mongolia on the distribution of lightning incidents. The study covers a 10-year period from 2004 to 2013. The country records a human death rate of 15.4 deaths per 10 million people per year, which is much higher than that of many countries with similar isokeraunic level. The reason may be the low-grown vegetation observed in most rural areas of Mongolia, a surface topography, typical to steppe climate. We suggest modifications to Gomes–Kadir equation for such countries, as it predicts a much lower annual death rate for Mongolia. The lightning incidents spread over the period from May to August with the peak of the number of incidents occurring in July. The worst lightning affected region in the country is the central part. Compared with impacts of other convective disasters such as squalls, thunderstorms and hail, lightning stands as the second highest in the number of incidents, human deaths and animal deaths. Economic losses due to lightning is only about 1% of the total losses due to the four extreme weather phenomena. However, unless precautionary measures are not promoted among the public, this figure of losses may significantly increase with time as the country is undergoing rapid industrialization at present.

  8. Incident users of antipsychotics

    DEFF Research Database (Denmark)

    Baandrup, Lone; Kruse, Marie

    2016-01-01

    PURPOSE: In Denmark, as well as in many other countries, consumption of antipsychotics is on the rise, partly due to increasing off-label use. The aim of this study was to analyze and quantify the extent of off-label use and polypharmacy in incident users of antipsychotic medication, and to examine...

  9. Incidents with hazardous radiation sources

    International Nuclear Information System (INIS)

    Schoenhacker, Stefan

    2016-01-01

    Incidents with hazardous radiation sources can occur in any country, even those without nuclear facilities. Preparedness for such incidents is supposed to fulfill globally agreed minimum standards. Incidents are categorized in incidents with licensed handling of radiation sources as for material testing, transport accidents of hazardous radiation sources, incidents with radionuclide batteries, incidents with satellites containing radioactive inventory, incidents wit not licensed handling of illegally acquired hazardous radiation sources. The emergency planning in Austria includes a differentiation according to the consequences: incidents with release of radioactive materials resulting in restricted contamination, incidents with release of radioactive materials resulting in local contamination, and incidents with the hazard of e@nhanced exposure due to the radiation source.

  10. Maximum Credible Incidents

    CERN Document Server

    Strait, J

    2009-01-01

    Following the incident in sector 34, considerable effort has been made to improve the systems for detecting similar faults and to improve the safety systems to limit the damage if a similar incident should occur. Nevertheless, even after the consolidation and repairs are completed, other faults may still occur in the superconducting magnet systems, which could result in damage to the LHC. Such faults include both direct failures of a particular component or system, or an incorrect response to a “normal” upset condition, for example a quench. I will review a range of faults which could be reasonably expected to occur in the superconducting magnet systems, and which could result in substantial damage and down-time to the LHC. I will evaluate the probability and the consequences of such faults, and suggest what mitigations, if any, are possible to protect against each.

  11. Contaminated Mexican steel incident

    International Nuclear Information System (INIS)

    1985-01-01

    This report documents the circumstances contributing to the inadvertent melting of cobalt 60 (Co-60) contaminated scrap metal in two Mexican steel foundries and the subsequent distribution of contaminated steel products into the United States. The report addresses mainly those actions taken by US Federal and state agencies to protect the US population from radiation risks associated with the incident. Mexico had much more serious radiation exposure and contamination problems to manage. The United States Government maintained a standing offer to provide technical and medical assistance to the Mexican Government. The report covers the tracing of the source to its origin, response actions to recover radioactive steel in the United States, and return of the contaminated materials to Mexico. The incident resulted in significant radiation exposures within Mexico, but no known significant exposure within the United States. Response to the incident required the combined efforts of the Nuclear Regulatory Commission (NRC), Department of Energy, Department of Transportation, Department of State, and US Customs Service (Department of Treasury) personnel at the Federal level and representatives of all 50 State Radiation Control Programs and, in some instances, local and county government personnel. The response also required a diplomatic interface with the Mexican Government and cooperation of numerous commercial establishments and members of the general public. The report describes the factual information associated with the event and may serve as information for subsequent recommendations and actions by the NRC. 8 figures

  12. Comparative studies of the laser Thomson scattering and Langmuir probe methods for measurements of negative ion density in a glow discharge plasma

    International Nuclear Information System (INIS)

    Noguchi, M; Hirao, T; Shindo, M; Sakurauchi, K; Yamagata, Y; Uchino, K; Kawai, Y; Muraoka, K

    2003-01-01

    The newly developed method of the negative ion density measurement in a plasma by laser Thomson scattering (LTS) was checked by comparing the obtained results against an independent technique, namely the Langmuir probe method. Both measurements were performed at the same position of the same inductively coupled plasma. The results agree quite well with each other and this has given confidence in the LTS method of negative ion density measurement. At the same time, both methods are complementary to each other, because the Langmuir probe measurement requires knowledge of the positive ion mass number

  13. Simulation of Micro-Channel and Micro-Orifice Flow Using Lattice Boltzmann Method with Langmuir Slip Model

    Directory of Open Access Journals (Sweden)

    A. R. Rahmati

    2016-12-01

    Full Text Available Because of its kinetic nature and computational advantages, the Lattice Boltzmann method (LBM has been well accepted as a useful tool to simulate micro-scale flows. The slip boundary model plays a crucial role in the accuracy of solutions for micro-channel flow simulations. The most used slip boundary condition is the Maxwell slip model. The results of Maxwell slip model are affected by the accommodation coefficient significantly, but there is not an explicitly relationship between properties at wall and accommodation coefficient. In the present wok, Langmuir slip model is used beside LBM to simulate micro-channel and micro-orifice flows. Slip velocity and nonlinear pressure drop profiles are presented as two major effects in such flows. The results are in good agreement with existing results in the literature.

  14. Aggregation of non-amphiphilic bathophenanthroline in the restricted geometry of Langmuir-Blodgett films with two different matrices

    Energy Technology Data Exchange (ETDEWEB)

    Pal, Ajitesh [Centre of Studies in Surface Science and Technology, School of Chemistry, Sambalpur University, Jyoti Vihar-768019, Orissa (India); Panigrahi, Simanchalo [Department of Physics, National Institute of Technology, Rourkela-788011, Orissa (India); Nath, Ranendu Kumar [Department of Chemistry, Tripura University, Suryamaninagar-799130, Tripura (India); Deb, Subrata [Department of Physics, Iswar Chandra Vidyasagar College, Belonia-799155, Tripura (India); Sinha, Tripurari Prasad [Department of Physics, Bose Institute, Kolkata-700009, West Bengal (India); Mishra, Bijay Kumar, E-mail: bijaym@hotmail.com [Centre of Studies in Surface Science and Technology, School of Chemistry, Sambalpur University, Jyoti Vihar-768019, Orissa (India)

    2011-10-31

    The behavior of binary mixed Langmuir monolayers from the mixture of non-amphiphilic bathophenanthroline (BPH) and behenic acid (BA)/poly(methyl methacrylate) (PMMA) spread on aqueous subphase was investigated on the basis of the analysis of surface pressure-average area per molecule ({pi}-A) isotherms complemented with UV-vis absorption spectroscopy and scanning electron microscopy. In addition, the miscibility of the components in the two investigated mixed systems (BPH/BA and BPH/PMMA) was also tested by using additivity and surface phase rules. The plots of area per molecule versus mole fraction suggest that BPH and BA are immiscible, whereas BPH and PMMA mixtures show non-ideal behavior at low surface pressures and complete miscibility or immiscibility at higher surface pressures. Spectroscopic study reveals that J-type of aggregates is formed in the mixed films. Scanning electron microscopic study supports the presence of aggregates.

  15. Conversion of Langmuir-Blodgett monolayers and bilayers of poly(amic acid) through polyimide to graphene

    Science.gov (United States)

    Jo, Hye Jin; Lyu, Ji Hong; Ruoff, Rodney S.; Lim, Hyunseob; In Yoon, Seong; Jeong, Hu Young; Shin, Tae Joo; Bielawski, Christopher W.; Shin, Hyeon Suk

    2017-03-01

    Various solid carbon sources, particularly poly(methyl methacrylate), have been used as precursors to graphene. The corresponding growth process generally involves the decomposition of the solids to hydrocarbon gases followed by their adsorption on metallic substrates (e.g., Cu). We report a different approach that uses a thermally-resistant polyimide (PI) as a carbon precursor. Langmuir-Blodgett films of poly(amic acid) (PAA) were transferred to copper foils and then converted to graphene via a PI intermediate. The Cu foil substrate was also discovered to facilitate the orientation of aromatic moieties upon carbonization process of the PI. As approximately 50% of the initial quantity of the PAA was found to remain at 1000 °C, thermally-stable polymers may reduce the quantity of starting material required to prepare high quality films of graphene. Graphene grown using this method featured a relatively large domain size and an absence of adventitious adlayers.

  16. The red, purple and blue modifications of polymeric unsymmetrical hydroxyalkadiynyl-N-arylcarbamate derivatives in Langmuir-Schaefer films

    Energy Technology Data Exchange (ETDEWEB)

    Alekseev, Alexander, E-mail: alexanderalekseev@yandex.ru [A. M. Prokhorov General Physics Institute, Russian Academy of Sciences, Moscow 119991 (Russian Federation); Ihalainen, Petri, E-mail: petri.ihalainen@abo.fi [Laboratory of Physical Chemistry, Center for Functional Materials, Åbo Akademi University, Turku FI-20500 (Finland); Ivanov, Artem [A. M. Prokhorov General Physics Institute, Russian Academy of Sciences, Moscow 119991 (Russian Federation); Domnin, Ivan [Department of Chemistry, St. Petersburg State University, Peterhof, St. Petersburg 198904 (Russian Federation); Klechkovskaya, Vera; Orekhov, Anton [Shubnikov Institute of Crystallography, Russian Academy of Science, Moscow 119333 (Russian Federation); NRC Kurchatov Institute, Moscow 123182 (Russian Federation); Lemmetyinen, Helge; Vuorimaa-Laukkanen, Elina [Department of Chemistry and Bioengineering, Tampere University of Technology, Tampere FI-33101 (Finland); Peltonen, Jouko [Laboratory of Physical Chemistry, Center for Functional Materials, Åbo Akademi University, Turku FI-20500 (Finland); Vyaz' min, Sergey [Laboratory of Nanobiotechnologies, St. Petersburg Academic University-Nanotechnology Research and Education Centre, Russian Academy of Science, St. Petersburg 194021 (Russian Federation)

    2016-08-01

    Solid topochemical photopolymerization (STP) of Langmuir-Schaefer films of a new class of unsymmetrical diynes, containing N-arylcarbamate groups in the hydrophobic part and hydroxymethylene groups in the hydrophilic part of the molecules was examined. In addition, the monomeric Langmuir monolayer formation was studied by Brewster angle microscopy and the surface morphology of monomer and polymer films on solid substrates were studied by scanning electron microscopy and atomic force microscopy. Three phases of polydiacetylene (PDA) (red, purple and blue) were observed after UV-light polymerization of above-mentioned films of alcohol diacetylene (DA) derivatives. The substitution of MeO group in the aryl ring substituent by hydrogen atom and the variation of the methylene group number in the hydrophobic part from 5 to 6 changed significantly the result of STP: instead of blue phase PDA observed for diynes with MeO group, the red phase PDA was observed for DA with H-atom from the very beginning of diyne film UV irradiation. For two other diynilic N-arylcarbamates of identical chemical structures except of the substituents in the aryl ring of hydrophobic parts of the molecules, no changes in the efficiency of polymerization or the position and shape of absorption bands were observed. This indicated the formation of the purple phase PDA. For these molecules, the number of methylene groups in hydrophobic and hydrophilic parts of the molecules was 9 and 2, respectively. - Highlights: • STP reaction of diacetylenes in LS films depends on number and ratio of CH{sub 2} groups. • Three phases of polydiacetylene (red, purple and blue) were observed in LS films. • Structural organization of the monomer film determines the type of polymer phase.

  17. Interfacial and thermal energy driven growth and evolution of Langmuir-Schaefer monolayers of Au-nanoparticles.

    Science.gov (United States)

    Mukhopadhyay, Mala; Hazra, S

    2018-01-03

    Structures of Langmuir-Schaefer (LS) monolayers of thiol-coated Au-nanoparticles (DT-AuNPs) deposited on H-terminated and OTS self-assembled Si substrates (of different hydrophobic strength and stability) and their evolution with time under ambient conditions, which plays an important role for their practical use as 2D-nanostructures over large areas, were investigated using the X-ray reflectivity technique. The strong effect of substrate surface energy (γ) on the initial structures and the competitive role of room temperature thermal energy (kT) and the change in interfacial energy (Δγ) at ambient conditions on the evolution and final structures of the DT-AuNP LS monolayers are evident. The strong-hydrophobic OTS-Si substrate, during transfer, seems to induce strong attraction towards hydrophobic DT-AuNPs on hydrophilic (repulsive) water to form vertically compact partially covered (with voids) monolayer structures (of perfect monolayer thickness) at low pressure and nearly covered buckled monolayer structures (of enhanced monolayer thickness) at high pressure. After transfer, the small kT-energy (in absence of repulsive water) probably fluctuates the DT-AuNPs to form vertically expanded monolayer structures, through systematic exponential growth with time. The effect is prominent for the film deposited at low pressure, where the initial film-coverage and film-thickness are low. On the other hand, the weak-hydrophobic H-Si substrate, during transfer, appears to induce optimum attraction towards DT-AuNPs to better mimic the Langmuir monolayer structures on it. After transfer, the change in the substrate surface nature, from weak-hydrophobic to weak-hydrophilic with time (i.e. Δγ-energy, apart from the kT-energy), enhances the size of the voids and weakens the monolayer/bilayer structure to form a similar expanded monolayer structure, the thickness of which is probably optimized by the available thermal energy.

  18. Direct calculation of unambiguous electron-density distributions of Langmuir-Blodgett films normal to the membrane plane

    International Nuclear Information System (INIS)

    Frieling, M. von; Bradaczek, H.

    1990-01-01

    In regard to X-ray diffraction, Langmuir-Blodgett (LB) films consisting of lipid bilayers represent a 'one-dimensional crystal' with a very small number of unit cells in the direction of stacking. Such bounded systems yield X-ray diffraction diagrams which, in certain respects, contain more information than those of the conventional effectively infinite single crystals. This additional information consists of the profiles of the broadened reflections and their dislocation from the reciprocal-lattice points. These profiles are specific for each different structure and hence enable the direct calculation of unambiguous electron-density distributions from a single set of intensity data. At first, the Q function (the generalized Patterson function), i.e. the distance statistics of the structure sought after is calculated from the intensity data. Thereafter, the unambiguous convolution square root of the Q function must be determined, which is identical to the unknown electron-density distribution. For this purpose two mathematically completely different methods were established and compared. They were applied to diffraction patterns of Langmuir-Blodgett films of simple synthetic lipids with characteristic molecular subunits and showed identical results within the experimental resolution. This verifies the structures and the methods to calculate them. Furthermore, all features of the simple structures were compatible with the expectations. All one-dimensional electron-density distributions showed the common features of lipid bilayers. The characteristic molecular subunits can be recognized and reveal some interesting details. In general, they yield information about orientation, conformation and localization of molecular subunits and membrane components. (orig.)

  19. Medication incidents reported to an online incident reporting system.

    LENUS (Irish Health Repository)

    Alrwisan, Adel

    2011-01-15

    AIMS: Approximately 20% of deaths from adverse events are related to medication incidents, costing the NHS an additional £500 million annually. Less than 5% of adverse events are reported. This study aims to assess the reporting rate of medication incidents in NHS facilities in the north east of Scotland, and to describe the types and outcomes of reported incidents among different services. Furthermore, we wished to quantify the proportion of reported incidents according to the reporters\\' profession. METHODS: A retrospective description was made of medication incidents reported to an online reporting system (DATIX) over a 46-month-period (July 2005 to April 2009). Reports originated from acute and community hospitals, mental health, and primary care facilities. RESULTS: Over the study period there were 2,666 incidents reported with a mean monthly reporting rate of 78.2\\/month (SD±16.9). 6.1% of all incidents resulted in harm, with insulin being the most commonly implicated medication. Nearly three-quarters (74.2%, n=1,978) of total incidents originated from acute hospitals. Administration incidents were implicated in the majority of the reported medication incidents (59%), followed by prescribing (10.8%) and dispensing (9.9%), while the nondescript "other medication incidents" accounted for 20.3% of total incidents. The majority of reports were made by nursing and midwifery staff (80%), with medical and dental professionals reporting the lowest number of incidents (n=56, 2%). CONCLUSIONS: The majority of medication incidents in this study were reported by nursing and midwifery staff, and were due to administration incidents. There is a clear need to elucidate the reasons for the limited contribution of the medical and dental professionals to reporting medication incidents.

  20. Prevalence Incidence Mixture Models

    Science.gov (United States)

    The R package and webtool fits Prevalence Incidence Mixture models to left-censored and irregularly interval-censored time to event data that is commonly found in screening cohorts assembled from electronic health records. Absolute and relative risk can be estimated for simple random sampling, and stratified sampling (the two approaches of superpopulation and a finite population are supported for target populations). Non-parametric (absolute risks only), semi-parametric, weakly-parametric (using B-splines), and some fully parametric (such as the logistic-Weibull) models are supported.

  1. Improving freight crash incident management.

    Science.gov (United States)

    2015-06-01

    The objective of this study was to determine the most effective way to mitigate the effect of freight : crash incidents on Louisiana freeways. Candidate incident management strategies were reviewed from : practice in other states and from those publi...

  2. Increasing incidence of pyogenic spondylodiscitis

    DEFF Research Database (Denmark)

    Kehrer, Michala; Pedersen, Court; Jensen, Thøger G

    2014-01-01

    Smaller studies indicate that the incidence of pyogenic spondylodiscitis is increasing, possible related to a growing elderly population. Data supporting this is sparse, and we therefore studied patient characteristics and changes in spondylodiscitis incidence 1995-2008.......Smaller studies indicate that the incidence of pyogenic spondylodiscitis is increasing, possible related to a growing elderly population. Data supporting this is sparse, and we therefore studied patient characteristics and changes in spondylodiscitis incidence 1995-2008....

  3. Simulation studies of plasma waves in the electron foreshock - The generation of Langmuir waves by a gentle bump-on-tail electron distribution

    Science.gov (United States)

    Dum, C. T.

    1990-01-01

    Particle simulation experiments were used to study the basic physical ingredients needed for building a global model of foreshock wave phenomena. In particular, the generation of Langmuir waves by a gentle bump-on-tail electron distribution is analyzed. It is shown that, with appropriately designed simulations experiments, quasi-linear theory can be quantitatively verified for parameters corresponding to the electron foreshock.

  4. Review of Langmuir-wave-caused dips and charge-exchange-caused dips in spectral lines from plasmas and their applications

    Czech Academy of Sciences Publication Activity Database

    Dalimier, E.; Oks, E.; Renner, Oldřich

    2014-01-01

    Roč. 2, č. 2 (2014), s. 178-194 ISSN 2218-2004 Grant - others:AVČR(CZ) M100101208 Institutional support: RVO:68378271 Keywords : Laser-matter interaction * spectral line profiles * Langmuir waves * plasma electron density * charge exchange rates Subject RIV: BL - Plasma and Gas Discharge Physics

  5. Langmuir monolayers of non-ionic polymers: Equilibrium of metastability? Case study of PEO and its PPO-PEO diblock copolymers

    NARCIS (Netherlands)

    Deschenes, L.; Saint-Germain, F.; Lyklema, J.

    2015-01-01

    Stability and reorganization in Langmuir films of PEO in PEO homopolymers and PPO–PEO block copolymers were investigated using film balance measurements. The apparent fractional losses of EO segments transferred into the subphase resulting from successive compression–expansion cycles have been

  6. Synthesis of organosilicon derivatives of [1]benzothieno[3,2-b][1]-benzothiophene for efficient monolayer Langmuir-Blodgett organic field effect transistors.

    Science.gov (United States)

    Borshchev, O V; Sizov, A S; Agina, E V; Bessonov, A A; Ponomarenko, S A

    2017-01-16

    For the first time, the synthesis of organosilicon derivatives of dialkyl[1]benzothieno[3,2-b][1]-benzothiophene (BTBT) capable of forming a semiconducting monolayer at the water-air interface is reported. Self-assembled monolayer organic field-effect transistors prepared from these materials using the Langmuir-Blodgett technique showed high hole mobilities and excellent air stability.

  7. A three-parameter langmuir-type model for fitting standard curves of sandwich enzyme immunoassays with special attention to the α-fetoprotein assay

    NARCIS (Netherlands)

    Kortlandt, W.; Endeman, H.J.; Hoeke, J.O.O.

    In a simplified approach to the reaction kinetics of enzyme-linked immunoassays, a Langmuir-type equation y = [ax/(b + x)] + c was derived. This model proved to be superior to logit-log and semilog models in the curve-fitting of standard curves. An assay for α-fetoprotein developed in our laboratory

  8. Incident Management: Process into Practice

    Science.gov (United States)

    Isaac, Gayle; Moore, Brian

    2011-01-01

    Tornados, shootings, fires--these are emergencies that require fast action by school district personnel, but they are not the only incidents that require risk management. The authors have introduced the National Incident Management System (NIMS) and the Incident Command System (ICS) and assured that these systems can help educators plan for and…

  9. Utilização dos modelos de Langmuir e de Freundlich na adsorção de cobre e zinco em solos Brasileiros Langmuir and Freundlich models applied to copper and zinc adsorption in Brazilian soils

    Directory of Open Access Journals (Sweden)

    Lucília Alves Linhares

    2010-07-01

    Full Text Available Objetivou-se com este trabalho estudar o processo de adsorção de cobre e zinco em seis solos naturais do Estado de Minas Gerais e avaliar a influência que propriedades dos solos, como pH, capacidade de troca de cátions, teores de argila e de óxidos de ferro exercem no referido processo. Para construção das curvas de adsorção de cobre e zinco foram tomados 1 g de solo, em triplicata, suspensos em 25 mL de solução contendo os metais individualmente na forma de nitrato, preparadas em CaCl2 0,01 mol L-1 nas concentrações de 0 a 100 µg mL-1 e de 0 a 40 µg mL-1, respectivamente. A quantidade adsorvida dos elementos foi determinada indiretamente pelas quantidades dos mesmos, determinadas no sobrenadante, após a adsorção e os dados ajustados à isoterma de Langmuir e de Freundlich. Os solos com maiores teores de argila, óxidos de ferro e de pH mais elevado (Latossolo Vermelho distrófico, Chernossolo Argilúvico Carbonático saprolítico e Cambissolo Háplico Tb eutrófico latossólico, foram os que apresentaram os maiores valores de energia de ligação e capacidade máxima de adsorção, obtidos das isotermas de Langmuir. Estes resultados indicam uma baixa disponibilidade desses metais quando presentes no solo como contaminantes. Isso pode ser entendido como condição favorável, à priori, de menor contaminação do lençol freático. Para o Plintossolo Pétrico concrecionário distrófico, Cambissolo Háplico Tb distrófico típico e Neossolo Quartzarênico órtico latossólico os metais tendem ficar menos retidos e ou mais fracamente retidos aos constituintes do solo, tornando-se mais disponíveis à lixiviação.The objective of this work was to evaluate the adsorption of copper and zinc and the influence of soil properties, pH, cation exchange capacity, clay and iron oxide contents, in six natural soils of Minas Gerais State, Brazil. The copper and zinc adsorption curves were plotted for triplicate soil samples (1 g suspended

  10. Synthesis of amphiphilic macrocyclic molecules from family of aza-porphyrins and study in Langmuir-Blodgett films; Synthese de molecules macrocycliques amphiphiles de la famille des azaporphyrines et etude en films de Langmuir-Blodgett

    Energy Technology Data Exchange (ETDEWEB)

    Palacin, Serge

    1988-03-04

    The cellular automata, also called formal neurons, directly inspired by the knowledge concerning the nervous system, are able to mimic some basic processes of brain, as shape recognition, connecting memory, information sorting... This work aims to build a molecular structure able to fit the working rules of a bidimensional cellular automata. So, amphiphilic molecules belonging to the aza-porphyrin family are synthesized and organized into a planar paving by the Langmuir-Blodgett technique. The regular structure of the outcoming ultra-thin films is studied by linear dichroism and anisotropic electron spin resonance. The physico-chemical behaviour of the amphiphilic molecules is studied and brings about an explanation of the redox phenomena which are observed on the monomolecular film on the water surface. So are we able to outline the future chemical addressing ways of the bidimensional cellular automata. In the end of this dissertation, different ways likely to insure covalent bindings between the active sites and allow the transfer of information within the cellular network are discussed. (author) [French] Les reseaux d'automates, aussi appeles neurones formels, directement inspires par les connaissances nouvelles concernant le fonctionnement du systeme nerveux, sont a l'heure actuelle capables de reproduire certaines operations fondamentales du cerveau, telles que la reconnaissance de forme, la memoire associative, le tri d'information... Le travail a pour but de realiser une structure moleculaire susceptible d'obeir aux regles de fonctionnement d'un automate cellulaire bi-dimensionnel. Dans ce but, des molecules amphiphiles de la famille des azaporphyrines sont synthetisees et organisees en un pavage plan par la methode de Langmuir-Blodgett. La structure reguliere des films ultraminces obtenus est determinee par dichroisme lineaire et resonance paramagnetique electronique anisotrope. Les caracteristiques physico-chimiques des molecules amphiphiles sont etudiees

  11. Grazing incidence beam expander

    Energy Technology Data Exchange (ETDEWEB)

    Akkapeddi, P.R.; Glenn, P.; Fuschetto, A.; Appert, Q.; Viswanathan, V.K.

    1985-01-01

    A Grazing Incidence Beam Expander (GIBE) telescope is being designed and fabricated to be used as an equivalent end mirror in a long laser resonator cavity. The design requirements for this GIBE flow down from a generic Free Electron Laser (FEL) resonator. The nature of the FEL gain volume (a thin, pencil-like, on-axis region) dictates that the output beam be very small. Such a thin beam with the high power levels characteristic of FELs would have to travel perhaps hundreds of meters or more before expanding enough to allow reflection from cooled mirrors. A GIBE, on the other hand, would allow placing these optics closer to the gain region and thus reduces the cavity lengths substantially. Results are presented relating to optical and mechanical design, alignment sensitivity analysis, radius of curvature analysis, laser cavity stability analysis of a linear stable concentric laser cavity with a GIBE. Fabrication details of the GIBE are also given.

  12. Cancer incidence among firefighters

    DEFF Research Database (Denmark)

    Pukkala, Eero; Martinsen, Jan Ivar; Weiderpass, Elisabete

    2014-01-01

    OBJECTIVES: Firefighters are potentially exposed to a wide range of known and suspected carcinogens through their work. The objectives of this study were to examine the patterns of cancer among Nordic firefighters, and to compare them with the results from previous studies. METHODS: Data for this......OBJECTIVES: Firefighters are potentially exposed to a wide range of known and suspected carcinogens through their work. The objectives of this study were to examine the patterns of cancer among Nordic firefighters, and to compare them with the results from previous studies. METHODS: Data...... for this study were drawn from a linkage between the census data for 15 million people from the five Nordic countries and their cancer registries for the period 1961-2005. SIR analyses were conducted with the cancer incidence rates for the entire national study populations used as reference rates. RESULTS......: A total of 16 422 male firefighters were included in the final cohort. A moderate excess risk was seen for all cancer sites combined, (SIR=1.06, 95% CI 1.02 to 1.11). There were statistically significant excesses in the age category of 30-49 years in prostate cancer (SIR=2.59, 95% CI 1.34 to 4...

  13. Precursor incident program at EDF

    International Nuclear Information System (INIS)

    Fourest, B.; Maliverney, B.; Rozenholc, M.; Piovesan, C.

    1998-01-01

    The precursor program was started by EDF in 1994, after an investigation of the US NRC's Accident Sequence Precursor Program. Since then, reported operational events identified as Safety Outstanding Events have been analyzed whenever possible using probabilistic methods based on PSAs. Analysis provides an estimate of the remaining protection against core damage at the time the incident occurred. Measuring the incidents' severity enables to detect incidents important regarding safety. Moreover, the most efficient feedback actions can be derived from the main accident sequences identified through the analysis. Therefore, incident probabilistic analysis provides a way to assess priorities in terms of treatment and resource allocation, and so, to implement countermeasures preventing further occurrence and development of the most significant incidents. As some incidents cannot be analyzed using this method, probabilistic analysis can only be one among the methods used to assess the nuclear power plants' safety level. Nevertheless, it provides an interesting complement to classical methods of deterministic studies. (author)

  14. Architecture effects of glucose oxidase/Au nanoparticle composite Langmuir-Blodgett films on glucose sensing performance

    Science.gov (United States)

    Wang, Ke-Hsuan; Wu, Jau-Yann; Chen, Liang-Huei; Lee, Yuh-Lang

    2016-03-01

    The Langmuir-Blodgett (LB) deposition technique is employed to prepare nano-composite films consisting of glucose oxidase (GOx) and gold nanoparticles (AuNPs) for glucose sensing applications. The GOx and AuNPs are co-adsorbed from an aqueous solution onto an air/liquid interface in the presence of an octadecylamine (ODA) template monolayer, forming a mixed (GOx-AuNP) monolayer. Alternatively, a composite film with a cascade architecture (AuNP/GOx) is also prepared by sequentially depositing monolayers of AuNPs and GOx. The architecture effects of the composite LB films on the glucose sensing are studied. The results show that the presence of AuNPs in the co-adsorption system does not affect the adsorption amount and preferred conformation (α-helix) of GOx. Furthermore, the incorporation of AuNPs in both composite films can significantly improve the sensing performance. However, the enhancement effects of the AuNPs in the two architectures are distinct. The major effect of the AuNPs is on the facilitation of charge-transfer in the (GOx-AuNP) film, but on the increase of catalytic activity in the (AuNP/GOx) one. Therefore, the sensing performance can be greatly improved by utilizing a film combining both architectures (AuNP/GOx-AuNP).

  15. Measurements of plasma profiles using a fast swept Langmuir probe in the VINETA-II magnetic reconnection experiment

    Science.gov (United States)

    Shesterikov, I.; Von Stechow, A.; Grulke, O.; Stenzel, R.; Klinger, T.

    2017-07-01

    A fast-swept Langmuir probe capable to be biased at a high voltages has been constructed and successfully operated at the VINETA-II magnetic reconnection experiment. The presented circuit has two main features beneficial for fast transient parameter changes in laboratory experiments as, e.g., plasma guns or magnetic reconnection: the implementation simplicity and the high voltage sweep range. This work presents its design and performance for time-dependent measurements of VINETA-II plasmas. The probe is biased with a sinusoidal voltage at a fixed frequency. Current - voltage characteristics are measured along the falling and rising slopes of the probe bias. The sweep frequency is fsweep= 150 kHz. The spatiotemporal evolution of radial plasma profiles is obtained by evaluation of the probe characteristics. The plasma density measurements agree with those derived from a microwave interferometer, demonstrating the reliability of the measurements. As a model plasma system, a plasma gun discharge with typical pulse times of 60 μ s is chosen.

  16. Langmuir probe study of a magnetically enhanced RF plasma source at pressures below 0.1 Pa

    Science.gov (United States)

    Kousal, Jaroslav; Tichý, Milan; Šebek, Ondřej; Čechvala, Juraj; Biederman, Hynek

    2011-08-01

    The majority of plasma polymerization sources operate at pressures higher than 1 Pa. At these pressures most common deposition methods do not show significant directionality. One way of enhancing the directional effects is to decrease the working pressure to increase the mean free path of the reactive molecules. The plasma source used in this work was designed to study the plasma polymerization process at pressures below 0.1 Pa. The source consists of the classical radio frequency (RF) (13.56 MHz, capacitive coupled) tubular reactor enhanced by an external magnetic circuit. The working gas is introduced into the discharge by a capillary. This forms a relatively localized zone of higher pressure where the monomer is activated. Due to the magnetic field, the plasma is constricted near the axis of the reactor with nearly collisionless gas flow. The plasma parameters were obtained using a double Langmuir probe. Plasma density in the range ni = 1013-1016 m-3 was obtained in various parts of the discharge under typical conditions. The presence of the magnetic field led to the presence of relatively strong electric fields (103 V m-1) and relatively high electron energies up to several tens of eV in the plasma.

  17. Langmuir probe study of a magnetically enhanced RF plasma source at pressures below 0.1 Pa

    Energy Technology Data Exchange (ETDEWEB)

    Kousal, Jaroslav; Tichy, Milan; Sebek, Ondrej; Cechvala, Juraj; Biederman, Hynek, E-mail: jaroslav.kousal@mff.cuni.cz [Charles University in Prague, Faculty of Mathematics and Physics, V Holesovickach 2, 180 00, Prague 8 (Czech Republic)

    2011-08-15

    The majority of plasma polymerization sources operate at pressures higher than 1 Pa. At these pressures most common deposition methods do not show significant directionality. One way of enhancing the directional effects is to decrease the working pressure to increase the mean free path of the reactive molecules. The plasma source used in this work was designed to study the plasma polymerization process at pressures below 0.1 Pa. The source consists of the classical radio frequency (RF) (13.56 MHz, capacitive coupled) tubular reactor enhanced by an external magnetic circuit. The working gas is introduced into the discharge by a capillary. This forms a relatively localized zone of higher pressure where the monomer is activated. Due to the magnetic field, the plasma is constricted near the axis of the reactor with nearly collisionless gas flow. The plasma parameters were obtained using a double Langmuir probe. Plasma density in the range n{sub i} = 10{sup 13}-10{sup 16} m{sup -3} was obtained in various parts of the discharge under typical conditions. The presence of the magnetic field led to the presence of relatively strong electric fields (10{sup 3} V m{sup -1}) and relatively high electron energies up to several tens of eV in the plasma.

  18. Structural and surface morphological studies of long chain fatty acid thin films deposited by Langmuir-Blodgett technique

    Energy Technology Data Exchange (ETDEWEB)

    Das, Nayan Mani, E-mail: nayanmanidas3@gmail.com [Department of Applied Physics, Indian School of Mines, Dhanbad 826004 (India); Roy, Dhrubojyoti [Department of Applied Physics, Indian School of Mines, Dhanbad 826004 (India); Gupta, Mukul [UGC-DAE Consortium for Scientific Research, University Campus, Khandwa Road, Indore 452017 (India); Gupta, P.S. [Department of Applied Physics, Indian School of Mines, Dhanbad 826004 (India)

    2012-12-15

    In the present work we aim to study the structural and surface morphological characteristics of divalent cation (cadmium ion, Cd{sup 2+}) induced thin mono- to multilayer films of fatty acids such as arachidic acid and stearic acid prepared by the Langmuir-Blodgett (LB) technique. These ultra thin films of various numbers of layers were studied by X-ray diffraction (XRD), X-ray reflectivity (XRR) and Atomic Force Microscopy (AFM). In this specific Y-type deposition, it was found that as the individual layer thickness increases, the corresponding layer by layer interfacial electron density of the thin films decreases. Since the fatty acid chain tries to maintain its minimum value of cross-sectional area, tilting occurs with respect to its nearest neighbor. The tilt angle calculated for 9 layers of cadmium arachidate (CdA{sub 2}) and cadmium stearate (CdSt{sub 2}) are 18 Degree-Sign and 19.5 Degree-Sign , respectively. An asymmetric air gap of thickness {approx}3 A was also seen between the tail parts of 2 molecular chains. The RMS roughness and average height factors calculated through AFM studies show non-uniform surface morphology of both CdA{sub 2} and CdSt{sub 2}, although the calculated topographic variations were found to have more irregularity in case of CdSt{sub 2} than in case of CdA{sub 2}.

  19. Use of Langmuir probe for analysis of charged particles in metal vapour generated by electron beam heating

    International Nuclear Information System (INIS)

    Dikshit, B; Bhatia, M S

    2008-01-01

    During electron beam evaporation of metal, a certain fraction of the vapor is ionized due to various processes such as Saha ionization and electron impact. These charge particles constitute a plasma which expands along with the vapour. To know about parameters of this plasma viz. electron temperature, electron density, plasma potential, we have used a disc type Langmuir probe inside the plasma. The measured electron temperature was found to be about ∼0.15eV (1740K) and measured plasma potential was ∼1V. The low value of electron temperature as compared to the source temperature, established that plasma cools significantly while traversing the distance between the source and the point of measurement. Again as the electron temperature was approximately same as the ion temperature of the vapor (expected to be same as kinetic temperature of vapor for collisional flow), we concluded that a kind of equilibrium had been established in the plasma. Finally, various processes responsible for ionization of the vapor are discussed and it was found that both Saha ionization and electron impact processes play important role in ionization of the uranium vapor generated by electron beam heating

  20. Fabrication of hydrogenase-cationic electrolyte biohybrids at interfaces and their electrochemical properties in Langmuir-Blodgett films

    International Nuclear Information System (INIS)

    Liu An; Zorin, Nikolay A.; Nakamura, Chikashi; Miyake, Jun; Qian Dongjin

    2010-01-01

    Hydrogenase (H 2 ase)-cationic electrolyte biohybrids were assembled at the air-water interface via intermolecular electrostatic interaction. The H 2 ase used was purified from the phototropic bacterium of Thiocapsa roseopersicina. Two kinds of cationic electrolyte compounds (CECs) were used, the difference of which was whether they contained viologen substituent or not. Surface pressure-area isotherms indicated that these CECs were co-existed with the H 2 ase in the monolayers, which were then transferred to substrate surfaces to form H 2 ase-CECs hybrid films by the Langmuir-Blodgett (LB) method. Uniform film was formed when polyelectrolyte was used as the subphase. Cyclic voltammograms (CVs) of the LB films showed a couple of redox waves in the potential range of -0.4 to -0.65 V vs. Ag/AgCl, which was ascribed to one electron process of either [4Fe-4S] clusters of H 2 ase or viologens of the CECs. A direct electron transfer between the H 2 ase and electrode surface was achieved in the LB films. Stronger current intensity was recorded when the CV measurements were done in H 2 saturated electrolyte solution than that in Ar. It was confirmed that the H 2 ase biocatalytic activity remained in the LB films. Thus, we suggest that the present H 2 ase-CECs biohybrids could act as potential materials for the studies of interconversion reaction of H 2 and protons.

  1. Langmuir probe-based observables for plasma-turbulence code validation and application to the TORPEX basic plasma physics experiment

    International Nuclear Information System (INIS)

    Ricci, Paolo; Theiler, C.; Fasoli, A.; Furno, I.; Labit, B.; Mueller, S. H.; Podesta, M.; Poli, F. M.

    2009-01-01

    The methodology for plasma-turbulence code validation is discussed, with focus on the quantities to use for the simulation-experiment comparison, i.e., the validation observables, and application to the TORPEX basic plasma physics experiment [A. Fasoli et al., Phys. Plasmas 13, 055902 (2006)]. The considered validation observables are deduced from Langmuir probe measurements and are ordered into a primacy hierarchy, according to the number of model assumptions and to the combinations of measurements needed to form each of them. The lowest levels of the primacy hierarchy correspond to observables that require the lowest number of model assumptions and measurement combinations, such as the statistical and spectral properties of the ion saturation current time trace, while at the highest levels, quantities such as particle transport are considered. The comparison of the observables at the lowest levels in the hierarchy is more stringent than at the highest levels. Examples of the use of the proposed observables are applied to a specific TORPEX plasma configuration characterized by interchange-driven turbulence.

  2. Diameter control of vertically aligned carbon nanotubes using CoFe2O4 nanoparticle Langmuir-Blodgett films

    Science.gov (United States)

    Tamiya, Shuhei; Sato, Taiga; Kushida, Masahito

    2018-03-01

    Vertically aligned carbon nanotubes (VA-CNTs) are suggested for utilization as a new catalyst support of polymer electrolyte fuel cells (PEFCs). The independent control of the diameter and number density of VA-CNTs is essential for application in PEFCs. As the catalyst for VA-CNT growth, we fabricated CoFe2O4 nanoparticle (NP) films using the Langmuir-Blodgett (LB) technique. Using the LB technique, we were able to separately control the diameter and number density of VA-CNTs. The number density of VA-CNTs was changed by mixing with the filler moleculer, palmitic acid (C16). The VA-CNT diameter was changed by the adjusting the CoFe2O4 NP diameter. However, the heat-induced aggregation of CoFe2O4 NPs occurred in thermal chemical vapor deposition to synthesize VA-CNTs. Therefore, we examined how to minimize the effect of heat-induced aggregation of CoFe2O4 NPs. As a result, selection of the appropriate number density and diameter of CoFe2O4 NPs was found to be important for the control of VA-CNT diameter.

  3. The neutron activation analysis in the study of Langmuir-Blodgett multilayers composition - relation to other methods of investigation

    International Nuclear Information System (INIS)

    Petrov, J.G.; Kulev, I.

    1985-01-01

    The features of the neutron activation analysis (NAA) used in the study of Langmuir-Blodget (LB) multilayers composition are compared with the following analytical techniques: radiometry, spectrophotometry, IR-spectroscopy and electron spectroscopy for chemical analysis. A very important advantage of NAA is possibility for the simultaneous determination of all the inorganic ions in the sample, especially when LB multilayers serve as models of biological systems. Thus competitive reactions of bivalent and monovalent cations (Ca 2+ /Na + , K + ) or specific reactions of counterions of equal charge (Zn 2+ /Cd 2+ . HPO 4 2- /HAsO 4 2- , SO 4 2- /CrO 4 2- ) can be investigated with great accuracy. The parallel application of onother analytical technique is necessary when the structure of the multilayers, their stability, the molecular interactions or the binding energies of the elements are to be studied. An attempt to classify roughly the applicability of each method to some particular counterions is given. Such characteristics as the lower limit of detection, simplicity of the analysis accessibility, rapidity, etc. have been taken into consideration

  4. Comparative measurements of plasma potential with ball-pen and Langmuir probe in low-temperature magnetized plasma

    International Nuclear Information System (INIS)

    Zanáška, M.; Kudrna, P.; Tichý, M.; Adámek, J.; Peterka, M.

    2015-01-01

    The ball-pen probe (BPP) is used for direct plasma potential measurements in magnetized plasma. The probe can adjust the ratio of the electron and ion saturation currents I sat − /I sat + to be close to one and therefore its I-V characteristic becomes nearly symmetric. If this is achieved, the floating potential of the BPP is close to the plasma potential. Because of its rather simple construction, it offers an attractive probe for measurements in magnetized plasma. Comparative measurements of plasma potential by BPPs of different dimensions as well as one Langmuir probe (LP) in an argon discharge plasma of a cylindrical magnetron were performed at various experimental conditions. An additional comparison by an emissive probe was also performed. All these types of probes provide similar values of plasma potential in a wide range of plasma parameters. Our results for three different BPP dimensions indicate that the BPP can be operated in a cylindrical magnetron DC argon discharge if the value of the ratio of the magnetic field and neutral gas pressure, B/p, is greater than approximately 10 mT/Pa

  5. Polyaniline Langmuir-Blodgett film modified glassy carbon electrode as a voltammetric sensor for determination of Ag+ ions

    International Nuclear Information System (INIS)

    Liu Qiongyan; Wang Fei; Qiao Yonghui; Zhang Shusheng; Ye Baoxian

    2010-01-01

    A highly sensitive electrochemical sensor made of a glassy carbon electrode (GCE) coated with a Langmuir-Blodgett film (LB) containing polyaniline (PAn) doped with p-toluenesulfonic acid (PTSA) (LB/PAn-PTSA/GCE) has been used for the detection of trace concentrations of Ag + . UV-vis absorption spectra indicated that the PAn was doped by PTSA. The surface morphology of the PAn LB film was characterized by atomic force microscopy (AFM). The electrochemical properties of this LB/PAn-PTSA/GCE were studied using electrochemical impedance spectroscopy (EIS) and cyclic voltammetry. The LB/PAn-PTSA/GCE was used as a voltammetric sensor for determination of trace Ag + at pH 5.0 using linear scanning stripping voltammetry. Under the optimal experimental conditions, the stripping current was proportional to the Ag + concentration over the range from 6.0 x 10 -10 mol L -1 to 1.0 x 10 -6 mol L -1 , with a detection limit of 4.0 x 10 -10 mol L -1 . The high sensitivity, selectivity, and stability of this LB/PAn-PTSA/GCE also demonstrated its practical utility for simple, rapid and economical determination of Ag + in water samples.

  6. Comparative measurements of plasma potential with ball-pen and Langmuir probe in low-temperature magnetized plasma

    Science.gov (United States)

    Zanáška, M.; Adámek, J.; Peterka, M.; Kudrna, P.; Tichý, M.

    2015-03-01

    The ball-pen probe (BPP) is used for direct plasma potential measurements in magnetized plasma. The probe can adjust the ratio of the electron and ion saturation currents Isat-/Isat+ to be close to one and therefore its I-V characteristic becomes nearly symmetric. If this is achieved, the floating potential of the BPP is close to the plasma potential. Because of its rather simple construction, it offers an attractive probe for measurements in magnetized plasma. Comparative measurements of plasma potential by BPPs of different dimensions as well as one Langmuir probe (LP) in an argon discharge plasma of a cylindrical magnetron were performed at various experimental conditions. An additional comparison by an emissive probe was also performed. All these types of probes provide similar values of plasma potential in a wide range of plasma parameters. Our results for three different BPP dimensions indicate that the BPP can be operated in a cylindrical magnetron DC argon discharge if the value of the ratio of the magnetic field and neutral gas pressure, B/p, is greater than approximately 10 mT/Pa.

  7. Comparative measurements of plasma potential with ball-pen and Langmuir probe in low-temperature magnetized plasma

    Energy Technology Data Exchange (ETDEWEB)

    Zanáška, M.; Kudrna, P.; Tichý, M. [Faculty of Mathematics and Physics, Charles University in Prague, Ke Karlovu 3, 12116 Prague 2 (Czech Republic); Adámek, J. [Institute of Plasma Physics AS CR, v.v.i., Za Slovankou 3, 18200 Prague 8 (Czech Republic); Peterka, M. [Faculty of Mathematics and Physics, Charles University in Prague, Ke Karlovu 3, 12116 Prague 2 (Czech Republic); Institute of Plasma Physics AS CR, v.v.i., Za Slovankou 3, 18200 Prague 8 (Czech Republic)

    2015-03-15

    The ball-pen probe (BPP) is used for direct plasma potential measurements in magnetized plasma. The probe can adjust the ratio of the electron and ion saturation currents I{sub sat}{sup −}/I{sub sat}{sup +} to be close to one and therefore its I-V characteristic becomes nearly symmetric. If this is achieved, the floating potential of the BPP is close to the plasma potential. Because of its rather simple construction, it offers an attractive probe for measurements in magnetized plasma. Comparative measurements of plasma potential by BPPs of different dimensions as well as one Langmuir probe (LP) in an argon discharge plasma of a cylindrical magnetron were performed at various experimental conditions. An additional comparison by an emissive probe was also performed. All these types of probes provide similar values of plasma potential in a wide range of plasma parameters. Our results for three different BPP dimensions indicate that the BPP can be operated in a cylindrical magnetron DC argon discharge if the value of the ratio of the magnetic field and neutral gas pressure, B/p, is greater than approximately 10 mT/Pa.

  8. Langmuir-Blodgett assembly of visible light responsive TiO{sub 2} nanotube arrays/graphene oxide heterostructure

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Ying; Gao, Hongyan; Wei, Danming; Dong, Xinju; Cao, Yan, E-mail: yan.cao@wku.edu

    2017-01-15

    Highlights: • First to report a heterostructure of TNA with GO prepared by LB assembly. • Much better photocurrent (32 μAcm{sup −2}) of TNA-GO, contrasting to TNA (12 μAcm{sup −2}). • Schottky junction formed between TNA and GO enhanced the photocurrent. • GO on TNA improved the hydrophilicity of TNA-GO. - Abstract: The hybrid nanocomposites of titanium dioxide (TiO{sub 2}) with graphene oxide (GO) have recently garnered much attention as electronic devices, energy conversion devices, photocatalysts and other applications. In this study, Langmuir-Blodgett (LB) assembly method was firstly reported to prepare a TiO{sub 2} nanotube arrays (TNA)-GO heterostructure. The as-prepared TNA-GO sample was characterized by X-ray diffraction, Raman spectra, scanning electron microscopy, transmission electron microscopy, energy dispersive X-ray spectroscopy and X-ray photoelectron spectroscopy. The promising characteristics of this TNA-GO material, the inexpensive, nontoxic and highly visible-light responsiveness, may raise the potential uses in many, various photocatalytic applications.

  9. Third-order nonlinearities and structural features in Langmuir-Blodgett films of 1-benzyl-9-hydrofullerene-60

    International Nuclear Information System (INIS)

    Shihong Ma; Liying Liu; Xingze Lu

    1995-01-01

    Third-order nonlinear susceptibilities χ xxxx (3) (-3ω; ω, ω, ω) have been deduced by measuring third-harmonic generation in Langmuir-Blodgett (LB) films of 1-benzyl-9-hydrofullerene-60 (C 60 -Be). The structural features of the condensed layer at the air-water interface and LB films of the C 60 -Be were investigated by small angle x-ray diffraction (SAXD) and optical measurements. The third-order nonlinear susceptibilities (χ (3) ) were obtained by measuring the THG intensities in LB films of C 60 -Be and comparing with that of CS 2 used as the reference. The value of χ xxxx (3) (2.1 x 10 -11 esu) was deduced at a 65 nm thick films. The χ (3) is attributed to a three-photon near resonance at the energy level of 29410 cm -1 . A new-type of two-chain amphiphilic molecule 1,10-bistearyl-4,6,13, 15-tetra-18-nitrogencrown-6 (NC) was used as insert material to construct mixed C 60 -Be/NC LB films. Our π-A, UV-visible absorption and SAXD measurements showed that the structural improvement in the mixed C 60 -Be/NC LB films was realized by insertion of the C 60 -Be molecules between the two hydrophobic chains of the NC molecules

  10. Single-Residue Sensitivity in Neutron Reflectivity and Resonant X-ray Reflectivity from Langmuir Monolayers of Synthetic Peptides

    Science.gov (United States)

    Strzalka, Joseph; Satija, Sushil; Dimasi, Elaine; Kuzmenko, Ivan; Gog, Thomas; Blasie, J. Kent

    2004-03-01

    Labeling groups with ^2H to distinguish them in the scattering length density (SLD) profile constitutes the chief advantage of neutron reflectivity (NR) in studying Langmuir monolayers (LM) of lipids and proteins. Solid phase synthesis (SPPS) permits the labeling of a single residue in a peptide. Recent work demonstrates the sensitivity of NR to single ^2H-labeled residues in LM of vectorially oriented α -helical bundle peptides. NR requires comparison of isomorphic samples of all-^1H and ^2H-labeled peptides. Alternately, resonant x-ray reflectivity (RXR) uses only one sample. RXR exploits energy-dependent changes in the scattering factor from heavy atoms to distinguish them within the SLD profile. Peptides may be labeled by SPPS (e.g. Br-Phe), or may have inherent labels (e.g. Fe in heme proteins). As test cases, we studied LM of Br-labeled lipids and peptides with RXR. Both approaches require a model-independent means of obtaining SLD profiles from the reflectivity data. We have applied box-refinement to obtain the gradient SLD profile. This is fit uniquely with a sum of Gaussians and integrated analytically [Blasie et al., PRB 67 224201 (2003)] to provide the SLD profile. Label positions can then be determined to sub-Ångstrom accuracy. This work supported by the NIH (GM55876).

  11. Heteroepitaxial growth of SiC films by carbonization of polyimide Langmuir-Blodgett films on Si

    Directory of Open Access Journals (Sweden)

    Goloudina S.I.

    2017-01-01

    Full Text Available High quality single crystal SiC films were prepared by carbonization of polyimide Langmuir-Blodgett films on Si substrate. The films formed after annealing of the polyimide films at 1000°C, 1100°C, 1200°C were studied by Fourier transform-infrared (FTIR spectroscopy, X-ray diffraction (XRD, Raman spectroscopy, transmission electon microscopy (TEM, transmission electron diffraction (TED, and scanning electron microscopy (SEM. XRD study and HRTEM cross-section revealed that the crystalline SiC film begins to grow on Si (111 substrate at 1000°C. According to the HRTEM cross-section image five planes in 3C-SiC (111 film are aligned with four Si(111 planes at the SiC/Si interface. It was shown the SiC films (35 nm grown on Si(111 at 1200°C have mainly cubic 3C-SiC structure with a little presence of hexagonal polytypes. Only 3C-SiC films (30 nm were formed on Si (100 substrate at the same temperature. It was shown the SiC films (30-35 nm are able to cover the voids in Si substrate with size up to 10 μm.

  12. Dynamical study of the radial structure of the fluctuations measured by a reciprocating Langmuir probe in Tore Supra

    International Nuclear Information System (INIS)

    Devynck, P.; Antar, G.; Wang, G.; Garbet, X.; Gunn, J.; Pascal, J.Y.

    1999-01-01

    The fluctuations in the Scrape Off Layer (S.O.L.) of Tore Supra are studied with a movable Langmuir probe biased to ion saturation current. The probe system consists of three probes separated poloidally (0.68 cm between two nearby probes). The probe has no magnetic connection to the mid plane limiter on which the plasma is leaning, but the radial profile of the ion saturation current fluctuations displays a dip at the limiter position. At the same location the ion saturation current displays a dip at the limiter position. At the same location the ion saturation current displays an inflexion point. A correlation analysis technique is developed to study the radial behaviour of the fluctuations. It reveals that this dip is associated with a reduction of the poloidal velocity of the fluctuations with no sign reversal. In the dip the mean poloidal correlation length of the fluctuations is also reduced. These observations are consistent with a reduction of the fluctuations by a shear of the radial electric field created at the limiter surface. The autocorrelation time is also calculated. It increases slightly in the dip and is found to be sensitive to both the convection time and lifetime of the turbulent structures, because these quantities are of the same order. (authors)

  13. Freundlich and Langmuir adsorption isotherms and kinetics for the removal of Tartrazine from aqueous solutions using hen feathers

    International Nuclear Information System (INIS)

    Mittal, Alok; Kurup, Lisha; Mittal, Jyoti

    2007-01-01

    Tartrazine, a yellow menace, is widely being used in cosmetics, foodstuffs, medicines and textile. It is carcinogenic and also catalyzes allergic problems. In the present work the ability to remove Tartrazine from aqueous solutions has been studied using waste material-hen feathers, as adsorbent. Effects of pH, concentration of the dye, temperature and adsorbent dosage have been studied. Equilibrium isotherms for the adsorption of the dye were measured experimentally. Results were analyzed by the Freundlich and Langmuir equation at different temperatures and determined the characteristic parameters for each adsorption isotherm. The adsorption process has been found endothermic in nature and thermodynamic parameters, Gibb's free energy (ΔG o ), change in enthalpy (ΔH o ) and change in entropy (ΔS o ) have been calculated. The paper also includes results on the kinetic measurements of adsorption of the dye on hen feathers at different temperatures. By rate expression and treatment of data it has been established that the adsorption of Tartrazine over hen feathers follows a first-order kinetics and a film diffusion mechanism operates at all the temperatures

  14. Hierarchically structured superhydrophobic coatings fabricated by successive Langmuir-Blodgett deposition of micro-/nano-sized particles and surface silanization.

    Science.gov (United States)

    Tsai, Ping-Szu; Yang, Yu-Min; Lee, Yuh-Lang

    2007-11-21

    The present study demonstrates the creation of a stable, superhydrophobic surface by coupling of successive Langmuir-Blodgett (LB) depositions of micro- and nano-sized (1.5 µm/50 nm, 1.0 µm/50 nm, and 0.5 µm/50 nm) silica particles on a glass substrate with the formation of a self-assembled monolayer of dodecyltrichlorosilane on the surface of the particulate film. Particulate films, in which one layer of 50 nm particles was deposited over one to five sublayers of larger micro-sized particles, with hierarchical surface roughness and superhydrophobicity, were successfully fabricated. Furthermore, the present 'two-scale' (micro- and nano-sized particles) approach is superior to the previous 'one-scale' (micro-sized particles) approach in that both higher advancing contact angle and lower contact angle hysteresis can be realized. Experimental results revealed that the superhydrophobicity exhibited by as-fabricated particulate films with different sublayer particle diameters increases in the order of 0.5 µm>1.0 µm>1.5 µm. However, no clear trend between sublayer number and surface superhydrophobicity could be discerned. An explanation of superhydrophobicity based on the surface roughness introduced by two-scale particles is also proposed.

  15. Relation between anchorings of liquid crystals and conformation changes in aligning agents by the Langmuir-Blodgett film technique investigation

    International Nuclear Information System (INIS)

    Zhu, Y.; Lu, Z.; Wei, Y.

    1995-01-01

    The anchoring direction of liquid crystals on a solid substrate surface depends upon many parameters characterizing the liquid-crystal--substrate interface, a variation of which may change this anchoring direction leading to the so-called anchoring transition. Here, based on the Langmuir-Blodgett film technique, we present two model systems to study the relation between anchoring directions and the conformation changes in aligning agents. A double-armed crown ether liquid crystal and a side chain polymer liquid crystal at an air-water interface both show phase transitions, accompanied by conformation changes. However, when the monolayers in different phases were transferred onto solid substrates to orient liquid crystals, we found that for the crown ether material the conformation change can alter the anchoring of liquid crystals between homeotropic and homogeneous alignments, while for the polymer liquid crystal, despite the conformation changes, the liquid crystals can only be aligned homeotropically. The involved mechanisms were briefly discussed in terms of the Landau-type phenomenological theory

  16. Preparation and voltammetric characterization of electrodes coated with Langmuir-Schaefer ultrathin films of Nafion®

    Directory of Open Access Journals (Sweden)

    Bertoncello Paolo

    2003-01-01

    Full Text Available Ultrathin films of Nafion® perfluorinated polymer were deposited on indium-tin oxide electrodes (ITO by using Langmuir-Schaefer (LS technique, after optimization of the subphase composition conditions. Morphological characteristics of these coatings were obtained by Atomic Force Microscopy (AFM. Nafion® LS films showed a good uniformity and complete coverage of the electrode surface, however a different organization degree of the polymer layer was evidenced with respect to thin films deposited by spin-coating. ITO electrodes modified with Nafion® LS coatings preconcentrate by ion-exchange electroactive cations, such as Ru[(NH36]3+, dissolved in diluted solutions. The electroactive species is retained by the Nafion® LS coated ITO also after transfer of the modified electrode into pure supporting electrolyte. This allowed the use of the ruthenium complex as voltammetric probe to test diffusion phenomena within the Nafion® LS films. Apparent diffusion coefficients (Dapp of Ru[(NH36]3+ incorporated in Nafion® LS films were obtained by voltammetric measurements. Dapp values decrease slightly by increasing the amount of ruthenium complex incorporated in the ultrathin film. They are significantly lower than values typical for recasted Nafion® films, in agreement with the highly condensed nature of the Nafion® LS fims.

  17. ATR-IR spectroscopy for the detection of induced-phase transition in Langmuir-Blodgett monolayer film

    International Nuclear Information System (INIS)

    Widayati, Suci

    1996-01-01

    The rate at which a solid substrate is transferred through the Air/Water interface in the Langmuir-Blodgett process of preparing monomolecular films influences the final structure of the transferred film. This phenomenon has been observed from the attenuated total reflectance infra-red (ATR-IR) spectra of fatty acid monolayer transferred onto germanium substrate. This transfer-induced effect is most evidence when the monolayer is transferred from an expanded region of the surface-pressure-molecular area isotherm, but has limited influence on the hydrocarbon chain conformation of film molecules transferred in the condensed phases at high surface pressure. Such a conformational ordering may due to a kinetically limited phase transition taking place in the meniscus formed between the solid substrate and aqueous sub phase. In addition, these results suggest that the structure of the amphiphilic molecules may modulate the extent and nature of the dipping-speed-induced structural changes taking place in the monomolecular L-B film. In order to use monomolecular L-B films to accurately characterize the structure, orientation and phase properties of monolayers at the Air/Water interface, the L-B transfer must be performed at transfer speeds that minimize this structural phase transition

  18. Freundlich and Langmuir adsorption isotherms and kinetics for the removal of Tartrazine from aqueous solutions using hen feathers

    Energy Technology Data Exchange (ETDEWEB)

    Mittal, Alok [Department of Applied Chemistry, Maulana Azad National Institute of Technology, Bhopal, 462 007 MP (India)]. E-mail: aljymittal@yahoo.co.in; Kurup, Lisha [Department of Applied Chemistry, Maulana Azad National Institute of Technology, Bhopal, 462 007 MP (India); Mittal, Jyoti [Department of Applied Chemistry, Maulana Azad National Institute of Technology, Bhopal, 462 007 MP (India)

    2007-07-19

    Tartrazine, a yellow menace, is widely being used in cosmetics, foodstuffs, medicines and textile. It is carcinogenic and also catalyzes allergic problems. In the present work the ability to remove Tartrazine from aqueous solutions has been studied using waste material-hen feathers, as adsorbent. Effects of pH, concentration of the dye, temperature and adsorbent dosage have been studied. Equilibrium isotherms for the adsorption of the dye were measured experimentally. Results were analyzed by the Freundlich and Langmuir equation at different temperatures and determined the characteristic parameters for each adsorption isotherm. The adsorption process has been found endothermic in nature and thermodynamic parameters, Gibb's free energy ({delta}G{sup o}), change in enthalpy ({delta}H{sup o}) and change in entropy ({delta}S{sup o}) have been calculated. The paper also includes results on the kinetic measurements of adsorption of the dye on hen feathers at different temperatures. By rate expression and treatment of data it has been established that the adsorption of Tartrazine over hen feathers follows a first-order kinetics and a film diffusion mechanism operates at all the temperatures.

  19. Freundlich and Langmuir adsorption isotherms and kinetics for the removal of Tartrazine from aqueous solutions using hen feathers.

    Science.gov (United States)

    Mittal, Alok; Kurup, Lisha; Mittal, Jyoti

    2007-07-19

    Tartrazine, a yellow menace, is widely being used in cosmetics, foodstuffs, medicines and textile. It is carcinogenic and also catalyzes allergic problems. In the present work the ability to remove Tartrazine from aqueous solutions has been studied using waste material-hen feathers, as adsorbent. Effects of pH, concentration of the dye, temperature and adsorbent dosage have been studied. Equilibrium isotherms for the adsorption of the dye were measured experimentally. Results were analyzed by the Freundlich and Langmuir equation at different temperatures and determined the characteristic parameters for each adsorption isotherm. The adsorption process has been found endothermic in nature and thermodynamic parameters, Gibb's free energy (DeltaG degrees), change in enthalpy (DeltaH degrees) and change in entropy (DeltaS degrees) have been calculated. The paper also includes results on the kinetic measurements of adsorption of the dye on hen feathers at different temperatures. By rate expression and treatment of data it has been established that the adsorption of Tartrazine over hen feathers follows a first-order kinetics and a film diffusion mechanism operates at all the temperatures.

  20. Two 238Pu inhalation incidents

    International Nuclear Information System (INIS)

    Fleming, R.R.; Hall, R.M.

    1978-06-01

    Two employees inhaled significant amounts of 238 Pu in separate unrelated contamination incidents in 1977. Both acute exposure incidents are described and the urine, feces, and in-vivo chest count data for each employee. Case B ( 238 PuNO 3 ) received 24 DTPA treatments beginning the day of the incident while, for medical reasons, Case A ( 238 PuO 2 ) received no therapy

  1. Goiania incident case study

    International Nuclear Information System (INIS)

    Petterson, J.S.

    1988-06-01

    The reasons for wanting to document this case study and present the findings are simple. According to USDOE technical risk assessments (and our own initial work on the Hanford socioeconomic study), the likelihood of a major accident involving exposure to radioactive materials in the process of site characterization, construction, operation, and closure of a high-level waste repository is extremely remote. Most would agree, however, that there is a relatively high probability that a minor accident involving radiological contamination will occur sometime during the lifetime of the repository -- for example, during transport, at an MRS site or at the permanent site itself during repacking and deposition. Thus, one of the major concerns of the Yucca Mountain Socioeconomic Study is the potential impact of a relatively minor radiation-related accident. A large number of potential impact of a relatively minor radiation-related accident. A large number of potential accident scenarios have been under consideration (such as a transportation or other surface accident which results in a significant decline in tourism, the number of conventions, or the selection of Nevada as a retirement residence). The results of the work in Goiania make it clear, however, that such a significant shift in established social patterns and trends is not likely to occur as a direct outcome of a single nuclear-related accident (even, perhaps, a relatively major one), but rather, are likely to occur as a result of the enduring social interpretations of such an accident -- that is, as a result of the process of understanding, communicating, and socially sustaining a particular set of associations with respect to the initial incident

  2. Grazing Incidence Optics Technology

    Science.gov (United States)

    Ramsey, Brian; Smith, W. Scott; Gubarev, Mikhail; McCracken, Jeff

    2015-01-01

    This project is to demonstrate the capability to directly fabricate lightweight, high-resolution, grazing-incidence x-ray optics using a commercially available robotic polishing machine. Typical x-ray optics production at NASA Marshall Space Flight Center (MSFC) uses a replication process in which metal mirrors are electroformed on to figured and polished mandrels from which they are later removed. The attraction of this process is that multiple copies can be made from a single master. The drawback is that the replication process limits the angular resolution that can be attained. By directly fabricating each shell, errors inherent in the replication process are removed. The principal challenge now becomes how to support the mirror shell during all aspects of fabrication, including the necessary metrology to converge on the required mirror performance specifications. This program makes use of a Zeeko seven-axis computer-controlled polishing machine (see fig. 1) and supporting fabrication, metrology, and test equipment at MSFC. The overall development plan calls for proof-of-concept demonstration with relatively thick mirror shells (5-6 mm, fig. 2) which are straightforward to support and then a transition to much thinner shells (2-3 mm), which are an order of magnitude thinner than those used for Chandra. Both glass and metal substrates are being investigated. Currently, a thick glass shell is being figured. This has enabled experience to be gained with programming and operating the polishing machine without worrying about shell distortions or breakage. It has also allowed time for more complex support mechanisms for figuring/ polishing and metrology to be designed for the more challenging thinner shells. These are now in fabrication. Figure 1: Zeeko polishing machine.

  3. Langmuir probes for SPIDER (source for the production of ions of deuterium extracted from radio frequency plasma) experiment: Tests in BATMAN (Bavarian test machine for negative ions)

    Science.gov (United States)

    Brombin, M.; Spolaore, M.; Serianni, G.; Pomaro, N.; Taliercio, C.; Palma, M. Dalla; Pasqualotto, R.; Schiesko, L.

    2014-11-01

    A prototype system of the Langmuir probes for SPIDER (Source for the production of Ions of Deuterium Extracted from RF plasma) was manufactured and experimentally qualified. The diagnostic was operated in RF (Radio Frequency) plasmas with cesium evaporation on the BATMAN (BAvarian Test MAchine for Negative ions) test facility, which can provide plasma conditions as expected in the SPIDER source. A RF passive compensation circuit was realised to operate the Langmuir probes in RF plasmas. The sensors' holder, designed to better simulate the bias plate conditions in SPIDER, was exposed to a severe experimental campaign in BATMAN with cesium evaporation. No detrimental effect on the diagnostic due to cesium evaporation was found during the exposure to the BATMAN plasma and in particular the insulation of the electrodes was preserved. The paper presents the system prototype, the RF compensation circuit, the acquisition system (as foreseen in SPIDER), and the results obtained during the experimental campaigns.

  4. Langmuir probes for SPIDER (source for the production of ions of deuterium extracted from radio frequency plasma) experiment: Tests in BATMAN (Bavarian test machine for negative ions)

    International Nuclear Information System (INIS)

    Brombin, M.; Spolaore, M.; Serianni, G.; Pomaro, N.; Taliercio, C.; Palma, M. Dalla; Pasqualotto, R.; Schiesko, L.

    2014-01-01

    A prototype system of the Langmuir probes for SPIDER (Source for the production of Ions of Deuterium Extracted from RF plasma) was manufactured and experimentally qualified. The diagnostic was operated in RF (Radio Frequency) plasmas with cesium evaporation on the BATMAN (BAvarian Test MAchine for Negative ions) test facility, which can provide plasma conditions as expected in the SPIDER source. A RF passive compensation circuit was realised to operate the Langmuir probes in RF plasmas. The sensors’ holder, designed to better simulate the bias plate conditions in SPIDER, was exposed to a severe experimental campaign in BATMAN with cesium evaporation. No detrimental effect on the diagnostic due to cesium evaporation was found during the exposure to the BATMAN plasma and in particular the insulation of the electrodes was preserved. The paper presents the system prototype, the RF compensation circuit, the acquisition system (as foreseen in SPIDER), and the results obtained during the experimental campaigns

  5. Studies on morphology of Langmuir-Blodgett films of stearic acid deposited with different orientation of substrates with respect to compression

    Energy Technology Data Exchange (ETDEWEB)

    Choudhary, Keerti; Manjuladevi, V.; Gupta, R. K., E-mail: raj@pilani.bits-pilani.ac.in [Department of physics, Birla Institute of Technology & Science, Pilani-333031, Rajasthan (India)

    2016-05-06

    The Langmuir monolayer at an air-water interface shows remarkably different surface pressure – area isotherm, when measured with the surface normal of a Wilhemly plate parallel or perpendicular to the direction of compression of the monolayer. Such difference arises due to difference in stress exerted by the monolayer on the plate in different direction. In this article, we report the effect of changing the direction of substrate normal with respect to the compression of the monolayer during Langmuir-Blodgett (LB) film deposition on the morphology of the films. The morphology of the LB film of stearic acid was studied using an atomic force microscope (AFM). The morphology of the LB films was found to be different due to difference in the stress in different directions.

  6. Transport properties of field-effect transistor with Langmuir-Blodgett films of C60 dendrimer and estimation of impurity levels

    Science.gov (United States)

    Kawasaki, Naoko; Nagano, Takayuki; Kubozono, Yoshihiro; Sako, Yuuki; Morimoto, Yu; Takaguchi, Yutaka; Fujiwara, Akihiko; Chu, Chih-Chien; Imae, Toyoko

    2007-12-01

    Field-effect transistor (FET) device has been fabricated with Langmuir-Blodgett films of C60 dendrimer. The device showed n-channel normally off characteristics with the field-effect mobility of 2.7×10-3cm2V-1s-1 at 300K, whose value is twice as high as that (1.4×10-3cm2V-1s-1) for the FET with spin-coated films of C60 dendrimer. This originates from the formation of ordered π-conduction network of C60 moieties. From the temperature dependence of field-effect mobility, a structural phase transition has been observed at around 300K. Furthermore, the density of states for impurity levels was estimated in the Langmuir-Blodgett films.

  7. Characterisation of the membrane affinity of an isoniazide peptide conjugate by tensiometry, atomic force microscopy and sum-frequency vibrational spectroscopy, using a phospholipid Langmuir monolayer model.

    Science.gov (United States)

    Hill, Katalin; Pénzes, Csanád Botond; Schnöller, Donát; Horváti, Kata; Bosze, Szilvia; Hudecz, Ferenc; Keszthelyi, Tamás; Kiss, Eva

    2010-10-07

    Tensiometry, sum-frequency vibrational spectroscopy, and atomic force microscopy were employed to assess the cell penetration ability of a peptide conjugate of the antituberculotic agent isoniazide. Isoniazide was conjugated to peptide (91)SEFAYGSFVRTVSLPV(106), a functional T-cell epitope of the immunodominant 16 kDa protein of Mycobacterium tuberculosis. As a simple but versatile model of the cell membrane a phospholipid Langmuir monolayer at the liquid/air interface was used. Changes induced in the structure of the phospholipid monolayer by injection of the peptide conjugate into the subphase were followed by tensiometry and sum-frequency vibrational spectroscopy. The drug penetrated lipid films were transferred to a solid support by the Langmuir-Blodgett technique, and their structures were characterized by atomic force microscopy. Peptide conjugation was found to strongly enhance the cell penetration ability of isoniazide.

  8. Isotermas de langmuir e de freundlich na descrição da adsorção de boro em solos altamente intemperizados

    Directory of Open Access Journals (Sweden)

    ALLEONI L.R.F.

    1998-01-01

    Full Text Available O objetivo deste trabalho foi estudar a adequação dos modelos de Langmuir e de Freundlich para descrever a adsorção do boro em amostras superficiais (0-0,2 m e subsuperficiais (na maior expressão do horizonte B de três solos altamente intemperizados: latossolo roxo distrófico textura muito argilosa (LR, podzólico vermelho-amarelo eutrófico textura arenosa/média (PV e latossolo vermelho-escuro álico textura média (LE. Para a determinação da quantidade de boro adsorvido, 20 mL de soluções de CaCl2 0,01 mol.L-1 com diferentes quantidades de boro (0; 1; 2; 4; 8 e 16 mg.mL-1 foram adicionados a 4 g de terra fina seca em estufa e agitados por 24 h. Tanto o modelo de Langmuir como o de Freundlich adequaram-se bem aos valores de boro adsorvido pelos solos, em toda faixa estudada. As adsorções máximas de maior valor estimadas pelo modelo de Langmuir foram encontradas para as amostras do LR (em torno de 14 mg.g-1, seguidas daquela do horizonte B do PV (7 mg.g-1. Valores menores foram encontrados nas amostras do LE e no horizonte superficial do PV, com menos de 6 mg.g-1 de boro adsorvido. O somatório dos desvios no PV e no LE foram maiores para o modelo de Freundlich, enquanto que, no LR, o somatório foi maior para os valores estimados pelo modelo de Langmuir.

  9. Incorporation in Langmuir-Blodgett films of an amphiphilic derivative of fullerene C{sub 60} and oligo-para-phenylenevinylene

    Energy Technology Data Exchange (ETDEWEB)

    Alvarez-Venicio, V. [Instituto de Ciencias Nucleares, Universidad Nacional Autonoma de Mexico (UNAM), Circuito Exterior, CU, C.P. 04510, D.F. (Mexico); Gutierrez-Nava, M. [CIATEQ, A.C., Centro de Tecnologia Avanzada, Circuito de la Industria Poniente Lote: 11, Mza. 3, No. 11, Colonia Parque Industrial Ex Hacienda Dona Rosa, Lerma C.P. 52004, Estado de Mexico (Mexico); Amelines-Sarria, O. [Instituto de Ciencias Nucleares, Universidad Nacional Autonoma de Mexico (UNAM), Circuito Exterior, CU, C.P. 04510, D.F. (Mexico); Alvarez-Zauco, E. [Facultad de Ciencias, UNAM, Circuito Exterior, C.U., C.P. 04510, D.F. (Mexico); Basiuk, V.A. [Instituto de Ciencias Nucleares, Universidad Nacional Autonoma de Mexico (UNAM), Circuito Exterior, CU, C.P. 04510, D.F. (Mexico); Carreon-Castro, M.P., E-mail: pilar@nucleares.unam.mx [Instituto de Ciencias Nucleares, Universidad Nacional Autonoma de Mexico (UNAM), Circuito Exterior, CU, C.P. 04510, D.F. (Mexico)

    2012-12-30

    Langmuir (L) and Langmuir-Blodgett (LB) films of fullerene C{sub 60}-oligo-para-phenylenevinylene (OPV) derivative with six C{sub 12}H{sub 25} aliphatic chains were characterized. For the Langmuir films, isotherms of surface pressure versus molecular area, compression/expansion cycles (hysteresis curves) and Brewster angle microscopic images were obtained. We performed molecular mechanics and density functional theory calculations to determine the molecular and electronic structure of our compound at a water-air interface. We found agreement between experimental and theoretical values for the molecular surface area. LB films of up to ten layers were obtained on glass substrates, and were characterized by ultraviolet-visible spectroscopy. We observed that the absorbance at a wavelength of 326 nm grows almost linearly as a function of the number of layers. Films on glass-indium tin oxide were characterized by atomic force microscopy. We also observed a uniform deposition over the whole area of the scanned substrate. We demonstrated that the fullerene C{sub 60}-OPV derivative is able to form both L and LB films preventing fullerene aggregation with its aliphatic chains. We suggest that, due to its electron-acceptor properties, the C{sub 60}-OPV derivative could be used for organic-photovoltaic and organic-electronic applications. - Highlights: Black-Right-Pointing-Pointer We performed isotherm and hysteresis studies of fullerene derivative compound. Black-Right-Pointing-Pointer We found that the theoretical and experimental molecular areas agree. Black-Right-Pointing-Pointer We deposited Langmuir-Blodgett (LB) films on glass-indium tin oxide. Black-Right-Pointing-Pointer LB films were characterized using UV-visible spectroscopy. Black-Right-Pointing-Pointer We observed the morphology of the LB films through atomic force microscopy.

  10. Real time freeway incident detection.

    Science.gov (United States)

    2014-04-01

    The US Department of Transportation (US-DOT) estimates that over half of all congestion : events are caused by highway incidents rather than by rush-hour traffic in big cities. Real-time : incident detection on freeways is an important part of any mo...

  11. True incidence of vestibular schwannoma?

    DEFF Research Database (Denmark)

    Stangerup, Sven-Eric; Tos, Mirko; Thomsen, Jens

    2010-01-01

    The incidence of diagnosed sporadic unilateral vestibular schwannomas (VS) has increased, due primarily to more widespread access to magnetic resonance imaging.......The incidence of diagnosed sporadic unilateral vestibular schwannomas (VS) has increased, due primarily to more widespread access to magnetic resonance imaging....

  12. Comparison of Langmuir probe and multipole resonance probe measurements in argon, hydrogen, nitrogen, and oxygen mixtures in a double ICP discharge

    Science.gov (United States)

    Fiebrandt, Marcel; Oberberg, Moritz; Awakowicz, Peter

    2017-07-01

    The results of a Multipole Resonance Probe (MRP) are compared to a Langmuir probe in measuring the electron density in Ar, H2, N2, and O2 mixtures. The MRP was designed for measurements in industry processes, i.e., coating or etching. To evaluate a possible influence on the MRP measurement due to molecular gases, different plasmas with increasing molecular gas content in a double inductively coupled plasma at 5 Pa and 10 Pa at 500 W are used. The determined electron densities from the MRP and the Langmuir probe slightly differ in H2 and N2 diluted argon plasmas, but diverge significantly with oxygen. In pure molecular gas plasmas, electron densities measured with the MRP are always higher than those measured with the Langmuir Probe, in particular, in oxygen containing mixtures. The differences can be attributed to etching of the tungsten wire in the Ar:O2 mixtures and rf distortion in the pure molecular discharges. The influence of a non-Maxwellian electron energy distribution function, negative ions or secondary electron emission seems to be of no or only minor importance.

  13. Langmuir probe measurements and mass spectrometry of plasma plumes generated by laser ablation of La0.4Ca0.6MnO3

    Science.gov (United States)

    Chen, Jikun; Lunney, James G.; Lippert, Thomas; Ojeda-G-P, Alejandro; Stender, Dieter; Schneider, Christof W.; Wokaun, Alexander

    2014-08-01

    The plasma formed in vacuum by UV nanosecond laser ablation of La0.4Ca0.6MnO3 in the fluence range of 0.8 to 1.9 J cm-2 using both Langmuir probe analysis and energy-resolved mass spectrometry has been studied. Mass spectrometry shows that the main positive ion species are Ca+, Mn+, La+, and LaO+. The Ca+ and Mn+ energy distributions are quite broad and lie in the 0-100 eV region, with the average energies increasing with laser fluence. In contrast, the La+ and LaO+ distributions are strongly peaked around 10 eV. The net time-of-arrival signal derived from the measured positive ion energy distributions is broadly consistent with the positive ion signal measured by the Langmuir probe. We also detected a significant number of O- ions with energies in the range of 0 to 10 eV. The Langmuir probe was also used to measure the temporal variation of the electron density and temperature at 6 cm from the ablation target. In the period when O- ions are found at this position, the plasma conditions are consistent with those required for significant negative oxygen ion formation, as revealed by studies on radio frequency excited oxygen plasma.

  14. Role of collective effects in dominance of scattering off thermal ions over Langmuir wave decay: Analysis, simulations, and space applications

    International Nuclear Information System (INIS)

    Cairns, Iver H.

    2000-01-01

    Langmuir waves driven to high levels by beam instabilities are subject to nonlinear processes, including the closely related processes of scattering off thermal ions (STI) and a decay process in which the ion response is organized into a product ion acoustic wave. Calculations of the nonlinear growth rates predict that the decay process should always dominate STI, creating two paradoxes. The first is that three independent computer simulation studies show STI proceeding, with no evidence for the decay at all. The second is that observations in space of type III solar radio bursts and Earth's foreshock, which the simulations were intended to model, show evidence for the decay proceeding but no evidence for STI. Resolutions to these paradoxes follow from the realization that a nonlinear process cannot proceed when its growth rate exceeds the minimum frequency of the participating waves, since the required collective response cannot be maintained and the waves cannot respond appropriately, and that a significant number of e-foldings and wave periods must be contained in the time available. It is shown that application of these ''collective'' and ''time scale'' constraints to the simulations explains why the decay does not proceed in them, as well as why STI proceeds in specific simulations. This appears to be the first demonstration that collective constraints are important in understanding nonlinear phenomena. Furthermore, applying these constraints to space observations, it is predicted that the decay should proceed (and dominate STI) in type III sources and the high beam speed regions of Earth's foreshock for a specific range of wave levels, with a possible role for STI alone at slightly higher wave levels. Deeper in the foreshock, for slower beams and weaker wave levels, the decay and STI are predicted to become ineffective. Suggestions are given for future testing of the collective constraint and an explanation for why waves in space are usually much weaker than

  15. A raft-associated species of phosphatidylethanolamine interacts with cholesterol comparably to sphingomyelin. A Langmuir-Blodgett monolayer study.

    Directory of Open Access Journals (Sweden)

    Michal Grzybek

    Full Text Available BACKGROUND: Specific interactions between sphingomyelin (SM and cholesterol (Ch are commonly believed to play a key role in the formation of rafts in the biological membranes. A weakness of this model is the implication that these microdomains are confined to the outer bilayer leaflet. The cytoplasmic leaflet, which contains the bulk of phosphatidylethanolamine (PE, phosphatidylserine (PS and phosphatidylinositol (PI, is thought also to harbour half of the membrane cholesterol. Moreover, SLPE (1-stearoyl-2-linoleoyl-sn-glycero-3-phosphatidyl-ethanolamine has recently been shown to be enriched in isolated detergent-resistant membranes (DRM, and this enrichment was independent of the method of isolation of DRM. METHODOLOGY/PRINCIPAL FINDINGS: Here we present quantitative evidence coming from Langmuir-Blodgett monolayer experiments that SLPE forms complex with Ch similar to that between SM and Ch. The energies of these interactions as calculated form the monolayer studies are highly negative. FRAP analysis showed that NBD-Ch recovery was similar in liposomes composed of DOPC/Ch SM or SLPE but not DPPE, providing further evidence that SLPE may form an l(o phase in the presence of high Ch concentration. Experiments on the solubility of DOPC liposomes containing DPPE/Ch (1ratio1, SM/Ch (1ratio1 or SLPE/Ch (1ratio1 showed the presence of Triton X-100 insoluble floating fraction (TIFF in the case of SM/Ch or SLPE/Ch but not in DPPE/Ch containing liposomes. Quantitative determination of particular lipid species in the TIFF fraction confirms the conclusion that SLPE (or similar PE species could be an important constituent of the inner leaflet raft. CONCLUSION: Such interactions suggest a possible existence of inner-leaflet nanoscale assemblies composed of cholesterol complexes with SLPE or similar unsaturated PE species.

  16. Control of indium tin oxide anode work function modified using Langmuir-Blodgett monolayer for high-efficiency organic photovoltaics

    Directory of Open Access Journals (Sweden)

    Yuya Yokokura

    2017-08-01

    Full Text Available The use of Langmuir-Blodgett (LB monolayers to modify the indium tin oxide (ITO work function and thus improve the performance of zinc phthalocyanine (ZnPc/fullerene (C60-based and boron subphthalocyanine chloride (SubPc/C60-based small molecule organic photovoltaic devices (OPVs was examined. In general, LB precursor compounds contain one or more long alkyl chain substituents that can act as spacers to prevent electrical contact with adjoining electrode surfaces. As one example of such a compound, arachidic acid (CH3(CH218COOH was inserted in the forms of one-layer, three-layer or five-layer LB films between the anode ITO layer and the p-type layer in ZnPc-C60-based OPVs to investigate the effects of the long alkyl chain group when it acts as an electrically insulating spacer. The short-circuit current density (Jsc values of the OPVs with the three- and five-layer inserts (1.78 mA·cm−2 and 0.61 mA·cm−2, respectively were reduced dramatically, whereas the Jsc value for the OPV with the single-layer insertion (2.88 mA·cm−2 was comparable to that of the OPV without any insert (3.14 mA·cm-2. The ITO work function was shifted positively by LB deposition of a surfactant compound, C9F19C2H4-O-C2H4-COOH (PFECA, which contained a fluorinated head group. This positive effect was maintained even after formation of an upper p-type organic layer. The Jsc and open-circuit voltage (Voc of the SubPc-C60-based OPV with the LB-modified ITO layers were effectively enhanced. As a result, a 42% increase in device efficiency was achieved.

  17. Atomic force microscopy and Langmuir-Blodgett monolayer technique to assess contact lens deposits and human meibum extracts.

    Science.gov (United States)

    Hagedorn, Sarah; Drolle, Elizabeth; Lorentz, Holly; Srinivasan, Sruthi; Leonenko, Zoya; Jones, Lyndon

    2015-01-01

    The purpose of this exploratory study was to investigate the differences in meibomian gland secretions, contact lens (CL) lipid extracts, and CL surface topography between participants with and without meibomian gland dysfunction (MGD). Meibum study: Meibum was collected from all participants and studied via Langmuir-Blodgett (LB) deposition with subsequent Atomic Force Microscopy (AFM) visualization and surface roughness analysis. CL Study: Participants with and without MGD wore both etafilcon A and balafilcon A CLs in two different phases. CL lipid deposits were extracted and analyzed using pressure-area isotherms with the LB trough and CL surface topographies and roughness values were visualized using AFM. Meibum study: Non-MGD participant meibum samples showed larger, circular aggregates with lower surface roughness, whereas meibum samples from participants with MGD showed more lipid aggregates, greater size variability and higher surface roughness. CL Study: Worn CLs from participants with MGD had a few large tear film deposits with lower surface roughness, whereas non-MGD participant-worn lenses had many small lens deposits with higher surface roughness. Balafilcon A pore depths were shallower in MGD participant worn lenses when compared to non-MGD participant lenses. Isotherms of CL lipid extracts from MGD and non-MGD participants showed a seamless rise in surface pressure as area decreased; however, extracts from the two different lens materials produced different isotherms. MGD and non-MGD participant-worn CL deposition were found to differ in type, amount, and pattern of lens deposits. Lipids from MGD participants deposited irregularly whereas lipids from non-MGD participants showed more uniformity. Copyright © 2014 Spanish General Council of Optometry. Published by Elsevier Espana. All rights reserved.

  18. Humidity-dependent compression-induced glass transition of the air-water interfacial Langmuir films of poly(D,L-lactic acid-ran-glycolic acid) (PLGA).

    Science.gov (United States)

    Kim, Hyun Chang; Lee, Hoyoung; Jung, Hyunjung; Choi, Yun Hwa; Meron, Mati; Lin, Binhua; Bang, Joona; Won, You-Yeon

    2015-07-28

    Constant rate compression isotherms of the air-water interfacial Langmuir films of poly(D,L-lactic acid-ran-glycolic acid) (PLGA) show a distinct feature of an exponential increase in surface pressure in the high surface polymer concentration regime. We have previously demonstrated that this abrupt increase in surface pressure is linked to the glass transition of the polymer film, but the detailed mechanism of this process is not fully understood. In order to obtain a molecular-level understanding of this behavior, we performed extensive characterizations of the surface mechanical, structural and rheological properties of Langmuir PLGA films at the air-water interface, using combined experimental techniques including the Langmuir film balance, X-ray reflectivity and double-wall-ring interfacial rheometry methods. We observed that the mechanical and structural responses of the Langmuir PLGA films are significantly dependent on the rate of film compression; the glass transition was induced in the PLGA film only at fast compression rates. Surprisingly, we found that this deformation rate dependence is also dependent on the humidity of the environment. With water acting as a plasticizer for the PLGA material, the diffusion of water molecules through the PLGA film seems to be the key factor in the determination of the glass transformation properties and thus the mechanical response of the PLGA film against lateral compression. Based on our combined results, we hypothesize the following mechanism for the compression-induced glass transformation of the Langmuir PLGA film; (1) initially, a humidified/non-glassy PLGA film is formed in the full surface-coverage region (where the surface pressure shows a plateau) during compression; (2) further compression leads to the collapse of the PLGA chains and the formation of new surfaces on the air side of the film, and this newly formed top layer of the PLGA film is transiently glassy in character because the water evaporation rate

  19. Traffic incident management resource management.

    Science.gov (United States)

    2009-01-01

    The necessity of a multi-disciplinary approach involving law enforcement, fire and rescue, transportation, towing and recovery, and others has been well-recognized and integrated into incident management operations. This same multidisciplinar...

  20. Police Incident Blotter (30 Day)

    Data.gov (United States)

    Allegheny County / City of Pittsburgh / Western PA Regional Data Center — The 30 Day Police Blotter contains the most recent initial crime incident data, updated on a nightly basis. All data is reported at the block/intersection level,...

  1. Incidents Associated with Gas Operation

    Directory of Open Access Journals (Sweden)

    Szer J.

    2017-06-01

    Full Text Available This article shows incidents associated with the use of gas as an energy carrier. It presents selected incidents which have occurred in Poland and around the world in recent decades. Based on this, consequences of gas and air mixture explosions were analysed as well. The article presents the main causes of gas incidents which have taken place, as per instances which are similar worldwide. Incidents associated with the use of gas are not frequent, but at the same time very tragic as they often lead to illness or even death. In Poland, in the last twenty years, construction area disasters caused by gas explosions account for only 5% of all which have occurred, but the number of fatalities resulting from these cases is approximately 14%. The number of individuals injured reached 39% of all construction disaster victims. Considering all these facts, it is necessary to undertake wide preventive measures in order to increase safety in the use of gaseous fuels.

  2. Regional comparison of cancer incidence

    International Nuclear Information System (INIS)

    Obralic, N.; Gavrankapetanovic, F.; Dizdarevic, Z.; Duric, O.; Sisic, F.; Selak, I.; Balta, S.; Nakas, B.

    2004-01-01

    Background. Due to specific war and post-war situation in Balkan region, differences in the number, type, development, biological course, treatment of malignant tumours and its outcome are possible. In order to perceive the situation realistically, it is necessary to gather continuously exact data about malignant tumours and compare them with the data from other European and world countries.The aim of the study was to collect and analyse the data on cancer incidence in the region of Sarajevo city, which represents a symbol of difficult times in the recent past, and to compare it to the incidence in the neighbouring countries. Patients and methods. Data on all newly diagnosed cancer cases, permanent residents of Sarajevo Canton, in the years 1999 and 2000 were collected. Crude incidence rate has been calculated according to the years observed, gender and localizations of the disease The data were compared to the cancer registries of Slovenia and Croatia and were observed in the light of specific local situation. Results. The crude cancer incidence of all sites but skin was the highest in both years and by both genders in Croatia. The incidence of the most common tumours (lung and breast cancer) was similar in all three countries. The differences in the incidence between both genders in the Sarajevo canton were registered in laryngeal and urinary bladder cancer, as well as in bone and cartilage sarcoma. Cervical cancer had extremely high incidence and was high up on the incidence list in the Sarajevo canton, which correlates with the data in developing countries. The incidence of other tumours in the post-war period is reaching expected numbers. Conclusions. It is difficult to identify whether the war and post-war stress, irregular and insufficient nutrition during and after the siege of the city of Sarajevo or some other factor influenced the cancer incidence among exposed population. The prevalence of smoking in the whole region is extremely high, in Bosnia and

  3. Functional analysis of controbloc incidents

    International Nuclear Information System (INIS)

    Gouffon, A.; Jorel, M.

    1992-11-01

    The subject of the present paper is the survey jointly carried out in 1989 by the IPSN Safety Analysis Department and the Firm BERTIN and Co. on significant incidents related to the Controbloc system equipping the EDF 1300 MWe PWR power plants in France. This survey consisted in a general review of Controbloc operating problems, together with analysis of the safety consequences of the incidents discussed. The survey enabled improvements to be recommended in this respect and provided a basis for safety analysis

  4. Cancer incidence in Spain, 2015.

    Science.gov (United States)

    Galceran, J; Ameijide, A; Carulla, M; Mateos, A; Quirós, J R; Rojas, D; Alemán, A; Torrella, A; Chico, M; Vicente, M; Díaz, J M; Larrañaga, N; Marcos-Gragera, R; Sánchez, M J; Perucha, J; Franch, P; Navarro, C; Ardanaz, E; Bigorra, J; Rodrigo, P; Bonet, R Peris

    2017-07-01

    Periodic cancer incidence estimates of Spain from all existing population-based cancer registries at any given time are required. The objective of this study was to present the current situation of cancer incidence in Spain. The Spanish Network of Cancer Registries (REDECAN) estimated the numbers of new cancer cases occurred in Spain in 2015 by applying the incidence-mortality ratios method. In the calculus, incidence data from population-based cancer registries and mortality data of all Spain were used. In 2015, nearly a quarter of a million new invasive cancer cases were diagnosed in Spain, almost 149,000 in men (60.0%) and 99,000 in women. Globally, the five most common cancers were those of colon-rectum, prostate, lung, breast and urinary bladder. By gender, the four most common cancers in men were those of prostate (22.4%), colon-rectum (16.6%), lung (15.1%) and urinary bladder (11.7%). In women, the most common ones were those of breast (28.0%), colon-rectum (16.9%), corpus uteri (6.2%) and lung (6.0%). In recent years, cancer incidence in men seems to have stabilized due to the fact that the decrease in tobacco-related cancers compensates for the increase in other types of cancer like those of colon and prostate. In women, despite the stabilization of breast cancer incidence, increased incidence is due, above all, to the rise of colorectal and tobacco-related cancers. To reduce these incident cancer cases, improvement of smoking control policies and extension of colorectal cancer screening should be the two priorities in cancer prevention for the next years.

  5. Cyber Incidents Involving Control Systems

    Energy Technology Data Exchange (ETDEWEB)

    Robert J. Turk

    2005-10-01

    The Analysis Function of the US-CERT Control Systems Security Center (CSSC) at the Idaho National Laboratory (INL) has prepared this report to document cyber security incidents for use by the CSSC. The description and analysis of incidents reported herein support three CSSC tasks: establishing a business case; increasing security awareness and private and corporate participation related to enhanced cyber security of control systems; and providing informational material to support model development and prioritize activities for CSSC. The stated mission of CSSC is to reduce vulnerability of critical infrastructure to cyber attack on control systems. As stated in the Incident Management Tool Requirements (August 2005) ''Vulnerability reduction is promoted by risk analysis that tracks actual risk, emphasizes high risk, determines risk reduction as a function of countermeasures, tracks increase of risk due to external influence, and measures success of the vulnerability reduction program''. Process control and Supervisory Control and Data Acquisition (SCADA) systems, with their reliance on proprietary networks and hardware, have long been considered immune to the network attacks that have wreaked so much havoc on corporate information systems. New research indicates this confidence is misplaced--the move to open standards such as Ethernet, Transmission Control Protocol/Internet Protocol, and Web technologies is allowing hackers to take advantage of the control industry's unawareness. Much of the available information about cyber incidents represents a characterization as opposed to an analysis of events. The lack of good analyses reflects an overall weakness in reporting requirements as well as the fact that to date there have been very few serious cyber attacks on control systems. Most companies prefer not to share cyber attack incident data because of potential financial repercussions. Uniform reporting requirements will do much to make this

  6. Role of collective effects in dominance of scattering off thermal ions over Langmuir wave decay: Analysis, simulations, and space applications

    Energy Technology Data Exchange (ETDEWEB)

    Cairns, Iver H.

    2000-12-01

    Langmuir waves driven to high levels by beam instabilities are subject to nonlinear processes, including the closely related processes of scattering off thermal ions (STI) and a decay process in which the ion response is organized into a product ion acoustic wave. Calculations of the nonlinear growth rates predict that the decay process should always dominate STI, creating two paradoxes. The first is that three independent computer simulation studies show STI proceeding, with no evidence for the decay at all. The second is that observations in space of type III solar radio bursts and Earth's foreshock, which the simulations were intended to model, show evidence for the decay proceeding but no evidence for STI. Resolutions to these paradoxes follow from the realization that a nonlinear process cannot proceed when its growth rate exceeds the minimum frequency of the participating waves, since the required collective response cannot be maintained and the waves cannot respond appropriately, and that a significant number of e-foldings and wave periods must be contained in the time available. It is shown that application of these ''collective'' and ''time scale'' constraints to the simulations explains why the decay does not proceed in them, as well as why STI proceeds in specific simulations. This appears to be the first demonstration that collective constraints are important in understanding nonlinear phenomena. Furthermore, applying these constraints to space observations, it is predicted that the decay should proceed (and dominate STI) in type III sources and the high beam speed regions of Earth's foreshock for a specific range of wave levels, with a possible role for STI alone at slightly higher wave levels. Deeper in the foreshock, for slower beams and weaker wave levels, the decay and STI are predicted to become ineffective. Suggestions are given for future testing of the collective constraint and an explanation

  7. Incorporation of amphiphilic ruthenium(II) ammine complexes into Langmuir-Blodgett thin films with switchable quadratic nonlinear optical behavior.

    Science.gov (United States)

    Boubekeur-Lecaque, Leïla; Coe, Benjamin J; Harris, James A; Helliwell, Madeleine; Asselberghs, Inge; Clays, Koen; Foerier, Stijn; Verbiest, Thierry

    2011-12-19

    Nine nonlinear optical (NLO) chromophores with pyridinium electron acceptors have been synthesized by complexing new proligands with {Ru(II)(NH(3))(5)}(2+) electron-donor centers. The presence of long alkyl/fluoroalkyl chain substituents imparts amphiphilic properties, and these cationic complexes have been characterized as their PF(6)(-) salts by using various techniques including electronic absorption spectroscopy and cyclic voltammetry. Each complex shows three reversible/quasireversible redox processes; a Ru(III/II) oxidation and two ligand-based reductions. The energies of the intense visible d → π* metal-to-ligand charge-transfer (MLCT) absorptions correlate to some extent with the ligand reduction potentials. (1)H NMR spectroscopy also provides insights into the relative electron-withdrawing strengths of the new ligands. Single crystal X-ray structures have been determined for two of the proligand salts and one complex salt, [Ru(II)(NH(3))(5)(4-C(16)H(33)PhQ(+))]Cl(3)·3.25H(2)O (PhQ(+) = N-phenyl-4,4'-bipyridinium), showing centrosymmetric packing structures in each case. The PF(6)(-) analogue of the latter complex has been used to deposit reproducibly high-quality, multilayered Langmuir-Blodgett (LB) thin films. These films show a strong second harmonic generation (SHG) response from a 1064 nm laser; their MLCT absorbance increases linearly with the number of layers (N) and I(2ω)/I(ω)(2) (I(2ω) = intensity at 532 nm; I(ω) = intensity at 1064 nm) scales quadratically with N, consistent with homogeneous deposition. LB films on indium tin oxide (ITO)-coated glass show electrochemically induced switching of the SHG response, with a decrease in activity of about 50% on Ru(II) → Ru(III) oxidation. This effect is reversible, but reproducible over only a few cycles before the signal from the Ru(II) species diminishes. This work extrapolates our original solution studies (Coe, B. J. et al. Angew. Chem., Int. Ed.1999, 38, 366) to the first demonstration of

  8. Incidence of hyperthyroidism in Sweden.

    Science.gov (United States)

    Abraham-Nordling, Mirna; Byström, Kristina; Törring, Ove; Lantz, Mikael; Berg, Gertrud; Calissendorff, Jan; Nyström, Helena Filipsson; Jansson, Svante; Jörneskog, Gun; Karlsson, F Anders; Nyström, Ernst; Ohrling, Hans; Orn, Thomas; Hallengren, Bengt; Wallin, Göran

    2011-12-01

    The incidence of hyperthyroidism has been reported in various countries to be 23-93/100,000 inhabitants per year. This extended study has evaluated the incidence for ~40% of the Swedish population of 9 million inhabitants. Sweden is considered to be iodine sufficient country. All patients including children, who were newly diagnosed with overt hyperthyroidism in the years 2003-2005, were prospectively registered in a multicenter study. The inclusion criteria are as follows: clinical symptoms and/or signs of hyperthyroidism with plasma TSH concentration below 0.2 mIE/l and increased plasma levels of free/total triiodothyronine and/or free/total thyroxine. Patients with relapse of hyperthyroidism or thyroiditis were not included. The diagnosis of Graves' disease (GD), toxic multinodular goiter (TMNG) and solitary toxic adenoma (STA), smoking, initial treatment, occurrence of thyroid-associated eye symptoms/signs, and demographic data were registered. A total of 2916 patients were diagnosed with de novo hyperthyroidism showing the total incidence of 27.6/100,000 inhabitants per year. The incidence of GD was 21.0/100,000 and toxic nodular goiter (TNG=STA+TMNG) occurred in 692 patients, corresponding to an annual incidence of 6.5/100,000. The incidence was higher in women compared with men (4.2:1). Seventy-five percent of the patients were diagnosed with GD, in whom thyroid-associated eye symptoms/signs occurred during diagnosis in every fifth patient. Geographical differences were observed. The incidence of hyperthyroidism in Sweden is in a lower range compared with international reports. Seventy-five percent of patients with hyperthyroidism had GD and 20% of them had thyroid-associated eye symptoms/signs during diagnosis. The observed geographical differences require further studies.

  9. Information sharing for traffic incident management.

    Science.gov (United States)

    2009-01-01

    Traffic incident management focuses on developing procedures, implementing policies, and deploying technologies to more quickly identify incidents, improve response times, and more effectively and efficiently manage the incident scene. Because so man...

  10. Extensibility effect of poly(3-hexylthiophene) on the glucose sensing performance of mixed poly(3-hexylthiophene)/octadecylamine/glucose oxidase Langmuir-Blodgett films.

    Science.gov (United States)

    Wang, Ke-Hsuan; Hsu, Wen-Ping; Chen, Liang-Huei; Lin, Wei-Don; Lee, Yuh-Lang

    2017-07-01

    Poly(3-hexylthiophene) (P3HT) is utilized as a material to enhance the glucose sensing performance of glucose oxidase (GOx) Langmuir-Blodgett (LB) films. To enhance the extensibility and homogeneity of the P3HT in the LB films, octadecylamine (ODA) is introduced. The characteristics of the mixed P3HT/ODA Langmuir monolayers are investigated first and then, utilized as template layers to adsorb GOx from the subphase, preparing P3HT/ODA/GOx Langmuir-Blodgett films for glucose sensing. The results show that P3HT molecules tend to aggregate at the air/liquid interface and, furthermore, the P3HT monolayer has a weak ability to adsorb GOx from the subphase. By using mixed P3HT/ODA monolayer, the presence of ODA not only inhibits the aggregation of P3HT, but also increases the adsorption ability of the monolayer to GOx. The extensibility of P3HT and the homogeneity of the P3HT/ODA monolayers are closely related to the concentration of P3HT/ODA stock solutions. On the glucose sensing experiments, the performance of the P3HT/ODA/GOx LB film is greatly improved due to the presence of P3HT and, furthermore, the sensibility increases with increasing extensibility of P3HT molecules. The best sensitivity achieved for the P3HT/ODA/GOx film is 5.4μAmM -1 cm -2 which is over two times the value obtained by the ODA/GOx film (2.3μAmM -1 cm -2 ). Copyright © 2017 Elsevier B.V. All rights reserved.

  11. Decreasing incidence rates of bacteremia

    DEFF Research Database (Denmark)

    Nielsen, Stig Lønberg; Pedersen, C; Jensen, T G

    2014-01-01

    BACKGROUND: Numerous studies have shown that the incidence rate of bacteremia has been increasing over time. However, few studies have distinguished between community-acquired, healthcare-associated and nosocomial bacteremia. METHODS: We conducted a population-based study among adults with first......-time bacteremia in Funen County, Denmark, during 2000-2008 (N = 7786). We reported mean and annual incidence rates (per 100,000 person-years), overall and by place of acquisition. Trends were estimated using a Poisson regression model. RESULTS: The overall incidence rate was 215.7, including 99.0 for community......-acquired, 50.0 for healthcare-associated and 66.7 for nosocomial bacteremia. During 2000-2008, the overall incidence rate decreased by 23.3% from 254.1 to 198.8 (3.3% annually, p incidence rate of community-acquired bacteremia decreased by 25.6% from 119.0 to 93.8 (3.7% annually, p

  12. Contribution to the application of the Langmuir probe techique for plasma monitoring in the Ar and n-hexane mixture plasma during the polymerisation process

    Czech Academy of Sciences Publication Activity Database

    Adámek, P.; Kalčík, J.; Šícha, M.; Tichý, M.; Biederman, H.; Soukup, Ladislav; Jastrabík, Lubomír

    1999-01-01

    Roč. 49, č. 12 (1999), s. 1685-1700 ISSN 0011-4626 R&D Projects: GA MŠk(CZ) OC 516.50; GA ČR(CZ) GA202/97/1011; GA ČR(CZ) GA202/98/0116; GA ČR(CZ) GA202/98/0666 Grant - others:GA UK(CZ) 75/98 Institutional research plan: CEZ:AV0Z1010914 Keywords : Langmuir probe * plasma monitoring * average energy of electrons * polymerisation process Subject RIV: BL - Plasma and Gas Discharge Physics Impact factor: 0.328, year: 1999

  13. Experimental estimation of tungsten impurity sputtering due to Type i ELMs in JET-ITER-like wall using pedestal electron cyclotron emission and target Langmuir probe measurements

    Czech Academy of Sciences Publication Activity Database

    Guillemaut, C.; Jardin, A.; Horáček, Jan; Borodkina, I.; Autricque, A.; Arnoux, G.; Boom, J.; Brezinsek, S.; Coenen, J.W.; De La Luna, E.; Devaux, S.; Eich, T.; Harting, D.; Kirschner, A.; Lipschultz, B.; Matthews, G. F.; Meigs, A.; Moulton, D.; O'Mullane, M.; Stamp, M.

    T167, February (2016), s. 014005 ISSN 0031-8949. [International Conference on Plasma-Facing Materials and Components for Fusion Applications, PFMC 2015/15./. Aix-en-Provence, 18.05.2015-22.05.2015] R&D Projects: GA MŠk LG14002 EU Projects: European Commission(XE) 633053 - EUROfusion Institutional support: RVO:61389021 Keywords : tungsten sputtering * edge localized mode * magnetic confinement fusion * ITER * H-mode * ELMs * Langmuir Probes (LP) Subject RIV: BL - Plasma and Gas Discharge Physics OBOR OECD: 1.3 Physical sciences Impact factor: 1.280, year: 2016 http://iopscience.iop.org/issue/1402-4896/2016/T167

  14. Risk - hazardous incident - communication 2

    International Nuclear Information System (INIS)

    Gerling, R.; Obermeier, O.P.

    1995-01-01

    It is difficult to develop an objective approach to risks and effects of a hazardous incident that would be acceptable to the community at large. It is a matter of fact that there is great dissimilarity in the way various social groups perceive and define the risks of a particular technology, or the effects of hazardous incidents, sometimes they have even contrary opinions. Hence, open communication is seriously hampered, which in turn aggravates the problems encountered in this context. This second volume of the publication dealing with the problem area of 'risk - hazardous incident - communication' is intended to reveal patterns of the recurrent process which impedes communication, and to bridge the gaps between the various 'styles' of risk perception and definition. (orig./CB) [de

  15. Risk - hazardous incident - communication 1

    International Nuclear Information System (INIS)

    Gerling, R.; Obermeier, O.P.

    1994-01-01

    Terms such as 'risk', 'hazardous incident', and 'communication' have become major catchwords in discussions about present-day problems, and may be reduced to a common denominator: disaster. Such an association, however, is inappropriate, as the concept indicated by the term 'risk' for instance covers a wide scale of possible danger. Even the term 'hazardous incident' describes events or conditions that are very different in terms of possible danger, let alone disastrous effects. The discrepancy to be observed between the facts and the public perception usually is due to the fact that people have little insight into the complex of problems involved, and to insufficient communication between the world of experts and the general public. The contributions to this publication present information and discuss a variety of solution sets to improve the communication problems in the context of the problem area of 'risk - hazardous incident - communication'. (orig./CB) [de

  16. Cardiovascular disease incidence and survival

    DEFF Research Database (Denmark)

    Byberg, Stine; Agyemang, Charles; Zwisler, Ann Dorthe

    2016-01-01

    Studies on cardiovascular disease (CVD) incidence and survival show varying results between different ethnic groups. Our aim was to add a new dimension by exploring the role of migrant status in combination with ethnic background on incidence of-and survival from-CVD and more specifically acute...... of some types of cardiovascular disease compared to Danish-born. Family-reunified migrants on the other hand had lower rates of CVD. All migrants had better survival than Danish-born indicating that migrants may not always be disadvantaged in health....

  17. Cancer incidence among merchant seafarers

    DEFF Research Database (Denmark)

    Ugelvig Petersen, Kajsa; Volk, Julie; Kaerlev, Linda

    2018-01-01

    on the incidence of specific cancers among both male and female seafarers. Methods: Using records from the Danish Seafarer Registry, all seafarers employed on Danish ships during 1986-1999 were identified, resulting in a cohort of 33 084 men and 11 209 women. Information on vital status and cancer was linked...... to each member of the cohort from the Danish Civil Registration System and the Danish Cancer Registry using the unique Danish personal identification number. SIRs were estimated for specific cancers using national rates. Results: The overall incidence of cancer was increased for both male and female...

  18. Incidence of sialolithiasis in Denmark

    DEFF Research Database (Denmark)

    Schrøder, Stine Attrup; Andersson, Mikael; Wohlfahrt, Jan

    2017-01-01

    Sialolithiasis is a frequent disorder affecting the salivary glands. The incidence rate (IR) has been reported to be 2.9-5.5 per 100,000 person-years, but all previous studies have been based on selected hospital data. In this study, we conducted a population-based study evaluating the IR...

  19. Divertor ‘death-ray’ explained: An artifact of a Langmuir probe operating at negative bias in a high-recycling divertor

    International Nuclear Information System (INIS)

    Brunner, D.; Umansky, M.V.; LaBombard, B.; Rognlien, T.D.

    2013-01-01

    The divertor ‘death-ray’, enhanced plasma pressure near the outer strike-point relative to ‘upstream’ values, was thought to correspond to axisymmetric increased divertor heat flux. Recent measurements on Alcator C-Mod show that the ‘death-ray’ is localized to biased Langmuir probes. Heat fluxes deduced from plasma-sheath theory and surface thermocouples agree in sheath-limited and moderate-recycling regimes. They diverge in high-recycling and detached regimes; surface thermocouples measure reduced heat flux while a ‘death-ray’ appears on Langmuir probes. The ‘death-ray’ is caused by the probe’s negative bias affecting the local flux tube. With the bias, electron heat flux to the probe surface is reduced. Thus, the local electron temperature is raised, enhancing neutral ionization and increasing the ion flux to the probe. The plasma fluid code UEDGE is used to simulate and reproduce many of the features of this integrated biased probe/divertor system

  20. Laser-produced Sm{sub 1-x}Nd{sub x}NiO{sub 3} plasma dynamic through Langmuir probe and ICCD imaging combined analysis

    Energy Technology Data Exchange (ETDEWEB)

    Ngom, B.D. [Universite Cheikh Anta Diop de Dakar (UCAD), Laboratoire de Photonique et Nano-Fabrication, Groupe de Physique du Solide et Sciences des Materiaux (GPSSM), Faculte des Sciences et Techniques, Dakar-Fann Dakar (Senegal); University of South Africa, UNESCO-UNISA Africa Chair in Nanosciences/Nanotechnology, College of Graduate Studies, Pretoria (South Africa); National Research Foundation, Nanosciences African Network (NANOAFNET), iThemba LABS, Somerset West, Western Cape (South Africa); Lafane, S.; Abdelli-Messaci, S.; Kerdja, T. [Centre de Developpement des Technologies Avancees, Division des Milieux Ionises et Laser, Baba Hassen (Algeria); Maaza, M. [University of South Africa, UNESCO-UNISA Africa Chair in Nanosciences/Nanotechnology, College of Graduate Studies, Pretoria (South Africa); National Research Foundation, Nanosciences African Network (NANOAFNET), iThemba LABS, Somerset West, Western Cape (South Africa)

    2016-01-15

    The dynamics of laser-produced plasma of Sm{sub 1-x}Nd{sub x}NiO{sub 3} is studied over oxygen pressure ranging from vacuum up to 2 mbar via Langmuir probe, and intensified charge-coupled device-imaging techniques. The analysis of the oxygen pressure dependence of the ion yield points out to four different regimes. More accurately, the specific ionic current shows a first drop at about 2 x 10{sup -2} mbar corresponding to the appearance of two peaks in the profile of the ionic signal. Likewise, this pressure marks the early stage of the plume splitting into two prominent components as observed by the ICCD imaging. Below 2 x 10{sup -2} mbar, the dynamic of the plume is directive (1D), while a quasi-stable behavior on the ionic current signal is observed. In the 0.2- to 0.5-mbar region, a quasi-stationary regime is obtained. More accurately, both the ionic yield and the plume stopping distance vary very slowly in such pressures range. Above 0.5 mbar, the ionic yield is altered again corresponding to the appearance of the diffusion regime. At a pressure of 1.5 mbar we observe a second appearance of an ionic signal peak. A correlation between the results obtained by Langmuir probe and ICCD imaging is made, presented, and discussed within this contribution. (orig.)

  1. Detecting Terrorism Incidence Type from News Summary

    DEFF Research Database (Denmark)

    Nizamani, Sarwat; Memon, Nasrullah

    2012-01-01

    The paper presents the experiments to detect terrorism incidence type from news summary data. We have applied classification techniques on news summary data to analyze the incidence and detect the type of incidence. A number of experiments are conducted using various classification algorithms...... and results show that a simple decision tree classifier can learn incidence type with satisfactory results from news data....

  2. Partial scram incident in FBTR

    International Nuclear Information System (INIS)

    Usha, S.; Pillai, C.P.; Muralikrishna, G.

    1989-01-01

    Evaluation of a partial scram incident occurred at the Fast Breeder Test Reactor at Kalpakkam was carried out. Based on the observations of the experiments it was ascertained that the nonpersistant order was due to superimposed noise component on the channel that was close to the threshold and had resulted in intermittent supply to electro-magnetic (EM) coils. Owing to a larger discharge time and a smaller charge time, the EM coils got progressively discharged. It was confirmed that during the incident, partial scram took place since the charging and discharging patterns of the EM coils are dissimilar and EM coils of rods A, E and F had discharged faster than others for noise component of a particular duty cycle. However, nonlatching of scram order was because of the fact that noise pulse duration was less than latching time. (author)

  3. Criticality incident detection assessment methodology

    International Nuclear Information System (INIS)

    Haley, Richard M.; Warburton, Simon J.; Bowden, Russell L.

    2003-01-01

    In the United Kingdom, all nuclear facilities that handle, treat or store fissile material require a Criticality Incident Detection and Alarm System (CIDAS) to be installed, unless a case is made for the omission of such a system. Where it is concluded that a CIDAS is required, the primary objective is the reliable detection of criticality and the initiation of prompt evacuation of plant workers from the vicinity of the incident. This paper will examine and compare various methods that can be used to demonstrate that a CIDAS will satisfy the detection criterion. The paper will focus on fit-for-purpose and cost-effective methods for the assessment of gamma-based systems. In the experience of the authors this is particularly useful in demonstrating the efficacy of existing systems in operational plant. (author)

  4. Dissociative Tendencies and Traffic Incidents

    Directory of Open Access Journals (Sweden)

    Valle, Virginia

    2012-01-01

    Full Text Available This paper analyses the relationship between dissociative experiences and road traffic incidents (crashes and traffic tickets in drivers (n=295 from Mar del Plata (Argentina city. A self-report questionnaire was applied to assess traffic crash involvement and sociodemographic variables. Dissociative tendencies were assessed by a modified version of the DES scale. To examine differences in DES scores tests of the difference of means were applied. Drivers who reported to be previously involved in traffic incidents obtained higher puntuations in the dissociative experiences scale than drivers who did not report such events. This result is observed for the total scale and for the three sub-scales (absorption, amnesia and depersonalization. However, differences appeared mainly for minor damage collisions. Further studies are needed to evaluate the role of dissociative tendencies as a risk factor in road traffic safety.

  5. [Skin cancer incidence in Zacatecas].

    Science.gov (United States)

    Pinedo-Vega, José Luis; Castañeda-López, Rosalba; Dávila-Rangel, J Ignacio; Mireles-García, Fernando; Ríos-Martínez, Carlos; López-Saucedo, Adrián

    2014-01-01

    Skin cancer is the most frequent cancer related to ultraviolet radiation. The aim was to estimate the incidence of skin cancer type, melanoma and non-melanoma in Zacatecas, Mexico. An epidemiological study was carried out during the period from 2008 to 2012. The data were obtained from the Instituto Mexicano del Seguro Social (IMSS), Instituto de Seguridad y Servicios Sociales de los Trabajadores del Estado (ISSSTE), Secretaría de Salud de Zacatecas (SSZ) and a private source, the Centro Médico Alameda. The incidence and the global prevalence were estimated. We studied 958 skin cancer cases, histopathologically confirmed. The cases were distributed as: 63.6 % basal cell carcinomas, 25.8 % squamous cell carcinomas, and 10.6 % melanoma. Significantly higher proportions were observed in women in the basal cell carcinomas (60.4 %) and squamous cell carcinomas (53.4 %). However, in the case of melanoma, the major proportion was observed in men (55.9 %). The more frequent skin cancer location was the face and for basal cell carcinoma was the nose (53 %); for squamous cell carcinomas were the lips (36 %), and for melanoma it was also the nose (40 %). The skin cancer incidence was estimated in 20 cases for each 100 000 inhabitants. Linear regression analysis showed that the skin cancer is increasing at an annual rate of 10.5 %. The anatomical location indicates that solar UV radiation is a risk factor, since the face is the zone with major exposure to solar radiation.

  6. Structure of a monolayer of molecular rotors on aqueous subphase from grazing-incidence X-ray diffraction.

    Science.gov (United States)

    Kaleta, Jiří; Wen, Jin; Magnera, Thomas F; Dron, Paul I; Zhu, Chenhui; Michl, Josef

    2018-03-23

    In situ grazing-incidence X-ray scattering shows that a monolayer of artificial rod-shaped dipolar molecular rotors produced on the surface of an aqueous subphase in a Langmuir trough has a structure conducive to a 2D ferroelectric phase. The axes of the rotors stand an average of 0.83 nm apart in a triangular grid, perpendicular to the surface within experimental error. They carry 2,3-dichlorophenylene rotators near rod centers, between two decks of interlocked triptycenes installed axially on the rotor axle. The analysis is based first on simultaneous fitting of observed Bragg rods and second on fitting the reflectivity curve with only three adjustable parameters and the calculated rotor electron density, which also revealed the presence of about seven molecules of water near each rotator. Dependent on preparation conditions, a minor and variable amount of a different crystal phase may also be present in the monolayer.

  7. Critical incident monitoring in anaesthesia.

    Science.gov (United States)

    Choy, Y C

    2006-12-01

    Critical incident monitoring in anaesthesia is an important tool for quality improvement and maintenance of high safety standards in anaesthetic services. It is now widely accepted as a useful quality improvement technique for reducing morbidity and mortality in anaesthesia and has become part of the many quality assurance programmes of many general hospitals under the Ministry of Health. Despite wide-spread reservations about its value, critical incident monitoring is a classical qualitative research technique which is particularly useful where problems are complex, contextual and influenced by the interaction of physical, psychological and social factors. Thus, it is well suited to be used in probing the complex factors behind human error and system failure. Human error has significant contributions to morbidities and mortalities in anaesthesia. Understanding the relationships between, errors, incidents and accidents is important for prevention and risk management to reduce harm to patients. Cardiac arrests in the operating theatre (OT) and prolonged stay in recovery, constituted the bulk of reported incidents. Cardiac arrests in OT resulted in significant mortality and involved mostly de-compensated patients and those with unstable cardiovascular functions, presenting for emergency operations. Prolonged-stay in the recovery extended period of observation for ill patients. Prolonged stay in recovery was justifiable in some cases, as these patients needed a longer period of post-operative observation until they were stable enough to return to the ward. The advantages of the relatively low cost, and the ability to provide a comprehensive body of detailed qualitative information, which can be used to develop strategies to prevent and manage existing problems and to plan further initiatives for patient safety makes critical incident monitoring a valuable tool in ensuring patient safety. The contribution of critical incident reporting to the issue of patient safety is

  8. The Tricastin incident; L'incident du Tricastin

    Energy Technology Data Exchange (ETDEWEB)

    Nifenecker, H.

    2008-07-01

    The author comments the incident which occurred on the Tricastin site in July 2008: the release of 30 cubic meters of a uranium-containing solution. First, he recalls the international nuclear event scale, outlines that the Tricastin is not a nuclear power plant, that uranium is more a chemical toxic product than a radiological toxic product. After having briefly recalled some dose threshold values, he discusses the presence of uranium in the environment, and states that the event is actually a non-event which has been in fact magnified by the media

  9. Fe3O4/γ-Fe2O3 nanoparticle multilayers deposited by the Langmuir-Blodgett technique for gas sensors application.

    Science.gov (United States)

    Capone, S; Manera, M G; Taurino, A; Siciliano, P; Rella, R; Luby, S; Benkovicova, M; Siffalovic, P; Majkova, E

    2014-02-04

    Fe3O4/γ-Fe2O3 nanoparticles (NPs) based thin films were used as active layers in solid state resistive chemical sensors. NPs were synthesized by high temperature solution phase reaction. Sensing NP monolayers (ML) were deposited by Langmuir-Blodgett (LB) techniques onto chemoresistive transduction platforms. The sensing ML were UV treated to remove NP insulating capping. Sensors surface was characterized by scanning electron microscopy (SEM). Systematic gas sensing tests in controlled atmosphere were carried out toward NO2, CO, and acetone at different concentrations and working temperatures of the sensing layers. The best sensing performance results were obtained for sensors with higher NPs coverage (10 ML), mainly for NO2 gas showing interesting selectivity toward nitrogen oxides. Electrical properties and conduction mechanisms are discussed.

  10. Energy transfer and electron transfer in dimers and polymers of porphyrin and phthalocyanines: from the liquid phase to Langmuir-Blodgett films

    International Nuclear Information System (INIS)

    Lipskier, Jean-Francois

    1991-01-01

    The understanding of phenomena of photo-induced transfer of energy and of electron between chromophores belonging to a same supra-molecular entity is necessary for the design and fabrication of molecule devices performing the conversion of a light signal into electric signal or chemical potential. As porphyrin oligomers and phthalocyanine oligomers are examples of interest for the systematic study of parameters governing these processes, the first part of this research thesis addresses the study of dimers and trimers bound by covalent bridges. The second part addresses the study of physical-chemical properties of complexes bound by the Van der Waals interaction as well as by the Coulomb attraction. An extension to Langmuir-Blodgett films is proposed, and the properties of complexes organised in thin films according to this methodology are compared with those of their homologues in solution [fr

  11. Use of atomic force microscopy for imaging the initial stage of the nucleation of calcium phosphate in Langmuir-blodgett films of stearic acid

    International Nuclear Information System (INIS)

    Zhang Yuanjian; He Ping; Xu Xiudong; Li Jinghong

    2004-01-01

    The nucleation of calcium phosphate on the substrate of steatic acid Langmuir-blodgett film at the initial stage was investigated by atomic force microscopy. Nano-dots, nano-wires and nano-islands were observed in sequence for the first time, reflecting the nucleation of calcium phosphate and the molecular arrangement of carboxylic layer. The nucleation rates perpendicular and parallel to the carboxylic terminal group were estimated from the height and diameter of the calcium phosphate crystals, respectively. And this stage was distinct from the late explosive grown stage, in which the change of the morphology was not obvious. The approaches based on this discovery would lead to the development of new strategies in the controlled synthesis of inorganic nano-phases and the assembly of organized composite and ceramic materials

  12. Closed-Form Solutions of the Thomas-Fermi in Heavy Atoms and the Langmuir-Blodgett in Current Flow ODEs in Mathematical Physics

    Directory of Open Access Journals (Sweden)

    Efstathios E. Theotokoglou

    2015-01-01

    Full Text Available Two kinds of second-order nonlinear, ordinary differential equations (ODEs appearing in mathematical physics are analyzed in this paper. The first one concerns the Thomas-Fermi (TF equation, while the second concerns the Langmuir-Blodgett (LB equation in current flow. According to a mathematical methodology recently developed, the exact analytic solutions of both TF and LB ODEs are proposed. Both of these are nonlinear of the second order and by a series of admissible functional transformations are reduced to Abel’s equations of the second kind of the normal form. The closed form solutions of the TF and LB equations in the phase and physical plane are given. Finally a new interesting result has been obtained related to the derivative of the TF function at the limit.

  13. Effect of metal ions on the formation and properties of monolayers and nanosized Langmuir-Blodgett films based on diphilic aminomethylated calix[4]resorcinarenes

    International Nuclear Information System (INIS)

    Neveshkin, A.A.; Rusanova, T.Yu.; Rumyantseva, S.S.; Serdobintsev, A.A.; Podkosov, K.V.; Shtykov, S.N.; Klimov, B.N.; Gorin, D.A.; Ryzhkina, I.S.

    2008-01-01

    The behavior of the monolayers of three diphilic aminomethylated calix[4]resorcinarene (CRA) derivatives on the surface of a pure aqueous subphase and subphase containing copper(II), nickel(II), europium(III), terbium(III), and lanthanum(III) ions was investigated. The monolayer transfer to the quartz and single-crystal silicon substrates was accomplished by the Langmuir-Blodgett (LB) technique. The films were studied by ellipsometry and mass-spectrometry. Metal ions were found to exert effect on the limit area per one CRA molecule in the monolayer, on the surface collapse pressure and transfer coefficient of monolayer, and on the thickness and refractive index of the CRA-based LB films [ru

  14. Review of Langmuir-Wave-Caused Dips and Charge-Exchange-Caused Dips in Spectral Lines from Plasmas and their Applications

    Directory of Open Access Journals (Sweden)

    Elisabeth Dalimier

    2014-05-01

    Full Text Available We review studies of two kinds of dips in spectral line profiles emitted by plasmas—dips that have been predicted theoretically and observed experimentally: Langmuir-wave-caused dips (L-dips and charge-exchange-caused dips (X-dips. There is a principal difference with respect to positions of L-dips and X-dips relative to the unperturbed wavelength of a spectral line: positions of L-dips scale with the electron density Ne roughly as Ne1/2, while positions of X-dips are almost independent of Ne (the dependence is much weaker than for L-dips. L-dips and X-dips phenomena are important, both fundamentally and practically. The fundamental importance is due to a rich physics behind each of these phenomena. L-dips are a multi-frequency resonance phenomenon caused by a single-frequency (monochromatic electric field. X-dips are due to charge exchange at anticrossings of terms of a diatomic quasi-molecule, whose nuclei have different charges. As for important practical applications, they are as follows: observations of L-dips constitute a very accurate method to measure the electron density in plasmas—a method that does not require knowledge of the electron temperature. L-dips also allow measuring the amplitude of the electric field of Langmuir waves—the only spectroscopic method available for this purpose. Observations of X-dips provide an opportunity to determine rate coefficient of charge exchange between multi-charged ions. This is an important reference data, virtually inaccessible by other experimental methods. The rate coefficients of charge exchange are important for magnetic fusion in Tokamaks, for population inversion in the soft x-ray and VUV ranges, for ion storage devices, as well as for astrophysics (e.g., for the solar plasma and for determining the physical state of planetary nebulae.

  15. Structural characterization and plasmonic properties of two-dimensional arrays of hydrophobic large gold nanoparticles fabricated by Langmuir-Blodgett technique

    Energy Technology Data Exchange (ETDEWEB)

    Ishida, Takuya; Tachikiri, Yuki; Sako, Takayuki [Department of Materials Physics and Chemistry, Graduate School of Engineering, Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka 819-0395 (Japan); Takahashi, Yukina, E-mail: yukina@mail.cstm.kyushu-u.ac.jp [Department of Applied Chemistry, Faculty of Engineering, Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka 819-0395 (Japan); Yamada, Sunao, E-mail: yamada@mail.cstm.kyushu-u.ac.jp [Department of Applied Chemistry, Faculty of Engineering, Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka 819-0395 (Japan); Center for Future Chemistry, Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka 819-0395 (Japan)

    2017-05-15

    Highlights: • Hydrophobic gold nanoparticles (AuNPs) by our method were large and stable enough. • Two-dimensional (2D) arrays of the AuNPs were obtained by Langmuir-Blodgett method with polyethylene glycol. • The plasmon resonant wavelength of the 2D arrays can be controlled by the diameter. - Abstract: We have succeeded in fabricating two-dimensional (2D) arrays of larger gold nanoparticles (AuNPs) (diameters 17, 28, and 48 nm) by Langmuir-Blodgett (LB) method. Although the particle size of AuNPs is one of the most important factors in order to control the optical properties of 2D arrays, there have been reported only the size of less than ∼20 nm. This is a first report on the bottom-up fabrication of 2D arrays consisting of hydrophobic AuNP with the diameter of ∼50 nm, of which the size is expected to obtain maximum near-field effects. Octadecylthiolate-capped AuNPs (ODT-AuNPs) which were prepared by our method could be re-dispersed in chloroform even after drying completely, realizing the spreading of the colloidal chloroform solution onto the water surface. Accordingly, densely-packed 2D LB films of ODT-AuNPs could be fabricated on an indium-tin-oxide substrate, when water as the subphase and polyethylene glycol (PEG) as an amphiphilic agent were used. PEG played an important role to form densely-packed film uniformly due to increasing affinity between hydrophobic AuNP and water. Absorption spectra of the films revealed that the resonance wavelengths of plasmon oscillation through interparticle plasmon coupling were clearly correlated with the particle sizes rather than deposition densities.

  16. Langmuir-Blodgett and X-ray diffraction studies of isolated photosystem II reaction centers in monolayers and multilayers: physical dimensions of the complex.

    Science.gov (United States)

    Uphaus, R A; Fang, J Y; Picorel, R; Chumanov, G; Wang, J Y; Cotton, T M; Seibert, M

    1997-04-01

    The photosystem II (PSII) reaction center (RC) is a hydrophobic intrinsic protein complex that drives the water-oxidation process of photosynthesis. Unlike the bacterial RC complex, an X-ray crystal structure of the PSII RC is not available. In order to determine the physical dimensions of the isolated PSII RC complex, we applied Langmuir techniques to determine the cross-sectional area of an isolated RC in a condensed monolayer film. Low-angle X-ray diffraction results obtained by examining Langmuir-Blodgett multilayer films of alternating PSII RC/Cd stearate monolayers were used to determine the length (or height; z-direction, perpendicular to the plane of the original membrane) of the complex. The values obtained for a PSII RC monomer were 26 nm2 and 4.8 nm, respectively, and the structural integrity of the RC in the multilayer film was confirmed by several approaches. Assuming a cylindrical-type RC structure, the above dimensions lead to a predicted volume of about 125 nm3. This value is very close to the expected volume of 118 nm3, calculated from the known molecular weight and partial specific volume of the PSII RC proteins. This same type of comparison was also made with the Rhodobacter sphaeroides RC based on published data, and we conclude that the PSII RC is much shorter in length and has a more regular solid geometric structure than the bacterial RC. Furthermore, the above dimensions of the PSII RC and those of PSII core (RC plus proximal antenna) proteins protruding outside the plane of the PSII membrane into the lumenal space as imaged by scanning tunneling microscopy (Seibert, Aust. J. Pl. Physiol. 22, 161-166, 1995) fit easily into the known dimensions of the PSII core complex visualized by others as electron-density projection maps. From this we conclude that the in situ PSII core complex is a dimeric structure containing two copies of the PSII RC.

  17. Hardware and software systems for the determination of charged particle parameters in low pressure plasmas using impedance-tuned Langmuir probes

    Science.gov (United States)

    Ye, Yuancai; Marcus, R. Kenneth

    1997-12-01

    A computer-controlled, impedance-tuned Langmuir probe data acquisition system and processing software package have been designed for the diagnostic study of low pressure plasmas. The combination of impedance-tuning and a wide range of applied potentials (± 100 V) provides a versatile system, applicable to a variety of analytical plasmas without significant modification. The automated probe system can be used to produce complete and undistorted current-voltage (i-V) curves with extremely low noise over the wide potential range. Based on these hardware and software systems, it is possible to determine all of the important charged particle parameters in a plasma; electron number density ( ne), ion number density ( ni), electron temperature ( Te), electron energy distribution function (EEDF), and average electron energy (). The complete data acquisition system and evaluation software are described in detail. A LabView (National Instruments Corporation, Austin, TX) application program has been developed for the Apple Macintosh line of microcomputers to control all of the operational aspects of the Langmuir probe experiments. The description here is mainly focused on the design aspects of the acquisition system with the targets of extremely low noise and reduction of the influence of measurement noise in the calculation procedures. This is particularly important in the case of electron energy distribution functions where multiple derivatives are calculated from the obtained i-V curves. A separate C-language data processing program has been developed and is included here to allow the reader to evaluate data obtained with the described hardware, or any i-V data imported in tab separated variable format. Both of the software systems are included on a Macintosh formatted disk for their use in other laboratories desiring these capabilities.

  18. Grazing incidence diffraction : A review

    Energy Technology Data Exchange (ETDEWEB)

    Gilles, B [LTPCM, ENSEEG. St. Martin d` Heres. (France)

    1996-09-01

    Different Grazing Incidence Diffraction (GID) methods for the analysis of thin films and multilayer structures are reviewed in three sections: the reflectivity is developed in the first one, which includes the non-specular diffuse scattering. The second one is devoted to the extremely asymmetric Bragg diffraction and the third one to the in-plane Bragg diffraction. Analytical formulations of the scattered intensities are developed for each geometry, in the framework of the kinetical analysis as well as the dynamical theory. Experimental examples are given to illustrate the quantitative possibility of the GID techniques.

  19. Browns Ferry charcoal adsorber incident

    International Nuclear Information System (INIS)

    Mays, G.T.

    1979-01-01

    The article reviews the temperature excursion in the charcoal adsorber beds of the Browns Ferry Unit 3 off-gas system that occurred on July 17, 1977. Significant temperature increases were experienced in the charcoal adsorber beds when charcoal fines were ignited by the ignition of a combustible mixture of hydrogen and oxygen in the off-gas system. The Browns Ferry off-gas system is described, and events leading up to and surrounding the incident are discussed. The follow-up investigation by Tennessee Valley Authority and General Electric Company personnel and their recommendations for system and operational modifications are summarized

  20. Ionospheric Oblique Incidence Soundings by Satellites

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The oblique incidence sweep-frequency ionospheric sounding technique uses the same principle of operation as the vertical incidence sounder. The primary difference...

  1. USFA NFIRS 2013 Fire Incident & Cause Data

    Data.gov (United States)

    Department of Homeland Security — The 2013 Fire Causes & Incident data was provided by the U.S. Fire Administration’s (USFA) National Fire Data Center’s (NFDC’s) National Fire Incident Reporting...

  2. Increasing incidence of diabetes after gestational diabetes

    DEFF Research Database (Denmark)

    Lauenborg, Jeannet; Hansen, Torben; Jensen, Dorte Møller

    2004-01-01

    To study the incidence of diabetes among women with previous diet-treated gestational diabetes mellitus (GDM) in the light of the general increasing incidence of overweight and diabetes and to identify risk factors for the development of diabetes.......To study the incidence of diabetes among women with previous diet-treated gestational diabetes mellitus (GDM) in the light of the general increasing incidence of overweight and diabetes and to identify risk factors for the development of diabetes....

  3. Poster - 27: Incident Learning Practices in Ontario

    Energy Technology Data Exchange (ETDEWEB)

    Angers, Crystal; Medlam, Gaylene; Liszewski, Brian; Simniceanu, Carina [The Ottawa Hospital Cancer Centre, Mississauga Halton/Central West Regional Cancer Center, Odette Cancer Centre, Cancer Care Ontario (Canada)

    2016-08-15

    Purpose: The Radiation Incident and Safety Committee (RISC), established and supported by Cancer Care Ontario (CCO), is responsible for advising the Provincial Head of the Radiation Treatment program on matters relating to provincial reporting of radiation incidents with the goal of improved risk mitigation. Methods: The committee is made up of Radiation Incident Leads (RILs) with representation from each of the 14 radiation medicine programs in the province. RISC routinely meets to review recent critical incidents and to discuss provincial reporting processes and future directions of the committee. Regular face to face meetings have provided an excellent venue for sharing incident learning practices. A summary of the incident learning practices across Ontario has been compiled. Results: Almost all programs in Ontario employ an incident learning committee to review incidents and identify corrective actions or process improvements. Tools used for incident reporting include: paper based reporting, a number of different commercial products and software solutions developed in-house. A wide range of classification schema (data taxonomies) are employed, although most have been influenced by national guidance documents. The majority of clinics perform root cause analyses but utilized methodologies vary significantly. Conclusions: Most programs in Ontario employ a committee approach to incident learning. However, the reporting tools and taxonomies in use vary greatly which represents a significant challenge to provincial reporting. RISC is preparing to adopt the National System for Incident Reporting – Radiation Therapy (NSIR-RT) which will standardize incident reporting and facilitate data analyses aimed at identifying targeted improvement initiatives.

  4. Poster - 27: Incident Learning Practices in Ontario

    International Nuclear Information System (INIS)

    Angers, Crystal; Medlam, Gaylene; Liszewski, Brian; Simniceanu, Carina

    2016-01-01

    Purpose: The Radiation Incident and Safety Committee (RISC), established and supported by Cancer Care Ontario (CCO), is responsible for advising the Provincial Head of the Radiation Treatment program on matters relating to provincial reporting of radiation incidents with the goal of improved risk mitigation. Methods: The committee is made up of Radiation Incident Leads (RILs) with representation from each of the 14 radiation medicine programs in the province. RISC routinely meets to review recent critical incidents and to discuss provincial reporting processes and future directions of the committee. Regular face to face meetings have provided an excellent venue for sharing incident learning practices. A summary of the incident learning practices across Ontario has been compiled. Results: Almost all programs in Ontario employ an incident learning committee to review incidents and identify corrective actions or process improvements. Tools used for incident reporting include: paper based reporting, a number of different commercial products and software solutions developed in-house. A wide range of classification schema (data taxonomies) are employed, although most have been influenced by national guidance documents. The majority of clinics perform root cause analyses but utilized methodologies vary significantly. Conclusions: Most programs in Ontario employ a committee approach to incident learning. However, the reporting tools and taxonomies in use vary greatly which represents a significant challenge to provincial reporting. RISC is preparing to adopt the National System for Incident Reporting – Radiation Therapy (NSIR-RT) which will standardize incident reporting and facilitate data analyses aimed at identifying targeted improvement initiatives.

  5. INCIDENCE OF AMPUTATION IN EMERGENCY

    Directory of Open Access Journals (Sweden)

    K. Rojaramani Kumbha

    2016-08-01

    Full Text Available Advanced Technology and early detection of disease by recent improvements in investigation modalities lead to decreased incidents of amputations while Road Traffic Accidents (RTA increase. Furthermore, it leads to variation and decreased morbidity, mortality and accidents (crush injuries, and better equipped and trained staff, specialist services, diabetic food, rehabilitation centres, and giving good support physically and psychologically for Amputated patients. OBJECTIVE To know incidence rates of Emergency Amputation who attended causality with advanced disease and severe Trauma. METHODOLOGY The study is done over a period of one year i.e. between June 2015 to June 2016 who attended causality with advanced and severe disease affecting the limbs either due to diabetes, trauma or vascular diseases. RESULTS During one-year period, total 6,371 patients attended for general surgery OP. In those, 187 patients needed emergency surgery which included both major and minor operations. Among those, 81 patients were amputated. CONCLUSION As per our available records and observation, even though there is increased literacy and access to advanced technology, there is still increased incidence of patients undergoing amputations due to diseases. Therefore, there is a need to improve awareness and importance of early detection of diabetes, hazards of smoking, and regular general health checkups for patients at root level. With that we can treat diabetes and/or any disease in time. So there must be awareness in peripheral health staff i.e. PHC, subcentres, and community health centres about early detection of disease which in turn improves the quality of life of the patient. Due to diabetes slight injury to the glucose laden tissue may cause chronic infection and ulcer formation.(1 The tumours are seen commonly in the age group of 20-40 years after bone fusion, bones affected commonly are those around the knee (lower end of knee, upper end of tibia. A lytic

  6. RADIATION CONTAMINATION INCIDENT AT ISOLDE

    CERN Multimedia

    2000-01-01

    On 27 June 2000 three specialists were investigating a problem with the extraction electrode of the high-resolution separator (HRS) in Isolde. Whilst using an endoscope in order to have a closer look at the interior, they came into contact with radioactive dust and became contaminated. The level of contamination was low and the radiation dose received by the 3 persons was far below the effective dose limit given in the CERN Radiation Safety Manual and in the regulations of the Host States.According to the usual procedure, the Director General has set up a Fact-Finding Group and an Accident Board in order to advise him on the steps and decisions tobe taken following this incident and in particular to avoid a recurrence.

  7. Reactor coolant pump transportation incident

    International Nuclear Information System (INIS)

    Noce, D.

    1992-01-01

    This paper reports on an incident, which occurred on August 27, 1991, in which a Reactor Coolant Pump motor en route from Surry Power Station to Westinghouse repair facilities struck the overpass at the junction of Interstate 64 and Jefferson Avenue in Newport News, Virginia. The transport container that housed the reactor coolant pump motor failed to clear the overpass. The force of the impact dislodged the container and motor from the truck bed, and it landed on the acceleration land and road shoulder. Upon impact, the container broke open and exposed the reactor coolant pump motor. Incidental radioactively contaminated water that remained in the motor coolers drained onto the road, contaminating the aggregate as well as the underlying gravel

  8. An introduction to incidence geometry

    CERN Document Server

    De Bruyn, Bart

    2016-01-01

    This book gives an introduction to the field of Incidence Geometry by discussing the basic families of point-line geometries and introducing some of the mathematical techniques that are essential for their study. The families of geometries covered in this book include among others the generalized polygons, near polygons, polar spaces, dual polar spaces and designs. Also the various relationships between these geometries are investigated. Ovals and ovoids of projective spaces are studied and some applications to particular geometries will be given. A separate chapter introduces the necessary mathematical tools and techniques from graph theory. This chapter itself can be regarded as a self-contained introduction to strongly regular and distance-regular graphs. This book is essentially self-contained, only assuming the knowledge of basic notions from (linear) algebra and projective and affine geometry. Almost all theorems are accompanied with proofs and a list of exercises with full solutions is given at the end...

  9. The Jarvis gas release incident

    International Nuclear Information System (INIS)

    Manocha, J.

    1992-01-01

    On 26 September, 1991, large volumes of natural gas were observed to be leaking from two water wells in the Town of Jarvis. Gas and water were being ejected from a drilled water well, at which a subsequent gas explosion occurred. Measurements of gas concentrations indicated levels far in excess of the lower flammability limit at several locations. Electrical power and natural gas services were cut off, and residents were evacuated. A state of emergency was declared, and gas was found to be flowing from water wells, around building foundations, and through other fractures in the ground. By 27 September the volumes of gas had reduced substantially, and by 30 September all residents had returned to their homes and the state of emergency was cancelled. The emergency response, possible pathways of natural gas into the aquifer, and public relations are discussed. It is felt that the likelihood of a similar incident occurring in the future is high. 11 figs

  10. Scrutinizing incident reporting in anaesthesia: why is an incident perceived as critical?

    DEFF Research Database (Denmark)

    Maaløe, R; la Cour, M; Hansen, A

    2006-01-01

    The purpose of the present study was to measure the incidence and type of incidents that occurred in relation to anaesthesia and surgery during a 1-year period in six Danish hospitals. Furthermore, we wanted to identify risk factors for incidents, as well as risk factors for incidents being deeme...... critical....

  11. Cancer incidence among Danish seafarers

    DEFF Research Database (Denmark)

    Kærlev, Linda; Hansen, Johnny; Lyngbeck Hansen, Hans

    2005-01-01

    ), and an excess of cancer of the lung, rectum, and cervix uteri among women. The differences in risk pattern for lung cancer between the different job categories among men ranged in terms of SIR from 1.2 (95% CI 0.9 to 1.7) (engine officers) to 2.3 (1.6 to 3.3) (engine room crew), and 4.1 (2.1 to 7.4) among...... extensively in ships. The aim of this study was to study cancer morbidity among Danish seafarers in relation to type of ship and job title. METHODS: A cohort of all Danish seafarers during 1986-1999 (33,340 men; 11,291 women) registered by the Danish Maritime Authority with an employment history was linked...... with the nationwide Danish Cancer Registry and followed up for cancer until the end of 2002. The number of person years at risk was 517,518. Standardised incidence ratios (SIR) were estimated by use of the corresponding national rates. RESULTS: The SIR of all cancers combined was higher than expected: 1.26 (95% CI 1...

  12. Critical incidents: exploring theory policy and practice

    OpenAIRE

    Beeke, Matthew A.

    2011-01-01

    Responding to critical incidents in school communities has become an established part of the practice of educational psychologists (EPs). Despite this the EP professional journal literature is sparse, the last major study being conducted by Houghton in 1996. Within a mixed methods design this study aimed to explore various aspects of EP practice in response to critical incidents. Firstly, critical incident policy and EP journal literature was examined to provide a definition...

  13. Reactor incident status 1981 annual report

    International Nuclear Information System (INIS)

    Kiser, S.H.

    1982-01-01

    Reactor Incident followup action is summarized through periodic status reports. This annual report summarizes action taken or anticipated for Reactor Incidents through December 1981. Incidents for which action has been completed, have been deleted from the report. Quarterly addende will update the report by tabulating incidents for each three month period through the coming year. The report consists of a part for the P, K, and C Reactors. Each reactor part is divided into three sections: Further Technical Analysis or Followup Needed; Funding and/or Implementation Needed; and No Further Technical Analysis Anticipated

  14. In situ and real-time atomic force microscopy studies of the stability of oligothiophene langmuir-blodgett monolayers in liquid

    KAUST Repository

    Yin, Naining

    2014-03-20

    Oligothiophene thin films have been considered as promising material for molecular electronics due to their desirable electronic properties and high structural stability under ambient conditions. To ensure performance in devices the functional structures, such as individual ordered domains, must be stable under practical and operational conditions or environments including exposure to various media. This work investigates the structure of oligothiophene Langmuir-Blodgett (LB) films upon exposure to liquid media such as water, ethanol (EtOH), and mixed tetrahydrofuran (THF)/EtOH solutions. The LB films form islands ranging from 500 nm up to 1 μm consisting of densely packed oligothiophene molecules. These islands are surrounded by bare substrate and loosely packed adsorbates. In situ and time-dependent AFM images were acquired to reveal the structural evolution, from which degradation pathways and kinetics are extracted. Degradation of these LB films initiates and propagates from intraisland defect sites, such as cracks and pin holes, whereas the edges of islands remain intact on the surface. The observations appear to be in contrast to the known degradation mechanism among self-assembled monolayers, such as alkanethiols on gold, which initiates and progresses at domain boundaries. Rationale for the observed degradation processes will also be discussed. © 2014 American Chemical Society.

  15. Mixing Rules Formulation for a Kinetic Model of the Langmuir-Hinshelwood Semipredictive Type Applied to the Heterogeneous Photocatalytic Degradation of Multicomponent Mixtures

    Directory of Open Access Journals (Sweden)

    John Wilman Rodriguez-Acosta

    2014-01-01

    Full Text Available Mixing rules coupled to a semipredictive kinetic model of the Langmuir-Hinshelwood type were proposed to determine the behavior of the heterogeneous solar photodegradation with TiO2-P25 of multicomponent mixtures at pilot scale. The kinetic expressions were expressed in terms of the effective concentration of total organic carbon (xTOC. An expression was obtained in a generalized form which is a function of the mixing rules as a product of a global contribution of the reaction rate constant k′ and a mixing function fC. Kinetic parameters of the model were obtained using the Nelder and Mead (N-M algorithm. The kinetic model was validated with experimental data obtained from the degradation of binary mixtures of chlorinated compounds (DCA: dichloroacetic acid and 4-CP: 4-chlorophenol at different initial global concentration, using a CPC reactor at pilot scale. A simplex-lattice {2,3} design experiment was adopted to perform the runs.

  16. Simulation studies of plasma waves in the electron foreshock: The generation of Langmuir waves by a gentle bump-on-tail electron distribution

    International Nuclear Information System (INIS)

    Dum, C.T.

    1990-01-01

    The generation of Langmuir waves by a gentle bump-on-tail electron distribution is analyzed. It is shown that with appropriately designed simulation experiments, quasi-linear theory can be quantitatively verified for parameters corresponding to the electron foreshock. The distribution function develops a plateau by resonant diffusion, and changes outside this velocity range are negligible, except for the contribution of nonresonant diffusion to acceleration of bulk electrons. The dispersion relation is solved for the evolving distribution function and exhibits the dynamics of wave growth and changes in real frequency. The integral of the quasi-linear equations is also used to relate the evolution of distribution function and wave spectrum and gives agreement with the simulations. Even in extremely long simulation runs there is practically no evolution in wave energy or the distribution function, once a plateau has been formed. the saturated field levels are much lower than the estimates that are generally used to assess the importance of additional weak or strong turbulence effects. These effects cannot prevent plateau formation and are only noticeable if ions are also included in the model. They then lead to a redistribution of the spectrum toward low wave number modes which propagate mainly opposite to the beam. This occurs long after plateau formation and plays no significant role in the overall system dynamics or energy balance. One will have to live with quasi-linear theory as a key ingredient for a global model of foreshock wave phenomena

  17. Self-Assembly, Interfacial Nanostructure, and Supramolecular Chirality of the Langmuir-Blodgett Films of Some Schiff Base Derivatives without Alkyl Chain

    Directory of Open Access Journals (Sweden)

    Tifeng Jiao

    2013-01-01

    Full Text Available A special naphthyl-containing Schiff base derivative, N,N′-bis(2-hydroxy-1-naphthylidene-1,2-phenylenediamine, was synthesized, and its coordination with various metal ions in situ at the air/water interface has been investigated. Although the ligand contains no alkyl chain, it can be spread on water surface. When metal ions existed in the subphase, an interfacial coordination between the ligand and different metal ions occurred in the spreading film, while different Nanostructures were fabricated in the monolayers. Interestingly to note that among various metal ions, only the in situ coordination-induced Cu(II-complex film showed supramolecular chirality, although the multilayer films from the ligand or preformed complex are achiral. The chirality of the in situ Cu(II-coordinated Langmuir film was developed due to the special distorted coordination reaction and the spatial limitation at the air/water interface. A possible organization mechanism at the air/water interface was suggested.

  18. Presenting a new kinetic model for methanol to light olefins reactions over a hierarchical SAPO-34 catalyst using the Langmuir-Hinshelwood-Hougen-Watson mechanism

    Science.gov (United States)

    Javad Azarhoosh, Mohammad; Halladj, Rouein; Askari, Sima

    2017-10-01

    In this study, a new kinetic model for methanol to light olefins (MTO) reactions over a hierarchical SAPO-34 catalyst using the Langmuir-Hinshelwood-Hougen-Watson (LHHW) mechanism was presented and the kinetic parameters was obtained using a genetic algorithm (GA) and genetic programming (GP). Several kinetic models for the MTO reactions have been presented. However, due to the complexity of the reactions, most reactions are considered lumped and elementary, which cannot be deemed a completely accurate kinetic model of the process. Therefore, in this study, the LHHW mechanism is presented as kinetic models of MTO reactions. Because of the non-linearity of the kinetic models and existence of many local optimal points, evolutionary algorithms (GA and GP) are used in this study to estimate the kinetic parameters in the rate equations. Via the simultaneous connection of the code related to modelling the reactor and the GA and GP codes in the MATLAB R2013a software, optimization of the kinetic models parameters was performed such that the least difference between the results from the kinetic models and experiential results was obtained and the best kinetic parameters of MTO process reactions were achieved. A comparison of the results from the model with experiential results showed that the present model possesses good accuracy.

  19. Conductivity of Langmuir-Blodgett films of a disk-shaped liquid-crystalline molecule-DNA complex studied by current-sensing atomic force microscopy

    Science.gov (United States)

    Nayak, Alpana; Suresh, K. A.

    2008-08-01

    We have studied the electrical conductivity in monolayer films of an ionic disk-shaped liquid-crystal molecule, pyridinium tethered with hexaalkoxytriphenylene (PyTp), and its complex with DNA by current-sensing atomic force microscopy (CS-AFM). The pure PyTp and PyTp-DNA complex monolayer films were first formed at the air-water interface and then transferred onto conducting substrates by the Langmuir-Blodgett (LB) technique to study the nanoscale electron transport through these films. The conductive tip of CS-AFM, the LB film, and the metal substrate form a nanoscopic metal-LB film-metal (M-LB-M) junction. We have measured the current-voltage (I-V) characteristics for the M-LB-M junction using CS-AFM and have analyzed the data quantitatively. We find that the I-V curves fit well to the Fowler-Nordheim (FN) model, suggesting electron tunneling to be a possible mechanism for electron transport in our system. Further, analysis of the I-V curves based on the FN model yields the barrier heights of PyTp-DNA complex and pure PyTp films. Electron transport studies of films of ionic disk-shaped liquid-crystal molecules and their complex with DNA are important from the point of view of their applications in organic electronics.

  20. The effect of purification of single-walled carbon nanotube bundles on the alcohol sensitivity of nanocomposite Langmuir-Blodgett films for SAW sensing applications

    International Nuclear Information System (INIS)

    Penza, M; Tagliente, M A; Aversa, P; Re, M; Cassano, G

    2007-01-01

    HiPco (high-pressure CO dissociation process) single-walled carbon nanotube (SWCNT) bundles containing Fe particles were purified in a two-step purification process by thermal annealing in oxygen and post-treatment in HCl. Nanocomposite films of pristine and purified SWCNTs embedded in an organic matrix of cadmium arachidate (CdA) were prepared by a Langmuir-Blodgett (LB) molecular engineering technique with a fixed weight filler content of 75 wt% onto a surface acoustic wave (SAW) transducer operating as an oscillator at a frequency of 433 MHz. The raw and purified samples were characterized at various stages of the purification process using thermogravimetric analysis (TGA), high-resolution transmission electron microscopy (HR-TEM), along with energy-dispersive x-ray spectroscopy (EDS), field emission scanning electron microscopy (FE-SEM) and x-ray diffraction (XRD). Functional characterizations of the SWCNT-nanocomposite-based SAW sensors were investigated towards methanol, isopropanol and ethanol, and demonstrated high sensitivity, reversibility, fast response and ppm level detection at room temperature. Results indicate that the sensitivity of the SAW sensors based on a nanocomposite film of oxygen-annealed SWCNTs is enhanced to the alcohols tested at room temperature. Purification of the SWCNTs in the nanocomposite film affects the SAW sensitivity to alcohol by modulating the sensing properties. The sensing mechanisms are analysed and discussed